WorldWideScience

Sample records for anomalous temperature dependence

  1. Anomalous Temperature Dependence of Magnetic Moment in Monodisperse Antiferromagnetic Nanoparticles

    Science.gov (United States)

    Gillaspie, Dane; Gu, B.; Wang, W.; Shen, J.

    2005-03-01

    1 Condensed Matter Sciences Division, Oak Ridge National Laboratory*, TN 37831 2 Department of Physics and Astronomy, The University of Tennessee, TN 37996 3 Environmental Sciences Division, Oak Ridge National Laboratory*, TN 37831 Recent experiments [1] and theory [2] from AFM nanoparticles showed that they exhibit sizable net magnetization, which increases with increasing temperature. In order to further understand such peculiar temperature dependence, we have measured the magnetic properties of monodisperse hematite (α-Fe2O3) nanoparticles, grown using a microemulsion precipitation technique, which minimizes the impact of the particle moment distribution on the measured properties of the samples. Our measured results indicate that the net magnetization of these nanoparticles, when small, indeed increases linearly with increasing temperature. This is in sharp contrast to the bulk-like behavior of α-Fe2O3, which was observed in particles with size larger than 120 nm. [1] M. Seehra et al, Phys. Rev. B 61, 3513 (2000) [2] S. Mørup, C. Frandsen, Phys. Rev. Lett. 92, 217201 (2004) *Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Dept. of Energy under contract DE-AC05-00OR22725

  2. Anomalous temperature dependence of the electrical resistivity of molten Sb

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Using the d.c. four-probe method, the electrical resistivity of high-purity liquid Sb has been accurately measured as functions of temperature. It is observed that the resistivity of liquid Sb changes abnormally with increasing temperature, which is very different from that of simple liquid metals. Based on the reported structure factor at several temperatures, the results obtained in this work have been discussed and interpreted qualitatively according to Ziman theory. The analysis suggests that the existence of shortrange order structure near the melting point can account for the abnormal phenomenon observed in the resistivity of liquid Sb, in which semimetal-metal transaction takes place in the melting process. At the same time, the progress of the structure change of liquid Sb with temperature has also been pointed out.``

  3. Anomalous temperature dependence in the Raman spectra of l-alanine: Evidence for dynamic localization

    Energy Technology Data Exchange (ETDEWEB)

    Migliori, A.; Maxton, P.M.; Clogston, A.M.; Zirngiebl, E.; Lowe, M.

    1988-12-15

    We measured the temperature dependence of the intensity of the two lowest Raman modes in single crystals of l-alanine. The sum of the intensities obeys Maxwell-Boltzman statistics accurately from 20 to 340 K but the intensities of the individual lines are anomalous. This behavior is explained by assuming that both lines share the same degrees of freedom but that a mode instability is triggered abruptly at an occupation of seven quanta. This instability, which has an activation energy of 500 K, is observed at temperatures as low as 20 K, possibly indicating the existence of dynamic localization of vibrational energy.

  4. Anomalous temperature dependent magneto-conductance in organic light-emitting diodes with multiple emissive states

    International Nuclear Information System (INIS)

    The temperature dependence of the magneto-conductance (MC) in organic electron donor-acceptor hybrid and layer heterojunction diodes was studied. The MC value increased with temperature in layer heterojunction and in 10 wt. % hybrid devices. An anomalous decrease of the MC with temperature was observed in 25 wt. %–50 wt. % hybrid devices. Further increasing donor concentration to 75 wt. %, the MC again increased with temperature. The endothermic exciplex-exciton energy transfer and the change in electroplex/exciton ratio caused by change in charge transport with temperature may account for these phenomena. Comparative studies of the temperature evolutions of the IV curves and the electroluminescence and photoluminescence spectra back our hypothesis

  5. The temperature dependent anomalous Hall effect in La-Ca-Mn-O films

    International Nuclear Information System (INIS)

    The colossal magnetoresistance of La1-xCaxMnO3 has been reported in many experiments. The authors present their study of the anomalous Hall effect in epitaxial La0.67Ca0.33MnO3 thin films. They have measured the temperature dependence of resistivity, magnetization and AHE coefficients between 300K and 5K for the samples grown on different substrates. From these studies, the relation between the resistivity and AHE coefficient as well as the temperature dependence of AHE coefficient are explored. The results show that the direction of AHE is reversed below approximately 100K. This sign reversal is discussed in term of the change of band structure and the co-existence of hole-like and electron-like conduction

  6. Anomalous temperature dependent photoluminescence properties of CdSxSe1-x quantum dots

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    CdSxSe1-x quantum dots were fabricated by a simple spin-coating heat volatilization method on InP wafer.Temperature dependent photoluminescence of CdSxSe1-x quantum dots was carried out in a range of 10-300 K.The integrated photoluminescence intensity revealed an anomalous behavior with increasing temperature in the range of 180-200 K.The band gap energy showed a redshift of 61.34 meV when the temperature increased from 10 to 300 K.The component ratio of S to Se in the CdSxSe1-x quantum dots was valued by both the X-ray diffraction data and photoluminescence peak energy at room temperature according to Vegard Law.Moreover,the parameters of the Varshni relation for CdS0.9Se0.1 materials were also obtained using photoluminescence peak energy as a function of temperature and the best-fit curve:α=(3.5 ± 0.1)10-4 eV/K,and β=210 ± 10 K (close to the Debye temperature θD of the material).

  7. Anomalous temperature dependence of the current in a metal-oxide-polymer resistive switching diode

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Henrique L; Rocha, Paulo R F; Kiazadeh, Asal [Center of Electronics Optoelectronics and Telecommunications (CEOT) Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); De Leeuw, Dago M [Philips Research Laboratories, Professor Holstlaan 4, 5656 AA Eindhoven (Netherlands); Meskers, Stefan C J, E-mail: hgomes@ualg.pt [Molecular Materials and Nanosystems, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven (Netherlands)

    2011-01-19

    Metal-oxide polymer diodes exhibit non-volatile resistive switching. The current-voltage characteristics have been studied as a function of temperature. The low-conductance state follows a thermally activated behaviour. The high-conductance state shows a multistep-like behaviour and below 300 K an enormous positive temperature coefficient. This anomalous behaviour contradicts the widely held view that switching is due to filaments that are formed reversibly by the diffusion of metal atoms. Instead, these findings together with small-signal impedance measurements indicate that creation and annihilation of filaments is controlled by filling of shallow traps localized in the oxide or at the oxide/polymer interface.

  8. Anomalous temperature dependence of PAL and 2D-ACAR in Ni-rich Ni-Ti alloy

    International Nuclear Information System (INIS)

    Ni-rich NiTi alloys have been investigated by means of PAL spectroscopy, electrical resistivity measurement, 2D-ACAR and first principle calculation. An anomaly of positron lifetime has been observed for Ni52Ti48 alloy which does not exhibit the martensitic transformation: positron lifetime increases by about 25% with lowering temperature. Almost the same change in positron lifetime is observed on the subsequent heating run with little hysteresis. The 2D-ACAR for the same alloy also depends on temperature anomalously: the peak height of the 2D-ACAR increases by 20% and the anisotropy decreases by 60% with lowering temperature. Experimental results are discussed with the idea of Fermi surface nesting of B2-NiTi which has been evaluated from the 2D-ACAR spectra by LCW theory. (orig.)

  9. Anomalous temperature-dependent spin-valley polarization in monolayer WS2

    Science.gov (United States)

    Hanbicki, A. T.; Kioseoglou, G.; Currie, M.; Hellberg, C. Stephen; McCreary, K. M.; Friedman, A. L.; Jonker, B. T.

    2016-01-01

    Single layers of transition metal dichalcogenides (TMDs) are direct gap semiconductors with nondegenerate valley indices. An intriguing possibility for these materials is the use of their valley index as an alternate state variable. Several limitations to such a utility include strong intervalley scattering, as well as multiparticle interactions leading to multiple emission channels. We prepare single-layer WS2 films such that the photoluminescence is from either the neutral or charged exciton (trion). After excitation with circularly polarized light, the neutral exciton emission has zero polarization. However, the trion emission has a large polarization (28%) at room temperature. The trion emission also has a unique, non-monotonic temperature dependence that is a consequence of the multiparticle nature of the trion. This temperature dependence enables us to determine that intervalley scattering, electron-hole radiative recombination, and Auger processes are the dominant mechanisms at work in this system. Because this dependence involves trion systems, one can use gate voltages to modulate the polarization (or intensity) emitted from TMD structures.

  10. Temperature-dependent reaction pathways for the anomalous hydrocracking of triglycerides in the presence of sulfided Co-Mo-catalyst.

    Science.gov (United States)

    Anand, Mohit; Sinha, Anil K

    2012-12-01

    Kinetic studies and product profiling was done to understand the anomalous cracking of jathropha oil triglycerides in the presence of sulfided Co-Mo/Al(2)O(3) catalyst. At temperatures between 320 and 340 °C, only deoxygenation and oligomerization reactions took place whereas at temperatures above 340 °C, internal conversions between the products and direct conversion to lighter and middle distillates were favored High pressures (80 bar) and H(2)/feed ratios (>1500) were necessary to minimize oligomerization of the products and to increase the lifespan of the catalyst. Lumped kinetic models were validated with experimental results. Activation energies for the formation of lighter (83 kJ/mol) and middle fractions (126 kJ/mol) were higher than those for the heavy (47 kJ/mol) and deoxygenated (47 kJ/mol) products. Jatropha oil triglycerides hydroconversion pathways were dependent on temperature and the triglycerides could be hydrocracked to lower range hydrocarbons (C5-C14) by increasing the reaction temperatures. PMID:23073102

  11. Anomalous Temperature Dependence of Photoluminescence in InAs/InAlGaAs/InP Quantum Wire and Dot Hybrid Nanostructures

    Institute of Scientific and Technical Information of China (English)

    YANG Xin-Rong; XU Bo; WANG Hai-Fei; ZHAO Guo-Qing; SHI Shu-Hui; SHEN Xiao-Zhi; LI Jun-Feng; WANG Zhan-Guo

    2011-01-01

    Self-assembled InAs quantum wires (QWRs) are fabricated on an InP substrate by solid-source molecular beam epitaxy (SSMBE). Photoluminescence (PL) spectra are investigated in these nanostructures as a function of temperature. An anomalous enhancement of PL intensity and a temperature insensitive PL emission are observed from lnAs nanostructures grown on InP substrates using lnAIGaAs as the matrix layer and the origin of this phenomenon is discussed. We attribute the anomalous temperature dependence of photoluminescence to the formation of Al-rich and In-rich region in the InAlGaAs buffer layer and the cap layer.%@@ Self-assembled InAs quantum wires (QWRs) are fabricated on an InP substrate by solid-source molecular beam epitaxy (SSMBE).Photoluminescence (PL) spectra are investigated in these nanostructures as a function of temperature.An anomalous enhancement of PL intensity and a temperature insensitive PL emission are observed from InAs nanostructures grown on InP substrates using InAlGaAs as the matrix layer and the origin of this phenomenon is discussed.We attribute the anomalous temperature dependence of photoluminescence to the formation of Al-rich and In-rich region in the InAlGaAs buffer layer and the cap layer.

  12. Temperature dependence of the perpendicular magnetic anisotropy in Ta/Co2FeAl/MgO structures probed by Anomalous Hall Effect

    Science.gov (United States)

    Gabor, M. S.; Petrisor, T.; Pop, O.; Colis, S.; Tiusan, C.

    2015-10-01

    We report a detailed study of the temperature dependence of the magnetic anisotropy in Ta/Co2FeAl/MgO structures by means of Anomalous Hall Effect measurements. The volume magnetic anisotropy, although negligible at room temperature, shows a non-negligible value at low temperatures and favors an in-plane easy magnetization axis. The surface magnetic anisotropy, which promotes the perpendicular magnetic easy axis, shows an increase from 0.76 ± 0.05 erg /cm2 at 300 K, up to 1.08 ± 0.04 erg /cm2 at 5 K, attributed to the evolution of the Co2FeAl layer saturation magnetization with temperature.

  13. Structural Origin of the Anomalous Temperature Dependence of the Local Magnetic Moments in the CaFe2As2 Family of Materials

    Science.gov (United States)

    Ortenzi, L.; Gretarsson, H.; Kasahara, S.; Matsuda, Y.; Shibauchi, T.; Finkelstein, K. D.; Wu, W.; Julian, S. R.; Kim, Young-June; Mazin, I. I.; Boeri, L.

    2015-01-01

    We report a combination of Fe K β x-ray emission spectroscopy and density functional reduced Stoner theory calculations to investigate the correlation between structural and magnetic degrees of freedom in CaFe2(As1-xPx) 2 . The puzzling temperature behavior of the local moment found in rare earth-doped CaFe2As2 [H. Gretarsson et al., Phys. Rev. Lett. 110, 047003 (2013)] is also observed in CaFe2(As1-xPx) 2 . We explain this phenomenon based on first-principles calculations with scaled magnetic interaction. One scaling parameter is sufficient to describe quantitatively the magnetic moments in both CaFe2(As1-xPx) 2 (x =0.055 ) and Ca0.78La0.22Fe2As2 at all temperatures. The anomalous growth of the local moments with increasing temperature can be understood from the observed large thermal expansion of the c -axis lattice parameter combined with strong magnetoelastic coupling. These effects originate from the strong tendency to form As-As dimers across the Ca layer in the CaFe2As2 family of materials. Our results emphasize the dual local-itinerant character of magnetism in Fe pnictides.

  14. Anomalous scaling in an age-dependent branching model

    OpenAIRE

    Keller-Schmidt, Stephanie; Tugrul, Murat; Eguíluz, Víctor M.; Hernández-García, Emilio; Klemm, Konstantin

    2015-01-01

    We introduce a one-parametric family of tree growth models, in which branching probabilities decrease with branch age $\\tau$ as $\\tau^{-\\alpha}$. Depending on the exponent $\\alpha$, the scaling of tree depth with tree size $n$ displays a transition between the logarithmic scaling of random trees and an algebraic growth. At the transition ($\\alpha=1$) tree depth grows as $(\\log n)^2$. This anomalous scaling is in good agreement with the trend observed in evolution of biological species, thus p...

  15. Anomalous scaling in an age-dependent branching model

    OpenAIRE

    Keller-Schmidt, Stephanie; Tugrul, Murat; Eguiluz, Victor M.; Hernandez-Garcia, Emilio; Klemm, Konstantin

    2010-01-01

    We introduce a one-parametric family of tree growth models, in which branching probabilities decrease with branch age $\\tau$ as $\\tau^{-\\alpha}$. Depending on the exponent $\\alpha$, the scaling of tree depth with tree size $n$ displays a transition between the logarithmic scaling of random trees and an algebraic growth. At the transition ($\\alpha=1$) tree depth grows as $(\\log n)^2$. This anomalous scaling is in good agreement with the trend observed in evolution of biological species, thus p...

  16. Anomalous scaling in an age-dependent branching model.

    Science.gov (United States)

    Keller-Schmidt, Stephanie; Tuğrul, Murat; Eguíluz, Víctor M; Hernández-García, Emilio; Klemm, Konstantin

    2015-02-01

    We introduce a one-parametric family of tree growth models, in which branching probabilities decrease with branch age τ as τ(-α). Depending on the exponent α, the scaling of tree depth with tree size n displays a transition between the logarithmic scaling of random trees and an algebraic growth. At the transition (α=1) tree depth grows as (logn)(2). This anomalous scaling is in good agreement with the trend observed in evolution of biological species, thus providing a theoretical support for age-dependent speciation and associating it to the occurrence of a critical point. PMID:25768548

  17. Anomalous scaling in an age-dependent branching model.

    Science.gov (United States)

    Keller-Schmidt, Stephanie; Tuğrul, Murat; Eguíluz, Víctor M; Hernández-García, Emilio; Klemm, Konstantin

    2015-02-01

    We introduce a one-parametric family of tree growth models, in which branching probabilities decrease with branch age τ as τ(-α). Depending on the exponent α, the scaling of tree depth with tree size n displays a transition between the logarithmic scaling of random trees and an algebraic growth. At the transition (α=1) tree depth grows as (logn)(2). This anomalous scaling is in good agreement with the trend observed in evolution of biological species, thus providing a theoretical support for age-dependent speciation and associating it to the occurrence of a critical point.

  18. Anomalous scaling in an age-dependent branching model

    OpenAIRE

    Keller-Schmidt, Stephanie; Tugrul, Murat; Víctor M Eguíluz; Hernández-García, Emilio; Klemm, Konstantin

    2015-01-01

    © 2015 American Physical Society. We introduce a one-parametric family of tree growth models, in which branching probabilities decrease with branch age τ as τ-α. Depending on the exponent α, the scaling of tree depth with tree size n displays a transition between the logarithmic scaling of random trees and an algebraic growth. At the transition (α=1) tree depth grows as (logn)2. This anomalous scaling is in good agreement with the trend observed in evolution of biological species, thus provid...

  19. Effect of entropy on anomalous transport in electron-temperature-gradient-modes

    Energy Technology Data Exchange (ETDEWEB)

    Yaqub Khan, M., E-mail: myaqubsultani@gmail.com [Department of Basic Sciences, Riphah International University, Islamabad 44000 (Pakistan); National Centre for Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Iqbal, J. [Department of Mathematics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Ul Haq, A. [Faculty of Engineering and Applied Physics, Riphah International University, Islamabad 44000 (Pakistan)

    2014-05-15

    Due to the interconnection of entropy with temperature and density of plasma, it would be interesting to investigate plasma related phenomena with respect to entropy. By employing Braginskii transport equations, it is proved that entropy is proportional to a function of potential and distribution function of entropy is re-defined, ∇S–drift in obtained. New dispersion relation is derived; it is found that the anomalous transport depends on the gradient of the entropy.

  20. Temperature dependence of the magnetization of canted spin structures

    DEFF Research Database (Denmark)

    Jacobsen, Henrik; Lefmann, Kim; Brok, Erik;

    2012-01-01

    Numerous studies of the low-temperature saturation magnetization of ferrimagnetic nanoparticles and diamagnetically substituted ferrites have shown an anomalous temperature dependence. It has been suggested that this is related to freezing of canted magnetic structures. We present models...... for the temperature dependence of the magnetization of a simple canted spin structure in which relaxation can take place at finite temperatures between spin configurations with different canting angles. We show that the saturation magnetization may either decrease or increase with decreasing temperature, depending...

  1. Anomalous collisional absorption of laser pulses in underdense plasma at low temperature

    Science.gov (United States)

    Kundu, M.

    2015-04-01

    In a previous paper [M. Kundu, Phys. Plasmas 21, 013302 (2014), 10.1063/1.4862038], fractional collisional absorption (α ) of laser light in underdense plasma was studied by using a classical scattering model of electron-ion collision frequency νei, where total velocity v =√{vth2+v02 } (with vth and v0 as the thermal and the ponderomotive velocity of an electron) dependent Coulomb logarithm lnΛ (v ) was shown to be responsible for the anomalous (unconventional) increase of νei and α (∝νei ) with the laser intensity I0 up to a maximum value about an intensity Ic in the low temperature (TeIc . One may object that the anomalous increase in νei and α were partly due to the artifact introduced in lnΛ through the maximum cutoff distance bmax∝v . In this work, we show similar anomalous increase in νei and α versus I0 (in the low temperature and underdense density regime) with more accurate quantum and classical kinetic models of νei without using lnΛ , but with a proper choice of the total velocity dependent inverse cutoff length kmax∝v2 (classical) or kmax∝v (quantum). For a given I0<5 ×1014Wcm -2 , νei versus Te also exhibits so far unnoticed identical anomalous increase as νei versus I0, even if the conventional kmax∝vth2 or kmax∝vth (without v0) is chosen. The total velocity dependent kmax in the kinetic models, as proposed here, is found to explain the anomalous increase of α with I0 measured in some earlier laser-plasma experiments.

  2. Effect of microstructure on anomalous strain-rate-dependent behaviour of bacterial cellulose hydrogel.

    Science.gov (United States)

    Gao, Xing; Shi, Zhijun; Lau, Andrew; Liu, Changqin; Yang, Guang; Silberschmidt, Vadim V

    2016-05-01

    This study is focused on anomalous strain-rate-dependent behaviour of bacterial cellulose (BC) hydrogel that can be strain-rate insensitive, hardening, softening, or strain-rate insensitive in various ranges of strain rate. BC hydrogel consists of randomly distributed nanofibres and a large content of free water; thanks to its ideal biocompatibility, it is suitable for biomedical applications. Motivated by its potential applications in complex loading conditions of body environment, its time-dependent behaviour was studied by means of in-aqua uniaxial tension tests at constant temperature of 37 °C at various strain rates ranging from 0.000 1s(-1) to 0.3s(-1). Experimental results reflect anomalous strain-rate-dependent behaviour that was not documented before. Micro-morphological observations allowed identification of deformation mechanisms at low and high strain rates in relation to microstructural changes. Unlike strain-rate softening behaviours in other materials, reorientation of nanofibres and kinematics of free-water flow dominate the softening behaviour of BC hydrogel at high strain rates. PMID:26952406

  3. Thickness Dependence of the Quantum Anomalous Hall Effect in Magnetic Topological Insulator Films.

    Science.gov (United States)

    Feng, Xiao; Feng, Yang; Wang, Jing; Ou, Yunbo; Hao, Zhenqi; Liu, Chang; Zhang, Zuocheng; Zhang, Liguo; Lin, Chaojing; Liao, Jian; Li, Yongqing; Wang, Li-Li; Ji, Shuai-Hua; Chen, Xi; Ma, Xucun; Zhang, Shou-Cheng; Wang, Yayu; He, Ke; Xue, Qi-Kun

    2016-08-01

    The evolution of the quantum anomalous Hall effect with the thickness of Cr-doped (Bi,Sb)2 Te3 magnetic topological insulator films is studied, revealing how the effect is caused by the interplay of the surface states, band-bending, and ferromagnetic exchange energy. Homogeneity in ferromagnetism is found to be the key to high-temperature quantum anomalous Hall material. PMID:27166762

  4. Dependence of (anomalous) fading of infra-red stimulated luminescence on trap occupancy in feldspars

    DEFF Research Database (Denmark)

    Morthekai, P.; Jain, Mayank; Gach, Grzegorz;

    2013-01-01

    Dose dependency of anomalous fading of infra-red stimulated luminescence (IRSL) from feldspars has been investigated using radiations of different ionisation qualities. The rate of fading of the IRSL signal after proton irradiation (9.4–30%/decade) is on an average almost twice compared...... to that after 90Sr/90Y beta particle irradiation (3.5–15%/decade) for all the measured feldspar mineral specimens. Similarly, the fading rates after x-rays of 50 kV and 10 kV fall in between those of beta particle and proton irradiations. Our results suggest that rate of anomalous fading in feldspars depends...... on the number density of the trapped charge carriers. These results support the hypothesis that anomalous fading occurs across randomly distributed donor-acceptor distances as opposed to pairs with a fixed distance....

  5. Unusual field and temperature dependence of Hall effect in graphene

    OpenAIRE

    Falkovsky, L. A.

    2006-01-01

    We calculate the classic Hall conductivity and mobility of the undoped and doped (or in the gate voltage) graphene as a function of temperature, magnetic field, and carrier concentration. Carrier collisions with defects and acoustic phonons are taken into account. The Hall resistivity varies almost linearly with temperature. The magnetic field dependence of resistivity and mobility is anomalous in weak magnetic fields. There is the square root contribution from the field in the resistivity. T...

  6. Frequency dependence of anomalous transport in field theory and holography⋆,⋆⋆

    Directory of Open Access Journals (Sweden)

    Megías Eugenio

    2014-01-01

    Full Text Available We study the frequency dependence of anomalous transport coefficients for a relativistic gas of free chiral fermions and for a strongly coupled conformal field theory with holographic dual. We perform the computation by using the Kubo formulae for- malism, and compare with a hydrodynamic calculation of two point functions. Some implications for heavy ion physics are discussed.

  7. Room-temperature anomalous Hall effect and magnetroresistance in (Ga, Co)-codoped ZnO diluted magnetic semiconductor films

    Institute of Scientific and Technical Information of China (English)

    Liu Xue-Chao; Chen Zhi-Zhan; Shi Er-Wei; Liao Da-Qian; Zhou Ke-Jin

    2011-01-01

    This paper reports that the (Ga, Co)-codoped ZnO thin films have been grown by inductively coupled plasma enhanced physical vapour deposition. Room-temperature ferromagnetism is observed for the as-grown thin films. The x-ray absorption fine structure characterization reveals that Co2+ and Ga3+ ions substitute for Zn2+ ions in the ZnO lattice and exclude the possibility of extrinsic ferromagnetism origin. The ferromagnetic (Ga, Co)-codoped ZnO thin films exhibit carrier concentration dependent anomalous Hall effect and positive magnetoresistance at room temperature. The mechanism of anomalous Hall effect and magneto-transport in ferromagnetic ZnO-based diluted magnetic semiconductors is discussed.

  8. Tokamak Plasmas : Measurement of temperature fluctuations and anomalous transport in the SINP tokamak

    Indian Academy of Sciences (India)

    R Kumar; S K Saha

    2000-11-01

    Temperature fluctuations have been measured in the edge region of the SINP tokamak. We find that these fluctuations have a comparatively high level (30–40%) and a broad spectrum. The temperature fluctuations show a quite high coherence with density and potential fluctuations and contribute considerably to the anomalous particle flux.

  9. Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature.

    Science.gov (United States)

    Nakatsuji, Satoru; Kiyohara, Naoki; Higo, Tomoya

    2015-11-12

    In ferromagnetic conductors, an electric current may induce a transverse voltage drop in zero applied magnetic field: this anomalous Hall effect is observed to be proportional to magnetization, and thus is not usually seen in antiferromagnets in zero field. Recent developments in theory and experiment have provided a framework for understanding the anomalous Hall effect using Berry-phase concepts, and this perspective has led to predictions that, under certain conditions, a large anomalous Hall effect may appear in spin liquids and antiferromagnets without net spin magnetization. Although such a spontaneous Hall effect has now been observed in a spin liquid state, a zero-field anomalous Hall effect has hitherto not been reported for antiferromagnets. Here we report empirical evidence for a large anomalous Hall effect in an antiferromagnet that has vanishingly small magnetization. In particular, we find that Mn3Sn, an antiferromagnet that has a non-collinear 120-degree spin order, exhibits a large anomalous Hall conductivity of around 20 per ohm per centimetre at room temperature and more than 100 per ohm per centimetre at low temperatures, reaching the same order of magnitude as in ferromagnetic metals. Notably, the chiral antiferromagnetic state has a very weak and soft ferromagnetic moment of about 0.002 Bohr magnetons per Mn atom (refs 10, 12), allowing us to switch the sign of the Hall effect with a small magnetic field of around a few hundred oersted. This soft response of the large anomalous Hall effect could be useful for various applications including spintronics--for example, to develop a memory device that produces almost no perturbing stray fields. PMID:26524519

  10. Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature.

    Science.gov (United States)

    Nakatsuji, Satoru; Kiyohara, Naoki; Higo, Tomoya

    2015-11-12

    In ferromagnetic conductors, an electric current may induce a transverse voltage drop in zero applied magnetic field: this anomalous Hall effect is observed to be proportional to magnetization, and thus is not usually seen in antiferromagnets in zero field. Recent developments in theory and experiment have provided a framework for understanding the anomalous Hall effect using Berry-phase concepts, and this perspective has led to predictions that, under certain conditions, a large anomalous Hall effect may appear in spin liquids and antiferromagnets without net spin magnetization. Although such a spontaneous Hall effect has now been observed in a spin liquid state, a zero-field anomalous Hall effect has hitherto not been reported for antiferromagnets. Here we report empirical evidence for a large anomalous Hall effect in an antiferromagnet that has vanishingly small magnetization. In particular, we find that Mn3Sn, an antiferromagnet that has a non-collinear 120-degree spin order, exhibits a large anomalous Hall conductivity of around 20 per ohm per centimetre at room temperature and more than 100 per ohm per centimetre at low temperatures, reaching the same order of magnitude as in ferromagnetic metals. Notably, the chiral antiferromagnetic state has a very weak and soft ferromagnetic moment of about 0.002 Bohr magnetons per Mn atom (refs 10, 12), allowing us to switch the sign of the Hall effect with a small magnetic field of around a few hundred oersted. This soft response of the large anomalous Hall effect could be useful for various applications including spintronics--for example, to develop a memory device that produces almost no perturbing stray fields.

  11. Temperature, pressure, and compositional effects on anomalous or "self" preservation of gas hydrates

    Science.gov (United States)

    Stern, L.A.; Circone, S.; Kirby, S.H.; Durham, W.B.

    2003-01-01

    We previously reported on a thermal regime where pure, polycrystalline methane hydrate is preserved metastably in bulk at up to 75 K above its nominal temperature stability limit of 193 K at 0.1 MPa, following rapid release of the sample pore pressure. Large fractions (>50 vol.%) of methane hydrate can be preserved for 2-3 weeks by this method, reflecting the greatly suppressed rates of dissociation that characterize this "anomalous preservation" regime. This behavior contrasts that exhibited by methane hydrate at both colder (193-240 K) and warmer (272-290 K) isothermal test conditions, where dissociation rates increase monotonically with increasing temperature. Here, we report on recent experiments that further investigate the effects of temperature, pressure, and composition on anomalous preservation behavior. All tests conducted on sI methane hydrate yielded self-consistent results that confirm the highly temperature-sensitive but reproducible nature of anomalous preservation behavior. Temperature-stepping experiments conducted between 250 and 268 K corroborate the relative rates measured previously in isothermal preservation tests, and elevated pore-pressure tests showed that, as expected, dissociation rates are further reduced with increasing pressure. Surprisingly, sII methane-ethane hydrate was found to exhibit no comparable preservation effect when rapidly depressurized at 268 K, even though it is thermodynamically stable at higher temperatures and lower pressures than sI methane hydrate. These results, coupled with SEM imaging of quenched sample material from a variety of dissociation tests, strongly support our earlier arguments that ice-"shielding" effects provided by partial dissociation along hydrate grain surfaces do not serve as the primary mechanism for anomalous preservation. The underlying physical-chemistry mechanism(s) of anomalous preservation remains elusive, but appears to be based more on textural or morphological changes within the hydrate

  12. Anomalous fiber optic gyroscope signals observed above spinning rings at low temperature

    Energy Technology Data Exchange (ETDEWEB)

    Tajmar, M; Plesescu, F; Seifert, B [Space Propulsion and Advanced Concepts, Austrian Research Centers GmbH - ARC, A-2444 Seibersdorf (Austria)], E-mail: martin.tajmar@arcs.ac.at

    2009-02-01

    Precision fiber optic gyroscopes were mounted mechanically de-coupled above spinning rings inside a cryostat. Below a critical temperature (typically <30 K), the gyroscopes measure a significant deviation from their usual offset due to Earth's rotation. This deviation is proportional to the applied angular ring velocity with maximum signals towards lower temperatures. The anomalous gyroscope signal is about 8 orders of magnitude smaller then the applied angular ring velocity, compensating about one third of the Earth rotation offset at an angular top speed of 420 rad/s. Moreover, our data shows a parity violation as the effect appears to be dominant for rotation against the Earth's spin. No systematic effect was found to explain this effect including the magnetic environment, vibration and helium gas friction suggesting that our observation is a new low temperature phenomenon. Tests in various configurations suggest that the rotating low temperature helium may be the source of our anomalous signals.

  13. Anomalous law of cooling

    Science.gov (United States)

    Lapas, Luciano C.; Ferreira, Rogelma M. S.; Rubí, J. Miguel; Oliveira, Fernando A.

    2015-03-01

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton's law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics.

  14. Anomalous law of cooling

    International Nuclear Information System (INIS)

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton’s law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics

  15. Anomalous law of cooling

    Energy Technology Data Exchange (ETDEWEB)

    Lapas, Luciano C., E-mail: luciano.lapas@unila.edu.br [Universidade Federal da Integração Latino-Americana, Caixa Postal 2067, 85867-970 Foz do Iguaçu, Paraná (Brazil); Ferreira, Rogelma M. S., E-mail: rogelma.maria@gmail.com [Centro de Ciências Exatas e Tecnológicas, Universidade Federal do Recôncavo da Bahia, 44380-000 Cruz das Almas, Bahia (Brazil); Rubí, J. Miguel, E-mail: mrubi@ub.edu [Departament de Física Fonamental, Facultat de Física, Universitat de Barcelona, Av. Diagonal 647, 08028 Barcelona (Spain); Oliveira, Fernando A., E-mail: fernando.oliveira@pq.cnpq.br [Instituto de Física and Centro Internacional de Física da Matéria Condensada, Universidade de Brasília, Caixa Postal 04513, 70919-970 Brasília, Distrito Federal (Brazil)

    2015-03-14

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton’s law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics.

  16. Relaxation and anomalous T- and H-dependence of the μ coefficient in (K,Ba)BiO3 superconductors

    International Nuclear Information System (INIS)

    Ac shielding and classical DC relaxation experiments have been used to study the flux creep phenomena in the cubic (K,Ba)BiO3 superconductor (Tc ∝ 30 K). The relaxation rate is found to be constant (S ∝ 1.5%) at low temperature and magnetic field and increases sharply as the vortex-glass transition line is approached. This behavior can be attributed to an anomalous decrease of the μ exponent (U(J) = U0(J0/J)μ) close to Tg(H). In this regime, the temperature dependence of the apparent critical current J is then directly related to μ(T) as J(T) = J0/[kT/U0.ln(1/ωτ)] μ(T). A similar analysis can be made on the J(B) data recently published by Abulafia et al. (1996) on YBaCuO single crystals. (orig.)

  17. Anomalous Fano resonance of massive Dirac particle through a time-dependent barrier

    Science.gov (United States)

    Zhang, Cunxi; Liu, Jie; Fu, Libin

    2015-06-01

    As is well known Fano resonance arises from the interference between a localized state and a continuum state. Using the standard Floquet theory and the scattering matrix method, we study theoretically the massive Dirac particle transmission over a quantum barrier with an oscillating field. It is found that the massive relativistic particles can generate not only normal Fano resonance in the transmission due to the interference between a localized state (bound state) and the continuum state, but also anomalous Fano resonance due to the interference between a delocalized state (extended state) and the continuum state. The dependence of line shapes on driving parameters for these two kinds of Fano resonances is quite different. For normal Fano resonance the asymmetry parameter is approximately proportional to a power law of the amplitude of the oscillating field, while for the anomalous Fano resonance the asymmetry parameters change slightly with different oscillation amplitudes. In practice, the anomalous Fano resonance can be identified by observing asymmetry parameters in experiment.

  18. Temperature dependence of basalt weathering

    Science.gov (United States)

    Li, Gaojun; Hartmann, Jens; Derry, Louis A.; West, A. Joshua; You, Chen-Feng; Long, Xiaoyong; Zhan, Tao; Li, Laifeng; Li, Gen; Qiu, Wenhong; Li, Tao; Liu, Lianwen; Chen, Yang; Ji, Junfeng; Zhao, Liang; Chen, Jun

    2016-06-01

    The homeostatic balance of Earth's long-term carbon cycle and the equable state of Earth's climate are maintained by negative feedbacks between the levels of atmospheric CO2 and the chemical weathering rate of silicate rocks. Though clearly demonstrated by well-controlled laboratory dissolution experiments, the temperature dependence of silicate weathering rates, hypothesized to play a central role in these weathering feedbacks, has been difficult to quantify clearly in natural settings at landscape scale. By compiling data from basaltic catchments worldwide and considering only inactive volcanic fields (IVFs), here we show that the rate of CO2 consumption associated with the weathering of basaltic rocks is strongly correlated with mean annual temperature (MAT) as predicted by chemical kinetics. Relations between temperature and CO2 consumption rate for active volcanic fields (AVFs) are complicated by other factors such as eruption age, hydrothermal activity, and hydrological complexities. On the basis of this updated data compilation we are not able to distinguish whether or not there is a significant runoff control on basalt weathering rates. Nonetheless, the simple temperature control as observed in this global dataset implies that basalt weathering could be an effective mechanism for Earth to modulate long-term carbon cycle perturbations.

  19. Anomalous transport in high-temperature plasmas with applications to solenoidal fusion systems

    International Nuclear Information System (INIS)

    The linear, non-linear, and anomalous transport properties associated with various micro-instabilities driven by cross-field currents in high-temperature plasmas are reviewed. Particular emphasis is placed on instabilities pertinent to the implosion and post-implosion phases of theta-pinch plasmas, e.g. Buneman (electron-ion two-stream), ion acoustic, lower-hybrid-drift, electromagnetic ion cyclotron, and ion-ion cross-field instabilities. Analytic studies of the non-linear and quasi-linear evolution of these instabilities are presented, together with a detailed comparison with computer simulation experiments to test the validity of the various theoretical models and non-linear saturation mechanisms. A general theoretical formalism is presented which describes, in a self-consistent manner, the macroscopic transport produced by the (short-wave-length) turbulence associated with the microinstabilities enumerated above. The experimental evidence that such a self-consistent anomalous transport model is required for describing the implosion behaviour (characterized by diffuse current sheaths) in rapidly pulsed theta pinches is reviewed, together with the early attempts at modelling these implosions numerically with a one-fluid (MHD) model including artificial viscosity. It is shown that fluid-numerical simulations that include (at each space and time step) the effects of anomalous transport in a fully self-consistent manner, explain several features of the experimental observations. The relevance of reflected ions to sheath structure and implosion dynamics is also discussed, and state-of-the-art hybrid-numerical studies (Vlasov ions and fluid electrons) of pinch implosions are presented, which include reflected ion dynamics as well as the anomalous transport associated with cross-field instabilities. Finally, instability mechanisms for producing long-time interpenetration of plasma and magnetic field in post-implosion theta pinches are discussed, together with estimates

  20. Anomalous law of cooling

    OpenAIRE

    Lapas, Luciano C.; Ferreira, Rogelma M. S.; Oliveira, Fernando A.; Rubí, J. Miguel

    2014-01-01

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergo a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton's law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature ma...

  1. Anomalous dependence of population growth on the birth rate in the plant-herbivore system

    Energy Technology Data Exchange (ETDEWEB)

    Cui, Xue M. [Chungbuk National University, Cheongju (Korea, Republic of); Yanbian University, Yanji (China); Han, Seung K.; Chung, Jean S. [Chungbuk National University, Cheongju (Korea, Republic of)

    2010-12-15

    We performed a simulation of the two-species plant-herbivore system by using the agent-based NetLogo program and constructed a dynamic model of populations consistent with the simulation results. The dynamic model is a three-dimensional system including the mean energy of the herbivore in addition to two variables denoting the populations of plants and herbivores. A steady-state analysis of the dynamic model shows that the dependence of the herbivore population on the birth and the death rates observed from the agent model is consistent with the prediction of the dynamic model. Especially, the anomalous dependence of the herbivore population on the birth rate, where the population decreases with the birth rate for small death rate, is consistently explained by a phase plane analysis of the dynamic model.

  2. Water ingress in Y-type zeolite: anomalous moisture-dependent transport diffusivity.

    Science.gov (United States)

    de Azevedo, Eduardo N; da Silva, D Vitoreti; de Souza, R E; Engelsberg, M

    2006-10-01

    Nuclear magnetic resonance imaging measurements of liquid water ingress in a large number of nonactivated Y-type (Na) zeolite samples prepared under different conditions are reported on. Using an experimental arrangement that permits the application of Boltzmann's transformation of the 1D (one-dimensional) diffusion equation, the spatiotemporal scaling variables required for a collapse of the measured profiles into universal curves revealed subdiffusive behavior in all cases. It is shown that the one-dimensional fractal time diffusion equation constitutes a powerful tool to analyze the data and provides a connection between the moisture dependence of the effective transport diffusivities and the shapes of the universal curves. Thus, even for anomalous diffusion, the relationship between the universal curves and structural characteristics of the system; such as porosity, tortuosity of the pore space and, in some cases, the interplay between mesopores and nanopores can be addressed. PMID:17155023

  3. A Two-Temperature Supernova Fallback Disk Model for Anomalous X-ray Pulsars

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    We present a case study of the relevance of the radially pulsational instability of a two-temperature accretion disk around a neutron star to anomalous X-ray pulsars (AXPs). Our estimates are based on the approximation that such a neutron star disk with mass in the range of 10-6 - 10-5 M⊙ is formed by supernova fallback. We derive several peculiar properties of the accretion disk instability: a narrow interval of X-ray pulse periods; lower X-ray luminosities; a period derivative and an evolution time scale. All these results are in good agreement with the observations of the AXPs.

  4. Anomalous excitation-power-dependent photoluminescence of InGaAsN/GaAs T-shaped quantum wire

    Energy Technology Data Exchange (ETDEWEB)

    Klangtakai, Pawinee; Pimanpang, Samuk [Faculty of Science, Department of Physics, Khon Kaen University, 123 Mittraphap Rd., Muang, Khon Kaen, 40002 (Thailand); Nanotec-KKU Center of Excellence on Advanced Nanomaterials for Energy Production and Storage, Khon Kaen, 40002 (Thailand); Integrated Nanotechnology Research Center, Khon Kaen University, Khon Kaen, 40002 (Thailand); Sanorpim, Sakuntam [Faculty of Science, Department of Physics, Chulalongkorn University, Phayathai Rd., Patumwan, Bangkok, 10330 (Thailand); Karlsson, Fredrik; Holtz, Per Olof [Department of Physics, Chemistry, and Biology (IFM), Linkoeping University, 58183, Linkoeping (Sweden); Onabe, Kentaro [Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561 (Japan)

    2014-08-15

    The selected InGaAsN/GaAs T-shaped quantum wire (T-QWR) fabricated by metal organic vapor phase epitaxy has been investigated by microphotoluminescence (μ-PL) and excitation-power-dependent μ-PL. The optical characteristics of one-dimensional structure were taken at low-temperature (4 K) and room temperature (RT) to clarify the intersection of two familiar quantum wells (QWs) in the [001] and [110] directions, named QW1 and QW2, respectively. For the excitation-power-dependent measurement, the intensity of the excitation source was used in the range of 0.001I{sub 0} to I{sub 0}. The result shows that all of emissions related to QW1 and QWR peaks have a nonsymmetric line shape as evidenced by the tailing on the lower-energy side. All peaks shift to higher-energy side (blueshift) with the increase of the excitation power intensity. The blueshift and the low-energy tailing of PL peaks are attributed to the alloying effect. However, the emission peak related to QWR region shows a larger blueshift rate than that of QW1 on increasing of the excitation power intensity. This is an anomalous characteristic for the low-dimensional structure, affected by the large fluctuation state in the QWR region. This fluctuation state is combined of both edges of QWs (QW1 and QW2). (copyright 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Anomalous roughness of turbulent interfaces with system size dependent local roughness exponent

    Energy Technology Data Exchange (ETDEWEB)

    Balankin, Alexander S. [SEPI, ESIME, Instituto Politecnico Nacional, Mexico D.F. 07738 (Mexico) and Grupo ' Mecanica Fractal' (Mexico) and Instituto Mexicano de Petroleo, Mexico D.F. 07730 (Mexico)]. E-mail: abalankin@ipn.mx; Matamoros, Daniel Morales [Grupo ' Mecanica Fractal' (Mexico); Instituto Mexicano de Petroleo, Mexico D.F. 07730 (Mexico)

    2005-05-16

    In a system far from equilibrium the system size can play the role of control parameter that governs the spatiotemporal dynamics of the system. Accordingly, the kinetic roughness of interfaces in systems far from equilibrium may depend on the system size. To get an insight into this problem, we performed a detailed study of rough interfaces formed in paper combustion experiments. Using paper sheets of different width {lambda}, we found that the turbulent flame fronts display anomalous multi-scaling characterized by non-universal global roughness exponent {alpha} and by the system size dependent spectrum of local roughness exponents, {zeta}{sub q}({lambda})={zeta}{sub 1}(1)q{sup -{omega}}{lambda}{sup {phi}}<{alpha}, whereas the burning fronts possess conventional multi-affine scaling characterized by the universal spectrum of roughness exponent {zeta}{sub q}=0.93q{sup -0.15}. The structure factor of turbulent flame fronts also exhibits unconventional scaling dependence on {lambda}. These results are expected to apply to a broad range of far from equilibrium systems when the kinetic energy fluctuations exceed a certain critical value.

  6. Temperature Dependence of Elastic Properties for Amorphous SiO2 by Molecular Dynamics Simulation

    Institute of Scientific and Technical Information of China (English)

    LIU Bin; WANG Jing-Yang; ZHOU Yan-Chun; LI Fang-Zhi

    2008-01-01

    @@ Large-scale and long-time molecular-dynamics simulations are used to investigate the temperature dependences of elastic properties for amorphous SiO2. The elastic moduli increase in a temperature range up to 1600 K and decrease thereafter. The anomalous behaviour in elasticity is explained by analysing the changes of atomic-scale structure with respect to increment of temperature. The mechanism originates predominantly from distortion of the SiO4 tetrahedra network in low-temperature ranges. At an elevated temperature range, thermal-induced Si-O bond stretching dominates the process and leads to normal temperature dependence of elastic properties.

  7. Temperature dependence of electroluminescence from silicon p-i-n light-emitting diodes

    OpenAIRE

    Li, Cheng; Lai, Hongkai; Chen, Songyan; Suemasu, T.; Hasegawa, F

    2006-01-01

    The temperature dependence of electroluminescence from silicon p-i-n light-emitting diodes with a layer of beta-FeSi2 particles inserted in intrinsic silicon was investigated. Anomalous blueshift of the peak energy and enhanced electroluminescence intensity of the silicon band-edge emission were observed at temperatures from 50 to 200 K. The electroluminescence intensity was enhanced due to longer diffusion paths of the injected electrons at elevated temperature, as well as thermal escape ...

  8. Dependence of anomalous resistivity on bulk drift velocity of electrons in the reconnecting current sheets in solar flares

    Institute of Scientific and Technical Information of China (English)

    Gui-Ping Wu; Guang-Li Huang; Hai-Sheng Ji

    2010-01-01

    Anomalous resistivity is critical for triggering fast magnetic reconnection in the nearly collisionless coronal plasma.Its nonlinear dependence on bulk drift velocity is usually assumed in MHD simulations.However,the mechanism for the production of anomalous resistivity and its evolution is still an open question.We numerically solved the one dimension Vlasov equation with the typical solar coronal parameters and realistic mass ratios to infer the relationship between anomalous resistivity and bulk drift velocity of electrons in the reconnecting current sheets as well as its nonlinear characteristics.Our principal findings are summarized as follows: 1)the relationship between the anomalous resistivity and bulk drift velocity of electrons relative to ions may be described as ηmax = 0.03724(vd/ve)5.702 Ω m for vd/ve in the range of 1.4-2.0 and ηmax = 0.8746(vd/ve)1.284 Ωm for vd/ve in the range of 2.5-4.5; 2)if drift velocity is just slightly larger than the threshold of ion-acoustic instability,the anomalous resistivity due to the wave-particle interactions is enhanced by about five orders as compared with classic resistivity due to Coulomb collisions.With the increase of drift velocity from 1.4ve to 4.5ve,the anomalous resistivity continues to increase 100 times; 3)in the rise phase of unstable waves,the anomalous resistivity has the same order as the one estimated from quasi-linear theory; after saturation of unstable waves,the anomalous resistivity decreases at least about one order as compared with its peak value; 4)considering that the final velocity of electrons ejected out of the reconnecting current sheet(RCS)decreases with the distance from the neutral point in the neutral plane,the anomalous resistivity decreases with the distance from the neutral point,which is favorable for the Petschek-like reconnection to take place.

  9. Anomalous capacitance in temperature and frequency characteristics of a TiW/p-InP Schottky barrier diode

    Science.gov (United States)

    Wang, Qingsong; Chen, Jun; Tang, Hengjing; Li, Xue

    2016-06-01

    The capacitance-voltage (C–V) and conductance voltage (G/ω–V) characteristics of a TiW/p-InP Schottky barrier diode (SBD) are measured at 310 K in the frequency range from 10 kHz to 1 MHz and the temperature dependency of the diode from 310 K to 400 K at 1 MHz are also investigated. Anomalous peaks and negative capacitances caused by interface states (N ss ) and series resistance (R s) are discussed, which strongly influence the electrical characteristics of SBD. R s is calculated from the measured capacitance (C m ) and conductance (G m ) values, indicating that the effects of R s are apparent at low frequency. The corrected capacitance (C c) and corrected conductance (G c) are both obtained from the C m and G m values by taking into account R s. The experimental results clearly show that the capacitance (C) and conductance (G) values are strongly dependent on the temperature and frequency.

  10. Layer-dependent quantum cooperation of electron and hole states in the anomalous semimetal WTe2.

    Science.gov (United States)

    Das, Pranab Kumar; Di Sante, D; Vobornik, I; Fujii, J; Okuda, T; Bruyer, E; Gyenis, A; Feldman, B E; Tao, J; Ciancio, R; Rossi, G; Ali, M N; Picozzi, S; Yadzani, A; Panaccione, G; Cava, R J

    2016-01-01

    The behaviour of electrons and holes in a crystal lattice is a fundamental quantum phenomenon, accounting for a rich variety of material properties. Boosted by the remarkable electronic and physical properties of two-dimensional materials such as graphene and topological insulators, transition metal dichalcogenides have recently received renewed attention. In this context, the anomalous bulk properties of semimetallic WTe2 have attracted considerable interest. Here we report angle- and spin-resolved photoemission spectroscopy of WTe2 single crystals, through which we disentangle the role of W and Te atoms in the formation of the band structure and identify the interplay of charge, spin and orbital degrees of freedom. Supported by first-principles calculations and high-resolution surface topography, we reveal the existence of a layer-dependent behaviour. The balance of electron and hole states is found only when considering at least three Te-W-Te layers, showing that the behaviour of WTe2 is not strictly two dimensional. PMID:26924386

  11. Stacking order dependence of inverse spin Hall effect and anomalous Hall effect in spin pumping experiments

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang-Il; Seo, Min-Su; Park, Seung-Young, E-mail: parksy@kbsi.re.kr [Division of Materials Science, Korea Basic Science Institute, Daejeon 305-806 (Korea, Republic of); Kim, Dong-Jun; Park, Byong-Guk [Department of Materials Science and Engineering, KAIST, Daejeon 305-701 (Korea, Republic of)

    2015-05-07

    The dependence of the measured DC voltage on the non-magnetic material (NM) in NM/CoFeB and CoFeB/NM bilayers is studied under ferromagnetic resonance conditions in a TE{sub 011} resonant cavity. The directional change of the inverse spin Hall effect (ISHE) voltage V{sub ISHE} for the stacking order of the bilayer can separate the pure V{sub ISHE} and the anomalous Hall effect (AHE) voltage V{sub AHE} utilizing the method of addition and subtraction. The Ta and Ti NMs show a broad deviation of the spin Hall angle θ{sub ISH}, which originates from the AHE in accordance with the high resistivity of NMs. However, the Pt and Pd NMs show that the kinds of NMs with low resistivity are consistent with the previously reported θ{sub ISH} values. Therefore, the characteristics that NM should simultaneously satisfy to obtain a reasonable V{sub ISHE} value in bilayer systems are large θ{sub ISH} and low resistivity.

  12. Anomalous length dependence of the conductance of graphene nanoribbons with zigzag edges

    KAUST Repository

    Bilić, Ante

    2013-01-01

    Charge transport through two sets of symmetric graphene nanoribbons with zigzag shaped edges in a two-terminal device has been investigated, using density functional theory combined with the non-equilibrium Green\\'s function method. The conductance has been explored as a function of nanoribbon length, bias voltage, and the strength of terminal coupling. The set of narrower nanoribbons, in the form of thiolated linear acenes, shows an anomalous length dependence of the conductance, which at first exhibits a drop and a minimum, followed by an evident rise. The length trend is shown to arise because of a gradual transformation in the transport mechanism, which changes from being governed by a continuum of out-of-plane π type and in-plane state channels to being fully controlled by a single, increasingly more resonant, occupied π state channel. For the set of nanoribbons with a wider profile, a steady increase is observed across the whole length range, owing to the absence of the former transport mechanism. The predicted trends are confirmed by the inclusion of self-interaction correction in the calculations. For both sets of nanoribbons the replacement of the strongly coupling thiol groups by weakly bonding phenathroline has been found to cause a strong attenuation with the length and a generally low conductance. © 2013 American Institute of Physics.

  13. Layer-dependent quantum cooperation of electron and hole states in the anomalous semimetal WTe2

    Science.gov (United States)

    Das, Pranab Kumar; di Sante, D.; Vobornik, I.; Fujii, J.; Okuda, T.; Bruyer, E.; Gyenis, A.; Feldman, B. E.; Tao, J.; Ciancio, R.; Rossi, G.; Ali, M. N.; Picozzi, S.; Yadzani, A.; Panaccione, G.; Cava, R. J.

    2016-02-01

    The behaviour of electrons and holes in a crystal lattice is a fundamental quantum phenomenon, accounting for a rich variety of material properties. Boosted by the remarkable electronic and physical properties of two-dimensional materials such as graphene and topological insulators, transition metal dichalcogenides have recently received renewed attention. In this context, the anomalous bulk properties of semimetallic WTe2 have attracted considerable interest. Here we report angle- and spin-resolved photoemission spectroscopy of WTe2 single crystals, through which we disentangle the role of W and Te atoms in the formation of the band structure and identify the interplay of charge, spin and orbital degrees of freedom. Supported by first-principles calculations and high-resolution surface topography, we reveal the existence of a layer-dependent behaviour. The balance of electron and hole states is found only when considering at least three Te-W-Te layers, showing that the behaviour of WTe2 is not strictly two dimensional.

  14. Anomalous thermal behaviour in small electronic devices: non-uniformity and overshoot in dynamic temperature distributions

    Energy Technology Data Exchange (ETDEWEB)

    Vermeersch, B; Mey, G de [Department of Electronics and Information Systems, Ghent University, Sint Pietersnieuwstraat 41, Gent 9000 (Belgium)

    2007-04-21

    This paper presents a theoretical investigation of the temperature distributions generated by a small heat source mounted on or embedded in semiconductor material. The dynamic thermal behaviour of the structures is studied in the frequency domain using phasor notation for the temperature and heat flux fields. Both classical and hyperbolic thermal conductions are considered. The latter accounts for the finite heat propagation speed, which is necessary for accurately describing very fast transitions. Although a uniform power density is applied, the temperature distribution inside the source is spatially non-uniform. As is already well known, this even holds for steady state conditions. For high frequencies, however, the maximum magnitude (i.e. largest oscillations) of the temperature occurs near the edges and corners of the heat source, rather than in the centre where it could intuitively be expected. This anomalous behaviour is observed for a wide variety of configurations, ranging from a simple 1D analytical slab model to numerical results for a 3D multi-layered electronic package. The classical theory clearly underestimates the edge effect, particularly for submicrometre structures. The substantial deviation from the distributions obtained by non-Fourier theory illustrates that special care should be taken when analysing fast heat transfer in small electronic devices.

  15. Magnetic modulation doping in topological insulators toward higher-temperature quantum anomalous Hall effect

    Energy Technology Data Exchange (ETDEWEB)

    Mogi, M., E-mail: mogi@cmr.t.u-tokyo.ac.jp; Yoshimi, R.; Yasuda, K.; Kozuka, Y. [Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Tokyo 113-8656 (Japan); Tsukazaki, A. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); PRESTO, Japan Science and Technology Agency (JST), Chiyoda-ku, Tokyo 102-0075 (Japan); Takahashi, K. S. [RIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198 (Japan); Kawasaki, M.; Tokura, Y. [Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Tokyo 113-8656 (Japan); RIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198 (Japan)

    2015-11-02

    Quantum anomalous Hall effect (QAHE), which generates dissipation-less edge current without external magnetic field, is observed in magnetic-ion doped topological insulators (TIs) such as Cr- and V-doped (Bi,Sb){sub 2}Te{sub 3}. The QAHE emerges when the Fermi level is inside the magnetically induced gap around the original Dirac point of the TI surface state. Although the size of gap is reported to be about 50 meV, the observable temperature of QAHE has been limited below 300 mK. We attempt magnetic-Cr modulation doping into topological insulator (Bi,Sb){sub 2}Te{sub 3} films to increase the observable temperature of QAHE. By introducing the rich-Cr-doped thin (1 nm) layers at the vicinity of both the surfaces based on non-Cr-doped (Bi,Sb){sub 2}Te{sub 3} films, we have succeeded in observing the QAHE up to 2 K. The improvement in the observable temperature achieved by this modulation-doping appears to be originating from the suppression of the disorder in the surface state interacting with the rich magnetic moments. Such a superlattice designing of the stabilized QAHE may pave a way to dissipation-less electronics based on the higher-temperature and zero magnetic-field quantum conduction.

  16. High-Temperature Quantum Anomalous Hall Effect in n -p Codoped Topological Insulators

    Science.gov (United States)

    Qi, Shifei; Qiao, Zhenhua; Deng, Xinzhou; Cubuk, Ekin D.; Chen, Hua; Zhu, Wenguang; Kaxiras, Efthimios; Zhang, S. B.; Xu, Xiaohong; Zhang, Zhenyu

    2016-07-01

    The quantum anomalous Hall effect (QAHE) is a fundamental quantum transport phenomenon that manifests as a quantized transverse conductance in response to a longitudinally applied electric field in the absence of an external magnetic field, and it promises to have immense application potential in future dissipationless quantum electronics. Here, we present a novel kinetic pathway to realize the QAHE at high temperatures by n -p codoping of three-dimensional topological insulators. We provide a proof-of-principle numerical demonstration of this approach using vanadium-iodine (V-I) codoped Sb2 Te3 and demonstrate that, strikingly, even at low concentrations of ˜2 % V and ˜1 % I, the system exhibits a quantized Hall conductance, the telltale hallmark of QAHE, at temperatures of at least ˜50 K , which is 3 orders of magnitude higher than the typical temperatures at which it has been realized to date. The underlying physical factor enabling this dramatic improvement is tied to the largely preserved intrinsic band gap of the host system upon compensated n -p codoping. The proposed approach is conceptually general and may shed new light in experimental realization of high-temperature QAHE.

  17. Temperature dependence of radiation chemistry of polymers

    International Nuclear Information System (INIS)

    Chemical reactions which occur during radiolysis of polymers usually show an increase in rate with increasing temperature that can be described by an Arrhenius relationship. The magnitude of the activation energy can vary widely and is affected by physical, as well as chemical, factors. Different reaction rates may be expected in crystalline and amorphous morphologies, and in glassy and rubbery regions. The temperature dependence of radiolysis reactions can be expected to show discontinuities at the glass and melting transitions, Tg and Tm. The ceiling temperature, Tc, for polymerization/depolymerization will also affect the rate of degradation, especially for depropagation to monomer. The temperature for this effect depends on the molecular structure of the polymer. The temperature dependence of free radical reactions can be studied by cryogenic trapping and ESR spectroscopy during thermal profiling. Increased degradation rates at high dose rates can be due to increased temperatures resulting from energy absorption

  18. Charge-dependent correlations from event-by-event anomalous hydrodynamics

    CERN Document Server

    Hirono, Yuji; Kharzeev, Dmitri E

    2016-01-01

    We report on our recent attempt of quantitative modeling of the Chiral Magnetic Effect (CME) in heavy-ion collisions. We perform 3+1 dimensional anomalous hydrodynamic simulations on an event-by-event basis, with constitutive equations that contain the anomaly-induced effects. We also develop a model of the initial condition for the axial charge density that captures the statistical nature of random chirality imbalances created by the color flux tubes. Basing on the event-by-event hydrodynamic simulations for hundreds of thousands of collisions, we calculate the correlation functions that are measured in experiments, and discuss how the anomalous transport affects these observables.

  19. Anomalous Molecular Weight Dependence of Chain Dynamics in Unentangled Polymer Blends with Strong Dynamic Asymmetry

    OpenAIRE

    Arrese-Igor, Silvia; Alegría, Ángel; Moreno Segurado, Ángel J.; Colmenero de León, Juan

    2011-01-01

    We address the general question of how the molecular weight dependence of chain dynamics in unentangled polymers is modified by blending. By dielectric spectroscopy we measure the normal mode relaxation of polyisoprene in blends with a slower component of poly(ter-butylstyrene). Unentangled polyisoprene in the blend exhibits strong deviations from Rouse scaling, approaching 'entangled-like' behavior at low temperatures in concomitance with the increase of the dynamic asymmetry in the blend. T...

  20. Escherichia coli survival in waters: Temperature dependence

    Science.gov (United States)

    Knowing the survival rates of water-borne Escherichia coli is important in evaluating microbial contamination and making appropriate management decisions. E. coli survival rates are dependent on temperature, a dependency that is routinely expressed using an analogue of the Q10 mo...

  1. Stability and anomalous compressibility of Bose gases near resonance: The scale-dependent interactions and thermal effects

    Science.gov (United States)

    Jiang, Shao-Jian; Zhou, Fei

    2015-07-01

    The stability of Bose gases near resonance has been a puzzling problem in recent years. In this article, we demonstrate that in addition to generating thermal pressure, thermal atoms enhance the repulsiveness of the scale-dependent interactions between condensed atoms due to a renormalization effect and further stabilize the Bose gases. Consequently, we find that, as a precursor of instability, the compressibility develops an anomalous structure as a function of scattering length and is drastically reduced compared with the mean-field value. Furthermore, the density profile of a Bose gas in a harmonic trap is found to develop a flat top near the center. This is due to the anomalous behavior of compressibility and can be a potential smoking gun for probing such an effect.

