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  1. Kinetically controlled synthesis of Au102(SPh)44 nanoclusters and catalytic application

    Science.gov (United States)

    Chen, Yongdong; Wang, Jin; Liu, Chao; Li, Zhimin; Li, Gao

    2016-05-01

    We here explore a kinetically controlled synthetic protocol for preparing solvent-solvable Au102(SPh)44 nanoclusters which are isolated from polydispersed gold nanoclusters by solvent extraction and size exclusion chromatography (SEC). The as-obtained Au102(SPh)44 nanoclusters are determined by matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry, in conjunction with UV-vis spectroscopy and thermogravimetric analysis (TGA). However, Au99(SPh)42, instead of Au102(SPh)44, is yielded when the polydispersed gold nanoclusters are etched in the presence of excess thiophenol under thermal conditions (e.g., 80 °C). Interestingly, the Au102(SPh)44 nanoclusters also can convert to Au99(SPh)42 with equivalent thiophenol ligands, evidenced by the analyses of UV-vis and MALDI mass spectrometry. Finally, the TiO2-supported Au102(SPh)44 nanocluster catalyst is investigated in the selective oxidation of sulfides into sulfoxides by the PhIO oxidant and gives rise to high catalytic activity (e.g., 80-99% conversion of R-S-R' sulfides with 96-99% selectivity for R-S(&z.dbd;O)-R' sulfoxides). The Au102(SPh)44/TiO2 catalyst also shows excellent recyclability in the sulfoxidation process.We here explore a kinetically controlled synthetic protocol for preparing solvent-solvable Au102(SPh)44 nanoclusters which are isolated from polydispersed gold nanoclusters by solvent extraction and size exclusion chromatography (SEC). The as-obtained Au102(SPh)44 nanoclusters are determined by matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry, in conjunction with UV-vis spectroscopy and thermogravimetric analysis (TGA). However, Au99(SPh)42, instead of Au102(SPh)44, is yielded when the polydispersed gold nanoclusters are etched in the presence of excess thiophenol under thermal conditions (e.g., 80 °C). Interestingly, the Au102(SPh)44 nanoclusters also can convert to Au99(SPh)42 with equivalent

  2. Kinetically controlled synthesis of Au102(SPh)44 nanoclusters and catalytic application.

    Science.gov (United States)

    Chen, Yongdong; Wang, Jin; Liu, Chao; Li, Zhimin; Li, Gao

    2016-05-21

    We here explore a kinetically controlled synthetic protocol for preparing solvent-solvable Au102(SPh)44 nanoclusters which are isolated from polydispersed gold nanoclusters by solvent extraction and size exclusion chromatography (SEC). The as-obtained Au102(SPh)44 nanoclusters are determined by matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry, in conjunction with UV-vis spectroscopy and thermogravimetric analysis (TGA). However, Au99(SPh)42, instead of Au102(SPh)44, is yielded when the polydispersed gold nanoclusters are etched in the presence of excess thiophenol under thermal conditions (e.g., 80 °C). Interestingly, the Au102(SPh)44 nanoclusters also can convert to Au99(SPh)42 with equivalent thiophenol ligands, evidenced by the analyses of UV-vis and MALDI mass spectrometry. Finally, the TiO2-supported Au102(SPh)44 nanocluster catalyst is investigated in the selective oxidation of sulfides into sulfoxides by the PhIO oxidant and gives rise to high catalytic activity (e.g., 80-99% conversion of R-S-R' sulfides with 96-99% selectivity for R-S([double bond, length as m-dash]O)-R' sulfoxides). The Au102(SPh)44/TiO2 catalyst also shows excellent recyclability in the sulfoxidation process. PMID:26758553

  3. Shape and size controlled synthesis of Au nanorods: H2S gas-sensing characterizations and antibacterial application

    International Nuclear Information System (INIS)

    Highlights: • We have demonstrated a facile method to prepare colloid Au nanorods. • The size and shape of Au nanorods can be controlled via seed-mediated growth method. • The H2S gas-sensing properties have been investigated. • The antibacterial application has been conducted. - Abstract: Controlling their size and shape is one of the important issues in the fundamental study and application of colloidal metal nanoparticles. In the current study, different sizes and shapes of Au nanorods were fabricated using a seed-mediated growth method. Material characterization by X-ray diffraction and transmission electron microscopy revealed that the obtained products were made of single-crystal Au nanorods with an average diameter and length of 10 nm and 40 nm, respectively. The Au nanorod-based sensor exhibited significantly high sensitivity and fast response/recovery time to low concentrations (2.5–10 ppm) of H2S at temperatures ranging from 300 °C to 400 °C. Additionally, they exhibited antibacterial effect at low concentration. These results suggested that the fabricated Au nanorods have excellent potential for practical application in air pollution monitoring and biomedicine

  4. Shape and size controlled synthesis of Au nanorods: H{sub 2}S gas-sensing characterizations and antibacterial application

    Energy Technology Data Exchange (ETDEWEB)

    Lanh, Le Thi [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Hoa, Tran Thai, E-mail: trthaihoa@yahoo.com [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Cuong, Nguyen Duc [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Faculty of Hospitality and Tourism, Hue University, 22 Lam Hoang, Hue City (Viet Nam); Khieu, Dinh Quang [College of Sciences, Hue University, 77 Nguyen Hue, Hue City (Viet Nam); Quang, Duong Tuan [College of Education, Hue University, 34 Le Loi, Hue City (Viet Nam); Van Duy, Nguyen; Hoa, Nguyen Duc [International Training Institute for Materials Science, Hanoi University of Science and Technology, Hanoi (Viet Nam); Van Hieu, Nguyen, E-mail: hieu@itims.edu.vn [International Training Institute for Materials Science, Hanoi University of Science and Technology, Hanoi (Viet Nam)

    2015-06-25

    Highlights: • We have demonstrated a facile method to prepare colloid Au nanorods. • The size and shape of Au nanorods can be controlled via seed-mediated growth method. • The H{sub 2}S gas-sensing properties have been investigated. • The antibacterial application has been conducted. - Abstract: Controlling their size and shape is one of the important issues in the fundamental study and application of colloidal metal nanoparticles. In the current study, different sizes and shapes of Au nanorods were fabricated using a seed-mediated growth method. Material characterization by X-ray diffraction and transmission electron microscopy revealed that the obtained products were made of single-crystal Au nanorods with an average diameter and length of 10 nm and 40 nm, respectively. The Au nanorod-based sensor exhibited significantly high sensitivity and fast response/recovery time to low concentrations (2.5–10 ppm) of H{sub 2}S at temperatures ranging from 300 °C to 400 °C. Additionally, they exhibited antibacterial effect at low concentration. These results suggested that the fabricated Au nanorods have excellent potential for practical application in air pollution monitoring and biomedicine.

  5. Fusion d'images: application au contr\\^ole de la distribution des biopsies prostatiques

    CERN Document Server

    Mozer, Pierre; Chevreau, G; Troccaz, Jocelyne

    2008-01-01

    This paper is about the application of a 3D ultrasound data fusion technique to the 3D reconstruction of prostate biopies in a reference volume. The method is introduced and its evaluation on a series of data coming from 15 patients is described.

  6. Interface controlled growth of nanostructures in discontinuous Ag and Au thin films fabricated by ion beam sputter deposition for plasmonic applications

    Indian Academy of Sciences (India)

    R Brahma; M Ghanashyam Krishna

    2012-08-01

    The growth of discontinuous thin films of Ag and Au by low energy ion beam sputter deposition is reported. The study focuses on the role of the film–substrate in determining the shape and size of nanostructures achieved in such films. Ag films were deposited using Ar ion energy of 150 eV while the Au films were deposited with Ar ion energies of 250–450 eV. Three types of interfaces were investigated in this study. The first set of film–substrate interfaces consisted of Ag and Au films grown on borosilicate glass and carbon coated Cu grids used as substrates. The second set of films was metallic bilayers in which one of the metals (Ag or Au) was grown on a continuous film of the other metal (Au or Ag). The third set of interfaces comprised of discontinuous Ag and Au films deposited on different dielectrics such as SiO2, TiO2 and ZrO2. In each case, a rich variety of nanostructures including self organized arrays of nanoparticles, nanoclusters and nanoneedles have been achieved. The role of the film–substrate interface is discussed within the framework of existing theories of thin film nucleation and growth. Interfacial nanostructuring of thin films is demonstrated to be a viable technique to realize a variety of nanostructures. The use of interfacial nanostructuring for plasmonic applications is demonstrated. It is shown that the surface Plasmon resonance of the metal nanostructures can be tuned over a wide range of wavelengths from 400 to 700 nm by controlling the film–substrate interface.

  7. Controlled electrodeposition of Au monolayer film on ionic liquid

    Science.gov (United States)

    Ma, Qiang; Pang, Liuqing; Li, Man; Zhang, Yunxia; Ren, Xianpei; Liu, Shengzhong Frank

    2016-05-01

    Gold (Au) nanoparticles have been attractive for centuries for their vibrant appearance enhanced by their interaction with sunlight. Nowadays, there have been tremendous research efforts to develop them for high-tech applications including therapeutic agents, sensors, organic photovoltaics, medical applications, electronics and catalysis. However, there remains to be a challenge to fabricate a monolayer Au coating with complete coverage in controlled fashion. Here we present a facile method to deposit a uniform Au monolayer (ML) film on the [BMIM][PF6] ionic liquid substrate using an electrochemical deposition process. It demonstrates that it is feasible to prepare a solid phase coating on the liquid-based substrate. Moreover, the thickness of the monolayer coating can be controlled to a layer-by-layer accuracy.

  8. Controlled Synthesis of Au@AgAu Yolk-Shell Cuboctahedra with Well-Defined Facets.

    Science.gov (United States)

    Londono-Calderon, Alejandra; Bahena, Daniel; Yacaman, Miguel J

    2016-08-01

    The synthesis of Au@AgAu yolk-shell cuboctahedra nanoparticles formed by galvanic replacement in a seed-mediated method is described. Initially, single-crystal Au seeds are used for the formation of Au@Ag core-shell nanocubes, which serve as the template material for the deposition of an external Au layer. The well-controlled synthesis yields the formation of cuboctahedra nanoparticles with smooth inner and outer Au/Ag surfaces. The deposition/oxidation process is described to understand the formation of cuboctahedra and octahedra nanoparticles. The Au core maintains the initial morphology of the seed and remains static at the center of the yolk-shell because of residual Ag. Structural analysis of the shell indicates intrinsic stacking faults (SFs) near the surface. Energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) compositional analysis show an Au-Ag nonordered alloy forming the shell. The three-dimensional structure of the nanoparticles presented open facets on the [111] as observed by electron tomography SIRT reconstruction over a stack of high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) images. The geometrical model was validated by analyzing the direction of streaks in coherent nanobeam diffraction (NBD). The catalytic activity was evaluated using a model reaction based on the reduction of 4-nitrophenol (4-NTP) by NaBH4 in the presence of Au@AgAu yolk-shell nanoparticles. PMID:27385583

  9. Photochemical preparation and application research of Au nanoparticles

    Institute of Scientific and Technical Information of China (English)

    DONG; Shou-an; SUN; Jia-lin

    2005-01-01

    Gold nanoparticles protected by organic small molecular compounds or macromolecule have attracted considerable attention and their preparation is one of hotspots in the nano-chemical material field due to their ongoing and potential applications in optics, electronics, catalysts and biosensors. In recent years there are many liquid phase chemistry methods to prepare monodispersed gold particles. Among them, the photochemical method is quite attractive because of its some important advantages for size-controlled synthesis of gold nanoparticles. Therefore, in this paper the recert progress of the photochemical preparing Au nanoparticle materials was briefly introduced and mainly emphasized authors' own works of this area.

  10. Controlling Au Photodeposition on Large ZnO Nanoparticles.

    Science.gov (United States)

    Fernando, Joseph F S; Shortell, Matthew P; Noble, Christopher J; Harmer, Jeffrey R; Jaatinen, Esa A; Waclawik, Eric R

    2016-06-01

    This study investigated how to control the rate of photoreduction of metastable AuCl2(-) at the solid-solution interface of large ZnO nanoparticles (NPs) (50-100 nm size). Band-gap photoexcitation of electronic charge in ZnO by 370 nm UV light yielded Au NP deposition and the formation of ZnO-Au NP hybrids. Au NP growth was observed to be nonepitaxial, and the patterns of Au photodeposition onto ZnO NPs observed by high-resolution transmission electron microscopy were consistent with reduction of AuCl2(-) at ZnO facet edges and corner sites. Au NP photodeposition was effective in the presence of labile oleylamine ligands attached to the ZnO surface; however, when a strong-binding dodecanethiol ligand coated the surface, photodeposition was quenched. Rates of interfacial electron transfer at the ZnO-solution interface were adjusted by changing the solvent, and these rates were observed to strongly depend on the solvent's permittivity (ε) and viscosity. From measurements of electron transfer from ZnO to the organic dye toluidine blue at the ZnO-solution interface, it was confirmed that low ε solvent mixtures (ε ≈ 9.5) possessed markedly higher rates of photocatalytic interfacial electron transfer (∼3.2 × 10(4) electrons·particle(-1)·s(-1)) compared to solvent mixtures with high ε (ε = 29.9, ∼1.9 × 10(4) electrons·particle(-1)·s(-1)). Dissolved oxygen content in the solvent and the exposure time of ZnO to band-gap, near-UV photoexcitation were also identified as factors that strongly affected Au photodeposition behavior. Production of Au clusters was favored under conditions that caused electron accumulation in the ZnO-Au NP hybrid. Under conditions where electron discharge was rapid (such as in low ε solvents), AuCl2(-) precursor ions photoreduced at ZnO surfaces in less than 5 s, leading to deposition of several small, isolated ∼6 nm Au NP on the ZnO host instead. PMID:27196721

  11. Les frameworks au coeur des applications web

    OpenAIRE

    Moro, Arielle; Daehne, Peter

    2010-01-01

    Depuis quelques années, Internet est vraiment entré dans les mœurs : tant dans les entreprises qu’au sein de chaque foyer. En effet, Internet permet de communiquer à travers le monde en quelques secondes, de vendre toute sorte de produits en déployant des solutions e-commerce facilement et bien d’autres choses. Internet est donc un véritable vecteur de communication, de commerce et à présent, avec le Web 2.0, un vrai berceau d’informations (tant des informations personnelles que des informati...

  12. Ordered Au Nanodisk and Nanohole Arrays: Fabrication and Applications

    KAUST Repository

    Zheng, Yue Bing

    2010-01-01

    We have utilized nanosphere lithography (NSL) to fabricate ordered Au nanodisk and nanohole arrays on substrates and have studied the localized surface plasmon resonance (LSPR) of the arrays. Through these investigations, we demonstrate that the angle- dependent behavior of the LSPR in the Au nanodisk arrays enables real-time observation of exciton-plasmon couplings. In addition, we show that the NSL-fabricated Au nanohole arrays can be applied as templates for patterning micro-/nanoparticles under capillary force. The unique structural and plasmonic characteristics of the Au nanodisk and nano- hole arrays, as well as the low-cost and high-throughput NSL-based nanofabrication technique, render these arrays excellent platforms for numerous engineering applications. © 2010 by ASME.

  13. Application of Cryopreserved Fibroblast Culture with Au Nanoparticles to Treat Burns.

    Science.gov (United States)

    Volkova, Nataliia; Yukhta, Mariia; Pavlovich, Olena; Goltsev, Anatoliy

    2016-12-01

    The aim was to investigate a possibility of using the cryopreserved human culture of fibroblasts (CrHFC) with gold nanoparticles (AuNPs) to treat experimental burns in rats.The third-degree burns were modeled in white male rats. All the animals with burns were divided into three experimental groups: control group with no wound treatment; group 1 was composed of animals with CrHFC application; and group 2 consisted of those with CrHFC and AuNPs (6 μg/ml) application to a burn surface the next day after the injury. The CrHFC was applied to the methylcellulose gel in a dose of 5 × 10(4) of viable cells per 1 cm(2) of the burn. The animals were removed from the experiment on day 21 after the treatment.The CrHFC use alone and with AuNPs to the surface of burns stimulated the wound healing compared with the control. The effect of using CrHFC was less pronounced compared to the CrHFC application with AuNPs. It was reflected in a slower recovery of burns and moderate lymphocytic infiltration of granulation tissue. Immunofluorescent analysis emphasized that the use of CrHFC with AuNPs accelerated the skin synthetic processes and was helpful in recovering type I and III collagen content on day 21 after therapy.The results were likely related primarily to the unique structure and antimicrobial properties of AuNPs. Our experimental study of the effect of CrHFC with AuNPs application on regenerative processes in burns gives some pre-conditions to the following advanced bio- and nanotechnology developments. PMID:26762263

  14. Optical Control of Electrons in Au Nanowires

    Science.gov (United States)

    Jones, Eric; Basnet, Gobind; Huang, Wayne; Flanders, Bret; Batelaan, Herman

    2016-05-01

    Gold nanowires, with diameters less than 100 nm, are novel sources for electron field emission. Their geometry confines the propagation of conduction electrons, giving rise to effects not seen in the bulk, such as ballistic currents and surface plasmon polaritons (SPPs). Dynamics within the wire are probed with laser-induced field emission from the nanowire tip. A balanced Mach-Zehnder interferometer is used to split and delay pulses up to 170 ps from a Ti:Saph oscillator (800 nm, 50 fs) in a pump-probe scheme. The output beamsplitter of the interferometer is mounted on a translation stage to control the separation of the pump and probe beams with sub-micron precision. The beams are focused to 3 μm spots on the tip and shaft of a nanowire, mounted under vacuum at 2 × 10-7 mTorr, by an off-axis parabolic mirror. Field-emitted electrons are counted by a channel electron multiplier. We discuss experimental results of our pump-probe experiments taken at different pump positions. Optical control of electron dynamics within these nanowires may lead to a truly on-demand source of single and multiple electron pulses. We gratefully acknowledge support from NSF awards 1306565 and 1430519.

  15. Fe/Au Core-Shell Nanoparticles for Biomedical Applications

    Science.gov (United States)

    Sra, Amandeep; Leslie-Pelecky, Diandra

    2009-10-01

    The physical properties of nanoparticles, including size, composition and surface chemistry, greatly influence biological and pharmacological properties and, ultimately, their clinical applications. Superparamagnetic iron oxide nanoparticles are widely used for applications such as MRI contrast agents, drug delivery via magnetic targeting and hyperthermia due to their chemical stability and biocompatibility; however, enhancing the saturation magnetization (Ms) of nanoparticles would produce greater sensitivity. Our design strategy involves a bottom-up wet chemistry approach to the synthesis of Fe nanoparticles. Specific advantages of Fe are the high value of Ms (210 emu/g in bulk) coupled with low toxicity; however, Fe nanoparticles must be protected from oxidation, which causes a dramatic reduction in Ms. To circumvent oxidation, Fe nanoparticles are coated with a Au shell that prevents the oxidation of the magnetic core and also provides the nanoparticles with plasmonic properties for optical stimulation. Ligands of various functionalities can be introduced through the well established Au-thiol surface chemistry for different biomedical applications while maintaining the magnetic functionality of the Fe core. In this presentation, we will discuss the physical, chemical and magnetic properties of our Fe/Au nanoparticles and their resistance to oxidation.

  16. Bright, NIR-emitting Au23 from Au25: characterization and applications including biolabeling.

    Science.gov (United States)

    Muhammed, Madathumpady Abubaker Habeeb; Verma, Pramod Kumar; Pal, Samir Kumar; Kumar, R C Arun; Paul, Soumya; Omkumar, Ramakrishnapillai Vyomakesannair; Pradeep, Thalappil

    2009-10-01

    A novel interfacial route has been developed for the synthesis of a bright-red-emitting new subnanocluster, Au(23), by the core etching of a widely explored and more stable cluster, Au(25)SG(18) (in which SG is glutathione thiolate). A slight modification of this procedure results in the formation of two other known subnanoclusters, Au(22) and Au(33). Whereas Au(22) and Au(23) are water soluble and brightly fluorescent with quantum yields of 2.5 and 1.3 %, respectively, Au(33) is organic soluble and less fluorescent, with a quantum yield of 0.1 %. Au(23) exhibits quenching of fluorescence selectively in the presence of Cu(2+) ions and it can therefore be used as a metal-ion sensor. Aqueous- to organic-phase transfer of Au(23) has been carried out with fluorescence enhancement. Solvent dependency on the fluorescence of Au(23) before and after phase transfer has been studied extensively and the quantum yield of the cluster varies with the solvent used. The temperature response of Au(23) emission has been demonstrated. The inherent fluorescence of Au(23) was used for imaging human hepatoma cells by employing the avidin-biotin interaction. PMID:19711391

  17. Control of fast non linear systems - application to a turbo charged SI engine with variable valve timing; controle des systemes rapides non lineaires - application au moteur a allumage commande turbocompresse a distribution variable

    Energy Technology Data Exchange (ETDEWEB)

    Colin, G.

    2006-10-15

    Spark ignition engine control has become a major issue for the compliance with emissions legislation while ensuring driving comfort. Engine down-sizing is one of the promising ways to reduce fuel consumption and resulting CO{sub 2} emissions. Combining several existing technologies such as supercharging and variable valve actuation, down-sizing is a typical example of the problems encountered in Spark Ignited (SI) engine control: nonlinear systems with saturation of actuators; numerous major physical phenomena not measurable; limited computing time; control objectives (consumption, pollution, performance) often competing. A methodology of modelling and model-based control (internal model and predictive control) for these systems is also proposed and applied to the air path of the down-sized engine. Models, physicals and generics, are built to estimate in-cylinder air mass, residual burned gases mass and air scavenged mass from the intake to the exhaust. The complete and generic engine torque control architecture for the turbo-charged SI engine with variable cam-shaft timing was tested in simulation and experimentally (on engine and vehicle). These tests show that new possibilities are offered in order to decrease pollutant emissions and optimize engine efficiency. (author)

  18. Colloidal Au-enhanced surface plasmon resonance imaging: application in a DNA hybridization process

    International Nuclear Information System (INIS)

    The detection of the DNA hybridization mechanism using monodispersed gold nanoparticles as labels is an interesting alternative to increase the sensitivity of the SPR imaging technique. DNA-modified Au nanoparticles (DNA-Au NPs) containing single-stranded (ss) portions of DNA were prepared by monitoring their monolayer formation by UV–vis spectroscopy. The hybridization process between specific thio-oligonucleotides immobilized on the DNA–Au NPs and the corresponding complementary strands is reported and compared with the traditional hybridization process on properly self-assembled thin gold films deposited on glass substrates. A remarkable signal amplification is observed, following the incorporation of colloidal Au into a SPR biosensing experiment, resulting in an increased SPR response to DNA–DNA interactions. In particular Fusarium thiolated DNA (5'HS poly(T)15ATC CCT CAA AAA CTG CCG CT-3) and trichothecenes complementary DNA (5'-AGC GGC AGT TTT TGA GGG AT-3') sequences have been explored due to their possible application to agro-industry for the control of food quality

  19. Colloidal Au-enhanced surface plasmon resonance imaging: application in a DNA hybridization process

    Science.gov (United States)

    Manera, M. G.; Spadavecchia, J.; Taurino, A.; Rella, R.

    2010-03-01

    The detection of the DNA hybridization mechanism using monodispersed gold nanoparticles as labels is an interesting alternative to increase the sensitivity of the SPR imaging technique. DNA-modified Au nanoparticles (DNA-Au NPs) containing single-stranded (ss) portions of DNA were prepared by monitoring their monolayer formation by UV-vis spectroscopy. The hybridization process between specific thio-oligonucleotides immobilized on the DNA-Au NPs and the corresponding complementary strands is reported and compared with the traditional hybridization process on properly self-assembled thin gold films deposited on glass substrates. A remarkable signal amplification is observed, following the incorporation of colloidal Au into a SPR biosensing experiment, resulting in an increased SPR response to DNA-DNA interactions. In particular Fusarium thiolated DNA (5'HS poly(T)15ATC CCT CAA AAA CTG CCG CT-3) and trichothecenes complementary DNA (5'-AGC GGC AGT TTT TGA GGG AT-3') sequences have been explored due to their possible application to agro-industry for the control of food quality.

  20. TiAu based shape memory alloys for high temperature applications

    International Nuclear Information System (INIS)

    TiAu (equiatomic) exhibits phase transformation from B2 (ordered bcc) to thermo-elastic orthorhombic B19 martensite at about 875K and thus TiAu is categorized as high temperature shape memory alloy. In this study, recent research and developments related to TiAu based high temperature shape memory alloys will be discussed in the Introduction part. Then some results of our research group related to strengthening of TiAu based high temperature shape memory alloys will be presented. Potential of TiAu based shape memory alloys for high temperature shape memory materials applications will also be discussed. (author)

  1. TiAu based shape memory alloys for high temperature applications

    International Nuclear Information System (INIS)

    TiAu (equiatomic) exhibits phase transformaion from B2 (ordered bcc) to thermo-elastic orthorhombic B19 martensite at about 875K and thus TiAu is categorized as high temperature shape memory alloy. In this study, recent research and developments related to TiAu based high temperature shape memory alloys will be discussed in the Introduction part. Then some results of our research group related to strengthening of TiAu based high temperature shape memory alloys will be presented. Potential of TiAu based shape memory alloys for high temperature shape memory materials applications will also be discussed

  2. Controlled shape modification of embedded Au nanoparticles by 3 MeV Au{sup 2+}-ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Datta, D.P., E-mail: debi@iopb.res.in [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005, Odisha (India); Quantum Beam Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0003 (Japan); Takeda, Y.; Amekura, H. [Quantum Beam Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0003 (Japan); Sasase, M. [Wakasa wan Energy Research Center, Nagatani, Tsuruga, Fukui 914-0192 (Japan); Kishimoto, N. [National Institute for Materials Science, Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-08-15

    Highlights: • By irradiation of 3 MeV Au{sup 2+} ions on spherical Au nanoparticles (NPs), shallowly-embedded in SiO{sub 2}, we have demonstrated the well-controlled fabrication of ellipsoidal Au NPs. • The observed nanostructural evolution can be qualitatively understood in terms of formation of a supersaturated solid solution and preferential growth of particles from the solution with a contribution from electronic energy loss induced elongation. • Our results indicate that inverse Ostwald ripening can be triggered after a certain amount of growth of the ellipsoids. • Our study thus provides a modification method for a shallow layer of embedded metal nanoparticles by MeV ion irradiation. - Abstract: Shape modification of embedded Au nanoparticles by 3 MeV Au{sup 2+}-ion irradiation has been studied by cross-sectional transmission electron microscopy (XTEM). The ion irradiation on spherical Au nanoparticles shallowly-embedded in SiO{sub 2} caused a well-controlled transformation of shape to ellipsoidal. Satellite nanoparticles of smaller sizes were found to nucleate around the ellipsoids. Rapid growth of the ellipsoidal nanoparticles was observed as the applied fluence increased from 3 × 10{sup 15} to 7 × 10{sup 15} ions cm{sup −2}. The XTEM study also revealed the crystallinity of the ellipsoids formed by MeV ion irradiation. Reduction in the surface plasmon resonance (SPR) peak intensity in the optical absorption spectrum indicates partial dissolution of the spherical nanoparticles by ion irradiation. We have thus obtained a unique near-surface structure of ellipsoidal nanoparticles. The results are discussed in terms of effects of ion energy deposition and inverse Ostwald ripening.

  3. Thermal stability of Mo/Au bilayers for TES applications

    International Nuclear Information System (INIS)

    Mo/Au bilayers are among the most suitable materials to be used as transition-edge sensors (TES) in cryogenic microcalorimeters and bolometers, developed, among other fields, for space missions. For this purpose the thermal stability of TES at temperatures below 150 °C is a critical issue. We report on the dependence of functional properties (superconducting critical temperature, residual resistance and α) as well as on microstructure, chemical composition and interface quality for optimized high quality Mo/Au bilayers on annealing temperature and time. Data show that the functional properties of the bilayers remain stable at T C at T ≥ 200 °C are mainly due to an increase in the average Au grain size and to Au migration along the Mo grain boundaries at the Au/Mo interface. A way to stabilize the functional properties of the Mo/Au bilayers against temperature enhancements is proposed. (paper)

  4. Application of 198Au grains for carcinoma of oral cavity

    International Nuclear Information System (INIS)

    The purpose of this study is to analyze the results of the treatment using gold grain implants over the past 9 years and to evaluate the usefulness of this treatment method. From January 1985 through April 1993, a total of 45 patients with squamous cell carcinomas of the oral cavity and the oropharynx were treated with 198Au grain (gold grain) at the Department of Radiology, Osaka University Medical School. The initial activity of the grains supplied weekly by the Japan Radioisotope Association was usually 5 mCi (185 MBq), and single implants were usual. In case of combined external irradiation, telecobalt γ-rays or 4 MV X-rays were used for treatment before implant. The local control rate for patients with T1 stages was 80% (20/25) and with T2 stages, 59% (10/17). The local control rate was 71% (10/14) for gold grain alone and 72% (13/18) for external irradiation combined with gold grain implants (combined therapy). In combined therapy, the median of the interval between external irradiation and gold grain implants was 21 days. The treatment interval or patients with recurrent diseases was 22 days, 22, 27, 39 and 46, respectively. The progression rate showed a tendency to increase in the patients with longer interval (more than 21 days), and with partial regression after external irradiation and gold grain implantation is an important factor in combined therapy. Therefore, we emphasize that the time interval should be shorter than 3 weeks. (orig.)

  5. Controlling the Atomic Structure of Au30 Nanoclusters by a Ligand-Based Strategy.

    Science.gov (United States)

    Higaki, Tatsuya; Liu, Chong; Zeng, Chenjie; Jin, Renxi; Chen, Yuxiang; Rosi, Nathaniel L; Jin, Rongchao

    2016-06-01

    We report the X-ray structure of a gold nanocluster with 30 gold atoms protected by 18 1-adamantanethiolate ligands (formulated as Au30 (S-Adm)18 ). This nanocluster exhibits a threefold rotationally symmetrical, hexagonal-close-packed (HCP) Au18 kernel protected by six dimeric Au2 (SR)3 staple motifs. This new structure is distinctly different from the previously reported Au30 S(S-(t) Bu)18 nanocluster protected by 18 tert-butylthiolate ligands and one sulfido ligand with a face-centered cubic (FCC) Au22 kernel. The Au30 (S-Adm)18 nanocluster has an anomalous solubility (it is only soluble in benzene but not in other common solvents). This work demonstrates a ligand-based strategy for controlling nanocluster structure and also provides a method for the discovery of possibly overlooked clusters because of their anomalous solubility. PMID:27099989

  6. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  7. Au coated Ni nanowires with tuneable dimensions for biomedical applications

    NARCIS (Netherlands)

    Pondman, K.M.; Maijenburg, A.W.; Celikkol, F.B.; Pathan, A.A.; Kishore, U.D.; Haken, ten B.; Elshof, ten J.E.

    2013-01-01

    Due to their shape anisotropy, high aspect ratio magnetic nanoparticles offer many advantages in biomedical applications. For biocompatibility, it is essential to have full control over the dimensions and surface chemistry of the particles. The aim of this study was to synthesize biocompatible nanow

  8. Solvent Control of Surface Plasmon-Mediated Chemical Deposition of Au Nanoparticles from Alkylgold Phosphine Complexes.

    Science.gov (United States)

    Muhich, Christopher L; Qiu, Jingjing; Holder, Aaron M; Wu, Yung-Chien; Weimer, Alan W; Wei, Wei David; McElwee-White, Lisa; Musgrave, Charles B

    2015-06-24

    Bottom-up approaches to nanofabrication are of great interest because they can enable structural control while minimizing material waste and fabrication time. One new bottom-up nanofabrication method involves excitation of the surface plasmon resonance (SPR) of a Ag surface to drive deposition of sub-15 nm Au nanoparticles from MeAuPPh3. In this work we used density functional theory to investigate the role of the PPh3 ligands of the Au precursor and the effect of adsorbed solvent on the deposition process, and to elucidate the mechanism of Au nanoparticle deposition. In the absence of solvent, the calculated barrier to MeAuPPh3 dissociation on the bare surface is deposition by the light induced SPR heating of the surface and nearby solution. PMID:26036274

  9. Au coated Ni nanowires with tuneable dimensions for biomedical applications

    OpenAIRE

    Pondman, K.M.; Maijenburg, A.W.; Celikkol, F.B.; Pathan, A A; Kishore, U.D.; Haken, ten, Bennie; Elshof, ten, J.E.

    2013-01-01

    Due to their shape anisotropy, high aspect ratio magnetic nanoparticles offer many advantages in biomedical applications. For biocompatibility, it is essential to have full control over the dimensions and surface chemistry of the particles. The aim of this study was to synthesize biocompatible nanowires with tuneable dimensions. This was achieved by electrodeposition of Ni in polycarbonate membranes. To ensure biocompatibility, a continuous gold coating was deposited onto the Ni wires by a ne...

  10. AuCu@Pt Nanoalloys for Catalytic Application in Reduction of 4-Nitrophenol

    Directory of Open Access Journals (Sweden)

    Sadia Mehmood

    2016-01-01

    Full Text Available To enhance and optimize nanocatalyst ability for nitrophenol (4-NP reduction reaction we look beyond Au-metal nanoparticles and describe a new class of Au nanoalloys with controlled composition for core of AuCu-metals and Pt-metal shell. The reduction of 4-NP was investigated in aqueous media spectroscopically on 7.8 nm Au nanospheres (AuNSs, 8.3 nm AuCuNSs, and 9.1 nm AuCu@Pt core-shell NSs in diameter. The rate constants of the catalyzed reaction at room temperature, activation energies, and entropies of activation of reactions catalyzed by the AuCu@Pt core-shell NSs are found to have different values to those of the pure metal NSs. The results strongly support the proposal that catalysis by nanoparticles is taking place efficiently on the surface of NSs. These core-shell nanocatalysts exhibited stability throughout the reduction reaction and proved that heterogonous type mechanisms are most likely to be dominant in nanoalloy based catalysis if the surface of the NSs is not defected upon shell incorporation.

  11. Facile Synthesis of Quasi-One-Dimensional Au/PtAu Heterojunction Nanotubes and Their Application as Catalysts in an Oxygen-Reduction Reaction.

    Science.gov (United States)

    Cai, Kai; Liu, Jiawei; Zhang, Huan; Huang, Zhao; Lu, Zhicheng; Foda, Mohamed F; Li, Tingting; Han, Heyou

    2015-05-11

    An intermediate-template-directed method has been developed for the synthesis of quasi-one-dimensional Au/PtAu heterojunction nanotubes by the heterogeneous nucleation and growth of Au on Te/Pt core-shell nanostructures in aqueous solution. The synthesized porous Au/PtAu bimetallic nanotubes (PABNTs) consist of porous tubular framework and attached Au nanoparticles (AuNPs). The reaction intermediates played an important role in the preparation, which fabricated the framework and provided a localized reducing agent for the reduction of the Au and Pt precursors. The Pt7 Au PABNTs showed higher electrocatalytic activity and durability in the oxygen-reduction reaction (ORR) in 0.1 M HClO4 than porous Pt nanotubes (PtNTs) and commercially available Pt/C. The mass activity of PABNTs was 218 % that of commercial Pt/C after an accelerated durability test. This study demonstrates the potential of PABNTs as highly efficient electrocatalysts. In addition, this method provides a facile strategy for the synthesis of desirable hetero-nanostructures with controlled size and shape by utilizing an intermediate template. PMID:25833689

  12. Inverse method for effects characterization from ultrasonic b-scan images; Caracterisation des defauts par une methode d'inversion lors d'un controle ultrasonore. Application au controle des defauts en paroi externe

    Energy Technology Data Exchange (ETDEWEB)

    Faur, M. [Paris-11 Univ., 91 - Orsay (France)

    1999-02-01

    In service inspections of French nuclear pressure water reactor vessels are carried out automatically in complete immersion from the inside by means of ultrasonic focused probes working in the pulse echo mode. Concern has been expressed about the capabilities of performing non destructive evaluation of the Outer Surface Defects (OSD), i.e. defects located in the vicinity of the outer surface of the inspected components. OSD are insonified by both a direct field that passes through the inner surface (water/steel) of the component containing the defect and a secondary field reflected from the outer surface. Consequently, the Bscan images, containing the signatures of such defects, are complicated and their interpretation is a difficult task. This work deals with extraction of the maximum available information for characterizing OSD from ultrasonic Bscan images. Our main objectives are to obtain the type of OSD and their geometric parameters by means of two specific inverse methods. The first method is used for the identification of the geometrical parameters of the equivalent planar OSD from segmented Bscan images. Ultrasonic equivalent defect sizing model-based methods may be used to size a defect in a material by obtaining a best-fit simple equivalent shape that matches the ultrasonic observed data. We illustrate the application of such an equivalent sizing OSD method that is based on a simplified direct model. The major drawback of this identification method, as used to date, is that only a part of the useful information contained into original Bscan image, i.e. segmented Bscan image, is used for defect characterization. Moreover, it requires the availability of defect classification information (i.e. if the defect is volumetric or planer, e. g. a crack or a lack of fusion), which, generally, may be as difficult to obtain as the defect parameters themselves. Therefore, we propose a parameter estimation method for extracting complementary information on the defect

  13. Enzymatic deposition of Au nanoparticles on the designed electrode surface and its application in glucose detection.

    Science.gov (United States)

    Zhang, Hongfang; Liu, Ruixiao; Sheng, Qinglin; Zheng, Jianbin

    2011-02-01

    This paper reported the enzymatic deposition of Au nanoparticles (AuNPs) on the designed 3-mercapto-propionic acid/glucose oxidase/chitosan (MPA/GOD/Chit) modified glassy carbon electrode and its application in glucose detection. Chit served as GOD immobilization matrix and interacted with MPA through electrostatic attraction. AuNPs, without nano-seeds presented on the electrode surface, was produced through the glucose oxidase catalyzed oxidation of glucose. The mechanism of production of AuNPs was confirmed to be that enzymatic reaction products H(2)O(2) in the solution reduce gold complex to AuNPs. The characterizations of the electrode modified after each assembly step was investigated by cyclic voltammetry and electrochemical impedance spectroscopy. Scanning electron microscopy showed the average particle size of the AuNPs is 40nm with a narrow particle size distribution. The content of AuNPs on the electrode surfaces was measured by differential pulse stripping voltammetry. The electrochemical signals on voltammogram showed a linear increase with the glucose concentration in the range of 0.010-0.12mM with a detection limit of 4μM. This provided a method to the determination of glucose. PMID:21115279

  14. Morphological evolution of Au nanowires controlled by Rayleigh instability

    Energy Technology Data Exchange (ETDEWEB)

    Karim, S [Department of Chemistry, Philipps University, Marburg (Germany); Toimil-Molares, M E [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Balogh, A G [Institute of Material Science, Darmstadt University of Technology, Darmstadt (Germany); Ensinger, W [Institute of Material Science, Darmstadt University of Technology, Darmstadt (Germany); Cornelius, T W [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Khan, E U [Department of Physics, CIIT, Islamabad (Pakistan); Neumann, R [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany)

    2006-12-28

    A sound knowledge and understanding of the thermal stability of nanowires is a prerequisite for the reliable implementation of nanowire-based devices. We investigate the morphology of Au nanowires annealed isothermally at different temperatures. During the processes, triggered by heating, the wires undergo various configurational changes to finally break up into chains of nanospheres at much lower than bulk melting temperatures due to capillary or so-called Rayleigh instability. The role of three parameters, namely, wire diameter, temperature, and annealing time, on the final morphology is investigated. Both the average sphere diameter and the mean spacing between adjacent spheres are larger than the values predicted for materials with isotropic surface energy. Possible reasons are discussed in the paper.

  15. Morphological evolution of Au nanowires controlled by Rayleigh instability

    International Nuclear Information System (INIS)

    A sound knowledge and understanding of the thermal stability of nanowires is a prerequisite for the reliable implementation of nanowire-based devices. We investigate the morphology of Au nanowires annealed isothermally at different temperatures. During the processes, triggered by heating, the wires undergo various configurational changes to finally break up into chains of nanospheres at much lower than bulk melting temperatures due to capillary or so-called Rayleigh instability. The role of three parameters, namely, wire diameter, temperature, and annealing time, on the final morphology is investigated. Both the average sphere diameter and the mean spacing between adjacent spheres are larger than the values predicted for materials with isotropic surface energy. Possible reasons are discussed in the paper

  16. Quality Control Applications

    CERN Document Server

    Chorafas, Dimitris N

    2013-01-01

    Quality control is a constant priority in electrical, mechanical, aeronautical, and nuclear engineering – as well as in the vast domain of electronics, from home appliances to computers and telecommunications. Quality Control Applications provides guidance and valuable insight into quality control policies; their methods, their implementation, constant observation and associated technical audits. What has previously been a mostly mathematical topic is translated here for engineers concerned with the practical implementation of quality control. Once the fundamentals of quality control are established, Quality Control Applications goes on to develop this knowledge and explain how to apply it in the most effective way. Techniques are described and supported using relevant, real-life, case studies to provide detail and clarity for those without a mathematical background. Among the many practical examples, two case studies dramatize the importance of quality assurance: A shot-by-shot analysis of the errors made ...

  17. Controllable assembly of well-defined monodisperse Au nanoparticles on hierarchical ZnO microspheres for enhanced visible-light-driven photocatalytic and antibacterial activity

    Science.gov (United States)

    Wang, Yuan; Fang, Hua-Bin; Zheng, Yan-Zhen; Ye, Rongqin; Tao, Xia; Chen, Jian-Feng

    2015-11-01

    A high-efficiency visible-light-driven photocatalyst composed of homogeneously distributed Au nanoparticles (AuNPs) well-defined on hierarchical ZnO microspheres (ZMS) via a controllable layer-by-layer self-assembly technique is demonstrated. The gradual growth of the characteristic absorption bands of Au loaded on ZnO in the visible light region with an increasing number of assemblies indicates the enhancement of the light harvesting ability of the ZMS/Au composites as well as the reproducibility and controllability of the entire assembly process. Results on the photoelectrochemical performance characterized by EIS and transient photocurrent response spectra indicate that the ZMS/Au composites possess increased photoinduced charge separation and transfer efficiency compared to the pure ZMS film. As a result, the hybrid composites exhibited enhanced decomposition activity for methylene blue and salicylic acid as well as antibacterial activity in killing S. aureus and E. coli under visible light irradiation. It can be noted that well-distributed Au components even at a rather low Au/ZnO weight ratio of ~1.2% also exhibited extraordinary photocatalysis. Such a facile and controllable self-assembly approach may be viable for preparing high-performance visible-light-driven ZMS/Au photocatalysts in a simple and controllable way, and consequently, the technology may extend to other plasmon-enhanced heterostructures made of nanostructured semiconductors and noble metals for great potential application in environmental protection.A high-efficiency visible-light-driven photocatalyst composed of homogeneously distributed Au nanoparticles (AuNPs) well-defined on hierarchical ZnO microspheres (ZMS) via a controllable layer-by-layer self-assembly technique is demonstrated. The gradual growth of the characteristic absorption bands of Au loaded on ZnO in the visible light region with an increasing number of assemblies indicates the enhancement of the light harvesting ability of

  18. Role of Carboxylate ligands in the Synthesis of AuNPs: Size Control, Molecular Interaction and Catalytic Activity

    KAUST Repository

    Aljohani, Hind Abdullah

    2016-05-22

    Nanoparticles (NPs) are the basis of nanotechnology and finding numerous applications in various fields such as health, electronics, environment, personal care products, transportation, and catalysis. To fulfill these functions, the nanoparticles must be synthesized, passivated to control their chemical reactivity, stabilized against aggregation and functionalized to achieve specific performances. The chemistry of metal nanoparticles especially that of noble metals (Gold, Platinum…) is a growing field. The nanoparticles have indeed different properties from those of the corresponding bulk material. These properties are largely influenced by several parameters; the most important are the size, shape, and the local environment of the nanoparticles. One of the most common synthetic methods for the preparation of gold nanoparticles (AuNPs) is based on stabilization by citrate. Since it was reported first by Turkevich et al. in 1951, this synthetic scheme has been widely used, studied and a substantial amount of important information regarding this system has been reported in the literature. The most popular method developed by Frens for controlling the size of the noble gold nanoparticles based on citrate was achieved by varying the concentration of sodium citrate. Despite a large number of investigations focused on utilizing Cit-AuNPs, the structural details of citrate anions adsorbed on the AuNP surface are still unknown. It is known only that citrate anions “coordinate” to the metal surface by inner sphere complexation of the carboxylate groups and there are trace amounts of AuCl4−, Cl−, and OH− on the metal surface. Moreover, it is generally accepted that the ligand shell morphology of Au nanoparticles can be partly responsible for important properties such as oxidation of carbon monoxide. The use of Au-NPs in heterogeneous catalysis started mostly with Haruta who discovered the effect of particle size on the activity for carbon monoxide oxidation at

  19. Dynamic Control of Plasmon-Exciton Coupling in Au Nanodisk–J-Aggregate Hybrid Nanostructure Arrays

    KAUST Repository

    Zheng, Yue Bing

    2009-01-01

    We report the dynamic control of plasmon-exciton coupling in Au nanodisk arrays adsorbed with J-aggregate molecules by incident angle of light. The angle-resolved spectra of an array of bare Au nanodisks exhibit continuous shifting of localized surface plasmon resonances. This characteristic enables the production of real-time, controllable spectral overlaps between molecular and plasmonic resonances, and the efficient measurement of plasmon-exciton coupling as a function of wavelength with one or fewer nanodisk arrays. Experimental observations of varying plasmon-exciton coupling match with coupled dipole approximation calculations.

  20. Nitrite ion-induced fluorescence quenching of luminescent BSA-Au(25) nanoclusters: mechanism and application.

    Science.gov (United States)

    Unnikrishnan, Binesh; Wei, Shih-Chun; Chiu, Wei-Jane; Cang, Jinshun; Hsu, Pang-Hung; Huang, Chih-Ching

    2014-05-01

    Fluorescence quenching is an interesting phenomenon which is highly useful in developing fluorescence based sensors. A thorough understanding of the fluorescence quenching mechanism is essential to develop efficient sensors. In this work, we investigate different aspects governing the nitrite ion-induced fluorescence quenching of luminescent bovine serum albumin stabilized gold nanoclusters (BSA-Au NCs) and their application for detection of nitrite in urine. The probable events leading to photoluminescence (PL) quenching by nitrite ions were discussed on the basis of the results obtained from ultraviolet-visible (UV-Vis) absorption spectroscopy, X-ray photoelectron spectroscopy (XPS), fluorescence measurements, circular dichroism (CD) spectroscopy, zeta potential and dynamic light scattering (DLS) studies. These studies suggested that PL quenching mainly occurred through the oxidation of Au(0) atoms to Au(i) atoms in the core of BSA-Au NCs mediated by nitrite ions. The interference caused by certain species such as Hg(2+), Cu(2+), CN(-), S(2-), glutathione, cysteine, etc. during the nitrite determination by fluorescence quenching was eliminated by using masking agents and optimising the conditions. Based on these findings we proposed a BSA-Au NC-modified membrane based sensor which would be more convenient for the real life applications such as nitrite detection in urine samples. The BSA-Au NC-modified nitrocellulose membrane (NCM) enabled the detection of nitrite at a level as low as 100 nM in aqueous solutions. This Au NC-based paper probe was validated to exhibit good performance for nitrite analysis in environmental water and urine samples, which makes it useful in practical applications. PMID:24634911

  1. Adsorption mechanisms of L-Glutathione on Au and controlled nano-patterning through Dip Pen Nanolithography

    Energy Technology Data Exchange (ETDEWEB)

    Calborean, A., E-mail: adrian.calborean@gmail.com [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania); Martin, F.; Marconi, D.; Turcu, R.; Kacso, I.E.; Buimaga-Iarinca, L. [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania); Graur, F. [Iuliu Haţieganu University of Medicine and Pharmacy Cluj-Napoca, Babeş 8, 400012 Cluj-Napoca (Romania); Turcu, I. [National Institute for Research and Development of Isotopic and Molecular Technologies, Donat 67-103, 400293 Cluj-Napoca (Romania)

    2015-12-01

    Dip Pen Nanolithography technique has been employed for patterning L-Glutathione tripeptide (L-y-glutamyl-L-cysteinyl-glycine) nanostructures at specific locations on metallic Au(111) substrate. The formed supramolecular architectures were designed through straight lines and dots serving as precursors for building blocks assemblies in nano-bio-electronics applications or as template structures for functionalized particles in the form of host–guest networks. Tween 20 polyoxyethylene surfactant concentrations ranging from 0.005 to 0.1% (v/v) into initial L-Glutathione tripeptide (2 mg mL{sup −1}) ink solutions were sequentially tested for the improvement of the ink delivery process and to assure an optimum uniformity and homogeneity over the patterned space. A strong relationship was found between the coated atomic force microscope (AFM) cantilever within the highly effective Tween 20 activator adjuvant and the molecular diffusion along concentration gradients. An increase in the driving force for ink transport from the AFM tip has been demonstrated within the highest 0.1% (v/v) TW 20 surfactant concentration, favoring the patterning of GSH molecules routinely with sub-100 nm resolution. Self-assembled monolayers of GSH were also fabricated and characterized in the light of X-ray photoemission spectroscopy (XPS) and ellipsometric optical measurements. Adsorption from water of L-Glutathione to the gold substrate is proven to be made by the thiol group of cysteine. Theoretical DFT approaches were applied for quantum chemical studies dedicated to electronic processes underneath molecular GSH/Au(111) systems. - Highlights: • Controlled nano-patterning of L-Glutathione was performed on Au by DPN. • Tween 20 was used for increasing driving force of molecular ink transport. • SAM's formation has described the adsorption mechanisms of L-Glutathione on Au. • Electronic properties of hybrid GSH/Au(111) structures were investigated by DFT. • Validation of

  2. Adsorption mechanisms of L-Glutathione on Au and controlled nano-patterning through Dip Pen Nanolithography

    International Nuclear Information System (INIS)

    Dip Pen Nanolithography technique has been employed for patterning L-Glutathione tripeptide (L-y-glutamyl-L-cysteinyl-glycine) nanostructures at specific locations on metallic Au(111) substrate. The formed supramolecular architectures were designed through straight lines and dots serving as precursors for building blocks assemblies in nano-bio-electronics applications or as template structures for functionalized particles in the form of host–guest networks. Tween 20 polyoxyethylene surfactant concentrations ranging from 0.005 to 0.1% (v/v) into initial L-Glutathione tripeptide (2 mg mL−1) ink solutions were sequentially tested for the improvement of the ink delivery process and to assure an optimum uniformity and homogeneity over the patterned space. A strong relationship was found between the coated atomic force microscope (AFM) cantilever within the highly effective Tween 20 activator adjuvant and the molecular diffusion along concentration gradients. An increase in the driving force for ink transport from the AFM tip has been demonstrated within the highest 0.1% (v/v) TW 20 surfactant concentration, favoring the patterning of GSH molecules routinely with sub-100 nm resolution. Self-assembled monolayers of GSH were also fabricated and characterized in the light of X-ray photoemission spectroscopy (XPS) and ellipsometric optical measurements. Adsorption from water of L-Glutathione to the gold substrate is proven to be made by the thiol group of cysteine. Theoretical DFT approaches were applied for quantum chemical studies dedicated to electronic processes underneath molecular GSH/Au(111) systems. - Highlights: • Controlled nano-patterning of L-Glutathione was performed on Au by DPN. • Tween 20 was used for increasing driving force of molecular ink transport. • SAM's formation has described the adsorption mechanisms of L-Glutathione on Au. • Electronic properties of hybrid GSH/Au(111) structures were investigated by DFT. • Validation of

  3. Size Control and Growth Process Study of Au@Cu2O Particles.

    Science.gov (United States)

    Wang, Yuyuan; Zheng, Min; Liu, Shengnan; Wang, Zuoshan

    2016-12-01

    Au@Cu2O cuboctahedron with gold triangular nanoplate core and Cu2O shell was synthesized by a chemical method. X-ray diffraction (XRD) and transmission electron microscopy (TEM) tests demonstrated that the as-synthesis samples were consisted of gold triangular nanoplate core and Cu2O shell, and both of them were in good crystallization. The effective size control of the particles could be realized by controlling the amount of Au cores added in the synthetic process and Au@Cu2O particles with different shell thickness could be synthesized. The decrease of Cu2O shell thickness had a great difference in the optical performance, including blue shift of the resonant peaks and enhanced absorption intensity. The growth process from rough sheet structure to cuboctahedron was also explored. The results of photocatalytic degradation experiment showed that Au@Cu2O particles showed much better photocatalytic performance than that of pure Cu2O. The improved photocatalytic property of the Au@Cu2O particles was attributed to the comprehensive effect of the enhanced visible-light absorption and high separation rate of electron-hole pairs. PMID:27613067

  4. Impedance measurements on Au microelectrodes using controlled atmosphere high temperature scanning probe microscope

    DEFF Research Database (Denmark)

    Wu, Yuehua; Hansen, Karin Vels; Jacobsen, Torben;

    2011-01-01

    High temperature impedance measurements on Au microelectrodes deposited on polished yttria stabilized zirconia (YSZ) pellets were demonstrated using a newly designed controlled atmosphere high temperature scanning probe microscope (CAHT-SPM). Probes based on Pt0.8Ir0.2 were fabricated and employed...

  5. Application of radioisotopes Au -198 to radiometrical field investigation of spraying machine

    Energy Technology Data Exchange (ETDEWEB)

    Goraczko, W.; Kocorowska, E. [Technical Univeristy, Poznan (Poland). Radio and Photo-Chemistry Department

    1997-10-01

    The poster shows application of radioisotope {sup 198}Au to radiometrical field testing of spraying machine. In the research was tested the Polish suspensioned tractor OZS400 type spraying machine. The machine worked in two different variants: without and with the beam stabilisation (oscillatory stabilisation)

  6. Application of radioisotopes Au -198 to radiometrical field investigation of spraying machine

    International Nuclear Information System (INIS)

    The poster shows application of radioisotope 198Au to radiometrical field testing of spraying machine. In the research was tested the Polish suspensioned tractor OZS400 type spraying machine. The machine worked in two different variants: without and with the beam stabilisation (oscillatory stabilisation)

  7. Organisation and Control of Nanoscale Structures on Au(111)

    DEFF Research Database (Denmark)

    Zhang, Jingdong; Chi, Qijin; Andersen, Jens Enevold Thaulov;

    2001-01-01

    system is IDe arnino acid cystine in the adsorbed state. Af ter dissociation of its disulfide band cystine farms a highly ordered pattem controlled by adsorption via IDe liberated sulfur atoms and intermolecular hydrogen bonding. Further organisation at three different leveis by lateral interactions can...... be distinguished by the complementary lise of single-crystal voltammetry and in situ STM. The second target molecule is the bine single-copper protein azurin which is shown to form monolayers which retain their lang-range electron transfer function through the protein in the adsorbed state. The third...

  8. Mesoporous Silica Supported Au Nanoparticles with Controlled Size as Efficient Heterogeneous Catalyst for Aerobic Oxidation of Alcohols

    Directory of Open Access Journals (Sweden)

    Xuefeng Chu

    2015-01-01

    Full Text Available A series of Au catalysts with different sizes were synthesized and employed on amine group functionalized ordered mesoporous silica solid supports as catalyst for the aerobic oxidation of various alcohols. The mesoporous silica of MCM-41 supported Au nanoparticles (Au-1 exhibited the smallest particle size at ~1.8 nm with superior catalytic activities owing to the confinement effect of the mesoporous channels. Au-1 catalyst is also very stable and reusable under aerobic condition. Therefore, this presented work would obviously provide us a platform for synthesizing more size-controlled metal catalysts to improve the catalytic performances.

  9. Control of spin-polarized electron magnetoresistance in Ta/NiFe/Ta films by intercalation of Au

    International Nuclear Information System (INIS)

    Intercalation layers of Au were formed in Ta/NiFe/Ta films to control the interface properties of the films. It was found that small amounts of Au may enhance the magnetoresistance (MR) value up to 2.63%. The intercalation at different interfaces had different effects. Intercalation of Au at the top (bottom) interface with respect to the substrate exhibits weak (strong) diffusion of Au into NiFe. At weak diffusion, a homogeneous Au layer is formed which explains the large MR effect. At strong diffusion, since Au possesses a relatively strong spin-orbit interaction, the enhanced MR effect was explained by the spin-orbit scattering of polarized electrons in the NiFe layer.

  10. FRET controlled photoluminescence in β-In2S3 microflower—Au nanoparticle ensemble

    Science.gov (United States)

    Warrier, Anita R.; Parameswaran, Chithra; Bingi, Jayachandra; Vijayan, C.

    2016-06-01

    We report on the exciton–plasmon interaction and fluorescence resonance energy transfer controlled photoluminescence quenching and switching in β-In2S3 microflowers dispersed in Au nanoparticle colloid. The strong resonant interaction of excited β-In2S3 microflowers with the surface plasmons of Au nanoparticles (∼520 nm) lead to shift in the excitonic binding energy (2.4 eV) with a magnitude of ∼50 meV. In the proximity of Au nanoparticles, the broad emission spectrum of β-In2S3 microflowers with prominent peak at wavelength of ∼540 nm is quenched and the peak switches to wavelength of ∼600 nm. We demonstrate that the quenching and switching of emission band depends on the rate of fluorescence resonance energy transfer, extent of spectral overlap and β-In2S3 microflowers (donor)- Au nanoparticles (acceptor) distance. This study opens the wide possibility of fabricating sensors and photonic devices with tunable optical properties.

  11. Controlled building of CdSe@ZnS/Au and CdSe@ZnS/ Au2S/Au nanohybrids

    Institute of Scientific and Technical Information of China (English)

    Raquel E. Galian[1; Pilar Diaz[1; Antonio Ribera[1; Alejandro Rincon-Bertolin[1; Said Agouram[2; Julia Perez-Prieto[1

    2015-01-01

    The addition of Au3. to spherical amine-capped CdSe@ZnS nanoparticles in toluene at room temperature and under darkness can lead to ternary CdSe@ZnS/Au nanohybrids. We demonstrate that this happens only when the nanoparticles possess a relatively thin ZnS shell, thus showing that thickness plays a key role in gold deposition on the CdSe@ZnS nanoparticle surface. Our hypothesis is that the amine ligand acts as the reductant of Au3+ ions into Au+ ions, whose affinity for sulfur would keep them at the CdSe@ZnS surface. This interaction stabilizes the Au+ ion, making it less prone to reduction than a non-coordinated Au+ ion. In CdSe@ZnS with a thin shell, Au+ ions at the surface of, or most probably within, the ZnS shell cause the transfer of Cd2+ ions into the solution. Subsequently, the core Se2- anion, which is a better reductant than the shell S2- reduces Au+ ions to Au(0), and large gold nanoparticles (AuNPs) are quickly deposited on the CdSe@ZnS surface in room temperature process, leading to ternary CdSe@ZnS/Au nanohybrids. In solution, these ternary nanohybrids progressively transform into quaternary CdSe@ZnS/Au2S/Au nanohybrids due to the reaction of the shell S2- anion with the remaining Au+ at the CdSe@ZnS surface, thus leading to the growth of Au2S nanoparticles on the CdSe@ZnS surface while Zn concomitantly leaches from the nanohybrid into the solution. Photoirradiation of the heterostructures with visible light enhances their emission efficiency. Comparatively, irradiation of the precursors, i.e., CdSe@ZnS nanoparticles, causes a drastic decrease in their emission accompanied by a blue shift of their emission maximum. The optical properties of these nanohybrids were analyzed by absorption and fluorescence (steady-state and time-resolved) spectroscopy, and the composition of the samples and the chemical states were determined by energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy

  12. Large coincidence lattice on Au/Fe3O4 incommensurate structure for spintronic applications

    Science.gov (United States)

    Muñoz-Noval, Alvaro; Rubio-Zuazo, Juan; Salas-Colera, Eduardo; Serrano, Aida; Rubio-Marcos, Fernando; Castro, Germán R.

    2015-11-01

    The design of metallic hybrid systems for spintronics has been widely studied during the past decade, motivated by the promising technological applications of these materials. Nevertheless, the importance of preserving the native structure and properties of the interfaces is often ignored. Here, we present the fabrication of nanocrystalline Au (0 0 1) onto a single oriented Fe3O4 (0 0 1) thin film as a promising hybrid system to develop spintronic devices by growing Au over the Fe3O4 by using a simple one-pot Pulsed Laser Deposition (PLD) approach. The structural coupling between Au nanocrystals and Fe3O4 layer results in the development of an incommensurate structure based on a coincidence lattice of order 35, which preserves the intrinsic properties of the Au nanocrystals, the Fe3O4 matrix and the interface between them. The general strategy described in the present work preserves the structure and main intrinsic properties of the constituting materials, being a fundamental issue for the future development of spintronic devices.

