WorldWideScience

Sample records for anomalous structural features

  1. Special features of the composition and chemical structure of green pigments - anomalous components of petroleum vanadylporphyrins

    Energy Technology Data Exchange (ETDEWEB)

    Pevneva, G.S.; Zemtseva, L.I.; Antipenko, V.R.; Titov, V.I.

    1985-01-01

    Investigations covering two decades, in the field of minerals, including petroleum porphyrins has widened considerably our understanding of their group composition and special features of their chemical structure. In addition to members of the basic homologous series (alkylporphyrins (series M) and cycloalkano-porphyrins (series M-2)), two groups of green porphyrins were found with spectroscopic properties very different from those of petroleum vanadylporphyrins and other bituminous components of sedimentary rocks. These compounds are, usually, contained in increased proportions in high and low-polarity fractions of petroleum vanadylporphyrin concentrates. Experimental data reported by other workers and from our previous study confirm that the combination of a carbonyl group with a quasi-aromatic porphyin macroring system, is a distinctive feature of the structure of the polar green pigment group. Some new data are presented here which confirm this point of view, however, the work is devoted mainly to the separation and study of another group of green pigments, concentrated in the least polar fraction from chromatographic separation of petroleum vanadylporphyrins. This group of green pigments has been reported previously as compounds of a minor homologous series of rhodoporphyrins of petroleum deposits (petroleum rhodophorphyrins).

  2. QCD Anomalous Structure of Electron

    OpenAIRE

    Slominski, Wojciech

    1998-01-01

    The parton content of the electron is analyzed within perturbative QCD. It is shown that electron acquires an anomalous component from QCD, analogously to photon. The evolution equations for the `exclusive' and `inclusive' electron structure function are constructed and solved numerically in the asymptotic $Q^2$ region.

  3. Anomalous features of EMT during keratinocyte transformation.

    Directory of Open Access Journals (Sweden)

    Tamar Geiger

    Full Text Available During the evolution of epithelial cancers, cells often lose their characteristic features and acquire a mesenchymal phenotype, in a process known as epithelial-mesenchymal transition (EMT. In the present study we followed early stages of keratinocyte transformation by HPV16, and observed diverse cellular changes, associated with EMT. We compared primary keratinocytes with early and late passages of HF1 cells, a cell line of HPV16-transformed keratinocytes. We have previously shown that during the progression from the normal cells to early HF1 cells, immortalization is acquired, while in the progression to late HF1, cells become anchorage independent. We show here that during the transition from the normal state to late HF1 cells, there is a progressive reduction in cytokeratin expression, desmosome formation, adherens junctions and focal adhesions, ultimately leading to poorly adhesive phenotype, which is associated with anchorage-independence. Surprisingly, unlike "conventional EMT", these changes are associated with reduced Rac1-dependent cell migration. We monitored reduced Rac1-dependent migration also in the cervical cancer cell line SiHa. Therefore we can conclude that up to the stage of tumor formation migratory activity is eliminated.

  4. Radar-anomalous, high-altitude features on Venus

    Science.gov (United States)

    Muhleman, Duane O.; Butler, Bryan J.

    1992-01-01

    Over nearly all of the surface of Venus the reflectivity and emissivity at centimeter wavelengths are about 0.15 and 0.85 respectively. These values are consistent with moderately dense soils and rock populations, but the mean reflectivity is about a factor of 2 greater than that for the Moon and other terrestrial planets. Pettingill and Ford, using Pioneer Venus reflectivities and emissivities, found a number of anomalous features on Venus that showed much higher reflectivities and much lower emissivities with both values approaching 0.5. These include Maxwell Montes, a number of high regions in Aphrodite Terra and Beta Regio, and several isolated mountain peaks. Most of the features are at altitudes above the mean radius by 2 to 3 km or more. However, such features have been found in the Magellan data at low altitudes and the anomalies do not exist on all high structures, Maat Mons being the most outstanding example. A number of papers have been written that attempt to explain the phenomena in terms of the geochemistry balance of weathering effects on likely surface minerals. The geochemists have shown that the fundamentally basaltic surface would be stable at the temperatures and pressures of the mean radius in the form of magnetite, but would evolve to pyrite and/or pyrrhotite in the presence of sulfur-bearing compounds such as SO2. Pyrite will be stable at altitudes above 4 or 5 km on Venus. Although the geochemical arguments are rather compelling, it is vitally important to rationally look at other explanations for radar and radio emission measurements such as that presented by Tryka and Muhleman. The radar reflectivity values are retrieved from the raw Magellan backscatter measurements by fitting the Hagfors' radar scattering model in which a surface roughness parameters and a normal incidence electrical reflectivity are estimated. The assumptions of the theory behind the model must be considered carefully before the results can be believed. These include

  5. Macromolecular structure phasing by neutron anomalous diffraction.

    Science.gov (United States)

    Cuypers, Maxime G; Mason, Sax A; Mossou, Estelle; Haertlein, Michael; Forsyth, V Trevor; Mitchell, Edward P

    2016-01-01

    In this report we show for the first time that neutron anomalous dispersion can be used in a practical manner to determine experimental phases of a protein crystal structure, providing a new tool for structural biologists. The approach is demonstrated through the use of a state-of-the-art monochromatic neutron diffractometer at the Institut Laue-Langevin (ILL) in combination with crystals of perdeuterated protein that minimise the level of hydrogen incoherent scattering and enhance the visibility of the anomalous signal. The protein used was rubredoxin in which cadmium replaced the iron at the iron-sulphur site. While this study was carried out using a steady-state neutron beam source, the results will be of major interest for capabilities at existing and emerging spallation neutron sources where time-of-flight instruments provide inherent energy discrimination. In particular this capability may be expected to offer unique opportunities to a rapidly developing structural biology community where there is increasing interest in the identification of protonation states, protein/water interactions and protein-ligand interactions - all of which are of central importance to a wide range of fundamental and applied areas in the biosciences. PMID:27511806

  6. Turbulence: mechanics and structure of anomalous scaling

    Directory of Open Access Journals (Sweden)

    S. N. Gordienko

    2001-01-01

    Full Text Available As the finite correlation time of a force driving turbulence is taken into account, a new, dimensionless parameter occurs in the theory of turbulence. This new parameter is responsible for two different mechanisms of formation of anomalous spectra. The first mechanism is related to the change of a governing parameter, which defines the spectrum of turbulent fluctuation. The second mechanism is associated with spontaneous formation of characteristic scales that differ parametrically from the scale of the external force. The last mechanism can explain the intermittent structure of turbulent flows. The appropriate discrete set of the possible characteristic scales and anomalous spectra has been calculated. The results give a new insight into the concept of universality: there is a set of universal power laws, although occurrence in the spectrum segments described by one or another power law from this set depends on the dimensionless parameter mentioned above. It is noted that for the broad class of geophysical flows, the new dimensionless parameter is connected with the so-called degree of turbulence, which guarantees that the smallness of this parameter, as the degree of turbulence is usually small enough. That explains the important role of the Kolmogorov spectrum in geophysical applications.

  7. Methodological approaches in estimating anomalous geochemical field structure

    International Nuclear Information System (INIS)

    Mathematical statistic methods were applied to analyze the core samples from vertical expendable wells in Chertovo Koryto gold ore field. The following methods were used to analyse gold in samples: assay tests and atomic absorption method (AAS), while emission spectrum semiquantative method was applied to identify traces. The analysis of geochemical association distribution in one central profile demonstrated that bulk metasomatic aureoles are characteristic of concentric zonal structure. The distribution of geochemical associations is correlated to the hydrothermal stages of mineral formation identified in this deposit. It was proved that the processed geochemical data by factor and cluster analyses provided additional information on the anomalous geochemical field structure in gold- bearing black-shale strata. Such methods are effective tools in interpretating specific features of geochemical field structures in analogous potential ore-bearing areas

  8. Fingerprints of Anomalous Primordial Universe on the Abundance of Large Scale Structures

    CERN Document Server

    Baghram, Shant; Firouzjahi, Hassan; Namjoo, Mohammad Hossein

    2014-01-01

    We study the predictions of anomalous inflationary models on the abundance of structures in large scale structure observations. The anomalous features encoded in primordial curvature perturbation power spectrum are (a): localized feature in momentum space, (b): hemispherical asymmetry and (c): statistical anisotropies. We present a model-independent expression relating the number density of structures to the changes in the matter density variance. Models with localized feature can alleviate the tension between observations and numerical simulations of cold dark matter structures on galactic scales as a possible solution to the missing satellite problem. In models with hemispherical asymmetry we show that the abundance of structures becomes asymmetric depending on the direction of observation to sky. In addition, we study the effects of scale-dependent dipole amplitude on the abundance of structures and, using the quasars data, we find the upper bound $n_A M_c)$ the enhancement in variance induced from anomalo...