  2. Anomalous results observed in magnetization of bulk high temperature superconductors—A windfall for applications

    Science.gov (United States)

    Weinstein, Roy; Parks, Drew; Sawh, Ravi-Persad; Carpenter, Keith; Davey, Kent

    2016-04-01

    Recent experiments on pulsed-zero field cool magnetization of bulk high Jc YBCO (YBa2Cu3O7-δ) have shown unexpected results. For example, reproducible, non-destructive, rapid, giant field leaps (GFLs) to higher penetrated field are observed. The observations are inconsistent with the critical state model (CSM), in several aspects. Additional experiments have been pursued in an attempt to clarify the physics involved in the observed anomalies. Here, we present experimental results for the Jc dependence of the anomalous features. It is found that the sudden field increase in the GFL is a monotonically increasing function of Jc. The ratio of required pulsed field amplitude, BA,max, to obtain maximum trappable field, BT,max, which CSM predicts to be ≥2.0, gradually approaches 1.0 at high Jc. Tests using values of pulsed, applied field BA,max just below the GFL exhibit two additional anomalies: (i) At high Jc, the highest trapped field is up to ˜6 times lower than predicted by CSM, and (ii) the measured Lorentz force as a function of Jc deviates sharply from CSM predictions. The data rule out heating effects and pinning center geometry as possible physical causes of these anomalies. A speculative cause is considered.

  3. Layer-dependent quantum cooperation of electron and hole states in the anomalous semimetal WTe2

    OpenAIRE

    Das, P. K.; Di Sante, D.; Vobornik, I.; Fujii, J.; Okuda, T; Bruyer, E.; Gyenis, A.; Feldman, B; Tao, J.; Ciancio, R.; Rossi, G.; Ali, M.(National Centre for Particle Physics, Universiti Malaya, Kuala Lumpur, Malaysia); Picozzi, S.; Yazdani, A.; G. Panaccione

    2016-01-01

    The behaviour of electrons and holes in a crystal lattice is a fundamental quantum phenomenon, accounting for a rich variety of material properties. Boosted by the remarkable electronic and physical properties of two-dimensional materials such as graphene and topological insulators, transition metal dichalcogenides have recently received renewed attention. In this context, the anomalous bulk properties of semimetallic WTe2 have attracted considerable interest. Here we report angle- and spin-r...

  4. Temperature dependent quasiparticle renormalization in nickel metal

    Energy Technology Data Exchange (ETDEWEB)

    Ovsyannikov, Ruslan; Sanchez-Barriga, Jaime; Fink, Joerg; Duerr, Hermann A. [Helmholtz Zentrum Berlin (Germany). BESSY II

    2009-07-01

    One of the fundamental consequences of electron correlation effects is that the bare particles in solids become 'dressed', i.e. they acquire an increased effective mass and a lifetime. We studied the spin dependent quasiparticle band structure of Ni(111) with high resolution angle resolved photoemission spectroscopy. At low temperatures (50 K) a renormalization of quasiparticle energy and lifetime indicative of electron-phonon coupling is observed in agreement with literature. With increasing temperature we observe a decreasing quasiparticle lifetime at the Fermi level for all probed minority spin bands as expected from electron phonon coupling. Surprisingly the majority spin states behave differently. We actually observe a slightly increased lifetime at room temperature. The corresponding increase in Fermi velocity points to a temperature dependent reduction of the majority spin quasiparticle renormalization.

  5. Dependence of electromagnetically induced transparency on temperature

    Institute of Scientific and Technical Information of China (English)

    Xiao Feng; Guo Rui-Min; Li Lu-Ming; Yang Dong-Hai; Chen Xu-Zong

    2004-01-01

    @@ We performed an experimental study on the dependence of the linewidth of electromagetically induced transparency (EIT) on the temperature of medium in a A-type configuration using caesium vapour. We found that the transparent window is narrowed in the EIT whose two ground levels are composed of two hyperfine levels, and broadened in the case when the two ground levels are degenerated Zeeman sublevels, as the temperature of vapour cell is increased. The explanation for the phenomena is given qualitatively.

  6. Investigations of Low Temperature Time Dependent Cracking

    Energy Technology Data Exchange (ETDEWEB)

    Van der Sluys, W A; Robitz, E S; Young, B A; Bloom, J

    2002-09-30

    The objective of this project was to investigate metallurgical and mechanical phenomena associated with time dependent cracking of cold bent carbon steel piping at temperatures between 327 C and 360 C. Boiler piping failures have demonstrated that understanding the fundamental metallurgical and mechanical parameters controlling these failures is insufficient to eliminate it from the field. The results of the project consisted of the development of a testing methodology to reproduce low temperature time dependent cracking in laboratory specimens. This methodology was used to evaluate the cracking resistance of candidate heats in order to identify the factors that enhance cracking sensitivity. The resultant data was integrated into current available life prediction tools.

  7. Temperature dependence of DC SQUID magnetometer performances

    Energy Technology Data Exchange (ETDEWEB)

    Granata, C. E-mail: c.granata@cib.na.cnr.it; Monaco, A.; Di Russo, C.; Lissitski, M.P.; Russo, M

    2004-05-01

    We report experimental results on temperature dependence of the main characteristics of fully integrated DC SQUID magnetometers realized on niobium technology. At T=4.2 K the sensor shown a white magnetic field noise spectral density of 2.9 fT/Hz{sup 1/2}. A slow increase of the field noise (about 20%) was observed with increasing temperature up to 5 K, giving a considerable tolerance of the working temperature of niobium magnetometers in some innovative multichannel systems for magnetoencephalography.

  8. Measurements of temperature dependence of 'localized susceptibility'

    CERN Document Server

    Shiozawa, H; Ishii, H; Takayama, Y; Obu, K; Muro, T; Saitoh, Y; Matsuda, T D; Sugawara, H; Sato, H

    2003-01-01

    The magnetic susceptibility of some rare-earth compounds is estimated by measuring magnetic circular dichroism (MCD) of rare-earth 3d-4f absorption spectra. The temperature dependence of the magnetic susceptibility obtained by the MCD measurement is remarkably different from the bulk susceptibility in most samples, which is attributed to the strong site selectivity of the core MCD measurement.

  9. The activity and radial dependence of anomalous diffusion by pitch angle scattering on split magnetic drift shells

    Science.gov (United States)

    O'Brien, T. P.

    2015-01-01

    in the magnetospheric magnetic field produce drift shell splitting, which causes the radial (drift shell) invariant to sometimes depend on pitch angle. Where drift shell splitting is significant, pitch angle scattering leads to diffusion in all three invariants of the particle's motion, including cross diffusion. We examine the magnitude of drift shell splitting-related anomalous diffusion for outer zone electrons compared to conventional diffusion in the absence of drift shell splitting. We assume that the primary local scattering process is wave-particle interactions with chorus. We find that anomalous radial diffusion can exceed that of conventional drift-resonant radial diffusion for particles with energies near 0.1 MeV at all radial distances outside the plasmasphere during quiet to moderate geomagnetic activity, and it is significant at 0.5 MeV. Cross diffusion involving the radial invariant can exceed the geometric mean of the corresponding pure diffusion coefficients at 0.1 MeV, and that such cross diffusion is significant even at 0.5-1 MeV. At 1 MeV, cross diffusion is often significant. The highest radial distances and magnetic activity levels in our study do not always exhibit as much significant anomalous diffusion as moderate radial distances and activity levels. This can be explained by (a) stronger dependence of conventional diffusion on magnetic activity and radius, and (b) strongest drift shell splitting at moderate magnetic activity. Simulation codes that neglect the possibility for cross terms will likely systematically underperform, especially for 0.1-0.5 MeV electrons, for much of the outer zone for quiet to moderate levels of magnetic activity.

  10. Temperature dependent quasiparticle renormalization in nickel and iron

    Energy Technology Data Exchange (ETDEWEB)

    Ovsyannikov, Ruslan; Thirupathaiah, Setti; Sanchez-Barriga, Jaime; Fink, Joerg; Duerr, Hermann [Helmholtz Zentrum Berlin, BESSY II, Albert-Einstein-Strasse 15, D-12489 Berlin (Germany)

    2010-07-01

    One of the fundamental consequences of electron correlation effects is that the bare particles in solids become 'dressed' with an excitation cloud resulting in quasiparticles. Such a quasiparticle will carry the same spin and charge as the original particle, but will have a renormalized mass and a finite lifetime. The properties of many-body interactions are described with a complex function called self energy which is directly accessible to modern high-resolution angle resolved photoemission spectroscopy (ARPES). Ferromagnetic metals like nickel or iron offers the exciting possibility to study the spin dependence of quasiparticle coupling to bosonic modes. Utilizing the exchange split band structure as an intrinsic 'spin detector' it is possible to distinguish between electron-phonon and electron-magnon coupling phenomena. In this contribution we will report a systematic investigation of the k- and temperature dependence of the electron-boson coupling in nickel and iron metals as well as discuss origin of earlier observed anomalous lifetime broadening of majority spin states of nickel at Fermi level.

  11. Temperature dependence of photoconductivity of color centers

    Energy Technology Data Exchange (ETDEWEB)

    Lakhno, V.D. (AN SSSR, Moscow. Nauchno-Vychislitel' nyj Tsentr)

    A method to calculate thermal activation energy ..delta..E from photoconductivity of colour centres taking into account its temperature dependence is suggested. Comparison of ..delta..E for ionic crystals (KCl, KBr, KI, RbCl), prepared by theoretical and experimental ways is made. It is shown, that the calculated values of ..delta..E are close to the experimental ones and can be used to calculate values, the experimental data for which are absent.

  12. Anomalous Ba/Ca signals associated with low temperature stresses in Porites corals from Daya Bay, northern South China Sea

    Institute of Scientific and Technical Information of China (English)

    Tianran Chen; Kefu Yu; Shu Li; Tegu Chen; Qi Shi

    2011-01-01

    Barium to calcium (Ba/Ca) ratio in corals has been considered as a useful geochemical proxy for upwelling,river flood and other oceanic processes.However,recent studies indicated that additional environmental or biological factors can influence the incorporation of Ba into coral skeletons.In this study,Ba/Ca ratios of two Porites corals collected from Daya Bay,northern South China Sea were analyzed.Ba/Ca signals in the two corals were 'anomalous' in comparison with Ba behaviors seen in other near-shore corals influenced by upwelling or riverine runoff.Our Ba/Ca profiles displayed similar and remarkable patterns characterized by low and randomly fluctuating background signals periodically interrupted by sharp and large synchronous peaks,clearly indicating an environmental forcing.Further analysis indicated that the Ba/Ca profiles were not correlated with previously claimed environmental factors such as precipitation,coastal upwelling,anthropogenic activities or phytoplankton blooms in other areas.The maxima of Ba/Ca appeared to occur in the period of Sr/Ca maxima,coinciding with the winter minimum temperatures,which suggests that the anomalous high Ba/Ca signals were related to winter-time low sea surface temperature.We speculated that the Ba/Ca peaks in corals of the Daya Bay were most likely the results of enrichment of Ba-rich particles in their skeletons when coral polyps retracted under the stresses of anomalous winter low temperatures.In this case,Ba/Ca ratio in relatively high-latitude corals can be a potential proxy for tracing the low temperature stress.

  13. Radial deformation of single-walled carbon nanotubes on quartz substrates and the resultant anomalous diameter-dependent reaction selectivity

    Institute of Scientific and Technical Information of China (English)

    Juan Yang; Yu Liu; Daqi Zhang; Xiao Wang; Ruoming Li; Yan Li

    2015-01-01

    Owing to the unique conjugated structure, the chemical-reaction selectivity of single-walled carbon nanotubes (SWNTs) has attracted great attention. By utilizing the radial deformation of SWNTs caused by the strong interactions with the quartz lattice, we achieve an anomalous diameter-dependent reaction selectivity of quartz lattice-oriented SWNTs in treatment with iodine vapor; this is distinctly different from the widely reported and well accepted higher reaction activity in small-diameter tubes compared to large-diameter tubes. The radial deformation of SWNTs on quartz substrate is verified by detailed Raman spectroscopy and mappings in both G-band and radial breathing mode. Due to the strong interaction between SWNTs and the quartz lattice, large-diameter tubes present a larger degree of radial deformation and more delocalized partial electrons are distributed at certain sidewall sites with high local curvature. It is thus easier for the carbon--carbon bonds at these high-curvature sites on large-diameter tubes to break down during reaction. This anomalous reaction activity offers a novel approach for selective removal of small-band~aD large-diameter tubes.

  14. Temperature dependent light transmission in ferrofluids

    Science.gov (United States)

    Brojabasi, Surajit; Mahendran, V.; Lahiri, B. B.; Philip, John

    2015-05-01

    We investigate the influence of temperature on the magnetic field induced light transmission in a kerosene based ferrofluid containing oleic acid coated Fe3O4 nanoparticles, where the direction of propagation of light is parallel to the direction of the external magnetic field. At a fixed temperature the transmitted light intensity is found to monotonically increase with incident wavelength due to reduced extinction efficiency at higher wavelength. The transmitted intensity decreases with external magnetic field due to enhanced scattering from the field induced linear chain like structures along the direction of the external magnetic field and due to the build-up of standing waves inside the scattering medium. The extinction of the field induced transmitted light intensity is found to occur at a lower external field as the sample temperature is lowered. The rate of extinction of normalized transmitted light intensity decreased linearly with increasing sample temperature due to slower field induced aggregation kinetics because of an increased Brownian motion of the suspended nanoparticles and a reduced coupling constant. The observed temperature dependent magneto-optical properties of magnetic nanofluids can be exploited for applications in optical devices.

  15. Temperature-dependent photoluminescence of polyazomethine films

    International Nuclear Information System (INIS)

    We report absorption and first reliable photoluminescence (PL) studies at various temperatures on relatively thick films of the basic polyazomethine — PPI, i.e., poly(1,4-phenylene-methylidynenitrilo-1,4-phenylenenitrilomethylidine), prepared by chemical vapor deposition (CVD). Both absorption and PL spectra exhibit the vibronic progression due to the C–C stretching mode, characteristic for conjugated polymers. The absorption spectra appear to be practically temperature independent, in contrast to PL spectra, the intensity of which strongly decreases with increasing temperature. The origin of generally weak photoluminescence of PPI is suggested to be the result of a non-radiative electronic state occupied by the lone electron pair on the nitrogen orbital. - Highlights: ► First reliable observation of photoluminescence (PL) in polyazomethine (PPI). ► PL spectrum of PPI appears to be strongly temperature-dependent. ► Weak PL of PPI is a result of non-radiative state occupied by lone electron pair.

  16. Temperature Dependent Kinetics DNA Charge Transport

    Science.gov (United States)

    Wohlgamuth, Chris; McWilliams, Marc; Slinker, Jason

    2012-10-01

    Charge transport (CT) through DNA has been extensively studied, and yet the mechanism of this process is still not yet fully understood. Besides the benefits of understanding charge transport through this fundamental molecule, further understanding of this process will elucidate the biological implications of DNA CT and advance sensing technology. Therefore, we have investigated the temperature dependence of DNA CT by measuring the electrochemistry of DNA monolayers modified with a redox-active probe. By using multiplexed electrodes on silicon chips, we compare square wave voltammetry of distinct DNA sequences under identical experimental conditions. We vary the probe length within the well matched DNA duplex in order to investigate distance dependent kinetics. This length dependent study is a necessary step to understanding the dominant mechanism behind DNA CT. Using a model put forth by O'Dea and Osteryoung and applying a nonlinear least squares analysis we are able to determine the charge transfer rates (k), transfer coefficients (α), and the total surface concentration (&*circ;) of the DNA monolayer. Arrhenius like behavior is observed for the multiple probe locations, and the results are viewed in light of and compared to the prominent charge transport mechanisms.

  17. Anomalous equivalent potential temperature: an atmospheric feature predicting days with higher risk for fatal outcome in acute ischemic stroke-a preliminary study.

    Science.gov (United States)

    Folyovich, András; Biczó, Dávid; Al-Muhanna, Nadim; Béres-Molnár, Anna K; Fejős, Ádám; Pintér, Ádám; Bereczki, Dániel; Fischer, Antal; Vadasdi, Károly; Pintér, Ferenc

    2015-09-01

    Acute stroke is a life-threatening condition. Fatal outcome is related to risk factors, some of these affected by climatic changes. Forecasting potentially harmful atmospheric processes may therefore be of practical importance in the acute care of stroke patients. We analyzed the history of all patients with acute ischemic stroke (N = 184) confirmed by neuroimaging including those who died (N = 35, 15 males) at our hospital department in the winter months of 2009. Patient data were anonymized, and the human meteorologists were only aware of patients' age, gender, and exact time of death. Of the meteorological parameters, equivalent potential temperature (EPT) has been chosen for analysis. EPT is generally used for forecasting thunderstorms, but in the case of synoptic scale airflow (10(6) m), it is suitable for characterizing the air mass inflowing from different regions. The behavior of measured EPT values was compared to the climatic (30 years) averages. We developed meteorological criteria for anomalous periods of EPT and tested if such periods are associated with higher rate of fatal outcome. The duration of anomalous and non-anomalous periods was nearly equal during the studied 3 months. Stroke onset distributed similarly between anomalous and non-anomalous days; however, of the 35 deaths, 27 occurred during anomalous periods: on average, 0.56 deaths occurred on anomalous days and 0.19 on non-anomalous days. Winter periods meeting the criteria of anomalous EPT may have a significant adverse human-meteorological impact on the outcome in acute ischemic stroke. PMID:26233665

  18. Anomalously High Isotope Ratio 3He/4He and Tritium in Deuterium-Loaded Metal: Evidence for Nuclear Reaction in Metal Hydrides at Low Temperature

    Institute of Scientific and Technical Information of China (English)

    JIANG Song-Sheng; HE Ming; WU Shao-Yong; QI Bu-Jia

    2012-01-01

    Anomalous 3He/4He ratios in deuterium-loaded titanium samples are observed to be about 1-4x10-1, much greater than the values (<10~4) in natural objects. Control experiments with the deuterium-unloaded titanium sample and original industrial deuterium gas are also carried out, but no anomalous 3He/4He values are observed. In addition, anomalous tritium in deuterium-loaded titanium samples are also observed. To explain the excess 3He and tritium in the deuterium-loaded titanium samples, it is required that the deuteron-induced nuclear reaction occurs in the samples at low temperature.%Anomalous 3He/4He ratios in deuterium-loaded titanium samples are observed to be about 1-4×10-1,much greater than the values (≤10-4) in natural objects.Control experiments with the deuterium-unloaded titanium sample and original industrial deuterium gas are also carried out,but no anomalous 3He/4He values are observed.In addition,anomalous tritium in deuterium-loaded titanium samples are also observed.To explain the excess 3He and tritium in the deuterium-loaded titanium samples,it is required that the deuteron-induced nuclear reaction occurs in the samples at low temperature.

  19. Temperature-Dependent Photoluminescence of Graphene Oxide

    Science.gov (United States)

    Jadhav, S. T.; Rajoba, S. J.; Patil, S. A.; Han, S. H.; Jadhav, L. D.

    2016-01-01

    Graphene oxide thin films have been deposited by spray pyrolysis using graphene oxide powder prepared by modified Hummers method. These thin films were characterized by different physico-chemical techniques. The x-ray diffraction studies revealed the structural properties of GO (graphene oxide) while the Raman spectrum showed the presence of D and G and two-dimensional bands. The D/G intensity ratio for spray-deposited GO film is 1.10. The x-ray photoelectron spectroscopy showed 67% and 33% atomic percentages of carbon and oxygen, respectively. The ratio of O1s/C1s was found to be 0.49. The temperature-dependent photoluminescence of GO thin film and GO solution showed a blue emission.

  20. Anomalous magnetic reordering in magnetodielectric terbium iron garnet at low temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Lahoubi, Mahieddine, E-mail: mlahoubi@hotmail.fr [Department of Physics, Laboratory L.P.S., Faculty of Sciences, Badji Mokhtar-Annaba University, PO Box -12, 23000 Annaba (Algeria); Ouladdiaf, Bachir [Institut Laue Langevin, BP 156, F-38042 Grenoble Cedex 9 (France)

    2015-01-01

    The paper deals with five topics: i) the single three-dimensional irreductible representation (Γ{sub 4g}=T{sub 1g}) of the paramagnetic space group Ia3{sup ¯}d No. 230 is chosen according to the representation analysis of Bertaut for the interpretation of the neutron powder diffraction experiments performed on terbium iron garnet (Tb{sub 3}Fe{sub 5}O{sub 12}); ii) the use of the method of the “symmetry lowering device” of Bertaut in order to select the appropriate rhombohedral subgroup of Ia3{sup ¯}d which allows to deal with the case where the cubic description provides an incomplete answer to the changes observed below 160 K in the ferrimagnetic structure around the [1 1 1] axis from the Néel model toward the “double umbrella” observed at 13 K; iii) the magnetic modes belonging to the one-dimensional irreductible representation A{sub 2g} of the highest rhombohedral subgroup R3{sup ¯}c No. 167 are able to describe the occurrence of its anisotropic character which steeply increases below 160 K due to the concomitant anisotropic effects; iv) the broad anomaly observed near 54 K in the temperature dependences of the components of both sublattices of the Tb{sup 3+} ions in the Wyckoff positions (6e) and (6e′) is explained partially on the basis of the concept of Belov of the strong paraprocess which has been termed “exchange-enhanced paramagnetism” at the so-called “low-temperature point” (T{sub B}); v) the results are related to the magnetodielectric effect in low magnetic field and to the significant coupling between exchange magnons and ligand-field excitations reported recently in this compound. - Highlights: • We examine the changes of the “double umbrella” in TbIG using neutron diffraction. • Symmetry arguments of Bertaut clarify suitable rhombohedral space group at 13 K. • Its opening leads to an increasing of anisotropy of the Tb components below 160 K. • The “low-temperature point” of Belov explains partly its intricate

  1. Anomalous Temperature Effects of the Entanglement of Two Coupled Qubits in Independent Environments

    Institute of Scientific and Technical Information of China (English)

    SHAN Chuan-Jia; CAO Shuai; XUE Zheng-Yuan; ZHU Shi-Liang

    2012-01-01

    We investigate the entanglement dynamical behavior of two coupled qubits via a Heisenberg XX interaction, which are connected with two independent finite temperature heat baths. By numerical simulations of the quantum master equation, it is found that the interesting phenomena of entanglement sudden death (ESD) as well as sudden birth (ESB) appear during the evolution process for particular initial states. We also show that two critical temperatures T1 (determining that the quantum state is entangled or separable) and T2 (where maximal stationary entanglement can be observed) exist, and stationary entanglement exhibits a non-monotonic behavior as a function of the finite temperature noise strength. These results enlarge the domain of the reasonable experimental temperature where stationary entanglement can be observable.%We investigate the entanglement dynamical behavior of two coupled qubits via a Heisenberg XX interaction,which are connected with two independent finite temperature heat baths.By numerical simulations of the quantum master equation,it is found that the interesting phenomena of entanglement sudden death (ESD) as well as sudden birth (ESB) appear during the evolution process for particular initial states.We also show that two critical temperatures T1 (determining that the quantum state is entangled or separable) and T2 (where maximal stationary entanglement can be observed) exist,and stationary entanglement exhibits a non-monotonic behavior as a function of the finite temperature noise strength.These results enlarge the domain of the reasonable experimental temperature where stationary entanglement can be observable.

  2. The anomalous low temperature resistivity of thermally evaporated alpha-Mn thin film

    Energy Technology Data Exchange (ETDEWEB)

    Ampong, F.K., E-mail: kampxx@yahoo.co [Department of Physics, Kwame Nkrumah University of Science and Technology, Kumasi (Ghana); Boakye, F.; Nkum, R.K. [Department of Physics, Kwame Nkrumah University of Science and Technology, Kumasi (Ghana)

    2010-08-15

    Electrical resistivity measurements have been carried out on thermally evaporated alpha-Mn thin film between 300 and 1.4 K using the van der Pauw four probe technique. The film was grown on a glass substrate held at a temperature of 373 K, in an ambient pressure of 5x10{sup -6} Torr. The results show a resistance minimum, a notable characteristic of alpha-Mn but at a (rather high) temperature of 194+-1 K. Below the resistivity maximum which corresponds to 70 K, the resistivity drops by only 0.02 muOMEGAm indicating a rather short range magnetic ordering. The low temperature results show a tendency towards saturation of the resistivity as the temperature approaches zero suggesting a Kondo scattering.

  3. Anomalous Weight Behavior in $YBa_{2}Cu_{3}O_{7}$ Compounds at Low Temperature

    CERN Document Server

    Rounds, F N

    1997-01-01

    YBa2Cu3O7 high temperature superconductor samples were weighed on an electronic balance during a warming cycle beginning at 77 degrees K. The experiment was configured so that the YBa2Cu3O7 material was weighed along with a magnet, a target mass, and liquid Nitrogen coolant. The weights were captured during Nitrogen evaporation. Results indicated unexpected variations in the system weight that appear as a function of temperature and possibly other parameters.

  4. Anomalous thickness-dependent strain states and strain-tunable magnetization in Zn-doped ferrite epitaxial films

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Y. J.; Bao, J.; Gao, C., E-mail: zlluo@ustc.edu.cn, E-mail: cgao@ustc.edu.cn [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China); CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yang, M. M.; Luo, Z. L., E-mail: zlluo@ustc.edu.cn, E-mail: cgao@ustc.edu.cn; Hu, C. S.; Chen, X. C.; Pan, G. Q. [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China); Huang, H. L. [CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhang, S.; Wang, J. W.; Li, P. S.; Liu, Y.; Zhao, Y. G. [Department of Physics and State Key Laboratory of New Ceramics, Fine Processing, Tsinghua University, Beijing 100084 (China); Jiang, T.; Liu, Y. K.; Li, X. G. [Hefei National Laboratory for Physical Sciences at Microscale and Department of Physics, University of Science, Technology of China, Hefei, Anhui 230026 (China)

    2014-05-07

    A series of Zn{sub x}Fe{sub 3−x}O{sub 4} (ZFO, x = 0.4) thin films were epitaxially deposited on single-crystal (001)-SrTiO{sub 3} (STO) substrates by radio frequency magnetron sputtering. The anomalous thickness-dependent strain states of ZFO films were found, i.e., a tensile in-plane strain exists in the thinner ZFO film and which monotonously turns into compressive in the thicker films. Considering the lattice constant of bulk ZFO is bigger than that of STO, this strain state cannot be explained in the conventional framework of lattice-mismatch-induced strain in the hetero-epitaxial system. This unusual phenomenon is proposed to be closely related to the Volmer-Weber film growth mode in the thinner films and incorporation of the interstitial atoms into the island's boundaries during subsequent epitaxial growth of the thicker films. The ZFO/STO epitaxial film is found in the nature of magnetic semiconductor by transport measurements. The in-plane magnetization of the ZFO/STO films is found to increase as the in-plane compressive strain develops, which is further proved in the (001)-ZFO/PMN-PT film where the film strain state can be in situ controlled with applied electric field. This compressive-strain-enhanced magnetization can be attributed to the strain-mediated electric-field-induced in-plane magnetic anisotropy field enhancement. The above results indicate that strain engineering on magnetic oxide semiconductor ZFO films is promising for novel oxide-electronic devices.

  5. Anomalous thickness-dependent strain states and strain-tunable magnetization in Zn-doped ferrite epitaxial films

    Science.gov (United States)

    Yang, Y. J.; Yang, M. M.; Luo, Z. L.; Hu, C. S.; Bao, J.; Huang, H. L.; Zhang, S.; Wang, J. W.; Li, P. S.; Liu, Y.; Zhao, Y. G.; Chen, X. C.; Pan, G. Q.; Jiang, T.; Liu, Y. K.; Li, X. G.; Gao, C.

    2014-05-01

    A series of ZnxFe3-xO4 (ZFO, x = 0.4) thin films were epitaxially deposited on single-crystal (001)-SrTiO3 (STO) substrates by radio frequency magnetron sputtering. The anomalous thickness-dependent strain states of ZFO films were found, i.e., a tensile in-plane strain exists in the thinner ZFO film and which monotonously turns into compressive in the thicker films. Considering the lattice constant of bulk ZFO is bigger than that of STO, this strain state cannot be explained in the conventional framework of lattice-mismatch-induced strain in the hetero-epitaxial system. This unusual phenomenon is proposed to be closely related to the Volmer-Weber film growth mode in the thinner films and incorporation of the interstitial atoms into the island's boundaries during subsequent epitaxial growth of the thicker films. The ZFO/STO epitaxial film is found in the nature of magnetic semiconductor by transport measurements. The in-plane magnetization of the ZFO/STO films is found to increase as the in-plane compressive strain develops, which is further proved in the (001)-ZFO/PMN-PT film where the film strain state can be in situ controlled with applied electric field. This compressive-strain-enhanced magnetization can be attributed to the strain-mediated electric-field-induced in-plane magnetic anisotropy field enhancement. The above results indicate that strain engineering on magnetic oxide semiconductor ZFO films is promising for novel oxide-electronic devices.

  6. Anomalous Increase in Nematic-Isotropic Transition Temperature in Dimer Molecules Induced by a Magnetic Field

    Science.gov (United States)

    Salili, S. M.; Tamba, M. G.; Sprunt, S. N.; Welch, C.; Mehl, G. H.; Jákli, A.; Gleeson, J. T.

    2016-05-01

    We have determined the nematic-isotropic transition temperature as a function of an applied magnetic field in three different thermotropic liquid crystalline dimers. These molecules are comprised of two rigid calamitic moieties joined end to end by flexible spacers with odd numbers of methylene groups. They show an unprecedented magnetic field enhancement of nematic order in that the transition temperature is increased by up to 15 K when subjected to a 22 T magnetic field. The increase is conjectured to be caused by a magnetic-field-induced decrease of the average bend angle in the aliphatic spacers connecting the rigid mesogenic units of the dimers.

  7. Temperature Dependent Molecular Dynamic Simulation of Friction

    CERN Document Server

    Dias, R A; Coura, P Z; Costa, B V

    2006-01-01

    In this work we present a molecular dynamics simulation of a FFM experiment. The tip-sample interaction is studied by varying the normal force in the tip and the temperature of the surface. The friction force, cA, at zero load and the friction coefficient, $\\mu$, were obtained. Our results strongly support the idea that the effective contact area, A, decreases with increasing temperature and the friction coefficient presents a clear signature of the premelting process of the surface.

  8. Anomalous fermion number non-conservation at high temperatures: Two dimensional example

    International Nuclear Information System (INIS)

    We consider γ5 version of Abelian Higgs model in 1+1 dimensions and find one loop expression for the rate of fermion number non-conservation at high temperatures. We discuss the construction of the noncontractible loop in the configuration space and an analog of the sphaleron solution in the theory. (orig.)

  9. Parametric dependencies of JET electron temperature profiles

    Energy Technology Data Exchange (ETDEWEB)

    Schunke, B. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Imre, K.; Riedel, K. [New York Univ., NY (United States)

    1994-07-01

    The JET Ohmic, L-Mode and H-Mode electron temperature profiles obtained from the LIDAR Thomson Scattering Diagnostic are parameterized in terms of the normalized flux parameter and a set of the engineering parameters like plasma current, toroidal field, line averages electron density... It is shown that the electron temperature profiles fit a log-additive model well. It is intended to use the same model to predict the profile shape for D-T discharges in JET and in ITER. 2 refs., 5 figs.

  10. Temperature dependence of gramicidin channel conductance

    Science.gov (United States)

    Song, Hyundeok; Beck, Thomas

    2010-03-01

    The gramicidin channel is the smallest known biological ion channel, and it exhibits cation selectivity. Recently, Dr. John Cuppoletti's group at the University of Cincinnati has shown that the gramicidin channel can function at high temperatures with significant currents. This finding may have implications for fuel cell technologies. In order to explore the effect of temperature on channel conductance, we examined the gramicidin system at 300K, 330K, and 360K by computer simulation. Two forms of gramicidin, the head-to-head helical dimer and the intertwined double helix, were examined. Both the decrease of the free energy barrier and the increase of the diffusion of potassium ions inside the gramicidin channel at high temperatures imply an increase of current. We found that higher temperatures also affect the lifetime of hydrogen bonds, the distribution of the bending angle, the distribution of the distance between dimers, and the size of the pore radius for the helical dimer structure. These finding may be related to the gating of the gramicidin channel.

  11. The universality of enzymatic rate-temperature dependency.

    Science.gov (United States)

    Elias, Mikael; Wieczorek, Grzegorz; Rosenne, Shaked; Tawfik, Dan S

    2014-01-01

    Organismal adaptation to extreme temperatures yields enzymes with distinct configurational stabilities, including thermophilic and psychrophilic enzymes, which are adapted to high and low temperatures, respectively. These enzymes are widely assumed to also have unique rate-temperature dependencies. Thermophilic enzymes, for example, are considered optimal at high temperatures and effectively inactive at low temperatures due to excess rigidity. Surveying published data, we find that thermophilic, mesophilic, and psychrophilic enzymes exhibit indistinguishable rate-temperature dependencies. Furthermore, given the nonenzymatic rate-temperature dependency, all enzymes, regardless of their operation temperatures, become >10-fold less powerful catalysts per 25 °C temperature increase. Among other factors, this loss of rate acceleration may be ascribed to thermally induced vibrations compromising the active-site catalytic configuration, suggesting that many enzymes are in fact insufficiently rigid.

  12. Testing dependence of anomalous Hall effect on resistivity in SrRuO3 by its increase with electron irradiation

    NARCIS (Netherlands)

    Haham, N.; Konczykowski, M.; Kuiper, B.; Koster, G.; Klein, L.

    2013-01-01

    We measure the anomalous Hall effect (AHE) in several patterns of the itinerant ferromagnet SrRuO 3 before and after the patterns are irradiated with electrons. The irradiation increases the resistivity of the patterns due to the introduction of point defects and we find that the AHE coefficient R

  13. Change of MMP dependent on temperature

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Akwansa, Eugene

    2008-01-01

    was divided into three samples. The pure carbon dioxide was injected into a chamber with the sample under pressure gradually increasing from 60 bars to 420 bars. CO2 was injected in a first sample at temperature 50oC , second at 60oC and third at 70oC. The amount of oil extracted was plotted against pressure......   The experiment was conducted with the purpose to investigate how Minimum Miscibility Pressure (MMP) changes at different temperatures. MMP was measured in a high pressure unit. An original oil saturated chalk core plug from the Danish oil field in North Sea was under investigation. The plug....... The oil recovery/pressure correlation obtained showed that: -  oil recovery grows rather in steps, - MMP (the point B on the curve), above which the oil recovery increases insignificantly,  is equal for all the temperatures, - but the starting points (A on the graph) from which oil recovery starts growing...

  14. Thermal fission rates with temperature dependent fission barriers

    CERN Document Server

    Zhu, Yi

    2016-01-01

    \\item[Background] The fission processes of thermal excited nuclei are conventionally studied by statistical models which rely on inputs of phenomenological level densities and potential barriers. Therefore the microscopic descriptions of spontaneous fission and induced fission are very desirable for a unified understanding of various fission processes. \\item[Purpose] We propose to study the fission rates, at both low and high temperatures, with microscopically calculated temperature-dependent fission barriers and mass parameters. \\item[Methods] The fission barriers are calculated by the finite-temperature Skyrme-Hartree-Fock+BCS method. The mass parameters are calculated by the temperature-dependent cranking approximation. The thermal fission rates can be obtained by the imaginary free energy approach at all temperatures, in which fission barriers are naturally temperature dependent. The fission at low temperatures can be described mainly as a barrier-tunneling process. While the fission at high temperatures ...

  15. Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.Y.; Horton, W. (Texas Univ., Austin, TX (United States). Inst. for Fusion Studies); Coppi, B. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Research Lab. of Electronics)

    1992-01-01

    Experiments show that the observed radial profiles of the ion thermal conductivity {chi}{sub i} have the opposite shapes with those obtained from the ion temperature gradient mode ({eta}{sub i} mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal {eta}{sub i} mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal {eta}{sub i} mode, and that the observed reduction of {chi}{sub i}(r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the {chi}{sub i}. It is shown the new formula fits well the observed {chi}{sub i}(r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula.

  16. Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.Y.; Horton, W. [Texas Univ., Austin, TX (United States). Inst. for Fusion Studies; Coppi, B. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Research Lab. of Electronics

    1992-08-01

    Experiments show that the observed radial profiles of the ion thermal conductivity {chi}{sub i} have the opposite shapes with those obtained from the ion temperature gradient mode ({eta}{sub i} mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal {eta}{sub i} mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal {eta}{sub i} mode, and that the observed reduction of {chi}{sub i}(r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the {chi}{sub i}. It is shown the new formula fits well the observed {chi}{sub i}(r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula.

  17. Anomalous ion thermal transport in hot ion plasmas by the ion temperature gradient mode

    International Nuclear Information System (INIS)

    Experiments show that the observed radial profiles of the ion thermal conductivity χi have the opposite shapes with those obtained from the ion temperature gradient mode (ηi mode) turbulence model by the traditional mixing length estimate. In this work, this radial profile problem is reconsidered with an electromagnetic study of the linear stability of the toroidal ηi mode and a new rule for choosing the mixing length. It is first shown that the electromagnetic effect gives a significant stabilizing effect on the toroidal ηi mode, and that the observed reduction of χi(r) in the core region can be explained by this electromagnetic effect. Secondly, in view of earlier numerical simulations showing the transfer of fluctuation energy to larger scales that those for the fastest growth rate, as well as fluctuation measurements indicating longer radial correlation lengths, a new mixing length formula is proposed to explain the radial increase of the χi. It is shown the new formula fits well the observed χi(r) profiles in two TFTR supershot discharges and also gives the scaling law in the current and the magnetic field which agrees better with experiment than the conventional formula

  18. Temperature dependence of anuran distortion product otoacoustic emissions

    NARCIS (Netherlands)

    Meenderink, Sebastlaan W. F.; Van Dijk, Pim

    2006-01-01

    To study the possible involvement of energy dependent mechanisms in the transduction of sound within the anuran ear, distortion product otoacoustic emissions (DPOAEs) were recorded in the northern leopard frog over a range of body temperatures. The effect of body temperature depended on the stimulus

  19. DNAzyme catalytic beacon sensors that resist temperature-dependent variations†

    OpenAIRE

    Nagraj, Nandini; Liu, Juewen; Sterling, Stephanie; Wu, Jenny; Lu, Yi

    2009-01-01

    The temperature-dependent variability of a Pb2+-specific 8-17E DNAzyme catalytic beacon sensor has been addressed through the introduction of mismatches in the DNAzyme, and the resulting sensors resist temperature-dependent variations from 4 to 30 °C.

  20. Crystal structure changes in Ni3Al and its anomalous temperature dependence of strength

    NARCIS (Netherlands)

    Ramesh, R.; Pathiraj, B.; Kolster, B.H.

    1996-01-01

    The existence of a structural transformation in Ni3Al alloys established earlier through X-ray diffraction, dilatometry and TEM investigations are summarised. The results obtained are discussed through a model proposed. The L12 structure appears to transform to another L12 or to a DO22 structure dur

  1. Temperature dependence of electronic heat capacity in Holstein model

    CERN Document Server

    Fialko, N S; Lakhno, V D

    2015-01-01

    The dynamics of charge migration was modeled to calculate temperature dependencies of its thermodynamic equilibrium values such as energy and electronic heat capacity in homogeneous adenine fragments. The energy varies from nearly polaron one at T~0 to midpoint of the conductivity band at high temperatures. The peak on the graph of electronic heat capacity is observed at the polaron decay temperature.

  2. Temperature dependence of DNA condensation at high ionic concentration

    Science.gov (United States)

    Mao, Wei; Gao, Qingqing; Liu, Yanhui; Fan, Yangtao; Hu, Lin; Xu, Houqiang

    2016-08-01

    A series of experiments pointed out that compact states of DNA condensed by multivalent cation prefer higher temperature. The condensed DNA takes elongated coil or compact globule states and the population of the compact globule states increases with an increase in temperature. At the same time, a recent experimental work carried out in buffer solution without multivalent cation points out that DNA persistence length strongly depends on the temperature. DNA persistence length is a key parameter for quantitative interpretation of the conformational properties of DNA and related to the bending rigidity of DNA. It is necessary to revolve the effects of temperature dependence of persistence length on DNA condensation, and a model including the temperature dependence of persistence length and strong correlation of multivalent cation on DNA is provided. The autocorrelation function of the tangent vectors is found as an effective way to detect the temperature dependence of toroid conformations. With an increase in temperature, the first periodic oscillation in the autocorrelation function shifts left and the number of segments containing the first periodic oscillation decreases gradually. According to the experiments mentioned above, the long-axis length is defined to estimate the temperature dependence of condensation process further. At the temperatures defined in experiments mentioned above, the relation between long-axis length and temperature matches the experimental results.

  3. Anomalous Magnetohydrodynamics

    OpenAIRE

    Giovannini, Massimo

    2013-01-01

    Anomalous symmetries induce currents which can be parallel rather than orthogonal to the hypermagnetic field. Building on the analogy with charged liquids at high magnetic Reynolds numbers, the persistence of anomalous currents is scrutinized for parametrically large conductivities when the plasma approximation is accurate. Different examples in globally neutral systems suggest that the magnetic configurations minimizing the energy density with the constraint that the helicity be conserved co...

  4. Temperature dependence of the emissivity of platinum in the IR.

    Science.gov (United States)

    Deemyad, Shanti; Silvera, Isaac F

    2008-08-01

    The accuracy of temperature determination by fitting the spectral irradiance to a Planck curve depends on knowledge of the emissivity at all temperatures and pressures of interest within a spectral region. Here, the emissivity of platinum is measured in the near infrared as a function of temperature. In the wavelength range of study and the temperature range of 650-1100 K, we find the emissivity to be independent of temperature to within experimental error. This result should lead to improved accuracy of temperature measurement by optical pyrometry where platinum is used as a thermal emitter. PMID:19044386

  5. Thermal fission rates with temperature dependent fission barriers

    Science.gov (United States)

    Zhu, Yi; Pei, J. C.

    2016-08-01

    Background: The fission processes of thermal excited nuclei are conventionally studied by statistical models which rely on inputs of phenomenological level densities and potential barriers. Therefore the microscopic descriptions of spontaneous fission and induced fission are very desirable for a unified understanding of various fission processes. Purpose: We propose to study the fission rates, at both low and high temperatures, with microscopically calculated temperature-dependent fission barriers and collective mass parameters. Methods: The fission barriers are calculated by the finite-temperature Skyrme-Hartree-Fock+BCS method. The mass parameters are calculated by the temperature-dependent cranking approximation. The thermal fission rates can be obtained by the imaginary free energy approach at all temperatures, in which fission barriers are naturally temperature dependent. The fission at low temperatures can be described mainly as a barrier-tunneling process. While the fission at high temperatures has to incorporate the reflection above barriers. Results: Our results of spontaneous fission rates reasonably agree with other studies and experiments. The temperature dependencies of fission barrier heights and curvatures have been discussed. The temperature dependent behaviors of mass parameters have also been discussed. The thermal fission rates from low to high temperatures with a smooth connection have been given by different approaches. Conclusions: Since the temperature dependencies of fission barrier heights and curvatures, and the mass parameters can vary rapidly for different nuclei, the microscopic descriptions of thermal fission rates are very valuable. Our studies without free parameters provide a consistent picture to study various fissions such as that in fast-neutron reactors, astrophysical environments, and fusion reactions for superheavy nuclei.

  6. Temperature and phase dependence of positron lifetimes in solid cyclohexane

    DEFF Research Database (Denmark)

    Eldrup, Morten Mostgaard

    1985-01-01

    longer of these (≈ 2.5 ns), which is temperature dependent, is ascribed to ortho-Ps trapped at vacancies. The shorter lifetime (≈ 0.9 ns), shows little temperature dependence. In contrast to most other plastic crystals, no sigmoidal behaviour of the average ortho-Ps lifetime is observed. A possibility......The temperature dependence of position lifetimes in both the brittle and plastic phases of cyclohaxane has been examined. Long-lived components in both phases are associated with the formation of positronium (Ps). Two long lifetimes attributable to ortho-Ps are resolvable in the plastic phase. The...

  7. Anomalous bootstrap current due to drift waves

    International Nuclear Information System (INIS)

    An anomalous parallel current driven by radial flux in tokamak is discussed. Drift waves, which cause an anomalous cross field diffusion, can generate a parallel current in a sheared magnetic field, if the fluctuation level has radial dependence. (author)

  8. Dark Signal Temperature Dependence Correction Method for Miniature Spectrometer Modules

    Directory of Open Access Journals (Sweden)

    Joel Kuusk

    2011-01-01

    Full Text Available A dark signal temperature dependence correction method for miniature spectrometer modules is described in this paper. It is based on laboratory measurements of dark signal temperature dependence at few different integration times. A set of parameters are calculated which make it possible to estimate dark signal at any temperature and integration time within reasonable range. In field conditions, it is not always possible to take frequent dark signal readings during spectral measurements. If temperature is recorded during the measurement, this method can be used for estimating dark signal for every single spectral measurement. The method is validated on two different miniature spectrometers.

  9. Pipeline flow of heavy oil with temperature-dependent viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Maza Quinones, Danmer; Carvalho, Marcio da Silveira [Pontifical Catholic University of Rio de Janeiro (PUC-Rio), RJ (Brazil). Dept. of Mechanical Engineering], E-mail: msc@puc-rio.br

    2010-07-01

    The heavy oil produced offshore needs to be transported through pipelines between different facilities. The pipelines are usually laid down on the seabed and are submitted to low temperatures. Although heavy oils usually present Newtonian behavior, its viscosity is a strong function of temperature. Therefore, the prediction of pressure drops along the pipelines should include the solution of the energy equation and the dependence of viscosity to temperature. In this work, an asymptotic model is developed to study this problem. The flow is considered laminar and the viscosity varies exponentially with temperature. The model includes one-dimensional equations for the temperature and pressure distribution along the pipeline at a prescribed flow rate. The solution of the coupled differential equation is obtained by second-order finite difference. Results show a nonlinear behavior as a result of coupled interaction between the velocity, temperature, and temperature dependent material properties. (author)

  10. 40Ar/39Ar impact ages and time-temperature argon diffusion history of the Bunburra Rockhole anomalous basaltic achondrite

    Science.gov (United States)

    Jourdan, Fred; Benedix, Gretchen; Eroglu, Ela.; Bland, Phil. A.; Bouvier, Audrey.

    2014-09-01

    The Bunburra Rockhole meteorite is a brecciated anomalous basaltic achondrite containing coarse-, medium- and fine-grained lithologies. Petrographic observations constrain the limited shock pressure to between ca. 10 GPa and 20 GPa. In this study, we carried out nine 40Ar/39Ar step-heating experiments on distinct single-grain fragments extracted from the coarse and fine lithologies. We obtained six plateau ages and three mini-plateau ages. These ages fall into two internally concordant populations with mean ages of 3640 ± 21 Ma (n = 7; P = 0.53) and 3544 ± 26 Ma (n = 2; P = 0.54), respectively. Based on these results, additional 40Ar/39Ar data of fusion crust fragments, argon diffusion modelling, and petrographic observations, we conclude that the principal components of the Bunburra Rockhole basaltic achondrite are from a melt rock formed at ∼3.64 Ga by a medium to large impact event. The data imply that this impact generated high enough energy to completely melt the basaltic target rock and reset the Ar systematics, but only partially reset the Pb-Pb age. We also conclude that a complete 40Ar∗ resetting of pyroxene and plagioclase at this time could not have been achieved at solid-state conditions. Comparison with a terrestrial analog (Lonar crater) shows that the time-temperature conditions required to melt basaltic target rocks upon impact are relatively easy to achieve. Ar data also suggest that a second medium-size impact event occurred on a neighbouring part of the same target rock at ∼3.54 Ga. Concordant low-temperature step ages of the nine aliquots suggest that, at ∼3.42 Ga, a third smaller impact excavated parts of the ∼3.64 Ga and ∼3.54 Ga melt rocks and brought the fragments together. The lack of significant impact activity after 3.5 Ga, as recorded by the Bunburra Rockhole suggests that (1) either the meteorite was ejected in a small secondary parent body where it resided untouched by large impacts, or (2) it was covered by a porous heat

  11. A percolation cluster model of the temperature dependent dielectric properties of hydrated proteins

    International Nuclear Information System (INIS)

    This study investigates the temperature dependence of the low frequency dielectric properties (0.1 Hz-1 MHz) of hydrated globular proteins (namely, ovalbumin, lysozyme and pepsin). The study aims to reveal the mechanisms of water-protein interaction from the dielectric response of these model proteins. Two principle dielectric responses were observed for each hydrated protein, namely, an anomalous low frequency dispersion and a dielectric loss peak at higher frequency (called the ε3 dispersion). The low frequency response conformed to a fractional power low of frequency, while the higher frequency response conformed to a Davidson-Cole model. The strength of both processes reached a maximum at a certain temperature within the experimental temperature range. This temperature is referred to as the percolation threshold (PT) and is thought to be associated with the percolation of protons between hydrogen-bonded water molecules. The relaxation times of the ε3 dispersion conformed to Arrhenius behaviour at temperatures below the PT, from which an activation energy (ΔH) could be calculated. This activation energy is thought to be a measure of the concentration of available charged sites through which proton transport is facilitated. The structural fractal dimension in the hydrated protein system was also calculated, and enabled the approximation of the pathway for charge percolation in the protein matrix

  12. A percolation cluster model of the temperature dependent dielectric properties of hydrated proteins

    Energy Technology Data Exchange (ETDEWEB)

    Suherman, Phe Man; Smith, Geoff [Faculty of Applied Sciences, De Montfort University, Leicester (United Kingdom)

    2003-02-21

    This study investigates the temperature dependence of the low frequency dielectric properties (0.1 Hz-1 MHz) of hydrated globular proteins (namely, ovalbumin, lysozyme and pepsin). The study aims to reveal the mechanisms of water-protein interaction from the dielectric response of these model proteins. Two principle dielectric responses were observed for each hydrated protein, namely, an anomalous low frequency dispersion and a dielectric loss peak at higher frequency (called the {epsilon}{sub 3} dispersion). The low frequency response conformed to a fractional power low of frequency, while the higher frequency response conformed to a Davidson-Cole model. The strength of both processes reached a maximum at a certain temperature within the experimental temperature range. This temperature is referred to as the percolation threshold (PT) and is thought to be associated with the percolation of protons between hydrogen-bonded water molecules. The relaxation times of the {epsilon}{sub 3} dispersion conformed to Arrhenius behaviour at temperatures below the PT, from which an activation energy ({delta}H) could be calculated. This activation energy is thought to be a measure of the concentration of available charged sites through which proton transport is facilitated. The structural fractal dimension in the hydrated protein system was also calculated, and enabled the approximation of the pathway for charge percolation in the protein matrix.

  13. Temperature dependence of postmortem MR quantification for soft tissue discrimination

    Energy Technology Data Exchange (ETDEWEB)

    Zech, Wolf-Dieter; Schwendener, Nicole; Jackowski, Christian [University of Bern, From the Institute of Forensic Medicine, Bern (Switzerland); Persson, Anders; Warntjes, Marcel J. [University of Linkoeping, The Center for Medical Image Science and Visualization (CMIV), Linkoeping (Sweden)

    2015-08-15

    To investigate and correct the temperature dependence of postmortem MR quantification used for soft tissue characterization and differentiation in thoraco-abdominal organs. Thirty-five postmortem short axis cardiac 3-T MR examinations were quantified using a quantification sequence. Liver, spleen, left ventricular myocardium, pectoralis muscle and subcutaneous fat were analysed in cardiac short axis images to obtain mean T1, T2 and PD tissue values. The core body temperature was measured using a rectally inserted thermometer. The tissue-specific quantitative values were related to the body core temperature. Equations to correct for temperature differences were generated. In a 3D plot comprising the combined data of T1, T2 and PD, different organs/tissues could be well differentiated from each other. The quantitative values were influenced by the temperature. T1 in particular exhibited strong temperature dependence. The correction of quantitative values to a temperature of 37 C resulted in better tissue discrimination. Postmortem MR quantification is feasible for soft tissue discrimination and characterization of thoraco-abdominal organs. This provides a base for computer-aided diagnosis and detection of tissue lesions. The temperature dependence of the T1 values challenges postmortem MR quantification. Equations to correct for the temperature dependence are provided. (orig.)

  14. Microscopic calculation of the temperature dependence of the effective interaction

    International Nuclear Information System (INIS)

    The effective interaction between two nucleons inside nuclear matter is calculated microscopically for several densities and several temperatures, assuming it is given by the Brueckner g-matrix, derived from the separable Graz version of the Paris potential. Particular attention is paid to the temperature dependence and to the way of putting the effective interaction into a Skyrme functional. It is found that the latter task can be achieved with a very good accuracy and that the Skyrme coefficients are weakly and quadratically temperature dependent. The g-matrix issued from the Paris potential turns out to be rather different from the standard Skyrme forces in singlet odd states. The charge dependence is investigated through the study of neutron matter. The connection with the temperature dependence of the surface energy is also discussed. (orig.)

  15. Hysteresis and Temperature Dependency of Moisture Sorption – New Measurements

    DEFF Research Database (Denmark)

    Rode, Carsten; Hansen, Kurt Kielsgaard

    2011-01-01

    It is well known that sorption characteristics of building materials exhibit hysteresis in the way the equilibrium curves develop between adsorption and desorption, and that the sorption curves are also somewhat temperature dependent. However, these two facts are most often neglected in models...... measurements of hysteresis and temperature dependency of the moisture sorption characteristics of three different porous building materials: aerated concrete, cement paste and spruce. Scanning curves are measured for all three materials where periods with adsorption and desorption interrupt each other...

  16. Identification of temperature-dependent thermal conductivity and experimental verification

    Science.gov (United States)

    Pan, Weizhen; Yi, Fajun; Zhu, Yanwei; Meng, Songhe

    2016-07-01

    A modified Levenberg–Marquardt method (LMM) for the identification of temperature-dependent thermal conductivity is proposed; the experiment and structure of the specimen for identification are also designed. The temperature-dependent thermal conductivities of copper C10200 and brass C28000 are identified to verify the effectiveness of the proposed identification method. The comparison between identified results and the measured data of laser flash diffusivity apparatus indicates the fine consistency and potential usage of the proposed method.

  17. Temperature and size-dependent Hamaker constants for metal nanoparticles

    Science.gov (United States)

    Jiang, K.; Pinchuk, P.

    2016-08-01

    Theoretical values of the Hamaker constant have been calculated for metal nanoparticles using Lifshitz theory. The theory describes the Hamaker constant in terms of the permittivity of the interacting bodies. Metal nanoparticles exhibit an internal size effect that alters the dielectric permittivity of the particle when its size falls below the mean free path of the conducting electrons. This size dependence of the permittivity leads to size-dependence of the Hamaker constant for metal nanoparticles. Additionally, the electron damping and the plasma frequency used to model the permittivity of the particle exhibit temperature-dependence, which lead to temperature dependence of the Hamaker constant. In this work, both the size and temperature dependence for gold, silver, copper, and aluminum nanoparticles is demonstrated. The results of this study might be of interest for studying the colloidal stability of nanoparticles in solution.

  18. Temperature and size-dependent Hamaker constants for metal nanoparticles.

    Science.gov (United States)

    Jiang, K; Pinchuk, P

    2016-08-26

    Theoretical values of the Hamaker constant have been calculated for metal nanoparticles using Lifshitz theory. The theory describes the Hamaker constant in terms of the permittivity of the interacting bodies. Metal nanoparticles exhibit an internal size effect that alters the dielectric permittivity of the particle when its size falls below the mean free path of the conducting electrons. This size dependence of the permittivity leads to size-dependence of the Hamaker constant for metal nanoparticles. Additionally, the electron damping and the plasma frequency used to model the permittivity of the particle exhibit temperature-dependence, which lead to temperature dependence of the Hamaker constant. In this work, both the size and temperature dependence for gold, silver, copper, and aluminum nanoparticles is demonstrated. The results of this study might be of interest for studying the colloidal stability of nanoparticles in solution. PMID:27454147

  19. Temperature Dependence of Radiative and Nonradiative Rates from Time-Dependent Correlation Function Methods.

    Science.gov (United States)

    Banerjee, Shiladitya; Baiardi, Alberto; Bloino, Julien; Barone, Vincenzo

    2016-02-01

    The temperature dependence of the rate constants in radiative and nonradiative decays from excited electronic states has been studied using a time-dependent correlation function approach in the framework of the adiabatic representation and the harmonic oscillator approximation. The present work analyzes the vibrational aspect of the processes, which gives rise to the temperature dependence, with the inclusion of mode-mixing, as well as of frequency change effects. The temperature dependence of the rate constants shows a contrasting nature, depending on whether the process has been addressed within the Franck-Condon approximation or beyond it. The calculation of the Duschinsky matrix and the shift vector between the normal modes of the two states can be done in Cartesian and/or internal coordinates, depending on the flexibility of the investigated molecule. A new computational code has been developed to calculate the rates of intersystem crossing, internal conversion, and fluorescence for selected molecules as functions of temperature. PMID:26683207

  20. Amino acid behavior in aqueous amide solutions: Temperature dependence of the L-phenylalanine–N,N-dimethylformamide interaction

    Energy Technology Data Exchange (ETDEWEB)

    Kustov, Andrey V., E-mail: kustov@isuct.ru

    2013-08-20

    Highlights: • Thermodynamics of amino acid solvation in aqueous DMF solutions was studied at 288–318 K. • The pair interaction parameters were compared with those for urea solutions. • For hydrophobic solutes enthalpies and entropies of interaction reveal strong temperature changes. • The relationship between the temperature dependence of solvation and solute–solute interactions was found. - Abstract: We have studied thermodynamics of the L-phenylalanine (Phe) pair interaction with denaturing agents – urea (U) and dimethylformamide (DMF) at 288–318 K. Our study does indicate that enthalpies and entropies of the Phe–U interaction reveal the anomalous temperature dependence which does not occur for DMF solutions. The anomalous Phe behavior in U solutions appears to be closely related to peculiarities of U hydration. One more result is in the fact that for hydrophobic solutes such as L-phenylalanine and substituted amides it is not justified to use the results obtained at 298 K for predicting the solute behavior at physiological temperatures.

  1. The temperature dependence of electrical excitability in fish hearts.

    Science.gov (United States)

    Vornanen, Matti

    2016-07-01

    Environmental temperature has pervasive effects on the rate of life processes in ectothermic animals. Animal performance is affected by temperature, but there are finite thermal limits for vital body functions, including contraction of the heart. This Review discusses the electrical excitation that initiates and controls the rate and rhythm of fish cardiac contraction and is therefore a central factor in the temperature-dependent modulation of fish cardiac function. The control of cardiac electrical excitability should be sensitive enough to respond to temperature changes but simultaneously robust enough to protect against cardiac arrhythmia; therefore, the thermal resilience and plasticity of electrical excitation are physiological qualities that may affect the ability of fishes to adjust to climate change. Acute changes in temperature alter the frequency of the heartbeat and the duration of atrial and ventricular action potentials (APs). Prolonged exposure to new thermal conditions induces compensatory changes in ion channel expression and function, which usually partially alleviate the direct effects of temperature on cardiac APs and heart rate. The most heat-sensitive molecular components contributing to the electrical excitation of the fish heart seem to be Na(+) channels, which may set the upper thermal limit for the cardiac excitability by compromising the initiation of the cardiac AP at high temperatures. In cardiac and other excitable cells, the different temperature dependencies of the outward K(+) current and inward Na(+) current may compromise electrical excitability at temperature extremes, a hypothesis termed the temperature-dependent depression of electrical excitation. PMID:27385752

  2. Temperature dependence of photovoltaic cells, modules, and systems

    Energy Technology Data Exchange (ETDEWEB)

    Emery, K.; Burdick, J.; Caiyem, Y. [National Renewable Energy Lab., Golden, CO (United States)] [and others

    1996-05-01

    Photovoltaic (PV) cells and modules are often rated in terms of a set of standard reporting conditions defined by a temperature, spectral irradiance, and total irradiance. Because PV devices operates over a wide range of temperatures and irradiances, the temperature and irradiance related behavior must be known. This paper surveys the temperature dependence of crystalline and thin-film, state-of-the-art, research-size cells, modules, and systems measured by a variety of methods. The various error sources and measurement methods that contribute to cause differences in the temperature coefficient for a given cell or module measured with various methods are discussed.

  3. A new temperature-dependent equation of state of solids

    Indian Academy of Sciences (India)

    Kamal Kapoor; Anuj Kumar; Narsingh Dass

    2014-03-01

    In the present paper, a temperature-dependent equation of state (EOS) of solids is discussed which is found to be applicable in high-pressure and high-temperature range. Present equation of state has been applied in 18 solids. The calculated data are found in very good agreement with the data available from other sources.

  4. Temperature Dependence of GaN HEMT Small Signal Parameters

    Directory of Open Access Journals (Sweden)

    Ali M. Darwish

    2011-01-01

    Full Text Available This study presents the temperature dependence of small signal parameters of GaN/SiC HEMTs across the 0–150°C range. The changes with temperature for transconductance (m, output impedance (ds and ds, feedback capacitance (dg, input capacitance (gs, and gate resistance (g are measured. The variations with temperature are established for m, ds, ds, dg, gs, and g in the GaN technology. This information is useful for MMIC designs.

  5. Temperature Dependence of Viscosities of Common Carrier Gases

    Science.gov (United States)

    Sommers, Trent S.; Nahir, Tal M.

    2005-01-01

    Theoretical and experimental evidence for the dependence of viscosities of the real gases on temperature is described, suggesting that this dependence is greater than that predicted by the kinetic theory of gases. The experimental results were obtained using common modern instrumentation and could be reproduced by students in analytical or…

  6. Anomalous spreading of a density front from an infinite continuous source in a concentration-dependent lattice gas automaton diffusion model

    CERN Document Server

    Kuentz, M

    2003-01-01

    A two-dimensional lattice gas automaton (LGA) is used for simulating concentration-dependent diffusion in a microscopically random heterogeneous structure. The heterogeneous medium is initialized at a low density rho sub 0 and then submitted to a steep concentration gradient by continuous injection of particles at a concentration rho sub 1 >rho sub 0 from a one-dimensional source to model spreading of a density front. Whereas the nonlinear diffusion equation generally used to describe concentration-dependent diffusion processes predicts a scaling law of the type phi = xt sup - sup 1 sup / sup 2 in one dimension, the spreading process is shown to deviate from the expected t sup 1 sup / sup 2 scaling. The time exponent is found to be larger than 1/2, i.e. diffusion of the density front is enhanced with respect to standard Fickian diffusion. It is also established that the anomalous time exponent decreases as time elapses: anomalous spreading is thus not a timescaling process. We demonstrate that occurrence of a...

