WorldWideScience

Sample records for arc coal process

  1. Coal processing and utilization

    Science.gov (United States)

    Schilling, H.-D.

    1980-04-01

    It is noted that the rising price of oil as well as supply concerns have lead to an increase in the use of coal. It is shown that in order for coal to take a greater role in energy supply, work must commence now in the areas of coal extraction and processing. Attention is given to new technologies such as coke production, electricity and heat generation, coal gasification, and coal liquifaction. Also covered are a separator for nitrogen oxides and active coal regeneration. Finally, the upgrading of coal is examined.

  2. Coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Baker, N.R.; Blazek, C.F.; Tison, R.R.

    1979-07-01

    Coal liquefaction is an emerging technology receiving great attention as a possible liquid fuel source. Currently, four general methods of converting coal to liquid fuel are under active development: direct hydrogenation; pyrolysis/hydrocarbonization; solvent extraction; and indirect liquefaction. This work is being conducted at the pilot plant stage, usually with a coal feed rate of several tons per day. Several conceptual design studies have been published recently for large (measured in tens of thousands of tons per day coal feed rate) commercial liquefaction plants, and these reports form the data base for this evaluation. Products from a liquefaction facility depend on the particular method and plant design selected, and these products range from synthetic crude oils up through the lighter hydrocarbon gases, and, in some cases, electricity. Various processes are evaluated with respect to product compositions, thermal efficiency, environmental effects, operating and maintenance requirements, and cost. Because of the large plant capacities of current conceptual designs, it is not clear as to how, and on what scale, coal liquefaction may be considered appropriate as an energy source for Integrated Community Energy Systems (CES). Development work, both currently under way and planned for the future, should help to clarify and quantify the question of applicability.

  3. Arc Interference Behavior during Twin Wire Gas Metal Arc Welding Process

    Directory of Open Access Journals (Sweden)

    Dingjian Ye

    2013-01-01

    Full Text Available In order to study arc interference behavior during twin wire gas metal arc welding process, the synchronous acquisition system has been established to acquire instantaneous information of arc profile including dynamic arc length variation as well as relative voltage and current signals. The results show that after trailing arc (T-arc is added to the middle arc (M-arc in a stable welding process, the current of M arc remains unchanged while the agitation increases; the voltage of M arc has an obvious increase; the shape of M arc changes, with increasing width, length, and area; the transfer frequency of M arc droplet increases and the droplet itself becomes smaller. The wire extension length of twin arc turns out to be shorter than that of single arc welding.

  4. Coal desulfurization process

    Science.gov (United States)

    Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

    1978-01-01

    A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

  5. The Charfuel coal refining process

    International Nuclear Information System (INIS)

    The patented Charfuel coal refining process employs fluidized hydrocracking to produce char and liquid products from virtually all types of volatile-containing coals, including low rank coal and lignite. It is not gasification or liquefaction which require the addition of expensive oxygen or hydrogen or the use of extreme heat or pressure. It is not the German pyrolysis process that merely 'cooks' the coal, producing coke and tar-like liquids. Rather, the Charfuel coal refining process involves thermal hydrocracking which results in the rearrangement of hydrogen within the coal molecule to produce a slate of co-products. In the Charfuel process, pulverized coal is rapidly heated in a reducing atmosphere in the presence of internally generated process hydrogen. This hydrogen rearrangement allows refinement of various ranks of coals to produce a pipeline transportable, slurry-type, environmentally clean boiler fuel and a slate of value-added traditional fuel and chemical feedstock co-products. Using coal and oxygen as the only feedstocks, the Charfuel hydrocracking technology economically removes much of the fuel nitrogen, sulfur, and potential air toxics (such as chlorine, mercury, beryllium, etc.) from the coal, resulting in a high heating value, clean burning fuel which can increase power plant efficiency while reducing operating costs. The paper describes the process, its thermal efficiency, its use in power plants, its pipeline transport, co-products, environmental and energy benefits, and economics

  6. The shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Koenders, L.O.M.; Zuideveld, P.O. [Shell Internationale Petroleum Maatschappij B.V., The Hague (Netherlands)

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  7. A Systematic Analysis of Coal Accumulation Process

    Institute of Scientific and Technical Information of China (English)

    CHENG Aiguo

    2008-01-01

    Formation of coal seam and coal-rich zone is an integrated result of a series of factors in coal accumulation process. The coal accumulation system is an architectural aggregation of coal accumulation factors. It can be classified into 4 levels: the global coal accumulation super-system, the coal accumulation domain mega.system, the coal accumulation basin system, and the coal seam or coal seam set sub-system. The coal accumulation process is an open, dynamic, and grey system, and is meanwhile a system with such natures as aggregation, relevance, entirety, purpose-orientated, hierarchy, and environment adaptability. In this paper, we take coal accumulation process as a system to study origin of coal seam and coal-rich zone; and we will discuss a methodology of the systematic analysis of coal accumulation process. As an example, the Ordos coal basin was investigated to elucidate the application of the method of the coal accumulation system analysis.

  8. Effect of arc on radiation thermometry in welding process

    Institute of Scientific and Technical Information of China (English)

    李亮玉; 王燕; 武宝林

    2002-01-01

    The effect of arc on radiation thermometry is analyzed in a field close to the arc during the welding process, and the ratio of signal to noise and other factors are obtained for a small current arc .The method of the temperature measurement is feasible when the arc current is decreased to a smaller value in the welding process.

  9. Collection of arc welding process data

    Directory of Open Access Journals (Sweden)

    K. Luksa

    2006-04-01

    Full Text Available Purpose: The aim of the research was to examine the possibility of detecting welding imperfections by recording the instant values of welding parameters. The microprocessor controlled system for real-time collection and display of welding parameters was designed, implemented and tested.Design/methodology/approach: The system records up to 4 digital or analog signals collected from welding process and displays their run on the LCD display. To disturb the welding process artificial disturbances were introduced.Findings: The occurrence of some welding imperfections is followed by changes of the welding parameters. In this case they can be revealed by the analysis of the instant values of the welding parameters.Research limitations/implications: In the paper results of monitoring manual metal arc welding and gas metal arc welding are presented.Practical implications: Monitoring of gas metal arc welding is a good tool for evaluation of the quality of weld. All introduced, artificial disturbances of the welding process destabilize the welding arc and produce changes in the instant values of the welding parameters.Originality/value: The paper presents a modern microprocessor controlled system for real-time collection and display of welding parameters. Results of tests show that simple statistical approach to welding parameters can help in evaluation of weld quality.

  10. The Shell coal gasification process

    International Nuclear Information System (INIS)

    This paper reports that Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency. Efficiency depends on many factors including the type of coal, the gasification process, the gas turbine, the steam cycle. NOx reduction measures and the degree and manner of integration. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV). The excellent environmental capabilities of IGCC systems are based on well established treating processes for removing sulphur and nitrogen species form the syngas. IGCC processes produce modest volumes of environmentally acceptable effluents. Gas turbine burner developments imply lower NOx emissions. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The plant is scheduled to start up in 1993

  11. Numerical Study on Arc Plasma Behavior During Arc Commutation Process in Direct Current Circuit Breaker

    International Nuclear Information System (INIS)

    This paper focuses on the numerical investigation of arc plasma behavior during arc commutation process in a medium-voltage direct current circuit breaker (DCCB) contact system. A three-dimensional magneto-hydrodynamic (MHD) model of air arc plasma in the contact system of a DCCB is developed, based on commercial software FLUENT. Coupled electromagnetic and gas dynamic interactions are considered as usual, and a thin layer of nonlinear electrical resistance elements is used to represent the voltage drop of plasma sheath and the formation of new arc root. The distributions of pressure, temperature, gas flow and current density of arc plasma in arc region are calculated. The simulation results indicate that the pressure distribution related to the contact system has a strong effect on the arc commutation process, arising from the change of electrical conductivity in the arc root region. In DCCB contact system, the pressure of arc root region will be concentrated and higher if the space above the moving contact is enclosed, which is not good for arc root commutation. However, when the region is opened, the pressure distribution would be lower and more evenly, which is favorable for the arc root commutation.

  12. Recent Advances in Precombustion Coal Cleaning Processes

    Institute of Scientific and Technical Information of China (English)

    Shiao-HungChiang; DaxinHe

    1994-01-01

    The mineral matter in coal constitutes a major impediment to the direct use of coal in power plants.A concerted effort has been mounted to reduce the ash/sulfur contents in product coal to meet the ever more stringent environmental regulations.In recent years,significant advances have taken place in fine coal cleaning technologies.A review of recent developments in aveanced physical,chemical and biological processes for deep-cleaning of fine coal is presented.

  13. Process characteristics of fibre-laser-assisted plasma arc welding

    Energy Technology Data Exchange (ETDEWEB)

    Mahrle, A; Schnick, M; Rose, S; Demuth, C; Beyer, E; Fuessel, U, E-mail: achim.mahrle@iws.fraunhofer.de [Dresden University of Technology, Institute of Surface and Manufacturing Technology, PO Box, D-01062 Dresden (Germany)

    2011-08-31

    Experimental and theoretical investigations on fibre-laser-assisted plasma arc welding (LAPW) were performed. Welding experiments were carried out on aluminium and steel sheets. In the case of a highly focused laser beam and a separate arrangement of plasma torch and laser beam, high-speed video recordings of the plasma arc and corresponding measurements of the time-dependent arc voltage revealed differences in the process behaviour for both materials. In the case of aluminium welding, a sharp decline in arc voltage and stabilization and guiding of the anodic arc root was observed whereas in steel welding the arc voltage was slightly increased after the laser beam was switched on. However, significant improvement of the melting efficiency with the combined action of plasma arc and laser beam was achieved for both types of material. Theoretical results of additional numerical simulations of the arc behaviour suggest that the properties of the arc plasma are mainly influenced not by a direct interaction with the laser radiation but by the laser-induced evaporation of metal. Arc stabilization with increased current densities is predicted for moderate rates of evaporated metal only whereas metal vapour rates above a certain threshold causes a destabilization of the arc and reduced current densities along the arc axis.

  14. Process characteristics of fibre-laser-assisted plasma arc welding

    Science.gov (United States)

    Mahrle, A.; Schnick, M.; Rose, S.; Demuth, C.; Beyer, E.; Füssel, U.

    2011-08-01

    Experimental and theoretical investigations on fibre-laser-assisted plasma arc welding (LAPW) were performed. Welding experiments were carried out on aluminium and steel sheets. In the case of a highly focused laser beam and a separate arrangement of plasma torch and laser beam, high-speed video recordings of the plasma arc and corresponding measurements of the time-dependent arc voltage revealed differences in the process behaviour for both materials. In the case of aluminium welding, a sharp decline in arc voltage and stabilization and guiding of the anodic arc root was observed whereas in steel welding the arc voltage was slightly increased after the laser beam was switched on. However, significant improvement of the melting efficiency with the combined action of plasma arc and laser beam was achieved for both types of material. Theoretical results of additional numerical simulations of the arc behaviour suggest that the properties of the arc plasma are mainly influenced not by a direct interaction with the laser radiation but by the laser-induced evaporation of metal. Arc stabilization with increased current densities is predicted for moderate rates of evaporated metal only whereas metal vapour rates above a certain threshold causes a destabilization of the arc and reduced current densities along the arc axis.

  15. Process characteristics of fibre-laser-assisted plasma arc welding

    International Nuclear Information System (INIS)

    Experimental and theoretical investigations on fibre-laser-assisted plasma arc welding (LAPW) were performed. Welding experiments were carried out on aluminium and steel sheets. In the case of a highly focused laser beam and a separate arrangement of plasma torch and laser beam, high-speed video recordings of the plasma arc and corresponding measurements of the time-dependent arc voltage revealed differences in the process behaviour for both materials. In the case of aluminium welding, a sharp decline in arc voltage and stabilization and guiding of the anodic arc root was observed whereas in steel welding the arc voltage was slightly increased after the laser beam was switched on. However, significant improvement of the melting efficiency with the combined action of plasma arc and laser beam was achieved for both types of material. Theoretical results of additional numerical simulations of the arc behaviour suggest that the properties of the arc plasma are mainly influenced not by a direct interaction with the laser radiation but by the laser-induced evaporation of metal. Arc stabilization with increased current densities is predicted for moderate rates of evaporated metal only whereas metal vapour rates above a certain threshold causes a destabilization of the arc and reduced current densities along the arc axis.

  16. Coal liquefaction process streams characterization and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  17. Coal liquefaction process streams characterization and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Winschel, R.A.; Brandes, S.D.; Robbins, G.A.; Burke, F.P.

    1991-11-01

    Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  18. Investigation on the stepping arc stud welding process

    Institute of Scientific and Technical Information of China (English)

    Chi Qiang; Zhang Jianxun; Fu Jifei; Zhang Youquan

    2005-01-01

    Through the investigation on traditional arc stud welding process, a new welding gun and its control system were developed in this paper. The stepping arc stud welding gun was mainly made by a stepping motor as actuating unit and a screw-driven device as moving unit. A control system with a MCS-51 single-chip microcomputer as main control component was used to realize the new stud welding procedure. This new welding process with stepping stud welding gun is named as stepping arc stud welding. In the new welding process, the stud action can be looked as constituted by some micro steps. The setting and adjusting of the stepping arc welding gun behavior parameters are accomplished independently. It is indicated from the results of process tests and bending test that the stepping arc stud welding process is practicable.

  19. Coals and coal requirements for the COREX process

    Energy Technology Data Exchange (ETDEWEB)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  20. Titanium or zirconium reduction process by arc heater

    International Nuclear Information System (INIS)

    A process is provided for the reduction of a refractory metal such as zirconium or titanium from its chloride salt. An electric arc is struck in the reaction chamber, and the arc is blown into an elongated arc stream by a pressurized gas. An alkali metal or alkaline earth metal, for instance sodium or magnesium, is fed into the arc stream, as well as a quantity of the metal chloride. The alkali metal or alkaline earth metal chloride thus formed is volatile and separates from the liquid elemental metal, which flows into an associated receptacle

  1. Mechanism of plasma-arc formation of fullerenes from coal and related materials

    Energy Technology Data Exchange (ETDEWEB)

    Pang, L.S.K.; Wilson, M.A.; Quezada, R.A. [CSIRO Petroleum, North Ryde (Australia)] [and others

    1995-12-31

    When an arc is struck across graphite or coal electrodes in a helium atmosphere several products are formed including soot containing fullerenes. The mechanism by which fullerenes and nanotubes are formed is not understood. At arc temperatures exceeding 3000{degrees}C, highly ordered fullerenes might be expected to be less stable than graphite, and hence fullerene production is believed to proceed in cooler regions at the edge of the arc. There is irrefutable evidence that [C{sub 60}]-fullerene grows in a plasma from atomic carbon vapour or equivalent. When {sup 13}C-labelled carbon powder is packed into the anode, the fullerenes as produced contain a statistical distribution of {sup 13}C atoms. This implies that graphite has split into small units, predominantly C{sub 1} or C{sub 2} in the plasma and these units are involved in fullerene formation. When coal or other organic materials are used in the anode, weaker bonds are present, which may break preferentially. As a result, larger fragments, other than C{sub 1} and C{sub 2} units can exist in the plasma. This paper demonstrates the existence of such larger fragments when various coals are used and this implies that fullerenes can be formed from larger units than C{sub 1} and C{sub 2}. The distribution of polycyclic hydrocarbons formed depends very much on the structure of the coal used for the arcing experiments. The distribution of the natural abundance of {sup 13}C/{sup 12}C ratios in the fullerene products further supports this evidence.

  2. Process for electrochemically gasifying coal using electromagnetism

    Science.gov (United States)

    Botts, Thomas E.; Powell, James R.

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  3. Trends in coal gas purification processes

    Energy Technology Data Exchange (ETDEWEB)

    Latysheva, L.A.; Emel' yanova, L.P.; Popova, N.S.; Fritsler, G.S.

    1988-01-01

    Comparatively evaluates processes for coal gas purification developed and used in the GDR, FRG, France, Italy, Japan, USA, UK and other countries. The following processes are discussed: a combined process for hydrogen sulfide and ammonia removal using the USS-FOSAM process, combined removal of hydrogen sulfide and ammonia with ammonia elimination, the Stretford process, the Holmes-Stretford process, the Takahax process, the Fumaks process, the Sulfiban process, the Dimox process, The Otto-Sulfammon and the Phosam process. The following processes of coal tar purification are characterized: absorption-desorption process, oxidation, hydrogen cyanide removal, purification of gases in the Claus process, removal of nitrogen oxides, coal gas cooling and removal of dusts, tar and naphthalene, removal of hydrogen sulfide, ammonia, hydrogen cyanide and nitrogen oxides using absorbents, regeneration processes. The most efficient and economic processes and the companies that developed these processes are characterized. 25 refs.

  4. The slurry-column coal beneficiation process

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, G.F.; Noah, K.S. [Idaho National Engineering Laboratory, Idaho Falls, ID (United States). Biotechnology Dept.

    1997-11-01

    The slurry-column coal beneficiation process is described. It is a second-generation process developed at the Idaho National Engineering Laboratory for the beneficiation of fine (60 mesh x 10 {mu}m) coal by a combination of the physical separation of mineral matter and the biooxidation of pyrite. The bioreactor is slurry-type airlift, specifically designed to allow the large liberated inclusions of pyrite and other insoluble minerals to settle out. They are transferred to a similar reactor, called the rougher/propagator, that gives a second stage of physical separation, as well as the longer residence time for the biodegradation of the large pyritic inclusions and the associated bacterial growth. The bioreactors operate in sequencing-batch mode, and also serve as settlers for coal/water separation when the air turned off. This separation allows counter-current flow of coal and water, which minimizes the volumes of water consumed and wastewater generated. The complete flow sheet incorporates two-stage washing to remove sulfate and bacteria from the product coal, and recycle of bacteria into the process to inoculate the feed coal. A description of the process illustrates some general principles applicable to the optimum design of any coal bioprocess. 17 refs., 5 figs., 2 tabs.

  5. Application of microorganisms in coal cleaning processes

    International Nuclear Information System (INIS)

    A secure energy supply is one of the basic pre-requisites for a sound economic system, sustained standard and quality of life and eventually for the social well-being of each individual. For a progressive country like Pakistan, it is obligatory that all energy options must be pursued vigorously including coal utilization, which given the relatively large resources available, is considered to be one of the major options for the next few hundred years. Bioprocessing of coal in an emerging technology which has started to receive considerable research attention. Recent research activities involving coal cleaning, direct coal conversion, and indirect conversion of coal-derived materials have generated a plethora of facts regarding biochemistry, chemistry, and thermodynamic behavior of coal, in that its bioprocessing is on the verge of becoming and acceptable means to great coals. In this research report, investigations pertaining to the various aspects of coal bio processing, including desulfurization and depyritization are discussed. Bituminous coals varying in total sulfur contents of 3-6% were depyritized more than 90% by mesophilic acidophiles like Thiobacillus ferroxidans and Thiobacillus thio oxidans and thermophilic Sulfolobus brierleyi. The archaebacterium, Sulfolobus brierleyi was found to desulfurize inorganic and organic sulfur components of the coal. Conditions were established under which it can remove more than 30% of the organic sulfur present in the coals. Heterotrophic microorganisms including oxenic and soil isolates were also employed for studying sulfurization. A soil isolate, Oil-2, was found to remove more than 70% dibenzothiophenic sulfur present in an oil-water emulsion (1:20 ratio). Pseudomonas putida and the bacterium oil-2 also remove 60-70% organic sulfur present in the shale-oil. Preliminary results indicate the presence of putatively known Kodama's pathway in the oil-2. The mass balance for sulfate indicated the possibility of the presence

  6. Catalysis questions in chemical processing of coal

    Energy Technology Data Exchange (ETDEWEB)

    Paal, Z.

    1980-01-01

    A brief review is given of the literature in the field of catalytic problems related to the chemical processing of coal. As is known, these processes have become especially significant due to the energy crisis. Existing problems can be divided into two groups: one group is connected with catalytic processing of liquid products of coal destructive hydrogenation (for example, by hydrogenation of coal at high pressures, or by extraction); the other groups is connected with catalytic reactions occurring during the destructive hydrogenation or gasification of coal. Extensive basic research is required in both fields, since certain basic properties of the systems examined are still unknown. The article also gives a brief review of certain new results obtained when studying Fisher-Tropsh reactions and MeOH synthesis.

  7. BENCH SCALE DEVELOPMENT OF MEYERS PROCESS FOR COAL DESULFURIZATION

    Science.gov (United States)

    The report gives results of coal desulfurization experiments to determine the feasibility and advantages of combining gravity separation of coal with chemical desulfurization. The investigations led to the definition of the Gravichem Process, a combination physical/chemical coal ...

  8. A method of realizing visualization research on regional prediction of coal and gas outburst based on ArcView%一种基于ArcView实现瓦斯区域预测可视化的方法

    Institute of Scientific and Technical Information of China (English)

    宋金星; 刘玉芳

    2011-01-01

    Using GIS data processing method and ArcView GIS software,this paper applied coal gas parameters combining with gas geology analysis of method to regional prediction of coal and gas outburst based on spatial data management.ArcView software is executed in sequence five operations,including attaining the affect area of gas outburst point and dynamic phenomenon point,differentiating gas weathered zone,according to the gas pressure or gas content on regional prediction and division,the comprehensive analysis,the isoline analysis,achieved coal and gas outburst dangerous regional prediction.By means of which the 4th coal seam in Shaqv mining ares was divided into coal and gas outburst dangerous area and threatened area,and the danger of coal and gas outburst was assessed and predicted.The visualization managements of coal and gas outburst prediction are achieved,then the accuracy and time effectiveness of gas of coal and gas outburst prediction is improved.%应用煤层瓦斯参数结合瓦斯地质分析的区域预测方法,在空间数据管理的基础上,运用GIS数据处理方法,使用ArcView软件依次进行圈定突出点和动力现象点影响范围、划分煤层瓦斯风化带、根据煤层瓦斯压力或瓦斯含量进行区域预测和划分、综合分析、等值线分析5项操作,实现了煤与瓦斯突出危险性的区域预测,并以沙曲矿4号煤层为例划分煤与瓦斯突出危险区和无突出危险区,对其煤与瓦斯突出危险性做出评估,实现了煤与瓦斯突出预测的可视化管理,提高了瓦斯灾害预测的准确性和时效性.

  9. Thermocatalytical processing of coal and shales

    Directory of Open Access Journals (Sweden)

    Zhaksyntay Kairbekov

    2012-12-01

    Full Text Available The article investigates the questions of thermocatalytical conversion of organic mass of coal (OMC, it is shown that in the absence of a catalyst process is carried out by a radical process. Accumulated data on the properties for radicals of different structure and therefore different reaction capacity enables us to understand and interpret the conversion of OMC. Thermal conversion of OMC regarded as a kind of depolymerization, accompanied by decomposition of the functional groups with the formation of radicals, competing for hydrogen atom. Catalyst can change the direction and conditions of the process. Modern catalysts can reduce the process pressure up to 50 atm., with a high degree of coal conversion. We consider examples of simultaneous conversion of coal and shale, shale and masut, shale and tar.

  10. CLASSIFICATION OF PULSE ARC WELDING PROCESSES

    OpenAIRE

    KRAMPIT A.G.; KRAMPIT N.Y.; KRAMPIT M.A.; DMITRIEVA A.V.

    2012-01-01

    Pulse welding processes improve productivity; also they allow welding of thin sheets of metal without penetration. Splashing and expenses for cleaning surfaces from droplets are also reduced. Pulse welding processes have a wholesome effect on seam formation at the expenses of thermal exposure on welding puddle and HAZ.

  11. Collection of arc welding process data

    OpenAIRE

    K. Luksa; Z. Rymarski

    2006-01-01

    Purpose: The aim of the research was to examine the possibility of detecting welding imperfections by recording the instant values of welding parameters. The microprocessor controlled system for real-time collection and display of welding parameters was designed, implemented and tested.Design/methodology/approach: The system records up to 4 digital or analog signals collected from welding process and displays their run on the LCD display. To disturb the welding process artificial disturbances...

  12. Characteristic parameters of the coal briquetting process

    International Nuclear Information System (INIS)

    The complete knowledge about the energetic sources in our country - Republic of Macedonia, point to the fact that coals are the most attractive and highly productive, still keeping the leadership position. However, the process of lignite exploitation causes their degradation and formation of large amount of fine fractions. The industrial valorization of these fractions is the most actual problem that could be solved only through production of made-up enriched fuels of wide spectrum of application. Thus, briquetting formation, with or without use of binds, is a process of mechanical or combined modification of coal fine fractions. At the same time, this is a possible procedure of solid fuels enrichment. Lignite from the Macedonian coal deposits 'Suvodol', 'Priskupshtina' and 'Brik-Berovo' is analyzed, in order to examine the possibilities of its briquetting. The results show that the 'Suvodol' lignite satisfy the quality requirements given with the MKS B H1.031 standard as well as the 'Brik-Berovo' lignite

  13. Spatial structure of the arc in a pulsed GMAW process

    International Nuclear Information System (INIS)

    A pulsed gas metal arc welding (GMAW) process of steel under argon shielding gas in the globular mode is investigated by measurements and simulation. The analysis is focussed on the spatial structure of the arc during the current pulse. Therefore, the radial profiles of the temperature, the metal vapour species and the electric conductivity are determined at different heights above the workpiece by optical emission spectroscopy (OES). It is shown that under the presence of metal vapour the temperature minimum occurs at the centre of the arc. This minimum is preserved at different axial positions up to 1 mm above the workpiece. In addition, estimations of the electric field in the arc from the measurements are given. All these results are compared with magneto-hydrodynamic simulations which include the evaporation of the wire material and the change of the plasma properties due to the metal vapour admixture in particular. The experimental method and the simulation model are validated by means of the satisfactory correspondence between the results. Possible reasons for the remaining deviations and improvements of the methods which should be aspired are discussed. (paper)

  14. Integrated coal preparation and CWF processing plant

    Energy Technology Data Exchange (ETDEWEB)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. [Science Applications International Corp., McLean, VA (United States)

    1993-12-31

    At the request of the U.S. Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The scale of the coal preparation and CWF plant design chosen for the study is 200 tons per hour coal output on a dry basis (285 tph CWF). The baseline case assumes round-the-clock operation with an annual operating capacity of 83 percent, corresponding to 166 tph dry coal average output or about 1.5 million tons per year. This is equivalent to the energy required to fuel approximately 500 MW of continuous electric generating capacity. (Other approximate equivalencies are 27,000 barrels per day of CWF or three unit trains per week of CWF delivery.) The design and costing are based on a battery-limit, integrated plant located at or near a coal mine site. As such, it is assumed that roads, rail lines, electric service, water access, auxiliaries, etc., will be available. Also, no provision is made for raw coal storage, since coal storage is assumed to be part of the mining operation. CWF delivery can be by rail, barge or pipeline. The normal operating mode is assumed to the out-loading of CWF directly into unit trains made up of rail tank cars. Storage is provided for two days production of CWF. Costs for off-site disposal of dewatered refuse are included in the final cost figure. The CWF type at which the study was directed is a boiler grade fuel intended to be burned in utility or large industrial units.

  15. Nuclear process heat - application to coal gasification

    International Nuclear Information System (INIS)

    The high temperature gas cooled reactor has achieved peak coolant temperatures from 775 to 9500C, depending on the core design. These temperatures are sufficiently high to consider the HTR as a source of heat for several large industrial processes. In this article the application is to a coal gasification process which produces a mixture of carbon monoxide and hydrogen as the key product. The gasifier system itself is coupled to the HTR via a catalyzed bed coal gasifier operating at 7000C and producing methane. The feed to this gasifier is a mixture of carbon monoxide, hydrogen and steam with the stoichiometry chosen to effect an overall athermal reaction so that no heat is directly transferred into the gasifier. Its hydrogen supply is generated by steam reforming the methane produced using the direct HTR heat. This indirect system has advantages in terms of its final product, indirect heat transer and ultimately in the savings of approximately 40% of the coal which would otherwise have been assumed in an all-coal process producing the same final product. (orig.)

  16. Comparison between open phase fault of arc suppression coil and single phase to earth fault in coal mine distribution network

    Institute of Scientific and Technical Information of China (English)

    LI Xiao-bo; WANG Chong-lin

    2008-01-01

    When, in a coal mine distribution network whose neutral point is grounded by an arc suppression coil (ASC), a fault occurs in the ASC, compensation cannot be properly realized. Furthermore, it can damage the safe and reliable run of the network.We first introduce a three-phase five-column arc suppression coil (TPFCASC) and discuss its autotracking compensation theory.Then we compare the single phase to ground fault of the coal mine distribution network with an open phase fault at the TPFCASC using the Thévenin theory, the symmetrical-component method and the complex sequence network respectively. The results show that, in both types of faults, zero-sequence voltage of the network will appear and the maximum magnitude of this zero-sequence voltage is different in both faults. Based on this situation, a protection for the open phase fault at the TPFCASC should be estab-lished.

  17. In process acoustic emission in multirun submerged arc welding

    International Nuclear Information System (INIS)

    In order to avoid the formation of deep grooves when repairing defects in welded joints in heavy plates, an investigation was made aiming to detect and locate the defects by in-process acoustic emission in multirun submerged arc welding. Twelve defects (lack of penetration, cracks, inclusions, lack of fusion together with inclusions, blowholes) were intentionally introduced when the first plate was welded. A space-time method for processing the acoustic activity during welding allowed the detection and the location of the intentional defects as well as of the most important accidental defects evidenced by ultrasonic testing

  18. PROCESS IMPROVEMENT STUDIES ON THE BATTELLE HYDROTHERMAL COAL PROCESS

    Science.gov (United States)

    The report gives results of a study to improve the economic viability of the Battelle Hydrothermal (HT) Coal Process by reducing the costs associated with liquid/solid separation and leachant regeneration. Laboratory experiments were conducted to evaluate process improvements for...

  19. The concept substantiation of selected technologies on deep coal processing

    International Nuclear Information System (INIS)

    Present article is devoted to concept substantiation of selected technologies on deep coal processing. The basic aspects of coal gasification were studied. The selection state of optimal technology of coal gasification was considered. The optimal technologies of gas processing were proposed.

  20. Geology Arc Export Layer From Coal Bearing Geology of the Gulf Coast Coal Region (gulf_geol_dd.e00)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset is a polygon vector coverage of coal bearing geologic units that occur in states which comprise the Gulf Coast Coal Assessment Region as defined by the...

  1. Advanced Coal Conversion Process Demonstration: A DOE Assessment

    Energy Technology Data Exchange (ETDEWEB)

    National Energy Technology Laboratory

    2005-04-01

    The objective of this project was to demonstrate a process for upgrading subbituminous coal by reducing its moisture and sulfur content and increasing its heating value using the Advanced Coal Conversion Process (ACCP) unit. The ACCP unit, with a capacity of 68.3 tons of feed coal per hour (two trains of 34 tons/hr each), was located next to a unit train loading facility at WECo's Rosebud Coal Mine near Colstrip, Montana. Most of the coal processed was Rosebud Mine coal, but several other coals were also tested. The SynCoal® produced was tested both at utilities and at several industrial sites. The demonstration unit was designed to handle about one tenth of the projected throughput of a commercial facility.

  2. High-Btu coal gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    Blazek, C.F.; Baker, N.R.; Tison, R.R.

    1979-01-01

    This evaluation provides estimates of performance and cost data for advanced technology, high-Btu, coal gasification facilities. The six processes discussed reflect the current state-of-the-art development. Because no large commercial gasification plants have yet been built in the United States, the information presented here is based only on pilot-plant experience. Performance characteristics that were investigated include unit efficiencies, product output, and pollution aspects. Total installed plant costs and operating costs are tabulated for the various processes. The information supplied here will assist in selecting energy conversion units for an Integrated Community Energy System (ICES).

  3. Study on Expansion Process of EDM Arc Plasma

    Science.gov (United States)

    Natsu, Wataru; Shimoyamada, Mayumi; Kunieda, Masanori

    In order to understand the phenomena of electrical discharge machining (EDM), the characteristics of transition arc plasma in EDM were investigated. The arc plasma was directly observed with a high speed video camera. In addition, to learn more about arc plasma expansion, plasma temperature was measured by spectroscopy. The arc plasma temperature was obtained by measuring the radiant fluxes of two different wavelengths from the arc plasma and applying the line pair method. Furthermore, a new expansion model for EDM arc plasma was proposed based on the observations, and validated by comparing experimental and computed results of the discharge crater.

  4. Survey and evaluation of current and potential coal beneficiation processes

    Energy Technology Data Exchange (ETDEWEB)

    Singh, S. P.N.; Peterson, G. R.

    1979-03-01

    Coal beneficiation is a generic term used for processes that prepare run-of-mine coal for specific end uses. It is also referred to as coal preparation or coal cleaning and is a means of reducing the sulfur and the ash contents of coal. Information is presented regarding current and potential coal beneficiation processes. Several of the processes reviewed, though not yet commercial, are at various stages of experimental development. Process descriptions are provided for these processes commensurate with the extent of information and time available to perform the evaluation of these processes. Conceptual process designs, preliminary cost estimates, and economic evaluations are provided for the more advanced (from a process development hierarchy viewpoint) processes based on production levels of 1500 and 15,000 tons/day (maf) of cleaned product coal. Economic evaluations of the coal preparation plants are conducted for several project financing schemes and at 12 and 15% annual after-tax rates of return on equity capital. A 9% annual interest rate is used on the debt fraction of the plant capital. Cleaned product coal prices are determined using the discounted cash flow procedure. The study is intended to provide information on publicly known coal beneficiation processes and to indicate the relative costs of various coal beneficiation processes. Because of severe timeconstraints, several potential coal beneficiation processes are not evaluated in great detail. It is recommended that an additional study be conducted to complement this study and to more fully appreciate the potentially significant role of coal beneficiation in the clean burning of coal.

  5. Robustness studies on coal gasification process variables

    Directory of Open Access Journals (Sweden)

    RLJ Coetzer

    2004-12-01

    Full Text Available Optimisation of the Sasol-Lurgi gasification process was carried out by utilising the method of Factorial Experimental Design on the process variables of interest from a specifically equipped full-scale test gasifier. The process variables that govern gasification are not always fully controllable during normal operation. This paper discusses the application of statistical robustness studies as a method for determining the most efficient combination of process variables that might be hard-to-control during normal operation. Response surface models were developed in the process variables for each of the performance variables. It will be shown how statistical robustness studies provided the optimal conditions for sustainable gasifier operability and throughput. In particular, the optimum operability region is significantly expanded towards higher oxygen loads by changing and controlling the particle size distribution of the coal.

  6. Coal liquefaction process research quarterly report, October-December 1979

    Energy Technology Data Exchange (ETDEWEB)

    Bickel, T.C.; Curlee, R.M.; Granoff, B.; Stohl, F.V.; Thomas, M.G.

    1980-03-01

    This quarterly report summarizes the activities of Sandia's continuing program in coal liquefaction process research. The overall objectives are to: (1) provide a fundamental understanding of the chemistry of coal liquefaction; (2) determine the role of catalysts in coal liquefaction; and (3) determine the mechanism(s) of catalyst deactivation. The program is composed of three major projects: short-contact-time coal liquefaction, mineral effects, and catalyst studies. These projects are interdependent and overlap significantly.

  7. Numerical analysis of arc plasma behaviour during contact opening process in low-voltage switching device

    International Nuclear Information System (INIS)

    This paper focuses on the numerical investigation of low-voltage arc plasma behaviour with the contact opening process included. A flexible experimental setup with a rotating contact is designed to support this study. Based on the magnetohydrodynamic arc model, the elongation and the commutation behaviour of the arc plasma during the contact rotation progress are simulated. Under the given conditions of the external magnetic field and the contact rotating velocity, the arc motion is described in detail by the temperature distribution. The stagnation together with the following rapid jump of two arc roots is observed by both calculation and experiment. The rapid rise in the arc voltage is mainly caused by the increasing difference between the two arc roots displacement in the moving direction, and the jump instant of the arc root on the moving contact is according to the moment of the maximal voltage value

  8. The variable polarity plasma arc welding process: Characteristics and performance

    Science.gov (United States)

    Hung, R. J.; Zhu, G. J.

    1991-01-01

    Significant advantages of the Variable Polarity Plasma Arc (VPPA) Welding Process include faster welding, fewer repairs, less joint preparation, reduced weldment distortion, and absence of porosity. The power distribution was analyzed for an argon plasma gas flow constituting the fluid in the VPPA Welding Process. The major heat loss at the torch nozzle is convective heat transfer; in the space between the outlet of the nozzle and the workpiece; radiative heat transfer; and in the keyhole in the workpiece, convective heat transfer. The power absorbed at the workpiece produces the molten puddle that solidifies into the weld bead. Crown and root widths, and crown and root heights of the weld bead are predicted. The basis is provided for an algorithm for automatic control of VPPA welding machine parameters to obtain desired weld bead dimensions.

  9. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

    2006-08-01

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

  10. High resolution processing of 3D seismic data for thin coal seam in Guqiao coal mine

    Science.gov (United States)

    Li, Qiaoling; Peng, Suping; Zou, Guangui

    2015-04-01

    Accurate identification of small faults for coal seams is very important for coal-field exploration, which can greatly improve mining efficiency and safety. However, coal seams in China are mostly thin layers, ranging from 2-5 m. Moreover, the shallow coal seam with strong reflection forms a shield underneath thin coal seam which is only about 40 m deeper. This causes great difficulty in seismic processing and interpretation. The primary concern is to obtain high-resolution seismic image of underneath thin coal seam for mining safety. In this paper, field data is carefully analyzed and fit-for-purpose solutions are adopted in order to improve the quality of reprocessed data and resolution of target coal seam. Identification of small faults has been enhanced significantly.

  11. Fuel production from coal by the Mobil Oil process using nuclear high-temperature process heat

    International Nuclear Information System (INIS)

    Two processes for the production of liquid hydrocarbons are presented: Direct conversion of coal into fuel (coal hydrogenation) and indirect conversion of coal into fuel (syngas production, methanol synthesis, Mobil Oil process). Both processes have several variants in which nuclear process heat may be used; in most cases, the nuclear heat is introduced in the gas production stage. The following gas production processes are compared: LURGI coal gasification process; steam reformer methanation, with and without coal hydrogasification and steam gasification of coal. (orig./EF)

  12. Experimental investigation of energy balance in plasma arc cutting process

    Czech Academy of Sciences Publication Activity Database

    Kavka, Tetyana; Tossens, S.; Mašláni, Alan; Konrád, Miloš; Pauser, H.; Stehrer, T.

    Vol. 511. Bristol: IOP Publishing, 2014, 012067-012067. (IoP. 511). ISSN 1742-6588. [International Congress on Plasma Physics (ICPP) / 13th Latin American Workshop on Plasma Physics (LAWPP)/15./. Santiago, CHILE (CL), 08.08.2010-13.08.2010] Institutional support: RVO:61389021 Keywords : plasma arc cutting * arc cutting * plasma arc Subject RIV: BL - Plasma and Gas Discharge Physics http://iopscience.iop.org/1742-6596/511/1/012067/pdf/1742-6596_511_1_012067.pdf

  13. Radiant-and-plasma technology for coal processing

    Directory of Open Access Journals (Sweden)

    Vladimir Messerle

    2012-12-01

    Full Text Available Radiant-and-plasma technology for coal processing is presented in the article. Thermodynamic computation and experiments on plasma processing of bituminous coal preliminary electron-beam activated were fulfilled in comparison with plasma processing of the coal. Positive influence of the preliminary electron-beam activation of coal on synthesis gas yield was found. Experiments were carried out in the plasma gasifier of 100 kW power. As a result of the measurements of material and heat balance of the process gave the following integral indicators: weight-average temperature of 2200-2300 K, and carbon gasification degree of 82,4-83,2%. Synthesis gas yield at thermochemical preparation of raw coal dust for burning was 24,5% and in the case of electron-beam activation of coal synthesis gas yield reached 36,4%, which is 48% higher.

  14. Underground Coal Gasification: Rates of Post Processing Gas Transport

    OpenAIRE

    Soukup, K.; Hejtmánek, V. (Vladimír); Stanczyk, K.; Šolcová, O.

    2014-01-01

    Two ex-situ and one in-situ semi-pilot plant UCG experiments in the experimental mine Barbara were performed with hard coal and lignite samples. To evaluate the influence of the UCG process on the textural properties of surrounding strata and coals, samples from various locations of the coal seam and the stratum samples before and after the UCG process were collected. Mercury porosimetry, helium pycnometry, and physical adsorption of nitrogen were used for the determination of textural proper...

  15. New progress in the processing and efficient utilization of coal

    Institute of Scientific and Technical Information of China (English)

    Zhao Yuemin; Liu Jiongtian; Wei Xianyong; Luo Zhenfu; Chen Qingru; Song Shulei

    2011-01-01

    Coal accounts for about 70% of the primary energy sources in China.The environmental pollution and resources waste involved with coal processing and utilization are serious.It is therefore urgent to develop highly-efficient coal resources utilization theory and methods with low-carbon discharge.Based on our long-term basic research and technology development,the progress in beneficiation,cleaning,and transformation of coal,which includes dense phase fluidized bed dry beneficiation,deep screening of wet fine coal,micro-bubble flotation column separation,molecular coal chemistry,and transformation and separation of coal and its derivatives into value-added chemicals under mild conditions,is discussed.

  16. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1991-01-01

    The objective of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines.

  17. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  18. Clean Processing and Utilization of Coal Energy

    Institute of Scientific and Technical Information of China (English)

    陈如清; 王海峰

    2006-01-01

    The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal, low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning, which is a highly efficient, clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.

  19. Processes of energy exchange between blasted electric arc and surrounding gas in arc heater channel

    Czech Academy of Sciences Publication Activity Database

    Heinz, J.; Šenk, J.; Hrabovský, Milan

    2002-01-01

    Roč. 52, supplement D (2002), s. 583. ISSN 0011-4626. [Symposium on Plasma Physics and Technology/20th./. Prague, 10.06.2002-13.06.2002] Institutional research plan: CEZ:AV0Z2043910 Keywords : electric arc , energy exchance, heater Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.311, year: 2002

  20. Analysis of hybrid Nd:Yag laser-MAG arc welding processes.

    OpenAIRE

    Le Guen, Emilie; Fabbro, Rémy; CARIN, Muriel; Coste, Frédéric; LE MASSON, Philippe

    2011-01-01

    In the hybrid laser-arc welding process, a laser beam and an electric arc are coupled in order to combine the advantages of both processes: high welding speed, low thermal load and high depth penetration thanks to the laser; less demanding on joint preparation/fit-up, typical of arc welding. So the hybrid laser-MIG/MAG (Metal Inert or Active Gas) arc welding has very interesting properties: the improvement of productivity results in higher welding speeds, thicker welded materials, joint fit-u...

  1. Contrasting sedimentary processes along a convergent margin: the Lesser Antilles arc system

    Science.gov (United States)

    Picard, Michel; Schneider, Jean-Luc; Boudon, Georges

    2006-12-01

    Sedimentation processes occurring in an active convergent setting are well illustrated in the Lesser Antilles island arc. The margin is related to westward subduction of the North and/or the South America plates beneath the Caribbean plate. From east to west, the arc can be subdivided into several tectono-sedimentary depositional domains: the accretionary prism, the fore-arc basin, the arc platform and inter-arc basin, and the Grenada back-arc basin. The Grenada back-arc basin, the fore-arc basin (Tobago Trough) and the accretionary prism on the east side of the volcanic arc constitute traps for particles derived from the arc platform and the South American continent. The arc is volcanically active, and provides large volumes of volcaniclastic sediments which accumulate mainly in the Grenada basin by volcaniclastic gravity flows (volcanic debris avalanches, debris flows, turbiditic flows) and minor amounts by fallout. By contrast, the eastern side of the margin is fed by ash fallout and minor volcaniclastic turbidites. In this area, the dominant component of the sediments is pelagic in origin, or derived from South America (siliciclastic turbidites). Insular shelves are the locations of carbonate sedimentation, such as large platforms which develop in the Limestone Caribbees in the northern part of the margin. Reworking of carbonate material by turbidity currents also delivers lesser amounts to eastern basins of the margin. This contrasting sedimentation on both sides of the arc platform along the margin is controlled by several interacting factors including basin morphology, volcanic productivity, wind and deep-sea current patterns, and sea-level changes. Basin morphology appears to be the most dominant factor. The western slopes of the arc platform are steeper than the eastern ones, thus favouring gravity flow processes.

  2. Removal of mercury from coal via a microbial pretreatment process

    Science.gov (United States)

    Borole, Abhijeet P.; Hamilton, Choo Y.

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  3. Flotation process diagnostics and modelling by coal grain analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ofori, P; O' Brien, G.; Firth, B.; Jenkins, B. [CSIRO Energy Technology, Brisbane, Qld. (Australia)

    2006-05-15

    In coal flotation, particles of different components of the coal such as maceral groups and mineral matter and their associations have different hydrophobicities and therefore different flotation responses. By using a new coal grain analysis method for characterising individual grains, more detailed flotation performance analysis and modelling approaches have been developed. The method involves the use of microscopic imaging techniques to obtain estimates of size, compositional and density information on individual grains of fine coal. The density and composition partitioning of coal processed through different flotation systems provides an avenue to pinpoint the actual cause of poor process performance so that corrective action may be initiated. The information on grain size, density and composition is being used as input data to develop more detailed flotation process models to provide better predictions of process performance for both mechanical and column flotation devices. A number of approaches may be taken to flotation modelling such as the probability approach and the kinetic model approach or a combination of the two. In the work reported here, a simple probability approach has been taken, which will be further refined in due course. The use of grain data to map the responses of different types of coal grains through various fine coal cleaning processes provided a more advanced diagnostic capability for fine coal cleaning circuits. This enabled flotation performance curves analogous to partition curves for density separators to be produced for flotation devices.

  4. Approximate entropy--a new statistic to quantify arc and welding process stability in short-circuiting gas metal arc welding

    Institute of Scientific and Technical Information of China (English)

    Cao Biao; Xiang Yuan-Peng; Lü Xiao-Qing; Zeng Min; Huang Shi-Sheng

    2008-01-01

    Based on the phase state reconstruction of welding current in short-circuiting gas metal arc welding using carbon dioxide as shielding gas, the approximate entropy of welding current as well as its standard deviation has been calculated and analysed to investigate their relation with the stability of electric arc and welding process. The extensive experimental and calculated results show that the approximate entropy of welding current is significantly and positively correlated with arc and welding process stability, whereas its standard deviation is correlated with them negatively. A larger approximate entropy and a smaller standard deviation imply a more stable arc and welding process, and vice versa. As a result, the approximate entropy of welding current promises well in assessing and quantifying the stability of electric arc and welding process in short-circuiting gas metal arc welding.

  5. Dynamic processes and kinetic theory of plasma fluctuations: ARCS3

    International Nuclear Information System (INIS)

    Dynamic processes on the ARCS3 fight involve six related coordinate systems: Rocket System, Local Geographic System, Local Geomagnetic System, Global Geographic System, Wave Vector System and Artificial Argon Beam System. The present thesis has found the relationships needed to carry out coordinate transformations between all these six coordinate systems. These coordinate transformations are used to investigate ion trajectories and the directional response of the detector OCTO4. A technique to calculate the 3-component acceleration of the main payload was completed, and the trajectory of the main payload relative to the sub payload was given. A method to use the measured spin plane component of the electric field vector to construct the full 3 dimensional electric field vector in the Local Geomagnetic System has been provided. A model to simulate the artificial argon beam distribution is proposed, and used to calculate the beam's flux, density and evolution. Several kinds of plasma waves were observed by the University of Minnesota ACE detector. To explain the wave observations, a kinetic theory of plasma fluctuations was developed. This theory includes magnetized plasma species with or without parallel streaming. It is also valid for plasma including an unmagnetized two temperature plasma species that is streaming in any direction. As an application of the theory, the thermal fluctuations of the O+ acoustic wave mode was calculated and compared with observations. The O+ - He+ bihybrid mode is also evaluated and compared with the observed wave spectra

  6. Workplace exposure to nanoparticles from gas metal arc welding process

    International Nuclear Information System (INIS)

    Workplace exposure to nanoparticles from gas metal arc welding (GMAW) process in an automobile manufacturing factory was investigated using a combination of multiple metrics and a comparison with background particles. The number concentration (NC), lung-deposited surface area concentration (SAC), estimated SAC and mass concentration (MC) of nanoparticles produced from the GMAW process were significantly higher than those of background particles before welding (P < 0.01). A bimodal size distribution by mass for welding particles with two peak values (i.e., 10,000–18,000 and 560–320 nm) and a unimodal size distribution by number with 190.7-nm mode size or 154.9-nm geometric size were observed. Nanoparticles by number comprised 60.7 % of particles, whereas nanoparticles by mass only accounted for 18.2 % of the total particles. The morphology of welding particles was dominated by the formation of chain-like agglomerates of primary particles. The metal composition of these welding particles consisted primarily of Fe, Mn, and Zn. The size distribution, morphology, and elemental compositions of welding particles were significantly different from background particles. Working activities, sampling distances from the source, air velocity, engineering control measures, and background particles in working places had significant influences on concentrations of airborne nanoparticle. In addition, SAC showed a high correlation with NC and a relatively low correlation with MC. These findings indicate that the GMAW process is able to generate significant levels of nanoparticles. It is recommended that a combination of multiple metrics is measured as part of a well-designed sampling strategy for airborne nanoparticles. Key exposure factors, such as particle agglomeration/aggregation, background particles, working activities, temporal and spatial distributions of the particles, air velocity, engineering control measures, should be investigated when measuring workplace

  7. The Influence of Contact Space on Arc Commutation Process in Air Circuit Breaker

    Science.gov (United States)

    Niu, Chunping; Ding, Juwen; Yang, Fei; Dong, Delong; Rong, Mingzhe; Xu, Dan

    2016-05-01

    In this paper, a 3D magneto-hydrodynamic (MHD) arc simulation model is applied to analyze the arc motion during current interruption in a certain air circuit breaker (ACB). The distributions of pressure, temperature, gas flow and current density of the arc plasma in the arc region are calculated, and the factors influencing the commutation process are analyzed according to the calculated results. Based on the airflow in the arc chamber, the causes of arc commutation asynchrony and the back commutation are investigated. It indicates that a reasonable contact space design is crucial to a successful arc commutation process. To verify the simulation results, the influence of contact space on arc voltage and arc commutation is tested. This research can provide methods and references to the optimization of ACB design. supported by National Key Basic Research Program of China (973 Program) (Nos. 2015CB251002, 6132620303) and National Natural Science Foundation of China (Nos. 51221005, 51377128, 51577144), and Science and Technology Project Through Grid State Corporation (No. SGSNKYOOKJJS1501564)

  8. Modified IRC bench-scale arc melter for waste processing

    International Nuclear Information System (INIS)

    This report describes the INEL Research Center (IRC) arc melter facility and its recent modifications. The arc melter can now be used to study volatilization of toxic and high vapor pressure metals and the effects of reducing and oxidizing (redox) states in the melt. The modifications include adding an auger feeder, a gas flow control and monitoring system, an offgas sampling and exhaust system, and a baghouse filter system, as well as improving the electrode drive, slag sampling system, temperature measurement and video monitoring and recording methods, and oxidation lance. In addition to the volatilization and redox studies, the arc melter facility has been used to produce a variety of glass/ceramic waste forms for property evaluation. Waste forms can be produced on a daily basis. Some of the melts performed are described to illustrate the melter's operating characteristics

  9. Experimental study of anode processes in plasma arc cutting

    Czech Academy of Sciences Publication Activity Database

    Kavka, Tetyana; Chumak, Oleksiy; Šonský, Jiří; Heinrich, M.; Stehrer, T.; Pauser, H.

    2013-01-01

    Roč. 46, č. 6 (2013), 065202-065202. ISSN 0022-3727 R&D Projects: GA ČR GAP205/11/2070 Institutional support: RVO:61389021 ; RVO:61388998 Keywords : Arc cutting * anode attachment * pilot arc * steam plasma cutting * torch * fluctuations * JET Subject RIV: BL - Plasma and Gas Discharge Physics; BL - Plasma and Gas Discharge Physics (UT-L) Impact factor: 2.521, year: 2013 http://iopscience.iop.org/0022-3727/46/6/065202/pdf/0022-3727_46_6_065202.pdf

  10. One-knob self-optimizing fuzzy control of CO2 arc welding process

    Institute of Scientific and Technical Information of China (English)

    俞建荣; 蒋力培

    2002-01-01

    A new one-knob self-optimizing fuzzy control system of CO2 arc welding is established based on the synthetic performance evaluation of droplet transfer process. It includes two kinds of self-optimizing fuzzy controllers: the arc voltage controller and the current waveform controller. The fuzzy control principle and the key points of the control patterns are presented. Through on-line detecting, computing of characteristic parameters and one-knob self-optimizing adjusting, the characteristic parameters and welding variables can be adjusted to suitable ranges under the control of the arc voltage controller. Meanwhile the current waveform controller is active in the rear-time stage of the short-circuiting and the instant of re-triggering arc. The experiment results show that the control and its algorithm can improve the synthetic performance of arc welding process apparently.

  11. Experimental Investigation of Energy Balance in Plasma Arc Cutting Process

    Czech Academy of Sciences Publication Activity Database

    Kavka, Tetyana; Tossens, S.; Mašláni, Alan; Konrád, Miloš; Pauser, G.; Stehrer, T.

    Santiago : The Pontificia Universidad Católica de Chile, 2010. s. 41-41. ISBN N. [Fifteenth International Congress on Plasma Physics (ICPP2010) and Thirteenth American Workshop on Plasma Physics (LAWPP). 08.08.2010-13.08.2010, Santiago] Institutional research plan: CEZ:AV0Z20430508 Keywords : plasma arc cutting * energy balance Subject RIV: BL - Plasma and Gas Discharge Physics

  12. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be

  13. Analysis of chemical coal cleaning processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-01

    Six chemical coal cleaning processes were examined. Conceptual designs and costs were prepared for these processes and coal preparation facilities, including physical cleaning and size reduction. Transportation of fine coal in agglomerated and unagglomerated forms was also discussed. Chemical cleaning processes were: Pittsburgh Energy Technology Center, Ledgemont, Ames Laboratory, Jet Propulsion Laboratory (two versions), and Guth Process (KVB). Three of the chemical cleaning processes are similar in concept: PETC, Ledgemont, and Ames. Each of these is based on the reaction of sulfur with pressurized oxygen, with the controlling factor being the partial pressure of oxygen in the reactor. All of the processes appear technically feasible. Economic feasibility is less certain. The recovery of process chemicals is vital to the JPL and Guth processes. All of the processes consume significant amounts of energy in the form of electric power and coal. Energy recovery and increased efficiency are potential areas for study in future more detailed designs. The Guth process (formally designed KVB) appears to be the simplest of the systems evaluated. All of the processes require future engineering to better determine methods for scaling laboratory designs/results to commercial-scale operations. A major area for future engineering is to resolve problems related to handling, feeding, and flow control of the fine and often hot coal.