  9. Application of relativistic scattering theory of x rays to diffraction anomalous fine structure in Cu

    OpenAIRE

    Arola, E.; Strange, Paul

    1998-01-01

    We apply our recent first-principles formalism of magnetic scattering of circularly polarized x rays to a single Cu crystal. We demonstrate the ability of our formalism to interpret the crystalline environment related near-edge fine structure features in the resonant x-ray scattering spectra at the Cu K absorption edge. We find good agreement between the computed and measured diffraction anomalous fine structure features of the x-ray scattering spectra.

  10. Liquid Water Structure from Anomalous Density under Ambient Condition

    Institute of Scientific and Technical Information of China (English)

    SUN Qiang; ZHENG Hai-Fei

    2006-01-01

    @@ From discussion of the structure of liquid water, we deduce that water under ambient condition is mainly composed of ice Ih-like molecular clusters and clathrate-like molecular clusters. The water molecular clusters remain in a state of chemical equilibrium (reversible clustering reactions). This structural model can be demonstrated by quantitative study on anomalous density with increasing temperature at ambient pressure.

  11. Fingerprints of anomalous primordial Universe on the abundance of large scale structures

    Energy Technology Data Exchange (ETDEWEB)

    Baghram, Shant; Abolhasani, Ali Akbar [Department of Physics, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Firouzjahi, Hassan; Namjoo, Mohammad Hossein, E-mail: baghram@sharif.edu, E-mail: abolhasani@ipm.ir, E-mail: firouz@mail.ipm.ir, E-mail: MohammadHossein.Namjoo@utdallas.edu [School of Astronomy, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531, Tehran (Iran, Islamic Republic of)

    2014-12-01

    We study the predictions of anomalous inflationary models on the abundance of structures in large scale structure observations. The anomalous features encoded in primordial curvature perturbation power spectrum are (a): localized feature in momentum space, (b): hemispherical asymmetry and (c): statistical anisotropies. We present a model-independent expression relating the number density of structures to the changes in the matter density variance. Models with localized feature can alleviate the tension between observations and numerical simulations of cold dark matter structures on galactic scales as a possible solution to the missing satellite problem. In models with hemispherical asymmetry we show that the abundance of structures becomes asymmetric depending on the direction of observation to sky. In addition, we study the effects of scale-dependent dipole amplitude on the abundance of structures. Using the quasars data and adopting the power-law scaling k{sup n{sub A}-1} for the amplitude of dipole we find the upper bound n{sub A} < 0.6 for the spectral index of the dipole asymmetry. In all cases there is a critical mass scale M{sub c} in which for M M{sub c}) the enhancement in variance induced from anomalous feature decreases (increases) the abundance of dark matter structures in Universe.

  12. Anomalous structure and dynamics of the Gaussian-core fluid

    OpenAIRE

    Krekelberg, William P.; Kumar, Tanuj; Mittal, Jeetain; Errington, Jeffrey R.; Truskett, Thomas M.

    2009-01-01

    It is known that there are thermodynamic states for which the Gaussian-core (GC) fluid displays anomalous properties such as expansion upon isobaric cooling (density anomaly) and increased single-particle mobility upon isothermal compression (self-diffusivity anomaly). We investigate how temperature and density affect its short-range translational structural order, as characterized by the two-body excess entropy. We find that there is a wide range of conditions for which the short-range trans...

  13. Can I solve my structure by SAD phasing? Anomalous signal in SAD phasing.

    Science.gov (United States)

    Terwilliger, Thomas C; Bunkóczi, Gábor; Hung, Li Wei; Zwart, Peter H; Smith, Janet L; Akey, David L; Adams, Paul D

    2016-03-01

    A key challenge in the SAD phasing method is solving a structure when the anomalous signal-to-noise ratio is low. A simple theoretical framework for describing measurements of anomalous differences and the resulting useful anomalous correlation and anomalous signal in a SAD experiment is presented. Here, the useful anomalous correlation is defined as the correlation of anomalous differences with ideal anomalous differences from the anomalous substructure. The useful anomalous correlation reflects the accuracy of the data and the absence of minor sites. The useful anomalous correlation also reflects the information available for estimating crystallographic phases once the substructure has been determined. In contrast, the anomalous signal (the peak height in a model-phased anomalous difference Fourier at the coordinates of atoms in the anomalous substructure) reflects the information available about each site in the substructure and is related to the ability to find the substructure. A theoretical analysis shows that the expected value of the anomalous signal is the product of the useful anomalous correlation, the square root of the ratio of the number of unique reflections in the data set to the number of sites in the substructure, and a function that decreases with increasing values of the atomic displacement factor for the atoms in the substructure. This means that the ability to find the substructure in a SAD experiment is increased by high data quality and by a high ratio of reflections to sites in the substructure, and is decreased by high atomic displacement factors for the substructure. PMID:26960122

  14. Features and Recursive Structure

    Directory of Open Access Journals (Sweden)

    Kuniya Nasukawa

    2015-01-01

    Full Text Available Based on the cross-linguistic tendency that weak vowels are realized with a central quality such as ə, ɨ, or ɯ, this paper attempts to account for this choice by proposing that the nucleus itself is one of the three monovalent vowel elements |A|, |I| and |U| which function as the building blocks of melodic structure. I claim that individual languages make a parametric choice to determine which of the three elements functions as the head of a nuclear expression. In addition, I show that elements can be freely concatenated to create melodic compounds. The resulting phonetic value of an element compound is determined by the specific elements it contains and by the head-dependency relations between those elements. This concatenation-based recursive mechanism of melodic structure can also be extended to levels above the segment, thus ultimately eliminating the need for syllabic constituents. This approach reinterprets the notion of minimalism in phonology by opposing the string-based flat structure.

  15. On the Anomalous Silicate Absorption Feature of the Prototypical Seyfert 2 Galaxy NGC 1068

    CERN Document Server

    Koehler, Melanie

    2012-01-01

    The first detection of the silicate absorption feature in AGNs was made at 9.7 micrometer for the prototypical Seyfert 2 galaxy NGC 1068 over 30 years ago, indicating the presence of a large column of silicate dust in the line-of-sight to the nucleus. It is now well recognized that type 2 AGNs exhibit prominent silicate absorption bands, while the silicate bands of type 1 AGNs appear in emission. More recently, using the Mid-Infrared Interferometric Instrument on the Very Large Telescope Interferometer, Jaffe et al. (2004) by the first time spatially resolved the parsec-sized dust torus around NGC 1068 and found that the 10 micrometer silicate absorption feature of the innermost hot component exhibits an anomalous profile differing from that of the interstellar medium and that of common olivine-type silicate dust. While they ascribed the anomalous absorption profile to gehlenite (Ca_2Al_2SiO_7, a calcium aluminum silicate species), we propose a physical dust model and argue that, although the presence of gehl...

  16. Anomalous structure and dynamics of the Gaussian-core fluid.

    Science.gov (United States)

    Krekelberg, William P; Kumar, Tanuj; Mittal, Jeetain; Errington, Jeffrey R; Truskett, Thomas M

    2009-03-01

    It is known that there are thermodynamic states for which the Gaussian-core fluid displays anomalous properties such as expansion upon isobaric cooling (density anomaly) and increased single-particle mobility upon isothermal compression (self-diffusivity anomaly). Here, we investigate how temperature and density affect its short-range translational structural order, as characterized by the two-body excess entropy. We find that there is a wide range of conditions for which the short-range translational order of the Gaussian-core fluid decreases upon isothermal compression (structural order anomaly). As we show, the origin of the structural anomaly is qualitatively similar to that of other anomalous fluids (e.g., water or colloids with short-range attractions) and is connected to how compression affects static correlations at different length scales. Interestingly, we find that the self-diffusivity of the Gaussian-core fluid obeys a scaling relationship with the two-body excess entropy that is very similar to the one observed for a variety of simple liquids. One consequence of this relationship is that the state points for which structural, self-diffusivity, and density anomalies of the Gaussian-core fluid occur appear as cascading regions on the temperature-density plane; a phenomenon observed earlier for models of waterlike fluids. There are, however, key differences between the anomalies of Gaussian-core and waterlike fluids, and we discuss how those can be qualitatively understood by considering the respective interparticle potentials of these models. Finally, we note that the self-diffusivity of the Gaussian-core fluid obeys different scaling laws depending on whether the two-body or total excess entropy is considered. This finding, which deserves more comprehensive future study, appears to underscore the significance of higher-body correlations for the behavior of fluids with bounded interactions. PMID:19391927

  17. Anomalous approach to thermodynamic equilibrium: Structure formation of molecules after vapor deposition.

    Science.gov (United States)