  7. Arrhenius temperature dependence of in vitro tissue plasminogen activator thrombolysis

    Science.gov (United States)

    Shaw, George J.; Dhamija, Ashima; Bavani, Nazli; Wagner, Kenneth R.; Holland, Christy K.

    2007-06-01

    Stroke is a devastating disease and a leading cause of death and disability. Currently, the only FDA approved therapy for acute ischemic stroke is the intravenous administration of the thrombolytic medication, recombinant tissue plasminogen activator (tPA). However, this treatment has many contraindications and can have dangerous side effects such as intra-cerebral hemorrhage. These treatment limitations have led to much interest in potential adjunctive therapies, such as therapeutic hypothermia (T model. We find that the temperature dependence is well described by an Arrhenius temperature dependence with an effective activation energy Eeff of 42.0 ± 0.9 kJ mole-1. Eeff approximates the activation energy of the plasminogen-to-plasmin reaction of 48.9 kJ mole-1. A model to explain this temperature dependence is proposed. These results will be useful in predicting the effects of temperature in future lytic therapies.

  8. Analysis of the anomalous scale-dependent behavior of dispersivity using straightforward analytical equations: Flow variance vs. dispersion

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.B. [E.I. du Pont de Nemours and Co., Aiken, SC (United States). Savannah River Lab.; Scott, M.T. [Clemson Univ., SC (United States)

    1988-12-31

    Recent field and laboratory data have confirmed that apparent dispersivity is a function of the flow distance of the measurement. This scale effect is not consistent with classical advection dispersion modeling often used to describe the transport of solutes in saturated porous media. Many investigators attribute this anomalous behavior to the fact that the spreading of solute is actually the result of the heterogeneity of subsurface materials and the wide distribution of flow paths and velocities available in such systems. An analysis using straightforward analytical equations confirms this hypothesis. An analytical equation based on a flow variance approach matches available field data when a variance description of approximately 0.4 is employed. Also, current field data provide a basis for statistical selection of the variance parameter based on the level of concern related to the resulting calculated concentration. While the advection dispersion approach often yielded reasonable predictions, continued development of statistical and stochastic techniques will provide more defendable and mechanistically descriptive models.

  9. Temperature dependence of surface enhanced Raman scattering on C70

    Institute of Scientific and Technical Information of China (English)

    GAO Ying; Zhang Zhenlong; DU Yinxiao; DONG Hua; MO Yujun

    2005-01-01

    The temperature dependence of surface enhanced Raman scattering of the C70 molecule is reported.The Raman scattering of C70 molecules adsorbed on the surface of a silver mirror was measured at different temperatures. The experimental results indicate that the relative intensities of the Raman features vary with the temperature of the sample. When the temperature decreases from room temperature to 0℃, the relative intensities of certain Raman bands decrease abruptly. If we take the strongest band 1565cm-1 as a standard value 100, the greatest decrease approaches to 43%. However, with the further decrease in the temperature these relative intensities increase and resume the value at room temperature. And such a temperature dependence is reversible. Our results show that the adsorption state of the C70 molecules on the silver surface around 0℃changes greatly with the temperature, resulting in a decrease in relative intensities for some main Raman features of C70molecule. When the temperature is lower than 0℃, the adsorption state changes continually and more slowly. Synchronously, eight new Raman featu res, which have not ever been reported in literature, are observed in our experiment and this enriches the basic information of the vibrational modes for C70 molecule.

  10. Fractal model of anomalous diffusion.

    Science.gov (United States)

    Gmachowski, Lech

    2015-12-01

    An equation of motion is derived from fractal analysis of the Brownian particle trajectory in which the asymptotic fractal dimension of the trajectory has a required value. The formula makes it possible to calculate the time dependence of the mean square displacement for both short and long periods when the molecule diffuses anomalously. The anomalous diffusion which occurs after long periods is characterized by two variables, the transport coefficient and the anomalous diffusion exponent. An explicit formula is derived for the transport coefficient, which is related to the diffusion constant, as dependent on the Brownian step time, and the anomalous diffusion exponent. The model makes it possible to deduce anomalous diffusion properties from experimental data obtained even for short time periods and to estimate the transport coefficient in systems for which the diffusion behavior has been investigated. The results were confirmed for both sub and super-diffusion.

  11. Temperature Dependent Constitutive Modeling for Magnesium Alloy Sheet

    International Nuclear Information System (INIS)

    Magnesium alloys have been increasingly used in automotive and electronic industries because of their excellent strength to weight ratio and EMI shielding properties. However, magnesium alloys have low formability at room temperature due to their unique mechanical behavior (twinning and untwining), prompting for forming at an elevated temperature. In this study, a temperature dependent constitutive model for magnesium alloy (AZ31B) sheet is developed. A hardening law based on non linear kinematic hardening model is used to consider Bauschinger effect properly. Material parameters are determined from a series of uni-axial cyclic experiments (T-C-T or C-T-C) with the temperature ranging 150-250 deg. C. The influence of temperature on the constitutive equation is introduced by the material parameters assumed to be functions of temperature. Fitting process of the assumed model to measured data is presented and the results are compared.

  12. Temperature dependence of the Soret coefficient of ionic colloids

    Science.gov (United States)

    Sehnem, A. L.; Figueiredo Neto, A. M.; Aquino, R.; Campos, A. F. C.; Tourinho, F. A.; Depeyrot, J.

    2015-10-01

    The temperature dependence of the Soret coefficient ST(T ) in electrostatically charged magnetic colloids is investigated. Two different ferrofluids, with different particles' mean dimensions, are studied. In both cases we obtain a thermophilic behavior of the Soret effect. The temperature dependence of the Soret coefficient is described assuming that the nanoparticles migrate along the ionic thermoelectric field created by the thermal gradient. A model based on the contributions from the thermoelectrophoresis and variation of the double-layer energy, without fitting parameters, is used to describe the experimental results of the colloid with the bigger particles. To do so, independent measurements of the ζ potential, mass diffusion coefficient, and Seebeck coefficient are performed. The agreement of the theory and the experimental results is rather good. In the case of the ferrofluid with smaller particles, it is not possible to get experimentally reliable values of the ζ potential and the model described is used to evaluate this parameter and its temperature dependence.

  13. Temperature dependent elasticity and damping in dehydrated sandstone

    Science.gov (United States)

    Darling, T. W.; Struble, W.

    2013-12-01

    Work reported previously at this conference, outlining our observation of anomalously large elastic softening and damping in dehydrated Berea sandstone at elevated temperatures, has been analysed to study shear and compressional effects separately. Modeling of the sample using COMSOL software was necessary to identify modes, as the vibration spectrum of the sample is poorly approximated by a uniform isotropic solid. The first torsional mode of our evacuated, dry, core softens at nearly twice the rate of Young's modulus modes (bending and compressional) and is also damped nearly twice as strongly as temperature increases. We consider two possible models for explaining this behavior, based on the assumption that the mechanical properties of the sandstone are dominated by the framework of quartz grains and polycrystalline cementation, neglecting initially the effects of clay and feldspar inclusions. The 20cm x 2.54cm diameter core is dry such that the pressure of water vapor in the experiment chamber is below 1e-6 Torr at 70C, suggesting that surface water beyond a small number of monolayers is negligible. Our models consider (1) enhanced sliding of grain boundaries in the cementation at elevated temperature and reduced internal water content, and (2) strain microcracking of the cementatioin at low water content due to anisotropic expansion in the quartz grains. In model (1) interfaces parallel to polyhedral grain surfaces were placed in the cement bonds and assigned frictional properties. Model (2) has not yet been implemented. The overall elasticity of a 3-D several-grain model network was determined by modeling quasistatic loading and measuring displacements. Initial results with a small number of grains/bonds suggests that only the first model provides softening and damping for all the modes, however the details of the effects of defect motioin at individual interfaces as the source for the frictional properties is still being evaluated. Nonlinear effects are

  14. Temperature dependence of protein hydration hydrodynamics by molecular dynamics simulations.

    Energy Technology Data Exchange (ETDEWEB)

    Lau, E Y; Krishnan, V V

    2007-07-18

    The dynamics of water molecules near the protein surface are different from those of bulk water and influence the structure and dynamics of the protein itself. To elucidate the temperature dependence hydration dynamics of water molecules, we present results from the molecular dynamic simulation of the water molecules surrounding two proteins (Carboxypeptidase inhibitor and Ovomucoid) at seven different temperatures (T=273 to 303 K, in increments of 5 K). Translational diffusion coefficients of the surface water and bulk water molecules were estimated from 2 ns molecular dynamics simulation trajectories. Temperature dependence of the estimated bulk water diffusion closely reflects the experimental values, while hydration water diffusion is retarded significantly due to the protein. Protein surface induced scaling of translational dynamics of the hydration waters is uniform over the temperature range studied, suggesting the importance protein-water interactions.

  15. Pressure and temperature dependence of growth and morphology of Escherichia coli: Experiments and Stochastic Model

    CERN Document Server

    Kumar, Pradeep

    2012-01-01

    We have investigated the growth of Escherichia coli E.coli, a mesophilic bacterium, as a function of pressure $P$ and temperature $T$. E.coli can grow and divide in a wide range of pressure (1-400atm) and temperature ($23-40^{\\circ}$C). For $T>30^{\\circ}$ C, the division time of E.coli increases exponentially with pressure and exhibit a departure from exponential behavior at pressures between 250-400 atm for all the temperatures studied in our experiments. For $T<30^{\\circ}$ C, the division time shows an anomalous dependence on pressure -- first decreases with increasing pressure and then increases upon further increase of pressure. The sharp change in division time is followed by a sharp change in phenotypic transition of E. Coli at high pressures where bacterial cells switch to an elongating cell type. We propose a model that this phenotypic changes in bacteria at high pressures is an irreversible stochastic process whereas the switching probability to elongating cell type increases with increasing press...

  16. Temperature dependence of temporal resolution in an insect nervous system.

    Science.gov (United States)

    Franz, A; Ronacher, B

    2002-05-01

    The vast majority of animals are poikilotherms, and thus face the problem that the temperature of their nervous systems rather smoothly follows the temperature changes imposed by their environment. Since basic properties of nerve cells, e.g., the time constants of ion channels, strongly depend on temperature, a temperature shift likely affects the processing of the temporal structure of sensory stimuli. This can be critical in acoustic communication systems in which time patterns of signals are decisive for recognition by the receiver. We investigated the temperature dependence of the responses of locust auditory receptors and interneurons by varying the temperature of the experimental animals during intracellular recordings. The resolution of fast amplitude modulations of acoustic signals was determined in a gap detection paradigm. In auditory receptors and local (second order) interneurons, temporal resolution was improved at higher temperatures. This gain could be attributed to a higher precision of spike timing. In a third-order neuron, a rise in temperature affected the interactions of inhibition and excitation in a complex manner, also resulting in a better resolution of gaps in the millisecond range. PMID:12012097

  17. Temperature dependence of plasmon resonances in spheroidal metal nanoparticles

    OpenAIRE

    N.I. Grigorchuk

    2013-01-01

    The effect of the electron temperature on both the light absorption and the scattering by metal nanoparticles (MNs) with excitation of the surface plasmon electron vibrations is studied in the framework of the kinetic theory. The formulae for electroconductivity and polarizability tensors are derived for finite temperatures of an electron gas. The electrical conductivity and the halfwidth of the surface plasmon resonance are studied in detail for a spherical MN. Depending on the size of MN, t...

  18. Thermal fission rates with temperature dependent fission barriers

    OpenAIRE

    Zhu, Yi; Pei, Junchen

    2016-01-01

    The fission processes of thermal excited nuclei are conventionally studied by statistical models which rely on inputs of phenomenological level densities and potential barriers. Therefore the microscopic descriptions of spontaneous fission and induced fission are very desirable for a unified understanding of various fission processes. We propose to study the fission rates, at both low and high temperatures, with microscopically calculated temperature-dependent fission barriers and collective ...

  19. Temperature Dependence of Spreading Width of Giant Dipole Resonance

    CERN Document Server

    Storozhenko, A N; Ventura, A; Blokhin, A I

    2002-01-01

    The Quasiparticle-Phonon Nuclear Model extended to finite temperature within the framework of Thermo Field Dynamics is applied to calculate a temperature dependence of the spreading width Gamma^{\\downarrow} of a giant dipole resonance. Numerical calculations are made for ^{120}Sn and ^{208}Pb nuclei. It is found that Gamma^{\\downarrow} increases with T. The reason of this effect is discussed as well as a relation of the present approach to other ones, existing in the literature.

  20. On the temperature dependence of the chiral vortical effects

    CERN Document Server

    Kalaydzhyan, Tigran

    2014-01-01

    We discuss the origins of temperature dependence of the axial vortical effect (AVE), i.e. generation of an axial current in a rotating chiral medium along the rotation axis. We show that the corresponding transport coefficient depends on the number of light weakly interacting degrees of freedom, rather than on the gravitational anomaly. We also comment on the role of low-dimensional defects in the rotating medium, and appearance of the chiral vortical effect due to them.

  1. Electron temperature profile invariance on OH, L- and H-mode plasmas and consequences for the anomalous transport

    Science.gov (United States)

    Becker, G.

    1992-01-01

    The shapes of the electron temperature and electron density profiles in the OH, L- and H-mode confinement regimes of ASDEX are explored by statistical analysis. It is shown that the shape of Te(r) is conserved in the outer half of the plasma in these regimes and that it is invariant with respect to heating power, heating profile, density, density scale length, q value and ion mass. These results suggest that microturbulence constrains the shape of the temperature profile by adjusting the electron heat diffusivity χe(r). No such invariance is found for the temperature profile in the inner half of the plasma and for the density profile over the whole cross-section. Properties of the empirical electron heat diffusivity and the diffusion coefficient in different regimes can be described by Te profile invariance. The improved confinement with peaked density profiles, the reduction of χe in the bulk of H-mode plasmas and the power dependence of χe in the L-regime are discussed

  2. Origin of the low critical observing temperature of the quantum anomalous Hall effect in V-doped (Bi, Sb)2Te3 film.

    Science.gov (United States)

    Li, W; Claassen, M; Chang, Cui-Zu; Moritz, B; Jia, T; Zhang, C; Rebec, S; Lee, J J; Hashimoto, M; Lu, D-H; Moore, R G; Moodera, J S; Devereaux, T P; Shen, Z-X

    2016-01-01

    The experimental realization of the quantum anomalous Hall (QAH) effect in magnetically-doped (Bi, Sb)2Te3 films stands out as a landmark of modern condensed matter physics. However, ultra-low temperatures down to few tens of mK are needed to reach the quantization of Hall resistance, which is two orders of magnitude lower than the ferromagnetic phase transition temperature of the films. Here, we systematically study the band structure of V-doped (Bi, Sb)2Te3 thin films by angle-resolved photoemission spectroscopy (ARPES) and show unambiguously that the bulk valence band (BVB) maximum lies higher in energy than the surface state Dirac point. Our results demonstrate clear evidence that localization of BVB carriers plays an active role and can account for the temperature discrepancy. PMID:27599406

  3. The temperature dependence of ponded infiltration under isothermal conditions

    Science.gov (United States)

    Constantz, J.; Murphy, F.

    1991-01-01

    A simple temperature-sensitive modification to the Green and Ampt infiltration equation is described; this assumes that the temperature dependence of the hydraulic conductivity is reciprocally equal to the temperature dependence of the viscosity of liquid water, and that both the transmission zone saturation and the wetting front matric potential gradient are independent of temperature. This modified Green and Ampt equation is compared with ponded, isothermal infiltration experiments run on repacked columns of Olympic Sand and Aiken Loam at 5, 25, and 60??C. Experimental results showed increases in infiltration rates of at least 300% between 5 and 60??C for both soil materials, with subsequent increases in cumulative infiltration of even greater magnitudes for the loam. There is good agreement between measured and predicted initial infiltration rates at 25??C for both soil materials, yet at 60??C, the predicted results overestimate initial infiltration rates for the sand and underestimate initial rates for the loam. Measurements of the wetting depth vs. cumulative infiltration indicate that the transmission zone saturation increased with increasing temperature for both soil materials. In spite of this increased saturation with temperature, the final infiltration rates at both 25 and 60??C were predicted accurately using the modified Green and Ampt equation. This suggests that increased saturation occurred primarily in dead-end pore spaces, so that transmission zone hydraulic conductivities were unaffected by these temperature-induced changes in saturation. In conclusion, except for initial infiltration rates at 60??C, the measured influence of temperature on infiltration rates was fully accounted for by the temperature dependence of the viscosity of liquid water. ?? 1991.

  4. Temperature dependent energy levels of methylammonium lead iodide perovskite

    Energy Technology Data Exchange (ETDEWEB)

    Foley, Benjamin J.; Marlowe, Daniel L.; Choi, Joshua J., E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Department of Chemical Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Sun, Keye; Gupta, Mool C., E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Department of Electrical and Computer Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Saidi, Wissam A. [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Scudiero, Louis, E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Chemistry Department and Materials Science and Engineering Program, Washington State University, Pullman, Washington 99164 (United States)

    2015-06-15

    Temperature dependent energy levels of methylammonium lead iodide are investigated using a combination of ultraviolet photoemission spectroscopy and optical spectroscopy. Our results show that the valence band maximum and conduction band minimum shift down in energy by 110 meV and 77 meV as temperature increases from 28 °C to 85 °C. Density functional theory calculations using slab structures show that the decreased orbital splitting due to thermal expansion is a major contribution to the experimentally observed shift in energy levels. Our results have implications for solar cell performance under operating conditions with continued sunlight exposure and increased temperature.

  5. Temperature dependent energy levels of methylammonium lead iodide perovskite

    International Nuclear Information System (INIS)

    Temperature dependent energy levels of methylammonium lead iodide are investigated using a combination of ultraviolet photoemission spectroscopy and optical spectroscopy. Our results show that the valence band maximum and conduction band minimum shift down in energy by 110 meV and 77 meV as temperature increases from 28 °C to 85 °C. Density functional theory calculations using slab structures show that the decreased orbital splitting due to thermal expansion is a major contribution to the experimentally observed shift in energy levels. Our results have implications for solar cell performance under operating conditions with continued sunlight exposure and increased temperature

  6. Temperature Dependent Fluorescence Lifetime Measurements in a Phosphor

    Science.gov (United States)

    Nettles, Charles J.; Smith, R. Seth; Heath, Jonathan J.

    2012-03-01

    This poster will describe an undergraduate senior research project involving fluorescence lifetime measurements in a LaSO4:Eu phosphor compound. Specifically, this project seeks to determine the temperature dependence of the lifetime. The temperature of the phosphor will be varied using a heater block with temperature control. The phosphor will be excited with the 337 nm output of a Nitrogen Laser. An Oriel Monochromator will be used to disperse the fluorescence, and the lifetime for a particular wavelength will be determined from a photomultiplier tube signal. At the time of the presentation, this project will be nearing completion; and I will discuss my progress, successes, and challenges.

  7. Temperature dependence of electronic transport property in ferroelectric polymer films

    International Nuclear Information System (INIS)

    Highlights: • The ferroelectric polymer was fabricated by Langmuir–Blodgett method. • The electrons as the dominant injected carrier were conformed in the ferroelectric polymer films. • The leakage current conduction mechanisms in ferroelectric polymer were investigated. - Abstract: The leakage current mechanism of ferroelectric copolymer of polyvinylidene fluoride with trifluoroethylene prepared by Langmuir–Blodgett was investigated in the temperature range from 100 K to 350 K. The electron as the dominant injected carrier was observed in the ferroelectric copolymer films. The transport mechanisms in copolymer strongly depend on the temperature and applied voltage. From 100 K to 200 K, Schottky emission dominates the conduction. With temperature increasing, the Frenkel–Poole emission instead of the Schottky emission to conduct the carrier transport. When the temperature gets to 260 K, the leakage current becomes independent of temperature, and the space charge limited current conduction was observed

  8. Turbulent thermal boundary layers with temperature-dependent viscosity

    International Nuclear Information System (INIS)

    Highlights: • Turbulent thermal boundary layers with temperature-dependent viscosity are simulated. • Effect of temperature-dependent viscosity on the statistics of the scalar field. • An identity for the Stanton number is derived and analyzed. • Effect of temperature-dependent viscosity on the statistics of scalar transfer rate. • Modification of turbulent flow field leads to an enhanced scalar transfer rate. - Abstract: Direct numerical simulations (DNS) of turbulent boundary layers (TBLs) over isothermally heated walls were performed, and the influence of the wall-heating on the thermal boundary layers was investigated. The DNS adopt an empirical relation for the temperature-dependent viscosity of water. The Prandtl number therefore changes with temperature, while the Péclet number is constant. Two wall temperatures (Tw = 70 °C and 99 °C) were considered relative to T∞ = 30 °C, and a reference simulation of TBL with constant viscosity was also performed for comparison. In the variable viscosity flow, the mean and variance of the scalar, when normalized by the friction temperature deficit, decrease relative to the constant viscosity flow. A relation for the mean scalar which takes into account the variable viscosity is proposed. Appropriate scalings for the scalar fluctuations and the scalar flux are also introduced, and are shown to be applicable for both variable and constant viscosity flows. Due to the modification of the near-wall turbulence, the Stanton number and the Reynolds analogy factor are augmented by 10% and 44%, respectively, in the variable viscosity flow. An identity for the Stanton number is derived and shows that the mean wall-normal velocity and wall-normal scalar flux cause the increase in the heat transfer coefficient. Finally, the augmented near-wall velocity fluctuations lead to an increase of the wall-normal scalar flux, which contributes favorably to the enhanced heat transfer at the wall

  9. DETERMINATION OF TEMPERATURE DISTRIBUTION FOR ANNULAR FINS WITH TEMPERATURE DEPENDENT THERMAL CONDUCTIVITY BY HPM

    Directory of Open Access Journals (Sweden)

    Davood Domairry Ganji

    2011-01-01

    Full Text Available In this paper, homotopy perturbation method has been used to evaluate the temperature distribution of annular fin with temperature-dependent thermal conductivity and to determine the temperature distribution within the fin. This method is useful and practical for solving the nonlinear heat transfer equation, which is associated with variable thermal conductivity condition. The homotopy perturbation method provides an approximate analytical solution in the form of an infinite power series. The annular fin heat transfer rate with temperature-dependent thermal conductivity has been obtained as a function of thermo-geometric fin parameter and the thermal conductivity parameter describing the variation of the thermal conductivity.

  10. A Model of Temperature-Dependent Young's Modulus for Ultrahigh Temperature Ceramics

    Directory of Open Access Journals (Sweden)

    Weiguo Li

    2011-01-01

    Full Text Available Based on the different sensitivities of material properties to temperature between ultrahigh temperature ceramics (UHTCs and traditional ceramics, the original empirical formula of temperature-dependent Young's modulus of ceramic materials is unable to describe the temperature dependence of Young's modulus of UHTCs which are used as thermal protection materials. In this paper, a characterization applied to Young's modulus of UHTC materials under high temperature which is revised from the original empirical formula is established. The applicable temperature range of the characterization extends to the higher temperature zone. This study will provide a basis for the characterization for strength and fracture toughness of UHTC materials and provide theoretical bases and technical reserves for the UHTC materials' design and application in the field of spacecraft.

  11. Efficiencies of thermodynamics when temperature-dependent energy levels exist.

    Science.gov (United States)

    Yamano, Takuya

    2016-03-14

    Based on a generalized form of the second law of thermodynamics, in which the temperature-dependent energy levels of a system are appropriately included in entropy generation, we show that the effect reasonably appears in efficiencies of thermodynamic processes. PMID:26890276

  12. Temperature dependence of the water retention curve for dry soils

    Science.gov (United States)

    Schneider, M.; Goss, K.-U.

    2011-03-01

    Water retention curves (WRCs) are equivalent to water adsorption isotherms that display the soil water content as a function of water activity in the pore space. The use of water activity implies that pure (unbound) water at the given temperature is considered to be a reference state. In this study we measured the temperature dependence of WRCs for nine European soils under dry conditions (i.e., water activity adsorption enthalpy of water, ?, which reflects this temperature dependence, increased with decreasing water content and thus deviated from the condensation enthalpy of a pure (unbound) water phase, ?. These results are explained by the following facts: under increasingly drier conditions the interactions between water molecules and the mineral surfaces become more and more dominant because the sorbed water film becomes very thin. These interactions between water and minerals are stronger than those between pure water molecules. The observed temperature dependence of WRCs varied only a little between the studied soils. Therefore, the average equation, ?, derived from our experimental data may serve as a good approximation of ? for soils in general and thus allow the temperature extrapolation of WRCs (in the dry region down to 30% RH) between 5°C and 40°C without the need for additional experimental information.

  13. Temperature-dependent imaging of living cells by AFM

    International Nuclear Information System (INIS)

    Characterization of lateral organization of plasma membranes is a prerequisite to the understanding of membrane structure-function relationships in living cells. Lipid-lipid and lipid-protein interactions are responsible for the existence of various membrane microdomains involved in cell signalization and in numerous pathologies. Developing approaches for characterizing microdomains associate identification tools like recognition imaging with high-resolution topographical imaging. Membrane properties are markedly dependent on temperature. However, mesoscopic scale topographical information of cell surface in a temperature range covering most of cell biology experimentation is still lacking. In this work we have examined the possibility of imaging the temperature-dependent behavior of eukaryotic cells by atomic force microscopy (AFM). Our results establish that the surface of living CV1 kidney cells can be imaged by AFM, between 5 and 37 deg. C, both in contact and tapping modes. These first temperature-dependent data show that large cell structures appeared essentially stable at a microscopic scale. On the other hand, as shown by contact mode AFM, the surface was highly dynamic at a mesoscopic scale, with marked changes in apparent topography, friction, and deflection signals. When keeping the scanning conditions constant, a progressive loss in the image contrast was however observed, using tapping mode, on decreasing the temperature

  14. Stress versus temperature dependence of activation energies for creep

    Science.gov (United States)

    Freed, A. D.; Raj, S. V.; Walker, K. P.

    1992-01-01

    The activation energy for creep at low stresses and elevated temperatures is associated with lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from dislocation climb to obstacle-controlled dislocation glide. Along with this change in deformation mechanism occurs a change in the activation energy. When the rate controlling mechanism for deformation is obstacle-controlled dislocation glide, it is shown that a temperature-dependent Gibbs free energy does better than a stress-dependent Gibbs free energy in correlating steady-state creep data for both copper and LiF-22mol percent CaF2 hypereutectic salt.

  15. Stress versus temperature dependent activation energies in creep

    Science.gov (United States)

    Freed, A. D.; Raj, S. V.; Walker, K. P.

    1990-01-01

    The activation energy for creep at low stresses and elevated temperatures is lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from that of dislocation climb to one of obstacle-controlled dislocation glide. Along with this change, there occurs a change in the activation energy. It is shown that a temperature-dependent Gibbs free energy does a good job of correlating steady-state creep data, while a stress-dependent Gibbs free energy does a less desirable job of correlating the same data. Applications are made to copper and a LiF-22 mol. percent CaF2 hypereutectic salt.

  16. The temperature dependence of positron annihilation in α-Hf

    International Nuclear Information System (INIS)

    Doppler-broadening of the positron annihilation photopeak has been measured for α-Hf (6.8 at% Zr) in the interval 298-1945 K. The data, in terms of peak (L) and wing (W) line-shape parameters, show three regions of behaviour. Region I, 298-750 K, shows a complex temperature response of W and S: it is associated with positron interactions with impurity-related defects. Region II, 750-1750 K, shows a linear temperature dependence of S and W, it is associated with thermal expansion effects. Region III, 1750-1945 K, shows an increasing temperature dependence indicative of positron-interactions with equilibrium vacancies. The vacancy formation energy deduced from the data is 2.5 eV. (orig.)

  17. Temperature dependence of penetration depth in thin film niobium

    Science.gov (United States)

    More, N.; Muhlfelder, B.; Lockhart, J.

    1989-01-01

    A novel technique is presented which should allow precise determination of the temperature dependence of the inductance, and hence of the penetration depth, of superconducting niobium thin-film structures. Four niobium thin-film stripline inductors are arranged in a bridge configuration, and inductance differences are measured using a potentiometric technique with a SQUID (superconducting quantum interference device) as the null detector. Numerical simulations of the stripline inductances are presented which allow the performance of the measurement technique to be evaluated. The prediction of the two-fluid model for the penetration-depth temperature dependence is given for reduced temperatures of 0.3 to 0.9. The experimental apparatus and its resolution and accuracy are discussed.

  18. Temperature dependence of angular momentum transport across interfaces

    Science.gov (United States)

    Chen, Kai; Lin, Weiwei; Chien, C. L.; Zhang, Shufeng

    2016-08-01

    Angular momentum transport in magnetic multilayered structures plays a central role in spintronic physics and devices. The angular momentum currents or spin currents are carried by either quasiparticles such as electrons and magnons, or by macroscopic order parameters such as local magnetization of ferromagnets. Based on the generic interface exchange interaction, we develop a microscopic theory that describes interfacial spin conductance for various interfaces among nonmagnetic metals, ferromagnetic insulators, and antiferromagnetic insulators. Spin conductance and its temperature dependence are obtained for different spin batteries including spin pumping, temperature gradient, and spin Hall effect. As an application of our theory, we calculate the spin current in a trilayer made of a ferromagnetic insulator, an antiferromagnetic insulator, and a nonmagnetic heavy metal. The calculated results on the temperature dependence of spin conductance quantitatively agree with the existing experiments.

  19. Temperature dependence of APD-based PET scanners

    International Nuclear Information System (INIS)

    Purpose: Solid state detectors such as avalanche photodiodes (APDs) are increasingly being used in PET detectors. One of the disadvantages of APDs is the strong decrease of their gain factor with increasing ambient temperature. The light yield of most scintillation crystals also decreases when ambient temperature is increased. Both effects lead to considerable temperature dependence of the performance of APD-based PET scanners. In this paper, the authors propose a model for this dependence and the performance of the LabPET8 APD-based small animal PET scanner is evaluated at different temperatures.Methods: The model proposes that the effect of increasing temperature on the energy histogram of an APD-based PET scanner is a compression of the histogram along the energy axis. The energy histogram of the LabPET system was acquired at 21 °C and 25 °C to verify the validity of this model. Using the proposed model, the effect of temperature on system sensitivity was simulated for different detector temperature coefficients and temperatures. Subsequently, the effect of short term and long term temperature changes on the peak sensitivity of the LabPET system was measured. The axial sensitivity profile was measured at 21 °C and 24 °C following the NEMA NU 4-2008 standard. System spatial resolution was also evaluated. Furthermore, scatter fraction, count losses and random coincidences were evaluated at different temperatures. Image quality was also investigated.Results: As predicted by the model, the photopeak energy at 25 °C is lower than at 21 °C with a shift of approximately 6% per °C. Simulations showed that this results in an approximately linear decrease of sensitivity when temperature is increased from 21 °C to 24 °C and energy thresholds are constant. Experimental evaluation of the peak sensitivity at different temperatures showed a strong linear correlation for short term (2.32 kcps/MBq/°C = 12%/°C, R = −0.95) and long term (1.92 kcps/MBq/°C = 10%/

  20. Finite element simulation of temperature dependent free surface flows

    Science.gov (United States)

    Engelman, M. S.; Sani, R. L.

    1985-01-01

    The method of Engelman and Sani (1984) for a finite-element simulation of incompressible surface flows with a free and/or moving fluid interface, such as encountered in crystal growth and coating and polymer technology, is extended to temperature-dependent flows, including the effect of temperature-dependent surface tension. The basic algorithm of Saito and Scriven (1981) and Ruschak (1980) has been generalized and implemented in a robust and versatile finite-element code that can be employed with relative ease for the simulation of free-surface problems in complex geometries. As a result, the costly dependence on the Newton-Raphson algorithm has been eliminated by replacing it with a quasi-Newton iterative method, which nearly retains the superior convergence properties of the Newton-Raphson method.

  1. Temperature dependence of carbon isotope fractionation in CAM plants

    Energy Technology Data Exchange (ETDEWEB)

    Deleens, E.; Treichel, I.; O' Leary, M.H.

    1985-09-01

    The carbon isotope fractionation associated with nocturnal malic acid synthesis in Kalanchoe daigremontiana and Bryophyllum tubiflorum was calculated from the isotopic composition of carbon-4 of malic acid, after appropriate corrections. In the lowest temperature treatment (17/sup 0/C nights, 23/sup 0/C days), the isotope fractionation for both plants is -4% per thousand (that is, malate is enriched in /sup 13/C relative to the atmosphere). For K. daigremontiana, the isotope fractionation decreases with increasing temperature, becoming approximately 0% per thousand at 27/sup 0/C/33/sup 0/C. Detailed analysis of temperature effects on the isotope fractionation indicates that stomatal aperture decreases with increasing temperature and carboxylation capacity increases. For B. tubiflorum, the temperature dependence of the isotope fractionation is smaller and is principally attributed to the normal temperature dependences of the rates of diffusion and carboxylation steps. The small change in the isotopic composition of remaining malic acid in both species which is observed during deacidification indicates that malate release, rather than decarboxylation, is rate limiting in the deacidification process. 28 references, 1 figure, 4 tables.

  2. Temperature-Dependent Dielectric Properties of Al/Epoxy Nanocomposites

    Science.gov (United States)

    Wang, Zijun; Zhou, Wenying; Sui, Xuezhen; Dong, Lina; Cai, Huiwu; Zuo, Jing; Chen, Qingguo

    2016-06-01

    Broadband dielectric spectroscopy was carried out to study the transition in electrical properties of Al/epoxy nanocomposites over the frequency range of 1-107 Hz and the temperature range of -20°C to 200°C. The dielectric permittivity, dissipation factor, and electrical conductivity of the nanocomposites increased with temperature and showed an abrupt increase around the glass transition temperature ( T g). The results clearly reveal an interesting transition of the electrical properties with increasing temperature: insulator below 70°C, conductor at about 70°C. The behavior of the transition in electrical properties of the nanocomposites was explored at different temperatures. The presence of relaxation peaks in the loss tangent and electric modulus spectra of the nanocomposites confirms that the chain segmental dynamics of the polymer is accompanied by the absorption of energy given to the system. It is suggested that the temperature-dependent transition of the electric properties in the nanocomposite is closely associated with the α-relaxation. The large increase in the dissipation factor and electric conductivity depends on the direct current conduction of thermally activated charge carriers resulting from the epoxy matrix above T g.

  3. On the Temperature Dependence of Enzyme-Catalyzed Rates.

    Science.gov (United States)

    Arcus, Vickery L; Prentice, Erica J; Hobbs, Joanne K; Mulholland, Adrian J; Van der Kamp, Marc W; Pudney, Christopher R; Parker, Emily J; Schipper, Louis A

    2016-03-29

    One of the critical variables that determine the rate of any reaction is temperature. For biological systems, the effects of temperature are convoluted with myriad (and often opposing) contributions from enzyme catalysis, protein stability, and temperature-dependent regulation, for example. We have coined the phrase "macromolecular rate theory (MMRT)" to describe the temperature dependence of enzyme-catalyzed rates independent of stability or regulatory processes. Central to MMRT is the observation that enzyme-catalyzed reactions occur with significant values of ΔCp(‡) that are in general negative. That is, the heat capacity (Cp) for the enzyme-substrate complex is generally larger than the Cp for the enzyme-transition state complex. Consistent with a classical description of enzyme catalysis, a negative value for ΔCp(‡) is the result of the enzyme binding relatively weakly to the substrate and very tightly to the transition state. This observation of negative ΔCp(‡) has important implications for the temperature dependence of enzyme-catalyzed rates. Here, we lay out the fundamentals of MMRT. We present a number of hypotheses that arise directly from MMRT including a theoretical justification for the large size of enzymes and the basis for their optimum temperatures. We rationalize the behavior of psychrophilic enzymes and describe a "psychrophilic trap" which places limits on the evolution of enzymes in low temperature environments. One of the defining characteristics of biology is catalysis of chemical reactions by enzymes, and enzymes drive much of metabolism. Therefore, we also expect to see characteristics of MMRT at the level of cells, whole organisms, and even ecosystems.

  4. Temperature dependent local atomic displacements in ammonia intercalated iron selenide superconductor.

    Science.gov (United States)

    Paris, E; Simonelli, L; Wakita, T; Marini, C; Lee, J-H; Olszewski, W; Terashima, K; Kakuto, T; Nishimoto, N; Kimura, T; Kudo, K; Kambe, T; Nohara, M; Yokoya, T; Saini, N L

    2016-01-01

    Recently, ammonia-thermal reaction has been used for molecular intercalation in layered FeSe, resulting a new Lix(NH3)yFe2Se2 superconductor with Tc ~ 45 K. Here, we have used temperature dependent extended x-ray absorption fine structure (EXAFS) to investigate local atomic displacements in single crystals of this new superconductor. Using polarized EXAFS at Fe K-edge we have obtained direct information on the local Fe-Se and Fe-Fe bondlengths and corresponding mean square relative displacements (MSRD). We find that the Se-height in the intercalated system is lower than the one in the binary FeSe, suggesting compressed FeSe4 tetrahedron in the title system. Incidentally, there is hardly any effect of the intercalation on the bondlengths characteristics, revealed by the Einstein temperatures, that are similar to those found in the binary FeSe. Therefore, the molecular intercalation induces an effective compression and decouples the FeSe slabs. Furthermore, the results reveal an anomalous change in the atomic correlations across Tc, appearing as a clear decrease in the MSRD, indicating hardening of the local lattice mode. Similar response of the local lattice has been found in other families of superconductors, e.g., A15-type and cuprates superconductors. This observation suggests that local atomic correlations should have some direct correlation with the superconductivity.

  5. Temperature dependent local atomic displacements in ammonia intercalated iron selenide superconductor

    Science.gov (United States)

    Paris, E.; Simonelli, L.; Wakita, T.; Marini, C.; Lee, J.-H.; Olszewski, W.; Terashima, K.; Kakuto, T.; Nishimoto, N.; Kimura, T.; Kudo, K.; Kambe, T.; Nohara, M.; Yokoya, T.; Saini, N. L.

    2016-01-01

    Recently, ammonia-thermal reaction has been used for molecular intercalation in layered FeSe, resulting a new Lix(NH3)yFe2Se2 superconductor with Tc ~ 45 K. Here, we have used temperature dependent extended x-ray absorption fine structure (EXAFS) to investigate local atomic displacements in single crystals of this new superconductor. Using polarized EXAFS at Fe K-edge we have obtained direct information on the local Fe-Se and Fe-Fe bondlengths and corresponding mean square relative displacements (MSRD). We find that the Se-height in the intercalated system is lower than the one in the binary FeSe, suggesting compressed FeSe4 tetrahedron in the title system. Incidentally, there is hardly any effect of the intercalation on the bondlengths characteristics, revealed by the Einstein temperatures, that are similar to those found in the binary FeSe. Therefore, the molecular intercalation induces an effective compression and decouples the FeSe slabs. Furthermore, the results reveal an anomalous change in the atomic correlations across Tc, appearing as a clear decrease in the MSRD, indicating hardening of the local lattice mode. Similar response of the local lattice has been found in other families of superconductors, e.g., A15-type and cuprates superconductors. This observation suggests that local atomic correlations should have some direct correlation with the superconductivity. PMID:27276997

  6. Temperature dependence of contact resistance at metal/MWNT interface

    Science.gov (United States)

    Lee, Sang-Eui; Moon, Kyoung-Seok; Sohn, Yoonchul

    2016-07-01

    Although contact resistance of carbon nanotube (CNT) is one of the most important factors for practical application of electronic devices, a study regarding temperature dependence on contact resistance of CNTs with metal electrodes has not been found. Here, we report an investigation of contact resistance at multiwalled nanotube (MWNT)/Ag interface as a function of temperature, using MWNT/polydimethylsiloxane (PDMS) composite. Electrical resistance of MWNT/PDMS composite revealed negative temperature coefficient (NTC). Excluding the contact resistance with Ag electrode, the NTC effect became less pronounced, showing lower intrinsic resistivity with the activation energy of 0.019 eV. Activation energy of the contact resistance of MWNT/Ag interface was determined to be 0.04 eV, two times larger than that of MWNT-MWNT network. The increase in the thermal fluctuation assisted electron tunneling is attributed to conductivity enhancement at both MWNT/MWNT and MWNT/Ag interfaces with increasing temperature.

  7. Temperature dependence of plasmon resonances in spheroidal metal nanoparticles

    Directory of Open Access Journals (Sweden)

    N.I. Grigorchuk

    2013-01-01

    Full Text Available The effect of the electron temperature on both the light absorption and the scattering by metal nanoparticles (MNs with excitation of the surface plasmon electron vibrations is studied in the framework of the kinetic theory. The formulae for electroconductivity and polarizability tensors are derived for finite temperatures of an electron gas. The electrical conductivity and the halfwidth of the surface plasmon resonance are studied in detail for a spherical MN. Depending on the size of MN, the efficiencies of light absorption and scattering with the temperature change are investigated. It is found, in particular, that the absorption efficiency can both increase and decrease with a temperature drop. The derived formulas make it possible to analytically calculate various optical and transport phenomena for MNs of any spheroidal shape embedded in any dielectric media.

  8. Temperature dependent relativistic mean field for highly excited hot nuclei

    Science.gov (United States)

    Gambhir, Y. K.; Maharana, J. P.; Lalazissis, G. A.; Panos, C. P.; Ring, P.

    2000-11-01

    The temperature dependent relativistic mean field (RMF-T) results obtained by using nonlinear Lagrangian parameter set NL3 are presented for a few selected representative spherical and deformed nuclei. The calculated total binding energy (entropy) decrease (increase) as temperature (T) increases. The depths of the potentials and the single particle (sp) energies change very little with temperature. The density slightly spreads out; as a result the radius increases as temperature rises. For well deformed nuclei the shell effects disappear at around T~3 MeV. This value of T is relatively higher as compared to the corresponding value of T (~1.8 MeV) obtained in the Strutinsky-type calculations. This difference in the value of T is shown to be due to the use of the effective nucleon mass (RMF Lagrangian.

  9. Comparison of Constant and Temperature Dependent Blood Perfusion in Temperature Prediction for Superficial Hyperthermia

    Directory of Open Access Journals (Sweden)

    T. Drizdal

    2010-06-01

    Full Text Available The purpose of this study was to determine whether prediction of the 3D temperature profile for superficial hyperthermia using constant blood perfusion model could be matched to one with a temperature dependent blood perfusion. We compared three different constant blood perfusion scenarios with one temperature dependent blood perfusion using a layered model of biological tissue consisting of skin (2 mm, fat (10 mm and muscle (108 mm. For all four scenarios the maximum temperature of 43 °C was found in the muscle tissue in the close proximity (1 – 3 mm of fat layer. Cumulative histograms of temperature versus volume were identical for the region of 100x100x40 mm3 under the applicator aperture for the three constant blood perfusion models. For temperature dependent blood perfusion model, 85 % of the studied region was covered with the temperature equal or higher than 40 °C in comparison with 43 % for the constant blood perfusion models. Hence this study demonstrates that constant blood perfusion scenarios cannot be matched to one with a temperature dependent blood perfusion.

  10. A nanoscale temperature-dependent heterogeneous nucleation theory

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Y. Y. [Nanosurface Science and Engineering Research Institute, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen, 518060 Guangdong (China); Yang, G. W., E-mail: stsygw@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, Nanotechnology Research Center, School of Materials Science and Engineering, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou, 510275 Guangdong (China)

    2015-06-14

    Classical nucleation theory relies on the hypothetical equilibrium of the whole nucleation system, and neglects the thermal fluctuations of the surface; this is because the high entropic gains of the (thermodynamically extensive) surface would lead to multiple stable states. In fact, at the nanometer scale, the entropic gains of the surface are high enough to destroy the stability of the thermal equilibrium during nucleation, comparing with the whole system. We developed a temperature-dependent nucleation theory to elucidate the heterogeneous nucleation process, by considering the thermal fluctuations based on classical nucleation theory. It was found that the temperature not only affected the phase transformation, but also influenced the surface energy of the nuclei. With changes in the Gibbs free energy barrier, nucleation behaviors, such as the nucleation rate and the critical radius of the nuclei, showed temperature-dependent characteristics that were different from those predicted by classical nucleation theory. The temperature-dependent surface energy density of a nucleus was deduced based on our theoretical model. The agreement between the theoretical and experimental results suggested that the developed nucleation theory has the potential to contribute to the understanding and design of heterogeneous nucleation at the nanoscale.

  11. Temperature-Dependent Giant Magnetoimpedance Effect in Amorphous Soft Magnets

    Science.gov (United States)

    Kurniawan, M.; Roy, R. K.; Panda, A. K.; Greve, D. W.; Ohodnicki, P.; McHenry, M. E.

    2014-12-01

    Giant magnetoimpedance (GMI)-based devices offer potential as next-generation low-cost, flexible, ultrasensitive sensors. They can be used in applications that include current sensors, field sensors, stress sensors, and others. Challenging applications involve operation at high temperatures, and therefore studies of GMI temperature dependence and performance of soft magnetic materials are needed. We present a high-temperature GMI study on an amorphous soft magnetic microwire from room temperature to 560°C. The GMI ratio was observed to be nearly constant at ˜86% at low temperatures and to decrease rapidly at ˜290°C, finally reaching a near-zero value at 500°C. The rapid drop in GMI ratio at 290°C is associated with a reduction in the long-range ferromagnetic order as measured by the spontaneous magnetization ( M) at the Curie temperature ( T c). We also correlated the impedance with the magnetic properties of the material. From room temperature to 290°C, the impedance was found to be proportional to the square root of the magnetization to magnetic anisotropy ratio. Lastly, M( T) has been fit using a Handrich-Kobe model, which describes the system with a modified Brillouin function and an asymmetrical distribution of exchange interactions. We infer that the structural fluctuations of the amorphous phase result in a relatively small asymmetry in the fluctuation parameters.

  12. Temperature-dependent solvation modulates the dimensions of disordered proteins.

    Science.gov (United States)

    Wuttke, René; Hofmann, Hagen; Nettels, Daniel; Borgia, Madeleine B; Mittal, Jeetain; Best, Robert B; Schuler, Benjamin

    2014-04-01

    For disordered proteins, the dimensions of the chain are an important property that is sensitive to environmental conditions. We have used single-molecule Förster resonance energy transfer to probe the temperature-induced chain collapse of five unfolded or intrinsically disordered proteins. Because this behavior is sensitive to the details of intrachain and chain-solvent interactions, the collapse allows us to probe the physical interactions governing the dimensions of disordered proteins. We find that each of the proteins undergoes a collapse with increasing temperature, with the most hydrophobic one, λ-repressor, undergoing a reexpansion at the highest temperatures. Although such a collapse might be expected due to the temperature dependence of the classical "hydrophobic effect," remarkably we find that the largest collapse occurs for the most hydrophilic, charged sequences. Using a combination of theory and simulation, we show that this result can be rationalized in terms of the temperature-dependent solvation free energies of the constituent amino acids, with the solvation properties of the most hydrophilic residues playing a large part in determining the collapse.

  13. Temperature-dependent dielectric properties of a thermoplastic gelatin

    Science.gov (United States)

    Landi, Giovanni; Neitzert, Heinz C.; Sorrentino, Andrea

    2016-05-01

    The frequency and the temperature dependence of the dielectric properties of a thermoplastic gelatin based bio-material have been investigated. At lower frequencies the dielectric response is strongly affected by charge carrier accumulation at the electrodes which modifies the dominating hopping conduction mechanism. The variation of the ac conductivity with frequency obeys a Jonscher type power law except for a small deviation in the low frequency range due to the electrode polarization effect. The master curve of the ac conductivity data shows that the conductivity relaxation of the gelatin is temperature independent.

  14. Temperature dependence of the thermal conductivity of thin silicon nanowires.

    Science.gov (United States)

    Donadio, Davide; Galli, Giulia

    2010-03-10

    We compute the lattice thermal conductivity (kappa) of silicon nanowires as a function of temperature by molecular dynamics simulations. In wires with amorphous surfaces kappa may reach values close to that of amorphous silicon and is nearly constant between 200 and 600 K; this behavior is determined by the presence of a majority of nonpropagating vibrational modes. We develop a parameter-free model that accounts for the temperature dependence observed in our simulations and provides a qualitative explanation of recent experiments. PMID:20163124

  15. The importance of temperature dependent energy gap in the understanding of high temperature thermoelectric properties

    Science.gov (United States)

    Singh, Saurabh; Pandey, Sudhir K.

    2016-10-01

    In this work, we show the importance of temperature dependent energy band gap, E g (T), in understanding the high temperature thermoelectric (TE) properties of material by considering LaCoO3 (LCO) and ZnV2O4 (ZVO) compounds as a case study. For the fix value of band gap, E g , deviation in the values of α has been observed above 360 K and 400 K for LCO and ZVO compounds, respectively. These deviation can be overcomed by consideration of temperature dependent band gap. The change in used value of E g with respect to temperature is ∼4 times larger than that of In As. This large temperature dependence variation in E g can be attributed to decrement in the effective on-site Coulomb interaction due to lattice expansion. At 600 K, the value of ZT for n and p-doped, LCO is ∼0.35 which suggest that it can be used as a potential material for TE device. This work clearly suggest that one should consider the temperature dependent band gap in predicting the high temperature TE properties of insulating materials.

  16. On the Temperature Dependence of the UNIQUAC/UNIFAC Models

    DEFF Research Database (Denmark)

    Skjold-Jørgensen, Steen; Rasmussen, Peter; Fredenslund, Aage

    1980-01-01

    Local composition models for the description of the properties of liquid mixtures do not in general give an accurate representation of excess Gibbs energy and excess enthalpy simultaneously. The introduction of temperature dependent interaction parameters leads to considerable improvements...... of the simultaneous correlation. The temperature dependent parameters have, however, little physical meaning and very odd results are frequently obtained when the interaction parameters obtained from excess enthalpy information alone are used for the prediction of vapor-liquid equilibria. The UNIQUAC/UNIFAC models...... as the original ones, namely two per binary pair of molecules/groups. The resulting simultaneous representation of excess Gibbs energy and excess enthalpy by means of one unique set of parameters is remarkably successful. One may with very good results predict excess Gibbs energy information from UNIQUAC...

  17. Temperature dependence of carrier capture by defects in gallium arsenide

    Energy Technology Data Exchange (ETDEWEB)

    Wampler, William R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Modine, Normand A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-08-01

    This report examines the temperature dependence of the capture rate of carriers by defects in gallium arsenide and compares two previously published theoretical treatments of this based on multi phonon emission (MPE). The objective is to reduce uncertainty in atomistic simulations of gain degradation in III-V HBTs from neutron irradiation. A major source of uncertainty in those simulations is poor knowledge of carrier capture rates, whose values can differ by several orders of magnitude between various defect types. Most of this variation is due to different dependence on temperature, which is closely related to the relaxation of the defect structure that occurs as a result of the change in charge state of the defect. The uncertainty in capture rate can therefore be greatly reduced by better knowledge of the defect relaxation.

  18. Temperature dependence of the beam-foil interaction

    International Nuclear Information System (INIS)

    The beam energy dependence between 50 and 200 keV of the linear polarization fraction (M/I) of the 2s 1S--3p 1P, 5016 A transition in He I on temperature was measured. The thin carbon exciter foils were heated externally by nichrome resistance elements. The measurements of Hight et al. are duplicated; the energy and current dependences are the same for corresponding between beam heating and external heating. It was also observed that γ, the number of slow secondary electrons produced per incident ion, decreases with increasing foil temperature. These two effects, in conjunction, offer a plausible explanation for the variation of polarization with beam current density. 5 figures

  19. Temperature Dependence of Internal Deformation Field in Zeolites

    Science.gov (United States)

    Cha, Wonsuk; Song, Sanghoon; Jeong, Nak Cheon; Pham, Tung; Harder, Ross; Xiong, Gang; Yoon, Kyung Byung; Robinson, Ian K.; Kim, Hyunjung

    2011-03-01

    We studied temperature dependent internal deformation field distributions in zeolite microcrystals using coherent x-ray diffraction. We measured the coherent x-ray diffraction patterns around (200) and (020) Bragg peaks of the crystals. The three-dimensional real space images were obtained by phasing and inverting the oversampled diffraction patterns using the phase retrieval algorithm combined with error reduction and hybrid input-output method. The internal deformation fields show unusual temperature dependent behaviors which might be originated from the synthesis and calcination process. This work was supported by National Research Foundation of Korea (Nos. 2010-0000112 and R15-2008-006-01001-0), Seoul Research and Business Development Program (10816), and Sogang University Research Grant (2010).

  20. Temperature dependent bacteriophages of a tropical bacterial pathogen

    Science.gov (United States)

    Shan, Jinyu; Korbsrisate, Sunee; Withatanung, Patoo; Adler, Natalie Lazar; Clokie, Martha R. J.; Galyov, Edouard E.

    2014-01-01

    There is an increasing awareness of the multiple ways that bacteriophages (phages) influence bacterial evolution, population dynamics, physiology, and pathogenicity. By studying a novel group of phages infecting a soil borne pathogen, we revealed a paradigm shifting observation that the phages switch their lifestyle according to temperature. We sampled soil from an endemic area of the serious tropical pathogen Burkholderia pseudomallei, and established that podoviruses infecting the pathogen are frequently present in soil, and many of them are naturally occurring variants of a common virus type. Experiments on one phage in the related model B. thailandensis demonstrated that temperature defines the outcome of phage-bacteria interactions. At higher temperatures (37°C), the phage predominantly goes through a lytic cycle, but at lower temperatures (25°C), the phage remains temperate. This is the first report of a naturally occurring phage that follows a lytic or temperate lifestyle according to temperature. These observations fundamentally alter the accepted views on the abundance, population biology and virulence of B. pseudomallei. Furthermore, when taken together with previous studies, our findings suggest that the phenomenon of temperature dependency in phages is widespread. Such phages are likely to have a profound effect on bacterial biology, and on our ability to culture and correctly enumerate viable bacteria. PMID:25452746

  1. Temperature dependent bacteriophages of a tropical bacterial pathogen

    Directory of Open Access Journals (Sweden)

    Martha Rebecca Jane Clokie

    2014-11-01

    Full Text Available There is an increasing awareness of the multiple ways that bacteriophages (phages influence bacterial evolution, population dynamics, physiology and pathogenicity. By studying a novel group of phages infecting a soil borne pathogen, we revealed a paradigm shifting observation that the phages switch their lifestyle according to temperature. We sampled soil from an endemic area of the serious tropical pathogen Burkholderia pseudomallei, and established that podoviruses infecting the pathogen are frequently present in soil, and many of them are naturally occurring variants of a common virus type. Experiments on one phage in the related model Burkholderia thailandensis demonstrated that temperature defines the outcome of phage-bacteria interactions. At higher temperatures (37°C, the phage predominantly goes through a lytic cycle, but at lower temperatures (25°C, the phage remains temperate. This is the first report of a naturally occurring phage that follows a lytic or temperate lifestyle according to temperature. These observations fundamentally alter the accepted views on the abundance, population biology and virulence of B. pseudomallei. Furthermore, when taken together with previous studies, our findings suggest that the phenomenon of temperature dependency in phages is widespread. Such phages are likely to have a profound effect on bacterial life, and on our ability to culture and correctly enumerate viable bacteria.

  2. Temperature-Dependent Conformations of Model Viscosity Index Improvers

    Energy Technology Data Exchange (ETDEWEB)

    Ramasamy, Uma Shantini; Cosimbescu, Lelia; Martini, Ashlie

    2015-05-01

    Lubricants are comprised of base oils and additives where additives are chemicals that are deliberately added to the oil to enhance properties and inhibit degradation of the base oils. Viscosity index (VI) improvers are an important class of additives that reduce the decline of fluid viscosity with temperature [1], enabling optimum lubricant performance over a wider range of operating temperatures. These additives are typically high molecular weight polymers, such as, but not limited to, polyisobutylenes, olefin copolymer, and polyalkylmethacrylates, that are added in concentrations of 2-5% (w/w). Appropriate polymers, when dissolved in base oil, expand from a coiled to an uncoiled state with increasing temperature [2]. The ability of VI additives to increase their molar volume and improve the temperature-viscosity dependence of lubricants suggests there is a strong relationship between molecular structure and additive functionality [3]. In this work, we aim to quantify the changes in polymer size with temperature for four polyisobutylene (PIB) based molecular structures at the nano-scale using molecular simulation tools. As expected, the results show that the polymers adopt more conformations at higher temperatures, and there is a clear indication that the expandability of a polymer is strongly influenced by molecular structure.

  3. Temperature Dependency of Water Vapor Permeability of Shape Memory Polyurethane

    Institute of Scientific and Technical Information of China (English)

    ZENG Yue-min; HU Jin-lian; YAN Hao-jing

    2002-01-01

    Solution-cast films of shape memory polyurethane have beea investigated. Differential scanning calorimetry,DMA, tensile test, water vapor permeability and the shape merry effect were carried out to characterize these polyurethane membranes. Samples cast at higher temperatures contained more hard segment in the crystalline state than a sample cast at lower temperature. The change in the water vapor permeability (WVP) of SMPU films with respect to the temperature follows an S- shaped curve, and increases abruptly at Tm of the soft segment for the fractional free volume (FFV, the ratio of free volume and specific volume in polymers) increased linearly with temperature. The water vapor permeability dependency of the temperature and humidity contribute to the result of the change of diffusion and solubility with the surrounding air condition. The diffusion coefficient (D)are the function of temperature and show good fit the Arrhenius form but show different parameter values when above and below Tg. The crystalline state hardsegment is necessary for the good shape memory effect.

  4. Temperature dependence of the reconstruction of zigzag edges in graphene.

    Science.gov (United States)

    He, Kuang; Robertson, Alex W; Fan, Ye; Allen, Christopher S; Lin, Yung-Chang; Suenaga, Kazu; Kirkland, Angus I; Warner, Jamie H

    2015-05-26

    We examine the temperature dependence of graphene edge terminations at the atomic scale using an in situ heating holder within an aberration-corrected transmission electron microscope. The relative ratios of armchair, zigzag, and reconstructed zigzag edges from over 350 frames at each temperature are measured. Below 400 °C, the edges are dominated by zigzag terminations, but above 600 °C, this changes dramatically, with edges dominated by armchair and reconstructed zigzag edges. We show that at low temperature chemical etching effects dominate and cause deviation to the thermodynamics of the system. At high temperatures (600 and 800 °C), adsorbates are evaporated from the surface of graphene and chemical etching effects are significantly reduced, enabling the thermodynamic distribution of edge types to be observed. The growth rate of holes at high temperature is also shown to be slower than at room temperature, indicative of the reduced chemical etching process. These results provide important insights into the role of chemical etching effects in the hole formation, edge sputtering, and edge reconstruction in graphene.

  5. Temperature dependence of hydrogenated amorphous silicon solar cell performances

    Science.gov (United States)

    Riesen, Y.; Stuckelberger, M.; Haug, F.-J.; Ballif, C.; Wyrsch, N.

    2016-01-01

    Thin-film hydrogenated amorphous silicon solar (a-Si:H) cells are known to have better temperature coefficients than crystalline silicon cells. To investigate whether a-Si:H cells that are optimized for standard conditions (STC) also have the highest energy yield, we measured the temperature and irradiance dependence of the maximum power output (Pmpp), the fill factor (FF), the short-circuit current density (Jsc), and the open-circuit voltage (Voc) for four series of cells fabricated with different deposition conditions. The parameters varied during plasma-enhanced chemical vapor deposition (PE-CVD) were the power and frequency of the PE-CVD generator, the hydrogen-to-silane dilution during deposition of the intrinsic absorber layer (i-layer), and the thicknesses of the a-Si:H i-layer and p-type hydrogenated amorphous silicon carbide layer. The results show that the temperature coefficient of the Voc generally varies linearly with the Voc value. The Jsc increases linearly with temperature mainly due to temperature-induced bandgap reduction and reduced recombination. The FF temperature dependence is not linear and reaches a maximum at temperatures between 15 °C and 80 °C. Numerical simulations show that this behavior is due to a more positive space-charge induced by the photogenerated holes in the p-layer and to a recombination decrease with temperature. Due to the FF(T) behavior, the Pmpp (T) curves also have a maximum, but at a lower temperature. Moreover, for most series, the cells with the highest power output at STC also have the best energy yield. However, the Pmpp (T) curves of two cells with different i-layer thicknesses cross each other in the operating cell temperature range, indicating that the cell with the highest power output could, for instance, have a lower energy yield than the other cell. A simple energy-yield simulation for the light-soaked and annealed states shows that for Neuchâtel (Switzerland) the best cell at STC also has the best energy

  6. Unconventional scaling of the anomalous Hall effect accompanying electron localization correction in the dirty regime

    KAUST Repository

    Lu, Y. M.

    2013-03-05

    Scaling of the anomalous Hall conductivity to longitudinal conductivity σAH∝σ2xx has been observed in the dirty regime of two-dimensional weak and strong localization regions in ultrathin, polycrystalline, chemically disordered, ferromagnetic FePt films. The relationship between electron transport and temperature reveals a quantitatively insignificant Coulomb interaction in these films, while the temperature dependent anomalous Hall conductivity experiences quantum correction from electron localization. At the onset of this correction, the low-temperature anomalous Hall resistivity begins to be saturated when the thickness of the FePt film is reduced, and the corresponding Hall conductivity scaling exponent becomes 2, which is above the recent unified theory of 1.6 (σAH∝σ1.6xx). Our results strongly suggest that the correction of the electron localization modulates the scaling exponent of the anomalous Hall effect.

  7. Temperature dependence of charge transport in conjugated single molecule junctions

    Science.gov (United States)

    Huisman, Eek; Kamenetska, Masha; Venkataraman, Latha

    2011-03-01

    Over the last decade, the break junction technique using a scanning tunneling microscope geometry has proven to be an important tool to understand electron transport through single molecule junctions. Here, we use this technique to probe transport through junctions at temperatures ranging from 5K to 300K. We study three amine-terminated (-NH2) conjugated molecules: a benzene, a biphenyl and a terphenyl derivative. We find that amine groups bind selectively to undercoordinate gold atoms gold all the way down to 5K, yielding single molecule junctions with well-defined conductances. Furthermore, we find that the conductance of a single molecule junction increases with temperature and we present a mechanism for this temperature dependent transport result. Funded by a Rubicon Grant from The Netherlands Organisation for Scientific Research (NWO) and the NSEC program of NSF under grant # CHE-0641523.

