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Sample records for application etude thermodynamique

  1. Preliminary studies on the closed cycle magneto aerodynamic converter; Etudes preliminaires sur les convertisseurs magnetohydrodynamiques fonctionnant hors d'equilibre thermodynamique

    Energy Technology Data Exchange (ETDEWEB)

    Ricateau, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    electron heating in argon-potassium can be achieved by magnetic fields from 1 to 2 Ts. Plans are being made to build an important facility which will work on the principle of hot shots. The gas generator will deliver cesium-seeded helium shots at a temperature of 2100 deg. K. The shot will last 1/ 10 s and the instantaneous thermal power will reach 1 MW. (author) [French] A cote des convertisseurs magnetoaerodynamiques a cycle ouvert qui transforment l'energie thermique contenue dans les gaz de combustion on etudie tres attentivement le convertisseur a cycle ferme qui peut tirer son energie de toute source de chaleur a haute temperature et tout particulierement des sources nucleaires. Avant une etude pratique de l'ensemble de la centrale les performances du convertisseur lui-meme doivent etre bien delimitees. Ces performances sont largement fonction de la conductivite du gaz utilise. Mais cette conductivite ne doit pas etre payee par une temperature techniquement inadmissible pour l'echangeur de chaleur. Dans le fluide de conversion on est amene a associer un gaz porteur, helium ou argon, et une semence facilement ionisable cesium ou potassium. L'ionisation purement thermique n'est efficace qu'a partir de 2500 deg. K, par contre le champ electrique developpe par induction dans le convertisseur peut, sous certaines conditions, accroitre la temperature electronique et developper une ionisation bien superieure a la valeur d'equilibre. Il devient alors possible d'ioniser le gaz a temperature moderee. Des travaux en cours ont pour but de preciser les conditions permettant de creer cette ionisation hors d'equilibre dans les gaz rares ensemenses. Des mesures ont ete faites a l'aide d'un plasmatron triphase do 500 kVA alimente a l'argon ensemence de potassium. On a fait debiter cet appareil dans une cellule permettant de mesurer les composantes tensorielles de la conductivite en presence de champ magnetique. Les valeurs trouvees dans les conditions d'equilibre thermodynamique

  2. Study of thermodynamic properties of binary and ternary liquid alloys of aluminium with the elements iron, cobalt, nickel and oxygen; Etude des proprietes thermodynamiques des alliages liquides binaires et ternaires de l'aluminium avec les elements fer, cobalt, nickel et l'oxygene

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    Vachet, F [CEA Vallee du Rhone, 26-Pierrelatte (France)

    1966-07-01

    The present work deals with the thermodynamic study of aluminium liquid alloys with the metals iron, cobalt and nickel. The experiments carried out lead to the activity, at 1600 deg C, of aluminium in the (Al, Fe), (Al, Co), (Al, Ni) liquid alloys. The experimental method used consists in studying the partition of aluminium between the liquid immiscible phases made up with the pairs of metals (Fe, Ag), (Co, Ag), (Ni, Ag). The informations so obtained are used for drawing the isothermal equilibrium phases diagrams sections of (Al, Fe, Ag), (Al, Co, Ag), (Al, Ni, Ag) systems. The study of the partition of silver between lead and aluminium joined with the determinations of several authors allows us to determine the aluminium activity, analytically presented, in the metal M (iron cobalt and nickel). The Wagner's interaction parameters of aluminium in metal M are determined. The results obtained as the equilibrium phases diagrams of (Al, M) systems allow to compare the thermodynamic properties of the Al Fe system in liquid and solid states and to estimate the enthalpies of melting of the AlCo and AlNi intermetallic compounds. The activity, at 1600 deg C, of aluminium in (Al, Fe, Co), (Al, Fe, Ni), (Al, Co, Ni) liquid alloys is estimated through thermodynamic properties of binary components systems by application of several methods leading to results in good agreement. The study of aluminium-oxygen interactions in the liquid metallic solvants M allows us to propose an explanation for the shape of the deoxidation equilibrium line of iron, cobalt and nickel by aluminium and to compare the de-oxidizing power of aluminium toward iron, cobalt and nickel oxides. (author) [French] Le travail presente se rapporte a l'etude thermodynamique des alliages liquides de l'aluminium avec les metaux fer, cobalt et nickel. Les experiences effectuees ont pour but de determiner l'activite, a 1600 C, de l'aluminium dans les alliages liquides (Al, Fe), (Al, Co), (Al, Ni). La methode

  3. Monte Carlo simulations for thermodynamical properties calculations of plasmas at thermodynamical equilibrium. Applications to opacity and equation of state calculations; Apport d'un code de simulation Monte Carlo pour l'etude des proprietes thermodynamiques d'un plasma a l'equilibre et application au calcul de l'elargissement des profils de raies ioniques emises dans les plasmas denses, aux opacites spectrales et aux equations d'etat de systemes fluides

    Energy Technology Data Exchange (ETDEWEB)

    Gilles, D

    2005-07-01

    This report is devoted to illustrate the power of a Monte Carlo (MC) simulation code to study the thermodynamical properties of a plasma, composed of classical point particles at thermodynamical equilibrium. Such simulations can help us to manage successfully the challenge of taking into account 'exactly' all classical correlations between particles due to density effects, unlike analytical or semi-analytical approaches, often restricted to low dense plasmas. MC simulations results allow to cover, for laser or astrophysical applications, a wide range of thermodynamical conditions from more dense (and correlated) to less dense ones (where potentials are long ranged type). Therefore Yukawa potentials, with a Thomas-Fermi temperature- and density-dependent screening length, are used to describe the effective ion-ion potentials. In this report we present two MC codes ('PDE' and 'PUCE') and applications performed with these codes in different fields (spectroscopy, opacity, equation of state). Some examples of them are discussed and illustrated at the end of the report. (author)

  4. Le modele de Hubbard bidimensionnel a faible couplage: Thermodynamique et phenomenes critiques

    Science.gov (United States)

    Roy, Sebastien

    Une etude systematique du modele de Hubbard en deux dimensions a faible couplage a l'aide de la theorie Auto-Coherente a Deux Particules (ACDP) dans le diagramme temperature-dopage-interaction-sauts permet de mettre en evidence l'influence des fluctuations magnetiques sur les proprietes thermodynamiques du systeme electronique sur reseau. Le regime classique renormalise a temperature finie pres du dopage nul est marque par la grandeur de la longueur de correlation de spin comparee a la longueur thermique de de Broglie et est caracterisee par un accroissement drastique de la longueur de correlation de spin. Cette croissance exponentielle a dopage nul marque la presence d'un pic de chaleur specifique en fonction de la temperature a basse temperature. Une temperature de crossover est alors associee a la temperature a laquelle la longueur de correlation de spin est egale a la longueur thermique de de Broglie. C'est a cette temperature caracteristique, ou est observee l'ouverture du pseudogap dans le poids spectral, que se situe le maximum du pic de chaleur specifique. La presence de ce pic a des consequences sur l'evolution du potentiel chimique avec le dopage lorsque l'uniformite thermodynamique est respectee. Les contraintes imposees par les lois de la thermodynamique font en sorte que l'evolution du potentiel chimique avec le dopage est non triviale. On demontre entre autres que le potentiel chimique est proportionnel a la double occupation qui est reliee au moment local. Par ailleurs, une derivation de la fonction de mise a l'echelle de la susceptibilite de spin a frequence nulle au voisinage d'un point critique marque sans equivoque la presence d'un point critique quantique en dopage pour une valeur donnee de l'interaction. Ce point critique, associe a une transition de phase magnetique en fonction du dopage a temperature nulle, induit un comportement non trivial sur les proprietes physiques du systeme a temperature finie. L'approche quantitative ACDP permet de

  5. Thermodynamic properties of beryllium hydroxide; Proprietes thermodynamiques de l'hydroxyde de beryllium. Etude du systeme BeO - H{sub 2}O - BE(OH){sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Baur, A; Lecocq, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The study of the hydro-thermal decomposition of beryllium hydroxide has made it possible to determine the free energy of formation and the entropy. The results obtained are in good agreement with the theoretical values calculated from the solubility product of this substance. They give furthermore the possibility of acquiring a better understanding of the BeO-H{sub 2}O-Be (OH){sub 2} system between 20 and 1500 C. (authors) [French] L'etude de la decomposition hydrothermale de l'hydroxyde de beryllium a permis de determiner l'energie libre de formation et l'entropie. Les resultats obtenus sont en bon accord avec les valeurs theoriques calculees a partir du produit de solubilite de ce corps. Ils donnent en outre la possibilite d'acceder a une meilleure comprehension du systeme BeO - H{sub 2}O - Be(OH){sub 2}, entre 20 C et 1500 C. (auteurs)

  6. Contribution to the thermodynamic study of the non-stoichiometric oxides UO{sub 2+x} et FeO{sub 1+x}; Contribution a l'etude thermodynamique des oxydes non stoechiometriques UO{sub 2+x} et FeO{sub 1+x}

    Energy Technology Data Exchange (ETDEWEB)

    Gerdanian, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-04-15

    This thermodynamic study has provided new results concerning the oxide UO{sub 2+X} and FeO{sub 1+x}. For the oxides UO{sub 2+X} correct values have been obtained for {mu}{sub O{sub 2}}{sup M} at 900, 1000 and 1100 deg. C using an improved method based on physico-chemical equilibria. For the oxides FeO{sub 1+x} the use of an E. Calvet high temperature calorimeter has made it possible to measure for the first time the values of h{sub O{sub 2}}{sup M} at 800 deg. C over the whole iron monoxide range. The method of oxygen transfer between oxides, usually used to determine the phase limits, has been improved by using a thermo-balance; this has made it possible to draw up simple rules which have to be respected in order to detect the phenomena under study. The theory due to J.S. Anderson has been applied to the oxides UO{sub 2+X} and a new method is given for improving the representation of non-stoichiometric oxides by models. (author) [French] Cette etude thermodynamique presente des resultats nouveaux en ce qui concerne les oxydes UO{sub 2+X} et FeO{sub 1+x}. Pour les oxydes UO{sub 2+X} les valeurs correctes de {mu}{sub O{sub 2}}{sup M} a 900, 1000 et 1100 deg. C ont pu etre obtenues, grace a la methode des equilibres physico-chimiques qui a ete amelioree. Pour les oxydes FeO{sub 1+x} l'emploi du microcalorimetre a haute temperature de Ed. CALVET a permis de mesurer pour la premiere fois les valeurs de h{sub O{sub 2}}{sup M} a 800 deg. C dans toute l'etendue du domaine du protoxyde de fer. La metode de transfert d'oxygene entre oxydes, habituellement utilisee pour determiner les limites de phase a ete perfectionnee par l'emploi d'une thermo-balance ce qui a permis d'enoncer les regles simples auxquelles il est indispensable de se conformer pour obtenir les limites cherchees. La theorie de J.S. Anderson a ete appliquee aux oxydes UO{sub 2+X} et une nouvelle voie est indiquee qui peut permettre de perfectionner la representation des oxydes non-stoechiometriques par des

  7. Contribution to thermodynamics and kinetics of argon, krypton and xenon at very low temperatures; Contribution a l'etude thermodynamique et cinetique de l'argon, du krypton et du xenon aux tres basses temperatures

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    Levenson, L L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    A critical analysis of the main theories of condensation, which are due to Zwanzig, Cabrera, Mc Caroll and Ehrlich, Wanlass, Armand, and Yu and Soo, is made. A condensation coefficient equal to unity is expected from these theories, except Armand and Yu and Soo, when the temperature of the gas impinging on its own solid phase is equal or less than 300 K. Using a resonating quartz microbalance the sensitivity of which is 10{sup -9} g. cm{sup 2} the experimental data agree with these theories when the temperature of the solid is less than 20 K. However the agreement must be interpreted for the more sophisticated theories of Armand and Yu and Soo. Regarding the sublimation of the rare gases one is faced with the theories of Salter, Eyring, Goodman and Armand. Within an order of magnitude the experimental data given here agree with the expected values. Moreover Armand theory is able to give the physical meaning of the observed results for argon sublimation from a krypton or a xenon crystalline substrate: localized modes of surface vibration occur. The relaxation time for the thermalization of the argon deposit is found greater than twelve hours at 25 K. (author) [French] Ce travail inclut l'etude critique des principales theories de la condensation dues a Zwanzig, Cabrera, Mc Caroll et Ehrlich, Wanlass, Armand, et Yu et Soo. Ces theories, sauf les deux dernieres, prevoient un coefficient de condensation egal a 1 lorsque le gaz incident sur son propre solide a une temperature inferieure ou egale a 300 K. Les mesures effectuees a l'aide d'une microbalance a quarz resonnant sensible a 10{sup -9} g. cm{sup 2} ont confirme ces theories dans le cas ou la temperature du solide est inferieure a 20 K. Cet accord doit cependant etre interprete pour les theories plus completes d'Armand d'une part, Yu et Soo d'autre part. Pour la sublimation des gaz rares on se trouve en presence des theories de Salter, Eyring, Goodman et Armand. Leurs previsions sont en accord, a un ordre de

  8. Thermodynamique des moteurs thermiques aux structures dissipatives

    CERN Document Server

    Prigogine, Ilya

    1999-01-01

    Ce livre constitue à la fois une présentation complète de la thermodynamique et une introduction scientifique à l'œuvre de Prigogine. Les auteurs innovent en montrant comment la thermodynamique du non-équilibre est un prolongement naturel de la thermodynamique de l'équilibre. Elle constitue ainsi la science des processus irréversibles - " la flèche du temps " - dont les structures dissipatives sont les témoignages les plus éclatants. Les développements historiques en font, non seulement un texte de référence, mais aussi un livre de culture. Les nombreux exemples et exercices, comme les programmes informatiques et les références aux sites Internet en font un outil de travail irremplaçable.

  9. Study of thermodynamics and electronics properties of hybrids of substituted Haucke compounds; Contribution a l'etude des proprietes thermodynamiques et electroniques d'hydrures de composes de Haucke substitues

    Energy Technology Data Exchange (ETDEWEB)

    Crivello, J.C

    2005-06-15

    This manuscript presents a combined experimental and theoretical contribution to the study of the substituted Haucke phase AB5. These compounds can reversibly absorb hydrogen under conditions of pressure and temperature satisfactory for many technological applications including hydrogen storage. The thermodynamic characterization of the solid-gas reaction was carried out for mono and poly-substituted compounds. In the respect of good conditions of growth (decomposition) of the hydride phase, we sought to determine the thermodynamic trajectories allowed during some various transformations. The experimental results showed that the rate of transformation and the hierarchy of the return-points memory are the only parameters allowing to draw a general law related to the irreversible character of hysteresis. These systems evolve in 'static' mode, independent of the time and whatever the nature of host materials. Moreover, the effect of substitution elements on electronic properties has been studied using ab initio band structure calculations for the ANi{sub 5} (A=La, Y, Ca) and LaNi{sub 5-x}M{sub x} compounds, where M is an element of the type s-p (Al, Si, Ge, Sn), of type s (Cu), or a transition metal (Mn, Fe, Co). While dissociating the structural effects, the role of the chemical interaction with hydrogen was analyzed. These results made it possible to identify the factors which control the stability of the hydrides and their maximum absorption capacity. The bulk moduli of these materials were calculated and their variation was discussed in relation to the properties of hydrogen absorption. (author)

  10. The thermodynamic approach of the pilot-scale purification of refractory metals; Application de la thermodynamique a la mise au point des methodes de purification industrielle des metaux et semi-metaux refractaires

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    Accary, A [Commissariat a l' Energie Atomique, Dir. des Piles Atomiques, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    The author shows how the thermodynamic can be applied to the prediction of the evolution of impurities from a metal or an alloy being melted and cast at the pilot-scale using electron bombardment and continuous casting in a water cooled copper. He studies this possibility on two examples: - the melting vanadium, - the melting of the uranium monocarbide. He shows using only the constants available in the literature and a few special runs in the pilot-equipment itself it is possible to determine: - the possibility of elimination of anyone impurity by keeping the material in the melting state under vacuum as well as the limit of purification which is achievable under given technological conditions, - the proportion of an impure metal which should be vaporized in order to bring the level of a given impurity down to a predetermined level and the necessary duration of heating. (author) [French] L'auteur montre comment la thermodynamique peut etre appliquee a la prevision de l'evolution d'un metal ou d'un alliage fondu a l'echelle pilote par bombardement d'electrons et coule en continu dans un creuset de cuivre refroidi. Il etudie cette possibilite sur deux cas particuliers: - la fusion de vanadium, - la fusion du monocarbure d'uranium. Il montre que, grace aux constantes disponibles dans la litterature et a des essais simples faits a l'aide de l'appareillage pilote lui-meme, on peut determiner: - la possibilite d'eliminer une impurete par maintien a l'etat fondu ainsi que la limite de purification dans des conditions technologiques donnees, - la proportion d'un metal brut qu'il faut evaporer pour amener sa teneur en une impurete a un niveau donne ainsi que la duree de chauffage necessaire, - la nature des additions propres a favoriser le depart d'une impurete et l'efficacite comparee des additions possibles. (auteur)

  11. Thermo chemical calculations applied to the study of ceramic corrosion at high temperature - Steel-making applications; Apport de la thermodynamique a l'etude de la corrosion des ceramiques a haute temperature - Applications siderurgiques

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    Poirier, J. [Orleans Univ., Polytechnique, 45 (France); Centre National de la Recherche Scientifique (CNRS/CEMHTI), 45 - Orleans-la-Source (France)

    2008-05-15

    At high temperature, corrosion by gas, slag or metal is recognized in many cases as the essential degradation mode of ceramics. The reaction between the ceramic and the corrosive agent should be described taking into account both the kinetic aspects (rates and mechanisms of the reactions) and the thermodynamic aspects (equilibrium conditions). After a short description of the thermodynamic tools, we will show how some thermo chemical calculations, involving complex multi-component systems at high temperature, can be applied to explain some practical situations. Different examples, from steel making, will be considered: effects of composition changes upon the stability of the refractories and reactions of corrosion between the refractories, the gas and the liquid oxides. (author)

  12. Application d'une équation d'état à la simulation du comportement thermodynamique des fluides dans les gisements et dans les installations de surface Application of an Equation of State to Simulating the Thermodynamic Behaviour of Fluids in Reservoirs and Surface Installations

    Directory of Open Access Journals (Sweden)

    Jain C.

    2006-11-01

    Full Text Available La connaissance des propriétés thermodynamiques des fluides pétroliers, en particulier des masses volumiques et des coefficients d'équilibre liquide-vapeur, intervient à divers stades de la production : primaire, secondaire par in-jection de gaz (C02 ou hydrocarbures miscibles, vapeur d'eau, séparation, réseau de collecte et de transport. L'ampleur du domaine de pression et de température à l'intérieur duquel on a besoin de connaître les propriétés des huiles et des gaz à condensat, et le fait que la compo-sition d'ensemble des mélanges diphasiques ne cesse de varier au cours de leur déplacement soit dans les gisements, soit dans les installations d'exploitation, rendent mani-feste l'intérêt de pouvoir calculer ces propriétés, en évi-tant d'avoir recours à des travaux de laboratoire beaucoup trop importants. Pour résoudre ces problèmes, une nouvelle équation d'état appelée Redlich-Kwong Développée (RKD a été mise au point. Au cours de cet exposé, nous verrons que cette équation restitue les enveloppes diphasiques de l'équilibre liquide-vapeur avec une qualité au moins égale à celles des méthodes de Soave et de Peng-Robinson qui jouissent actuellement d'une grande notoriété. L'avantage de ce modèle sur ces dernières méthodes est l'évaluation simultanée des propriétés volumétriques des phases en présence avec une bonne précision, ce qui est d'une grande utilité pour l'application de ce modèle aux problèmes industriels. Knowing the thermodynamic properties of petroleum fluids, and in particular the density and liquid-vapor equilibrium coefficients, is important at different stages of production, i. e. primary production, secondary production by gas flooding (CO2 or miscible hydrocarbons, steam, separation, gathering network and transportation. The pressure and temperature range within which the oil and gas-condensate properties must be known coupled with the fact that the overall composition of

  13. Etude cinetique et thermodynamique de la dissolution de la fluorapatite dans l'acide phosphorique

    International Nuclear Information System (INIS)

    Brahim, K.; Khattech, I.; Dubes, J.P.; Jemal, M.

    2005-01-01

    A modification on the reversal cells of a C-80 SETARAM calorimeter allows a Joule effect in the reaction cells to determine a transfer function in experimental conditions close to those of dissolution of a solid in a liquid. The calorimeter was then used to determine in isothermal conditions both thermodynamic and kinetic parameters associated with dissolution of synthetic fluorapatite in phosphoric acid solutions. Due to the rapidity of reaction, the heat flow recordings were deconvoluted and the resulting curves were analyzed iteratively to obtain the rates of digestion and the enthalpy of dissolution at 298 K of fluorapatite in phosphoric acid solution containing 10, 18 or 30 wt% P 2 O 5 . The results agree with a two-step dissolution mechanism. The first step is the dissolution of the solid in phosphoric acid, and the second is the formation of the complex Ca(H 2 PO 4 ) +

  14. Fundamental study of ionization and dissociation processes caused by electron impact in aromatic molecules; application of the quasi-equilibrium theory to phenanthrene and to methylphenanthrenes; Etudes fondamentales des processus d'ionisation et de dissociation des molecules aromatiques par impact electronique et application de la theorie du quasi-equilibre au phenanthrene et aux methyl-phenanthrenes

    Energy Technology Data Exchange (ETDEWEB)

    Nounou, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    behaviour under ionizing radiations of the studied compounds. (author) [French] La theorie du quasi-equilibre n'a ete appliquee jusqu'a present qu'a la seule famille des hydrocarbures aliphatiques en chaine droite. Nous avons donc essaye de l'etendre au phenanthrene et au methyl-phenantrene, c'est-a-dire, d'une part a des molecules aromatiques et d'autre part a des molecules ayant un tres grand nombre de degres de liberte. Dans une premiere partie nous avons tente d'interpreter de facon methodique les processus d'ionisation et de dissociation des molecules phenanthreniques. Cette premiere etude experimentale du comportement des composes sous impact electronique, et son interpretation, nous ont fourni de precieux renseignements sur de profonds changements de structure des ions moleculaires et fragmentaires, voire d'excitation des molecules etudiees. L'etude approfondie des pics metastables a ensuite confirme les processus de dissociation precedents, tout en precisant certaines grandeurs thermodynamiques relatives aux reactions de decomposition. Etudes des processus d'ionisation, puis de dissociation, et enfin des pics metastables, constituent les trois temps d'une methode generale d'interpretation de la fragmentation en spectrometrie de masse. Pour donner a cette methode son assise theorique nous avons ete amenes a elaborer les diagrammes moleculaires de chacun des composes etudies, montrant ainsi l'aide efficace que peut presenter la Mecanique Quantique pour l'etude des etats excites et ionises. Dans une seconde partie, nous avons calcule les spectres de masse du phenanthrene et des methyl-phenanthrenes a partir des expressions des constantes de reaction donnees par ROSENSTOCK. Pour ce faire, nous avons propose de nouvelles methodes de calcul des facteurs de frequence, tant pour les molecules aliphatiques que les aromatiques. Si le bon accord generalement observe entre le calcul et l'experience ne peut etre attribue a coup sur a l'exactitude de la theorie, il n'en demontre

  15. Development of mercury porosimeter. Application to nuclear graphite studies (1961); Mise au point d'un porosimetre a mercure. Application a l'etude des graphites nucleaires (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Bocquet, M; Genisson, J; Sailleau, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    A mercury porosimeter, model IFP-CEA, has been developed for application to nuclear graphite studies. The apparatus is based on the capillary depression phenomenon. The relationship between the radius of a pore and the pressure at which mercury fills it is pr = -2 {sigma} cos {theta} ( {sigma} is the surface tension, {theta} the angle of contact of the mercury). After some theoretical consideration, the apparatus is described. The mercury pressure is increased step-wise from 0 to 1000 kg/cm{sup 2} thus yielding the complete distribution of pores from 92 {mu} to 75 A. Results are, then presented concerning nuclear graphites which show the evolution of the porous structure under the effect of bitumen impregnation. In general, the volume of the large pores decreases while that of the small pores increases. The structure of impregnated products appears to depend to a certain extent on that of the starting materials. It has also been possible to study other products with this porosimeter; the range of measurements possible is such that it may be used for the study of the majority of porous materials. (authors) [French] Un porosimetre a mercure modele IFP-CEA a ete mis au point en vue de son application a l'etude de graphites nucleaires. Le fonctionnement de l'appareil repose sur le phenomene de depression capillaire. On etablit la relation existant entre le rayon r d'un pore et la pression p pour laquelle le mercure peut y penetrer: pr = -2 {sigma} cos {theta} ( {sigma} tension superficielle, {theta} angle de contact du mercure). Apres quelques considerations theoriques, l'appareil utilise est decrit. Il permet de faire varier par palier la pression du mercure entre 0 et 1000 kg/cm{sup 2} et d'etablir ainsi la distribution complete des rayons de pores compris entre 92 {mu} et 75 A. Les resultats d'une etude faite sur des graphites nucleaires sont alors presentes faisant apparaitre l'evolution de la structure poreuse sous l'effet des impregnations au brai. D'une facon

  16. Diverses questions de mecanique et de thermodynamique classiques et relativistes

    Science.gov (United States)

    de Broglie, Louis; Lochak, Georges; Karatchentzeff, Michel; Fargue, Daniel

    Ce livre reproduit un cours inédit de Louis de Broglie, de 1948, dans lequel il réexamine, gráce à la relativité, les analogies entre la mécanique et la thermodynamique étudiés par Helmholtz, Boltzmann et Planck avant le succès de la mécanique statistique. C'est le premier d'une série de travaux de de Broglie en vue de prolonger sa découverte de 1924 vers une mécanique ondulatoire des processus irréversibles, en unifiant les principes de Fermat, de Maupertuis et de Carnot-Clausius. L'intérêt du livre est triple: 1. une généralisation de la mécanique quantique qui décrirait les transitions quantiques en tant que processus dynamiques; 2. revisiter la physique classique en compagnie de l'un des plus grands physiciens du siècle 3. découvrir quelques grands idées oubliées de la physique classique.

  17. Thermodynamic Calculation of the Distribution Coefficient Between the Liquid and Solid Phases of an Element in Dilute Solution in a Metal: Application to the Purification of Beryllium; Calcul Thermodynamique du Coefficient de Distribution Entre Phases Liquide et Solide d'un Element en Presence d'Autres Constituants en Solution Diluee dans un Metal: Application a la Purification du Beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Desre, P. [Ecole Nationale Superieure d' Electrochimie et d' Electrometallurgie (France); Schaub, B. [Centre d' Etudes Nucleaires de Grenoble (France); Bonnier, I. E. [Ecole Nationale Superieure d' Electrochimie et d' Electrometallurgie, Grenoble (France)

    1966-01-15

    The authors calculate the distribution coefficient {Gamma}{sub i} between the liquid and solid phases of an element i in the presence of other elements j in a solvent M ({Gamma}{sub i} = x'{sub i}/x{sub i}, where x'{sub i} and x{sub i} are the atomic fractions of i in the solid and liquid phases respectively) from the thermodynamic properties of binary systems of the type (i, M), (j, M) and (i, j). They show that the interaction of all the elements present may, under certain conditions, strongly affect the value of the coefficient {Gamma}{sub i}. This effect is pronounced if the following condition is fulfilled: {gamma}{sup {infinity}}{sub i(M)}, {gamma}{sup {infinity}}{sub j(M)} > {gamma}{sup {infinity}}{sub ij} where {gamma}{sup {infinity}}{sub i(M)}, {gamma}{sup {infinity}}{sub j(M)} and {gamma}{sup {infinity}}{sub ij} are limiting activity coefficients of the constituents i and j in the (i, M) (j, M) and (i, j) liquid state systems. It is a simple matter to deduce from this condition an application to the purification of metals by the zone-melting method; the condition enables one to choose an element j which is added deliberately to a metal in order to facilitate the elimination-of an element i (subsequent elimination of the element j being also, of course, a simple matter). For example, the authors were able to confirm that the addition of aluminium to beryllium enables one to improve the elimination of iron during the purification of the beryllium by the zone-melting technique, the aluminium acting as a carrier. (author) [French] Les auteurs calculent le coefficient de distribution Greek-Capital-Letter-Gamma {sub i} entre phases liquide et solide d'un element i en presence d'autres elements j dans un solvant M ( Greek-Capital-Letter-Gamma {sub i} = x'{sub i}/x{sub i}, x'{sub i} et x{sub i} representant respectivement les fractions atomiques de i dans les phases solide et liquide), a partir des proprietes thermodynamiques des systemes binaires de type: (i, M

  18. Folds and Etudes

    Science.gov (United States)

    Bean, Robert

    2007-01-01

    In this article, the author talks about "Folds" and "Etudes" which are images derived from anonymous typing exercises that he found in a used copy of "Touch Typing Made Simple". "Etudes" refers to the musical tradition of studies for a solo instrument, which is a typewriter. Typing exercises are repetitive attempts to type words and phrases…

  19. The Application of Oxygen Concentration Cells with the Solid Electrolyte ZrO{sub 2} * CaO to Thermodynamic Research; Emploi des Cellules a Concentration d'Oxygene avec Electrolyte Soude de ZrO{sub 2} * CaO, Dans les Recherches en Thermodynamique; Primenenie kislorodnykh kontsentratsionnykh kamer s tverdym ehlektrolitom ZrO{sub 2} * CaO dlya issledovanij po termodinamike; Aplicacion de las Celdas de Concentracion de Oxigeno con Electrolito Solido de ZrO{sub 2} * CaO a las Investigaciones Termodinamicas

    Energy Technology Data Exchange (ETDEWEB)

    Matsushita, Y.; Goto, K. [University of Tokyo (Japan)

    1966-01-15

    'oxygene dans les etudes fondamentales sur les processus metallurgiques, et ils discutent aussi leur application industrielle. (author) [Spanish] Se presentan en la memoria seis trabajos experimentales relacionados con la aplicacion de las celdas de concentracion de oxigeno con electrolito de ZrO{sub 2} * CaO (que permite una conduccion amonica pura debida a la migracion de defectos de oxigeno) a tareas de investigacion basica en procesos metalurgicos. 1. Se midieron las energias libres tipo de formacion del FeO, Fe{sub 3}O{sub 4}, SnO, PbO, Cu{sub 2}O, CuO y Ta{sub 2}O{sub 5} y se expresan mediante funciones de la temperatura en el intervalo 500 Degree-Sign - 1300 Degree-Sign C. 2. Se midio de 800 Degree-Sign a 1100 Degree-Sign C la tension de oxigeno en solucion liquida de PbO-SiO{sub 2}: se calcularon las actividades quimicas del PbO y del SiO{sub 2}, y tambien las propiedades termodinamicas, de la solucion de Pb0-Si02. 3. Uno de los autores de la presente memoria midio la actividad quimica del estano en una solucion binaria liquida Pb-Sn de 700 Degree-Sign a 900 Degree-Sign C y calculo las propiedades termodinamicas de las aleaciones Pb-Sn. 4. Este autor ha disenado ademas un manometro de oxigeno para medir la presion parcial del oxigeno en los gases a temperaturas elevadas (de 500 Degree-Sign - 1300 Degree-Sign C) en el intervalo 10{sup -1} a 10{sup -20} atm. Se han obtenido valores coherentes y reproducibles para las fuerzas electromotrices con varias mezclas gaseosas. 5. Partiendo de los resultados EMF obtenidos con el manometro de oxigeno se calcularon las velocidades de oxidacion o reduccion del hierro puro y de los oxidos de hierro por accion de una mezcla gaseosa de CO-CO{sub 2}, a 900 Degree-Sign - 1000 Degree-Sign C. 6. Usando electrodos de referencia de grafito o polvo de (Ni + NiO) se midio la presion del oxigeno en hierro liquido que contenia diversas cantidades de carbon hasta el valor de saturacion, o bien estaba saturado con oxigeno o grafito, Es evidente que

  20. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete mesurees, et les schemas de

  1. Possibilities and limitations of analogue methods for studying the dynamics of nuclear power stations; Possibilites et limitations du calcul analogique pour les etudes dynamiques de centrales nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Caillet, C; Deat, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    1. Introduction: the present paper is devoted to analog simulation of problems related to nuclear reactors other than the simulation of the kinetic equations which is well known. 2. Thermodynamic problems: various problems relative to temperature evolution in a reactor, in a pipe, in an exchanger, in a turbine, are studied, and simulation techniques used by earlier authors are critically reviewed. 3. Pipe simulators: it is shown that this problem can be solved by the use of specialized simulators which will be described and analysed. 4. Rotating machine simulators: the particular aspect of rotating machine calculations introducing frequent use of diagrams is emphasized. A simulator requiring both digital and analogue methods is described. 5. The study of a nuclear power station: as an example it is proposed to discuss problems a rising in connection with the preceding elements (a, b, c, d) when simulating the behaviour of large nuclear plants. The part played by ordinary computing elements for the simulation of the different servomechanism transfer functions is considered and process of regulation is outlined. 6. Conclusion: the necessity of the use of high quality simulators and computers is underlined and the accuracy of the solutions is discussed. (author)Fren. [French] 1. Cinetique des reacteurs: la simulation des equations cinetiques d'un reacteur nucleaire ne pose desormais plus de probleme. II est donc possible de faire le point des differentes applications de la technique analogique dans ce domaine. 2. Les problemes thermodynamiques: on discute les differents problemes poses par l'evolution des temperatures dans un reacteur, dans une tuyauterie, dans un echangeur, dans une turbine, et on passe en revue les techniques de simulation proposees jusqu'a ce jour. 3s simulateurs de tuyauteries: on montre comment les differents problemes poses ci-dessus peuvent etre resolus, pour une classe tres vaste de reacteurs par l'emploi de simulateurs speciaux que l

  2. Contributions a l'etude et a l'application industrielle de la machine asynchrone

    Science.gov (United States)

    Ouhrouche, Mohand-Ameziane

    The work presented in this thesis, done in the Electrical Drives Laboratory of Electrical and Computer Engineering Department, deals with the industrial applications of a three-phase induction machine (electrical drives and electricity generation). This thesis, characterized by its multidisciplinary content, has two major parts. The first one deals with the on-line and off-line parametric identification of the induction machine model necessary to achieve accurate vector control strategy. The second part, which is a resume of a research work sponsored by Hydro-Quebec, deals with the application of an induction machine in Asynchronous Non Utility Generators units (ANUG). As it is shown in the following, major scientific contributions are made in both two parts. In the first part of our research work, we propose a new speed sensorless vector control strategy for an induction machine, which is adaptive to the rotor resistance variations. The proposed control strategy is based on the Extended Kalman Filter approach and a decoupling controller which takes into account the rotor resistance variations. The consideration of coupled electrical and mechanical modes leads to a fifth order nonlinear model of the induction machine. The load torque is taken as a function of the rotor angular speed. The Extended Kalman Filter, based on the process's nonlinear (bilinear) model, estimate simultaneously the rotor resistance, angular speed and the flux vector from the startup to the steady state equilibrium point. The machine-converter-control system is implemented in MATLAB/SIMULINK environment and the obtained results confirm the robustness of the proposed scheme. As in the electrical drives erea, the induction machine is now widely used by small to medium power Non Utility Generator units (NUG) to produce electricity. In Quebec, these NUGs units are integrated into the Hydro-Quebec 25 kV distribution system via transformer which exhibit nonlinear characteristics. We have shown by

  3. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J.P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete

  4. Application of the Moessbauer effect to the study of the structure of transition metal complexes; Applications de l'effet Mossbauer a l'etude de la structure des complexes des metaux de transition

    Energy Technology Data Exchange (ETDEWEB)

    Tsymbal, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    In this survey, the structural investigations of transition metal complexes by the hyperfine interactions in the Moessbauer effect are described. The isomer shift provides a unique tool for estimating s electrons covalency in high spin complexes and one of the best pieces of evidence for the importance of bacle donation in low spin complexes. The electric field gradient deriving from quadrupole coupling measurements is correlated with the energy levels distribution of d orbitals in high spin complexes, whereas in low spin complexes it originates from the unbalanced d electrons. (authors) [French] Dans cette etude, nous decrivons les applications des interactions hyperfines dans l' effet Mossbauer a l'etude de la structure des complexes des metaux de transition. Le deplacement isomerique donne des informations tres utiles sur la covalence des electrons s dans les complexes a spin eleve et met en evidence d'une maniere nette l'importance du phenomene de 'bacle donation' dans les complexes a spin faible. Le gradient de champ electrique qui provient des mesures d'interaction quadripolaire est lie a la distribution des niveaux d'energie des orbitales d dans les complexes a spin eleve alors que dans les complexes a spin faible, il est provoque par des electrons d non apparies. (auteurs)

  5. Experimental study of superconductivity induced by proximity effects; Etude experimentale de la supraconductivite induite par effets de proximite

    Energy Technology Data Exchange (ETDEWEB)

    Martinet, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-11-15

    We present a study of the proximity effects between a superconductor (InBi or PbBi alloys) and a 'normal' metal (Zn or Sn respectively, above their critical temperature) using essentially the tunneling techniques. On the N side, some specific properties of such an induced superconductivity are described: linear variation of the pair potential near the critical temperature of the binary layer, T{sub CNS}; reduced energy scale at T{sub CNS}; evidence of a thermodynamic critical field (called breakdown field) presented by N above its critical temperature. On the S side, we study crossing from a gapless to a quasi gapless regime. This gives a proof of a finite coherence length at T{sub CNS}. Experimental details (in particular about the preparation and measurement of tunneling junctions) are given in annexe. Possible applications are suggested. (author) [French] Nous presentons une etude experimentale des effets de proximite entre un supraconducteur (alliages d'InBi ou de PbBi) et un metal 'normal' (Zn ou Sn respectivement, pris au-dessus de leur temperature critique), en utilisant principalement des mesures d'effet tunnel. Du cote N, on met en evidence des proprietes specifiques de cette supraconductivite induite: comportement lineaire du potentiel de paires pres de la temperature critique du bilame, T{sub CNS}; echelle d'energie reduite a T{sub CNS}; apparition d'un champ critique thermodynamique (appele champ de basculement) dans N au-dessus de sa temperature critique. Du cote S, nous etudions le passage continu d'une situation 'sans bande interdite' a basse temperature et en champ fort, a une situation 'pratiquement sans bande interdite' pres de T{sub CNS} en champ nul. Ceci fournit une preuve de la non divergence de la longueur de coherence a T{sub CNS}. Les techniques experimentales (et en particulier la preparation et la mesure de jonctions tunnel) sont decrites en detail dans une annexe. On envisage des applications pratiques possibles. (auteur)

  6. Introduction à la thermodynamique cours et problèmes résolus

    CERN Document Server

    Lhuillier, Claire

    1994-01-01

    Si la thermodynamique fait appel à des concepts comme l'entropie, son étude renvoie souvent à des phénomènes courants (les changements d'état) ou encore à des technologies lourdes (les centrales thermiques). De ce fait, on la considère parfois comme une discipline difficile d'accès. Dans le cadre de leur enseignement de première année de premier cycle, Claire LHUILLIER et Jean ROUS ont rédigé un cours - appuyé de très nombreux exemples - dans lesquels ils introduisent avec clarté et rigueur toutes les notions de base : pression, température, énergie interne, premier principe, travail des forces de pression, chaleurs, etc. L'introduction de l'entropie est dissociée de celle du second principe : c'est une fonction d'état qui mesure l'information microscopique manquante. Le second principe est alors formulé comme un principe d'évolution, adapté à l'étude des phénomènes irréversibles. Les potentiels thermodynamiques ont été plus longuement traités dans cette nouvelle édition. Une f...

  7. Thermodynamique statistique résumés de cours et problèmes résolus

    CERN Document Server

    Chahine, C

    1976-01-01

    Le présent ouvrage est conçu pour une initiation à la thermodynamique statistique en présentant un très grand nombre d'applications sous forme de problèmes résolus, et en donnant des résumés de cours constitués de l'essentiel des résultats théoriques nécessaires pour traiter les applications chaque fois qu'est abordé un nouveau domaine. Partant d'un niveau élémentaire et rédigé de façon très progressive, ce livre qui se suffit à lui-même, permet de saisir l'aspect physique des phénomènes, et de faire le lien entre les statistiques élémentaires et les statistiques de Gibbs. Le lecteur pourra, soit résoudre effectivement les problèmes sans avoir recours à la solution et tirer alors tout le bénéfice d'une recherche personnelle, soit lire l'ensemble de l'énoncé et de la solution qui sont très détaillés, et forment ainsi un exposé très clair. L'ouvrage, qui développe principalement l'aspect physique des phénomènes, intéresse les étudiants en physique dès la 1ère année ...

  8. X-spectrographic method for plutonium detection. Application to contamination measurements in humans; Etude d'une methode de detection du plutonium par spectrographie X. Application a la mesure des contaminations sur l'homme

    Energy Technology Data Exchange (ETDEWEB)

    Trouble, Michel [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    After reviewing the radio-toxicology of plutonium 239 and conventional detection methods using its {alpha}-radiation, the author considers the measurement of the X emission spectrum of plutonium 239 using a proportional counter filled with argon under pressure. This preliminary work leads to the third part of this research involving the detailed study of the possibilities of applying thin alkali halide crystal scintillators to the detection of soft plutonium X-rays; there follows a systematic study of all the parameters liable to render the detection as sensitive as possible: movement due to the photomultiplier itself and its accessory electronic equipment, nature and size of the crystal scintillator as well as its mode of preparation, shielding against external parasitic radiation. Examples of some applications to the measurement of contamination in humans give an idea of the sensitivity of this method. (author) [French] Apres un apercu de la radiotoxicologie du plutonium 239 et des methodes classiques de detection par son rayonnement {alpha}, on etudie le spectre d'emission X du plutonium 239 avec un compteur proportionnel rempli avec de l'argon sous pression. Ce travail preliminaire permet d'aborder la troisieme partie de cette etude dans laquelle nous examinons d'une fagon approfondie les possibilites d'application des cristaux scintillateurs minces d'halogenure alcalin a la detection du rayonnement X mou du plutonium; suit une etude systematique de tous les parametres susceptibles de rendre la detection aussi sensible que possible: mouvement propre du photomultiplicateur et de l'electronique associee, nature et dimensions du cristal scintillateur ainsi que son mode de fabrication, blindage contre les rayonnements parasites exterieurs. Quelques applications a la mesure des contaminations sur l'homme permettent d'apprecier la sensibilite de cette methode. (auteur)

  9. Probes and their application to the study of H.F. plasmoids; Les sondes et leur application dans l'etude des plasmoides H.F

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, A; Geller, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In the first part of this paper, we study the single Langmuir probe and the double-probe method. In the second part, we describe the probe-technique in connection with R.F. plasmoids. (author) [French] Dans la premiere partie de cet article, nous rappelons les principes d'utilisation de la sonde simple de Langmuir ainsi que la methode de la sonde double. La seconde partie est consacree a la pratique des sondes dans l'etude des plasmoides H.F. (auteur)

  10. Applications of prospecting geochemical techniques to the search for and to the study of uranium deposits in metropolitan France; Applications des techniques geochimiques de prospection a la recherche et a l'etude des gites uraniferes en France metropolitaine

    Energy Technology Data Exchange (ETDEWEB)

    Grimbert, Arnold

    1957-07-01

    After having recalled facts which leaded the CEA to use new geochemical techniques for the prospecting of uranium deposits through sampling and analysis of soils and waters, the author describes the organisation and methods implemented for this prospecting activity: team composition for sampling and analysis, role of each engineer and technician in the prospecting stages (preliminary study, routine prospecting, result interpretation), sampling and analysis processes. He also reports campaigns of geochemical prospecting: study of the La Chapelle Largeau deposit (objectives, geological context, preliminary study, routine prospecting, study of geochemical anomalies), tactical research on Verneix indices (study of radioactivity anomaly discovered by radio-prospecting), strategical searches in a non prospected area in the South of Avallon. The author discusses the issues of efficiency and cost price of this geochemical prospecting technique in soils and in waters. Appendices present the equipment and operation modality for soil sampling, and for soil sample preparation, and principles, equipment and products for soil analysis and for water analysis [French] A la suite des resultats satisfaisants obtenus dans la recherche de methodes de dosage adaptees au cas de l'uranium, la Direction des Recherches Minieres du Commissariat a l'Energie atomique a decide, en decembre 1954, d'utiliser, conjointement avec les methodes classiques de prospection, les techniques geochimiques pour la recherche et l'etude des gites uraniferes. Ces applications pratiques ont ete confiees a une Section de Geochimie dont l'organisation, les moyens en personnel et en materiel, ainsi que les methodes de travail, font l'objet d'un expose detaille. Quelques exemples de prospection, en France metropolitaine, montrent la nature des problemes poses (etude d'un gisement connu, recherche tactique sur des indices, recherche strategique dans une region non prospectee), les methodes utilisees pour les

  11. Historique en grandes enjambées de la thermodynamique de l'équilibre

    Science.gov (United States)

    Hertz, J.

    2004-12-01

    La Thermodynamique, une science totalement nouvelle au XIXème siècle, a germé en France en contrepoint des idées du siècle des Lumières, dans le milieu particulier des anciens élèves de l’Ecole Polytechnique, officiers supérieurs formés pour l’armée républicaine ou napoléonienne, mais qui ne trouvaient plus leur place dans l’armée de la Restauration. Ils se convertissaient en ingénieurs civils des métiers industriels en pleine expansion, comme le développement de la machine à vapeur ou des chemins de fer. La plupart d’entre eux, plutôt libre-penseurs, adhéraient aux idées scientistes du « positivisme », véhiculées dans les Loges de la Franc-Maçonnerie du Grand Orient de France et plus particulièrement dans les cercles Saint-Simoniens, premiers adeptes du socialisme industriel. C’est ainsi que naquit en 1824, dans le cerveau subtil mais brouillon de Sadi Carnot toute la vision illuminée de cette science nouvelle, incompréhensible pour ses contemporains. Elle ressuscita en 1834 sous la plume d’un Emile Clapeyron qui avait pris conscience de l’immensité de l’œuvre de Sadi Carnot. Mais le rappel de Clapeyron demeura également sans écho pendant dix années. Le réveil de la Thermodynamique se fera désormais hors de France par des hommes de grande pratique religieuse et généralement protestants. C’est ainsi que William Thomson en Ecosse et Rudolph Clausius, venu de Prusse, achevèrent l’œuvre de leurs deux prédécesseurs et que la Thermodynamique mécano-thermique fut définitivement établie en 1864. La thermodynamique chimique peut être attribuée à un seul génie mathématicien, Josiah Willard Gibbs qui travaillait tout seul au Yale College de New-Haven, dans le Connecticut, et rédigea sa nouvelle théorie entre 1875 et 1878. Enfin l’interprétation statistique du second principe sera l’œuvre en 1877 d’un Autrichien, Ludwig Boltzmann, homme génial mais fragile qui eut le temps d’insuffler ses id

  12. New methods of thermodynamics; Nouvelles methodes en thermodynamique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This day, organized by the SFT French Society of Thermology, took stock on the new methods in the domain of the thermodynamics. Eight papers have been presented during this day: new developments of the thermodynamics in finite time; the optimal efficiency of energy converters; a version of non-equilibrium thermodynamics with entropy and information as positive and negative thermal change; the role of thermodynamics in process integration; application of the thermodynamics to critical nuclear accidents; the entropic analysis help in the case of charge and discharge state of an energy storage process; fluid flow threw a stable state in the urban hydraulic; a computer code for phase diagram prediction. (A.L.B.)

  13. Study and industrial applications of the external slowing-down {beta}{sup -} radiation of the yttrium - 90; Etude et applications industrielles du rayonnement de freinage externe des {beta}{sup -} de l'yttrium - 90

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P; Martinelli, P; Chauvin, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    Inelastic scattering of the {beta}{sup -} particles on the nucleus gives place to the emission of a X-ray Bremsstrahlung radiation. In view of possible industrial applications, we studied the slowing-down radiation of {sup 90}(Sr + Y) sources in various materials. This pure {beta}{sup -} emitter of long period is in the fission products of uranium. Among of the industrial applications, these sources of weak X-rays energy can be used for the radiography of thin pieces, for measuring the thickness, or for the analysis by fluorescence. (M.B.) [French] La diffusion inelastique des particules {beta}{sup -} sur les noyaux donne lieu a l'emission d'un rayonnement X de freinage. En vue de possibles applications industrielles, nous avons etudie le rayonnement de freinage des sources {sup 90}(Sr + Y) dans divers materiaux. Cet emetteur {beta}{sup -} pur a longue periode se trouve dans les produits de fission de l'uranium. Parmi les applications industrielles a l'etude, ces sources de rayons X de faible energie peuvent etre utilisees pour la radiographie de pieces minces, la mesure d'epaisseurs, ou encore pour l'analyse par fluorescence. (M.B.)

  14. Contribution to the study of the thermodynamic properties of solutions using their phase diagrams (1961); Contribution au calcul des proprietes thermodynamiques des solutions a partir des diagrammes de phases (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Hagege, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-10-15

    The thermodynamic study of the behaviour of solutions is of great interest in applied metallurgical problems, since the use of physical phenomena (solubility or volatility, for example) makes it possible to effect chemical reactions which, would not take place if the products formed did not mix. It is interesting to be able to predict this behaviour, at least for binary systems, using a knowledge of the phase diagrams. After showing the theoretical impossibility of resolving this problem without further data, an attempt is made to show what can be calculated from a knowledge of the phase diagrams: on the one hand it is possible to study the coherence between different types of data (calorimetric or equilibrium); on the other hand can be calculated the 'model' parameters, whether they be empirical, or statistically derived, and their validity can be checked. (author) [French] L'etude thermodynamique du comportement des solutions presente un grand interet dans les problemes de metallurgie appliquee puisque l'emploi de phenomenes physiques (solubilite ou volatilisation par exemple) permet de realiser des reactions chimiques qui seraient irrealisables si les produits formes ne se melangeaient pas. Il semble tres interessant de pouvoir prevoir ce comportement, tout au moins dans le cas de systemes binaires, a partir de la connaissance des diagrammes de phases. Apres avoir montre l'impossibilite theorique de resoudre ce probleme sans autres donnees, on essaie de voir ce que permet de calculer la connaissance des diagrammes de phases: d'une part, on peut etudier la coherenc entre divers types de donnees (calorimetrique ou d'equilibre); d'autre-part, on peut calculer les parametres de 'modeles', qu'ils soient empiriques ou a base statistique, et verifier leur validite. (auteur)

  15. Thermodynamic Aspects of Supercritical Fluids Processing: Applications of Polymers and Wastes Treatment Aspects thermodynamiques des procédés mettant en oeuvre des fluides supercritiques : applications aux traitements des polymères et des déchets

    Directory of Open Access Journals (Sweden)

    Beslin P.

    2006-11-01

    Full Text Available Supercritical fluid processes are of increasing interest for many fields : in supercritical fluid separation (petroleum-chemistry separation and purification, food industry and supercritical fluid chromatography (analytical and preparative separation, determination of physicochemical properties; as reaction media with continuously adjustable properties from gas to liquid (low-density polyethylene, waste destruction, polymer recycling; in geology and mineralogy (volcanoes, geothermal energy, hydrothermal synthesis; in particle, fibber and substrate formations (pharmaceuticals, explosives, coatings; in drying materials (gels. This paper presents the unusual physicochemical properties of supercritical fluids in relation to their engineering applications. After a short report of fundamental concepts of critical behavior in pure fluids, we develop in more details the tunable physicochemical properties of fluid in the supercritical domain. The second part of this paper describes the engineering applications of supercritical fluids relevant of chemical reactions and polymer processing. Each application presentation is divided in two parts : the first one recalls the basic concepts including general background, physicochemical properties and the second one develops the engineering applications relevant of the advocated domain. La mise en Suvre des fluides supercritiques est d'un intérêt croissant dans de nombreux domaines : pour la séparation (séparation et purification en pétrochimie, industrie alimentaire et la chromatographie par fluides supercritiques (séparation analytique et préparatoire, détermination des propriétés physicochimiques, comme milieux réactifs aux propriétés continûment ajustables allant du gaz au liquide (polyéthylène de faible densité, élimination des déchets, recyclage des polymères, en géologie et en minéralogie (volcanologie, énergie géothermique, synthèse hydrothermique, dans la formation des particules

  16. ETUDE DE LA DISTRIBUTION DES CATIONS ECHANGEABLES

    African Journals Online (AJOL)

    SEI Joseph

    : entropie (J/mol/K); v: volume molaire (cm3). Pour les diagrammes en potentiels chimiques, nous n'avons besoin que de l'enthalpie libre de référence. La validité de la base des données thermodynamiques est primordiale pour pouvoir ...

  17. Application of mathematical methods to the investigation of uranium deposits; Application des methodes mathematiques a l'etude des gisements d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Formery, P; Ziegler, V [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    It may be considered approximately that grades, widths and accumulations (grade-width products), in french uranium deposits are distributed according to a lognormal law. This property associated to KRIGE'S and de WIGE'S formulae make a powerful tool in ore deposits surveys. The correlation between radioactivities and grades is realized, in logarithmic coordinates, through a straight line the properties of which are analysed in the paper. MATHERON'S recent works, in association with data of classical statistics and the above mentioned formulae make possible to complete the ore reserves evaluation by computing the accuracy. Statistical methods applied to ore deposits have given birth to a parameter which is as important as the mean grade for characterisation of deposits: the absolute dispersion. (author) [French] On peut considerer en premiere approximation que les teneurs, les puissances et les accumulations se distribuent dans les gisements fran is d'uranium suivant une loi log normale. Cette propriete, associee aux hypotheses de De WIGE et de KRIGE, constitue un puissant instrument d'etude des gisements. La correspondance des radioactivites et des teneurs s'effectue, en coordonnees bilogarithmiques, par une droite dont on etudie les proprietes. Grace aux travaux recents de MATHERON, associes aux donnees de la statistique classique ainsi qu'aux hypotheses enumerees plus haut, il est possible de completer le calcul des reserves d'un gisement par une evaluation de l'erreur commise. Les methodes statistiques ont fait apparaitre un parametre aussi important pour caracteriser un gisement, que la teneur moyenne: la dispersion absolue. (auteur)

  18. Elaboration du Ge mesoporeux et etude de ses proprietes physico-chimiques en vue d'applications photovoltaiques

    Science.gov (United States)

    Tutashkonko, Sergii

    Le sujet de cette these porte sur l'elaboration du nouveau nanomateriau par la gravure electrochimique bipolaire (BEE) --- le Ge mesoporeux et sur l'analyse de ses proprietes physico-chimiques en vue de son utilisation dans des applications photovoltaiques. La formation du Ge mesoporeux par gravure electrochimique a ete precedemment rapportee dans la litterature. Cependant, le verrou technologique important des procedes de fabrication existants consistait a obtenir des couches epaisses (superieure a 500 nm) du Ge mesoporeux a la morphologie parfaitement controlee. En effet, la caracterisation physico-chimique des couches minces est beaucoup plus compliquee et le nombre de leurs applications possibles est fortement limite. Nous avons developpe un modele electrochimique qui decrit les mecanismes principaux de formation des pores ce qui nous a permis de realiser des structures epaisses du Ge mesoporeux (jusqu'au 10 mum) ayant la porosite ajustable dans une large gamme de 15% a 60%. En plus, la formation des nanostructures poreuses aux morphologies variables et bien controlees est desormais devenue possible. Enfin, la maitrise de tous ces parametres a ouvert la voie extremement prometteuse vers la realisation des structures poreuses a multi-couches a base de Ge pour des nombreuses applications innovantes et multidisciplinaires grace a la flexibilite technologique actuelle atteinte. En particulier, dans le cadre de cette these, les couches du Ge mesoporeux ont ete optimisees dans le but de realiser le procede de transfert de couches minces d'une cellule solaire a triple jonctions via une couche sacrificielle en Ge poreux. Mots-cles : Germanium meso-poreux, Gravure electrochimique bipolaire, Electrochimie des semi-conducteurs, Report des couches minces, Cellule photovoltaique

  19. Application of general methods for the study of porous materials to the determination of the characteristics of barriers; Application des methodes generales d'etudes des corps poreux a la determination des caracteristiques des barrieres

    Energy Technology Data Exchange (ETDEWEB)

    Plurien, P; Charpin, J; Mommejac, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Barriers foreseen for the separation of uranium isotopes by gaseous diffusion must posses pores of about 100 Angstrom radius and as high an output as possible. They should thus be of small but uniform thickness. In view of these conditions it is necessary to adapt the normal methods available for studying porous materials in order to check the characteristics of the prototypes examined. It has been found that only by cross-comparison of data from various methods can progress in the development of different prototypes be followed. The following account consists of two parts: 1) A review of the main experimental methods we have used: a) various absorption methods, b) electron microscopy, c) X-ray studies, d) mercury porosimetry, e) liquid permeability, f) gas permeability, g) measurement of separation efficiency. 2) Comparison of the results obtained using these various methods and their application with a view to acquiring as complete a knowledge as possible of the structure of the barrier. (author) [French] Les barrieres susceptibles d'etre utilisees pour la separation des isotopes de l'uranium, par diffusion gazeuse, doivent presenter des pores de rayon de l'ordre de 100 Angstrom et un debit aussi grand que possible. Elles doivent donc avoir une epaisseur faible et constante. Ces conditions necessitent une adaptation des methodes usuelles d'etude des corps poreux pour controler les caracteristiques des prototypes etudies. Il est apparu que seul le recoupement entre diverses methodes permet de suivre les progres dans la realisation de differents prototypes. L'expose qui va suivre comprend deux parties: 1) Une revue des principales methodes experimentales que nous utilisons: a) differentes methodes d'absorption, b) microscopie electronique, c) rayons X, d) porosimetrie a mercure, e) permeabilite aux liquides, f) permeabilite aux gaz, g) mesure de l'efficacite de separation. 2) Comparaison des differents resultats obtenus par ces diverses methodes et leur application

  20. Etude fondamentale des mecanismes de gravure par plasma de materiaux de pointe: Application a la fabrication de dispositifs photoniques

    Science.gov (United States)

    Stafford, Luc

    Advances in electronics and photonics critically depend upon plasma-based materials processing either for transferring small lithographic patterns into underlying materials (plasma etching) or for the growth of high-quality films. This thesis deals with the etching mechanisms of materials using high-density plasmas. The general objective of this work is to provide an original framework for the plasma-material interaction involved in the etching of advanced materials by putting the emphasis on complex oxides such as SrTiO3, (Ba,Sr)TiO 3 and SrBi2Ta2O9 films. Based on a synthesis of the descriptions proposed by different authors to explain the etching characteristics of simple materials in noble and halogenated plasma mixtures, we propose comprehensive rate models for physical and chemical plasma etching processes. These models have been successfully validated using experimental data published in literature for Si, Pt, W, SiO2 and ZnO. As an example, we have been able to adequately describe the simultaneous dependence of the etch rate on ion and reactive neutral fluxes and on the ion energy. From an exhaustive experimental investigation of the plasma and etching properties, we have also demonstrated that the validity of the proposed models can be extended to complex oxides such as SrTiO3, (Ba,Sr)TiO 3 and SrBi2Ta2O9 films. We also reported for the first time physical aspects involved in plasma etching such as the influence of the film microstructural properties on the sputter-etch rate and the influence of the positive ion composition on the ion-assisted desorption dynamics. Finally, we have used our deep investigation of the etching mechanisms of STO films and the resulting excellent control of the etch rate to fabricate a ridge waveguide for photonic device applications. Keywords: plasma etching, sputtering, adsorption and desorption dynamics, high-density plasmas, plasma diagnostics, advanced materials, photonic applications.

  1. Chrono-potentiometry in molten chlorides. Application to the study of the electrochemical properties of uranium and plutonium in the LiCl-KCl eutectic; Chronopotentiometrie dans les chlorures fondus. Application a l'etude des proprietes electrochimiques de l'uranium et du plutonium dans l'eutectique LiCl-KCl

    Energy Technology Data Exchange (ETDEWEB)

    Leseur, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-05-01

    Using solutions of cadmium chloride in the eutectic LiCl-KCl, a chrono-potentiometric method has been developed with a view to its application to the study of molten solutions. Particular attention has been paid to the choice of the indicator electrodes. The method makes it possible to analyze molten solutions quantitatively and to determine diffusion coefficients and their activation energies; it yields furthermore information about the nature and the behaviour of ionic species in solution. The method has been applied to the study of solutions of uranium and plutonium chloride in the eutectic LiCl-KCl. Linear chrono-amperometry has been used for studying these solutions quantitatively, but chrono-potentiometry, of which the theory is better developed, is better suited to a quantitative study. The results obtained have made it possible to determine the diffusion coefficients of the ions Cd{sup 2+}, U{sup 3+}, U{sup 4+} and U(IV) in the presence of F{sup -} and Pu{sup 3+} ions, as well as the activation energy of the diffusion coefficients. (author) [French] La mise au point de la chronopotentiometrie comme moyen d'etude des solutions fondues a ete effectuee avec des solutions de chlorure de cadmium dans l'eutectique LiCl-KCl. Le probleme du choix des electrodes indicatrices a ete particulierement etudie. La methode permet l'analyse quantitative des solutions fondues ainsi que la determination des coefficients de diffusion et de leurs energies d'activation: elle donne en outre des renseignements sur la nature et le comportement des especes ioniques en solution. Elle a ete appliquee a l'etude des solutions des chlorures d'uranium et de plutonium dans l'eutectique LiCl-KCl. La chronoamperometrie lineaire a ete utilisee pour l'etude qualitative de ces solutions, mais la chronopotentiometrie, dont la theorie est plus complete, convient mieux pour l'etude quantitative. Les resultats obtenus ont permis de determiner les

  2. Corrosion in the presence of a complexing agent - application to the continuous determination of hydrofluoric acid in the atmosphere; Corrosion en presence de complexant. - Application a la determination en continu de l'acide fluorhydrique dans l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Chapron, J [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1966-10-01

    After a presentation of the thermodynamics and kinetics involved during corrosion in the presence of a complexing agent, the first part of this report deals with the electrochemical properties of an aluminium electrode in the presence of fluoride solutions. Various physical and chemical parameters have been studied together with their influence on the aforementioned properties. From this first part are deduced the medium and the various parameters which lead to the maximum efficiency for the detection of fluorides by amperometry. The second part is an application of the results of the above work, which has made it possible to develop a cell having an original design. Its performances are described. They show that the cell has a greater sensitivity and a shorter response time than existing equipment. (author) [French] Apres un rappel sur la thermodynamique et la cinetique de la corrosion en presence de complexant, la premiere partie du memoire est consacree a l'etude des proprietes electrochimiques de l'electrode d'aluminium, en presence de solutions de fluorure. Differents parametres physiques et chimiques ont ete etudies ainsi que leurs influences sur les dites proprietes. De cette premiere partie on en a deduit le milieu et les divers parametres a fixer de facon a obtenir un rendement optimum au vue de la detection des fluorures par amperometrie. La deuxieme partie, qui est l'application des renseignements tires du travail deja cite, a permis de mettre au point une cellule de conception nouvelle. Ses performances sont decrites. Elles indiquent une sensibilite plus grande, un temps de reponse plus court que les appareils existants. (auteur)

  3. Contribution to the experimental survey of the nuclear isomerism. Application of the deferred coincidences method to research and to the survey of metastable states of short period; Contribution a l'etude experimentale de l'isomerie nucleaire. Application de la methode des coincidences differees a la recherche et a l'etude d'etats metastables de periode courte

    Energy Technology Data Exchange (ETDEWEB)

    Ballini, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1953-06-15

    transitions qu'ils subissent, lorsqu'elles donnent naissance a des especes nucleaires mieux connues: parmi ces transitions figurent les transitions isomeriques. Le but de ce travail est l'etude des transitions isomeriques a partir d'etats metastables de periode courte, comprise dans le domaine de la microseconde a quelques millisecondes. La methode des coincidences differees a ete mise au point et appliquee dans ce but en utilisant les avantages des selecteurs a plusieurs canaux, sous deux aspects principaux ou l'appareil a plusieurs canaux etait soit un selecteur de temps, soit un selecteur d'amplitudes. Cette methode a servi a etudier le fonctionnement de compteurs Geiger-Muller et a mesurer avec precision la periode de {sup 181}Ta{sup *} dans des conditions experimentales variees. La valeur adoptee est 17,2 {+-} 0,2 {mu}s. Ce travail a aussi trouve une application pratique immediate a la mise en evidence de quantites tres faibles de hafnium dans le zirconium, dont il constitue une impurete tenace et difficile a analyser par les moyens ordinaires. (M.B.)

  4. Neutron Activation for Studying Hydroelectrolytic Disorders in Child Pathology; Application de l'Activation Neutronique a l'Etude des Troubles Hydroelectrolytiques en Pathologie Infantile

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, J. [Hopital Universitaire St-Pierre, Bruxelles (Belgium); Colard, J. [Centre d' Etude de l' Energie Nucleaire, Mol (Belgium); Vis, H. L. [Institut pour la Recherche Scientifique en Afrique Centrale, Bukavu (Congo, The Democratic Republic of the)

    1967-10-15

    The authors describe a method of determining electrolytes (Na, K, CI) and phosphorus in small fragments of muscle taken from child patients by needle biopsy. This method has been used to study muscular disturbances in hydroelectrolytic illnesses of childhood, whether acute, such as dehydration or toxicosis in infants, or chronic, such as malnutrition or marasmus. The results are discussed in the light of parallel data obtained by other methods of investigation. The authors also discuss the possibility of using this method to estimate intra-cellular hydroelectrolytic disorders in child pathology. (author) [French] Les auteurs presentent la description d'une methode permettant le dosage des electrolytes (Na, K, Cl) et du phosphore sur de petits fragments musculaires preleves par ponction-biopsie chez l'enfant. Cette methode a ete appliquee a l'etude des perturbations du milieu musculaire dans des troubles hydroelectrolytiques aigus (deshydratation et toxicose des nourrissons) et chroniques (malnutrition et denutrition) de l'enfance. Les resultats obtenus sont discutes a la lumiere de donnees recueillies parallelement par d'autres methodes d'investigation. Les auteurs discutent egalement la possibilite d'estimer par cette methode les perturbations hydroelectrolytiques intra-cellulaires en pathologie pediatrique. (author)

  5. Etude Cinétique et thermodynamique de l’adsorption de méthyle orange sur deux biomasses aquatiques : Crabes et Coquilles.

    Directory of Open Access Journals (Sweden)

    Yasser HERMOUCH

    2016-06-01

    Full Text Available Kinetic and thermodynamic study of adsorption of methyl orange on two aquatic biomass: Crabs and Shells. Description of the subject. This article examines the use of biosorbents prepared from two aquatic animal biomass for purifying water contaminated with methyl orange. Objectives. Contaminated water with methyl orange is taken as a sample for studying the effect of various experimental parameters such as contact time, temperature, the initial concentration of dye and the dose of adsorbent.Results. The results show that as the amount of adsorbent increases, the adsorption of methyl orange decreases while it increases with increasing the concentration of the initial dye. The adsorption kinetics follows the pseudo-second-order model (R2> 0.99. The thermodynamic parameters were calculated. They proved that the adsorption process is spontaneous and endothermic. Conclusions.Biomass made from two aquatic animal biomass can be used as adsorbents for the removal of methyl orange and opens prospects for their recovery with other pollutants.

  6. Thermodynamic study of sulphur hemi-oxide using mass spectrometry (1963); Etude thermodynamique de l'hemioxyde de soufre par spectrometry de masse (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Hagemann, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-01-15

    The action of oxygen on sulphur, at low pressures, in a high frequency discharge has been studied by continuous mass-spectrometric analysis of the reaction products. The mass spectra of the gases produced by the discharge correspond to a mixture of SO{sub 2}, S{sub 2}O, S{sub 2} and O{sub 2}. We have measured up to 75 per cent of SO{sub 2} in the SO{sub 2} + S{sub 2}O mixture. We have concluded that the molecules S{sub 2}O{sub 2}, and SO are not present in the mixture. The ionisation potentials of the molecules and the potential required for the appearance of ion fragments in the gas discharge mixture have been studied by mass spectrometry. The heat of formation of S{sub 2}O has been estimated using the appearance potentials of the SO{sup +} ions coming from SO{sub 2}, and S{sub 2}O. ( 18.5 kcal/mole < {delta}H, (S{sub 2}O{sub g}) < 7 kcal/mole). We have measured the ionisation potentials of the molecules S{sub 2}, S{sub 4}, S{sub 6} and S{sub 8} which are respectively as follows: 9.7 {+-} 0.1 eV; 10.4 {+-} 0.5 eV; 8.5 {+-} 0.3 eV et 7.3 {+-} 0.3 eV. Finally we have studied the equilibrium for the formation of S{sub 2}O from sulphur and SO{sub 2} in a hot filament reactor. The measurement of the variation, between 1100 deg K and 1500 deg K, of the equilibrium constant for the reaction: SO{sub 2} + 3/2 S{sub 2} {r_reversible} 2 S{sub 2}O has made it possible to determine the enthalpy change of this reaction. ({delta}H = 5310 {+-} 370 cals) The sum of the states of the S{sub 2}O molecule, Z{sup 0}, has been calculated from the literature data. By applying to the S{sub 2}O formation equilibrium the equation: Log K{sub p} = {delta}Log Z{sup 0}/N - {delta}H{sup 0}{sub 0}/RT it has been possible to calculate the enthalpy of the reaction at absolute zero ({delta}H{sup 0}{sub 0} 4780 {+-} 60 cal/mole). Taking into account the specific heat integral between 0 deg K and 1300 deg K, the values obtained by this method and by using Van't Hoff's law are in good agreement. We have also examined the work concerning the heat of formation of SO to discover whether the formation of SO is possible between 1000 deg K and 1500 deg K starting from sulphur and SO{sub 2}. (author) [French] L'action de l'oxygene sur le soufre, a basse pression, dons une decharge haute frequence, a ete etudiee en analysant en continu, les produits de la reaction par spectrometrie de masse. Les spectres de masse du gaz issu de la decharge correspondent a un melange SO{sub 2}, S{sub 2}O, S{sub 2} et O{sub 2}. Nous avons mesure jusqu'a 75 pour rent de SO{sub 2} dans le melange SO{sub 2} + S{sub 2}O. Nous avons conclu a l'absence des molecules S{sub 2}O{sub 2}, et SO dans le melange. Les potentiels d'ionisation des molecules, et d'apparition des ions fragments du melange issu de la decharge, ont ete etudies par spectrometrie de masse. La chaleur de formation de S{sub 2}O a ete estimee a partir des mesures des potentiels d'apparition des ions SO{sup +} provenant de SO{sub 2}, et S{sub 2}O. (- 18.5 kcal/mole - < {delta}H, (S{sub 2}O{sub g}) < - 7 kcal/mole). Nous avons ete amenes a mesurer les potentiels d'ionisation des molecules S{sub 2}, S{sub 4}, S{sub 6} et S{sub 8} dont les valeurs sont respectivement: 9,7 {+-} 0,1 eV; 10,4 {+-} 0,5 eV; 8,5 {+-} 0,3 eV et 7,3 {+-} 0,3 eV. Nous avons enfin etudie l'equilibre de formation de StO a partir de soufre et de S{sub 2}O, dans un reacteur a filaments chauds. La mesure de la variation, entre 1100 deg K et 1500 deg K. de h constante d'equilibre de la reaction: SO{sub 2} + 3/2 S{sub 2} {r_reversible} 2 S{sub 2}O a permis de determiner la variation d'enthalpie de cette reaction ({delta}H = 5310 {+-} 370 calories) La somme d'etats de la molecule S{sub 2}O, Z{sup 0}, a ete calculee a partir des donnees bibliographiques. En appliquant a l'equilibre de formation de S{sub 2}O l'equation: Log K{sub p} = {delta}Log Z{sup 0}/N - {delta}H{sup 0}{sub 0}/RT nous avons calcule l'enthalpie de ia reaction au zero absolu ({delta}H{sup 0}{sub 0} = 4780 {+-} 60 cal/mole). Compte tenu de l'integrale des chaleurs specifiques entre 0 deg K et 1300 deg K. les valeurs obtenues par cette methode et par la loi de Van't Hoff concordent. Nous avons egalement examine les travaux concernant la chaleur de formation de SO, pour savoir si la formation de SO est possible entre 1000 deg K et 1500 deg K a partir de soufre et de SO{sub 2}. (auteur)

  7. Lanthanides in geological fluids: experimental study of standard thermodynamic properties and of solubilities; Les lanthanides dans les fluides geologiques: etude experimentale des proprietes thermodynamiques standard et des solubilites

    Energy Technology Data Exchange (ETDEWEB)

    Pourtier, E

    2006-11-15

    Standard thermodynamic properties (STP) of lanthanides (Ln{sup 3+}) are necessary to predict their transport in hydrothermal fluids. New STP (apparent molal volumes and heat capacities) of Ln{sup 3+} are determined with dilute (La{sup 3+}, Nd{sup 3+}, Gd{sup 3+}, Yb{sup 3+}) triflates solutions, up to 300 deg. C and 300 bars, using a vibrating tube flow densimeter and a differential heat flow calorimeter. The triflate anion (CF{sub 3}SO{sub 3}), stable at high temperature, does not form complexes with Ln{sup 3+}. The STP of HCF{sub 3}SO{sub 3} and NaCF{sub 3}SO{sub 3} are measured in order to get the STP of CF{sub 3}SO{sub 3}. The solubility of the Nd-pure pole of monazite (NdPO{sub 4}) studied between 300 and 800 deg. C at 2 kbars in H{sub 2}O and H{sub 2}O+NaCl using weight loss and isotope dilution methods, is prograde for neutral pH. The study of Nd{sup 3+} speciation at 650 deg. C and 300 deg. C, 2 kbars, shows that only hydroxylated species are present. These data allow the revision of Ln{sup 3+} parameters in the HKF model. (author)

  8. Application of radioisotopes to studies of crystal imperfections; Application des radioisotopes a l'etude des imperfections des cristaux; Primenenie radioizotopov dlya izucheniya defektov v kristallakh; Aplicaciones de los radioisotopos al estudio de las imperfecciones cristalinas

    Energy Technology Data Exchange (ETDEWEB)

    Sproull, R L; Slack, G A; Moss, M; Pohl, R O; Krumhansl, J A [Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY (United States)

    1962-01-15

    Radioisotopes have been used in two important ways in studying imperfections in alkali halide crystals. The zone refining of the compounds has been monitored by addition of tracers, and segregation coefficients have been determined from such measurements. The other application has been to insert small concentrations of impurity ions into alkali halides in order to study the phonon scattering by such impurities or by the vacancies they introduce; these measurements are carried out at very low temperatures where the phonon mean free path is limited by lattice imperfections. The most commonly used radioisotope in this work has been Ca{sup 45}. This work is reviewed and some current and possible future applications of radioisotopes in this field are mentioned. (author) [French] Les radioisotopes ont recu deux applications importantes dans l'etude des imperfections des cristaux d'halogenures alcalins. Employes comme indicateurs, ils ont permis de controler le raffinage par zones des composes et, par suite, de determiner les coefficients de segregation. La deuxieme application a consiste a introduire dans les halogenures alcalins de faibles concentrations d'ions sous forme d'impuretes afin d'etudier la diffusion des phonons par ces impuretes ou par les lacunes que celles-ci produisent; les mesures sont effectuees a des temperatures tres basses, auxquelles le libre parcours moyen des phonons se trouve limite par les imperfections du reseau. Le radioisotope le plus frequemment employe pour ces operations a ete le {sup 45}Ca. Le memoire passe en revue ces divers travaux et signale quelques applications effectives ou possibles des radioisotopes dans le domaine considere. (author) [Spanish] Los autores han empleado radioisotopos en dos importantes campos del estudio de los cristales de haluros alcalinos. Uno de estos campos es el control de la purificacion por zonas de los compuestos y la determinacion de los coeficientes de segregacion por medida de las actividades de los

  9. The application of radioactive isotopes to the study of motion of silt and pebbles in the rivers and in the sea; Application des isotopes radioactifs a l'etude des mouvements des sediments et des galets dans les cours d'eau et en mer

    Energy Technology Data Exchange (ETDEWEB)

    Hours, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P [Electricite de France (EDF), 78 - Chatou (France). Lab. National d' Hydraulique

    1959-07-01

    The application of radioactive tracers to the study of sediments drift has received considerable attention since 1954 in various countries. A comparative review is made of a number of techniques of labelling, immersing and detecting silts, sands, and pebbles. The influence of the burying of the active material is emphasized. The different experiments which have been so far carried out are described. (author) [French] L'application des traceurs radioactifs a l'etude des deplacements de sediments a fait depuis 1954 l'objet de travaux nombreux dans divers pays. On passe en revue et on compare differentes techniques de marquage, d'immersion et de detection des vases, sables et galets; on insiste sur l'influence de l'enfouissement du materiau actif. On decrit les differentes experiences effectuees jusqu'a ce jour. (auteur)

  10. Corrosion in the presence of a complexing agent - application to the continuous determination of hydrofluoric acid in the atmosphere; Corrosion en presence de complexant. - Application a la determination en continu de l'acide fluorhydrique dans l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Chapron, J. [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1966-10-01

    After a presentation of the thermodynamics and kinetics involved during corrosion in the presence of a complexing agent, the first part of this report deals with the electrochemical properties of an aluminium electrode in the presence of fluoride solutions. Various physical and chemical parameters have been studied together with their influence on the aforementioned properties. From this first part are deduced the medium and the various parameters which lead to the maximum efficiency for the detection of fluorides by amperometry. The second part is an application of the results of the above work, which has made it possible to develop a cell having an original design. Its performances are described. They show that the cell has a greater sensitivity and a shorter response time than existing equipment. (author) [French] Apres un rappel sur la thermodynamique et la cinetique de la corrosion en presence de complexant, la premiere partie du memoire est consacree a l'etude des proprietes electrochimiques de l'electrode d'aluminium, en presence de solutions de fluorure. Differents parametres physiques et chimiques ont ete etudies ainsi que leurs influences sur les dites proprietes. De cette premiere partie on en a deduit le milieu et les divers parametres a fixer de facon a obtenir un rendement optimum au vue de la detection des fluorures par amperometrie. La deuxieme partie, qui est l'application des renseignements tires du travail deja cite, a permis de mettre au point une cellule de conception nouvelle. Ses performances sont decrites. Elles indiquent une sensibilite plus grande, un temps de reponse plus court que les appareils existants. (auteur)

  11. Mathematical study of chemical kinetics schemes. Application to air pollution models; Etude mathematique de schemas de cinetique chimique. Application a des modeles de pollution atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Billette, E.