    Jana, Pritam Kumar; Wang, Can; Jack, Robert L; Chi, Lifeng; Heuer, Andreas

    2015-11-01

    We describe experiments and computer simulations of molecular deposition on a substrate in which the molecules (substituted adenine derivatives) self-assemble into ordered structures. The resulting structures depend strongly on the deposition rate (flux). In particular, there are two competing surface morphologies (α and β), which differ by their topology (interdigitated vs lamellar structure). Experimentally, the α phase dominates at both low and high flux, with the β phase being most important in the intermediate regime. A similar nonmonotonic behavior is observed on varying the substrate temperature. To understand these effects from a theoretical perspective, a lattice model is devised which reproduces qualitatively the topological features of both phases. Via extensive Monte Carlo studies we can, on the one hand, reproduce the experimental results and, on the other hand, obtain a microscopic understanding of the mechanisms behind this anomalous behavior. The results are discussed in terms of an interplay between kinetic trapping and temporal exploration of configuration space. PMID:26651707

  18. Structural features of lignohumic acids

    Science.gov (United States)

    Novák, František; Šestauberová, Martina; Hrabal, Richard

    2015-08-01

    The composition and structure of humic acids isolated from lignohumate, which is produced by hydrolytic-oxidative conversion of technical lignosulfonates, were characterized by chemical and spectral methods (UV/VIS, FTIR, and 13C NMR spectroscopy). As comparative samples, humic acids (HA) were isolated also from lignite and organic horizon of mountain spruce forest soil. When compared with other HA studied, the lignohumate humic acids (LHHA) contained relatively few carboxyl groups, whose role is partly fulfilled by sulfonic acid groups. Distinctive 13C NMR signal of methoxyl group carbons, typical for lignin and related humic substances, was found at the shift of 55.9 ppm. Other alkoxy carbons were present in limited quantity, like the aliphatic carbons. Due to the low content of these carbon types, the LHHA has high aromaticity of 60.6%. Comparison with the natural HA has shown that lignohumate obtained by thermal processing of technical lignosulfonate can be regarded as an industrially produced analog of natural humic substances. Based on the chemical and spectral data evaluation, structural features of lignohumate humic acids were clarified and their hypothetical chemical structure proposed, which described typical "average" properties of the isolated fraction.

  19. On the resumed gluon anomalous dimension and structure functions at small x

    International Nuclear Information System (INIS)

    The impact of the recently evaluated open-quotes irreducibleclose quotes contributions to the resummed next-to-leading logarithmic small-x anomalous dimension γgg is evaluated for the unpolarized parton densities and structure functions of the nucleon. These new terms diminish the gluon distribution and are found to overcompensate the enhancement caused by the resummed leading logarithmic small-x anomalous dimension and the quarkonic contributions beyond next-to-leading order. copyright 1997 The American Physical Society

  20. Polarization dependent diffraction anomalous fine structure of rutile TiO2 001 and 111 reflections

    International Nuclear Information System (INIS)

    Energy and polarization dependent Diffraction Anomalous Fine Structure (DAFS) also known as Anisotropic Anomalous Scattering (AAS) can be employed in addition to X-ray Absorption Fine Structure (XAFS) to study electronic transitions from core states to unoccupied states. Here, we present results from resonant X-ray diffraction experiments on TiO2 rutile, space group (136) P42/mnm. For this model structure, site symmetry information was extracted from determination of the structure factor tensor by refining elements of Ti atomic scattering factor tensors. Influences of oxygen vacancies on the anomalous scattering contributions have been studied on a series of rutile wafers of different oxygen concentration. Samples investigated were 10 x 10 x 1 mm3 single crystal wafers and experiments were carried out at DESY/HASYLAB beamlines C and E2 using a Si(111) double crystal monochromator in the vicinity of the Ti-K absorption edge. Considered reflections include the 'forbidden' 001 and allowed 111 reflection.

  1. Structural features of lignohumic acids

    Czech Academy of Sciences Publication Activity Database

    Novák, František; Šestauberová, Martina; Hrabal, R.

    2015-01-01

    Roč. 1093, August (2015), s. 179-185. ISSN 0022-2860 Institutional support: RVO:60077344 Keywords : C-13 NMR * FTIR * humic acids * lignohumate * lignosulfonate * structure Subject RIV: DF - Soil Science Impact factor: 1.602, year: 2014

  2. Anomalous Inner-Gap Structure in Transport Characteristics of Superconducting Junctions with Degraded Interfaces.

    Science.gov (United States)

    Zhitlukhina, E; Devyatov, I; Egorov, O; Belogolovskii, M; Seidel, P

    2016-12-01

    Quantitative description of charge transport across tunneling and break-junction devices with novel superconductors encounters some problems not present or not as severe for traditional superconducting materials. In this work, we explain unexpected features in related transport characteristics as an effect of a degraded nanoscaled sheath at the superconductor surface. A model capturing the main aspects of the ballistic charge transport across hybrid superconducting structures with normally conducting nanometer-thick interlayers is proposed. The calculations are based on a scattering formalism taking into account Andreev electron-into-hole (and inverse) reflections at normal metal-superconductor interfaces as well as transmission and backscattering events in insulating barriers between the electrodes. Current-voltage characteristics of such devices exhibit a rich diversity of anomalous (from the viewpoint of the standard theory) features, in particular shift of differential-conductance maxima at gap voltages to lower positions and appearance of well-defined dips instead expected coherence peaks. We compare our results with related experimental data. PMID:26842791

  3. Development of dispersive anomalous diffraction, application to the study of inorganic modulated structures and biological macromolecules

    International Nuclear Information System (INIS)

    X-ray diffraction has been developed since the beginning of the century for the determination of crystallographic structures. Most complex structures (proteins, incommensurate crystals...) require the use of anomalous diffraction, i.e. the measurement of diffracted intensities at several wavelengths around the absorption edge of one element of the crystal. This technique allows the determination of the phase of the structure factor, as well as the positions of the anomalous atoms. In this thesis, we present the Dispersive Anomalous Diffraction (DAD) method, which allows the simultaneous measure of diffracted intensities at a number of wavelengths for many reflections. Two collection modes can be used, either continuous (DDAFS-Dispersive Diffraction Anomalous Fine Structure) or discrete (SMAD-Simultaneous Multiwavelength Anomalous Diffraction. A specific procedure and a program (DAD) have been developed for the quantitative analysis of dispersive diffraction images. This program also allows the analysis of monochromatic diffraction images, with satellite reflections near main diffraction peaks. We present the first two quantitative experiments in dispersive diffraction for biological compounds. Our results show that the use of SMAD for structure determination is possible, although several improvements are still necessary for both data collection and analysis. An important point in this thesis is the study of quasi-1D compound (TaSe4)2I: this crystal exhibits a Peierls transition, for which no condensation of the metallic atoms was shown for the last 15 years. Our study has characterized the domain structure of this material, and anomalous diffraction has shown in a specific way the tetramerisation of tantalum atoms, which exists along the already-known acoustic modulation. (author)

  4. Robust structural analysis of native biological macromolecules from multi-crystal anomalous diffraction data

    International Nuclear Information System (INIS)

    Anomalous diffraction signals from typical native macromolecules are very weak, frustrating their use in structure determination. Here, native SAD procedures are described for enhancing the signal to noise in anomalous diffraction by using multiple crystals are described. Five applications demonstrate that truly routine structure determination is possible without the need for heavy atoms. Structure determinations for biological macromolecules that have no known structural antecedents typically involve the incorporation of heavier atoms than those found natively in biological molecules. Currently, selenomethionyl proteins analyzed using single- or multi-wavelength anomalous diffraction (SAD or MAD) data predominate for such de novo analyses. Naturally occurring metal ions such as zinc or iron often suffice in MAD or SAD experiments, and sulfur SAD has been an option since it was first demonstrated using crambin 30 years ago; however, SAD analyses of structures containing only light atoms (Zmax ≤ 20) have not been common. Here, robust procedures for enhancing the signal to noise in measurements of anomalous diffraction by combining data collected from several crystals at a lower than usual X-ray energy are described. This multi-crystal native SAD method was applied in five structure determinations, using between five and 13 crystals to determine substructures of between four and 52 anomalous scatterers (Z ≤ 20) and then the full structures ranging from 127 to 1200 ordered residues per asymmetric unit at resolutions from 2.3 to 2.8 Å. Tests were devised to assure that all of the crystals used were statistically equivalent. Elemental identities for Ca, Cl, S, P and Mg were proven by f′′ scattering-factor refinements. The procedures are robust, indicating that truly routine structure determination of typical native macromolecules is realised. Synchrotron beamlines that are optimized for low-energy X-ray diffraction measurements will facilitate such direct

  5. Abstract Machine for Typed Feature Structures

    OpenAIRE

    Wintner, Shuly; Francez, Nissim

    1995-01-01

    This paper describes an abstract machine for linguistic formalisms that are based on typed feature structures, such as HPSG. The core design of the abstract machine is given in detail, including the compilation process from a high-level language to the abstract machine language and the implementation of the abstract instructions. The machine's engine supports the unification of typed, possibly cyclic, feature structures. A separate module deals with control structures and instructions to acco...

