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  1. Kinetically controlled synthesis of Au102(SPh)44 nanoclusters and catalytic application

    Science.gov (United States)

    Chen, Yongdong; Wang, Jin; Liu, Chao; Li, Zhimin; Li, Gao

    2016-05-01

    We here explore a kinetically controlled synthetic protocol for preparing solvent-solvable Au102(SPh)44 nanoclusters which are isolated from polydispersed gold nanoclusters by solvent extraction and size exclusion chromatography (SEC). The as-obtained Au102(SPh)44 nanoclusters are determined by matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry, in conjunction with UV-vis spectroscopy and thermogravimetric analysis (TGA). However, Au99(SPh)42, instead of Au102(SPh)44, is yielded when the polydispersed gold nanoclusters are etched in the presence of excess thiophenol under thermal conditions (e.g., 80 °C). Interestingly, the Au102(SPh)44 nanoclusters also can convert to Au99(SPh)42 with equivalent thiophenol ligands, evidenced by the analyses of UV-vis and MALDI mass spectrometry. Finally, the TiO2-supported Au102(SPh)44 nanocluster catalyst is investigated in the selective oxidation of sulfides into sulfoxides by the PhIO oxidant and gives rise to high catalytic activity (e.g., 80-99% conversion of R-S-R' sulfides with 96-99% selectivity for R-S(&z.dbd;O)-R' sulfoxides). The Au102(SPh)44/TiO2 catalyst also shows excellent recyclability in the sulfoxidation process.We here explore a kinetically controlled synthetic protocol for preparing solvent-solvable Au102(SPh)44 nanoclusters which are isolated from polydispersed gold nanoclusters by solvent extraction and size exclusion chromatography (SEC). The as-obtained Au102(SPh)44 nanoclusters are determined by matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry, in conjunction with UV-vis spectroscopy and thermogravimetric analysis (TGA). However, Au99(SPh)42, instead of Au102(SPh)44, is yielded when the polydispersed gold nanoclusters are etched in the presence of excess thiophenol under thermal conditions (e.g., 80 °C). Interestingly, the Au102(SPh)44 nanoclusters also can convert to Au99(SPh)42 with equivalent

  2. Shape and size controlled synthesis of Au nanorods: H{sub 2}S gas-sensing characterizations and antibacterial application

    Energy Technology Data Exchange (ETDEWEB)

    Lanh, Le Thi [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Hoa, Tran Thai, E-mail: trthaihoa@yahoo.com [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Cuong, Nguyen Duc [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Faculty of Hospitality and Tourism, Hue University, 22 Lam Hoang, Hue City (Viet Nam); Khieu, Dinh Quang [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Quang, Duong Tuan [College of Education, Hue University, 34 Le Loi, Hue City (Viet Nam); Van Duy, Nguyen; Hoa, Nguyen Duc [International Training Institute for Materials Science, Hanoi University of Science and Technology, Hanoi (Viet Nam); Van Hieu, Nguyen, E-mail: hieu@itims.edu.vn [International Training Institute for Materials Science, Hanoi University of Science and Technology, Hanoi (Viet Nam)

    2015-06-25

    Highlights: • We have demonstrated a facile method to prepare colloid Au nanorods. • The size and shape of Au nanorods can be controlled via seed-mediated growth method. • The H{sub 2}S gas-sensing properties have been investigated. • The antibacterial application has been conducted. - Abstract: Controlling their size and shape is one of the important issues in the fundamental study and application of colloidal metal nanoparticles. In the current study, different sizes and shapes of Au nanorods were fabricated using a seed-mediated growth method. Material characterization by X-ray diffraction and transmission electron microscopy revealed that the obtained products were made of single-crystal Au nanorods with an average diameter and length of 10 nm and 40 nm, respectively. The Au nanorod-based sensor exhibited significantly high sensitivity and fast response/recovery time to low concentrations (2.5–10 ppm) of H{sub 2}S at temperatures ranging from 300 °C to 400 °C. Additionally, they exhibited antibacterial effect at low concentration. These results suggested that the fabricated Au nanorods have excellent potential for practical application in air pollution monitoring and biomedicine.

  3. Fusion d'images: application au contr\\^ole de la distribution des biopsies prostatiques

    CERN Document Server

    Mozer, Pierre; Chevreau, G; Troccaz, Jocelyne

    2008-01-01

    This paper is about the application of a 3D ultrasound data fusion technique to the 3D reconstruction of prostate biopies in a reference volume. The method is introduced and its evaluation on a series of data coming from 15 patients is described.

  4. Knowledge Based System Applications for Guidance and Control (Application des Systemes a Base de Connaissances au Guidage-Pilotage)

    Science.gov (United States)

    1991-01-01

    pour le pilote, l’automatisation du combat, ]a fusion oes capteurs et les concepts de ]a gestion tactique de ]a bataille par des moyens embarquds... naturellement A aceroitue sea marges de adcuntd ci donc A dimtnuer la capacti effective de leapace qu’iI contr~le 11 cherche en effet A se prdmuntr...d𔄀tabliesement du modble des ph~nom~nes do pertes de r~solution suivant la distance de la cible au capteur . La parte do r~solution a deux causes

  5. Interface controlled growth of nanostructures in discontinuous Ag and Au thin films fabricated by ion beam sputter deposition for plasmonic applications

    Indian Academy of Sciences (India)

    R Brahma; M Ghanashyam Krishna

    2012-08-01

    The growth of discontinuous thin films of Ag and Au by low energy ion beam sputter deposition is reported. The study focuses on the role of the film–substrate in determining the shape and size of nanostructures achieved in such films. Ag films were deposited using Ar ion energy of 150 eV while the Au films were deposited with Ar ion energies of 250–450 eV. Three types of interfaces were investigated in this study. The first set of film–substrate interfaces consisted of Ag and Au films grown on borosilicate glass and carbon coated Cu grids used as substrates. The second set of films was metallic bilayers in which one of the metals (Ag or Au) was grown on a continuous film of the other metal (Au or Ag). The third set of interfaces comprised of discontinuous Ag and Au films deposited on different dielectrics such as SiO2, TiO2 and ZrO2. In each case, a rich variety of nanostructures including self organized arrays of nanoparticles, nanoclusters and nanoneedles have been achieved. The role of the film–substrate interface is discussed within the framework of existing theories of thin film nucleation and growth. Interfacial nanostructuring of thin films is demonstrated to be a viable technique to realize a variety of nanostructures. The use of interfacial nanostructuring for plasmonic applications is demonstrated. It is shown that the surface Plasmon resonance of the metal nanostructures can be tuned over a wide range of wavelengths from 400 to 700 nm by controlling the film–substrate interface.

  6. Controlled electrodeposition of Au monolayer film on ionic liquid

    Science.gov (United States)

    Ma, Qiang; Pang, Liuqing; Li, Man; Zhang, Yunxia; Ren, Xianpei; Liu, Shengzhong Frank

    2016-05-01

    Gold (Au) nanoparticles have been attractive for centuries for their vibrant appearance enhanced by their interaction with sunlight. Nowadays, there have been tremendous research efforts to develop them for high-tech applications including therapeutic agents, sensors, organic photovoltaics, medical applications, electronics and catalysis. However, there remains to be a challenge to fabricate a monolayer Au coating with complete coverage in controlled fashion. Here we present a facile method to deposit a uniform Au monolayer (ML) film on the [BMIM][PF6] ionic liquid substrate using an electrochemical deposition process. It demonstrates that it is feasible to prepare a solid phase coating on the liquid-based substrate. Moreover, the thickness of the monolayer coating can be controlled to a layer-by-layer accuracy.

  7. Photochemical preparation and application research of Au nanoparticles

    Institute of Scientific and Technical Information of China (English)

    DONG; Shou-an; SUN; Jia-lin

    2005-01-01

    Gold nanoparticles protected by organic small molecular compounds or macromolecule have attracted considerable attention and their preparation is one of hotspots in the nano-chemical material field due to their ongoing and potential applications in optics, electronics, catalysts and biosensors. In recent years there are many liquid phase chemistry methods to prepare monodispersed gold particles. Among them, the photochemical method is quite attractive because of its some important advantages for size-controlled synthesis of gold nanoparticles. Therefore, in this paper the recert progress of the photochemical preparing Au nanoparticle materials was briefly introduced and mainly emphasized authors' own works of this area.

  8. Seed-mediated growth and manipulation of Au nanorods via size-controlled synthesis of Au seeds

    Energy Technology Data Exchange (ETDEWEB)

    Liu Juncheng; Duggan, Jennifer N.; Morgan, Joshua; Roberts, Christopher B., E-mail: croberts@eng.auburn.edu [Auburn University, Department of Chemical Engineering (United States)

    2012-12-15

    Seed-mediated growth of gold (Au) nanorods with highly controllable length, width, and aspect ratio was accomplished via carefully size-controlled synthesis of the original Au seeds. A slow dynamic growth of Au nanoparticle seeds was observed after reduction of the Au salt (i.e., hydrogen tetrachloroaurate (III) hydrate) by sodium borohydride (NaBH{sub 4}) in the presence of cetyltrimethyl ammonium bromide (CTAB). As such, the size of the Au nanoparticle seeds can therefore be manipulated through control over the duration of the reaction period (i.e., aging times of 2, 8, 48, 72, and 144 h were used in this study). These differently sized Au nanoparticles were subsequently used as seeds for the growth of Au nanorods, where the additions of Au salt, CTAB, AgNO{sub 3}, and ascorbic acid were employed. Smaller Au nanoparticle seeds obtained via short growth/aging time resulted in Au nanorods with higher aspect ratio and thus longer longitudinal surface plasmon wavelength (LSPW). The larger Au nanoparticle seeds obtained via longer growth/aging time resulted in Au nanorods with lower aspect ratio and shorter LSPW.

  9. Technical Evaluation Report on Knowledge Based System Applications for Guidance and Control (Application des Systemes a Base de Connaissances au Guidage-Pilotage),

    Science.gov (United States)

    1991-07-01

    Sanz-Aranguez SP ProfessorJohn T.Shcpherd UK Dr Elihu Zimet us HOST PAINEL COORDINATOR Mdr Carlos A. Garriga. Lopez SENER Ingenieria y Sistemas SA...real-time expert systems. This problem arises when the prototype phase is finished and the goal is to produce an industrialized system. A methodology...meaningful in terms of industrial applications. The industrial exploitation of AI technology is strictly associated with the combination of both

  10. Controllable photoluminescence enhancement of CdTe/CdS quantum dots thin films incorporation with Au nanoparticles.

    Science.gov (United States)

    Wang, Hongyu; Xu, Ling; Zhang, Renqi; Ge, Zhaoyun; Zhang, Wenping; Xu, Jun; Ma, Zhongyuan; Chen, Kunji

    2015-01-01

    Au nanoparticles (Au NPs)/CdTe/CdS QDs nanocomposite films were fabricated by deposition of Au NPs and layer-by-layer self-assembly of colloidal CdTe/CdS QDs. Photoluminescence (PL) spectra showed that Au NPs incorporation resulted in an increase of PL intensity about 16-fold compared with that of the samples without Au NPs. PL enhancement of Au NPs/CdTe/CdS QDs nanocomposite films can be controlled by tuning the thickness of spacer layer between the metal nanoparticles (MNPs) and QDs. Optical absorption spectra exhibited the incorporation of Au NPs boosted the absorption of Au NPs/CdTe/CdS QDs nanocomposite films. The results of finite-difference time-domain (FDTD) simulation indicated that the increased sizes of Au NPs resulted in stronger localization of electric field, which boosted the PL intensity of QDs in the vicinity of Au NPs. We thought that these were mainly attributed to localized SP enhancement effects of the Au NPs. Our experiment results demonstrated that Au NPs/QDs nanocomposite films would be a promising candidate for optoelectronic devices application. PACS 78.55.-m; 82.33.Ln; 68.65.Hb.

  11. Controlling Au Photodeposition on Large ZnO Nanoparticles.

    Science.gov (United States)

    Fernando, Joseph F S; Shortell, Matthew P; Noble, Christopher J; Harmer, Jeffrey R; Jaatinen, Esa A; Waclawik, Eric R

    2016-06-08

    This study investigated how to control the rate of photoreduction of metastable AuCl2(-) at the solid-solution interface of large ZnO nanoparticles (NPs) (50-100 nm size). Band-gap photoexcitation of electronic charge in ZnO by 370 nm UV light yielded Au NP deposition and the formation of ZnO-Au NP hybrids. Au NP growth was observed to be nonepitaxial, and the patterns of Au photodeposition onto ZnO NPs observed by high-resolution transmission electron microscopy were consistent with reduction of AuCl2(-) at ZnO facet edges and corner sites. Au NP photodeposition was effective in the presence of labile oleylamine ligands attached to the ZnO surface; however, when a strong-binding dodecanethiol ligand coated the surface, photodeposition was quenched. Rates of interfacial electron transfer at the ZnO-solution interface were adjusted by changing the solvent, and these rates were observed to strongly depend on the solvent's permittivity (ε) and viscosity. From measurements of electron transfer from ZnO to the organic dye toluidine blue at the ZnO-solution interface, it was confirmed that low ε solvent mixtures (ε ≈ 9.5) possessed markedly higher rates of photocatalytic interfacial electron transfer (∼3.2 × 10(4) electrons·particle(-1)·s(-1)) compared to solvent mixtures with high ε (ε = 29.9, ∼1.9 × 10(4) electrons·particle(-1)·s(-1)). Dissolved oxygen content in the solvent and the exposure time of ZnO to band-gap, near-UV photoexcitation were also identified as factors that strongly affected Au photodeposition behavior. Production of Au clusters was favored under conditions that caused electron accumulation in the ZnO-Au NP hybrid. Under conditions where electron discharge was rapid (such as in low ε solvents), AuCl2(-) precursor ions photoreduced at ZnO surfaces in less than 5 s, leading to deposition of several small, isolated ∼6 nm Au NP on the ZnO host instead.

  12. Ordered Au Nanodisk and Nanohole Arrays: Fabrication and Applications

    KAUST Repository

    Zheng, Yue Bing

    2010-01-01

    We have utilized nanosphere lithography (NSL) to fabricate ordered Au nanodisk and nanohole arrays on substrates and have studied the localized surface plasmon resonance (LSPR) of the arrays. Through these investigations, we demonstrate that the angle- dependent behavior of the LSPR in the Au nanodisk arrays enables real-time observation of exciton-plasmon couplings. In addition, we show that the NSL-fabricated Au nanohole arrays can be applied as templates for patterning micro-/nanoparticles under capillary force. The unique structural and plasmonic characteristics of the Au nanodisk and nano- hole arrays, as well as the low-cost and high-throughput NSL-based nanofabrication technique, render these arrays excellent platforms for numerous engineering applications. © 2010 by ASME.

  13. Detection of {alpha} particles using semiconductors. Application to the control of plutonium extraction; Detection des particules {alpha} par semiconducteurs application au controle de l'extraction du plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Tanguy, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-03-01

    A study is made of a particles produced by thick sources, using either diffused junction or surface barrier semiconductor detectors for controlling continuously the plutonium extraction process. For this, a presenting apparatus is described in which the solutions to be analyzed flow in contact with the detector protected by a thin mica membrane. A method is described which gives a precise recording of the spectra and which thus allows the separation of two or more {alpha} emitters present in the same solution. This method has been applied to the measurement of {sup 239}Pu in the the presence of {sup 241}Am with an accuracy of {+-}5 per cent. In the second part of the report is considered the detection of plutonium in solutions of {beta} - {gamma} emitting fission products. Pile-up is reduced by using a fast amplification chain associated to totally depleted thin detectors. Under these conditions a few mg of {sup 239}Pu can be detected in solutions of fission products having an activity of 100 curies/liter. A method is given for discriminating {alpha} and {beta} particles, it is based on the difference in the collection times for the charges liberated by these particles in the detector. (author) [French] On etudie la detection de particules {alpha} issues de sources epaisses par detecteurs semiconducteurs a jonction diffusee ou a barriere de surface pour le controle continu du procede d'extraction du plutonium. A cet effet on decrit un appareil presentateur dans lequel les solutions a analyser circulent au contact du detecteur protege par une membrane mince de mica. On decrit une methode qui permet par le trace precis des spectres de separer deux ou plusieurs emetteurs {alpha} presents dans une meme solution. Cette methode a ete appliquee a la mesure du {sup 239}Pu en presence de {sup 241}Am avec une precision de {+-} 5 pour cent. Dans la deuxieme partie on traite de la detection du plutonium dans des solutions de produits de fission emetteurs {beta} and {gamma

  14. New ideally absorbing Au plasmonic nanostructures for biomedical applications

    Science.gov (United States)

    Zakomirnyi, Vadim I.; Rasskazov, Ilia L.; Karpov, Sergey V.; Polyutov, Sergey P.

    2017-01-01

    In this paper a new set of plasmonic nanostructures operating at the conditions of an ideal absorption (Grigoriev et al., 2015 [1]) was proposed for novel biomedical applications. We consider spherical x/Au nanoshells and Au/x/Au nanomatryoshkas, where 'x' changes from conventional Si and SiO2 to alternative plasmonic materials (Naik and Shalaev, 2013 [2]), such as zinc oxide doped with aluminum, gallium and indium tin oxide. The absorption peak of proposed nanostructures lies within 700-1100 nm wavelength region and corresponds to the maximal optical transparency of hemoglobin and melanin as well as to the radiation frequency of available pulsed medical lasers. It was shown that the ideal absorption takes place in a given wavelength region for Au coatings with thickness less than 12 nm. In this case finite quantum size effects for metallic nanoshells play a significant role. The mathematical model for the search of the ideal absorption conditions was modified by taking into account the finite quantum size effects.

  15. Surface dislocation nucleation controlled deformation of Au nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Roos, B.; Kapelle, B.; Volkert, C. A., E-mail: volkert@ump.gwdg.de [Institute of Materials Physics, Georg August University, Göttingen 37077 (Germany); Richter, G. [Max-Plank-Institute for Intelligent Systems, Stuttgart 70569 (Germany)

    2014-11-17

    We investigate deformation in high quality Au nanowires under both tension and bending using in-situ transmission electron microscopy. Defect evolution is investigated during: (1) tensile deformation of 〈110〉 oriented, initially defect-free, single crystal nanowires with cross-sectional widths between 30 and 300 nm, (2) bending deformation of the same wires, and (3) tensile deformation of wires containing coherent twin boundaries along their lengths. We observe the formation of twins and stacking faults in the single crystal wires under tension, and storage of full dislocations after bending of single crystal wires and after tension of twinned wires. The stress state dependence of the deformation morphology and the formation of stacking faults and twins are not features of bulk Au, where deformation is controlled by dislocation interactions. Instead, we attribute the deformation morphologies to the surface nucleation of either leading or trailing partial dislocations, depending on the Schmid factors, which move through and exit the wires producing stacking faults or full dislocation slip. The presence of obstacles such as neutral planes or twin boundaries hinder the egress of the freshly nucleated dislocations and allow trailing and leading partial dislocations to combine and to be stored as full dislocations in the wires. We infer that the twins and stacking faults often observed in nanoscale Au specimens are not a direct size effect but the result of a size and obstacle dependent transition from dislocation interaction controlled to dislocation nucleation controlled deformation.

  16. Control of fast non linear systems - application to a turbo charged SI engine with variable valve timing; controle des systemes rapides non lineaires - application au moteur a allumage commande turbocompresse a distribution variable

    Energy Technology Data Exchange (ETDEWEB)

    Colin, G.

    2006-10-15

    Spark ignition engine control has become a major issue for the compliance with emissions legislation while ensuring driving comfort. Engine down-sizing is one of the promising ways to reduce fuel consumption and resulting CO{sub 2} emissions. Combining several existing technologies such as supercharging and variable valve actuation, down-sizing is a typical example of the problems encountered in Spark Ignited (SI) engine control: nonlinear systems with saturation of actuators; numerous major physical phenomena not measurable; limited computing time; control objectives (consumption, pollution, performance) often competing. A methodology of modelling and model-based control (internal model and predictive control) for these systems is also proposed and applied to the air path of the down-sized engine. Models, physicals and generics, are built to estimate in-cylinder air mass, residual burned gases mass and air scavenged mass from the intake to the exhaust. The complete and generic engine torque control architecture for the turbo-charged SI engine with variable cam-shaft timing was tested in simulation and experimentally (on engine and vehicle). These tests show that new possibilities are offered in order to decrease pollutant emissions and optimize engine efficiency. (author)

  17. Colloidal Au-enhanced surface plasmon resonance imaging: application in a DNA hybridization process

    Science.gov (United States)

    Manera, M. G.; Spadavecchia, J.; Taurino, A.; Rella, R.

    2010-03-01

    The detection of the DNA hybridization mechanism using monodispersed gold nanoparticles as labels is an interesting alternative to increase the sensitivity of the SPR imaging technique. DNA-modified Au nanoparticles (DNA-Au NPs) containing single-stranded (ss) portions of DNA were prepared by monitoring their monolayer formation by UV-vis spectroscopy. The hybridization process between specific thio-oligonucleotides immobilized on the DNA-Au NPs and the corresponding complementary strands is reported and compared with the traditional hybridization process on properly self-assembled thin gold films deposited on glass substrates. A remarkable signal amplification is observed, following the incorporation of colloidal Au into a SPR biosensing experiment, resulting in an increased SPR response to DNA-DNA interactions. In particular Fusarium thiolated DNA (5'HS poly(T)15ATC CCT CAA AAA CTG CCG CT-3) and trichothecenes complementary DNA (5'-AGC GGC AGT TTT TGA GGG AT-3') sequences have been explored due to their possible application to agro-industry for the control of food quality.

  18. Laser nanostructuring of Au/Ag and Au/Ni films for application in SERS

    Science.gov (United States)

    Nikov, Ru. G.; Nedyalkov, N. N.; Atanasov, P. A.; Grochowska, K.; Iwulska, A.; Sliwinski, G.

    2013-03-01

    In this paper results on laser nanostructuring of Au/Ag and Au/Ni thin films are presented. The nanostructuring leads to formation of arrays of bimetallic nanoparticles. The fabrication of the these structures is made using a two step procedure. Initially, thin films are deposited on quartz substrates by classical pulsed laser deposition method. In order to produce Au/Ag or Au/Ni thin films, targets with two sections consist the different metals are used. Thin films with different concentrations of the two metals are obtained by changing the area of the different sections in the target. The as prepared films are then annealed by nanosecond laser pulses delivered by Nd:YAG laser system operated at λ = 355 nm. It is found that the laser annealing may lead to nanostructuring of the deposited films as at certain conditions decomposition into monolayers of nanoparticles with narrow size distribution is obtained. The performed EDX analyses indicate that the fabricated particles are composed by a bimetallic system of the basic metals used. The transmission spectra of the obtained structures show evidences of plasmon excitations. The bimetal nanostructures are covered with Rhodamine 6G and then tested as active substrates for Surface Enhanced Raman Spectroscopy (SERS).

  19. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  20. Multifunctional Au-Fe3O4@MOF core-shell nanocomposite catalysts with controllable reactivity and magnetic recyclability

    Science.gov (United States)

    Ke, Fei; Wang, Luhuan; Zhu, Junfa

    2014-12-01

    The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional catalysts used in the reduction of 4-nitrophenol, this porous MOF-based magnetic catalyst is green, cheap and promising for industrial applications.The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional

  1. Templated Control of Au nanospheres in Silica Nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Tringe, J W; Vanamu, G; Zaidi, S H

    2007-03-15

    The formation of regularly-spaced metal nanostructures in selectively-placed insulating nanowires is an important step toward realization of a wide range of nano-scale electronic and opto-electronic devices. Here we report templated synthesis of Au nanospheres embedded in silica nanowires, with nanospheres consistently spaced with a period equal to three times their diameter. Under appropriate conditions, nanowires form exclusively on Si nanostructures because of enhanced local oxidation and reduced melting temperatures relative to templates with larger dimensions. We explain the spacing of the nanospheres with a general model based on a vapor-liquid-solid mechanism, in which an Au/Si alloy dendrite remains liquid in the nanotube until a critical Si concentration is achieved locally by silicon oxide-generated nanowire growth. Additional Si oxidation then locally reduces the surface energy of the Au-rich alloy by creating a new surface with minimum area inside of the nanotube. The isolated liquid domain subsequently evolves to become an Au nanosphere, and the process is repeated.

  2. Lignin-AuNPs liquid marble for remotely-controllable detection of Pb2+

    Science.gov (United States)

    Han, Guocheng; Wang, Xiaoying; Hamel, Jonathan; Zhu, Hongli; Sun, Runcang

    2016-12-01

    This work reported the green and facile fabrication of a versatile lignin-AuNP composite, which was readily and remotely encapsulated to form novel liquid marbles. The marbles can stay suspended in water, and show excellent photothermal conversion properties, as well as visual detection and adsorption towards Pb2+. More importantly, the marbles can simultaneously remotely detect and adsorb Pb2+ via co-precipitation by simply controlling the near infrared (NIR) irradiation. It is believed that the remotely-controllable NIR-responsive lignin-AuNPs liquid marble can be used in Pb2+-related reactions. The liquid marble can be placed in the system at the very beginning of the reaction and stably stays on the surface until the reaction has ended. After reacting, upon remote NIR irradiation, the liquid marble bursts to adsorb Pb2+, and the residual Pb2+ can be collected. This facile manipulation strategy does not use complicated nanostructures or sophisticated equipment, so it has potential applications for channel-free microfluidics, smart microreactors, microengines, and so on.

  3. Multifunctional Au-Fe3O4@MOF core-shell nanocomposite catalysts with controllable reactivity and magnetic recyclability.

    Science.gov (United States)

    Ke, Fei; Wang, Luhuan; Zhu, Junfa

    2015-01-21

    The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional catalysts used in the reduction of 4-nitrophenol, this porous MOF-based magnetic catalyst is green, cheap and promising for industrial applications.

  4. Application of Turkevich Method for Gold Nanoparticles Synthesis to Fabrication of SiO2@Au and TiO2@Au Core-Shell Nanostructures

    Directory of Open Access Journals (Sweden)

    Paulina Dobrowolska

    2015-05-01

    Full Text Available The Turkevich synthesis method of Au nanoparticles (AuNPs was adopted for direct fabrication of SiO2@Au and TiO2@Au core-shell nanostructures. In this method, chloroauric acid was reduced with trisodium citrate in the presence of amine-functionalized silica or titania submicroparticles. Core-shells obtained in this way were compared to structures fabricated by mixing of Turkevich AuNPs with amine-functionalized silica or titania submicroparticles. It was found that by modification of reaction conditions of the first method, such as temperature and concentration of reagents, control over gold coverage on silicon dioxide particles has been achieved. Described method under certain conditions allows fabrication of semicontinuous gold films on the surface of silicon dioxide particles. To the best of our knowledge, this is the first report describing use of Turkevich method to direct fabrication of TiO2@Au core-shell nanostructures.

  5. High-Performance Li-O2 Batteries with Controlled Li2O2 Growth in Graphene/Au-Nanoparticles/Au-Nanosheets Sandwich.

    Science.gov (United States)

    Wang, Guoqing; Tu, Fangfang; Xie, Jian; Du, Gaohui; Zhang, Shichao; Cao, Gaoshao; Zhao, Xinbing

    2016-10-01

    The working of nonaqueous Li-O2 batteries relies on the reversible formation/decomposition of Li2O2 which is electrically insulating and reactive with carbon and electrolyte. Realizing controlled growth of Li2O2 is a prerequisite for high performance of Li-O2 batteries. In this work, a sandwich-structured catalytic cathode is designed: graphene/Au-nanoparticles/Au-nanosheets (G/Au-NP/Au-NS) that enables controlled growth of Li2O2 spatially and structurally. It is found that thin-layer Li2O2 (below 10 nm) can grow conformally on the surface of Au NPs confined in between graphene and Au NSs. This unique crystalline behavior of Li2O2 effectively relieves or defers the electrode deactivation with Li2O2 accumulation and largely reduces the contact of Li2O2 with graphene and electrolyte. As a result, Li-O2 batteries with the G/Au-NP/Au-NS cathode exhibit superior electrochemical performance. A stable cycling of battery can last 300 times at 400 mA g(-1) when the capacity is limited at 500 mAh g(-1). This work provides a practical design of catalytic cathodes capable of controlling Li2O2 growth.

  6. Pd-on-Au Supra-nanostructures Decorated Graphene Oxide: An Advanced Electrocatalyst for Fuel Cell Application.

    Science.gov (United States)

    Tao, Yingzhou; Dandapat, Anirban; Chen, Liming; Huang, Youju; Sasson, Yoel; Lin, Zhenyu; Zhang, Jiawei; Guo, Longhua; Chen, Tao

    2016-08-30

    We report a very easy and effective approach for synthesizing unique palladium-on-gold supra-nanostructure (Au@Pd-SprNS)-decorated graphene oxide (GO) nanosheets. The SprNSs comprising Au nanorods as core and a unique close-packed assembly of tiny anisotropic Pd nanoparticles (NPs) as shell were homogeneously distributed on the GO surface via electrostatic self-assembly. Compared with the traditional one-pot method for synthesis of metal NPs on GO sheets, the size and shape of core-shell Au@Pd SprNSs can be finely controlled and uniformly distributed on the GO carrier. Interestingly, this Au@Pd-SprNSs/GO nanocomposite displayed high electrocatalytic activities toward the oxidation of methanol, ethanol, and formic acid, which can be attributed to the abundance of intrinsic active sites including high density of atomic steps, ledges and kinks, Au-Pd heterojunctions and cooperative action of the two metals of the SprNSs. Additionally, uniform dispersion of the SprNSs over the GO nanosheets prevent agglomeration between the SprNSs, which is of great significance to enhance the long-term stability of catalyst. This work will introduce a highly efficient Pd-based nanoelectrocatalyst to be used in fuel cell application.

  7. Synthesis of Au nanowires with controlled morphological and structural characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Gurvinder, E-mail: gurvinder.singh@ntnu.no [Ugelstad Laboratory, Department of Chemical Engineering, Norwegian University of Science and Technology (NTNU), NO-7491 Trondheim (Norway); Helvoort, Antonius T.J. van [Department of Physics, Norwegian University of Science and Technology, NO-7491 Trondheim (Norway); Bandyopadhyay, Sulalit; Volden, Sondre; Andreassen, Jens-Petter [Ugelstad Laboratory, Department of Chemical Engineering, Norwegian University of Science and Technology (NTNU), NO-7491 Trondheim (Norway); Glomm, Wilhelm R., E-mail: Wilhelm.Glomm@sintef.no [Ugelstad Laboratory, Department of Chemical Engineering, Norwegian University of Science and Technology (NTNU), NO-7491 Trondheim (Norway); SINTEF Materials and Chemistry, Biotechnology and Nanomedicine Sector, NO-7491 Trondheim (Norway)

    2014-08-30

    Graphical abstract: - Highlights: • Synthesis of metal nanowires. • Control over structural and morphological characteristics via seed type nanoparticle. • Growth via surfactant or surface diffusion process. • Structural and surface characterization. - Abstract: A growth of one-dimensional noble metal nanostructure with controlled structural characteristic has been under intense investigation as the physical properties, for example, mechanical and electrical properties highly depend on the crystallinity of the nanostructure. Herein, we report a seed-mediated growth of gold nanowires with controlled structural and morphological characteristics, which can easily be varied by selecting appropriate seed nanoparticles, either spherical or rod type in aqueous solution at room temperature. The growth of nanowires was monitored by characterizing the samples at different time period during the reaction, and our observations suggest that growth occurs from seeds rapidly growing along one-dimension followed by surfactant induced fusion or welding and surface diffusion. The aspect ratio and morphology of these NWs can be tuned by CTAB concentration, pH and temperature of the growth solution. We show that the aspect ratio and morphology of these NWs can be tuned by the surfactant concentration, pH and temperature of the growth solution. Electron microscopy and X-ray Photoelectron spectroscopic techniques were employed for investigating structural and surface characteristics of nanowires. This approach can possibly help to synthesize nanowires of other metals with controlled crystalline behaviour which is highly essential for understanding their properties and practical applications in nanoelectronics, optical devices, catalysis, and sensors.

  8. AuCu@Pt Nanoalloys for Catalytic Application in Reduction of 4-Nitrophenol

    Directory of Open Access Journals (Sweden)

    Sadia Mehmood

    2016-01-01

    Full Text Available To enhance and optimize nanocatalyst ability for nitrophenol (4-NP reduction reaction we look beyond Au-metal nanoparticles and describe a new class of Au nanoalloys with controlled composition for core of AuCu-metals and Pt-metal shell. The reduction of 4-NP was investigated in aqueous media spectroscopically on 7.8 nm Au nanospheres (AuNSs, 8.3 nm AuCuNSs, and 9.1 nm AuCu@Pt core-shell NSs in diameter. The rate constants of the catalyzed reaction at room temperature, activation energies, and entropies of activation of reactions catalyzed by the AuCu@Pt core-shell NSs are found to have different values to those of the pure metal NSs. The results strongly support the proposal that catalysis by nanoparticles is taking place efficiently on the surface of NSs. These core-shell nanocatalysts exhibited stability throughout the reduction reaction and proved that heterogonous type mechanisms are most likely to be dominant in nanoalloy based catalysis if the surface of the NSs is not defected upon shell incorporation.

  9. Facile Synthesis of Quasi-One-Dimensional Au/PtAu Heterojunction Nanotubes and Their Application as Catalysts in an Oxygen-Reduction Reaction.

    Science.gov (United States)

    Cai, Kai; Liu, Jiawei; Zhang, Huan; Huang, Zhao; Lu, Zhicheng; Foda, Mohamed F; Li, Tingting; Han, Heyou

    2015-05-11

    An intermediate-template-directed method has been developed for the synthesis of quasi-one-dimensional Au/PtAu heterojunction nanotubes by the heterogeneous nucleation and growth of Au on Te/Pt core-shell nanostructures in aqueous solution. The synthesized porous Au/PtAu bimetallic nanotubes (PABNTs) consist of porous tubular framework and attached Au nanoparticles (AuNPs). The reaction intermediates played an important role in the preparation, which fabricated the framework and provided a localized reducing agent for the reduction of the Au and Pt precursors. The Pt7 Au PABNTs showed higher electrocatalytic activity and durability in the oxygen-reduction reaction (ORR) in 0.1 M HClO4 than porous Pt nanotubes (PtNTs) and commercially available Pt/C. The mass activity of PABNTs was 218 % that of commercial Pt/C after an accelerated durability test. This study demonstrates the potential of PABNTs as highly efficient electrocatalysts. In addition, this method provides a facile strategy for the synthesis of desirable hetero-nanostructures with controlled size and shape by utilizing an intermediate template.

  10. Impedance measurements on Au microelectrodes using controlled atmosphere high temperature scanning probe microscope

    DEFF Research Database (Denmark)

    Wu, Yuehua; Hansen, Karin Vels; Jacobsen, Torben

    2011-01-01

    High temperature impedance measurements on Au microelectrodes deposited on polished yttria stabilized zirconia (YSZ) pellets were demonstrated using a newly designed controlled atmosphere high temperature scanning probe microscope (CAHT-SPM). Probes based on Pt0.8Ir0.2 were fabricated and employed...... in all the investigations. The electrical properties of the Au microelectrodes were investigated using CAHT-SPM at various temperatures in air. The influences of the tip-sample force and of the size of the microelectrode on the electrical properties of the Au microelectrodes were also studied....... The impedance spectra of circular Au microelectrodes down to 8μm in diameter at different temperatures were successfully obtained. The CAHT-SPM presented in this paper is capable of obtaining topography images, conductivity images and impedance spectra in-situ in a temperature range from room temperature...

  11. Systematic control of edge length, tip sharpness, thickness, and localized surface plasmon resonance of triangular Au nanoprisms

    Science.gov (United States)

    Noda, Yuta; Hayakawa, Tomokatsu

    2016-10-01

    Triangular gold (Au) nanoprisms of various sizes were synthesized in a controlled way using a modified three-step seed-mediated method with different volumes of starting seed solution and subsequent first step's growth solution. The structures and optical properties of the triangular Au nanoprisms were investigated using transmission electron microscopy (TEM), atomic force microscopy, and UV-Vis-NIR spectrophotometry. The Au nanoprisms synthesized also varied in optical response frequency of localized surface plasmon resonance (LSPR) owing to electric dipole polarizations of the Au nanoprisms. This variation depended nonlinearly on the volume of the seed solution. From optical extinction spectra and careful TEM observations, the dipole LSPR peak frequency was found to be linearly proportional to the edge length of the Au nanoprisms. Consequently, it was experimentally shown that the LSPR optical response frequency of their colloidal solutions could be controlled in the near-infrared region (700-1200 nm), corresponding to an edge length of 40-180 nm of the Au nanoprisms. It was also demonstrated that the tip sharpness of triangular Au nanoprisms was improved by using fine Au seeds instead of coarse Au seeds, and the resulting Au nanoprisms were smaller and thinner. A formation mechanism of triangular Au nanoprisms shall also be discussed with a prospect of synthesizing very tiny Au nanoprisms.

  12. Inverse method for effects characterization from ultrasonic b-scan images; Caracterisation des defauts par une methode d'inversion lors d'un controle ultrasonore. Application au controle des defauts en paroi externe

    Energy Technology Data Exchange (ETDEWEB)

    Faur, M. [Paris-11 Univ., 91 - Orsay (France)

    1999-02-01

    In service inspections of French nuclear pressure water reactor vessels are carried out automatically in complete immersion from the inside by means of ultrasonic focused probes working in the pulse echo mode. Concern has been expressed about the capabilities of performing non destructive evaluation of the Outer Surface Defects (OSD), i.e. defects located in the vicinity of the outer surface of the inspected components. OSD are insonified by both a direct field that passes through the inner surface (water/steel) of the component containing the defect and a secondary field reflected from the outer surface. Consequently, the Bscan images, containing the signatures of such defects, are complicated and their interpretation is a difficult task. This work deals with extraction of the maximum available information for characterizing OSD from ultrasonic Bscan images. Our main objectives are to obtain the type of OSD and their geometric parameters by means of two specific inverse methods. The first method is used for the identification of the geometrical parameters of the equivalent planar OSD from segmented Bscan images. Ultrasonic equivalent defect sizing model-based methods may be used to size a defect in a material by obtaining a best-fit simple equivalent shape that matches the ultrasonic observed data. We illustrate the application of such an equivalent sizing OSD method that is based on a simplified direct model. The major drawback of this identification method, as used to date, is that only a part of the useful information contained into original Bscan image, i.e. segmented Bscan image, is used for defect characterization. Moreover, it requires the availability of defect classification information (i.e. if the defect is volumetric or planer, e. g. a crack or a lack of fusion), which, generally, may be as difficult to obtain as the defect parameters themselves. Therefore, we propose a parameter estimation method for extracting complementary information on the defect

  13. Understanding and controlling the structure and segregation behaviour of AuRh nanocatalysts

    Science.gov (United States)

    Piccolo, Laurent; Li, Z. Y.; Demiroglu, Ilker; Moyon, Florian; Konuspayeva, Zere; Berhault, Gilles; Afanasiev, Pavel; Lefebvre, Williams; Yuan, Jun; Johnston, Roy L.

    2016-01-01

    Heterogeneous catalysis, which is widely used in the chemical industry, makes a great use of supported late-transition-metal nanoparticles, and bimetallic catalysts often show superior catalytic performances as compared to their single metal counterparts. In order to optimize catalyst efficiency and discover new active combinations, an atomic-level understanding and control of the catalyst structure is desirable. In this work, the structure of catalytically active AuRh bimetallic nanoparticles prepared by colloidal methods and immobilized on rutile titania nanorods was investigated using aberration-corrected scanning transmission electron microscopy. Depending on the applied post-treatment, different types of segregation behaviours were evidenced, ranging from Rh core – Au shell to Janus via Rh ball – Au cup configuration. The stability of these structures was predicted by performing density-functional-theory calculations on unsupported and titania-supported Au-Rh clusters; it can be rationalized from the lower surface and cohesion energies of Au with respect to Rh, and the preferential binding of Rh with the titania support. The bulk-immiscible AuRh/TiO2 system can serve as a model to understand similar supported nanoalloy systems and their synergistic behaviour in catalysis. PMID:27739480

  14. Controllable assembly of well-defined monodisperse Au nanoparticles on hierarchical ZnO microspheres for enhanced visible-light-driven photocatalytic and antibacterial activity

    Science.gov (United States)

    Wang, Yuan; Fang, Hua-Bin; Zheng, Yan-Zhen; Ye, Rongqin; Tao, Xia; Chen, Jian-Feng

    2015-11-01

    A high-efficiency visible-light-driven photocatalyst composed of homogeneously distributed Au nanoparticles (AuNPs) well-defined on hierarchical ZnO microspheres (ZMS) via a controllable layer-by-layer self-assembly technique is demonstrated. The gradual growth of the characteristic absorption bands of Au loaded on ZnO in the visible light region with an increasing number of assemblies indicates the enhancement of the light harvesting ability of the ZMS/Au composites as well as the reproducibility and controllability of the entire assembly process. Results on the photoelectrochemical performance characterized by EIS and transient photocurrent response spectra indicate that the ZMS/Au composites possess increased photoinduced charge separation and transfer efficiency compared to the pure ZMS film. As a result, the hybrid composites exhibited enhanced decomposition activity for methylene blue and salicylic acid as well as antibacterial activity in killing S. aureus and E. coli under visible light irradiation. It can be noted that well-distributed Au components even at a rather low Au/ZnO weight ratio of ~1.2% also exhibited extraordinary photocatalysis. Such a facile and controllable self-assembly approach may be viable for preparing high-performance visible-light-driven ZMS/Au photocatalysts in a simple and controllable way, and consequently, the technology may extend to other plasmon-enhanced heterostructures made of nanostructured semiconductors and noble metals for great potential application in environmental protection.A high-efficiency visible-light-driven photocatalyst composed of homogeneously distributed Au nanoparticles (AuNPs) well-defined on hierarchical ZnO microspheres (ZMS) via a controllable layer-by-layer self-assembly technique is demonstrated. The gradual growth of the characteristic absorption bands of Au loaded on ZnO in the visible light region with an increasing number of assemblies indicates the enhancement of the light harvesting ability of

  15. Role of Carboxylate ligands in the Synthesis of AuNPs: Size Control, Molecular Interaction and Catalytic Activity

    KAUST Repository

    Aljohani, Hind Abdullah

    2016-05-22

    Nanoparticles (NPs) are the basis of nanotechnology and finding numerous applications in various fields such as health, electronics, environment, personal care products, transportation, and catalysis. To fulfill these functions, the nanoparticles must be synthesized, passivated to control their chemical reactivity, stabilized against aggregation and functionalized to achieve specific performances. The chemistry of metal nanoparticles especially that of noble metals (Gold, Platinum…) is a growing field. The nanoparticles have indeed different properties from those of the corresponding bulk material. These properties are largely influenced by several parameters; the most important are the size, shape, and the local environment of the nanoparticles. One of the most common synthetic methods for the preparation of gold nanoparticles (AuNPs) is based on stabilization by citrate. Since it was reported first by Turkevich et al. in 1951, this synthetic scheme has been widely used, studied and a substantial amount of important information regarding this system has been reported in the literature. The most popular method developed by Frens for controlling the size of the noble gold nanoparticles based on citrate was achieved by varying the concentration of sodium citrate. Despite a large number of investigations focused on utilizing Cit-AuNPs, the structural details of citrate anions adsorbed on the AuNP surface are still unknown. It is known only that citrate anions “coordinate” to the metal surface by inner sphere complexation of the carboxylate groups and there are trace amounts of AuCl4−, Cl−, and OH− on the metal surface. Moreover, it is generally accepted that the ligand shell morphology of Au nanoparticles can be partly responsible for important properties such as oxidation of carbon monoxide. The use of Au-NPs in heterogeneous catalysis started mostly with Haruta who discovered the effect of particle size on the activity for carbon monoxide oxidation at

  16. Dynamic Control of Plasmon-Exciton Coupling in Au Nanodisk–J-Aggregate Hybrid Nanostructure Arrays

    KAUST Repository

    Zheng, Yue Bing

    2009-01-01

    We report the dynamic control of plasmon-exciton coupling in Au nanodisk arrays adsorbed with J-aggregate molecules by incident angle of light. The angle-resolved spectra of an array of bare Au nanodisks exhibit continuous shifting of localized surface plasmon resonances. This characteristic enables the production of real-time, controllable spectral overlaps between molecular and plasmonic resonances, and the efficient measurement of plasmon-exciton coupling as a function of wavelength with one or fewer nanodisk arrays. Experimental observations of varying plasmon-exciton coupling match with coupled dipole approximation calculations.

  17. UV and visible light photocatalytic activity of Au/TiO2 nanoforests with Anatase/Rutile phase junctions and controlled Au locations

    Science.gov (United States)

    Yu, Yang; Wen, Wei; Qian, Xin-Yue; Liu, Jia-Bin; Wu, Jin-Ming

    2017-01-01

    To magnify anatase/rutile phase junction effects through appropriate Au decorations, a facile solution-based approach was developed to synthesize Au/TiO2 nanoforests with controlled Au locations. The nanoforests cons®isted of anatase nanowires surrounded by radially grown rutile branches, on which Au nanoparticles were deposited with preferred locations controlled by simply altering the order of the fabrication step. The Au-decoration increased the photocatalytic activity under the illumination of either UV or visible light, because of the beneficial effects of either electron trapping or localized surface plasmon resonance (LSPR). Gold nanoparticles located preferably at the interface of anatase/rutile led to a further enhanced photocatalytic activity. The appropriate distributions of Au nanoparticles magnify the beneficial effects arising from the anatase/rutile phase junctions when illuminated by UV light. Under the visible light illumination, the LSPR effect followed by the consecutive electron transfer explains the enhanced photocatalysis. This study provides a facile route to control locations of gold nanoparticles in one-dimensional nanostructured arrays of multiple-phases semiconductors for achieving a further increased photocatalytic activity.

  18. UV and visible light photocatalytic activity of Au/TiO2 nanoforests with Anatase/Rutile phase junctions and controlled Au locations.

    Science.gov (United States)

    Yu, Yang; Wen, Wei; Qian, Xin-Yue; Liu, Jia-Bin; Wu, Jin-Ming

    2017-01-24

    To magnify anatase/rutile phase junction effects through appropriate Au decorations, a facile solution-based approach was developed to synthesize Au/TiO2 nanoforests with controlled Au locations. The nanoforests cons®isted of anatase nanowires surrounded by radially grown rutile branches, on which Au nanoparticles were deposited with preferred locations controlled by simply altering the order of the fabrication step. The Au-decoration increased the photocatalytic activity under the illumination of either UV or visible light, because of the beneficial effects of either electron trapping or localized surface plasmon resonance (LSPR). Gold nanoparticles located preferably at the interface of anatase/rutile led to a further enhanced photocatalytic activity. The appropriate distributions of Au nanoparticles magnify the beneficial effects arising from the anatase/rutile phase junctions when illuminated by UV light. Under the visible light illumination, the LSPR effect followed by the consecutive electron transfer explains the enhanced photocatalysis. This study provides a facile route to control locations of gold nanoparticles in one-dimensional nanostructured arrays of multiple-phases semiconductors for achieving a further increased photocatalytic activity.

  19. UV and visible light photocatalytic activity of Au/TiO2 nanoforests with Anatase/Rutile phase junctions and controlled Au locations

    Science.gov (United States)

    Yu, Yang; Wen, Wei; Qian, Xin-Yue; Liu, Jia-Bin; Wu, Jin-Ming

    2017-01-01

    To magnify anatase/rutile phase junction effects through appropriate Au decorations, a facile solution-based approach was developed to synthesize Au/TiO2 nanoforests with controlled Au locations. The nanoforests cons®isted of anatase nanowires surrounded by radially grown rutile branches, on which Au nanoparticles were deposited with preferred locations controlled by simply altering the order of the fabrication step. The Au-decoration increased the photocatalytic activity under the illumination of either UV or visible light, because of the beneficial effects of either electron trapping or localized surface plasmon resonance (LSPR). Gold nanoparticles located preferably at the interface of anatase/rutile led to a further enhanced photocatalytic activity. The appropriate distributions of Au nanoparticles magnify the beneficial effects arising from the anatase/rutile phase junctions when illuminated by UV light. Under the visible light illumination, the LSPR effect followed by the consecutive electron transfer explains the enhanced photocatalysis. This study provides a facile route to control locations of gold nanoparticles in one-dimensional nanostructured arrays of multiple-phases semiconductors for achieving a further increased photocatalytic activity. PMID:28117448

  20. Adsorption mechanisms of L-Glutathione on Au and controlled nano-patterning through Dip Pen Nanolithography

    Energy Technology Data Exchange (ETDEWEB)

    Calborean, A., E-mail: adrian.calborean@gmail.com [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania); Martin, F.; Marconi, D.; Turcu, R.; Kacso, I.E.; Buimaga-Iarinca, L. [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania); Graur, F. [Iuliu Haţieganu University of Medicine and Pharmacy Cluj-Napoca, Babeş 8, 400012 Cluj-Napoca (Romania); Turcu, I. [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania)

    2015-12-01

    Dip Pen Nanolithography technique has been employed for patterning L-Glutathione tripeptide (L-y-glutamyl-L-cysteinyl-glycine) nanostructures at specific locations on metallic Au(111) substrate. The formed supramolecular architectures were designed through straight lines and dots serving as precursors for building blocks assemblies in nano-bio-electronics applications or as template structures for functionalized particles in the form of host–guest networks. Tween 20 polyoxyethylene surfactant concentrations ranging from 0.005 to 0.1% (v/v) into initial L-Glutathione tripeptide (2 mg mL{sup −1}) ink solutions were sequentially tested for the improvement of the ink delivery process and to assure an optimum uniformity and homogeneity over the patterned space. A strong relationship was found between the coated atomic force microscope (AFM) cantilever within the highly effective Tween 20 activator adjuvant and the molecular diffusion along concentration gradients. An increase in the driving force for ink transport from the AFM tip has been demonstrated within the highest 0.1% (v/v) TW 20 surfactant concentration, favoring the patterning of GSH molecules routinely with sub-100 nm resolution. Self-assembled monolayers of GSH were also fabricated and characterized in the light of X-ray photoemission spectroscopy (XPS) and ellipsometric optical measurements. Adsorption from water of L-Glutathione to the gold substrate is proven to be made by the thiol group of cysteine. Theoretical DFT approaches were applied for quantum chemical studies dedicated to electronic processes underneath molecular GSH/Au(111) systems. - Highlights: • Controlled nano-patterning of L-Glutathione was performed on Au by DPN. • Tween 20 was used for increasing driving force of molecular ink transport. • SAM's formation has described the adsorption mechanisms of L-Glutathione on Au. • Electronic properties of hybrid GSH/Au(111) structures were investigated by DFT. • Validation of

  1. Core-shell Au-Pd nanoparticles as cathode catalysts for microbial fuel cell applications

    Science.gov (United States)

    Yang, Gaixiu; Chen, Dong; Lv, Pengmei; Kong, Xiaoying; Sun, Yongming; Wang, Zhongming; Yuan, Zhenhong; Liu, Hui; Yang, Jun

    2016-01-01

    Bimetallic nanoparticles with core-shell structures usually display enhanced catalytic properties due to the lattice strain created between the core and shell regions. In this study, we demonstrate the application of bimetallic Au-Pd nanoparticles with an Au core and a thin Pd shell as cathode catalysts in microbial fuel cells, which represent a promising technology for wastewater treatment, while directly generating electrical energy. In specific, in comparison with the hollow structured Pt nanoparticles, a benchmark for the electrocatalysis, the bimetallic core-shell Au-Pd nanoparticles are found to have superior activity and stability for oxygen reduction reaction in a neutral condition due to the strong electronic interaction and lattice strain effect between the Au core and the Pd shell domains. The maximum power density generated in a membraneless single-chamber microbial fuel cell running on wastewater with core-shell Au-Pd as cathode catalysts is ca. 16.0 W m−3 and remains stable over 150 days, clearly illustrating the potential of core-shell nanostructures in the applications of microbial fuel cells. PMID:27734945

  2. Core-shell Au-Pd nanoparticles as cathode catalysts for microbial fuel cell applications

    Science.gov (United States)

    Yang, Gaixiu; Chen, Dong; Lv, Pengmei; Kong, Xiaoying; Sun, Yongming; Wang, Zhongming; Yuan, Zhenhong; Liu, Hui; Yang, Jun

    2016-10-01

    Bimetallic nanoparticles with core-shell structures usually display enhanced catalytic properties due to the lattice strain created between the core and shell regions. In this study, we demonstrate the application of bimetallic Au-Pd nanoparticles with an Au core and a thin Pd shell as cathode catalysts in microbial fuel cells, which represent a promising technology for wastewater treatment, while directly generating electrical energy. In specific, in comparison with the hollow structured Pt nanoparticles, a benchmark for the electrocatalysis, the bimetallic core-shell Au-Pd nanoparticles are found to have superior activity and stability for oxygen reduction reaction in a neutral condition due to the strong electronic interaction and lattice strain effect between the Au core and the Pd shell domains. The maximum power density generated in a membraneless single-chamber microbial fuel cell running on wastewater with core-shell Au-Pd as cathode catalysts is ca. 16.0 W m‑3 and remains stable over 150 days, clearly illustrating the potential of core-shell nanostructures in the applications of microbial fuel cells.

  3. Controlling the Nanoscale Patterning of AuNPs on Silicon Surfaces

    Directory of Open Access Journals (Sweden)

    Chris J. Allender

    2013-03-01

    Full Text Available This study evaluates the effectiveness of vapour-phase deposition for creating sub-monolayer coverage of aminopropyl triethoxysilane (APTES on silicon in order to exert control over subsequent gold nanoparticle deposition. Surface coverage was evaluated indirectly by observing the extent to which gold nanoparticles (AuNPs deposited onto the modified silicon surface. By varying the distance of the silicon wafer from the APTES source and concentration of APTES in the evaporating media, control over subsequent gold nanoparticle deposition was achievable to an extent. Fine control over AuNP deposition (AuNPs/μm2 however, was best achieved by adjusting the ionic concentration of the AuNP-depositing solution. Furthermore it was demonstrated that although APTES was fully removed from the silicon surface following four hours incubation in water, the gold nanoparticle-amino surface complex was stable under the same conditions. Atomic force microscopy (AFM and X-ray photoelectron spectroscopy (XPS were used to study these affects.

  4. Magnetic susceptibility and hardness of Au-xPt-yNb alloys for biomedical applications.

    Science.gov (United States)

    Uyama, Emi; Inui, Shihoko; Hamada, Kenichi; Honda, Eiichi; Asaoka, Kenzo

    2013-09-01

    Metal devices in the human body induce serious metal artifacts in magnetic resonance imaging (MRI). Metals artifacts are mainly caused by a volume magnetic susceptibility (χv) mismatch between a metal device and human tissue. In this research, Au-xPt-yNb alloys were developed for fabricating MRI artifact-free biomedical metal devices. The magnetic properties, hardness and phase constitutions of these alloys were investigated. The Au-xPt-8Nb alloys showed satisfactory χv values. Heat treatments did not clearly change the χv values for Au-xPt-8Nb alloys. The Vickers hardness (HV) of these two alloys was much higher than that of high-Pt alloys; moreover, aging at 700°C increased the HV values of these two alloys. A dual phase structure consisting of face-centered cubic α1 and α2 phases was observed and aging at 700°C promoted phase separation. The Au-5Pt-8Nb and Au-10Pt-8Nb alloys showed satisfactory χv values and high hardness and are thus suggested as candidates for MRI artifact-free alloys for biomedical applications.

  5. Au dotted magnetic network nanostructure and its application for on-site monitoring femtomolar level pesticide.

    Science.gov (United States)

    Yang, Tianxi; Guo, Xiaoyu; Wang, Hui; Fu, Shuyue; Yu, Jie; Wen, Ying; Yang, Haifeng

    2014-04-09

    A novel magnetically responsive and surface-enhanced Raman spectroscopy (SERS) active nanocomposite is designed and prepared by direct grafting of Au nanoparticles onto the surface of magnetic network nanostructure (MNN) with the help of a nontoxic and environmentally friendly reagent of inositol hexakisphosphate shortly named as IP6. The presence of IP6 as a stabilizer and a bridging agent could weave Fe3O4 nanoparticles (NPs) into magnetic network nanostructure, which is easily dotted with Au nanoparticles (Au NPs). It has been shown firstly that the huge Raman enhancement of Au-MNN is reached by an external magnetic collection. Au-MNN presenting the large surface and high detection sensitivity enables it to exhibit multifunctional applications involving sufficient adsorption of dissolved chemical species for enrichment, separation, as well as a Raman amplifier for the analysis of trace pesticide residues at femtomolar level by a portable Raman spectrometer. Therefore, such multifunctional nanocomposites can be developed as a smart and promising nanosystem that integrates SERS approach with an easy assay for concentration by an external magnet for the effective on-site assessments of agricultural and environmental safety.

  6. Organisation and Control of Nanoscale Structures on Au(111)

    DEFF Research Database (Denmark)

    Zhang, Jingdong; Chi, Qijin; Andersen, Jens Enevold Thaulov;

    2001-01-01

    system is IDe arnino acid cystine in the adsorbed state. Af ter dissociation of its disulfide band cystine farms a highly ordered pattem controlled by adsorption via IDe liberated sulfur atoms and intermolecular hydrogen bonding. Further organisation at three different leveis by lateral interactions can...

  7. Atomic force microscopy investigation of the kinetic growth mechanisms of sputtered nanostructured Au film on mica: towards a nanoscale morphology control

    Directory of Open Access Journals (Sweden)

    Torrisi Vanna

    2011-01-01

    Full Text Available Abstract The study of surface morphology of Au deposited on mica is crucial for the fabrication of flat Au films for applications in biological, electronic, and optical devices. The understanding of the growth mechanisms of Au on mica allows to tune the process parameters to obtain ultra-flat film as suitable platform for anchoring self-assembling monolayers, molecules, nanotubes, and nanoparticles. Furthermore, atomically flat Au substrates are ideal for imaging adsorbate layers using scanning probe microscopy techniques. The control of these mechanisms is a prerequisite for control of the film nano- and micro-structure to obtain materials with desired morphological properties. We report on an atomic force microscopy (AFM study of the morphology evolution of Au film deposited on mica by room-temperature sputtering as a function of subsequent annealing processes. Starting from an Au continuous film on the mica substrate, the AFM technique allowed us to observe nucleation and growth of Au clusters when annealing process is performed in the 573-773 K temperature range and 900-3600 s time range. The evolution of the clusters size was quantified allowing us to evaluate the growth exponent 〈z〉 = 1.88 ± 0.06. Furthermore, we observed that the late stage of cluster growth is accompanied by the formation of circular depletion zones around the largest clusters. From the quantification of the evolution of the size of these zones, the Au surface diffusion coefficient was evaluated in D ( T   =   [ ( 7 . 42   ×   1 0 − 13   ±   ( 5 . 94   ×   1 0 − 14   m 2 /s ] exp ( − ( 0.33 ± 0.04   eV k T . These quantitative data and their correlation with existing theoretical models elucidate the kinetic growth mechanisms of the sputtered Au on mica. As a consequence we acquired a methodology to control the morphological characteristics of the Au film simply controlling the annealing temperature and time.

  8. Mesoporous Silica Supported Au Nanoparticles with Controlled Size as Efficient Heterogeneous Catalyst for Aerobic Oxidation of Alcohols

    Directory of Open Access Journals (Sweden)

    Xuefeng Chu

    2015-01-01

    Full Text Available A series of Au catalysts with different sizes were synthesized and employed on amine group functionalized ordered mesoporous silica solid supports as catalyst for the aerobic oxidation of various alcohols. The mesoporous silica of MCM-41 supported Au nanoparticles (Au-1 exhibited the smallest particle size at ~1.8 nm with superior catalytic activities owing to the confinement effect of the mesoporous channels. Au-1 catalyst is also very stable and reusable under aerobic condition. Therefore, this presented work would obviously provide us a platform for synthesizing more size-controlled metal catalysts to improve the catalytic performances.