    1997-06-23

    Complex chemical kinetics modelling is relevant in numerous fields related to the petroleum industry, for instance engine combustion, petrochemistry and atmospheric pollution. Many numerical difficulties are encountered in the computation of these models, mainly due to the large size, the non-linearity and the stiffness of the associated ordinary differential systems. We first studied systems that have an asymptotic behaviour which may be derived from an algebraic analysis. Then we reviewed different methods that make possible the reduction of size and stiffness for chemical kinetics-related differential systems, and suggest possible improvements for some of those methods. We also studied their application to atmospheric chemistry models. Finally, we started to extend those reduction methods to partial differential systems that include, in addition to chemical kinetics, other phenomena such as species emission, advection or diffusion. (author) 44 refs.

  12. Physical study of the 'snow flake' version of the reactor EL-3 (1963); Etude physique de la version ''cristal de neige'' de la pile EL-3 (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Abillon, E; Genthon, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    A systematic study has been made of the different thermodynamic and neutronic aspects of various versions of the 'snow flake' likely to fulfil the aims which were set out (improvement of the reactivity, of the experimental volume, improvement in the working conditions of EL-3). After this systematic study, a choice was made in principle of one version amongst the several available (solutions using 8 or 10 pencils-various methods of heat transfer: corrugation, cartridges which may or may not be filled with helium... etc., variable enrichments... ). The choice is that of a version which can already at the present be considered as feasible, which represents already a notable improvement of the pile and which does not imply the existence of a major problem as far as the possible change-over later to an improved version is concerned. This choice defines a fuel element and a configuration for the core. A detailed recapitulation has been made of all the research being carried out for the possible solutions in this particular case. (authors) [French] On a etudie systematiquement les differents aspects thermodynamiques et neutroniques de diverses versions 'cristal de neige' susceptibles de remplir les buts fixes (amelioration en reactivite, en volume experimental, amelioration des problemes d'exploitation de EL-3). Apres cette etude systematique, on a procede au choix de principe d'une version parmi les differentes solutions possibles (solutions a 8 ou 10 crayons - possibilite de transfert de chaleur divers: corrugations, cartouches remplies He ou non.... etc., enrichissements variables... ). Ce choix est celui d'une version qu'on peut juger viable des aujourd'hui, qui represente deja une amelioration importante de la pile et qui n'implique pas de probleme majeur quant au passage ulterieur et eventuel a une version plus amelioree. Ce choix definit un element combustible, et une configuration de coeur. On a recapitule et detaille sur ce cas particulier de pile les etudes

  13. A spectrometer using semi-conductor detectors; study and applications (1963); Spectrometre utilisant les detecteurs a semi-conducteur: etudes et applications (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Roux, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    The low average energy, 2.5 to 3.5 eV, required to produce one hole-electron pair in a semiconductor allows an accurate measurement of the energy of the ionizing particles. A high resolution spectrometer has been built using semiconductor detectors. The limit of resolution, due to electronics associated to the detector, to the detector itself and to the source of particles is studied here. The present practical limit of resolution of the spectrometer is 1700 elementary electric charges (full width at half maximum of a ray of a spectrum) or 6 keV in terms of energy lost by a particle in a silicon detector. The physical resolution usually obtained is 20 keV (0.33 per cent) with {alpha} particles of the {sup 212}Bi (6.087 MeV). It depends a lot of the kind of detector used. Some results, concerning the background of the detectors and limit of measurements for low energies are given. Various applications are presented: spectrometry {beta}, spectrometry {gamma} and X, spectrometry of mixtures of {alpha} radioactive elements, collection of {alpha} spectra. (author) [French] La faible energie moyenne, 2,5 a 3,5 eV, necessaire pour produire une paire electron-trou dans un semi-conducteur, permet une mesure precise de l'energie des particules ionisantes. Un spectrometre a haute resolution a ete construit utilisant des detecteurs a semi-conducteur. La limitation en resolution due a l'electronique associee au detecteur, au detecteur lui-meme et a la source de particules, est etudiee. La resolution pratique limite actuelle du spectrometre est 1700 charges electriques elementaires (largeur a mi-hauteur d'une raie de spectre) ou 6 keV exprimee en energie perdue par une particule dans un detecteur au silicium. La resolution physique couramment obtenue est de 20 keV (0,33 pour cent) pour les particules {alpha} du bismuth 212 (6,087 MeV). Elle depend beaucoup du detecteur utilise. Quelques resultats sont donnes concernant le mouvement propre des detecteurs et la limitation des

  14. Application of wavelet analysis to the nuclear phase space study; Application de l`analyse en ondelettes a l`etude de l`espace des phases nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Jouault, B. [Nantes Univ., 44 (France)

    1996-11-22

    The objective of this thesis is to present a methodology, based on the projection methods used in statistical physics and on the wavelet approach, which allows to obtain various classes of information. A coherent modelling was elaborated as the tools used for generating and solving the evolution equations, expressed in terms of pertinent variables, are based on common concepts. The property of scale separation of the wavelet analysis allows an approximation hierarchy based on the geometrical structure of phase space to be defined. This information structuration offers the opportunity of solving the evolution equations with various degrees of precision by controlling the information loss and avoiding the sampling methods of Monte Carlo type. The application of this methodology to the case of heavy ion collisions needs an entirely numerical treatment of the density matrix evolution equation. This implies a very precise level of description in order to take into account the important dissipation effects occurring in intermediate energy nuclear dynamics. A proper solution less expensive was adopted by using the wavelets analytically expressed, this entailing also the testing of model validity by comparing its results with the analytical solutions. This model takes into account the structure of the system wave functions, thus conserving the microscopical information. The present methodology can be applied also at other energy domains providing the nuclear systems are subject to transient non steady-state regimes. The wavelet analysis was used extensively in the field of signal processing particularly to extract from background a physical signal and also in the field of turbulence phenomena 152 refs.

  15. Applicability of ICRP principles for safety analysis of radioactive waste geological storage; Etude de l'applicabilite des principes de la CIPR a l'analyse de surete du stockage geologique des dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Lombard, J; Hubert, P; Pages, P

    1987-07-01

    modalites de stockage) doit etre determine par un processus comparatif visant a selectionner le niveau conduisant au meilleur compromis entre es depenses de protection et les risques residuels. Ces recommandations, particulierement Ia seconde, s'ecartent des principes des analyses de surete suivis jusqu'a present en France et a l'etranger; cette etude envisage les avantages et inconvenients potentiels lies a l'introduction de ce second principe. Dans ce but on se base sur differentes analyses realisees au niveau international integrant partiellement au moms ces principes. II ressort de cet examen que ces principes sont applicables mais que leur mise en oeuvre necessite une reorientation de modeles d'evaluation en particulier pour s'affranchir d'hypotheses trop conservatrices. Cette mise en oeuvre necessite par ailleurs davantage d'informations que dans le cas d'une approche deterministe de Ia surete puisqu'il faut estimer les consequences et les probabilites de I'ensemble des evenements possibles et ce pour es diverses modalites de stockage que l'on se propose de comparer. L'integration d'evaluation de ce type est cependant plus riche d'enseignements et constitue de ce fait une aide a Ia decision qui peut etre feconde. On peut enfin souligner que cette approche permet un meilleur dialogue entre les differentes instances decisionnelles et plus generalement entre les acteurs du debat, dans Ia mesure ou elle apporte un langage de discussion commun. On notera d'ailleurs que ce souci de clarification s'exprime quelle que soit I'optique de surete adopte (deterministe ou probabiliste), comme en temoignent les interrogations sur le sens du 'scenario central' de I'etude KBS. Par ailleurs, ii semble que ces principes seront vraisemblablement suivis au plan international afin d'uniformiser en outre les modes de gestion de Ia radioprotection dans ses diff?rentes composantes. (author)

  16. Criticality studies; Etudes de criticite

    Energy Technology Data Exchange (ETDEWEB)

    Breton, D; Lecorche, P; Clouet d' Orval, Ch [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Criticality studies made at the Commissariat a l'Energie atomique deal on the one hand with experiments on plutonium and uranium solutions, on the other hand with theoretical work on the development and use of computation, methods for the resolution of problems concerning the nuclear safety of chemical and metallurgical plants. I - Since 1958 the experimental studies have dealt with homogeneous media constituted by a fissile salt dissolved in light water. Developed using the reactor Proserpine, the experiments have been carried on at Saclay on the Alecto assemblies where solutions of plutonium or of 90 p.100 - enriched uranium can be made critical. The results already obtained relate to critical masses of cylindrical tanks of diameters from 20 to 50 cm. reflected in several ways (water, concrete, etc. . ) at concentrations up to 100 g/liter. Physical measurements (spectra, reactor noises) and interaction measurements complete the results. Other experiments relating to plutonium solutions were begun in 1963, at the Valduc Center. They deal with the study of critical masses of annular vessels of external diameter 50 cm and internal diameter varying from 10 to 30 cm. These vessels can be water reflected internally, externally, or both. Two of these vessels have been studied in interaction for various geometries. Slabs of various thicknesses were also studied. II - The studies thus undertaken allowed the development of methods of computation which have been tested on several experiments. Particular use has been made of the possibilities of calculations based on transport theory and on Monte Carlo methods. All these theoretical studies are applied to the design and control of industrial plants from the point of view of safety. (authors) [French] Les etudes de criticite effectuees au CEA comportent d'une part des experiences sur des solutions de plutonium et d'uranium enrichi, d'autre part des travaux theoriques portant sur la mise au point et l'exploitation de methodes

  17. Contribution to the study of the uranium-hydrogen system; Contribution a l'etude du systeme uranium-hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Chevallier, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-01-01

    Previous work on uranium-hydrogen system is reviewed. The U-H{sub 2}-UH{sub n} equilibrium is then investigated at pressures below one atmosphere, i.e. at temperatures lower than 430 deg. C. The hydride obtained at equilibrium is deficient in hydrogen (UH{sub n<3}), the hydrogen deficit increasing as the temperature rises. Thermodynamic functions for the formation of non-stoichiometric hydride and of one hydrogen vacancy are derived from pressure composition isotherms, in U-H phase diagram is proposed. The hydrogenation of U-UC alloys is also examined at pressures below one atmosphere with regard to the equilibrium: (free U + UC) - H{sub 2}-UH{sub n}. The equilibrium conditions are found different from that observed for pure uranium. (author) [French] Une etude bibliographique du systeme uranium-hydrogene est exposee. L'equilibre U-H{sub 2}-UH{sub n} est ensuite etudie sous des pressions inferieures a une atmosphere, soit aux temperatures inferieures a environ 430 degs. C. L'hydrure obtenu a l'equilibre est deficitaire en hydrogene - UH{sub n<3} - et d'autant plus que la temperature s'eleve. Les grandeurs thermodynamiques relatives a la formation et a la saturation de l'hydrure, ainsi qu'a la formation d'une lacune d'hydrogene sont deduites des pressions d'equilibre. Un modele de diagramme de phases U-H est propose. L'hyduration des alliages U-UC est etudiee egalement sous des pressions inferieures a l'atmosphere, au point de vue de l'equilibre (U libre + UC) - H{sub 2}-UH{sub n}. Les conditions d'equilibre sont trouvees differentes de celles observees sur l'uranium pur. (auteur)

  18. Processing of data issued from {gamma} spectrometer. Application to the study of decay schemes; Traitement des informations issues d'un spectrometre {gamma}. Application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P; Legrand, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    The main purpose of the following report is the study of a generation method of {gamma} spectra corresponding to any energy, from a library of some basic spectra. Then we point out how to establish the decay scheme of a radio-nuclide, in using an accurate analysis of full-energy peaks which appear in its complex spectrum, followed by a generation of plain spectra corresponding to the energies of the different transitions, and ending with a least-squares fitting procedure of the complex spectrum. The accuracy of the process is examined comparing the calculated spectra to the ones issued from two kinds of spectrometers (Na I(Tl) and Ge(Li)). The method is then applied to the study of {sup 134}Cs and {sup 95}Zr - {sup 95}Nb. (authors) [French] Le present rapport a pour principal objet l'etude d'une methode de generation de spectres {gamma} correspondant a n'importe quelle energie, a partir d'une bibliotheque de quelques spectres de reference. On montre ensuite comment on peut etablir le schema de desintegration d'un radionucleide, a l'aide d'une analyse precise des pics d'absorption totale apparaissant dans son spectre complexe, suivie d'une generation des spectres simples correspondant aux energies des diverses transitions, et en terminant par une decomposition du spectre complexe par la methode des moindres carres. On examine la validite du procede en comparant les spectres calcules a ceux obtenus avec deux types de detecteurs (scintillateurs et semi-conducteurs). On applique alors la methode a l'etude du {sup 134}Cs et du {sup 95}Zr - {sup 95}Nb. (auteurs)

  19. Contribution to the study on the flow rate adjustment for gas cooled power reactors (1964); Contributiom a l'etude de reglage du debit pour les reacteurs industriels refroidis par gaz (1964)

    Energy Technology Data Exchange (ETDEWEB)

    Milliot, B. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1961-06-15

    1. This original study firstly defines the problem of the adjustment of the coolant flow rate in a reactor channel as a function of the corresponding heat transfer equations and of the local and temporal neutron flux. The necessity of such an adjustment is pointed out and the modifying parameters are studied. An adjustment study using the envelope of the possible flux curves is developed. A short study on the technology and the economical advantage of this adjustment is presented. Some measurements, made on G-1 and G-2, show the precision one can obtain from adjustment apparatus itself as well as from the complete reactor adjustment system. 2. Evolution of nuclear properties of fuel in an heterogeneous thermal reactor. In the first port of this paper, the phenomena of fuel evolution have been mainly pointed out. Now a bibliographical study more qualitatively than quantitatively has been done. This survey specifies the present theories and relates to a real effective cross section and also yields to the bases of such a nuclear calculation. (author) [French] 1. Cette etude originale definit d'abord le probleme du reglage du debit de refrigerant dans un canal de reacteur en fonction de la formulation du calcul des performances thermodynamiques de ce canal et des variations du flux neutronique dans l'espace et le temps. La necessite du reglage est ensuite mise en evidence et les parametres le modifiant sont etudies. Une methode de reglage, basee sur l'emploi d 'une courbe enveloppe des courbes de flux possibles, est donnee. Une breve etude de la technologie et des incidences economiques du reglage est presentee. Des mesures effectuees sur les reacteurs G-1 et G-2 montrent la precision que l'on peut attendre des dispositifs de reglage comme du reglage d'ensemble du reacteur lui-meme. 2. Evolution des proprietes nucleaires du combustible dans un reacteur heterogene a neutrons thermiques. Les phenomenes d'evolution du combustible

  20. Contribution to the study on the flow rate adjustment for gas cooled power reactors (1964); Contributiom a l'etude de reglage du debit pour les reacteurs industriels refroidis par gaz (1964)

    Energy Technology Data Exchange (ETDEWEB)

    Milliot, B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1961-06-15

    1. This original study firstly defines the problem of the adjustment of the coolant flow rate in a reactor channel as a function of the corresponding heat transfer equations and of the local and temporal neutron flux. The necessity of such an adjustment is pointed out and the modifying parameters are studied. An adjustment study using the envelope of the possible flux curves is developed. A short study on the technology and the economical advantage of this adjustment is presented. Some measurements, made on G-1 and G-2, show the precision one can obtain from adjustment apparatus itself as well as from the complete reactor adjustment system. 2. Evolution of nuclear properties of fuel in an heterogeneous thermal reactor. In the first port of this paper, the phenomena of fuel evolution have been mainly pointed out. Now a bibliographical study more qualitatively than quantitatively has been done. This survey specifies the present theories and relates to a real effective cross section and also yields to the bases of such a nuclear calculation. (author) [French] 1. Cette etude originale definit d'abord le probleme du reglage du debit de refrigerant dans un canal de reacteur en fonction de la formulation du calcul des performances thermodynamiques de ce canal et des variations du flux neutronique dans l'espace et le temps. La necessite du reglage est ensuite mise en evidence et les parametres le modifiant sont etudies. Une methode de reglage, basee sur l'emploi d 'une courbe enveloppe des courbes de flux possibles, est donnee. Une breve etude de la technologie et des incidences economiques du reglage est presentee. Des mesures effectuees sur les reacteurs G-1 et G-2 montrent la precision que l'on peut attendre des dispositifs de reglage comme du reglage d'ensemble du reacteur lui-meme. 2. Evolution des proprietes nucleaires du combustible dans un reacteur heterogene a neutrons thermiques. Les phenomenes d'evolution du combustible tiennent une place importante dans l'etude

  1. Etude de l'impact de la variation de la température sur les activités ...

    African Journals Online (AJOL)

    Etude de l'impact de la variation de la température sur les activités microbiennes : application à une population de Listeria monocytogenes CIP 7831, Listeria monocytogenes Scott A CIP 103575 et Escherichia coli ATCC 25922.

  2. Contribution to the study of the geophysical behaviour of lead-210 by application of alpha spectrometry; Contribution a l'etude du comportement geophysique du plomb 210 par application de la spectrometrie alpha

    Energy Technology Data Exchange (ETDEWEB)

    Nezami, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    A study of the changes in the lead-210 contents of rain-water and of water produced by melting polar ice has required the development of a method for dosing lead-210, an {alpha} emitter. This method is 40 times more sensitive than that which measures the lead-210 by bismuth-210, a ({beta} emitter. The first part of the report presents the study of a spectrometry using semiconductor detectors; a catalogue of a spectra shows the advantages of this method. In the second part will be found at first a new chemical separation method for polonium-210 and the results obtained with this method. The main results obtained on the geophysical behaviour of lead-210 are the following: - the monthly lead-210 and polonium-210 contents in rain water are approximately constant with time. - in the Gif-sur-Yvette region, the clean-up by 'dry fall-out' can attain 40 to 50 per cent of the total fall-out. - a study of Antarctic ice samples makes it possible to determine an annual accumulation rate equivalent to 13.8 cm of water and to show discrepancies in the periodic concentrations which correspond to the latest maxima of solar activity. - a balance is drawn up between the radon produced by the continents and the lead-210 fall-out. (author) [French] Une etude sur les variations de la teneur en plomb 210 des eaux de pluie et des eaux de fusion des glaces polaires a necessite la mise au point d'une methode de dosage du plomb 210 emetteur {alpha}. Cette methode permet d'obtenir une sensibilite quarante fois superieure a celle dosant le plomb 210 par le bismuth 210 emetteur {beta}. La premiere partie du travail presente l'etude de la spectrometrie {alpha} par detecteur a semiconducteurs, un catalogue de spectres {alpha} met en evidence les avantages de cette methode. Dans la deuxieme partie on trouvera en premier lieu une nouvelle methode chimique de separation du polonium 210 ainsi que les resultats obtenus grace a cette methode. Les principaux resultats sur le comportement geophysique du

  3. Contribution to the study of the geophysical behaviour of lead-210 by application of alpha spectrometry; Contribution a l'etude du comportement geophysique du plomb 210 par application de la spectrometrie alpha

    Energy Technology Data Exchange (ETDEWEB)

    Nezami, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    A study of the changes in the lead-210 contents of rain-water and of water produced by melting polar ice has required the development of a method for dosing lead-210, an {alpha} emitter. This method is 40 times more sensitive than that which measures the lead-210 by bismuth-210, a ({beta} emitter. The first part of the report presents the study of a spectrometry using semiconductor detectors; a catalogue of a spectra shows the advantages of this method. In the second part will be found at first a new chemical separation method for polonium-210 and the results obtained with this method. The main results obtained on the geophysical behaviour of lead-210 are the following: - the monthly lead-210 and polonium-210 contents in rain water are approximately constant with time. - in the Gif-sur-Yvette region, the clean-up by 'dry fall-out' can attain 40 to 50 per cent of the total fall-out. - a study of Antarctic ice samples makes it possible to determine an annual accumulation rate equivalent to 13.8 cm of water and to show discrepancies in the periodic concentrations which correspond to the latest maxima of solar activity. - a balance is drawn up between the radon produced by the continents and the lead-210 fall-out. (author) [French] Une etude sur les variations de la teneur en plomb 210 des eaux de pluie et des eaux de fusion des glaces polaires a necessite la mise au point d'une methode de dosage du plomb 210 emetteur {alpha}. Cette methode permet d'obtenir une sensibilite quarante fois superieure a celle dosant le plomb 210 par le bismuth 210 emetteur {beta}. La premiere partie du travail presente l'etude de la spectrometrie {alpha} par detecteur a semiconducteurs, un catalogue de spectres {alpha} met en evidence les avantages de cette methode. Dans la deuxieme partie on trouvera en premier lieu une nouvelle methode chimique de separation du polonium 210 ainsi que les resultats obtenus grace a cette methode. Les principaux resultats sur le

  4. Magnetic resonance studies of solid polymers; Etude des polymeres solides par resonance magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Lenk, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    This paper is a review of the application of nuclear magnetic resonance (NMR) to solid polymers. In the first, theoretical part, the elements of the theory of NMR, which are necessary for the study of the properties of solid polymers are discussed: the moments method, nuclear relaxation and the distribution of correlation times. In the second part the experimental results are presented. (author) [French] Cette etude est une recherche bibliographique sur l'application de la resonance magnetique nucleaire (RMN) aux polymeres solides. Dans la premiere partie theorique on discute les elements de la theorie de RMN, necessaires pour l'etude des proprietes des polymeres solides: la methode des moments, la relaxation nucleaire et la distribution des temps de correlation. La deuxieme partie presente les resultats des experiences. (auteur)

  5. Realization of an electromagnetic isotope separator. Application to the isotopes of the mass 93 from the molybdenum and the technetium; Realisation d'un separateur electromagnetique d'isotope. Application a l'etude des isotopes de masse 93 du molybdene et du technetium

    Energy Technology Data Exchange (ETDEWEB)

    Bernas, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1954-07-15

    Analysis of focusing properties of a homogeneous magnetic field leads the author to use a magnetic sector of 60 deg, for the realization of an electromagnetic separator. The sources of realized ions provide ionic debits of 10 mA. The currents ionic detached isotopes to the collector vary from 1 to 5 mA. The separation efficiency is of 125 for a current collected of 1 mA. A survey of the neutralization of the space charge permitted to specify the role of the negative ions in this phenomenon. A method of neutralization of the space charge is proposed and gave excellent results. A report will be given of the separations of some elements: mercury, bromine, thorium, etc... The application of the separator to the study of the isomeric transfers in the molybdenum and the technetium permitted to assign definitely for {sup 93}Mo and {sup 93}Tc two radiances {gamma} of respective energies 260 and 390 keV. A new process of fast chemical separation Mo/Tc is described. (author) [French] L'analyse des proprietes de focalisation d'un champ magnetique homogene conduit l'auteur, pour la realisation d'un separateur electromagnetique, a employer un secteur magnetique de 60 deg. Les sources d'ions realisees fournissent des debits ioniques de 10 mA. Les courants ioniques d'isotopes separes au collecteur varient de 1 a 5 mA. Le pouvoir separateur est de 125 pour un courant collecte de 1 mA. Une etude de la neutralisation de la charge d'espace a permis de preciser le role des ions negatifs dans ce phenomene. Une methode de neutralisation de la charge d'espace est proposee et a donne d'excellents resultats. On donne le compte rendu des separations de quelques elements: mercure, brome, thorium, etc... L'application du separateur a l'etude des translations isomeriques dans le molybdene et le technetium a permis d'attribuer definitivement a {sup 93}Mo et a {sup 93}Tc deux rayonnements {gamma} d'energies respectives 260 et 390 keV. Un nouveau procede de separation chimique rapide Mo c est

  6. Realization of an electromagnetic isotope separator. Application to the isotopes of the mass 93 from the molybdenum and the technetium; Realisation d'un separateur electromagnetique d'isotope. Application a l'etude des isotopes de masse 93 du molybdene et du technetium

    Energy Technology Data Exchange (ETDEWEB)

    Bernas, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1954-07-15

    Analysis of focusing properties of a homogeneous magnetic field leads the author to use a magnetic sector of 60 deg, for the realization of an electromagnetic separator. The sources of realized ions provide ionic debits of 10 mA. The currents ionic detached isotopes to the collector vary from 1 to 5 mA. The separation efficiency is of 125 for a current collected of 1 mA. A survey of the neutralization of the space charge permitted to specify the role of the negative ions in this phenomenon. A method of neutralization of the space charge is proposed and gave excellent results. A report will be given of the separations of some elements: mercury, bromine, thorium, etc... The application of the separator to the study of the isomeric transfers in the molybdenum and the technetium permitted to assign definitely for {sup 93}Mo and {sup 93}Tc two radiances {gamma} of respective energies 260 and 390 keV. A new process of fast chemical separation Mo/Tc is described. (author) [French] L'analyse des proprietes de focalisation d'un champ magnetique homogene conduit l'auteur, pour la realisation d'un separateur electromagnetique, a employer un secteur magnetique de 60 deg. Les sources d'ions realisees fournissent des debits ioniques de 10 mA. Les courants ioniques d'isotopes separes au collecteur varient de 1 a 5 mA. Le pouvoir separateur est de 125 pour un courant collecte de 1 mA. Une etude de la neutralisation de la charge d'espace a permis de preciser le role des ions negatifs dans ce phenomene. Une methode de neutralisation de la charge d'espace est proposee et a donne d'excellents resultats. On donne le compte rendu des separations de quelques elements: mercure, brome, thorium, etc... L'application du separateur a l'etude des translations isomeriques dans le molybdene et le technetium a permis d'attribuer definitivement a {sup 93}Mo et a {sup 93}Tc deux rayonnements {gamma} d'energies respectives 260 et 390

  7. ETUDE - European Trade Union Distance Education.

    Science.gov (United States)

    Creanor, Linda; Walker, Steve

    2000-01-01

    Describes transnational distance learning activities among European trade union educators carried out as part of the European Trade Union Distance Education (ETUDE) project, supported by the European Commission. Highlights include the context of international trade union distance education; tutor training course; tutors' experiences; and…

  8. Contribution to the development of a gamma radiation camera for use in scintigraphy; Contribution a l'etude et a la realisation d'une camera a rayonnement gamma en vue d'une application a la scintigraphie

    Energy Technology Data Exchange (ETDEWEB)

    Felix, J [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-10-01

    This report constitutes an attempt to study systematically the properties of the detection head of a multichannel collimating grid camera. The object has been to show the disadvantages of present equipment, and to propose possible solutions for overcoming them: firstly by improving the methods used for collecting data, and the performances of the equipment doing the collecting; secondly by devising methods for processing the data so as to reduce image distortion and, first of all, the astigmatism due to the collimator. The first part deals with the study of the formation of the image by means of the collimating grid, the second with the examination of many systems which could be used for acquiring data. The last part summarizes the experiments carried out and proposes an experimental programme for the development of a prototype. (author) [French] Ce rapport constitue une tentative d'etude systematique des proprietes de la tete de detection d'une camera a grille collimatrice multicanal. Le but de cette etude est de souligner les inconvenients des dispositifs actuels et d'esquisser des solutions propres a y remedier: premierement, par l'amelioration du mode d'acquisition des donnees et des performances du sous-ensemble charge de cette acquisition; deuxiemement, par la recherche de methodes de traitement des donnees propres a reduire les distorsions de l'image et en premier lieu l'astigmatisme du au collimateur. La premiere partie en est devolue a l'etude de la formation de l'image par l'intermediaire de la grille collimatrice, la seconde a l'examen de nombreux systemes utilisables pour l'acquisition des donnees. La derniere partie resume les experiences effectuees et propose un programme de manipulations utiles a l'elaboration d'un prototype d'appareil. (auteur)

  9. Study of the dynamic behaviour of the reactor Rapsodie; Etude du comportement dynamique de la pile rapsodie

    Energy Technology Data Exchange (ETDEWEB)

    Abdon, R; Chaigne, M [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1964-07-01

    . The investigation of the control, carried out on analog computer, served to determine the different possible means of starting and changing the conditions of the reactor as well as its automatic control. The calculations were examined in the totality by the construction of a training simulator composed of a board similar to the control board of the reactor, all of whose commands (reactivity and flows) work on an analogue computer which resolves in the real time the dynamic equations of the reactor and which reproduces simultaneously all the parameters representing the state of the installation (power, period, temperatures, etc. ) in the case of various incidents as well as under normal conditions of functioning. (authors) [French] On sait que le developpement des reacteurs surgenerateurs a neutrons rapides pose des problemes nouveaux d'une part dans les domaines mecanique et thermique et d'autre part en ce qui concerne leur comportement dynamique et leur surete. La pile RAPSODIE a ete l'objet de tres nombreuses etudes dynamiques effectuees sur machines analogiques et digitales, pour deux versions du combustible (metal et oxyde). Apres elaboration des modeles mathematiques representatifs de l'ensemble de l'installation (bloc pile et circuit de refroidissement) tant du point de vue neutronique que du point de vue thermodynamique, on a mis au point les schemas analogiques et les codes digitaux utilisables pour mener a bien les simulations d'incidents, de conduite et de stabilite du reacteur. On s'est attache, par rapport aux methodes habituelles a obtenir une precision plus grande, par un decoupage en zones plus fines, par l'emploi de formulations plus representatives du systeme reel, voire solubles analytiquement. Les etudes d'incidents ont ete effectuees par voie analogique pour l'ensemble de l'installation et par voie digitale pour l'etude du bloc pile seul ou de l'installation fonctionnant avec un seul circuit thermique. Un programme complementaire special - qui, a

  10. Study of the behaviour of artificial radioactive aerosols. Applications to some problems of atmospheric circulation (1963); Etude du comportement dcs aerosols radioactifs artificiels. Applications a quelques problemes de circulation atmospherique (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Lambert, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-11-15

    The aim of this work, consists in the examination of the behaviour of radioactive aerosols produced in the atmosphere by nuclear explosions, in order to deduce the most general laws governing atmospheric circulation and diffusion. After having given a general table of the radioactive aerosols present the authors consider the validity and the precision of the measurement methods and the concentration of the aerosols at ground level and in the upper atmosphere, as well as their deposition on the ground. The existence is thus demonstrated of a tropospheric equatorial barrier and of discontinuous and seasonal aspects of stratosphere-troposphere transfers. The role is shown of precipitations and dry auto-filtration in the lower atmosphere cleaning processes. This work makes it possible to describe the general behaviour of dust from the stratosphere, and to improve the total radioactive contamination of the globe. (author) [French] L'objectif de ce travail consiste a examiner le comportement des aerosols radioactifs introduits dans l'atmosphere par les explosions nucleaires, pour en deduire les lois les plus generals de la circulation et diffusion atmospheriques. Apres avoir dresse un tableau d'ensemble des aerosols radioactifs presents, on examine la validite et la precision des methodes de mesure de leur concentration, au niveau du sol et en haute atmosphere, ainsi que de leur depot a la surface du sol. On met ainsi en evidence l'existence d'une barriere equatoriale tropospherique; l'aspect discontinu et saisonnier des transferts stratosphere-troposphere; le role des precipitations et de l'auto-filtration seche, dans les processus de nettoyage de la basse atmosphere. Ces etudes permettent de decrire le comportement general des poussieres d'origine stratospherique et d'ameliorer le bilan de la contamination radioactive du globe. (auteur)

  11. Study of the behaviour of artificial radioactive aerosols. Applications to some problems of atmospheric circulation (1963); Etude du comportement dcs aerosols radioactifs artificiels. Applications a quelques problemes de circulation atmospherique (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Lambert, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-11-15

    The aim of this work, consists in the examination of the behaviour of radioactive aerosols produced in the atmosphere by nuclear explosions, in order to deduce the most general laws governing atmospheric circulation and diffusion. After having given a general table of the radioactive aerosols present the authors consider the validity and the precision of the measurement methods and the concentration of the aerosols at ground level and in the upper atmosphere, as well as their deposition on the ground. The existence is thus demonstrated of a tropospheric equatorial barrier and of discontinuous and seasonal aspects of stratosphere-troposphere transfers. The role is shown of precipitations and dry auto-filtration in the lower atmosphere cleaning processes. This work makes it possible to describe the general behaviour of dust from the stratosphere, and to improve the total radioactive contamination of the globe. (author) [French] L'objectif de ce travail consiste a examiner le comportement des aerosols radioactifs introduits dans l'atmosphere par les explosions nucleaires, pour en deduire les lois les plus generals de la circulation et diffusion atmospheriques. Apres avoir dresse un tableau d'ensemble des aerosols radioactifs presents, on examine la validite et la precision des methodes de mesure de leur concentration, au niveau du sol et en haute atmosphere, ainsi que de leur depot a la surface du sol. On met ainsi en evidence l'existence d'une barriere equatoriale tropospherique; l'aspect discontinu et saisonnier des transferts stratosphere-troposphere; le role des precipitations et de l'auto-filtration seche, dans les processus de nettoyage de la basse atmosphere. Ces etudes permettent de decrire le comportement general des poussieres d'origine stratospherique et d'ameliorer le bilan de la contamination radioactive du globe. (auteur)

  12. Study of secondary electronic emission in some piezo-electric materials: application to ultrasonic visualization; Etude de l'emission electronique secondaire de quelques materiaux piezoelectriques: application a la visualisation ultrasonore

    Energy Technology Data Exchange (ETDEWEB)

    Marini, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    Methods allowing the visualization of acoustic images appear at the moment to be of great interest in the field of non-destructive testing as well as in that of underwater detection. In order to carry out certain calculations on the operation of an ultrasonic camera, it has been necessary to study the secondary electron emission of some piezoelectric materials liable to be incorporated into the equipment. The secondary electron emission of insulators is a rather complex phenomenon; in order to find a rational explanation for the observations made, a theory has been developed for the energy spectrum of the emitted electrons. The experimental results of this work have then been used to build an ultrasonic visualization installation. Some examples of acoustic images which have been visualized are also presented. (author) [French] Les methodes qui permettent de visualiser des images acoustiques trouvent a l'heure actuelle un grand interet dans le domaine du controle non destructif comme dans celui de la detection sous-marine. De maniere a effectuer certains calculs sur le fonctionnement d'une camera ultrasons, il a ete necessaire d'etudier l'emission electronique secondaire de quelques materiaux piezoelectriques susceptibles d'etre utilises dans sa construction. L'emission electronique secondaire des isolants est un phenomene assez complexe et de maniere a trouver des explications coherentes aux observations effectuees, une theorie du spectre energetique des electrons emis a ete elaboree. Une installation de visualisation ultrasonore a alors ete realisee a partir des donnees experimentales de cette etude. Quelques exemples d'images acoustiques visualisees par cette methode sont egalement presentees. (auteur)

  13. Study of secondary electronic emission in some piezo-electric materials: application to ultrasonic visualization; Etude de l'emission electronique secondaire de quelques materiaux piezoelectriques: application a la visualisation ultrasonore

    Energy Technology Data Exchange (ETDEWEB)

    Marini, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    Methods allowing the visualization of acoustic images appear at the moment to be of great interest in the field of non-destructive testing as well as in that of underwater detection. In order to carry out certain calculations on the operation of an ultrasonic camera, it has been necessary to study the secondary electron emission of some piezoelectric materials liable to be incorporated into the equipment. The secondary electron emission of insulators is a rather complex phenomenon; in order to find a rational explanation for the observations made, a theory has been developed for the energy spectrum of the emitted electrons. The experimental results of this work have then been used to build an ultrasonic visualization installation. Some examples of acoustic images which have been visualized are also presented. (author) [French] Les methodes qui permettent de visualiser des images acoustiques trouvent a l'heure actuelle un grand interet dans le domaine du controle non destructif comme dans celui de la detection sous-marine. De maniere a effectuer certains calculs sur le fonctionnement d'une camera ultrasons, il a ete necessaire d'etudier l'emission electronique secondaire de quelques materiaux piezoelectriques susceptibles d'etre utilises dans sa construction. L'emission electronique secondaire des isolants est un phenomene assez complexe et de maniere a trouver des explications coherentes aux observations effectuees, une theorie du spectre energetique des electrons emis a ete elaboree. Une installation de visualisation ultrasonore a alors ete realisee a partir des donnees experimentales de cette etude. Quelques exemples d'images acoustiques visualisees par cette methode sont egalement presentees. (auteur)

  14. Synthetic diamond devices for medical dosimetry applied to radiotherapy; Etude et developpement de dispositifs en diamant synthetique pour la dosimetrie medicale: applications en radiotherapie

    Energy Technology Data Exchange (ETDEWEB)

    Descamps, C

    2007-06-15

    The aim of this thesis, lead in the framework of an integrated European project entitled M.A.E.S.T.R.O. for ' Methods and Advanced Equipment for Simulation and Treatment in Radio Oncology', was to develop and test synthetic diamond detector in clinical environment for new modalities used in radiotherapy. Diamond is a good candidate for the detection of high energy beams in medical fields. It can be used for passive dosimetry, as thermoluminescent dosimeters or for active dosimetry as ionisation chambers. These two applications are presented here. Concerning the thermoluminescence, several impurities or dopants (boron, phosphorus, and nitrogen) have been incorporated in the diamond films during growth, in order to modify the material dosimetric properties and a detailed study of nitrogen-containing films is proposed. The second part presents the results obtained in active dosimetry. Two guide lines were followed: the measurement set-up optimisation and the material modification. The first dosimetric studies under radiotherapy beams concerning nitrogen-containing polycrystalline diamond as well as high purity single crystal diamond are conclusive. The detectors behaviours are in agreement with the recommendations of the International Atomic Energy Agency (IAEA). (author)

  15. Synthetic diamond devices for medical dosimetry applied to radiotherapy; Etude et developpement de dispositifs en diamant synthetique pour la dosimetrie medicale: applications en radiotherapie

    Energy Technology Data Exchange (ETDEWEB)

    Descamps, C

    2007-06-15

    The aim of this thesis, lead in the framework of an integrated European project entitled M.A.E.S.T.R.O. for ' Methods and Advanced Equipment for Simulation and Treatment in Radio Oncology', was to develop and test synthetic diamond detector in clinical environment for new modalities used in radiotherapy. Diamond is a good candidate for the detection of high energy beams in medical fields. It can be used for passive dosimetry, as thermoluminescent dosimeters or for active dosimetry as ionisation chambers. These two applications are presented here. Concerning the thermoluminescence, several impurities or dopants (boron, phosphorus, and nitrogen) have been incorporated in the diamond films during growth, in order to modify the material dosimetric properties and a detailed study of nitrogen-containing films is proposed. The second part presents the results obtained in active dosimetry. Two guide lines were followed: the measurement set-up optimisation and the material modification. The first dosimetric studies under radiotherapy beams concerning nitrogen-containing polycrystalline diamond as well as high purity single crystal diamond are conclusive. The detectors behaviours are in agreement with the recommendations of the International Atomic Energy Agency (IAEA). (author)

  16. Calage thermodynamique du point mort haut des moteurs à piston Thermodynamic Calibration of Top Dead Center in Piston Engines

    Directory of Open Access Journals (Sweden)

    Pinchon P.

    2006-11-01

    Full Text Available Lorsqu'on utilise un système d'acquisition rapide de données sur moteur, il se pose souvent le problème d'associer des grandeurs calculées, comme le volume de la chambre de combustion, à des grandeurs mesurées comme la pression dans le cylindre. II est alors indispensable de synchroniser avec une grande précision absolue ces deux grandeurs en repérant avec soin au moins un point de référence de la cinématique bielle-manivelle. Dans la méthode développée ici on a choisi de déterminer la position angulaire du vilebrequin correspondant au Point Mort Haut (PMH grâce à l'exploitation du signal de pression-cylindre acquis en compression-détente sans combustion, le moteur étant entraîné en rotation. Le principe du calage consiste à calculer l'écart existant entre le PMH et l'angle de la pression maximale qui est aisément repérable. Basée sur des considérations thermodynamiques théoriques, cette méthode de calage a été testée avec succès au cours d'essais effectués sur divers moteurs dont on a fait varier en particulier le rapport volumétrique, le remplissage et les pertes à la segmentation. La précision de la méthode est de l'ordre de 1/10e de degré de rotation vilebrequin. When a fast data-acquisition system is used for an engine, the problem often arises of associating both calculated data, such as combustion chamber volume, and measured data, such as pressure inside the cylinder. It then becomes indispensable to synchronize these two data with great absolute accuracy by carefully determining at least a reference point in the kinematics of the connecting-rod/crank shaft assembly. In the method developed here, we have chosen to determine the angular position of the crankshaft corresponding to top dead center (TDC by making use of the cylinder-pressure signal recorded during compression/expansion without combustion for motored engine. The calibration principle consists in calculating the shift between TDC and the

  17. Étude thermodynamique du corium en cuve - Application à l'interaction corium/béton

    OpenAIRE

    Quaini , Andrea

    2015-01-01

    During a severe accident in a pressurised water reactor, the nuclear fuel can interact with the Zircaloy cladding, the neutronic absorber and the surrounding metallic structure forming a partially or completely molten mixture. The molten core can then interact with the reactor steel vessel forming a mixture called in-vessel corium. In the worst case, this mixture can pierce the vessel and pour onto the concrete underneath the reactor, leading the formation of the ex-vessel corium. Furthermore...

  18. Neutron spin echo spectroscopy. Its application to the study of the dynamics of polymers in solution; La spectrometrie par echos de spins de neutrons. Application a l'etude de la dynamique des polymeres en solution

    Energy Technology Data Exchange (ETDEWEB)

    Papoular, Robert

    1992-06-15

    : ses caracteristiques et ses performances, ainsi que les premiers resultats physiques que nous avons obtenus a l'aide de MESS. En particulier, ce memoire inclut deux articles montrant comment la depolarisation des neutrons, la rotation des spins et les echos de spins peuvent etre utilises pour etudier les supraconducteurs de haut-Tc. La derniere partie traite de la dynamique des systemes ternaires Polymere-Polymere-Solvant et montre comment l'utilisation conjointe des echos de spins de neutrons et des methodes de variation de contraste font des Echos de Spins de Neutrons un outil privilegie pour de telles etudes physico-chimiques, et cela grace aux gammes de temps et de vecteurs de diffusion accessibles par cette technique. Enfin, le cas specifique du polydimethylsiloxane partiellement deuterie en solution semi-diluee dans le toluene est decrit. Nous avons mis en evidence experimentalement et separement les modes diffusifs cooperatif et interdiffusif predits par la theorie de Akcasu, Benoit Benmouna et al. Ces resultats, obtenus au L.L.B. (Saclay), font l'objet du dernier article de cette these. (auteur)

  19. Study of the anodic process in the electrolysis of molten chlorides. Application to the chlorine electrode; Contribution a l'etude du processus anodique dans l'electrolyse des chlorures fondus. Application a l'electrode de chlore

    Energy Technology Data Exchange (ETDEWEB)

    Fondanaiche, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-05-01

    propriete de la reaction d'oxydation des ions Cl{sup -} nous a permis de proposer une methode electrochimique pour l'etude de l'equilibre d'absorption du chlore entre une phase solide et une phase liquide. Nous pouvons, en effet, remplacer l'apport exterieur de chlore sous une pression P par une electrolyse sous une densite de courant I. Nous avons developpe un schema qui rend compte de la cinetique de la reaction de decharge des ions Cl{sup -}. Il a ete verifie a l'aide des courbes intensite-potentiel et des courbes potentiel-temps caracterisant la depolarisation du carbone en circuit ouvert. Deux methodes ont ete utilisees pour la mesure de la quantite de chlore adsorbe sur le carbone. Les liaisons des molecules de chlore adsorbe sur le carbone et la surface d'echange electrode-electrolyte ont pu etre precisees en faisant varier la temperature, la nature de l'electrode et de l'electrolyte. Certaines anomalies et en particulier certains phenomenes transitoires, ont ete expliques par l'influence de l'oxygene present dans le sel fondu sous forme d'ions O{sup 2-} et a la surface de l'electrode, sous forme de complexes de chimisorption. (auteur)

  20. Study of semi-conductor spectrometers for high counting rates. Application to the study of the reaction {sup 31}P (p, {alpha}{sub 0}): E{sub p} < 2 MeV; Etude de spectrometres a semi-conducteurs pour forts taux de comptage application a l'etude de la reaction {sup 31}P (p, {alpha}0): E{sub p} < 2 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Ligeon, E [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1967-10-01

    The study of nuclear reactions involving particles of low charge (E < 2 MeV) calls for spectrometers of high resolving power. In many experiments however, the counting rate is high because of Coulomb scattering at the target: this results in a distortion of the experimental spectra and a loss of resolving power in the detection equipment. The first part of the work is devoted to an evaluation of the resolving power obtained with silicon-detector spectrometers. A study of the elastic scattering of protons by {sup 31}P shows which are the factors limiting the resolving power. In the second part we examine the various types of spectrometer which can be used in the case of a high count-rate. We have built an apparatus which can be used for carrying out spectrometry on particles produced by nuclear reactions, for a total, count-rate of 10{sup 5} counts/sec. (author) [French] L'etude des reactions nucleaires avec particules chargees a basse energie (E < 2 MeV) exige des spectrometres de haute resolution. Cependant, dans de nombreuses experiences le taux de comptage est eleve, par suite de la diffusion coulombienne sur la cible; on observe alors une distorsion des spectres experimentaux et une perte de resolution de l'ensemble de detection. La premiere partie de ce travail est consacree a l'evaluation de la resolution obtenue avec des spectrometres utilisant des detecteurs au silicium. L'etude de la diffusion elastique des protons sur le {sup 31}P montre quels sont les facteurs qui limitent la resolution. Dans une deuxieme partie, nous etudions les differents types de spectrometres que l'on peut utiliser dans le cas d'un taux de comptage eleve. Nous avons construit un appareil qui permet de faire la spectrometrie de particules, provenant de reactions nucleaires, pour un taux de comptage total de 10{sup 5} c/s. (auteur)

  1. Study of semi-conductor spectrometers for high counting rates. Application to the study of the reaction {sup 31}P (p, {alpha}{sub 0}): E{sub p} < 2 MeV; Etude de spectrometres a semi-conducteurs pour forts taux de comptage application a l'etude de la reaction {sup 31}P (p, {alpha}0): E{sub p} < 2 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Ligeon, E. [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1967-10-01

    The study of nuclear reactions involving particles of low charge (E < 2 MeV) calls for spectrometers of high resolving power. In many experiments however, the counting rate is high because of Coulomb scattering at the target: this results in a distortion of the experimental spectra and a loss of resolving power in the detection equipment. The first part of the work is devoted to an evaluation of the resolving power obtained with silicon-detector spectrometers. A study of the elastic scattering of protons by {sup 31}P shows which are the factors limiting the resolving power. In the second part we examine the various types of spectrometer which can be used in the case of a high count-rate. We have built an apparatus which can be used for carrying out spectrometry on particles produced by nuclear reactions, for a total, count-rate of 10{sup 5} counts/sec. (author) [French] L'etude des reactions nucleaires avec particules chargees a basse energie (E < 2 MeV) exige des spectrometres de haute resolution. Cependant, dans de nombreuses experiences le taux de comptage est eleve, par suite de la diffusion coulombienne sur la cible; on observe alors une distorsion des spectres experimentaux et une perte de resolution de l'ensemble de detection. La premiere partie de ce travail est consacree a l'evaluation de la resolution obtenue avec des spectrometres utilisant des detecteurs au silicium. L'etude de la diffusion elastique des protons sur le {sup 31}P montre quels sont les facteurs qui limitent la resolution. Dans une deuxieme partie, nous etudions les differents types de spectrometres que l'on peut utiliser dans le cas d'un taux de comptage eleve. Nous avons construit un appareil qui permet de faire la spectrometrie de particules, provenant de reactions nucleaires, pour un taux de comptage total de 10{sup 5} c/s. (auteur)

  2. The study by means of a photomultiplier of the scintillations produced by {alpha} particles striking a zinc sulphide screen; Etude, au photomultiplicateur, des scintillations produites par les particules {alpha} dans un ecran de sulfure de zinc. Application a la numeration precise des particules {alpha}

    Energy Technology Data Exchange (ETDEWEB)

    Anthony, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-06-15

    The object of the study is the accurate counting of {alpha} particles by p-m. detection of their scintillations upon impact with a zinc sulphide screen. The main advantage of the method is the extreme simplicity of the electronics used: the possibility of obtaining a utilizable pulse from the p-m. (EMI5311) without any amplification, and in linear response, is demonstrated. The scintillation produced by an impact on Zn-S has also been studied experimentally. The decrease of light intensity in relation to time may be interpreted by the exponential relation: I = I{sub 0} exp (-t / {tau}) whereby {tau} = (39 {+-} 0,1) 10{sup -6} s. The relation between scintillation intensity and remaining trajectory after travel through a given air-space has also been determined. Possible suitable applications of this method of {alpha} counting are those where good stability and low background are necessary. Results stated bear on air contamination studies, isotopic composition variation measurement of uranium, bismuth content measurement in alloys by irradiation of specimens in a thermal neutron flux and {alpha} count on the Po formed. (author) [French] Ce travail est consacre a l'etude de la numeration precise des particules {alpha} par detection au photomultiplicateur des scintillations produites par ces particules dans un ecran de sulfure de zinc. Le principal avantage de cette methode reside dans l'extreme simplicite de l'appareillage electronique; il est en effet montre qu'il est possible, tout en convoyant une reponse lineaire, d'obtenir du photomultiplicateur (EMI5311) un signal electrique utilisable sans aucune amplification. La scintillation produite par l'impact des particules {alpha} sur un ecran de Zn-S est etudiee experimentalement. La decroissance de l'intensite lumineuse en fonction du temps est interpretable par la relation exponentielle I = I{sub 0} exp (-t / {tau}) avec {tau} = (39 {+-} 0,1) 10{sup -6} s. La relation entre l'intensite de la scintillation et le

  3. Determination of Thermodynamical Data of Calcium Hydroxichloride Détermination des données thermodynamiques de l'hydroxychlorure de calcium

    Directory of Open Access Journals (Sweden)

    Allal K. M.

    2006-12-01

    Full Text Available The reaction of hydrochloric acid with dry alkaline sorbents such as hydrated lime in the incineration units leads to the formation of not only calcium chloride but calcium hydroxichloride as well. A thermodynamic study of the chemical reactions involved in the dechlorination process is required in order to show if such a product is theoretically possible to be formed. However, the data of CaCIOH necessary to carry out such a study are not available in the literature. Hence, a method of predicting these data is developed in the present work. Predicted values of Gibbs energy and entropy of formation of CaCIOH at different temperatures are compared to values calculated by Mostafa's model and satisfactory results were obtained. La réaction de l'acide chlorhydrique avec des adsorbants alcalins tels que la chaux au niveau de stations d'incinération entraîne la formation de chlorure ainsi que de l'hydroxychlorure de calcium. Une étude thermodynamique des différentes réactions mises en jeu dans le procédé de déchloruration serait nécessaire, afin de montrer qu'un tel produit serait théoriquement susceptible d'être formé. Cependant, les données thermodynamiques de CaCIOH permettant de mener à bien une telle étude ne sont pas disponibles dans la littérature. Par conséquent, une méthode permettant de prédire ces données a été développée dans ce présent travail. Des valeurs d'énergie de Gibbs et d'entropie de formation de CaCIOH prédites par cette méthode à différentes températures ont été comparées à celles déterminées à l'aide du modèle de Mostafa, et des résultats satisfaisants ont été obtenus.

  4. Instrumental performance of an etude after three methods of practice.

    Science.gov (United States)

    Vanden Ark, S

    1997-12-01

    For 80 fifth-grade students three practice conditions (mental, mental with physical simulation, and physical with singing) produced significant mean differences in instrumental performance of an etude. No significant differences were found for traditional, physical practice.

  5. Study of the Dissociative Processes in O{sub 2} Discharges. Development of an Atomic Oxygen Beam Source; Etude de la dissociation de O{sub 2} dans les decharges d'oxygene. Application a la realisation de sources d'atomes

    Energy Technology Data Exchange (ETDEWEB)

    Pagnon, Daniel

    1992-09-24

    The first part of this work is devoted to the study of dissociative processes in an oxygen glow discharge at low pressure (0,1-5 Torr, 1-80 mA). The kinetics of oxygen atoms has been determined supported by the measurements of atomic concentrations by VUV absorption spectroscopy and actinometry. The reaction coefficients for dissociative excitation and direct excitation of oxygen atoms have been calculated using the cross sections of the literature and a previously calculated EEDF. It has been demonstrated that dissociative excitation is negligible in respect with direct excitation for dissociation rates smaller than 2,5 %. An upper limit of 20 % for dissociative rates is observed. This limit has been explained by the increase of the atomic recombination at the discharge wall with increasing wall temperature. Using all these results, we have designed and optimized a source of oxygen atoms which has then been adapted on a MBE device. The spatial distribution of the atomic density has been measured in molecular jet by laser induced fluorescence (LIF) and Resonant Multi-Photon Ionization (RMPI). A stimulated emission has been evidenced and the coefficient for this process evaluated. A model for the effusion of atoms has been developed from which the flow of atoms on the sample can be predicted. This source has already been used in industrial MBE devices for in-situ oxidation of copper films, superconductors, and substrates for VLSI high speed applications. The methodology of this work and the diagnostics developed can be applied to other kinds of discharges, of other molecular gases, to design sources of atoms for the treatment of large area samples. (author) [French] Ce travail debute par l'etude de la dissociation dans une decharge luminescente d'oxygene a basse pression (0,1-5 torr, 1-80 ma). La cinetique des atomes d'oxygene a ete etablie a partir de la mesure des concentrations atomiques par spectroscopie d'absorption vuv et par actinometrie. Les coefficients de

  6. Etude theorique et experimentale des evaporateurs de dioxyde de carbone operant dans des conditions de givrage

    Science.gov (United States)

    Bendaoud, Adlane Larbi

    . Dans la partie theorique, un modele traitant les aspects thermique, hydrodynamique et massique a ete elabore. Sur la base de ce modele a ete ecrit un programme informatique en langage FORTRAN 6.6. Il est base sur la discretisation du serpentin en volumes de controle, est entierement automatise et peut traiter des echangeurs de chaleur avec des circuits de refrigerant complexes pouvant avoir des entrees et sorties multiples ainsi que des bifurcations. La presence simultanee des trois phases thermodynamiques du refrigerant (liquide sous refroidi, fluide sature, vapeur surchauffee) dans le serpentin est aussi prise en charge. Le modele a ete valide pour un fonctionnement avec et sans formation de givre en utilisant des donnees experimentales disponibles dans la litterature et celles obtenues sur le banc d'essai de CanmetENERGIE. Celui-ci a ete mis a jour pour les besoins de la presente recherche et pour cela, un systeme de surchauffe et d'injection de la vapeur d'eau dans une enceinte a tres basse temperature a ete dimensionne, fabrique et installe. Un dispositif de visualisation de la formation de givre, ainsi qu'un equipement de mesure de la temperature, de la pression et de l'humidite relative de l'air ont aussi ete ajoutes. Une fois le modele valide, des simulations numeriques sur le serpentin avec et sans formation de givre ont ete effectuees. Un premier cas de base a servi comme reference pour d'autres cas pour lesquels une etude parametrique sur la geometrie et le fonctionnement a ete menee. Il a ete montre par rapport au cas de base que : 1. la diminution de la densite des ailettes sur des rangees specifiques du serpentin donne une surface minimale (Amin) plus grande, retardant ainsi l'obstruction totale du serpentin par le givre et permet donc un temps de fonctionnement plus grand et une frequence de degivrage plus faible. 2. une bonne configuration de circuit de refrigerant augmente le temps de fonctionnement du serpentin de 200 % et delivre une puissance

  7. Utilisation de mélanges non-azéotropiques dans les cycles thermodynamiques à compression Use of Non-Azeotropic Mixtures in Thermodynamic Compression Cycles

    Directory of Open Access Journals (Sweden)

    Ambrosino J. L.

    2006-11-01

    Full Text Available L'utilisation de mélanges non-azéotropiques comme fluides frigorigènes présente différents avantages en ce qui concerne le fonctionnement des installations de réfrigération / conditionnement / chauffage mettant en oeuvre des cycles thermodynamiques à compression avec changement de phase. En outre, de tels mélanges représentent une alternative intéressante aux corps purs actuellement recherchés pour résoudre les problèmes d'environnement liés à la destruction de la couche d'ozone. Cet article analyse les connaissances acquises concernant la mise en oeuvre d'une telle solution. The use of non-azeotropic mixtures as refrigerants has various advantages concerning the operating of refrigeration / air-conditioning / heating installations implementing thermodynamic compression cycles with a phase change. Likewise, such mixtures represent an interesting alternative to pure components which are now being looked to as a solution to environmental problems linked to the destruction of the ozone layer. This article analyzes what is known about the implementation of such a solution.

  8. Baby fission chambers; Etude de chambres a fission miniatures

    Energy Technology Data Exchange (ETDEWEB)

    Guery, U; Tachon, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    The present report is intended, on the one band, as a study of the main types of fission chambers produced to date, and on the other, to deal more generally with this type of detector. Originally, it was with a view to the charting of neutron scatter in 'Proserpine' that the authors undertook the study of these chambers. During the course of the task, it was considered worth tbe trouble of developing its scope to include a more general application: neutron scatter measurement of various energy neutrons within a reduced volume with slight local disturbance. (author) [French] Le present rapport se propose, d'une part, d'exposer les principales realisations de chambres a fission, d'autre part de faire une mise au point a caractere plus general sur ces detecteurs. Au depart, c'est surtout en vue des mesures de densite neutronique dans 'Proserpine' que les auteurs ont etudie ces chambres; au cours de la mise au point, il a paru interessant de developper leur etude pour des applications plus generales: mesures de densites de neutrons de differentes energies dans un element de volume tres reduit et avec faible perturbation locale. (auteur)

  9. Baby fission chambers; Etude de chambres a fission miniatures

    Energy Technology Data Exchange (ETDEWEB)

    Guery, U.; Tachon, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    The present report is intended, on the one band, as a study of the main types of fission chambers produced to date, and on the other, to deal more generally with this type of detector. Originally, it was with a view to the charting of neutron scatter in 'Proserpine' that the authors undertook the study of these chambers. During the course of the task, it was considered worth tbe trouble of developing its scope to include a more general application: neutron scatter measurement of various energy neutrons within a reduced volume with slight local disturbance. (author) [French] Le present rapport se propose, d'une part, d'exposer les principales realisations de chambres a fission, d'autre part de faire une mise au point a caractere plus general sur ces detecteurs. Au depart, c'est surtout en vue des mesures de densite neutronique dans 'Proserpine' que les auteurs ont etudie ces chambres; au cours de la mise au point, il a paru interessant de developper leur etude pour des applications plus generales: mesures de densites de neutrons de differentes energies dans un element de volume tres reduit et avec faible perturbation locale. (auteur)

  10. Study of the integration of distributed generation systems in the grid: application in micro-grids; Etude de structures d'integration des systemes de generation decentralisee: application aux microreseaux

    Energy Technology Data Exchange (ETDEWEB)

    Gaztanaga Arantzamendi, H

    2006-12-15

    The present PhD deals with an original micro-grid concept and its application as a Renewable Energy Source's (RES) grid integration scheme. This micro-grid is composed of RES generators as well as support systems that incorporate additional functionalities in order to improve RES integration into the grid. According to this concept, two practical micro-grid applications have been studied in detail: a residential micro-grid and a wind farm supported by DFACTS systems (STATCOM and DVR). In both applications, the control structures which are implemented at different levels and applied to the different micro-grid elements have been developed, analyzed by means of off-line simulations and finally validated in real-time conditions with physical reduced-scale prototypes. (author)

  11. Fusion of multimodal medical images. Application to dynamic tri dimensional study of vertebral column; Fusion d`images medicales multimodales. Application a l`etude tridimensionnelle dynamique de la colonne vertebrale

    Energy Technology Data Exchange (ETDEWEB)

    Brunie, L

    1992-12-01

    The object of this thesis is to put in correspondence images coming from different ways. The area of application is biomedical imaging, particularly dynamic imaging in three dimensional calculations of spinal cord. The use of computers allows modeling. Then a study of validation by clinical experimentation on spinal cord proves the efficiency of the simulation.

  12. Thermodynamic and structural of the water - dodecane - bis(ethyl-2-hexyl) phosphoric acid and its sodium salt; Etude thermodynamique et structurale du systeme: eau - dodecane - acide bis(ethyl-2 hexyl) phosphorique et de son sel de sodium

    Energy Technology Data Exchange (ETDEWEB)

    Lovera, Jacqueline

    1985-12-20

    This research thesis reports the study of the appearance and disappearance of the 'third phase' obtained during the salification of the bis(ethyl-2 hexyl) phosphoric acid (HDEHP) diluted in dodecane, by sodium aqueous solutions. After a large bibliographical study on the properties of the intervening compounds (extraction of metallic cation by the acid, parameters influencing the 'third phase' appearance, surfactant properties, direct and inverse micelles, formation of para-crystalline phases), the author presents chemical experimental methods: liquid-liquid extraction tests, tests by the synthetic way, preparation of reactants, dosing method, methods of chemical analysis). Then, she reports and discusses experimental results in terms of determination of phase diagrams at 25 C, of composition by weight of the third phase, of influence of the apolar diluent, and of influence of the electrolyte. Physical experimental methods are then presented (differential calorimetric analysis, NMR, small angle X-ray scattering, light scattering, polarised light microscopy, constrained phase microscopy, photography, infrared spectroscopy, conductometry, transmission electron micrography, volumetric mass measurements, surface and interface tension measurements, viscoelasticity measurements) and their results are discussed and interpreted [French] Nous etudions l'apparition et la disparition de la 'troisieme phase' obtenue lors de la salification de l'acide bis(ethyl-2 hexyl) phosphorique - HDEHP - dilue dans le dodecane, par des solutions aqueuses de soude. Nous obtenons cinq resultats experimentaux essentiels: a - dans le systeme etudie, la troisieme phase n'apparait qu'au dela de la salification. La phase qui apparait est une phase aqueuse de soude diluee, se separant de la phase organique en equilibre avec le dodecane presente a la salification exacte. b - la disparition de la troisieme phase s'effectue par recombinaison des deux phases organiques: la 'phase organique lourde', contenant le sel de sodium de HDEHP - le NaDEHP -, de l'eau, du dodecane et tres peu de soude et la 'phase organique legere' qui est du dodecane pur. Elle se produit a des concentrations en soude aqueuse finale d'autant plus faibles que la solution organique initiale est plus concentree en HDEHP. c - les tetraedres NaDEHP - H{sub 2}O - Dodecane- HDEHP et NaDEHP - H{sub 2}O - Dodecane - NaOH sont etudies en detail: les sept faces sont tracees et les grandes zones d'equilibre interieures aux tetradedres sont detaillees. d - une synthese du NaDEHP est mise au point; le diagramme des phases NaDEHP - H{sub 2}O est trace dans toute la gamme de concentrations et une large gamme de temperatures. Des vesicules, des cristaux liquides lyotropes lamellaires, cubiques inverses et hexagonaux inverses sont determines, et leurs caracteristiques sont mesurees a temperature ambiante. e - des microemulsions existent dans les melanges NaDEHP - H{sub 2}O - Dodecane et NaDEHP - H{sub 2}O - Dodecane - HDEHP. Enfin, nous effectuons un parallele entre le role du 'modificateur', qui inhibe l'apparition de la troisieme phase, et celui du 'cosurfactant', qui favorise la transition des micelles aux microemulsions. (auteur)

  13. Thermodynamic study on the complexation of Trivalent actinide and lanthanide cation by N-donor ligands in homogeneous conditions; Etude thermodynamique de la complexation des ions actinide (III) et lanthanide (III) par des ligands polyazotes en milieu homogene

    Energy Technology Data Exchange (ETDEWEB)

    Miguirditchian, M

    2004-07-01

    Polydentate N-donor ligands, alone or combined with a synergic acid, may selectively extract minor actinides(III) from lanthanide(III) ions, allowing to develop separation processes of long-live radioelements. The aim of the researches carried out during this thesis was to better understand the chemical mechanisms of the complexation of f-elements by Adptz, a tridentate N-donor ligand, in homogeneous conditions. A thermodynamic approach was retained in order to estimate, from an energetic point of view, the influence of the different contributions to the reaction, and to acquire a complete set of thermodynamic data on this reaction. First, the influence of the nature of the cation on the thermodynamics was considered. The stability constants of the 1/1 complexes were systematically determined by UV-visible spectrophotometry for every lanthanide ion (except promethium) and for yttrium in a mixed solvent methanol/water in volume proportions 75/25%. The thermodynamic parameters ({delta}H{sup 0} {delta}{sup S}) of complexation were estimated by the van't Hoff method and by micro-calorimetry. The trends of the variations across the lanthanide series are compared with similar studies. The same methods were applied to the study of three actinide(III) cations: plutonium, americium and curium. The comparison of these values with those obtained for the lanthanides highlights the increase of stability of these complexes by a factor of 20 in favor of the actinide cations. This gap is explained by a more exothermic reaction and is associated, in the data interpretation, to a higher covalency of the actinide(III)-nitrogen bond. Then, the influence of the change of solvent composition on the thermodynamic of complexation was studied. The thermodynamic parameters of the complexation of europium(III) by Adptz were determined for several fractions of methanol. The stability of the complex formed increases with the percentage of methanol in the mixed solvent, owing to an increase of the entropic contribution. The solvent reorganization upon complexation seems to be the prominent process from the energetic point of view. (author)

  14. Study of the thorium phosphate-diphosphate (TPD) dissolution: kinetic aspect - thermodynamic aspect: analysis of the neo-formed phases; Etude de la dissolution du phosphate diphosphate de thorium: - aspect cinetique - aspect thermodynamique: analyse des phases neoformees

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, A.Ch

    2000-10-06

    The aim of this work is to study the aqueous corrosion of the thorium phosphate-diphosphate (TPD), of the formula Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}, in the framework of the actinides immobilization. In order to complete the anterior studies concerning solid solutions where thorium is substituted by a tetravalent ion (uranium (IV) or plutonium (IV)) in the TPD structure, compounds of thorium and neptunium phosphate-diphosphate, of formula Th{sub 4-x}Np{sub x}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}, have been prepared. Furthermore, a new chemical way of synthesis has been investigated in order to sinter solids solution of thorium and uranium phosphate-diphosphate (TUPD) in good conditions. The TPD dissolution study showed two principals steps. The first one corresponds to the control of element concentration by the material dissolution whereas the second corresponds to the formation of secondary precipitates for which thermodynamic equilibrium controls the concentration of the species in solution. Leaching tests have been performed varying several independent parameters in order to determine the TPD dissolution rate. The partial orders related to the protons or to the hydroxide ions have been found between 0.35 and 0.45 whereas the apparent dissolution rate constants are in the range 1.10{sup -5} for 9.10{sup -5} g.m{sup -2}.j{sup -1} for acidic and basic media. The neo-formed phases have been characterized after the dissolution of TPD and TUPD. We found that the TPD leaching in acidic medium leads to the formation of the crystallized thorium phosphate-hydrogen-phosphate (TPHP), of formula Th{sub 2}(PO{sub 4}){sub 2}(HPO{sub 4}), x H{sub 2}O, whereas the TUPD dissolution leads to the TPHP and an other compound, of formula (UO{sub 2}){sub 3}(PO{sub 4}){sub 2}, 5 H{sub 2}O. We calculated its solubility product which is in good agreement with those found in the literature. The phases formed during the leaching of solids containing plutonium; americium or curium (Th{sub 2-y}Pu{sub y}(PO{sub 4}){sub 2}(HPO{sub 4}), x H{sub 2}O; AmPO{sub 4}, x H{sub 2}O and CmPO{sub 4}, x H{sub 2}O) have not been characterized but their ionic products have been calculated. (author)

  15. Experimental and numerical study of two-phase flows at the inlet of evaporators in vapour compression cycles; Etude experimentale et numerique d'ecoulements diphasiques a l'entree des evaporateurs de cycles thermodynamiques

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, M

    2007-09-15

    Maldistribution of liquid-vapour two phase flows causes a significant decrease of the thermal and hydraulic performance of evaporators in thermodynamic vapour compression cycles. A first experimental installation was used to visualize the two phase flow evolution between the expansion valve and the evaporator inlet. A second experimental set-up simulating a compact heat exchanger has been designed to identify the functional and geometrical parameters creating the best distribution of the two phases in the different channels. An analysis and a comprehension of the relation between the geometrical and functional parameters with the flow pattern inside the header and the two phase distribution, has been established. A numerical simulations of a stratified flow and a stratified jet flow have been carried out using two CFD codes: FLUENT and NEPTUNE. In the case of a fragmented jet configuration, a global definition of the interfacial area concentration for a separated phases and dispersed phases flow has been established and a model calculating the fragmented mass fraction has been developed. (author)

  16. Determination of a PWR key neutron parameters uncertainties and conformity studies applications; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustible et applications aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2002-07-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and lifetime. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimised. (author)

  17. Determination of a PWR key neutron parameters uncertainties and conformity studies applications; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustible et applications aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2002-07-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and lifetime. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimised. (author)

  18. An experimental study of the thermal conductivity: application of EST 205 borehole of Meuse/Haute Marne site (ANDRA); Etude experimentale de la conductivite thermique: application au forage EST 205 du site de Meuse/Haute Marne (ANDRA)

    Energy Technology Data Exchange (ETDEWEB)

    Jorand, R

    2006-10-15

    The determination of the thermal properties of clayey rocks is fundamental for predicting the behaviour a radioactive waste geological repository, and geothermal and oil reservoirs. The main objectives of this thesis work were to 1) better understand the effects of the parameters controlling the thermal conductivity, 2) study to which extent the laboratory measurements can be extrapolated to the field, and 3) find relationships between the thermal conductivity and other quantities easier to measure on the field, e.g. the P- and S- wave velocities. The study was conducted on 24 cores of marls carbonates and argillites coming from the EST205 borehole of the M/HM site (ANDRA). After a complete characterisation of the samples, their thermal conductivities were measured using a stationary method. The borehole was drilled with a special oil-based mud to avoid damaging the argillites, and many logs were available. Hence, it is ideal to study the properties of clayey rocks and compare them with field data. The results show the major effect of the microstructure (mainly the particles orientation), which causes the important anisotropy of the thermal conductivity in the marls and argillites. For all lithologies, linear relationships between the conductivity and the P- and S- wave velocities were obtained. The application of this experimental law to the sonic log helped building a synthetic log of thermal conductivity. Finally, we developed a heat probe, which allows measurements in function of temperature and saturation. We showed with this method that the thermal conductivity increases quasi-linearly with the saturation in a sandstone and a carbonate samples. (author)

  19. Study of optically stimulated luminescence (OSL) for radiation detection. Application to an optical fibre {gamma}-radiation sensor; Etude de la luminescence stimulee optiquement (OSL) pour la detection de rayonnements: application a un capteur a fibre optique de rayonnement {gamma}

    Energy Technology Data Exchange (ETDEWEB)

    Roy, O. [CEA Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Electronique et d`Instrumentation Nucleaire]|[Paris-7 Univ., 75 (France)

    1998-12-31

    This work shows up the usefulness of the Optically Stimulated Luminescence (OSL) to resolve radioprotection problems. We study the use of OSL as a gamma dosimetric technique with respect to the ALARA`s concept (As Low As Reasonably Achievable). A new approach based on optical fibers and luminescent materials showing OSL properties (closely related to Thermoluminescence phenomena) is presented in order to improve the remote real time dosimetry monitoring. Like thermoluminescent materials (TLD), OSL materials can trap charges under an irradiation (UV, X, {gamma},...). Instead of heating, the charges trapped are released by light stimulation and produce a visible luminescence which amount is proportional to trap the `data stored` left by irradiation, enabling the dose measurement. The OSL phenomenon offers the same advantages as TLD plus the interesting possibility of a remote optical stimulation. The end-user objective deals with the development of a {gamma}-radiation Optical FIber Sensor (OFS) for dose measurement which can offer new functionalities based on OSL materials coupled with an optical fiber. Rare earth doped Alkaline Earth Sulphides (AES), BAFX:EU{sup 2+} (X = Cl, Br, I) and halogen alkaline have been studied (crystalline form, synthesis techniques, influence of dopants and color centers). Their characteristics are presented and extensively discussed. A specific experimental set-up to characterise various OSL phosphors has been developed. It allows the study of sensitivity, linearity, time decay behaviour of OSL signal and zeroing time. A joint study of OSL and TL has shown the technical limitations as well as the thermal fading and the origin of the long zeroing time. An Optical Fiber Sensor (OFS) based on OSL and using MgS:Sm has been developed for practical applications on nuclear fields. Its specifications are presented and discussed, moreover improvements are proposed. (author) 320 refs.

  20. Experimental and numerical study of flows in PEM fuel cell stacks for traction applications; Etude numerique et experimentale des ecoulements dans une pile a combustible de type PEM adaptable aux applications embarquees

    Energy Technology Data Exchange (ETDEWEB)

    Picot, D

    1998-07-01

    The problems with the optimization and design of proton exchange membrane fuel cells (PEMFC) are mainly based on the mastery of water and heat transfers inside the active cells. A theoretical and experimental discussion about this topic is proposed. The average sharing coefficients of the generated water are measured for 3 Nora fuel cells (1, 5 and 10 kW). The values obtained with nafion 117 are in agreement with the data of the literature, while the 40% generated water recovered inside the anode compartment with nafion 115 are unexpected. The difficulty to obtain a physical formulation of electro-osmosis does not allow to quantify this coefficient and leads to justify the limitations of use of the numerical codes on this topic. However, by separating the intrinsic parameters of the electrodes/membrane system and the global operation parameters of a cell, it is possible to extrapolate realistic humidification strategies. In the framework of the European project 'Fever', a systemic model of a 30 kW module for electric-powered vehicle has been developed. For an optimum energy integration of Nora fuel cells in volume-limited applications, it is necessary to separate the humidification sections of these modules. In the case where air is used as oxidant, the presence of nitrogen inside the anode compartment has been evidenced both in close and recirculation modes. In agreement with the literature data about nafion permeability, the nitrogen migration through the electrolyte is explained by the diffusion theory. A discussion about the interest of using both operational modes to maximize the energy efficiency is proposed. Finally, a simple-phase and double-phase numerical study with interface reconstruction is carried out using the resolution of Navier-Stokes equations in Eulerian formalism in order to consider the problems linked with the internal flows inside the collectors of Nora cells. (J.S.)

  1. Synthesis and study of nano-structured cellulose acetate based materials for energy applications; Synthese et etude de materiaux nanostructures a base d'acetate de cellulose pour applications energetiques

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, F

    2006-12-15

    Nano-structured materials have unique properties (high exchange areas, containment effect) because of their very low characteristic dimensions. The elaboration way set up in this PhD work consists in applying the classical processes for the preparation of aerogel-like materials (combining sol-gel synthesis and CO{sub 2} supercritical extraction) to cellulosic polymers. This work is divided in four parts: a literature review, the presentation and the study of the chemical synthesis that leads to cellulose acetate-based aerogel, the characterizations (chemical, structural and thermal) of the elaborated nano-materials, and finally the study of the first carbons that were obtained after pyrolysis of the organic matrix. The formulations and the sol-gel protocol lead to chemical gels by crosslinking cellulose acetate using a poly-functional iso-cyanate. The dry materials obtained after solvent extraction with supercritical CO{sub 2} are nano-structured and mainly meso-porous. Correlations between chemical synthesis parameters (reagent concentrations, crosslinking rate and degree of polymerisation) and porous properties (density, porosity, pore size distribution) were highlighted thanks to structural characterizations. An ultra-porous reference aerogel, with a density equals to 0,245 g.cm{sup -3} together with a meso-porous volume of 3,40 cm{sup 3}.g{sup -1} was elaborated. Once in granular shape, this material has a thermal conductivity of 0,029 W.m{sup -1}.K{sup -1}. In addition, carbon materials produced after pyrolysis of the organic matrix and after grinding are nano-structured and nano-porous, even if important structural modifications have occurred during the carbonization process. The elaborated materials are evaluated for applications in relation with energy such as thermal insulation (organic aerogels) but also for energy conversion and storage through electrochemical way (carbon aerogels). (author)

  2. Analysis of Simultaneous Gas-Liquid Flow Through an Orifice and Its Application to Flow Metering Etude de l'écoulement simultané d'un mélange gaz-liquide à travers un orifice et son application à la mesure du débit

    Directory of Open Access Journals (Sweden)

    Pascal H.

    2006-11-01

    Full Text Available The purpose of this article is to show a more accurate orifice equation for a two-phase flow, such a compressible mixture of gas and liquid. The orifice equation given here con be used for the measurement of a gas-liquid mixture of fine emulsions by the orificemeter method. From the thermodynamic point of view, an equation of state has been formulated which provides the relationship between the specific mass of the mixture and pressure, under conditions of adiabatic expansion. The results obtained enable the mass flow rates of gas and liquid ta be determined without separation of the phases, provided thot the gas liquid mass ratio is known. The critical pressure ratio corresponding ta sonic velocity is also determined. Cet article présente une relation plus précise pour l'écoulement d'un système à deux phases, tel qu'un mélange compressible gaz-liquide, à travers un diaphragme. Cette relation peut être utilisée pour des mesures de mélanges gaz-liquide très finement divisés, c'est-à-dire des émulsions ou brouillards, par la méthode du diaphragme en paroi mince. Du point de vue thermodynamique, on a formulé une équation d'état donnant la relation entre la masse spécifique du mélange et la pression dans des conditions d'expansion adiabatique. Les résultats obtenus per-mettent de déterminer le débit massique du gaz et du liquide, sans séparation des deux phases, à condition que le rapport de masse gaz-liquide soit connu. On détermine également le rapport de pression critique correspondantà la vitesse du son.

  3. Study of hydrogenated amorphous silicon devices under intense electric field: application to nuclear detection; Etude de dispositifs electroniques en silicium amorphe hydrogene sous fort champ electrique: application a la detection nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Ilie, A. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Direction des Technologies Avancees]|[Paris-11 Univ., 91 - Orsay (France)

    1996-12-31

    The goal of this work was the study, development and optimization of hydrogenated amorphous silicon (a-Si:H) devices for use in detection of ionizing radiation. Thick p-i-n devices, capable of withstanding large electric fields (up to 10{sup 6} V/cm) with small currents (nA/cm{sup 2}), were developed. To decrease fabrication time, films were made using the `He diluted` PECVD process and compared to standard a-Si:H films. Aspects connected to specific detector applications as well as to the fundamental physics of a-Si:H were considered: the internal electric field technique, in which the depletion charge was measured as a function of the applied bias voltage; study of the leakage current of p-i-n devices permitted us to demonstrate different regimes: depletion, field-enhanced thermal generation and electronic injection across the p layer. The effect of the electric field on the thermal generation of the carriers was studied considering the Poole-Frenkel and tunneling mechanisms. A model was developed taking under consideration the statistics of the correlated states and electron-phonon coupling. The results suggest that mechanisms not included in the `standard model` of a Si:h need to be considered, such as defect relaxation, a filed-dependent mobility edge etc...; a new metastable phenomenon, induced by prolonged exposure to a strong electric field, was observed and studied. It is characterized by marked decrease of the leakage current and the detector noise, and increase in the breakdown voltage, as well as an improvement of carrier collection efficiency. This forming process appears to be principally due to an activation of the dopants in the p layer; finally, the capacity of thick p-i-n a Si:H devices to detect ionizing radiation has been evaluated. We show that it is possible, with 20-50 micron thick p-i-n devices, to detect the full spectrum of alpha and beta particles. With an appropriate converter, neutron detection then becomes possible. (author). 137 refs.