  6. Diffraction Anomalous Fine Structure study and atomistic simulation of Ge/Si nanoislands

    Energy Technology Data Exchange (ETDEWEB)

    Katcho, N.A. [Instituto de Quimica Fisica Rocasolano, IQFR-CSIC, c. Serrano 119, 28006 Madrid (Spain); ICMA, Dep. Fisica de la Materia Condensada, CSIC-Universidad de Zaragoza (Spain); Richard, M.-I. [Aix-Marseille Universite, IM2NP-CNRS, Faculte des Sciences et Techniques, F-13397 Marseille Cedex (France); Proietti, M.G., E-mail: proietti@unizar.es [ICMA, Dep. Fisica de la Materia Condensada, CSIC-Universidad de Zaragoza (Spain); Renevier, H., E-mail: hubert.renevier@grenoble-inp.fr [LMGP, Grenoble INP - Minatec, Grenoble (France); Leclere, C. [LMGP, Grenoble INP - Minatec, Grenoble (France); Favre-Nicolin, V. [CEA-UJF, INAC, SP2M, Grenoble (France); Zhang, J.J.; Bauer, G. [Institut fuer Halbleiter - und Festkoerperphysik, Johannes Kepler Universitaet Linz (Austria)

    2012-08-01

    We applied Grazing Incidence Diffraction Anomalous Fine Structure to the study of the structure of Ge dome-shaped nanoislands, grown by Molecular Beam Epitaxy on Si (0 0 1) substrates at a temperature of 650 Degree-Sign C. We determined the vertical composition of the islands showing the presence of a strong Ge/Si intermixing that is nearly constant from bottom to top. In particular, an abrupt change is found at the substrate interface where the composition switches from pure Si to Ge{sub 0.6}Si{sub 0.4}. The analysis of the Diffraction Anomalous Fine Structure oscillations of the spectra is crucial to obtain the true composition profile. We performed atomistic simulations to investigate the role of the strained substrate underneath the dome on the diffraction results and to quantify the resolution of our method. Anomalous Diffraction spectra and Diffraction Anomalous Fine Structure oscillations have been simulated for a real size and real shape cluster including faceting, giving a more detailed data interpretation and understanding of the Ge-Si intermixing mechanism.

  7. Diffraction Anomalous Fine Structure spectroscopy at the beamline BM2 at the European Synchrotron Radiation Facility

    OpenAIRE

    Renevier, H.; Grenier, S.; ARNAUD, S; Berar, J.F.; Caillot, B.; Hodeau, J. L.; Letoublon, A.; Proietti, M. G.; Ravel, B.

    2003-01-01

    Diffraction Anomalous Fine Structure (DAFS) spectroscopy uses resonant elastic x-rays scattering as an atomic, shell and site selective probe that gives information on the electronic structure and the local atomic environment as well as on the long range ordered crystallographic structure. A DAFS experiment consists of measuring the Bragg peak intensities as a function of the energy of the incoming x-ray beam. The French CRG (Collaborative Research Group) beamline BM2-D2AM (Diffraction Diffus...

  8. Anomalous elastic buckling of layered crystalline materials in the absence of structure slenderness

    Science.gov (United States)

    Ren, Manrui; Liu, Yilun; Zhe Liu, Jefferson; Wang, Lifeng; Zheng, Quanshui

    2016-03-01

    Layered crystalline materials, such as graphene, boron nitride, tungsten sulfate, phosphorene, etc., have attracted enormous attentions, due to their unique crystal structures and superior mechanical, thermal, and physical properties. Making use of mechanical buckling is a promising route to control their structural morphology and thus tune their physical properties, giving rise to many novel applications. In this paper, we employ molecular dynamics (MD) simulations and theoretical modeling to study the compressive buckling of a column made of layered crystalline materials with the crystal layers parallel to the compressive direction. We find that the mechanical buckling of the layered crystalline materials exhibits two anomalous and counter-intuitive features as approaching the zero slenderness ratio. First, the critical buckling strain εcr has a finite value that is much lower than the material's elastic limit strain. A continuum mechanics model (by homogenizing the layered materials) is proposed for the εcr, which agrees well with the results of MD simulations. We find that the εcr solely depends on elastic constants without any structural dimension, which appears to be an intrinsic material property and thus is defined as intrinsic buckling strain (IBS), εcrIBS , in this paper. Second, below a certain nanoscale length, l0, in the compressive direction (e.g., about 20 nm for graphite), the critical buckling strain εcr shows a size effect, i.e., increasing as the column length L decreases. To account for the size effect, inspired by our recently developed multi-beam shear model (Liu et al., 2011), a bending energy term of individual crystal layer is introduced in our continuum model. The theoretical model of εcr agrees well with the size effects observed in MD simulations. This study could lay a ground for engineering layered crystalline materials in various nano-materials and nano-devices via mechanical buckling.

  9. On the Anomalous Silicate Absorption Feature of the Prototypical Seyfert 2 Galaxy NGC 1068

    OpenAIRE

    Koehler, Melanie; Li, Aigen

    2012-01-01

    The first detection of the silicate absorption feature in AGNs was made at 9.7 micrometer for the prototypical Seyfert 2 galaxy NGC 1068 over 30 years ago, indicating the presence of a large column of silicate dust in the line-of-sight to the nucleus. It is now well recognized that type 2 AGNs exhibit prominent silicate absorption bands, while the silicate bands of type 1 AGNs appear in emission. More recently, using the Mid-Infrared Interferometric Instrument on the Very Large Telescope Inte...

  10. Feature extraction for structural dynamics model validation

    Energy Technology Data Exchange (ETDEWEB)

    Hemez, Francois [Los Alamos National Laboratory; Farrar, Charles [Los Alamos National Laboratory; Park, Gyuhae [Los Alamos National Laboratory; Nishio, Mayuko [UNIV OF TOKYO; Worden, Keith [UNIV OF SHEFFIELD; Takeda, Nobuo [UNIV OF TOKYO

    2010-11-08

    This study focuses on defining and comparing response features that can be used for structural dynamics model validation studies. Features extracted from dynamic responses obtained analytically or experimentally, such as basic signal statistics, frequency spectra, and estimated time-series models, can be used to compare characteristics of structural system dynamics. By comparing those response features extracted from experimental data and numerical outputs, validation and uncertainty quantification of numerical model containing uncertain parameters can be realized. In this study, the applicability of some response features to model validation is first discussed using measured data from a simple test-bed structure and the associated numerical simulations of these experiments. issues that must be considered were sensitivity, dimensionality, type of response, and presence or absence of measurement noise in the response. Furthermore, we illustrate a comparison method of multivariate feature vectors for statistical model validation. Results show that the outlier detection technique using the Mahalanobis distance metric can be used as an effective and quantifiable technique for selecting appropriate model parameters. However, in this process, one must not only consider the sensitivity of the features being used, but also correlation of the parameters being compared.

  11. Structural study of Zr-Cu-Ag bulk metallic glasses using the anomalous X-ray scattering method

    International Nuclear Information System (INIS)

    The structures of Zr45Cu45Ag10 and Zr40Cu40Ag20 bulk metallic glasses (BMGs) were investigated using the anomalous x-ray scattering and reverse Monte Carlo simulation (AXS-RMC) method. The fundamental structural features of Zr45Cu45Ag10 and Zr40Cu40Ag20 can be properly demonstrated through the common dense random packing of the hard spheres, and the addition of Ag appeared to result in no prominent formation of the particular chemical ordering units. A Voronoi analysis indicated that the fraction of the icosahedron-like coordination was the largest around the Cu in Zr45Cu45Ag10 BMG, where the best glass-forming ability was realized. The improvement in the glass-forming ability in a Zr-Cu-Ag system appears to be associated with the icosahedron-like local coordination.

  12. Anomalous electronic structure and magnetoresistance in TaAs2.

    Science.gov (United States)

    Luo, Yongkang; McDonald, R D; Rosa, P F S; Scott, B; Wakeham, N; Ghimire, N J; Bauer, E D; Thompson, J D; Ronning, F

    2016-01-01

    The change in resistance of a material in a magnetic field reflects its electronic state. In metals with weakly- or non-interacting electrons, the resistance typically increases upon the application of a magnetic field. In contrast, negative magnetoresistance may appear under some circumstances, e.g., in metals with anisotropic Fermi surfaces or with spin-disorder scattering and semimetals with Dirac or Weyl electronic structures. Here we show that the non-magnetic semimetal TaAs2 possesses a very large negative magnetoresistance, with an unknown scattering mechanism. Density functional calculations find that TaAs2 is a new topological semimetal [ℤ2 invariant (0;111)] without Dirac dispersion, demonstrating that a negative magnetoresistance in non-magnetic semimetals cannot be attributed uniquely to the Adler-Bell-Jackiw chiral anomaly of bulk Dirac/Weyl fermions. PMID:27271852

  13. Crystal structure of thermostable catechol 2,3-dioxygenase determined by multiwavelength anomalous dispersion method

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The selenomethionyl derivative of the thermostable catechol 2,3-dioxygenase (SeMet-TC23O) is expressed,purified and crystallized. By using multiwave length anomalous dispersion (MAD) phasing techniques, the crystal structure of TC23O at 0.3 nm resolutions is determined.TC23O is a homotetramer. Each monomer is composed of N-terminal and C-terminal domains (residues 1~153 and 153~319, respectively). The two domains are proximately symmetric by a non-crystallographic axis. Each domain contains two characteristic motifs which are found in almost all of extradial dioxygenases.Kevwords: multiwavelength anomalous dispersion (MAD), X-ray diffraction, thermostable catechol 2,3-dioxygenase, crystal structure,synchrotron light source.