  13. 分布式神经元PID在不均衡系统同步控制中的应用%Application of Distributed Neuron PID in Synchronous Controlling of au Unbalanced System

    Institute of Scientific and Technical Information of China (English)

    乌建中; 侯贤士; 陈吉

    2009-01-01

    The hydraulic turnover mechanism,using a dual cylinder hinge,is an advanced blade mould closing equipment of high technologies,mostly used for megawatt class wind blades above 40 meters,where more than three mechanisms are arranged along one blade mould at the same time.Obviously,there will be an unbalanced load on each mechanism due to the irregular shape of moulds and the inaccurate installing locations.The synchronous performance of multiple rotating arms.during a large-angle rotating process,directly influences the service life of blade moulds and the production quality of wind blades.For the turnover mechanism toenjoy high reliability,adaptability and control accuracy,a newcontrol method using the distributed single neuron PID algorithm is proposed for a synehmnons control of angular displacement of rotating arms.An improved LMS algorithm is used in the learning process,and the gain of the neuron output is adjusted automatically by the neuron based on the motion analysis results.Through rotating motion analysis with iterations,some basic parameters aredetermined,and a mechanical and hydraulic combined simulation model in AMESim is established,including a planar mechanical model.The LabVIEW subprogram of neuron PID could be nm through dynamic shared memory simultaneously.Finally,the results of traditional PID and neuron PID are shown in the gaule plot.It is shown through simulation results as well as practical applications that this method enjoys a good conlaml accuracy for nonlinear and time variant unbalanced systems.%大型风电叶片模具的合模或脱模,采用双缸铰接的液压翻转机构,其在大角度翻转过程中多转臂同步性能将直接影响翻转模具的寿命和叶片生产质量.针对该翻转设备可靠性、适应性和控制精度要求较高的特点,提出一种分布式的单神经元PID控制算法对机构转臂进行角位移同步控制,学习过程采用改进的LMS算法,并根据运动分析结果实现神经元输

  14. AZO/Au/AZO tri-layer thin films for the very low resistivity transparent electrode applications

    International Nuclear Information System (INIS)

    Highlights: • High-quality Al-doped ZnO (AZO)/Au/AZO transparent conducting oxide films. • AZO films (30 nm) made by RF sputtering; ion sputtering for Au film (5–20 nm). • Effects of Au thickness on optical and electrical properties were analyzed. • The resistivity of 9 × 10−5 Ω cm and the transmittance of 86.2% of the multilayer films were obtained in this study. - Abstract: Aluminum-doped ZnO (AZO)/gold/AZO tri-layer structures with very low resistivity and high transmittance are prepared by simultaneous RF magnetron sputtering (for AZO) and ion sputtering (for Au). The properties of the tri-layer films are investigated at different Au layer thicknesses (5–20 nm). The effects of Au layer thickness and the role of Au on the transmission properties of the tri-layer films were investigated. The very low resistivity of 1.01 × 10−5 Ω cm, mobility of 27.665 cm2 V−1 s−1, and carrier concentration of 4.563 × 1022 cm−3 were obtained at an Au layer thickness of 20 nm. The peak transmittance of 86.18% at 650-nm wavelength was obtained at an Au layer thickness of 8 nm. These results show the films to be a good candidate for high-quality electrode scheme in various display applications

  15. AZO/Au/AZO tri-layer thin films for the very low resistivity transparent electrode applications

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Chien-Hsun [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan (China); Wu, Hung-Wei, E-mail: hwwu@mail.ksu.edu.tw [Department of Computer and Communication, Kun Shan University, Tainan 71003, Taiwan (China); Huang, Jow-Lay [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan (China); Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 81148, Taiwan (China); Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 70101, Taiwan (China)

    2014-08-01

    Highlights: • High-quality Al-doped ZnO (AZO)/Au/AZO transparent conducting oxide films. • AZO films (30 nm) made by RF sputtering; ion sputtering for Au film (5–20 nm). • Effects of Au thickness on optical and electrical properties were analyzed. • The resistivity of 9 × 10{sup −5} Ω cm and the transmittance of 86.2% of the multilayer films were obtained in this study. - Abstract: Aluminum-doped ZnO (AZO)/gold/AZO tri-layer structures with very low resistivity and high transmittance are prepared by simultaneous RF magnetron sputtering (for AZO) and ion sputtering (for Au). The properties of the tri-layer films are investigated at different Au layer thicknesses (5–20 nm). The effects of Au layer thickness and the role of Au on the transmission properties of the tri-layer films were investigated. The very low resistivity of 1.01 × 10{sup −5} Ω cm, mobility of 27.665 cm{sup 2} V{sup −1} s{sup −1}, and carrier concentration of 4.563 × 10{sup 22} cm{sup −3} were obtained at an Au layer thickness of 20 nm. The peak transmittance of 86.18% at 650-nm wavelength was obtained at an Au layer thickness of 8 nm. These results show the films to be a good candidate for high-quality electrode scheme in various display applications.

  16. Optical and structural properties of Au-Ag islands films for plasmonic applications

    Energy Technology Data Exchange (ETDEWEB)

    Sancho-Parramon, J.; Janicki, V.; Loncaric, M.; Zorc, H.; Dubcek, P. [Ruder Boskovic Institute, Zagreb (Croatia); Bernstorff, S. [Sincrotrone Trieste, Basovizza Trieste (Italy)

    2011-06-15

    Bimetallic islands films consisting of composite Au-Ag nanoparticles are deposited on glass substrates by electron beam evaporation. Broad tuning of the surface-plasmon resonance (SPR) characteristics can be achieved by controlling film composition, deposition temperature and post-deposition thermal annealing. Optical and structural characterization of the samples enable one to establish the link between the SPR and the morphological and compositional characteristics of nanoparticles. (orig.)

  17. Controllable synthesis and characterization of Fe3O4/Au composite nanoparticles

    International Nuclear Information System (INIS)

    Fe3O4/Au composite nanoparticles (GoldMag NPs) have received considerable attention because of their advantageous properties arisen from both individual Au and Fe3O4 nanoparticles. Many efforts have been devoted to the synthesis of these composite nanoparticles. Herein, GoldMag NPs were reported to be synthesized by two-step method. Fe3O4 nanoparticles were prepared by co-precipitation and modified by the citric acid, and then citric acid-coated Fe3O4 nanoparticles were used as seeds in sodium citrate solution to reduce the HAuCl4. The size of obtained nanoparticles was geared from 25 to 300 nm by controlling the concentration of reactants. The GoldMag NPs were characterized by UV–vis spectrometer, dynamic light scattering (DLS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The GoldMag NPs showed good superparamagnetism at room temperature and were well dispersed in water with surface plasmon resonance absorption peak varied from 538 nm to 570 nm. - Highlights: • A low cost, simple manipulation and nontoxic approach was designed for preparation of magnetic Fe3O4/Au (GoldMag NPs) nanocomposites. • The size of GoldMag NPs could be controlled from 25 to 300 nm by varying the concentration of reactants. • GoldMag NPs possessed good magnetic response, high dispersion, and good stability

  18. Highly narrow nanogap-containing Au@Au core-shell SERS nanoparticles: size-dependent Raman enhancement and applications in cancer cell imaging

    Science.gov (United States)

    Hu, Chongya; Shen, Jianlei; Yan, Juan; Zhong, Jian; Qin, Weiwei; Liu, Rui; Aldalbahi, Ali; Zuo, Xiaolei; Song, Shiping; Fan, Chunhai; He, Dannong

    2016-01-01

    Cellular imaging technologies employing metallic surface-enhanced Raman scattering (SERS) tags have gained much interest toward clinical diagnostics, but they are still suffering from poor controlled distribution of hot spots and reproducibility of SERS signals. Here, we report the fabrication and characterization of high narrow nanogap-containing Au@Au core-shell SERS nanoparticles (GCNPs) for the identification and imaging of proteins overexpressed on the surface of cancer cells. First, plasmonic nanostructures are made of gold nanoparticles (~15 nm) coated with gold shells, between which a highly narrow and uniform nanogap (~1.1 nm) is formed owing to polyA anchored on the Au cores. The well controlled distribution of Raman reporter molecules, such as 4,4'-dipyridyl (44DP) and 5,5'-dithiobis(2-nitrobenzoic acid) (DTNB), are readily encoded in the nanogap and can generate strong, reproducible SERS signals. In addition, we have investigated the size-dependent SERS activity of GCNPs and found that with the same laser wavelength, the Raman enhancement discriminated between particle sizes. The maximum Raman enhancement was achieved at a certain threshold of particle size (~76 nm). High narrow nanogap-containing Au@Au core-shell SERS tags (GCTs) were prepared via the functionalization of hyaluronic acid (HA) on GCNPs, which recognized the CD44 receptor, a tumor-associated surface biomarker. And it was shown that GCTs have a good targeting ability to tumour cells and promising prospects for multiplex biomarker detection.Cellular imaging technologies employing metallic surface-enhanced Raman scattering (SERS) tags have gained much interest toward clinical diagnostics, but they are still suffering from poor controlled distribution of hot spots and reproducibility of SERS signals. Here, we report the fabrication and characterization of high narrow nanogap-containing Au@Au core-shell SERS nanoparticles (GCNPs) for the identification and imaging of proteins overexpressed on

  19. Controllable synthesis and characterization of Fe{sub 3}O{sub 4}/Au composite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Yan; Jin, Yan-Yan; Si, Jian-Chao [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); Peng, Ming-Li, E-mail: mlpeng@nwu.edu.cn [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); Wang, Xiao-Fang [Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi' an 710069 (China); Chen, Chao [National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); College of Life Sciences, Northwest University, Xi' an 710069 (China); Cui, Ya-Li, E-mail: yalicui@nwu.edu.cn [National Engineering Research Center for Miniaturized Detection Systems, Xi' an 710069 (China); College of Life Sciences, Northwest University, Xi' an 710069 (China)

    2015-04-15

    Fe{sub 3}O{sub 4}/Au composite nanoparticles (GoldMag NPs) have received considerable attention because of their advantageous properties arisen from both individual Au and Fe{sub 3}O{sub 4} nanoparticles. Many efforts have been devoted to the synthesis of these composite nanoparticles. Herein, GoldMag NPs were reported to be synthesized by two-step method. Fe{sub 3}O{sub 4} nanoparticles were prepared by co-precipitation and modified by the citric acid, and then citric acid-coated Fe{sub 3}O{sub 4} nanoparticles were used as seeds in sodium citrate solution to reduce the HAuCl{sub 4}. The size of obtained nanoparticles was geared from 25 to 300 nm by controlling the concentration of reactants. The GoldMag NPs were characterized by UV–vis spectrometer, dynamic light scattering (DLS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The GoldMag NPs showed good superparamagnetism at room temperature and were well dispersed in water with surface plasmon resonance absorption peak varied from 538 nm to 570 nm. - Highlights: • A low cost, simple manipulation and nontoxic approach was designed for preparation of magnetic Fe{sub 3}O{sub 4}/Au (GoldMag NPs) nanocomposites. • The size of GoldMag NPs could be controlled from 25 to 300 nm by varying the concentration of reactants. • GoldMag NPs possessed good magnetic response, high dispersion, and good stability.

  20. DNA motion induced by electrokinetic flow near an Au coated nanopore surface as voltage controlled gate

    International Nuclear Information System (INIS)

    We used fluorescence microscopy to investigate the diffusion and drift motion of λ DNA molecules on an Au-coated membrane surface near nanopores, prior to their translocation through solid-state nanopores. With the capability of controlling electric potential at the Au surface as a gate voltage, Vgate, the motions of DNA molecules, which are presumably generated by electrokinetic flow, vary dramatically near the nanopores in our observations. We carefully investigate these DNA motions with different values of Vgate in order to alter the densities and polarities of the counterions, which are expected to change the flow speed or direction, respectively. Depending on Vgate, our observations have revealed the critical distance from a nanopore for DNA molecules to be attracted or repelled—DNA’s anisotropic and unsteady drifting motions and accumulations of DNA molecules near the nanopore entrance. Further finite element method (FEM) numerical simulations indicate that the electrokinetic flow could qualitatively explain these unusual DNA motions near metal-collated gated nanopores. Finally, we demonstrate the possibility of controlling the speed and direction of DNA motion near or through a nanopore, as in the case of recapturing a single DNA molecule multiple times with alternating current voltages on the Vgate. (paper)

  1. Binary Assembly of Au Nanoparticles with Controllable Two-dimensional Architecture Directed by Phosphate Backbone Modified Oligonucleotide

    Institute of Scientific and Technical Information of China (English)

    MA,Yu-Dan; GUO,Yi; LI,Jun; YANG,Wen-Sheng

    2008-01-01

    A three complementary strand oligonucleotide system was employed to assemble two different-sized,15 and 25 nm,Au nanoparticles into binary two-dimensional (2D) structures.First,two non-complementary strands of phosphate backbone modified oligonucleotides (PM oligo-DNA) were loaded on the surface of the 15 and 25 nm Au nanoparticles,respectively.Upon the addition of the third linker DNA,which was half complementary to each of the modified DNA,the An nanoparticles would be assembled to binary 2D aggregates.The number of the 15 nm Au nanoparticles around a 25 nm Au naoparticle can be readily controlled by the length of the DNA helix used.

  2. Controlling crystal phases in GaAs nanowires grown by Au-assisted molecular beam epitaxy

    International Nuclear Information System (INIS)

    Control of the crystal phases of GaAs nanowires (NWs) is essential to eliminate the formation of stacking faults which deteriorate the optical and electronic properties of the NWs. In addition, the ability to control the crystal phase of NWs provides an opportunity to engineer the band gap without changing the crystal material. We show that the crystal phase of GaAs NWs grown on GaAs(111)B substrates by molecular beam epitaxy using the Au-assisted vapor–liquid–solid growth mechanism can be tuned between wurtzite (WZ) and zinc blende (ZB) by changing the V/III flux ratio. As an example we demonstrate the realization of WZ GaAs NWs with a ZB GaAs insert that has been grown without changing the substrate temperature. (paper)

  3. Control and optimal control theories with applications

    CERN Document Server

    Burghes, D N

    2004-01-01

    This sound introduction to classical and modern control theory concentrates on fundamental concepts. Employing the minimum of mathematical elaboration, it investigates the many applications of control theory to varied and important present-day problems, e.g. economic growth, resource depletion, disease epidemics, exploited population, and rocket trajectories. An original feature is the amount of space devoted to the important and fascinating subject of optimal control. The work is divided into two parts. Part one deals with the control of linear time-continuous systems, using both transfer fun

  4. Electrocatalytic applications of a vertical Au nanorod array using ultrathin Pt/Ru/Pt layer-by-layer coatings

    International Nuclear Information System (INIS)

    This study compared the electro-oxidation of carbon monoxide adlayers formed on a codeposited and a layer-by-layer deposited Pt/Ru thin overlayer on a Au surface. Vertical arrays of smooth and nanoporous Au nanorods were used as a platform for the Pt/Ru overlayer-coating. The vertical arrays of Au nanorods served as high surface area templates, where the surface area could be controlled as a function of the rod length in a given geometrical surface area. A coating of the Au nanorod arrays with Pt/Ru via Cu underpotential deposition (UPD) steps allowed control of the overlayer thickness with an ultrathin film nature. The electronic modification of the Pt overlayer with a Ru underlayer became increasingly weaker with increasing Pt overlayer thickness. The thick Pt overlayer exhibited CO electro-oxidation that was similar to the electro-oxidation profile on the Pt bulk surface. Coating of the Au nanorod arrays with Pt/Ru through Cu UPD steps demonstrated an optimal electronic response between the Pt outer overlayer and the underlying Ru layer. It is expected that an ultrathin overlayer-coating strategy can be expanded to nanoporous Au nanorod arrays. These finding will facilitate better design of highly active Pt/Ru composite nanostructures for electrocatalysis

  5. Nanocomposite of Au Nanoparticles/Helical Carbon Nanofibers and Application in Hydrogen Peroxide Biosensor.

    Science.gov (United States)

    Zhai, Mumu; Cui, Rongjing; Gu, Ning; Zhang, Genhua; Lin, Wang; Yu, Lingjun

    2015-06-01

    A combined sol-gel/hydrogen reduction method has been developed for the mass production of helical carbon nanofibers (HCNFs) by the pyrolysis of acetylene at 425 degrees C in the presence of NiO nanoparticles. The synthesized HCNFs were characterized with scanning electron microscopy (SEM), X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The helical-structured carbon nanofibers have a large specific surface area and excellent biocompatibility. A novel enzymatic hydrogen peroxide sensor was then successfully fabricated based on the nanocomposites containing HCNFs and gold nanoparticles (AuNPs). The results indicated that the Au/HCNFs nanocomposites exhibited excellent electrocatalytic activity to the reduction of H2O2, offering a wide linear range from 1.0 μM to 3157 μM with a detection limit as low as 0.46 μM. The apparent Michaelis-Menten constant of the biosensor was 0.61 mM. The as-fabricated biosensor showed a rapid and sensitive amperometric response to hydrogen peroxide with acceptable preparation reproducibility and excellent stability. Because of their low cost and high stability, these novel HCNFs represent seem to be a kind of promising biomaterial and may find wide new applications in scopes such as biocatalysis, immunoassay, environmental monitoring and so on. PMID:26369097

  6. Monitoring Control Applications at CERN

    CERN Document Server

    Bernard, F; Milcent, H; Petrova, L B; Varela, F

    2011-01-01

    The Industrial Controls and Engineering (EN-ICE) group [1] of the Engineering Department at CERN has produced, and is responsible for the operation of around 60 applications, which control critical processes in the domains of cryogenics, quench protection systems, power interlocks for the Large Hadron Collider and other subsystems of the accelerator complex. These applications require 24/7 operation and a quick reaction to problems. For this reason the EN-ICE group is presently developing the Monitoring Operation of cOntrols Networks (MOON) tool to detect, anticipate and inform of possible anomalies in the integrity of the applications. The tool builds on top of Simatic WinCC Open Architecture (WinCC OA) [2] SCADA and makes usage of the Joint COntrols Project (JCOP) [3] and the UNified INdustrial COntrol System (UNICOS) [4] Frameworks developed at CERN. The tool provides centralized monitoring and software management of the different elements integrating the control systems like Windows and L...

  7. Electrical conductivity dependence of thin metallic films of Au and Pd as a top electrode in capacitor applications

    International Nuclear Information System (INIS)

    Electrical conductivity dependence of thin metallic films of Au and Pd over the different perovskites was investigated. It is found from electrical properties that crystallographic growth orientation of Au and Pd thin layers attained from X-ray diffraction results indicate the slop of current (I)-voltage (V) plots. Besides, surface morphology and topography was considered using Field Emission Scanning Electron Microscopy and Atomic Force Microscopy, respectively. Obtained results showed the Stranski-Krastanov growth of the Pd and Au. Indeed, diminishing of the root-mean-square roughness of Pd/BiMnO3/SrTiO3 following by Au deposition should be concerned due to growth of Au onto the crack-like parts of the substrate. These crack-like parts appeared due to parasitic phases of the Bi-Mn-O system mainly Mn3O4 (l 0 l) and Mn3O4 (0 0 4 l). The different response in the electrical properties of heterostructures suggests that electrical conductance of the Au and Pd thin metallic films have the crystallographic orientation dependence. Furthermore, polycrystallinity of the thin metallic films are desired in electrode applications due to increase the conductivity of the metallic layers.

  8. Controlling core/shell Au/FePt nanoparticle electrocatalysis via changing the core size and shell thickness

    Science.gov (United States)

    Sun, Xiaolian; Li, Dongguo; Guo, Shaojun; Zhu, Wenlei; Sun, Shouheng

    2016-01-01

    Using a modified seed-mediated method, we synthesized core/shell Au/FePt nanoparticles (NPs) with Au sizes of 4, 7, and 9 nm and the FePt shell was controlled to have similar FePt compositions and 0.5, 1, and 2 nm thickness. We studied both core and shell effects on electrochemical and electrocatalytic properties of the Au/FePt NPs, and found that the Au core did change the redox chemistry of the FePt shell and promoted its electrochemical oxidation of methanol. The catalytic activity was dependent on the FePt thicknesses, but not much on the Au core sizes, and the 1 nm FePt shell was found to be the optimal thickness for catalyzing methanol oxidation in 0.1 M HClO4 + 0.1 M methanol, offering not only high activity (1.19 mA cm-2 at 0.5 V vs. Ag/AgCl), but also enhanced stability. Our studies demonstrate a general approach to the design and tuning of shell catalysis in the core/shell structure to achieve optimal catalysis for important electrochemical reactions.Using a modified seed-mediated method, we synthesized core/shell Au/FePt nanoparticles (NPs) with Au sizes of 4, 7, and 9 nm and the FePt shell was controlled to have similar FePt compositions and 0.5, 1, and 2 nm thickness. We studied both core and shell effects on electrochemical and electrocatalytic properties of the Au/FePt NPs, and found that the Au core did change the redox chemistry of the FePt shell and promoted its electrochemical oxidation of methanol. The catalytic activity was dependent on the FePt thicknesses, but not much on the Au core sizes, and the 1 nm FePt shell was found to be the optimal thickness for catalyzing methanol oxidation in 0.1 M HClO4 + 0.1 M methanol, offering not only high activity (1.19 mA cm-2 at 0.5 V vs. Ag/AgCl), but also enhanced stability. Our studies demonstrate a general approach to the design and tuning of shell catalysis in the core/shell structure to achieve optimal catalysis for important electrochemical reactions. Electronic supplementary information (ESI

  9. Au-SN Flip-Chip Solder Bump for Microelectronic and Optoelectronic Applications

    CERN Document Server

    Yoon, Jeong-Won; Koo, Ja-Myeong; Jung, Seung-Boo

    2007-01-01

    As an alternative to the time-consuming solder pre-forms and pastes currently used, a co-electroplating method of eutectic Au-Sn alloy was used in this study. Using a co-electroplating process, it was possible to plate the Au-Sn solder directly onto a wafer at or near the eutectic composition from a single solution. Two distinct phases, Au5Sn and AuSn, were deposited at a composition of 30at.%Sn. The Au-Sn flip-chip joints were formed at 300 and 400 degrees without using any flux. In the case where the samples were reflowed at 300 degrees, only an (Au,Ni)3Sn2 IMC layer formed at the interface between the Au-Sn solder and Ni UBM. On the other hand, two IMC layers, (Au,Ni)3Sn2 and (Au,Ni)3Sn, were found at the interfaces of the samples reflowed at 400 degrees. As the reflow time increased, the thickness of the (Au,Ni)3Sn2 and (Au,Ni)3Sn IMC layers formed at the interface increased and the eutectic lamellae in the bulk solder coarsened.

  10. Nanometre Ni and core/shell Ni/Au nanoparticles with controllable dimensions synthesized in reverse microemulsion

    Energy Technology Data Exchange (ETDEWEB)

    Chen Dong [Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Liu Shuo [Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering, Tianjin University, Tianjin 300072 (China); Li Jiajun [Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Zhao Naiqin [Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China)], E-mail: nqzhao@tju.edu.cn; Shi Chunsheng; Du Xiwen; Sheng Jing [Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China)

    2009-05-05

    Ni nanoparticles with different diameters were chemically synthesized in reverse microemulsion. Furthermore, core/shell Ni/Au nanoparticles with different core diameters and shell thickness were chemically synthesized from the above Ni nanoparticles through an in situ redox-transmetalation method in reverse microemulsion. The X-ray diffraction patterns revealed the presence of crystalline nickel and gold of the core/shell Ni/Au nanoparticles. The spherical Ni nanoparticles and the core/shell structured Ni/Au nanoparticles could be clearly observed by the transmission electron microscope. The diameter of the Ni nanoparticles with narrow size distribution could be controlled to range from about 8 to 30 nm. The diameter of the core/shell Ni/Au nanoparticles could be controlled to range from about 14 to 30 nm, with about 7-21 nm core diameter and about 3-7 nm shell thickness. The ZFC (zero-field-cooled) and FC (field-cooled) curves of the core/shell Ni/Au nanoparticles indicated that the blocking temperature increased from 16 to 53 K as the diameter of the Ni cores increased from about 7 to 15 nm.

  11. Controlling dynamic SERS hot spots on a monolayer film of Fe3O4@Au nanoparticles by a magnetic field

    Science.gov (United States)

    Guo, Qing-Hua; Zhang, Chen-Jie; Wei, Chao; Xu, Min-Min; Yuan, Ya-Xian; Gu, Ren-Ao; Yao, Jian-Lin

    2016-01-01

    A large surface-enhanced Raman scattering (SERS) effect is critically dependent on the gap distance of adjacent nanostructures, i.e., "hot spots". However, the fabrication of dynamically controllable hot spots still remains a remarkable challenge. In the present study, we employed an external magnetic field to dynamically control the interparticle spacing of a two-dimensional monolayer film of Fe3O4@Au nanoparticles at a hexane/water interface. SERS measurements were performed to monitor the expansion and shrinkage of the nanoparticles gaps, which produced an obvious effect on SERS activities. The balance between the electrostatic repulsive force, surface tension, and magnetic attractive force allowed observation of the magnetic-field-responsive SERS effect. Upon introduction of an external magnetic field, a very weak SERS signal appeared initially, indicating weak enhancement due to a monolayer film with large interparticle spacing. The SERS intensity reached maximum after 5 s and thereafter remained almost unchanged. The results indicated that the observed variations in SERS intensities were fully reversible after removal of the external magnetic field. The reduction of interparticle spacing in response to a magnetic field resulted in about one order of magnitude of SERS enhancement. The combined use of the monolayer film and external magnetic field could be developed as a strategy to construct hot spots both for practical application of SERS and theoretical simulation of enhancement mechanisms.

  12. Shape-controlled synthesis of Au@Pd core-shell nanoparticles and their corresponding electrochemical properties

    KAUST Repository

    Song, HyonMin

    2012-01-01

    The shape-controlled synthesis of Au@Pd core-shell nanoparticles (NPs) was successfully achieved through the emulsion phase generated during the phase transfer from organic to aqueous medium. Contrary to conventional epitaxial growth for obtaining core-shell structures, this method does not require high temperatures and does not have shape restrictions. © 2012 The Royal Society of Chemistry.

  13. Finding Security Bugs in Web Applications using a Catalog of Access Control Patterns

    OpenAIRE

    Near, Joseph Paul; Jackson, Daniel

    2016-01-01

    We propose a specification-free technique for finding missing security checks in web applications using a catalog of access control patterns in which each pattern models a common access control use case. Our implementation, Space, checks that every data exposure allowed by an application's code matches an allowed exposure from a security pattern in our catalog. The only user-provided input is a mapping from application types to the types of the catalog; the rest of the process is entirely au...

  14. Nanoscaled redox active protein adsorption on Au-dot arrays: An electrochemical scanning probe microscopic investigation for application in nano-biodevices

    Energy Technology Data Exchange (ETDEWEB)

    Yagati, Ajay Kumar; Jung, Mi; Kim, Sang-Uk [Interdisciplinary Program of Integrated Biotechnology, Sogang University, 1 Shinsu-dong, Mapo-gu, Seoul 121-742 (Korea, Republic of); Min, Junhong [College of Bionanotechnology, Kyungwon University, Bokjung-dong, Sujung-gu, Seongnam 461-701 (Korea, Republic of); Choi, Jeong-Woo, E-mail: jwchoi@sogang.ac.k [Interdisciplinary Program of Integrated Biotechnology, Sogang University, 1 Shinsu-dong, Mapo-gu, Seoul 121-742 (Korea, Republic of); Department of Chemical and Biomolecular Engineering, Interdisciplinary Program of Integrated Biotechnology Sogang University, 1 Shinsu-dong, Mapo-gu, Seoul 121-742 (Korea, Republic of)

    2009-11-30

    Highly dense and uniform protein dot arrays on Au-nanodots using size controllable method were fabricated on indium tin oxide (ITO) substrate in order to develop an electrochemical nanobiochip. Cysteine modified azurin was directly immobilized on the fabricated Au-nanodots without any linker materials. Atomic force microscopy was used for characterizing Au-dots formed on ITO substrate. Electrochemical scanning tunneling microscopy (ECSTM) revealed the monolayer formation with an in situ cyclic voltammetry to observe redox behaviour of both bare Au-dots and protein immobilized Au-dots. I-V characteristics were obtained on both bare Au-dots and protein immobilized Au-dots structured on ITO conductive electrodes.

  15. Contribution to the evaluation of safety of software used in command control systems in nuclear plants: application to the SPIN N4; Contribution a l`evaluation de surete des logiciels de controle-commande des centrales nucleaires: application au SPIN N4

    Energy Technology Data Exchange (ETDEWEB)

    Soubies, B.; Boulc`h, J.; Elsensohn, O.; Le Meur, M.; Henry, J.Y.

    1994-06-01

    The licensing procedures process of nuclear plants features compulsory steps which bring about a thorough exam of the commands control system. This analysis accounts for the aspects linked to technologies (integrated circuits, software packages) which have been chosen by the manufacturer for the programmed systems in charge of safety functions. Important innovations have been introduced in terms of design and manufacturing processes of safety systems of 1400 MWe pressurized water reactors, more precisely for the integrated numerical protection system (SPIN). The methodology used by the IPSN for the exam of the software of this system is presented in the communication. This methodology leads the IPSN to carry out studies and developments of tools keeping in sight as their main goal to bring substantial help to analysis. (authors). 2 refs.

  16. Self-assembly of thiolated cyanine aggregates on Au(111) and Au nanoparticle surfaces

    Science.gov (United States)

    Menéndez, Guillermo O.; Cortés, Emiliano; Grumelli, Doris; Méndez de Leo, Lucila P.; Williams, Federico J.; Tognalli, Nicolás G.; Fainstein, Alejandro; Vela, María Elena; Jares-Erijman, Elizabeth A.; Salvarezza, Roberto C.

    2012-01-01

    Heptamethinecyanine J-aggregates display sharp, intense fluorescence emission making them attractive candidates for developing a variety of chem-bio-sensing applications. They have been immobilized on planar thiol-covered Au surfaces and thiol-capped Au nanoparticles by weak molecular interactions. In this work the self-assembly of novel thiolated cyanine (CNN) on Au(111) and citrate-capped AuNPs from solutions containing monomers and J-aggregates has been studied by using STM, XPS, PM-IRRAS, electrochemical techniques and Raman spectroscopy. Data show that CNN species adsorb on the Au surfaces by forming thiolate-Au bonds. We found that the J-aggregates are preferentially adsorbed on the Au(111) surface directly from the solution while adsorbed CNN monomers cannot organize into aggregates on the substrate surface. These results indicate that the CNN-Au interaction is not able to disorganize the large J-aggregates stabilized by π-π stacking to optimize the S-Au binding site but it is strong enough to hinder the π-π stacking when CNNs are chemisorbed as monomers. The optical properties of the J-aggregates remain active after adsorption. The possibility of covalently bonding CNN J-aggregates to Au planar surfaces and Au nanoparticles controlling the J-aggregate/Au distance opens a new path regarding their improved stability and the wide range of biological applications of both CNN and AuNP biocompatible systems.Heptamethinecyanine J-aggregates display sharp, intense fluorescence emission making them attractive candidates for developing a variety of chem-bio-sensing applications. They have been immobilized on planar thiol-covered Au surfaces and thiol-capped Au nanoparticles by weak molecular interactions. In this work the self-assembly of novel thiolated cyanine (CNN) on Au(111) and citrate-capped AuNPs from solutions containing monomers and J-aggregates has been studied by using STM, XPS, PM-IRRAS, electrochemical techniques and Raman spectroscopy. Data show

  17. Synthesis of biocompatible AuAgS/Ag2S nanoclusters and their applications in photocatalysis and mercury detection

    International Nuclear Information System (INIS)

    In this paper, a facile approach for preparation of AuAgS/Ag2S nanoclusters was developed. The unique AuAgS/Ag2S nanoclusters capped with biomolecules exhibit interesting excellent optical and catalytic properties. The fluorescent AuAgS/Ag2S nanoclusters show tunable luminescence depending on the nanocluster size. The apoptosis assay demonstrated that the AuAgS/Ag2S nanoclusters showed low cytotoxicity and good biocompatibility. Therefore, the nanoclusters can be used not only as a probe for labeling cells but also for their photocatalytic activity for photodegradation of organic dye. Moreover, a highly selective and sensitive assay for detection of mercury including Hg2+ and undissociated mercury complexes was developed based on the quenching fluorescent AuAgS/Ag2S nanoclusters, which provides a promising approach for determining various forms of Hg in the mercury-based compounds in environment. These unique nanoclusters may have potential applications in biological labeling, sensing mercury, and photodegradation of various organic pollutants in waste water.Graphical Abstract

  18. Synthesis of biocompatible AuAgS/Ag{sub 2}S nanoclusters and their applications in photocatalysis and mercury detection

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Qian; Chen, Shenna; Zhang, Lingyang; Huang, Haowen, E-mail: hhwn09@163.com; Liu, Fengping [Hunan University of Science and Technology, Key Laboratory of Theoretical Organic Chemistry and Function Molecule, Ministry of Education, Hunan Provincial University Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering (China); Liu, Xuanyong, E-mail: xyliu@mail.sic.ac.cn [Chinese Academy of Sciences, State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics (China)

    2014-12-15

    In this paper, a facile approach for preparation of AuAgS/Ag{sub 2}S nanoclusters was developed. The unique AuAgS/Ag{sub 2}S nanoclusters capped with biomolecules exhibit interesting excellent optical and catalytic properties. The fluorescent AuAgS/Ag{sub 2}S nanoclusters show tunable luminescence depending on the nanocluster size. The apoptosis assay demonstrated that the AuAgS/Ag{sub 2}S nanoclusters showed low cytotoxicity and good biocompatibility. Therefore, the nanoclusters can be used not only as a probe for labeling cells but also for their photocatalytic activity for photodegradation of organic dye. Moreover, a highly selective and sensitive assay for detection of mercury including Hg{sup 2+} and undissociated mercury complexes was developed based on the quenching fluorescent AuAgS/Ag{sub 2}S nanoclusters, which provides a promising approach for determining various forms of Hg in the mercury-based compounds in environment. These unique nanoclusters may have potential applications in biological labeling, sensing mercury, and photodegradation of various organic pollutants in waste water.Graphical Abstract.

  19. Biomedical applications of control engineering

    CERN Document Server

    Hacısalihzade, Selim S

    2013-01-01

    Biomedical Applications of Control Engineering is a lucidly written textbook for graduate control engin­eering and biomedical engineering students as well as for medical prac­ti­tioners who want to get acquainted with quantitative methods. It is based on decades of experience both in control engineering and clinical practice.   The book begins by reviewing basic concepts of system theory and the modeling process. It then goes on to discuss control engineering application areas like ·         Different models for the human operator, ·         Dosage and timing optimization in oral drug administration, ·         Measuring symptoms of and optimal dopaminergic therapy in Parkinson’s disease, ·         Measure­ment and control of blood glucose le­vels both naturally and by means of external controllers in diabetes, and ·         Control of depth of anaesthesia using inhalational anaesthetic agents like sevoflurane using both fuzzy and state feedback controllers....

  20. Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2

    Science.gov (United States)

    Saavedra, Johnny; Whittaker, Todd; Chen, Zhifeng; Pursell, Christopher J.; Rioux, Robert M.; Chandler, Bert D.

    2016-06-01

    Industrial hydrogen production through methane steam reforming exceeds 50 million tons annually and accounts for 2–5% of global energy consumption. The hydrogen product, even after processing by the water–gas shift, still typically contains ∼1% CO, which must be removed for many applications. Methanation (CO + 3H2 → CH4 + H2O) is an effective solution to this problem, but consumes 5–15% of the generated hydrogen. The preferential oxidation (PROX) of CO with O2 in hydrogen represents a more-efficient solution. Supported gold nanoparticles, with their high CO-oxidation activity and notoriously low hydrogenation activity, have long been examined as PROX catalysts, but have shown disappointingly low activity and selectivity. Here we show that, under the proper conditions, a commercial Au/Al2O3 catalyst can remove CO to below 10 ppm and still maintain an O2-to-CO2 selectivity of 80–90%. The key to maximizing the catalyst activity and selectivity is to carefully control the feed-flow rate and maintain one to two monolayers of water (a key CO-oxidation co-catalyst) on the catalyst surface.

  1. Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2.

    Science.gov (United States)

    Saavedra, Johnny; Whittaker, Todd; Chen, Zhifeng; Pursell, Christopher J; Rioux, Robert M; Chandler, Bert D

    2016-06-01

    Industrial hydrogen production through methane steam reforming exceeds 50 million tons annually and accounts for 2-5% of global energy consumption. The hydrogen product, even after processing by the water-gas shift, still typically contains ∼1% CO, which must be removed for many applications. Methanation (CO + 3H2 → CH4 + H2O) is an effective solution to this problem, but consumes 5-15% of the generated hydrogen. The preferential oxidation (PROX) of CO with O2 in hydrogen represents a more-efficient solution. Supported gold nanoparticles, with their high CO-oxidation activity and notoriously low hydrogenation activity, have long been examined as PROX catalysts, but have shown disappointingly low activity and selectivity. Here we show that, under the proper conditions, a commercial Au/Al2O3 catalyst can remove CO to below 10 ppm and still maintain an O2-to-CO2 selectivity of 80-90%. The key to maximizing the catalyst activity and selectivity is to carefully control the feed-flow rate and maintain one to two monolayers of water (a key CO-oxidation co-catalyst) on the catalyst surface. PMID:27219703

  2. MONITORING CONTROL APPLICATIONS AT CERN

    CERN Document Server

    Bernard, F; Milcent, H; Petrova, L B; Varlea, F

    2011-01-01

    The Industrial Controls and Engineering (EN-ICE) group [1] of the Engineering Department at CERN has produced, and is responsible for the operation of around 60 applications, which control critical processes in the domains of cryogenics, quench protection systems, power interlocks for the Large Hadron Collider and other sub-systems of the accelerator complex. These applications require 24/7 operation and a quick reaction to problems. For this reason the EN-ICE group is presently developing the Monitoring Operation of cOntrols Networks (MOON) tool to detect, anticipate and inform of possible anomalies in the integrity of the applications. The tool builds on top of Simatic WinCC Open Architecture (WinCC OA) [2] SCADA and makes usage of the Joint COntrols Project (JCOP) [3] and the UNified INdustrial COntrol System (UNICOS) [4] Frameworks developed at CERN. The tool provides centralized monitoring and software management of the different elements integrating the control systems like Windows and Linux servers, PL...

  3. Systematic Control of Self-Assembled Au Nanoparticles and Nanostructures Through the Variation of Deposition Amount, Annealing Duration, and Temperature on Si (111)

    Science.gov (United States)

    Li, Ming-Yu; Sui, Mao; Pandey, Puran; Zhang, Quanzhen; Kim, Eun-Soo; Lee, Jihoon

    2015-09-01

    The size, density, and configurations of Au nanoparticles (NPs) can play important roles in controlling the electron mobility, light absorption, and localized surface plasmon resonance, and further in the Au NP-assisted nanostructure fabrications. In this study, we present a systematical investigation on the evolution of Au NPs and nanostructures on Si (111) by controlling the deposition amount (DA), annealing temperature (AT), and dwelling time (DT). Under an identical growth condition, the morphologies of Au NPs and nanostructures drastically evolve when the DA is only slightly varied, based on the Volmer-Weber and coalescence models: i.e. I: mini NPs, II: mid-sized round dome-shaped Au NPs, III: large Au NPs, and IV: coalesced nanostructures. With the AT control, three distinctive ranges are observed: i.e., NP nucleation, Au NPs maturation and melting. The gradual dimensional expansion of Au NPs is always compensated with the density reduction, which is explained with the thermodynamic theory. The DT effect is relatively minor on Au NPs, a sharp contrast to other metallic NPs, which is discussed based on the Ostwald-ripening.

  4. Electrical performance of Ti-ZnO-Au thin film composite structure for device application

    Science.gov (United States)

    Joshi, Priyanka; Singh, Jitendra; Das, Surajit; Desai, J. V.; Akhtar, Jamil

    2016-04-01

    Thin film layers of Au/Ti approximately 2200 Å thick and ZnO approximately 2.24 µm thick were sputtered sequentially onto silicon dioxide coated Si-wafer. Conventional wisdom confirms the adhesion of gold over zinc oxide (ZnO) by an intermediate layer of titanium for better adhesion. But, in Au/Ti/ZnO/Au/Ti structure, it was observed that with the passing of time the gold diffused into ZnO thin film at room temperature, making a very low resistance between the two gold layers eventually making a conductive path in ZnO. Therefore, electrical connectivity was found between the metal layers. A detailed experimental analysis has been carried out in support of the observed Au diffusion. In the present work, reliability of Ti/Au metallisation and anomalous electrical behavior due to gold diffusion has been studied.

  5. Engine Modelling for Control Applications

    DEFF Research Database (Denmark)

    Hendricks, Elbert

    1997-01-01

    In earlier work published by the author and co-authors, a dynamic engine model called a Mean Value Engine Model (MVEM) was developed. This model is physically based and is intended mainly for control applications. In its newer form, it is easy to fit to many different engines and requires little ...

  6. Crystallographic investigation of Au nanoparticles embedded in a SrTiO3 thin film for plasmonics applications by means of synchrotron radiation

    International Nuclear Information System (INIS)

    Self-organized monocrystalline Au nanoparticles with potential applications in plasmonics are grown in a SrTiO3 matrix by a novel two-step deposition process. The crystalline preferred orientation of these Au nanoparticles is investigated by synchrotron hard x-ray diffraction. Nanoparticles preferentially align with the (111) direction along the substrate normal (001), whereas two in-plane orientations are found with [110]SrTiO3∥[110]Au and [100]SrTiO3∥[110]Au. Additionally, a smaller diffraction signal from nanoparticles with the (001) direction parallel to the substrate normal (001) is observed; once again, two in-plane orientations are found, with [100]SrTiO3∥[100]Au and [100]SrTiO3∥[110]Au. The populations of the two in-plane orientations are found to depend on the thickness of the gold film deposited in the first step of the growth

  7. Fabrication of Te and Te-Au Nanowires-Based Carbon Fiber Fabrics for Antibacterial Applications

    Directory of Open Access Journals (Sweden)

    Ting-Mao Chou

    2016-02-01

    Full Text Available Pathogenic bacteria that give rise to diseases every year remain a major health concern. In recent years, tellurium-based nanomaterials have been approved as new and efficient antibacterial agents. In this paper, we developed the approach to directly grow tellurium nanowires (Te NWs onto commercial carbon fiber fabrics and demonstrated their antibacterial activity. Those Te NWs can serve as templates and reducing agents for gold nanoparticles (Au NPs to deposit. Three different Te-Au NWs with varied concentration of Au NPs were synthesized and showed superior antibacterial activity and biocompability. These results indicate that the as-prepared carbon fiber fabrics with Te and Te-Au NWs can become antimicrobial clothing products in the near future.

  8. Cu2O and Au/Cu2O Particles: Surface Properties and Applications in Glucose Sensing

    OpenAIRE

    Yu-Ho Won; Stanciu, Lia A.

    2012-01-01

    In this work we investigated the surface and facet-dependent catalytic properties of metal oxide particles as well as noble metal/metal oxide heterogeneous structures, with cuprous oxide (Cu2O) and Au/Cu2O being selected as model systems. As an example of application, we explored the potential of these materials in developing electrocatalytic devices. Cu2O particles were synthesized in various shapes, then used for testing their morphology-dependent electrochemical properties applied to the d...

  9. Lead Telluride Doped with Au as a Very Promising Material for Thermoelectric Applications

    Directory of Open Access Journals (Sweden)

    Pantelija M. Nikolic

    2015-01-01

    Full Text Available PbTe single crystals doped with monovalent Au or Cu were grown using the Bridgman method. Far infrared reflectivity spectra were measured at room temperature for all samples and plasma minima were registered. These experimental spectra were numerically analyzed and optical parameters were calculated. All the samples of PbTe doped with Au or Cu were of the “n” type. The properties of these compositions were analyzed and compared with PbTe containing other dopants. The samples of PbTe doped with only 3.3 at% Au were the best among the PbTe + Au samples having the lowest plasma frequency and the highest mobility of free carriers-electrons, while PbTe doped with Cu was the opposite. Samples with the lowest Cu concentration of 0.23 at% Cu had the best properties. Thermal diffusivity and electronic transport properties of the same PbTe doped samples were also investigated using a photoacoustic (PA method with the transmission detection configuration. The results obtained with the far infrared and photoacoustic characterization of PbTe doped samples were compared and discussed. Both methods confirmed that when PbTe was doped with 3.3 at% Au, thermoelectric and electrical properties of this doped semiconductor were both significantly improved, so Au as a dopant in PbTe could be used as a new high quality thermoelectric material.

  10. Facet-controlled phase separation in supersaturated Au-Ni nanoparticles upon shape equilibration

    International Nuclear Information System (INIS)

    Solid-state dewetting is used to fabricate supersaturated, submicron-sized Au-Ni solid solution particles out of thin Au/Ni bilayers by means of a rapid thermal annealing technique. Phase separation in such particles is studied with respect to their equilibrium crystal (or Wulff) shape by subsequent annealing at elevated temperature. It is found that (100) faceting planes of the equilibrated particles are enriched with Ni and (111) faces with Au. Both phases are considered by quantum-mechanical calculations in combination with an error-reduction scheme that was developed to compensate for a missing exchange-correlation potential that would reliably describe both Au and Ni. The observed phase configuration is then related to the minimization of strongly anisotropic elastic energies of Au- and Ni-rich phases and results in a rather unique nanoparticle composite state that is characterized by nearly uniform value of elastic response to epitaxial strains all over the faceted surface. The same conclusion is yielded also by evaluating bi-axial elastic moduli when employing interpolated experimental elastic constants. This work demonstrates a useful route for studying features of physical metallurgy at the mesoscale

  11. Stabilization of AuNPs by monofunctional triazole linked to ferrocene, ferricenium, or coumarin and applications to synthesis, sensing, and catalysis.

    Science.gov (United States)

    Li, Na; Zhao, Pengxiang; Igartua, María E; Rapakousiou, Amalia; Salmon, Lionel; Moya, Sergio; Ruiz, Jaime; Astruc, Didier

    2014-11-01

    Monofunctional triazoles linked to ferrocene, ferricenium, or coumarin (Cou), easily synthesized by copper-catalyzed azide alkyne (CuAAC) "click" reactions between the corresponding functional azides and (trimethylsilyl)acetylene followed by silyl group deprotection, provide a variety of convenient neutral ligands for the stabilization of functional gold nanoparticles (AuNPs) in polar organic solvents. These triazole (trz)-AuNPs are very useful toward a variety of applications to synthesis, sensing, and catalysis. Both ferrocenyl (Fc) and isostructural ferricenium linked triazoles give rise to AuNP stabilization, although by different synthetic routes. Indeed, the first direct synthesis and stabilization of AuNPs by ferricenium are obtained by the reduction of HAuCl4 upon reaction with a ferrocene derivative, AuNP stabilization resulting from a synergy between electrostatic and coordination effects. The ferricenium/ferrocene trz-AuNP redox couple is fully reversible, as shown by cyclic voltammograms that were recorded with both redox forms. These trz-AuNPs are stable for weeks in various polar solvents, but at the same time, the advantage of trz-AuNPs is the easy substitution of neutral trz ligands by thiols and other ligands, giving rise to applications. Indeed, this ligand substitution of trz at the AuNP surface yields a stable Fc-terminated nanogold-cored dendrimer upon reaction with a Fc-terminated thiol dendron, substitution of Cou-linked trz with cysteine, homocysteine, and glutathione provides remarkably efficient biothiol sensing, and a ferricenium-linked trz-AuNP catalyst is effective for NaBH4 reduction of 4-nitrophenol to 4-aminophenol. In this catalytic example, the additional electrostatic AuNP stabilization modulates the reaction rate and induction time. PMID:25363304

  12. Composition-selective fabrication of ordered intermetallic Au-Cu nanowires and their application to nano-size electrochemical glucose detection

    Science.gov (United States)

    Kim, Si-In; Eom, Gayoung; Kang, Mijeong; Kang, Taejoon; Lee, Hyoban; Hwang, Ahreum; Yang, Haesik; Kim, Bongsoo

    2015-06-01

    Bimetallic nanostructures can provide distinct and improved physicochemical properties by the coupling effect of the two metal components, making them promising materials for a variety of applications. Herein, we report composition-selective fabrication of ordered intermetallic Au-Cu nanowires (NWs) by two-step chemical vapor transport method and their application to nano-electrocatalytic glucose detection. Ordered intermetallic Au3Cu and AuCu3 NWs are topotaxially fabricated by supplying Cu-containing chemicals to pre-synthesized single-crystalline Au NW arrays. The composition of fabricated Au-Cu NWs can be selected by changing the concentration of Cu-containing species. Interestingly, Au3Cu NW electrodes show unique electrocatalytic activity for glucose oxidation, allowing us to detect glucose without interference from ascorbic acid. Such interference-free detection of glucose is attributed to the synergistic effect, induced by incorporation of Cu in Au. We anticipate that Au3Cu NWs could show possibility as efficient nano-size electrochemical glucose sensors and the present fabrication method can be employed to fabricate valuable ordered intermetallic nanostructures.

  13. Application of {sup 198}Au grains for carcinoma of oral cavity

    Energy Technology Data Exchange (ETDEWEB)

    Shimizutani, K. [Dept. of Oral Radiology, Osaka Dental University, Osaka (Japan); Koseki, Y. [Dept. of Oral Radiology, Osaka Dental University, Osaka (Japan); Inoue, To. [Dept. of Radiation Oncology, Biomedical Research Center, Osaka University Medical School, Osaka (Japan); Teshima, T. [Dept. of Radiology, Osaka University Medical School, Osaka (Japan); Furukawa, S. [Dept. of Oral and Maxillofacial Radiology, Osaka University, Faculty of Dentistry, Osaka (Japan); Kubo, K. [Dept. of Oral and Maxillofacial Radiology, Osaka University, Faculty of Dentistry, Osaka (Japan); Fachihata, H. [Dept. of Oral and Maxillofacial Radiology, Osaka University, Faculty of Dentistry, Osaka (Japan); Masaki, N. [Dept. of Therapeutic Radiology, Center for Adult Diseases, Osaka (Japan); Ikeda, H. [Dept. of Radiation Oncology, National Cancer Center Hospital, Tokyo (Japan); Tanaka, Y. [Dept. of Dentistry, Kobe Municipal Chuo Hospital, Kobe (Japan)

    1995-01-01

    The purpose of this study is to analyze the results of the treatment using gold grain implants over the past 9 years and to evaluate the usefulness of this treatment method. From January 1985 through April 1993, a total of 45 patients with squamous cell carcinomas of the oral cavity and the oropharynx were treated with {sup 198}Au grain (gold grain) at the Department of Radiology, Osaka University Medical School. The initial activity of the grains supplied weekly by the Japan Radioisotope Association was usually 5 mCi (185 MBq), and single implants were usual. In case of combined external irradiation, telecobalt {gamma}-rays or 4 MV X-rays were used for treatment before implant. The local control rate for patients with T1 stages was 80% (20/25) and with T2 stages, 59% (10/17). The local control rate was 71% (10/14) for gold grain alone and 72% (13/18) for external irradiation combined with gold grain implants (combined therapy). In combined therapy, the median of the interval between external irradiation and gold grain implants was 21 days. The treatment interval or patients with recurrent diseases was 22 days, 22, 27, 39 and 46, respectively. The progression rate showed a tendency to increase in the patients with longer interval (more than 21 days), and with partial regression after external irradiation and gold grain implantation is an important factor in combined therapy. Therefore, we emphasize that the time interval should be shorter than 3 weeks. (orig.) [Deutsch] Ziel dieser Untersuchung sind die Analyse der Behandlungsergebnisse der letzten neun Jahre bei Verwendung von Gold-Seed-Implantaten und die Bestimmung der Wertigkeit dieser Methode. Von Januar 1985 bis April 1993 wurden insgesamt 45 Patienten mit Plattenepithelkarzinomen der Mundhoehle und des Oropharynx mit {sup 198}Au-Seeds im Department of Radiology der Osaka University medical School behandelt. Die Ausgangsaktivitaet der Seeds war ueblicherweise 5 mCi (185 MBq), sie wurden woechentlich von der

  14. Corrosion Protection of Al/Au/ZnO Anode for Hybrid Cell Application.

    Science.gov (United States)

    Slaughter, Gymama; Stevens, Brian

    2015-01-01

    Effective protection of power sources from corrosion is critical in the development of abiotic fuel cells, biofuel cells, hybrid cells and biobateries for implantable bioelectronics. Corrosion of these bioelectronic devices result in device inability to generate bioelectricity. In this paper Al/Au/ZnO was considered as a possible anodic substrate for the development of a hybrid cell. The protective abilities of corrosive resistant aluminum hydroxide and zinc phosphite composite films formed on the surface of Al/Au/ZnO anode in various electrolyte environments were examined by electrochemical methods. The presence of phosphate buffer and physiological saline (NaCl) buffer allows for the formation of aluminum hyrdroxide and zinc phosphite composite films on the surface of the Al/Au/ZnO anode that prevent further corrosion of the anode. The highly protective films formed on the Al/Au/ZnO anode during energy harvesting in a physiological saline environment resulted in 98.5% corrosion protective efficiency, thereby demonstrating that the formation of aluminum hydroxide and zinc phosphite composite films are effective in the prevention of anode corrosion during energy harvesting. A cell assembly consisting of the Al/Au/ZnO anode and platinum cathode resulted in an open circuit voltage of 1.03 V. A maximum power density of 955.3 mW/ cm² in physiological saline buffer at a cell voltage and current density of 345 mV and 2.89 mA/ cm², respectively. PMID:26580661

  15. Self-ordering of Au(111) vicinal surfaces and application to nanostructure organized growth

    International Nuclear Information System (INIS)

    This paper reports on Au(111) vicinal surfaces, either regularly stepped surfaces, reconstructed or not, or periodically faceted surfaces, which are well suited to be used as templates for organized growth of clusters. Angles of misorientation with respect to the (111) plane lie between 1 deg. and 12 deg. and two opposite azimuths are considered: (i) [21-bar1-bar], that leads to steps with (100) microfacets, and (ii) [2-bar11], that leads to steps with (111) microfacets. The behaviour of the Au(111) reconstruction in the vicinity of steps depends drastically on the step microstructure, and this is a key point for understanding the various periodic morphologies existing on Au(111) vicinal surfaces. The interaction between the reconstruction and the close-packed steps of the Au(111) surface is interpreted in terms of the relative stability of both types of step. Self-organized morphologies between 10 and 100 nm are interpreted within the framework of elastic theory and by pointing out the crucial role played by the atomic boundary energy term. The microscopic origin of faceting is discussed, proposing two different models depending on each azimuth. Then, we illustrate the use of Au(111) vicinal surfaces as templates for growing long range ordered nanostructures. Examples are given in the case of cobalt growth

  16. Highly stable SERS pH nanoprobes produced by co-solvent controlled AuNP aggregation.

    Science.gov (United States)

    Wei, Haoran; Willner, Marjorie R; Marr, Linsey C; Vikesland, Peter J

    2016-08-15

    Production of gold nanoparticle (AuNP) surface-enhanced Raman spectroscopy (SERS) nanoprobes requires replicable aggregation to produce multimers with high signal intensity. Herein, we illustrate a novel, yet simple, approach to produce SERS nanoprobes through control of co-solvent composition. AuNP multimers were produced by mixing AuNP monomers in water : ethanol co-solvent for variable periods of time. By varying the water : ethanol ratio and the amount of 4-mercaptobenzoic acid (4-MBA) present, the aggregation rate can be systematically controlled. Thiolated poly(ethylene glycol) was then added to halt the aggregation process and provide steric stability. This approach was used to produce pH nanoprobes with excellent colloidal stability in high ionic strength environments and in complex samples. The pH probe exhibits broad pH sensitivity over the range 6-11 and we calculate that a single AuNP dimer in a 35 fL volume is sufficient to generate a detectable SERS signal. As a proof-of-concept, the probes were used to detect the intracellular pH of human prostate cancer cells (PC-3). The internalized probes exhibit a strong 4-MBA signal without any interfering bands from either the cells or the culture media and produce exceptionally detailed pH maps. pH maps obtained from 19 xy surface scans and 14 yz depth scans exhibit highly consistent intracellular pH in the range of 5 to 7, thus indicating the greater reliability and reproducibility of our pH probes compared with other probes previously reported in the literature. Our water : ethanol co-solvent production process is fast, simple, and efficient. Adjustment of solvent composition may become a powerful way to produce SERS tags or nanoprobes in the future. PMID:27143623

  17. Production of radio-gold {sup 199}Au for diagnostic and therapeutic applications

    Energy Technology Data Exchange (ETDEWEB)

    Khandaker, Mayeen Uddin, E-mail: mu-khandaker@um.edu.my; Kassim, Hasan Abu, E-mail: hasanak@um.edu.my [Department of Physics, University of Malaya, 50603 Kuala Lumpur (Malaysia); Haba, Hiromitsu, E-mail: haba@riken.jp [Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198 (Japan)

    2016-01-22

    Production cross-sections of the {sup nat}Pt(d,x){sup 199}Au reactions have been measured from a 24-MeV deuteron energy down to the threshold by using a stacked-foil activation technique combined with HPGe γ-ray spectrometry. Only a partial agreement is obtained with the existing literature data. Theoretical data extracted from the TENDL-2013 library shows large discrepancy with the measured ones. Physical thick target yield for the {sup 199}Au radionuclide was deduced using the measured cross-sections, and found a general agreement with the directly measured yield available in the literature. This study reveals that a low deuteron energy (<15 MeV) cyclotron and an enriched {sup 198}Pt (100%) target could be used to obtain {sup 199}Au in no carrier added form.

  18. An application of Au thin-film emissivity barrier on Ni alloy

    Energy Technology Data Exchange (ETDEWEB)

    Huang Zhibin [State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechincial University, Xi' an 710072 (China)], E-mail: huangzhibin83@163.com; Zhu Dongmei; Lou Fa; Zhou Wancheng [State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechincial University, Xi' an 710072 (China)

    2008-12-30

    1000 nm-thick Au film was sputter-deposited on two groups of nickel alloy substrates, in which one group (Group A) was oxidated at 800 deg. C for 20 h to form a oxide film before coating gold while another group (Group B) was unoxidated. The gold thin-film is applied to serve as a low emissivity coating to reflect thermal radiation. The gold-coated samples were heated in air at 600 deg. C for 150 h to explore the effect of high-temperature environment on the emissivity of coated Au film. After heat-treatment, the average thermal emissivity at the wavelength of 3-14 {mu}m of Group B greatly increased from 0.18 to 0.82 while that of Group A only increased a little. The diffusion between Au and other nickel alloy elements at 600 deg. C also had been discussed in this paper.

  19. Characterization of self-assembled electrodes based on Au-Pt nanoparticles for PEMFC application

    Energy Technology Data Exchange (ETDEWEB)

    Valenzuela, E. [Politecnica Univ. de Chiapas, Tuxtla Gutierrez, Chiapas (Mexico). Energia y Sustentabilidad; Sebastian, P.J. [Politecnica Univ. de Chiapas, Chiapas (Mexico). Energia y Sustentabilidad; Centro de Investigacion en Energia, UNAM, Morelos (Mexico); Gamboa, S.A. [Centro de Investigacion en Energia, UNAM, Morelos (Mexico); Pal, U. [Inst. de Fisica, Universidad Autonoma de Puebla Univ., Puebla (Mexico). Inst. de Fisica; Gonzalez, I. [Autonoma Metropolitana Univ. (Mexico). Dept. de Quimica

    2008-07-01

    This paper reported on a study in which membrane electrode assemblies (MEAs) were fabricated by depositing Au, Pt and AuPt nanoparticles on Nafion 115 membrane for use in a proton exchange membrane fuel cell (PEMFC). A Rotating Disc Electrode (RDE) was used to measure the nanoparticle catalyst activity. After deposition of the nanoparticles on the membrane, the surface was studied by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS). The membrane proton conduction process was studied by Electrochemical Impedance Spectroscopy (EIS) with the 4 probe technique. The MEAs fabricated with Nafion/Metal membranes were evaluated in a PEMFC under standard conditions. Colloidal solutions were used to prepare self-assembled electrodes with nanoparticles deposited on Nafion membrane. The particles deposited on Nafion showed good stability and had homogeneous distribution along the membrane surface. The impedance results revealed an increase in the membrane proton resistance of the self-assembled electrodes compared to unmodified Nafion. The Au-Pt nanoparticles were obtained by chemical reduction. The nanoparticle size in the three systems was about 2 nm. The self-assembled electrodes performed well in standard conditions. The optimum colloidal concentration and immersion time must be determined in order to obtain good catalytic activity and high membrane conductance. The self-assembled Nafion/AuPt had the best open circuit potential (887 mV). The Au and Pt self-assemblies showed a similar performance in terms of maximum power and maximum current density. The performance of the Nafion/Au self-assembly was influenced more by ohmic losses, particularly in the membrane. The maximum power generation was obtained at 0.35 V. The mass transport losses increased after this value, thereby affecting the efficiency of the PEMFC. 2 figs.

  20. Neural Networks in Control Applications

    DEFF Research Database (Denmark)

    Sørensen, O.

    The intention of this report is to make a systematic examination of the possibilities of applying neural networks in those technical areas, which are familiar to a control engineer. In other words, the potential of neural networks in control applications is given higher priority than a detailed...... study of the networks themselves. With this end in view the following restrictions have been made: - Amongst numerous neural network structures, only the Multi Layer Perceptron (a feed-forward network) is applied. - Amongst numerous training algorithms, only four algorithms are examined, all in a...... recursive form (sample updating). The simplest is the Back Probagation Error Algorithm, and the most complex is the recursive Prediction Error Method using a Gauss-Newton search direction. - Over-fitting is often considered to be a serious problem when training neural networks. This problem is specifically...

  1. Collapse and control of the MnAu2 spin-spiral state through pressure and doping

    Science.gov (United States)

    Glasbrenner, J. K.

    2016-05-01

    MnAu2 is a spin-spiral material with in-plane ferromagnetic Mn layers that form a screw-type pattern around a tetragonal c axis. The spiral angle θ was shown using neutron diffraction experiments to decrease with pressure, and in later studies it was found to suffer a collapse to a ferromagnetic state above a critical pressure, although the two separate experiments did not agree on whether this phase transition is first or second order. To resolve this contradiction, we use density functional theory calculations to investigate the spiral state as a function of pressure, charge doping, and also electronic correlations via a Hubbard-like U . We fit the results to the one-dimensional J1-J2-J3-J4 Heisenberg model, which predicts either a first- or second-order spiral-to-ferromagnetic phase transition for different regions of parameter space. At ambient pressure, MnAu2 sits close in parameter space to a dividing line separating first- and second-order transitions, and a combination of pressure and electron doping shifts the system from the first-order region into the second-order region. Our findings demonstrate that the contradiction in pressure experiments regarding the kind of phase transition are likely due to variations in sample quality. Our results also suggest that MnAu2 is amenable to engineering via chemical doping and to controlling θ using pressure and gate voltages, which holds potential for integration in spintronic devices.

  2. Critical Factors Controlling Pd and Pt Potential in Porphyry Cu–Au Deposits: Evidence from the Balkan Peninsula

    Directory of Open Access Journals (Sweden)

    Demetrios G. Eliopoulos

    2014-03-01

    Full Text Available Porphyry Cu–Au–Pd±Pt deposits are significant Au resources, but their Pd and Pt potential is still unknown. Elevated Pd, Pt (hundreds of ppb and Au contents are associated with typical stockwork magnetite-bornite-chalcopyrite assemblages, at the central parts of certain porphyry deposits. Unexpected high grade Cu–(Pd+Pt (up to 6 ppm mineralization with high Pd/Pt ratios at the Elatsite porphyry deposit, which is found in a spatial association with the Chelopech epithermal deposit (Bulgaria and the Skouries porphyry deposit, may have formed during late stages of an evolved hydrothermal system. Estimated Pd, Pt and Au potential for porphyry deposits is consistent with literature model calculations demonstrating the capacity of aqueous vapor and brine to scavenge sufficient quantities of Pt and Pd, and could contribute to the global platinum-group element (PGE production. Critical requirements controlling potential of porphyry deposits may be from the metals contained in magma (metasomatized asthenospheric mantle wedge as indicated by significant Cr, Co, Ni and Re contents. The Cr content may be an indicator for the mantle input.