  9. Controlled building of CdSe@ZnS/Au and CdSe@ZnS/ Au2S/Au nanohybrids

    Institute of Scientific and Technical Information of China (English)

    Raquel E. Galian[1; Pilar Diaz[1; Antonio Ribera[1; Alejandro Rincon-Bertolin[1; Said Agouram[2; Julia Perez-Prieto[1

    2015-01-01

    The addition of Au3. to spherical amine-capped CdSe@ZnS nanoparticles in toluene at room temperature and under darkness can lead to ternary CdSe@ZnS/Au nanohybrids. We demonstrate that this happens only when the nanoparticles possess a relatively thin ZnS shell, thus showing that thickness plays a key role in gold deposition on the CdSe@ZnS nanoparticle surface. Our hypothesis is that the amine ligand acts as the reductant of Au3+ ions into Au+ ions, whose affinity for sulfur would keep them at the CdSe@ZnS surface. This interaction stabilizes the Au+ ion, making it less prone to reduction than a non-coordinated Au+ ion. In CdSe@ZnS with a thin shell, Au+ ions at the surface of, or most probably within, the ZnS shell cause the transfer of Cd2+ ions into the solution. Subsequently, the core Se2- anion, which is a better reductant than the shell S2- reduces Au+ ions to Au(0), and large gold nanoparticles (AuNPs) are quickly deposited on the CdSe@ZnS surface in room temperature process, leading to ternary CdSe@ZnS/Au nanohybrids. In solution, these ternary nanohybrids progressively transform into quaternary CdSe@ZnS/Au2S/Au nanohybrids due to the reaction of the shell S2- anion with the remaining Au+ at the CdSe@ZnS surface, thus leading to the growth of Au2S nanoparticles on the CdSe@ZnS surface while Zn concomitantly leaches from the nanohybrid into the solution. Photoirradiation of the heterostructures with visible light enhances their emission efficiency. Comparatively, irradiation of the precursors, i.e., CdSe@ZnS nanoparticles, causes a drastic decrease in their emission accompanied by a blue shift of their emission maximum. The optical properties of these nanohybrids were analyzed by absorption and fluorescence (steady-state and time-resolved) spectroscopy, and the composition of the samples and the chemical states were determined by energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy

  10. Green synthesis and applications of Au-Ag bimetallic nanoparticles.

    Science.gov (United States)

    Meena Kumari, M; Jacob, John; Philip, Daizy

    2015-02-25

    This paper reports for the first time the synthesis of bimetallic nanoparticles at room temperature using the fruit juice of pomegranate. Simultaneous reduction of gold and silver ions in different molar ratios leads to the formation of alloy as well as core-shell nanostructures. The nanoparticles have been characterized using UV-vis spectroscopy, transmission electron microscopy, Fourier Transform Infrared Spectroscopy and X-ray diffraction. The synthesized alloy particles are used as catalysts in the reduction of 2-, 3-, 4-nitrophenols to the corresponding amines and in the degradation of methyl orange. The reduction kinetics for all the reactions follows pseudo-first order. The rate constants follow the order k4-nitrophenolnanoparticles enhances the thermal conductivity of the base fluid (water) showing nanofluid application. The nitric oxide and hydroxyl radical scavenging activity shown by the nanoparticles promise the potential application in biomedical field.

  11. FRET controlled photoluminescence in β-In2S3 microflower—Au nanoparticle ensemble

    Science.gov (United States)

    Warrier, Anita R.; Parameswaran, Chithra; Bingi, Jayachandra; Vijayan, C.

    2016-06-01

    We report on the exciton-plasmon interaction and fluorescence resonance energy transfer controlled photoluminescence quenching and switching in β-In2S3 microflowers dispersed in Au nanoparticle colloid. The strong resonant interaction of excited β-In2S3 microflowers with the surface plasmons of Au nanoparticles (˜520 nm) lead to shift in the excitonic binding energy (2.4 eV) with a magnitude of ˜50 meV. In the proximity of Au nanoparticles, the broad emission spectrum of β-In2S3 microflowers with prominent peak at wavelength of ˜540 nm is quenched and the peak switches to wavelength of ˜600 nm. We demonstrate that the quenching and switching of emission band depends on the rate of fluorescence resonance energy transfer, extent of spectral overlap and β-In2S3 microflowers (donor)- Au nanoparticles (acceptor) distance. This study opens the wide possibility of fabricating sensors and photonic devices with tunable optical properties.

  12. Quality Control Applications

    CERN Document Server

    Chorafas, Dimitris N

    2013-01-01

    Quality control is a constant priority in electrical, mechanical, aeronautical, and nuclear engineering – as well as in the vast domain of electronics, from home appliances to computers and telecommunications. Quality Control Applications provides guidance and valuable insight into quality control policies; their methods, their implementation, constant observation and associated technical audits. What has previously been a mostly mathematical topic is translated here for engineers concerned with the practical implementation of quality control. Once the fundamentals of quality control are established, Quality Control Applications goes on to develop this knowledge and explain how to apply it in the most effective way. Techniques are described and supported using relevant, real-life, case studies to provide detail and clarity for those without a mathematical background. Among the many practical examples, two case studies dramatize the importance of quality assurance: A shot-by-shot analysis of the errors made ...

  13. Internal-Modified Dithiol DNA-Directed Au Nanoassemblies: Geometrically Controlled Self-Assembly and Quantitative Surface-Enhanced Raman Scattering Properties

    Science.gov (United States)

    Yan, Yuan; Shan, Hangyong; Li, Min; Chen, Shu; Liu, Jianyu; Cheng, Yanfang; Ye, Cui; Yang, Zhilin; Lai, Xuandi; Hu, Jianqiang

    2015-11-01

    In this work, a hierarchical DNA-directed self-assembly strategy to construct structure-controlled Au nanoassemblies (NAs) has been demonstrated by conjugating Au nanoparticles (NPs) with internal-modified dithiol single-strand DNA (ssDNA) (Au-B-A or A-B-Au-B-A). It is found that the dithiol-ssDNA-modified Au NPs and molecule quantity of thiol-modified ssDNA grafted to Au NPs play critical roles in the assembly of geometrically controlled Au NAs. Through matching Au-DNA self-assembly units, geometrical structures of the Au NAs can be tailored from one-dimensional (1D) to quasi-2D and 2D. Au-B-A conjugates readily give 1D and quasi-2D Au NAs while 2D Au NAs can be formed by A-B-Au-B-A building blocks. Surface-enhanced Raman scattering (SERS) measurements and 3D finite-difference time domain (3D-FDTD) calculation results indicate that the geometrically controllable Au NAs have regular and linearly “hot spots”-number-depended SERS properties. For a certain number of NPs, the number of “hot spots” and accordingly enhancement factor of Au NAs can be quantitatively evaluated, which open a new avenue for quantitative analysis based on SERS technique.

  14. Optimised photocatalytic hydrogen production using core–shell AuPd promoters with controlled shell thickness

    DEFF Research Database (Denmark)

    Jones, Wilm; Su, Ren; Wells, Peter

    2014-01-01

    on photocatalytic performance remains unclear. Here we report the synthesis of core–shell structured AuPd NPs with the controlled deposition of one and two monolayers (ML) equivalent of Pd onto Au NPs by colloidal and photodeposition methods. We have determined the shell composition and thickness......The development of efficient photocatalytic routines for producing hydrogen is of great importance as society moves away from energy sources derived from fossil fuels. Recent studies have identified that the addition of metal nanoparticles to TiO2 greatly enhances the photocatalytic performance...... of these materials towards the reforming of alcohols for hydrogen production. The core–shell structured Au–Pd bimetallic nanoparticle supported on TiO2 has being of interest as it exhibited extremely high quantum efficiencies for hydrogen production. However, the effect of shell composition and thickness...

  15. Analysis of the applicability of Ni, Cu, Au, Pt, and Pd nanoclusters for data recording

    Science.gov (United States)

    Redel', L. V.; Gafner, S. L.; Gafner, Yu. Ya.; Zamulin, I. S.; Goloven'ko, Zh. V.

    2017-02-01

    The applicability of individual Ni, Cu, Au, Pt, and Pd nanoclusters as data bits in next generation memory devices constructed on the phase-change carrier principle is studied. To this end, based on the modified tight-binding potential (TB-SMA), structure formation from the melt of nanoparticles of these metals to 10 nm in diameter was simulated by the molecular dynamics method. The effect of various crystallization conditions on the formation of the internal structures of Ni, Cu, Au, Pt, and Pd nanoclusters is studied. The stability boundaries of various crystalline isomers are analyzed. The obtained systematic features are compared for nanoparticles of copper, nickel, gold, platinum, and palladium of identical sizes. It is concluded that platinum nanoclusters of diameter D > 8 nm are the best materials among studied metals for producing memory elements based on phase transitions.

  16. Antitumor therapeutic application of self-assembled RNAi-AuNP nanoconstructs: Combination of VEGF-RNAi and photothermal ablation

    Science.gov (United States)

    Son, Sejin; Kim, Namho; You, Dong Gil; Yoon, Hong Yeol; Yhee, Ji Young; Kim, Kwangmeyung; Kwon, Ick Chan; Kim, Sun Hwa

    2017-01-01

    Nucleic acid-directed self-assembly provides an attractive method to fabricate prerequisite nanoscale structures for a wide range of technological applications due to the remarkable programmability of DNA/RNA molecules. In this study, exquisite RNAi-AuNP nanoconstructs with various geometries were developed by utilizing anti-VEGF siRNA molecules as RNAi-based therapeutics in addition to their role as building blocks for programmed self-assembly. In particular, the anti-VEGF siRNA-functionalized AuNP nanoconstructs can take additional advantage of gold-nanoclusters for photothermal cancer therapeutic agent. A noticeable technical aspect of self-assembled RNAi-AuNP nanoconstructs in this study is the precise conjugation and separation of designated numbers of therapeutic siRNA onto AuNP to develop highly sophisticated RNA-based building blocks capable of creating various geometries of RNAi-AuNP nano-assemblies. The therapeutic potential of RNAi-AuNP nanoconstructs was validated in vivo as well as in vitro by combining heat generation capability of AuNP and anti-angiogenesis mechanism of siRNA. This strategy of combining anti-VEGF mechanism for depleting angiogenesis process at initial tumor progression and complete ablation of residual tumors with photothermal activity of AuNP at later tumor stage showed effective tumor growth inhibition and tumor ablation with PC-3 tumor bearing mice. PMID:28042312

  17. Plasmonic effects of au/ag bimetallic multispiked nanoparticles for photovoltaic applications.

    Science.gov (United States)

    Sharma, Manisha; Pudasaini, Pushpa Raj; Ruiz-Zepeda, Francisco; Vinogradova, Ekaterina; Ayon, Arturo A

    2014-09-10

    In recent years, there has been considerable interest in the use of plasmons, that is, free electron oscillations in conductors, to boost the performance of both organic and inorganic thin film solar cells. This has been driven by the possibility of employing thin active layers in solar cells in order to reduce materials costs, and is enabled by significant advances in fabrication technology. The ability of surface plasmons in metallic nanostructures to guide and confine light in the nanometer scale has opened up new design possibilities for solar cell devices. Here, we report the synthesis and characterization of highly monodisperse, reasonably stable, multipode Au/Ag bimetallic nanostructures using an inorganic additive as a ligand for photovoltaic applications. A promising surface enhanced Raman scattering (SERS) effect has been observed for the synthesized bimetallic Au/Ag multispiked nanoparticles, which compare favorably well with their Au and Ag spherical nanoparticle counterparts. The synthesized plasmonic nanostructures were incorporated on the rear surface of an ultrathin planar c-silicon/organic polymer hybrid solar cell, and the overall effect on photovoltaic performance was investigated. A promising enhancement in solar cell performance parameters, including both the open circuit voltage (VOC) and short circuit current density (JSC), has been observed by employing the aforementioned bimetallic multispiked nanoparticles on the rear surface of solar cell devices. A power conversion efficiency (PCE) value as high as 7.70% has been measured in a hybrid device with Au/Ag multispiked nanoparticles on the rear surface of an ultrathin, crystalline silicon (c-Si) membrane (∼ 12 μm). This value compares well to the measured PCE value of 6.72% for a similar device without nanoparticles. The experimental observations support the hope for a sizable PCE increase, due to plasmon effects, in thin-film, c-Si solar cells in the near future.

  18. Controlled-layer and large-area MoSsub>2sub> films encapsulated Au nanoparticle hybrids for SERS.

    Science.gov (United States)

    Li, Zhen; Jiang, Shouzhen; Huo, Yanyan; Liu, Mei; Yang, Cheng; Zhang, Chao; Liu, Xiaoyun; Sheng, Yingqing; Li, Chonghui; Man, Baoyuan

    2016-11-14

    In this work, a facile and effective method for controlled-layer and large-area MoSsub>2sub> films encapsulated Au nanoparticle hybrids is developed. With accurate Ar plasma treatment time control, the large-area MoSsub>2sub> layers can be obtained from monolayer to trilayer. The fabricated MoSsub>2sub>@Au NPs with higher surface area exhibit excellent Raman enhanced effect for aromatic organic molecules (rhodamine 6G and crystal violet) and achieve the best when the monolayer MoSsub>2sub>@AuNPs was obtained. The limit of detection is found to be as low as 1 × 10-10 M. The MoSsub>2sub>@AuNPs was characterized by SEM, EDS, AFM, Raman spectroscopy, UV-Vis, XRD and HRTEM.

  19. Controllable synthesis and characterization of Fe{sub 3}O{sub 4}/Au composite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Yan; Jin, Yan-Yan; Si, Jian-Chao [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); Peng, Ming-Li, E-mail: mlpeng@nwu.edu.cn [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); Wang, Xiao-Fang [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); Chen, Chao [National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); College of Life Sciences, Northwest University, Xi' an 710069 (China); Cui, Ya-Li, E-mail: yalicui@nwu.edu.cn [National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); College of Life Sciences, Northwest University, Xi' an 710069 (China)

    2015-04-15

    Fe{sub 3}O{sub 4}/Au composite nanoparticles (GoldMag NPs) have received considerable attention because of their advantageous properties arisen from both individual Au and Fe{sub 3}O{sub 4} nanoparticles. Many efforts have been devoted to the synthesis of these composite nanoparticles. Herein, GoldMag NPs were reported to be synthesized by two-step method. Fe{sub 3}O{sub 4} nanoparticles were prepared by co-precipitation and modified by the citric acid, and then citric acid-coated Fe{sub 3}O{sub 4} nanoparticles were used as seeds in sodium citrate solution to reduce the HAuCl{sub 4}. The size of obtained nanoparticles was geared from 25 to 300 nm by controlling the concentration of reactants. The GoldMag NPs were characterized by UV–vis spectrometer, dynamic light scattering (DLS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The GoldMag NPs showed good superparamagnetism at room temperature and were well dispersed in water with surface plasmon resonance absorption peak varied from 538 nm to 570 nm. - Highlights: • A low cost, simple manipulation and nontoxic approach was designed for preparation of magnetic Fe{sub 3}O{sub 4}/Au (GoldMag NPs) nanocomposites. • The size of GoldMag NPs could be controlled from 25 to 300 nm by varying the concentration of reactants. • GoldMag NPs possessed good magnetic response, high dispersion, and good stability.

  20. Fluorescence Emission Study of Cdse/ZnS Quantum Dot and Au Nanoparticles Composite for Application in Quantum Dot Solar Concentrators

    OpenAIRE

    Chandra, Subhash; Doran, John; Kennedy, Manus; McCormack, S.; Chatten, A

    2011-01-01

    Fluorescence of core shell (CdSe/ZnS) quantum dots (QDs) and Au nanoparticles (NPs) composite has been studied for application in quantum dot solar concentrators (QDSC). We conclude two points from the particular QD/Au NP composite studied. One; for the particular Au NPs concentration, the relative fluorescence emission enhancement increases with decreasing QD concentration. Second; the enhancement is more pronounced for the Au nanoparticles whose surface plasmon resonance wavelength overlaps...

  1. Controlling crystal phases in GaAs nanowires grown by Au-assisted molecular beam epitaxy.

    Science.gov (United States)

    Dheeraj, D L; Munshi, A M; Scheffler, M; van Helvoort, A T J; Weman, H; Fimland, B O

    2013-01-11

    Control of the crystal phases of GaAs nanowires (NWs) is essential to eliminate the formation of stacking faults which deteriorate the optical and electronic properties of the NWs. In addition, the ability to control the crystal phase of NWs provides an opportunity to engineer the band gap without changing the crystal material. We show that the crystal phase of GaAs NWs grown on GaAs(111)B substrates by molecular beam epitaxy using the Au-assisted vapor-liquid-solid growth mechanism can be tuned between wurtzite (WZ) and zinc blende (ZB) by changing the V/III flux ratio. As an example we demonstrate the realization of WZ GaAs NWs with a ZB GaAs insert that has been grown without changing the substrate temperature.

  2. Mechanical control of the plasmon coupling with Au nanoparticle arrays fixed on the elastomeric film via chemical bond

    Science.gov (United States)

    Bedogni, Elena; Kaneko, Satoshi; Fujii, Shintaro; Kiguchi, Manabu

    2017-03-01

    We have fabricated Au nanoparticle arrays on the flexible poly(dimethylsiloxane) (PDMS) film. The nanoparticles were bound to the film via a covalent bond by a ligand exchange reaction. Thanks to the strong chemical bonding, highly stable and uniformly dispersed Au nanoparticle arrays were fixed on the PDMS film. The Au nanoparticle arrays were characterized by the UV–vis, scanning electron microscope (SEM) and surface enhanced Raman scattering (SERS). The UV–vis and SEM measurements showed the uniformity of the surface-dispersed Au nanoparticles, and SERS measurement confirmed the chemistry of the PDMS film. Reflecting the high stability and the uniformity of the Au nanoparticle arrays, the plasmon wavelength of the Au nanoparticles reversely changed with modulation of the interparticle distance, which was induced by the stretching of the PDMS film. The plasmon wavelength linearly decreased from 664 to 591 nm by stretching of 60%. The plasmon wavelength shift can be explained by the change in the strength of the plasmon coupling which is mechanically controlled by the mechanical strain.

  3. Properties of ordered titanium templates covered with Au thin films for SERS applications

    Science.gov (United States)

    Grochowska, Katarzyna; Siuzdak, Katarzyna; Sokołowski, Michał; Karczewski, Jakub; Szkoda, Mariusz; Śliwiński, Gerard

    2016-12-01

    Currently, roughened metal nanostructures are widely studied as highly sensitive Raman scattering substrates that show application potential in biochemistry, food safety or medical diagnostic. In this work the structural properties and the enhancement effect due to surface enhanced Raman scattering (SERS) of highly ordered nano-patterned titanium templates covered with thin (5-20 nm) gold films are reported. The templates are formed by preparation of a dense structure of TiO2 nanotubes on a flat Ti surface (2 × 2 cm2) and their subsequent etching down to the substrate. SEM images reveal the formation of honeycomb nanostructures with the cavity diameter of 80 nm. Due to the strongly inhomogeneous distribution of the electromagnetic field in the vicinity of the Au film discontinuities the measured average enhancement factor (107-108) is markedly higher than observed for bare Ti templates. The enhancement factor and Raman signal intensity can be optimized by adjusting the process conditions and thickness of the deposited Au layer. Results confirm that the obtained structures can be used in surface enhanced sensing.

  4. Au-SN Flip-Chip Solder Bump for Microelectronic and Optoelectronic Applications

    CERN Document Server

    Yoon, Jeong-Won; Koo, Ja-Myeong; Jung, Seung-Boo

    2007-01-01

    As an alternative to the time-consuming solder pre-forms and pastes currently used, a co-electroplating method of eutectic Au-Sn alloy was used in this study. Using a co-electroplating process, it was possible to plate the Au-Sn solder directly onto a wafer at or near the eutectic composition from a single solution. Two distinct phases, Au5Sn and AuSn, were deposited at a composition of 30at.%Sn. The Au-Sn flip-chip joints were formed at 300 and 400 degrees without using any flux. In the case where the samples were reflowed at 300 degrees, only an (Au,Ni)3Sn2 IMC layer formed at the interface between the Au-Sn solder and Ni UBM. On the other hand, two IMC layers, (Au,Ni)3Sn2 and (Au,Ni)3Sn, were found at the interfaces of the samples reflowed at 400 degrees. As the reflow time increased, the thickness of the (Au,Ni)3Sn2 and (Au,Ni)3Sn IMC layers formed at the interface increased and the eutectic lamellae in the bulk solder coarsened.

  5. Interaction of Au, Ag, and Bi ions with Ba2YCu3O(7-y) - Implications for superconductor applications

    Science.gov (United States)

    Hepp, A. F.; Gaier, J. R.; Pouch, J. J.; Hambourger, P. D.

    1988-01-01

    Results are presented on the reactions of Au, Ag, and Bi ions with Ba2YCu3O(7-y) oxides and on the properties of the resultant materials. The results indicate that Au(3+) structural chemistry makes gold an excellent candidate for multiphase structures of the Ba2Y(Cu/1-x/Au/x/)3O(7-y)-type substituted superconductors. Silver is structurally and chemically compatible with the perovskite structure, but when it forms a second phase, it does so without the destruction of the superconducting phase, making silver a useful metal for metal/ceramic applications. On the other hand, bismuth was shown to degrade Tc phase or to form other phases, indicating that it may not be useful in applications with rare-earth-based superconductors.

  6. Development of ultrafine multichannel microfluidic mixer for synthesis of bimetallic nanoclusters: catalytic application of highly monodisperse AuPd nanoclusters stabilized by poly(N-vinylpyrrolidone).

    Science.gov (United States)

    Hayashi, Naoto; Sakai, Yuka; Tsunoyama, Hironori; Nakajima, Atsushi

    2014-09-02

    On account of their novel properties, bimetallic nanoparticles and nanoclusters (NCs) are strong potential candidates for optical, magnetic, and catalytic functional materials. These properties depend on the chemical composition and size (number of constituent atoms) of the NCs. Control of size, structure, and composition is particularly important for fabricating highly functional materials based on bimetallic NCs. Size- and structure-controlled synthesis of two-element alloys can reveal their intrinsic electronic synergistic effects. However, because synergistic enhancement of activity is strongly affected by composition as well as by size and structure, controlled synthesis is a challenging task, particularly in catalytic applications. To investigate catalytic synergistic effects, we have synthesized highly monodisperse, sub-2 nm, solid-solution AuPd NCs stabilized with poly(N-vinylpyrrolidone) (AuPd:PVP) using a newly developed ultrafine microfluidic mixing device with 15 μm wide multiple lamination channels. The synergistic enhancement for catalytic aerobic oxidation of benzyl alcohol exhibited a volcano-shaped trend, with a maximum at 20-65 at. % Pd. From X-ray photoelectron spectroscopic measurements, we confirmed that the enhanced activity originates from the enhanced electron density at the Au sites, donated by Pd sites.

  7. Shape-controlled synthesis of Au@Pd core-shell nanoparticles and their corresponding electrochemical properties

    KAUST Repository

    Song, Hyon Min

    2012-01-01

    The shape-controlled synthesis of Au@Pd core-shell nanoparticles (NPs) was successfully achieved through the emulsion phase generated during the phase transfer from organic to aqueous medium. Contrary to conventional epitaxial growth for obtaining core-shell structures, this method does not require high temperatures and does not have shape restrictions. © 2012 The Royal Society of Chemistry.

  8. Formation of Au nanoparticles on CNTs three dimensional structure for LSPR biosensor application

    Science.gov (United States)

    Yang, Ming; Shimizu, Tetsuhide

    2017-02-01

    A 3D LSPR sensor was fabricated by using CNTs as support and depositing AuNPs on the support in this study. We proposed a simple process to arrange AuNPs to CNTs by using vacuum deposition and annealing for 3D LSPR sensor. In order to fabricate 3D LSPR sensor, CNTs was synthesized and patterned on quartz glass substrate by CVD method and photolithography. For the synthesis of AuNPs, Au thin film was deposited on glass and CNTs by vacuum deposition. After deposition, Au thin film on glass and CNTs was particulated by annealing. The performance of 3D LSPR sensor was confirmed using BSA for bio analysis. LSPR characteristics was measured and compared before and after adsorption of BSA. The detection limit was 100ng/ml and detection sensitivity was 10 times in comparison with 2D LSPR sensor of same AuNPs formation condition.

  9. Controlling the stereochemistry and regularity of butanethiol self-assembled monolayers on Au(111)

    DEFF Research Database (Denmark)

    Yan, Jiawei; Ouyang, Runhai; Jensen, Palle Skovhus;

    2014-01-01

    The rich stereochemistry of the self-assembled monolayers (SAMs) of four butanethiols on Au(111) is described, the SAMs containing up to 12 individual C, S, or Au chiral centers per surface unit cell. This is facilitated by synthesis of enantiomerically pure 2-butanethiol (the smallest unsubstitu...

  10. Controlling core/shell Au/FePt nanoparticle electrocatalysis via changing the core size and shell thickness.

    Science.gov (United States)

    Sun, Xiaolian; Li, Dongguo; Guo, Shaojun; Zhu, Wenlei; Sun, Shouheng

    2016-02-01

    Using a modified seed-mediated method, we synthesized core/shell Au/FePt nanoparticles (NPs) with Au sizes of 4, 7, and 9 nm and the FePt shell was controlled to have similar FePt compositions and 0.5, 1, and 2 nm thickness. We studied both core and shell effects on electrochemical and electrocatalytic properties of the Au/FePt NPs, and found that the Au core did change the redox chemistry of the FePt shell and promoted its electrochemical oxidation of methanol. The catalytic activity was dependent on the FePt thicknesses, but not much on the Au core sizes, and the 1 nm FePt shell was found to be the optimal thickness for catalyzing methanol oxidation in 0.1 M HClO4 + 0.1 M methanol, offering not only high activity (1.19 mA cm(-2) at 0.5 V vs. Ag/AgCl), but also enhanced stability. Our studies demonstrate a general approach to the design and tuning of shell catalysis in the core/shell structure to achieve optimal catalysis for important electrochemical reactions.

  11. Sonophotodeposition of bimetallic photocatalysts Pd-Au/TiO2 : application to selective oxidation of methanol to methyl formate.

    Science.gov (United States)

    Colmenares, Juan C; Lisowski, Paweł; Łomot, Dariusz; Chernyayeva, Olga; Lisovytskiy, Dmytro

    2015-05-22

    The aim of this work is to develop bimetallic Pd-Au/TiO2 P90 systems, which are highly active and selective for the photocatalytic oxidation of methanol to form methyl formate. Modification of commercial TiO2 P90 with Pd-Au nanoparticles was successfully achieved for the first time by means of a sonophotodeposition (SPD) method. The prepared materials were characterized by TEM, UV/Vis spectroscopy, X-ray photoelectron spectroscopy, and powder XRD. The Pd-Au bimetallic nanoparticles supported on titania exhibited remarkably enhanced catalytic activity in selective methanol oxidation to form methyl formate due to the synergism of Au and Pd particles, as well as the strong interaction between TiO2 and Pd-Au. SPD is a green methodology that can be used to prepare well-defined bimetallic surfaces on semiconductor supports with great promise for catalytic applications, in which selectivity can be tuned through adjustment of the surface composition.

  12. Low temperature activation of Au/Ti getter film for application to wafer-level vacuum packaging

    Science.gov (United States)

    Wu, Ming; Moulin, Johan; Lani, Sébastien; Hallais, Géraldine; Renard, Charles; Bosseboeuf, Alain

    2015-03-01

    Non-evaporable getter (NEG) thin films based on alloys of transition metals have been studied by various authors for vacuum control in wafer-level packages of micro electro mechanical systems (MEMS). These materials have typically a relatively high activation temperature (300-450 °C) which is incompatible with some temperature sensitive MEMS devices. In this work we investigate the potential of Au/Ti system with a thin or ultrathin non oxidizable Au layer as a low activation temperature getter material. In this bilayer system, gettering activation is produced by thermal outdiffusion of titanium atoms through the gold film. The outdiffusion kinetics of titanium was modelled and characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Rutherford backscattering spectrometry (RBS) at various temperatures. Results confirm that Au/Ti bilayer is a promising getter material for wafer-level packaging with an activation temperature below 300 °C for 1 h annealing time.

  13. Self-standing corrugated Ag and Au-nanorods for plasmonic applications

    DEFF Research Database (Denmark)

    Habouti, S.; Mátéfi-Tempfli, M.; Solterbeck, C.-H.;

    2011-01-01

    We use home-made Si-supported anodized alumina thin film templates for the electrodeposition of large area self-standing Ag- and Au-nanorod (Au-NR) arrays. The deposition conditions chosen, i.e. electrolyte composition and deposition voltage, lead to a corrugated rod morphology, particularly for ...

  14. Tunable thermodynamic stability of Au-CuPt core-shell trimetallic nanoparticles by controlling the alloy composition: insights from atomistic simulations.

    Science.gov (United States)

    Huang, Rao; Shao, Gui-Fang; Wen, Yu-Hua; Sun, Shi-Gang

    2014-11-07

    A microscopic understanding of the thermal stability of metallic core-shell nanoparticles is of importance for their synthesis and ultimately application in catalysis. In this article, molecular dynamics simulations have been employed to investigate the thermodynamic evolution of Au-CuPt core-shell trimetallic nanoparticles with various Cu/Pt ratios during heating processes. Our results show that the thermodynamic stability of these nanoparticles is remarkably enhanced upon rising Pt compositions in the CuPt shell. The melting of all the nanoparticles initiates at surface and gradually spreads into the core. Due to the lattice mismatch among Au, Cu and Pt, stacking faults have been observed in the shell and their numbers are associated with the Cu/Pt ratios. With the increasing temperature, they have reduced continuously for the Cu-dominated shell while more stacking faults have been produced for the Pt-dominated shell because of the significantly different thermal expansion coefficients of the three metals. Beyond the overall melting, all nanoparticles transform into a trimetallic mixing alloy coated by an Au-dominated surface. This work provides a fundamental perspective on the thermodynamic behaviors of trimetallic, even multimetallic, nanoparticles at the atomistic level, indicating that controlling the alloy composition is an effective strategy to realize tunable thermal stability of metallic nanocatalysts.

  15. Control and optimal control theories with applications

    CERN Document Server

    Burghes, D N

    2004-01-01

    This sound introduction to classical and modern control theory concentrates on fundamental concepts. Employing the minimum of mathematical elaboration, it investigates the many applications of control theory to varied and important present-day problems, e.g. economic growth, resource depletion, disease epidemics, exploited population, and rocket trajectories. An original feature is the amount of space devoted to the important and fascinating subject of optimal control. The work is divided into two parts. Part one deals with the control of linear time-continuous systems, using both transfer fun

  16. Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2

    Science.gov (United States)

    Saavedra, Johnny; Whittaker, Todd; Chen, Zhifeng; Pursell, Christopher J.; Rioux, Robert M.; Chandler, Bert D.

    2016-06-01

    Industrial hydrogen production through methane steam reforming exceeds 50 million tons annually and accounts for 2-5% of global energy consumption. The hydrogen product, even after processing by the water-gas shift, still typically contains ˜1% CO, which must be removed for many applications. Methanation (CO + 3H2 → CH4 + H2O) is an effective solution to this problem, but consumes 5-15% of the generated hydrogen. The preferential oxidation (PROX) of CO with O2 in hydrogen represents a more-efficient solution. Supported gold nanoparticles, with their high CO-oxidation activity and notoriously low hydrogenation activity, have long been examined as PROX catalysts, but have shown disappointingly low activity and selectivity. Here we show that, under the proper conditions, a commercial Au/Al2O3 catalyst can remove CO to below 10 ppm and still maintain an O2-to-CO2 selectivity of 80-90%. The key to maximizing the catalyst activity and selectivity is to carefully control the feed-flow rate and maintain one to two monolayers of water (a key CO-oxidation co-catalyst) on the catalyst surface.

  17. Neural Networks in Control Applications

    DEFF Research Database (Denmark)

    Sørensen, O.

    examined, and it appears that considering 'normal' neural network models with, say, 500 samples, the problem of over-fitting is neglible, and therefore it is not taken into consideration afterwards. Numerous model types, often met in control applications, are implemented as neural network models....... - Control concepts including parameter estimation - Control concepts including inverse modelling - Control concepts including optimal control For each of the three groups, different control concepts and specific training methods are detailed described.Further, all control concepts are tested on the same......The intention of this report is to make a systematic examination of the possibilities of applying neural networks in those technical areas, which are familiar to a control engineer. In other words, the potential of neural networks in control applications is given higher priority than a detailed...

  18. Monitoring Control Applications at CERN

    CERN Document Server

    Bernard, F; Milcent, H; Petrova, L B; Varela, F

    2011-01-01

    The Industrial Controls and Engineering (EN-ICE) group [1] of the Engineering Department at CERN has produced, and is responsible for the operation of around 60 applications, which control critical processes in the domains of cryogenics, quench protection systems, power interlocks for the Large Hadron Collider and other subsystems of the accelerator complex. These applications require 24/7 operation and a quick reaction to problems. For this reason the EN-ICE group is presently developing the Monitoring Operation of cOntrols Networks (MOON) tool to detect, anticipate and inform of possible anomalies in the integrity of the applications. The tool builds on top of Simatic WinCC Open Architecture (WinCC OA) [2] SCADA and makes usage of the Joint COntrols Project (JCOP) [3] and the UNified INdustrial COntrol System (UNICOS) [4] Frameworks developed at CERN. The tool provides centralized monitoring and software management of the different elements integrating the control systems like Windows and L...

  19. Facet-controlled phase separation in supersaturated Au-Ni nanoparticles upon shape equilibration

    Energy Technology Data Exchange (ETDEWEB)

    Herz, A., E-mail: andreas.herz@tu-ilmenau.de, E-mail: dong.wang@tu-ilmenau.de; Rossberg, D.; Hentschel, M.; Theska, F.; Wang, D., E-mail: andreas.herz@tu-ilmenau.de, E-mail: dong.wang@tu-ilmenau.de; Schaaf, P. [Department of Materials for Electronics and Electrical Engineering, Institute of Materials Science and Engineering and Institute of Micro- and Nanotechnologies MacroNano, TU Ilmenau, D-98693 Ilmenau (Germany); Friák, M. [Institute of Physics of Materials, Academy of Sciences of the Czech Republic, v.v.i., Žižkova 22, CZ-616 62 Brno (Czech Republic); Central European Institute of Technology, CEITEC MU, Masaryk University, Kamenice 5, CZ-625 00 Brno (Czech Republic); Holec, D. [Department of Physical Metallurgy and Materials Testing, Montanuniversität Leoben, A-8700 Leoben (Austria); Šob, M. [Central European Institute of Technology, CEITEC MU, Masaryk University, Kamenice 5, CZ-625 00 Brno (Czech Republic); Institute of Physics of Materials, Academy of Sciences of the Czech Republic, v.v.i., Žižkova 22, CZ-616 62 Brno (Czech Republic); Department of Chemistry, Faculty of Science, Masaryk University, Kotlářská 2, CZ-611 37 Brno (Czech Republic); Schneeweiss, O. [Institute of Physics of Materials, Academy of Sciences of the Czech Republic, v.v.i., Žižkova 22, CZ-616 62 Brno (Czech Republic)

    2015-08-17

    Solid-state dewetting is used to fabricate supersaturated, submicron-sized Au-Ni solid solution particles out of thin Au/Ni bilayers by means of a rapid thermal annealing technique. Phase separation in such particles is studied with respect to their equilibrium crystal (or Wulff) shape by subsequent annealing at elevated temperature. It is found that (100) faceting planes of the equilibrated particles are enriched with Ni and (111) faces with Au. Both phases are considered by quantum-mechanical calculations in combination with an error-reduction scheme that was developed to compensate for a missing exchange-correlation potential that would reliably describe both Au and Ni. The observed phase configuration is then related to the minimization of strongly anisotropic elastic energies of Au- and Ni-rich phases and results in a rather unique nanoparticle composite state that is characterized by nearly uniform value of elastic response to epitaxial strains all over the faceted surface. The same conclusion is yielded also by evaluating bi-axial elastic moduli when employing interpolated experimental elastic constants. This work demonstrates a useful route for studying features of physical metallurgy at the mesoscale.

  20. Lead Telluride Doped with Au as a Very Promising Material for Thermoelectric Applications

    Directory of Open Access Journals (Sweden)

    Pantelija M. Nikolic

    2015-01-01

    Full Text Available PbTe single crystals doped with monovalent Au or Cu were grown using the Bridgman method. Far infrared reflectivity spectra were measured at room temperature for all samples and plasma minima were registered. These experimental spectra were numerically analyzed and optical parameters were calculated. All the samples of PbTe doped with Au or Cu were of the “n” type. The properties of these compositions were analyzed and compared with PbTe containing other dopants. The samples of PbTe doped with only 3.3 at% Au were the best among the PbTe + Au samples having the lowest plasma frequency and the highest mobility of free carriers-electrons, while PbTe doped with Cu was the opposite. Samples with the lowest Cu concentration of 0.23 at% Cu had the best properties. Thermal diffusivity and electronic transport properties of the same PbTe doped samples were also investigated using a photoacoustic (PA method with the transmission detection configuration. The results obtained with the far infrared and photoacoustic characterization of PbTe doped samples were compared and discussed. Both methods confirmed that when PbTe was doped with 3.3 at% Au, thermoelectric and electrical properties of this doped semiconductor were both significantly improved, so Au as a dopant in PbTe could be used as a new high quality thermoelectric material.

  1. Controllers, observers, and applications thereof

    Science.gov (United States)

    Gao, Zhiqiang (Inventor); Miklosovic, Robert (Inventor); Radke, Aaron (Inventor); Zhou, Wankun (Inventor); Zheng, Qing (Inventor)

    2011-01-01

    Controller scaling and parameterization are described. Techniques that can be improved by employing the scaling and parameterization include, but are not limited to, controller design, tuning and optimization. The scaling and parameterization methods described here apply to transfer function based controllers, including PID controllers. The parameterization methods also apply to state feedback and state observer based controllers, as well as linear active disturbance rejection (ADRC) controllers. Parameterization simplifies the use of ADRC. A discrete extended state observer (DESO) and a generalized extended state observer (GESO) are described. They improve the performance of the ESO and therefore ADRC. A tracking control algorithm is also described that improves the performance of the ADRC controller. A general algorithm is described for applying ADRC to multi-input multi-output systems. Several specific applications of the control systems and processes are disclosed.

  2. Structural control and (remobilization of the extinct Haveri Au-Cu deposit, southern Finland

    Directory of Open Access Journals (Sweden)

    Nironen, M.

    1994-06-01

    Full Text Available The extinct Haveri Au-Cu deposit is located within mafic metalavas and mafic/ intermediate banded rocks of the Haveri Formation, in the western part of the Paleoproterozoic Tampere Schist Belt. The sulfide-bearing banded rocks display a large E-W trending fold structure in magnetic and electromagnetic maps. Field evidence suggest that the Au-Cu deposit is in a F1/F2 fold interferrence pattern in the western core of the large fold. The ore-forming elements concentrated into the F1 fold closure during D1 deformation. Sulfide-bearing fractures subparallel to S2 spaced cleavage indicate slight remobilization during D2.

  3. On-substrate, self-standing Au-nanorod arrays showing morphology controlled properties

    DEFF Research Database (Denmark)

    Habouti, S.; Mátéfi-Tempfli, M.; Solterbeck, C.-H.;

    2011-01-01

    We use supported alumina templates and electrodeposition to fabricate self-standing Au-nanorods (Au-NR) arrays. Depending on electrolyte and deposition conditions two different NR morphologies with either corrugated or smooth topologies are fabricated. We show that the properties of the NR arrays...... of the NR arrays as substrates for molecular detection using Raman scattering, and Rhodamine 6G (R6G) as model dye, also strongly depends on their morphology. R6G concentrations down to 1 pM are detected on the corrugated arrays yielding an effective enhancement factor (EF) of approximately 1 × 10...

  4. Engine Modelling for Control Applications

    DEFF Research Database (Denmark)

    Hendricks, Elbert

    1997-01-01

    In earlier work published by the author and co-authors, a dynamic engine model called a Mean Value Engine Model (MVEM) was developed. This model is physically based and is intended mainly for control applications. In its newer form, it is easy to fit to many different engines and requires little...... engine data for this purpose. It is especially well suited to embedded model applications in engine controllers, such as nonlinear observer based air/fuel ratio and advanced idle speed control. After a brief review of this model, it will be compared with other similar models which can be found...

  5. Binary self-assembled monolayers modified Au nanoparticles as carriers in biological applications.

    Science.gov (United States)

    Chang, Hsun-Yun; You, Yun-Wen; Liao, Hua-Yang; Shyue, Jing-Jong

    2014-12-01

    Gold nanoparticles (AuNPs) are good nonviral carriers because of their ease of synthesis and conjugation in biochemistry, and self-assembled monolayers (SAMs) provide a tunable system to change their interfacial properties. Using homogeneously mixed carboxylic acid and amine functional groups, a series of surface potentials and isoelectric points (IEPs) could be obtained and allow systematic study of the effect of surface potential. In this work, the result of the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay revealed that binary-SAM modified AuNPs have high biocompatibility with HEK293T cells. The amount of AuNPs ingested by the cells was found to increase with increasing surface potential and the difference was also confirmed with a scanning transmission electron microscope. The ability of binary-SAM modified AuNPs as carriers was examined, and the plasmid deoxyribose nucleic acid (DNA)-containing eGFP reporter gene was used as the model cargo. Fluorescence imaging revealed that the transfection efficiency generally increased with increasing surface potential. More importantly, when the IEP of the AuNPs was higher than that of the environment of the endosome but lower than that of the cytoplasm, the plasmid DNA can be protected better and released more easily during the endocytosis process hence higher efficiency is obtained with 60% NH2 and 40% COOH in the binary-SAM.

  6. Synthesis, characterization and potential application of MnZn ferrite and MnZn ferrite @ Au nanoparticles.

    Science.gov (United States)

    Wang, Xin; Wang, Lingyan; Lim, I-Im S; Bao, Kun; Mott, Derrick; Park, Hye-Young; Luo, Jin; Hao, Shunli; Zhong, Chuan-Jian

    2009-05-01

    The ability to tune the magnetic properties of magnetic nanoparticles by manipulating the composition or surface properties of the nanoparticles is important for exploiting the application of the nanomaterials. This report describes preliminary findings of an investigation of the viability of synthesizing MnZn ferrite and core @ shell MnZn ferrite @ Au nanoparticles as potentially magnetization-tunable nanomaterials. The synthesis of the core-shell magnetic nanoparticles involved a simple combination of seed formation of the MnZn ferrite magnetic nanoparticles and surface coating of the seeds with gold shells. Water-soluble MnZn ferrite nanoparticles of 20-40 nm diameters and MnZn ferrite @ Au nanoparticles of 30-60 nm have been obtained. The MnZn ferrite @ Au nanoparticles have been demonstrated to be viable in magnetic separation of nanoparticles via interparticle antibody-specific binding reactivity between antibodies on the gold shells of the core-shell magnetic particles and proteins on gold nanoparticles. These findings have significant implications to the design of the core @ shell magnetic nanomaterials with core composition tuned magnetization for bioassay application.

  7. Synthesis of Ag-Au bimetallic film at liquid-liquid interface and its application in vapor sensing

    Energy Technology Data Exchange (ETDEWEB)

    Pasricha, Renu, E-mail: pasrichar@mail.nplindia.ernet.i [Material Characterization Division, National Physical Laboratory, New Delhi-110012 (India); Gupta, Shweta [Material Characterization Division, National Physical Laboratory, New Delhi-110012 (India); Sastry, M. [Tata Chemical Innovation Center, Anmol Pride, Baner Road, Pune-45 (India); Singh, Nahar; Gupta, Prabhat [Material Characterization Division, National Physical Laboratory, New Delhi-110012 (India)

    2010-11-30

    We demonstrate a novel process for preparing densely packed film of silver nanoparticles at the liquid-liquid interface followed by a transmetallation reaction with gold ion to yield a film of bimetallic nanoparticles. Films of assembled silver as well as Ag-Au bimetallic were characterized by UV-vis-spectroscopy, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) analysis. I-V measurement shows linear behavior for both the films with ca. five orders of magnitude drop in resistance for the Ag-Au bimetallic film. Temperature dependent I-V measurement revealed a semiconductor to metal transition after transmetallation reaction. The films where checked for their potential application in chemical vapor sensing to ammonia vapors.

  8. Production of radio-gold {sup 199}Au for diagnostic and therapeutic applications

    Energy Technology Data Exchange (ETDEWEB)

    Khandaker, Mayeen Uddin, E-mail: mu-khandaker@um.edu.my; Kassim, Hasan Abu, E-mail: hasanak@um.edu.my [Department of Physics, University of Malaya, 50603 Kuala Lumpur (Malaysia); Haba, Hiromitsu, E-mail: haba@riken.jp [Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198 (Japan)

    2016-01-22

    Production cross-sections of the {sup nat}Pt(d,x){sup 199}Au reactions have been measured from a 24-MeV deuteron energy down to the threshold by using a stacked-foil activation technique combined with HPGe γ-ray spectrometry. Only a partial agreement is obtained with the existing literature data. Theoretical data extracted from the TENDL-2013 library shows large discrepancy with the measured ones. Physical thick target yield for the {sup 199}Au radionuclide was deduced using the measured cross-sections, and found a general agreement with the directly measured yield available in the literature. This study reveals that a low deuteron energy (<15 MeV) cyclotron and an enriched {sup 198}Pt (100%) target could be used to obtain {sup 199}Au in no carrier added form.

  9. Characterization of self-assembled electrodes based on Au-Pt nanoparticles for PEMFC application

    Energy Technology Data Exchange (ETDEWEB)

    Valenzuela, E. [Politecnica Univ. de Chiapas, Tuxtla Gutierrez, Chiapas (Mexico). Energia y Sustentabilidad; Sebastian, P.J. [Politecnica Univ. de Chiapas, Chiapas (Mexico). Energia y Sustentabilidad; Centro de Investigacion en Energia, UNAM, Morelos (Mexico); Gamboa, S.A. [Centro de Investigacion en Energia, UNAM, Morelos (Mexico); Pal, U. [Inst. de Fisica, Universidad Autonoma de Puebla Univ., Puebla (Mexico). Inst. de Fisica; Gonzalez, I. [Autonoma Metropolitana Univ. (Mexico). Dept. de Quimica

    2008-07-01

    This paper reported on a study in which membrane electrode assemblies (MEAs) were fabricated by depositing Au, Pt and AuPt nanoparticles on Nafion 115 membrane for use in a proton exchange membrane fuel cell (PEMFC). A Rotating Disc Electrode (RDE) was used to measure the nanoparticle catalyst activity. After deposition of the nanoparticles on the membrane, the surface was studied by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS). The membrane proton conduction process was studied by Electrochemical Impedance Spectroscopy (EIS) with the 4 probe technique. The MEAs fabricated with Nafion/Metal membranes were evaluated in a PEMFC under standard conditions. Colloidal solutions were used to prepare self-assembled electrodes with nanoparticles deposited on Nafion membrane. The particles deposited on Nafion showed good stability and had homogeneous distribution along the membrane surface. The impedance results revealed an increase in the membrane proton resistance of the self-assembled electrodes compared to unmodified Nafion. The Au-Pt nanoparticles were obtained by chemical reduction. The nanoparticle size in the three systems was about 2 nm. The self-assembled electrodes performed well in standard conditions. The optimum colloidal concentration and immersion time must be determined in order to obtain good catalytic activity and high membrane conductance. The self-assembled Nafion/AuPt had the best open circuit potential (887 mV). The Au and Pt self-assemblies showed a similar performance in terms of maximum power and maximum current density. The performance of the Nafion/Au self-assembly was influenced more by ohmic losses, particularly in the membrane. The maximum power generation was obtained at 0.35 V. The mass transport losses increased after this value, thereby affecting the efficiency of the PEMFC. 2 figs.

  10. Frabrication of Au Nanoparticles in Various Shapes and Their Application in Surface-enhanced Raman Scattering

    Institute of Scientific and Technical Information of China (English)

    Chen-yang XUE; Hui-juan WANG; Yong-feng LIANG; Rong CHEN; Jun LIU

    2010-01-01

    Anisotropic metallic Nanoparticles (NPs) have unique optical properties, such as Surface Enhanced Raman Scattering (SERS)spectroscopy. In this paper, star-shaped and sphere gold NPs were prepared by seed-mediated growth and Frence methods respectively. The reaction process and the effect of reagent in seed-mediated growth of gold nanostar particles were systematically described. After fabricating NPs the authors test their Raman enhancement using Crystal Violet (CV) molecules apart. The experimental results indicated that star-shaped Au NPs had stronger Raman enhancement spectrum than that of sphere Au NPs.

  11. Enhancement of the transverse magneto-optical Kerr effect via resonant tunneling in Au/Ce:YIG/Au trilayers and its application

    Science.gov (United States)

    Li, Jie; Tang, Tingting; Zhang, Yanfen; Luo, Li

    2017-02-01

    We propose a new structure to enhance the transverse magneto-optical Kerr effect (TMOKE) via resonant photon tunneling. In trilayer structures with a magnetic dielectric layer sandwiched between non-magnetic metal layers, an enhanced TMOKE can be observed. The TMOKE in Au/Ce:YIG/Au trilayers with different widths of magnetic dielectric layers are calculated using a 4  ×  4 transfer-matrix method, in which the maximum absolute value reaches 0.7. Based on the enhanced TMOKE, we apply the structure proposed above in magnetic field sensing, and TMOKE values are calculated when the external magnetic field intensity is increasing. Compared with other magnetic field sensing methods, the Au/Ce:YIG/Au trilayer possesses a very simple structure and shows high sensitivity to magnetic field variation, which is promising as a highly integrated and sensitive magneto-optical device.

  12. Applications of sliding mode control

    CERN Document Server

    Ghommam, Jawhar; Zhu, Quanmin

    2017-01-01

    This book presents essential studies and applications in the context of sliding mode control, highlighting the latest findings from interdisciplinary theoretical studies, ranging from computational algorithm development to representative applications. Readers will learn how to easily tailor the techniques to accommodate their ad hoc applications. To make the content as accessible as possible, the book employs a clear route in each paper, moving from background to motivation, to quantitative development (equations), and lastly to case studies/illustrations/tutorials (simulations, experiences, curves, tables, etc.). Though primarily intended for graduate students, professors and researchers from related fields, the book will also benefit engineers and scientists from industry. .

  13. Critical Factors Controlling Pd and Pt Potential in Porphyry Cu–Au Deposits: Evidence from the Balkan Peninsula

    Directory of Open Access Journals (Sweden)

    Demetrios G. Eliopoulos

    2014-03-01

    Full Text Available Porphyry Cu–Au–Pd±Pt deposits are significant Au resources, but their Pd and Pt potential is still unknown. Elevated Pd, Pt (hundreds of ppb and Au contents are associated with typical stockwork magnetite-bornite-chalcopyrite assemblages, at the central parts of certain porphyry deposits. Unexpected high grade Cu–(Pd+Pt (up to 6 ppm mineralization with high Pd/Pt ratios at the Elatsite porphyry deposit, which is found in a spatial association with the Chelopech epithermal deposit (Bulgaria and the Skouries porphyry deposit, may have formed during late stages of an evolved hydrothermal system. Estimated Pd, Pt and Au potential for porphyry deposits is consistent with literature model calculations demonstrating the capacity of aqueous vapor and brine to scavenge sufficient quantities of Pt and Pd, and could contribute to the global platinum-group element (PGE production. Critical requirements controlling potential of porphyry deposits may be from the metals contained in magma (metasomatized asthenospheric mantle wedge as indicated by significant Cr, Co, Ni and Re contents. The Cr content may be an indicator for the mantle input.

  14. Simultaneous Au(III) Extraction and In Situ Formation of Polymeric Membrane-Supported Au Nanoparticles: A Sustainable Process with Application in Catalysis.

    Science.gov (United States)

    Mora-Tamez, Lucía; Esquivel-Peña, Vicente; Ocampo, Ana L; Rodríguez de San Miguel, Eduardo; Grande, Daniel; de Gyves, Josefina

    2017-01-07

    A polymeric membrane-supported catalyst with immobilized gold nanoparticles (AuNPs) was prepared through the extraction and in situ reduction of Au(III) salts in a one-step strategy. Polymeric inclusion membranes (PIMs) and polymeric nanoporous membranes (PNMs) were tested as different membrane-support systems. Transport experiments indicated that PIMs composed of cellulose triacetate, 2-nitrophenyloctyl ether, and an aliphatic tertiary amine (Adogen 364 or Alamine 336) were the most efficient supports for Au(III) extraction. The simultaneous extraction and reduction processes were proven to be the result of a synergic phenomenon in which all the membrane components were involved. Scanning electron microscopy characterization of cross-sectional samples suggested a distribution of AuNPs throughout the membrane. Transmission electron microscopy characterization of the AuNPs indicated average particle sizes of 36.7 and 2.9 nm for the PIMs and PNMs, respectively. AuNPs supported on PIMs allowed for >95.4 % reduction of a 0.05 mmol L(-1) 4-nitrophenol aqueous solution with 10 mmol L(-1) NaBH4 solution within 25 min.

  15. Biomedical applications of control engineering

    CERN Document Server

    Hacısalihzade, Selim S

    2013-01-01

    Biomedical Applications of Control Engineering is a lucidly written textbook for graduate control engin­eering and biomedical engineering students as well as for medical prac­ti­tioners who want to get acquainted with quantitative methods. It is based on decades of experience both in control engineering and clinical practice.   The book begins by reviewing basic concepts of system theory and the modeling process. It then goes on to discuss control engineering application areas like ·         Different models for the human operator, ·         Dosage and timing optimization in oral drug administration, ·         Measuring symptoms of and optimal dopaminergic therapy in Parkinson’s disease, ·         Measure­ment and control of blood glucose le­vels both naturally and by means of external controllers in diabetes, and ·         Control of depth of anaesthesia using inhalational anaesthetic agents like sevoflurane using both fuzzy and state feedback controllers....

  16. Mixed Phytochemicals Mediated Synthesis of Multifunctional Ag-Au-Pd Nanoparticles for Glucose Oxidation and Antimicrobial Applications.

    Science.gov (United States)

    Rao, K Jagajjanani; Paria, Santanu

    2015-07-01

    The growing awareness toward the environment is increasing commercial demand for nanoparticles by green route syntheses. In this study, alloy-like Ag-Au-Pd trimetallic nanoparticles have been prepared by two plants extracts Aegle marmelos leaf (LE) and Syzygium aromaticum bud extracts (CE). Compositionally different Ag-Au-Pd nanoparticles with an atomic ratio of 5.26:2.16:1.0 (by LE) and 11.36:13.14:1.0 (by LE + CE) of Ag:Au:Pd were easily synthesized within 10 min at ambient conditions by changing the composition of phytochemicals. The average diameters of the nanoparticles by LE and LE + CE are ∼8 and ∼11 nm. The catalytic activity of the trimetallic nanoparticles was studied, and they were found to be efficient catalysts for the glucose oxidation process. The prepared nanoparticles also exhibited efficient antibacterial activity against a model Gram-negative bacteria Escherichia coli. The catalytic and antimicrobial properties of these readymade trimetallic nanoparticles have high possibility to be utilized in diverse fields of applications such as health care to environmental.

  17. Controlling the stereochemistry and regularity of butanethiol self-assembled monolayers on au(111).

    Science.gov (United States)

    Yan, Jiawei; Ouyang, Runhai; Jensen, Palle S; Ascic, Erhad; Tanner, David; Mao, Bingwei; Zhang, Jingdong; Tang, Chunguang; Hush, Noel S; Ulstrup, Jens; Reimers, Jeffrey R

    2014-12-10

    The rich stereochemistry of the self-assembled monolayers (SAMs) of four butanethiols on Au(111) is described, the SAMs containing up to 12 individual C, S, or Au chiral centers per surface unit cell. This is facilitated by synthesis of enantiomerically pure 2-butanethiol (the smallest unsubstituted chiral alkanethiol), followed by in situ scanning tunneling microscopy (STM) imaging combined with density functional theory molecular dynamics STM image simulations. Even though butanethiol SAMs manifest strong headgroup interactions, steric interactions are shown to dominate SAM structure and chirality. Indeed, steric interactions are shown to dictate the nature of the headgroup itself, whether it takes on the adatom-bound motif RS(•)Au(0)S(•)R or involves direct binding of RS(•) to face-centered-cubic or hexagonal-close-packed sites. Binding as RS(•) produces large, organizationally chiral domains even when R is achiral, while adatom binding leads to rectangular plane groups that suppress long-range expression of chirality. Binding as RS(•) also inhibits the pitting intrinsically associated with adatom binding, desirably producing more regularly structured SAMs.

  18. Tailored Au nanorods: optimizing functionality, controlling the aspect ratio and increasing biocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Cai Xiaoqing; Wang, Cheng-Liang; Chen, Hsiang-Hsin; Chien, Chia-Chi; Lai Shengfeng; Chen Yiyun; Hua, Tzu-En; Kempson, Ivan M; Hwu, Y [Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan (China); Yang, C S [Center for Nanomedicine, National Health Research Institutes, Miaoli, Taiwan (China); Margaritondo, G, E-mail: phhwu@sinica.edu.tw [Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2010-08-20

    Monodisperse gold nanorods with high aspect ratio were synthesized by x-ray irradiation. Irradiation was first used to stimulate the creation of seeds. Afterward, nanorod growth was stimulated either by chemical reduction or again by x-ray irradiation. In the last case, the entire process took place without reducing agents. The shape of the final products could be controlled by modulating the intensity of the x-ray irradiation during the seed synthesis. In turn, the nanorod aspect ratio determines the absorption wavelength of the nanorods that can thus be optimized for different applications. Likewise, the aspect ratio influences the uptake of the nanorods by HeLa cells.

  19. Synthesis of alginate stabilized gold nanoparticles by gamma-irradiation with controllable size using different Au{sup 3+} concentration and seed particles enlargement

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen Tue Anh; Dang Van Phu; Nguyen Ngoc Duy [Research and Development Center for Radiation Technology, Vietnam Atomic Energy Institute, 202 A, Street 11, Linh xuan Ward, Thu duc District, Ho Chi Minh City (Viet Nam); Bui Duy Du [Institute of Applied Material Science, Vietnam National Institute for Science and Technology, Ha Noi (Viet Nam); Nguyen Quoc Hien, E-mail: hien7240238@yahoo.co [Research and Development Center for Radiation Technology, Vietnam Atomic Energy Institute, 202 A, Street 11, Linh xuan Ward, Thu duc District, Ho Chi Minh City (Viet Nam)

    2010-04-15

    Gold nanoparticles with pre-selected size in the range 5-40 nm were synthesized by gamma-irradiation of Au{sup 3+} solution containing natural polysaccharide alginate as a stabilizer. The gold nanoparticles with controllable size were prepared by two approaches: (i) varying the concentration of Au{sup 3+} from 0.25 to 1 mM and alginate from 0.25% to 1% (w/v) and (ii) enlargement of seed particles with double size from 20 to 40 nm at [Au{sup 3+}]/[Au{sup 0}]=6. The obtained gold nanoparticles were characterized by UV-vis spectroscopy and transmission electron microscopy. The results indicated that gamma-irradiation method is suitable for production of gold nanoparticles with controllable size and high purity.

  20. Corrosion Protection of Al/Au/ZnO Anode for Hybrid Cell Application

    OpenAIRE

    2015-01-01

    Effective protection of power sources from corrosion is critical in the development of abiotic fuel cells, biofuel cells, hybrid cells and biobateries for implantable bioelectronics. Corrosion of these bioelectronic devices result in device inability to generate bioelectricity. In this paper Al/Au/ZnO was considered as a possible anodic substrate for the development of a hybrid cell. The protective abilities of corrosive resistant aluminum hydroxide and zinc phosphite composite films formed o...

  1. Interaction of Hydrogen with Au Modified by Pd and Rh in View of Electrochemical Applications

    Directory of Open Access Journals (Sweden)

    Fernanda Juarez

    2016-07-01

    Full Text Available Hydrogen interaction with bimetallic Au(Pd and Au(Rh systems are studied with the density functional theory (DFT-based periodic approach. Several bimetallic configurations with varying concentrations of Pd and Rh atoms in the under layer of a gold surface(111 were considered. The reactivity of the doped Au(111 toward hydrogen adsorption and absorption was related to the property modifications induced by the presence of metal dopants. DFT-computed quantities, such as the energy stability, the inter-atomic and inter-slab binding energies between gold and dopants, and the charge density were used to infer the similarities and differences between both Pd and Rh dopants in these model alloys. The hydrogen penetration into the surface is favored in the bimetallic slab configurations. The underlayer dopants affect the reactivity of the surface gold toward hydrogen adsorption in the systems with a dopant underlayer, covered by absorbed hydrogen up to a monolayer. This indicates a possibility to tune the gold surface properties of bimetallic electrodes by modulating the degree of hydrogen coverage of the inner dopant layer(s.