  14. Numerical Simulation of the Eddy Current Effects on the Arc Splitting Process

    International Nuclear Information System (INIS)

    This paper focuses on a numerical simulation of the arc plasma behavior in the arc splitting process, considering the eddy currents in the electrodes and the splitter plate. Based on three-dimensional (3D) magneto-hydrodynamic (MHD) theory, a thin layer of nonlinear electrical resistance elements is used in the model to represent the voltage drop of plasma sheath and the formation of new arc root in order to include the arc splitting process in the simulation. In the arcing process, eddy currents in metal parts are generated by a time-varying magnetic field. The arc model is calculated with the time-varying magnetic field term, so that the eddy current effects can be considered. The effect of nonlinear permeability of a ferromagnetic material is also involved in the calculation. Using the simulation results for the temperature, velocity and current density distribution, the arc splitting process is analyzed in detail. The calculated results are compared with the simulation neglecting eddy currents. (low temperature plasma)

  15. Numerical Simulation of the Eddy Current Effects on the Arc Splitting Process

    Institute of Scientific and Technical Information of China (English)

    杨飞; 荣命哲; 吴翊; 孙昊; 马瑞光; 纽春萍

    2012-01-01

    This paper focuses on a numerical simulation of the arc plasma behavior in the arc splitting process, considering the eddy currents in the electrodes and the splitter plate. Based on three-dimensional (3D) magneto-hydrodynamic (MHD) theory, a thin layer of nonlinear electrical resistance elements is used in the model to represent the voltage drop of plasma sheath and the formation of new arc root in order to include the arc splitting process in the simulation. In the arcing process, eddy currents in metal parts are generated by a time-varying magnetic field. The arc model is calculated with the time-varying magnetic field term, so that the eddy current effects can be considered. The effect of nonlinear permeability of a ferromagnetic material is also involved in the calculation. Using the simulation results for the temperature, velocity and current density distribution, the arc splitting process is analyzed in detail. The calculated results are compared with the simulation neglecting eddy currents.

  16. The Main Plasma Chemical Process of Nitric Oxide Production by Arc Discharge

    Science.gov (United States)

    Yang, Qi; Hu, Hui; Chen, Weipeng; Xu, Jie; Zhang, Jinli; Wu, Shuang

    2011-12-01

    By adopting the optical multi-channel analyzer combined with fourier transform infrared (FTIR) spectrometer, the dominant free radicals and products generated by arc discharge were measured and studied, and the main plasma chemical reaction process in the nitric oxide production by arc discharge was identified. Plasma chemical kinetic curves of O, O2, N2, N and NO were simulated by using CHEMKIN and MATLAB. The results show that the main plasma chemical reaction process of nitric oxide production by arc discharge is a replacement reaction between O and N2, where NO can be generated instantaneously when discharging reaches stable.

  17. The Main Plasma Chemical Process of Nitric Oxide Production by Arc Discharge

    International Nuclear Information System (INIS)

    By adopting the optical multi-channel analyzer combined with fourier transform infrared (FTIR) spectrometer, the dominant free radicals and products generated by arc discharge were measured and studied, and the main plasma chemical reaction process in the nitric oxide production by arc discharge was identified. Plasma chemical kinetic curves of O, O2, N2, N and NO were simulated by using CHEMKIN and MATLAB. The results show that the main plasma chemical reaction process of nitric oxide production by arc discharge is a replacement reaction between O and N2, where NO can be generated instantaneously when discharging reaches stable. (15th asian conference on electrical discharge)

  18. Use of the GranuFlow Process in Coal Preparation Plants to Improve Energy Recovery and Reduce Coal Processing Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Glenn A. Shirey; David J. Akers

    2005-12-31

    With the increasing use of screen-bowl centrifuges in today's fine coal cleaning circuits, a significant amount of low-ash, high-Btu coal can be lost during the dewatering step due to the difficulty in capturing coal of this size consist (< 100 mesh or 0.15mm). The GranuFlow{trademark} technology, developed and patented by an in-house research group at DOE-NETL, involves the addition of an emulsified mixture of high-molecular-weight hydrocarbons to a slurry of finesized coal before cleaning and/or mechanical dewatering. The binder selectively agglomerates the coal, but not the clays or other mineral matter. In practice, the binder is applied so as to contact the finest possible size fraction first (for example, froth flotation product) as agglomeration of this fraction produces the best result for a given concentration of binder. Increasing the size consist of the fine-sized coal stream reduces the loss of coal solids to the waste effluent streams from the screen bowl centrifuge circuit. In addition, the agglomerated coal dewaters better and is less dusty. The binder can also serve as a flotation conditioner and may provide freeze protection. The overall objective of the project is to generate all necessary information and data required to commercialize the GranuFlow{trademark} Technology. The technology was evaluated under full-scale operating conditions at three commercial coal preparation plants to determine operating performance and economics. The handling, storage, and combustion properties of the coal produced by this process were compared to untreated coal during a power plant combustion test.

  19. Influence of flux-cored wire composition on arc combustion process stability in wet underwater welding

    OpenAIRE

    Kakhovskyi, Mykola Yu.; Maksimov, Serhii Yu.

    2015-01-01

    The components-stabilizers, which increase the stability of the arc combustion process have been investigated. The aim of research was to introduce the components-stabilizers in the welding wire to determine the component which provides the most optimal stability process of the arc combustion. The welding wire characteristics were experimentally studied. They are the quantity of short circuits, the deviations of current and the voltage and nature of the electrode metal transfer. The most stab...

  20. Arc magmatic chemistry: The source versus process debate

    International Nuclear Information System (INIS)

    Most geochemical studies of arcs world-wide easily demonstrate mixing trends in isotope-isotope space that originate with a MORB component. A slab-derived and possible hydrous fluid-dominated component is also well defined in some studies. This is best observed in arcs in which the magmas are otherwise highly lithophile-element poor, such as the Tonga-Kermadec arc. This component is only moderately LIL element-enriched with very high 87Sr/86Sr and 207Pb/204Pb ratios, low Ce/Pb and low'143Nd/144Nd. It is also characterised by high U/Th and with U-series disequilibrium to the right of the equiline. A third and important geochemical vector is one particularly recognised in arcs in complex tectonic settings in the Mediterranean, the Aegean and in Indonesia and is one which leads to the development of K20-rich suites. Features include silica-undersaturation, very high K/Nb, Ba/Nb and Ce/Y with 87Sr/86Sr values which are moderately low at moderately low 143Nd/144Nd values. On 87Sr/86Sr versus 143Nd/'144Nd diagrams these show mixing lines towards a significantly less radiogenic Sr end member than the MORB-sediment mixture. Magmas enriched in this component don't tend to show U-series disequilibrium and have low 230Th/232Th and 238U values. They appear to have κTH values that reflect a source with a long term history of high Th/U. The Nd- and Sr-isotopic characteristics imply a source with a moderately long history of LREE enrichment at moderate Rb/Sr and U/Pb

  1. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

    2006-05-12

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

  2. Utilization of chemical looping strategy in coal gasification processes

    Institute of Scientific and Technical Information of China (English)

    Liangshih Fan; Fanxing Li; Shwetha Ramkumar

    2008-01-01

    Three chemical looping gasification processes, i. e. Syngas Chemical Looping (SCL) process, Coal Direct Chemical Looping (CDCL) process, and Calcium Looping process (CLP), are being developed at the Ohio State University (OSU). These processes utilize simple reaction schemes to convert carbonaceous fuels into products such as hydrogen, electricity, and synthetic fuels through the transformation of a highly reactive, highly recyclable chemical intermediate. In this paper, these novel chemical looping gasification processes are described and their advantages and potential challenges for commercialization are discussed.

  3. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    Energy Technology Data Exchange (ETDEWEB)

    K. Osseo-Asare; X. Zeng

    2002-01-01

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  4. Complex technology of vacuum-arc processing of structural material surface

    Science.gov (United States)

    Arustamov, V. N.; Ashurov, Kh. B.; Kadyrov, Kh. Kh.; Khudoikulov, I. Kh.

    2015-08-01

    The development of environmentally friendly and energy-resource-saving technologies based on vacuum arc discharge is a topical problem in science and engineering. In view of their unique properties, cathode spots of a vacuum arc induce cleaning of the surface of an article (cathode) from various contaminations and pulsed thermal action on the surface layers. These processes occur in complex with vacuum-arc deposition of coatings in the same technological cycle, which makes it possible to considerably increase the efficiency of methods for changing physical, mechanical, and chemical properties of the surface of steel articles, which considerably increase their service life. Analysis of the formation of the temperature regime of the surface during vacuum arc action and of the parameters of the deposited coating will make it possible to optimize the regimes of complex treatment of the surfaces of articles and is of considerable theoretical and practical importance.

  5. Effect of Autogenous Arc Welding Processes on Tensile and Impact Properties of Ferritic Stainless Steel Joints

    Institute of Scientific and Technical Information of China (English)

    A K Lakshminarayanan; K Shanmugam; V Balasubramanian

    2009-01-01

    The effect of autogeneous arc welding processes on tensile and impact properties of ferritic stainless steel conformed to AISI 409M grade is studied.Rolled plates of 4 mm thickness have been used as the base material for preparing single pass butt welded jointa.Tensile and impact properties,microhardness,microstructure,and fracture surface morphology of continuous current gas tungsten arc welding (CCGTAW),pulsed current gas tungsten arc welding (PCGTAW),and plasma arc welding (PAW) joints are evaluated and the results are compared.It is found that the PAW joints of ferritic stainless steel show superior tensile and impact properties when compared with CCGTAW and PCGTAW joints,and this is mainly due to lower heat input,finer fusion zone grain diameter,and higher fusion zone hardness.

  6. Investigation of processing properties of polyamide filled with hard coal

    Directory of Open Access Journals (Sweden)

    J. Stabik

    2009-04-01

    Full Text Available Purpose: The aim of this article is to present the influence of contents and kind of hard coal used as powder filler on rheological properties (viscosity of polyamide 6.Design/methodology/approach: Preparation of composite of polyamide 6 with hard coal was carried out on laboratory twin screw extruder. Extruded composite was granulated and in this form was used for MFR analysis. Taking into account MFR results viscosity was calculated. The influence of filler content on viscosity was next searched.Findings: Results of research showed that addition of powdered hard coal to polyamide 6 matrix cause pronounced decrease of MFR index. In this way significant increase of viscous flow was observed. It is often observed phenomenon for polymer composite filled with powder materials.Research limitations/implications: It is necessary to carry out the research with surface modified hard coal with coupling agents which provide better adhesion of polymer matrix to filler.Practical implications: Hard coal used as a filler in composites makes it possible to gain new and cheaper polymeric materials with many possible applications.Originality/value: Investigation described in article shows possibility of hard coal application as innovatory filler of polymers. The influence of this filler on rheological properties indicate that processing of these new materials may be accompanied with some problems.

  7. High-speed imaging investigation of transient phenomena impacting plasma arc cutting process optimization

    International Nuclear Information System (INIS)

    In this work, we report on the investigation of selected transient phenomena taking place in plasma arc cutting (PAC) that are relevant for process optimization. High-speed imaging diagnostics is exploited for the characterization of different technological solutions in order to provide deeper insights into torch and process design. In particular, the pilot arc start-up phase is analysed for a 250 A automatic dual-gas torch equipped with electrodes with different shapes of the initial insert recess, revealing that there is no influence of the recess depth on the time for the stabilization of the pilot arc attachment on the cathode insert. The influence of different insert materials, including Ag–Hf and Cu–Zr binary alloys, on erosion during the shut-down phase is investigated at 120 A and reduced emission of material and faster shut-down is found for alloy inserts compared with standard Hf inserts. The start-up and shut-down transients are also investigated during transferred arc operation using a modified nozzle that comprises a viewing port on one side of the nozzle, and pulsing arc behaviour inside the plasma chamber that is correlated with cathode-nozzle voltage oscillations at a frequency of 7.7 kHz is found. Finally, results regarding the influence of different plasma gas diffusers on the arc stability during the cutting initiation phase in a 100 A mono-gas manual torch are reported. (paper)

  8. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; Quentin C. Berg; Stephen P. Carpenter; Dady Dadyburjor; Jason C. Hissam; Manoj Katakdaunde; Liviu Magean; Abha Saddawi; Alfred H. Stiller; John W. Zondlo

    2006-03-07

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of carbon electrodes for Direct Carbon Fuel Cells (DCFC), and on carbon foam composites used in ballistic armor, as well as the hydrotreatment of solvents used in the basic solvent extraction process. A major goal is the production of 1500 pounds of binder pitch, corresponding to about 3000 pounds of hydrotreated solvent.

  9. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  10. Design Fuels Corporation (DFC)-Apache, Inc. coal reclamation system for the plant of the future for processing clean coal

    International Nuclear Information System (INIS)

    The mechanical washing processing and drying portion of the DFC process offers an efficient method for cleaning of pyritic sulfur bearing compounds which represents 25% sulfur reduction from original run-of-mine coal quality. This reduction can be augmented with the use of calcium and sodium based compounds to reduce the sulfur in many coals to produce compliance quality coal. The use of mechanical/physical methods for the removal of the pyritic material found in coal is used by the DFC process as a first step to the final application of a complete coal refuse clean-up technology based on site specific conditions of the parent coal. The paper discusses the use of the DFC process to remediate slurry ponds and tailings piles and to improve coal cleaning by gravity separation methods, flotation, hydrocyclones and spiral separators, dense media separation, water only cyclones, and oil/solvent agglomeration. A typical DFC Project is the Rosa Coal Reclamation Project which involves the development of a bituminous coal waste impoundment reclamation and washery system. The plant would be located adjacent to a coal fines pond or tailings pond and refuse pile or gob pile at a former coal strip mine in Oneonta, Alabama. Design Fuels would provide a development program by which coal waste at the Rosa Mine could be reclaimed, cleaned and sold profitably. This feedstock could be furnished from recovered coal for direct use in blast furnaces, or as feedstock for coke ovens at 250,000 tons per year at an attractive price on a 10-year contract basis. The site has an old coal washing facility on the property that will be dismantled. Some equipment salvage has been considered; and removal of the existing plant would be the responsibility of Design Fuels. The paper briefly discusses the market potential of the process

  11. Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, R.M.; Miller, R.L.

    1990-01-01

    The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal conversion utilizing low rank coals and low severity conditions (reaction temperatures generally less than 350{degrees}C) are the primary focus of the liquefaction experiments, as it is expected that the effect of pretreatment conditions and the attendant reactivity enhancement will be greatest for these coals and at these conditions. This document presents a comprehensive report summarizing the findings on the effect of mild alkylation pretreatment on coal reactivity under both direct hydroliquefaction and liquefaction co-processing conditions. Results of experiments using a dispersed catalyst system (chlorine) are also presented for purposes of comparison. IN general, mild alkylation has been found to be an effective pretreatment method for altering the reactivity of coal. Selective (oxygen) methylation was found to be more effective for high oxygen (subbituminous) coals compared to coals of higher rank. This reactivity enhancement was evidenced under both low and high severity liquefaction conditions, and for both direct hydroliquefaction and liquefaction co-processing reaction environments. Non-selective alkylation (methylation) was also effective, although the enhancement was less pronounced than found for coal activated by O-alkylation. The degree of reactivity enhancement was found to vary with both liquefaction and/or co-processing conditions and coal type, with the greatest positive effect found for subbituminous coal which had been selectively O-methylated and subsequently liquefied at low severity reaction conditions. 5 refs., 18 figs., 9 tabs.

  12. Steam gasification of coal, project prototype plant nuclear process heat

    International Nuclear Information System (INIS)

    This report describes the tasks, which Bergbau-Forschung has carried out in the field of steam gasification of coal in cooperation with partners and contractors during the reference phase of the project. On the basis of the status achieved to date it can be stated, that the mode of operation of the gas-generator developed including the direct feeding of caking high volatile coal is technically feasible. Moreover through-put can be improved by 65% at minimum by using catalysts. On the whole industrial application of steam gasification - WKV - using nuclear process heat stays attractive compared with other gasification processes. Not only coal is conserved but also the costs of the gas manufactured are favourable. As confirmed by recent economic calculations these are 20 to 25% lower. (orig.)

  13. Simulation of droplet transfer process and current waveform control of CO2 arc welding

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A simulation system used in the arc welding short-circuit transfer process and current waveform control process was developed in this paper. The simulation results are basically consistent with welding technical experiments. The simulation system can be used to simulate and test the current waveform control parameters with welding variables. By this simulation system, the influence regularities of the current waveform control parameters in the CO2 arc welding droplet short-circuit transfer process can be got. Moreover, the basic mode of real-time current waveform control can be also established by the simulation testing.

  14. Problems in processing Rheinische Braunkohle (soft coal)

    Energy Technology Data Exchange (ETDEWEB)

    von Hartmann, G.B.

    At Wesseling, difficulties were encountered with the hydrogenation of Rhine brown coal. The hydrogenation reaction was proceeding too rapidly at 600 atm pressure under relatively low temperature and throughput conditions. This caused a build-up of ''caviar'' deposits containing ash and asphalts. This flocculation of asphalt seemed to arise because the rapid reaction produced a liquid medium unable to hold the heavy asphalt particles in suspension. A stronger paraffinic character of the oil was also a result. To obtain practical, problem-free yields, throughput had to be increased (from .4 kg/liter/hr to more than .5), and temperature had to be increased (from 24.0 MV to 24,8 MV). Further, a considerable increase in sludge recycling was recommended. The Wesseling plant was unable to increase the temperature and throughput. However, more sludge was recycled, producing a paste better able to hold higher-molecular-weight particles in suspension. If this were not to solve the ''caviar'' deposit problems, further recommendations were suggested including addition of more heavy oil.

  15. Measurement and modeling of advanced coal conversion processes, Volume III

    Energy Technology Data Exchange (ETDEWEB)

    Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G. [and others

    1993-08-01

    A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

  16. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    Energy Technology Data Exchange (ETDEWEB)

    Mackiewicz-Ludtka, G.; Sebright, J. [Caterpillar Corp.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for

  17. Development of a process model for intelligent control of gas metal arc welding

    International Nuclear Information System (INIS)

    This paper discusses work in progress on the development of an intelligent control scheme for arc welding. A set of four sensors is used to detect weld bead cooling rate, droplet transfer mode, weld pool and joint location and configuration, and weld defects during welding. A neural network is being developed as the bridge between the multiple sensor set a conventional proportional-integral controller that provides independent control of process variables. This approach is being developed for the gas metal arc welding process. 20 refs., 8 figs

  18. Robustness studies on coal gasification process variables

    OpenAIRE

    RLJ Coetzer; MJ Keyser

    2004-01-01

    Optimisation of the Sasol-Lurgi gasification process was carried out by utilising the method of Factorial Experimental Design on the process variables of interest from a specifically equipped full-scale test gasifier. The process variables that govern gasification are not always fully controllable during normal operation. This paper discusses the application of statistical robustness studies as a method for determining the most efficient combination of process variables that might be hard-to-...

  19. On the tectonic processes along the Hellenic Arc

    Directory of Open Access Journals (Sweden)

    A. G. GALANOPOULOS

    1974-06-01

    Full Text Available On the grounds of existing geophysical data one might be allowed lo conclude t h a t the origin of t h e stress field in the Ionian center (Ceplialonia-Zante-Patras at t h e northwestern margin of the Aegean microplate is r a t h e r shallow and in the southeastern center (Dodecanese-Crete is surely under the crust. In the area occupied by the second center of higher earthquake activity t h e relief of the Moho-discontinuity is shallower and smoother in comparison to t h a t derived from g r a v i t y and seismic d a t a for t he area of t h e northwestern center. Another difference derived from the fault-plane solutions is t h a t the Ionian center is seated in a region of horizontal pressure; the second center in the southeastern Aegean Sea belongs to a region of paramount horizontal tension. In the western side of the Hellenic arc the high sediment supply rate, combined with a thickening of the E a r t h ' s crust along the Ionian zone, is interpreted as evidence t h a t accretion has occurred there until recently or may still be occurring locally; plate consumption, if any, is rather low. The existence, 011 t h e other hand, of two very deep subparallel trenches with little fill southeast of Crete (Pliny trench, Strabo trench, combined with a very high subcrustal activity in the southeastern margin of t h e Aegean Bubplate, suggest that the subduction rate at the northern boundary of the African plate must be relatively high; 110 p l a t e accretion is expected to occur there.

  20. Numerical analysis on coal-breaking process under high pressure water jet

    Energy Technology Data Exchange (ETDEWEB)

    Jin-hua Chen; Yun-pei Liang; Guo-qiang Cheng [Shandong University of Science and Technology, Qingdao (China)

    2009-09-15

    Based on the theory of nonlinear dynamic finite element, a control equation of coal and water jet was acquired in the coal breaking process under a water jet. A calculation model of coal breaking under a water jet was established; the fluid-structure coupling of water jet and coal was implemented by penalty function and convection calculation. The dynamic process of coal breaking under a water jet was simulated and analyzed by combining the united fracture criteria of the maximum tensile strain and the maximal shear strain in the two cases of damage to coal and damage failure to coal. 5 refs., 5 figs., 2 tabs.

  1. Numerical analysis on coal-breaking process under high pressure water jet

    Institute of Scientific and Technical Information of China (English)

    CHEN Jin-hua; LIANG Yun-pei; CHENG Guo-qiang

    2009-01-01

    Based on the theory of nonlinear dynamic finite element, the control equation of coal and water jet was acquired in the coal breaking process under a water jet. The calcu-lation model of coal breaking under a water jet was established; the fluid-structure cou-pling of water jet and coal was implemented by penalty function and convection calculation. The dynamic process of coal breaking under a water jet was simulated and analyzed by combining the united fracture criteria of the maximum tensile strain and the maximal shear strain in the two cases of damage to coal and damage failure to coal.

  2. Application studies of RFID technology in the process of coal logistics transport

    Science.gov (United States)

    Qiao, Bingqin; Chang, Xiaoming; Hao, Meiyan; Kong, Dejin

    2012-04-01

    For quality control problems in coal transport, RFID technology has been proposed to be applied to coal transportation process. The whole process RFID traceability system from coal production to consumption has been designed and coal supply chain logistics tracking system integration platform has been built, to form the coal supply chain traceability and transport tracking system and providing more and more transparent tracking and monitoring of coal quality information for consumers of coal. Currently direct transport and combined transport are the main forms of coal transportation in China. The means of transport are cars, trains and ships. In the booming networking environment of RFID technology, the RFID technology will be applied to coal logistics and provide opportunity for the coal transportation tracking in the process transportation.

  3. Plasma Processes : Arc root dynamics in high power plasma torches – Evidence of chaotic behavior

    Indian Academy of Sciences (India)

    A K Das

    2000-11-01

    Although plasma torches have been commercially available for about 50 years, areas such as plasma gun design, process efficiency, reproducibility, plasma stability, torch lives etc. have remained mostly unattended. Recent torch developments have been focusing on the basic understanding of the plasma column and its dynamics inside the plasma torch, the interaction of plasma jet and the powders, the interaction of the plasma jet with surroundings and the impingement of the jet on the substrate. Two of the major causes of erratic and poor performance of a variety of thermal plasma processes are currently identified as the fluctuations arising out of the arc root movement on the electrodes inside the plasma torch and the fluid dynamic instabilities arising out of entrainment of the air into the plasma jet. This paper reviews the current state of understanding of these fluctuations as well as the dynamics of arc root movement in plasma torches. The work done at the author’s laboratory on studying the fluctuations in arc voltage, arc current, acoustic emissions and optical emissions are also presented. These fluctuations are observed to be chaotic and interrelated. Real time monitoring and controlling the arc instabilities through chaos characterization parameters can greatly contribute to the understanding of electrode erosion as well as improvement of plasma torch lifetime.

  4. Studies of steered arc motion and macroparticle production in PVD processing

    Energy Technology Data Exchange (ETDEWEB)

    Craven, A.L

    2000-03-01

    During the past decade the production industry has constantly strived to improve performance and cut costs, this has been aided by the development of high performance tools. The advancement of these tools has been accomplished by the application of hard wearing, low friction, coatings. A key process in the production of such coatings is Physical Vapour Deposition (PVD). Interest in such thin films has led to much research effort, both academic and industrial, being devoted to the area. In order that these advancements in technology continue, research into the fundamental aspects of PVD is required. This thesis describes research and experimental studies which have been performed to study the effect of 'steering' an electric arc on various aspects of its behaviour. 'Steering' of the arc is achieved by applying external magnetic fields which allow the guidance of the path of the arc. Work by earlier authors has aimed to control the arc more fully. The research presented here is based of a novel electromagnetic three coil steering array of cylindrical geometry. With such coils it is possible to vary the field profiles to a greater degree than has been previously achieved, permitting a greater range of steering arrangements/fields to be applied. The research presented is divided into two distinct areas: Firstly a number of experiments were performed to assess the effectiveness of the new steering coils on the motion of the arc. A personal computer was used here along with new arc motion monitoring electronics. This enabled the simultaneous measurement of the orbital transit times and also the degree of travel perpendicular to the steered direction of motion of the arc, as it traversed the surface of the cathode. Such information was then used to produce values for standard deviation of the arc from its steered path, velocity of the arc and a diffusion constant related to the motion of the are. Such values then allowed evaluation of the stochastic

  5. Studies of steered arc motion and macroparticle production in PVD processing

    International Nuclear Information System (INIS)

    During the past decade the production industry has constantly strived to improve performance and cut costs, this has been aided by the development of high performance tools. The advancement of these tools has been accomplished by the application of hard wearing, low friction, coatings. A key process in the production of such coatings is Physical Vapour Deposition (PVD). Interest in such thin films has led to much research effort, both academic and industrial, being devoted to the area. In order that these advancements in technology continue, research into the fundamental aspects of PVD is required. This thesis describes research and experimental studies which have been performed to study the effect of 'steering' an electric arc on various aspects of its behaviour. 'Steering' of the arc is achieved by applying external magnetic fields which allow the guidance of the path of the arc. Work by earlier authors has aimed to control the arc more fully. The research presented here is based of a novel electromagnetic three coil steering array of cylindrical geometry. With such coils it is possible to vary the field profiles to a greater degree than has been previously achieved, permitting a greater range of steering arrangements/fields to be applied. The research presented is divided into two distinct areas: Firstly a number of experiments were performed to assess the effectiveness of the new steering coils on the motion of the arc. A personal computer was used here along with new arc motion monitoring electronics. This enabled the simultaneous measurement of the orbital transit times and also the degree of travel perpendicular to the steered direction of motion of the arc, as it traversed the surface of the cathode. Such information was then used to produce values for standard deviation of the arc from its steered path, velocity of the arc and a diffusion constant related to the motion of the are. Such values then allowed evaluation of the stochastic model of arc motion

  6. Arc Export File Of Permitted and Mined Out Coal Areas of the Gulf Coast Coal-Bearing (gulfmines.e00)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset contains permitted coal mines and mined out areas in the Gulf Coast coal-bearing geology prior to 1998. The data included in the coverage are mine...

  7. Measurement and modeling of advanced coal conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1992-01-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO[sub x]-NO[sub x] submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  8. Characterization of Mullite-Zirconia Composite Processed by Non-Transferred and Transferred Arc Plasma

    Institute of Scientific and Technical Information of China (English)

    S. YUGESWARAN; V. SELVARAJAN; L. LUSVARGHI; A. I. Y. TOK; D. SIVA RAMA KRISHNA

    2009-01-01

    The arc plasma melting technique is a simple method to synthesize high temperature reaction composites. In this study, mullite-zirconia composite was synthesized by transferred and non-transferred arc plasma melting, and the results were compared. A mixture of alumina and zircon powders with a mole ratio of 3 : 2 were ball milled for four hours and melted for two minutes in the transferred and non-transferred mode of plasma arcs. Argon and air were used as plasma forming gases. The phase and microstructural formation of melted samples were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM). The microstructure of the com-posites was found to be affected by the mode of melting. In transferred arc melting, zirconia flowers with uniform lines along with mullite whiskers were obtained. In the case of non-transferred arc plasma melting, mullite whiskers along with star shape zirconia were formed. Differential thermal analysis (DTA) of the synthesized mullite-zirconia composites provided a deeper understanding of the mechanisms of mullite formation during the two different processes.

  9. Elaboration of metallic and composite fillings by plasma transferred arc. Process analysis and tribological study

    International Nuclear Information System (INIS)

    The experimental part of this research thesis addresses the parametric study of two surface filling processes (by plasma transferred arc, and by plasma arc projection followed by a coating remelting by electron beam), the elaboration by plasma transferred arc and the metallurgical characterization of fillings of nickel base alloys and composite materials made of tungsten carbides dispersed in a nickel matrix, and the characterization of fretting wear of the so-elaborated fillings in aqueous environment. The results show that the plasma transferred arc filling technique allows coating quality and microstructure to be controlled by adjusting the mass energy of the transferred arc. Besides, this technique results in a very good control of nickel alloy coatings. The various studied composites show that it is better to use a matrix with very few alloying elements or pre-coated carbides in order to avoid any cracking phenomenon. The content of dispersed carbides must not be greater than 60 per cent in weight. The best wear behaviour is obtained with polyhedral tungsten carbides dispersed within a low alloyed nickel matrix

  10. Experimental and theoretical studies of recombination ionization and diffusion processes in an arc plasma

    International Nuclear Information System (INIS)

    We have experimentally determined the changes of the electron density and excited atom density in a wall-stabilized arc burning in argon at atmospheric pressure; we have deduced the changes of electronic temperature, and the difference between electronic temperature and gas temperature. Whe have found these parameters by means of two wavelengths laser interferometry and spectroscopy measurements. By means of collisional radiatif model, we have found ionization and recombination coefficients. Knowing electronic density profiles, we have determined the different plasma parameters and analysed the electronic energy losses using our model. Whe have studied the electronic loss processes during the early stages of arc extinction

  11. Qualification of submerged-arc narrow strip cladding process

    International Nuclear Information System (INIS)

    Babcock and Wilcox has developed an unique narrow strip cladding process for use on both plate and forging material for nuclear components. The qualification testing of this low-heat input process for cladding nuclear components is described, including those of SA508 Class 2 material. The theory that explains the acceptable results of these tests is also given

  12. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    Energy Technology Data Exchange (ETDEWEB)

    Edwin S. Olson; Charles J. Moretti

    1999-11-01

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require

  13. Thermo-mechanical analysis of wire and arc additive manufacturing process

    OpenAIRE

    Ding, J

    2012-01-01

    Conventional manufacturing processes often require a large amount of machining and cannot satisfy the continuously increasing requirements of a sustainable, low cost, and environmentally friendly modern industry. Thus, Additive Manufacturing (AM) has become an important industrial process for the manufacture of custom-made metal workpieces. Among the different AM processes, Wire and Arc Additive Manufacture (WAAM) has the ability to manufacture large, low volume metal work-p...

  14. Vacuum Arc Melting Processes for Biomedical Ni-Ti Shape Memory Alloy

    OpenAIRE

    Tsai De-Chang; Chiang Chen-Hsueh

    2015-01-01

    This study primarily involved using a vacuum arc remelting (VAR) process to prepare a nitinol shape-memory alloy with distinct ratios of alloy components (nitinol: 54.5 wt% to 57 wt%). An advantage of using the VAR process is the adoption of a water-cooled copper crucible, which effectively prevents crucible pollution and impurity infiltration. Optimising the melting production process enables control of the alloy component and facilitates a uniformly mixed compound during subsequent processi...

  15. Brine disposal process for Morcinek coal mine

    Energy Technology Data Exchange (ETDEWEB)

    Tait, J.H. [Aquatech Services, Inc., Citrus Heights, CA (United States)

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  16. ARC Code TI: Block-GP: Scalable Gaussian Process Regression

    Data.gov (United States)

    National Aeronautics and Space Administration — Block GP is a Gaussian Process regression framework for multimodal data, that can be an order of magnitude more scalable than existing state-of-the-art nonlinear...

  17. Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, R.M.; Miller, R.L.

    1991-12-01

    The findings in the first phase were as follows: 1. Both reductive (non-selective) alkylation and selective oxygen alkylation brought about an increase in liquefaction reactivity for both coals. 2. Selective oxygen alkylation is more effective in enhancing the reactivity of low rank coals. In the second phase of studies, the major findings were as follows: 1. Liquefaction reactivity increases with increasing level of alkylation for both hydroliquefaction and co-processing reaction conditions. 2. the increase in reactivity found for O-alkylated Wyodak subbituminous coal is caused by chemical changes at phenolic and carboxylic functional sites. 3. O-methylation of Wyodak subbituminous coal reduced the apparent activation energy for liquefaction of this coal.

  18. Radiation-thermal processes of conversion in the coals

    International Nuclear Information System (INIS)

    Full text: The brief review, history, modern condition and bibliographic data on research of radiation-stimulated processes in coals are adduced in the report. Results of new researches of influence of gamma - radiation and accelerated electrons on pyrolysis, gasification, desulphurization, paramagnetism, adsorption and optical properties of coals in wide intervals of change of absorbed dose, dose rate, temperature, radiation type and other parameters of processes are stated. As object of researches Turkish (Yeni koy, Yatagan) and Russian (Siberia) coals were used. Specific peculiarities of influence of ionizing radiations on fossil fuels, bringing in change of their reactivity as result of destruction and polycondensation processes are considered. a)Pyrolysis: Under action of gamma-radiation and accelerated electrons the rate of thermal (t) pyrolysis grows and the ratio of radiation-thermal (rt) and thermal (t) processes: Wrt/ Wt depends on dose rate and temperature. By increase of dose rate the radiation effects grows, and at increase of temperature this effect is reduced. The influence of high rate heating of coals under pulls action of accelerated electrons on conversion degree and product composition has been established. The investigation regularities of formation liquid and gas products is resulted at radiation - thermal processing of mixtures of lignites with fuel oil. These experiments were conducted in flowing conditions in the interval of temperature T=350-500 degrees centigrade, power of the pulls accelerated electrons P=30-50 W, flow velocity of fuel oil 0,2-2 ml/minute. As a index of process were controlled conversion degree of coals, overall yield, contents and characteristic of liquid and gas products. The products of thermal treatment of these mixtures and also radiation-thermal treatment of separate components significantly less than radiation-thermal conversion of binary mixtures. It has been established that radiation effect has a positive

  19. Influence of Process Parameters on Coal Combustion Performance

    DEFF Research Database (Denmark)

    Lans, Robert Pieter Van Der

    and swirl number on the flow pattern in the near burner zone of the laboratory furnace-model were studied. Experimentally obtained residence time distributions have been used to derive a chemical reaction engineering model for the mixing process. The model is based on a combination of plug flow...... facilities with self-sustaining flames, while extensions are made to full scale boilers and furnace modeling. Since coal combustion and flame aerodynamics are reviewed elsewhere, these phenomena are only treated briefly. The influence of coal type and process conditions on NO formation and carbon burnout has...... study has been performed in order to initiate an investigation of the potential of chemical engineering models to predict NO from pulverized fuel burners. The success of chemical engineering modeling is strongly connected to the simplification of the flow pattern into a reactor configuration. The...

  20. Parameters and evaluation criteria for the coal coking process

    Energy Technology Data Exchange (ETDEWEB)

    Postrzednik, S.

    1988-09-01

    Analyzes effects of temperature distribution on black coal coking in a conventional coke oven. Two parameters are used for description of temperature distribution: a local (time-average) divergence function and an instant (volumetric) divergence function. Formulae for determining the two parameters are derived. Use of the mean values of the two functions as an evaluation criteria for assessment of the coking process is recommended. Practical use of the proposed criteria is discuussed. 8 refs.

  1. Novel graphene production: an aqueous arc discharge process

    OpenAIRE

    Kim, Sejung

    2015-01-01

    Graphene plays important roles in technological developments regarding electronic device, environment and energy management and the motivation to prepare two-dimensional (2D) nanomaterials. As the pioneer for 2D nanomaterials, graphene has been shown to be not only thermodynamically stable, but also superior in terms of electronic and mechanical properties and that it can be processed into a wide variety of novel materials. However, they are still limited to the challenges such as multi-stack...

  2. Study on the formation mechanism of shock wave in process of coal and gas outburst

    Institute of Scientific and Technical Information of China (English)

    SUN Dong-ling; MIAO Fa-tian; LIANG Yun-pei

    2009-01-01

    According to the research results of motion parameters of coal-gas flow, ana-lyzed the formation mechanism of shock waves at different states of coal-gas flow in the process of coal and gas outburst, and briefly described the two possible cases of outburst shock wave formation and their formation conditions in the process of coal and gas out-burst, and then pointed out that a high degree of under-expanded coal-gas flow was the main reason for the formation of a highly destructive shock wave. The research results improved the shock wave theory in coal and gas outburst.

  3. RESEARCH ON CARBON PRODUCTS FROM COAL USING AN EXTRACTIVE PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo; Chong Chen; Brian Bland; David Fenton

    2002-03-31

    This report presents the results of a one-year effort directed at the exploration of the use of coal as a feedstock for a variety of industrially-relevant carbon products. The work was basically divided into three focus areas. The first area dealt with the acquisition of laboratory equipment to aid in the analysis and characterization of both the raw coal and the coal-derived feedstocks. Improvements were also made on the coal-extraction pilot plant which will now allow larger quantities of feedstock to be produced. Mass and energy balances were also performed on the pilot plant in an attempt to evaluate the scale-up potential of the process. The second focus area dealt with exploring hydrogenation conditions specifically aimed at testing several less-expensive candidate hydrogen-donor solvents. Through a process of filtration and vacuum distillation, viable pitch products were produced and evaluated. Moreover, a recycle solvent was also isolated so that the overall solvent balance in the system could be maintained. The effect of variables such as gas pressure and gas atmosphere were evaluated. The pitch product was analyzed and showed low ash content, reasonable yield, good coking value and a coke with anisotropic optical texture. A unique plot of coke yield vs. pitch softening point was discovered to be independent of reaction conditions or hydrogen-donor solvent. The third area of research centered on the investigation of alternate extraction solvents and processing conditions for the solvent extraction step. A wide variety of solvents, co-solvents and enhancement additives were tested with varying degrees of success. For the extraction of raw coal, the efficacy of the alternate solvents when compared to the benchmark solvent, N-methyl pyrrolidone, was not good. However when the same coal was partially hydrogenated prior to solvent extraction, all solvents showed excellent results even for extractions performed at room temperature. Standard analyses of the

  4. Development of Process Maps in Two-Wire Tandem Submerged Arc Welding Process of HSLA Steel

    Science.gov (United States)

    Kiran, D. V.; Alam, S. A.; De, A.

    2013-04-01

    Appropriate selection of welding conditions to guarantee requisite weld joint mechanical properties is ever difficult because of their complex interactions. An approach is presented here to identify suitable welding conditions in typical two-wire tandem submerged arc welding (SAW-T) that involves many welding variables. First, an objective function is defined, which depicts the squared error between the mechanical properties of weld joint and of base material. A set of artificial neural network (ANN)-based models are developed next to estimate the weld joint properties as function of welding conditions using experimentally measured results. The neural network model-based predictions are used next to create a set of process map contours that depict the minimum achievable values of the objective function and the corresponding welding conditions. In typical SAW-T of HSLA steel, welding speed from 9.0 to 11.5 mm/s, leading wire current from 530 to 580 A, and trailing wire negative current from 680 to 910 A are found to be the most optimal.

  5. Study on chaos in short circuit gas metal arc welding process

    Institute of Scientific and Technical Information of China (English)

    Lü Xiaoqing; Cao Biao; Zeng Min; Wang Zhenmin; Huang Shisheng

    2007-01-01

    Based on the chaos theory, an idea is put forward to analyze the short circuit Gas Metal Arc Welding (GMAW-S) process. The theory of phase space reconstruction and related algorithms such as mutual information and so on, are applied to analyze the chaos of the GMAW-S process. The largest Lyapunov exponents of some current time series are calculated, and the results indicate that chaos exists in the GMAW-S process. The research of the chaos in the GMAW-S process can be help to get new knowledge of the process.

  6. Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD)

    International Nuclear Information System (INIS)

    The present paper is the first of a series of two articles dealing with the development of an integrated process for the recovery of zinc from electric arc furnace dust (EAFD), a hazardous industrial waste generated in the collection of particulate material during steelmaking process via electric arc furnace. Part I presents the EAFD characterization and its leaching process by diluted sulphuric acid, whereas Part II deals with the purification of the leach liquor and the recovery of zinc by solvent extraction/electrowinning. The characterization of the examined electric arc furnace dust was carried out by using granulometry analysis, chemical analysis, X-ray diffraction (XRD), thermogravimetric/differential thermal analysis (TG/DTA) and scanning electron microscopy (SEM). The leaching process was based on the Zn extraction with diluted sulphuric acid from EAFD under atmospheric conditions and without using any preliminary treatment. Statistical design and analysis of experiments were used, in order to determine the main effects and interactions of the leaching process factors, which were: acid normality, temperature and solid to liquid ratio. The zinc recovery efficiency on the basis of EAFD weight reached 80%. X-ray diffraction and scanning electron microscopy were used for the characterization of the leached residues.

  7. Coal

    International Nuclear Information System (INIS)

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  8. Experimental simulation and numerical analysis of coal spontaneous combustion process at low temperature

    Institute of Scientific and Technical Information of China (English)

    文虎; 徐精彩; 葛岭梅

    2001-01-01

    The characteristic of coal spontaneous, combustion includes oxidative property and exothermic capacity. It can really simulate the process of coal spontaneous combustion to use the large-scale experimental unit loading coal ! 000 kg. According to the field change of gas concentration and coal temperature determined through experiment of coal self-ignite at low temperature stage, and on the basis of hydromechanics and heat-transfer theory, some parameters can be calculated at different low temperature stage, such as, oxygen consumption rate, heat liberation intensity. It offers a theoretic criterion for quantitatively analyzing characteristic of coal self-ignite and forecasting coal spontaneous combustion. According to coal exothermic capability and its thermal storage surroundings, thermal equilibrium is applied to deduce the computational method of limit parameter of coal self-ignite. It offers a quantitative theoretic criterion for coal self-ignite forecasting and preventing. According to the measurement and test of spontaneous combustion of Haibei coal, some token parameter of Haibei coal,spontaneous combustion is quantitatively analyzed, such as, spontaneous combustion period of coal, critical temperature, oxygen consumption rate, heat liberation intensity, and limit parameter of coal self-ignite.

  9. Experimental simulation and numerical analysis of coal spontaneous combustion process at low temperature*

    Institute of Scientific and Technical Information of China (English)

    WEN Hu; XU Jing-cai; GE Ling-mei

    2001-01-01

    The characteristic of coal spontaneous combustion includes oxidative p roperty and exothermic capacity. It can really simulate the process of coal spon taneous combustion to use the large-scale experimental unit loading coal 1 000 kg. According to the field change of gas concentration and coal temperature determi ned through experiment of coal self-ignite at low temperature stage, and on the basis of hydromechanics and heat-transfer theory, some parameters can be calcul at ed at different low temperature stage, such as, oxygen consumption rate, heat li beration intensity. It offers a theoretic criterion for quantitatively analyzing characteristic of coal self-ignite and forecasting coal spontaneous combustion . According to coal exothermic capability and its thermal storage surroundings, t hermal equilibrium is applied to deduce the computational method of limit parame ter of coal self-ignite. It offers a quantitative theoretic criterion for coal s elf-ignite forecasting and preventing. According to the measurement and test of spontaneous combustion of Haibei coal, some token parameter of Haibei coal spont aneous combustion is quantitatively analyzed, such as, spontaneous combustion pe riod of coal, critical temperature, oxygen consumption rate, heat liberation int ensity, and limit parameter of coal self-ignite.

  10. An analysis of the dynamic resistance and the instantaneous energy of the CO2 arc welding process

    Institute of Scientific and Technical Information of China (English)

    Wang Zhenmin; Xue Jiaxiang; Dong Fei; Yang Guohua; Lu Xiaoming

    2007-01-01

    A self-developed welding dynamic arc wavelet analyzer was adopted to analyze and assess the welding process of two CO2 arc welding machines. The experimental results indicate that the instantaneous energy can reflect the influence of the welding current and voltage on dynamic arc characteristic synthetically. Through calculating and analyzing the instantaneous energy, the energy during arc ignition and short circuit in CO2 welding process can be confirmed rationally, thus the foundation for the accurate design and control of the welding current and voltage can be provided. By reducing the ripple disturbance of the dynamic resistance, avoiding peak current and voltage waveform,and enhancing the transition frequency of short circuit suitably, the stability of the welding arc and the weld appearance can be improved.

  11. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    OpenAIRE

    Kartika K. Hendratna; Osami Nishida; Hirotsugu Fujita; Wataru Harano

    2010-01-01

    Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory s...

  12. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  13. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Winschel, R.A.; Brandes, S.D.; Robbins, G.A.; Burke, F.P.

    1991-11-01

    Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  14. Numerical Simulation of Gas Flow During Arcing Process for 252 kV Puffer Circuit Breakers

    Science.gov (United States)

    Wu, Junhui; Wang, Xiaohua; Ma, Zhiying; Rong, Mingzhe; Yan, Jing

    2011-12-01

    A numerical simulation model for 252 kV puffer circuit breaker is constructed, by using a proven commercial computational fluid dynamics (CFD) package, PHOENICS. The model takes into account the moving parts in the circuit breaker, turbulence enhanced momentum and energy transport, radiation transport. The arcing process in a SF6 puffer circuit breaker with two hollow contacts is simulated under different conditions, and the simulation results are verified with experimental results. Through simulation, the pressure, temperature and velocity in the arc quenching chamber can be obtained. The simulation model is also capable of predicting the influence of design parameters variations on breaker performance, and can thus help to reduce the number of short-circuit tests during the design stage.

  15. Numerical Simulation of Gas Flow During Arcing Process for 252 kV Puffer Circuit Breakers

    International Nuclear Information System (INIS)

    A numerical simulation model for 252 kV puffer circuit breaker is constructed, by using a proven commercial computational fluid dynamics (CFD) package, PHOENICS. The model takes into account the moving parts in the circuit breaker, turbulence enhanced momentum and energy transport, radiation transport. The arcing process in a SF6 puffer circuit breaker with two hollow contacts is simulated under different conditions, and the simulation results are verified with experimental results. Through simulation, the pressure, temperature and velocity in the arc quenching chamber can be obtained. The simulation model is also capable of predicting the influence of design parameters variations on breaker performance, and can thus help to reduce the number of short-circuit tests during the design stage. (15th asian conference on electrical discharge)

  16. Evaporation Erosion During the Relay Contact Breaking Process Based on a Simplified Arc Model

    Science.gov (United States)

    Cui, Xinglei; Zhou, Xue; Zhai, Guofu; Peng, Xiyuan

    2016-05-01

    Evaporation erosion of the contacts is one of the fundamental failure mechanisms for relays. In this paper, the evaporation erosion characteristics are investigated for the copper contact pair breaking a resistive direct current (dc) 30 V/10 A circuit in the air. Molten pool simulation of the contacts is coupled with the gas dynamics to calculate the evaporation rate. A simplified arc model is constructed to obtain the contact voltage and current variations with time for the prediction of the current density and the heat flux distributions flowing from the arc into the contacts. The evaporation rate and mass variations with time during the breaking process are presented. Experiments are carried out to verify the simulation results. supported by National Natural Science Foundation of China (Nos. 51377038, 51307030)

  17. Evaporation Erosion During the Relay Contact Breaking Process Based on a Simplified Arc Model

    Institute of Scientific and Technical Information of China (English)

    CUI Xinglei; ZHOU Xue; ZHAI Guofu; PENG Xiyuan

    2016-01-01

    Evaporation erosion of the contacts is one of the fundamental failure mechanisms for relays.In this paper,the evaporation erosion characteristics are investigated for the copper contact pair breaking a resistive direct current (dc) 30 V/10 A circuit in the air.Molten pool simulation of thc contacts is coupled with the gas dynamics to cMculate the evaporation rate.A simplified arc model is constructed to obtain the contact voltage and current variations with time for the prediction of the current density and the heat flux distributions flowing from the arc into the contacts.The evaporation rate and mass variations with time during the breaking process are presented.Experiments are carried out to verify the simulation results.

  18. Controlling the Twin Wire Arc Spray Process Using Artificial Neural Networks (ANN)

    Science.gov (United States)

    Hartz-Behrend, K.; Schaup, J.; Zierhut, J.; Schein, J.

    2016-01-01

    One approach for controlling the twin wire arc spray process is to use optical properties of the particle beam as input parameters for a process control. The idea is that changes in the process like eroded contact nozzles or variations of current, voltage, and/or atomizing gas pressure may be detected through observation of the particle beam. It can be assumed that if these properties deviate significantly from those obtained from a beam recorded for an optimal coating process, the spray particle and thus the coating properties change significantly. The goal is to detect these deviations and compensate the occurring errors by adjusting appropriate process parameters for the wire arc spray unit. One method for monitoring optical properties is to apply the diagnostic system particle flux imaging (PFI): PFI fits an ellipse to an image of a particle beam thereby defining easy to analyze characteristical parameters by relating optical beam properties to ellipse parameters. Using artificial neural networks (ANN), mathematical relations between ellipse and process parameters can be defined. It will be shown that in the case of a process disturbance through the use of an ANN-based control new process parameters can be computed to compensate particle beam deviations.

  19. Effect of cleaning process on the combustion characteristics of two different rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Kok, M.V.; Hicyilmaz, C.; Ozbas, K.E. [Middle East Technical University, Ankara (Turkey). Dept. of Mining Engineering

    2001-12-01

    In this research, thermogravimetry (TG/DTG) was used to determine the combustion characteristics of two different rank coals (Tuncbilek and Afsin Elbistan) before and after cleaning process. Applying sink-float process cleaned raw coal samples, and optimum-separating densities for each sample was determined using the criteria of 'degree of washability'. The results indicated that coal cleaning was very effective on Tuncbilek sample due to its high rank. TG/DTG analysis of raw and cleaned samples indicated different reaction regions occurring at different temperature intervals. Easy combustibility and long-lasting combustion were the distinctive effects of coal cleaning on raw coals. Kinetic analysis of the samples showed that clean coals require lower activation energies to initiate the combustion process than raw coals. 14 refs., 6 figs., 10 tabs.

  20. Study on the mechanism of coal liquefaction reaction and a new process concept

    Institute of Scientific and Technical Information of China (English)

    SHI Shi-dong; LI Wen-bo; WANG Yong; GUO Zhi; LI Ke-jian

    2008-01-01

    The coal hydrogenation reaction process is simply considered as three steps. In the first step, the smaller molecules associated with coal structure units are released as some gases and water in the condition of solvent and heating. In this step, some weaker bonds of the coal structure units are ruptured to form free radicals. The radicals are stabi-lized by hydrogen atoms from donor solvent and/or H2. In the second step, chain reaction occurs quickly. In the process of chain reaction, the covalent bonds of coal structure units are attacked by the radicals to form some asphaltenes. In the third step, asphaltenes are hydrogenated form more liquids and some gases. In coal liquefaction, the second step of coal hydrogenation reaction should be controlled to avoid integration of radicals, and the third step of coal hydrogenation should be accelerated to increase the coal conversion and the oil yield. A new concept of coal liquefaction process named as China direct coal lique-faction (CDCL) process is presented based on the mechanism study of coal liquefaction.

  1. Numerical simulation for arc-plasma dynamics during contact opening process in electrical circuit-breakers

    Science.gov (United States)

    Gupta, D. N.; Patil, G. N.; Srinivas, D.; Kale, S. S.; Potnis, S. B.

    2010-02-01

    The high-energy, high-current thermal plasma that develops between electric contacts in a gas circuit-breaker during circuit interruption is an important phenomenon in the power transmission industry. The high temperature and pressure arc dissipates the tremendous amount of energy generated by the fault current. Simultaneously, this energy has to be transferred away from the contacts to build the dielectric strength level of the circuit-breaker. In order to interrupt the current, the arc must be weakened and finally extinguished. We model these phenomena by using a computer software code based on the solution of the unsteady Euler equations of gas dynamics. We consider the equations of fluid flows. These equations are solved numerically in complex circuit breaker geometries using a finite-volume method. The domain is initially filled with SF6 gas. We begin our simulations from cold mode, where the fault current is not present (hence no arc). An axis-symmetric geometry of a 145 kV gas circuit-breaker is considered to study the pressure, density, and temperature profile during contact opening process.

  2. Numerical simulation for arc-plasma dynamics during contact opening process in electrical circuit-breakers

    International Nuclear Information System (INIS)

    The high-energy, high-current thermal plasma that develops between electric contacts in a gas circuit-breaker during circuit interruption is an important phenomenon in the power transmission industry. The high temperature and pressure arc dissipates the tremendous amount of energy generated by the fault current. Simultaneously, this energy has to be transferred away from the contacts to build the dielectric strength level of the circuit-breaker. In order to interrupt the current, the arc must be weakened and finally extinguished. We model these phenomena by using a computer software code based on the solution of the unsteady Euler equations of gas dynamics. We consider the equations of fluid flows. These equations are solved numerically in complex circuit breaker geometries using a finite-volume method. The domain is initially filled with SF6 gas. We begin our simulations from cold mode, where the fault current is not present (hence no arc). An axis-symmetric geometry of a 145 kV gas circuit-breaker is considered to study the pressure, density, and temperature profile during contact opening process.

  3. CFBC evaluation of fuels processed from Illinois coals. Technical report, March 1, 1992--May 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Rajan, S. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes

    1992-10-01

    The combustion and emissions properties of (a) flotation slurry fuel beneficiated from coal fines at various stages of the cleaning process and (b) coal-sorbent pellets made from the flotation concentrate of the same beneficiation process using corn starch as binder is being investigated in a 4-inch internal diameter circulating fluidized bed combustor (CFBC). Combustion data such as SO{sub 2}, NO{sub x} emissions, combustion efficiency and ash mineral matter analyses from these fuels are compared with similar parameters from a reference coal burnt in the same fluidized bed combustor. In the last quarter, the CFBC was brought on line and tests were performed on standard coal No. 3 from the Illinois Basin Coal Sample Program (IBCSP). During this quarter, it was decided, that a more meaningful comparison could be obtained if, instead of using the IBCSP No. 3 coal as a standard, the run-of-mine Illinois No. 5 coal from the Kerr-McGee Galatia plant could be used as the reference coal for purposes of comparing the combustion and emissions performance, since the slurry and pellet fuels mentioned in (a) and (b) above were processed from fines recovered form this same Illinois No. 5 seam coal. Accordingly, run-of-the mine Illinois No. 5 coal from the Galatia plant were obtained, riffled and sieved to {minus}14+18 size for the combustion tests. Preliminary combustion tests have been made in the CFBC with this new coal. In preparation for the slurry tests, the moisture content of the beneficiated slurry samples was determined. Proximate and ultimate analyses of all the coal samples were performed. Using a Leeds and Northrup Model 7995-10 Microtrek particle size analyzer, the size distributions of the coal in the three slurry samples were determined. The mineral matter content of the coal in the three slurry samples and the Illinois No. 5 seam coal were investigated using energy dispersive x-ray analysis.