  3. Dynamics of Green AuNP Formation and Their Application in Core-Shell Nanostructures

    DEFF Research Database (Denmark)

    Engelbrekt, Christian; Zhang, Jingdong; Jensen, Palle Skovhus;

    potential, conductivity, pH, turbidity, UV - Vis extinction , core size and hydrodynamic diameter . The synthesized AuNPs have been employed as core particles in advanced core - shell structures with highly porous platinum nanoparticle coating or copper oxide shells. These hold poten- tials as effective...... catalysts in fuel cells and methanol reformers....

  4. Quantum control theory and applications: A survey

    OpenAIRE

    Dong, Daoyi; Petersen, Ian R.

    2009-01-01

    This paper presents a survey on quantum control theory and applications from a control systems perspective. Some of the basic concepts and main developments (including open-loop control and closed-loop control) in quantum control theory are reviewed. In the area of open-loop quantum control, the paper surveys the notion of controllability for quantum systems and presents several control design strategies including optimal control, Lyapunov-based methodologies, variable structure control and q...

  5. Tailored Au nanorods: optimizing functionality, controlling the aspect ratio and increasing biocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Cai Xiaoqing; Wang, Cheng-Liang; Chen, Hsiang-Hsin; Chien, Chia-Chi; Lai Shengfeng; Chen Yiyun; Hua, Tzu-En; Kempson, Ivan M; Hwu, Y [Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan (China); Yang, C S [Center for Nanomedicine, National Health Research Institutes, Miaoli, Taiwan (China); Margaritondo, G, E-mail: phhwu@sinica.edu.tw [Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2010-08-20

    Monodisperse gold nanorods with high aspect ratio were synthesized by x-ray irradiation. Irradiation was first used to stimulate the creation of seeds. Afterward, nanorod growth was stimulated either by chemical reduction or again by x-ray irradiation. In the last case, the entire process took place without reducing agents. The shape of the final products could be controlled by modulating the intensity of the x-ray irradiation during the seed synthesis. In turn, the nanorod aspect ratio determines the absorption wavelength of the nanorods that can thus be optimized for different applications. Likewise, the aspect ratio influences the uptake of the nanorods by HeLa cells.

  6. Application of Au/TiO2–WO3 material in visible light photoreductive ozone sensors

    International Nuclear Information System (INIS)

    Various ratios of TiO2–WO3 and Au/TiO2–WO3 composites were prepared as ozone-sensing materials. These materials were characterized by temperature-programmed reduction, UV–visible reflective spectra, transmission electron microscopy, and X-ray diffraction. A 460-nm blue LED light source was used for the detection of gaseous ozone, and the sensing properties of various ratios of TiO2–WO3 were measured. Among the various weight ratios of TiO2–WO3, the sensor response of the TiO2–WO3 (3:1) was the highest obtained response (23.8) to 2.5 ppm ozone. By adding 0.1 wt.% Au to the TiO2–WO3 (3:1), the sensor response was improved to 64.0. The ozone-sensing properties are attributed to the mechanism of adsorption, photoreduction, desorption, and the surface reaction processes of ozone. - Highlights: • Visible light LED as photo-reductive light source • Application of Au/TiO2–WO3 material for gaseous ozone sensor • High sensor response of 64.0 to 2.5 ppm ozone

  7. Structural control and K/Ar dating of the Au-Ag epithermal veins in the Shila Cordillera, southern Peru

    International Nuclear Information System (INIS)

    The Au-Ag epithermal mineralization of the Shila Cordillera is dated at about 10.7 Ma (K/Ar on adularia). The vein system is characterized by the association of a major ≅ east-west vein and N120-135 deg. E secondary fractures. The strike-slip faults controlling the veins indicate an initial NE-SW to ENE-WSW Shortening direction, which is compatible with that generally accepted for this period. These structures were reopened during a second phase and channeled mineralizing fluids, the circulation of which may have began at the end of stage 1. (authors)

  8. Robotic vision. [process control applications

    Science.gov (United States)

    Williams, D. S.; Wilf, J. M.; Cunningham, R. T.; Eskenazi, R.

    1979-01-01

    Robotic vision, involving the use of a vision system to control a process, is discussed. Design and selection of active sensors employing radiation of radio waves, sound waves, and laser light, respectively, to light up unobservable features in the scene are considered, as are design and selection of passive sensors, which rely on external sources of illumination. The segmentation technique by which an image is separated into different collections of contiguous picture elements having such common characteristics as color, brightness, or texture is examined, with emphasis on the edge detection technique. The IMFEX (image feature extractor) system performing edge detection and thresholding at 30 frames/sec television frame rates is described. The template matching and discrimination approach to recognize objects are noted. Applications of robotic vision in industry for tasks too monotonous or too dangerous for the workers are mentioned.

  9. Dynamics of Green AuNP Formation and Their Application in Core-Shell Nanostructures

    OpenAIRE

    Engelbrekt, Christian; Zhang, Jingdong; Jensen, Palle Skovhus; Ulstrup, Jens

    2011-01-01

    The formation of gold nanoparticles in our optimized synthesis is achieved through reduction of tetrachloroauric acid in 2 - (N - morpholino)ethanesulphonic acid (MES) buffered glucose and stabilization by starch at room temperature. The formation has been followed by measuring the electrochemical potential, conductivity, pH, turbidity, UV - Vis extinction , core size and hydrodynamic diameter . The synthesized AuNPs have been employed as core particles in advanced core - shell structures wit...

  10. Characterization of self-assembled electrodes based on Au-Pt nanoparticles for PEMFC application

    Energy Technology Data Exchange (ETDEWEB)

    Valenzuela, E. [Univ. Politecnica de Chiapas (Mexico). Energia y Sustentabilidad; Sebastian, P.J.; Gamboa, S.A.; Joseph, S. [Univ. Nacional Autonoma de Mexico, Morelos (Mexico). Centrode Investigacion en Energia; Pal, U. [Univ. Autonoma de Puebla, Pue (Mexico). Inst. de Fisica; Gonzalez, I. [Univ. Autonoma Metropolitana, Mexico City (Mexico). Dept. de Quimica

    2010-07-01

    This paper described the synthesis and characterization of gold (Au), platinum (Pt) and Au-Pt nanoparticles impregnated on a Nafion membrane in a proton exchange membrane fuel cell (PEMFC). The aim of the study was to fabricate the membrane electrode assembly (MEA) by depositing the nanoparticles on the membrane using an immersion technique. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to study the deposition process. Electrochemical impedance spectroscopy (EIS) was used to study the membrane proton conduction process. An elemental mapping analysis was performed in order to study the location of the Au and Pt in the self-assemblies. Results of the study showed that the particles deposited on the Nafion had good stability and a homogenous distribution along the membrane surface. The particles showed a direct relation in size and location with the hydrophilic and hydrophobic distribution phases of the membrane. The main membrane resistance was located between the membrane and the electrolyte. The self-assembled electrodes demonstrated a good performance at standard conditions. 33 refs., 4 tabs., 11 figs.

  11. Electrogenerated Chemiluminescence Behavior of Au nanoparticles-hybridized Pb (II) metal-organic framework and its application in selective sensing hexavalent chromium.

    Science.gov (United States)

    Ma, Hongmin; Li, Xiaojian; Yan, Tao; Li, Yan; Liu, Haiyang; Zhang, Yong; Wu, Dan; Du, Bin; Wei, Qin

    2016-01-01

    In this work, a novel electrochemiluminescence (ECL) sensor based on Au nanoparticles-hybridized Pb (II)-β-cyclodextrin (Pb-β-CD) metal-organic framework for detecting hexavalent chromium (Cr(VI)) was developed. Pb-β-CD shows excellent ECL behavior and unexpected reducing ability towards Au ions. Au nanoparticles could massively form on the surface of Pb-β-CD (Au@Pb-β-CD) without use of any additional reducing agent. In the presence of coreactant K2S2O8, the ECL emission of Pb-β-CD was enhanced by the formation of Au nanoparticles. Cr(VI) can collisionally quench the ECL behavior of Au@Pb-β-CD/S2O8(2-) system and the detection mechanism was investigated. This ECL sensor is found to have a linear response in the range of 0.01-100 μM and a low detection limit of 3.43 nM (S/N = 3) under the optimal conditions. These results suggest that metal-organic framework Au@Pb-β-CD has great potential in extending the application in the ECL field as an efficient luminophore. PMID:26902375

  12. Electrogenerated Chemiluminescence Behavior of Au nanoparticles-hybridized Pb (II) metal-organic framework and its application in selective sensing hexavalent chromium

    Science.gov (United States)

    Ma, Hongmin; Li, Xiaojian; Yan, Tao; Li, Yan; Liu, Haiyang; Zhang, Yong; Wu, Dan; Du, Bin; Wei, Qin

    2016-01-01

    In this work, a novel electrochemiluminescence (ECL) sensor based on Au nanoparticles-hybridized Pb (II)-β-cyclodextrin (Pb-β-CD) metal-organic framework for detecting hexavalent chromium (Cr(VI)) was developed. Pb-β-CD shows excellent ECL behavior and unexpected reducing ability towards Au ions. Au nanoparticles could massively form on the surface of Pb-β-CD (Au@Pb-β-CD) without use of any additional reducing agent. In the presence of coreactant K2S2O8, the ECL emission of Pb-β-CD was enhanced by the formation of Au nanoparticles. Cr(VI) can collisionally quench the ECL behavior of Au@Pb-β-CD/S2O82− system and the detection mechanism was investigated. This ECL sensor is found to have a linear response in the range of 0.01–100 μM and a low detection limit of 3.43 nM (S/N = 3) under the optimal conditions. These results suggest that metal-organic framework Au@Pb-β-CD has great potential in extending the application in the ECL field as an efficient luminophore. PMID:26902375

  13. Application oriented programming and control of industrial robots

    International Nuclear Information System (INIS)

    Efficient use of industrial robots requires a strong interplay between user level commands, the motion control system, and external equipment. It should also be possible for an experienced application engineer to tailor the motion control to a specific application in a convenient way, instead of deficient utilization of the device or tricky user programming which is often the case today. A layered software architecture has been designed based on an application oriented view, considering typical hardware and software constraints. The top layers or the architecture support improved integration of off-line programming with interactive teach-in programming. The proposed solution is based on a transformation of robot programs between an on-line and an off-line representation. A central part of the architecture is an intermediate software layer, allowing the experienced user to introduce application specific motion primitives, on top of the motion control system. Flexibility during system configuration combined with computing efficiency and performance at run-time is of major importance. The solution is based on so called actions, which are methods to be passed between different software layers. Such methods can be specification of nonlinear control parameters, application specific control strategies, or treatment of external sensor signals. The actions can be implemented efficiently even in the multiprocessor case by using relocatable executable pieces of code generated from a special cross-compilation strategy. The lowest layers, comprising the motion control, have to be efficient and still fit in with the upper layers. In these layers, software solutions include an external sensor interface and a concept of motion pipelining allowing sensor based motions to be partly computed in advance. An experimental platform, built around commercially available robots, has been developed to verify the proposed solutions. (au)

  14. Study of the nucleation and growth of antibiotic labeled Au NPs and blue luminescent Au8 quantum clusters for Hg2+ ion sensing, cellular imaging and antibacterial applications

    Science.gov (United States)

    Khandelwal, Puneet; Singh, Dheeraj K.; Sadhu, Subha; Poddar, Pankaj

    2015-11-01

    Herein, we report a detailed experimental study supported by DFT calculations to understand the mechanism behind the synthesis of cefradine (CFD - an antibiotic) labeled gold nanoparticles (Au NPs) by employing CFD as both a mild reducing and capping agent. The analysis of the effect of growth conditions reveals that a higher concentration of HAuCl4 results in the formation of an increasing fraction of anisotropic structures, higher temperature leads to the formation of quasi-spherical particles instead of anisotropic ones, and larger pH leads to the formation of much smaller particles. The cyclic voltammetry (CV) results show that when the pH of the reaction medium increases from 4 to 6, the reduction potential of CFD increases which leads to the synthesis of nanoparticles (in a pH 4 reaction) to quantum clusters (in a pH 6 reaction). The MALDI-TOF mass spectrometry results of supernatant of the pH 6 reaction indicate the formation of [Au8(CFD)2S6] QCs which show fluorescence at ca. 432 nm with a Stokes shift of ca. 95 nm. The blue luminescence from Au8 QCs was applied for sensing of Hg2+ ions on the basis of an aggregation-induced fluorescence quenching mechanism and offers good selectivity and a high sensitivity with a limit of detection ca. 2 nM which is lower than the detection requirement of 10 nM by the U.S. EPA and 30 nM by WHO for drinking water. We have also applied the sensing probe to detect Hg2+ ions in bacterial samples. Further, we have investigated the antibacterial property of as-synthesized Au NPs using MIC, growth curve and cell survival assay. The results show that Au NPs could reduce the cell survival very efficiently rather than the cell growth in comparison to the antibiotic itself. The scanning electron microscopy study shows the degradation and blebbing of the bacterial cell wall upon exposure with Au NPs which was further supported by fluorescence microscopy results. These Au NPs did not show reactive oxygen species generation. We believe

  15. Optical properties of random alloys: application to CuAu and NiPt

    Energy Technology Data Exchange (ETDEWEB)

    Saha, Kamal Krishna; Mookerjee, Abhijit [S N Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake City, Kolkata-700098 (India)

    2005-07-20

    In an earlier paper we presented a formulation for the calculation of the configuration-averaged optical conductivity in random alloys. Our formulation is based on the augmented-space theorem introduced by one of us (Mookerjee 1973 J. Phys. C: Solid State Phys. 6 1340). In this communication we shall combine the augmented space methodology with the tight-binding linear muffin-tin orbital technique (TB-LMTO) to study the optical conductivities of two alloys, CuAu and NiPt.

  16. Synthesis and SERS application of SiO2@Au nanoparticles

    OpenAIRE

    Saini, Apurve; Maurer, Thomas; Lorenzo, Irene Izquierdo; Santos, Andre Ribeiro; Beal, Jérémie; Goffard, Julie; Gérard, Davy; Vial, Alexandre; Plain, Jérôme

    2014-01-01

    In this letter, we report a chemical route for synthesizing SiO2@Au core-shell nanoparticles. The process includes four steps: i) preparation of the silica cores, ii) grafting gold nanoparticles over SiO2 cores, iii) priming of the silica-coated gold nanoparticles with 2 and 10 nm gold colloids and finally iv) formation of complete shell. The optical extinction spectra were experimentally measured and compared to numerical calculations in order to confirm the dimensions deduced from SEM image...

  17. Phenomenological study and modelling of weld behaviour for the control of GTA process by computer aided welding; Etude phenomenologique et modelisation du comportement du bain de fusion en soudage TIG en vue d'une application au controle du procede

    Energy Technology Data Exchange (ETDEWEB)

    Tissot, F.X

    1998-07-01

    The CEA-CEREM/LMS has been working on automation of arc welding processes for years. Particularly, a computer aided welding (CAW) system called 'SYLVARC' was developed to compensate the effects of any eventual disturbance, by means of a real-time control of the welding parameters. Images analysis of the topside weld pool permits to maintain its width at a nominal value. For each welding case, the control parameters have to be determined by considering the transient changes in the weld pool shape following a shift of the welding operating conditions around the nominal working setpoint. However, each corresponding empirical law do not allow any prediction nor any interpretation of the variations which are displayed. Thus, a theoretical model has been developed in this study, by using an analytical solution of heat conduction equations in the case of a Gaussian heat source, moving at constant speed at the surface of a thick plate. In parallel, a numerical approach using the finite elements code MARCUS has been carried out to validate the assumption that the eventual effects which could come from the chosen hypothesis (convection flows in the melt, latent heat transfers and temperature-dependence of the thermo-physical properties of the material are neglected) are constant for small variations around the working setpoint. This has shown that the weld behaviour around the working setpoint is easily predicted by the analytical model if restricted to conduction heat transfers. The using conditions of the model have been optimised as a result of a thorough parametric study. Experimental validations of the approach have been carried out focusing on the welding of stainless steel plates of low thickness. Particularly, in the case of a sharp step in the plate thickness, there is a good agreement of the simulation with the transient behaviour of the weld pool. (author)

  18. Applications of robust control theory - Educational implications

    Science.gov (United States)

    Dorato, P.; Yedavalli, R. K.

    1992-01-01

    A survey is made of applications of robust control theory to problems of flight control, control of flexible space structures, and engine control which have appeared in recent conferences and journals. An analysis is made of which theoretical techniques are most commonly used and what implications this has for graduate and undergraduate education in aerospace engineering.

  19. Crystallographic investigation of Au nanoparticles embedded in a SrTiO{sub 3} thin film for plasmonics applications by means of synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Pincini, Davide, E-mail: davide.pincini@mail.polimi.it [European Synchrotron Radiation Facility, CS 40220, 71, avenue des Martyrs, F-38043 Grenoble Cedex 9 (France); Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy); Mazzoli, Claudio [Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milano (Italy); Bernhardt, Hendrik; Katzer, Christian; Schmidl, Frank [Institut für Festkörperphysik, Friedrich-Schiller-Universität Jena, Helmholtzweg 5, 07743 Jena (Germany); Uschmann, Ingo [Institut für Optik und Quantenelektronik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Detlefs, Carsten [European Synchrotron Radiation Facility, CS 40220, 71, avenue des Martyrs, F-38043 Grenoble Cedex 9 (France)

    2015-03-14

    Self-organized monocrystalline Au nanoparticles with potential applications in plasmonics are grown in a SrTiO{sub 3} matrix by a novel two-step deposition process. The crystalline preferred orientation of these Au nanoparticles is investigated by synchrotron hard x-ray diffraction. Nanoparticles preferentially align with the (111) direction along the substrate normal (001), whereas two in-plane orientations are found with [110]{sub SrTiO{sub 3}}∥[110]{sub Au} and [100]{sub SrTiO{sub 3}}∥[110]{sub Au}. Additionally, a smaller diffraction signal from nanoparticles with the (001) direction parallel to the substrate normal (001) is observed; once again, two in-plane orientations are found, with [100]{sub SrTiO{sub 3}}∥[100]{sub Au} and [100]{sub SrTiO{sub 3}}∥[110]{sub Au}. The populations of the two in-plane orientations are found to depend on the thickness of the gold film deposited in the first step of the growth.

  20. Novel electrochemical redox-active species: one-step synthesis of polyaniline derivative-Au/Pd and its application for multiplexed immunoassay

    Science.gov (United States)

    Wang, Liyuan; Feng, Feng; Ma, Zhanfang

    2015-11-01

    Electrochemical redox-active species play crucial role in electrochemically multiplexed immunoassays. A one-pot method for synthesizing four kinds of new electrochemical redox-active species was reported using HAuCl4 and Na2PdCl4 as dual oxidating agents and aniline derivatives as monomers. The synthesized polyaniline derivative-Au/Pd composites, namely poly(N-methyl-o-benzenediamine)-Au/Pd, poly(N-phenyl-o-phenylenediamine)-Au/Pd, poly(N-phenyl-p-phenylenediamine)-Au/Pd and poly(3,3’,5,5’-tetramethylbenzidine)-Au/Pd, exhibited electrochemical redox activity at -0.65 V, -0.3 V, 0.12 V, and 0.5 V, respectively. Meanwhile, these composites showed high H2O2 electrocatalytic activity because of the presence of Au/Pd. The as-prepared composites were used as electrochemical immunoprobes in simultaneous detection of four tumor biomarkers (carcinoembryonic antigen (CEA), carbohydrate antigen 19-9 (CA199), carbohydrate antigen 72-4 (CA724), and alpha fetoprotein (AFP)). This immunoassay shed light on potential applications in simultaneous gastric cancer (related biomarkers: CEA, CA199, CA724) and liver cancer diagnosis (related biomarkers: CEA, CA199, AFP). The present strategy to the synthesize redox species could be easily extended to other polymers such as polypyrrole derivatives and polythiophene derivatives. This would be of great significance in the electrochemical detection of more analytes.

  1. Tridentate benzylthiols on Au(111): control of self-assembly geometry.

    Science.gov (United States)

    Mezour, Mohamed A; Perepichka, Iryna I; Ivasenko, Oleksandr; Lennox, R Bruce; Perepichka, Dmitrii F

    2015-03-21

    A set of hexasubstituted benzene derivatives with three thiol groups in the 1, 3, 5 positions and varied aliphatic substituents in the 2, 4, 6 positions (Me3-BTMT, Et3-BTMT, ODe3-BTMT) has been synthesized and self-assembled on Au(111). The resulting self-assembled monolayers (SAMs) are characterized by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and electrochemistry. The molecular orientation and long-range order are affected by the “gear effect” of the hexasubstituted benzene ring and van der Waals interactions between the physisorbed alkyl chains drive. Me3-BTMT adopts a standing up orientation which results in the highest molecular surface density but also the lowest degree of chemisorption (1 to 2 Au–S bonds per molecule). In contrast, Et3-BTMT favors a lying down orientation with a greater number of surface-bonded thiol groups (2 to 3) per molecule, associated with the peculiar geometry of this molecule. Finally, ODe3-BTMT adsorbs mainly in a lying down orientation, forming the SAM with the highest degree of chemisorption (all thiol groups are gold-bonded) and the lowest molecular areal density. PMID:25695677

  2. Synthesis and Optical Properties of Au-Ag Alloy Nanoclusters with Controlled Composition

    Directory of Open Access Journals (Sweden)

    J. F. Sánchez-Ramírez

    2008-01-01

    Full Text Available Colloidal solid-solution-like Au-Ag alloy nanoclusters of different compositions were synthesized through citrate reduction of mixed metal ions of low concentrations, without using any other protective or capping agents. Optical absorption of the alloy nanoclusters was studied both theoretically and experimentally. The position of the surface plasmon resonance (SPR absorption band of the nanoclusters could be tuned from 419 nm to 521 nm through the variation of their composition. Considering effective dielectric constant of the alloy, optical absorption spectra for the nanoclusters were calculated using Mie theory, and compared with the experimentally obtained spectra. Theoretically obtained optical spectra well resembled the experimental spectra when the true size distribution of the nanoparticles was considered. High-resolution transmission electron microscopy (HREM, high-angle annular dark field (HAADF imaging, and energy dispersive spectroscopy (EDS revealed the true alloy nature of the nanoparticles with nominal composition being preserved. The synthesis technique can be extended to other bimetallic alloy nanoclusters containing Ag.

  3. ÉTUDE DU TRAITEMENT DES SILOXANES PAR ADSORPTION SUR MATÉRIAUX POREUX : APPLICATION AU TRAITEMENT DES BIOGAZ

    OpenAIRE

    Ricaurte Ortega, Deyanira

    2009-01-01

    Étude du traitement des siloxanes par adsorption sur matériaux poreux : application au traitement des biogaz Les biogaz sont des mélanges à forte teneur en méthane utilisés dans la production de chaleur ou d'électricité. Ils contiennent des quantités plus ou moins importantes de siloxanes qui sont interdits pour de nombreuses utilisations du biogaz. La possibilité d'élimination des siloxanes par adsorption est étudiée. Une étude en réacteurs statiques permet d'évaluer les capacités d'adsorpti...

  4. Low-pressure ETEM Studies of Au assisted MgO Nanorod Growth

    DEFF Research Database (Denmark)

    Wagner, Jakob Birkedal; Duchstein, Linus Daniel Leonhard; Ming, Lin; Damsgaard, Christian Danvad; Hansen, Thomas Willum

    Over the past few decades, there has been an increasing interest in the use of supported nanoparticles in applications ranging from drug delivery to catalysis. The functionality of such nanoparticles is to a large extent controlled by their shape, exposed surface facets and interaction with the...... catalyst nanoparticles in a controlled gas atmosphere, in order to elucidate the mobility of Au surface atoms and the configuration of the Au/MgO interface. The particles are synthesized by depositing a thin layer of Au onto MgO smoke particles. The Au agglomerates into particles that are a few nanometers...

  5. Applications of Feedback Control in Quantum Systems

    OpenAIRE

    Jacobs, Kurt

    2006-01-01

    We give an introduction to feedback control in quantum systems, as well as an overview of the variety of applications which have been explored to date. This introductory review is aimed primarily at control theorists unfamiliar with quantum mechanics, but should also be useful to quantum physicists interested in applications of feedback control. We explain how feedback in quantum systems differs from that in traditional classical systems, and how in certain cases the results from modern optim...

  6. Review of the application of isotopic studies to the genesis of Cu-Au mineralisation at Olympic Dam and Au mineralisation at Porgera, the Tennant Creek district and Yilgarn Craton

    International Nuclear Information System (INIS)

    This paper reviews the application of radiogenic isotopes to the study of four Cu-U and Au deposits or deposit types in the Australasian region: Olympic Dam, Porgera, the Proterozoic Au deposits of the Tennant Creek district and the Archaean gold deposits of the Yilgarn Craton. In each case it has been possible to date the mineralisation and to correlate ore formation with a specific igneous event or stage in crystal evolution. In three cases it was also possible to use radiogenic isotopes to trace the source of the metal(s) or to constrain the fluid pathway. The results of K-Ar , 39Ar/40Ar dating of hydrothermal minerals associated with gold deposits, SHRIMP U-Pb analyses of zircon, and conventional Sr, Nd and Pb isotopic tracing of the ore fluids are reported to illustrate the power of radiogenic isotopes in ore-genesis studies

  7. Adsorption mechanisms of L-Glutathione on Au and controlled nano-patterning through Dip Pen Nanolithography.

    Science.gov (United States)

    Calborean, A; Martin, F; Marconi, D; Turcu, R; Kacso, I E; Buimaga-Iarinca, L; Graur, F; Turcu, I

    2015-12-01

    Dip Pen Nanolithography technique has been employed for patterning L-Glutathione tripeptide (l-y-glutamyl-l-cysteinyl-glycine) nanostructures at specific locations on metallic Au(111) substrate. The formed supramolecular architectures were designed through straight lines and dots serving as precursors for building blocks assemblies in nano-bio-electronics applications or as template structures for functionalized particles in the form of host-guest networks. Tween 20 polyoxyethylene surfactant concentrations ranging from 0.005 to 0.1% (v/v) into initial l-Glutathione tripeptide (2 mg mL(-1)) ink solutions were sequentially tested for the improvement of the ink delivery process and to assure an optimum uniformity and homogeneity over the patterned space. A strong relationship was found between the coated atomic force microscope (AFM) cantilever within the highly effective Tween 20 activator adjuvant and the molecular diffusion along concentration gradients. An increase in the driving force for ink transport from the AFM tip has been demonstrated within the highest 0.1% (v/v) TW 20 surfactant concentration, favoring the patterning of GSH molecules routinely with sub-100 nm resolution. Self-assembled monolayers of GSH were also fabricated and characterized in the light of X-ray photoemission spectroscopy (XPS) and ellipsometric optical measurements. Adsorption from water of l-Glutathione to the gold substrate is proven to be made by the thiol group of cysteine. Theoretical DFT approaches were applied for quantum chemical studies dedicated to electronic processes underneath molecular GSH/Au(111) systems. PMID:26354252

  8. Application of Smalltalk language for accelerator control

    International Nuclear Information System (INIS)

    This paper describes the results of studies for object-oriented control system creation. Using VisualWorks environment based on Smalltalk we created a set of programs, such as Control Model Editor, Control Model Scanner and Control Views, for developing and running an object-oriented model of an accelerator. Our system allows the user to easily create a class library which can be used to develop a number of control programs. The object model defines the object under control, the control logic and graphics for displaying control objects' states. Our experience shows that object-oriented software development is faster compared with traditional languages, and provides more functionality. VisualWorks is a multiplatform environment, and all applications can be ported to different operating systems with only minor changes. VisualWorks also provides high performance, which is important for time-critical control applications. (orig.)

  9. The optimal control and its multiple applications

    OpenAIRE

    Silva, Cristiana J.; Torres, Delfim F.M.; Trelat, Emmanuel

    2009-01-01

    In this work we refer to motivations, applications, and relations of control theory with other areas of mathematics. We present a brief historical review of optimal control theory, from its roots in the calculus of variations and the classical theory of control to the present time, giving particular emphasis to the Pontryagin maximum principle.

  10. Advances and applications in nonlinear control systems

    CERN Document Server

    Volos, Christos

    2016-01-01

    The book reports on the latest advances and applications of nonlinear control systems. It consists of 30 contributed chapters by subject experts who are specialized in the various topics addressed in this book. The special chapters have been brought out in the broad areas of nonlinear control systems such as robotics, nonlinear circuits, power systems, memristors, underwater vehicles, chemical processes, observer design, output regulation, backstepping control, sliding mode control, time-delayed control, variables structure control, robust adaptive control, fuzzy logic control, chaos, hyperchaos, jerk systems, hyperjerk systems, chaos control, chaos synchronization, etc. Special importance was given to chapters offering practical solutions, modeling and novel control methods for the recent research problems in nonlinear control systems. This book will serve as a reference book for graduate students and researchers with a basic knowledge of electrical and control systems engineering. The resulting design proce...

  11. A highly sensitive pressure sensor using a Au-patterned polydimethylsiloxane membrane for biosensing applications

    International Nuclear Information System (INIS)

    We report on the fabrication and characterization of a highly sensitive pressure sensor using a Au film patterned on a polydimethylsiloxane (PDMS) membrane. The strain-induced change in the film resistance was utilized to perform the quantitative measurement of absolute pressure. The highest sensitivity obtained for a 200 µm thick PDMS film sensor was 0.23/KPa with a range of 50 mm Hg, which is the best result reported so far, over that range, for any pressure sensor on a flexible membrane. The noise-limited pressure resolution was found to be 0.9 Pa (0.007 mm Hg), and a response time of ∼200 ms, are the best reported results for these sensors. The ultrahigh sensitivity is attributed to the strain-induced formation of microcracks, the effect of which on the resistance change was found to be highly reversible within a certain pressure range. A physical model correlating the sensitivity with the sensor parameters and crack geometry has been proposed. (paper)

  12. Application of fuzzy logic control in industry

    International Nuclear Information System (INIS)

    An overview is given of the various ways fuzzy logic can be used to improve industrial control. The application of fuzzy logic in control is illustrated by two case studies. The first example shows how fuzzy logic, incorporated in the hardware of an industrial controller, helps to finetune a PID controller, without the operator having any a priori knowledge of the system to be controlled. The second example is from process industry. Here, fuzzy logic supervisory control is implemented in software and enhances the operation of a sintering oven through a subtle combination of priority management and deviation-controlled timing

  13. Safety critical application of fuzzy control

    International Nuclear Information System (INIS)

    After an introduction into safety terms a short description of fuzzy logic will be given. Especially, for safety critical applications of fuzzy controllers a possible controller structure will be described. The following items will be discussed: Configuration of fuzzy controllers, design aspects like fuzzfiication, inference strategies, defuzzification and types of membership functions. As an example a typical fuzzy rule set will be presented. Especially, real-time behaviour a fuzzy controllers is mentioned. An example of fuzzy controlling for temperature control purpose within a nuclear reactor together with membership functions and inference strategy of such a fuzzy controller will be presented. (author). 4 refs, 17 figs

  14. Molecular beam epitaxy of GaAs nanowires and their sustainability for optoelectronic applications. Comparing Au- and self-assisted growth methods

    Energy Technology Data Exchange (ETDEWEB)

    Breuer, Steffen

    2011-09-28

    In this work the synthesis of GaAs nanowires by molecular beam epitaxy (MBE) using the vapour-liquid-solid (VLS) mechanism is investigated. A comparison between Au- and self-assisted VLS growth is at the centre of this thesis. While the Au-assisted method is established as a versatile tool for nanowire growth, the recently developed self-assisted variation results from the exchange of Au by Ga droplets and thus eliminates any possibility of Au incorporation. By both methods, we achieve nanowires with epitaxial alignment to the Si(111) substrates. Caused by differences during nanowire nucleation, a parasitic planar layer grows between the nanowires by the Au-assisted method, but can be avoided by the self-assisted method. Au-assisted nanowires grow predominantly in the metastable wurtzite crystal structure, while their self-assisted counterparts have the zincblende structure. All GaAs nanowires are fully relaxed and the strain arising from the lattice mismatch between GaAs and Si of 4.1 % is accommodated by misfit dislocations at the interface. Self-assisted GaAs nanowires are generally found to have vertical and non-polar side facets, while tilted and polar nanofacets were described for Au-assisted GaAs nanowires. We employ VLS nucleation theory to understand the effect of the droplet material on the lateral facets. Optoelectronic applications require long minority carrier lifetimes at room temperature. We fabricate GaAs/(Al,Ga)As core-shell nanowires and analyse them by transient photoluminescence (PL) spectroscopy. The results are 2.5 ns for the self-assisted nanowires as well as 9 ps for the Au-assisted nanowires. By temperature-dependent PL measurements we find a characteristic activation energy of 77 meV that is present only in the Au-assisted nanowires. We conclude that most likely Au is incorporated from the droplets into the GaAs nanowires and acts as a deep, non-radiative recombination centre.

  15. Genome Wide Transcriptome Analysis reveals ABA mediated response in Arabidopsis during Gold (AuCl4-) treatment

    OpenAIRE

    Devesh eShukla; Sneha eKrishnamurthy; Shivendra Vikram Sahi

    2014-01-01

    The unique physico-chemical properties of gold nanoparticles (AuNPs) find manifold applications in diagnostics, medicine and catalysis. Chemical synthesis produces reactive AuNPs and generates hazardous by-products. Alternatively, plants can be utilized to produce AuNPs in an eco-friendly manner. To better control the biosynthesis of AuNPs, we need to first understand the detailed molecular response induced by AuCl4- In this study, we carried out global transcriptome analysis in root tissue ...

  16. Genome wide transcriptome analysis reveals ABA mediated response in Arabidopsis during gold (AuCl− 4) treatment

    OpenAIRE

    Shukla, Devesh; Krishnamurthy, Sneha; Shivendra V. Sahi

    2014-01-01

    The unique physico-chemical properties of gold nanoparticles (AuNPs) find manifold applications in diagnostics, medicine and catalysis. Chemical synthesis produces reactive AuNPs and generates hazardous by-products. Alternatively, plants can be utilized to produce AuNPs in an eco-friendly manner. To better control the biosynthesis of AuNPs, we need to first understand the detailed molecular response induced by AuCl− 4 In this study, we carried out global transcriptome analysis in root tissue ...

  17. Genome wide transcriptome analysis reveals ABA mediated response in Arabidopsis during gold (AuCl−4) treatment

    OpenAIRE

    Shukla, Devesh; Krishnamurthy, Sneha; Shivendra V. Sahi

    2014-01-01

    The unique physico-chemical properties of gold nanoparticles (AuNPs) find manifold applications in diagnostics, medicine and catalysis. Chemical synthesis produces reactive AuNPs and generates hazardous by-products. Alternatively, plants can be utilized to produce AuNPs in an eco-friendly manner. To better control the biosynthesis of AuNPs, we need to first understand the detailed molecular response induced by AuCl−4 In this study, we carried out global transcriptome analysis in root tissue o...

  18. A Fabrication Route for Arrays of Ultra-low-Noise MoAu Transition Edge Sensors on Thin Silicon Nitride for Space Applications

    OpenAIRE

    Glowacka, D. M.; Crane, M.; Goldie, D. J.; Withington, S.

    2014-01-01

    We describe a process route to fabricate arrays of Ultra-low-Noise MoAu Transition Edge Sensors (TESs). The low thermal conductance required for space applications is achieved using 200 nm-thick Silicon Nitride (SiNx ) patterned to form long-thin legs with widths of 2.1 {\\mu}m. Using bilayers formed on SiNx islands from films with 40 nm-thick Mo and Au thicknesses in the range 30 to 280 nm deposited by dc-sputtering in ultra-high vacuum we can obtain tunable transition temperatures in the ran...

  19. LA CONTRIBUTION DU CONTROLE INTERNE ET DE L’AUDIT AU GOUVERNEMENT D’ENTREPRISE.

    OpenAIRE

    Ebondo Wa Mandzila, Eustache

    2004-01-01

    Assimilating the management of managerial corporations to the governing of a nation, some researchers have focused their studies on developing their research and then recommending the mechanisms of internal and external control as remedies to limit the opportunistic behaviours of agents. After introducing the limits of these mechanisms, the first part of the thesis will focus on considering the internal control and audit as two mechanisms capable of regulating the behaviours of different stak...

  20. Development of bifacial inverted polymer solar cells using a conductivity-controlled transparent PEDOT:PSS and a striped Au electrode on the hole collection side

    Science.gov (United States)

    Kuwabara, Takayuki; Katori, Shinji; Arima, Kazuhiro; Omura, Yoshihiro; Yamaguchi, Takahiro; Taima, Tetsuya; Takahashi, Kohshin

    2014-02-01

    An inverted bifacial polymer solar cell was developed using a conductivity-controlled transparent poly(3,4-ethylenedioxylenethiophene):poly(4-styrene sulfonic acid) (PEDOT:PSS) as a hole collection layer and a striped Au electrode with a large open aperture ratio (Rap) as a hole collection electrode. We investigated the performance of the device by varying the interelectrode distance of the striped Au electrode and the sheet resistance of the PEDOT:PSS film. The device using untreated Clevios P (PEDOT:PSS) showed a maximum electric output (Pw) in the Rap range of 50 to 65%. When alcohol-treated Clevios P (Clevios P+) with a lower electrical resistance was used, the maximum Pw increased by 40% compared with that of the device using Clevios P. The maximum Pw was obtained in the Rap range of 84% as the hole collection efficiency of the striped Au electrode improved with the decreased sheet resistance of the PEDOT:PSS.

  1. DNA-templated synthesis of PtAu bimetallic nanoparticle/graphene nanocomposites and their application in glucose biosensor

    OpenAIRE

    Leng, Jing; Wang, Wen-Min; Lu, Li-min; Bai, Ling; Qiu, Xin-Lan

    2014-01-01

    In this paper, single-stranded DNA (ss-DNA) is demonstrated to functionalize graphene (GR) and to further guide the growth of PtAu bimetallic nanoparticles (PtAuNPs) on GR with high densities and dispersion. The obtained nanocomposites (PtAuNPs/ss-DNA/GR) were characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectrometer (EDS), and electrochemical techniques. Then, an enzyme nanoassembly was prepared by self-assembling glucose oxidase (GOD) on PtAuNP/ss-DNA/GR ...

  2. Unfalsified Control; Application to automatic flight control system design

    Directory of Open Access Journals (Sweden)

    Adrian-Mihail STOICA

    2011-09-01

    Full Text Available Unfalsified Control Theory has been developed to provide a way for avoiding modeling uncertainties in controller design. It belongs to the class of control methods called Adaptive Supervisory Switching Control, which work by introducing in the control scheme a supervisory unit which chooses, from a set of candidate controllers the one most suited for the current plant. Unfalsified Control works by using a switching logic that dispenses with the need for a-priori knowledge of the dynamic model. At discrete moments of time, using the input/output data recorded up to that point, the supervisory calculates for each candidate controller a performance index, and compares it to a given threshold. Controllers surpassing that threshold are removed from the candidate controller set. This process is called falsification. If the controller in the loop is one such falsified controller it is replaced. In this paper we investigate the suitability of this method for aeronautical control applications. We review the theory behind this control scheme and adapt it to the case of controlling a fighter aircraft. We also provide a case study, where we test this control scheme on a simulated fighter aircraft.

  3. Symbolic quality control for multimedia applications

    OpenAIRE

    Combaz J.; Fernandez J.-C.; Sifakis J.; Strus L.

    2008-01-01

    We present a fine grain quality control method for multimedia applications. The method takes as input an application software composed of actions. The execution times of actions are unknown increasing functions of quality level parameters. The method allows the construction of a Controller which computes adequate action schedules and corresponding quality levels, so as to meet QoS requirements for a given platform. These include requirements for safety (action deadlines are met) as well optim...

  4. Synthèse de nouveaux polyesters “verts” issus de ressources oléagineuses : application au renfort au choc du poly(L-lactide)

    OpenAIRE

    Lebarbe, Thomas

    2013-01-01

    Dans cette étude, plusieurs voies ont été explorées dans l’objectif d’utiliser des polyesters aliphatiques issus de ressources oléagineuses comme additifs pour le renfort au choc du poly(L-lactide) (PLLA). Dans un premier temps, des poly(ester-amide)s (PEAs) ont été synthétisés à partir de dérivés de l’huile de ricin. La relation structure-propriétés des PEAs obtenus a été clairement établie. La dispersion des PEAs (à différents taux) par extrusion à l’état fondu dans une matrice de PLLA a en...

  5. Optimal control with aerospace applications

    CERN Document Server

    Longuski, James M; Prussing, John E

    2014-01-01

    Want to know not just what makes rockets go up but how to do it optimally? Optimal control theory has become such an important field in aerospace engineering that no graduate student or practicing engineer can afford to be without a working knowledge of it. This is the first book that begins from scratch to teach the reader the basic principles of the calculus of variations, develop the necessary conditions step-by-step, and introduce the elementary computational techniques of optimal control. This book, with problems and an online solution manual, provides the graduate-level reader with enough introductory knowledge so that he or she can not only read the literature and study the next level textbook but can also apply the theory to find optimal solutions in practice. No more is needed than the usual background of an undergraduate engineering, science, or mathematics program: namely calculus, differential equations, and numerical integration. Although finding optimal solutions for these problems is a...

  6. Developing an aqueous approach for synthesizing Au and M@Au (M = Pd, CuPt) hybrid nanostars with plasmonic properties

    CERN Document Server

    Du, Jingshan; Xiong, Yalin; Lin, Zhuoqing; Zhang, Hui; Yang, Deren

    2014-01-01

    Anisotropic Au nanoparticles show unique localized surface plasmon resonance (LSPR) properties, which make it attractive in optical, sensing, and biomedical applications. In this contribution, we report a general and facile strategy towards aqueous synthesis of Au and M@Au (M = Pd, CuPt) hybrid nanostars by reducing HAuCl4 with ethanolamine in the presence of cetyltrimethylammonium bromide (CTAB). According to electron microscopic observation and spectral monitoring, we found that the layered epitaxial growth mode (i.e., Frank-van der Merwe mechanism) contributes to the enlargement of the core, while, the random attachment of Au nanoclusters onto the cores accounts for the formation of the branches. Both of them are indispensable for the formation of the nanostars. The LSPR properties of the Au nanoparticles have been well investigated with morphology control via precursor amount and growth temperature. The Au nanostars showed improved surface-enhanced Raman spectroscopy (SERS) performance for rhodamine 6G du...

  7. Using Geomodelling and Geophysical Inversion to Evaluate the Geological Controls on Low-Sulphidation Epithermal Au-Ag mineralisation in the Drummond and Bowen Basins, Australia

    Science.gov (United States)

    Feltrin, Leonardo; Baker, Timothy; Oliver, Nick; Scott, Margaretha; Wilkinson, Kate; Fitzell, Melanie; Dixon, Owen; Bertelli, Martina

    2008-05-01

    We present a 3D geological model that integrates different datasets and incorporates geophysical inversion of airborne gravimetric and magnetic surveys of the northern part of the Drummond and Bowen basins. These basins are known for their endowment of low-sulphidation, epithermal Au-Ag mineralisation. The objective of this computer based reconstruction is to empirically evaluate the key controlling variables that contributed to the spatial localization of 147 Palaeozoic and Mesozoic shallow hydrothermal gold systems, found predominantly in veins and breccia hosted in basal volcanics and volcaniclastic intervals developed in a back-arc rift environment. The model provides a three-dimensional, regional scale (100,000 km2) perspective on the spatial associations between geology, structure, magmatism and known mineral occurrences, representing a 3D framework for precious-metals exploration. Results of 3D visualisation of geological and geophysical data suggest that magmatic intrusions, and correlative volcanic centres localized most of the major deposits and also controlled the arrangement of clusters of uneconomic Au-Ag occurrences. The empirical modelling supports a model for the genesis of low-sulphidation epithermal Au-Ag mineralisation that favours a strong spatial association with shallow felsic to intermediate magmatic intrusions, similarly to that proposed for high-sulphidation systems. Geophysical inversion estimates for the depth of magmatic bodies suggest also that they may have controlled the efficiency of the hydrothermal, mineralising systems-shallow intrusions tend to be associated with greater tonnages of Au-Ag and are spatially associated with the larger clusters of occurrences. However, the composition of magmatic intrusions (mafic, intermediate, felsic) may have been important in regulating the amount of available bisulphide in the volatile phase, exerting a control on Au grade/tonnage independent of the depth of emplacement of intrusions.

  8. Contribution au developpement d'une methode de controle des procedes dans une usine de bouletage

    Science.gov (United States)

    Gosselin, Claude

    This thesis, a collaborative effort between Ecole de technologie superieure and ArcelorMittal Company, presents the development of a methodology for monitoring and quality control of multivariable industrial production processes. This innovation research mandate was developed at ArcelorMittal Exploitation Miniere (AMEM) pellet plant in Port-Cartier (Quebec, Canada). With this undertaking, ArcelorMittal is striving to maintain its world class level of excellence and continues to pursue initiatives that can augment its competitive advantage worldwide. The plant's gravimetric classification process was retained as a prototype and development laboratory due to its effect on the company's competitiveness and its impact on subsequent steps leading to final production of iron oxide pellets. Concretely, the development of this expertise in process control and in situ monitoring will establish a firm basic knowledge in the fields of complex system physical modeling, data reconciliation, statistical observers, multivariate command and quality control using real-time monitoring of the desirability function. The hydraulic classifier is mathematically modeled. Using planned disturbances on the production line, an identification procedure was established to provide empirical estimations of the model's structural parameters. A new sampling campaign and a previously unpublished data collection and consolidation policy were implemented plant-wide. Access to these invaluable data sources has enabled the establishment of new thresholds that govern the production process and its control. Finally, as a substitute for the traditional quality control process, we have implemented a new strategy based on the use of the desirability function. Our innovation is not in using this Finally, as a substitute for the traditional quality control process, we have implemented a new strategy based on the use of the desirability function. Our innovation is not in using this function as an indicator of

  9. Quality Control for Expanded Tsetse Production, Sterilization and Field Application

    International Nuclear Information System (INIS)

    The use of the sterile insect technique (SIT) for the control of pest insects as part of an integrated, area-wide approach is widely accepted. Its application for the eradication of different tsetse flies, the vectors of human sleeping sickness and African animal trypanosomosis, is attracting increasing interest. Following several initial demonstrations of the application of the SIT for tsetse control the technique was applied on the island of Unguja, Zanzibar, in the mid-1990s and, as the final component of an integrated control programme, led to the eradication of the only tsetse species on the island, Glossina austeni. This successful programme encouraged a number of countries to embark on projects with an SIT component for tsetse control, most Ethiopia. In 2001 the Pan African Tsetse and Trypanosomosis Eradication Campaign (PATTEC) was launched by the Organization of African Unity (now African Union, AU) and, subsequently, six countries obtained funding from the African Development Bank (AfDB) in 2005 to support control programmes with an SIT component. A further six countries have subsequently requested AfDB funding for their programmes. The FAO/IAEA coordinated research project (CRP) on Automation for Tsetse Mass Rearing For Use in Sterile Insect Technique Programmes, which was completed in 2001, led to the development of a semi-automated system for tsetse production. Using this new system, a large rearing facility was established in Addis Ababa, Ethiopia, to supply sterile males for an elimination programme in the southern Rift Valley. The development of large-scale rearing highlighted the need for improved quality control procedures and, with this in mind, the Joint FAO/IAEA Division of Nuclear Techniques in Food and Agriculture established a CRP in 2003 entitled Improved and Harmonized Quality Control for Expanded Tsetse Production, Sterilization and Field Application with the Objective of Improving and Expanding the Quality Control Sections of the FAO

  10. Application of an asymmetric flow field flow fractionation multi-detector approach for metallic engineered nanoparticle characterization - Prospects and limitations demonstrated on Au nanoparticles

    International Nuclear Information System (INIS)

    Highlights: → In this study we present a size- and element selective method, outlined to characterize metallic ENPs, and demonstrated on engineered Au-NP. → A method for quantification of ionic- and particular fraction for nanoparticles in dispersions is presented. → Influence of membrane materials, carrier liquid and flow parameters for A4F was studied. → Comparison of MALLS and DLS for nanoparticle size determination was performed. → Coupling of ICPMS to the A4F, UV/vis and light scattering apparatus is shown. - Abstract: In this work we discuss about the method development, applicability and limitations of an asymmetric flow field flow fractionation (A4F) system in combination with a multi-detector setup consisting of UV/vis, light scattering, and inductively coupled plasma mass spectrometry (ICPMS). The overall aim was to obtain a size dependent-, element specific-, and quantitative method appropriate for the characterization of metallic engineered nanoparticle (ENP) dispersions. Thus, systematic investigations of crucial method parameters were performed by employing well characterized Au nanoparticles (Au-NPs) as a defined model system. For good separation performance, the A4F flow-, membrane-, and carrier conditions were optimized. To obtain reliable size information, the use of laser light scattering based detectors was evaluated, where an online dynamic light scattering (DLS) detector showed good results for the investigated Au-NP up to a size of 80 nm in hydrodynamic diameter. To adapt large sensitivity differences of the various detectors, as well as to guarantee long term stability and minimum contamination of the mass spectrometer a split-flow concept for coupling ICPMS was evaluated. To test for reliable quantification, the ICPMS signal response of ionic Au standards was compared to that of Au-NP. Using proper stabilization with surfactants, no difference for concentrations of 1-50 μg Au L-1 in the size range from 5 to 80 nm for citrate

  11. Probabilistically Tuned LQ Control for Mechatronic Applications

    Czech Academy of Sciences Publication Activity Database

    Belda, Květoslav

    2009-01-01

    Roč. 9, č. 2 (2009), s. 19-24. ISSN 1336-5010 Institutional research plan: CEZ:AV0Z10750506 Keywords : adaptive control * state-space realization * mechatronic applications Subject RIV: BC - Control System s Theory http://library.utia.cas.cz/separaty/historie/belda-0332695.pdf

  12. Core-shell Au/Ag nanoparticles embedded in silicate sol-gel network for sensor application towards hydrogen peroxide

    Indian Academy of Sciences (India)

    Shanmugam Manivannan; Ramasamy Ramaraj

    2009-09-01

    The electrocatalytic activity of core-shell Au100-Ag ( = 15, 27, 46, and 60) bimetallic nanoparticles embedded in methyl functionalized silicate MTMOS network towards the reduction of hydrogen peroxide was investigated by using cyclic voltammetry and chronoamperometric techniques. Core-shell Au/Ag bimetallic nanoparticles were characterized by absorption spectra and HRTEM. The MTMOS silicate sol-gel embedded Au73Ag27 core-shell nanoparticles modified electrode showed better synergistic electrocatalytic effect towards the reduction of hydrogen peroxide when compared to monometal MTMOS-Aunps and MTMOS-Agnps modified electrodes. These modified electrodes were studied without immobilizing any enzyme in the MTMOS sol-gel matrix. The present study highlights the influence of molar composition of Ag nanoparticles in the Au/Ag bimetallic composition towards the electrocatalytic reduction and sensing of hydrogen peroxide in comparison to monometal Au and Ag nanoparticles.

  13. Return method: Some applications to flow control

    International Nuclear Information System (INIS)

    Due to recent progress in advanced technologies in many fields of engineering sciences, applications of flow control are developing very quickly. In this paper we survey only a tiny and theoretical part of the recent results obtained in flow control, namely some results on the controllability and on the stabilizability of the equations of incompressible fluids which have been obtained by means of the return method. (author)

  14. Synthesis, characterization and in vitro biocompatibility study of Au/TMC/Fe3O4 nanocomposites as a promising, nontoxic system for biomedical applications

    Directory of Open Access Journals (Sweden)

    Hanieh Shirazi

    2015-08-01

    Full Text Available The unique properties and applications of iron oxide and Au nanoparticles have motivated researchers to synthesize and optimize a combined nanocomposite containing both. By using various polymers such as chitosan, some of the problems of classic core–shell structures (such as reduced saturation magnetization and thick coating have been overcome. In the present study, chitosan and one of its well-known derivatives, N-trimethylchitosan (TMC, were applied to construct three-layer nanocomposites in an Au/polymer/Fe3O4 system. It was demonstrated that replacement of chitosan with TMC reasonably improved the properties of the final nanocomposites including their size, magnetic behavior and thermal stability. Moreover, the results of the MTT assay showed no significant cytotoxicity effect when the Au/TMC/Fe3O4 nanocomposites were applied in vitro. These TMC-containing magnetic nanoparticles are well-coated by Au nanoparticles and have good biocompatibility and can thus play the role of a platform or a label in various fields of application, especially the biomedical sciences and biosensors.

  15. Soft Computing Techniques for Process Control Applications

    Directory of Open Access Journals (Sweden)

    Rahul Malhotra

    2011-09-01

    Full Text Available Technological innovations in soft computing techniques have brought automation capabilities to new levelsof applications. Process control is an important application of any industry for controlling the complexsystem parameters, which can greatly benefit from such advancements. Conventional control theory isbased on mathematical models that describe the dynamic behaviour of process control systems. Due to lackin comprehensibility, conventional controllers are often inferior to the intelligent controllers. Softcomputing techniques provide an ability to make decisions and learning from the reliable data or expert’sexperience. Moreover, soft computing techniques can cope up with a variety of environmental and stabilityrelated uncertainties. This paper explores the different areas of soft computing techniques viz. Fuzzy logic,genetic algorithms and hybridization of two and abridged the results of different process control casestudies. It is inferred from the results that the soft computing controllers provide better control on errorsthan conventional controllers. Further, hybrid fuzzy genetic algorithm controllers have successfullyoptimized the errors than standalone soft computing and conventional techniques.

  16. Détection et suivi visuels robustes d'objets complexes : applications au rendezvous spatial autonome

    OpenAIRE

    Petit, Antoine

    2013-01-01

    In this thesis, we address the issue of fully localizing a known object through computer vision, using a monocular camera, what is a central problem in robotics. A particular attention is here paid on space robotics applications, with the aims of providing a unified visual localization system for autonomous navigation purposes for space rendezvous and proximity operations. Two main challenges of the problem are tackled: initially detecting the targeted object and then tracking it frame-by-fra...

  17. Cfd Engine Applications At Fiat Research Centre Applications de la modélisation 3D au FIAT Research Centre

    Directory of Open Access Journals (Sweden)

    Lisbona M. G.

    2006-12-01

    Full Text Available The CFD (computer fluid dynamic simulation of the complete engine cycle of the 2400 cm3 JTD 10 V engine for the Alfa Romeo 156 is presented. The intake stroke analysis has followed a procedure usually applied at CRF for gasoline engines. Spray and combustion analysis at the selected operating condition of 3500 tr/min and 13 bar BMEP (brake mean effective pressure has given results in fair agreement with the experimental data, but revealed the need of more accurate models for the initial phase of combustion. Finally, the simulation of the exhaust phase has required great care in the set-up of the initial field and boundary conditions. Flow field characteristics are discussed at two crank angles, corresponding to peak values of the exhaust mass flow rate. Cet article présente la simulation 3D du cycle complet du moteur 2400 cm3 JTD 10 V de l'Alfa Romeo 156. L'analyse de la phase d'admission a suivi une procédure habituellement utilisée pour les moteurs à essence. L'analyse du spray et de la combustion au régime choisi de 3500 tr/min et 13 bar de PMI se compare raisonnablement aux essais, mais indique qu'une meilleure description de la phase initiale de la combustion est nécessaire. La simulation de la phase d'échappement a requis une grande attention quant à la spécification du champ initial et des conditions aux limites. On étudie ici les caractéristiques de l'écoulement à deux instants de cycles correspondant à des maxima de débits à l'échappement.

  18. The kinetics of hollowing of Ag–Au core–shell nanowhiskers controlled by short-circuit diffusion

    International Nuclear Information System (INIS)

    We have grown single-crystalline Ag nanowhiskers on an inert substrate covered by a thin layer of carbon employing a molecular beam epitaxy deposition technique. Subsequent deposition of Au resulted in single-crystalline core–shell Ag–Au nanowhiskers separated by a nanocrystalline thin Au film. Annealing of the core–shell nanowhiskers at the temperature of 170 °C resulted in their partial hollowing and formation of Au nanotubes. We found that the hollowing process is accompanied by Ag enrichment in the thin Au film in the vicinity of the nanowhisker, and by the increase in grain size in the film with increasing distance from the nanowhisker root. The Ag enrichment on the surface of the Au film, and at the Au–carbon interface in the vicinity of the nanowhisker, was identified with the aid of analytical transmission electron microscopy. We proposed a kinetic model of hollowing based on the competition between the energy decrease driving the hollowing process (formation of Au–Ag solid solution in the grain boundaries) and the energy increase associated with the creation of new surfaces. The model predicted an inverse dependence of the hollowing rate on the inner radius of the nanowhiskers, in good agreement with the experimental data

  19. Different control applications on a vehicle using fuzzy logic control

    Indian Academy of Sciences (India)

    Nurkan Yagiz; L Emir Sakman; Rahmi Guclu

    2008-02-01

    In this paper, the active suspension control of a vehicle model that has five degrees of freedom with a passenger seat using a fuzzy logic controller is studied. Three cases are taken into account as different control applications. In the first case, the vehicle model having passive suspensions with an active passenger seat is controlled. In the second case, active suspensions with passive passenger seat combination are controlled. In the third case, both the passenger seat and suspensions have active controllers. Vibrations of the passenger seat in the three cases due to road bump input are simulated. At the end of the study, the results are compared in order to select the combination that supplies the best ride comfort.

  20. Plasmon-controlled narrower and blue-shifted fluorescence emission in (Au-SiO2)SiC nanohybrids

    International Nuclear Information System (INIS)

    Fluorescent imaging is a key tool in biology. On one hand, organic dyes are subjected to bleaching; while, on the other hand II–VI semiconductor quantum dots are photostable, but may exhibit some toxicity. Silicon carbide nanoparticles (SiC NPs) are a good alternative as SiC is chemically inert and considered as biocompatible material. However, their fluorescence quantum yield is weak. Plasmon-controlled fluorescence appears as a mean to enhance SiC NPs fluorescence. To this aim, new fluorescent nanohybrids (NHs) involving a gold colloid surrounded by a silica shell and overcoated with SiC NPs have been engineered. Au-SiO2 particles were synthesized via a sol–gel method to obtain a controlled thickness of silica around gold colloid. Then, SiC NPs were immobilized onto silica by covalent bonding. TEM was used to study the structural properties of NHs. The influence of several parameters on NHs’ fluorescence properties was investigated. It reveals that excitation wavelength must be chosen as close as possible to the gold plasmon band to avoid quenching of emission due to energy transfer between gold absorption and SiC emission. Moreover, the silica thickness is a key parameter to obtain high enhancement; for gold colloids of 20 nm in diameter overcoated by a 25 nm shell, an enhancement factor as high as 12.5 was obtained with a narrower and blue-shifted emission band. This blue-shift can be attributed to the surface chemistry modification of SiC NPs when they are covalently bonded to silica.

  1. Contributions au traitement statistique du signal avec des applications biomédicales

    OpenAIRE

    Nguyen, Quang Thang

    2012-01-01

    Cette étude présente des contributions en traitement statistique du signal avec des applications biomédicales. La thèse est divisée en deux parties. La première partie traite de la détection des hotspots à l'interface des protéines. Les hotspots sont les résidus dont les contributions énergétiques sont les plus importantes dans l'interaction entre protéines. Les forêts aléatoires (Random Forests) sont utilisées pour la classification. Une nouvelle famille de descripteurs de hotspot est égalem...

  2. Carbon nanotubes: controlled growth and application

    Directory of Open Access Journals (Sweden)

    Chang Liu

    2013-01-01

    Full Text Available Notable progress has been made on the synthesis, properties and uses of carbon nanotubes (CNTs in the past two decades. However, the controlled growth of single-wall CNTs (SWCNTs with predefined and uniform structures remains a big challenge, and making full use of CNTs in applications still requires great effort. In this article, our strategies and recent progress on the controlled synthesis of SWCNTs by chemical vapor deposition are reviewed, and the applications of CNTs in lithium-ion batteries, transparent conductive films, and as connectors of metal atomic chains are discussed. Finally, future prospects for CNTs are considered.

  3. Fluorescent Properties of Au Nanoclusters and Their Biological Applications%金团簇的荧光性质及其生物应用

    Institute of Scientific and Technical Information of China (English)

    任娟; 代雯乐; 付欣; 苏梦; 蔡晶晶; 马占芳

    2011-01-01

    金纳米团簇作为一类新型纳米材料具有独特的光学特性。当金纳米团簇颗粒的尺寸小到与电子的费米波长(〈1nm)相当时,由于量子尺寸效应,金颗粒会受激发射出荧光。作为一种新型荧光材料,金纳米团簇具有发光颜色随团簇尺寸可调、荧光不易猝灭等许多优势。本文主要综述了金纳米团簇的荧光性质及其在生物标记、生物成像以及生物检测等方面的应用。%Au nanoclusters have emerged as a class of materials with unique optical properties.When the size of Au nanocluster decrease to comparable to the Fermi wavelength(1nm) of an electron,it exhibits fluorescent characteristics while they are excited,which resulted from its quantum effect.As a novel fluorescent material,Au nanoclusters show size-dependent emission,a slower photobleaching rate and very good stability.The fluorescent properties of Au nanoclusters and their applications in the fields of biological labeling,biological imaging,and biodetection were mainly reviewed.

  4. Application of EIS with Au-Hg microelectrode in determining electron transfer mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Bai, X. [College of Marine Studies, University of Delaware, Lewes, DE 19958 (United States); Dexter, S.C. [College of Marine Studies, University of Delaware, Lewes, DE 19958 (United States)]. E-mail: dexter@udel.edu; Luther, G.W. [College of Marine Studies, University of Delaware, Lewes, DE 19958 (United States)

    2006-01-20

    The objective of this study was to investigate the application of microelectrodes with electrochemical impedance spectroscopy (EIS) for distinguishing between one- and two-electron transfer electrochemical reactions occurring within marine microbial biofilms. In our study, both gold and gold-mercury amalgam microelectrodes with tip diameters of 100 {mu}m were used. EIS measurements were performed at the half-wave potentials of the chemicals of interest in 0.5 M NaCl aqueous solutions containing 100 {mu}M each of FeCl{sub 3}, [Fe(Cat){sub 2}]{sup -}, [Fe(Cat){sub 3}]{sup 3-}, [Fe(4NCat){sub 3}]{sup 3-}, MnCl{sub 2}, FeCl{sub 2} and mixed solutions with two of those chemicals in NaCl solution or seawater. The results showed that there was a linear relationship between the impedance Z {sub re}, Z {sub im} and angular frequency {omega} {sup -1/2} obtained at phase angle of 45{sup o} for both one- and two-electron transfer reactions. One-electron transfer reactions could then be distinguished from two-electron transfer reactions by the slopes.