  2. Characterization of self-assembled electrodes based on Au-Pt nanoparticles for PEMFC application

    Energy Technology Data Exchange (ETDEWEB)

    Valenzuela, E. [Univ. Politecnica de Chiapas (Mexico). Energia y Sustentabilidad; Sebastian, P.J.; Gamboa, S.A.; Joseph, S. [Univ. Nacional Autonoma de Mexico, Morelos (Mexico). Centrode Investigacion en Energia; Pal, U. [Univ. Autonoma de Puebla, Pue (Mexico). Inst. de Fisica; Gonzalez, I. [Univ. Autonoma Metropolitana, Mexico City (Mexico). Dept. de Quimica

    2010-07-01

    This paper described the synthesis and characterization of gold (Au), platinum (Pt) and Au-Pt nanoparticles impregnated on a Nafion membrane in a proton exchange membrane fuel cell (PEMFC). The aim of the study was to fabricate the membrane electrode assembly (MEA) by depositing the nanoparticles on the membrane using an immersion technique. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to study the deposition process. Electrochemical impedance spectroscopy (EIS) was used to study the membrane proton conduction process. An elemental mapping analysis was performed in order to study the location of the Au and Pt in the self-assemblies. Results of the study showed that the particles deposited on the Nafion had good stability and a homogenous distribution along the membrane surface. The particles showed a direct relation in size and location with the hydrophilic and hydrophobic distribution phases of the membrane. The main membrane resistance was located between the membrane and the electrolyte. The self-assembled electrodes demonstrated a good performance at standard conditions. 33 refs., 4 tabs., 11 figs.

  3. Adaptive control with aerospace applications

    Science.gov (United States)

    Gadient, Ross

    Robust and adaptive control techniques have a rich history of theoretical development with successful application. Despite the accomplishments made, attempts to combine the best elements of each approach into robust adaptive systems has proven challenging, particularly in the area of application to real world aerospace systems. In this research, we investigate design methods for general classes of systems that may be applied to representative aerospace dynamics. By combining robust baseline control design with augmentation designs, our work aims to leverage the advantages of each approach. This research contributes the development of robust model-based control design for two classes of dynamics: 2nd order cascaded systems, and a more general MIMO framework. We present a theoretically justified method for state limiting via augmentation of a robust baseline control design. Through the development of adaptive augmentation designs, we are able to retain system performance in the presence of uncertainties. We include an extension that combines robust baseline design with both state limiting and adaptive augmentations. In addition we develop an adaptive augmentation design approach for a class of dynamic input uncertainties. We present formal stability proofs and analyses for all proposed designs in the research. Throughout the work, we present real world aerospace applications using relevant flight dynamics and flight test results. We derive robust baseline control designs with application to both piloted and unpiloted aerospace system. Using our developed methods, we add a flight envelope protecting state limiting augmentation for piloted aircraft applications and demonstrate the efficacy of our approach via both simulation and flight test. We illustrate our adaptive augmentation designs via application to relevant fixed-wing aircraft dynamics. Both a piloted example combining the state limiting and adaptive augmentation approaches, and an unpiloted example with

  4. L’application d’outils marketing au sein des associations touristiques

    OpenAIRE

    Pontier, Monique

    2011-01-01

    Au sein d’un contexte devenu concurrentiel, les associations touristiques se trouvent aujourd’hui face à des problématiques de recherche d’efficacité et de rentabilité nécessaires à leur survie, mais pouvant remettre en cause leur légitimité dans un secteur non lucratif. Des outils marketing sont ainsi mis en place afin de présenter aux publics une offre de qualité. Parmi ces méthodes, le marketing interne conduit les membres de l’association à devenir eux-mêmes acteurs de la commercialisatio...

  5. Controls on magmatic PGE and Au mineralization in the Skaergaard Intrusion

    Science.gov (United States)

    Keays, Reid; Tegner, Christian

    2013-04-01

    The Skaergaard Intrusion of East Greenland is the host for significant magmatic PGE and Au mineralization (the Platinova Reefs). It was formed from a single batch of magma that crystallized in its entirety as a closed system. Unlike all other examples of significant magmatic PGE and Ni-Cu-PGE mineralization, the Skaergaard rocks exhibit no evidence of crustal contamination, the major factor responsible for driving magmas to sulphide saturation and ore genesis. Although the Skaergaard rocks and mineralized zones have extremely low S contents, the mineralization is believed to be the product of late stage sulphide saturation of the magma. Three factors drove the magma to sulphide saturation, viz: (1) prolonged build up of S in the residual melt of the fractionating magma; (2) crystallization of magnetite which slowed down the build up of FeO in the fractionating magma; and (3) cooling of the magma against the walls of the intrusion. High quality PGE, Au, Cu, S, Se data and other geochemical data for samples from a detailed stratigraphic section through the Skaergaard intrusion are used to model these elements throughout its crystallization history, estimate their concentrations in the Skaergaard parental magma, and to establish the timing of sulphide saturation and the causes of PGE-Au mineralization. The model indicates that the parental magma contained 4.0 ppb Au, 18.7 ppb Pd, 9.0 ppb Pt, 95 ppb Se and 240 ppm Cu. The high Pd/Pt ratio indicates that the magma had undergone a significant amount of fractionation prior to entry into the Skaergaard magma chamber, consistent with the silicate mineralogy. A sharp increase in PGE contents (but not Cu or incompatible lithophile trace elements) 300m below the Platinova Reefs coincides with the first appearance of cumulus magnetite and marks the stratigraphic position at which tiny amounts of cumulus PGE-rich sulphides segregated from the magma. Although the S contents of all rocks below the Platinova Reefs are below the

  6. Controlling spin–orbit interaction in a ferromagnetic Fe/Au double layer

    Energy Technology Data Exchange (ETDEWEB)

    Samarin, Sergey N.; Kostylev, Mikhail; Williams, James F. [School of Physics, The University of Western Australia, Perth, Western Australia 6009 (Australia); Artamonov, Oleg M.; Baraban, Alexander P. [Research Institute of Physics, St. Petersburg State University, St. Petersburg 199034 (Russian Federation); Guagliardo, Paul [Centre for Microscopy, Characterisation and Analysis, the University of Western Australia, Perth, Western Australia 6009 (Australia)

    2015-01-26

    Using spin-polarized single- and two-electron spectroscopy, we probe exchange and spin–orbit interaction in a double layer of Fe and Au on W(110) and measure the spin asymmetry of the Bloch spectral density function of the sample. In a 5 ML iron film, the spin-orbit contribution to the measured asymmetry of the (e,2e) spectra was not detectable, whereas a deposition of about 1 ML of gold introduced a substantial spin-orbit component in the measured asymmetry. At the same time, this double layer still exhibits ferromagnetic properties: (i) the spectral density function asymmetry demonstrate imbalance of spin-up and spin-down electron densities in the valence band and (ii) the Stoner excitation asymmetry has almost the same value as in a pure Fe film.

  7. Controlling spin-orbit interaction in a ferromagnetic Fe/Au double layer

    Science.gov (United States)

    Samarin, Sergey N.; Artamonov, Oleg M.; Baraban, Alexander P.; Kostylev, Mikhail; Guagliardo, Paul; Williams, James F.

    2015-01-01

    Using spin-polarized single- and two-electron spectroscopy, we probe exchange and spin-orbit interaction in a double layer of Fe and Au on W(110) and measure the spin asymmetry of the Bloch spectral density function of the sample. In a 5 ML iron film, the spin-orbit contribution to the measured asymmetry of the (e,2e) spectra was not detectable, whereas a deposition of about 1 ML of gold introduced a substantial spin-orbit component in the measured asymmetry. At the same time, this double layer still exhibits ferromagnetic properties: (i) the spectral density function asymmetry demonstrate imbalance of spin-up and spin-down electron densities in the valence band and (ii) the Stoner excitation asymmetry has almost the same value as in a pure Fe film.

  8. Enhanced fluorescence of graphene oxide by well-controlled Au@SiO2 core-shell nanoparticles.

    Science.gov (United States)

    Li, Cuiyan; Zhu, Yihua; Wang, Siwen; Zhang, Xiaoqing; Yang, Xiaoling; Li, Chunzhong

    2014-01-01

    Graphene and graphene derivatives, including graphene oxide (GO) and reduced GO (rGO), have attracted remarkable attention in different fields due to their unique electronic, thermal, and mechanical properties, whereas the fluorescence property is rarely been studied. This paper reports on metal-enhanced fluorescence Au@SiO2 composite nanoparticles adsorbed graphene oxide nanosheets, where the silica-shell is used to control the distance between gold-core and fluorophore GO, and a positively charged polyelectrolyte poly(allylamine hydrochloride) (PAH) is used to adsorb the negatively charged silica-shell and GO by layer-by-layer assembly (LbL) approach. The silica-shell around the 80 nm gold-core can be well-controlled by ending the reaction at different times. Various analytical techniques were applied to characterize the morphology and optical characters of the as-prepared particles. A more than three-fold increase of the fluorescence intensity of GO was obtained.

  9. Chemical vapor deposition of monolayer WS2 nano- sheets on Au foils toward direct application in hydrogen evolution

    Institute of Scientific and Technical Information of China (English)

    Yanshuo Zhang[1; Jianping Shi[1; Gaofeng Han[3; Minjie Li[2; Qingqing Ji[2; Donglin Ma[2; Yu Zhang[1,2; Cong Li[1,2; Xingyou Lang[3; Yanfeng Zhang[1,2; Zhongfan Liu[2

    2015-01-01

    Monolayer tungsten disulfide (WS2), a typical member of the semiconducting transition metal dichalcogenide family has drawn considerable interest because of its unique properties. Intriguingly the edge of WS2 exhibits an ideal hydrogen binding energy which makes WS2 a potential alternative to Pt-based electrocatalysts for the hydrogen evolution reaction (HER). Here, we demonstrate for the first time the successful synthesis of uniform monolayer WS2 nanosheets on centimeter- scale Au foils using a facile, low-pressure chemical vapor deposition method. The edge lengths of the universally observed triangular WS2 nanosheets are tunable from -100 to N1,000 nm. The WS2 nanosheets on Au foils featuring abundant edges were then discovered to be efficient catalysts for the HER, exhibiting a rather high exchange current density of -30.20 μA/cm2 and a small onset potential of Nl10 mV. The effects of coverage and domain size (which correlate closely with the active edge density of WS2) on the electrocatalytic activity were investigated. This work not only provides a novel route toward the batch-production of monolayer WS2 via the introduction of metal foil substrates but also opens up its direct application for facile HER.

  10. Novel electrochemical redox-active species: one-step synthesis of polyaniline derivative-Au/Pd and its application for multiplexed immunoassay.

    Science.gov (United States)

    Wang, Liyuan; Feng, Feng; Ma, Zhanfang

    2015-11-18

    Electrochemical redox-active species play crucial role in electrochemically multiplexed immunoassays. A one-pot method for synthesizing four kinds of new electrochemical redox-active species was reported using HAuCl4 and Na2PdCl4 as dual oxidating agents and aniline derivatives as monomers. The synthesized polyaniline derivative-Au/Pd composites, namely poly(N-methyl-o-benzenediamine)-Au/Pd, poly(N-phenyl-o-phenylenediamine)-Au/Pd, poly(N-phenyl-p-phenylenediamine)-Au/Pd and poly(3,3',5,5'-tetramethylbenzidine)-Au/Pd, exhibited electrochemical redox activity at -0.65 V, -0.3 V, 0.12 V, and 0.5 V, respectively. Meanwhile, these composites showed high H2O2 electrocatalytic activity because of the presence of Au/Pd. The as-prepared composites were used as electrochemical immunoprobes in simultaneous detection of four tumor biomarkers (carcinoembryonic antigen (CEA), carbohydrate antigen 19-9 (CA199), carbohydrate antigen 72-4 (CA724), and alpha fetoprotein (AFP)). This immunoassay shed light on potential applications in simultaneous gastric cancer (related biomarkers: CEA, CA199, CA724) and liver cancer diagnosis (related biomarkers: CEA, CA199, AFP). The present strategy to the synthesize redox species could be easily extended to other polymers such as polypyrrole derivatives and polythiophene derivatives. This would be of great significance in the electrochemical detection of more analytes.

  11. Crystallographic investigation of Au nanoparticles embedded in a SrTiO{sub 3} thin film for plasmonics applications by means of synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Pincini, Davide, E-mail: davide.pincini@mail.polimi.it [European Synchrotron Radiation Facility, CS 40220, 71, avenue des Martyrs, F-38043 Grenoble Cedex 9 (France); Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy); Mazzoli, Claudio [Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy); Bernhardt, Hendrik; Katzer, Christian; Schmidl, Frank [Institut für Festkörperphysik, Friedrich-Schiller-Universität Jena, Helmholtzweg 5, 07743 Jena (Germany); Uschmann, Ingo [Institut für Optik und Quantenelektronik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Detlefs, Carsten [European Synchrotron Radiation Facility, CS 40220, 71, avenue des Martyrs, F-38043 Grenoble Cedex 9 (France)

    2015-03-14

    Self-organized monocrystalline Au nanoparticles with potential applications in plasmonics are grown in a SrTiO{sub 3} matrix by a novel two-step deposition process. The crystalline preferred orientation of these Au nanoparticles is investigated by synchrotron hard x-ray diffraction. Nanoparticles preferentially align with the (111) direction along the substrate normal (001), whereas two in-plane orientations are found with [110]{sub SrTiO{sub 3}}∥[110]{sub Au} and [100]{sub SrTiO{sub 3}}∥[110]{sub Au}. Additionally, a smaller diffraction signal from nanoparticles with the (001) direction parallel to the substrate normal (001) is observed; once again, two in-plane orientations are found, with [100]{sub SrTiO{sub 3}}∥[100]{sub Au} and [100]{sub SrTiO{sub 3}}∥[110]{sub Au}. The populations of the two in-plane orientations are found to depend on the thickness of the gold film deposited in the first step of the growth.

  12. Les moyens d'auscultation et de surveillance : Applications au viaduc de Merlebach

    OpenAIRE

    Tessier, C.; Gaillet, L.; BRUHAT, D; Michel, R.; NOBLET, S; Barbier, V

    2005-01-01

    Les câbles sont souvent des éléments fondamentaux pour la tenue des structures, et la sécurité des usagers dépend étroitement de leur état. Cette sécurité est directement liée à la qualité des matériaux employés et de l'exécution des travaux, mais aussi, tout au long de la vie des ouvrages, à la capacité de surveiller et de détecter des dégradations. Le cas du viaduc de Merlebach (Moselle) donne un exemple des moyens mis en oeurvre pour assurer cette surveillance, notamment en matière de surv...

  13. Fabrication of monodisperse FePt rate at Au core-shell nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Wei, D.H. [Institute of Physics, Academia Sinica, Taipei 115 (China); Hung, D.S. [Department of Information and Telecommunications Engineering, Ming Chuan University, Taipei 111 (China); Ho, C.S.; Wang, J.W. [Department of Chemical Engineering, Tunghai University, Taichung 407 (China); Yao, Y.D. [Department of Materials Engineering, Tatung University, Taipei 104 (China)

    2007-12-15

    Hydrophobic FePt rate at Au core-shell nanoparticles were chemically synthesized and with controllable surface-function properties. The enhanced optical property is due to the contribution of Au shell. The surface modification of FePt rate at Au nanoiparticles by using 11-mercaptoundecanoic acid (MUA) was hydrophilic through ligand exchange and with good biocompatibility for future multi-functional applications. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  14. Phenomenological study and modelling of weld behaviour for the control of GTA process by computer aided welding; Etude phenomenologique et modelisation du comportement du bain de fusion en soudage TIG en vue d'une application au controle du procede

    Energy Technology Data Exchange (ETDEWEB)

    Tissot, F.X

    1998-07-01

    The CEA-CEREM/LMS has been working on automation of arc welding processes for years. Particularly, a computer aided welding (CAW) system called 'SYLVARC' was developed to compensate the effects of any eventual disturbance, by means of a real-time control of the welding parameters. Images analysis of the topside weld pool permits to maintain its width at a nominal value. For each welding case, the control parameters have to be determined by considering the transient changes in the weld pool shape following a shift of the welding operating conditions around the nominal working setpoint. However, each corresponding empirical law do not allow any prediction nor any interpretation of the variations which are displayed. Thus, a theoretical model has been developed in this study, by using an analytical solution of heat conduction equations in the case of a Gaussian heat source, moving at constant speed at the surface of a thick plate. In parallel, a numerical approach using the finite elements code MARCUS has been carried out to validate the assumption that the eventual effects which could come from the chosen hypothesis (convection flows in the melt, latent heat transfers and temperature-dependence of the thermo-physical properties of the material are neglected) are constant for small variations around the working setpoint. This has shown that the weld behaviour around the working setpoint is easily predicted by the analytical model if restricted to conduction heat transfers. The using conditions of the model have been optimised as a result of a thorough parametric study. Experimental validations of the approach have been carried out focusing on the welding of stainless steel plates of low thickness. Particularly, in the case of a sharp step in the plate thickness, there is a good agreement of the simulation with the transient behaviour of the weld pool. (author)

  15. Synthesis and Optical Properties of Au-Ag Alloy Nanoclusters with Controlled Composition

    Directory of Open Access Journals (Sweden)

    J. F. Sánchez-Ramírez

    2008-01-01

    Full Text Available Colloidal solid-solution-like Au-Ag alloy nanoclusters of different compositions were synthesized through citrate reduction of mixed metal ions of low concentrations, without using any other protective or capping agents. Optical absorption of the alloy nanoclusters was studied both theoretically and experimentally. The position of the surface plasmon resonance (SPR absorption band of the nanoclusters could be tuned from 419 nm to 521 nm through the variation of their composition. Considering effective dielectric constant of the alloy, optical absorption spectra for the nanoclusters were calculated using Mie theory, and compared with the experimentally obtained spectra. Theoretically obtained optical spectra well resembled the experimental spectra when the true size distribution of the nanoparticles was considered. High-resolution transmission electron microscopy (HREM, high-angle annular dark field (HAADF imaging, and energy dispersive spectroscopy (EDS revealed the true alloy nature of the nanoparticles with nominal composition being preserved. The synthesis technique can be extended to other bimetallic alloy nanoclusters containing Ag.

  16. Reduction of Fermi level pinning at Au-MoS2 interfaces by atomic passivation on Au surface

    Science.gov (United States)

    Min, Kyung-Ah; Park, Jinwoo; Wallace, Robert M.; Cho, Kyeongjae; Hong, Suklyun

    2017-03-01

    Monolayer molybdenum disulfide (MoS2), which is a semiconducting material with direct band gap of ˜1.8 eV, has drawn much attention for application in field effect transistors (FETs). In this connection, it is very important to understand the Fermi level pinning (FLP) which occurs at metal-semiconductor interfaces. It is known that MoS2 has an n-type contact with Au, which is a high work function metal, representing the strong FLP at Au-MoS2 interfaces. However, such FLP can obstruct the attainment of high performance of field effect devices. In this study, we investigate the reduction of FLP at Au-MoS2 interfaces by atomic passivation on Au(111) using first-principles calculations. To reduce the FLP at Au-MoS2 interfaces, we consider sulfur, oxygen, nitrogen, fluorine, and hydrogen atoms that can passivate the surface of Au(111). Calculations show that passivating atoms prevent the direct contact between Au(111) and MoS2, and thus FLP at Au-MoS2 interfaces is reduced by weak interaction between atom-passivated Au(111) and MoS2. Especially, FLP is greatly reduced at sulfur-passivated Au-MoS2 interfaces with the smallest binding energy. Furthermore, fluorine-passivated Au(111) can form ohmic contact with MoS2, representing almost zero Schottky barrier height (SBH). We suggest that SBH can be controlled depending on the passivating atoms on Au(111).

  17. Design of highly sensitive and selective Au@NiO yolk-shell nanoreactors for gas sensor applications.

    Science.gov (United States)

    Rai, Prabhakar; Yoon, Ji-Wook; Jeong, Hyun-Mook; Hwang, Su-Jin; Kwak, Chang-Hoon; Lee, Jong-Heun

    2014-07-21

    Au@NiO yolk-shell nanoparticles (NPs) were synthesized by simple solution route and applied for efficient gas sensor towards H₂S gas. Carbon encapsulated Au (Au@C core-shell) NPs were synthesized by glucose-assisted hydrothermal method, whereas Au@NiO yolk-shell NPs were synthesized by precipitation method using Au@C core-shell NPs as a template. Sub-micrometer Au@NiO yolk-shell NPs were formed having 50-70 nm Au NPs at the periphery of NiO shell (10-20 nm), which was composed of 6-12 nm primary NiO particles. Au@NiO yolk-shell NPs showed higher response for H2S compared to other interfering gases (ethanol, p-xylene, NH₃, CO and H₂). The maximum response was 108.92 for 5 ppm of H₂S gas at 300 °C, which was approximately 19 times higher than that for the interfering gases. The response of Au@NiO yolk-shell NPs to H₂S was approximately 4 times higher than that of bare NiO hollow nanospheres. Improved performance of Au@NiO yolk-shell NPs was attributed to hollow spaces that allowed the accessibility of Au NPs to gas molecules. It was suggested that adsorption of H₂S on Au NPs resulted in the formation of sulfide layer, which possibly lowered its work function, and therefore tuned the electron transfer from Au to NiO rather NiO to Au, which leaded to increase in resistance and therefore response.

  18. Synthesis of nanocrystals with variable high-index Pd facets through the controlled heteroepitaxial growth of trisoctahedral Au templates.

    Science.gov (United States)

    Yu, Yue; Zhang, Qingbo; Liu, Bo; Lee, Jim Yang

    2010-12-29

    The shape-controlled synthesis of noble metal nanocrystals (NCs) bounded by high-index facets is a current research interest because the products have the potential of significantly improving the catalytic performance of NCs in industrially important reactions. This study reports a versatile method for synthesizing polyhedral NCs enclosed by a variety of high-index Pd facets. The method is based on the heteroepitaxial growth of Pd layers on concave trisoctahedral (TOH) gold NC seeds under careful control of the growth kinetics. Polyhedral Au@Pd NCs with three different classes of high-index facets, including concave TOH NCs with {hhl} facets, concave hexoctahedral (HOH) NCs with {hkl} facets, and tetrahexahedral (THH) NCs with {hk0} facets, can be formed in high yield. The Miller indices of NCs are also modifiable, and we have used the THH NCs as a demonstrative example. The catalytic activities of these NCs were evaluated by the structure-sensitive reaction of formic acid electro-oxidation. The results showed that the high-index facets are generally more active than the low-index facets. In summary, a seeded growth process based on concave high-index faceted monometallic TOH NC templates and careful control of the growth kinetics is a simple and effective strategy for the synthesis of noble metal NCs with high-index facets. It also offers tailorability of the surface structure in shape-controlled synthesis.

  19. Applications de la tranformee en ondelettes au traitement de l'information optique

    Science.gov (United States)

    Deschenes, Sylvain

    La these presente l'apport d'un outil mathematique recemment decouvert, la transformee en ondelettes, au traitement de l'information optique. Les ondelettes continues sont d'abords introduites et leur realisation optique est presentee. Ensuite, une ondelette repondant aux equations de Maxwell est developpee. Cette derniere permet de tisser des liens entre la transformee en ondelettes et le principe de Huygens utilise pour etudier la diffraction scalaire. La possibilite d'utiliser cette ondelette pour generer des faisceaux non diffractants est egalement discutee. Dans un deuxieme temps, les ondelettes discretes sont utilisees dans le but d'extraire des informations pertinentes dans une banque d'images infrarouges. Ces images representent les vues de vehicules prises a tous les cinq degres. La transformee en ondelettes genere une analyse multiresolution permettant d'extraire des contours moins bruites. Cette information est alors traitee par de nouveaux algorithmes de reconnaissance de forme dans un espace qui caracterise de facon invariante les objets 3-D.

  20. Molecular beam epitaxy of GaAs nanowires and their sustainability for optoelectronic applications. Comparing Au- and self-assisted growth methods

    Energy Technology Data Exchange (ETDEWEB)

    Breuer, Steffen

    2011-09-28

    In this work the synthesis of GaAs nanowires by molecular beam epitaxy (MBE) using the vapour-liquid-solid (VLS) mechanism is investigated. A comparison between Au- and self-assisted VLS growth is at the centre of this thesis. While the Au-assisted method is established as a versatile tool for nanowire growth, the recently developed self-assisted variation results from the exchange of Au by Ga droplets and thus eliminates any possibility of Au incorporation. By both methods, we achieve nanowires with epitaxial alignment to the Si(111) substrates. Caused by differences during nanowire nucleation, a parasitic planar layer grows between the nanowires by the Au-assisted method, but can be avoided by the self-assisted method. Au-assisted nanowires grow predominantly in the metastable wurtzite crystal structure, while their self-assisted counterparts have the zincblende structure. All GaAs nanowires are fully relaxed and the strain arising from the lattice mismatch between GaAs and Si of 4.1 % is accommodated by misfit dislocations at the interface. Self-assisted GaAs nanowires are generally found to have vertical and non-polar side facets, while tilted and polar nanofacets were described for Au-assisted GaAs nanowires. We employ VLS nucleation theory to understand the effect of the droplet material on the lateral facets. Optoelectronic applications require long minority carrier lifetimes at room temperature. We fabricate GaAs/(Al,Ga)As core-shell nanowires and analyse them by transient photoluminescence (PL) spectroscopy. The results are 2.5 ns for the self-assisted nanowires as well as 9 ps for the Au-assisted nanowires. By temperature-dependent PL measurements we find a characteristic activation energy of 77 meV that is present only in the Au-assisted nanowires. We conclude that most likely Au is incorporated from the droplets into the GaAs nanowires and acts as a deep, non-radiative recombination centre.

  1. Optical and electrochemical evaluation of colloidal Au nanoparticle-ITO hybrid optically transparent electrodes and their application to attenuated total reflectance spectroelectrochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Richardson, John N.; Aguilar, Zoraida; Kaval, Necati; Andria, Sara E.; Shtoyko, Tanya; Seliskar, Carl J.; Heineman, William R

    2003-12-15

    Colloidal Au nanoparticle monolayers covalently deposited on conductive layers of indium tin oxide (ITO) were fabricated and evaluated as optically transparent electrodes (OTEs) for spectroelectrochemical applications. Specifically, the electrodes were characterized using UV-Vis spectroscopy and cyclic voltammetry; comparisons are made with other types of hybrid ITO optically transparent electrodes. The optical modulation of surface-bound colloidal Au in response to potential cycling over a wide potential window (0.6 to -1.0 V) was acquired in an attenuated total reflectance (ATR) spectroelectrochemical cell. Finally, uptake of a model analyte, tris-(2,2'-bipyridyl)ruthenium(II) chloride, into a Nafion charge selective film spin coated onto the colloidal Au-ITO hybrid electrode was examined using ATR absorbance spectroelectrochemistry. Dependence of uptake on film thickness is addressed, and non-optimized detection limits of 10 nM are reported.

  2. Developing an aqueous approach for synthesizing Au and M@Au (M = Pd, CuPt) hybrid nanostars with plasmonic properties

    CERN Document Server

    Du, Jingshan; Xiong, Yalin; Lin, Zhuoqing; Zhang, Hui; Yang, Deren

    2014-01-01

    Anisotropic Au nanoparticles show unique localized surface plasmon resonance (LSPR) properties, which make it attractive in optical, sensing, and biomedical applications. In this contribution, we report a general and facile strategy towards aqueous synthesis of Au and M@Au (M = Pd, CuPt) hybrid nanostars by reducing HAuCl4 with ethanolamine in the presence of cetyltrimethylammonium bromide (CTAB). According to electron microscopic observation and spectral monitoring, we found that the layered epitaxial growth mode (i.e., Frank-van der Merwe mechanism) contributes to the enlargement of the core, while, the random attachment of Au nanoclusters onto the cores accounts for the formation of the branches. Both of them are indispensable for the formation of the nanostars. The LSPR properties of the Au nanoparticles have been well investigated with morphology control via precursor amount and growth temperature. The Au nanostars showed improved surface-enhanced Raman spectroscopy (SERS) performance for rhodamine 6G du...

  3. Control of Melt Structures on Cu-Au Mineralization in Basic-Ultrabasic Complexes of Northern China

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Based on systematic analyses of 72 samples of different basic-ultrabasic rocks, the present paper discusses the relationship between melt strcture and Cu and Au mineralization. It is found that if the NBO/T, NBO, M2+,FeO and MgO values are relatively high and the T, M3+, Fe2O3 and CaO values are low the basic-ultrahasic melt will be favourable to Cu (Ni) mineralization, but if the former are low and the latter are high it is favourable to Au metallization. Cu ions occupy dominantly octahedra in basic-ultrabasic melt and the higher the NBO/T, NBO and M2+ values, the more the octahedra in the melt. Au element mainly takes the form of Au+ions in basic-ultrabasic melt and the Au+ ions constitute tetrahedral sites together with Fe3+ ions. Therefore, low M2+ and high Fe3+, i.e. high oxygen fugacity, can promote the enrichment of Au+ ions and Au mineralization. Components M+ (other than Au+), Al2O3 and SiO2 in basic-ultrabasic melt have no effect on metallogenetic species. As mentioned above, in relevant diagrams distribution areas of the characteristic values of ore-free melt and those of ore-forming melt are overlapped in different degrees, which possibly indicates that not all the magmas have mineralizing ability. It can be well distinguished whather basic-ultrabasic rocks are favourable to Cu or Au mineralization or they are just ore-free rocks by analysing integrated diagrams of the characteristic values of the magmatic melt structure.

  4. Core-shell Au/Ag nanoparticles embedded in silicate sol-gel network for sensor application towards hydrogen peroxide

    Indian Academy of Sciences (India)

    Shanmugam Manivannan; Ramasamy Ramaraj

    2009-09-01

    The electrocatalytic activity of core-shell Au100-Ag ( = 15, 27, 46, and 60) bimetallic nanoparticles embedded in methyl functionalized silicate MTMOS network towards the reduction of hydrogen peroxide was investigated by using cyclic voltammetry and chronoamperometric techniques. Core-shell Au/Ag bimetallic nanoparticles were characterized by absorption spectra and HRTEM. The MTMOS silicate sol-gel embedded Au73Ag27 core-shell nanoparticles modified electrode showed better synergistic electrocatalytic effect towards the reduction of hydrogen peroxide when compared to monometal MTMOS-Aunps and MTMOS-Agnps modified electrodes. These modified electrodes were studied without immobilizing any enzyme in the MTMOS sol-gel matrix. The present study highlights the influence of molar composition of Ag nanoparticles in the Au/Ag bimetallic composition towards the electrocatalytic reduction and sensing of hydrogen peroxide in comparison to monometal Au and Ag nanoparticles.

  5. Application of Model Predictive Control to BESS for Microgrid Control

    Directory of Open Access Journals (Sweden)

    Thai-Thanh Nguyen

    2015-08-01

    Full Text Available Battery energy storage systems (BESSs have been widely used for microgrid control. Generally, BESS control systems are based on proportional-integral (PI control techniques with the outer and inner control loops based on PI regulators. Recently, model predictive control (MPC has attracted attention for application to future energy processing and control systems because it can easily deal with multivariable cases, system constraints, and nonlinearities. This study considers the application of MPC-based BESSs to microgrid control. Two types of MPC are presented in this study: MPC based on predictive power control (PPC and MPC based on PI control in the outer and predictive current control (PCC in the inner control loops. In particular, the effective application of MPC for microgrids with multiple BESSs should be considered because of the differences in their control performance. In this study, microgrids with two BESSs based on two MPC techniques are considered as an example. The control performance of the MPC used for the control microgrid is compared to that of the PI control. The proposed control strategy is investigated through simulations using MATLAB/Simulink software. The simulation results show that the response time, power and voltage ripples, and frequency spectrum could be improved significantly by using MPC.

  6. Détection et suivi visuels robustes d'objets complexes : applications au rendezvous spatial autonome

    OpenAIRE

    Petit, Antoine

    2013-01-01

    In this thesis, we address the issue of fully localizing a known object through computer vision, using a monocular camera, what is a central problem in robotics. A particular attention is here paid on space robotics applications, with the aims of providing a unified visual localization system for autonomous navigation purposes for space rendezvous and proximity operations. Two main challenges of the problem are tackled: initially detecting the targeted object and then tracking it frame-by-fra...

  7. Une formulation du contact à frottement sec; application au calcul numérique

    OpenAIRE

    Moreau, Jean-Jacques

    1986-01-01

    International audience; A formulation of contact with dry friction; computational application. The usual law of dry friction is turned into a statement which does not involve splitting the contact force into its normal and tangential components. A numerical algorithm is derived for the dynamics of systems with unilateral contact; possible shocks are inelastic.; La loi usuelle du frottement sec est mise sous une forme évitant d'exhiber la composante normale et la composante tangentielle de la ...

  8. A simple way to prepare Au@polypyrrole/Fe3O4 hollow capsules with high stability and their application in catalytic reduction of methylene blue dye

    Science.gov (United States)

    Yao, Tongjie; Cui, Tieyu; Wang, Hao; Xu, Linxu; Cui, Fang; Wu, Jie

    2014-06-01

    Metal nanoparticles are promising catalysts for dye degradation in treating wastewater despite the challenges of recycling and stability. In this study, we have introduced a simple way to prepare Au@polypyrrole (PPy)/Fe3O4 catalysts with Au nanoparticles embedded in a PPy/Fe3O4 capsule shell. The PPy/Fe3O4 capsule shell used as a support was constructed in one-step, which not only dramatically simplified the preparation process, but also easily controlled the magnetic properties of the catalysts through adjusting the dosage of FeCl2.4H2O. The component Au nanoparticles could catalyze the reduction of methylene blue dye with NaBH4 as a reducing agent and the reaction rate constant was calculated through the pseudo-first-order reaction equation. The Fe3O4 nanoparticles permitted quick recycling of the catalysts with a magnet due to their room-temperature superparamagnetic properties; therefore, the catalysts exhibited good reusability. In addition to catalytic activity and reusability, stability is also an important property for catalysts. Because both Au and Fe3O4 nanoparticles were wrapped in the PPy shell, compared with precursor polystyrene/Au composites and bare Fe3O4 nanoparticles, the stability of Au@PPy/Fe3O4 hollow capsules was greatly enhanced. Since the current method is simple and flexible to create recyclable catalysts with high stability, it would promote the practicability of metal nanoparticle catalysts in industrial polluted water treatment.Metal nanoparticles are promising catalysts for dye degradation in treating wastewater despite the challenges of recycling and stability. In this study, we have introduced a simple way to prepare Au@polypyrrole (PPy)/Fe3O4 catalysts with Au nanoparticles embedded in a PPy/Fe3O4 capsule shell. The PPy/Fe3O4 capsule shell used as a support was constructed in one-step, which not only dramatically simplified the preparation process, but also easily controlled the magnetic properties of the catalysts through adjusting

  9. Applications of intelligent telerobotic control

    Energy Technology Data Exchange (ETDEWEB)

    Herget, C.J.; Grasz, E.L.; Merrill, R.D.

    1991-10-01

    The telerobotics laboratory at Lawrence Livermore National Laboratory is a facility for developing and testing new concepts in robotics controls. Research and development is being conducted in computer vision; adaptive control; software architectures for real-time, intelligent control; artificial neural networks; fuzzy logic controllers; telepresence; and path planning and collision avoidance. The equipment in the telerobotics laboratory includes a six degree of freedom articulating robot arm with controller, gripper, and force and torque sensor; a 3D CAD workstation with software to model the work cell environment and simulate the robot dynamics; a six degree of freedom forceball for operator input to the telerobotics controller and the robot simulation; and a computer with a real-time operating system. Soon to be added are a 3D viewing system and a force reflecting hand controller. This paper describes one of the research and development efforts currently in progress on this program. 3 refs., 3 figs.

  10. A simple way to prepare Au@polypyrrole/Fe3O4 hollow capsules with high stability and their application in catalytic reduction of methylene blue dye.

    Science.gov (United States)

    Yao, Tongjie; Cui, Tieyu; Wang, Hao; Xu, Linxu; Cui, Fang; Wu, Jie

    2014-07-07

    Metal nanoparticles are promising catalysts for dye degradation in treating wastewater despite the challenges of recycling and stability. In this study, we have introduced a simple way to prepare Au@polypyrrole (PPy)/Fe3O4 catalysts with Au nanoparticles embedded in a PPy/Fe3O4 capsule shell. The PPy/Fe3O4 capsule shell used as a support was constructed in one-step, which not only dramatically simplified the preparation process, but also easily controlled the magnetic properties of the catalysts through adjusting the dosage of FeCl2·4H2O. The component Au nanoparticles could catalyze the reduction of methylene blue dye with NaBH4 as a reducing agent and the reaction rate constant was calculated through the pseudo-first-order reaction equation. The Fe3O4 nanoparticles permitted quick recycling of the catalysts with a magnet due to their room-temperature superparamagnetic properties; therefore, the catalysts exhibited good reusability. In addition to catalytic activity and reusability, stability is also an important property for catalysts. Because both Au and Fe3O4 nanoparticles were wrapped in the PPy shell, compared with precursor polystyrene/Au composites and bare Fe3O4 nanoparticles, the stability of Au@PPy/Fe3O4 hollow capsules was greatly enhanced. Since the current method is simple and flexible to create recyclable catalysts with high stability, it would promote the practicability of metal nanoparticle catalysts in industrial polluted water treatment.

  11. Cfd Engine Applications At Fiat Research Centre Applications de la modélisation 3D au FIAT Research Centre

    Directory of Open Access Journals (Sweden)

    Lisbona M. G.

    2006-12-01

    Full Text Available The CFD (computer fluid dynamic simulation of the complete engine cycle of the 2400 cm3 JTD 10 V engine for the Alfa Romeo 156 is presented. The intake stroke analysis has followed a procedure usually applied at CRF for gasoline engines. Spray and combustion analysis at the selected operating condition of 3500 tr/min and 13 bar BMEP (brake mean effective pressure has given results in fair agreement with the experimental data, but revealed the need of more accurate models for the initial phase of combustion. Finally, the simulation of the exhaust phase has required great care in the set-up of the initial field and boundary conditions. Flow field characteristics are discussed at two crank angles, corresponding to peak values of the exhaust mass flow rate. Cet article présente la simulation 3D du cycle complet du moteur 2400 cm3 JTD 10 V de l'Alfa Romeo 156. L'analyse de la phase d'admission a suivi une procédure habituellement utilisée pour les moteurs à essence. L'analyse du spray et de la combustion au régime choisi de 3500 tr/min et 13 bar de PMI se compare raisonnablement aux essais, mais indique qu'une meilleure description de la phase initiale de la combustion est nécessaire. La simulation de la phase d'échappement a requis une grande attention quant à la spécification du champ initial et des conditions aux limites. On étudie ici les caractéristiques de l'écoulement à deux instants de cycles correspondant à des maxima de débits à l'échappement.

  12. Redox-Robust Pentamethylferrocene Polymers and Supramolecular Polymers, and Controlled Self-Assembly of Pentamethylferricenium Polymer-Embedded Ag, AgI, and Au Nanoparticles.

    Science.gov (United States)

    Gu, Haibin; Ciganda, Roberto; Castel, Patricia; Vax, Amélie; Gregurec, Danijela; Irigoyen, Joseba; Moya, Sergio; Salmon, Lionel; Zhao, Pengxiang; Ruiz, Jaime; Hernández, Ricardo; Astruc, Didier

    2015-12-01

    We report the first pentamethylferrocene (PMF) polymers and the redox chemistry of their robust polycationic pentamethylferricenium (PMFium) analogues. The PMF polymers were synthesized by ring-opening metathesis polymerization (ROMP) of a PMF-containing norbornene derivative by using the third-generation Grubbs ruthenium metathesis catalyst. Cyclic voltammetry studies allowed us to determine confidently the number of monomer units in the polymers through the Bard-Anson method. Stoichiometric oxidation by using ferricenium hexafluorophosphate quantitatively and instantaneously provided fully stable (even in aerobic solutions) blue d(5) Fe(III) metallopolymers. Alternatively, oxidation of the PMF-containing polymers was conducted by reactions with Ag(I) or Au(III) , to give PMFium polymer-embedded Ag and Au nanoparticles (NPs). In the presence of I2 , oxidation by using Ag(I) gave polymer-embedded Ag/AgI NPs and AgNPs at the surface of AgI NPs. Oxidation by using Au(III) also produced an Au(I) intermediate that was trapped and characterized. Engineered single-electron transfer reactions of these redox-robust nanomaterial precursors appear to be a new way to control their formation, size, and environment in a supramolecular way.

  13. A rapid green strategy for the synthesis of Au "meatball"-like nanoparticles using green tea for SERS applications

    Science.gov (United States)

    Wu, Shichao; Zhou, Xi; Yang, Xiangrui; Hou, Zhenqing; Shi, Yanfeng; Zhong, Lubin; Jiang, Qian; Zhang, Qiqing

    2014-09-01

    We report a simple and rapid biological approach to synthesize water-soluble and highly roughened "meatball"-like Au nanoparticles using green tea extract under microwave irradiation. The synthesized Au meatball-like nanoparticles possess excellent monodispersity and uniform size (250 nm in diameter). Raman measurements show that these tea-generated meatball-like gold nanostructures with high active surface areas exhibit a high enhancement of surface-enhanced Raman scattering. In addition, the Au meatball-like nanoparticles demonstrate good biocompatibility and remarkable in vitro stability at the biological temperature. Meanwhile, the factors that influence the Au meatball-like nanoparticles morphology are investigated, and the mechanisms behind the nonspherical shape evolution are discussed.

  14. Interface effects on tunneling magnetoresistance in organic spintronics with flexible amine-Au links.

    Science.gov (United States)

    Gorjizadeh, Narjes; Quek, Su Ying

    2013-10-18

    Organic spintronics is a promising emerging field, but the sign of the tunneling magnetoresistance (TMR) is highly sensitive to interface effects, a crucial hindrance to applications. A key breakthrough in molecular electronics was the discovery of amine-Au link groups that give a reproducible conductance. Using first-principles calculations, we predict that amine-Au links give improved reproducibility in organic spintronics junctions with Au-covered Fe leads. The Au layers allow only states with sp character to tunnel into the molecule, and the flexibility of amine-Au links results in a narrow range of TMR for a fixed number of Au layers. Even as the Au thickness changes, the TMR remains positive as long as the number of Au layers is the same on both sides of the junction. Since the number of Au layers on Fe surfaces or Fe nanoparticles can now be experimentally controlled, amine-Au links provide a route towards robust TMR in organic spintronics.

  15. Une chaîne de traitement de l'information géographique au service de l'application de la loi Littoral

    Directory of Open Access Journals (Sweden)

    Patrick GUILLOPÉ

    1994-09-01

    Full Text Available L’application de la loi Littoral nécessitait une approche nouvelle de la part de l’État et la mise en œuvre d’outils nouveaux pour une gestion à long terme. L’apport de traitements automatiques de l’information géographique a été ainsi testé au CETE Normandie-Centre sur trois des grands principes posés par cette loi.

  16. An enhanced photocatalytic response of nanometric TiO2 wrapping of Au nanoparticles for eco-friendly water applications

    Science.gov (United States)

    Scuderi, Viviana; Impellizzeri, Giuliana; Romano, Lucia; Scuderi, Mario; Brundo, Maria V.; Bergum, Kristin; Zimbone, Massimo; Sanz, Ruy; Buccheri, Maria A.; Simone, Francesca; Nicotra, Giuseppe; Svensson, Bengt G.; Grimaldi, Maria G.; Privitera, Vittorio

    2014-09-01

    We propose a ground-breaking approach by an upside-down vision of the Au/TiO2 nano-system in order to obtain an enhanced photocatalytic response. The system was synthesized by wrapping Au nanoparticles (~8 nm mean diameter) with a thin layer of TiO2 (~4 nm thick). The novel idea of embedding Au nanoparticles with titanium dioxide takes advantage of the presence of metal nanoparticles, in terms of electron trapping, without losing any of the TiO2 exposed surface, so as to favor the photocatalytic performance of titanium dioxide. A complete structural characterization was made by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The remarkable photocatalytic performance together with the stability of the nano-system was demonstrated by degradation of the methylene blue dye in water. The non-toxicity of the nano-system was established by testing the effect of the material on the reproductive cycle of Mytilus galloprovincialis in an aquatic environment. The originally synthesized material was also compared to conventional TiO2 with Au nanoparticles on top. The latter system showed a dispersion of Au nanoparticles in the liquid environment, due to their instability in the aqueous solution that clearly represents an environmental contamination issue. Thus, the results show that nanometric TiO2 wrapping of Au nanoparticles has great potential in eco-friendly water/wastewater purification.

  17. The optimal control and its multiple applications

    OpenAIRE

    2009-01-01

    In this work we refer to motivations, applications, and relations of control theory with other areas of mathematics. We present a brief historical review of optimal control theory, from its roots in the calculus of variations and the classical theory of control to the present time, giving particular emphasis to the Pontryagin maximum principle.

  18. Au-controlled enhancement of photoluminescence of NiS nanostructures synthesized via a microwave-assisted hydrothermal technique

    Energy Technology Data Exchange (ETDEWEB)

    Linganiso, Ella Cebisa [DST/CSIR Nanotech Innovation Centre, National Centre for Nano-structured Materials, Council for Scientific and Industrial Research, PO Box 395, Pretoria 0001 (South Africa); Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa); Mwakikunga, Bonex Wakufwa, E-mail: bmwakikunga@csir.co.za [DST/CSIR Nanotech Innovation Centre, National Centre for Nano-structured Materials, Council for Scientific and Industrial Research, PO Box 395, Pretoria 0001 (South Africa); Department of Physics and Biochemical Sciences, The Polytechnic of the University of Malawi, Private Bag 303, Chichiri, Blantyre 0003 (Malawi); Mhlanga, Sabelo Dalton [Department of Applied Chemistry, University of Johannesburg, PO Box 17011, Doornfontein, 2028 Johannesburg (South Africa); Coville, Neil John [Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa); DST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa)

    2014-11-15

    Nickel sulphide (NiS) nanostructures decorated with gold (Au) nanoparticles (NPs) were synthesized via a microwave-assisted hydrothermal technique. Binary phase NiS (α and β) crystalline nanostructures, bare, and decorated with Au NPs were obtained and confirmed by X-ray diffraction (XRD) studies. TEM analysis revealed that the NiS nanostructures were of various shapes. A quantum confinement effect was confirmed by the blue shift PL emissions and high optical energy band gap observed for the as-synthesized sample. A threefold light emission enhancement due to Au NP coatings was obtained when Au metal NP decoration concentrations was varied from 1% to 10%. These enhancements were attributed to the surface plasmon resonance (SPR) excitation of the surface decorated metal NPs which results in an increased rate of spontaneous emission. The PL enhancement factor was observed to vary at different NiS emissions as well as with the size of the Au NPs. The effect of metal NP decoration on the PL emission of NiS is to the best of our knowledge, presented for the first time. - Highlights: • Binary phase NiS decorated with gold nanoparticles. • Quantum confinement effect confirmed by PL analysis. • PL enhancement depending more on particle size distribution. • Effect of gold on NiS PL is to the best of our knowledge reported for the first time.

  19. Advances and applications in nonlinear control systems

    CERN Document Server

    Volos, Christos

    2016-01-01

    The book reports on the latest advances and applications of nonlinear control systems. It consists of 30 contributed chapters by subject experts who are specialized in the various topics addressed in this book. The special chapters have been brought out in the broad areas of nonlinear control systems such as robotics, nonlinear circuits, power systems, memristors, underwater vehicles, chemical processes, observer design, output regulation, backstepping control, sliding mode control, time-delayed control, variables structure control, robust adaptive control, fuzzy logic control, chaos, hyperchaos, jerk systems, hyperjerk systems, chaos control, chaos synchronization, etc. Special importance was given to chapters offering practical solutions, modeling and novel control methods for the recent research problems in nonlinear control systems. This book will serve as a reference book for graduate students and researchers with a basic knowledge of electrical and control systems engineering. The resulting design proce...

  20. Fuel cells for stationary applications in Japan; Les piles a combustible pour les applications stationnaires au Japon

    Energy Technology Data Exchange (ETDEWEB)

    Hug, F.; Mermillod, N.; Millet, C.; Pinget, A.

    2000-05-01

    This document is a mission report on stationary applications of fuel cells in Japan. This mission was organized by the Science and Technology Service of the French embassy in Japan in December 1999. The organizations shown were: NEDO, Osaka Gas, Tokyo Gas, Sanyo, the Kawagoe facility, Mitsubishi Heavy Industries, CRIEPI and Toto. Since the year 2000, the public effort made on fuel cells development has shot up and reaches 7 billions of yen among which more than a half is devoted to polymer electrolyte fuel cells (PEFC). Applications of PEFCs are various, from stationary cogeneration to transportation systems. (J.S.)

  1. Physics related to control and safety of hybrid systems; Physique associee au controle et a la surete des systemes hybrides

    Energy Technology Data Exchange (ETDEWEB)

    Gueton, O

    2001-12-01

    Regarding nuclear waste management, ADS can be considered as large minor actinides burners. In a first part, a critical analysis of different reactor types shows that fast spectrum, helium coolant and nitride fuel, containing 100% minor actinides, agree perfectly with the high transmutation requirements of ADS. The control and safety demonstration of this system represents the main purpose of this study. Understanding spatial and dynamic behaviour of ADS flux is absolutely necessary. For this purpose, we have defined an indicator to quantify spatial decoupling. It shows, on the one hand, point kinetic deficiency to study local transients, and on the other hand, perturbations propagation differences between ADS and critical cores. Then, in a more concrete approach, accidental sequences (source transient, beam de-focalization, reactivity insertions, loss of flow, depressurization) are evaluated for this core, strongly loaded with minor actinides. It is shown that the automatic beam shutdown leads to preserve large safety margins for all studied transients. The accelerator emergency stop is induced by an unexpected evolution of the core control parameters. These parameters, except reactivity, can be directly measured in subcritical systems like in critical ones. Concerning reactivity, we suggest a new method for its absolute determination in ADS: at the time of reactor start-up, the reactivity must be calibrated by coupling two methods of relative reactivity measurements (pulsed source and Approached Source Multiplication) for successive subcritical levels. After that, the on-line follow-up of reactivity is obtained from this calibration like in a critical core. (authors)

  2. Application de la methode des sous-groupes au calcul Monte-Carlo multigroupe

    Science.gov (United States)

    Martin, Nicolas

    This thesis is dedicated to the development of a Monte Carlo neutron transport solver based on the subgroup (or multiband) method. In this formalism, cross sections for resonant isotopes are represented in the form of probability tables on the whole energy spectrum. This study is intended in order to test and validate this approach in lattice physics and criticality-safety applications. The probability table method seems promising since it introduces an alternative computational way between the legacy continuous-energy representation and the multigroup method. In the first case, the amount of data invoked in continuous-energy Monte Carlo calculations can be very important and tend to slow down the overall computational time. In addition, this model preserves the quality of the physical laws present in the ENDF format. Due to its cheap computational cost, the multigroup Monte Carlo way is usually at the basis of production codes in criticality-safety studies. However, the use of a multigroup representation of the cross sections implies a preliminary calculation to take into account self-shielding effects for resonant isotopes. This is generally performed by deterministic lattice codes relying on the collision probability method. Using cross-section probability tables on the whole energy range permits to directly take into account self-shielding effects and can be employed in both lattice physics and criticality-safety calculations. Several aspects have been thoroughly studied: (1) The consistent computation of probability tables with a energy grid comprising only 295 or 361 groups. The CALENDF moment approach conducted to probability tables suitable for a Monte Carlo code. (2) The combination of the probability table sampling for the energy variable with the delta-tracking rejection technique for the space variable, and its impact on the overall efficiency of the proposed Monte Carlo algorithm. (3) The derivation of a model for taking into account anisotropic

  3. Seebeck effect in {ital p}-CdTe: The control of electrical properties of the system Au/{ital p}-CdTe/Au by temperature gradient

    Energy Technology Data Exchange (ETDEWEB)

    Vackova, S. [Charles University, Prague (Czech Republic)

    1994-08-10

    The interaction of holes with phonons was studied in {ital p}-CdTe by means of Seebeck effect and {ital I}-{ital U} characteristics measurements without and with longitudinal temperature gradient. The both phenomena are evidently influenced by optical phonon drag effect. Optical phonon drag effect obviously diminishes thermopower values, in the second case the {ital I}-{ital U} characteristics shift was observed; in our arrangement temperature difference 10 K increases or decreases the current through the sample of about 40%. The explanation of this effects observed is based on Gurevich {ital et} {ital al}. theory about the charge redistribution in mediums with nonequilibrium carriers (of two types) and phonons in semiconductors. Our experimental results could have new promising applications. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  4. Eco-friendly synthesis of TiO2, Au and Pt doped TiO2 nanoparticles for dye sensitized solar cell applications and evaluation of toxicity

    Science.gov (United States)

    Gopinath, K.; Kumaraguru, S.; Bhakyaraj, K.; Thirumal, S.; Arumugam, A.

    2016-04-01

    Driven by the demand of pure TiO2, Au and Pt doped TiO2 NPs were successfully synthesized using Terminalia arjuna bark extract. The eco-friendly synthesized NPs were characterized by UV-Vis-DRS, ATR-FT-IR, PL, XRD, Raman, SEM with EDX and TEM analysis. The synthesized NPs were investigation for dye sensitized solar cell applications. UV-Vis-Diffused Reflectance Spectra clearly showed that the expected TiO2 inter band absorption below 306 nm, incorporation of gold shows surface plasma resonant (SPR) near 555 nm and platinum incorporated TiO2 NPs shows absorbance at 460 nm. The energy conversion efficiency for Au doped TiO2 NPs when compared to pure and Pt doped TiO2 NPs. In addition to that, Au noble metal present TiO2 matrix and an improve open-circuit voltage (Voc) of DSSC. Synthesized NPs was evaluated into antibacterial and antifungal activities by disk diffusion method. It is observed that NPs have not shown any activities in all tested bacterial and fungal strains. In this eco-friendly synthesis method to provide non toxic and environmental friendly nanomaterials can be used for solar energy device application.

  5. Tuning the photoluminescence of condensed-phase cyclic trinuclear Au(I) complexes through control of their aggregated structures by external stimuli

    Science.gov (United States)

    Fujisawa, Kaori; Yamada, Shigeyuki; Yanagi, Yukihiro; Yoshioka, Yasunori; Kiyohara, Ayumi; Tsutsumi, Osamu

    2015-03-01

    A series of new cyclic trinuclear Au(I) complexes with alkoxy side chains of various lengths were synthesized as photoluminescence materials. None of the complexes emitted luminescence in solution; however, some showed photoluminescence in the crystalline phase. Single crystal X-ray structural analyses revealed that an intermolecular interaction between two Au atoms (aurophilic interaction) existed only in the emissive complexes, which formed molecular aggregates in the crystal. Because isolated molecules show no luminescence in the present system, we conclude that only molecules aggregated via aurophilic interactions can luminesce. We demonstrated that luminescence properties, such as colour and intensity, were very sensitive to the aggregated structure of the molecules. We also found that such luminescence properties can be controlled by a change in the aggregated structure induced by external stimuli, such as heat, solvent, and mechanical stress.

  6. Magnetic Flux Controllers for Induction Heating Applications

    Institute of Scientific and Technical Information of China (English)

    Valentin Nemkov; Robert Goldstein; Robert Ruffini

    2004-01-01

    Application of magnetic flux controllers/concentrators to induction heating coils can drastically improve the process efficiency and heat pattern control. Presentation includes: benefits provided by flux controllers, materials available for controllers, application techniques, computer assisted design of induction coils with concentrators, examples of applications. Depending on induction system design, magnetic flux controllers can concentrate heating in a specified area,change heat source distribution and shield a particular part zone or external area preventing unintended eddy current heating.Besides of the coil efficiency improvement and optimal power distribution, magnetic flux controllers reduce the coil current demand from a supplying circuitry thus strongly reducing losses in busswork, cables, transformers and inverter components.Improvement that can be achieved due to magnetic flux controllers is case dependable. 2D and 3D computer simulation allows the designer to predict accurately effect of controllers on the coil parameters and temperature distribution and optimize the whole electromagnetic system. Special attention in presentation is paid to new magnetodielectric materials optimized for induction heating conditions. These materials have high magnetic permeability and saturation flux density,excellent machinability, good chemical and temperature resistance. Concentrators from these materials can work in a wide range of frequencies and specific powers. Examples of magnetic flux controller application include surface hardening of shafts and gears, induction surface hardfacing and brazing.

  7. Controlling Lateral Fano Interference Optical Force with Au-Ge2Sb2Te5 Hybrid Nanostructure

    DEFF Research Database (Denmark)

    Cao, Tun; Bao, Jiaxin; Mao, Libang;

    2016-01-01

    We numerically demonstrate that a pronounced dipole-quadrupole (DQ) Fano resonance (FR) induced lateral force can be exerted on a dielectric particle 80 nm in radius (R-sphere = 80 nm) that is placed 5 nm above an asymmetric bow-tie nanoantenna array based on Au/Ge2Sb2Te5 dual layers. The DQ-FR-i...

  8. Assembling of redox proteins on Au(111) surfaces: A scanning probe microscopy investigation for application in bio-nanodevices

    Energy Technology Data Exchange (ETDEWEB)

    Andolfi, L. [Biophysics and Nanoscience Centre, INFM-CNISM, Dipartimento di Scienze Ambientali, Universita della Tuscia, Viterbo, I-01100 (Italy); Bizzarri, A.R. [Biophysics and Nanoscience Centre, INFM-CNISM, Dipartimento di Scienze Ambientali, Universita della Tuscia, Viterbo, I-01100 (Italy); Cannistraro, S. [Biophysics and Nanoscience Centre, INFM-CNISM, Dipartimento di Scienze Ambientali, Universita della Tuscia, Viterbo, I-01100 (Italy)]. E-mail: cannistr@unitus.it

    2006-09-25

    The morphology and conductive properties of azurin molecules, chemically attached to sulfhydryl terminated alkanethiol monolayer assembled on Au(111) surface, are mapped at single molecule level and compared with those observed for the same molecule immobilised on bare Au(111). High-resolution Tapping Mode Atomic Force Microscopy shows that the protein molecules immobilised on modified gold, better reproduces the crystallographic height of the protein, than that immobilised on bare gold. Such a height recovering is also found in the Scanning Tunnelling Microscopy images. Consistently, a good tunnelling conduction of azurins on the modified gold electrode is demonstrated by Tunnelling Spectroscopy. Cyclic voltammetry measurements show, in addition, that the redox activity of azurin molecules covalently immobilised on sulfhydryl functionalised Au(111) surface is retained. These results are discussed in connection with possible use of this linker in the assembling of nano-hybrid systems.

  9. Optimal control with aerospace applications

    CERN Document Server

    Longuski, James M; Prussing, John E

    2014-01-01

    Want to know not just what makes rockets go up but how to do it optimally? Optimal control theory has become such an important field in aerospace engineering that no graduate student or practicing engineer can afford to be without a working knowledge of it. This is the first book that begins from scratch to teach the reader the basic principles of the calculus of variations, develop the necessary conditions step-by-step, and introduce the elementary computational techniques of optimal control. This book, with problems and an online solution manual, provides the graduate-level reader with enough introductory knowledge so that he or she can not only read the literature and study the next level textbook but can also apply the theory to find optimal solutions in practice. No more is needed than the usual background of an undergraduate engineering, science, or mathematics program: namely calculus, differential equations, and numerical integration. Although finding optimal solutions for these problems is a...

  10. Fusion d'images multi-modales pour la radiothérapie conformationnelle : application au repositionnement du patient

    OpenAIRE

    1998-01-01

    Le traitement des cancers par radiothérapie externe met en .uvre un environnement complexe. L'irradiation doit être le plus possible limitée au volume tumoral, en évitant au maximum les tissus et organes sains avoisinants. L'utilisation de logiciels dosimétriques en trois dimensions permet d'adapter exactement la balistique d'irradiation à la forme de la tumeur. Le patient est replacé à chaque séance de son traitement dans la même position pour permettre de reproduire avec précision la balist...

  11. Controllable conversion of plasmonic Cu2-xS nanoparticles to Au2S by cation exchange and electron beam induced transformation of Cu2-xS-Au2S core/shell nanostructures.

    Science.gov (United States)

    Wang, Xianliang; Liu, Xin; Zhu, Dewei; Swihart, Mark T

    2014-08-01

    Self-doped Cu2-xS nanocrystals (NCs) were converted into monodisperse Cu2-xS-Au2S NCs of tunable composition, including pure Au2S, by cation exchange. The near-infrared (NIR) localized surface plasmon resonance (LSPR) was dampened and red-shifted with increasing Au content. Cation exchange was accompanied by elimination of cation vacancies and a change in crystal structure. Partially exchanged Cu2-xS-Au2S core/shell structures evolved to dumbbell-like structures under electron irradiation in the transmission electron microscope (TEM).