  4. Process for converting coal into liquid fuel and metallurgical coke

    Science.gov (United States)

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  5. Measurement of three-dimensional welding torch orientation for manual arc welding process

    International Nuclear Information System (INIS)

    Torch orientation plays an important role in welding quality control for a manual arc welding process. The detection of the torch orientation can facilitate weld monitoring, welder training, and may also open a door to many other interesting and useful applications. Yet, little research has been done in measuring the torch orientation in the manual arc welding process. This paper introduces a torch orientation measurement scheme that can be conveniently incorporated both in a real manual arc welding process and in a welder training system. The proposed measurement employs a miniature wireless inertial measurement unit (WIMU), which includes a tri-axial accelerometer and a tri-axial gyroscope. A quaternion-based unscented Kalman filter (UKF) has been designed to estimate the three-dimensional (3D) torch orientation, in which the quaternion associated with the orientation is included in the state vector, as is the angular rate measured by the gyroscope. In addition, an auto-nulling procedure has been developed where the WIMU drift and measurement noise are captured and adaptively compensated in-line to ensure the measurement accuracy. The performance of the proposed scheme has been evaluated by simulations and welding experiments with different types of processes and fit-ups. The simulation results show that the inclination (x- and y-axes) of the torch has been accurately measured with a root-mean-square error (RMSE) in the order of 0.3°. The major error obtained in the heading (z-axis) measurement has been reduced significantly by the proposed auto-nulling procedure. Statistics from welding experiments indicate the proposed scheme is able to provide a complete 3D orientation measurement with the RMSE in the order of 3°. (paper)

  6. Swelling and shrinkage behavior of raw and processed coals during pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Zhixin Fu; Zhancheng Guo; Zhangfu Yuan; Zhi Wang [Chinese Academy of Sciences, Beijing (China). Laboratory of Multiphase Reactions, Institute of Process Engineering

    2007-02-15

    Direct observation of transient swelling and shrinkage behavior of raw coals and processed coals was conducted by using a digital camera with a long focus lens, and quantitative description of swelling and shrinkage was resulted from subsequent image processing. The results showed that the raw and processed coals in pyrolysis behaved differently. The shrinkage of the processed coals was quite different, the maximum volumetric shrinkage ratio at 1000{sup o}C as in the range of 32-38% with swelling ratios less than 5%, and the volumetric swelling ratio increased and the shrinkage ratio decreased with the increase of coal sample density. The maximum volumetric swelling ratio of the raw coals was more prominent than those of the processed coals. The raw coal A{sub 2} showed a maximum swelling ratio of 20-85% and the raw coal B{sub 2} showed a maximum swelling ratio of 25-45%. The volumetric swelling ratios decreased and the shrinkage increased with the decrease of the sample size. It is considered that the different pyrolysis behaviors were mainly due to the variation in their macroscopic structures. However, the similar swelling and shrinkage curves of coal samples were observed for the same raw or processed coals. In addition, the effect of volatile matter on the volumetric shrinkage ratios would be weakened if the raw coal was crushed into powder and then pressed into processed coal samples. Scanning electron microscope analysis showed that the structure of coke after pyrolysis was also different. 19 refs., 9 figs., 2 tabs.

  7. Characteristics of process oils from HTI coal/plastics co-liquefaction runs

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A. [and others

    1995-12-31

    The objective of this project is to provide timely analytical support to DOE`s liquefaction development effort. Specific objectives of the work reported here are presented. During a few operating periods of Run POC-2, HTI co-liquefied mixed plastics with coal, and tire rubber with coal. Although steady-state operation was not achieved during these brief tests periods, the results indicated that a liquefaction plant could operate with these waste materials as feedstocks. CONSOL analyzed 65 process stream samples from coal-only and coal/waste portions of the run. Some results obtained from characterization of samples from Run POC-2 coal/plastics operation are presented.

  8. Carbon Nanostructures Production by AC Arc Discharge Plasma Process at Atmospheric Pressure

    OpenAIRE

    Shenqiang Zhao; Ruoyu Hong; Zhi Luo; Haifeng Lu; Biao Yan

    2011-01-01

    Carbon nanostructures have received much attention for a wide range of applications. In this paper, we produced carbon nanostructures by decomposition of benzene using AC arc discharge plasma process at atmospheric pressure. Discharge was carried out at a voltage of 380 V, with a current of 6 A–20 A. The products were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), and Raman spectra. The results sho...

  9. Improving Processes of Mechanized Pulsed Arc Welding of Low-Frequency Range Variation of Mode Parameters

    Science.gov (United States)

    Saraev, Yu N.; Solodskiy, S. A.; Ulyanova, O. V.

    2016-04-01

    A new technology of low-frequency modulation of the arc current in MAG and MIG welding is presented. The technology provides control of thermal and crystallization processes, stabilizes the time of formation and crystallization of the weld pool. Conducting theoretical studies allowed formulating the basic criteria for obtaining strong permanent joints for high-duty structures, providing conditions for more equilibrium structure of the deposited metal and the smaller width of the HAZ. The stabilization of time of the formation and crystallization of the weld pool improves the formation of the weld and increases productivity in welding thin sheet metal.

  10. Aspects of plasma arc cutting process in the AISI 321 type stainless steel

    International Nuclear Information System (INIS)

    Some aspects of plasma arc cutting process in the AISI321 stainless steel, used in nuclear industry, are analysed. The maximum values of the velocity of cutting and, the minimum quantity of energy per unit of length necesary for the plasma were determined. The localization of irregularities in the cut surface in function of the velocity of cutting was investigated. The cut surfaces were evaluated by surface roughness, using as measurement parameter, the distance between the sharpest salience and the deepest reentrance of the sample profile. The width of layer from thermal action of the plasma was influenced by the velocity of cutting. (Author)

  11. Process Evaluation of Carbon Dioxide Capture for Coal-Fired Power Plants

    OpenAIRE

    Satoshi Kodama; Kazuya Goto; Hidetoshi Sekiguchi

    2014-01-01

    Carbon capture is a promising technology for carbon dioxide (CO2) removal from large stationary CO2 sources. The effects of carbon dioxide capture process on output efficiency of fossil power plants were investigated. Supercritical pulverized coal and integrated coal gasification combined cycle (IGCC) were assumed as model coal-fired power plants for this investigation. Heat-driven and pressure-driven CO2 capture processes such as chemical absorption and physical adsorption were assumed for C...

  12. Study of methanol-to-gasoline process for production of gasoline from coal

    Institute of Scientific and Technical Information of China (English)

    HE Tian-cai; CHENG Xiao-han; LI Ling; MENG Guo-ying

    2009-01-01

    The methanol-to-gasoline (MTG) process is an efficient way to produce liquid fuel.The academic basis of the coal-to-liquid process is described and two different syn-thesis processes are focused on: Fixed MTG process and Fluid Bed MTG process.Then,the superiority of the Fluid Bed MTG Process is pointed out relative to the Fixed MTG Process.In addition,the development of the coal-to-liquid technique in China is briefly summarized.

  13. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-01

    This report discusses the effects on SRC yields of seven process variables (reactor temperature, SRT, hydrogen partial pressure, recycle ash and coal concentrations, gas velocity and coal type) predicted by second-order regression models developed from a data base containing pilot plant data with both Kentucky and Powhatan coals. The only effect of coal type in the model is a shift in each yield by a constant factor. Although some differences were found between the models developed from the Kentucky data base (1) (which we call Kentucky models) and the pooled coal models, the general conclusions of the previous report are confirmed by the new models and the assumption of similar behavior of the two coals appears to be justified. In some respects the dependence of the yields (MAF coal basis) on variables such as pressure and temperature are clearer than in the previous models. The principal trends which emerge are discussed.

  14. Energetic and exergetic performance assessment of some coals in Turkey for gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Ozturk, M.; Ozek, N.; Yuksel, Y.E. [Suleyman Demirel University, Isparta (Turkey). Dept. of Physics

    2011-07-01

    This paper undertakes a study on energetic and exergetic performance evaluation of various types of coals in Turkey, such as Armutcuk, Amasra, Zonguldak and Catalagzi hard coals and Tuncbilek, Beypazari, Cayirhan, Afsin, Soma, Yatagan, Can and Sorgun lignites for gasification purposes, where syn-gas may subsequently be used for the production of electricity, heat, hydrogen, etc. in industry. The chemical exergy contents of these coals are determined and compared for a potential use in gasification, and their energetic and exergetic efficiencies are also assessed for performance comparison. In the analysis, exergetic efficiencies are evaluated for an idealised gasifier in which chemical equilibrium is reached, ashes of coals are not considered and heat losses are neglected. It is observed that coals having lower heating value have higher gasification efficiency, and the ratios of hydrogen to chemical exergy of coal are related to the gasification process efficiencies of this coal.

  15. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  16. Tectonic block rotation, arc curvature, and back-arc rifting: Insights into these processes in the Mediterranean and the western Pacific

    International Nuclear Information System (INIS)

    The fastest modern-day tectonic block rotations on Earth (up to 9 degrees/Myr) occur in the forearcs of convergent plate margins where a transition from collision of a bathymetric high to subduction of normal oceanic crust occurs. GPS techniques have enabled accurate documentation of the kinematics of these rotations, leading us to develop a conceptual model where the change from collision to subduction exerts a torque on microplates within the plate boundary zone, causing them to spin rapidly about an axis at the collision point. We have investigated geophysical and geological data from several active plate boundaries (from the western Pacific and Mediterranean regions) to document a compelling spatial and temporal relationship between the transition from collision to subduction, plate boundary curvature, and rapid tectonic block rotations. In some cases, these microplate rotations can initiate back-arc rifting. We also present numerical modelling results supporting our conceptual model for block rotations at collision/subduction transition. Our results suggest that the rate of microplate rotation depends on the incoming indentor velocity, and can be greatly enhanced by: (1) extensional stresses acting at the subduction interface (possibly due to slab roll back), and (2) a low-viscosity back-arc. Where viscosity of the back-arc is low, forearc microplate rotation dominates. In contrast, tectonic escape of strike-slip fault-bounded microplates is predicted in areas where the back-arc viscosity is high. Previous workers have suggested that the kinematics of the Anatolian block and back-arc rifting in the Aegean are influenced by some combination of forces associated with Arabia/Eurasia collision, and/or subduction (including slab rollback) at the Hellenic trench. Based on previous work from active western Pacific arcs, we propose that the collision of two separate indentors (Arabian promontory in the east, Apulian platform in the west), is a fundamental tectonic

  17. Effect of heat input on dilution and heat affected zone in submerged arc welding process

    Indian Academy of Sciences (India)

    Hari Om; Sunil Pandey

    2013-12-01

    Submerged arc welding (SAW) is a fusion joining process, known for its high deposition capabilities. This process is useful in joining thick section components used in various industries. Besides joining, SAW can also be used for surfacing applications. Heat Affected Zone (HAZ) produced within the base metal as a result of tremendous heat of arc is of big concern as it affects the performance of welded/surfaced structure in service due to metallurgical changes in the affected region. This work was carried out to investigate the effect of polarity and other SAW parameters on HAZ size and dilution and to establish their correlations. Influence of heat input on dilution and heat affected zone was then carried out. Four levels of heat input were used to study their effect on % dilution and HAZ area at both the electrode positive and electrode negative polarities. Proper management of heat input in welding is important, because power sources can be used more efficiently if one knows how the same heat input can be applied to get the better results. Empirical models have been developed using statistical technique.

  18. CHARACTERIZATION OF THE DUST GENERATED IN THE RECYCLING PROCESS OF THE ELECTRIC ARC FURNACE DUST

    Directory of Open Access Journals (Sweden)

    Fábio Gonçalves Rizz

    2013-10-01

    Full Text Available Electric Arc Furnace Dust (EAFD is a solid waste generated by the production of steel through the Electric Arc Furnace. This waste is labeled dangerous, which motivates studies aiming its recycling. Experiments were made to study a pyrometallurgical process for the recycling of the dust, using the insertion of dust briquettes in molten pig iron in three temperatures. In the briquettes, there were made additions of calcium fluoride in four different concentrations. This paper has the objective to characterize the dust that results from this process, verifying the influence of the temperature and the concentration of calcium fluoride in the briquette in the morphology and chemical composition of the new dust, determining the optimal conditions for the recovery of the zinc content of the dust. This newly generated dust was analyzed in an Scanning Electronic Microscope, used to capture micrographs and chemical composition by EDS. The micrographs show that the temperature and the calcium fluoride concentration interfere in the way the dust particles agglomerate. Chemical analysis points that the higher zinc recuperation occurrs in the experiments at 1500°C with 7% addition of calcium fluoride.

  19. Computerized processing of Kosovo Coal Basin on a study scale. [Yugoslavia

    Energy Technology Data Exchange (ETDEWEB)

    Jovicic, R.

    1983-01-01

    This paper is the first of a series dealing with the computerized processing of the Kosovo Coal Basin. A study programme was initiated requiring the collection and processing of material to form as comprehensive a data base as possible. The project did not include a detailed analysis of the information, which dealt with coal, overburden, hydrological conditions, land costs, compension for subsidence, communications, etc.

  20. The Origin of Voluminous Dacite (vs. Andesite) at Mature, Thick Continental Arcs: A Reflection of Processes in the Deep Crust

    Science.gov (United States)

    Lange, R. A.

    2013-12-01

    An outstanding question is why some continental arc segments are characterized by voluminous eruptions of dacite (65-70 wt% SiO2), whereas others erupt more andesite (58-64 wt% SiO2) than any other magma type. An example of the former is the Altiplano-Puna region of the central Andean arc, which has erupted a predominance of dacite over all magma types 10-1 Ma (de Silva, 1989). In contrast, a 200-km arc segment of the Mexican volcanic arc (Michoacán-Guanajuato arc segment) has erupted ~75% andesite, ~26% basaltic andesite and literature, it is proposed that the andesites were derived by partial melting (>20%) of hornblende-rich (~40%) gabbronorite in the deep crust, driven by mantle-derived basalt intrusions at depths of 30-40 km. The absence of any dacite or rhyolite along this arc segment indicates that interstitial liquid from crystal-rich andesites never segregated to form eruptible magma. Thus, little upper-crust differentiation occurred along this arc segment. On the basis of phase-equilibrium experiments in the literature (e.g., Sisson et al., 2005), it is proposed that rhyolite and dacite did form during partial melting of the lower arc crust, but at melt fractions too low (≤15%) to permit efficient transport to the upper crust (Vigneresse and Tikoff, 1999). It is further proposed that the reason why dacite is so abundant at mature thick continental arcs (e.g., Altiplano-Puno complex) may be because mantle-derived basalts are primarily emplaced at similar depths (~30-40 km) in continental arc crustal columns. If so, in the central Andean arc, a depth of 30-40 km is within the middle dioritic crust (Graeber and Asch, 1999). Partial melts of hornblende diorite (vs. hornblende gabbro) are predicted to be dacitic (vs. andesitic) at melt fractions of 20-25%, which permits transport to the upper crust. It is therefore proposed that it is deep crustal processes that determine whether andesite or dacite is the most voluminous magma type emplaced into the upper

  1. Prospects of LTC process of coal and pollutional potentiality of its wastewater

    International Nuclear Information System (INIS)

    Coal is one of the non-renewable energy sources and is available in plenty as a natural reserves in India. There are various technologies to convert coal into different forms of energy to be used for various purposes. Low temperature carbonization (LTC) of coal is one of the economically viable technology which is employed for low grade Indian coals to obtain the products, like domestic coke, tar, oil, etc. Some undesirable chemicals are also generated during LTC process of coal and get discharged into the environment in the form of liquid waste, Waste ammonia liquor (WAL). Such wastes are of environmental concern. Therefore, it is necessary to evaluate critically the prospects of LTC process of coal in Indian scenario, chemistry of different pollutants and pollutional potentiality of the wastewater. (author). 55 refs., 5 figs., 4 tabs

  2. COMPUTER PROCESSING OF MULTISPECTRAL SCANNER DATA OVER COAL STRIP MINES

    Science.gov (United States)

    There is little doubt that remote sensing techniques can be effectively applied to the task of monitoring coal strip mine progress and reclamation work. Aircraft multispectral scanner data acquired over six coal strip mines in the states of Wyoming, Montana, Colorado, and Arizona...

  3. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  4. Weldability of Nb steel by the submerged arc process, using national consumables, at high speed

    International Nuclear Information System (INIS)

    A set of procedures was established for welding of Nb micro-alloyed steel by the submerged arc process, using national consumables, in order to simultaneously achieve a more economic welding and better mechanical properties. By a series of experiments involuing seven flux-wire combinations, and three different welding conditions, the properties of the weldments were evalvated by means of mechanical tests (tension, bending and impact). Analysis of results was based on chemical composition and microstructure of the weldments. The influence of the consumables on microstructure and chemical composition was verified by relating the properties with the several flux-wire combinations. The possibility of determining the parameters satisfying the requirements of economic welding with a few tests was verified. The influence of welding parameters on wire consumption, basicity, activity and flux consumption was also determined. Finaly, given the difficulties usually encountered when selecting submerged arc consumables, the possibility was shown of establishing a systematic approach towards that purpose. From all the analyses and observations conclusion was obtained that for some of the flux-wire combinations considered, the proposed objectives were achieved. (Author)

  5. Study of the welding gas influence on a controlled short-arc GMAW process by optical emission spectroscopy

    OpenAIRE

    Wilhelm, G; Gött, G; Schöpp, H; Uhrlandt, D

    2010-01-01

    Abstract The controlled short arc processes, variants of the Gas Metal Arc Welding (GMAW) process, which have recently been developed, are used to reduce the heat input into the workpiece. Such a process with a wire feeding speed which varies periodically, using a steel wire and a steel workpiece to produce bead on plate welds has been investigated. As welding gases CO 2 and a mixture of Ar and O 2 have been used. Depending on the gas the properties of the plasma change, and as a consequen...

  6. Temporal geochemical trends in northern Luzon arc lavas (Philippines): implications on metasomatic processes in the island arc mantle

    International Nuclear Information System (INIS)

    Neogene and Quaternary lavas from Batan, Babuyan de Claro, Camiguin and Calayan islands (northern Luzon arc) display temporal increases in incompatible elements including Cs, Rb, Ba, K, La, Ce, Th, U, Ta, Hf and Zr from volcanoes older than 3 Ma to younger ones. These enrichments occur either within a single island (Batan) or within an island group (from Calayan to Camiguin and Babuyan). We show that these enrichments result from incompatible element input into the mantle wedge rather than from partial melting or fractionation effects. The fact that highly incompatible elements display temporal enrichment patterns in Batan lavas whatever their chemical properties indicates that hydrous fluids are not the only metasomatic agents operating in the mantle wedge and that slab-derived melts (adakitic magmas) may also be involved. The coupled temporal variation patterns of large ion lithophile elements and Sr-Nd isotopes suggest that the metasomatic budgets beneath the southern group of islands are mainly controlled by hydrous fluids inputs. In contrast, young Batan lavas likely derive from a mantle source mostly metasomatized by adakitic magmas. (authors)

  7. Dispersed catalysts for co-processing and coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bockrath, B.; Parfitt, D.; Miller, R. [Pittsburgh Energy Technology Center, PA (United States)

    1995-12-31

    The basic goal is to improve dispersed catalysts employed in the production of clean fuels from low value hydrocarbons. The immediate objective is to determine how the properties of the catalysts may be altered to match the demands placed on them by the properties of the feedstock, the qualities of the desired end products, and the economic constraints put upon the process. Several interrelated areas of the application of dispersed catalysts to co-processing and coal conversion are under investigation. The first involves control of the selectivity of MoS{sub 2} catalysts for HDN, HDS, and hydrogenation of aromatics. A second area of research is the development and use of methods to evaluate dispersed catalysts by means of activity and selectivity tests. A micro-flow reactor has been developed for determining intrinsic reactivities using model compounds, and will be used to compare catalysts prepared in different ways. Micro-autoclaves will also be used to develop data in batch experiments at higher partial pressures of hydrogen. The third area under investigation concerns hydrogen spillover reactions between MoS{sub 2} catalysts and carbonaceous supports. Preliminary results obtained by monitoring H{sub 2}/D{sub 2} exchange reactions with a pulse-flow microreactor indicate the presence of spillover between MoS{sub 2} and a graphitic carbon. A more complete study will be made at a later stage of the project. Accomplishments and conclusions are discussed.

  8. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    Energy Technology Data Exchange (ETDEWEB)

    Suardini, P.J. [Custom Coals, International, Pittsburgh, PA (United States)

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  9. Sulfur Isotopic Characteristics of Coal in China and Sulfur Isotopic Fractionation during Coal—burning Process

    Institute of Scientific and Technical Information of China (English)

    洪业汤; 张鸿斌; 等

    1993-01-01

    The determined results of the sulfur contents and isotopic composition of coal samples from major coal mines in 15 provinces and regions of China show that the coal mined in the north of China is characterized by higher 34S and lower sulfur content, but that in the south of China has lower 34S and higher sulfur content.During the coal-burning process in both indrstrial and daily use of coal as fuel the released sulfur dioxide is always enriched in lighter sulfur isotope relative to the corresponding coal;the particles are always enriched in heavier sulfur isotope.The discussion on the environmental geochemical significance of the above-mentioned results also has been made.

  10. A comparison of the economics of materials processing with solar furnaces and high-intensity arc lamps

    International Nuclear Information System (INIS)

    This paper reports on the cost and performance of treating materials with a solar furnace that were compared to similar treatment with high-intensity electric-arc lamps. Qualitative results indicate that because of the long focal length of the solar furnace, it is capable of performing much dirtier materials processing tasks than the arc lamp. Quantitative results indicate that if the furnace is located in a good solar region, the solar furnace can beat the economics of the lamp by as much as a factor of three under certain operating scenarios. In other scenarios, the lamp is more cost-effective. The scenario that appears most promising for the furnace is batch processing that employs flux levels near 500 W/cm2 or greater. At lower flux levels, or in assembly-line-type processing tasks, the arc lamp is preferred

  11. Detection of short circuit in pulse gas metal arc welding process

    Directory of Open Access Journals (Sweden)

    P.K.D.V. Yarlagadda

    2007-09-01

    Full Text Available Purpose: The paper discusses several methods of detecting occurrence of short circuit and short circuit severity in pulse gas metal arc welding process (GMAW-P.Design/methodology/approach: Welding experiments with different values of pulsing parameter and simultaneous recording of high speed camera pictures and welding signals (such as current and voltage were used to identify the occurrence of short circuit and its severity in GMAW-P process. The investigation is based on the measurement of welding signals specifically current and voltage signals and their synchronization with high speed camera to investigate the short circuit phenomenon in GMAW-P process.Findings: The results reveal that short circuit can be detected using signal processing techniques and its severity can be predicted by using statistical models and artificial intelligence techniques in GMAW-P process.Research limitations/implications: Several factors are responsible for short circuit occurrence in GMAW-P process. The results show that voltage and current signal carry rich information about the metal transfer and especially short circuit occurrence in GMAW-P process. Hence it’s possible to detect short circuit occurrence in GMAW-P process. Future work should concentrate on development of advance techniques to improve reliability of techniques mentioned in this paper for short circuit detection and prediction in GMAW-P process.Originality/value: For achieving atomization of the welding processes, implementation of real time monitoring of weld quality is essential. Specifically for GMAW-P process which is widely used for light weight metal which is widely gaining popularity in manufacturing industry. However, in case of GMAW-P process hardly any attempt is made to analyse techniques to detect and predict occurrence of short circuit. This paper analyses different techniques that can be employed for real time monitoring and prediction of short circuit and its severity in the

  12. Evaluation of stress-controlled coal swelling processes

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jishan; Chen, Zhongwei [Shool of Mechanical Engineering, The University of Western Australia, WA, 6009 (Australia); Elsworth, Derek [Department of Energy and Mineral Engineering, Penn State University, PA 16802-5000 (United States); Miao, Xiexing; Mao, Xianbiao [State Key Laboratory for Geomechanics and Underground Engineering, China University of Mining and Technology (China)

    2010-09-01

    Stress-controlled swelling tests are normally conducted in the laboratory to characterize the evolution of coal permeability under the influence of gas sorption. Typically reductions in permeability are observed from gas-sorption-induced swelling even where effective stresses remain constant. This behavior remains enigmatic as the permeability of the porous coal is determined by the effective stress only. When these observations were interpreted, a matchstick or cubic coal model was assumed. Under this assumption, matrix swelling would not affect coal permeability because of the complete separation between matrix blocks caused by through-going fractures. This is why current coal permeability models have little success in explaining this inconsistency. It is generally believed that the reason for the failure is the inconsistency between the experimental conditions and the model assumptions. However, in this paper, it is considered that the reason may be the internal actions between coal fractures and matrixes have not been taken into consideration. In this study, a model capable of replicating this apparently anomalous behavior is developed. We consider the interactions of the fractured coal mass where cleats do not create a full separation between adjacent matrix blocks but where solid rock bridges are present. We accommodate the role of swelling strains both over contact bridges that hold cleat faces apart but also over the non-contacting span between these bridges. The effects of swelling act competitively over these two components: increasing porosity and permeability due to swelling of the bridging contacts but reducing porosity and permeability due to the swelling of the intervening free-faces. Under these conditions, a new permeability model is formulated. The new model is the key cross link that couples the multiphysics of coal-gas interactions. The formulation and incorporation of this permeability model into the multiphysics simulation of coal

  13. Validation of the materials-process-product model (coal SNG). [Estimating method for comparing processes, changing assumptions and technology assessment

    Energy Technology Data Exchange (ETDEWEB)

    Albanese, A.; Bhagat, N.; Friend, L.; Lamontagne, J.; Pouder, R.; Vinjamuri, G.

    1980-03-01

    The use of coal as a source of high Btu gas is currently viewed as one possible means of supplementing dwindling natural gas supplies. While certain coal gasification processes have demonstrated technical feasibility, much uncertainty and inconsistency remains regarding the capital and operating costs of large scale coal conversion facilities; cost estimates may vary by as much as 50%. Studies conducted for the American Gas Association (AGA) and US Energy Research and Development Administration by C.F. Braun and Co. have defined technical specifications and cost guidelines for estimating costs of coal gasification technologies (AGA Guidelines). Based on the AGA Guidelines, Braun has also prepared cost estimates for selected coal gasification processes. Recent efforts by International Research and Technology Inc. (IR and T) have led to development of the Materials-Process-Product Model (MPPM), a comprehensive anaytic tool for evaluation of processes and costs for coal gasification and other coal conversion technologies. This validation of the MPPM presents a comparison of engineering and cost computation methodologies employed in the MPPM to those employed by Braun and comparison of MPPM results to Braun cost estimates. These comparisons indicate that the MPPM has the potential to be a valuable tool for assisting in the evaluation of coal gasification technologies.

  14. Alleviation of process-induced cracking of the antireflection TiN coating (ARC-TiN) in Al-Cu and Al-Cu-Si films

    CERN Document Server

    Peng, Y C; Yang, Y R; Hsieh, W Y; Hsieh, Y F

    1999-01-01

    The alleviation of cracking of the TiN-ARC layer on Al-Cu and Al-Cu-Si films after the development process has been achieved. For the TiN-ARC/Al-Cu system, the stress-induced defects decreased with increasing TiN-ARC layer thickness. In contrast, for the TiN-ARC/Al-Cu-Si system, Si nodules formed during cooling, thereby inducing poor coverage with high aspect-ratio holes. As a result, the photoresist developer penetrated through the films. Chemical vapor deposition of TiN-ARC or predeposition of a Ti Interposing layer was used to eliminate the formation of Si nodules.

  15. Alleviation of process-induced cracking of the antireflection TiN coating (ARC-TiN) in Al-Cu and Al-Cu-Si films

    International Nuclear Information System (INIS)

    The alleviation of cracking of the TiN-ARC layer on Al-Cu and Al-Cu-Si films after the development process has been achieved. For the TiN-ARC/Al-Cu system, the stress-induced defects decreased with increasing TiN-ARC layer thickness. In contrast, for the TiN-ARC/Al-Cu-Si system, Si nodules formed during cooling, thereby inducing poor coverage with high aspect-ratio holes. As a result, the photoresist developer penetrated through the films. Chemical vapor deposition of TiN-ARC or predeposition of a Ti Interposing layer was used to eliminate the formation of Si nodules

  16. Fractal characteristics of surface crack evolution in the process of gas-containing coal extrusion

    Institute of Scientific and Technical Information of China (English)

    Chen Peng; Wang Enyuan; Ou Jianchun; Li Zhonghui; Wei Mingyao; Li Xuelong

    2013-01-01

    In this paper,simulated experiment device of coal and gas outburst was employed to perform the experiment on gas-containing coal extrusion.In the experiment,coal surface cracks were observed with a highspeed camera and then the images were processed by sketch.Based on the above description,the paper studied the fractal dimension values from different positions of coal surface as well as their changing laws with time.The results show that there is a growing parabola treen of crack dimension value in the process of coal extrusion.Accordingly,we drew the conclusion that extruded coal crack evolution is a process of fractal dimension value increase.On the basis of factal dimension values taken from different parts of coal masses,a fractal dimension of the contour map was drawn.Thus,it is clear that the contour map involves different crack fractal dimension values from different positions.To be specific,where there are complicated force and violent movement In coal mass,there are higher fractal dimension values,i.e.,the further the middle of observation surface is from the exit of coal mass,and the lower the fractal dimension value is.In line with fractal geometry and energy theory of coal and gas outburst,this study presents the relation between fractal dimension and energy in the process of extruding.In conclusion,the evolution of crack fractal dimension value can signify that of energy,which has laid a solid foundation for the quantification research on the mechanism of gas-containing coal extrusion.

  17. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Dady Dadyburjor; Chong Chen; Elliot B. Kennel; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2006-02-23

    The purpose of this DOE-funded effort is to develop technologies for carbon products from coal-derived feedstocks. Carbon products can include precursor materials such as solvent extracted carbon ore (SECO) and synthetic pitch (Synpitch). In addition, derived products include carbon composites, fibers, foams and others. Key milestones included producing hydrogenated coal in the Hydrotreating Facility for the first time. The facility is now operational, although digital controls have not yet been completely wired. In addition, ultrasound is being used to investigate enhanced dissolution of coal. Experiments have been carried out.

  18. Measurement and modeling of advanced coal conversion processes, Volume II

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1993-06-01

    A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

  19. Membrane-integrated oxy-fuel combustion of coal: Process design and simulation

    NARCIS (Netherlands)

    Chen, Wei; Ham, van der A.G.J.; Nijmeijer, A.; Winnubst, A.J.A.

    2015-01-01

    A membrane-integrated oxy-fuel combustion process is designed and simulated in UniSim Design®. The results of the simulation indicate that a net efficiency of 31.8% is obtained for a coal-fired power plant of 182 MWth (assuming only carbon in the coal), including the compression of CO2 to 100 bar. T

  20. Proceedings of a workshop on the utilization of coal fuels in process heaters

    Energy Technology Data Exchange (ETDEWEB)

    1979-01-01

    Almost 5% of the nation's energy consumption takes place in tubular process heaters. Currently, these units are gas- and, to a lesser extent, oil-fired. Process heaters provide energy for refining petroleum and the manufacture of numerous chemicals and petrochemicals. Since the current state-of-the-art, using waste heat recovery and forced draft burners, can achieve thermal efficiencies of about 90%, it is unlikely that current process heat and fuel requirements will be dramatically reduced by process modifications and/or conservation measures. Hence, if this sizeable, inexorable drain on our fluid petroleum reserves is to be halted, it seems reasonable to consider the utilization of coal and/or coal-based fuels to fire process heaters. In order to assess the feasibility and potential for a coal-based process heater industry, Brookhaven National Laboratory (BNL) organized a workshop to define and explore the various problems that must be solved in order to burn coal in process heaters. A primary aim of the workshop was to consider the design methodology for process heaters when firing coal and compare it to those for gas and oil firing. The overall conclusions were: that retrofitting present process heaters to coal fuel was impractical; that it would be difficult to fit larger heaters designed to burn coal into present refineries; that there would be difficulties with process heaters burning coal; and that a better approach would be one large utility coal heater with a circulating heat transfer medium. Seven papers have been entered individually into EDB and ERA. (LTN)

  1. Processing and transformation of TiAl-base alloys: reactive sintering and classical arc melting

    International Nuclear Information System (INIS)

    This work aims at optimizing processing and transformation of TiAl two-phased alloys using today's powder metallurgy development. It is completed by testing the mechanical behavior of the alloys elaborated at the lab. The first part deals with the different ways of producing these intermetallics: reactive sintering of elemental powders, sintering and extrusion of the pre-alloyed powder or classical arc melting of pure metal. The extrusion optimization of the sintered alloy and the rolling of the TiAl ingot is studied in the second part. The titanium aluminides microstructure is detailed after applying different thermomechanical and heat treatments. The last part of the study devoted to the mechanical properties is supplied by the different statistical analysis methods of the obtained data. (author)

  2. Evaluation of the graphite electrode arc melter for processing heterogeneous waste

    Energy Technology Data Exchange (ETDEWEB)

    O' Connor, William K.; Turner, Paul C.; Soelberg, N.R. (Idaho National Engineering Laboratory); Anderson, G.L. (Idaho National Engineering Laboratory)

    1996-01-01

    The U.S. Bureau of Mines (USBM) conducted a series of 4 demonstration melting tests in a 3-phase AC graphite electrode arc furnace at its Albany Research Center (ALRC) thermal treatment facility in Albany, Oregon (now part of the U.S. Department of Energy, DOE). The scope of these tests provides a unique opportunity to evaluate a single melting technology regarding its applicability to the treatment of several different heterogeneous mixed wastes. The current system can continuously process combustible-bearing wastes at feedrates to 682 kg/h (1,500 lb/h), continuously tap slag or glass, and intermittently tap metal products, and includes a close-coupled thermal oxidizer and air pollution control system (APCS). The 4 demonstration melting tests were conducted in cooperation with the American Society of Mechanical Engineers (ASME), the Idaho National Engineering Laboratory (INEL), and the Westinghouse Hanford Company (WHC).

  3. In-flight oxidation of aluminum in the twin-wire electric arc process

    Science.gov (United States)

    Guillen, Donna Post; Williams, Brian G.

    2006-03-01

    This paper examines the in-flight oxidation of aluminum sprayed in air using the twin-wire electric arc (TWEA) thermal spray process. Aerodynamic shear at the droplet surface increases the amount of in-flight oxidation by promoting entrainment of the surface oxides within the molten droplet and continually exposing fresh fluid available for oxidation. Mathematical predictions herein confirm experimental measurements that reveal an elevated, nearly constant surface temperature (˜2273 K) of the droplets during flight. The calculated oxide volume fraction of a “typical” droplet with internal circulation compares favorably to the experimentally determined oxide content (3.3 12.7%) for a typical TWEA-sprayed aluminum coating sprayed onto a room temperature substrate. It is concluded that internal circulation within the molten aluminum droplet is a significant source of oxidation. This effect produces an oxide content nearly two orders of magnitude larger than that of a droplet without continual oxidation.

  4. Advanced coal conversion process demonstration. Technical progress report, April 1--June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high moisture, low rank coals to a high quality, low sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep bed stratifier cleaning process to separate the pyrite rich ash from the coal. The SynCoal process enhances low rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 Btu/lb, by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45 ton per hour unit is located adjacent to a unit train load out facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. During this report period the primary focus has been to continue the operation of the demonstration facility. Production has been going to area power plants. Modifications and maintenance work was also performed this quarter.

  5. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    Energy Technology Data Exchange (ETDEWEB)

    K. Osseo-Asare

    2000-06-02

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. The partitioning behavior of fly ash in the PEG-2000 Na{sub 2}SO{sub 4}/H{sub 2}O system was studied and the solid in each fraction was characterized by CHN analysis (carbon content), X-ray diffraction (XRD; crystal component), and inductively coupled plasma spectrophotometry (ICP; elemental composition in the ash). In the pH range from 2 to 5, the particles separated into two different layers, i.e., the polymer-rich (top) and salt-rich (bottom) layers. However, above pH 5, the particles in the polymer-rich phase split into two zones. The percent carbon content of the solids in the upper zone ({approximately}80 wt%) was higher than that in the parent sample (63.2 wt%), while the lower zone in the polymer-rich phase had the same percent ash content as the original sample. The particles in the salt-rich phase were mainly composed of ash (with < 4 wt% carbon content). However, when the solid concentration in the whole system increased from 1 wt% to 2 wt%, this 3-fraction phenomenon only occurred above pH 10. XRD results showed that the main crystal components in the ash included quartz, hematite, and mullite. The ICP results showed that Si, Al, and Fe were the major elements in the fly ash, with minor elements of Na, K, Ca, Mg, and Ba. The composition of the ash in the lower zone of the polymer-rich phase remained almost the same as that in the parent fly ash. The largest amount of product ({approximately}60% yield) with the highest carbon content ({approximately}80 wt% C) was obtained in the range pH 6-9. Based on the experimental results obtained, a flowsheet is proposed for the beneficiation of high-carbon fly ash with the aqueous biphase extraction process.

  6. Contribution of moving speed of vacuum arc cathode spot to the heat conduction process

    Science.gov (United States)

    Nagasawa, Chihiro; Yamamoto, Shinji; Iwao, Toru

    2015-11-01

    Thermal spraying has been widely used because it can give various functions by coating materials on the surface. It is necessary to remove an oxide layer and form a roughness. However, the blast has problems that occurs crushing and wear of the particles, and residual grid becomes a starting point of rust and peeling. The pretreatment with vacuum arc cathode spot is focused by this problem. Cathode spot with high energy density evaporates the oxide layer and melts the bulk for roughness. However, this process is believed that surface state is changed by the power density and sojourn time because the roughness depends on the location. It remains to be elucidated the formation factor of roughness and removal process. Therefore, the models of heat conduction process and vapor mixed affected by moving speed were proposed. To elucidate the formation factor of roughness and removal process, the contribution of moving speed to the heat conduction process is analyzed. As a result, the molten depth, width, and volume depend on the moving speed.

  7. Repair of power generation components by laser and plasma transferred arc processes: procedures and qualification

    International Nuclear Information System (INIS)

    The power generation industry in Australia recognises the need to develop procedure guidelines for metal deposition processes to protect valuable and critical components used in steam power plants. The components are typically used in boilers and regulating valves and can be subjected to a range of types of wear. Although many of the components examined were already deposited with specific alloys in specific areas, they still exhibited a high degree of wear. The project focused on worn components which were deemed to have reached the end of their operating life. The procedure guidelines and selection of materials for the deposition process are expected to provide the options for re-use of the critical components for additional and longer service life compared to the original design. Several metal deposition processes were initially identified as potential repair processes for the refurbishment of various components. Two processes, laser and plasma transferred arc (PTA) deposition, were selected for the study. Laboratory trials were carried out to examine the performance of the coating and then the actual parts were repaired based on the laboratory results. A company specialising in the laser cladding repair of engineering components carried out the repair of a number of power station components, which were subsequently returned to the relevant power stations for service evaluation. The paper discusses the research conducted and presents the procedures developed to assist local power generators in selection of the most appropriate materials and parameters for the repair of worn components.

  8. Investigation of processing properties of polyamide filled with hard coal

    OpenAIRE

    J. Stabik; Ł. Suchoń; M. Rojek; M. Szczepanik

    2009-01-01

    Purpose: The aim of this article is to present the influence of contents and kind of hard coal used as powder filler on rheological properties (viscosity) of polyamide 6.Design/methodology/approach: Preparation of composite of polyamide 6 with hard coal was carried out on laboratory twin screw extruder. Extruded composite was granulated and in this form was used for MFR analysis. Taking into account MFR results viscosity was calculated. The influence of filler content on viscosity was next se...

  9. Energy and Entropy Fluxes in Coal Gasification and Liquefaction Processes

    OpenAIRE

    H. Voigt

    1980-01-01

    In the long-term studies on energy systems performed at IIASA, scenarios that provide for substitutes for fossil oil and gas are considered. In the future coal is expected to contribute to energy supplies to a greatly increasing extent only if it is converted to liquid or gaseous fuels or electricity. Coal conversion systems are rather complex, not only internally but also with respect to their exchanges with the environment; some use auxiliary energy, others yield byproducts. Therefore, the ...

  10. Development of biological coal gasification (MicGAS Process)

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-28

    This report describes progress on three fronts of the project. First in studies to elucidate optimal growing conditions for the consortia of coal degraders employed indicates that best growth occurs with 0. 2% w/v Shefton T. Secondly in comparing the biodegradative properties of the coal degraders, isolates identified as Mic-1 and Mic-4 were the best performers. And lastly bioreactors studies in batch mode are related.

  11. Modern processes for Indian power plant coal beneficiation

    Energy Technology Data Exchange (ETDEWEB)

    Brinkman, F.; Schwerdtfeger, J.

    1997-12-31

    Presently in India 160 Mio tonnes per year of non-coking coal are mined for power generation, which have not been at all beneficiated until today. In order to beneficiate the whole amount of raw coal, an investment of approximately 45 billion Rupees is required. Due to the fact that the beneficiation costs are increasing drastically, when beneficiating finer material, it is recommended to wash in a first step the grainsize 400-30 mm only. This amounts to 110 Mio tonnes per year. The required beneficiation plants will need an investment of approximately 8 billion INR. The washed grain size {gt}40 mm, which is approximately 65% of the entire raw coal, dewaters without any mechanical assistance to 4% moisture. It can be crushed down and mixed with the unwashed fine coal without increasing the moisture content compared to the r.o.m. coal. For this duty - to wash the raw coal 400-30 mm - in close cooperation with Indian mining engineers the ROMJIG has been developed and tested during the operation. 3 figs.

  12. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    Energy Technology Data Exchange (ETDEWEB)

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  13. Digital-image Based Numerical Simulation on Failure Process of High-sulfur Coal

    Directory of Open Access Journals (Sweden)

    Ye Junjian

    2013-01-01

    Full Text Available Crushing of high-sulfur coal was important for physical desulfurization, but there were little research on crushing mechanism. This paper combined digital image processing technology and rock failure process analysis system RFPA2D to simulate the failure process of high-sulfur coal in Pu'an of Guizhou under uniaxial compression, and discussed the influence of horizontal restraint, existence and different geometric distribution of pyrite particle on mechanical performance and failure process of high-sulfur coal. The numerical results indicated that without horizontal restraint the compressive strength of high-sulfur coal was lower and monomial dissociation of pyrite particle was more sufficient than that with horizontal restraint. The compressive strength of coal containing pyrite particle was larger than that of pure coal and there was stress concentration in upper and lower pyrite particle during failure process. When pyrite particle distributed in the middle position of a coal sample, the compressive strength was higher than that of the other three positions, but monomial dissociation of pyrite particle was more sufficient than that of the other three positions, and this was beneficial to the following desulfurization operation. The study had certain reference value for crushing mechanism, crushing process design, selection of breaking equipment and energy saving and consumption reduction.

  14. Field study of disposed solid wastes from advanced coal processes

    International Nuclear Information System (INIS)

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells

  15. Visualizing the influence of the process parameters on the keyhole dimensions in plasma arc welding

    International Nuclear Information System (INIS)

    The keyhole status and its dimensions are critical information determining both the process quality and weld quality in plasma arc welding (PAW). It is of great significance to measure the keyhole shape and size and to correlate them with the main process parameters. In this study, a low-cost vision system is developed to visualize the keyhole at the backside of the test-pieces in PAW. Three stages of keyhole evolution, i.e. initial blind stage (non-penetrated keyhole), unstable stage with momentarily disappeared keyhole and quasi-steady open keyhole stage (fully-penetrated keyhole), are measured in real-time during the PAW tests on stainless steel test-pieces of thickness 8 mm. Based on the captured images of keyhole under different welding conditions, the correlations of the main welding process parameters (welding current, welding speed, plasma gas flow rate) with the keyhole length, width and area are visualized through vision measurement. It lays a solid foundation for implementing keyhole stability control and process optimization in keyhole PAW. (paper)

  16. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  17. Improving processes for coal gas desulfurization in foreign countries. Sovershenstvovanie protsessov seroochistki koksovogo gaza za rubezhom

    Energy Technology Data Exchange (ETDEWEB)

    Antipova, V.V.; Ukhmylova, G.S.

    1985-01-01

    Processes are comparatively evaluates for coal gas desulfurization developed in the FRG, the USA, United Kingdom and Japan. The following processes are described: the Vacuum-Carbonate process, the Sulfiban process, the Carl Still process, the Otto-Sulfammon process, the Takahax-Hirohax process, the Holmes-Stretford process and the Fumaks process. Flowsheets of desulfurization systems are shown. Desulfurization efficiency, content of hydrogen sulfide in coal gas after desulfurization, desulfurization cost and regeneration methods are analyzed. The Holmes-Stretford process and the Sulfiban process are characterized by the highest efficiency (hydrogen sulfide content in coal gas leaving desulfurization system is 0.115 g/m/sup 3/ and 0.15-0.16 g/m/sup 3/ respectively). The Claus sulfur recovery system is particularly economic. 21 references.

  18. Relationship between geometric welding parameters and optical-acoustic emissions from electric arc in GMAW-S process

    Directory of Open Access Journals (Sweden)

    E. Huanca Cayo

    2011-05-01

    Full Text Available Purpose: Show the relationship between geometric characteristics of the weld bead and the optical-acoustic emissions from electric arc during welding in the GMAW-S process.Design/methodology/approach: Bead on plate welding experiments was carried out setting different process parameters. Every welding parameter group was set aiming to reach a high stability level what guarantee a geometrical uniformity in the weld beads. In each experiment was simultaneously acquired arc voltage, welding current, infrared and acoustic emissions; from them were computed parameters as arc power, acoustic peaks rate and infrared radiation rate. It was used a tri-dimensional LASER scanner for to acquire geometrical information from the weld beads surface as width and height of the bead. Depth penetration was measured from sectional cross cutting of weld beads.Findings: Previous analysis showed that the arc emission parameters reach a stationary state with different characteristic for each experiment group which means that there is some correlation level between them. Posterior analysis showed that from infrared parameter is possible to monitoring external weld bead geometry and principally its penetration depth. From acoustic parameter is possible to monitoring principally the external weld bead geometry. Therefore is concluded that there is a close relation between the arc emissions and the weld bead geometry and that them could be used to measuring the welding geometrical parameters.Research limitations/implications: After analysis it was noticed that the infrared sensing has a better performance than acoustic sensing in the depth penetration monitoring. Infrared sensing also sources some information about external geometric parameters that in conjunction with the acoustic sensing is possible to have reliable information about weld bead geometry. This method of sensing geometric parameters could be applied in other welding processes, but is necessary to have

  19. PRODUCTION OF FOAMS, FIBERS AND PITCHES USING A COAL EXTRACTION PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Chong Chen; Elliot B. Kennel; Liviu Magean; Pete G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-06-20

    This Department of Energy National Energy Technology Laboratory sponsored project developed processes for converting coal feedstocks to carbon products, including coal-derived pitch, coke foams and fibers based on solvent extraction processes. A key technology is the use of hydrogenation accomplished at elevated temperatures and pressures to obtain a synthetic coal pitch. Hydrogenation, or partial direct liquefaction of coal, is used to modify the properties of raw coal such that a molten synthetic pitch can be obtained. The amount of hydrogen required to produce a synthetic pitch is about an order of magnitude less than the amount required to produce synthetic crude oil. Hence the conditions for synthetic pitch production consume very little hydrogen and can be accomplished at substantially lower pressure. In the molten state, hot filtration or centrifugation can be used to separate dissolved coal chemicals from mineral matter and insolubles (inertinite), resulting in the production of a purified hydrocarbon pitch. Alternatively, if hydrogenation is not used, aromatic hydrocarbon liquids appropriate for use as precursors to carbon products can obtained by dissolving coal in a solvent. As in the case for partial direct liquefaction pitches, undissolved coal is removed via hot filtration or centrifugation. Excess solvent is boiled off and recovered. The resultant solid material, referred to as Solvent Extracted Carbon Ore or SECO, has been used successfully to produce artificial graphite and carbon foam.

  20. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    Energy Technology Data Exchange (ETDEWEB)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  1. Development of processes for the utilization of Brazilian coal using nuclear process heat and/or nuclear process steam

    International Nuclear Information System (INIS)

    Status of the project: End of the project definition phase and preparation of the planned conceptual phase. Objective of the project: Development of processes for the utilization of nuclear process heat and/or nuclear process steam for the gasification of coal with high ash content, in particular coal from Brazil. Results: With the data of Brazilian coal of high ash content (mine Leao/ 43% ash in the mine-mouth quality, 20% ash after preparation) there have been worked out proposals for the mine planning and for a number of processes. On the basis of these proposals and under consideration of the main data specified by the Brazilian working group there have been choosen two processes and worked out in a conceptual design: 1) pressurized water reactor + LURGI-pressure gasifier/hydrogasification for the production of SNG and 2) high temperature reactor steam gasification for the production of town gas. The economic evaluation showed that the two processes are not substantially different in their cost efficiency and they are economical on a long-term basis. For more specific design work there has been planned the implementation of an experimental programme using the semi-technical plants 'hydrogasification' in Wesseling and 'steam gasification' in Essen as the conceptual phase. (orig.)

  2. Effect of annealing process on TiN/TiC bilayers grown by pulsed arc discharge

    International Nuclear Information System (INIS)

    In this work, a study of annealing process effect on TiN/TiC bilayer is presented. The annealing temperature was varied between room temperature and 500 °C. Materials were produced by the plasma-assisted pulsed vacuum arc discharge technique. In order to grow the films, a target of Ti with 99.9999% purity and stainless-steel 304 substrate were used. For the production of TiN layer, the reaction chamber was filled up with nitrogen gas until reaching 25 Pa and the discharge was performed at 310 V. The TiC layer was grown in a methane atmosphere at 30 Pa and 270 V. X-ray diffraction and X photoelectron spectroscopy were employed for studying the structure and chemical composition evolution during the annealing process. At 400 °C, TiO2 phase begun to appear and it was well observed at 500 °C. Crystallite size and microstrain was obtained as a function of the annealing temperature. XPS technique was employed for analyzing the bilayers before and after the annealing process. Narrow spectra of Ti2p, N1s and O1s were obtained, presenting TiO phases.

  3. Amenability to dry processing of high ash thermal coal using a pneumatic table

    Institute of Scientific and Technical Information of China (English)

    Dey Shobhana; Gangadhar B.; Gopalkrishna S.J.

    2015-01-01

    High ash thermal coal from India was used to conduct the dry processing of fine coal using a pneumatic table to evolve a techno-economically novel technique. The fine as-received sample having 55.2%ash was subjected to washability studies at variant densities from 1.4 to 2.2 to assess the amenability to separa-tion. The experiments were conducted using a central composite design for assessing the interactive effects of the variable parameters of a pneumatic table on the product yield and ash content. The perfor-mance of the pneumatic table was analyzed in terms of clean coal yield, recovery of combustibles, separation efficiency (Esp) and useful heat value of clean coal. The combustibles of clean coal obtained through a single stage operation at 35% and 38.7% ash were 40% and 63% respectively. However, the two stage processing was more effective in reducing the ash content in the clean coal. The rougher con-centrate generated at higher ash level was subsequently processed in different conditions at 35% ash level, and 58%combustibles could be recovered. Hence, two stage processing increases the combustibles by 18 units and the useful heat value of clean coal increases from 1190 kcal/kg to 3750 kcal/kg.

  4. Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, R.M.; Miller, R.L.

    1991-12-01

    The findings in the first phase were as follows: 1. Both reductive (non-selective) alkylation and selective oxygen alkylation brought about an increase in liquefaction reactivity for both coals. 2. Selective oxygen alkylation is more effective in enhancing the reactivity of low rank coals. In the second phase of studies, the major findings were as follows: 1. Liquefaction reactivity increases with increasing level of alkylation for both hydroliquefaction and co-processing reaction conditions. 2. the increase in reactivity found for O-alkylated Wyodak subbituminous coal is caused by chemical changes at phenolic and carboxylic functional sites. 3. O-methylation of Wyodak subbituminous coal reduced the apparent activation energy for liquefaction of this coal.

  5. Enhanced ultrafine coal dewatering using flocculation filtration processes

    Energy Technology Data Exchange (ETDEWEB)

    Tao, D.; Groppo, J.G.; Parekh, B.K. [University of Kentucky, Lexington, KY (USA). Dept. of Mining Engineering

    2000-02-01

    A comparative flocculation filtration study was performed for enhancing dewatering of ultrafine coal using vacuum, hyperbaric and centrifugal filters. The cationic and anionic flocculants were added into the slurry individually or in combinations. Vacuum filtration results showed that use of flocculants increased filtration rate by several times and/or substantially reduced cake moisture. Combined use of anionic and cationic flocculants showed further improvement. Addition of flocculants significantly increased filtration rate of hyperbaric filtration and reduced cake moisture in centrifugal filtration. Anionic flocculant was more effective in enhancing fine coal dewatering than cationic flocculant in vacuum filtration while cationic flocculant was more effective in high shear centrifugal filtration. A new approach on using flocculants in vacuum filtration is proposed for enhanced fine coal dewatering. 11 refs., 6 figs.

  6. Fine coal cleaning via the micro-mag process

    Science.gov (United States)

    Klima, Mark S.; Maronde, Carl P.; Killmeyer, Richard P.

    1991-01-01

    A method of cleaning particulate coal which is fed with a dense medium slurry as an inlet feed to a cyclone separator. The coal particle size distribution is in the range of from about 37 microns to about 600 microns. The dense medium comprises water and ferromagnetic particles that have a relative density in the range of from about 4.0 to about 7.0. The ferromagnetic particles of the dense medium have particle sizes of less than about 15 microns and at least a majority of the particle sizes are less than about 5 microns. In the cyclone, the particulate coal and dense-medium slurry is separated into a low gravity product stream and a high gravity produce stream wherein the differential in relative density between the two streams is not greater than about 0.2. The low gravity and high gravity streams are treated to recover the ferromagnetic particles therefrom.

  7. Thermo-mechanical analysis of Wire and Arc Additive Layer Manufacturing process on large multi-layer parts

    OpenAIRE

    Ding, J.; Colegrove, Paul A.; Mehnen, Jorn; Ganguly, Supriyo; Sequeira Almeida, P. M.; Wang, F.; Williams, Stewart W.

    2011-01-01

    Wire and Arc Additive Layer Manufacturing (WAALM) is gaining increasing popularity as the process allows the production of large custom-made metal workpieces with high deposition rates. The high power input of the welding process, causes significant residual stress and distortion of the workpiece. This paper describes the thermo-mechanical behaviour of the multi-layer wall structure made by the WAALM process. A 3D thermo-elastic–plastic transient model and a model based on a...

  8. Activities of the Institute of Chemical Processing of Coal at Zabrze

    Energy Technology Data Exchange (ETDEWEB)

    Dreszer, K.