  5. Adaptive Control Algorithms, Analysis and Applications

    OpenAIRE

    Landau, Ioan; Lozano, Rogelio; M'Saad, Mohammed; Karimi, Alireza

    2011-01-01

    Adaptive Control (second edition) shows how a desired level of system performance can be maintained automatically and in real time, even when process or disturbance parameters are unknown and variable. It is a coherent exposition of the many aspects of this field, setting out the problems to be addressed and moving on to solutions, their practical significance and their application. Discrete-time aspects of adaptive control are emphasized to reflect the importance of digital computers in the ...

  6. Une chaîne de traitement de l'information géographique au service de l'application de la loi Littoral

    Directory of Open Access Journals (Sweden)

    Patrick GUILLOPÉ

    1994-09-01

    Full Text Available L’application de la loi Littoral nécessitait une approche nouvelle de la part de l’État et la mise en œuvre d’outils nouveaux pour une gestion à long terme. L’apport de traitements automatiques de l’information géographique a été ainsi testé au CETE Normandie-Centre sur trois des grands principes posés par cette loi.

  7. DNA-templated synthesis of PtAu bimetallic nanoparticle/graphene nanocomposites and their application in glucose biosensor

    Science.gov (United States)

    Leng, Jing; Wang, Wen-Min; Lu, Li-Min; Bai, Ling; Qiu, Xin-Lan

    2014-02-01

    In this paper, single-stranded DNA (ss-DNA) is demonstrated to functionalize graphene (GR) and to further guide the growth of PtAu bimetallic nanoparticles (PtAuNPs) on GR with high densities and dispersion. The obtained nanocomposites (PtAuNPs/ss-DNA/GR) were characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectrometer (EDS), and electrochemical techniques. Then, an enzyme nanoassembly was prepared by self-assembling glucose oxidase (GOD) on PtAuNP/ss-DNA/GR nanocomposites (GOD/PtAuNPs/ss-DNA/GR). The nanocomposites provided a suitable microenvironment for GOD to retain its biological activity. The direct and reversible electron transfer process between the active site of GOD and the modified electrode was realized without any extra electron mediator. Thus, the prepared GOD/PtAuNP/ss-DNA/GR electrode was proposed as a biosensor for the quantification of glucose. The effects of pH, applied potential, and temperature on the performance of the biosensor were discussed in detail and were optimized. Under optimal conditions, the biosensor showed a linearity with glucose concentration in the range of 1.0 to 1,800 μM with a detection limit of 0.3 μM (S/N = 3). The results demonstrate that the developed approach provides a promising strategy to improve the sensitivity and enzyme activity of electrochemical biosensors.

  8. Growth and electrical characterization of thin conductive Au nanoparticle chains on oxidized Si substrates between electrodes for sensor applications

    International Nuclear Information System (INIS)

    Citrate-stabilized colloid Au nanoparticles with an average diameter of 40 nm have been assembled in nanoparticle chains between microelectrodes on oxidized V-groove-etched Si surfaces by the technique of dielectrophoresis. Chain formation was investigated as a function of electrodes configuration and the amplitude and frequency of the applied electric field. Conductive thin (∝100-200 nm thick) single and multiple Au nanoparticle chains, with a length in the range of 1 to 10 μm, were preferentially formed on V-groove lines between the electrodes. Electrical characterization by temperature-dependent current-voltage measurements showed that the Au nanoparticle chains exhibit ohmic conductivity with a resistance in the range of few Ω to few kΩ, depending on the distance between electrodes and the configuration of the Au nanoparticles in the structure. On the contrary, 5 nm diameter tiopronin-stabilized Au NPs chains exhibited nearest- neighbour hopping conductivity and non-linear thermally-activated I-V characteristics. We also tested nanogap formation in the chains by an applied pulse of electric current, in view of applying the nanoparticle chains in the tracing of chemical or biological molecules. The conductive thin Au nanoparticle chains, with or without nanogaps, are interesting building blocks for different sensor devices. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  9. Controlled Living Nanowire Growth: Precise Control over the Morphology and Optical Properties of AgAuAg Bimetallic Nanowires.

    Science.gov (United States)

    Mayer, Martin; Scarabelli, Leonardo; March, Katia; Altantzis, Thomas; Tebbe, Moritz; Kociak, Mathieu; Bals, Sara; García de Abajo, F Javier; Fery, Andreas; Liz-Marzán, Luis M

    2015-08-12

    Inspired by the concept of living polymerization reaction, we are able to produce silver-gold-silver nanowires with a precise control over their total length and plasmonic properties by establishing a constant silver deposition rate on the tips of penta-twinned gold nanorods used as seed cores. Consequently, the length of the wires increases linearly in time. Starting with ∼210 nm × 32 nm gold cores, we produce nanowire lengths up to several microns in a highly controlled manner, with a small self-limited increase in thickness of ∼4 nm, corresponding to aspect ratios above 100, whereas the low polydispersity of the product allows us to detect up to nine distinguishable plasmonic resonances in a single colloidal solution. We analyze the spatial distribution and the nature of the plasmons by electron energy loss spectroscopy and obtain excellent agreement between measurements and electromagnetic simulations, clearly demonstrating that the presence of the gold core plays a marginal role, except for relatively short wires or high-energy modes. PMID:26134470

  10. Physics related to control and safety of hybrid systems; Physique associee au controle et a la surete des systemes hybrides

    Energy Technology Data Exchange (ETDEWEB)

    Gueton, O

    2001-12-01

    Regarding nuclear waste management, ADS can be considered as large minor actinides burners. In a first part, a critical analysis of different reactor types shows that fast spectrum, helium coolant and nitride fuel, containing 100% minor actinides, agree perfectly with the high transmutation requirements of ADS. The control and safety demonstration of this system represents the main purpose of this study. Understanding spatial and dynamic behaviour of ADS flux is absolutely necessary. For this purpose, we have defined an indicator to quantify spatial decoupling. It shows, on the one hand, point kinetic deficiency to study local transients, and on the other hand, perturbations propagation differences between ADS and critical cores. Then, in a more concrete approach, accidental sequences (source transient, beam de-focalization, reactivity insertions, loss of flow, depressurization) are evaluated for this core, strongly loaded with minor actinides. It is shown that the automatic beam shutdown leads to preserve large safety margins for all studied transients. The accelerator emergency stop is induced by an unexpected evolution of the core control parameters. These parameters, except reactivity, can be directly measured in subcritical systems like in critical ones. Concerning reactivity, we suggest a new method for its absolute determination in ADS: at the time of reactor start-up, the reactivity must be calibrated by coupling two methods of relative reactivity measurements (pulsed source and Approached Source Multiplication) for successive subcritical levels. After that, the on-line follow-up of reactivity is obtained from this calibration like in a critical core. (authors)

  11. Au-controlled enhancement of photoluminescence of NiS nanostructures synthesized via a microwave-assisted hydrothermal technique

    Energy Technology Data Exchange (ETDEWEB)

    Linganiso, Ella Cebisa [DST/CSIR Nanotech Innovation Centre, National Centre for Nano-structured Materials, Council for Scientific and Industrial Research, PO Box 395, Pretoria 0001 (South Africa); Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa); Mwakikunga, Bonex Wakufwa, E-mail: bmwakikunga@csir.co.za [DST/CSIR Nanotech Innovation Centre, National Centre for Nano-structured Materials, Council for Scientific and Industrial Research, PO Box 395, Pretoria 0001 (South Africa); Department of Physics and Biochemical Sciences, The Polytechnic of the University of Malawi, Private Bag 303, Chichiri, Blantyre 0003 (Malawi); Mhlanga, Sabelo Dalton [Department of Applied Chemistry, University of Johannesburg, PO Box 17011, Doornfontein, 2028 Johannesburg (South Africa); Coville, Neil John [Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa); DST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, Wits, 2050 Johannesburg (South Africa)

    2014-11-15

    Nickel sulphide (NiS) nanostructures decorated with gold (Au) nanoparticles (NPs) were synthesized via a microwave-assisted hydrothermal technique. Binary phase NiS (α and β) crystalline nanostructures, bare, and decorated with Au NPs were obtained and confirmed by X-ray diffraction (XRD) studies. TEM analysis revealed that the NiS nanostructures were of various shapes. A quantum confinement effect was confirmed by the blue shift PL emissions and high optical energy band gap observed for the as-synthesized sample. A threefold light emission enhancement due to Au NP coatings was obtained when Au metal NP decoration concentrations was varied from 1% to 10%. These enhancements were attributed to the surface plasmon resonance (SPR) excitation of the surface decorated metal NPs which results in an increased rate of spontaneous emission. The PL enhancement factor was observed to vary at different NiS emissions as well as with the size of the Au NPs. The effect of metal NP decoration on the PL emission of NiS is to the best of our knowledge, presented for the first time. - Highlights: • Binary phase NiS decorated with gold nanoparticles. • Quantum confinement effect confirmed by PL analysis. • PL enhancement depending more on particle size distribution. • Effect of gold on NiS PL is to the best of our knowledge reported for the first time.

  12. Au-controlled enhancement of photoluminescence of NiS nanostructures synthesized via a microwave-assisted hydrothermal technique

    International Nuclear Information System (INIS)

    Nickel sulphide (NiS) nanostructures decorated with gold (Au) nanoparticles (NPs) were synthesized via a microwave-assisted hydrothermal technique. Binary phase NiS (α and β) crystalline nanostructures, bare, and decorated with Au NPs were obtained and confirmed by X-ray diffraction (XRD) studies. TEM analysis revealed that the NiS nanostructures were of various shapes. A quantum confinement effect was confirmed by the blue shift PL emissions and high optical energy band gap observed for the as-synthesized sample. A threefold light emission enhancement due to Au NP coatings was obtained when Au metal NP decoration concentrations was varied from 1% to 10%. These enhancements were attributed to the surface plasmon resonance (SPR) excitation of the surface decorated metal NPs which results in an increased rate of spontaneous emission. The PL enhancement factor was observed to vary at different NiS emissions as well as with the size of the Au NPs. The effect of metal NP decoration on the PL emission of NiS is to the best of our knowledge, presented for the first time. - Highlights: • Binary phase NiS decorated with gold nanoparticles. • Quantum confinement effect confirmed by PL analysis. • PL enhancement depending more on particle size distribution. • Effect of gold on NiS PL is to the best of our knowledge reported for the first time

  13. Stimuli responsive nanomaterials for controlled release applications

    KAUST Repository

    Li, Song

    2012-01-01

    The controlled release of therapeutics has been one of the major challenges for scientists and engineers during the past three decades. Coupled with excellent biocompatibility profiles, various nanomaterials have showed great promise for biomedical applications. Stimuli-responsive nanomaterials guarantee the controlled release of cargo to a given location, at a specific time, and with an accurate amount. In this review, we have combined the major stimuli that are currently used to achieve the ultimate goal of controlled and targeted release by "smart" nanomaterials. The most heavily explored strategies include (1) pH, (2) enzymes, (3) redox, (4) magnetic, and (5) light-triggered release.

  14. Interface effects on tunneling magnetoresistance in organic spintronics with flexible amine-Au links.

    Science.gov (United States)

    Gorjizadeh, Narjes; Quek, Su Ying

    2013-10-18

    Organic spintronics is a promising emerging field, but the sign of the tunneling magnetoresistance (TMR) is highly sensitive to interface effects, a crucial hindrance to applications. A key breakthrough in molecular electronics was the discovery of amine-Au link groups that give a reproducible conductance. Using first-principles calculations, we predict that amine-Au links give improved reproducibility in organic spintronics junctions with Au-covered Fe leads. The Au layers allow only states with sp character to tunnel into the molecule, and the flexibility of amine-Au links results in a narrow range of TMR for a fixed number of Au layers. Even as the Au thickness changes, the TMR remains positive as long as the number of Au layers is the same on both sides of the junction. Since the number of Au layers on Fe surfaces or Fe nanoparticles can now be experimentally controlled, amine-Au links provide a route towards robust TMR in organic spintronics. PMID:24060599

  15. Interface effects on tunneling magnetoresistance in organic spintronics with flexible amine–Au links

    International Nuclear Information System (INIS)

    Organic spintronics is a promising emerging field, but the sign of the tunneling magnetoresistance (TMR) is highly sensitive to interface effects, a crucial hindrance to applications. A key breakthrough in molecular electronics was the discovery of amine–Au link groups that give a reproducible conductance. Using first-principles calculations, we predict that amine–Au links give improved reproducibility in organic spintronics junctions with Au-covered Fe leads. The Au layers allow only states with sp character to tunnel into the molecule, and the flexibility of amine–Au links results in a narrow range of TMR for a fixed number of Au layers. Even as the Au thickness changes, the TMR remains positive as long as the number of Au layers is the same on both sides of the junction. Since the number of Au layers on Fe surfaces or Fe nanoparticles can now be experimentally controlled, amine–Au links provide a route towards robust TMR in organic spintronics. (paper)

  16. Application de la methode des sous-groupes au calcul Monte-Carlo multigroupe

    Science.gov (United States)

    Martin, Nicolas

    This thesis is dedicated to the development of a Monte Carlo neutron transport solver based on the subgroup (or multiband) method. In this formalism, cross sections for resonant isotopes are represented in the form of probability tables on the whole energy spectrum. This study is intended in order to test and validate this approach in lattice physics and criticality-safety applications. The probability table method seems promising since it introduces an alternative computational way between the legacy continuous-energy representation and the multigroup method. In the first case, the amount of data invoked in continuous-energy Monte Carlo calculations can be very important and tend to slow down the overall computational time. In addition, this model preserves the quality of the physical laws present in the ENDF format. Due to its cheap computational cost, the multigroup Monte Carlo way is usually at the basis of production codes in criticality-safety studies. However, the use of a multigroup representation of the cross sections implies a preliminary calculation to take into account self-shielding effects for resonant isotopes. This is generally performed by deterministic lattice codes relying on the collision probability method. Using cross-section probability tables on the whole energy range permits to directly take into account self-shielding effects and can be employed in both lattice physics and criticality-safety calculations. Several aspects have been thoroughly studied: (1) The consistent computation of probability tables with a energy grid comprising only 295 or 361 groups. The CALENDF moment approach conducted to probability tables suitable for a Monte Carlo code. (2) The combination of the probability table sampling for the energy variable with the delta-tracking rejection technique for the space variable, and its impact on the overall efficiency of the proposed Monte Carlo algorithm. (3) The derivation of a model for taking into account anisotropic

  17. Modular control of fusion power heating applications

    Energy Technology Data Exchange (ETDEWEB)

    Demers, D. R.

    2012-08-24

    This work is motivated by the growing demand for auxiliary heating on small and large machines worldwide. Numerous present and planned RF experiments (EBW, Lower Hybrid, ICRF, and ECH) are increasingly complex systems. The operational challenges are indicative of a need for components of real-time control that can be implemented with a moderate amount of effort in a time- and cost-effective fashion. Such a system will improve experimental efficiency, enhance experimental quality, and expedite technological advancements. The modular architecture of this control-suite serves multiple purposes. It facilitates construction on various scales from single to multiple controller systems. It enables expandability of control from basic to complex via the addition of modules with varying functionalities. It simplifies the control implementation process by reducing layers of software and electronic development. While conceived with fusion applications in mind, this suite has the potential to serve a broad range of scientific and industrial applications. During the Phase-I research effort we established the overall feasibility of this modular control-suite concept. We developed the fundamental modules needed to implement open-loop active-control and demonstrated their use on a microwave power deposition experiment.

  18. Modular control of fusion power heating applications

    International Nuclear Information System (INIS)

    This work is motivated by the growing demand for auxiliary heating on small and large machines worldwide. Numerous present and planned RF experiments (EBW, Lower Hybrid, ICRF, and ECH) are increasingly complex systems. The operational challenges are indicative of a need for components of real-time control that can be implemented with a moderate amount of effort in a time- and cost-effective fashion. Such a system will improve experimental efficiency, enhance experimental quality, and expedite technological advancements. The modular architecture of this control-suite serves multiple purposes. It facilitates construction on various scales from single to multiple controller systems. It enables expandability of control from basic to complex via the addition of modules with varying functionalities. It simplifies the control implementation process by reducing layers of software and electronic development. While conceived with fusion applications in mind, this suite has the potential to serve a broad range of scientific and industrial applications. During the Phase-I research effort we established the overall feasibility of this modular control-suite concept. We developed the fundamental modules needed to implement open-loop active-control and demonstrated their use on a microwave power deposition experiment

  19. Biosynthesis and stabilization of Au and Au-Ag alloy nanoparticles by fungus, Fusarium semitectum

    International Nuclear Information System (INIS)

    Crystallized and spherical-shaped Au and Au-Ag alloy nanoparticles have been synthesized and stabilized using a fungus, F . semitectum in an aqueous system. Aqueous solutions of chloroaurate ions for Au and chloroaurate and Ag+ ions (1 : 1 ratio) for Au-Ag alloy were treated with an extracellular filtrate of F . semitectum biomass for the formation of Au nanoparticles (AuNP) and Au-Ag alloy nanoparticles (Au-AgNP). Analysis of the feasibility of the biosynthesized nanoparticles and core-shell alloy nanoparticles from fungal strains is particularly significant. The resultant colloidal suspensions are highly stable for many weeks. The obtained Au and Au-Ag alloy nanoparticles were characterized by the surface plasmon resonance (SPR) peaks using a UV-vis spectrophotometer, and the structure, morphology and size were determined by Fourier transform infrared spectroscopy (FTIR), x-ray diffraction (XRD), and transmission electron microscopy (TEM). Possible optoelectronics and medical applications of these nanoparticles are envisaged.

  20. Optimal control applications in electric power systems

    CERN Document Server

    Christensen, G S; Soliman, S A

    1987-01-01

    Significant advances in the field of optimal control have been made over the past few decades. These advances have been well documented in numerous fine publications, and have motivated a number of innovations in electric power system engineering, but they have not yet been collected in book form. Our purpose in writing this book is to provide a description of some of the applications of optimal control techniques to practical power system problems. The book is designed for advanced undergraduate courses in electric power systems, as well as graduate courses in electrical engineering, applied mathematics, and industrial engineering. It is also intended as a self-study aid for practicing personnel involved in the planning and operation of electric power systems for utilities, manufacturers, and consulting and government regulatory agencies. The book consists of seven chapters. It begins with an introductory chapter that briefly reviews the history of optimal control and its power system applications and also p...

  1. Dynamic Surface Control and Its Application to Lateral Vehicle Control

    Directory of Open Access Journals (Sweden)

    Bongsob Song

    2014-01-01

    Full Text Available This paper extends the design and analysis methodology of dynamic surface control (DSC in Song and Hedrick, 2011, for a more general class of nonlinear systems. When rotational mechanical systems such as lateral vehicle control and robot control are considered for applications, sinusoidal functions are easily included in the equation of motions. If such a sinusoidal function is used as a forcing term for DSC, the stability analysis faces the difficulty due to highly nonlinear functions resulting from the low-pass filter dynamics. With modification of input variables to the filter dynamics, the burden of mathematical analysis can be reduced and stability conditions in linear matrix inequality form to guarantee the quadratic stability via DSC are derived for the given class of nonlinear systems. Finally, the proposed design and analysis approach are applied to lateral vehicle control for forward automated driving and backward parallel parking at a low speed as well as an illustrative example.

  2. Photoelectrochemical studies of DNA-tagged biomolecules on Au and Au/Ni/Au multilayer nanowires

    Directory of Open Access Journals (Sweden)

    Swaminathan Viswanathan

    2011-01-01

    Full Text Available Abstract The use of nanowires (NWs for labeling, sensing, and sorting is the basis of detecting biomolecules attached on NWs by optical and magnetic properties. In spite of many advantages, the use of biomolecules-attached NWs sensing by photoelectrochemical (PEC study is almost non-existent. In this article, the PEC study of dye-attached single-stranded DNA on Au NWs and Au-Ni-Au multilayer NWs prepared by pulse electrodeposition are investigated. Owing to quantum-quenching effect, the multilayer Au NWs exhibit low optical absorbance when compared with Au NWs. The tagged Au NWs show good fluorescence (emission at 570 nm, indicating significant improvement in the reflectivity. Optimum results obtained for tagged Au NWs attached on functionalized carbon electrodes and its PEC behavior is also presented. A twofold enhancement in photocurrent is observed with an average dark current of 10 μA for Au NWs coated on functionalized sensing electrode. The importance of these PEC and optical studies provides an inexpensive and facile processing platform for Au NWs that may be suitable for biolabeling applications.

  3. Facile fabrication of truncated octahedral Au nanoparticles and its application for ultrasensitive surface enhanced Raman scattering immunosensing

    International Nuclear Information System (INIS)

    Monodispersed truncated octahedral (TOH) Au nanoparticles (NPs) with an average edge-length of about 16 nm were synthesized using poly(diallyldimethylammonium chloride) (PDDA) both as a stabilizing and reducing agent via a one-step reaction. Remarkably, no seeds, surfactants or additional reductant were used in this reaction. In addition, the PDDA molecules on the surface of the TOH AuNPs make them convenient for use in layer-by-layer assembly by electrostatic interactions. Importantly, the TOH AuNPs show a significant surface enhanced Raman scattering (SERS) activity, and can be directly used for building SERS-active substrates and tags. Based on these promising properties, an ultrasensitive SERS-based immunosensing platform was developed. Using human immunoglobulin (h-IgG) as a model target analyte, a detection limit of 36.56 fg ml−1 was reached. (paper)

  4. Current limitation properties of YBa2Cu3O7-δ/Au thin films: application to transformer connection

    International Nuclear Information System (INIS)

    In view of the development of superconducting fault current limiters, the properties of switching and recovering of YBa2Cu3O7-δ/Au (YBCO/Au) thin films are studied at 77 K and 50 Hz for overcurrents. The bilayers present an abrupt transition to a high dissipative state leading to a current limitation at a maximum value of about 2.5 times the critical current Ic, and allow the development of electric fields of 3 kV m-1 without any damage. After the overcurrent regime, the recovery of the superconducting state under the rated current In is studied as a function of overcurrent parameters. These results show clearly the strong potential of YBCO/Au thin films which can recover their superconducting state under nominal mode. This last point is crucial for transformer connection, as experimentally shown in this paper

  5. Application of Cl2/BCl3/Ar Plasma Treatment in the Improvement of Ti/Al/Mo/Au Ohmic Contacts

    Directory of Open Access Journals (Sweden)

    Jacek Gryglewicz

    2016-01-01

    Full Text Available Significant improvement of Ti/Al/Mo/Au ohmic contacts deposited on previously Cl2/BCl3/Ar plasma treated surface was observed. The standard deviation of contact resistance was crucially reduced due to the incorporation of Cl2/BCl3/Ar plasma treatment. The Cl2:BCl3:Ar gas mixture was used in order to thin the top of AlGaN layer prior to deposition of Ti/Al/Mo/Au ohmic contacts. The surface morphology of AlGaN was investigated using scanning electron microscopy and atomic force microscopy. TLM measurements revealed a consequential decrease of contact resistivity.

  6. Intrathecal application of 198Au colloid in acute leukemia and non-Hodgkin's lymphoma in chilhood. 2

    International Nuclear Information System (INIS)

    7 children suffering from acute lymphatic leukemia (ALL) and non-Hodgkin's lymphoma, resp., were injected intrathecally with 198Au colloid for metaphylaxis. The children had been cured of 8 relapses of miningosis and received irregularly intrathecal injections of methotrexate for cerebral maintenance therapy. The median cerebral period of remission was 52 weeks. 1 child suffering from ALL had been free from meningosis relapses for 128 weeks. Continuous cytostatic therapy is necessary for methaphylaxis. However, despite of the good results presented, 198Au colloid can not be recommended for long-term therapy because radiation injuries are to be expected. (author)

  7. Voltage controlled spintronic devices for logic applications

    International Nuclear Information System (INIS)

    We consider logic device concepts based on our previously proposed spintronics device element whose magnetization orientation is controlled by application of a bias voltage instead of a magnetic field. The basic building block is the voltage-controlled rotation (VCR) element that consists of a four-layer structure--two ferromagnetic layers separated by both nanometer-thick insulator and metallic spacer layers. The interlayer exchange coupling between the two ferromagnetic layers oscillates as a function of applied voltage. We illustrate transistorlike concepts and reprogrammable logic gates based on VCR elements. (c) 2000 American Institute of Physics

  8. Fuzzy modeling and control theory and applications

    CERN Document Server

    Matía, Fernando; Jiménez, Emilio

    2014-01-01

    Much work on fuzzy control, covering research, development and applications, has been developed in Europe since the 90's. Nevertheless, the existing books in the field are compilations of articles without interconnection or logical structure or they express the personal point of view of the author. This book compiles the developments of researchers with demonstrated experience in the field of fuzzy control following a logic structure and a unified the style. The first chapters of the book are dedicated to the introduction of the main fuzzy logic techniques, where the following chapters focus o

  9. Applications of Circulation Control, Yesterday and Today

    Directory of Open Access Journals (Sweden)

    Jonathan Kweder

    2010-12-01

    Full Text Available Circulation control, an aerodynamic method of changing the properties of an airfoil, such as lift, camber and angle of attack, has been used in several unique ways since its inception, as an enhancement to fixed wing aircraft, in the 1960’s. Early in the research venture, this technology was used on the main wing of an aircraft in conjunction with a Coandă surface, such as a rounded trailing edge or a deployable flap. Research during this time proved to be the foundation of the circulation control technology and showed that small amounts of exit jet velocity could have a large impact on the aerodynamics of an airfoil. In the 1970’s the inspirations that drove circulation control research changed from design work to optimization of the parameters which were found to have the most effect on circulation control. These studies included slot placement, favorable momentum coefficient, and pressurization benefits and determents. This research period also allowed for expansion of the uses of circulation control to submarine/hydrodynamic and rotary wing applications. Newest research has brought on several propeller driven applications and the recent push for efficient renewable research has allowed circulation control research technologies to evolve into use in wind turbine and water turbine applications. The idea being that with circulation control the turbine can adapt easier to the changing wind velocity and direction and ultimately capture more power than an un-augmented turbine. As with most new and novel technologies there is a process and time delay associated with their development and ultimate application. For some technologies the market, or the supporting hardware, are lacking and sometimes the technology has strong advocacies for yet to be fulfilled expectations. In most of these cases a strong idea will re-surface repeatedly until the art has matured, or the better solution is found. This paper will focus on the previously developed

  10. Controlled functionalization of nanoparticles & practical applications

    Science.gov (United States)

    Rashwan, Khaled

    With the increasing use of nanoparticles in both science and industry, their chemical modification became a significant part of nanotechnology. Unfortunately, most commonly used procedures provide just randomly functionalized materials. The long-term objective of our work is site- and stoichiometrically-controlled functionalization of nanoparticles with the utilization of solid supports and other nanostructures. On the examples of silica nanoparticles and titanium dioxide nanorods, we have obtained results on the solid-phase chemistry, method development, and modeling, which advanced us toward this goal. At the same time, we explored several applications of nanoparticles that will benefit from the controlled functionalization: imaging of titanium-dioxide-based photocatalysts, bioimaging by fluorescent nanoparticles, drug delivery, assembling of bone implants, and dental compositions. Titanium dioxide-based catalysts are known for their catalytic activity and their application in solar energy utilization such as photosplitting of water. Functionalization of titanium dioxide is essential for enhancing bone-titanium dioxide nanotube adhesion, and, therefore, for its application as an interface between titanium implants and bones. Controlled functionalization of nanoparticles should enhance sensitivity and selectivity of nanoassemblies for imaging and drug delivery applications. Along those lines, we studied the relationship between morphology and surface chemistry of nanoparticles, and their affinity to organic molecules (salicylic and caffeic acid) using Langmuir adsorption isotherms, and toward material surfaces using SEM- and TEM-imaging. We focused on commercial samples of titanium dioxide, titanium dioxide nanorods with and without oleic acid ligands, and differently functionalized silica nanoparticles. My work included synthesis, functionalization, and characterization of several types of nanoparticles, exploring their application in imaging, dentistry, and bone

  11. Panic Control Treatment and Its Applications

    OpenAIRE

    Hofmann, Stefan G.; Spiegel, David A.

    1999-01-01

    Panic Control Treatment (PCT) is a widely used, empirically validated cognitive-behavioral treatment for panic disorder. Initially developed for the treatment of panic disorder with limited agoraphobic avoidance, PCT more recently has been finding broader applications. It has been used as an aid to pharmacotherapy discontinuation in panic disorder; in the treatment of panic attacks associated with other disorders such as schizophrenia; and, in combination with a situational exposure component...

  12. Comparison of some morphological and absorption properties of the nanoparticles Au/TiO2 embedded films prepared by different technologies on the substrates for application in the plasmonic solar cell

    International Nuclear Information System (INIS)

    The nanoparticle Au/TiO2 embedded system plays a very important role in the plasmonic solar cell. The features of the nanoparticle embedded system will determine light enhancement, light absorption, scattering and localized surface plasmon resonance (LSPR), aiming to enhance the efficiency of the plasmatic solar cell. The characterizations of nanoparticles Au/TiO2 embedded system consist of many parameters: the sizes of nanoparticles (Au, TiO2), the weight ratio of Au to TiO2, the thickness of the single layer or multilayer of Au/TiO2, the arrangements of Au and TiO2 nanoparticles in integrated-matrix system, the light absorption, scattering and LSPR capacities of the Au/TiO2 system. These parameters, however, depend on the technological conditions, the structure of plasmonic solar cell as well as the used substrate materials. This paper presents some technological developments for nanoparticles Au/TiO2 embedded systems by different methods, including the preparation of the mixer Au/TiO2 solutions and fabrication of the nanoparticle Au/TiO2 systems with different Au percentages on several substrates (glass/ITO and AAO(Al)/Si…), and measured results of the morphological, structural and optical properties using FESEM, EDX, UV–vis spectroscopy. The comparisons of experiment results between different technology conditions and substrates (glass/ITO, AAO(Al)/Si…) are also shown and discussed with the aim of choosing the suitable technological process and technological conditions for application in the plasmonic solar cell. (paper)

  13. Silver Nanopartical over AuFON Substrate for Enhanced Raman Readout and Their Application in Pesticide Monitoring

    Directory of Open Access Journals (Sweden)

    Kun Guo

    2015-04-01

    Full Text Available Surface-enhanced Raman detection of thiram is demonstrated by using Ag-nanoparticles (Ag NPs on Au film over nanosphere (AuFON substrate as the hybrid substrate. The SERS signal of the Ag NPs attached to solid supports is studied. The close coupling together of thousands of Ag NPs on AuFON leads to the generation of hot spots for SERS. The Ag NPs on AuFON can be applied to detect rhodamine-6G (R6G with the detection limitation of 10−11 M and the pesticide thiram in acetone with a detection limit of as low as 0.24 ppm, which is much lower than the maximal residue limit (MRL of 7 ppm in fruit prescribed by the U.S. Environmental Protection Agency (EPA. The hybrid substrates are shown to be highly sensitive for the detection of thriam, which produce highly enhanced Raman signals with good uniformity and reproducibility due to having plenty of hot spots on its surface.

  14. Fast and facile preparation of CTAB based gels and their applications in Au and Ag nanoparticles synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Upadhyay, Ravi Kant, E-mail: rkupadhyay85@gmail.com [Department of Chemistry, School of Natural Sciences, Shiv Nadar University, Gautam Budh Nagar, 201314 Uttar Pradesh (India); Soin, Navneet, E-mail: n.soin@bolton.ac.uk [Knowledge Centre for Materials Chemistry (KCMC), Institute for Materials Research and Innovation (IMRI), University of Bolton, Deane Road, Bolton BL3 5AB (United Kingdom); Saha, Susmita, E-mail: ssaha@bose.res.in [Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India); Barman, Anjan, E-mail: abarman@bose.res.in [Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India); Sinha Roy, Susanta, E-mail: susanta.roy@snu.edu.in [Department of Physics, School of Natural Sciences, Shiv Nadar University, Gautam Budh Nagar, 201314 Uttar Pradesh (India)

    2015-04-15

    We have demonstrated that the gel-like mesophase of Cetyltrimethylammonium bromide (CTAB) can be synthesized by judicial adjustment of water to surfactant molar ratio (W{sub 0}), without using any additional salts, gelating agents or co-surfactants. Gel formation was found to be highly dependent on the water to surfactant molar ratio (W{sub 0}), with the lowest value of W{sub 0} (41.5) resulting in rapid gel formation. Environmental scanning electron microscope (ESEM) analysis revealed that the gel was comprised of interconnected cylindrical structures. The presence of hydrogen bonding in the gel-like mesophase was confirmed by Fourier Transform Infrared spectroscopy (FTIR) analysis. Rheology measurements revealed that all the gel samples were highly viscoelastic in nature. Furthermore, Au and Ag containing CTAB gels were explored as precursors for the preparation of spherical Gold (Au) and Silver (Ag) nanoparticles using Sodium borohydride (NaBH{sub 4}) as reducing agent. The effects of NaBH{sub 4} concentration on the particle size and morphology of the Au and Ag nanoparticles have also been studied. - Highlights: • A facile synthesis of CTAB based gel-like mesophase is reported. • CTAB gels were obtained by adjusting water to surfactant molar ratio (W{sub 0}). • FTIR analysis revealed that hydrogen bonding plays a key role in gel formation. • Au, Ag nanoparticles were synthesized by using CTAB gel and NaBH{sub 4}.

  15. Fast and facile preparation of CTAB based gels and their applications in Au and Ag nanoparticles synthesis

    International Nuclear Information System (INIS)

    We have demonstrated that the gel-like mesophase of Cetyltrimethylammonium bromide (CTAB) can be synthesized by judicial adjustment of water to surfactant molar ratio (W0), without using any additional salts, gelating agents or co-surfactants. Gel formation was found to be highly dependent on the water to surfactant molar ratio (W0), with the lowest value of W0 (41.5) resulting in rapid gel formation. Environmental scanning electron microscope (ESEM) analysis revealed that the gel was comprised of interconnected cylindrical structures. The presence of hydrogen bonding in the gel-like mesophase was confirmed by Fourier Transform Infrared spectroscopy (FTIR) analysis. Rheology measurements revealed that all the gel samples were highly viscoelastic in nature. Furthermore, Au and Ag containing CTAB gels were explored as precursors for the preparation of spherical Gold (Au) and Silver (Ag) nanoparticles using Sodium borohydride (NaBH4) as reducing agent. The effects of NaBH4 concentration on the particle size and morphology of the Au and Ag nanoparticles have also been studied. - Highlights: • A facile synthesis of CTAB based gel-like mesophase is reported. • CTAB gels were obtained by adjusting water to surfactant molar ratio (W0). • FTIR analysis revealed that hydrogen bonding plays a key role in gel formation. • Au, Ag nanoparticles were synthesized by using CTAB gel and NaBH4

  16. Magnetic gold nanocatalyst (nanocat-Fe–Au): catalytic applications for the oxidative esterification and hydrogen transfer reactions

    Science.gov (United States)

    An efficient and sustainable protocol is described for the oxidative esterification of aldehydes and the reduction of aromatic nitro compounds that uses magnetically separable and reusable maghemite-supported gold nanocatalyst (nanocat-Fe-Au) under mild conditions. The complex ch...

  17. Robust and Adaptive Control With Aerospace Applications

    CERN Document Server

    Lavretsky, Eugene

    2013-01-01

    Robust and Adaptive Control shows the reader how to produce consistent and accurate controllers that operate in the presence of uncertainties and unforeseen events. Driven by aerospace applications the focus of the book is primarily on continuous-dynamical systems.  The text is a three-part treatment, beginning with robust and optimal linear control methods and moving on to a self-contained presentation of the design and analysis of model reference adaptive control (MRAC) for nonlinear uncertain dynamical systems. Recent extensions and modifications to MRAC design are included, as are guidelines for combining robust optimal and MRAC controllers. Features of the text include: ·         case studies that demonstrate the benefits of robust and adaptive control for piloted, autonomous and experimental aerial platforms; ·         detailed background material for each chapter to motivate theoretical developments; ·         realistic examples and simulation data illustrating key features ...

  18. A Fabrication Route for Arrays of Ultra-low-Noise MoAu Transition Edge Sensors on Thin Silicon Nitride for Space Applications

    CERN Document Server

    Glowacka, D M; Goldie, D J; Withington, S

    2014-01-01

    We describe a process route to fabricate arrays of Ultra-low-Noise MoAu Transition Edge Sensors (TESs). The low thermal conductance required for space applications is achieved using 200 nm-thick Silicon Nitride (SiNx ) patterned to form long-thin legs with widths of 2.1 {\\mu}m. Using bilayers formed on SiNx islands from films with 40 nm-thick Mo and Au thicknesses in the range 30 to 280 nm deposited by dc-sputtering in ultra-high vacuum we can obtain tunable transition temperatures in the range 700 to 70 mK. The sensors use large-area absorbers fabricated from high resistivity, thin-film beta-phase Ta to provide impedance-matching to incident radiation. The absorbers are patterned to reduce the heat capacity associated with the nitride support structure and include Au thermalizing features to assist the heat flow into the TES. Arrays of 400 detectors at the pixel spacing required for the long-wavelength band of the far-infrared instrument SAFARI are now being fabricated. Device yields approaching 99% are achi...

  19. PRATIQUES DE CONTROLE TOUT AU LONG DE LA RELATION DE FRANCHISE : UNE DOUBLE ENQUETE FRANCHISEUR-FRANCHISE

    OpenAIRE

    Goullet, Catherine

    2012-01-01

    Cette communication propose une étude du contrôle dans les réseaux de franchise de service tout au long de la relation franchiseurs-franchisés. A partir d'une étude exploratoire précédemment réalisée, un modèle de contrôle des réseaux de franchise a été proposé. Une recherche empirique de la dyade franchiseurs - franchisés présente une analyse descriptive du système de contrôle et des tests sur l'évolution de ces pratiques tout au cycle de vie de la relation. Les résultats montrent une évolut...

  20. Thin-films interdiffusion Ti/Pd/Au, Ti/Au/Pd

    International Nuclear Information System (INIS)

    Rutherford backscattering spectroscopy (RBS) is used to study the interdiffusion in Ti/Pd/Au and Ti/Au/Pd thin films system. The purpose of our study is to prepare an alloy of high resistance against corrosion, due to its important use in space industries, optical and visual receivers. In addition to another scientific results for future applications. Interdiffusion in the Ti/Pd/Au thin film system is measured using Rutherford backscattering. Interdiffusion rates of Pd/Au for temperatures between 200 and 490 centigrade degree have been correlated with the defect structure of the films. Air, as compared with vacuum, annealing enhances interdiffusion in the Ti/Au couple and inhibits interdiffusion in Ti/Pd, Ti/Pd and Ti/Au interdiffusion in the Ti/Pd/Au and Ti/Au/Pd ternary systems is strongly reduced in comparison with interdiffusion in the corresponding Ti/Pd or Ti/Au couples for vacuum annealing. (Author)

  1. Size-tunable Au nanoparticles on MoS2(0001)

    Science.gov (United States)

    Chu, Xinjun; Yao, Guanggeng; Thye Shen Wee, Andrew; Wang, Xue-Sen

    2012-09-01

    Ultra-fine Au nanoparticles (NPs) show great application potential in catalysis. Size-tunable Au NPs have been fabricated on MoS2 covered with monolayer 3,4,5,10-perylene tetracarboxylic dianhydride (PTCDA), and the morphological evolution as a function of Au deposition amount was investigated using scanning tunneling microscopy (STM). The PTCDA molecules act as a surfactant to stabilize ultra-fine Au NPs. Molecular scale STM images show that on MoS2 the Au NPs with PTCDA molecules on top can be formed with height and lateral size down to 1.3 nm and 3.5 nm, respectively. By controlling the deposition amount and annealing temperature, the size of Au NPs can be tuned. After annealing at 270 °C to remove PTCDA, Au NPs with a linear size ≤5 nm can be obtained on MoS2(0001), facilitating the characterization of their intrinsic physical and chemical properties using various analytical techniques. In addition, photoemission spectroscopy data reveal charge transfer from Au NPs to PTCDA, indicating that the NPs possess more reactive chemical properties than bulk Au.

  2. Size-tunable Au nanoparticles on MoS2(0001)

    International Nuclear Information System (INIS)

    Ultra-fine Au nanoparticles (NPs) show great application potential in catalysis. Size-tunable Au NPs have been fabricated on MoS2 covered with monolayer 3,4,5,10-perylene tetracarboxylic dianhydride (PTCDA), and the morphological evolution as a function of Au deposition amount was investigated using scanning tunneling microscopy (STM). The PTCDA molecules act as a surfactant to stabilize ultra-fine Au NPs. Molecular scale STM images show that on MoS2 the Au NPs with PTCDA molecules on top can be formed with height and lateral size down to 1.3 nm and 3.5 nm, respectively. By controlling the deposition amount and annealing temperature, the size of Au NPs can be tuned. After annealing at 270 °C to remove PTCDA, Au NPs with a linear size ≤5 nm can be obtained on MoS2(0001), facilitating the characterization of their intrinsic physical and chemical properties using various analytical techniques. In addition, photoemission spectroscopy data reveal charge transfer from Au NPs to PTCDA, indicating that the NPs possess more reactive chemical properties than bulk Au. (paper)

  3. A simple approach to the synthesis of eccentric Au@SiO2 Janus nanostructures and their catalytic applications

    Science.gov (United States)

    Zhao, Yang; Yang, Di; Hu, Huicheng; Chen, Lei; Xu, Yong; Qu, Lili; Yang, Peipei; Zhang, Qiao

    2016-06-01

    In this paper, we present a simple method to synthesize eccentric Au@SiO2 Janus nanoparticles. By simply tuning the concentration of poly(vinyl pyrrolidone) (PVP), the surface of gold nanoparticle can be partially or fully wrapped with the amphiphilic ligand. As a result, Janus nanoparticle or concentric core-shell nanostructures can be obtained, respectively. A systematic study has been carried out to confirm the function of PVP molecules. The as-prepared Janus nanoparticle can act as a catalyst to catalyze the reduction of 4-nitrophenol, while the core-shell nanostructure is not active due to the coverage of dense silica shell. This work provides a robust and scalable method to produce Au@SiO2 Janus nanoparticles.

  4. Intrathecal application of 198Au-colloid in children suffering from leukemia and non-Hodgkin's disease

    International Nuclear Information System (INIS)

    26 children suffering from acute leukemia and non-Hodgkin lymphoma (group 1) received intrathecal Au-198-colloid injections as a prophylactic measure against central nervous system (CNS) relapses. No primary CNS relapses were observed in the period from 1 Sep. 1974 to 31 Oct. 1978. Two children were taken ill at the same time with meningosis leucaemica in the first and second relapse, respectively. Four children (group 2) were treated with Au-198-colloid after overcoming a meningosis leucaemica. It was not possible to prevent another CNS relapse in all four patients of this group. Clinical status, liquor tests and EEG examinations carried out after the therapy showed good tolerance of the gold colloid. (author)

  5. Adsorption between TC-stabilized AuNPs and the phosphate group: application of the PTP1B activity assay.

    Science.gov (United States)

    Lv, Jun; Wang, Xiaonan; Zhang, Yuanyuan; Li, Defeng; Zhang, Juan; Sun, Lizhou

    2015-12-01

    Based on the adsorption between tetracycline (TC) and phosphate groups, a general colorimetric method is explored in this work by using TC-stabilized gold nanoparticles (TC/AuNPs) and 4-aminophenyl phosphate-functionalized Fe3O4 magnetic nanoparticles (APP/MNPs). Taking protein tyrosine phosphatase 1B (PTP1B) as an example, 4-aminophenyl phosphate (APP) can be hydrolyzed into 4-aminophenol (AP) by PTP1B, resulting in the disappearance of the phosphate group on the outer layer of MNPs and the loss of corresponding adsorptive ability. Upon addition of TC/AuNP solution, TC/AuNPs will remain in the supernatant solution after magnetic separation and a high absorbance value can be observed. So PTP1B activity is related to the concentrations of TC/AuNPs in the supernatant solution. In this work, the enzyme activity can be determined at levels as low as 0.0885 U mL(-1) and over a linear detection range as wide as 0.1 U mL(-1) to 0.9 U mL(-1). Moreover, using the proposed method, the inhibition effect of betulinic acid (BA) and sodium orthovanadate (Na3VO4) on PTP1B activity can be tested with IC50 values of 30 μM and 4 μM, respectively. Therefore, a universal platform for the accurate colorimetric analysis of kinase and phosphatase activities can be established through the adsorption between TC and phosphate groups. PMID:26523458

  6. Electronic Characterization of Au/DNA/ITO Metal-Semiconductor-Metal Diode and Its Application as a Radiation Sensor.

    Science.gov (United States)

    Al-Ta'ii, Hassan Maktuff Jaber; Periasamy, Vengadesh; Amin, Yusoff Mohd

    2016-01-01

    Deoxyribonucleic acid or DNA molecules expressed as double-stranded (DSS) negatively charged polymer plays a significant role in electronic states of metal/silicon semiconductor structures. Electrical parameters of an Au/DNA/ITO device prepared using self-assembly method was studied by using current-voltage (I-V) characteristic measurements under alpha bombardment at room temperature. The results were analyzed using conventional thermionic emission model, Cheung and Cheung's method and Norde's technique to estimate the barrier height, ideality factor, series resistance and Richardson constant of the Au/DNA/ITO structure. Besides demonstrating a strongly rectifying (diode) characteristic, it was also observed that orderly fluctuations occur in various electrical parameters of the Schottky structure. Increasing alpha radiation effectively influences the series resistance, while the barrier height, ideality factor and interface state density parameters respond linearly. Barrier height determined from I-V measurements were calculated at 0.7284 eV for non-radiated, increasing to about 0.7883 eV in 0.036 Gy showing an increase for all doses. We also demonstrate the hypersensitivity phenomena effect by studying the relationship between the series resistance for the three methods, the ideality factor and low-dose radiation. Based on the results, sensitive alpha particle detectors can be realized using Au/DNA/ITO Schottky junction sensor. PMID:26799703

  7. The graphene/Au/Ni interface and its application in the construction of a graphene spin filter

    International Nuclear Information System (INIS)

    A modification of the contact of graphene with ferromagnetic electrodes in a model of the graphene spin filter allowing restoration of the graphene electronic structure is proposed. It is suggested for this aim to intercalate into the interface between the graphene and the ferromagnetic (Ni or Co) electrode a Au monolayer to block the strong interaction between the graphene and Ni (Co) and, thus, prevent destruction of the graphene electronic structure which evolves in direct contact of graphene with Ni (Co). It is also suggested to insert an additional buffer graphene monolayer with the size limited by that of the electrode between the main graphene sheet providing spin current transport and the Au/Ni electrode injecting the spin current. This will prevent the spin transport properties of graphene from influencing contact phenomena and eliminate pinning of the graphene electronic structure relative to the Fermi level of the metal, thus ensuring efficient outflow of injected electrons into the graphene. The role of the spin structure of the graphene/Au/Ni interface with enhanced spin–orbit splitting of graphene π states is also discussed, and its use is proposed for additional spin selection in the process of the electron excitation. (paper)

  8. Simulation of Distributed Control Applications in Dynamic Environments (Simulatie van gedistribueerde controle applicaties in dynamische omgevingen)

    OpenAIRE

    Helleboogh, Alexander

    2007-01-01

    Distributed control applications are software systems designed to coordinate and control the operation of several distributed devices. An example of a distributed control application is a software system that controls production machines in a manufacturing environment. The environment in which a distributed control application operates is typically dynamic.In a dynamic environment the operating conditions of the control application are continuously changing. For example, in a manufacturing en...

  9. Heterojunction metal-oxide-metal Au-Fe3O4-Au single nanowire device for spintronics

    International Nuclear Information System (INIS)

    In this report, we present the synthesis of heterojunction magnetite nanowires in alumina template and describe magnetic and electrical properties from a single nanowire device for spintronics applications. Heterojunction Au-Fe-Au nanowire arrays were electrodeposited in porous aluminum oxide templates, and an extensive and controlled heat treatment process converted Fe segment to nanocrystalline cubic magnetite phase with well-defined Au-Fe3O4 interfaces as confirmed by the transmission electron microscopy. Magnetic measurements revealed Verwey transition shoulder around 120 K and a room temperature coercive field of 90 Oe. Current–voltage (I-V) characteristics of a single Au-Fe3O4-Au nanowire have exhibited Ohmic behavior. Anomalous positive magnetoresistance of about 0.5% is observed on a single nanowire, which is attributed to the high spin polarization in nanowire device with pure Fe3O4 phase and nanocontact barrier. This work demonstrates the ability to preserve the pristine Fe3O4 and well defined electrode contact metal (Au)–magnetite interface, which helps in attaining high spin polarized current

  10. Heterojunction metal-oxide-metal Au-Fe{sub 3}O{sub 4}-Au single nanowire device for spintronics

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, K. M., E-mail: mrkongara@boisestate.edu; Punnoose, Alex; Hanna, Charles [Department of Physics, Boise State University, Boise, Idaho 83725 (United States); Padture, Nitin P. [School of Engineering, Brown University, Providence, Rhode Island 02912 (United States)

    2015-05-07

    In this report, we present the synthesis of heterojunction magnetite nanowires in alumina template and describe magnetic and electrical properties from a single nanowire device for spintronics applications. Heterojunction Au-Fe-Au nanowire arrays were electrodeposited in porous aluminum oxide templates, and an extensive and controlled heat treatment process converted Fe segment to nanocrystalline cubic magnetite phase with well-defined Au-Fe{sub 3}O{sub 4} interfaces as confirmed by the transmission electron microscopy. Magnetic measurements revealed Verwey transition shoulder around 120 K and a room temperature coercive field of 90 Oe. Current–voltage (I-V) characteristics of a single Au-Fe{sub 3}O{sub 4}-Au nanowire have exhibited Ohmic behavior. Anomalous positive magnetoresistance of about 0.5% is observed on a single nanowire, which is attributed to the high spin polarization in nanowire device with pure Fe{sub 3}O{sub 4} phase and nanocontact barrier. This work demonstrates the ability to preserve the pristine Fe{sub 3}O{sub 4} and well defined electrode contact metal (Au)–magnetite interface, which helps in attaining high spin polarized current.

  11. Graphene nanoribbons synthesized from molecular precursor polymerization on Au(110)

    International Nuclear Information System (INIS)

    A spectroscopic study of 10,10-dibromo-9,9 bianthracene (DBBA) molecules deposited on the Au(110) surface is presented, by means of ultraviolet and X-ray photoemission, and X-ray absorption spectroscopy. Through a thermally activated procedure, these molecular precursors polymerize and eventually form graphene nanoribbons (GNRs) with atomically controlled shape and width, very important building blocks for several technological applications. The GNRs observed by scanning tunneling microscopy (STM) appear as short segments on top of the gold surface reconstruction, pointing out the delicate balance among surface diffusion and surface corrugation in their synthesis on the Au(110) surface

  12. Graphene nanoribbons synthesized from molecular precursor polymerization on Au(110)

    Energy Technology Data Exchange (ETDEWEB)

    Massimi, Lorenzo; Ourdjini, Oualid; Della Pia, Ada; Mariani, Carlo; Betti, Maria Grazia [Dipartimento di Fisica, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy); Cavaliere, Emanuele; Gavioli, Luca [i-LAMP & Dipartimento di Matematica e Fisica, Università Cattolica, 25121 Brescia (Italy)

    2015-06-23

    A spectroscopic study of 10,10-dibromo-9,9 bianthracene (DBBA) molecules deposited on the Au(110) surface is presented, by means of ultraviolet and X-ray photoemission, and X-ray absorption spectroscopy. Through a thermally activated procedure, these molecular precursors polymerize and eventually form graphene nanoribbons (GNRs) with atomically controlled shape and width, very important building blocks for several technological applications. The GNRs observed by scanning tunneling microscopy (STM) appear as short segments on top of the gold surface reconstruction, pointing out the delicate balance among surface diffusion and surface corrugation in their synthesis on the Au(110) surface.

  13. Reliable methods for silica coating of Au nanoparticles.

    Science.gov (United States)

    Pastoriza-Santos, Isabel; Liz-Marzán, Luis M

    2013-01-01

    The inherent properties of silica, such as optical transparency, high biocompatibility, chemical and colloidal stability, controllable porosity, and easy surface modification, provide silica materials with a tremendous potential in biomedicine. Therefore, the coating of Au nanoparticles with silica largely contributes to enhance the important applications of metal nanoparticles in biomedicine. We describe in this chapter a number of reliable strategies that have been reported for silica coating of different types of Au nanoparticles. All descriptions are based on tested protocols and are expected to provide a reference for scientists with an interest in this field. PMID:23918330

  14. Introduction au droit commercial

    OpenAIRE

    Thirion, Nicolas; Delvaux, Thierry; Benoit-Moury, Anne

    2009-01-01

    Le cours d'introduction au droit commercial, destiné à des non-juristes, a pour objet de décrire, dans ses grandes lignes, le régime juridique applicable à l'organisation et au fonctionnement de l'économie. Les liens avec des disciplines autres que le droit, notamment l'économie et l'histoire, seront privilégiés, afin d'adapter la matière aux besoins et centres d'intérêts d'étudiants en sciences humaines. Après une introduction générale, le cours s'articule autour de la trilogie fondamentale ...

  15. Pt@AuNPs integrated quantitative capillary-based biosensors for point-of-care testing application.

    Science.gov (United States)

    Wu, Ze; Fu, Qiangqiang; Yu, Shiting; Sheng, Liangrong; Xu, Meng; Yao, Cuize; Xiao, Wei; Li, Xiuqing; Tang, Yong

    2016-11-15

    Current diagnostic technologies primarily rely on bulky and costly analytical instruments. Therefore, cost-effective and portable diagnosis tools that can be used for point-of-care tests (POCT) are highly desirable. In this study, we report a cost-effective, portable capillary-based biosensor for quantitative detection of biomarkers by the naked eye. This capillary-based biosensor was tested by measuring the distance of blue ink movement, which was directly correlated with the oxygen (O2) produced by efficient core-shell Pt@Au nanoparticles (Pt@AuNPs) catalysts decomposed hydrogen peroxide (H2O2). By linking the Pt@AuNPs with antibodies, capillary-based biosensor sandwich immunoassays were constructed. The concentrations of the target proteins were positively correlated with the distances of ink movement. To demonstrate their performance, the biosensors were used to detect the cancer biomarker sprostate-specific antigen (PSA) and carcinoembryonic antigen (CEA). The linear detection range (LDR) of the capillary-based biosensor for detecting PSA was from 0.02 to 2.5ng/mL, and the limit of detection (LOD) was 0.017ng/mL. LDR of the biosensor for detecting CEA was from 0.063 to 16ng/mL, and the LOD was 0.044ng/mL. For detection of PSA and CEA in clinical serum samples, the detection results of the capillary-based biosensor were well correlate with the results from of chemiluminescence immunoassays (CLIAs). Thus, the capillary-based biosensor may potentially be a useful strategy for point-of-care testing, in addition to being portable and cost effective. PMID:27240013

  16. Algorithmes Heuristiques et Techniques d'Apprentissage : Applications au Problème de Coloration de Graphe

    OpenAIRE

    Porumbel, Daniel Cosmin

    2009-01-01

    Au cours des trois dernières décennies, les algorithmes heuristiques ont permis de réaliser des progrès remarquables dans la résolution des problèmes difficiles d'optimisation combinatoire. Cependant, la conception de ces algorithmes relève encore plusieurs challenges importants - en particulier, il semble qu'il est toujours difficile d'intégrer dans une heuristique une vue d'ensemble sur l'évolution de la recherche ou sur sa trajectoire. Prenant comme cadre expérimental le problème bien conn...

  17. Application of control theory to dynamic systems simulation

    Science.gov (United States)

    Auslander, D. M.; Spear, R. C.; Young, G. E.

    1982-01-01

    The application of control theory is applied to dynamic systems simulation. Theory and methodology applicable to controlled ecological life support systems are considered. Spatial effects on system stability, design of control systems with uncertain parameters, and an interactive computing language (PARASOL-II) designed for dynamic system simulation, report quality graphics, data acquisition, and simple real time control are discussed.

  18. Supercomputer optimizations for stochastic optimal control applications

    Science.gov (United States)

    Chung, Siu-Leung; Hanson, Floyd B.; Xu, Huihuang

    1991-01-01

    Supercomputer optimizations for a computational method of solving stochastic, multibody, dynamic programming problems are presented. The computational method is valid for a general class of optimal control problems that are nonlinear, multibody dynamical systems, perturbed by general Markov noise in continuous time, i.e., nonsmooth Gaussian as well as jump Poisson random white noise. Optimization techniques for vector multiprocessors or vectorizing supercomputers include advanced data structures, loop restructuring, loop collapsing, blocking, and compiler directives. These advanced computing techniques and superconducting hardware help alleviate Bellman's curse of dimensionality in dynamic programming computations, by permitting the solution of large multibody problems. Possible applications include lumped flight dynamics models for uncertain environments, such as large scale and background random aerospace fluctuations.

  19. Various applications of Active Field Control (AFC)

    Science.gov (United States)

    Watanabe, Takayuki; Miyazaki, Hideo; Kishinaga, Shinji; Kawakami, Fukushi

    2003-10-01

    AFC is an electro-acoustic enhancement system, which has been under development at Yamaha Corporation. In this paper, several types of various AFC applications are discussed, while referring to representative projects for each application in Japan. (1) Realization of acoustics in a huge hall to classical music program, e.g., Tokyo International Forum. This venue is a multipurpose hall with approximately 5000 seats. AFC achieves loudness and reverberance equivalent to those of a hall with 2500 seats or fewer. (2) Optimization of acoustics for a variety of programs, e.g., Arkas Sasebo. AFC is used to create the optimum acoustics for each program, such as reverberance for classical concerts, acoustical support for opera singers, uniformity throughout the hall from the stage to under-balcony area, etc. (3) Control of room shape acoustical effect, e.g., Osaka Central Public Hall: In this renovation project, preservation of historically important architecture in the original form is required. AFC is installed to vary only the acoustical environment without architectural changes. (4) Assistance with crowd enthusiasm for sports entertainment, e.g., Tokyo Metropolitan Gymnasium. In this venue, which is designed as a very absorptive space for speech intelligibility, AFC is installed to enhance the atmosphere of live sports entertainment.

  20. Computer applications in controlled fusion research

    International Nuclear Information System (INIS)

    The application of computers to controlled thermonuclear research (CTR) is essential. In the near future the use of computers in the numerical modeling of fusion systems should increase substantially. A recent panel has identified five categories of computational models to study the physics of magnetically confined plasmas. A comparable number of types of models for engineering studies is called for. The development and application of computer codes to implement these models is a vital step in reaching the goal of fusion power. To meet the needs of the fusion program the National CTR Computer Center has been established at the Lawrence Livermore Laboratory. A large central computing facility is linked to smaller computing centers at each of the major CTR Laboratories by a communication network. The crucial element needed for success is trained personnel. The number of people with knowledge of plasma science and engineering trained in numerical methods and computer science must be increased substantially in the next few years. Nuclear engineering departments should encourage students to enter this field and provide the necessary courses and research programs in fusion computing

  1. Magnetic, optical and relaxometric properties of organically coated gold-magnetite (Au-Fe{sub 3}O{sub 4}) hybrid nanoparticles for potential use in biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    Umut, E., E-mail: eumut@hacettepe.edu.tr [Hacettepe University Physics Engineering Department, 06800 Beytepe-Ankara (Turkey); Pineider, F. [INSTM and Universita degli Studi di Firenze, Department of Chemistry, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy); CNR-ISTM Padova, 35131 Padova (Italy); Arosio, P. [INSTM and Universita degli Studi di Milano, Department of Molecular Sciences Applied to Biosystems (DISMAB), I-20134 Milano (Italy); Sangregorio, C. [INSTM and Universita degli Studi di Firenze, Department of Chemistry, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy); CNR-ISTM Milano, 50123 via C.Golgi 19, 20133 Milano (Italy); Corti, M. [INSTM, CNISM and Dipartimento di Fisica ' A.Volta' , Univ. di Pavia, Via Bassi 6, I-27100 Pavia (Italy); Tabak, F. [Hacettepe University Physics Engineering Department, 06800 Beytepe-Ankara (Turkey); Lascialfari, A. [INSTM and Universita degli Studi di Milano, Department of Molecular Sciences Applied to Biosystems (DISMAB), I-20134 Milano (Italy); INSTM, CNISM and Dipartimento di Fisica ' A.Volta' , Univ. di Pavia, Via Bassi 6, I-27100 Pavia (Italy); Ghigna, P. [INSTM and Dipartimento di Chimica Univ. di Pavia, v.le Taramelli 13, I-27100 Pavia (Italy)

    2012-08-15

    We present the magnetic, optical and relaxometric properties of multifunctional Au-Fe{sub 3}O{sub 4} hybrid nanoparticles (HNPs), as possible novel contrast agents (CAs) for magnetic resonance imaging (MRI). The HNPs have been synthesized by wet chemical methods in heterodimer and core-shell geometries and capped with oleylamine. Structural characterization of the samples have been made by X-ray diffraction and transmission electron microscopy, while magnetic properties have been investigated by means of Superconducting Quantum Interference Device-SQUID magnetometry experiments. As required for MRI applications using negative CAs, the samples resulted superparamagnetic at room temperature and well above their blocking temperatures. Optical properties have been investigated by analyzing the optical absorbtion spectra collected in UV-visible region. Relaxometric measurements have been performed on organic suspensions of HNPs and Nuclear Magnetic Resonance (NMR) dispersion curves have been obtained by measuring the longitudinal 1/T{sub 1} and transverse 1/T{sub 2} relaxation rates of solvent protons in the range 10 kHz/300 MHz at room temperature. NMR relaxivities r{sub 1} and r{sub 2} have been compared with ENDOREM{sup Registered-Sign }, one of the commercial superparamagnetic iron oxide based MRI contrast agents. MRI contrast enhancement efficiencies have been investigated also by examining T{sub 2}-weighted MR images of suspensions. The experimental results suggest that the nanoparticles' suspensions are good candidates as negative CAs. - Highlights: Black-Right-Pointing-Pointer Au-Fe{sub 3}O{sub 4} superparamagnetic Hybrid NanoPrticles (HNPs) enhance contrast in MRI. Black-Right-Pointing-Pointer HNPs are expected to have optical activities through observed SPR phenomena. Black-Right-Pointing-Pointer HNPs have relatively high magnetic anisotropy originating from Au/Fe{sub 3}O{sub 4} interface. Black-Right-Pointing-Pointer Magnetic dipolar interactions have

  2. Control of domain wall pinning by localised focused Ga + ion irradiation on Au capped NiFe nanowires

    International Nuclear Information System (INIS)

    Understanding domain wall pinning and propagation in nanowires are important for future spintronics and nanoparticle manipulation technologies. Here, the effects of microscopic local modification of the magnetic properties, induced by focused-ion-beam intermixing, in NiFe/Au bilayer nanowires on the pinning behavior of domain walls was investigated. The effects of irradiation dose and the length of the irradiated features were investigated experimentally. The results are considered in the context of detailed quasi-static micromagnetic simulations, where the ion-induced modification was represented as a local reduction of the saturation magnetization. Simulations show that domain wall pinning behavior depends on the magnitude of the magnetization change, the length of the modified region, and the domain wall structure. Comparative analysis indicates that reduced saturation magnetisation is not solely responsible for the experimentally observed pinning behavior.