  4. PENULISAN ETUDE-ETUDE MUSIK TALEMPONG UNGGAN (Sebuah Usaha Pembelajaran Musik Tradisi Berbasis Literatur

    Directory of Open Access Journals (Sweden)

    Asri MK

    2014-12-01

    Full Text Available “Talempong unggan”, a traditional music from Minangkabau community particularly in Unggan, Sumpur Kudus, Sijunjung Regency, West Sumatera Indonesia is classified into genre of “talempong duduak” (rea. Due to its special musical concept and the playing technics, this traditional music is selected as a practising course in the Karawitan Department of Indonesian Institute of Art (ISI Padang Panjang since 1993 till now. In a system of class learning with many students, Talempong Unggan definitely needs supporting methods and learning technics suitable for the course where the students can reach their maximum skills. All the melody of “talempong unggan” that has been made as a material of practice is transcribed to the system of numeric notation and rhythm motive of “gendang” and “aguang” which is written into signs and special notation. All of qualitative data is formulated into finding methods, technics and etude of learning ensamble of Talempong Unggan the traditional music that learned in Karawitan Department of ISI Padang Panjang. Key words: Talempong Unggan, Methods, Technics, Etude

  5. Study of the retention of fission products by a few common minerals. Application to the treatment of medium activity effluents (1962); Etude de la retention des produits de fission par quelques mineraux usuels. Application aux traitements d'effluents de moyenne activite specifique (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Auchapt, J M [Commissariat a l' Energie Atomique, Centre de Production de Plutonium, Marcoule (France). Centre d' Etudes Nucleaires

    1962-07-01

    The conditions in which strontium is fixed on calcite (the object of the Geneva report P/395 - USA - 1958) are more closely studied and the work is extended to five fission products present in the effluents, and to 17 common rocks and minerals. Although as it turns out this fixation is not suitable as a method of treating the S.T.E. effluents (i.e. those from the Effluent Treatment plant at Marcoule), the study shows that all the crystals considered are strongly contaminated by simple contact with the effluents. (author) [French] Les conditions de fixation du strontium sur la calcite (objet du rapport de Geneve P/395 - USA - 1958) sont approfondies et l'etude est etendue aux cinq produits de fission presents dans les effluents et a 17 roches et minerais courants. Bien qu'en definitive cette fixation se revele inutilisable comme procede de traitement d'effluents S.T.E. (Station de Traitement des Effluents, Marcoule), l'etude montre que tous les cristaux consideres se contaminent fortement par simple contact avec les effluents. (auteur)

  6. Aspects récents de la thermodynamique des solutions de polymères Recent Aspects of the Thermodynamics of Polymer Solutions

    Directory of Open Access Journals (Sweden)

    Dayantis J.

    2006-11-01

    Full Text Available On examine dans cet article différentes approches de la thermodynamique des solutions de polymères placées dans leur contexte historique. On rappelle d'abord le modèle du réseau de Flory-Huggins et on en souligne les déficiences. On traite ensuite brièvement de la mécanique statistique des solutions de polymères introduite par Prigogine en 1957 et on montre qu'elle constitue un progrès qualitatif par rapport à la théorie du réseau, mais qu'elle ne prévoit cependant pas de manière quantitative les propriétés de ces solutions. On montre ensuite que le concept de volume libre, qui permet un traitement simplifié de certaines quantités, permet également d'expliquer tout naturellement l'existence d'une deuxième température de séparation en phase lorsque l'on élève la température, propriété qui différencie les solutions de polymères des mélanges de liquidés simples. Enfin, dans une dernière partie, on mentionne brièvement les travaux récents de l'École de Paris, qui traite les solutions de polymères par analogie avec les transitions magnétiques. This article examines différent approaches ta the thermodynamics of polymer solutions set in their historical context. First of all, the Flory-Huggins network model is described and ifs deficiencies are pointed out. Then attention is briefly drawn to the statistical mechanics of polymer solutions as introduced by Prigogine in 1957, and this mechanics is shown to be a qualitative advance compared with the network theory, but it nonetheless does not quantitatively predict the properties of such solutions. It is then shown that the concept of free volume, enabling some quantifies to be treated in a simplified way, also serves to provide a quite natural explanation for the existence of a second phase separation temperature when the temperature is raised, i. e. a property that differentiates polymer solutions from simple liquid mixtures. In the final part, brief mention is made

  7. Thermodynamique de l'écoulement diphasique compressible à deux constituants de Fanno Thermodynamic of Two-Phase Two Component Compressible Fanno Type Flow

    Directory of Open Access Journals (Sweden)

    Attou A.

    2006-12-01

    Full Text Available Le comportement d'un fluide diphasique gaz-liquide lors d'un écoulement adiabatique à travers une conduite de section constante est étudié, dans cet article, du point de vue thermodynamique. En admettant le mélange diphasique homogène, le traitement des lois physiques de conservation permet de déduire analytiquement l'équation d'évolution du fluide et la manière dont celle-ci s'écarte de l'évolution isotherme. Sur les bases de la forme différentielle de cette équation et du second principe de la thermodynamique, les propriétés de cet écoulement sont discutées. La détermination de la limite de Fanno a permis de mettre en évidence l'existence d'une longueur maximale de conduite au-delà de laquelle l'écoulement considéré n'est plus possible. Cette longueur maximale est fonction du titre massique et des conditions initiales, c'est-à-dire les variables d'état et la vitesse à l'entrée. La cohérence des résultats est vérifiée en appliquant systématiquement ceux-ci à l'écoulement d'un gaz parfait. Cette théorie permet de comprendre et de justifier l'existence d'états d'écoulement dits multicritiques pour lesquels un formalisme physique est proposé. Elle est appliquée à des écoulements diphasiques à travers les circuits de décharge comportant des singularités géométriques telles que des élargissements brusques. Le présent modèle, basé sur le formalisme proposé pour la multicriticité, est validé au moyen de données expérimentales obtenues pour des relâchements quasi stationnaires d'azote pur et de mélange eau-azote à travers une ligne de décharge complexe comportant plusieurs élargissements brusques en cascade. Prédites par le modèle, la configuration critique et les valeurs du débit maximum et des variables de l'écoulement (pression et température à travers la ligne de décharge s'accordent avec succès avec les résultats expérimentaux. The behaviour of an adiabatic two-phase gas

  8. A study of the aptitude of soils under natural conditions to retain radiostrontium; Etude de la vocation des sols en place a la retention du radiostrontium

    Energy Technology Data Exchange (ETDEWEB)

    Bovard, P; Grauby, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Independently of the theoretical study of the propagation of radioactivity in the soil as a result of submersions or of radioactive rain, the authors have studied directly and practically how this radioactivity can vary in the actual soil. To this end a simple, rapid method has been perfected; it makes it possible to maintain for each soil sample the natural parameters (structure, humidity, etc.) without introducing boundary effects. In the laboratory, after charging the soil samples, part of the study of the propagation of radioactivity is done by autoradiography; finally, as a practical application, the study of an atomic site illustrates the methods described. (author) [French] Independamment de l'etude theorique de la propagation de la radioactivite dans le sol a la suite de submersions ou de pluies radioactives, les auteurs ont etudie directement et pratiquement comment pourrait evoluer cette radioactivite dans les sols en place. Pour cela, une methode simple et rapide a ete mise au point; elle permet de conserver pour chaque echantillon de sol, les parametres naturels (structure, humidite, etc...), sans introduire d'effets de paroi. En laboratoire, apres mise en charge des massifs preleves, une partie de l'etude de la propagation des radioelements est realisee par autoradiographie; enfin, une application pratique, l'etude d'un site atomique, illustre l'expose. (auteur)

  9. A study of the aptitude of soils under natural conditions to retain radiostrontium; Etude de la vocation des sols en place a la retention du radiostrontium

    Energy Technology Data Exchange (ETDEWEB)

    Bovard, P.; Grauby, A. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Independently of the theoretical study of the propagation of radioactivity in the soil as a result of submersions or of radioactive rain, the authors have studied directly and practically how this radioactivity can vary in the actual soil. To this end a simple, rapid method has been perfected; it makes it possible to maintain for each soil sample the natural parameters (structure, humidity, etc.) without introducing boundary effects. In the laboratory, after charging the soil samples, part of the study of the propagation of radioactivity is done by autoradiography; finally, as a practical application, the study of an atomic site illustrates the methods described. (author) [French] Independamment de l'etude theorique de la propagation de la radioactivite dans le sol a la suite de submersions ou de pluies radioactives, les auteurs ont etudie directement et pratiquement comment pourrait evoluer cette radioactivite dans les sols en place. Pour cela, une methode simple et rapide a ete mise au point; elle permet de conserver pour chaque echantillon de sol, les parametres naturels (structure, humidite, etc...), sans introduire d'effets de paroi. En laboratoire, apres mise en charge des massifs preleves, une partie de l'etude de la propagation des radioelements est realisee par autoradiographie; enfin, une application pratique, l'etude d'un site atomique, illustre l'expose. (auteur)

  10. Implementing Formative Assessment in Engineering Education: The Use of the Online Assessment System Etude

    Science.gov (United States)

    Dopper, Sofia M.; Sjoer, Ellen

    2004-01-01

    This article describes the possibilities offered by the online assessment system Etude to achieve the benefits of formative assessment. In order to find out the way this works in practice, we carried out an experiment with the use of Etude for formative assessment in the course on collaborative report writing. Results show that online formative…

  11. Density and electrical conductivity of molten salts. Comparative study of binary mixtures of alkali nitrates with silver nitrate and with thallium nitrate; Densite et conductibilite de sels fondus. Etude comparative des melanges binaires nitrates alcalins-nitrate d'argent et nitrates alcalins-nitrate de thallium

    Energy Technology Data Exchange (ETDEWEB)

    Brillant, S [Commissariat a l' Energie Atomique Saclay (France). Centre d' Etudes Nucleaires

    1967-10-01

    The choice of methods and the number of measurements made enable us to give results on the density and electrical conductivity of molten binary mixtures, alkali nitrate and silver nitrate, and alkali nitrate and thallium nitrate, in the form of equations. The deviations from linearity of the volume and the molar conductivity are determined by calculating the corresponding excess values whose variations are analyzed as a function of the Tobolsky parameter. The absence of any relationship in the sign of the entropy and the excess volume is justified. It is shown that the silver and thallium nitrates, in contrast to the thermodynamic properties, behave as the alkali nitrates in so far as the excess conductivity is concerned. This result is confirmed by the study of changes in the activation enthalpy for the partial molar conductivity; this study also shows the particular behaviour of lithium nitrate. (author) [French] Le choix des methodes et le nombre de mesures effectuees nous permettent de donner les resultats de densite et de conductibilite electrique des melanges fondus binaires nitrate alcalin-nitrate d'argent et nitrate alcalin-nitrate de thallium sous forme d'equations. Les ecarts a la linearite des isothermes de volume et de conductibilite molaire sont precises en calculant les grandeurs d'exces correspondantes dont les variations sont analysees en fonction du parametre de Tobolsky. Nous justifions l'absence de relation de signe entre l'entropie et le volume d'exces. Nous montrons que les nitrates d'argent et de thallium, vis-a-vis de la conductibilite d'exces, contrairement aux proprietes thermodynamiques, se conduisent comme les nitrates alcalins. Ce resultat est confirme par l'etude des variations des enthalpies d'activation de conductibilite partielle molaire qui met d'autre part en evidence le comportement particulier du nitrate de lithium. (auteur)

  12. Multiphase Production. Representation of Thermodynamic Properties of Methanol by Different Equations of State Production polyphasique. Représentation des propriétés thermodynamiques du méthanol à partir de différentes équations d'état

    Directory of Open Access Journals (Sweden)

    Peneloux A.

    2006-11-01

    , excessivement coûteuses. C'est la raison pour laquelle divers types de nouveaux additifs anti-hydrates sont en cours de mise au point et de test (en particulier à l'Institut Français du Pétrole (IFP. . . en complément à l'utilisation du méthanol. Il est clair, en effet, qu'en association avec ces nouveaux additifs, le méthanol restera d'un emploi courant en transport polyphasique et qu'il est donc indispensable de pouvoir mieux calculer et donc réduire les quantités de méthanol à utiliser dans ses diverses conditions d'emploi c'est-à-dire, en préventif comme en curatif. Ceci nécessite l'étude des mélanges complexes eau-hydrocarbures-méthanol et donc une bonne représentation préalable : - des équilibres entre phases des binaires eau-hydrocarbures, eau-méthanol et méthanol-hydrocarbures ; - des propriétés thermodynamiques des corps purs, et particulièrement de celles du méthanol. Cependant la recherche d'une équation d'état restituant correctement et simultanément la courbe de saturation et les données volumétriques du méthanol ne se fait pas sans embûches. En effet, un grand nombre d'auteurs se sont déjà intéressés au méthanol en utilisant différentes approches qui se sont révélées jusqu'à présent peu performantes (si l'on élimine les équations ne représentant qu'une seule grandeur thermodynamique : pressions de saturation, volumes liquides ou gazeux, etc. . Base de données : La mise au point de modèles thermodynamiques caractérisant le méthanol pur étant souvent fondée sur des méthodes d'ajustement de paramètres sur des données telles que les pressions de vapeur, les densités liquides et gazeuses à saturation (et quelquefois données volumétriques hors saturation, nous avons dû procéder à une recherche bibliographique exhaustive . Soucieux de la validité et du domaine d'application des équations d'état qui établissent une relation entre la pression, la température et le volume, nous avons jugé très important

  13. Complexation studies of actinides (U, Pu, Am) with linear polyamino-carboxylate ligands and sidero-chelates; Etudes de la chelation d'actinides (U, Pu, Am) par des ligands polyaminocarboxylate lineaires et des siderochelates d'interet environnemental

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, L.V.

    2010-11-25

    'aide de mesures par spectroscopie EXAFS (Extended X-ray Absorption Fine Structure) effectuees au synchrotron de l'ESRF. Ces travaux ont ete completes par des etudes thermodynamiques realisees en couplant des mesures potentiometriques et spectrophotometriques UV-Visible afin d'identifier la nature des complexes d'uranium(VI) et d'americium(III) formes en solution et d'evaluer leur stabilite. A l'aide des constantes d'equilibre, il est possible de simuler le diagramme de speciation dans les conditions de traitement des effluents du centre de Valduc et de definir ainsi une gamme de pH dans laquelle le ligand est efficace pour atteindre une decontamination 'ultime'

  14. 98 Etude Comparative du Systeme Phonematique et Tonal des ...

    African Journals Online (AJOL)

    98. Etude Comparative du Systeme Phonematique et Tonal des. Deux Parlers: Le Yoruba du Nigeria et L'itsa Parle en. Republique du Benin. Ajani Akinwumi Lateef et Ayuba G. Ajibabi http://dx.doi./org/10.4314/ujah.v18i3.5. Résume. En ce début de l'époque ou la mondialisation et la coexistence des peuples dans le ...

  15. Nuclear study of Melusine; Etude nucleaire de Melusine

    Energy Technology Data Exchange (ETDEWEB)

    Cherot, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In this report are reviewed - with respect to starting of experiments - the main nuclear characteristics of a 20 per cent enriched uranium lattice, with light water as moderator and reflector. The reactor is to operate at 1 MW. 1) Study of various critical masses. 2) Control. Effectiveness of cadmium. Control rods and of a stainless steel regulating rod. 3) Study of the effect on reactivity of disturbances in the core center. 4) Study of xenon and samarium poisoning. 5) Temperature factor. 6) Heat exchanges in a fuel element. (author) [French] On etudie, dans ce rapport, les principales proprietes nucleaires d'un reseau a uranium enrichi (20 pour cent), dont le moderateur et le reflecteur sont l'eau legere en vue des experiences de demarrage. Ce reacteur devra fonctionner a 1 MW. 1) Etude de diverses masses critiques. 2) Controle. Efficacite des barres de controle en cadmium et d'une barre de reglage en acier inoxydable. 3) Etude de l'effet sur la reactivite de perturbation au centre du coeur. 4) Etude de l'empoisonnement xenon et samarium. 5) Coefficient de temperature. 6) Echanges thermiques dans un element. (auteur)

  16. Etude d'un continuum de lumière en régime femtoseconde. Applications au domaine biologique : microscopies et spectroscopie en temps résolu.

    OpenAIRE

    Courvoisier , Céline

    2006-01-01

    For few years, a new type of source, called "continuum of light", has been developed. It presents many advantages like a wideband spectrum, a huge brilliancy, a pulsed nature. The aim of this work is to perform a complete characterization of a continuum generated by the injection of femtosecond pulses into a microstructured fiber, and to consider the use of this continuum as optical source for biomedical applications.With acousto-optic filters, the continuum has been successfully employed as ...

  17. Application of radioisotopes to the investigation of the kinetics and mechanism of reactions of some inorganic complex compounds; Application des radioisotopes a l'etude de la cinetique et du mecanisme des reactions de certains complexes inorganiques; Primenenie radioizotopov k issledovaniyam kinetiki i mekhanizma reaktsij nekotorykh neorganicheskikh slozhnykh soedinenij; Aplicacion de los radioisotopos al estudio de la cinetica y del mecanismo de las reacciones de algunos complejos inorganicos

    Energy Technology Data Exchange (ETDEWEB)

    Harris, Gordon M [Department of Chemistry, University of Buffalo, Buffalo 14, NY (United States)

    1962-03-15

    cyanide is an important end-product. (author) [French] Les radioisotopes sont particulierement precieux dans l'etude de nombreux types de reactions de chimie minerale, notamment de reactions ou interviennent des ions complexes en solution aqueuse. Les recherches sur la vitesse et le mecanisme des echanges isotopiques constituent un aspect important de ces applications. C'est ainsi qu'on a fait une serie d'etudes sur l'echange entre du carbonate ''libre'' marque au carbone-14 et le carbonate qui joue le role de coordinafc dans les ions complexes octaedriques du type CoA{sub 2}CO{sub 3}{sup +}, ou A represente le 2NH{sub 3}, ou l'ethylene-diamine (en), ou la propylene-diamine (pn) ou la trimethylene-diamine (tn). Grace aux etudes ainsi effectuees, on connait assez exactement la nature de ces reactions par substitution de coordinate, ainsi que le role joue par les coordinais amines qui ne participent pas a l'echange. Des etudes analogues sur l'echange entre oxalates dans les complexes tri-oxaliques de forme M (C{sub 2}O{sub 4}){sub 3}{sup 3-}, ou M=Co (III), Cr (III), ou Rh (III), n'ont pas ete moins fecondes en resultats. Une autre technique, applicable seulement lorsqu'on utilise des radioisotopes de faible poids atomique comme le carbone-14, consiste a observer les effets d'equilibre ou les effets cinetiques que les isotopes exercent sur la reaction etudiee. C'est ainsi qu'il a ete possible d'interpreter des differences dans le mecanisme d'echange du coordinat carbonate dans le Coen{sub 2}CO{sub 3}{sup +} et le Cotn{sub 2}CO{sub 3}{sup +}, par mesure de l'effet isotopique a l'etat d'equilibre dans la reaction d'echange des carbonates. De meme, des donnees sur l'effet isotopique cinetique dans l'hydratation avec catalyseur acide de l'ion Co(NH{sub 3}){sub 4}CO{sub 3}{sup +} ont confirme les deductions faites en ce qui concerne l'etape a laquelle se rompt la liaison, etape qui determine la vitesse de ces reactions. Enfin, la determination des positions successives de

  18. Developpement d'un modele thermodynamique pour les cristallites de coke: Application aux systems carbone-hydrogene et carbone-soufre

    Science.gov (United States)

    Ouzilleau, Philippe

    Carbon materials are essential components of multiple key industrial processes. One example of such a process is the production of aluminum using the Hall-Heroult process. It is well known that important quantities of carbon materials are regularily consumed by the operation of the Hall-Heroult process. In recent years, the increased impurity content of industrial carbon materials motivated the development of a better understanding for the high temperature behavior of these specific materials. The most common forms of carbon materials used in the industry are cokes. Cokes are carbon materials which, following heat treatment, present a crystalline structure similar to that observed in graphite. However, the observed crystallite size of cokes is usually much smaller than the one observed in graphite. For this reason, the chemical and thermodynamic properties of the ordered phase of cokes (i.e. coke crystallites) are very different than those of graphite (although coke crystallites of infinite size would possess properties almost identical to graphite). Coke crystallites consist of hexagonal planes of carbon atoms stacked one above the other. This particular aspect causes strong anisotropic properties in coke crystallites. No thermodynamic model was found for the production of a reliable correlation between the effect of crystallite size and chemical composition for the predictive calculations of the thermodynamic properties (and phase equilibriums) of coke crystallites. It is also difficult to produce predictive calculations that can be compared to experimental results using such a thermodynamic model. The goal of the present work is to propose a thermodynamic model designed to solve this problem. The present model is based on the well-defined geometrical properties of coke cristallites. This geometry allows the development of mathematical equations for the calculation of the mass balances of the crystallite (using a simplified geometry) using only the commonly used cristallite size parameters La (diameter of the crystallite) and Lc (height of the crystallite). The use of the Compound Energy Formalism is necessary to establish the methodology of the present model. Globally, the planar structure of the crystallites is divided into three sublattices on which individual chemical species are assumed to mix randomly. Appropriate thermodynamic paths are used to define the relative enthalpies and absolute entropies of these chemical species. The relative enthalpy and absolute entropy of the coke crystallites are derived for various values of La in the carbon/hydrogen and carbon/sulfur chemical systems. For the carbon/hydrogen system, the model parameters are based on the known values for the entropy of formation of simple hydrogenous organic compounds in the gaseous phase and known carbon/hydrogen bond enthalpies. Also, additional enthalpic properties of coke crystallites and graphitic structures are required for the definition of the thermodynamic paths (for example, the enthalpy associated with the delocalization of one electron in graphitic structures). Results for the carbon/hydrogen system are compared to experiments concerning the dehydrogenation of various cokes. A very satisfying agreement is obtained between the dehydrogenation curves predictively calculated by the model and the reported experimental results (obtained using slow heating rates). Most of the hydrogen content of coke crystallites (this content does not inclue the hydrogen in the condensed volatile matter phase) is predicted to leave the crystalline structure for temperatures between 1100 and 1300 K. Also, experimental measurements of the Gibbs energy of coke relative to graphite are reported. These measurements were obtained using a solid state electrochemical technique. A stabiliy of approximately 900 J g-1, relative to graphite, is reported for temperatures between 950 and 1250 K and for a crystallite size La of ˜10 nm. This value is in excellent agreement with the present thermodynamic model. Finally, an open discussion is made on the possible existance of a degraphitization behavior for coke crystallites heat treated above 2585 K. For the carbon/sulfur system, a modeling approach similar to the one developed for the carbon/hydrogen system is used. Approximately 75% of the model parameters of the carbon/hydrogen and carbon/sulfur systems are common to the two models. Predictive desulfurization curves using the current thermodynamic model are presented for temperatures above 1500 K. A very good agreement is obtained between the model calculations and the reported experimental data. Most of the sulfur content of coke crystallites is predicted to leave the crystallites for temperatures between 1600 and 1850 K. This temperature range is very similar to the puffing temperatures typically found during the desulfurization of petrochemical cokes. The good precision of the model for both studied systems (carbon/sulfur and carbon/hydrogen) combined with the transferability of the model parameters between the carbon/hydrogen and carbon/sulfur systems tend to validate the global approach developed so far.

  19. The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa

    Energy Technology Data Exchange (ETDEWEB)

    Tomilin, I A

    1962-01-15

    In this paper a method is suggested for determining the thermodynamic activity of antimony dissolved in alpha-iron, based on the study of antimony distribution between the two phases: liquid lead and solid iron. By this method, it was found that solid solutions of antimony in alpha-iron can be distinguished by positive divergences from the ideal state. Over a fairly wide range of concentrations, solutions of antimony in iron obey Henry's law. Special experiments on the distribution of antimony between lead and liquid iron showed that in the liquid state also the iron-antimony system is marked by positive divergences from the ideal state when small concentrations of antimony are present. The heat required for the solution of antimony in alpha-iron, and the excess partial molar entropy, were calculated from the activity temperature. The results were used for accurately locating the line showing the solubility limit of antimony in alpha-iron. Since alloys of antimony with iron were obtained by diffusion saturation and not by cooling from the liquid state, there was no liquefaction. Thus the lattice constant of the alloys and its relation to the alloy concentration could be reliably determined. The solubility limit established from X-ray data agrees with that obtained with Sb{sup 124}. (author) [French] Le memoire propose, pour determiner l'activite thermodynamique de l'antimoine dissous dans le fer alpha, une methode fondee sur l'etude de la distribution de l'antimoine entre deux phases: plomb liquide et fer solide. La methode a permis d'etablir que les solutions solides de l'antimoine dans le fer alpha se distinguent par des divergences positives par rapport a l'etat parfait. Dans une gamme assez etendue de valeurs de la concentration, les solutions de l'antimoine dans le fer sont regies par la loi de Henry. Des experiences sur la repartition de l'antimoine entre le plomb et le fer liquide ont montre qu'a l'etat liquide, le systeme ferantimoine est caracterise par

  20. Studies of high repetition rate laser-produced plasma soft-X-ray amplifiers; Etudes d'amplificateurs plasma laser a haute cadence dans le domaine X-UV et applications

    Energy Technology Data Exchange (ETDEWEB)

    Cassou, K

    2006-12-15

    The progress made as well on the Ti:Sa laser system, as in the control and the knowledge of laser produced X-UV sources allowed the construction of a X-UV laser station dedicated to the applications. My thesis work falls under the development of this station and more particularly on the characterization of a X-UV laser plasma amplifier. The experimental study relates to the coupling improvement of the pump infra-red laser with plasma within the framework of the transient collisional X-UV laser generation. These X-UV lasers are generated in a plasma formed by the interaction of a solid target and a laser pulse of approximately 500 ps duration, followed by a second infra-red laser pulse known as of pump (about 5 ps) impinging on the target in grazing incidence. For the first time, a complete parametric study was undertaken on the influence of the grazing angle on the pumping of the amplifying medium. One of the results was to reach very high peak brightness about 10{sup 28} ph/s/mm{sup 2}/mrad{sup 2}/(0.1%bandwidth), which compares well with the free-electron laser brightness. Moreover, we modified then used a new two-dimensional hydrodynamic code with adaptive mesh refinement in order to understand the influence of the space-time properties of the infra-red laser on the formation and the evolution of the amplifying plasma. Our modeling highlighted the interest to use a super Gaussian transverse profile for the line focus leading to an increase in a factor two of the gain region size and a reduction of the electron density gradient by three orders of magnitude. These improvements should strongly increase the energy contained in X-UV laser beam. We thus used X-UV laser to study the appearance of transient defects produced by a laser IR on a beam-splitter rear side. We also began research on the mechanisms of DNA damage induced by a very intense X-UV radiation. (author)

  1. Contribution to the study of diffusion in poly-phase system; Contribution a l'etude de la diffusion en systeme polyphase

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y; Philibert, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    this latter result and of the anomalies in the coefficient of diffusion should probably take into account the accumulation of reticular defects which would appear after displacement of the phase boundaries. (author) [French] Apres diffusion chimique entre deux metaux, a des temperatures auxquelles le diagramme d'equilibre indique l'existence de plusieurs phases, on observe, sur une section perpendiculaire au front de diffusion, des bandes paralleles correspondant a ces diverses phases. On sait que, dans ce cas, la courbe concentration-penetration presente alors une discontinuite a chaque interface. Les concentrations a l'aplomb de ces discontinuites donnent les limites de solubilites respectives des phases en presence. Au cours de nos essais relatifs au couple uranium-zirconium, nous avons verifie que ces concentrations ne varient pas avec la duree de diffusion et que, donc, les conditions de l'equilibre thermodynamique sont bien remplies. On dispose alors d'une methode interessante pour etablir le diagramme d'equilibre a l'etat solide, methode que nous avons appliquee au systeme U-Zr. Les etudes cinetiques de la diffusion polyphasee sont encore assez rares, par suite des difficultes experimentales. Aussi diverses methodes sont-elles proposees pour evaluer le coefficient de diffusion a partir d'etudes purement micrographiques (mesure des epaisseurs des phases intermediaires). Nos resultats experimentaux montrent que les hypotheses sur lesquelles sont basees ces methodes sont tres rarement valables. En effet, nous avons etabli les courbes concentration-penetration dans les systemes U-Zr (entre 590 deg. C et 950 deg. C), et U-MO (entre 800 deg. C et 1050 deg. C). Celles-ci montrent souvent des courbures tres accentuees, qui traduisent des variations du coefficient de diffusion qui ne peuvent pas s'exprimer suivant des relations simples. Enfin, nous avons observe certaines anomalies au voisinage des interfaces entre phases adjacentes. En outre, nous avons etudie l

  2. Contribution to the study of diffusion in poly-phase system; Contribution a l'etude de la diffusion en systeme polyphase

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y.; Philibert, J. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    this latter result and of the anomalies in the coefficient of diffusion should probably take into account the accumulation of reticular defects which would appear after displacement of the phase boundaries. (author) [French] Apres diffusion chimique entre deux metaux, a des temperatures auxquelles le diagramme d'equilibre indique l'existence de plusieurs phases, on observe, sur une section perpendiculaire au front de diffusion, des bandes paralleles correspondant a ces diverses phases. On sait que, dans ce cas, la courbe concentration-penetration presente alors une discontinuite a chaque interface. Les concentrations a l'aplomb de ces discontinuites donnent les limites de solubilites respectives des phases en presence. Au cours de nos essais relatifs au couple uranium-zirconium, nous avons verifie que ces concentrations ne varient pas avec la duree de diffusion et que, donc, les conditions de l'equilibre thermodynamique sont bien remplies. On dispose alors d'une methode interessante pour etablir le diagramme d'equilibre a l'etat solide, methode que nous avons appliquee au systeme U-Zr. Les etudes cinetiques de la diffusion polyphasee sont encore assez rares, par suite des difficultes experimentales. Aussi diverses methodes sont-elles proposees pour evaluer le coefficient de diffusion a partir d'etudes purement micrographiques (mesure des epaisseurs des phases intermediaires). Nos resultats experimentaux montrent que les hypotheses sur lesquelles sont basees ces methodes sont tres rarement valables. En effet, nous avons etabli les courbes concentration-penetration dans les systemes U-Zr (entre 590 deg. C et 950 deg. C), et U-MO (entre 800 deg. C et 1050 deg. C). Celles-ci montrent souvent des courbures tres accentuees, qui traduisent des variations du coefficient de diffusion qui ne peuvent pas s'exprimer suivant des relations simples. Enfin, nous avons observe certaines anomalies au voisinage des interfaces entre phases

  3. ETUDE STRUCTURELLE ET SPECTRES D’ABSORPTION DE Kr3+

    Directory of Open Access Journals (Sweden)

    A CHIKHAOUI

    2001-12-01

    Full Text Available Le présent travail, qui comporte deux étapes, est une étude théorique de l'agrégat de Krypton chargé une fois (Kr3+. La première étape est l'étude structurelle de Kr3+. L'hamiltonien modèle est développé dans le cadre de la méthode D.I.M (Diatomics In Molecules. Les résultats obtenus montrent que Kr3+ est linéaire. La profondeur du puits attractif De est égale  à 0.29 eV par rapport à la dissociation en Kr2+ + Kr pour une distance d'équilibre Re = 5.496 u.a. Ce résultat est en bon accord avec la valeur expérimentale qui vaut 0.27 eV. La deuxième étape est l'étude thermodynamique et spectroscopique de Kr3+. Les résultats obtenus montrent que le spectre vertical de Kr3+ linéaire comporte trois pics situés dans le domaine du visible à 625nm, 551nm et 466nm. L'analyse statistique des populations de charges atomiques montre que Kr3+ subit une isomérisation qui le ramène à une configuration de type ( Kr2+ ...Kr ou à une configuration plus probable de type  (Kr+...Kr2 .

  4. Contribution to the study of influences in emission spectrography on solutions. Application to a general analysis method for stainless steels (1961); Contribution a l'etude des influences en spectographie d'emission sur solution. Application a une methode generale d'analyse des aciers inoxydables (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Baudin, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1961-11-15

    In order to establish a general method of analysis of stainless steels, by means of spark spectroscopy on solutions, a systematic study has been made of the factors involved. The variations in acidity of the solutions, or in the ratio of concentrations of two acids at constant pH, lead to a displacement of the calibration curve. Simple relations have been established between the concentration of the extraneous elements, and the effects produced, for the constituents Fe, Ti, Ni, Cr, Mn; a general method using abacus is proposed for steels containing only these elements. The interactions in the case of the elements Mo, Nb, Ta, W, were more complex, so that the simultaneous separation was studied with the help of ion-exchange resins. A general method of analysis is proposed for stainless steels. (author) [French] En vue d'etablir une methode generale d'analyse des aciers inoxydables par spectrographie d'etincelles sur solution, on a effectue une etude systematique des influences. Les variations de l'acidite des solutions ou du rapport des concentrations de deux acides a pH constant, entrainent un deplacement des courbes d'etalonnage. On a etabli des relations simples entre la teneur des tiers elements et les effets produits pour les constituants Fe, Ti, Ni, Cr, Mn; une methode generale avec abaques est proposee pour les aciers contenant ces seuls elements. Les influences dans le cas des elements Mo, Nb, Ta, W etant plus complexes, on eut a etudier la separation simultanee a l'aide de resines echangeuses d'ions. On propose une methode generale d'analyse des aciers inoxydables. (auteur)

  5. The Preparation and Thermodynamics of Europium Dicarbide; Preparation et Thermodynamique du Bicarbure d'Europium; Poluchenie i termodinamicheskie svojstva dikarbida evropiya; Preparacion y Termodinamica del Dicarburo de Europio

    Energy Technology Data Exchange (ETDEWEB)

    Gebelt, R. E. [Oklahoma State University, Stillwater, OK (United States); Eick, H. A. [Michigan State University, East Lansing, MI (United States)

    1966-01-15

    determiner la concentration du bicarbure gazeux en fonction de la temperature. Apres avoir etalonne le spectrometre de masse au moyen de l'argent, il a ete possible de calculer les pressions correspondant aux intensites ioniques observees. Une equation empirique a ete ajustee aux donnees relatives a l'europium par la methode des moindres carres. En appliquant le deuxieme principe de la thermodynamique a la reaction, on a calcule les valeurs suivantes: EuC{sub 2} Rightwards-Harpoon-Over-Leftwards-Harpoon Eu(g) + 2C (graphite); {Delta}H{sup 0}{sub 298} = 51.09{+-}1.42kcal/mole; {Delta}H{sup 0}{sub 298} = 18.43 {+-} 1.75 e.u. Les auteurs ont determine des valeurs estimees de la fonction d'energie libre pour EuC{sub 2}(s) et les ont combinees avec les donnees publiees; ils ont ainsi obtenu pour la meme reaction, en se fondant sur le troisieme principe de thermodynamique, la valeur {Delta}H{sup 0}{sub 298} = 51.22 {+-} 0.80 kcal/mole. Ils ont combine les enthalpies obtenues pour la reaction de dissociation avec les donnees publiees sur l'enthalpie de vaporisation de l'europium et ont ainsi obtenu la valeur ci-apres pour Venthalpie type de la formation de EuC{sub 2} : {Delta}H{sub f(298)} = -9.17 {+-} 1.15 kcal/ mole. (author) [Spanish] Se preparo dicarburo de europio por reaccion entre europio metalico y grafito, en una bomba de acero inoxidable. Los analisis quimicos indican que la composicion media del producto puede representarse por la formula EuC{sub 1.87{+-}0.07}. El examen mediante difraccion de rayos X por polvos muestra que el compuesto posee una simetria tetragonal centrada en el cuerpo (grupo espacial D{sup 17}{sub 4}n-14/mmm) con parametros del reticulado a{sub 0} = 4.045 A; c{sub 0} = 6.645 A. El analisis cromato- grafico en fase vapor indica que el 98% del producto gaseoso proveniente de la hidrolisis acida del dicarburo de europio esta formado por acetileno. Estos datos analiticos, juntamente con los parametros del reticulado, indican que el dicarburo de europio se

  6. Étude des équilibres thermodynamiques des réactions de gazéification en vue de l'optimisation du rapport vapeur/comburant injecté dans un gazogène souterrain Study of Thermodynamic Equilibria in Gasification Reactions So As to Optimise the Steam/Oxidizer Ratio Injected Into an Underground Gas Generator

    OpenAIRE

    Pirard J. P.

    2006-01-01

    Le but de cette étude est de déterminer sur la base des équilibres thermodynamiques des réactions de gazéification le rapport vapeur/comburant à injecter dans un gazogène fonctionnant sous pression pour optimaliser les compositions, les pouvoirs calorifiques, les rendements de gazéification et la consommation d'agent gazéifiant. The aim of this study is to determine, on the basis of the thermodynamic equilibria of gazification reactions, the steam/oxidizer ratio to be injected into a gas g...

  7. Realisation and subsequent improvements of a progressive wave laser. Application to the study of HFA fluorescence; Realisation et mise au point d'un laser UV a onde progressive. Application a l'etude de la fluorescence de l'hexafluoroacetone

    Energy Technology Data Exchange (ETDEWEB)

    Petit, Alain

    1976-05-26

    different pressures and several observation wavelengths. This work confirms Ware's results: the lifetime is independent, within the experimental errors, of the HFA pressure over the range from 20 to 400 torr and has a mean value of 87 ± 2 ns (compared to Ware's value of 84 ± 2 ns). The measurements have been completed at different observation wavelengths (band pass: Δλ 6 nm). We also have checked that the lifetime is the same over the entire emission band in this pressure range. At low pressures (≤ 10 torr), however, with a new experimental arrangement, it has been seen that the apparent fluorescence lifetime begins to decrease with pressure at certain observation wavelengths, ranging from 80 ns at 70 torr to 56 ns at 0,5 torr. Our results are in good agreement with the photochemical mechanism proposed by Ware. (author) [French] Waynant, Shipman, Hogdson et Schafer ont recemment montre qu'il etait possible, en excitant un gaz avec une decharge electrique transversale et progressive, d'obtenir des emissions laser dans l'UV et l'UV lointain de courte duree. Ce dispositif experimental est connu sous le nom de laser a onde progressive. Jusqu'a present avec ce type de laser, des emissions stimulees ont pu etre observees dans les gaz suivants: N{sub 2} (C{sup 3}πu → B{sup 3}πg), CO(A{sup 1}π → X{sup 1}Σ), H{sub 2}[B{sup 1}Σ → X{sup 1}Σ) et H{sub 2}(C{sup 1}π → X{sup 1}Σ) situees respectivement a 337, 193, 160 et 120 nm. La brievete des impulsions obtenues et les longueurs d'onde emises par ce type de laser nous ont incites a construire un tel laser et a etudier ses caracteristiques. Notre laser se compose principalement d'un canal de 24 cm, limite en largeur par deux electrodes en acier en forme de T entre lesquelles s'effectue la decharge. L'etude des caracteristiques de ce laser a azote donne les resultats suivants: une mesure a basse resolution de l'emission laser, due a la bande 0-0 du systeme 2{sup e} positif de l'azote situee a 337.1 nm, montre que l

  8. Low-energy electron observation of graphite and molybdenite crystals. Application to the study of graphite oxidation; Observation au moyen d'electrons de faible energie de cristaux de graphite et de molybdenite. Application a l'etude de l'oxydation du graphite

    Energy Technology Data Exchange (ETDEWEB)

    David, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The LEED study of cleaved (0001) faces of crystals having a layered structure allowed to investigate flakes free of steps on graphite and molybdenite, to show twinning on natural graphite. By intensity measurements and computation in the case of a kinematical approximation it has been possible to determine an inner potential of 19 eV for graphite and to identify the direction of the Mo-S bond of the surface layer of molybdenite. The oxidation of graphite has been studied by observing changes, in symmetry of the diffraction patterns and by mass spectrometry of the gases evolved during the oxidation. No surface compounds have been detected and the carbon layers appeared to be peeled off one after the other. The oxidation took place at temperatures higher than 520 C under an oxygen pressure of 10{sup -5} torr. (author) [French] L'etude par diffraction des electrons lents des faces (0001) de cristaux ayant une structure en feuillet a permis de mettre en evidence des plages sans gradins sur des clivages de graphite et de molybdenite caracterisees par la symetrie ternaire des diagrammes, de montrer l'existence de macles sur des cristaux de graphite naturel. Un calcul utilisant une approximation cinematique a ete applique aux intensites mesurees des taches de diffraction; il a ete ainsi possible de determiner un potentiel interne de 19 eV pour le graphite et de preciser la direction de la liaison Mo-S du feuillet superficiel de la molybdenite. L'oxydation du graphite a ete etudiee en mettant en relation des changements de symetrie des diagrammes de diffraction avec l'analyse des gaz provenant de la reaction carbone-oxygene. Il a ete montre qu'il n'y avait pas formation de composes de surface et que les couches de carbone etaient enlevees les unes apres les autres. L'oxydation a ete observee sous une pression d'oxygene de 10{sup -5} torr au-dessus de 520 C. (auteur)

  9. The use radioactive tracers in the study of solid transport in water streams; Emploi de traceurs radioactifs pour l'etude du transport solide dans les cours d'eau

    Energy Technology Data Exchange (ETDEWEB)

    Courtois, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P; Heuzel, M [Laboratoire National d' Hydraulique de Chatou, 78 (France)

    1960-07-01

    The Laboratoire National d'Hydraulique which has been studying, during the last few years in conjunction with the Centre d'Etudes Nucleaires at Saclay, the development of apparatus and of methods of investigation of sediment transport by radioactive tracer techniques, is at the moment trying to perfect a genuinely quantitative method of investigation. Two experiments have recently been carried out in rivers, the first designed to investigate the transport of pebbles in the river Rhone, the other to investigate the movement of sands in the Niger. This second experiment has been supported by parallel experiments carried out on a reduced scale model of the Niger built at the laboratories of Chatou: in this experiment are used the radiation from {sup 56}Mn and {sup 24}Na obtained by direct activation of the crushed apricot store which represents, in the scale model, the natural sediment on the bed of the Niger. The combined efforts of the laboratories of Chatou and of the Centre d'Etudes Nucleaires at Saclay are at the moment directed to the application of radioactive tracers to studies on the scale models with the double aim: a) of having a single investigational method for the actual experiment and for the model making it possible to control the accuracy of the model in the preliminary stage of calibrating this model; b) of making the most of the possibilities of observation and of direct measurement offered by the scale models for studying the possibility of improving the tracer method, in particular with respect to the collecting of quantitative data. (author) [French] La Laboratoire National d'Hydraulique qui, depuis quelques annees a developpe, en collaboration avec le Centre d'Etudes Nucleaires de Saclay, les appareillages et les techniques d'etudes des mouvements de sediments par la methode des traceurs radioactifs, s'efforce actuellement de mettre au point un moyen d'investigation veritablement quantitatif. Deux experiences ont ete effectuees recemment en

  10. Treatment of effluent at the Saclay Centre d'Etudes Nucleaires (1960); Le traitement des effluents du Centre d'Etudes Nucleaires de Saclay (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Wormser, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The Centre d'Etudes Nucleaires at Saclay possesses several installations from which liquid radioactive effluent is rejected, and it has thus been found necessary to construct a station for the purification of radioactive liquids and to settle various chemical, analytical and technological problems. This report describes, in the following order: - the disposal possibilities at the Centre d'Etudes Nucleaires, Saclay, - the effluents produced at the centre, - the set-up for collecting effluent, - treatment of the effluent, - results of these treatments. (author) [French] La presence, au Centre d'Etudes Nucleaires de Saclay, de plusieurs installations susceptibles de rejeter des effluents liquides radioactifs a necessite la construction d'une station d'epuration d'eaux radioactives et la mise au point de differents problemes chimiques, analytiques et technologiques. Dans ce rapport, nous exposerons successivement: - les possibilites de rejet du Centre d'Etudes Nucleaires de Saclay, - les effluents du centre, - le dispositif de collecte des effluents, - le traitement de ces effluents, - les resultats de ces traitements. (auteur)

  11. Etudes sur le Portugal au Temps de l'Humanisme

    Directory of Open Access Journals (Sweden)

    J. Cruz Costa

    1953-06-01

    Full Text Available BATAILLON (Marcel. — Etudes sur le Portugal au Temps de l'Humanisme.  Acta Universitatis Conimbrigencis, 1952, 309 pp. (Primeiro Parágrafo do Artigo O Prof. Marcel Bataillon, erudito dos mais inteligentes da França atual, autor de uma obra que é hoje impr:scindível para quem pretenda estudar o humanismo renascentista na Espanha ou em Portugal, diríamos melhor, talvez: para quem pretenda estudar o Humanismo e a Renascença, — acaba de publicar, na coleção Acta Universitatis Conimbrigencis, êste volume no qual reune alguns trabalhos da mais alta importância para o conhecimento de muitos aspectos da vida espiritual portuguêsa do século XVI.

  12. Localization of alpha emitters by damage production in a thin film. Application to the study of alpha emitter diffusion in irradiated samples; Localisation des emetteurs alpha par creation de dommages dans un film mince. Application a l'etude de la diffusion des emetteurs alpha dans des echantillons irradies

    Energy Technology Data Exchange (ETDEWEB)

    Houdaille, B; Perrot, M [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    The process of recording {alpha} particles on cellulose nitrate films, called alpha-graphy, is applied to the study of the diffusion of {alpha}-emitting elements in irradiated alloys. The existence of diffusion is shown by attacking the film with concentrated caustic soda after exposition. The insensitivity of the recorder to {beta} {gamma} radiation emitted by the sample after passing in the reactor makes it possible to operate with long exposure times and to detect small diffusions. The concentration-penetration curves are drawn up after carrying out a densitometric analysis of the alpha-graphies. - As the cellulose nitrate is affected only by {alpha} particles of energies of between 0.5 and 4 MeV, it was first necessary to determine the yield of the recorder for {alpha} particles emitted by a thick source, i.e. whose energy varies between 0 and E{sub 0}, E{sub 0} being the energy of the alpha emitter. - The concentration C of the {alpha}-emitter, as a function of the optical density D of the alpha-graphy, and of the exposure time t is given by a simple relationship: C = D/at where a is an experimental constant determined by calibration. It depends on the nature of the cellulose nitrate, of the {alpha}-emitting element and of the alloy studied. (authors) [French] Le procede d'enregistrement des particules alpha sur film de nitrate de cellulose, ou alphagraphie, est applique a l'etude de la diffusion d'elements emetteurs alpha dans des alliages irradies. La diffusion est mise en evidence par une attaque du film de nitrate, apres exposition, dans de la soude concentree. L'insensibilite de l'enregistreur au rayonnement {beta} {gamma}, emis par l'echantillon apres son sejour en pile, permet d'operer sur de longs temps de pose et de detecter des diffusions faibles. Les courbes concentration - penetration sont etablies par exploitation densitometrique des alphagraphies. - Comme le nitrate de cellulose n'est impressionne que par des particules alpha dont l'energie est

  13. ETUDE DE LA DISTRIBUTION DES CATIONS ECHANGEABLES

    African Journals Online (AJOL)

    SEI Joseph

    En considérant alors le cas numérique, où l'observation du signal x (t) se résume à N valeurs échantillonnées à la période Te, la densité spectrale de puissance peut ...... "ANAFOR, une stratégie efficace d'acquisition et de traitement du signal pour la. RMN du solide", Méthodes, Applications, Perspectives, Evreux (2000).

  14. Preliminary study of the preparation of uranium 232 by irradiation of protactinium 231; Etude preliminaire a la preparation d'uranium 232 par irradiation de protactinium 231

    Energy Technology Data Exchange (ETDEWEB)

    Guillot, Ph. [Commissariat a l' Energie Atomique, Fontenay aux Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    A bibliography about preparation of uranium 232 is done. This even-even isotope of uranium is suitable for radioactive tracer, neutron source through {alpha},n reaction and heat source applications. The irradiation of protactinium 231, the chemical separation and the purification of uranium are studied. (author) [French] Une etude bibliographique de la preparation d'uranium 232 a ete effectuee. Cet isotope pair-pair de l'uranium peut etre utilise en tant que traceur, source d'energie et source de neutrons, lorsqu'il est melange a un element leger tel le beryllium. Une etude du taux de formation des isotopes produits, lors de l'irradiation du protactinium 231 - une des manieres d'obtenir l'uranium 232 - a ete faite a l'aide d'un programme passe sur ordinateur. Les problemes poses par la separation chimique et la purification de l'uranium ont ete egalement envisages dans ce rapport. (auteur)

  15. Technical Developments in the USAEC Process Radiation Development Program; Etudes technologiques dans le cadre du programme de mise au point d'applications industrielles des rayonnements de la CEA-EU; Issledovaniya v oblasti promyshlennogo primeneniya izluchenij, vkhodyashchie v programmu komissii po atomnoj ehnergii USAEC; Progresos tecnicos en el programa de la USAEC para el fomento de la irradiacion industrial

    Energy Technology Data Exchange (ETDEWEB)

    Machurek, J. E.; Stein, M. H. [Division of Isotopes Development, USAEC, Washington, DC (United States)

    1963-11-15

    A broad range of researches have been undertaken in the USAEC 'Process radiation development program'. The primary objective of these studies is to foster development of technology leading to the productive industrial use of ionizing radiation. Results of fourteen of these investigations are reported.some in outline in this paper and some in detail in these Proceedings. The subjects included are researches on: (1) Preparation of wood-plastic combinations using gamma radiation to induce polymerization. (2) Use of fission-product beta radiation for the hydrogenation of coal and coal products to produce liquid hydrocarbon fuels. (3) Production of semi-conductor devices with the formation of predetermined spacial distribution impurity patterns via neutron transmutation doping. (4) Radiation-induced polymerization of ethylene and copolymers. (5) Basic studies in radiation-induced reaction mechanisms and kinetics. (6) Radiation chemistry involved in the fluorination of various aromatic compounds. (7) Use of polyfunctional monomers for enhanced radiation cross-linking of polyethylene, polypropylene, polyisobutylene and cellulose acetate. (8) Effect of swelling, strain and temperature on the physical and chemical properties of radiation produced polymers. (9) Radiation-induced changes in polymers leading to graft copolymerization as influenced by structural factors. (10) The utilization of nuclear radiation for the modification of textile materials. (11) Radiation-induced reactions utilizing krypton-85. (12) The preparation of a ''Radiation Handbook''. (13) Use of the organometallic bond in high level gamma radiation dosimetry. (14) The development of a solar cell dosimeter. (author) [French] Des recherches tres diverses ont ete entreprises dans le cadre du programme de mise au point d'applications industrielles des rayonnements execute par la CEA-EU. Ce programme a pour but essentiel de favoriser le developpement de la technologie en vue d'un emploi industriel productif

  16. Etude de la corrosion de l’acier dans le nitrate de sodium à 340°C

    OpenAIRE

    Le , Thi-Kim-Khanh

    2016-01-01

    This thesis was originally performed as part of the STARS project (Stockage Thermique Appliqué à l’extension de Production d’énergie Solaire thermodynamique) which was supported by ADEME (l'Agence De l'Environnement et de la Maîtrise de l'Energie). The objective is to develop a thermal storage system using latent heat from a phase change material (PCM) in order to match with Fresnel technology using direct steam generation. Sodium nitrate (NaNO3) has been selected as PCM and low-alloy steel h...

  17. Contribution to the study of several chemical hazards in the Centre d'Etudes Nucleaires of Fontenay-aux-Roses; Contribution a l'etude de quelques nuisances chimiques au centre d'etudes nucleaires de Fontenay-aux-Roses

    Energy Technology Data Exchange (ETDEWEB)

    Megemont, C; Grau, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-10-01

    From the checking of 2750 index cards of hazards, the study relates the distribution of the chemical hazards in the Centre d'Etudes Nucleaires of Fontenay-aux-Roses. Those concerning the greatest number of agents in the Centre are classified according to the categories corresponding to the different conditions of working. Thus, the most important are put forward. Then, the authors rapidly make a review of hazards which may have some special interest because they appear more specific of the nuclear energy or because they are the most frequently noted on the index cards of hazards. The case of the tributylphosphate is studied more precisely. (authors) [French] A partir de l'examen de 2750 fiches de nuisances, l'etude porte sur la repartition des nuisances chimiques au Centre d'Etudes Nucleaires de Fontenay-aux-Roses. Celles qui concernent le plus grand nombre d'agents du Centre sont classees selon les categories correspondant aux differentes conditions de travail. Les plus importantes d'entre elles sont ainsi mises en evidence. | Les auteurs passent ensuite en revue, rapidement, les nuisances qui peuvent presenter un interet particulier soit parce qu'elles semblent plus specifiques de l'Energie Nucleaire, soit parce qu'on les rencontre le plus frequemment sur les fiches de nuisances. Le cas du tributylphosphate est envisage de facon plus detaillee. (auteurs)

  18. Etude de la qualité physico-chimique et biologique des eaux du ...

    African Journals Online (AJOL)

    Etude de la qualité physico-chimique et biologique des eaux du fleuve Niger à Niamey. ... le récepteur principal des rejets d'eaux usées de la ville de Niamey, capital du ... La description de ces taxons montre une variation de la structure des ...

  19. English Department Reforms at the Hautes Etudes Commerciales: Entering the Nineties.

    Science.gov (United States)

    Shanahan, Daniel

    1993-01-01

    Discusses the reforms made in the fall of 1990 in the English department at the Ecole Hautes Etudes Commerciales (Paris, France), which were based on the basis of a combination of literature-culture and second- and foreign-language acquisition pedagogical biases. (four references) (VWL)

  20. Contribution a l'etude des plantes alimentaires mineures dans la ...

    African Journals Online (AJOL)

    Contribution a l'etude des plantes alimentaires mineures dans la prefecture de Dankpen (Togo). AB Kebenzikato, S Akpavi, K Batawila, K Wala, M Dourma, K Kossi-Titrikou, KS Amouzou, I Butare, H Dantsey-Barry, K Akpagana ...

  1. 152 Etude de cas sur l'impact des amendements organiques vis-à ...

    African Journals Online (AJOL)

    john mukalay

    Etude de cas sur l'impact des amendements organiques vis-à-vis de la salinité en culture de bananier. Michel Mazinga KWEY1, Séverin Kalala BANZE2 et John Banza MUKALAY2*. 1Laboratoire des cultures in vitro, Département de phytotechnie, Faculté des sciences agronomiques,. Université de Lubumbashi, BP 1825, ...

  2. 186 Etude théorique du transport électronique par la simulation ...

    African Journals Online (AJOL)

    youness

    Choukria SAYAH et al. 186. Etude théorique du ... For that we carried out the microscopic simulations, based on the Monte. Carlo method. ... intervalles, piezoelectric as well as the interactions of alloy and on ionized impurities. ..... SAYA et al. 198. [5] - R. W. Hockney, J. W. Eastwood, "Computer simulation using particles",.

  3. Etude comparative de la flore aux abords des cours d'eau dans les ...

    African Journals Online (AJOL)

    Etude comparative de la flore aux abords des cours d'eau dans les zones hypo et hyper endémiques d'ulcère de Buruli en Côte d'Ivoire. C. Cisse Boni, E. Ehouman, D. Soro, M.W. Kone, A. Bakayoko, F. Dembele, K. Bauthire, M Dosso ...

  4. Étude des équilibres thermodynamiques des réactions de gazéification en vue de l'optimisation du rapport vapeur/comburant injecté dans un gazogène souterrain Study of Thermodynamic Equilibria in Gasification Reactions So As to Optimise the Steam/Oxidizer Ratio Injected Into an Underground Gas Generator

    Directory of Open Access Journals (Sweden)

    Pirard J. P.

    2006-11-01

    Full Text Available Le but de cette étude est de déterminer sur la base des équilibres thermodynamiques des réactions de gazéification le rapport vapeur/comburant à injecter dans un gazogène fonctionnant sous pression pour optimaliser les compositions, les pouvoirs calorifiques, les rendements de gazéification et la consommation d'agent gazéifiant. The aim of this study is to determine, on the basis of the thermodynamic equilibria of gazification reactions, the steam/oxidizer ratio to be injected into a gas generator operating under pressure so as to optimize the compositions, the heating values, the gasification efficiencies and the consumption of gasifying agent.

  5. Alecto 2 - interaction studies; Alecto 2 - etudes d'interaction

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, J P; Clouet d' Orval, Ch; Mougniot, J C; Penet, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    Weak interactions were experimentally studies with the tank of the critical assembly Alecto II and one, two or three bottles containing solutions of various concentrations. In particular, was studied the validity of certain classical assumptions, shielding effects, screening and semi-reflexion effects, importance of thermal coupling. The method of the 'k{sub eff}, solid angle' is shown to apply to such a system. The determination by divergence and pulsed neutron technique of the reactivity related to a millimeter of solution level affords the obtention of critical heights in terms of reactivity. (authors) [French] Une etude experimentale d'interactions faibles a ete faite entre la cuve de l'experience critique ALECTO II et une, deux ou trois bouteilles contenant des concentrations variees. On etudie, en particulier, la validite de certaines hypotheses classiques, effets d'ombre, d'ecrans, de semi-reflexion, importance du couplage thermique. On montre d'autre part que la methode du 'K{sub eff}, angle solide' peut s'appliquer a un tel systeme. La determination par divergence et neutrons pulses de la reactivite liee au millimetre de solution permet de traduire les hauteurs critiques obtenues, en terme de reactivite. (auteurs)

  6. SEPA (Service d'etudes, de Procedes et Analyses)

    International Nuclear Information System (INIS)

    2017-01-01

    The SEPA (Service d'etudes, de Procedes et Analyses), is an engineering department specializing in the analysis and processing of uranium ore. It comes from a long tradition of mining in France that began sixty-five years ago with the French Atomic Energy Commission (CEA) and that has been carried on by COGEMA and then Areva. SEPA brings a combination of experience and excellence to its activities thanks to its multidisciplinary staff (mineralogists, chemists, mechanical engineers, instrumentation specialists...), who come from diverse cultural backgrounds. Today, the SEPA draws on its wealth of know-how and expertise to devise and develop new methods for processing and valorizing ores everywhere in the world. Its mission is to: - Develop and conduct laboratory tests on methods for processing uranium and other valuable elements such as molybdenum, vanadium, rare earths, niobium, tantalum and thorium; - Analyze ores obtained during prospecting at locations all over the world; -Serve as an advisor in the commissioning of Areva industrial units and ore processing plants; -Perform environmental analyses during the full period of mining operations; -Conduct audits and provide advice on processes and analysis methods; -Carry out research and development in all aspects of minerals treatment (including the filing of patents). The SEPA combines experience, skills and a global approach to technologies used in ore processing. Its role is to continually improve the processes for extracting, processing and valorizing ores while protecting the environment

  7. A review of micro-wave techniques in plasma studies; Survol des techniques micro-ondes pour l'etude des plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Consoli, T [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The problem of the application of micro-wave techniques to the study of plasma properties is considered in this report. In section I, the author summarizes a few fundamental laws concerning the theory of waves in an ionised medium as well as measurable effects of transverse and longitudinal propagation. Section II is a rapid review of the experimental methods and of the various measurements which may be effected in very high frequency plasmas. Only recent experimental work carried out since the last U. R.S.I. Assembly is considered. Section III is devoted to micro-wave techniques developed during this period in the laboratories of the Applied Physics Service. These techniques deal with longitudinal propagation and in particular with the propagation along a right mode. Section IV is a general view of similar studies undertaken in European Research Centres working on plasma physics or controlled fusion. Section V is a contribution concerning three particular topics from the Juelich and Max Planck Institute laboratories. (author) [French] On etudie dans ce rapport le probleme de l'application des techniques micro-ondes a l'etude des proprietes d'un plasma. Dans la section I, l'auteur rappelle rapidement quelques lois fondamentales de la theorie des ondes dans un milieu ionise ainsi que les effets mesurables en propagation transversale et longitudinale. La section II est une revue rapide des methodes experimentales et des diverses mesures qui peuvent etre faites dans les plasmas aux tres hautes frequences. On ne considere seulement que les etudes experimentales recentes depuis la derniere assemblee de l'U.R.S.I. La section III est consacree aux techniques hyperfrequences developpees durant la meme periode dans les laboratoires des Services de Physique Appliquee. Ces techniques se rapportent a la propagation longitudinale et particulierement a la propagation suivant le mode droit. La section IV est un panorama de travaux similaires entrepris dans les centres europeens

  8. Contribution to the theoretical study of the thermal diffusion of point defects in metals; Contribution a l'etude theorique et experimentale de la thermodiffusion de defauts ponctuels dans les metaux

    Energy Technology Data Exchange (ETDEWEB)

    Gerl, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-01-01

    An experimental study of diffusion under a thermal gradient shows that the heat of transport Q-bar* for self-diffusion in the noble metals is very low (a few hundredths of I eV) and relatively large in Fe{alpha} (+ 1,7 {+-} 0,8 eV). The apparent heat of transport of Sb in Cu, measured by the 'thin layer technique' is -0.21 {+-}0,05 eV.The influence of the density of sources and sinks of vacancies on the observed vacancy flux is determined by a calculation involving the thermodynamics of irreversible processes; when the mean distance between sources and sinks is larger than a certain limiting value, the vacancy flux vanishes.The contribution to the heat of transport of electron-defect (q*e) and phonon-defect (q*p) collisions is calculated using a semi-classical approach and by a quantum mechanical method; q*e is related to the resistivity {delta} -{rho}{sub d} and to the thermoelectric power of the defect at its stable position and at its saddle-point. A relation between q*e and the effective valency Z* of the defect allows a determination of {delta}{sub {rho}}{sub d} at the saddle-point. Numerical values of q*e are given for some impurities in noble metals. (author) [French] L'etude experimentale de la diffusion sous gradient de temperature montre que la chaleur de transport d'autodiffusion des metaux nobles est tres faible (quelques centiemes d'eV), alors que celle de Fe{alpha} est relativement elevee (+1,7 {+-} 0,8 eV). La chaleur de transport apparente de Sb dans Cu, mesuree par la technique de la couche mince, est (-0.21 {+-} 0.05 eV). L'influence de la densite de sources et puits de lacunes sur le flux de lacunes observe est determinee en appliquant le formalisme de la thermodynamique des processus irreversibles; si la distance moyenne entre sources et puits excede une certaine valeur limite, le flux de lacunes devient pratiquement nul. La contribution des chocs electrons-defaut (q*e) et phonons-defaut (q*p) a la chaleur de transport,est calcul theoriquement a

  9. Contribution to the theoretical study of the thermal diffusion of point defects in metals; Contribution a l'etude theorique et experimentale de la thermodiffusion de defauts ponctuels dans les metaux

    Energy Technology Data Exchange (ETDEWEB)

    Gerl, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-01-01

    An experimental study of diffusion under a thermal gradient shows that the heat of transport Q-bar* for self-diffusion in the noble metals is very low (a few hundredths of I eV) and relatively large in Fe{alpha} (+ 1,7 {+-} 0,8 eV). The apparent heat of transport of Sb in Cu, measured by the 'thin layer technique' is -0.21 {+-}0,05 eV.The influence of the density of sources and sinks of vacancies on the observed vacancy flux is determined by a calculation involving the thermodynamics of irreversible processes; when the mean distance between sources and sinks is larger than a certain limiting value, the vacancy flux vanishes.The contribution to the heat of transport of electron-defect (q*e) and phonon-defect (q*p) collisions is calculated using a semi-classical approach and by a quantum mechanical method; q*e is related to the resistivity {delta} -{rho}{sub d} and to the thermoelectric power of the defect at its stable position and at its saddle-point. A relation between q*e and the effective valency Z* of the defect allows a determination of {delta}{sub {rho}}{sub d} at the saddle-point. Numerical values of q*e are given for some impurities in noble metals. (author) [French] L'etude experimentale de la diffusion sous gradient de temperature montre que la chaleur de transport d'autodiffusion des metaux nobles est tres faible (quelques centiemes d'eV), alors que celle de Fe{alpha} est relativement elevee (+1,7 {+-} 0,8 eV). La chaleur de transport apparente de Sb dans Cu, mesuree par la technique de la couche mince, est (-0.21 {+-} 0.05 eV). L'influence de la densite de sources et puits de lacunes sur le flux de lacunes observe est determinee en appliquant le formalisme de la thermodynamique des processus irreversibles; si la distance moyenne entre sources et puits excede une certaine valeur limite, le flux de lacunes devient pratiquement nul. La contribution des chocs electrons-defaut (q*e) et phonons-defaut (q*p) a la chaleur de

  10. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P; Accary, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  11. Overview of the use of refrigerating fluids in thermodynamical machines; Panorama de l`utilisation des fluides frigorigenes dans les machines thermodynamiques

    Energy Technology Data Exchange (ETDEWEB)

    Bernier, J. [Syrec SA (France)

    1996-12-31

    The R-22 refrigerant has been used as a substitute of chlorofluorocarbons in refrigerating machineries but its use will become prohibited very soon. This paper raises the problem of its replacement by other HFC or natural fluids. The problem of natural fluids like ammonia or propane concerns their toxicity, flammability and explosion risk. If a regulation about the greenhouse effect is defined, the performance of the installation will be the decisive parameter for the choice of a refrigerant. R-22 fluid has multiple applications from air-conditioning systems to freezing tunnels and the most suitable substitutes will be different from one application to the other. The different criteria that influence the choice of a refrigerating fluid are: the condensation pressure, the delivery temperature, the compressor volume efficiency, the volume refrigerating power, the coefficient of performance, the variation of vaporization temperature, the global greenhouse effect, the toxicity, flammability and explosive character. A comparison between several fluids has been performed with a single-stage airtight compressor of 10 m{sup 3}/h, at a 40 deg. C constant condensation temperature, a 5 deg. C overheating and a 3 deg. C under-cooling. (J.S.) 6 refs.

  12. Etude aerodynamique d'un jet turbulent impactant une paroi concave

    Science.gov (United States)

    LeBlanc, Benoit

    Etant donne la demande croissante de temperatures elevees dans des chambres de combustion de systemes de propulsions en aerospatiale (turbomoteurs, moteur a reaction, etc.), l'interet dans le refroidissement par jets impactant s'est vu croitre. Le refroidissement des aubes de turbine permet une augmentation de temperature de combustion, ce qui se traduit en une augmentation de l'efficacite de combustion et donc une meilleure economie de carburant. Le transfert de chaleur dans les au bages est influence par les aspects aerodynamiques du refroidissement a jet, particulierement dans le cas d'ecoulements turbulents. Un manque de comprehension de l'aerodynamique a l'interieur de ces espaces confinees peut mener a des changements de transfert thermique qui sont inattendus, ce qui augmente le risque de fluage. Il est donc d'interet pour l'industrie aerospatiale et l'academie de poursuivre la recherche dans l'aerodynamique des jets turbulents impactant les parois courbes. Les jets impactant les surfaces courbes ont deja fait l'objet de nombreuses etudes. Par contre des conditions oscillatoires observees en laboratoire se sont averees difficiles a reproduire en numerique, puisque les structures d'ecoulements impactants des parois concaves sont fortement dependantes de la turbulence et des effets instationnaires. Une etude experimentale fut realisee a l'institut PPRIME a l'Universite de Poitiers afin d'observer le phenomene d'oscillation dans le jet. Une serie d'essais ont verifie les conditions d'ecoulement laminaires et turbulentes, toutefois le cout des essais experimentaux a seulement permis d'avoir un apercu du phenomene global. Une deuxieme serie d'essais fut realisee numeriquement a l'Universite de Moncton avec l'outil OpenFOAM pour des conditions d'ecoulement laminaire et bidimensionnel. Cette etude a donc comme but de poursuivre l'enquete de l'aerodynamique oscillatoire des jets impactant des parois courbes, mais pour un regime d'ecoulement transitoire, turbulent

  13. Impact of the lubricating oil on thermodynamic performances of reversible heat pumps; Impact de l'huile de lubrification sur les performances thermodynamiques des pompes a chaleur reversibles

    Energy Technology Data Exchange (ETDEWEB)

    Youbi-Idrissi, M

    2003-12-01

    This work deals with the effect of oil on the energy performances of refrigerating systems. To characterise this impact, two thermodynamic properties were studied: the solubility and the enthalpy. Thus, a simple measurement method was presented, allowing to study both transient and steady-state behaviour of various refrigerant/oil pairs. Thus, experimental data were validated and modelled. The suitable use of the solubility curves showed the zeotropic character of the refrigerant/oil mixture, which is directly reflected on the enthalpy calculation. For this property, a thermodynamic model was developed and experimentally validated. Its application led to a new presentation of the Mollier diagram taking into account the oil presence. It was then shown that, among all the circuit elements, the evaporator is the most penalized by the oil presence. Its performances decrease when the circulating mass fraction of oil increases, the superheat decreases and when the refrigerant-oil solubility increases. An experimental study on a reversible heat pump confirmed that if the circulation mass fraction of oil in the machine is lower than 2%, the impact of oil is reduced. Lastly, a local model of a refrigerating unit, initially charged with a zeotropic mixture, allowed to analyse the profiles of temperature, heat transfer coefficient and local composition of the refrigerant along a circuit. (author)

  14. Time-of-flight spectrometer for slow neutrons in use at the reactor in Saclay. Its application for the study of the inelastic diffusion of cold neutrons; L'appareillage de spectrometrie a temps-de-vol pour neutrons lents en service a la pile de Saclay. Son application a l'etude de la diffusion inelastique des neutrons froids

    Energy Technology Data Exchange (ETDEWEB)

    Jacsot, B; Netter, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Galula, M [Centre National de la Recherche Scientifique (CNRS), 91 - Gif-sur-Yvette (France)

    1955-07-01

    The time-of-flight spectrometers is constituted of a mechanic swivel obturator which absorbs neutrons until energies above 1 KeV, a mechanic filter which allow to retain only high wave length components and a delayed pulses selector with 100 channels. Its main application field is the thermic region where it allowed to measure the inelastic scattering of neutrons using various materials as H{sub 2}O, D{sub 2}O, Be, BeO, etc... (M.P.)

  15. Study of a micro-sublimation apparatus with removal of the vapours by pumping; application to the analysis of fluorinated products (1963); Etude d'un appareillage de microsublimation avec entrainement des vapeurs par pompage et application a l'analyse des produits fluores (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Delvalle, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Micro-sublimation analysis presents definite advantages both from the qualitative and quantitative points of view. An automatic micro-sublimation analysis apparatus has been developed for the analysis of fluorinated products (ClF{sub 3}, HF, UF{sub 6}, etc.) but this is only one particular application of a method which has a far wider field of possible applications. We give first the most favorable conditions for the operation of such an apparatus. These conditions are the use of a detector which is linear and independent of the nature of the gas, the flow of the sublimed vapours in the conditions of molecular flow, and finally a reproducible and linear re-heating of the separating trap. The apparatus thus built has the advantage of yielding any analysis without prior calibration. It also makes possible the easy identification of an unknown product by the determination of its vapour pressure curve and its molecular weight. The analysis of fluorinated products with this apparatus has shown that the experimental results agree well with what is expected. (author) [French] L'analyse par microsublimation presente un interet certain tant au point de vue qualitatif que quantitatif. Nous avons mis au point un appareillage automatique d'analyse par microsublimation pour l'analyse des produits fluores (CIF{sub 3}, HF, UF{sub 6}, etc.) mais il ne s'agit que de l'application a un cas particulier d'une methode ayant un champ d'applications bien plus vaste. Nous exposons tout d'abord les conditions les plus favorables au bon fonctionnement d'un tel appareil. Ces conditions sont l'emploi d'un detecteur lineaire et independant de la nature du gaz, l'ecoulement des vapeurs sublimees en regime moleculaire et enfin un rechauffage reproductible et lineaire du piege separateur. L'appareil ainsi realise presente l'avantage d'effectuer une analyse quelconque sans etalonnage prealable. Il permet en outre d'identifier aisement un corps inconnu par la determination de sa courbe de tension

  16. Resonant ionization by laser beams: application to ions sources and to study the nuclear structure of radioactive tellurium isotopes; Ionisation resonante par faisceaux laser: application aux sources d'ions et a l'etude de la structure des noyaux radioactifs de tellure

    Energy Technology Data Exchange (ETDEWEB)

    Sifi, R

    2007-07-15

    The radioactive ion beams that are produced through current isotope separators are well separated according to the A mass but not according to the Z parameter. The resonant ionization through laser beams applied to ion sources allows the production of radioactive ion beam in a very selective and efficient way by eliminating the isobaric contamination. The first chapter is dedicated to the resonant ionization by laser beams, we describe the principle, the experimental setting, the lasers used, the ionization schemes and the domain of application. The second chapter deals with the application of resonant ionization to laser ion sources for the production of radioactive ion beams. We present experimental tests performed for getting copper ion beams. Resonant ionization through laser is also used in the spectroscopy experiments performed at the Isolde (isotope separation on-line device) installation in CERN where more than 20 elements are ionized very efficiently. The technique is based on a frequency scanning around the excitation transition of the atoms in order to probe the hyperfine structure. Laser spectroscopy allows the determination of the hyperfine structure as well as the isotopic shift of atoms. In the third chapter the method is applied to the spectroscopy of tellurium atoms. First, we define the 2 parameters on which the extraction is based: charge radius and nuclear moments, then we present several theoretical models that we have used to assess our experimental results. (A.C.)

  17. Thermodynamical study of the vanadium-hydrogen system. The hydrogen effect on the mechanical properties of V-4Cr-4Ti and V-5Cr-5Ti alloys; Etude thermodynamique du systeme vanadium-hydrogene. Effets de l'hydrogene sur les proprietes mecaniques des alliages V-4Cr-4Ti et V-5Cr-5Ti

    Energy Technology Data Exchange (ETDEWEB)

    Coulombeaux, O

    1998-07-01

    In the framework of the international research programs on fusion reactors, the vanadium alloys are among the most appropriate candidate to constitute the first wall. The author deals with the specific alloys V-4Cr-4Ti and V-5Cr-5Ti and study the hydrogen diffusion. Experimental results show that the induced hydrogen concentration in the sample by diffusion is higher, for the same partial pressure of exposure, in the case of the alloy than for the pure vanadium. He shows that this result can be explainedby the trapping for which the hydrogen is trapped by the titanium. (A.L.B.)

  18. Quantum molecular dynamics: Numerical methods and physical study of the structure, thermodynamics, stability and fragmentation of sodium metallic clusters; Dynamique moleculaire quantique: Methodes numeriques et etude physique de la structure, de la thermodynamique, de la stabilite et de la fragmentation des agregats metalliques de sodium

    Energy Technology Data Exchange (ETDEWEB)

    Blaise, Philippe [Universite Joseph Fourier, Grenoble 1, 74 Annecy (France)

    1998-09-29

    The aim of this thesis is to study metallic sodium clusters by numerical simulation. We have developed two ab initio molecular dynamics programs within the formalism of density functional theory. The first is based on the semi-classical extended Thomas-Fermi approach. We use a real-space grid and a Car-Parrinello-like scheme. The computational cost is O(N), and we have built a pseudopotential that speeds up the calculations. By neglecting quantum shell effects, we are able to study a very large set of clusters. We show that sodium cluster energies fit well a liquid drop formula, by adjusting a few parameters. We have investigated breathing modes, surface oscillations and the net charge density. We have shown that the surface energy varies strongly with temperature, and that clusters have a lower melting point than bulk material. We have calculated fission barriers by a constraint method. The second program is based on the quantum Kohn-Sham approach. We use a real-space grid, and combine a generalized Broyden scheme for assuring self-consistency with an iterative Davidson-Lanczos algorithm for solving the Eigen-problem. The cost of the method is much higher. First of all, we have calculated some stable structures for small clusters and their energetics. We obtained very good agreement with previous works. Then, we have investigated highly charged cluster dynamics. We have identified a chaotic fission process. For high fissility systems, we observe a multi-fragmentation dynamics and we find preferential emission of monomers on a characteristic time scale less than a pico-second. This has been simulated for the first time, with the help of our adaptive grid method which follows each fragment as they move apart during the fragmentation. (author) 87 refs., 57 figs., 4 tabs.

  19. Aqueous complexes of lanthanides(III) and actinides(III) with the carbonate and sulphate ions. Thermodynamic study by time-resolved laser-induced fluorescence spectroscopy and electro-spray-ionisation mass spectrometry; Complexes aqueux de lanthanides (3) et actinides (3) avec les ions carbonate et sulfate. Etude thermodynamique par spectrofluorimetrie laser resolue en temps et spectrometrie de masse a ionisation electrospray

    Energy Technology Data Exchange (ETDEWEB)

    Vercouter, Th

    2005-03-15

    The prediction of the environmental impact of a possible geological disposal of radioactive wastes is supported by the thermodynamic modelling of the radionuclides behaviour in the groundwater. In this framework, the analogy between lanthanides and actinides(III) is confirmed by a critical analysis of the literature and the comparison with experimental results obtained here. The limiting complex, Eu(CO{sub 3}){sub 3}{sup 3-}, is identified by solubility measurements in Na{sub 2}CO{sub 3} solutions. Then the formation constants of the complexes Eu(CO{sub 3}){sub i}{sup 3-2i} (i=1-3) and Eu(SO{sub 4}){sub i}{sup 3-2i} (i=1-2) are measured by TRLFS. The formation of aqueous LaSO{sub 4}{sup +} is studied by ESI-MS and is in good agreement with the expected speciation. The enthalpy and entropy of the reaction Cm(CO{sub 3}){sub 2}{sup -} + CO{sub 3}{sup 2-} {r_reversible} Cm(CO{sub 3}){sub 3}{sup 3-} are deduced from TRLFS measurements of the equilibrium constant between 10 and 70 C. The ionic strength effect is calculated using the SIT formula. (author)

  20. Structural and thermodynamic study of rare earth(III) complexation by poly-hydroxylated carboxylic acids: synthesis of new extractants and outlook for the extraction of these cations; Etude structurale et thermodynamique de la complexation de lanthanides (III) par des acides carboxyliques polyhydroxyles: synthese de nouveaux extractants et perspectives pour l'extraction de ces cations

    Energy Technology Data Exchange (ETDEWEB)

    Aury, S

    2002-12-15

    The aim of this work is: to improve the knowledge on the binding sites of the poly-hydroxylated carboxylic acids with the trivalent lanthanide(III) ions by comparing them to gluconic acid (previously studied) and to molecules with different configuration and with a variable number of OH functions (threonic acid, glyceric acid, 2-hydroxy-butanoic acid, 3-hydroxy-butanoic acid). To find the best complexing agent among different acids (aldonic acids, aldaric acids, di-hydroxybenzoic acids) (determination of the set of complexes and their stability constants by potentiometry, NMR and UV-Visible spectroscopy). To synthesize hydrophobic monoamides from one lactone form of saccharic acid, to study their complexing power and their capacity to extract the trivalent lanthanide(III) ions. (author)

  1. Thermodynamic and kinetics study of the extraction of lanthanides nitrates by a malonamide (dimethyl di-octyl hexyl-ethoxy malonamide); Etude thermodynamique et cinetique de l'extraction des nitrates de lanthanides par un malonamide: N,N dimethyl-N,N dioctyl hexylethoxy malonamide ou DMDOHEMA

    Energy Technology Data Exchange (ETDEWEB)

    Bosland, L

    2005-10-15

    In the field of nuclear waste separation, DIAMEX Process (Based on liquid-liquid extraction) allows the co-extraction of trivalent lanthanides and actinides thanks to DMDOHEMA molecule. The objectives of this study are to measure the lanthanides extraction kinetics and to characterize the organic phase. Firstly, a thermodynamic study of water, nitric acid and neodymium nitrate extraction was done in DIAMEX process experimental conditions. Organic phase characterisation was done at different temperatures: measurement of the interfacial tension show the presence of aggregate (determination of the critical micellization concentrations); vapour pressure osmometry measurements confirm the presence of aggregates of diamide molecule in organic phase and show that their size and concentration vary with the temperature and the composition of aqueous phase. Nitric acid extraction was modelled at 25 deg C, several complexes were identified: - monomeric species: L(HNO{sub 3}), L(HNO{sub 3} ){sub 2} and (L){sub 2} (HNO{sub 3}) (with L: DMDOHEMA molecule) - and aggregate species: (L){sub 4} (HNO{sub 3} ){sub 2} (H{sub 2}O){sub 4} and (L){sub 15} (HNO{sub 3}){sub 7} (H{sub 2}O){sub 9}. When metal is in trace level concentration, lanthanides nitrate extraction at 25 deg C can be modelled by the species L{sub 12} (Ln(NO{sub 3}){sub 3} ). This stoichiometry can be dependant on the temperature. Then, kinetics study of neodymium nitrate by DMDOHEMA was done with two techniques: 'ARMOLLEX' cell and 'single drop technique'. Diffusional regime is the limiting step in 'ARMOLLEX' cell whereas a mix regime is rather obtained with 'single drop technique'. An increase of the temperature leads to a decreasing of the global transfer coefficient. This result could be explained by the interfacial behaviour of DMDOHEMA molecule that is not well understood, or by the extraction mechanisms which could be dependant on the temperature. (author)

  2. Contribution to the thermal and thermodynamic study of an adsorption cooling system running with pulsed warm air; Contribution a l'etude thermique et thermodynamique d'une machine frigorifique a adsorption fonctionnant avec une source chaude a air pulse

    Energy Technology Data Exchange (ETDEWEB)

    Dumas, A.