    1995-12-31

    The Institute of Chemical Processing of Coal at Zabrze was established in 1955. The works on carbochemical technologies have been, therefore, carried out at the Institute for 40 years. The targets of the Institute`s activities are research, scientific and developing works regarding a sensible utilization of fuels via their processing into more refined forms, safe environment, highly efficient use of energy carriers and technological products of special quality. The Institute of Chemical Processing of Coal has been dealing with the following: optimized use of home hard coals; improvement of classic coal coking technologies, processing and utilization of volatile coking products; production technologies of low emission rate fuels for communal management; analyses of coal processing technologies; new technologies aimed at increasing the efficiency of coal utilization for energy-generating purposes, especially in industry and studies on the ecological aspects of these processes; production technologies of sorbents and carbon activating agents and technologies of the utilization; rationalization of water and wastes management in the metallurgical and chemical industries in connection with removal of pollution especially dangerous to the environment from wastes; utilization technologies of refined materials (electrode cokes, binders, impregnating agents) for making electrodes, refractories and new generation construction carbon materials; production technologies of high quality bituminous and bituminous and resin coating, anti-corrosive and insulation materials; environmentally friendly utilization technologies for power station, mine and other wastes, and dedusting processes in industrial gas streams.

  9. Deposição por plasma com arco transferido Hardfacing by plasma transfer arc process

    Directory of Open Access Journals (Sweden)

    Víctor Vergara Díaz

    2010-03-01

    Full Text Available Em virtude do Processo de Soldagem Plasma com Alimentação de Pó ter similaridades com o Processo de Soldagem Plasma com Alimentação de Arame, foi realizado um estudo comparativo entre ambos os processos utilizando-se a liga a base de cobalto comercialmente conhecida como Stellite 6, como material de adição na forma de pó e arame. A pesquisa foi realizada com a expectativa de ser aplicada nas operações de revestimentos de superfícies, em especial em pás de turbinas hidráulicas desgastadas por cavitação. A seleção do material de adição a ser empregado depende da natureza do mecanismo de desgaste encontrado. No Labsolda, a liga Stellite 6 vem sendo uma das mais utilizadas, por apresentar uma excelente resistência ao desgaste erosivo por cavitação. Foi avaliada a influência da vazão de gás de plasma a partir dos valores de diluição, dimensões do cordão, dureza e microestrutura. O Processo de Soldagem Plasma com Alimentação de Pó foi o que produziu o melhor acabamento superficial, menor diluição, melhor molhamento e maior largura. Com isto abre-se uma nova perspectiva para revestimentos metálicos e neste contexto se insere a recuperação por soldagem de partes erodidas de turbinas hidráulicas.The Plasma powder transferred arc welding process, which uses feed stock in the powder form, has similarities with Plasma wire transferred arc welding. This work describes a comparative study of the two processes using a Cobalt-based alloy commercially known as Stellite 6. This Co-based alloy is recognized for its superior cavitation erosion resistance. The aim of this work is to investigate the potential of PTA coatings for the protection and refurbishiment hydraulic turbine blades. Coatings were evaluated for the influence of Plasma gas flow rate on coating dilution, geometry, hardness and microstructure. Coatings processed with the atomized Stellite 6 powder feestock showed a superior surface quality, lower dilution

  10. Flotation machine and process for removing impurities from coals

    Science.gov (United States)

    Szymocha, Kazimierz; Ignasiak, Boleslaw; Pawlak, Wanda; Kulik, Conrad; Lebowitz, Howard E.

    1995-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  11. Modeling and optimization of processes for clean and efficient pulverized coal combustion in utility boilers

    OpenAIRE

    Belošević Srđan V.; Tomanović Ivan D.; Crnomarković Nenad Đ.; Milićević Aleksandar R.; Tucaković Dragan R.

    2016-01-01

    Pulverized coal-fired power plants should provide higher efficiency of energy conversion, flexibility in terms of boiler loads and fuel characteristics and emission reduction of pollutants like nitrogen oxides. Modification of combustion process is a cost-effective technology for NOx control. For optimization of complex processes, such as turbulent reactive flow in coal-fired furnaces, mathematical modeling is regularly used. The NOx emission reduction by c...

  12. Prototype plant for nuclear process heat (PNP) - operation of the pilot plant for hydrogasification of coal

    International Nuclear Information System (INIS)

    The Rheinische Braunkohlenwerke AG developed the process of hydrogasification of coal in a fluidized bed for generation of SNG. On basis of test results obtained in a semi-technical pilot plant of a through-put of 250 kg/h dried coal a large pilot plant was erected processing 10 t/h dried brown coal. This plant was on stream for about 14700 h, of which about 7800 h were with gasifier operation; during this time about 38000 t of dried brown coal of the Rhenish district were processed containing 4 to 25% of ash. At pressures of 60 to 120 bar and temperatures of 800 to 9350C carbon conversion rates up to 81 percent and methane amounts of 5000 m3 (STP)/h were reached. The decisive parameter for methane generation was the hydrogen/coal-ratio. Even at high moisture contents, usually diminishing the methane yield from the coal essentially, by high hydrogen/coal-ratios high methane yields could be obtained. The gasifier itself caused no troubles during the total time operation. Difficulties with the original design of the residual char cooler could be overcome by change-over from water injection to liquid carbon dioxide. The design of the heat recovery system proved well. Alltogether so the size increasement of the gasifier from the semi-technical to the large pilot plant as well as the harmonization of gas generation and gas refining was proved. (orig.) With 20 refs., 20 tabs., 81 figs

  13. Analysis and application of partial least square regression in arc welding process

    Institute of Scientific and Technical Information of China (English)

    YANG Hai-lan; CAI Yan; BAO Ye-feng; ZHOU Yun

    2005-01-01

    Because of the relativity among the parameters, partial least square regression(PLSR)was applied to build the model and get the regression equation. The improved algorithm simplified the calculating process greatly because of the reduction of calculation. The orthogonal design was adopted in this experiment. Every sample had strong representation, which could reduce the experimental time and obtain the overall test data. Combined with the formation problem of gas metal arc weld with big current, the auxiliary analysis technique of PLSR was discussed and the regression equation of form factors (i.e. surface width, weld penetration and weld reinforcement) to process parameters(i.e. wire feed rate, wire extension, welding speed, gas flow, welding voltage and welding current)was given. The correlativity structure among variables was analyzed and there was certain correlation between independent variables matrix X and dependent variables matrix Y. The regression analysis shows that the welding speed mainly influences the weld formation while the variation of gas flow in certain range has little influence on formation of weld. The fitting plot of regression accuracy is given. The fitting quality of regression equation is basically satisfactory.

  14. Recovery of Zn from acid mine water and electric arc furnace dust in an integrated process.

    Science.gov (United States)

    Carranza, Francisco; Romero, Rafael; Mazuelos, Alfonso; Iglesias, Nieves

    2016-01-01

    In this paper, the purification of acid mine water and the treatment of electric arc furnace dust (EAFD) are integrated into one process with the aim of recovering the Zn content of both effluent and waste. Zinc recovery can reduce the cost of their environmental management: purified acid mine water is discharged after removing all metals; EAFD ceases to be hazardous waste; and Zn is valorised. The process consists of the recovery of Zn as zinc oxide and its purification into commercial products. First, EAFD is leached with acid water and the dissolved metals are selectively precipitated as hydroxides. After EADF leaching, ferrous iron is bio-oxidized and Fe and Al are then precipitated; in the following stage, Cu, Ni, Co and Cd are cemented and finally Zn is precipitated as ZnO. In order to purify water that finally is discharged to a river, lime is used as the neutralizing agent, which results in a precipitate of mainly gypsum, MnO, and ZnO. From the impure zinc oxide produced, various alternatives for the attainment of commercial products, such as basic zinc carbonate and electrolytic zinc, are studied in this work. PMID:26433358

  15. Development of processes for zircaloy chips recycling by electric arc furnace remelting and powder metallurgy

    International Nuclear Information System (INIS)

    PWR reactors employ, as nuclear fuel, UO2 pellets with Zircaloy clad. In the fabrication of fuel element parts, machining chips from the alloys are generated. As the Zircaloy chips cannot be discarded as ordinary metallic waste, the recycling of this material is important for the Brazilian Nuclear Policy, which targets the reprocess of Zircaloy residues for economic and environmental aspects. This work presents two methods developed in order to recycle Zircaloy chips. In one of the methods, Zircaloy machining chips were refused using an electric-arc furnace to obtain small laboratory ingots. The second one uses powder metallurgy techniques, where the chips were submitted to hydriding process and the resulting material was milled, isostatically pressed and vacuum sintered. The ingots were heat-treated by vacuum annealing. The microstructures resulting from both processing methods were characterized using optical and scanning electron microscopy. Chemical composition, crystal phases and hardness were also determined. The results showed that the composition of recycled Zircaloy comply with the chemical specifications and presented adequate microstructure for nuclear use. The good results of the powder metallurgy method suggest the possibility of producing small parts, like cladding end-caps, using near net shape sintering. (author)

  16. An evaluation of Substitute natural gas production from different coal gasification processes based on modeling

    International Nuclear Information System (INIS)

    Coal and lignite will play a significant role in the future energy production. However, the technical options for the reduction of CO2 emissions will define the extent of their share in the future energy mix. The production of synthetic or substitute natural gas (SNG) from solid fossil fuels seems to be a very attractive process: coal and lignite can be upgraded into a methane rich gas which can be transported and further used in high efficient power systems coupled with CO2 sequestration technologies. The aim of this paper is to present a modeling analysis comparison between substitute natural gas production from coal by means of allothermal steam gasification and autothermal oxygen gasification. In order to produce SNG from syngas several unit operations are required such as syngas cooling, cleaning, potential compression and, of course, methanation reactors. Finally the gas which is produced has to be conditioned i.e. removal of unwanted species, such as CO2 etc. The heat recovered from the overall process is utilized by a steam cycle, producing power. These processes were modeled with the computer software IPSEpro™. An energetic and exergetic analysis of the coal to SNG processes have been realized and compared. -- Highlights: ► The production of SNG from coal is examined. ► The components of the process were simulated for integrated autothermal or allothermal coal gasification to SNG. ► The energetic and exergetic evaluation of the two processes is presented.

  17. Subtask 3.9 - Direct Coal Liquefaction Process Development

    Energy Technology Data Exchange (ETDEWEB)

    Aulich, Ted; Sharma, Ramesh

    2012-07-01

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  18. Environmental impacts of brown coal surface mining and processing

    International Nuclear Information System (INIS)

    The proceedings contain 9 contributions, out of which 2 have been inputted in INIS. These are concerned with the impacts of mining in the North Bohemian Brown Coal Mining District on the air quality and public health, and with the effect of mined-out land reclamation on the environment. (M.D.). 8 tabs., 5 figs., 6 refs

  19. Change in surface characteristics of coal in upgrading of low-rank coals; Teihin`itan kaishitsu process ni okeru sekitan hyomen seijo no henka

    Energy Technology Data Exchange (ETDEWEB)

    Oki, A.; Xie, X.; Nakajima, T.; Maeda, S. [Kagoshima University, Kagoshima (Japan). Faculty of Engineering

    1996-10-28

    With an objective to learn mechanisms in low-rank coal reformation processes, change of properties on coal surface was discussed. Difficulty in handling low-rank coal is attributed to large intrinsic water content. Since it contains highly volatile components, it has a danger of spontaneous ignition. The hot water drying (HWD) method was used for reformation. Coal which has been dry-pulverized to a grain size of 1 mm or smaller was mixed with water to make slurry, heated in an autoclave, cooled, filtered, and dried in vacuum. The HWD applied to Loy Yang and Yallourn coals resulted in rapid rise in pressure starting from about 250{degree}C. Water content (ANA value) absorbed into the coal has decreased largely, with the surface made hydrophobic effectively due to high temperature and pressure. Hydroxyl group and carbonyl group contents in the coal have decreased largely with rising reformation treatment temperature (according to FT-IR measurement). Specific surface area of the original coal of the Loy Yang coal was 138 m{sup 2}/g, while it has decreased largely to 73 m{sup 2}/g when the reformation temperature was raised to 350{degree}C. This is because of volatile components dissolving from the coal as tar and blocking the surface pores. 2 refs., 4 figs.

  20. Fundamental research on novel process alternatives for coal gasification: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  1. A simple process modelling for a dry-feeding entrained bed coal gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Lee, H.; Choi, S.; Paek, M. [Korean Advanced Institute of Science & Technology, Taejon (Republic of Korea). Dept. of Mechanical Engineering

    2011-07-01

    A dry-feeding entrained bed coal gasifier was numerically modelled by simultaneously solving the rate equations for chemical reactions of the solid and gas phases. This model describes simplified physical and chemical processes in the entrained bed coal gasifier. Chemical reaction processes for coal gasification and combustion are considered along with the simplified gas flow passage in the reactor, so that progress of reactions at the designated spatial location is represented. Gasification phenomena of coal particles were separated into devolatilization, gas-phase, and solid-phase reactions. Coal gasifier geometry was simplified to a pseudo-two-dimensional (pseudo-2D) reactor model based on the 1D plug flow concept. The dimension in the pseudo-2D model was conceptually divided by considering the recirculation effect. As a result, carbon conversion, cold gas efficiency, and temperature distribution were obtained at variable oxygen to coal mass ratio, steam to coal mass ratio, and operating pressure. Operating conditions could be appropriately controlled by knowing the degree of reaction in the reactor.

  2. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  3. Integrated coal preparation and CWF processing plant: Conceptual design and costing

    Energy Technology Data Exchange (ETDEWEB)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. (Science Applications International Corp., McLean, VA (United States)); Korkmaz, M. (Roberts and Schaefer Co., Salt Lake City, UT (United States))

    1992-12-01

    At the request of the US Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information, a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The design output of the integrated plant is 200 tons of coal (dry basis) per hour. Operating at a capacity factor of 83 percent, the baseline design yields approximately 1.5 million tons per year of coal on a dry basis. This is approximately equivalent to the fuel required to continuously generate 500 MW of electric power. The CWF produced by the plant is intended as a replacement for heavy oil or gas in electric utility and large industrial boilers. The particle size distribution, particularly the top size, and the ash content of the coal in the CWF are specified at significantly lower levels than is commonly found in typical pulverized coal grinds. The particle top size is 125 microns (vs typically 300m[mu] for pulverized coal) and the coal ash content is 3.8 percent. The lower top size is intended to promote complete carbon burnout at less derating in boilers that are not designed for coal firing. The reduced mineral matter content will produce ash of very fine particle size during combustion, which leads to less impaction and reduced fouling of tubes in convective passages.

  4. Integrated coal preparation and CWF processing plant: Conceptual design and costing. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. [Science Applications International Corp., McLean, VA (United States); Korkmaz, M. [Roberts and Schaefer Co., Salt Lake City, UT (United States)

    1992-12-01

    At the request of the US Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information, a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The design output of the integrated plant is 200 tons of coal (dry basis) per hour. Operating at a capacity factor of 83 percent, the baseline design yields approximately 1.5 million tons per year of coal on a dry basis. This is approximately equivalent to the fuel required to continuously generate 500 MW of electric power. The CWF produced by the plant is intended as a replacement for heavy oil or gas in electric utility and large industrial boilers. The particle size distribution, particularly the top size, and the ash content of the coal in the CWF are specified at significantly lower levels than is commonly found in typical pulverized coal grinds. The particle top size is 125 microns (vs typically 300m{mu} for pulverized coal) and the coal ash content is 3.8 percent. The lower top size is intended to promote complete carbon burnout at less derating in boilers that are not designed for coal firing. The reduced mineral matter content will produce ash of very fine particle size during combustion, which leads to less impaction and reduced fouling of tubes in convective passages.

  5. Neuronet Modelling of the Processes of Budgeting and Use of Labour Resources at Coal Mining Enterprises

    Directory of Open Access Journals (Sweden)

    Hlіnska Olha M.

    2014-01-01

    Full Text Available The article considers issues of efficient budgeting and use of labour resources at coal mining enterprises. It proves expediency of use of modern neuronet, namely, multilayer perceptron, for solution of tasks of modelling the process of budgeting and use of labour resources at coal mining enterprises. It shows that Statistika is the best software package for creation of neuronets of the multilayer perceptron architecture. On the basis of analysis and comparative characteristic the article selects the topology and builds a neuronet model of budgeting and use of labour resources at coal mining enterprises.

  6. A comparison of thermal conversion process for several coal tar pitches

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Y.; Shui, H.; Yuan, X. [East China Metallurgical Institute, Ma`anshan (China)

    1995-03-01

    The property and constituents of coal tar pitch are of great importance to the production of raw material for needle coke. Structural constituents of five coal tar pitches were determined using {sup 1}H-NMR. Besides, thermal conversion process of these pitches in which primary quinoline in soluble fraction was removed by centrifugal separation method was also investigated. The experimental results show Baogang (I) and Meishan coal tar pitches meet the requirements of raw material for needle coke. The thermal conversion data was correlated with structural parameters. 6 refs.,1 fig., 1 tab.

  7. Sensoring Fusion Data from the Optic and Acoustic Emissions of Electric Arcs in the GMAW-S Process for Welding Quality Assessment

    Directory of Open Access Journals (Sweden)

    Eber Huanca Cayo

    2012-05-01

    Full Text Available The present study shows the relationship between welding quality and optical-acoustic emissions from electric arcs, during welding runs, in the GMAW-S process. Bead on plate welding tests was carried out with pre-set parameters chosen from manufacturing standards. During the welding runs interferences were induced on the welding path using paint, grease or gas faults. In each welding run arc voltage, welding current, infrared and acoustic emission values were acquired and parameters such as arc power, acoustic peaks rate and infrared radiation rate computed. Data fusion algorithms were developed by assessing known welding quality parameters from arc emissions. These algorithms have showed better responses when they are based on more than just one sensor. Finally, it was concluded that there is a close relation between arc emissions and quality in welding and it can be measured from arc emissions sensing and data fusion algorithms.

  8. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    Directory of Open Access Journals (Sweden)

    Kartika K. Hendratna

    2010-01-01

    Full Text Available Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory scale furnace for more stable of combustion. Approach: New way for preparation for liquid coal oil steady combustion on a 2.75 m horizontal boiler with four annular segment tubes, a water jacket system and a system for measurement of water temperature inside was archived. Data was gained by applying liquid coal in the experiment. Detailed preparation and setting for steady combustion of coal oil and formation of the exhaust gas were discussed based on data sampling from four sample points in each centre of the angular tube segments. Results: Preparation for coal oil combustion is an important point in the successful of combustion. Heating coal fuel to than 100°C, heating the fuel line to the same temperature and providing enough air pressure for atomization of coal oil until 0.1 MPa allows coal fuel smoothly atomized in the semi gas phase. There was enough of air combustion via a blower with 4500 L min-1 of flow rate and a 24 L min-1 of water flow rate in the water jacket transforms the energy of the fuel to the heat. Uncolored of the exhaust gas and the physical inspection describes the completion of combustion. This result close-relates with the pollutants formation in the exhaust gas. Conclusion: By conducting a deep research process, there is a chance for the substitute of heavy fuel oil with liquid coal fuel with no special treatment needed in combustion process without ignoring the contribution of the combustion results as an environmental problem.

  9. Evaluation of Structural Changes in the Coal Specimen Heating Process and UCG Model Experiments for Developing Efficient UCG Systems

    OpenAIRE

    Gota Deguchi; Koutarou Ohga; Ken-ichi Itakura; Takuya Nakanowataru; Faqiang Su

    2013-01-01

    In the underground coal gasification (UCG) process, cavity growth with crack extension inside the coal seam is an important phenomenon that directly influences gasification efficiency. An efficient and environmentally friendly UCG system also relies upon the precise control and evaluation of the gasification zone. This paper presents details of laboratory studies undertaken to evaluate structural changes that occur inside the coal under thermal stress and to evaluate underground coal-oxygen g...

  10. Neuronet Modelling of the Processes of Budgeting and Use of Labour Resources at Coal Mining Enterprises

    OpenAIRE

    Hlіnska Olha M.; Parkhomenko Sergіy O.; Khmelyova Anhelina V.

    2014-01-01

    The article considers issues of efficient budgeting and use of labour resources at coal mining enterprises. It proves expediency of use of modern neuronet, namely, multilayer perceptron, for solution of tasks of modelling the process of budgeting and use of labour resources at coal mining enterprises. It shows that Statistika is the best software package for creation of neuronets of the multilayer perceptron architecture. On the basis of analysis and comparative characteristic the article sel...

  11. Underground Coal Gasification: Rates of Post Processing Gas Transport

    Czech Academy of Sciences Publication Activity Database

    Soukup, Karel; Hejtmánek, Vladimír; Stanczyk, K.; Šolcová, Olga

    2014-01-01

    Roč. 68, č. 12 (2014), s. 1707-1715. ISSN 0366-6352 R&D Projects: GA MŠk 7C12017 Grant ostatní: RFCS(XE) RFCR-CT-2011-00002 Institutional support: RVO:67985858 Keywords : underground coal gasification * gas transport * textural properties Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.468, year: 2014

  12. A Characterization and Evaluation of Coal Liquefaction Process Streams

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-10-01

    An updated assessment of the physico-chemical analytical methodology applicable to coal-liquefaction product streams and a review of the literature dealing with the modeling of fossil-fuel resid conversion to product oils are presented in this document. In addition, a summary is provided for the University of Delaware program conducted under this contract to develop an empirical test to determine relative resid reactivity and to construct a computer model to describe resid structure and predict reactivity.

  13. Low- and medium-Btu coal gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    Baker, N.R.; Blazek, C.F.; Tison, R.R.

    1979-01-01

    Coal gasifiers, for the production of low- and medium-Btu fuel gases, come in a wide variety of designs and capacities. For single gasifier vessels gas energy production rates range from about 1 to 18 billion Btu/day. The key characteristics of gasifiers that would be of importance for their application as an energy source in Integrated Community Energy Systems (ICES) are evaluated here. The types of gasifiers considered here are single- and two-stage, fixed-bed units; fluidized-bed units; and entrained-bed units, as producers of both low-Btu (less than 200 Btu/SCF and medium-Btu (200 to 400 Btu/SCF) gases. The gasifiers are discussed with respect to maximum and minimum capacity, the effect of feed coal parameters, product characteristics, thermal efficiency, environmental effects, operating and maintenance requirements, reliability, and cost. Some of the most recent development work in this area of coal conversion, and use of these gas products also is considered. Except in small plant installations (< 10/sup 9/ Btu/day) the annual operating costs for the various gasifier types are approximately the same. This is somewhat surprising in view of the personnel requirements, efficiencies, utility requirements, heating value of the product gas, and operating characteristics associated with each. Operating costs tend to increase with a power function exponent of 0.92 (i.e., a doubling in plant capacity increases the operating cost by about 1.9).

  14. GMAW (Gas Metal Arc Welding) process development for girth welding of high strength pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Rajan, Vaidyanath; Daniel, Joe; Quintana, Marie [The Lincoln Electric Company, Cleveland, OH (United States); Chen, Yaoshan [Center for Reliable Energy Systems (CRES), Dublin, OH (United States); Souza, Antonio [Lincoln Electric do Brasil, Guarulhos, SP (Brazil)

    2009-07-01

    This paper highlights some of the results and findings from the first phase of a consolidated program co-funded by US Department of Transportation Pipeline and Hazardous Materials Safety Administration (PHMSA) and Pipeline Research Council Inc (PRCI) to develop pipe weld assessment and qualification methods and optimize X 100 pipe welding technologies. One objective of the program is to establish the range of viable welding options for X 100 line pipe, and define the essential variables to provide welding process control for reliable and consistent mechanical performance of the weldments. In this first phase, a series of narrow gap girth welds were made with pulsed gas metal arc welding (GMAW), instrumented with thermocouples in the heat affected zone (HAZ) and weld metal to obtain the associated thermal profiles, and instrumented to measure true energy input as opposed to conventional heat input. Results reveal that true heat input is 16%-22% higher than conventional heat input. The thermal profile measurements correlate very well with thermal model predictions using true energy input data, which indicates the viability of treating the latter as an essential variable. Ongoing microstructural and mechanical testing work will enable validation of an integrated thermal-microstructural model being developed for these applications. Outputs from this model will be used to correlate essential welding process variables with weld microstructure and hardness. This will ultimately enable development of a list of essential variables and the ranges needed to ensure mechanical properties are achieved in practice, recommendations for controlling and monitoring these essential variables and test methods suitable for classification of welding consumables. (author)

  15. Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

  16. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  17. Exploratory Research on Novel Coal Liquefaction Concept - Task 2: Evaluation of Process Steps.

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, S.D.; Winschel, R.A.

    1997-05-01

    A novel direct coal liquefaction technology is being investigated in a program being conducted by CONSOL Inc. with the University of Kentucky, Center for Applied Energy Research and LDP Associates under DOE Contract DE-AC22-95PC95050. The novel concept consists of a new approach to coal liquefaction chemistry which avoids some of the inherent limitations of current high-temperature thermal liquefaction processes. The chemistry employed is based on hydride ion donation to solubilize coal at temperatures (350-400{degrees}C) significantly lower than those typically used in conventional coal liquefaction. The process concept being explored consists of two reaction stages. In the first stage, the coal is solubilized by hydride ion donation. In the second, the products are catalytically upgraded to acceptable refinery feedstocks. The program explores not only the initial solubilization step, but integration of the subsequent processing steps, including an interstage solids-separation step, to produce distillate products. A unique feature of the process concept is that many of the individual reaction steps can be decoupled, because little recycle around the liquefaction system is expected. This allows for considerable latitude in the process design. Furthermore, this has allowed for each key element in the process to be explored independently in laboratory work conducted under Task 2 of the program.

  18. Optimization of Process Parameters of Hybrid Laser-Arc Welding onto 316L Using Ensemble of Metamodels

    Science.gov (United States)

    Zhou, Qi; Jiang, Ping; Shao, Xinyu; Gao, Zhongmei; Cao, Longchao; Yue, Chen; Li, Xiongbin

    2016-08-01

    Hybrid laser-arc welding (LAW) provides an effective way to overcome problems commonly encountered during either laser or arc welding such as brittle phase formation, cracking, and porosity. The process parameters of LAW have significant effects on the bead profile and hence the quality of joint. This paper proposes an optimization methodology by combining non-dominated sorting genetic algorithm (NSGA-II) and ensemble of metamodels (EMs) to address multi-objective process parameter optimization in LAW onto 316L. Firstly, Taguchi experimental design is adopted to generate the experimental samples. Secondly, the relationships between process parameters ( i.e., laser power ( P), welding current ( A), distance between laser and arc ( D), and welding speed ( V)) and the bead geometries are fitted using EMs. The comparative results show that the EMs can take advantage of the prediction ability of each stand-alone metamodel and thus decrease the risk of adopting inappropriate metamodels. Then, the NSGA-II is used to facilitate design space exploration. Besides, the main effects and contribution rates of process parameters on bead profile are analyzed. Eventually, the verification experiments of the obtained optima are carried out and compared with the un-optimized weld seam for bead geometries, weld appearances, and welding defects. Results illustrate that the proposed hybrid approach exhibits great capability of improving welding quality in LAW.

  19. Optimization of Process Parameters of Hybrid Laser-Arc Welding onto 316L Using Ensemble of Metamodels

    Science.gov (United States)

    Zhou, Qi; Jiang, Ping; Shao, Xinyu; Gao, Zhongmei; Cao, Longchao; Yue, Chen; Li, Xiongbin

    2016-04-01

    Hybrid laser-arc welding (LAW) provides an effective way to overcome problems commonly encountered during either laser or arc welding such as brittle phase formation, cracking, and porosity. The process parameters of LAW have significant effects on the bead profile and hence the quality of joint. This paper proposes an optimization methodology by combining non-dominated sorting genetic algorithm (NSGA-II) and ensemble of metamodels (EMs) to address multi-objective process parameter optimization in LAW onto 316L. Firstly, Taguchi experimental design is adopted to generate the experimental samples. Secondly, the relationships between process parameters (i.e., laser power (P), welding current (A), distance between laser and arc (D), and welding speed (V)) and the bead geometries are fitted using EMs. The comparative results show that the EMs can take advantage of the prediction ability of each stand-alone metamodel and thus decrease the risk of adopting inappropriate metamodels. Then, the NSGA-II is used to facilitate design space exploration. Besides, the main effects and contribution rates of process parameters on bead profile are analyzed. Eventually, the verification experiments of the obtained optima are carried out and compared with the un-optimized weld seam for bead geometries, weld appearances, and welding defects. Results illustrate that the proposed hybrid approach exhibits great capability of improving welding quality in LAW.

  20. Process for the production of coal briquettes and installation for carrying out this process

    Energy Technology Data Exchange (ETDEWEB)

    Fried, R.

    1989-01-25

    Coal briquettes are produced with the aid of a granular mixture of bituminous coal and inert coal by heating the bituminous coal above its softening point in contact with the inert coal previously heated to a higher temperature and mixed with the bituminous coal in a mixer to form a pasty substance through the softening of the bituminous coal. This pasty substance is extracted through the bottom of the mixer and guided into a briquette forming apparatus, the briquettes then being hardened and cooled. The gases produced in the mixer are delivered into a separator, at the bottom of which the solid constituents entrained by the gases are recovered and are recycled into the mixer at a point below the top level of the mixture.

  1. Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process

    International Nuclear Information System (INIS)

    Highlights: • Present the opportunities and challenges of coal-to-olefins (CTO) development. • Conduct a techno-economic analysis on CTO compared with oil-to-olefins (OTO). • Suggest approaches for improving energy efficiency and economic performance of CTO. • Analyze effects of plant scale, feedstock price, CO2 tax on CTO and OTO. - Abstract: Olefins are one of the most important oil derivatives widely used in industry. To reduce the dependence of olefins industry on oil, China is increasing the production of olefins from alternative energy resources, especially from coal. This study is concerned with the opportunities and obstacles of coal-to-olefins development, and focuses on making an overall techno-economic analysis of a coal-to-olefins plant with the capacity of 0.7 Mt/a olefins. Comparison is made with a 1.5 Mt/a oil-to-olefins plant based on three criteria including energy efficiency, capital investment, and product cost. It was found that the coal-based olefins process show prominent advantage in product cost because of the low price of its feedstock. However, it suffers from the limitations of higher capital investment, lower energy efficiency, and higher emissions. The effects of production scale, raw material price, and carbon tax were varied for the two production routes, and thus the operational regions were found for the coal-to-olefins process to be competitive

  2. Principles of processes used for coal gas cleaning and recovery of chemical products of coking. Part II. [Poland

    Energy Technology Data Exchange (ETDEWEB)

    Ulatowski, R.

    1983-02-01

    This paper discusses removal of tars, ammonia, benzene and desulfurization of coal gas from black coal coking. About 30% of coal gas produced by coking plants in Poland is desulfurized. The average content of hydrogen sulfide in coal gas ranges from 6 to 8 g/m/sup 3/. After desulfurization hydrogen sulfur content does not exceed 0.2 g/m/sup 3/. Two processes are used in Poland for coal gas desulfurization: the vacuum carbonate process and the Thylox process. Chemical reactions during gas desulfurization with the two processes are discussed. Regeneration systems, productivity and efficiency of gas desulfurization using the two processes are compared. The following processes used in other countries are comparatively evaluated: the Fumaks-Rodax process in Japan, the Perox process, the Stretford process, the Sulfiban process in the USA and the Claus process.

  3. Examination of the physical processes associated with the keyhole region of variable polarity plasma arc welds in aluminum alloy 2219

    Science.gov (United States)

    Walsh, Daniel W.

    1987-01-01

    The morphology and properties of the Variable Polarity Plasma Arc (VPPA) weld composite zone are intimately related to the physical processes associated with the keyhole. This study examined the effects of oxide, halide, and sulfate additions to the weld plate on the keyhole and the weld pool. Changes in both the arc plasma character and the bead morphology were correlated to the chemical environment of the weld. Pool behavior was observed by adding flow markers to actual VPPA welds. A low temperature analog to the welding process was developed. The results of the study indicate that oxygen, even at low partial pressures, can disrupt the stable keyhole and weld pool. The results also indicate that the Marangoni surface tension driven flows dominate the weld pool over the range of welding currents studied.

  4. CHINA'S RECENT DEVELOPMENT IN COAL MINING,PROCESSING AND UTILIZATION

    Institute of Scientific and Technical Information of China (English)

    范维唐; 王成龙; 朱德仁

    1996-01-01

    This paper describes the state-of-the-art and outlook of coal mining and clean coal echnology in China. As the major mining method,underground mining accounts for 96% of the total production. Among the state own mines, the percentage of mechanized mining reached 71%. A rapid development of high-productive and high-profitable mines,especially those with longwall sublevel caving method, is described. The issues of heavy duty equipment, roof bolting, mine safety are also addressed. The Chinese government is paying more and more attention on the environmental problems inducing from coal mining,processing and utilization. A basic framework of clean coal technology is being formed and a wide range of technology is included.

  5. Growth of small diameter multi-walled carbon nanotubes by arc discharge process

    Science.gov (United States)

    T. Chaudhary, K.; J., Ali; P. Yupapin, P.

    2014-03-01

    Multi-walled carbon nanotubes (MWCNTs) are grown by arc discharge method in a controlled methane environment. The arc discharge is produced between two graphite electrodes at the ambient pressures of 100 torr, 300 torr, and 500 torr. Arc plasma parameters such as temperature and density are estimated to investigate the influences of the ambient pressure and the contributions of the ambient pressure to the growth and the structure of the nanotubes. The plasma temperature and density are observed to increase with the increase in the methane ambient pressure. The samples of MWCNT synthesized at different ambient pressures are analyzed using transmission electron microscopy, scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. An increase in the growth of MWCNT and a decrease in the inner tube diameter are observed with the increase in the methane ambient pressure.

  6. Gas tungsten arc and laser beam welding processes effects on duplex stainless steel 2205 properties

    International Nuclear Information System (INIS)

    Highlights: ► LBW results in considerable variation in the ferrite–austenite balance of FZ. ► LBW produces smaller FZ size than GTAW. ► The effect of FZ size is more pronounced than that of ferrite–austenite balance. ► Satisfactory mechanical properties were obtained using both GTAW and LBW. ► LBW process has produced welded joint properties comparable to BM. - Abstract: A comparative study on the influence of gas tungsten arc welding (GTAW) and carbon dioxide laser beam welding (LBW) processes on the size and microstructure of fusion zone FZ then, on the mechanical and corrosion properties of duplex stainless steel DSS grade 2205 plates of 6.4 mm thickness was investigated. Autogenous butt welded joints were made using both GTAW and LBW. The GTA welded joint was made using well established welding parameters (i.e., current ampere of 110 A, voltage of 12 V, welding speed of 0.15 m/min and argon shielding rate of 15 l/min). While optimum LBW parameters were used (i.e., welding speed of 0.5 m/min, defocusing distance of 0.0 mm, argon shielding flow rate of 20 l/min and maximum output laser power of 8 kW). The results achieved in this investigation disclose that welding process play an important role in obtaining satisfactory weld properties. In comparison with GTAW, LBW has produced welded joint with a significant decrease in FZ size and acceptable weld profile. The ferrite–austenite balance of both weld metal WM and heat affected zone (HAZ) are influenced by heat input which is a function of welding process. In comparison with LBW, GTAW has resulted in ferrite–austenite balance close to that of base metal BM due to higher heat input in GTAW. However, properties of LB welded joint, particularly corrosion resistance are much better than that of GTA welded joint. The measured corrosion rates for LBW and GTAW joints are 0.05334 mm/year and 0.2456 mm/year, respectively. This is related to the relatively small size of both WM and HAZ produced in the case

  7. Gas tungsten arc and laser beam welding processes effects on duplex stainless steel 2205 properties

    Energy Technology Data Exchange (ETDEWEB)

    Mourad, A-H.I., E-mail: ahmourad@uaeu.ac.ae [Mechanical Engineering Department, Faculty of Engineering, United Arab Emirates University, Al-Ain, P.O. Box. 17555 (United Arab Emirates); Khourshid, A.; Sharef, T. [Mechanical Design and Production Department, Faculty of Engineering, Tanta University, Tanta (Egypt)

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer LBW results in considerable variation in the ferrite-austenite balance of FZ. Black-Right-Pointing-Pointer LBW produces smaller FZ size than GTAW. Black-Right-Pointing-Pointer The effect of FZ size is more pronounced than that of ferrite-austenite balance. Black-Right-Pointing-Pointer Satisfactory mechanical properties were obtained using both GTAW and LBW. Black-Right-Pointing-Pointer LBW process has produced welded joint properties comparable to BM. - Abstract: A comparative study on the influence of gas tungsten arc welding (GTAW) and carbon dioxide laser beam welding (LBW) processes on the size and microstructure of fusion zone FZ then, on the mechanical and corrosion properties of duplex stainless steel DSS grade 2205 plates of 6.4 mm thickness was investigated. Autogenous butt welded joints were made using both GTAW and LBW. The GTA welded joint was made using well established welding parameters (i.e., current ampere of 110 A, voltage of 12 V, welding speed of 0.15 m/min and argon shielding rate of 15 l/min). While optimum LBW parameters were used (i.e., welding speed of 0.5 m/min, defocusing distance of 0.0 mm, argon shielding flow rate of 20 l/min and maximum output laser power of 8 kW). The results achieved in this investigation disclose that welding process play an important role in obtaining satisfactory weld properties. In comparison with GTAW, LBW has produced welded joint with a significant decrease in FZ size and acceptable weld profile. The ferrite-austenite balance of both weld metal WM and heat affected zone (HAZ) are influenced by heat input which is a function of welding process. In comparison with LBW, GTAW has resulted in ferrite-austenite balance close to that of base metal BM due to higher heat input in GTAW. However, properties of LB welded joint, particularly corrosion resistance are much better than that of GTA welded joint. The measured corrosion rates for LBW and GTAW joints are 0.05334 mm

  8. Welding stability assessment in the GMAW-S process based on fuzzy logic by acoustic sensing from arc emissions

    Directory of Open Access Journals (Sweden)

    E. Huanca Cayo

    2012-11-01

    Full Text Available Purpose: The present research work has as purpose detecting perturbations, measuring and assessing the welding stability in GMAW process in short circuit mode named hereafter as GMAW-S process.Design/methodology/approach: Welding trials were performed with a set of optimal input welding parameters. During experiments were induced some perturbations on the welding trajectory. It causes alteration on the stability of welding resulting as consequence geometrical shape deformations. During each experiments, acoustic emission signal coming from electric arc as well as arc voltage and welding current were acquired aided by a card acquisition and virtual instrumentation software. A heuristic model was performed as knowledge base rules of a fuzzy logic system. This system has two inputs and one output. Some additional welding trials were performed for assessing its performance.Findings: It was performed a welding stability assessment system based on fuzzy logic. As well as, this system is based on non-contact sensing what reduces the loading effects on the welding process.Research limitations/implications: In the present work was monitored just the acoustic emissions coming from arc. Although that, the results were satisfactory, an approach on data fusion of sensors including electromagnetic emission sensors could improve the quality assessments system.Originality/value: The non-contact welding stability assessment methods have reduces loading effects and a heuristic approach on the relations between arc emissions and welding stability allows quantifying nonlinear variables such as knowledge and experience of skilled welders, such that, it is possible to represent linguistic terms numerically what could be used as an on-line monitoring system of welding processes.

  9. Effect Of Pulsed Current Micro Plasma Arc Welding Process Parameters On Fusion Zone Grain Size And Ultimate Tensile

    OpenAIRE

    Kondapalli Siva Prasad; Chalamalasetti Srinivasa Rao; Damera Nageswara Rao

    2012-01-01

    AISI 304L is an austenitic Chromium-Nickel stainless steel offering the optimum combination of corrosion resistance, strength and ductility. These attributes make it a favorite for many mechanical components. The low carbon content reduces susceptibility to carbide precipitation during welding. In case of single pass welding of thinner section of this alloy, pulsed current micro plasma arc welding was found beneficial due to its advantages over the conventional continuous current process. The...

  10. Arc-welding process control based on back face thermography: application to the manufacturing of nuclear steam generators

    OpenAIRE

    Cobo García, Adolfo; Mirapeix Serrano, Jesús María; Conde Portilla, Olga María; García Allende, Pilar Beatriz; Madruga Saavedra, Francisco Javier; López Higuera, José Miguel

    2007-01-01

    The possibility of reducing defects in the arc welding process has attracted research interest, particularly, in the aerospace and nuclear sectors where the resulting weld quality is a major concern and must be assured by costly, time-consuming, non-destructive testing (NDT) procedures. One possible approach is the analysis of a measurand correlated with the formation of defects, from which a control action is derived. Among others, the thermographic analysis of the weld pool and the heat-aff...

  11. Microstructural Evolution and Mechanical Properties of Inconel 625 Alloy during Pulsed Plasma Arc Deposition Process

    Institute of Scientific and Technical Information of China (English)

    Fujia Xu; Yaohui Lv; Yuxin Liu; Fengyuan Shu; Peng He; Binshi Xu

    2013-01-01

    Pulsed plasma arc deposition (PPAD),which combines pulsed plasma cladding with rapid prototyping,is a promising technology for manufacturing near net shape components due to its superiority in cost and convenience of processing.In the present research,PPAD was successfully used to fabricate the Ni-based superalloy Inconel 625 components.The microstructures and mechanical properties of deposits were investigated by scanning electron microscopy (SEM),optical microscopy (OM),transmission electron microscopy (TEM) with energy dispersive spectrometer (EDS),microhardness and tensile testers.It was found that the as-deposited structure exhibited homogenous columnar dendrite structure,which grew epitaxially along the deposition direction.Moreover,some intermetallic phases such as Laves phase,minor MC (NbC,TiC) carbides and needle-like δ-Ni3Nb were observed in γ-Ni matrix.Precipitation mechanism and distribution characteristics of these intermetallic phases in the as-deposited 625 alloy sample were analyzed.In order to evaluate the mechanical properties of the deposits,microhardness was measured at various location (including transverse plane and longitudinal plane).The results revealed hardness was in the range of 260-285 HVo.2.In particular,microhardness at the interface region between two adjacent deposited layers was slightly higher than that at other regions due to highly refined structure and the disperse distribution of Laves particles.Finally,the influence of precipitation phases and fabrication strategies on the tensile properties of the as-deposited samples was investigated.The failure modes of the tensile specimens were analyzed with fractography.

  12. Vision of the Arc for Quality Documentation and for Closed Loop Control of the Welding Process

    DEFF Research Database (Denmark)

    Kristiansen, Morten; Kristiansen, Ewa; Jensen, Casper Houmann;

    2014-01-01

    For gas metal arc welding a vision system was developed, which was robust to monitor the position of the arc. The monitoring documents the welding quality indirectly and a closed loop fuzzy control was implemented to control an even excess penetration. For welding experiments on a butt......-joint with a V-groove with varying root gapthe system demonstrated increased welding quality compared to the system with no control. The system was implemented with a low cost vision system, which makes the system interesting to apply in industrial welding automation systems....

  13. Acoustic Emission Characteristics of Gas-Containing Coal during Loading Dilation Process

    Directory of Open Access Journals (Sweden)

    Z. Q. Yin

    2015-12-01

    Full Text Available Raw coal was used as the study object in this paper to identify the evolution characteristics of acoustic emission (AE during the dilation process of gas-containing coal. The coal specimens were stored in gas seal devices filled with gas at different pressures (0, 0.5, 1.0, and 1.5 MPa for 24 h prior to testing. Then, the specimens were tested in a rock-testing machine, and the deformation and crack fracture patterns were recorded by using strain gauges and an AE system. The axial and volumetric strains–stress curves were analyzed in relation to the AE and the failure mode. Results show that as gas pressure increases, the uniaxial compression strength and elasticity modulus of gas-containing coal decreases, whereas the Poisson’s ratio increases. In all the coal specimens, the dilation initiation stress decreases, and the dilation degree increases. During the dilation process, before the loaded coal specimens reach peak stress, and as the load increases, the changes in the specimens and in the AE energy parameter of specimens can be divided into four phases: crack closure deformation, elastic deformation, stable crack propagation, and unstable crack propagation (dilation process. Across the four phases, the AE energy increases evidently during crack closure and elastic deformation but decreases during stable crack propagation. As the gas pressure increases, the AE signal frequency increases from 4.5 KHz to 8.1 KHz during the dilation process. Thus, the gas presence in coal specimens exerts a significant influence on the closure of sample cracks and dilation damage.

  14. Novel Intergrated Process to Process to Produce Fuels from Coal and Other Carbonaceous Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Lucero

    2009-03-25

    BioConversion Technology, LLC has developed a novel gasifier design that produces a clean, medium to high BTU synthesis gas that can be utilized for a variety of applications. The staged, indirectly heated design produces high quality synthesis gas without the need for costly pure oxygen. This design also allows for extreme flexibility with respect to feedstocks (including those with high moisture contents) in addition to high throughputs in a small gasifier footprint. A pilot scale testing project was proposed to assist BCT with commercializing the process. A prototype gasifier constructed by BCT was transported to WRI for installation and testing. After troubleshooting, the gasifier was successfully operated with both coal and biomass feedstocks. Instrument upgrades are recommended for further testing.

  15. Critical Analysis of Moving Heat Source Shape for ARC Welding Process of High Deposition Rate

    Czech Academy of Sciences Publication Activity Database

    Ghosh, A.; Hloch, Sergej; Chattopadhyaya, S.

    2014-01-01

    Roč. 21, č. 1 (2014), s. 95-98. ISSN 1330-3651 Institutional support: RVO:68145535 Keywords : Gaussian heat distribution * oval heat source shape * Submerged Arc Welding Subject RIV: JQ - Machines ; Tools Impact factor: 0.579, year: 2014 http://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=172337

  16. Seismic response to recent tectonic processes in the Banda Arc region

    Czech Academy of Sciences Publication Activity Database

    Špičák, Aleš; Matějková, Radka; Vaněk, Jiří

    2013-01-01

    Roč. 64, 5 March (2013), s. 1-13. ISSN 1367-9120 R&D Projects: GA MŠk ME09011 Institutional support: RVO:67985530 Keywords : Banda Arc * subduction * Wadati-Benioff zone * collision * calc-alkaline volcanism Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 2.831, year: 2013

  17. New Coke Oven Facilities at Linhuan Coal Chemical Company Adopt LyondellBasell's Aromatics Extraction Process

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ The new 80 kt/a coal chemical unit at the Linhuan Coal Chemical Company in Anhui province will adopt the aro-matics extraction process licensed by LyondellBasell Company. This unit is expected to come on stream by 2009.This technology is suitable for manufacture of high-purity aromatics with broad adaptability and large scale produc-tion capability. In the previous year LyondellBasell was awarded six patents on aromatics extraction process. It is told that the achievements to be adopted by the Linhuan Coal Chemical Company are partly a series of aromatics extrac-tion processes for recovery of coke oven light oil performed by LyondellBasell.

  18. Use of nuclear process heat for methane and hydrogen production via in-situ coal gasification

    International Nuclear Information System (INIS)

    Coal gasification plants and processes have been in existence for many years, using fossil fuel as the source of energy input. However, there appear to be no significant installations carrying out in-situ coal gasification and using high-temperature, high pressure, process heat (e.g., as steam) from a high-temperature nuclear reactor. In the present paper, historical and theoretical aspects of gasification are outlined and a concept is put forward for a full-scale commercial in-situ coal gasification plant using process steam from a high-temperature gas-cooled nuclear reactor, and producing two streams, one being methane for transport use and industrial feedstock, and the other being hydrogen for a future hydrogen economy. The possibility of a CANDU reactor meeting the thermal requirements is discussed

  19. Process simulation and optimization for fry drying of low rank coal

    Energy Technology Data Exchange (ETDEWEB)

    Chun, D.H.; Kim, S.D.; Rhim, Y.J.; Rho, N.S.; Choi, H.K.; Yoo, J.H.; Lim, J.H.; Lee, S.H. [Korea Institute of Energy Research, Daejeon (Korea, Republic of). Clean Fossil energy Research Center

    2013-07-01

    We conducted fry drying process simulations of low rank coal and operation optimization. We set up the operating condition of evaporator so that the coal moisture content would come down from 35 to 10 wt.% during the drying process. Through process simulations, we calculated the heat duty supplied and power consumption under each operating condition. From the simulation results, we calculated operating costs on the basis of prices in Indonesia which is a coal producing place. Cases where thermal energy was reused through MVR showed an effect of reducing operating costs by around 50%. The operating conditions were optimized through operating cost analysis and the results indicated that the optimum operating conditions were evaporator pressure 500 kPa and temperature 168 C.

  20. Trace and major element pollution originating from coal ash suspension and transport processes.

    Science.gov (United States)

    Popovic, A; Djordjevic, D; Polic, P

    2001-04-01

    Coal ash obtained by coal combustion in the "Nikola Tesla A" power plant in Obrenovac, near Belgrade, Yugoslavia, is mixed with water of the Sava river and transported to the dump. In order to assess pollution caused by leaching of some minor and major elements during ash transport through the pipeline, two sets of samples (six samples each) were subjected to a modified sequential extraction. The first set consisted of coal ash samples taken immediately after combustion, while the second set was obtained by extraction with river water, imitating the processes that occur in the pipeline. Samples were extracted consecutively with distilled water and a 1 M solution of KCl, pH 7, and the differences in extractability were compared in order to predict potential pollution. Considering concentrations of seven trace elements as well as five major elements in extracts from a total of 12 samples, it can be concluded that lead and cadmium do not present an environmental threat during and immediately after ash transport to the dump. Portions of zinc, nickel and chromium are released during the ash transport, and arsenic and manganese are released continuously. Copper and iron do not present an environmental threat due to element leaching during and immediately after the coal ash suspension and transport. On the contrary, these elements, as well as chromium, become concentrated during coal ash transport. Adsorbed portions of calcium, magnesium and potassium are also leached during coal ash transport. PMID:11341293

  1. AuroView 2000 - An optical image processing system in rank and grade analysis of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, A. [Jadavpur University, Calcutta (India). Dept. of Geological Science

    2002-07-01

    Rank and grade analysis of coal plays an important role in its use in different industries like thermal power plants and/or steel industries. Petrographically, coal is evaluated on the basis of its relative abundance of microscopic constituents that ultimately influence its reactivity, heat value, ash content, agglutinating characteristics and inflammability. Rank is a maturity characteristic of coal, measured on the basis of reflectance values usually of a particular organic constituent, vitrinite. Using the optical image processing system called AuroView 2000, the microscope images of a coal sample are acquired through a computer under normal incident light as well as under fluorescent light. The image under normal incident light is a black and white (b/w), whereas the image under fluorescent light is coloured. From these images, important groups of microscopic components called mineral matter, vitrinite, liptinite and inertinite are classified. The AuroView 2000 software has two modules viz. analysis module and prediction module. The analysis module is capable of producing modal percentages of macerals and mineral matter, and can measure mean max R-0, V-type distribution (reflectance) automatically or manually under this set up without any MPV attachment. In fact, it converts light intensity values (the grey levels) to a calibrated reflectance scale. The prediction module can predict ash content (%), VM on dmmf basis and elemental carbon on pure coal basis. Finally, it can predict the rank and grade of coal as per Indian Bureau of Standards nomenclature.

  2. Matrix isolation-Fourier transform infrared spectroscopy studies of slow pyrolysis processes for four coals

    Energy Technology Data Exchange (ETDEWEB)

    Chu, C.J.; Cannon, S.A.; Hauge, R.H.; Margrave, J.L.

    1988-12-01

    Slow pyrolysis processes for four coals (Illinois No. 6, Pittsburgh bituminous, Rawhide sub-bituminous and Texas lignite) were studied using matrix isolation-Fourier transform infrared (FTIR) spectroscopy. The temperature-dependent evolution of products during slow pyrolysis was used to correlate product species to the existence of various functional groups initially present in the respective coals. As other investigators have found, the amount of a specific product is correlated to the initial amount of a specific functional group. The yields of pyrolysis products such as CO, CO/sub 2/, H/sub 2/O, H/sub 2/S, CS/sub 2/, HCN and CH/sub 4/ were derived from peak area calculations and their corresponding extinction coefficients. Correlations were established between the yields of low-temperature CO and the amount of ether functional groups in coal, between CO/sub 2/ and carboxyl functional groups in coal, between H/sub 2/O and hydroxyl functional groups, between HCN and organic nitrogen and between CS/sub 2/ and H/sub 2/S to sulfur. The extent of methane evolution correlates with existing methyl groups initially present in the respective coals. Pyrolysis and reduction of kaolinite in coal were observed at high temperatures (approx. 1150-1500 C) to form the high-temperature species SiO, Al/sub 2/O and aluminium atoms. Aluminium atoms were detected in the presence of CO, by the formation of Al-CO complexes to give Al/sub x/(CO)/sub 2/ and Al/sub x/CO. The intensities of these aluminium complexes give a qualitative measurement of the amount of kaolinite in coal. Results obtained from the slow pyrolyses of these four coals have demonstrated the potential of matrix isolation-FTIR spectroscopy as an useful analytical tool for the study of fossil fuels. 10 figs., 23 refs., 7 tabs.

  3. MeCrAl coatings obtained by arc PVD and pack cementation processes on nickel base superalloys

    International Nuclear Information System (INIS)

    The paper presents the results of researches on obtaining and structure of high temperature resistance coatings on superalloys. The coatings were deposited on nickel and nickel base superalloys in two stages. During the first stage, the NiCr and NiCrHf coatings were obtained by arc-PVD method. Basic technology, bias, arc current, rotation, parameters of deposition of NiCr and MeCrHf coatings were defined. The high efficiency of deposition of both single and two sources was observed. The targets were made by vacuum melting and machining. An influence of targets chemical composition on coating structure and chemical coatings composition was described. The second stage was made by pack cementation HTLA (high temperature low activity) on 1323 K chromoaluminizing process. These arc-PVD and diffusion (pack cementation) connected processes permitted to obtain MeCrAl and MeCrAlHf type of coatings. The morphology, structure and microchemical composition were characterized by scanning electron microscopy, X-ray microanalysis, energy dispersive X-ray spectroscopy and X-ray diffraction methods. (orig.)

  4. Corrosion and stress corrosion cracking in coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Baylor, V. B.; Keiser, J. R.

    1980-01-01

    The liquefaction of coal to produce clean-burning synthetic fuels has been demonstrated at the pilot plant level. However, some significant materials problems must be solved before scale-up to commercial levels of production can be completed. Failures due to inadequate materials performance have been reported in many plant areas: in particular, stress corrosion cracking has been found in austenitic stainless steels in the reaction and separation areas and several corrosion has been observed in fractionation components. In order to screen candidate materials of construction, racks of U-bend specimens in welded and as-wrought conditions and unstressed surveillance coupons were exposed in pilot plant vessels and evaluated. Failed components were analyzed on-site and by subsequent laboratory work. Laboratory tests were also performed. From these studies alloys have been identified that are suitable for critical plant locations. 19 figures, 7 tables.