  12. Towards a laser fluence dependent nanostructuring of thin Au films on Si by nanosecond laser irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ruffino, F., E-mail: francesco.ruffino@ct.infn.it [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); MATIS CNR-IMM, via S. Sofia 64, I-95123 Catania (Italy); Pugliara, A. [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); Carria, E.; Romano, L. [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); MATIS CNR-IMM, via S. Sofia 64, I-95123 Catania (Italy); Bongiorno, C. [Consiglio Nazionale delle Ricerche - Istituto per la Microelettronica e Microsistemi (CNR-IMM) VIII Strada 5, 95121 Catania (Italy); Fisicaro, G. [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); Consiglio Nazionale delle Ricerche - Istituto per la Microelettronica e Microsistemi (CNR-IMM) VIII Strada 5, 95121 Catania (Italy); La Magna, A.; Spinella, C. [Consiglio Nazionale delle Ricerche - Istituto per la Microelettronica e Microsistemi (CNR-IMM) VIII Strada 5, 95121 Catania (Italy); Grimaldi, M.G. [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); MATIS CNR-IMM, via S. Sofia 64, I-95123 Catania (Italy)

    2012-09-15

    Highlights: Black-Right-Pointing-Pointer Au nanoclusters are produced by nanosecond laser irradiations of thin Au film on Si. Black-Right-Pointing-Pointer The shape, size, and surface density of the Au nanoclusters are tunable by laser fluence. Black-Right-Pointing-Pointer The formation dynamic of the Au nanoclusters under nanosecond laser irradiation is analyzed. - Abstract: In this work, we study the nanostructuring effects of nanosecond laser irradiations on 5 nm thick Au film sputter-deposited on Si. After deposition of Au on Si substrate, nanosecond laser irradiations were performed increasing the laser fluence from 750 to 1500 mJ/cm{sup 2}. Several analyses techniques, such as Rutherford backscattering spectrometry, scanning electron microscopy, atomic force microscopy, and transmission electron microscopy were crossed to study the morphological evolution of the Au film as a function of laser fluence. In particular, the formation of Au nanoparticles was observed. The analyses allowed a quantitative evaluation of the evolution of the nanoparticles size, surface density, and shape as a function of the laser fluence. Therefore, a control the structural properties of the Au nanoparticles is reached, for example, for applications in Si nanowires growth or plasmonics.

  13. Decentralized neural control application to robotics

    CERN Document Server

    Garcia-Hernandez, Ramon; Sanchez, Edgar N; Alanis, Alma y; Ruz-Hernandez, Jose A

    2017-01-01

    This book provides a decentralized approach for the identification and control of robotics systems. It also presents recent research in decentralized neural control and includes applications to robotics. Decentralized control is free from difficulties due to complexity in design, debugging, data gathering and storage requirements, making it preferable for interconnected systems. Furthermore, as opposed to the centralized approach, it can be implemented with parallel processors. This approach deals with four decentralized control schemes, which are able to identify the robot dynamics. The training of each neural network is performed on-line using an extended Kalman filter (EKF). The first indirect decentralized control scheme applies the discrete-time block control approach, to formulate a nonlinear sliding manifold. The second direct decentralized neural control scheme is based on the backstepping technique, approximated by a high order neural network. The third control scheme applies a decentralized neural i...

  14. Fast and facile preparation of CTAB based gels and their applications in Au and Ag nanoparticles synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Upadhyay, Ravi Kant, E-mail: rkupadhyay85@gmail.com [Department of Chemistry, School of Natural Sciences, Shiv Nadar University, Gautam Budh Nagar, 201314 Uttar Pradesh (India); Soin, Navneet, E-mail: n.soin@bolton.ac.uk [Knowledge Centre for Materials Chemistry (KCMC), Institute for Materials Research and Innovation (IMRI), University of Bolton, Deane Road, Bolton BL3 5AB (United Kingdom); Saha, Susmita, E-mail: ssaha@bose.res.in [Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India); Barman, Anjan, E-mail: abarman@bose.res.in [Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India); Sinha Roy, Susanta, E-mail: susanta.roy@snu.edu.in [Department of Physics, School of Natural Sciences, Shiv Nadar University, Gautam Budh Nagar, 201314 Uttar Pradesh (India)

    2015-04-15

    We have demonstrated that the gel-like mesophase of Cetyltrimethylammonium bromide (CTAB) can be synthesized by judicial adjustment of water to surfactant molar ratio (W{sub 0}), without using any additional salts, gelating agents or co-surfactants. Gel formation was found to be highly dependent on the water to surfactant molar ratio (W{sub 0}), with the lowest value of W{sub 0} (41.5) resulting in rapid gel formation. Environmental scanning electron microscope (ESEM) analysis revealed that the gel was comprised of interconnected cylindrical structures. The presence of hydrogen bonding in the gel-like mesophase was confirmed by Fourier Transform Infrared spectroscopy (FTIR) analysis. Rheology measurements revealed that all the gel samples were highly viscoelastic in nature. Furthermore, Au and Ag containing CTAB gels were explored as precursors for the preparation of spherical Gold (Au) and Silver (Ag) nanoparticles using Sodium borohydride (NaBH{sub 4}) as reducing agent. The effects of NaBH{sub 4} concentration on the particle size and morphology of the Au and Ag nanoparticles have also been studied. - Highlights: • A facile synthesis of CTAB based gel-like mesophase is reported. • CTAB gels were obtained by adjusting water to surfactant molar ratio (W{sub 0}). • FTIR analysis revealed that hydrogen bonding plays a key role in gel formation. • Au, Ag nanoparticles were synthesized by using CTAB gel and NaBH{sub 4}.

  15. Magnetic gold nanocatalyst (nanocat-Fe–Au): catalytic applications for the oxidative esterification and hydrogen transfer reactions

    Science.gov (United States)

    An efficient and sustainable protocol is described for the oxidative esterification of aldehydes and the reduction of aromatic nitro compounds that uses magnetically separable and reusable maghemite-supported gold nanocatalyst (nanocat-Fe-Au) under mild conditions. The complex ch...

  16. Silver Nanopartical over AuFON Substrate for Enhanced Raman Readout and Their Application in Pesticide Monitoring

    Directory of Open Access Journals (Sweden)

    Kun Guo

    2015-04-01

    Full Text Available Surface-enhanced Raman detection of thiram is demonstrated by using Ag-nanoparticles (Ag NPs on Au film over nanosphere (AuFON substrate as the hybrid substrate. The SERS signal of the Ag NPs attached to solid supports is studied. The close coupling together of thousands of Ag NPs on AuFON leads to the generation of hot spots for SERS. The Ag NPs on AuFON can be applied to detect rhodamine-6G (R6G with the detection limitation of 10−11 M and the pesticide thiram in acetone with a detection limit of as low as 0.24 ppm, which is much lower than the maximal residue limit (MRL of 7 ppm in fruit prescribed by the U.S. Environmental Protection Agency (EPA. The hybrid substrates are shown to be highly sensitive for the detection of thriam, which produce highly enhanced Raman signals with good uniformity and reproducibility due to having plenty of hot spots on its surface.

  17. Soft Computing Techniques for Process Control Applications

    Directory of Open Access Journals (Sweden)

    Rahul Malhotra

    2011-09-01

    Full Text Available Technological innovations in soft computing techniques have brought automation capabilities to new levelsof applications. Process control is an important application of any industry for controlling the complexsystem parameters, which can greatly benefit from such advancements. Conventional control theory isbased on mathematical models that describe the dynamic behaviour of process control systems. Due to lackin comprehensibility, conventional controllers are often inferior to the intelligent controllers. Softcomputing techniques provide an ability to make decisions and learning from the reliable data or expert’sexperience. Moreover, soft computing techniques can cope up with a variety of environmental and stabilityrelated uncertainties. This paper explores the different areas of soft computing techniques viz. Fuzzy logic,genetic algorithms and hybridization of two and abridged the results of different process control casestudies. It is inferred from the results that the soft computing controllers provide better control on errorsthan conventional controllers. Further, hybrid fuzzy genetic algorithm controllers have successfullyoptimized the errors than standalone soft computing and conventional techniques.

  18. MO-FG-303-08: PET-Detectable Bimetallic (Zn@Au) Nanoparticles for Radiotherapy and Molecular Imaging Applications

    Energy Technology Data Exchange (ETDEWEB)

    Cho, J; Cho, S [UT MD Anderson Cancer Center, Houston, TX (United States); Wang, M; Zubarev, E [Rice University, Houston, TX - Texas (United States); Gonzalez-Lepera, C [University of Texas MD Anderson Cancer Center, Houston, TX - Texas (United States)

    2015-06-15

    Purpose: A technical challenge in clinical translation of GNP-mediated radiotherapy is lack of in-vivo imaging tools for monitoring biodistribution of GNPs. While several modalities (x-ray fluorescence, photoacoustic, etc.) are investigated, we propose a potentially more effective technique based on PET imaging. We developed Zn@Au NPs whose Zn core acts as positron emitters when activated by protons, while the Au shell plays the original role for GNP-mediated radiosensitization. Methods: Spherical Zn NPs (∼7nm diameter) were synthesized and then coated with ∼7nm thick Au layer to make Zn@Au NPs (∼20nm diameter). A water slurry containing 29mg of Zn@Au NPs was deposited (<10µm thickness) on a thin cellulose target and subsequently baked to remove the water. The cellulose matrix was placed in an aluminum target holder and irradiated with 14.5MeV protons from a GE PETtrace cyclotron with 4µA for 5min. After irradiation the cellulose matrix with the NPs was placed in a dose calibrator to assay radioactivity. Gamma spectroscopy using a HPGe detector was conducted on a very small fraction (<1mg) of the irradiated NPs. Results: We measured 158µCi of activity 32min after end of bombardment (EOB) using 66Ga setting on the dose calibrator (contribution from the cellulose matrix is negligible) which decreased to 2µCi over a 24hrs period. A gamma spectrum started one hour after EOB on the small fraction and acquired for 700sec showed a strong peak at 511keV (∼40,000 counts) with several other peaks (highest peak <1200 counts) of smaller magnitude. Conclusion: Strong 511keV gamma emission from proton-activated Zn cores can potentially be utilized to image the biodistribution of Zn@Au NPs using a PET scanner. The developed Zn@Au NPs are expected to retain radiosensitizing capability similar to solid GNPs, while observable through PET imaging for human-sized objects. Moreover, bioconjugated PET-detectable GNPs would allow a new option to perform molecular imaging.

  19. A Fabrication Route for Arrays of Ultra-low-Noise MoAu Transition Edge Sensors on Thin Silicon Nitride for Space Applications

    CERN Document Server

    Glowacka, D M; Goldie, D J; Withington, S

    2014-01-01

    We describe a process route to fabricate arrays of Ultra-low-Noise MoAu Transition Edge Sensors (TESs). The low thermal conductance required for space applications is achieved using 200 nm-thick Silicon Nitride (SiNx ) patterned to form long-thin legs with widths of 2.1 {\\mu}m. Using bilayers formed on SiNx islands from films with 40 nm-thick Mo and Au thicknesses in the range 30 to 280 nm deposited by dc-sputtering in ultra-high vacuum we can obtain tunable transition temperatures in the range 700 to 70 mK. The sensors use large-area absorbers fabricated from high resistivity, thin-film beta-phase Ta to provide impedance-matching to incident radiation. The absorbers are patterned to reduce the heat capacity associated with the nitride support structure and include Au thermalizing features to assist the heat flow into the TES. Arrays of 400 detectors at the pixel spacing required for the long-wavelength band of the far-infrared instrument SAFARI are now being fabricated. Device yields approaching 99% are achi...

  20. Shape-Controlled Synthesis of Magnetic Iron Oxide@SiO₂-Au@C Particles with Core-Shell Nanostructures.

    Science.gov (United States)

    Li, Mo; Li, Xiangcun; Qi, Xinhong; Luo, Fan; He, Gaohong

    2015-05-12

    The preparation of nonspherical magnetic core-shell nanostructures with uniform sizes still remains a challenge. In this study, magnetic iron oxide@SiO2-Au@C particles with different shapes, such as pseduocube, ellipsoid, and peanut, were synthesized using hematite as templates and precursors of magnetic iron oxide. The as-obtained magnetic particles demonstrated uniform sizes, shapes, and well-designed core-shell nanostructures. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) analysis showed that the Au nanoparticles (AuNPs) of ∼6 nm were uniformly distributed between the silica and carbon layers. The embedding of the metal nanocrystals into the two different layers prevented the aggregation and reduced the loss of the metal nanocrystals during recycling. Catalytic performance of the peanut-like particles kept almost unchanged without a noticeable decrease in the reduction of 4-nitrophenol (4-NP) in 8 min even after 7 cycles, indicating excellent reusability of the particles. Moreover, the catalyst could be readily recycled magnetically after each reduction by an external magnetic field.

  1. Different control applications on a vehicle using fuzzy logic control

    Indian Academy of Sciences (India)

    Nurkan Yagiz; L Emir Sakman; Rahmi Guclu

    2008-02-01

    In this paper, the active suspension control of a vehicle model that has five degrees of freedom with a passenger seat using a fuzzy logic controller is studied. Three cases are taken into account as different control applications. In the first case, the vehicle model having passive suspensions with an active passenger seat is controlled. In the second case, active suspensions with passive passenger seat combination are controlled. In the third case, both the passenger seat and suspensions have active controllers. Vibrations of the passenger seat in the three cases due to road bump input are simulated. At the end of the study, the results are compared in order to select the combination that supplies the best ride comfort.

  2. Accurate tracking control in LOM application

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The fabrication of accurate prototype from CAD model directly in short time depends on the accurate tracking control and reference trajectory planning in (Laminated Object Manufacture) LOM application. An improvement on contour accuracy is acquired by the introduction of a tracking controller and a trajectory generation policy. A model of the X-Y positioning system of LOM machine is developed as the design basis of tracking controller. The ZPETC (Zero Phase Error Tracking Controller) is used to eliminate single axis following error, thus reduce the contour error. The simulation is developed on a Maltab model based on a retrofitted LOM machine and the satisfied result is acquired.

  3. Carbon nanotubes: controlled growth and application

    Directory of Open Access Journals (Sweden)

    Chang Liu

    2013-01-01

    Full Text Available Notable progress has been made on the synthesis, properties and uses of carbon nanotubes (CNTs in the past two decades. However, the controlled growth of single-wall CNTs (SWCNTs with predefined and uniform structures remains a big challenge, and making full use of CNTs in applications still requires great effort. In this article, our strategies and recent progress on the controlled synthesis of SWCNTs by chemical vapor deposition are reviewed, and the applications of CNTs in lithium-ion batteries, transparent conductive films, and as connectors of metal atomic chains are discussed. Finally, future prospects for CNTs are considered.

  4. Modular control system for embedded applications

    Directory of Open Access Journals (Sweden)

    Dostálek Petr

    2016-01-01

    Full Text Available This paper deals with hardware design of a modular control system intended for embedded applications demanding high computational power while maintaining low cost. The control system central unit is based on 32bit microcontroller MK60DN512 with ARM Cortex-M4 core manufactured by NXP Semiconductor. Module provides all the necessary signals on the two 2-row 40 pin headers and Ethernet communication interface in the form of a small daughter board. It is connected to the mainboard which must always contain 5 V stabilized power supply; other circuits are application specific. In our application the mainboard is equipped with SD card slot, RS232 and RS485 interface which is used for high speed interconnection with up to 15 expansion peripheral modules. This concept enables high flexibility to specific application demands without necessity of redesigning the control system. Controller is freely programmable in C language using any compatible integrated development environment – NXP Kinetis Design Studio, for example. Software development and debugging is simplified by our support program libraries including necessary routines for control and monitoring tasks.

  5. Industrial applications of advanced control techniques

    Institute of Scientific and Technical Information of China (English)

    刘国平

    2003-01-01

    This paper discusses two industrial control applications using advanced control techniques. They are theoptimal-tuning nonlinear PID control of hydraulic systems and the neural predictive control of combustor acoustic ofgas turbines. For hydraulic control systems, an optimal PID controller with inverse of dead zone is introduced toovercome the dead zone and is designed to satisfy desired time-domain performance requirements. Using the adaptivemodel, an optimal-tuning PID control scheme is proposed to provide optimal PID parameters even in the case wherethe system dynamics is time variant. For combustor acoustic control of gas turbines, a neural predictive controlstrategy is presented, which consists of three parts: an output model, output predictor and feedback controller. Theoutput model of the combustor acoustic is established using neural networks to predict the output and overcome thetime delay of the system, which is often very large, compared with the sampling period. The output-feedback con-troller is introduced which uses the output of the predictor to suppress instability in the combustion process. The a-bove control strategies are implemented in the SIMULINK/dSPACE controller development environment. Theirperformance is evaluated on the industrial hydraulic test rig and the industrial combustor test rig.

  6. Graphene nanoribbons synthesized from molecular precursor polymerization on Au(110)

    Energy Technology Data Exchange (ETDEWEB)

    Massimi, Lorenzo; Ourdjini, Oualid; Della Pia, Ada; Mariani, Carlo; Betti, Maria Grazia [Dipartimento di Fisica, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy); Cavaliere, Emanuele; Gavioli, Luca [i-LAMP & Dipartimento di Matematica e Fisica, Università Cattolica, 25121 Brescia (Italy)

    2015-06-23

    A spectroscopic study of 10,10-dibromo-9,9 bianthracene (DBBA) molecules deposited on the Au(110) surface is presented, by means of ultraviolet and X-ray photoemission, and X-ray absorption spectroscopy. Through a thermally activated procedure, these molecular precursors polymerize and eventually form graphene nanoribbons (GNRs) with atomically controlled shape and width, very important building blocks for several technological applications. The GNRs observed by scanning tunneling microscopy (STM) appear as short segments on top of the gold surface reconstruction, pointing out the delicate balance among surface diffusion and surface corrugation in their synthesis on the Au(110) surface.

  7. Electronic Characterization of Au/DNA/ITO Metal-Semiconductor-Metal Diode and Its Application as a Radiation Sensor.

    Science.gov (United States)

    Al-Ta'ii, Hassan Maktuff Jaber; Periasamy, Vengadesh; Amin, Yusoff Mohd

    2016-01-01

    Deoxyribonucleic acid or DNA molecules expressed as double-stranded (DSS) negatively charged polymer plays a significant role in electronic states of metal/silicon semiconductor structures. Electrical parameters of an Au/DNA/ITO device prepared using self-assembly method was studied by using current-voltage (I-V) characteristic measurements under alpha bombardment at room temperature. The results were analyzed using conventional thermionic emission model, Cheung and Cheung's method and Norde's technique to estimate the barrier height, ideality factor, series resistance and Richardson constant of the Au/DNA/ITO structure. Besides demonstrating a strongly rectifying (diode) characteristic, it was also observed that orderly fluctuations occur in various electrical parameters of the Schottky structure. Increasing alpha radiation effectively influences the series resistance, while the barrier height, ideality factor and interface state density parameters respond linearly. Barrier height determined from I-V measurements were calculated at 0.7284 eV for non-radiated, increasing to about 0.7883 eV in 0.036 Gy showing an increase for all doses. We also demonstrate the hypersensitivity phenomena effect by studying the relationship between the series resistance for the three methods, the ideality factor and low-dose radiation. Based on the results, sensitive alpha particle detectors can be realized using Au/DNA/ITO Schottky junction sensor.

  8. Computational criterion for application of the characteristic effective medium approximation to ultrathin Co-Au multi-bilayer structures

    Energy Technology Data Exchange (ETDEWEB)

    Haija, A.J. [Physics Department, Indiana University of Pennsylvania, 975 Oakland Avenue, Weyandt Hall-Rm 40, Indiana, PA 15705-1087 (United States)], E-mail: haija@iup.edu; Larry Freeman, W.; DeNinno, Matthew [Physics Department, Indiana University of Pennsylvania, 975 Oakland Avenue, Weyandt Hall-Rm 40, Indiana, PA 15705-1087 (United States)

    2008-11-30

    The basic optical properties, reflectivity and transmissivity, of three sets of Co-Au bilayer structures are calculated for normal incidence in the wavelength range 300-700 nm. Each set consists of a total number of bilayer identity periods m=1, 2, 3, 4, 5, 6. The thickness of the bilayer in each set is 5, 7, and 9 nm. The composition of the bilayer is kept fixed: 40% Co and 60% Au. The calculations are done for ideal layered Co-Au stacks using the characteristic matrix technique. Calculations for each stack based on the thicknesses of the two composite layers and their optical constants are contrasted against calculations using the characteristic effective medium approximation, CEMA. A third calculation of the optical properties for each stack is performed, again using the CEMA, but when the whole stack, called the effective stack, ES, is treated as one uniform medium of effective optical constants. The comparison of the three sets of calculations for all sets is intended to shed more light onto the validity of the CEMA approximation that has been established for thin bilayer structures whose constituents have thicknesses much less than the wavelength of the incident radiation. The study establishes a limit based on the product of the number of layers m and the identity period of the stack h, beyond which the CEMA approximation cannot be applied. This limit is consistent with a previous study carried out on Ag-SiO ultrathin stacks.

  9. Computational criterion for application of the characteristic effective medium approximation to ultrathin Co Au multi-bilayer structures

    Science.gov (United States)

    Haija, A. J.; Larry Freeman, W.; DeNinno, Matthew

    2008-11-01

    The basic optical properties, reflectivity and transmissivity, of three sets of Co-Au bilayer structures are calculated for normal incidence in the wavelength range 300-700 nm. Each set consists of a total number of bilayer identity periods m=1, 2, 3, 4, 5, 6. The thickness of the bilayer in each set is 5, 7, and 9 nm. The composition of the bilayer is kept fixed: 40% Co and 60% Au. The calculations are done for ideal layered Co-Au stacks using the characteristic matrix technique. Calculations for each stack based on the thicknesses of the two composite layers and their optical constants are contrasted against calculations using the characteristic effective medium approximation, CEMA. A third calculation of the optical properties for each stack is performed, again using the CEMA, but when the whole stack, called the effective stack, ES, is treated as one uniform medium of effective optical constants. The comparison of the three sets of calculations for all sets is intended to shed more light onto the validity of the CEMA approximation that has been established for thin bilayer structures whose constituents have thicknesses much less than the wavelength of the incident radiation. The study establishes a limit based on the product of the number of layers m and the identity period of the stack h, beyond which the CEMA approximation cannot be applied. This limit is consistent with a previous study carried out on Ag-SiO ultrathin stacks.

  10. Stimuli responsive nanomaterials for controlled release applications

    KAUST Repository

    Li, Song

    2012-01-01

    The controlled release of therapeutics has been one of the major challenges for scientists and engineers during the past three decades. Coupled with excellent biocompatibility profiles, various nanomaterials have showed great promise for biomedical applications. Stimuli-responsive nanomaterials guarantee the controlled release of cargo to a given location, at a specific time, and with an accurate amount. In this review, we have combined the major stimuli that are currently used to achieve the ultimate goal of controlled and targeted release by "smart" nanomaterials. The most heavily explored strategies include (1) pH, (2) enzymes, (3) redox, (4) magnetic, and (5) light-triggered release.

  11. Optimal control applications in electric power systems

    CERN Document Server

    Christensen, G S; Soliman, S A

    1987-01-01

    Significant advances in the field of optimal control have been made over the past few decades. These advances have been well documented in numerous fine publications, and have motivated a number of innovations in electric power system engineering, but they have not yet been collected in book form. Our purpose in writing this book is to provide a description of some of the applications of optimal control techniques to practical power system problems. The book is designed for advanced undergraduate courses in electric power systems, as well as graduate courses in electrical engineering, applied mathematics, and industrial engineering. It is also intended as a self-study aid for practicing personnel involved in the planning and operation of electric power systems for utilities, manufacturers, and consulting and government regulatory agencies. The book consists of seven chapters. It begins with an introductory chapter that briefly reviews the history of optimal control and its power system applications and also p...

  12. Ultrasound control modelization at the Atomic Energy Commission; La modelisation du controle par ultrasons au commissariat a l`energie atomique

    Energy Technology Data Exchange (ETDEWEB)

    Calmon, P.; Lecoeur-Taibi, I.; Lhemery, A. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. des Procedes et Systemes Avances

    1995-10-01

    The Champ-Sons code (for the ultrasonic field modelization) and of the Mephisto code (prediction of the ultrasonic echography from the a priori knowledge of the controlled piece and of the encountered defects) are presented with three applications: pipes with inner or outer cracks, rocket tank fuel with a welded joint and PWR pressure vessel with an irregular coating. (A.B.). 7 refs., 4 figs.

  13. Contactless Magnetic Gear for Robot Control Application

    Science.gov (United States)

    Komiyama, Hiroki; Uchimura, Yutaka

    This paper describes the application of a magnetic gear to a robot by fulfilling the essential requirements for a robot control, which are velocity control, position control, and force control. A magnetic gear is a transmission device that realizes contactless torque transmission by applying a magnetic force. When using a magnetic gear, cogging torque and spring characteristics need to be considered. In this paper, we introduce an approximate model of cogging torque. This model is used for velocity control to attenuate the disturbance due to cogging torque. In the case of position control, the oscillations due to the spring effect of the magnetic attractive force become a problem. To reduce the adverse effect due to these oscillations, resonance ratio control is applied. We also propose to use a magnetic gear for realizing the force sensorless bilateral control of teleoperation. Thanks to the frictionless transmission of a magnetic gear, the force sensorless estimation of a reaction force can be realized using a reaction force observer.

  14. Enzyme-catalyzed bio-pumping of electrons into au-nanoparticles: a surface plasmon resonance and electrochemical study.

    Science.gov (United States)

    Lioubashevski, Oleg; Chegel, Vladimir I; Patolsky, Fernando; Katz, Eugenii; Willner, Itamar

    2004-06-09

    The enzyme glucose oxidase (GOx) is reconstituted on a flavin adenin dinucleotide (FAD, 1) cofactor-functionalized Au-nanoparticle (Au-NP), 1.4 nm, and the GOx/Au-NP hybrid is linked to a bulk Au-electrode by a short dithiol, 1,4-benzenedithiol (2), or a long dithiol, 1,9-nonanedithiol (3), monolayer. The reconstituted GOx/Au-NP hybrid system exhibits electrical communication between the enzyme redox cofactor and the Au-NP core. Because the thiol monolayers provide a barrier for electron tunneling, the electron transfer occurring upon the biocatalytic oxidation of glucose results in the Au-NPs charging. The charging of the Au-NPs alters the plasma frequency and the dielectric constant of the Au-NPs, thus leading to the changes of the dielectric constant of the interface. These are reflected in pronounced shifts of the plasmon angle, theta(P), in the surface plasmon resonance (SPR) spectra. As the biocatalytic charging phenomenon is controlled by the concentration of glucose, the changes in the theta(P) values correlate with the concentration of glucose. The biocatalytic charging process is characterized by following the differential capacitance of the GOx/Au-NP interface and by monitoring the potential generated on the bulk Au-electrode. The charging of the GOx/Au-NPs is also accomplished in the absence of glucose by the application of an external potential on the electrode, that resulted in similar plasmon angle shifts. The results allowed us to estimate the number of electrons stored per Au-NP at variable concentrations of glucose in the presence of the two different thiol linkers.

  15. Au-Ag hollow nanostructures with tunable SERS properties

    Science.gov (United States)

    Jiji, S. G.; Gopchandran, K. G.

    2017-01-01

    Fabrication of hollow Au-Ag nanoparticles is done by the sequential action of galvanic replacement and Kirkendall effect. Polyol synthesized silver nanoparticles were used as templates and the size of cavities is controlled by the systematic addition of the HAuCl4. Au-Ag nanoparticles carved in different depths were tested for application as substrates for surface enhanced Raman scattering. Two medically important Raman active analytes-Nile blue chloride and Crystal violet were used in the surface enhanced Raman scattering (SERS) performance analysis. A systematic study has been made on the Raman enhancement of hollow nanoparticles fabricated with different cavity dimensions and compared with that of the silver templates used. The enhancement observed for these hollow substrates with cavities is of interest since Au protected hollow nanostructures are vital and an active area of interest in drug delivery systems.

  16. Control of nonlinear systems with applications

    Science.gov (United States)

    Pan, Haizhou

    In practical applications of feedback control, most actuators exhibit physical constraints that limit the control amplitude and/or rate. The principal challenge of control design problem for linear systems with input constraints is to ensure closed-loop stability and yield a good transient performance in the presence of amplitude and/or rate-limited control. Since actuator saturation manifests itself as a nonlinear behavior in an otherwise linear system, the development of a nonconservative saturation control design methodology poses a significant challenge. In particular, it is well known that unstable linear systems can be stabilized using smooth controllers only in a local sense in the presence of actuator saturation. Thus, it is of paramount importance to develop a saturation control design methodology that yields a nonconservative estimate of the stability domain for closed-loop system. The first part of this research focuses on a numerically tractable formulation of the control synthesis problem for linear systems with actuator amplitude and rate saturation nonlinearity using a linear-matrix-inequality (LMI) framework. Following the recent trend in the actuator saturation control research, we (i) utilize absolute stability theory to ensure closed-loop stability and (ii) minimize a quadratic cost to account for the closed-loop system performance degradation. In order to reduce the inherent conservatism of the absolute stability based saturation control framework, we exploit stability multipliers (of, e.g., weighted circle criterion, Popov criterion, etc.). For the control of linear systems with simultaneous actuator amplitude and rate saturation nonlinearities, by virtue of a rate limiter that is predicated on designing the control amplitude and then computing the control rates, we directly account for rate constraints. Both continuous- and discrete-time systems with actuator saturation are considered. A number of design examples are presented to demonstrate

  17. Magnetic, optical and relaxometric properties of organically coated gold-magnetite (Au-Fe{sub 3}O{sub 4}) hybrid nanoparticles for potential use in biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    Umut, E., E-mail: eumut@hacettepe.edu.tr [Hacettepe University Physics Engineering Department, 06800 Beytepe-Ankara (Turkey); Pineider, F. [INSTM and Universita degli Studi di Firenze, Department of Chemistry, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy); CNR-ISTM Padova, 35131 Padova (Italy); Arosio, P. [INSTM and Universita degli Studi di Milano, Department of Molecular Sciences Applied to Biosystems (DISMAB), I-20134 Milano (Italy); Sangregorio, C. [INSTM and Universita degli Studi di Firenze, Department of Chemistry, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy); CNR-ISTM Milano, 50123 via C.Golgi 19, 20133 Milano (Italy); Corti, M. [INSTM, CNISM and Dipartimento di Fisica ' A.Volta' , Univ. di Pavia, Via Bassi 6, I-27100 Pavia (Italy); Tabak, F. [Hacettepe University Physics Engineering Department, 06800 Beytepe-Ankara (Turkey); Lascialfari, A. [INSTM and Universita degli Studi di Milano, Department of Molecular Sciences Applied to Biosystems (DISMAB), I-20134 Milano (Italy); INSTM, CNISM and Dipartimento di Fisica ' A.Volta' , Univ. di Pavia, Via Bassi 6, I-27100 Pavia (Italy); Ghigna, P. [INSTM and Dipartimento di Chimica Univ. di Pavia, v.le Taramelli 13, I-27100 Pavia (Italy)

    2012-08-15

    We present the magnetic, optical and relaxometric properties of multifunctional Au-Fe{sub 3}O{sub 4} hybrid nanoparticles (HNPs), as possible novel contrast agents (CAs) for magnetic resonance imaging (MRI). The HNPs have been synthesized by wet chemical methods in heterodimer and core-shell geometries and capped with oleylamine. Structural characterization of the samples have been made by X-ray diffraction and transmission electron microscopy, while magnetic properties have been investigated by means of Superconducting Quantum Interference Device-SQUID magnetometry experiments. As required for MRI applications using negative CAs, the samples resulted superparamagnetic at room temperature and well above their blocking temperatures. Optical properties have been investigated by analyzing the optical absorbtion spectra collected in UV-visible region. Relaxometric measurements have been performed on organic suspensions of HNPs and Nuclear Magnetic Resonance (NMR) dispersion curves have been obtained by measuring the longitudinal 1/T{sub 1} and transverse 1/T{sub 2} relaxation rates of solvent protons in the range 10 kHz/300 MHz at room temperature. NMR relaxivities r{sub 1} and r{sub 2} have been compared with ENDOREM{sup Registered-Sign }, one of the commercial superparamagnetic iron oxide based MRI contrast agents. MRI contrast enhancement efficiencies have been investigated also by examining T{sub 2}-weighted MR images of suspensions. The experimental results suggest that the nanoparticles' suspensions are good candidates as negative CAs. - Highlights: Black-Right-Pointing-Pointer Au-Fe{sub 3}O{sub 4} superparamagnetic Hybrid NanoPrticles (HNPs) enhance contrast in MRI. Black-Right-Pointing-Pointer HNPs are expected to have optical activities through observed SPR phenomena. Black-Right-Pointing-Pointer HNPs have relatively high magnetic anisotropy originating from Au/Fe{sub 3}O{sub 4} interface. Black-Right-Pointing-Pointer Magnetic dipolar interactions have

  18. Voltage controlled spintronics device for logic applications.

    Energy Technology Data Exchange (ETDEWEB)

    Bader, S. D.; You, C.-Y.

    1999-09-03

    We consider logic device concepts based on our previously proposed spintronics device element whose magnetization orientation is controlled by application of a bias voltage instead of a magnetic field. The basic building block is the voltage-controlled rotation (VCR) element that consists of a four-layer structure--two ferromagnetic layers separated by both nanometer-thick insulator and metallic spacer layers. The interlayer exchange coupling between the two ferromagnetic layers oscillates as a function of applied voltage. We illustrate transistor-like concepts and re-programmable logic gates based on VCR elements.

  19. Controlled functionalization of nanoparticles & practical applications

    Science.gov (United States)

    Rashwan, Khaled

    With the increasing use of nanoparticles in both science and industry, their chemical modification became a significant part of nanotechnology. Unfortunately, most commonly used procedures provide just randomly functionalized materials. The long-term objective of our work is site- and stoichiometrically-controlled functionalization of nanoparticles with the utilization of solid supports and other nanostructures. On the examples of silica nanoparticles and titanium dioxide nanorods, we have obtained results on the solid-phase chemistry, method development, and modeling, which advanced us toward this goal. At the same time, we explored several applications of nanoparticles that will benefit from the controlled functionalization: imaging of titanium-dioxide-based photocatalysts, bioimaging by fluorescent nanoparticles, drug delivery, assembling of bone implants, and dental compositions. Titanium dioxide-based catalysts are known for their catalytic activity and their application in solar energy utilization such as photosplitting of water. Functionalization of titanium dioxide is essential for enhancing bone-titanium dioxide nanotube adhesion, and, therefore, for its application as an interface between titanium implants and bones. Controlled functionalization of nanoparticles should enhance sensitivity and selectivity of nanoassemblies for imaging and drug delivery applications. Along those lines, we studied the relationship between morphology and surface chemistry of nanoparticles, and their affinity to organic molecules (salicylic and caffeic acid) using Langmuir adsorption isotherms, and toward material surfaces using SEM- and TEM-imaging. We focused on commercial samples of titanium dioxide, titanium dioxide nanorods with and without oleic acid ligands, and differently functionalized silica nanoparticles. My work included synthesis, functionalization, and characterization of several types of nanoparticles, exploring their application in imaging, dentistry, and bone

  20. Fixed-frequency and Frequency-agile (au, HTS) Microstrip Bandstop Filters for L-band Applications

    Science.gov (United States)

    Saenz, Eileen M.; Subramanyam, Guru; VanKeuls, Fred W.; Chen, Chonglin; Miranda, Felix A.

    2001-01-01

    In this work, we report on the performance of a highly selective, compact 1.83 x 2.08 cm(exp 2) (approx. 0.72 x 0.82 in(exp 2) microstrip line bandstop filter of YBa2CU3O(7-delta) (YBCO) on LaAlO3 (LAO) substrate. The filter is designed for a center frequency of 1.623 GHz for a bandwidth at 3 dB from reference baseline of less than 5.15 MHz, and a bandstop rejection of 30 dB or better. The design and optimization of the filter was performed using Zeland's IE3D circuit simulator. The optimized design was used to fabricate gold (Au) and High-Temperature Superconductor (HTS) versions of the filter. We have also studied an electronically tunable version of the same filter. Tunability of the bandstop characteristics is achieved by the integration of a thin film conductor (Au or HTS) and the nonlinear dielectric ferroelectric SrTiO3 in a conductor/ferroelectric/dielectric modified microstrip configuration. The performance of these filters and comparison with the simulated data will be presented.

  1. Control Improvisation with Application to Music

    Science.gov (United States)

    2013-11-04

    Control Improvisation with Application to Music Alexandre Donze Sophie Libkind Sanjit A. Seshia David Wessel Electrical Engineering and Computer...to Music 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7...domain of music . More speci cally, we consider the scenario of generating a monophonic Jazz melody (solo) on a given song harmonization. The music is

  2. Improvement on controllable fabrication of streptavidin-modified three-layer core-shell Fe3O4@SiO2@Au magnetic nanocomposites with low fluorescence background.

    Science.gov (United States)

    Jiang, Hongrong; Zeng, Xin; Xi, Zhijiang; Liu, Ming; Li, Chuanyan; Li, Zhiyang; Jin, Lian; Wang, Zhifei; Deng, Yan; He, Nongyue

    2013-04-01

    In present study, we put forward an approach to prepare three-layer core-shell Fe3O4@SiO2@Au magnetic nanocomposites via the combination of self-assembling, seed-mediated growing and multi-step chemical reduction. The Fe3O4@SiO2@Au magnetic nanocomposites were analyzed and characterized by transmission electron microscope (TEM), scanning electronic microscope (SEM), energy dispersive spectrometer analysis (EDS), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), and ultraviolet and visible spectrophotometer (UV-Vis). TEM and SEM characterizations showed that the FeO4@SiO2@Au nanocomposites were obtained successfully with three-layer structures, especially a layer of thin, smooth and continuous gold shell. The average diameter of Fe3O4@SiO2@Au nanocomposites was about 600 nm and an excellent dispersity was observed for the as-prepared nanoparticles. EDS characterizations demonstrated that the nanocomposites contained three elements of the precursors, Fe, Si, and Au. Furthermore, FT-IR showed that the silica and gold shell were coated successfully. UV-Vis and VSM characterizations showed that the Fe3O4@SiO2@Au nanocomposites exhibited good optical and magnetic property, and the saturation magnetization was 25.76 emu/g. In conclusion, the Fe3O4@SiO2@Au magnetic nanocomposites with three-layer core-shell structures were prepared. Furthermore, Fe3O4@SiO2@Au magnetic nanocomposites were modified with streptavidin (SA) successfully, and it was validated that they performed low fluorescence background, suggesting that they should have good applications especially in bioassay based on fluorescence detection through bonding the biotinylated fluorescent probes.

  3. Resonant mode controllers for launch vehicle applications

    Science.gov (United States)

    Schreiner, Ken E.; Roth, Mary Ellen

    Electro-mechanical actuator (EMA) systems are currently being investigated for the National Launch System (NLS) as a replacement for hydraulic actuators due to the large amount of manpower and support hardware required to maintain the hydraulic systems. EMA systems in weight sensitive applications, such as launch vehicles, have been limited to around 5 hp due to system size, controller efficiency, thermal management, and battery size. Presented here are design and test data for an EMA system that competes favorably in weight and is superior in maintainability to the hydraulic system. An EMA system uses dc power provided by a high energy density bipolar lithium thionyl chloride battery, with power conversion performed by low loss resonant topologies, and a high efficiency induction motor controlled with a high performance field oriented controller to drive a linear actuator.

  4. Self-assembly of various Au nanocrystals on functionalized water-stable PVA/PEI nanofibers: a highly efficient surface-enhanced Raman scattering substrates with high density of "hot" spots.

    Science.gov (United States)

    Zhu, Han; Du, MingLiang; Zhang, Ming; Wang, Pan; Bao, ShiYong; Zou, Meiling; Fu, YaQin; Yao, JuMing

    2014-04-15

    We have demonstrated a facile approach for the fabrication of flexible and reliable sulfydryl functionalized PVA/PEI nanofibers with excellent water stability for the self-assembly of Au nanocrystals, such as Au nanoparticles (AuNPs), Au nanoflowers (AuNFs) and Au nanorods (AuNRs), used as the highly efficient surface-enhanced Raman scattering (SERS) substrates for the detection of rhodamine B (RhB). Various methods were employed to cross-link the PVA nanofibers with better morphology and porous structures after immersing in water for desired times. Various SERS-active Au nanocrystals, such as AuNPs, AuNFs, and AuNRs have been successfully synthesized. After the grafting of MPTES on the cross-linked PVA/PEI nanofibers, the Au nanocrystals can easily be self-assembled on the surfaces of the nanofibers because of the strong interactions of the Au-S chemical bondings. The Au nanocrystals self-assembled throughout the PVA/PEI nanofibers used as SERS substrates all exhibit enhanced SERS signals of RhB compared with their individual nanocrystals. It is mainly due to the close interparticle distance, mutual orientation and high density of "hot" spots, that can strongly affect the overall optical response and the SERS enhancement. By changing the amounts of the self-assembled AuNFs on the nanofibers, we can control the density of the "hot" spots. With the increased amounts of the AuNFs throughout the nanofibers, the SERS substrates show enhanced Raman signals of the RhB, indicating that the increased density of "hot" spots can directly lead to the SERS enhancement. The AuNFs/(PVA/PEI) SERS substrates show good sensitivity, reliability and low detection limit (10(-9) M). The presented approach can be broadly applicable to the assembly of different types of plasmonic nanostructures and these novel materials with strong SERS enhancement can be applied in bioanalysis and biosensors.

  5. Robust and Adaptive Control With Aerospace Applications

    CERN Document Server

    Lavretsky, Eugene

    2013-01-01

    Robust and Adaptive Control shows the reader how to produce consistent and accurate controllers that operate in the presence of uncertainties and unforeseen events. Driven by aerospace applications the focus of the book is primarily on continuous-dynamical systems.  The text is a three-part treatment, beginning with robust and optimal linear control methods and moving on to a self-contained presentation of the design and analysis of model reference adaptive control (MRAC) for nonlinear uncertain dynamical systems. Recent extensions and modifications to MRAC design are included, as are guidelines for combining robust optimal and MRAC controllers. Features of the text include: ·         case studies that demonstrate the benefits of robust and adaptive control for piloted, autonomous and experimental aerial platforms; ·         detailed background material for each chapter to motivate theoretical developments; ·         realistic examples and simulation data illustrating key features ...

  6. Characterization of Au Irradiated Glassy Polymeric Carbon at 2,000°C for Nuclear Applications

    Science.gov (United States)

    Abunaemeh, M.; Seif, M.; Batra, A.; Elsamadicy, A.; Yang, Y.; Wang, L.; Muntele, C.; Ila, D.

    The TRISO fuel has been used in some of the Generation IV nuclear reactor designs [1]. It consists of a fuel kernel of UOx coated with several layers of materials with different functions. Pyrolytic carbon (PyC) is one of the materials in the layers. In this study we investigate the possibility of using Glassy Polymeric Carbon (GPC) as an alternative to PyC. In this work, we are comparing the changes in physical and microstructure properties of GPC after exposure to irradiation fluence of 5 MeV Au equivalent to a 1 displacement per atom (dpa) for GPC prepared at 2,000°C. The GPC material is manufactured and tested at the Center for Irradiation Materials (CIM) at Alabama A&M University using Transmission electron microscopy (TEM) and stopping range of ions in matter (SRIM) software.

  7. Spectral Matrix Filtering Applied to Vsp Processing Application du filtrage matriciel au traitement des profils sismiques verticaux

    Directory of Open Access Journals (Sweden)

    Glangeaud F.

    2006-11-01

    données et de séparer ces signaux. Nous montrons que les signaux peuvent être automatiquement séparés sans connaissance a priori sur leurs vitesses apparentes, en fonction du produit scalaire (calculé dans le domaine fréquentiel et de l'amplitude relative des signaux. Nous montrons des exemples d'application sur des données de sismique de puits. Le filtrage matriciel est effectué dans le domaine fréquentiel en utilisant la matrice spectrale construite à l'aide des intercorrélations des différents enregistrements constituant les données à traiter. Les méthodes d'estimation de la matrice spectrale sont des méthodes de moyenne : moyenne en fréquence (méthode du périodogramme lissé et/ou moyenne en distance (lissage réalisé le long des diagonales de la matrice spectrale. Le lissage en fréquence est obtenu par l'intermédiaire d'une fonction de pondération (par exemple fenêtre de Hanning élevée à une puissance donnée appliquée à chaque corrélation. Les moyennes sont utilisées pour décorréler les signaux et de ce fait favoriser la séparation. Une fois correctement estimée, la matrice spectrale est diagonalisée sur toutes les fréquences du spectre moyenné, et décomposée selon ses vecteurs propres qui sont orthogonaux entre eux et normalisés. Chaque vecteur propre a une valeur propre associée qui représente la répartition d'énergie en fonction de la fréquence du modèle lié au vecteur propre. Le filtrage est réalisé par projection des données sur les différents vecteurs propres issus de la matrice spectrale. Il est à noter cependant que la séparation des différents signaux (projection sur vecteur propre n'est réalisée en terme d'indicatrice sismique que si les événements sismiques sont naturellement orthogonaux et alignés sur les vecteurs propres. Glangeaud et al (1989 ont étudié l'influence des amplitudes relatives et du produit scalaire de deux ondes. Si la vitesse apparente d'une onde est connue, cette derni

  8. Active Tuberculosis Case Finding in Port-au-Prince, Haiti: Experiences, Results, and Implications for Tuberculosis Control Programs

    Science.gov (United States)

    Delva, Guesly J.; Fort, Dumesle St.

    2016-01-01

    Background. Haiti has the highest tuberculosis (TB) prevalence in the Americas with 254 cases per 100,000 persons. Case detection relies on passive detection and TB services in many regions suffer from poor diagnostic and clinical resources. Methods. Mache Chache (“Go and Seek”) was a TB REACH Wave 3 funded TB case finding project in Port-au-Prince between July 2013 and September 2014, targeting four intervention areas with insufficient TB diagnostic performance. Results. Based on a verbal symptom screen emphasizing the presence of cough, the project identified 11,150 (11.75%) of all screened persons as TB subjects and 2.67% as smear-positive (SS+) TB cases. Enhanced case finding and strengthening of laboratory services led to a 59% increase in bacteriologically confirmed cases in the evaluation population. In addition, smear grades dropped significantly, suggesting earlier case detection. Xpert® MTB/RIF was successfully introduced and improved TB diagnosis in HIV-infected, smear-negative clinic patients, but not in HIV-negative, smear-negative TB suspects in the community. However, the number needed to screen for one additional SS+ case varied widely between clinic and community screening activities. Conclusion. Enhanced and active TB case finding in Haiti can improve TB diagnosis and care. However, screening algorithms have to be tailored to individual settings, necessitating long-term commitment. PMID:27668093

  9. Quantitative Robust Control Engineering: Theory and Applications

    Science.gov (United States)

    2006-09-01

    collaboration in this work, and wish also to gratefully appreciate the support given by the Spanish “Ministerio de Ciencia y Tecnología” (MCyT) under grant...1992). Discrete quantitative feedback technique, Capítulo 16 en el libro : Digital Control Systems: theory, hardware, software, 2ª edicion. McGraw...Rasmussen S.J., Garcia-Sanz, M. (2001, 2005), Software de diseño del libro Quantitative Feedback Theory: Fundamentals and Applications. Edición 2ª. CRCPress

  10. Strain distributions of confined Au/Ag and Ag/Au nanoparticles

    Institute of Scientific and Technical Information of China (English)

    黄红华; 章英; 刘晓山; 骆兴芳; 袁彩雷; 叶双莉

    2015-01-01

    The strain distributions of Au/Ag and Ag/Au nanoparticles confined in the Al2O3 matrix with different core sizes are investigated by using the finite element method, respectively. The simulation results clearly indicate that the compressive strains exerted on the Au/Ag and Ag/Au nanoparticles can be induced by the Al2O3 matrix. Moreover, it can be found that the strain gradient existing in a Au/Ag nanoparticle is much larger than that in a Ag/Au nanoparticle, which could be due to the larger Young’s modulus of Au than that of Ag. With the core size increasing, the strain gradient existing in the Au/Ag nanoparticle becomes larger, while the strain gradient existing in the Ag/Au nanoparticle keeps constant. These different strain distributions may have significant infl uences on the structures and morphologies of the Au/Ag and Ag/Au nanoparticles, leading to the different physical properties for potential applications.

  11. Time evolution of relativistic d + Au and Au + Au collisions

    CERN Document Server

    Wolschin, G; Mizoguchi, T; Suzuki, N; Biyajima, Minoru; Mizoguchi, Takuya; Suzuki, Naomichi; Wolschin, Georg

    2006-01-01

    The evolution of charged-particle production in collisions of heavy ions at relativistic energies is investigated as function of centrality in a nonequilibrium-statistical framework. Precise agreement with recent d + Au and Au + Au data at sqrt(s_NN) = 200 GeV is found in a Relativistic Diffusion Model with three sources for particle production. Only the midrapidity source comes very close to local equilibrium, whereas the analyses of the overall pseudorapidity distributions show that the systems remain far from statistical equilibrium.

  12. Electrochemical preparation of Au-PtNPs/SWNT modified electrode and its application%Au-PtNPs/SWNT复合材料修饰电极的电化学制备及其应用

    Institute of Scientific and Technical Information of China (English)

    李春兰; 朱效华; 朱旭; 徐茂田

    2013-01-01

    The Au-PtNPs/SWNT modified electrode was prepared by an electrochemical method at room temperature. The surface morphology of the modified electrode was measured by AFM and the results indicate that there are dispersions and high loadings of Au-Pt nanoparticles on SWNT. Under the optimal modification conditions(Electrodeposition of SWNT for 30 s,soaking in H2PtO6 for 10 minutes,multi-step deposition of gold nanoparticles for 45 cycles(glucose) or 30 cycles( methanol) ) ,glucose and methanol can be electrocatalytically oxidized on the surface of Au-PtNPs/SWNT modified electrode in alkaline environment Thus,the Au-Pt-NPs/SWNT/GCE is expected to be applied as a nonenzymatic glucose sensor or in the filed of methanol fuel cells.%在室温条件下,利用恒电位吸附法和多电位阶跃法制备了金-铂纳米粒子(Au-PtNPs)/单壁碳纳米管(SWNT)复合材料修饰电极,并利用电化学方法和原子力显微镜(AFM)对其进行了表征.结果表明:Au-Pt-NPs可很好的结合在SWNT表面,在该电极的最佳修饰条件下(SWNT分散液中电沉积30 s,H2PtO6中浸泡10min,循环阶跃沉积金纳米粒子45次(葡萄糖)或30次(甲醇))可以较好的电催化氧化碱性环境中的葡萄糖及甲醇,有望在葡萄糖无酶传感器及甲醇燃料电池中得到应用.

  13. The point-defect of carbon nanotubes anchoring Au nanoparticles

    DEFF Research Database (Denmark)

    Lv, Y. A.; Cui, Y. H.; Li, X. N.

    2010-01-01

    The understanding of the interaction between Au and carbon nanotubes (CNTs) is very important since Au/CNTs composites have wide applications in many fields. In this study, we investigated the dispersion of Au nanoparticles on the CNTs by transmission electron microscopy and the bonding mechanism...... of states, charge transfer and frontier molecular orbitals. (C) 2010 Elsevier B.V. All rights reserved....

  14. Electrochemicla Behavior of Ascorbic Acid on Hexaaza Macrocyclic Copper(II) Complex Modified Au Electrode and Its Analytical Application

    Institute of Scientific and Technical Information of China (English)

    WU,Hai-Xia; DONG,Shu-Qing; KANG,Jing-Wan; LU,Xiao-Quan

    2008-01-01

    A novel hexaaza macrocyclic copper(II) complex modified Au electrode was developed and used for the measurement of ascorbic acid. Its electrochemical behavior was investigated by cyclic voltammetry and scanning electrochemical microscopy. This modified electrode exhibited electrocatalytic response to the oxidation of ascorbic acid. Compared with a bare gold electrode, the modified electrode exhibited a 250 mV shift of the oxidation potential of ascorbic acid in the cathodic direction and a marked enhancement of the current response. The response current revealed a good linear relationship with the concentration of ascorbic acid in the range of 5.0×10-7 to 4.0× 10-5 mol/L and the detection limit of 4.8× 10-8 mol/L (S/N=3) in the pH 4.0 Tris-HCl buffer of ascorbic acid in fruits without any other pretreatment. The concentrations of ascorbic acid measured by this method were in good agreement with the literature values. It is very promising for the modified electrode to be used as an electrochemical sensor for the detection of ascorbic acid.

  15. First principles calculations of the optical and plasmonic response of Au alloys and intermetallic compounds.

    Science.gov (United States)

    Keast, V J; Barnett, R L; Cortie, M B

    2014-07-30

    Pure Au is widely used in plasmonic applications even though its use is compromised by significant losses due to damping. There are some elements that are less lossy than Au (e.g. Ag or Al) but they will normally oxidize or corrode under ambient conditions. Here we examine whether alloying Au with a second element would be beneficial for plasmonic applications. In order to evaluate potential alternatives to pure Au, the density of states (DOS), dielectric function and plasmon quality factor have been calculated for alloys and compounds of Au with Al, Cd, Mg, Pd, Pt, Sn, Ti, Zn and Zr. Substitutional alloying of Au with Al, Cd, Mg and Zn was found to slightly improve the plasmonic response. Of the large number of intermetallic compounds studied, only AuAl2, Au3Cd, AuMg, AuCd and AuZn were found to be suitable for plasmonic applications.

  16. Fabrication and spectroscopic studies of folic acid-conjugated Fe3O4@Au core-shell for targeted drug delivery application

    Science.gov (United States)

    Karamipour, Sh.; Sadjadi, M. S.; Farhadyar, N.

    2015-09-01

    Gold coated magnetite core shell is a kind of nanoparticle that include magnetic iron oxide core with a thin layer nanogold. Fe3O4-gold core-shell nanostructure can be used in biomedical applications such as magnetic bioseparation, bioimaging, targeting drug delivery and cancer treatment. In this study, the synthesis and characterization of gold coated magnetite nanoparticles were discussed. Magnetite nanoparticles with an average size of 6 nm in diameter were synthesized by the chemical co-precipitation method and gold-coated Fe3O4 core-shell nanostructures were produced with an average size of 11.5 nm in diameter by reduction of Au3+ with citrate ion in the presence of Fe3O4. Folate-conjugated gold coated magnetite nanoparticles were synthesized to targeting folate receptor that is overexpressed on the surface of cancerous cells. For this purpose, we used L-cysteine, as a bi-functional linker for attachment to gold surface and it was linked to the gold nanoparticles surface through its thiol group. Then, we conjugated amino-terminated nanoparticles to folic acid with an amide-linkage formation. These gold magnetic nanoparticles were characterized by various techniques such as X-ray powder diffraction (XRD) analysis, Fourier transform infrared spectrometer (FT-IR), UV-visible spectroscopy, transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), dispersive analysis of X-ray (EDAX) and vibrating sample magnetometer (VSM) analysis. The magnetic and optical properties of Fe3O4 nanostructure were changed by gold coating and attachment of L-cysteine and folic acid to Fe3O4@Au nanoparticles.

  17. Au-Ag@Au Hollow Nanostructure with Enhanced Chemical Stability and Improved Photothermal Transduction Efficiency for Cancer Treatment.

    Science.gov (United States)

    Jiang, Tongtong; Song, Jiangluqi; Zhang, Wenting; Wang, Hao; Li, Xiaodong; Xia, Ruixiang; Zhu, Lixin; Xu, Xiaoliang

    2015-10-07

    Despite the fact that Au-Ag hollow nanoparticles (HNPs) have gained much attention as ablation agents for photothermal therapy, the instability of the Ag element limits their applications. Herein, excess Au atoms were deposited on the surface of a Au-Ag HNP by improving the reduction power of l-ascorbic acid (AA) and thereby preventing the reaction between HAuCl4 and the Ag element in the Au-Ag alloy nanostructure. Significantly, the obtained Au-Ag@Au HNPs show excellent chemical stability in an oxidative environment, together with remarkable increase in extinction peak intensity and obvious narrowing in peak width. Moreover, finite-difference time-domain (FDTD) was used to simulate the optical properties and electric field distribution of HNPs. The calculated results show that the proportion of absorption cross section in total extinction cross section increases with the improvement of Au content in HNP. As predicted by the theoretical calculation results, Au-Ag@Au nanocages (NCs) exhibit a photothermal transduction efficiency (η) as high as 36.5% at 808 nm, which is higher than that of Au-Ag NCs (31.2%). Irradiated by 808 nm laser at power densities of 1 W/cm(2), MCF-7 breast cancer cells incubated with PEGylated Au-Ag@Au NCs were seriously destroyed. Combined together, Au-Ag@Au HNPs with enhanced chemical stability and improved photothermal transduction efficiency show superior competitiveness as photothermal agents.

  18. Solid phase metallurgy strategy to sub-5 nm Au-Pd and Ni-Pd bimetallic nanoparticles with controlled redox properties.

    Science.gov (United States)

    Tang, Yu; Xu, Shaodan; Dai, Yihu; Yan, Xiaoqing; Li, Renhong; Xiao, Liping; Fan, Jie

    2014-01-07

    A solid phase metallurgy strategy is applied to synthesize Au-Pd and Ni-Pd bimetallic nanoparticles (BMNPs) with a tight sub-5 nm particle size distribution. The near-surface elemental composition and redox properties of Au-Pd BMNPs can be well tailored, which leads to an optimized catalytic performance in n-hexane combustion.

  19. Cation coordination reactions on nanocrystals: surface/interface, doping control and advanced photocatalysis applications (Conference Presentation)

    Science.gov (United States)

    Zhang, Jiatao

    2016-10-01

    Abstract: Including the shape and size effect, the controllable doping, hetero-composite and surface/interface are the prerequisite of colloidal nanocrystals for exploring their optoelectronic properties, such as fluorescence, plasmon-exciton coupling, efficient electron/hole separation, and enhanced photocatalysis applications. By controlling soft acid-base coordination reactions between cation molecular complexes and colloidal nanocrystals, we showed that chemical thermodynamics could drive nanoscale monocrystalline growth of the semiconductor shell on metal nano-substrates and the substitutional heterovalent doping in semiconductor nanocrystals. We have demonstrated evolution of relative position of Au and II-VI semiconductor in Au-Semi from symmetric to asymmetric configuration, different phosphines initiated morphology engineering, oriented attachment of quantum dots into micrometer nanosheets with synergistic control of surface/interface and doing, which can further lead to fine tuning of plasmon-exciton coupling. Therefore, different hydrogen photocatalytic performance, Plasmon enhanced photocatalysis properties have been achieved further which lead to the fine tuning of plasmon-exciton coupling. Substitutional heterovalent doping here enables the tailoring of optical, electronic properties and photocatalysis applications of semiconductor nanocrystals because of electronic impurities (p-, n-type doping) control. References: (1) J. Gui, J. Zhang*, et al. Angew. Chem. Int. Ed. 2015, 54, 3683. (2) Q. Zhao, J. Zhang*, etc., Adv. Mater. 2014, 26, 1387. (3) J. Liu, Q. Zhao, S. G. Wang*, J. Zhang*, etc., Adv. Mater. 2015, 27-2753-2761. (4) H. Qian, J. Zhang*, etc., NPG Asia Mater. (2015) 7, e152. (5) M. Ji, M. Xu, etc., J. Zhang*, Adv. Mater. 2016, in proof. (6) S. Yu, J. T. Zhang, Y. Tang, M. Ouyang*, Nano Lett. 2015, 15, 6282-6288. (7) J. Zhang, Y. Tang, K. Lee and M. Ouyang*, Science 2010, 327, 1634. (8) J. Zhang, Y. Tang, K. Lee, M. Ouyang*, Nature 2010, 466

  20. Various applications of Active Field Control (AFC)

    Science.gov (United States)

    Watanabe, Takayuki; Miyazaki, Hideo; Kishinaga, Shinji; Kawakami, Fukushi

    2003-10-01

    AFC is an electro-acoustic enhancement system, which has been under development at Yamaha Corporation. In this paper, several types of various AFC applications are discussed, while referring to representative projects for each application in Japan. (1) Realization of acoustics in a huge hall to classical music program, e.g., Tokyo International Forum. This venue is a multipurpose hall with approximately 5000 seats. AFC achieves loudness and reverberance equivalent to those of a hall with 2500 seats or fewer. (2) Optimization of acoustics for a variety of programs, e.g., Arkas Sasebo. AFC is used to create the optimum acoustics for each program, such as reverberance for classical concerts, acoustical support for opera singers, uniformity throughout the hall from the stage to under-balcony area, etc. (3) Control of room shape acoustical effect, e.g., Osaka Central Public Hall: In this renovation project, preservation of historically important architecture in the original form is required. AFC is installed to vary only the acoustical environment without architectural changes. (4) Assistance with crowd enthusiasm for sports entertainment, e.g., Tokyo Metropolitan Gymnasium. In this venue, which is designed as a very absorptive space for speech intelligibility, AFC is installed to enhance the atmosphere of live sports entertainment.