  14. Optimisation of anomalous scattering and structural studies of proteins using synchrotron radiation

    International Nuclear Information System (INIS)

    Measurements from crystalline protein samples using SR can be conveniently divided into two classes. Firstly, small samples, large unit cells, the rapid collection of accurate high resolution data and dynamical studies can all benefit from the high intensity. Secondly, an important extension of the classical methods of protein structure determination arises from use of the tunability of SR for optimization of anomalous scattering and subsequent phase determination. This paper concentrates on this area of application. (author)

  15. Superconducting properties of a stoichiometric FeSe compound and two anomalous features in the normal state

    Energy Technology Data Exchange (ETDEWEB)

    Song, Yoo Jang; Hong, Jong Beom; Min, Byeong Hun; Kwon, Yong Seung [Sungkyunkwan University, Suwon (Korea, Republic of); Lee, Kyu Jun; Jung, Myung Hwa [Sogang University, Seoul (Korea, Republic of); Rhyee, Jong Soo [Kyunghee University, Seoul (Korea, Republic of)

    2011-08-15

    This paper reports the superconducting behavior of the tetragonal iron-chalcogenide superconductor FeSe. The electrical resistivity and the magnetic moment measurements confirmed its superconductivity with T{sup zero}{sub c} and T{sup mag}{sub c} of 9.4 K under ambient pressure. Electron probe macro analysis indicated that the sample had a stoichiometric Fe:Se ratio of 1:1. The Seebeck coefficient, which was 12.3 {mu}V/K at room temperature, changed to a negative value near 200 K, indicating it to be a two-carrier material. Above T{sub c}, the {rho}(T) curve revealed an 'S' shape, and d{rho}(T)/dT and d{sup 2}{rho}(T)/dT{sup 2} showed two anomalous features, one near T{sub an} = 30 K and the other near T{sup *} = 110 K. The Seebeck coefficient, S(T), also displays peculiar behavior near the T{sub an} and T{sup *}. We also report a rather smaller critical current density, J{sub c} = 10{sup 2} {approx} 10{sup 4} A/cm{sup 2}, compared to those observed for the other pnictides and doped chalcogenides.

  16. Superconducting properties of a stoichiometric FeSe compound and two anomalous features in the normal state

    International Nuclear Information System (INIS)

    This paper reports the superconducting behavior of the tetragonal iron-chalcogenide superconductor FeSe. The electrical resistivity and the magnetic moment measurements confirmed its superconductivity with Tzeroc and Tmagc of 9.4 K under ambient pressure. Electron probe macro analysis indicated that the sample had a stoichiometric Fe:Se ratio of 1:1. The Seebeck coefficient, which was 12.3 μV/K at room temperature, changed to a negative value near 200 K, indicating it to be a two-carrier material. Above Tc, the ρ(T) curve revealed an 'S' shape, and dρ(T)/dT and d2ρ(T)/dT2 showed two anomalous features, one near Tan = 30 K and the other near T* = 110 K. The Seebeck coefficient, S(T), also displays peculiar behavior near the Tan and T*. We also report a rather smaller critical current density, Jc = 102 ∼ 104 A/cm2, compared to those observed for the other pnictides and doped chalcogenides.

  17. Anomalous dimensions of four-quark operators and renormalon structure of mesonic two-point correlators

    CERN Document Server

    Boito, Diogo; Jamin, Matthias

    2015-01-01

    In this work, we calculate leading-order anomalous dimension matrices for dimension-6 four-quark operators which appear in the operator product expansion of flavour non-diagonal and diagonal vector and axial-vector two-point correlation functions. The infrared renormalon structure corresponding to four-quark operators is reviewed and it is investigated how the eigenvalues of the anomalous dimension matrices influence the singular behaviour of the $u=3$ infrared renormalon pole. It is found that compared to the large-$\\beta_0$ approximation where at most quadratic poles are present, in full QCD at $N_f=3$ the most singular pole is more than cubic with an exponent $\\kappa\\approx 3.2$.

  18. Momentum and Energy Dependence of the Anomalous High-Energy Dispersion in the Electronic Structure of High Temperature Superconductors

    Science.gov (United States)

    Inosov, D. S.; Fink, J.; Kordyuk, A. A.; Borisenko, S. V.; Zabolotnyy, V. B.; Schuster, R.; Knupfer, M.; Büchner, B.; Follath, R.; Dürr, H. A.; Eberhardt, W.; Hinkov, V.; Keimer, B.; Berger, H.

    2007-12-01

    Using high-resolution angle-resolved photoemission spectroscopy we have studied the momentum and photon energy dependence of the anomalous high-energy dispersion, termed waterfalls, between the Fermi level and 1 eV binding energy in several high-Tc superconductors. We observe strong changes of the dispersion between different Brillouin zones and a strong dependence on the photon energy around 75 eV, which we associate with the resonant photoemission at the Cu3p→3dx2-y2 edge. We conclude that the high-energy “waterfall” dispersion results from a strong suppression of the photoemission intensity at the center of the Brillouin zone due to matrix element effects and is, therefore, not an intrinsic feature of the spectral function. This indicates that the new high-energy scale in the electronic structure of cuprates derived from the waterfall-like dispersion may be incorrect.

  19. Feature Extraction for Structural Dynamics Model Validation

    Energy Technology Data Exchange (ETDEWEB)

    Farrar, Charles [Los Alamos National Laboratory; Nishio, Mayuko [Yokohama University; Hemez, Francois [Los Alamos National Laboratory; Stull, Chris [Los Alamos National Laboratory; Park, Gyuhae [Chonnam Univesity; Cornwell, Phil [Rose-Hulman Institute of Technology; Figueiredo, Eloi [Universidade Lusófona; Luscher, D. J. [Los Alamos National Laboratory; Worden, Keith [University of Sheffield

    2016-01-13

    As structural dynamics becomes increasingly non-modal, stochastic and nonlinear, finite element model-updating technology must adopt the broader notions of model validation and uncertainty quantification. For example, particular re-sampling procedures must be implemented to propagate uncertainty through a forward calculation, and non-modal features must be defined to analyze nonlinear data sets. The latter topic is the focus of this report, but first, some more general comments regarding the concept of model validation will be discussed.

  20. Answer Ranking with Discourse Structure Feature

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    For the complex questions of Chinese question answering system, we propose an answer extraction method with discourse structure feature combination. This method uses the relevance of questions and answers to learn to rank the answers. Firstly, the method analyses questions to generate the query string, and then submits the query string to search engines to retrieve relevant documents. Sec- ondly, the method makes retrieved documents seg- mentation and identifies the most relevant candidate answers, in addition, it uses the rhetorical relations of rhetorical structure theory to analyze the relationship to determine the inherent relationship between para- graphs or sentences and generate the answer candi- date paragraphs or sentences. Thirdly, we construct the answer ranking model,, and extract five feature groups and adopt Ranking Support Vector Machine (SVM) algorithm to train ranking model. Finally, it re-ranks the answers with the training model and fred the optimal answers. Experiments show that the proposed method combined with discourse structure features can effectively improve the answer extrac- ting accuracy and the quality of non-factoid an- swers. The Mean Reciprocal Rank (MRR) of the an- swer extraction reaches 69.53%.

  1. Relation between the structure and catalytic activity for automotive emissions. Use of x-ray anomalous dispersion effect

    CERN Document Server

    Mizuki, J; Tanaka, H

    2003-01-01

    The employment of the X-ray anomalous dispersion effect allows us to detect the change in structure of catalytic converters with the environment exposed. Here we show that palladium atoms in a perovskite crystal move into and out of the crystal by anomalous X-ray diffraction and absorption techniques. This movement of the precious metal plays an important role to keep the catalytic activity long-lived. (author)

  2. Structural features of algebraic quantum notations

    Science.gov (United States)

    Gire, Elizabeth; Price, Edward

    2015-12-01

    [This paper is part of the Focused Collection on Upper Division Physics Courses.] The formalism of quantum mechanics includes a rich collection of representations for describing quantum systems, including functions, graphs, matrices, histograms of probabilities, and Dirac notation. The varied features of these representations affect how computations are performed. For example, identifying probabilities of measurement outcomes for a state described in Dirac notation may involve identifying expansion coefficients by inspection, but if the state is described as a function, identifying those expansion coefficients often involves performing integrals. In this study, we focus on three notational systems: Dirac notation, algebraic wave-function notation, and matrix notation. These quantum notations must include information about basis states and their associated complex probability amplitudes. In this theory paper, we identify four structural features of quantum notations, which we term individuation, degree of externalization, compactness, and symbolic support for computational rules. We illustrate how student reasoning interacts with these structural features with episodes from interviews with advanced undergraduate physics majors reasoning about a superposition state of an infinite square well system. We find evidence of the students coordinating different notations through the use of Dirac notation, using an expression in Dirac notation to guide their work in another notation. These uses are supported by the high degree of individuation, compactness, and symbolic support for computation and the moderate degree of externalization provided by Dirac notation.