  5. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    Energy Technology Data Exchange (ETDEWEB)

    K. Osseo-Asare; X. Zeng

    2001-06-30

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. The partitioning behaviors of hematite in the dextran (Dex)/Triton X-100 (TX100) and polyethylene glycol (PEG)/dextran systems were investigated and the effects of some ionic surfactants on solid partition were studied. In both biphase systems, the particles stayed in the bottom dextran-rich phase under all pH conditions. This behavior is attributable to the fact that the hydrophilic oxide particles prefer the more hydrophilic bottom phase. Also, the strong favorable interaction between dextran and ferric oxide facilitates the dispersion of the solids in the polysaccharide-rich phase. In the Dex/TX100 system, addition of sodium dodecylsulfate (SDS) or potassium oleate had no effect on the solid partition; on the other hand, addition of dodecyltrimethylammonium bromide (DTAB) transferred the particles to the top phase or interface at high pH values. In the PEG/Dex system, the preferred location of hematite remained the bottom phase in the presence of either SDS or DTAB. The effects of anionic surfactants on the partition behavior are attributable to the fact that they are not able to replace the strongly adsorbed polysaccharide layer on the ferric oxide surface. The results with the cationic surfactant are due to electrostatic interaction between the cationic surfactant and the charged surface of the solid particles. The difference in solids partitioning in the two systems is the result of the different distribution of DTAB in these systems. In the Dex/TX100 system, DTAB prefers the top surfactant-rich phase, while it concentrates in the bottom phase in the PEG/dextran system.

  6. Centrifugal dewatering and reconstitution of fine coal: the GranuFlow Process

    Energy Technology Data Exchange (ETDEWEB)

    Wen, W.W.; Killmeyer, R.P. [USDOE, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center

    1996-12-31

    This paper describes the testing and evaluation of the GranuFlow process, which combines fine coal dewatering and reconstitution into a one-step process. A fine clean-coal slurry was treated with a bitumen emulsion prior to dewatering in both a high-g force solid-bowl and screen-bowl centrifuge. The products were drier than the original materials, and more easily handled. The improvements in moisture content, handling properties, and dust reduction the dewatered product were evaluated. The costs of using Orimulsion in centrifuging were noted. 9 refs., 8 figs., 3 tabs.

  7. IMPROVING METHODS OF MODELING CANAL WAVES PROPAGATION PROCESS IN COAL SEAMS

    Directory of Open Access Journals (Sweden)

    SMIRNOV YU.M.

    2012-01-01

    Full Text Available There has been analyzed the principal methods of modeling the process of canal waves propagation in coal seams when carrying out mining geophysical studies. There has been established that the wave guide moving into the surface of the elastic half-space doesn’t practically change the main properties of the interferential waves propagating in them. There has been recommended to use Fourier integral describing the single pulse spectrum for studying the registered seismograms. There have been formulated the main problems of improving physical processes modeling in coal seams when carrying out their geological studying

  8. Correlation between the coal quality from 'Suvodol' and briquetting processes for coals, peat and other combustible materials (coal deposit in Macedonia)

    International Nuclear Information System (INIS)

    In this paper the regression equations for the characteristics of Suvodol coal and the technological parameters of obtained briquets are given. It is shown that correlations between the coal characteristics are linear, while correlations between briquetting parameters are nonlinear

  9. Coal upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

    2009-10-15

    This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

  10. Application of coal-water slurry on the rotary calcining kiln of pedgion magnesium reduction process

    Institute of Scientific and Technical Information of China (English)

    LI Hua-qing; XIE Shui-sheng; LIU Jin-ping; WU Peng-yue; HUANG Guo-jie

    2006-01-01

    Energy saving has been an important concept in modern industry especially to the countries and regions with energy shortage such as China and Japan. Utilization of Coal-Water Slurry (CWS) can improve the burning efficiency of coal and reduce the pollutions of soot, sulfide and the nitride by burning lump coal directly. The CWS is a promising energy saving technique and the effectual substitute of oil. The study on the preparation and application of the CWS has made progresses in many aspects. The present paper studied the basal problems for applying the CWS on the rotary kilns during the calcining-dolomite process in the magnesium factory, summarized the key points for the application process of the CWS and gave the corresponding solutions.

  11. Project report on coal gasification by nuclear process heat. Phase 2

    International Nuclear Information System (INIS)

    The process heat of a HTR is used for conversion of coal to the energy sources H2, MeOH, and SNG. The nuclear gasification processes (non-catalytic steam gasification, catalytic steam gasification, hydrogenation) are compared with the autothermal coal gasification techniques (Texaco, Lurgi). The results of the study show the technical feasibility of the steam gasification process. Cost-benefit analyses show the cost ratios of the nuclear gasification processes to be higher than those of the autothermal processes. Investigations on improvement potentials of the steam gasification process did show possible economic efficiency enhancement, but cost ratios still are above those of the autothermal techniques. In addition, there is need for better or even optimised adjustment of HTR operation to the requirements of the relevant nuclear process heat applications. (orig.) With 6 refs., 11 tabs., 11 figs

  12. The influence of process parameters on desulfurization of Mezino coal by HNO3/HCl leaching

    International Nuclear Information System (INIS)

    Coal desulfurization prior to usage is a preprocessing in order to achieve clean fuel and reduce environmental impacts such as acid rain. Desulfurization of Tabas Mezino coal was conducted with two consecutive steps of froth flotation at ambient temperature followed by leaching at various conditions. Reducing the ash content of Mezino coal by 35.7 wt.% and its total sulfur content by 36.9% using froth flotation process was successful. HCl and HNO3 were used, separately, to leach the floated coal, and the effectiveness of each acid on Mezino coal desulfurization was investigated. Nitric acid was found to be much more effective than HCl and the effects of reaction time, acid concentration and temperatures as well as stirring speed were studied as major parameters in the nitric leaching process. Taguchi orthogonal experiment with the above mentioned parameter elements; one at three levels was used to optimize the experiment parameters by the analysis of variances. Applying of the Taguchi technique significantly reduced the time and cost required for the experimental investigation. The findings indicated that acid concentration, with a high contribution, had the most dominant effect on desulfurization performance, followed by temperature, stirring speed and time. Accordingly, the optimum condition was obtained as, temperature: 90 C., acid concentration: 30%., and stirring rate: 1000 rpm. The total sulfur and ash removal after flotation and leaching at optimum condition reached to 75.4 and 53.2% respectively that is a remarkable result compared to the previous works. (author)

  13. Characterization of titanium welded joints by the orbital gas tungsten arc welding process for aerospace application

    OpenAIRE

    José A. Orlowski de Garcia; Gérson Luiz de Lima; Wilson D. Bocallão Pereira; Valdir Alves Guimarães; Carlos de Moura Neto; Ronaldo Pinheiro R. Paranhos

    2010-01-01

    In this work, three welding programs for orbital gas tungsten arc welding (GTAW), previously developed, were used, using pulsed current and increasing speed (#A), constant current (#B) and pulsed current and decreasing current (#C). One of these should be used for the propulsion system of the Satellite CBERS (China – Brazil Earth Resources Satellite). Welded joints using tubes of commercially pure titanium were obtained with these procedures, which were characterized by means of mechanical an...

  14. The Method for Evaluation of Energy Processes in Intensively Blasted Electric Arc

    Czech Academy of Sciences Publication Activity Database

    Heinz, J.; Hrabovský, Milan; Jakubová, I.; Šenk, J.

    Bari: Department of Chemistry, University of Bari, 2003 - (d'Agostino, R.; Favia, P.; Fracassi, F.; Palumbo, F.), s. - [International Symposium on Plasma Chemistry/16th./. Taormina (IT), 22.06.2003-27.06.2003] R&D Projects: GA ČR GA202/01/1563 Institutional research plan: CEZ:AV0Z2043910 Keywords : arc, plasma Subject RIV: BL - Plasma and Gas Discharge Physics

  15. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    Energy Technology Data Exchange (ETDEWEB)

    K. Osseo-Asare; X. Zeng

    2001-06-30

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. The partitioning behaviors of silica in the polyethylene glycol (PEG)/dextran (Dex) and dextran/Triton X-100 (TX100) systems have been investigated, and the effects of sodium dodecylsulfate (SDS) and dodecyltrimethylammonium bromide (DTAB) on solid partition have been studied. In both biphase systems, silica particles stayed in the top PEG-rich phase at low pH. With increase in pH, the particles moved from the top phase to the interface, then to the bottom phase. At very high pH, the solids preferred the top phase again. These trends are attributable to variations in the polymer/solid and nonionic surfactant/solid interactions. Addition of ionic surfactants into these two systems introduces a weakly charged environment, since ionic surfactants concentrate into one phase, either the top phase or the bottom phase. Therefore, coulombic forces also play a key role in the partition of silica particles because electrostatic attractive or repulsive forces are produced between the solid surface and the ionic-surfactant-concentrated phase. For the PEG/dextran system in the presence of SDS, SiO{sub 2} preferred the bottom dextran-rich phase above its pH{sub PZC}. However, addition of DTAB moved the oxide particles from the top phase to the interface, and then to the bottom phase, with increase in pH. These different behaviors are attributable to the fact that SDS and DTAB concentrated into the opposite phase of the PEG/dextran system. On the other hand, in the dextran/Triton X-100 system, both ionic surfactants concentrated in the top surfactant-rich phase and formed mixed micelles with TX100. Therefore, addition of the anionic surfactant, SDS, moved the silica particles from top phase to the

  16. Coal liquefaction process streams characterization and evaluation. Volume 1, Base program activities

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1994-05-01

    This 4.5-year project consisted of routine analytical support to DOE`s direct liquefaction process development effort (the Base Program), and an extensive effort to develop, demonstrate, and apply new analytical methods for the characterization of liquefaction process streams (the Participants Program). The objective of the Base Program was to support the on-going DOE direct coal liquefaction process development program. Feed, process, and product samples were used to assess process operations, product quality, and the effects of process variables, and to direct future testing. The primary objective of the Participants Program was to identify and demonstrate analytical methods for use in support of liquefaction process development, and in so doing, provide a bridge between process design, and development, and operation and analytical chemistry. To achieve this objective, novel analytical methods were evaluated for application to direct coal liquefaction-derived materials. CONSOL teamed with 24 research groups in the program. Well-defined and characterized samples of coal liquefaction process-derived materials were provided to each group. CONSOL made an evaluation of each analytical technique. During the performance of this project, we obtained analyses on samples from numerous process development and research programs and we evaluated a variety of analytical techniques for their usefulness in supporting liquefaction process development. Because of the diverse nature of this program, we provide here an annotated bibliography of the technical reports, publications, and formal presentations that resulted from this program to serve as a comprehensive summary of contract activities.

  17. Thermodynamic and rheological properties of solid-liquid systems in coal processing. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Kabadi, V.N.

    1995-06-30

    The work on this project was initiated on September 1, 1991. The project consisted of two different tasks: (1) Development of a model to compute viscosities of coal derived liquids, and (2) Investigate new models for estimation of thermodynamic properties of solid and liquid compounds of the type that exist in coal, or are encountered during coal processing. As for task 1, a model for viscosity computation of coal model compound liquids and coal derived liquids has been developed. The detailed model is presented in this report. Two papers, the first describing the pure liquid model and the second one discussing the application to coal derived liquids, are expected to be published in Energy & Fuels shortly. Marginal progress is reported on task 2. Literature review for this work included compilation of a number of data sets, critical investigation of data measurement techniques available in the literature, investigation of models for liquid and solid phase thermodynamic computations. During the preliminary stages it was discovered that for development of a liquid or solid state equation of state, accurate predictive models for a number of saturation properties, such as, liquid and solid vapor pressures, saturated liquid and solid volumes, heat capacities of liquids and solids at saturation, etc. Most the remaining time on this task was spent in developing predictive correlations for vapor pressures and saturated liquid volumes of organic liquids in general and coal model liquids in particular. All these developments are discussed in this report. Some recommendations for future direction of research in this area are also listed.

  18. ENVIRONMENTAL AND ECONOMIC ASPECTS OF INDIRECT COAL LIQUEFACTION PROCESSES: A REPORT EMPHASIZING THE RELATIONSHIP BETWEEN PRODUCT MIX AND EFFICIENCY

    Science.gov (United States)

    This report covers environmental and economic aspects of three indirect liquefaction processes. Specifically, the following are addressed: U.S. coal resources; the Lurgi/Methanol, Lurgi/Methanol/Mobil M, and the Lurgi/Fischer-Tropsch indirect coal liquefaction processes; and envi...

  19. Measurement and modeling of advanced coal conversion processes. Twenty-first quarterly report, October 1, 1991--December 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

    1991-12-31

    The objective of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines.

  20. Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  1. Multifluid modeling of the desulfurization process within a bubbling fluidized bed coal gasifier

    OpenAIRE

    Armstrong, L-M.; Gu, Sai; Luo, K. H.; P Mahanta

    2013-01-01

    The desulfurization process to a two-dimensional (2-D) and three-dimensional (3-D) Eulerian-Eulerian computational fluid dynamic (CFD) model of a coal bubbling fluidized gasifier is introduced. The desulfurization process is important for the reduction of harmful SOx emissions; therefore, the development of a CFD model capable of predicting chemical reactions involving desulfurization is key to the optimization of reactor designs and operating conditions. To model the process, one gaseous pha...

  2. Space Data Collection and Processing of Census for Water Based on ArcGIS%借助ArcGIS进行水利普查空间数据的采集与处理

    Institute of Scientific and Technical Information of China (English)

    宋智丽; 王尊旗

    2013-01-01

    结合江苏省水利普查项目实践,总结了借助ArcGIS平台进行水利普查空间数据的采集与处理的作业经验,有利于作业人员较快掌握有关技术要领.%Combined with Jiangsu census for water project practice, the paper sums up the space data collection and processing of census for water based on ArcGIS, which is conducive to the operating personnel to master the technical essential.

  3. 30 CFR 912.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 912.764 Section 912.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE IDAHO § 912.764...

  4. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NORTH CAROLINA §...

  5. 30 CFR 939.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 939.764 Section 939.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE RHODE ISLAND §...

  6. 30 CFR 941.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 941.764 Section 941.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE SOUTH DAKOTA §...

  7. 30 CFR 910.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 910.764 Section 910.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE GEORGIA § 910.764...

  8. 30 CFR 937.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 937.764 Section 937.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OREGON § 937.764...

  9. 30 CFR 903.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 903.764 Section 903.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE ARIZONA § 903.764...

  10. 30 CFR 905.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 905.764 Section 905.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE CALIFORNIA §...

  11. 30 CFR 922.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 922.764 Section 922.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MICHIGAN §...

  12. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE TENNESSEE §...

  13. 30 CFR 921.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 921.764 Section 921.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MASSACHUSETTS §...

  14. 30 CFR 947.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 947.764 Section 947.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE WASHINGTON §...

  15. Coal Mine Permit Boundaries

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — ESRI ArcView shapefile depicting New Mexico coal mines permitted under the Surface Mining Control and Reclamation Act of 1977 (SMCRA), by either the NM Mining...

  16. The Release of Trace Elements in the Process of Coal Coking

    OpenAIRE

    Jan Konieczyński; Elwira Zajusz-Zubek; Magdalena Jabłońska

    2012-01-01

    In order to assess the penetration of individual trace elements into the air through their release in the coal coking process, it is necessary to determine the loss of these elements by comparing their contents in the charge coal and in coke obtained. The present research covered four coke oven batteries differing in age, technology, and technical equipment. By using mercury analyzer MA-2 and the method of ICP MS As, Be, Cd, Co, Hg, Mn, Ni, Se, Sr, Tl, V, and Zn were determined in samples of ...

  17. Comparative study on transverse shrinkage, mechanical and metallurgical properties of AA2219 aluminium weld joints prepared by gas tungsten arc and gas metal arc welding processes

    OpenAIRE

    Arunkumar, S.; P.Rangarajan; K. Devakumaran; P.Sathiya

    2015-01-01

    Aluminium alloy AA2219 is a high strength alloy belonging to 2000 series. It has been widely used for aerospace applications, especially for construction of cryogenic fuel tank. However, arc welding of AA2219 material is very critical. The major problems that arise in arc welding of AA2219 are the adverse development of residual stresses and the re-distribution as well as dissolution of copper rich phase in the weld joint. These effects increase with increase in heat input. Thus, special atte...

  18. Trace and major element pollution originating from coal ash suspension and transport processes

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, A.; Djordjevic, D.; Polic, P. [University of Belgrade, Belgrade (Yugoslavia). Faculty of Science, Dept. of Chemistry

    2001-07-01

    Coal ash obtained from Nikola Tesla A power plant in Obrenovac, near Belgrade, Yugoslavia, is mixed with water of the Sava river and transported to the dump. In order to assess pollution caused by leaching of some minor and major elements during ash transport through the pipeline, two sets of samples (six samples each) were subjected to a modified sequential extraction. The first set consisted of coal ash samples taken immediately after combustion, while the second set was obtained by extraction with river water, imitating the processes that occur in the pipeline. Samples were extracted consecutively with distilled water and a 1 M solution of KCl, pH 7, and the differences in extractability were compared in order to predict potential pollution. It is concluded that lead and cadmium do not present an environmental threat during and immediately after ash transport to the dump. Portions of zinc, nickel and chromium are released during the ash transport, and arsenic and manganese are released continuously. Copper and iron do not present an environmental threat due to element leaching during and immediately after the coal ash suspension and transport. On the contrary, these elements, as well as chromium, become concentrated during coal ash transport. Adsorbed portions of calcium, magnesium and potassium are also leached during coal ash transport.

  19. Coal Mines, Abandoned - COAL_MINE_ENTRIES_IN: Underground Coal Mine Entrances in Indiana (Indiana Geological Survey, 1:24,000, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — SW_COAL_ENTRY, the predecessor of COAL_MINE_ENTRIES_IN, is a point- based ESRI ArcView shapefile that shows the locations of underground coal mine entrances in the...

  20. Coal Mines, Abandoned - COAL_MINE_UNDERGROUND_IN: Underground Coal Mines in Indiana (Indiana Geological Survey, 1:24,000, Polygon Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — COAL_UND, the predecessor of COAL_MINE_UNDERGROUND_IN, is a polygon-based ESRI ArcView shapefile that shows the location and extent of underground coal mines in the...

  1. Image pre-processing research of coal level in underground coal pocket

    Institute of Scientific and Technical Information of China (English)

    WU Bing; GAO Na

    2008-01-01

    Mathematical morphology is widely applicated in digital image procesing. Vari-ary morphology construction and algorithm being developed are used in deferent digital image processing. The basic idea of mathematical morphology is to use construction ele-ment measure image morphology for solving understand problem. The article presented advanced cellular neural network that forms mathematical morphological cellular neural network (MMCNN) equation to be suit for mathematical morphology filter. It gave the theo-ries of MMCNN dynamic extent and stable state. It is evidenced that arrived mathematical morphology filter through steady of dynamic process in definite condition.

  2. Use of a Nuclear High Temperature Gas Reactor in a Coal-To-Liquids Process

    International Nuclear Information System (INIS)

    AREVA's High Temperature Gas Reactor (HTGR) can potentially provide nuclear-generated, high-level heat to chemical process applications. The use of nuclear heat to help convert coal to liquid fuels is particularly attractive because of concerns about the future availability of petroleum for vehicle fuels. This report was commissioned to review the technical and economic aspects of how well this integration might actually work. The objective was to review coal liquefaction processes and propose one or more ways that nuclear process heat could be used to improve the overall process economics and performance. Shell's SCGP process was selected as the gasifier for the base case system. It operates in the range of 1250 to 1600 C to minimize the formation of tars, oil, and methane, while also maximizing the conversion of the coal's carbon to gas. Synthesis gas from this system is cooled, cleaned, reacted to produce the proper ratio of hydrogen to carbon monoxide and fed to a Fischer-Tropsch (FT) reaction and product upgrading system. The design coal-feed rate of 18,800 ton/day produces 26.000 barrels/day of FT products. Thermal energy at approximately 850 C from a HTGR does not directly integrate into this gasification process efficiently. However, it can be used to electrolyze water to make hydrogen and oxygen, both of which can be beneficially used in the gasification/FT process. These additions then allow carbon-containing streams of carbon dioxide and FT tail-gas to be recycled in the gasifier, greatly improving the overall carbon recovery and thereby producing more FT fuel for the same coal input. The final process configuration, scaled to make the same amount of product as the base case, requires only 5,800 ton/day of coal feed. Because it has a carbon utilization of 96.9%, the process produces almost no carbon dioxide byproduct Because the nuclear-assisted process requires six AREVA reactors to supply the heat, the capital cost is high. The conventional plant is

  3. Process simulation and thermodynamic analysis of an IGCC (integrated gasification combined cycle) plant with an entrained coal gasifier

    International Nuclear Information System (INIS)

    An IGCC (integrated gasification combined cycle) is a widely used electrical power generation system that allows for a variety of feedstocks with high efficiencies. In this study, a 300 MW class IGCC plant was simulated using the PRO/II software package, and thermodynamic analysis was performed. The simulated results were compared to the basic design data for a 300 MW Class IGCC demonstration plant to evaluate the validity. Since changing the feed coal grade causes one of the most significant issues in operating an IGCC system, this study investigated the coal sensitivity of the system by examining two different grade coals (Coal #1: 25,439 kJ/kg and Coal #2:21,338 kJ/kg). Their net powers were determined via thermodynamic analysis and by evaluating the power generation and power consumption and were found to be 324.4 MW and 279.1 MW for Coal #1 and Coal #2. Based on the inlet coal energy, the overall efficiencies under the same conditions were found to be 40.38% for Coal #1 and 41.42% for Coal #2. This paper presents Sankey diagrams for the energy and exergy flow associated with the first and second laws of thermodynamics, and discusses how they influence the major components of the IGCC. As a final point, in order to elucidate the preferable coal in terms of financial sense, economic analysis was carried out on the viability of the cases considered. The costs of electricity for Coal #1 and Coal #2 were evaluated as 0.07 US$/kWh and 0.08 US$/kWh. Hence, Coal #1 can confidently be chosen as a more economic option even though, it costs relatively higher than the other Coal #2. - Highlights: • Process modeling and simulation for IGCC was carried out using PRO/II. • The simulation methodology and result were validated using commercial design data. • Coal sensitivity analysis was performed with two different grade coals. • Power consumption, net power and thermal efficiencies were evaluated for two coals. • Sankey diagram was presented for energy and exergy

  4. Investigation of non-isothermal and isothermal gasification process of coal char using different kinetic model

    Institute of Scientific and Technical Information of China (English)

    Wang Guangwei; Zhang Jianliang; Shao Jiugang; Li Kejiang; Zuo Haibin

    2015-01-01

    Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravi-metric analysis (TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore model (RPM), unreacted shrinking core model (URCM) and volume model (VM). With the increase of heating rate, gasification curve moves into high temperature zone and peak rate of gasification increases;with the increase of gasification temperature, gasification rate increases and the total time of gasification is shortened. The increase of both heating rate and gasification temperature could improve gasification process of coal char. Kinetics analysis indicates that experimental data agree better with the RPM than with the other two models. The apparent activation energy of non-isothermal and isother-mal gasification of coal char using RPM is 193.9 kJ/mol and 212.6 kJ/mol respectively, which are in accor-dance with reported data. Gasification process of coal char under different heating rates and different temperatures are predicted by the RPM derived in this study, and it is found that the RPM predicts the reaction process satisfactorily.

  5. Low-severity catalytic two-stage liquefaction process: Illinois coal conceptual commercial plant design and economics

    Energy Technology Data Exchange (ETDEWEB)

    Abrams, L.M.; Comolli, A.G.; Popper, G.A.; Wang, C.; Wilson, G.

    1988-09-01

    Hydrocarbon Research, Inc. (HRI) is conducting a program for the United States Department of Energy (DOE) to evaluate a Catalytic Two-Stage Liquefaction (CTSL) Process. This program which runs through 1987, is a continuation of an earlier DOE sponsored program (1983--1985) at HRI to develop a new technology concept for CTSL. The earlier program included bench-scale testing of improved operating conditions for the CTSL Process on Illinois No. 6 bituminous coal and Wyoming sub-bituminous coal, and engineering screening studies to identify the economic incentive for CTSL over the single-stage H-Coal/reg sign/ Process for Illinois No. 6 coal. In the current program these engineering screening studies are extended to deep-cleaned Illinois coal and use of heavy recycle. The results from this comparison will be used as a guide for future experiments with respect to selection of coal feedstocks and areas for further process optimization. A preliminary design for CTSL of Illinois deep-cleaned coal was developed based on demonstrated bench-scale performance in Run No. 227-47(I-27), and from HRI's design experience on the Breckinridge Project and H-Coal/reg sign/ Process pilot plant operations at Catlettsburg. Complete conceptual commercial plant designs were developed for a grassroots facility using HRI's Process Planning Model. Product costs were calculated and economic sensitivities analyzed. 14 refs., 11 figs., 49 tabs.

  6. Microstructure and abrasive wear properties of M(Cr,Fe)7C3 carbides reinforced high-chromium carbon coating produced by gas tungsten arc welding (GTAW) process

    OpenAIRE

    Buytoz, Soner; M.Mustafa YILDIRIM

    2010-01-01

    In the present study, high-chromium ferrochromium carbon hypereutectic alloy powder was coated on AISI 4340 steel by the gas tungsten arc welding (GTAW) process. The coating layers were analyzed by optical microscopy, X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), X-ray energy-dispersive spectroscopy (EDS). Depending on the gas tungsten arc welding pa-rameters, either hypoeutectic or hypereutectic microstructures were produced. Wear tests of the coatings were c...

  7. A combined physical/microbial process for the beneficiation of coal

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, G.F.; Stevens, C.J.; Noah, K.S.; McIlwain, M.E.

    1993-09-01

    A large-laboratory scale physical/microbial process was demonstrated for the removal of pyritic sulfur from coal. The process took place in an aerated-trough slurry reactor with a total slurry volume of 150 L. The reactor was divided into six sections, each of which acted as a physical separator and a bioreactor. The process objective was to physically remove the larger pyritic inclusions and to biodegrade the small inclusions (micropyrite). The process was continuously operated for 120 days, treating approximately 1 ton of Illinois {number_sign}6 coal. Ninety percent pyrite removal was achieved at a 20% slurry concentration and a reactor residence time of 5 days. Additional research should be performed to find the optimum values for reactor residence time, slurry concentration, and process hydraulic residence time (or recycle ratio). Finding these optimum values will enable a process to be developed that will maximize the amount of coal that can be processed per unit reactor volume per unit time with the desired level of pyritic sulfur removal.

  8. Selection of an Appropriate Mechanized Mining Technical Process for Thin Coal Seam Mining

    OpenAIRE

    Chen Wang; Shihao Tu

    2015-01-01

    Mechanized mining technical process (MMTP) related to the control method of the shearer is a vital process in thin coal seam mining operations. An appropriate MMTP is closely related to safety, productivity, labour intensity, and efficiency. Hence, the evaluation of alternative MMTP is an important part of the mining design. Several parameters should be considered in MMTP evaluation, so the evaluation is complex and must be compliant with a set of criteria. In this paper, two multiple criteri...

  9. Influence of process parameters on coal combustion performance. Review, experiments and engineering modeling

    Energy Technology Data Exchange (ETDEWEB)

    Lans, R.P. van der

    1997-04-01

    The objective of this study is to improve the understanding of nitrogen oxide formation and carbon burnout during the combustion of pulverized coal, and to contribute to addressing the potential of chemical engineering models for the prediction of furnace temperatures, NO emissions and the amount of carbon in ash. To this purpose, the effect of coal quality on NO and burnout has been investigated experimentally, a radiation heat balance has been developed based on a simple chemical engineering methodology, and a mixing study has been conducted in order to describe the near burner macro mixing in terms of a reactor configuration. The influence of coal type and process conditions on NO formation and carbon burnout has been investigated experimentally in a 400 MW{sub e} corner fired boiler with over fire air, a 350 MW{sub e} opposed fired boiler, and in a 160 kW{sub t} pilot scale test rig. Three different coals were fired in each of the furnaces as part of the activities in group 3 of the European Union JOULE 2 Extension project `Atmospheric Pressure Combustion of Pulverized Coal and Coal Based Blends for Power Generation`. On the pilot scale test both single stage and air staged tests were performed. A simple, one-dimensional combustion and radiation heat transfer model has been developed for the furnace of full scale boilers. The model has been applied to the two boilers mentioned above, and is validated against measured temperatures and carbon in ash concentrations. A mixing study has been performed in order to initiate an investigation of the potential of chemical engineering models to predict NO from pulverized fuel burners. (EG) 11 refs.

  10. Process modeling and thermodynamic analysis of Lurgi fixed-bed coal gasifier in an SNG plant

    International Nuclear Information System (INIS)

    Highlights: • A comprehensive model is proposed for the Lurgi fixed-bed gasifier. • A strategy is proposed to accelerate the convergence of the model solutions. • Satisfactory agreement between model predictions and industrial data is obtained. • An exergy analysis is applied to both the Lurgi gasifier and the gasification system. - Abstract: This paper presents a comprehensive steady state kinetic model of a commercial-scale pressurized Lurgi fixed-bed dry bottom coal gasifier. The model is developed using the simulator Aspen Plus. Five sequential modules: drying zone, pyrolysis zone, gasification zone, combustion zone and overall heat recovery unit, are considered in the main process model. A non-linear programming (NLP) model is employed to estimate the pyrolysis products, which include char, coal gas and high-weight hydrocarbons/distillable liquids (tar, phenol, naphtha and oil). To accelerate solution convergence, an external FORTRAN subroutine is used to simulate the kinetics of the combustion and gasification processes which are formulated in terms of a series of continuous stirred-tank reactors. The model is validated with industrial data. The effects of two key operating parameters, namely oxygen/coal mass ratio and steam/coal mass ratio, on the thermodynamic efficiencies of the Lurgi gasifier and the gasification system as a whole are investigated via extensive simulation studies

  11. Development of a new continuous zeolite production process using coal fly ash

    Energy Technology Data Exchange (ETDEWEB)

    M. Matsukata; A. Yamazaki; S. Ueno; E. Kikuchi; T. Shimoda [Waseda University (Japan). Department of Applied Chemistry

    2003-07-01

    Developing valuable products is important for promoting the effective use of coal ash. Zeolite, microporous crystalline aluminosilicate, is an attractive candidate because it has vast possible applications like water-retaining material, soil conditioner, and ion-exchanger. Further, since mainly consisting of alumina and silica, coal fly ash would be suitable for synthesizing zeolite. We developed a novel process for continuous production of zeolite and applied to the zeolitization of coal fly ash. This process has four sections: (1) Raw materials supply, (2) tubular pre-reactor, (3) main disk-type reactor, and (4) product recovery. The capacity of our bench-scale unit is 400 kg/year. Based on the concept of on a series of continuous stirred tank reactors, the main disk-type reactor was designed. Coal fly ash was supplied to the reactor with NaOH solution and then hydrothermally converted into zeolite in the temperature range of 70-200{degree}C. Though the crystalline part (mainly quartz and mullite) of fly ash stayed in the product, glassy part was successfully converted into zeolite. The main product was P-type zeolite and sodalite became a dominant product at higher temperatures. Alumina was additionally supplied to control Si/Al ratio of raw materials. The addition of an appropriate amount of alumina gave A-type zeolite of which Si/Al ratio = 1 at about 100{degree}C. (Abstract only)

  12. A Study on Comparison of Liquid-phase Methanol Synthesis Processes for Coal-Derived Gas

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jang Sik; Lee, Jong Dae [Dept. of Chem. Eng., Chungbuk National University, Cheongju (Korea); Jong, Heon [Energy Conversion Research Team, Korea Institute of Energy Research, Taejon (Korea)

    2001-04-01

    Two liquid-phase methanol synthesis processed, the 'Methyl Formate Intermediate' process(MF process) and the LPMEOH process, were experimentally investigated to find the suitability of the process for the coal-derived syngas. The MF process showed the superior methanol synthesis rate at the same gas hourly space velocity(GHSV) than LPMEOH process. The MF process showed more than 50% conversion of syngas per pass and 3.7%/day of deactivation rate which are far better than 30% conversion per pass and 24%/day deactivation rate of the LPMEOH process. The reaction condition of the MF process is milder than that of the LPMEOH process. The weakness of the MF process, which is the severe poisoning by small amounts of CO{sub 2}, was able to be overcome from the experimental result that the reaction proceeded even with the syngas with 0.5% CO{sub 2}. Overall comparison reveals that MF process is more suitable than the LPMEOH process when the coal-derived syngas is to be used for methanol synthesis. 18 refs., 12 figs., 2 tabs.

  13. Deposition of various metal, ceramic, and cermet coatings by an industrial-scale large area filtered arc deposition process

    International Nuclear Information System (INIS)

    Nearly defect-free nitride, carbide, and oxiceramic coatings have been deposited by a unidirectional dual large area filtered arc deposition (LAFAD) process. One LAFAD dual arc vapor plasma source was used in both gas ionization and coating deposition modes with and without vertical magnetic rastering of the plasma flow. Substrates made of different metal alloys, as well as carbide and ceramics, were installed at different vertical positions on the 0.5 m diameter turntable of the industrial-scale batch coating system which was rotated at 12 rpm to assess deposition rates and coating thickness uniformity. Targets of the same or different compositions were installed on the primary cathodic arc sources of the LAFAD plasma source to deposit a variety of coating compositions by mixing the metal vapor and reactive gaseous components in a magnetically confined, strongly ionized plasma flow with large kinetic energy. The maximum deposition rate typically ranged from 1.5 μm/h for TiCr/TiCrN to 2.5 μm/h for Ti/TiN multilayer and AlN single layer coatings, and up to 6 μm/h for AlCr-based oxiceramic coatings for primary cathode current ranging from 120 to 140 A. When the arc current was increased to 200 A, the deposition rates of TiN-based coatings were as high as 5 μm/h. The vertical coating thickness uniformity was ±15% inside of a 150 mm area without vertical rastering. Vertical rastering increased the uniform coating deposition area up to 250 mm. The coating thickness distribution was well correlated with the output ion current distribution as measured by a multisection ion collector probe. Coatings were characterized for thickness, surface profile, adhesion, hardness, and elemental composition. Estimates of electrical resistivity indicated good dielectric properties for most of the TiCrAlY-based oxiceramic, oxinitride, and nitride coatings. The multielement LAFAD plasma flow consisting of fully ionized metal vapor with a reactive gas ionization rate in excess of 50

  14. Molten salt coal gasification process development unit. Phase 1. Volume 1. PDU operations. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kohl, A.L.

    1980-05-01

    This report summarizes the results of a test program conducted on the Molten Salt Coal Gasification Process, which included the design, construction, and operation of a Process Development Unit. In this process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for regeneration of sodium carbonate, removal of sulfur, and disposal of the ash. The process can handle a wide variety of feed materials, including highly caking coals, and produces a gas relatively free from tars and other impurities. The gasification step is carried out at approximately 1800/sup 0/F. The PDU was designed to process 1 ton per hour of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur and ash in forms suitable for disposal. Five extended test runs were made. The observed product gas composition was quite close to that predicted on the basis of earlier small-scale tests and thermodynamic considerations. All plant systems were operated in an integrated manner during one of the runs. The principal problem encountered during the five test runs was maintaining a continuous flow of melt from the gasifier to the quench tank. Test data and discussions regarding plant equipment and process performance are presented. The program also included a commercial plant study which showed the process to be attractive for use in a combined-cycle, electric power plant. The report is presented in two volumes, Volume 1, PDU Operations, and Volume 2, Commercial Plant Study.

  15. Characteristics and performance of the variable polarity plasma arc welding process used in the Space Shuttle external tank

    Science.gov (United States)

    Hung, R. J.; Lee, C. C.; Liu, J. W.

    1990-01-01

    Significant advantages of the Variable Polarity Plasma Arc (VPPA) Welding Process include faster welding, fewer repairs, less joint preparation, reduced weldment distortion, and absence of porosity. Flow profiles and power distribution of argon plasma gas as a working fluid to produce plasma arc jet in the VPPA welding process was analyzed. Major loss of heat transfer for flow through the nozzle is convective heat transfer; for the plasma jet flow between the outlet of the nozzle and workpiece is radiative heat transfer; and for the flow through the keyhole of the workpiece is convective heat transfer. The majority of the power absorbed by the keyhole of the workpiece is used for melting the solid metal workpiece into a molten metallic puddle. The crown and root widths and the crown and root heights can be predicted. An algorithm for promoting automatic control of flow parameters and the dimensions of the final product of the welding specification to be used for the VPPA Welding System operated at MSFC are provided.

  16. Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment. Quarterly technical progress report, March--May 1990

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, R.M.; Miller, R.L.

    1990-12-31

    The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal conversion utilizing low rank coals and low severity conditions (reaction temperatures generally less than 350{degrees}C) are the primary focus of the liquefaction experiments, as it is expected that the effect of pretreatment conditions and the attendant reactivity enhancement will be greatest for these coals and at these conditions. This document presents a comprehensive report summarizing the findings on the effect of mild alkylation pretreatment on coal reactivity under both direct hydroliquefaction and liquefaction co-processing conditions. Results of experiments using a dispersed catalyst system (chlorine) are also presented for purposes of comparison. IN general, mild alkylation has been found to be an effective pretreatment method for altering the reactivity of coal. Selective (oxygen) methylation was found to be more effective for high oxygen (subbituminous) coals compared to coals of higher rank. This reactivity enhancement was evidenced under both low and high severity liquefaction conditions, and for both direct hydroliquefaction and liquefaction co-processing reaction environments. Non-selective alkylation (methylation) was also effective, although the enhancement was less pronounced than found for coal activated by O-alkylation. The degree of reactivity enhancement was found to vary with both liquefaction and/or co-processing conditions and coal type, with the greatest positive effect found for subbituminous coal which had been selectively O-methylated and subsequently liquefied at low severity reaction conditions. 5 refs., 18 figs., 9 tabs.

  17. Investigations of some aspects of the spray process in a single wire arc plasma spray system using high speed camera.

    Science.gov (United States)

    Tiwari, N; Sahasrabudhe, S N; Tak, A K; Barve, D N; Das, A K

    2012-02-01

    A high speed camera has been used to record and analyze the evolution as well as particle behavior in a single wire arc plasma spray torch. Commercially available systems (spray watch, DPV 2000, etc.) focus onto a small area in the spray jet. They are not designed for tracking a single particle from the torch to the substrate. Using high speed camera, individual particles were tracked and their velocities were measured at various distances from the spray torch. Particle velocity information at different distances from the nozzle of the torch is very important to decide correct substrate position for the good quality of coating. The analysis of the images has revealed the details of the process of arc attachment to wire, melting of the wire, and detachment of the molten mass from the tip. Images of the wire and the arc have been recorded for different wire feed rates, gas flow rates, and torch powers, to determine compatible wire feed rates. High speed imaging of particle trajectories has been used for particle velocity determination using time of flight method. It was observed that the ripple in the power supply of the torch leads to large variation of instantaneous power fed to the torch. This affects the velocity of the spray particles generated at different times within one cycle of the ripple. It is shown that the velocity of a spray particle depends on the instantaneous torch power at the time of its generation. This correlation was established by experimental evidence in this paper. Once the particles leave the plasma jet, their forward speeds were found to be more or less invariant beyond 40 mm up to 500 mm from the nozzle exit. PMID:22380128

  18. Vacuum arc behavior and its voltage characteristics in drawing process controlled by composite magnetic fields along axial and transverse directions

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Lijun, E-mail: lijunwang@mail.xjtu.edu.cn; Deng, Jie; Wang, Haijing; Jia, Shenli; Qin, Kang; Shi, Zongqian [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China)

    2015-10-15

    In this research, drawing vacuum arc (VA) experiments were conducted using composite contacts under currents ranging from 5 kA to 20 kA root mean square (rms). The new type of contact comprised an axial magnetic field (AMF) configuration and a transverse magnetic field (TMF) configuration. The TMF plate was in the center, surrounded by the AMF plate. The contact generated both AMFs and TMFs simultaneously. VA appearances and arc voltages were recorded, and the VA was modeled as a conductor for electromagnetic force analysis in ANSYS software. The results showed that the coaxiality of operating mechanisms significantly influenced arc behavior just as the arc was ignited. When arc brightness did not increase after ignition, there was a voltage drop accompanied with diffusion of the VA. As to VA development, when an arc was ignited on an AMF plate, it spread on the plate and rotated. Over time the arc current increased, the constricting arc forms, and the arc column rotated on the TMF plate under the action of Ampere's force. With regard to the influence of a magnetic field on a VA at different stages, in the initial drawing arc stage the TMF was dominant, and the arc started to rotate under the action of Ampere's force. Afterwards, the AMF was dominant, with a steadily burning arc. As for contact melting, in the initial arcing period, a contracted short arc caused severe melting and erosion of the contact plate. When the ignition spot or root was close to the slot of plate, the electromagnetic force pushed the arc toward slot and contact edge, resulting in local erosion of the slot region.

  19. Vacuum arc behavior and its voltage characteristics in drawing process controlled by composite magnetic fields along axial and transverse directions

    Science.gov (United States)

    Wang, Lijun; Deng, Jie; Wang, Haijing; Jia, Shenli; Qin, Kang; Shi, Zongqian

    2015-10-01

    In this research, drawing vacuum arc (VA) experiments were conducted using composite contacts under currents ranging from 5 kA to 20 kA root mean square (rms). The new type of contact comprised an axial magnetic field (AMF) configuration and a transverse magnetic field (TMF) configuration. The TMF plate was in the center, surrounded by the AMF plate. The contact generated both AMFs and TMFs simultaneously. VA appearances and arc voltages were recorded, and the VA was modeled as a conductor for electromagnetic force analysis in ANSYS software. The results showed that the coaxiality of operating mechanisms significantly influenced arc behavior just as the arc was ignited. When arc brightness did not increase after ignition, there was a voltage drop accompanied with diffusion of the VA. As to VA development, when an arc was ignited on an AMF plate, it spread on the plate and rotated. Over time the arc current increased, the constricting arc forms, and the arc column rotated on the TMF plate under the action of Ampere's force. With regard to the influence of a magnetic field on a VA at different stages, in the initial drawing arc stage the TMF was dominant, and the arc started to rotate under the action of Ampere's force. Afterwards, the AMF was dominant, with a steadily burning arc. As for contact melting, in the initial arcing period, a contracted short arc caused severe melting and erosion of the contact plate. When the ignition spot or root was close to the slot of plate, the electromagnetic force pushed the arc toward slot and contact edge, resulting in local erosion of the slot region.

  20. Vacuum arc behavior and its voltage characteristics in drawing process controlled by composite magnetic fields along axial and transverse directions

    International Nuclear Information System (INIS)

    In this research, drawing vacuum arc (VA) experiments were conducted using composite contacts under currents ranging from 5 kA to 20 kA root mean square (rms). The new type of contact comprised an axial magnetic field (AMF) configuration and a transverse magnetic field (TMF) configuration. The TMF plate was in the center, surrounded by the AMF plate. The contact generated both AMFs and TMFs simultaneously. VA appearances and arc voltages were recorded, and the VA was modeled as a conductor for electromagnetic force analysis in ANSYS software. The results showed that the coaxiality of operating mechanisms significantly influenced arc behavior just as the arc was ignited. When arc brightness did not increase after ignition, there was a voltage drop accompanied with diffusion of the VA. As to VA development, when an arc was ignited on an AMF plate, it spread on the plate and rotated. Over time the arc current increased, the constricting arc forms, and the arc column rotated on the TMF plate under the action of Ampere's force. With regard to the influence of a magnetic field on a VA at different stages, in the initial drawing arc stage the TMF was dominant, and the arc started to rotate under the action of Ampere's force. Afterwards, the AMF was dominant, with a steadily burning arc. As for contact melting, in the initial arcing period, a contracted short arc caused severe melting and erosion of the contact plate. When the ignition spot or root was close to the slot of plate, the electromagnetic force pushed the arc toward slot and contact edge, resulting in local erosion of the slot region

  1. Characterization of titanium welded joints by the orbital gas tungsten arc welding process for aerospace application

    Directory of Open Access Journals (Sweden)

    José A. Orlowski de Garcia

    2010-08-01

    Full Text Available In this work, three welding programs for orbital gas tungsten arc welding (GTAW, previously developed, were used, using pulsed current and increasing speed (#A, constant current (#B and pulsed current and decreasing current (#C. One of these should be used for the propulsion system of the Satellite CBERS (China – Brazil Earth Resources Satellite. Welded joints using tubes of commercially pure titanium were obtained with these procedures, which were characterized by means of mechanical and metallographic tests. The obtained results showed that the three welding procedures produce welded joints free of defects and with adequate shape. Although small differences on mechanical properties and on microstructure have been observed, the three welding programs attained compatible results with international standards used in the aerospace segment. The welding program #B, due to the reduced heat input used, was considered to obtain slightly advantage over the others.

  2. Arc-sprayed Coatings for High Temperature Reactors in Titanium Sponge Process

    Science.gov (United States)

    Zhang, Z. L.; Gong, X.; Zhang, N. N.

    2015-07-01

    An arc-sprayed composite coating consisted of an under coat Fe25Cr5Al and a top coat Al5Si was sprayed on the reactor wall surface, which is made of mild steel and used for batch production of titanium sponges. After a trial for 15 production cycles, the morphology of the sprayed coating changed greatly into somewhat like a thermal barrier coating. A large number of composite oxides containing aluminum and chromium had been generated in situ within the protective coatings, especially close to the coating/substrate interface. The oxides generated at the interface could improve the bonding of the coating to the steel substrate together with the surface alumina on the coating surface may provide an effective and long-term protection to the steel substrate of reactor at high temperatures.

  3. Coal fields and outlines of coal-bearing strata in the Colorado Plateau coal assessment study area (cpcf*g)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These are shapefiles and ARC/INFO coverages of coal fields and coal-bearing formations in the Colorado Plateau. These GIS layers were created by combining numerous...

  4. Choice of antipyrogenetic substances and their inhibition influence to self burning processes in coal

    International Nuclear Information System (INIS)

    Coal inclination towards spontaneous ignition and the frequent endogenous fires represent very actual problem which imposes the need for their complete study, following-up and finding out of corresponding solutions. The paper presents the functional dependence of separate parameters having direct influence on oxidation process, which unavoidably, lead towards spontaneous ignition of the lignite. Moreover, the natural index of spontaneous ignition after the Olpinsky method has been determined on the representative lignite tests, which has been based on velocity measurement of the uncombined heat in the moment of adiabatic oxidation. The results obtained range from 83 to 115 oC/min, which points out that in the investigated coal district there are coal layers being proned towards spontaneous ignition. Anti pyrogenic measure has been chosen from a group of inhibitors which action is based by contact interruption between the coal and the oxygen in the air. Lignite inhibition has been made by a chosen inhibitor in concentration from 0-20%. From the experimental investigation, it is evident the great influence of the applied inhibitor on the natural index of spontaneous ignition. Thus, determined values of the natural index of spontaneous ignition of the already inhibited tests, show an inhibitory action ranging from 28.69 to 83.47%. (Author)

  5. Fe and Mn removal from mining drainage using goaf filling materials obtained from coal mining process.

    Science.gov (United States)

    Zhang, Liping; Chen, Aolei; Qu, Hongbin; Xu, Shouqiang; Zhang, Xue; He, Xuwen

    2015-01-01

    Coal gangue, sandy soil and clay (mass ratio 45:4:1) as goaf filling materials acquired from coal mining processes were applied to remove Fe and Mn effectively from mining drainage. The results of an adsorption kinetic study showed that the Fe adsorption equation was y=21.454y+8.4712, R2=0.9924 and the Mn adsorption equation was y=7.5409x+0.905, R2=0.9957. Meanwhile, the goaf filling materials had low desorption capacity (Fe 6.765 μg/g, Mn 1.52 μg/g) and desorption ratio (Fe 8.98%, Mn 11.04%). Experiments demonstrated that Fe and Mn from mining drainage could be removed stably at a flow rate of 1.2 L/min, Fe inlet concentration of less than 40 mg/L, Mn inlet concentration of less than 2 mg/L and neutral or alkaline conditions. During a procedure of continuous experiments, the effluent quality could meet the requirement of the 'Code for Engineering Design of Sewage Regeneration-GB503352-2002'. A real-application project using goaf filling materials to treat mining drainage in Shendong coal mine showed that the average cost per ton of mining drainage was about 0.55 RMB, which could bring about considerable economic benefit for coal mining enterprises. PMID:26606087

  6. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-12-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

  7. The production of a premium solid fuel from Powder River Basin coal. [COMPCOAL Process

    Energy Technology Data Exchange (ETDEWEB)

    Merriam, N.; Sethi, V.; Thomas, K.; Grimes, R.W.

    1992-01-01

    This report describes our initial evaluation of a process designed to produce premium-quality solid fuel from Powder River Basin (PRB) coal. The process is based upon our experience gained by producing highly-reactive, high-heating-value char as part of a mild-gasification project. In the process, char containing 20 to 25 wt % volatiles and having a gross heating value of 12,500 to 13,000 Btu/lb is produced. The char is then contacted by coal-derived liquid. The result is a deposit of 6 to 8 wt % pitch on the char particles. The lower boiling component of the coal-derived liquid which is not deposited on the char is burned as fuel. Our economic evaluation shows the process will be economically attractive if the product can be sold for about $20/ton or more. Our preliminary tests show that we can deposit pitch on to the char, and the product is less dusty, less susceptible to readsorption of moisture, and has reduced susceptibility to self heating.

  8. Surface Modification of Micro-Alloyed High-Strength Low-Alloy Steel by Controlled TIG Arcing Process

    Science.gov (United States)

    Ghosh, P. K.; Kumar, Ravindra

    2015-02-01

    Surface modification of micro-alloyed HSLA steel plate has been carried out by autogenous conventional and pulse current tungsten inert gas arcing (TIGA) processes at different welding parameters while the energy input was kept constant. At a given energy input the influence of pulse parameters on the characteristics of surface modification has been studied in case of employing single and multi-run procedure. The role of pulse parameters has been studied by considering their summarized influence defined by a factor Φ. The variation in Φ and pulse frequency has been found to significantly affect the thermal behavior of fusion and accordingly the width and penetration of the modified region along with its microstructure, hardness and wear characteristics. It is found that pulsed TIGA is relatively more advantageous over the conventional TIGA process, as it leads to higher hardness, improved wear resistance, and a better control over surface characteristics.

  9. New Approach to Study the Ignition Processes of Organic Coal-Water Fuels in an Oxidizer Flow

    Science.gov (United States)

    Valiullin, T. R.; Dmitrienko, M. A.; Strizhak, P. A.

    2016-02-01

    To converge the conditions of organic water-coal fuel composition combustion in the typical power equipment we developed a new approach and installed an experimental setup, eliminating the traditional fixing the fuel droplets on the thermocouples or rods. Specialized cone-shaped chamber was used to implement the process of lingering of organic water-coal fuel droplets. Necessary and sufficient conditions for the lingering of organic water-coal fuel droplets were established. We determined the parameters of the system (droplet size of 0.4-0.6 mm, temperatures 823-903 K and the velocity of the oxidizer flow 1.5-6 m/s) at which the droplets were consistently ignited in the process of lingering. Minimum temperatures and ignition delay times of organic water-coal fuel droplets based on brown coal, used motor, turbine, transformer oils, kerosene, gasoline and water were defined.

  10. New Approach to Study the Ignition Processes of Organic Coal-Water Fuels in an Oxidizer Flow

    Directory of Open Access Journals (Sweden)

    Valiullin T.R.

    2016-01-01

    Full Text Available To converge the conditions of organic water-coal fuel composition combustion in the typical power equipment we developed a new approach and installed an experimental setup, eliminating the traditional fixing the fuel droplets on the thermocouples or rods. Specialized cone-shaped chamber was used to implement the process of lingering of organic water-coal fuel droplets. Necessary and sufficient conditions for the lingering of organic water-coal fuel droplets were established. We determined the parameters of the system (droplet size of 0.4-0.6 mm, temperatures 823-903 K and the velocity of the oxidizer flow 1.5-6 m/s at which the droplets were consistently ignited in the process of lingering. Minimum temperatures and ignition delay times of organic water-coal fuel droplets based on brown coal, used motor, turbine, transformer oils, kerosene, gasoline and water were defined.

  11. Coal Fields - COAL_NCRDS_IN: Coal Resource Data in Indiana, Derived from the National Coal Resource Data System (Indiana Geological Survey, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This ESRI ArcInfo point shapefile depicts the location of 9,117 public point-source coal resource data points in Indiana. This shapefile includes location and coal...

  12. Clean coal technology: commercial-scale demonstration of the liquid phase methanol (LPMEOH{trademark}) process

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-04-01

    The report discusses the demonstration of Air Products and Chemical, Inc.`s Liquid Phase Methanol (LPMEOTH {trademark}) Process which is designed to convert synthesis gas derived from the gasification of coal into methanol for use as a chemical intermediate or as a low-sulfur dioxide and low-nitrogen oxides emitting alternative fuel. The project was selected for funding by the US Clean Coal Technology Program Round III in 1992. Construction of the Demonstration Project at Eastman Chemical Co`s Kingsport complex began in October 1995 and was completed in January 1997. Production rates of over 300 tons per day of methanol have been achieved and availability for the unit has exceeded 96% since startup. The LPMEOH{trademark} Process can enhance integrated gasification combined cycle (IGCC) power generation by converting part of the syngas from the gasifier to methanol which can be solid or used as a peak-sharing fuel. 50 refs., 5 figs., 7 photos.

  13. Coal liquefaction process streams characterization and evaluation. Volume 2, Participants program final summary evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, S.D.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1994-05-01

    This 4.5-year project consisted of routine analytical support to DOE`s direct liquefaction process development effort (the Base Program), and an extensive effort to develop, demonstate, and apply new analytical methods for the characterization of liquefaction process streams (the Participants Program). The objective of the Base Program was to support the on-going DOE direct coal liquefaction process development program. Feed, process, and product samples were used to assess process operations, product quality, and the effects of process variables, and to direct future testing. The primary objective of the Participants Program was to identify and demonstrate analytical methods for use in support of liquefaction process develpment, and in so doing, provide a bridge between process design, development, and operation and analytical chemistry. To achieve this direct coal liquefaction-derived materials. CONSOL made an evaluation of each analytical technique. During the performance of this project, we obtained analyses on samples from numerous process development and research programs and we evaluated a variety of analytical techniques for their usefulness in supporting liquefaction process development. Because of the diverse nature of this program, we provide here an annotated bibliography of the technical reports, publications, and formal presentations that resulted from this program to serve as a comprehensive summary of contract activities.

  14. Airborne contamination of forest soils by carbonaceous particles from industrial coal processing

    OpenAIRE

    Schmidt, M. W. I.; Knicker, Heike; Hatcher, Patrick G.; Kögel-Knabner, I.