  1. Transport de particules massives dans un fluide turbulent: Application a l'erosion due au sable sur les parois d'une turbine hydraulique

    Science.gov (United States)

    Bergeron, Stephen

    Le transport de particules massives par un champ turbulent est un vaste domaine de la mécanique des fluides. Il possède de nombreuses applications comme par exemple le transport de sable dans une turbine hydraulique. En raison de la dureté des grains de quartz et des grandes vitesses de collision avec les parois métalliques, un phénomène d'érosion intensif se produit. Les dommages résultants peuvent diminuer le rendement de la turbine au cours des quelques mois suivant la mise en opération. L'objectif de cette thèse est de mettre au point un outil permettant de prédire ces zones d'érosion. Ce projet de recherche en contexte industriel a été réalisé en collaboration avec la compagnie General Electric Hydro du Canada. Dans un régime hautement turbulent, il est possible d'obtenir une expression suffisamment générale en utilisant une formulation partiellement empirique: l'équation de Basset- Boussinesq-Oseen modifiée. Ce choix de modèle tient compte du niveau de précision recherché et de la méthode numérique employée afin de résoudre la phase fluide. Il permet aussi d'éliminer plusieurs ambiguïtés fréquemment rencontrées dans la littérature et implementées dans certains codes commerciaux courants. La formulation mathématique du problème est effectuée dans un espace mixte Euler-Lagrange. Les paramètres dynamiques sont relies au type de particules et à l'intensité de la turbulence. Le code numérique résultant est le plus performant développé à ce jour (août 1998). Les trajectoires de plusieurs centaines de milliers de particules peuvent être simulées et visualisées de manière interactive sur une station de travail (SGI R4K, R8K et R10K). L'utilisateur du logiciel est libre de se déplacer dans l'espace à l'aide d'un environnement similaire a un ``simulateur de vol''. Il peut ainsi analyser les détails du processus d'érosion de même que l'écoulement du fluide dans la turbine. Les zones d'érosion obtenues à l

  2. Using Variable Speed Control on Pump Application

    Directory of Open Access Journals (Sweden)

    Dr.Sc. Aida Spahiu

    2012-06-01

    Full Text Available Pumps are one of the most common variable speed drive (VSD system applications and special interest has focused on improving their energy efficiency by using variable speed control instead of throttling or other less efficient flow control methods. Pumps are the single largest user of electricity in industry in the European Union, consuming 160 TWh per annum of electricity and accounting for 79 million tonnes of carbon dioxide (CO2 emissions [1]. Centrifugal pumps are the most likely pump style to provide a favorable return based on energy savings when applied with a variable speed drive. To help illustrate this, are conducted benchmark testing to document various head and flow scenarios and their corresponding effect on energy savings. Paper shows the relationship of static and friction head in the energy efficiency equation and the effect of motor, pump and VSD efficiencies. The received results are good reference points for engineers and managers of water sector in Albania to select the best prospects for maximizing efficiency and energy savings.

  3. IDCDACS: IDC's Distributed Application Control System

    Science.gov (United States)

    Ertl, Martin; Boresch, Alexander; Kianička, Ján; Sudakov, Alexander; Tomuta, Elena

    2015-04-01

    The Preparatory Commission for the CTBTO is an international organization based in Vienna, Austria. Its mission is to establish a global verification regime to monitor compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT), which bans all nuclear explosions. For this purpose time series data from a global network of seismic, hydro-acoustic and infrasound (SHI) sensors are transmitted to the International Data Centre (IDC) in Vienna in near-real-time, where it is processed to locate events that may be nuclear explosions. We newly designed the distributed application control system that glues together the various components of the automatic waveform data processing system at the IDC (IDCDACS). Our highly-scalable solution preserves the existing architecture of the IDC processing system that proved successful over many years of operational use, but replaces proprietary components with open-source solutions and custom developed software. Existing code was refactored and extended to obtain a reusable software framework that is flexibly adaptable to different types of processing workflows. Automatic data processing is organized in series of self-contained processing steps, each series being referred to as a processing pipeline. Pipelines process data by time intervals, i.e. the time-series data received from monitoring stations is organized in segments based on the time when the data was recorded. So-called data monitor applications queue the data for processing in each pipeline based on specific conditions, e.g. data availability, elapsed time or completion states of preceding processing pipelines. IDCDACS consists of a configurable number of distributed monitoring and controlling processes, a message broker and a relational database. All processes communicate through message queues hosted on the message broker. Persistent state information is stored in the database. A configurable processing controller instantiates and monitors all data processing

  4. Mechano-optic logic gate controlled by third-order nonlinear optical properties in a rotating ZnO:Au thin film

    Science.gov (United States)

    Carrillo-Delgado, C.; García-Gil, C. I.; Trejo-Valdez, M.; Torres-Torres, C.; García-Merino, J. A.; Martínez-Gutiérrez, H.; Khomenko, A. V.; Torres-Martínez, R.

    2016-01-01

    Measurements of the third-order nonlinear optical properties exhibited by a ZnO thin solid film deposited on a SnO2 substrate are presented. The samples were prepared by a spray pyrolysis processing route. Scanning electron microscopy analysis and UV-Vis spectroscopy studies were carried out. The picosecond response at 1064 nm was explored by the z-scan technique. A large optical Kerr effect with two-photon absorption was obtained. The inhibition of the nonlinear optical absorption together with a noticeable enhancement in the optical Kerr effect in the sample was achieved by the incorporation of Au nanoparticles into the ZnO film. Additionally, a two-wave mixing configuration at 532 nm was performed and an optical Kerr effect was identified as the main cause of the nanosecond third-order optical nonlinearity. The relaxation time of the photothermal response of the sample was estimated to be about 1 s when the sample was excited by nanosecond single-shots. The rotation of the sample during the nanosecond two-wave mixing experiments was analyzed. It was stated that a non-monotonic relation between rotating frequency and pulse repetition rate governs the thermal contribution to the nonlinear refractive index exhibited by a rotating film. Potential applications for switching photothermal interactions in rotating samples can be contemplated. A rotary logic system dependent on Kerr transmittance in a two-wave mixing experiment was proposed.

  5. One-step synthesis of graphene-AuNPs by HMTA and the electrocatalytical application for O2 and H2O2.

    Science.gov (United States)

    Hu, Jianguo; Li, Fenghua; Wang, Kaikai; Han, Dongxue; Zhang, Qixian; Yuan, Junhua; Niu, Li

    2012-05-15

    A green, one-step method for synthesis of graphene-Au nanoparticles (graphene-AuNPs) was introduced in this article, using an environmentally benign hexamethylenetetramine (HMTA) as reducing and stabilizing agent. HMTA slowly was hydrolyzed to generate aldehyde ammonia to reduce graphene oxides (GO) and hydrogen tetrachloroaurate (Au precursor). The structure and composition of the graphene-AuNPs nanocomposites were studied by means of ultraviolet visible (UV) absorption spectra, X-ray photoelectron spectroscopy (XPS) and Transmission electron microscopy (TEM). The AuNPs are well-dispersed on graphene nanosheets in narrow size range. The nanocomposites have excellent electrocatalytical properties for catalytic reduction of O(2) and H(2)O(2).

  6. 75 FR 22844 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-04-30

    ... Technologies, 72 FR 3417 (2007), comments and requests for hearings on applications to import narcotic raw... 23, 1975, (40 FR 43745), all applicants for registration to import a basic class of any controlled... Enforcement Administration Importer of Controlled Substances; Notice of Application This is notice that...

  7. Engineering Gold Nanorod-Based Plasmonic Nanocrystals for Optical Applications

    KAUST Repository

    Huang, Jianfeng

    2015-09-01

    Plasmonic nanocrystals have a unique ability to support localized surface plasmon resonances and exhibit rich and intriguing optical properties. Engineering plasmonic nanocrystals can maximize their potentials for specific applications. In this dissertation, we developed three unprecedented Au nanorod-based plasmonic nanocrystals through rational design of the crystal shape and/or composition, and successfully demonstrated their applications in light condensation, photothermal conversion, and surface-enhanced Raman spectroscopy (SERS). The “Au nanorod-Au nanosphere dimer” nanocrystal was synthesized via the ligand-induced asymmetric growth of a Au nanosphere on a Au nanorod. This dimeric nanostructure features an extraordinary broadband optical absorption in the range of 400‒1400nm, and it proved to be an ideal black-body material for light condensation and an efficient solar-light harvester for photothermal conversion. The “Au nanorod (core) @ AuAg alloy (shell)” nanocrystal was built through the epitaxial growth of homogeneously alloyed AuAg shells on Au nanorods by precisely controlled synthesis. The resulting core-shell structured, bimetallic nanorods integrate the merits of the AuAg alloy with the advantages of anisotropic nanorods, exhibiting strong, stable and tunable surface plasmon resonances that are essential for SERS applications in a corrosive environment. The “high-index faceted Au nanorod (core) @ AuPd alloy (shell)” nanocrystal was produced via site-specific epitaxial growth of AuPd alloyed horns at the ends of Au nanorods. The AuPd alloyed horns are bound with high-index side facets, while the Au nanorod concentrates an intensive electric field at each end. This unique configuration unites highly active catalytic sites with strong SERS sites into a single entity and was demonstrated to be ideal for in situ monitoring of Pd-catalyzed reactions by SERS. The synthetic strategies developed here are promising towards the fabrication of

  8. The Research and Application of Prediction Control in Multi-variable Control Process

    Institute of Scientific and Technical Information of China (English)

    WEI Shuangying

    2006-01-01

    The modern industrial control objects become more and more complicated, and higher control quality is required, so a series of new control strategies appear, applied, modified and develop quickly. This paper researches a new control strategy-prediction control-and its application in Multi-Variable Control Process. The research result is worthy for automatic control in process industry.

  9. Light-controlled synthesis of gold nanoparticles using a rigid, photoresponsive surfactant

    Science.gov (United States)

    Huang, Youju; Kim, Dong-Hwan

    2012-09-01

    We report a new strategy for shape control over the synthesis of gold nanoparticles (AuNPs) by using a photoresponsive surfactant based on a modified seed growth method. Owing to photoresponsive properties of the azo group, the designed surfactant, N1,N3,N5-tris[(4'-azobenzene-4-sulphonic acid)phenyl]benzene-1,3,5-tricarboxamide, exhibits a distinctive molecular configuration under light leading to different growth processes of AuNPs. As a result, the blackberry-like, spherical AuNPs and multilayered Au plates were successfully prepared in high yield under visible and UV light. The size and morphological control of Au nanocrystals are described and the synthesized Au nanocrystals are evaluated for SERS applications.We report a new strategy for shape control over the synthesis of gold nanoparticles (AuNPs) by using a photoresponsive surfactant based on a modified seed growth method. Owing to photoresponsive properties of the azo group, the designed surfactant, N1,N3,N5-tris[(4'-azobenzene-4-sulphonic acid)phenyl]benzene-1,3,5-tricarboxamide, exhibits a distinctive molecular configuration under light leading to different growth processes of AuNPs. As a result, the blackberry-like, spherical AuNPs and multilayered Au plates were successfully prepared in high yield under visible and UV light. The size and morphological control of Au nanocrystals are described and the synthesized Au nanocrystals are evaluated for SERS applications. Electronic supplementary information (ESI) available: The UV-vis spectra, representative field-emission scanning electron microscopy (FESEM) images and size distributions of Au seeds (18 nm) and spherical AuNPs (50 nm), photograph images of AuNPs solution and TEM images of blackberry-like AuNPs. See DOI: 10.1039/c2nr31717f

  10. Au pair trajectories

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    and dreams for the future become intertwined with their financial possibilities, limitations and responsibilities. The following three articles employ the notion of relatedness to explore the transnational and local social networks, including family relations, of which the au pairs are part. Arguing...... that Filipina au pairs see their stay abroad as an avenue of personal development and social recognition, I examine how the au pairs re-position themselves within their families at home through migration, and how they navigate between the often conflicting expectations of participation in the sociality...... important remittances back home. Their time in Denmark is also often part of long-term migration trajectories involving future stays in Scandinavia and southern Europe. Based on ten months of fieldwork among current and former au pairs in Denmark and ten weeks of fieldwork among prospective au pairs and au...

  11. Robot Control System based on Web Application and RFID Technology

    Directory of Open Access Journals (Sweden)

    Barenji Ali Vatankhah

    2015-01-01

    Full Text Available This paper discusses an integration driven framework for enabling the RFID based identification of parts to perform robotic distributor operations in the random mix based parts control based on web application. The RFID technology senses newly arriving parts to be distribution robot, the robot is able to recognize them and perform cooperative distributing via web-based application. The developed web application control system is implemented in the educational robotic arm. RFID system sends real time information from parts to the web application and web based application makes a decision for control of the robot arm, controller of robot controls the robot as based on the decision from web application. The proposed control system has increases the reconfiguration and scalability of robot system.

  12. Application framework for programmable network control

    NARCIS (Netherlands)

    Strijkers, R.; Cristea, M.; de Laat, C.; Meijer, R.; Clemm, A.; Wolter, R.

    2011-01-01

    We present a framework that enables application developers to create complex and application specific network services. The essence of our approach is to utilize programmable network elements to create a software representation of network elements in the application. We show that the typical pattern

  13. Applicator Training Manual for: Aquatic Weed Control.

    Science.gov (United States)

    Herron, James W.

    The aquatic weeds discussed in this manual include algae, floating weeds, emersed weeds, and submerged weeds. Specific requirements for pesticide application are given for static water, limited flow, and moving water situations. Secondary effects of improper application rates and faulty application are described. Finally, techniques of limited…

  14. Modelisation et commande des redresseurs triphases fonctionnant a haut rendement et a faible taux de distorsion harmonique: Application au redresseur triphase de vienne

    Science.gov (United States)

    Belhadj Youssef, Nesrine

    Les problemes de la qualite de l'onde electrique constituent l'une des preoccupations majeures des fournisseurs de l'energie et des organismes specialises en qualite d'energie. Ce sujet a gagne davantage d'ampleur avec l'utilisation ascendante des convertisseurs de l'energie electrique dans la majorite des applications industrielles et domestiques. Dans le cadre de cette these, on s'interesse plus particulierement au type des convertisseurs alternatif/continu, dont le fonctionnement adequat implique la parfaite regulation du bus DC de tension, l'attenuation des harmoniques de courants, la compensation de l'energie reactive et la maximisation du rendement energetique. Ces differents criteres doivent etre maintenus pour diverses conditions de fonctionnement, c'est-a-dire independamment des variations parametriques auxquelles le systeme peut etre sujet. Il s'avere donc indispensable d'adopter des techniques de commande efficaces, ce qui passe par une modelisation correcte du convertisseur. L'optimisation du nombre de capteurs dans le circuit est egalement un facteur cle a prendre en consideration.

  15. Application of dimensional analysis in systems modeling and control design

    CERN Document Server

    Balaguer, Pedro

    2013-01-01

    Dimensional analysis is an engineering tool that is widely applied to numerous engineering problems, but has only recently been applied to control theory and problems such as identification and model reduction, robust control, adaptive control, and PID control. Application of Dimensional Analysis in Systems Modeling and Control Design provides an introduction to the fundamentals of dimensional analysis for control engineers, and shows how they can exploit the benefits of the technique to theoretical and practical control problems.

  16. Facile synthesis and intraparticle self-catalytic oxidation of dextran-coated hollow Au-Ag nanoshell and its application for chemo-thermotherapy.

    Science.gov (United States)

    Jang, Hongje; Kim, Young-Kwan; Huh, Hyun; Min, Dal-Hee

    2014-01-28

    Galvanic replacement reaction is a useful method to prepare various hollow nanostructures. We developed fast and facile preparation of biocompatible and structurally robust hollow Au-Ag nanostructures by using dextran-coated Ag nanoparticles. Oxidation of the surface dextran alcohols was enabled by catalytic activity of the core Au-Ag nanostructure, introducing carbonyl groups that are useful for further bioconjugation. Subsequent doxorubicin (Dox) conjugation via Schiff base formation was achieved, giving high payload of approximately 35 000 Dox per particle. Near-infrared-mediated photothermal conversion showed high efficacy of the Dox-loaded Au-Ag nanoshell as a combinational chemo-thermotherapy to treat cancer cells.

  17. Application of Improved Fuzzy Controller in Networked Control System

    Institute of Scientific and Technical Information of China (English)

    ZHANG Qian; GUO Xi-jin; WANG Zhen; TIAN Xi-lan

    2006-01-01

    Aiming at the problem of network-induced delay and data dropout in networked control system, an improved fuzzy controller is proposed in this paper. Considering the great influence of a controller on the performance of control system, an improved controller with a second order fuzzy controller and network-induced delay compensator being added to the basic fuzzy controller is proposed to realize self-regulation on-line. For this type of controller, neither plant model nor measurement of network delay is required. So it is capable of automatically adjusting quantified factor, proportional factor, and integral factor according to the control system error and its derivative. The design makes full use of the advantages of quickness in operation and reduction of steady state error because of its integral function. The controller has a good control effect on time-delay and can keep a better performance by self-regulation on-line in the network with data dropout and interference. It is good in quickness, adaptability, and robustness, which is favorable for controlling the long time-delay system.

  18. AN APPLICATION OF OPTIMAL CONTROL THEORY.

    Science.gov (United States)

    The purpose of this article is to show that optimal control theory can be used to develop a control strategy for a practical system, namely a distillation column. The approach will be to model the complex system with a simple model, use optimal control theory to determine a control strategy for the simple model, and then apply the results to the original system. (Author)

  19. Fuzzy Logic Controller for Low Temperature Application

    Science.gov (United States)

    Hahn, Inseob; Gonzalez, A.; Barmatz, M.

    1996-01-01

    The most common temperature controller used in low temperature experiments is the proportional-integral-derivative (PID) controller due to its simplicity and robustness. However, the performance of temperature regulation using the PID controller depends on initial parameter setup, which often requires operator's expert knowledge on the system. In this paper, we present a computer-assisted temperature controller based on the well known.

  20. Nonlinear Robust Control Theory and Applications

    Science.gov (United States)

    1997-01-18

    IEEE Transactions on Automatic Control , pp. 228-238...34Robustness in the presence of mixed parametric uncertainty and unmodelled dynamics," IEEE Transactions on Automatic Control , pp. 25-38, 1991. 8 [10...Letter, 1994. [14] B. Moore, "Principal component analysis of linear systems: Controllability, observ- ability and model reduction," IEEE Transactions on Automatic Control ,

  1. Theory, Methods, and Applications of Nonlinear Control

    Science.gov (United States)

    2012-08-29

    IEEE Transactions on Automatic Control , Volume...tracking control using input-to-state stability,” IEEE Transactions on Automatic Control , Volume 57, Number 5, May 2012, pp. 1320-1326. [MZ12a... Transactions on Automatic Control , Volume 55, Number 4, April 2010, pp. 841-854. 4 [MM10b] Mazenc, F., and M. Malisoff, “Stabilization of

  2. Ionic liquid assisted synthesis of nano Pd-Au particles and application for the detection of epinephrine, dopamine and uric acid

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, Tsung-Hsuan; Thiagarajan, Soundappan; Chen Shenming, E-mail: smchen78@ms15.hinet.net; Cheng Chingyi

    2012-01-31

    Nano Pd-Au particles have been electrochemically fabricated utilizing ionic liquid as green electrolyte (1-Butyl-3-methylimidazolium tetrafluoroborate). Nano Pd-Au particles modified glassy carbon electrode (GCE) and indium tin oxide coated glass electrodes were examined using atomic force microscopy, field emission scanning electron microscope and X-ray diffraction studies. Electrodeposited nano Pd-Au particles' average diameter was found as 33 nm. Nano Pd-Au particle modified GCE was electrochemically active and stable in various pH solutions. The proposed nano particle modified GCE reduces the over potential and shows the well defined oxidation peaks for the detection of epinephrine and simultaneous determination of dopamine and uric acid (in pH 7.0 phosphate buffer solution) using cyclic voltammetry and differential pulse voltammetry.

  3. Au-Loaded Titanium Dioxide Nanoparticles Synthesized by Modified Sol-Gel/Impregnation Methods and Their Application to Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Hathaithip Ninsonti

    2014-01-01

    Full Text Available Au-loaded TiO2 nanoparticles were synthesized by the modified sol-gel method together with the impregnation method. Anatase phase of TiO2 was obtained in all samples with an average particle size of 20 nm. For the enhancement of DSSCs, the dye-sensitized solar cells composed of the ITO/Au-loaded TiO2/N-719/electrolyte/Pt were fabricated. Au-loaded TiO2 films were deposited by using squeegee method. Finally, the fabricated cells were studied upon an irradiation of solar light to study the performance. The fabricated cell with up to 1.0 mol% Au-loaded TiO2 could enhance the performance by localized surface plasmon effect and scattering property.

  4. Adaptive Sampling for WSAN Control Applications Using Artificial Neural Networks

    OpenAIRE

    2012-01-01

    Wireless sensor actuator networks are becoming a solution for control applications. Reliable data transmission and real time constraints are the most significant challenges. Control applications will have some Quality of Service (QoS) requirements from the sensor network, such as minimum delay and guaranteed delivery of packets. We investigate variable sampling method to mitigate the effects of time delays in wireless networked control systems using an observer based control system model. Our...

  5. Finite Set Control Transcription for Optimal Control Applications

    Science.gov (United States)

    2009-05-01

    local eigenstructure of the linear system. Along with Hsiao,46 they developed a stabilizing control law intended for a low-thrust ion engine. Gurfil...asymptotically stabilizing control to track to an arbitrary trajectory from any epoch position and velocity. Of course, when the epoch values are along the...propul- sion suite like this, a spacecraft attitude can be in any orientation and still implement a stabilizing control law. Unfortunately, it may not be

  6. A study on the effect of low energy ion beam irradiation on Au/TiO2 system for its application in photoelectrochemical splitting of water

    Science.gov (United States)

    Verma, Anuradha; Srivastav, Anupam; Sharma, Dipika; Banerjee, Anamika; Sharma, Shailja; Satsangi, Vibha Rani; Shrivastav, Rohit; Avasthi, Devesh Kumar; Dass, Sahab

    2016-07-01

    Nanostructured TiO2 thin films were deposited on indium tin oxide (ITO) substrate via sol-gel technique and were modified by plasmonic Au layer. The plasmonic Au modified TiO2 (Au/TiO2) thin films were then irradiated with 500 keV Ar2+ ion beam at different ion fluences viz. 1 × 1016, 3 × 1016 and 1 × 1017 to study the effect of nuclear energy deposition on the morphology, crystallinity, band gap, surface plasmon resonance (SPR) peak exhibited by Au particles and photoelectrochemical properties of the system. Prepared thin films were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM), Rutherford backscattering spectrometry (RBS) measurements and UV-visible spectroscopy. The photoelectrochemical measurements revealed that both Au/TiO2 and Au/TiO2 thin film irradiated at 1 × 1016 fluence exhibits enhanced photoelectrochemical response in comparison to pristine TiO2. The film irradiated at 1 × 1016 fluence offered maximum applied bias photon-to-current efficiency (ABPE) and shows 6 times increment in photocurrent density which was attributed to more negative flat band potential, maximum decrease in band gap, high open circuit voltage (Voc) and reduced charge transfer resistance.

  7. A study on the effect of low energy ion beam irradiation on Au/TiO{sub 2} system for its application in photoelectrochemical splitting of water

    Energy Technology Data Exchange (ETDEWEB)

    Verma, Anuradha; Srivastav, Anupam; Sharma, Dipika; Banerjee, Anamika; Sharma, Shailja [Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra 282005 (India); Satsangi, Vibha Rani [Department of Physics & Computer Science, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra 282005 (India); Shrivastav, Rohit [Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra 282005 (India); Avasthi, Devesh Kumar [Inter University Accelerator Centre, P.O. Box 10502, New Delhi 110067 (India); Amity University, Noida-201313, Uttar Pradesh (India); Dass, Sahab, E-mail: drsahabdas@gmail.com [Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra 282005 (India)

    2016-07-15

    Nanostructured TiO{sub 2} thin films were deposited on indium tin oxide (ITO) substrate via sol–gel technique and were modified by plasmonic Au layer. The plasmonic Au modified TiO{sub 2} (Au/TiO{sub 2}) thin films were then irradiated with 500 keV Ar{sup 2+} ion beam at different ion fluences viz. 1 × 10{sup 16}, 3 × 10{sup 16} and 1 × 10{sup 17} to study the effect of nuclear energy deposition on the morphology, crystallinity, band gap, surface plasmon resonance (SPR) peak exhibited by Au particles and photoelectrochemical properties of the system. Prepared thin films were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM), Rutherford backscattering spectrometry (RBS) measurements and UV–visible spectroscopy. The photoelectrochemical measurements revealed that both Au/TiO{sub 2} and Au/TiO{sub 2} thin film irradiated at 1 × 10{sup 16} fluence exhibits enhanced photoelectrochemical response in comparison to pristine TiO{sub 2}. The film irradiated at 1 × 10{sup 16} fluence offered maximum applied bias photon-to-current efficiency (ABPE) and shows 6 times increment in photocurrent density which was attributed to more negative flat band potential, maximum decrease in band gap, high open circuit voltage (V{sub oc}) and reduced charge transfer resistance.

  8. Photonic gene circuits by optically addressable siRNA-Au nanoantennas.

    Science.gov (United States)

    Lee, Somin Eunice; Sasaki, Darryl Y; Park, Younggeun; Xu, Ren; Brennan, James S; Bissell, Mina J; Lee, Luke P

    2012-09-25

    The precise perturbation of gene circuits and the direct observation of signaling pathways in living cells are essential for both fundamental biology and translational medicine. Current optogenetic technology offers a new paradigm of optical control for cells; however, this technology relies on permanent genomic modifications with light-responsive genes, thus limiting dynamic reconfiguration of gene circuits. Here, we report precise control of perturbation and reconfiguration of gene circuits in living cells by optically addressable siRNA-Au nanoantennas. The siRNA-Au nanoantennas fulfill dual functions as selectively addressable optical receivers and biomolecular emitters of small interfering RNA (siRNA). Using siRNA-Au nanoantennas as optical inputs to existing circuit connections, photonic gene circuits are constructed in living cells. We show that photonic gene circuits are modular, enabling subcircuits to be combined on-demand. Photonic gene circuits open new avenues for engineering functional gene circuits useful for fundamental bioscience, bioengineering, and medical applications.

  9. High Level Control Applications for SOLEIL Commissioning and Operation

    CERN Document Server

    Nadolski, Laurent S; Ho, Katy; Leclercq, Nicolas; Ounsy, Majid; Petit, Sylvain

    2005-01-01

    The SOLEIL control system, namely TANGO developed in collaboration with ESRF, is now mature and stable. TANGO has also been chosen now by several other laboratories. High-level control applications implemented in the control room for the storage ring, the two transfer lines, and the booster will be described in this paper. Three kinds of tools for commissioning are used. First the generic TANGO tools (alarms, simple graphical control applications), which allow us to control in a simple way any TANGO Device Server. Secondly a Matlab Middle Layer (adapted from ALS and SPEAR3): Matlab is fully interconnected with TANGO; it is used primarily for writing Physics control applications. Finally Globalscreen, a commercial SCADA software devoted for building operation applications has been selected (panels for controlling or displaying setpoint, readback values, status of equipments). In addition an overview of the historical and short-term databases for the accelerators will be given. They have been developed in house...

  10. Application of generalized predictive control in networked control system

    Institute of Scientific and Technical Information of China (English)

    YANG Can; ZHU Sha-nan; KONG Wan-zeng; LU Li-ming

    2006-01-01

    A new framework for networked control system based on Generalized Predictive Control (GPC) is proposed in this paper. Clock-driven sensors, event-driven controller, and clock-driven actuators are required in this framework. A queuing strategy is proposed to overcome the network induced delay. Without redesigning, the proposed framework enables the existing GPC controller to be used in a network environment. It also does not require clock synchronization and is only slightly affected by bad network condition such as package loss. Various experiments are designed over the real network to test the proposed approach,which verify that the proposed approach can stabilize the Networked Control System (NCS) and is robust.

  11. DC Hierarchical Control System for Microgrid Applications

    OpenAIRE

    Lu, Xiaonan; Sun, Kai; Guerrero, Josep M.; Huang, Lipei

    2013-01-01

    In order to enhance the DC side performance of AC-DC hybrid microgrid,a DC hierarchical control system is proposed in this paper.To meet the requirement of DC load sharing between the parallel power interfaces,droop method is adopted.Meanwhile,DC voltage secondary control is employed to restore the deviation in the DC bus voltage.The hierarchical control system is composed of two levels.DC voltage and AC current controllers are achieved in the primary control level.

  12. 76 FR 42731 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-07-19

    ... notice published in the Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... importer of the following basic classes of controlled substances: Drug Schedule Methaqualone (2565)...

  13. 75 FR 160 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-01-04

    ... Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for registration to import a... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... be registered as an importer of the basic classes of controlled substances listed in schedule...

  14. 76 FR 81978 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-12-29

    ... Federal Register on September 23, 1975, ] 40 FR 43745-46, all applicants for registration to import a... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of the following basic classes of controlled...

  15. 75 FR 76755 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-12-09

    ... published in the Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for registration... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of the basic classes of controlled substances listed...

  16. 75 FR 36684 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-28

    ... notice published in the Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... (DEA) to be registered as an importer of the basic classes of controlled substances listed in...

  17. 76 FR 30969 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-05-27

    ... Register on September 23, 1975, (40 FR 43745), all applicants for registration to import a basic class of... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... importer of Remifentanil (9739), a basic class of controlled substance listed in schedule II. The...

  18. 77 FR 16262 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-03-20

    ... notice published in the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958...) to be registered as an importer of Fentanyl (9801), a basic class of controlled substance listed...

  19. 75 FR 65660 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-10-26

    ... the Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for registration to... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... as an importer of the basic classes of controlled substances listed in schedule II: Drug...

  20. 77 FR 21998 - Importer of Controlled Substances: Notice of Application

    Science.gov (United States)

    2012-04-12

    ... notice published in the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for... Enforcement Administration Importer of Controlled Substances: Notice of Application Pursuant to 21 U.S.C. 958...) to be registered as an importer of Nabilone (7379), a basic class of controlled substance listed...

  1. 75 FR 64744 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-10-20

    ... notice published in the Federal Register on September 23, 1975, (40 FR 43745), all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... (DEA) to be registered as an importer of Remifentanil (9739), a basic class of controlled...

  2. 76 FR 30968 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-05-27

    ... notice published in the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of the following basic classes of controlled...

  3. 76 FR 42732 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-07-19

    ... Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for registration to import a basic... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of the following basic classes of controlled...

  4. Controlling noncovalent interactions between a lysine-rich α-helical peptide and self-assembled monolayers of alkanethiols on Au through functional group diversity

    Science.gov (United States)

    Raigoza, Annette F.; Onyirioha, Kristeen; Webb, Lauren J.

    2017-02-01

    Reliably attaching a structured biomolecule to an inorganic substrate would enable the preparation of surfaces that incorporate both biological and inorganic functions and structures. To this end, we have previously developed a procedure using the copper(I)-catalyzed click reaction to tether synthetic α-helical peptides carrying two alkyne groups to well-ordered alkanethiol self-assembled monolayers (SAM) on a Au(111) surface, in which the SAM is composed of a mixture of methyl and azide termination. Proteins, however, are composed of many diverse functional groups, and this composition directly effects protein structure, interactions, and reactivity. Here, we explore the utility of mixed SAMs with alternative terminating functional groups to tune and direct the reactivity of the surface through noncovalent peptide-surface interactions. We study both polar surfaces (OH-terminated) and charged surfaces (COOH- and NH3-terminated, which are negatively and positively charged, respectively, under our reaction conditions). Surfaces were functionalized with a bipolar peptide composed of Lys and Leu residues that could express different interactions through either hydrophilic and/or charge (Lys) or hydrophobic (Leu) influences. X-ray photoelectron spectroscopy (XPS) and surface infrared spectroscopy were used to characterize surfaces at all stages of the peptide functionalization procedure. This strategy resulted in a high density of surface-bound α-helices without aggregation. Mixed SAMs that included a positively charged alkanethiol along with the azide-terminated thiol resulted in a more efficient reaction and better alignment of the peptide with the azide on the surface. Negatively charged surfaces increased physisorption of the peptide, which was then removed during sample rinsing. This work demonstrates that varying easily controlled chemical inputs during the functionalization steps allows the reaction conditions to be balanced for the chemical needs of a

  5. Quelques applications du contrôle stochastique aux options réelles et au risque de liquidité.

    OpenAIRE

    Ly Vath, Vathana

    2006-01-01

    We study stochastic control applications to real options and to liquidity risk model. More precisely, we investigate, in the first part, a model of optimal portfolio selection under liquidity risk and price impact, then, in the second part, two real option problems: an optimal switching problem and a mixed singular/switching control problem for a dividend policy with reversible investment, and finally, in the third part, a competitive market equilibrium problem under asymmetric information. I...

  6. 76 FR 25374 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-05-04

    ... of Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for... published in the Federal Register on September 23, 1975, 40 FR 43745, all applicants for registration to... Enforcement Administration Importer of Controlled Substances; Notice of Application This is notice that...

  7. 77 FR 4831 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-01-31

    ..., and coca leaves. As explained in the Correction to Notice of Application pertaining to 72 FR 3417... the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for registration to import... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21...

  8. 75 FR 36680 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-28

    ... pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for hearings on applications to... Register on September 23, 1975, (40 FR 43745), all applicants for registration to import a basic class of... Enforcement Administration Importer of Controlled Substances; Notice of Application This is notice that...

  9. 76 FR 5827 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-02-02

    ... Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for hearings on... notice published in the Federal Register on September 23, 1975, (40 FR 43745), all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21...

  10. Application Oriented Programming and Control of Industrial Robots

    OpenAIRE

    Nilsson, Klas

    1992-01-01

    Efficient use of industrial robots requires a strong interplay between user level commands, the motion control system, and external equipment. It should also be possible for an experienced application engineer to tailor the motion control to a specific application in a convenient way, instead of deficient utilization of the device or tricky user programming which is often the case today. A layered software architecture has been designed based on an application oriented view, considering typic...

  11. Fuzzy multinomial control chart and its application

    Science.gov (United States)

    Wibawati, Mashuri, Muhammad; Purhadi, Irhamah

    2016-03-01

    Control chart is a technique that has been used widely in industry and services. P chart is the simplest control chart. In this chart, item is classified into two categories as either conforming and non conforming. This chart based on binomial distribution. In practice, each item can classify in more than two categories such as very bad, bad, good and very good. Then to monitor the process we used multinomial p control chart. However, if the classification is an element of vagueness, the fuzzy multinomial control chart (FM) is more appropriately used. Control limit of FM chart obtained multinomial distribution and the degree of membership using fuzzy trianguler are 0, 0.25. 0.5 and 1. This chart will be applied to the data glass and will compare with multinomial p control chart.

  12. Advanced thermal control for spacecraft applications

    Science.gov (United States)

    Hardesty, Robert; Parker, Kelsey

    2015-09-01

    In optical systems just like any other space borne system, thermal control plays an important role. In fact, most advanced designs are plagued with volume constraints that further complicate the thermal control challenges for even the most experienced systems engineers. Peregrine will present advances in satellite thermal control based upon passive heat transfer technologies to dissipate large thermal loads. This will address the use of 700 W/m K and higher conducting products that are five times better than aluminum on a specific basis providing enabling thermal control while maintaining structural support.

  13. Wireless Sensor/Actuator Network Design for Mobile Control Applications

    CERN Document Server

    Xia, Feng; Li, Yanjun; Sun, Youxian

    2008-01-01

    Wireless sensor/actuator networks (WSANs) are emerging as a new generation of sensor networks. Serving as the backbone of control applications, WSANs will enable an unprecedented degree of distributed and mobile control. However, the unreliability of wireless communications and the real-time requirements of control applications raise great challenges for WSAN design. With emphasis on the reliability issue, this paper presents an application-level design methodology for WSANs in mobile control applications. The solution is generic in that it is independent of the underlying platforms, environment, control system models, and controller design. To capture the link quality characteristics in terms of packet loss rate, experiments are conducted on a real WSAN system. From the experimental observations, a simple yet efficient method is proposed to deal with unpredictable packet loss on actuator nodes. Trace-based simulations give promising results, which demonstrate the effectiveness of the proposed approach.

  14. Bimetallic PtAu superlattice arrays: Highly electroactive and durable catalyst for oxygen reduction and methanol oxidation reactions

    Science.gov (United States)

    Feng, Jiu-Ju; He, Li-Li; Fang, Rui; Wang, Qiao-Li; Yuan, Junhua; Wang, Ai-Jun

    2016-10-01

    Superlattice arrays, an important type of nanomaterials, have wide applications in catalysis, optic/electronics and energy storage for the synergetic effects determined by both individual metals and collective interactions. Herein, a simple one-pot solvothermal coreduction approach is developed for facile preparation of bimetallic PtAu alloyed superlattice arrays (PtAu SLAs) in oleylamine, with the assistance of urea via hydrogen bonding induced self-assembly. Urea is essential in morphology-controlled process and prevents PtAu nanoparticles from the disordered aggregation. The characterization and formation mechanism of PtAu SLAs are investigated in details. The as-synthesized hybrid nanocrystals exhibit enhanced electrocatalytic performances for oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) in alkaline electrolyte in comparison with commercial Pt-C (50%, wt.%) and Pt black catalysts.

  15. Optimal control application to an Ebola model

    Institute of Scientific and Technical Information of China (English)

    Ebenezer Bonyah; Kingsley Badu; Samuel Kwesi Asiedu-Addo

    2016-01-01

    Ebola virus is a severe,frequently fatal illness,with a case fatality rate up to 90%.The outbreak of the disease has been acknowledged by World Health Organization as Public Health Emergency of International Concern.The threat of Ebola in West Africa is still a major setback to the socioeconomic development.Optimal control theory is applied to a system of ordinary differential equations which is modeling Ebola infection through three different routes including contact between humans and a dead body.In an attempt to reduce infection in susceptible population,a preventive control is put in the form of education and campaign and two treatment controls are applied to infected and late-stage infected(super) human population.The Pontryagins maximum principle is employed to characterize optimality control,which is then solved numerically.It is observed that time optimal control is existed in the model.The activation of each control showed a positive reduction of infection.The overall effect of activation of all the controls simultaneously reduced the effort required for the reduction of the infection quickly.The obtained results present a good framework for planning and designing cost-effective strategies for good interventions in dealing with Ebola disease.It is established that in order to reduce Ebola threat all the three controls must be taken into consideration concurrently.

  16. Application of neural networks to unsteady aerodynamic control

    Science.gov (United States)

    Faller, William E.; Schreck, Scott J.; Luttges, Marvin W.

    1994-01-01

    The problem under consideration in this viewgraph presentation is to understand, predict, and control the fluid mechanics of dynamic maneuvers, unsteady boundary layers, and vortex dominated flows. One solution is the application of neural networks demonstrating closed-loop control. Neural networks offer unique opportunities: simplify modeling of three dimensional, vortex dominated, unsteady separated flow fields; are effective means for controlling unsteady aerodynamics; and address integration of sensors, controllers, and time lags into adaptive control systems.

  17. Parametric control systems design with applications in missile control

    Institute of Scientific and Technical Information of China (English)

    DUAN GuangRen; YU HaiHua; TAN Feng

    2009-01-01

    This paper considers parametric control of high-order descriptor linear systems via proportional plus derivative feedback.By employing general parametric solutions to a type of so-called high-order Sylvester matrix equations,complete parametric control approaches for high-order linear systems are presented.The proposed approaches give simple complete parametric expressions for the feedback gains and the closed-loop eigenvector matrices,and produce all the design degrees of freedom.Furthermore,Important special cases are particularly treated.Based on the proposed parametric design approaches,a parametric method for the gain-scheduling controller design of a linear time-varying system is proposed and the design of a BTT missile autopilot is carried out.The simulation results show that the method is superior to the traditional one in sense of either global stability or system performance.

  18. Adaptive sliding mode control and its application in chaos control

    Directory of Open Access Journals (Sweden)

    Liqun Shen

    2014-12-01

    Full Text Available The sliding motion of sliding mode control system is studied in this paper. Using the measure concept, two new quantities about the sliding motion are introduced, and a new relationship about the sliding motion is derived with the new quantities. According to this relationship, an adaptive law of the magnitude of the controller’s switching part is proposed, which can minimize the chattering phenomenon according to the predefined robust margin. To verify the effectiveness of the proposed control scheme, it is applied to Rössler system with uncertain disturbances. Simulation results show that the proposed control method can stabilize Rössler system with the magnitude of the controller’s switching part adjusted adaptively with the disturbances.

  19. Electrophoretic deposition of fluorescent Cu and Au sheets for light-emitting diodes

    Science.gov (United States)

    Liu, Jiale; Wu, Zhennan; Li, Tingting; Zhou, Ding; Zhang, Kai; Sheng, Yu; Cui, Jianli; Zhang, Hao; Yang, Bai

    2015-12-01

    Electrophoretic deposition (EPD) is a conventional method for fabricating film materials from nanometer-sized building blocks, and exhibits the advantages of low-cost, high-efficiency, wide-range thickness adjustment, and uniform deposition. Inspired by the interest in the application of two-dimensional (2D) nanomaterials, the EPD technique has been recently extended to building blocks with 2D features. However, the studies are mainly focused on simplex building blocks. The utilization of multiplex building blocks is rarely reported. In this work, we demonstrate a controlled EPD of Cu and Au sheets, which are 2D assemblies of luminescent Cu and Au nanoclusters. Systematic investigations reveal that both the deposition efficiency and the thickness are determined by the lateral size of the sheets. For Cu sheets with a large lateral size, a high ζ-potential and strong face-to-face van der Waals interactions facilitate the deposition with high efficiency. However, for Au sheets, the small lateral size and ζ-potential limit the formation of a thick film. To solve this problem, the deposition dynamics are controlled by increasing the concentration of the Au sheets and adding acetone. This understanding permits the fabrication of a binary EPD film by the stepwise deposition of Cu and Au sheets, thus producing a luminescent film with both Cu green emission and Au red emission. A white light-emitting diode prototype with color coordinates (x, y) = (0.31, 0.36) is fabricated by employing the EPD film as a color conversion layer on a 365 nm GaN clip and further tuning the amount of deposited Cu and Au sheets.Electrophoretic deposition (EPD) is a conventional method for fabricating film materials from nanometer-sized building blocks, and exhibits the advantages of low-cost, high-efficiency, wide-range thickness adjustment, and uniform deposition. Inspired by the interest in the application of two-dimensional (2D) nanomaterials, the EPD technique has been recently extended to

  20. Unidirectional thermal diffusion in bimetallic Cu@Au nanoparticles.

    Science.gov (United States)

    Liu, Shoujie; Sun, Zhihu; Liu, Qinghua; Wu, Lihui; Huang, Yuanyuan; Yao, Tao; Zhang, Jing; Hu, Tiandou; Ge, Mengran; Hu, Fengchun; Xie, Zhi; Pan, Guoqiang; Wei, Shiqiang

    2014-02-25

    Understanding the atomic diffusions at the nanoscale is important for controlling the synthesis and utilization of nanomaterials. Here, using in situ X-ray absorption spectroscopy coupled with theoretical calculations, we demonstrate a so far unexplored unidirectional diffusion from the Au shell to the Cu core in thermally alloying Cu@Au core@shell architecture of ca. 7.1 nm. The initial diffusion step at 423 K is found to be characterized by the formation of a diffusion layer composed of a Au-dilute substitutional CuAu-like intermetallic compound with short Cu-Au bond length (2.61 Å). The diffusion further happens by the migration of the Au atoms with large disorder into the interior Cu matrix at higher temperatures (453 and 553 K). These results suggest that the structural preference of a CuAu-like compound, along with the nanosized effect, plays a critical role in determining the atomic diffusion dynamics.

  1. Recent advances in electrical engineering and control applications

    CERN Document Server

    Bououden, Sofiane; Zelinka, Ivan

    2017-01-01

    This book of proceedings includes papers presenting the state of art in electrical engineering and control theory as well as their applications. The topics focus on classical as well as modern methods for modeling, control, identification and simulation of complex systems with applications in science and engineering. The papers were selected from the hottest topic areas, such as control and systems engineering, renewable energy, faults diagnosis—faults tolerant control, large-scale systems, fractional order systems, unconventional algorithms in control engineering, signals and communications. The control and design of complex systems dynamics, analysis and modeling of its behavior and structure is vitally important in engineering, economics and in science generally science today. Examples of such systems can be seen in the world around us and are a part of our everyday life. Application of modern methods for control, electronics, signal processing and more can be found in our mobile phones, car engines, hom...

  2. Feedback linearization application for LLRF control system

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, S.; Regan, A.; Wang, Y.M.; Rohlev, T.

    1999-06-01

    The Low Energy Demonstration Accelerator (LEDA) being constructed at Los Alamos National Laboratory will serve as the prototype for the low energy section of Acceleration Production of Tritium (APT) accelerator. This paper addresses the problem of the LLRF control system for LEDA. The authors propose a control law which is based on exact feedback linearization coupled with gain scheduling which reduces the effect of the deterministic klystron cathode voltage ripple that is due to harmonics of the high voltage power supply and achieves tracking of desired set points. Also, they propose an estimator of the ripple and its time derivative and the estimates based feedback linearization controller.

  3. Feedback linearization application for LLRF control system

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, S.; Regan, A.; Wang, Y.M.; Rohlev, T.

    1998-12-31

    The Low Energy Demonstration Accelerator (LEDA) being constructed at Los Alamos National Laboratory will serve as the prototype for the low energy section of Acceleration Production of Tritium (APT) accelerator. This paper addresses the problem of the LLRF control system for LEDA. The authors propose a control law which is based on exact feedback linearization coupled with gain scheduling which reduces the effect of the deterministic klystron cathode voltage ripple that is due to harmonics of the high voltage power supply and achieves tracking of desired set points. Also, they propose an estimator of the ripple and its time derivative and the estimates based feedback linearization controller.

  4. Application study of complex control algorithm for regenerative furnace temperature

    Institute of Scientific and Technical Information of China (English)

    Lusheng GE

    2004-01-01

    Altemative switch combustion mode of air and gas is adopted on the two sides of the regenerative furnace, its temperature is in uncontrolled state in the switching process and the switch period is generally 3 ~ 5 min. Thus, the conventional bi-cross limited combustion control method is no longer applicable to the object. This paper makes use of neutral network algorithm to adjust the static operating point. On this basis, fuzzy control strategy is used for the furnace temperature control. The actual application result shows that the control strategy is effective to solve the problem of the combustion control for regenerative furnace.

  5. PC-Based Applications Programming on the SRS Control System.

    Science.gov (United States)

    Martlew, Brian; Owen, Hywel; Pugh, Martin; Rawlinson, Bill; Smith, Susan

    1997-05-01

    The CERN PC-based ISOLDE control system has been installed at the SRS electron storage ring at Daresbury Laboratory. The use of Windows NT for the control consoles together with PC and VME front-end computers running under several operating systems has resulted in a flexible and reliable system for accelerator control. The implementation and philosophy of control application programs, based around a suite of Microsoft Visual Basic and Excel programs, is described. In particular, the use of Excel to provide adaptable programs online allows rapid generation of new control functions; orbit correction and servoing at the application level are described as examples of this.

  6. In situ fabrication of ultrathin porous alumina and its application for nanopatterning Au nanocrystals on the surface of ion-sensitive field-effect transistors.

    Science.gov (United States)

    Kisner, A; Heggen, M; Fischer, W; Tillmann, K; Offenhäusser, A; Kubota, L T; Mourzina, Y

    2012-12-07

    In situ fabrication in a single step of thin films of alumina exhibiting a thickness of less than 100 nm and nanopores with a highly regular diameter distribution in order to pattern nanostructures over field-effect devices is a critical issue and has not previously been demonstrated. Here we report the fabrication in situ of 50 nm thick ultrathin nanoporous alumina membranes with a regular pore size directly over metal-free gate ion-sensitive field-effect transistors. Depositing thin films of aluminum by an electron beam at a relatively low rate of deposition on top of chips containing the transistors and using a conventional single-step anodization process permits the production of a well-adhering nanoporous ultrathin layer of alumina on the surface of the devices. The anodization process does not substantially affect the electrical properties of the transistors. The small thickness and pore size of ultrathin alumina membranes allow them to be sequentially employed as masks for patterning Au nanocrystals grown by an electroless approach directly on the top of the transistors. The patterning process using a wet chemical approach enables the size of the patterned crystals to be controlled not only by the dimensions of the pores of alumina, but also by the concentration of the reactants employed. Surface modification of these nanocrystals with alkanethiol molecules demonstrates that the electrostatic charge of the functional groups of the molecules can modulate the electrical characteristics of the transistors. These results represent substantial progress towards the development of novel nanostructured arrays on top of field-effect devices that can be applied for chemical sensing or non-volatile memories.

  7. Beyond arms control? Looking for the lost paradigm..; Au-dela de l'arms control? A la recherche du paradigme perdu..

    Energy Technology Data Exchange (ETDEWEB)

    Dahan, P

    2002-07-01

    Since the tragic events of September 11, 2001, the international relations have become more complex and the arms control concept, born during the cold war and implemented during the 3 last decades is today marking time. Disarmament and non-proliferation, which were the keystones of arms control and international negotiations, are today undergoing erosion. This article analyzes the change of situation between the end of the 20. century and the beginning of the 21. century. Three steps are defined by the author: a 'flux' step with the signature of a huge number of international agreements about non-proliferation and arms control, a stagnation step marked by the difficulties of implementing some of the existing treaties and by the violation by some states of some of them, and a 'reflux' step marked by a freezing up of the bilateral US-Russian disarmament process and a general renouncement of the multilateral arms control concept. (J.S.)

  8. Simplified microprocessor design for VLSI control applications

    Science.gov (United States)

    Cameron, K.

    1991-01-01

    A design technique for microprocessors combining the simplicity of reduced instruction set computers (RISC's) with the richer instruction sets of complex instruction set computers (CISC's) is presented. They utilize the pipelined instruction decode and datapaths common to RISC's. Instruction invariant data processing sequences which transparently support complex addressing modes permit the formulation of simple control circuitry. Compact implementations are possible since neither complicated controllers nor large register sets are required.

  9. Applicator Training Manual for: Forest Pest Control.

    Science.gov (United States)

    Newman, Jim

    Described in this manual is the use of insecticides, fungicides, and herbicides in forestry. Both diseases and insects found in hardwoods and conifers are covered. Detailed information is given on methods of herbicide application. Finally, five important environmental considerations are given. (BB)

  10. CO₂ electroreduction at bare and Cu-decorated Pd pseudomorphic layers: catalyst tuning by controlled and indirect supporting onto Au(111).

    Science.gov (United States)

    Januszewska, Aneta; Jurczakowski, Rafal; Kulesza, Pawel J

    2014-12-02

    We report here the results of electrochemical studies on CO2 electroreduction at multilayered catalyst composed of the monatomic layer of copper covering palladium overlayers (0.8-10 monolayers) deposited on the well-defined Au(111) surface. These multilayered systems were obtained by successive underpotential deposition steps: Pd on Au(111) as well as Cu on Pd/Au(111). Low index orientation of Au substrate was chosen to compare Pd overlayers with bulk Pd(111), which is known to reduce CO2 to CO adsorbates in acidic solutions. The process of CO2 electroreduction was studied by using classical transient electrochemical methods. Catalytic activity of bare Pd layers was investigated in acidic and neutral solutions. In the latter case, much higher activity of Pd overlayers was observed. The results showed that the palladium layer thickness significantly changed the catalytic activities of both bare Pd overlayers and the one Cu monolayer covered electrodes toward CO2 electroreduction. Results show that catalytic activity can be finely tuned by using the multilayered near-surface-alloy approach.

  11. Au-Free GaN High-Electron-Mobility Transistor with Ti/Al/W Ohmic and WN X Schottky Metal Structures for High-Power Applications

    Science.gov (United States)

    Hsieh, Ting-En; Lin, Yueh-Chin; Chu, Chung-Ming; Chuang, Yu-Lin; Huang, Yu-Xiang; Shi, Wang-Cheng; Dee, Chang-Fu; Majlis, Burhanuddin Yeop; Lee, Wei-I.; Chang, Edward Yi

    2016-07-01

    In this study, an Au-free AlGaN/GaN high-electron-mobility transistor (HEMT) with Ti/Al/W ohmic and WN x Schottky metal structures is fabricated and characterized. The device exhibits smooth surface morphology after metallization and shows excellent direct-current (DC) characteristics. The device also demonstrates better performance than the conventional HEMTs under high voltage stress. Furthermore, the Au-free AlGaN/GaN HEMT shows stable device performance after annealing at 400°C. Thus, the Ti/Al/W ohmic and WN X Schottky metals can be applied in the manufacturing of GaN HEMT to replace the Au based contacts to reduce the manufacturing costs of the GaN HEMT devices with comparable device performance.

  12. Application of genetic algorithms to tuning fuzzy control systems

    Science.gov (United States)

    Espy, Todd; Vombrack, Endre; Aldridge, Jack

    1993-01-01

    Real number genetic algorithms (GA) were applied for tuning fuzzy membership functions of three controller applications. The first application is our 'Fuzzy Pong' demonstration, a controller that controls a very responsive system. The performance of the automatically tuned membership functions exceeded that of manually tuned membership functions both when the algorithm started with randomly generated functions and with the best manually-tuned functions. The second GA tunes input membership functions to achieve a specified control surface. The third application is a practical one, a motor controller for a printed circuit manufacturing system. The GA alters the positions and overlaps of the membership functions to accomplish the tuning. The applications, the real number GA approach, the fitness function and population parameters, and the performance improvements achieved are discussed. Directions for further research in tuning input and output membership functions and in tuning fuzzy rules are described.

  13. Simulation of Fuzzy Inductance Motor using PI Control Application

    Directory of Open Access Journals (Sweden)

    S.V.Halse

    2013-06-01

    Full Text Available Fuzzy control has been widely used in industrial controls, particularly in situations where conventional control design techniques have been difficult to apply. Number of fuzzy rules is very important for real time fuzzy control applications. This study is motivated by the increasing need in the industry to design highly reliable, efficiency and low complexity controllers. The proposed fuzzy controller is constructed by several fuzzy controllers with less fuzzy rules to carry out control tasks. Performances of the proposed fuzzy controller are investigated and compared to those obtained from the conventional fuzzy controller. Fuzzy logic control method has the ability to handle errors in control operation with system nonlinearity and its performance is less affected by system parameter variations.

  14. Using supported Au nanoparticles as starting material for preparing uniform Au/Pd bimetallic catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Villa, Alberto [Universita di Milano, Italy; Prati, Laura [Universita di Milano, Italy; Su, Dangshen [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Wang, Di [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Veith, Gabriel M [ORNL

    2010-01-01

    One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and catalytic activities by investigating three different gold seeds. Uniform Au-Pd alloy were obtained when a steric/electrostatic protecting group, poly(vinyl alcohol) (PVA), was used to form the gold clusters on activated carbon (AC). In contrast Au/AC precursors prepared using Au nanoparticles with only electrostatic stabilization (tetrakis(hydroxypropyl)phosphonium chloride (THPC)), or no stabilization (magnetron sputtering) produced inhomogeneous alloys and segregation of the gold and palladium. The uniform alloyed catalyst (Pd{at}Au{sub PVA}/AC) is the most active and selective catalyst, while the inhomogenous catalysts are less active and selective. Further study of the PVA protected Au clusters revealed that the amount of PVA used is also critical for the preparation of uniform alloyed catalyst, their stability, and their catalytic activity.

  15. Control of particles flux in a tokamak with an events structure; Controle des flux de particules dans un Tokamak au moyen d`une structure a events

    Energy Technology Data Exchange (ETDEWEB)

    Tsitrone, E.

    1995-12-01

    Two key problems in the development of a controlled fusion reactor are: -the control of the ashes resulting from the fusion reaction (helium) and of the impurities coming from the wall erosion, which affect the central plasma performances by diluting the fuel and dissipating a part of the produced energy by radiation. - the removal of the heat carried to the walls by charged particles, which is highly concentrated (peak values of several tens of MW per m{sup 2}). Two types of systems are generally used for the plasma-wall interface: throat limiter and axisymmetric divertor. Neither is an ideal candidate to control simultaneously the heat and particle fluxes. This thesis investigates an alternative configuration, the vented limiter, tested for the first time on the Tore Supra tokamak. The vented limiter principle lies on the recycling neutrals collection by slots, in such a way that local thermal overload is avoided. It is shown experimentally that the surface temperature of the prototype installed in Tore Supra remains uniform. As far as the particle collection is concerned, even though the pressure in the vented limiter is lower than the pressure in the throat limiter by a factor 3 for deuterium and 4 helium, it is sufficient to control the plasma density. Moreover, as with a throat limiter, the pressure exhibits a quadratic evolution with the plasma density. To interpret these results, a model describing the plasma recycling on the limiter and the pumping by the slots has been developed. The model has been validated by a comparison with the experimental data. It was then used to propose an optimized version of the prototype with reshaped slots. This should improve the pumping efficiency by a factor 2, in deuterium as well as in helium, but without removing the discrepancy between both pumping efficiencies. (Abstract Truncated)

  16. Advances in control system technology for aerospace applications

    CERN Document Server

    2016-01-01

    This book is devoted to Control System Technology applied to aerospace and covers the four disciplines Cognitive Engineering, Computer Science, Operations Research, and Servo-Mechanisms. This edited book follows a workshop held at the Georgia Institute of Technology in June 2012, where the today's most important aerospace challenges, including aerospace autonomy, safety-critical embedded software engineering, and modern air transportation were discussed over the course of two days of intense interactions among leading aerospace engineers and scientists. Its content provide a snapshot of today's aerospace control research and its future, including Autonomy in space applications, Control in space applications, Autonomy in aeronautical applications, Air transportation, and Safety-critical software engineering.

  17. Labview Application For A Vehicle Control

    Directory of Open Access Journals (Sweden)

    Douglas Paladine Vieira

    2002-01-01

    Full Text Available This article deals with the construction of a vehicle driven by electric motors and that is automated, that is, that can move anywhere without human intervention. The control was done using the software Labview, with data acquisition and generation of control signs. The vehicle has an infrared sensors system that indicates the existence of an obstacle ahead the vehicle, informing it that it should stop and bypass the obstacle. The program is the responsible for the engine control, making it possible for the prototype to run and bypass the objects that block its way. The possibility of remote-controlling a vehicle is very important is risky situations for human beings, for example in radioactive places. The main advantage of this system is the total flexibility for making alterations in the control software, without being necessary to touch the physical part of the prototype. The conclusion of this work is that the system is efficient and able to move in a room with objects without touching them.

  18. Inline feedback control for deep drawing applications

    Science.gov (United States)

    Fischer, P.; Harsch, D.; Heingärtner, J.; Renkci, Y.; Hora, P.

    2016-11-01

    In series production of deep drawing products the quality of the parts is significantly influenced by material scatter. To guarantee a robust manufacturing the processes are designed to have a large process window. As the different material properties can lead to a drift in the process, the press settings have to be adjusted to keep the quality. In the scope of the work a feedback control system is proposed to keep the operation point inside the process window. The blank draw-in measured in predefined points is used as the primary indicator of the expected part quality. A simulation based meta model is then used to design the control algorithm with the blank holder forces as control variable. As the draw-in measurements are carried out punctually, their positioning within the tool becomes of critical importance. A simulation based study is therefore presented for the identification of sensor positions with the highest significance in relation to the process outcome. The baseline calibration of the controller is also based on the meta model. The validation of the proposed control system is illustrated based on experiments in a production line.

  19. Au/ZnO nanoarchitectures with Au as both supporter and antenna of visible-light

    Science.gov (United States)

    Liu, Tianyu; Chen, Wei; Hua, Yuxiang; Liu, Xiaoheng

    2017-01-01

    In this paper, we fabricate Au/ZnO nanostructure with smaller ZnO nanoparticles loaded onto bigger gold nanoparticles via combining seed-mediated method and sol-gel method. The obtained Au/ZnO nanocomposites exhibit excellent properties in photocatalysis process like methyl orange (MO) degradation and oxidative conversion of methanol into formaldehyde under visible light irradiation. The enhanced properties were ascribed to the surface plasmon resonance (SPR) effect of Au nanoparticles, which could contribute to the separation of photo-excited electrons and holes and facilitate the process of absorbing visible light. This paper contributes to the emergence of multi-functional nanocomposites with possible applications in visible-light driven photocatalysts and makes the Au/ZnO photocatalyst an exceptional choice for practical applications such as environmental purification of organic pollutants in aqueous solution and the synthesis of fine chemicals and intermediates.