  3. Anomalous scaling of structure functions and dynamic constraints on turbulence simulations

    International Nuclear Information System (INIS)

    The connection between anomalous scaling of structure functions (intermittency) and numerical methods for turbulence simulations is discussed. It is argued that the computational work for direct numerical simulations (DNS) of fully developed turbulence increases as Re4, and not as Re3 expected from Kolmogorov's theory, where Re is a large-scale Reynolds number. Various relations for the moments of acceleration and velocity derivatives are derived. An infinite set of exact constraints on dynamically consistent subgrid models for Large Eddy Simulations (LES) is derived from the Navier-Stokes equations, and some problems of principle associated with existing LES models are highlighted. (author)

  4. Anomalous structural behavior in the metamagnetic transition of FeRh thin films from a local viewpoint

    Science.gov (United States)

    Wakisaka, Yuki; Uemura, Yohei; Yokoyama, Toshihiko; Asakura, Hiroyuki; Morimoto, Hiroyuki; Tabuchi, Masao; Ohshima, Daiki; Kato, Takeshi; Iwata, Satoshi

    2015-11-01

    The metamagnetic transition in FeRh thin films has been investigated via temperature-dependent x-ray-absorption fine-structure spectroscopy in order to gain correlations between magnetization and local electronic and geometric structures. According to the Fe and Rh K -edge x-ray-absorption near-edge structure (XANES), strong hybridization between Fe and Rh was revealed to exist. This Fe-Rh hybridization was observed to decrease during the phase transition from the antiferromagnetic (AFM) to ferromagnetic (FM) phases from the systematic change in the Fe K -edge XANES. In addition, only the Debye-Waller factor of the Fe-Fe pair in the AFM phase was observed to be considerably enhanced when compared with that in the FM phase, which was ascribed to local structural fluctuation inherent in the AFM phase. By considering the different features of the exchange interactions in Fe-Rh and Fe-Fe, this anomalous behavior is interpreted as being consistent with the recent theoretical study proposing the local fluctuations of spin and structure. Therefore, we consider that the local spin and Fe-Fe distance fluctuations play an important role in driving the metamagnetic transition, whereas the Fe-Rh hybridization correlates with the static stability of each magnetic phase.

  5. Anomalous wave structure in magnetized materials described by non-convex equations of state

    Energy Technology Data Exchange (ETDEWEB)

    Serna, Susana, E-mail: serna@mat.uab.es [Departament de Matematiques, Universitat Autonoma de Barcelona, 08193 Bellaterra, Barcelona (Spain); Marquina, Antonio, E-mail: marquina@uv.es [Departamento de Matematicas, Universidad de Valencia, 46100 Burjassot, Valencia (Spain)

    2014-01-15

    We analyze the anomalous wave structure appearing in flow dynamics under the influence of magnetic field in materials described by non-ideal equations of state. We consider the system of magnetohydrodynamics equations closed by a general equation of state (EOS) and propose a complete spectral decomposition of the fluxes that allows us to derive an expression of the nonlinearity factor as the mathematical tool to determine the nature of the wave phenomena. We prove that the possible formation of non-classical wave structure is determined by both the thermodynamic properties of the material and the magnetic field as well as its possible rotation. We demonstrate that phase transitions induced by material properties do not necessarily imply the loss of genuine nonlinearity of the wavefields as is the case in classical hydrodynamics. The analytical expression of the nonlinearity factor allows us to determine the specific amount of magnetic field necessary to prevent formation of complex structure induced by phase transition in the material. We illustrate our analytical approach by considering two non-convex EOS that exhibit phase transitions and anomalous behavior in the evolution. We present numerical experiments validating the analysis performed through a set of one-dimensional Riemann problems. In the examples we show how to determine the appropriate amount of magnetic field in the initial conditions of the Riemann problem to transform a thermodynamic composite wave into a simple nonlinear wave.

  6. Anomalous wave structure in magnetized materials described by non-convex equations of state

    International Nuclear Information System (INIS)

    We analyze the anomalous wave structure appearing in flow dynamics under the influence of magnetic field in materials described by non-ideal equations of state. We consider the system of magnetohydrodynamics equations closed by a general equation of state (EOS) and propose a complete spectral decomposition of the fluxes that allows us to derive an expression of the nonlinearity factor as the mathematical tool to determine the nature of the wave phenomena. We prove that the possible formation of non-classical wave structure is determined by both the thermodynamic properties of the material and the magnetic field as well as its possible rotation. We demonstrate that phase transitions induced by material properties do not necessarily imply the loss of genuine nonlinearity of the wavefields as is the case in classical hydrodynamics. The analytical expression of the nonlinearity factor allows us to determine the specific amount of magnetic field necessary to prevent formation of complex structure induced by phase transition in the material. We illustrate our analytical approach by considering two non-convex EOS that exhibit phase transitions and anomalous behavior in the evolution. We present numerical experiments validating the analysis performed through a set of one-dimensional Riemann problems. In the examples we show how to determine the appropriate amount of magnetic field in the initial conditions of the Riemann problem to transform a thermodynamic composite wave into a simple nonlinear wave

  7. Extracting Conceptual Feature Structures from Text

    DEFF Research Database (Denmark)

    Andreasen, Troels; Bulskov, Henrik; Jensen, Per Anker;

    2011-01-01

    This paper describes an approach to indexing texts by their conceptual content using ontologies along with lexico-syntactic information and semantic role assignment provided by lexical resources. The conceptual content of meaningful chunks of text is transformed into conceptual feature structures...... and mapped into concepts in a generative ontology. Synonymous but linguistically quite distinct expressions are mapped to the same concept in the ontology. This allows us to perform a content-based search which will retrieve relevant documents independently of the linguistic form of the query as well...

  8. A statistical feature of anomalous seismic activities prior to large shallow earthquakes in Japan revealed by the Pattern Informatics method

    Directory of Open Access Journals (Sweden)

    M. Kawamura

    2013-03-01

    Full Text Available For revealing the preparatory processes of large inland earthquakes, we systematically applied the Pattern Informatics method (PI method to the earthquake data of Japan. We focused on 12 large earthquakes with magnitudes larger than M = 6.4 (an official magnitude of the Japan Meteorological Agency that occurred at depths shallower than 30 km between 2000 and 2010. We examined the relation between the spatiotemporal locations of such large shallow earthquakes and those of PI hotspots, which correspond to the grid cells of anomalous seismic activities in a designated time span. Based on a statistical test using Molchan's error diagram, we inquired into the existence of precursory anomalous seismic activities of the large earthquakes and, if any, their characteristic time span. The test indicated that the Japanese M ≧ 6.4 inland earthquakes tend to be preceded by anomalous seismic activities of 8-to-10-yr time scales.

  9. Fractional order analysis of Sephadex gel structures: NMR measurements reflecting anomalous diffusion

    Science.gov (United States)

    Magin, Richard L.; Akpa, Belinda S.; Neuberger, Thomas; Webb, Andrew G.

    2011-12-01

    We report the appearance of anomalous water diffusion in hydrophilic Sephadex gels observed using pulse field gradient (PFG) nuclear magnetic resonance (NMR). The NMR diffusion data was collected using a Varian 14.1 Tesla imaging system with a home-built RF saddle coil. A fractional order analysis of the data was used to characterize heterogeneity in the gels for the dynamics of water diffusion in this restricted environment. Several recent studies of anomalous diffusion have used the stretched exponential function to model the decay of the NMR signal, i.e., exp[-( bD) α], where D is the apparent diffusion constant, b is determined the experimental conditions (gradient pulse separation, durations and strength), and α is a measure of structural complexity. In this work, we consider a different case where the spatial Laplacian in the Bloch-Torrey equation is generalized to a fractional order model of diffusivity via a complexity parameter, β, a space constant, μ, and a diffusion coefficient, D. This treatment reverts to the classical result for the integer order case. The fractional order decay model was fit to the diffusion-weighted signal attenuation for a range of b-values (0 < b < 4000 s mm -2). Throughout this range of b values, the parameters β, μ and D, were found to correlate with the porosity and tortuosity of the gel structure.