    2000-01-01

    In the German Ruhr-area industrial coal processing emitted large amounts of carbonaceous particles for a century until 1970. Our objectives were to detect the presence of airborne carbonaceous particles and assess their impact on the chemical structure of soil organic matter in two forest soils (Podzols) with potential sources of carbonaceous particles approximately 10 to 30 km away. Contamination was not visible macroscopicaily. Organic matter was characterized in bulk soils and in particle-...

  15. Silica membranes for hydrogen separation in coal gas processing. Final report, January 1993

    OpenAIRE

    Gavalas, G. R.

    1993-01-01

    The general objective of this project was to synthesize permselective membranes suitable for hydrogen separation from coal gas. The specific objectives were: (i) to synthesize membranes by chemical vapor deposition (CVD) of SiO(sub 2) or other oxides on porous support tubes, (ii) characterize the membranes by permeation measurements of various gases and by electron microscopy, and (iii) obtain information about the mechanism and kinetics Of SiO(sub 2) deposition, and model the process of memb...

  16. IMPROVING METHODS OF MODELING CANAL WAVES PROPAGATION PROCESS IN COAL SEAMS

    OpenAIRE

    SMIRNOV YU.M.; КЕNZHIN B.М.

    2012-01-01

    There has been analyzed the principal methods of modeling the process of canal waves propagation in coal seams when carrying out mining geophysical studies. There has been established that the wave guide moving into the surface of the elastic half-space doesn’t practically change the main properties of the interferential waves propagating in them. There has been recommended to use Fourier integral describing the single pulse spectrum for studying the registered seismograms. There have been fo...

  17. Modeling and optimization of processes for clean and efficient pulverized coal combustion in utility boilers

    Directory of Open Access Journals (Sweden)

    Belošević Srđan V.

    2016-01-01

    Full Text Available Pulverized coal-fired power plants should provide higher efficiency of energy conversion, flexibility in terms of boiler loads and fuel characteristics and emission reduction of pollutants like nitrogen oxides. Modification of combustion process is a cost-effective technology for NOx control. For optimization of complex processes, such as turbulent reactive flow in coal-fired furnaces, mathematical modeling is regularly used. The NOx emission reduction by combustion modifications in the 350 MWe Kostolac B boiler furnace, tangentially fired by pulverized Serbian lignite, is investigated in the paper. Numerical experiments were done by an in-house developed three-dimensional differential comprehensive combustion code, with fuel- and thermal-NO formation/destruction reactions model. The code was developed to be easily used by engineering staff for process analysis in boiler units. A broad range of operating conditions was examined, such as fuel and preheated air distribution over the burners and tiers, operation mode of the burners, grinding fineness and quality of coal, boiler loads, cold air ingress, recirculation of flue gases, water-walls ash deposition and combined effect of different parameters. The predictions show that the NOx emission reduction of up to 30% can be achieved by a proper combustion organization in the case-study furnace, with the flame position control. Impact of combustion modifications on the boiler operation was evaluated by the boiler thermal calculations suggesting that the facility was to be controlled within narrow limits of operation parameters. Such a complex approach to pollutants control enables evaluating alternative solutions to achieve efficient and low emission operation of utility boiler units. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018: Increase in energy and ecology efficiency of processes in pulverized coal-fired furnace and optimization of utility steam boiler air preheater by using in

  18. Alternative utilization of organic wastes - their co-processing with coal

    Czech Academy of Sciences Publication Activity Database

    Kříž, Vlastimil; Bučko, Z.

    Ostrava: Vysoká škola báňská, 2006 - (Fečko, P.), s. 7-10 ISBN 80-248-1088-3. [Conference on enviroment and mineral processing /10./. Ostrava (CZ), 22.06.2006-24.06.2006] Institutional research plan: CEZ:AV0Z30460519 Keywords : gasification * coal * used tires Subject RIV: DM - Solid Waste and Recycling

  19. Assessment of H-Coal process developments: impact on the performance and economics of a proposed commercial plant

    Energy Technology Data Exchange (ETDEWEB)

    Talib, A.; Gray, D.; Neuworth, M.

    1984-01-01

    This report assesses the performance of the H-Coal process, a catalytic direct liquefaction process, at a process development and large pilot-plant scale of operation. The assessment focused on the evaluation of operating results from selected long-term successful process development unit (PDU) and pilot plant runs made on Illinois No. 6 coal. The pilot plant has largely duplicated the product yield structure obtained during the PDU runs. Also, the quality of products, particularly liquid products, produced during the pilot plant run is quite comparable to that produced during the PDU runs. This confirms the scalability of the H-Coal ebullated-bed reactor system from a PDU-scale, 3 tons of coal per day, to a large pilot scale, 220 tons of coal per day, plant. The minor product yield differences, such as higher yields of C/sub 3/, C/sub 4/, and naphtha fractions, and lower yields of distillate oils obtained during pilot plant runs as compared to the PDU runs, will not impact the projected technical and economic performance of a first-of-a-kind commercial H-Coal plant. Thus, the process yield and operating data collected during the PDU operations provided an adequate basis for projecting the technical and economic performance of the proposed H-Coal commercial plant. 18 references, 9 figures, 56 tables.

  20. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, January 1, through March 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Accomplishments for this quarter are described.

  1. Environmental quality and energy conservation in coal conversion processes. [Overall minimization of energy required for sulfur pollution control

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, G.L.; Hill, A.H.; Fleming, D.K.

    1979-01-01

    In general, controlling emissions from a coal conversion process is an energy consuming process. In this paper, a parametric assessment of energy requirements for sulfur management in a coal gasification process to produce substitute natural gas is presented. The results of this assessment suggest that the least energy intensive sulfur management practice to utilize in coal gasification plants using low sulfur coal (< 3.5%) is an H/sub 2/S selective removal process providing a Claus plant feed-stream containing 10% or less H/sub 2/S with tail gas from the Claus plant being incinerated in the coal-fired boiler and the additional SO/sub 2/ removed in the flue gas desulfurization (FGD) system. For high sulfur coals (> 3.5%), energy consumptions for all combinations were similar for a given FGD SO/sub 2/ removal specification. As the SO/sub 2/ specification increases for the FGD system, the total energy required for sulfur management also increases. Finally, contrary to expectations, the total energy requirements for sulfur management decrease with increasing sulfur content of the feed coal indicating that the energy requiements of the H/sub 2/S removal process dominates. The total energy requirements for the two Claus plant tail gas treatment processes are similar. Incineration in the boiler is slightly more energy efficient. For low sulfur coals (< 3.5%) the total energy requirements decreased rapidly as the level of H/sub 2/S selective acid-gas removal process decreased from 30% to 10%. For high sulfur coals (> 3.5%) the total energy requirements were similar for all levels of H/sub 2/S in the Claus plant feed gas with a possible minimum in energy requirements for the 15% H/sub 2/S cases.

  2. Characteristic of coal combustion in oxygen/carbon dioxide atmosphere and nitric oxide release during this process

    International Nuclear Information System (INIS)

    Combustion characteristic of a bituminous coal and an anthracite coal in oxygen/carbon dioxide (O2/CO2) atmosphere is investigated in a thermogravimetric (TG) analyzer. The characteristic parameters, which are deduced from the TG-DTG (differential thermogravimetric) curves, show that the coal combustion process is basically kept consistent in O2/CO2 and O2/N2 atmosphere at the O2 concentration of 20%. The Coats-Redfern method with the reaction order of 1.25 could perfectly describe the combustion process in these two different atmospheres through the calculation of the kinetic parameters for the two coals. Nitric oxide (NO) release is concentrated in a narrower time period in O2/CO2 atmosphere compared with the one in O2/N2 atmosphere during the coal combustion process. Though the high value of the NO release rate peak, the total conversion of the fuel-N to NO is strongly depressed in O2/CO2 atmosphere, and at 1473 K, the conversion is reduced by 28.99% for the bituminous coal and 22.54% for the anthracite coal, respectively. When O2 concentration is increased from 20% to 40% in O2/CO2 atmosphere, the coal combustion property is obviously improved with the shift of the whole process into the lower temperature zone and the more intensive of the reaction occurrence in a narrower temperature range. However, the total fuel-N to NO conversion is increased accordingly. For bituminous coal the increase is 17.22% at 1073 K and 20.51% at 1173 K, and for anthracite coal the increase is 15.73% at 1073 K and 16.19% at 1173 K.

  3. Coal conversion processes. Quarterly report, December 13, 1983-March 12, 1984

    Energy Technology Data Exchange (ETDEWEB)

    Cobb, J.T. Jr.; Biloen, P.; Holder, G.D.; Klinzing, G.E.; Tierney, J.W.

    1984-05-01

    Experimental work is continuing on four separate projects related to coal conversion processes. The direct digital control of exothermic multiphase reactions is being studied in an experimental adiabatic flow reactor. The existence of two stable steady states for the Fischer-Tropsch reaction network at the same temperature and feed condition has been verified and quantified. Various absorbents for SO/sub 2/ and NO/sub X/ are being studied. The absorption of NO/sub 2/ by methanol and N-cyclohexyl-2-pyrrolidone has been extensively examined. Preliminary data have been obtained with triethylene-tetraamine. Hindered amines will be studied next. Procedures for the preparation of liquid membranes have been tested and the incorporation of hindered amines in them will now be examined. Isotopic switching is being used to study the way in which promoters affect supported metal catalysts. With improved resolution from the mass spectrometer, early quantitative results give indications of three different surface species and of non-statistical ingrowth of /sup 13/C into the product molecules. A program for the study of the extraction of coal and oil shale using supercritical fluids is being carried out. The effect of the presence of piperidine on the amount of toluene solubles produced by supercritical extraction of coal with toluene/piperidine mixture has been determined. A new kinetic model for the extraction/liquefaction of coal by supercritical toluene and THF has been developed and proven satisfactory. Bruceton coal and Hi Na lignite have been extracted with supercritical water. 3 references, 7 figures, 6 tables.

  4. ALICE - ARC integration

    OpenAIRE

    Anderlik, Csaba; Gregersen, Anders Rhod; Kleist, Josva; Peters, Andreas; Siaz, Pablo

    2007-01-01

    AliEn or Alice Environment is the Gridware developed and used within the ALICE collaboration for storing and processing data in a distributed manner. ARC (Advanced Resource Connector) is the Grid middleware deployed across the Nordic countries and gluing together the resources within the Nordic Data Grid Facility (NDGF). In this paper we will present our approach to integrate AliEn and ARC, in the sense that ALICE data management and job processing can be carried out on the NDGF infrastructur...

  5. Role of the Liquids From Coal process in the world energy picture

    Energy Technology Data Exchange (ETDEWEB)

    Frederick, J.P.; Knottnerus, B.A. [ENCOAL Corp., Gillette, WY (United States)

    1997-12-31

    ENCOAL Corporation, a wholly owned indirect subsidiary of Zeigler Coal Holding Company, has essentially completed the demonstration phase of a 1,000 Tons per day (TPD) Liquids From Coal (LFC{trademark}) plant near Gillette, Wyoming. The plant has been in operation for 4{1/2} years and has delivered 15 unit trains of Process Derived Fuel (PDF{trademark}), the low-sulfur, high-Btu solid product to five major utilities. Recent test burns have indicated the PDF{trademark} can offer the following benefits to utility customers: lower sulfur emissions, lower NO{sub x} emissions, lower utilized fuel costs to power plants, and long term stable fuel supply. More than three million gallons of Coal Derived Liquid (CDL{trademark}) have also been delivered to seven industrial fuel users and one steel mill blast furnace. Additionally, laboratory characteristics of CDL{trademark} and process development efforts have indicated that CDL{trademark} can be readily upgraded into higher value chemical feedstocks and transportation fuels. Commercialization of the LFC{trademark} is also progressing. Permit work for a large scale commercial ENCOAL{reg_sign} plant in Wyoming is now underway and domestic and international commercialization activity is in progress by TEK-KOL, a general partnership between SGI International and a Zeigler subsidiary. This paper covers the historical background of the project, describes the LFC{trademark} process and describes the worldwide outlook for commercialization.

  6. Study of the processes for of remelting zirconium alloys in an electric arc furnace

    International Nuclear Information System (INIS)

    Zirconium alloy tubes are used as cladding for fuel elements of PWR nuclear reactors, which contains the UO2 pellets. In the manufacture of these fuel element parts, machining chips from the nuclear grade zirconium alloys are generated. Hence, these machining chips cannot be discarded, as ordinary metallic waste. Thus, the recycling of this material is a strategic aspect for the nuclear technology, both for economic and environmental issues. The main reason is that nuclear grade alloys have very high cost, are not commercially produced in Brazil and has to be imported for the manufacture of the nuclear fuels. This work discusses a method to melt and recycle Zircaloy chips, using an electric-arc furnace to obtain small laboratory ingots. The chemical composition of the ingots was determined using X-ray fluorescence spectroscopy and was compared to the specifications of nuclear grade Zircaloy and to the chemical composition of the received machining chips. The ingots were annealed in high vacuum, as well as were hot rolled in a mill. The microstructures were characterized by optical microscopy. The hardness was evaluated using the Rockwell B scale hardness. The results showed that the compositions of the recycled Zircaloy comply with the chemical specifications and a suitable microstructure has been obtained for nuclear use. (author)

  7. Twin-wire Submerged Arc Welding Process of a High-strength Low-alloy Steel

    Institute of Scientific and Technical Information of China (English)

    YANG Xiuzhi; XU Qinghua; YIN Niandong; XIAO Xinhua

    2011-01-01

    The measurement of thermal cycle curves of a high-strength low-alloy steel (HSLA)subjected twin-wire submerged arc welding (SAW) was introduced. The thermal simulation test was performed by using the obtained curves. The impact toughness at -50 ℃ temperature of the simulated samples was also tested. OM, SEM and TEM of the heat-affected zone (HAZ) of some simulation specimens were investigated. The results showed that the HSLA endured the twin-wire welding thermal cycle, generally, the low-temperature toughness values of each part of HAZ was lower than that of the parent materials, and the microstructure of coarse-grained zone(CGHAZ) mainly made up of granular bainite is the reason of the toughness serious deterioration. Coarse grain, grain boundary carbide extract and M-A island with large size and irregular polygon, along the grain boundary distribution, are the reasons for the toughness deterioration of CGHAZ. The research also showed that selected parameters of twin-wire SAW can meet the requirements to weld the test steel.

  8. Processing and structure of in situ Fe-Al alloys produced by gas tungsten arc welding

    Energy Technology Data Exchange (ETDEWEB)

    Banovic, S.W.; DuPont, J.N.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States). Energy Research Center

    1997-02-14

    Iron aluminide weld overlays are being investigated for corrosion and erosion protection of boiler tubes in low NOx burners. The primary objective of the research is to identify overlay compositions which can be deposited in a crack-free condition and provide corrosion protection in moderately reducing environments. In the current phase of work, Fe-Al alloy weld overlays were produced by depositing commercially pure aluminum wire on to low carbon steel substrates using Gas Tungsten Arc Welding. A systematic variation of the wire feed speed and current, two major factors affecting dilution, resulted in a variation in aluminum contents of the welds ranging from 3--42 wt% aluminum. The aluminum content was observed to increase with wire feed speed and a decrease in the current. The aluminum content was also found to affect the cracking susceptibility of the overlays. At 10wt% aluminum, few to no cracks were observed in the deposits. Above this value, cracking was prevalent throughout the weld. In addition, two types of microstructures were found correlating to different concentrations of aluminum. A homogeneous matrix with second phase particles consisting of coarse columnar grains was found for low aluminum concentrations. With higher aluminum contents, a two-phase constituent was observed to surround primary dendrites growing from the substrate. The transition of the microstructures occurred between 24 and 32 wt% Al.

  9. H/sub 2/S-removal processes for low-Btu coal gas

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, M. S.

    1979-01-01

    Process descriptions are provided for seven methods of removing H/sub 2/S from a low-Btu coal-derived gas. The processes include MDEA, Benfield, Selexol, Sulfinol, Stretford, MERC Iron Oxide, and Molecular Sieve. Each of these processes was selected as representing a particular category of gas treating (e.g., physical solvent systems). The open literature contains over 50 processes for H/sub 2/S removal, of which 35 were briefly characterized in the literature survey. Using a technical evaluation of these 35 processes, 21 were eliminated as unsuitable for the required application. The remaining 14 processes represent six categories of gas treating. A seventh category, low-temperature solid sorption, was subsequently added. The processes were qualitatively compared within their respective categories to select a representative process in each of the seven categories.

  10. Low and non-waste process technology - Production of high-calorific fuel gas from waste oil using electric arc cracking

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Joon Hyung; Kim, In Tae; Kim, Jeong Guk; Kim, Hwan Young; Cho, Kwang Hoon; Park, Hyun Soo [Korea Atomic Energy Research Institute, Taejon, (Korea)

    1999-04-01

    The generation amount of waste lubricating oil is the increasing trend. Environmental contamination is caused by an improper treatment of the waste oil or use of recycled fuel oil. Production of clean and high-calorific fuel gas from waste lubricating oil by electric arc cracking can protect the globe from contamination and save money as well. In this year, a laboratory-scale waste oil cracking process using direct discharge method was manufactured. Performance tests had been done under the various experimental conditions such as change of electrode specifications (material, shape, and dimension), amount of applied current, and discharge time. Characteristics of product gas (amount of production, constituents and composition), consumption of electrode and electric power were analyzed. The state-of-the-art on the electric arc cracking technology, experiences acquired through the design and manufacture of lab-scale arc cracking process, and experimental data were used to develop arc cracking technology and to manufacture the small-scale electric arc cracking process. 18 refs., 23 figs., 20 tabs. (Author)

  11. Steam gasification of coal, project prototype plant nuclear process heat: Report at the end of the reference phase

    Science.gov (United States)

    Vanheek, K. H.

    1982-05-01

    The work carried out in the field of steam gasification of coal is described. On the basis of the status achieved to date, it can be stated that the mode of operation of the gas generator developed, including the direct feeding of caking high volatile coal, is technically feasible. Moreover, throughput can be improved by 65% at minimum by using catalysts. On the whole, industrial application of steam gasification, using nuclear process heat, stays attractive compared with other gasification processes. Not only coal is conserved, but also the costs of the gas manufactured are favorable. As confirmed by recent economic calculations, these are 20 to 25% lower.

  12. Thomson scattering diagnostics of decay processes of Ar/SF6 gas-blast arcs confined by a nozzle

    International Nuclear Information System (INIS)

    Because of its instability, it is difficult to measure precisely the electron density (ne) of a long-gap decaying arc discharge in a circuit breaker. However, it is well known that it is an essential parameter for the determination of success or failure of the current interruption in a circuit breaker. In this paper, the spatiotemporal evolutions of the electron density were successfully measured in decaying SF6 gas-blast arc discharges formed with a long gap (50 mm) in a confined nozzle using laser Thomson scattering. Pure Ar gas and an 80%Ar/20%SF6 mixture gas were used as the arc quenching media at atmospheric pressure. After reducing the current to zero, both the measured ne and arc radius in the Ar/SF6 gas arc clearly decayed more rapidly than in the pure Ar gas arc. (fast track communication)

  13. Microstructural control of Cr-Si-N films by a hybrid arc ion plating and magnetron sputtering process

    International Nuclear Information System (INIS)

    The microstructural evolution of Cr-Si-N films deposited by a hybrid arc ion plating and magnetron sputtering process was investigated by varying the sputtering power of Si target and substrate bias voltage. Detailed nanocomposite microstructures of the films were studied by high-resolution transmission electron microscopy. The results indicated that the incorporation of Si into the growing CrN films at 0 V led to the formation of a nanocomposite containing CrN nanocolumns embedded in amorphous SiNx matrix or near-amorphous microstructure. For the films having a Si content of ∼10 at.% and ∼15 at.%, a negative bias voltage of -50 V resulted in the aggregation of nanocolumns in the amorphous matrix. Further increase of negative bias voltage to -250 V led to the formation of a three-dimensional CrN/a-SiNx nanocomposite microstructure. The mechanism of microstructure evolution is discussed by considering the thermodynamic and kinetic factors.

  14. Bioactivity of CaO-MgO-SiO2 glass ceramics synthesized using transferred arc plasma (TAP) process

    International Nuclear Information System (INIS)

    Glass ceramic with a nominal composition of 35.6% CaO, 12.8% MgO and 51.6% SiO2 was prepared by transferred arc plasma processing. The in vitro bioactivity of the plasma synthesized CaO-MgO-SiO2 glass ceramic was examined for its biomedical applicability which was evaluated by immersion in simulated body fluid at 36.5 deg. C for several days. The apatite particles were found to be formed on the surface of the glass ceramic and grew with the passage of soaking time. The simulated body fluid test results showed the formation of carbonated hydroxyapatite like layer on the surface of the glass ceramic. The cytocompatibility was evaluated through human fibroblast proliferation. The fibroblasts adhere, spread, and proliferate on the CaO-MgO-SiO2 glass ceramic, and the cell proliferation was more obvious.

  15. Effect of Included Angle in V-Groove Butt Joints on Shrinkages in Submerged Arc Welding Process

    Directory of Open Access Journals (Sweden)

    N. LAKSHMANA SWAMY

    2012-04-01

    Full Text Available The problems of distortion, residual stresses and reduced strength of structure in and around a welded joint are of major concern in the shipbuilding industry and in other similar manufacturing industries. The predictions of the degree of shrinkages in ship panels due to welding are of great importance from the point of view of dimensional control and it is important to analyze transverse and longitudinal shrinkage. This paper deals with the experimental analysis of transverse and longitudinal shrinkage in single and double V-groove butt joints in submerged arc welding by varying included angle and keeping process parameters constant. It is found that, the maximum shrinkage was at the centre of the plate and minimum at the ends. It is also found that, the transverse and longitudinal shrinkage increase with increase in the included angle. There is a significant increase in the transverse shrinkage and small variation in longitudinal shrinkage.

  16. Application of the Granuflow Process to Pipeline-Transported Coal Slurry CRADA PC96-010, Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Richard P. Killmeyer; Wu-Wey Wen

    1997-09-24

    In light of the current difficulties in processing fine coal and the potential for a significant increase in fines due to more demanding quality specifications, the U.S. Department of Energy's Federal Energy Technology Center (FETC) has been involved in the reconstitution of the fine clean coal resulting from advanced fine coal cleaning technologies. FETC has invented and developed a new strategy that combines fine-coal dewatering and reconstitution into one step. The process reduces the moisture content of the clean coal, and alleviates handling problems related to dustiness, stickiness, flowability, and freezing. This process has been named the GranuFlow Process. Early work successfully demonstrated the feasibility of the process for laboratory-scale vacuum filtration dewatering using asphalt emulsion. Further tests focused on the application of the process to a screen-bowl centrifuge via batch mode tests at 300 lb/hr. These tests produced roughly the same results as the laboratory filtration tests did, and they included some testing using Orimulsion, a bitumen emulsion. The Orimulsion seemed to offer greater potential for moisture reduction and was less affected by colder slurry temperatures. Most recently, FETC has conducted several series of tests in its Coal Preparation Process Research Facility. These tests dramatically showed the visible difference in the dewatered product by applying the GranuFlow Process, turning it from a clumpy, wet, sticky material into a granular, dry free-flowing product. In addition, it verified previous results with improvements in moisture content, dustiness, stickiness, and freezing. Orimulsion showed a significant benefit over asphalt emulsion in moisture reduction at additions more than 5%. The overall goal of this project was to successfully apply FETC'S GranuFlow Process to improve coal slurry pipeline operations. Williams Technologies, Inc. (WTI), a leader in pipeline technology, has an interest in reducing the

  17. EDS coal liquefaction process development: Phase V. Final technical progress report, Volume I

    Energy Technology Data Exchange (ETDEWEB)

    None

    1984-02-01

    All objectives in the EDS Cooperative Agreement for Phases III-B through V have been achieved for the RCLU pilot plants. EDS operations have been successfully demonstrated in both the once-through and bottoms recycle modes for coals of rank ranging from bituminous to lignitic. An extensive data base detailing the effects of process variable changes on yields, conversions and product qualities for each coal has been established. Continuous bottoms recycle operations demonstrated increased overall conversion and improved product slate flexibility over once-through operations. The hydrodynamics of the liquefaction reactor in RCLU were characterized through tests using radioactive tracers in the gas and slurry phases. RCLU was shown to have longer liquid residence times than ECLP. Support work during ECLP operations contributed to resolving differences between ECLP conversions and product yields and those of the small pilot plants. Solvent hydrogenation studies during Phases IIIB-V of the EDS program focused on long term activity maintenance of the Ni-MO-10 catalyst. Process variable studies for solvents from various coals (bituminous, subbituminous, and lignitic), catalyst screening evaluations, and support of ECLP solvent hydrogenation operations. Product quality studies indicate that highly cyclic EDS naphthas represent unique and outstanding catalytic reforming feedstocks. High volumes of high octane motor gasoline blendstock are produced while liberating a considerable quantity of high purity hydrogen.

  18. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-04-13

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. A process has been developed which results in high quality binder pitch suitable for use in graphite electrodes or carbon anodes. A detailed description of the protocol is given by Clendenin. Briefly, aromatic heavy oils are hydro-treated under mild conditions in order to increase their ability to dissolve coal. An example of an aromatic heavy oil is Koppers Carbon Black Base (CBB) oil. CBB oil has been found to be an effective solvent and acceptably low cost (i.e., significantly below the market price for binder pitch, or about $280 per ton at the time of this writing). It is also possible to use solvents derived from hydrotreated coal and avoid reliance on coke oven recovery products completely if so desired.

  19. Hydrometallurgical-UV process to produce ferrous sulfate from the pyrite present in coal tailings

    International Nuclear Information System (INIS)

    The oxidation of pyrite can promote acid mine drainage (AMD). This study developed a hydrometallurgical-UV route for the production of ferrous sulfate. The laboratory study was conducted using a pyrite concentrate obtained from a processed coal tailing. Leaching of the tailing was performed in packed bed columns in an oxidizing environment with an aqueous medium. Recirculation of the liquor produced an Fe3+ iron rich extract. Ultraviolet irradiation was then used to convert the Fe3+ to Fe2+. Heat provided by the UV lamps caused the ferrous sulfate to crystallize. X-ray diffraction (XRD) studies of the crystals demonstrated that it is possible to produce commercial-grade ferrous sulfate heptahydrate crystals from the pyrite present in coal tailings. The crystals are used to treat anemia in humans and animals, and are also used as reagents for waste and waste water treatment. 7 refs., 2 tabs., 2 figs.

  20. Clean-up and processing of coal-derived gas for hydrogen applications

    Science.gov (United States)

    Kasper, S.

    It appears that only a few large-scale industrial applications need to be examined for utilization of coal-derived hydrogen. Applications selected as representative for considerations of purification are related to ammonia, methanol, iron ore reduction, fuel cells, and pipeline gas. Purity requirements and raw gas composition are discussed, and a description of purification processes is provided. Attention is given to particulates, tar, ammonia and water, light oils, bulk acid gas removal, trace sulfur removal, carbon monoxide, hydrogen cyanide, cryogenic purification, and molecular sieves. In view of the very high purity requirements for many hydrogen applications, and the variety of undesirable components in the raw coal gas, the purification task may seem to be too formidable. However, the utilization of hydrogen gas for the production of methanol and ammonia in many countries proves that such a purification is economically feasible.

  1. State of the art of biological processes for coal gasification wastewater treatment.

    Science.gov (United States)

    Zhao, Qian; Liu, Yu

    2016-01-01

    The treatment of coal gasification wastewater (CGW) poses a serious challenge on the sustainable development of the global coal industry. The CGW contains a broad spectrum of high-strength recalcitrant substances, including phenolic, monocyclic and polycyclic aromatic hydrocarbons, heterocyclic nitrogenous compounds and long chain aliphatic hydrocarbon. So far, biological treatment of CGW has been considered as an environment-friendly and cost-effective method compared to physiochemical approaches. Thus, this reviews aims to provide a comprehensive picture of state of the art of biological processes for treating CGW wastewater, while the possible biodegradation mechanisms of toxic and refractory organic substances were also elaborated together with microbial community involved. Discussion was further extended to advanced bioprocesses to tackle high-concentration ammonia and possible options towards in-plant zero liquid discharge. PMID:27364381

  2. Research of the Institute of Chemical Processing of Coal on hot briquetting

    Energy Technology Data Exchange (ETDEWEB)

    Malczyk, R.; Rychly, J.; Sekula, M.; Zakrzewski, Z. (Instytut Chemicznej Przerobki Wegla, Zabrze (Poland))

    1992-04-01

    Reviews research work carried out for the past 40 years by the Institute of Chemical Processing of Coal in Zabrze, Poland in the field of coal briquetting. The first task faced by the Institute in the mid 1950s was briquetting of semicoke. General briquetting parameters for semicoke are discussed. The history and achievements of the Institute's research and development from the early 60s up to today is outlined. In addition to economic aspects, environmental problems became more and more the focus of study. Production of smokeless fuel is the subject of recent studies. Future activities to be performed in this field and perspectives for their implementation in industry are pointed out. 26 refs.

  3. STUDY ON THE PRESSURE IN PLASMA ARC

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The axial pressure in plasma arc is measured under different conditions. The effects of the parameters, such as welding current, plasma gas flow rate, electrode setback and arc length, on the pressure in plasma arc are investigated and quantitative analyzed to explain the relationship between the quality of weld and the matching of parameters in plasma arc welding process.

  4. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-06-08

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

  5. Dynamic process simulation as an engineering tool. A case of analysing a coal plant evaporator

    Energy Technology Data Exchange (ETDEWEB)

    Lappalainen, Jari; Juslin, Kaj [VTT Technical Research Centre of Finland, Espoo (Finland); Blom, Harri [Fortum Power and Heat Oy, Naantali (Finland)

    2012-07-01

    Methods relying on mathematical models, such as simulation and optimisation, have been adopted in process industry and routinely used in various engineering tasks. This paper discusses the current status of simulation, especially dynamic simulation (DS), in engineering projects, which provides means to study process behaviour in both normal operation and during incidents. A case example of solving an engineering problem with DS at the power plant is presented. A model of a once-through evaporator of a coal-fired power plant was developed, and used to analyse thermal behaviour of the evaporator pipes. (orig.)

  6. Toxicologic studies of emissions from coal gasification process. I. Subchronic feeding studies.

    Science.gov (United States)

    Kostial, K; Kello, D; Blanusa, M; Maljković, T; Rabar, I; Bunarević, A; Stara, J F

    1980-09-01

    The increasing use of new sources of energy may result in additional contamination of the human environment with inorganic and organic pollutants which are not yet adequately investigated with regard to their potential impact on human health. However, some evidence exists that several trace inorganic and organic contaminants found in coal processing residues may constitute potential health problems. Therefore, the comparative biological hazards of solid wastes and effluents from a Lurgi coal gasification plant were initially evaluated using acute and chronic feeding experiments in male and female rats. In the subchronic experiment, six-week old animals were fed diets wih various levels of ash (slag) additive (0.5%, 1%, and 5%) for period of 16 weeks. Following exposure, blood samples were taken and 22-hour urine samples were collected. Livers and kidneys, and testicles in males, were taken for trace element analysis or histologic examination. The urinary values, erythrocyte and leucocyte count, hemoglobin, packed cell volume, and concentration of trace elements in exposed animals were determined. The addition of ash (slag) to the diet in concentrations much higher than expected in conditions of environmental contamination had no measurable health effects. Although these initial results obtained in relatively short-term experiments cannot be directly extrapolated to human health effects, particularly not for carcinogenic assessment, there is an indication that exposure to solid wastes from the coal gasification plant may not be toxic. PMID:7462912

  7. The Process of Separating Bovine Serum Albumin Using Hydroxyapatite and Active Babassu Coal (Orbignya martiana

    Directory of Open Access Journals (Sweden)

    Márcia Regina Ribeiro Alves

    2016-01-01

    Full Text Available Bovine serum albumin is one of the major serum proteins; it plays an important role as a result of its functional and nutritional properties which have bioactive peptides. Adsorption method was used to separate protein, which involves hydroxyapatite, synthetic hydroxyapatite, and active babassu coal. Initially, characterization was carried out using the zeta potential of the adsorbents. Kinetic pseudo-first- and pseudo-second-order models were applied. For isotherms, equilibrium data studies were carried out using the Langmuir and Freundlich models, in addition to determining the efficiency of adsorptive process. The results of the zeta potential showed loads ranging from +6.9 to −42.8 mV. The kinetic data were better represented in the pseudo-second-order model with chemisorption characteristics. The adsorption capacity of the adsorbents decreased as pH increased, indicating that the electrostatic bonds and some functional groups of active babassu coal contributed to the reduction of adsorption, especially oxygen linked to carbon atoms. The value of pH 4.0 showed the best results of adsorption, being obtained as the maximum adsorption capacity (qm and yield (% (where qm=87.95 mg g−1 and 74.2%; 68.26 mg g−1 and 68.6%; and 36.18 mg g−1, 37.4% of hydroxyapatite, synthetic hydroxyapatite, and active babassu coal, respectively.

  8. The Release of Trace Elements in the Process of Coal Coking

    Directory of Open Access Journals (Sweden)

    Jan Konieczyński

    2012-01-01

    Full Text Available In order to assess the penetration of individual trace elements into the air through their release in the coal coking process, it is necessary to determine the loss of these elements by comparing their contents in the charge coal and in coke obtained. The present research covered four coke oven batteries differing in age, technology, and technical equipment. By using mercury analyzer MA-2 and the method of ICP MS As, Be, Cd, Co, Hg, Mn, Ni, Se, Sr, Tl, V, and Zn were determined in samples of charge coal and yielded coke. Basing on the analyses results, the release coefficients of selected elements were determined. Their values ranged from 0.5 to 94%. High volatility of cadmium, mercury, and thallium was confirmed. The tests have shown that although the results refer to the selected case studies, it may be concluded that the air purity is affected by controlled emission occurring when coke oven batteries are fired by crude coke oven gas. Fugitive emission of the trace elements investigated, occurring due to coke oven leaks and openings, is small and, is not a real threat to the environment except mercury.

  9. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-01

    A set of statistically designed experiments was used to study the effects of several important operating variables on coal liquefaction product yield structures. These studies used a Continuous Stirred-Tank Reactor to provide a hydrodynamically well-defined system from which kinetic data could be extracted. An analysis of the data shows that product yield structures can be adequately represented by a correlative model. It was shown that second-order effects (interaction and squared terms) are necessary to provide a good model fit of the data throughout the range studied. Three reports were issued covering the SRC-II database and yields as functions of operating variables. The results agree well with the generally-held concepts of the SRC reaction process, i.e., liquid phase hydrogenolysis of liquid coal which is time-dependent, thermally activated, catalyzed by recycle ash, and reaction rate-controlled. Four reports were issued summarizing the comprehensive SRC reactor thermal response models and reporting the results of several studies made with the models. Analytical equipment for measuring SRC off-gas composition and simulated distillation of coal liquids and appropriate procedures have been established.

  10. Comparative study on the impact of coal and uranium mining, processing, and transportation in the western United States

    International Nuclear Information System (INIS)

    A comparative study and quantitative assessment of the impacts, costs and benefits associated with the mining, processing and transportation of coal and uranium within the western states, specifically Arizona, California, Colorado, Montana, New Mexico, Oregon, Utah, Washington and Wyoming are presented. The western states possess 49% of the US reserve coal base, 67% of the total identified reserves and 82% of the hypothetical reserves. Western coal production has increased at an average annual rate of about 22% since 1970 and should become the major US coal supplier in the 1980's. The Colorado Plateau (in Arizona, Colorado, New Mexico and Utah) and the Wyoming Basin areas account for 72% of the $15/lb U3O8 resources, 76% of the $30/lb, and 75% of the $50/lb resources. It is apparent that the West will serve as the major supplier of domestic US coal and uranium fuels for at least the next several decades. Impacts considered are: environmental impacts, (land, water, air quality); health effects of coal and uranium mining, processing, and transportation; risks from transportation accidents; radiological impact of coal and uranium mining; social and economic impacts; and aesthetic impacts (land, air, noise, water, biota, and man-made objects). Economic benefits are discussed

  11. Comparative study on the impact of coal and uranium mining, processing, and transportation in the western United States

    Energy Technology Data Exchange (ETDEWEB)

    Sandquist, G.M.

    1979-06-01

    A comparative study and quantitative assessment of the impacts, costs and benefits associated with the mining, processing and transportation of coal and uranium within the western states, specifically Arizona, California, Colorado, Montana, New Mexico, Oregon, Utah, Washington and Wyoming are presented. The western states possess 49% of the US reserve coal base, 67% of the total identified reserves and 82% of the hypothetical reserves. Western coal production has increased at an average annual rate of about 22% since 1970 and should become the major US coal supplier in the 1980's. The Colorado Plateau (in Arizona, Colorado, New Mexico and Utah) and the Wyoming Basin areas account for 72% of the $15/lb U/sub 3/O/sub 8/ resources, 76% of the $30/lb, and 75% of the $50/lb resources. It is apparent that the West will serve as the major supplier of domestic US coal and uranium fuels for at least the next several decades. Impacts considered are: environmental impacts, (land, water, air quality); health effects of coal and uranium mining, processing, and transportation; risks from transportation accidents; radiological impact of coal and uranium mining; social and economic impacts; and aesthetic impacts (land, air, noise, water, biota, and man-made objects). Economic benefits are discussed.

  12. Evaluation of Structural Changes in the Coal Specimen Heating Process and UCG Model Experiments for Developing Efficient UCG Systems

    Directory of Open Access Journals (Sweden)

    Gota Deguchi

    2013-05-01

    Full Text Available In the underground coal gasification (UCG process, cavity growth with crack extension inside the coal seam is an important phenomenon that directly influences gasification efficiency. An efficient and environmentally friendly UCG system also relies upon the precise control and evaluation of the gasification zone. This paper presents details of laboratory studies undertaken to evaluate structural changes that occur inside the coal under thermal stress and to evaluate underground coal-oxygen gasification simulated in an ex-situ reactor. The effects of feed temperature, the direction of the stratified plane, and the inherent microcracks on the coal fracture and crack extension were investigated using some heating experiments performed using plate-shaped and cylindrical coal specimens. To monitor the failure process and to measure the microcrack distribution inside the coal specimen before and after heating, acoustic emission (AE analysis and X-ray CT were applied. We also introduce a laboratory-scale UCG model experiment conducted with set design and operating parameters. The temperature profiles, AE activities, product gas concentration as well as the gasifier weight lossess were measured successively during gasification. The product gas mainly comprised combustible components such as CO, CH4, and H2 (27.5, 5.5, and 17.2 vol% respectively, which produced a high average calorific value (9.1 MJ/m3.

  13. Diagnostics of plasma arc during the process of remelting of surface layer in 40Cr4 steel

    Directory of Open Access Journals (Sweden)

    Z. Nitkiewicz

    2007-06-01

    Full Text Available Purpose: The purpose of this work is to propose a research method for diagnostics and determination of temperature and shape of plasma arc used for surface treatment of 40Cr4 steel with TiO2 coating.Design/methodology/approach: The surfaces of samples, previously coated with ceramic coating, have been remelted with plasma arc. For investigations of arc shape the high-resolution modern visible light camera and thermovision camera have been used.Findings: The temperature distribution in plasma arc with percentage quantity of temperature fields has been determined. The arc limiting profiles with isotherms have also been determined.Research limitations/implications: Further research is aimed to assign the identified spatial points of the arc with the appropriate values of temperature.Practical implications: Selection of remelting parameters is performed by trial and error method, which is time-consuming and expensive. In-depth recognition of parameters, which characterise the source, will be useful in creation of the method of fast prognosis of parameters for the used source with the effects of remelting.Originality/value: The diagnostics of plasma arc which consists in estimation of the temperature and the shape of the arc by means of high-resolution visible light camera and the thermovision camera.

  14. Quantitative carbon analysis in coal by combining data processing and spatial confinement in laser-induced breakdown spectroscopy

    International Nuclear Information System (INIS)

    Online measurement of carbon content of coal is important for coal-fired power plants to realize the combustion optimization of coal-fired boilers. Given that the measurement of carbon content of coal using laser-induced breakdown spectroscopy (LIBS) suffers from low measurement accuracy because of matrix effects, our previous study has proposed a combination model to improve the measurement accuracy of carbon content of coal. The spatial confinement method, which utilizes the spectral emissions of laser-induced plasmas spatially confined by cavities for quantitative analysis, has potential to improve quantitative analysis performance. In the present study, the combination model was used for coal measurement with cylindrical cavity confinement to further improve the measurement accuracy of carbon content of coal. Results showed that measurement accuracy was improved when the combination model was used with spatial confinement method. The coefficient of determination, root-mean-square error of prediction, average relative error, and average absolute error for the combination model with cylindrical cavity confinement were 0.99, 1.35%, 1.66%, and 1.08%, respectively, whereas values for the combination model without cylindrical cavity confinement were 0.99, 1.63%, 1.82%, and 1.27%, respectively. This is the first time that the average absolute error of carbon measurement for coal analysis has achieved close to 1.0% using LIBS, which is the critical requirement set for traditional chemical processing method by Chinese national standard. These results indicated that LIBS had significant application potential for coal analysis. - Highlights: • Spatial confinement method is applied for the measurement of carbon content in coal. • Previously proposed combination model is used with spatial confinement method. • The final result is firstly close to the critical reproducibility requirement of Chinese national standard

  15. Chemical kinetics and transport processes in supercritical fluid extraction of coal. Final report, August 10, 1990--December 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, B.J.; Smith, J.M.; Wang, M.; Zhang, C.J.

    1993-02-01

    The overall objective of this project was to study the supercritical fluid extraction of hydrocarbons from coal. Beyond the practical concern of deriving products from coal, the research has provided insights into the structure, properties, and reactivities of coal. Information on engineering fundamentals of coal thermolysis and extraction, including physical and chemical processes, is presented in this final report. To accomplish the goals of the project we developed continuous-flow experiments for fixed-bed samples of coal that allow two types of analysis of the extract: continuous spectrophotometric absorbance measurements of the lumped concentration of extract, and chromatographic determinations of molecular-weight distributions as a function of time. Thermolysis of coal yields a complex mixture of many extract products whose molecular-weight distribution (MWD) varies with time for continuous-flow, semibatch experiments. The flow reactor with a differential, fixed bed of coal particles contacted by supercritical t-butanol was employed to provide dynamic MWD data by means of HPLC gel permeation chromatography of the extract. The experimental results, time-dependent MWDs of extract molecules, were interpreted by a novel mathematical model based on continuous-mixture kinetics for thermal cleavage of chemical bonds in the coal network. The parameters for the MWDs of extractable groups in the coal and the rate constants for one- and two-fragment reaction are determined from the experimental data. The significant effect of temperature on the kinetics of the extraction was explained in terms of one- and two-fragment reactions in the coal.

  16. A CUSP CATASTROPHE, PRECURSORS PATTERN ANDEVOLUTION PROCESS OF ROCKBUST OF COAL PILLARUNDER A HARD ROCK SUBJECT TO ELASTIC SUPPORT

    Institute of Scientific and Technical Information of China (English)

    徐曾和; 徐小荷

    1996-01-01

    The rockburst of the coal pillar under a thick hard roof stratum is modelled as the instability failure problem of coal pillars under strata subject to elastic support. The instability mechanism of rockburst is studied by applying cusp catastrophic theory. The effects of the stiffness ratio of the system and loads imposed on the system on the rockburst are explicated.The factors affecting rockbursts are discussed. Based on them, the "evolution process, the forewarning regularity and forewarning sings of rockbursts are studied. It is indicated that the subsidence velocity of roof stratum, which increases quickly and tends to infinity, is the forewarning measurable signs of the rockbursts of coal pillar.

  17. Combined coal gasification and Fe{sub 3}O{sub 4}-reduction using high-temperature solar process heat

    Energy Technology Data Exchange (ETDEWEB)

    Tamaura, Y. [Tokyo Inst. of Technology, Tokyo (Japan); Ehrensberger, K.; Steinfeld, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The coal/Fe{sub 3}O{sub 4} system was experimentally studied at PSI solar furnace. The reactants were directly exposed to a solar flux irradiation of 3,000 suns (1 sun = 1 kW/m{sup 2}). The combined gasification of coal and reduction of Fe{sub 2}O{sub 3} proceeded rapidly after only one second exposure, suggesting an efficient heat transfer and chemical conversion by direct solar energy absorption at the reaction site. The proposed solar thermochemical process offers the possibility of converting coal to a cleaner fluid fuel with a solar-upgraded calorific value. (author) 2 figs., 8 refs.

  18. Coal conversion systems design and process modeling. Volume 1: Application of MPPR and Aspen computer models

    Science.gov (United States)

    1981-01-01

    The development of a coal gasification system design and mass and energy balance simulation program for the TVA and other similar facilities is described. The materials-process-product model (MPPM) and the advanced system for process engineering (ASPEN) computer program were selected from available steady state and dynamic models. The MPPM was selected to serve as the basis for development of system level design model structure because it provided the capability for process block material and energy balance and high-level systems sizing and costing. The ASPEN simulation serves as the basis for assessing detailed component models for the system design modeling program. The ASPEN components were analyzed to identify particular process blocks and data packages (physical properties) which could be extracted and used in the system design modeling program. While ASPEN physical properties calculation routines are capable of generating physical properties required for process simulation, not all required physical property data are available, and must be user-entered.

  19. Solvent Refined Coal (SRC) process. Research and development report No. 53, interim report No. 29, August-November, 1978. Volume VI. Process development unit studies. Part 1

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-01-01

    This report presents the results of seven SRC-II runs on Process Development Unit P99 feeding Pittsburgh Seam coal. Four of these runs (Runs 41-44) were made feeding coal from the Robinson Run Mine and three (Runs 45-47) were made feeding a second shipment of coal from the Powhatan No. 5 Mine. This work showed that both these coals are satisfactory feedstocks for the SRC-II process. Increasing dissolver outlet hydrogen partial pressure from approximately 1300 to about 1400 psia did not have a significant effect on yields from Robinson Run coal, but simultaneously increasing coal concentration in the feed slurry from 25 to 30 wt% and decreasing the percent recycle solids from 21% to 17% lowered distillate yields. With the Powhatan coal, a modest increase in the boiling temperature (approximately 35/sup 0/F) at the 10% point) of the process solvent had essentially no effect on product yields, while lowering the average dissolver temperature from 851/sup 0/F to 842/sup 0/F reduced gas yield.

  20. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  1. The whole process confirmation management and its application in coal mine safe production

    Institute of Scientific and Technical Information of China (English)

    YAO Hai-fei

    2012-01-01

    After analyzing the reasons for coal mine accidents and the current management methods,effective actions for the implementation of safety management were put forward by carrying out the whole process confirmation management.The basic content and the five implementation steps were described,and the implementation method and the program of every step were introduced.Some rules for the implementation of the whole process confirmation management in coal mine safety production were explained,such as during the process of preproduction,before descent,descent,after descent,walking in the roadway,post-operation,shift,and hoisting after work.The results show that the guardians and the executors should both confirm the implementation,which can improve the workers' attention and self-awareness to avoid errors in detail and reduce the "three violations" phenomenon.To ensure the effect of the whole process confirmation management,relevant departments should designate a person-in-charge in the specific work in all stages,make a work plan,and strengthen the internal evaluation.

  2. An environmentally-friendly vacuum reduction metallurgical process to recover germanium from coal fly ash.

    Science.gov (United States)

    Zhang, Lingen; Xu, Zhenming

    2016-07-15

    The demand for germanium in the field of semiconductor, electronics, and optical devices is growing rapidly; however, the resources of germanium are scarce worldwide. As a secondary material, coal fly ash could be further recycled to retrieve germanium. Up to now, the conventional processes to recover germanium have two problems as follows: on the one hand, it is difficult to be satisfactory for its economic and environmental effect; on the other hand, the recovery ratio of germanium is not all that could be desired. In this paper, an environmentally-friendly vacuum reduction metallurgical process (VRMP) was proposed to recover germanium from coal fly ash. The results of the laboratory scale experiments indicated that the appropriate parameters were 1173K and 10Pa with 10wt% coke addition for 40min, and recovery ratio germanium was 93.96%. On the basis of above condition, the pilot scale experiments were utilized to assess the actual effect of VRMP for recovery of germanium with parameter of 1473K, 1-10Pa and heating time 40min, the recovery ratio of germanium reached 94.64%. This process considerably enhances germanium recovery, meanwhile, eliminates much of the water usage and residue secondary pollution compared with other conventional processes. PMID:27015376

  3. Hybrid laser-arc welding

    DEFF Research Database (Denmark)

    Hybrid laser-arc welding (HLAW) is a combination of laser welding with arc welding that overcomes many of the shortfalls of both processes. This important book gives a comprehensive account of hybrid laser-arc welding technology and applications. The first part of the book reviews...... the characteristics of the process, including the properties of joints produced by hybrid laser-arc welding and ways of assessing weld quality. Part II discusses applications of the process to such metals as magnesium alloys, aluminium and steel as well as the use of hybrid laser-arc welding in such sectors as ship...... building and the automotive industry. With its distinguished editor and international team of contributors, Hybrid laser-arc welding, will be a valuable source of reference for all those using this important welding technology. Professor Flemming Ove Olsen works in the Department of Manufacturing...

  4. Numerical modeling of a hybrid arc / laser welding process in a level set framework : application to multipass welding of high thickness steel sheets

    OpenAIRE

    Desmaison, Olivier

    2013-01-01

    Hybrid arc / laser welding represents the solution for high thickness steel sheets assembly. The laser heat source added to the MIG torch improves the process productivity while respecting quality standards. Nevertheless, the phenomenology of the process remains complex and not totally understood. This is the thrust for the development of numerical simulation. The present study has been carried out as part of the "SISHYFE" Material and Process ANR project.For that purpose, a new non stationar...

  5. Laser Shock Processing of Surface Copperize on Arc-Meshes Gear

    Institute of Scientific and Technical Information of China (English)

    马德毅; 刘继光; 宋丹路

    2004-01-01

    This paper presents surface modifications of aluminum-alloy induced by laser-shock processing (LSP). In the first part, the basic principles are discussed to provide an overview of the physical processes involved in laser shock processing, and to introduce pressure loadings generated by different laser generators. In the second part, emphases are given to the effects of laser intensity, target material, laser pulse duration and laser wavelength, and uniform and localized modeling of fatigue behavior after LSP. In the third part,experimental results are given to show the laser-induced pure mechanical effects on aluminum-alloy by using LSP.

  6. On the Modeling of Vacuum Arc Remelting Process in Titanium Alloys

    Science.gov (United States)

    Patel, Ashish; Fiore, Daniel

    2016-07-01

    Mathematical modeling is routinely used in the process development and production of advanced aerospace alloys to gain greater insight into the effect of process parameters on final properties. This article describes the application of a 2-D mathematical VAR model presented at previous LMPC meetings. The impact of process parameters on melt pool geometry, solidification behavior, fluid-flow and chemistry in a Ti-6Al-4V ingot is discussed. Model predictions are validated against published data from a industrial size ingot, and results of a parametric study on particle dissolution are also discussed.

  7. Cylindrical particle modelling in pulverized coal and biomass co-firing process

    International Nuclear Information System (INIS)

    Numerical analysis of co-firing pulverized coal and biomass in a vertical cylindrical laboratory furnace is explored. The ratio of coal and biomass in the fuel was 80:20 by mass for all cases. The mathematical model of combustion in the furnace was established by describing physical phenomena such as turbulent flow, heat and mass transfer, devolatilization and combustion. A 3D-model of combustion in a laboratory furnace was created using the CFD software FLUENT. The shape of the biomass particles was estimated as cylindrical and was accounted for in the calculation of particle trajectories via a custom-developed model. Experimental measurements were conducted on a 20 kW laboratory furnace with controllable wall temperature. The temperature varied in the range from 1233 K to 1823 K, depending on the case. Excess air for combustion was set at 10% or 20%, depending on the case. The developed model shows better agreement with the experimental data than the existing models, which estimate particles as spheres. Analysis of the results shows that the influence of the particle size increases with the size of the particle. Also, the geometry of the cylindrical particles strongly influences the beginning and the intensity of the devolatilization process and subsequently the combustion process. - Highlights: • Co-firing of pulverized biomass and coal is modelled using CFD Software Fluent. • Shape of biomass particles is taken into consideration in the model. • Geometry of particles influences the process of devolatilization and combustion. • Influence of the particle shape and size increases with the particle size

  8. The Complex Alarming Event Detecting and Disposal Processing Approach for Coal Mine Safety Using Wireless Sensor Network

    OpenAIRE

    Cheng Bo; Zhou Peng; Zhu Da; Chen Junliang

    2012-01-01

    Due to the complex environment of the coal mine, the accidents can occur at any time and often result in partial or total evacuation of mine personnel and could result in the loss of lives. Therefore, it is important and necessary to detect the accidents and generate a corresponding alarming disposal in time. This paper proposed a real-time complex alarming event detecting and disposal processing approach for coal mine safety using wireless sensor network. Firstly, we introduce the event and ...

  9. Thermodynamic and kinetic processes associated with CO 2-sequestration and CO 2-enhanced coalbed methane production from unminable coal seams

    OpenAIRE

    Busch, Andreas

    2005-01-01

    The present thesis investigates the thermodynamic and kinetic processes associated with gas sorption (CO2, CH4) on coal. It is incorporated into a research field which studies CO2-sequestration in combination with CO2-enhanced coalbed methane production in unminable coal seams. This combination is regarded as a viable and promising option to reduce anthropogenic CO2-emissions. At the moment numerous world-wide research projects investigate the feasibility of this concept under different geolo...

  10. Real time error detection in metal arc welding process using Artificial Neural Netwroks

    OpenAIRE

    Sharma, Prashant; Shaju K. Albert; Rajeswari, S.

    2016-01-01

    Quality assurance in production line demands reliable weld joints. Human made errors is a major cause of faulty production. Promptly Identifying errors in the weld while welding is in progress will decrease the post inspection cost spent on the welding process. Electrical parameters generated during welding, could able to characterize the process efficiently. Parameter values are collected using high speed data acquisition system. Time series analysis tasks such as filtering, pattern recognit...

  11. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-08-11

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.

  12. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no

  13. Alignment mask design and image processing for the Advanced Radiographic Capability (ARC) at the National Ignition Facility

    Science.gov (United States)

    Leach, Richard R.; Awwal, Abdul; Cohen, Simon; Lowe-Webb, Roger; Roberts, Randy; Salmon, Thad; Smauley, David; Wilhelmsen, Karl

    2015-09-01

    The Advance Radiographic Capability (ARC) at the National Ignition Facility (NIF) is a laser system that employs up to four petawatt (PW) lasers to produce a sequence of short pulses that generate X-rays which backlight high-density inertial confinement fusion (ICF) targets. ARC is designed to produce multiple, sequential X-ray images by using up to eight back lighters. The images will be used to examine the compression and ignition of a cryogenic deuterium-tritium target with tens-of-picosecond temporal resolution during the critical phases of an ICF shot. Multi-frame, hard-X-ray radiography of imploding NIF capsules is a capability which is critical to the success of NIF's missions. As in the NIF system, ARC requires an optical alignment mask that can be inserted and removed as needed for precise positioning of the beam. Due to ARC's split beam design, inserting the nominal NIF main laser alignment mask in ARC produced a partial blockage of the mask pattern. Requirements for a new mask design were needed. In this paper we describe the ARC mask requirements, the resulting mask design pattern, and the image analysis algorithms used to detect and identify the beam and reference centers required for ARC alignment.