  3. Application of Au-Sn eutectic bonding in hermetic radio-frequency microelectromechanical system wafer level packaging

    Science.gov (United States)

    Wang, Qian; Choa, Sung-Hoon; Kim, Woonbae; Hwang, Junsik; Ham, Sukjin; Moon, Changyoul

    2006-03-01

    Development of packaging is one of the critical issues toward realizing commercialization of radio-frequency-microelectromechanical system (RF-MEMS) devices. The RF-MEMS package should be designed to have small size, hermetic protection, good RF performance, and high reliability. In addition, packaging should be conducted at sufficiently low temperature. In this paper, a low-temperature hermetic wafer level packaging scheme for the RF-MEMS devices is presented. For hermetic sealing, Au-Sn eutectic bonding technology at temperatures below 300°C is used. Au-Sn multilayer metallization with a square loop of 70 µm in width is performed. The electrical feed-through is achieved by the vertical through-hole via filling with electroplated Cu. The size of the MEMS package is 1 mm × 1 mm × 700 µm. The shear strength and hermeticity of the package satisfies the requirements of MIL-STD-883F. Any organic gases or contamination are not observed inside the package. The total insertion loss for the packaging is 0.075 dB at 2 GHz. Furthermore, the robustness of the package is demonstrated by observing no performance degradation and physical damage of the package after several reliability tests.

  4. IDCDACS: IDC's Distributed Application Control System

    Science.gov (United States)

    Ertl, Martin; Boresch, Alexander; Kianička, Ján; Sudakov, Alexander; Tomuta, Elena

    2015-04-01

    The Preparatory Commission for the CTBTO is an international organization based in Vienna, Austria. Its mission is to establish a global verification regime to monitor compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT), which bans all nuclear explosions. For this purpose time series data from a global network of seismic, hydro-acoustic and infrasound (SHI) sensors are transmitted to the International Data Centre (IDC) in Vienna in near-real-time, where it is processed to locate events that may be nuclear explosions. We newly designed the distributed application control system that glues together the various components of the automatic waveform data processing system at the IDC (IDCDACS). Our highly-scalable solution preserves the existing architecture of the IDC processing system that proved successful over many years of operational use, but replaces proprietary components with open-source solutions and custom developed software. Existing code was refactored and extended to obtain a reusable software framework that is flexibly adaptable to different types of processing workflows. Automatic data processing is organized in series of self-contained processing steps, each series being referred to as a processing pipeline. Pipelines process data by time intervals, i.e. the time-series data received from monitoring stations is organized in segments based on the time when the data was recorded. So-called data monitor applications queue the data for processing in each pipeline based on specific conditions, e.g. data availability, elapsed time or completion states of preceding processing pipelines. IDCDACS consists of a configurable number of distributed monitoring and controlling processes, a message broker and a relational database. All processes communicate through message queues hosted on the message broker. Persistent state information is stored in the database. A configurable processing controller instantiates and monitors all data processing

  5. Application of X-ray photoelectron spectroscopy to characterization of Au nanoparticles formed by ion implantation into SiO2

    International Nuclear Information System (INIS)

    In X-ray photoelectron spectroscopy (XPS) of Au nanoparticles, the width of 5d valence band changes with Au particle size. This enables us to estimate the size of Au nanoparticles by using XPS. In this work, the 5d-band width has been measured for Au nanoparticles formed by ion implantation into SiO2. The 5d-band width is found to be correlated strongly with the Au concentration. As the Au concentration increases, the 5d-band width becomes larger, indicating that the Au nanoparticles with the larger size tend to be formed in the vicinity of the projected range of Au ions. This correlation agrees very well with the results from transmission electron microscopy.

  6. Au nanorings for enhancing absorption and backscattering monitored with optical coherence tomography

    Energy Technology Data Exchange (ETDEWEB)

    Tseng, Hung-Yu; Lee, Cheng-Kuang; Wu, Shou-Yen; Chi, Ting-Ta; Yang, Kai-Min; Wang, Jyh-Yang; Kiang, Yean-Woei; Yang, C C [Institute of Photonics and Optoelectronics, and Department of Electrical Engineering, National Taiwan University, No 1, Section 4, Roosevelt Road, Taipei 10617, Taiwan, Republic of China (China); Tsai, Meng-Tsan [Department of Electrical Engineering, Chang Gung University, No 259 Wen-Hwa 1st Road, Kwei-Shan, Tao-Yuan, 33302 Taiwan (China); Wu, Yang-Che [Graduate Institute of Clinical Dentistry, School of Dentistry, National Taiwan University, No 1 Changde St, Taipei, 10002 Taiwan (China); Chou, Han-Yi E; Chiang, Chun-Pin, E-mail: ywkiang@ntu.edu.tw, E-mail: ccy@cc.ee.ntu.edu.tw [Graduate Institute of Oral Biology, School of Dentistry, National Taiwan University, No 1 Changde St, Taipei, 10002 Taiwan (China)

    2010-07-23

    Preparation of a high-concentration Au nanoring (NR) water solution and its applications to the enhancement of image contrast in optical coherence tomography (OCT) and the generation of the photothermal effect in a bio-sample through localized surface plasmon (LSP) resonance are demonstrated. Au NRs are first fabricated on a sapphire substrate with colloidal lithography and secondary sputtering of Au, and then transferred into a water solution through a liftoff process. By controlling the NR geometry, the LSP dipole resonance wavelength in tissue can cover a spectral range of 1300 nm for OCT scanning of deep tissue penetration. The extinction cross sections of the fabricated Au NRs in water are estimated to give levels of 10{sup -10}-10{sup -9} cm{sup 2} near their LSP resonance wavelengths. The fabricated Au NRs are then delivered into pig adipose samples for OCT scanning. It is observed that, when resonant Au NRs are delivered into such a sample, LSP resonance-induced Au NR absorption results in a photothermal effect, making the opaque pig adipose cells transparent. Also, the delivered Au NRs in the intercellular substance enhance the image contrast of OCT scanning through LSP resonance-enhanced scattering. By continuously OCT scanning a sample, both photothermal and image contrast enhancement effects are observed. However, by continually scanning a sample with a low scan frequency, only the image contrast enhancement effect is observed.

  7. Controlled deposition or organic semiconductor single crystals and its application in field-effect transistors

    Science.gov (United States)

    Liu, Shuhong

    The search for low-cost, large area, flexible devices has led to a remarkable increase in the research and development of organic semiconductors. Single-crystal organic field-effect transistors (OFETs) are ideal device structures for studying fundamental science associated with charge transport in organic materials and have demonstrated high mobility and outstanding electrical characteristics. For example, an exceptionally high carrier mobility of 20 cm2/Vs has been demonstrated for rubrene single crystal field effect transistors. However, it remains a technical challenge to integrate single-crystal devices into practical electronic applications. A key difficulty is that organic single-crystal devices are usually fabricated one device at a time by handpicking a single crystal and placing it onto the device substrate. This makes it impossible to mass-produce at high density with reasonable throughput. Therefore, there is a great need for a high-throughput method for depositing large arrays of organic semiconductor single crystals directly onto device structures. In this dissertation, I develop several approaches towards realizing this goal. The first approach is a solution-processing technique, which relies on solvent wetting and de-wetting on substrates with patterned wettability to selectively direct the deposition or removal of organic crystals. The assembly of different organic crystals over centimeter-squared areas on Au, SiO 2 and flexible plastic substrates is demonstrated. By designing line features on the substrate, alignment of needle-like crystals is also achieved. As a demonstration of the potential application of this approach, arrays of organic single crystal FETs are fabricated by patterning organic single crystals directly onto and between transistor source and drain electrodes. Besides organic single crystals, this self-assembly strategy is also applicable for patterning other objects such as metallic nanowires. In the second technique, organic

  8. Thermohydraulique des écoulements d'hélium faiblement supercritique en conduite application au refroidissement des écrans de faisceau du LHC

    CERN Document Server

    Hatchadourian, E

    2000-01-01

    Au cours d'observations, au-delà de la mise en évidence d'un effet inattendu, l'effort de compréhension porte tout d'abord vers une description qualitative du phénomène et ensuite quantitative. Puis, lorsque ce phénomène est compris, le travail peut s'orienter vers une étape d'exploitation o le mécanisme est utilisé pour développer de nouvelles voies de recherche ou encore apporter des solutions à des besoins d'ordre technologique. L'étude établie sur le projet du futur collisionneur de particules du CERN en est un exemple convaincant : il s'agit dans un premier temps de définir un modèle simplifié sur l'écoulement d'hélium supercritique dans des tubes soumis à des apports de chaleur, afin de permettre la compréhension des mécanismes essentiels puis developper un modèle plus précis, mais également plus complet, pour l'étude quantitative. L'application directe de cette étude thermohydraulique concerne le refroidissement des écrans de faisceau du LHC. Ces écrans, maintenus à une te...

  9. Magnetic force control technique in industrial application

    International Nuclear Information System (INIS)

    Techniques of the magnetic force control have been examined for industrial application. The problems and the technique are different in dispersion medium of gas and that of liquid. In addition, the method is different depending on the magnetic characteristic of the target objects. In case of the liquid, the dispersion medium having different viscosity was examined. The separation speed is decided with the magnitude of the magnetic force because a drag force increases with the viscosity. When the water is the dispersion medium, magnetic seeding is possible and hence the nonmagnetic materials can be separated and even the dissolved material could be separated. The separation technique has been used for purifying the waste water form paper mill or wash water of drum. On the other hand when the water is not dispersion medium, mainly the ferromagnetism particle becomes the target object because the magnetic seeding becomes difficult. The iron fragments have been separated from the slurry of slicing machine of solar battery. It has been clarified high gradient magnetic separation (HGMS) can be applied for the viscous fluid of which viscosity was as high as 10 Pa s. When the dispersion medium is gaseous material, the air is important. The drag force from air depends greatly on Reynolds number. When speed of the air is small, the Reynolds number is small, and the drag force is calculated by the Stokes' law of resistance. The study with gaseous dispersion medium is not carried out much. The magnetic separation will discuss the possibility of the industrial application of this technique.

  10. Applications of super elasticity in vibrational control

    International Nuclear Information System (INIS)

    In this work, the possibilities of using shape memory alloys (SMA) as passive dampers devices in mechanicals vibrations problems are studied.The property that is exploited is the super elastic effect, by wich strains of the order of 10% can be obtained.The relationship between stress and strain means that this is an inelastic process.Nevertheless when load is removed the material recoveries its original dimension, presenting zero or almost zero permanent strain relative to others common materials, describing in its stress-strain diagram an important hysteretic loop.This features occurs basically because in well suited conditions the SMA can undergo martensitic transformations induced by stress.A series of uniaxial tension tests in commercial NiTi wires are performed, in order to characterize the super elastic behavior of the material.The influence of variables as ambient temperature, strain rate, strain levels and number of tension cycles accumulated are studied paying attention to the dissipative capacity of the material defined by means of the shape of the hysteretic loop.The influence on the damping capacity of the thermal effects associated with the martensitic transformation are evaluated by performing experiments at different transformation rates.Results are rationalized in terms of a model considering the interaction between a source term (heat of transformation), heat convection to the ambient and conduction along the wire.Some numerical results are obtained and discussed. For a performance evaluation in devices applications a simplified model of super elasticity is proposed.Then, the response of an elastic frame structure endowed with SMA tensors is evaluated following the model behavior when seismic movement is imposed at the base.The obtained results verify the possibility of using SMA as kernel elements in vibration control.This conclusion is experimentally verified in a prototype of the structure specially designed and constructed for this work

  11. Spectral Matrix Filtering Applied to Vsp Processing Application du filtrage matriciel au traitement des profils sismiques verticaux

    Directory of Open Access Journals (Sweden)

    Glangeaud F.

    2006-11-01

    données et de séparer ces signaux. Nous montrons que les signaux peuvent être automatiquement séparés sans connaissance a priori sur leurs vitesses apparentes, en fonction du produit scalaire (calculé dans le domaine fréquentiel et de l'amplitude relative des signaux. Nous montrons des exemples d'application sur des données de sismique de puits. Le filtrage matriciel est effectué dans le domaine fréquentiel en utilisant la matrice spectrale construite à l'aide des intercorrélations des différents enregistrements constituant les données à traiter. Les méthodes d'estimation de la matrice spectrale sont des méthodes de moyenne : moyenne en fréquence (méthode du périodogramme lissé et/ou moyenne en distance (lissage réalisé le long des diagonales de la matrice spectrale. Le lissage en fréquence est obtenu par l'intermédiaire d'une fonction de pondération (par exemple fenêtre de Hanning élevée à une puissance donnée appliquée à chaque corrélation. Les moyennes sont utilisées pour décorréler les signaux et de ce fait favoriser la séparation. Une fois correctement estimée, la matrice spectrale est diagonalisée sur toutes les fréquences du spectre moyenné, et décomposée selon ses vecteurs propres qui sont orthogonaux entre eux et normalisés. Chaque vecteur propre a une valeur propre associée qui représente la répartition d'énergie en fonction de la fréquence du modèle lié au vecteur propre. Le filtrage est réalisé par projection des données sur les différents vecteurs propres issus de la matrice spectrale. Il est à noter cependant que la séparation des différents signaux (projection sur vecteur propre n'est réalisée en terme d'indicatrice sismique que si les événements sismiques sont naturellement orthogonaux et alignés sur les vecteurs propres. Glangeaud et al (1989 ont étudié l'influence des amplitudes relatives et du produit scalaire de deux ondes. Si la vitesse apparente d'une onde est connue, cette derni

  12. Application of H∞ control theory to PWR power control

    International Nuclear Information System (INIS)

    In this paper, a robust controller is designed by the use of H∞ control theory for the PWR power control. The design specification is incorporated by the frequency weights using the mixed-sensitivity problem. The robustness of H∞ control is verified by comparing with the classical output feedback control and LQG control in the case of measurement delay of the power measurement system. The H∞ optimal control shows excellent stability-robustness and performance-robustness for external disturbances and noises, model parameter variations, and modeling errors. It also provides a practical design method because the design specification can be easily implemented

  13. PWM Rectifier Control Comparison for Aerospace Applications

    OpenAIRE

    R. Todd, K. Liu, Y. Lau

    2014-01-01

    High-voltage DC-bus power quality is examined when the power network is supplied by a PWM rectifier controlled using different DC-bus voltage regulation schemes. Three controllers are compared, a voltage oriented control and two model predictive control schemes, predictive current fixed frequency and predictive direct power control. A set of PWM rectifier simulation models illustrate the performance of the controllers; a switched model, an ideal averaged-value model and an enhanced averaged-v...

  14. Repérage et typage d'expressions temporelles pour l'annotation sémantique automatique de pages Web - Application au e-tourisme

    OpenAIRE

    Weiser, Stéphanie

    2010-01-01

    Cette thèse présente Adetoa, système dédié au repérage et à l'annotation sémantique automatique d'expressions temporelles dans des pages Web pour une application de e-tourisme. Une étude linguistique détaillée a permis de mettre en avant les caractéristiques et la complexité de l'expression de la temporalité dans les pages Web touristiques. Une étude sémiotique de ce type de pages a montré que les données y étaient organisées de manière fort variée, ne présentant aucune régularité, ce qui ren...

  15. Application of dimensional analysis in systems modeling and control design

    CERN Document Server

    Balaguer, Pedro

    2013-01-01

    Dimensional analysis is an engineering tool that is widely applied to numerous engineering problems, but has only recently been applied to control theory and problems such as identification and model reduction, robust control, adaptive control, and PID control. Application of Dimensional Analysis in Systems Modeling and Control Design provides an introduction to the fundamentals of dimensional analysis for control engineers, and shows how they can exploit the benefits of the technique to theoretical and practical control problems.

  16. Programming a real-time operating system for satellite control applications Satellite Control Applications

    International Nuclear Information System (INIS)

    With the realization of ideas like formation flights and multi-body space vehicles the demands on an attitude control system have become increasingly complex. Even in its most simplified form, the control system for a typical geostationary satellite has to run various supervisory functions along with determination and control algorithms side by side. Within each algorithm it has to employ multiple actuation and sensing mechanisms and service real time interrupts, for example, in the case of actuator saturation and sensor data fusion. This entails the idea of thread scheduling and program synchronization, tasks specifically meant for a real time OS. This paper explores the embedding of attitude determination and control loop within the framework of a real time operating system provided for TI's DSP C6xxx series. The paper details out the much functionality provided within the scaleable real time kernel and the analysis and configuration tools available, It goes on to describe a layered implementation stack associated with a typical control for Geo Stationary satellites. An application for control is then presented in which state of the art analysis tools are employed to view program threads, synchronization semaphores, hardware interrupts and data exchange pipes operating in real time. (author)

  17. Application Framework for Programmable Network Control

    NARCIS (Netherlands)

    Strijkers, R.J.; Cristea, R.M.; Laat, C. de; Meijer, R.J.

    2011-01-01

    We present a framework that enables application developers to create complex and application specific network services. The essence of our approach is to utilize programmable network elements to create a software representation of network elements in the application. We show that the typical pattern

  18. Applicator Training Manual for: Aquatic Weed Control.

    Science.gov (United States)

    Herron, James W.

    The aquatic weeds discussed in this manual include algae, floating weeds, emersed weeds, and submerged weeds. Specific requirements for pesticide application are given for static water, limited flow, and moving water situations. Secondary effects of improper application rates and faulty application are described. Finally, techniques of limited…

  19. Fuzzy Logic Controller for Low Temperature Application

    Science.gov (United States)

    Hahn, Inseob; Gonzalez, A.; Barmatz, M.

    1996-01-01

    The most common temperature controller used in low temperature experiments is the proportional-integral-derivative (PID) controller due to its simplicity and robustness. However, the performance of temperature regulation using the PID controller depends on initial parameter setup, which often requires operator's expert knowledge on the system. In this paper, we present a computer-assisted temperature controller based on the well known.

  20. Application of Improved Fuzzy Controller in Networked Control System

    Institute of Scientific and Technical Information of China (English)

    ZHANG Qian; GUO Xi-jin; WANG Zhen; TIAN Xi-lan

    2006-01-01

    Aiming at the problem of network-induced delay and data dropout in networked control system, an improved fuzzy controller is proposed in this paper. Considering the great influence of a controller on the performance of control system, an improved controller with a second order fuzzy controller and network-induced delay compensator being added to the basic fuzzy controller is proposed to realize self-regulation on-line. For this type of controller, neither plant model nor measurement of network delay is required. So it is capable of automatically adjusting quantified factor, proportional factor, and integral factor according to the control system error and its derivative. The design makes full use of the advantages of quickness in operation and reduction of steady state error because of its integral function. The controller has a good control effect on time-delay and can keep a better performance by self-regulation on-line in the network with data dropout and interference. It is good in quickness, adaptability, and robustness, which is favorable for controlling the long time-delay system.

  1. Dynamics study of green AuNP formation and their basis for Au-Pt core-shell nanostructure synthesis

    DEFF Research Database (Denmark)

    Engelbrekt, Christian; Seselj, Nedjeljko; Ulstrup, Jens; Zhang, Jingdong

    details of nanoparticle formation has been developed employing readily available electrochemical and optical techniques. The aim is to understand which parameters control the growth and shape and at which stages of the synthesis. The gold nanoparticles (AuNPs) studied are further used as seeds for size...... controlled AuNPs and Au - Pt core - shell NPs with an atomically thin Pt shell...

  2. Application of fuzzy logic operation and control to BWRs

    International Nuclear Information System (INIS)

    Fuzzy logic control schemes employing linguistic decision rules for flexible operator control strategies have undergone application tests in dynamic systems. The advantages claimed for fuzzy logic control are its abilities: (a) to facilitate direct use of skillful operator know-how for automatic operation and control of the systems and (b) to provide robust multivariable control for complex plants. The authors have also studied applications of fuzzy logic control to automatic startup operations and load-following control in boiling water reactors, pursuing these same advantages

  3. Web-based control application using WebSocket

    International Nuclear Information System (INIS)

    The WebSocket allows asynchronous full-duplex communication between a Web-based (i.e. Java Script-based) application and a Web-server. WebSocket started as a part of HTML5 standardization but has now been separated from HTML5 and has been developed independently. Using WebSocket, it becomes easy to develop platform independent presentation layer applications for accelerator and beamline control software. In addition, a Web browser is the only application program that needs to be installed on client computer. The WebSocket-based applications communicate with the WebSocket server using simple text-based messages, so WebSocket is applicable message-based control system like MADOCA, which was developed for the SPring-8 control system. A simple WebSocket server for the MADOCA control system and a simple motor control application were successfully made as a first trial of the WebSocket control application. Using Google-Chrome (version 13.0) on Debian/Linux and Windows 7, Opera (version 11.0) on Debian/Linux and Safari (version 5.0.3) on Mac OS X as clients, the motors can be controlled using a WebSocket-based Web-application. Diffractometer control application use in synchrotron radiation diffraction experiment was also developed. (author)

  4. Laminar flow control for transport aircraft applications

    Science.gov (United States)

    Wagner, R. D.

    1986-01-01

    The incorporation of laminar flow control into transport aircraft is discussed. Design concepts for the wing surface panel of laminar flow control transport aircraft are described. The development of small amounts of laminar flow on small commercial transports with natural or hybrid flow control is examined. Techniques for eliminating the insect contamination problem in the leading-edge region are proposed.

  5. Touch panel system for control applications

    International Nuclear Information System (INIS)

    The use of finger-sensitive touch panels in association with computer-generated displays for control and monitoring of the Stanford linear accelerator is discussed. This control concept has proven to be very effective. The hardware and software aspects of the Touch Panel portion of the control system are described

  6. Strain distributions of confined Au/Ag and Ag/Au nanoparticles

    Institute of Scientific and Technical Information of China (English)

    黄红华; 章英; 刘晓山; 骆兴芳; 袁彩雷; 叶双莉

    2015-01-01

    The strain distributions of Au/Ag and Ag/Au nanoparticles confined in the Al2O3 matrix with different core sizes are investigated by using the finite element method, respectively. The simulation results clearly indicate that the compressive strains exerted on the Au/Ag and Ag/Au nanoparticles can be induced by the Al2O3 matrix. Moreover, it can be found that the strain gradient existing in a Au/Ag nanoparticle is much larger than that in a Ag/Au nanoparticle, which could be due to the larger Young’s modulus of Au than that of Ag. With the core size increasing, the strain gradient existing in the Au/Ag nanoparticle becomes larger, while the strain gradient existing in the Ag/Au nanoparticle keeps constant. These different strain distributions may have significant infl uences on the structures and morphologies of the Au/Ag and Ag/Au nanoparticles, leading to the different physical properties for potential applications.

  7. Au/Sn共晶键合技术在MEMS封装中的应用%Application of the Au/Sn Eutectic Bonding Technology in the Packaging of MEMS

    Institute of Scientific and Technical Information of China (English)

    胥超; 徐永青; 杨拥军; 杨志

    2014-01-01

    研究了Au/Sn共晶圆片键合技术在MEMS气密性封装中的应用.设计了共晶键合多层材料的结构和密封环图形,盖帽层采用Ti/Ni/Au/Sn/Au结构,器件层采用Ti/Ni/Au结构,盖帽层腔体尺寸为4.5mm×4.5 mm×20 μm,Au/Sn环的宽度为700 μm,优化了键合工艺,对影响气密性的因素(如组分配比、键合前处理和键合温度等)进行了分析.两层硅片在氮气气氛中靠静态的压力实现紧密接触.在峰值温度为300℃、持续时间为2 min的条件下实现了良好的键合效果,其剪切力平均值达到16.663 kg,漏率小于2×10-3 Pa·cm3/s,满足检验标准(GJB548A)的要求,验证了Au/Sn共晶键合技术在MEMS气密封装中的适用性.

  8. Electrogenerated Chemiluminescence Behavior of Au nanoparticles-hybridized Pb (II) metal-organic framework and its application in selective sensing hexavalent chromium

    OpenAIRE

    Hongmin Ma; Xiaojian Li; Tao Yan; Yan Li; Haiyang Liu; Yong Zhang; Dan Wu; Bin Du; Qin Wei

    2016-01-01

    In this work, a novel electrochemiluminescence (ECL) sensor based on Au nanoparticles-hybridized Pb (II)-β-cyclodextrin (Pb-β-CD) metal-organic framework for detecting hexavalent chromium (Cr(VI)) was developed. Pb-β-CD shows excellent ECL behavior and unexpected reducing ability towards Au ions. Au nanoparticles could massively form on the surface of Pb-β-CD (Au@Pb-β-CD) without use of any additional reducing agent. In the presence of coreactant K2S2O8, the ECL emission of Pb-β-CD was enhanc...

  9. Time evolution of relativistic d + Au and Au + Au collisions

    CERN Document Server

    Wolschin, G; Mizoguchi, T; Suzuki, N; Biyajima, Minoru; Mizoguchi, Takuya; Suzuki, Naomichi; Wolschin, Georg

    2006-01-01

    The evolution of charged-particle production in collisions of heavy ions at relativistic energies is investigated as function of centrality in a nonequilibrium-statistical framework. Precise agreement with recent d + Au and Au + Au data at sqrt(s_NN) = 200 GeV is found in a Relativistic Diffusion Model with three sources for particle production. Only the midrapidity source comes very close to local equilibrium, whereas the analyses of the overall pseudorapidity distributions show that the systems remain far from statistical equilibrium.

  10. Fuzzy multinomial control chart and its application

    Science.gov (United States)

    Wibawati, Mashuri, Muhammad; Purhadi, Irhamah

    2016-03-01

    Control chart is a technique that has been used widely in industry and services. P chart is the simplest control chart. In this chart, item is classified into two categories as either conforming and non conforming. This chart based on binomial distribution. In practice, each item can classify in more than two categories such as very bad, bad, good and very good. Then to monitor the process we used multinomial p control chart. However, if the classification is an element of vagueness, the fuzzy multinomial control chart (FM) is more appropriately used. Control limit of FM chart obtained multinomial distribution and the degree of membership using fuzzy trianguler are 0, 0.25. 0.5 and 1. This chart will be applied to the data glass and will compare with multinomial p control chart.

  11. Elliptic optimal control problems with L1-control cost and applications for the placement of control devices

    OpenAIRE

    Stadler, Georg

    2006-01-01

    Elliptic optimal control problems with L1-control cost are analyzed. Due to the nonsmooth objective functional the optimal controls are identically zero on large parts of the control domain. For applications, in which one cannot put control devices (or actuators) all over the control domain, this provides information about where it is most efficient to put them. We analyze structural properties of L1- control cost solutions. For solving the non-differentiable optimal control pr...

  12. Breath sampling control for medical application

    OpenAIRE

    Vautz, Wolfgang; Baumbach, Jörg I.; Westhoff, Michael; Züchner, Klaus; Carstens, Eike T. H.; Perl, Thorsten

    2010-01-01

    Sampling of breath under human control or automated control with sensors was combined with chemical determination of a synthetic sample using multi-capillary column ion mobility spectrometry to measure quantitative variability. Variation was 19% with an automated inlet and 33% with human control. Sensors to operate an automated inlet were also evaluated with human subjects and included carbon dioxide (CO2), flow (direction and velocity), volume (integrated from the flow rate) and humidity, al...

  13. Application Oriented Programming and Control of Industrial Robots

    OpenAIRE

    Nilsson, Klas

    1992-01-01

    Efficient use of industrial robots requires a strong interplay between user level commands, the motion control system, and external equipment. It should also be possible for an experienced application engineer to tailor the motion control to a specific application in a convenient way, instead of deficient utilization of the device or tricky user programming which is often the case today. A layered software architecture has been designed based on an application oriented view, considering typic...

  14. First principles calculations of the optical and plasmonic response of Au alloys and intermetallic compounds.

    Science.gov (United States)

    Keast, V J; Barnett, R L; Cortie, M B

    2014-07-30

    Pure Au is widely used in plasmonic applications even though its use is compromised by significant losses due to damping. There are some elements that are less lossy than Au (e.g. Ag or Al) but they will normally oxidize or corrode under ambient conditions. Here we examine whether alloying Au with a second element would be beneficial for plasmonic applications. In order to evaluate potential alternatives to pure Au, the density of states (DOS), dielectric function and plasmon quality factor have been calculated for alloys and compounds of Au with Al, Cd, Mg, Pd, Pt, Sn, Ti, Zn and Zr. Substitutional alloying of Au with Al, Cd, Mg and Zn was found to slightly improve the plasmonic response. Of the large number of intermetallic compounds studied, only AuAl2, Au3Cd, AuMg, AuCd and AuZn were found to be suitable for plasmonic applications. PMID:25001413

  15. Transport de particules massives dans un fluide turbulent: Application a l'erosion due au sable sur les parois d'une turbine hydraulique

    Science.gov (United States)

    Bergeron, Stephen

    Le transport de particules massives par un champ turbulent est un vaste domaine de la mécanique des fluides. Il possède de nombreuses applications comme par exemple le transport de sable dans une turbine hydraulique. En raison de la dureté des grains de quartz et des grandes vitesses de collision avec les parois métalliques, un phénomène d'érosion intensif se produit. Les dommages résultants peuvent diminuer le rendement de la turbine au cours des quelques mois suivant la mise en opération. L'objectif de cette thèse est de mettre au point un outil permettant de prédire ces zones d'érosion. Ce projet de recherche en contexte industriel a été réalisé en collaboration avec la compagnie General Electric Hydro du Canada. Dans un régime hautement turbulent, il est possible d'obtenir une expression suffisamment générale en utilisant une formulation partiellement empirique: l'équation de Basset- Boussinesq-Oseen modifiée. Ce choix de modèle tient compte du niveau de précision recherché et de la méthode numérique employée afin de résoudre la phase fluide. Il permet aussi d'éliminer plusieurs ambiguïtés fréquemment rencontrées dans la littérature et implementées dans certains codes commerciaux courants. La formulation mathématique du problème est effectuée dans un espace mixte Euler-Lagrange. Les paramètres dynamiques sont relies au type de particules et à l'intensité de la turbulence. Le code numérique résultant est le plus performant développé à ce jour (août 1998). Les trajectoires de plusieurs centaines de milliers de particules peuvent être simulées et visualisées de manière interactive sur une station de travail (SGI R4K, R8K et R10K). L'utilisateur du logiciel est libre de se déplacer dans l'espace à l'aide d'un environnement similaire a un ``simulateur de vol''. Il peut ainsi analyser les détails du processus d'érosion de même que l'écoulement du fluide dans la turbine. Les zones d'érosion obtenues à l

  16. Application of fuzzy logic controller in a nuclear power plant

    International Nuclear Information System (INIS)

    Possible application of a fuzzy logic controller in a PWR nuclear power plant is investigated in this paper. A simplified model of the complex dynamics of the system is used for simulation purposes. The goal is to keep average coolant temperature as close as possible to a desired (but changing) reference value. The position of the control rods is selected as control variable. Simulation results demonstrate the possibility of using fuzzy logic controllers in load following control of nuclear power plants

  17. Parametric control systems design with applications in missile control

    Institute of Scientific and Technical Information of China (English)

    DUAN GuangRen; YU HaiHua; TAN Feng

    2009-01-01

    This paper considers parametric control of high-order descriptor linear systems via proportional plus derivative feedback.By employing general parametric solutions to a type of so-called high-order Sylvester matrix equations,complete parametric control approaches for high-order linear systems are presented.The proposed approaches give simple complete parametric expressions for the feedback gains and the closed-loop eigenvector matrices,and produce all the design degrees of freedom.Furthermore,Important special cases are particularly treated.Based on the proposed parametric design approaches,a parametric method for the gain-scheduling controller design of a linear time-varying system is proposed and the design of a BTT missile autopilot is carried out.The simulation results show that the method is superior to the traditional one in sense of either global stability or system performance.

  18. A Result On Implicit Consensus with Application to Emissions Control

    OpenAIRE

    Knorn, Florian; Corless, Martin J.; Shorten, Robert N.

    2011-01-01

    This paper is concerned with a class of decentralised control problems that arise in contemporary applications where agents cooperate to control and regulate a global quantity, are limited in the manner in which they communicate with each other, and are required to reach consensus on some implicit variable (for instance, CO2 emissions). An algorithm is presented for achieving this goal. A simplified application of the algorithm to emissions control for a fleet of Plug-in ...

  19. Electromechanical actuation for thrust vector control applications

    Science.gov (United States)

    Roth, Mary Ellen

    At present, actuation systems for the Thrust Vector Control (TVC) for launch vehicles are hydraulic systems. The Advanced Launch System (ALS), a joint initiative between NASA and the Air Force, is a launch vehicle that is designed to be cost effective, highly reliable and operationally efficient with a goal of reducing the cost per pound to orbit. As part of this initiative, an electromechanical actuation system is being developed as an attractive alternative to the hydraulic systems used today. NASA-Lewis is developing and demonstrating an Induction Motor Controller Actuation System with a 40 hp peak rating. The controller will integrate 20 kHz resonant link Power Management and Distribution (PMAD) technology and Pulse Population Modulation (PPM) techniques to implement Field Oriented Vector Control (FOVC) of a new advanced induction motor. Through PPM, multiphase variable frequency, variable voltage waveforms can be synthesized from the 20 kHz source. FOVC shows that varying both the voltage and frequency and their ratio (V/F), permits independent control of both torque and speed while operating at maximum efficiency at any point on the torque-speed curve. The driver and the FOVC will be microprocessor controlled. For increased system reliability, a Built-in Test (BITE) capability will be included. This involves introducing testability into the design of a system such that testing is calibrated and exercised during the design, manufacturing, maintenance and prelaunch activities. An actuator will be integrated with the motor controller for performance testing of the EMA TVC system. The design and fabrication of the motor controller is being done by General Dynamics Space Systems Division. The University of Wisconsin-Madison will assist in the design of the advanced induction motor and in the implementation of the FOVC theory. A 75 hp electronically controlled dynamometer will be used to test the motor controller in all four quadrants of operation using flight type

  20. Engineering Gold Nanorod-Based Plasmonic Nanocrystals for Optical Applications

    KAUST Repository

    Huang, Jianfeng

    2015-09-01

    Plasmonic nanocrystals have a unique ability to support localized surface plasmon resonances and exhibit rich and intriguing optical properties. Engineering plasmonic nanocrystals can maximize their potentials for specific applications. In this dissertation, we developed three unprecedented Au nanorod-based plasmonic nanocrystals through rational design of the crystal shape and/or composition, and successfully demonstrated their applications in light condensation, photothermal conversion, and surface-enhanced Raman spectroscopy (SERS). The “Au nanorod-Au nanosphere dimer” nanocrystal was synthesized via the ligand-induced asymmetric growth of a Au nanosphere on a Au nanorod. This dimeric nanostructure features an extraordinary broadband optical absorption in the range of 400‒1400nm, and it proved to be an ideal black-body material for light condensation and an efficient solar-light harvester for photothermal conversion. The “Au nanorod (core) @ AuAg alloy (shell)” nanocrystal was built through the epitaxial growth of homogeneously alloyed AuAg shells on Au nanorods by precisely controlled synthesis. The resulting core-shell structured, bimetallic nanorods integrate the merits of the AuAg alloy with the advantages of anisotropic nanorods, exhibiting strong, stable and tunable surface plasmon resonances that are essential for SERS applications in a corrosive environment. The “high-index faceted Au nanorod (core) @ AuPd alloy (shell)” nanocrystal was produced via site-specific epitaxial growth of AuPd alloyed horns at the ends of Au nanorods. The AuPd alloyed horns are bound with high-index side facets, while the Au nanorod concentrates an intensive electric field at each end. This unique configuration unites highly active catalytic sites with strong SERS sites into a single entity and was demonstrated to be ideal for in situ monitoring of Pd-catalyzed reactions by SERS. The synthetic strategies developed here are promising towards the fabrication of

  1. Application study of complex control algorithm for regenerative furnace temperature

    Institute of Scientific and Technical Information of China (English)

    Lusheng GE

    2004-01-01

    Altemative switch combustion mode of air and gas is adopted on the two sides of the regenerative furnace, its temperature is in uncontrolled state in the switching process and the switch period is generally 3 ~ 5 min. Thus, the conventional bi-cross limited combustion control method is no longer applicable to the object. This paper makes use of neutral network algorithm to adjust the static operating point. On this basis, fuzzy control strategy is used for the furnace temperature control. The actual application result shows that the control strategy is effective to solve the problem of the combustion control for regenerative furnace.

  2. ANDROID APPLICATION DEVELOPMENT FOR POLYHOUSE CONTROL

    OpenAIRE

    Sidhant S. Kulkarni*, S. K. Gupta

    2016-01-01

    Parameter monitoring and control of polyhouse environment play an important role in polyhouse production and management. This project involve a design and implementation of an monitor and control the essential polyhouse parameters, such as, soil moisture sensing scheduled based Plant monitoring system. This implementation supports the farmers to increase the crop production. The standalone GSM module which is integrated with specific small size sensors. All monitored parameters are transmitte...

  3. Advanced Control Strategies for Mobile Hydraulic Applications

    OpenAIRE

    Cristofori, Davide

    2013-01-01

    Mobile hydraulic machines are affected by numerous undesired dynamics, mainly discontinuous motion and vibrations. Over the years, many methods have been developed to limit the extent of those undesired dynamics and improve controllability and safety of operation of the machine. However, in most of the cases, today's methods do not significantly differ from those developed in a time when electronic controllers were slower and less reliable than they are today. This dissertation addresses t...

  4. Fabrication of macroporous Pt and PtAu electrodes for electrochemical application through galvanic replacement at macroporous Cu electrode electrodeposited at polystyrene template from room temperature ionic liquid

    International Nuclear Information System (INIS)

    Highlights: ► Macroporous Pt and PtAu electrodes were prepared through galvanic replacement. ► Galvanic replacement occurred at macroporous Cu electrodes in aqueous solutions. ► Macroporous Cu electrodes were electrodeposited from ionic liquid at PS template. ► Surfactant played an important role on the formation of macroporous structures. ► Macroporous PtAu revealed good electrocatalytic activity to ethanol oxidation. -- Abstract: Macroporous Pt and PtAu electrodes (MP-Pt and MP-PtAu) were prepared through galvanic replacement at macroporous Cu electrodes, which were formed by electrodeposition of Cu at Au-coated indium tin oxide (Au/ITO) electrodes covered with ordered arrays of polystyrene (PS) nanospheres (PS/Au/ITO) in N-butyl-N-methylpyrrolidinium dicyanamide room temperature ionic liquid (BMP-DCA RTIL). After dissolving the PS templates in tetrahydrofuran (THF), macroporous Cu electrodes (MP-Cu/Au/ITO; denoted as MP-Cu hereafter) were obtained. The surface of a MP-Cu was spontaneously replaced by Pt or Pt/Au when a MP-Cu was immersed in an aqueous solution containing H2PtCl6 or H2PtCl6/HAuCl4 to form the MP-Pt (actually, MP-Pt/Cu/Au/ITO) or MP-PtAu electrodes. The atomic ratios of Au in PtAu could be adjusted by changing the concentration of HAuCl4 in the mixtures of H2PtCl6/HAuCl4. The electrodeposition potential, the time of replacement reaction, the concentrations of H2PtCl6 and HAuCl4, and the content of surfactant, which influence the structure of macroporous electrodes, were investigated. The surface morphologies of these macroporous electrodes were characterized with scanning electron microscope (SEM). MP-PtAu electrodes showed the better performance than the MP-Pt electrodes on the electrocatalytic oxidation of ethanol in alkaline solutions

  5. Simulation of Fuzzy Inductance Motor using PI Control Application

    Directory of Open Access Journals (Sweden)

    S.V.Halse

    2013-06-01

    Full Text Available Fuzzy control has been widely used in industrial controls, particularly in situations where conventional control design techniques have been difficult to apply. Number of fuzzy rules is very important for real time fuzzy control applications. This study is motivated by the increasing need in the industry to design highly reliable, efficiency and low complexity controllers. The proposed fuzzy controller is constructed by several fuzzy controllers with less fuzzy rules to carry out control tasks. Performances of the proposed fuzzy controller are investigated and compared to those obtained from the conventional fuzzy controller. Fuzzy logic control method has the ability to handle errors in control operation with system nonlinearity and its performance is less affected by system parameter variations.

  6. Méthode de vieillissement accéléré au dioxyde de chlore : application au polyamide 66 non stabilisé et non chargé

    OpenAIRE

    Dauseins, J.; El Mazry, Chaker; Mallet, J; Colin, Xavier; CORREC, Olivier

    2014-01-01

    Dans l'objectif d'étudier à long terme des accessoires utilisés dans les réseaux intérieurs d'eau, le Centre scientifique et technique du bâtiment (CSTB) a mis au point un banc d'essai de vieillissement accéléré au dioxyde de chlore sur sa plateforme expérimentale Aquasim. Les premières études réalisées avec le banc montrent que ce désinfectant de l'eau potable attaque aussi les matériaux polymères. Initialement utilisé pour détruire les micro-organismes, il n'est pas totalement sélectif puis...

  7. Contribution à l'élaboration d'un guide de bonnes pratiques de la gestion des ressources humaines au sein des structures vétérinaires : application au personnel non vétérinaire

    OpenAIRE

    Debeaupuits, Julien

    2014-01-01

    La réussite d'un vétérinaire ne passe plus seulement par ses compétences scientifiques, il doit aussi gérer ses capitaux, son personnel, ...Le vétérinaire est un véritable entrepreneur. Le nombre de salariés non vétérinaires au sein des structures vétérinaires augmente au fil des années. De nombreuses études démontrent l'importance d'une bonne gestion des ressources humaines. Même si ces notions sont parmi les plus dificiles à gérer pour le clinicien, la réussite de cette partie du management...

  8. Mechano-optic logic gate controlled by third-order nonlinear optical properties in a rotating ZnO:Au thin film

    Science.gov (United States)

    Carrillo-Delgado, C.; García-Gil, C. I.; Trejo-Valdez, M.; Torres-Torres, C.; García-Merino, J. A.; Martínez-Gutiérrez, H.; Khomenko, A. V.; Torres-Martínez, R.

    2016-01-01

    Measurements of the third-order nonlinear optical properties exhibited by a ZnO thin solid film deposited on a SnO2 substrate are presented. The samples were prepared by a spray pyrolysis processing route. Scanning electron microscopy analysis and UV-Vis spectroscopy studies were carried out. The picosecond response at 1064 nm was explored by the z-scan technique. A large optical Kerr effect with two-photon absorption was obtained. The inhibition of the nonlinear optical absorption together with a noticeable enhancement in the optical Kerr effect in the sample was achieved by the incorporation of Au nanoparticles into the ZnO film. Additionally, a two-wave mixing configuration at 532 nm was performed and an optical Kerr effect was identified as the main cause of the nanosecond third-order optical nonlinearity. The relaxation time of the photothermal response of the sample was estimated to be about 1 s when the sample was excited by nanosecond single-shots. The rotation of the sample during the nanosecond two-wave mixing experiments was analyzed. It was stated that a non-monotonic relation between rotating frequency and pulse repetition rate governs the thermal contribution to the nonlinear refractive index exhibited by a rotating film. Potential applications for switching photothermal interactions in rotating samples can be contemplated. A rotary logic system dependent on Kerr transmittance in a two-wave mixing experiment was proposed.

  9. Applicator Training Manual for: Forest Pest Control.

    Science.gov (United States)

    Newman, Jim

    Described in this manual is the use of insecticides, fungicides, and herbicides in forestry. Both diseases and insects found in hardwoods and conifers are covered. Detailed information is given on methods of herbicide application. Finally, five important environmental considerations are given. (BB)

  10. The influence of industrial applications on a control system toolbox

    International Nuclear Information System (INIS)

    Vsystem is as an open, advanced software application toolbox for rapidly creating fast, efficient and cost-effective control and data-acquisition systems. Vsystem's modular architecture is designed for single computers, networked computers and workstations running under VAX/VMS or VAX/ELN. At the heart of Vsystem lies Vaccess, a user extendible real-time database and library of access routines. The application database provides the link to the hardware of the application and can be organized as one database or separate database installed in different computers on the network. Vsystem has found application in charged-particle accelerator control, tokamak control, and industrial research, as well as its more recent industrial applications. This paper describes the broad feature of Vsystem and the influence that recent industrial applications have had on the software. (author)

  11. Labview Application For A Vehicle Control

    Directory of Open Access Journals (Sweden)

    Douglas Paladine Vieira

    2002-01-01

    Full Text Available This article deals with the construction of a vehicle driven by electric motors and that is automated, that is, that can move anywhere without human intervention. The control was done using the software Labview, with data acquisition and generation of control signs. The vehicle has an infrared sensors system that indicates the existence of an obstacle ahead the vehicle, informing it that it should stop and bypass the obstacle. The program is the responsible for the engine control, making it possible for the prototype to run and bypass the objects that block its way. The possibility of remote-controlling a vehicle is very important is risky situations for human beings, for example in radioactive places. The main advantage of this system is the total flexibility for making alterations in the control software, without being necessary to touch the physical part of the prototype. The conclusion of this work is that the system is efficient and able to move in a room with objects without touching them.

  12. Designing Control System Application Software for Change

    Science.gov (United States)

    Boulanger, Richard

    2001-01-01

    The Unified Modeling Language (UML) was used to design the Environmental Systems Test Stand (ESTS) control system software. The UML was chosen for its ability to facilitate a clear dialog between software designer and customer, from which requirements are discovered and documented in a manner which transposes directly to program objects. Applying the UML to control system software design has resulted in a baseline set of documents from which change and effort of that change can be accurately measured. As the Environmental Systems Test Stand evolves, accurate estimates of the time and effort required to change the control system software will be made. Accurate quantification of the cost of software change can be before implementation, improving schedule and budget accuracy.

  13. MEMS device for spacecraft thermal control applications

    Science.gov (United States)

    Swanson, Theordore D. (Inventor)

    2003-01-01

    A micro-electromechanical device that comprises miniaturized mechanical louvers, referred to as Micro Electro-Mechanical Systems (MEMS) louvers are employed to achieve a thermal control function for spacecraft and instruments. The MEMS louvers are another form of a variable emittance control coating and employ micro-electromechanical technology. In a function similar to traditional, macroscopic thermal louvers, the MEMS louvers of the present invention change the emissivity of a surface. With the MEMS louvers, as with the traditional macroscopic louvers, a mechanical vane or window is opened and closed to allow an alterable radiative view to space.

  14. Advances in control system technology for aerospace applications

    CERN Document Server

    2016-01-01

    This book is devoted to Control System Technology applied to aerospace and covers the four disciplines Cognitive Engineering, Computer Science, Operations Research, and Servo-Mechanisms. This edited book follows a workshop held at the Georgia Institute of Technology in June 2012, where the today's most important aerospace challenges, including aerospace autonomy, safety-critical embedded software engineering, and modern air transportation were discussed over the course of two days of intense interactions among leading aerospace engineers and scientists. Its content provide a snapshot of today's aerospace control research and its future, including Autonomy in space applications, Control in space applications, Autonomy in aeronautical applications, Air transportation, and Safety-critical software engineering.

  15. Applications software supporting the Spartan Attitude Control System

    Science.gov (United States)

    Stone, R. W.

    1986-01-01

    The native software supporting a single mission for the Spartan Attitude Control System can require up to 40,000 lines of code. Most of this must be rewritten for each mission. Control system engineers use an array of Applications Software Packages residing in ground computers to write each mission's flight software. These Applications Packages are written in the 'C' programming language and run under the UNIX Operating System. This paper discusses each of the Attitude Control Applications Software Packages, and describes the purpose and design of each.

  16. Application of fuzzy logic control system for reactor feed-water control

    International Nuclear Information System (INIS)

    The successful actual application of a fuzzy logic control system to the a nuclear Fugen nuclear power reactor is described. Fugen is a heavy-water moderated, light-water cooled reactor. The introduction of fuzzy logic control system has enabled operators to control the steam drum water level more effectively in comparison to a conventional proportional-integral (PI) control system

  17. A comparative study of Ge/Au/Ni/Au-based ohmic contact on graphene

    International Nuclear Information System (INIS)

    Superior graphene—metal contacts can improve the performance of graphene devices. We report on an experimental demonstration of Ge/Au/Ni/Au-based ohmic contact on graphene. The transfer length method (TLM) is adopted to measure the resistivity of graphene-metal contacts. We designed a process flow, which can avoid residual photoresist at the interface of metal and graphene. Additionally, rapid thermal annealing (RTA) at different temperatures as a post-processing method is studied to improve graphene—metal contact. The results reveal that the contact resistivity of graphene and Ge/Au/Ni/Au can reach 10−5 Ω·cm2 after RTA, and that 350 °C is optimum annealing temperature for the contact of graphene—Ge/Au/Ni/Au. This paper provides guidance for fabrication and applications of graphene devices. (semiconductor technology)

  18. Ground control segment for UAS civil applications

    OpenAIRE

    Cuadrado Santolaria, Raúl

    2011-01-01

    The aeronautical industry is in a new era of growth thanks to numerous technological advances. One of them is the UAS; Unmanned Aircraft Systems are able to fly by themselves with autonomous operation capabilities. UAS can advantage manned aircrafts in the so called D-cube applications: Dull, Dirty or Dangerous. Risks and costs can be minimized using UAS since they need no crew and their construction, operation and maintenance costs are comparatively lower. This Master Thesi...

  19. Synthesis and characterization of Au-alumina nanocomposites prepared by atom beam co-sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Tiwari, Manisha; Annapoorni, S. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Agarwal, D.C.; Avasthi, D.K. [Inter University Accelerator Centre, P.O. Box 10502, New Delhi 110067 (India); Mohapatra, S. [School of Basic and Applied Sciences, Guru Gobind Singh Indraprastha University, Dwarka, New Delhi 110075 (India); Pivin, J.C. [CSNSM, IN2P3-CNRS, Batiment 108, 1405 Orsay Campus (France)

    2012-12-15

    Nanocomposite thin films of Au-alumina with varying Au contents were synthesized by atom beam co-sputtering. The Au content and the thickness of nanocomposite films were determined by Rutherford backscattering spectrometry. Transmission electron microscopy studies reveal the presence of Au nanoparticles with bimodal size distribution in nanocomposites for lower Au content. Overlapping Au nanoparticles were observed for higher Au content. The increase in size of Au nanocrystals is observed with increase in Au concentration as also evident by glancing angle X-ray diffraction studies. Ultraviolet (UV)-visible absorption studies revealed surface plasmon resonance (SPR) peak which showed a red shift from 519 to 602 nm with increasing Au content of the nanocomposites. Preliminary study exploring the interaction between Au nanoparticles in the nanocomposites and bovine serum albumin (BSA) showed the Au nanoparticles to be BSA sensitive, indicating their possible applications in biosensors. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  20. Exploring applicability of the workload control concept

    NARCIS (Netherlands)

    Henrich, P.; Land, M.J.; Gaalman, G.J.C.

    2004-01-01

    To be successful in companies, a production planning and control (PPC) concept should fit to the production environment. Essential elements of the concept should correspond with the characteristics of the production system. For classical concepts such as MRP these elements have become common sense.

  1. Locus of Control and Performance: Widening Applicabilities

    Science.gov (United States)

    Manichander, T.

    2014-01-01

    In an attempt to explain the evidence which indicates that internal perception of control is positively related to academic achievement, this paper suggests that mediating motivational and cognitive reactions, which differentiate internals from externals, may account for this relationship. Furthermore, on the basis of data which suggest that the…

  2. Modelisation et commande des redresseurs triphases fonctionnant a haut rendement et a faible taux de distorsion harmonique: Application au redresseur triphase de vienne

    Science.gov (United States)

    Belhadj Youssef, Nesrine

    Les problemes de la qualite de l'onde electrique constituent l'une des preoccupations majeures des fournisseurs de l'energie et des organismes specialises en qualite d'energie. Ce sujet a gagne davantage d'ampleur avec l'utilisation ascendante des convertisseurs de l'energie electrique dans la majorite des applications industrielles et domestiques. Dans le cadre de cette these, on s'interesse plus particulierement au type des convertisseurs alternatif/continu, dont le fonctionnement adequat implique la parfaite regulation du bus DC de tension, l'attenuation des harmoniques de courants, la compensation de l'energie reactive et la maximisation du rendement energetique. Ces differents criteres doivent etre maintenus pour diverses conditions de fonctionnement, c'est-a-dire independamment des variations parametriques auxquelles le systeme peut etre sujet. Il s'avere donc indispensable d'adopter des techniques de commande efficaces, ce qui passe par une modelisation correcte du convertisseur. L'optimisation du nombre de capteurs dans le circuit est egalement un facteur cle a prendre en consideration.

  3. A Robust Controller Structure for Pico-Satellite Applications

    DEFF Research Database (Denmark)

    Kragelund, Martin Nygaard; Green, Martin; Kristensen, Mads;

    This paper describes the development of a robust controller structure for use in pico-satellite missions. The structure relies on unknown disturbance estimation and use of robust control theory to implement a system that is robust to both unmodeled disturbances and parameter uncertainties. As one...... possible application, a satellite mission with the purpose of monitoring shipping routes for oil spills has been considered. However, it is the aim of the control structure to be widely applicable and adaptable for a vide variety of pico-satellite missions. The robust control structure has been evaluated...

  4. Weapon Control System for Airborne Application.

    Directory of Open Access Journals (Sweden)

    M. Sankar Kishore

    2000-07-01

    Full Text Available The integrated fire' control system (IFCS plays an important role in the present-day fighter aircraft and helicopters. Wecapons, such as missiles (active/passive, rockets and guns may be present on thelfighter aircraft or helicopter .IFCS monitors the status of the weapons present on the vehicle and passes the information to pilot/co-pilot. Depending upon the health/availability of the weapons, IFCS selects/fires the weapons. An attempt has been made to bring out the details of one such IFCS. As a I stepping stone, smaller version is developed and same philosophy can be used for integrating ftlore and I more weapons. Here, emphasis has been made on design and development of weapon control unit which is the heart f IFCS, both in hardware and software. The system has been developed using a 486 DX2 processor, and an elaborate software has been developed in PL/M.

  5. Advanced Applications of Subsea Control Systems

    International Nuclear Information System (INIS)

    Technology transfer is one of the main arguments Norwegian companies have for getting involved in difficult markets like Angola. There is great need for sub sea technology in Angola, and Kvaerner Oilfield Products is one of the companies that have successfully fought for contracts in this lucrative market. Field operator TotalFinaElf Exploration and Production Angola has awarded Kvaerner Oilfield Products a USD 3.1 million contract for pre-engineering and qualification testing of the sub sea production systems for the Dalia field offshore Angola. Kvaerner Oilfield Products has already started pre-engineering and testing activity. The sub sea production system includes 42 Xmas trees for controlling the well stream, nine manifolds as well as related control equipment. As sub sea technology improves and advances, equipment that is more complex is being placed on the seabed and downhole environments. Factors such as the cost of the umbilical, increased noise immunity and speed requirements will almost certainly result in optical communications being widely adopted for future system designs. However; in the immediate future operators are likely to insist on backup electrical communications due to the immaturity of certain aspects such as Wetmate optical connectors, fibre handling and fibre degradation. Perhaps the single greatest advantage of open standard sub sea networking is derived from the exploitation of the growing range of third party intelligent instrumentation available on the market. This instrumentation when properly integrated into a sensor to boardroom data management system allows unparalleled control to be delivered to the user at a total cost of installation which can be radically less than conventional technology. It can provide a compelling case for adoption of true open standards. In order to deliver power over any significant distance it is necessary to consider the losses in the transmission medium. The major constraint in the sub sea industry is

  6. CONCEPTION-ET-MODELISATION-D’UN-MICROLEVIER-PIEZORESISTI- APPLICATION-AU-MICROSCOPE-A-FORCE-ATOMIQUE-inistère

    OpenAIRE

    MEDJAHDI, Nadjia

    2014-01-01

    Dans le cadre de ce mémoire, nous avons modélisé le comportement du microlevier piézorésistif, nous avons étudié une de ces applications : c’est le microscope à force atomique. Enfin, nous nous sommes attachés à concevoir un microlevier piézorésistif pouvant servir de produit consommable pour l’AFM. Dans le premier chapitre, nous avons rappelé quelques notions de base sur les microsystèmes. Nous avons aussi donné les principaux types de microsystèmes à savoir les microcapteu...

  7. Analyse économique du droit au respect de la vie personnelle : application à la relation de travail en France

    OpenAIRE

    Stéphanie Arnaud

    2007-01-01

    Privacy protection is part of the social demand, which is rendered more crucial by the introduction of new technologies of information and communication in the workplace. Indeed, they improve the capacities of traditional systems for control and offer new ways to monitor (cybersurveillance) and to collect personal data. “Big Brother is Watching” can illustrate the perceptions about the workplace of numerous employees. Can we reconcile privacy protection of employees with the enterprise’s need...

  8. Inductive Logic Programming for Industrial Control Applications

    OpenAIRE

    Samiya Bouarroudj; Zizette Boufaida

    2014-01-01

    Advanced Monitoring Systems of the processes consti tute a higher level to the systems of control and use specific techniques and methods. An importa nt part of the task of supervision focuses on the detection and the diagnosis of various situatio ns of faults which can affect the process. Methods of fault detection and diagnosis (FDD) are different from the type of knowledge about the process that they require. They can be classifi ed as...

  9. 75 FR 32505 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-08

    ... the listed controlled substance in bulk active pharmaceutical ingredient (API) form. There are no... the Federal Register on September 23, 1975 (40 FR 43745-46), all applicants for registration to...

  10. 76 FR 21915 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-04-19

    ... listed controlled substance in bulk ] active pharmaceutical ingredient (API) form. There are no domestic... Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for registration to import a...

  11. 5th International Conference on Optimization and Control with Applications

    CERN Document Server

    Teo, Kok; Zhang, Yi

    2014-01-01

    This book presents advances in state-of-the-art solution methods and their applications to real life practical problems in optimization, control and operations research. Contributions from world-class experts in the field are collated here in two parts, dealing first with optimization and control theory and then with techniques and applications. Topics covered in the first part include control theory on infinite dimensional Banach spaces, history-dependent inclusion and linear programming complexity theory. Chapters also explore the use of approximations of Hamilton-Jacobi-Bellman inequality for solving periodic optimization problems and look at multi-objective semi-infinite optimization problems, and production planning problems.  In the second part, the authors address techniques and applications of optimization and control in a variety of disciplines, such as chaos synchronization, facial expression recognition and dynamic input-output economic models. Other applications considered here include image retr...

  12. Preparation of Au Nanoparticles Immobilized Cross-Linked Poly(4-vinylpyridine) Nanofibers and Their Catalytic Application for the Reduction of 4-Nitrophenol.

    Science.gov (United States)

    Qin, Qi-Hu; Na, Hui; Zhang, Chunyu; Yu, Qizhou; Zhang, Xue-Quan; Zhang, He-Xin

    2015-05-01

    Catalytic nanofibers are prepared by the immobilization of Au nanoparticles (AuNPs) onto the surface of cross-linked electrospun poly(4-vinylpyridine) (P4VP) nanofibers. The crosslinking of the P4VP nanofibers by 1,4-diiodobutane via quaternization reaction greatly enhances the stability of the nanofibers against the solvent dissolution, which can then be used as promising platform for the immobilization of catalytic metal nanoparticles. The AuNPs immobilized cross-linked P4VP nanofibers have shown a good catalytic activity for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). PMID:26505022

  13. Au-Loaded Titanium Dioxide Nanoparticles Synthesized by Modified Sol-Gel/Impregnation Methods and Their Application to Dye-Sensitized Solar Cells

    OpenAIRE

    Hathaithip Ninsonti; Weerasak Chomkitichai; Akira Baba; Natda Wetchakun; Wiyong Kangwansupamonkon; Sukon Phanichphant; Kazunari Shinbo; Keizo Kato; Futao Kaneko

    2014-01-01

    Au-loaded TiO2 nanoparticles were synthesized by the modified sol-gel method together with the impregnation method. Anatase phase of TiO2 was obtained in all samples with an average particle size of 20 nm. For the enhancement of DSSCs, the dye-sensitized solar cells composed of the ITO/Au-loaded TiO2/N-719/electrolyte/Pt were fabricated. Au-loaded TiO2 films were deposited by using squeegee method. Finally, the fabricated cells were studied upon an irradiation of solar light to study the perf...

  14. Facile synthesis and intraparticle self-catalytic oxidation of dextran-coated hollow Au-Ag nanoshell and its application for chemo-thermotherapy.