  8. Temperature dependence of densities of Sb and Bi melts

    Institute of Scientific and Technical Information of China (English)

    GENG HaoRan; SUN ChunJing; WANG Rui; QI XiaoGang; ZHANG Ning

    2007-01-01

    The densities of Sb and Bi melts were investigated by an improved Archimedean method. The results show that the density of the Sb melt decreases linearly with increasing temperature, but the density of the Bi melt firstly increases and then decreases as the temperature increases. There is a maximum density value of 10.002 g/cm3 at 310℃, about 39℃ above the melting point. The temperature dependence of the Sb melt is well fitted with the expression ρ= 6.8590-5.8105×10-4T, and that of the Bi melt is fitted with ρ=10.3312-1.18×10-3T. The results were discussed from a microstructure viewpoint.

  9. Density of biogas digestate depending on temperature and composition.

    Science.gov (United States)

    Gerber, Mandy; Schneider, Nico

    2015-09-01

    Density is one of the most important physical properties of biogas digestate to ensure an optimal dimensioning and a precise design of biogas plant components like stirring devices, pumps and heat exchangers. In this study the density of biogas digestates with different compositions was measured using pycnometers at ambient pressure in a temperature range from 293.15 to 313.15K. The biogas digestates were taken from semi-continuous experiments, in which the marine microalga Nannochloropsis salina, corn silage and a mixture of both were used as feedstocks. The results show an increase of density with increasing total solid content and a decrease with increasing temperature. Three equations to calculate the density of biogas digestate were set up depending on temperature as well as on the total solid content, organic composition and elemental composition, respectively. All correlations show a relative deviation below 1% compared to experimental data.

  10. Heat experiment design to estimate temperature dependent thermal properties

    International Nuclear Information System (INIS)

    Experimental conditions are studied to optimize transient experiments for estimating temperature dependent thermal conductivity and volumetric heat capacity. A mathematical model of a specimen is the one-dimensional heat equation with boundary conditions of the second kind. Thermal properties are assumed to vary nonlinearly with temperature. Experimental conditions refer to the thermal loading scheme, sampling times and sensor location. A numerical model of experimental configurations is studied to elicit the optimal conditions. The numerical solution of the design problem is formulated on a regularization scheme with a stabilizer minimization without a regularization parameter. An explicit design criterion is used to reveal the optimal sensor location, heating duration and flux magnitude. Results obtained indicate that even the strongly nonlinear experimental design problem admits the aggregation of its solution and has a strictly defined optimal measurement scheme. Additional region of temperature measurements with allowable identification error is revealed.

  11. Temperature dependent electroreflectance study of CdTe solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Raadik, T., E-mail: taavi.raadik@ttu.ee [Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn (Estonia); Krustok, J.; Josepson, R.; Hiie, J. [Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn (Estonia); Potlog, T.; Spalatu, N. [Moldova State University, A. Mateevici str. 60, MD-2009 Chisinau (Moldova, Republic of)

    2013-05-01

    Cadmium telluride is a promising material for large scale photovoltaic applications. In this paper we study CdS/CdTe heterojunction solar cells with electroreflectance spectroscopy. Both CdS and CdTe layers in solar cells were grown sequentially without intermediate processing by the close-space sublimation method. Electroreflectance measurements were performed in the temperature range of T = 100–300 K. Two solar cells were investigated with conversion efficiencies of 4.1% and 9.6%. The main focus in this work was to study the temperature dependent behavior of the broadening parameter and the bandgap energy of CdTe thin film in solar cells. Room temperature bandgap values of CdTe were E{sub g} = 1.499 eV and E{sub g} = 1.481 eV for higher and lower efficiency solar cells, respectively. Measured bandgap energies are lower than for single crystal CdTe. The formation of CdTe{sub 1−x}S{sub x} solid solution layer on the surface of CdTe is proposed as a possible cause of lower bandgap energies. - Highlights: ► Temperature dependent electroreflectance measurements of CdS/CdTe solar cells ► Investigation of junction properties between CdS and CdTe ► Formation of CdTe{sub 1−} {sub x}S{sub x} solid solution layer in the junction area.

  12. Temperature dependent electroreflectance study of CdTe solar cells

    International Nuclear Information System (INIS)

    Cadmium telluride is a promising material for large scale photovoltaic applications. In this paper we study CdS/CdTe heterojunction solar cells with electroreflectance spectroscopy. Both CdS and CdTe layers in solar cells were grown sequentially without intermediate processing by the close-space sublimation method. Electroreflectance measurements were performed in the temperature range of T = 100–300 K. Two solar cells were investigated with conversion efficiencies of 4.1% and 9.6%. The main focus in this work was to study the temperature dependent behavior of the broadening parameter and the bandgap energy of CdTe thin film in solar cells. Room temperature bandgap values of CdTe were Eg = 1.499 eV and Eg = 1.481 eV for higher and lower efficiency solar cells, respectively. Measured bandgap energies are lower than for single crystal CdTe. The formation of CdTe1−xSx solid solution layer on the surface of CdTe is proposed as a possible cause of lower bandgap energies. - Highlights: ► Temperature dependent electroreflectance measurements of CdS/CdTe solar cells ► Investigation of junction properties between CdS and CdTe ► Formation of CdTe1− xSx solid solution layer in the junction area

  13. Speed of light with temperature dependence of the expanding universe

    International Nuclear Information System (INIS)

    Full text: From an extended relativistic dynamics for a particle moving in a cosmic background field with temperature T, we aim to obtain the speed of light with an explicit dependence on the background temperature of the universe. Although finding the speed of light in the early universe much larger than its current value, our approach does not violate the postulate of Special Relativity (SR). Moreover, it is shown that the high value of the speed of light in the early universe was drastically decreased before the beginning of the inflationary period. So we are led to conclude that the theory of Varying Speed of Light (VSL) should be questioned as a possible solution of the horizon problem. It is curious to notice that the speed of light with temperature dependence emerges from Magueijo-Smolin DSR equation when we consider the background thermal energy instead of simply a relativistic energy E of a single particle in their equation. Our approach is within the context of Sciama, Shrodinger and Mach since we are considering the presence of the whole universe, which modifies the energy of the particle by means of a background field with temperature T. (author)

  14. Temperature-Dependent Fission Barriers of Superheavy Nuclei

    CERN Document Server

    Pei, J C; Sheikh-Javid, A; Kerman, A K

    2009-01-01

    The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. We study the temperature-dependent fission barriers by means of the self-consistent nuclear density functional theory. The equivalence of isothermal and isentropic descriptions is demonstrated. The effect of the particle gas is found to be negligible in the range of temperatures studied. Calculations have been carried out for $^{264}$Fm, $^{272}$Ds, $^{278}$112, $^{292}$114, and $^{312}$124. For nuclei around $^{278}$112 produced in "cold fusion" reactions, we predict a more rapid decrease of fission barriers with temperature as compared to the nuclei around $^{292}$114 synthesized in "hot fusion" experiments. This is explained in terms of the difference between the ground-state and fission-barrier temperatures. Our calculations are consistent with the long survival probabilities of the superheavy elements produced in Dubna with th...

  15. Spacetime Dependence of Local Temperature in Relativistic Quantum Field Theory

    CERN Document Server

    Gransee, Michael

    2016-01-01

    The spacetime dependence of the inverse temperature four-vector $\\boldsymbol{\\beta}$ for certain states of the quantized Klein-Gordon field on (parts of) Minkowski spacetime is discussed. These states fulfill a recently proposed version of the Kubo-Martin-Schwinger (KMS) boundary value condition, the so-called "local KMS (LKMS) condition". It turns out that, depending on the mass parameter $m\\geq 0$, any such state can be extended either (i) to a LKMS state on some forward or backward lightcone, with $\\boldsymbol{\\beta}$ depending linearily on spacetime, or (ii) to a thermal equilibrium (KMS) state on all of Minkowski space with constant $\\boldsymbol{\\beta}$. This parallels previously known results for local thermal equilibrium (LTE) states of the quantized Klein-Gordon field. Furthermore, in the case of a massless field our results point to a discrepancy with some classic results in general approaches to (non-quantum) relativistic thermodynamics.

  16. Theoretical description of anomalous properties of novel room temperature multiferroics Pb(Fe1/2Ta1/2)x(Zr0.53Ti0.47)1-xO3 and Pb(Fe1/2Nb1/2)x(Zr0.53Ti0.47)1-xO3

    OpenAIRE

    Glinchuk, Maya D.; Eliseev, Eugene A.; Morozovska, Anna N.

    2015-01-01

    The theoretical description of the anomalous ferroelectric, ferromagnetic and magnetoelectric properties of Pb(Fe1/2Ta1/2)x(Zr0.53Ti0.47)1-xO3 and Pb(Fe1/2Nb1/2)x(Zr0.53Ti0.47)1-xO3 micro-ceramics is given. We performed calculations of temperature, composition and external field dependence of ferroelectric, ferromagnetic and antiferromagnetic phases transition temperatures, remanent polarization, magnetization, hysteresis loops, coercive fields, dielectric permittivity and magnetoelectric cou...

  17. Temperature-dependent emergence of Osmia cornifrons (Hymenoptera: Megachilidae) adults.

    Science.gov (United States)

    White, Joseph; Son, Youngsoo; Park, Yong-Lak

    2009-12-01

    Japanese hornfaced bees Osmia cornifrons (Radoszkowski) (Hymenoptera: Megachilidae) are used for pollination of spring blooming fruit crops such as apple, pear, and blueberry. Because O. cornifrons has a short adult life span, synchronization of bee emergence with bloom is critical to maximize crop pollination. This study was conducted to determine lower temperature thresholds (LTDs), optimum temperatures, and required degree-day accumulation for emergence of O. cornifrons adults. Patterns of temperature-dependent emergence of O. cornifrons adults at seven temperatures (3.9, 12.0, 18.6, 26.6, 30.3, 35.6, and 42.5 degrees C) were modeled and simulated with linear and nonlinear regression analyses. Results of this study showed that required degree-days (DD) for emergence of male and female O. cornifrons adults were 125.2 DD, with LTD of 8.9 degrees C and 179.8 DD, with LTD of 8.6 degrees C, respectively. The optimum temperatures for emergence were 36.5, 30.2, and 35.7 degrees C for male, female, and both sexes combined, respectively. This study indicated that emergence of O. cornifrons adults could be manipulated to synchronize with pollination periods of target fruit crops. PMID:20069827

  18. Anomalous superfluid density in quantum critical superconductors

    Science.gov (United States)

    Hashimoto, Kenichiro; Mizukami, Yuta; Katsumata, Ryo; Shishido, Hiroaki; Yamashita, Minoru; Ikeda, Hiroaki; Matsuda, Yuji; Schlueter, John A.; Fletcher, Jonathan D.; Carrington, Antony; Gnida, Daniel; Kaczorowski, Dariusz; Shibauchi, Takasada

    2013-01-01

    When a second-order magnetic phase transition is tuned to zero temperature by a nonthermal parameter, quantum fluctuations are critically enhanced, often leading to the emergence of unconventional superconductivity. In these “quantum critical” superconductors it has been widely reported that the normal-state properties above the superconducting transition temperature Tc often exhibit anomalous non-Fermi liquid behaviors and enhanced electron correlations. However, the effect of these strong critical fluctuations on the superconducting condensate below Tc is less well established. Here we report measurements of the magnetic penetration depth in heavy-fermion, iron-pnictide, and organic superconductors located close to antiferromagnetic quantum critical points, showing that the superfluid density in these nodal superconductors universally exhibits, unlike the expected T-linear dependence, an anomalous 3/2 power-law temperature dependence over a wide temperature range. We propose that this noninteger power law can be explained if a strong renormalization of effective Fermi velocity due to quantum fluctuations occurs only for momenta k close to the nodes in the superconducting energy gap Δ(k). We suggest that such “nodal criticality” may have an impact on low-energy properties of quantum critical superconductors. PMID:23404698

  19. Temperature dependence of the electrical properties of hydrogen titanate nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Diego C. B.; Brandão, Frederico D.; Krambrock, Klaus; Ferlauto, Andre S. [Departamento de Física, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais 31270-901 (Brazil); Fonseca, Fabio C. [Instituto de Pesquisas Energéticas e Nucleares, IPEN/CNEN-SP, 05508-000 São Paulo (Brazil)

    2014-11-14

    The temperature dependence of the electrical properties of hydrogen-rich titanate nanotubes (H-TNTs) in the 90–270 °C range was investigated by impedance spectroscopy. Three types of dominant conduction were found which depend on the previous thermal treatment of the samples. For untreated samples, at low temperatures (T < 100 °C), electrical conductivity is relatively high (>10{sup −4} S/cm at T ≈ 90 °C) and is dominated by protonic transport within structural water molecules. For thermal annealing in inert atmosphere up to 150 °C, water molecules are released from the nanotube structure resulting in a dehydrated H{sub 2}Ti{sub 3}O{sub 7} phase. Such phase has a low, thermally-dependent, electrical conductivity (10{sup −8} S/cm at T ≈ 90 °C) with activation energy of 0.68 eV. For samples annealed up to 260 °C, loss of OH groups, and consequent generation of oxygen vacancies, occurs that result in the non-stoichiometric H{sub 2(1−z)}Ti{sub 3}O{sub 7−z} phase. This phase has much higher conductivity (10{sup −5} S/cm at T ≈ 90 °C) and lower associated activation energy (0.40 eV). The generation of oxygen vacancies is confirmed by electron paramagnetic resonance measurements at room temperature, which revealed the presence of single-electron-trapped oxygen vacancies. The activation energy value found is consistent with the thermal ionization energy of the oxygen vacancies. Such defect formation represents the initial stage of the phase transformation from titanate to TiO{sub 2} (B). X-ray diffraction and Raman spectroscopy measurements also support such interpretation.

  20. Temperature Dependence of the Particle Diffusion Coefficient in Dust Grains

    Science.gov (United States)

    Pechal, Radim; Richterova, Ivana; Pavlu, Jiri; Safrankova, Jana; Nemecek, Zdenek

    2014-05-01

    During the interaction of ions/neutrals with dust grains, some of the particles are implanted into the grain and, as a consequence, the density gradient induces their diffusion toward the grain surface. Their release can cause a transport of these particles over large distances in space. In our laboratory experiment, measurements of the diffusion coefficient of the particles implanted into the dust grain are carried out in an electrodynamic quadrupole trap. Although experimental setup does not allow an assessment of the dust grain temperature, it can be modified (e.g., by changing thermal radiation from the surrounding walls, laser irradiation, etc.). We present an upgraded laboratory set-up and the resulting temperature dependence of diffusion coefficient estimations and discuss implications for the space dust.

  1. Temperature-dependent potential in cluster-decay process

    Science.gov (United States)

    Gharaei, R.; Zanganeh, V.

    2016-08-01

    Role of the thermal effects of the parent nucleus in the Coulomb barrier and the half-life of 28 cluster-decays is systematically analyzed within the framework of the proximity formalism, namely proximity potential 2010. The WKB approximation is used to determine the penetration probability of the emitted cluster. It is shown that the height and width of the Coulomb barrier in the temperature-dependent proximity potential are less than its temperature-independent version. Moreover, this investigation reveals that the calculated values of half-life for selected cluster-decays are in better agreement with the experimental data when the mentioned effects are imposed on the proximity approach. A discussion is also presented about the predictions of the present thermal approach for cluster-decay half-lives of the super-heavy-elements.

  2. Simulations of the temperature dependence of amide I vibration.

    Science.gov (United States)

    Kaminský, Jakub; Bouř, Petr; Kubelka, Jan

    2011-01-13

    For spectroscopic studies of peptide and protein thermal denaturation it is important to single out the contribution of the solvent to the spectral changes from those originated in the molecular structure. To obtain insights into the origin and size of the temperature solvent effects on the amide I spectra, combined molecular dynamics and density functional simulations were performed with the model N-methylacetamide molecule (NMA). The computations well reproduced frequency and intensity changes previously observed in aqueous NMA solutions. An empirical correction of vacuum frequencies in single NMA molecule based on the electrostatic potential of the water molecules provided superior results to a direct density functional average obtained for a limited number of solute-solvent clusters. The results thus confirm that the all-atom quantum and molecular mechanics approach captures the overall influence of the temperature dependent solvent properties on the amide I spectra and can improve the accuracy and reliability of molecular structural studies.

  3. Localized subcritical convective cells in temperature-dependent viscosity fluids

    Science.gov (United States)

    Solomatov, V. S.

    2012-06-01

    Numerical simulations of infinite Prandtl number convection in the stagnant lid regime of temperature-dependent viscosity convection demonstrate the existence of spatially localized, stable convective cells below the critical Rayleigh number (subcritical convection). These solutions are in stark contrast to the usual, supercritical, convective planforms, where convective cells form in the entire layer. The isolated cell has a shape of an axisymmetric dome with an upwelling at the center and thus appears as a very weak plume. Formation of these structures requires subcritical conditions and a localized initial temperature perturbation but does not require any spatial heterogeneity in the material properties or the heat flux. When several localized plumes form, they tend to attract to each other and form stable clusters. This type of subcritical convection may play a role in the formation and longevity of localized features on planetary bodies, including the crustal dichotomy and Tharsis region on Mars and the asymmetric pattern of volcanism on Mercury.

  4. Temperature Dependent Variations of Phonon Interactions in Nanocrystalline Cerium Oxide

    Directory of Open Access Journals (Sweden)

    Sugandha Dogra Pandey

    2015-01-01

    Full Text Available The temperature dependent anharmonic behavior of the phonon modes of nanocrystalline CeO2 was investigated in the temperature range of 80–440 K. The anharmonic constants have been derived from the shift in phonon modes fitted to account for the anharmonic contributions as well as the thermal expansion contribution using the high pressure parameters derived from our own high pressure experimental data reported previously. The total anharmonicity has also been estimated from the true anharmonicity as well as quasiharmonic component. In the line-width variation analysis, the cubic anharmonic term was found to dominate the quartic term. Finally, the phonon lifetime also reflected the trend so observed.

  5. Temperature dependence of the dielectric constant of acrylic dielectric elastomer

    Energy Technology Data Exchange (ETDEWEB)

    Sheng, Junjie; Chen, Hualing; Li, Bo; Chang, Longfei [Xi' an Jiaotong University, State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi' an (China); Xi' an Jiaotong University, School of Mechanical Engineering, Xi' an (China)

    2013-02-15

    The dielectric constant is an essential electrical parameter to the achievable voltage-induced deformation of the dielectric elastomer. This paper primarily focuses on the temperature dependence of the dielectric constant (within the range of 173 K to 373 K) for the most widely used acrylic dielectric elastomer (VHB 4910). First the dielectric constant was investigated experimentally with the broadband dielectric spectrometer (BDS). Results showed that the dielectric constant first increased with temperature up to a peak value and then dropped to a relative small value. Then by analyzing the fitted curves, the Cole-Cole dispersion equation was found better to characterize the rising process before the peak values than the Debye dispersion equation, while the decrease process afterward can be well described by the simple Debye model. Finally, a mathematical model of dielectric constant of VHB 4910 was obtained from the fitted results which can be used to further probe the electromechanical stability of the dielectric elastomers. (orig.)

  6. Temperature dependence of bulk viscosity in water using acoustic spectroscopy

    CERN Document Server

    Holmes, M J; Povey, M J W

    2010-01-01

    Despite its fundamental role in the dynamics of compressible fluids, bulk viscosity has received little experimental attention and there remains a paucity of measured data. Acoustic spectroscopy provides a robust and accurate approach to measuring this parameter. Working from the Navier-Stokes model of a compressible fluid one can show that the bulk viscosity makes a significant and measurable contribution to the frequency-squared acoustic attenuation. Here we employ this methodology to determine the bulk viscosity of Millipore water over a temperature range of 7 to 50 degrees Celsius. The measured attenuation spectra are consistent with the theoretical predictions, while the bulk viscosity of water is found to be approximately three times larger than its shear counterpart, reinforcing its significance in acoustic propagation. Moreover, our results demonstrate that this technique can be readily and generally applied to fluids to accurately determine their temperature dependent bulk viscosities.

  7. The Dependence of Differential Rotation on Temperature and Rotation

    CERN Document Server

    Barnes, J R; Donati, J F; James, D J; Marsden, S C; Petit, P

    2004-01-01

    We use Doppler imaging techniques to determine the dependence of starspot rotation rates on latitude in an homogeneous sample of young, rapidly-rotating solar analogues. A solar-like differential rotation law is used, where the rotation depends on sin$^2$($\\theta$), where $\\theta$ is the stellar latitude. By including this term in the image reconstruction process, using starspots as tracers, we are able to determine the magnitude of the shear over more than one rotation cycle. We also consider results from matched filter starspot tracking techniques, where individual starspot rotation rates are determined. In addition we have re-analysed published results and present a new measurement for the K3 dwarf, Speedy Mic. A total of 10 stars of spectral type G2 - M2 are considered. We find a trend towards decreasing surface differential rotation with decreasing effective temperature. The implied approach to solid body rotation with increasing relative convection zone depth implies that the dynamo mechanism operating ...

  8. Temperature-dependent photoluminescence of surface-engineered silicon nanocrystals

    Science.gov (United States)

    Mitra, Somak; Švrček, Vladimir; Macias-Montero, Manual; Velusamy, Tamilselvan; Mariotti, Davide

    2016-06-01

    In this work we report on temperature-dependent photoluminescence measurements (15–300 K), which have allowed probing radiative transitions and understanding of the appearance of various transitions. We further demonstrate that transitions associated with oxide in SiNCs show characteristic vibronic peaks that vary with surface characteristics. In particular we study differences and similarities between silicon nanocrystals (SiNCs) derived from porous silicon and SiNCs that were surface-treated using a radio-frequency (RF) microplasma system.

  9. Temperature dependence of the receiver noise temperature and IF bandwidth of superconducting hot electron bolometer mixers

    International Nuclear Information System (INIS)

    In this paper we study the temperature dependence of the receiver noise temperature and IF noise bandwidth of superconducting hot electron bolometer (HEB) mixers. Three superconducting NbN HEB devices of different transition temperatures (Tc) are measured at 0.85 THz and 1.4 THz at different bath temperatures (Tbath) between 4 K and 9 K. Measurement results demonstrate that the receiver noise temperature of superconducting NbN HEB devices is nearly constant for Tbath/Tc, less than 0.8, which is consistent with the simulation based on a distributed hot-spot model. In addition, the IF noise bandwidth appears independent of Tbath/Tc, indicating the dominance of phonon cooling in the investigated HEB devices. (paper)

  10. Phenomenological Spin Transport Theory Driven by Anomalous Nernst Effect

    Science.gov (United States)

    Taniguchi, Tomohiro

    2016-07-01

    Several experimental efforts such as material investigation and structure improvement have been made recently to find a large anomalous Nernst effect in ferromagnetic metals. Here, we develop a theory of spin transport driven by the anomalous Nernst effect in a diffusive ferromagnetic/nonmagnetic multilayer. Starting from a phenomenological formula of a spin-dependent electric current, the theoretical formulas of electric voltage and spin torque generated by the anomalous Nernst effect are derived. The magnitude of the electric voltage generated from the spin current via the inverse spin Hall effect is on the order of 0.1 µV for currently available experimental parameter values. The temperature gradient necessary to switch the magnetization is quite larger than the typical experimental value. The separation of the contributions of the Seebeck and transverse spin Seebeck effects is also discussed.

  11. A Conceptual Model to Link Anomalously High Temperature Gradients in the Cerros del Rio Volcanic Field to Regional Flow in the Espanola Basin, New Mexico

    Science.gov (United States)

    Fillingham, E. J.; Keller, S. N.; McCullough, K. R.; Watters, J.; Weitering, B.; Wilce, A. M.; Folsom, M.; Kelley, S.; Pellerin, L.

    2015-12-01

    Temperature-depth well data along with electromagnetic (EM) data were collected by students of the Summer of Applied Geophysics Experience (SAGE) 2015 field season in the Espanola Basin, New Mexico. The data from this year, in addition to data acquired since 2013, were used to construct a conceptual east-west cross-section of the Espanola Basin and the adjacent highlands in order to evaluate the regional flow system. Vertical geothermal gradients from several monitoring wells were measured using a thermistor. Anomalously warm geothermal gradients were mapped in the Cerros del Rio volcanic field in the basin just east of the Rio Grande. Temperature gradients are up to 70℃/km, while the background geothermal gradients in the Rio Grande rift zone generally show 28℃-35℃/km. This anomaly extends to the Buckman well field, which supplies water to the city of Santa Fe. Overpumping of this well field has led to subsidence in the past. However, discharge temperature plots indicate that the temperature gradients of the Buckman field may be rebounding as pumping is reduced. Audiomagnetotelluric (AMT) and transient electromagnetic (TEM) data were acquired in the vicinity of three monitoring wells. TEM and AMT methods complement each other with the former having depths of investigation of less than ten to hundreds of meters and AMT having depths of investigation comparable to the wells deeper than 500m. These datasets were used collectively to image the subsurface stratigraphy and, more specifically, the hydrogeology related to shallow aquifers. The EM data collected at these wells showed a trend indicating a shallow aquifer with a shallower resistive layer of approximately 100 ohm-m at 70-100 meters depth. Beneath this resistive layer we resolved a more conductive, clay-rich layer of 10 ohm-m. These resistivity profiles compliment the electrical logs provided by Jet West, which indicate shallower sandstone interbedded with silt on top of more silt-dominant layers. Our

  12. Anomalous Hall effect in Fe/Gd bilayers

    KAUST Repository

    Xu, W. J.

    2010-04-01

    Non-monotonic dependence of anomalous Hall resistivity on temperature and magnetization, including a sign change, was observed in Fe/Gd bilayers. To understand the intriguing observations, we fabricated the Fe/Gd bilayers and single layers of Fe and Gd simultaneously. The temperature and field dependences of longitudinal resistivity, Hall resistivity and magnetization in these films have also been carefully measured. The analysis of these data reveals that these intriguing features are due to the opposite signs of Hall resistivity/or spin polarization and different Curie temperatures of Fe and Gd single-layer films. Copyright (C) EPLA, 2010

  13. Anomalous behavior of the pressure dependence of lattice constants in Tl sub 2 Ba sub 2 CuO sub 6+x

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, H. (Materials Science Div., Argonne National Lab., IL (United States) Inst. for Solid State Physics, Univ. of Tokyo (Japan)); Jorgensen, J.D.; Hitterman, R.L. (Materials Science Div., Argonne National Lab., IL (United States)); Hunter, B.A.; Pei Shiyou (Science and Tech. Center for Superconductivity, Argonne National Lab., IL (United States)); Izumi, F. (National Inst. for Research in Inorganic Materials, Ibaraki (Japan)); Shimakawa, Y.; Kubo, Y.; Manako, T. (Fundamental Research Labs., NEC Corporation, Ibaraki (Japan))

    1992-02-01

    The crystal structure of Tl{sub 2}Ba{sub 2}CuO{sub 6+x} has been investigated as a function of pressure and temperature under hydrostatic conditions using neutron powder diffraction. The crystal structure at 0.609 GPa and 60 K depends systematically on the path in pressure-temperature space by which these conditions are achieved. Applying pressure at room temperature and then cooling produces different changes in the structure than cooling first and then applying pressure. Our results support those of Sieburger and Schilling who reported that the Tc at high pressure for this compound depends markedly on whether the sample is pressurized at room temperature or low temperature. We speculate that this unusual behavior may be associated with differences in the mobility of interstitial oxygen defects between room temperature and 60 K and that applying pressure at room temperature changes the state of the sample through such processes as defect ordering, while changing the pressure at low temperature does not. (orig.).

  14. Temperature dependent transport characteristics of graphene/n-Si diodes

    International Nuclear Information System (INIS)

    Realizing an optimal Schottky interface of graphene on Si is challenging, as the electrical transport strongly depends on the graphene quality and the fabrication processes. Such interfaces are of increasing research interest for integration in diverse electronic devices as they are thermally and chemically stable in all environments, unlike standard metal/semiconductor interfaces. We fabricate such interfaces with n-type Si at ambient conditions and find their electrical characteristics to be highly rectifying, with minimal reverse leakage current (<10−10 A) and rectification of more than 106. We extract Schottky barrier height of 0.69 eV for the exfoliated graphene and 0.83 eV for the CVD graphene devices at room temperature. The temperature dependent electrical characteristics suggest the influence of inhomogeneities at the graphene/n-Si interface. A quantitative analysis of the inhomogeneity in Schottky barrier heights is presented using the potential fluctuation model proposed by Werner and Güttler

  15. Interpretation of the temperature dependence of equilibrium and rate constants.

    Science.gov (United States)

    Winzor, Donald J; Jackson, Craig M

    2006-01-01

    The objective of this review is to draw attention to potential pitfalls in attempts to glean mechanistic information from the magnitudes of standard enthalpies and entropies derived from the temperature dependence of equilibrium and rate constants for protein interactions. Problems arise because the minimalist model that suffices to describe the energy differences between initial and final states usually comprises a set of linked equilibria, each of which is characterized by its own energetics. For example, because the overall standard enthalpy is a composite of those individual values, a positive magnitude for DeltaH(o) can still arise despite all reactions within the subset being characterized by negative enthalpy changes: designation of the reaction as being entropy driven is thus equivocal. An experimenter must always bear in mind the fact that any mechanistic interpretation of the magnitudes of thermodynamic parameters refers to the reaction model rather than the experimental system. For the same reason there is little point in subjecting the temperature dependence of rate constants for protein interactions to transition-state analysis. If comparisons with reported values of standard enthalpy and entropy of activation are needed, they are readily calculated from the empirical Arrhenius parameters. PMID:16897812

  16. Dependence of friction on roughness, velocity, and temperature

    Science.gov (United States)

    Sang, Yi; Dubé, Martin; Grant, Martin

    2008-03-01

    We study the dependence of friction on surface roughness, sliding velocity, and temperature. Expanding on the classic treatment of Greenwood and Williamson, we show that the fractal nature of a surface has little influence on the real area of contact and the static friction coefficient. A simple scaling argument shows that the static friction exhibits a weak anomaly μ˜A0-χ/4 , where A0 is the apparent area and χ is the roughness exponent of the surface. We then develop a method to calculate atomic-scale friction between a microscopic asperity, such as the tip of a friction force microscope (FFM) and a solid substrate. This method, based on the thermal activation of the FFM tip, allows a quantitative extraction of all the relevant microscopic parameters and reveals a universal scaling behavior of atomic friction on velocity and temperature. This method is extended to include a soft atomic substrate in order to simulate FFM scans more realistically. The tip is connected with the support of the cantilever by an ideal spring and the substrate is simulated with a ball-spring model. The tip and substrate are coupled with repulsive potentials. Simulations are done at different temperatures and scanning velocities on substrates with different elastic moduli. Stick-slip motion of the tip is observed, and the numerical results of the friction force and distribution of force maxima match the theoretical framework.

  17. Nonlocal Anomalous Hall Effect

    Science.gov (United States)

    Zhang, Steven S.-L.; Vignale, Giovanni

    2016-04-01

    The anomalous Hall (AH) effect is deemed to be a unique transport property of ferromagnetic metals, caused by the concerted action of spin polarization and spin-orbit coupling. Nevertheless, recent experiments have shown that the effect also occurs in a nonmagnetic metal (Pt) in contact with a magnetic insulator [yttrium iron garnet (YIG)], even when precautions are taken to ensure that there is no induced magnetization in the metal. We propose a theory of this effect based on the combined action of spin-dependent scattering from the magnetic interface and the spin-Hall effect in the bulk of the metal. At variance with previous theories, we predict the effect to be of first order in the spin-orbit coupling, just as the conventional anomalous Hall effect—the only difference being the spatial separation of the spin-orbit interaction and the magnetization. For this reason we name this effect the nonlocal anomalous Hall effect and predict that its sign will be determined by the sign of the spin-Hall angle in the metal. The AH conductivity that we calculate from our theory is in order of magnitude agreement with the measured values in Pt /YIG structures.

  18. Nonlocal Anomalous Hall Effect.

    Science.gov (United States)

    Zhang, Steven S-L; Vignale, Giovanni

    2016-04-01

    The anomalous Hall (AH) effect is deemed to be a unique transport property of ferromagnetic metals, caused by the concerted action of spin polarization and spin-orbit coupling. Nevertheless, recent experiments have shown that the effect also occurs in a nonmagnetic metal (Pt) in contact with a magnetic insulator [yttrium iron garnet (YIG)], even when precautions are taken to ensure that there is no induced magnetization in the metal. We propose a theory of this effect based on the combined action of spin-dependent scattering from the magnetic interface and the spin-Hall effect in the bulk of the metal. At variance with previous theories, we predict the effect to be of first order in the spin-orbit coupling, just as the conventional anomalous Hall effect-the only difference being the spatial separation of the spin-orbit interaction and the magnetization. For this reason we name this effect the nonlocal anomalous Hall effect and predict that its sign will be determined by the sign of the spin-Hall angle in the metal. The AH conductivity that we calculate from our theory is in order of magnitude agreement with the measured values in Pt/YIG structures.

  19. Variable Responses of Benthic Communities to Anomalously Warm Sea Temperatures on a High-Latitude Coral Reef

    OpenAIRE

    Bridge, Tom C.L.; Renata Ferrari; Mitch Bryson; Renae Hovey; Figueira, Will F.; Stefan B Williams; Oscar Pizarro; Harborne, Alastair R.; Maria Byrne

    2014-01-01

    High-latitude reefs support unique ecological communities occurring at the biogeographic boundaries between tropical and temperate marine ecosystems. Due to their lower ambient temperatures, they are regarded as potential refugia for tropical species shifting poleward due to rising sea temperatures. However, acute warming events can cause rapid shifts in the composition of high-latitude reef communities, including range contractions of temperate macroalgae and bleaching-induced mortality in c...

  20. Strain rate and temperature dependent mechanical behavior of nanocrystalline gold

    Science.gov (United States)

    Karanjgaokar, Nikhil J.

    Nanocrystalline metal films are candidate materials for microelectronics and Microelectromechanical Systems (MEMS). The long term mechanical stability of metal films requires quantitative understanding of their thermo-mechanical behavior in the large range of operating strain rates and temperatures. This dissertation research studied (a) the role of thermally activated processes based on the strain rate and temperature dependent mechanical behavior of nanocrystalline Au thin films, and (b) deformation processes at nominally elastic loads that lead to creep strain over a moderate temperature range that is relevant to MEMS applications. The rate dependent mechanical behavior of nanocrystalline Au thin films was first investigated at room temperature ~ 25 °C and at strain rates between 10-6 to 20 s-1. The use of digital image correlation (DIC) facilitated repeatable and accurate measurements of fullfield strain from free-standing nanocrystalline Au thin films. The experimental stress-strain curves were used to calculate activation volumes for two film thicknesses (0.85 mum, and 1.75 mum), which were 4.5b3 and 8.1b3, at strain rates smaller than 10-4 s-1 and 12.5b3 and 14.6b3 at strain rates higher than 10-4 s-1. The reduced activation volume and increased strain rate sensitivity at slow strain rates were attributed to grain boundary (GB) diffusional processes that result in creep strain. The room temperature strain rate results were augmented with microscale strain rate experiments at temperatures up to 110 °C. Two methods for heating free-standing microscale thin film specimens, namely uniform heating using a custom-built microheater and resistive (Joule) heating, were evaluated using a combination of full-field strain measurements by optical microscopy and full-field temperature measurements by infrared (IR) thermal imaging. It was shown for the first time that the Joule specimen heating method results in large underestimation of the inelastic material properties

  1. Temperature Dependence of Lattice Dynamics of Lithium 7

    DEFF Research Database (Denmark)

    Beg, M. M.; Nielsen, Mourits

    1976-01-01

    parameter is found to be 3.490 ± 0.003 Å at 110 K and 3.537 ± 0.003 Å at 424 K. The elastic constants obtained at 293 K from the model parameters are (1011 dyn/cm2) C11=1.73±0.10, C12=1.31±0.20, and C44=0.84±0.060. The temperature dependence of elastic constants is also determined.......Phonon dispersion relations in 7Li have been measured by the coherent inelastic neutron scattering at 293 and 110 K. The frequency distributions are obtained from the experimental data using the Born-von Kármán general force model. The first-neighbor force constants at 293 K are found to be about...

  2. Time-dependent radiolytic yields at room temperature and temperature-dependent absorption spectra of the solvated electrons in polyols

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900, 970, and 1000 mol-1·m2 for 1,2-ethanediol (12ED), 1,2-propanediol (12PD), and 1,3-propanediol (13PD), respectively. These values are two-third or three-fourth of the value usually reported in the published report.Picosecond pulse radiolysis studies have aided in depicting the radiolytic yield of the solvated electron in these solvents as a function of time from picosecond to microsecond. The radiolytic yield in these viscous solvents is found to be strongly different from that of the water solution. The temperature dependent absorption spectra of the solvated electron in 12ED, 12PD, and 13PD have been also investigated. In all the three solvents, the optical spectra shift to the red with increasing temperature. While the shape of the spectra does not change in 13PD, a widening on the blue side of the absorption band is observed in 12ED and 12PD at elevated temperatures.

  3. Temperature dependence of the electronic structure of semiconductors and insulators

    Energy Technology Data Exchange (ETDEWEB)

    Poncé, S., E-mail: samuel.pon@gmail.com; Gillet, Y.; Laflamme Janssen, J.; Gonze, X. [European Theoretical Spectroscopy Facility and Institute of Condensed Matter and Nanosciences, Université catholique de Louvain, Chemin des étoiles 8, bte L07.03.01, B-1348 Louvain-la-neuve (Belgium); Marini, A. [Consiglio Nazionale delle Ricerche (CNR), Via Salaria Km 29.3, CP 10, 00016 Monterotondo Stazione (Italy); Verstraete, M. [European Theoretical Spectroscopy Facility and Physique des matériaux et nanostructures, Université de Liège, Allée du 6 Août 17, B-4000 Liège (Belgium)

    2015-09-14

    The renormalization of electronic eigenenergies due to electron-phonon coupling (temperature dependence and zero-point motion effect) is sizable in many materials with light atoms. This effect, often neglected in ab initio calculations, can be computed using the perturbation-based Allen-Heine-Cardona theory in the adiabatic or non-adiabatic harmonic approximation. After a short description of the recent progresses in this field and a brief overview of the theory, we focus on the issue of phonon wavevector sampling convergence, until now poorly understood. Indeed, the renormalization is obtained numerically through a slowly converging q-point integration. For non-zero Born effective charges, we show that a divergence appears in the electron-phonon matrix elements at q → Γ, leading to a divergence of the adiabatic renormalization at band extrema. This problem is exacerbated by the slow convergence of Born effective charges with electronic wavevector sampling, which leaves residual Born effective charges in ab initio calculations on materials that are physically devoid of such charges. Here, we propose a solution that improves this convergence. However, for materials where Born effective charges are physically non-zero, the divergence of the renormalization indicates a breakdown of the adiabatic harmonic approximation, which we assess here by switching to the non-adiabatic harmonic approximation. Also, we study the convergence behavior of the renormalization and develop reliable extrapolation schemes to obtain the converged results. Finally, the adiabatic and non-adiabatic theories, with corrections for the slow Born effective charge convergence problem (and the associated divergence) are applied to the study of five semiconductors and insulators: α-AlN, β-AlN, BN, diamond, and silicon. For these five materials, we present the zero-point renormalization, temperature dependence, phonon-induced lifetime broadening, and the renormalized electronic band structure.

  4. Temperature dependence of the electronic structure of semiconductors and insulators.

    Science.gov (United States)

    Poncé, S; Gillet, Y; Laflamme Janssen, J; Marini, A; Verstraete, M; Gonze, X

    2015-09-14

    The renormalization of electronic eigenenergies due to electron-phonon coupling (temperature dependence and zero-point motion effect) is sizable in many materials with light atoms. This effect, often neglected in ab initio calculations, can be computed using the perturbation-based Allen-Heine-Cardona theory in the adiabatic or non-adiabatic harmonic approximation. After a short description of the recent progresses in this field and a brief overview of the theory, we focus on the issue of phonon wavevector sampling convergence, until now poorly understood. Indeed, the renormalization is obtained numerically through a slowly converging q-point integration. For non-zero Born effective charges, we show that a divergence appears in the electron-phonon matrix elements at q → Γ, leading to a divergence of the adiabatic renormalization at band extrema. This problem is exacerbated by the slow convergence of Born effective charges with electronic wavevector sampling, which leaves residual Born effective charges in ab initio calculations on materials that are physically devoid of such charges. Here, we propose a solution that improves this convergence. However, for materials where Born effective charges are physically non-zero, the divergence of the renormalization indicates a breakdown of the adiabatic harmonic approximation, which we assess here by switching to the non-adiabatic harmonic approximation. Also, we study the convergence behavior of the renormalization and develop reliable extrapolation schemes to obtain the converged results. Finally, the adiabatic and non-adiabatic theories, with corrections for the slow Born effective charge convergence problem (and the associated divergence) are applied to the study of five semiconductors and insulators: α-AlN, β-AlN, BN, diamond, and silicon. For these five materials, we present the zero-point renormalization, temperature dependence, phonon-induced lifetime broadening, and the renormalized electronic band structure

  5. The anomalous low and high temperatures of 2012 over Greece: an explanation from a meteorological and climatological perspective

    Science.gov (United States)

    Tolika, K.; Maheras, P.; Pytharoulis, I.; Anagnostopoulou, C.

    2013-09-01

    The year of 2012 is characterized, for Greece, as the hottest one in the available record dating back to 1958, presenting also the widest annual temperature range. During the summer and autumn months, numerous regions in the domain of study experienced record-breaking maximum and minimum temperatures. Conversely, the winter period was particularly cold and January was one of the coldest months in the last 55 yr. The analysis of the cold period indicates that the synoptic conditions resemble the positive phase of the Eastern Mediterranean Pattern (EMP). The predominance of these cool conditions seems to be primarily related to an intense NNW or NNE atmospheric circulation, as a consequence of the positive EMP phase. Moreover, the reduction of the floating sea ice emerged as a key driver to the formation of a low pressure pattern and the reinforcement of the trough south of Scandinavia, which in turn strengthened the Siberia High east of the trough. This reinforcement resulted in a blocking pattern and in the favorable conditions for the EMP formation The atmospheric circulation during the prolonged high-temperature period resembles, respectively, the negative phase of North Sea-Caspian Pattern teleconnection. The observed positive pole, in conjunction with the strong southwestern circulation, results in temperature increases and in the development of a smooth pressure field that contributes to the weakening of the Etesian winds and therefore to calm conditions over the continental areas.

  6. The anomalous low and high temperatures of 2012 over Greece - an explanation from a meteorological and climatological perspective

    Science.gov (United States)

    Tolika, K.; Maheras, P.; Pytharoulis, I.; Anagnostopoulou, C.

    2014-03-01

    2012 was the hottest year in Greece on the basis of the available record dating back to 1958, displaying at the same time the widest annual temperature range. During the summer and autumn months, numerous regions in the domain of study experienced record-breaking maximum and minimum temperatures. Conversely, the winter period was particularly cold and January one of the coldest months over the last 55 yr. The analysis of the cold period indicates that the synoptic conditions resemble the positive phase of the Eastern Mediterranean Pattern (EMP). The predominance of these cool conditions seems to be related primarily to an intense NNW or NNE atmospheric circulation, as a consequence of the positive EMP phase. Moreover, the reduction in the floating sea ice emerges as a key driver of the formation of a low-pressure pattern and the reinforcement of the trough south of Scandinavia, which in turn strengthened the Siberia High east of the trough. This reinforcement resulted in a blocking pattern and in favorable conditions for the EMP formation. The atmospheric circulation during the prolonged high-temperature period resembles, respectively, the negative phase of North Sea-Caspian Pattern teleconnection. The observed positive pole, in conjunction with the strong southwestern circulation, results in temperature increases and in the development of a smooth pressure field that contributes to the weakening of the Etesian winds and therefore to calm conditions over the continental areas.

  7. Anomalous Hall effect in localization regime

    Science.gov (United States)

    Wu, Lin; Zhu, Kai; Yue, Di; Tian, Yuan; Jin, Xiaofeng

    2016-06-01

    The anomalous Hall effect in the ultrathin film regime is investigated in Fe(001)(1-3 nm) films epitaxial on MgO(001). The logarithmic localization correction to longitudinal resistivity and anomalous Hall resistivity are observed at low temperature. We identify that the coefficient of skew scattering has a reduction from metallic to localized regime, while the contribution of side jump has inconspicuous change except for a small drop below 10 K. Furthermore, we discover that the intrinsic anomalous Hall conductivity decreases with the reduction of thickness below 2 nm. Our results provide unambiguous experimental evidence to clarify the problem of localization correction to the anomalous Hall effect.

  8. Influenza virus transmission is dependent on relative humidity and temperature.

    Directory of Open Access Journals (Sweden)

    Anice C Lowen

    2007-10-01

    Full Text Available Using the guinea pig as a model host, we show that aerosol spread of influenza virus is dependent upon both ambient relative humidity and temperature. Twenty experiments performed at relative humidities from 20% to 80% and 5 degrees C, 20 degrees C, or 30 degrees C indicated that both cold and dry conditions favor transmission. The relationship between transmission via aerosols and relative humidity at 20 degrees C is similar to that previously reported for the stability of influenza viruses (except at high relative humidity, 80%, implying that the effects of humidity act largely at the level of the virus particle. For infected guinea pigs housed at 5 degrees C, the duration of peak shedding was approximately 40 h longer than that of animals housed at 20 degrees C; this increased shedding likely accounts for the enhanced transmission seen at 5 degrees C. To investigate the mechanism permitting prolonged viral growth, expression levels in the upper respiratory tract of several innate immune mediators were determined. Innate responses proved to be comparable between animals housed at 5 degrees C and 20 degrees C, suggesting that cold temperature (5 degrees C does not impair the innate immune response in this system. Although the seasonal epidemiology of influenza is well characterized, the underlying reasons for predominant wintertime spread are not clear. We provide direct, experimental evidence to support the role of weather conditions in the dynamics of influenza and thereby address a long-standing question fundamental to the understanding of influenza epidemiology and evolution.

  9. Temperature Dependence of Growth Mechanism for Nanoscale High Tc Superconductors

    Institute of Scientific and Technical Information of China (English)

    Wu-Ming Chen; Mustafa Yavuz; Jian-Xun Jin

    2008-01-01

    The growth mechanisms of high temper- ature Yttrium- and Bismuth-based-superconductors were investigated at nanoscale. We started with studying the growth relationships among the three phases of Bi-2201, Bi-2212, and Bi-2233, and then extended to another growth mechanism of Bi-2223 and the growth of yttrium-based high-temperature nanosupercon- ductors (nano-YBCO). A time dependence of growth experiment was performed. In this experiment, the Bi-based superconductors grew within different sintering periods, and its three phases were determined by X-ray diffraction. And then, a time dependence of growth model was suggested to explain the experimental facts. With this model, governing equations were derived to quantitatively describe the growth and decomposition mechanisms during sintering period. The results calculated from the derived equations were well in agreement with the experimental data. We also suggested an alternative growth mechanism for the Bi-2223 phase, which was supported by an observation of transmission electron microscopy (TEM). The nano-YBCO also grew, and their orthorhombic crystal structures were determined by the TEM. The superconducting properties of Bi-2223 were investigated by the measurements of ac magnetic susceptibility. It is expected that the derived equations will fit the alter- native experimental growth mechanism of the Bi-2223 phase and the nano-YBCO growth mechanism, too.

  10. Anomalous Hall effect in polycrystalline Ni films

    KAUST Repository

    Guo, Zaibing

    2012-02-01

    We systematically studied the anomalous Hall effect in a series of polycrystalline Ni films with thickness ranging from 4 to 200 nm. It is found that both the longitudinal and anomalous Hall resistivity increased greatly as film thickness decreased. This enhancement should be related to the surface scattering. In the ultrathin films (46 nm thick), weak localization corrections to anomalous Hall conductivity were studied. The granular model, taking into account the dominated intergranular tunneling, has been employed to explain this phenomenon, which can explain the weak dependence of anomalous Hall resistivity on longitudinal resistivity as well. © 2011 Elsevier Ltd. All rights reserved.

  11. Anomalous Freezing of Nano-Confined Water in Room-Temperature Ionic Liquid 1-Butyl-3-Methylimidazolium Nitrate.

    Science.gov (United States)

    Abe, Hiroshi; Takekiyo, Takahiro; Yoshimura, Yukihiro; Saihara, Koji; Shimizu, Akio

    2016-04-18

    Non-crystal formation of ice is investigated by simultaneous X-ray diffraction and differential scanning calorimetry measurements upon cooling to -100 °C. At room temperature, size-tunable water confinement (≈20 Å size) in a room-temperature ionic liquid (RTIL, 1-butyl-3-methylimidazolium nitrate, [C4 mim][NO3 ]) exists in a water-rich region (70-90 mol % D2 O). The confined water (water pocket) is characterized by almost monodispersive size distribution. In [C4 mim][NO3 ]-x mol % D2 O (70Bragg reflections and a distinct exothermal peak indicate that crystallization/cold crystallization both of [C4 mim][NO3 ] and D2 O is suppressed, even upon slow cooling and heating. PMID:26841088

  12. Inclusion of temperature dependent shell corrections in Landau theory for hot rotating nuclei

    Indian Academy of Sciences (India)

    G Shanmugam; P Arumugam

    2001-07-01

    Landau theory used for studying hot rotating nuclei usually uses zero temperature Strutinsky smoothed total energy for the temperature dependent shell corrections. This is replaced in this work by the temperature dependent Strutinsky smoothed free energy. Our results show that this replacement has only marginal effect for temperatures greater than 1 MeV but plays significant role at lower temperatures.

  13. Temperature dependence of the deformation behavior of 316 stainless steel after low temperature neutron irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Pawel-Robertson, J.E.; Rowcliffe, A.F.; Grossbeck, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1996-10-01

    The effects of low temperature neutron irradiation on the tensile behavior of 316 stainless steel have been investigated. A single heat of solution annealed 316 was irradiated to 7 and 18 dpa at 60, 200, 330, and 400{degrees}C. The tensile properties as a function of dose and as a function of temperature were examined. Large changes in yield strength, deformation mode, strain to necking, and strain hardening capacity were seen in this irradiation experiment. The magnitudes of the changes are dependent on both irradiation temperature and neutron dose. Irradiation can more than triple the yield strength over the unirradiated value and decrease the strain to necking (STN) to less than 0.5% under certain conditions. A maximum increase in yield strength and a minimum in the STN occur after irradiation at 330{degrees}C but the failure mode remains ductile.

  14. Anomalous magnetoresistance in NiMnGa thin films

    Science.gov (United States)

    Golub, Vladimir O.; Vovk, Andriy Ya.; Malkinski, Leszek; O'Connor, Charles J.; Wang, Zhenjun; Tang, Jinke

    2004-10-01

    The origin of anomalous negative magnetoresistance and its temperature dependence in polycrystalline Ni -Mn-Ga films prepared by pulse laser deposition was studied. The investigation of structural, transports, magnetic, and ferromagnetic resonance properties of the films suggests contributions of different mechanisms in magnetotransport. At low magnetic fields the main contribution to magnetoresistance is due to the transport between the areas with different orientation of magnetic moments, while at high fields it is an electron scattering of in spin-disordered areas.

  15. Gain Flattening Filter Canceling Temperature Dependence of EDFA s gain

    Institute of Scientific and Technical Information of China (English)

    M.; Ohmura; Y.; Ishizawa; H.; Nakaji; K.; Hashimoto; T.; Shibata; M.; Shigehara; A.; Inoue

    2003-01-01

    We have developed a gain flattening filter (GFF) for an erbium doped fiber (EDF) without temperature control systems. This GFF, which consists of temperature-sensitive long period gratings (LPGs) and a temperature compensated slanted fiber Bragg grating (SFBG), follows the gain shift of EDF with temperature. Gain variation of the EDFA less than 0.25dBp-p was achieved with the bandwidth of 37nm, and the temperature range 0-65℃ without any temperature control systems.

  16. Observation of Anomalous Properties associated with the Low Temperature Structural Distortion in β-FeSe and Related Superconductorsa

    Directory of Open Access Journals (Sweden)

    Wu M. K.

    2012-03-01

    Full Text Available The discovery of Superconductivity in the tetragonal phase FeSe provides a unique platform for the detailed investigation of the correlation between the physical properties and crystal structure to better understand the possible origin of superconductivity in the new iron-based superconductors. We have carried out a series of properties characterizations by measuring magnetic susceptibility, Raman, NMR and femtosecond spectroscopy on single crystals and epitaxial thin films of the FeSe and Te-doped Fe(SeTe samples. Our results show clearly the presence of anomalies in all the characterized properties at the temperature where a structural distortion from tetragonal to orthorhombic (or monoclinic appears for all superconducting samples, but not in the non-superconducting ones. This structural distortion was observed not accompanied by a magnetic ordering as commonly occurs in the parent compounds of FeAs-based superconductors. All the observations suggest that the low temperature structural distortion is essential for the occurrence of superconductivity in the FeSe and related compounds. Details of the experimental results will be presented and discussed.

  17. Temperature dependence of the thermal conductivity in chiral carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Mensah, N.G. [Department of Mathematics, University of Cape Coast, Cape Coast (Ghana); Abdus Salam International Centre for Theoretical Physics, Trieste (Italy); Nkrumah, G. [Department of Physics, University of Ghana, Legon, Accra (Ghana) and Abdus Salam International Centre for Theoretical Physics, Trieste (Italy)]. E-mail: geon@ug.edu.gh; Mensah, S.Y. [Department of Physics, Laser and Fibre Optics Centre, University of Cape Coast, Cape Coast (Ghana); Allotey, F.K.A. [Institute of Mathematical Sciences, Accra (Ghana)

    2004-08-30

    The thermal conductivity of a chiral carbon nanotube (CCNT) is calculated using a tractable analytical approach. This is based on solving the Boltzmann kinetic equation with energy dispersion relation obtained in the tight binding approximation. The results obtained are numerically analysed. Unusually high electron thermal conductivity {chi}{sub ez} is observed along the tubular axis. The dependence of {chi}{sub ez} against temperature T was plotted for varying {delta}{sub z} and a given {delta}{sub s} ({delta}{sub z} and {delta}{sub s} are the overlapping integrals (exchange energy) for the jumps along the tubular axis and the base helix, respectively). It is noted that {chi}{sub ez} shows a peaking behaviour before falling off at higher temperature. As {delta}{sub z} varies from 0.010 eV to 0.048 eV for a given {delta}{sub s}=0.0150 eV, the peak values of {chi}{sub ez} shift from 40000 W/m K at 100 K to 55000 W/m K at about 300 K. Interestingly our results at 104 K which is 41000 W/m K and occurred at {delta}{sub z}=0.023 eV compares very well with that reported for a 99.9% isotopically enriched {sup 12}C diamond crystal. Another interesting result obtained is the fact that the circumferential electron thermal conductivity {chi}{sub ec} appears to be very small. The ratio of {chi}{sub ez} to {chi}{sub ec} is of the order of 2.

  18. Variable responses of benthic communities to anomalously warm sea temperatures on a high-latitude coral reef.

    Directory of Open Access Journals (Sweden)

    Tom C L Bridge

    Full Text Available High-latitude reefs support unique ecological communities occurring at the biogeographic boundaries between tropical and temperate marine ecosystems. Due to their lower ambient temperatures, they are regarded as potential refugia for tropical species shifting poleward due to rising sea temperatures. However, acute warming events can cause rapid shifts in the composition of high-latitude reef communities, including range contractions of temperate macroalgae and bleaching-induced mortality in corals. While bleaching has been reported on numerous high-latitude reefs, post-bleaching trajectories of benthic communities are poorly described. Consequently, the longer-term effects of thermal anomalies on high-latitude reefs are difficult to predict. Here, we use an autonomous underwater vehicle to conduct repeated surveys of three 625 m(2 plots on a coral-dominated high-latitude reef in the Houtman Abrolhos Islands, Western Australia, over a four-year period spanning a large-magnitude thermal anomaly. Quantification of benthic communities revealed high coral cover (>70%, comprising three main morphospecies prior to the bleaching event. Plating Montipora was most susceptible to bleaching, but in the plot where it was most abundant, coral cover did not change significantly because of post-bleaching increases in branching Acropora. In the other two plots, coral cover decreased while macroalgal cover increased markedly. Overall, coral cover declined from 73% to 59% over the course of the study, while macroalgal cover increased from 11% to 24%. The significant differences in impacts and post-bleaching trajectories among plots underline the importance of understanding the underlying causes of such variation to improve predictions of how climate change will affect reefs, especially at high-latitudes.

  19. Variable responses of benthic communities to anomalously warm sea temperatures on a high-latitude coral reef.

    Science.gov (United States)

    Bridge, Tom C L; Ferrari, Renata; Bryson, Mitch; Hovey, Renae; Figueira, Will F; Williams, Stefan B; Pizarro, Oscar; Harborne, Alastair R; Byrne, Maria

    2014-01-01

    High-latitude reefs support unique ecological communities occurring at the biogeographic boundaries between tropical and temperate marine ecosystems. Due to their lower ambient temperatures, they are regarded as potential refugia for tropical species shifting poleward due to rising sea temperatures. However, acute warming events can cause rapid shifts in the composition of high-latitude reef communities, including range contractions of temperate macroalgae and bleaching-induced mortality in corals. While bleaching has been reported on numerous high-latitude reefs, post-bleaching trajectories of benthic communities are poorly described. Consequently, the longer-term effects of thermal anomalies on high-latitude reefs are difficult to predict. Here, we use an autonomous underwater vehicle to conduct repeated surveys of three 625 m(2) plots on a coral-dominated high-latitude reef in the Houtman Abrolhos Islands, Western Australia, over a four-year period spanning a large-magnitude thermal anomaly. Quantification of benthic communities revealed high coral cover (>70%, comprising three main morphospecies) prior to the bleaching event. Plating Montipora was most susceptible to bleaching, but in the plot where it was most abundant, coral cover did not change significantly because of post-bleaching increases in branching Acropora. In the other two plots, coral cover decreased while macroalgal cover increased markedly. Overall, coral cover declined from 73% to 59% over the course of the study, while macroalgal cover increased from 11% to 24%. The significant differences in impacts and post-bleaching trajectories among plots underline the importance of understanding the underlying causes of such variation to improve predictions of how climate change will affect reefs, especially at high-latitudes. PMID:25426718

  20. Soft self-assembled nanoparticles with temperature-dependent properties

    Science.gov (United States)

    Rovigatti, Lorenzo; Capone, Barbara; Likos, Christos N.

    2016-02-01

    The fabrication of versatile building blocks that reliably self-assemble into desired ordered and disordered phases is amongst the hottest topics in contemporary materials science. To this end, microscopic units of varying complexity, aimed at assembling the target phases, have been thought, designed, investigated and built. Such a path usually requires laborious fabrication techniques, especially when specific functionalisation of the building blocks is required. Telechelic star polymers, i.e., star polymers made of a number of f di-block copolymers consisting of solvophobic and solvophilic monomers grafted on a central anchoring point, spontaneously self-assemble into soft patchy particles featuring attractive spots (patches) on the surface. Here we show that the tunability of such a system can be widely extended by controlling the physical and chemical parameters of the solution. Indeed, under fixed external conditions the self-assembly behaviour depends only on the number of arms and on the ratio of solvophobic to solvophilic monomers. However, changes in temperature and/or solvent quality make it possible to reliably change the number and size of the attractive patches. This allows the steering of the mesoscopic self-assembly behaviour without modifying the microscopic constituents. Interestingly, we also demonstrate that diverse combinations of the parameters can generate stars with the same number of patches but different radial and angular stiffness. This mechanism could provide a neat way of further fine-tuning the elastic properties of the supramolecular network without changing its topology.

  1. Analysis of Temperature Dependence of Silicon-on-Insulator Thermo-Optic Attenuator

    Institute of Scientific and Technical Information of China (English)

    LI Yun-Tao; YU Jin-Zhong; CHEN Yuan-Yuan; SUN Fei; CHEN Shao-Wu

    2007-01-01

    The temperature dependence of silicon-on-insulator thermo-optic attenuators is analysed, which originates from the temperature dependence of characteristics of multimode interference. The attenuator depth and power consumption are independent of temperature while the insertion loss depends on the temperature heavily. The variation of the insertion loss decreases from 4.3 dB to 1 dB as the temperature increases from 273 K to 343 K.

  2. Anomalous hysteresis properties of iron films deposited on liquid surfaces

    Science.gov (United States)

    Ye, Quan-Lin; Feng, Chun-Mu; Xu, Xiao-Jun; Jin, Jin-Sheng; Xia, A.-Gen; Ye, Gao-Xiang

    2005-07-01

    A nearly free sustained iron film system, deposited on silicone oil surfaces by vapor-phase deposition method, has been fabricated and its crystal structure as well as magnetic properties has been studied. Both the temperature-dependent coercivity Hc(T) and exchange anisotropy field HE(T) of the iron films possess a maximum peak around the critical temperature Tcrit=10-15 and 4K, respectively. Our experimental results show that the anomalous hysteresis properties mainly result from the oxide surfaces of the films with spin-glass-like phase below freezing temperature Tf=30-50K.

  3. Gain Flattening Filter Canceling Temperature Dependence of EDFA's gain

    Institute of Scientific and Technical Information of China (English)

    M. Ohmura; Y. Ishizawa; H. Nakaji; K. Hashimoto; T. Shibata; M. Shigehara; A. Inoue

    2003-01-01

    We have developed a gain flattening filter(GFF) for an erbium doped fiber (EDF) without temperature control systems. This GFF, which consists of temperature-sensitive long period gratings (LPGs)and a temperature compensated slanted fiber Bragg grating (SFBG), follows the gain shift of EDF with temperature. Gain variation of the EDFA less than 0.25dBp-p was achieved with the bandwidth of 37nm,and the temperature range 0-65℃ without and temperature control systems.

  4. Temperature dependence of small polaron population decays in iron-doped lithium niobate by Monte Carlo simulations

    Science.gov (United States)

    Mhaouech, I.; Guilbert, L.