  14. Improvement in the morphology of micro-arc oxidised titanium surfaces: A new process to increase osteoblast response

    International Nuclear Information System (INIS)

    This study describes a method for combining sandblast-acid etching and micro-arc oxidation to optimise titanium implant surfaces, and examines the effects of these surfaces on osteoblast response. Titanium discs were grouped as: micro-arc oxidised (MAO), sandblast-acid etched and micro-arc oxidised (MAO-SA), micro-arc oxidised and heated (MAO-HT), and untreated smooth surface. The combination of sandblast-acid etching and micro-arc oxidation in the MAO-SA group created an average surface roughness of 2.02 ± 0.15 μm compared to the untreated machined surface of 0.31 ± 0.06 μm. Scanning electron microscopy observations of the surface structures showed that the irregularly ordered valleys created by sandblast-acid etching remained after micro-arc oxidation and that micropores had also formed. These microstructures provided a better place for osteoblasts to spread compared with the other surfaces. In addition, our results indicated that adherent osteoblasts expressed greater alkaline phosphatase (ALP) activity and osteocalcin (OC) production on MAO-SA surfaces compared with MAO, MAO-HT, and smooth surfaces. The overall results clearly indicate that combining sandblast-acid etching and micro-arc oxidation techniques improves the titanium surface morphology and increases the roughness, which provides an optimal surface for cell differentiation and osseointegration.

  15. Improvement in the morphology of micro-arc oxidised titanium surfaces: A new process to increase osteoblast response

    Energy Technology Data Exchange (ETDEWEB)

    Deng Feilong [Guanghua College of Stomatology, Hospital of Stomatology, Sun Yat-sen University, Guangzhou 510080 (China); Zhang Weizhen [Department of Physiology and Pathophysiology, Peking University Health Science Center, Beijing 100083 (China); Department of Surgery, University of Michigan Medical Center, Ann Arbor, MI 48109-0346 (United States); Zhang Peifen; Liu Chenhan [Guanghua College of Stomatology, Hospital of Stomatology, Sun Yat-sen University, Guangzhou 510080 (China); Ling Junqi, E-mail: pre_implant@yahoo.cn [Guanghua College of Stomatology, Hospital of Stomatology, Sun Yat-sen University, Guangzhou 510080 (China)

    2010-01-01

    This study describes a method for combining sandblast-acid etching and micro-arc oxidation to optimise titanium implant surfaces, and examines the effects of these surfaces on osteoblast response. Titanium discs were grouped as: micro-arc oxidised (MAO), sandblast-acid etched and micro-arc oxidised (MAO-SA), micro-arc oxidised and heated (MAO-HT), and untreated smooth surface. The combination of sandblast-acid etching and micro-arc oxidation in the MAO-SA group created an average surface roughness of 2.02 {+-} 0.15 {mu}m compared to the untreated machined surface of 0.31 {+-} 0.06 {mu}m. Scanning electron microscopy observations of the surface structures showed that the irregularly ordered valleys created by sandblast-acid etching remained after micro-arc oxidation and that micropores had also formed. These microstructures provided a better place for osteoblasts to spread compared with the other surfaces. In addition, our results indicated that adherent osteoblasts expressed greater alkaline phosphatase (ALP) activity and osteocalcin (OC) production on MAO-SA surfaces compared with MAO, MAO-HT, and smooth surfaces. The overall results clearly indicate that combining sandblast-acid etching and micro-arc oxidation techniques improves the titanium surface morphology and increases the roughness, which provides an optimal surface for cell differentiation and osseointegration.

  16. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-07-01

    This report describes the Western Research Institute (WRI) COMPCOAL{trademark} process which is designed to produce a stable, high-Btu fuel from Powder River Basin (PRB) and other low-rank coals. The process is designed to overcome the problems of oxidation and spontaneous combustion, readsorption of moisture, and dust formation from the friable coal. PRB coal is susceptible to low-temperature oxidation and self-heating, particularly after it has been dried. This report describes a method WRI has developed to prevent self-heating of dried PRB coal. The ``accelerated aging`` not only stabilizes the dried coal, but it also increases the heating value of the COMPCOAL product. The stabilized COMPCOAL product has a heating value of 12,000 to 12,700 Btu/lb, contains 35 to 40 wt % volatiles, and is comparable to unprocessed PRB coal in self-heating and low-temperature oxidation characteristics. Importantly, the self-heating tendency can be controlled by slightly adjusting the ``aging`` step in the process.

  17. Microstructure and properties of TiN/Ni composite coating prepared by plasma transferred arc scanning process

    Institute of Scientific and Technical Information of China (English)

    WANG Wei; QIAN Shi-qiang; ZHOU Xi-ying

    2009-01-01

    The TiN/Ni composite coatings were deposited on 7005 aluminium alloy by high speed jet electroplating and then processed with plasma transferred arc(PTA) scanning process. The microstructure, microhardness and friction coefficient of PTA scanning treated specimens were investigated. It is shown that the PTA scanning treated specimens have a rapidly solidified microstructure consisting of the uniformly distributed TiN phase and fine Al3Ni2 intermetallic phases. The composite coating has an average microhardness of approximately HV 800. The friction coefficient of PTA scanning treated specimens (oscillated at around 0.25) is considerably lower than that of TiN/Ni composite coating (oscillated at around 0.35). The corrosion behavior of the composite coating in 3.5% NaCl solution at room temperature was also determined using a potentiostat system. In comparison with the corrosion potential φcorr of -0.753 V for 7005 aluminium alloy, the corrosion potentials for TiN/Ti composite coating and PTA scanning treated specimen are increased by 0.148 V and 0.305 V, respectively. The PTA scanning treated specimen has the lowest corrosion current density Jcorr as well as the highest corrosion potential φcorr, showing an improved corrosion resistance compared with 7005 aluminium alloy.

  18. Pilot development of polygeneration process of circulating fluidized bed combustion combined with coal pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Qu, X. [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan (China); Graduate School, Chinese Academy of Sciences, Beijing (China); Liang, P. [College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao (China); Wang, Z. [Ningbo Branch of Academy of Ordnace Science, Ningbo (China); Zhang, R.; Sun, D.; Bi, J. [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan (China); Gong, X. [Hengyuan Coal Electrochemical Co., Ltd, Fugu (China); Gan, Z. [State Key Laboratory of Low Carbon Energy, ENN Science and Technology Ltd, Langfang (China)

    2011-01-15

    A pilot polygeneration process of a 75 t h{sup -1} circulating fluidized bed (CFB) boiler combined with a moving bed coal pyrolyzer was developed based on laboratory-scale experimental results. The process operation showed good consistency and integration between boiler and pyrolyzer. Some critical operating parameters such as hot ash split flow from the CFB boiler to the pyrolyzer, mixing of hot ash and coal particles, control of pyrolysis temperature and solid inventory in the pyrolyzer, and pyrolysis gas clean-up were investigated. Yields of 6.0 wt-% tar and 8.0 wt-% gas with a heating value of about 26 MJ m{sup -3} at 600 C were obtained. Particulate content in tar was restrained less than 4.0 wt-% by using a granular filter of the moving bed. Operation results showed that this pilot polygeneration process was successfully scaled up. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Behaviour of coal associated minerals during coking and blast furnace processes. A review

    Energy Technology Data Exchange (ETDEWEB)

    Gornostayev, Stanislav; Haerkki, Jouko [Lab. of Process Metallurgy, Univ. of Oulu (Finland); Kerkkonen, Olavi [Ruukki Oyj, Raahe (Finland)

    2009-06-15

    Metallurgical coke is made from a mix of several types of coal that contain various minerals, including quartz, carbonates, feldspars, sulphides and a number of phyllosilicates, represented by clay minerals and micas. During coking and coke consumption processes the minerals undergo various physical and chemical changes, which in the case of coke oven batteries include desulphurization, decarbonation, dehydration, dehydroxylation, polymorph transformations, melting with the formation of an alkali and silica-rich liquid, and transformation to another crystalline phase. The typical modifications of mineral phases in a blast furnace (BF) coke are polymorph transformations, melting, and the formation of another crystalline phase. These events are also preceded by notable changes in the shape of crystalline aggregates. All these changes affect the coke properties and the processes occurring in a BF. Mineralogical data can help us to better understand the processes taking place in coke batteries and in a BF, and to improve the quality of a coke by more careful selection of coal blends and setting optimal temperatures for its pre-heating. The degradation of a BF coke by alkalis can be reduced by the addition of certain minerals to the feed coke before charging into the BF. (orig.)

  20. Growth process and corrosion resistance of ceramic coatings of micro-arc oxidation on Mg-Gd-Y magnesium alloys

    Institute of Scientific and Technical Information of China (English)

    王萍; 李建平; 郭永春; 杨忠

    2010-01-01

    The regulation of ceramic coating formed by micro-arc oxidation on Mg-11Gd-1Y-0.5Zn (wt.%) magnesium alloys was investigated by scanning electron microscopy (SEM) and X-ray diffractometer (XRD). The relation of phase structure and corrosion resistance of MgO coating formed by micro-arc oxidation in different growth stages was analyzed. The results showed that the growth of coating accorded with linear regularity in the initial stage of micro-arc oxidation, which was the stage of anodic oxidation controlled ...

  1. Quantitative carbon analysis in coal by combining data processing and spatial confinement in laser-induced breakdown spectroscopy

    Science.gov (United States)

    Li, Xiongwei; Yin, Hualiang; Wang, Zhe; Fu, Yangting; Li, Zheng; Ni, Weidou

    2015-09-01

    Online measurement of carbon content of coal is important for coal-fired power plants to realize the combustion optimization of coal-fired boilers. Given that the measurement of carbon content of coal using laser-induced breakdown spectroscopy (LIBS) suffers from low measurement accuracy because of matrix effects, our previous study has proposed a combination model to improve the measurement accuracy of carbon content of coal. The spatial confinement method, which utilizes the spectral emissions of laser-induced plasmas spatially confined by cavities for quantitative analysis, has potential to improve quantitative analysis performance. In the present study, the combination model was used for coal measurement with cylindrical cavity confinement to further improve the measurement accuracy of carbon content of coal. Results showed that measurement accuracy was improved when the combination model was used with spatial confinement method. The coefficient of determination, root-mean-square error of prediction, average relative error, and average absolute error for the combination model with cylindrical cavity confinement were 0.99, 1.35%, 1.66%, and 1.08%, respectively, whereas values for the combination model without cylindrical cavity confinement were 0.99, 1.63%, 1.82%, and 1.27%, respectively. This is the first time that the average absolute error of carbon measurement for coal analysis has achieved close to 1.0% using LIBS, which is the critical requirement set for traditional chemical processing method by Chinese national standard. These results indicated that LIBS had significant application potential for coal analysis.

  2. Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA

    Science.gov (United States)

    Cravotta, Charles; Keith B.C. Brady

    2015-01-01

    Clean sampling and analysis procedures were used to quantify more than 70 inorganic constituents, including 35 potentially toxic or hazardous constituents, organic carbon, and other characteristics of untreated (influent) and treated (effluent) coal-mine discharges (CMD) at 38 permitted coal-mining or coal-processing facilities in the bituminous coalfield and 4 facilities in the anthracite coalfield of Pennsylvania. Of the 42 facilities sampled during 2011, 26 were surface mines, 11 were underground mines, and 5 were coal refuse disposal operations. Treatment of CMD with caustic soda (NaOH), lime (CaO or Ca(OH)2), flocculent, or limestone was ongoing at 21%, 40%, 6%, and 4% of the facilities, respectively; no chemicals were added at the remaining facilities. All facilities with CMD treatment incorporated structures for active or passive aeration and settling of metal-rich precipitate.

  3. An Experimental Perspective on Lower Crustal Processing of (Arc) Magmas (Invited)

    Science.gov (United States)

    Muntener, O.; Ulmer, P.

    2013-12-01

    A major question in Earth Sciences is how continental crust forms and how it is modified over geological timescales. While there are a multitude of processes that constantly modify the continental crust (recycling), the initial formation of silicic crust is generally related to two hypotheses. One is melting of mafic or pelitic crust while the alternative is fractionation from primary mantle derived melts. These processes may occur simultaneously since the lower crust is energetically the most favorable place for modification processes of crustal rocks. Volatiles and heat play a key role in determining the respective solidi of lower crustal rocks, with the important difference that volatiles available for partial melting processes are restricted to structural bound volatiles in hydrous phases, while crystallization produces a much larger variability of potential magmatic water contents. Here we present an experimental perspective on both melting and crystallization processes in the lower crust, with an emphasis on experimentally derived liquid lines of descent by fractional and equilibrium crystallization at middle to lower crustal levels for hydrous, calc-alkaline magmas. These results indicate that fractionation can explain some features of plutonic-volcanic systems that are commonly ascribed to partial melting. Experimental simulation of fractional crystallization is particularly suited to understand the major controls on phase relations and compositions of magmas in the lower crust. Experimental data at pressures of 0.4 to 1.5 GPa, simulating thin and thick lower continental crustal settings are compiled and will be presented. The temperature ranged from near-liquidus conditions at 1300 - 1150 °C to near-solidus conditions at 700 °C. We investigate the mutual phase relations of the principal phases olivine, cpx, opx, garnet, amphibole, plagioclase and Fe-Ti-oxides. Crystallization experiments at lower crustal conditions demonstrate that liquids at 0.7 to 1

  4. Recycling of electric arc furnace (EAF dust for use in steel making process

    Directory of Open Access Journals (Sweden)

    José Alencastro de Araújo

    2014-07-01

    Full Text Available The EAF dust is listed as hazardous waste from specific source, K061, according to ABNT 10004:2004 and constitutes one of the major problems of electrical steel plant. This work suggests recycling of the EAF dust by sintering of a composite, pre-cast agglomerate (PCA consisting of EAF dust agglomerate to coke particles, mill scale and ceramic fluorite into pellets. The work was divided into three stages, in the first stage the technical viability of using only solid waste industrial to produce a PCA was observed, in the second phase, the main effects between the components of the PCA to obtain the optimal formulation was tested. In the third phase the intensity of the variables, coke and fluorite ceramics, for removing zinc of PCA was checked. Every stage was chemically analyzed by X-ray fluorescence spectrometer and X-ray diffraction. The first two stages of the production PCA were carried out in a pilot plant sintering downstream and the third phase in a pilot plant upstream. As a result of the process two by-products were obtained, the pre-cast agglomerated, PCA, with total iron content exceeding 70%, object of the process of sintering and zinc dust, containing more than 50% zinc resulting from volatilization of this metal during the sintering process and collected by bag filter. In addition, approximately 90% of lead and cadmium contained in the initial EAF dust was extracted.

  5. Process development studies on recovery of clean coal from ultra fine hardcoal tailings using enhanced gravity separator

    Energy Technology Data Exchange (ETDEWEB)

    Ozgen, S.; Turksoy, V.O.; Sabah, E.; Oruc, F. [Afyon Kocatepe Univ., Afyonkarahisar (Turkey). Dept. of Mining Engineering

    2009-10-15

    Gravity-based processing methods were used to process and recover clean coal from ultra-fine hardcoal tailings at a site in Turkey. The coal samples were analyzed using X-ray diffraction and X-ray fluorescence. A hydrocyclone was used to conduct classification tests and to separate the clay minerals from the coal. The effects of various operating parameters were also investigated. Regression analysis was used to characterize the relationship between the ash content and coal recovery rate and the feed solid, inlet pressure, diameter of vortex, and diameter of apex variables of the hydrocyclone. The effects of feed pressure were also investigated. The study showed that coal can be economically recovered from hardcoal tailings containing clay minerals. It was concluded that a coal sample with 6.98 per cent ash content and a net calorific value of 28,778 kJ was obtained with a weight recovery of 61.73 per cent. 25 refs., 8 tabs., 18 figs.

  6. A characterization and evaluation of coal liquefaction process streams. The kinetics of coal liquefaction distillation resid conversion

    Energy Technology Data Exchange (ETDEWEB)

    Klein, M.T.; Calkins, W.H.; Huang, H.; Wang, S.; Campbell, D.

    1998-03-01

    Under subcontract from CONSOL Inc., the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. The program at Delaware was conducted between August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivity toward hydrocracking of coal-derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An introduction and Summary of the project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here.

  7. Research Progress of Micro-arc Oxidation Process for Magnesium Alloy%镁合金微弧氧化研究进展

    Institute of Scientific and Technical Information of China (English)

    赵晓鑫; 马颖; 孙钢

    2013-01-01

    介绍了镁合金微弧氧化直流电源、交流电源、脉冲电源、多种电源的发展现状.同时对酸性、碱性电解液体系以及添加剂对微弧氧化的影响进行了分析.通过几个应用实例阐述了制约镁合金微弧氧化发展的主要因素,对镁合金微弧氧化技术的未来发展方向进行了展望.%The development of micro-arc oxidation process for magnesium alloy with DC power, AC power, pulse power, and the variety of power was described. And the effects of acidic, alkaline electrolyte and additives on micro-arc oxidation was analyzed. By several application examples, the main factors restricting the development of magnesium alloy micro-arc oxidation were describes. And the development direction of micro-arc oxidation process for magnesium alloy was prospected in future.

  8. 太原选煤厂煤泥脱水工艺改造%Transformation of Coal Slime Dehydration Process in Taiyuan Coal Preparation Plant

    Institute of Scientific and Technical Information of China (English)

    刘仙萍

    2014-01-01

    According to the characteristics of production technology of Taiyuan coal preparation plant and the ac-tual situation,reformed the dehydration process of three links of the coarse slime(clean coal),flotation concentrate and tailings slime.Coarse coal slime dewatering adopts advanced coal hydrocyclone and changes the dewatering screen feeding method.Flotation concentrate dewatering reformed the whole process system by swift diaphragm filter press. The tailings slime was grading concentrated by coal slime hydrocyclone before it entered into dewatering screen,im-proved the material concentration of dewatering screen.Through the transformation of coal slime dewatering process, the water content of the final concentrate and tailings slime are greatly reduced,improved the quality of the products, won the market,obtained good economic benefits.%根据太原选煤厂生产工艺的特点和现场的实际情况,对该厂的粗煤泥(精煤)、浮精和尾矿煤泥3个环节的脱水工艺进行了改造。粗煤泥脱水采用先进的煤泥旋流器,同时改变了脱水筛的入料方式;浮精脱水运用快开式隔膜压滤机,进行了整个工艺系统的改造;尾矿煤泥在脱水筛前,用煤泥旋流器进行了预先分级浓缩,提高了脱水筛的入料浓度。通过煤泥脱水环节的改造,使精煤和尾矿煤泥的水分降低,提高了产品质量,赢得了市场,取得了较好的经济效益。

  9. DOE Coal Gasification Multi-Test Facility: fossil fuel processing technical/professional services

    Energy Technology Data Exchange (ETDEWEB)

    Hefferan, J.K.; Lee, G.Y.; Boesch, L.P.; James, R.B.; Rode, R.R.; Walters, A.B.

    1979-07-13

    A conceptual design, including process descriptions, heat and material balances, process flow diagrams, utility requirements, schedule, capital and operating cost estimate, and alternative design considerations, is presented for the DOE Coal Gasification Multi-Test Facility (GMTF). The GMTF, an engineering scale facility, is to provide a complete plant into which different types of gasifiers and conversion/synthesis equipment can be readily integrated for testing in an operational environment at relatively low cost. The design allows for operation of several gasifiers simultaneously at a total coal throughput of 2500 tons/day; individual gasifiers operate at up to 1200 tons/day and 600 psig using air or oxygen. Ten different test gasifiers can be in place at the facility, but only three can be operated at one time. The GMTF can produce a spectrum of saleable products, including low Btu, synthesis and pipeline gases, hydrogen (for fuel cells or hydrogasification), methanol, gasoline, diesel and fuel oils, organic chemicals, and electrical power (potentially). In 1979 dollars, the base facility requires a $288 million capital investment for common-use units, $193 million for four gasification units and four synthesis units, and $305 million for six years of operation. Critical reviews of detailed vendor designs are appended for a methanol synthesis unit, three entrained flow gasifiers, a fluidized bed gasifier, and a hydrogasifier/slag-bath gasifier.

  10. Recovery of reagent in a process for producing ultra clean coal

    Energy Technology Data Exchange (ETDEWEB)

    K.M. Steel; J.W. Patrick [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre

    2003-07-01

    A technique for selectively separating approximately 65 wt% of the Si(IV) in coal has been developed. The technique first uses aqueous HF to react with aluminosilicates and quartz to form fluoride complexed Al and Si species in solution. Aluminium cations, in the form of Al(NO{sub 3}){sub 3}, are then added to the solution to complex fluoride as AlF{sub 2}{sup +} and hydrolyse the silicon fluoride species to silicon hydroxide, which precipitates as pure silica gel and is removed by filtration. The solution is then distilled to recover a water stream, a nitric acid stream and a solid residue. The water stream is used to pyrohydrolyse the solid residue at temperatures in excess of 500{sup o}C to liberate HF for recycling. To complete the circuit, the solid remaining after pyrohydrolysis is treated with the nitric acid stream to produce Al(NO{sub 3}){sub 3} for recycling. The application of this work is primarily as part of a process for producing ultra-clean coal. As it is a technique for the selective separation of Al and Si from aluminosilicates, it may have application in other areas of mineral processing. 10 refs., 3 figs., 2 tabs.

  11. Development of Biological Coal Gasification (MicGAS Process). Topical report, July 1991--February 1993

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, K.C.

    1993-06-01

    Laboratory and bench scale reactor research carried out during the report period confirms the feasibility of biomethanation of Texas lignite (TxL) and some other low-rank coals to methane by specifically developed unique anaerobic microbial consortia. The data obtained demonstrates specificity of a particular microbial consortium to a given lignite. Development of a suitable microbial consortium is the key to the success of the process. The Mic-1 consortium was developed to tolerate higher coal loadings of 1 and 5% TxL in comparison to initial loadings of 0.01% and 0.1% TxL. Moreover, the reaction period was reduced from 60 days to 14 to 21 days. The cost of the culture medium for bioconversion was reduced by studying the effect of different growth factors on the biomethanation capability of Mic-1 consortium. Four different bench scale bioreactor configurations, namely Rotating Biological Contactor (RBC), Upflow Fluidized Bed Reactor (UFBR), Trickle Bed Reactor (TBR), and Continuously Stirred Tank Reactor (CSTR) were evaluated for scale up studies. Preliminary results indicated highest biomethanation of TxL by the Mic-1 consortium in the CSTR, and lowest in the trickle bed reactor. However, highest methane production and process efficiency were obtained in the RBC.

  12. New insights into hydrothermal vent processes in the unique shallow-submarine arc-volcano, Kolumbo (Santorini), Greece

    OpenAIRE

    Kilias, Stephanos P.; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Polymenakou, Paraskevi N.; Godelitsas, Athanasios; Argyraki, Ariadne; Carey, Steven; Gamaletsos, Platon; Mertzimekis, Theo J.; Stathopoulou, Eleni; Goettlicher, Joerg; Steininger, Ralph; Betzelou, Konstantina; Livanos, Isidoros; Christakis, Christos

    2013-01-01

    We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires i...

  13. Usage of calculation experiment for coal combustion process optimization with purpose of toxic discharges decrease. Chapter 4

    International Nuclear Information System (INIS)

    In the chapter 4 the results of numerical simulation of dust-coal combustion process before and after radiation treatment on the base of three-dimensional equation of convective heat-mass exchange with taking into account the combustion reactions is presented. Conducted numerical experiments allow to create perfect ways for combustion of solid fuel with high moisture and ashiness to increase of combustion processes efficiency and to give suitable conception for power generation with minimal quantity of harmful substances with taking into consideration preliminary coal processing

  14. Properties of boron and phosphorous incorporated tetrahedral amorphous carbon films grown using filtered cathodic vacuum arc process

    International Nuclear Information System (INIS)

    This paper reports the electrical, mechanical, structural and field emission properties of as grown and also boron and phosphorous incorporated tetrahedral amorphous carbon (ta-C) films, deposited using a filtered cathodic vacuum arc process. The effect of varying boron and phosphorous content (up to 2.0 at.% in to ta-C) on the conductivity (σD), activation energy (ΔE1), hardness, microstructure, emission threshold (Eturn-ON) and emission current density (J) at 12.5 V/μm of ta-C: B and ta-C: P films deposited at a high negative substrate bias of -300 V are reported. It is observed that both boron and phosphorous incorporation leads to a nearly an order increase in σD and corresponding decrease in ΔE1 and a slight increase in hardness as compared to as grown ta-C films. In the case of field assisted electron emission, it is observed that Eturn-ON increases and J decreases. The changes are attributed to the changes in the sp3/sp2 ratio of the films due to boron and phosphorous incorporation. The effect of boron on ta-C is to give a p-type effect whereas the effect of phosphorous gives n-type doping effect.

  15. Oxidation Behavior of In-Flight Molten Aluminum Droplets in the Twin-Wire Electric Arc Thermal Spray Process

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Brian G. Williams

    2005-05-01

    This paper examines the in-flight oxidation of molten aluminum sprayed in air using the twin-wire electric arc (TWEA) thermal spray process. The oxidation reaction of aluminum in air is highly exothermic and is represented by a heat generation term in the energy balance. Aerodynamic shear at the droplet surface enhances the amount of in-flight oxidation by: (1) promoting entrainment and mixing of the surface oxides within the droplet, and (2) causing a continuous heat generation effect that increases droplet temperature over that of a droplet without internal circulation. This continual source of heat input keeps the droplets in a liquid state during flight. A linear rate law based on the Mott-Cabrera theory was used to estimate the growth of the surface oxide layer formed during droplet flight. The calculated oxide volume fraction of an average droplet at impact agrees well with the experimentally determined oxide content for a typical TWEA-sprayed aluminum coating, which ranges from 3.3 to 12.7%. An explanation is provided for the elevated, nearly constant surface temperature (~ 2000 oC) of the droplets during flight to the substrate and shows that the majority of oxide content in the coating is produced during flight, rather than after deposition.

  16. Removal of hexavalent chromium in carbonic acid solution by oxidizing slag discharged from steelmaking process in electric arc furnace

    Science.gov (United States)

    Yokoyama, Seiji; Okazaki, Kohei; Sasano, Junji; Izaki, Masanobu

    2014-02-01

    Hexavalent chromium (Cr(VI)) is well-known to be a strong oxidizer, and is recognized as a carcinogen. Therefore, it is regulated for drinking water, soil, groundwater and sea by the environmental quality standards all over the world. In this study, it was attempted to remove Cr(VI) ion in a carbonic acid solution by the oxidizing slag that was discharged from the normal steelmaking process in an electric arc furnace. After the addition of the slag into the aqueous solution contained Cr(VI) ion, concentrations of Cr(VI) ion and total chromium (Cr(VI) + trivalent chromium (Cr(III)) ions decreased to lower detection limit of them. Therefore, the used slag could reduce Cr(VI) and fix Cr(III) ion on the slag. While Cr(VI) ion existed in the solution, iron did not dissolve from the slag. From the relation between predicted dissolution amount of iron(II) ion and amount of decrease in Cr(VI) ion, the Cr(VI) ion did not react with iron(II) ion dissolved from the slag. Therefore, Cr(VI) ion was removed by the reductive reaction between Cr(VI) ion and the iron(II) oxide (FeO) in the slag. This reaction progressed on the newly appeared surface of iron(II) oxide due to the dissolution of phase composed of calcium etc., which existed around iron(II) oxide grain in the slag.

  17. Chemical analysis and mutational assay of distilled oils from the H-coal direct liquefaction process: a status report

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, B.W.; Later, D.W.; Wright, C.W.; Stewart, D.L.

    1985-01-01

    Samples from the H-Coal process, a catalytic, single-stage, coal liquefaction technology, were chemically characterized and screened for microbial mutagenicity. For these investigations, a blend of light and heavy H-Coal process oils was fractionally distilled into 50/sup 0/F boiling point cuts. The chemical analyses and biological testing results presented in this status report deal primarily with the blended material and the distillate fractions boiling above 650/sup 0/F. Results from the microbial mutagenicity assays indicated that onset of biological activity in the crude materials occurred above 700/sup 0/F. Similar trends have been observed for Solvent Refined Coal (SRC) I, SRC II, Integrated Two-Stage Liquefaction (ITSL) and Exxon EDS process materials. After chemical class fractionation, the primary source of microbial mutagenicity of the crude boiling point cuts was the nitrogen-containing polycyclic aromatic compound (N-PAC) fractions. Amino polycyclic aromatic hydrocarbons (amino-PAH) were present at sufficient concentration levels in the N-PAC fractions to account for the observed mutagenic responses. In general, the chemical composition of the H-Coal materials studied was similar to that of other single-stage liquefaction materials. The degree of alkylation in these materials was determined to be greater than in the SRC and less than in the EDS process distillate cuts. 13 references, 8 figures, 11 tables.

  18. Arc Statistics

    CERN Document Server

    Meneghetti, M; Dahle, H; Limousin, M

    2013-01-01

    The existence of an arc statistics problem was at the center of a strong debate in the last fifteen years. With the aim to clarify if the optical depth for giant gravitational arcs by galaxy clusters in the so called concordance model is compatible with observations, several studies were carried out which helped to significantly improve our knowledge of strong lensing clusters, unveiling their extremely complex internal structure. In particular, the abundance and the frequency of strong lensing events like gravitational arcs turned out to be a potentially very powerful tool to trace the structure formation. However, given the limited size of observational and theoretical data-sets, the power of arc statistics as a cosmological tool has been only minimally exploited so far. On the other hand, the last years were characterized by significant advancements in the field, and several cluster surveys that are ongoing or planned for the near future seem to have the potential to make arc statistics a competitive cosmo...

  19. A new method to estimate heat source parameters in gas metal arc welding simulation process

    International Nuclear Information System (INIS)

    Highlights: •A new method for accurate simulation of heat source parameters was presented. •The partial least-squares regression analysis was recommended in the method. •The welding experiment results verified accuracy of the proposed method. -- Abstract: Heat source parameters were usually recommended by experience in welding simulation process, which induced error in simulation results (e.g. temperature distribution and residual stress). In this paper, a new method was developed to accurately estimate heat source parameters in welding simulation. In order to reduce the simulation complexity, a sensitivity analysis of heat source parameters was carried out. The relationships between heat source parameters and welding pool characteristics (fusion width (W), penetration depth (D) and peak temperature (Tp)) were obtained with both the multiple regression analysis (MRA) and the partial least-squares regression analysis (PLSRA). Different regression models were employed in each regression method. Comparisons of both methods were performed. A welding experiment was carried out to verify the method. The results showed that both the MRA and the PLSRA were feasible and accurate for prediction of heat source parameters in welding simulation. However, the PLSRA was recommended for its advantages of requiring less simulation data

  20. Early maturation processes in coal. Part 1: Pyrolysis mass balances and structural evolution of coalified wood from the Morwell Brown Coal seam

    CERN Document Server

    Salmon, Elodie; Lorant, François; Hatcher, Patrick G; Marquaire, Paul-Marie; 10.1016/j.orggeochem.2009.01.004

    2009-01-01

    In this work, we develop a theoretical approach to evaluate maturation process of kerogen-like material, involving molecular dynamic reactive modeling with a reactive force field to simulate the thermal stress. The Morwell coal has been selected to study the thermal evolution of terrestrial organic matter. To achieve this, a structural model is first constructed based on models from the literature and analytical characterization of our samples by modern 1-and 2-D NMR, FTIR, and elemental analysis. Then, artificial maturation of the Morwell coal is performed at low conversions in order to obtain, quantitative and qualitative, detailed evidences of structural evolution of the kerogen upon maturation. The observed chemical changes are a defunctionalization of the carboxyl, carbonyl and methoxy functional groups coupling with an increase of cross linking in the residual mature kerogen. Gaseous and liquids hydrocarbons, essentially CH4, C4H8 and C14+ liquid hydrocarbons, are generated in low amount, merely by clea...

  1. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, January--March 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. This report describes leach tests and groundwater monitoring.

  2. Modeling Arcs

    CERN Document Server

    Insepov, Zeke; Veitzer, Seth; Mahalingam, Sudhakar

    2011-01-01

    Although vacuum arcs were first identified over 110 years ago, they are not yet well understood. We have since developed a model of breakdown and gradient limits that tries to explain, in a self-consistent way: arc triggering, plasma initiation, plasma evolution, surface damage and gra- dient limits. We use simple PIC codes for modeling plasmas, molecular dynamics for modeling surface breakdown, and surface damage, and mesoscale surface thermodynamics and finite element electrostatic codes for to evaluate surface properties. Since any given experiment seems to have more variables than data points, we have tried to consider a wide variety of arcing (rf structures, e beam welding, laser ablation, etc.) to help constrain the problem, and concentrate on common mechanisms. While the mechanisms can be comparatively simple, modeling can be challenging.

  3. Structure and pozzolanic activity of calcined coal gangue during the process of mechanical activation

    Energy Technology Data Exchange (ETDEWEB)

    Wei Guo; Dongxu Li; Jianhua Chen; Nanru Yang [Yancheng Institute of Technology, Yancheng (China). Department of Material Engineering

    2009-04-15

    On the basis of analyzing coal gangue's chemical and mineral compositions, the structure change of coal gangue during the mechanical activation was investigated by XRD, FTIR, NMR, and the mechanical strength of the cement doped coal gangue with various specific surface area was tested. The experimental results indicate that the lattice structure of metakaolin in coal gangue samples calcined at 700{sup o}C disorganizes gradually and becomes disordered, and the lattice structure of {alpha}-quartz is distorted slightly. The pozzolanic activity of the coal gangue increases obviously with its structural disorganization.

  4. Large pilot plant alternatives for scaleup of the catalytic coal gasification process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, S.J.

    1979-01-01

    This is the final report for US Department of Energy Contract No. EX-76-C-01-2480, Scaleup Requirements of the Exxon Catalyzed Coal Gasification Process. The objective was to develop the information necessary to determine if an existing DOE large pilot plant could be used to obtain the scaleup data necessary to design and construct a Catalytic Coal Gasification (CCG) pioneer plant with acceptable risk. A pioneer plant is a stand-alone facility, whose primary function is to operate as a profitable commercial venture. The pioneer plant would contain all equipment of full commercial size, as defined by the requirements for an optimum-sized commercial plant. However, the pioneer plant could have a single train of equipment in some or all of the plant sections. The three tasks contained in this contract are discussed: study design and cost estimate for a grass-roots large pilot plant; selection of the preferred existing pilot plant; and study design and cost estimate for revamp of the preferred existing pilot plant.

  5. Investigation of environmental and exergetic performance for coal-preparation units in cement production processes

    International Nuclear Information System (INIS)

    The main objectives of the present study are to perform energy and exergy analyses of a coal-preparation unit in a cement plant and investigate the effect of varying dead state (ambient) temperatures on exergy efficiency. This is the first study conducted on a coal-preparation unit located in a cement plant with respect to the perspective of exergy. The consumption of exergy, the potential improvement of the unit and the effects of CO2 emission by the unit are also examined in terms of the chosen type of fuel. Based on the results of the analyses, the mean values of energy and exergy efficiencies of the unit are found to be 74.03% and 21.36%, respectively while the average potential improvement of the unit is calculated as 78.24%. The analyses demonstrate that the exergy destruction ratio affects the CO2 emission rate of the unit. Consequently, the present technique is proposed as a useful tool for purposes of developing energy policies and providing energy conservation measures, especially concerning similar types of industrial processes.

  6. Removal of unburned carbon in fly ash produced in coal combustion process

    International Nuclear Information System (INIS)

    The coal unburned in flying ashes obtained in the processes of coal combustion is the main disadvantage for its use in the industry of the construction. This material normally has a size of particle greater than the mineral material, therefore it is possible to be separated in a considerable percentage, obtaining double benefit: the reusability of unburned like fuel or precursor for the activated charcoal production and the use of the mineral material in the industry of the construction since the organic matter has retired him that disables its use. In this work it is experienced with a sifted technique of separation by for three obtained flying ash samples with different technology (travelling Grill, pneumatic injection and overturning grill), were made grain sized analyses with meshes of a diameter of particle greater to 0,589 mm, the short analyses were made to them next to the retained material in each mesh and the unburned percentage of removal was determined of. The technique was compared with other developing.

  7. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL-FIRED POWER PROCESSES

    Energy Technology Data Exchange (ETDEWEB)

    Leon R. Glicksman; Michael Louge; Hesham F. Younis; Richard Tan; Mathew Hyre; Mark Torpey

    2003-11-24

    This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor an agency thereof, nor any of the their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, A combined-cycle High Performance Power System (HIPPS) capable of overall cycle efficiencies approaching 50% has been proposed and designed by Foster Wheeler Development Corporation (FWDC). A pyrolyzer in the first stage of the HIPPS process converts a coal feedstock into fuel gas and char at an elevated pressure of 1.4 Map. (206 psia) and elevated temperature of 930 C (1700 F). The generated char serves as the feedstock for a Pulverized Coal (PC) boiler operating at atmospheric pressure, and the fuel gas is directly fired in a gas turbine. The hydrodynamic behavior of the pyrolyzer strongly influences the quality of both the fuel gas and the generated char, the energy split between the gas turbine and the steam turbine, and hence the overall efficiency of the system. By utilizing a simplified set of scaling parameters (Glicksman et al.,1993), a 4/7th labscale cold model of the pyrolyzer operating at ambient temperature and pressure was constructed and tested. The scaling parameters matched include solid to gas density ratio, Froude number, length to diameter ratio; dimensionless superficial gas velocity and solid recycle rate, particle sphericity and particle size distribution (PSD).

  8. Coal gasification by indirect heating in a single moving bed reactor: Process development & simulation

    Directory of Open Access Journals (Sweden)

    Junaid Akhlas

    2015-10-01

    Full Text Available In this work, the development and simulation of a new coal gasification process with indirect heat supply is performed. In this way, the need of pure oxygen production as in a conventional gasification process is avoided. The feasibility and energetic self-sufficiency of the proposed processes are addressed. To avoid the need of Air Separation Unit, the heat required by gasification reactions is supplied by the combustion flue gases, and transferred to the reacting mixture through a bayonet heat exchanger installed inside the gasifier. Two alternatives for the flue gas generation have been investigated and compared. The proposed processes are modeled using chemical kinetics validated on experimental gasification data by means of a standard process simulator (Aspen PlusTM, integrated with a spreadsheet for the modeling of a special type of heat exchanger. Simulation results are presented and discussed for proposed integrated process schemes. It is shown that they do not need external energy supply and ensure overall efficiencies comparable to conventional processes while producing syngas with lower content of carbon dioxide.

  9. Application of hybrid coal reburning/SNCR processes for NOx reduction in a coal-fired boiler

    Energy Technology Data Exchange (ETDEWEB)

    Yang, W.J.; Zhou, Z.J.; Zhou, J.H.; Hongkun, L.V.; Liu, J.Z.; Cen, K.F. [Zhejiang University, Hangzhou (China)

    2009-07-01

    Boilers in Beijing Thermal Power Plant of Zhongdian Guohua Co. in China are coal-fired with natural circulation and tangential fired method, and the economical continuous rate is 410 ton per hour of steam. Hybrid coal reburning/SNCR technology was applied and it successfully reduced NOx to about 170 mg/Nm{sup 3} from about 540 mg/Nm{sup 3}, meanwhile ammonia slip was lower than 10 ppm at 450-210 t/h load and the total reduction efficiency was about 70%. Normal fineness pulverized coal from the bin was chosen as the reburning fuel and the nozzles of the upper primary air were retrofitted to be used as the reburning fuel nozzles. The reducing agent of SNCR was an urea solution, and it was injected by the four layer injectors after online dilution. At 410 t/h load, NOx emission was about 300 mg/Nm{sup 3} when the ratio of reburning fuel to the total fuel was 25.9%-33.4%. Controlling the oxygen content of the gas in the reversal chamber to less than 3.4% resulted in not only low NOx emission but also high combustion efficiency. Ammonia slip distribution in the down gas pass was uneven and ammonia slip was higher in the front of the down gas pass than in the rear of the down gas pass. NSR and NOx reduction were proportional to each other and usually resulted in more ammonia slip with reduction in NOx. About 100 mg/Nm{sup 3} NOx emission could be achieved with about 40 ppm NH{sub 3} slip at 300-450 t/h, and ammonia slip from the SNCR reactions could be used as reducing agent of SCR, which was favorable for the future SCR retrofit.

  10. Development of coal petrography applied in technical processes at the Bergbau-Forschung/DMT during the last 50 years

    Energy Technology Data Exchange (ETDEWEB)

    Steller, Monika; Arendt, Paul; Kuehl, Helmut [Deutsche Montan Technologie GmbH ? Mining Service Division?Essen (Germany)

    2006-06-06

    The paper deals with the activities of the Bergbau-Forschung Coal Petrography Laboratory in Essen (Germany), which, under the influence of Marie-Therese Mackowsky, developed into a stronghold of the industrial application of coal petrology. In 1979, the formerly independent Section for Mineralogy and Petrology was merged with the Chemistry Section. This synergy has widened the research limits and resulted in higher efficiency of projects being carried out within both units. Since 1990, after transforming Bergbau-Forschung into DMT GmbH, a worldwide competition within hard coal and hard coal-based coke markets, together with the switch of the industry towards alternative energy sources, have significantly lowered the importance of the domestic coal mining industry. This in turn resulted in reduction of coal research programs. However, it is stressed that, in spite of transformations of the applied coal petrology experienced during the past 50 years, some achievements are still as applicable as ever. Among them, the method of predicting coke strength using maceral analysis and coal types, published by Mackowsky and Simonis [Mackowsky, M.-Th., Simonis, W., 1969. Die Kennzeichnung von Kokskohlen fur die mathematische Beschreibung der Hochtemperaturverkokung im Horizontalkammerofen bei Schuttbetrieb durch Ergebnisse mikroskopischer Analysen. Gluckauf-Forschungshefte 30, 25-27], is still in use today. The second part of this paper presents some examples of coal petrography applications, which are still important in carbonization processes. Mackowsky discovered that the pyrolytic components were influencing the coke homogeneity in coke ovens and affected coke quality parameters such as CRI and CSR. These highly graphitic layers and lenses prevent gasification of the inner zones of coke lumps, thus lowering the reactivity of metallurgical coke. Moreover, it also seems possible to predict wall load and maximum internal gas pressure as to prevent coke ovens from damage

  11. Development of coal petrography applied in technical processes at the Bergbau-Forschung/DMT during the last 50 years

    International Nuclear Information System (INIS)

    The paper deals with the activities of the Bergbau-Forschung Coal Petrography Laboratory in Essen (Germany), which, under the influence of Marie-Therese Mackowsky, developed into a stronghold of the industrial application of coal petrology. In 1979, the formerly independent Section for Mineralogy and Petrology was merged with the Chemistry Section. This synergy has widened the research limits and resulted in higher efficiency of projects being carried out within both units. Since 1990, after transforming Bergbau-Forschung into DMT GmbH, a worldwide competition within hard coal and hard coal-based coke markets, together with the switch of the industry towards alternative energy sources, have significantly lowered the importance of the domestic coal mining industry. This in turn resulted in reduction of coal research programs. However, it is stressed that, in spite of transformations of the applied coal petrology experienced during the past 50 years, some achievements are still as applicable as ever. Among them, the method of predicting coke strength using maceral analysis and coal types, published by Mackowsky and Simonis [Mackowsky, M.-Th., Simonis, W., 1969. Die Kennzeichnung von Kokskohlen fur die mathematische Beschreibung der Hochtemperaturverkokung im Horizontalkammerofen bei Schuttbetrieb durch Ergebnisse mikroskopischer Analysen. Gluckauf-Forschungshefte 30, 25-27], is still in use today. The second part of this paper presents some examples of coal petrography applications, which are still important in carbonization processes. Mackowsky discovered that the pyrolytic components were influencing the coke homogeneity in coke ovens and affected coke quality parameters such as CRI and CSR. These highly graphitic layers and lenses prevent gasification of the inner zones of coke lumps, thus lowering the reactivity of metallurgical coke. Moreover, it also seems possible to predict wall load and maximum internal gas pressure as to prevent coke ovens from damage

  12. Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

    1989-04-28

    This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

  13. Arc Plasma Torch Modeling

    CERN Document Server

    Trelles, J P; Vardelle, A; Heberlein, J V R

    2013-01-01

    Arc plasma torches are the primary components of various industrial thermal plasma processes involving plasma spraying, metal cutting and welding, thermal plasma CVD, metal melting and remelting, waste treatment and gas production. They are relatively simple devices whose operation implies intricate thermal, chemical, electrical, and fluid dynamics phenomena. Modeling may be used as a means to better understand the physical processes involved in their operation. This paper presents an overview of the main aspects involved in the modeling of DC arc plasma torches: the mathematical models including thermodynamic and chemical non-equilibrium models, turbulent and radiative transport, thermodynamic and transport property calculation, boundary conditions and arc reattachment models. It focuses on the conventional plasma torches used for plasma spraying that include a hot-cathode and a nozzle anode.

  14. Post-combustion CO2 capture : energetic evaluation of chemical absorption processes in coal-fired steam power plants

    OpenAIRE

    Oexmann, Jochen

    2011-01-01

    In this work, a semi-empirical column model is developed to represent absorber and desorber columns of post-combustion CO2 capture processes in coal-fired steam power plants. The chemical solvents are represented by empirical correlations on the basis of fundamental measurement data (CO2 solubility, heat capacity, density). The model of a CO2 capture process including the column model is coupled to detailed models of a hard-coal-fired steam power plant and of a CO2 compressor to evaluate and ...

  15. ALICE-ARC integration

    International Nuclear Information System (INIS)

    AliEn or Alice Environment is the Grid middleware developed and used within the ALICE collaboration for storing and processing data in a distributed manner. ARC (Advanced Resource Connector) is the Grid middleware deployed across the Nordic countries and gluing together the resources within the Nordic Data Grid Facility (NDGF). In this paper we will present our approach to integrate AliEn and ARC, in the sense that ALICE data management and job processing can be carried out on the NDGF infrastructure, using the client tools available in AliEn. The inter-operation has two aspects, one is the data management part and the second the job management aspect. The first aspect was solved by using dCache across NDGF to handle data. Therefore, we will concentrate on the second part. Solving it, was somewhat cumbersome, mainly due to the different computing models employed by AliEn and ARC. AliEN uses an Agent based pull model while ARC handles jobs through the more 'traditional' push model. The solution comes as a module implementing the functionalities necessary to achieve AliEn job submission and management to ARC enabled sites

  16. Iron-based syngas chemical looping process and coal-direct chemical looping process development at Ohio State University

    International Nuclear Information System (INIS)

    Highlights: • Moving bed reducer maximizes solids conversion and maintains full fuel conversion. • 850+ Operating hours completed in 25-kWth sub-pilot chemical looping units. • Full solid and gaseous fuel conversion achieved in sub-pilot chemical looping units. • Fully integrated, pressurized 250-kWth pilot SCL unit construction initiated. • Extensive techno-economic analysis performed on CDCL and SCL process configurations. - Abstract: The increasing demands for energy and concern of global warming are intertwined issues of critical importance. With the pressing need for clean, efficient, and cost-effective energy conversion processes, the chemical looping strategy has evolved as a promising alternative to the traditional carbonaceous fuel conversion processes. Chemical looping processes utilize oxygen carrier particles to indirectly convert carbonaceous fuels while capturing CO2 for sequestration and/or utilization. Throughout its development, multiple oxygen carrier compositions and reactor configurations have been studied and demonstrated. The Ohio State University (OSU) chemical looping technologies have received significant attention over the recent years. OSU’s unique moving-bed chemical looping technologies coupled with iron-based oxygen carrier particles capable of sustaining hundreds of redox cycles have the advantage of converting a variety of carbonaceous fuels, such as natural gas, coal and biomass, to electricity, H2, liquid fuels, or any combination thereof with zero to negative net CO2 emissions. Specifically, two chemical looping processes are being developed and studied, the syngas chemical looping (SCL) and the coal direct chemical looping (CDCL) technologies. Over the past 14 years, these processes have developed from a novel concept to successful sub-pilot (25 kWth) demonstrations. With the support of the Advanced Research Projects Agency – Energy (ARPA-E) of the US Department of Energy (USDOE), a 250 kWth high pressure SCL pilot

  17. Simulation of the Process of Arc Energy-Effect in High Voltage Auto-Expansion SF6 Circuit Breaker

    Institute of Scientific and Technical Information of China (English)

    Rong Mingzhe; Yang Qian; Fan Chunduo

    2005-01-01

    A new magnetic hydro-dynamics (MHD) model of arc in H.V. auto-expansion SF6circuit breaker that takes into consideration nozzle ablation due to both radiation and thermal conduction is presented in this paper. The effect of PTFE (polytetrafluorethylene) vapor is considered in the mass, momentum and energy conservation equations of the constructed model. Then,the gas flow fields with and without conduction considered are simulated. By comparing the aforementioned two results, it is indicated that the arc's maximal temperature with conduction considered is 90 percent of that without considering conduction.

  18. Performance assessment of CO2 capture with calcination carbonation reaction process driven by coal and concentrated solar power

    International Nuclear Information System (INIS)

    Calcination carbonation reaction (CCR) process is regarded as a promising option for pulverized coal power plant to mitigate CO2 emission. In this paper, concentrated solar power (CSP) substitutes for coal to supply part of the calcination energy in order to reduce the fossil fuel consumption associated with the calciner. A CCR process driven by coal and CSP is examined from the perspective of energy efficiency. This paper focuses on the parameters of heat recovery efficiency, CSP capacity, compression energy, air separation energy and recycled energy to determine the contribution of each to the overall energy penalty. In addition, the effects of heat recovery efficiency, CSP capacity, purge percentage and CO2 capture efficiency on the co-driven case are analyzed through a sensitivity analysis. The results indicate that the thermal efficiency of integrating CCR co-driven process into an ultra-supercritical 1019 MW power plant is 35.37%, which means that the overall efficiency penalty is 9.63 percentage points. Moreover, the co-driven case reduces the fossil fuel consumption and the mass flow rate of fresh sorbent and circulation solids compared with coal-driven case. Increasing heat recovery efficiency and CSP efficiency can improve the co-driven case performance. - Highlights: • We examine a CCR process driven by coal and concentrated solar power simultaneously. • The contributors to the overall energy penalty are quantitatively identified. • Obvious coal-saving effect has been found in the co-driven system. • A sensitivity analysis is conducted to find the impact of key parameters

  19. Process simulation of oxy-fuel combustion for a 300 MW pulverized coal-fired power plant using Aspen Plus

    International Nuclear Information System (INIS)

    Graphical abstract: This paper studied the combustion processes of pulverized coal in a 300 MW power plant using Aspen Plus software. The amount of each component in flue gas in coal-fired processes with air or O2/CO2 as oxidizer was obtained. The differences between the two processes were identified, and the parameter influences of temperature, excess oxygen ratio and molar fraction of O2/CO2 on the proportions of different components in flue gas were examined by sensitivity analysis. - Highlights: • Combustion processes were studied with Aspen Plus for a 300 MW pulverized coal power plant. • The amount of each flue gas component in coal-fired processes with air or O2/CO2 as oxidizer was obtained. • Differences between the two process models were identified. • The influences of operation parameters on the flue gas components were examined. - Abstract: This work focuses on the amounts and components of flue gas for oxy-fuel combustion in a coal-fired power plant (CFPP). The combustion process of pulverized coal in a 300 MW power plant is studied using Aspen Plus software. The amount of each component in flue gas in coal-fired processes with air or O2/CO2 as oxidizer is obtained. The differences between the two processes are identified, and the influences of temperature, excess oxygen ratio and molar fraction of O2/CO2 on the proportions of different components in flue gas are examined by sensitivity analysis. The process simulation results show that replacing atmospheric air by a 21%O2/79%CO2 mixture leads the decrease of the flame temperature from 1789 °C to 1395 °C. The equilibrium amount of NOx declines obviously but the SOx are still at the same level. The mass fraction of CO2 in flue gas increased from 21.3% to 81.5%. The amount of NOx is affected sensitively by the change of temperature and the excess oxygen ratio, but the change of O2/CO2 molar fraction has a little influence to the generation of NOx. With the increasing of O2 concentration, the

  20. Exxon catalytic coal gasification process development program. Quarterly technical progress report, January 1-March 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    1979-05-01

    This report covers the activites for the Exxon Catalytic Coal Gasification Development Program during the quarter January 1-March 31, 1979. Construction of a bench apparatus to study reactions of product and recycle gas in furnace and heat exchanger tubes was completed and checkout of the apparatus was begun. A Startup and Initial Operation Schedule, a Checkout Test Plan, and an Initial Startup Plan were developed for the Process Develoment Unit (PDU). The PDU will be started up in a sequential manner, with the gasification system being started up on a once-through basis first. The gas separation system will be started up next, followed by the catalyst recovery system. The programmable controller, which handles valve sequencing, alarming, and other miscellaneous functions on the PDU, was programmed and checkout was completed on the coal feed, gas feed, and filter systems. Work continued on defining the cause of the breakdown of char and lime during digestion in the prototype catalyst recovery unit. It was concluded that both the lime and char particles are fragile and will break down to fines if handled roughly. Removal of the potassium from the char by water washing does not cause the char particles to disintegrate. The perferred processing sequence for catalyst recovery in the PDU has been identified. Bench scale tests confirmed that the change in catalyst from K/sub 2/CO/sub 3/ to KOH was not responsible for the differences in fluidized bed densities between the present and the predevelopment operations of the FBG. Work was completed on a revised offsites facilities definition and cost estimate to update the CCG Commercial Plant Study Design prepared during the predevelopment program.