  20. Application of Adaptive Fuzzy PID Leveling Controller

    Directory of Open Access Journals (Sweden)

    Ke Zhang

    2013-05-01

    Full Text Available Aiming at the levelling precision, speed and stability of suspended access platform, this paper put forward a new adaptive fuzzy PID control levelling algorithm by fuzzy theory. The method is aided design by using the SIMULINK toolbox of MATLAB, and setting the membership function and the fuzzy-PID control rule. The levelling algorithm can real-time adjust the three parameters of PID according to the fuzzy rules due to the current state. It is experimented, which is verified the algorithm have better stability and dynamic performance.

  1. Wireless Sensor/Actuator Network Design for Mobile Control Applications

    Directory of Open Access Journals (Sweden)

    Youxian Sung

    2007-10-01

    Full Text Available Wireless sensor/actuator networks (WSANs are emerging as a new generationof sensor networks. Serving as the backbone of control applications, WSANs will enablean unprecedented degree of distributed and mobile control. However, the unreliability ofwireless communications and the real-time requirements of control applications raise greatchallenges for WSAN design. With emphasis on the reliability issue, this paper presents anapplication-level design methodology for WSANs in mobile control applications. Thesolution is generic in that it is independent of the underlying platforms, environment,control system models, and controller design. To capture the link quality characteristics interms of packet loss rate, experiments are conducted on a real WSAN system. From theexperimental observations, a simple yet efficient method is proposed to deal withunpredictable packet loss on actuator nodes. Trace-based simulations give promisingresults, which demonstrate the effectiveness of the proposed approach.

  2. Communication from the CRE relative to the control of the appropriated book-keeping; Communication de la CRE relative au controle de la comptabilite appropriee

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-05-01

    The appropriated book-keeping mentioned in the article 5 of the law from February 10, 2000 is used to calculate the charges of the power production public utility. This book-keeping is controlled by an independent organization approved by the French commission of electricity regulation (CRE). This document precises the criteria requested by the CRE for the approval of this independent organization. The information note about the content of the appropriated book-keeping is attached in appendix: cost overruns due to the contracts of purchase, production cost overruns in non-interconnected areas, technical data to be archived by the operators during 6 years. (J.S.)

  3. Au nanostructures: an emerging prospect in cancer theranostics.

    Science.gov (United States)

    Nie, Xin; Chen, Chunying

    2012-10-01

    Au nanoparticles have been used in biomedical applications since ancient times. However, the rapid development of nanotechnology over the past century has led to recognition of the great potential of Au nanoparticles in a wide range of applications. Advanced fabrication techniques allow us to synthesize a variety of Au nanostructures possessing physiochemical properties that can be exploited for different purposes. Functionalization of the surface of Au nanoparticles further eases their application in various roles. These advantages of Au nanoparticles make them particularly suited for cancer treatment and diagnosis. The small size of Au particles enables them to preferentially accumulate at tumor sites to achieve in vivo targeting after systemic administration. Efficient light absorption followed by rapid heat conversion makes them very promising in photothermal therapy. The facile surface chemistry of Au nanoparticles eases delivery of drugs, ligands or imaging contrast agents in vivo. In this review, we summarize recent development of Au nanoparticles in cancer theranostics including imaging-based detection, photothermal therapy, chemical therapy and drug delivery. The multifunctional nature of Au nanoparticles means they hold great promise as novel anti-cancer therapeutics.

  4. Exploring applicability of the workload control concept

    NARCIS (Netherlands)

    Henrich, P.; Land, M.J.; Gaalman, G.J.C.

    2004-01-01

    To be successful in companies, a production planning and control (PPC) concept should fit to the production environment. Essential elements of the concept should correspond with the characteristics of the production system. For classical concepts such as MRP these elements have become common sense.

  5. Exploring applicability of the workload control concept

    NARCIS (Netherlands)

    Henrich, Peter; Land, Martin; Gaalman, Gerard

    2002-01-01

    To be successful in companies, a production planning and control (PPC) concept should fit to the production environment. Essential elements of the concept should correspond with the characteristics of the production system. For classical concepts such as MRP these elements have become common sense.

  6. Integrated natural gas pipeline control and customer service system of Gasum; Le systeme integre de controle des canalisations de gaz et de service au consommateur chez Gasum

    Energy Technology Data Exchange (ETDEWEB)

    Aho, J.; Manty, O.; Ahlnas, B. [Gasul Oy (Finland)

    2000-07-01

    Due to the rapid development of the information technology, ageing is not the only driving force for replacing old computer systems with more sophisticated ones. The Finnish natural Gas company, Gasum Oy, has recently taken into use a new control and monitoring system for natural gas pipeline. A special customer service system, developed by Gasum Oy, is closely connected to monitoring system. It provides up-to-date information to all customers of Gasum Oy. The information is layered in three confidential levels: general information, operational data and invoicing information. The system is operating interactively in confidential Extranet. Inside Gasum Oy to meet the needs of departments outside the control room, a new GID system is developed. GID is a way to present pipeline process data and its further modifications with a very user-friendly interface based on geographical map. The system is based on data warehouse architecture and it is working on company's Intranet. This makes it possible to present various secrecy level information based on user ID. Gasum's new SCADA is not only the base for operating the pipeline, but it also provides lot of vital information to other systems serving different user groups within natural gas business in Finland. (authors)

  7. A Robust Controller Structure for Pico-Satellite Applications

    DEFF Research Database (Denmark)

    Kragelund, Martin Nygaard; Green, Martin; Kristensen, Mads

    This paper describes the development of a robust controller structure for use in pico-satellite missions. The structure relies on unknown disturbance estimation and use of robust control theory to implement a system that is robust to both unmodeled disturbances and parameter uncertainties. As one...... possible application, a satellite mission with the purpose of monitoring shipping routes for oil spills has been considered. However, it is the aim of the control structure to be widely applicable and adaptable for a vide variety of pico-satellite missions. The robust control structure has been evaluated...

  8. Magmatic and structural controls on porphyry-style Cu-Au-Mo mineralization at Kemess South, Toodoggone District of British Columbia, Canada

    Science.gov (United States)

    Duuring, Paul; Rowins, Stephen M.; McKinley, Bradley S. M.; Dickinson, Jenni M.; Diakow, Larry J.; Kim, Young-Seog; Creaser, Robert A.

    2009-05-01

    Kemess South is the only Cu-Au-Mo mine in the Toodoggone district and a major Cu and Au producer in British Columbia. Porphyry-style Cu-Au-Mo mineralization is mainly hosted by the tabular, SW-plunging, 199.6 ± 0.6-Ma Maple Leaf granodiorite, which intrudes tightly folded, SW-dipping, Permian Asitka Group siltstone and limestone and homogeneous Triassic Takla Group basalt. Southwest-dipping 194.0 ± 0.4-Ma Toodoggone Formation conglomerate, volcaniclastic, and epiclastic rocks overlie the granodiorite and Asitka Group rocks. Minor Cu-Au-Mo mineralization is hosted by the immediate Takla Group basalt country rock, whereas low-tonnage high-grade Cu zones occur beneath a 30-m-thick leached capping in supergene-altered granodiorite and in exotic positions in overlying Toodoggone Formation conglomerate. Granodiorite has an intrusive contact with mineralized and altered Takla Group basalt but displays a sheared contact with unmineralized and less altered Asitka Group siltstone. The North Block fault is a deposit-scale, E-striking, steeply S-dipping normal fault that juxtaposes the granodiorite/basalt ore body against unmineralized Asitka Group rocks. Younger NW- and NE-striking normal-dextral faults cut all rock types, orebodies, and the North Block fault with displacements of up to 100 m and result in the graben-and-horst-style block faulting of the stratigraphy and ore body. Both basalt and granodiorite host comparable vein sequence and alteration histories, with minor variations in hydrothermal mineral assemblages caused by differing protolith chemistry. Early potassic alteration (and associated early-stage Cu ± Au ± Mo mineralization) is partly replaced by phyllic and intermediate argillic alteration associated with main-stage Cu-Au-Mo mineralization. Two main-stage veins have Re-Os molybdenite ages of 201.3 ± 1.2 and 201.1 ± 1.2 Ma. These mineralization ages overlap the 199.6 ± 0.6-Ma U-Pb zircon crystallization age for the Maple Leaf granodiorite. Late

  9. DSP applications in advanced, intelligent motion control: the future

    Energy Technology Data Exchange (ETDEWEB)

    Beierke, S. [Texas Instruments Deutschland GmBh, Freising (Germany); Vas, P. [Univ. of Aberdeen, Dept. of Engineering (United Kingdom)

    2000-08-01

    Recently there has been a rapid increase in the number of DSPs for various motion control applications. However, in the future, further significant increase is expected due to wider applications in existing and new areas (e.g. household appliances, automotive auxiliaries, micro-electromechanical systems, military applications, etc.). The present paper discusses the state-of-art Texas Instruments fixed point and floating point DSPs used in motion control applications and will also focus on future activities. Currently new chip technologies are being developed which involve copper interconnects, silicon-on-insulator wafers, insulators with- low dielectric constants, etc. It is expected that future single-chip DSPs for advanced intelligent motion control will have higher performance, reduced costs, simpler designs, will incorporate various sensors, different modules for optimised PWM generation, efficiency control, vector and direct torque control (sensorless and quasisensorless solutions as well), condition monitoring, selfcommissioning, artificial-intelligence-based control, etc. A manufacturer's task of implementing sensorless and/or quasisensorless torque control schemes for induction, synchronous and switched reluctance motor drives will be significantly reduced by the application of the newly developed DSPs. The paper will discuss these issues and will also show some implementation results in various sensorless (classical DTC; DTC with torque-ripple reduction schemes; vector) and quasisensorless ac drives (e.g. a vector controlled induction motor drive). (orig.)

  10. 76 FR 14690 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-03-17

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of...

  11. 76 FR 23627 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-04-27

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of...

  12. 75 FR 75497 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-12-03

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of...

  13. 76 FR 21916 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-04-19

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Enforcement Administration (DEA) to be registered as a bulk manufacturer of 4-...

  14. 5th International Conference on Optimization and Control with Applications

    CERN Document Server

    Teo, Kok; Zhang, Yi

    2014-01-01

    This book presents advances in state-of-the-art solution methods and their applications to real life practical problems in optimization, control and operations research. Contributions from world-class experts in the field are collated here in two parts, dealing first with optimization and control theory and then with techniques and applications. Topics covered in the first part include control theory on infinite dimensional Banach spaces, history-dependent inclusion and linear programming complexity theory. Chapters also explore the use of approximations of Hamilton-Jacobi-Bellman inequality for solving periodic optimization problems and look at multi-objective semi-infinite optimization problems, and production planning problems.  In the second part, the authors address techniques and applications of optimization and control in a variety of disciplines, such as chaos synchronization, facial expression recognition and dynamic input-output economic models. Other applications considered here include image retr...

  15. Approximate viability for nonlinear evolution inclusions with application to controllability

    Directory of Open Access Journals (Sweden)

    Omar Benniche

    2016-12-01

    Full Text Available We investigate approximate viability for a graph with respect to fully nonlinear quasi-autonomous evolution inclusions. As application, an approximate null controllability result is given.

  16. Preparation and Characterization of Au-ZrO2-SiO2 Nanocomposite Spheres and Their Application in Enrichment and Detection of Organophosphorus Agents

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yuqi; Tu, Haiyang; Zhang, Aidong; Du, Dan; Lin, Yuehe

    2012-03-01

    Au-ZrO{sub 2}-SiO{sub 2} nanocomposite spheres were synthesized and used as selective sorbents for the solid-phase extraction (SPE) of orananophosphorous agents. A non-enzymatic electrochemical sensor based on an Au-ZrO{sub 2}-SiO{sub 2} modified electrode was developed for selective detection of orananophosphorous pesticides (OPs). The Au-ZrO{sub 2}-SiO{sub 2} nanocomposite spheres were synthesized by hydrolysis and condensation of zirconia n-butoxide (TBOZ) on the surface of SiO{sub 2} spheres and then introduction of gold nanoparticles on the surface. Transmission electron microscope and X-ray photoelectron spectroscopy were performed to characterize the formation of the nanocomposite sphere. Fast extraction of OP was achieved by Au-ZrO{sub 2}-SiO{sub 2} modified electrode within 5 min via the specific affinity between zirconia and phosphoric group. The assay yields a broad concentration range of paraoxon-ethyl from 1.0 to 500 ng/mL{sup -1} with a detection limit 0.5 ng/mL{sup -1}. This selective and sensitive method holds great promise for the enrichment and detection of OPs.

  17. Oxidation and reduction kinetics of eutectic SnPb, InSn, and AuSn: a knowledge base for fluxless solder bonding applications

    DEFF Research Database (Denmark)

    Kuhmann, Jochen Friedrich; Preuss, A.; Adolphi, B.;

    1998-01-01

    For microelectronics and especially for upcoming new packaging technologies in micromechanics and photonics fluxless, reliable and economic soldering technologies are needed. In this article, we consequently focus on the oxidation and reduction kinetics of three commonly used eutectic solder allo...... and reflowed AuSn(80/20) and SnPb(60/40) after the introduction of H2...

  18. Applicability of near-infrared hyperspectral imagery (NIR-HI) for sensor based sorting of an epithermal Au-Ag ore

    NARCIS (Netherlands)

    Dalm, M.; Buxton, M.W.N.; Van Ruitenbeek, F.J.A.

    2015-01-01

    In the presented study test work was performed with near-infrared hyperspectral imagery (NIR-HI) on 36 ore samples from a South-American epithermal Au-Ag mine. The aim of the test work was to investigate if NIR-HI provides information about the alteration mineralogy of samples that can be used to pr

  19. Bioinspired polydopamine as the scaffold for the active AuNPs anchoring and the chemical simultaneously reduced graphene oxide: characterization and the enhanced biosensing application.

    Science.gov (United States)

    Tian, Juan; Deng, Sheng-Yuan; Li, Da-Li; Shan, Dan; He, Wei; Zhang, Xue-Ji; Shi, You

    2013-11-15

    We report here an efficient approach to enhance the performance of biosensing platform based on graphene or graphene derivate. Initially, graphene oxides (GO) nanosheets were reduced and surface functionalized by one-step oxidative polymerization of dopamine in basic solution at environment friendly condition to obtain the polydopamine (Pdop) modified reduced graphene oxides (PDRGO). The bioinspired surface was further used as a support to anchor active gold nanoparticles (AuNPs). The morphology and structure of the as-prepared AuNPs/PDRGO nanocomposite were investigated by field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Fourier transform-infrared spectroscopy (FT-IR). Electrochemical studies demonstrate that the as-prepared AuNPs/PDRGO hybrid materials possess excellent electrochemical properties and electrocatalytic activity toward the oxidation of NADH at low potential (0.1 V vs. SCE) with the fast response (15s) and the broad linear range (5.0 × 10(-8)-4.2 × 10(-5)M). Thus, this AuNPs/PDRGO nanocomposite can be further used to fabricate a sensitive alcohol biosensor using alcohol dehydrogenase (ADH), by simply incorporating the specific enzyme within the composite matrix with the aid of chitosan (Chit).

  20. Weapon Control System for Airborne Application.

    Directory of Open Access Journals (Sweden)

    M. Sankar Kishore

    2000-07-01

    Full Text Available The integrated fire' control system (IFCS plays an important role in the present-day fighter aircraft and helicopters. Wecapons, such as missiles (active/passive, rockets and guns may be present on thelfighter aircraft or helicopter .IFCS monitors the status of the weapons present on the vehicle and passes the information to pilot/co-pilot. Depending upon the health/availability of the weapons, IFCS selects/fires the weapons. An attempt has been made to bring out the details of one such IFCS. As a I stepping stone, smaller version is developed and same philosophy can be used for integrating ftlore and I more weapons. Here, emphasis has been made on design and development of weapon control unit which is the heart f IFCS, both in hardware and software. The system has been developed using a 486 DX2 processor, and an elaborate software has been developed in PL/M.

  1. Heat conduction controlled combustion for scramjet applications

    Science.gov (United States)

    Ferri, A.; Agnone, A. M.

    1974-01-01

    The use of heat conduction flame generated in a premixed supersonic stream is discussed. It is shown that the flame is controlled initially by heat conduction and then by chemical reaction. Such a flame is shorter than the diffusion type of flame and therefore it requires a much shorter burner. The mixing is obtained by injecting the hydrogen in the inlet. Then the inlet can be cooled by film cooling.

  2. History and applications in controlled environments

    Science.gov (United States)

    Downs, R. J.

    1994-01-01

    The widespread application of electric (often called artificial) light in greenhouses, growing rooms, and plant growth chambers would presuppose that the role of phytochrome would be considered in the selection and use of such lighting systems. Unfortunately this is not usually the case. Part of the problem is that many students, and indeed an unfortunate number of senior scientists, seem to regard phytochrome as a laboratory phenomenon without much application in the real world. They simply have not grasped the concept that phytochrome is functioning through all stages of plant development, wherever plants are grown. It is certainly true, as Meijer (1971) stated, that one cannot compare experimental results obtained under very strict laboratory conditions with plant irradiation in glasshouses and in growth rooms. When Karl Norris developed the first practical portable spectroradiometer about 1962, some of the first measurements were to determine the red/far-red ratios under tree canopies. These measurements showed clearly the predominance of far-red in the understory and suggested that far-red was contributing to the elongation exhibited by many species growing in the shade, and possibly was a factor in the induction of light requirements in seeds. Subsequently we used Catalpa leaves as far-red filters to make light-insensitive lettuce seed light requiring. Much more detailed work has since been done on phytochrome effects in the natural environment, and it is encouraging to note that efforts are bring made to apply phytochrome research to horticulture.

  3. Applications of Fuzzy Sliding Mode Control for a Gyroscope System

    Directory of Open Access Journals (Sweden)

    Shih-Chung Chen

    2013-01-01

    Full Text Available The study proposed the application of the fuzzy sliding mode for a gyroscope system status control. The state response analysis of the gyroscope system revealed highly nonlinear and chaotic subharmonic motions of 2T during state formation. The current study discussed the use of tracking control on the sliding mode control and fuzzy sliding mode control of a gyroscope control system. Consequently, the gyroscope system drives from chaotic motion to periodic motion. The numerical simulation results confirm that the proposed controller provides good system stability and convergence without chattering phenomena.

  4. Application of Object-Based Industrial Controls for Cryogenics

    CERN Document Server

    Casas-Cubillos, J; Gomes, P; Pezzetti, M; Sicard, Claude Henri; Varas, F J

    2002-01-01

    The first application of the CERN Unified Industrial Control system (UNICOS) has been developed for the 1.8 K refrigerator at point 1.8 in mid-2001. This paper presents the engineering methods used for application development, in order to reach the objectives of maintainability and reusability, in the context of a development done by an external consortium of engineering firms. It will also review the lessons learned during this first development and the improvements planned for the next applications.

  5. 75 FR 20001 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-04-16

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... application by renewal to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer...

  6. 75 FR 32506 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-08

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... application by renewal to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer...

  7. 75 FR 14190 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-03-24

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... application by renewal to the Drug Enforcement Administration (DEA) as a bulk manufacturer of the...

  8. 75 FR 36683 - Importer of Controlled Substances; Notice of Application

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    2010-06-28

    ... Register on September 23, 1975, ] (40 FR 43745-46), all applicants for registration to import a basic class... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... renewal to the Drug Enforcement Administration (DEA) to be registered as an importer of...

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    Science.gov (United States)

    2010-11-15

    ... Notice of Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for... a previous notice published in the Federal Register on September 23, 1975, (40 FR 43745-46), all... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21...

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    2013-05-22

    ... Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for registration to import a basic... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21, Code... Drug Enforcement Administration (DEA) to be registered as an importer of Pentobarbital (2270), a...

  11. 75 FR 1812 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-01-13

    ... Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for hearings on... a previous notice published in the Federal Register on September 23, 1975, (40 FR 43745), all... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21...

  12. 75 FR 53719 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-09-01

    ... notice published in the Federal Register on September 23, 1975, (40 FR 43745-46), all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... the Drug Enforcement Administration (DEA) to be registered as an importer of the basic classes...

  13. 76 FR 51398 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-08-18

    ... Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for hearings on...). As noted in a previous notice published in the Federal Register on September 23, 1975, 40 FR 43745... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to Title 21...

  14. 75 FR 53718 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-09-01

    ... the Correction to Notice of Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments... noted in a previous notice published in the Federal Register on September 23, 1975, (40 FR 43745), all... Enforcement Administration Importer of Controlled Substances; Notice of Application This is notice that on...

  15. 77 FR 35020 - Importer of Controlled Substances Notice of Application

    Science.gov (United States)

    2012-06-12

    ... September 23, 1975, 40 FR 43745-46, all applicants for registration to import a basic class of any... Enforcement Administration Importer of Controlled Substances Notice of Application Pursuant to 21 U.S.C. 958(i... Administration (DEA) to be registered as an importer of Pentobarbital (2270), a basic class of...

  16. 75 FR 65658 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-10-26

    ... the Correction to Notice of Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments... noted in a previous notice published in the Federal Register on September 23, 1975, (40 FR 43745), all... Enforcement Administration Importer of Controlled Substances;Notice of Application This is notice that on...

  17. 75 FR 32505 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-08

    ... the Federal Register on September 23, 1975 (40 FR 43745-46), all applicants for registration to import... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Enforcement Administration (DEA) to be registered as an importer of Nabilone (7379), a basic class...

  18. 76 FR 35239 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-06-16

    ... notice published in the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of Phenylacetone (8501), a basic class of...

  19. Enhanced Photoresponse of Conductive Polymer Nanowires Embedded with Au Nanoparticles.

    Science.gov (United States)

    Zhang, Junchang; Zhong, Liubiao; Sun, Yinghui; Li, Anran; Huang, Jing; Meng, Fanben; Chandran, Bevita K; Li, Shuzhou; Jiang, Lin; Chen, Xiaodong

    2016-04-20

    A conductive polymer nanowire embedded with a 1D Au nanoparticle chain with defined size, shape, and interparticle distance is fabricated which demonstrates enhanced photoresponse behavior. The precise and controllable positioning of 1D Au nanoparticle chain in the conductive polymer nanowire plays a critical role in modulating the photoresponse behavior by excitation light wavelength or power due to the coupled-plasmon effect of 1D Au nanoparticle chain.

  20. Multimodel Approach for Intelligent Control and Applications

    Institute of Scientific and Technical Information of China (English)

    Abdelkader El Kamel; Pierre Borne

    2004-01-01

    The use of the multimodel approach in the modelling, analysis and control of non-linear complex and/or ill-defined systems was advocated by many researchers. This approach supposes the definition of a set of local models valid in a given region or domain. Different strategies exist in the literature and are generally based on a partitioning of the non-linear system's full range of operation into multiple smaller operating regimes each of which is associated with a locally valid model or controller. However, most of these strategies, which suppose the determination of these local models as well as their validity domain, remain arbitrary and are generally fixed thanks to a certain a priori knowledge of the system whatever its order. Recently, we have proposed a new approach to derive a multimodel basis which allows us to limit the number of models in the basis to almost four models. Meanwhile, the transition problem between the different models, which may use either a simple commutation or a fusion technique, remains still arise. In this plenary talk, a fuzzy fusion technique is presented and has the following main advantages: (1) use of a fuzzy partitioning in order to determine the validity of each model which enhances the robustness of the solution; (2) introduction, besides the four extreme models, of another model, called average model, determined as an average of the boundary models.

  1. Studies of the structure and phase transitions of nano-confined pentanedithiol and its application in directing hierarchical molecular assemblies on Au(1 1 1)

    Science.gov (United States)

    Pawlicki, Alison; Avery, Erin; Jurow, Matthew; Ewers, Bradley; Vilan, Ayelet; Drain, Charles Michael; Batteas, James

    2016-03-01

    Directing molecular devices into pre-designed integrated electronic circuits while enforcing selectivity and hierarchy is an inherent challenge for molecular electronics. Here we explore ways to direct the assembly of electrically-active molecular monolayers into specific locations as well as controlling their internal organization. We have accomplished this by two consecutive surface reactions: (1) forming pentanedithiol (C5DT) domains within an inert alkanethiol self-assembled monolayer (SAM) on Au; and (2) selectively binding porphyrin derivatives to the C5DT domains. The C5DT domains were fabricated by phase segregation during co-adsorption from a mixed C5DT/dodecanethiol (C12) solution and nanografting with Atomic Force Microscopy (AFM). AFM revealed that co-absorbed and nanografted C5DT domains were in a standing-up phase and scanning tunneling microscopy (STM) showed that their molecular organization within about 5 nm, 40 nm, 50 nm and 120 nm domains, was dependent upon the size of the domain, such that structure of the C5DT transitions from (\\sqrt{3}   ×  \\sqrt{3} ) R30°, to (2  ×  2), and ultimately to a disordered phase with increasing domain size. This is due to the varying degrees of influence of the surrounding C12; providing sufficient van der Waals interactions as well as a geometric confinement to stabilize the standing-up phase of the C5DT. Understanding the molecular configuration of dithiol SAMs affords their use as a reactive template to subsequently bind active head groups. As a proof of principle, porphyrins with a pendant pentafluorophenyl ring were attached to the C5DT domains by a ‘click’ reaction between the fluorinated ring and the free thiol on the surface. From AFM and STM, these porphyrin derivatives reacted selectively with the C5DT domains with some porphyrins binding directly to the C5DT, subsequently allowing additional localized porphyrin deposition through pi-stacking.

  2. Controlled Vocabulary Service Application for Environmental Data Store

    Science.gov (United States)

    Ji, P.; Piasecki, M.; Lovell, R.

    2013-12-01

    In this paper we present a controlled vocabulary service application for Environmental Data Store (EDS). The purpose for such application is to help researchers and investigators to archive, manage, share, search, and retrieve data efficiently in EDS. The Simple Knowledge Organization System (SKOS) is used in the application for the representation of the controlled vocabularies coming from EDS. The controlled vocabularies of EDS are created by collecting, comparing, choosing and merging controlled vocabularies, taxonomies and ontologies widely used and recognized in geoscience/environmental informatics community, such as Environment ontology (EnvO), Semantic Web for Earth and Environmental Terminology (SWEET) ontology, CUAHSI Hydrologic Ontology and ODM Controlled Vocabulary, National Environmental Methods Index (NEMI), National Water Information System (NWIS) codes, EPSG Geodetic Parameter Data Set, WQX domain value etc. TemaTres, an open-source, web -based thesaurus management package is employed and extended to create and manage controlled vocabularies of EDS in the application. TemaTresView and VisualVocabulary that work well with TemaTres, are also integrated in the application to provide tree view and graphical view of the structure of vocabularies. The Open Source Edition of Virtuoso Universal Server is set up to provide a Web interface to make SPARQL queries against controlled vocabularies hosted on the Environmental Data Store. The replicas of some of the key vocabularies commonly used in the community, are also maintained as part of the application, such as General Multilingual Environmental Thesaurus (GEMET), NetCDF Climate and Forecast (CF) Standard Names, etc.. The application has now been deployed as an elementary and experimental prototype that provides management, search and download controlled vocabularies of EDS under SKOS framework.

  3. Spatially-controlled complex molecules and their applications

    CERN Document Server

    Chang, Yuan-Pin; Trippel, Sebastian; Küpper, Jochen

    2015-01-01

    The understanding of molecular structure and function is at the very heart of the chemical and molecular sciences. Experiments that allow for the creation of structurally pure samples and the investigation of their molecular dynamics and chemical function have developed tremendeously over the last few decades, although "there's plenty of room at the bottom" for better control as well as further applications. Here, we describe the use of inhomogeneous electric fields for the manipulation of neutral molecules in the gas-phase, \\ie, for the separation of complex molecules according to size, structural isomer, and quantum state. Current applications of these controlled samples are summarized and interesting future applications discussed.

  4. Controllable Edge Feature Sharpening for Dental Applications

    Directory of Open Access Journals (Sweden)

    Ran Fan

    2014-01-01

    Full Text Available This paper presents a new approach to sharpen blurred edge features in scanned tooth preparation surfaces generated by structured-light scanners. It aims to efficiently enhance the edge features so that the embedded feature lines can be easily identified in dental CAD systems, and to avoid unnatural oversharpening geometry. We first separate the feature regions using graph-cut segmentation, which does not require a user-defined threshold. Then, we filter the face normal vectors to propagate the geometry from the smooth region to the feature region. In order to control the degree of the sharpness, we propose a feature distance measure which is based on normal tensor voting. Finally, the vertex positions are updated according to the modified face normal vectors. We have applied the approach to scanned tooth preparation models. The results show that the blurred edge features are enhanced without unnatural oversharpening geometry.

  5. 76 FR 77850 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-12-14

    ... Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following basic classes of... manufacture Hydromorphone HCL for sale to other manufacturers, and to manufacture other controlled...

  6. 76 FR 62449 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-10-07

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... (DEA) to be registered as a bulk manufacturer of the following basic classes of controlled...

  7. 75 FR 44285 - Manufacturer of Controlled Substances: Notice of Application

    Science.gov (United States)

    2010-07-28

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances: Notice of Application Pursuant to Sec. 1301... manufacturer of the basic classes of controlled substances listed in schedule II: Drug Schedule...

  8. 76 FR 66994 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-10-28

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... registered as a bulk manufacturer of the following basic classes of controlled substances: Drug...

  9. 75 FR 69464 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-11-12

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Administration (DEA) as a bulk manufacturer of the basic classes of controlled substances listed in schedules...

  10. 77 FR 5845 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-02-06

    ...). As noted in a previous notice published in the Federal Register on September 23, 1975, 40 FR 43745-46... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of Fentanyl (9801), a basic class of controlled...

  11. 76 FR 77253 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-12-12

    ... noted in a previous notice published in the Federal Register on September 23, 1975, 40 FR 43745, all... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958...) to be registered as an importer of Remifentanil (9739), a basic class of controlled substance...

  12. The synthesis of Au@C@Pt core-double shell nanocomposite and its application in enzyme-free hydrogen peroxide sensing

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yayun; Li, Yuhui; Jiang, Yingying [College of Chemistry & Environment, Minnan Normal University, Zhangzhou 363000 (China); Li, Yancai, E-mail: liyancai@mnnu.edu.cn [College of Chemistry & Environment, Minnan Normal University, Zhangzhou 363000 (China); Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou 363000 (China); Li, Shunxing [College of Chemistry & Environment, Minnan Normal University, Zhangzhou 363000 (China); Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou 363000 (China)

    2016-08-15

    Highlights: • A novel Au@C@Pt core-double shell nanocomposite was synthesized and characterized by SEM(*), TEM and EDS, etc. • The synthesized Au@C@Pt core-double shell nanocomposite showed high sensitivity and selectivity to electrocatalytic reduction of hydrogen peroxide (H{sub 2}O{sub 2}) and can be used to fabricate enzyme-free H{sub 2}O{sub 2} electrochemical sensor. • The H{sub 2}O{sub 2} sensor has two linear range of 9.0 μM–1.86 mM and 1.86 mM–7.11 mM, respectively, with a low limit of detection of 0.13 μM. • The H{sub 2}O{sub 2} sensor also displays high anti-interference ability, good stability and reproducibility. - Abstract: A novel Au@C@Pt core-double shell nanocomposite was synthesized and used to fabricate enzyme-free electrochemical sensor for rapid and sensitive detection of hydrogen peroxide (H{sub 2}O{sub 2}). The well-designed Au@C@Pt core-double shell nanocomposite was characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM) and energy-dispersed spectrum (EDS). The Au@C@Pt core-double shell nanocomposite modified glassy carbon electrode (Au@C@Pt/GCE) exhibits good electrocatalytic activity towards H{sub 2}O{sub 2} reduction at 0.0 V and can be used as H{sub 2}O{sub 2} sensor. The sensor displays two wide linear ranges towards H{sub 2}O{sub 2} detection. The one is 9.0 μM–1.86 mM with high sensitivity of 144.7 μA mM{sup −1} cm{sup −2}, and the other is 1.86 mM–7.11 mM with sensitivity of 80.1 μA mM{sup −1} cm{sup −2}. When signal to noise (S/N) is 3, the calculated detection limit (LOD) is 0.13 μM. Furthermore, the interference from the common interfering species such as glucose, ascorbic acid, dopamine and uric acid can be effectively avoided to H{sub 2}O{sub 2} detection. Additionally, the H{sub 2}O{sub 2} sensor also displays good stability and reproducibility.

  13. Soft Computing Applications in Optimization, Control, and Recognition

    CERN Document Server

    Castillo, Oscar

    2013-01-01

    Soft computing includes several intelligent computing paradigms, like fuzzy logic, neural networks, and bio-inspired optimization algorithms. This book describes the application of soft computing techniques to intelligent control, pattern recognition, and optimization problems. The book is organized in four main parts. The first part deals with nature-inspired optimization methods and their applications. Papers included in this part propose new models for achieving intelligent optimization in different application areas. The second part discusses hybrid intelligent systems for achieving control. Papers included in this part make use of nature-inspired techniques, like evolutionary algorithms, fuzzy logic and neural networks, for the optimal design of intelligent controllers for different kind of applications. Papers in the third part focus on intelligent techniques for pattern recognition and propose new methods to solve complex pattern recognition problems. The fourth part discusses new theoretical concepts ...

  14. Fuzzy logic applications to expert systems and control

    Science.gov (United States)

    Lea, Robert N.; Jani, Yashvant

    1991-01-01

    A considerable amount of work on the development of fuzzy logic algorithms and application to space related control problems has been done at the Johnson Space Center (JSC) over the past few years. Particularly, guidance control systems for space vehicles during proximity operations, learning systems utilizing neural networks, control of data processing during rendezvous navigation, collision avoidance algorithms, camera tracking controllers, and tether controllers have been developed utilizing fuzzy logic technology. Several other areas in which fuzzy sets and related concepts are being considered at JSC are diagnostic systems, control of robot arms, pattern recognition, and image processing. It has become evident, based on the commercial applications of fuzzy technology in Japan and China during the last few years, that this technology should be exploited by the government as well as private industry for energy savings.

  15. Stability and Sensitivity Analysis of Fuzzy Control Systems. Mechatronics Applications

    Directory of Open Access Journals (Sweden)

    Radu-Emil Precup

    2006-01-01

    Full Text Available The development of fuzzy control systems is usually performed by heuristicmeans, incorporating human skills, the drawback being in the lack of general-purposedevelopment methods. A major problem, which follows from this development, is theanalysis of the structural properties of the control system, such as stability, controllabilityand robustness. Here comes the first goal of the paper, to present a stability analysismethod dedicated to fuzzy control systems with mechatronics applications based on the useof Popov’s hyperstability theory. The second goal of this paper is to perform the sensitivityanalysis of fuzzy control systems with respect to the parametric variations of the controlledplant for a class of servo-systems used in mechatronics applications based on theconstruction of sensitivity models. The stability and sensitivity analysis methods provideuseful information to the development of fuzzy control systems. The case studies concerningfuzzy controlled servo-systems, accompanied by digital simulation results and real-timeexperimental results, validate the presented methods.

  16. Stability and Sensitivity Analysis of Fuzzy Control Systems. Mechatronics Applications

    OpenAIRE

    Radu-Emil Precup; Stefan Preitl

    2006-01-01

    The development of fuzzy control systems is usually performed by heuristicmeans, incorporating human skills, the drawback being in the lack of general-purposedevelopment methods. A major problem, which follows from this development, is theanalysis of the structural properties of the control system, such as stability, controllabilityand robustness. Here comes the first goal of the paper, to present a stability analysismethod dedicated to fuzzy control systems with mechatronics applications bas...

  17. Applications to Regular and Bang-Bang Control

    OpenAIRE

    Maurer, Helmut; Osmolovskii, Nikolai,

    2012-01-01

    International audience; This book is devoted to the theory and applications of second-order necessary and sufficient optimality conditions in the calculus of variations and optimal control. The authors develop theory for a control problem with ordinary differential equations subject to boundary conditions of equality and inequality type, and for mixed state-control constraints of equality type. The book has several distinctive features: necessary and sufficient conditions are given in the for...

  18. Inductive Logic Programming for Industrial Control Applications

    Directory of Open Access Journals (Sweden)

    Samiya Bouarroudj

    2014-04-01

    Full Text Available Advanced Monitoring Systems of the processes consti tute a higher level to the systems of control and use specific techniques and methods. An importa nt part of the task of supervision focuses on the detection and the diagnosis of various situatio ns of faults which can affect the process. Methods of fault detection and diagnosis (FDD are different from the type of knowledge about the process that they require. They can be classifi ed as data-driven, analytical, or knowledge- based approach. A collaborative FDD approach that c ombines the strengths of various heterogeneous FDD methods is able to maximize diagn ostic performance. The new generation of knowledge-based systems or decision support syst ems needs to tap into knowledge that is both very broad, but specific to a domain, combinin g learning, structured representations of domain knowledge such as ontologies and reasoning t ools. In this paper, we present a decision- aid tool in case of malfunction of high power indus trial steam boiler. For this purpose an ontology was developed and considered as a prior co nceptual knowledge in Inductive Logic Programming (ILP for inducing diagnosis rules. The next step of the process concerns the inclusion of rules acquired by induction in the kno wledge base as well as their exploitation for reasoning.

  19. Intelligent control based on intelligent characteristic model and its application

    Institute of Scientific and Technical Information of China (English)

    吴宏鑫; 王迎春; 邢琰

    2003-01-01

    This paper presents a new intelligent control method based on intelligent characteristic model for a kind of complicated plant with nonlinearities and uncertainties, whose controlled output variables cannot be measured on line continuously. The basic idea of this method is to utilize intelligent techniques to form the characteristic model of the controlled plant according to the principle of combining the char-acteristics of the plant with the control requirements, and then to present a new design method of intelli-gent controller based on this characteristic model. First, the modeling principles and expression of the intelligent characteristic model are presented. Then based on description of the intelligent characteristic model, the design principles and methods of the intelligent controller composed of several open-loops and closed-loops sub controllers with qualitative and quantitative information are given. Finally, the ap-plication of this method in alumina concentration control in the real aluminum electrolytic process is in-troduced. It is proved in practice that the above methods not only are easy to implement in engineering design but also avoid the trial-and-error of general intelligent controllers. It has taken better effect in the following application: achieving long-term stable control of low alumina concentration and increasing the controlled ratio of anode effect greatly from 60% to 80%.

  20. The Vital Function of Fe3O4@Au nanocomposites for Hydrolase Biosensor Design and Its Application in Detection of Methyl Parathion

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Yuting; Zhang, Weiying; Lin, Yuehe; Du, Dan

    2013-02-04

    A nanocomposite of gold nanoparticles (AuNPs) decorating a magnetic Fe3O4 core was synthesized using cysteamine (SH–NH2) as linker, and characterized by TEM, XPS, UV and electrochemistry. Then a hydrolase biosensor, based on self-assembly of methyl parathion hydrolase (MPH) on the Fe3O4@Au nanocomposite, was developed for sensitive and selective detection of the organophosphorus pesticide (OP) methyl parathion. The magnetic nanocomposite provides an easy way to construct the enzyme biosensor by simply exerting an external magnetic field, and also provides a simple way to renew the electrode surface by removing the magnet. Unlike inhibition-based enzyme biosensors, the hydrolase is not poisoned by OPs and thus is reusable for continuous measurement. AuNPs not only provide a large surface area, high loading efficiency and fast electron transfer, but also stabilize the enzyme through electrostatic interactions. The MPH biosensor shows rapid response and high selectivity for detection of methyl parathion, with a linear range from 0.5 to 1000 ng/mL and a detection limit of 0.1 ng/mL. It also shows acceptable reproducibility and stability. The simplicity and ease of operation of the proposed method has great potential for on-site detection of P–S containing pesticides and provides a promising strategy to construct a robust biosensor.

  1. High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures

    Science.gov (United States)

    Hong, Xinguo; Ehm, Lars; Zhong, Zhong; Ghose, Sanjit; Duffy, Thomas S.; Weidner, Donald J.

    2016-02-01

    We report development of micro-focusing optics for high-energy x-rays by combining a sagittally bent Laue crystal monchromator with Kirkpatrick-Baez (K-B) X-ray focusing mirrors. The optical system is able to provide a clean, high-flux X-ray beam suitable for pair distribution function (PDF) measurements at high pressure using a diamond anvil cell (DAC). A focused beam of moderate size (10-15 μm) has been achieved at energies of 66 and 81 keV. PDF data for nanocrystalline platinum (n-Pt) were collected at 12.5 GPa with a single 5 s X-ray exposure, showing that the in-situ compression, decompression, and relaxation behavior of samples in the DAC can be investigated with this technique. PDFs of n-Pt and nano Au (n-Au) under quasi-hydrostatic loading to as high as 71 GPa indicate the existence of substantial reduction of grain or domain size for Pt and Au nanoparticles at pressures below 10 GPa. The coupling of sagittally bent Laue crystals with K-B mirrors provides a useful means to focus high-energy synchrotron X-rays from a bending magnet or wiggler source.

  2. Spin resonance transport properties of a single Au atom in S-Au-S junction and Au-Au-Au junction

    Science.gov (United States)

    Fangyuan, Wang; Guiqin, Li

    2016-07-01

    The spin transport properties of S-Au-S junction and Au-Au-Au junction between Au nanowires are investigated with density functional theory and the non-equilibrium Green's function. We mainly focus on the spin resonance transport properties of the center Au atom. The breaking of chemical bonds between anchor atoms and center Au atom significantly influences their spin transmission characteristics. We find the 0.8 eV orbital energy shift between anchor S atoms and the center Au atom can well protect the spin state stored in the S-Au-S junction and efficiently extract its spin state to the current by spin resonance mechanism, while the spin interaction of itinerant electrons and the valence electron of the center Au atom in the Au-Au-Au junction can extract the current spin information into the center Au atom. Fermi energy drift and bias-dependent spin filtering properties of the Au-Au-Au junction may transform information between distance, bias, and electron spin. Those unique properties make them potential candidates for a logical nanocircuit. Project supported by the National Basic Research Program of China (Grants No. 2011CB921602) and the National Natural Science Foundation of China (Grants No. 20121318158).

  3. Electrostatic assembles and optical properties of Au CdTe QDs and Ag/Au CdTe QDs

    Science.gov (United States)

    Yang, Dongzhi; Wang, Wenxing; Chen, Qifan; Huang, Yuping; Xu, Shukun

    2008-09-01

    Au-CdTe and Ag/Au-CdTe assembles were firstly investigated through the static interaction between positively charged cysteamine-stabilized CdTe quantum dots (QDs) and negatively charged Au or core/shell Ag/Au nano-particles (NCs). The CdTe QDs synthesized in aqueous solution were capped with cysteamine which endowed them positive charges on the surface. Both Au and Ag/Au NCs were prepared through reducing precursors with gallic acid obtained from the hydrolysis of natural plant poly-phenols and favored negative charges on the surface of NCs. The fluorescence spectra of CdTe QDs exhibited strong quenching with the increase of added Au or Ag/Au NCs. Railey resonance scattering spectra of Au or Ag/Au NCs increased firstly and decreased latter with the concentration of CdTe QDs, accompanied with the solution color changing from red to purple and colorless at last. Experimental results on the effects of gallic acid, chloroauric acid tetrahydrate and other reagents demonstrated the static interaction occurred between QDs and NCs. This finding reveals the possibilities to design and control optical process and electromagnetic coupling in hybrid structures.

  4. Indicateurs cles au Canada

    OpenAIRE

    Warren, Paul

    2005-01-01

    Au cours des dernieres annees, on s'est beaucoup interesse sur la scene internationale aux indicateurs cles. Le present document se veut un tour d'horizon des efforts deployes recemment au Canada en vue d'elaborer des indicateurs cles du bien etre economique, social, environnemental et physique. Y sont classifies et examines en detail plus de 40 projets et publications portant sur ce sujet. Y figurent aussi l'enumeration breve de 20 autres projets, ainsi que des renvois a plusieurs enquetes a...

  5. Wearable Device Control Platform Technology for Network Application Development

    Directory of Open Access Journals (Sweden)

    Heejung Kim

    2016-01-01

    Full Text Available Application development platform is the most important environment in IT industry. There are a variety of platforms. Although the native development enables application to optimize, various languages and software development kits need to be acquired according to the device. The coexistence of smart devices and platforms has rendered the native development approach time and cost consuming. Cross-platform development emerged as a response to these issues. These platforms generate applications for multiple devices based on web languages. Nevertheless, development requires additional implementation based on a native language because of the coverage and functions of supported application programming interfaces (APIs. Wearable devices have recently attracted considerable attention. These devices only support Bluetooth-based interdevice communication, thereby making communication and device control impossible beyond a certain range. We propose Network Application Agent (NetApp-Agent in order to overcome issues. NetApp-Agent based on the Cordova is a wearable device control platform for the development of network applications, controls input/output functions of smartphones and wearable/IoT through the Cordova and Native API, and enables device control and information exchange by external users by offering a self-defined API. We confirmed the efficiency of the proposed platform through experiments and a qualitative assessment of its implementation.

  6. Access Control of Web- and Java-Based Applications

    Science.gov (United States)

    Tso, Kam S.; Pajevski, Michael J.

    2013-01-01

    Cybersecurity has become a great concern as threats of service interruption, unauthorized access, stealing and altering of information, and spreading of viruses have become more prevalent and serious. Application layer access control of applications is a critical component in the overall security solution that also includes encryption, firewalls, virtual private networks, antivirus, and intrusion detection. An access control solution, based on an open-source access manager augmented with custom software components, was developed to provide protection to both Web-based and Javabased client and server applications. The DISA Security Service (DISA-SS) provides common access control capabilities for AMMOS software applications through a set of application programming interfaces (APIs) and network- accessible security services for authentication, single sign-on, authorization checking, and authorization policy management. The OpenAM access management technology designed for Web applications can be extended to meet the needs of Java thick clients and stand alone servers that are commonly used in the JPL AMMOS environment. The DISA-SS reusable components have greatly reduced the effort for each AMMOS subsystem to develop its own access control strategy. The novelty of this work is that it leverages an open-source access management product that was designed for Webbased applications to provide access control for Java thick clients and Java standalone servers. Thick clients and standalone servers are still commonly used in businesses and government, especially for applications that require rich graphical user interfaces and high-performance visualization that cannot be met by thin clients running on Web browsers

  7. Systematic Study on the Self-Assembled Hexagonal Au Voids, Nano-Clusters and Nanoparticles on GaN (0001.

    Directory of Open Access Journals (Sweden)

    Puran Pandey

    Full Text Available Au nano-clusters and nanoparticles (NPs have been widely utilized in various electronic, optoelectronic, and bio-medical applications due to their great potentials. The size, density and configuration of Au NPs play a vital role in the performance of these devices. In this paper, we present a systematic study on the self-assembled hexagonal Au voids, nano-clusters and NPs fabricated on GaN (0001 by the variation of annealing temperature and deposition amount. At relatively low annealing temperatures between 400 and 600°C, the fabrication of hexagonal shaped Au voids and Au nano-clusters are observed and discussed based on the diffusion limited aggregation model. The size and density of voids and nano-clusters can systematically be controlled. The self-assembled Au NPs are fabricated at comparatively high temperatures from 650 to 800°C based on the Volmer-Weber growth model and also the size and density can be tuned accordingly. The results are symmetrically analyzed and discussed in conjunction with the diffusion theory and thermodynamics by utilizing AFM and SEM images, EDS maps and spectra, FFT power spectra, cross-sectional line-profiles and size and density plots.

  8. High density unaggregated Au nanoparticles on ZnO nanorod arrays function as efficient and recyclable photocatalysts for environmental purification.

    Science.gov (United States)

    Yang, Tung-Han; Huang, Li-De; Harn, Yeu-Wei; Lin, Chun-Cheng; Chang, Jan-Kai; Wu, Chih-I; Wu, Jenn-Ming

    2013-09-23

    Photodegradation of organic pollutants in aqueous solution is a promising method for environmental purification. Photocatalysts capable of promoting this reaction are often composed of noble metal nanoparticles deposited on a semiconductor. Unfortunately, the separation of these semiconductor-metal nanopowders from the treated water is very difficult and energy consumptive, so their usefulness in practical applications is limited. Here, a precisely controlled synthesis of a large-scale and highly efficient photocatalyst composed of monolayered Au nanoparticles (AuNPs) chemically bound to vertically aligned ZnO nanorod arrays (ZNA) through a bifunctional surface molecular linker is demonstrated. Thioctic acid with sufficient steric stabilization is used as a molecular linker. High density unaggregated AuNPs bonding on entire surfaces of ZNA are successfully prepared on a conductive film/substrate, allowing easy recovery and reuse of the photocatalysts. Surprisingly, the ZNA-AuNPs heterostructures exhibit a photodegradation rate 8.1 times higher than that recorded for the bare ZNA under UV irradiation. High density AuNPs, dispersed perfectly on the ZNA surfaces, significantly improve the separation of the photogenerated electron-hole pairs, enlarge the reaction space, and consequently enhance the photocatalytic property for degradation of chemical pollutants. Photoelectron, photoluminescence and photoconductive measurements confirm the discussion on the charge carrier separation and photocatalytic experimental data. The demonstrated higher photodegradation rates demonstrated indicate that the ZNA-AuNPs heterostructures are candidates for the next-generation photocatalysts, replacing the conventional slurry photocatalysts.

  9. Complex systems and networks dynamics, controls and applications

    CERN Document Server

    Yu, Xinghuo; Chen, Guanrong; Yu, Wenwu

    2016-01-01

    This elementary book provides some state-of-the-art research results on broad disciplinary sciences on complex networks. It presents an in-depth study with detailed description of dynamics, controls and applications of complex networks. The contents of this book can be summarized as follows. First, the dynamics of complex networks, for example, the cluster dynamic analysis by using kernel spectral methods, community detection algorithms in bipartite networks, epidemiological modeling with demographics and epidemic spreading on multi-layer networks, are studied. Second, the controls of complex networks are investigated including topics like distributed finite-time cooperative control of multi-agent systems by applying homogenous-degree and Lyapunov methods, composite finite-time containment control for disturbed second-order multi-agent systems, fractional-order observer design of multi-agent systems, chaos control and anticontrol of complex systems via Parrondos game and many more. Third, the applications of ...

  10. Selective data collection in vehicular networks for traffic control applications

    CERN Document Server

    Płaczek, Bartłomiej

    2011-01-01

    Vehicular sensor network (VSN) is an emerging technology, which combines wireless communication offered by vehicular ad hoc networks (VANET) with sensing devices installed in vehicles. VSN creates a huge opportunity to extend the road-side sensor infrastructure of existing traffic control systems. The efficient use of the wireless communication medium is one of the basic issues in VSN applications development. This paper introduces a novel method of selective data collection for traffic control applications, which provides a significant reduction in data amounts transmitted through VSN. The underlying idea is to detect the necessity of data transfers on the basis of uncertainty determination of the traffic control decisions. According to the proposed approach, sensor data are transmitted from vehicles to the control node only at selected time moments. Data collected in VSN are processed using on-line traffic simulation technique, which enables traffic flow prediction, performance evaluation of control strateg...

  11. Magnetic switch of permeability for polyelectrolyte microcapsules embedded with Co@Au nanoparticles.

    Science.gov (United States)

    Lu, Zonghuan; Prouty, Malcolm D; Guo, Zhanhu; Golub, Vladimir O; Kumar, Challa S S R; Lvov, Yuri M

    2005-03-01

    We explored using a magnetic field to modulate the permeability of polyelectrolyte microcapsules prepared by layer-by-layer self-assembly. Ferromagnetic gold-coated cobalt (Co@Au) nanoparticles (3 nm diameter) were embedded inside the capsule walls. The final 5 mum diameter microcapsules had wall structures consisting of 4 bilayers of poly(sodium styrene sulfonate)/poly(allylamine hydrochloride) (PSS/PAH), 1 layer of Co@Au, and 5 bilayers of PSS/PAH. External alternating magnetic fields of 100-300 Hz and 1200 Oe were applied to rotate the embedded Co@Au nanoparticles, which subsequently disturbed and distorted the capsule wall and drastically increased its permeability to macromolecules like FITC-labeled dextran. The capsule permeability change was estimated by taking the capsule interior and exterior fluorescent intensity ratio using confocal laser scanning microscopy. Capsules with 1 layer of Co@Au nanoparticles and 10 polyelectrolyte bilayers are optimal for magnetically controlling permeability. A theoretical explanation was proposed for the permeability control mechanisms. "Switching on" of these microcapsules using a magnetic field makes this method a good candidate for controlled drug delivery in biomedical applications.

  12. Distributed, Modular, Network Enabled Architecture For Process Control Military Applications

    Directory of Open Access Journals (Sweden)

    Abhijit Kamble*,

    2014-02-01

    Full Text Available In process control world, use of distributed modular embedded controller architecture drastically reduces the number and complexity of cabling; at the same time increases the system computing performance and response for real time application as compared to centralized control system. We propose a design based on ARM Cortex M4 hardware architecture and Cortex Microcontroller Software Interface Standard (CMSIS based software development. The ARM Cortex-M series ensures a compatible target processor and provides common core peripherals whereas CMSIS abstraction layer reduces development time, helps design software reusability and provides seamless application software interface for controllers. Being a custom design, we can built features like Built-In Test Equipment (BITE, single point fault tolerance, redundancy, 2/3 logic, etc. which are more desirable for a military applications. This paper describes the design of a generic embedded hardware module that can be configured as local I/O controller or application controller or Man Machine Interface (MMI. This paper also proposes a philosophy for step by step hardware and software development.

  13. Development of Plant Control Diagnosis Technology and Increasing Its Applications

    Science.gov (United States)

    Kugemoto, Hidekazu; Yoshimura, Satoshi; Hashizume, Satoru; Kageyama, Takashi; Yamamoto, Toru

    A plant control diagnosis technology was developed to improve the performance of plant-wide control and maintain high productivity of plants. The control performance diagnosis system containing this technology picks out the poor performance loop, analyzes the cause, and outputs the result on the Web page. Meanwhile, the PID tuning tool is used to tune extracted loops from the control performance diagnosis system. It has an advantage of tuning safely without process changes. These systems are powerful tools to do Kaizen (continuous improvement efforts) step by step, coordinating with the operator. This paper describes a practical technique regarding the diagnosis system and its industrial applications.

  14. Cascaded process model based control: packed absorption column application.

    Science.gov (United States)

    Govindarajan, Anand; Jayaraman, Suresh Kumar; Sethuraman, Vijayalakshmi; Raul, Pramod R; Rhinehart, R Russell

    2014-03-01

    Nonlinear, adaptive, process-model based control is demonstrated in a cascaded single-input-single-output mode for pressure drop control in a pilot-scale packed absorption column. The process is shown to be nonlinear. Control is demonstrated in both servo and regulatory modes, for no wind-up in a constrained situation, and for bumpless transfer. Model adaptation is demonstrated and shown to provide process insight. The application procedure is revealed as a design guide to aid others in implementing process-model based control.

  15. Late Cretaceous structural control and Alpine overprint of the high-sulfidation Cu-Au epithermal Chelopech deposit, Srednogorie belt, Bulgaria

    Science.gov (United States)

    Chambefort, Isabelle; Moritz, Robert

    2006-06-01

    The Chelopech epithermal high-sulfidation deposit is located in the Panagyurishte ore district in Bulgaria, which is defined by a NNW alignment of Upper Cretaceous porphyry-Cu and Cu-Au epithermal deposits, and forms part of the Eastern European Banat-Srednogorie belt. Detailed structural mapping and drillcore descriptions have been used to define the structural evolution of the Chelopech deposit from the Late Cretaceous to the present. The Chelopech deposit is characterized by three fault populations including ˜N55, ˜N110, and ˜N155-trending faults, which are also recognized in the entire Panagyurishte district. Mapping and 3-D modeling show that hydrothermal alteration and orebody geometry at Chelopech are controlled by the ˜N55-trending and ˜N110-trending faults. Moreover, the ˜N155-trending faults are parallel to the regional ore deposit alignment of the Panagyurishte ore district. It is concluded that the three fault populations are early features and Late Cretaceous in age, and that they were active during high-sulfidation ore formation at Chelopech. However, the relative fault chronology cannot be deduced anymore due to Late Cretaceous and Tertiary tectonic overprint. Structurally controlled ore formation was followed by Senonian sandstone, limestone, and flysch deposition. The entire Late Cretaceous magmatic and sedimentary rock succession underwent folding, which produced WNW-oriented folds throughout the Panagyurishte district. A subsequent tectonic stage resulted in overthrusting of older rock units along ˜NE-trending reverse faults on the Upper Cretaceous magmatic and sedimentary host rocks of the high-sulfidation epithermal deposit at Chelopech. The three fault populations contemporaneous with ore formation, i.e., the ˜N55-, ˜N110- and ˜N155-trending faults, were reactivated as thrusts or reverse faults, dextral strike-slip faults, and transfer faults, respectively, during this event. Previous studies indicate that the present-day setting is

  16. A Modular Integrated RFID System for Inventory Control Applications

    OpenAIRE

    Ross Bunker; Atef Elsherbeni

    2017-01-01

    Recent advances in single-board computer technology have allowed for lightweight, power-efficient devices, such as the Raspberry Pi, to take the place of desktop PCs in certain applications. This has the potential to disrupt the way many current systems are structured, particularly for inventory management and control applications. In this paper, we explore the design and topology of a modular Radio frequency identification (RFID) system for inventory management comprised of self-contained, a...

  17. Robust Control for High-Speed Visual Servoing Applications

    DEFF Research Database (Denmark)

    Ellekilde, Lars-Peter; Favrholdt, Peter; Paulin, Mads;

    2007-01-01

    This paper presents a new control scheme for visual servoing applications. The approach employs quadratic optimization, and explicitly handles both joint position, velocity and acceleration limits. Contrary to existing techniques, our method does not rely on large safety margins and slow task...... the correctness and efficiency of our approach in a number of visual servoing applications, and compare it to a range of previously proposed techniques....

  18. Catalytic activity of Au nanoparticles

    DEFF Research Database (Denmark)

    Larsen, Britt Hvolbæk; Janssens, Ton V.W.; Clausen, Bjerne;

    2007-01-01

    Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with par......Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change...... with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the catalytic activity, suggesting that atoms on the corners and edges of Au nanoparticles are the active sites. This effect is explained using density functional calculations....

  19. Application of infinite model predictive control methodology to other advanced controllers.

    Science.gov (United States)

    Abu-Ayyad, M; Dubay, R; Hernandez, J M

    2009-01-01

    This paper presents an application of most recent developed predictive control algorithm an infinite model predictive control (IMPC) to other advanced control schemes. The IMPC strategy was derived for systems with different degrees of nonlinearity on the process gain and time constant. Also, it was shown that IMPC structure uses nonlinear open-loop modeling which is conducted while closed-loop control is executed every sampling instant. The main objective of this work is to demonstrate that the methodology of IMPC can be applied to other advanced control strategies making the methodology generic. The IMPC strategy was implemented on several advanced controllers such as PI controller using Smith-Predictor, Dahlin controller, simplified predictive control (SPC), dynamic matrix control (DMC), and shifted dynamic matrix (m-DMC). Experimental work using these approaches combined with IMPC was conducted on both single-input-single-output (SISO) and multi-input-multi-output (MIMO) systems and compared with the original forms of these advanced controllers. Computer simulations were performed on nonlinear plants demonstrating that the IMPC strategy can be readily implemented on other advanced control schemes providing improved control performance. Practical work included real-time control applications on a DC motor, plastic injection molding machine and a MIMO three zone thermal system.

  20. A Backstepping Simple Adaptive Control Application to Flexible Space Structures

    Institute of Scientific and Technical Information of China (English)

    LIU Min; XU Shijie; HAN Chao

    2012-01-01

    Although the simple adaptive control (SAC) is widely studied both in theory and application in flexible space structure control and other control problems,it is restricted by the almost strictly positive real (ASPR) conditions.In most practical control problems,the ASPR conditions are not satisfied.Therefore,based on the SAC theory,this paper proposes a backstepping simple adaptive control algorithm which suits the system with arbitrary relative degree with no need of parallel feedforward compensator.The proposed control algorithm consists of decomposition of the arbitrary relative degree system into a known subsystem and an unknown ASPR subsystem which are eonneeted in cascade,design of constant outpul feedback controller for the known subsystem,and implementation of backstepping method and SAC of the unknown ASPR subsystem.Inheriting the characteristics of the SAC,this method can be adaptive online for the parameter uncertainties.Then,the application of the proposed controller to large flexible space structure with collocated sensors and actuators is studied,and the simulation results validate the proposed controller.It is a new strategy to apply the classical SAC to high relative degree plants.