    2016-10-01

    The population decay of light-induced small polarons in iron-doped lithium niobate is simulated by a Monte-Carlo method on the basis of Holstein's theory. The model considers random walks of both bound polarons (NbLi4+) and free polarons (NbNb4+) ending to deep traps (FeLi3+). The thermokinetic interplay between polaron species is introduced by trapping and de-trapping rates at niobium antisites (NbLi). The decay of the NbLi4+ population proceeds by three possible channels: direct trapping at FeLi3+ sites, hopping on niobium antisites and hopping on Nb regular sites after conversion to the free state. Up to three regimes, each one reflecting the predominance of one of these processes, appear with different activation energies in the Arrhenius plots of the decay time. The influence of FeLi and NbLi concentrations on the transition temperatures is evidenced. For both polaron species, the length of the final hop (trapping length) is found much larger than the usual hopping length and decreases at rising temperature. This trap size effect is a natural consequence of Holstein's theory and may explain some unclear features of polaron-related light-induced phenomena, such as the temperature-dependent stretching exponent of light-induced absorption decays and the anomalous increase of the photoconductivity at high doping levels.

  5. Observation of an intermediate phase in tungsten doped Sb2Te phase change thin films by temperature dependent measurements of structural, optical, and electronic properties

    Science.gov (United States)

    Guo, S.; Huang, T.; Xu, L. P.; Shi, K.; Zhang, J. Z.; Ji, X. L.; Hu, Z. G.; Wu, L. C.; Song, Z. T.; Chu, J. H.

    2016-07-01

    The optical properties, electronic structure, and microstructure of Sb2Te (ST) phase change films as functions of temperature and tungsten (W) concentration have been investigated by means of temperature dependent x-ray diffraction (XRD), Raman scattering, and spectroscopic ellipsometry. Based on the variations of the diffraction peaks, phonon modes, and dielectric functions during the temperature elevation process, the intermediate (INT) crystalline state of W doped Sb2Te (WST) films between amorphous (AM) and hexagonal (HEX) phases can be readily proposed, which is a mixture of crystalline Sb and Te. The anomalous behaviors of dielectric functions and partial spectral weight integral for crystalline films elucidate the existence of INT state. Furthermore, the good agreement between experimental and calculated dielectric functions reveals that the first-principles calculation method can be used to make qualitative analysis in the materials with similar multilayered structures.

  6. Dependence of the anomalous fading of the TL and blue-OSL of fluorapatite on the occupancy of the tunnelling recombination sites

    Energy Technology Data Exchange (ETDEWEB)

    Tsirliganis, N.C. [Cultural and Educational Technology Institute, Archaeometry Laboratory, Tsimiski 58, 67100 Xanthi (Greece); Polymeris, G.S. [Cultural and Educational Technology Institute, Archaeometry Laboratory, Tsimiski 58, 67100 Xanthi (Greece); Nuclear Physics Laboratory, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Kitis, G. [Nuclear Physics Laboratory, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)]. E-mail: gkitis@auth.gr; Pagonis, V. [Physics Department, McDaniel College, Westminster, MD 21158 (United States)

    2007-10-15

    The anomalous fading (AF) of thermoluminescence (TL) and optically stimulated luminescence (OSL) signals in Durango apatite is attributed to tunnelling effects. Electrons from the TL and OSL traps in this material are transferred, via a tunnelling effect, to the recombination sites. The availability of recombination sites for tunnelled electrons is of major importance for the degree of AF rate observed in this material. It is expected that a variation of the number of the electron recombination sites will be reflected in the experimentally measured AF rate. In the present work an investigation of the recombination sites for the tunnelled electrons is attempted by studying the AF effect using a special technique, in which the anomalously faded TL (OSL) is replaced by an equal amount of TL (OSL) induced by a beta dose.

  7. Temperature-dependant study of phosphorus ion implantation in germanium

    Science.gov (United States)

    Razali, M. A.; Smith, A. J.; Jeynes, C.; Gwilliam, R. M.

    2012-11-01

    We present experimental results on shallow junction formation in germanium by phosphorus ion implantation and standard rapid thermal processing. An attempt is made to improve phosphorus activation by implanting phosphorus at high and low temperature. The focus is on studying the germanium damage and phosphorus activation as a function of implant temperature. Rutherford backscattering spectrometry with channelling and Hall Effect measurements are employed for characterisation of germanium damage and phosphorus activation, respectively. High and low temperature implants were found to be better compared to room temperature implant.

  8. Dependence of Arc Plasma Dispersion Capability on its Temperature

    Institute of Scientific and Technical Information of China (English)

    CHEN Yun-Yun; SONG Yang; HE An-Zhi; LI Zhen-Hua

    2008-01-01

    @@ The relationship between the dispersion capability and the temperature of argon arc plasma at Iatm is deduced in view of the plasma's refractive index equation.The results indicate that argon arc plasma has a normal dispersion and its dispersion capability is nonlinear to the plasma's temperature in a wide range of temperature and wavelength region.According to the results of numerical calculation, the preferred optical methods are believed to be suitable for the diagnosis of argon arc plasma in different temperature regions.

  9. Anomalous Hall effects in pseudo-single-crystal γ'-Fe4N thin films

    Science.gov (United States)

    Kabara, Kazuki; Tsunoda, Masakiyo; Kokado, Satoshi

    2016-05-01

    The anomalous Hall effects (AHE) were investigated at various temperatures for the pseudo-single-crystal Fe4N films, deposited on MgO substrates with changing the degree of order (S) of the nitrogen site. Both the anomalous Hall resistivity and the longitudinal resistivity simply decrease with lowering temperature for all the specimens. The AHE of the Fe4N films is presumed to arise from an intrinsic mechanism because of the relationship between the anomalous Hall resistivity and longitudinal resistivity. The anomalous Hall conductivity, σAH, exhibits a specific behavior at low temperature. In the case of the film with S = 0.93, the σAH drastically drops below 50 K, while it simply increases with lowering temperature in the range of 50-300 K. This low-temperature anomaly decays with decreasing S of the film and nearly vanishes in the films with low S. The threshold temperature and the dependence on S of the low-temperature anomaly of the σAH well correspond to those of the anisotropic magnetoresistance effects in the Fe4N films, reported in the literatures. From these results, it is suggested that the low-temperature anomaly of the σAH originates from the crystal field effect which reflects the structural transformation from a cubic to a tetragonal symmetry below 50 K and provides a modulation of the orbital angular momentum of the 3d orbitals at the Fermi level.

  10. Temperature-dependent phenotypic variation of Campylobacter jejuni lipooligosaccharides

    LENUS (Irish Health Repository)

    Semchenko, Evgeny A

    2010-11-30

    Abstract Background Campylobacter jejuni is a major bacterial cause of food-borne enteritis, and its lipooligosaccharide (LOS) plays an initiating role in the development of the autoimmune neuropathy, Guillain-Barré syndrome, by induction of anti-neural cross-reactive antibodies through ganglioside molecular mimicry. Results Herein we describe the existence and heterogeneity of multiple LOS forms in C. jejuni strains of human and chicken origin grown at 37°C and 42°C, respectively, as determined on sodium dodecyl sulphate-polyacrylamide electrophoresis gels with carbohydrate-specific silver staining and blotting with anti-ganglioside ligands, and confirmed by nuclear magnetic resonance (NMR) spectroscopy. The C. jejuni NCTC 11168 original isolate (11168-O) was compared to its genome-sequenced variant (11168-GS), and both were found to have a lower-Mr LOS form, which was different in size and structure to the previously characterized higher-Mr form bearing GM1 mimicry. The lower-Mr form production was found to be dependent on the growth temperature as the production of this form increased from ~5%, observed at 37°C to ~35% at 42°C. The structure of the lower-Mr form contained a β-D-Gal-(1→3)-β-D-GalNAc disaccharide moiety which is consistent with the termini of the GM1, asialo-GM1, GD1, GT1 and GQ1 gangliosides, however, it did not display GM1 mimicry as assessed in blotting studies but was shown in NMR to resemble asialo-GM1. The production of multiple LOS forms and lack of GM1 mimicry was not a result of phase variation in the genes tested of NCTC 11168 and was also observed in most of the human and chicken isolates of C. jejuni tested. Conclusion The presence of differing amounts of LOS forms at 37 and 42°C, and the variety of forms observed in different strains, indicate that LOS form variation may play a role in an adaptive mechanism or a stress response of the bacterium during the colonization of different hosts.

  11. Thermal Aware Floorplanning Incorporating Temperature Dependent Wire Delay Estimation

    DEFF Research Database (Denmark)

    Winther, AndreasThor; Liu, Wei; Nannarelli, Alberto;

    2015-01-01

    Temperature has a negative impact on metal resistance and thus wire delay. In state-of-the-art VLSI circuits, large thermal gradients usually exist due to the uneven distribution of heat sources. The difference in wire temperature can lead to performance mismatch because wires of the same length ...

  12. Temperature-dependence of wetting properties of carbon nanotubes

    Science.gov (United States)

    Ebrahimi, Fatemeh; Gholamian Moghaddam, Melika

    2016-07-01

    We have carried out molecular dynamics simulations to study the spontaneous imbibition of water into a single-wall carbon nanotube (CNT) at various temperatures, ranging from 270 K to 370 K. The simulations indicate that by increasing the temperature, the rate of mass uptake improves as well. Considering the end-loss friction as the main source of energy dissipation and ignoring the inertial effect on the nano-scale transport, we derive a simple expression that relates the CNT's wettability to the fluid viscosity and the rate of imbibition over the temperature range that we study. Our results also indicate that the increase in the wettability of the CNT, and the reduction in the viscosity of water at higher temperatures cause enhancement of water uptake into the nanotube. They also enable us to estimate the wetting transition temperature for TIP3P model of water in the CNTs.

  13. Temperature dependence of the energy dissipation in dynamic force microscopy

    CERN Document Server

    Roll, Tino; Fendrich, Markus; Moeller, Rolf; Schleberger, Marika

    2008-01-01

    he dissipation of energy in dynamic force microscopy is usually described in terms of an adhesion hysteresis mechanism. This mechanism should become less efficient with increasing temperature. To verify this prediction we have measured topography and dissipation data with dynamic force microscopy in the temperature range from 100 K up to 300 K. We used 3,4,9,10-perylenetetracarboxylic-dianhydride (PTCDA) grown on KBr(001), both materials exhibiting a strong dissipation signal at large frequency shifts. At room temperature, the energy dissipated into the sample (or tip) is 1.9 eV/cycle for PTCDA and 2.7 eV/cycle for KBr, respectively, and is in good agreement with an adhesion hysteresis mechanism. The energy dissipation over the PTCDA surface decreases with increasing temperature yielding a negative temperature coefficient. For the KBr substrate, we find the opposite behaviour: an increase of dissipated energy with increasing temperature. While the negative temperature coefficient in case of PTCDA agrees rathe...

  14. Theoretical analysis for temperature dependence of laser- induced damage threshold of optical thin films

    Science.gov (United States)

    Mikami, K.; Motokoshi, S.; Somekawa, T.; Jitsuno, T.; Fujita, M.; Tanaka, KA; Azechi, H.

    2016-03-01

    The temperature dependence of the laser-induced damage threshold on optical coatings was studied in detail for laser pulses from 123 K to 473 K at different temperatures. The laser-induced damage threshold increased with decreasing temperatures when we tested long pulses (200 ps and 4 ns). The temperature dependence, however, was reversed for pulses shorter than a few picoseconds (100 fs testing). We propose a scaling model with a flowchart that includes three separate processes: free-electron generation, electron multiplication, and electron heating. Furthermore, we calculated the temperature dependence of laser-induced damage thresholds at different temperatures. Our calculation results agreed well with the experimental results.

  15. Optical fiber temperature sensor based on wavelength-dependent detection

    Institute of Scientific and Technical Information of China (English)

    Zhigang Li(李志刚); Zhenhui Du(杜振辉); Baoguang Wang(王宝光); Chengzhi Jiang(蒋诚志)

    2004-01-01

    Semiconductor fiber temperature sensors have been used widely in many fields, but most of them pick up temperature by measuring the optical intensity of certain fixed narrow-band in absorption spectrum.Furthermore, they are sensitive to the loss of optical intensity and the fluctuation of light source power.The novel temperature measurement system proposed in this paper is based on the semiconductor absorption theory and the spectral analysis of method. To measure temperature, the sensor model detects not the certain narrow-band spectrum but the most spectra of the optical absorption edge. Therefore the measurement accuracy and the stability can be improved greatly. Experimental results are in agreement with theoretical analysis results perfectly.

  16. Temperature dependence of the PER in PM-PCF coil

    Institute of Scientific and Technical Information of China (English)

    Hong Zhao; Meng Chen; Gang Li

    2012-01-01

    A piece of domestic polarization-maintaining photonic crystal fiber (PM-PCF,964 m in length) is made into a fiber coil,and its polarization extinction ratio (PER) is measured in a temperature range of -45-80 ℃ before and after PM-PCF is wound and solidified.A fiber coil made of commercial panda PM fiber (PMF) is also fabricated and measured for comparison.Our experiments show that the PER variation of the PM-PCF coil (2.25 dB) is far smaller than that of the panda PMF coil (10 dB) in the whole temperature range because PM-PCF is intrinsically insensitive to the temperature variation and stress in the fiber coil induced by the winding and solidification process.This characteristic is important for the real application of PM-PCFs in temperature-insensitive fiber interferometers,fiber sensors,and optical fiber gyroscopes.

  17. Temperature dependence of the energy dissipation in dynamic force microscopy

    OpenAIRE

    Roll, Tino; Kunstmann, Tobias; Fendrich, Markus; Moeller, Rolf; Schleberger, Marika

    2008-01-01

    The dissipation of energy in dynamic force microscopy is usually described in terms of an adhesion hysteresis mechanism. This mechanism should become less efficient with increasing temperature. To verify this prediction we have measured topography and dissipation data with dynamic force microscopy in the temperature range from 100 K up to 300 K. We used 3,4,9,10-perylenetetracarboxylic-dianhydride (PTCDA) grown on KBr(001), both materials exhibiting a strong dissipation signal at large freque...

  18. Temperature dependence of the optical absorption coefficient of microcrystalline silicon

    OpenAIRE

    Poruba, A.; Špringer, J.; Mullerova, L.; Beitlerova, A.; Vaněček, M.; Wyrsch, Nicolas; Shah, Arvind

    2008-01-01

    The optical absorption coefficient of amorphous and microcrystalline silicon was determined in a spectral range 400–3100 nm and a temperature range 77–350 K. Transmittance measurement and Fourier transform photocurrent spectroscopy were used. The measured data served as an input for our optical model of amorphous/microcrystalline tandem solar cell. Differences in the current generated in the amorphous and microcrystalline parts were computed, for an operating temperature between −20 °C and +8...

  19. The temperature dependence of FeRh's transport properties

    OpenAIRE

    Mankovsky, S.; Polesya, S.; Chadova, K.; Ebert, H.; Staunton, J. B.; Gruenbaum, T.; Schoen, M. A. W.; Back, C.H.; Chen, X. Z.; C. Song

    2016-01-01

    The finite-temperature transport properties of FeRh compounds are investigated by first-principles Density Functional Theory-based calculations. The focus is on the behavior of the longitudinal resistivity with rising temperature, which exhibits an abrupt decrease at the metamagnetic transition point, $T = T_m$ between ferro- and antiferromagnetic phases. A detailed electronic structure investigation for $T \\geq 0$ K explains this feature and demonstrates the important role of (i) the differe...

  20. Temperature Dependence of Stark Broadening Dominated by Strong Collisions

    International Nuclear Information System (INIS)

    The influence of electron temperature in the broadening of spectral lines dominated by strong collisions has been studied. Computer simulation allows us to study the effects of strong and weak collisions separately. Results shown here are focused on some Sr+ and Ba+ resonance lines as examples of lines broadened dominantly by strong collisions. The exact numerical integration of the perturbation process due to the collision with a single particle permits the evaluation of Weisskopf radius. This parameter is usually defined as rw ∼ 1/v ∼ 1/√T, obtained from Bora approximation that is correct for high temperatures. However, at low temperatures the full integration of the collision process permits to test the relationship rw ∼ 1/T1/6. This calculation has allowed us to study the influence of temperature on the broadening of the lines dominated by strong collisions. This study has been done in two ways : through a plasma simulation and analyzing the calculated Weisskopf radius for an individual collision. The obtained results show that at low temperatures the width of the line increases for increasing temperature as a consequence of an increase of the number of collisions not compensated by the decrease of Weisskopf radius

  1. Temperature Dependent Seed Germination of Dalbergia nigra Allem (Leguminosae

    Directory of Open Access Journals (Sweden)

    Fernanda G. A. Ferraz-Grande

    2001-12-01

    Full Text Available The germination of endangered species Dalbergia nigra was studied and 30.5° C was found as optimum temperature, although the species presented a broad temperature range where germination occurs and light had no effect. The analysis of kinetics of seed germination confirmed the asynchronized germination below and above the optimum temperature. The light insensitive seed and germination also at high temperatures indicated that D. nigra could occur both in understories and gaps where the mean temperature was high.A germinação de sementes de Dalbergia nigra Allem, comumente conhecida como jacarandá-da-Bahia, caviúna, jacarandá, uma espécie em extinção, foi estudada e determinamos a temperatura ótima de 30,5° C. A espécie apresenta uma ampla faixa de temperatura onde a germinação ocorre e a luz branca não influenciou o processo. A análise da cinética da germinação de sementes confirma a germinação não sincronizada acima e abaixo da temperatura ótima de germinação. A semente insensível à luz e a germinação também em altas temperaturas indicam que D. nigra pode ocorrer tanto na sombra da vegetação bem como em clareiras.

  2. Temperature dependence of the coercive field of gas atomized Fe{sub 73.5}Si{sub 13.5}B{sub 9}Nb{sub 3}Cu{sub 1}

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Escorial, A., E-mail: age@cenim.csic.es [CENIM-CSIC, Avda, Gregorio del Amo, 8, 28040 Madrid (Spain); Lieblich, M. [CENIM-CSIC, Avda, Gregorio del Amo, 8, 28040 Madrid (Spain); Hernando, A.; Aragon, A.; Marin, P. [Instituto de Magnetismo Aplicado, IMA, P.O. Box 155, 28230 Madrid (Spain)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer An anomalous thermal dependence of the coercive field of gas atomized Fe{sub 73.5}Si{sub 13.5}B{sub 9}Nb{sub 3}Cu{sub 1} powder particles under 25 {mu}m powder particle, increasing Hc as temperature increases. Black-Right-Pointing-Pointer It is proposed that Cu rich regions at inter-grain boundaries could act as exchange decoupling regions contributing to the thermal increase of coercivity. Black-Right-Pointing-Pointer This anomalous thermal dependence points out that tailoring microstructure and size, by controlling the cooling rate of more adequate multiphase systems, could be a promising procedure to develop soft or hard magnets, avoiding Rare Earths metals that is nowadays an important target for the engineering of magnetic materials. - Abstract: In this work, the dependence of the coercive field of Fe{sub 73.5}Si{sub 13.5}B{sub 9}Nb{sub 3}Cu{sub 1} gas atomized powder with the temperature for different particle sizes has been studied, observing an anomalous behavior in the under 25 powder particle size fraction. This unusual behavior is related with the microstructure of the powder, and is attributed to the presence of a multiphase magnetic system, with non-magnetic regions decoupling the ferromagnetic domains.

  3. Temperature-Dependent Current-Voltage (I-V) and Capacitance-Voltage (C-V) Characteristics of Ni/Cu/n-InP Schottky Barrier Diodes

    Science.gov (United States)

    Munikrishana Reddy, Y.; Nagaraj, M. K.; Siva Pratap Reddy, M.; Lee, Jung-Hee; Rajagopal Reddy, V.

    2013-04-01

    The current-voltage (I-V) and capacitance-voltage (C-V) characteristics of Ni/Cu/n-InP Schottky barrier diodes are studied over a wide temperature range, from 210 K to 420 K. The I-V characteristics display anomalous thermal behavior. The apparent barrier height decays, and the ideality factor grows at low temperatures, and the series resistances resulting from Cheung's and Norde's procedures are markedly temperature dependent. The nonlinearity of the Richardson plot and the strong temperature dependence of the Schottky-barrier parameters indicate that the interface is spatially inhomogeneous. Plots of the zero-bias barrier height as a function of 1/(2kT) points to a Gaussian distribution of barrier heights with 0.90 eV mean height and 0.014 eV standard deviation. When this distribution is accounted for, a Richardson of 6.5 A/(cm K)2 results, relatively close to the 9.4/(cm K)2 predicted by theory. We conclude that, combined with a Gaussian distribution of barrier heights, the thermionic-emission mechanism explains the temperature-dependent I-V and C-V characteristics of the studied Schottky-barrier diodes.

  4. Temperature-dependent permittivity of annealed and unannealed gold films

    CERN Document Server

    Shen, Po-Ting; Lin, Cheng-Wei; Liu, Hsiang-Lin; Chang, Chih-Wei; Chu, Shi-Wei

    2016-01-01

    Due to local field enhancement and subwavelength confinements, nano-plasmonics provide numerous novel applications. Simultaneously, as an efficient nanoscale heat generator from inherent absorption, thermo-plasmonics is emerging as an important branch. However, although significant temperature increase is involved in applications, detailed characterization of metal permittivity at different temperatures is lacking. In this work, we extract the permittivity of gold film from 300K to the annealing temperature of 570K. By comparing annealed and unannealed films, more than one-order difference in thermo-derivative of permittivity is revealed, resulting in unexpectedly large variation of plasmonic properties. Our result is valuable not only for characterizing extensively used unannealed nanoparticles, but also for designing future thermo-nano-plasmonic systems.

  5. Parallel temperature-dependent microrheological measurements in a microfluidic chip.

    Science.gov (United States)

    Josephson, Lilian Lam; Galush, William J; Furst, Eric M

    2016-07-01

    Microfluidic stickers are used as a sample environment to measure the microrheology of monoclonal antibody (mAb) protein solutions. A Peltier-based microscope stage is implemented and validated, and is capable of controlling the sample temperature over the range 0.9-40 °C. The design accounts for heat transfer to and from the objective, controls the sample environment humidity to mitigate condensation, and provides adequate damping to reduce vibration from the cooling system. A concentrated sucrose solution is used as a standard sample to provide an in situ temperature measurement by the Stokes-Einstein-Sutherland relation. By combining microfluidic stickers and microrheology, 72 temperature-concentration viscosity measurements of mAb solutions can be made in 1 day, a significant increase in throughput over conventional rheometry. PMID:27375825

  6. Temperature dependence of impact ionization coefficients in InP

    Science.gov (United States)

    Taguchi, Kenko; Torikai, Toshitaka; Sugimoto, Yoshimasa; Makita, Kikuo; Ishihara, Hisahiro

    1986-01-01

    Impact ionization coefficients for electrons and holes in InP were measured experimentally at 25-175 °C in the 400-600 kV/cm electric field range with planar avalanche photodiodes, in which the n-InP avalanche region was separated from the light absorbing InGaAs and/or InGaAsP layers. α and β monotonically decreased with elevated temperatures; β/α slightly decreased with increasing temperature. Comparison of the experimental results with Okuto-Crowell formula on the impact ionization coefficient gave the phonon energy ERO=46 meV and the phonon scattering mean free path λ0=41.7 Å for electron impact ionization and ERO=36 meV and λ0=41.3 Å for hole impact ionization, respectively. Curves calculated by using these parameters agree with the experimental results quite satisfactorily at each temperature.

  7. Mechanical behaviour of ferritic ODS steels - Temperature dependancy and anisotropy

    Science.gov (United States)

    Fournier, B.; Steckmeyer, A.; Rouffie, A.-L.; Malaplate, J.; Garnier, J.; Ratti, M.; Wident, P.; Ziolek, L.; Tournie, I.; Rabeau, V.; Gentzbittel, J. M.; Kruml, T.; Kubena, I.

    2012-11-01

    Ferritic 14%Cr and 18%Cr ODS steels produced at CEA in round bars or plates were tested mechanically. The present paper reports results obtained in tension, impact, fatigue, creep and toughness tests. These tests were carried out at various temperatures and in different directions. These materials show a pronounced anisotropy at all tested temperatures. No matter the loading, the transversal direction is always found to be far less resistant than the longitudinal one. This anisotropy is mainly observed in terms of damage mechanisms, with intergranular fracture preferentially occurring along the extrusion direction. This intergranular fracture mode leads to very low and anisotropic toughness values and to the absence of tertiairy creep stage, pointing out the unstable nature of fracture, even at high temperature. The unrealistically high values of the Norton exponent measured in creep suggests the existence of a threshold stress, which is consistent with the mainly kinematic nature of the stress as revealed by fatigue tests.

  8. Soil Temperature Dependent Growth of Cotton Seedlings Before Emergence

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Soil temperature is an important variable governing plant growth and development.Studies were conducted under laboratory conditions to determine the effect of soil temperature on root and shoot growth of cotton during emergence.Cotton seedlings were grown for 192 h at 20,32 and 38℃ in soil packed in 300 mm long and 50 mm diameter cylinders.The data indicated that the longest roots(173 ram)as well as shoots(152 mm)were recorded at 32 ℃ followed by 20 (130 mm root and 82 mm shoot)and 38℃(86 mm root and 50 mm shoot).Roots grown at 20 and 38 ℃ were 20% and 50% shorter,respectively,than those grown at 32℃ after 192 h.Roots and shoots exhibited the lowest length and dry biomass at 38℃.Shoot lengths grown at 20(74 ram)and 38℃(51 mm)were 44% and 61% shorter than those grown at 32℃(131 mm)after 180 h growth period,respectively.Growth at all three temperatures followed a similar pattern.Initially there was a linear growth phase followed by the reduction or cessation of growth.Time to cessation of growth varied with temperature and decreased faster at higher temperatures.Sowing of cotton should be accomlplished before seedbed reaches a soil temperature(≥38℃)detrimental for emergence.Further,the seedbeds should be capable of providing sufficient moisture and essential nutrients for emerging seedling before its seed reserves are exhausted to enhance seedling establishment in soil.

  9. Temperature-dependent enthalpy of oxygenation in Antarctic fish hemoglobins

    DEFF Research Database (Denmark)

    Fago, A.; Wells, R.M.G.; Weber, Roy E.

    1997-01-01

    The effect of temperature on the oxygen-binding properties of the hemoglobins of three cold-adapted Antarctic fish species, Dissostichus mawsoni, Pagothenia borchgrevinki and Trematomus, sp., has been investigated under different pH values and buffer conditions. A clear non linear van't Hoff plot...... literature data for the enthalpy of oxygenation in Antarctic fish hemoglobins derives from the use of the nonintegrated (linearized) form of the van't Hoff equation over different temperature ranges. The general assumption that a low heat of oxygenation in hemoglobins from polar animals represents...

  10. TEMPERATURE DEPENDENCE OF VISCOSITY OF Al-Si ALLOY MELTS

    Institute of Scientific and Technical Information of China (English)

    H.R. Geng; R. Wang; Z.X. Yang; J.H. Chen; C.J. Sun; Y. Wang

    2005-01-01

    The relationship between the viscosity and temperature of Al-Si alloy melts was investigated.The viscosity of three different types of Al-Si alloy melts was measured. It was showed that the relationship between the viscosity and temperature of hypoeutectic Al-5% Si and eutectic Al12.5%Si alloy melts is approximately exponential except for some special zones, but that of the hypereutectic melt is different. The paper discussed the correlation of the viscosity and atomic density, which is thought that the viscosity corresponds to the atomic density to some extent.

  11. Altitude dependence of atmospheric temperature trends: Climate models versus observation

    CERN Document Server

    Douglass, D H; Singer, F

    2004-01-01

    As a consequence of greenhouse forcing, all state of the art general circulation models predict a positive temperature trend that is greater for the troposphere than the surface. This predicted positive trend increases in value with altitude until it reaches a maximum ratio with respect to the surface of as much as 1.5 to 2.0 at about 200 to 400 hPa. However, the temperature trends from several independent observational data sets show decreasing as well as mostly negative values. This disparity indicates that the three models examined here fail to account for the effects of greenhouse forcings.

  12. On the frequency dependence of the high temperature background

    International Nuclear Information System (INIS)

    The high temperature background (HTB) damping in metals and alloys has been measured mostly as a function of temperature. These data were described by several empirical expressions proposed in the literature. In the present work, HTB in pure Mg and in two alloys (Zry-4 and Cu-5 at.%Au), measured with a torsion pendulum with variable moment of inertia, are analyzed on considering a new treatment of the data. This analysis provides an useful tool to determine whether a damping process is linear or not. (orig.)

  13. Temperature-dependent indentation behavior of transformation-toughened zirconia-based ceramics

    Science.gov (United States)

    Tikare, Veena; Heuer, Arthur H.

    1991-01-01

    Indentation behavior of Ce-TZP, Y-TZP, and Mg-PSZ between room temperature and 1300 C was investigated. Hardness decreased with increasing temperature for all three materials, but indentation cracking increased with increasing temperature. The opposing temperature dependences are discussed in terms of dislocation and transformation plasticity.

  14. On the gauge dependence of vacuum transitions at finite temperature

    Energy Technology Data Exchange (ETDEWEB)

    Garny, Mathias [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Konstandin, Thomas [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); European Organization for Nuclear Research (CERN), Geneva (Switzerland)

    2012-05-15

    In principle, observables as for example the sphaleron rate or the tunneling rate in a first-order phase transition are gauge-independent. However, in practice a gauge dependence is introduced in explicit perturbative calculations due to the breakdown of the gradient expansion of the effective action in the symmetric phase. We exemplify the situation using the effective potential of the Abelian Higgs model in the general renormalizable gauge. Still, we find that the quantitative dependence on the gauge choice is small for gauges that are consistent with the perturbative expansion.

  15. Temperature-Dependent Nickel Release from Nickel-Alloys

    DEFF Research Database (Denmark)

    Menne, T.; Solgaard, Per Bent

    1979-01-01

    Ni release from Danish 1 krone coins and metal buttons from jeans was measured at 20.degree. C in distilled water and at 35.degree. C in distilled water and synthetic sweat. The temperature elevation increased the Ni release from the coins and 2 of the 9 metal buttons investigated. The sensitivit...

  16. Temperature dependence of fluctuation time scales in spin glasses

    DEFF Research Database (Denmark)

    Kenning, Gregory G.; Bowen, J.; Sibani, Paolo;

    2010-01-01

    Using a series of fast cooling protocols we have probed aging effects in the spin glass state as a function of temperature. Analyzing the logarithmic decay found at very long time scales within a simple phenomenological barrier model, leads to the extraction of the fluctuation time scale of the s......-aging behavior in scaling aged TRM decay curves, as recently discussed theoretically~\\cite{Sibani09}.......Using a series of fast cooling protocols we have probed aging effects in the spin glass state as a function of temperature. Analyzing the logarithmic decay found at very long time scales within a simple phenomenological barrier model, leads to the extraction of the fluctuation time scale of the...... system at a particular temperature. This is the smallest dynamical time-scale, defining a lower-cut off in a hierarchical description of the dynamics.  We find that this fluctuation time scale, which is approximately equal to atomic spin fluctuation time scales near the transition temperature, follows a...

  17. The external field dependence of the BCS critical temperature

    DEFF Research Database (Denmark)

    Frank, Rupert L.; Hainzl, Christian; Seiringer, Robert;

    2016-01-01

    We consider the Bardeen-Cooper-Schrieffer free energy functional for particles interacting via a two-body potential on a microscopic scale and in the presence of weak external fields varying on a macroscopic scale. We study the influence of the external fields on the critical temperature. We show...

  18. Temperature Dependences on Various Types of Photovoltaic (PV) Panel

    Science.gov (United States)

    Audwinto, I. A.; Leong, C. S.; Sopian, K.; Zaidi, S. H.

    2015-09-01

    Temperature is one of the key roles in PV technology performance, since with the increases of temperature the open-circuit voltage will drop accordingly so do the electrical efficiency and power output generation. Different types of Photovoltaic (PV) panels- silicon solar panels and thin film solar panels; mono-crystalline, poly-crystalline, CIS, CIGS, CdTe, back-contact, and bi-facial solar panel under 40°C to 70°C approximately with 5°C interval have been comparatively analyzed their actual performances with uniformly distribution of light illumination from tungsten halogen light source, ±500W/m2. DC-Electronic Load and Data Logger devices with “Lab View” data program interface were used to collect all the necessary parameters in this study. Time needed to achieve a certain degree of temperature was recorded. Generally, each of the panels needed 15 minutes to 20 minutes to reach 70°C. Halogen based light source is not compatible in short wave-length in response to thin-film solar cell. Within this period of times, all the panels are facing a performance loss up to 15%. Other parameters; Pmax, Vmax, Imax, Voc, Isc, Rserries, Rshunt, Fillfactor were collected as study cases. Our study is important in determining Photovoltaic type selection and system design as for study or industrial needed under different temperature condition.

  19. Temperature-dependent structure of Tb-doped magnetite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rice, Katherine P.; Russek, Stephen E., E-mail: stephen.russek@nist.gov; Shaw, Justin M.; Usselman, Robert J.; Evarts, Eric R.; Silva, Thomas J.; Nembach, Hans T. [National Institute of Standards and Technology, Boulder, Colorado 80305 (United States); Geiss, Roy H. [Colorado State University, Fort Collins, Colorado 80523 (United States); Arenholz, Elke [Lawrence Berkeley National Laboratory, Advanced Light Source, Berkeley, California 94720 (United States); Idzerda, Yves U. [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States)

    2015-02-09

    High quality 5 nm cubic Tb-doped magnetite nanoparticles have been synthesized by a wet-chemical method to investigate tailoring of magnetic properties for imaging and biomedical applications. We show that the Tb is incorporated into the octahedral 3+ sites. High-angle annular dark-field microscopy shows that the dopant is well-distributed throughout the particle, and x-ray diffraction measurements show a small lattice parameter shift with the inclusion of a rare-earth dopant. Magnetization and x-ray magnetic circular dichroism data indicate that the Tb spins are unpolarized and weakly coupled to the iron spin lattice at room temperature, and begin to polarize and couple to the iron oxide lattice at temperatures below 50 K. Broadband ferromagnetic resonance measurements show no increase in magnetic damping at room temperature for Tb-doped nanoparticles relative to undoped nanoparticles, further confirming weak coupling between Fe and Tb spins at room temperature. The Gilbert damping constant, α, is remarkably low for the Tb-doped nanoparticles, with α = 0.024 ± 0.003. These nanoparticles, which have a large fixed moment, a large fluctuating moment and optically active rare-earth elements, are potential high-relaxivity T1 and T2 MRI agents with integrated optical signatures.

  20. Temperature-dependent structure of Tb-doped magnetite nanoparticles

    Science.gov (United States)

    Rice, Katherine P.; Russek, Stephen E.; Geiss, Roy H.; Shaw, Justin M.; Usselman, Robert J.; Evarts, Eric R.; Silva, Thomas J.; Nembach, Hans T.; Arenholz, Elke; Idzerda, Yves U.

    2015-02-01

    High quality 5 nm cubic Tb-doped magnetite nanoparticles have been synthesized by a wet-chemical method to investigate tailoring of magnetic properties for imaging and biomedical applications. We show that the Tb is incorporated into the octahedral 3+ sites. High-angle annular dark-field microscopy shows that the dopant is well-distributed throughout the particle, and x-ray diffraction measurements show a small lattice parameter shift with the inclusion of a rare-earth dopant. Magnetization and x-ray magnetic circular dichroism data indicate that the Tb spins are unpolarized and weakly coupled to the iron spin lattice at room temperature, and begin to polarize and couple to the iron oxide lattice at temperatures below 50 K. Broadband ferromagnetic resonance measurements show no increase in magnetic damping at room temperature for Tb-doped nanoparticles relative to undoped nanoparticles, further confirming weak coupling between Fe and Tb spins at room temperature. The Gilbert damping constant, α, is remarkably low for the Tb-doped nanoparticles, with α = 0.024 ± 0.003. These nanoparticles, which have a large fixed moment, a large fluctuating moment and optically active rare-earth elements, are potential high-relaxivity T1 and T2 MRI agents with integrated optical signatures.

  1. Temperature dependence of excitonic transition in ZnSe/ZnCdSe quantum wells

    Institute of Scientific and Technical Information of China (English)

    GUO Zi-zheng; LIANG Xi-xia; BAN Shi-liang

    2005-01-01

    A theoretical calculation for the temperature dependence of the excitonic transition in ZnSe/ZnCdSe quantum wells is performed. The exciton binding energy is calculated with a variational technique by considering the temperature-dependence parameters. Our results show that the exciton binding energy reduces linearly with temperature increasing. We find that the strain due to lattice mismatch and differential thermal expansion decreases with the temperature increasing.

  2. Finite range effective interactions and temperature dependence of nuclear symmetry energy

    International Nuclear Information System (INIS)

    The temperature dependence of nuclear symmetry energy has become a subject of current research interest because of its role in the studies of isoscaling analyses of Heavy Ion reactions and the formation mechanism of neutron stars particularly the properties of proto neutron stars (PNS). While the temperature dependence of the kinetic part of the nuclear symmetry energy is well understood, the temperature dependence of its interaction part is not yet known to a satisfactory extent. In the present work, we have investigated the temperature dependence of nuclear symmetry energy using some finite range effective interactions proposed in some earlier works

  3. Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy

    Science.gov (United States)

    Hemalatha, K. S.; Sriprakash, G.; Ambika Prasad, M. V. N.; Damle, R.; Rukmani, K.

    2015-10-01

    Dielectric and conductivity behaviors of nano ZnO doped polyvinyl alcohol (PVA) composites for various concentrations of dopant were investigated using impedance spectroscopy for a wide range of temperatures (303 K-423 K) and frequencies (5 Hz-30 MHZ). The dielectric properties of host polymer matrix have been improved by the addition of nano ZnO and are found to be highly temperature dependent. Anomalous dielectric behavior was observed in the frequency range of 2.5 MHz-5 MHz. Increase in dielectric permittivity and dielectric loss was observed with respect to temperature. The Cole-Cole plot could be modeled by low resistance regions in a high resistance matrix and the lowest resistance was observed for the 10 mol. % films. The imaginary part of the electric modulus showed asymmetric peaks with the relaxation following Debye nature below and non-Debye nature above the peaks. The ac conductivity is found to obey Jonscher's power law, whereas the variation of dc conductivity with temperature was found to follow Arrhenius behavior. Two different activation energy values were obtained from Arrhenius plot indicating that two conduction mechanisms are involved in the composite films. Fitting the ac conductivity data to Jonscher's law indicates that large polaron assisted tunneling is the most likely conduction mechanism in the composites. Maximum conductivity is observed at 423 K for all the samples and it is optimum for 10 mol. % ZnO doped PVA composite film. Significant increase in dc and ac conductivities in these composite films makes them a potential candidate for application in electronic devices.

  4. Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hemalatha, K. S.; Damle, R.; Rukmani, K., E-mail: rukmani9909@yahoo.co.in [Department of Physics, Bangalore University, Bangalore 560056 (India); Sriprakash, G. [Department of Physics, Maharani' s Science College for Women, Bangalore 560001 (India); Ambika Prasad, M. V. N. [Department of Physics, Gulbarga University, Gulbarga 585106 (India)

    2015-10-21

    Dielectric and conductivity behaviors of nano ZnO doped polyvinyl alcohol (PVA) composites for various concentrations of dopant were investigated using impedance spectroscopy for a wide range of temperatures (303 K–423 K) and frequencies (5 Hz–30 MHZ). The dielectric properties of host polymer matrix have been improved by the addition of nano ZnO and are found to be highly temperature dependent. Anomalous dielectric behavior was observed in the frequency range of 2.5 MHz–5 MHz. Increase in dielectric permittivity and dielectric loss was observed with respect to temperature. The Cole-Cole plot could be modeled by low resistance regions in a high resistance matrix and the lowest resistance was observed for the 10 mol. % films. The imaginary part of the electric modulus showed asymmetric peaks with the relaxation following Debye nature below and non-Debye nature above the peaks. The ac conductivity is found to obey Jonscher's power law, whereas the variation of dc conductivity with temperature was found to follow Arrhenius behavior. Two different activation energy values were obtained from Arrhenius plot indicating that two conduction mechanisms are involved in the composite films. Fitting the ac conductivity data to Jonscher's law indicates that large polaron assisted tunneling is the most likely conduction mechanism in the composites. Maximum conductivity is observed at 423 K for all the samples and it is optimum for 10 mol. % ZnO doped PVA composite film. Significant increase in dc and ac conductivities in these composite films makes them a potential candidate for application in electronic devices.

  5. Anomalous extracellular diffusion in rat cerebellum.

    Science.gov (United States)

    Xiao, Fanrong; Hrabe, Jan; Hrabetova, Sabina

    2015-05-01

    Extracellular space (ECS) is a major channel transporting biologically active molecules and drugs in the brain. Diffusion-mediated transport of these substances is hindered by the ECS structure but the microscopic basis of this hindrance is not fully understood. One hypothesis proposes that the hindrance originates in large part from the presence of dead-space (DS) microdomains that can transiently retain diffusing molecules. Because previous theoretical and modeling work reported an initial period of anomalous diffusion in similar environments, we expected that brain regions densely populated by DS microdomains would exhibit anomalous extracellular diffusion. Specifically, we targeted granular layers (GL) of rat and turtle cerebella that are populated with large and geometrically complex glomeruli. The integrative optical imaging (IOI) method was employed to evaluate diffusion of fluorophore-labeled dextran (MW 3000) in GL, and the IOI data analysis was adapted to quantify the anomalous diffusion exponent dw from the IOI records. Diffusion was significantly anomalous in rat GL, where dw reached 4.8. In the geometrically simpler turtle GL, dw was elevated but not robustly anomalous (dw = 2.6). The experimental work was complemented by numerical Monte Carlo simulations of anomalous ECS diffusion in several three-dimensional tissue models containing glomeruli-like structures. It demonstrated that both the duration of transiently anomalous diffusion and the anomalous exponent depend on the size of model glomeruli and the degree of their wrapping. In conclusion, we have found anomalous extracellular diffusion in the GL of rat cerebellum. This finding lends support to the DS microdomain hypothesis. Transiently anomalous diffusion also has a profound effect on the spatiotemporal distribution of molecules released into the ECS, especially at diffusion distances on the order of a few cell diameters, speeding up short-range diffusion-mediated signals in less permeable

  6. Rate dependent of strength in metallic glasses at different temperatures

    Science.gov (United States)

    Wang, Y. W.; Bian, X. L.; Wu, S. W.; Hussain, I.; Jia, Y. D.; Yi, J.; Wang, G.

    2016-06-01

    The correlation between the strength at the macroscale and the elastic deformation as well as shear cracking behavior at the microscale of bulk metallic glasses (BMGs) is investigated. The temperatures of 298 K and 77 K as well as the strain rate ranging from 10‑6 s‑1 to 10‑2 s‑1 are applied to the BMGs, in which the mechanical responses of the BMGs are profiled through the compression tests. The yield strength is associated with the activation of the elementary deformation unit, which is insensitive to the strain rate. The maximum compressive strength is linked to the crack propagation during shear fracture process, which is influenced by the strain rate. The cryogenic temperature of 77 K significantly improves the yield strength and the maximum compressive strength of the BMGs.

  7. Temperature-dependent high resolution absorption cross sections of propane

    Science.gov (United States)

    Beale, Christopher A.; Hargreaves, Robert J.; Bernath, Peter F.

    2016-10-01

    High resolution (0.005 cm-1) absorption cross sections have been measured for pure propane (C3H8). These cross sections cover the 2550-3500 cm-1 region at five temperatures (from 296 to 700 K) and were measured using a Fourier transform spectrometer and a quartz cell heated by a tube furnace. Calibrations were made by comparison to the integrated cross sections of propane from the Pacific Northwest National Laboratory. These are the first high resolution absorption cross sections of propane for the 3 μm region at elevated temperatures. The cross sections provided may be used to monitor propane in combustion environments and in astronomical sources such as the auroral regions of Jupiter, brown dwarfs and exoplanets.

  8. The temperature dependence of the friction in the fission

    Energy Technology Data Exchange (ETDEWEB)

    Yamaji, Shuhei [Institute of Physical and Chemical Research, Wako, Saitama (Japan)

    1996-03-01

    We study the slow collective motion at finite excitation on the basis of the linear response theory. The transport coefficients such as friction {gamma}, inertia M and local stiffness C formulated within a locally harmonic approximation are computed along the fission path of {sup 224}Th. It is found that the effective damping rate {eta} = {gamma}/=2{radical}(M|C|)= increases with the temperature T in accord with the fission experiment with the emission of {gamma}-rays. (author)

  9. The Temperature-Dependent Nature of Coronal Dimmings

    CERN Document Server

    Robbrecht, Eva

    2010-01-01

    The opening-up of the magnetic field during solar eruptive events is often accompanied by a dimming of the local coronal emission. From observations of filament eruptions recorded with the Extreme-Ultraviolet Imager on STEREO during 2008-2009, it is evident that these dimmings are much more pronounced in 19.5 nm than in the lower-temperature line 17.1 nm, as viewed either on the disk or above the limb. We conclude that most of the cooler coronal plasma is not ejected but remains gravitationally bound when the loops open up. This result is consistent with Doppler measurements by Imada and coworkers, who found that the upflow speeds in a transient coronal hole increased dramatically above a temperature of 1 MK; it is also consistent with the quasistatic behavior of polar plumes, as compared with the hotter interplume regions that are the main source of the fast solar wind. When the open flux reconnects and closes down again, the trapped plasma is initially heated to such high temperatures that it is no longer v...

  10. Exponential temperature dependence of the resistivity, thermopower, and susceptibility of Y9Co7: Evidence for local mode (abstract)

    Science.gov (United States)

    Sarkissian, B. V. B.

    1985-04-01

    The magnetic superconductor Y9Co7 is unique in that its magnetism coexists with superconductivity at a temperature (˜5.5 K) before it transforms into the superconducting state at a lower temperature (˜2.7 K) [B. V. B. Sarkissian, J. Appl. Phys. 53, 8070 (1982)]. There is now ample evidence that the compound has a puzzling array of magnetic properties. The magnetism is consistent with the lack of long-range order, and shows some evidence of dominant incipient ferromagnetic ordering. Apart from these striking effects this compound shows anomalous temperature dependence in a variety of physical properties at high temperatures, in particular, the ``saturation'' of the resistivity and thermopower with increasing temperature and marked departure of the susceptibility from the usual Curie-Weiss behavior. The conventional view of these effects is that the resistivity and the thermopower anomalies are a consequence of the s-d scattering mechanism [E. Gratz et al., J. Magn. Magn. Mater. 21, 191 (1980)], whereas the magnetic susceptibility is viewed as a composite of a Curie-Weiss and a temperature independent part [A. Kolodziejczyk and J. Spalek, J. Phys. F 14, 1277 (1984)]. We have carried out measurements of the variation in resistivity, thermopower, and susceptibility with temperature in Y9Co7. All the results show a temperature dependence dominated by an exponential-type behavior with a well-defined characteristic temperature. The latter defines the crossover from the region dominated by strong T dependence to that dominated by weak T dependence. The presence of similar unusual high T properties in many intermetallic compounds—particularly the A15 compounds—has been evident for many years. Many of them show one or more of the properties of the Y9Co7; however, at lower temperatures their behavior differs considerably from that of Y9Co7. In interpreting the anomalous exponential behavior shown by Y9Co7 a mechanism, closely related to localized phonon mode formation

  11. Time and temperature dependences of the magnetization reversal in a Co /Pd multilayer film

    Science.gov (United States)

    Brown, C. Scott; Harrell, J. W.; Matsunuma, S.

    2006-09-01

    The time and temperature dependences of the magnetization reversal have been measured in a high-coercivity Co /Pd multilayer film characterized by nucleation and domain wall motion. The time and field dependences of magnetic relaxation curves at room temperature were interpreted in terms of an energy barrier that depends linearly on reverse field, suggesting a Sharrock-type [M. P. Sharrock and J. T. McKinney, IEEE Trans. Magn. 17, 3020 (1981)] equation for the time and temperature dependences of coercivity with unity exponent. The sweep rate and temperature dependence of the coercivity were analyzed using the Sharrock equation to obtain the temperature dependence of the intrinsic, short-time coercivity H0 and the zero-field energy barrier E0. A single power law behavior was found for H0 versus the saturation magnetization Ms.

  12. Exact conditions on the temperature dependence of density functionals

    CERN Document Server

    Burke, Kieron; Grabowski, Paul E; Pribram-Jones, Aurora

    2015-01-01

    Universal exact conditions guided the construction of most ground-state density functional approximations in use today. We derive the relation between the entropy and Mermin free energy density functionals for thermal density functional theory. Both the entropy and sum of kinetic and electron-electron repulsion functionals are shown to be monotonically increasing with temperature, while the Mermin functional is concave downwards. Analogous relations are found for both exchange and correlation. The importance of these conditions is illustrated in two extremes: the Hubbard dimer and the uniform gas.

  13. Anomalous near-field heat transfer between a cylinder and a perforated surface

    OpenAIRE

    Rodriguez, Alejandro W.; Reid, M. T. Homer; Varela, Jaime; Joannopoulos, John D.; Capasso, Federico; Johnson, Steven G.

    2012-01-01

    We predict that the radiative heat-transfer rate between a cylinder and a perforated surface depends non-monotonically on their separation. This anomalous behavior, which arises due to near-field effects, is explained using a heuristic model based on the interaction of a dipole with a plate. We show that nonmonotonicity depends not only on geometry and temperature but also on material dispersion - for micron and submicron objects, nonmonotonicity is present in polar dielectrics but absent in ...

  14. Electrical conduction in polycrystalline CVD diamond: Temperature dependent impedance measurements

    Energy Technology Data Exchange (ETDEWEB)

    Ye, H.; Williams, O.A.; Jackman, R.B. [Electronic and Electrical Engineering, University College London, Torrington Place, London WC1E 7JE (United Kingdom); Rudkin, R.; Atkinson, A. [Department of Materials, Imperial College London, South Kensington, London SW7 2AZ (United Kingdom)

    2002-10-16

    In this paper, we report the first measurement of impedance on freestanding diamond films from 0.1 Hz to 10 MHz up to 300 C. A wide range of CVD materials have been investigated, but here we concentrate on 'black' diamond grown by MWPECVD. The Cole-Cole (Z' via Z{sup ''}) plots are well fitted to a RC parallel circuit model and the equivalent resistance and capacitance for the diamond films have been estimated using the Zview curve fitting. The results show only one single semicircle response at each temperature measured. It was found that the resistance decreases from 62 M{omega} at room temperature to 4 k{omega} at 300 C, with an activation energy around 0.51 eV. The equivalent capacitance is maintained at the level of 10{sup 2} pF up to 300 C, suggesting that the diamond grain boundaries are dominating the conduction. At 400 C, the impedance at low frequencies shows a linear tail, which can be explained that the ac polarization of diamond/Au interface occurs. (Abstract Copyright [2002], Wiley Periodicals, Inc.)

  15. Seafloor Weathering Dependence on Temperature and Dissolved Inorganic Carbon

    Science.gov (United States)

    Abbot, D. S.; Farahat, N. X.; Archer, D. E.

    2015-12-01

    Most thinking on Earth's carbon cycle implicates silicate weathering as the dominant control of atmospheric CO2 concentration over long timescales. Recent analyses of alteration of basalt at the seafloor, however, suggest that seafloor weathering (low-temperature (type of weathering available on an exoplanet entirely covered by water, so understanding how it might work is essential for understanding the habitable zones of such waterworlds. We have built a 2D numerical model of the flow of seawater through porous basalt coupled to chemical alteration reactions that can calculate alkalinity fluxes and carbonate deposition (seafloor weathering). I will present simulations in which we vary the seawater temperature and dissolved inorganic carbon concentration, which are boundary conditions to our model, over large ranges. These results will provide a constraint on the ability of seafloor weathering to act as an effective climate buffer on Earth and other planets. I can't give you a preview of the results yet because at the time of writing this abstract we haven't completed the simulations!

  16. Temperature Dependence on The Synthesis of Jatropha Biolubricant

    Science.gov (United States)

    Gunam Resul, Muhammad Faiz M.; Idaty Mohd Ghazi, Tinia; Idris, Azni

    2011-02-01

    Jatropha oil has good potential as the renewable energy as well as lubricant feedstock. The synthesis of jatropha biolubricant was performed by transesterification of jatropha methyl ester (JME) with trimethyl-ol-propane (TMP) with sodium methoxide (NaOCH3) catalyst. The effects of temperature on the synthesis were studied at a range between 120°C and 200°C with pressure kept at 10mbar. The conversion of JME to jatropha biolubricant was found to be the highest (47%) at 200°C. However, it was suggested that the optimum temperature of the reaction is at 150°C due to insignificant improvement in biolubricant production. To maintain forward reaction, the excess amount of JME was maintained at 3.9:1 ratios to TMP. Kinetic study was done and compared. The synthesis was found to follow a second order reaction with overall rate constant of 1.49 × 10-1 (%wt/wt.min.°C)-1. The estimated activation energy was 3.94 kJ/mol. Pour point for jatropha biolubricant was at -3°C and Viscosity Index (VI) ranged from 178 to 183. The basic properties of jatropha biolubricant, pour point and viscosities are found comparable to other plant based biolubricant, namely palm oil and soybean based biolubricant.

  17. Temperature Dependence on The Synthesis of Jatropha Biolubricant

    Energy Technology Data Exchange (ETDEWEB)

    Resul, Muhammad Faiz M Gunam; Ghazi, Tinia Idaty Mohd; Idris, Azni, E-mail: tinia@eng.upm.edu.my [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia)

    2011-02-15

    Jatropha oil has good potential as the renewable energy as well as lubricant feedstock. The synthesis of jatropha biolubricant was performed by transesterification of jatropha methyl ester (JME) with trimethyl-ol-propane (TMP) with sodium methoxide (NaOCH3) catalyst. The effects of temperature on the synthesis were studied at a range between 120 deg. C and 200 deg. C with pressure kept at 10mbar. The conversion of JME to jatropha biolubricant was found to be the highest (47%) at 200 deg. C. However, it was suggested that the optimum temperature of the reaction is at 150 deg. C due to insignificant improvement in biolubricant production. To maintain forward reaction, the excess amount of JME was maintained at 3.9:1 ratios to TMP. Kinetic study was done and compared. The synthesis was found to follow a second order reaction with overall rate constant of 1.49 x 10-1 (%wt/wt.min.deg. C)-1. The estimated activation energy was 3.94 kJ/mol. Pour point for jatropha biolubricant was at -3 deg. C and Viscosity Index (VI) ranged from 178 to 183. The basic properties of jatropha biolubricant, pour point and viscosities are found comparable to other plant based biolubricant, namely palm oil and soybean based biolubricant.

  18. Temperature dependent simulation of diamond depleted Schottky PIN diodes

    Science.gov (United States)

    Hathwar, Raghuraj; Dutta, Maitreya; Koeck, Franz A. M.; Nemanich, Robert J.; Chowdhury, Srabanti; Goodnick, Stephen M.

    2016-06-01

    Diamond is considered as an ideal material for high field and high power devices due to its high breakdown field, high lightly doped carrier mobility, and high thermal conductivity. The modeling and simulation of diamond devices are therefore important to predict the performances of diamond based devices. In this context, we use Silvaco® Atlas, a drift-diffusion based commercial software, to model diamond based power devices. The models used in Atlas were modified to account for both variable range and nearest neighbor hopping transport in the impurity bands associated with high activation energies for boron doped and phosphorus doped diamond. The models were fit to experimentally reported resistivity data over a wide range of doping concentrations and temperatures. We compare to recent data on depleted diamond Schottky PIN diodes demonstrating low turn-on voltages and high reverse breakdown voltages, which could be useful for high power rectifying applications due to the low turn-on voltage enabling high forward current densities. Three dimensional simulations of the depleted Schottky PIN diamond devices were performed and the results are verified with experimental data at different operating temperatures

  19. Binary accretion rates: dependence on temperature and mass-ratio

    CERN Document Server

    Young, Matthew D

    2015-01-01

    We perform a series of 2D smoothed particle hydrodynamics (SPH) simulations of gas accretion onto binaries via a circumbinary disc, for a range of gas temperatures and binary mass ratios ($q$). We show that increasing the gas temperature increases the accretion rate onto the primary for all values of the binary mass ratio: for example, for $q=0.1$ and a fixed binary separation, an increase of normalised sound speed by a factor of $5$ (from our "cold" to "hot" simulations) changes the fraction of the accreted gas that flows on to the primary from $ 10\\%$ to $\\sim40\\%$. We present a simple parametrisation for the average accretion rate of each binary component accurate to within a few percent and argue that this parametrisation (rather than those in the literature based on warmer simulations) is relevant to supermassive black hole accretion and all but the widest stellar binaries. We present trajectories for the growth of $q$ during circumbinary disc accretion and argue that the period distribution of stellar "...

  20. Anomalous temperature variation of thermoelectric power in CdO and Ag{sub 2}O substituted lead vanadate glass system

    Energy Technology Data Exchange (ETDEWEB)

    Bhujanga Rao, Ch. [Department of Physics, Andhra University, Visakhapatnam 530 003, AP (India)]. E-mail: bhujang_rao@yahoo.com; Ramesh, K.V. [Department of Engineering physics, GITAM College Of Engineering, Rushikonda Visakhapatnam 530 045, AP (India)]. E-mail: kv_ramesh5@yahoo.co.in; Sastry, D.L. [Department of Physics, Andhra University, Visakhapatnam 530 003, AP (India)]. E-mail: sastry_dl@yahoo.co.in

    2006-06-15

    Thermoelectric power studies on eutectic lead vanadate glass system in which CdO or Ag{sub 2}O is substituted for PbO upto 15 mol% are reported in the temperature range 300-500 K. It was observed that while the un-substituted samples exhibit almost temperature-independent thermoelectric power, the CdO and Ag{sub 2}O substituted samples exhibit thermoelectric power with marked temperature dependence. The Ag{sub 2}O substituted samples remain n-type with an increase in the magnitude of thermoelectric power while the CdO substituted samples exhibit a change from n- to p-type as the temperature is increased. Application of Emin's formula gives a reasonable estimate of the disorder energy (W {sub D}) for Ag{sub 2}O substituted samples, while for CdO substituted samples the W {sub D} values obtained are supposed to be too large to be acceptable. These observations are discussed in the light of recently reported results on similar systems.

  1. Dynamic temperature dependence patterns in future energy demand models in the context of climate change

    NARCIS (Netherlands)

    Hekkenberg, M.; Moll, H.C.; Schoot Uiterkamp, A.J.M.

    2009-01-01

    Energy demand depends on outdoor temperature in a 'u' shaped fashion. Various studies have used this temperature dependence to investigate the effects of climate change on energy demand. Such studies contain implicit or explicit assumptions to describe expected socio-economic changes that may affect

  2. Dependence of electric strength on the ambient temperature

    Energy Technology Data Exchange (ETDEWEB)

    Čaja, Alexander, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk; Nemec, Patrik, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk; Malcho, Milan, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk [University of Žilina, Faculty of Mechanical Engineering, Department of Power Engeneering, Univerzitná 1, 010 26 Žilina (Slovakia)

    2014-08-06

    At present, the volume concentration of electronic components in their miniaturization to different types of microchips and increasing their performance raises the problem of cooling such elements due to the increasing density of heat flow of heat loss. Compliance with safe operating temperature of active semiconductor element is very closely related to the reliability and durability not only components, but also the entire device. Often it is also necessary to electrically isolate the unit from the side of the cooler air. Cooling demand by natural convection is typical for applications with high operating reliability. To the reliability of the system for removing heat loss increased, it is necessary to minimize need to use the mechanically or electrically powered elements, such as circulation pumps or fans. Experience to date with applications of heat pipe in specific systems appears to be the most appropriate method of cooling.

  3. Temperature Dependence of PMD of the Optical Cables

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, S.J. [Korea Electric Power Research Institute, Taejon (Korea)

    2000-03-01

    This report is relevant to the project {sup K}EPCO All-Optical Network Project{sup w}hich is being carried out by Computer and Communication Group in Power System Laboratory. This report is planned to be used as a reference guide for the PMD strategy of the KEPCO optical networks. The PMD of the optical cable installed in the air as OPGW is greatly affected by the environmental temperature change, unlike that of the optical cable installed underground. The variance was turned out to be 70% larger compared with that of underground optical cable and the time scale of the PMD was less than 5 min, in the worst case. Hence, the compensation technology should be chosen taking into account the properties of the aerial optical cables. (author). 6 refs., 3 figs., 1 tab.

  4. Dependence of electric strength on the ambient temperature

    International Nuclear Information System (INIS)

    At present, the volume concentration of electronic components in their miniaturization to different types of microchips and increasing their performance raises the problem of cooling such elements due to the increasing density of heat flow of heat loss. Compliance with safe operating temperature of active semiconductor element is very closely related to the reliability and durability not only components, but also the entire device. Often it is also necessary to electrically isolate the unit from the side of the cooler air. Cooling demand by natural convection is typical for applications with high operating reliability. To the reliability of the system for removing heat loss increased, it is necessary to minimize need to use the mechanically or electrically powered elements, such as circulation pumps or fans. Experience to date with applications of heat pipe in specific systems appears to be the most appropriate method of cooling

  5. Temperature dependence of the lowest excitonic transition for an InAs ultrathin quantum well

    Science.gov (United States)

    Singh, S. D.; Porwal, S.; Sharma, T. K.; Rustagi, K. C.

    2006-03-01

    Temperature dependent photoluminescence and photoreflectance techniques are used to investigate the lowest excitonic transition of InAs ultrathin quantum well. It is shown that the temperature dependence of the lowest energy transition follows the band gap variation of GaAs barrier, which is well reproduced by calculated results based on the envelope function approximation with significant corrections due to strain and temperature dependences of the confinement potential. A redshift in photoluminescence peak energy compared to photoreflectance is observed at low temperatures. This is interpreted to show that the photoluminescence signal originates from the recombination of carriers occupying the band-tail states below the lowest critical point.