    1998-07-01

    This work is dedicated to the study of a cooling machine based on methanol adsorption by activated charcoal. In the first part of this work, some thermal characteristics of methanol: conductivity and wall conductance have been experimentally analysed. The second part of this work deals with the thermodynamic behaviour of the system. Thermal and thermodynamic phenomena have been reproduced on a laboratory bench in order to estimate the performance of such a system. It is shown that under certain circumstances the length of the cycle can be drastically reduced.

  3. The study of some thiazinic and indaminic dye syntheses induced by ionising radiation; Etude de quelques syntheses de colorants thianziniques et indaminiques amorcees par les rayonnements ionisants

    Energy Technology Data Exchange (ETDEWEB)

    Balestic, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-03-15

    With a view to finding some radiochemical reactions applicable on an industrial scale for evaluating the radioactive waste from nuclear reactors, a systematic study was made of the radiochemical synthesis of thiazinic dyes such as methylene blue and Lauths' violet, on which the first tests were carried out in 1954. The first part of the study concerned the identification and the dosage, during radiolysis, of dyes by means of their absorption spectra after separation from the reaction medium by adsorption chromatography or ion-exchange; other radiolysis products such as ammonium chloride and hydrogen peroxide were also identified. During a later stage by systematically varying the physico-chemical parameters it was possible to determine the most favourable conditions for radio-synthesis; the maximum radiochemical yields obtained had the following values: G (Lauths' violet) 1,65; G (Methylene blue) = 1,75. Furthermore, the study of the influence of variously substituted aminated products on the radiochemical yield showed the possibility of synthesising Bindsehedlers green and Wursters blue by radiochemical methods. Finally the discovery of a fundamental intermediate product, Wursters red, together with the kinetic study of the chemical synthesis of methylene blue made it possible to determine the main stages of the reaction mechanism and to decide which of these stages could be attributed to ionising radiations in the case of the radiochemical synthesis. (author) [French] Dans le but de trouver des reactions radiochimiques susceptibles d'une application industrielle pour valoriser les dechets radioactifs provenant des reacteurs nucleaires, il a ete entrepris une etude systematique de la synthese radiochimique des colorants thiazimiques tels que le Bleu de Methylene et le Violet de Lauth dont les premiers essais ont ete effectues par Loiseleur en 1954. La premiere partie de l'etude a porte sur l'identification et le dosage des colorants formes au cours de la radiolyse

  4. Developpement de techniques numeriques pour l'estimation, la modelisation et la prediction de proprietes thermodynamiques et structurales de systems metalliques a fort ordonnancement chimique

    Science.gov (United States)

    Harvey, Jean-Philippe

    In this work, the possibility to calculate and evaluate with a high degree of precision the Gibbs energy of complex multiphase equilibria for which chemical ordering is explicitly and simultaneously considered in the thermodynamic description of solid (short range order and long range order) and liquid (short range order) metallic phases is studied. The cluster site approximation (CSA) and the cluster variation method (CVM) are implemented in a new minimization technique of the Gibbs energy of multicomponent and multiphase systems to describe the thermodynamic behaviour of metallic solid solutions showing strong chemical ordering. The modified quasichemical model in the pair approximation (MQMPA) is also implemented in the new minimization algorithm presented in this work to describe the thermodynamic behaviour of metallic liquid solutions. The constrained minimization technique implemented in this work consists of a sequential quadratic programming technique based on an exact Newton’s method (i.e. the use of exact second derivatives in the determination of the Hessian of the objective function) combined to a line search method to identify a direction of sufficient decrease of the merit function. The implementation of a new algorithm to perform the constrained minimization of the Gibbs energy is justified by the difficulty to identify, in specific cases, the correct multiphase assemblage of a system where the thermodynamic behaviour of the equilibrium phases is described by one of the previously quoted models using the FactSage software (ex.: solid_CSA+liquid_MQMPA; solid1_CSA+solid2_CSA). After a rigorous validation of the constrained Gibbs energy minimization algorithm using several assessed binary and ternary systems found in the literature, the CVM and the CSA models used to describe the energetic behaviour of metallic solid solutions present in systems with key industrial applications such as the Cu-Zr and the Al-Zr systems are parameterized using fully

  5. Evaluation of uncertainties of key neutron parameters of PWR-type reactors with slab fuel, application to neutronic conformity; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustibles et application aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2001-12-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and life-time. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then, neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimized. (author)

  6. Evaluation of uncertainties of key neutron parameters of PWR-type reactors with slab fuel, application to neutronic conformity; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustibles et application aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2001-12-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and life-time. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then, neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimized. (author)

  7. Study and installation of concrete shielding in the civil engineering of nuclear construction (1960); Etude et mise en place des betons de protection dans le genie civil des ouvrages nucleaires (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, F [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The object of this report is to give technical information about high density concretes which have become very important for radiation biological shielding. The most generally used heavy aggregates (barytes, ilmenite, ferrophosphorus, limonite, magnetite and iron punching) to make these concretes are investigated from the point of view prospecting and physical and chemical characteristics. At first, a general survey of shielding concretes is made involving the study of components, mixing and placing methods, then, a detailed investigation of some high density concretes: barytes concrete, with incorporation of iron punching or iron shot, ferrophosphorus concrete, ilmenite concrete and magnetite concrete, more particularly with regard to grading and mix proportions and testing process. To put this survey in concrete form, two practical designs are described such as they have been carried out at the Saclay Nuclear Station. Specifications are given for diverse concretes and for making the proton-synchrotron 'Saturne' shielding blocks. (author) [French] Ce rapport a pour objet de donner des precisions techniques au sujet des betons a haute densite qui ont pris une grande importance pour la protection biologique contre les rayonnements. Les agregats lourds les plus couramment utilises (barytine, ilmenite, ferrophosphore, limonite, magnetite et riblons) pour la fabrication de ces betons, sont examines du point de vue prospection et caracteristiques physiques et chimiques. On procede d'abord a une etude generale des betons de protection comprenant l'etude des constituants, de la confection et de la mise en place, ensuite, a un examen detaille de quelques betons a haute densite: betons a base de barytine, avec incorporation de riblons ou de grenaille de fonte, betons au ferrophosphore, a base d'ilmenite ou de magnetite, notamment en ce qui concerne la granulometrie, la composition, le dosage et les processus d'essais. Pour concretiser ces etudes, deux applications pratiques

  8. Study and installation of concrete shielding in the civil engineering of nuclear construction (1960); Etude et mise en place des betons de protection dans le genie civil des ouvrages nucleaires (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, F. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    etudes, deux applications pratiques sont decrites telles qu'elles ont ete realisees au Centre d'Etudes Nucleaires de Saclay. Des specifications sont donnees pour les betons de barytine et pour la fabrication des blocs de protection du synchrotron a protons 'Saturne'. (auteur)

  9. High resolution and high precision absorption spectroscopy using high finesse cavities: application to the study of molecules with atmospheric interest; Cavites de haute finesse pour la spectroscopie d'absorption haute sensibilite et haute precision: application a l'etude de molecules d'interet atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Motto-Ros, V.

    2005-12-15

    High finesse cavities are used to measure very weak absorption features. Two different methodologies are investigated and applied to the study of molecules with atmospheric interest. First, Continuous Wave - Cavity Ring Down Spectroscopy (CW-CRDS) is used to study the atmospheric spectra of water vapour in the near infrared range. These measurements are performed for temperature and pressure of atmospheric relevance for DIAL applications (Differential Absorption Lidar). This study, financed by the European Space Agency (ESA), goes with the WALES mission (Water Vapour Lidar Experiment in Space). The experimental setup was conceived in order to control pressure, temperature and relative humidity conditions. A particular attention is done to characterize and describe the spectrometer. Then, measurements of red Oxygen B band are performed to demonstrate the huge performance of Optical Feedback Cavity Enhanced Absorption Spectroscopy (OF-CEAS). The desired optical feedback is obtained by light injection into the high finesse cavity through a glass plate placed inside the cavity and closed to the Brewster angle. We show a measurement dynamical range of 5 orders of magnitude (10{sup -5} to 10{sup -10} /cm) and a sensitivity of 10{sup -10} /cm/{radical} Hz. Also, sampling absorption spectra by the super linear cavity frequency comb allows very precise frequency measurements. This is demonstrated by the determination of Oxygen pressure shifts with an absolute accuracy of around 5 x 10{sup -5} cm{sup -1}/atm. To our knowledge, we provide the highest accuracy ever reported for this parameter. (author)

  10. Study of deuterons induced nuclear reactions on light elements (N, Al and Si): Application to containment materials of radioactive wastes; Etude des reactions nucleaires induites par des deuterons sur des elements legers (N, Al, Si): application aux materiaux de confinement des dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrino, St

    2004-03-01

    Nuclear reaction analysis is well adapted to the quantification of light element. Profiles of concentration in order to follow elements migration into materials can be undertaken. This technique is used to study the behavior of the future matrices for nuclear waste containment. This technique is isotopic, characterized by a good signal-to-background ratio and a very low detection limit. The probability of a nuclear reaction is linked to a parameter called 'cross section' we have to know in order to carry out quantitative analysis. We have determined excitation curves for nitrogen, aluminium and silicon. These experiments were done with deuterons from 0.5 to 2 MeV. Two methods for the cross section characterization are presented and are in agreement with each other. The second one reduces uncertainty. Data are incorporated in the simulation software SIMNRA. We have compared the results obtained on different samples when we use data in literature or data of the study. We have noticed a great fit improvement with the data of this study. The new cross sections of this work will be integrated in the general data base SIGMABASE. Applications on materials such as Si{sub 3}N{sub 4}, nano-metric powders, WCN and nuclear glass YLaMgSiAlON studied for radioactive waste containment are also presented. (author)

  11. Numerical solution of the Maxwell-Vlasov equations in the periodic regime. Application to the study of isotope separation by ion cyclotron resonance; Resolution numerique des equations de Maxwell-Vlasov en regime periodique. Application a l'etude de la separation isotopique par resonance cyclotron ionique

    Energy Technology Data Exchange (ETDEWEB)

    Omnes, P

    1999-01-25

    This work is dedicated to the study of the behaviour of a magnetic confined plasma that is excited by a purely sinusoidal electric current delivered by an antenna. The response of the electrons to the electromagnetic field is considered as linear,whereas the ions of the plasma are represented by a non-relativistic Vlasov equation. In order to avoid transients, the coupled Maxwell-Vlasov equations are solved in a periodic mode and in a bounded domain. An equivalent electric conductivity tensor has been defined, this tensor is a linear operator that links the electric current generated by the movement of the particles to the electromagnetic field. Theoretical considerations can assure the existence and uniqueness of a periodical solution to Vlasov equations and of a solution to Maxwell equations in harmonic mode. The system of equations is periodical and has been solved by using an iterative method. The application of this method to the simulation of a isotopic separation device based on ionic cyclotron resonance has shown that the convergence is reached in a few iterations and that the solution is valid. Furthermore a method based on a finite-volume formulation of Maxwell equations in the time domain is presented. 2 new variables are defined in order to better take into account the Gauss' law and the conservation of the magnetic flux, the new system is still hyperbolic. The parallelization of the process has been successfully realized. (A.C.)

  12. High resolution and high precision absorption spectroscopy using high finesse cavities: application to the study of molecules with atmospheric interest; Cavites de haute finesse pour la spectroscopie d'absorption haute sensibilite et haute precision: application a l'etude de molecules d'interet atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Motto-Ros, V

    2005-12-15

    High finesse cavities are used to measure very weak absorption features. Two different methodologies are investigated and applied to the study of molecules with atmospheric interest. First, Continuous Wave - Cavity Ring Down Spectroscopy (CW-CRDS) is used to study the atmospheric spectra of water vapour in the near infrared range. These measurements are performed for temperature and pressure of atmospheric relevance for DIAL applications (Differential Absorption Lidar). This study, financed by the European Space Agency (ESA), goes with the WALES mission (Water Vapour Lidar Experiment in Space). The experimental setup was conceived in order to control pressure, temperature and relative humidity conditions. A particular attention is done to characterize and describe the spectrometer. Then, measurements of red Oxygen B band are performed to demonstrate the huge performance of Optical Feedback Cavity Enhanced Absorption Spectroscopy (OF-CEAS). The desired optical feedback is obtained by light injection into the high finesse cavity through a glass plate placed inside the cavity and closed to the Brewster angle. We show a measurement dynamical range of 5 orders of magnitude (10{sup -5} to 10{sup -10} /cm) and a sensitivity of 10{sup -10} /cm/{radical} Hz. Also, sampling absorption spectra by the super linear cavity frequency comb allows very precise frequency measurements. This is demonstrated by the determination of Oxygen pressure shifts with an absolute accuracy of around 5 x 10{sup -5} cm{sup -1}/atm. To our knowledge, we provide the highest accuracy ever reported for this parameter. (author)

  13. Singing as a Therapeutic Agent, inThe Etude, 1891-1949.

    Science.gov (United States)

    Hunter

    1999-01-01

    The Etude music magazine, founded by Theodore Presser, was one of a number of popular music magazines published in the years prior to the establishment of the music therapy profession in 1950. During its publication run from 1883 to 1957, over 100 music therapy related articles appeared, including 13 on the health benefits of singing published between 1891 and 1949. Written by authors with diverse backgrounds, such as the famous Battle Creek, Michigan physician John Harvey Kellogg and Boston music critic Louis C. Elson, the articles contained consistent and adamant support regarding the health benefits of singing. The advantages described were both physical and psychological, and were recommended prophylactically for well persons and therapeutically for ill persons. Although the articles varied in perspective, from philosophical to theoretical to pedagogical, there is a consistent holistic medicine theme that appeared almost ahead of its time and no doubt linked to the push for vocal music education in that era. The importance of The Etude in promulgating ideas that helped shape the early practice of music therapy should not be underestimated. For much of its publication run The Etude was the largest music periodical in print, reaching its peak circulation of 250,000 copies per month in 1924.

  14. Study of the droplet size of sprays generated by swirl nozzles dedicated to gasoline direct injection: measurement and application of the maximum entropy formalism; Etude de la granulometrie des sprays produits par des injecteurs a swirl destines a l'injection directe essence: mesures et application du formalisme d'entropie maximum

    Energy Technology Data Exchange (ETDEWEB)

    Boyaval, S.

    2000-06-15

    This PhD presents a study on a series of high pressure swirl atomizers dedicated to Gasoline Direct Injection (GDI). Measurements are performed in stationary and pulsed working conditions. A great aspect of this thesis is the development of an original experimental set-up to correct multiple light scattering that biases the drop size distributions measurements obtained with a laser diffraction technique (Malvern 2600D). This technique allows to perform a study of drop size characteristics near the injector tip. Correction factors on drop size characteristics and on the diffracted intensities are defined from the developed procedure. Another point consists in applying the Maximum Entropy Formalism (MEF) to calculate drop size distributions. Comparisons between experimental distributions corrected with the correction factors and the calculated distributions show good agreement. This work points out that the mean diameter D{sub 43}, which is also the mean of the volume drop size distribution, and the relative volume span factor {delta}{sub v} are important characteristics of volume drop size distributions. The end of the thesis proposes to determine local drop size characteristics from a new development of deconvolution technique for line-of-sight scattering measurements. The first results show reliable behaviours of radial evolution of local characteristics. In GDI application, we notice that the critical point is the opening stage of the injection. This study shows clearly the effects of injection pressure and nozzle internal geometry on the working characteristics of these injectors, in particular, the influence of the pre-spray. This work points out important behaviours that the improvement of GDI principle ought to consider. (author)

  15. Study of air entrainment in high pressure spray: optics diagnostics and application to the Diesel injection; Etude de l'entrainement d'air dans un spray haute pression: diagnostics optiques et application a l'injection diesel

    Energy Technology Data Exchange (ETDEWEB)

    Arbeau, A.

    2004-12-15

    The actual development of the engine must reply to a will of fuel consumption reduction and to norms more and more strict concerning the pollutant emissions. Although the Diesel engines are efficient, the NO{sub x} and particle emissions mainly come from the existence of wealthy fuel zone preventing an optimal combustion. Therefore, the air / fuel mixing preparation, highly controlled by the air entrainment in spray, is essential. In this context, we have developed metrological tools in order to analyse the air entrainment mechanism in a dense spray. The Particle Image Velocimetry (PIV) technique is first applied to a conical spray with an injection pressure less than 100 bars to study the air entrainment in spray. A transfer of the methodologies allows then the characterisation and the understanding of the air entrainment mechanism in high pressure full spray (injection pressure less than 1600 bars) type Diesel one. The influence of injection parameters (injection pressure and back pressure) on the mixing rate is studied. The increase of the injection pressure from 800 to 1600 bars implies an increase of the mixing rate of 60 %. Moreover, the thermodynamic conditions of the ambient air, simulated by the chamber back pressure, widely favours the mixing rate. Actually, this latter increases of 350 % when the chamber back pressure varies from 1 to 7 bars. The experimental results do not follow classical laws of air entrainment in one-phase flow jet with variable density, but are in good agreement with an integral model for air entrainment in an axisymmetric full spray. Finally, the Fluorescence Particle Image Velocimetry (FPIV) is introduced in order to extend the PIV application field in dense two-phase flows. (author)

  16. The thermodynamic solar energy; Le solaire thermodynamique

    Energy Technology Data Exchange (ETDEWEB)

    Rivoire, B. [Centre National de la Recherche Scientifique (CNRS-IMP), 66 - Perpignan (France)

    2002-04-01

    The thermodynamic solar energy is the technic in the whole aiming to transform the solar radiation energy in high temperature heat and then in mechanical energy by a thermodynamic cycle. These technic are most often at an experimental scale. This paper describes and analyzes the research programs developed in the advanced countries, since 1980. (A.L.B.)

  17. Experimental study and mechanical modelling of the effects of water-driving in an oil saturated chalk. Application to the petroleum industry; Etude experimentale et modelisation mecanique des effets du balayage a l'eau dans une craie saturee d'huile. Application a l'industrie petroliere

    Energy Technology Data Exchange (ETDEWEB)

    Mata, C.

    2001-01-01

    measurements and SEM observation, let us highlight two different contributions to mechanical strength of chalk-: 1) The cohesion due to solid micro-bridges between calcite grains (always present in intact samples); 2) The cohesion due to water capillary menisci (which decreases when the degree of water saturation increases). On these grounds, an elasto-plastic model is proposed is order to explain how contributions are coupled. In this modelling, plastic strain is an hardening parameter while water saturation ratio is a softening one. Applications are developed in order to relate water-driving, stress state and subsidence rate in an oil reservoir configuration. (author)

  18. Applications of electrical resistivity measurements to research into the purification of uranium using floating molten zone by electronic bombardment; Applications des mesures de resistivite electrique a l'etude de la purification de l'uranium par fusion de zone flottante par bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Pascal, J L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-02-01

    The purification of uranium has been achieved by zone melting. Because of the high affinity of uranium towards elements such as oxygen, contamination has been avoided by adopting the floating zone technique and by working under high vacuum. The difficulties created by the deformations of uranium rod, which are caused by anisotropy of dilatation of phases {alpha} and {beta} and allotropic transformations {alpha} {r_reversible} {beta} and {beta} {r_reversible} {alpha}, have been overcome by the use of electron bombardment stabilized by feedback. A rough control of the purification was obtained by micrographic examination, microhardness measurements, and tests of secondary recrystallization, allowed us to appreciate the new degree of purity of the uranium obtained. The investigation of the purity degree was pursued by electrical resistivity measurements at 20 deg. K. But one had to take care in the interpretation of those measurements of the anisotropy of the uranium resistivity and the influence of structure on residual resistivity. Those measurements have led us, by determination of single crystal and uranium resistivity, to be able to distinguish between the principal resistivity against axis [100] and [010]. (author) [French] La purification de l'uranium a ete realisee par l'application de la methode dite de la zone fondue. L'uranium etant particulierement reactif vis-a-vis d'elements tels que l'oxygene, les risques de contamination ont ete supprimes en adoptant la technique de la zone flottante et en operant sous vide eleve. Les difficultes creees par les deformations du barreau d'uranium, dues a l'anisotropie de dilatation des phases {alpha} et {beta} et ou passage des deux points de transformation allotropiques {alpha} {r_reversible} {beta} et {beta} {r_reversible} {alpha}, ont pu etre surmontees par l'emploi du chauffage par bombardement electronique, stabilise par un systeme tres simple de contre reaction. Un premier controle de la purification effectue par

  19. Contribution to the study of recoil species produced by potassium ferrocyanide neutron irradiation; Contribution a l'etude de la reactivite des especes de recul dans le ferrocyanure de potassium irradie aux neutrons thermiques

    Energy Technology Data Exchange (ETDEWEB)

    Meriadec Vernier de Byans, B. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    The chemical species produced by potassium ferrocyanide neutron irradiation were separated and identified. The study of their behaviour upon thermal annealing has allowed to establish a scheme of reaction as well as a kinetic treatment of the data. Activation energies are determined in different conditions and the effects of radiation dose, oxygen and water of crystallisation upon the activation energies were studied. Preliminary E.S.R. data and its relevance to the decomposition process is also discussed. (authors) [French] On a separe et identifie les differentes especes chimiques produites par irradiation neutronique de ferrocyanure de potassium. L'etude de leur comportement au cours du recuit thermique a permis l'application de differentes cinetiques et l'etablissement d'un schema de reaction. On a deterrmine la valeur des energies d'activation dans differentes conditions de recuit ainsi que l'influence de la dose de radiations, de l'oxygene et de l'eau de cristallisation sur ces energies. Une serie de mesures de resonance paramagnetique electronique a complete cette etude. (auteurs)

  20. Contribution to the micrographic study of uranium and its alloys; Contribution a l'etude micrographique de l'uranium et de ses alliages

    Energy Technology Data Exchange (ETDEWEB)

    Monti, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-06-15

    The present report is the result of research carried out by the radio metallurgy section, to perfect micrographic techniques applicable to the study of samples of irradiated uranium. In the first part of this work, two polishing baths are developed, having the qualities with a minimum of disadvantages inherent in their respective compositions: they are, on the one hand perchloric acid-ethanol mixtures, and on the other hand a phospho-chromic-ethanol bath. In the chapter following, the micrographic attack of uranium is studied. The only satisfactory process is oxidation by cathode bombardment forming epitaxic layers. In the third chapter, an attempt is made to characterise the different surface states of the uranium by dissolution potential measurements and electronic diffraction. In the fourth chapter are given some examples of the application of these techniques to the micrographic study of various uranium alloys. In an appendix, it is shown how the chemical oxidation after phospho-chromic-alcohol polishing allows the different inclusions present in the molten uranium to be distinguished. By X-ray diffraction, uranium monocarbide and mononitride inclusions in particular are characterised. (author) [French] Le present rapport est le resultat de recherches effectuees au service de radiometallurgie pour la mise au point de techniques micrographiques applicables a l'etude d'echantillons d'uranium irradie. Dans la premiere partie de ce travail, nous mettons au point deux bains de polissage qui presentent les qualites inherentes a leur composition respective, avec le minimum d'inconvenients: ce sont d'une part des melanges acide perchlorique-ethanol, et d'autre part un bain phospho-chromique-ethanol. Dans le chapitre suivant, nous etudions l'attaque micrographique de l'uranium. Seul le procede d'oxydation par bombardement cathodique formant des couches epitaxiques, est satisfaisant. Dans le troisieme chapitre, nous essayons de caracteriser les differents etats de

  1. Contribution to the micrographic study of uranium and its alloys; Contribution a l'etude micrographique de l'uranium et de ses alliages

    Energy Technology Data Exchange (ETDEWEB)

    Monti, H. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-06-15

    The present report is the result of research carried out by the radio metallurgy section, to perfect micrographic techniques applicable to the study of samples of irradiated uranium. In the first part of this work, two polishing baths are developed, having the qualities with a minimum of disadvantages inherent in their respective compositions: they are, on the one hand perchloric acid-ethanol mixtures, and on the other hand a phospho-chromic-ethanol bath. In the chapter following, the micrographic attack of uranium is studied. The only satisfactory process is oxidation by cathode bombardment forming epitaxic layers. In the third chapter, an attempt is made to characterise the different surface states of the uranium by dissolution potential measurements and electronic diffraction. In the fourth chapter are given some examples of the application of these techniques to the micrographic study of various uranium alloys. In an appendix, it is shown how the chemical oxidation after phospho-chromic-alcohol polishing allows the different inclusions present in the molten uranium to be distinguished. By X-ray diffraction, uranium monocarbide and mononitride inclusions in particular are characterised. (author) [French] Le present rapport est le resultat de recherches effectuees au service de radiometallurgie pour la mise au point de techniques micrographiques applicables a l'etude d'echantillons d'uranium irradie. Dans la premiere partie de ce travail, nous mettons au point deux bains de polissage qui presentent les qualites inherentes a leur composition respective, avec le minimum d'inconvenients: ce sont d'une part des melanges acide perchlorique-ethanol, et d'autre part un bain phospho-chromique-ethanol. Dans le chapitre suivant, nous etudions l'attaque micrographique de l'uranium. Seul le procede d'oxydation par bombardement cathodique formant des couches epitaxiques, est satisfaisant. Dans le troisieme chapitre, nous essayons

  2. Bio-metric study of pig karyotype; Etude biometrique du caryotype du porc

    Energy Technology Data Exchange (ETDEWEB)

    Haag, J; Lacourly, N; Nizza, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    This study has a twofold purpose, the former is to determine the swine karyotype as accurately as possible, the latter is to try and develop a method of automatic classification and to show its possibilities and limits. (authors) [French] Cette etude a un double objet: d'une part, de definir de la facon aussi precise que possible le caryotype du porc et d'autre part, de tenter une methode de classification automatique et d'en montrer les possibilites ainsi que les limites. (auteurs)

  3. A study of the conformation and stability of nitroxide free radicals; Etude de la conformation et de la stabilite de radicaux libres nitroxydes

    Energy Technology Data Exchange (ETDEWEB)

    Briere, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-03-01

    The first part of this study is an application of nuclear magnetic resonance to the determination of the sign and magnitude of the long range nuclear-electron spin-spin couplings in the free radical nitroxide derived from piperidine. It has been shown that the coupling constants of the protons {gamma} to the nitrogen atom have a pronounced spatial dependence as do the protons in the {beta} position, a point which has not been brought out by previous investigations. Conformational analysis of these compounds has been carried out by measurement of the effect of temperature on the NMR spectra at 310 MHz. The synthesis of di-t-Bu nitroxide labelled with C{sup 13} in the {alpha}-position made possible the unambiguous determination of the corresponding {sup 13}C nuclear-electron spin-spin coupling constant, a parameter which had not previously been measured. The coupling constants measured in the 2,2,6,6-tetramethyl piperidine series could then be attributed to the {sup 13}C atoms in the {beta}-position and their variation related to the conformations of the heterocycles. This constitutes the second part of the work reported here. The final section is devoted to a study of the decomposition of an unstable nitroxide having a hydrogen atom in the p-position. This decomposition is bimolecular and the primary isotope effect shows that the rupture. of the C-H bond is involved. From this one can conclude that a nitroxide is stable when the different groups attached to the nitrogen atom cannot give rise to a decomposition either intra molecularly, if the molecular geometry is suitable, or inter molecularly by dimerisation through attack on a different center of a neighbouring molecule thus leading to a fragmentation or a disproportionation. (author) [French] La premiere partie est une application de la resonance magnetique nucleaire a la determination du signe et de la grandeur des couplages a longue distance dans des radicaux libres nitroxydes piperidiniques. Il est montre que

  4. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P.; Accary, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  5. Study of immiscibilities in the trilaurylamine - dodecane - nitric acid - plutonium system; Etude des immiscibilites dans le systeme trilaurylamine - dodecane - acide nitrique - plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Saey, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Phase equilibrium in systems made up of trilaurylamine, dodecane, nitric acid tetravalent plutonium is shown by drawing the triangular diagrams. the study of these diagrams provides informations concerning the causes of immiscibility. Heterogeneity of the organic mixtures can be related to some characteristics of the components- dipole moment, molecular polarizability and hydrogen bond exchanging ability-Depending on these, some rules may be established which can be used to make a proper choice of an additive in order to improve the miscibility. As an application a study on the partial substitution of dodecane with decalin, in plutonium extraction experiments, has been done showing a possible improvement of the extraction process. (author) [French] L equilibre des phases dans les systemes formes a partir de trilaurylamine, de dodecane, d'acide nitrique et de plutonium tetravalent est represente en tracant les diagrammes triangulaires. L'examen de ces diagrammes permet d'apporter certaines precisions en ce qui concerne l'origine des immiscibilites. Celles ci sont ensuite reliees a certaines caracteristiques des constituants: le moment dipolaire, la polarisabilite moleculaire et la tendance a former des liaisons hydrogene. Sur les memes bases, il est possible d'etablir un certain nombre de regles pouvant servir a guider le choix d'un additif ameliorant la miscibilite. En application, une etude sur le remplacement partiel du dodecane par la decaline montre l'interet de l'emploi de ce compose dans le procede de purification du plutonium. (auteur)

  6. The formation of scientists and technicians at the 'Centre d'Etudes Nucleaires' at Saclay

    International Nuclear Information System (INIS)

    Debiesse, J.

    1958-01-01

    The considerable needs in research workers and scientists which are asked by the nuclear energy obliged the Commissariat a l'Energie atomique to deal with a particular effort to increase the quantitative and qualitative formation of scientists. Most various ways have been used. 1- A National Institute of Nuclear Sciences and Nuclear Techniques was created, by a joint decree of the Prime Minister and the Minister for National Education (june 18, 1957). This Institute of Higher Teaching (250 students) indulges in the following matters: atomic engineering, quantum mechanics, theory and technic of particle accelerators, special metallurgy, radiobiology, thermic and mechanics of fluids. 2- An associated centre of the 'Conservatoire National des Arts et Metiers' was created (200 students) for technical assistants, drawers, etc. 3- In contribution with both electronic industry and Ministry of Work, the Centre d'Etudes Nucleaires contributes to an accelerated formation of technical assistants into Professional Centres. Conclusion: Training of scientists and research workers is one of the most important activities of the Centre d'Etudes Nucleaires de Saclay. Without losing its technical efficiency, it has supplied and varied means adapted to the various purposes that we shall reach. (author) [fr

  7. Etude hyperfrequence et ultrasonore des supraconducteurs organiques kappa-(ET)(2)X (X = copper(thiocyanogen), copper[N(CN)(2)]bromine)

    Science.gov (United States)

    Frikach, Kamal

    2001-09-01

    Dans ce travail je presente une etude de l'impedance de surface, ainsi que de l'attenuation et la variation de la vitesse ultrasonores dans les etats normal et supraconducteur sur les composes organiques k-(ET)2X (X = Cu(SCN) 2, Cu[N(CN)2]Br). A partir des mesures d'impedance de surface, les deux composantes sigma 1 et sigma2 de la conductivite complexe sont extraites en utilisant le modele de Drude. Ces mesures montrent que la symetrie du parametre d'ordre dans ces composes est differente de celle du cas BCS. Afin de comprendre le profil de sigma1 (T) nous avons etudie les fluctuations supraconductrices a partir de la paraconductivite sigma'( T). Cette etude est rendue possible grace a la structure quasi-2D des composes k-(ET)2X dans lesquelles les fluctuations supraconductrices sont fortes. Ces dernieres sont observees sur deux decades de temperatures dans le Cu(SCN)2. L'application du modele de Aslamazov-Larkin 2D et 3D montre la possibilite du passage du regime 2D a haute temperature au regime 3D au voisinage de Tc. En se basant sur ce resultat, nous avons calcule la paraconductivite en utilisant une approche a l'ordre d'une boucle a partir du modele de Lawrence-Doniach. En tenant compte de la correction par la self energie dans la limite dynamique (17 GHz), l'ajustement de la paraconductivite calculee est en bon accord avec les donnees experimentales. Le couplage interplan obtenu est compatible avec le caractere quasi-2D des composes organiques. Le temps de relaxation des quasi-particules dans l'etat supraconducteur est ensuite extrait pour la premiere fois dans ces composes dont le comportement en fonction de la temperature est compatible avec la presence des noeuds dans le gap. Dans l'etat normal, la variation de la vitesse ultrasonore presente un comportement anormal caracterise par un fort ramollissement a T = 38 K et 50 K dans k-(ET) 2Cu(SCN)2 et k-(ET)2Cu[N(CN) 2]Br respectivement dont l'amplitude est independante du champ magnetique jusqu'a H = Hc 2

  8. Experimental study of metal gasketed joints for ultra-high vacuums; Etude experimentale de joints metalliques pour ultra-vide

    Energy Technology Data Exchange (ETDEWEB)

    Boulloud, J. P.; Schweitzer, J. [Commissariat a l' energie atomique et aux energies alternatives - CEA, Service de Physique Appliquee, groupe de Vide, Centre d' Etudes Nucleaires de Saclay (France)

    1960-07-01

    Various type of leak-tight metal joints have been studied with their application in assemblies containing total vacuums in mind. Their integrity has been tested with a helium leak detector, and leaks of about 2 x 10{sup -12} cm{sup 3} Atm/s per meter of joint have been measured, simultaneously with the clamping effort applied at the joint and the deformation of the metal gasket. The integrity to clamping effort ratio curve is not retraced in reverse upon relaxation of the clamping effort, but a 'return curve' analogous to a hysteresis cycle explains why certain types of joint retain their integrity at high temperatures. The use of a tracer gas permits discrimination between external permeation of the joint and gas from occlusions between its mating surfaces. The authors have been led to consider that neither the nature nor the purity or surface condition of the joint have any basic influence on its integrity. Clamping effort values in respect of various joints and necessary for total integrity are indicated. Reprint of a paper published in Le vide, no. 82, Jul-Aug 1959 [French] L'etude de differents types de joints metalliques etanches, en vue de leur application a l'ultra-vide, a ete effectuee a l'aide d'un detecteur de fuite a helium. On a mesure simultanement le debit de fuite, l'effort applique sur le joint et sa deformation. On a reussi a mesurer des debits de fuite de l'ordre de 2 x 10{sup -12} cm{sup 3} Atm/s/m de joint pour l'air. La courbe de l'etancheite en fonction de l'effort applique n'est pas reversible et on a pu mettre en evidence un 'cycle d'hysteresis' qui explique que certains joints conservent leur etancheite a haute temperature. La methode de mesure d'etancheite au moyen d'un gaz traceur a amene a faire une distinction entre la permeation et le degazage des gaz occlus dans l'interface des joints et a considerer que ni la nature, ni la purete et ni l'etat de surface du joint n'ont une influence primordiale sur l'etancheite de joint. Des valeurs

  9. Initiation of detonation by impact on granular explosives; Contribution a l'etude de la generation de la detonation provoquee par impact sur un explosif

    Energy Technology Data Exchange (ETDEWEB)

    Bernier, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-05-15

    A good number of experiments have shown up the particular behaviour of granular explosives when they are detonated by barrier transmitted shocks. Similar results can be obtained when the shock is induced by impact. In this case the pressure signal shape applied at the explosive is better known and both its intensity and duration can be varied. By using a mathematical model in which the law of chemical kinetics is a linear function of pressure, and different temperatures are used for solids and gases, it is possible to describe most of the behaviour of detonation initiation in solid granular explosives. (author) [French] De nombreuses etudes experimentales ont montre le comportement particulier des explosifs granulaires lors de la detonation provoquee par choc transmis a travers une barriere. Les memes resultats peuvent etre obtenus lorsque la detonation est engendree par impact. Dans ce cas, la forme du signal de pression induit dans l'explosif est mieux connue, et il est possible d'en faire varier l'intensite et la duree d'application. Un modele mathematique utilisant une loi de cinetique chimique fonction lineaire de la pression et ou les temperatures des etats solide et gazeux pendant la reaction sont differenciees, permet de retrouver la plupart des caracteres specifiques de la generation dans un explosif solide granulaire. (auteur)

  10. Thermodynamic Behaviour of Hypostoichiometric UO{sub 2}; Comportement Thermodynamique de UO{sub 2} HypostoeChiometrique; Termodinamicheskoe povedenie gipostekhiometricheskoj UO{sub 2}; Comportamiento Termodinamico del UO{sub 2} Subestequiometrico

    Energy Technology Data Exchange (ETDEWEB)

    Aitken, E. A.; Brassfield, H. C.; Fryxell, R. E. [General Electric Company, Nuclear Materials and Propulsion Operation, Cincinnati, OH (United States)

    1966-02-15

    with a statistical model. The model assumes that departure from the stoichiometric composition is accommodated by an excess of oxygen atoms occupying interstitial positions or by a deficiency of oxygen on the oxygen sub-lattice. Disordering occurs with the oxygen interstitials and oxygen vacancies. The Frenkel energy of the oxygen is 60 kcal/g-atom which agrees favourably with previous estimates from oxygen self-diffusion data. The relationship between G(O{sub 2}) and the partial pressure of the gaseous oxides, UO and UO{sub 2} , is discussed and some general comments are made on results obtained, using these experimental methods, on other compounds such as ThO{sub 2}. (author) [French] La possibilite pour une structure de type UO{sub 2} d'admettre un exces d'oxygene est bien connue. Des observations recentes indiquent que cette structure est stable egalement a l'etat hypostoechiometrique a haute temperature et sous basse pression partielle d'oxygene, mais elle se manifeste sous forme de precipites d'uranium metallique dans l'oxyde apres refroidissement. Les auteurs donnent de nouvelles preuves de l'existence a haute temperature d'une urane hypostoechiometrique stable et decrivent en partie les variations des proprietes thermodynamiques dans l'intervalle d'homogeneie. UO{sub 2} hypostoechiometrique s'evapore de facon congruente au cours d'une vaporisation libre dans un courant lent d'hydrogene (point de rosee -40 Degree-Sign C) a une temperature de 2400 Degree-Sign C, sa composition correspondant a un rapport entre l'oxygene et l'uranium egal a 1,88. Si l'on diminue la temperature ou que l'on augmente la teneur en eau (pression partielle de l'oxygene), la composition congruente augmente. La teneur en eau de l'hydrogene a 2400 Degree-Sign C doit etre d'au moins 1% opour maintenir le bioxyde d'uranium a l'etat stoechiometrique. Lorsqu'on scelle des pastilles d'UC dans des capsules en tantale et qu'on les chauffe au-dessus de 1700 Degree-Sign C, le rapport O/U des

  11. Etude comparative de tubes en matériaux composites en vue de l'application à l'exploitation des hydrocarbures en mer profonde Comparative Study of Composite-Material Tubes with a View to Their Use for Deep Offshore Hydrocarbon Production

    Directory of Open Access Journals (Sweden)

    Bonavent G.

    2006-11-01

    Full Text Available Les prévisions de développement de la production pétrolière en mer profonde font apparaître de nouveaux besoins en tubes légers et à haute résistance pour les liaisons verticales entre les têtes de puits sous-marines et les plates-formes flottantes, et les conduites immergées par grand fond. Certains matériaux composites peuvent répondre à ces besoins et présentent en outre l'avantage d'une excellente résistance à la corrosion dans l'environnement marin. Toutefois, les choix sont imposés essentiellement par des contraintes d'ordre mécanique. On cherche ici à comparer, par rapport à l'acier, les avantages de deux types de matériaux composites - les composites acier-résine - les composites fibres-résine dont on résume les principales caractéristiques et les domaines d'applications possibles en fonction des spécifications pétrolières Development forecosts for deep offshore petroleum production bring out new needs for light tubes for vertlcaf linksbetween subsea wellheads and floating piatforms as well as for subsea pipelines ut great depths. Some composite materials moy meet such requirements while also hoving the advantoge of high résistance ta corrosion in a marine environment. However, the choices are mainly governed by stresses of a mechanical nature. Compared with steel, this article seeks ta describe the advantages of the following two types of composite materials : (il steel-resin composites, and (ii fiber-resin composites. The leading properties and the possible arecs of application are summed up as a function of petroleum specifications.

  12. Etudes optiques de nouveaux materiaux laser: Des orthosilicates dopes a l'ytterbium: Le yttrium (lutetium,scandium) pentoxide de silicium

    Science.gov (United States)

    Denoyer, Aurelie

    La decouverte et l'elaboration de nouveaux materiaux laser solides suscitent beaucoup d'interet parmi la communaute scientifique. En particulier les lasers dans la gamme de frequence du micron debouchent sur beaucoup d'applications, en telecommunication, en medecine, dans le domaine militaire, pour la, decoupe des metaux (lasers de puissance), en optique non lineaire (doublage de frequence, bistabilite optique). Le plus couramment utilise actuellement est le Nd:YAG dans cette famille de laser, mais des remplacants plus performants sont toujours recherches. Les lasers a base d'Yb3+ possedent beaucoup d'avantages compares aux lasers Nd3+ du fait de leur structure electronique simple et de leur deterioration moins rapide. Parmi les matrices cristallines pouvant accueillir l'ytterbium, les orthosilicates Yb:Y 2SiO5, Yb:Lu2SiO5 et Yb:Sc2SiO 5 se positionnent tres bien, du fait de leur bonne conductivite thermique et du fort eclatement de leur champ cristallin necessaire a l'elaboration de lasers quasi-3 niveaux. De plus l'etude fine et systematique des proprietes microscopiques de nouveaux materiaux s'avere toujours tres interessante du point de vue de la recherche fondamentale, c'est ainsi que de nouveaux modeles sont concus (par exemple pour le champ cristallin) ou que de nouvelles proprietes inhabituelles sont decouvertes, menant a de nouvelles applications. Ainsi d'autres materiaux dopes a l'ytterbium sont connus pour leurs proprietes de couplage electron-phonon, de couplage magnetique, d'emission cooperative ou encore de bistabilite optique, mais ces proprietes n'ont encore jamais ete mises en evidence dans Yb:Y 2SiO5, Yb:Lu2SiO5 et Yb:Sc2SiO 5. Ainsi, cette these a pour but l'etude des proprietes optiques et des interactions microscopiques dans Yb:Y2SiO 5, Yb:Lu2SiO5 et Yb:Sc2SiO5. Nous utilisons principalement les techniques d'absorption IR et de spectroscopie Raman pour determiner les excitations du champ cristallin et les modes de vibration dans le materiau

  13. Modélisation thermodynamique et cinétique des réactions diagénétiques dans les bassins sédimentaires. Présentation du modèle géochimique KINDISP Thermodynamic and Kinetic Modelling of Diagenetic Reactions in Sedimentary Basins. Description of the Geochemical Code Kindisp

    Directory of Open Access Journals (Sweden)

    Clement A.

    2006-11-01

    Full Text Available Le programme thermodynamique et cinétique KINDISP (KINetic of DISsolution and Precipitation simule les interactions minéraux/solutions aqueuses en considérant la dissolution irréversible des réactants et la précipitation réversible ou irréversible des phases secondaires. Les lois générales introduites dans le modèle ont pour base théorique la Thermodynamique des Processus Irréversibles. Les interactions eaux/roches à basse température (25-30 °C sont interprétées théoriquement à l'aide de la Théorie de l'Etat de Transition et de la Chimie de Coordination de Surface. Le mécanisme qui limite la vitesse de dissolution ou de précipitation d'un minéral, c'est-à-dire le mécanisme le plus lent pour les réactions irréversibles successives, est soit la diffusion moléculaire aqueuse d'une entité élémentaire (atome, molécule . . . ou bien la réaction de surface (adsorption-désorption d'une entité élémentaire. A chaque étape du calcul, caractérisé par un incrément de temps (dt, le modèle informatique KINDISP calcule les vitesses de réaction pour chaque minéral réactif dans le système eau-roche. A partir de ce calcul, le modèle compare les vitesses contrôlées par la diffusion moléculaire et par la réaction de surface. Ensuite, KINDISP retient la vitesse la plus lente pour représenter la loi de dissolution d'un minéral réactif primaire ou la loi de précipitation d'une phase néoformée secondaire. La croissance des minéraux secondaires est simulée, soit à l'équilibre thermodynamique, soit en domaine de sursaturation (en nonéquilibre, après une étape de nucléation, lorsque le point de sursaturation critique S* est atteint. Le programme géochimique KINDISP est divisé en deux ensembles : un module de calcul d'équilibre initial de la solution aqueuse appelé EQUILT et un module constitué de la procédure de perturbation par incréments de temps rendant compte de l'évolution géochimique du syst

  14. Generalities on the dynamic behaviour of rapid reactors. Preliminary studies on Rapsodie; Generalites sur le comportement dynamique des piles rapides. Etudes preliminaires de rapsodie

    Energy Technology Data Exchange (ETDEWEB)

    Campan, J L; Chaumont, J P; Clauzon, P P; Ghesquiere, G; Leduc, J; Schmitt, A P; Zaleski, C P [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1963-07-01

    The study of the dynamic behaviour of fast reactors may be divided into three section: 1. Stability studies around equilibrium power only the linear case was examining. S. Transient studies in the case of usual reactor operation (shut down, scram, etc.) with thermal shocks evaluation, for instance. 3. Explosion studies, for the maximum credible accidents. This report presents the status of the studies performed at the 'Physics Research Department' at Cadarache. Methods used are detailed and illustrated with the results obtained on a preliminary metallic core of the Rapsodie Reactor. (authors) [French] Le comportement dynamique des piles rapides, se presente tout naturellement sous trois aspects: 1. Etude de stabilite autour d'un regime d'equilibre (nous nous sommes bornes ici au cas lineaire). 2. Etude de regimes transitoires lors des operations normales de pile (arret, arret d'urgence, etc.) avec evaluation des chocs thermiques par exemple. 3. Etude des regimes transitoires de caractere explosif lors des accidents les plus graves possibles. Ce rapport presente l'etat des etudes a la date du 20 decembre 1961 a la Section d'Etudes de Piles Rapides a CADARACHE. Les methodes employees ont ete detaillees et illustrees a partir des resultats obtenus sur une premiere version 'combustible metallique' de Rapsodie. (auteurs)

  15. Etude cinétique de la dégradation de l'Endosufane en solution ...

    African Journals Online (AJOL)

    Etude cinétique de la dégradation de l'Endosufane en solution. S Traore, K Mamadou, A Dembele, V Yao, Y Bekro, P Mazellier, B Legube, P Houenou. Abstract. Les pesticides sont fréquemment utilisés en Côte d'Ivoire. Leur détection dans les eaux de forage témoigne de leur mauvais usage et d'un grave problème ...

  16. Study of the tributyl phosphate - 30% dodecane solvent; Etude du solvant phosphate tributylique - 30 % dodecane

    Energy Technology Data Exchange (ETDEWEB)

    Leroy, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses. Centre d' Etudes Nucleaires, 92 (France)

    1967-07-01

    This study, originating mainly from a literature survey, gives the principal chemical and physical features of the tributyl-phosphate (TBP) agent diluted at 30 volumes per cent in dodecane. The mixture is a very commonly used extractant in nuclear fuel processing. In this paper, the main following points are reported: -) the components (TBP and diluents) -) the TBP-diluents systems (non-loaded), -) the TBP-diluents-water systems, -) TBP-diluents-water-nitric acid systems, and -) industrial solvents. (author) [French] Cette etude, d'origine bibliographique, regroupe les caracteristiques physico-chimiques essentielles du phosphate tributylique (TBP) dilue a 30% en volume dans du dodecane. Ce melange constitue un agent d'extraction tres utilise dans le traitement des combustibles nucleaires. Les principaux points traites sont les suivants: -) les constituants (TBP et diluants), -) les systemes TBP-diluants non charges, -) les systemes TBP-diluants-eau, -) les systemes TBP-diluants-eau-acide nitrique, et -) les solvants industriels. (auteur)

  17. An economic study of the site of Marcoule; Etude economique du site de Marcoule

    Energy Technology Data Exchange (ETDEWEB)

    Duprat, H [Commissariat a l' Energie Atomique, Marcoule (France). Centre d' Etudes Nucleaires

    1964-07-01

    The study of this site of the Marcoule Center shows that its regional economical influence is limited to the buying power distributed among its personnel. This entails distortions between first this supplementary buying power and the overall markets within the possible Marcoule influence zone, and secondly the concentration on Bagnols-sur-Ceze and this town's normal extension possibilities. (author) [French] L'etude du site de Marcoule demontre que son influence economique se limite, pour la region, au pouvoir d'achat distribue a son personnel. Ceci entraine une disproportion d'une part entre ce pouvoir d'achat supplementaire et l'ensemble des marches contenus dans l'aire d'influence possible de Marcoule, d'autre part entre la concentration realisee a Bagnole-sur-Ceze et la capacite d'extension normale de cette agglomeration. (auteur)

  18. Neutronic study of the two french heavy water reactors; Etude neutronique des deux piles francaises a eau lourde

    Energy Technology Data Exchange (ETDEWEB)

    Horowitz, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    The two french reactors - the reactor of Chatillon, named Zoe, and the reactor of Saclay - P2 - were the object of detailed neutronic studies which the main ideas are exposed in this report. These studies were mostly done by the Department of the Reactor Studies (D.E.P.). We have thus studied the distribution of neutronic fluxes; the factors influencing reactivity; the link between reactivity and divergence with the formula of Nordheim; the mean time life of neutrons; neutron spectra s of P2; the xenon effect; or the effect of the different adjustments of the plates and controls bar. (M.B.) [French] Les deux reacteurs francais - la pile de Chatillon, appelee ZOE, et la pile de Saclay, designee dans la suite par P2 - ont fait l'objet d'etudes neutroniques detaillees dont les principales sont exposees dans ce rapport. Ces etudes ont ete pour la plupart effectuees dans le cadre du Departement des Etudes de Piles (D.E.P.). Nous avons ainsi entre autre etudie la distribution du flux neutronique; les facteurs influencants la reactivite; le lien entre reactivite et divergence par la formule de Nordheim; le temps de vie moyen des neutrons; les spectres de neutrons de P2; l'effet xenon; ou encore l'effet des differents reglages des plaques et barres de controles. (M.B.)

  19. Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico

    Energy Technology Data Exchange (ETDEWEB)

    Besnard, S; Talbot, J [Centre National de la Recherche Scientifique, Vitry (France)

    1962-01-15

    Certain elements, such as arsenic for example, are commonly used in the laboratory to facilitate the penetration of hydrogen into iron. It has been found in industry that steel corrosion caused by hydrogen was aggravated by the presence of sulphurated hydrogen. It is an interesting question whether these elements, hitherto considered to be catalysts, merely permit a higher hydrogen absorption or whether they directly affect the metal. A study of this phenomenon is undertaken in the authors' laboratory, using electrolytic pure iron. Hydrogen supersaturation is effected by cathode charging. The addition element is S{sup 35}-labelled sodium sulphide. It is shown that, in half an hour, at -15 Degree-Sign C, the sulphur penetrates into the iron to a depth of some 120 {mu}m. A preferential localization of the sulphur at the grain boundaries is also noted. This result, which could not have been obtained without the help of radioactive tracers, has important consequences, especially for the oil industry. A similar study is made using phosphorus-32. (author) [French] Certains elements, comme l'arsenic par exemple, sont couramment utilises au laboratoire pour favoriser la penetration de l'hydrogene dans le fer. Dans l'industrie, on a constate que la corrosion des aciers due a l'hydrogene etait aggravee par la presence d'hydrogene sulfure. On pouvait se demander si ces corps, consideres jusqu'ici comme des catalyseurs, permettaient uniquement une plus grande absorption de l'hydrogene ou s'ils avaient une action directe sur le metal. L'etude de ce phenomene a ete entreprise dans notre laboratoire en utilisant du fer pur electrolytique. La sursaturation en hydrogene a ete realisee par chargement cathodique. L'element d'addition etait le sulfure de sodium marque au soufre-35. Nous avons pu montrer qu'en une demi-heure a -15 Degree-Sign C le soufre penetre dans le fer jusqu'a une profondeur de 120 {mu} environ. Par ailleurs, on a pu constater une localisation preferentielle du

  20. Etude des phenomenes dynamiques ultrarapides et des caracteristiques impulsionnelles d'emission terahertz du supraconducteur YBCO

    Science.gov (United States)

    Savard, Stephane

    Les premieres etudes d'antennes a base de supraconducteurs a haute temperature critique emettant une impulsion electromagnetique dont le contenu en frequence se situe dans le domaine terahertz remontent a 1996. Une antenne supraconductrice est formee d'un micro-pont d'une couche mince supraconductrice sur lequel un courant continu est applique. Un faisceau laser dans le visible est focalise sur le micro-pont et place le supraconducteur dans un etat hors-equilibre ou des paires sont brisees. Grace a la relaxation des quasiparticules en surplus et eventuellement de la reformation des paires supraconductrices, nous pouvons etudier la nature de la supraconductivite. L'analyse de la cinetique temporelle du champ electromagnetique emis par une telle antenne terahertz supraconductrice s'est averee utile pour decrire qualitativement les caracteristiques de celle-ci en fonction des parametres d'operation tels que le courant applique, la temperature et la puissance d'excitation. La comprehension de l'etat hors-equilibre est la cle pour comprendre le fonctionnement des antennes terahertz supraconductrices a haute temperature critique. Dans le but de comprendre ultimement cet etat hors-equilibre, nous avions besoin d'une methode et d'un modele pour extraire de facon plus systematique les proprietes intrinseques du materiau qui compose l'antenne terahertz a partir des caracteristiques d'emission de celle-ci. Nous avons developpe une procedure pour calibrer le spectrometre dans le domaine temporel en utilisant des antennes terahertz de GaAs bombarde aux protons H+ comme emetteur et detecteur. Une fois le montage calibre, nous y avons insere une antenne emettrice dipolaire de YBa 2Cu3O7-delta . Un modele avec des fonctions exponentielles de montee et de descente du signal est utilise pour lisser le spectre du champ electromagnetique de l'antenne de YBa 2Cu3O7-delta, ce qui nous permet d'extraire les proprietes intrinseques de ce dernier. Pour confirmer la validite du modele

  1. Some Applications of Short-Lived Radioisotopes in the Study of Metals; Applications Diverses des Radioelements de Courte Periode dans l'Etude des Metaux; РАЗЛИЧНЫЕ ПРИМЕНЕНИЯ КОРОТКОЖИВУЩИХ РАДИОЭЛЕМЕНТОВ ПРИ ИССЛЕДОВАНИЯХ МЕТАЛЛОВ; Aplicaciones de los Radioelementos de Periodo Corto en el Estudio de los Metales

    Energy Technology Data Exchange (ETDEWEB)

    Kohn, A. [Institut de Recherches de la Siderurgie, Saint-Germain-en-Laye (France)

    1963-03-15

    Some typical applications of short-lived radioisotopes in various metallurgical investigations are described. A simple method of activation analysis has been designed for determining the amount of lanthanum in steels, to which mischmetall had been added during melting. A study was carried out to determine the behaviour of arsenic, present in small amounts, during the oxidation of iron. The enrichment of arsenic at the metal-oxide interface was first shown by autoradiography. A quantitative study of the phenomenon was then made on oxidized samples irradiated in a nuclear reactor, by dissolving successive layers several microns thick. By this means it was possible to see that the arsenic concentrates itself at the surface of the metal where its content may be as high as 30 or 40 times the initial concentration in the alloy. Research on the growth of metallic crystals was carried out by autoradiography. This was possible because the content of an alloying element in the crystals is lower than its content in the melt from which the crystals are growing. Samples of 2% copper-aluminium alloys were melted, slowly cooled, then quenched during the course of solidification. It was thus possible to show the shape of the crystals at various stages of their growth and to relate this to the temperature of the alloy as measured by a thermocouple. An examination was made of convection currents inside large forge ingots. The purpose of this investigation was to confirm the existence of important convection currents inside large steel ingots for forgings, as they solidify. The tests were carried out by introducing a small amount of gold-198 at various times after pouring, in ingots of 4 t and of 30 to 60 t. It was possible to see that in large ingots the convection currents were sufficiently strong one hour after pouring to mix the gold through a large volume of the ingot. (author) [French] Ce memoire se propose de presenter quelques applications typiques des radioelements de courte

  2. 7. Saturne study meeting; Septiemes journees d`etudes saturne

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This Saturne workshop has welcomed 120 scientists. 3 sessions have been organized: accelerators, physics and miscellaneous. The most recent experiments realized or scheduled at Saturne have been presented and the discussions which followed showed the high scientific interest taken in that equipment and made the participants regret its definitive closing down. Presentations by european teams about existent equipment, machines under construction or new projects opened the way to new perspectives. A lot of contributions were dedicated to the realization of high intensity particle beams and to the applications of accelerators. (A.C.)

  3. 7. Saturne study meeting; Septiemes journees d`etudes saturne

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    This Saturne workshop has welcomed 120 scientists. 3 sessions have been organized: accelerators, physics and miscellaneous. The most recent experiments realized or scheduled at Saturne have been presented and the discussions which followed showed the high scientific interest taken in that equipment and made the participants regret its definitive closing down. Presentations by european teams about existent equipment, machines under construction or new projects opened the way to new perspectives. A lot of contributions were dedicated to the realization of high intensity particle beams and to the applications of accelerators. (A.C.)

  4. Etude d'une centrale électrique à biomasse de 200 kWe. Quelle filière choisir ?

    OpenAIRE

    Garin , P.

    1982-01-01

    On évalue deux filières possibles pour la production d'énergie électrique par conversion thermodynamique en utilisant pour combustible de la biomasse. La première solution consiste à gazéifier la biomasse sous pression dans un four à pyrolyse, à brûler le gaz produit dans une chambre à combustion et à détendre le gaz chaud produit, dans une turbine à gaz avec échangeur récupérateur. La seconde solution consiste à alimenter un moteur à gaz pauvre dual-fuel, à partir d'un gazogène. Les bilans é...

  5. Thermodynamic Properties of Alloys of Iron and Silicon; Proprietes Thermodynamiques des Alliages Fer-Silicium; Termodinamicheskie svojstva splavov zheleza s kremniem; Propiedades Termodinamicas de las Aleaciones de Hierro y Silicio

    Energy Technology Data Exchange (ETDEWEB)

    Vecher, R. A.; Gejderih, V. A.; Gerasimov, Ja. I. [Moskovskij Gosudarstvennyj Universitet Im.M.V. Lomonosova, Moskva, SSSR (Russian Federation)

    1966-01-15

    ] Le diagramme d'equilibre Fe-Si est tres complexe. A 1000 Degree-Sign K on constate la presence des phases suivantes: FeSi{sub 2}({beta}), FeSi, solutions solides de silicium dans {alpha} et {alpha}'. Les auteurs ont mesure la force electromotrice des cellules electrochimiques: Fe|Fe{sup 2+} , KI + Nal|Fe-Si pour 600-800 Degree-Sign C liquide Les alliages ont ete obtenus a partir d'elements de tres grande purete par la methode de la metallurgie des poudres et soumis a un recuit prolonge. L'etude a porte sur dix alliages ayant une teneur en silicium de 85 a 4%, dans toutes les zones d'une coupe du diagramme d'equilibre a 1000 Degree-Sign K. On a calcule les valeurs integrales de {Delta}G, {Delta}H et {Delta}S relatives a la formation des siliciures FeSi{sub 2} ({beta}), FeSi et Fe{sub 3}Si pour la temperature moyenne de l'intervalle des experiences (1000 Degree-Sign K), ainsi que (en utilisant la capacite thermique des siliciures, du fer et du silicium) pour 298, 1188 et 1798 Degree-Sign K. La chaleur de formation des siliciures mentionnes, a 298{sup K}, est de -19,4, -17,6 et -22,4 kcal/mol respectivement. Les valeurs deja publiees permettent de calculer la chaleur de formation de FeSi{sub 2,33} (leboiete - {alpha}) a 298{sup K}; onaconstatequ'elleetaitde -14,4kcal/mol. Les chaleurs calculees par les auteurs sont superieures aux valeurs experimentales de Corber et Olsen de 1,5 a 3 kcal. Quant aux chaleurs de melange, qui ont ete calculees pour les alliages liquides, elles concordent parfaitement avec les valeurs publiees. Les valeurs obtenues peuvent etre considerees comme resultant de la modification que subit le caractere du lien dans les siliciures, en effet, le lien metallique devient covalent lorsque la teneur en silicium augmente. En partant des valeurs relatives aux alliages (solutions de silicium dans du fer alpha) on a calcule les activites du fer. Il a ete constate que la transformation observee anterieurement {alpha} Rightwards

  6. Workstations studies and radiation protection; Etudes de postes et radioprotection

    Energy Technology Data Exchange (ETDEWEB)

    Lahaye, T. [Direction des relations du travail, 75 - Paris (France); Donadille, L.; Rehel, J.L.; Paquet, F. [Institut de Radioprotection et de Surete Nucleaire, 92 - Fontenay-aux-Roses (France); Beneli, C. [Paris-5 Univ., 75 (France); Cordoliani, Y.S. [Societe Francaise de Radioprotection, 92 - Fontenay-aux-Roses (France); Vrigneaud, J.M. [Assistance Publique - Hopitaux de Paris, 75 (France); Gauron, C. [Institut National de Recherche et de Securite, 75 - Paris (France); Petrequin, A.; Frison, D. [Association des Medecins du Travail des Salaries du Nucleaire (France); Jeannin, B. [Electricite de France (EDF), 75 - Paris (France); Charles, D. [Polinorsud (France); Carballeda, G. [cabinet Indigo Ergonomie, 33 - Merignac (France); Crouail, P. [Centre d' Etude sur l' Evaluation de la Protection dans le Domaine Nucleaire, 92 - Fontenay-aux-Roses (France); Valot, C. [IMASSA, 91 - Bretigny-sur-Orge (France)

    2006-07-01

    This day on the workstations studies for the workers follow-up, was organised by the research and health section. Devoted to the company doctors, for the competent persons in radiation protection, for the engineers of safety, it presented examples of methodologies and applications in the medical, industrial domain and the research, so contributing to a better understanding and an application of regulatory measures. The analysis of the workstation has to allow a reduction of the exposures and the risks and lead to the optimization of the medical follow-up. The agenda of this day included the different subjects as follow: evolution of the regulation in matter of demarcation of the regulated zones where the measures of workers protection are strengthened; presentation of the I.R.S.N. guide of help to the realization of a workstation study; implementation of a workstation study: case of radiology; the workstation studies in the research area; Is it necessary to impose the operational dosimetry in the services of radiodiagnostic? The experience feedback of a competent person in radiation protection (P.C.R.) in a hospital environment; radiation protection: elaboration of a good practices guide in medical field; the activities file in nuclear power plant: an evaluation tool of risks for the prevention. Methodological presentation and examples; insulated workstation study; the experience feedback of a provider; Contribution of the ergonomics to the determiners characterization in the ionizing radiation exposure situations;The workstations studies for the internal contamination in the fuel cycle facilities and the consideration of the results in the medical follow-up; R.E.L.I.R. necessity of workstation studies; the consideration of the human factor. (N.C.)

  7. The circular electrical mobility spectrometer; theory, performances and applications

    International Nuclear Information System (INIS)

    Mesbah, Boualem

    1995-04-01

    A new type of electrical mobility spectrometer (S.M.E.C.) has been designed in the Service d'Etudes et de Recherches en Aerocontamination et en Confinement (CEA) laboratories. It differs from classical electrical mobility spectrometers in its plan circular geometry and its radial flow. This gives some advantages and the possibility of new applications. The theories that we derive for the different versions of this device are confirmed by experimental results obtained using aerosol particles with known electrical mobility. The S.M.E.C's performances are tested for several applications: - controlled surface contamination, - monodisperse aerosol production, - fine and ultrafine aerosol sizing. (author) [fr

  8. Synthesis, characterization, kinetic and thermodynamic studies of the dissolution of ThO{sub 2} and of solid solutions Th{sub 1-x}M{sub x}O{sub 2} (M = U, Pu); Synthese, caracterisation et etudes cinetique et thermodynamique de la dissolution de ThO{sub 2} et des solutions solides Th{sub 1-x}M{sub x}O{sub 2} (M = U, Pu)

    Energy Technology Data Exchange (ETDEWEB)

    Heisbourg, G

    2003-12-01

    The aim of this work was to understand the mechanisms of dissolution of ThO{sub 2} and of thorium mixed oxides such as Th{sub 1-x}U{sub x}O{sub 2} and Th{sub 1-x}Pu{sub x}O{sub 2} in aqueous, oxygenated or inert media. Several solids have been synthesized by precipitation in oxalic medium: Th{sub 1-x}U{sub x}O{sub 2} (x= 0.11; 0.24; 0.37; 0.53; 0.67; 0.81 and 0.91) and Th{sub 1-x}Pu{sub x}O{sub 2} (x= 0.13; 0.32 and 0.66). They have been characterized by XRD, SEM, TEM, XPS, XAS, PIXE and EPMA. The sintering conditions of these materials have been studied and optimized in order to obtain sintered samples with a measured density very near the theoretical densities. A kinetic study of the dissolution of ThO{sub 2} and of solid solutions Th{sub 1-x}U{sub x}O{sub 2} has been carried out in several aqueous media (HNO{sub 3}, HCl, H{sub 2}SO{sub 4}) in terms of several parameters: protons concentration, temperature, pH, ionic strength, nature of the electrolyte solution and uranium molar ratio for the solid solutions Th{sub 1-x}U{sub x}O{sub 2} in order to determine the kinetic laws of dissolution of the solid solutions having different compositions comparatively to ThO{sub 2}. The leaching tests carried out in natural waters of compositions near those of the deep geologic sites considered for the storage of nuclear wastes have shown that the dissolution of the solids was bound to the complexing effect of the constitutional ions of the water considered. The leaching tests carried out on sintered samples of the same composition have led to the same normalized dissolution velocities. The thermodynamic aspect of the dissolution of the solid solutions Th{sub 1-x}U{sub x}O{sub 2} in nitric medium has been studied at last. (O.M.)

  9. Contribution to the study of french pitchblendes; Contribution a l'etude des pechblendes francaises

    Energy Technology Data Exchange (ETDEWEB)

    Geffroy, J [Commissariat a l' Energie Atomique, Lab. de Mineralogie, Centre de Chatillon (France). Centre d' Etudes Nucleaires; Sarcia, J A [Commissariat a l' Energie Atomique, Div. de la Crouzille, Haute Vienne (France). Centre d' Etudes Nucleaires

    1955-07-01

    The authors first review the characteristics of uraninite-pitchblende, as deduced of present literature. They set apart from typical pitchblende a black oxide aspect, which probably corresponds to neo-formations, and a 'para-pitchblende' aspect, which they relate to deep sur-oxidation of normal pitchblende. They insist on the easy replacement of pitchblende by silica. and give indications as to changes in vein stones (fluorite, quartz, etc...). A detailed study of paragenesis and successions in french uranium districts follows (including discussion of uranium of uranium-bearing coals). The authors attempt to classify french pitchblende veins. They are chiefly epithermal and poor in satellite ores. Three types of deposits are identified: massive - pitchblende type, silica type, fluorite type. These deposits, as those of Portugal, are included in granite, Central-European peri-batholitic types where uranium associates which Ni, Co, Bi and Ag, are in France both rare and poor. Finally, the authors attempt to bring out in the european Hercynian area a particular distribution of paragenetic types. (authors) [French] Les auteurs recapitulent d'abord les caracteres et les occurences de l'uraninite - pechblende, tels qu'ils peuvent etre degages de l'actuelle bibliographie. Ils exposent ensuite les faits qui du point de vue mineralogique seulement ressortent de l'etude mineralogique et chalcographique des pechblendes francaises et de leurs satellites. Ils distinguent de la pechblende-type un facies oxyde noir; correspondant probablement a une neoformation, et un facies parapechblende, qui est rapporte a une sur oxydation hypogene de la pechblende proprement dite. Ils insistent sur le facile remaniement de la pechblende par la slice; et donnent quelques precisions sur les modifications des gangues (fluorine, quartz, etc...). Suit l'etude detaillee des parageneses et des successions dans les districts uraniferes francais: Divisions du Limousin, de Grury, de Lachaux et de

  10. Study of some properties of zirconium phosphate; Etude de quelques proprietes du phosphate de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Prospert, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-05-01

    Zirconium phosphate has been studied with a view to using it as an ion exchanger: the first objective was to develop a method of preparation easy to apply and also reproducible. To this end, several tests were carried out varying the molar ratios of phosphorus and of zirconium. Some physical properties such as the diffraction of X-rays were examined. The work then involved certain chemical properties, particularly the percentages of free water and structural water given by the loss on calcination, the Karl-Fisher method and the weight losses by thermogravimetry. Finally an attempts was made to apply the exchanger to the separation of alkaline ions. The static tests showed that the order of fixation of these ions was Cs{sup +} > Rb{sup +} >> K{sup +} > Na{sup +}. Tests with columns showed that Na{sup +} and K{sup +} were easily separable, as was the Rb{sup +}-Cs{sup +} mixture, this last pair being fairly difficult to dissociate. (author) [French] Le phosphate de zirconium a ete etudie en vue de son utilisation comme echangeur d'ions: le premier but a atteindre a ete de mettre au point une preparation pouvant se reveler facilement utilisable ainsi qu'aisement reproductible. A cet effet, plusieurs essais ont ete effectues en faisant varier les rapports molaires du phosphore et du zirconium. Quelques proprietes physiques, telle la diffraction des rayons X, ont ete abordees. Ensuite, l'etude a porte sur certaines proprietes chimiques, particulierement les pourcentages d'eau libre et d'eau de structure par des pertes au feu, utilisation de la methode de Karl-Fisher, ainsi que des pertes de poids a la thenmobalance. Enfin, on a tente d'utiliser l'echangeur a la separation des ions alcalins. Les etudes statiques ont permis de constater que l'ordre de fixation de ces ions etait Cs{sup +} > Rb{sup +} >> K{sup +} > Na{sup +}. Les essais effectues en colonne ont montre que Na{sup +} et K{sup +} etaient aisement separables entre eux, ainsi que du couple Rb{sup +}-Cs{sup +}, ce

  11. The formation of scientists and technicians at the 'Centre d'Etudes Nucleaires' at Saclay; Formation des scientifiques et des techniciens au Centre d'Etudes Nucleaires de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Debiesse, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    The considerable needs in research workers and scientists which are asked by the nuclear energy obliged the Commissariat a l'Energie atomique to deal with a particular effort to increase the quantitative and qualitative formation of scientists. Most various ways have been used. 1- A National Institute of Nuclear Sciences and Nuclear Techniques was created, by a joint decree of the Prime Minister and the Minister for National Education (june 18, 1957). This Institute of Higher Teaching (250 students) indulges in the following matters: atomic engineering, quantum mechanics, theory and technic of particle accelerators, special metallurgy, radiobiology, thermic and mechanics of fluids. 2- An associated centre of the 'Conservatoire National des Arts et Metiers' waeated (200 students) for technical assistants, drawers, etc. 3- In contribution with both electronic industry and Ministry of Work, the Centre d'Etudes Nucleaires contributes to an accelerated formation of technical assistants into Professional Centres. Conclusion: Training of scientists and research workers is one of the most important activities of the Centre d'Etudes Nucleaires de Saclay. Without losing its technical efficiency, it has supplied and varied means adapted to the various purposes that we shall reach. (author)Fren. [French] Les besoins considerables actuels et previsibles en chercheurs et scientifiques necessites par l'avevement de l'energie nucleaire imposaient au Commissariat a I'Energie atomique un effort particulier pour augmenter la formation quantitative et qualitative des scientifiques. Les moyens les plus divers ont ete mis en oeuvre: 1- Creation de l'Institut National des Sciences et Techniques Nucleaires par decret de la Presidence du Conseil et de l'Education Nationale en date du 18.6.57. Cet Institut d'Enseignement Superieur (250 etudiants) donne des cours en: genie atomique, mecanique quantique, theorie et technique des Accelerateurs de particules, metallurgie speciale, radiobiologie

  12. Optical spectroscopy of Cm{sup 3+} in the elpasolite Cs{sub 2} NaYCl{sub 6}. Application in the structural study of Cm(III) sorption on phosphate materials; Spectroscopie optique de Cm{sup 3+} dans l`elpasolite Cs{sub 2}NaYCl{sub 6}. Application a l`etude structurale de la sorption de Cm(III) sur des materiaux phosphates

    Energy Technology Data Exchange (ETDEWEB)

    Cavellec, Ronan [Universite de Paris Sud, 91 - Orsay (France)

    1998-05-15

    Radwaste management involves important research. In order to contribute to this program we proposed the examination of two different and complementary aspects of nuclear waste: the detection by laser spectroscopy of trivalent actinide ions diluted in a crystal host and the migration of radionuclides through different barriers in geosphere that is related to understanding and modelling the sorption processes. In both cases the spectro-fluorimetry laser is used to investigate different phenomenological processes at microscopic scale. The first part of the thesis deals with the investigation of Cm{sup 3+} energy levels in Cs{sub 2}NaYCl{sub 6}. From the analysis of excitation and emission spectra 52 crystal-field levels have been assigned and the phenomenological parameters calculated. A discussion about these parameters, compared with those in case of LaCl{sub 3} and ThO{sub 2} cases, is given. An intense green fluorescence has been found for the first time for Cm{sup 3+} in elpasolite. Thus, this material seems to be a promising solid for the analytical application of actinides such as Cm{sup 3+} and Am{sup 3+} ions. In the second part the sorption of curium (5{center_dot}10{sup -8} mol {center_dot}l{sup -1}) onto phosphate materials was studied. The ionic strength, electrolyte nature and complexing agent were investigated. The laser spectro-fluorimetry is shown to be a powerful technique. The formation of surface complexes for ZrP{sub 2}O{sub 7}, Zr{sub 2}O(PO{sub 4}){sub 2} and Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7} has been demonstrated. Fluorescence lifetime measurements indicate that in complexing medium the aqueous complex of Cm is sorbed preferentially to the Cm{sup 3+} free ion onto the solid 82 refs., 54 figs., 35 tabs.

  13. Autoradiographic methods for studying marked volatile substances (1961); Methode.d'etude autoradiographique de substances marquees volatiles (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, Y; Wepierre, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    de Pellerin (1957) evite cette dessication, mais la comparaison a l'echelle histologique de l'autoradiographie avec le document biologique lui-meme est difficile sinon impossible. Cependant, nous nous sommes inspire de certains points de chacune des deux methodes pour proposer la technique suivante d'etude autoradiographique de molecules marquees volatiles: 1- nous preparons la surface du bloc congele a autoradiographier a l'aide d'un microtome a congelation; 2- la derniere coupe de 20 {mu} d'epaisseur, dont les elements histologiques font face a ceux du bloc, est dessechee au froid et sert de document biologique de reference a l'autoradiographie obtenue, comme il est indique en 3; 3- les films radiographiques sont appliques sur le bloc congele a -30 deg. C. Les autoradiographies correspondent a la radioactivite de la molecule volatile et de ses produits de degradation non volatils. 4- De plus, le film radiographique est applique sur la coupe de 20 {mu} prealablement dessechee a -20 deg. C. Cette autoradiographie correspond a la radioactivite des produits de degradation non volatils de la molecule. 5- Nous nous sommes assuree de l'absence de diffusion de la molecule volatile et d'effets pseudo-radiographiques (photochimiques et autres). Cette methode qui nous a permis d'etudier la distribution d'un carbure, le paracymene ({sup 14}C) 7 a l'echelle macroscopique sur la souris entiere et a l'echelle microscopique sur la peau de chien, est susceptible d'une application generale. (auteurs)

  14. Development of a gas-ionization {beta}-spectrometer; Etude et realisation d'un spectrometre {beta} a ionisation gazeuse

    Energy Technology Data Exchange (ETDEWEB)

    Le Du, R [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1968-05-15

    We intend to develop in our laboratory a {beta}-spectrometer. This apparatus will have two main objectives: 1 - the determination of the nature and the degree of purity of certain {beta}-emitting radioactive substances; 2 - the study of an activity calibration process for {beta}-emitting radioactive sources. (author) [French] Nous nous proposons d'etudier et de realiser dans notre laboratoire un spectrometre {beta}. Cet appareil aura deux buts principaux: 1 - determiner la nature et le degre de purete de certains corps radioactifs emetteurs {beta}; 2 - permettre l'etude d'un procede d'etalonnage en activite de sources radioactives emetteurs {beta}. (auteur)

  15. Etude sur la prédiction de l'inversion de phase Phase Inversion Behavior for Liquid Dispersions

    Directory of Open Access Journals (Sweden)

    Decarre S.