    Science.gov (United States)

    Jang, Hongje; Kim, Young-Kwan; Huh, Hyun; Min, Dal-Hee

    2014-01-28

    Galvanic replacement reaction is a useful method to prepare various hollow nanostructures. We developed fast and facile preparation of biocompatible and structurally robust hollow Au-Ag nanostructures by using dextran-coated Ag nanoparticles. Oxidation of the surface dextran alcohols was enabled by catalytic activity of the core Au-Ag nanostructure, introducing carbonyl groups that are useful for further bioconjugation. Subsequent doxorubicin (Dox) conjugation via Schiff base formation was achieved, giving high payload of approximately 35 000 Dox per particle. Near-infrared-mediated photothermal conversion showed high efficacy of the Dox-loaded Au-Ag nanoshell as a combinational chemo-thermotherapy to treat cancer cells. PMID:24383549

  15. Applications of artificial intelligence to reactor and plant control

    International Nuclear Information System (INIS)

    Potential improvements in plant efficiency and reliability are often cited as reasons for developing and applying artificial intelligence (AI) techniques, principally expert systems, to the control and operation of nuclear reactors. Nevertheless, there have been few such applications and then mostly at the prototype level. Therefore, if AI techniques are to contribute to process control, methods must be identified by which rule-based and analytic approaches can be merged. This hypothesis is the basic premise of this article. Presented below are 1. a brief review of the human approach towards process control, 2. a discussion of the suitability of AI methodologies for the performance of control tasks, 3. examples of AI applications to both open- and closed-loop control, 4. an enumeration of unresolved issues associated with the use of AI for control, and 5. a discussion of the possible role of expert system techniques in process control. (orig./GL)

  16. Plasmon-controlled narrower and blue-shifted fluorescence emission in (Au-SiO{sub 2})SiC nanohybrids

    Energy Technology Data Exchange (ETDEWEB)

    Sui Ning; Monnier, Virginie, E-mail: virginie.monnier@ec-lyon.fr [Institut des Nanotechnologies de Lyon-INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, Universite de Lyon (France); Zakharko, Yuriy [Institut des Nanotechnologies de Lyon-INL-UMR 5270-CNRS, Site INSA Lyon, Universite de Lyon (France); Chevolot, Yann [Institut des Nanotechnologies de Lyon-INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, Universite de Lyon (France); Alekseev, Sergei [Kiev National Taras Schevchenko University, Faculty of Chemistry (Ukraine); Bluet, Jean-Marie; Lysenko, Vladimir [Institut des Nanotechnologies de Lyon-INL-UMR 5270-CNRS, Site INSA Lyon, Universite de Lyon (France); Souteyrand, Eliane [Institut des Nanotechnologies de Lyon-INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, Universite de Lyon (France)

    2012-08-15

    Fluorescent imaging is a key tool in biology. On one hand, organic dyes are subjected to bleaching; while, on the other hand II-VI semiconductor quantum dots are photostable, but may exhibit some toxicity. Silicon carbide nanoparticles (SiC NPs) are a good alternative as SiC is chemically inert and considered as biocompatible material. However, their fluorescence quantum yield is weak. Plasmon-controlled fluorescence appears as a mean to enhance SiC NPs fluorescence. To this aim, new fluorescent nanohybrids (NHs) involving a gold colloid surrounded by a silica shell and overcoated with SiC NPs have been engineered. Au-SiO{sub 2} particles were synthesized via a sol-gel method to obtain a controlled thickness of silica around gold colloid. Then, SiC NPs were immobilized onto silica by covalent bonding. TEM was used to study the structural properties of NHs. The influence of several parameters on NHs' fluorescence properties was investigated. It reveals that excitation wavelength must be chosen as close as possible to the gold plasmon band to avoid quenching of emission due to energy transfer between gold absorption and SiC emission. Moreover, the silica thickness is a key parameter to obtain high enhancement; for gold colloids of 20 nm in diameter overcoated by a 25 nm shell, an enhancement factor as high as 12.5 was obtained with a narrower and blue-shifted emission band. This blue-shift can be attributed to the surface chemistry modification of SiC NPs when they are covalently bonded to silica.

  17. Future applications of artificial intelligence to Mission Control Centers

    Science.gov (United States)

    Friedland, Peter

    1991-01-01

    Future applications of artificial intelligence to Mission Control Centers are presented in the form of the viewgraphs. The following subject areas are covered: basic objectives of the NASA-wide AI program; inhouse research program; constraint-based scheduling; learning and performance improvement for scheduling; GEMPLAN multi-agent planner; planning, scheduling, and control; Bayesian learning; efficient learning algorithms; ICARUS (an integrated architecture for learning); design knowledge acquisition and retention; computer-integrated documentation; and some speculation on future applications.

  18. Aspect ratio control of Au nanorods via covariation of the total amount of HAuCl4 and ascorbic acid

    International Nuclear Information System (INIS)

    Highlights: • The AR value decreased as the total amount of [HAuCl4] and [AA] increasing. • The UV–vis absorption spectra showed the peak wavelength of TSPR at around 530 nm. • The wavelength of LSPR had a red-shifted effect. - Abstract: Controlling the aspect ratio (AR) of gold nanorods (GNRs) via covariation of the total concentrations of HAuCl4 ([HAuCl4]) and ascorbic acid ([AA]) has been studied. Characteristics of GNRs were examined by transmission electron microscopy (TEM) and ultraviolet–visible (UV–vis) absorption spectrophotometry. TEM results showed that single crystalline GNRs grew along an elongated growth direction of [100]. TEM results also revealed that the quantity of plate shaped and nearly spherical nanoparticles increased as the total amount of [HAuCl4] and [AA] decreased. The AR value measured from TEM images decreased from 4.74 to 2.41 as the total amount of [HAuCl4] and [AA] was increased from 0.305 to 2.44 mM. The UV–vis absorption spectra of all samples showed that the wavelength of transverse surface plasmon resonance (TSPR) peak appeared at around 530 nm for all samples. The wavelength of longitudinal surface plasmon resonance (LSPR) peak increased from 640 to 894 nm as the total amount of [HAuCl4] and [AA] decreased from 2.44 to 0.305 mM. The wavelength of LSPR peak shows a red-shifted effect except when the total amount of [HAuCl4] and [AA] was 0.122 mM

  19. Applications of Circulation Control, Yesterday and Today

    OpenAIRE

    Jonathan Kweder; Chad C. Panthe; James E. Smit

    2010-01-01

    Circulation control, an aerodynamic method of changing the properties of an airfoil, such as lift, camber and angle of attack, has been used in several unique ways since its inception, as an enhancement to fixed wing aircraft, in the 1960’s. Early in the research venture, this technology was used on the main wing of an aircraft in conjunction with a Coandă surface, such as a rounded trailing edge or a deployable flap. Research during this time proved to be the foundation of the circulation co...

  20. Weapon Control System for Airborne Application.

    OpenAIRE

    M. Sankar Kishore

    2000-01-01

    The integrated fire' control system (IFCS) plays an important role in the present-day fighter aircraft and helicopters. Wecapons, such as missiles (active/passive), rockets and guns may be present on thelfighter aircraft or helicopter .IFCS monitors the status of the weapons present on the vehicle and passes the information to pilot/co-pilot. Depending upon the health/availability of the weapons, IFCS selects/fires the weapons. An attempt has been made to bring out the details of one such IFC...

  1. Development of operator requested control system applications: Experience with the SLC control system at SLAC

    International Nuclear Information System (INIS)

    The SLC Control system at SLAC has evolved into a powerful tool for operation of the accelerator and for troubleshooting the unique problems encountered in extracting maximum performance from the SLC. The evolution has included the development of many custom applications and user interface features generated from accelerator operator and accelerator physicist requests. These applications are written and maintained primarily by the Controls Software Engineering group, and not by the users themselves. The process of developing and supporting user requested control systems applications at SLAC is described, including the effects of organizational structure, formal and informal procedures, and control system architecture

  2. Détection d'intrusions comportementale par diversification de COTS : application au cas des serveurs web

    OpenAIRE

    Majorczyk, Frédéric

    2008-01-01

    version non-définitive de la thèse, présentée lors de la soutenance. L'informatique et en particulier l'Internet jouent un rôle grandissant dans notre société. Un grand nombre d'applications critiques d'un point de vue de leur sécurité sont déployées dans divers domaines comme le domaine militaire, la santé, le commerce électronique, etc. La sécurité des systèmes informatiques devient alors une problématique essentielle tant pour les individus que pour les entreprises ou les états. Il est ...

  3. 76 FR 25374 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2011-05-04

    ... bulk manufacture controlled substances in Active Pharmaceutical Ingredient (API) form. The company... of Application pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for... published in the Federal Register on September 23, 1975, 40 FR 43745, all applicants for registration...

  4. 75 FR 36680 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2010-06-28

    ... manufacture controlled substances in Active Pharmaceutical Ingredient (API) form. The company distributes the... pertaining to Rhodes Technologies, 72 FR 3417 (2007), comments and requests for hearings on applications to... Register on September 23, 1975, (40 FR 43745), all applicants for registration to import a basic class...

  5. Revisiting the S-Au(111) interaction: Static or Dynamic?

    Energy Technology Data Exchange (ETDEWEB)

    Biener, M M; Biener, J; Friend, C M

    2004-08-17

    The chemical inertness typically observed for Au does not imply a general inability to form stable bonds with non-metals but is rather a consequence of high reaction barriers. The Au-S interaction is probably the most intensively studied interaction of Au surfaces with non-metals as, for example, it plays an important role in Au ore formation, and controls the structure and dynamics of thiol-based self-assembled-monolayers (SAMs). In recent years a quite complex picture of the interaction of sulfur with Au(111) surfaces emerged, and a variety of S-induced surface structures was reported under different conditions. The majority of these structures were interpreted in terms of a static Au surface, where the positions of the Au atoms remain essentially unperturbed. Here we demonstrate that the Au(111) surface exhibits a very dynamic character upon interaction with adsorbed sulfur: low sulfur coverages modify the surface stress of the Au surface leading to lateral expansion of the surface layer; large-scale surface restructuring and incorporation of Au atoms into a growing two-dimensional AuS phase were observed with increasing sulfur coverage. These results provide new insight into the Au-S surface chemistry, and reveal the dynamic character of the Au(111) surface.

  6. Multimodel Approach for Intelligent Control and Applications

    Institute of Scientific and Technical Information of China (English)

    Abdelkader El Kamel; Pierre Borne

    2004-01-01

    The use of the multimodel approach in the modelling, analysis and control of non-linear complex and/or ill-defined systems was advocated by many researchers. This approach supposes the definition of a set of local models valid in a given region or domain. Different strategies exist in the literature and are generally based on a partitioning of the non-linear system's full range of operation into multiple smaller operating regimes each of which is associated with a locally valid model or controller. However, most of these strategies, which suppose the determination of these local models as well as their validity domain, remain arbitrary and are generally fixed thanks to a certain a priori knowledge of the system whatever its order. Recently, we have proposed a new approach to derive a multimodel basis which allows us to limit the number of models in the basis to almost four models. Meanwhile, the transition problem between the different models, which may use either a simple commutation or a fusion technique, remains still arise. In this plenary talk, a fuzzy fusion technique is presented and has the following main advantages: (1) use of a fuzzy partitioning in order to determine the validity of each model which enhances the robustness of the solution; (2) introduction, besides the four extreme models, of another model, called average model, determined as an average of the boundary models.

  7. Application of Object-Based Industrial Controls for Cryogenics

    CERN Document Server

    Casas-Cubillos, J; Gomes, P; Pezzetti, M; Sicard, Claude Henri; Varas, F J

    2002-01-01

    The first application of the CERN Unified Industrial Control system (UNICOS) has been developed for the 1.8 K refrigerator at point 1.8 in mid-2001. This paper presents the engineering methods used for application development, in order to reach the objectives of maintainability and reusability, in the context of a development done by an external consortium of engineering firms. It will also review the lessons learned during this first development and the improvements planned for the next applications.

  8. A Mobile Application for Smart House Remote Control System

    OpenAIRE

    Rajabzadeh, Amir; Manashty, Ali Reza; Jahromi, Zahra Forootan

    2010-01-01

    At the start of the second decade of 21th century, the time has come to make the Smart Houses a reality for regular use. The different parts of a Smart House are researched but there are still distances from an applicable system, using the modern technology. In this paper we present an overview of the Smart House subsystems necessary for controlling the house using a mobile application efficiently and securely. The sequence diagram of the mobile application connecting to the server applicatio...

  9. Structural control and metamorphic setting of the shear zone-related Au vein mineralization of the Adola Belt (southern Ethiopia) and its tectono-genetic development

    Science.gov (United States)

    Worku, H.

    1996-10-01

    Structural study of the Adola Belt shows that most of its known and potential Au deposits occur in quartz veins which are localised within shear contacts between lithological units, and along major shear zones that divide the Adola Belt into different lithostructural domains. Analysis of the shear zone-related ore bodies and their host volcano-sedimentary succession and gneisses indicates that Au mineralization in the Adola Belt is pre-dated by two stages of deformation and a regional prograde metamorphism. The first deformation event (D 1) is a fold-and-thrust event which is characterised by low-angle thrusts, associated recumbent folds and axial planar S 1 foliation, and is related to nappe-style deformation. The second event (D 2) has folded and/or reactivated the thrust-related structures and formed upright folds and high-angle reverse shear zones and is related to the collision event. Gold mineralization occurred over a prolonged deformation history but is closely related to alteration, retrograde greenschistfacies assemblages and brittle-ductile deformation of late D 2 and D 3 transpressional shear zones that accommodate regional shortening both by crustal thickening and lateral displacement. The mineralization occurs in associated dilational jogs or bends that might have formed during the lateral or vertical expulsion. The Au-hosting shear zones are characterised by extensive development of heterogeneous mylonitic fault rocks which reveals that the accompanied deformation is characterised by processes that can increase the porosity and permeability of the rocks within the shear zones. This gave rise to further extensive dilatancy within the major dilational jogs and produced a suitable structural regime for vein-hosted Au mineralization. This implies that the Au mineralization is epigenetic in origin and that it resulted from precipitation from metamorphic hydrothermal fluids circulating through major shear zones and associated structures late during the

  10. Controllable edge feature sharpening for dental applications.

    Science.gov (United States)

    Fan, Ran; Jin, Xiaogang

    2014-01-01

    This paper presents a new approach to sharpen blurred edge features in scanned tooth preparation surfaces generated by structured-light scanners. It aims to efficiently enhance the edge features so that the embedded feature lines can be easily identified in dental CAD systems, and to avoid unnatural oversharpening geometry. We first separate the feature regions using graph-cut segmentation, which does not require a user-defined threshold. Then, we filter the face normal vectors to propagate the geometry from the smooth region to the feature region. In order to control the degree of the sharpness, we propose a feature distance measure which is based on normal tensor voting. Finally, the vertex positions are updated according to the modified face normal vectors. We have applied the approach to scanned tooth preparation models. The results show that the blurred edge features are enhanced without unnatural oversharpening geometry. PMID:24741376

  11. Voltage controlled spintronic devices for logic applications

    Science.gov (United States)

    You, Chun-Yeol; Bader, Samuel D.

    2001-01-01

    A reprogrammable logic gate comprising first and second voltage-controlled rotation transistors. Each transistor comprises three ferromagnetic layers with a spacer and insulating layer between the first and second ferromagnetic layers and an additional insulating layer between the second and third ferromagnetic layers. The third ferromagnetic layer of each transistor is connected to each other, and a constant external voltage source is applied to the second ferromagnetic layer of the first transistor. As input voltages are applied to the first ferromagnetic layer of each transistor, the relative directions of magnetization of the ferromagnetic layers and the magnitude of the external voltage determines the output voltage of the gate. By altering these parameters, the logic gate is capable of behaving as AND, OR, NAND, or NOR gates.

  12. Ultra-relativistic Au+Au and d+Au collisions:

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Hauer, M.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Seals, H.; Sedykh, I.; Skulski, W.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Wenger, E.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    In this talk I will review PHOBOS data on charged particle multiplicities, obtained in Au+Au and d+Au collisions at RHIC. The general features of the Au+Au pseudorapidity distributions results will be discussed and compared to those of /line{p}p collisions. The total charged particle multiplicity, scaled by the number of participant pairs, is observed to be about 40% higher in Au+Au collisions than in /line{p}p and d+Au systems, but, surprisingly at the same level of e+e- collisions. Limiting fragmentation scaling is seen to be obeyed in Au+Au collisions.

  13. Controlled Vocabulary Service Application for Environmental Data Store

    Science.gov (United States)

    Ji, P.; Piasecki, M.; Lovell, R.

    2013-12-01

    In this paper we present a controlled vocabulary service application for Environmental Data Store (EDS). The purpose for such application is to help researchers and investigators to archive, manage, share, search, and retrieve data efficiently in EDS. The Simple Knowledge Organization System (SKOS) is used in the application for the representation of the controlled vocabularies coming from EDS. The controlled vocabularies of EDS are created by collecting, comparing, choosing and merging controlled vocabularies, taxonomies and ontologies widely used and recognized in geoscience/environmental informatics community, such as Environment ontology (EnvO), Semantic Web for Earth and Environmental Terminology (SWEET) ontology, CUAHSI Hydrologic Ontology and ODM Controlled Vocabulary, National Environmental Methods Index (NEMI), National Water Information System (NWIS) codes, EPSG Geodetic Parameter Data Set, WQX domain value etc. TemaTres, an open-source, web -based thesaurus management package is employed and extended to create and manage controlled vocabularies of EDS in the application. TemaTresView and VisualVocabulary that work well with TemaTres, are also integrated in the application to provide tree view and graphical view of the structure of vocabularies. The Open Source Edition of Virtuoso Universal Server is set up to provide a Web interface to make SPARQL queries against controlled vocabularies hosted on the Environmental Data Store. The replicas of some of the key vocabularies commonly used in the community, are also maintained as part of the application, such as General Multilingual Environmental Thesaurus (GEMET), NetCDF Climate and Forecast (CF) Standard Names, etc.. The application has now been deployed as an elementary and experimental prototype that provides management, search and download controlled vocabularies of EDS under SKOS framework.

  14. An application of modern control theory to an elastic spacecraft

    Science.gov (United States)

    Larson, V.; Likins, P. W.

    1976-01-01

    Results are presented to illustrate the application of established procedures of linear, quadratic, Gaussian optimal estimation and control to a spacecraft with dynamically significant elastic appendages. Interpretations are provided in both time domain and frequency domain, and conclusions are drawn for a wide class of problems of flexible spacecraft attitude control.

  15. Spatially-controlled complex molecules and their applications

    CERN Document Server

    Chang, Yuan-Pin; Trippel, Sebastian; Küpper, Jochen

    2015-01-01

    The understanding of molecular structure and function is at the very heart of the chemical and molecular sciences. Experiments that allow for the creation of structurally pure samples and the investigation of their molecular dynamics and chemical function have developed tremendeously over the last few decades, although "there's plenty of room at the bottom" for better control as well as further applications. Here, we describe the use of inhomogeneous electric fields for the manipulation of neutral molecules in the gas-phase, \\ie, for the separation of complex molecules according to size, structural isomer, and quantum state. Current applications of these controlled samples are summarized and interesting future applications discussed.

  16. Sonochemical fabrication of CdSe{sub x}Te{sub 1-x}/Au nanotubes and their potential application in biosensing

    Energy Technology Data Exchange (ETDEWEB)

    Lu Feng; Liu Shanhu, E-mail: liushanhu@163.com; Jiang Liping; Zhu Junjie, E-mail: jjzhu@nju.edu.cn [Nanjing University, State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering (China)

    2013-01-15

    CdSe{sub x}Te{sub 1-x} semiconductor alloy nanotubes (with an external diameter of 140 nm and an internal diameter of 100 nm) were successfully prepared based on the sacrificial template of Cd(OH)Cl nanorods, and were further in situ assembled with gold nanoparticles (AuNPs) via a sonochemical approach to form the CdSe{sub x}Te{sub 1-x}/Au nanotubes. The prepared CdSe{sub x}Te{sub 1-x}/Au nanotubes were characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive spectrometry, and X-ray photoelectron spectra. CdSe{sub x}Te{sub 1-x}/Au nanotubes could integrate the advantages of the electronic properties of CdSeTe and the biocompatible properties of AuNPs. A novel biosensor was fabricated after the immobilization of hemoglobin (Hb) on CdSe{sub x}Te{sub 1-x}/Au nanotubes. The immobilized Hb exhibited fast direct electron transfer and good electrocatalytic performance to H{sub 2}O{sub 2}.

  17. Synthesis of double-shelled sea urchin-like yolk-shell Fe3O4/TiO2/Au microspheres and their catalytic applications

    International Nuclear Information System (INIS)

    Double-shelled sea urchin-like yolk-shell Fe3O4/TiO2/Au microspheres were successfully synthesized through loading Au nanoparticles on the Fe3O4/TiO2 support by a in situ reduction of HAuCl4 with NaBH4 aqueous solution. These microspheres possess tunable cavity size, adjustable shell layers, high structural stability and large specific surface area. The Au nanoparticles of approximately 5 nm in diameter were loaded both on the TiO2 nanofibers and inside the cavities of sea urchin-like yolk-shell Fe3O4/TiO2 microspheres. The sea urchin-like structure composed of TiO2 nanofibers ensure the good distribution of the Au nanoparticles, while the novel double-shelled yolk-shell structure guarantees the high stability of the Au nanoparticles. Furthermore, the Fe3O4 magnetic core facilitates the convenient recovery of the catalyst by applying an external magnetic field. The Fe3O4/TiO2/Au microspheres display excellent activities and recycling properties in the catalytic reduction of 4-nitrophenol (4-NP): the rate constant is 1.84 min−1 and turnover frequency is 5457 h−1. (paper)

  18. A study on the effect of low energy ion beam irradiation on Au/TiO2 system for its application in photoelectrochemical splitting of water

    Science.gov (United States)

    Verma, Anuradha; Srivastav, Anupam; Sharma, Dipika; Banerjee, Anamika; Sharma, Shailja; Satsangi, Vibha Rani; Shrivastav, Rohit; Avasthi, Devesh Kumar; Dass, Sahab

    2016-07-01

    Nanostructured TiO2 thin films were deposited on indium tin oxide (ITO) substrate via sol-gel technique and were modified by plasmonic Au layer. The plasmonic Au modified TiO2 (Au/TiO2) thin films were then irradiated with 500 keV Ar2+ ion beam at different ion fluences viz. 1 × 1016, 3 × 1016 and 1 × 1017 to study the effect of nuclear energy deposition on the morphology, crystallinity, band gap, surface plasmon resonance (SPR) peak exhibited by Au particles and photoelectrochemical properties of the system. Prepared thin films were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM), Rutherford backscattering spectrometry (RBS) measurements and UV-visible spectroscopy. The photoelectrochemical measurements revealed that both Au/TiO2 and Au/TiO2 thin film irradiated at 1 × 1016 fluence exhibits enhanced photoelectrochemical response in comparison to pristine TiO2. The film irradiated at 1 × 1016 fluence offered maximum applied bias photon-to-current efficiency (ABPE) and shows 6 times increment in photocurrent density which was attributed to more negative flat band potential, maximum decrease in band gap, high open circuit voltage (Voc) and reduced charge transfer resistance.

  19. Stability and Sensitivity Analysis of Fuzzy Control Systems. Mechatronics Applications

    Directory of Open Access Journals (Sweden)

    Radu-Emil Precup

    2006-01-01

    Full Text Available The development of fuzzy control systems is usually performed by heuristicmeans, incorporating human skills, the drawback being in the lack of general-purposedevelopment methods. A major problem, which follows from this development, is theanalysis of the structural properties of the control system, such as stability, controllabilityand robustness. Here comes the first goal of the paper, to present a stability analysismethod dedicated to fuzzy control systems with mechatronics applications based on the useof Popov’s hyperstability theory. The second goal of this paper is to perform the sensitivityanalysis of fuzzy control systems with respect to the parametric variations of the controlledplant for a class of servo-systems used in mechatronics applications based on theconstruction of sensitivity models. The stability and sensitivity analysis methods provideuseful information to the development of fuzzy control systems. The case studies concerningfuzzy controlled servo-systems, accompanied by digital simulation results and real-timeexperimental results, validate the presented methods.

  20. Applicability of the Fuzzy Logic Controllers for the Steam Generator Level Control

    International Nuclear Information System (INIS)

    The fuzzy logic controllers are found to provide real advantages for some control problems. They are actually being used in consumer products made in Japan or in Korea. For the application of the fuzzy logic controllers to the nuclear power plants, there have been several preliminary studies most of which are related to the steam generator level control where the enhancement of the controller capability is mostly needed. In this paper, we examine the possibility of their applications to the nuclear power plants, We start with a brief discussion on how to build a fuzzy algorithm and how to generate an equivalent analytic form of the algorithm, and then propose a method using the artificial neural network technique for the tuning of the controller. Finally, we examine the major licensing problems related to the application of the fuzzy logic controllers to the nuclear power plants

  1. Application of Lanczos vectors to control design of flexible structures

    Science.gov (United States)

    Craig, Roy R., Jr.; Su, Tzu-Jeng

    1990-01-01

    This report covers research conducted during the first year of the two-year grant. The research, entitled 'Application of Lanczos Vectors to Control Design of Flexible Structures' concerns various ways to obtain reduced-order mathematical models for use in dynamic response analyses and in control design studies. This report summarizes research described in several reports and papers that were written under this contract. Extended abstracts are presented for technical papers covering the following topics: controller reduction by preserving impulse response energy; substructuring decomposition and controller synthesis; model reduction methods for structural control design; and recent literature on structural modeling, identification, and analysis.

  2. Inductive Logic Programming for Industrial Control Applications

    Directory of Open Access Journals (Sweden)

    Samiya Bouarroudj

    2014-04-01

    Full Text Available Advanced Monitoring Systems of the processes consti tute a higher level to the systems of control and use specific techniques and methods. An importa nt part of the task of supervision focuses on the detection and the diagnosis of various situatio ns of faults which can affect the process. Methods of fault detection and diagnosis (FDD are different from the type of knowledge about the process that they require. They can be classifi ed as data-driven, analytical, or knowledge- based approach. A collaborative FDD approach that c ombines the strengths of various heterogeneous FDD methods is able to maximize diagn ostic performance. The new generation of knowledge-based systems or decision support syst ems needs to tap into knowledge that is both very broad, but specific to a domain, combinin g learning, structured representations of domain knowledge such as ontologies and reasoning t ools. In this paper, we present a decision- aid tool in case of malfunction of high power indus trial steam boiler. For this purpose an ontology was developed and considered as a prior co nceptual knowledge in Inductive Logic Programming (ILP for inducing diagnosis rules. The next step of the process concerns the inclusion of rules acquired by induction in the kno wledge base as well as their exploitation for reasoning.

  3. Redesigning an Infection Control Application to Support an Enterprise Model

    OpenAIRE

    Doherty, Joshua A.; Huang, Christine; Mayfield, Jennie; Dunagan, Wm Claiborne; Bailey, Thomas C.

    2005-01-01

    As the demands on hospital infection control teams increase, it becomes less efficient for them to use paper-based surveillance methods. The existing electronic infection control surveillance system at our largest facility was not designed to support a multi-hospital model. Our goal was to redesign the application using generic, open source technologies, and make it flexible enough to support the infection control surveillance needs of the entire enterprise.

  4. Application of programmable logic controller in nuclear experiments

    International Nuclear Information System (INIS)

    The applicability of programmable logic controller (PLC) in nuclear experiments was studied on an example that simulated the monitoring and control of an ion beam in an accelerator. Using infrared and laser light, a comparison was made between the complexity and suitability of PLC compared to a setup using a personal computer. The experiments are described in detail. The routines for registration of signals from appropriate sensors and for control of the stepper monitor were written in quick BASIC. (author). 5 figs

  5. Distributed, Modular, Network Enabled Architecture For Process Control Military Applications

    OpenAIRE

    Abhijit Kamble*,; Ashish Dubey

    2014-01-01

    In process control world, use of distributed modular embedded controller architecture drastically reduces the number and complexity of cabling; at the same time increases the system computing performance and response for real time application as compared to centralized control system. We propose a design based on ARM Cortex M4 hardware architecture and Cortex Microcontroller Software Interface Standard (CMSIS) based software development. The ARM Cortex-M series ensures a compa...

  6. Current Controlled Current Differencing Buffered Amplifier: Implementation and Applications

    Directory of Open Access Journals (Sweden)

    Sudhanshu Maheshwari

    2004-01-01

    Full Text Available A new four terminal current-controlled active element is introduced, where parasitic resistances at two current input ports are controlled leading to the definition of current-controlled current differencing buffered amplifier. Bipolar implementation and as application current-mode band-pass filter circuits are proposed. Simulation results using real device parameters are included, which show device bandwidth of 35 MHz, low total harmonic distortions, and tuning over a wide current range.

  7. Application of reflective memory network in Tokamak fast controller

    International Nuclear Information System (INIS)

    A specific application of reflective memory network in Tokamak fast controller was introduced in this paper. The PMC-5565 reflective memory card and ACC-5565 network hub were used to build a reflective memory real-time network to test its real- time function. The real-time, rapidity and determinacy of the time delay for fast controller controlling power device under the reflective memory network were tested in the LabVIEW RT real-time operation system. Depending on the reflective memory technology, the data in several fast controllers were synchronized, and multiple control tasks using a single control task were finished. The experiment results show that the reflective memory network can meet the real-time requirements for fast controller to perform the feedback control over devices. (authors)

  8. A further discussion of the factors controlling the distribution of Pt, Pd, Rh and Au in road dust, gullies, road sweeper and gully flusher sediment in the city of Sheffield, UK.

    Science.gov (United States)

    Prichard, H M; Sampson, J; Jackson, M

    2009-02-15

    Forty paired road dust and gully sediments from the city of Sheffield in NE England show that high platinum, palladium and rhodium concentrations derived from catalytic converters depend on proximity to both roundabouts rather than traffic lights and to topographic lows. Road dust outside schools and control samples, further away on the same road, show that Pt, Pd and Rh concentrations are dependent on passing traffic flow rather than numbers of stopping vehicles. Highest values of Pt+Pd in road dust are 852 ppb and 694 ppb in gullies. Rh has maximum values of 113 ppb in road dust and 49 ppb in gullies. Pt and Pd values of a few ppb to just over 100 ppb occur in road dust where traffic does not stop, on roads away from junctions. Pt, Pd, Rh and Au are all picked up by road sweepers and gully flushers both with maximum values of just over 100 ppb Pt and Pd. High Au values (maximum 610 ppb in a road dust) were located on pavements, in suburbs, outside schools and in road sweepers collecting in residential areas rather than on high traffic flow roads. Stratification of Pt and Pd in gullies was not observed whereas a high Au value was recorded at the bottom of a gully suggesting gravity concentration for Au. Anomalous Pd grades of 1050 ppb in road dust from a school entrance and 2040 ppb in a street sweeper sample were recorded. These high Pd- and Au-bearing samples do not have anomalous Pt or Rh values and may be sourced from jewellery or dental fillings. However, most samples have consistent Pt/Pd ratios of about 1 and Pt/Rh values of 4 to 5 indicating a catalytic converter source. Pt and Pd are concentrated in road dust at levels well above background in all the samples, including on high and low traffic flow roads. PMID:19081605

  9. Intelligent control based on intelligent characteristic model and its application

    Institute of Scientific and Technical Information of China (English)

    吴宏鑫; 王迎春; 邢琰

    2003-01-01

    This paper presents a new intelligent control method based on intelligent characteristic model for a kind of complicated plant with nonlinearities and uncertainties, whose controlled output variables cannot be measured on line continuously. The basic idea of this method is to utilize intelligent techniques to form the characteristic model of the controlled plant according to the principle of combining the char-acteristics of the plant with the control requirements, and then to present a new design method of intelli-gent controller based on this characteristic model. First, the modeling principles and expression of the intelligent characteristic model are presented. Then based on description of the intelligent characteristic model, the design principles and methods of the intelligent controller composed of several open-loops and closed-loops sub controllers with qualitative and quantitative information are given. Finally, the ap-plication of this method in alumina concentration control in the real aluminum electrolytic process is in-troduced. It is proved in practice that the above methods not only are easy to implement in engineering design but also avoid the trial-and-error of general intelligent controllers. It has taken better effect in the following application: achieving long-term stable control of low alumina concentration and increasing the controlled ratio of anode effect greatly from 60% to 80%.

  10. Structural, electronic and magnetic properties of Au-based monolayer derivatives in honeycomb structure

    Science.gov (United States)

    Kapoor, Pooja; Sharma, Munish; Kumar, Ashok; Ahluwalia, P. K.

    2016-05-01

    We present electronic properties of atomic layer of Au, Au2-N, Au2-O and Au2-F in graphene-like structure within the framework of density functional theory (DFT). The lattice constant of derived monolayers are found to be higher than the pristine Au monolayer. Au monolayer is metallic in nature with quantum ballistic conductance calculated as 4G0. Similarly, Au2-N and Au2-F monolayers show 4G0 and 2G0 quantum conductance respectively while semiconducting nature with calculated band gap of 0.28 eV has been observed for Au2-O monolayer. Most interestingly, half metalicity has been predicted for Au2-N and Au2-F monolayers. Our findings may have importance for the application of these monolayers in nanoelectronic and spintronics.

  11. Wearable Device Control Platform Technology for Network Application Development

    Directory of Open Access Journals (Sweden)

    Heejung Kim

    2016-01-01

    Full Text Available Application development platform is the most important environment in IT industry. There are a variety of platforms. Although the native development enables application to optimize, various languages and software development kits need to be acquired according to the device. The coexistence of smart devices and platforms has rendered the native development approach time and cost consuming. Cross-platform development emerged as a response to these issues. These platforms generate applications for multiple devices based on web languages. Nevertheless, development requires additional implementation based on a native language because of the coverage and functions of supported application programming interfaces (APIs. Wearable devices have recently attracted considerable attention. These devices only support Bluetooth-based interdevice communication, thereby making communication and device control impossible beyond a certain range. We propose Network Application Agent (NetApp-Agent in order to overcome issues. NetApp-Agent based on the Cordova is a wearable device control platform for the development of network applications, controls input/output functions of smartphones and wearable/IoT through the Cordova and Native API, and enables device control and information exchange by external users by offering a self-defined API. We confirmed the efficiency of the proposed platform through experiments and a qualitative assessment of its implementation.

  12. Complex systems and networks dynamics, controls and applications

    CERN Document Server

    Yu, Xinghuo; Chen, Guanrong; Yu, Wenwu

    2016-01-01

    This elementary book provides some state-of-the-art research results on broad disciplinary sciences on complex networks. It presents an in-depth study with detailed description of dynamics, controls and applications of complex networks. The contents of this book can be summarized as follows. First, the dynamics of complex networks, for example, the cluster dynamic analysis by using kernel spectral methods, community detection algorithms in bipartite networks, epidemiological modeling with demographics and epidemic spreading on multi-layer networks, are studied. Second, the controls of complex networks are investigated including topics like distributed finite-time cooperative control of multi-agent systems by applying homogenous-degree and Lyapunov methods, composite finite-time containment control for disturbed second-order multi-agent systems, fractional-order observer design of multi-agent systems, chaos control and anticontrol of complex systems via Parrondos game and many more. Third, the applications of ...

  13. Selective data collection in vehicular networks for traffic control applications

    CERN Document Server

    Płaczek, Bartłomiej

    2011-01-01

    Vehicular sensor network (VSN) is an emerging technology, which combines wireless communication offered by vehicular ad hoc networks (VANET) with sensing devices installed in vehicles. VSN creates a huge opportunity to extend the road-side sensor infrastructure of existing traffic control systems. The efficient use of the wireless communication medium is one of the basic issues in VSN applications development. This paper introduces a novel method of selective data collection for traffic control applications, which provides a significant reduction in data amounts transmitted through VSN. The underlying idea is to detect the necessity of data transfers on the basis of uncertainty determination of the traffic control decisions. According to the proposed approach, sensor data are transmitted from vehicles to the control node only at selected time moments. Data collected in VSN are processed using on-line traffic simulation technique, which enables traffic flow prediction, performance evaluation of control strateg...

  14. Access Control of Web- and Java-Based Applications

    Science.gov (United States)

    Tso, Kam S.; Pajevski, Michael J.

    2013-01-01

    Cybersecurity has become a great concern as threats of service interruption, unauthorized access, stealing and altering of information, and spreading of viruses have become more prevalent and serious. Application layer access control of applications is a critical component in the overall security solution that also includes encryption, firewalls, virtual private networks, antivirus, and intrusion detection. An access control solution, based on an open-source access manager augmented with custom software components, was developed to provide protection to both Web-based and Javabased client and server applications. The DISA Security Service (DISA-SS) provides common access control capabilities for AMMOS software applications through a set of application programming interfaces (APIs) and network- accessible security services for authentication, single sign-on, authorization checking, and authorization policy management. The OpenAM access management technology designed for Web applications can be extended to meet the needs of Java thick clients and stand alone servers that are commonly used in the JPL AMMOS environment. The DISA-SS reusable components have greatly reduced the effort for each AMMOS subsystem to develop its own access control strategy. The novelty of this work is that it leverages an open-source access management product that was designed for Webbased applications to provide access control for Java thick clients and Java standalone servers. Thick clients and standalone servers are still commonly used in businesses and government, especially for applications that require rich graphical user interfaces and high-performance visualization that cannot be met by thin clients running on Web browsers

  15. Beyond arms control? Looking for the lost paradigm..; Au-dela de l'arms control? A la recherche du paradigme perdu..

    Energy Technology Data Exchange (ETDEWEB)

    Dahan, P

    2002-07-01

    Since the tragic events of September 11, 2001, the international relations have become more complex and the arms control concept, born during the cold war and implemented during the 3 last decades is today marking time. Disarmament and non-proliferation, which were the keystones of arms control and international negotiations, are today undergoing erosion. This article analyzes the change of situation between the end of the 20. century and the beginning of the 21. century. Three steps are defined by the author: a 'flux' step with the signature of a huge number of international agreements about non-proliferation and arms control, a stagnation step marked by the difficulties of implementing some of the existing treaties and by the violation by some states of some of them, and a 'reflux' step marked by a freezing up of the bilateral US-Russian disarmament process and a general renouncement of the multilateral arms control concept. (J.S.)

  16. Low-pressure Environmental TEM (ETEM) studies of Au assisted MgO nanorod growth

    DEFF Research Database (Denmark)

    Duchstein, Linus Daniel Leonhard; Damsgaard, Christian Danvad; Hansen, Thomas Willum;

    2012-01-01

    Over the past few decades, there has been an increasing interest in the use of supported nanoparticles in applications ranging from drug delivery to catalysis. The functionality of such nanoparticles is to a large extent controlled by their shape and exposed surface facets. However, information...... 300keV electron beam with a residual pressure of 10-6mbar and a current density 10-1A/cm². Over a period of one hour, growth of MgO nanorods catalyzed by Au nanoparticles is observed. Eventually the Au nanoparticles fall off, leaving the MgO nanorods for beam induced dissolution. Figure 2 shows the...

  17. Expert system driven fuzzy control application to power reactors

    International Nuclear Information System (INIS)

    For the purpose of nonlinear control and uncertainty/imprecision handling, fuzzy controllers have recently reached acclaim and increasing commercial application. The fuzzy control algorithms often require a ''supervisory'' routine that provides necessary heuristics for interface, adaptation, mode selection and other implementation issues. Performance characteristics of an on-line fuzzy controller depend strictly on the ability of such supervisory routines to manipulate the fuzzy control algorithm and enhance its control capabilities. This paper describes an expert system driven fuzzy control design application to nuclear reactor control, for the automated start-up control of the Experimental Breeder Reactor-II. The methodology is verified through computer simulations using a valid nonlinear model. The necessary heuristic decisions are identified that are vitally important for the implemention of fuzzy control in the actual plant. An expert system structure incorporating the necessary supervisory routines is discussed. The discussion also includes the possibility of synthesizing the fuzzy, exact and combined reasoning to include both inexact concepts, uncertainty and fuzziness, within the same environment

  18. Distributed, Modular, Network Enabled Architecture For Process Control Military Applications

    Directory of Open Access Journals (Sweden)

    Abhijit Kamble*,

    2014-02-01

    Full Text Available In process control world, use of distributed modular embedded controller architecture drastically reduces the number and complexity of cabling; at the same time increases the system computing performance and response for real time application as compared to centralized control system. We propose a design based on ARM Cortex M4 hardware architecture and Cortex Microcontroller Software Interface Standard (CMSIS based software development. The ARM Cortex-M series ensures a compatible target processor and provides common core peripherals whereas CMSIS abstraction layer reduces development time, helps design software reusability and provides seamless application software interface for controllers. Being a custom design, we can built features like Built-In Test Equipment (BITE, single point fault tolerance, redundancy, 2/3 logic, etc. which are more desirable for a military applications. This paper describes the design of a generic embedded hardware module that can be configured as local I/O controller or application controller or Man Machine Interface (MMI. This paper also proposes a philosophy for step by step hardware and software development.

  19. Collective flow in Au + Au collisions

    International Nuclear Information System (INIS)

    Based on a preliminary sample of Au + Au collisions in the EOS time projection chamber at the Bevalac, we study sideward flow as a function of bombarding energy between 0.25A GeV and 1.2A GeV. We focus on the increase in in-plane transverse momentum per nucleon with fragment mass. We also find event shapes to be close to spherical in the most central collisions, independent of bombarding energy and fragment mass up to 4He

  20. Application of modern control theory to HTGR-plant

    International Nuclear Information System (INIS)

    The classical control theory approach to the multivariate control problem is to decouple the system intentionally and to treat each loop independently. As a result, final control system design is limited in complexity by the available mathematical techniques limitation and it's control performance is insufficient in many cases. The modern control theory approach based on the state variables to the problem provides far more powerful methods and more design flexibility than the classical control theory approach by the new mathematical formulation about the problem. The state variable feedback in formulating as an optimal regulator is the most effective way to obtain the desired control performance. In this report, some results of optimal regulator application to High Temperature Gas Cooled Reactor (HTGR) are shown. (author)

  1. Optimizing Flight Control Software With an Application Platform

    Science.gov (United States)

    Smith, Irene Skupniewicz; Shi, Nija; Webster, Christopher

    2012-01-01

    Flight controllers in NASA s mission control centers work day and night to ensure that missions succeed and crews are safe. The IT goals of NASA mission control centers are similar to those of most businesses: to evolve IT infrastructure from basic to dynamic. This paper describes Mission Control Technologies (MCT), an application platform that is powering mission control today and is designed to meet the needs of future NASA control centers. MCT is an extensible platform that provides GUI components and a runtime environment. The platform enables NASA s IT goals through its use of lightweight interfaces and configurable components, which promote standardization and incorporate useful solution patterns. The MCT architecture positions mission control centers to reach the goal of dynamic IT, leading to lower cost of ownership, and treating software as a strategic investment.

  2. Development of Plant Control Diagnosis Technology and Increasing Its Applications

    Science.gov (United States)

    Kugemoto, Hidekazu; Yoshimura, Satoshi; Hashizume, Satoru; Kageyama, Takashi; Yamamoto, Toru

    A plant control diagnosis technology was developed to improve the performance of plant-wide control and maintain high productivity of plants. The control performance diagnosis system containing this technology picks out the poor performance loop, analyzes the cause, and outputs the result on the Web page. Meanwhile, the PID tuning tool is used to tune extracted loops from the control performance diagnosis system. It has an advantage of tuning safely without process changes. These systems are powerful tools to do Kaizen (continuous improvement efforts) step by step, coordinating with the operator. This paper describes a practical technique regarding the diagnosis system and its industrial applications.

  3. Control of particles flux in a tokamak with an events structure; Controle des flux de particules dans un Tokamak au moyen d`une structure a events

    Energy Technology Data Exchange (ETDEWEB)

    Tsitrone, E.

    1995-12-01

    Two key problems in the development of a controlled fusion reactor are: -the control of the ashes resulting from the fusion reaction (helium) and of the impurities coming from the wall erosion, which affect the central plasma performances by diluting the fuel and dissipating a part of the produced energy by radiation. - the removal of the heat carried to the walls by charged particles, which is highly concentrated (peak values of several tens of MW per m{sup 2}). Two types of systems are generally used for the plasma-wall interface: throat limiter and axisymmetric divertor. Neither is an ideal candidate to control simultaneously the heat and particle fluxes. This thesis investigates an alternative configuration, the vented limiter, tested for the first time on the Tore Supra tokamak. The vented limiter principle lies on the recycling neutrals collection by slots, in such a way that local thermal overload is avoided. It is shown experimentally that the surface temperature of the prototype installed in Tore Supra remains uniform. As far as the particle collection is concerned, even though the pressure in the vented limiter is lower than the pressure in the throat limiter by a factor 3 for deuterium and 4 helium, it is sufficient to control the plasma density. Moreover, as with a throat limiter, the pressure exhibits a quadratic evolution with the plasma density. To interpret these results, a model describing the plasma recycling on the limiter and the pumping by the slots has been developed. The model has been validated by a comparison with the experimental data. It was then used to propose an optimized version of the prototype with reshaped slots. This should improve the pumping efficiency by a factor 2, in deuterium as well as in helium, but without removing the discrepancy between both pumping efficiencies. (Abstract Truncated)

  4. Synthesis of SERS active Au nanowires in different noncoordinating solvents

    International Nuclear Information System (INIS)

    Au nanowires with length up to micrometers were synthesized through a simple and one-pot solution growth method. HAuCl4 was reduced in a micellar structure formed by 1-octadecylamine and oleic acid in hexane, heptane, toluene and chloroform, respectively. As the non-polarity of noncoordinating solvents can affect the nucleation and growth rates of Au nanostructures, Au nanowires with different diameters could be obtained by changing the noncoordinating solvents in the synthetic process. The influences of the solvents on the morphology of Au nanowires were systematically studied. When using hexane as reaction solvent, the product turned to be high portion of Au nanowires with more uniform size than the others. Furthermore, surface-enhanced Raman scattering (SERS) spectrum of 2-thionaphthol was obtained on the Au nanowire-modified substrate, indicating that the as-synthesized Au nanowires have potential for highly sensitive optical detection application.

  5. The use of compact programmable controllers (PLC) for measuring applications

    OpenAIRE

    Burda, Tomáš

    2012-01-01

    The aim of this thesis is to determine the extent to which one can use compact PLC technology for measurement applications. The first chapter "Programmable Logic Controllers" describes the basic functions and structure of PLC. The next chapter provides a brief list of compact PLC series produced by different manufacturers which are usable for measurement applications. With the selected automat I performed some measurement and present an evaluation of the results. The last chapt...

  6. Application of digital computers to nuclear reactor instrumentation and control

    International Nuclear Information System (INIS)

    The standard specifies requirements to be satisfied when applying digital computers to warning, data storage, and control and protection of nuclear facilities. The uses of computers and their functions in on-line and off-line applications are classified. General recommendations are presented concerning the application of computers, use of protocols and records relating to the power plant status history, and the function of the display units. Examples of problem solving in operational calculations are given. (J.B)

  7. Au-Free GaN High-Electron-Mobility Transistor with Ti/Al/W Ohmic and WN X Schottky Metal Structures for High-Power Applications

    Science.gov (United States)

    Hsieh, Ting-En; Lin, Yueh-Chin; Chu, Chung-Ming; Chuang, Yu-Lin; Huang, Yu-Xiang; Shi, Wang-Cheng; Dee, Chang-Fu; Majlis, Burhanuddin Yeop; Lee, Wei-I.; Chang, Edward Yi

    2016-07-01

    In this study, an Au-free AlGaN/GaN high-electron-mobility transistor (HEMT) with Ti/Al/W ohmic and WN x Schottky metal structures is fabricated and characterized. The device exhibits smooth surface morphology after metallization and shows excellent direct-current (DC) characteristics. The device also demonstrates better performance than the conventional HEMTs under high voltage stress. Furthermore, the Au-free AlGaN/GaN HEMT shows stable device performance after annealing at 400°C. Thus, the Ti/Al/W ohmic and WN X Schottky metals can be applied in the manufacturing of GaN HEMT to replace the Au based contacts to reduce the manufacturing costs of the GaN HEMT devices with comparable device performance.

  8. Au-Free GaN High-Electron-Mobility Transistor with Ti/Al/W Ohmic and WN X Schottky Metal Structures for High-Power Applications

    Science.gov (United States)

    Hsieh, Ting-En; Lin, Yueh-Chin; Chu, Chung-Ming; Chuang, Yu-Lin; Huang, Yu-Xiang; Shi, Wang-Cheng; Dee, Chang-Fu; Majlis, Burhanuddin Yeop; Lee, Wei-I.; Chang, Edward Yi

    2016-04-01

    In this study, an Au-free AlGaN/GaN high-electron-mobility transistor (HEMT) with Ti/Al/W ohmic and WNx Schottky metal structures is fabricated and characterized. The device exhibits smooth surface morphology after metallization and shows excellent direct-current (DC) characteristics. The device also demonstrates better performance than the conventional HEMTs under high voltage stress. Furthermore, the Au-free AlGaN/GaN HEMT shows stable device performance after annealing at 400°C. Thus, the Ti/Al/W ohmic and WN X Schottky metals can be applied in the manufacturing of GaN HEMT to replace the Au based contacts to reduce the manufacturing costs of the GaN HEMT devices with comparable device performance.

  9. Communication from the CRE relative to the control of the appropriated book-keeping; Communication de la CRE relative au controle de la comptabilite appropriee

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-05-01

    The appropriated book-keeping mentioned in the article 5 of the law from February 10, 2000 is used to calculate the charges of the power production public utility. This book-keeping is controlled by an independent organization approved by the French commission of electricity regulation (CRE). This document precises the criteria requested by the CRE for the approval of this independent organization. The information note about the content of the appropriated book-keeping is attached in appendix: cost overruns due to the contracts of purchase, production cost overruns in non-interconnected areas, technical data to be archived by the operators during 6 years. (J.S.)

  10. TiO2 nanotube arrays co-loaded with Au nanoparticles and reduced graphene oxide: Facile synthesis and promising photocatalytic application

    International Nuclear Information System (INIS)

    Graphical abstract: Methyl orange (MO) can be efficiently removed through photodegradation process using a novel photocatalyst, Au nanoparticles and reduced graphene oxide co-loaded TiO2 nanotube arrays. Highlights: •The photocatalyst is prepared by an one-step constant potential deposition process. •The ternary photocatalyst shows effective separation of photogenerated charges. •The photocatalyst displays almost 100% photocatalytic removal of methyl orange. •The photocatalyst is easily recovered with excellent cycling stability. -- Abstract: Au nanoparticles and reduced graphene oxide co-loaded TiO2 nanotube arrays (Au/RGO–TiO2 NTs) were prepared through a simple one-step constant-potential electrolysis of chloroauric acid and graphene oxide on TiO2 NTs. Compared with Au–TiO2 NTs, RGO–TiO2 NTs and un-modified TiO2 NTs, the Au/RGO–TiO2 NTs exhibited high efficiency in photocatalytic degradation of methyl orange (MO) under simulated solar light irradiation. The highly efficient photocatalytic activity is associated with broad absorption in the visible light region, increased photoinduced charge separation through transferring photogenerated electrons from TiO2 NTs to both Au and RGO, as well as the strong adsorption ability of RGO to MO molecules. Moreover, the Au/RGO–TiO2 NTs has an excellent stability. This work provides an insight into designing and synthesizing new TiO2 NTs-based hybrid materials for effective visible light-activated photocatalysis

  11. Model Oriented Application Generation for Industrial Control Systems

    CERN Document Server

    Copy, B; Blanco Vinuela, E; Fernandez Adiego, B; Nogueira Ferandes, R; Prieto Barreiro, I

    2011-01-01

    The CERN Unified Industrial Control Systems framework (UNICOS) is a software generation methodology and a collection of development tools that standardizes the design of industrial control applications [1]. A Software Factory, named the UNICOS Application Builder (UAB) [2], was introduced to ease extensibility and maintenance of the framework, introducing a stable metamodel, a set of platformindependent models and platformspecific configurations against which code generation plugins and configuration generation plugins can be written. Such plugins currently target PLC programming environments (Schneider and SIEMENS PLCs) as well as SIEMENS WinCC Open Architecture SCADA (previously known as ETM PVSS) but are being expanded to cover more and more aspects of process control systems. We present what constitutes the UNICOS metamodel and the models in use, how these models can be used to capture knowledge about industrial control systems and how this knowledge can be leveraged to generate both code and configuratio...

  12. New approaches in intelligent control techniques, methodologies and applications

    CERN Document Server

    Kountchev, Roumen

    2016-01-01

    This volume introduces new approaches in intelligent control area from both the viewpoints of theory and application. It consists of eleven contributions by prominent authors from all over the world and an introductory chapter. This volume is strongly connected to another volume entitled "New Approaches in Intelligent Image Analysis" (Eds. Roumen Kountchev and Kazumi Nakamatsu). The chapters of this volume are self-contained and include summary, conclusion and future works. Some of the chapters introduce specific case studies of various intelligent control systems and others focus on intelligent theory based control techniques with applications. A remarkable specificity of this volume is that three chapters are dealing with intelligent control based on paraconsistent logics.

  13. Electrophoretic deposition of fluorescent Cu and Au sheets for light-emitting diodes

    Science.gov (United States)

    Liu, Jiale; Wu, Zhennan; Li, Tingting; Zhou, Ding; Zhang, Kai; Sheng, Yu; Cui, Jianli; Zhang, Hao; Yang, Bai

    2015-12-01

    Electrophoretic deposition (EPD) is a conventional method for fabricating film materials from nanometer-sized building blocks, and exhibits the advantages of low-cost, high-efficiency, wide-range thickness adjustment, and uniform deposition. Inspired by the interest in the application of two-dimensional (2D) nanomaterials, the EPD technique has been recently extended to building blocks with 2D features. However, the studies are mainly focused on simplex building blocks. The utilization of multiplex building blocks is rarely reported. In this work, we demonstrate a controlled EPD of Cu and Au sheets, which are 2D assemblies of luminescent Cu and Au nanoclusters. Systematic investigations reveal that both the deposition efficiency and the thickness are determined by the lateral size of the sheets. For Cu sheets with a large lateral size, a high ζ-potential and strong face-to-face van der Waals interactions facilitate the deposition with high efficiency. However, for Au sheets, the small lateral size and ζ-potential limit the formation of a thick film. To solve this problem, the deposition dynamics are controlled by increasing the concentration of the Au sheets and adding acetone. This understanding permits the fabrication of a binary EPD film by the stepwise deposition of Cu and Au sheets, thus producing a luminescent film with both Cu green emission and Au red emission. A white light-emitting diode prototype with color coordinates (x, y) = (0.31, 0.36) is fabricated by employing the EPD film as a color conversion layer on a 365 nm GaN clip and further tuning the amount of deposited Cu and Au sheets.Electrophoretic deposition (EPD) is a conventional method for fabricating film materials from nanometer-sized building blocks, and exhibits the advantages of low-cost, high-efficiency, wide-range thickness adjustment, and uniform deposition. Inspired by the interest in the application of two-dimensional (2D) nanomaterials, the EPD technique has been recently extended to

  14. Integrated natural gas pipeline control and customer service system of Gasum; Le systeme integre de controle des canalisations de gaz et de service au consommateur chez Gasum

    Energy Technology Data Exchange (ETDEWEB)

    Aho, J.; Manty, O.; Ahlnas, B. [Gasul Oy (Finland)

    2000-07-01

    Due to the rapid development of the information technology, ageing is not the only driving force for replacing old computer systems with more sophisticated ones. The Finnish natural Gas company, Gasum Oy, has recently taken into use a new control and monitoring system for natural gas pipeline. A special customer service system, developed by Gasum Oy, is closely connected to monitoring system. It provides up-to-date information to all customers of Gasum Oy. The information is layered in three confidential levels: general information, operational data and invoicing information. The system is operating interactively in confidential Extranet. Inside Gasum Oy to meet the needs of departments outside the control room, a new GID system is developed. GID is a way to present pipeline process data and its further modifications with a very user-friendly interface based on geographical map. The system is based on data warehouse architecture and it is working on company's Intranet. This makes it possible to present various secrecy level information based on user ID. Gasum's new SCADA is not only the base for operating the pipeline, but it also provides lot of vital information to other systems serving different user groups within natural gas business in Finland. (authors)

  15. Embedded target toolbox for DSP control applications of BLDC motor

    Directory of Open Access Journals (Sweden)

    Benk Enikö

    2009-10-01

    Full Text Available This paper presents a Matlab embedded target toolbox used for the DC brushless (BLDC motor applications. The synthesis, code generation, and the implementation of the control program, and also the control task itself are carried out on the host PC, under the Simulink. The target system is a brushless DC motor control kit – MSK243, connected on serial port COM to the host computer. With this real time library, it is possible to develop a Rapid Control Prototyping and Hardware-in-the-Loop Simulations. During the running control task on the target, the full functionality of Matlab/Simulink can be used for parameter’s visualization without interrupting or impeding the control process on the MSK240 board.

  16. Type-2 Fuzzy Logic in Intelligent Control Applications

    CERN Document Server

    Castillo, Oscar

    2012-01-01

    We describe in this book, hybrid intelligent systems based mainly on type-2 fuzzy logic for intelligent control. Hybrid intelligent systems combine several intelligent computing paradigms, including fuzzy logic, and bio-inspired optimization algorithms, which can be used to produce powerful automatic control systems. The book is organized in three main parts, which contain a group of chapters around a similar subject. The first part consists of chapters with the main theme of theory and design algorithms, which are basically chapters that propose new models and concepts, which can be the basis for achieving intelligent control with interval type-2 fuzzy logic. The second part of the book is comprised of chapters with the main theme of evolutionary optimization of type-2 fuzzy systems in intelligent control with the aim of designing optimal type-2 fuzzy controllers for complex control problems in diverse areas of application, including mobile robotics, aircraft dynamics systems and hardware implementations. Th...

  17. Principle and applications of Controlled-Drift Detectors

    International Nuclear Information System (INIS)

    The Controlled-Drift Detector is a fully depleted silicon detector that allows 2D position sensing and energy spectroscopy of X-rays in the range 0.5-30 keV with imaging capability up to 100 kframe/s, event timing of few ns and limited readout channels. In this paper we review the Controlled-Drift Detector operating principle and we present its applications in X-ray absorption imaging and in Compton electrons tracking

  18. The application of human engineering in control room of HFETR

    International Nuclear Information System (INIS)

    The human-machine system for improving the working environment in the control room of HFETR is described. The reliability of the equipment, instruments and operation by human engineering is increased. The relations between human engineering and lowering human failure in HFETR are also discussed. It is concluded that the further application of human engineering can increase interaction of the human and machine in the control room and provide assurances for the safe and reliable operation of reactor. (authors)

  19. DARC: Next generation decentralized control framework for robot applications

    DEFF Research Database (Denmark)

    Kjærgaard, Morten; Andersen, Nils Axel; Ravn, Ole

    This paper presents DARC, a next generation control framework for robot applications. It is designed to be equally powerful in prototyping research projects and for building serious commercial robots running on low powered embedded hardware, thus closing the gab between research and industry. It ...... incorporates several new techniques such as a decentralized peer-to-peer architecture, transparent network distribution of the control system, and automatic run-time supervision to guarantee robustness....

  20. Application of Online Iterative Learning Tracking Control for Quadrotor UAVs

    OpenAIRE

    Pipatpaibul, Pong-in; Ouyang, P. R.

    2013-01-01

    Quadrotor unmanned aerial vehicles (UAVs) have attracted considerable interest for various applications including search and rescue, environmental monitoring, and surveillance because of their agilities and small sizes. This paper proposes trajectory tracking control of UAVs utilizing online iterative learning control (ILC) methods that are known to be powerful for tasks performed repeatedly. PD online ILC and switching gain PD online ILC are used to perform a variety of manoeuvring such as t...

  1. Dynamically Authorized Role-Based Access Control for Grid Applications

    Institute of Scientific and Technical Information of China (English)

    YAO Hanbing; HU Heping; LU Zhengding; LI Ruixuan

    2006-01-01

    Grid computing is concerned with the sharing and coordinated use of diverse resources in distributed "virtual organizations". The heterogeneous, dynamic and multi-domain nature of these environments makes challenging security issues that demand new technical approaches. Despite the recent advances in access control approaches applicable to Grid computing, there remain issues that impede the development of effective access control models for Grid applications. Among them there are the lack of context-based models for access control, and reliance on identity or capability-based access control schemes. An access control scheme that resolve these issues is presented, and a dynamically authorized role-based access control (D-RBAC) model extending the RBAC with context constraints is proposed. The D-RABC mechanisms dynamically grant permissions to users based on a set of contextual information collected from the system and user's environments, while retaining the advantages of RBAC model. The implementation architecture of D-RBAC for the Grid application is also described.

  2. Control synthesis for polynomial nonlinear systems and application in attitude control

    Institute of Scientific and Technical Information of China (English)

    Chang-fei TONG; Hui ZHANG; You-xian SUN

    2008-01-01

    A method for positive polynomial validation based on polynomial decomposition is proposed to deal with control synthesis problems. Detailed algorithms for decomposition are given which mainly consider how to convert coefficients of a polynomial to a matrix with free variables. Then, the positivity of a polynomial is checked by the decomposed matrix with semidefinite programming solvers. A nonlinear control law is presented for single input polynomial systems based on the Lyapunov stability theorem. The control synthesis method is advanced to multi-input systems further. An application in attitude control is finally presented. The proposed control law achieves effective performance as illustrated by the numerical example.

  3. Application of modern control theory to temperature control of the MBE system

    Science.gov (United States)

    Ishikawa, Takuya; Chan, Yuen Chuen; Nakano, Yoshiaki; Tada, Kunio

    1990-03-01

    The setup of an MBE control system without PID controllers, whereby one microprocessor manages all the Knudsen cells directly, is reported. The model-following algorithm is applied to the temperature control of the Knudsen cells, and improved dynamic response of the cell temperature is obtained compared with that obtained by the conventional PID algorithm. An application of the model-following algorithm to device fabrication is demonstrated.

  4. Engineering applications of discrete-time optimal control

    DEFF Research Database (Denmark)

    Vidal, Rene Victor Valqui; Ravn, Hans V.

    1990-01-01

    Many problems of design and operation of engineering systems can be formulated as optimal control problems where time has been discretisized. This is also true even if 'time' is not involved in the formulation of the problem, but rather another one-dimensional parameter. This paper gives a review...... of some well-known and new results in discrete time optimal control methods applicable to practical problem solving within engineering. Emphasis is placed on dynamic programming, the classical maximum principle and generalized versions of the maximum principle for optimal control of discrete time...

  5. Engineering applications of discrete-time optimal control

    DEFF Research Database (Denmark)

    Vidal, Rene Victor Valqui; Ravn, Hans V.

    1990-01-01

    of some well-known and new results in discrete time optimal control methods applicable to practical problem solving within engineering. Emphasis is placed on dynamic programming, the classical maximum principle and generalized versions of the maximum principle for optimal control of discrete time......Many problems of design and operation of engineering systems can be formulated as optimal control problems where time has been discretisized. This is also true even if 'time' is not involved in the formulation of the problem, but rather another one-dimensional parameter. This paper gives a review...

  6. DRACULA: Dynamic range control for broadcasting and other applications

    Science.gov (United States)

    Gilchrist, N. H. C.

    The BBC has developed a digital processor which is capable of reducing the dynamic range of audio in an unobtrusive manner. It is ideally suited to the task of controlling the level of musical programs. Operating as a self-contained dynamic range controller, the processor is suitable for controlling levels in conventional AM or FM broadcasting, or for applications such as the compression of program material for in-flight entertainment. It can, alternatively, be used to provide a supplementary signal in DAB (digital audio broadcasting) for optional dynamic compression in the receiver.