  6. Simulation of Temperature-Dependent Charge Transport in Organic Semiconductors with Various Degrees of Disorder.

    Science.gov (United States)

    Heck, Alexander; Kranz, Julian J; Elstner, Marcus

    2016-07-12

    Different trends in the temperature dependence of the mobility can be observed in organic semiconductors, which constitutes a serious challenge for theoretical approaches. In this work, we apply an atomistic bottom-up simulation for the calculation of temperature-dependent mobilities of a broad selection of materials, ranging from single crystal to amorphous solid. We evaluate how well the method is able to distinguish temperature dependences of different materials and how the findings relate to experimental observations. The applied method is able to cover the full range of temperature dependencies from activated transport in amorphous materials to band-like transport in crystals. In well-characterized materials, we find good agreement with the experiment and a band-like temperature dependence. In less-ordered materials, we find discrepancies from the experiment that indicated that experimentally studied materials possess a higher degree of disorder than do the simulated defect-free morphologies. PMID:27224054

  7. Integrated optic current transducers incorporating photonic crystal fiber for reduced temperature dependence.

    Science.gov (United States)

    Chu, Woo-Sung; Kim, Sung-Moon; Oh, Min-Cheol

    2015-08-24

    Optical current transducers (OCT) are indispensable for accurate monitoring of large electrical currents in an environment suffering from severe electromagnetic interference. Temperature dependence of OCTs caused by its components, such as wave plates and optical fibers, should be reduced to allow temperature-independent operation. A photonic crystal fiber with a structural optical birefringence was incorporated instead of a PM fiber, and a spun PM fiber was introduced to overcome the temperature-dependent linear birefringence of sensing fiber coil. Moreover, an integrated optic device that provides higher stability than fiber-optics was employed to control the polarization and detect the phase of the sensed optical signal. The proposed OCT exhibited much lower temperature dependence than that from a previous study. The OCT satisfied the 0.5 accuracy class (IIEC 60044-8) and had a temperature dependence less than ± 1% for a temperature range of 25 to 78 °C.

  8. Temperature-dependence of detection efficiency in NbN and TaN SNSPD

    OpenAIRE

    Engel, Andreas; Inderbitzin, Kevin; Schilling, Andreas; Lusche, Robert; Semenov, Alexei; Hübers, Heinz-Wilhelm; Henrich, Dagmar; Hofherr, Matthias; Il'in, Konstantin; Siegel, Michael

    2012-01-01

    We present systematic measurements of the temperature-dependence of detection efficiencies in TaN and NbN superconducting nanowire single-photon detectors. We have observed a clear increase of the cut-off wavelength with decreasing temperature that we can qualitatively describe with a temperature-dependent diffusion coefficient of the quasi-particles created after photon absorption. Furthermore, the detection efficiency at wavelengths shorter than the cut-off wavelength as well as at longer w...

  9. Effect of interband interactions on the pressure dependence on transition temperature of MgB2

    Science.gov (United States)

    Ogbuu, Okechukwu A.; Abah, Obinna

    2015-12-01

    A two-band BCS model with interactions, both phonon and non-phonon induced interactions, were employed to investigate the pressure dependence on superconducting transition temperature of two-band superconductor. We derived the transition temperature and its pressure dependence within Bogoliubov--Valatin formalism for magnesium diboride superconductor. We examined the influence of interband interactions on transition temperature at varying pressure and analyzed the relevance of this calculation in magnesium diboride, MgB2.

  10. A Temperature-Dependent Thermal Model of IGBT Modules Suitable for Circuit-Level Simulations

    OpenAIRE

    Wu, Rui; Wang, Huai; Ma, Ke; Ghimire, Pramod; Iannuzzo, Francesco; Blaabjerg, Frede

    2014-01-01

    Thermal impedance of IGBT modules may vary with operating conditions due to that the thermal conductivity and heat capacity of materials are temperature dependent. This paper proposes a Cauer thermal model for a 1700 V/1000 A IGBT module with temperature-dependent thermal resistances and thermal capacitances. The temperature effect is investigated by Finite Element Method (FEM) simulation based on the geometry and material information of the IGBT module. The developed model is ready for circu...

  11. Temperature dependent electron Lande g-factor and interband matrix element in GaAs

    Energy Technology Data Exchange (ETDEWEB)

    Huebner, Jens; Doehrmann, Stefanie; Haegele, Daniel; Oestreich, Michael [Institute for Solid State Physics, Gottfried Wilhelm Leibniz University Hannover (Germany)

    2007-07-01

    High precision measurements of the electron Lande g-factor in GaAs are presented using spin quantum beat spectroscopy at low excitation densities and temperatures ranging from 2.6 to 300 K. Influences of nuclear spin polarization at low temperatures have been fully compensated. Comparing these measurements with available data for the temperature dependent effective mass reveals an unexpected strong temperature dependence of the interband matrix element and resolves a long lasting discrepancy between experiment and kp - theory. The strong decrease of the interband matrix element with increasing temperature is explained by phonon induced fluctuations of the interatomic spacing and adiabatic following of the electrons.

  12. Temperature-Dependent Diffusion Coefficients from ab initio Computations: Hydrogen in Nickel

    Energy Technology Data Exchange (ETDEWEB)

    E Wimmer; W Wolf; J Sticht; P Saxe; C Geller; R Najafabadi; G Young

    2006-03-16

    The temperature-dependent mass diffusion coefficient is computed using transition state theory. Ab initio supercell phonon calculations of the entire system provide the attempt frequency, the activation enthalpy, and the activation entropy as a function of temperature. Effects due to thermal lattice expansion are included and found to be significant. Numerical results for the case of hydrogen in nickel demonstrate a strong temperature dependence of the migration enthalpy and entropy. Trapping in local minima along the diffusion path has a pronounced effect especially at low temperatures. The computed diffusion coefficients with and without trapping bracket the available experimental values over the entire temperature range between 0 and 1400 K.

  13. Temperature Dependence of Short-Range Order in β-Brass

    DEFF Research Database (Denmark)

    Dietrich, O.W.; Als-Nielsen, Jens Aage

    1967-01-01

    Critical scattering of neutrons around the superlattice reflections (1, 0, 0) and (1, 1, 1) from a single crystal of beta-brass has been measured at temperatures from 2 to 25deg C above the transition temperature. The temperature dependence of the critical peak intensity, proportional to the susc...

  14. A simple equation for describing the temperature dependent growth of free-floating macrophytes

    NARCIS (Netherlands)

    Heide, van Tj.; Roijackers, R.M.M.; Nes, van E.H.; Peeters, E.T.H.M.

    2006-01-01

    Temperature is one of the most important factors determining growth rates of free-floating macrophytes in the field. To analyse and predict temperature dependent growth rates of these pleustophytes, modelling may play an important role. Several equations have been published for describing temperatur

  15. Fiber-optic temperature sensor based on interaction of temperature-dependent refractive index and absorption of germanium film.

    Science.gov (United States)

    Li, Min; Li, Yulin

    2011-01-10

    The interaction of a large temperature-dependent refractive index and a temperature-dependent absorption of semiconductor materials at 1550 nm can be used to build a very sensitive, film coated fiber-optic temperature probe. We developed a sensor model for the optical fiber-germanium film sensor. A temperature sensitivity of reflectivity change of 0.0012/°C, corresponding to 0.1°C considering a moderate signal processing system, over 100°C within the temperature regime of -20°C to 120°C, has been demonstrated by experimental tests of the novel sensor. The potential sensitivity and further applications of the sensor are discussed. PMID:21221150

  16. Nuclear Quadrupole Double Resonance Investigation of the Anomalous Temperature Coefficients of the Strong Hydrogen Bonds in Sodium and Potassium Deuterium Diacetate.

    Science.gov (United States)

    Shaw, Eric Max

    This thesis was directed at learning more about the unusual electronic environment near hydrogen within strong hydrogen bonds. "Strong" hydrogen bonds are unique in that the hydrogen atom is symmetrically located, or nearly so, between two electronegative atoms; the bond energies are relatively large. In a "normal" hydrogen bond the hydrogen atom is bonded to, and thus physically closer to, a parent atom, and only weakly attracted to another electronegative atom; bond energies are typically small. To examine these bonds, deuterium was substituted for hydrogen and the electric quadrupole coupling constant (QCC) of deuterium was measured using field cycling nuclear magnetic resonance. The electric quadrupole moment of deuterium is sensitive to changes in the surrounding electric field gradient, and is thus a good probe of the immediate electronic structure. The results show that the temperature dependence of the QCC is opposite to, and much larger than, what one would normally expect to observe for deuterium. The QCC is found to decrease strongly with decreasing temperature. This project was the first to study in detail the temperature dependence of deuterium QCCs in strong hydrogen bonds. The magnitude of the deuterium QCCs for the diacetates was found to be strongly depressed relative to typical values for deuterium. These results parallel large shifts in the infrared vibrational frequencies observed in many molecules which contain strong hydrogen bonds. The asymmetry parameter, which is a measure of the departure from axial symmetry of the electric field gradient (EFG) at deuterium, was found to be unusually large for what are known to be linear, or nearly linear, three-center bonds. Based on ab initio Hartree-Fock calculations aimed at determining the EFG at H in the archetypal bifluoride ion, F-H-F^-, the electronic charge density is drastically depleted at H. It is believed that the large reduction in the charge density allows the deuterium EFG to be highly

  17. Wall temperature measurements using a thermal imaging camera with temperature-dependent emissivity corrections

    International Nuclear Information System (INIS)

    A methodology is presented whereby the relationship between temperature and emissivity for fused quartz has been used to correct the temperature values of a quartz impingement plate detected by an SC3000 thermal imaging camera. The methodology uses an iterative method using the initial temperature (obtained by assuming a constant emissivity) to find the emissivity values which are then put into the thermal imaging software and used to find the subsequent temperatures, which are used to find the emissivities, and so on until converged. This method is used for a quartz impingement plate that has been heated under various flame conditions, and the results are compared. Radiation losses from the plate are also calculated, and it is shown that even a slight change in temperature greatly affects the radiation loss. It is a general methodology that can be used for any wall material whose emissivity is a function of temperature

  18. Temperature dependence of amino acid side chain IR absorptions in the amide I' region.

    Science.gov (United States)

    Anderson, Benjamin A; Literati, Alex; Ball, Borden; Kubelka, Jan

    2014-05-01

    Amide I' IR spectra are widely used for studies of structural changes in peptides and proteins as a function of temperature. Temperature dependent absorptions of amino acid side-chains that overlap the amide I' may significantly complicate the structural analyses. While the side-chain IR spectra have been investigated previously, thus far their dependence on temperature has not been reported. Here we present the study of the changes in the IR spectra with temperature for side-chain groups of aspartate, glutamate, asparagine, glutamine, arginine, and tyrosine in the amide I' region (in D2O). Band fitting analysis was employed to extract the temperature dependence of the individual spectral parameters, such as peak frequency, integrated intensity, band width, and shape. As expected, the side-chain IR bands exhibit significant changes with temperature. The majority of the spectral parameters, particularly the frequency and intensity, show linear dependence on temperature, but the direction and magnitude vary depending on the particular side-chain group. The exception is arginine, which exhibits a distinctly nonlinear frequency shift with temperature for its asymmetric CN3H5(+) bending signal, although a linear fit can account for this change to within ~1/3 cm(-1). The applicability of the determined spectral parameters for estimations of temperature-dependent side-chain absorptions in peptides and proteins are discussed.

  19. The charmonium dissociation in an "anomalous wind"

    CERN Document Server

    Sadofyev, Andrey V

    2016-01-01

    We study the charmonium dissociation in a strongly coupled chiral plasma in the presence of magnetic field and axial charge imbalance. This type of plasma carries ``anomalous flow" induced by the chiral anomaly and exhibits novel transport phenomena such as chiral magnetic effect. We found that the ``anomalous flow" would modify the charmonium color screening length by using the gauge/gravity correspondence. We derive an analytical expression quantifying the ``anomalous flow" experienced by a charmonium for a large class of chiral plasma with a gravity dual. We elaborate on the similarity and {\\it qualitative} difference between anomalous effects on the charmonium color screening length which are {\\it model-dependent} and those on the heavy quark drag force which are fixed by the second law of thermodynamics. We speculate on the possible charmonium dissociation induced by chiral anomaly in heavy ion collisions.

  20. Fluctuating temperatures and ectotherm growth: distinguishing non-linear and time-dependent effects.

    Science.gov (United States)

    Kingsolver, Joel G; Higgins, Jessica K; Augustine, Kate E

    2015-07-01

    Most terrestrial ectotherms experience diurnal and seasonal variation in temperature. Because thermal performance curves are non-linear, mean performance can differ in fluctuating and constant thermal environments. However, time-dependent effects--effects of the order and duration of exposure to temperature--can also influence mean performance. We quantified the non-linear and time-dependent effects of diurnally fluctuating temperatures for larval growth rates in the tobacco hornworm, Manduca sexta L., with four main results. First, the shape of the thermal performance curve for growth rate depended on the duration of exposure: for example, optimal temperature and thermal breadth were greater for growth rates measured over short (24 h during the last instar) compared with long (the entire period of larval growth) time periods. Second, larvae reared in diurnally fluctuating temperatures had significantly higher optimal temperatures and maximal growth rates than larvae reared in constant temperatures. Third, for larvae maintained at three mean temperatures (20, 25 and 30°C) and three diurnal temperature ranges (±0, ±5 and ±10°C), diurnal fluctuations had opposite effects on mean growth rates at low versus high mean temperature. Fourth, both short- and long-term thermal performance curves yielded poor predictions of the non-linear effects of fluctuating temperature on mean growth rates (compared with our experimental results) at higher mean temperatures. Our results suggest caution in using constant temperature studies to model the consequences of variable thermal environments. PMID:25987738

  1. Large anomalous Hall effect driven by a nonvanishing Berry curvature in the noncolinear antiferromagnet Mn3Ge.

    Science.gov (United States)

    Nayak, Ajaya K; Fischer, Julia Erika; Sun, Yan; Yan, Binghai; Karel, Julie; Komarek, Alexander C; Shekhar, Chandra; Kumar, Nitesh; Schnelle, Walter; Kübler, Jürgen; Felser, Claudia; Parkin, Stuart S P

    2016-04-01

    It is well established that the anomalous Hall effect displayed by a ferromagnet scales with its magnetization. Therefore, an antiferromagnet that has no net magnetization should exhibit no anomalous Hall effect. We show that the noncolinear triangular antiferromagnet Mn3Ge exhibits a large anomalous Hall effect comparable to that of ferromagnetic metals; the magnitude of the anomalous conductivity is ~500 (ohm·cm)(-1) at 2 K and ~50 (ohm·cm)(-1) at room temperature. The angular dependence of the anomalous Hall effect measurements confirms that the small residual in-plane magnetic moment has no role in the observed effect except to control the chirality of the spin triangular structure. Our theoretical calculations demonstrate that the large anomalous Hall effect in Mn3Ge originates from a nonvanishing Berry curvature that arises from the chiral spin structure, and that also results in a large spin Hall effect of 1100 (ħ/e) (ohm·cm)(-1), comparable to that of platinum. The present results pave the way toward the realization of room temperature antiferromagnetic spintronics and spin Hall effect-based data storage devices. PMID:27152355

  2. Large anomalous Hall effect driven by a nonvanishing Berry curvature in the noncolinear antiferromagnet Mn3Ge.

    Science.gov (United States)

    Nayak, Ajaya K; Fischer, Julia Erika; Sun, Yan; Yan, Binghai; Karel, Julie; Komarek, Alexander C; Shekhar, Chandra; Kumar, Nitesh; Schnelle, Walter; Kübler, Jürgen; Felser, Claudia; Parkin, Stuart S P

    2016-04-01

    It is well established that the anomalous Hall effect displayed by a ferromagnet scales with its magnetization. Therefore, an antiferromagnet that has no net magnetization should exhibit no anomalous Hall effect. We show that the noncolinear triangular antiferromagnet Mn3Ge exhibits a large anomalous Hall effect comparable to that of ferromagnetic metals; the magnitude of the anomalous conductivity is ~500 (ohm·cm)(-1) at 2 K and ~50 (ohm·cm)(-1) at room temperature. The angular dependence of the anomalous Hall effect measurements confirms that the small residual in-plane magnetic moment has no role in the observed effect except to control the chirality of the spin triangular structure. Our theoretical calculations demonstrate that the large anomalous Hall effect in Mn3Ge originates from a nonvanishing Berry curvature that arises from the chiral spin structure, and that also results in a large spin Hall effect of 1100 (ħ/e) (ohm·cm)(-1), comparable to that of platinum. The present results pave the way toward the realization of room temperature antiferromagnetic spintronics and spin Hall effect-based data storage devices.

  3. Silicon carbide powders: Temperature-dependent dielectric properties and enhanced microwave absorption at gigahertz range

    Science.gov (United States)

    Yang, Hui-Jing; Yuan, Jie; Li, Yong; Hou, Zhi-Ling; Jin, Hai-Bo; Fang, Xiao-Yong; Cao, Mao-Sheng

    2013-06-01

    The dielectric properties of SiC powders are investigated in the temperature range of 373-773 K at gigahertz range (8.2-12.4 GHz). The complex permittivity ɛ and the loss tgδ exhibit frequency-dependent characteristics with the frequency, and they also show temperature-dependent characteristic with the temperature. From the Cole-Cole plots, the relaxation and electrical conductance both affect the dielectric properties at high temperature. First principle calculations are employed to analyze the electronic structure of SiC, which infer the influence of relaxation and conductance on dielectric behaviors. The reflection loss RL peak is below -10 dB in temperatures of 373-773 K with the sample in thickness 2.1 mm. More importantly, the microwave absorption coupled with widening effective absorption bandwidth demonstrates positive temperature effects on the absorption with the increasing temperature, indicating promising potential applications in high-temperature microwave absorption fields.

  4. The effect of temperature dependent tissue parameters on acoustic radiation force induced displacements

    CERN Document Server

    Suomi, Visa; Konofagou, Elisa; Cleveland, Robin

    2016-01-01

    Multiple ultrasound elastography techniques rely on acoustic radiation force (ARF) in monitoring high-intensity focused ultrasound (HIFU) therapy. However, ARF is dependent on tissue attenuation and sound speed, both of which are also known to change with temperature making the therapy monitoring more challenging. Furthermore, the viscoelastic properties of tissue are also temperature dependent, which affects the displacements induced by ARF. The aim of this study is to quantify the temperature dependent changes in the acoustic and viscoelastic properties of liver and investigate their effect on ARF induced displacements by using both experimental methods and simulations. Furthermore, the temperature dependent viscoelastic properties of liver are experimentally measured over a frequency range of 0.1-200 Hz at temperatures reaching 80 C, and both conventional and fractional Zener models are used to fit the data. The fractional Zener model was found to fit better with the experimental viscoelasticity data with ...

  5. Anomalous role change of tertiary amino and ester groups as hydrogen acceptors in eudragit E based solid dispersion depending on the concentration of naproxen.

    Science.gov (United States)

    Ueda, Hiroshi; Wakabayashi, Shinobu; Kikuchi, Junko; Ida, Yasuo; Kadota, Kazunori; Tozuka, Yuichi

    2015-04-01

    Eudragit E (EGE) is a basic polymer incorporating tertiary amino and ester groups. The role of the functional groups of EGE in the formation of solid dispersion (SD) with Naproxen (NAP) was investigated. The glass transition temperature (Tg) of EGE decreased with the plasticizing effect of NAP up to 20% weight ratio. Addition of NAP at over 30% induced a rise in Tg, with the maximum value being reached at 60% NAP. Further addition of NAP led to a rapid drop of the Tg. A dramatic difference of physical stability between the SDs including 60 and 70% NAP was confirmed. The SD including 70% NAP rapidly crystallized at 40 °C with 75% relative humidity, while the amorphous state could be maintained over 6 months in the SD with 60% NAP. The infrared and (13)C solid state-NMR spectra of the SDs suggested a formation of ionic interaction between the carboxylic acid of NAP and the amino group of EGE. The SD with 20% NAP raised the (13)C spin-lattice relaxation (T1) of the amino group, but it decreased with over 30% NAP. The change in the (13)C-T1 disappeared with 70% NAP. The (13)C-T1 of the ester group rose depending on the amount of NAP. From these findings, we concluded that the role as hydrogen acceptor shifted from the amine to the ester group with an increase in amount of NAP. Furthermore, the amino group of EGE did not contribute to the interaction at over 70% NAP. These phenomena could be strongly correlated with Tg and stability.

  6. Temperature dependence calibration and correction of the DAMPE BGO electromagnetic calorimeter

    Science.gov (United States)

    Wei, Y. F.; Zhang, Z. Y.; Zhang, Y. L.; Wen, S. C.; Wang, C.; Li, Z. Y.; Feng, C. Q.; Wang, X. L.; Xu, Z. Z.; Huang, G. S.; Liu, S. B.

    2016-07-01

    A BGO electromagnetic calorimeter (ECAL) is built for the DArk Matter Particle Explorer (DAMPE) mission. The temperature effect on the BGO ECAL was investigated with a thermal vacuum experiment. The light output of a BGO crystal depends on temperature significantly, and the readout system is also affected by temperature. The temperature coefficient of each BGO detection unit has been calibrated, and a correction method is also presented in this paper.

  7. Temperature-dependent photocarrier recombination dynamics in Cu[2]ZnSnS[4] single crystals

    OpenAIRE

    Phuong, Le Quang; Okano, Makoto; Yamada, Yasuhiro; Nagaoka, Akira; Yoshino, Kenji; Kanemitsu, Yoshihiko

    2014-01-01

    Time-resolved photoluminescence (PL) measurements have been used to study the temperature-dependent photocarrier recombination dynamics in Cu[2]ZnSnS[4] (CZTS) single crystals. We found a significant change of nearly four orders of magnitude of the PL decay time, from microseconds at low temperatures to subnanoseconds at room temperature. The slow PL decay at low temperatures indicates localization of the photocarriers at the band tails. Due to the large band tail states, the PL decay time de...

  8. A unified model for temperature dependent electrical conduction in polymer electrolytes

    OpenAIRE

    Mikrajuddin; Lenggoro, I. Wuled; Okuyama, Kikuo

    2001-01-01

    The observed temperature dependence of electrical conduction in polymer electrolytes is usually fitted with two separated equations: an Arrhenius equation at low temperatures and Vogel-Tamman-Fulcher (VTF) at high temperatures. We report here a derivation of a single equation to explain the variation of electrical conduction in polymer electrolytes at all temperature ranges. Our single equation is in agreement with the experimental data

  9. Study of the Energy Dependence of the Anomalous Mean Free Path Effect by Means of High-energy ($\\geq$12 GeV/nucleon) Helium Nuclei

    CERN Multimedia

    2002-01-01

    The proposal concerns an extension to higher energies of previous experiments which have provided evidence for anomalously short reaction mean free paths among projectile fragments from heavy ion interactions.\\\\ \\\\ It is intended to provide information on the interaction properties of projectile fragments, mainly 3He, P, D, T as well as of scattered 4He nuclei in passive detectors exposed to beams of energies exceeding those available in previous experim factor of about 7. \\\\ \\\\ Interaction mean free paths and event topologies will be measured in a nuclear emulsion stack (LBL) of 7.5~cm~x~5~cm~x~25~cm dimensions. Decay effects will be recorded by comparing the activity of spallation residues in dense and diluted copper target assemblies (Marburg). Target fragmentation will be studied in a stack of silverchloride crystal foils (Frankfurt) of about 7~cm~x~6~cm~x~1~cm dimensions. The \\alpha beam ejected at EJ~62 will be used to provide both exposures at high intensity of 10|1|2 alphas on th and at low intensity ...

  10. Analysis of polysilicon micro beams buckling with temperature-dependent properties

    CERN Document Server

    Shamshirsaz, M; Asgari, M B; Tayefeh, M

    2008-01-01

    The suspended electrothermal polysilicon micro beams generate displacements and forces by thermal buckling effects. In the previous electro-thermal and thermo-elastic models of suspended polysilicon micro beams, the thermo-mechanical properties of polysilicon have been considered constant over a wide rang of temperature (20- 900 degrees C). In reality, the thermo-mechanical properties of polysilicon depend on temperature and change significantly at high temperatures. This paper describes the development and validation of theoretical and Finite Element Model (FEM) including the temperature dependencies of polysilicon properties such as thermal expansion coefficient and Young's modulus. In the theoretical models, two parts of elastic deflection model and thermal elastic model of micro beams buckling have been established and simulated. Also, temperature dependent buckling of polysilicon micro beam under high temperature has been modeled by Finite Element Analysis (FEA). Analytical results and numerical results ...

  11. Anomalous ionic conductivity of Sc sub 2 (WO sub 4) sub 3 mediated by structural changes at high pressures and temperatures

    CERN Document Server

    Secco, R A; Imanaka, N; Adachi, G

    2002-01-01

    The ionic conductivity of Sc sub 2 (WO sub 4) sub 3 at 400 deg. C shows a normal decrease with increase in pressure up to 2.9 GPa but then increases anomalously at pressures up to 4.3 GPa. Synchrotron in situ x-ray diffraction results show that Sc sub 2 (WO sub 4) sub 3 undergoes pressure-induced amorphization at pressures coincident with the reversal in conductivity behaviour. The loss of crystal structure at high pressure may be associated with the property of negative thermal expansion in Sc sub 2 (WO sub 4) sub 3.

  12. On the Limitations of the Anomalous Microwave Emission Emissivity

    OpenAIRE

    Roberta Paladini; Tibbs, Christopher T.; Clive Dickinson

    2012-01-01

    Many studies of anomalous microwave emission (AME) have computed an AME emissivity to compare the strength of the AME detected in different regions. Such a value is usually defined as the ratio between the intensity of the AME at 1 cm and the thermal dust emission at 100 \\mu m. However, as studies of Galactic dust emission have shown, the intensity of the thermal dust emission at 100 \\mu m is strongly dependent on the dust temperature, which has severe implications for the AME emissivity defi...

  13. Temperature Dependence of the Raman Spectra and Phase Transition of Zirconia

    Institute of Scientific and Technical Information of China (English)

    尤静林; 蒋国昌; 杨松华; 马金昌; 徐匡迪

    2001-01-01

    A newly constructed high-temperature Raman spectrometer was used to study the temperature-dependence Raman spectra (up to 2023 K) and transformation of zirconia crystal. High-temperature Raman scattering is a useful tool in characterizing the different structures of zirconia and offers the possibility of identifying the phase transformation. It shows that monoclinic zirconia transforms to tetragonal phase at about 1440 K during the process of increasing temperature, but shows a lower transformation temperature from tetragonal to monoclinic phase at about 1323 K while the temperature decreases.

  14. Temperature dependence of photoluminescence from ordered GaInP{sub 2} epitaxial layers

    Energy Technology Data Exchange (ETDEWEB)

    Prutskij, T. [Instituto de Ciencias, BUAP, Apartado Postal 207, 72000 Puebla, Pue. (Mexico); Pelosi, C. [IMEM/CNR, Parco Area delle Scienze 37/A, 43010 Parma (Italy)

    2010-01-15

    The temperature behavior of the integrated intensity of photoluminescence (PL) emission from ordered GaInP{sub 2} epitaxial layer was measured at temperatures of 10 - 300 K. Within this temperature range the PL emission is dominated by band-to-band radiative recombination. The PL intensity temperature dependence has two regions: at low temperatures it quenches rapidly as the temperature increases, and above 100 K it reduces slowly. This temperature behavior is compared with that of disordered GaInP{sub 2} layer. The specter of the PL emission of the disordered layer has two peaks, which are identified as due to donor-accepter (D-A) and band-to-band recombination. The PL intensity quenching of these spectral bands is very different: With increasing temperature, the D-A peak intensity remains almost unchanged at low temperatures and then decreases at a higher rate. The intensity of the band-to-band recombination peak decays gradually, having a higher rate at low temperatures than at higher temperatures. Comparing these temperature dependencies of these PL peaks of ordered and disordered alloys and the temperature behavior of their full width at half maximum (FWHM), we conclude that the different morphology of these alloys causes their different temperature behavior. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Topological Defects in Double Exchange Materials and Anomalous Hall Resistance.

    Science.gov (United States)

    Calderón, M. J.; Brey, L.

    2000-03-01

    Recently it has been proposed that the anomalous Hall effect observed in Double Exchange materials is due to Berry phase effects caused by carrier hopping in a nontrivial spins background (J.Ye et al.) Phys.Rev.Lett. 83, 3737 1999.In order to study this possibility we have performed Monte Carlo simulations of the Double Exchange model and we have computed, as a function of the temperature, the number of topological defects in the system and the internal gauge magnetic field associated with these defects. In the simplest Double Exchange model the gauge magnetic field is random, and its average value is zero. The inclusion in the problem of spin-orbit coupling privileges the opposite direction of the magnetization and an anomalous Hall resistance (AHR) effect arises. We have computed the AHR, and we have obtained its temperature dependence. In agreement with previous experiments we obtain that AHR increases exponentially at low temperature and presents a maximum at a temperature slightly higher than the critical temperature.

  16. Analysis of Anomalously Low Surface Air Temperature in the Northern Hemisphere during 2009/2010 Winter%2009/2010年北半球冬季异常低温分析

    Institute of Scientific and Technical Information of China (English)

    孙诚; 李建平

    2012-01-01

    The anomalously low Surface Air Temperature (SAT) and the corresponding atmospheric circulation anomalies in the Northern Hemisphere during the winter (DJF) of 2009/2010 are investigated. Surface Air Temperature Anomalies (SATA) were zonally distributed with a "positive-negative-positive" pattern from tropical to polar region which was characterized by positive SATA in low latitudes, negative SATA in middle latitudes, and positive SAT A in high latitudes. The coldest SATA were located in Eurasia and eastern USA, and in some parts SATA exceeded -4 ℃. SAT in middle latitudes decreased by nearly 1 °C compared to the average of the last 15 years, and in Eurasia SAT even decreased by -8 ℃ The anomalous feathers of horizontal circulation was that, both sea level pressure and geopotential height fields exhibited positive anomalies in high latitudes and negative anomalies in low latitudes, associated with anticyelonic circulation anomalies in high latitudes and cyclonic circulation anomalies in middle latitude, and both high levels and low levels exhibited this feather. The anomalous feathers of zonally mean meridional circulation indicated that, Ferrel cell was weakened, with anomalous ascending motion in middle latitudes and anomalous descending motion in high latitudes, at the same time, atmosphere temperature of troposphere in middle latitudes was anomalously low and that in high latitudes was warmer, with a stronger jet in subtropics and a weaker jet in the polar region. Composite and correlation analysis of the Northern Hemisphere Annular Mode (NAM) and SATA shows that, during positive (negative) phase of NAM, there was a positive (negative) band in middle latitudes, and it was most significant in Eurasia and eastern USA, with nearly 2 °C warming (cooling) in some regions. Analysis of air temperature equation shows that meridional temperature advection anomalies associated with anomalous meridional wind play a very important role in the variability of local

  17. The dependence of surface temperature on IGBTs load and ambient temperature

    Directory of Open Access Journals (Sweden)

    Alexander Čaja

    2015-01-01

    Full Text Available Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT elements by loop heat pipe (LHP. IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  18. The dependence of surface temperature on IGBTs load and ambient temperature

    Science.gov (United States)

    Alexander, Čaja; Marek, Patsch

    2015-05-01

    Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT) elements by loop heat pipe (LHP). IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  19. The Temperature Dependence of the Debye-Waller Factor of Magnesium

    DEFF Research Database (Denmark)

    Sledziewska-Blocka, D.; Lebech, Bente

    1976-01-01

    The temperature dependence of the average Debye-Waller factor for magnesium was measured by means of neutron diffraction spectrometry. The experimental results obtained in the temperature range from 5 to 256 K are compared with theoretical calculations, using the harmonic and quasi-harmonic appro......The temperature dependence of the average Debye-Waller factor for magnesium was measured by means of neutron diffraction spectrometry. The experimental results obtained in the temperature range from 5 to 256 K are compared with theoretical calculations, using the harmonic and quasi...

  20. Tunneling magnetoresistance dependence on the temperature in a ferromagnetic Zener diode

    Energy Technology Data Exchange (ETDEWEB)

    Comesana, E; Aldegunde, M; GarcIa-Loureiro, A, E-mail: enrique.comesana@usc.e [Departamento de Electronica e Computacion, Universidade de Santiago de Compostela, 15782 Santiago de Compostela (Spain)

    2009-11-15

    In the present work we focus on the study of the temperature dependence of the tunnelling current in a ferromagnetic Zener diode. We predict the tunneling magnetoresistance dependence on the temperature. Large doping concentrations lead to magnetic semiconductors with Curie temperature T{sub C} near or over room temperature and this will facilitate the introduction of new devices that make use of the ferromagnetism effects. According to our calculations the tunneling magnetoresistance has the form TMR {proportional_to} (T{sup n}{sub C}-T{sup n}).

  1. Exponential temperature dependence of the penetration depth in single crystal MgB2.

    Science.gov (United States)

    Manzano, F; Carrington, A; Hussey, N E; Lee, S; Yamamoto, A; Tajima, S

    2002-01-28

    The temperature dependence of the London penetration depth, lambda(T), was measured in both single crystal and polycrystalline MgB2 samples by a high-resolution, radio frequency technique. A clear exponential temperature dependence of lambda(T) was observed at low temperature, indicating s-wave pairing. A BCS fit to the lowest temperature data gives an in-plane energy gap Delta of 30+/-2 K (2Delta/T(c) = 1.5+/-0.1), which is significantly smaller than the standard BCS weak coupling value of 3.5. We find that the data are best described by a two-gap model.

  2. Temperature dependence of spin Hall magnetoresistance in W/CoFeB bilayer

    Science.gov (United States)

    Okuno, Takaya; Taniguchi, Takuya; Kim, Sanghoon; Baek, Seung-heon Chris; Park, Byong-Guk; Moriyama, Takahiro; Kim, Kab-Jin; Ono, Teruo

    2016-08-01

    We investigate the temperature dependence of the spin Hall magnetoresistance (SMR) in a W/CoFeB bilayer. The SMR is found to increase with decreasing temperature. An analysis based on the SMR theory suggests that the spin Hall angle of W and/or the spin polarization of CoFeB can be the origin of the temperature dependence of the SMR. We also find that the spin diffusion length and the resistivity of W do not significantly vary with temperature, which indicates the necessity of further study on the electron transport mechanism in W films to reveal the origin of the spin Hall effect in W.

  3. Anomalous Hall effect in the Co-based Heusler compounds Co2FeSi and Co2FeAI

    Science.gov (United States)

    Imort, I.-M.; Thomas, P.; Reiss, G.; Thomas, A.

    2012-04-01

    The anomalous Hall effect (AHE) in the Heusler compounds Co2FeSi and Co2FeAl is studied in dependence of the annealing temperature to achieve a general comprehension of its origin. We have demonstrated that the crystal quality affected by annealing processes is a significant control parameter to tune the electrical resistivity ρxx as well as the anomalous Hall resistivity ρahe. Analyzing the scaling behavior of ρahe in terms of ρxx points to a temperature-dependent skew scattering as the dominant mechanism in both Heusler compounds.

  4. Temperature dependent photoluminescence and micromapping of multiple stacks InAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Ming, E-mail: ming.xu@lgep.supelec.fr; Jaffré, Alexandre, E-mail: ming.xu@lgep.supelec.fr; Alvarez, José, E-mail: ming.xu@lgep.supelec.fr; Kleider, Jean-Paul, E-mail: ming.xu@lgep.supelec.fr; Boutchich, Mohamed [LGEP, CNRS UMR8507, SUPELEC, Univ Paris-Sud, Sorbonne Universités - UPMC, Univ Paris 06, 11 rue Joliot-Curie, Plateau de Moulon, 91192 Gif-sur-Yvette Cedex (France); Jittrong, Apichat; Chokamnuai, Thitipong; Panyakeow, Somsak; Kanjanachuchai, Songphol [Semiconductor Device Research Laboratory (Nanotec Center of Excellence), Department of Electrical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330 (Thailand)

    2015-02-27

    We utilized temperature dependent photoluminescence (PL) techniques to investigate 1, 3 and 5 stack InGaAs quantum dots (QDs) grown on cross-hatch patterns. PL mapping can well reproduce the QDs distribution as AFM and position dependency of QD growth. It is possible to observe crystallographic dependent PL. The temperature dependent spectra exhibit the QDs energy distribution which reflects the size and shape. The inter-dot carrier coupling effect is observed and translated as a red shift of 120mV on the [1–10] direction peak is observed at 30K on 1 stack with regards to 3 stacks samples, which is assigned to lateral coupling.

  5. Deformation microstructure and positive temperature dependence of flow stress in Ni3Ge

    International Nuclear Information System (INIS)

    Single crystalline specimens of Ni3Ge were compressed along [0 0 1] at different temperatures. Temperature dependence of the critical resolved shear stress (τ0(T)) has been obtained. Detailed measurements at cryogen temperatures (4.2-77 K temperature interval) showed that the increase of the yield stress with temperature starts at liquid helium temperature. The values of the apparent activation volume (V*) have been obtained as a result of stress relaxation tests repeated along the stress-strain curve at different stress levels at seven temperatures (77, 293, 373, 473, 573, 673, 773 K). Transmission electron microscopy (TEM) methods were used to analyze the evolution of dislocation structure with temperature and strain. The measurements of the straight dislocations fraction determined as δ = ρsd / ρ, (ρsd is the straight dislocation density, ρ is a total dislocation density) have been performed. The experimental data obtained in different tests in Ni3Ge confirm two-stage nature of the positive temperature dependence of the flow stress of alloys with the L12 structure. The model of thermal strengthening considering two different types of mechanisms, first acting at low temperatures and second at high has been proposed. Using this model the temperature dependence of the critical resolved shear stress has been approximated and the activation parameters of thermal strengthening of Ni3Ge have been obtained

  6. Quantitative Analysis of Temperature Dependence of Raman shift of monolayer WS2.

    Science.gov (United States)

    Huang, Xiaoting; Gao, Yang; Yang, Tianqi; Ren, Wencai; Cheng, Hui-Ming; Lai, Tianshu

    2016-01-01

    We report the temperature-dependent evolution of Raman spectra of monolayer WS2 directly CVD-grown on a gold foil and then transferred onto quartz substrates over a wide temperature range from 84 to 543 K. The nonlinear temperature dependence of Raman shifts for both and A1g modes has been observed. The first-order temperature coefficients of Raman shifts are obtained to be -0.0093 (cm(-1)/K) and -0.0122 (cm(-1)/K) for and A1g peaks, respectively. A physical model, including thermal expansion and three- and four-phonon anharmonic effects, is used quantitatively to analyze the observed nonlinear temperature dependence. Thermal expansion coefficient (TEC) of monolayer WS2 is extracted from the experimental data for the first time. It is found that thermal expansion coefficient of out-plane mode is larger than one of in-plane mode, and TECs of and A1g modes are temperature-dependent weakly and strongly, respectively. It is also found that the nonlinear temperature dependence of Raman shift of mode mainly originates from the anharmonic effect of three-phonon process, whereas one of A1g mode is mainly contributed by thermal expansion effect in high temperature region, revealing that thermal expansion effect cannot be ignored. PMID:27576751

  7. Sex reversal triggers the rapid transition from genetic to temperature-dependent sex.

    Science.gov (United States)

    Holleley, Clare E; O'Meally, Denis; Sarre, Stephen D; Marshall Graves, Jennifer A; Ezaz, Tariq; Matsubara, Kazumi; Azad, Bhumika; Zhang, Xiuwen; Georges, Arthur

    2015-07-01

    Sex determination in animals is amazingly plastic. Vertebrates display contrasting strategies ranging from complete genetic control of sex (genotypic sex determination) to environmentally determined sex (for example, temperature-dependent sex determination). Phylogenetic analyses suggest frequent evolutionary transitions between genotypic and temperature-dependent sex determination in environmentally sensitive lineages, including reptiles. These transitions are thought to involve a genotypic system becoming sensitive to temperature, with sex determined by gene-environment interactions. Most mechanistic models of transitions invoke a role for sex reversal. Sex reversal has not yet been demonstrated in nature for any amniote, although it occurs in fish and rarely in amphibians. Here we make the first report of reptile sex reversal in the wild, in the Australian bearded dragon (Pogona vitticeps), and use sex-reversed animals to experimentally induce a rapid transition from genotypic to temperature-dependent sex determination. Controlled mating of normal males to sex-reversed females produces viable and fertile offspring whose phenotypic sex is determined solely by temperature (temperature-dependent sex determination). The W sex chromosome is eliminated from this lineage in the first generation. The instantaneous creation of a lineage of ZZ temperature-sensitive animals reveals a novel, climate-induced pathway for the rapid transition between genetic and temperature-dependent sex determination, and adds to concern about adaptation to rapid global climate change. PMID:26135451

  8. Power-law temperature dependence of collision broadening and shift of atomic and molecular rovibronic lines

    International Nuclear Information System (INIS)

    The classical phase-shift theory of spectral line shapes is used to examine various aspects of the applicability of the power-law relations to the description of temperature variations of pressure broadening and shifting coefficients of the isolated atomic and rovibronic molecular lines in a wide temperature range. Model calculations performed for potentials of the Lennard-Jones type indicate that the temperature dependence exponents of the broadening and shifting can be related to the details of the intermolecular interactions. It is shown that they are sensitive to the range of temperatures assumed in the fit and therefore extreme care must be taken when the power-law temperature dependence is used as a scaling law. The problems of the failure of the power-law and of variations in the sign of pressure shift coefficients with increasing temperature are discussed. Very good fits of Frost's empirical formula for temperature dependence of pressure shift to the theoretical ones are obtained. -- Highlights: ► Classical theory of line shapes is used to examine the power-law relations. ► The broadening and shifting exponents depend on the range of temperatures in the fit. ► Extreme care must be taken when using the power-law dependence as a scaling law

  9. In-situ high temperature irradiation setup for temperature dependent structural studies of materials under swift heavy ion irradiation

    Science.gov (United States)

    Kulriya, P. K.; Kumari, Renu; Kumar, Rajesh; Grover, V.; Shukla, R.; Tyagi, A. K.; Avasthi, D. K.

    2015-01-01

    An in-situ high temperature (1000 K) setup is designed and installed in the materials science beam line of superconducting linear accelerator at the Inter-University Accelerator Centre (IUAC) for temperature dependent ion irradiation studies on the materials exposed with swift heavy ion (SHI) irradiation. The Gd2Ti2O7 pyrochlore is irradiated using 120 MeV Au ion at 1000 K using the high temperature irradiation facility and characterized by ex-situ X-ray diffraction (XRD). Another set of Gd2Ti2O7 samples are irradiated with the same ion beam parameter at 300 K and simultaneously characterized using in-situ XRD available in same beam line. The XRD studies along with the Raman spectroscopic investigations reveal that the structural modification induced by the ion irradiation is strongly dependent on the temperature of the sample. The Gd2Ti2O7 is readily amorphized at an ion fluence 6 × 1012 ions/cm2 on irradiation at 300 K, whereas it is transformed to a radiation-resistant anion-deficient fluorite structure on high temperature irradiation, that amorphized at ion fluence higher than 1 × 1013 ions/cm2. The temperature dependent ion irradiation studies showed that the ion fluence required to cause amorphization at 1000 K irradiation is significantly higher than that required at room temperature irradiation. In addition to testing the efficiency of the in-situ high temperature irradiation facility, the present study establishes that the radiation stability of the pyrochlore is enhanced at higher temperatures.

  10. Temperature dependence of spectral induced polarization data: experimental results and membrane polarization theory

    Science.gov (United States)

    Bairlein, Katharina; Bücker, Matthias; Hördt, Andreas; Hinze, Björn

    2016-04-01

    Spectral induced polarization measurements are affected by temperature variations due to a variety of temperature-dependent parameters that control the complex electrical conductivity. Most important is the influence of the ion mobility, which increases with increasing temperature. It is responsible for the increase of the conductivity of the fluid in the pores with temperature and influences the electrical double layer on the mineral surface. This work is based on laboratory measurements of 13 sandstone samples from different sources with different geological and petrophysical characteristics. We measured the complex impedance in a frequency range from 0.01 to 100 Hz and a temperature range from 0 to 40 °C. The main observation is a decrease of the characteristic time (defined by the inverse of the frequency, at which the phase shift is maximum) with increasing temperature. The strength of this decrease differs from one sample to another. The temperature dependence of the phase shift magnitude cannot easily be generalized, as it depends on the particular sample. The experimental findings suggest that neglecting the influence of temperature on complex conductivity may lead to significant errors when estimating hydraulic conductivity from relaxation time. We also simulate the temperature dependence with a theoretical model of membrane polarization and review some of the model properties, with an emphasis on the temperature dependence of the parameters. The model reproduces several features characterizing the measured data, including the temperature dependence of the characteristic times. Computed tomography and microscope images of the pore structure of three samples also allow us to associate differences in the geometrical parameters used in the modelling with pore scale parameters of the actual samples.

  11. Anomalous Chiral Superfluidity

    OpenAIRE

    Lublinsky, Michael(Physics Department, Ben-Gurion University of the Negev, Beer Sheva 84105, Israel); Zahed, Ismail

    2009-01-01

    We discuss both the anomalous Cartan currents and the energy-momentum tensor in a left chiral theory with flavour anomalies as an effective theory for flavored chiral phonons in a chiral superfluid with the gauged Wess-Zumino-Witten term. In the mean-field (leading tadpole) approximation the anomalous Cartan currents and the energy momentum tensor take the form of constitutive currents in the chiral superfluid state. The pertinence of higher order corrections and the Adler-Bardeen theorem is ...

  12. Temperature dependence of pulse-induced mechanoluminescence excitation in coloured alkali halide crystals

    Indian Academy of Sciences (India)

    Namita Rajput; S Tiwari; B P Chandra

    2004-12-01

    In practice, the relative efficiencies of different crystals are often determined under identical conditions of temperature and excitation. If the temperature of a crystal is increased or decreased with respect to room temperature, luminescence efficiency may get increased or decreased according to the composition of the crystal. When coloured crystals of NaCl, NaBr, KCl and KBr are excited by pulse-induced excitation at different temperatures, the mechanoluminescence (ML) intensity increases with temperature. The ML intensity of first peak, ml, second peak, _m2 and the total ML intensity, T, initially increase with temperature and then tend to attain an optimum value for a particular temperature of crystals. The ratio, m2/ml, is found to increase with increasing temperature of the crystals. The expression derived on the basis of rate equations, are able to explain the temperature dependence of ML intensity on several parameters.

  13. Temperature-dependent dynamic mechanical properties of magnetorheological elastomers under magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Ju, Benxiang, E-mail: jubenxiang@qq.com [National Instrument Functional Materials Engineering Technology Research Center, Chongqing 400707 (China); Tang, Rui; Zhang, Dengyou; Yang, Bailian [National Instrument Functional Materials Engineering Technology Research Center, Chongqing 400707 (China); Yu, Miao; Liao, Changrong [College of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China)

    2015-01-15

    Both anisotropic and isotropic magnetorheological elastomer (MRE) samples were fabricated by using as-prepared polyurethane (PU) matrix and carbonyl iron particles. Temperature-dependent dynamic mechanical properties of MRE were investigated and analyzed. Due to the unique structural features of as-prepared matrix, temperature has a greater impact on the properties of as-prepared MRE, especially isotropic MRE. With increasing of temperature and magnetic field, MR effect of isotropic MRE can reach up to as high as 4176.5% at temperature of 80 °C, and the mechanism of the temperature-dependent in presence of magnetic field was discussed. These results indicated that MRE is a kind of temperature-dependent material, and can be cycled between MRE and MR plastomer (MRP) by varying temperature. - Highlights: • Both anisotropic and isotropic MRE were fabricated by using as-prepared matrix. • Temperature-dependent properties of MRE under magnetic field were investigated. • As-prepared MRE can transform MRE to MRP by adjusting temperature.

  14. Temperature dependence of the spin relaxation in highly degenerate ZnO thin films

    Energy Technology Data Exchange (ETDEWEB)

    Prestgard, M. C.; Siegel, G.; Tiwari, A., E-mail: tiwari@eng.utah.edu [Department of Materials Science and Engineering, University of Utah, Salt Lake City, Utah 84112 (United States); Materials Research Science and Engineering Center, University of Utah, Salt Lake City, Utah 84112 (United States); Roundy, R.; Raikh, M. [Materials Research Science and Engineering Center, University of Utah, Salt Lake City, Utah 84112 (United States); Department of Physics and Astronomy, University of Utah, Salt Lake City, Utah 84112 (United States)

    2015-02-28

    Zinc oxide is considered a potential candidate for fabricating next-generation transparent spintronic devices. However, before this can be achieved, a thorough scientific understanding of the various spin transport and relaxation processes undergone in this material is essential. In the present paper, we are reporting our investigations into these processes via temperature dependent Hanle experiments. ZnO thin films were deposited on c-axis sapphire substrates using a pulsed laser deposition technique. Careful structural, optical, and electrical characterizations of the films were performed. Temperature dependent non-local Hanle measurements were carried out using an all-electrical scheme for spin injection and detection over the temperature range of 20–300 K. From the Hanle data, spin relaxation time in the films was determined at different temperatures. A detailed analysis of the data showed that the temperature dependence of spin relaxation time follows the linear-in-momentum Dyakonov-Perel mechanism.

  15. Temperature dependences of Raman scattering in different types of GaN epilayers

    Institute of Scientific and Technical Information of China (English)

    Xue Xiao-Yong; Xu Sheng-Rui; Zhang Jin-Cheng; Lin Zhi-Yu; Ma Jun-Cai; Liu Zi-Yang; Xue Jun-Shuai; Hao Yue

    2012-01-01

    First-order Raman scatterings of hexagonal GaN layers deposited by the hydride vapour phase epitaxy and by metal-organic chemical vapour deposition on SiC and sapphire substrates are studied in a temperature range between 303 K and 503 K.The temperature dependences of two GaN Raman modes (A1 (LO) and E2 (high)) are obtained.We focus our attention on the temperature dependence of E2 (high) mode and find that for different types of GaN epilayers their temperature dependences are somewhat different.We compare their differences and give them an explanation.The simplified formulas we obtained are in good accordance with experiment data.The results can be used to determine the temperature of a GaN sample.

  16. Temperature dependence of 1H NMR relaxation time, T2, for intact and neoplastic plant tissues

    Science.gov (United States)

    Lewa, Czesław J.; Lewa, Maria

    Temperature dependences of the spin-spin proton relaxation time, T2, have been shown for normal and tumorous tissues collected from kalus culture Nicotiana tabacum and from the plant Kalanchoe daigremontiana. For neoplastic plant tissues, time T2 was increased compared to that for intact plants, a finding similar to that for animal and human tissues. The temperature dependences obtained were compared to analogous relations observed with animal tissues.

  17. Temperature-dependent transformation thermotics: From switchable thermal cloaks to macroscopic thermal diodes

    OpenAIRE

    Li, Ying; Shen, Xiangying; Wu, Zuhui; Huang, Junying; Chen, Yixuan; Ni, Yushan; Huang, Jiping

    2015-01-01

    The macroscopic control of ubiquitous heat flow remains poorly explored due to the lack of a fundamental theoretical method. Here, by establishing temperature-dependent transformation thermotics for treating materials whose conductivity depends on temperature, we show analytical and simulation evidence for switchable thermal cloaking and a macroscopic thermal diode based on the cloaking. The latter allows heat flow in one direction but prohibits the flow in the opposite direction, which is al...

  18. Temperature dependence and mechanism of the reaction between O(3P) and chlorine dioxide

    Science.gov (United States)

    Colussi, A. J.; Sander, S. P.; Fiedl, R. R.

    1992-01-01

    Second-order rate constants for the decay of O(3P) in excess chlorine dioxide, k(II), were measured as a function of total pressure (20-600 Torr argon) and temperature (248-312 K), using flash photolysis-atomic resonance fluorescence. Results indicate that k(II) is pressure dependent with a value, K(b), that is nonzero at zero pressure, and both the third-order rate constant and k(b) have negative temperature dependences.

  19. Effects of a temperature dependent viscosity on thermal convection in binary mixtures

    OpenAIRE

    Hilt, Markus; Glässl, Martin; Zimmermann, Walter

    2013-01-01

    We investigate the effect of a temperature dependent viscosity on the onset of thermal convection in a horizontal layer of a binary fluid mixture that is heated from below. For an exponential temperature dependence of the viscosity, we find in binary mixtures as a function of a positive separation ratio and beyond a certain viscosity contrast a discontinuous transition between two stationary convection modes having a different wavelength. In the range of negative values of the separation rati...

  20. Quark mass density- and temperature- dependent model for bulk strange quark matter

    OpenAIRE

    al, Yun Zhang et.

    2002-01-01

    It is shown that the quark mass density-dependent model can not be used to explain the process of the quark deconfinement phase transition because the quark confinement is permanent in this model. A quark mass density- and temperature-dependent model in which the quark confinement is impermanent has been suggested. We argue that the vacuum energy density B is a function of temperature. The dynamical and thermodynamical properties of bulk strange quark matter for quark mass density- and temper...

  1. A Temperature-Dependent Thermal Model of IGBT Modules Suitable for Circuit-Level Simulations

    DEFF Research Database (Denmark)

    Wu, Rui; Wang, Huai; Ma, Ke;

    2014-01-01

    Thermal impedance of IGBT modules may vary with operating conditions due to that the thermal conductivity and heat capacity of materials are temperature dependent. This paper proposes a Cauer thermal model for a 1700 V/1000 A IGBT module with temperature-dependent thermal resistances and thermal...... relevant reliability aspect performance. A test bench is built up with an ultra-fast infrared (IR) camera to validate the proposed thermal impedance model....

  2. Temperature dependence of the bandgap width in FeIn2Se4 single crystals

    International Nuclear Information System (INIS)

    We have used the Bridgman method to grow single crystals of the ternary compound FeIn2Se4 and we have determined their composition and structure. We measured the transmission spectra in the intrinsic absorption edge region in the temperature range 20-300 K. From the transmission spectra, we determined the bandgap width and plotted its temperature dependence. We show that the Eg(T) dependence has a shape typical for semiconductor compounds. (authors)

  3. Anomalous Growth of Aging Populations

    Science.gov (United States)

    Grebenkov, Denis S.

    2016-04-01

    We consider a discrete-time population dynamics with age-dependent structure. At every time step, one of the alive individuals from the population is chosen randomly and removed with probability q_k depending on its age, whereas a new individual of age 1 is born with probability r. The model can also describe a single queue in which the service order is random while the service efficiency depends on a customer's "age" in the queue. We propose a mean field approximation to investigate the long-time asymptotic behavior of the mean population size. The age dependence is shown to lead to anomalous power-law growth of the population at the critical regime. The scaling exponent is determined by the asymptotic behavior of the probabilities q_k at large k. The mean field approximation is validated by Monte Carlo simulations.

  4. Peculiarities of temperature dependent ion beam sputtering and channeling of crystalline bismuth.

    Science.gov (United States)

    Langegger, Rupert; Hradil, Klaudia; Steiger-Thirsfeld, Andreas; Bertagnolli, Emmerich; Lugstein, Alois

    2014-08-01

    In this paper, we report on the surface evolution of focused ion beam treated single crystalline Bi(001) with respect to different beam incidence angles and channeling effects. 'Erosive' sputtering appears to be the dominant mechanism at room temperature (RT) and diffusion processes during sputtering seem to play only a minor role for the surface evolution of Bi. The sputtering yield of Bi(001) shows anomalous behavior when increasing the beam incidence angle along particular azimuthal angles of the specimen. The behavior of the sputtering yield could be related to channeling effects and the relevant channeling directions are identified. Dynamic annealing processes during ion irradiation retain the crystalline quality of the Bi specimen allowing ion channeling at RT. Lowering the specimen temperature to T = -188 °C reduces dynamic annealing processes and thereby disables channeling effects. Furthermore unexpected features are observed at normal beam incidence angle. Spike-like features appear during the ion beam induced erosion, whose growth directions are not determined by the ion beam but by the channeling directions of the Bi specimen.

  5. High spectral resolution ozone absorption cross-sections – Part 2: Temperature dependence

    Directory of Open Access Journals (Sweden)

    A. Serdyuchenko

    2013-07-01

    Full Text Available We report on the temperature dependence of ozone absorption cross-sections measured in our laboratory in the spectral range 213–1100 nm with a spectral resolution of 0.02–0.24 nm (Full Width Half Maximum, FWHM in the atmospherically relevant temperature range from 193 to 293 K. The temperature dependence of ozone absorption cross-sections was established using measurements at eleven temperatures. The methodology of the absolute broadband measurements, experimental procedures and spectra processing were described in our companion paper together with the associated error budget. In this paper, we report in detail on our data below room temperature and compare them with literature data using direct comparisons as well as the standard approach using a quadratic polynomial in temperature fitted to the cross-section data.

  6. Diameter and Temperature Dependence of Thermal Conductivity of Single-Walled Carbon Nanotubes

    Institute of Scientific and Technical Information of China (English)

    PAN Rui-Qin

    2011-01-01

    Temperature and diameter dependence of the thermal conductivity of several armchair single-walled carbon nan-otubes (SWNTs) are studied by nonequilibrium molecular dynamics method with Brenner II potential. The thermal conductivities are calculated at temperatures from WOK to 600K. It is found that the thermal conductivity decreases as the temperature increases and increases as the diameter of SWNT increases. The results demonstrate that these two phenomena are due to the onset of the Umklapp process.%@@ Temperature and diameter dependence of the thermal conductivity of several armchair single-walled carbon nan- otubes (SWNTs) are studied by nonequilibrium molecular dynamics method with Brenner Ⅱ potential.The thermal conductivities are calculated at temperatures from 100K to 600K.It is found that the thermal con- ductivity decreases as the temperature increases and increases as the diameter of SWNT increases.The results demonstrate that these two phenomena are due to the onset of the Umklapp process.

  7. Temperature-dependent infrared reflectivity studies of multiferroic TbMnO3: Evidence for spin-phonon coupling

    Indian Academy of Sciences (India)

    Pradeep Kumar; Surajit Saha; C R Serrao; A K Sood; C N R Rao

    2010-02-01

    We have measured near normal incidence far-infrared (FIR) reflectivity spectra of a single crystal of TbMnO3 from 10 K to 300 K in the spectral range of 50 cm-1 –700 cm-1. Fifteen transverse optic (TO) and longitudinal optic (LO) modes are identified in the imaginary part of the dielectric function 2 ()$ and energy loss function Im(−1/()), respectively. Some of the observed phonon modes show anomalous softening below the magnetic transition temperature N (∼ 46 K). We attribute this anomalous softening to the spin-phonon coupling caused by phonon modulation of the superexchange integral between the Mn3+ spins. The effective charge of oxygen (O) calculated using the measured LO–TO splitting increases below N.

  8. Temperature dependence of acoustic harmonics generated by nonlinear ultrasound wave propagation in water at various frequencies.

    Science.gov (United States)

    Maraghechi, Borna; Hasani, Mojtaba H; Kolios, Michael C; Tavakkoli, Jahan

    2016-05-01

    Ultrasound-based thermometry requires a temperature-sensitive acoustic parameter that can be used to estimate the temperature by tracking changes in that parameter during heating. The objective of this study is to investigate the temperature dependence of acoustic harmonics generated by nonlinear ultrasound wave propagation in water at various pulse transmit frequencies from 1 to 20 MHz. Simulations were conducted using an expanded form of the Khokhlov-Zabolotskaya-Kuznetsov nonlinear acoustic wave propagation model in which temperature dependence of the medium parameters was included. Measurements were performed using single-element transducers at two different transmit frequencies of 3.3 and 13 MHz which are within the range of frequencies simulated. The acoustic pressure signals were measured by a calibrated needle hydrophone along the axes of the transducers. The water temperature was uniformly increased from 26 °C to 46 °C in increments of 5 °C. The results show that the temperature dependence of the harmonic generation is different at various frequencies which is due to the interplay between the mechanisms of absorption, nonlinearity, and focusing gain. At the transmit frequencies of 1 and 3.3 MHz, the harmonic amplitudes decrease with increasing the temperature, while the opposite temperature dependence is observed at 13 and 20 MHz. PMID:27250143

  9. Universality of temperature-dependent effects in finite many-fermion systems

    International Nuclear Information System (INIS)

    The temperature dependence of the specific heat for a finite system of fermions is investigated for some simple models. It is found that finite-size effects produce a maximum in the specific heat at a temperature Tc that has a universal value when scaled by the appropriate characteristic energy

  10. The temperature dependence of the isothermal bulk modulus at 1 bar pressure

    OpenAIRE

    Garai, J.; Laugier, A

    2006-01-01

    It is well established that the product of the volume coefficient of thermal expansion and the bulk modulus is nearly constant at temperatures higher than the Debye temperature. Using this approximation allows predicting the values of the bulk modulus. The derived analytical solution for the temperature dependence of the isothermal bulk modulus has been applied to ten substances. The good correlations to the experiments indicate that the expression may be useful for substances for which bulk ...

  11. Investigation of light intensity and temperature dependency of solar cells electric parameters

    OpenAIRE

    Tobnaghi, Davoud Mostafa; Madatov, Rahim; Farhadi, Payam

    2013-01-01

    In this paper, the performance and overview use of solar cells is expressed. The role of temperature, sunlight intensity on the solar cells electric parameters has been studied. Experimental results the amount of solar cell output parameters variations such as maximum output power, open circuit voltage, short circuit current, and fill factor in terms of temperature and light intensity shows. the most significant is the temperature dependence of the voltage which decreases with increasing t...

  12. Sensitively Temperature-Dependent Spin Orbit Coupling in SrIrO3 Thin Films

    OpenAIRE

    Zhang, Lunyong; Chen, Y. B.; Zhou, Jian; Zhang, Shan-Tao; Gu, Zheng-Bin; Yao, Shu-Hua; Chen, Yan-Feng

    2013-01-01

    Spin orbit coupling plays a non-perturbation effect in many recently developed novel fields including topological insulators and spin-orbit assistant Mott insulators. In this paper, strongly temperature-dependent spin orbit coupling, revealed by weak anti-localization, is observed at low temperature in 5d strongly correlated compound, SrIrO3. As the temperature rising, increase rate of Rashba coefficient is nearly 30%-45%/K. The increase is nearly 100 times over that observed in semiconductor...