    2006-12-01

    Full Text Available En écoulement diphasique eau-huile dans lequel une des phases est dispersée dans l'autre, il peut se produire sous certaine condition d'écoulement une inversion de phase, la phase continue devenant dispersée. Ce phénomène, qui contrôle la nature de la phase mouillant la paroi de la conduite dans laquelle s'écoulent les phases, a des conséquences importantes sur la corrosion et sur la perte de charge. Nous présentons un modèle d'inversion, basé sur une approche thermodynamique, valable pour tous les régimes d'écoulement. Les données expérimentales utilisées pour la validation du modèle sont issues d'une étude bibliographique. En écoulement laminaire, cette approche conduit à des résultats similaires à ceux du modèle de Yeh. Pour la plupart des données disponibles, ce modèle prédit bien la fraction critique pour laquelle l'inversion de phase se produit. In two phase oil-water dispersed flow, a phase inversion may occur whereby the continuous phase becomes dispersed. This phenomenon which controls the nature of the phase in contact with the pipe has a great importance on the corrosion and on the pressure drop. A model for the phase inversion is presented, it is based on a thermodynamic approach, and it is valid for all flow regimes. Experimental data from the litterature are used to validate the model. In laminar flow, this approach gives similar results to those obtained by Yeh. For most data, the model agrees well with the experimental data.

  16. Stable isotope separation; Separations physicochimiques d'isotopes stables realisations et etudes de petites productions

    Energy Technology Data Exchange (ETDEWEB)

    Botter, F; Molinari, Ph; Dirian, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    capacite totale environ 2 litres, il a ete realise un appareil preparatif, de faible volume mort, permettant de produire 1 litre de D{sub 2} pur a partir des melange 50 p.100 D{sub 2}, 50 p.100 H{sub 2} en 12 minutes environ. Sur le plan theorique, en premiere approximation, nous assimilions la chromatographie a un fractionnement contre courant en negligeant resistance superficielle a l'echange ainsi que diffusions longitudinale et laterale. On etablit graphiquement ou par calcul, le nombre de plateaux theoriques necessires a un certain enrichissement de la phase gazeuse ce qui permet de comparer l'efficacite de colonnes qui different par leur masse palladiee. DIFFUSION THERMIQUE: Afin d'assurer une separation des isotopes de l'hydrogene, on a realise une installation de diffusion thermique construite en acier inoxydable et entierement telecommandee. La cascade de separation se compose de deux couples identiques de colonnes a fil central chaud. Chaque couple peut travailler isolement ou etre relie par thermosyphon. La temperature du fil chaud est de l'ordre de 1000 deg C entretenue par courant redresse. Avec cette installation, des echantillons d'hydrogene a la teneur isotopique en deuterium inferieure a 0,5 ppm. ont ete obtenus a partir d'un gaz initial a 32 ppm. Il a ainsi ete possible de preparer du tritium a la teneur de 99,3 p. 100 a partir d'un gaz d'une teneur initale de 6 p. 100. Pour la separation quantitative du Xenon enrichi cinq fois en {sup 124}Xe par thermodiffusion on a construit deux cascades identiques de 5 colonnes fonctionnant en parallele, reliees par thermosyphon ou par tube capillaire lie a un oscillateur thermique de gaz. Le fil central en tungstene fonctionne a 1200 deg C. Les colonnes sont groupees a la facon d'un faisceau tubulaire d'un echangeur de chaleur dans une virole de 30 cm de diametre ou circule l'eau de refroidissement. Des etudes sont en cours pour augmenter le facteur de separation de la cascade en utilisant un gaz auxiliaire. ECHANGE

  17. Preparation and study of dialkyl nitroxide radicals; Preparation et etude de radicaux nitroxydes diacyles

    Energy Technology Data Exchange (ETDEWEB)

    Chenavas, P. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    These radicals are obtained by oxidation of N-hydroxy-imides with lead tetracetate or p-nitro-perbenzoic acid. These imides are prepared by heating dicarboxylic acids anhydrides with benzyloxy-amine followed by catalytic hydrogenation of N-benzyloxy-imides so obtained. Two series of radicals have mainly been studied, the first concerning five-membered cyclic imides, the second six-membered cyclic imides, these molecules having methyls substituents or no on the carbon ring. N. M. R. spectra of some O-benzyl-imides have been analysed. These different results have made it possible to study the conformation and stereochemistry of these imides. (author) [French] Ces radicaux sont obtenus par oxydation d'imides N-hydroxyles par le tetracetate de plomb ou l'acide p-nitroperbenzoique; ces imides sont prepares par chauffage d'anhydrides de diacides en presence de benzyloxyamine suivie d'une hydrogenation catalytique des N-benzyloxyimides ainsi obtenus. Deux series de radicaux ont principalement ete etudies: la premiere relative a des imides cycliques a cinq chainons, la seconde a des imides cycliques a six chainons, ces molecules ayant des substituants methyles ou non sur la chaine carbonee. Les derives O-benzyles de quelques-uns de ces imides ont ete analyses en R. M. N. Ces differents resultats ont permis une etude de la conformation et de la stereochimie de ces imides. (auteur)

  18. The abject gaze and the homosexual body: Flandrin's Figure d'Etude.

    Science.gov (United States)

    Camille, M

    1994-01-01

    This article charts the history of the reception, reproduction and appropriation of a single image that has recently become a kind of "gay icon"--the Figure d'Etude in the Louvre, painted by Hippolyte Flandrin in 1835. Initially no more than a neo-classical academic exercise, the formal emptiness of this picture meant that it could be re-invested and reinscribed with new meanings and new titles at every turn. Emblematic of the anxious visibility/invisibility of the newly discovered homosexual body during a period when the gaze still had to be kept a dark secret, Flandrin's image only "came out" in its later photographic reworkings by Frederick Holland Day and Baron von Gloeden. After being reproduced for a specifically homosexual audience early this century, the popular Romantic pose of the young man curled-up in profile became a standard one, reappearing recently in the photographs of Robert Mapplethorpe. The inactive, abject and inward-turned isolation of the figure with its narcissistic self-absorption makes it, in my view, a profoundly negative stereotype of the gay gaze and the homosexual body. Flandrin's figure nonetheless appears today on gay merchandise world-wide as a sign of our separate and secluded subject positions and our community's unwillingness to radically alter older imposed and inherited classical stereotypes.

  19. Study of copper fluorination; Contribution a l'etude de la fluoruration du cuivre

    Energy Technology Data Exchange (ETDEWEB)

    Gillardeau, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-02-01

    This report deals with the action of fluorine on copper. Comprehensive descriptions are given of the particular technological methods and of the preparation of the reactants. This fluorination reaction has been studied at medium and low fluorine pressures. A nucleation and growth phenomenon is described. The influence of a pollution of the gas phase on the fluorination process is described. The solid-state reaction between cupric fluoride and cooper has also been studied. A special study has been made of the growth of copper deposits by thermal decomposition of gaseous fluorides. (author) [French] Ce rapport traite de la reaction du fluor sur le cuivre. Les methodes technologiques particulieres ainsi que les preparations des reactifs sont largement developpees. Cette reaction de fluoruration est etudiee sous pressions moyennes et sous basses pressions de fluor. Un phenomene de germination et croissance est decrit. L'influence de la pollution de la phase gazeuse sur le processus de fluoruration est rapportee. La reaction a l'etat solide du fluorure cuivrique sur le cuivre a egalement ete etudiee. La croissance de depots de cuivre par decomposition thermique des fluorures de cuivre gazeux fait l'objet d'une etude speciale. (auteur)

  20. Preparation and study of dialkyl nitroxide radicals; Preparation et etude de radicaux nitroxydes diacyles

    Energy Technology Data Exchange (ETDEWEB)

    Chenavas, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    These radicals are obtained by oxidation of N-hydroxy-imides with lead tetracetate or p-nitro-perbenzoic acid. These imides are prepared by heating dicarboxylic acids anhydrides with benzyloxy-amine followed by catalytic hydrogenation of N-benzyloxy-imides so obtained. Two series of radicals have mainly been studied, the first concerning five-membered cyclic imides, the second six-membered cyclic imides, these molecules having methyls substituents or no on the carbon ring. N. M. R. spectra of some O-benzyl-imides have been analysed. These different results have made it possible to study the conformation and stereochemistry of these imides. (author) [French] Ces radicaux sont obtenus par oxydation d'imides N-hydroxyles par le tetracetate de plomb ou l'acide p-nitroperbenzoique; ces imides sont prepares par chauffage d'anhydrides de diacides en presence de benzyloxyamine suivie d'une hydrogenation catalytique des N-benzyloxyimides ainsi obtenus. Deux series de radicaux ont principalement ete etudies: la premiere relative a des imides cycliques a cinq chainons, la seconde a des imides cycliques a six chainons, ces molecules ayant des substituants methyles ou non sur la chaine carbonee. Les derives O-benzyles de quelques-uns de ces imides ont ete analyses en R. M. N. Ces differents resultats ont permis une etude de la conformation et de la stereochimie de ces imides. (auteur)

  1. Study of {gamma}'s in Naiade; Etude des gamma de Naiade

    Energy Technology Data Exchange (ETDEWEB)

    Millot, J P; Rastoin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Following a study of the gamma sources, the flux of gamma of different energies in the swimming pool is investigated. The biological dose can thus be obtained by calculation, and compared with the results given by photographic plates. The influence of photoneutrons is estimated by calculation, and research is being carried out on their influence on the thermal neutron flux curve on the axis of the uranium plate, with the plate emitting neutrons and with the plate protected by boral. (author) [French] Apres l'etude des sources de gamma, l'on etudie le flux de gamma de differentes energies dans la piscine. La dose biologique peut etre obtenue ainsi par le calcul et comparee avec les resultats donnes par les plaques photographiques. L'influence des photoneutrons est estimee par le calcul et l'on recherche leur influence sur la courbe de flux de neutrons thermiques sur l'axe de la plaque d'uranium, la plaque emettant des neutrons et la plaque protegee par du boral. (auteur)

  2. Technological study of organic fluids; Etudes technologiques des fluides caloporteurs organique

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Under contract to EURATOM (MM. VAN der VENNE and HANNAERT), the C.E.A. and the Progil Society have collaborated on a technological study of the terphenyls. The results obtained from the radiolysis and pyrolysis of the product OM2 (70 p. 100 m-terphenyl, 25 p. 100 o-terphenyl, 5 p. 100 p-terphenyl) are reported. Using two pile loops at temperatures up to 450 deg. C, a phenomena of accelerated pyrolysis on the radiolized material has been demonstrated. Some by-products of the petroleum industry have also been studied, with a view to finding substitutes for terphenyl. (author) [French] Le C.E.A. et la Societe PROGIL ont entrepris en commun sous contrat EURATOM (MM. VAN der VENNE et HANNAERT) une etude technologique des terphenyles. Les resultats de radiolyse et de pyrolyse obtenus sur le produit OM2 (70 p. 100 m-terphenyle, 25 p. 100 o-terphenyle. 5 p. 100 de p-terphenyle) sont exposes. L'exploitation de deux boucles en pile jusqu'a des temperatures de 450 deg. C a mis en evidence un phenomene de pyrolyse acceleree sur le produit radiolyse. On a etudie egalement quelques sous-produits de l'industrie petroliere dans le but de trouver des substituts au terphenyle. (auteur)

  3. Underground nuclear explosions. Geological survey of the cavities; Explosions nucleaires souterraines etude geologique des cavites

    Energy Technology Data Exchange (ETDEWEB)

    Faure, J [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1969-07-01

    A geological survey of underground nuclear explosions makes it possible to determine the main characteristics of the cavity formed. The lower portion is spherical; the same was very likely true of the roof, which collapses in the majority of media with the exception of rock-salt. Its radius, for a given bomb size, can vary by a factor of two according to the type of rock. The lay-out of its contents depends on the characteristics of the solid and liquid products at the moment of the roof collapse; according to the medium involved, mixing of the rubble and the mud-flow occurs (granite) or does not occur (tuff and alluvia). In all media, the average physical properties can be evaluated. (author) [French] L'etude geologique d'explosions nucleaires souterraines permet de determiner les principaux caracteres de la cavite creee. Sa partie inferieure est spherique; il en etait vraisemblablement de meme de sa voute, effondree dans la plupart des milieux a l'exception du sel gemme. Son rayon, a energie d'engin egale, varie selon les roches du simple au double. La disposition de son contenu depend des caracteristiques des produits solides et liquides au moment de la chute du toit; selon le cas, il n'y a pas (tuf et alluvions) ou il y a (granite) melange des eboulis et des laves. Dans tous les milieux, les proprietes physiques moyennes peuvent etre evaluees. (auteur)

  4. High-Temperature Gas-Cooled Reactor Critical Experiment and its Application to Thorium Absorption Rates; Experience Critique pour l'Etude d'un Reacteur a Haute Temperature, Refroidi par un Gaz et son Application a la Determination des Taux d'Absorption du Thorium; Kriticheskij opyt, postavlennyj na vysokotemperaturnom reaktore s gazovym okhlazhdeniem, i primenenie ego dlya opredeleniya stepeni pogloshcheniya toriya; Experimento Critico Efectuado en un Reactor de Elevada Temperatura Refrigerado por Gas y su Aplicacion para Calcular los Indices de Absorcion del Torio

    Energy Technology Data Exchange (ETDEWEB)

    Bardes, R. G.; Brown, J. R.; Drake, M. K.; Fischer, P. U.; Pound, D. C.; Sampson, J. B.; Stewart, H. B. [General Dynamics Corporation,San Diego, CA (United States)

    1964-04-15

    the fact that the thorium is dispersed in graphite and the usual cadmium-ratio technique is difficult to apply. Comparison of experimental and theoretical results shows excellent agreement over a range of variables. In addition, the results of both activation and reactivity measurements of Doppler coefficient are in agreement, a fact which is felt to be significant in view of the disparity between results from these two techniques in the literature. (author) [French] Lors de l'etude du reacteur HTGR a haute temperature refroidi par un gaz, et de son premier prototype a Peach Bottom, la General Atomic Division de la societe General Dynamics a decide qu'il fallait proceder a une experience critique pour obtenir certaines donnees d'entree necessaires pour l'analyse nucleaire. Aux fins de l'etude nucleaire theorique, les besoins particuliers en donnees d'entree relatives aux absorptions par le thorium ont amene les ingenieurs a concevoir un assemblage experimental critique compose d'un reseau central entoure d*une region tampon et d'une region de commande. Ce type.d'assemblage, dans lequel on peut creer le spectre a mesurer dans le reseau central relativement petit ayant la geometrie voulue, permet d'obtenir des donnees d'entree tres diverses pour les etudes de projets nouveaux, au point de vue de l'analyse nucleaire. Le memoire indique les avantages particuliers que presente cette methode par rapport a celle qiu consiste a construire une maquette, ainsi que le role de la theorie pour determiner quelles experiences sont le plus utiles et comment utiliser ensuite ces experiences dans la verification des procedes d'etude. Les auteurs ont mis au point deux methodes relativement nouvelles qui peuvent etre utilisees avec l'assemblage decrit ci-dessus: une methode d'oscillation de la reactivite pour determiner le coefficient Doppler pour le thorium; une methode d'activation pour determiner a la fois l'integrale de resonance pour le thorium disperse dans le graphite et ses

  5. Study of the reaction {pi}{sup -}p {yields} {pi}{sup -}{pi}{sup 0} p at 2.77 GeV/c for low momentum transfer of the proton. Application to the Chew-Low extrapolation method for the {pi}{sup -}{pi}{sup 0} elastic scattering; Etude de la reaction {pi}{sup -}p {yields} {pi}{sup -}{pi}{sup 0} p a 2.77 GeV/c pour de faibles impulsions du proton diffuse. Application de la methode d'extrapolation de Chew et Low a la diffusion elastiques {pi}{sup -}{pi}{sup 0}

    Energy Technology Data Exchange (ETDEWEB)

    Baton, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-05-01

    Study of the reaction {pi}{sup -}p {yields} {pi}{sup -}{pi}{sup 0} p at 2.77 GeV/c carried out in the CERN 2 meter large liquid hydrogen bubble chamber at the proton synchrotron, shows that 70 per cent of this reaction goes through {pi}{sup -}p {yields} {rho}{sup -}p channel. The high statistics allow us to specify the mass and the width of the {rho}{sup -} resonance. In other hand, if the {rho}{sup -} production parameters are independent of the {rho}{sup -} width, it is not the same case for the decay parameters. In the second part, the Chew-Low extrapolation method allows us to determine the {pi}{sup -}{pi}{sup 0} elastic cross section to the pole, and the phase shifts of the P waves in the isospin 1 state and S waves in the isospin 2 state. (author) [French] L'etude de la reaction {pi}{sup -}p {yields} {pi}{sup -}{pi}{sup 0} p a 2.77 GeV/c, effectuee a l'aide de la chambre a bulles a hydrogene liquide de 2 metres du CERN, exposee aupres du synchrotron a protons, montre que 70 pour cent de cette reaction passe par la voie {pi}{sup -}p {yields} {rho}{sup -}p. L'abondance de la statistique a permis de preciser la masse et la largeur de la resonance {rho}{sup -}. D'autre part, si les parametres de la production du {rho}{sup -} sont independants de la largeur de la resonance, il n'en est pas de meme des parametres de la desintegration. Dans la deuxieme partie, la methode d'extrapolation de Chew et Low permet de determiner la section efficace de diffusion elastique {pi}{sup -}{pi}{sup 0} au pole, ainsi que les dephasages des ondes P dans l'etat d'isospin 1 et S dans l'etat d'isospin 2. (auteur)

  6. Contribution to the study of the flow of adsorbed phases. Enrichment of binary Gaseous mixtures; Contribution a l'etude de l'ecoulement des phases absorbees. Enrichissement des melanges gazeux binaires

    Energy Technology Data Exchange (ETDEWEB)

    Sapet, J C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-12-15

    sujet dont il n'est pas besoin de souligner l'importance. L'auteur a imagine des techniques tres sensibles permettant d'etudier l'ecoulement des phases bidimensionnelles a travers des corps microporeux. Il a mis en evidence non seulement le role de la pression relative et de la nature des constituants (gaz et substrat) mais encore la relation entre la mobilite de l'adsorbat et les caracteristiques thermodynamiques de l'adsorption. L'auteur a traite de nombreux exemples concernant la diffusion soit de corps purs (n-butane, n-pentane, isopentane), soit de melanges binaires, et a montre d'une part que l'effet separatif de l'ecoulement tridimensionnel d'interface est maximum au voisinage de la monocouche, d'autre part que l'effet de masse est du second ordre par rapport au facteur structural de la molecule diffusante. Le probleme traite est important aussi bien sur le plan fondamental que sur celui des applications industrielles. (auteur)

  7. Study: control of atomic energy power plant; Etude de la regulation d'une installation atomique productrice d'energie

    Energy Technology Data Exchange (ETDEWEB)

    Dautray, R; Leny, J C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    We are studying the control of a very flexible atomic power plant, able to supply an independent network. Two systems have been examined: in the first the moderator pre-heats the light water, in the second, this preheating is dispensed with, subsequent to a study of the dynamics of the plant. Very complete linear approximation study is being effected on the model of the second system, all effects being taken into account. The reactor is stable at all power levels, though slight reactivity or load variations cause undamped power oscillations around the equilibrium level. (author)Fren. [French] Nous etudions la regulation d'une installation atomique d'une grande souplesse, pouvant eventuellement fournir de l'energie a un reseau isole. Deux versions de l'installation sont etudiees: dans la premiere le moderateur sert a rechauffer l'eau industrielle, mais l'etude dynamique conduit a supprimer ce rechauffage, ce qui donne la deuxieme version. On effectue sur celle-ci une etude en approximation lineaire tres complete ou l'on tient compte de differents effets. L'installation se montre stable a tous les niveaux de puissance. Toutefois, de petites perturbations de reactivite ou de charge entrainent des oscillations de puissance mal amorties autour de la position d'equilibre. (auteur)

  8. Methods for studying the radioactive contamination of plants (1963); Methodes d'etude de la contamination radioactive des vegetaux (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, R; Jeanmaire, L; Michon, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1963-07-01

    The authors first define the doctrine which led to the devising of a method for studying the radioactive pollution of plants, based on the use of simple techniques, having the possibility of being adapted for routine work, and so devised that each stage is proceeded with only if the preceding one justifies it. For each stage a study is effected comparing the results obtained by the use of more exact techniques. The second part describes in detail the techniques used. (authors) [French] Dans une premiere partie lea auteurs definissent la doctrine qui leur a permis d'elaborer une methode d'etude de la pollution radioactive des vegetaux, basee sur l'utilisation de techniques simples, se pretant au travail de serie et concues de telle maniere que chaque etape n'est abordee que si la precedente le justifie. Chaque etape fait l'objet d'une etude qui compare les resultats a ceux obtenue par des techniques plus precises. La deuxieme partie decrit dans le detail les techniques utilisees. (auteurs)

  9. Biological applications of the Moessbauer effect; Applications de l'effet Mossbauer a la biologie

    Energy Technology Data Exchange (ETDEWEB)

    Boulay, P [CEA Bruyeres-le-Chatel, 91 (France)

    1968-12-01

    The applications of Moessbauer spectrometry in the fields of physics and chemistry have been increasing steadily since its discovery in 1958. Attempts have been made to find applications in biology. Two possibilities of investigation exist in this field: the study of mechanical or vibrational movements in certain animal organs, and the determination of the organic molecular structure in a biological context. An example is given of each of these possibilities. (author) [French] Les applications de la spectrometrie Mossbauer dans le domaine de la physique et de la chimie n'ont cesse de progresser depuis sa decouverte en 1958. Des essais d'application a la biologie ont ete entrepris. Dans ce domaine il existe deux possibilites d'investigation: l'etude des mouvements mecaniques ou vibratoires de certaines organes d'animaux, et la determination de la structure moleculaire organique a destinee biologique. Un exemple est donne de chacune de ces possibilites. (auteur)

  10. Impact of the lubricating oil on thermodynamic performances of reversible heat pumps; Impact de l'huile de lubrification sur les performances thermodynamiques des pompes a chaleur reversibles

    Energy Technology Data Exchange (ETDEWEB)

    Youbi-Idrissi, M.

    2003-12-01

    This work deals with the effect of oil on the energy performances of refrigerating systems. To characterise this impact, two thermodynamic properties were studied: the solubility and the enthalpy. Thus, a simple measurement method was presented, allowing to study both transient and steady-state behaviour of various refrigerant/oil pairs. Thus, experimental data were validated and modelled. The suitable use of the solubility curves showed the zeotropic character of the refrigerant/oil mixture, which is directly reflected on the enthalpy calculation. For this property, a thermodynamic model was developed and experimentally validated. Its application led to a new presentation of the Mollier diagram taking into account the oil presence. It was then shown that, among all the circuit elements, the evaporator is the most penalized by the oil presence. Its performances decrease when the circulating mass fraction of oil increases, the superheat decreases and when the refrigerant-oil solubility increases. An experimental study on a reversible heat pump confirmed that if the circulation mass fraction of oil in the machine is lower than 2%, the impact of oil is reduced. Lastly, a local model of a refrigerating unit, initially charged with a zeotropic mixture, allowed to analyse the profiles of temperature, heat transfer coefficient and local composition of the refrigerant along a circuit. (author)

  11. Contribution to the study of french pitchblendes; Contribution a l'etude des pechblendes francaises

    Energy Technology Data Exchange (ETDEWEB)

    Geffroy, J. [Commissariat a l' Energie Atomique, Lab. de Mineralogie, Centre de Chatillon (France). Centre d' Etudes Nucleaires; Sarcia, J.A. [Commissariat a l' Energie Atomique, Div. de la Crouzille, Haute Vienne (France). Centre d' Etudes Nucleaires

    1955-07-01

    The authors first review the characteristics of uraninite-pitchblende, as deduced of present literature. They set apart from typical pitchblende a black oxide aspect, which probably corresponds to neo-formations, and a 'para-pitchblende' aspect, which they relate to deep sur-oxidation of normal pitchblende. They insist on the easy replacement of pitchblende by silica. and give indications as to changes in vein stones (fluorite, quartz, etc...). A detailed study of paragenesis and successions in french uranium districts follows (including discussion of uranium of uranium-bearing coals). The authors attempt to classify french pitchblende veins. They are chiefly epithermal and poor in satellite ores. Three types of deposits are identified: massive - pitchblende type, silica type, fluorite type. These deposits, as those of Portugal, are included in granite, Central-European peri-batholitic types where uranium associates which Ni, Co, Bi and Ag, are in France both rare and poor. Finally, the authors attempt to bring out in the european Hercynian area a particular distribution of paragenetic types. (authors) [French] Les auteurs recapitulent d'abord les caracteres et les occurences de l'uraninite - pechblende, tels qu'ils peuvent etre degages de l'actuelle bibliographie. Ils exposent ensuite les faits qui du point de vue mineralogique seulement ressortent de l'etude mineralogique et chalcographique des pechblendes francaises et de leurs satellites. Ils distinguent de la pechblende-type un facies oxyde noir; correspondant probablement a une neoformation, et un facies parapechblende, qui est rapporte a une sur oxydation hypogene de la pechblende proprement dite. Ils insistent sur le facile remaniement de la pechblende par la slice; et donnent quelques precisions sur les modifications des gangues (fluorine, quartz, etc...). Suit l'etude detaillee des parageneses et des successions dans les districts uraniferes francais: Divisions du

  12. Monte-Carlo method for studying the slowing down of neutrons in a thin plate of hydrogenated matter; Methode de Monte-Carlo pour l'etude du ralentissement des neutrons dans une plaque mince de matiere hydrogenee

    Energy Technology Data Exchange (ETDEWEB)

    Ribon, P; Michaudon, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The studies of interaction of slow neutrons with atomic nuclei by means of the time of flight methods are made with a pulsed neutron source with a broad energy spectrum. The measurement accuracy needs a high intensity and an output time as short as possible and well defined. If the neutrons source is a target bombarded by the beam of a pulsed accelerator, it is usually required to slow down the neutrons to obtain a sufficient intensity at low energies. The purpose of the Monte-Carlo method which is described in this paper is to study the slowing down properties, mainly the intensity and the output time distribution of the slowed-down neutrons. The choice of the method and parameters studied is explained as well as the principles, some calculations and the program organization. A few results given as examples were obtained in the line of this program, the limits of which are principally due to simplifying physical hypotheses. (author) [French] l'etude de l'interaction des neutrons lents avec les noyaux atomiques par la methode du temps de vol s'effectue avec une source pulsee de neutrons dont le spectre en energie est assez etendu. La precision des mesures demande que la source soit intense et que la duree d'emission des neutrons soit breve et bien definie. Si la source est une cible bombardee par le faisceau de particules d'un accelerateur pulse, il est generalement indispensable de ralentir les neutrons pour avoir une intensite suffisante a basse energie. Nous presentons ici une methode de Monte-Carlo pour l'etude detaillee de ce ralentissement, notamment l'intensite et la distribution des temps de sortie des neutrons ralentis. Cette presentation comprend: la justification du choix de la methode de Monte-Carlo, les principes generaux, les differentes etapes du calcul et du programme ecrit pour le calculateur electronique IBM 7090. Nous indiquons aussi les restrictions qui sont apportees au domaine d'application de ce programme et qui proviennent surtout des

  13. Study of microinstabilities due to an anisotropic velocity distribution function of the particles of a homogeneous plasma; Etude des microinstabilities liees a l'anisotropie de la fonction de distribution des vitesses des particules d'un plasma homogene

    Energy Technology Data Exchange (ETDEWEB)

    Hennion, F [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-06-01

    A study is made of instabilities in a plasma with an ion velocity distribution function of the form: f{sub oi} = 1 / (2*{pi}*{alpha}{sub p}e{sub i}*{alpha}{sub p}a{sub i}) * {lambda}({nu}{sub p}e - {alpha}{sub p}e{sub i}) * e{sup -}(v{sub pa2}/{alpha}{sub pai2}). The plasma is assumed to have finite dimensions limited by infinitely conductive boundary surfaces. A theoretical and numerical analysis of marginal stability locates the regions of stability as a function of several parameters; i.e. plasma length, ion anisotropy ({tau}) and electron temperature (T{sub e}). A limiting plasma length is found, below which the plasma is stable regardless of its density. For the parameters of the injection experiment M.M.I.I. at Fontenay-aux-roses it is found that the type of instabilities studied here should not occur. (author) [French] L'etude est faite en choisissant une fonction de distribution des ions de la forme f{sub oi} = 1 / (2*{pi}*{alpha}{sub p}e{sub i}*{alpha}{sub p}a{sub i}) * {lambda}({nu}{sub p}e - {alpha}{sub p}e{sub i}) * e{sup -}(v{sub pa2}/{alpha}{sub pai2}) et en supposant une conductivite infinie sur les limites du plasma de dimensions finies. L'etude theorique et numerique de la stabilite marginale determine les domaines de stabilite qui sont etudies en fonction de plusieurs parametres: longueur du plasma, anisotropie des ions ({tau}), temperature electronique (T{sub e}). Il apparait une longueur limite du plasma au-dessous de laquelle le plasma est stable, independemment de la densite. L'application faite avec les valeurs des parametres de l'experience d'injection M.M.I.I, a Fontenay-aux-Roses permet de conclure a la non existence dans cet appareil du type d'instabilite etudie ici. (auteur)

  14. The dynamic behaviour of heat exchangers; Etude du comportement dynamique des echangeurs de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Fonteray, J; Rozenholc, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    In order to study the dynamics of nuclear power plants, one needs mathematical models made up of ordinary differential equations. This report deals with models for heat exchangers. These models allow exact evaluations of the temperatures for any steady state. The deformation of the temperature maps during transients is taken into account. To do this, average temperatures are evaluated keeping In mind, on one hand the partial differential equations, on the other hand, the physical phenomenons which are involved. Seven ordinary differential equations at most, are necessary for one heat exchanger. Theses models were compared with mathematically exact ones and also with experimental results, that EDF was able to measure on EDF-1 heat exchangers. The results appear to be correct. (authors) [French] Les etudes de dynamique sur les centrales nucleaires exigent l'elaboration de modeles apparaissant sous forme d'equations differentlelles ordinaires. Ce rapport est consacre a la recherche de modeles d'echangeurs. Dans ces modeles les temperatures sont calculees exactement pour n'importe quel regime permanent. Pour tenir compte de la deformation des distributions de temperature en regime transitoire, on evalue les temperatures moyennes dans l'echangeur en s'appuyant, d'une part, sur les equations aux derivees partielles et, d'autre part, sur une analyse des phenomenes physiques. Les modeles contiennent au plus sept equations differentielles ordinaires. Ces modeles ont ete compares aux modeles mathematiques exacts et aussi a des resultats experimentaux, obtenus par l'EDF, sur les echangeurs d'EDF-1. Les resultats paraissent satisfaisants. (auteurs)

  15. An approach to automated chromosome analysis; Etudes pour une methode d'automatisation des analyses chromosomiques

    Energy Technology Data Exchange (ETDEWEB)

    Le Go, Roland

    1972-05-03

    d'une automatisation des differentes etapes de l'analyse chromosomique. Il est divise en trois tomes dont la matiere est decrite ci-apres. Dans le tome 1 est decrite l'etude d'un selecteur automatique de metaphases. Cet appareil doit realiser au cours du scanning d'une preparation, un processus de decision aboutissant a rejeter toutes images ininteressantes et a conserver les images pertinentes (bonnes metaphases). Ce probleme a ete aborde au moyen d'une etude sur ordinateur par un programme de simulation. La realisation de ce programme a permis d'etablir des algorithmes de selection dont la replique pourra etre realisee dans des circuits logiques electroniques. Dans le tome 2 est traite le probleme de l'automatisation de l'etude morphologique des chromosomes presents dans une metaphase. Cette automatisation necessite le traitement des photographies de metaphases par un appareil convertisseur optique-numerique qui extrait l'information-image et la transcrit sous la forme d'un fichier numerique. Ce fichier comporte pour une image de metaphase, environ 200 000 valeurs de gris, codees selon une echelle a 16, 32 ou 64 ni veaux. Ce fichier numerique est traite par un programme de reconnaissance de forme, qui isole les chromosomes et en recherche les traits caracteristiques: sommets de bras et region centromerique, dans le but d'obtenir des mensurations equivalentes aux longueurs des quatre bras. Le tome 3 etudie un programme d'etablissement automatique du caryotype humain, par appariement optimise des chromosomes. Les donnees proviennent de la numerisation directe des longueurs de bras, effectuee au moyen d'un lecteur digital BENSON. Le programme etablit une liste des appariements, un document graphique imprime representant les paires constituees, dans l'espace: longueur - index centromerique; enfin un document graphique obtenu sur traceur BENSON dans lequel l'auteur donne une representation personnelle des chromosomes, sous forme de croix a bras orthogonaux, dont chaque

  16. Pegase: safety studies - experimental study of burn-out risks in transient operation; Pegase: etude de surete - etude experimentale des risques de burn out en regime transitoire

    Energy Technology Data Exchange (ETDEWEB)

    Vernier, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    canal chaud se met en etat de calefaction au bout de 0.1 s et que sa temperature atteint 500 C en 0.8 s. Les regimes hydrodynamiques rencontres dans les canaux apres l'accident sont des regimes d'expulsion periodiques de periodes courtes 0.2 a 0.5 s, caracteristiques de l'ebullition a basse pression. L'etude en regime permanent de la redistribution de debit dans un by-pass a donne des flux PHI{sub R} de redistribution de 190 W/cm{sup 2} pour une vitesse de 4.5 m/s a 50 C et de 175 W/cm{sup 2} a 60 C. Ces valeurs sont a majorer de 25 pour cent pour une vitesse de 6 m/s. On a montre la distinction a faire entre flux critique PHI{sub C} en regime periodique d'expulsion et flux de redistribution PHI{sub R} en regime permanent. (auteur)

  17. Study relating to the physico-chemical behaviour of heavy water in nuclear reactors; Etudes relatives au comportement physico-chimique de l'eau lourde dans les reacteurs nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Chenouard, J; Dirian, G; Roth, E; Vignet, P; Platzer, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1959-07-01

    Chemical and isotope pollution, and radiolytic decomposition are the two most important ways in which heavy water becomes degraded in nuclear reactors. Chemical pollution has led to the creation of ion exchange purification loops specially designed for reactors: the report contains a description in detail of the application of this purification method in CEA research reactors, including the analysis required, results obtained, and their interpretation. The intelligence obtained on radiolytic decomposition with the same facilities is also discussed, as well as the recombination apparatus and control equipment utilized. Finally, investigation to date in the CEA on recombination circuits for power reactors is also discussed. (author) [French] Parmi les degradations subies par l'eau lourde dans les reacteurs nucleaires, les deux plus importantes sont la pollution chimique et isotopique et la decomposition radiolytique. La pollution chimique a conduit a mettre au point pour le cas particulier des reacteurs, des circuits d'epuration par echange d'ions. On decrit ici en detail la mise en oeuvre de cette methode dans les reacteurs de recherche du CEA; les controles qu'elle necessite, les resultats obtenus et leur interpretation. En ce qui concerne la dissociation radiolytique de l'eau, les renseignements obtenus sur ces memes reacteurs sont communiques, ainsi que les details des dispositifs de recombinaison et des moyens de controle. Enfin, on fait le point des etudes poursuivies au CEA sur ces memes problemes de recombinaison dans le cas des reacteurs de puissance. (auteur)

  18. Study of the fluctuations of the partial and total radiative widths by neutron capture resonance method; Etude des fluctuations des largeurs radiatives partielles et totales par la capture des neutrons de resonance

    Energy Technology Data Exchange (ETDEWEB)

    Huynh, V D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    Radiative capture experiments by neutron time-of-flight methods have been made for following studies: distribution of partial radiative widths, effects of correlation between different radiative transitions, fluctuations of total radiative widths {gamma}{sub {gamma}} from resonance to resonance, variation of {gamma}{sub {gamma}} with number of mass and the search for the existence of potential capture. Also, some other experiments with the use of neutron capture gamma-rays spectra have been investigated. (author) [French] Par la capture des neutrons de resonance dont les energies sont selectionnees a l'aide de la technique du temps de vol, differents types d'experiences ont ete realisees concernant les etudes des distributions des largeurs radiatives partielles, des effets de correlation entre differentes voies de desexcitation, de la fluctuation des largeurs radiatives totales {gamma}{sub {gamma}} de resonance a resonance, de la variation de la quantite {gamma}{sub {gamma}} en fonction du nombre de masse et de la mise en evidence de l'existence du processus de capture potentielle. Quelques autres applications de l'emploi du spectre de rayons gamma ont egalement ete presentees. (auteur)

  19. Study relating to the physico-chemical behaviour of heavy water in nuclear reactors; Etudes relatives au comportement physico-chimique de l'eau lourde dans les reacteurs nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Chenouard, J.; Dirian, G.; Roth, E.; Vignet, P.; Platzer, R. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1959-07-01

    Chemical and isotope pollution, and radiolytic decomposition are the two most important ways in which heavy water becomes degraded in nuclear reactors. Chemical pollution has led to the creation of ion exchange purification loops specially designed for reactors: the report contains a description in detail of the application of this purification method in CEA research reactors, including the analysis required, results obtained, and their interpretation. The intelligence obtained on radiolytic decomposition with the same facilities is also discussed, as well as the recombination apparatus and control equipment utilized. Finally, investigation to date in the CEA on recombination circuits for power reactors is also discussed. (author) [French] Parmi les degradations subies par l'eau lourde dans les reacteurs nucleaires, les deux plus importantes sont la pollution chimique et isotopique et la decomposition radiolytique. La pollution chimique a conduit a mettre au point pour le cas particulier des reacteurs, des circuits d'epuration par echange d'ions. On decrit ici en detail la mise en oeuvre de cette methode dans les reacteurs de recherche du CEA; les controles qu'elle necessite, les resultats obtenus et leur interpretation. En ce qui concerne la dissociation radiolytique de l'eau, les renseignements obtenus sur ces memes reacteurs sont communiques, ainsi que les details des dispositifs de recombinaison et des moyens de controle. Enfin, on fait le point des etudes poursuivies au CEA sur ces memes problemes de recombinaison dans le cas des reacteurs de puissance. (auteur)

  20. Study of the fluctuations of the partial and total radiative widths by neutron capture resonance method; Etude des fluctuations des largeurs radiatives partielles et totales par la capture des neutrons de resonance

    Energy Technology Data Exchange (ETDEWEB)

    Huynh, V.D. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    Radiative capture experiments by neutron time-of-flight methods have been made for following studies: distribution of partial radiative widths, effects of correlation between different radiative transitions, fluctuations of total radiative widths {gamma}{sub {gamma}} from resonance to resonance, variation of {gamma}{sub {gamma}} with number of mass and the search for the existence of potential capture. Also, some other experiments with the use of neutron capture gamma-rays spectra have been investigated. (author) [French] Par la capture des neutrons de resonance dont les energies sont selectionnees a l'aide de la technique du temps de vol, differents types d'experiences ont ete realisees concernant les etudes des distributions des largeurs radiatives partielles, des effets de correlation entre differentes voies de desexcitation, de la fluctuation des largeurs radiatives totales {gamma}{sub {gamma}} de resonance a resonance, de la variation de la quantite {gamma}{sub {gamma}} en fonction du nombre de masse et de la mise en evidence de l'existence du processus de capture potentielle. Quelques autres applications de l'emploi du spectre de rayons gamma ont egalement ete presentees. (auteur)

  1. The study of neutron transport by oscillation method; Etude du transport des neutrons par la methode de modulation

    Energy Technology Data Exchange (ETDEWEB)

    Raievski, V

    1959-07-01

    The oscillation method is of very general use for studying the behavior of thermal neutrons in media. The main experiments are described and a general theory of them is given. This theory, which is presented in the first part, is established using the two-group approximation which has proved its efficiency in the case of thermal neutron piles. The validity of the two-group approximation is recalled. This allows definition of the meaning of the parameters used in the theory and which are measured in these experiments. The experiments carried out by this method are described, especially those performed at the Centre d'Etudes Nucleaires de Saclay where the method has been extensively used. These experiments are interpreted by means of the general theory given previously. In this way, the identity of parameters measured by this method and those given by the theory is proved. This is particularly conclusive is the case of the mean life of neutrons in a pile. (author) [French] La methode de modulation est un procede tres general d'etude des proprietes neutroniques des milieux contenant des neutrons thermiques. Le present rapport a pour but de decrire les principales de ces experiences et d'en donner une theorie generale. Cette theorie, exposee dans la premiere partie, est etablie dons le cadre de l'approximation a deux groupes de vitesse qui a prouve son efficacite dons le cas des piles a neutrons thermiques. Le domaine de validite de l'approximation a deux groupes est rappele au debut, ce qui permet de definir avec precision la signification des parametres qui entrent dons la theorie et qui font l'objet de ces mesures. La deuxieme partie decrit les experiences realisees, en particulier celles effectuees au Centre d'Etudes Nucleaires de Saclay ou la methode a ete considerablement developpee. Ces experiences sont interpretees dans le cadre de la theorie generale exposee precedemment. On prouve ainsi l'identite des parametres mesures par cette methode et de ceux figurant

  2. Randomized control trial for the assessment of the anti-albuminuric effects of topiroxostat in hyperuricemic patients with diabetic nephropathy (the ETUDE study).

    Science.gov (United States)

    Kato, Sawako; Ando, Masahiko; Mizukoshi, Toshihiro; Nagata, Takanobu; Katsuno, Takayuki; Kosugi, Tomoki; Tsuboi, Naotake; Maruyama, Shoichi

    2016-05-01

    Proteinuria is an established risk factor for diabetic nephropathy. Recent studies indicate that some xanthine oxidase inhibitors have a renoprotective effect. The aim of this study was to assess whether topiroxostat reduces albuminuria in hyperuricemic patients with diabetic nephropathy and overt proteinuria. The ETUDE study is an ongoing 24-week, multicenter, open-label, randomized (1:1), parallel group study involving hyperuricemic patients with diabetic nephropathy (estimated glomerular filtration rate [eGFR] ≥ 20 mL/min/1.73 m(2)) and overt proteinuria (0.3 ≤ urine protein to creatinine ratio (UPCR) ETUDE trial is the first randomized controlled study of topiroxostat in hyperuricemic patients with diabetic nephropathy and overt proteinuria. We will clarify the pleiotropic function of topiroxostat including an anti-albumiuric effect as well as its effects on safely decreasing serum uric acid levels.

  3. Study of the solubility of plutonyl nitrate with a view to its extraction by a solvent; Etude de la solubilite du nitrate de plutonyle en vue de son extraction par solvant

    Energy Technology Data Exchange (ETDEWEB)

    Vergnaud, G. [Commissariat a l' Energie Atomique, Fontenay aux Roses (France). Centre d' Etudes Nucleaires

    1965-09-01

    The research covers the determination of the partition coefficient of plutonyl nitrate and their application to the industrial treatment of plutonium. The solvent used is a tri-n-butyl phosphate solution diluted to 30 per cent in dodecane. The parameters which have been studied and which can affect the extraction of the plutonyl nitrate are: the plutonyl nitrate concentration; the nitric acid concentration; the uranyl nitrate concentration; the tetravalent plutonium nitrate concentration. The industrial application has been studied using a battery of mixer-separators. The operational conditions are defined in the case of a conventional plutonium separation plant. The results obtained, for a higher plutonyl nitrate concentration than that actually planned, are satisfactory and encouraging as far as the operation is concerned. Only the presence of polymerized tetravalent plutonium can adversely affect the satisfactory extraction of the plutonium. (author) [French] L'etude porte sur les coefficients de partage du nitrate de plutonyle et leur application a l'elaboration industrielle du plutonium. Le solvant utilise est une solution de phosphate de tri-n-butyle, dilue a 30 pour cent dans le dodecane. Les parametres etudies et pouvant influencer l'extraction du nitrate de plutonyle, par ce solvant, sont: concentration du nitrate de plutonyle; concentration de l'acide nitrique; concentration du nitrate d'uranyle; concentration au nitrate de plutonium tetravalent. L'application industrielle est etudiee au moyen d'une batterie de melangeurs-decanteurs. Les conditions operatoires sont definies d'apres un schema classique d'usine de separation de plutonium. Les resultats obtenus, pour une concentration du nitrate de plutonyle superieure a celle reellement prevue, sont satisfaisants et encourageants pour l'exploitation. Seule, la presence de plutonium tetraralent polymerise, peut nuire a une bonne extraction du plutonium

  4. Study of the solubility of plutonyl nitrate with a view to its extraction by a solvent; Etude de la solubilite du nitrate de plutonyle en vue de son extraction par solvant

    Energy Technology Data Exchange (ETDEWEB)

    Vergnaud, G [Commissariat a l' Energie Atomique, Fontenay aux Roses (France). Centre d' Etudes Nucleaires

    1965-09-01

    The research covers the determination of the partition coefficient of plutonyl nitrate and their application to the industrial treatment of plutonium. The solvent used is a tri-n-butyl phosphate solution diluted to 30 per cent in dodecane. The parameters which have been studied and which can affect the extraction of the plutonyl nitrate are: the plutonyl nitrate concentration; the nitric acid concentration; the uranyl nitrate concentration; the tetravalent plutonium nitrate concentration. The industrial application has been studied using a battery of mixer-separators. The operational conditions are defined in the case of a conventional plutonium separation plant. The results obtained, for a higher plutonyl nitrate concentration than that actually planned, are satisfactory and encouraging as far as the operation is concerned. Only the presence of polymerized tetravalent plutonium can adversely affect the satisfactory extraction of the plutonium. (author) [French] L'etude porte sur les coefficients de partage du nitrate de plutonyle et leur application a l'elaboration industrielle du plutonium. Le solvant utilise est une solution de phosphate de tri-n-butyle, dilue a 30 pour cent dans le dodecane. Les parametres etudies et pouvant influencer l'extraction du nitrate de plutonyle, par ce solvant, sont: concentration du nitrate de plutonyle; concentration de l'acide nitrique; concentration du nitrate d'uranyle; concentration au nitrate de plutonium tetravalent. L'application industrielle est etudiee au moyen d'une batterie de melangeurs-decanteurs. Les conditions operatoires sont definies d'apres un schema classique d'usine de separation de plutonium. Les resultats obtenus, pour une concentration du nitrate de plutonyle superieure a celle reellement prevue, sont satisfaisants et encourageants pour l'exploitation. Seule, la presence de plutonium tetraralent polymerise, peut nuire a une bonne extraction du plutonium. (auteur)

  5. Theoretical and experimental study of heat transfers and pressure drops along surfaces fitted with herring-bone fins: correlation between geometric and aero thermal parameters; Etudes theorique et experimentale du transfert de chaleur et des pertes de charge de surfaces munies d'ailettes disposees en chevron - correlation entre parametres geometriques et aerothermiques

    Energy Technology Data Exchange (ETDEWEB)

    Pelce, J; Malherbe, J; Pierre, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    Principal results are given of experimental research which has been carried out on the flow of a fluid along a surface fitted with herringbone fins. Aero-thermal tests have been effected on a large number of these surfaces whose geometrical parameters have been made to vary systematically. In particular, work on a large scale model has made it possible to analyse the mechanisms of heat transfer and of pressure drops. On this basis a theoretical study has led to the establishment of a correlation between the geometric configuration and the aero-thermal performances of these surfaces. Experimental results are in good agreement with the theoretical relationships. An expression has thus been derived applicable to this type of herring-boned surface in a wide zone. (authors) [French] L'ecoulement d'un fluide au voisinage d'une surface munie d'ailettes disposees en chevron a fait l'objet de recherches experimentales dont on a rappele les principaux resultats. Des essais aerothermiques ont ete effectues sur un grand nombre de ces surfaces dont a fait varier les parametres geometriques de facon systematique. En particulier, des etudes sur une maquette a grande echelle ont permis d'analyser les mecanismes de transfert de chaleur et de perte de charge. Sur ces bases, une etude theorique a conduit a des correlations entre la geometrie et les performances aerothermiques de ces surfaces. Les resultats experimentaux sont en bon accord avec les relations theoriques. On possede ainsi une formulation pour ce type de surface ailettee valable dans un domaine etendu. (auteurs)

  6. Theoretical and experimental study of a calorimetric technique for measuring energy deposition in materials caused by complex pile irradiation; Etude theorique et experimentale d'une technique calorimetrique de mesure des depots d'energie dans les materiaux dus au rayonnement complexe de pile

    Energy Technology Data Exchange (ETDEWEB)

    Mas, P; Sciers, P; Droulers, Y [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires, 38 - Grenoble (France)

    1962-07-01

    Calorimetric methods may be used to measure gamma fluxes greater than 10{sup 6} r/h near the cores of swimming pool reactors. The theory, design, and properties of isothermal calorimeters are discussed, and experimental results obtained with two types are presented. Measurement of energy deposition in materials and the long term integration of energy depositions are other uses of these devices. Results of measurements on heat deposition in steel and water are given. Fluxes were also measured. (authors) [French] Une premiere partie traite de la theorie des calorimetres isothermes mis en oeuvre au C.K.N. Grenoble. La puissance deposee dans le calorimetre par les flux de rayonnement echauffe celui-ci. L'echauffement est mesure a l'aide d'un thermocouple. On montre que l'on a ainsi une mesure absolue de cette puissance. Une deuxieme partie traite de l'etude experimentale de: deux types d'appareils utilises: leur construction, les resultats experimentaux, leurs utilisations. Trois de celles-ci sont particulierement interessantes: - la mesure des hauts flux gamma, - la mesure du depot d'energie dans les materiaux, - l'integration pendant une longue duree des depots d'energie (un modele de calorimetre a fonctionne a ce jour 2 500 heures et a integre 9 x 10 puissance 10 rads gamma et 6 x 10 puissance 18 neutrons rapides). La troisieme partie est consacree a l'etude des qualites de l'appareil: robustesse, fidelite, precision, sensibilite, gamme de mesure. Enfin dans la derniere partie sont decrites deux applications de la methode calorimetrique a la mesure du depot d'energie dans un acier special et dans l'eau. (auteurs)

  7. The purification by ion exchange resins of the heavy water la the reactors EL1 and EL2. B - study of the general properties of the resins used; Purification par resines echangeuses d'ions de l'eau lourde de reacteurs EL1 et EL2. B - etude des proprietes generales des resines utilisees

    Energy Technology Data Exchange (ETDEWEB)

    Fourre,; Platzer, [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    Within the programme of the pile heavy water purification project, organized by the stable Isotopes Section, we have carried out a certain number of tests on ion exchange resins. The problem posed by the stable Isotopes Section was to determine the conditions of utilisation of ion exchange resins, knowing that they would be employed in a system branching off the heavy water circuit in the piles. These investigations were carried out in close collaboration with the stable Isotopes Section, and were guided chiefly by the extremely short delay permitted between the laboratory study and its application to the piles. The tests are divided into two groups: 1- General properties of the resins. 2- Utilisation of the resins, particularly in an apparatus similar to those mounted on the piles but of smaller dimensions. (author) [French] Dans le cadre du projet d'epuration de l'eau lourde des piles, traite par la Section des Isotopes stables, nous avons fait un certain nombre d'essais sur les resines echangeuses d'ions. Le probleme pose par la Section des Isotopes stables etait de determiner les conditions d'utilisation des resines echangeuses d'ions sachant qu'elles devraient etre employees dans un appareil place en derivation sur le circuit d'eau lourde des piles. L'ensemble de l'etude a ete mene en collaboration etroite avec la Section des Isotopes stables et a ete guide principalement par le delai extremement court dans lequel l'etude de laboratoire devait etre appliquee aux piles. Les essais se divisent en deux groupes: 1- Proprietes generales des resines. 2- Utilisation des resines, en particulier dans un appareil analogue a ceux montes sur les piles, mais de dimensions reduites. (auteur)

  8. Etude de la transition ferroelectrique-ferroelastique du KD2PO4 forme du front de phase en fonction du gradient thermique

    OpenAIRE

    Kvítek, Zdeněk

    2010-01-01

    Etude de la transition ferroelectrique-ferroelastique du KD2PO4 forme du front de phase en fonction du gradient thermique The thesis explores complex process of first order transition of KD2PO4 crystal from tetragonal phase to ferroelectric - ferroelastic orthorhombic phase and back at temperature 209 K. The experimental set up of nitrogeneous cryostat allowes temperature and temperature gradient variations during simultaneous three axes optical sample observations, dielectric measurements. T...

  9. Point-of-care ultrasonography adoption in Canada: using diffusion theory and the Evaluation Tool for Ultrasound skills Development and Education (ETUDE).

    Science.gov (United States)

    Woo, Michael Y; Frank, Jason R; Lee, A Curtis

    2014-09-01

    Point-of-care ultrasonography (PoCUS) first appeared in the 1980s in North America, but the extent of the diffusion of its adoption is unknown. We characterized early PoCUS adoption by emergency physicians in Canada and its barriers to use using Rogers' diffusion of innovations theory. We developed a questionnaire based on a pilot study and literature review to assess past, current, and potential use of PoCUS and potential barriers to adoption. A Dillman technique for electronic surveys was used for dissemination. Using Rogers' diffusion of innovations theory, we developed and validated the Evaluation Tool for Ultrasound skills Development and Education (ETUDE). ETUDE scores allowed categorization of respondents into innovators, early adopters, majority, and nonadopters. Descriptive statistics, correlations, and χ² statistics were used to analyze the data. The 296 respondents (36.4% of 814 surveyed) had a median age of 40 and were 72.5% male. Adoption scores using ETUDE revealed nonadopters (18.8%), majority (28.7%), early adopters (34.5%), and innovators (18.0%). Respondents endorsed "always" using PoCUS currently and in the future for focused assessment with sonography in trauma (FAST) (current 41.8%/future 88.4%), first trimester pregnancy (current 23.3%/future 73.7%), suspected abdominal aortic aneurysm (current 32.7%/future 92.6%), basic cardiac indications (current 30.7%/future 87.5%), and central venous catheterization (current 17.0%/future 80.3%). Several barriers to PoCUS were identified for part-time emergency physicians and those working in inner-city/urban/suburban settings. This is the first study to determine the state of adoption and barriers to the introduction of PoCUS in Canadian emergency medicine practice. The novel validated ETUDE instrument should be used to evaluate the uptake of PoCUS over time.

  10. Theoretical study, and construction, of a spherical electrostatic beta spectrometer; Etude theorique et realisation d'un spectrometre beta electrostatique spherique

    Energy Technology Data Exchange (ETDEWEB)

    Moret, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-03-15

    After a literature survey showing the importance of an electrostatic spectrometer with spherical electrodes for studying disintegration processes, the theoretical characteristics of such an apparatus are derived (determination of the trajectory equations calculation of the transmission and of the resolving power the case of a point source and of an extended source). The apparatus built as a result of these calculations is described. The electrostatic field distribution outside the electrodes is derived. As well as giving electron spectra ({beta} disintegration and conversion electrons) the apparatus make s it possible to study e-{gamma}, e-{beta}, e-e-{gamma} and e-e-{beta} coincidences. In the last part are given experimental characteristics and the results of the first measurements made on conversion electron spectra ({sup 161}Tb, {sup 151}Pm, {sup 155}Eu) and on coincidences ({sup 170}Tm) using this spectrometer. (author) [French] Apres une etude bibliographique montrant l'interet que presente un spectrometre electrostatique a electrodes spheriques pour l'etude des schemas de desintegration, l'auteur etablit les caracteristiques theoriques d'un tel appareil (determination de l'equation des trajectoires calcul de la transmission et du pouvoir de resolution cas d'une source ponctuelle et d'une source etendue). On decrit l'appareil realise d'apres ces calculs. On etablit la repartition du champ electrostatique a l'exterieur des electrodes. Outre le trace des spectres d'electrons (desintegration {beta} et electrons de conversion), l'appareil permet l'etude de coincidences e-{gamma}, e-{beta}, e-e-{gamma} and e-e-{beta}. Dans la derniere partie, sont donnees les caracteristiques experimentales et les premieres etudes de spectres d'electrons de conversion ({sup 161}Tb, {sup 151}Pm, {sup 155}Eu) et de coincidences ({sup 170}Tm) faites a l'aide de ce spectrometre. (auteur)

  11. Experimental study of contamination by inhalation of radioactive iodine aerosols. Biological balance; Etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif bilan biologique

    Energy Technology Data Exchange (ETDEWEB)

    Marble, G [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Several articles have been published concerning research into contamination produced by inhalation of radioactive iodine aerosols in monkeys. Results dealing with the biological balance of this contamination are presented and discussed in this report. (author) [French] L'etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif effectuee chez le singe a fait l'objet de plusieurs publications. Les resultats concernant le bilan biologique de cette contamination sont presentes et discutes dans ce rapport. (auteur)

  12. Studies of iron carbon alloys; Contribution a l'etude des alliages dilues de carbone dans le fer {alpha}

    Energy Technology Data Exchange (ETDEWEB)

    Anagnostopoulos, T [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1971-07-01

    Precipitation of carbon in {alpha} iron during a thermal treatment was followed using the magnetic after effect. A study was made of the influence of different parameters such as quenching speed, annealing rate, carbon concentration with or without impurity, irradiation effects. A transient sur-saturation occurs during dissolution of carbon in iron at 500 C. (author) [French] La precipitation du carbone dans le fer au cours d'un traitement thermique a ete suivie au moyen du trainage magnetique. L'etude de differents parametres tels que: vitesse de trempe, mode de recuit, concentration en carbone, presence d'impuretes, effet d'une irradiation, ont ete menes a bien. Un phenomene de sursaturation transitoire au cours de la remise en solution a 500 C a ete mis en evidence. (auteur)

  13. Dosimeter calibration facilities and methods at the Radiation Measurement Laboratory of the Centre d'etudes nucleaires, Grenoble

    International Nuclear Information System (INIS)

    Choudens, H. de; Herbaut, Y.; Haddad, A.; Giroux, J.; Rouillon, J.; CEA Centre d'Etudes Nucleaires de Grenoble, 38

    1975-01-01

    At the Centre d'etudes nucleaires, Grenoble, the Radiation Measurement Laboratory, which forms part of the Environmental Protection and Research Department, serves the entire Centre for purposes of dosimetry and the calibration of dose meters. The needs of radiation protection are such that one must have facilities for checking periodically the calibration of radiation-monitoring instruments and developing special dosimetry techniques. It was thought a good idea to arrange for the dosimetry and radiation protection team to assist other groups working at the Centre - in particular, the staff of the biology and radiobiology laboratories - and also bodies outside the framework of the French Commissariat a l'energie atomique. Thus, technical collaboration has been established with, for example, Grenoble's Centre hospitalier universitaire (university clinic), which makes use of the facilities and skills available at the Radiation Measurement Laboratory for solving special dosimetry problems. With the Laboratory's facilities it is possible to calibrate dose meters for gamma, beta and neutron measurements

  14. Some techniques for studying actomyosin by electron microscopy; Quelques techniques d'etude de l'actomyosine par microscopie electronique

    Energy Technology Data Exchange (ETDEWEB)

    Herzberg, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires. Departement de Biologie

    1967-07-01

    A method has been developed for shadowing using a platinum-carbon alloy; it has been applied to the study of the interaction of actomyosin with its substrate ATP. The results obtained seem to favour the hypothesis of a dissociation of the actomyosin into its two components: actin and myosin. Pictures have been obtained showing particles resembling non-polymerized myosin but no rigorous proof of this exists. (author) [French] Une methode d'ombrage par un alliage de platine et carbone a ete mise au point et appliquee a l'etude de l'interaction de l'actomyosine et de son substrat l'ATP. Les resultats obtenus semblent pencher en faveur de la these d'une dissociation de l'actomyosine en ses deux constituants: l'actine et la myosine. Des images ont ete obtenues montrant des particules dont l'identite avec la myosine non polymerisee reste a demontrer plus rigoureusement. (auteur)

  15. Cell for studying electron-adsorbed gas interactions; Cellule d'etudes des interactions electron-gaz adsorbe

    Energy Technology Data Exchange (ETDEWEB)

    Golowacz, H; Degras, D A [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires, Deptartement de Physique des Plasmas et de la Fusion Controlee, Service de Physique Appliquee, Service de Physique des Interractions Electroniques, Section d' Etude des Interactions Gaz-Solides

    1967-07-01

    The geometry and the technology of a cell used for investigations on electron-adsorbed gas interactions are described. The resonance frequencies of the surface ions which are created by the electron impact on the adsorbed gas are predicted by simplified calculations. The experimental data relative to carbon monoxide and neon are in good agreement with these predictions. (authors) [French] Les caracteristiques geometriques et technologiques generales d'une cellule d'etude des interactions entre un faisceau d'electrons et un gaz adsorbe sont donnees. Un calcul simplifie permet de prevoir les frequences de resonance des ions de surface crees par l'impact des electrons sur le gaz adsorbe. Les donnees experimentales sur l'oxyde de carbone et le neon confirment les previsions du calcul. (auteurs)

  16. The development of a very high stability electrostatic generator (1962); Etude et realisation d'un generateur electrostatique a tres haute stabilite (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Jonckheere, R E.L. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1962-07-01

    This thesis deals with the study of an electrostatic high voltage generator having a voltage stability of the order of 10{sup -6} per minute. This equipment should be very useful in electron microscopy. The electrostatic generator is studied as a control system element: transfer function, parasitic signals and noise are determined and a mathematical model is proposed. A theoretical study of the open loop transfer function, stability, transient response, voltage stabilization of five different control systems shows which one should be able to fulfill the requirements There follows a detailed study of drift, a description of the actual system and performance data. (author) [French] Cette etude concerne un generateur electrostatique capable de fournir une tres haute tension continue dont la stabilite relative est de l'ordre de 10{sup -6} pendant une minute. Une telle performance rend cet appareillage tres utile en microscopie electronique. La generatrice electrostatique est etudiee en tant qu'element d'un systeme asservi: on determine successivement la fonction de transfert, les perturbations, le bruit de fond et le modele mathematique. L'etude de cinq differents circuits de regulation en ce qui concerne leur fonction de transfert, stabilite, reponse en regime transitoire, attenuation des perturbations, permettra de choisir le systeme qui semble le mieux repondre aux exigences. Viennent ensuite une etude detaillee de la derive, la description de la realisation pratique et les resultats de mesure. (auteur)

  17. Contribution to the study of the stability of water-cooled reactors; Contribution a l'etude de la stabilite des reacteurs refroidis par de l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Coudert, C [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-06-01

    This work is devoted to the study of the stability of reactors cooled by water subjected only to natural convection. It is made up of two parts, a theoretical study and experimental work, each of these parts being devoted to a consideration of linear and non-linear conditions: - calculation of the transfer function of the reactor using neutronic and hydrodynamic linear equations with the determination of the instability threshold; - demonstration of the existence of the limiting oscillation cycle in the case of a linear feedback using MALKIN'S method; - measurement and interpretation of the reactor's transfer functions and of the hydrodynamic transfer functions; and - analysis of the noise due to boiling. (author) [French] Dans ce travail on etudie la stabilite des piles refroidies par de l'eau circulant en convection naturelle. Cette etude se divise en deux parties: un travail theorique et un travail experimental, chacune de ces parties comportant une etude lineaire et une etude non-lineaire: - calcul de la fonction de transfert du reacteur a partir des equations lineaires de la neutronique et de l'hydrodynamique avec determination du seuil d'instabilite; - demonstration de l'existence du cycle limite des oscillations dans le cas d'une retroaction lineaire en utilisant la methode de MALKIN; - mesure et interpretation de la fonction de transfert du reacteur et des fonctions de transfert hydrodynamiques; et - analyse du bruit d'ebullition. (auteur)

  18. The development of a very high stability electrostatic generator (1962); Etude et realisation d'un generateur electrostatique a tres haute stabilite (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Jonckheere, R.E.L. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1962-07-01

    This thesis deals with the study of an electrostatic high voltage generator having a voltage stability of the order of 10{sup -6} per minute. This equipment should be very useful in electron microscopy. The electrostatic generator is studied as a control system element: transfer function, parasitic signals and noise are determined and a mathematical model is proposed. A theoretical study of the open loop transfer function, stability, transient response, voltage stabilization of five different control systems shows which one should be able to fulfill the requirements There follows a detailed study of drift, a description of the actual system and performance data. (author) [French] Cette etude concerne un generateur electrostatique capable de fournir une tres haute tension continue dont la stabilite relative est de l'ordre de 10{sup -6} pendant une minute. Une telle performance rend cet appareillage tres utile en microscopie electronique. La generatrice electrostatique est etudiee en tant qu'element d'un systeme asservi: on determine successivement la fonction de transfert, les perturbations, le bruit de fond et le modele mathematique. L'etude de cinq differents circuits de regulation en ce qui concerne leur fonction de transfert, stabilite, reponse en regime transitoire, attenuation des perturbations, permettra de choisir le systeme qui semble le mieux repondre aux exigences. Viennent ensuite une etude detaillee de la derive, la description de la realisation pratique et les resultats de mesure. (auteur)

  19. Study of electron groupings in the Saclay linear accelerator; Etude du groupement des electrons dans l'accelerateur lineaire de Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Bergere, R; Veyssiere, A; Beil, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The classical theory of the linear accelerator buncher does not fit the experimental measurements of the shape of the bunch of electrons performed at Saclay by the method of the energy spectrum. If the spurious effect of the mode converter at the input of the linac is taken into account the theory can fit the experimental results and also explain the variations of the phase of the bunch on the accelerating sine wave. (authors) [French] Une etude classique du groupeur en tete de l'Accelerateur Lineaire de Saclav conduit a des resultats incompatibles avec les resultats experimentaux obtenus sur le groupement des electrons par l'etude du spectre des frequences rayonnees par le faisceau d'electrons ou par l'etude des spectres en energie. Par contre si l'effet parasite du convertisseur de mode a l'entree de l'accelerateur est pris en consideration les resultats theoriques coincident bien avec les resultats experimentaux et permettent en outre d'expliquer les variations du calage en phase des paquets elementaires d'electrons. (auteurs)

  20. Study of thermocouples for control of high temperatures; Etude de thermocouples pour le reperage des hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Villamayor, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Faculte des Sciences de l' Universite de Lyon - 69 (France)

    1967-07-01

    Previous works have shown that the tungsten-rhenium alloys thermocouples were a good instrument for control of high temperatures. From its, the author has studied the W/W 26 per cent and W 5 per cent Re/W 26 per cent Re french manufactured thermocouples and intended for control of temperatures in nuclear reactors until 2300 deg. C. In 'out-pile' study he determines the general characteristics of these thermocouples: average calibration curves, thermal shocks influence, response times, and alloys allowing the cold source compensation. The evolution of these thermocouples under thermal neutron flux has been determined by 'in-pile' study. The observations have led the author to propose a new type of thermocouples settled of molybdenum-columbium alloys. (author) [French] Des travaux anterieurs ont montre que les thermocouples des alliages tungstene-rhenium etaient susceptibles de reperer avec precision des hautes temperatures. A partir de la, l'auteur a etudie las thermocouples W/W 26 pour cent Re et W 5 pour cent Re/W 26 pour cent Re de fabrication francaise et destines au controle des temperatures dans les reacteurs nucleaires, jusqu'a 2300 deg. C Dans l'etude 'hors-pile' il a determine les caracteristiques generales de ces thermocouples: courbes d'etalonnage moyen, influence des chocs thermiques, temps de reponse, et alliages assurant la compensation de soudure froide. L'etude 'en-pile' a permis de rendre compte de l'evolution de ces thermocouples sous flux neutroniques. Les phenomenes observes ont conduit l'auteur a proposer un nouveau type de thermocouples constitues d'alliages molybdene-niobium. (auteur)

  1. Study of radio-active ions in the atmosphere; Etude des ions radioactifs de l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Renoux, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-01-01

    A comparative study is made of active, deposits of radon and thoron in suspension in the atmosphere by means of {alpha} radiation counting, using ZELENY tubes, scattering equipment, filter papers or membranes. It has been possible to show the existence of small and large ions which are negative and positive, as well as of neutral radio-active nuclei; their properties are studied. A theoretical interpretation of the results is presented. The average content of radon (using the Ra A concentration) and of Th B in the air has been determined. The radioactive equilibrium between radon and its daughter products in atmospheric air are examined. The techniques developed for active radon and thoron deposits are applied to the study of artificial radio-activity, the analyses being carried out by means of {gamma} spectrometry. (author) [French] On effectue une etude comparative entre les depots actifs du radon et du thoron en suspension dont l'atmosphere a l'aide de comptages de rayonnement {alpha}, en utilisant des tubes de ZELENY, une batterie de diffusion, des papiers filtres ou des membranes. On met ainsi en evidence la presence de petits et gros ions negatifs et positifs, ainsi que celle de noyaux neutres radioactifs, et on etudie leurs proprietes. Une Interpretation theorique des resultats obtenus est developpee. On determine la teneur moyenne de l'air en radon (a partir de la concentration en Ra A) et en Th B. L'equilibre radioactif entre le radon et ses descendants, dans l'air atmospherique, est examine. Les Techniques mises au point pour les depots actifs du radon et du thoron sont appliquees a l'etude de la radioactivite artificielle, les depouillements s'effectuant par spectrometrie {gamma}. (auteur)

  2. Theoretical study for a digital transfer function analyser; Etude theorique pour un transferometre digital

    Energy Technology Data Exchange (ETDEWEB)

    Freycenon, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    This study deals with the harmonic analysis of the instantaneous counting rate of a pulse train. This arises from using a fission chamber for reactivity to power transfer function measurements by oscillation methods in reactors. The systematical errors due to the sampling process are computed. The integration carried out when sampling the signal modifies the formulae of the Nyquist theorem on spectrum folding. The statistical errors due to the noise are analysed: it is shown that the bandwidth of the spectral window applied to the noise frequency spectrum is equal to the inverse of the time duration of the experiment. A dead time of 25 per cent of the sampling time does not increase appreciably the bandwidth. A new method is proposed afterwards yielding very approximate results of the Fourier analysis during the experiment. The systematical errors arising from the measuring process are determined, and it is shown that the bandwidth of the corresponding spectral window is still given by the inverse of the time duration of the experiment. (author) [French] Cette etude se rapporte a l'analyse harmonique de la valeur instantanee du taux de comptage d'une suite d'impulsions. On rencontre ce probleme dans l'utilisation de chambres a fission pour les mesures de fonction de transfert reactivite-puissance par la methode d'oscillation dans les piles. On calcule l'erreur systematique due au processus d'echantillonnage ou l'integration operee modifie les formules classiques de recouvrement du spectre. On analyse ensuite les erreurs statistiques dues au bruit de fond. On montre que la largeur de bande de la fenetre spectrale appliquee au spectre de puissance du bruit est donnee par l'inverse du temps de mesure. Un temps mort de 25 pour cent du temps de prelevement n'accroit pas sensiblement cette largeur de bande. On propose ensuite un procede simple qui permet d'obtenir, en cours d'experience, des resultats tres approches de l'analyse de Fourier. On determine les erreurs

  3. Study of the recrystallisation of irradiated uranium; Etude sur l'uranium irradie

    Energy Technology Data Exchange (ETDEWEB)

    Bloch, J; Mustelier, J P; Bussy, P; Blin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    1- Study of the recrystallisation of irradiated uranium. The recrystallisation of uranium irradiated to a burnup level of 220 MWj/t, at a temperature of the order of 350 deg. C, has been investigated. The observations were made chiefly by means of micrography an hardness measurements. If the irradiated metal is compared with a cold-drawn metal showing the same shearing of the twinned crystals, and therefore the same rate of plastic deformation, as the irradiated metal, it is noted that the restoring of the irradiated metal takes place at a considerably higher temperature than that of the cold-drawn metal. Pre-crystallisation is very much delayed. Only, a passage of the {alpha}-{beta} transformation point quickly wipes out irradiation effect. 2- Hardening of uranium by irradiation. Using hardness measurements we have studied more especially the effect of very weak irradiations on uranium (integrated flux < 10{sup 16} nvt). The hardness does not increase linearly with the flux, but a period of incubation is observed probably representing the time necessary for saturation of the dislocations. (author)Fren. [French] 1- Etude de la recristallisation de l'uranium irradie. On a etudie la recristallisation d'uranium irradie jusqu'a un taux de combustion de 220 MWj/t a une temperature de l'ordre de 350 deg. C. Les observations ont ete faites principalement a l'aide de la micrographie et de la durete. Si l'on compare le metal irradie avec un metal ecroui presentant le meme cisaillement des macles, donc le meme taux de deformation plastique que le metal irradie, on constate que la restauration du metal irradie se fait a une temperature notablement superieure a celle du metal ecroui. La recristallisation est tres retardee. Seul, un passage du point de transformation {alpha}-{beta} efface rapidement l'effet de l'irradiation. 2- Durcissement de l'uranium par irradiation. Nous avons, a l'aide de la durete, etudie plus particulierement l'effet de tres faibles irrtions sur l

  4. Recent Developments in the Chemical Thermodynamics of the Uranium Chalcogenides; Progres Accomplis Recemment dans la Thermodynamique Chimique des Chalcogenures d'Uranium; Poslednie dostizheniya v khimicheskoj termodinamike khal'kogenidov Urana; Recientes Progresos en la Termodinamica Quimica de los Calcogenidos de Uranio

    Energy Technology Data Exchange (ETDEWEB)

    Westrum, Jr., E. F. [University of Michigan, Ann Arbor, MI (United States)

    1966-02-15

    constantes relatives au nonaoxyde de tetrauranium a revele les aspects thermophysiques de la transition structurale de ' type {lambda} supposee progressive a 348 Degree-Sign K avec accroissement d'entropie associe de 1,84 cal/gfm Degree-Sign K, qui intervient dans le deplacement d'atomes d'oxygene interstitiels. Des mesures de la capacite calorifique et de la susceptibilite magnetique sur du bioxyde d'uranium fritte de Mallincktodt ont confirme que la transition antiferromagnetique-paramagnetique se produit a 30,4 Degree-Sign K avec 400 cal/gfm Degree-Sign K pour la capacite calorifique et non a 28,7 Degree-Sign K avec une saute de 9 cal/gfm Degree-Sign K comme il est dit dans d'autres ouvrages. On peut ainsi interpreter l'anomalie thermique trouvee dans l'heptaoxyde de triuianium beta. L'auteur a combine les capacites calorifiques, aux basses temperatures, d'echantillons bien caracterises de trioxyde d'uranium alpha, beta et gamma prepares par E. Cordfunke du Reactor Centrum Nederland avec les valeurs des capacites calorifiques, des enthalpies de formation et d'autres constantes thermodynamiques pour en tirer les valeurs de la stabilite relative pour ces importants materiaux nucleaires. Il a constate que le mohoseleniure et le biseleniure d'uranium presentaient tous deux des anomalies du type lambda associees a un desordre magnetique. Cette anomalie se produit a 13,1 Degree-Sign K dans le biseleniure, avec un accroissement d'entropie associe de 0,16 cal/gfm Degree-Sign K. L'anomalie se produisant a 160 Degree-Sign K dans le monoseleniure est accompagnee d'un accroissement d'entropie de 1,0 cal/gfm Degree-Sign K, qui peut etre compare a la valeur 1,17 trouvee pour le monosulfure au voisinage de 180 Degree-Sign K. Les deux anomalies thermiques dans les monochalcogenures resultent d'un desordre de l'etat ferromagnetique et s'opposent b l'anomalie antiferromagnetique constatee dans le mononitrure isostructural a 52 Degree-Sign K. Les nouvelles valeurs des constantes

  5. Comparative study of the creep behaviour of single crystals and polycrystals of alpha uranium; Etude comparee du comportement au fluage de l'uranium alpha mono et polycristallin

    Energy Technology Data Exchange (ETDEWEB)

    Andre, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-03-01

    In the first chapter, one describes the creep machine developed to study the deformation of uranium at high temperature in vacuum with a continuous recording. The second chapter presents the results concerning the polycrystals of uranium. The application of the DORN method gives an activation energy for creep of 42 {+-} 2 Kc, above 550 Celsius degrees, equal to the activation energy for self-diffusion. The study of the variation of the creep rate with the applied stress and the metallographic observations of the deformation induced polygonization allow to conclude that the deformation is controlled by climb of dislocations. In the third chapter, the deformation above 550 Celsius degrees of single crystals of uranium (obtained by {beta} {yields} {alpha} change) is studied. The major deformation mode is slip. The preexisting polygonization of these single crystals is very stable and the disorientation between adjacent sub-grains increases with the deformation. The activation energy for creep is higher than that for polycrystals. These results show the influence of the polygonization due to the {beta} {yields} {alpha} change on the creep behaviour of {alpha} uranium. (authors) [French] Dans le premier chapitre, on decrit la machine de fluage sous vide a enregistrement continu, mise au point pour etudier le phenomene. Le deuxieme chapitre presente les resultats relatifs aux polycristaux. L'utilisation de la methode de DORN a permis de constater que, au-dessus de 550 degres Celsius, l'energie d'activation pour le fluage avait une valeur constante egale a 42 {+-} 2 Kc, voisine de la chaleur d'autodiffusion. L'etude de l'influence de la contrainte appliquee sur la vitesse de fluage et l'observation micrographique de la polygonisation developpee au cours de la deformation permettent de conclure que le phenomene est controle par la montee des dislocations. Dans le troisieme chapitre, on etudie le comportement au fluage au-dessus de 550 C des monocristaux obtenus par

  6. Proceedings of the European Symposium on Pressure Equipment - ESOPE 2007; Actes des Journees d'Etudes Europeennes Equipements sous Pression - ESOPE 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    orientations retained for pressure equipments used in the nuclear industry, the European standards and the international collaboration, the Chinese standards and finally the recent developments of the codes and standards of the ASME in the USA. ESOPE 2007 also includes a Poster Session organized in the context of the international exhibition, which allows the companies to present their industrial realizations in parallel to the Symposium. (author) [French] Tous les trois ans, et depuis maintenant trente ans, l AFIAP organise un symposium ou les experts et acteurs oeuvrant dans le domaine des equipements sous pression, qu'ils soient fixes ou transportables, peuvent se rencontrer et echanger sur tous les developpements touchant a leur activite. Ce qui etait dans un premier temps denomme 'Congres national sur la technologie des appareils a pression', puis 'Journees d'etude sur les appareils a pression', est devenu depuis 2001 les 'Journees d'etude Europeennes sur les equipements sous pression' ou encore 'European Symposium on Pressure Equipment' (ESOPE), marquant ainsi une volonte d'ouverture a l'Europe et a l'international dans un contexte marque par la mise en oeuvre des directives europeennes applicables a ces equipements. Les journees 2001 furent plus particulierement consacrees a la mise en oeuvre des directives harmonisant la construction des equipements, et les journees 2004 ont ete plus particulierement axees sur la gestion des equipements en service. Pour le symposium ESOPE 2007, le comite d organisation a souhaite reprendre ces deux themes sous les aspects de la securite et de la competitivite, ainsi que de l'innovation. La seance pleniere du dernier jour sera entierement consacree a ces themes et comportera une Table Ronde ou s'exprimeront des representants nationaux et europeens des pouvoirs publics, des representants des fabricants et utilisateurs, ainsi que des experts engages dans la

  7. Use of radioactive tracers in studying the transport of solids in watercourses; Emploi de traceurs radioactifs pour l'etude du transport solide dans les cours d'eau; Ispol'zovanie radioaktivnykh indikatorov dlya izucheniya peremeshcheniya tverdykh chastits v vodnykh potokakh; Empleo de indicadores radiactivos para el estudio del transporte de solidos en las corrientes de agua

    Energy Technology Data Exchange (ETDEWEB)

    Courtois, G [Centre d' Etudes Nucleaires de Saclay (France); Jaeery, P; Heuzel, M [Laboratoire National d' Hydraulique de Chatou (France)

    1962-01-15

    The National Hydraulics Laboratory which, in collaboration with the Saclay Nuclear Research Centre, has for several years been devising equipment and techniques for the study of sediment movements by the radioactive tracer method, is now endeavouring to develop a really quantitative method of research. Two river experiments were recently made, the first a study of shingle drifting in the Rhone, the second a study of sand movement in the Niger. The latter experiment was matched by identical experiments carried out on a scale model of the River Niger which the Chatou Laboratory has at its disposal. The experiments used Mn{sup 56} and Na{sup 24} radiation obtained by direct activation of crushed apricot stone, this representing in the scale model the natural sediment of the Niger bed. The Chatou Laboratory and the Saclay Nuclear Study Centre are at present both devoting attention to the application of radioactive tracers in studies with scale models, with the twin aims of: (a) Obtaining a single research tool for use under natural conditions and with scale models in order to gauge the trustworthiness of the model, in the calibration testing stage; (b) Taking advantage of the facilities for direct observation and measurement offered by scale models in order to study prospects of improving the tracer method, with a view particularly to securing quantitative data. (author) [French] Le Laboratoire national d'hydraulique, qui depuis quelques annees a developpe, en collaboration avec le Centre d'etudes nucleaires de Saclay, les appareillages et les techniques d'etudes des mouvements de sediments par la methode des traceurs radioactifs, s'efforce actuellement de mettre au point un moyen d'investigation veritablement quantitatif. Deux experiences ont ete effectuees recemment en riviere, la premiere a ete consacree a l'etude du charriage des galets dans le Rhone, l'autre a l'etude des transports de sables dans le Niger. Cette derniere experience a ete doublee d

  8. Production of heavy water in France; Etude sur la production d'eau lourde en France

    Energy Technology Data Exchange (ETDEWEB)

    Lerat, J M; Roth, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Lefrancois, B [Houllere du Bassin du Nord et du Pas de Calais (France)

    1964-07-01

    Since 1958, studies relating to heavy water production have covered several processes. Each one has been examined to a greater or lesser degree and attention has finally been concentrated on the isotopic exchanges between hydrogen sulphide and water and between ammonia and synthesis gas, the pilot experiment having shown that hydrogen distillation, although technologically satisfactory, was not competitive. NH{sub 3} synthesis gas exchange process; 1) Research was continued and led to the decision to build a production unit, devoted also to the synthesis of ammonia. The process essentially depends on the source of the synthesis gas; the use of a H{sub 2}O/H{sub 2} exchange, which could make it independent, has in fact been rejected for economic reasons. Amongst the various possible designs for the process, the one temperature system was chosen, in spite of certain technological problems, because of it provides: a high enrichment with a reduced number of contact devices. These have now been perfected after large-scale pilot tests. The original industrial experiment to be set in operation will supply useful information for second generation plants, whether they use the one temperature lay out again or whether they adopt the two temperature system. H{sub 2}S-H{sub 2}O exchange process. The pilot plant, described in 1958, has been used for a systematic study of corrosion. It was possible to proceed to preliminary specifications of plants, with 2 or 3 H{sub 2}S - H{sub 2}O stages exchange for primary enrichment. They final stage beyond a 10 to 20 p.100 D{sub 2}O concentration being carried out by the distillation of water. Various heat exchange systems have been studied in detail and it was concluded that choices, as for instance the one of optimum division of the cascade, were eventually to be made according to the particular economic conditions of creation at the chosen location of the plant. (author) [French] Depuis 1958 les etudes concernant la production d

  9. Influence of the Periodic Boundary Conditions on the Fluid Structure and on the Thermodynamic Properties Computed from the Molecular Simulations Influence des conditions périodiques sur la structure et sur les propriétés thermodynamiques calculées à partir des simulations moléculaires

    Directory of Open Access Journals (Sweden)

    Janeček J.