  1. Integrated fluid dynamics-process modelling of a coal-fired power plant with carbon capture

    International Nuclear Information System (INIS)

    Oxyfuel combustion, where the fuel is combusted in a mixture of pure oxygen and recycled flue gases instead of air, is one of the leading options for carbon capture from coal-fired power plants. Accurate simulation of the operation of such plants is critical for successful development of the technology. A major challenge of such a simulation is how to account for the fundamental differences in gaseous physical and thermal properties; in particular the radiative and convective heat transfer coefficients. In this paper a combined CFD-process approach is developed whereby a detailed CFD model is utilised to represent the complex gas-phase combustion and radiative heat transfer to the furnace walls and the radiant section of the boiler. This is then combined with a full plant process simulation which includes modifications to the heat transfer components to account for differing gas compositions. The novel integrated calculations have been completed for air-firing and for oxyfuel under a range of conditions and a comparison reveals that there is a possible ‘working range’ of oxygen concentrations/recycle ratios under which the distribution of heat transfer in the system is similar to air firing and hence the steam conditions can be controlled to set-point temperatures and flows. -- Highlights: ► Oxy fuel firing of pulverised coal in a conventional power plant with a thermosyphon boiler circuit. ► Boiler side modelled by CFD(FLUENT). ► Thermosyphon circuit modelled by gPROMS. ► Heat flux distribution from CFD drives the gPROMS simulation. ► Oxygen concentration recycle ratios predicted for oxy fuel firing

  2. A novel process for preparation of ultra-clean micronized coal by high pressure water jet comminution technique

    Energy Technology Data Exchange (ETDEWEB)

    Longlian Cui; Liqian An; Weili Gong; Hejin Jiang [China University of Mining and Technology, Beijing (China). School of Mechanics, Architecture and Civil Engineering

    2007-03-15

    A novel process for the preparation of ultra-clean micronized coal is presented in this paper. High pressure water jet mill replacing the ball mill is employed for coal comminution in the new preparation process, which is the essential difference from the traditional one. To compare the new preparation process with the traditional one, the comparison experiments were performed, with froth flotation tests of the fine particles ground by both mills using diesel oil and n-dodecane as collector, 2-octanol as frother, and sink-float separation tests using mixtures of carbon tetrachloride-benzene and carbon tetrachloride-bromoform as dense liquid. Different parameters including combustible recovery, ash content of the clean coal, separation efficiency, and energy consumption were investigated based on the two different preparation processes. The results show that the new preparation process has high combustible recovery, low ash content of the product, high separation efficiency, and low energy consumption compared with the traditional one. The comminution mechanism of high pressure water jet mill is introduced in this paper. The high pressure water jet comminution technique has great potential in coal pulverization, having the advantages of low energy consumption, low iron content, and low equipment wear. 35 refs., 4 figs., 7 tabs.

  3. Net coal thickness isopachs, Ferris 23, 25, 31, 50 and 65 coal zones, Hanna Basin Wyoming (fer*catg)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These ArcView shapefiles contain representations of the net coal thickness in the Ferris 23, 25, 31, 50 and 65 coal zones in the Ferris coalfield, Hanna Basin,...

  4. Net coal thickness in the Hanna 77, 78, 79 and 81 coal zones of Hanna Basin, Wyoming (ha*catg)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These ArcView shapefiles contain representations of the net coal thickness in the Hanna 77, 78, 79 and 81 coal zones, Hanna coalfield, Hanna Basin, Wyoming. These...

  5. Assessing coal burnout

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, A. [Pacific Power, Sydney, NSW (Australia)

    1999-11-01

    Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

  6. Study on activity evaluation of activated coal-gangue and the hydration process

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Chemical compositions, mineral compositions and the activated mechanism of the coal-gangue were analyzed. And pozzolana activities of the coal-gangue were evaluated after activated. Moreover, hydration heat and hydration compositions of activated coal-gangue-calcium oxide system, as well as hydration degree and hardened paste microstructures of activated coal-gangue-cement system were studied. Results show that pozzolana activities of the activated coal-gangue root in amorphous SiO2 and activated Al2 O3. With the exciting of gypsum, the reaction of activated coal-gangue and Ca(OH)2 would produce hydration products as ettringite, calcium silicate hydrate, and calcium aluminate. The relationship between the curing age and the content of Ca(OH)2 in coal-gangue-cement system was ascertained. Unhydrated particles in the coal-gangue-cement paste were more than that in the neat cement paste at the same hydration periods, and even existed at the later stage of hydration. Furthermore, the activated coal-gangue could inhibit growth and gathering of the calcium oxide crystal, and improve the structure of hardened cement paste.

  7. A review of state-of-the-art processing operations in coal preparation

    Institute of Scientific and Technical Information of China (English)

    Noble Aaron; Luttrell Gerald H.

    2015-01-01

    Coal preparation is an integral part of the coal commodity supply chain. This stage of post-mining, pre-utilization beneficiation uses low-cost separation technologies to remove unwanted mineral matter and moisture which hinder the value of the coal product. Coal preparation plants typically employ several parallel circuits of cleaning and dewatering operations, with each circuit designed to optimally treat a specific size range of coal. Recent innovations in coal preparation have increased the efficiency and capac-ity of individual unit operations while reinforcing the standard parallel cleaning approach. This article, which describes the historical influences and state-of-the-art design for the various coal preparation unit operations, is organized to distinguish between coarse/intermediate coal cleaning and fine/ultrafine coal cleaning. Size reduction, screening, classification, cleaning, dewatering, waste disposal unit operations are particularly highlighted, with a special focus on the U.S. design philosophy. Notable differences between the U.S. and international operations are described as appropriate.

  8. Application of welding science to welding engineering: A lumped parameter gas metal arc welding dynamic process model

    Energy Technology Data Exchange (ETDEWEB)

    Murray, P.E.; Smartt, H.B.; Johnson, J.A. [Lockheed Martin Idaho Technologies, Idaho Falls, ID (United States)

    1997-12-31

    We develop a model of the depth of penetration of the weld pool in gas metal arc welding (GMAW) which demonstrates interaction between the arc, filler wire and weld pool. This model is motivated by the observations of Essers and Walter which suggest a relationship between droplet momentum and penetration depth. A model of gas metal arc welding was augmented to include an improved model of mass transfer and a simple model of accelerating droplets in a plasma jet to obtain the mass and momentum of impinging droplets. The force of the droplets and depth of penetration is correlated by a dimensionless linear relation used to predict weld pool depth for a range of values of arc power and contact tip to workpiece distance. Model accuracy is examined by comparing theoretical predictions and experimental measurements of the pool depth obtained from bead on plate welds of carbon steel in an argon rich shielding gas. Moreover, theoretical predictions of pool depth are compared to the results obtained from the heat conduction model due to Christensen et al. which suggest that in some cases the momentum of impinging droplets is a better indicator of the depth of the weld pool and the presence of a deep, narrow penetration.

  9. EDS coal liquefaction process development, Phase V. Engineering design study of an EDS Illinois bottoms fired hybrid boiler

    Energy Technology Data Exchange (ETDEWEB)

    None

    1984-04-01

    This interim report documents work carried out by Combustion Engineering, Inc. under a contract to Exxon Research and Engineering Company and was prepared by Combustion Engineering, Inc. This report is the second of two reports by Combustion Engineering, Inc. on the predevelopment phase of the Hybrid Boiler program and covers the results of an engineering design study of a Hybrid Boiler firing the vacuum distillation residue (vacuum bottoms) derived from processing Illinois No. 6 coal in the EDS Coal Liquefaction Process. The function of the Hybrid Boiler is to heat the coal slurry feed for an EDS coal liquefaction plant by a process coil in the convection section and to generate high pressure steam in the radiant section. The Hybrid Boiler design developed in this phase of the program is based on the results of a laboratory characterization program (reported in EDS Interim Report FE-2893-112), on Combustion Engineering, Inc.'s extensive experience as a designer and supplier of steam generating equipment, and on Exxon Research and Engineering Co.'s experience with the design and operation of process heaters.

  10. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  11. Exergetic analysis of a steam power plant using coal and rice straw in a co-firing process

    Energy Technology Data Exchange (ETDEWEB)

    Restrepo, Alvaro; Miyake, Raphael Guardini; Bazzo, Edson [Federal University of Santa Catarina (UFSC), Dept. of Mechanical Engineering, Florianopolis, SC (Brazil)], e-mails: arestrep@labcet.ufsc.br, miyake@labcet.ufsc.br, ebazzo@emc.ufsc.br; Bzuneck, Marcelo [Tractebel Energia S.A., Capivari de Baixo, SC (Brazil). U.O. Usina Termeletrica Jorge Lacerda C.], e-mail: marcelob@tractebelenergia.com.br

    2010-07-01

    This paper presents an exergetic analysis concerning an existing 50 M We steam power plant, which operates with pulverized coal from Santa Catarina- Brazil. In this power plant, a co-firing rice straw is proposed, replacing up to 10% of the pulverized coal in energy basis required for the boiler. Rice straw has been widely regarded as an important source for bio-ethanol, animal feedstock and organic chemicals. The use of rice straw as energy source for electricity generation in a co-firing process with low rank coal represents a new application as well as a new challenge to overcome. Considering both scenarios, the change in the second law efficiency, exergy destruction, influence of the auxiliary equipment and the greenhouse gases emissions such as CO{sub 2} and SO{sub 2} were considered for analysis. (author)

  12. Thermal Arc Spray Overview

    Science.gov (United States)

    Hafiz Abd Malek, Muhamad; Hayati Saad, Nor; Kiyai Abas, Sunhaji; Mohd Shah, Noriyati

    2013-06-01

    Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

  13. Thermal Arc Spray Overview

    International Nuclear Information System (INIS)

    Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

  14. The influence of sorption processes on gas stresses leading to the coal and gas outburst in the laboratory conditions

    Energy Technology Data Exchange (ETDEWEB)

    Jacek Sobczyk [Strata Mechanics Research Institute of the Polish Academy of Sciences, Krakow (Poland)

    2011-03-15

    The seepage of gas through coal and in particular through coal briquettes has already been a quite well known phenomenon. This also refers to its influence on certain initial conditions of coal and gas outbursts such as threshold values of so called gas stresses. In turn a detailed research on the influence of sorption processes on these conditions has been neglected until now. There is, however, an opinion that (fast) desorption is crucial for rock and gas outburst initiation and continuance, although many examples contradict such a thesis. The goal of the studies described here was to investigate a part of this ambiguity, namely the influence of sorption processes on gas stresses leading to coal and gas outbursts carried out in laboratory conditions. A series of laboratory experiments concerning provoking coal and gas outbursts was conducted. Coal briquettes and two gases: nitrogen and carbon dioxide were used. The experimental data was computed out into the gas stresses and the most important information was extracted. The obtained results showed that in experiments with nitrogen slightly higher gas stresses and thus more intensive provoking were needed in order to initiate outburst than in experiments with carbon dioxide. It indicates that sorption may be the factor that promotes outbursts. Comparative analysis implied also that for a given level of gas stresses the more sorptive the gas was, the longer it took to initiate an outburst. Moreover, in the experiments with nitrogen the global maximum of gas stresses occurred deeper inside of the briquette for any given time than in experiments with carbon dioxide. All the found differences were weak, though easily noticeable. 27 refs., 6 figs.

  15. Graduate training in Earth science across borders and disciplines: ArcTrain -"Processes and impacts of climate change in the North Atlantic Ocean and the Canadian Arctic"

    Science.gov (United States)

    Stein, Rüdiger; Kucera, Michal; Walter, Maren; de Vernal, Anne

    2015-04-01

    Due to a complex set of feedback processes collectively known as "polar amplification", the Arctic realm is expected to experience a greater-than-average response to global climate forcing. The cascades of feedback processes that connect the Arctic cryosphere, ocean and atmosphere remain incompletely constrained by observations and theory and are difficult to simulate in climate models. Our capacity to predict the future of the region and assess the impacts of Arctic change processes on global and regional environments hinges on the availability of interdisciplinary experts with strong international experience and understanding of the science/society interface. This is the basis of the International Research Training Group "Processes and impacts of climate change in the North Atlantic Ocean and the Canadian Arctic - ArcTrain", which was initiated in 2013. ArcTrain aims to educate PhD students in an interdisciplinary environment that combines paleoclimatology, physical oceanography, remote sensing and glaciology with comprehensive Earth system modelling, including sea-ice and ice-sheet components. The qualification program for the PhD students includes joint supervision, mandatory research residences at partner institutions, field courses on land and on sea (Floating University), annual meetings and training workshops and a challenging structured training in expert skills and transferrable skills. Its aim is to enhance the career prospects and employability of the graduates in a challenging international job market across academic and applied sectors. ArcTrain is a collaborative project at the University of Bremen and the Alfred Wegener Institute for Polar and Marine Research in Bremerhaven. The German part of the project is designed to continue for nine years and educate three cohorts of twelve PhD students each. The Canadian partners comprise a consortium of eight universities led by the GEOTOP cluster at the Université du Québec à Montréal and including

  16. Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

    Science.gov (United States)

    Knightly, W. F.

    1980-01-01

    About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuels consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

  17. Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section B

    Science.gov (United States)

    Knightly, W. F.

    1980-01-01

    About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

  18. Reasonable Optimization of Coal Preparation Process Improve Efficiency of Coal Slime Recovery%合理优化选煤工艺提高煤泥回收效率

    Institute of Scientific and Technical Information of China (English)

    吕勇

    2014-01-01

    There is a coal preparation plant which type is a capacity of 5 .00 Mt/a mine coal preparation plant. Through the analysis of the status quo and existing problems of production,the existing process is improved.Puts for-ward the optimization scheme and adjusts the layout process and make full use of existing equipment to reach the best washing effect.Through the improvement of the coal slime water system process,can reduce the coal slime water re-tention time,increase the coal washing proportion of fine coal,improve the efficiency of the coal slime recovery.%某选煤厂是一座处理能力5.00 Mt/a矿井型选煤厂,通过分析其生产现状及存在问题,对现有工艺进行了改进,提出了优化方案并调整布置工艺,充分利用现有设备,达到最佳洗选效果;通过对煤泥水系统工艺的改进,减少了煤泥水滞留时间,增加了末煤洗选比例,提高了煤泥回收效率。

  19. Coal liquefaction process streams characterization and evaluation: Application of liquid chromatographic separation methods to THF-soluble portions of integrated two-stage coal liquefaction resids

    Energy Technology Data Exchange (ETDEWEB)

    Green, J.B.; Pearson, C.D.; Young, L.L.; Green, J.A. (National Inst. for Petroleum and Energy Research, Bartlesville, OK (United States))

    1992-05-01

    This study demonstrated the feasibility of using non-aqueous ion exchange liquid chromatography (NIELC) for the examination of the tetrahydrofuran (THF)-soluble distillation resids and THF-soluble whole oils derived from direct coal liquefaction. The technique can be used to separate the material into a number of acid, base, and neutral fractions. Each of the fractions obtained by NIELC was analyzed and then further fractionated by high-performance liquid chromatography (HPLC). The separation and analysis schemes are given in the accompanying report. With this approach, differences can be distinguished among samples obtained from different process streams in the liquefaction plant and among samples obtained at the same sampling location, but produced from different feed coals. HPLC was directly applied to one THF-soluble whole process oil without the NIELC preparation, with limited success. The direct HPLC technique used was directed toward the elution of the acid species into defined classes. The non-retained neutral and basic components of the oil were not analyzable by the direct HPLC method because of solubility limitations. Sample solubility is a major concern in the application of these techniques.

  20. Microstructure and abrasive wear properties of M(Cr,Fe7C3 carbides reinforced high-chromium carbon coating produced by gas tungsten arc welding (GTAW process

    Directory of Open Access Journals (Sweden)

    Soner BUYTOZ

    2010-01-01

    Full Text Available In the present study, high-chromium ferrochromium carbon hypereutectic alloy powder was coated on AISI 4340 steel by the gas tungsten arc welding (GTAW process. The coating layers were analyzed by optical microscopy, X-ray diffraction (XRD, field-emission scanning electron microscopy (FE-SEM, X-ray energy-dispersive spectroscopy (EDS. Depending on the gas tungsten arc welding pa-rameters, either hypoeutectic or hypereutectic microstructures were produced. Wear tests of the coatings were carried out on a pin-on-disc apparatus as function of contact load. Wear rates of the all coating layers were decreased as a function of the loading. The improvement of abrasive wear resistance of the coating layer could be attributed to the high hardness of the hypereutectic M7C3 carbides in the microstruc-ture. As a result, the microstructure of surface layers, hardness and abrasive wear behaviours showed different characteristics due to the gas tungsten arc welding parameters.

  1. ALICE: ARC integration

    CERN Document Server

    Anderlik, C; Kleist, J; Peters, A; Saiz, P

    2008-01-01

    AliEn or Alice Environment is the Grid middleware developed and used within the ALICE collaboration for storing and processing data in a distributed manner. ARC (Advanced Resource Connector) is the Grid middleware deployed across the Nordic countries and gluing together the resources within the Nordic Data Grid Facility (NDGF). In this paper we will present our approach to integrate AliEn and ARC, in the sense that ALICE data management and job processing can be carried out on the NDGF infrastructure, using the client tools available in AliEn. The inter-operation has two aspects, one is the data management part and the second the job management aspect. The first aspect was solved by using dCache across NDGF to handle data. Therefore, we will concentrate on the second part. Solving it, was somewhat cumbersome, mainly due to the different computing models employed by AliEn and ARC. AliEN uses an Agent based pull model while ARC handles jobs through the more 'traditional' push model. The solution comes as a modu...

  2. Monitoring temperatures in coal conversion and combustion processes via ultrasound. [Ultrasonic thermometry proposal

    Energy Technology Data Exchange (ETDEWEB)

    Gopalsami, N.; Raptis, A. C.; Mulcahey, T. P.

    1980-02-01

    A study of the state-of-the-art of instrumentation for monitoring temperatures in coal conversion and combustion systems has been carried out. The instrumentation types studied include Thermocouples, Radiation Pyrometers, and Acoustical Thermometers. The capabilities and limitations of each type are reviewed. The study determined that ultrasonic thermometry has the potential of providing viable instrumentation. Consequently, a feasibility study of the ultrasonic thermometry was undertaken. A mathematical model of a pulse-echo ultrasonic temperature measurement system is developed using linear system theory. The mathematical model lends itself to the adaptation of generalized correlation techniques for the estimation of propagation delays. Computer simulations are made to test the efficacy of the signal processing techniques for noise-free as well as noisy signals. Based on the theoretical study, acoustic techniques to measure temperature in reactors and combustors are feasible. To experimentally verify the technique it is needed (a) to test the available sensor materials at high temperatures under erosive and corrosive conditions and (b) upon the selection of the appropriate sensor material to validate the proposed signal processing technique. The base for the applicability of this technique will be the frequency of operation, which will determine the length of the sensor and the noise background at the frequency of interest. It is, however, believed that the proposed technique will provide reliable estimates under the noise background.

  3. Characterization of semi-coke generated by coal-based direct reduction process of siderite

    Institute of Scientific and Technical Information of China (English)

    朱德庆; 罗艳红; 潘建; 周仙霖

    2015-01-01

    Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based direct reduction process of iron ore is a by-product and its suitable utilization is not available so far. In order to handle it properly, the characteristics of this by-product were comprehensively investigated. A series of analysis methods were used to demonstrate its mineral compositions, petrography and physico-chemical properties. The results reveal that the semi-coke has poor washability. The fixed carbon content of semi-coke reaches 76.11% and the gross calorific value is 28.10 MJ/kg, both of which are similar to those of traditional sinter coke breeze. Also, semi-coke ash possesses lower content of SiO2, Al2O3, S and higher content of CaO and MgO, which could improve the strength of sinter ore when partially substituting for coke breeze in sintering. Semi-coke features well-development porous structure and higher reaction activity, which predicts that the sintering speed could be elevated to some extent when employing it as a partial replacement of coke breeze, so the studies further suggest that the potential adverse effect of the high reactivity on sintering process could be weakened by adequately coarsening the semi-coke’s particle size.

  4. Application of the SULF-X process to coal conversion and utilization. Phase II final report

    Energy Technology Data Exchange (ETDEWEB)

    Shapiro, E.; Bramer, H.C.; New, R.A.

    1984-01-01

    Pittsburgh Environmental and Energy Systems, Inc. contracted with the Department of Energy to demonstrate the efficacy of an iron sulfide flue gas treatment system (FGT) for removing sulfur dioxide (SO/sub 2/) and nitrogen oxides (NO/sub x/) and to correlate process variables to system performance. Laboratory and bench-scale testing was conducted with the SULF-X process, using both synthesized gas and actual flue gas from a coal-fired furnace. Laboratory tests resulted in 95% SO/sub 2/ removal and up to 95% NO/sub x/ removal. The bench-scale system demonstrated similar SO/sub 2/ removal efficiencies, but achieved only 39% NO/sub x/ removal due to relatively high oxygen concentrations in the flue gas and insufficient liquid-gas interfacial area within the absorber. Elemental sulfur was recovered during the regeneration steps. Total capital investment for the SULF-X system was estimated to be $91 to $103 per kilowatt (electric), compared to $90/kw for sodium solution scrubbing, $78 to $83/kw for magnesia slurry scrubbing and $74/kw for limestone slurry scrubbing. Annual operating costs for the SULF-X system were estimated to be 5.44 to 6.90 mills per kilowatt-hour, compared to 4.96 to 5.22 for sodium, 3.68 to 3.99 for magnesia and 3.73 to 4.25 for limestone. 6 references, 6 figures, 9 tables.

  5. Development of data processing system for regional geophysical and geochemical exploration of sandstone-hosted uranium deposits based on ArcGIS Engine

    International Nuclear Information System (INIS)

    According to the data processing need of geophysical and geochemical exploration of sandstone-hosted uranium deposits, the function design of the regional geophysical and geochemical data processing system is completed in the paper. The geophysical and geochemical data processing software with powerful functions is also developed based on ArcGIS Engine which remedies the shortage of GIS software for performing the geophysical and geochemical data processing. The development technique route of system software and key techniques are introduced, and the development processes of system software are showed through some development examples. Application practices indicate that the interface of developed system software with friendly interface and utility functions, may quickly perform the data processing of regional geophysical and geochemical exploration and provide the helpful deep information for predicting metallogenic prospective areas of sandstone-hosted uranium deposits. The system software is of a great application foreground. (authors)

  6. Measurement and modeling of advanced coal conversion processes. Twenty-second quarterly report, January 2, 1992--March 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

    1992-12-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO{sub x}-NO{sub x} submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  7. Explosions of coal powder in pressured process; Explosiones de Polvo de Carbon en Procesos a Presion

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    As continuation of the previous introductory work about explosions of coal under hyperbaric conditions and considering the higher risk of explosions repercution with pressure; it was decided to develop this ambitious project, taking into account the more extensive range of type of coals: since subbituminous coals through hard coal to anthracite. It has been considered also several type of sorbents as limestones and others. The main objective of the project is to define, by experimental way, the utilization conditions for a safety coal handling. Many variables have been analyzed: Coal characteristics and origin, type of limestones, oxygen. moisture, temperature, and pressure. Due the great project complexity it was necessary to build one especial installation for trails under high pressure, where it was possible to use all the big number of variable combinations. The main research result has been the development of a model which has the possibility to simulate and analyze the foreseeable performance of coals and sorbent blends, in order to avoid the exploitations using specific handling methods. (Author)

  8. Experimental and modeling study of the effect of CH(4) and pulverized coal on selective non-catalytic reduction process.

    Science.gov (United States)

    Zhang, Yanwen; Cai, Ningsheng; Yang, Jingbiao; Xu, Bo

    2008-10-01

    The reduction of nitric oxide using ammonia combined with methane and pulverized coal additives has been studied in a drop tube furnace reactor. Simulated flue gas with 1000 ppm NO(x) and 3.4% excess oxygen was generated by cylinder gas. Experiments were performed in the temperature range of 700-1200 degrees C to investigate the effects of additives on the DeNO(x) performance. Subsequently, a kinetic mechanism was modified and validated based on experimental results, and a computational kinetic modeling with CHEMKIN was conducted to analyze the secondary pollutants. For both methane and pulverized coal additives, the temperature window is shifted towards lower temperatures. The appropriate reaction temperature is shifted to about 900 and 800 degrees C, respectively with 1000 ppm methane and 0.051 g min(-1) pulverized lignite coal. The addition of methane and pulverized coal widens the temperature window towards lower temperature suggesting a low temperature application of the process. Furthermore, selective non-catalytic reduction (SNCR) reaction rate is accelerated evidently with additives and the residence time to complete the reaction is shortened distinctly. NO(x) reduction efficiency with 80% is achieved in about 0.3s without additive at 1000 degrees C. However, it is achieved in only about 0.2s with 100 ppm methane as additive, and only 0.07 and 0.05s are needed respectively for the cases of 500 and 1000 ppm methane. The modified kinetic modeling agrees well with the experimental results and reveals additional information about the process. Investigation on the byproducts where NO(2) and N(2)O were analyzed by modeling and the others were investigated by experimental means indicates that emissions would not increase with methane and pulverized coal additions in SNCR process and the efficacious temperature range of SNCR reaction is widened approximately with 100 degrees C. PMID:18727998

  9. Effect of different milling processes on the mineral distribution in a coal powder

    Institute of Scientific and Technical Information of China (English)

    Hao Juan; Zhang Hong; Yang Keyang; Lu Chao; Chen Jiabao; Li Yanan

    2012-01-01

    Coal samples obtained from Wanbei (WB),Pingxiang (PX),Liupanshui (LP),and Datong (DT) mines were pulverized,using either a vibration mill or a ball mill,to different degrees of fineness.The effect of the different grinding methods on the mineral distribution within the pulverized coal was investigated by using proximate analysis,particle size analysis,and float-sink tests.The results show that the ash content in WB,PX,and DT coal increases with increasing particle size overall,while the ash content of the LP coal remain almost the same within each size fraction.In that case the ash in each fraction is similar to that of the raw coal.The ash versus size distributions for the same coal sample milled with the same grinding method to different degrees of fineness are similar.The ash versus size distribution of the coal powder with a 15% screen residue that was prepared with the vibration mill is different from the distribution of a similar sample prepared with a ball mill.The curves also vary between different coal samples.The grinding method has a great influence on the distribution of minerals across the various particle sizes.The float-sink tests and the laser particle size analysis results on PX and DT coal samples show that fines dominate the higher density fractions although the large +2.0 g/cm3 fraction was dominated by coarse particles.The size distribution of the low density fraction and +2.0g/cm3 density fraction is bimodal.The size distribution of the intermediate density fraction is multimodal.

  10. Coal stream composition analysis for process control using prompt neutron activation analysis

    International Nuclear Information System (INIS)

    In this paper we describe early results of a series of laboratory experiments and computer modeling studies designed to provide realistic accuracy limits for the determination of the elemental concentration in coal using prompt neutron activation analysis. The results provide guidance for optimizing the technique for monitoring the quality of coal which is being input to an electric power generating plant. The reported work was performed as the initial phase of an ongoing program to develop a prototype on-line coal analyzer based on the PNAA technique for power plant application

  11. OPTIMIZATION OF PROCESS PARAMETERS TO MINIMIZE ANGULAR DISTORTION IN GAS TUNGSTEN ARC WELDED STAINLESS STEEL 202 GRADE PLATES USING PARTICLE SWARM OPTIMIZATION

    Directory of Open Access Journals (Sweden)

    R. SUDHAKARAN

    2012-04-01

    Full Text Available This paper presents a study on optimization of process parameters using particle swarm optimization to minimize angular distortion in 202 grade stainless steel gas tungsten arc welded plates. Angular distortion is a major problem and most pronounced among different types of distortion in butt welded plates. The process control parameters chosen for the study are welding gun angle, welding speed, plate length, welding current and gas flow rate. The experiments were conducted using design of experiments technique with five factor five level central composite rotatable design with full replication technique. A mathematical model was developed correlating the process parameters with angular distortion. A source code was developed in MATLAB 7.6 to do the optimization. The optimal process parameters gave a value of 0.0305° for angular distortion which demonstrates the accuracy of the model developed. The results indicate that the optimized values for the process parameters are capable of producing weld with minimum distortion.

  12. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-06-23

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. There are a number of parameters which are important for the production of acceptable cokes, including purity, structure, density, electrical resistivity, thermal conductivity etc. From the standpoint of a manufacturer of graphite electrodes such as GrafTech, one of the most important parameters is coefficient of thermal expansion (CTE). Because GrafTech material is usually fully graphitized (i.e., heat treated at 3100 C), very high purity is automatically achieved. The degree of graphitization controls properties such as CTE, electrical resistivity, thermal conductivity, and density. Thus it is usually possible to correlate these properties using a single parameter. CTE has proven to be a useful index for the quality of coke. Pure graphite actually has a slightly negative coefficient of thermal expansion, whereas more disordered carbon has a positive coefficient.

  13. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  14. 30 CFR 77.1112 - Welding, cutting, or soldering with arc or flame; safeguards.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Welding, cutting, or soldering with arc or... WORK AREAS OF UNDERGROUND COAL MINES Fire Protection § 77.1112 Welding, cutting, or soldering with arc or flame; safeguards. (a) When welding, cutting, or soldering with arc or flame near...

  15. Ground Penetrating Radar Signal Processing Algorithm in Advance Detection of Coal Seam

    OpenAIRE

    Wang Shuqi; Wang Zhen

    2013-01-01

    According to the electromagnetic propagation characteristics of Ground Penetrating Radar (GPR) in the medium, how to identify the target in coal seam using the relative permittivity of the dielectric object is studied, the identification algorithm of dielectric object based on electromagnetic echo field intensity with propagation loss and reflection loss are analyzed. The simulation results show that coal seam attenuation coefficient has extremely weak infl...

  16. Coupled flow and geomechanical processes during gas production from coal seams

    Energy Technology Data Exchange (ETDEWEB)

    Connell, L.D. [CSIRO Petroleum, Ian Wark Laboratory, Clayton, Victoria (Australia)

    2009-07-01

    Permeability in coal seams is sensitive to stress and pore pressure changes. An additional influence on this behaviour is the nature of the coal matrix to shrink with gas desorption and swell with adsorption. Concise relationships for permeability have been developed which incorporate these mechanisms, some of which are derived from a geomechanical basis such as the Shi-Durucan model and the Palmer-Mansoori model. While these expressions are attractive approaches for defining coal permeability during gas migration, the geomechanical behaviour has been simplified by assuming uni-axial strain and constant vertical stress. In this paper a coupled numerical model is developed and used to investigate the applicability of these geomechanical assumptions for gas drainage from coal seams. The modelling approach involved coupling the existing coal seam gas reservoir simulator, SIMED II, with the geomechanical simulator, FLAC3D. While SIMED II was used to simulate gas migration in a hypothetical coal seam and a series of production scenarios, FLAC3D simulated the geomechanical response of the coal and the adjacent non-coal geological formations to fluid pressure and gas content changes imported from SIMED II. The simulations, which considered a range of property values relevant to the San Juan basin, found that while the assumption of uni-axial strain introduced negligible discrepancy, the assumption of constant vertical stress leads to significant differences between the Shi-Durucan permeability estimate and that calculated from the SIMED-FLAC3D simulation, especially at early times during production. These differences were a result of the pressure and sorption strain changes induced by production leading to arching of stresses in the vicinity of the production well. The mechanism was shown to produce significant differences in the calculated gas rate particularly at early times during production. (author)

  17. Development of biological coal gasification (MicGAS Process). Eighth quarterly report

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-28

    This report describes progress on three fronts of the project. First in studies to elucidate optimal growing conditions for the consortia of coal degraders employed indicates that best growth occurs with 0. 2% w/v Shefton T. Secondly in comparing the biodegradative properties of the coal degraders, isolates identified as Mic-1 and Mic-4 were the best performers. And lastly bioreactors studies in batch mode are related.

  18. Use of advanced chemical fingerprinting in PAH source identification and allocation at a coal tar processing site

    International Nuclear Information System (INIS)

    Advanced chemical fingerprinting analyses were used to determine source allocation at a former coal tar processing facility which had been converted to a petroleum recycling site. Soil samples from the site had high petroleum hydrocarbon concentrations and elevated levels of polynuclear aromatic hydrocarbons (PAH). Comparisons of PAH distributions were used to differentiate the coal tar hydrocarbons from the petroleum hydrocarbons in soil samples. A more specific technique was needed to accurately allocate the contribution of the two sources to the observed PAH contamination in the soil. Petroleum biomarkers (steranes and triterpanes) which are present in crude oils and many refined petroleum products but are absent in coal tar were used to quantitatively allocate the source of the PAH contamination based on the relative ratio of the PAH to the biomarkers in soil samples. Using the resulting coal tar/petroleum source ratio the contribution of petroleum to the overall PAH contamination at the site was calculated. A multivariate statistical technique (principal component analysis or PCA) was used to provide an independent validation of the source allocation. The results of the source allocation provided a foundation for the site clean-up and remediation costs

  19. Coherence of Auger and inter-Coulombic decay processes in the photoionization of Ar@C60 versus Kr@C60

    CERN Document Server

    Magrakvelidze, Maia; Javani, Mohammad H; Madjet, Mohamed E; Manson, Steven T; Chakraborty, Himadri S

    2015-01-01

    For the asymmetric spherical dimer of an endohedrally confined atom and a host fullerene, an innershell vacancy of either system can decay through the continuum of an outer electron hybridized between the systems. Such decays, viewed as coherent superpositions of the single-center Auger and two-center inter-Coulombic (ICD) amplitudes, are found to govern leading decay mechanisms in noble-gas endofullerenes, and are likely omnipresent in this class of nanomolecules. A comparison between resulting autoionizing resonances calculated in the photoionization of Ar@C60 and Kr@C60 exhibits details of the underlying processes.

  20. Journal of Coal Science & Engineering(China)

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ Guide for Authors Journal of Coal Science & Engineering(English Edition), a comprehensive academic periodical of the China Coal Society, covers the fields of coal science and technology including coal geology, exploration,mine survey, mine project assessment, mine construction, coal mining, coal mine electrical machinery,mine safety, coal processing and utilization, coal mine environmental protection, etc. It reflects the latest research results and findings.

  1. Fabrication of Fe-FeAl Functionally Graded Material Using the Wire-Arc Additive Manufacturing Process

    Science.gov (United States)

    Shen, Chen; Pan, Zengxi; Cuiuri, Dominic; Roberts, Jon; Li, Huijun

    2016-02-01

    A functionally gradient iron-aluminum wall structure with aluminum composition gradient from 0 at. pct to over 50 at. pct is fabricated using a wire-arc additive manufacturing (WAAM) system. The as-fabricated alloy is investigated using optical microstructure analysis, hardness testing, tensile testing, X-ray diffraction phase characterization, and electron-dispersive spectrometry. The comprehensive analysis of the experimental samples has shown that the WAAM system can be used for manufacturing iron aluminide functionally graded material with full density, desired composition, and reasonable mechanical properties.

  2. Impregnating Coal With Calcium Carbonate

    Science.gov (United States)

    Sharma, Pramod K.; Voecks, Gerald E.; Gavalas, George R.

    1991-01-01

    Relatively inexpensive process proposed for impregnating coal with calcium carbonate to increase rates of gasification and combustion of coal and to reduce emission of sulfur by trapping sulfur in calcium sulfide. Process involves aqueous-phase reactions between carbon dioxide (contained within pore network of coal) and calcium acetate. Coal impregnated with CO2 by exposing it to CO2 at high pressure.

  3. 德国IGOR煤液化工艺及云南先锋褐煤液化%IGOR PROCESS OF DIRECT COAL LIQUEFACTION AND XIANFENG BROWN COAL LIQUEFACTION IN IT

    Institute of Scientific and Technical Information of China (English)

    李克健; 史士东; 李文博

    2001-01-01

    In this paper, IGOR process of direct coal liquefaction in Germany and experimental results of Xianfeng brown coal in 200 kg/d PDU of IGOR process in Germany are introduced. Compared with other direct coal liquefaction processes, IGOR process is characterized with higher throughout of coal hydrogenation reactor, higher integration degree and higher quality of oils. The results of Xianfeng coal tested in 200 kg/d PDU of IGOR process in Germany showed IGOR process marched Xianfeng brown coal well with 53% of oil yield, 2 mg/kg and 17 mg/kg of N and S contents. Qualified 0# diesel oil can be produced from Xianfeng coal oil with simple distillation and qualified 90# lead free gasoline can be produced from it with reforming step.%介绍了德国IGOR煤直接液化工艺和云南先锋褐煤在IGOR工艺200 kg/d的PDU装置的试验结果. 与其它煤直接液化工艺相比, IGOR工艺具有煤直接液化反应器的空速高、系统集成度高和油品质量好的特点. 云南先锋褐煤在IGOR工艺200 kg/d的PDU装置上的试验结果表明, 先锋褐煤是适宜IGOR煤液化的煤种, 得到的油收率为53%, 油品中氮和硫的含量分别为2 mg/kg和17 mg/kg.煤液化油经过简单蒸馏可得到合格的0#柴油,经过重整可得到合格的90#无铅汽油.

  4. Processing of Janina coal at 600 atm. to gasoline and middle oil. Second progress report

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer, H.; Leonhardt

    1944-03-13

    The experiments described here were run in a 10-liter hydrogenation oven which was fitted with an outlet for desanding the reaction mixture to keep down the formation of caviar deposits in the oven. The experiments proceeded very well, and the Janina coal proved to be one that was very well suited to hydrogenation because of its relatively low carbon content. The coal gave high yields of products (0.35 kg/liter/hour), low losses to gases (18.6%), and low levels of asphalt formation. Although the fact needed further confirmation in full-scale operations, it seemed that the Janina coal did not require as high a temperature from the preheater as did other coals in order to initiate the reaction (about 400/sup 0/C vs. about 425/sup 0/C). One of the disadvantages of the Janina coal was the fact that its rather large yield of liquid-phase gasoline had lower octane number than that from some other coals (Heinitz coal, for example - about 71 vs. 74). The gasoline contained 33% paraffins, 35% naphthenes, 23% aromatics, and 9% unsaturated compounds. The gasoline contained 11% phenol, whereas the middle oil contained 20.5% phenols. The aniline point of the various dephenolized fractions of gasoline varied from 18.2 to 36.0/sup 0/, whereas the aniline point of the various dephenolized fractions of middle oil varied from -24.5 to -14.0/sup 0/. The solidifying point of the heavy oil was 9/sup 0/C. 7 tables.

  5. Coal liquefaction process solvent characterization and evaluation: Technical progress report, July 1, 1986 through September 30, 1986

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1987-03-01

    Conoco Coal Research Division is characterizing samples of direct coal liquefaction process oils based on a variety of analytical techniques to provide a detailed description of the chemical composition of the oils, to more fully understand the interrelationship of process oil composition and process operations, to aid in plant operation, and to lead to process improvements. The approach taken is to obtain analyses of a large number of well-defined process oils taken during periods of known operating conditions and known process performance. Close cooperation is maintained with the process developers and with DOE in order to maximize the benefits of the work. Analytical methods used are based on their ability to provide quantitatively valid measures of process oil composition. Particular use is made of methods which provide chemical/molecular information of proven relevance to process performance. In addition, all samples are treated using conventional methods of analysis and preparation so that unit performance parameters, such as conversions and yields, can be independently determined to assure sample validity and correlation of analytical results among various plant operations. 10 refs., 3 figs., 20 tabs.

  6. Arc saw development report

    International Nuclear Information System (INIS)

    The arc saw is one of the key components of the Contaminated Equipment Volume Reduction (CEVR) Program. This report describes the progress of the arc saw from its inception to its current developmental status. History of the arc saw and early contributors are discussed. Particular features of the arc saw and their advantages for CEVR are detailed. Development of the arc saw including theory of operation, pertinent experimental results, plans for the large arc saw and advanced control systems are covered. Associated topics such as potential applications for the arc saw and other arc saw installations in the world is also touched upon

  7. Optimization of Gas Metal Arc Welding (GMAW) Process for Maximum Ballistic Limit in MIL A46100 Steel Welded All-Metal Armor

    Science.gov (United States)

    Grujicic, M.; Ramaswami, S.; Snipes, J. S.; Yavari, R.; Yen, C.-F.; Cheeseman, B. A.

    2015-01-01

    Our recently developed multi-physics computational model for the conventional gas metal arc welding (GMAW) joining process has been upgraded with respect to its predictive capabilities regarding the process optimization for the attainment of maximum ballistic limit within the weld. The original model consists of six modules, each dedicated to handling a specific aspect of the GMAW process, i.e., (a) electro-dynamics of the welding gun; (b) radiation-/convection-controlled heat transfer from the electric arc to the workpiece and mass transfer from the filler metal consumable electrode to the weld; (c) prediction of the temporal evolution and the spatial distribution of thermal and mechanical fields within the weld region during the GMAW joining process; (d) the resulting temporal evolution and spatial distribution of the material microstructure throughout the weld region; (e) spatial distribution of the as-welded material mechanical properties; and (f) spatial distribution of the material ballistic limit. In the present work, the model is upgraded through the introduction of the seventh module in recognition of the fact that identification of the optimum GMAW process parameters relative to the attainment of the maximum ballistic limit within the weld region entails the use of advanced optimization and statistical sensitivity analysis methods and tools. The upgraded GMAW process model is next applied to the case of butt welding of MIL A46100 (a prototypical high-hardness armor-grade martensitic steel) workpieces using filler metal electrodes made of the same material. The predictions of the upgraded GMAW process model pertaining to the spatial distribution of the material microstructure and ballistic limit-controlling mechanical properties within the MIL A46100 butt weld are found to be consistent with general expectations and prior observations.

  8. Study on law of raw coal seepage during loading process at different gas pressures

    Institute of Scientific and Technical Information of China (English)

    Meng Junqing; Nie Baisheng; Zhao Bi; Ma Yechao

    2015-01-01

    In order to reveal the law of raw coal seepage at different gas pressures, the gravity constant load seepage experimental system was developed and used. The law of raw coal seepage at different gas pressures with He, N2 and CO2 was investigated. The results show that, in a given state of stress during the experiment, with the increase of gas pressure, the permeability of raw coal sample prone to outburst exhibits a significantly decrease, and then exhibits an increasing trend when reaching the extreme point. The law of Klingberg coefficient related to the stress state and the gas adsorption properties was also obtained. Under the same experimental conditions, the Klingberg coefficient of He is greater than that of N2; and the Klingberg coefficient of CO2 has minimum value; so the stronger the gas adsorption is, the smaller the Klingberg coefficient of gas goes. Klinkenberg coefficient decreases with the increase of effective stress. Under the same conditions, the permeability of He is greater than that of N2; the permeability of CO2 has minimum value;so the stronger the gas adsorption is, the lower the permeability of the coal sample goes. The results have important significance in revealing the mechanism of gas seepage, predicting coal mine gas disaster, and gas drainage and safety production.

  9. A novel process for preparation of active carbon from sapropelitic coals

    Energy Technology Data Exchange (ETDEWEB)

    Bodoev, N.V.; Gruber, R.; Kucherenko, V.A.; Guet, J.-M.; Khabarova, T.; Cohaut, N.; Heintz, O.; Rokosova, N.N. [Siberian Branch of the Russian Academy of Sciences, Kemerovo (Russian Federation). Inst. of Carbon Material Chemistry

    1998-05-01

    The paper reports the preparation of active carbons starting from sapropelitic coals. First a traditional route of manufacturing, coking and activation (820{degree}C) was carried out. The specific area (BET) of the activated semicokes of six sapropelitic coal samples varied from a few square meters to about five hundred (for Taimylir coal). Secondly, using Taimylir coal, a novel way of active carbon preparation was attempted combining low temperature modification and chemical activation. The modification was carried out using nitric acid-acetic anhydride mixture at room temperature and tested by swelling and weight uptake measurements. The modified coal samples were analyzed by thermogravimetry (TGA) and FT-IR spectroscopy. The chemical activation route included impregnation by an activant (KOH) and a subsequent heating (2 hr under argon) at selected temperatures ranging from 300 to 900{degree}C. Surface areas were determined by BET and SAXS methods. The chemical modification resulted in a new functional group formation and organic framework reorganization, which strongly affected the activation, as a value of 1200 m{sup 2} g{sup -1} was obtained after chemical activation. 11 refs., 4 figs., 4 tabs.

  10. Coal Combustion Science

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  11. Efficiency improvements for the coal-fired power plant retrofit with CO2 capture plant using chilled ammonia process

    International Nuclear Information System (INIS)

    Highlights: • NH3 has been proposed as a viable solvent to reduce the efficiency penalty. • Retrofit of a coal-fired power plant with a chilled ammonia process was analysed. • A base case scenario showed that efficiency penalty fell between 10.4% and 10.9%. • Alternative process configurations for the efficiency improvement were investigated. • The efficiency penalty was reduced to 8.7%. - Abstract: Development of clean coal technologies for power generation is crucial in meeting the European Union 2050 target to reduce greenhouse gas emissions. CO2 capture technology using chemical solvents currently has the highest potential to decarbonise coal-based power generation. Substitution of amine solvent with NH3 has been proposed as a viable option to reduce the efficiency penalty. In this study, the scenario of a supercritical coal-fired power plant retrofitted with a chilled ammonia process capture plant and CO2 compression unit was modelled in a common simulation environment. To fully assess the integration impact on power plant performance, the pressure loss due to steam extraction has been taken into account by using the Stodola ellipse law. Analysis of a basic integration scenario revealed that the efficiency penalty fell between 10.4% and 10.9% points depending on the stripper pressure. The quality of extracted steam became insufficient to meet the reboiler heat requirement above a stripper pressure of 21.8 bar, and the lowest efficiency penalty was obtained when reboiler condensate was returned to the deaerator in the power plant. In evaluating measures to improve integration, the efficiency penalty was reduced to 8.7–8.8% points through the integration of a single-stage or two-stage auxiliary steam turbine, respectively, and a back-pressure turbine. Nevertheless, the analysis has indicated that the net impact on power plant performance is similar to that of an amine-based post-combustion CO2 capture plant

  12. Simultaneous effect of mechanical alloying and arc-melting processes in the microstructure and hardness of an AlCoFeMoNiTi high-entropy alloy

    International Nuclear Information System (INIS)

    Highlights: • Multi-component systems of AlCoFeMoNiTi were produced by mechanical alloying. • Consolidated samples were fabricated by two different processing routes, sintering and arc melting. • Effect of routes of consolidation on microstructural evolution and microhardness is reported. • High hardness values are found in consolidated samples. • Alloying elements, grain size, and precipitates have a high effect on microhardness. - Abstract: A nanostructured AlCoFeMoNiTi high entropy alloy was synthesized through the mechanical alloying process. Bulk samples were obtained by two different routes to compare the microstructural evolution and hardness behavior: sintering and arc melting. Through electron microscopy analyses the formation of Mo-rich and Ti-rich phases were identified in the melted sample, while Ti-rich nano-precipitates were observed in the sintered sample. A higher microhardness value was achieved on the sintered sample than for the melted sample. The disadvantage of porosity in the sintered sample in comparison to the melted one was overcome by the hardening effect produced by the mechanical alloying

  13. Simultaneous effect of mechanical alloying and arc-melting processes in the microstructure and hardness of an AlCoFeMoNiTi high-entropy alloy

    Energy Technology Data Exchange (ETDEWEB)

    Baldenebro-Lopez, F.J. [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, 31109 Chihuahua, Chih. (Mexico); Facultad de Ingeniería Mochis, Universidad Autónoma de Sinaloa, Prol. Ángel Flores y Fuente de Poseidón, S.N., 81223 Los Mochis, Sinaloa (Mexico); Herrera-Ramírez, J.M. [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, 31109 Chihuahua, Chih. (Mexico); Arredondo-Rea, S.P. [Facultad de Ingeniería Mochis, Universidad Autónoma de Sinaloa, Prol. Ángel Flores y Fuente de Poseidón, S.N., 81223 Los Mochis, Sinaloa (Mexico); Gómez-Esparza, C.D. [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, 31109 Chihuahua, Chih. (Mexico); Martínez-Sánchez, R., E-mail: roberto.martinez@cimav.edu.mx [Centro de Investigación en Materiales Avanzados (CIMAV), Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, 31109 Chihuahua, Chih. (Mexico)

    2015-09-15

    Highlights: • Multi-component systems of AlCoFeMoNiTi were produced by mechanical alloying. • Consolidated samples were fabricated by two different processing routes, sintering and arc melting. • Effect of routes of consolidation on microstructural evolution and microhardness is reported. • High hardness values are found in consolidated samples. • Alloying elements, grain size, and precipitates have a high effect on microhardness. - Abstract: A nanostructured AlCoFeMoNiTi high entropy alloy was synthesized through the mechanical alloying process. Bulk samples were obtained by two different routes to compare the microstructural evolution and hardness behavior: sintering and arc melting. Through electron microscopy analyses the formation of Mo-rich and Ti-rich phases were identified in the melted sample, while Ti-rich nano-precipitates were observed in the sintered sample. A higher microhardness value was achieved on the sintered sample than for the melted sample. The disadvantage of porosity in the sintered sample in comparison to the melted one was overcome by the hardening effect produced by the mechanical alloying.

  14. Influence of Plasma Transferred Arc Process Parameters on Structure and Mechanical Properties of Wear Resistive NiCrBSi-WC/Co Coatings

    Directory of Open Access Journals (Sweden)

    Eitvydas GRUZDYS

    2011-07-01

    Full Text Available Self-fluxing NiCrBSi and related coatings received considerable interest due to their good wear as well as corrosion resistance at moderate and elevated temperatures. Hard tungsten carbide (WC particles can be included in NiCrBSi for further increase of the coating hardness and abrasive wear resistance. Flame spray technique is widely used for fabrication of NiCrBSi films. However, in such a case, subsequent remelting of the deposited coatings by flame, arc discharge or high power laser beam is necessary. In present study NiCrBSi-WC/Co coatings were formed using plasma transferred arc process. By adjusting plasma parameters, such as current, plasma gas flow, shielding gas flow, a number of coatings were formed on steel substrates. Structure of the coatings was investigated using X-ray diffractometry. Microstructure of cross-sectioned coatings was examined using scanning electron microscopy. Hardness of the coating was evaluated by means of the Vickers hardness tests. Wear tests were also performed on specimens to determine resistance to abrasive wear. Acquired results allowed estimating the influence of the deposition process parameters on structure and mechanical properties of the coatings.http://dx.doi.org/10.5755/j01.ms.17.2.482

  15. Coal conversion processes and analysis methodologies for synthetic fuels production. [technology assessment and economic analysis of reactor design for coal gasification

    Science.gov (United States)

    1979-01-01

    Information to identify viable coal gasification and utilization technologies is presented. Analysis capabilities required to support design and implementation of coal based synthetic fuels complexes are identified. The potential market in the Southeast United States for coal based synthetic fuels is investigated. A requirements analysis to identify the types of modeling and analysis capabilities required to conduct and monitor coal gasification project designs is discussed. Models and methodologies to satisfy these requirements are identified and evaluated, and recommendations are developed. Requirements for development of technology and data needed to improve gasification feasibility and economies are examined.

  16. Dung beetle communities in coal mining areas in the process of recovery

    Directory of Open Access Journals (Sweden)

    Joana Zamprônio Bett

    2014-09-01

    Full Text Available Dung beetles that are sensitive to environmental alterations may be used as indicator species to mark the recovery of degraded areas. This work aimed at registering and comparing the communities of Scarabaeinae located in areas with different periods of environmental recovery after being used for coal mining. This study was developed in Lauro Müller, Santa Catarina, and consisted of two areas in the process of recovery, one for one year and one for five years. Fifteen pitfall traps baited with human feces were placed in each area in order to attract the dung beetles. The counting, identification and measurement of body size and biomass of the specimens captured were carried out in the laboratory. Sampling sufficiency was verified and variables from both areas were compared using a t test. The recorded species were Canthon aff. chalybaeus, Canthon angularis, Canthon rutilans cyanescens, Deltochilum multicolor, Dichotomius sericeus, Eurysternus parallelus and Ontherus sulcator. A total of 35 individuals were captured, three in the one-year recovery area and 32 in the area under recovery for five years, C. rutilans cyanescens being the most abundant species (40.6%. All species collected were found in the five-years recovery area, whereas only C. aff. chalybaeus and D. multicolor were found in the one-year recovery area. Individuals sampled in the area with one year of recovery had an average size of 11.03 mm and average biomass of 0.051 g, whereas in the five-years recovery area the average size and the biomass of the dung beetles sampled was 12.25 mm and 0.093 g, respectively.

  17. Waste Minimization Protocols for the Process of Synthesizing Zeolites from South African Coal Fly Ash

    Directory of Open Access Journals (Sweden)

    Leslie F. Petrik

    2013-04-01

    Full Text Available Production of a high value zeolite from fly ash has been shown to be an avenue for the utilization of South African fly ash which presently constitutes a huge disposal problem. The synthesis of zeolites Na-P1 and analcime on a micro-scale has been successful and preliminary investigation shows that scale-up synthesis is promising. However, the post-synthesis supernatant waste generated contains high levels of NaOH that may constitute a secondary disposal problem. A waste minimization protocol was developed to reduce the volume of waste generated with a view to enhancing the feasibility of the scale synthesis. Series of experiments were conducted in 100 mL jacketed batch reactors. Fly ash was reacted with 5 Mol NaOH on a 1:1 mass basis during the aging step, followed by hydrothermal treatment in which ultrapure water was added to the slurry. This study shows that by re-introducing the supernatant waste into the experiments in such a way that it supplies the required reagent (NaOH for the zeolite synthesis, zeolite Na-P1 and analcime can be synthesized. It also shows that the synthesis process can be altered to allow up to 100% re-use of the supernatant waste to yield high value zeolitic products. This study effectively constructed two protocols for the minimization of waste generated during the synthesis of zeolites from South African coal fly ash. This result could be used to establish a basis for legal and environmental aspects involved in the commission of a full-scale plant synthesizing zeolites NaP1 and analcime.

  18. Coal in South Africa

    Energy Technology Data Exchange (ETDEWEB)

    Dykes, A.R.

    1982-01-01

    This paper comprises a report on the coal industry in the Republic of South Africa. Stresses the importance of coal in the South African economy (meets 75% of the country's energy requirements and is in second place in the South African exports table). Covers deposits, production and prices, exports policy; winning methods, productivity and the various grades of coal. Also includes data on investments and refers to synthetic fuels from coal (Sasol I, II, III processes).

  19. Composition of neutral oils obtained in processing coals from Kansko-Achinsk basin

    Energy Technology Data Exchange (ETDEWEB)

    Plotskii, E.Y.; Kirilets, V.M.; Sidel' nikov, V.N.; Utkin, V.A.

    1986-03-01

    The authors used isopropyl alcohol as a solvent for coal from the Nazarovo deposit of the Kansko-Achinsk Basin. The separation and analysis of the liquid product obtained by supercritical dissolution (SCD) were performed in accordance with the scheme of separation and analysis of products from supercritical dissolution of coal presented in the paper. The group composition of the SCD liquid product and the elemental composition of the compounds recovered from this product (benzene-solubles, nitrogen bases, carboxylic acids, phenols, asphaltenes, paraffins, and neutral oils) are evidence of its value as a raw material for the production of motor fuels and as a raw material for the chemical industry.

  20. Gasification Coupled Chemical Looping Combustion of Coal: A Thermodynamic Process Design Study

    OpenAIRE

    Sonali A. Borkhade; Shriwas, Preksha A.; Ganesh R. Kale

    2013-01-01

    A thermodynamic investigation of gasification coupled chemical looping combustion (CLC) of carbon (coal) is presented in this paper. Both steam and CO2 are used for gasification within the temperature range of 500–1200°C. Chemical equilibrium model was considered for the gasifier and CLC fuel reactor. The trends in product compositions and energy requirements of the gasifier, fuel reactor, and air reactor were determined. Coal (carbon) gasification using 1.5 mol H2O and 1.5 mol CO2 per mole c...