  13. Efficiency and optimisation of fin with temperature-dependent thermal conductivity: a simplified solution

    Energy Technology Data Exchange (ETDEWEB)

    Bouaziz, M.N.; Hanini, S.

    2007-11-15

    An analytical simplified solution is proposed for temperature distribution and fin efficiency, when thermal conductivity is temperature dependent. An optimal linearization technique is used to solve the nonlinear equation. Based on classical solution, some accurate results are obtained and presented with thermal conductivity parameter and fin parameter. Arithmetic mean temperature is less precise than an equivalent thermal conductivity. Optimal thickness for rectangular fin is derived. (orig.)

  14. Temperature and humidity dependence of secondary organic aerosol yield from the ozonolysis of β-pinene

    Directory of Open Access Journals (Sweden)

    O. J. Nielsen

    2007-02-01

    Full Text Available The temperature dependence of secondary organic aerosol (SOA formation from ozonolysis of β-pinene was studied in a flow reactor at 263 K–303 K and 1007 hPa under dry and humid conditions (0% and 26%–68% relative humidity, respectively. The observed SOA yields were of similar magnitude as predicted by a two-product model based on detailed gas phase chemistry (Jenkin, 2004, reaching maximum values of 0.18–0.39 at high particle mass concentrations (Mo. Under dry conditions, however, the measurement data exhibited significant oscillatory deviations from the predicted linear increase with inverse temperature (up to 50% at high Mo. Under humid conditions the SOA yield exhibited a linear decrease with inverse temperature, which is opposite to modelled temperature dependence and implies that the model substantially overestimates the yield at low temperatures and underestimates it at high temperatures (deviations up to 80% at high Mo. For the atmospherically relevant concentration level of Mo=10 μg m−3 and temperature range 263 K–293 K, the results from humid experiments in this study indicate that the SOA yield of β-pinene ozonolysis may be well represented by an average value of 0.15 with an uncertainty estimate of ±0.05. When fitting the measurement data with a two-product model, both the partitioning coefficients (Kom,i and the stoichiometric yields (αi of the low-volatile and semi-volatile model species were found to vary with temperature. The results indicate that not only the reaction product vapour pressures but also the relative contributions of different gas-phase or multiphase reaction channels are strongly dependent on temperature and the presence of water vapour. In fact, the oscillatory positive temperature dependence observed under dry conditions and the negative temperature dependence observed under humid conditions indicate that the SOA yield is governed much more by the temperature and humidity dependence of the involved

  15. Shape Dependence of Low-Temperature Magnetic Relaxation of Mn12Ac

    Institute of Scientific and Technical Information of China (English)

    LIU Hai-Qing; SU Shao-Kui; JING Xiu-nian; LIU Ying; LI Yan-rong; HE Lun-Hua; GE Pei-Wen; YAN Qi-Wei; WANG Yun-Ping

    2008-01-01

    We report the discovery that the low-temperature magnetic relaxation in Mn,12 Ac single crystals strongly depends on the shape of the samples. The relaxation time exhibits a minimum at the phase transition point between ferromagnetic and antiferromagnetic phases. The shape dependence is attributed to the dipolar interaction between molecular magnets.

  16. Temperature dependence of crystals conductivity both potassium sulfates and ammonium sulfates

    International Nuclear Information System (INIS)

    In the work the results of temperature dependence of conductivity of crystals both potassium sulfate and ammonium sulfate are given. The superficial specific conductivity and its dependence on width of a backlash between the central and ring electrodes are determined. (author)

  17. Dependence of negative muon depolarization on molecular weight and temperature in organic compounds

    International Nuclear Information System (INIS)

    An atomic capture of negative muons in the aliphatic spirit series, the dependence of muon rest polarization on the molecular weight of spirit have been studied. The temperature dependence of depolarization in benzole and styrene has been obtained. The results on depolarization are being interpreted basing on notions about chemical interactions of mesic atoms in organic compounds. (author)

  18. Anomalous transport effects in magnetically-confined plasma columns

    International Nuclear Information System (INIS)

    The evolution of density structure in a magnetized plasma column is analyzed accounting for anomalous diffusion due to the lower hybrid drift instability. The plasma column is found to be divided into regions of classical, anomalous, and intermediate diffusivity. The bulk behavior, described in terms of radial confinement time, depends most sensitively upon the particle line density (ion/cm). For broad plasmas (large line density), the transport is characteristic of classical diffusion, and for slender plasmas (small line density) the transport is characteristic of anomalous diffusion. For intermediate line densities, the transport undertakes a rapid transition from classical to anomalous. Correlations between the theoretical results and past experiments are described

  19. Temperature dependent optical properties of stacked InGaAs/GaAs quantum rings

    International Nuclear Information System (INIS)

    In this paper we describe the results of temperature dependent photoluminescence intensity and decay time measurements of In(Ga)As/GaAs quantum rings where the depth of barrier is varied from sample to sample. The activation energy found for the reduction of the exciton decay time as a function of the temperature is approximately half the value of the thermionic escape energy of excitons. The temperature dependant behaviour is ascribed to the carriers lost via the excited state to the WL. The time resolved PL study indicates that thermal escape mechanisms is not so affected by reducing the spacer thickness, but it's influenced essentially by the excited state recombination

  20. Temperature-dependent efficiency droop of blue InGaN micro-light emitting diodes

    International Nuclear Information System (INIS)

    Temperature-dependent trends in radiative and Auger recombination coefficients have been determined at different injection carrier concentrations using InGaN micro-light emitting diodes 40 μm in diameter. The differential lifetime was obtained first from the measured modulation bandwidth and was then employed to calculate the carrier concentration in the quantum well active region. When the temperature increases, the carrier concentration increases, but both the radiative and Auger recombination coefficients decrease. In addition, the temperature dependence of radiative and Auger recombination coefficients is weaker at a higher injection carrier concentration, which is strongly related to phase space filling.

  1. Temperature dependence of residual electrical resistivity of Cu-Au in pseudopotential approximation

    International Nuclear Information System (INIS)

    The problem of temperature dependence of residual electrical resistivity of Cu-Au system is re-examined in the light of static distortion and thermal vibration of the lattice along with the short-range-order of atoms above critical temperature. The extended version of Ziman's formula for resistivity obtained yields a unified version for the calculation of resistivity in pseudopotential approximation. The temperature dependence of the quantity Δρ/ρ in this framework for Cu-Au system is found to be in better agreement with the experimental data as compared to previous calculation. (author)

  2. Temperature-dependent hyperfine interactions at {sup 111}Cd-C complex in germanium

    Energy Technology Data Exchange (ETDEWEB)

    Mola, Genene Tessema [University of Kwazulu-Natal, School Chemistry and Physics, Pietermaritzburg Campus, Private Bag X01, Scottsville (South Africa)

    2013-09-15

    The temperature dependent nuclear hyperfine interaction of {sup 111}Cd-carbon complex in germanium has been studied using the perturbed {gamma}-{gamma} angular correlation (PAC) method. The parameters of the hyperfine interaction representing substitutional carbon-cadmium complex in germanium ({nu} {sub Q1}=207(1) MHz ({eta}=0.16)) shows dependence on temperature. The formation and thermal stability of the complex has been reported by the same author earlier. It was found in this study that the quadrupole coupling constant of the interaction increases at sample temperature below 293 K. The results are encouraging toward better understanding of the complex in the host matrix. (orig.)

  3. Temperature-dependent energy band gap variation in self-organized InAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Yeo, Inah [CEA/CNRS/UJF Joint Team ' ' Nanophysics and Semiconductors,' ' Institut Neel-CNRS, BP 166, 25 rue des Martyrs, 38042 Grenoble Cedex 9 (France); Dong Song, Jin; Lee, Jungil [Nanophotonics Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of)

    2011-10-10

    We investigated the temperature-dependent variation of the photoluminescence emission energy of self-organized InAs/GaAs quantum dots (QDs) grown by conventional Stranski-Krastanov (SK) molecular beam epitaxy and migration-enhanced molecular beam epitaxy (MEMBE) and that of MEMBE InAs QDs in a symmetric and an asymmetric In{sub 0.2}Ga{sub 0.8}As/GaAs well. The temperature-dependent energy variation of each QD is analyzed in low and high temperature regions, including a sigmoidal behavior of conventional SK quantum dots with the well-known Varshni and semi-empirical Fan models.

  4. Temperature dependence of fracture toughness in HT9 steel neutron-irradiated up to 145 dpa

    Energy Technology Data Exchange (ETDEWEB)

    Baek, Jong-Hyuk [KAERI; Byun, Thak Sang [ORNL; Maloy, S [Los Alamos National Laboratory (LANL); Toloczko, M [Pacific Northwest National Laboratory (PNNL)

    2014-01-01

    The temperature dependence of fracture toughness in HT9 steel irradiated to high doses was investigated using miniature three-point bend (TPB) fracture specimens. These specimens were from the ACO-3 fuel duct wall of the Fast Flux Test Facility (FFTF), in which irradiation doses were in the range of 3.2 144.8 dpa and irradiation temperatures in the range of 380.4 502.6 oC. A miniature specimen reuse technique has been established for this investigation: the specimens used were the tested halves of miniature Charpy impact specimens (~13 3 4 mm) with diamond-saw cut in the middle. The fatigue precracking for specimens and fracture resistance (J-R) tests were carried out in a MTS servo-hydraulic testing machine with a vacuum furnace following the standard procedure described in the ASTM Standard E 1820-09. For each of five irradiated and one archive conditions, 7 to 9 J-R tests were performed at selected temperatures ranging from 22 C to 600 C. The fracture toughness of the irradiated HT9 steel was strongly dependent on irradiation temperatures rather than irradiation dose. When the irradiation temperature was below about 430 C, the fracture toughness of irradiated HT9 increased with test temperature, reached an upper shelf of 180 200 MPa m at 350 450 C and then decreased with test temperature. When the irradiation temperature 430 C, the fracture toughness was nearly unchanged until about 450 C and decreased with test temperature in higher temperature range. Similar test temperature dependence was observed for the archive material although the highest toughness values are lower after irradiation. Ductile stable crack growth occurred except for a few cases where both the irradiation temperature and test temperature are relatively low.

  5. Experimental determination of the temperature dependence of water activities for a selection of aqueous organic solutions

    Directory of Open Access Journals (Sweden)

    G. Ganbavale

    2014-05-01

    Full Text Available This work presents experimental data of the temperature dependence of water activity in aqueous organic solutions relevant for tropospheric conditions (200–273 K. Water activity (aw at low temperatures (T is a crucial parameter for predicting homogeneous ice nucleation. We investigated temperature dependent water activities, ice freezing and melting temperatures of solutions, and vapour pressures of a selection of atmospherically relevant aqueous organic systems. To measure aw over a wide composition range and with a focus on low temperatures, we use various aw measurement techniques and instruments: a dew point water activity meter, an electrodynamic balance (EDB, differential scanning calorimetry (DSC, and a setup to measure the total gas phase pressure at equilibrium over aqueous solutions. Water activity measurements were performed for aqueous multicomponent and multifunctional organic mixtures containing the functional groups typically found in atmospheric organic aerosols, such as hydroxyl, carboxyl, ketone, ether, ester, and aromatic groups. The aqueous organic systems studied at several fixed compositions over a considerable temperature range differ significantly in their temperature dependence. Aqueous organic systems of 1,4-butanediol and methoxyacetic acid show a moderate decrease in aw with decreasing temperature. The aqueous M5 system (a multicomponent system containing five different dicarboxylic acids and aqueous 2-(2-ethoxyethoxyethanol solutions both show a strong increase of water activity with decreasing temperature at high solute concentrations for TTaw can be reversed at low temperatures and that linear extrapolations of high temperature data may lead to erroneous predictions. To avoid this, experimentally determined aw at low temperature are needed to improve thermodynamic models towards lower temperatures and for improved predictions of the ice nucleation ability of organic–water systems.

  6. Interferometric signatures of the temperature dependence of the specific shear viscosity in heavy-ion collisions

    CERN Document Server

    Plumberg, Christopher

    2015-01-01

    Recent work has shown that a temperature dependence of the shear viscosity to entropy ratio, $\\eta/s$, influences the collective flow pattern in heavy-ion collisions in characteristic ways that can be measured by studying hadron transverse momentum spectra and their anisotropies. Here we point out that it also affects the pair momentum dependence of the Hanbury-Brown$-$Twiss (HBT) radii (the source size parameters extracted from two-particle intensity interferometry) and the variance of their event-by-event fluctuations. This observation establishes interferometric signatures as useful observables to complement the constraining power of single-particle spectra on the temperature dependence of $\\eta/s$.

  7. Temperature dependence of electric quadrupole interaction in high Tc superconductor Bi1.7Pb0.3Sr2CaCu2O8+δ

    International Nuclear Information System (INIS)

    The temperature dependence of the electric quadrupole interaction in high Tc superconductor Bi1.7Pb0.3Sr2CaCu2O8+δ has been measured by means of the differential perturbed angular correlation (DPAC) from 77 K to 300 K. Two static, non-axially symmetric electric field gradients, which assigned to Bi1 and Bi2 sites in the Bi-O planes and the incommensurate modulation sites respectively have been derived from the fitting of DPAC spectra. Anomalous changes of the EFGs and their non-axially symmetric parameters of both the Bi sites were observed at 120 K and 170 K. It may indicate that a phase-like transition caused by the lattice displacing happens. The stronger nuclear relaxation phenomenon of B11 sites in the Bi-O planes can be found from the changes of relaxation constants measured with temperature. It shows that there is a fluctuation field in action. The behavior of the relaxation constants with temperature is different from the regularity of the low temperature superconductor expected by the BCS theory

  8. Temperature dependent competition between different recombination channels in organic heterojunction solar cells

    International Nuclear Information System (INIS)

    A modification of the Shockley–Queisser theory for organic heterojunctions is presented with a special focus on constellations, where a linear extrapolation of the temperature dependence of the open circuit voltage results in the optical gap of the absorber rather than in the intermolecular charge transfer (CT) gap. We demonstrate that, depending on the electronic coupling strength between donor and acceptor molecules, either singlet or CT recombination is dominant in different temperature regimes. The different regimes are separated by a transition temperature that is usually well above room temperature (RT). However, in the case of small energy level offset and weak electronic coupling, it can be around 300 K or even below. We point out that a linear extrapolation of the open circuit voltage V oc towards 0 K for measured temperatures larger than the transition temperature results in a photovoltaic gap that is close to the optical gap, whereas for values below the transition temperature the CT gap will be extracted. We show that for α-sexithiophene (6T)/diindenoperylene (DIP) solar cells heating the substrate during 6T deposition leads to a molecular configuration at the interface where the coupling between donor and acceptor molecules is strongly reduced. This leads to a transition temperature well below RT which is confirmed by temperature dependent electroluminescence measurements. By comparing the temperature dependent spectra of high temperature and RT grown 6T/DIP solar cells to the spectra of the individual materials, the different contributions from the CT gap and the optical gap are separated. (paper)

  9. The effect of interfacial intermixing on magnetization and anomalous Hall effect in Co/Pd multilayers

    KAUST Repository

    Guo, Zaibing

    2015-05-01

    The effect of interfacial intermixing on magnetization and anomalous Hall effect (AHE) in Co/Pd multilayers is studied by using rapid thermal annealing to enhance the interfacial diffusion. The dependence of saturation magnetization and coercivity on the temperature of rapid thermal annealing at 5 K is discussed. It is found that AHE is closely related to the relative thickness of the Co and Pd layers. Localized paramagnetism has been observed which destroys AHE, while AHE can be enhanced by annealing.

  10. Angular dependence of coercivity with temperature in Co-based nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Bran, C., E-mail: cristina.bran@icmm.csic.es [Institute of Materials Science of Madrid, CSIC, 28049 Madrid (Spain); Espejo, A.P. [Departamento de Física, Universidad de Santiago de Chile (USACH) and Center for the Development of Nanoscience and Nanotechnology (CEDENNA), Avenida Ecuador 3493, 9170124 Santiago (Chile); Palmero, E.M. [Institute of Materials Science of Madrid, CSIC, 28049 Madrid (Spain); Escrig, J. [Departamento de Física, Universidad de Santiago de Chile (USACH) and Center for the Development of Nanoscience and Nanotechnology (CEDENNA), Avenida Ecuador 3493, 9170124 Santiago (Chile); Vázquez, M. [Institute of Materials Science of Madrid, CSIC, 28049 Madrid (Spain)

    2015-12-15

    The magnetic behavior of arrays of Co and CoFe nanowire arrays has been measured in the temperature range between 100 and 300 K. We have paid particular attention to the angular dependence of magnetic properties on the applied magnetic field orientation. The experimental angular dependence of coercivity has been modeled according to micromagnetic analytical calculations, and we found that the propagation of a transversal domain wall mode gives the best fitting with experimental observations. That reversal mode holds in the whole measuring temperature range, for nanowires with different diameters and crystalline structure. Moreover, the quantitative strength of the magnetocrystalline anisotropy and its magnetization easy axis are determined to depend on the crystalline structure and nanowires diameter. The evolution of the magnetocrystalline anisotropy with temperature for nanowires with different composition gives rise to an opposite evolution of coercivity with increasing temperature: it decreases for CoFe while it increases for Co nanowire arrays.

  11. Scaling Laws for Convection with Temperature-dependent Viscosity and Grain-damage

    CERN Document Server

    Foley, Bradford J

    2014-01-01

    Numerical experiments of convection with grain-damage are used to develop scaling laws for convective heat flow, mantle velocity, and plate velocity across the stagnant lid and plate-tectonic regimes. Three main cases are presented in order of increasing complexity: a simple case wherein viscosity is only dependent on grainsize, a case where viscosity depends on temperature and grainsize, and finally a case where viscosity is temperature and grainsize sensitive, and the grain-growth (or healing) is also temperature sensitive. In all cases, convection with grain-damage scales differently than Newtonian convection due to the effects of grain-damage. For the fully realistic case, numerical results show stagnant lid convection, fully mobilized convection that resembles the temperature-independent viscosity case, and partially mobile or transitional convection, depending on damage to healing ratio, Rayleigh number, and the activation energies for viscosity and healing. Applying our scaling laws for the fully reali...

  12. Temperature dependence of magnetic susceptibility in the vicinity of martensitic transformation in ferromagnetic shape memory alloys.

    Science.gov (United States)

    Zablotskii, V; Pérez-Landazábal, J I; Recarte, V; Gómez-Polo, C

    2010-08-11

    Temperature dependences of low-field quasistatic magnetic susceptibility in the vicinity of martensitic transitions in an NiFeGa alloy are studied both by experiment and analytically. Pronounced reversible jumps of the magnetic susceptibility were observed near the martensitic transition temperature. A general description of the temperature dependences of the susceptibility in ferromagnetic austenite and martensite phases and the susceptibility jump at the transition is suggested. As a result, the main factors governing the temperature dependences of the magnetic susceptibility in the magnetic shape memory alloys are revealed. The magnetic susceptibility jump value is found to be related to changes of: (i) magnetic anisotropy; (ii) magnetic domain wall geometrical constraints (those determined by the alignment and size of twin variants) and (iii) mean magnetic domain spacing.

  13. Uniaxial Time-Dependent Ratcheting of SS304 Stainless Steel at High Temperatures

    Institute of Scientific and Technical Information of China (English)

    KANG Guo-zheng; ZHANG Juan; SUN Ya-fang; KAN Qian-hua

    2007-01-01

    The uniaxial time-dependent strain cyclic behaviors and ratcheting of SS304 stainless steel were studied at high temperatures (350 ℃ and 700 ℃). The effects of straining and stressing rates, holding time at the peak and/or valley of each cycle in addition to ambient temperature on the cyclic softening/hardening behavior and ratcheting of the material were discussed. It can be seen from experimental results that the material presents remarkable time dependence at 700 ℃, and the ratcheting strain depends greatly on the stressing rate, holding time and ambient temperature. Some significant conclusions are obtained, which are useful to build a constitutive model describing the time-dependent cyclic deformation of the material.

  14. Calculation of temperature distribution in adiabatic shear band based on gradient-dependent plasticity

    Institute of Scientific and Technical Information of China (English)

    王学滨

    2004-01-01

    A method for calculation of temperature distribution in adiabatic shear band is proposed in terms of gradient-dependent plasticity where the characteristic length describes the interactions and interplaying among microstructures. First, the increment of the plastic shear strain distribution in adiabatic shear band is obtained based on gradient-dependent plasticity. Then, the plastic work distribution is derived according to the current flow shear stress and the obtained increment of plastic shear strain distribution. In the light of the well-known assumption that 90% of plastic work is converted into the heat resulting in increase in temperature in adiabatic shear band, the increment of the temperature distribution is presented. Next, the average temperature increment in the shear band is calculated to compute the change in flow shear stress due to the thermal softening effect. After the actual flow shear stress considering the thermal softening effect is obtained according to the Johnson-Cook constitutive relation, the increment of the plastic shear strain distribution, the plastic work and the temperature in the next time step are recalculated until the total time is consumed. Summing the temperature distribution leads to rise in the total temperature distribution. The present calculated maximum temperature in adiabatic shear band in titanium agrees with the experimental observations. Moreover, the temperature profiles for different flow shear stresses are qualitatively consistent with experimental and numerical results. Effects of some related parameters on the temperature distribution are also predicted.

  15. Improved Regression Analysis of Temperature-Dependent Strain-Gage Balance Calibration Data

    Science.gov (United States)

    Ulbrich, N.

    2015-01-01

    An improved approach is discussed that may be used to directly include first and second order temperature effects in the load prediction algorithm of a wind tunnel strain-gage balance. The improved approach was designed for the Iterative Method that fits strain-gage outputs as a function of calibration loads and uses a load iteration scheme during the wind tunnel test to predict loads from measured gage outputs. The improved approach assumes that the strain-gage balance is at a constant uniform temperature when it is calibrated and used. First, the method introduces a new independent variable for the regression analysis of the balance calibration data. The new variable is designed as the difference between the uniform temperature of the balance and a global reference temperature. This reference temperature should be the primary calibration temperature of the balance so that, if needed, a tare load iteration can be performed. Then, two temperature{dependent terms are included in the regression models of the gage outputs. They are the temperature difference itself and the square of the temperature difference. Simulated temperature{dependent data obtained from Triumph Aerospace's 2013 calibration of NASA's ARC-30K five component semi{span balance is used to illustrate the application of the improved approach.

  16. Analytic model for description of temperature dependent rate phenomena in arthropods

    Energy Technology Data Exchange (ETDEWEB)

    Logan, J.A.; Wollkind, D.J.; Hoyt, S.C.; Tanigoshi, L.K.

    1976-12-15

    A new description of temperature-dependent, rate phenomena was deduced to describe developmental time and ovipositional data for the McDaniel spider mite, Tetranychus mcdanieli McGregor. The derived equation accounted for asymmetry about optimum temperature and was of particular utility for description of systems operating at or above optimum temperatures. Ovipositional and developmental rate functions were used in a temperature-driven, discrete-time, simulation model describing McDaniel spider mite population dynamics. Temperature dependence of the instantaneous population growth rate was determined by fitting the derived rate-temperature function to data generated through simulation at various fixed temperatures. The functional relationship of important population parameters to temperature provided the mechanism for inclusion of phenological effects on mite populations in a synoptic apple pest management model. Two derived functions were fit to several published rate-temperature data sets. Adequacy of description (as indicated by R/sup 2/ values) indicated general applicability of both functions for description of temperature-controlled, biological processes. Further, it was concluded that the singular perturbation method of matched asymptotes has potentially wide application in ecology, and an Appendix detailing the application of this method is included.

  17. Anomalous phonon behaviour in V sub 3 Si

    CERN Document Server

    Yethiraj, M

    2002-01-01

    In earlier studies of phonons in V sub 3 Si, a gradual softening of the (hh0) branch was observed and attributed to the martensitic transition in this compound, which precedes the onset of superconductivity by a few degrees K. In this work, the temperature dependence of the transverse acoustic (TA) branch along the hh0 direction was studied in greater detail and it is shown that while the TA hh0 mode starts to soften at relatively high temperatures (>200 K), an anomalous softening, which is rather localized in q, occurs just below T sub c. The intensity of this soft-phonon peak correlates extremely well with the onset of the superconducting phase and appears to vary as the order parameter with temperature and applied field. The similarities in the phonon softening and Fermi-surface anisotropy between this compound and the rare-earth nickel borocarbides suggest the existence of a common mechanism for the superconducting transition. (orig.)

  18. Temperature dependence of electromechanical properties of PLZT /57/43 ceramics

    Indian Academy of Sciences (India)

    A K Shukla; V K Agrawal; I M L Das; Janardan Singh; S L Srivastava

    2010-08-01

    The compositions of lead lanthanum zirconate titanate PLZT [Pb(Zr0.57Ti0.43)O3 + at% of La, where = 3, 5, 6, 10 and 12] have been synthesized using mixed oxide route. The temperature dependent electromechanical parameters have been determined using vector impedance spectroscopy (VIS). The charge constant 31 and elastic compliance $s^{E}_{11}$ show a peak in all the samples at a temperature mt much below the ferroelectric – paraelectric transition temperature, whereas the series resonance frequency s shows a dip at these temperatures. The Poisson’s ratio increases with temperature showing a broad peak at a temperature higher than mt. The voltage constant 31 decreases and the planar coupling coefficient p remains constant up to half of the mt and then falls sharply with . Half of the mt can, therefore, be used for specifying the working temperature limit of the piezoceramics for the device applications.

  19. Temperature-dependent structural relaxation in As40Se60 glass

    International Nuclear Information System (INIS)

    The origin of structural relaxation in As40Se60 glass at different annealing temperatures is studied by differential scanning calorimetry (DSC) and in situ extended X-ray absorption fine structure (EXAFS) methods. Strong physical aging effect, expressed through the increase of endothermic peak area in the vicinity of Tg, is recorded by DSC technique at the annealing temperatures Ta>90oC. EXAFS data show that the observed structural relaxation is not associated with significant changes in the short-range order of this glass. An explanation is proposed for this relaxation behavior assuming temperature-dependent constraints. -- Highlights: → In this study we report experimental evidence for temperature-dependent constraints theory. → Structural relaxation of As2Se3 glass at higher annealing temperatures is studied by DSC technique. → Accompanied changes in the structure are monitored by in situ EXAFS measurements.

  20. Temperature dependence of the velocity of longitudinal ultrasonic wave propagation in steels

    International Nuclear Information System (INIS)

    Results of measurement of the velocity of longitudinal ultrasonic wave propagation in low-alloy steels as well as in armco-iron and in invar alloy at 700-1000 deg C are given. Temperature dependences are shown to be nonlinear, the largest drop of the curve takes place in the region of the Curie temperature. Decrease of the velocity of longitudinal ultrasonic waves reaches 8% within the temperature range of investigation. Effect of the magnetic phase transition on the temperature dependence of the velocity of ultrasound propagation (drop of the curve is maximum in the Curie point region) is also established. Investigation results are used to correct data on ultrasonic contactless control of wall thickness of hot-rolled tubes at high temperatures

  1. Temperature-dependent structural relaxation in As{sub 40}Se{sub 60} glass

    Energy Technology Data Exchange (ETDEWEB)

    Golovchak, R., E-mail: roman_ya@yahoo.com [Lviv Sci. and Res. Institute of Materials of SRC ' Carat' , 202 Stryjska str., 79031 Lviv (Ukraine); Kozdras, A. [Opole University of Technology, 75, Ozimska str., Opole, PL-45370 (Poland); Academy of Management and Administration, 18 Niedzialkowski str., Opole, PL-45085 (Poland); Shpotyuk, O. [Jan Dlugosz University, 13/15, al. Armii Krajowej, 42201, Czestochowa (Poland); Gorecki, Cz. [Opole University of Technology, 75, Ozimska str., Opole, PL-45370 (Poland); Kovalskiy, A.; Jain, H. [Department of Materials Science and Engineering, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015-3195 (United States)

    2011-08-01

    The origin of structural relaxation in As{sub 40}Se{sub 60} glass at different annealing temperatures is studied by differential scanning calorimetry (DSC) and in situ extended X-ray absorption fine structure (EXAFS) methods. Strong physical aging effect, expressed through the increase of endothermic peak area in the vicinity of T{sub g}, is recorded by DSC technique at the annealing temperatures T{sub a}>90{sup o}C. EXAFS data show that the observed structural relaxation is not associated with significant changes in the short-range order of this glass. An explanation is proposed for this relaxation behavior assuming temperature-dependent constraints. -- Highlights: → In this study we report experimental evidence for temperature-dependent constraints theory. → Structural relaxation of As{sub 2}Se{sub 3} glass at higher annealing temperatures is studied by DSC technique. → Accompanied changes in the structure are monitored by in situ EXAFS measurements.

  2. Temperature dependence of light power propagation in bending plastic optical fiber

    Science.gov (United States)

    Jing, Ning; Teng, Chuanxin; Zheng, Jie; Wang, Guanjun; Zhang, Minjuan; Wang, Zhibin

    2016-09-01

    This study investigates the effect of temperature variation on the light power propagation in bending plastic optical fiber (POF). The transmittance of bending POFs with curvature radius of 2-30 mm and turns of 1/4, 1/2, 1, and 2 are measured over temperature of 20-70 °C. The temperature dependent loss of the bending POF is obtained. It is found that the temperature dependent loss of the bending POF changes with curvature radius and turns. The temperature effect reaches the highest value of 0.011 dB/°C with 2 turns, and is less than 0.002 dB/°C with curvature radius greater than 25 mm.

  3. Temperature Dependence of Sound Velocity in High-Strength Fiber-Reinforced Plastics

    Science.gov (United States)

    Nomura, Ryuji; Yoneyama, Keiichi; Ogasawara, Futoshi; Ueno, Masashi; Okuda, Yuichi; Yamanaka, Atsuhiko

    2003-08-01

    Longitudinal sound velocity in unidirectional hybrid composites or high-strength fiber-reinforced plastics (FRPs) was measured along the fiber axis over a wide temperature range (from 77 K to 420 K). We investigated two kinds of high-strength crystalline polymer fibers, polyethylene (Dyneema) and polybenzobisoxazole (Zylon), which are known to have negative thermal expansion coefficients and high thermal conductivities along the fiber axis. Both FRPs had very high sound velocities of about 9000 m/s at low temperatures and their temperature dependences were very strong. Sound velocity monotonically decreased with increasing temperature. The temperature dependence of sound velocity was much stronger in Dyneema-FRP than in Zylon-FRP.

  4. Temperature dependent two-phase behaviour of magnetisation and spin polarisation in NiPt

    Energy Technology Data Exchange (ETDEWEB)

    Schaefers, Markus; Thomas, Andy; Reiss, Guenter [Bielefeld University, Universitaetsstrasse 25, D-33615 Bielefeld (Germany)

    2007-07-01

    We investigated the temperature dependent behaviour of magnetisation and spin polarisation in NiCu and NiPt alloys. The advantage of these alloys is the reduced Curie temperature compared with pure Nickel. The whole range of magnetisation is accessible in experiment for these alloys. Magnetic tunnel junctions with these alloys as free electrode were prepared by dc-magnetron sputtering in an UHV system with a base pressure of 1 . 10{sup -7} mbar and argon ion beam etching. TMR ratio was measured temperature dependent with a dc 2-point method. Spin polarisation was calculated by Julliere's formula. Magnetisation was measured with a SQUID for different temperatures. The NiPt alloy showed a maximum for in-plane magnetisation and spin polarisation at about 190 K. There are indications for a perpendicular magnetic anisotropy at low temperatures in the NiPt alloy.

  5. Temperature dependence of the photoluminescence of MnS/ZnS core—shell quantum dots

    Science.gov (United States)

    Fang, Dai-Feng; Ding, Xing; Dai, Ru-Cheng; Zhao, Zhi; Wang, Zhong-Ping; Zhang, Zeng-Ming

    2014-12-01

    The temperature dependence of the photoluminescence (PL) from MnS/ZnS core—shell quantum dots is investigated in a temperature range of 8 K-300 K. The orange emission from the 4T1 → 6A1 transition of Mn2+ ions and the blue emission related to the trapped surface state are observed in the MnS/ZnS core—shell quantum dots. As the temperature increases, the orange emission is shifted toward a shorter wavelength while the blue emission is shifted towards the longer wavelength. Both the orange and blue emissions reduce their intensities with the increase of temperature but the blue emission is quenched faster. The temperature-dependent luminescence intensities of the two emissions are well explained by the thermal quenching theory.

  6. Surface Temperature Dependence of Hydrogen Ortho-Para Conversion on Amorphous Solid Water

    Science.gov (United States)

    Ueta, Hirokazu; Watanabe, Naoki; Hama, Tetsuya; Kouchi, Akira

    2016-06-01

    The surface temperature dependence of the ortho-to-para conversion of H2 on amorphous solid water is first reported. A combination of photostimulated desorption and resonance-enhanced multiphoton ionization techniques allowed us to sensitively probe the conversion on the surface of amorphous solid water at temperatures of 9.2-16 K. Within a narrow temperature window of 8 K, the conversion time steeply varied from ˜4.1 ×103 to ˜6.4 ×102 s . The observed temperature dependence is discussed in the context of previously suggested models and the energy dissipation process. The two-phonon process most likely dominates the conversion rate at low temperatures.

  7. Temperature Dependence of Exchange Bias and Coercivity in Ferromagnetic Layer Coupled with Polycrystalline Antiferromagnetic Layer

    Institute of Scientific and Technical Information of China (English)

    ZHAO Jin-Wei; HU Jing-Guo; CHEN Guang

    2004-01-01

    The temperature dependence of exchange bias and coercivity in a ferromagnetic layer coupled with an antiferromagnetic layer is discussed.In this model,the temperature dependence comes from the thermal instability of the system states and the temperature modulated relative magnetic parameters.Morever,the thermal fluctuation of orientations of easy axes of antiferromagnetic grains at preparing has been considered.From the present model,the experimental results can be illustrated qualitatively for available magnetic parameters.Based on our discussion,we can conclude that soft ferromagnetic layer coupled by hard antiferromagnetic layer may be very applicable to design magnetic devices.In special exchange coupling,we can get high exchange bias and low coercivity almost independent of temperature for proper temperature ranges.

  8. Temperature-dependent striped antiferromagnetism of LaFeAsO in a Green's function approach.

    Science.gov (United States)

    Liu, Gui-Bin; Liu, Bang-Gui

    2009-05-13

    We use a Green's function method to study the temperature-dependent average moment and magnetic phase-transition temperature of the striped antiferromagnetism of LaFeAsO, and other similar compounds, as the parents of FeAs-based superconductors. We consider the nearest and the next-nearest couplings in the FeAs layer, and the nearest coupling for inter-layer spin interaction. The dependence of the transition temperature T(N) and the zero-temperature average spin on the interaction constants is investigated. We obtain an analytical expression for T(N) and determine our temperature-dependent average spin from zero temperature to T(N) in terms of unified self-consistent equations. For LaFeAsO, we obtain a reasonable estimation of the coupling interactions with the experimental transition temperature T(N) = 138 K. Our results also show that a non-zero antiferromagnetic (AFM) inter-layer coupling is essential for the existence of a non-zero T(N), and the many-body AFM fluctuations reduce substantially the low-temperature magnetic moment per Fe towards the experimental value. Our Green's function approach can be used for other FeAs-based parent compounds and these results should be useful to understand the physical properties of FeAs-based superconductors.

  9. Tuning anomalous Hall conductivity in L1[sub 0] FePt films by long range chemical ordering

    KAUST Repository

    Chen, M.

    2011-02-24

    For L10 FePt films, the anomalous Hall conductivity σ xy=-a σxx-b, where a=a0f(T), b=b 0f(T), and f (T) is the temperature dependence factor of the spontaneous magnetization. With increasing chemical long range ordering S, a0 changes its sign accompanied by a reduction of its magnitude and b0 increases monotonically. The spin-orbit coupling strength is suggested to increase with increasing S. As an approach, the long range chemical ordering can be used to control the anomalous Hall effect in ferromagnetic alloy films. © 2011 American Institute of Physics.

  10. Unusual temperature dependence of the dissociative electron attachment cross section of 2-thiouracil.

    Science.gov (United States)

    Kopyra, Janina; Abdoul-Carime, Hassan

    2016-01-21

    At low energies (ion, can be initiated by shape resonance or vibrational Feshbach resonance (VFR) mediated by the formation of a dipole bound anion. The temperature dependence for shape-resonances is well established; however, no experimental information is available yet on the second mechanism. Here, we show that the dissociation cross section for VFRs mediated by the formation of a dipole bound anion decreases as a function of a temperature. The change remains, however, relatively small in the temperature range of 370-440 K but it might be more pronounced at the extended temperature range. PMID:26801033

  11. Temperature-Dependent Raman Spectra and Microstructure of Barium Metaborate Crystals and Its Melts

    Institute of Scientific and Technical Information of China (English)

    尤静林; 蒋国昌; 侯怀宇; 吴永全; 陈辉; 徐匡迪

    2002-01-01

    We have measured the Raman spectra of β- and α-barium metaborate in crystal and liquid states from room temperature to 1873K, with a semiconductor laser as the laser source, coupled with a time-resolved detection system to eliminate the dense thermal emission background when temperature was considerably high.Temperature-dependent Raman spectra can clearly indicate that the phase transformation from β- to α-barium metaborate has been completed during 1273 - 1300 K. Variations of different kinds of microstructure units with temperature are identified and discussed.

  12. Temperature-dependent fluorescence quenching of a cavitand derivative by copper ions

    Science.gov (United States)

    Secenji, Györgyi; Matisz, Gergely; Csók, Zsolt; Kollár, László; Kunsági-Máté, Sándor

    2016-07-01

    Temperature dependence of fluorescence quenching of a cavitand derivative by Cu2+ ion has been studied in dimethylformamide solution. Results derived from PL studies highlighted two temperature regions where the formation of cavitand-Cu2+ complexes is based on significantly different molecular processes. From the experimental results and the comparison of the calculated interaction energies of the possible complex structures obtained by density functional calculations, it is assumed that at lower temperatures the Cu2+ ion takes place in the cavity while at higher temperature region Cu2+ is coordinated to the outer part of the cavitand with its almost retained solvation shell.

  13. Dependence of nitrogen concentration in type Ib diamonds on synthesis temperature

    Institute of Scientific and Technical Information of China (English)

    TIAN Yu; JIA XiaoPeng; ZANG ChuanYi; LI ShangSheng; XIAO HongYu; ZHANG YaFei; HUANG GuoFeng; LI Rui; HAN QiGang; MA LiQiu; LI Yong; CHEN XiaoZhou; ZHANG Chong; MA HongAn

    2009-01-01

    Type Ib diamonds were grown by the temperature gradient method (TGM) at 5.5 GPa and 1500-1560 K in a china-type cubic anvil high pressure apparatus using Ni70Mn25Co5 alloy as solvent/catalyst. The concentration of nitrogen (CN) in type Ib diamonds synthesized at different synthesis temperatures was measured by a Fourier transform infrared (FTIR) spectrometer. The dependence of CN in diamond on synthesis temperature was studied. For the type Ib diamonds synthesized using Ni70Mn25Co5 as catalyst, its CN decreases along with the increase of synthesis temperature.

  14. Temperature dependence of I-V characteristics of C60 molecule

    Directory of Open Access Journals (Sweden)

    SA Ketabi

    2010-06-01

    Full Text Available Making use of a generalized Green’s function technique and Landauer formalism, the temperature depended current-voltage (I-V characteristics of C60 molecule, sandwiched between two metallic electrodes are numerically investigated. In addition, the influence of the electron-phonon coupling strength on the electronic properties of the molecule is studied. The I-V characteristics of the molecule are determined in two temperature limits, T=3K and T=300K. Our results indicate that the molecule primarily acts as a semiconductor in lower temperatures but moves toward becoming an ohmic-like conductor when the temperature increased to the higher magnitudes.

  15. Spatial organization and time dependence of Jupiter's tropospheric temperatures, 1980-1993

    Science.gov (United States)

    Orton, Glenn S.; Friedson, A. James; Yanamandra-Fisher, Padmavati A.; Caldwell, John; Hammel, Heidi B.; Baines, Kevin H.; Bergstralh, Jay T.; Martin, Terry Z.; West, Robert A.; Veeder, Glenn J., Jr.

    1994-01-01

    The spatial organization and time dependence of Jupiter's temperature near 250-millibar pressure were measured through a jovian year by imaging thermal emission at 18 micrometers. The temperature field is influenced by seasonal radiative forcing, and its banded organization is closely correlated with the visible cloud field. Evidence was found for a quasi-periodic oscillation of temperatures in the Equatorial Zone, a correlation between tropospheric and stratospheric waves in the North Equatorial Belt, and slowly moving thermal features in the North and South Equatorial Belts. There appears to be no common relation between temporal changes of temperature and changes in the visual albedo of the various axisymmetric bands.

  16. Anomalous Higgs couplings

    CERN Document Server

    González-Garciá, M Concepción

    1999-01-01

    We review the effects of new effective interactions on Higgs-boson phenomenology. New physics in the electroweak bosonic sector is expected to induce additional interactions between the Higgs doublet field and the electroweak gauge bosons, leading to anomalous Higgs couplings as well as anomalous gauge-boson self-interactions. Using a linearly realized SU(2)/sub L/*U(1)/sub Y/ invariant effective Lagrangian to describe the bosonic sector of the Standard Model, we review the effects of the new effective interactions on the Higgs- boson production rates and decay modes. We summarize the results from searches for the new Higgs signatures induced by the anomalous interactions in order to constrain the scale of new physics, in particular at CERN LEP and Fermilab Tevatron colliders. (43 refs).

  17. Mechanisms of temperature-dependent swimming: the importance of physics, physiology and body size in determining protist swimming speed

    OpenAIRE

    Beveridge, Oliver S; Petchey, Owen L; Humphries, Stuart

    2010-01-01

    Body temperatures and thus physiological rates of poikilothermic organisms are determined by environmental temperature. The power an organism has available for swimming is largely dependent on physiological rates and thus body temperature. However, retarding forces such as drag are contingent on the temperature-dependent physical properties of water and on an organism’s size. Consequently, the swimming ability of poikilotherms is highly temperature dependent. The importance of the te...

  18. Assessing the Temperature Dependence of Narrow-Band Raman Water Vapor Lidar Measurements: A Practical Approach

    Science.gov (United States)

    Whiteman, David N.; Venable, Demetrius D.; Walker, Monique; Cardirola, Martin; Sakai, Tetsu; Veselovskii, Igor

    2013-01-01

    Narrow-band detection of the Raman water vapor spectrum using the lidar technique introduces a concern over the temperature dependence of the Raman spectrum. Various groups have addressed this issue either by trying to minimize the temperature dependence to the point where it can be ignored or by correcting for whatever degree of temperature dependence exists. The traditional technique for performing either of these entails accurately measuring both the laser output wavelength and the water vapor spectral passband with combined uncertainty of approximately 0.01 nm. However, uncertainty in interference filter center wavelengths and laser output wavelengths can be this large or larger. These combined uncertainties translate into uncertainties in the magnitude of the temperature dependence of the Raman lidar water vapor measurement of 3% or more. We present here an alternate approach for accurately determining the temperature dependence of the Raman lidar water vapor measurement. This alternate approach entails acquiring sequential atmospheric profiles using the lidar while scanning the channel passband across portions of the Raman water vapor Q-branch. This scanning is accomplished either by tilt-tuning an interference filter or by scanning the output of a spectrometer. Through this process a peak in the transmitted intensity can be discerned in a manner that defines the spectral location of the channel passband with respect to the laser output wavelength to much higher accuracy than that achieved with standard laboratory techniques. Given the peak of the water vapor signal intensity curve, determined using the techniques described here, and an approximate knowledge of atmospheric temperature, the temperature dependence of a given Raman lidar profile can be determined with accuracy of 0.5% or better. A Mathematica notebook that demonstrates the calculations used here is available from the lead author.

  19. A space and time scale-dependent nonlinear geostatistical approach for downscaling daily precipitation and temperature

    KAUST Repository

    Jha, Sanjeev Kumar

    2015-07-21

    A geostatistical framework is proposed to downscale daily precipitation and temperature. The methodology is based on multiple-point geostatistics (MPS), where a multivariate training image is used to represent the spatial relationship between daily precipitation and daily temperature over several years. Here, the training image consists of daily rainfall and temperature outputs from the Weather Research and Forecasting (WRF) model at 50 km and 10 km resolution for a twenty year period ranging from 1985 to 2004. The data are used to predict downscaled climate variables for the year 2005. The result, for each downscaled pixel, is daily time series of precipitation and temperature that are spatially dependent. Comparison of predicted precipitation and temperature against a reference dataset indicates that both the seasonal average climate response together with the temporal variability are well reproduced. The explicit inclusion of time dependence is explored by considering the climate properties of the previous day as an additional variable. Comparison of simulations with and without inclusion of time dependence shows that the temporal dependence only slightly improves the daily prediction because the temporal variability is already well represented in the conditioning data. Overall, the study shows that the multiple-point geostatistics approach is an efficient tool to be used for statistical downscaling to obtain local scale estimates of precipitation and temperature from General Circulation Models. This article is protected by copyright. All rights reserved.

  20. Effects of activation energy and activation volume on the temperature-dependent viscosity of water

    Science.gov (United States)

    Kwang-Hua, Chu Rainer

    2016-08-01

    Water transport in a leaf is vulnerable to viscosity-induced changes. Recent research has suggested that these changes may be partially due to variation at the molecular scale, e.g., regulations via aquaporins, that induce reductions in leaf hydraulic conductance. What are the quantitative as well as qualitative changes in temperature-dependent viscosity due to the role of aquaporins in tuning activation energy and activation volume? Using the transition-state approach as well as the boundary perturbation method, we investigate temperature-dependent viscosity tuned by activation energy and activation volume. To validate our approach, we compare our numerical results with previous temperature-dependent viscosity measurements. The rather good fit between our calculations and measurements confirms our present approach. We have obtained critical parameters for the temperature-dependent (shear) viscosity of water that might be relevant to the increasing and reducing of leaf hydraulic conductance. These parameters are sensitive to temperature, activation energy, and activation volume. Once the activation energy increases, the (shear) viscosity of water increases. Our results also show that as the activation volume increases (say, 10-23m3 ), the (shear) viscosity of water decreases significantly and the latter induces the enhancing of leaf hydraulic conductance. Within the room-temperature regime, a small increase in the activation energy will increase the water viscosity or reduce the leaf hydraulic conductance. Our approach and results can be applied to diverse plant or leaf attributes.

  1. Temperature dependence of the superconducting proximity effect quantified by scanning tunneling spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Stępniak, A.; Caminale, M.; Leon Vanegas, A. A.; Oka, H.; Sander, D., E-mail: sander@mpi-halle.mpg.de [Max-Planck-Institut für Mikrostrukturphysik, Weinberg 2, 06120 Halle (Saale) (Germany); Kirschner, J. [Max-Planck-Institut für Mikrostrukturphysik, Weinberg 2, 06120 Halle (Saale) (Germany); Institut für Physik, Martin-Luther-Universität Halle-Wittenberg, 06120 Halle (Saale) (Germany)

    2015-01-15

    Here, we present the first systematic study on the temperature dependence of the extension of the superconducting proximity effect in a 1–2 atomic layer thin metallic film, surrounding a superconducting Pb island. Scanning tunneling microscopy/spectroscopy (STM/STS) measurements reveal the spatial variation of the local density of state on the film from 0.38 up to 1.8 K. In this temperature range the superconductivity of the island is almost unaffected and shows a constant gap of a 1.20 ± 0.03 meV. Using a superconducting Nb-tip a constant value of the proximity length of 17 ± 3 nm at 0.38 and 1.8 K is found. In contrast, experiments with a normal conductive W-tip indicate an apparent decrease of the proximity length with increasing temperature. This result is ascribed to the thermal broadening of the occupation of states of the tip, and it does not reflect an intrinsic temperature dependence of the proximity length. Our tunneling spectroscopy experiments shed fresh light on the fundamental issue of the temperature dependence of the proximity effect for atomic monolayers, where the intrinsic temperature dependence of the proximity effect is comparably weak.

  2. Anomalous chiral superfluidity

    Energy Technology Data Exchange (ETDEWEB)

    Lublinsky, Michael, E-mail: lublinsky@phys.uconn.ed [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794 (United States); Physics Department, Ben-Gurion University, Beer Sheva 84105 (Israel); Zahed, Ismail [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794 (United States)

    2010-02-08

    We discuss both the anomalous Cartan currents and the energy-momentum tensor in a left chiral theory with flavor anomalies as an effective theory for flavored chiral phonons in a chiral superfluid with the gauged Wess-Zumino-Witten term. In the mean-field (leading tadpole) approximation the anomalous Cartan currents and the energy-momentum tensor take the form of constitutive currents in the chiral superfluid state. The pertinence of higher order corrections and the Adler-Bardeen theorem is briefly noted.

  3. Temperature dependence of a microstructured SiC coherent thermal source

    Science.gov (United States)

    Hervé, Armande; Drévillon, Jérémie; Ezzahri, Younès; Joulain, Karl; De Sousa Meneses, Domingos; Hugonin, Jean-Paul

    2016-09-01

    By ruling a grating on a polar material that supports surface phonon-polaritons such as silicon carbide (SiC), it is possible to create directional and monochromatic thermal sources. So far, most of the studies have considered only materials with room temperature properties as the ones tabulated in Palik's handbooks. Recently, measurements have provided experimental data of the SiC dielectric function at different temperatures. Here we study, numerically, the effect of the temperature dependence of the dielectric function on the thermal emission of SiC gratings (1D grating, in a first approach), heated at different temperatures. When materials are heated, the position of the grating emissivity peak shifts towards higher wavelength values. A second consequence of the temperature dependence of optical properties is that room temperature designed gratings are not optimal for higher temperatures. However, by modifying the grating parameters, it is possible to find an emission peak, with a maximum of emissivity near 1, for each temperature. We tried first to catch some patterns in the emissivity variation. Then, we obtained a grating, which leads to an optimum emissivity for all available temperature data for SiC.

  4. Temperature and humidity dependence of secondary organic aerosol yield from the ozonolysis of β-pinene

    Directory of Open Access Journals (Sweden)

    C. von Hessberg

    2009-06-01

    Full Text Available The temperature dependence of secondary organic aerosol (SOA formation from ozonolysis of β-pinene was studied in a flow reactor at 263 K–303 K and 1007 hPa under dry and humid conditions (0% and 26%–68% relative humidity, respectively. The observed SOA yields reached maximum values of 0.18–0.39 at high particle mass concentrations (Mo. Under dry conditions, the measurement data showed an overall increase in SOA yield with inverse temperature, but significant oscillatory deviations from the predicted linear increase with inverse temperature (up to 50% at high Mo was observed. Under humid conditions the SOA yield exhibited a linear decrease with inverse temperature. For the atmospherically relevant concentration level of Mo=10 μg m−3 and temperature range 263 K–293 K, the results from humid experiments in this study indicate that the SOA yield of β-pinene ozonolysis may be well represented by an average value of 0.15 with an uncertainty estimate of ±0.05. When fitting the measurement data with a two-product model, both the partitioning coefficients (Kom,i and the stoichiometric yields (αi of the low-volatile and semi-volatile model species were found to vary with temperature. The results indicate that not only the reaction product vapour pressures but also the relative contributions of different gas-phase or multiphase reaction channels are strongly dependent on temperature and the presence of water vapour. In fact, the oscillatory positive temperature dependence observed under dry conditions and the negative temperature dependence observed under humid conditions indicate that the SOA yield is governed much more by the temperature and humidity dependence of the involved chemical reactions than by vapour pressure temperature dependencies. We suggest that the elucidation and modelling of SOA formation need to take into account the

  5. Temperature-dependent minority carrier lifetime of crystalline silicon wafers passivated by high quality amorphous silicon oxide

    Science.gov (United States)

    Inaba, Masahiro; Todoroki, Soichiro; Nakada, Kazuyoshi; Miyajima, Shinsuke

    2016-04-01

    We investigated the effects of annealing on the temperature-dependent minority carrier lifetime of a crystalline silicon wafer passivated by hydrogenated amorphous silicon oxide. The annealing significantly affects the lifetime and its temperature dependence. Our device simulations clearly indicate that valence band offset significantly affects the temperature dependence. We also found a slight increase in the interface defect density after annealing.

  6. Modeling and Compensating Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras.

    Science.gov (United States)

    Wolf, Alejandro; Pezoa, Jorge E; Figueroa, Miguel

    2016-07-19

    Images rendered by uncooled microbolometer-based infrared (IR) cameras are severely degraded by the spatial non-uniformity (NU) noise. The NU noise imposes a fixed-pattern over the true images, and the intensity of the pattern changes with time due to the temperature instability of such cameras. In this paper, we present a novel model and a compensation algorithm for the spatial NU noise and its temperature-dependent variations. The model separates the NU noise into two components: a constant term, which corresponds to a set of NU parameters determining the spatial structure of the noise, and a dynamic term, which scales linearly with the fluctuations of the temperature surrounding the array of microbolometers. We use a black-body radiator and samples of the temperature surrounding the IR array to offline characterize both the constant and the temperature-dependent NU noise parameters. Next, the temperature-dependent variations are estimated online using both a spatially uniform Hammerstein-Wiener estimator and a pixelwise least mean squares (LMS) estimator. We compensate for the NU noise in IR images from two long-wave IR cameras. Results show an excellent NU correction performance and a root mean square error of less than 0.25 ∘ C, when the array's temperature varies by approximately 15 ∘ C.

  7. Modeling and Compensating Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras.

    Science.gov (United States)

    Wolf, Alejandro; Pezoa, Jorge E; Figueroa, Miguel

    2016-01-01

    Images rendered by uncooled microbolometer-based infrared (IR) cameras are severely degraded by the spatial non-uniformity (NU) noise. The NU noise imposes a fixed-pattern over the true images, and the intensity of the pattern changes with time due to the temperature instability of such cameras. In this paper, we present a novel model and a compensation algorithm for the spatial NU noise and its temperature-dependent variations. The model separates the NU noise into two components: a constant term, which corresponds to a set of NU parameters determining the spatial structure of the noise, and a dynamic term, which scales linearly with the fluctuations of the temperature surrounding the array of microbolometers. We use a black-body radiator and samples of the temperature surrounding the IR array to offline characterize both the constant and the temperature-dependent NU noise parameters. Next, the temperature-dependent variations are estimated online using both a spatially uniform Hammerstein-Wiener estimator and a pixelwise least mean squares (LMS) estimator. We compensate for the NU noise in IR images from two long-wave IR cameras. Results show an excellent NU correction performance and a root mean square error of less than 0.25 ∘ C, when the array's temperature varies by approximately 15 ∘ C. PMID:27447637

  8. Modeling and Compensating Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras

    Directory of Open Access Journals (Sweden)

    Alejandro Wolf

    2016-07-01

    Full Text Available Images rendered by uncooled microbolometer-based infrared (IR cameras are severely degraded by the spatial non-uniformity (NU noise. The NU noise imposes a fixed-pattern over the true images, and the intensity of the pattern changes with time due to the temperature instability of such cameras. In this paper, we present a novel model and a compensation algorithm for the spatial NU noise and its temperature-dependent variations. The model separates the NU noise into two components: a constant term, which corresponds to a set of NU parameters determining the spatial structure of the noise, and a dynamic term, which scales linearly with the fluctuations of the temperature surrounding the array of microbolometers. We use a black-body radiator and samples of the temperature surrounding the IR array to offline characterize both the constant and the temperature-dependent NU noise parameters. Next, the temperature-dependent variations are estimated online using both a spatially uniform Hammerstein-Wiener estimator and a pixelwise least mean squares (LMS estimator. We compensate for the NU noise in IR images from two long-wave IR cameras. Results show an excellent NU correction performance and a root mean square error of less than 0.25 ∘ C, when the array’s temperature varies by approximately 15 ∘ C.

  9. Angular radiation temperature simulation for time-dependent capsule drive prediction in inertial confinement fusion

    Energy Technology Data Exchange (ETDEWEB)

    Jing, Longfei; Yang, Dong; Li, Hang; Zhang, Lu; Lin, Zhiwei; Li, Liling; Kuang, Longyu [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Jiang, Shaoen, E-mail: jiangshn@vip.sina.com; Ding, Yongkun [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Center for Applied Physics and Technology, Peking University, Beijing 100871 (China); Huang, Yunbao, E-mail: huangyblhy@gmail.com [Mechatronics School of Guangdong University of Technology, Guangzhou 510080 (China)

    2015-02-15

    The x-ray drive on a capsule in an inertial confinement fusion setup is crucial for ignition. Unfortunately, a direct measurement has not been possible so far. We propose an angular radiation temperature simulation to predict the time-dependent drive on the capsule. A simple model, based on the view-factor method for the simulation of the radiation temperature, is presented and compared with the experimental data obtained using the OMEGA laser facility and the simulation results acquired with VISRAD code. We found a good agreement between the time-dependent measurements and the simulation results obtained using this model. The validated model was then used to analyze the experimental results from the Shenguang-III prototype laser facility. More specifically, the variations of the peak radiation temperatures at different view angles with the albedo of the hohlraum, the motion of the laser spots, the closure of the laser entrance holes, and the deviation of the laser power were investigated. Furthermore, the time-dependent radiation temperature at different orientations and the drive history on the capsule were calculated. The results indicate that the radiation temperature from “U20W112” (named according to the diagnostic hole ID on the target chamber) can be used to approximately predict the drive temperature on the capsule. In addition, the influence of the capsule on the peak radiation temperature is also presented.

  10. Fabrication and temperature dependence of a GaInP/GaAs/Ge tandem solar cell

    Institute of Scientific and Technical Information of China (English)

    崔敏; 陈诺夫; 杨晓丽; 张汉

    2012-01-01

    GaInP/GaAs/Ge tandem solar cells were fabricated by a MOCVD technique.The photoelectric properties of the solar cells were characterized by a current-voltage test method.The dependence of the solar cell's characteristics on temperature were investigated from 30 to 170 ℃ at intervals of 20 ℃.Test results indicated that with increasing temperature,Jsc of the cell increased slightly with a temperature coefficient of 9.8 (μA/cm2)/℃.Voc reduced sharply with a coefficient of-5.6 mV/℃.FF was reduced with a temperature coefficient of-0.00063/℃.Furthermore,the conversion efficiency decreased linearly with increasing temperature which decreased from 28% at 30 ℃ to 22.1% at 130 ℃.Also,detailed theoretical analyses for temperature characteristics of the solar cell were given.

  11. Temperature Dependence of the Raman Spectra of Na2Si2O5

    Institute of Scientific and Technical Information of China (English)

    YOU Jing-Lin; JIANG Guo-Chang; XU Kuang-Di

    2001-01-01

    The microstructures of Na2Si2O5 from room temperature up to 1773 K are studied by high-temperature Paman spectroscopy. Deconvolutions of complex Raman spectra of crystal and amorphous states (glass and melt) are described. The results show that the temperature-dependent Raman spectra clearly indicate phase transition.The relative abundance of various kinds of SiO4 tetrahedrons (each Si binding to different numbers of bridging oxygens) can be qualitatively and quantitatively resolved as to be varied obviously with different temperatures.This shows that high-temperature Raman spectroscopy provides a useful tool for microstructure research under high temperature and helps to explain the properties of silicate glasses and melts.

  12. Temperature dependence of FMR and magnetization in nanocrystalline zinc ferrite thin films

    Science.gov (United States)

    Sahu, B. N.; Doshi, Akash S.; Prabhu, R.; Venkataramani, N.; Prasad, Shiva; Krishnan, R.

    2016-05-01

    Single phase nano-crystalline zinc ferrite thin films were deposited by RF-magnetron sputtering on quartz substrate at room temperature (RT) in pure Argon environment and annealed (in air) at different temperatures. Temperature dependence of magnetization was studied on these films using both VSM and by observing FMR (in X band). Value of exchange stiffness constant (D) was obtained by fitting Bloch's law to the low temperature magnetization data. The value of D decreased monotonously with the annealing temperature (TA) of the samples. A film annealed at TA = 523 K, exhibited the highest magnetization value. The FMR line width of the films decreased with increase in measurement temperature. At RT (˜293 K), the lowest value of line width (ΔH) was 15 kA/m and 13 kA/m in parallel and perpendicular configuration respectively for the sample annealed at TA = 623 K.

  13. Frequency analysis of temperature-dependent interferometric signal for the measurement of the temperature coefficient of refractive index

    Science.gov (United States)

    Zhou, Jianqin; Shen, Jun; Neill, W. Stuart

    2016-07-01

    A method of frequency analysis for the measurement of the temperature coefficient of refractive index (dn/dT) using a Fabry-Perot interferometer was developed and tested against ethanol and water. The temperature-dependent interferometric signal described by Airy's formula was analyzed in both the temperature and frequency domains. By fast Fourier transform, a low-pass filter was designed and employed to eliminate the noise superimposed on the signal. dn/dT was determined accurately from the noise-removed signal by peak analysis. Furthermore, the signal frequency parameters may be utilized for the material thermophysical property characterization. This method lays the foundation for an online dn/dT instrument for monitoring chemical processes.