    2013-03-01

    structure de fluide causée par les conditions périodiques; la théorie et les résultats de simulation sont en bon accord. Nous avons étudié la relation entre l’anisotropie des fonctions de corrélation et la dépendance vis-à-vis de la taille du système de l’énergie interne résiduelle et du facteur de compressibilité. Les effets de taille deviennent significatifs dans les systèmes dont la taille de la boîte est inférieure à 5 fois le diamètre des particules, en particulier si la longueur de la boîte est égale à un multiple non entier du diamètre moléculaire. Quand la température augmente, les effets de taille sur la structure du fluide et les propriétés thermodynamiques deviennent moins importants. La principale cause de la déformation de la structure réside dans les corrélations entre particules à courte portée, tandis que les interactions à longue portée n’ont pas d’influence. Les effets de taille du système affectent toutes les simulations atomistiques, y compris celles utilisant les interactions courtes portées et les simulations de dynamique moléculaire. Cependant, les systèmes simulés actuellement sont généralement de taille suffisamment grande, donc la taille finie n’engendre pas de problèmes, sauf pour la détermination des propriétés de surface par des simulations hétérogènes, qui sont sensibles à la dimension latérale de la boîte de simulation.

  10. Study of UO{sub 2}F{sub 2} - H{sub 2}O - HF compounds; Etude des composes UO{sub 2}F{sub 2} - H{sub 2}O - HF

    Energy Technology Data Exchange (ETDEWEB)

    Neveu, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    We study various compounds resulting from the interaction of UO{sub 2}F{sub 2} with H{sub 2}O and HF (gas), and various triple compounds UO{sub 2}F{sub 2} - H{sub 2}O - HF; the conditions of decomposition and the thermodynamic limits of stability are specified. (author) [French] Nous etudions divers composes formes par reaction de UO{sub 2}F{sub 2} avec H{sub 2}O et HF (gaz) et divers composes triples UO{sub 2}F{sub 2} - H{sub 2}O - HF, en essayant de preciser les decompositions et domaines d'exisfence thermodynamiques de ces corps. (auteur)

  11. Contribution to the studies on the mineral content of plant material through radioactivation analysis; Contribution a l'etude de la composition minerale des matieres vegetales au moyen de l'analyse par radioactivation

    Energy Technology Data Exchange (ETDEWEB)

    Fourcy, A. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-03-15

    Radioactivation analysis is by its great sensibility or its rapidity quite helpful in plant biology and agronomy. Specific composition of plants and results to obtain in biological experimentation have needed a practical research on analytical methods for plant materials, using for radioactivation swimming-pool reactor neutrons and 14 MeV neutrons from a generator. Dosage process for 25 elements is exposed, taking account of the interest of the analysis for each element, the average amount occurring in plants and the result obtained. Many applications are developed, concerning nutrition physiology, genetics, parasitology, toxicology, control of manufactured agricultural and pharmaceutical products industrial and pesticides residues, ecology, radioecology and biochemistry. (author) [French] L'analyse par radioactivation, par sa grande sensibilite ou sa rapidite, est susceptible de rendre de nombreux services en biologie vegetale et en agronomie. La composition particuliere des plantes et les buts recherches dans l'experimentation ont exige une etude concrete des methodes d'analyse propres a la matiere vegetale en utilisant, pour la radioactivation, soit un reacteur de type piscine a eau legere, soit un accelerateur generateur de neutrons de 14 MeV. Le mode de dosage de 25 elements est expose en tenant compte de l'interet de l'analyse de chaque element, des teneurs moyennes rencontrees dans les plantes, et du resultat atteint. De nombreuses applications sont developpees qui touchent a la physiologie de la nutrition, la genetique, la parasitologie, la toxicologie, le controle des fabrications, les pollutions industrielles, l'ecologie, la radioecologie et la biochimie. (auteur)

  12. Study of the long-term values and prices of plutonium; a simplified parametrized model; Etude des valeurs et des prix du plutonium a long terme; un modele parametre simplifie

    Energy Technology Data Exchange (ETDEWEB)

    Gaussens, J; Paillot, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors define the notions of use values and price of plutonium. They give a 'simplified parametrized model' simulating the equilibrium of the offer and the demand in time, concerning the plutonium and the price deriving from the relative scarcity of this metal, taking into account the technical and economic operating parameters of the various reactors confronted. This model is simple enough to allow direct computations and establish clear relations between the various parameters. The use of the linear programmes method allows on the other hand a wide extension of the model. This report includes three main parts: I - General description of the study (without detailed calculations) II - Mathematical development of the simplified parametrized model and application (the basic data and the results of the calculations are given) III - Appendices (giving the detailed computations of part II). (authors) [French] Les auteurs definissent les notions de valeurs d'usage et de prix du plutonium. Ils donnent un 'modele parametre simplifie' simulant l'equilibre de l'office et de la demande dans le temps concernant le plutonium et le prix qui decoule de la rarete relative de ce metal, compte tenu des parametres techniques et economiques de fonctionnement des divers reacteurs en presence. Ce modele est suffisamment simple pour permettre des calculs manuels et etablir des liaisons claires entre les divers parametres. L'utilisation de la technique des programmes lineaires permet par ailleurs une extension considerable du modele. Cette note comprend trois parties: I - Expose general de l'etude (sans expose du detail des calculs) II - Developpement mathematique du modele parametre simplifie et application (on precise les donnees de base et le resultat des calculs) III - Annexes (donnant le detail des calculs de la partie II). (auteurs)

  13. Contribution to the study of the biological properties of compounds labeled with radio-chromium {sup 51}Cr; Contribution a l'etude des proprietes biologiques des composes marques au radiochrome {sup 51}Cr

    Energy Technology Data Exchange (ETDEWEB)

    Ingrand, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-15

    Among the radioisotopes commonly used in biology and medicine which are controlled Individually in the Radioelement Departement of the Saclay Nuclear Research Centre before being sent to the users, the author has chosen chromium 51 incorporated in inorganic salts or in organic substrates for a study of the biological properties of the compounds. In the first part, he has compared the pathways followed by the radioactive sodium chromate and chromic chloride mixed with blood or given to the whole animal, the object being to determine whether a reduction of hexavalent chromium occurs, both in vitro and in vivo. In the second part, the author has tried to show the validity of using, various substrates labeled with chromium 51, red cells, haemoglobin, plasma proteins and cytochrome c. The results obtained have contributed to underline the interest of using such compounds for biological applications. (author) [French] Parmi les radioisotopes d'utilisation courants en biologie et en medecine qui sont l'objet d'un controle particulier dans le Departement des Radioelements du Centre d'Etudes Nucleaires de Saclay avant leur diffusion aux utilisateurs, l'auteur a choisi le chrome 51 incorpore a des sels mineraux ou a des substrats organiques, afin d'en etudier les proprietes biologiques. Dans la premiere partie, il a compare le sort du chromate de sodium et du chlorure chromique radioactifs melanges a du sang ou administres a l'animal entier en s'efforcant de mettre en evidence une reduction du chrome hexavalent aussi bien in vitro qu'in vivo. Dans la deuxieme partie, il a cherche a etablir la validite de l'emploi de differents substrats marques au chrome 51, l'hematie, l'hemoglobine, les proteines plasmatiques et le cytochrome c. Les resultats obtenus ont permis de souligner le reel interet des applications biologiques des composes marques par le radioisotope. (auteur)

  14. Contribution to the studies on the mineral content of plant material through radioactivation analysis; Contribution a l'etude de la composition minerale des matieres vegetales au moyen de l'analyse par radioactivation

    Energy Technology Data Exchange (ETDEWEB)

    Fourcy, A [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-03-15

    Radioactivation analysis is by its great sensibility or its rapidity quite helpful in plant biology and agronomy. Specific composition of plants and results to obtain in biological experimentation have needed a practical research on analytical methods for plant materials, using for radioactivation swimming-pool reactor neutrons and 14 MeV neutrons from a generator. Dosage process for 25 elements is exposed, taking account of the interest of the analysis for each element, the average amount occurring in plants and the result obtained. Many applications are developed, concerning nutrition physiology, genetics, parasitology, toxicology, control of manufactured agricultural and pharmaceutical products industrial and pesticides residues, ecology, radioecology and biochemistry. (author) [French] L'analyse par radioactivation, par sa grande sensibilite ou sa rapidite, est susceptible de rendre de nombreux services en biologie vegetale et en agronomie. La composition particuliere des plantes et les buts recherches dans l'experimentation ont exige une etude concrete des methodes d'analyse propres a la matiere vegetale en utilisant, pour la radioactivation, soit un reacteur de type piscine a eau legere, soit un accelerateur generateur de neutrons de 14 MeV. Le mode de dosage de 25 elements est expose en tenant compte de l'interet de l'analyse de chaque element, des teneurs moyennes rencontrees dans les plantes, et du resultat atteint. De nombreuses applications sont developpees qui touchent a la physiologie de la nutrition, la genetique, la parasitologie, la toxicologie, le controle des fabrications, les pollutions industrielles, l'ecologie, la radioecologie et la biochimie. (auteur)

  15. Contribution to the study of the biological properties of compounds labeled with radio-chromium {sup 51}Cr; Contribution a l'etude des proprietes biologiques des composes marques au radiochrome {sup 51}Cr

    Energy Technology Data Exchange (ETDEWEB)

    Ingrand, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-15

    Among the radioisotopes commonly used in biology and medicine which are controlled Individually in the Radioelement Departement of the Saclay Nuclear Research Centre before being sent to the users, the author has chosen chromium 51 incorporated in inorganic salts or in organic substrates for a study of the biological properties of the compounds. In the first part, he has compared the pathways followed by the radioactive sodium chromate and chromic chloride mixed with blood or given to the whole animal, the object being to determine whether a reduction of hexavalent chromium occurs, both in vitro and in vivo. In the second part, the author has tried to show the validity of using, various substrates labeled with chromium 51, red cells, haemoglobin, plasma proteins and cytochrome c. The results obtained have contributed to underline the interest of using such compounds for biological applications. (author) [French] Parmi les radioisotopes d'utilisation courants en biologie et en medecine qui sont l'objet d'un controle particulier dans le Departement des Radioelements du Centre d'Etudes Nucleaires de Saclay avant leur diffusion aux utilisateurs, l'auteur a choisi le chrome 51 incorpore a des sels mineraux ou a des substrats organiques, afin d'en etudier les proprietes biologiques. Dans la premiere partie, il a compare le sort du chromate de sodium et du chlorure chromique radioactifs melanges a du sang ou administres a l'animal entier en s'efforcant de mettre en evidence une reduction du chrome hexavalent aussi bien in vitro qu'in vivo. Dans la deuxieme partie, il a cherche a etablir la validite de l'emploi de differents substrats marques au chrome 51, l'hematie, l'hemoglobine, les proteines plasmatiques et le cytochrome c. Les resultats obtenus ont permis de souligner le reel interet des applications biologiques des composes marques par le radioisotope. (auteur)

  16. Costic's technical day: thermodynamical heating and air conditioning in accommodations (heat pumps and heating/cooling floors). Air systems and their application in collective installations; Journee technique Costic: chauffage thermodynamique et climatisation dans l'habitat (les pompes a chaleur, les planchers chauffants-rafraichissants). Les systemes a air les applications en collectif

    Energy Technology Data Exchange (ETDEWEB)

    Lenotte, J.J.

    2002-07-01

    Direct expansion air systems are now currently used in individual residential houses. Some of these systems are used also in collective residential buildings where they allow to take into account the individualization of consumptions, as wished by some property developers. Some other centralized air-conditioning systems can be used. They require a distribution water loop for the supply of terminal units of ventilation-convection type. This document presents successively: the direct expansion air systems (direct emission air/air heat pumps, aeraulic distribution air/air heat pumps, production dimensioning, implementation, regulation, systems with variable flow rate of refrigerant); the centralized air/water systems with ventilation-convection systems (production dimensioning, implementation, regulation); the air distribution and diffusion. (J.S.)

  17. Theoretical study of the paramagnetic scattering of neutrons; Etude theorique de la diffusion paramagnetique des neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Saint-James, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-02-15

    diverses diffusions (elastique et inelastiques) est calculee pour les terres rares soumises a l'action d'un champ cristallin de symetrie cubique, pour les sesquioxydes d'holmium et d'erbium et pour le chlorure ferreux anhydre (Cl{sub 2}Fe). Elle est suffisamment forte pour permettre une detection experimentale, fournissant ainsi une determination directe de la distance des niveaux par mesure de la variation de longueur d'onde du neutron. Il est, de plus, remarquable que, dans le cas du neodyme, de l'holium et de l'erbium, la section efficace totale calculee pour des neutrons de longueur d'onde aux alentours de l'angstrom soit peu sensible aux effets du champ cristallin. On compare les resultats des calculs ci-dessus aux etudes experimentales existantes. On examine egalement l'influence du moment orbital sur la dependance angulaire de la diffusion pour des ions polarises. La loi I = I{sub 0}sin{sup 2}{beta} n'est qu'approchee; on en donne les limites de validite. On envisage enfin l'influence des interactions d'echange entre les ions magnetiques. Les raies de diffusion elastiques et inelastiques sont elargies. Le comportement de la largeur de raie, avec la longueur du vecteur de diffusion k, est different de celui obtenu dans le cas ou le niveau fondamental de l'ion magnetique est defini par un moment cinetique J . La largeur de raie ne tend pas vers zero avec K. (auteur)

  18. Contribution to the study of samarium-151 excited levels; Contribution a l'etude des niveaux excites du samarium-151

    Energy Technology Data Exchange (ETDEWEB)

    Locard, P [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Grenoble, 38 (France)

    1967-07-01

    The nucleus of {sup 151}Sm, which has 89 neutrons, happens to be on the lower edge of the deformed nuclei of region II. Therefore, the study of its levels is very interesting for the verification of the goodness of the collective models for deformed nuclei when the deformation is small (we introduce these models in the first chapter). {sup 151}Sm has often been studied, but the direct gamma spectrum measured with a lithium drift-germanium detector (chapter 3) shows many high energy transitions which did not appear in the previous level schemes. In order to settle these transitions, we have undertaken gamma-gamma coincidence spectra (as well as sum-coincidence spectra) experiments with a scintillation spectrometer designed in our laboratory (chapter 2). The investigation of the intensities of these coincidences leads us to modify the last proposed level schemes: we suppress the levels at 405,5 and 650 keV, we add levels at 245,6 - 306,6 - 522 - 952 and 962 keV. We have also verified the multipolarities of the main transitions and measured the half-lives of a few levels (chapter 3) (we find a half-life of 1.1 {+-} 0.5 nanosecond for the level at 167,7 keV). In chapter 4, we compare our results to the predictions of the models described in chapter 1. (author) [French] Le noyau de {sup 151}Sm, qui possede 89 neutrons, se trouve a la limite inferieure des noyaux deformes de la region II. L'etude de ses niveaux excites est donc d'un interet tout particulier pour la verification de la validite des differents modeles collectifs pour les noyaux deformes, lorsque la deformation est petite (nous introduisons ces modeles dans un premier chapitre). Le {sup 151}Sm a deja fait l'objet de nombreuses etudes, mais le spectre gamma direct fait avec une jonction de germanium compense au lithium (chapitre 3), nous a montre l'existence d'un grand nombre de transitions de hautes energies qui ne sont pas placees dans les schemas proposes jusqu'a ce jour. Pour preciser la place de ces

  19. Study of the artificial radioactivity of the marine medium using gamma spectrometry (1962-1966); Etude de la radioactivite artificielle du milieu marin par spectrometrie gamma (1962-1966)

    Energy Technology Data Exchange (ETDEWEB)

    Chesselet, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The results described in this study are relative to the artificial radioactivity of such elements as zirconium-95, niobium-95, ruthenium-103, ruthenium-106, cerium-141, cerium-144 and praseodymium-144 which were present in the atmospheric fallout between 1962 and 1964, and their incidence in superficial marine waters. Various physical, chemical or biological processes are studied by a high sensitivity gamma ray spectrometry technic, using those radioelements as 'tracers'. The change of state in sea water of an important fraction (about 50 per cent) of the radioactive particles going into the soluble phase - this phenomenon was not expected for those radioelements - controls the processes of accumulation in the planktonic biomass and the diffusion towards deeper waters. On the other hand, an 'in situ' spectrometry method is described. It enables the direct measurement in the sea of very low concentrations of some gamma ray emitters. The application of this method has made possible to carry out numerous observations in the surface waters of the Western Mediterranean sea and in the Bay of Biscay. It is shown that the mixing depth is closely connected to the depth of the thermocline. An accumulation process at this level is observed. The diffusion coefficients are similar to the thermal turbulent coefficient. The existence during several months of 'compartments' is established for the surface waters of the Bay of Biscay. From the establishment of the budget of fall-out, a comparative study shows that the rate of radioactive fallout on the maritime zone considered is always two to three times higher than on the neighbouring continental regions. Several explanations of this phenomenon are discussed. (author) [French] Les resultats decrits dans cette etude concernent la radioactivite artificielle sous forme de zirconium-95, niobium-95, ruthenium-103, ruthenium-106, cerium-141, cerium-144 et praseodyme-144 apportee par la retombee atmospherique entre 1962 et 1964 et les

  20. Study of the artificial radioactivity of the marine medium using gamma spectrometry (1962-1966); Etude de la radioactivite artificielle du milieu marin par spectrometrie gamma (1962-1966)

    Energy Technology Data Exchange (ETDEWEB)

    Chesselet, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The results described in this study are relative to the artificial radioactivity of such elements as zirconium-95, niobium-95, ruthenium-103, ruthenium-106, cerium-141, cerium-144 and praseodymium-144 which were present in the atmospheric fallout between 1962 and 1964, and their incidence in superficial marine waters. Various physical, chemical or biological processes are studied by a high sensitivity gamma ray spectrometry technic, using those radioelements as 'tracers'. The change of state in sea water of an important fraction (about 50 per cent) of the radioactive particles going into the soluble phase - this phenomenon was not expected for those radioelements - controls the processes of accumulation in the planktonic biomass and the diffusion towards deeper waters. On the other hand, an 'in situ' spectrometry method is described. It enables the direct measurement in the sea of very low concentrations of some gamma ray emitters. The application of this method has made possible to carry out numerous observations in the surface waters of the Western Mediterranean sea and in the Bay of Biscay. It is shown that the mixing depth is closely connected to the depth of the thermocline. An accumulation process at this level is observed. The diffusion coefficients are similar to the thermal turbulent coefficient. The existence during several months of 'compartments' is established for the surface waters of the Bay of Biscay. From the establishment of the budget of fall-out, a comparative study shows that the rate of radioactive fallout on the maritime zone considered is always two to three times higher than on the neighbouring continental regions. Several explanations of this phenomenon are discussed. (author) [French] Les resultats decrits dans cette etude concernent la radioactivite artificielle sous forme de zirconium-95, niobium-95, ruthenium-103, ruthenium-106, cerium-141, cerium-144 et praseodyme-144 apportee par la retombee

  1. Apprendre et maîtriser LabVIEW par ses applications

    CERN Document Server

    Martaj, Nadia

    2014-01-01

    Cet ouvrage traite de l'apprentissage du langage LabVIEW a travers ses applications dans des domaines industriels et academiques, qui permettront a l'ingenieur, technicien ou etudiant d'apprehender rapidement et efficacement ce langage. L'ouvrage commence, dans la partie I, par traiter les differents types de donnees du langage LabVIEW (tableaux, clusters, complexes, chaines de caracteres...), leur manipulation dans des structures d'execution (boucles While, For, la structure Condition, etc.), le langage textuel MathScript, des scripts Matlab, la boite de calcul utilisant la syntaxe du langage C ainsi que les nœuds de propriete qui permettent d'obtenir ou definir la propriete d''un VI. Cette etude est menee a travers des applications d'ingenierie.La partie II est consacree a l'etude de l'outil « Conception de controle et simulation » avec lequel nous pouvons simuler des systemes analogiques ou discrets.La partie III contient differentes applications qui traitent de nombreux themes comme la regulation (diff...

  2. Aerodynamic and thermal studies of cans of gas cooled fuel elements; Etudes aerodynamiques et thermiques de gaines d'elements combustibles refroidis par gaz

    Energy Technology Data Exchange (ETDEWEB)

    Gelin, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Milliat, J P [Electricite de France (EDF), 75 - Paris (France)

    1964-07-01

    Research on clusters was undertaken at the CEA in 1959, while studies on herring-bone cans were developed at the EDF Laboratory at Chatou and the CEA laboratory at Saclay at the end of 1959. In 1962, a general study on corrugations was begun at the Saclay Laboratory with a view to improving the clusters, and continued later in both laboratories relative to the internal cooling of annular fuel elements. As these studies progressed, trial facilities were extended while experimental methods have improved constantly. At the present time, both laboratories, working in complete collaboration, have powerful means at their disposal. Work on the clusters has been concerned chiefly with pressure losses due to the assembly parts, and with the temperature variations around the elements of the cluster. In this way, we have been able to determine satisfactorily the hot points of the can, the deformations of the rods and the conditions of stability of these deformations. In the case of the herring-bone cans, studies have been directed to the evolution of performances as a function of the geometric parameters on the one hand, and to the special aerodynamic and thermal features caused by the fins and by interruptions of cartridge on the other hand. These studies have led to a very thorough knowledge of the cartridges chosen for the reactors EDF 2 and EDF 3, and now open up very hopeful prospects for future reactors, particularly those fitted with annular elements; among the alternatives suitable for the inner surface of the annular element can, corrugations and longitudinal fins have been fairly extensively tested over a wide range of Reynolds number. (authors) [French] Les etudes de grappes ont ete entreprises au C.E.A. en 1959, tandis que les etudes de gaines a chevrons se sont developpees au Laboratoire de Chatou de l'EDF et au Laboratoire de Saclay du C.E.A. a la fin de l'annee 1959. En 1962, une etude generale sur les corrugations a ete commencee au Laboratoire de Saclay pour

  3. Development of a slow mono-kinetic electron source; Etude et realisation d'une source d'electrons lents monocinetiques

    Energy Technology Data Exchange (ETDEWEB)

    Ballu, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-06-01

    A comparative study of already existing slow mono-kinetic electron guns shows that those using a 127 degrees electrostatic selector can be improved still further to arrive at the performances obtained with spherical 180 degrees selectors for example. For this reason we have examined the 127 degrees selector theoretically in more detail; it appears that it should be possible to obtain a resolving power better than 30 mV for a current of about 10{sup -10} A, on condition that certain improvements be made to the instrument as normally designed, in particular concerning the entrance and exit slides. As a result, the usual suppressors for the scattered electrons are no longer necessary. The development of this apparatus has been carried out with particular care: the dimensional characteristics are fixed to an accuracy of a few microns, although the instrument can be baked out at 300 C. The experimental results are in excellent agreement with the theoretical predictions: for a current of 10{sup -10} A, the measured resolving power is 24 {+-} 4 mV. The easy detection of the He{sup -} resonance line at 19.3 eV has confirmed the advantages of this apparatus for the study of atomic collisions. (author) [French] L'etude comparative des canons a electrons lents monocinetiques realises jusqu'a present montre que ceux qui utilisent un selecteur electrostatique a 127 degres peuvent etre encore perfectionnes en vue de parvenir aux performances obtenues avec les selecteurs spheriques a 180 degres par exemple. D'ou notre etude theorique approfondie du selecteur a 127 degres qui nous a conduit a esperer une resolution meilleure que 30 mV pour un courant de l'ordre de 10{sup -10} A a condition d'apporter certaines ameliorations a la conception usuelle de cet instrument notamment au niveau des fentes d'entree et de sortie. Par voie de consequence les suppresseurs habituels d'electrons parasites deviennent inutiles. L'etude et la mise au point de l'appareil ont fait l'objet de soins

  4. Study of cerenkov radiation. Production of {gamma} rays by electron accelerators; Etude du rayonnement de freinage. Production de rayons {gamma} par des accelerateurs d'electrons

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    This study is a critical comparison of the theories of Bremsstrahlung. Experimental results obtained by the production of {gamma} radiation with electron accelerators are compared to the theoretical results in order to estimate the extent to which the various theories are valid. (author) [French] Cette etude est une synthese des theories du rayonnement de freinage. Des resultats experimentaux, obtenus par la production de rayonnements {gamma} avec des accelerateurs d'electrons, sont compares aux resultats theoriques afin d'evaluer les domaines de validite des diverses theories. (auteur)

  5. Use of hydraulic and aerial mock up to study atmospheric pollution; L'utilisation des maquettes aeriennes et hydrauliques pour l'etude de la pollution atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Facy, L; Perrin De Brichambaut, C; Doury, A; Le Quinio, R

    1962-07-01

    Fundamental studies on turbulent atmospheric diffusion of finely divided particles, cannot remain on a purely theoretical basis. Further experimental studies must be considered. - In full scale, from accidental and induced releases. - On a reduced scale, in aerodynamic wind tunnels or hydraulic water tunnels. A first set of studies on reduced scale models has been worked out according to a contract between French 'Meteorologie Nationale' and French 'Commissariat a l'Energie Atomique' and with the Collaboration of Saint-Cyr 'Institut Aerotechnique'. Essentially two kinds of results have been obtained: - The mathematical model of SUTTON for the turbulent diffusion in the atmosphere, deduced from the SUTTON theory, generally used by us, has been correctly verified, qualitatively and quantitatively whenever experiments were consistent with the theory conditions. - The quantitative assays of photographic and cinematographic visualization have given precise details on the phenomena inaccessible to calculations, due to the influence of obstacles and release conditions. - Generally, it can be asserted, that the atmospheric pollution studies are worked out by mock up experimentations and that, in some cases these experiments never can be replaced by mathematically pure models. (authors) [French] Les etudes fondamentales portant sur la diffusion turbulente dans l'atmosphere de quantites de matieres finement divisees, ne peuvent se maintenir sur un plan exclusivement theorique. C'est pourquoi des etudes experimentales complementaires doivent etre obligatoirement envisagees: - en vraie grandeur, a partir d'emissions accidentelles ou provoquees; - sur modeles reduits, en soufflerie aerodynamique ou en veine hydraulique. En ce qui concerne les modeles reduits, une premiere serie d'etudes a pu etre menee a bien, dans le cadre d'un contrat passe entre la Meteorologie Nationale et le Commissariat a l'Energie Atomique, et avec la collaboration de l'Institut Aerotechnique de Saint

  6. Studies of magnetism with inelastic scattering of cold neutrons; Etudes de magnetisme realisees a l'aide de la diffusion inelastique de neutrons froids

    Energy Technology Data Exchange (ETDEWEB)

    Jacrot, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Inelastic scattering of cold neutrons can be used to study some aspects of magnetism: spins waves, exchange integrals, vicinity of Curie point. After description of the experimental set-up, several experiments, in the fields mentioned above, are analysed. (author) [French] La technique de diffusion inelastique des neutrons froids est utilisee pour etudier certains aspects du magnetisme: ondes de spins, integrales d'echange, etude au voisinage du point de Curie, etc. Apres une description de l'appareillage, on analyse diverses experiences effectuees dans les domaines enumeres plus haut. (auteur)

  7. Some examples of application of activation analysis to geology

    International Nuclear Information System (INIS)

    Schiltz, Jean-Claude

    1969-10-01

    For some fifteen years, activation analysis knows a considerable development. New facilities have become to be done to research workers and industrials by the fitting up of special laboratories near high flux reactors, in the Centre d'Etudes Nucleaires de Saclay and Grenoble. Other laboratories apparatus and particles sources are also used (fast neutrons generators, accelerators, etc. ). For some years, our laboratory contributed to study activation analysis applications to the field of Earth Sciences, particularly to geochemistry. Collecting here our experience and that of other laboratories, we have wished to give a glimpse of the diversity of applications and their as well economical as purely technical interest. This job, initial web of a conference done to the ADERP week in February 1969, doesn't obviously pretend to the exhaustion of the subject. We have simply chosen examples among the 'ost typical of our works and among those which have shown a bibliographical interest for us. (author) [fr

  8. Contribution to a research on electron beam welding of metals; Contribution a l'etude de la soudure des metaux par faisceau d'electrons

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-03-15

    pressure, occasioned by additional elements with high vapour pressure, put on the formation of the hole. Micrographs made with welded parts of different metals show melting segregations similar to those obtained when filling a mould of great length. One may point out, that the geometrical configuration adopted by these segregations confirm the hypothesis of the metal flow, as previously contemplated. The study of these segregations, observed during examination through an interferential contrast microscope, has been attempted with a Castaing probe and by radiographical inspection of thin plates: no heterogeneity whatever has been observed. Mechanical tests operated on welded parts, did not show any appreciable difference existing between failure, elongation, yield point and impact values of a welded piece and those of a piece of the basic metal. This method applied on stainless steel shows not only excellent results, but also that the number of calories provided per length unit increases slightly with the welded thickness, whereas one could have expected a linear expression. Results obtained during this work, allow us to sift a certain number of data inherent to the electron beam welding, and to reflect on the definition of welding parameters versus aim to be reached. (author) [French] La soudure des metaux par faisceau d'electrons s'effectue par deplacement du point de focalisation du faisceau sur la ligne de jonction des deux pieces a assembler. Les parametres de soudure sont la puissance du canon W, la valeur de la surface d'impact des electrons S, la vitesse de soudure s. Des le debut de notre etude en 1954, est apparu le role essentiel joue par la puissance specifique W/s, sur la forme de la zone soudee et la profondeur de penetration. Une etude plus systematique a ete entreprise aux laboratoires du C.E.N. Saclay sous le patronage de Monsieur le Professeur CHAUDRON pour mieux definir l'Importance des divers parametres de soudure et voir l'influence exercee par eux sur

  9. Method of research and study of uranium deposits; Methode de recherches et d'etude des gites uraniferes

    Energy Technology Data Exchange (ETDEWEB)

    Lenoble, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    In a first part, the author gives a fast retrospective of the evaluations of the uranium deposits in the French Union. The author established a method of prospecting and studying, modifiable at all times following the experiences and the results, permitting to make the general inventory of uranium resources on the territory. The method is based on: 1 - the determination of geological guides in order to mark the most promising deposits, 2 - the definition of a methodology adapted to every steps of the research, 3 - the choice of the material adapted for each of the steps. This method, originally established for the prospecting in crystalline massifs, is adaptable to the prospecting of the sedimentary formations. (M.B.) [French] Dans une premiere partie, l'auteur donne une retrospective rapide des estimations des gites uraniferes dans l'Union Francaise. L'auteur a etabli une methode de prospection et d'etude, modifiable a tout instant suivant les experiences et les resultats, permettant de faire l'inventaire general des ressources en uranium du territoire. La methode est base sur: 1 - la determination de guides geologiques afin de reperer les gisements les plus prometteurs, 2 - la definition d'une methodologie adaptee a chaque stade de la recherche, 3 - le choix du materiel adapte pour chacun des stades. Cette methode, a l'origine etablie pour la prospection en massifs cristallins, est adaptable a la prospection des formations sedimentaires. (M.B.)

  10. Some equipment for graphite research in swimming pool reactors; Quelques dispositifs d'etude du graphite dans les piles piscines

    Energy Technology Data Exchange (ETDEWEB)

    Seguin, M; Arragon, Ph; Dupont, G; Gentil, J; Tanis, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-07-01

    The irradiation devices described are used for research concerning reactors of the natural uranium type, moderated by graphite and cooled by carbon dioxide. The devices are generally designed for use in swimming pool reactors. The following points have been particularly studied: - maximum use of the irradiation volume, - use of the simplest technological solutions, - standardization of certain constituent parts. This standardization calls for precision machining and careful assembling; these requirements are also true when a relatively low irradiation temperature is required and the nuclear heating is pronounced. Finally, the design of these devices is suitable for the irradiation of other fissile or non-fissile materials. (authors) [French] Les dispositifs d'irradiation decrits servent aux etudes relatives a la filiere des reacteurs a uranium naturel, moderes au graphite et refroidis par le gaz carbonique. Ils sont generalement concus pour etre utilises dans des piles piscines. L'accent a ete mis sur: - l'utilisation au maximum du volume d'irradiation, - le recours aux solutions technologiques les plus simples, - la standardisation de certaines parties constitutives. Cette standardisation impose un usinage precis et un montage soigne, lesquels sont egalement necessaires lorsqu'on doit obtenir une temperature d'irradiation relativement basse alors que l'echauffement nucleaire est important. Enfin, la conception de ces dispositifs est valable pour irradier d'autres materiaux non fissiles ou fissiles. (auteurs)

  11. Serotonin transporter gene polymorphism and myocardial infarction: Etude Cas-Témoins de l'Infarctus du Myocarde (ECTIM).

    Science.gov (United States)

    Fumeron, Frédéric; Betoulle, Dina; Nicaud, Viviane; Evans, Alun; Kee, Frank; Ruidavets, Jean-Bernard; Arveiler, Dominique; Luc, Gérald; Cambien, François

    2002-06-25

    Depression is a risk factor for myocardial infarction (MI). Selective serotonin reuptake inhibitors reduce this risk. The site of action is the serotonin transporter (SLC6A4), which is expressed in brain and blood cells. A functional polymorphism in the promoter region of the SLC6A4 gene has been described. This polymorphism may be associated with the risk of MI. The SLC6A4 polymorphism has been investigated by polymerase chain reaction in 671 male patients with MI and in 688 controls from the Etude Cas-Témoins de l'Infarctus du Myocarde (ECTIM) multicentric study. Percentages for LL, LS, and SS genotypes were 35.5%, 45.4%, and 19.1%, respectively, for cases versus 28.1%, 49.1%, and 22.8%, respectively, for controls. S allele frequency was 41.8% and 47.4% for cases and controls, respectively. After adjustment for age and center by using multivariable logistic regression, the odds ratio for MI associated with the LL genotype was 1.40 (95% CI 1.11 to 1.76, P=0.0047). The LL genotype of the SLC6A4 polymorphism is associated with a higher risk of MI. This could be attributable to the effect of the polymorphism on serotonin-mediated platelet activation or smooth muscle cell proliferation or on other risk factors, such as depression or response to stress.

  12. Cognitive decline is associated with systemic oxidative stress: the EVA study. Etude du Vieillissement Artériel.

    Science.gov (United States)

    Berr, C; Balansard, B; Arnaud, J; Roussel, A M; Alpérovitch, A

    2000-10-01

    To determine whether systemic oxidative stress status is associated with cognitive decline. A longitudinal population-based study. A cohort study of older subjects in Nantes, France. A total of 1166 high cognitive functioning subjects aged 60 to 70 in the Etude du Vieillissement Arteriel (EVA) cohort with a 4 year follow-up. Subjects completed a baseline interview and a global cognitive test (Mini-Mental Status Examination (MMSE)). Blood samples were obtained at baseline to determine plasma levels of selenium, carotenoids, thiobarbituric acid reactant substances (TBARS), an indicator of lipoperoxidation, and red blood cell vitamin E. Risk of cognitive decline, defined as a loss of 3 points in MMSE score between baseline and the 4 year follow-up, was assessed by oxidative stress level. Subjects with the highest levels of TBARS show an increased risk of cognitive decline (adjusted odds ratio (OR) = 2.25; confidence interval (CI) 95% = 1.26-4.02). This result is reinforced in the lower antioxidant status subgroup. Subjects with low levels of selenium have an increased risk of cognitive decline (OR = 1.58; CI 95% = 1.08-2.31) after adjustment for various confounding factors. These results suggest that increased levels of oxidative stress and/or antioxidant deficiencies may pose risk factors for cognitive decline. The direct implication of oxidative stress in vascular and neurodegenerative mechanisms that lead to cognitive impairment should be further explored.

  13. Some aspects of nuclear graphite production in France; Etude generale sur les graphites nucleaires produits en France

    Energy Technology Data Exchange (ETDEWEB)

    Gueron, J; Hering, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Legendre, A [Pechiney, 75 - Paris (France)

    1958-07-01

    1) Manufacturing: A summary and results on the CEA-Pechiney purification process are given. Variations in the preparation of green pastes and their effects on graphitized material are described. 2) Physical and mechanical properties: Results are given on: - Statistics of dimensional variatior products having square cross-section. - Statistical variation of thermal expansion coefficients and of electrical conductivity. - Density of normals to carbon layer planes and their connexion with thermal expansion. - Stress-strain cycles and conclusions drawn therefrom. - Mechanical resistance and gas permeability of items for supporting fuel elements. 3) Behaviour under radiation: Alteration under radiation of French graphites irradiated either in G1 pile or in experimental piles, and thermal annealing of those alterations, are given. (author)Fren. [French] 1) Fabrication: On resume le procede d'epuration CEA-PECHINEY, ainsi que diverses modalites de preparation des pates et on expose les resultats obtenus. 2) Proprietes physiques et mecaniques: On indique le resultat d'etudes sur: - la statistique des dimensions de produits a section carree. - celle des variations des coefficients de dilatation thermique et de la conductibilite electrique. - la densite des normales aux plans graphitiques et leur connexion avec la dilatation thermique. - la compression mecanique du graphite. - la solidite mecanique et la permeabilite aux gaz de pieces destinees a supporter des cartouches de combustible. 3) Tenue sous rayonnement: Modification sous rayonnement des graphites fran is irradies soit dans la pile G1, soit dans des piles experimentales, et guerison thermique de ces modifications. (auteur)

  14. Studies of the Stabilization of Superconductor Coils; Etudes sur la Stabilisation des Bobines Supraconductrices

    Energy Technology Data Exchange (ETDEWEB)

    Donadieu, L.; Maldy, J. [Compagnie Generale d' Electricite Marcoussis (France)

    1966-12-15

    operation of the coil will be stable and the passage of the I-B characteristic of the material will be reversible; (b) Ic < Im, the operation of the coil is unstable and any sufficiently large disturbances (flux jump, movement of windings, etc. ) can produce blocking. This is inevitably the case with the large coils whose operational limit tends towards Im. Different coils have been constructed with more or leas stabilised materials and the results of tests on them are analysed as a' function of the previous theories. There Is a full discussion of the advantages and disadvantages of coil stabilizations. (author) [French] La stabilisation de l'intensite du courant dans les bobinages supra-conducteurs, qui apparait d'une importance capitale pour la construction de bobinages de grande taille , est etudiee a la fois du point de vue theorique et du point de vue experiment a l. L'etude de la dynamique de la transition d'un supraconducteur transportant du courant, entre l ' e t at supraconducteur a resistance nulle et l ' e tat a resistance normale ( l e blocage), revele l'existence d'une intensite caracteristique, Im, pour laquelle la vitesse de propagation de la region normale est nulle. Cette intensite depend directement des echanges de chaleur entre le supraconducteur et le milieu ambiant, et de la resistance du materiau a l ' e t a t normal; Im depend indirectement de l'intensite du champ magnetique. Si un supraconducteur est utilise avec une intensite de courant inferieure a Im, la vitesse de propagation est negative et le supraconducteur est capable eventuellement de realiser la transition inverse de l ' e t a t normal a l ' e t a t supraconducteur. On peut montrer que pour une intensite Is telle que Is = Im/ Square-Root 2 , la vitesse de propagation qui est negative devient infiniment grande. L'existence de ces 2 intensites caracteristiques permet de distinguer trois cas de comportement differents selon l'intensite du courant qui parcourt le supraconducteur. L'auteur a

  15. Electrochemical study in molten potassium thiocyanate; Etude electrochimique dans le thiocyanate de potassium fondu

    Energy Technology Data Exchange (ETDEWEB)

    Metzger, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    comparaison des valeurs des potentiels trouves dans le thiocyanate avec celles qui sont connues pour d'autres solvants fondus, nous a permis de rapprocher les proprietes du thiocyanate de celles de certains sels comme les chlorures ou les nitrates fondus. Ainsi les proprietes complexantes de SCN{sup -} vis-a-vis de Cu{sup +} exaltent les proprietes oxydantes de Cu{sup 2+}. Une etude polarographique de complexes dans le bain fondu, nous a revele l'existence de deux complexes cupro-cyanures de formules Cu(CN){sup -}{sub 2} et Cu(CN){sup 3-}{sub 4}, dont nous avons determine, experimentalement les constantes de dissociation. (auteur)

  16. Study of uranium-titanium diffusion; Etude de la diffusion uranium-titane

    Energy Technology Data Exchange (ETDEWEB)

    Adda, Y; Philibert, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1959-07-01

    . (author) [French] Dans le cadre de recherches sur la diffusion chimique de l'uranium et des metaux de transition, nous avons etudie le systeme uranium-titane. Les couples de diffusion sont prepares, suivant une technique que avons deja decrite, par soudage sous pression de plaquettes d'uranium et de titane. Apres traitement de diffusion sous vide, les echantillons sont etudies micrographiquement suivant une section polie. Cet examen nous a permis de mettre en evidence une diffusion intergranulaire au-dessous de 650 deg. C; aux temperatures superieures, la diffusion a lieu uniquement en volume, et la zone de diffusion apparait alors comme une succession de bandes qui se distinguent par leur aspect micrographique. L'etude de la cinetique de croissance de ces bandes nous a permis de mesurer les 'coefficients de penetration' correspondants. En outre, nous avons observe, dans la zone de diffusion, des variations importantes de microdurete, que nous avons cherche a relier a la variation de concentration. Celle-ci est mesuree par analyse ponctuelle au moyen de la microsonde de Castaing. Nous avons ainsi etabli avec precision les courbes concentration-penetration pour des temperatures comprises entre 950 et 1075 deg. C. A partir de ces courbes nous avons calcule le coefficient de diffusion D en fonction de la concentration c par la methode de Matano. La coube D(c) presente a toutes les temperatures une forme en U, deja observee pour le systeme U-Zr. L'energie d'activation passe par un maximum de 42 kcal/g pour une concentration atomique 0,5. Bien que nous n'ayons observe que rarement la presence de pores dans la zone de diffusion, nous avons neanmoins observe un effet Kirkendall important en etudiant les deplacements x{sub i} d'un interface repere au moyen de fils de tungstene. Ces deplacements peuvent s'exprimer en fonction du temps t et de la temperature T par la relation x{sub i} = 0,9 t {sup 1/2} exp ( - 14600/(RT)). Enfin, au moyen des equations de Darken nous avons calcule

  17. Study of workplace: concept and practical application; Etude de postes de travail: le concept et sa traduction en pratique

    Energy Technology Data Exchange (ETDEWEB)

    Varin, J.C.; Casanova, P.; Benjamin, P.; Rey, M. [COGEMA La Hague, 50 - Beaumont Hague (France)

    2006-04-15

    The order in council published in March 2003 deals with the radiation protection of workers. It completes the French regulation of risks prevention. In this text appears a new item called 'study of workplace'. This new concept does not deal only with radiation risks: in a risks management organization, this concept must be a complementary disposition of the existing procedures. In the La Hague plant, a risks management policy has been developed for many years in respect with OHSAS 18001 referential. This risks management system involves all the departments which work in the risks prevention field: safety department, radiation protection department, health department. Many procedures and quality assurance tools have been crated which comply with the concept of 'work place study'. (author)

  18. Development of a method for studying non-linear phenomena in plasma; Mise au point d'une methode d'etude des phenomenes non lineaires dans un plasma

    Energy Technology Data Exchange (ETDEWEB)

    Gonfalone, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-03-01

    gaz d'electrons est a la base des meilleures methodes de mesure des frequences de collisions electroniques dans l'ionosphere. Dans les plasmas de laboratoire l'apparition de ces phenomenes est liee a un champ critique de valeur elevee. Tout en n'utilisant qu'une source electromagnetique de puissance relativement faible, nous avons mis au point une methode hyperfrequence simple qui permet de mettre ces phenomenes en evidence, de les mesurer et d'en donner une interpretation elementaire. Une onde electromagnetique, fournie par un klystron de 1 W de puissance, interagit avec une decharge HF (25 MHz) dans le volume d'une cavite TE{sub 111}. Le tube contenant la decharge et l'axe de la cavite cylindrique sont colineaires a un champ magnetique pouvant atteindre une valeur telle que la frequence de l'onde soit egale a la frequence gyromagnetique des electrons. La courbe de resonance de la cavite, qui depend de la densite electronique et de la frequence des collisions, devient d'autant plus dissymetrique que la puissance absorbee est grande et que la frequence gyromagnetique des electrons est voisine de la frequence de l'onde incidente. L'etude de la resonance permet de calculer les coefficients de proportionnalite qui relient les variations de la densite et de la frequence de collisions a la puissance absorbee. Les experiences ont ete faites en faisant varier separement: la puissance UHF incidente, la densite electronique initiale, la pression du gaz neutre ambiant, ainsi que le champ magnetique axial. La variation de la densite electronique en fonction du champ magnetique pour une puissance UHF forte, montre une resonance de forme dissymetrique avec quelquefois un pic aigu, au voisinage de {omega}{sub H}. L'application eventuelle des proprietes mises en evidence a la realisation de dispositifs pratiques est envisagee. (auteur)

  19. Study of superconductors with high critical temperature by using the vibrating blade technique: anelastic properties, vortices dynamics; Etude des supraconducteurs a haute temperature critique par la technique de la lame vibrante: - proprietes anelastiques, - dynamique des vortex

    Energy Technology Data Exchange (ETDEWEB)

    De Brion, Sophie

    1991-10-04

    This research thesis reports the application of the vibrating blade technique to the study of high critical temperature superconductors, first for the anelastic properties, and then for vortices dynamics. As far as the study of anelastic properties is concerned, the author reports the measurement of dissipation and of Young modulus, between 4 K and 300 K and at about 1 khz, in YbaCuO ceramics with various oxygen content. A detailed study of the tetragonal phase reveals the existence of a single relaxation process, the magnitude of which depends on the compound oxygen content and on its thermal treatment. In the second part, the author reports the measurement, under magnetic field and within a temperature range lower than the superconducting critical temperature, of a YbaCuO crystal with two different oxygen concentrations. At low temperature, the author studies the contribution of vortices trapped in an irreversible state. At high temperature, this contribution disappears and thus defines an irreversibility line beyond which vortices are in a reversible regime. This line is studied for different magnetic field orientations with respect to CuO planes. It is interpreted in terms of de-trapping thermally activated by vortices [French] La technique de la lame vibrante a ete appliquee a l'etude des supraconducteurs a haute temperature critique, pour leurs proprietes anelastiques d'abord, pour la dynamique des vortex ensuite. Dans la gamme de temperature 4 K - 300 K, nous avons mesure la dissipation et le module d'Young, a une frequence de 1 kHz environ, dans des ceramiques YBaCuO (phase 123) de differentes teneurs en oxygene (variant de O{sub 6} a O{sub 7}). Nous avons observe plusieurs pics de dissipation. Une etude detaillee de la phase tetragonale (de O{sub 6} a O{sub 6,4}) a mis en evidence un seul processus de relaxation, active thermiquement avec une energie de 0,1 eV et dont l'ampleur depend de la teneur en oxygene du compose et de son traitement thermique. Cette

  20. A study of the fluorescence of the rare gases excited by nuclear particles. Use of the principle for the detection of nuclear radiation by scintillation; Etude de la fluorescence des gaz rares excites par des particules nucleaires. Utilisation pour la detection des rayonnements nucleaires par scintillation

    Energy Technology Data Exchange (ETDEWEB)

    Koch, L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1959-12-15

    In the first part is studied the properties of atoms excited by the passage of {alpha} particles through the various rare gases at atmospheric pressure. A spectral analysis of the emitted light showed that certain impurities play an important part in producing the fluorescence, and it has led to the conclusion that the light emission contains at least two components - one very short - lived due to the direct deexcitation of the rare gas, the other relatively slower due to the energy transfers to the impurity. The measurement of the life-time of the excited states has confirmed this foregoing hypothesis, the rapid part of the impulse is extremely short: less than 2,25.10{sup -9} s in the case of xenon; the slower part has a life-time depending directly on the nitrogen concentration, nitrogen being the impurity giving the largest effect in all cases. The study of rare gases under the influence of an electric field has made it possible to show that the amount of light produced by an {alpha} particle can be multiplied (by 60, for example, in a field of 600 V:cm) so that the luminescent efficiency is greater than in the case of INaTI. In the second part the characteristics of the rare gases acting as scintillators is examined, the most important property being the absence of fluorescence saturation when the intensity of the excitation incident on the gas is very large. This, together with the very short time of scintillation has made it possible to study a certain number of nuclear physical applications (heavy particle energy-measurements, kinetic studies on nuclear reactors, neutron spectroscopy). (author) [French] On etudie dans la premiere partie les proprietes des atomes excites par le passage de particules {alpha} dans les differents gaz rares a la pression atmospherique. L'etude spectrale de la lumiere emise a montre que certaines impuretes jouent un role considerable dans la fluorescence et on a ete amene a penser que l'emission de lumiere comporte au moins deux

  1. Reduction of uranium and plutonium oxides by aluminum. Application to the recycling of plutonium; Reduction des oxydes d'uranium et de plutonium par l'aluminium application au recyclage du plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Gallay, J [Commissariat a l' Energie Atomique, Valduc (France). Centre d' Etudes

    1968-07-01

    A process for treating plutonium oxide calcined at high temperatures (1000 to 2000 deg. C) with a view to recovering the metal consists in the reduction of this oxide dissolved in a mixture of aluminium, sodium and calcium fluorides by aluminium at about 1180 deg. C. The first part of the report presents the results of reduction tests carried out on the uranium oxides UO{sub 2} and U{sub 3}O{sub 8}; these are in agreement with the thermodynamic calculations of the exchange reaction at equilibrium. The second part describes the application of this method to plutonium oxides. The Pu-Al alloy obtained (60 per cent Pu) is then recycled in an aqueous medium. (author) [French] Un procede de traitement de l'oxyde de plutonium calcine a haute temperature (1000 deg. C a 2000 deg. C), en vue de la recuperation du metal, consiste a reduire cet oxyde dissous dans un melange de fluorures d'aluminium, de sodium et de calcium, par l'aluminium vers 1180 deg. C. Une premiere partie du rapport presente les resultats des essais de reduction des oxydes d'uranium UO{sub 2} et U{sub 3}O{sub 8}, en accord avec les resultats du calcul thermodynamique de la reaction d'echange a l'equilibre. Une seconde partie rend compte de l'application de cette methode a l'oxyde de plutonium. L'alliage Pu-Al obtenu (60 pour cent Pu) est ensuite recycle par voie aqueuse. (auteur)

  2. Castor and Pollux - shielded cells for studying fuel treatment processes; Castor et Pollux chaines blindees d'etudes de procedes de traitement de combustibles

    Energy Technology Data Exchange (ETDEWEB)

    Faudot, G; Bathellier, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    CASTOR and POLLUX, two alpha, beta, gamma cells are described in the present paper. They are located in the CEN at Fontenay-aux-Roses (France). They are designed for improvement studies of the various aqueous separation processes used in irradiated fuels reprocessing plants. Located in the same air-tight steel encasement, they arc inter-connected by a pneumatic transfer. These two cells have a similar in-line conception and they include: a gamma shielding in lead of 10 cm of thickness; an inner air-tight box, made with stainless steel and plexiglas, is maintained in lowering in comparison to room pressure. Eleven Hobson model seven master-slave manipulators allow inner manipulations. Then the inner equipment is described briefly. (author) [French] Le present document decrit les cellules alpha, beta, gamma CASTOR et POLLUX edifiees au Centre d'Etudes Nucleaires de Fontenay-aux-Roses. Elles sont destinees aux etudes visant a l'amelioration des procedes de separation par voie aqueuse utilises dans les usines de retraitement des combustibles irradies. Ces deux chaines, implantees dans le meme caisson et reliees par convoyeur pneumatique, sont de conception identique et comprennent: une protection biologique constituee par 10 cm d'epaisseur de plomb; une enceinte interieure etanche alpha, en acier inoxidable et plexiglas, maintenue en depression. Des telemanipulateurs Hobson, modele 7, permettent les manipulations interieures. On decrit ensuite brievement les installations annexes. (auteur)

  3. Study of point defects in pure iron by means of electrical resistivity; Etude au moyen de la resistivite electrique des defauts ponctuels dans le fer pur

    Energy Technology Data Exchange (ETDEWEB)

    Minier-Cassayre, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-04-01

    In the first part of this work, after having reviewed the production, observation and the annealing of point defects In metals, we resume the present state of research. In the second part, we explain the techniques we have employed to produce point defects at low temperatures: irradiation, quenching and cold-work; and go on to the study of their migration and annealing. The experimental results obtained for pure iron and for iron containing certain impurities are presented in the third part. In the fourth part we suggest a model which explains the different stages of annealing observed, and their properties. We then compare the energies of interaction between point defects with the values deduced from the theory of elasticity. (author) [French] Dans la premiere partie de cette etude, apres avoir passe en revue la production, l'observation et les modes de guerison des defauts ponctuels dans les metaux, nous exposons l'etat actuel des recherches. La seconde partie est consacree aux techniques que nous avons employees pour produire des defauts ponctuels a basse temperature: irradiations, trempe et ecrouissage puis a l'etude de leur migration et de leur guerison. Les resultats experimentaux obtenus dans le fer pur et le fer contenant certaines impuretes sont presentes dans le troisieme chapitre. Nous proposons ensuite un modele qui explique les differents stades de guerison observes et leurs nombreuses proprietes: nous comparons les energies d'interaction entre defauts ponctuels aux valeurs que l'on pourrait deduire d'un modele elastique. (auteur)

  4. The ultrasonic copper and brass decontamination study; Etude de la decontamination du cuivre et des laitons en presence d'ultra-sons

    Energy Technology Data Exchange (ETDEWEB)

    Courtault, J; Kerdelleau, J de; Mestre, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The use of ultra-sounds as a decontamination technic does not bring an absolute solution. As a function of the materials it seemed necessary to find what was the optimum conditions for using the ultra-sounds and to define not only the ultra-sonic factors but also the chemical solutions which bring some appreciable decontamination factors without bringing any too important corrosion processus. This report gives the results of this study applied to copper and brass. This study allowed to select some effective treatment baths on the two types of contamination: plutonium and fission products. (authors) [French] L'emploi des ultra-sons comme technique de decontamination n'amene pas une solution absolue. Il est apparu necessaire de rechercher en fonction de la nature du materiau a decontaminer quelles etaient les conditions optimales d'utilisation des ultra-sons et de definir alors non seulement les facteurs ultrasoniques mais encore les solutions chimiques qui apportent des facteurs de decontamination appreciables sans amener des phenomenes de corrosion trop importants. Ce rapport donne les resultats de cette etude appliquee au cuivre et aux laitons. Cette etude a permis de selectionner des bains de traitement efficaces dans les deux cas de contamination: plutonium et produits de fission. (auteurs)

  5. A crystallographic and spectroscopic study of crystal sites in the 'spinel' structure; Etude cristallographique et spectroscopique des sites cristallins dans la structure 'spinelle'

    Energy Technology Data Exchange (ETDEWEB)

    Drifford, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    A crystallographic study on magnesium aluminates led to the determination of crystal site average distortion. A spectroscopic study of transition elements doped spinels gave the position of the doping element in tetrahedral (A) or octahedral (B) sites, and the local distortion of the latter. The comparison of average and local parameters points to differences in the behaviour of doping elements and shows the size of (A) sites are independent of the host crystal composition while the average size of (B) sites varies with the composition. (author) [French] Une etude cristallographique des aluminates de magnesium a permis de determiner la deformation moyenne des sites cristallins. Une etude spectroscopique des aluminates de magnesium dopes avec des elements de transition a permis de localiser les dopants entre les sites tetraedriques (A) et octaedriques (B) et d'etudier la deformation locale de ces sites. La comparaison entre les parametres moyens et locaux a caracterise le comportement du dopant et montre que les dimensions des sites (A) sont independantes de la composition de la matrice, alors que les caracteristiques geometriques moyennes des sites (B) varient continument avec la composition. (auteur)

  6. Contribution to the study of hydrogenated and oxygenated impurities in liquid sodium; Contribution a l'etude des impuretees hydrogenees et oxygenees dans le sodium liquide

    Energy Technology Data Exchange (ETDEWEB)

    Naud, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-15

    This study is made up essentially of two parts. The first is devoted to the development of dosage methods for selectively determining the oxygenated and hydrogenated impurities present in sodium, that is the oxide, the hydride and the hydroxide. The second makes use of these methods for a study of the Na-H{sub 2}-O{sub 2} system, as well as of the related problem of the attack of pyrex glass by molten sodium. The conventional method for dosing oxygen by amalgamation was first adapted to the simultaneous measurement of the hydride. We then developed a method for dosing the total hydrogen by measuring successively the concentrations of gas present in the hydride and hydroxide form. This method is based on the thermal decomposition of the hydride and the reaction between sodium and the hydroxide. Our contribution to the study of the Na-H{sub 2}-O{sub 2} System consists first of all in the study of the reaction between hydrogen and sodium in the temperature range from 150 to 250 deg C and at a pressure of about 150 mm of mercury. The study of the thermal decomposition of the hydride in sodium was then studied. It was possible to make some qualitative observations concerning the reaction between sodium and sodium hydroxide. Finally some complementary tests made it possible to define the nature of the phenomena occurring during the attack of pyrex glass by sodium. (author) [French] Cette etude comporte essentiellement deux parties. La premiere est consacree a la mise au point de methodes de dosages permettant de determiner selectivement les impuretes oxygenees et hydrogenees presentes dans le sodium, a savoir l'oxyde, l'hydrure et l'hydroxyde. La seconde met a profit ces methodes en vue de l'etude du systeme Na-H{sub 2}-O{sub 2}. ainsi que du phenomene connexe d'attaque du verre pyrex par le sodium fondu. La methode classique de dosage de l'oxygene par amalgamation a d'abord ete adaptee au dosage simultane de l'hydrure. Nous avons ensuite mis au point le dosage de l

  7. Inventory of natural emissions in the Mediterranean region: application to the establishment of detailed cadastral surveys of the Marseille-Berre area in the framework of the Escompte project. On-site determination of emission factors specific of the studied area; Inventaire des emissions naturelles en region mediterraneenne: application a l'etablissement de cadastres detailles de la zone Marseille-Berre dans le cadre du projet Escompte. Determination sur site de facteurs d'emission specifiques a la zone d'etude

    Energy Technology Data Exchange (ETDEWEB)

    Dumergues, L.

    2003-12-01

    The natural emissions, which gather Volatile Organic compounds (VOC) as well as nitrogen and sulphur compounds, take part in the physico-chemistry of the atmosphere. Qualitative and quantitative knowledge such emissions are essential to understand phenomena of pollution such as the tropospheric ozone formation. The work carried out in the frame of the ESCOMPTE project, provide a series of results as for example: - the inventory of the main natural sources of organic and inorganic compounds in a Mediterranean zone and the development of suitable algorithms of emission for each sources. - the daily and annual estimate of the natural emissions in the Marseille area by application of mathematical models. - the validation of the results and the sensitivity of algorithmic factors of one of the most important biotic sources: the forest. - the determination, during campaigns on Mediterranean sites, of rates and flows of terpenic emission of Quercus pubescens, Pinus halepensis and garrigue from the Cuvette and the aerodynamic gradient method. (author)

  8. A study of internal contamination levels resulting from {sup 90}Sr and {sup 137}Cs environmental pollution. The influence of different factors; Etude des niveaux de contamination interne resultant d'une pollution de l'environnement par le {sup 90}Sr et le {sup 137}Cs influence des differents parametres

    Energy Technology Data Exchange (ETDEWEB)

    Garnier, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1970-07-01

    This study includes two parts. The purpose of the former one is to try and evaluate the amounts of {sup 90}Sr and {sup 137}Cs dietary intakes as a function of age with a view to assessing internal exposure doses and estimating the critical age, and to study the relative significance of the several factors it depends on. The data used are both the results of dietary surveys made in 11 districts of the European community from which the evolution of the consumed amounts of 13 groups of foodstuffs, as a function of age was derived, and the mean factors of contamination pathways. The variability of some factors is very large and an attempt is made to assess their significance on the whole contamination; also, the influence of the various diets has been emphasized. The purpose of the second part is to assess, doses as a function of age in the case of protracted exposure on the basis of the aforesaid results and radiobiological factors derived from bibliographic states of the arts. An assessment is made of body burdens and mean doses (either to the skeleton or the whole body according to the radionuclides) originating either from a direct unitary exposure or from situations implying both modes of exposure. As assumed only the diets vary with the districts, thus the results reflect their significance which should be corrected, for a more accurate assessment of the dose variability, by the significance of human and transfer factors. (author) [French] Cette etude comprend deux parties. L'objet de la premiere partie est a la fois un essai d'evaluation en fonction de l'age des quantites de strontium 90 et de cesium 137 ingerees avec les aliments dans la perspective d'une application a l'estimation des doses d'irradiation interne et a la recherche de l'age critique, et une etude de l'influence relative des divers parametres dont elle depend. Les donnees utilisees sont, d'une part, les resultats des enquetes alimentaires faites en onze regions de la Communaute Europeenne dont on

  9. A study of internal contamination levels resulting from {sup 90}Sr and {sup 137}Cs environmental pollution. The influence of different factors; Etude des niveaux de contamination interne resultant d'une pollution de l'environnement par le {sup 90}Sr et le {sup 137}Cs influence des differents parametres

    Energy Technology Data Exchange (ETDEWEB)

    Garnier, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1970-07-01

    This study includes two parts. The purpose of the former one is to try and evaluate the amounts of {sup 90}Sr and {sup 137}Cs dietary intakes as a function of age with a view to assessing internal exposure doses and estimating the critical age, and to study the relative significance of the several factors it depends on. The data used are both the results of dietary surveys made in 11 districts of the European community from which the evolution of the consumed amounts of 13 groups of foodstuffs, as a function of age was derived, and the mean factors of contamination pathways. The variability of some factors is very large and an attempt is made to assess their significance on the whole contamination; also, the influence of the various diets has been emphasized. The purpose of the second part is to assess, doses as a function of age in the case of protracted exposure on the basis of the aforesaid results and radiobiological factors derived from bibliographic states of the arts. An assessment is made of body burdens and mean doses (either to the skeleton or the whole body according to the radionuclides) originating either from a direct unitary exposure or from situations implying both modes of exposure. As assumed only the diets vary with the districts, thus the results reflect their significance which should be corrected, for a more accurate assessment of the dose variability, by the significance of human and transfer factors. (author) [French] Cette etude comprend deux parties. L'objet de la premiere partie est a la fois un essai d'evaluation en fonction de l'age des quantites de strontium 90 et de cesium 137 ingerees avec les aliments dans la perspective d'une application a l'estimation des doses d'irradiation interne et a la recherche de l'age critique, et une etude de l'influence relative des divers parametres dont elle depend. Les donnees utilisees sont, d'une part, les resultats des enquetes alimentaires faites en

  10. Composes inter-halogenes sous pression: etude des transformations structurales dans le monobromure d'iode sous forme dense

    Science.gov (United States)

    Bouchard, Alexandre

    La famille des composes halogenes et inter-halogenes representent des solides moleculaires adoptant des phases denses communes avec des solides moleculaires diatomiques comme l'azote et l'hydrogene. Parmi les transformations structurales et electroniques induites sous haute pression et observees dans ces solides, on note, entre autres, la dissociation moleculaire et la metallisation. De plus, l'etude des phases denses de l'iode a permis recemment l'observation d'une structure cristalline possedant une modulation dite incommensurable, c'est-a-dire une modulation possedant une periodicite differente de celle de la structure cristalline, jetant ainsi une lumiere nouvelle sur le processus de dissociation moleculaire dans les solides halogenes. Dans ce memoire, on propose d'etudier les changements structuraux dans monobromure d'iode (IBr), un compose inter-halogene possedant des proprietes structurales semblables a celles de deux composes halogenes, soit l'iode (I 2) et le brome (Br2) sous leur forme solide. Des experiences de diffraction des rayons X de poudres en utilisant un rayonnement synchrotron ont ete realisees a temperature ambiante sur l'IBr en variant la pression jusqu'aux environs de 60 GPa. La nature chimique particuliere du compose IBr a necessite la mise au point de techniques de chargement d'echantillon destinees a preserver l'integrite chimique de la substance utilisee. On rapporte egalement l'observation d'une phase de l'IBr presentant une modulation incommensurable. Les phases observees dans l'IBr permettent d'etablir des paralleles avec les phases denses rapportees dans I2 et Br2 par le biais d'un modele phenomenologique decrivant la sequence structurale des solides halogenes sous forme condensee.

  11. Comparative study of thyroid fixation of different iodine compounds; Etude comparative de la fixation thyroidienne de differents composes iodes

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi, R; Coeur, A; Raynfeld, Ch [Commissariat a l' Energie Atomique, Grenoble (France).Centre d' Etudes Nucleaires

    1961-07-01

    The aim of this work is to study the thyroid fixation of various iodine compounds in mineral or organic form. The animals (rats) are given therapeutic doses of the derivative orally with the object of saturating the thyroid, and then receive a determined dose of radio-iodine 131 by intra-peritoneal injection; any fixation of this latter is then measured under anaesthetic by means of a scintillation counter. Whatever form of iodine derivative was used whether in ionic (potassium iodide type) or organic form (iodo-tannic syrup) or in the form of elementary iodine (iodinated water), thyroid saturation was always obtained, as shown by practically zero fixation of the 4 {mu}curies of iodine 131 administered by intra-peritoneal injection. (author) [French] Notre travail a pour but l'etude de la fixation thyroidienne de differents composes iodes sous forme minerale ou organique. Les animaux (rats), apres absorption orale de doses therapeutiques de derives destines a saturer leur thyroide recoivent par voie intra-peritoneale une dose determinee de radio-iode {sup 131}I, la fixation eventuelle de ce dernier est ensuite mesuree sous anesthesie en utilisant un compteur a scintillation. Quelle que soit la forme utilisee, c'est-a-dire derive iode sous forme ionique (type iodure de potassium) ou sous forme organique (sirop iodotanique) ou encore sous forme d'iode metalloidique (eau iodee), nous avons obtenu chaque fois une saturation thyroidienne mise en evidence par une fixation pratiquement nulle des 4 {mu}curies de l'iode 131 injectes par voie intraperitoneale. (auteur)

  12. Systematic study of plasma and serum proteins in the pig; Etude systematique des proteines plasmatiques et seriques du porc

    Energy Technology Data Exchange (ETDEWEB)

    Daburon, F; Nizza, P; Hatchikian, C; Schmidt, J -P [Commissariat a l' Energie Atomique (France)

    1966-07-01

    This work has been carried out in the framework of the determination of the physiological constants of a normal pig. The aim was to study the serum and plasma proteins of this animal species, the ultimate object being to discover whether the qualitative and quantitative changes in these proteins can make a significant contribution to the establishment of a biological dosimetry for irradiated pigs. The serum and plasma from a normal pig were analyzed first by various simple electrophoretic methods and then by immuno-electrophoresis. As a result of the particular characteristics of pig serum we have gradually been led to make numerous modifications to the techniques used for human serums or for those of small laboratory animals. Much careful work and patience were required in order to obtain reproducible results. (authors) [French] Ce travail se situe dans le cadre de la determination des constantes physiologiques du porc normal. il s'agissait de proceder a l'etude des proteines seriques et plasmatiques de cette espece animale, le but ulterieur etant de savoir si les modifications qualitatives et quantitatives de ces proteines pourront representer une contribution valable a l'etablissement d'une dosimetrie biologique chez le porc irradie. Le serum et le plasma du porc normal ont ete analyses d'abord par diverses methodes electrophoretiques simples puis par immunoelectrophorese. Les caracteristiques particulieres du serum de porc nous ont conduits a apporter progressivement de nombreuses modifications aux techniques utilisees pour des serums humains ou de petits animaux de laboratoire. L'obtention de resultats reproductible a exige beaucoup de patience et de minutie. (auteurs)

  13. Study of free acidity determinations in aqueous solution; Etude des dosages d'acidite libre en solution aqueuse

    Energy Technology Data Exchange (ETDEWEB)

    Kergreis, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-04-01

    The object of this work is the study of the principal methods which can be applied to the measurement of 'free' acidity. In the first part, we define the various types of acidity which can exist in aqueous solution; then, after having studied some hydrolysis reactions, we compare the value of the neutralisation pH of the hydrated cation and that of the precipitation of the hydroxide. In the second part we have started to study the determination of the acidity of an aqueous solution. After having rapidly considered the 'total' acidity determination, we deal with the problem of the 'free' acidity titration. We have considered in particular certain methods: extrapolation of the equivalent point, colorimetric titrations with or without a complexing agent, and finally the use of ion-exchange resins with mixed aqueous and solvent solutions. (author) [French] Le but de ce travail est l'etude des principales methodes de determination de l'acidite 'libre'. Dans une premiere partie nous avons defini les differentes sortes d'acidites pouvant exister en solution aqueuse, puis apres avoir etudie quelques reactions d'hydrolyse, nous avons compare la valeur de pH de neutralisation du cation hydrate et celle de precipitation de l'hydroxyde. Dans la seconde partie nous avons aborde l'etuce des dosages de l'acidite d'une solution aqueuse. Apres avoir envisage assez rapidement la determination de l'acidite 'totale', nous traitons du probleme du titrage de l'acidite 'libre'. Nous avons porte notre attention sur certaines methodes: extrapolation du point equivalent, titrimetrie colorimetrique avec ou sans complexant, et enfin utilisation des resines echangeuses d'ions en milieu aqueux et solvant mixte.