  10. Structural Features of Caspase-Activating Complexes

    Directory of Open Access Journals (Sweden)

    Hyun Ho Park

    2012-04-01

    Full Text Available Apoptosis, also called programmed cell death, is an orderly cellular suicide program that is critical for the development, immune regulation and homeostasis of a multi-cellular organism. Failure to control this process can lead to serious human diseases, including many types of cancer, neurodegenerative diseases, and autoimmununity. The process of apoptosis is mediated by the sequential activation of caspases, which are cysteine proteases. Initiator caspases, such as caspase-2, -8, -9, and -10, are activated by formation of caspase-activating complexes, which function as a platform to recruit caspases, providing proximity for self-activation. Well-known initiator caspase-activating complexes include (1 DISC (Death Inducing Signaling Complex, which activates caspases-8 and 10; (2 Apoptosome, which activates caspase-9; and (3 PIDDosome, which activates caspase-2. Because of the fundamental biological importance of capases, many structural and biochemical studies to understand the molecular basis of assembly mechanism of caspase-activating complexes have been performed. In this review, we summarize previous studies that have examined the structural and biochemical features of caspase-activating complexes. By analyzing the structural basis for the assembly mechanism of the caspase-activating complex, we hope to provide a comprehensive understanding of caspase activation by these important oligomeric complexes.

  11. Honeycomb lattice with multiorbital structure: Topological and quantum anomalous Hall insulators with large gaps

    Science.gov (United States)

    Zhang, Gu-Feng; Li, Yi; Wu, Congjun

    2015-03-01

    We construct a minimal four-band model for the two-dimensional topological insulators and quantum anomalous Hall insulators based on the px- and py-orbital bands in the honeycomb lattice. The multiorbital structure allows the atomic spin-orbit coupling which lifts the degeneracy between two sets of on-site Kramers doublets jz = +/-3/2 and jz = +/-1/2 . Because of the orbital angular momentum structure of Bloch-wave states at Γ and K (K') points, topological gaps are equal to the atomic spin-orbit coupling strengths, which are much larger than those based on the mechanism of the s - p band inversion.The energy spectra and eigen wave functions are solved analytically based on Clifford algebra. The competition among spin-orbit coupling λ, sublattice asymmetry m, and the Néel exchange field n results in band crossings at Γ and K (K') points, which leads to various topological band structure transitions. The quantum anomalous Hall state is reached under the condition that three gap parameters λ, m, and n satisfy the triangle inequality. Flat bands also naturally arise which allow a local construction of eigenstates. The above mechanism is related to several classes of solid state semiconductor. G.F.Z. and C.W. are supported by the NSF DMR-1410375 and AFOSR FA9550-11-1-0067(YIP). Y.L. thanks the Inamori Fellowship and the support at the Princeton Center for Theoretical Science. C.W. acknowledges financial support from the National Natural Science.

  12. Prion protein: structural features and related toxicity

    Institute of Scientific and Technical Information of China (English)

    Ping Ping Hu; Cheng Zhi Huang

    2013-01-01

    Transmissible spongiform encephalopathies,or prion diseases,is a group of infectious neurodegenerative disorders.The conformational conversion from cellular form (PrPC) to disease-causing isoform (PrPSc) is considered to be the most important and remarkable event in these diseases,while accumulation of PrPSc is thought to be the main reason for cell death,inflammation and spongiform degeneration observed in infected individuals.Although these rare but unique neurodegenerative disorders have attracted much attention,there are still many questions that remain to be answered.Knowledge of the scrapie agent structures and the toxic species may have significance for understanding the causes of the diseases,and could be helpful for rational design of novel therapeutic and diagnostic methods.In this review,we summarized the available experimental evidence concerning the relationship among the structural features,aggregation status of misfolded PrP and related neurotoxicity in the course of prion diseases development.In particular,most data supports the idea that the smaller oligomeric PrPSc aggregates,rather than the mature amyloid fibers,exhibit the highest toxicity to the host.

  13. Structural features that optimize high temperature superconductivity

    International Nuclear Information System (INIS)

    Studies of a large number of compounds have provided a consistent picture of what structural features give rise to the highest Tc's in copper-oxide superconductors. For example, various defects can be introduced into the blocking layer to provide the optimum carrier concentration, but defects that form in or adjacent to the CuO2 layers will lower Tc and eventually destroy superconductivity. After these requirements are satisfied, the highest Tc's are observed for compounds (such as the HgBa2Can-1CunO2n+2+x family) that have flat and square CuO2 planes and long apical Cu-O bonds. This conclusion is confirmed by the study of materials in which the flatness of the CuO2 plane can be varied in a systematic way. In more recent work, attention has focused on how the structure can be modified, for example, by chemical substitution, to improve flux pinning properties. Two strategies are being investigated: (1) Increasing the coupling of pancake vortices to form vortex lines by shortening or ''metallizing'' the blocking layer; and (2) the formation of defects that pin flux. (orig.)

  14. Anomalous origin of the left coronary artery from the pulmonary trunk. Clinical features and midterm results after surgical treatment

    Directory of Open Access Journals (Sweden)

    Amaral Fernando

    1999-01-01

    Full Text Available OBJECTIVE: To report the authors' experience with the anomalous origin of the left coronary artery (AOLCA from the pulmonary trunk, emphasizing preoperative data, surgical aspects and midterm results of the follow-up. METHODS: Retrospective analysis of 11 patients operated upon at the Royal Brompton Hospital from October, 84 to April, 97. RESULTS: Nine infants had heart failure (HF and two other children presented with dyspnea and chest pain. All had ECG changes. The echocardiogram identified the anomalous origin of the coronary artery in 7 (64% patients and hemodynamic studies were performed in 7 patients. All infants were operated upon between the 2nd and 10th month of life. Six patients were treated with aortic reimplantation of the left coronary artery, whereas five were operated upon according to the Takeuchi technique. All patients are alive, with clear improvement of the ECG changes and ventricular function, as evaluated by echocardiography. Two patients operated upon according to the Takeuchi technique required additional surgery due to severe supravalvular pulmonary stenosis. CONCLUSION: AOLCA is a rare disease. Most patients show early signs of severe HF associated with ECG findings. Surgical therapy must be instituted early in the disease, preferentially through aortic implantation of the anomalous coronary artery, with a high possibility of success. Shortly after surgery, clinical and ECG improvement, as well as normalization of left ventricular function, should be expected.

  15. Age features of eyeball envelopes structure

    Directory of Open Access Journals (Sweden)

    Ulyanova N.A.

    2014-03-01

    Full Text Available Background. The absence of adequate experimental model of myopia is the actual problem in pathophysiological investigation of the myopia progression. Studies of the chick eye have formed the basis for several hypotheses of myopia development. The most pathogenically valid animal model of myopia is a deprivation model. Before introduction of this model in mammals, in particular rats, it is necessary to investigate the dynamics of age morphological changes in sclera and retina. Objective. To determine the age-related features of the sclera and retina in intact rats. Methods. The sclera and retina were investigated by optic microscopy method on the 14th, 21st, 30th, 40th, 50th, 60th, 70th, 90th days after birth. Results. It was determined that sagittal, vertical and horizontal sizes of rats eyes increase more intensively at the age period from the 14th to the 30th day. At this time the maximal number of fibroblasts was observed in sclera. The total amount of these cells decreases after 40 days of postnatal ontogenesis. At the same time changes in thickness and compactness of retina layers were detected. At the age period from the 14th to the 30th day definitive scleral tissue architecture is not yet formed, part of collagen fibrils are organized in bundles, part of them are loosely arranged. On the 90th day all collagen fibrils of scleral stroma and retina are arranged. Conclusion. The highest intensity of sclera and retina restructuring is observed between the 14th and 30th days of postnatal ontogenesis. This period could be considered as optimal for experimental modeling of myopia in rats. Citation: Ulyanova NA. [Age features of eyeball envelopes structure]. Morphologia. 2014;8(1:95-8. Russian.

  16. Structure investigation of metal ions clustering in dehydrated gel using x-ray anomalous dispersion effect

    CERN Document Server

    Soejima, Y; Sugiyama, M; Annaka, M; Nakamura, A; Hiramatsu, N; Hara, K

    2003-01-01

    The structure of copper ion clusters in dehydrated N-isopropylacrylamide/sodium acrylate (NIPA/SA) gel has been studied by means of small angle X-ray scattering (SAXS) method. In order to distinguish the intensity scattered by Cu ions, the X-ray anomalous dispersion effect around the Cu K absorption edge has been coupled with SAXS. It is found that the dispersion effect dependent on the incident X-ray energy is remarkable only at the momentum transfer q = 0.031 A sup - sup 1 , where a SAXS peak is observed. The results indicate that copper ions form clusters in the dehydrated gel, and that the mean size of clusters is the same as that of SA clusters produced by microphase separation. It is therefore naturally presumed that copper ions are adsorbed into the SA molecules. On the basis of the presumption, a mechanism is proposed for microphase-separation and clustering of Cu ions.