  14. Implications of temperature dependent ferrite arrest toughness to an invariant master curve shape

    International Nuclear Information System (INIS)

    Full text of publication follows: The toughness temperature Kjc(T-T0) curves of ferritic-martensitic steels may have a remarkably invariant master curve (MC) shape, where the reference temperature, T0, depends on material and environmental/test conditions. For unirradiated alloys, with T0 jc(T) is governed almost entirely by the temperature dependence of σy(T). Irradiation hardening, Δσy, increases T0(ΔT0). When T0 is in the athermal σy regime, the assumption of a temperature independent σ* predicts changes (layovers) in the shape of Kjc(T). This apparent contradiction with observation is resolved by assuming a mildly temperature dependent σ*(T) at higher temperatures. The temperature dependence is, in turn, controlled by the micro-arrest toughness of the material controlling the conditions for the propagation of microcracks formed at brittle trigger particles. Here we describe results of an independent study of the temperature dependent initiation (KIc) and arrest toughness (Ka) for (100)[010] and (100)[011] Fe single crystals oriented for cleavage, using specially designed composite specimen test techniques. The Ka(T) is weakly temperature dependent below about -100 deg. C, increasing from a minimum of 3.5 MPa√(m), but rises more rapidly to 9 MPa√(m) at higher temperatures near 0 deg. C. Static and dynamic Kic/d(T) curves were also measured over a wide range of loading rates from about 0.1 to 20,000 MPa √(m)/s. In all cases, the cleavage fracture dynamics were found to be controlled by nucleation of double kinks on screw dislocations, that also control the flow stress dynamics. When plotted on a strain rate compensated temperature, T', the arrest and initiation data overlap to form a Ka(T') master curve. The results were extended complex alloys by proposing that both the thermal and athermal contributions to σy combine to control Ka(T) as a fitted model Ka(T') = C(σy)/σy(T) with a minimum Ka of about 3.5 MPa and where C(σy) is a weak function of

  15. INS, DFT and temperature dependent IR investigations of dynamical properties of low temperature phase of choline chloride

    Energy Technology Data Exchange (ETDEWEB)

    Pawlukojć, A., E-mail: andrzej@jinr.ru [Institute of Nuclear Chemistry and Technology, Dorodna 16 str., 03-195 Warsaw (Poland); Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Hetmańczyk, Ł. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Faculty of Chemistry, Jagiellonian University, Ingardena 3 str., 30-060 Cracow (Poland)

    2014-12-05

    Highlights: • Choline chloride was investigated by INS and IR. • DFT calculations for solids state model were performed. • Full vibrational analysis was performed. • Activation energy for the CH{sub 3} group reorientation was obtained. - Abstract: Within the framework of the research the inelastic neutron scattering and temperature dependent infra-red spectroscopy investigations of the low temperature phase of choline chloride were performed. The infra-red spectra in wavenumber region 4000–80 cm{sup −1} and in a temperature range 9–300 K were collected. The density functional theory calculations with the periodic boundary conditions for determination and description of the normal modes in the vibration spectra of choline chloride were applied. Bands assigned to the CH{sub 3} torsional vibration were observed at 288 and 249 cm{sup −1}. From the analysis of the temperature dependence of the full-width-at-half-maximum the activation energy for CH{sub 3} group reorientation is found to be equal to 1.6 ± 0.2 kcal/mol.

  16. Temperature dependence of the scintillation properties of Ce:GSO and Ce:GSOZ

    Energy Technology Data Exchange (ETDEWEB)

    Kurosawa, Shunsuke, E-mail: kurosawa@imr.tohoku.ac.jp [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); Sugiyama, Makoto [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); Yanagida, Takayuki [New Industry Creation Hatchery Center (NICHe), 6-6-10 Aoba Aramaki, Aoba-ku, Sendai, Miyagi 980-8579 (Japan); Yokota, Yuui [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); Yoshikawa, Akira [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan); New Industry Creation Hatchery Center (NICHe), 6-6-10 Aoba Aramaki, Aoba-ku, Sendai, Miyagi 980-8579 (Japan)

    2012-10-21

    The light output and decay times of Ce:GSO and Ce:GSOZ scintillators depend on Ce concentration and temperature. We investigated the temperature dependence of the light output and the decay time for Ce:GSO and Ce:GSOZ doped with 0.3 (only GSO), 0.5, 1.0, and 1.5 mol% Ce. These samples were measured with a ruggedized photomultiplier (PMT) (Hamamatsu R6877A) at 175 Degree-Sign C (in the thermostat chamber). Up to 100 Degree-Sign C, the relative light output of all of the samples remained within 10% after correcting the PMT gain, which depends on the temperature. The decay times of the GSO and GSOZ samples with the identical Ce concentrations were equal. Moreover, the quenching energy values for all the samples were equivalent.

  17. Plate-like convection induced by symmetries in fluids with temperature-dependent viscosity

    CERN Document Server

    Curbelo, Jezabel

    2014-01-01

    The study of instabilities in fluids in which viscosity experiences a transition at a certain temperature range is of great interest for the understanding of planetary interiors, since this phenomena models the melting and solidification of a magma ocean and thus is suitable for representing a lithosphere over a convecting mantle. To this end, we study a 2D convection problem in which viscosity depends on temperature by abruptly changing its value by a factor 400 within a narrow temperature gap at which magma melts. We perform a study which combines bifurcation analysis and time dependent simulations. Solutions such as limit cycles are found that are fundamentally related to the presence of symmetry. Sporadically during these cycles, through abrupt bursts, spontaneous plate-like behaviors that rapidly evolve towards a stagnant lid regime emerge. The plate-like evolution alternates motions towards either right or left, introducing temporary asymmetries on the convecting styles. Further time dependent regimes w...

  18. The Size Effect on the Temperature Dependence of the Resistivity of Metal Films

    Directory of Open Access Journals (Sweden)

    L.V. Odnodvorets

    2014-11-01

    Full Text Available The analysis of the temperature dependences of the electrical conductivity of thin metal films is per-formed. It is shown that the size dependence of the effective parameter of the electron-phonon interaction is connected with amplification of high-temperature electron-phonon interaction at the decrease in the film thickness which appears as a result of the shift of the phonon spectrum to higher frequencies. We have found that the slope of the experimental temperature dependences of the resistance for Pd, Pt, and Sc films, as in the case of Mo, Cr, Ag, Au, and PdAu films, according to the data of other authors, increases with the decrease in the thickness. As the film thickness decreases the average phonon energy increases that leads to the increase in the efficiency of the electron-phonon scattering and, finally, to the increase in the resistivity.

  19. Temperature dependence of meson screening masses; a comparison of effective model with lattice QCD

    CERN Document Server

    Ishii, Masahiro; Kashiwa, Kouji; Kouno, Hiroaki; Yahiro, Masanobu

    2015-01-01

    Temperature dependence of pion and sigma-meson screening masses is evaluated by the Polyakov-loop extended Nambu--Jona-Lasinio model with the entanglement vertex (EPNJL model). We propose a practical way of calculating meson screening masses in the NJL-type effective models. The method based on the Pauli-Villars regularization solves the well-known difficulty that the evaluation of screening masses is not easy in the NJL-type effective models. The method is applied to analyze temperature dependence of pion screening masses calculated with state-of-the-art lattice simulations with success in reproducing the lattice QCD results. We predict the temperature dependence of pole mass by using EPNJL model.

  20. Manipulating the temperature dependence of the thermal conductivity of graphene phononic crystal

    Science.gov (United States)

    Hu, Shiqian; An, Meng; Yang, Nuo; Li, Baowen

    2016-07-01

    By using non-equilibrium molecular dynamics simulations, modulating the temperature dependence of thermal conductivity of graphene phononic crystals (GPnCs) is investigated. It is found that the temperature dependence of thermal conductivity of GPnCs follows ∼T ‑α behavior. The power exponents (α) can be efficiently tuned by changing the characteristic size of GPnCs. The phonon participation ratio spectra and dispersion relation reveal that the long-range phonon modes are more affected in GPnCs with larger holes (L 0). Our results suggest that constructing GPnCs is an effective method to manipulate the temperature dependence of thermal conductivity of graphene, which would be beneficial for developing GPnC-based thermal management and signal processing devices.

  1. Temperature dependence of dislocation dynamics during nano-indentation in metals

    Science.gov (United States)

    Rathinam, Murugavel

    Temperature dictates mechanical properties of materials. In present day applications, materials are rarely utilized at room temperature alone. Meanwhile, temperatures may have drastic effects on the mechanical responses of materials, such as the deformation and fracture properties at different temperatures. Nanoscale testing of materials at non-ambient temperatures is now possible. The ability to perform nanotest measurements at elevated temperatures opens up significant new possibilities in nanotechnology. Sub-zero and high temperature analysis using nanoindentation technology is the first of its kind. Materials behave differently in real-life environments due to thermal loading. The objective of this thesis is to investigate the response of metals to nanoindentation at temperatures above and below the normal room temperature, using a combination of experiments and computer simulations. The metals studied include both face-center-cubic (FCC) and body-center-cubic (BCC) elements, and dislocation dynamics is the focus of this mechanics study. The experiments are performed with tailor-made Berkovitch tip of radius 100 nm at temperatures of 265 K, 388 K, 348 K, 473 K and 623 K. Single-crystals of tungsten, gold, Aluminum and polycrystalline copper are considered for the investigation. The indentation is done for BCC tungsten on the (111) and (110) crystallographic surfaces, FCC gold on the (111) and (110) crystallographic surfaces, single crystal aluminum with (100) crystallographic orientation and polycrystalline copper at different temperatures. Both the behaviour of material during loading and unloading are analyzed, and the processes are examined both experimentally and by computer simulations. Emphases are placed on the defects generation mechanisms during the elastic plastic contact of crystals. Special attention has been devoted to the elastic response before the onset of plastic yield. The temperature dependency experiments and computer simulations yield very

  2. Temperature and excitation power dependences of the photoluminescence in CdMnTe crystals

    International Nuclear Information System (INIS)

    We investigated the temperature and the excitation power dependences of the photoluminescence (PL) for Cd1-xMnxTe crystals with x = 0.45 grown using a vertical Bridgman method. At low temperatures, both near-band-edge and intra-Mn2+ emission peaks were observed. With increasing temperature, the band-edge emission peak clearly showed a red-shift while the Mn2+ emission band did not change monotonically. The temperature dependence of the band-edge emission intensity was demonstrated using a two-step quenching mechanism. Also, the intensity of the band-edge emission peak increased with increasing excitation power while the peak's position was red-shifted.

  3. Nonlinear temperature dependence of glue-induced birefringence in polarization maintaining FBG sensors

    Science.gov (United States)

    Hopf, Barbara; Koch, Alexander W.; Roths, Johannes

    2016-05-01

    Glue-induced stresses decrease the accuracy of surface-mounted fiber Bragg gratings (FBG). Significant temperature dependent glue-induced birefringence was verified when a thermally cured epoxy-based bonding technique had been used. Determining the peak separation of two azimuthally aligned FBGs in PM fibers combined with a polarization resolved measurement set-up in a temperature range between -30°C and 150°C revealed high glue-induced stresses at low temperatures. Peak separations of about 60 pm and a nonlinear temperature dependence of the glue-induced birefringence due to stress relaxation processes and a visco-elastic behavior of the used adhesive have been shown.

  4. Inverse Temperature Dependence of Nuclear Quantum Effects in DNA Base Pairs.

    Science.gov (United States)

    Fang, Wei; Chen, Ji; Rossi, Mariana; Feng, Yexin; Li, Xin-Zheng; Michaelides, Angelos

    2016-06-01

    Despite the inherently quantum mechanical nature of hydrogen bonding, it is unclear how nuclear quantum effects (NQEs) alter the strengths of hydrogen bonds. With this in mind, we use ab initio path integral molecular dynamics to determine the absolute contribution of NQEs to the binding in DNA base pair complexes, arguably the most important hydrogen-bonded systems of all. We find that depending on the temperature, NQEs can either strengthen or weaken the binding within the hydrogen-bonded complexes. As a somewhat counterintuitive consequence, NQEs can have a smaller impact on hydrogen bond strengths at cryogenic temperatures than at room temperature. We rationalize this in terms of a competition of NQEs between low-frequency and high-frequency vibrational modes. Extending this idea, we also propose a simple model to predict the temperature dependence of NQEs on hydrogen bond strengths in general. PMID:27195654

  5. An improved temperature-dependent large signal model of microwave GaN HEMTs

    Science.gov (United States)

    Changsi, Wang; Yuehang, Xu; Zhang, Wen; Zhikai, Chen; Ruimin, Xu

    2016-07-01

    Accurate modeling of the electrothermal effects of GaN electronic devices is critical for reliability design and assessment. In this paper, an improved temperature-dependent model for large signal equivalent circuit modeling of GaN HEMTs is proposed. To accurately describe the thermal effects, a modified nonlinear thermal sub-circuit which is related not only to power dissipation, but also ambient temperature is used to calculate the variations of channel temperature of the device; the temperature-dependent parasitic and intrinsic elements are also taken into account in this model. The parameters of the thermal sub-circuit are extracted by using the numerical finite element method. The results show that better performance can be achieved by using the proposed large signal model in the range of -55 to 125 °C compared with the conventional model with a linear thermal sub-circuit. Project supported by the National Natural Science Foundation of China (No. 61106115).

  6. Flavor dependence of baryon melting temperature in effective models of QCD

    CERN Document Server

    Torres-Rincon, Juan M; Aichelin, Joerg

    2015-01-01

    We apply the three-flavor (Polyakov-)Nambu-Jona-Lasinio model to generate baryons as quark-diquark bound states using many-body techniques at finite temperature. All the baryonic states belonging to the octet and decuplet flavor representations are generated in the isospin-symmetric case. For each state we extract the melting temperature at which the baryon may decay into a quark-diquark pair. We seek for an evidence of the strangeness dependence of the baryon melting temperature as suggested by the statistical thermal models and supported by lattice-QCD results. A clear and robust signal for this claim is found, pointing to a flavor dependence of the hadronic deconfinement temperature.

  7. Inverse Temperature Dependence of Nuclear Quantum Effects in DNA Base Pairs

    Science.gov (United States)

    2016-01-01

    Despite the inherently quantum mechanical nature of hydrogen bonding, it is unclear how nuclear quantum effects (NQEs) alter the strengths of hydrogen bonds. With this in mind, we use ab initio path integral molecular dynamics to determine the absolute contribution of NQEs to the binding in DNA base pair complexes, arguably the most important hydrogen-bonded systems of all. We find that depending on the temperature, NQEs can either strengthen or weaken the binding within the hydrogen-bonded complexes. As a somewhat counterintuitive consequence, NQEs can have a smaller impact on hydrogen bond strengths at cryogenic temperatures than at room temperature. We rationalize this in terms of a competition of NQEs between low-frequency and high-frequency vibrational modes. Extending this idea, we also propose a simple model to predict the temperature dependence of NQEs on hydrogen bond strengths in general. PMID:27195654

  8. Temperature dependence of Hall electron density of GaN-based heterostructures

    Institute of Scientific and Technical Information of China (English)

    Zhang Jin-Feng; Zhang Jin-Cheng; Hao Yue

    2004-01-01

    The theoretic calculation and analysis of the temperature dependence of Hall electron density of a sample AlGaN/GaN heterostructure has been carried out in the temperature range from 77 to 300K. The densities of the twodimensional electron gas and the bulk electrons are solved by self-consistent calculation of one-dimensional Schrodinger and Poisson equations at different temperatures, which allow for the variation of energy gap and structure strain, and are used for evaluation of the temperature dependence of Hall electron density. The calculated Hall electron density agrees with the measured one quite well with the appropriate bulk mobility data. Analysis revealed that for the temper ature range considered, even in the heterostructures with a small bulk conductance the factors that determine the Hall mobility and electron density could be of different sources, and not just the two-dimensional electron gas as generally supposed.

  9. Biophysical Insights from Temperature-Dependent Single-Molecule Förster Resonance Energy Transfer

    Science.gov (United States)

    Holmstrom, Erik D.; Nesbitt, David J.

    2016-05-01

    Single-molecule fluorescence microscopy techniques can be used in combination with micrometer length-scale temperature control and Förster resonance energy transfer (FRET) in order to gain detailed information about fundamental biophysical phenomena. In particular, this combination of techniques has helped foster the development of remarkable quantitative tools for studying both time- and temperature-dependent structural kinetics of biopolymers. Over the past decade, multiple research efforts have successfully incorporated precise spatial and temporal control of temperature into single-molecule FRET (smFRET)-based experiments, which have uncovered critical thermodynamic information on a wide range of biological systems such as conformational dynamics of nucleic acids. This review provides an overview of various temperature-dependent smFRET approaches from our laboratory and others, highlighting efforts in which such methods have been successfully applied to studies of single-molecule nucleic acid folding.

  10. Temperature dependence of spin pumping and Gilbert damping in thin Co/Pt bilayers.

    Science.gov (United States)

    Verhagen, T G A; Tinkey, H N; Overweg, H C; van Son, M; Huber, M; van Ruitenbeek, J M; Aarts, J

    2016-02-10

    We report on the temperature dependence of the spin-pumping effect and the Gilbert damping in Co/Pt bilayers grown on Silicon oxide by measuring the change of the linewidth in a ferromagnetic resonance (FMR) experiment. By varying the Co thickness d(Co) between 1.5 nm and 50 nm we find that the damping increases inversely proportional to d(Co) at all temperatures between 300 K and 5 K, showing that the spin pumping effect does not depend on temperature. We also find that the linewidth increases with decreasing temperature for all thicknesses down to about 30 K, before leveling off to a constant, or even decreasing again. This behavior is similar to what is found in bulk ferromagnets, leading to the conclusion that in thin films a conductivity-like damping mechanism is present similar to what is known in crystals. PMID:26759959

  11. Temperature dependence of the magnetization of disc shaped NiO nanoparticles

    DEFF Research Database (Denmark)

    Klausen, Stine Nyborg; Lindgard, P.A.; Lefmann, Kim;

    2002-01-01

    We present neutron diffraction data of NiO nanoparticles measuring the total magnetization and the sublattice magnetization at various temperatures. Electron microscopy shows that the particles are disc shaped with average diameter of about 12 nm and a thickness of about 2 nm. The Neel temperature...... as a temperature dependent contribution of a structural peak in contrast to bulk NiO. The two magnetic signals vanish at the same temperature. The data are interpreted on the basis of an extended mean field model on disc shaped NiO particles. This model includes the finite size dependence of the effective field...... (approximate to460 K) is less than for bulk NiO (523 K). The magnetic domain size, as estimated from the width of the neutron diffraction peaks corresponding to the antiferromagnetic reflection is smaller than the particle size estimated from the structural peaks. A ferromagnetic contribution is present...

  12. Observation of a large spin-dependent transport length in organic spin valves at room temperature.

    Science.gov (United States)

    Zhang, Xianmin; Mizukami, Shigemi; Kubota, Takahide; Ma, Qinli; Oogane, Mikihiko; Naganuma, Hiroshi; Ando, Yasuo; Miyazaki, Terunobu

    2013-01-01

    The integration of organic semiconductors and magnetism has been a fascinating topic for fundamental scientific research and future applications in electronics, because organic semiconductors are expected to possess a large spin-dependent transport length based on weak spin-orbit coupling and weak hyperfine interaction. However, to date, this length has typically been limited to several nanometres at room temperature, and a large length has only been observed at low temperatures. Here we report on a novel organic spin valve device using C(60) as the spacer layer. A magnetoresistance ratio of over 5% was observed at room temperature, which is one of the highest magnetoresistance ratios ever reported. Most importantly, a large spin-dependent transport length of approximately 110 nm was experimentally observed for the C(60) layer at room temperature. These results provide insights for further understanding spin transport in organic semiconductors and may strongly advance the development of spin-based organic devices. PMID:23340432

  13. Temperature dependences of the electric polarization and wave number of incommensurate structures in multiferroics

    Science.gov (United States)

    Pikin, S. A.

    2016-05-01

    It is shown that the electric polarization and wave number of incommensurate modulations, proportional to each other, increase according to the Landau law in spin multiferroic cycloids near the Néel temperature. In this case, the constant magnetization component (including the one for a conical spiral) is oriented perpendicular to the spin incommensurability wave vector. A similar temperature behavior should manifest itself for spin helicoids, the axes of which are oriented parallel to the polarization vector but their spin rotation planes are oriented perpendicular to the antiferromagnetic order plane. When the directions of axes of the magnetization helicoid and polarization vector coincide, the latter is quadratic with respect to magnetization and linearly depends on temperature, whereas the incommensurate-modulation wave number barely depends on temperature. Structural distortions of unit cells for multiferroics of different types determine their axial behavior.

  14. Temperature dependent Raman spectroscopic study of mono-, bi-, and tri-layer molybdenum ditelluride

    Science.gov (United States)

    Park, June; Kim, Younghee; Jhon, Young In; Jhon, Young Min

    2015-10-01

    We investigate the thermal properties of mono-, bi- and tri-layer MoTe2 by using temperature-dependent Raman spectroscopy ranging from 90 K to 300 K. The E2g 1 and B2g 1 modes of MoTe2 blueshift as the temperature decreases. The temperature dependence of the peak positions obtained from mono- to tri-layer MoTe2 is analyzed using the Grüneisen model. The first order temperature coefficients of E2g 1 and B2g 1 Raman modes of mono- to tri-layer MoTe2 are extracted. This study provides the fundamental information about the thermal properties of MoTe2 layers, which is crucial for developing thermal and electronic applications of MoTe2 based devices.

  15. Temperature-dependent photoluminescence of water-soluble quantum dots for a bioprobe

    International Nuclear Information System (INIS)

    The photoluminescence of water-soluble CdSe/ZnS core/shell quantum dots is found to be temperature-dependent: as temperature arising from 280 K to 351 K, the photoluminescence declines with emission peak shifting towards the red at a rate of ∼0.11 nm K-1. And the studies show that the photoluminescence of water-soluble CdSe/ZnS quantum dots with core capped by a thinner ZnS shell is more sensitive to temperature than that of ones with core capped by a thicker one. That is, with 50% decrement of the quantum yield the temperature of the former need to arise from 280 K to 295 K, while the latter requires much higher temperature (315.6 K), which means that the integrality of shell coverage is a very important factor on temperature-sensitivity to for the photoluminescence of water-soluble CdSe/ZnS quantum dots. Moreover, it is found that the water-soluble CdSe quantum dots with different core sizes, whose cores are capped by thicker ZnS shells, possess almost the same sensitivity to the temperature. All of the studies about photoluminescence temperature-dependence of water-soluble CdSe/ZnS core/shell quantum dots show an indispensable proof for their applications in life science

  16. Anomalous inverse bremsstrahlung heating of laser-driven plasmas

    Science.gov (United States)

    Kundu, Mrityunjay

    2016-05-01

    Absorption of laser light in plasma via electron-ion collision (inverse bremsstrahlung) is known to decrease with the laser intensity as I 0 -3/2 or with the electron temperature as T e -3/2 where Coulomb logarithm ln Λ = 0.5ln(1 + k 2 min/k 2 max) in the expression of electron-ion collision frequency v ei is assumed to be independent of ponderomotive velocity v 0 = E0/ω which is unjustified. Here k -1 min = v th/max(ω, ω p), and k -1 max = Z/v 2 th are maximum and minimum cut-off distances of the colliding electron from the ion, v th = √T e is its thermal velocity, ω, ω p are laser and plasma frequency. Earlier with a total velocity v = (v 2 0 + v 2 th)1/2 dependent ln Λ(v) it was reported that v ei and corresponding fractional laser absorption (α) initially increases with increasing intensity, reaches a maximum value, and then fall according to the conventional I 0 -3/2 scaling. This anomalous increase in v ei and α may be objected due to an artifact introduced in ln Λ(v) through k-1 min ∝ v. Here we show similar anomalous increase of v ei and α versus I 0 (in the low temperature and under-dense density regime) with quantum and classical kinetic models of v ei without using ln Λ, but a proper choice of the total velocity dependent inverse cut-off length kmax -1 ∝ v 2 (in classical case) or kmax ∝ v (in quantum case). For a given I 0 15 eV, anomalous growth of vei and a disappear. The total velocity dependent k max in kinetic models, as proposed here, may explain anomalous increase of a with I 0 measured in some earlier laser-plasma experiments. This work may be important to understand collisional absorption in the under-dense pre-plasma region due to low intensity pre-pulses and amplified spontaneous emission (ASE) pedestal in the context of laser induced inertial confinement fusion.

  17. Soft-/rapidity- anomalous dimensions correspondence

    CERN Document Server

    Vladimirov, Alexey A

    2016-01-01

    We establish a correspondence between ultraviolet singularities of soft factors for multi-particle production and rapidity singularities of soft factors for multi-parton scattering. This correspondence is a consequence of a conformal mapping between scattering geometries. The correspondence is valid to all orders of perturbation theory and in this way provides a proof of rapidity renormalization procedure for multi-parton scattering soft factors (including the transverse momentum dependent (TMD) soft factor as a special case). As a by-product we obtain an exact relation between the rapidity anomalous dimension and the well-known soft anomalous dimension. The three-loop rapidity anomalous dimensions for TMD and a general multi-parton scattering are derived.

  18. Temperature and field dependence of the anisotropy of MgB2.

    Science.gov (United States)

    Angst, M; Puzniak, R; Wisniewski, A; Jun, J; Kazakov, S M; Karpinski, J; Roos, J; Keller, H

    2002-04-22

    The anisotropy gamma of the superconducting state of high quality single crystals of MgB2 was determined, using torque magnetometry with two different methods. The anisotropy of the upper critical field was found to be temperature dependent, decreasing from gamma approximately 6 at 15 K to 2.8 at 35 K. Reversible torque data near T(c) reveal a field dependent anisotropy, increasing nearly linearly from gamma approximately equal to 2 in zero field to 3.7 in 10 kOe. The unusual temperature dependence is a true bulk property and can be explained by nonlocal effects of anisotropic pairing and/or the k--> dependence of the effective mass tensor.

  19. Preisach modeling of temperature-dependent ferroelectric response of piezoceramics at sub-switching regime

    Science.gov (United States)

    Ochoa, Diego Alejandro; García, Jose Eduardo

    2016-04-01

    The Preisach model is a classical method for describing nonlinear behavior in hysteretic systems. According to this model, a hysteretic system contains a collection of simple bistable units which are characterized by an internal field and a coercive field. This set of bistable units exhibits a statistical distribution that depends on these fields as parameters. Thus, nonlinear response depends on the specific distribution function associated with the material. This model is satisfactorily used in this work to describe the temperature-dependent ferroelectric response in PZT- and KNN-based piezoceramics. A distribution function expanded in Maclaurin series considering only the first terms in the internal field and the coercive field is proposed. Changes in coefficient relations of a single distribution function allow us to explain the complex temperature dependence of hard piezoceramic behavior. A similar analysis based on the same form of the distribution function shows that the KNL-NTS properties soften around its orthorhombic to tetragonal phase transition.

  20. Anomalous pion decay revisited

    CERN Document Server

    Battistel, O A; Nemes, M C; Hiller, B

    1999-01-01

    An implicit four dimensional regularization is applied to calculate the axial-vector-vector anomalous amplitude. The present technique always complies with results of Dimensional Regularization and can be easily applied to processes involving odd numbers of $\\gamma_5$ matrices. This is illustrated explicitely in the example of this letter.

  1. FEM–based thermal modelling of the cutting process using power law-temperature dependent concept

    OpenAIRE

    W. Grzesik; P. Niesłony

    2008-01-01

    Purpose: Purpose of this study is to compare two variants of the FEM simulation model of orthogonal cuttingprocess of AISI 1045 carbon steel with uncoated and multilayer-coated carbide tools i.e. standard and Power Law–Temperature Dependent (PL-TD) options. The primary reason for undertaking this problem was unsatisfactoryaccuracy of the predictions of cutting temperature especially for coated cutting tools.Design/methodology/approach: Methodology used employs the Lagrangian-FEM model with mo...

  2. On the temperature dependence of the lower wavelength cutoff of a series of Schott glass filters

    OpenAIRE

    Hickey, J. R.; Brett, D. A.; Drummond, A. J.

    2011-01-01

    The authors have extended the work of Ångström & Drummond concerning the temperature dependence of the three meteorological standard filters (Schott OG 1, RG 2 and RG 8) and here give values of the temperature coefficient of the center of lower cutoff for seven other Schott sharp cutoff filters. The results demonstrate that there is a definite relationship between the normalized cutoff wavelength and this coefficient, the coefficient increasing semi-logarithmically with wavelength over th...

  3. Unsteady Flow of a Dusty Conducting Fluid Between Parallel Porous Plates With Temperature Dependent Viscosity

    OpenAIRE

    ATTIA, Hazem A.

    2005-01-01

    This paper studies unsteady laminar flow of dusty conducting fluid between parallel porous plates with temperature dependent viscosity. The fluid is acted upon by a constant pressure gradient and an external uniform magnetic field is applied perpendicular to the plates. The parallel plates are assumed to be porous and subjected to a uniform suction from above and injection from below. The viscosity of the fluid is assumed to vary exponentially with temperature. The governing nonlin...

  4. Temperature dependency of the hysteresis behaviour of PZT actuators using Preisach model

    DEFF Research Database (Denmark)

    Mangeot, Charles; Zsurzsan, Tiberiu-Gabriel

    2016-01-01

    The Preisach model is a powerful tool for modelling the hysteresis phenomenon on multilayer piezo actuators under large signal excitation. In this paper, measurements at different temperatures are presented, showing the effect on the density of the Preisach matrix. An energy-based approach...... is presented, aiming at defining a temperature-dependent phenomenological model of hysteresis for a better understanding of the non-linear effects in piezo actuators....

  5. Slow dynamics of salol: a pressure and temperature dependent light scattering study

    OpenAIRE

    Comez, L.; Corezzi, S.; Fioretto, D.; Kriegs, H.; A. Best; Steffen, W.

    2014-01-01

    We study the slow dynamics of salol by varying both temperature and pressure using photon correlation spectroscopy and pressure-volume-temperature measurements, and compare the behavior of the structural relaxation time with equations derived within the Adam-Gibbs entropy theory and the Cohen-Grest free volume theory. We ?nd that pressure dependent data are crucial to assess the validity of these model equations. Our analysis supports the entropy-based equation, and estimates the con?guration...

  6. Supplementary material: Modeling and Compensating Temperature-dependent Non-uniformity Noise in IR Microbolometer Cameras

    OpenAIRE

    Wolf, A.; Pezoa, J. E.; Figueroa, M.

    2016-01-01

    Abstract: Images rendered by uncooled microbolometer-based infrared (IR) cameras are severely degraded by the spatial non-uniformity (NU) noise. The NU noise imposes a fixed-pattern over the true images, and the intensity of the pattern changes with time due to the temperature instability of such cameras. In this paper, we present a novel model and a compensation algorithm for the spatial NU noise and its temperature-dependent variations. The model separates the NU noise into two components: ...

  7. Specific heat of solutions of system apricot oil-n-hexane depending on temperature and pressure

    International Nuclear Information System (INIS)

    Present article is devoted to specific heat of solutions of system apricot oil-n-hexane depending on temperature and pressure. Thus, the results of studies of specific heat of system oil-n-hexane at 293-423 K temperature range and 0.101-49.1 MPa pressure range are considered. On the basis of conducted studies the state equation is defined. By means of state equation it is possible to evaluate the thermodynamic properties of studied solutions.

  8. Molecular players involved in temperature-dependent sex determination and sex differentiation in Teleost fish

    OpenAIRE

    Shen, Zhi-Gang; Wang, Han-Ping

    2014-01-01

    The molecular mechanisms that underlie sex determination and differentiation are conserved and diversified. In fish species, temperature-dependent sex determination and differentiation seem to be ubiquitous and molecular players involved in these mechanisms may be conserved. Although how the ambient temperature transduces signals to the undifferentiated gonads remains to be elucidated, the genes downstream in the sex differentiation pathway are shared between sex-determining mechanisms. In th...

  9. Microbial interactions with the cyanobacterium Microcystis aeruginosa and their dependence on temperature

    DEFF Research Database (Denmark)

    Dziallas, Claudia; Grossart, Hans-Peter

    2012-01-01

    cultures changed in a temperature-dependent manner, its quality greatly varied under the same environmental conditions, but with different associated bacterial communities. Furthermore, temperature affected quantity and quality of cell-bound microcystins, whereby interactions between M. aeruginosa......’ methanogens contributed to the associated microbial community. This implies so far uncharacterized interactions between Microcystis aeruginosa and its associated prokaryotic community, which has unknown ecological consequences in a climatically changing world....

  10. Temperature and humidity dependence of bulk resistivity of bakelite for resistive plate chambers in CMS

    CERN Document Server

    Ahn, S H; Bahk, S Y; Gapienko, V A; Hong, B; Hong, S J; Jung, S Y; Kim, J Y; Kim, Y J; Kim, Y U; Koo, D G; Lee, K S; Lee, S J; Lee, Y L; Lim, I T; Nam, S K; Pac, M Y; Park, S K; Ra, Y S; Rhee, J T; Seo, S W; Sim, K S

    2000-01-01

    This paper presents data obtained in a systematic study on the bulk resistivity of Korean bakelike as a function of temperature in the range 20-30 degrees C and relative humidity in the range 35-65%. Strong dependence of resistivity on both temperature and humidity was observed. Measurements were carried out in the framework of R&D work on resistive plate chambers which will be used in the CMS detector. (4 refs).

  11. Temperature dependence of birefringence in ethanol-filled suspended core fiber.

    Science.gov (United States)

    Vilas, Jose Luis; Sanchez-Martin, Jose Antonio; Bernabeu, Eusebio

    2016-08-10

    The temperature dependence of the birefringence in a suspended core fiber (SCF) has been experimentally analyzed by using a polarimetric setup. The used configuration consists of two linear polarizers and the SCF as birefringent medium. A theoretical study based on Jones matrices has been carried out to analyze the experimental observed behavior. For this, a polarimetric all-fiber configuration was used whose sensitivity depends on the wavelength variation with temperature. Results obtained show that it is strongly affected when the air holes of SCF are partially filled with ethanol. PMID:27534462

  12. Nonlinear Temperature Dependence of Magnetization of Two-Band Superconductors Near Upper Critical Field

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Temperature dependence of the magnetization M(T) of two-band superconductors is studied in the vicinity of upper critical field Hc2 by using a two-band Ginzburg-Landau (GL) theory. It is shown that magnetization M(T) has a nonlinear character due to positive curvature of upper critical field Hc2(T) and temperature dependence of effective Ginzburg-Landau parameter (n)eff(T). The results are shown to be in qualitative agreement with experimental data for the superconducting magnesium diboride, MgB2.

  13. Temperature dependence of the activation energy at low magnetic induction in high-Tc superconductors

    International Nuclear Information System (INIS)

    The activation energy U0 has been measured for melt-textured YBa2Cu3O7 samples at low magnetic induction B parallel c. The data indicate that U0 has a nearly linear temperature dependence in a certain temperature regime (congruent 10--60 K) and is insensitive to magnetic induction. In terms of the collective-pinning ideas and taking into account the modification due to the thermal fluctuation of the flux-line lattice, we propose a possible theoretical explanation. Meanwhile, the critical current Jc, which depends upon the magnetic induction B as Jc∝1/ √B , was obtained

  14. Effects of a temperature dependent viscosity on thermal convection in binary mixtures

    CERN Document Server

    Hilt, Markus; Zimmermann, Walter

    2013-01-01

    We investigate the effect of a temperature dependent viscosity on the onset of thermal convection in a horizontal layer of a binary fluid mixture that is heated from below. For an exponential temperature dependence of the viscosity, we find in binary mixtures as a function of a positive separation ratio and beyond a certain viscosity contrast a discontinuous transition between two stationary convection modes having a different wavelength. In the range of negative values of the separation ratio, a (continuous or discontinuous) transition from an oscillatory to a stationary onset of convection occurs beyond a certain viscosity contrast, and for large values of the viscosity ratio, the oscillatory onset of convection is suppressed.

  15. Temperature dependence of magnetism near defects in SrB sub 6

    CERN Document Server

    Jarlborg, T

    2003-01-01

    The temperature (T) dependence of magnetic moments in SrB sub 6 is studied through spin-polarized band calculations for a supercell of Sr sub 2 sub 7 B sub 1 sub 5 sub 6 containing a B sub 6 vacancy. The magnetic moment decays rather quickly with T despite the fact that only electronic Fermi-Dirac effects are included. This result and the T dependence of moments near an La impurity can hardly explain the reports of a very high Curie temperature in hexaborides, but suggest that the magnetism is caused by some other type of impurity. (letter to the editor)

  16. Magnetic field and temperature dependence of the critical vortex velocity in type-II superconducting films.

    Science.gov (United States)

    Grimaldi, G; Leo, A; Cirillo, C; Attanasio, C; Nigro, A; Pace, S

    2009-06-24

    We study the vortex dynamics in the instability regime induced by high dissipative states well above the critical current in Nb superconducting strips. The magnetic field and temperature behavior of the critical vortex velocity corresponding to the observed dynamic instability is ascribed to intrinsic non-equilibrium phenomena. The Larkin-Ovchinnikov (LO) theory of electronic instability in high velocity vortex motion has been applied to interpret the temperature dependence of the critical vortex velocity. The magnetic field dependence of the vortex critical velocity shows new features in the low-field regime not predicted by LO.

  17. Temperature-dependence of Threshold Current Density-Length Product in Metallization Lines: A Revisit

    Science.gov (United States)

    Saptono Duryat, Rahmat; Kim, Choong-Un

    2016-04-01

    One of the important phenomena in Electromigration (EM) is Blech Effect. The existence of Threshold Current Density-Length Product or EM Threshold has such fundamental and technological consequences in the design, manufacture, and testing of electronics. Temperature-dependence of Blech Product had been thermodynamically established and the real behavior of such interconnect materials have been extensively studied. The present paper reviewed the temperature-dependence of EM threshold in metallization lines of different materials and structure as found in relevant published articles. It is expected that the reader can see a big picture from the compiled data, which might be overlooked when it was examined in pieces.

  18. Experimental investigation of the energy and temperature dependence of beryllium self sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Korshunov, S.N.; Guseva, M.I.; Stolijarova, V.G. [RRC Kurchatov Institute, Moscow (Russian Federation)

    1995-09-01

    The low-Z metal beryllium is considered as plasma facing material (PFM) for the ITER. It is expected that operation temperature range of beryllium PFM will be (670 - 1070) K. While experimental Be-sputtering data bases exist for H{sup +}, D{sup +} and He{sup +}-ions, the self-sputtering yields of Be have only been estimated by computer simulation. In this paper we report the experimental results on the energy and temperature dependence of the beryllium self-sputtering yield (S). The energy dependence of S{sup s} in the energy range (0.5 - 10.0) keV was measured at 670 K. The self-sputtering yield of Be attains its maximal value at the ion energy of 1.5 keV, being equal to 0.32 {+-} at./ion. Comparison of the experimental results and theoretical prediction shows a good agreement for energy dependence of S{sup s}. The temperature dependence of S{sup s} in the temperature range (370-1070)K was obtained for 0.9keV Be{sup +}-ions. The value of S{sup s} is not changed up to 870 K. It sharply increases at the temperatures above 870 attaining the value of 0.75 at./ion at 1070 K.

  19. Temperature dependence of magnetic moments of nanoparticles and their dipole interaction in magnetic fluids

    Energy Technology Data Exchange (ETDEWEB)

    Lebedev, A.V.

    2015-01-15

    Magnetic susceptibility measurements were carried out for magnetite-based fluids over a wide temperature range. The fluids were stabilized with commonly used surfactants (fatty acids) and new surfactants (polypropylene glycol and tallow acids). The coefficients of temperature dependence of the particle magnetic moments were determined by fitting of the measured and calculated values of magnetic susceptibility. The influence of the inter-particle dipole–dipole interaction on the susceptibility was taken into account in the framework of A.O. Ivanov's model. The corrections for thermal expansion were determined by density measurements of the carrier fluid. The obtained values of temperature coefficients correlate to the solidification temperature of the fluid samples. For fluids with a low solidification temperature the value of the temperature coefficient of particle magnetization coincides with its value for bulk magnetite. - Highlights: • Susceptibility measurements made for magnetic fluids over a wide temperature range. • Temperature coefficients of particle magnetization found from susceptibility data. • The value of coefficients correlates to the solidification temperature of the fluid. • For the lowest solidification temperature the coefficient corresponds to that of bulk magnetite.

  20. Comment on 'Temperature dependence of the energy dissipation in dynamic force microscopy'.

    Science.gov (United States)

    Burke, S A; Grütter, P

    2008-10-01

    A recent article in this journal by Roll et al (2008 Nanotechnology 19 045703) presents experimental results of the temperature dependence of dissipation in dynamic force microscopy which they use to elucidate the mechanisms of such a dissipation signal in the PTCDA on KBr system. We argue here that dissipation results are often highly dependent upon the tip structure, and urge caution in the interpretation of single sets of experimental data. PMID:21832607

  1. Comment on 'Temperature dependence of the energy dissipation in dynamic force microscopy'

    Energy Technology Data Exchange (ETDEWEB)

    Burke, S A; Gruetter, P [Physics Department, McGill University, 3600 rue University, Montreal H3A 2T8 (Canada)], E-mail: burkes@physics.mcgill.ca

    2008-10-01

    A recent article in this journal by Roll et al (2008 Nanotechnology 19 045703) presents experimental results of the temperature dependence of dissipation in dynamic force microscopy which they use to elucidate the mechanisms of such a dissipation signal in the PTCDA on KBr system. We argue here that dissipation results are often highly dependent upon the tip structure, and urge caution in the interpretation of single sets of experimental data. (comment)

  2. Temperature dependence of nanosecond laser pulse thresholds of melanosome and microsphere microcavitation

    Science.gov (United States)

    Schmidt, Morgan S.; Kennedy, Paul K.; Noojin, Gary D.; Thomas, Robert J.; Rockwell, Benjamin A.

    2016-01-01

    Melanosome microcavitation is the threshold-level retinal pigment epithelium (RPE) damage mechanism for nanosecond (ns) pulse exposures in the visible and near-infrared (NIR). Thresholds for microcavitation of isolated bovine RPE melanosomes were determined as a function of temperature (20 to 85°C) using single ns laser pulses at 532 and 1064 nm. Melanosomes were irradiated using a 1064-nm Q-switched Nd:YAG (doubled for 532-nm irradiation). For comparison to melanosome data, a similar temperature (20 to 65°C) dependence study was also performed for 532 nm, ns pulse exposures of black polystyrene microbeads. Results indicated a decrease in the microcavitation average radiant exposure threshold with increasing sample temperature for both 532- and 1064-nm single pulse exposures of melanosomes and microbeads. Threshold data and extrapolated nucleation temperatures were used to estimate melanosome absorption coefficients in the visible and NIR, and microbead absorption coefficients in the visible, indicating that melanin is a better absorber of visible light than black polystyrene. The NIR melanosome absorption coefficients ranged from 3713 cm-1 at 800 nm to 222 cm-1 at 1319 nm. These data represent the first temperature-dependent melanosome microcavitation study in the NIR and provide additional information for understanding melanosome microcavitation threshold dependence on wavelength and ambient temperature.

  3. Spontaneous otoacoustic emissions in the European edible frog (Rana esculenta): spectral details and temperature dependence.

    Science.gov (United States)

    van Dijk, P; Wit, H P; Segenhout, J M

    1989-11-01

    Spontaneous otoacoustic emissions were recorded in 41 ears of 29 European edible frogs (Rana esculenta). Emission frequencies ranged from 450 to 1350 Hz. The distribution of frequencies shows two distinct populations: one above and one below 1 kHz. With one exception, a maximum number of two emissions were recorded per ear, each in a different population. An amplitude distribution of a frog emission was sampled, from which it was concluded that the emission is generated by an active oscillator. The spectral width of an emission ranged from 1 to 200 Hz (average 38 Hz). There was negative correlation between sound pressure level of an emission and spectral width. In 4 frogs the dependence of emission power and frequency on temperature was investigated. An emission could be 'switched on and off' within a few degrees centigrade. At temperatures below the switching interval no emission was recorded; for higher temperatures emission power showed no dependence on temperature. Frequency increased with temperature (Q10 = 1.1 to 1.3). This yields a mismatch with temperature dependence of best frequencies of auditory fibers. The consequences of this mismatch are discussed. PMID:2691473

  4. Phase separation time/temperature dependence of thermoplastics-modified thermosetting systems

    Institute of Scientific and Technical Information of China (English)

    Xiujuan ZHANG; Xiaosu YI; Yuanze XU

    2008-01-01

    The cure-induced phase separation processes of various thermoplastics(TP)-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature depend-ency of the phase separation time and its potential application in the cure time-temperature processing win-dow.We found that the phase separation time/temper-ature relationship follows the simple Arrhenius equation.The cure-induced phase separation activation energy Ea(ps) generated from the linear fitting of the Arrhenius equation is irrelevant to the detection means of phase separation time.We also found that Ea(ps) is insensitive to TP content,TP molecular weight and curing rate,but it changes with the cure reaction kinetics and the chemical environment of the systems.With the established phase separation time-temperature dependence relation,we can easily establish the whole cure time-temperature transformation (TTT) diagram with morphology information which is a useful map for the TP/TS compo-sites processing industry.

  5. Dependence of O{sub 2} diffusion dynamics on pressure and temperature in silica nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Iovino, G., E-mail: giuseppe.iovino@unipa.it; Agnello, S., E-mail: simonpietro.agnello@unipa.it; Gelardi, F. M., E-mail: franco.gelardi@unipa.it [University of Palermo, Department of Physics and Chemistry (Italy)

    2013-10-15

    An experimental study of the molecular O{sub 2} diffusion process in high purity non-porous silica nanoparticles having 50 m{sup 2}/g BET specific surface and 20 nm average radius was carried out in the temperature range from 127 to 177 Degree-Sign C at O{sub 2} pressure in the range from 0.2 to 66 bar. The study was performed by measuring the volume average interstitial O{sub 2} concentration by a Raman and photoluminescence technique using a 1,064 nm excitation laser to detect the singlet to triplet emission at 1,272 nm of the molecular oxygen in silica. A dependence of the diffusion kinetics on the O{sub 2} absolute pressure, in addition to temperature dependence, was found. The kinetics can be fit by the solution of Fick's diffusion equation using an effective diffusion coefficient related to temperature and O{sub 2} external pressure. The fit results have evidenced that the temperature and pressure dependencies can be disentangled and that the pressure effects are more pronounced at lower temperatures. An Arrhenius temperature law is determined for the effective diffusion coefficient and the activation energy and pre-exponential factor are found in the explored experimental range. The reported findings have not been evidenced previously in the studies in bulk silica and could probably be originated by the reduced spatial extension of the considered system.

  6. Temperature response of soil respiration is dependent on concentration of readily decomposable C

    Directory of Open Access Journals (Sweden)

    A. A. Larionova

    2007-12-01

    Full Text Available Temperature acclimation of soil organic matter (SOM decomposition is one of the major uncertainties in predicting soil CO2 efflux associated with the increase in global mean temperature. A reasonable explanation for an apparent acclimation proposed by Davidson and colleagues (2006 based on Michaelis-Menten kinetics suggests that temperature sensitivity decreases when both maximal activity of respiratory enzymes (Vmax and half-saturation constant (Ks cancel each other upon temperature increase. We tested the hypothesis of the canceling effect by the mathematical simulation of data obtained in incubation experiments with forest and arable soils. Our data support the hypothesis and suggest that concentration of readily decomposable C substrate (as glucose equivalents and temperature dependent substrate release are the important factors controlling temperature sensitivity of soil respiration. The highest temperature sensitivity of soil respiration was observed when substrate release was temperature dependent and C substrate concentration was much lower than Ks. Increase of substrate content to the half-saturation constant by glucose addition resulted in temperature acclimation associated with the canceling effect. Addition of the substrate to the level providing respiration at a maximal rate Vmax leads to the acclimation of the whole microbial community as such. However, growing microbial biomass was more sensitive to the temperature alterations. This study improves our understanding of the instability of temperature sensitivity of soil respiration under field conditions, attributing this phenomenon to changes in concentration of readily decomposable C substrate.

  7. Temperature dependent surface modification of molybdenum due to low energy He{sup +} ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Tripathi, J.K., E-mail: jtripat@purdue.edu [Center for Materials Under Extreme Environment (CMUXE), School of Nuclear Engineering, Purdue University, West Lafayette, IN 47907 (United States); Novakowski, T.J.; Joseph, G. [Center for Materials Under Extreme Environment (CMUXE), School of Nuclear Engineering, Purdue University, West Lafayette, IN 47907 (United States); Linke, J. [Forschungszentrum Jülich GmbH, EURATOM Association, Jülich D-52425 (Germany); Hassanein, A. [Center for Materials Under Extreme Environment (CMUXE), School of Nuclear Engineering, Purdue University, West Lafayette, IN 47907 (United States)

    2015-09-15

    In this paper, we report on the temperature dependent surface modifications in molybdenum (Mo) samples due to 100 eV He{sup +} ion irradiation in extreme conditions as a potential candidate to plasma-facing components in fusion devices alternative to tungsten. The Mo samples were irradiated at normal incidence, using an ion fluence of 2.6 × 10{sup 24} ions m{sup −2} (with a flux of 7.2 × 10{sup 20} ions m{sup −2} s{sup −1}). Surface modifications have been studied using high-resolution field emission scanning electron-(SEM) and atomic force (AFM) microscopy. At 773 K target temperature homogeneous evolution of molybdenum nanograins on the entire Mo surface were observed. However, at 823 K target temperature appearance of nano-pores and pin-holes nearby the grain boundaries, and Mo fuzz in patches were observed. The fuzz density increases significantly with target temperatures and continued until 973 K. However, at target temperatures beyond 973 K, counterintuitively, a sequential reduction in the fuzz density has been seen till 1073 K temperatures. At 1173 K and above temperatures, only molybdenum nano structures were observed. Our temperature dependent studies confirm a clear temperature widow, 823–1073 K, for Mo fuzz formation. Ex-situ high resolution X-ray photoelectron spectroscopy studies on Mo fuzzy samples show the evidence of MoO{sub 3} 3d doublets. This elucidates that almost all the Mo fuzz were oxidized during open air exposure and are thick enough as well. Likewise the microscopy studies, the optical reflectivity measurements also show a sequential reduction in the reflectivity values (i.e., enhancement in the fuzz density) up to 973 K and after then a sequential enhancement in the reflectivity values (i.e., reduction in the fuzz density) with target temperatures. This is in well agreement with microscopy studies where we observed clear temperature window for Mo fuzz growth.

  8. Temperature dependency of the Ga/In distribution in Cu(In,Ga)Se2 absorbers in high temperature processes

    Science.gov (United States)

    Mueller, B. J.; Demes, T.; Lill, P. C.; Haug, V.; Hergert, F.; Zweigart, S.; Herr, U.

    2016-05-01

    The current article reports about the influence of temperature and glass substrate on Ga/In interdiffusion and chalcopyrite phase formation in the stacked elemental layer process. According to the Shockley-Queisser limit the optimum for single junction devices is near 1.4 eV, which is strongly coupled on the Ga/(Ga+In) ratio of Cu(In,Ga)Se2 thin film solar cells. To increase the Ga content in the active region of the Cu(In,Ga)Se2 a 70:30 CuGa alloy target is used. An increase of the selenization temperature leads to a more homogeneous Ga/In distribution and a less pronounced Ga agglomeration at the back contact. The Ga/In interdiffusion rates for different selenization temperatures and substrates were estimated with the model of a two layer system. At the highest selenization temperature used an absorber band gap of 1.12 eV was realized, which is similar to typical values of absorbers produced during the co-evaporation process. The Na diffusion into the Cu(In,Ga)Se2 is weakly temperature dependent but strongly influenced by the choice of the glass substrate composition.

  9. Temperature dependence of the liquid eutectic lead-lithium alloy density

    Institute of Scientific and Technical Information of China (English)

    Alchagirov; Boris; B.; Mozgovoi; Alexandr; G.; Taova; Tamara; M.

    2005-01-01

    Lead-lithium alloys are of great interest for practice as the advanced materials to be used in new technique, nuclear energetics, and so forth. Terefore, study on the physico-chemical properties of the latter is of major significance. An analysis of the available literature shows that there are a few works, devoted to study of Pb-Li alloys densities. However, temperature dependence of the density ρ(T), and its temperature coefficientK=dρ/dT for eutectic alloy were obtained by either extrapolation of the density data up to the eutectic alloy's composition, or calculation method. There is a certain discrepancy amounting to as high as 4%, while the allowable error in the density measurements is less than 0.5%. The discrepancy between the results for the temperature coefficients of density amounts to 80%.In this work we present the experimental data on the temperature dependence of Ph0.83 Li0.17 eutectic alloy's density in the temperature range 520K to 643 K. The alloys were prepared using Pb and Li with 99. 999% and 99.8% contents of the basic elements, respectively. We use the improved device, which permits to get the results with error less than 0. 15%. The results of 115 measurements of density in 520K to 643K temperature range were processed by the least-square method. Density polytherm of Pb0.83 Li0. 17 eutectic alloy is described by linear equation ρ(T) =9507.89-0. 79813(T-508) , kg/m3 ,where T is the absolute temperature by K. Mearsurement error was 0. 12% at 95% reliability.Discrepancy in the temperature coefficient data was 1.08%.Thus, the temperature dependence of the Pb-Li eutectic alloy density was studied by the precise two-capillary method. The obtained results may be recommended as the most reliable reference data.

  10. Beta Function and Anomalous Dimensions

    DEFF Research Database (Denmark)

    Pica, Claudio; Sannino, Francesco

    2011-01-01

    We demonstrate that it is possible to determine the coefficients of an all-order beta function linear in the anomalous dimensions using as data the two-loop coefficients together with the first one of the anomalous dimensions which are universal. The beta function allows to determine the anomalous...

  11. Temperature and angular momentum dependence of the quadrupole deformation in sd-shell

    Indian Academy of Sciences (India)

    P A Ganai; J A Sheikh; I Maqbool; R P Singh

    2009-11-01

    Temperature and angular momentum dependence of the quadrupole deformation is studied in the middle of the sd-shell for 28Si and 27Si isotopes using the spherical shell model approach. The shell model calculations have been performed using the standard universal sd-shell (USD) interaction and the canonical partition function constructed from the calculated eigensolutions. It is shown that the extracted average quadrupole moments show a transitional behaviour as a function of temperature and the infered transitional temperature is shown to vary with angular momentum. The quadrupole deformation of the individual eigenstate is also analysed.

  12. Temperature dependence of radiation damage and its annealing in silicon detectors

    Energy Technology Data Exchange (ETDEWEB)

    Ziock, H.J.; Boissevain, J.G.; Holzscheiter, K.; Kapustinsky, J.S.; Palounek, A.P.T.; Sondheim, W.E. [Los Alamos National Lab., NM (United States); Barberis, E.; Cartiglia, N.; Leslie, J.; Pitzl, D.; Rowe, W.A.; Sadrozinski, H.F.W.; Seiden, A.; Spencer, E.; Wilder, M. [California Univ., Santa Cruz, CA (United States). Inst. for Particle Physics; Ellison, J.A.; Fleming, J.K.; Jerger, S.; Joyce, D.; Lietzke, C.; Reed, E.; Wimpenny, S.J. [California Univ., Riverside, CA (United States); Ferguson, P. [Missouri Univ., Rolla, MO (United States); Frautschi, M.A.; Matthews, J.A.J.; Skinner, D. [New Mexico Univ., Albuquerque, NM (United States)

    1992-12-01

    The radiation damage resulting from the large particle fluences predicted at the Superconducting Super Collider will induce significant leakage currents in silicon detectors. In order to limit those currents, we plan to operate the detectors at reduced temperatures ({approximately}0{degree} C). In this paper, we present the results of a study of temperature effects on both the initial radiation damage and the long-term annealing of that damage in silicon PIN detectors. Depletion voltage results are reported. The detectors were exposed to approximately 10{sup 14}/cm{sup 2} 650 MeV protons. Very pronounced temperature dependencies were observed.

  13. Temperature dependence of radiation damage and its annealing in silicon detectors

    Energy Technology Data Exchange (ETDEWEB)

    Ziock, H.J.; Boissevain, J.G.; Holzscheiter, K.; Kapustinsky, J.S.; Palounek, A.P.T.; Sondheim, W.E. (Los Alamos National Lab., NM (United States)); Barberis, E.; Cartiglia, N.; Leslie, J.; Pitzl, D.; Rowe, W.A.; Sadrozinski, H.F.W.; Seiden, A.; Spencer, E.; Wilder, M. (Univ. of California, Santa Cruz, CA (United States). Santa Cruz Inst. for Particle Physics); Ellison, J.A.; Fleming, J.K.; Jerger, S.; Joyce, D.; Lietzke, C.; Reed, E.; Wimpenny, S.J. (Univ. of California, Riverside, CA (United States)); Ferguson, P. (Univ. of Missouri, Rolla, MO (United States)); Frautschi, M.A.; Matthews, J.A.J.; Skinner, D. (Univ. of New Mexico, Albuquerque, NM (United States))

    1993-08-01

    The radiation damage resulting from the large particle fluences predicted at the Superconducting Super Collider will induce significant leakage currents in silicon detectors. In order to limit those currents, the authors plan to operate the detectors at reduced temperatures ([approximately] 0 C). In this paper, they present the results of a study of temperature effects on both the initial radiation damage and the long-term annealing of that damage in silicon PIN detectors. Depletion voltage results are reported. The detectors were exposed to approximately 10[sup 14]/cm[sup 2] 650 MeV protons. Very pronounced temperature dependencies were observed.

  14. Temperature dependence of radiation damage and its annealing in silicon detectors

    Energy Technology Data Exchange (ETDEWEB)

    Ziock, H.J.; Boissevain, J.G.; Holzscheiter, K.; Kapustinsky, J.S.; Palounek, A.P.T.; Sondheim, W.E. (Los Alamos National Lab., NM (United States)); Barberis, E.; Cartiglia, N.; Leslie, J.; Pitzl, D.; Rowe, W.A.; Sadrozinski, H.F.W.; Seiden, A.; Spencer, E.; Wilder, M. (California Univ., Santa Cruz, CA (United States). Inst. for Particle Physics); Ellison, J.A.; Fleming, J.K.; Jerger, S.; Joyce, D.; Lietzke, C.; Re

    1992-01-01

    The radiation damage resulting from the large particle fluences predicted at the Superconducting Super Collider will induce significant leakage currents in silicon detectors. In order to limit those currents, we plan to operate the detectors at reduced temperatures ([approximately]0[degree] C). In this paper, we present the results of a study of temperature effects on both the initial radiation damage and the long-term annealing of that damage in silicon PIN detectors. Depletion voltage results are reported. The detectors were exposed to approximately 10[sup 14]/cm[sup 2] 650 MeV protons. Very pronounced temperature dependencies were observed.

  15. Dibaryon systems in the quark mass density- and temperature-dependent model

    OpenAIRE

    Zhang, Yun; Su, Ru-Keng

    2003-01-01

    Using the quark mass density- and temperature-dependent model, we have studied the properties of the dibaryon systems. The binding energy, radius and mean lifetime of Omega-Omega and Omega-Xi are given. We find the dibaryons Omega-Omega, Omega-Xi are metastable at zero temperature, but the strong decay channel for Omega-Omega opens when temperature arrives at 129.3MeV. It is shown that our results are in good agreement with those given by the chiral S(3) quark model.

  16. Temperature Dependence of Polarizability and Dispersion in Three, Two and One Dimensional Electron Gases

    Institute of Scientific and Technical Information of China (English)

    YAN Baorong; KONG Linghua; LV Jianhong; HU Xiwei

    2009-01-01

    Both temperature dependence of polarizability and plasmon dispersion in unmagnetized metal (or semiconductor) electron gases are investigated in this paper.It is obtained that,with a continuous variation of temperature in a large region,the polarizability and dispersion change non-monotonously.The static polarizability x(q,ω=0,μ,T) and dispersion ωp(q,T) for finite T in three,two and one dimensional electron gases are calculated numerically.In addition,dispersion relation ω(q) at a definite temperature (T≠0) is similar to that at T=0.

  17. Temperature-dependent Structural Relaxation in As40Se60 Glass

    Energy Technology Data Exchange (ETDEWEB)

    R Golovchak; A Kozdras; O Shpotyuk; C Gorecki; A Kovalskkiy; H Jain

    2011-12-31

    The origin of structural relaxation in As{sub 40}Se{sub 60} glass at different annealing temperatures is studied by differential scanning calorimetry (DSC) and in situ extended X-ray absorption fine structure (EXAFS) methods. Strong physical aging effect, expressed through the increase of endothermic peak area in the vicinity of Tg, is recorded by DSC technique at the annealing temperatures T{sub a} > 90 C. EXAFS data show that the observed structural relaxation is not associated with significant changes in the short-range order of this glass. An explanation is proposed for this relaxation behavior assuming temperature-dependent constraints.

  18. A temperature dependent infrared absorption study of strong hydrogen bonds in bis(glycinium)oxalate

    Science.gov (United States)

    Bhatt, Himal; Deo, M. N.; Murli, C.; Vishwakarma, S. R.; Chitra, R.; Sharma, Surinder M.

    2016-05-01

    We report infrared absorption studies on Bis(glycinium)oxalate, an organic complex of the simplest amino acid Glycine, under varying temperatures in the range 77 - 350 K. The measurements have been carried out in the spectral range 400 - 4000 cm-1 and the strongest O-H---O hydrogen bond, which plays a vital role in the structural stabilization, has been studied. Subtle changes in widths of modes and temperature dependent frequency variations have been observed near 250 K. The hydrogen bonding network remains stable in the entire temperature range. This is in contrast to its reported high pressure behavior.

  19. Dependence of the surface resistance of niobium coated copper cavities on the coating temperature

    International Nuclear Information System (INIS)

    Six hydro-formed copper 1.5 GHz cavities have been baked and coated with niobium at different temperatures between 100 deg C and 200 deg C, while keeping the other discharge parameters unchanged. Their surface resistance has been measured as a function RF field and trapped magnetic field. Its dependence on deposition temperature confirms earlier indications obtained using 350 MHz LEP cavities that 150 deg C leads to optimal performances. The critical temperatures of Nb/Cu and bulk niobium cavities have also been measured. (author)

  20. The temperature dependence of refractive index of hemoglobin at the wavelengths 930 and 1100 nm

    Science.gov (United States)

    Lazareva, Ekaterina N.; Tuchin, Valery V.

    2016-04-01

    In this study, the refractive index of hemoglobin was measured at different temperatures within a physiological range and above that is characteristic to light-blood interaction at laser therapy. Measurements were carried out using the multi-wavelength Abbe refractometer (Atago, Japan). The refractive index was measured at two NIR wavelengths of 930 nm and 1100 nm. Samples of hemoglobin solutions with concentration of 80, 120 and 160 g/l were investigated. The temperature was varied between 25 and 55 °C. It was shown that the dependence of the refractive index of hemoglobin is nonlinear with temperature, which may be associated with changes in molecular structure of hemoglobin.