  14. Study of superconducting Nb{sub 3}Sn coils; Etude de bobinages supraconducteurs en Nb{sub 3}Sn

    Energy Technology Data Exchange (ETDEWEB)

    Vivet, B

    1963-07-01

    Composite superconducting Nb{sub 3}Sn wires with a diameter of 0.5 mm and a length of about 100 m were made, and Hc-Ic diagrams were plotted up to fields of 80 kgauss for short lengths. Two solenoids producing fields of about 20 kgauss were studied. Nb{sub 3}Sn solenoids, as opposed to those of Nb-Zr or Nb-Ti, appear to have a predictable behavior. Solenoids with less insulation produced stronger fields than heavily insulated solenoids. (author) [French] Une etude des fils composites supraconducteurs de Nb{sub 3}Sn a ete entreprise au C.E.N. Saclay, en collaboration avec la Societe S.O.D.E.R.X. Des fils de 0,5 mm de diametre et d'une centaine de metres de longueur ont ete produits de facon experimentale. Des diagrammes Hc-Ic ont pu etre traces, jusqu'en des champs de 80 kG, sur des echantillons de petite longueur. Deux solenoides ont ete etudies produisant les champs de l'ordre de 20 kg. Il semble que, contrairement aux alliages Nb-Zr ou Nb-Ti, les solenoides en Nb{sub 3}Sn aient un comportement previsible d'apres les tests sur des echantillons courts. On montrera d'autre part qu'un bobinage a faible isolement peut produire un champ notablement plus eleve qu'un bobinage isole. Une production plus extensive permettra, dans les semaines a venir, la fabrication de solenoides de plus grosse dimension et produisant des champs plus eleves. (auteur)

  15. Systematic study of plasma and serum proteins in the pig; Etude systematique des proteines plasmatiques et seriques du porc

    Energy Technology Data Exchange (ETDEWEB)

    Daburon, F.; Nizza, P.; Hatchikian, C.; Schmidt, J.-P. [Commissariat a l' Energie Atomique (France)

    1966-07-01

    This work has been carried out in the framework of the determination of the physiological constants of a normal pig. The aim was to study the serum and plasma proteins of this animal species, the ultimate object being to discover whether the qualitative and quantitative changes in these proteins can make a significant contribution to the establishment of a biological dosimetry for irradiated pigs. The serum and plasma from a normal pig were analyzed first by various simple electrophoretic methods and then by immuno-electrophoresis. As a result of the particular characteristics of pig serum we have gradually been led to make numerous modifications to the techniques used for human serums or for those of small laboratory animals. Much careful work and patience were required in order to obtain reproducible results. (authors) [French] Ce travail se situe dans le cadre de la determination des constantes physiologiques du porc normal. il s'agissait de proceder a l'etude des proteines seriques et plasmatiques de cette espece animale, le but ulterieur etant de savoir si les modifications qualitatives et quantitatives de ces proteines pourront representer une contribution valable a l'etablissement d'une dosimetrie biologique chez le porc irradie. Le serum et le plasma du porc normal ont ete analyses d'abord par diverses methodes electrophoretiques simples puis par immunoelectrophorese. Les caracteristiques particulieres du serum de porc nous ont conduits a apporter progressivement de nombreuses modifications aux techniques utilisees pour des serums humains ou de petits animaux de laboratoire. L'obtention de resultats reproductible a exige beaucoup de patience et de minutie. (auteurs)

  16. Recent research on the pharmaceutical checking of radioelements (1961); Etudes recentes sur le controle pharmaceutique des radioelements (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, Y; Ingrand, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Checking on radioactive preparations for medical use is complicated by difficulties due to the radioactivity, the instability and the methods of using these solutions. In effect it is necessary, in order to draw up a practicable set of rules governing such checks, to know both the method of preparation and the properties of the radioelement, as well as special and often contradictory features of its use. These tests fall into three categories: physical, chemical and biological. Preparations of chromium 51, iron 59 and arsenic 76 have been dealt with in recent studies. In each case special tests were necessary, and these will be described in this paper. The practice of these tests is of twofold interest: firstly they provide a maximum guarantee to the user, and secondly they guide the chemist in his manipulations, immediately and thoroughly. (author) [French] Le controle des preparations radioactives a usage medical est complexe par suite des difficultees dues a la radioactivite, a l'instabilite et aux modalites d'utilisation de ces solutions. En effet, l'etablissement justifie d'un protocole de controle necessite la connaissance aussi bien du mode de preparation, que des proprietes du radioelement et des particularites parfois contradictoires de son emploi. Ces controles sont de trois ordres physiques, chimiques, biologiques. Des etudes recentes ont porte sur des preparations de chrome 51, de fer 59, d'arsenic 76. Dans chaque cas, il est apparu necessaire de pratiquer des controles particuliers qui seront exposes dans la communication. La pratique de ces derniers presente un double interet; d'une part, ils assurent a l'utilisateur un maximum de garantie, d'autre part, ils orientent le chimiste dans ses mises au point, immediatement et de facon approfondie. (auteur)

  17. Study of the stopping power of various filters; Etude du pouvoir d'arret de differents filtres

    Energy Technology Data Exchange (ETDEWEB)

    Madelaine, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The first part is devoted to a study of aerosols obtained from the combustion of various smoke-producing compounds. A trial aerosol of which the size distribution is the closest possible to that of atmospheric dusts has been defined. The efficiency of various filters has been determined for successive increments of the dimensions and not for the whole range of its diameter distribution. The variation in the efficiency of the filtering layers as a function of the filtering speed and particle size has been studied for aerosols having particle diameters of over 0.3 {mu}. The second part describes an original method for measuring the efficiency of filters for ultra-fine particles (under 0.1 {mu}) using the fixation properties of radioactive atoms resulting from the decay of thoron. (author) [French] La premiere partie est consacree a l'etude des aerosols obtenus a partir de la combustion de divers types de fumigenes. Un aerosol d'essai, dont la repartition granulometrique se rapproche le plus possible des poussieres atmospheriques a ete defini. L'efficacite de plusieurs filtres a ete determinee pour des tranches successives de dimension et non pour l'aerosol pris dans sa totalite. La variation de l'efficacite des couches filtrantes en fonction de la taille des particules et de la vitesse de filtration a ete examinee pour des aerosols superieurs a 0,3 {mu}. La seconde partie decrit une methode originale permettant de mesurer l'efficacite des filtres pour des particules ultrafines (inferieures a 0,1 {mu}) en utilisant la propriete de fixation des atomes radioactifs des descendants du thoron. (auteur)

  18. Contribution to the study of alpha-alpha interaction; Contribution a l'etude de l'interaction alpha - alpha

    Energy Technology Data Exchange (ETDEWEB)

    Darriulai, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-03-01

    Two sets of measurements of the {alpha}-{alpha} elastic scattering differential cross section are presented. The first set - angular distributions from 50 up to 120 MeV - shows two new resonances, 6{sup +} and 8{sup +}, at 25 and 57 MeV. Complex phase shifts are extracted from the data and a phenomenological potential is given. A description of the 3 {alpha}-particle 0{sup +} states in C{sup 12} is made with this interaction potential. The second set - excitation curves between 20 and 50 MeV - allows investigation of the Be{sup 8} level structure within this energy range - It identifies the 16.6 and 16.9 MeV states as 2{sup +}, but the rise of inelastic processes at higher energies makes further identification of spins and parities more and more difficult. (author) [French] Deux series de mesures de la section efficace differentielle de diffusion {alpha}-{alpha} sont presentees. La premiere - distributions angulaires entre 50 et 120 MeV - fait apparaitre deux nouvelles resonances, 6{sup +} et 8{sup +}, a 25 et 57 MeV d'excitation. Des dephasages complexes en sont extraits et un potentiel phenomenologique est presente. Une etude des etats 0{sup +} a parentage (3{alpha}) de {sup 12}C est faite a partir de ce potentiel. La seconde - courbes d'excitation s'etendant de 20 a 50 MeV - met en evidence la structure de {sup 8}Be dans cette region. Elle montre que les niveaux a 16,6 et 16,9 MeV sont des 2{sup +} mais l'importance des processus inelastiques rend difficile l'identification des niveaux d'excitation plus elevee. (auteur)

  19. Experiments on neutron-attenuation by ordinary concrete; Etude experimentale de l'attenuation des neutrons dans le beton ordinaire

    Energy Technology Data Exchange (ETDEWEB)

    Beauge, R; Millot, J P; Rastoin, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    The penetration of fission-neutrons in water and glass mixtures has been investigated in the NAIADE facility. The slopes of the thermal and fast fluxes (the latter measured with a dosimeter) remain similar when the volume proportion of water is greater than 15 per cent. For smaller water-contents the measurements show the evidence of streaming, presumably due to slowing-down neutrons of energy smaller than 300 keV. Since a volume proportion of about 15 per cent of water in glass corresponds to the composition of ordinary concrete, the present work enables to predict the effects of a desiccation of concrete. Moreover, it is seen that there is no interest in increasing the proportion of water in ordinary concrete beyond the usual values (15-20 per cent). (author) [French] La propagation des neutrons de fission a ete etudiee dans les melanges verre-eau au moyen du dispositif NAIADE. La pente du flux thermique et la pente du flux rapide (obtenue au moyen d'un dosimetre) restent voisines lorsque la proportion d'eau dans le melange depasse 15 pour cent en volume. Pour des proportions d'eau inferieures les mesures mettent en evidence un 'streaming' de neutrons en ralentissement d'energie probablement inferieure a 300 keV. La composition des melanges verre-eau aux environs de 15 pour cent d'eau en volume correspondant au beton ordinaire, la presente etude permet de prevoir les effets d'une dessication du beton, et montre, en outre, qu'il n'y a pas interet a essayer d'augmenter la proportion d'eau dans le beton ordinaire au dela des valeurs usuelles (15 a 20 pour cent). (auteur)

  20. Silicon P.I.N. Junctions used for studies of radiation damage; Etude de l'irradiation aux neutrons rapides du silicium au moyen de jonctions P.I.N

    Energy Technology Data Exchange (ETDEWEB)

    Lanore, J [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-06-01

    Irradiation of silicon P.I.N. junction has been studied primarily for the purpose of developing a radiation damage dosimeter, but also for the purpose of investigating silicon itself. It is known that the rate of recombination of electrons and holes is a linear function of defects introduced by neutron irradiation. Two methods have been used to measure that rate of recombination: forward characteristic measurements, recovery time measurements. In order to explain how these two parameters depend on recombination rate we have given a theory of the P.I.N. junction. We have also given an idea of the carrier lifetime dependence versus temperature. Annealing effects in the range of 70 to 700 K have also been studied, we found five annealing stages with corresponding activation energies. As an application for these studies, we developed a radiation damage dosimeter with which we made several experiments in facilities such as Naiade or Marias. (author) [French] L'irradiation de structures P.I.N. etait faite dans le but d'etudier principalement la mise au point d'un dosimetre a ''radiation damage'' et aussi pour etudier plus profondement le silicium lui-meme. On sait que le taux de recombinaison electrons-trous est une fonction lineaire du taux de defauts introduits par irradiation aux neutrons. Deux methodes ont ete utilisees pour atteindre ce taux de recombinaison: mesures de la caracteristique directe, mesures du temps de retournement. Pour expliquer de quelle facon ces parametres dependent du taux de recombinaison. Nous avons donne une theorie de la jonction P.I.N. Nous avons aussi donne l'allure des variations du temps de vie des porteurs en fonction de la temperature. Nous avons d'autre part effectue des recuits entre 70 et 700 K, domaine dans lequel nous avons trouve cinq etapes de ''guerison'' avec les energies d'activation correspondantes. En application de ces etudes nous avons mis ou point un dosimetre a ''radiation damage'' avec lequel nous avons effectue des

  1. Contribution to the study of U-Ti and U-Pu-Ti carbides; Contribution a l'etude des carbures U-C-Ti et (U, Pu) - C-Ti

    Energy Technology Data Exchange (ETDEWEB)

    Milet, C A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    After having discussed the reasons to use (U,Pu) carbides as fast reactor fuel, we examine the influence of the addition of titanium to these carbides. A preliminary study has been done on the system of U-C-Ti and some properties have been measured such as: density, thermal expansion, electrical resistivity, atmospheric corrosion and compatibility with stainless steel. The systems U-Pu-C-Ti (Pu/U + Pu equal to 15 per cent) and U-C-Ti have been found to be very similar. There exists a two phases region (U,Pu)C + TiC, an eutectic between (U,Pu)C and TiC for approximately 15 at %. The solubilities of U + Pu in TiC and of Ti in (U,Pu)C is less than 1 % at. The addition of titanium does not markedly change thermal expansion coefficients of (U,Pu)C. However the resistance to atmospheric corrosion and compatibility with stainless steel is improved. Thermal conductivity, calculated from electrical resistivity, has increased. On the other side, the density of fissile material is lowered. The combination of (U,Pu)C + TiC seems to be the most promising alloy for application as nuclear fuel. (author) [French] Apres avoir rappele les problemes poses par un combustible pour les reacteurs a neutrons rapides et l'interet des carbures U-Pu-C comme combustible, on examine l'influence de l'addition de titane dans ces carbures. Une etude preliminaire sur le systeme U-C-Ti a ete effectuee et quelques proprietes sont indiquees: densite, coefficients de dilatation, resistivite electrique, tenue a la corrosion atmospherique, compatibilite avec l'acier inoxydable. Le systeme U-Pu-C-Ti (Pu/U + Pu egal a 15 pour cent) presente de grandes analogies avec le systeme U-C-Ti. Il existe un domaine biphase (U,Pu)C + TiC, un eutectique entre (U,Pu)C et TiC pour environ 15 at % Ti; les solubilites de U + Pu clans TiC et de Ti dans (U,Pu)C sont inferieures a 1 at %. Par rapport a la phase (U,Pu)C, l'addition de titane est sans effets importants sur les coefficients de dilatation. Par contre la tenue a

  2. Silicon P.I.N. Junctions used for studies of radiation damage; Etude de l'irradiation aux neutrons rapides du silicium au moyen de jonctions P.I.N

    Energy Technology Data Exchange (ETDEWEB)

    Lanore, J. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-06-01

    Irradiation of silicon P.I.N. junction has been studied primarily for the purpose of developing a radiation damage dosimeter, but also for the purpose of investigating silicon itself. It is known that the rate of recombination of electrons and holes is a linear function of defects introduced by neutron irradiation. Two methods have been used to measure that rate of recombination: forward characteristic measurements, recovery time measurements. In order to explain how these two parameters depend on recombination rate we have given a theory of the P.I.N. junction. We have also given an idea of the carrier lifetime dependence versus temperature. Annealing effects in the range of 70 to 700 K have also been studied, we found five annealing stages with corresponding activation energies. As an application for these studies, we developed a radiation damage dosimeter with which we made several experiments in facilities such as Naiade or Marias. (author) [French] L'irradiation de structures P.I.N. etait faite dans le but d'etudier principalement la mise au point d'un dosimetre a ''radiation damage'' et aussi pour etudier plus profondement le silicium lui-meme. On sait que le taux de recombinaison electrons-trous est une fonction lineaire du taux de defauts introduits par irradiation aux neutrons. Deux methodes ont ete utilisees pour atteindre ce taux de recombinaison: mesures de la caracteristique directe, mesures du temps de retournement. Pour expliquer de quelle facon ces parametres dependent du taux de recombinaison. Nous avons donne une theorie de la jonction P.I.N. Nous avons aussi donne l'allure des variations du temps de vie des porteurs en fonction de la temperature. Nous avons d'autre part effectue des recuits entre 70 et 700 K, domaine dans lequel nous avons trouve cinq etapes de ''guerison'' avec les energies d'activation correspondantes. En application de ces etudes nous avons mis ou point un

  3. Study of the influence of the fast neutron spectrum on the production of defects in solids and liquids; Etude de l'influence du spectre des neutrons rapides sur la creation de defauts dans les solides et les liquides

    Energy Technology Data Exchange (ETDEWEB)

    Mas, P; Droulers, Y [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-07-01

    In the first part of this work a calculation has been made of the number of defects formed in graphite by a given neutron flux having various spectral distributions. The defect formation function is that of KINCHIN and PEASE; its formulation is briefly given. An efficiency function is then defined for a fast neutron spectrum. This defects produced in a light water reactor and those produced in a graphite reactor. Finally an application of this method is given for comparing the defect forming tendency in graphite in the case of the reactor Melusine and of the reactor G-2 and G-3. In the second part are calculated the integrals for the energy release brought about by fast neutrons in carbon oxygen and hydrogen. In a region of 25 cm around the core of a swimming-pool type reactor these energy release integrals are approximately proportional to the neutron flux above 1 MeV. The determination of the energy released as a result of the passage of neutrons in organic liquids can therefore be reduced to the measurement of the flux above 1 MeV for the real spectral distribution. A calorimetric verification has been carried out in the case of water. (authors) [French] Dans la premiere partie de cette etude, on a calcule le nombre de defauts crees dans le graphite par un flux de neutrons donne, pris sous differents spectres. On a ainsi fait les calculs pour 4 spectres de pile. piscine et 2 spectres de pile au graphite. La fonction creation de defauts est celle de KINCHIN et PEASE. On rappelle brievement sa formulation. Puis on definit une fonction efficacite d'un spectre de neutrons rapides. Cette fonction permet alors d'etablir la relation entre defauts crees dans une pile a eau legere et defauts crees dans une pile au graphite. Enfin, une application de cette methode est donnee pour comparer l'aptitude a creer les defauts dans le graphite par la pile MELUSINE et les piles G-2 ou G-3. Dans la deuxieme partie, on a calcule les integrales de degagement d'energie provoque par

  4. Study of beam-plasma interactions in the presence of a magnetic field; Etude d'interactions faisceau-plasma en la presence d'un champ magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Etievant, C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1963-12-15

    The instabilities developing in a 'beam-plasma' system and in a 'double-beam' system in the presence of a magnetic field are discussed theoretically starting from the conductivity tensor expression for a multi-beam system. Oblique propagation is taken into account and this leads to the introduction of certain instability mechanisms which would not appear in the case of a propagation which is purely parallel or perpendicular to the magnetic field. Two experiments are described: a) Study of the collision of two counterstreaming electron beams: An instability has been observed experimentally which leads to the generation of a stationary cyclotron wave having a frequency of {omega}{sub ce}/2. A description is given of the measurement of the interaction frequency, of the wavelength and of the build-up time of the wave. b) Study of a 'beam-plasma' system: A description is given of the measurement of the spectra of excited waves and of the perturbation of the beam velocity distribution at the plasma-exit. This perturbation is very pronounced when 'plasma-plasma' interaction appears in the system. A study into cyclotron oscillations produced in the plasma by excitation due to the passage of the beam is also described in this report. (author) [French] Les instabilites se developpant dans un systeme 'faisceau-plasma' et dans un systeme 'faisceau-faisceau' en la presence d'un champ magnetique sont discutees theoriquement a partir de l'expression du tenseur de conductivite d'un systeme multi-faisceaux. La propagation oblique est prise en consideration, ce qui introduit certains mecanismes d'instabilite qui n'apparaitraient pas pour une propagation purement parallele ou perpendiculaire au champ magnetique. Deux experiences sont decrites: a) Etude de la collision de deux faisceaux d'electrons: Une instabilite conduisant a la generation d'une onde cyclotronique stationnaire a la frequence {omega}{sub ce}/2 a ete observee experimentalement. Les mesures de la frequence d

  5. Reconstruction de la surface de Fermi dans l'etat normal d'un supraconducteur a haute Tc: Une etude du transport electrique en champ magnetique intense

    Science.gov (United States)

    Le Boeuf, David

    Des mesures de resistance longitudinale et de resistance de Hall en champ magnetique intense transverse (perpendiculaire aux plans CuO2) ont ete effectuees au sein de monocristaux de YBa2Cu3Oy (YBCO) demacles, ordonnes et de grande purete, afin d'etudier l'etat fondamental des supraconducteurs a haute Tc dans le regime sous-dope. Cette etude a ete realisee en fonction du dopage et de l'orientation du courant d'excitation J par rapport a l'axe orthorhombique b de la structure cristalline. Les mesures en champ magnetique intense revelent par suppression de la supraconductivite des oscillations magnetiques des resistances longitudinale et de Hall dans YBa2Cu 3O6.51 et YBa2Cu4O8. La conformite du comportement de ces oscillations quantiques au formalisme de Lifshitz-Kosevich, apporte la preuve de l'existence d'une surface de Fermi fermee a caractere quasi-2D, abritant des quasiparticules coherentes respectant la statistique de Fermi-Dirac, dans la phase pseudogap d'YBCO. La faible frequence des oscillations quantiques, combinee avec l'etude de la partie monotone de la resistance de Hall en fonction de la temperature indique que la surface de Fermi d'YBCO sous-dope comprend une petite poche de Fermi occupee par des porteurs de charge negative. Cette particularite de la surface de Fermi dans le regime sous-dope incompatible avec les calculs de structure de bande est en fort contraste avec la structure electronique presente dans le regime surdope. Cette observation implique ainsi l'existence d'un point critique quantique dans le diagramme de phase d'YBCO, au voisinage duquel la surface de Fermi doit subir une reconstruction induite par l'etablissement d'une brisure de la symetrie de translation du reseau cristallin sous-jacent. Enfin, l'etude en fonction du dopage de la resistance de Hall et de la resistance longitudinale en champ magnetique intense suggere qu'un ordre du type onde de densite (DW) est responsable de la reconstruction de la surface de Fermi. L'analogie de

  6. F{sup 19} relaxation in non-magnetic hexafluorides; Contribution a l'etude de la relaxation des fluors dans les hexafluorures non magnetiques

    Energy Technology Data Exchange (ETDEWEB)

    Rigny, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-12-01

    The interesting properties of the fluorine magnetic resonance in the hexafluorides of molybdenum, tungsten and uranium, are very much due to large anisotropies of the chemical shift tensors. In the solid phases these anisotropies, the values of which are deduced from line shape studies, allow one to show that the molecules undergo hindered rotations about the metal atom. The temperature and frequency dependence of the fluorine longitudinal relaxation times shows that the relaxation is due to the molecular motion. The dynamical parameters of this motion are then deduced from the complete study of the fluorine relaxation in the rotating frame. In the liquid phases, the existence of anisotropies allows an estimation of the different contributions to the relaxation. In particular, the frequency and temperature dependence of the relaxation shows it to be dominated by the spin-rotation interaction. We have shown that the strength of this interaction can be deduced from the chemical shifts, and the angle through which the molecule rotates quasi-freely can be determined. In the hexafluorides, this angle is roughly one radian at 70 C, and with the help of this value, the friction coefficients which describe the intermolecular interactions are discussed. (author) [French] Les proprietes de la resonance magnetique des fluors dans les hexafluorures de molybdene, tungstene et uranium sont influencees par l'existence de deplacements chimiques tres anisotropes. Dans les phases solides, la valeur de cette anisotropie peut etre determinee par l'analyse des formes de raies et son existence permet de montrer que les molecules sont en rotation empechee autour de leur atome central. L'etude du temps de relaxation longitudinal en fonction de la temperature et de la frequence montre que la relaxation est due aux mouvements moleculaires, aux plus hautes temperatures. Les proprietes dynamiques du mouvement sont obtenues par l'etude complete de la relaxation spin-reseau dans le referentiel

  7. New apparatus for discriminating shapes - application to the study of neutron-proton elastic scattering at 14.6 MeV; Nouveau dispositif de discrimination de formes - Application a l'etude de la diffusion elastique neutron-proton a 14,6 MeV; Novyj diskriminator po forme - primenenie k izucheniyu uprugogo rasseyaniya nejtronproton s 14,6 MeV; Nuevo dispositivo para discriminacion de formas - Aplicacion al estudio de la dispersion elastica neutron-proton a 14,6 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Crettez, J P; Cambou, F; Ambrosino, G [Laboratoire Maurice de Broglie, Paris (France)

    1962-04-15

    The mean life of scintillations in caesium iodide is dependent on the nature of the ionizing particle, the shortest life corresponding to the highest ionization density. This property is utilized for distinguishing different particles producing scintillations of similar amplitude. The apparatus described is a shape discriminator. It measures the time required by the scintillation to fall from its maximum to an adjustable fraction thereof. A time-amplitude converter provides a pulse the height of which is proportional to the time so measured. A comparison is then made between the shapes of the scintillations produced by alpha particles, protons and electrons, and the results obtained are shown. Application of this method to the measurement of recoil protons set in motion in a thin hydrogenated diffuser by a neutron flux is also described. Suppression of the pulses produced by gamma rays makes it possible to deduce from the spectra obtained the variation of the differential elastic scattering cross-section in terms of the angle, for d-t reaction neutrons. (author) [French] La vie moyenne des scintillations dans l'iodure de cesium varie suivant la nature de la particule ionisante. A la plus grande densite d'ionisation correspond la vie la plus courte. Cette propriete est employee pour distinguer differentes particules produisant des scintillations d'amplitude analogue. L'appareil decrit est un discriminateur de forme. Il mesure le temps mis par la scintillation pour passer de son maximum a une fraction reglable de cette amplitude. Un convertisseur temps-amplitude fournit une impulsion dont la hauteur est proportionnelle au temps ainsi mesure. Les auteurs comparent les formes des scintillations produites par les particules a, les protons, les electrons; ils presentent les resultats obtenus. Les auteurs decrivent l'application de cette methode a la mesure des protons de recul qu'un flux de neutrons met en mouvement dans un diffuseur hydrogene mince. La suppression des

  8. Study of the asymptotic expansion of multiple integrals in mathematical physics; Etudes sur les developpements asymptotiques des integrales multiples de la physique mathematique

    Energy Technology Data Exchange (ETDEWEB)

    Chako, N [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    , provided one interprets in a proper manner the results derived from the two methods, especially the expression of the geometrical wave. (author) [French] Nous avons applique la methode de la phase stationnaire pour evaluer les integrales doubles et multiples du type: (A) U(k) = g(x)e{sup ik{phi}}{sup (x)} d(x), (x)=(x{sub 1},..., x{sub n}) pour les grandes valeurs du parametre k. Dans la premiere partie nous avons etendu d'une maniere rigoureuse la methode de la phase stationnaire aux integrales doubles et multiples de type (A). De plus, nous avons obtenu un developpement asymptotique de (A), lorsque l'amplitude et la phase peuvent se developper sous forme canonique au voisinage de points critiques ou stationnaires de l'integrale (A). Ce developpement contient comme cas particuliers tous les cas importants dans les applications physiques et particulierement en diffraction et diffusion d'ondes electromagnetiques et corpusculaires par des systemes optiques, corps diffractants et potentiels de diffusions. Dans la seconde partie nous avons considere le probleme de la convergence du developpement de la contribution principale a l'integrale, au sens asymptotique de Poincare. La preuve est basee sur la methode des majorantes, utilisee en analyse mathematique. La troisieme partie contient la derivation des series asymptotiques diverses, due aux types varies de points critiques ou stationnaires lies aux fonctions d'amplitude et de phase. Dans la quatrieme partie nous avons generalise la methode aux integrales multiples et au cas ou le parametre k entre implicitement dans la fonction de phase. Ce dernier type d'integrales permet l'extension du premier type a de nombreux problemes physiques, par exemple a la propagation d'ondes en milieux dispersifs et absorbants. Au dernier chapitre, nous faisons l'etude des integrales doubles de diffractions (theorie de Kirchhoff) et nous comparons les resultats par l'application de la methode de la phase stationnaire et de la methode Young

  9. Study of the {sup 14}C benzimidazole distribution in mice after inter-peritoneal injection; Etude de la repartition du benzimidazole {sup 14}C chez la souris apres injection intraperitoneale

    Energy Technology Data Exchange (ETDEWEB)

    Tyortyalian, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-07-01

    In order to provide further information on the mechanism of benzimidazole radioprotective activity, this work studies the tissual repartition in mice of this compound labelled with carbon 14. Experiments have showed that benzimidazole distribution is fast and homogeneous in all the tissues, but however affinity appears at the level of stomach and gastric content. Elimination is made through the urinary system and is very fast. (author) [French] Dans le cadre de l'etude du mecanisme de l'action radioprotectrice du benzimidazole, ce travail a pour objet l'etude de la repartition tissulaire chez la souris de ce compose marque au carbone 14. L'experimentation a montre que le benzimidazole se repartit tres rapidement et de facon pratiquement homogene dans tous les tissus, avec toutefois une affinite paraissant se manifester au niveau de l'estomac et du contenu gastrique. L'elimination, qui se fait par voie urinaire, est tres rapide. (auteur)

  10. Study methods for the drillings around the underground nuclear explosions in the Sahara. Part 1. study of rock samples; Methodes d'etude des forages realises autour des explosions nucleaires souterraines au Sahara. Premiere partie: etude des echantillons de roche

    Energy Technology Data Exchange (ETDEWEB)

    Derlich, S [Commissariat a l' Energie Atomique, Bruyers-le-Chatel (France). Centre d' Etudes

    1969-07-01

    An examination of the mechanical effects produced on rocks by an underground nuclear explosion calls for the use of particular means of exploration which are described in this report, special attention being paid to the equipment used in connection with the French nuclear tests in the Sahara. The drilling methods used (rotary and turbo-drilling) are adapted to the particular conditions of the sampling programme, to the radioactivity and to the temperature in the region of the explosion. A study of the samples makes it possible to obtain the new characteristics of the rock and to assess the chemical and mechanical transformations which it has undergone. An examination of the core obtained from the drilling, together with a knowledge of the drilling parameters (depth of the probe, sample recovery, etc...), makes it possible to study the extent and the characteristics of the zones which have been damaged to different degrees according to their distance from the zero point: cavity, strongly powdered zone, fractured zone, chimney, zones containing high stresses leading to a particular type of fracture of the cores. The problems connected with the interpretation of the results are also presented. (author) [French] L'examen des effets mecaniques provoques par une explosion nucleaire souterraine sur la roche necessite la mise en oeuvre de moyens d'exploration particuliers dont l'expose fait l'objet de ce rapport, essentiellement pour les moyens utilises autour des essais nucleaires francais au Sahara. Les methodes de forage (rotary et turboforage) sont adaptees aux conditions particulieres dues au programme d'echantillonnage, a la radioactivite et a la temperature regnant a proximite du point de tir. L'etude des echantillons permet la determination des nouveaux caracteres de la roche et de ses transformations chimique et mecanique. L'examen des carottes et l'utilisation des parametres de forage (cotes sondeurs, recuperation des echantillons, etc...) permettent d'etudier l

  11. Realisation and tests of a compressed gas Cherenkov counter. Study of the pollution of a beam (1961); Realisation et essais d'un compteur cherenkov a gaz comprime etude de la pollution d'un faisceau (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Duboc, J; Banaigs, J; Detoeuf, J F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The realisation of a compressed as Cherenkov counter permits the study of the pollution of a beam of {pi} mesons with momentum varying from 220 to 11000 MeV/c. (authors) [French] La realisation d'un compteur Cherenkov a gaz sous pression permet l'etude de la pollution d'un faisceau de mesons {pi} d'impulsions comprise entre 220 et 1100 MeV/c. (auteurs)

  12. Etude de quelques conditions influençant la filtration des vins sur membrane

    Directory of Open Access Journals (Sweden)

    M. Salgues

    1982-12-01

    The filterability test proposed by Gaillard helps to estimate the volume of wine that can be filtered by a winery, to control and optimise the assembly line preparation of wines. Different applications are studied. The water flowrate test allows a better control of clopping and of membrane regeneration. Regeneration technics by soaking in detergent solutions are studied and proposed.

  13. Experimental study of the hydrodynamic instabilities occurring in boiling-water reactors; Etude experimentale des instabilites hydrodynamiques survenant dans les reacteurs nucleaires a ebullition

    Energy Technology Data Exchange (ETDEWEB)

    Fabreca, S. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-10-01

    The subjects is an experimental out-of pile loop study of the hydrodynamic oscillations occurring in boiling-water reactors. The study was carried out at atmospheric pressure and at pressure of about 8 atmospheres, in channels heated electrically by a constant and uniform specified current. In the test at 8 atmospheres the channel was a round tube of approximately 6 mm interior diameter. At 1 atmosphere a ring-section channel was used, 10 * 20 mm in diameter, with an inner heating tube and an outer tube of pyrex. It was possible to operate with natural convection and also with forced convection with test-channel by-pass. The study consists of 3 parts: 1. Preliminary determination of the laws governing pressure-drop during boiling. 2. Determination of the fronts at which oscillation appears, within a wide range of the parameters involved. 3. A descriptive study of the oscillations and measurement of the periods. The report gives the oscillation fronts with natural and forced convection for various values of the singular pressure drop at the channel inlet and for various riser lengths. The results are presented in non-dimensional form, which is available, in first approximation, for all geometric scales and for all fluids. Besides the following points were observed: - the wall (nature and thickness) can be an important factor ; - oscillation can occur in a horizontal channel. (author) [French] II a ete effectue une etude experimentale, en boucle hors-pile, des oscillations hydrodynamiques survenant dans les reacteurs a ebullition. L'etude a ete effectuee a la pression atmospherique et a une pression voisine de 8 atmospheres dans des canaux chauffes electriquement a puissance imposee constante et uniforme. Dans les essais a 8 atmospheres le canal etait un tube circulaire de diametre interieur 6 mm environ. A 1 atmosphere le canal etait de section annulaire 10 * 20 mm avec un tube interieur chauffant et un tube exterieur en pyrex. Le fonctionnement etait possible

  14. Magnetic study of solid uranium-fluorine complexes; Contribution a l'etude magnetique de composes fluores solides de l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Dianoux, A J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-06-01

    A study of the magnetic susceptibility of uranium V fluorine complexes and of the magnetic resonance of fluorine atoms in uranium VI fluorine complexes has made it possible to put forward a structural model for these compounds for which it is impossible, because of the lack of suitable single crystals for X-ray diffraction work, to deduce the exact position of the fluorine atoms. It is shown that it is difficult to interpret the paramagnetism of uranium fluorides, because the uranium ions are in low-symmetry sites. A theoretical study of the magnetism of the U{sup V} ion in complex fluorides of the type M{sub 3}UF{sub 8} (M = NH{sub 4}, Na, Rb, Cs) leads to an interpretation based on a trigonal deformation of the eight fluorine atom structure surrounding the uranium atom. By applying a Hamiltonian spin formalism and making a systematic use of group theory, it is possible to present the susceptibility calculations very concisely. Study of the resonance and of the relaxation of the fluorine atoms in powdered uranium VI complex fluorides suggests a structural model in the case of NaUF{sub 7}. It is shown that the shape of the magnetic resonance absorption lines is strongly affected by the presence of large anisotropic chemical shifts. In the model proposed here, six fluorine atoms are linked to the uranium, atom by strongly covalent bonds in a deformed UF{sub 6} octahedral structure; the seventh fluorine atom remains ionic. The occurrence of a rotational movement of the octahedron is confirmed by a study of the longitudinal relaxation of the fluorine atoms, the activation energy being 0.46 eV. (author) [French] L'etude de la susceptibilite magnetique de complexes fluores d'uranium V et la resonance magnetique des fluors dans des complexes fluores d'uranium VI permettent de proposer un modele structural pour ces composes, ou la diffraction des rayons X, en l'absence de monocristaux convenables, est incapable de preciser la position des atomes de fluor. Nous montrons

  15. Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A; Meriel, P [Commissariat a l' Energie Atomique, Saclay (France)

    1959-07-01

    Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

  16. Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A.; Meriel, P. [Commissariat a l' Energie Atomique, Saclay (France)

    1959-07-01

    Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

  17. Apparatus for studying the diffusion of rare gases in stainless steel; Appareil pour etude de la diffusion des gaz rares dans l'acier inoxydable

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J A; Alfille, L [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    This apparatus enables measurements to be carried out on the diffusion of gaseous fission products and of gases in general across thin metallic walls at high temperatures. This work was initially intended to solve the problems involved in systems for detecting the rupture of a fuel element can (D.R.G.) by the diffusion of fission products through the cans at high temperatures. The extension of the work to other fields is envisaged. (author) [French] Cet appareil permet d'effectuer des mesures sur la diffusion des produits de fission gazeux, et des gaz en general, au travers de parois metalliques minces a haute temperature. Au depart, ce procede devait contribuer a resoudre les problemes poses aux systemes detecteurs de rupture de gaine (D.R.G.), par la diffusion des produits de fission au travers des gaines de cartouches a haute temperature. Son extension a d'autres etudes est envisagee. (auteur)

  18. Contribution to the study of the diffusion of fission products in uranium; Contribution a l'etude de la diffusion des produits de fission dans l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Tournier, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-10-15

    In this work we have developed a simple method for determining the diffusion constants and the solid-state solubilities of a metal which is volatile and only slightly soluble in second metal. This method has been applied to the behaviour of certain fission products in {gamma} uranium: strontium, barium, lanthanum, samarium and cerium. This work has made it possible to show the effect of the atomic radius of the solute on the diffusion constants. (author) [French] Dans ce travail nous avons mis au point une methode simple permettant de determiner les constantes de diffusion ainsi que les solubilites a l'etat solide d'un metal volatil et peu soluble dans un autre. Cette methode a ete appliquee au comportement de certains produits de fission dans l'uranium {gamma}: strontium, baryum, lanthane, samarium et cerium. Cette etude a permis de mettre en evidence le role du rayon atomique du solute sur les constantes de diffusion. (auteur)

  19. Contribution to the study of the vertical molten zone process (1963); Contribution a l'etude du procede de la zone fondue verticale (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Lenzin, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Construction and use of several molten zone apparatuses operating either vertically or horizontally. Efficient purification of uranyl nitrate hexahydrate but less successful in the case of other hydrated double salts and of zirconyl chloride in the hydrochloric gel form. Demonstration and study of the dissymmetry in the direction of the transport of the impurity during, the purification by a vertical molten zone process. (author) [French] Construction et utilisation de plusieurs appareils de zone fondue travaillant soit en vertical, soit en horizontal. Purification efficace du nitrate d'uranyle hexahydrate mais peu significative dans le cas des autres couples de sels hydrates et du chlorure de zirconyle a l'etat de gel chlorhydrique. Mise en evidence et etude de la dissymetrie sur le sens de transport de l'impurete au cours de la purification par zone fondue verticale. (auteur)

  20. Solidification of residual fission-product solutions; laboratory studies; Solidification de solutions residuaires concentrees de produits de fission: etudes de laboratoire

    Energy Technology Data Exchange (ETDEWEB)

    Boniaud, R; Cohen, P; Sombret, C [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1961-07-01

    This paper describes the results obtained, at laboratory scale, during the study of the incorporation of fission products into glasses and synthetic micas. The rate of leaching of fission products from the glass and their volatility during firing were measured. A hot cell was built to complete these results. (author) [French] Ce rapport resume le resultat des etudes faites en laboratoire (activite de l'ordre du millicurie) sur l'incorporation des produits de fission dans des verres et micas synthetiques. On a mesure le taux de lixiviation des produits de fission et leur volatilisation au cours de la cuisson. Une cellule chaude a ete installee pour completer ces resultats au moyen d'essais realises avec une activite superieure. (auteur)

  1. Beach sediments drift study by means of radioactive tracers; L'etude du transport littoral par la methode des traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Hours, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P [Electricite de France (EDF), 78 - Chatou (France). Lab. National d' Hydraulique

    1959-07-01

    The present state of the sediments drift studies by means of radioactive tracers is exposed. Various processes of labelling, immersion and detection, used in France and other countries, are reviewed. A more extended analysis of some aspects of the problem by the same authors can be found in 'La Houille Blanche', number 3, may-june 1959 (Rapport C.E.A. number 1269). (author) [French] L'etude du transport littoral des sediments et galets par la methode des traceurs radioactifs est en plein developpement. Le present rapport precise l'etat actuel de la question. Les techniques de marquage, d'immersion et de detection utilisees en France et a l'etranger sont decrites; une analyse plus detaillee de certains aspects de la question est presentee par les memes auteurs dans 'La Houille Blanche', numero 3, mai-juin 1959 (Rapport C.E.A. numero 1269). (auteur)

  2. Experimental study of the hydrodynamic instabilities occurring in boiling-water reactors; Etude experimentale des instabilites hydrodynamiques survenant dans les reacteurs nucleaires a ebullition

    Energy Technology Data Exchange (ETDEWEB)

    Fabreca, S [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1964-10-01

    The subjects is an experimental out-of pile loop study of the hydrodynamic oscillations occurring in boiling-water reactors. The study was carried out at atmospheric pressure and at pressure of about 8 atmospheres, in channels heated electrically by a constant and uniform specified current. In the test at 8 atmospheres the channel was a round tube of approximately 6 mm interior diameter. At 1 atmosphere a ring-section channel was used, 10 * 20 mm in diameter, with an inner heating tube and an outer tube of pyrex. It was possible to operate with natural convection and also with forced convection with test-channel by-pass. The study consists of 3 parts: 1. Preliminary determination of the laws governing pressure-drop during boiling. 2. Determination of the fronts at which oscillation appears, within a wide range of the parameters involved. 3. A descriptive study of the oscillations and measurement of the periods. The report gives the oscillation fronts with natural and forced convection for various values of the singular pressure drop at the channel inlet and for various riser lengths. The results are presented in non-dimensional form, which is available, in first approximation, for all geometric scales and for all fluids. Besides the following points were observed: - the wall (nature and thickness) can be an important factor ; - oscillation can occur in a horizontal channel. (author) [French] II a ete effectue une etude experimentale, en boucle hors-pile, des oscillations hydrodynamiques survenant dans les reacteurs a ebullition. L'etude a ete effectuee a la pression atmospherique et a une pression voisine de 8 atmospheres dans des canaux chauffes electriquement a puissance imposee constante et uniforme. Dans les essais a 8 atmospheres le canal etait un tube circulaire de diametre interieur 6 mm environ. A 1 atmosphere le canal etait de section annulaire 10 * 20 mm avec un tube interieur chauffant et un tube exterieur en pyrex. Le fonctionnement etait possible en

  3. Hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements; Etude du couplage hyperfin dans les alliages gadolinium-praseodyme par mesures de chaleur specifique

    Energy Technology Data Exchange (ETDEWEB)

    Michel, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-12-01

    We have studied the hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements down to 0.3 K. In the first part we describe the apparatus used to perform our measurements. The second part is devoted to some theoretical considerations. We have studied in detail the case of praseodymium which is an exception in the rare earth series. The third part shows the results we have obtained. (author) [French] Nous avons etudie le couplage hyperfin d'alliages de gadolinium-praseodyme par des mesures de chaleur specifique jusqu'a 0.3 K. Dans la premiere partie de cette etude nous decrivons le dispositif experimental. La deuxieme partie est consacree a des considerations theoriques. Nous avons etudie en detail le cas du praseodyme qui est une exception dans la serie des terres rares. La troisieme partie est consacree aux resultats experimentaux. (auteur)

  4. Magnetic study of solid uranium-fluorine complexes; Contribution a l'etude magnetique de composes fluores solides de l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Dianoux, A.J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-06-01

    A study of the magnetic susceptibility of uranium V fluorine complexes and of the magnetic resonance of fluorine atoms in uranium VI fluorine complexes has made it possible to put forward a structural model for these compounds for which it is impossible, because of the lack of suitable single crystals for X-ray diffraction work, to deduce the exact position of the fluorine atoms. It is shown that it is difficult to interpret the paramagnetism of uranium fluorides, because the uranium ions are in low-symmetry sites. A theoretical study of the magnetism of the U{sup V} ion in complex fluorides of the type M{sub 3}UF{sub 8} (M = NH{sub 4}, Na, Rb, Cs) leads to an interpretation based on a trigonal deformation of the eight fluorine atom structure surrounding the uranium atom. By applying a Hamiltonian spin formalism and making a systematic use of group theory, it is possible to present the susceptibility calculations very concisely. Study of the resonance and of the relaxation of the fluorine atoms in powdered uranium VI complex fluorides suggests a structural model in the case of NaUF{sub 7}. It is shown that the shape of the magnetic resonance absorption lines is strongly affected by the presence of large anisotropic chemical shifts. In the model proposed here, six fluorine atoms are linked to the uranium, atom by strongly covalent bonds in a deformed UF{sub 6} octahedral structure; the seventh fluorine atom remains ionic. The occurrence of a rotational movement of the octahedron is confirmed by a study of the longitudinal relaxation of the fluorine atoms, the activation energy being 0.46 eV. (author) [French] L'etude de la susceptibilite magnetique de complexes fluores d'uranium V et la resonance magnetique des fluors dans des complexes fluores d'uranium VI permettent de proposer un modele structural pour ces composes, ou la diffraction des rayons X, en l'absence de monocristaux convenables, est incapable de preciser la position des atomes de

  5. Mineralogical and geochemical investigation of the Oligocene sedimentary series of Saint-Agoulin; Etude mineralogique et geochimique de la serie sedimentaire oligocene de Saint-Agoulin

    Energy Technology Data Exchange (ETDEWEB)

    Mohadjer, K [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires, direction des productions; Faculte des Sciences de l' Universite de Paris, 75 (France)

    1967-07-05

    The mineralogical investigation is based on determination of the amounts of quartz, clays, feldspars and on grain size analysis. A distinction was established between two lithological groups: the lower group with dominant silica the upper with dominant carbonates. Clays of the two groups are comparable with dominant illite, and accessory kaolinite and montmorillonite. The amounts of the elements Si, Al, Fe, Ca, Mg, Na, K, Ti, Mn, P, Ba, Sr, Rb, Pb, Cu, Ni, Co, V, Be, B, Zr, U, were determined by several analytical methods: chemistry, X ray fluorescence, spectrography and fluorimetry. Correlations between the chemical elements and the mineralogical components were computed and plotted. Lastly the conditions of filling up of the basin are defined, taking into account the Oligocene climatic conditions. (author) [French] L'etude mineralogique est basee sur les dosages du quartz, de la calcite, des argiles, des feldspaths et sur les granulometries. On a distingue 2 familles lithologiques: l'une riche en quartz dans la partie inferieure, l'autre riche en carbonate dans la partie superieure. Les argiles des 2 familles sont comparables: illite predominante, kaolinite et montmorillonite accessoires. Les elements: Si, Al, Fe, Ca, Mg, Na, K, Ti, Mn, P, Ba, Sr, Rb, Pb, Cu, Ni, Co, V, Be, B, Zr, U, ont ete doses par differentes methodes d'analyse: analyse chimique, fluorescence X, spectrographie et fluorimetrie. Une etude de correlation entre les elements chimiques et les constituants mineralogiques a ete realisee. Enfin, les conditions de remplissage du Bassin sont definies, en tenant compte du contexte climatique oligocene. (auteur)

  6. Theoretical study and construction of a multichannel {beta} spectrometer with uniform magnetic field; Etude et realisation d'un spectrometre {beta} multivoies a champ magnetique uniforme

    Energy Technology Data Exchange (ETDEWEB)

    Schussler, F [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-09-01

    After a brief survey of the interest of a multichannel beta spectrometer for studying decay schemes of short lived nuclides (30 seconds minimum, the theoretically well known characteristics of uniform magnetic field analyser (image of a large source, transmission and resolution) are briefly remembered. In the second part, the apparatus built as a result of these calculations is described. This apparatus allows the determination of beta spectra by simultaneous determination of the beta spectra in coincidence with four gamma rays predetermined in the gamma spectrum of the studied nuclide. Finally, in the last part, the experimental characteristics of the spectrometer (calibration in energy and transmission) and the first measurement of beta spectra ({sup 155}Sm) and of coincidences ({sup 24}Na), are given. (author) [French] Apres avoir brievement souligne l'interet pratique que presente un spectrometre multivoies pour l'etude des schemas de desintegration des corps radioactifs de courtes periodes (30 secondes au maximum), l'auteur effectue un rappel des caracteristiques theoriques bien connues d'un analyseur magnetique a champ uniforme (image d'une source etendue) calcul de la transmission et du pouvoir de resolution. Une deuxieme partie est consacree a la description de l'appareil realise d'apres ces calculs. Cet appareil permet le releve des spectres beta par detection, simultanee de dix groupes d'electrons d'energies differentes; il permet egalement le releve simultane des spectres beta en coincidence avec quatre rayonnements gammas preselectionnes a l'avance dans le spectre gamma du corps etudie. Dans une derniere partie enfin, sont donnees les caracteristiques experimentales du spectrometre (etalonnage en energie et en transmission) ainsi que les premiers resultats des etudes de spectre beta ({sup 155}Sm) et de coincidence ({sup 24}Na). (auteur)

  7. Contribution to the study of uranyl salts in butyl phosphate solutions; Contribution a l'etude des solutions de sels d'uranyle dans les phosphates butyliques

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-06-01

    A spectroscopic study in the normal infrared region and involving the following associations: tri-alkyl phosphates (tri-butyl, tri-ethyl, tri-methyl), uranyl salts (nitrate, chloride, acetate) has confirmed the existence of an interaction between the phosphoryl group and the uranium atom, as shown by a movement of absorption band for the valency P = 0 from {approx} 1270 cm{sup -1} to {approx} 1180 cm{sup -1}. A study of the preparation, analysis and spectroscopy of the solids obtained by the precipitation of uranyl salts by acid butyl phosphates has been carried out. By infrared spectrophotometry it has been shown that the tri-butyl and di-butyl phosphates are associated in non-polar diluents even before the uranium is introduced. The extraction of uranyl salts from acid aqueous solutions by a diluted mixture of tri-butyl and di-butyl phosphates proceeds by different mechanisms according to the nature of the ion (nitrate or chloride). (author) [French] Une etude spectroscopique dans l'infrarouge moyen portant sur les associations: - phosphates trialcoyliques (tributylique - triethylique - trimethylique) - sels d'uranyle (nitrate, chlorure, acetate) a confirme l'existence d'une interaction entre le groupement phosphoryle et l'atome d'uranium, se manifestant par un deplacement de la bande d'absorption de la vibration de valence P = 0 de {approx} 1270 cm{sup -1} a {approx} 1180 cm{sup -1}. Une etude preparative, analytique et spectroscopique des solides obtenus par precipitation de sels d'uranyle par les phosphates butyliques acides a ete effectuee. La spectrophotomerie infrarouge met en evidence l'association, anterieure a toute introduction d'uranium, des phosphates tributylique et dibutylique dans des diluants non polaires. L'extraction de sels d'uranyle, d'une solution aqueuse acide par un melange dilue de phosphates tributylique et dibutylique, s'effectue suivant des processus differents a la nature de l'anion (nitrate ou chlorure). (auteur)

  8. Contribution to the study of deformed heavy nuclei by means of nuclear reactions; Contribution a l'etude des noyaux lourds deformes au moyen de reactions nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Gastebois, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-06-01

    The experimental results obtained in the study of the (d,p) reactions, at E{sub d} = 12 MeV, on the three even-even deformed nuclei {sup 170}Yb, {sup 172}Yb and {sup 174}Yb have been analysed in terms of DWBA calculations. The spectroscopic information relative to the odd final nuclei have been compared with the predictions of the collective model and of the Nilsson's model. The effect of various parameters used in the DWBA analysis (form factors, optical wave functions) has been carefully studied. The observed differences between the three final nuclei are qualitatively reproduced in the experimental study of resonances, seen in excitation functions of elastically and inelastically scattered protons on the same target nuclei, and corresponding to analogue states in the three nuclei {sup 171}Lu, {sup 173}Lu and {sup 175}Lu. (author) [French] Les resultats experimentaux de l'etude des reactions (d.p) a E{sub d} = 12 MeV, sur les noyaux deformes pairs-pairs {sup 170}Yb, {sup 172}Yb et {sup 174}Yb ont ete interpretes dans le cadre de l'approximation de Born des ondes deformees. Les informations spectroscopiques relatives aux noyaux impairs finals ont ete comparees aux predictions du modele collectif et du modele de Nilsson, apres avoir examine avec soin l'influence des differents parametres (facteurs de forme, fonctions d'onde 'optiques') utilises lors de l'analyse. Les differences observees entre les trois noyaux finals sont qualitativement reproduites par les resultats experimentaux de l'etude de resonances dans les fonctions d'excitation de diffusion elastique et inelastique de protons sur les memes noyaux-cibles, lors de la recherche d'etats analogues dans les noyaux {sup 171}Lu, {sup 173}Lu et {sup 175}Lu. (auteur)

  9. Kinetic ion exchange studies in ultramarines by the radioactive tracer method; Etudes cinetiques d'echanges d'ions dans les outremers par la technique des traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    May, S; Goenvec, H; Pinte, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The possibility of ion exchanges in various ultramarines has been studied in the aqueous phase. The kinetics of the exchange reactions is followed by studying the behaviour of a radioactive ion, either in the solution of the exchanging salt or in the ultramarine itself. The sodium in the make-up of the ultramarine, is found to exchange with various ions in solution. The reaction speeds appear to be governed by a diffusion process inside the grains of ultramarine. The diffusion coefficients and the activation energies are determined for the exchanges studied. Several exchange studies were carried out in an organic medium. The kinetics of ion exchange is also investigated in ultramarines from which most of the constituent sulphur has been eliminated. The results obtained in these ultramarines are compared with the exchange kinetics of the same ions in ordinary ultramarine. (author) [French] Nous avons etudie la possibilite d'echanges ioniques dans differents outremers, en phase aqueuse. L'etude cinetique des reactions d'echanges est suivie en etudiant le comportement d'ion radioactif, soit dans la solution du sel echangeant, soit dans l'outremer lui-meme. C'est le sodium de constitution de l'outremer qui s'echange avec differents ions en solution. Les vitesses de reactions semblent etre controlees par un processus de diffusion a l'interieur des grains d'outremer. Les coefficients de diffusion et les energies d'activation sont determines pour les echanges etudies. Quelques etudes sont realisees en milieu organique ou quelques echanges ont ete etudies. La cinetique d'echange d'ions est egalement etudie dans des outremers dans lesquels la majorite du soufre de constitution a ete eliminee. On compare les resultats obtenus dans ces outremers avec les cinetiques d'echanges des memes ions dans l'outremer ordinaire. (auteur)

  10. Study and achievement of a digital-analog-divider; Etude et realisation d'un diviseur-analogique-numerique

    Energy Technology Data Exchange (ETDEWEB)

    Petin, A [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-04-01

    paragraphes suivants presentent la recherche d'un schema synoptique, l'etude des circuits et la realisation. (auteur)

  11. Contribution to the study of internal friction in graphites; Contribution a l'etude du frottement interieur des graphites

    Energy Technology Data Exchange (ETDEWEB)

    Merlin, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-03-01

    A study has been made of the internal friction in different graphites between -180 C and +500 C using a torsion pendulum; the graphites had been previously treated thermo-mechanically, by neutron irradiation and subjected to partial annealings. It has been shown that there occurs: a hysteretic type dissipation of energy, connected with interactions between dislocations and other defects in the matrix; a dissipation having a partially hysteretic character which can be interpreted by a Granato-Luke type formalism and which is connected with the presence of an 'ultra-micro porosity'; a dissipation by a relaxation mechanism after a small dose of irradiation; this is attributed to the reorientation of bi-interstitials; a dissipation having the characteristics of a solid state transformation, this during an annealing after irradiation. It is attributed to the reorganization of interstitial defects. Some information has thus been obtained concerning graphites, in particular: their behaviour at low mechanical stresses, the nature of irradiation defects and their behaviour during annealing, the structural changes occurring during graphitization, the relationship between internal friction and macroscopic mechanical properties. (author) [French] L'etude du coefficient de frottement interieur au moyen d'un pendule de torsion entre -180 C et +500 C a ete realisee pour differents graphites apres des traitements thermo-mecaniques, des irradiations neutroniques et des guerisons partielles. Il a ete mis en evidence: une dissipation d'energie a caractere hysteretique, reliee aux interactions des dislocations avec les autres defauts de la matrice; une dissipation a caractere partiellement hysteretique, interpretable par un formalisme type Granato-Lucke et reliee a la presence d'une ''ultra-microporosite''; une dissipation par un mecanisme de relaxation, apres irradiation a faible dose, attribuee a la reorientation de di-interstitiels; une dissipation presentant les caracteristiques d

  12. Study of the aqueous chemical treatment of uranium zirconium fuels; Etude du traitement chimique des combustibles uraniumzirconium par voie seche

    Energy Technology Data Exchange (ETDEWEB)

    Bourgeois, M; Nollet, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    A dry process has been studied for separating the uranium from the zirconium-either for recovering the enriched uranium from fuel element production waste, or with a view to treating this waste after irradiation. In this process the alloy is treated with hydrochloric acid at 400 deg. C in a fluidized corundum bed which causes the zirconium to volatilize as tetrachloride and the uranium to form the trichloride. This latter is then converted to the hexafluoride by attack with fluorure. After the laboratory tests, a first pilot plant with a capacity of 1 kg of alloy was tried out at the Fontenay-aux-Roses Nuclear Research Centre; this made it possible to fix the operational conditions for the process. An industrial scale plant was then built with the collaboration of the from Kuhlmann, and operated until a satisfactory process had been developed for treating the waste. This installation treats 3 kg/h of alloy with a yield for the hydrochloric acid of about 50 per cent and with a uranium loss in the zirconium tetrachloride of about 0.1 per cent. An active pilot plant capable of treating of treating a few kilos of irradiated alloy is now being studied. (authors) [French] On a etudie un procede de voie seche pour effectuer la separation de l'uranium et du zirconium - soit en vue de la recuperation de l'uranium enrichi contenu dans les dechets de fabrication des elements combustibles - soit en vue du traitement de ceux-ci apres irradiation. Ce procede consiste a attaquer l'alliage par l'acide chlorhydrique a 400 deg. C dans un lit fluidise de corindon, ce qui a pour effet de volatiliser le zirconium sous forme de tetrachlorure et de transformer l'uranium en trichlorure. Ce dernier est ensuite converti en hexafluorure par action du fluor. Apres des essais de laboratoire, un premier pilote a l'echelle de 1 kg d'alliage a ete experimente au Centre d'Etudes Nucleaires de Fontenay-aux-Roses et a permis de determiner les conditions operatoires du procede. En collaboration avec

  13. Study and achievement of a digital-analog-divider; Etude et realisation d'un diviseur-analogique-numerique

    Energy Technology Data Exchange (ETDEWEB)

    Petin, A. [Commissariat a l' Energie Atomique, Cadarache (France). Centre d' Etudes Nucleaires

    1969-04-01

    theorie du systeme, les paragraphes suivants presentent la recherche d'un schema synoptique, l'etude des circuits et la realisation. (auteur)

  14. Study of the low energy gamma transitions of molybdenum 99; Etude des transitions gamma de basse energie du molybdene 99

    Energy Technology Data Exchange (ETDEWEB)

    Ravier, J.

    1959-07-01

    The study of the decay scheme of Mo{sup 99} has been performed on the magnetic iron-less and double focalization spectrograph of the Institute of Nuclear Physics of Lyon. Methods of internal and external conversion have been used. The intensities of the Mo{sup 99} sources used were not strong enough to determine the characteristics of the internal conversion accurately but were sufficient to precise the decay scheme at low energy. We have determined the internal conversion ratio for the transition of 180 KeV, we have got: 0.13 ± 0.03 which is not in agreement with the value given by a previous experiment based on γ-γ coincidence. Our method seems to be more reliable. We confirm the E2 feature of this transition and its 5/2+ spin. We have determined another important parameter for the 180 KeV de-excitation: the percentage of transitions that do not pass by the isomeric level but by the 140 KeV level is (6 ± 2)%, the isomeric level being at 142 KeV. The gamma spectra at low energy has been studied through the photoelectric effect in a lead converter [French] L'etude du schema de desintegration du Mo{sup 99} deja faite par differents auteurs a ete reprise par des methodes de conversion interne et externe, an moyen du spectrographe magnetique sans fer et a double focalisation de l'Institut de Physique Nucleaire de Lyon. Apres avoir cherche les possibilites d'obtention de sources de haute activite specifique par separation isotopique Szilard-Chalmers sur des molybdates alcalins, le spectre de conversion interne a basse energie a ete mesure. Ainsi se trouverent etre determines les coefficients partiaux de conversion interne. Le spectre γ a basse energie a ete etudier au moyen de l'effet photoelectrique sur un convertisseur de plomb. Les coefficients de conversion interne et les intensites relatives des differentes transitions ont ete calcules moyennant certaines hypotheses. La comparaison entre les valeurs donnees par la theorie et l'experience des differentes

  15. A study by internal friction of defects produced in iron and nickel irradiated at very low temperatures; Etude au moyen du frottement interne des defauts crees par irradiation a tres basse temperature dans le fer et le nickel

    Energy Technology Data Exchange (ETDEWEB)

    Keating-Hart, G de [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    This work represents a contribution to the study of point defects in metals. After a brief review of the theory of internal friction we will discuss some technical innovations aimed at increasing the flexibility of the apparatus at our disposal. These innovations have allowed us to extend our range of measurements down to 20 deg. K. We will then discuss our experimental results. Firstly, we describe preliminary experiments on electron irradiated iron and the evidence for a laminar structure. Secondly, we present and account of the first measurements on nickel after neutron irradiation at 27 deg. K. We will compare the results with those obtained by other methods in this laboratory. Essentially we have observed transitory peaks at low temperature due to close Frenkel pairs and we have noticed the absence of a peak which would correspond to the magnetic after effect band of stage I{sub E}. An attempt is made to explain the disappearance of the observed peaks upon the application of an internal saturating magnetic field. (author) [French] Ce memoire constitue une contribution a l'etude des defauts ponctuels dans les metaux. Apres un bref apercu theorique sur le frottement interne, nous presenterons quelques realisations techniques destinees a accroitre les possibilites des instruments qui nous ont ete confies. Ces dernieres nous ont permis d'etendre la gamme des mesures jusqu'a 20 deg. K. Nous parlerons ensuite de nos resultats experimentaux. En premier lieu, ceux obtenus au cours de premieres experiences, sur le fer irradie aux electrons mettent en evidence des structures de laminage. En second lieu, nous exposerons les premieres mesures realisees sur du nickel irradie aux neutrons; nous comparerons ces resultats avec ceux obtenus par d'autres moyens experimentaux dans le laboratoire. Nous avons observe essentiellement des pics fugitifs a basse temperature dus aux paires proches de Frenckel et nous avons constate l'absence d'un pic correspondant a la bande de tramage

  16. Physico-Chemical Study of the Separation of Calcium Isotopes by Chemical Exchange Between Amalgam and Salt Solutions; Etude physico-chimique de la separation des isotopes du calcium par echange chimique entre amalgame et solution saline

    Energy Technology Data Exchange (ETDEWEB)

    Duie, P; Dirian, G [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France)

    1962-07-01

    In a preliminary study of the isotopic exchange between Ca amalgam and aqueous or organic solutions of Ca salts, the main parameters governing the feasibility of a separation process based on these systems such as separation factor, exchange kinetics, rate of decomposition of the amalgam were investigated. The separation factor between {sup 40}Ca and {sup 46}Ca was found to be of the order of 1.02. The rate of the exchange reaction is rather low for aqueous solutions, extremely low for organic solutions. The amalgam seems not to be attacked by dimethyl-formamide solutions; but it is rapidly decomposed by aqueous solutions of Ca halides. This decomposition is slow in the case of aqueous solutions of calcium formate and still slower for Ca(OH){sub 2}; however, except in particular conditions, the observed rate is often much higher, owing to interfering reactions between amalgam and water vapor contained in H{sub 2} bubbles. (authors) [French] On a fait une etude preliminaire, pour des systemes amalgame de calcium - solution aqueuse ou organique de sels de calcium, des principaux parametres pouvant intervenir dans l'application d'un procede d'echange a l'enrichissement isotopique du calcium: facteur de separation, cinetique de l'echange, cinetique de la decomposition de l'amalgame. Les facteurs de separation {sup 40}Ca-{sup 46}Ca sont de l'ordre de 1,02. L'echange est assez lent pour les solutions aqueuses, extremement lent pour les solutions organiques. La decomposition de l'amalgame est pratiquement inexistante avec les solutions dans le dimethyl- formamide, appreciable pour les solutions alcooliques, rapide pour les solutions aqueuses d'halogenures; elle est normalement lente pour les solutions aqueuses de formiate et surtout de chaux, mais la decomposition est en general acceleree par une reaction parasite entre l'amalgame et l'eau a l'etat vapeur, reaction que l'on n'evite dans des conditions tres particulieres. (auteurs)

  17. The use of radioactive sources for the study of wear in refractory linings; L'emploi de sources radioactives pour l'etude de l'usure des revetements refractaires

    Energy Technology Data Exchange (ETDEWEB)

    Courtois, G; Hours, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Following a discussion on the radioactive method for studying wear in refractory linings (description of the method, advantages and disadvantages, choice of radioactive indicator and detection), the article deals in some detail with the problems of safety involved in this technique. The two most important points discussed are: 1- the need to fix an upper limit of activity in the cast iron: the authors propose a figure of 1 mc of cobalt 60 in 500 tons; 2- the precautions necessary to remedy the diffusion of cobalt 60 in the brickwork (development of special pyro-ceramic sources). After a discussion on the international view point regarding the use of the method, a brief outline of some French projects is given, with particular reference to the case of a blast furnace. A note from the Commission interministerielle des Radioelements is given as an appendix; this deals with special conditions laid down for the use of radioelements in the determination of wear in refractory walls. (author) [French] Apres avoir discute de la methode radioactive pour l'etude de l'usure des revetements refractaires (description de la methode, avantages et inconvenients, choix de l'indicateur radioactif et detection), l'article traite plus particulierement des problemes de securite intervenant dans cette application. Les deux points les plus importants discutes dans ce rapport sont: 1- la necessite de fixer l'activite limite de la fonte et les auteurs proposent ici le chiffre de 1 mc de cobalt 60 dans 500 tonnes de fonte; 2- les remedes a apporter a la diffusion du cobalt 60 dans la maconnerie (realisation de sources speciales en pyrocerame). Apres avoir examine le point de vue international sur l'utilisation de la methode, l'article decrit brievement quelques realisations francaises en etudiant plus particulierement le cas d'un haut-fourneau. En annexe, se trouve une note de la Commission interministerielle des Radio-elements traitant des conditions particulieres d'emploi des radio

  18. Studies on radiation-image detectors; Etudes sur les detecteurs a images de rayonnements; Izuchenie detektorov izobrazheniya radiatsii; Estudios sobre detectores de radiaciones productores de imagenes

    Energy Technology Data Exchange (ETDEWEB)

    Reiffel, L [Armour Research Foundation, Chicago, IL (United States)

    1962-04-15

    collimateur etait constitue par un tube droit de 1 cm sur 1 cm. L'auteur expose l'application de ces compteurs a d'autres etudes neutroniques et presente des observations sur le plus grand pouvoir de resolution que l'on puisse obtenir avec de plus faibles ecartements des electrodes, en procedant a un depouillement dynamique et, eventuellement, par filtrage de l'image optique. Une autre methode generale de detection des rayonnements par l'image consiste dans l'emploi d'ecrans de conversion luminescents ou phosphorescents. Des matrices en fibres luminescentes, composees de tubes de verre tres minces contenant un scintillateur liquide, ont fait l'objet d'essais. Ces matrices sont tres utiles pour la detection des rayons X et des rayonnements {gamma}; les matieres constituant la paroi, ou bien le liquide du coeur, peuvent etre en vue de les rendre sensibles aux neutrons. Le memoire expose de nouvelles methodes de fabrication de divers types d'ecrans en fibres luminescentes, ainsi que des donnees sur le comportement optique, qui ont des rapports avec la technologie de la chambre a scintillation. L'auteur examine brievement des detecteurs a images qui emploieraient des blocs epais de materiaux et qui seraient capables d'emmagasiner des energies non negligeables et d'emettre une phosphorescence stimulee par irradiation; il passe egalement en revue les methodes de lecture utilisant un procede de depouillement optique pour obvier a la diminution du pouvoir de resolution occasionnee par l'epaisseur finie du scintillateur. (author) [Spanish] El autor describe los trabajos sobre detectores de radiaciones capaces de proporcionar informacion sobre la distribucion espacial de estas. Las investigaciones se refieren principalmente al problema de determinar la distribucion de intensidades en un plano, o, si es posible, en una superficie cilindrica. Ello implica estudios sobre difraccion y radiografia neutronicas, sobre radiografia con rayos X y con rayos gamma o sobre la dispersion

  19. Steady-State Two-Phase Flow in Porous Media: Review of Progress in the Development of the DeProF Theory Bridging Pore to Statistical Thermodynamics Scales Écoulement diphasique stationnaire en milieu poreux : revue des avancées sur les développements de la théorie DeProF reliant l’échelle du pore à l’échelle de la thermodynamique

    Directory of Open Access Journals (Sweden)

    Valavanides M.S.

    2012-11-01

    écoulement macroscopique moyen. L’utilisation, comme outil de simulation, de ce modèle mécanistique (années 2000 a permis de découvrir de nombreuses propriétés caractéristiques du processus étudié. On notera l’importance de l’existence, dans le domaine des paramètres de fonctionnement du processus, d’une fenêtre d’intérêt optimale sous la forme d’une surface lisse et continue. La justification de l’existence de conditions opératoires optimales pour le transport de l’huile, dissimulées dans l’utilisation des courbes de perméabilité relatives, a récemment été apportée par la théorie DeProF. Les efforts de recherche se poursuivent actuellement (années 2010 pour élaborer une approche physique s’appuyant sur la thermodynamique statistique et sur le concept aSaPP “aussi spontané que physiquement possible” (as Spontaneous as Physically Possible, qui confirme la corrélation entre l’efficacité du transport et la multiplicité des combinaisons d’écoulements élémentaires.

  20. Study of the variance of a Monte Carlo calculation. Application to weighting; Etude de la variance d'un calcul de Monte Carlo. Application a la ponderation

    Energy Technology Data Exchange (ETDEWEB)

    Lanore, Jeanne-Marie [Commissariat a l' Energie Atomique - CEA, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, Direction des Piles Atomiques, Departement des Etudes de Piles, Service d' Etudes de Protections de Piles (France)

    1969-04-15

    One of the main difficulties in Monte Carlo computations is the estimation of the results variance. Generally, only an apparent variance can be observed over a few calculations, often very different from the actual variance. By studying a large number of short calculations, the authors have tried to evaluate the real variance, and then to apply the obtained results to the optimization of the computations. The program used is the Poker one-dimensional Monte Carlo program. Calculations are performed in two types of fictitious environments: a body with constant cross section, without absorption, where all shocks are elastic and isotropic; a body with variable cross section (presenting a very pronounced peak and hole), with an anisotropy for high energy elastic shocks, and with the possibility of inelastic shocks (this body presents all the features that can appear in a real case)

  1. Application of microhardness measurements to the study of diffusion zones; Application des mesures de microdurete a l'etude des zones de diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Levy, V; Bouchet, P; Siouffi, J; Adda, Y [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    It is well known that the concentration fluctuations in diffusion zones can be determined by microhardness tests. It was therefore interesting to define the experimental conditions leading to the best accuracy. To this end, we have studied the influence of the kind of penetrator used, and of the applied load on the reproducibility of the curves plotting the variation of microhardness values against penetration. This work carried out for diffusion zones of various widths, has enabled us to determine in each case the best experimental procedure. (author) [French] On sait que les variations de concentration existant dans les zones de diffusion peuvent etre determinees au moyen de mesures de microdurete. Il etait donc interessant de definir les conditions experimentales conduisant a la meilleure precision. Dans ce but, nous avons etudie l'influence de la nature du penetrateur et celle de la charge appliquee sur la reproductibilite des courbes representant les variations de durete en fonction de la penetration. Ce travail, effectue pour des zones de diffusion de differentes largeurs, nous a permis de determiner dans chaque cas les conditions experimentales les plus favorables. (auteur)

  2. Theoretical and Experimental Studies of High-Frequency Plasma Structures; Etudes Theoriques et Experimentales sur les Structures HF a Plasma

    Energy Technology Data Exchange (ETDEWEB)

    Consoli, T. [CEA, Centre d' Etudes Nucleaires de Saclay (France)

    1969-03-15

    currents of more than 20 keV and of about 10 mA/cm{sub 2} were obtained. Ion entrainment for a magnetic field twice that necessary for resonance was also verified. Finally, with the Pleiade I device ({lambda} = 100 cm, P{sub HF} {approx}500 W, CW), the reflection of accelerated plasma jets by a mirror pulse lasting 75 {mu}s was verified. From measurements of the fast neutrals resulting from ion charge exchange (with the residual gas; p {<=} 10{sup -4} mmHg) it was deduced that the density of the ions (directed energy {approx} 1.5 keV) may be increased from 2 x 10{sub 8} cm{sup -3} (direct beam) to 6 x 10{sup 9} cm{sup -3} during the mirror pulse. The accumulated density appears to be limited by the charge exchange, and the increased duration of the mirror pulse to 200 {mu}s with p Less-Than-Or-Equivalent-To 10{sup -4} mmHg (unchanged) hardly improves the accumulation ratio. This agrees with the predictions if one takes into account the fact that the ion lifetime is {approx} 10 {mu}s. (author) [French] Il s'agit des etudes sur les structures HF a la resonance ( {omega}{sub ec} = {omega}{sub HF}) en champ magnetique inhomogene. Les points suivants ont ete developpes theoriquement: description analytique complete (relativiste et non lineaire) du mouvement individuel, compte tenu du fait que le nombre de revolutions des particules dans la zone de resonance est eleve ; etude du champ de charge d' espace autocoherent ( 'self-consistent') en vue d'etablir les conditions pour que l' energie des ions soit de l'ordre de celle gagnee par les electrons dans la zone de resonance; calcul du champ HF autocoherent dans le plasma accelere en vue d' etablir les conditions de fonctionnement optimum de l'accelerateur HF; probleme des pertes aux miroirs. Les resultats experimentaux ont ete obtenus avec divers dispositifs construits en vue de la verification des previsions theoriques.

  3. Etude de l.inocuite et de l.acceptabilite du sulfate de cellulose (SC ...

    African Journals Online (AJOL)

    L.objectif principal de l.étude était d.évaluer les effets secondaires locaux et systémiques de l.application vaginale de plusieurs doses de gel de sulfate de cellulose à 6%. L.objectif secondaire était d.en évaluer l.acceptabilité par les participantes. L.autorisation pour mener l.étude a été obtenue du Ministère de la Santé ...

  4. Adsorption studies in a fluorinated atmosphere; Etude de l'adsorption en atmosphere fluorante

    Energy Technology Data Exchange (ETDEWEB)

    Abassin, J J; Barberi, P; Guillouet, Y; Hartmanshenn, O; Lambard, J; Machefer, J; Michel, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-03-01

    This CEA report deals with the adaptation of conventional or non-conventional apparatus to the measurement of the physical and chemical adsorption of corrosive fluorine-containing gases. Various techniques are reviewed, in particular: - thermogravimetry; - volumetry; - use of radio-active tracers; - calorimetry; - hertzian spectroscopy; - infrared spectroscopy. In each of these cases, problems of corrosion call for the use of special techniques which require the extensive use of pure nickel and aluminium or certain of their alloys. Diagrams of the apparatus and some examples of applications are given, together with some details of the performances obtained and of the main drawbacks. (authors) [French] Ce rapport CEA traite de l'adaptation d'appareillages classiques ou non a la mesure de l'adsorption physique et chimique de derives fluores gazeux corrosifs. Differentes techniques sont passees en revue, en particulier: - la thermogravimetrie; - la volumetrie; - l'utilisation de traceurs radioactifs; - la calorimetrie; - la spectroscopie hertzienne; - la spectroscopie infra-rouge. Dans chacun des cas, les problemes de corrosion conduisent a une technologie specialement adaptee et utilisant tres largement le nickel et l'aluminium purs ou certains de leurs alliages. Des schemas d'appareils et quelques exemples d'application sont proposes, ainsi que quelques precisions sur les performances obtenues et les principaux defauts. (auteurs)

  5. Adsorption studies in a fluorinated atmosphere; Etude de l'adsorption en atmosphere fluorante

    Energy Technology Data Exchange (ETDEWEB)

    Abassin, J.J.; Barberi, P.; Guillouet, Y.; Hartmanshenn, O.; Lambard, J.; Machefer, J.; Michel, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-03-01

    This CEA report deals with the adaptation of conventional or non-conventional apparatus to the measurement of the physical and chemical adsorption of corrosive fluorine-containing gases. Various techniques are reviewed, in particular: - thermogravimetry; - volumetry; - use of radio-active tracers; - calorimetry; - hertzian spectroscopy; - infrared spectroscopy. In each of these cases, problems of corrosion call for the use of special techniques which require the extensive use of pure nickel and aluminium or certain of their alloys. Diagrams of the apparatus and some examples of applications are given, together with some details of the performances obtained and of the main drawbacks. (authors) [French] Ce rapport CEA traite de l'adaptation d'appareillages classiques ou non a la mesure de l'adsorption physique et chimique de derives fluores gazeux corrosifs. Differentes techniques sont passees en revue, en particulier: - la thermogravimetrie; - la volumetrie; - l'utilisation de traceurs radioactifs; - la calorimetrie; - la spectroscopie hertzienne; - la spectroscopie infra-rouge. Dans chacun des cas, les problemes de corrosion conduisent a une technologie specialement adaptee et utilisant tres largement le nickel et l'aluminium purs ou certains de leurs alliages. Des schemas d'appareils et quelques exemples d'application sont proposes, ainsi que quelques precisions sur les performances obtenues et les principaux defauts. (auteurs)

  6. Use of a Monte-Carlo method for studying the statistical distribution of electric fields around an ion in a one-component plasma; Etude, par une methode de Monte-Carlo de la repartition statistique des champs electriques au niveau d'un ion, dans un plasma a une composante

    Energy Technology Data Exchange (ETDEWEB)

    Rossignol-Guzzi, D [Commissariat a l' Energie Atomique, 94 - Limeil-Brevannes (France). Centre d' Etudes Nucleaires

    1968-11-01

    A Monte-Carlo simulation has been made of the equilibrium configurations taken by a plasma of equally charged punctual ions, immersed in a uniform neutralizing background of electrons. The statistical repartition of the electric field acting on one ion, needed to obtain Stark effect, was specially obtained. Comparison for dense plasmas, was made with the former works of Holtzmark, Mayer, Broyles. (author) [French] On simule sur ordinateur, suivant une methode de Monte-Carlo, les configurations prises a l'equilibre thermodynamique par un plasma d'ions ponctuels et de meme charge, places dans un milieu d'electrons uniformement distribues. On etudie, en particulier, la repartition statistique des champs electriques au niveau d'un ion, utilisee dans les calculs d'effets Stark. On compare, dans le cadre des plasmas denses, les resultats obtenus aux travaux precedents de Holtzmark, Mayer, Broyles. (auteur)

  7. Etude numérique d'une structure bicouche en grave hydraulique

    OpenAIRE

    SIMONIN, Jean Michel; LABORATOIRE CENTRAL DES PONTS ET CHAUSSEES - LCPC

    2005-01-01

    L'étude réalisé montre que la méthode Impact-Echo permet de détecter des défauts d'interface dans la mesure où l'interface est assez fortement dégradée, et le défaut a une extension latérale suffisante. La fréquence Impact-Echo varie légèrement en fonction de ces caractéristiques, conduisant à des variations dans l'estimation de la profondeur de ce défaut. L'épaisseur du défaut a peu d'influence sur l'application de la méthode. Les résultats mentionnés suppose que l'impact est réalisé au cent...

  8. ETUDE DE L’INFLUENCE DES DIFFERENTS PARAMETRES SUR UN MODULE PHOTOVOLTAÏQUE

    Directory of Open Access Journals (Sweden)

    Assia ZERDOUDI

    2015-06-01

    Full Text Available L’Algérie dispose d’environ 3200 heures d’ensoleillement par année, bénéficiant d’une situation climatique favorable à l’application des techniques solaires. La conception des installations efficaces et rentables sur la base des modules solaires est particulièrement importante. Des logiciels dédiés à la simulation des systèmes photovoltaïques peuvent réaliser une vaste et précise analyse, mais ils ne permettent généralement pas à l'utilisateur de modifier les algorithmes. Dans le présent travail, un programme fonctionnant en environnement MATLAB, de la simulation de l'application d'un système photovoltaïque sur la base des modèles mathématiques, de ses composants a été conçu, nous avons modélisé un générateur photovoltaïque en se basant sur les équations électriques et mathématiques qui régissent son comportement ainsi que la dégradation  des caractéristiques de ce générateur en fonction des conditions météorologiques (température et éclairement. Nous avons  réalisé notre étude sur le module SPR 315 E de chez SUNPOWER, qui fournit une puissance de 315 W..