  1. Metal-inducd assembly of a semiconductor-island lattice: Getruncated pyramids on Au-patterned Si

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, J.T.; Liddle, J.A.; Minor, A.; Radmilovic, V.; Yi,D.O.; Greaney, P.A.; Long, K.N.; Chrzan, D.C.; Dubon, O.D.

    2005-08-28

    We report the two-dimensional alignment of semiconductor islands using rudimentary metal patterning to control nucleation and growth. In the Ge on Si system, a square array of sub-micron Au dots on the Si (001) surface induces the assembly of deposited Ge adatoms into an extensive island lattice. Remarkably, these highly ordered Ge islands form between the patterned Au dots and are characterized by a unique truncated pyramidal shape. A model based on patterned diffusion barriers explains the observed ordering and establishes general criteria for the broader applicability of such a directed assembly process to quantum dot ordering.

  2. Nanoporous Silicified Phospholipids and Application to Controlled Glycolic Acid Release

    Directory of Open Access Journals (Sweden)

    Kang SangHwa

    2008-01-01

    Full Text Available Abstract This work demonstrates the synthesis and characterization of novel nanoporous silicified phospholipid bilayers assembled inorganic powders. The materials are obtained by silicification process with silica precursor at the hydrophilic region of phospholipid bilayers. This process involves the co-assembly of a chemically active phospholipids bilayer within the ordered porosity of a silica matrix and holds promise as a novel application for controlled drug release or drug containers with a high level of specificity and throughput. The controlled release application of the synthesized materials was achieved to glycolic acid, and obtained a zero-order release pattern due to the nanoporosity.

  3. Au-ZnO hybrid nanoflowers, nanomultipods and nanopyramids: one-pot reaction synthesis and photocatalytic properties.

    Science.gov (United States)

    Chen, Yuanzhi; Zeng, Deqian; Zhang, Kun; Lu, Aolin; Wang, Laisen; Peng, Dong-Liang

    2014-01-21

    The preparation of noble metal-semiconductor hybrid nanocrystals with controlled morphologies has received intensive interest in recent years. In this study, facile one-pot reactions have been developed for the synthesis of Au-ZnO hybrid nanocrystals with different interesting morphologies, including petal-like and urchin-like nanoflowers, nanomultipods and nanopyramids. In the synthesis strategy, oleylamine-containing solution serves as the reaction medium, and the in situ generated Au seeds play an important role in the subsequently induced growth of ZnO nanocrystals. With the aid of several surfactants, hybrid nanocrystals with different morphologies that have considerable influences on their optical and photocatalytic activities are readily achieved. Through high-resolution transmission electron microscopy measurements, an observed common orientation relationship between ZnO and Au is that ZnO nanocrystals prefer to grow with their polar {001} facets on the {111} facets of Au nanocrystals, and well-defined interfaces are evident. Surface plasmon resonance bands of Au with different positions are observed in the UV-vis spectra, and the UV and visible emissions of ZnO are found to be dramatically reduced. Finally, the as-prepared Au-ZnO nanocrystals exhibit excellent photocatalytic activity for the photodegradation of rhodamine B compared with pure ZnO nanocrystals. The Au-ZnO hybrid nanopyramids show the highest catalytic efficiency, which is correlated with the exposed crystal facets, crystallinity and the formation of hybrid nanostructures. The as-prepared Au-ZnO hybrid nanocrystals are expected to find diverse potential applications in the fields such as photocatalysis, solar energy conversion, sensing and biological detection.

  4. Interaction Kinetics between Sn-Pb Solder Droplet and Au/Ni/Cu Pad

    Institute of Scientific and Technical Information of China (English)

    Fuquan LI; Chunqing WANG; Yanhong TIAN

    2006-01-01

    The interfacial phenomena of the Sn-Pb solder droplet on Au/Ni/Cu pad are investigated. A continuous AuSn2and needle-like AuSn4 are formed at the interface after the liquid state reaction (soldering). The interfacial reaction between the solder and Au layer continues during solid state aging with AuSn4 breaking off from the interface and felling into the solder. The kinetics of Au layer dissolution and diffusion into the solder during soldering and aging is analyzed to elucidate intermetallic formation mechanism at the solder/Au pad interface.The concentration of Au near the solder/pad interface is identified to increase and reach the solubility limit during the period of liquid state reaction. During solid state reaction, the thickening of Au-Sn compound is mainly controlled by element diffusion.

  5. Controllable synthesis and biomedical applications of silver nanomaterials.

    Science.gov (United States)

    Huang, Zhihai; Jiang, Xiaoli; Guo, Dawei; Gu, Ning

    2011-11-01

    Silver nanomaterials have lots of peculiar and exciting physical and chemical properties that are different from massive silver, so the synthesis and applications of silver nanomaterials have attracted a great deal of attention in the last decade. Currently, all kinds of silver nanomaterials having different shapes and sizes have been synthesized by many ingenious methods, and silver nanomaterials have exhibited extensive application prospects in many fields especially in biomedical aspect. In this article, the controllable synthesis of silver nanomaterials including nanorods, nanowires, nanotubes, nanoprisms, nanoplates, nanodisks, nanospheres, and nanopolyhedrons, etc. are reviewed. Silver nanomaterials are most utilized in the form of nanoparticles, so the main biomedical applications of silver nanoparticles, such as antibacterial and antiviral applications, antitumor applications, biosensors and biological labels, optical imaging and imaging intensifier, are discussed. Although antibacterial applications are still the most important aspects of silver nanomaterials at present, antitumor, optical sensors and imaging applications of silver nanomaterials have also shown good potential perspectives. More biomedical applications of silver nanomaterials still need to be exploited for the future, and the biological safety of silver nanomaterials also should be paid enough attention before their practical applications.

  6. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ohno, S.; Shimakura, H. [Niigata University of Pharmacy and Applied Life Sciences, Higashijima, Akiha-ku, Niigata 956-8603 (Japan); Tahara, S. [Faculty of Science, University of the Ryukyus, Nishihara-cho, Okinawa 903-0213 (Japan); Okada, T. [Niigata College of Technology, Kamishin’eicho, Nishi-ku, Niigata 950-2076 (Japan)

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  7. New approaches in intelligent control techniques, methodologies and applications

    CERN Document Server

    Kountchev, Roumen

    2016-01-01

    This volume introduces new approaches in intelligent control area from both the viewpoints of theory and application. It consists of eleven contributions by prominent authors from all over the world and an introductory chapter. This volume is strongly connected to another volume entitled "New Approaches in Intelligent Image Analysis" (Eds. Roumen Kountchev and Kazumi Nakamatsu). The chapters of this volume are self-contained and include summary, conclusion and future works. Some of the chapters introduce specific case studies of various intelligent control systems and others focus on intelligent theory based control techniques with applications. A remarkable specificity of this volume is that three chapters are dealing with intelligent control based on paraconsistent logics.

  8. Application of IFT and SPSA to servo system control.

    Science.gov (United States)

    Rădac, Mircea-Bogdan; Precup, Radu-Emil; Petriu, Emil M; Preitl, Stefan

    2011-12-01

    This paper treats the application of two data-based model-free gradient-based stochastic optimization techniques, i.e., iterative feedback tuning (IFT) and simultaneous perturbation stochastic approximation (SPSA), to servo system control. The representative case of controlled processes modeled by second-order systems with an integral component is discussed. New IFT and SPSA algorithms are suggested to tune the parameters of the state feedback controllers with an integrator in the linear-quadratic-Gaussian (LQG) problem formulation. An implementation case study concerning the LQG-based design of an angular position controller for a direct current servo system laboratory equipment is included to highlight the pros and cons of IFT and SPSA from an application's point of view. The comparison of IFT and SPSA algorithms is focused on an insight into their implementation.

  9. Randomized Algorithms for Systems and Control: Theory and Applications

    Science.gov (United States)

    2008-05-01

    IEIIT-CNR Randomized Algorithms for Systems and Control: Theory and Applications NATO LS Glasgow, Pamplona , Cleveland @RT 2008 Roberto Tempo IEIIT...Glasgow, Pamplona , Cleveland @RT 2008 roberto.tempo@polito.it IEIIT-CNR References R. Tempo, G. Calafiore and F. Dabbene, “Randomized Algorithms for...Analysis and Control of Uncertain Systems,” Springer-Verlag, London, 2005 R Tempo and H Ishii “Monte Carlo and Las Vegas NATO LS Glasgow, Pamplona , Cleveland

  10. Improved forwarding control design method and its application

    Institute of Scientific and Technical Information of China (English)

    Chen Yimei; Han Zhengzhi; Cai Xiushan

    2006-01-01

    Integrator forwarding is a recursive nonlinear design technique for the stabilization of feed-forward systems.However, this method still has some limitation. An improved design method is proposed to extend the field of application of this technique. This method is used to design a stabilizer for the inertia wheel pendulum system. Moreover, it is shown that the control Lyapunov function which is obtained from this method can also be used to design a globally asymptotically stabilizing controller with optimality.

  11. Embedded target toolbox for DSP control applications of BLDC motor

    Directory of Open Access Journals (Sweden)

    Benk Enikö

    2009-10-01

    Full Text Available This paper presents a Matlab embedded target toolbox used for the DC brushless (BLDC motor applications. The synthesis, code generation, and the implementation of the control program, and also the control task itself are carried out on the host PC, under the Simulink. The target system is a brushless DC motor control kit – MSK243, connected on serial port COM to the host computer. With this real time library, it is possible to develop a Rapid Control Prototyping and Hardware-in-the-Loop Simulations. During the running control task on the target, the full functionality of Matlab/Simulink can be used for parameter’s visualization without interrupting or impeding the control process on the MSK240 board.

  12. Type-2 Fuzzy Logic in Intelligent Control Applications

    CERN Document Server

    Castillo, Oscar

    2012-01-01

    We describe in this book, hybrid intelligent systems based mainly on type-2 fuzzy logic for intelligent control. Hybrid intelligent systems combine several intelligent computing paradigms, including fuzzy logic, and bio-inspired optimization algorithms, which can be used to produce powerful automatic control systems. The book is organized in three main parts, which contain a group of chapters around a similar subject. The first part consists of chapters with the main theme of theory and design algorithms, which are basically chapters that propose new models and concepts, which can be the basis for achieving intelligent control with interval type-2 fuzzy logic. The second part of the book is comprised of chapters with the main theme of evolutionary optimization of type-2 fuzzy systems in intelligent control with the aim of designing optimal type-2 fuzzy controllers for complex control problems in diverse areas of application, including mobile robotics, aircraft dynamics systems and hardware implementations. Th...

  13. Direct electron transfer biosensor for hydrogen peroxide carrying nanocomplex composed of horseradish peroxidase and Au-nanoparticle – Characterization and application to bienzyme systems

    Directory of Open Access Journals (Sweden)

    Yusuke Okawa

    2015-09-01

    Full Text Available A reagentless electrochemical biosensor for hydrogen peroxide was fabricated. The sensor carries a monolayer of nanocomplex composed of horseradish peroxidase and Au-nanoparticle, and responds to hydrogen peroxide through the highly efficient direct electron transfer at a mild electrode potential without any soluble mediator. Formation of the nanocomplex was studied with visible spectroscopy and size exclusion chromatography. The sensor performance was analyzed based on a hydrodynamic electrochemical technique and enzyme kinetics. The sensor was applied to fabrication of sensors for glucose and uric acid through further modification of the nanocomplex-carrying electrode with the corresponding hydrogen peroxide-generating oxidases, glucose oxidase and urate oxidase, respectively.

  14. Dynamically Authorized Role-Based Access Control for Grid Applications

    Institute of Scientific and Technical Information of China (English)

    YAO Hanbing; HU Heping; LU Zhengding; LI Ruixuan

    2006-01-01

    Grid computing is concerned with the sharing and coordinated use of diverse resources in distributed "virtual organizations". The heterogeneous, dynamic and multi-domain nature of these environments makes challenging security issues that demand new technical approaches. Despite the recent advances in access control approaches applicable to Grid computing, there remain issues that impede the development of effective access control models for Grid applications. Among them there are the lack of context-based models for access control, and reliance on identity or capability-based access control schemes. An access control scheme that resolve these issues is presented, and a dynamically authorized role-based access control (D-RBAC) model extending the RBAC with context constraints is proposed. The D-RABC mechanisms dynamically grant permissions to users based on a set of contextual information collected from the system and user's environments, while retaining the advantages of RBAC model. The implementation architecture of D-RBAC for the Grid application is also described.

  15. ER fluid applications to vibration control devices and an adaptive neural-net controller

    Science.gov (United States)

    Morishita, Shin; Ura, Tamaki

    1993-07-01

    Four applications of electrorheological (ER) fluid to vibration control actuators and an adaptive neural-net control system suitable for the controller of ER actuators are described: a shock absorber system for automobiles, a squeeze film damper bearing for rotational machines, a dynamic damper for multidegree-of-freedom structures, and a vibration isolator. An adaptive neural-net control system composed of a forward model network for structural identification and a controller network is introduced for the control system of these ER actuators. As an example study of intelligent vibration control systems, an experiment was performed in which the ER dynamic damper was attached to a beam structure and controlled by the present neural-net controller so that the vibration in several modes of the beam was reduced with a single dynamic damper.

  16. Maîtrise de la cohérence des modèles UML d'applications critiques. Approche par l'analyse des risques liés au langage UML

    OpenAIRE

    Seuma Vidal, Jean-Pierre

    2006-01-01

    Le langage UML permet la description de systèmes informatiques complexes dont la sécurité est parfois critique. Lors de la conception de telles applications, des fautes de modélisation peuvent être introduites dans les diagrammes UML représentant différentes vues du système. Ces fautes peuvent mener à des incohérences entre diagrammes ou au sein même d'un seul diagramme. Outre les propriétés spécifiques de l'application, il convient de vérifier en premier lieu que les modèles sont cohérents v...

  17. Solid-Phase Equilibria in the Au-As, Au-Ga-Sb, Au-In-As, and Au-In-Sb Ternaries.

    Science.gov (United States)

    1986-02-28

    AD6i5 469 SOLID- PHASE EQUILIBRIA IN THE Ru-As AU-GA-SB AU-IN-AS- 1/17 AND AU-IN-SB TERNAR (U) CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY AND...REPORT & PERIOD COVERED SOLID- PHASE EQUILIBRIA IN THE Au-Ga-As, Au-Ga-Sb Thchnical Report Au-In-As, and Au-In-Sb TEARIEIS S. PERFORMING ORG. REPORT NUMBER...CLASSIFICATION OF THIS PAGEMI*n Does Entepd) 4./ lie- . .- - - - - -- -- Solid Phase Equilibria in the Au-Ga-As, Au-Ga-Sb, Au-In-As, and Au-In-Sb Ternaries C

  18. Plasmonic Au islands on polymer nanopillars

    Energy Technology Data Exchange (ETDEWEB)

    Knoben, Wout; Brongersma, Sywert H; Crego-Calama, Mercedes, E-mail: wout.knoben@imec-nl.nl [Holst Centre/IMEC, High Tech Campus 31, 5656 AE Eindhoven (Netherlands)

    2011-07-22

    The refractive index sensitivity of localized surface plasmon resonance sensors can be improved by placing the plasmonic metal particles on pillars instead of on a planar substrate. In this paper, a simple and versatile colloidal lithography method for the fabrication of plasmonic Au islands on top of polymer nanopillars is described. The pillar height is controlled by varying the thickness of the initial polymer film. An increased pillar height results in a blue shift of the absorption spectrum of the Au islands. This is explained by a decreased effective refractive index around the islands. For pillars higher than approximately 40 nm no further blue shift is observed, in agreement with the decay length of the electromagnetic field around the islands. Pillar-supported Au islands were also fabricated on a flexible foil, demonstrating the potential of the method described here for the fabrication of flexible plasmonic substrates. Benefits and limitations of the method and of using polymers as the pillar material are discussed.

  19. Control synthesis for polynomial nonlinear systems and application in attitude control

    Institute of Scientific and Technical Information of China (English)

    Chang-fei TONG; Hui ZHANG; You-xian SUN

    2008-01-01

    A method for positive polynomial validation based on polynomial decomposition is proposed to deal with control synthesis problems. Detailed algorithms for decomposition are given which mainly consider how to convert coefficients of a polynomial to a matrix with free variables. Then, the positivity of a polynomial is checked by the decomposed matrix with semidefinite programming solvers. A nonlinear control law is presented for single input polynomial systems based on the Lyapunov stability theorem. The control synthesis method is advanced to multi-input systems further. An application in attitude control is finally presented. The proposed control law achieves effective performance as illustrated by the numerical example.

  20. Computer and control applications in a vegetable processing plant

    Science.gov (United States)

    There are many advantages to the use of computers and control in food industry. Software in the food industry takes 2 forms - general purpose commercial computer software and software for specialized applications, such as drying and thermal processing of foods. Many applied simulation models for d...

  1. 75 FR 14189 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-03-24

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of Amphetamine (1100),...

  2. 76 FR 51401 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-08-18

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following basic classes...

  3. 75 FR 75498 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-12-03

    ... Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... letter to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the basic..., Inc.'s legal existence as a corporation and as a DEA registrant as a bulk manufacturer will...

  4. 75 FR 21661 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-04-26

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... by renewal to the Drug Enforcement Administration (DEA) as a bulk manufacturer of the basic...

  5. 77 FR 2324 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-01-17

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the...

  6. 76 FR 14689 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-03-17

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following...

  7. 77 FR 2323 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-01-17

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following...

  8. 75 FR 13304 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-03-19

    ... Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... renewal to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the basic... commercial distribution. The company plans to manufacture Hydromorphone HCL for sale to other...

  9. 76 FR 33785 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-06-09

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following...

  10. 76 FR 51400 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-08-18

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... ] Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of Morphine (9300),...

  11. 76 FR 62450 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-10-07

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the following...

  12. 76 FR 36577 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-06-22

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the...

  13. 76 FR 77257 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-12-12

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... by renewal to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer...

  14. 76 FR 44358 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-07-25

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of...

  15. 76 FR 31638 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-06-01

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... renewal to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer...

  16. 76 FR 51402 - Manufacturer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-08-18

    ... From the Federal Register Online via the Government Publishing Office ] DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application Pursuant to Sec. 1301... to the Drug Enforcement Administration (DEA) to be registered as a bulk manufacturer of the...

  17. Biopolymers in controlled release devices for agricultural applications.

    Science.gov (United States)

    The use of biopolymers such as starch for agricultural applications including controlled release devices is growing due the environmental benefits. Recently, concerns have grown about the worldwide spread of parasitic mites (Varroa destructor) that infect colonies of honey bees (Apis mellifera L.). ...

  18. Impedance Coordinative Control for Cascaded Converter in Bidirectional Application

    DEFF Research Database (Denmark)

    Tian, Yanjun; Deng, Fujin; Chen, Zhe;

    2015-01-01

    difference between forward and reversed power flow. This paper addresses the analysis with the topology of cascaded dual-active-bridge converter (DAB) with inverter, and the proposed control method can also be implemented in unidirectional applications and other general cascaded converter system...

  19. 76 FR 35241 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-06-16

    ...). As noted in a previous notice published in the Federal Register on September 23, 1975, 40 FR 43745... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of Etorphine Hydrochloride (9059), a basic class...

  20. 76 FR 12134 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-03-04

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Importer of Controlled Substances; Notice of Application Correction In notice document 2011-3945 appearing on pages 10067-10068 in the issue of Wednesday, February 23, 2011, make...

  1. 77 FR 35718 - Importer of Controlled Substances Notice of Application

    Science.gov (United States)

    2012-06-14

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF JUSTICE Drug Enforcement Administration Importer of Controlled Substances Notice of Application Correction In notice document 2012-14161, appearing on pages 35020-35021 in the issue of Tuesday, June 12, 2012, make...

  2. 78 FR 30329 - Importer of Controlled Substances, Notice of Application

    Science.gov (United States)

    2013-05-22

    ... (f). As noted in a previous notice published in the Federal Register on September 23, 1975, 40 FR... Enforcement Administration Importer of Controlled Substances, Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of Etorphine (except HCl) (9056), a basic class...

  3. 75 FR 64743 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-10-20

    ... a previous notice published in the Federal Register on September 23, 1975, (40 FR 43745-46), all... Enforcement Administration Importer of Controlled Substances; Notice of Application Pursuant to 21 U.S.C. 958... Administration (DEA) to be registered as an importer of Phenylacetone (8501), a basic class of...

  4. Model-Driven Development of Automation and Control Applications: Modeling and Simulation of Control Sequences

    Directory of Open Access Journals (Sweden)

    Timo Vepsäläinen

    2014-01-01

    Full Text Available The scope and responsibilities of control applications are increasing due to, for example, the emergence of industrial internet. To meet the challenge, model-driven development techniques have been in active research in the application domain. Simulations that have been traditionally used in the domain, however, have not yet been sufficiently integrated to model-driven control application development. In this paper, a model-driven development process that includes support for design-time simulations is complemented with support for simulating sequential control functions. The approach is implemented with open source tools and demonstrated by creating and simulating a control system model in closed-loop with a large and complex model of a paper industry process.

  5. Development and applications of Krotov method of global control improvement

    Science.gov (United States)

    Rasina, Irina V.; Trushkova, Ekaterina A.; Baturina, Olga V.; Bulatov, Alexander V.; Guseva, Irina S.

    2016-06-01

    This is a survey of works on main properties, application and development of the Krotov method of global control improvement very popular among researchers of modern problems in quantum physics and quantum chemistry, applying actively optimal control methods. The survey includes a brief description of the method in comparison with well known gradient method demonstrating such its serious advantage as absence of tuning parameters; investigations aimed to make its special version for the quantum system well defined and more effective; and generalization for wide classes of control systems, including the systems of heterogeneous structure.

  6. ADAPTIVE OUTPUT CONTROL: SUBJECT MATTER, APPLICATION TASKS AND SOLUTIONS

    Directory of Open Access Journals (Sweden)

    Alexey A. Bobtsov

    2013-01-01

    Full Text Available The problem of adaptive output control for parametric and functionally uncertain plants is considered. Application examples illustrating the practical use of the discussed theory are given along with the mathematical formulation of the problem. A brief review of adaptive output control methods, by both linear and non-linear systems, is presented and an extensive bibliography, in which the reader will find a detailed description of the specific algorithms and their properties, is represented. A new approach to the output control problem - a method of consecutive compensator - is considered in detail.

  7. Optimal control theory applications to management science and economics

    CERN Document Server

    Sethi, Suresh P

    2006-01-01

    Optimal control methods are used to determine the best ways to control a dynamic system. This book applies theoretical work to business management problems developed from the authors' research and classroom instruction. The thoroughly revised new edition has been refined with careful attention to the text and graphic material presentation. Chapters cover a range of topics including finance, production and inventory problems, marketing problems, machine maintenance and replacement, problems of optimal consumption of natural resources, and applications of control theory to economics. The book in

  8. Iterative Feedback Tuning in Fuzzy Control Systems. Theory and Applications

    Directory of Open Access Journals (Sweden)

    Stefan Preitl

    2006-07-01

    Full Text Available The paper deals with both theoretical and application aspects concerningIterative Feedback Tuning (IFT algorithms in the design of a class of fuzzy controlsystems employing Mamdani-type PI-fuzzy controllers. The presentation is focused on twodegree-of-freedom fuzzy control system structures resulting in one design method. Thestability analysis approach based on Popov’s hyperstability theory solves the convergenceproblems associated to IFT algorithms. The suggested design method is validated by realtimeexperimental results for a fuzzy controlled nonlinear DC drive-type laboratoryequipment.

  9. Controllable azimuthons of four-wave mixing and their applications

    Science.gov (United States)

    Wang, R. M.; Che, J. L.; Wang, X. P.; Lan, H. Y.; Wu, Z. K.; Zhang, Y. Q.; Zhang, Y. P.

    2014-08-01

    We report controllable azimuthons of four-wave mixing (FWM), which can be modulated by several parameters in experiment. The spot number, splitting depth, rotation angular velocity and direction of such azimuthons can be controlled by the frequency and intensity of the FWM signal or the dressing field through the cross-phase modulation due to atomic coherence. The intensity gain of the azimuthons can be modulated by frequency detuning through quantum parametric amplification. The quantum correlated FWM vortex is observed in experiment. We also discuss the applications of such controllable azimuthons in all-optical circulators, multiplexers (demultiplexers), routers, cross-connects and optical amplifiers.

  10. Structured Control of LPV Systems with Application to Wind Turbines

    DEFF Research Database (Denmark)

    Adegas, Fabiano Daher; Stoustrup, Jakob

    2012-01-01

    This paper deals with structured control of linear parameter varying systems (LPV) with application to wind turbines. Instead of attempting to reduce the problem to linear matrix inequalities (LMI), we propose to design the controllers via an LMI-based iterative algorithm. The proposed algorithm...... can synthesize structured controllers like decentralized, static output and reduced order output feedback for discrete-time LPV systems. Based on a coordinate decent, it relies on a sufficient matrix inequality condition extended with slack variables to an upper bound on the induced L2-norm...

  11. DRACULA: Dynamic range control for broadcasting and other applications

    Science.gov (United States)

    Gilchrist, N. H. C.

    The BBC has developed a digital processor which is capable of reducing the dynamic range of audio in an unobtrusive manner. It is ideally suited to the task of controlling the level of musical programs. Operating as a self-contained dynamic range controller, the processor is suitable for controlling levels in conventional AM or FM broadcasting, or for applications such as the compression of program material for in-flight entertainment. It can, alternatively, be used to provide a supplementary signal in DAB (digital audio broadcasting) for optional dynamic compression in the receiver.

  12. Engineering applications of discrete-time optimal control

    DEFF Research Database (Denmark)

    Vidal, Rene Victor Valqui; Ravn, Hans V.

    1990-01-01

    Many problems of design and operation of engineering systems can be formulated as optimal control problems where time has been discretisized. This is also true even if 'time' is not involved in the formulation of the problem, but rather another one-dimensional parameter. This paper gives a review...... of some well-known and new results in discrete time optimal control methods applicable to practical problem solving within engineering. Emphasis is placed on dynamic programming, the classical maximum principle and generalized versions of the maximum principle for optimal control of discrete time systems...

  13. Access Control of Web and Java Based Applications

    Science.gov (United States)

    Tso, Kam S.; Pajevski, Michael J.; Johnson, Bryan

    2011-01-01

    Cyber security has gained national and international attention as a result of near continuous headlines from financial institutions, retail stores, government offices and universities reporting compromised systems and stolen data. Concerns continue to rise as threats of service interruption, and spreading of viruses become ever more prevalent and serious. Controlling access to application layer resources is a critical component in a layered security solution that includes encryption, firewalls, virtual private networks, antivirus, and intrusion detection. In this paper we discuss the development of an application-level access control solution, based on an open-source access manager augmented with custom software components, to provide protection to both Web-based and Java-based client and server applications.

  14. Chaos in electric drive systems analysis control and application

    CERN Document Server

    Chau, K T

    2011-01-01

    In Chaos in Electric Drive Systems: Analysis, Control and Application authors Chau and Wang systematically introduce an emerging technology of electrical engineering that bridges abstract chaos theory and practical electric drives. The authors consolidate all important information in this interdisciplinary technology, including the fundamental concepts, mathematical modeling, theoretical analysis, computer simulation, and hardware implementation. The book provides comprehensive coverage of chaos in electric drive systems with three main parts: analysis, control and application. Corresponding drive systems range from the simplest to the latest types: DC, induction, synchronous reluctance, switched reluctance, and permanent magnet brushless drives.The first book to comprehensively treat chaos in electric drive systemsReviews chaos in various electrical engineering technologies and drive systemsPresents innovative approaches to stabilize and stimulate chaos in typical drivesDiscusses practical application of cha...

  15. M\\TiO₂ (M=Au, Ag) transparent aqueous sols and its application on polymeric surface antibacterial post-treatment.

    Science.gov (United States)

    Wu, Liangzhuan; Yu, Yuan; Song, Le; Zhi, Jinfang

    2015-05-15

    In this paper, we reported a simple and mild chemical method for synthesis of crystalline metal\\TiO2 (M=Au, Ag) transparent aqueous sols at low temperature (80°C). It should be found that the as-synthesized metal\\TiO2 sols could easily be coated on the flexible PET surfaces of the through the as-developed electroless-plating-like solution deposition (EPLSD) procedure. The as-prepared metal\\TiO2 sols and related flexible thin film were characterized by TEM, SEM, XRD, UV-vis, and FTIR analysis. The results showed that the Au and Ag nanoparticles can significantly improve the optical absorption properties of TiO2 due to the surface plasmon generated by the noble metal, which in turn enhanced the photo-induced antibacterial performance of the as-prepared metal\\TiO2 flexible film. Moreover, the photo-generated electrons could transfer between the metal and titanium dioxide under different irradiation (ultraviolet or visible light), which could significantly reduce the recombination of photo-induced electrons and holes, resulting in the better photo-induced antibacterial performance. Therefore, the EPLSD procedure may be used as a general polymeric surface antibacterial post-treatment procedure for preparing the metal\\TiO2 flexible film because of the noble metal enhanced antibacterial performance.

  16. Development of casting investment preventing blackening of noble metal alloys part 1. Application of developed investment for Ag-Pd-Cu-Au alloy.

    Science.gov (United States)

    Kakuta, Kiyoshi; Nakai, Akira; Goto, Shin-ichi; Wakamatsu, Yasushi; Yara, Atushi; Miyagawa, Yukio; Ogura, Hideo

    2003-03-01

    The objective of this study is to develop a casting investment that prevents the blackening of the cast surface of noble metal alloys. The experimental investments were prepared using a gypsum-bonded investment in which the metallic powders such as boron (B), silicon (Si), aluminum (Al) and titanium (Ti) were added as oxidizing agents. An Ag-Pd-Cu-Au alloy was cast into the mold made of the prepared investment. The effect of the addition of each metal powder was evaluated from the color difference between the as-cast surface and the polished surface of the cast specimen. The color of the as-cast surface approached that of the polished surface with increasing B and Al content. A lower mean value in the color difference was obtained at 0.25-1.00 mass% B content. B and Al are useful as an additive in a gypsum-bonded investment to prevent the blackening of an Ag-Pd-Cu-Au alloy. The effects of Si and Ti powder addition could not be found.

  17. Networked Control System Simulation Design and Its Application

    Institute of Scientific and Technical Information of China (English)

    A. B. Soglo; YANG Xianhui

    2006-01-01

    This paper presents a framework for networked control system simulation (NCSS) to enable the analysis of the influence of network transmissions on the performance of control systems. The simulation is composed of the network environment simulated using the network simulator, the control system component simulation using Matlab or C/C++, and an external application programming interface. To implement the plant (sensor), controller, and actuator nodes, an agent-based design is introduced, and a multi-agent networked control system is constructed. Therefore, the network simulator 2-26 (NS-2.26) release is extended by modifying the user data protocol (UDP) common header in order to support application data transmission between network nodes. Then, modifying the network topology parameters, networked control system simulations are analyzed for different parameter changes, such as the network bandwidth, the number of plant nodes, and the sampling period. An analysis of the influence of these parameters on network-induced delays and packet drop is made. The results show that the simulation system is an effective tool for the study of networked control systems.

  18. Control of Linear Parameter Varying Systems with Applications

    CERN Document Server

    Mohammadpour, Javad

    2012-01-01

    Control of Linear Parameter Varying Systems with Applications compiles state-of-the-art contributions on novel analytical and computational methods to address system modeling and identification, complexity reduction, performance analysis and control design for time-varying and nonlinear systems in the LPV framework. The book has an interdisciplinary character by emphasizing techniques that can be commonly applied in various engineering fields. It also includes a rich collection of illustrative applications in diverse domains to substantiate the effectiveness of the design methodologies and provide pointers to open research directions. The book is divided into three parts. The first part collects chapters of a more tutorial character on the background of LPV systems modeling and control. The second part gathers chapters devoted to the theoretical advancement of LPV analysis and synthesis methods to cope with the design constraints such as uncertainties and time delay. The third part of the volume showcases con...

  19. DARC: Next generation decentralized control framework for robot applications

    DEFF Research Database (Denmark)

    Kjærgaard, Morten; Andersen, Nils Axel; Ravn, Ole

    2013-01-01

    This paper presents DARC, a next generation control framework for robot applications. It is designed to be equally powerful in prototyping research projects and for building serious commercial robots running on low powered embedded hardware, thus closing the gab between research and industry. It ....... It incorporates several new techniques such as a decentralized peer-to-peer architecture, transparent network distribution of the control system, and automatic run-time supervision to guarantee robustness.......This paper presents DARC, a next generation control framework for robot applications. It is designed to be equally powerful in prototyping research projects and for building serious commercial robots running on low powered embedded hardware, thus closing the gab between research and industry...

  20. Indirect control of flexible demand for power system applications

    DEFF Research Database (Denmark)

    Sossan, Fabrizio

    Flexhouse, a facility of DTU Elektro for testing demand side management strategies, as experimental site. In the latter case, we develop four applications where flexible demand is required to support power system operations. The applications are: integration of the operation of flexible demand......This thesis addresses the topic of control of flexible demand to provide support to the operation of the electric power system. We focus on the indirect control approach, a framework that enables demand response by means of a consumption incentive signal. Initially, the concept of flexibility...... is defined and a classification of flexible electric loads is presented. In order to evaluate the potential of flexible demand, the storage capacity associated with the operation of a number domestic electric loads is quantified by means of simulations. Subsequently, the topic of indirect control of flexible...

  1. Formation of one-dimensional Ag-Au solid solution colloids with Au nanorods as seeds, their alloying mechanisms, and surface plasmon resonances

    Science.gov (United States)

    Guo, Tao; Tan, Yiwei

    2012-12-01

    In this work, one dimensional (1D) Ag-Au solid solution nanoalloys were synthesized by rapidly diffusing Ag into the preformed Au nanorod (AuNR) seeds at ambient temperature in aqueous solution. By varying the molar ratio of AgCl/AuNR (in gold atoms), two kinds of 1D Ag-Au alloy nanostructures with a narrow size distribution--AgAu nanowires and Ag33Au67 nanorods--could be obtained in high yields when NaCl and polyvinylpyrrolidone (PVP) were used as an additive and capping reagent, respectively. Based on HRTEM imaging combined with a series of control experiments, it is conceivable that vacancy/defect-motivated interdiffusion of Ag and Au atoms coupled with oxidative etching is a crucial stage in the mechanism responsible for this room-temperature alloying process, and the subsequent conjugation of the fused Ag-Au alloyed nanostructures is associated with the formation of the AgAu nanowires. The resulting 1D Ag-Au nanoalloys form stable colloidal dispersions and show unique localized surface plasmon resonance (LSPR) peaks in the ensemble extinction spectra.In this work, one dimensional (1D) Ag-Au solid solution nanoalloys were synthesized by rapidly diffusing Ag into the preformed Au nanorod (AuNR) seeds at ambient temperature in aqueous solution. By varying the molar ratio of AgCl/AuNR (in gold atoms), two kinds of 1D Ag-Au alloy nanostructures with a narrow size distribution--AgAu nanowires and Ag33Au67 nanorods--could be obtained in high yields when NaCl and polyvinylpyrrolidone (PVP) were used as an additive and capping reagent, respectively. Based on HRTEM imaging combined with a series of control experiments, it is conceivable that vacancy/defect-motivated interdiffusion of Ag and Au atoms coupled with oxidative etching is a crucial stage in the mechanism responsible for this room-temperature alloying process, and the subsequent conjugation of the fused Ag-Au alloyed nanostructures is associated with the formation of the AgAu nanowires. The resulting 1D Ag-Au

  2. Low-pressure ETEM Studies of Au assisted MgO Nanorod Growth

    DEFF Research Database (Denmark)

    Duchstein, Linus Daniel Leonhard; Damsgaard, Christian Danvad; Hansen, Thomas Willum;

    2014-01-01

    Environmental transmission electron microscopy (ETEM) studies MgO nanorod growth from Au catalyst nanoparticles in a controlled gas atmosphere have been performed, in order to elucidate the mobility of Au surface atoms and the configuration of the Au/MgO interface. MgO nanorod growth is driven...

  3. /Au Back Contacts

    Science.gov (United States)

    Paudel, Naba R.; Compaan, Alvin D.; Yan, Yanfa

    2014-08-01

    We report on the fabrication and characterization of CdTe thin-film solar cells with Cu-free MoO3- x /Au back contacts. CdTe solar cells with sputtered CdTe absorbers of thicknesses from 0.5 to 1.75 μm were fabricated on Pilkington SnO2:F/SnO2-coated soda-lime glasses coated with a 60- to 80-nm sputtered CdS layer. The MoO3- x /Au back contact layers were deposited by thermal evaporation. The incorporation of MoO3- x layer was found to improve the open circuit voltage ( V OC) but reduce the fill factor of the ultrathin CdTe cells. The V OC was found to increase as the CdTe thickness increased.

  4. Disturbance Accommodating Adaptive Control with Application to Wind Turbines

    Science.gov (United States)

    Frost, Susan

    2012-01-01

    Adaptive control techniques are well suited to applications that have unknown modeling parameters and poorly known operating conditions. Many physical systems experience external disturbances that are persistent or continually recurring. Flexible structures and systems with compliance between components often form a class of systems that fail to meet standard requirements for adaptive control. For these classes of systems, a residual mode filter can restore the ability of the adaptive controller to perform in a stable manner. New theory will be presented that enables adaptive control with accommodation of persistent disturbances using residual mode filters. After a short introduction to some of the control challenges of large utility-scale wind turbines, this theory will be applied to a high-fidelity simulation of a wind turbine.

  5. Improvements and applications of entrainment control for nonlinear dynamical systems.

    Science.gov (United States)

    Liu, Fang; Song, Qiang; Cao, Jinde

    2008-12-01

    This paper improves the existing entrainment control approaches and develops unified schemes to chaos control and generalized (lag, anticipated, and complete) synchronization of nonlinear dynamical systems. By introducing impulsive effects to the open-loop control method, we completely remove its restrictions on goal dynamics and initial conditions, and derive a sufficient condition to estimate the upper bound of impulsive intervals to ensure the global asymptotic stability. We then propose two effective ways to implement the entrainment strategy which combine open-loop and closed-loop control, and we prove that the feedback gains can be chosen according to a lower bound or be tuned with an adaptive control law. Numerical examples are given to verify the theoretical results and to illustrate their applications.

  6. GASICA: Generic Automated Stress Induction and Control ApplicationDesign of an application for controlling the stress state

    Directory of Open Access Journals (Sweden)

    Benny Van Der Vijgh

    2014-12-01

    Full Text Available 1.In a multitude of research and therapy paradigms it is relevant to know, and desirably to control, the stress state of a patient or participant. Examples include research paradigms in which the stress state is the dependent or independent variable, or therapy paradigms where this state indicates the boundaries of the therapy. To our knowledge, no application currently exists that focuses specifically on the automated control of the stress state while at the same time being generic enough to be used in various therapy and research purposes. Therefore, we introduce GASICA, an application aimed at the automated control of the stress state in a multitude of therapy and research paradigms. The application consists of three components: a digital stressor game, a set of measurement devices and a feedback model. These three components form a closed loop (called a biocybernetic loop by Pope, Bogart, & Bartolome, 1995 and Fairclough, 2009 that continuously presents an acute psychological stressor, measures several physiological responses to this stressor, and adjusts the stressor intensity based on these measurements by means of the feedback model, hereby aiming to control the stress state. In this manner GASICA presents multidimensional and ecological valid stressors, whilst continuously in control of the form and intensity of the presented stressors, aiming at the automated control of the stress state. Furthermore, the application is designed as a modular open-source application to easily implement different therapy and research tasks using a high-level programming interface and configuration file, and allows for the addition of (existing measurement equipment, making it usable for various paradigms.

  7. GASICA: generic automated stress induction and control application design of an application for controlling the stress state.

    Science.gov (United States)

    van der Vijgh, Benny; Beun, Robbert J; van Rood, Maarten; Werkhoven, Peter

    2014-01-01

    In a multitude of research and therapy paradigms it is relevant to know, and desirably to control, the stress state of a patient or participant. Examples include research paradigms in which the stress state is the dependent or independent variable, or therapy paradigms where this state indicates the boundaries of the therapy. To our knowledge, no application currently exists that focuses specifically on the automated control of the stress state while at the same time being generic enough to be used in various therapy and research purposes. Therefore, we introduce GASICA, an application aimed at the automated control of the stress state in a multitude of therapy and research paradigms. The application consists of three components: a digital stressor game, a set of measurement devices, and a feedback model. These three components form a closed loop (called a biocybernetic loop by Pope et al. (1995) and Fairclough (2009) that continuously presents an acute psychological stressor, measures several physiological responses to this stressor, and adjusts the stressor intensity based on these measurements by means of the feedback model, hereby aiming to control the stress state. In this manner GASICA presents multidimensional and ecological valid stressors, whilst continuously in control of the form and intensity of the presented stressors, aiming at the automated control of the stress state. Furthermore, the application is designed as a modular open-source application to easily implement different therapy and research tasks using a high-level programming interface and configuration file, and allows for the addition of (existing) measurement equipment, making it usable for various paradigms.

  8. LA DIVERSITÉ DÉPLOYÉE AU SEIN DE L’UNIVERSITÉ D’ENTREPRISE : L’APPLICATION CONCRÈTE D’UNE VALEUR ADOPTÉE PAR LA DIRECTION GÉNÉRALE

    Directory of Open Access Journals (Sweden)

    Virginia Drummond-Guitel

    2009-09-01

    Full Text Available La diversité devenue une valeur incontournable adoptée par les grands groupes, encore faut-t-il trouver les moyens concrets pour l’intégrer dans les pratiques des ressources humaines et dans les mentalités des personnes. Le présent papier a pour but de montrer comment les valeurs de la diversité adoptées par la direction générale ont été déclinées et appliquées dans un processus de sélection de candidats pour une formation continue au sein d’une grande organisation internationale. A travers l’application d’une méthode qualitative de recherche, 10 (dix dirigeants ayant conçu la formation et 42 (quarante-deux managers ayant suivi le programme confirment l’atteinte du but stratégique de cette formation, autrement dit, l’atteinte d’une vision partagée (SENGE, 1991, à travers la consolidation d’un fort sentiment d’appartenance à la culture organisationnelle (SCHEIN, 1995. Les managers ont été sélectionnés selon leurs différentes professions, cultures nationales et différents secteurs d’activités, confirmant ainsi une promotion de la diversité au sein de l’organisation.

  9. Antibacterial Au nanostructured surfaces

    Science.gov (United States)

    Wu, Songmei; Zuber, Flavia; Brugger, Juergen; Maniura-Weber, Katharina; Ren, Qun

    2016-01-01

    We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was information (ESI) available. See DOI: 10.1039/c5nr06157a

  10. A Mobile Application for Smart House Remote Control System

    CERN Document Server

    Rajabzadeh, Amir; Jahromi, Zahra Forootan

    2010-01-01

    At the start of the second decade of 21th century, the time has come to make the Smart Houses a reality for regular use. The different parts of a Smart House are researched but there are still distances from an applicable system, using the modern technology. In this paper we present an overview of the Smart House subsystems necessary for controlling the house using a mobile application efficiently and securely. The sequence diagram of the mobile application connecting to the server application and also the use-cases possible are presented. The challenges faced in designing the mobile application and illustrating the updated house top plane view in that application, are discussed and solutions are adapted for it. Finally the designed mobile application was implemented and the important sections of it were described, such as the interactive house top view map which indicates the status of the devices using predefined icons. The facilities to manage the scheduled tasks and defined rules are also implemented in t...

  11. Structurally-controlled nanomaterials for fuel cell catalysis and biomedical applications

    Science.gov (United States)

    Kamundi, Martha Mukiri

    Nanomaterials e.g. nanoporous metals (NPM) and nanoparticles (NPs) feature unique chemical and physical properties and make excellent candidates for catalysis, sensing, biomedicine etc. While NPs are generated through chemical synthesis, electrochemical deposition, vapor deposition, etc, NPM obtained through dealloying are gaining more attention as alternatives to NPs due to ease of fabrication, synthetic control, structural reproducibility, and enhanced conductivity. The focus of this dissertation is the development and implementation of electrochemical routes for synthesis, characterization and testing of nanoporous catalysts. An effort is made to understand structural and compositional factors associated with the dealloying behavior and surface area evolution of different types of AuxAg(1-x) alloys; bulk samples (single and poly crystals), thin films, large spherical particles and NPs. The dealloying critical potential differs according to the crystallinity and curvature of the alloys. All samples except NPs develop significant area increase upon dealloying. A green electrodeposition bath for AuxAg(1-x) alloy deposition is established using thiosulfate electrolyte. Then a set of electrochemical routines is employed for the synthesis of platinized nanoporous Au (Pt-NPG) catalyst on gold (Au) and glassy carbon (GC) electrodes. Platinization by 1-2 nm thick layers is sufficient to cover the NPG surface completely. NPG surface area is retained after platinization. Pt-NPG are tested in formic acid oxidation reaction, current densities of ~50 mA cm-2 , mass activities of ~3 A mg-1 (of combined Pt-Au catalyst) and durability of over 2600 cycles are observed. Activities aimed at densification of the AuxAg(1-x) cluster network normally deposited on GC to a nearly continuous structure are explored by seeding GC with Cu, Ag, Pd and Au using electroless and electrodeposition approaches prior to alloy electrodeposition. The best overall results are obtained by Pd and/or Au

  12. Synthesis of 4H/fcc-Au@Metal Sulfide Core-Shell Nanoribbons.

    Science.gov (United States)

    Fan, Zhanxi; Zhang, Xiao; Yang, Jian; Wu, Xue-Jun; Liu, Zhengdong; Huang, Wei; Zhang, Hua

    2015-09-02

    Although great advances on the synthesis of Au-semiconductor heteronanostructures have been achieved, the crystal structure of Au components is limited to the common face-centered cubic (fcc) phase. Herein, we report the synthesis of 4H/fcc-Au@Ag2S core-shell nanoribbon (NRB) heterostructures from the 4H/fcc Au@Ag NRBs via the sulfurization of Ag. Remarkably, the obtained 4H/fcc-Au@Ag2S NRBs can be further converted to a novel class of 4H/fcc-Au@metal sulfide core-shell NRB heterostructures, referred to as 4H/fcc-Au@MS (M = Cd, Pb or Zn), through the cation exchange. We believe that these novel 4H/fcc-Au@metal sulfide NRB heteronanostructures may show some promising applications in catalysis, surface enhanced Raman scattering, solar cells, photothermal therapy, etc.

  13. Plasmon assisted enhanced second-harmonic generation in single hybrid Au/ZnS nanowires

    Science.gov (United States)

    Jassim, Nadia M.; Wang, Kai; Han, Xiaobo; Long, Hua; Wang, Bing; Lu, Peixiang

    2017-02-01

    We demonstrate the enhanced second-harmonic generation (SHG) in single ZnS nanowires (NWs) attached with gold nanoparticles (Au NPs). The hybrid Au/ZnS NWs with different densities of the attached Au NPs were prepared by a simple solution impregnation method. By comparing with bare ZnS NWs, ∼1.3, ∼6.6, ∼7 and ∼2 times enhancement of SH intensity was achieved in the hybrid Au/ZnS NWs with low, moderate, high and ultrahigh densities of the attached Au NPs, respectively. The enhanced SHG in the hybrid Au/ZnS NWs is attributed to the strong local-fields from the Au cluster under the near-resonant condition, which is supported by the related dark-field scattering spectra. This hybrid Au/ZnS NWs provide a simple platform for enhancing nonlinear optical responses, which have potential applications in nano-probing and nano-sensing.

  14. Epitaxial growth of unusual 4H hexagonal Ir, Rh, Os, Ru and Cu nanostructures on 4H Au nanoribbons

    KAUST Repository

    Fan, Zhanxi

    2016-09-12

    Metal nanomaterials normally adopt the same crystal structure as their bulk counterparts. Herein, for the first time, the unusual 4H hexagonal Ir, Rh, Os, Ru and Cu nanostructures have been synthesized on 4H Au nanoribbons (NRBs) via solution-phase epitaxial growth under ambient conditions. Interestingly, the 4H Au NRBs undergo partial phase transformation from 4H to face-centered cubic (fcc) structures after the metal coating. As a result, a series of polytypic 4H/fcc bimetallic Au@M (M = Ir, Rh, Os, Ru and Cu) core-shell NRBs has been obtained. We believe that the rational crystal structure-controlled synthesis of metal nanomaterials will bring new opportunities for exploring their phase-dependent physicochemical properties and promising applications.

  15. ADAPTIVE CONTROLLER AND ITS APPLICATION IN FORCE SYSTEM OF ASYMMETRIC CYLINDER CONTROLLED BY SYMMETRIC VALVE

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Partial pressure, system vibration and asymmetric system dynamic performance exit in asymmetric cylinder controller by symmetric valve hydraulic system. To solve this problem in the force control system, model reference adaptive controller is designed using equilibrium point stability theory and output error equation polynomial. The reference model is selected in such a way that it meets the system dynamic performance. Hardware configuration of asymmetric cylinder controlled by asymmetric valve hydraulic system is replaced by intelligent control algorithm, thus the cost is lowered and easy to application. Simulation results demonstrate that the proposed adaptive control sheme has good adaptive ability and well solves asymmetric dynamic performance problem. The designed adaptive controller is fairly robust to load disturbance and system parameter variation.

  16. APPLICATION FEATURES OF FUZZY CONTROLLERS ON EXAMPLE OF DC MOTOR SPEED CONTROL

    Directory of Open Access Journals (Sweden)

    G. L. Demidova

    2016-09-01

    Full Text Available A prerequisite for the use of intelligent control methods, including algorithms of fuzzy logic, is increasing complexity in all industries, especially when parameters of technical systems while in operation vary in wide range. The paper provides comparative analysis of the basic types of common fuzzy direct action controllers on the example of speed control system in the DC motor drive. Design features of these types of fuzzy controllers are shown. Their comparison with traditional PI controller is carried out through the use of simulation, including the conditions of uncertainty expressed in changing of equivalent moment of inertia of the motor shaft. As a result, the conclusion about the feasibility of fuzzy PID-type controller application is made. The features of fuzzy controllers outlined in the paper can be summarized to more complex motor drive systems and to other non-linear systems that require the maintenance of any parameter within a given range.

  17. Développement d'une application de suivi de trajectoire : stage ingénieur du 2 mai au 17 août 2007

    OpenAIRE

    LABONNE, Sébastien; LABORATOIRE CENTRAL DES PONTS ET CHAUSSEES - LCPC; ECOLE CENTRALE DE NANTES

    2007-01-01

    Le projet RADARR s'inscrit dans la volonté d'améliorer la sécurité des routes en offrant aux gestionnaires un moyen de prévention des sites dangereux. Il vise particulièrement les routes secondaires qui enregistrent aujourd'hui encore un nombre élevé d'accidents mortels dus à l'état de la chaussée ou au manque de signalisation, notamment dans certains virages. L'objectif de ce projet consiste à déterminer la dangerosité d'un site en étudiant la vitesse des véhicules ainsi que leur trajectoire...

  18. Effect of Silicon on Activity Coefficients of Siderophile Elements (P, Au, Pd, As, Ge, Sb, and In) in Liquid Fe, with Application to Core Formation

    Science.gov (United States)

    Righter, K.; Pando, K.; Danielson, L. R.; Humayun, M.; Righter, M.; Lapen, T.; Boujibar, A.

    2016-01-01

    Earth's core contains approximately 10 percent light elements that are likely a combination of S, C, Si, and O, with Si possibly being the most abundant. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of P, Au, Pd, and many other SE between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle siderophile element concentrations.

  19. Novel photoswitchable dielectric properties on nanomaterials of electronic core-shell γ-FeOx@Au@fullerosomes for GHz frequency applications

    Science.gov (United States)

    Wang, Min; Su, Chefu; Yu, Tzuyang; Tan, Loon-Seng; Hu, Bin; Urbas, Augustine; Chiang, Long Y.

    2016-03-01

    We unexpectedly observed a large amplification of the dielectric properties associated with the photoswitching effect and the new unusual phenomenon of delayed photoinduced capacitor-like (i.e. electric polarization) behavior at the interface on samples of three-layered core-shell (γ-FeOx@AuNP)@[C60(>DPAF-C9)]n2 nanoparticles (NPs) in frequencies of 0.5-4.0 GHz. The detected relative dielectric constant amplification was initiated upon switching off the light followed by relaxation to give an excellent recyclability. These NPs having e--polarizable fullerosomic structures located at the outer layer were fabricated from highly magnetic core-shell γ-FeOx@AuNPs. Surface-stabilized 2 in a core-shell structure was found to be capable of photoinducing the surface plasmonic resonance (SPR) effect by white LED light. The accumulated SPR energy was subsequently transferred to the partially bilayered C60(>DPAF-C9) fullerosomic membrane layer in a near-field (~1.5 nm) region without producing radiation heat. Since the monostatic SAR signal is dielectric property-dependent, we used these measurements to provide evidence of derived reflectivity changes on a surface coated with 2 at 0.5-4.0 GHz upon illumination of LED white light. We found that a high, >99%, efficiency of response amplification in image amplitude can be achieved.We unexpectedly observed a large amplification of the dielectric properties associated with the photoswitching effect and the new unusual phenomenon of delayed photoinduced capacitor-like (i.e. electric polarization) behavior at the interface on samples of three-layered core-shell (γ-FeOx@AuNP)@[C60(>DPAF-C9)]n2 nanoparticles (NPs) in frequencies of 0.5-4.0 GHz. The detected relative dielectric constant amplification was initiated upon switching off the light followed by relaxation to give an excellent recyclability. These NPs having e--polarizable fullerosomic structures located at the outer layer were fabricated from highly magnetic core-shell γ-FeOx@Au

  20. Mise en evidence de mouvements de sable a partir d'images satellitales ; application au piemont sud de l'atlas saharien(Algerie

    Directory of Open Access Journals (Sweden)

    ABDELLAOUI ABDELKADER

    2010-09-01

    Full Text Available La zone d’étude se localise au piémont sud de l’Atl as saharien (Algérie et concerne le site de la vil le de Laghouat et ses environs limitrophes. Les principaux éléments orogr aphiques sont représentés par Djebel Ahmar (883m a u Sud-Ouest, Djebel Oum Deloua (1023m au Nord-Ouest, formant un syncli nal perché, et un peu plus au Nord-Ouest le grand s ynclinal du Milok, de direction atlasique. Le principal cours d’eau qui t raverse la zone Est Oued M’zi d’orientation Nord-Ou est-Sud-Est, empruntant par la suite une direction globale sous-latitudinale, à p artir de l’extrémité Sud-Ouest du Djebel Oum Deloua . Son affluent le plus important est Oued Messaad, avec un écoulement Sud-Ouest-Nord -Est. Cette zone comprend différentes formes et formation s sableuses dont la disposition est tributaire des ensembles orographiques, de la topographie de détail et des d irections du transport éolien. La population de Laghouat, ville présaharienne, est passée d’environ 6000 habitants en 1830 à 42800 ha bitants en 1977 et à 119043 habitants en 2003, soit une variation d e 178% (c’est-à-dire une multiplication par un fact eur de 2,8 sur une période de 26 ans entre 1977 et 2003. L’extension du bâti, sous la pression des besoins croissants en logemen ts, arrive à l’heure actuelle aux limites des massifs avoisinants (dépôt s sableux sur les flancs et des zones inondables. Le sable constitue ainsi un facteur de risque permanent de plus en plus ressent i pour la santé publique, la qualité de vie, mais é galement un danger pour les zones de mise en valeur agricole, notamment du Mekh areg à l’Est de Laghouat. Il devient alors pertinen t de mettre au point un moyen de localisation et de surveillance de la d ynamique des édifices de sable dans la région. Les traitements conventionnels de l’image satellita le (compositions colorées, indices thématiques ne permettent pas de différencier correctement le voile sableux

  1. Preparation of radioactive core-shell type 198Au@SiO2 nanoparticles as a radiotracer for industrial process applications.

    Science.gov (United States)

    Jung, Sung-Hee; Kim, Kyo-Il; Ryu, Jung-Ho; Choi, Seong-Ho; Kim, Jong-Bum; Moon, Jin-Ho; Jin, Joon-Ha

    2010-06-01

    Silica-coated gold nanoparticles produced by gamma-ray irradiation were bombarded with neutrons in a nuclear reactor in order to activate gold nuclides into Au-198 emitting gamma radiation of 0.412-1.088 MeV. The particle size ranges from 20 to 200 nm. The physical integrity of the particles was examined by TEM before and after the neutron irradiation and the silica-gold particles were not affected in terms of structural appearance under gamma radiation environment. The gamma emitting NPs can be utilized as a tracer in petrochemical and refinery industrial processes where the internal temperature is extremely high and the conventional organic radioactive labeled compound would be decomposed.

  2. Extracted Electronic Parameters of a Novel Ag/SnO2:In/Si/Au Schottky Diode for Solar Cell Application

    Directory of Open Access Journals (Sweden)

    Mostefa Benhaliliba

    2015-06-01

    Full Text Available The effect of indium on the characteristics of Ag / SnO2 : In / Si / Au Schottky diode (SD is studied. The electronic parameters, ideal factor, the effective barrier, flat band barrier height, the series resistance, the saturation current density of the diodes were extracted from the current voltage (I-V and capacitance voltage (C-V characteristics. The series resistance (Rs determined by Cheung method increases (508-534 Ω with In doping level while the barrier height still constant around 0.57 V. Norde approximation gives a similar barrier height values of 0.69 V but the series resistance reaches higher values of 5500 Ω.

  3. Application of a pilot control banding tool for risk level assessment and control of nanoparticle exposures

    Energy Technology Data Exchange (ETDEWEB)

    Paik, S Y; Zalk, D M; Swuste, P

    2008-03-03

    Control Banding (CB) strategies offer simplified solutions for controlling worker exposures to constituents that are found in the workplace in the absence of firm toxicological and exposure data. These strategies may be particularly useful in nanotechnology applications, considering the overwhelming level of uncertainty over what nanomaterials and nanotechnologies present as potential work-related health risks, what about these materials might lead to adverse toxicological activity, how risk related to these might be assessed, and how to manage these issues in the absence of this information. This study introduces a pilot CB tool or 'CB Nanotool' that was developed specifically for characterizing the health aspects of working with engineered nanoparticles and determining the level of risk and associated controls for five ongoing nanotechnology-related operations being conducted at two Department of Energy (DOE) research laboratories. Based on the application of the CB Nanotool, four of the five operations evaluated in this study were found to have implemented controls consistent with what was recommended by the CB Nanotool, with one operation even exceeding the required controls for that activity. The one remaining operation was determined to require an upgrade in controls. By developing this dynamic CB Nanotool within the realm of the scientific information available, this application of CB appears to be a useful approach for assessing the risk of nanomaterial operations, providing recommendations for appropriate engineering controls, and facilitating the allocation of resources to the activities that most need them.

  4. Applications of active adaptive noise control to jet engines

    Science.gov (United States)

    Shoureshi, Rahmat; Brackney, Larry

    1993-01-01

    During phase 2 research on the application of active noise control to jet engines, the development of multiple-input/multiple-output (MIMO) active adaptive noise control algorithms and acoustic/controls models for turbofan engines were considered. Specific goals for this research phase included: (1) implementation of a MIMO adaptive minimum variance active noise controller; and (2) turbofan engine model development. A minimum variance control law for adaptive active noise control has been developed, simulated, and implemented for single-input/single-output (SISO) systems. Since acoustic systems tend to be distributed, multiple sensors, and actuators are more appropriate. As such, the SISO minimum variance controller was extended to the MIMO case. Simulation and experimental results are presented. A state-space model of a simplified gas turbine engine is developed using the bond graph technique. The model retains important system behavior, yet is of low enough order to be useful for controller design. Expansion of the model to include multiple stages and spools is also discussed.

  5. Advanced discrete-time control designs and applications

    CERN Document Server

    Abidi, Khalid

    2015-01-01

    This book covers a wide spectrum of systems such as linear and nonlinear multivariable systems as well as control problems such as disturbance, uncertainty and time-delays. The purpose of this book is to provide researchers and practitioners a manual for the design and application of advanced discrete-time controllers.  The book presents six different control approaches depending on the type of system and control problem. The first and second approaches are based on Sliding Mode control (SMC) theory and are intended for linear systems with exogenous disturbances. The third and fourth approaches are based on adaptive control theory and are aimed at linear/nonlinear systems with periodically varying parametric uncertainty or systems with input delay. The fifth approach is based on Iterative learning control (ILC) theory and is aimed at uncertain linear/nonlinear systems with repeatable tasks and the final approach is based on fuzzy logic control (FLC) and is intended for highly uncertain systems with heuristi...