  7. Applicator Training Manual for: Agricultural Animal Pest Control.

    Science.gov (United States)

    Christensen, Christian M.

    This manual discusses pesticide safety and environmental considerations, pesticide toxicity, residue potential, pesticide formulations, and application techniques. In addition, descriptions of, and methods for controlling insects and related pests that attack cattle, sheep and goats, swine, horses and other equines, and poultry are given. These…

  8. Computer and control applications in a vegetable processing plant

    Science.gov (United States)

    There are many advantages to the use of computers and control in food industry. Software in the food industry takes 2 forms - general purpose commercial computer software and software for specialized applications, such as drying and thermal processing of foods. Many applied simulation models for d...

  9. 77 FR 16262 - Importer of Controlled Substances; Notice of Application

    Science.gov (United States)

    2012-03-20

    ... notice published in the Federal Register on September 23, 1975, 40 FR 43745-46, all applicants for...) to be registered as an importer of Fentanyl (9801), a basic class of controlled substance listed in... export domestically manufactured FDF to foreign markets. In reference to the import of Fentanyl...

  10. Non-destructive control: technologies, applications and markets

    International Nuclear Information System (INIS)

    A description of NDC - nondestructive controls - (acoustic emission, Eddy currents, infrared and thermal, liquid penetrants, magnetic particles, radiographic, ultrasonic, visual and optical techniques) is given with various industrial applications and market trends. Some research projects, contacts and a list of NDC systems main manufacturers are given. (A.B.). 37 figs. and tabs

  11. The application of XRF technique in cement quality control

    International Nuclear Information System (INIS)

    XRF (X Ray Florescence) is a rapid and accurate analysis method that used in many fields. The theory of XRF and its application in quality control of raw cement will be introduced in this paper, and according to the experience, and the problems that attention should be paid to in utilizing and developing will be discussed also. (authors)

  12. Biopolymers in controlled release devices for agricultural applications.

    Science.gov (United States)

    The use of biopolymers such as starch for agricultural applications including controlled release devices is growing due the environmental benefits. Recently, concerns have grown about the worldwide spread of parasitic mites (Varroa destructor) that infect colonies of honey bees (Apis mellifera L.). ...

  13. Model-Driven Development of Automation and Control Applications: Modeling and Simulation of Control Sequences

    Directory of Open Access Journals (Sweden)

    Timo Vepsäläinen

    2014-01-01

    Full Text Available The scope and responsibilities of control applications are increasing due to, for example, the emergence of industrial internet. To meet the challenge, model-driven development techniques have been in active research in the application domain. Simulations that have been traditionally used in the domain, however, have not yet been sufficiently integrated to model-driven control application development. In this paper, a model-driven development process that includes support for design-time simulations is complemented with support for simulating sequential control functions. The approach is implemented with open source tools and demonstrated by creating and simulating a control system model in closed-loop with a large and complex model of a paper industry process.

  14. Applicability of near-infrared hyperspectral imagery (NIR-HI) for sensor based sorting of an epithermal Au-Ag ore

    NARCIS (Netherlands)

    Dalm, M.; Buxton, M.W.N.; Van Ruitenbeek, F.J.A.

    2015-01-01

    In the presented study test work was performed with near-infrared hyperspectral imagery (NIR-HI) on 36 ore samples from a South-American epithermal Au-Ag mine. The aim of the test work was to investigate if NIR-HI provides information about the alteration mineralogy of samples that can be used to pr

  15. One-step construction of an electrode modified with electrodeposited Au/SiO2 nanoparticles, and its application to the determination of NADH and ethanol

    International Nuclear Information System (INIS)

    A new electrode was developed by one-step potentiostatic electrodeposition (at -2. 0 V for 20 s) of Au/SiO2 nanoparticles on a glassy carbon electrode. The resulting electrode (nano-Au/SiO2/GCE) was characterized by scanning electronic microscopy, X-ray photoelectron spectroscopy and electrochemical techniques. The electrochemical behavior of dihydronicotinamide adenine dinucleotide (NADH) at the nano-Au/SiO2/GCE were thoroughly investigated. Compared to the unmodified electrode, the overpotential decreased by about 300 mV, and the current response significantly increased. These changes indicated that the modified electrode showed excellent catalytic activity in the oxidation of NADH. A linear relationship was obtained in the NADH concentration range from 1. 0 x 10-6 to 1. 0 x 10-4 mol L-1. In addition, amperometric sensing of ethanol at the nano-Au/SiO2/GCE in combination with alcohol dehydrogenase and nicotinamide adenine dinucleotide was successfully demonstrated. A wide linear response was also found for ethanol in the range from 5. 0 x 10-5 to 1. 0 x 10-3 mol L-1 and 1. 0 x 10-3 to 1. 0 x 10-2 mol L-1, respectively. The method was successfully applied to determine ethanol in beer and biological samples. (author)

  16. Preparation and Characterization of Au-ZrO2-SiO2 Nanocomposite Spheres and Their Application in Enrichment and Detection of Organophosphorus Agents

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yuqi; Tu, Haiyang; Zhang, Aidong; Du, Dan; Lin, Yuehe

    2012-03-01

    Au-ZrO{sub 2}-SiO{sub 2} nanocomposite spheres were synthesized and used as selective sorbents for the solid-phase extraction (SPE) of orananophosphorous agents. A non-enzymatic electrochemical sensor based on an Au-ZrO{sub 2}-SiO{sub 2} modified electrode was developed for selective detection of orananophosphorous pesticides (OPs). The Au-ZrO{sub 2}-SiO{sub 2} nanocomposite spheres were synthesized by hydrolysis and condensation of zirconia n-butoxide (TBOZ) on the surface of SiO{sub 2} spheres and then introduction of gold nanoparticles on the surface. Transmission electron microscope and X-ray photoelectron spectroscopy were performed to characterize the formation of the nanocomposite sphere. Fast extraction of OP was achieved by Au-ZrO{sub 2}-SiO{sub 2} modified electrode within 5 min via the specific affinity between zirconia and phosphoric group. The assay yields a broad concentration range of paraoxon-ethyl from 1.0 to 500 ng/mL{sup -1} with a detection limit 0.5 ng/mL{sup -1}. This selective and sensitive method holds great promise for the enrichment and detection of OPs.

  17. The synthesis of Au@C@Pt core-double shell nanocomposite and its application in enzyme-free hydrogen peroxide sensing

    Science.gov (United States)

    Zhang, Yayun; Li, Yuhui; Jiang, Yingying; Li, Yancai; Li, Shunxing

    2016-08-01

    A novel Au@C@Pt core-double shell nanocomposite was synthesized and used to fabricate enzyme-free electrochemical sensor for rapid and sensitive detection of hydrogen peroxide (H2O2). The well-designed Au@C@Pt core-double shell nanocomposite was characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM) and energy-dispersed spectrum (EDS). The Au@C@Pt core-double shell nanocomposite modified glassy carbon electrode (Au@C@Pt/GCE) exhibits good electrocatalytic activity towards H2O2 reduction at 0.0 V and can be used as H2O2 sensor. The sensor displays two wide linear ranges towards H2O2 detection. The one is 9.0 μM-1.86 mM with high sensitivity of 144.7 μA mM-1 cm-2, and the other is 1.86 mM-7.11 mM with sensitivity of 80.1 μA mM-1 cm-2. When signal to noise (S/N) is 3, the calculated detection limit (LOD) is 0.13 μM. Furthermore, the interference from the common interfering species such as glucose, ascorbic acid, dopamine and uric acid can be effectively avoided to H2O2 detection. Additionally, the H2O2 sensor also displays good stability and reproducibility.

  18. A STUDY OF INTELLIGENT CONTROLLERS APPLICATION IN DISTRIBUTED SYSTEMS

    Directory of Open Access Journals (Sweden)

    RAVI KUMAR GULLAPALLI

    2011-09-01

    Full Text Available Intelligent Control emulates the human intelligence and achieves automation in various areas of Engineering. Intelligent Controls have been used mainly in the areas of Electrical Systems; Machine Intelligence based systems like Robotics. Intelligent Control has been active in various industrial and engineering applications.There is active research in applying Intelligent Controls in distributed computing systems like web based environments. The advent of internet has changed the business models for the service providers and consumers. The Distributed Computing Systems which host various IT and business services are expected to be available with high performance and scalability to meet the desired SLAs. There is absolute necessity in predicting the future trends of the IT environments, recognize the load patterns such that the provisioning of the hardware, software resources is appropriately handled. There are research attempts to explore the applicability of intelligent control in such different areas of computing like infrastructure provisioning and Distributed Systems. In this paper we study the various Intelligent Controls and discuss the recent trends of applying intelligent controls in Distributed Systems such as Web Servers.

  19. Networked Control System Simulation Design and Its Application

    Institute of Scientific and Technical Information of China (English)

    A. B. Soglo; YANG Xianhui

    2006-01-01

    This paper presents a framework for networked control system simulation (NCSS) to enable the analysis of the influence of network transmissions on the performance of control systems. The simulation is composed of the network environment simulated using the network simulator, the control system component simulation using Matlab or C/C++, and an external application programming interface. To implement the plant (sensor), controller, and actuator nodes, an agent-based design is introduced, and a multi-agent networked control system is constructed. Therefore, the network simulator 2-26 (NS-2.26) release is extended by modifying the user data protocol (UDP) common header in order to support application data transmission between network nodes. Then, modifying the network topology parameters, networked control system simulations are analyzed for different parameter changes, such as the network bandwidth, the number of plant nodes, and the sampling period. An analysis of the influence of these parameters on network-induced delays and packet drop is made. The results show that the simulation system is an effective tool for the study of networked control systems.

  20. Chaos in electric drive systems analysis control and application

    CERN Document Server

    Chau, K T

    2011-01-01

    In Chaos in Electric Drive Systems: Analysis, Control and Application authors Chau and Wang systematically introduce an emerging technology of electrical engineering that bridges abstract chaos theory and practical electric drives. The authors consolidate all important information in this interdisciplinary technology, including the fundamental concepts, mathematical modeling, theoretical analysis, computer simulation, and hardware implementation. The book provides comprehensive coverage of chaos in electric drive systems with three main parts: analysis, control and application. Corresponding drive systems range from the simplest to the latest types: DC, induction, synchronous reluctance, switched reluctance, and permanent magnet brushless drives.The first book to comprehensively treat chaos in electric drive systemsReviews chaos in various electrical engineering technologies and drive systemsPresents innovative approaches to stabilize and stimulate chaos in typical drivesDiscusses practical application of cha...

  1. Access Control of Web and Java Based Applications

    Science.gov (United States)

    Tso, Kam S.; Pajevski, Michael J.; Johnson, Bryan

    2011-01-01

    Cyber security has gained national and international attention as a result of near continuous headlines from financial institutions, retail stores, government offices and universities reporting compromised systems and stolen data. Concerns continue to rise as threats of service interruption, and spreading of viruses become ever more prevalent and serious. Controlling access to application layer resources is a critical component in a layered security solution that includes encryption, firewalls, virtual private networks, antivirus, and intrusion detection. In this paper we discuss the development of an application-level access control solution, based on an open-source access manager augmented with custom software components, to provide protection to both Web-based and Java-based client and server applications.

  2. Using supported Au nanoparticles as starting material for preparing uniform Au/Pd bimetallic catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Villa, Alberto [Universita di Milano, Italy; Prati, Laura [Universita di Milano, Italy; Su, Dangshen [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Wang, Di [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Veith, Gabriel M [ORNL

    2010-01-01

    One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and catalytic activities by investigating three different gold seeds. Uniform Au-Pd alloy were obtained when a steric/electrostatic protecting group, poly(vinyl alcohol) (PVA), was used to form the gold clusters on activated carbon (AC). In contrast Au/AC precursors prepared using Au nanoparticles with only electrostatic stabilization (tetrakis(hydroxypropyl)phosphonium chloride (THPC)), or no stabilization (magnetron sputtering) produced inhomogeneous alloys and segregation of the gold and palladium. The uniform alloyed catalyst (Pd{at}Au{sub PVA}/AC) is the most active and selective catalyst, while the inhomogenous catalysts are less active and selective. Further study of the PVA protected Au clusters revealed that the amount of PVA used is also critical for the preparation of uniform alloyed catalyst, their stability, and their catalytic activity.

  3. Evolution of thermal micro-measurement technique for various applications; Evolution des techniques de micromesures thermiques au travers de quelques applications

    Energy Technology Data Exchange (ETDEWEB)

    Thiery, L.; Bailly, Y.; Lanzetta, F.; Gualous, H.; Gavignet, E. [Institut de genie energetique (ICE), Institut des microtechniques de Franche-Comte (IMFC), Universite de Franche-Comte, 90 - Belfort (France)

    1998-01-01

    The thermoelectric sensors made at present in our laboratory have junction dimensions from e few micrometers to 0.5 {mu}m. Two techniques are used: welding of ultra-thin wires and vacuum deposition (PVD). Two applications related to the first one will be presented: the detection of periodic field of temperature for photothermal microscopy and acoustic resonator characterization. In the latter, the comparison of simultaneous pressure and temperature will lead us to improve the knowledge of thermo-acoustic phenomena. The deposition technique allows us to create either simple thermoelectric couples, multiple as thermopiles; or heat (and light) flow sensors. Our work is presented in that field, with the development of a laser light sensor designed to image its light profile for large emission bandwidth and power densities. Finally, the description followed by an example of application is shown in the case of the heat flow measurement between a laminar gaseous flow and a wall. By comparison, we show that the use of such sensors could be worthwhile to replace the usual temperature sensors in the estimation of the heat transfer coefficient at the gas-wall boundary. (authors) 27 refs.

  4. Disturbance Accommodating Adaptive Control with Application to Wind Turbines

    Science.gov (United States)

    Frost, Susan

    2012-01-01

    Adaptive control techniques are well suited to applications that have unknown modeling parameters and poorly known operating conditions. Many physical systems experience external disturbances that are persistent or continually recurring. Flexible structures and systems with compliance between components often form a class of systems that fail to meet standard requirements for adaptive control. For these classes of systems, a residual mode filter can restore the ability of the adaptive controller to perform in a stable manner. New theory will be presented that enables adaptive control with accommodation of persistent disturbances using residual mode filters. After a short introduction to some of the control challenges of large utility-scale wind turbines, this theory will be applied to a high-fidelity simulation of a wind turbine.

  5. Efficient controller area network data compression for automobile applications

    Institute of Scientific and Technical Information of China (English)

    Yu-jing WU; Jin-Gyun CHUNG

    2015-01-01

    Controller area networks (CANs) have been designed for multiplexing communication between electronic control units (ECUs) in vehicles and many high-level industrial control applications. When a CAN bus is overloaded by a large number of ECUs connected to it, both the waiting time and the error probability of the data transmission are increased. Thus, it is desirable to reduce the CAN frame length, since the duration of data transmission is proportional to the frame length. In this paper, we present a CAN message compression method to reduce the CAN frame length. Experimental results indicate that CAN transmission data can be compressed by up to 81.06%with the proposed method. By using an embedded test board, we show that 64-bit engine management system (EMS) CAN data compression can be performed within 0.16 ms;consequently, the proposed algorithm can be successfully used in automobile applications.

  6. Intelligent control and automation technology for nuclear applications

    International Nuclear Information System (INIS)

    This project intends to establish the basic technology of intelligent control and automation to be applied to the next generation nuclear plant. For that, the research status of those technologies is surveyed for various application areas at first. The characteristics and availability of those techniques such as neural network, fuzzy rule based control and reasoning, multimedia, real-time software and qualitative modelling are studied through a series of simulations and experiments. By integrating each technologies studied above, we developed a hierarchical, intelligent control system for an autonomous mobile robot as a test bed. The system is composed of several modules of software and hardware subsystems, which are implemented by use of the intelligent techniques. Through the analysis of the results and experiences, we investigated the feasibility of application of the basic technology to the next generation plant. (Author)

  7. Control of Linear Parameter Varying Systems with Applications

    CERN Document Server

    Mohammadpour, Javad

    2012-01-01

    Control of Linear Parameter Varying Systems with Applications compiles state-of-the-art contributions on novel analytical and computational methods to address system modeling and identification, complexity reduction, performance analysis and control design for time-varying and nonlinear systems in the LPV framework. The book has an interdisciplinary character by emphasizing techniques that can be commonly applied in various engineering fields. It also includes a rich collection of illustrative applications in diverse domains to substantiate the effectiveness of the design methodologies and provide pointers to open research directions. The book is divided into three parts. The first part collects chapters of a more tutorial character on the background of LPV systems modeling and control. The second part gathers chapters devoted to the theoretical advancement of LPV analysis and synthesis methods to cope with the design constraints such as uncertainties and time delay. The third part of the volume showcases con...

  8. Stochastic Model Predictive Control with Applications in Smart Energy Systems

    DEFF Research Database (Denmark)

    Sokoler, Leo Emil; Edlund, Kristian; Mølbak, Tommy;

    2012-01-01

    cover more than 50% of the total consumption by 2050. Energy systems based on significant amounts of renewable energy sources are subject to uncertainties. To accommodate the need for model predictive control (MPC) of such systems, the effect of the stochastic effects on the constraints must be...... function). This is convenient for energy systems, since some constraints are very important to satisfy with a high probability, whereas violation of others are less prone to have a large economic penalty. In MPC applications the control action is obtained by solving an optimization problem at each sampling...... instant. To make the controller applicable in real-time efficient and reliable algorithms are required. If the uncertainty is assumed to be Gaussian, the optimization problems associated with chance constrained (linear) MPC can be expressed as second order cone programming (SOCP) problems. In this paper...

  9. Impedance Coordinative Control for Cascaded Converter in Bidirectional Application

    DEFF Research Database (Denmark)

    Tian, Yanjun; Deng, Fujin; Chen, Zhe;

    2015-01-01

    Two stage cascaded converters are widely used in bidirectional applications, but the negative impedance may cause system instability. Actually the impedance interaction is much different between forward power flow and reversed power flow, which will introduce more uncertainty to the system...... difference between forward and reversed power flow. This paper addresses the analysis with the topology of cascaded dual-active-bridge converter (DAB) with inverter, and the proposed control method can also be implemented in unidirectional applications and other general cascaded converter system. The...... stability. This paper proposes a control method for the constant power controlled converter in cascaded system, and consequently it can change the negative impedance of constant power converter into resistive impedance, which will improve the cascaded system stability, as well as merge the impedance...

  10. Fabrication and temperature-dependent magnetic properties of one-dimensional multilayer Au–Ni–Au–Ni–Au nanowires

    International Nuclear Information System (INIS)

    Multilayer Au–Ni–Au–Ni–Au nanowires with a controlled diameter of ∼100 nm were synthesized by electrochemical deposition in porous alumina templates. The length of each Ni-segment was controlled up to ∼230 nm, while the length of the Au segment sandwiched between two Ni segments was ∼180 nm. X-ray diffraction patterns and energy-dispersive X-ray spectra confirmed the formation of purely crystalline nanowires. The magnetic properties of the multilayer Au–Ni–Au–Ni–Au nanowires were investigated in the temperature range 2–300 K. Room-temperature magnetic hysteresis confirmed the ferromagnetic nature of the nanowires. The plot of coercivity as a function of temperature (from 2 to 300 K) followed law applicable for ferromagnetic nanostructures. The magnetization tended to increase as the temperature decreased, following the modified Bloch's law similar to ferromagnetic nanoparticles. - Graphical abstract: (a) SEM image of Au–Ni–Au–Ni–Au nanowire with 230 nm Ni segment length and 180 nm Au sandwiched between Ni segments (b) Kneller's law (c) Bloch's law Display Omitted - Highlights: • Electrochemical fabrication of Au–Ni–Au–Ni–Au nanowires in alumina templates. • Formation of beadlike structure of Ni segments. • Coercivity versus T follows Kneller's law for ferromagnetic materials. • Magnetization as a function of temperature follows the modified Bloch's law

  11. The Controlled Single-Step Synthesis of Ag/TiO2 and Au/TiO2 by Ultrasonic Spray Pyrolysis (USP)

    Science.gov (United States)

    Bogovic, J.; Rudolf, R.; Friedrich, B.

    2016-01-01

    This article reports the synthesis of Ag/TiO2 and Au/TiO2 nanoparticles by single-step ultrasonic spray pyrolysis (USP) conducted by an investigation of the process parameters and the morphological characteristics of the obtained nanostructures. The influence of the ratio in the precursor solution, physical characteristics of used components, and temperature had a large influence on the formation of different nanoparticle morphologies. The experimental investigations were performed using classic USP equipment, with variations of the process parameters. Scanning electron microscopy, transmission electron microscopy, and focused ion beam analyses were used to characterize the complex nanostructures. Based on the obtained results, the optimal process window for the formation of the different morphologies for the Ag/TiO2 and Au/TiO2 nanoparticles is determined and the possibility of synthesis of the core-shell structures in one step by USP is confirmed.

  12. Studies of the structure and phase transitions of nano-confined pentanedithiol and its application in directing hierarchical molecular assemblies on Au(1 1 1)

    Science.gov (United States)

    Pawlicki, Alison; Avery, Erin; Jurow, Matthew; Ewers, Bradley; Vilan, Ayelet; Drain, Charles Michael; Batteas, James

    2016-03-01

    Directing molecular devices into pre-designed integrated electronic circuits while enforcing selectivity and hierarchy is an inherent challenge for molecular electronics. Here we explore ways to direct the assembly of electrically-active molecular monolayers into specific locations as well as controlling their internal organization. We have accomplished this by two consecutive surface reactions: (1) forming pentanedithiol (C5DT) domains within an inert alkanethiol self-assembled monolayer (SAM) on Au; and (2) selectively binding porphyrin derivatives to the C5DT domains. The C5DT domains were fabricated by phase segregation during co-adsorption from a mixed C5DT/dodecanethiol (C12) solution and nanografting with Atomic Force Microscopy (AFM). AFM revealed that co-absorbed and nanografted C5DT domains were in a standing-up phase and scanning tunneling microscopy (STM) showed that their molecular organization within about 5 nm, 40 nm, 50 nm and 120 nm domains, was dependent upon the size of the domain, such that structure of the C5DT transitions from (\\sqrt{3}   ×  \\sqrt{3} ) R30°, to (2  ×  2), and ultimately to a disordered phase with increasing domain size. This is due to the varying degrees of influence of the surrounding C12; providing sufficient van der Waals interactions as well as a geometric confinement to stabilize the standing-up phase of the C5DT. Understanding the molecular configuration of dithiol SAMs affords their use as a reactive template to subsequently bind active head groups. As a proof of principle, porphyrins with a pendant pentafluorophenyl ring were attached to the C5DT domains by a ‘click’ reaction between the fluorinated ring and the free thiol on the surface. From AFM and STM, these porphyrin derivatives reacted selectively with the C5DT domains with some porphyrins binding directly to the C5DT, subsequently allowing additional localized porphyrin deposition through pi-stacking.

  13. Properties and electrochemical behaviors of AuPt alloys prepared by direct-current electrodeposition for lithium air batteries

    International Nuclear Information System (INIS)

    AuPt catalyst has a prospective application in a lithium air battery because of its bi-function on catalyzing Oxygen Reduction Reaction (ORR) and Oxygen Evolution Reaction (OER). Electrodeposition is an in-situ convenient technology for catalyst preparation without chemical residue. In an acid electrolyte, AuPt alloy catalysts were electrodeposited on carbon paper. The effect of main salt concentration, electrodeposition time and current density were studied by deposit micromorphology observation, structure analyses and composition testing. Catalytic abilities of AuPt alloys were measured by cyclic voltammetry (CV) in an ionic liquid of EMI-TFSI/Li-TFSI [1- Ethyl - 3- methylimidazolium–bis (trifluoromethanesulphonyl) imide/lithium–bis (trifluoromethanesulphonyl) imide]. The electrochemical behaviors of Au, Pt and AuPt deposits were also measured. An optimized direct-current electrodeposition process of getting high active AuPt catalyst is concluded, which is an aqueous solution containing 6.7∼10 mmol · L−1 HAuCl4, 10∼13.3 mmol · L−1 H2PtCl6 and 0.5 mol · L−1 H2SO4 as the electrolyte, current density of 20mA · cm−2 and electrodeposition time of 8∼34 s. The co-deposition of AuPt alloy is an irregular co-deposition controlled by diffusion, while gold atoms enter the platinum’s crystal lattice in the structure of AuPt alloy. The increase of the concentration of H2PtCl6 in the electrolyte, the extension of the electrodeposition time or the raise of the current density can improve the content of Pt in the deposit. The clusters’ diameters of AuPt catalysts decrease to 150∼250 nm by adjusting current densities during electrodeposition

  14. Au pair trajectories

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    workers from the global South, the first article demonstrates how Facebook can be a fruitful methodological tool in the aspiration to open up the research to new themes of inquiry. However, rather than disregarding the au pairs’ economic problems, the dissertation shows how their family participation and......Since 2000, thousands of young Filipino migrants have come to Denmark as au pairs. Officially, they are there to “broaden their cultural horizons” by living temporarily with a Danish host family, but they also conduct domestic labor in exchange for food and money, which allows them to send...... pair-sending families in the Philippines, this dissertation examines the long-term trajectories of these young Filipinas. It shows how the au pairs’ local and transnational family relations develop over time and greatly influence their life trajectories. A focal point of the study is how au pairs...

  15. A Mobile Application for Smart House Remote Control System

    CERN Document Server

    Rajabzadeh, Amir; Jahromi, Zahra Forootan

    2010-01-01

    At the start of the second decade of 21th century, the time has come to make the Smart Houses a reality for regular use. The different parts of a Smart House are researched but there are still distances from an applicable system, using the modern technology. In this paper we present an overview of the Smart House subsystems necessary for controlling the house using a mobile application efficiently and securely. The sequence diagram of the mobile application connecting to the server application and also the use-cases possible are presented. The challenges faced in designing the mobile application and illustrating the updated house top plane view in that application, are discussed and solutions are adapted for it. Finally the designed mobile application was implemented and the important sections of it were described, such as the interactive house top view map which indicates the status of the devices using predefined icons. The facilities to manage the scheduled tasks and defined rules are also implemented in t...

  16. Neutronics - thermal-hydraulics coupling: application to the helium-cooled fast reactor; Couplage neutronique - thermohydraulique: application au reacteur a neutrons rapides refroidi a l'helium

    Energy Technology Data Exchange (ETDEWEB)

    Vaiana, F.

    2009-11-15

    This thesis focuses on the study of interactions between neutron-kinetics and thermal-hydraulics. Neutron-kinetics allow to calculate the power in a nuclear reactor and the temperature evolution of materials where this power is deposited is known thanks to thermal-hydraulics. Moreover, when the temperatures evolve, the densities and cross sections change. These two disciplines are thus coupled. The first part of this work corresponds to the study and development of a method which allows to simulate transients in nuclear reactors and especially with a Monte-Carlo code for neutron-kinetics. An algorithm for the resolution of the neutron transport equation has been established and validated with a benchmark. In thermal-hydraulics, a porous media approach, based on another thesis, is considered. This gives the opportunity to solve the equations on the whole core without unconscionable computation time. Finally, a theoretical study has been performed on the statistical uncertainties which result from the use of a Monte-Carlo code and which spread from the reactivity to the power and from the power to the temperatures. The second part deals with the study of a misplaced control rod withdrawing in a GFR (helium-cooled fast reactor), a fourth generation reactor. Some models allowing to calculate neutron-kinetics and thermal-hydraulics in the core (which contains assemblies built up with fuel plates) were defined. In thermal-hydraulics, a model for the core based on the porous media approach and a fuel plate homogenization model have been set up. A similar homogenization model has been studied for neutron-kinetics. Finally, the control rod withdrawing transient where we can observe the power raising and the stabilisation by thermal feedback has been performed with the Monte-Carlo code Tripoli for neutron-kinetics and the code Trio-U for thermal-hydraulics. (author)

  17. ADAPTIVE CONTROLLER AND ITS APPLICATION IN FORCE SYSTEM OF ASYMMETRIC CYLINDER CONTROLLED BY SYMMETRIC VALVE

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Partial pressure, system vibration and asymmetric system dynamic performance exit in asymmetric cylinder controller by symmetric valve hydraulic system. To solve this problem in the force control system, model reference adaptive controller is designed using equilibrium point stability theory and output error equation polynomial. The reference model is selected in such a way that it meets the system dynamic performance. Hardware configuration of asymmetric cylinder controlled by asymmetric valve hydraulic system is replaced by intelligent control algorithm, thus the cost is lowered and easy to application. Simulation results demonstrate that the proposed adaptive control sheme has good adaptive ability and well solves asymmetric dynamic performance problem. The designed adaptive controller is fairly robust to load disturbance and system parameter variation.

  18. Stabilizing sliding mode control design and application for a dc motor: Speed control

    OpenAIRE

    Rhif, Ahmed

    2012-01-01

    The regulation by sliding mode control (SMC) is recognized for its qualities of robustness and dynamic response. This article will briefly talk about the regulation principles by sliding mode as well as the application of this approach to the adjustment of a speed control DC motor bench using the TY36A/EV unit. This unit, from Electronica Veneta products, uses a PID controller to control the speed and position of the DC motor. Our purpose is to improve the set time answer and the robustness o...

  19. UNICOS CPC6: automated code generation for process control applications

    International Nuclear Information System (INIS)

    The Continuous Process Control package (CPC) is one of the components of the CERN Unified Industrial Control System framework (UNICOS). As a part of this framework, UNICOS-CPC provides a well defined library of device types, a methodology and a set of tools to design and implement industrial control applications. The new CPC version uses the software factory UNICOS Application Builder (UAB) to develop CPC applications. The CPC component is composed of several platform oriented plug-ins (PLCs and SCADA) describing the structure and the format of the generated code. It uses a resource package where both, the library of device types and the generated file syntax, are defined. The UAB core is the generic part of this software, it discovers and calls dynamically the different plug-ins and provides the required common services. In this paper the UNICOS CPC6 package is introduced. It is composed of several plug-ins: the Instance generator and the Logic generator for both, Siemens and Schneider PLCs, the SCADA generator (based on PVSS) and the CPC wizard as a dedicated plug-in created to provide the user a friendly GUI (Graphical User Interface). A tool called UAB Bootstrap will manage the different UAB components, like CPC, and its dependencies with the resource packages. This tool guides the control system developer during the installation, update and execution of the UAB components. (authors)

  20. Advanced discrete-time control designs and applications

    CERN Document Server

    Abidi, Khalid

    2015-01-01

    This book covers a wide spectrum of systems such as linear and nonlinear multivariable systems as well as control problems such as disturbance, uncertainty and time-delays. The purpose of this book is to provide researchers and practitioners a manual for the design and application of advanced discrete-time controllers.  The book presents six different control approaches depending on the type of system and control problem. The first and second approaches are based on Sliding Mode control (SMC) theory and are intended for linear systems with exogenous disturbances. The third and fourth approaches are based on adaptive control theory and are aimed at linear/nonlinear systems with periodically varying parametric uncertainty or systems with input delay. The fifth approach is based on Iterative learning control (ILC) theory and is aimed at uncertain linear/nonlinear systems with repeatable tasks and the final approach is based on fuzzy logic control (FLC) and is intended for highly uncertain systems with heuristi...

  1. Applications of active adaptive noise control to jet engines

    Science.gov (United States)

    Shoureshi, Rahmat; Brackney, Larry

    1993-01-01

    During phase 2 research on the application of active noise control to jet engines, the development of multiple-input/multiple-output (MIMO) active adaptive noise control algorithms and acoustic/controls models for turbofan engines were considered. Specific goals for this research phase included: (1) implementation of a MIMO adaptive minimum variance active noise controller; and (2) turbofan engine model development. A minimum variance control law for adaptive active noise control has been developed, simulated, and implemented for single-input/single-output (SISO) systems. Since acoustic systems tend to be distributed, multiple sensors, and actuators are more appropriate. As such, the SISO minimum variance controller was extended to the MIMO case. Simulation and experimental results are presented. A state-space model of a simplified gas turbine engine is developed using the bond graph technique. The model retains important system behavior, yet is of low enough order to be useful for controller design. Expansion of the model to include multiple stages and spools is also discussed.

  2. Optimization of ion sources for controlled fusion research applications

    International Nuclear Information System (INIS)

    The prospect for improvements in the performance of ion sources for controlled fusion research applications is investigated from a theoretical point of view. The objectives are identified in terms of beam energy, intensity, purity and power efficiency. By analyzing the process in the extraction and formation of an ion beam, an expression is obtained which relates the parameters of the ion source to the quality of the beam. The implications of the result in improving the performance of the ion source for CTR applications is discussed

  3. Application of stability theory to laminar flow control

    Science.gov (United States)

    Hefner, J. N.; Bushnell, D. M.

    1979-01-01

    The paper summarizes the state-of-the-art for application of stability theory to laminar flow control using suction, wall temperature and/or favorable pressure gradient ('natural laminar flow'). Discussions include current LFC problem areas requiring stability analyses, methods of relating stability theory to transition with results from data and theory comparisons available thus far, and a summary of low disturbance data available for theory calibration on swept wings. Critical issues highlighted are problems peculiar to suction LFC on high performance transonic wings and application of the e-to-the-n-power method to both low and high speed flight data.

  4. A measuring method of photo-electric cross section. Application to high-Z elements between 40 keV and 220 keV. Measurement of K absorption edge energy of Au, Th, U, Pu

    International Nuclear Information System (INIS)

    This study first describes a bent crystal monochromator developed for the production of monochromatic beams in a continuous energy range from 30 to 250 keV; it is completed by a metrological application of the device (determination of K absorption edge energy of Au, Th, U, Pu). A method and the associated experimental procedure were developed to measure the photo-electric cross section for high-Z elements; the results are presented with a relative uncertainty ranging between 3 and 6%. Finally, the experimental values are compared with values calculated from theories using self-consistent potential models

  5. Application of Adaptive Predictive Control to a Newborn Incubator

    Directory of Open Access Journals (Sweden)

    Med A. Zermani

    2011-01-01

    Full Text Available Problem statement: This study presents an application of Indirect Adaptive Generalized Predictive Control (IAGPC of an incubator for newborn, in order to improve the performance of temperature control. Approach: Analysis of physical phenomena of incubator was involved together knowledge of the dynamic behavior. Incubator was identified by means of Recursive Least Square (RLS technique associated with a projection of the model parameters for robust system identification. Results: Results showed that mathematical model of neonatal incubator predicted coincide with the measured data. A comparative study was made between ON-OFF, PID and IAGPC control in order to provide the performance of each strategy. Conclusion: Results had proved effectiveness of the IAGPC as a control of incubator system.

  6. Structured Control of LPV Systems with Application to Wind Turbines

    DEFF Research Database (Denmark)

    Adegas, Fabiano Daher; Stoustrup, Jakob

    2012-01-01

    This paper deals with structured control of linear parameter varying systems (LPV) with application to wind turbines. Instead of attempting to reduce the problem to linear matrix inequalities (LMI), we propose to design the controllers via an LMI-based iterative algorithm. The proposed algorithm...... can synthesize structured controllers like decentralized, static output and reduced order output feedback for discrete-time LPV systems. Based on a coordinate decent, it relies on a sufficient matrix inequality condition extended with slack variables to an upper bound on the induced L2-norm of the...... closed-loop system. Algorithms for the computation of feasible as well as optimal controllers are presented. The general case where no restrictions are imposed on the parameter dependence is treated here due to its suitability for modeling wind turbines. A comprehensive numerical example of a gain...

  7. Controllable Femtosecond Laser-Induced Dewetting for Plasmonic Applications

    CERN Document Server

    Makarov, Sergey V; Mukhin, Ivan S; Shishkin, Ivan I; Zuev, Dmitriy A; Mozharov, Alexey M; Krasnok, Alexander E; Belov, Pavel A

    2015-01-01

    Dewetting of thin metal films is one of the most widespread method for functional plasmonic nanostructures fabrication. However, simple thermal-induced dewetting does not allow to control degree of nanostructures order without additional lithographic process steps. Here we propose a novel method for lithography-free and large-scale fabrication of plasmonic nanostructures via controllable femtosecond laser-induced dewetting. The method is based on femtosecond laser surface pattering of a thin film followed by a nanoscale hydrodynamical instability, which is found to be very controllable under specific irradiation conditions. We achieve control over degree of nanostructures order by changing laser irradiation parametrs and film thickness. This allowed us to exploit the method for the broad range of applications: resonant light absorbtion and scattering, sensing, and potential improving of thin-film solar cells.

  8. Control of coupled oscillator networks with application to microgrid technologies.

    Science.gov (United States)

    Skardal, Per Sebastian; Arenas, Alex

    2015-08-01

    The control of complex systems and network-coupled dynamical systems is a topic of vital theoretical importance in mathematics and physics with a wide range of applications in engineering and various other sciences. Motivated by recent research into smart grid technologies, we study the control of synchronization and consider the important case of networks of coupled phase oscillators with nonlinear interactions-a paradigmatic example that has guided our understanding of self-organization for decades. We develop a method for control based on identifying and stabilizing problematic oscillators, resulting in a stable spectrum of eigenvalues, and in turn a linearly stable synchronized state. The amount of control, that is, number of oscillators, required to stabilize the network is primarily dictated by the coupling strength, dynamical heterogeneity, and mean degree of the network, and depends little on the structural heterogeneity of the network itself. PMID:26601231

  9. PLC-Based Pressure Control in Multi-Pump Applications

    Directory of Open Access Journals (Sweden)

    Vodovozov Valery

    2015-12-01

    Full Text Available The paper is devoted to the centrifugal pumps represented the most popular type of pumping equipment used in different areas. The pressure control approach for variable speed driven (VSD parallel connected centrifugal pumps is reported. The goal of the study is optimization of some quality indices, such as efficiency, consumed power, productivity, energy carrier temperature, heat irradiation, etc. One of them – efficiency – has been studied in the paper more carefully. The mathematical model of pumping process is discussed and a vector-matrix description of the multi-pump application is given. The program-based pressure control system is developed which productivity is changed by regulating the number of working pumps. The paper introduces new pressure control algorithms based on the working point estimation intended for programmable logical controllers (PLC. Experiments prove correctness of the offered methodology.

  10. Application of a pilot control banding tool for risk level assessment and control of nanoparticle exposures

    Energy Technology Data Exchange (ETDEWEB)

    Paik, S Y; Zalk, D M; Swuste, P

    2008-03-03

    Control Banding (CB) strategies offer simplified solutions for controlling worker exposures to constituents that are found in the workplace in the absence of firm toxicological and exposure data. These strategies may be particularly useful in nanotechnology applications, considering the overwhelming level of uncertainty over what nanomaterials and nanotechnologies present as potential work-related health risks, what about these materials might lead to adverse toxicological activity, how risk related to these might be assessed, and how to manage these issues in the absence of this information. This study introduces a pilot CB tool or 'CB Nanotool' that was developed specifically for characterizing the health aspects of working with engineered nanoparticles and determining the level of risk and associated controls for five ongoing nanotechnology-related operations being conducted at two Department of Energy (DOE) research laboratories. Based on the application of the CB Nanotool, four of the five operations evaluated in this study were found to have implemented controls consistent with what was recommended by the CB Nanotool, with one operation even exceeding the required controls for that activity. The one remaining operation was determined to require an upgrade in controls. By developing this dynamic CB Nanotool within the realm of the scientific information available, this application of CB appears to be a useful approach for assessing the risk of nanomaterial operations, providing recommendations for appropriate engineering controls, and facilitating the allocation of resources to the activities that most need them.

  11. Enhanced Photoresponse of Conductive Polymer Nanowires Embedded with Au Nanoparticles.

    Science.gov (United States)

    Zhang, Junchang; Zhong, Liubiao; Sun, Yinghui; Li, Anran; Huang, Jing; Meng, Fanben; Chandran, Bevita K; Li, Shuzhou; Jiang, Lin; Chen, Xiaodong

    2016-04-01

    A conductive polymer nanowire embedded with a 1D Au nanoparticle chain with defined size, shape, and interparticle distance is fabricated which demonstrates enhanced photoresponse behavior. The precise and controllable positioning of 1D Au nanoparticle chain in the conductive polymer nanowire plays a critical role in modulating the photoresponse behavior by excitation light wavelength or power due to the coupled-plasmon effect of 1D Au nanoparticle chain. PMID:26901850

  12. Integration and Application of TCV Advanced Plasma Control System

    International Nuclear Information System (INIS)

    Full text: A digital system for plasma control at Tokamak a Configuration Variable (TCV) was developed and integrated. The Advanced Plasma Control System (APCS) enables enhanced control of plasma properties such as shape, position, current and density, with more flexibility and better performance than the existing analogue system. APCS is a grid of 32 interconnected processing units with analogue input/output capabilities, using in-house developed data communication bus and protocol. The control cycle using the entire grid, with data sharing between all units, can go up to 25us, defined as the slow control cycle. For faster control needs such as the vertical stabilization of plasma, single hardware module with 4 processing units is used. By confining the communication to one hardware module, the time for data sharing is reduced and the control cycle can go down, defined as the fast control cycle. The APCS hardware and data sharing architecture is described in this contribution. To integrate the APCS in the existing TCV control plant, a software package that runs in the embedded system hosting the hardware modules was developed and installed. The host state-machine and the structure of the software are discussed, as well as the system performance and stability. An application that uses the APCS to enhance the plasma vertical position stabilization is under development. Past tokamaks with circular cross-section plasmas were vertically stable; however, vertically elongated cross section plasmas suffer from a vertical instability that demands the use of closed loop feedback control systems. The use of the APCS for vertical instability control is evaluated and results on a new vertical position observer are presented. (author)

  13. Robust control of integrated motor-transmission powertrain system over controller area network for automotive applications

    Science.gov (United States)

    Zhu, Xiaoyuan; Zhang, Hui; Cao, Dongpu; Fang, Zongde

    2015-06-01

    Integrated motor-transmission (IMT) powertrain system with directly coupled motor and gearbox is a good choice for electric commercial vehicles (e.g., pure electric buses) due to its potential in motor size reduction and energy efficiency improvement. However, the controller design for powertrain oscillation damping becomes challenging due to the elimination of damping components. On the other hand, as controller area network (CAN) is commonly adopted in modern vehicle system, the network-induced time-varying delays that caused by bandwidth limitation will further lead to powertrain vibration or even destabilize the powertrain control system. Therefore, in this paper, a robust energy-to-peak controller is proposed for the IMT powertrain system to address the oscillation damping problem and also attenuate the external disturbance. The control law adopted here is based on a multivariable PI control, which ensures the applicability and performance of the proposed controller in engineering practice. With the linearized delay uncertainties characterized by polytopic inclusions, a delay-free closed-loop augmented system is established for the IMT powertrain system under discrete-time framework. The proposed controller design problem is then converted to a static output feedback (SOF) controller design problem where the feedback control gains are obtained by solving a set of linear matrix inequalities (LMIs). The effectiveness as well as robustness of the proposed controller is demonstrated by comparing its performance against that of a conventional PI controller.

  14. Effets de site : évalutation expérimentale et modélisations multidimensionnelles : application au site test EURO-SEISTEST (Grèce)

    OpenAIRE

    Riepl, Judith

    1997-01-01

    L'objectif de cette thèse est, l'étude fine des effets d'amplification suite à la géologie locale, notamment dans des bassins sédimentaires, ainsi que l'évaluation des avantages et Iimites des méthodes d'estimations. La partie expérimentale est basée sur des données acquises au site test EURO-SEISTEST, le premier site-test en Europe occidentale proche de Thessalonique (Grèce). Après une évaluation des effets d'amplification au site même et une étude de leur stabilité en fonction de plusieurs ...

  15. Proposition d'un modèle de simplification d'un système documentaire. Application au sein de Turbomeca

    OpenAIRE

    Barroso, Ludovic; Maranzana, Nicolas; Douvrendelle, Franck

    2015-01-01

    La gestion de la qualité est un domaine central pour les entreprises. Associé au système de vérification et au système d'analyse des résultats, c'est à travers ce troisième pilier, le système documentaire, que les entreprises formalisent leur organisation. Fréquemment les systèmes documentaires des sociétés sont volumineux, difficiles à maîtriser et ne suscitent plus autant d'intérêt pour leur personnel. Le modèle proposé ici présente la manière dont on peut améliorer l'efficacité du système ...

  16. Application of modern control theory for building structures

    Science.gov (United States)

    Basharkhah, M. A.; Yao, J. T. P.

    The design of feedback compensators is considered for linear and constant-coefficient multivariable systems and an attempt is made to find a suitable gain matrix for active control of structures. The application of the pole-assignment method is discussed. It is based on the shifting of open-loop poles to the left side of the s-plane, and is applicable to mechanical and electrical systems. The second method developed in this study provides a physical understanding of the active control of civil engineering structures because it allows control of several modes of the system. The K matrix of the control law can be found so that the first few modes of the system have smaller displacements than the corresponding displacements of the original system. Therefore, more modes of higher gain can be used to substantially reduce system displacements. Because the pole-assignment method will not always significantly reduce displacements, the second method is found to be better for the control of civil engineering structures.

  17. Neuro-fuzzy predictive control for nonlinear application

    Institute of Scientific and Technical Information of China (English)

    CHEN Dong-xiang; WANG Gang; LV Shi-xia

    2008-01-01

    Aiming at the unsatisfactory dynamic performances of conventional model predictive control (MPC) in a highly nonlinear process, a scheme employed the fuzzy neural network to realize the nonlinear process is proposed. The neuro-fuzzy predictor has the capability of achieving high predictive accuracy due to its nonlinear mapping and interpolation features, and adaptively updating network parameters by a learning procedure to re-duce the model errors caused by changes of the process under control. To cope with the difficult problem of non-linear optimization, Pepanaqi method was applied to search the optimal or suboptimal solution. Comparisons were made among the objective function values of alternatives in initial space. The search was then confined to shrink the smaller region according to results of comparisons. The convergent point was finally approached to be considered as the optimal or suboptimal solution. Experimental results of the neuro-fuzzy predictive control for drier application reveal that the proposed control scheme has less tracking errors and can smooth control actions, which is applicable to changes of drying condition.

  18. Cognitive interference modeling with applications in power and admission control

    KAUST Repository

    Mahmood, Nurul Huda

    2012-10-01

    One of the key design challenges in a cognitive radio network is controlling the interference generated at coexisting primary receivers. In order to design efficient cognitive radio systems and to minimize their unwanted consequences, it is therefore necessary to effectively control the secondary interference at the primary receivers. In this paper, a generalized framework for the interference analysis of a cognitive radio network where the different secondary transmitters may transmit with different powers and transmission probabilities, is presented and various applications of this interference model are demonstrated. The findings of the analytical performance analyses are confirmed through selected computer-based Monte-Carlo simulations. © 2012 IEEE.

  19. Metamodeling Techniques Applied to the Design of Reconfigurable Control Applications

    Directory of Open Access Journals (Sweden)

    Luca Ferrarini

    2008-02-01

    Full Text Available In order to realize autonomous manufacturing systems in environments characterized by high dynamics and high complexity of task, it is necessary to improve the control system modelling and performance. This requires the use of better and reusable abstractions. In this paper, we explore the metamodel techniques as a foundation to the solution of this problem. The increasing popularity of model-driven approaches and a new generation of tools to support metamodel techniques are changing software engineering landscape, boosting the adoption of new methodologies for control application development.

  20. Indirect control of flexible demand for power system applications

    DEFF Research Database (Denmark)

    Sossan, Fabrizio

    demand is addressed. We investigate the subject considering both how to achieve a shift in the consumption of the single DSRs, and how to generate the indirect control signal for a population of DSRs in order to support the operation of the grid. In the former case, we develop algorithms that achieve...... and storage in the operation of the future power system, we develop a model predictive control strategy for a smart building with the objective of supplying iii space heating and providing regulating power to the grid according to a dynamic electricity price. We named this application energy replacement...

  1. Oxidation and reduction kinetics of eutectic SnPb, InSn, and AuSn: a knowledge base for fluxless solder bonding applications

    OpenAIRE

    Kuhmann, Jochen Friedrich; Preuss, A.; Adolphi, B.; K. Maly; Wirth, T.; Oesterle, W.; Pittroff, W.; Weyer, G.; Fanciulli, M.

    1998-01-01

    For microelectronics and especially for upcoming new packaging technologies in micromechanics and photonics fluxless, reliable and economic soldering technologies are needed. In this article, we consequently focus on the oxidation and reduction kinetics of three commonly used eutectic solder alloys: (1) SnPb; (2) InSn; (3) AuSn. The studies of the oxidation kinetics show that the growth of the native oxide, which covers the solder surfaces from the start of all soldering operations is self-li...

  2. Robust Control for High-Speed Visual Servoing Applications

    DEFF Research Database (Denmark)

    Ellekilde, Lars-Peter; Favrholdt, Peter; Paulin, Mads; Petersen, Henrik Gordon

    2007-01-01

    This paper presents a new control scheme for visual servoing applications. The approach employs quadratic optimization, and explicitly handles both joint position, velocity and acceleration limits. Contrary to existing techniques, our method does not rely on large safety margins and slow task...... execution to avoid joint limits, and is hence able to exploit the full potential of the robot. Furthermore, our control scheme guarantees a well-defined behavior of the robot even when it is in a singular configuration, and thus handles both internal and external singularities robustly. We demonstrate the...... correctness and efficiency of our approach in a number of visual servoing applications, and compare it to a range of previously proposed techniques....

  3. Nanosilicon properties, synthesis, applications, methods of analysis and control

    CERN Document Server

    Ischenko, Anatoly A; Aslalnov, Leonid A

    2015-01-01

    Nanosilicon: Properties, Synthesis, Applications, Methods of Analysis and Control examines the latest developments on the physics and chemistry of nanosilicon. The book focuses on methods for producing nanosilicon, its electronic and optical properties, research methods to characterize its spectral and structural properties, and its possible applications. The first part of the book covers the basic properties of semiconductors, including causes of the size dependence of the properties, structural and electronic properties, and physical characteristics of the various forms of silicon. It presents theoretical and experimental research results as well as examples of porous silicon and quantum dots. The second part discusses the synthesis of nanosilicon, modification of the surface of nanoparticles, and properties of the resulting particles. The authors give special attention to the photoluminescence of silicon nanoparticles. The third part describes methods used for studying and controlling the structure and pro...

  4. A Novel Rate Control Method for Low-Delay Applications

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In real-time applications, the low-delay rate is an important requirement of video coding. We propose a simple low-delay rate control method in this paper for such applications. In this method, target bits are divided into two parts: uncontrolled and controlled bits in the frame layer. The first part is assigned to the header, syntax and motion vectors according to that spent in the previous encoded frame. The second part is assigned to DCT coeffcients by employing a rate model for mactorblock Qpdetermination. Experiments show that the proposed method can achieve better performance compared with that of the test model TMN5 of H. 263, and slightly worse performance, but with lower computation complexity, compared with that of the TMN8 of H. 263 + .

  5. Codetermination of crystal structures at high pressure: Combined application of theory and experiment to the intermetallic compound AuGa2

    Science.gov (United States)

    Godwal, B. K.; Stackhouse, S.; Yan, J.; Speziale, S.; Militzer, Burkhard; Jeanloz, R.

    2013-03-01

    A combination of x-ray diffraction at high pressures and first-principles calculations reveals the sequence of crystal-structural phase transitions in AuGa2 from cubic (Fm3¯m) to orthorhombic (Pnma) at 10 (±4) GPa and then to monoclinic (P21/n) at 33 (±6) GPa. Neither theory nor experiment would have been adequate, on their own, in documenting this sequence of phases, but together they confirm a sequence differing from the Fm3¯m→Pnma→P63/mmc transitions predicted for CaF2 and Pnma → P1121/a transition reported for PbCl2 and SnCl2. The combined results from theory and experiment also allow us to constrain the equations of state of the three phases of AuGa2. Calculations on the analog PbCl2 predict a transition to the P21/n phase seen in AuGa2 that could, therefore, be a common high-pressure phase for PbCl2-structured compounds.

  6. Application of ZnO quantum dots dotted carbon nanotube for sensitive electrochemiluminescence immunoassay based on simply electrochemical reduced Pt/Au alloy and a disposable device

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Fang; Deng, Wenping; Zhang, Yan [Key Laboratory of Chemical Sensing and Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022 (China); Ge, Shenguang [Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, 250022 (China); Yu, Jinghua, E-mail: ujn.yujh@gmail.com [Key Laboratory of Chemical Sensing and Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022 (China); Song, Xianrang, E-mail: sxr@vip.163.com [Cancer Research Center, Shandong Tumor Hospital, Jinan, 250012 (China)

    2014-03-01

    Highlights: • A sandwich-type electrochemluminence immunosensor was fabricated. • Simply electrochemical reduced Pt/Au alloy was selected as immunosensing probes. • ZnO@CNT composite was first employed as signal amplification label. Abstract: We report on a disposable microdevice suitable for sandwich-type electrochemiluminescence (ECL) detection of prostate specific antigen (PSA). The method is making use of ZnO quantum dots dotted carbon nanotube (ZnO@CNT) and simply electrochemical reduced Pt/Au alloy. The latter was selected as immunosensing probe to modify screen-printed carbon electrode, due to its excellent electrical property. For further ultrasensitive, low-potential and stable ECL detection, ZnO@CNT composite was first synthesized using a facile solvothermal method, and employed as signal amplification label. In this work, two working electrodes in one device were used for one determination to obtain more exact results based on screen-print technique. Taking advantage of dual-amplification effects of the Pt/Au and ZnO@CNT, this immunosensor could detect the PSA quantitatively, in the range of 0.001–500 ng mL⁻¹, with a low detection limit of 0.61 pg mL⁻¹. The resulting versatile immunosensor possesses high sensitivity, satisfactory reproducibility and regeneration. This simple and specific strategy has vast potential to be used in other biological assays.

  7. Green synthesis, characterization of Au-Ag core-shell nanoparticles using gripe water and their applications in nonlinear optics and surface enhanced Raman studies

    Science.gov (United States)

    Kirubha, E.; Palanisamy, P. K.

    2014-12-01

    In recent years there has been excessive progress in the ‘green’ chemistry approach for the synthesis of gold and silver nanoparticles. Bimetallic nanoparticles have gained special significance due to their unique tunable optical properties. Herein we report a facile one-pot, eco-friendly synthesis of Au-Ag bimetallic core-shell nanoparticles using gripe water as reducing as well as stabilizing agent. The as-synthesized Au-Ag nanoparticles are characterized using UV-Vis spectroscopy to determine the surface plasmon resonance, and using transmission electron microscopy to study the morphology and the particle size. The optical nonlinearity of the bimetallic nanoparticles investigated by z-scan technique using femtosecond Ti:sapphire is in the order of 109. The nonlinear optical parameters such as the nonlinear refractive index n2, nonlinear absorption coefficient β and the third order nonlinear susceptibility χ3 are measured for various wavelengths from 700 nm to 950 nm. The Au-Ag nanoparticles are also used in surface enhanced Raman spectroscopic studies to enhance the Raman signals of rhodamine 6G.

  8. High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures

    Science.gov (United States)

    Hong, Xinguo; Ehm, Lars; Zhong, Zhong; Ghose, Sanjit; Duffy, Thomas S.; Weidner, Donald J.

    2016-02-01

    We report development of micro-focusing optics for high-energy x-rays by combining a sagittally bent Laue crystal monchromator with Kirkpatrick-Baez (K-B) X-ray focusing mirrors. The optical system is able to provide a clean, high-flux X-ray beam suitable for pair distribution function (PDF) measurements at high pressure using a diamond anvil cell (DAC). A focused beam of moderate size (10-15 μm) has been achieved at energies of 66 and 81 keV. PDF data for nanocrystalline platinum (n-Pt) were collected at 12.5 GPa with a single 5 s X-ray exposure, showing that the in-situ compression, decompression, and relaxation behavior of samples in the DAC can be investigated with this technique. PDFs of n-Pt and nano Au (n-Au) under quasi-hydrostatic loading to as high as 71 GPa indicate the existence of substantial reduction of grain or domain size for Pt and Au nanoparticles at pressures below 10 GPa. The coupling of sagittally bent Laue crystals with K-B mirrors provides a useful means to focus high-energy synchrotron X-rays from a bending magnet or wiggler source.

  9. The Vital Function of Fe3O4@Au nanocomposites for Hydrolase Biosensor Design and Its Application in Detection of Methyl Parathion

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Yuting; Zhang, Weiying; Lin, Yuehe; Du, Dan

    2013-02-04

    A nanocomposite of gold nanoparticles (AuNPs) decorating a magnetic Fe3O4 core was synthesized using cysteamine (SH–NH2) as linker, and characterized by TEM, XPS, UV and electrochemistry. Then a hydrolase biosensor, based on self-assembly of methyl parathion hydrolase (MPH) on the Fe3O4@Au nanocomposite, was developed for sensitive and selective detection of the organophosphorus pesticide (OP) methyl parathion. The magnetic nanocomposite provides an easy way to construct the enzyme biosensor by simply exerting an external magnetic field, and also provides a simple way to renew the electrode surface by removing the magnet. Unlike inhibition-based enzyme biosensors, the hydrolase is not poisoned by OPs and thus is reusable for continuous measurement. AuNPs not only provide a large surface area, high loading efficiency and fast electron transfer, but also stabilize the enzyme through electrostatic interactions. The MPH biosensor shows rapid response and high selectivity for detection of methyl parathion, with a linear range from 0.5 to 1000 ng/mL and a detection limit of 0.1 ng/mL. It also shows acceptable reproducibility and stability. The simplicity and ease of operation of the proposed method has great potential for on-site detection of P–S containing pesticides and provides a promising strategy to construct a robust biosensor.

  10. Micro reactor for heterogeneous catalysis / application: hydrogen storage from methyl-cyclohexane; Microreacteur pour la catalyse heterogene / application au stockage d'hydrogene a partir du methylcyclohexane

    Energy Technology Data Exchange (ETDEWEB)

    Roumanie, M.; Pijolat, C. [Ecole Nationale Superieure des Mines, Centre SPIN, Dept. MICC, LPMG-URA CNRS D2021, 42 - Saint-Etienne (France); Meille, V.; Bellefon, C. de [CNRS - CPE, Lab. de Genie des Procedes Catalytiques, 69 - Villeurbanne (France); Pouteau, P.; Delattre, C. [CEA Grenoble, Lab. d' Electronique et de Technologie de l' Intrumentation, LETI, 38 (France)

    2005-07-01

    The use of micro-technology and the miniaturization of various systems such as micro-fuel cell is a current field of activity. The aim of this work is to study and to realize an autonomous catalytic micro-reactor for hydrogen release from methyl-cyclohexane. For this reaction of dehydrogenation, the common catalyst is platinum supported on alumina. Consequently, the general objectives of this work are: (i)to develop a micro-reactor with its heaters, sensors..., (ii)to deposit catalysts in the micro-reactor, and (iii)to study the catalytic conversion of this system. The chip used has been developed by the CEA-LETI for biomedical application especially DNA chip. It is comprising several channels etched in silicon substrate with a classic deep reactive ion etching process. These channels of 100 {mu}m depth are structured with pillars to increase the surface and thus improve the overall reaction rate compare to a channel without pillar. The structured micro-reactor is molecularly bonded with a silicon cover to form an airtight devices. As the silicon is transparent to the infrared wavelength a CCD camera is used to observe the bonding quality. The chips are then connected with micro-tubes to test them. The first tested solution consists in a polyimide-glass capillary of 100 {mu}m OD and 40 {mu}m ID stuck inside the channel entrance and glued with a ceramic cement or glass. A second solution is currently under development with metallic capillaries. The reaction studied is extremely endothermic with a heat of reaction of 204 kJ/mol. Consequently it is necessary to include in this system some heaters to have an autonomous micro-reactor. Thick film resistances of platinum have been deposited by the screen printing and used as micro-heaters. The tests of micro-heaters are realized using the infrared thermographic camera. As the silicon is transparent to infrared wavelength, a sputtered platinum layer has been deposited on the opposite face of the resistances. This layer

  11. Nonlinear time-series-based adaptive control applications

    Science.gov (United States)

    Mohler, R. R.; Rajkumar, V.; Zakrzewski, R. R.

    1991-01-01

    A control design methodology based on a nonlinear time-series reference model is presented. It is indicated by highly nonlinear simulations that such designs successfully stabilize troublesome aircraft maneuvers undergoing large changes in angle of attack as well as large electric power transients due to line faults. In both applications, the nonlinear controller was significantly better than the corresponding linear adaptive controller. For the electric power network, a flexible AC transmission system with series capacitor power feedback control is studied. A bilinear autoregressive moving average reference model is identified from system data, and the feedback control is manipulated according to a desired reference state. The control is optimized according to a predictive one-step quadratic performance index. A similar algorithm is derived for control of rapid changes in aircraft angle of attack over a normally unstable flight regime. In the latter case, however, a generalization of a bilinear time-series model reference includes quadratic and cubic terms in angle of attack.

  12. Fractional order PID controller for improvement of PMSM speed control in aerospace applications

    Energy Technology Data Exchange (ETDEWEB)

    Saraji, Ali Motalebi [Young Researchers and Elite Club, AliAbad Katoul Branch, Islamic Azad University, AliAbad Katoul (Iran, Islamic Republic of); Ghanbari, Mahmood [Department of Electrical Engineering, AliAbad Katoul Branch, Islamic Azad University, AliAbad Katoul (Iran, Islamic Republic of)

    2014-12-10

    Because of the benefits reduced size, cost and maintenance, noise, CO2 emissions and increased control flexibility and precision, to meet these expectations, electrical equipment increasingly utilize in modern aircraft systems and aerospace industry rather than conventional mechanic, hydraulic, and pneumatic power systems. Electric motor drives are capable of converting electrical power to drive actuators, pumps, compressors, and other subsystems at variable speeds. In the past decades, permanent magnet synchronous motor (PMSM) and brushless dc (BLDC) motor were investigated for aerospace applications such as aircraft actuators. In this paper, the fractional-order PID controller is used in the design of speed loop of PMSM speed control system. Having more parameters for tuning fractional order PID controller lead to good performance ratio to integer order. This good performance is shown by comparison fractional order PID controller with the conventional PI and tuned PID controller by Genetic algorithm in MATLAB soft wear.