  9. Studies on the gamma-gamma method. Definition of an apparatus for on-the-spot measurement of uranium ore densities; Etudes sur la methode gamma-gamma. Determination d'un appareillage pour la mesure en place de la densite des minerais d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Czubek, J A [Institut de Recheches Nucleaires, Dept. 6, Cracovie (Poland); Guitton, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    The work described follows on to the research published in report CEA-R--2720 in march 1965. It includes: - experimental results obtained with a model composed of a constant density material (graphite); - the drawing-up of calibration curves using the similitude principle; - determination of the characteristics of a gamma-gamma probe, together with a discussion. The influence is studied of a certain number of parameters on the shape of the energy spectra of scattered radiation, and of the calibration curves: nature of the radioactive source, diameter of the probe area, source detector distance, geometrical shape of shielding between the source and the detector. An attempt is made to find a mathematical model for the calibration curve, for given conditions. Numerical applications make it possible to establish the optimum technical characteristics for a probe measuring the density with the smallest statistical error. (authors) [French] Les travaux decrits font suite aux etudes presentees dans le rapport CEA-R--2720 de mars 1965. Ils portent sur: - les resultats experimentaux obtenus sur un modele constitue d'un materiau de densite constante (graphite) ; - l'etablissement de courbes d'etalonnage a l'aide du principe de similitude; - la recherche et la discussion des caracteristiques d'une sonde gamma-gamma. L'influence d'un certain nombre de parametres sur la forme des spectres d'energie du rayonnement diffuse et des courbes d'etalonnage est etudiee: nature de la source radioactive, diametre du sondage, distance source-detecteur, forme geometrique du blindage entre la source et le detecteur. Pour des conditions determinees, le modele mathematique de la courbe d'etalonnage est recherche. Des applications numeriques permettent d'etablir les caracteristiques techniques optimales d'une sonde mesurant la densite avec la plus faible erreur statistique. (auteurs)

  10. Investigation of the glide modes of single crystals of beryllium; Etude des modes de glissement de monocristaux de beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Regnier, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-05-01

    glissement et des configurations de dislocations. L'etude du glissement prismatique a ete developpee beaucoup plus largement: l'influence de la temperature de la vitesse de deformation, de l'orientation initiale du plan de base et des plans prismatiques ont ete releves sur des echantillons d'orientation soignee, deformes en tension. On a egalement effectue quelques essais de microdeformation et observe de facon detaillee les lignes de glissement et les configurations de dislocations. Le comportement tres particulier observe n'est pas du aux impuretes, mais au glissement devie. On propose un mecanisme de blocage des dislocations permettant de l'expliquer. Comme ce mecanisme suppose que les dislocations a-bar peuvent aussi se dissocier sur les plans prismatiques [101-bar0] on examine cette possibilite et l'on propose plusieurs dissociations eventuelles dont la plus probable correspond a la transformation de phase hexagonale compacte {yields} cubique centree. En generalisant cette hypothese, on montre alors comment on peut rendre compte de la facilite relative des divers modes de glissement dans tous les metaux hexagonaux. (auteur)

  11. Theoretical, physical and experimental study of fissile aqueous media; Etudes theorique, physique et experimentale des milieux fissiles aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Caizergues, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    This thesis consists of a set of theoretical and experimental studies. a) Theoretical calculation methods used for cross-sections and the critical parameters; b) Comparison of the theoretical and experimental results: it is shown that the agreement between these results cannot be improved above a certain limit because of the accuracy with which are known the composition and the dimensions of the media and the microscopic cross-sections; c) Determination of the ratios {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar for fissile aqueous media ({eta}-bar: number of neutrons emitted per neutron absorbed, averaged over the reactor neutron spectrum). Evaluation of the accuracy to which these ratios are known; d) Effect of {sup 240}Pu: the measurements are carried out on Pu with a {sup 240}Pu content of 1.5 per cent, 3.11 per cent and 9.95 per cent; Calculation of the resonance integral I240 using the experimental results gives values in reasonable agreement with the results obtained by other more conventional methods. e) Measurement of the spectrum indices for aqueous media containing Pu, U5 and U3. With these latter it is possible to obtain mean fission cross-section ratios {sigma}f239-bar / {sigma}f235-bar for these different spectra. A calculation-experiment comparison is carried out using various theoretical methods. (author) [French] Cette these groupe un ensemble d'etudes theoriques et experimentales. a) Methodes theoriques de calcul utilisees pour les sections efficaces et les parametres critiques; b) Comparaisons des resultats theoriques et experimentaux: on montre que l'accord entre ces resultats ne peut etre ameliore au-dela de certaines limites vu la precision avec laquelle sont connues la composition et les dimensions des milieux et les sections efficaces macroscopiques; c) Determination des rapports {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar pour les milieux fissiles aqueux ({eta}: nombre de

  12. Etude exploratoire des conceptions de la circulation sanguine aupres d'eleves de l'ordre collegial

    Science.gov (United States)

    Robitaille, Jean-Marc

    Il existe peu d'etudes sur les conceptions touchant les domaines de la biologie, notamment sur les conceptions de la circulation sanguine Nous avons observe egalement l'absence de recherche menee aupres d'eleves de l'ordre collegial sur cette question. Nous avons voulu combler une lacune en menant une recherche sur les conceptions de la circulation sanguine aupres d'eleves de l'ordre collegial. Pour mener cette recherche nous nous sommes inspires d'une methode developpee par Treagust (1988). Le premier niveau de formulation didactique etablit l'architecture du systeme et la fonction nutritive de la circulation. Le second niveau de formulation didactique decrit et relie les parametres de la dynamique de la circulation et leur relation: Pression, Debit et Resistance. Le troisieme niveau de formulation didactique s'interesse au controle de la circulation du sang dans un contexte d'homeostasie qui implique la regulation de la pression arterielle. Nous avons construit un questionnaire en nous guidant sur les niveaux de formulation didactique et l'analyse des entrevues menees aupres de dix-huit eleves, representatifs de la population cible. Ce questionnaire fut administre a un echantillon de 2300 eleves disperses dans six colleges de la region de Montreal. Notre echantillon comprend des eleves inscrits a des programmes de l'ordre collegial en Sciences de la nature et en Techniques de la sante et qui n'ont pas suivi le cours sur la circulation sanguine. Notre analyse des reponses des eleves de notre echantillon aux questions sur le premier niveau de formulation didactique revele que la majorite des eleves considerent que le systeme circulatoire relie les organes les uns aux autres dans un circuit en serie. Notre analyse revele egalement que la majorite des eleves estiment que les nutriments sont extraits du sang par les organes selon un processus de selection base sur les besoins determines par la fonction de l'organe. Ces besoins sont differents selon les organes qui ne

  13. Theoretical, physical and experimental study of fissile aqueous media; Etudes theorique, physique et experimentale des milieux fissiles aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Caizergues, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-04-01

    This thesis consists of a set of theoretical and experimental studies. a) Theoretical calculation methods used for cross-sections and the critical parameters; b) Comparison of the theoretical and experimental results: it is shown that the agreement between these results cannot be improved above a certain limit because of the accuracy with which are known the composition and the dimensions of the media and the microscopic cross-sections; c) Determination of the ratios {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar for fissile aqueous media ({eta}-bar: number of neutrons emitted per neutron absorbed, averaged over the reactor neutron spectrum). Evaluation of the accuracy to which these ratios are known; d) Effect of {sup 240}Pu: the measurements are carried out on Pu with a {sup 240}Pu content of 1.5 per cent, 3.11 per cent and 9.95 per cent; Calculation of the resonance integral I240 using the experimental results gives values in reasonable agreement with the results obtained by other more conventional methods. e) Measurement of the spectrum indices for aqueous media containing Pu, U5 and U3. With these latter it is possible to obtain mean fission cross-section ratios {sigma}f239-bar / {sigma}f235-bar for these different spectra. A calculation-experiment comparison is carried out using various theoretical methods. (author) [French] Cette these groupe un ensemble d'etudes theoriques et experimentales. a) Methodes theoriques de calcul utilisees pour les sections efficaces et les parametres critiques; b) Comparaisons des resultats theoriques et experimentaux: on montre que l'accord entre ces resultats ne peut etre ameliore au-dela de certaines limites vu la precision avec laquelle sont connues la composition et les dimensions des milieux et les sections efficaces macroscopiques; c) Determination des rapports {eta}{sup 9}-bar / {eta}{sup 5}-bar, {eta}{sup 3}-bar / {eta}{sup 5}-bar pour les milieux fissiles aqueux ({eta}: nombre de neutrons emis

  14. Lethal action of canavanine in Escherichia coli; Etude de l'action lethale de la canavanine sur Escherichia coli

    Energy Technology Data Exchange (ETDEWEB)

    Simonnet, Gerard Marc

    1972-01-04

    We studied the action of canavanine, analog of arginine, on the loss of bacteria viability; macromolecular synthesis (proteins, RNA and DNA) and DNA structure. We used bacteria because among different kinds of cells (ascitic tumor cells, erythrocytes, reticulocytes) they are the only ones which show the best capability of concentrating canavanine. This compound penetrates bacteria cells by active transportation uptake. Canavanine causes an irreversible inhibition of the cell division of bacteria. The loss of viability is connected to the incorporation in proteins of canavanine instead of arginine. Canavanine stimulates RNA synthesis in bacteria, strains RC{sup Str} arg{sup -}, starved of arginine, but it inhibits the incorporation of uracil, UMP and UDP in strains RC{sup str} arg{sup -}. Canavanine allows the completion of pre-initiated DNA chains; this result is similar to that observed of starved amino acid bacteria. The DNA of bacteria incubated with canavanine shows a lesion which results in the breaking of DNA. Part of the DNA does not sediment at 10 000 xg with the membranes. This DNA does not sediment either at 150 000 xg in alkaline sucrose gradient. Our results are consistent with the hypothesis that canavanine death is due to this breaking of the DNA. (author) [French] Dans le present travail, on a etudie l'action de la canavanine, analogue structural de l'arginine, sur la viabilite des bacteries, les syntheses macromoleculaires (proteines, ARN et ADN) et la structure de l'ADN. Les bacteries ont ete utilisees pour cette etude car des differents types de cellules testes (hepatomes ascitiques, reticulocytes et erythrocytes), ce sont elles qui presentent la meilleure permeabilite a la canavanine. Cette substance penetre dans les bacteries par un mecanisme de transport actif. La canavanine inhibe de facon irreversible la division cellulaire des bacteries. Cette perte de viabilite est liee a l'incorporation de la canavanine a la place de l'arginine dans les

  15. PRI 8.1: CARNOT. Analysis and research community of the new orientations of the thermodynamics. Activity report june 2002/ june 2004; PRI 8.1: CARNOT. Communaute d'Analyse et de Recherche des Nouvelles Orientations de la Thermodynamique. Rapport d'activite juin 2002/ juin 2004

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This progress report takes stock on the CARNOT project. This project aims to standardize the different approaches or identify the application fields of each thermodynamical methodology. The cycles analysis and more generally thermodynamical machines (design, energy efficiency, new energy utilization concepts). The environmental impact is also an important topic of the project. (A.L.B.)

  16. Study of isotopic exchange reactors (1961); Etude des reacteurs d'echange isotopique (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Grandcollot, P; Dirian, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    A study is made of the general case of the theory of first-order isotopic chemical exchange between a gaseous and a liquid phase in a reactor, starting from fundamental reaction kinetics data, and without making any limiting hypothesis concerning the value of the separation factor. The cases of counter-current reactors and of co-current reactors are considered successively. The general deuterium conservation equation requires the definition of the quotient of the reactor; the performances of this reactor are characterised by its overall efficiency. The idea of the ratio is introduced because it represents a convenient intermediary in the calculations. The search for an additive value for reactors in series leads logically to the defining of an exchange capacity, and a total efficiency, or number of theoretical reactors. This method of expressing the performances of a reactor is more general than the efficiency due to Murphee which only has a physical significance in the particular case of homogeneous liquid reactors. The relationships between these various quantities are established, and the representation due to Mc Cabe and Thiele is generalized. The reactor performances are linked to the first - order reaction kinetics by the transfer number. The relationships are given for a certain number of concrete cases. Finally the application of these calculations is given, together with the approximations necessary in the case where, because of the presence of several components in each phase, the exchange reaction no longer obeys a single kinetic law. (authors) [French] On examine dans le cas general la theorie d'un reacteur quelconque pour l'echange chimique isotopique du premier ordre entre une phase gazeuse et une phase liquide, a partir des donnees fondamentales sur la cinetique de la reaction, sans faire aucune hypothese limitative sur le cas des reacteurs a contre ourant, puis celui des reacteurs a co-courant. L'equation generale de conservation du deuterium

  17. Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium

    Energy Technology Data Exchange (ETDEWEB)

    Le Ber, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    protons de HSO{sup -}{sub 4}. Nous avons compare les domaines d'electroactivite obtenus a differentes electrodes (Ag-Au-Graphite-Hg). Nous avons envisage la dissolution de quelques oxydes et halogenures metalliques. Cette etude montre le role des ions HSO{sup -}{sub 4} en tant qu'accepteurs d'ions O{sup 2-}. Nous avons entrepris l'etude electrochimique de quelques systemes oxydo-reducteurs: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (I), les systemes du vanadium et de l'uranium, du mercure Hg{down_arrow} / Hg{sup 2-}{sub 2} et de l'or Au/Au{sup 3+}; puis l'attaque par le solvant de quelques metaux usuels comme l'aluminium, le fer, le cuivre et le nickel. L'etude des systemes de l'argent nous a permis d'atteindre les produits de solubilite de AgCl et AgBr et d'envisager le titrage coulometrique des ions Cl{sup -} par des ions Ag{sup +}. Nous avons mis en evidence differentes especes chimiques du vanadium pouvant exister dans l'eutectique fondu. (auteur)

  18. Etude hydromecanique d'une fracture en cisaillement sous contrainte normale constante

    Science.gov (United States)

    Lamontagne, Eric

    This research study deals with the effects of shear direction and injection flow rate on the flow directional anisotropy for a given normal stress. It presents experimental works on hydromechanical shear behaviour of a fracture under constant normal stress conditions that permits the characterisation of the intrinsic hydraulic transmissivity in relation with the directional anisotropy of the roughness morphology on the fracture surfaces. Tests were performed on mortar replicas of a natural fracture so that the fracture roughness and void space geometry were kept the same for each test. The experimental work program was performed through direct shear tests on the fracture replicas in four shear directions under four constant normal stress levels. The application of the normal stress was followed by several injections of fluid under constant flow rate. Then, for each defined shear displacement, several injections of fluid were done at different flow rate but under constant flow rate. The test results show that: (1) for the whole shear tests, the global intrinsic transmissivity is included within an enveloping zone of about one order of size. The transmissivity curves within the enveloping zone has a particularity to increase about two orders of size in the first millimetre of shear displacement and subsequently stabilised rapidly; (2) the highest dilatancy do not correspond necessarily with the highest intrinsic transmissivity so that, the behaviour of the global intrinsic transmissivity is not directly proportional to the fracture dilatancy during shear; (3) after the peak shear stress, the divergence is more marked between the global intrinsic transmissivity curves at various flow rate; (4) after peak shear strength and the beginning of asperity degradation, the gradual passage to residual friction shear behaviour causes a directional flow anisotropy and a reorientation of the flow chenalisation direction sub perpendicularly to the shear direction; (5) the

  19. Study of the point defects formed in cobalt by electron bombardment; Etude des defauts ponctuels crees par bombardement electronique dans le cobalt

    Energy Technology Data Exchange (ETDEWEB)

    Sulpice, G [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-12-01

    A study of the point defects formed in cobalt by electron bombardment is presented. The results are compared with those previously obtained for two other ferromagnetic metals of different structure, iron and nickel. In the first part we give a review of the literature concerning the creation of point defects, their contribution to resistivity and their annihilation mode in the three structure types. We then describe the experimental techniques adapted, in particular the study of the resistivity increase during a linear temperature rise. Our investigations concern the following, essential points : the observation of the successive annihilation stages of the point defects formed in pure cobalt, a study of the variations with respect to the doses and energy of the incident particles, and the determination of the annealing kinetics and the corresponding activation energies. The results are finally compared with the various models of point defect annihilation proposed for other metals: none of these interpretations is in perfect agreement with our results. In the case of cobalt we are thus led to modify the model proposed by our laboratory for iron an nickel. The difference between these three metals is explained by the anisotropic character of the cobalt matrix. (author) [French] Nous presentons une etude des defauts ponctuels crees par bombardement electronique dans le cobalt et comparons nos resultats a ceux obtenus precedemment dans deux autres metaux ferromagnetiques de structure differente, le fer et le nickel. Dans une premiere partie nous faisons une mise au point bibliographique comparee sur la creation des defauts, leur contribution a la resistivite et leur mode d'annihilation dans les trois types de structure. Nous decrivons ensuite les techniques experimentales mises au point, en particulier l'etude du revenu de la resistivite au cours d'une montee lineaire de temperature. Au cours de ce travail, nous avons mis en evidence les stades successifs d

  20. Contribution to the study of point defects formed in nickel by electron bombardment; Contribution a l'etude des defauts ponctuels crees par bombardement electronique dans le nickel

    Energy Technology Data Exchange (ETDEWEB)

    Oddou, J L [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-12-01

    After a short account of the experimental techniques employed in our studies, the experimental results obtained on pure nickel samples are exposed. The apparition of the successive annihilation stages of point defects created by electron bombardment is established by isochronal heat treatments: the annihilation kinetics and the corresponding activation energies are determined. The effect of the incident particle doses is also studied. The experimental results are then compared with R.A. Johnson's theoretical calculations of the stability and the migration of point defects in nickel, and taking into account the results obtained by Peretto in magnetic after effect measurements. This leads us to a model in good agreement with calculations and experiment for the first stages. In a second chapter the behaviour of nickel doped by certain impurities is studied. First, the results concerning the rate of increase of resistivity (function of sample purity) is investigated. Two possible explanations of the observed phenomenon are proposed: either a deviation with respect to Mathiessen's law, or an increase of the number of defects formed in the presence of impurity atoms. Finally, a study of the resistivity recovery of the doped samples permits us to suggest an order of magnitude for the binding energy interstitial/impurity atom in the nickel matrix. (author) [French] Apres avoir brievement rappele les techniques experimentales que nous avons utilisees pour cette etude, nous exposons les resultats experimentaux obtenus sur des echantillons de nickel pur. Les stades successifs d'annihilation des defauts ponctuels crees par bombardement electronique sont mis en evidence par traitements thermiques isochrones; les cinetiques de disparition, et les energies d'activation correspondantes sont determinees. Nous etudions egalement l'effet de la dose des particules incidentes. Les resultats experimentaux sont ensuite compares avec les calculs theoriques de R.A JOHNSON sur la stabilite

  1. Some ways for the investigation of the solar modulation of cosmic electrons; Moyens d'etude de la modulation solaire des electrons cosmiques

    Energy Technology Data Exchange (ETDEWEB)

    Mercier, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    In this report, we are investigating the solar modulation of cosmic electrons, in different ways. By comparing the calculated intensity with the measured intensity of positrons, we can evaluate the solar modulation of positrons, hence the modulation of negatons, since the modulation of negatons is probably the same that for positrons. By comparing the electron spectrum in interstellar space needed to explain the galactic background radio emission with that observed near the earth, we can deduce information about the modulation of electrons. We can investigate the modulation through the observation of its variations during the solar cycle. This different ways lead us to compatible results. In spite of the fact that the precision of the experimental data is poor, the modulation can be represented by: a constant or a form in exp(- K/Ro{beta}) under the rigidity Ro {approx_equal} 0,5 BV; a form in exp(- K/R) or exp(- K/R{beta}) above this rigidity. In addition, the investigation of both electrons and protons displays that the diffusion-convection theory is inadequate to explain all the features of the solar modulation. (author) [French] Dans le present rapport, nous etudions la modulation solaire des electrons cosmiques a l'aide de plusieurs methodes. Par comparaison entre l'intensite calculee et l'intensite mesuree des positons, on peut evaluer la modulation solaire des positons, et aussi des negatons, puisque la modulation des negatons est probablement la meme que celle des positons. Par le calcul, a partir du bruit de fond radio, du flux des electrons a l'exterieur du systeme solaire et sa confrontation avec le flux observe a l'orbite de la Terre permet l'etude de la modulation solaire des electrons. On peut aussi analyser ce phenomene de modulation pour l'etude de ses variations au cours du cycle solaire. Ces diverses methodes donnent des resultats compatibles. En depit de la precision mediocre des donnees experimentales, on peut caracteriser la modulation par: une

  2. Theoretical study of properties due to the curvature in the toroid shape in magnetohydrodynamics; Etude theorique des proprietes dues a la courbure dans les configurations toriques en magnetohydrodynamique

    Energy Technology Data Exchange (ETDEWEB)

    Adam, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-03-01

    - We are considering a toroidal plasma centred around a closed {gamma}. When the rotational transform L/2{pi} approach an integer k if some specific relations are not satisfied curvature effects can become very important. When the rotational transform is created by current flowing in the plasma this happen if the coefficient a{sub k} of the Fourier expansion of curvature 1/R(s) of is non equal zero. One find then that the influence of a{sub k} is preponderant and that is possible to neglect all the other members of the series to study the neighbourhood of the corresponding equilibrium singularity. By developing an adapted coordinate system it is thus possible to take into account curvature effects at the lowest order. Equilibrium study bring us to introduce an equilibrium parameter {nu} {<=} 1 characterizing curvature effects. It is shown that the more {nu} is near of 1 the more shear and V{sup {phi}} quantities occurring in the stability criterion are important. Finally stability investigation show that the larger is the integer k the smaller is the domain of stability when L/2{pi} is near of k. (author) [French] Nous considerons un plasma toroidal centre autour d'une courbe fermee {gamma}. Lorsque la transformation rotationnelle L/2{pi} est voisine d'un nombre entier k, si certaines relations ne sont pas satisfaites, les effets de courbure peuvent devenir tres importants. Quand la transformation rotationnelle est cree par les courants circulant dans le plasma ceci se produit si le coefficient a{sub k} du developpement en serie de Fourier de la courbure 1/R(s) de {gamma} est non nul. On trouve alors que l'influence du k-ieme coefficient devient preponderante et il possible de negliger les autres termes pour etudier le voisinage de la singularite d'equilibre correspondante. En developpant un systeme de coordonnees adapte il est alors possible de tenir compte des le premier ordre des effets de courbure. L' etude de l'equilibre conduit a introduire un parametre d

  3. A statistical analysis of electrical cerebral activity; Contribution a l'etude de l'analyse statistique de l'activite electrique cerebrale

    Energy Technology Data Exchange (ETDEWEB)

    Bassant, Marie-Helene

    1971-01-15

    The aim of this work was to study the statistical properties of the amplitude of the electroencephalographic signal. The experimental method is described (implantation of electrodes, acquisition and treatment of data). The program of the mathematical analysis is given (calculation of probability density functions, study of stationarity) and the validity of the tests discussed. The results concerned ten rabbits. Trips of EEG were sampled during 40 s. with very short intervals (500 μs). The probability density functions established for different brain structures (especially the dorsal hippocampus) and areas, were compared during sleep, arousal and visual stimulus. Using a Χ{sup 2} test, it was found that the Gaussian distribution assumption was rejected in 96.7 per cent of the cases. For a given physiological state, there was no mathematical reason to reject the assumption of stationarity (in 96 per cent of the cases). (author) [French] Le but de ce travail est d'etudier les proprietes statistiques des amplitudes du signal electroencephalographique. La methode experimentale est decrite (implantation d'electrodes, acquisition et traitement des donnees). Le programme d'analyse mathematique est precise (calcul des courbes de repartition statistique, etude de la stationnarite du signal) et la validite des tests, discutee. Les resultats de l'etude portent sur 10 lapins. Des sequences de 40 s d'EEG sont echantillonnees. La valeur de la tension est prelevee a un pas d'echantillonnage de 500 μs. Les courbes de repartition statistiques sont comparees d'une region de l'encephale a l'autre (l'hippocampe dorsal a ete specialement analyse) ceci pendant le sommeil, l'eveil et des stimulations visuelles. Le test du Χ{sup 2} rejette l'hypothese de distribution normale dans 97 pour cent des cas. Pour un etat physiologique donne, il n'existe pas de raison mathematique a ce que soit repoussee l'hypothese de stationnarite, ceci dans 96.7 pour cent des cas. (auteur)

  4. Study of liquid hydrogen and liquid deuterium cold neutron sources; Etude de sources de neutrons froids a hydrogene et deuterium liquides

    Energy Technology Data Exchange (ETDEWEB)

    Harig, H D [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-12-01

    In view of the plant of the cold neutron source for a high flux reactor (maximal thermal flux of about 10{sup 15} n/cm{sup 2}s) an experimental study of several cold sources of liquid hydrogen and liquid deuterium has been made in a low power reactor (100 kW, about 10{sup 12} n/cm{sup 2}s). We have investigated: -cold neutron sources of liquid hydrogen shaped as annular layers of different thickness. Normal liquid hydrogen was used as well as hydrogen with a high para-percentage. -Cold neutron sources of liquid deuterium in cylinders of 18 and 38 cm diameter. In this case the sources could be placed into different positions to the reactor core within the heavy water reflector. This report gives a general description of the experimental device and deals more detailed with the design of the cryogenic systems. Then, the measured results are communicated, interpreted and finally compared with those of a theoretical study about the same cold moderators which have been the matter of the experimental investigation. (authors) [French] En vue de l'installation d'une source a neutrons froids dans un reacteur a haut flux (flux thermique maximal environ 10{sup 15} n/cm{sup 2}s), nous avons fait une etude neutronique experimentale de differentes sources froides a hydrogene et a deuterium liquides aupres d'un reacteur a faible puissance (100 kW environ 10{sup 12} n/cm{sup 2}s). Nous avons etudie: des couches annulaires de differentes epaisseurs d'hydrogene liquide normal et d'hydrogene a grand pourcentage para, des cellules cylindriques de 18 et 38 cm de diametre, remplies de deuterium liquide et placees a differentes positions dans le reflecteur D{sub 2}O. Ce travail traite l'implantation de l'installation cryogenique et donne une description generale de l'experience. L'interpretation des resultats fait etat entre autres d'une comparaison entre l'experience et une etude theorique portant sur les memes moderateurs. (auteurs)

  5. Thermodynamic modelling of the extraction of nitrates of lanthanides by CMPO and by CMPO-like calixarene in concentrated nitric acid medium. Application in the optimization of the separation of lanthanides and actinides/lanthanides; Modelisation thermodynamique de l'extraction de nitrates de lanthanides par le CMPO et par un calixarene-CMPO en milieu acide nitrique concentre. Application a l'optimisation de la separation des lanthanides et des actinides/lanthanides

    Energy Technology Data Exchange (ETDEWEB)

    Belair, S

    2003-07-01

    The separation minor actinides / lanthanides in nitric acid medium is as one of problems of separative chemistry the most delicate within the framework of the processes allowing the recovery of long life radioelements present in the solutions of fission products. Previous studies showed that CMPO-substituted calix[4]arenes presents a better affinity for actinides than for lanthanides. To optimize the operating conditions of separation and to take into account the degree of non-ideality for the concentrated nitric solutions, we adopted a thermodynamic approach. The methodology taken to determine the number and the stoichiometry of the complexes formed in organic phase base on MIKULIN-SERGIEVSKII's model used through a software of data processing of experimental extraction isotherms. These tools are exploited at first on an extraction system engaging the CMPO, extractant reagent of actinides and lanthanides in concentrated nitric medium. The modelling of the system Ln(NO{sub 3}){sub 3}-HNO{sub 3}-H{sub 2}O/CMPO comes to confirm the results of several studies. At the same time, they allow to establish working hypotheses aiming at limiting the investigations of our researches towards the most stable complexes formed between lanthanides and CMPO-like calixarene to which the same method is then applied. An analytical expression of the selectivity of separation by the calixarene is established to determine the parameters and physico-chemical variables on which it depends. So, the ratio of the constants of extraction and the value of the activity of water of the system fixes the selectivity of separation of 2 elements. The exploitation of this relation allows to preview the influence of a variation of the concentration of nitric acid. Experiments of extraction confirm these forecasts and inform about the affinity of the calixarene with respect to lanthanides elements and to the americium. (author)

  6. Experimental study of the radio-active contamination of certain cultivated plants by irrigation water; Etude experimentale de la contamination radioactive par l'eau d'irrigation de certaines plantes cultivees

    Energy Technology Data Exchange (ETDEWEB)

    Michon, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires; Barbier, G.; Le Blaye, P.; Brossard, M. [Station Centrale d' Agronomie, 78 - Versailles (France); Fioramonti, S.; Marty, J.R. [Station Agronomique de Toulouse, 31 (France); Benard, P.; Flanzy, M. [Station Centrale de Technologie des Produits Vegetaux, 11 - Narbonne (France); Delas, J.; Delmas, J.; Demias, Ch. [Station d' Agronomie de Bordeaux (Pont de la Maye), 33 (France); Huguet, C. [Station Agronomique d' Avignon, 84 (France)

    1964-07-01

    This report follows on to the CEA reports no 1860 and 2159 and gives the results obtained during the years 1961 and 1962. These results confirm for the most part those obtained previously and deal also with a larger variety of vegetables. Vines and artificial prairies were also dealt with during the course of this work. The large dispersion of the limiting values of the coefficient r (the ratio between the amount of radio-elements in a kilogram of product harvested, to the amount of radio-elements present in a litre of irrigation water) with different types of soil, different plant types, etc... , makes it impossible to draw any general conclusions. Each case of rejection requires a special study of which the outlive is given. At all events it is to be expected that in the majority of cases these studies will lead to a decrease in the norms now in force. (authors) [French] Ce rapport fait suite aux rapports CEA no 1860 et 2159 et rapporte les resultats obtenus pendant les annees 1961 et 1962. Ces resultats confirment dans l'ensemble ceux precedemment obtenus tout en augmentant la variete des legumes etudies. La vigne et les prairies artificielles ont egalement fait l'objet d'etudes. La grande dispersion des valeurs limites du coefficient r (rapport entre la quantite de radioelements dans un kg de produits recoltes a la quantite de radioelements presente dans un litre d'eau d'irrigation) en rapport avec la nature des sols, le type vegetal, etc.., ne permet pas de degager de conclusions generales. Chaque cas de rejet necessite une etude particuliere dont le schema est donne. En tout etat de cause l'on doit s'attendre a ce que dans la plupart des cas ces etudes conduisent a une diminution des normes actuellement utilisees. (auteurs)

  7. Clinical and symptomatological study of pigs subjected to a lethal dose of integral gamma irradiation; Etude clinique et symptomatologique chez le porc soumis a une irradiation gamma totale a dose letale

    Energy Technology Data Exchange (ETDEWEB)

    Vaiman, M; Guenet, J -L; Maas, J; Nizza, P

    1966-05-01

    Results are reported from a clinical and haematological study on a Corsican species of pigs wholly exposed to an approximately lethal dose of {gamma} radiation. The aim of this work was to examine the changes in the irradiation syndrome of irradiation for pigs to make it thus possible to devise further experiments, in particular in the therapeutic field. The dose received was 285 rads (measured as the absorption in the vertical antero-posterior medial plane). Data are presented on cyto-haematological changes in the blood circulating immediately after irradiation, and followed up to death, and changes in the medullary cytology after irradiation. The clinical picture of lethal radiation injury in swine is described. (authors) [French] Les auteurs rapportent les resultats d'une etude clinique et hematologique chez des porcs de race corse irradies in toto a dose sensiblement letale. Le but de cette etude etait de connaitre l'evolution du syndrome aigu d'irradiation chez le porc et de permettre ainsi le developpement d'experimentations ulterieures, en particulier dans le domaine therapeutique. La dose delivree etait de 285 rad (en dose absorbee au niveau du plan median vertical anteroposterieur. L'etude a porte essentiellement: 1. Sur les modifications cyclo-hematologiques du sang circulant immediatement apres l'irradiation, pour les differentes lignees cellulaires; l'evolution de ces modifications a ete notee jusqu'a la mort; 2. Sur les modifications de la cytologie medullaire apres irradiation (evolution du myelogramme et essai d'evaluation de la cellularite de la moelle osseuse);: 3. Sur les signes cliniques, d'ailleurs tres discrets, observes chez les porcs apres irradiation. (auteurs)

  8. Studies of elements used in hertzian interferometry (millimetric waves). Measurement of the permittivity of a liquid dielectric; Etudes d'elements utilises en interferometrie hertzienne (ondes millimetriques). Mesure de la permittivite de dielectrique liquide

    Energy Technology Data Exchange (ETDEWEB)

    Dagai, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-12-01

    Study of some elements used in EHF interferometry (bond of millimeter waves). This study is about design of the following elements: horns, horns associated with lens, power separators: -) Study of assemblies allowing measurements of complex dielectric constants of liquids. These devices are used in free propagation about wave lengths {<=} 2 mm; -) Studied devices: Interferometer for 2 separated waves and Michelson's type interferometer; -) 4 liquids have been used: {epsilon}'{sub r} Octane from -50 to 70 C (-58 to 158 F), {epsilon}'{sub r} and {epsilon}'' [Monochlorobenzene at 22,8 C (73 F), Mixture of octane with 10,8 per cent citral at 22 C (72 F) and Benzene at 21 C (70 F)]. -) Precision obtained about measurements: {delta}{epsilon}'/{epsilon}' de 1 a 2%, {delta}{epsilon}''/{epsilon}'' de 4 a 6%.(author) [French] Etudes d'elements utilises en interferometrie hertzienne fonctionnant en ondes millimetriques. Cette etude porte sur la realisation des elements suivants: cornets, cornets associes aux lentilles, separateurs de puissance. Etudes des montages permettant les mesures de la constante dielectrique complexe des corps liquides. Ces montages fonctionnent en propagation libre, sur des longueurs d'onde inferieures ou egales a 2 millimetres. Les montages etudies sont: interferometre a deux ondes separees et interferometre du type Michelson. De plus 4 liquides ont ete etudies: {epsilon}'{sub r} octane de -50 a 70 C, {epsilon}'{sub r} et {epsilon}'' [monochlorobenzene a 22,8 C et melange octane avec 10,8 pour cent citral a 22 C, Benzene a 21 C]. Les precisions obtenues sur les mesures sont: {delta}{epsilon}'/{epsilon}' de 1 a 2 pour cent, {delta}{epsilon}''/{epsilon}'' de 4 a 6 pour cent.

  9. Clinical and symptomatological study of pigs subjected to a lethal dose of integral gamma irradiation; Etude clinique et symptomatologique chez le porc soumis a une irradiation gamma totale a dose letale

    Energy Technology Data Exchange (ETDEWEB)

    Vaiman, M.; Guenet, J.-L.; Maas, J.; Nizza, P

    1966-05-01

    Results are reported from a clinical and haematological study on a Corsican species of pigs wholly exposed to an approximately lethal dose of {gamma} radiation. The aim of this work was to examine the changes in the irradiation syndrome of irradiation for pigs to make it thus possible to devise further experiments, in particular in the therapeutic field. The dose received was 285 rads (measured as the absorption in the vertical antero-posterior medial plane). Data are presented on cyto-haematological changes in the blood circulating immediately after irradiation, and followed up to death, and changes in the medullary cytology after irradiation. The clinical picture of lethal radiation injury in swine is described. (authors) [French] Les auteurs rapportent les resultats d'une etude clinique et hematologique chez des porcs de race corse irradies in toto a dose sensiblement letale. Le but de cette etude etait de connaitre l'evolution du syndrome aigu d'irradiation chez le porc et de permettre ainsi le developpement d'experimentations ulterieures, en particulier dans le domaine therapeutique. La dose delivree etait de 285 rad (en dose absorbee au niveau du plan median vertical anteroposterieur. L'etude a porte essentiellement: 1. Sur les modifications cyclo-hematologiques du sang circulant immediatement apres l'irradiation, pour les differentes lignees cellulaires; l'evolution de ces modifications a ete notee jusqu'a la mort; 2. Sur les modifications de la cytologie medullaire apres irradiation (evolution du myelogramme et essai d'evaluation de la cellularite de la moelle osseuse);: 3. Sur les signes cliniques, d'ailleurs tres discrets, observes chez les porcs apres irradiation. (auteurs)

  10. Experimental study of the radio-active contamination of certain cultivated plants by irrigation water; Etude experimentale de la contamination radioactive par l'eau d'irrigation de certaines plantes cultivees

    Energy Technology Data Exchange (ETDEWEB)

    Michon, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires; Barbier, G; Le Blaye, P; Brossard, M [Station Centrale d' Agronomie, 78 - Versailles (France); Fioramonti, S; Marty, J R [Station Agronomique de Toulouse, 31 (France); Benard, P; Flanzy, M [Station Centrale de Technologie des Produits Vegetaux, 11 - Narbonne (France); Delas, J; Delmas, J; Demias, Ch [Station d' Agronomie de Bordeaux (Pont de la Maye), 33 (France); Huguet, C [Station Agronomique d' Avignon, 84 (France)

    1964-07-01

    This report follows on to the CEA reports no 1860 and 2159 and gives the results obtained during the years 1961 and 1962. These results confirm for the most part those obtained previously and deal also with a larger variety of vegetables. Vines and artificial prairies were also dealt with during the course of this work. The large dispersion of the limiting values of the coefficient r (the ratio between the amount of radio-elements in a kilogram of product harvested, to the amount of radio-elements present in a litre of irrigation water) with different types of soil, different plant types, etc... , makes it impossible to draw any general conclusions. Each case of rejection requires a special study of which the outlive is given. At all events it is to be expected that in the majority of cases these studies will lead to a decrease in the norms now in force. (authors) [French] Ce rapport fait suite aux rapports CEA no 1860 et 2159 et rapporte les resultats obtenus pendant les annees 1961 et 1962. Ces resultats confirment dans l'ensemble ceux precedemment obtenus tout en augmentant la variete des legumes etudies. La vigne et les prairies artificielles ont egalement fait l'objet d'etudes. La grande dispersion des valeurs limites du coefficient r (rapport entre la quantite de radioelements dans un kg de produits recoltes a la quantite de radioelements presente dans un litre d'eau d'irrigation) en rapport avec la nature des sols, le type vegetal, etc.., ne permet pas de degager de conclusions generales. Chaque cas de rejet necessite une etude particuliere dont le schema est donne. En tout etat de cause l'on doit s'attendre a ce que dans la plupart des cas ces etudes conduisent a une diminution des normes actuellement utilisees. (auteurs)

  11. Processing radioactive effluents with ion-exchanging resins: study of result extrapolation; Traitement des effluents radioactifs par resines echangeuses d'ions: etude de l'extrapolation des resultats

    Energy Technology Data Exchange (ETDEWEB)

    Wormser, G.

    1960-05-03

    As a previous study showed the ion-exchanging resins could be used in Saclay for the treatment of radioactive effluents, the author reports a study which aimed at investigating to which extent thus obtained results could be extrapolated to the case of higher industrial columns. The author reports experiments which aimed at determining extrapolation modes which could be used for columns of organic resin used for radioactive effluent decontamination. He notably studied whether the Hiester and Vermeulen extrapolation law could be applied. Experiments are performed at constant percolation flow rate, at varying flow rate, and at constant flow rate [French] Plusieurs etudes ont ete faites dans le but d'examiner les possibilites d'emploi des resines echangeuses d'ions pour le traitement des effluents radioactifs. Dans un rapport preliminaire, nous avons montre dans quelles limites un tel procede pouvait etre utilise au Centre d'Etudes Nucleaires de Saclay. Les essais ont ete effectues sur des petites colonnes de resine au laboratoire; il est apparu ensuite necessaire de prevoir dans quelle mesure les resultats ainsi obtenus peuvent etre extrapoles a des colonnes industrielles, de plus grande hauteur. Les experiences dont les resultats sont exposes dans ce rapport, ont pour but de determiner les modes d'extrapolation qui pourraient etre employes pour des colonnes de resine organique utilisees pour la decontamination d'effluents radioactifs. Nous avons en particulier recherche si la loi d'extrapolation de Hiester et Vermeulen qui donne de bons resultats dans le cas de fixation d'ions radioactifs en presence d'un ion macrocomposant sur des terres, pouvait etre appliquee. Les experiences, en nombre limite, ont montre que la loi d'extrapolation de Hiester et Vermeulen pouvait s'appliquer dans le cas de l'effluent considere quand les debits de percolation sont tres faibles; quand ils sont plus forts, les volumes de liquide percoles, a fixation egale, sont proportionnels aux

  12. Niger Republic Mineral Planning : Part IV - first volume : Main mineral substances specific study and their geological context; Plan Mineral de la Republique du Niger : Tome IV - 1er volume : Etude specifique des principales substances minerals et leur contexte geologique

    Energy Technology Data Exchange (ETDEWEB)

    Franconi, Antoine; Joo' , Julien; Zibo, Idde

    1981-07-01

    This volume contains the detailed study of mineral substances industrially exploited to date : uranium, coal, non metallic building materials and public activities, and non conventionally exploited substances, that are : tin, columbite-tantalite, tungsten, gold, phosphates and evaporates. [French] Ce volume contient l'etude detaillee des substances minerals exploitees industriellement a ce jour : l'uranium, le charbon, les materiaux non metalliques de construction et de travaux publics et les substances exploitees artisanalement qui sont : l'etain, la Colombo-tantalite, le tungstene, l'or, les phosphates et les evaporates.

  13. Experimental study of contamination by inhalation of radioactive iodine aerosols. Biological balance; Etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif bilan biologique

    Energy Technology Data Exchange (ETDEWEB)

    Marble, G. [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Several articles have been published concerning research into contamination produced by inhalation of radioactive iodine aerosols in monkeys. Results dealing with the biological balance of this contamination are presented and discussed in this report. (author) [French] L'etude experimentale de la contamination par inhalation d'aerosols d'iode radioactif effectuee chez le singe a fait l'objet de plusieurs publications. Les resultats concernant le bilan biologique de cette contamination sont presentes et discutes dans ce rapport. (auteur)

  14. Etude de trois souches d'Arthrobotrys oligospora : Caractérisation biologique et effets sur Meloidogyne mayaguensis parasite de la tomate au Sénégal

    Directory of Open Access Journals (Sweden)

    Gueyei, M.

    1997-01-01

    Full Text Available Etude de trois souches d'Arthrobotrys oligospora : Caractérisation biologique et effets sur Meloidogyne mayaguensis parasite de la tomate au Sénégal. Three strains (ORS 18690 S2, ORS 18691 S6 and ORS 18693 S5 of the nematophagous fungus Arthrobotrys oligospora have been isolated in Senegal for the first time. In vitro, two strains (ORS 18690 S2 and ORS 18693 S5 of them trapped 100 % and the other (ORS 18691 S5 80 %> of 7-day-old juvenile Meloidogyne mayaguensis within 48h. Optimal growth occured at 25-30°C and at a pH 5.6, but salinity inhibited development. In order to test the ability of fungi to control M. mayaguensis in pots on tomato, the fungus was incorporated into compost blocks or in vermiculite before sowing or subsequent transplanting. In pot experiments both strains reduced nematode populations ans stimulated seedling growth. However, these effects were higher in compost blocks than in vermiculite.

  15. Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

    Energy Technology Data Exchange (ETDEWEB)

    Hasselin, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

  16. Studies on solid-state physics carried out with the Saclay reactor (1962); Etudes de physique du solide realisees a la pile de Saclay (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Herpin, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    This paper deals only with solid-state physics experiments carried out on outgoing beams: rather than giving a general review of the work performed, if refers to only a few of the most important studies or those nearest completion. These are being made with the experimental beams of the two Saclay reactors EL-2, with a central flux of 10{sup 13} n/cm{sup 2}, and - since 1958 - EL-3, whose central flux is equal ta 10{sup 14} n/cm{sup 2}. The experiments are being carried out by two separate groups of physicists, employing different techniques, namely neutron diffraction using a crystal spectrometer, and inelastic scattering using a time-of-flight spectrometer. (author) [French] Cet expose ne relate que des experiences de physique du solide faites sur des faisceaux sortis; plutot que de donner une revue de l'ensemble des travaux effectues, on ne cite que quelques etudes que l'on peut considerer comme plus essentielles ou mieux achevees. On utilise les faisceaux experimentaux des deux piles de Saclay, EL-2 dont le flux au centre est de 10{sup 13}n/cm{sup 2} et, depuis 1958, EL-3 pour laquelle il est egal a 10{sup 14} n/cm{sup 2}. Les experiences sont realisees par deux groupes de physiciens distincts, employant des techniques differentes, la diffraction des neutrons qui utilise un spectrometre a cristal, et la diffusion inelastique avec un spectrometre a temps de vol. (auteur)

  17. Study of the acceptance of a constant gradient synchrotron (1960); Etude de l'acceptance d'un synchrotron a gradient constant (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Bronca, G; Gendreau, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    This paper is a synthesis of the work of H. Bell and E. Persico; a detailed analysis is given of the phenomena which occurs at the time of injection (collision against the back of the inflector, overshooting of the 'useful zone'; collision against the horizontal walls of the chamber) and of capture (assumed to be fast) in a faultless machine. The maximum number of particles which may be injected and captured is determined as a function of various parameters: emittance of the beam injected, radial position of the inflector, synchronous phase or peak HF voltage. A final limitation due to the transverse space charge is then recalled, and lastly conclusions are drawn from the results with particular reference to Saturn. (author) [French] Cette etude est une synthese du travail de H. BELL et E. PERSICO; on analyse en detail les phenomenes a l'injection (choc contre le dos inflecteur, depassement de 'zone utile', choc contre les parois horizontales de la chambre) et a la capture (supposee rapide) pour une machine sans defaut. On determine le nombre maximum de particules injectables et capturables en fonction de divers parametres: emittance du faisceau injecte, position radiale de l'inflecteur, phase synchrone ou tension crete HF. Puis, on rappelle une derniere limitation due a la charge d'espace transversale et enfin les conclusions qu'on tire des resultats en ce qui concerne plus particulierement Saturne. (auteur)

  18. Physical activity patterns in the French 18-74-year-old population: French Nutrition and Health Survey (Etude Nationale Nutrition Santé, ENNS) 2006-2007.

    Science.gov (United States)

    Salanave, Benoit; Vernay, Michel; Szego, Emmanuelle; Malon, Aurélie; Deschamps, Valérie; Hercberg, Serge; Castetbon, Katia

    2012-11-01

    To describe detailed physical activity and sedentary behaviour in French adults across physical activity categories. The French Nutrition and Health Survey (Etude Nationale Nutrition Santé, ENNS), conducted in 2006-2007, was a national cross-sectional survey based on three-stage random sampling. The International Physical Activity Questionnaire (IPAQ) was used to classify participants into three physical activity categories. Time spent in a sitting position and time spent in front of a screen were used as markers of sedentary behaviour. France. Adults (n 2971) aged 18 to 74 years were included. Overall, 29·5 % of men and 23·6 % of women were classified into the high-IPAQ category, while 36·1 % of men and 37·5 % of women were in the low-IPAQ category. For each intensity level of physical activity (vigorous intensity, moderate intensity or walking), the number of active days per week decreased from the high- to the low-IPAQ category and daily duration of physical activity was longer in the high-IPAQ category than in the other two categories; 6 % of adults declared neither vigorous nor moderate nor walking activities. For most adults in the low-IPAQ category, an increasing number of active days per week would be sufficient to attain the moderate-IPAQ category. This should be taken into account in public health initiatives aimed at promoting physical activity.

  19. Smoking Trajectories during the Perinatal Period and Their Risk Factors: The Nationally Representative French ELFE (Etude Longitudinale Française Depuis l'Enfance) Birth Cohort Study.

    Science.gov (United States)

    El-Khoury, Fabienne; Sutter-Dallay, Anne-Laure; Van Der Waerden, Judith; Surkan, Pamela; Martins, Silvia; Keyes, Katherine; de Lauzon-Guillain, Blandine; Charles, Marie-Aline; Melchior, Maria

    2017-01-01

    In France, rates of perinatal smoking are among the highest worldwide; however, perinatal smoking trajectories and associated factors have still not been adequately researched. Among women participating in the French nationally representative etude longitudinale française depuis l'enfance birth cohort (n = 15,540), perinatal smoking trajectories were estimated using group-based modelling. Associated characteristics were studied using multinomial logistic regression. Four trajectories were identified: non-smokers (59%), quitters (20%), persistent moderate (12%) and persistent heavy (9%) smokers. Older age, being native French, low socioeconomic position, persistent psychological difficulties and alcohol use in pregnancy, lack of social support, partner's smoking, mistimed pregnancy, and child formula feeding at birth were associated with persistent heavy smoking. Most of these factors were also associated, but to a lesser extent, with persistent moderate smoking, except for age and migrant status, which had opposite effects. Women who successfully lost weight prior to pregnancy had higher levels of quitting smoking. Women's long-term smoking trajectories vary in terms of initial tobacco consumption level but also in relation to socio-demographic, psychological, behavioral and partner characteristics. Health professionals in contact with pregnant smokers should address perceived risks and benefits of smoking, including partner's smoking and weight-gain concerns. © 2017 S. Karger AG, Basel.

  20. A microcosm of musical expression. I. Quantitative analysis of pianists' timing in the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1998-08-01

    Patterns of expressive timing were measured in bars 1-5 of 115 commercially recorded performances of Chopin's Etude in E major, op. 10, No. 3. These patterns were subjected to principal components analysis, which suggested at least four independent "timing strategies": (1) major ritards at the ends of melodic gestures; (2) acceleration within some of these gestures, without final ritards; (3) extreme lengthening of the initial downbeat; and (4) ritards between as well as within melodic gestures. Strategies 1 and 4 respond in different ways to the melodic-rhythmic grouping structure of the music, and strategy 3 merely represents a local emphasis. Strategy 2 is the one most difficult to rationalize; it does not seem to represent an alternative structural interpretation of the music but rather an alternative gestural shaping. Each individual pianist's timing pattern could be described as a weighted combination of these four strategies plus idiosyncratic variation. A wide variety of combinations was represented, and no two individual patterns were exactly the same. In addition, there was a wide range of basic tempi and of degrees of tempo modulation. There were no strong relationships between any of these variables and sociocultural characteristics of the artists, although some weak trends were observed.

  1. A microcosm of musical expression. III. Contributions of timing and dynamics to the aesthetic impression of pianists' performances of the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1999-07-01

    Four judges repeatedly assessed the overall aesthetic quality of more than 100 recorded performances of the opening of Chopin's Etude in E major on a 10-point scale. The judgments, which exhibited reasonable reliability and modest intercorrelations, were entered into regression analyses with 16 independent variables derived from earlier objective analyses of the expressive timing and dynamics of the performances [Repp, J. Acoust. Soc. Am. 104, 1085-1100 (1998); 105, 1972-1988 (1999)]. Only between 9% and 18% of the variance in the judges' ratings was accounted for. By contrast, timing variables accounted for 53% of the variance in one judge's ratings of synthesized performances that varied in timing only and mimicked the timing patterns of the original performances. These results indicate, first, that the aesthetic impression of the original recordings rested primarily on aspects other than those measured (such as texture, tone, or aspects of timing and dynamics that eluded the earlier analyses) and, second, that very different patterns of timing and dynamics are aesthetically acceptable for the same music, provided that other, aesthetically more crucial performance aspects are present.

  2. A microcosm of musical expression: II. Quantitative analysis of pianists' dynamics in the initial measures of Chopin's Etude in E major.

    Science.gov (United States)

    Repp, B H

    1999-03-01

    Patterns of expressive dynamics were measured in bars 1-5 of 115 commercially recorded performances of Chopin's Etude in E major, op. 10, No. 3. The grand average pattern (or dynamic profile) was representative of many performances and highly similar to the average dynamic profile of a group of advanced student performances, which suggests a widely shared central norm of expressive dynamics. The individual dynamic profiles were subjected to principal components analysis, which yielded Varimax-rotated components, each representing a different, nonstandard dynamic profile associated with a small subset of performances. Most performances had dynamic patterns resembling a mixture of several components, and no clustering of of performances into distinct groups was apparent. Some weak relationships of dynamic profiles with sociocultural variables were found, most notably a tendency of female pianists to exhibit a greater dynamic range in the melody. Within the melody, there were no significant relationships between expressive timing [Repp, J. Acoust. Soc. Am. 104, 1085-1100 (1998)] and expressive dynamics. These two important dimensions seemed to be controlled independently at this local level and thus offer the artist many degrees of freedom in giving a melody expressive shape.

  3. Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

    Energy Technology Data Exchange (ETDEWEB)

    Hasselin, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

  4. Collection and processing of information in biological kinetics studies with radioactive tracers; Collecte et traitement de l'information dans les etudes de cinetique biologique avec traceurs radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Remy, J; Lafuma, J [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    The authors present an automatic method for the collection and treatment of information in biological kinetics experiments using radioactive tracers. The recording are made without any time constant on magnetic tape. The information recorded is sampled by a 400 channel multi-scale analyzer and transferred to punched cards. The digital analysis is done by an I.B.M. computer. The method is illustrated by an example: the hepatic fixation of colloidal gold in the pig. Its advantages and requirements are discussed. In the appendix are given the FORTRAN texts for two programmes used in treating the example presented. (authors) [French] Les auteurs presentent une methode automatique de collecte et de traitement de l'information dans les experiences de cinetique biologique utilisant les traceurs radioactifs. Les enregistrements sont realises sans constante de temps sur bande magnetique. L'information enregistree fait l'objet d'un echantillonnage a l'aide d'un analyseur a 400 canaux en mode multi-echelle puis est transferee sur cartes perforees. L'exploitation digitale est confiee a un ordinateur I.B.M.. La methode est illustree par un exemple d'etude de la fixation hepatique de l'or colloidal chez le porc. Ses avantages et ses exigences sont discutes. En annexe figurent les textes en FORTRAN de deux programmes utilises pour le traitement de l'exemple cite. (auteurs)

  5. Design and construction of a faraday cup for measuring small electron currents; Etudes et realisation d'une ''coupe de faraday'' pour les mesures de faibles courants electroniques

    Energy Technology Data Exchange (ETDEWEB)

    Veyssiere, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    This paper describes the design of a device for measuring and integrating very small currents generated by the impact of a charged particle beam upon a Faraday cup. Part one considers the detector as such. The main component is a graphite bloc capable of stopping practically all the incident charges. Part two describes the associated electrode apparatus required to measure better than 10{sup -13} ampere with a precision- of 1 per cent: Integration of such weak currents over periods of several hours, in the presence of a strong background current, is also discussed. (author) [French] Ce rapport decrit l'etude et la realisation d'un ensemble permettant de mesurer et d'integrer sur des periodes de plusieurs heures des courants electroniques tres faibles provenant d'un faisceau de particules chargees, Dans la premiere partie du rapport nous etudierons le capteur proprement dit qui se compose essentiellement d'un bloc de graphite dont la forme et les dimensions sont telles, que la majeure partie des charges (positons et negatons de 60 MeV) est captee (1 pour mille reussissent a s'echapper). Dans la deuxieme partie nous decrivons l'appareillage associe au capteur capable de mesurer moins de 10{sup -13} ampere avec une precision de l'ordre du pour cent et d'integrer ce courant sur des periodes de temps variables, compte tenu de l'ambiance 'bruyante' (Accelerateur Lineaire) dans laquelle la mesure s'effectue. (auteur)

  6. Study of the improvement of the radioprotective power of imidazole; Etude de l'amelioration du pouvoir radioprotecteur de l'imidazole

    Energy Technology Data Exchange (ETDEWEB)

    Mourret, A; Rinaldi, R [Commissariat a l' Energie Atomique, 38 - Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    In studies made on the Imidazole radioprotective power, the authors have attempted to neutralize its convulsive properties by the Depamide so as to decrease drug toxicity. Then, having studied in what manner the two products simultaneous action could carry one increase of radioprotective activity, they have established that if the Depamide permits to decrease very much the Imidazole toxicity, the variation of radioprotection power which is subject to animal sex, generally increases for females and decreases for males. (authors) [French] Dans le cadre de l'etude du pouvoir radioprotecteur de l'Imidazole, les auteurs ont essaye de neutraliser les proprietes convulsivantes de cette substance par le Depamide afin d'en dimunuer la toxicite. Ayant ensuite etudie dans quelle mesure l'action simultanee de ces deux produits pouvait apporter une amelioration de l'activite radioprotectrice, ils ont constate que si le Depamide permet de diminuer tres sensiblement la toxicite de l'Imidazole, la variation du pouvoir radioprotecteur, qui depend du sexe de l'animal, augmente en general pour les femelles et diminue pour les males. (auteurs)

  7. Study of the molecular structure of uranium hexafluoride; Contribution a l'etude de la structure moleculaire de l'hexafluorure d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Bougon, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-01

    The vibrational spectrum of uranium hexafluoride has been studied in both the gaseous and solid states. The study of gaseous UF{sub 6} confirms the regular octahedral structure of the fluorine atoms around the central U atom and makes it possible to evaluate some of the vibrational frequencies. From these, some new force constants have been determined. A tetragonal distortion is observed on solid UF{sub 6}; this distortion has only observed up till now by means of X-ray diffraction and nuclear magnetic resonance techniques. (author) [French] Le spectre de vibration de l'hexafluorure d'uranium UF{sub 6} est etudie sous les formes gazeuse et solide. L'etude de l'UF{sub 6} gaz confirme la structure d'octaedre regulier d'atomes de fluor autour de l'atome central d'uranium et apporte une precision sur certaines frequences de vibration. A partir de ces valeurs, de nouvelles determinations de constantes de force ont ete realisees. L'observation de UF{sub 6} solide confirme la deformation tetragonale de l'octaedre, deformation observee jusqu'a present par les seules methodes de resonance magnetique nucleaire et diffraction des rayons X. (auteur)

  8. Electron microscope study of irradiated beryllium oxide; Etude au microscope electronique de l'oxyde de beryllium irradie

    Energy Technology Data Exchange (ETDEWEB)

    Bisson, A A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-06-01

    utilisant des echantillons frittes. Les fractures sont examinees sous differents aspects. Ce sont les frittes les plus denses a fractures intragranulaires qui sont les plus interessants pour l'etude microscopique. Le 'pore' resultant du frittage est differencie de la 'bulle' qui peut se former au cours de traitements thermiques ulterieurs par suite de reactions donnant naissance a des gaz. Apres irradiation, la fragilisation intergranulaire est importante. Par recuit, on suit l'evolution des gaz, produits par les reactions (n. 2n) et (n, {alpha}), qui s'accumulent aux joints de grains. L oxyde de beryllium irradie est ensuite etudie par transmission. Pour cela, une methode simple a ete mise au point; elle consiste a examiner les eclats de cristaux broyes. Les amas de defauts ponctuels, formes par les neutrons, sont ainsi mis en evidence dans les cristaux irradies aux trois doses suivantes: 6.10{sup 19}, 9.10{sup 19} et 2.10{sup 20} n{sub r}.cm{sup -2} a une temperature inferieure a 100 deg. C. Pour l'irradiation a 6.10{sup 19} n{sub r}.cm{sup -2} les defauts sont a peine visibles mais a 2.10{sup 20} n{sub r}.cm{sup -2} les cristaux sont cribles d'amas alors que les lignes de Kikuchi ont disparu des diagrammes de microdiffraction. L'evolution des amas de defauts en boucles de dislocation est etudiee par des recuits successifs. L'energie d'activation de 0.37 eV, calculee a partir des courbes de recuits, incite a penser que ce sont les defauts interstitiels qui se condensent en boucles de dislocation. Des echantillons irradies a haute temperature sont egalement etudies (650, 900 et 1100 deg. C). Dans ceux-ci les boucles de dislocation atteignent un etat d'equilibre different de celui des precedentes. Ces dernieres boucles de dislocation sont etudiees plus specialement et leur vecteur de Burgers est determine par microdiffraction. (auteur)

  9. Study of U - Pu - Fe alloys (Masurca critical experiment); Etudes d'alliages U-Pu-Fe (experience critique MASURCA)

    Energy Technology Data Exchange (ETDEWEB)

    Barthelemy, P; Boucher, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    pour ces deux dernieres teneurs le passage du point de transformation (595 et 590 deg. C respectivement) entraine une deterioration rapide et complete des echantillons sous air. Les essais d'inflammabilite sous air montrent que la temperature de debut d'oxydation se situe vers 250 deg. C et que la reaction ne s'entretient pas d'elle-meme. On n'a pas observe d'inflammation proprement dite lors d'une montee jusqu'a 660 deg. C. L'etude dilatometrique a permis de determiner la temperature de transformation a l'etat solide, la temperature de fusion commencante et les coefficients de dilatation. En dessous de la transformation les alliages sont formes principalement des phases U-Pu zeta et (U, Pu){sub 6}Fe. La conductibilite thermique, le module d'Young, la densite et la chaleur de fusion ont ete mesures. les essais de compatibilite U-Pu-Fe{approx}acier inox NS 22 S montrent qu'au contact des deux alliages se forme une phase du type (U,Pu){sub 6}Fe. L'alliage a 1% de fer parait preferable, la phase (U,Pu){sub 6}Fe formee a l'interface etant 2 a 3 fois moins etendue qu'avec l'alliage a 1,5% de fer. Enfin le probleme de la stabilite thermique a temperature peu elevee a ete considere pour l'alliage a 1% de fer. Le passage du point de transformation a 595 deg. C entraine l'apparition d'une anomalie dilatometrique, au refroidissement, se traduisant par une tres faible dilatation dont l'amplitude diminue en fonction du nombre de cycles effectues entre 20 et 650 deg. C sur l'alliage brut de coulee a l'origine. Par contre, des cyclages thermiques entre 50 et 400 deg. C montrent que les alliages ne presentent pas d'anomalie et sont stables. De meme, des maintiens de 5 mois a 100 deg. C, 200 deg. C, 300 deg. C, sous vide, n'entrainent aucune alteration des alliages. (auteurs)

  10. Contribution to the experimental study of wave particle interactions in a plasma having a two-population electronic distribution function; Contribution a l'etude experimentale de l'interaction ondes-particules dans un plasma presentant une fonction de distribution electronique a deux populations

    Energy Technology Data Exchange (ETDEWEB)

    Frank, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The aim of this work is the experimental study of the interaction between electrostatic waves and electrons in a plasma characterized by a so called 'bump in tail' distribution function. To study experimentally the mechanism of this interaction it is necessary to measure precisely the electron distribution and its evolution in space or in time. This was performed with an electrostatic separation probe which was designed especially. We measured also the evolution in space and time of the noise spectrum. We studied this mechanism in two different regimes of our discharge: - In the first case the distribution function is very close to that describing the interaction of a semi-infinite plasma with a cold beam injected at its edge. We showed that the instability resulting from this interaction is convective and that the growth of the waves results in a very important modification of the distribution function. The ionization due to the electric field related to the waves is also important. This modification is similar to that described by the quasi linear theory. The mechanism described by this theory remains then qualitatively valid in a strongly non linear case. - In the second case the conditions necessary for the quasi linear theory to be valid are satisfactorily fulfilled. It is then possible to measure, simultaneously, and precisely, the evolution of the distribution function and of the noise spectrum. From these measurements one can deduce the mechanism of the energy exchange between waves and particles and show that it is in good agreement with that described by the quasi linear theory. (author) [French] On presente ici l'etude experimentale detaillee du mecanisme de l'echange d'energie entre les oscillations e la frequence plasma des electrons et des electrons energetiques dans un plasma presentant une fonction de distribution du type a 'double bosse'. Pour realiser cette etude on a mis au point, une 'sonde a separation electrostatique' qui permet de mesurer

  11. Use of the classical approximation in quantum electrodynamics; Applications de l'approximation classique en electrodynamique quantique

    Energy Technology Data Exchange (ETDEWEB)

    Brezin, Edouard

    1970-06-22

    Approximations commonly used in the study of the classical limit of quantum mechanics are applied, with justification, to quantum electrodynamics. First, the infrared divergence in the scattering of two charged particles is examined with the help of a remarkable series of Feynman diagrams, which in particular preserves gauge invariance and a correct static limit. Looking for the poles in energy of the scattering amplitude, a formula for the binding energies of two charged particles, which generalizes the Balmer formula and takes into account the correct relativistic kinematics, has been derived. A second type of applications concerns phenomena due to the interaction of the electromagnetic field with the vacuum current and charge fluctuations. For instance, when the intensities become very high, the theory predicts the creation of electron-positron pairs by the field. The creation rate is known in the limit of static fields, and the aim of these calculations was to demonstrate the role of frequency in the domain starting from the lowest frequencies up to X-rays. The pair production rate was found to be entirely negligible, even for the most intense laser beams. An increase in frequency, even up to several tens of keV, did not have any effect on the pair production. (author) [French] Des approximations habituellement reservees a l'etude de la limite classique de la mecanique quantique sont ici appliquees, apres justification, a l'electrodynamique quantique. En premier, l'etude de la divergence infrarouge dans la diffusion de deux particules chargees est conduite a l'aide d'une serie de diagrammes de Feynman possedant des proprietes remarquables, en particulier l'invariance de jauge et une limite statique correcte. De la est obtenue, en recherchant les poles dans la variable d'energie de l'amplitude de diffusion, une expression des energies de liaison de deux particules chargees tenant compte exactement de la cinematique relativiste et generalisant la formule de

  12. Application of radioactivity to subterranean hydraulic engineering (1961); Application de la radioactivite a l'hydraulique souterraine (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Hours, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    The search for radioactive tracers for water capable of percolating through permeable grounds without significant absorption has led to the choosing of two isotopes, bromine 82 (half-life 36 hours) and iodine (half-life 8 days), both {gamma} emitters; various combinations of other {gamma} emitters with longer half-lives have been tried but with only partial success. The recent progress in the dosage of tritium should make it possible to widen the field of application of this tracer which is unique in its kind. Being detectable at concentrations of 10{sup -6} to 10{sup -8} curies per cubic meter, the radioactive tracers are suitable for all the usual applications of conventional tracers; furthermore, some original techniques have been devised for measurements of flow, of reservoir capacity, of porosity and of permeability. Techniques based on the absorption and scattering of {gamma}-rays have also been developed for the measurement of the density, the humidity and the porosity of soils, and also for their analysis. Up to the present, radioactivity has been mainly applied to the study of oil-bearing formations. Furthermore, the study of the distribution of natural of thermonuclear tritium has contributed greatly to the study of the hydrological cycle. (author) [French] La recherche de traceurs radioactifs de l'eau susceptibles de circuler a travers les terrains permeables sans retention notable a abouti a la selection de deux isotopes, le brome 82 (periodes 36 heures) et l'iode (periode 8 jours), tous deux emetteurs {gamma}; diverses combinaisons mettant en jeu des emetteurs {gamma} de periode plus longue ont ete essayees, mais avec un succes partiel. Les progres recemment accomplis dans le dosage du tritium doivent permettre une rapide extension de l'emploi de ce traceur unique en son genre. Decelables a des concentrations de 10{sup -6} a 10{sup -8} curies par metre cube, les traceurs radioactifs se pretent a toutes les applications des traceurs classiques; de plus

  13. Genetic cytological and biochemical study of a tomato chlorophyll mutant of the xanthic type, obtained by irradiation of the seeds; Etude genetique, cytologique et biochimique d'un mutant chlorophyllien de tomate du type xantha, obtenu par irradiation de graines

    Energy Technology Data Exchange (ETDEWEB)

    Lefort, M; Duranton, J; Galmiche, J M; Roux, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Irradiation of Lycopersicum aesculantum seeds with increasing doses of X-rays and thermal neutrons leads to the appearance of chlorophyll mutations in the descendants of the irradiated seeds. A genetic study of one of these mutants of the xanthic type showed that it was a recessive mutant with typical mono-genetic separation, while the cytological study demonstrated that the differentiation of the plast stopped at the stage of elementary lamella. Finally it is shown that in the light, the mutation brings about a very large deviation of the carbon metabolism towards the synthesis of amino acids and proteins, at the expense of that of glucosides. (author) [French] L'irradiation de graines de Lycopersicum Aesculantum avec des doses croissantes de rayons X et de neutrons thermiques entraine l'apparition de mutations chlorophylliennes dans la descendance des graines irradiees. L'etude genetique d'un de ces mutants du type xantha a montre qu'il s'agissait d'un mutant recessif a disjonction monogenique typique, tandis que l'etude cytologique a revele que la differentiation du plaste s'arretait au stade de lamelles elementaires. Il est apparu enfin qu'a la lumiere la mutation entrainait une deviation tres importante du metabolisme du carbone vers la synthese des acides amines et des proteines, au detriment de celle des glucides. (auteur)

  14. Syntheses and study of pyrrolidinic nitroxide free radicals. Preparation of a nitroxide-type stable bi-radical; Synthese et etudes de radicaux libres nitroxydes pyrrolidiniques. Preparation d'un biradical stable du type nitroxyde

    Energy Technology Data Exchange (ETDEWEB)

    Dupeyre, R M [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires, Laboratoire de chimie organique physique

    1967-12-01

    Syntheses and study of pyrrolidinic nitroxide free radicals: These radicals are obtained by oxidation, with hydrogen peroxide, of pyrrolidinic amines prepared from triacetonamine by ring contraction. The U. V,, I. R, and E.P.R. spectral characteristics have been determined. The oxidation of these amines with hydrogen peroxide has led also to rupture of the pentagonal ring; some of the decomposition products have been identified. The high chemical stability of the nitroxide group has made it possible to synthesize and study a stable bi-radical. (author) [French] Syntheses et etudes de radicaux libres nitroxydes pyrrolidiniques: Ces radicaux sont obtenus par oxydation l'eau oxygenee d'amines pyrrolidiniques preparees a partir de la triacetonamine par contraction de cycle. Les caracteristiques spectroscopiques ultra-violettes, infra-rouge et resonance paramagnetique sont determinees. Cependant, 1'oxydation de ces amines a l'eau oxygenee a entraine la coupure du cycle pentagonal et identification de certaines substances de decomposition obtenues. La grande stabilite chimique de groupement nitroxyde a permis la synthese et l'etude d'un biradical stable. (auteur)

  15. Development of an analogue multiplexed regulation for periodic 1. order delayed processes; Etude et realisation d'une regulation analogique multiplexee pour processus aperiodiques du 1. ordre avec retard pur

    Energy Technology Data Exchange (ETDEWEB)

    Amblard, J C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-15

    The present note deals with the study regulations of the sampled type, for 1. order process with simple delay. In order to obtain a good stability in such regulations, together with acceptable performances, it is interesting to use polynomial type correctors acting directly on the sampled error signals. The active elements of these correctors can be shared by all the channels to be controlled. Furthermore, the determination of the correction parameters results from an optimal study of the system. In the second part is described the construction of a multiplexed regulation for diffusion ovens. (author) [French] La presente note concerne l'etude des regulations de type echantillonne, pour processus du 1. ordre avec retard pur. Pour obtenir une bonne stabilite de telles regulations, ainsi que des performances correcte il est interessant d'utiliser des correcteurs de type polynomial, agissant directement sur les signaux d'erreur echantillonnes. Les elements actifs de ces correcteurs peuvent etre pris communs a toutes les voies a controler. D'autre part, la determination des parametres de correction decoula d'une etude optimale du systeme. Dans une seconde partie on decrit la realisation d'une regulation multiplexee de fours a diffusion. (auteur)

  16. Radio-vulcanization of natural rubber in the latex phase. Study of an experimental 1 tonne per hour production; Radio-vulcanisation du caoutchouc naturel en phase latex. Etude d'une production experimentale de 1 tonne par heure

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P; Puig, J R; Roudeix, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    After briefly reviewing the main research carried out on the radio-vulcanization of latex and elastomers, a description is given of 4 types of cell which have been used successively with a view to industrial irradiation. They have made it possible to acquire the information necessary for resolving the main problem arising during irradiation - the formation of coagulum. The first two cell are designed for irradiation by a horizontal beam ('Dynamitron'), the two others use a vertical beam ('Circe'). The study of the properties of the rubber obtained shows it to compare favorably with 'Revultex'. In the appendix are given some characteristics of natural latex and information about its processing. (authors) [French] Apres un rappel des principales etudes sur la radio-vulcanisation du latex et des elastomeres, on decrit les quatre types de cellules successivement essayes en vue de l'irradiation industrielle. Ils ont permis d'acquerir les informations necessaires a la resolution du probleme principal pose par l'irradiation, la formation de coagulum au cours de celle,-ci. Les deux premiers sont concus pour l'irradiation par un faisceau horizontal ('Dynamitron'), les derniers par un faisceau vertical ('Circe'). L'etude des proprietes du caoutchouc obtenu montre qu'il se compare favorablement au 'Revultex'. Un apercu est donne en annexe des caracteristiques du latex naturel et de sa mise en oeuvre. (auteurs)

  17. A crystallographic and spectroscopic study of crystal sites in the 'spinel' structure; Etude cristallographique et spectroscopique des sites cristallins dans la structure 'spinelle'

    Energy Technology Data Exchange (ETDEWEB)

    Drifford, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    A crystallographic study on magnesium aluminates led to the determination of crystal site average distortion. A spectroscopic study of transition elements doped spinels gave the position of the doping element in tetrahedral (A) or octahedral (B) sites, and the local distortion of the latter. The comparison of average and local parameters points to differences in the behaviour of doping elements and shows the size of (A) sites are independent of the host crystal composition while the average size of (B) sites varies with the composition. (author) [French] Une etude cristallographique des aluminates de magnesium a permis de determiner la deformation moyenne des sites cristallins. Une etude spectroscopique des aluminates de magnesium dopes avec des elements de transition a permis de localiser les dopants entre les sites tetraedriques (A) et octaedriques (B) et d'etudier la deformation locale de ces sites. La comparaison entre les parametres moyens et locaux a caracterise le comportement du dopant et montre que les dimensions des sites (A) sont independantes de la composition de la matrice, alors que les caracteristiques geometriques moyennes des sites (B) varient continument avec la composition. (auteur)

  18. Study of the antithyroid and radioprotective properties of compounds of the 5 thione imidazolidines group; Etude des proprietes antithyroidiennes et radioprotectrices de composes de la famille des 5 thione imidazolidines

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi, R; Bernard, Y [Commissariat a l' Energie Atomique, Grenoble (France).Centre d' Etudes Nucleaires

    1961-07-01

    Some compounds of the 5 thione imidazolidines group were synthesized by conventional or original methods, and this study is aimed at defining certain pharmacodynamic properties which these substances may be expected to show on the basis of their structure. The properties looked for are: - antithyroid activity, by studying the difference in iodine 131 fixation by the thyroid of rats previously treated or not with these materials; - radioprotective activity, by the comparative study of percentage survival; after 30 days, of mice subjected to a lethal dose of X radiation and having received or not, before irradiation, an intraperitoneal injection of the product under investigation. (author) [French] La synthese de quelques composes de la famille des 5 thione imidazolidines a ete realisee par des methodes classiques ou originales, et le but de ce travail est d'essayer de preciser certaines proprietes pharmacodynamiques que la structure de ces substances peut laisser prevoir. Les proprietes recherchees sont: - l'activite antithyroidienne par l'etude de la difference de la fixation de l'iode 131 par la thyroide de rats prealablement traites ou non par ces produits; - l'activite radioprotectrice par l'etude comparative du pourcentage de survie a 30 jours chez des souris soumises a une dose lethale de rayonnement X, et ayant recu ou non, avant irradiation une injection intraperitoneale du produit a etudier. (auteur)

  19. Development of an analogue multiplexed regulation for periodic 1. order delayed processes; Etude et realisation d'une regulation analogique multiplexee pour processus aperiodiques du 1. ordre avec retard pur

    Energy Technology Data Exchange (ETDEWEB)

    Amblard, J.C. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-15

    The present note deals with the study regulations of the sampled type, for 1. order process with simple delay. In order to obtain a good stability in such regulations, together with acceptable performances, it is interesting to use polynomial type correctors acting directly on the sampled error signals. The active elements of these correctors can be shared by all the channels to be controlled. Furthermore, the determination of the correction parameters results from an optimal study of the system. In the second part is described the construction of a multiplexed regulation for diffusion ovens. (author) [French] La presente note concerne l'etude des regulations de type echantillonne, pour processus du 1. ordre avec retard pur. Pour obtenir une bonne stabilite de telles regulations, ainsi que des performances correcte il est interessant d'utiliser des correcteurs de type polynomial, agissant directement sur les signaux d'erreur echantillonnes. Les elements actifs de ces correcteurs peuvent etre pris communs a toutes les voies a controler. D'autre part, la determination des parametres de correction decoula d'une etude optimale du systeme. Dans une seconde partie on decrit la realisation d'une regulation multiplexee de fours a diffusion. (auteur)

  20. E. P. R. spectroscopic study of nitroxide mono- and bi-radicals; Etude par spectroscopie de resonance paramagnetique electronique de monoradicaux et de biradicaux nitroxydes

    Energy Technology Data Exchange (ETDEWEB)

    Lemaire, H [Commissariat a l' Energie Atomique, Grenoble, 38 (France). Centre d' Etudes Nucleaires

    1967-07-01

    A nitroxide is a molecule containing the group N-O where the oxygen atom made only one bond instead of the usual two. The main advantage of these radicals is their exceptional stability; this allows the study of well defined chemical structures while varying at will the experimental conditions. Studies by electron paramagnetic resonance of nitroxide mono-radicals have given the principal directions and the principal values of the electron-nitrogen nucleus hyperfine tensor and of the anisotropic g-factor tensor. The results were then related to the electronic structure of radicals. An understanding was obtained of the influence of the solvent on the principal values of the tensors, and the marked differences observed in the broadening of hyperfine lines when the medium become viscous. In the nitroxide biradicals, the hyperfine spectra depends not only on the magnetic interactions relative to each monomer, but also on the magnitude of the exchange interaction between the singlet and the triplet states of the dimer; the biradicals studied here are the first organic compounds which show clearly the influence of this exchange on the hyperfine structure. The two unpaired electrons also interact by a magnetic dipolar interaction: in the intermediate case, this can be used to derive the sign of the exchange interaction if the bi-radical is studied in a liquid crystal. Just as for mono-radicals, the hyperfine spectra of bi-radicals show selective broadening in viscous media, which is caused by an overall motional modulation of the anisotropic tensors. This gives another way to determine the sign of the exchange interaction. (author) [French] On appelle nitroxyde une molecule contenant le groupement N-O ou l'atome d'oxygene n'a satisfait qu'une seule liaison de valence sur les deux qui lui sont habituelles. L'interet majeur de ces radicaux reside dans leur exceptionnelle stabilite, permettant ainsi de faire varier a loisir les conditions experimentales d'etude de produits

  1. Contribution to the study of the sintering of finely divided alumina; Contribution a l'etude du frittage de l'alumine finement divisee

    Energy Technology Data Exchange (ETDEWEB)

    Vergnon, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    Two crystalline forms of alumina, delta and alpha, were used to prepare compacts. The shrinkage of these compacts was investigated at different temperatures. The samples of alumina are composed of non porous, spherical particles, of a very high purity. Their mean diameter varies between 160 and 1 200 Angstrom for the delta alumina samples and between 400 and 1 200 Angstrom for the alpha alumina samples. The shrinkage of compacts, heated at a linearly increasing temperature (300 deg. C/h, slow heating) was studied in a A.D.A.M.E.L. dilatometer, modified to be used as a retractometer. The kinetics of the isothermal shrinkage of compacts after their rapid introduction (a few seconds, flash heating) in the high temperature zone of the furnace were followed with a photographic technique. It is shown that the heating rate influences the shrinkage of the compacts when they are heated at temperatures over 1 000 deg. C. The kinetics of the isothermal shrinkage, at temperature between 1000 deg. C and 1600 deg. C were thoroughly studied. Values of the apparent activation energy for the different classes of compacts are given. An interpretation of the results is proposed. It takes into account two different but interdependent mechanisms of sintering: the disappearance of porosity as a result of vacancy diffusion and the grain growth as a result of boundary migration. (author) [French] Deux formes cristallines de l'alumine, la forme delta et la forme alpha, ont ete utilisees pour confectionner des comprimes en vue d'une etude cinetique du frittage. Ces alumines d'une tres grande purete sont constituees de particules spheriques non poreuses, sensiblement homodispersees dont le diametre moyen varie entre 160 et 1200 Angstrom pour les echantillons de l'alumine delta et entre 400 et 1200 Angstrom pour ceux de l'alumine alpha. Le retrait des comprimes chauffes a temperature linerairement croissante (300 deg. C/h: chauffage lent) a ete suivi a l'aide du dilotometre A

  2. Contribution to the study of the sintering of finely divided alumina; Contribution a l'etude du frittage de l'alumine finement divisee

    Energy Technology Data Exchange (ETDEWEB)

    Vergnon, P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    Two crystalline forms of alumina, delta and alpha, were used to prepare compacts. The shrinkage of these compacts was investigated at different temperatures. The samples of alumina are composed of non porous, spherical particles, of a very high purity. Their mean diameter varies between 160 and 1 200 Angstrom for the delta alumina samples and between 400 and 1 200 Angstrom for the alpha alumina samples. The shrinkage of compacts, heated at a linearly increasing temperature (300 deg. C/h, slow heating) was studied in a A.D.A.M.E.L. dilatometer, modified to be used as a retractometer. The kinetics of the isothermal shrinkage of compacts after their rapid introduction (a few seconds, flash heating) in the high temperature zone of the furnace were followed with a photographic technique. It is shown that the heating rate influences the shrinkage of the compacts when they are heated at temperatures over 1 000 deg. C. The kinetics of the isothermal shrinkage, at temperature between 1000 deg. C and 1600 deg. C were thoroughly studied. Values of the apparent activation energy for the different classes of compacts are given. An interpretation of the results is proposed. It takes into account two different but interdependent mechanisms of sintering: the disappearance of porosity as a result of vacancy diffusion and the grain growth as a result of boundary migration. (author) [French] Deux formes cristallines de l'alumine, la forme delta et la forme alpha, ont ete utilisees pour confectionner des comprimes en vue d'une etude cinetique du frittage. Ces alumines d'une tres grande purete sont constituees de particules spheriques non poreuses, sensiblement homodispersees dont le diametre moyen varie entre 160 et 1200 Angstrom pour les echantillons de l'alumine delta et entre 400 et 1200 Angstrom pour ceux de l'alumine alpha. Le retrait des comprimes chauffes a temperature linerairement croissante (300 deg. C/h: chauffage lent) a ete suivi a l'aide du

  3. Electrochemical study of chemical properties in ethanolamine and its mixtures with water; Etude electrochimique de proprietes chimiques dans l'ethanolamine et ses melanges avec l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Grall, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-12-01

    This work is concerned with the study of acid-base reactions and of complex formation in ethanolamine and its mixtures with water. The ionic product of the solvent has been determined by an electro-chemical study of the H{sup +}/H{sub 2} system. The reduction curves for ethanolamine-water mixtures, for different acidities, have made it possible to follow the variations in the size of the pH domain as a function of the composition of the solvent. The form of this variation has been explained on the basis of the dielectric constant and the solvation of the proton by the ethanolamine. In the second part, the electrochemical systems of mercury have been studied by anodic polarography. In order to establish a parallel between the acid-base reactions and complex formation reactions, we have studied the stability of Hg (CN){sub 2} in water-ethanolamine mixtures. It has been possible to deduce the law for the variation of pK{sub c} with solvent composition. The representative graph of this function passes through a minimum for a proportion of about 50 per cent of ethanolamine as in the case of acids. This variation has been explained by the predominating influence of {epsilon} for ethanolamine propositions of over 50 per cent and by that of the solvation of Hg{sup 2+} for proportions of under 50 per cent. (author) [French] Ce travail porte sur l'