  6. Controllable Femtosecond Laser-Induced Dewetting for Plasmonic Applications

    CERN Document Server

    Makarov, Sergey V; Mukhin, Ivan S; Shishkin, Ivan I; Zuev, Dmitriy A; Mozharov, Alexey M; Krasnok, Alexander E; Belov, Pavel A

    2015-01-01

    Dewetting of thin metal films is one of the most widespread method for functional plasmonic nanostructures fabrication. However, simple thermal-induced dewetting does not allow to control degree of nanostructures order without additional lithographic process steps. Here we propose a novel method for lithography-free and large-scale fabrication of plasmonic nanostructures via controllable femtosecond laser-induced dewetting. The method is based on femtosecond laser surface pattering of a thin film followed by a nanoscale hydrodynamical instability, which is found to be very controllable under specific irradiation conditions. We achieve control over degree of nanostructures order by changing laser irradiation parametrs and film thickness. This allowed us to exploit the method for the broad range of applications: resonant light absorbtion and scattering, sensing, and potential improving of thin-film solar cells.

  7. PLC-Based Pressure Control in Multi-Pump Applications

    Directory of Open Access Journals (Sweden)

    Vodovozov Valery

    2015-12-01

    Full Text Available The paper is devoted to the centrifugal pumps represented the most popular type of pumping equipment used in different areas. The pressure control approach for variable speed driven (VSD parallel connected centrifugal pumps is reported. The goal of the study is optimization of some quality indices, such as efficiency, consumed power, productivity, energy carrier temperature, heat irradiation, etc. One of them – efficiency – has been studied in the paper more carefully. The mathematical model of pumping process is discussed and a vector-matrix description of the multi-pump application is given. The program-based pressure control system is developed which productivity is changed by regulating the number of working pumps. The paper introduces new pressure control algorithms based on the working point estimation intended for programmable logical controllers (PLC. Experiments prove correctness of the offered methodology.

  8. Control of coupled oscillator networks with application to microgrid technologies.

    Science.gov (United States)

    Skardal, Per Sebastian; Arenas, Alex

    2015-08-01

    The control of complex systems and network-coupled dynamical systems is a topic of vital theoretical importance in mathematics and physics with a wide range of applications in engineering and various other sciences. Motivated by recent research into smart grid technologies, we study the control of synchronization and consider the important case of networks of coupled phase oscillators with nonlinear interactions-a paradigmatic example that has guided our understanding of self-organization for decades. We develop a method for control based on identifying and stabilizing problematic oscillators, resulting in a stable spectrum of eigenvalues, and in turn a linearly stable synchronized state. The amount of control, that is, number of oscillators, required to stabilize the network is primarily dictated by the coupling strength, dynamical heterogeneity, and mean degree of the network, and depends little on the structural heterogeneity of the network itself.

  9. Neuro-fuzzy predictive control for nonlinear application

    Institute of Scientific and Technical Information of China (English)

    CHEN Dong-xiang; WANG Gang; LV Shi-xia

    2008-01-01

    Aiming at the unsatisfactory dynamic performances of conventional model predictive control (MPC) in a highly nonlinear process, a scheme employed the fuzzy neural network to realize the nonlinear process is proposed. The neuro-fuzzy predictor has the capability of achieving high predictive accuracy due to its nonlinear mapping and interpolation features, and adaptively updating network parameters by a learning procedure to re-duce the model errors caused by changes of the process under control. To cope with the difficult problem of non-linear optimization, Pepanaqi method was applied to search the optimal or suboptimal solution. Comparisons were made among the objective function values of alternatives in initial space. The search was then confined to shrink the smaller region according to results of comparisons. The convergent point was finally approached to be considered as the optimal or suboptimal solution. Experimental results of the neuro-fuzzy predictive control for drier application reveal that the proposed control scheme has less tracking errors and can smooth control actions, which is applicable to changes of drying condition.

  10. Application of model based control to robotic manipulators

    Science.gov (United States)

    Petrosky, Lyman J.; Oppenheim, Irving J.

    1988-01-01

    A robot that can duplicate humam motion capabilities in such activities as balancing, reaching, lifting, and moving has been built and tested. These capabilities are achieved through the use of real time Model-Based Control (MBC) techniques which have recently been demonstrated. MBC accounts for all manipulator inertial forces and provides stable manipulator motion control even at high speeds. To effectively demonstrate the unique capabilities of MBC, an experimental robotic manipulator was constructed, which stands upright, balancing on a two wheel base. The mathematical modeling of dynamics inherent in MBC permit the control system to perform functions that are impossible with conventional non-model based methods. These capabilities include: (1) Stable control at all speeds of operation; (2) Operations requiring dynamic stability such as balancing; (3) Detection and monitoring of applied forces without the use of load sensors; (4) Manipulator safing via detection of abnormal loads. The full potential of MBC has yet to be realized. The experiments performed for this research are only an indication of the potential applications. MBC has no inherent stability limitations and its range of applicability is limited only by the attainable sampling rate, modeling accuracy, and sensor resolution. Manipulators could be designed to operate at the highest speed mechanically attainable without being limited by control inadequacies. Manipulators capable of operating many times faster than current machines would certainly increase productivity for many tasks.

  11. Cognitive interference modeling with applications in power and admission control

    KAUST Repository

    Mahmood, Nurul Huda

    2012-10-01

    One of the key design challenges in a cognitive radio network is controlling the interference generated at coexisting primary receivers. In order to design efficient cognitive radio systems and to minimize their unwanted consequences, it is therefore necessary to effectively control the secondary interference at the primary receivers. In this paper, a generalized framework for the interference analysis of a cognitive radio network where the different secondary transmitters may transmit with different powers and transmission probabilities, is presented and various applications of this interference model are demonstrated. The findings of the analytical performance analyses are confirmed through selected computer-based Monte-Carlo simulations. © 2012 IEEE.

  12. Nanosilicon properties, synthesis, applications, methods of analysis and control

    CERN Document Server

    Ischenko, Anatoly A; Aslalnov, Leonid A

    2015-01-01

    Nanosilicon: Properties, Synthesis, Applications, Methods of Analysis and Control examines the latest developments on the physics and chemistry of nanosilicon. The book focuses on methods for producing nanosilicon, its electronic and optical properties, research methods to characterize its spectral and structural properties, and its possible applications. The first part of the book covers the basic properties of semiconductors, including causes of the size dependence of the properties, structural and electronic properties, and physical characteristics of the various forms of silicon. It presents theoretical and experimental research results as well as examples of porous silicon and quantum dots. The second part discusses the synthesis of nanosilicon, modification of the surface of nanoparticles, and properties of the resulting particles. The authors give special attention to the photoluminescence of silicon nanoparticles. The third part describes methods used for studying and controlling the structure and pro...

  13. A Modular Integrated RFID System for Inventory Control Applications

    Directory of Open Access Journals (Sweden)

    Ross Bunker

    2017-01-01

    Full Text Available Recent advances in single-board computer technology have allowed for lightweight, power-efficient devices, such as the Raspberry Pi, to take the place of desktop PCs in certain applications. This has the potential to disrupt the way many current systems are structured, particularly for inventory management and control applications. In this paper, we explore the design and topology of a modular Radio frequency identification (RFID system for inventory management comprised of self-contained, autonomous scanning, and stationary control PCs in a handheld/portable configuration. While similar solutions for such a system may exist on the commercial market, this proposed development provides a template for an open source flexible, low-cost solution that can be easily expanded to meet the needs of businesses with large and small inventories.

  14. Adaptive mode control in few mode fibers and its applications

    Science.gov (United States)

    Ashry, Islam; Lu, Peng; Xu, Yong

    2016-10-01

    With the development of mode-division-multiplexing (MDM), few mode fibers (FMFs) have found a wide range of applications in optical sensing and communications. However, how to precisely control the mode composition of optical signals in FMFs remains a difficult challenge. In this paper, we present an adaptive mode control method that can selectively excite the linearly polarized (LP) mode within the FMF. The method is based on using optical pulses reflected by a fiber Bragg grating (FBG) for wavefront optimization. Two potential applications are discussed. First, we theoretically demonstrate the feasibility of large scale multiplexing of absorption based fiber optical sensors. Second, we discuss the possibility of using mode dependent loss to reconstruct the spatial distributions of absorptive chemicals diffused within a FMF.

  15. Applications of monolithic fiber interferometers and actively controlled fibers

    OpenAIRE

    Rugeland, Patrik

    2013-01-01

    The objective of this thesis was to develop applications of monolithic fiber devices and actively controlled fibers. A special twin-core fiber known as a ‘Gemini’ fiber was used to construct equal arm-length fiber interferometers, impervious to temperature and mechanical perturbations. A broadband add/drop multiplexer was constructed by inscribing fiber Bragg gratings in the arms of a Gemini Mach-Zehnder interferometer. A broadband interferometric nanosecond switch was constructed from a micr...

  16. Fractional order PID controller for improvement of PMSM speed control in aerospace applications

    Science.gov (United States)

    Saraji, Ali Motalebi; Ghanbari, Mahmood

    2014-12-01

    Because of the benefits reduced size, cost and maintenance, noise, CO2 emissions and increased control flexibility and precision, to meet these expectations, electrical equipment increasingly utilize in modern aircraft systems and aerospace industry rather than conventional mechanic, hydraulic, and pneumatic power systems. Electric motor drives are capable of converting electrical power to drive actuators, pumps, compressors, and other subsystems at variable speeds. In the past decades, permanent magnet synchronous motor (PMSM) and brushless dc (BLDC) motor were investigated for aerospace applications such as aircraft actuators. In this paper, the fractional-order PID controller is used in the design of speed loop of PMSM speed control system. Having more parameters for tuning fractional order PID controller lead to good performance ratio to integer order. This good performance is shown by comparison fractional order PID controller with the conventional PI and tuned PID controller by Genetic algorithm in MATLAB soft wear.

  17. The application of active noise control technology to reduce noise from air pollution control equipment

    Energy Technology Data Exchange (ETDEWEB)

    Depies, C. R.; Kapsos, D. W.

    1996-08-01

    The basic concept of active noise control, i. e. to create a noise field in a space in order to destructively interfere with an existing noise, and in the process create a quieter space, was explained. The manner in which noise control technology can be used in air pollution control equipment was described and guidelines for application were provided. A number of case studies were used to illustrate the suitability of active noise control for low frequency noise problems, especially in the area of air pollution control equipment. Impressive reduction of low frequency noise, energy efficiency, ability to retrofit into an existing duct system, and the hardware`s insensitivity to dirty exhaust environments were cited as the principal reasons for the success of active noise control technology over more traditional in-line passive silencers. 1 ref., 8 figs.

  18. Fractional order PID controller for improvement of PMSM speed control in aerospace applications

    Energy Technology Data Exchange (ETDEWEB)

    Saraji, Ali Motalebi [Young Researchers and Elite Club, AliAbad Katoul Branch, Islamic Azad University, AliAbad Katoul (Iran, Islamic Republic of); Ghanbari, Mahmood [Department of Electrical Engineering, AliAbad Katoul Branch, Islamic Azad University, AliAbad Katoul (Iran, Islamic Republic of)

    2014-12-10

    Because of the benefits reduced size, cost and maintenance, noise, CO2 emissions and increased control flexibility and precision, to meet these expectations, electrical equipment increasingly utilize in modern aircraft systems and aerospace industry rather than conventional mechanic, hydraulic, and pneumatic power systems. Electric motor drives are capable of converting electrical power to drive actuators, pumps, compressors, and other subsystems at variable speeds. In the past decades, permanent magnet synchronous motor (PMSM) and brushless dc (BLDC) motor were investigated for aerospace applications such as aircraft actuators. In this paper, the fractional-order PID controller is used in the design of speed loop of PMSM speed control system. Having more parameters for tuning fractional order PID controller lead to good performance ratio to integer order. This good performance is shown by comparison fractional order PID controller with the conventional PI and tuned PID controller by Genetic algorithm in MATLAB soft wear.

  19. Nonlinear time-series-based adaptive control applications

    Science.gov (United States)

    Mohler, R. R.; Rajkumar, V.; Zakrzewski, R. R.

    1991-01-01

    A control design methodology based on a nonlinear time-series reference model is presented. It is indicated by highly nonlinear simulations that such designs successfully stabilize troublesome aircraft maneuvers undergoing large changes in angle of attack as well as large electric power transients due to line faults. In both applications, the nonlinear controller was significantly better than the corresponding linear adaptive controller. For the electric power network, a flexible AC transmission system with series capacitor power feedback control is studied. A bilinear autoregressive moving average reference model is identified from system data, and the feedback control is manipulated according to a desired reference state. The control is optimized according to a predictive one-step quadratic performance index. A similar algorithm is derived for control of rapid changes in aircraft angle of attack over a normally unstable flight regime. In the latter case, however, a generalization of a bilinear time-series model reference includes quadratic and cubic terms in angle of attack.

  20. Corrosion properties of Ag-Au-Cu-Pd system alloys containing indium.

    Science.gov (United States)

    Hattori, Masayuki; Tokizaki, Teruhiko; Matsumoto, Michihiko; Oda, Yutaka

    2010-01-01

    In this study, the corrosion resistance of Ag-Au-Cu-Pd system alloys consisting of 5 or 10 mass% indium was evaluated. Levels of element release and tarnish were determined and electrochemical measurements performed. Results were compared with those for commercial silver-palladium-gold alloy. In terms of electrochemical behavior, the transpassive potential of these experimental alloys was 168-248mV. Experimental alloys with 25 mass% Au showed similar corrosion resistance to control gold-silver-palladium alloy. Amount of released elements was 14-130microg/cm(2) at 7 days, which is in the allowable range for dental alloys. Addition of indium to Ag-Au-Cu-10mass%Pd system alloys was effective in increasing resistance to tarnish and alloys containing 10 mass% of indium showed a minimal decrease in L(*) values after immersion. These findings indicate that 25Au-37.5Ag-15Cu-10Pd-2Zn-10In-0.5Ir alloy is applicable in dental practice.

  1. Electrodeposition of Various Au Nanostructures on Aligned Carbon Nanotubes as Highly Sensitive Nanoelectrode Ensembles

    Science.gov (United States)

    Fayazfar, H.; Afshar, A.; Dolati, A.

    2015-05-01

    An efficient method has been developed to synthesize well-aligned multi-walled carbon nanotubes (MWCNTs) on a conductive Ta substrate by chemical vapor deposition. Free-standing MWCNTs arrays were functionalized through electrochemical oxidation with the formation of hydroxyl and carboxyl functional groups. Facile template-free electrochemical routes were then developed for the shape-selective synthesis of less-common Au nanostructures, including flower, sphere, dendrite, rod, sheet, and cabbage onto the aligned MWCNTs at room temperature. Especially, among all the synthesis methods for Au nanocrystals, this is the first report using electrochemical technique to synthesize wide variety shapes of gold nanostructures (GNs) onto the aligned MWCNTs. The morphology of electrodeposited Au nanostructures was controlled by adjustment of the deposition time and potential, the number of potential cycles, the kind of deposition bath, and electrodeposition method. Transmission electron microscopy and field-emission scanning electron microscopy were used to characterize the products. Cyclic voltammograms showed that the MWCNT/Ta electrodes modified with GNs have higher sensitivity compared to the unmodified electrodes in the presence of Fe2+/Fe3+ redox couple. These kinds of aligned-CNT/Au nanostructure hybrid materials introduced by these efficient and simple electrochemical methods could lead to the development of a new generation device for ultrasensitive catalytic and biological application.

  2. L’olivier au Maroc

    Directory of Open Access Journals (Sweden)

    El Mouhtadi Issam

    2014-03-01

    Full Text Available L’olivier est une culture traditionnelle sur le pourtour de la Méditerranée. Il est donc naturel de trouver cet arbre au Maroc où il est présent depuis des siècles. Cultivé surtout traditionnellement jusqu’à ses dernières années, il fait l’objet maintenant d’un plan de valorisation très ambitieux pour non seulement garder le Royaume à son niveau actuel (2e producteur mondial pour l’olive de conserve et 6e pour l’huile d’olive mais pour conquérir de nouveaux marchés au niveau mondial et profiter ainsi de l’engouement que connaît cette huile reconnue pour ses bienfaits. Le plan national « Maroc Vert » permet ainsi, grâce à des subventions conséquentes, non seulement de renouveler les vergers existant avec la variété traditionnelle picholine du Maroc, mais également la plantation de nouvelles variétés en super-intensif dans le but d’industrialiser au maximum de nouveaux vergers. Il en est de même pour la transformation des olives en huile de bonne qualité avec la mise en place d’unités de trituration modernes qui doivent supplanter à terme la multitude de « maâsra » et réduire ainsi l’impact environnemental dû aux margines. L’olive ne sera plus dans l’avenir que représentée par son huile et ses formes comestibles, mais les résidus de son extraction seront valorisés soit sous forme de combustible élaboré pour le grignon, soit sous forme d’une base de chimie verte pour les sous-produits du raffinage. D’autres applications sont actuellement à l’étude, car le Maroc à compris, comme tous les autres grands pays producteurs, que l’olive était un nouveau gisement de richesses.

  3. Case studies on design, simulation and visualization of control and measurement applications using REX control system

    Science.gov (United States)

    Ozana, Stepan; Pies, Martin; Docekal, Tomas

    2016-06-01

    REX Control System is a professional advanced tool for design and implementation of complex control systems that belongs to softPLC category. It covers the entire process starting from simulation of functionality of the application before deployment, through implementation on real-time target, towards analysis, diagnostics and visualization. Basically it consists of two parts: the development tools and the runtime system. It is also compatible with Simulink environment, and the way of implementation of control algorithm is very similar. The control scheme is finally compiled (using RexDraw utility) and uploaded into a chosen real-time target (using RexView utility). There is a wide variety of hardware platforms and real-time operating systems supported by REX Control System such as for example Windows Embedded, Linux, Linux/Xenomai deployed on SBC, IPC, PAC, Raspberry Pi and others with many I/O interfaces. It is modern system designed both for measurement and control applications, offering a lot of additional functions concerning data archiving, visualization based on HTML5, and communication standards. The paper will sum up possibilities of its use in educational process, focused on control of case studies of physical models with classical and advanced control algorithms.

  4. Chaos control using an adaptive fuzzy sliding mode controller with application to a nonlinear pendulum

    Energy Technology Data Exchange (ETDEWEB)

    Bessa, Wallace M. [Universidade Federal do Rio Grande do Norte, Department of Mechanical Engineering, Campus Universitario Lagoa Nova, 59072-970 Natal, RN (Brazil)], E-mail: wmbessa@ufrnet.br; Paula, Aline S. de [Universidade Federal do Rio de Janeiro, COPPE - Department of Mechanical Engineering, P.O. Box 68.503, 21941-972 Rio de Janeiro, RJ (Brazil)], E-mail: alinesp27@gmail.com; Savi, Marcelo A. [Universidade Federal do Rio de Janeiro, COPPE - Department of Mechanical Engineering, P.O. Box 68.503, 21941-972 Rio de Janeiro, RJ (Brazil)], E-mail: savi@mecanica.ufrj.br

    2009-10-30

    Chaos control may be understood as the use of tiny perturbations for the stabilization of unstable periodic orbits embedded in a chaotic attractor. The idea that chaotic behavior may be controlled by small perturbations of physical parameters allows this kind of behavior to be desirable in different applications. In this work, chaos control is performed employing a variable structure controller. The approach is based on the sliding mode control strategy and enhanced by an adaptive fuzzy algorithm to cope with modeling inaccuracies. The convergence properties of the closed-loop system are analytically proven using Lyapunov's direct method and Barbalat's lemma. As an application of the control procedure, a nonlinear pendulum dynamics is investigated. Numerical results are presented in order to demonstrate the control system performance. A comparison between the stabilization of general orbits and unstable periodic orbits embedded in chaotic attractor is carried out showing that the chaos control can confer flexibility to the system by changing the response with low power consumption.

  5. Au pairs on Facebook

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2016-01-01

    Ethnographers are increasingly making use of Facebook to acquire access and general acquaintance with their field of study. However, little has been written on how Facebook is used methodologically in research that does not have social media sites as the main focus of interest. This article argues...... that engagement with Facebook as a methodological tool can be useful in research among migrants in highly politicised fields. Pointing to a discursive construction of Filipina au pairs as victims of labour exploitation, the article shows how fieldwork on Facebook enables the exploration of the ways in which...... and on Facebook....

  6. Structural, electrical and magnetic properties of single Au-Ni/NiO-Au nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Steinweg, Corinna; Sewcz, Rene; Baldus, Sabrina; Fischer, Saskia F. [Werkstoffe und Nanoelektronik, Ruhr-Universitaet Bochum (Germany); Daub, Mihaela [Max-Planck-Institut fuer Mikrostrukturphysik, Halle (Germany); Nielsch, Kornelius [Multifunctional Nanostructures, Universitaet Hamburg (Germany)

    2010-07-01

    Ferromagnetic metallic nanowires are of high interest for magnetic sensing and storage applications. However, due to surface oxidation of the nanowires electrical contacts easily lead to high-contact resistances of a few k{omega}. Here, we present multisegmented Au-Ni(NiO)-Au nanowires with a direct Au-Ni interface. Individual nanowires were laterally contacted in a four-terminal geometry via optical lithography, electron-beam lithography, thermal evaporation and lift-off patterning. The nanowires exhibit low-ohmic contacts of about 20 {omega}. The resistivity decreases with the temperature (300 K to 4.2 K) and is in the order of that of high-purity bulk nickel. The longitudinal anisotropic magnetoresistance (AMR) is about 1.5 % at 80 K and decreases with higher temperatures, 0.5 % at 300 K. The coercive field and the AMR are investigated for different angles between the current and magnetic field.

  7. Charge transport through O-deficient Au-MgO-Au junctions

    KAUST Repository

    Fadlallah, M. M.

    2009-12-29

    Metal-oxide heterostructures have been attracting considerable attention in recent years due to various technological applications. We present results of electronic structure and transport calculations for the Au-MgO-Au (metal-insulator-metal) heterostructure based on density-functional theory and the nonequilibrium Green’s functions method. The dependence of the conductance of the heterostructure on the thickness of the MgO interlayer and the interface spacing is studied. In addition, we address the effects of O vacancies. We observe deviations from an exponentially suppressed conductance with growing interlayer thickness caused by Au-O chemical bonds. Electronic states tracing back to O vacancies can increase the conductance. Furthermore, this effect can be enhanced by enlarging the interface spacing as the vacancy induced Mg states are shifted toward the Fermi energy.

  8. Genome Wide Transcriptome Analysis reveals ABA mediated response in Arabidopsis during Gold (AuCl4- treatment

    Directory of Open Access Journals (Sweden)

    Devesh eShukla

    2014-11-01

    Full Text Available The unique physico-chemical properties of gold nanoparticles (AuNPs find manifold applications in diagnostics, medicine and catalysis. Chemical synthesis produces reactive AuNPs and generates hazardous by-products. Alternatively, plants can be utilized to produce AuNPs in an eco-friendly manner. To better control the biosynthesis of AuNPs, we need to first understand the detailed molecular response induced by AuCl4- In this study, we carried out global transcriptome analysis in root tissue of Arabidopsis grown for 12- hours in presence of gold solution (HAuCl4 using the novel unbiased Affymetrix exon array. Transcriptomics analysis revealed differential regulation of a total of 704 genes and 4900 exons. Of these, 492 and 212 genes were up- and downregulated, respectively. The validation of the expressed key genes, such as glutathione-S-transferases, auxin responsive genes, cytochrome P450 82C2, methyl transferases, transducin (G protein beta subunit, ERF transcription factor, ABC, and MATE transporters, was carried out through quantitative RT-PCR. These key genes demonstrated specific induction under AuCl4- treatment relative to other heavy metals, suggesting a unique plant-gold interaction. GO enrichment analysis reveals the upregulation of processes like oxidative stress, glutathione binding, metal binding, transport, and plant hormonal responses. Changes predicted in biochemical pathways indicated major modulation in glutathione mediated detoxification, flavones and derivatives, and plant hormone biosynthesis. Motif search analysis identified a highly significant enriched motif, ACGT, which is an abscisic acid responsive core element (ABRE, suggesting the possibility of ABA- mediated signaling. Identification of abscisic acid response element (ABRE points to the operation of a predominant signaling mechanism in response to AuCl4- exposure. Overall, this study presents a useful picture of plant-gold interaction with an identification of

  9. Tourisme et communautés rurales au Venezuela : vers une application des principes du Développement Durable

    Directory of Open Access Journals (Sweden)

    Olivier Dehoorne

    2008-02-01

    Full Text Available L’évolution récente du tourisme international au Venezuela est particulièrement intéressante : l'activité touristique qui reste très largement concentrée sur la côte caribéenne, et notamment l’île de Margarita, se diversifie au profit de nouveaux centres d’intérêt dans les régions intérieures. L’affichage de nouvelles volontés politiques sur la scène régionale et internationale, sous l’impulsion du président Chavez, a perturbé le marché touristique national qui était dominé pour les clientèles nord-américaines ; le Venezuela apparaît désormais aux yeux des Etats-Unis comme un pays à risque, instable. C’est dans ce contexte que s’inscrit le « Programa Andes Tropicales » [PAT] qui soutient le  développement rural dans les parcs nationaux ; ce programme repose sur la participation des populations locales et leur implication dans les politiques de conservation des ressources naturelles et culturelles sources de revenus. Le soutien financier des microprojets familiaux et communautaires doivent permettent de lutter contre la pauvreté.The recent evolution of international tourism in Venezuela is particularly interesting. Even if tourism activity remains heavily concentrated on the Caribbean coast, in particular on the island of Margarita, it is nevertheless diversifying gradually to make way for new areas of interest in the country’s interior. The display of new political will on the regional and international scene, under the leadership of President Chavez, has disrupted the national tourism market which was dominated by North American customers. Venezuela now appears in the eyes of the United States as a country that is at risk,and therefore unstable. It is in this context that the “Programa Andes Tropicales" [PAT] was developed to promote rural development in national parks; This program is based on the participation and involvement of local populations in the development of appropriate

  10. Isolation and characterization of the tertiary amine Alamine 304 hydrochioride. Its application on the extraction of Co(II, Au(III and Pt(IV

    Directory of Open Access Journals (Sweden)

    López-Delgado, Aurora

    2000-06-01

    Full Text Available Amine Alamine 304 dissolved in xylene reacts with hydrochloric acid to form the amine chloride (R3NH+Cl- and the amine dichloride (R3NH2Cl2. The former compound was isolated and characterized by chemical analysis, X-ray powder diffraction, infrared spectroscopy and scanning electron microscopy. Lattice parameters of the isolated amine chloride were determined and refined by least-square numerical treatment (monoclinic cell, with a = 29.017(4 Å, b = 14.564(7 Å, c = 5.043(1 Å, b = 95.68(3 ° and V = 2,120 Å3. The amine chloride is a potential anion-exchanger with metals, thus data on the liquid-liquid extraction of Co(II, Au(III and Pt(IV are also reported.

    La amina Alamine 304 disuelta en xileno reacciona con el ácido clorhídrico para formar el cloruro de la amina (R3NH+Cl- y el dicloruro de amina (R3NH2Cl2. El primero de estos compuestos se aisló y caracterizó mediante análisis químico, difracción de rayos X, espectroscopia de IR y microscopía electrónica de barrido. Se determinaron y refinaron los parámetros de red del cloruro de amina (monoclínico, a = 29,017(4 Å, b = 14,564(7 Å, c = 5,043(1 Å, b = 95,68(3 ° y V = 2.120 Å3. El cloruro de amina actúa como un intercambiador aniónico con ciertos metales, por lo que se incluyen datos sobre la extracción líquido-líquido de Co(II, Au(III y Pt(IV.

  11. Economic model predictive control theory, formulations and chemical process applications

    CERN Document Server

    Ellis, Matthew; Christofides, Panagiotis D

    2017-01-01

    This book presents general methods for the design of economic model predictive control (EMPC) systems for broad classes of nonlinear systems that address key theoretical and practical considerations including recursive feasibility, closed-loop stability, closed-loop performance, and computational efficiency. Specifically, the book proposes: Lyapunov-based EMPC methods for nonlinear systems; two-tier EMPC architectures that are highly computationally efficient; and EMPC schemes handling explicitly uncertainty, time-varying cost functions, time-delays and multiple-time-scale dynamics. The proposed methods employ a variety of tools ranging from nonlinear systems analysis, through Lyapunov-based control techniques to nonlinear dynamic optimization. The applicability and performance of the proposed methods are demonstrated through a number of chemical process examples. The book presents state-of-the-art methods for the design of economic model predictive control systems for chemical processes. In addition to being...

  12. Moving shape analysis and control applications to fluid structure interactions

    CERN Document Server

    Moubachir, Marwan

    2006-01-01

    Problems involving the evolution of two- and three-dimensional domains arise in many areas of science and engineering. Emphasizing an Eulerian approach, Moving Shape Analysis and Control: Applications to Fluid Structure Interactions presents valuable tools for the mathematical analysis of evolving domains. The book illustrates the efficiency of the tools presented through different examples connected to the analysis of noncylindrical partial differential equations (PDEs), such as Navier-Stokes equations for incompressible fluids in moving domains. The authors first provide all of the details of existence and uniqueness of the flow in both strong and weak cases. After establishing several important principles and methods, they devote several chapters to demonstrating Eulerian evolution and derivation tools for the control of systems involving fluids and solids. The book concludes with the boundary control of fluid-structure interaction systems, followed by helpful appendices that review some of the advanced m...

  13. Delayless acceleration measurement method for motion control applications

    Energy Technology Data Exchange (ETDEWEB)

    Vaeliviita, S.; Ovaska, S.J. [Helsinki University of Technology, Otaniemi (Finland). Institute of Intelligent Power Electronics

    1997-12-31

    Delayless and accurate sensing of angular acceleration can improve the performance of motion control in motor drives. Acceleration control is, however, seldom implemented in practical drive systems due to prohibitively high costs or unsatisfactory results of most acceleration measurement methods. In this paper we propose an efficient and accurate acceleration measurement method based on direct differentiation of the corresponding velocity signal. Polynomial predictive filtering is used to smooth the resulting noisy signal without delay. This type of prediction is justified by noticing that a low-degree polynomial can usually be fitted into the primary acceleration curve. No additional hardware is required to implement the procedure if the velocity signal is already available. The performance of the acceleration measurement method is evaluated by applying it to a demanding motion control application. (orig.) 12 refs.

  14. Advances and applications in sliding mode control systems

    CERN Document Server

    Zhu, Quanmin

    2015-01-01

    This book describes the advances and applications in Sliding mode control (SMC) which is widely used as a powerful method to tackle uncertain nonlinear systems. The book is organized into 21 chapters which have been organised by the editors to reflect the various themes of sliding mode control. The book provides the reader with a broad range of material from first principles up to the current state of the art in the area of SMC and observation presented in a clear, matter-of-fact style. As such it is appropriate for graduate students with a basic knowledge of classical control theory and some knowledge of state-space methods and nonlinear systems. The resulting design procedures are emphasized using Matlab/Simulink software.    

  15. Explicit Nonlinear Model Predictive Control Theory and Applications

    CERN Document Server

    Grancharova, Alexandra

    2012-01-01

    Nonlinear Model Predictive Control (NMPC) has become the accepted methodology to solve complex control problems related to process industries. The main motivation behind explicit NMPC is that an explicit state feedback law avoids the need for executing a numerical optimization algorithm in real time. The benefits of an explicit solution, in addition to the efficient on-line computations, include also verifiability of the implementation and the possibility to design embedded control systems with low software and hardware complexity. This book considers the multi-parametric Nonlinear Programming (mp-NLP) approaches to explicit approximate NMPC of constrained nonlinear systems, developed by the authors, as well as their applications to various NMPC problem formulations and several case studies. The following types of nonlinear systems are considered, resulting in different NMPC problem formulations: Ø  Nonlinear systems described by first-principles models and nonlinear systems described by black-box models; �...

  16. Dependence of SERS enhancement on the chemical composition and structure of Ag/Au hybrid nanoparticles.

    Science.gov (United States)

    Chaffin, Elise; O'Connor, Ryan T; Barr, James; Huang, Xiaohua; Wang, Yongmei

    2016-08-01

    Noble metal nanoparticles (NPs) such as silver (Ag) and gold (Au) have unique plasmonic properties that give rise to surface enhanced Raman scattering (SERS). Generally, Ag NPs have much stronger plasmonic properties and, hence, provide stronger SERS signals than Au NPs. However, Ag NPs lack the chemical stability and biocompatibility of comparable Au NPs and typically exhibit the most intense plasmonic resonance at wavelengths much shorter than the optimal spectral region for many biomedical applications. To overcome these issues, various experimental efforts have been devoted to the synthesis of Ag/Au hybrid NPs for the purpose of SERS detections. However, a complete understanding on how the SERS enhancement depends on the chemical composition and structure of these nanoparticles has not been achieved. In this study, Mie theory and the discrete dipole approximation have been used to calculate the plasmonic spectra and near-field electromagnetic enhancements of Ag/Au hybrid NPs. In particular, we discuss how the electromagnetic enhancement depends on the mole fraction of Au in Ag/Au alloy NPs and how one may use extinction spectra to distinguish between Ag/Au alloyed NPs and Ag-Au core-shell NPs. We also show that for incident laser wavelengths between ∼410 nm and 520 nm, Ag/Au alloyed NPs provide better electromagnetic enhancement than pure Ag, pure Au, or Ag-Au core-shell structured NPs. Finally, we show that silica-core Ag/Au alloy shelled NPs provide even better performance than pure Ag/Au alloy or pure solid Ag and pure solid Au NPs. The theoretical results presented will be beneficial to the experimental efforts in optimizing the design of Ag/Au hybrid NPs for SERS-based detection methods.

  17. Application of new control strategy for sun tracking

    Energy Technology Data Exchange (ETDEWEB)

    Rubio, F.R.; Ortega, M.G.; Gordillo, F.; Lopez-Martinez, M. [Depto. Ingenieria de Sistemas y Automatica, Escuela Superior de Ingenieros, Universidad de Sevilla, 41092 Sevilla (Spain)

    2007-07-15

    The application of high concentration solar cells technology allows a significant increase in the amount of energy collected by solar arrays per unit area. However, to make it possible, more severe specifications on the sun pointing error are required. In fact, the performance of solar cells with concentrators decreases drastically if this error is greater than a small value. These specifications are not fulfilled by simple tracking systems due to different sources of errors (e.g., small misalignments of the structure with respect to geographical north) that appear in practice in low cost, domestic applications. This paper presents a control application of a sun tracker that is able to follow the sun with high accuracy without the necessity of either a precise procedure of installation or recalibration. A hybrid tracking system that consists of a combination of open loop tracking strategies based on solar movement models and closed loop strategies using a dynamic feedback controller is presented. Energy saving factors are taken into account, which implies that, among other factors, the sun is not constantly tracked with the same accuracy, to prevent energy overconsumption by the motors. Simulation and experimental results with a low cost two axes solar tracker are exposed, including a comparison between a classical open loop tracking strategy and the proposed hybrid one. (author)

  18. Interaction Tasks and Controls for Public Display Applications

    Directory of Open Access Journals (Sweden)

    Jorge C. S. Cardoso

    2014-01-01

    Full Text Available Public displays are becoming increasingly interactive and a broad range of interaction mechanisms can now be used to create multiple forms of interaction. However, the lack of interaction abstractions forces each developer to create specific approaches for dealing with interaction, preventing users from building consistent expectations on how to interact across different display systems. There is a clear analogy with the early days of the graphical user interface, when a similar problem was addressed with the emergence of high-level interaction abstractions that provided consistent interaction experiences to users and shielded developers from low-level details. This work takes a first step in that same direction by uncovering interaction abstractions that may lead to the emergence of interaction controls for applications in public displays. We identify a new set of interaction tasks focused on the specificities of public displays; we characterise interaction controls that may enable those interaction tasks to be integrated into applications; we create a mapping between the high-level abstractions provided by the interaction tasks and the concrete interaction mechanisms that can be implemented by those displays. Together, these contributions constitute a step towards the emergence of programming toolkits with widgets that developers could incorporate into their public display applications.

  19. Application of altitude control techniques for low altitude earth satellites

    Science.gov (United States)

    Nickerson, K. G.; Herder, R. W.; Glass, A. B.; Cooley, J. L.

    1977-01-01

    The applications sensors of many low altitude earth satellites designed for recording surface or atmospheric data require near zero orbital eccentricities for maximum usefulness. Coverage patterns and altitude profiles require specified values of orbit semimajor axis. Certain initial combinations of semimajor axis, eccentricity, and argument of perigee can produce a so called 'frozen orbit' and minimum altitude variation which enhances sensor coverage. This paper develops information on frozen orbits and minimum altitude variation for all inclinations, generalizing previous results. In the altitude regions where most of these satellites function (between 200 and 1000 kilometers) strong atmospheric drag effects influence the evolution of the initial orbits. Active orbital maneuver control techniques to correct evolution of orbit parameters while minimizing the frequency of maneuvers are presented. The paper presents the application of theoretical techniques for control of near frozen orbits and expands upon the methods useful for simultaneously targeting several inplane orbital parameters. The applications of these techniques are illustrated by performance results from the Atmosphere Explorer (AE-3 and -5) missions and in preflight maneuver analysis and plans for the Seasat Oceanographic Satellite.

  20. Microwave array applicator for radiometry-controlled superficial hyperthermia

    Science.gov (United States)

    Stauffer, Paul R.; Jacobsen, Svein; Neuman, Daniel

    2001-06-01

    Hyperthermia therapy has been shown clinically effective for a variety of skin diseases but current heating equipment is inadequate for most patients. This effort describes the design and performance of a flexible microstrip array applicator intended for heating large regions of tissue over contoured anatomy while at the same time monitoring temperature of the underlying tissue by non-invasive radiometric sensing of blackbody radiation from the heated volume. For this dual purpose applicator, an array of broadband Archimedean spiral receive antennas is integrated into an array of Dual Concentric Conductor heating apertures. Applicator heating uniformity is assessed with electric field scans in homogenous muscle phantoms and with measured temperature distributions in clinical treatments of chestwall recurrence of breast carcinoma. The data demonstrate precisely controlled heating out to the perimeter of large (40 x 13 cm2) multiaperture conformal array applicators. Capabilities of the radiometry system are assessed by correlation of brightness temperatures measured in phantom loads of known temperature distribution as seen through an intervening 5 mm thick water bolus at constant 40°C. The radiometer demonstrates excellent sensitivity and an accuracy of +0.1-0.45°C for temperature measurements up to 5 cm deep in phantom when using a one dimensional weighting function analysis and up to 6 independent 500 MHz bandwidths within the 1-4 GHz range. The data clearly indicate that both heating and radiometric thermometry are possible using the same thin and flexible printed circuit board microstrip array applicator. Once development is complete, this dual mode conformal array applicator with multiplexed radiometric display system should provide significantly improved uniformity and ease of heating large area superficial tissue disease.

  1. Tunable VO2/Au hyperbolic metamaterial

    Science.gov (United States)

    Prayakarao, S.; Mendoza, B.; Devine, A.; Kyaw, C.; van Dover, R. B.; Liberman, V.; Noginov, M. A.

    2016-08-01

    Vanadium dioxide (VO2) is known to have a semiconductor-to-metal phase transition at ˜68 °C. Therefore, it can be used as a tunable component of an active metamaterial. The lamellar metamaterial studied in this work is composed of subwavelength VO2 and Au layers and is designed to undergo a temperature controlled transition from the optical hyperbolic phase to the metallic phase. VO2 films and VO2/Au lamellar metamaterial stacks have been fabricated and studied in electrical conductivity and optical (transmission and reflection) experiments. The observed temperature-dependent changes in the reflection and transmission spectra of the metamaterials and VO2 thin films are in a good qualitative agreement with theoretical predictions. The demonstrated optical hyperbolic-to-metallic phase transition is a unique physical phenomenon with the potential to enable advanced control of light-matter interactions.

  2. Comparison of photoluminescence properties of HSA-protected and BSA-protected Au25 nanoclusters

    Science.gov (United States)

    Tsukamoto, Masato; Kawasaki, Hideya; Saitoh, Tadashi; Inada, Mitsuru; Kansai Univ. Collaboration

    Gold nanoclusters (NCs) have attracted great interest for a wide range of applications. In particular, red light-emitting Au25 NCs have been prepared with various biological ligands. It has been shown that Au25 NCs have Au13-core/6Au2(SR)3-semiring structure. The red luminescence thought to be originated from both core (670 nm) and semiring (625 nm). It is important to reveal a structure of Au25 NCs to facilitate the progress of applications. However, the precise structure of Au25 NCs has not been clarified. There is a possibility of obtaining structural information about Au25 NCs to compare optical properties of the NCs that protected by slightly different molecules. Bovine and human serum albumin (BSA, HSA) are suitable one for this purpose. It has been suggested that rich tyrosine and cysteine residues in these molecules are important to produce the thiolate-protected Au NCs. If Au25 NCs have core/shell structure, only the luminescence of the semiring will be affected by the difference of the albumin molecules. We carefully compared PL characteristics of BSA- and HSA- protected Au25 NCs. As a result, there was no difference in the PL at 670 nm (core), while differences were observed in the PL at 625 nm (semiring). The results support that Au25 NCs have core/semiring structure.

  3. Scheduling with conflicts, and applications to traffic signal control

    Energy Technology Data Exchange (ETDEWEB)

    Irani, S.; Leung, V. [Univ. of California, Irvine, CA (United States)

    1996-12-31

    In this paper, we consider the scheduling of jobs that may be competing for mutually exclusive resources. We model the conflicts between jobs with a conflict graph, so that all concurrently running jobs must form an independent set in the graph. We believe that this model is natural and general enough to have applications in a variety of settings; however, we are motivated by the following two specific applications: traffic intersection control and session scheduling in high speed local area networks with spatial reuse. In both of these applications, guaranteeing the best turnaround time to any job entering the system is important. Our results focus on two special classes of graphs motivated by our applications: bipartite graphs and interval graphs. Although the algorithms for bipartite and intervals graphs are quite different, the bounds they achieve are the same: we prove that for any sequence of jobs in which the maximum completion time of a job in the optimal schedule is bounded by A, the algorithm can complete every job in time O(n{sup 3} A{sup 2}). n is the number of nodes in the conflict graph. We also show that the best competitive ratio achievable by any online algorithm for the maximum completion time on interval or bipartite graphs is {Omega}(n).

  4. A control strategy for PV stand-alone applications

    Science.gov (United States)

    Slouma, S.; Baccar, H.

    2015-04-01

    This paper proposes a stand-alone photovoltaic (PV) system study in domestic applications. Because of the decrease in power of photovoltaic module as a consequence of changes in solar radiation and temperature which affect the photovoltaic module performance, the design and control of DC-DC buck converter was proposed for providing power to the load from a photovoltaic source.In fact, the control of this converter is carried out with integrated MPPT (Maximum Power Point Tracking) algorithm which ensures a maximum energy generated by the PV arrays. Moreover, the output stage is composed by a battery energy storage system, dc-ac inverter, LCL filter which enables higher efficiency, low distortion ac waveforms and low leakage currents. The control strategy adopted is cascade control composed by two regulation loops.Simulations performed with PSIM software were able to validate the control system.The realization and testing of the photovoltaic system were achieved in the Photovoltaic laboratory of the Centre for Research and Energy Technologies at the Technopark Borj Cedria. Experimental results verify the effeciency of the proposed system.

  5. SMES application for frequency control during islanded microgrid operation

    Science.gov (United States)

    Kim, A.-Rong; Kim, Gyeong-Hun; Heo, Serim; Park, Minwon; Yu, In-Keun; Kim, Hak-Man

    2013-01-01

    This paper analyzes the operating characteristics of a superconducting magnetic energy storage (SMES) for the frequency control of an islanded microgrid operation. In the grid-connected mode of a microgrid, an imbalance between power supply and demand is solved by a power trade with the upstream power grid. The difference in the islanded mode is a critical problem because the microgrid is isolated from any power grid. For this reason, the frequency control during islanded microgrid operation is a challenging issue. A test microgrid in this paper consisted of a wind power generator, a PV generation system, a diesel generator and a load to test the feasibility of the SMES for controlling frequency during islanded operation as well as the transient state varying from the grid-connected mode to the islanded mode. The results show that the SMES contributes well for frequency control in the islanded operation. In addition, a dual and a single magnet type of SMES have been compared to demonstrate the control performance. The dual magnet has the same energy capacity as the single magnet, but there are two superconducting coils and each coil has half inductance of the single magnet. The effectiveness of the SMES application with the simulation results is discussed in detail.

  6. LA DIVERSITÃ DÃPLOYÃE AU SEIN DE LâUNIVERSITÃ DâENTREPRISE : LâAPPLICATION CONCRÃTE DâUNE VALEUR ADOPTÃE PAR LA DIRECTION GÃNÃRALE

    Directory of Open Access Journals (Sweden)

    Virginia Drummond-Guitel

    2009-09-01

    Full Text Available La diversité devenue une valeur incontournable adoptée par les grands groupes, encore faut-t-il trouver les moyens concrets pour lâintégrer dans les pratiques des ressources humaines et dans les mentalités des personnes. Le présent papier a pour but de montrer comment les valeurs de la diversité adoptées par la direction générale ont été déclinées et appliquées dans un processus de sélection de candidats pour une formation continue au sein dâune grande organisation internationale. A travers lâapplication dâune méthode qualitative de recherche, 10 (dix dirigeants ayant conçu la formation et 42 (quarante-deux managers ayant suivi le programme confirment lâatteinte du but stratégique de cette formation, autrement dit, lâatteinte dâune vision partagée (SENGE, 1991, à travers la consolidation dâun fort sentiment dâappartenance à la culture organisationnelle (SCHEIN, 1995. Les managers ont été sélectionnés selon leurs différentes professions, cultures nationales et différents secteurs dâactivités, confirmant ainsi une promotion de la diversité au sein de lâorganisation.

  7. Modélisation et commande de processus par réseaux de neurones ; application au pilotage d'un véhicule autonome

    OpenAIRE

    Rivals, Isabelle

    1995-01-01

    Artificial neural networks allow the construction of a wide family of nonlinear models and controllers using statistical learning. The purpose of this thesis is to establish how to implement neural networks for the modeling and control of nonlinear dynamic processes, and to evaluate their contribution for these tasks. At the theoretical level, we present the neural modeling and control in a general framework, from the viewpoint of classic automatic control. Concerning modeling, the results ab...

  8. Contribution of the ultrasonic simulation to the testing methods qualification process; Contribution de la modelisation ultrasonore au processus de qualification des methodes de controle

    Energy Technology Data Exchange (ETDEWEB)

    Le Ber, L.; Calmon, P. [CEA/Saclay, STA, 91 - Gif-sur-Yvette (France); Abittan, E. [Electricite de France (EDF-GDL), 93 - Saint-Denis (France)

    2001-07-01

    The CEA and EDF have started a study concerning the simulation interest in the qualification of nuclear components control by ultrasonic methods. In this framework, the simulation tools of the CEA, as CIVA, have been tested on real control. The method and the results obtained on some examples are presented. (A.L.B.)

  9. Embedded Thermal Control for Subsystems for Next Generation Spacecraft Applications

    Science.gov (United States)

    Didion, Jeffrey R.

    2015-01-01

    Thermal Fluids and Analysis Workshop, Silver Spring MD NCTS 21070-15. NASA, the Defense Department and commercial interests are actively engaged in developing miniaturized spacecraft systems and scientific instruments to leverage smaller cheaper spacecraft form factors such as CubeSats. This paper outlines research and development efforts among Goddard Space Flight Center personnel and its several partners to develop innovative embedded thermal control subsystems. Embedded thermal control subsystems is a cross cutting enabling technology integrating advanced manufacturing techniques to develop multifunctional intelligent structures to reduce Size, Weight and Power (SWaP) consumption of both the thermal control subsystem and overall spacecraft. Embedded thermal control subsystems permit heat acquisition and rejection at higher temperatures than state of the art systems by employing both advanced heat transfer equipment (integrated heat exchangers) and high heat transfer phenomena. The Goddard Space Flight Center Thermal Engineering Branch has active investigations seeking to characterize advanced thermal control systems for near term spacecraft missions. The embedded thermal control subsystem development effort consists of fundamental research as well as development of breadboard and prototype hardware and spaceflight validation efforts. This paper will outline relevant fundamental investigations of micro-scale heat transfer and electrically driven liquid film boiling. The hardware development efforts focus upon silicon based high heat flux applications (electronic chips, power electronics etc.) and multifunctional structures. Flight validation efforts include variable gravity campaigns and a proposed CubeSat based flight demonstration of a breadboard embedded thermal control system. The CubeSat investigation is technology demonstration will characterize in long-term low earth orbit a breadboard embedded thermal subsystem and its individual components to develop

  10. Fluctuations Magnetiques des Gaz D'electrons Bidimensionnels: Application AU Compose Supraconducteur LANTHANE(2-X) Strontium(x) Cuivre OXYGENE(4)

    Science.gov (United States)

    Benard, Pierre

    Nous presentons une etude des fluctuations magnetiques de la phase normale de l'oxyde de cuivre supraconducteur La_{2-x}Sr _{x}CuO_4 . Le compose est modelise par le Hamiltonien de Hubbard bidimensionnel avec un terme de saut vers les deuxiemes voisins (modele tt'U). Le modele est etudie en utilisant l'approximation de la GRPA (Generalized Random Phase Approximation) et en incluant les effets de la renormalisation de l'interaction de Hubbard par les diagrammes de Brueckner-Kanamori. Dans l'approche presentee dans ce travail, les maximums du facteur de structure magnetique observes par les experiences de diffusion de neutrons sont associes aux anomalies 2k _{F} de reseau du facteur de structure des gaz d'electrons bidimensionnels sans interaction. Ces anomalies proviennent de la diffusion entre particules situees a des points de la surface de Fermi ou les vitesses de Fermi sont tangentes, et conduisent a des divergences dont la nature depend de la geometrie de la surface de Fermi au voisinage de ces points. Ces resultats sont ensuite appliques au modele tt'U, dont le modele de Hubbard usuel tU est un cas particulier. Dans la majorite des cas, les interactions ne determinent pas la position des maximums du facteur de structure. Le role de l'interaction est d'augmenter l'intensite des structures du facteur de structure magnetique associees a l'instabilite magnetique du systeme. Ces structures sont souvent deja presentes dans la partie imaginaire de la susceptibilite sans interaction. Le rapport d'intensite entre les maximums absolus et les autres structures du facteur de structure magnetique permet de determiner le rapport U_ {rn}/U_{c} qui mesure la proximite d'une instabilite magnetique. Le diagramme de phase est ensuite etudie afin de delimiter la plage de validite de l'approximation. Apres avoir discute des modes collectifs et de l'effet d'une partie imaginaire non-nulle de la self-energie, l'origine de l'echelle d'energie des fluctuations magnetiques est examinee

  11. AU-FREDI - AUTONOMOUS FREQUENCY DOMAIN IDENTIFICATION

    Science.gov (United States)

    Yam, Y.

    1994-01-01

    The Autonomous Frequency Domain Identification program, AU-FREDI, is a system of methods, algorithms and software that was developed for the identification of structural dynamic parameters and system transfer function characterization for control of large space platforms and flexible spacecraft. It was validated in the CALTECH/Jet Propulsion Laboratory's Large Spacecraft Control Laboratory. Due to the unique characteristics of this laboratory environment, and the environment-specific nature of many of the software's routines, AU-FREDI should be considered to be a collection of routines which can be modified and reassembled to suit system identification and control experiments on large flexible structures. The AU-FREDI software was originally designed to command plant excitation and handle subsequent input/output data transfer, and to conduct system identification based on the I/O data. Key features of the AU-FREDI methodology are as follows: 1. AU-FREDI has on-line digital filter design to support on-orbit optimal input design and data composition. 2. Data composition of experimental data in overlapping frequency bands overcomes finite actuator power constraints. 3. Recursive least squares sine-dwell estimation accurately handles digitized sinusoids and low frequency modes. 4. The system also includes automated estimation of model order using a product moment matrix. 5. A sample-data transfer function parametrization supports digital control design. 6. Minimum variance estimation is assured with a curve fitting algorithm with iterative reweighting. 7. Robust root solvers accurately factorize high order polynomials to determine frequency and damping estimates. 8. Output error characterization of model additive uncertainty supports robustness analysis. The research objectives associated with AU-FREDI were particularly useful in focusing the identification methodology for realistic on-orbit testing conditions. Rather than estimating the entire structure, as is

  12. Au@AuPt nanoparticles embedded in B-doped graphene: A superior electrocatalyst for determination of rutin

    Science.gov (United States)

    Chen, Xianlan; Yang, Guangming; Feng, Shaoping; Shi, Ling; Huang, Zhaolong; Pan, Haibo; Liu, Wei

    2017-04-01

    A hydrothermal approach was used to prepare B-doped graphene with B2O3 as reductant and boron source. Results reveal that the boron atoms have been successfully embedded into graphene with a high content of a total B species (2.85 at.%). Then, B-doped graphene was exfoliated further into monolayer nanosheet by impregnating Au@AuPt core-shell nanoparticles (Au@AuPt NPs) because boron atom creates a net positive charge, which facilitates Au@AuPt NPs adsorption to form Au@AuPt NPs/B-doped graphene hybrid nanocatalysts. After that, the Au@AuPt NPs/B-doped hybrid suspension was dropped on glassy carbon electrode for sensing rutin. In this way, the dispersed carboxyl units of B-doped graphene can form hydrogen bonding with the phenolic hydroxyl groups of rutin, making rutin enrich easily on modified electrode surface to enhance the electrochemical response. At the same time, its electrochemical mechanism on the modified electrode was elucidated using cyclic voltammetry. It was found that its electrochemical behavior on modified electrode surface was a surface-controlled quasi-reversible process, and the charge transfer coefficient (α) and electron transfer number (n) were 0.296 and 2, respectively. This electrochemical sensor for rutin provided a wide linear response range of 2.00 × 10-9-4.00 × 10-6 M with the detection limit (S/N = 3) of 2.84 × 10-10 M. The proposed method was applied successfully to selective determination of rutin in Tablets with acceptable recovery range (97.23-101.65%).

  13. Optimization of Control Self Assessment Application to Minimize Fraud

    Directory of Open Access Journals (Sweden)

    Wendy Endrianto

    2016-05-01

    Full Text Available This article discussed a method that can be done by a company to minimize fraud action by applying Control Self Assessment (CSA. The study was conducted by studying literature on the topics discussed that were presented descriptively in a systematic manner through the review one by one from the initial problem to solve the problem. It can be concluded that CSA is one form of auditing practices that emphasizes anticipatory action (preventive of the act of detection (detective that the concept of modern internal audit which is carried more precise in application. It is one alternative that is most efficient and effective in reducing fraud.

  14. Equivalent sample theory of networked control systems and its application

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The equivalent sample theory and its application in analysis of networked control system (NCS) are presented. After analyzing NCS's scheduling in master-slave mode, the characteristics of time delay and sample are summarized. Looking on master station visiting the slave station as a special sample process, the theory of equivalent sample is presented. And based on it, the stability of a kind of NCS is analyzed. The criterion to determine the upper bound of transmission delay is introduced, which guarantees the stability. Finally, an example with simulation shows the availability and usability of this analysis method.

  15. Electric Voltage Control as an Implementation of Neural Network Applications

    Directory of Open Access Journals (Sweden)

    A. A. Al-Rababah

    2008-01-01

    Full Text Available Present study was proposed the monitoring of mathematical model of electric voltage source with using neural network for application in control systems as sensor and command signal. The monitoring system, consist of toroidal choke or transformer with high saturated ferromagnetic cores. The input information we receive from current periodic curves. The current was distributed into Fourier or walsh series. The combination of these harmonics and their amplitude values determine monitoring voltage value directly. For increase of this system precision, the mathematical model was constructed on basis of partial differential quasi-stationary electromagnetic field equations and ordi-nary differential electromagnetic circuit equations combination.

  16. Controlled synthesis of porous platinum nanostructures for catalytic applications.

    Science.gov (United States)

    Cao, Yanqin; Zhang, Junwei; Yang, Yong; Huang, Zhengren; Long, Nguyen Viet; Nogami, Masayuki

    2014-02-01

    Porous platinum, that has outstanding catalytic and electrical properties and superior resistant characteristics to corrosion, has been widely applied in chemical, petrochemical, pharmaceutical, electronic, and automotive industries. As the catalytic activity and selectivity depend on the size, shape and structure of nanomaterials, the strategies for controlling these factors of platinum nanomaterials to get excellent catalytic properties are discussed. Here, recent advances in the design and preparation of various porous platinum nanostructures are reviewed, including wet-chemical synthesis, electro-deposition, galvanic replacement reaction and de-alloying technology. The applications of various platinum nanostructures are also discussed, especially in fuel cells.

  17. Controlling End User Computing Applications - a case study

    CERN Document Server

    Chambers, Jamie

    2008-01-01

    We report the results of a project to control the use of end user computing tools for business critical applications in a banking environment. Several workstreams were employed in order to bring about a cultural change within the bank towards the use of spreadsheets and other end-user tools, covering policy development, awareness and skills training, inventory monitoring, user licensing, key risk metrics and mitigation approaches. The outcomes of these activities are discussed, and conclusions are drawn as to the need for appropriate organisational models to guide the use of these tools.

  18. Effects of Two Application Methods of Plantaricin BM-1 on Control of Listeria monocytogenes and Background Spoilage Bacteria in Sliced Vacuum-Packaged Cooked Ham Stored at 4°C.

    Science.gov (United States)

    Zhou, Huimin; Xie, Yuanhong; Liu, Hui; Jin, Junhua; Duan, Huixia; Zhang, Hongxing

    2015-10-01

    Two application methods were used to investigate the effect of plantaricin BM-1 on the control of Listeria monocytogenes and background spoilage bacteria in sliced vacuum-packaged cooked ham without the addition of any chemical preservatives, including sodium nitrite, during 35 days of storage at 4°C. Regardless of the application method, plantaricin BM-1 treatment (320, 640, or 1,280 arbitrary units [AU]/g of sliced cooked ham) significantly (P < 0.05) reduced the survival of L. monocytogenes (inoculated at 4 log CFU/g of sliced ham) compared with its survival in the control during the first 21 days of storage at 4°C. The inhibitory effect of plantaricin applied to the surface of the ham was significantly better than the same concentration of plantaricin incorporated into the cooked ham (P < 0.0001) during storage. Even 320 AU/g plantaricin applied to the surface exhibited greater inhibition of L. monocytogenes than 1,280 AU/g plantaricin incorporated into the cooked ham on days 1, 14, and 28. A level of 1,280 AU/g plantaricin applied to the surface of the ham reduced L. monocytogenes counts to below the detection limit from the 1st to the 21st day of storage at 4°C. Afterwards, L. monocytogenes was able to regrow, and the viable counts of L. monocytogenes at the end of storage reached 2.76 log CFU/g (6.11 log CFU/g lower than in the control). In the control ham, the counts of background spoilage bacteria increased gradually and surpassed the microbiological spoilage limitation level on the 21st day of storage. However, plantaricin BM-1 treatment significantly (P < 0.05) reduced the survival of background spoilage bacteria in ham compared with their survival in the control from day 21 to 35 of storage at 4°C. A level of 1,280 AU/g plantaricin incorporated into cooked ham was the most effective, reducing the count of background spoilage bacteria count from an initial 2.0 log CFU/g to 1.5 log CFU/g on day 7. This was then maintained for another 14 days and

  19. ITS au Japon

    OpenAIRE

    JANIN, JF; LOUETTE, E; MALLEJACQ, P; PAGNY, R; YGNACE, JL

    2003-01-01

    Dans le cadre de l'accord de coopération signe entre les ministres des transports français et japonais en janvier 2002, des échanges de mission sont organisés de manière à comparer de façon concrète les développements des programmes its dans les deux pays. La première mission française avait eu lieu en mai 2002 à Tokyo. Elle a permis d'organiser un premier séminaire à l'arche de la défense il y a un an au cours duquel les experts japonais ont présenté leurs projets. Un second séminaire s'est ...

  20. Applicability of the FASTBUS standard to distributed control

    Energy Technology Data Exchange (ETDEWEB)

    Deiss, S.R.; Downing, R.W.; Gustavson, D.B.; Larsen, R.S.; Logg, C.A.; Paffrath, L.

    1981-03-01

    The new FASTBUS standard has been designed to provide a framework for distributed processing in both experimental data acquisition and accelerator control. The features of FASTBUS which support distributed control are a priority arbitration scheme which allows intercrate as well as intracrate message flow between processors and slave devices; and a high bandwidth to permit efficient sharing of the data paths by high-speed devices. Sophisticated diagnostic aids permit system-wide error checking and/or correction. Software has been developed for large distributed systems. This consists of a system data base description, and initialization algorithms to allocate address space and establish preferred message routes. A diagnostics package is also being developed, based on an independent Ethernet-like serial link. The paper describes available hardware and software, on-going developments, and current applications.