  13. Fractional order PID controller for improvement of PMSM speed control in aerospace applications

    Science.gov (United States)

    Saraji, Ali Motalebi; Ghanbari, Mahmood

    2014-12-01

    Because of the benefits reduced size, cost and maintenance, noise, CO2 emissions and increased control flexibility and precision, to meet these expectations, electrical equipment increasingly utilize in modern aircraft systems and aerospace industry rather than conventional mechanic, hydraulic, and pneumatic power systems. Electric motor drives are capable of converting electrical power to drive actuators, pumps, compressors, and other subsystems at variable speeds. In the past decades, permanent magnet synchronous motor (PMSM) and brushless dc (BLDC) motor were investigated for aerospace applications such as aircraft actuators. In this paper, the fractional-order PID controller is used in the design of speed loop of PMSM speed control system. Having more parameters for tuning fractional order PID controller lead to good performance ratio to integer order. This good performance is shown by comparison fractional order PID controller with the conventional PI and tuned PID controller by Genetic algorithm in MATLAB soft wear.

  14. Fractional order PID controller for improvement of PMSM speed control in aerospace applications

    International Nuclear Information System (INIS)

    Because of the benefits reduced size, cost and maintenance, noise, CO2 emissions and increased control flexibility and precision, to meet these expectations, electrical equipment increasingly utilize in modern aircraft systems and aerospace industry rather than conventional mechanic, hydraulic, and pneumatic power systems. Electric motor drives are capable of converting electrical power to drive actuators, pumps, compressors, and other subsystems at variable speeds. In the past decades, permanent magnet synchronous motor (PMSM) and brushless dc (BLDC) motor were investigated for aerospace applications such as aircraft actuators. In this paper, the fractional-order PID controller is used in the design of speed loop of PMSM speed control system. Having more parameters for tuning fractional order PID controller lead to good performance ratio to integer order. This good performance is shown by comparison fractional order PID controller with the conventional PI and tuned PID controller by Genetic algorithm in MATLAB soft wear

  15. Software application for quality control protocol of mammography systems

    International Nuclear Information System (INIS)

    Considering the fact that the Quality Control of the technological process of the mammographic system involves testing of a large number of parameters, it is clearly evident that there is a need for using the information technology for gathering, processing and storing of all the parameters that are result of this process. The main goal of this software application is facilitation and automation of the gathering, processing, storing and presenting process of the data related to the qualification of the physical and technical parameters during the quality control of the technological process of the mammographic system. The software application along with its user interface and database has been made with the Microsoft Access 2003 application which is part of the Microsoft Office 2003 software packet and has been chosen as a platform for developing because it is the most commonly used office application today among the computer users in the country. This is important because it will provide the end users a familiar environment to work in, without the need for additional training and improving the computer skills that they posses. Most importantly, the software application is easy to use, fast in calculating the parameters needed and it is an excellent way to store and display the results. There is a possibility for up scaling this software solution so it can be used by many different users at the same time over the Internet. It is highly recommended that this system is implemented as soon as possible in the quality control process of the mammographic systems due to its many advantages.(Author)

  16. Design of Control Application Using Processor Expert Blockset

    Czech Academy of Sciences Publication Activity Database

    Stružka, P.; Waszniowski, L.; Bartosinski, Roman; Bysterský, T.

    Praha: Humusoft, 2007, s. 1-8. ISBN 978-80-7080-658-6. [Technical Computing Prague 2007. Praha (CZ), 14.11.2007-14.11.2007] R&D Projects: GA AV ČR 1ET400750406 Institutional research plan: CEZ:AV0Z10750506 Keywords : design of control application * simulation * model based design * generated code Subject RIV: JC - Computer Hardware ; Software

  17. Applications of monolithic fiber interferometers and actively controlled fibers

    OpenAIRE

    Rugeland, Patrik

    2013-01-01

    The objective of this thesis was to develop applications of monolithic fiber devices and actively controlled fibers. A special twin-core fiber known as a ‘Gemini’ fiber was used to construct equal arm-length fiber interferometers, impervious to temperature and mechanical perturbations. A broadband add/drop multiplexer was constructed by inscribing fiber Bragg gratings in the arms of a Gemini Mach-Zehnder interferometer. A broadband interferometric nanosecond switch was constructed from a micr...

  18. Nonlinear Identification and Control with Solar Energy Applications

    OpenAIRE

    Brus, Linda

    2008-01-01

    Nonlinear systems occur in industrial processes, economical systems, biotechnology and in many other areas. The thesis treats methods for system identification and control of such nonlinear systems, and applies the proposed methods to a solar heating/cooling plant. Two applications, an anaerobic digestion process and a domestic solar heating system are first used to illustrate properties of an existing nonlinear recursive prediction error identification algorithm. In both cases, the accuracy ...

  19. Genetic Programming in Application to Flight Control System Design Optimisation

    OpenAIRE

    Bourmistrova, Anna; Khantsis, Sergey

    2010-01-01

    In this chapter, an application of the Evolutionary Design (ED) is demonstrated. The aim of the design was to develop a controller which provides recovery of a fixed-wing UAV onto a ship under the full range of disturbances and uncertainties that are present in the real world environment. Evolutionary computation is an attractive and quickly developing technique. Methodological shortcomings of the early approaches and lack of intercommunication between different EA schools contributed to the ...

  20. Quantitative application study on the control system of contract progress

    International Nuclear Information System (INIS)

    Quantitative application study on the control system of contract progress, which is based on project management theory and PDCA cycle methods, provides a new way for the contract business management of enterprise, in line with the current situation and the nuclear power enterprise performance management needs. The concept of the system, system development, program design and development of ERP (VBA design) which come from the work experience summary of business managers are convenient and feasible in practical applications. By way of the applications in 2009, 2010, 2011 three-year overhaul contract management and continuous adjustment it has become an important business management tool, which not only effectively guaranteed the contract time and efficiency, but also combines the performance management and contract progress management. This study has provided useful reference for the enterprise management. (authors)

  1. Programming Methods for Road Traffic Control Video Applications

    Directory of Open Access Journals (Sweden)

    Răzvan Ghită

    2011-09-01

    Full Text Available This paper aims to present an application capable of detecting the road traffic load in urban areas using an infrastructure of video cameras in conjunction with a well known programming language: Lab View. The presentation will highlight the role played by video detection technology, what advantages it offers and some examples of its successful use in the area of public transports. Developments in recent years clearly show that video systems certainly can, and will, establish themselves in the market. Also, an important aspect of the application consist of the advantage that it can determine the degree of occupation of a traffic link at certain hours, but it also can realize a traffic optimization by interconnecting this application with a traffic light adaptive, control system.

  2. Case studies on design, simulation and visualization of control and measurement applications using REX control system

    Science.gov (United States)

    Ozana, Stepan; Pies, Martin; Docekal, Tomas

    2016-06-01

    REX Control System is a professional advanced tool for design and implementation of complex control systems that belongs to softPLC category. It covers the entire process starting from simulation of functionality of the application before deployment, through implementation on real-time target, towards analysis, diagnostics and visualization. Basically it consists of two parts: the development tools and the runtime system. It is also compatible with Simulink environment, and the way of implementation of control algorithm is very similar. The control scheme is finally compiled (using RexDraw utility) and uploaded into a chosen real-time target (using RexView utility). There is a wide variety of hardware platforms and real-time operating systems supported by REX Control System such as for example Windows Embedded, Linux, Linux/Xenomai deployed on SBC, IPC, PAC, Raspberry Pi and others with many I/O interfaces. It is modern system designed both for measurement and control applications, offering a lot of additional functions concerning data archiving, visualization based on HTML5, and communication standards. The paper will sum up possibilities of its use in educational process, focused on control of case studies of physical models with classical and advanced control algorithms.

  3. Autonomous Reactor Control Using Model Based Predictive Control for Space Propulsion Applications

    International Nuclear Information System (INIS)

    Reliable reactor control is important to reactor safety, both in terrestrial and space systems. For a space system, where the time for communication to Earth is significant, autonomous control is imperative. Based on feedback from reactor diagnostics, a controller must be able to automatically adjust to changes in reactor temperature and power level to maintain nominal operation without user intervention. Model-based predictive control (MBPC) (Clarke 1994; Morari 1994) is investigated as a potential control methodology for reactor start-up and transient operation in the presence of an external source. Bragg-Sitton and Holloway (2004) assessed the applicability of MBPC to reactor start-up from a cold, zero-power condition in the presence of a time-varying external radiation source, where large fluctuations in the external radiation source can significantly impact a reactor during start-up operations. The MBPC algorithm applied the point kinetics model to describe the reactor dynamics, using a single group of delayed neutrons; initial application considered a fast neutron lifetime (10-3 sec) to simplify calculations during initial controller analysis. The present study will more accurately specify the dynamics of a fast reactor, using a more appropriate fast neutron lifetime (10-7 sec) than in the previous work. Controller stability will also be assessed by carefully considering the dependencies of each component in the defined cost (objective) function and its subsequent effect on the selected 'optimal' control maneuvers

  4. Chaos control using an adaptive fuzzy sliding mode controller with application to a nonlinear pendulum

    International Nuclear Information System (INIS)

    Chaos control may be understood as the use of tiny perturbations for the stabilization of unstable periodic orbits embedded in a chaotic attractor. The idea that chaotic behavior may be controlled by small perturbations of physical parameters allows this kind of behavior to be desirable in different applications. In this work, chaos control is performed employing a variable structure controller. The approach is based on the sliding mode control strategy and enhanced by an adaptive fuzzy algorithm to cope with modeling inaccuracies. The convergence properties of the closed-loop system are analytically proven using Lyapunov's direct method and Barbalat's lemma. As an application of the control procedure, a nonlinear pendulum dynamics is investigated. Numerical results are presented in order to demonstrate the control system performance. A comparison between the stabilization of general orbits and unstable periodic orbits embedded in chaotic attractor is carried out showing that the chaos control can confer flexibility to the system by changing the response with low power consumption.

  5. FireSignal application Node for subsystem control

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, A.S., E-mail: andre.duarte@ipfn.ist.utl.p [Instituto de Plasmas e Fusao Nuclear - Instituto Superior Tecnico, Avenida Rovisco Pais 1, 1049-001 Lisbon (Portugal); Santos, B.; Pereira, T.; Carvalho, B.B.; Fernandes, H.; Neto, A. [Instituto de Plasmas e Fusao Nuclear - Instituto Superior Tecnico, Avenida Rovisco Pais 1, 1049-001 Lisbon (Portugal); Janky, F.; Cahyna, P.; Pisacka, J.; Hron, M. [Institute of Plasma Physics AS CR, Association EURATOM/IPP.CR, Za Slovankou 3, 182 00 Prague (Czech Republic)

    2010-07-15

    Modern fusion experiments require the presence of several subsystems, responsible for the different parameters involved in the operation of the machine. With the migration from the pre-programmed to the real-time control paradigm, their integration in Control, Data Acquisition, and Communication (CODAC) systems became an important issue, as this implies not only the connection to a main central coordination system, but also communications with related diagnostics and actuators. A subsystem for the control and operation of the vacuum, gas injection and baking was developed and installed in the COMPASS tokamak. These tasks are performed by dsPIC microcontrollers that receive commands from a hub computer and send information regarding the status of the operation. Communications are done in the serial protocol RS-232 through fibre optics. Java software, with an intuitive graphical user interface, for controlling and monitoring of the subsystem was developed and installed in a hub computer. In order to allow operators to perform these tasks remotely besides locally, this was integrated in the FireSignal system. Taking advantage of FireSignal features, it was possible to provide the users with, not only the same functionalities of the local application but also a similar user interface. An independent FireSignal Java Node bridges the central server and the control application. This design makes possible to easily reuse the Node for other subsystems or integrate the vacuum slow control in the other CODAC systems. The complete system, with local and remote control, has been installed successfully on COMPASS and has been in operation since April this year.

  6. FireSignal application Node for subsystem control

    International Nuclear Information System (INIS)

    Modern fusion experiments require the presence of several subsystems, responsible for the different parameters involved in the operation of the machine. With the migration from the pre-programmed to the real-time control paradigm, their integration in Control, Data Acquisition, and Communication (CODAC) systems became an important issue, as this implies not only the connection to a main central coordination system, but also communications with related diagnostics and actuators. A subsystem for the control and operation of the vacuum, gas injection and baking was developed and installed in the COMPASS tokamak. These tasks are performed by dsPIC microcontrollers that receive commands from a hub computer and send information regarding the status of the operation. Communications are done in the serial protocol RS-232 through fibre optics. Java software, with an intuitive graphical user interface, for controlling and monitoring of the subsystem was developed and installed in a hub computer. In order to allow operators to perform these tasks remotely besides locally, this was integrated in the FireSignal system. Taking advantage of FireSignal features, it was possible to provide the users with, not only the same functionalities of the local application but also a similar user interface. An independent FireSignal Java Node bridges the central server and the control application. This design makes possible to easily reuse the Node for other subsystems or integrate the vacuum slow control in the other CODAC systems. The complete system, with local and remote control, has been installed successfully on COMPASS and has been in operation since April this year.

  7. FireSignal Application Node for Subsystem Control

    International Nuclear Information System (INIS)

    Modern fusion experiments require the presence of several sub-systems, responsible for the different parameters involved in the operation of the machine. With the migration from the pre-programmed to the real-time control paradigm, their integration in Control, Data Acquisition, and Communication (CODAC) systems became an important issue, as this implies not only the connection to a main central coordination system, but also communications with related diagnostics and actuators. A sub-system for the control and operation of the vacuum, gas injection and baking was developed and installed in the COMPASS tokamak. These tasks are performed by 'dsPIC' micro-controllers that receive commands from a computer and send information regarding the status of the operation. Communications are done in the serial protocol RS-232 through fibre optics at speeds up to 1 Mbaud. A Java software, with an intuitive graphical user interface, for controlling and monitoring the sub-system was developed and installed in a hub computer. In order to allow operators to perform these tasks remotely besides locally, this was integrated in the FireSignal system. Taking advantage of FireSignal features, it was possible to provide the users with, not only the same functionalities of the local application but also a similar user interface. An independent FireSignal Java node bridges the central server and the control application. This design makes possible to easily reuse the node for other subsystems or integrate the vacuum slow control in the other CODAC systems. This document is composed of an abstract and a poster. (authors)

  8. UNICOS CPC6: Automated Code Generation for Process Control Applications

    CERN Document Server

    Fernandez Adiego, B; Prieto Barreiro, I

    2011-01-01

    The Continuous Process Control package (CPC) is one of the components of the CERN Unified Industrial Control System framework (UNICOS) [1]. As a part of this framework, UNICOS-CPC provides a well defined library of device types, amethodology and a set of tools to design and implement industrial control applications. The new CPC version uses the software factory UNICOS Application Builder (UAB) [2] to develop CPC applications. The CPC component is composed of several platform oriented plugins PLCs and SCADA) describing the structure and the format of the generated code. It uses a resource package where both, the library of device types and the generated file syntax, are defined. The UAB core is the generic part of this software, it discovers and calls dynamically the different plug-ins and provides the required common services. In this paper the UNICOS CPC6 package is introduced. It is composed of several plug-ins: the Instance generator and the Logic generator for both, Siemens and Schneider PLCs, the SCADA g...

  9. Formation of oligonucleotide-gated silica shell-coated Fe₃O₄-Au core-shell nanotrisoctahedra for magnetically targeted and near-infrared light-responsive theranostic platform.

    Science.gov (United States)

    Li, Wei-Peng; Liao, Pei-Yi; Su, Chia-Hao; Yeh, Chen-Sheng

    2014-07-16

    A new multifunctional nanoparticle to perform a near-infrared (NIR)-responsive remote control drug release behavior was designed for applications in the biomedical field. Different from the previous studies in formation of Fe3O4-Au core-shell nanoparticles resulting in a spherical morphology, the heterostructure with polyhedral core and shell was presented with the truncated octahedral Fe3O4 nanoparticle as the core over a layer of trisoctahedral Au shell. The strategy of Fe3O4@polymer@Au was adopted using poly-l-lysine as the mediate layer, followed by the subsequent seeded growth of Au nanoparticles to form a Au trisoctahedral shell. Fe3O4@Au trisoctahedra possess high-index facets of {441}. To combine photothermal and chemotherapy in a remote-control manner, the trisoctahedral core-shell Fe3O4@Au nanoparticles were further covered with a mesoporous silica shell, yielding Fe3O4@Au@mSiO2. The bondable oligonucleotides (referred as dsDNA) were used as pore blockers of the mesoporous silica shell that allowed the controlled release, resulting in a NIR-responsive DNA-gated Fe3O4@Au@mSiO2 nanocarrier. Taking advantage of the magnetism, remotely triggered drug release was facilitated by magnetic attraction accompanied by the introduction of NIR radiation. DNA-gated Fe3O4@Au@mSiO2 serves as a drug control and release carrier that features functions of magnetic target, MRI diagnosis, and combination therapy through the manipulation of a magnet and a NIR laser. The results verified the significant therapeutic effects on tumors with the assistance of combination therapy consisting of magnetic guidance and remote NIR control. PMID:24953310

  10. Synthesis of Core/Shell MnFe{sub 2}O{sub 4}/Au Nanoparticles for Advanced Proton Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jeong Chan [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-05-15

    Among many approaches for the surface modification with materials, such as polymers, organic ligands and metals, one of the most attractive ways is using metals. The fabrication of metal-based, monolayer-coated magnetic nanoparticles has been intensively studied. However, the synthesis of metal-capped magnetic nanoparticles with monodIspersities and controllable sizes is still challenged. Recently, gold-capped magnetic nanoparticles have been reported to increase stability and to provide biocompatibility. Magnetic nanoparticle with gold coating is an attractive system, which can be stabilized in biological conditions and readily functionalized through well-established surface modification (Au-S) chemistry. The Au coating offers plasmonic properties to magnetic nanoparticles. The core/shell nanoparticles were transferred from organic to aqueous solutions for biomedical applications. The core/shell structured MnFe{sub 2}O{sub 4}/Au nanoparticles have been prepared and transferred from organic phase to aqueous solutions. The resulting Au-coated nanocrystals may be an attractive system for biomedical applications, which are needed both magnetic resonance imaging and optical imaging. The phase transferred core/shell nanoparticles can be decorated with targeting moiety, such as antibodies, peptides, aptamers, small molecules and ligands for biological applications. The proton treatment with the resulting Au-MnFe{sub 2}O{sub 4} nanoparticles is undergoing.

  11. Synthesis of Core/Shell MnFe2O4/Au Nanoparticles for Advanced Proton Treatment

    International Nuclear Information System (INIS)

    Among many approaches for the surface modification with materials, such as polymers, organic ligands and metals, one of the most attractive ways is using metals. The fabrication of metal-based, monolayer-coated magnetic nanoparticles has been intensively studied. However, the synthesis of metal-capped magnetic nanoparticles with monodIspersities and controllable sizes is still challenged. Recently, gold-capped magnetic nanoparticles have been reported to increase stability and to provide biocompatibility. Magnetic nanoparticle with gold coating is an attractive system, which can be stabilized in biological conditions and readily functionalized through well-established surface modification (Au-S) chemistry. The Au coating offers plasmonic properties to magnetic nanoparticles. The core/shell nanoparticles were transferred from organic to aqueous solutions for biomedical applications. The core/shell structured MnFe2O4/Au nanoparticles have been prepared and transferred from organic phase to aqueous solutions. The resulting Au-coated nanocrystals may be an attractive system for biomedical applications, which are needed both magnetic resonance imaging and optical imaging. The phase transferred core/shell nanoparticles can be decorated with targeting moiety, such as antibodies, peptides, aptamers, small molecules and ligands for biological applications. The proton treatment with the resulting Au-MnFe2O4 nanoparticles is undergoing.

  12. Nutritional Control of mRNA Stability Is Mediated by a Conserved AU-rich Element That Binds the Cytoplasmic Shuttling Protein HuR*

    OpenAIRE

    Yaman, Ibrahim; Fernandez, James; Sarkar, Bedabrata; Schneider, Robert J.; Snider, Martin D.; Nagy, Laura E.; Hatzoglou, Maria

    2002-01-01

    The cationic amino acid transporter, Cat-1, is a high affinity transporter of the essential amino acids, arginine and lysine. Expression of the cat-1 gene increases during nutritional stress as part of the adaptive response to starvation. Amino acid limitation induces coordinate increases in stability and translation of the cat-1 mRNA, at a time when global protein synthesis decreases. It is shown here that increased cat-1 mRNA stability requires an 11 nucleotide AU-rich element within the di...

  13. Application of modern control theory to the design of optimum aircraft controllers

    Science.gov (United States)

    Power, L. J.

    1973-01-01

    A procedure is described for synthesis of optimal aircraft control systems by application of the concepts of optimal control theory to time-invariant linear systems with quadratic performance criteria. Essential in this synthesis procedure is the solution of the Riccati matrix equation which results in a constant linear feedback control law for an output regulator which maintains a plant in an equilibrium in the presence of impulse disturbances. An algorithm is derived for designing maneuverable output regulators with selected state variables for feedback.

  14. Advances and applications in sliding mode control systems

    CERN Document Server

    Zhu, Quanmin

    2015-01-01

    This book describes the advances and applications in Sliding mode control (SMC) which is widely used as a powerful method to tackle uncertain nonlinear systems. The book is organized into 21 chapters which have been organised by the editors to reflect the various themes of sliding mode control. The book provides the reader with a broad range of material from first principles up to the current state of the art in the area of SMC and observation presented in a clear, matter-of-fact style. As such it is appropriate for graduate students with a basic knowledge of classical control theory and some knowledge of state-space methods and nonlinear systems. The resulting design procedures are emphasized using Matlab/Simulink software.    

  15. Application of controlled thermonuclear reactor fusion energy for food production

    International Nuclear Information System (INIS)

    Food and energy shortages in many parts of the world in the past two years raise an immediate need for the evaluation of energy input in food production. The present paper investigates systematically (1) the energy requirement for food production, and (2) the provision of controlled thermonuclear fusion energy for major energy intensive sectors of food manufacturing. Among all the items of energy input to the ''food industry,'' fertilizers, water for irrigation, food processing industries, such as beet sugar refinery and dough making and single cell protein manufacturing, have been chosen for study in detail. A controlled thermonuclear power reactor was used to provide electrical and thermal energy for all these processes. Conceptual design of the application of controlled thermonuclear power, water and air for methanol and ammonia synthesis and single cell protein production is presented. Economic analysis shows that these processes can be competitive. (auth)

  16. A Data Mining Application for ATLAS Detector Controls Data

    CERN Document Server

    Balkin, Reuven

    2013-01-01

    Modern experiments in high energy physics conducted in the Large Hadron Collider in CERN are incredibly complex. Measurements in these experiments require many different and advanced systems, integrated in complicated machines called detectors. ATLAS is a general purpose detector at the LHC. Such an elaborate machine requires a sophisticated control system to allow users to control and monitor its performance. This system, called the ATLAS Detector Control System (DCS), regularly logs information regarding the various subsystems, such as system information coming from DCS servers and software tools. It also notifies users about any malfunctions in the detectors software or hardware using alarms. Accessing log information and alarms efficiently may help detect problem more easily, increase our understanding of the various systems and even help predict and prevent future problems. DCS Data miner (DDM) is an application created using a tool called Splunk, in order to make data mining of log and alarm information...

  17. Delayless acceleration measurement method for motion control applications

    Energy Technology Data Exchange (ETDEWEB)

    Vaeliviita, S.; Ovaska, S.J. [Helsinki University of Technology, Otaniemi (Finland). Institute of Intelligent Power Electronics

    1997-12-31

    Delayless and accurate sensing of angular acceleration can improve the performance of motion control in motor drives. Acceleration control is, however, seldom implemented in practical drive systems due to prohibitively high costs or unsatisfactory results of most acceleration measurement methods. In this paper we propose an efficient and accurate acceleration measurement method based on direct differentiation of the corresponding velocity signal. Polynomial predictive filtering is used to smooth the resulting noisy signal without delay. This type of prediction is justified by noticing that a low-degree polynomial can usually be fitted into the primary acceleration curve. No additional hardware is required to implement the procedure if the velocity signal is already available. The performance of the acceleration measurement method is evaluated by applying it to a demanding motion control application. (orig.) 12 refs.

  18. Secure control systems with application to cyber-physical systems

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Jin [ORNL; Djouadi, Seddik M [ORNL; Nutaro, James J [ORNL; Kuruganti, Phani Teja [ORNL

    2014-01-01

    Control systems are computer-based systems with networked units consisting of sensors, actuators, control processing units, and communication devices. The role of control system is to interact, monitor, and control physical processes. Reactive power control is a fundamental issue in ensuring the security of the power network. It is claimed that Synchronous Condensers (SC) have been used at both distribution and transmission voltage levels to improve stability and to maintain voltages within desired limits under changing load conditions and contingency situations. Performance of PI controller corresponding to various tripping faults are analyzed for SC systems. Most of the eort in protecting these systems has been in protection against random failures or reliability. However, besides failures these systems are subject to various signal attacks for which new analysis are discussed here. When a breach does occur, it is necessary to react in a time commensurate with the physical dynamics of the system as it responds to the attack. Failure to act swiftly enough may result in undesirable, and possibly irreversible, physical eects. Therefore, it is meaningful to evaluate the security of a cyber-physical system, especially to protect it from cyber-attack. Illustrative numerical examples are provided together with an application to the SC systems.

  19. An Autonomic Auto-scaling Controller for Cloud Based Applications

    Directory of Open Access Journals (Sweden)

    Jorge M. Londoño-Peláez

    2013-10-01

    Full Text Available One of the key promises of Cloud Computing is elasticity – applications have at their disposal a very large pool of resources from which they can allocate whatever they need. For any fair-size application the amount of resources is significant and both overprovisioning and under provisioning have a negative impact on the customer. In the first case it leads to over costs and in the second case to poor application performance with negative business repercussions as well. It is then an important problem to provision resources appropriately. In addition, it is well known that application workloads exhibit high variability over short time periods. This creates the necessity of having autonomic mechanisms that make resource management decisions in real time and optimizing both cost and performance. To address these problems we present and autonomic auto-scaling controller that based on the stream of measurements from the system maintains the optimal number of resources and responds efficiently to workload variations, without incurring in over costs for high churn of resources or short duration peaks in the workload. To evaluate the performance of our system we conducted extensive evaluations based on traces of real applications deployed in the cloud. Our results show significant improvements over existing techniques.

  20. Development of automated controller system for controlling reactivity by using FPGA in research reactor application

    International Nuclear Information System (INIS)

    The scope for this research paper is to produce a detail design for Development of Automated Controller System for Controlling Reactivity by using FPGA in Research Reactor Application for high safety nuclear operation. The development of this project including design, purchasing, fabrication, installation, testing and validation and verification for one prototype automated controller system for controlling reactivity in industry local technology for human capacity and capability development towards the first Nuclear Power Programme (NPP) in Malaysia. The specific objectives of this research paper are to Development of Automated Controller System for Controlling Reactivity (ACSCR) in Research Reactor Application (PUSPATI TRIGA Reactor) by using simultaneous movement method; To design, fabricate and produce the accuracy of Control Rods Drive Mechanism to 0.1 mm resolution using a stepper motor as an actuator; To design, install and produce the system response to be more faster by using Field Programmable Gate Array (FPGA) and High Speed Computer; and to improve the Safety Level of the Research Reactor in high safety nuclear operation condition. (author)

  1. Remote and Local Display Applications for the Launch Control System and the Kennedy Ground Control System

    Science.gov (United States)

    Gordillo, Orlando Enrique

    2016-01-01

    This spring 2016 semester, I interned through the OSSI Intern program, sponsored by USRA, at NASA's Kennedy Space Center. I worked under the Engineering Directorate (NE-ES), under the software branch. We are creating the future Launch Control System (LCS). The system monitors, manages and sends commands to ground or flight subsystems. I worked on both the remote applications, which reside in the firing room, and local applications that are in Panel Views. The two kinds of applications have completely different development environments but work in parallel. For each project I was assigned to work with a specific subsystems team. I worked with the Launch Release Subsystem (LRS) on the remote side and with the Environmental Control Subsystem (ECS) on the Local side.

  2. Systematic Study on the Self-Assembled Hexagonal Au Voids, Nano-Clusters and Nanoparticles on GaN (0001).

    Science.gov (United States)

    Pandey, Puran; Sui, Mao; Li, Ming-Yu; Zhang, Quanzhen; Kim, Eun-Soo; Lee, Jihoon

    2015-01-01

    Au nano-clusters and nanoparticles (NPs) have been widely utilized in various electronic, optoelectronic, and bio-medical applications due to their great potentials. The size, density and configuration of Au NPs play a vital role in the performance of these devices. In this paper, we present a systematic study on the self-assembled hexagonal Au voids, nano-clusters and NPs fabricated on GaN (0001) by the variation of annealing temperature and deposition amount. At relatively low annealing temperatures between 400 and 600°C, the fabrication of hexagonal shaped Au voids and Au nano-clusters are observed and discussed based on the diffusion limited aggregation model. The size and density of voids and nano-clusters can systematically be controlled. The self-assembled Au NPs are fabricated at comparatively high temperatures from 650 to 800°C based on the Volmer-Weber growth model and also the size and density can be tuned accordingly. The results are symmetrically analyzed and discussed in conjunction with the diffusion theory and thermodynamics by utilizing AFM and SEM images, EDS maps and spectra, FFT power spectra, cross-sectional line-profiles and size and density plots. PMID:26285135

  3. Systematic Study on the Self-Assembled Hexagonal Au Voids, Nano-Clusters and Nanoparticles on GaN (0001.

    Directory of Open Access Journals (Sweden)

    Puran Pandey

    Full Text Available Au nano-clusters and nanoparticles (NPs have been widely utilized in various electronic, optoelectronic, and bio-medical applications due to their great potentials. The size, density and configuration of Au NPs play a vital role in the performance of these devices. In this paper, we present a systematic study on the self-assembled hexagonal Au voids, nano-clusters and NPs fabricated on GaN (0001 by the variation of annealing temperature and deposition amount. At relatively low annealing temperatures between 400 and 600°C, the fabrication of hexagonal shaped Au voids and Au nano-clusters are observed and discussed based on the diffusion limited aggregation model. The size and density of voids and nano-clusters can systematically be controlled. The self-assembled Au NPs are fabricated at comparatively high temperatures from 650 to 800°C based on the Volmer-Weber growth model and also the size and density can be tuned accordingly. The results are symmetrically analyzed and discussed in conjunction with the diffusion theory and thermodynamics by utilizing AFM and SEM images, EDS maps and spectra, FFT power spectra, cross-sectional line-profiles and size and density plots.

  4. Tailoring the FeRh magnetostructural response with Au diffusion

    OpenAIRE

    Loving, Melissa. L.; De Vries, Mark; Gimenez-Villacorta, Felix; Liu, Xuerong; Langridge, Sean; Heiman, Donald; Marrows, Christopher M.; Lewis, Laura

    2012-01-01

    Factors which contribute to magnetostructural transition control have been demonstrated by study of the effects of Au incorporation on the magnetic and structural character of CsCl-structured equiatomic FeRh thin films. Sputtered films were capped with 2 nm of Au deposited at 873 K and at 323 K and subsequently characterized with magnetometry and synchrotron-based structural probes. Diffusion of Au into the FeRh film layer at 873 K is confirmed by a reduction in the Au capping layer thickness...

  5. Component conversion from pure Au nanorods to multiblock Ag-Au-Ag nanorods assisted by Pt nanoframe templates

    Science.gov (United States)

    Lee, Sangji; Jang, Hee-Jeong; Jang, Ho Young; Kim, Seong Kyu; Park, Sungho

    2016-06-01

    We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications.We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr03484e

  6. Metal-induced assembly of a semiconductor island lattice: Ge truncated pyramids on Au-patterned Si.

    Science.gov (United States)

    Robinson, J T; Liddle, J A; Minor, A; Radmilovic, V; Yi, D O; Greaney, P Alex; Long, K N; Chrzan, D C; Dubon, O D

    2005-10-01

    We report the two-dimensional alignment of semiconductor islands using rudimentary metal patterning to control nucleation and growth. In the Ge on Si system, a square array of submicron Au dots on the Si (001) surface induces the assembly of deposited Ge adatoms into an extensive island lattice. Remarkably, these highly ordered Ge islands form between the patterned Au dots and are characterized by a unique truncated pyramidal shape. A model based on patterned diffusion barriers explains the observed ordering and establishes general criteria for the broader applicability of such a directed assembly process to quantum dot ordering. PMID:16218739

  7. A control strategy for PV stand-alone applications

    Science.gov (United States)

    Slouma, S.; Baccar, H.

    2015-04-01

    This paper proposes a stand-alone photovoltaic (PV) system study in domestic applications. Because of the decrease in power of photovoltaic module as a consequence of changes in solar radiation and temperature which affect the photovoltaic module performance, the design and control of DC-DC buck converter was proposed for providing power to the load from a photovoltaic source.In fact, the control of this converter is carried out with integrated MPPT (Maximum Power Point Tracking) algorithm which ensures a maximum energy generated by the PV arrays. Moreover, the output stage is composed by a battery energy storage system, dc-ac inverter, LCL filter which enables higher efficiency, low distortion ac waveforms and low leakage currents. The control strategy adopted is cascade control composed by two regulation loops.Simulations performed with PSIM software were able to validate the control system.The realization and testing of the photovoltaic system were achieved in the Photovoltaic laboratory of the Centre for Research and Energy Technologies at the Technopark Borj Cedria. Experimental results verify the effeciency of the proposed system.

  8. Analytical chemistry measurements quality control program using computer applications

    International Nuclear Information System (INIS)

    An Analytical Chemistry Measurements Quality Control Program assures the reliability of analytical measurements performed at the Barnwell Nuclear Fuel Plant. The program includes training, methods quality control, replicate samples and measurements, mass measurements, interlaboratory sample exchanges, and standards preparation. This program has been designed to meet the requirements of 10CFR70.57. Portions of the program have been automated by using a PDP 11/35 computer system to provide features which are not readily available in manual systems. These include such items as realtime measurement control, computer calculated bias and precision estimates, various surveillance applications, and evaluation of measurement system variables. The efficiency of the computer system has been demonstrated in gathering and assimilating the results of over 1100 quality control samples during a recent cold chemical checkout campaign. These data were used to determine equations for predicting measurements reliability estimates; to evaluate measurement performance of the analysts, equipment, and measurement period; and to provide directions for chemistry methods modifications and additional training requirements. A procedure of replicate sampling and measuring provides random error estimates. The analytical chemistry measurement quality control activities during the campaign represented about 10% of the total analytical chemistry effort

  9. Wind turbine control applications of turbine-mounted LIDAR

    International Nuclear Information System (INIS)

    In recent years there has been much interest in the possible use of LIDAR systems for improving the performance of wind turbine controllers, by providing preview information about the approaching wind field. Various potential benefits have been suggested, and experimental measurements have sometimes been used to claim surprising gains in performance. This paper reports on an independent study which has used detailed analytical methods for two main purposes: firstly to try to evaluate the likely benefits of LIDAR-assisted control objectively, and secondly to provide advice to LIDAR manufacturers about the characteristics of LIDAR systems which are most likely to be of value for this application. Many different LIDAR configurations were compared: as a general conclusion, systems should be able to sample at least 10 points every second, reasonably distributed around the swept area, and allowing a look-ahead time of a few seconds. An important conclusion is that the main benefit of the LIDAR will be to enhance of collective pitch control to reduce thrust-related fatigue loads; there is some indication that extreme loads can also be reduced, but this depends on other considerations which are discussed in the paper. LIDAR-assisted individual pitch control, optimal Cp tracking and yaw control were also investigated, but the benefits over conventional methods are less clear

  10. SMES application for frequency control during islanded microgrid operation

    Science.gov (United States)

    Kim, A.-Rong; Kim, Gyeong-Hun; Heo, Serim; Park, Minwon; Yu, In-Keun; Kim, Hak-Man

    2013-01-01

    This paper analyzes the operating characteristics of a superconducting magnetic energy storage (SMES) for the frequency control of an islanded microgrid operation. In the grid-connected mode of a microgrid, an imbalance between power supply and demand is solved by a power trade with the upstream power grid. The difference in the islanded mode is a critical problem because the microgrid is isolated from any power grid. For this reason, the frequency control during islanded microgrid operation is a challenging issue. A test microgrid in this paper consisted of a wind power generator, a PV generation system, a diesel generator and a load to test the feasibility of the SMES for controlling frequency during islanded operation as well as the transient state varying from the grid-connected mode to the islanded mode. The results show that the SMES contributes well for frequency control in the islanded operation. In addition, a dual and a single magnet type of SMES have been compared to demonstrate the control performance. The dual magnet has the same energy capacity as the single magnet, but there are two superconducting coils and each coil has half inductance of the single magnet. The effectiveness of the SMES application with the simulation results is discussed in detail.

  11. γ-radiation synthesis of temperature sensitive polymer polyNIPAAm and application in concentration of Au3+ in dilute aqueous solution

    International Nuclear Information System (INIS)

    A Water-soluble temperature sensitive polymer, polyNIPAAm, was synthesized by radiation technology in H2O-THF mixed solutions and further, in simple alcohols, ketones and Cl-containing organic compounds as the solvents. The results showed that all the synthesis was successful. Several polyNIPAAms with different molecular weight were obtained in this way. In addition, the concentration effects of Au2+ in dilute aqueous solutions was investigated by using polyNIPAAm obtained in this work. The concentration coefficient could come up to more than 90%. The effects of acidity and concentration coefficient in the solution were investigated. The optimum conditions were obtained

  12. Direct electron transfer biosensor for hydrogen peroxide carrying nanocomplex composed of horseradish peroxidase and Au-nanoparticle – Characterization and application to bienzyme systems

    Directory of Open Access Journals (Sweden)

    Yusuke Okawa

    2015-09-01

    Full Text Available A reagentless electrochemical biosensor for hydrogen peroxide was fabricated. The sensor carries a monolayer of nanocomplex composed of horseradish peroxidase and Au-nanoparticle, and responds to hydrogen peroxide through the highly efficient direct electron transfer at a mild electrode potential without any soluble mediator. Formation of the nanocomplex was studied with visible spectroscopy and size exclusion chromatography. The sensor performance was analyzed based on a hydrodynamic electrochemical technique and enzyme kinetics. The sensor was applied to fabrication of sensors for glucose and uric acid through further modification of the nanocomplex-carrying electrode with the corresponding hydrogen peroxide-generating oxidases, glucose oxidase and urate oxidase, respectively.

  13. Modélisation et simulation d'un écoulement sous vibration. Application au soudage par ultrasons de composites à matrice thermoplastique.

    OpenAIRE

    Levy, Arthur

    2010-01-01

    Les matériaux composites occupent une place de plus en plus importante dans l'industrie, en particulier aéronautique. Les composites à matrice thermoplastique suscitent aujourd'hui dans ce secteur un très fort engouement par rapport à leurs concurrents thermodurcissables. Le présent travail de thèse se concentre sur le soudage de matériaux composites à matrice thermoplastique. Le procédé de soudage ultrasons consiste à dissiper un travail mécanique au niveau de l'interface. La température aug...

  14. Thiol-PEG-carboxyl-stabilized Fe2O3/Au nanoparticles targeted to CD105: Synthesis, characterization and application in MR imaging of tumor angiogenesis

    International Nuclear Information System (INIS)

    Objective: To detect tumor angiogenesis in tumor-bearing mice using thiol-PEG-carboxyl-stabilized Fe2O3/Au nanoparticles targeted to CD105 on magnetic resonance imaging (MRI). Methods: Fe2O3/Au nanoparticles (hybrids) were prepared by reducing Au3+ on the surface of Fe2O3 nanoparticles. Hybrids were stabilized with thiol-PEG-carboxyl via the Au–S covalent bond, and further conjugated with anti-CD105 antibodies through amide linkages. Characteristics of the hybrid-PEG-CD105 nanoparticles were evaluated. Using these nanoparticles, the labeling specificity of human umbilical vein endothelial cells (HUVECs) was evaluated in vitro. MRI T2*-weighted images were obtained at different time points after intravenous administration of the hybrid-PEG-CD105 nanoparticles in the tumor-bearing mice. After MR imaging, the breast cancer xenografts were immediately resected for immunohistochemistry staining and Prussian blue staining to measure the tumor microvessel density (MVD) and evaluate the labeling of blood microvessels by the hybrid-PEG-CD105 nanoparticles in vivo. Results: The mean diameter of the hybrid-PEG-CD105 nanoparticles was 56.6 ± 8.0 nm, as measured by transmission electron microscopy (TEM). Immune activity of the hybrid-PEG-CD105 nanoparticles was 53% of that of the anti-CD105 antibody, as detected by enzyme-linked immunosorbent assay (ELISA). The specific binding of HUVECs with the hybrid-PEG-CD105 nanoparticles was proved by immunostaining and Prussian blue staining in vitro. For breast cancer xenografts, the combination of the hybrid-PEG-CD105 nanoparticles with blood microvessels was detectable by MRI after 60 min administration of the contrast agent. The T2* relative signal intensity (SIR) was positively correlated with the tumor MVD (R2 = 0.8972). Conclusion: Anti-CD105 antibody-coupled, thiol-PEG-carboxyl-stabilized core–shell Fe2O3/Au nanoparticles can efficiently target CD105 expressed by HUVECs. Furthermore, the hybrid-PEG-CD105 nanoparticles can be

  15. Experimental Physics and Industrial Control System (EPICS): Application source/release control for EPICS R3.11.6

    International Nuclear Information System (INIS)

    This manual describes a set of tools that can be used to develop software for EPICS based control systems. It provides the following features: Multiple applications; the entire system is composed of an arbitrary number of applications: Source/Release Control; all files created or modified by the applications developers can be put under sccs (a UNIX Source/Release control utility): Multiple Developers; it allows a number of applications developers to work separately during the development phase but combine their applications for system testing and for a production system; Makefiles: makefiles are provided to automatically rebuild various application components. For C and state notation programs, Imagefiles are provided

  16. Electrochemically Controlled Reconstitution of Immobilized Ferritins for Bioelectronic Applications

    Science.gov (United States)

    Kim, Jae-Woo; Choi, Sang H.; Lillehei, Peter T.; Chu, Sang-Hong; King, Glen C.; Watt, Gerald D.

    2007-01-01

    Site-specific reconstituted nanoparticles were fabricated via electrochemically-controlled biomineralization through the immobilization of biomolecules. The work reported herein includes the immobilization of ferritin with various surface modifications, the electrochemical biomineralization of ferritins with different inorganic cores, and the electrocatalytic reduction of oxygen on the reconstituted Pt-cored ferritins. Protein immobilization on the substrate is achieved by anchoring ferritins with dithiobis-N-succinimidyl propionate (DTSP). A reconstitution process of site-specific electrochemical biomineralization with a protein cage loads ferritins with different core materials. The ferritin acts as a nano-scale template, a biocompatible cage, and a separator between the nanoparticles. This first demonstration of electrochemically controlled site-specific reconstitution of biomolecules provides a new tool for biomineralization and opens the way to produce the bio-templated nanoparticles by electrochemical control. The nanosized platinum-cored ferritins on gold displayed good catalytic activity for the electrochemical reduction of oxygen, which is applicable to biofuel cell applications. This results in a smaller catalyst loading on the electrodes for fuel cells or other bioelectronic devices.

  17. SMES application for frequency control during islanded microgrid operation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, A-Rong, E-mail: haven21c@changwon.ac.kr [Changwon National University, Sarim-dong, Changwon 641-773 (Korea, Republic of); Kim, Gyeong-Hun; Heo, Serim; Park, Minwon [Changwon National University, Sarim-dong, Changwon 641-773 (Korea, Republic of); Yu, In-Keun, E-mail: yuik@changwon.ac.kr [Changwon National University, Sarim-dong, Changwon 641-773 (Korea, Republic of); Kim, Hak-Man [University of Incheon, Songdo-dong, Incheon 406-772 (Korea, Republic of)

    2013-01-15

    Highlights: ► The operating characteristics of SMES for the frequency control of an islanded microgrid were investigated. ► The SMES contributes well for frequency control in the islanded operation. ► A dual and a single magnet type of SMES have been compared to demonstrate the performances. -- Abstract: This paper analyzes the operating characteristics of a superconducting magnetic energy storage (SMES) for the frequency control of an islanded microgrid operation. In the grid-connected mode of a microgrid, an imbalance between power supply and demand is solved by a power trade with the upstream power grid. The difference in the islanded mode is a critical problem because the microgrid is isolated from any power grid. For this reason, the frequency control during islanded microgrid operation is a challenging issue. A test microgrid in this paper consisted of a wind power generator, a PV generation system, a diesel generator and a load to test the feasibility of the SMES for controlling frequency during islanded operation as well as the transient state varying from the grid-connected mode to the islanded mode. The results show that the SMES contributes well for frequency control in the islanded operation. In addition, a dual and a single magnet type of SMES have been compared to demonstrate the control performance. The dual magnet has the same energy capacity as the single magnet, but there are two superconducting coils and each coil has half inductance of the single magnet. The effectiveness of the SMES application with the simulation results is discussed in detail.

  18. Combining cutting and herbicide application for Ambrosia artemisiifolia control

    Directory of Open Access Journals (Sweden)

    Sölter, Ulrike

    2016-02-01

    Full Text Available The effect on Ambrosia artemisiifolia (common ragweed of combining cutting and herbicide application was studied in pot experiments in Germany and Denmark in 2013. Single plants of common ragweed were established in 2 L pots in glasshouses. Two cutting treatments were conducted: cutting to 10 cm height at the beginning of male budding (BBCH 51-59 and no cutting. Clopyralid (in Germany: Lontrel 600, in Denmark: Matrigon, mesotrione (in Germany and Denmark: Callisto and glyphosate (in Germany: Clinic, in Denmark: Roundup Bio were applied at 4 doses at three different timings: on the day of cutting, one week and two weeks after cutting. The plants were harvested 5 weeks after the last herbicide application. At both sites clopyralid and mesotrione had a low efficacy on common ragweed when applied on developed plants with only minor differences in efficacy at the three timings. Application after cutting improved the efficacy of clopyralid at both sites and of mesotrione in Denmark. In Germany glyphosate had a higher efficacy on noncut plants in comparison to the cut plants, in Denmark it was vice versa. The highest dose of glyphosate provided higher control levels on developed plants than clopyralid and mesotrione at both sites. In Denmark the highest effects were obtained shortly after cutting with the maximum dose of each herbicide and declined with time between cutting and herbicide application. In summary the results demonstrated that herbicides can be applied shortly after cutting without loss of efficacy.

  19. Luminescent metal nanoclusters: controlled synthesis and functional applications

    International Nuclear Information System (INIS)

    Luminescent metal nanoclusters that consist of only several, to tens of, metal atoms and which possess sizes comparable to the Fermi wavelength of electrons have recently attracted significant attention. This new class of luminescent materials not only provides the missing link between atomic and nanoparticle behaviors in metals but also they present abundant novel information for the development of new applicable material systems to meet urgent needs in many areas (such as ultrasensitive sensors for heavy metals, bioimaging, as well as information technology) mainly because of their attractive characteristics, including ultra-small size, good dispersibility, excellent biocompatibility and photostability. In this review, we summarize recent advances in the controlled synthesis and application of luminescent metal nanoclusters, with a particular emphasis on Pt, Mo, Bi and alloy clusters. We also speculate on their future and discuss potential developments for their use in sensors, bioimaging and energy harvesting and conversion. (review)

  20. Application of diffraction methods to materials control during processing procedures

    International Nuclear Information System (INIS)

    The application of diffraction analytical methods for the express-express acquisition of data on the materials structural states and determination of their technological characteristics is described. The application of the roentgenostructural analysis for determination of the carbon steel stamping ability, technological plasticity of the 40Kh steel by pressing, the TiN coating thickness on the 40Kh steel in the process of ion-plasma spraying, the perfection of texture in the alloys for the (Nd2Fe14B, SmCo5). The method for determining crystals orientation in turbine blades with the purpose of providing for suitable crystallographic orientation by production of items through the method of directed crystallization for improving their service life is described. The diffraction analytical methods are characterized in comparison to the traditional control methods by the same advantages, which are nondestructive ones, and specified by high expressivity

  1. Intelligent control and automation technology for nuclear applications

    International Nuclear Information System (INIS)

    Using recently established intelligent mobile robot theory and high technologies in computer science, we have designed an inspection automation system for welded parts of the reactor vessel, and we intend to establish basic technologies. The recent status of those technologies is surveyed for various application areas, and the characteristics and availability of those techniques such as intelligent mobile robot, digital computer control, intelligent user interface, realtime data processing, ultrasonic signal processing, intelligent user interface, intelligent defect recognition, are studied and examined at first. The high performance and compact size inspection system is designed, and if implemented, it is expected to be very efficient in economic point of view. In addition, the use of integrated SW system leads to the reduction of human errors. Through the analysis results and experiences, we investigated the further feasibility of basic technology applications to the various similar operation systems in NPP. (Author)

  2. Applicability of gamma radiation in the control of paper fungi

    International Nuclear Information System (INIS)

    The paper and graphic documents can be affected by biological, chemical and physical agents. Among the biological agents, the most important are the fungi and insects, causing greater damage to bibliographic materials and promoting the deterioration and destruction of scientific-historical or cultural valuable documents. The traditional methods of fungal attack prevention: control of temperature, relative humidity, light, air circulation, etc. and application of fumigants, like ethylene oxide, thymol formaldehyde, etc. However, fungal attacks are becoming more frequent and fumigant applications more restricted by the toxicity, cancerous effects, environmental pollution and damage to some properties of treated material. Research with physical methods, like gamma radiation, in materials affected by fungi and insects have been conducted, at the same time, since the late sixties. (author). 83 refs., 25 figs., 17 tabs

  3. Violence et ordre politique au Nigeria

    OpenAIRE

    Fourchard, Laurent

    2007-01-01

    International audience De nombreuses analyses ont associé le retour d'un régime civil au Nigeria en 1999 au développement d'organisations armées privées et au regain de conflits dits religieux, inter-ethniques ou communautaires. L'application controversée de la charia dans douze Etats du nord et les actions de guérilla dans la région pétrolière du delta ont ainsi largement focalisé l'attention des médias. Le retour de la " démocratie " témoignerait-t-il d'un déclin de l'Etat ? Ces violence...

  4. Développement d’une méthode d’hygiénisation thermique des effluents au moyen d’échangeurs de chaleur (application au lisier porcin)

    OpenAIRE

    Cunault, C.

    2012-01-01

    / La plupart des traitements classiques appliqués aux effluents ont peu d’impact sur les microorganismes pathogènes. Aussi une méthode de traitement thermique des effluents a été développée et son efficacité de désinfection a été évaluée. Son principe repose sur l’application d’un couple temps/température. L’effluent est chauffé en continu puis maintenu chaud avant d’être refroidi. Le système comprend deux échangeurs de chaleur qui permettent de recycler jusqu...

  5. Controlled synthesis of porous platinum nanostructures for catalytic applications.

    Science.gov (United States)

    Cao, Yanqin; Zhang, Junwei; Yang, Yong; Huang, Zhengren; Long, Nguyen Viet; Nogami, Masayuki

    2014-02-01

    Porous platinum, that has outstanding catalytic and electrical properties and superior resistant characteristics to corrosion, has been widely applied in chemical, petrochemical, pharmaceutical, electronic, and automotive industries. As the catalytic activity and selectivity depend on the size, shape and structure of nanomaterials, the strategies for controlling these factors of platinum nanomaterials to get excellent catalytic properties are discussed. Here, recent advances in the design and preparation of various porous platinum nanostructures are reviewed, including wet-chemical synthesis, electro-deposition, galvanic replacement reaction and de-alloying technology. The applications of various platinum nanostructures are also discussed, especially in fuel cells. PMID:24749422

  6. Equivalent sample theory of networked control systems and its application

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The equivalent sample theory and its application in analysis of networked control system (NCS) are presented. After analyzing NCS's scheduling in master-slave mode, the characteristics of time delay and sample are summarized. Looking on master station visiting the slave station as a special sample process, the theory of equivalent sample is presented. And based on it, the stability of a kind of NCS is analyzed. The criterion to determine the upper bound of transmission delay is introduced, which guarantees the stability. Finally, an example with simulation shows the availability and usability of this analysis method.

  7. Controlling End User Computing Applications - a case study

    CERN Document Server

    Chambers, Jamie

    2008-01-01

    We report the results of a project to control the use of end user computing tools for business critical applications in a banking environment. Several workstreams were employed in order to bring about a cultural change within the bank towards the use of spreadsheets and other end-user tools, covering policy development, awareness and skills training, inventory monitoring, user licensing, key risk metrics and mitigation approaches. The outcomes of these activities are discussed, and conclusions are drawn as to the need for appropriate organisational models to guide the use of these tools.

  8. New technology in digital signal controllers, study & applications

    Directory of Open Access Journals (Sweden)

    Jaime Fonseca Beltrán

    2012-05-01

    Full Text Available This paper addresses the new technologies of digital signal controllers (DSC, is a general reference of the different companies making this type of device, in order that the reader has a general idea of the various products available market, highlighting thedifferences it with its predecessors, so as to identify in a clear and precise differences. This work was conceived in order to provide the user, a transition in the management of PIC ® microcontrollers general purpose, to the management of advanced microcontrollerssuch as the dsPIC., Same to be found from the use of general purpose, even those who have special features designed to more specialized applications.

  9. Electric Voltage Control as an Implementation of Neural Network Applications

    Directory of Open Access Journals (Sweden)

    A. A. Al-Rababah

    2008-01-01

    Full Text Available Present study was proposed the monitoring of mathematical model of electric voltage source with using neural network for application in control systems as sensor and command signal. The monitoring system, consist of toroidal choke or transformer with high saturated ferromagnetic cores. The input information we receive from current periodic curves. The current was distributed into Fourier or walsh series. The combination of these harmonics and their amplitude values determine monitoring voltage value directly. For increase of this system precision, the mathematical model was constructed on basis of partial differential quasi-stationary electromagnetic field equations and ordi-nary differential electromagnetic circuit equations combination.

  10. LSI development for microcomputer application to weapon control

    International Nuclear Information System (INIS)

    The concept of the secure PAL (permissive-action link) system has been proposed for the control of nuclear weapons. Essential to the successful application of this system is the design of a miniature, all-LSI (large-scale-integration), secure PAL coded switch (SPCS). Two prototypes have been constructed to demonstrate the feasibility of a coded switch that occupies a volume of less than 0.5 cm3. Engineering development work on this system since 1972 is discussed, as is current activity. (auth)

  11. Parallel and vector computation for stochastic optimal control applications

    Science.gov (United States)

    Hanson, F. B.

    1989-01-01

    A general method for parallel and vector numerical solutions of stochastic dynamic programming problems is described for optimal control of general nonlinear, continuous time, multibody dynamical systems, perturbed by Poisson as well as Gaussian random white noise. Possible applications include lumped flight dynamics models for uncertain environments, such as large scale and background random atmospheric fluctuations. The numerical formulation is highly suitable for a vector multiprocessor or vectorizing supercomputer, and results exhibit high processor efficiency and numerical stability. Advanced computing techniques, data structures, and hardware help alleviate Bellman's curse of dimensionality in dynamic programming computations.

  12. Applications of nonlinear systems theory to control design

    Science.gov (United States)

    Hunt, L. R.; Villarreal, Ramiro

    1988-01-01

    For most applications in the control area, the standard practice is to approximate a nonlinear mathematical model by a linear system. Since the feedback linearizable systems contain linear systems as a subclass, the procedure of approximating a nonlinear system by a feedback linearizable one is examined. Because many physical plants (e.g., aircraft at the NASA Ames Research Center) have mathematical models which are close to feedback linearizable systems, such approximations are certainly justified. Results and techniques are introduced for measuring the gap between the model and its truncated linearizable part. The topic of pure feedback systems is important to the study.

  13. Reduction of graphene oxide by 100 MeV Au ion irradiation and its application as H2O2 sensor

    International Nuclear Information System (INIS)

    Graphene oxide (GO) synthesized from a modified Hummer’s method was reduced (referred, rGO) by using 100 MeV Au ion species and its response to the sense H2O2 was investigated. The changes in the atomic composition and structural properties of rGO after irradiation were studied using x-ray diffraction, Fourier transform infrared spectroscopy and x-ray photo-electron spectroscopy. These results suggested that the removal of the oxygen-containing functional groups and the improvement of the electrochemical performance of reduced graphene oxide (rGO) after ion irradiation. Raman spectroscopic results revealed the increase in the disorder parameter (I D/I G) after Au ion irradiation and also the formation of a large number of small sp2 domains due to the electronic energy loss of ion beam. The resultant rGO was investigated for H2O2 sensing using electrochemical techniques and it showed a good response. (paper)

  14. M\\TiO₂ (M=Au, Ag) transparent aqueous sols and its application on polymeric surface antibacterial post-treatment.

    Science.gov (United States)

    Wu, Liangzhuan; Yu, Yuan; Song, Le; Zhi, Jinfang

    2015-05-15

    In this paper, we reported a simple and mild chemical method for synthesis of crystalline metal\\TiO2 (M=Au, Ag) transparent aqueous sols at low temperature (80°C). It should be found that the as-synthesized metal\\TiO2 sols could easily be coated on the flexible PET surfaces of the through the as-developed electroless-plating-like solution deposition (EPLSD) procedure. The as-prepared metal\\TiO2 sols and related flexible thin film were characterized by TEM, SEM, XRD, UV-vis, and FTIR analysis. The results showed that the Au and Ag nanoparticles can significantly improve the optical absorption properties of TiO2 due to the surface plasmon generated by the noble metal, which in turn enhanced the photo-induced antibacterial performance of the as-prepared metal\\TiO2 flexible film. Moreover, the photo-generated electrons could transfer between the metal and titanium dioxide under different irradiation (ultraviolet or visible light), which could significantly reduce the recombination of photo-induced electrons and holes, resulting in the better photo-induced antibacterial performance. Therefore, the EPLSD procedure may be used as a general polymeric surface antibacterial post-treatment procedure for preparing the metal\\TiO2 flexible film because of the noble metal enhanced antibacterial performance. PMID:25678155

  15. Enhanced electrochromic coloration of poly(3-hexylthiophene) films by electrodeposited Au nanoparticles.

    Science.gov (United States)

    Nah, Yoon-Chae

    2013-05-01

    Au nanoparticles and poly(3-hexylthiophene) (P3HT) composite films were prepared by electrodeposition of Au nanoparticles using pulse-current electrodeposition followed by the spin coating of P3HT and their enhanced electrochromic coloration was investigated. A relatively uniformed Au nanoparticle was obtained by the controlled electrodeposition on indium tin oxide (ITO) substrate and plasmon absorption band of Au nanoparticles were observed. Optical and electrochemical properties of Au/P3HT composite films were compared with the pure P3HT films. The enhanced electrochromic absorption of the composite films was observed due to the surface plasmon resonance of the Au nanoparticles. PMID:23858881

  16. Indirect sensorless speed control of a PMSG for wind application

    DEFF Research Database (Denmark)

    Diaz, S.A.; Silva, C.; Juliet, J.;

    2009-01-01

    In this paper, the sensorless control of a permanent magnet synchronous generator (PMSG) for wind turbine applications is presented. This kind of generator has many advantages, such as: high efficiency, high power density and low maintenance requirements. To improve these characteristics in the...... sensorless strategies are avoided. The sensorless scheme proposed here is based on a synchronous d-q frame phaselocked loop (PLL) for back-emf estimation, as those used in voltage phase detection for grid connected converters. The wind turbine control includes maximum power point tracking (MPPT) using the...... whole wind generator system a sensorless scheme is proposed, thereby avoiding problems of electromagnetic interferences and failures in the position sensor. Usually, in wind drive system, the generator is not operated a very low speeds, therefore problems related to low back-emf for flux estimation in...

  17. Lockheed laminar-flow control systems development and applications

    Science.gov (United States)

    Lange, Roy H.

    1987-01-01

    Progress is summarized from 1974 to the present in the practical application of laminar-flow control (LFC) to subsonic transport aircraft. Those efforts included preliminary design system studies of commercial and military transports and experimental investigations leading to the development of the leading-edge flight test article installed on the NASA JetStar flight test aircraft. The benefits of LFC on drag, fuel efficiency, lift-to-drag ratio, and operating costs are compared with those for turbulent flow aircraft. The current activities in the NASA Industry Laminar-Flow Enabling Technologies Development contract include summaries of activities in the Task 1 development of a slotted-surface structural concept using advanced aluminum materials and the Task 2 preliminary conceptual design study of global-range military hybrid laminar flow control (HLFC) to obtain data at high Reynolds numbers and at Mach numbers representative of long-range subsonic transport aircraft operation.

  18. Applicability of the Sunna dosimeter for food irradiation control

    International Nuclear Information System (INIS)

    The quick development concerning the commercial application of food irradiation in the USA recently resulted in growing marketing of irradiated red meat as well as irradiated fresh and dried fruits. These gamma and electron irradiation technologies require specific dosimetry systems for process control. The new version of the Sunna dosimeter has been characterized in gamma, electron and bremsstrahlung radiation fields by measuring the optically stimulated luminescence (osl) at 530 nm both below and above 1 kGy, i.e. for disinfestation and for meat irradiation purposes. No humidity and no significant dose rate effect on the green osl signal was observed. The temperature coefficient was determined from 0 deg. C up to about 40 deg. C and to stabilize the osl signal after irradiation a heat treatment method was introduced. Based on these investigations the Sunna 'gamma' film is a suitable candidate for dose control below and above 1 kGy for food irradiation technologies

  19. Microcontroller Based Solar Charge Controller for Power Application

    Directory of Open Access Journals (Sweden)

    Mr. Vikas Khare

    2012-01-01

    Full Text Available Photovoltaic cell converts solar energy directly into electricity. This paper describes a design of microcontroller based solar charge controller for power application.[2] The work of the Paper is to charge a 12 volt battery by using a 50 watt solar panel with maximum power. This circuit regulates the charging of battery in a solar system by monitoring battery voltage and switching the solar or other power source off when the battery reached a preset value.[1] The microprocessor based charge control technique presented in this paper shows the assurance for charging the battery with the maximum power. Though the voltage of photovoltaic cell and the voltage of battery are different, the maximum power can be attained during battery charging from the photovoltaic cell through this technique. The voltages of the solar panel are different in different time and days.

  20. Application of Risk Management for Control and Monitoring Systems

    CERN Document Server

    Grau, S; Balda, F; Chouvelon, A

    2001-01-01

    This paper presents an application of the state of the art and new trends for risk management of safety-related control and monitoring systems, currently applied in the industry. These techniques not only enable to manage safety and reliability issues but they also help in the control of quality and economic factors affected by the availability and maintenance of the system. The method includes an unambiguous definition of the system in terms of functions and a systematic analysis of hazardous situations, undesired events and possible malfunctions. It also includes the identification and quantification of the risk associated to the system. The required risk reduction is specified in terms of safety integrity levels. The safety integrity level results in requirements, preventive measures, possible improvements and recommendations to assure the satisfactory management of the risk.