  17. Structure determination by multiple-wavelength anomalous dispersion (MAD) at the Pr LIII edge

    International Nuclear Information System (INIS)

    A successful MAD experiment has been conducted at the Pr LIII edge on HZB beamline BL14.2. The use of longer X-ray wavelengths in macromolecular crystallography has grown significantly over the past few years. The main reason for this increased use of longer wavelengths has been to utilize the anomalous signal from sulfur, providing a means for the experimental phasing of native proteins. Here, another possible application of longer X-ray wavelengths is presented: MAD at the LIII edges of various lanthanide compounds. A first experiment at the LIII edge of Pr was conducted on HZB MX beamline BL14.2 and resulted in the successful structure determination of the C-terminal domain of a spliceosomal protein. This experiment demonstrates that LIII edges of lanthanides constitute potentially attractive targets for long-wavelength MAD experiments

  18. Is there evidence for anomalous dipole anisotropy in the large-scale structure?

    CERN Document Server

    Bengaly,, C A P; Alcaniz, J S; Xavier, H S; Novaes, C P

    2016-01-01

    We probe the anisotropy of the large-scale structure (LSS) with the WISE-2MASS catalogue. This analysis is performed by a directional comparison of the galaxy number counts through the entire celestial sphere once systematic effects, such as star-galaxy separation and foregrounds contamination, are properly taken into account. We find a maximal hemispherical asymmetry whose dipolar component is $A = 0.0507 \\pm 0.0014$ toward the $(l,b) = (323^{\\circ},-5^{\\circ})$ direction. This result is consistent with previous estimations of our proper motion in low and intermediate redshifts, as those carried out with Type Ia Supernovae and similar LSS catalogues.Furthermore, this dipole amplitude obtained is statistically consistent with mock catalogues simulated according to the $\\Lambda$CDM matter density expected fluctuations, in addition to observational biases such as the incomplete celestial coverage, anisotropic sky exposure. Our results suggest, therefore, that there is no strong evidence for anomalous anisotropy...

  19. Anomalous structural dynamics in liquid Al80Cu20: An ab initio molecular dynamics study

    International Nuclear Information System (INIS)

    In this work, the structural dynamics of liquid Al80Cu20 is systematically investigated in terms of the evolution of its atomic structure, diffusivity, viscosity and fragility through ab initio molecular dynamics simulations. In addition to using pair correlation functions and coordination numbers, the various local ordered clusters are characterized comprehensively by Honeycutt-Anderson bond pairs and Voronoi polyhedra. Compared to the self diffusivity of pure liquid Cu, the tracer diffusion coefficients of Cu in liquid Al80Cu20 are increased, in agreement with the results measured by quasielastic neutron-scattering (QENS). Although the interdiffusion coefficients predicted by Darken’s equation match well to those obtained from the viscosity measurements via the Stokes-Einstein relation, they are smaller than those measured by QENS or X-ray radiography, indicative of an anomalous nature of the structural dynamics, dominated by the local ordered clusters in liquid Al80Cu20. Furthermore, Vogel–Fulcher–Tammann fitting results indicate that the liquid Al80Cu20 can be classified into a strong liquid. The deformation electron density shows that the intrinsic tetrahedral-type bonds in FCC Al and Cu are transformed into an amorphous type in liquid Al80Cu20. The present work provides insights into the understanding of structural dynamics and the kinetic properties of such metallic melts

  20. Protein structure determination by single-wavelength anomalous diffraction phasing of X-ray free-electron laser data.

    Science.gov (United States)

    Nass, Karol; Meinhart, Anton; Barends, Thomas R M; Foucar, Lutz; Gorel, Alexander; Aquila, Andrew; Botha, Sabine; Doak, R Bruce; Koglin, Jason; Liang, Mengning; Shoeman, Robert L; Williams, Garth; Boutet, Sebastien; Schlichting, Ilme

    2016-05-01

    Serial femtosecond crystallography (SFX) at X-ray free-electron lasers (XFELs) offers unprecedented possibilities for macromolecular structure determination of systems that are prone to radiation damage. However, phasing XFEL data de novo is complicated by the inherent inaccuracy of SFX data, and only a few successful examples, mostly based on exceedingly strong anomalous or isomorphous difference signals, have been reported. Here, it is shown that SFX data from thaumatin microcrystals can be successfully phased using only the weak anomalous scattering from the endogenous S atoms. Moreover, a step-by-step investigation is presented of the particular problems of SAD phasing of SFX data, analysing data from a derivative with a strong anomalous signal as well as the weak signal from endogenous S atoms. PMID:27158504

  1. The Edgerton Structure: A Possible Meteorite Impact Feature in Eastern Kansas

    Directory of Open Access Journals (Sweden)

    Daniel F. Merriam

    2009-01-01

    Full Text Available Recognized meteorite impact features are relatively rare in the U.S. Midcontinent region, but recently with increased interest and research, the number has increased dramatically. We add another possibility to the growing list, the Edgerton structure in northwestern Miami County, Kansas. The feature is elliptical (∼5.5 × 6.5 km, slightly elongated east-west with radial surface drainage. The feature was first observed on hillshade maps of digitized topography of 7.5 minute quadrangles. Subsequent magnetic profiles show a higher magnetic value in the center of the ellipse with higher values around the edges; this shape is characteristic of an impact feature. Depth to the anomalous body is estimated to be about 1 km, which puts it in the Precambrian crystalline basement under a cover of Paleozoic sediments. There are no deep boreholes in the vicinity and no seismic profiles are available. If it is an impact structure, it will be the second such feature documented in Kansas, the first being the Brenham meteorite crater at Haviland in Kiowa County in southwestern Kansas. It would be older than the other impact structures identified in the Midcontinent—Manson in Iowa, Ames in Oklahoma, Haswell Hole in Colorado, and possibly Belton in Missouri and Merna in Nebraska. There are at least two other prospective impact features in Kansas: the Goddard ring west of Wichita and Garden City ellipse north-west of Garden City.

  2. A semi-structured, phenomenologically oriented psychiatric interview: Descriptive congruens in assessing anomalous subjective experience and mental status

    DEFF Research Database (Denmark)

    Frederiksen, Julie Elisabeth Nordgaard; Parnas, Josef Stefan Stanislaw

    2012-01-01

    Objective: The contemporary methodology in obtaining psychopathological information relies almost exclusively on the use of structured questionnaires and interview schedules. These interviews yield high interrater reliability and reduce cost. The assessments of anomalous self-experience and of...... mental status (disorders of experience and expression) are often considered as “soft”, “subjective” and hence unreliable. In spite of the advantages of the structured interviews, concerns have been raised about the epistemological coherence and the validity of the structured interviews. To examine the...... interrater congruens between experienced clinicians with a semi structured, phenomenologically oriented psychopathological interview assessing anomalous self-experience and mental status. Method: Seventeen inpatients were interviewed by one of the raters, with both raters were present. The interview...

  3. Development of powder diffraction anomalous fine structure method and applications to electrode materials for rechargeable batteries

    International Nuclear Information System (INIS)

    A powder diffraction anomalous fine structure (P-DAFS) method is developed both in analytical and experimental techniques and applied to cathode materials for lithium ion batteries. The DAFS method, which is an absorption spectroscopic technique through a scattering measurement, enables us to analyze the chemical states and the local structures of a certain element at different sites, thanks to the nature of x-ray diffraction, where the contributions from each site are different at each diffraction. Electrode materials for rechargeable batteries frequently exhibit the interchange between Li and a transition metal, which is known as the cation mixing phenomena. This cation mixing significantly affects the whole electrode properties; therefore, the site-distinguished understanding of the roles of the transition metal is essential for further material design by controlling and positively utilizing this cation mixing phenomenon. However, the developments of the P-DAFS method are required for the applications to the practical materials such as the electrode materials. In the present study, a direct analysis technique to extract the absorption spectrum from the scattering without using the conventional iterative calculations, fast and accurate measurement techniques of the P-DAFS method, and applications to a typical electrode material of Li1-xNi1+xO2, which exhibits the significant cation mixing, are described. (author)

  4. Clustering effects for explaining an anomalous JLab result on the Be-9 structure function

    CERN Document Server

    Hirai, M; Saito, K; Watanabe, T

    2011-01-01

    An anomalous nuclear modification was reported by JLab measurements on the beryllium-9 structure function F_2. It is unexpected in the sense that a nuclear modification slope is too large to be expected from its average nuclear density. We investigated whether it is explained by a nuclear clustering configuration in Be-9 with two \\alpha nuclei and surrounding neutron clouds. Such clustering aspects are studied by using antisymmetrized molecular dynamics (AMD) and also by a simple shell model for comparison. We consider that nuclear structure functions F_2^A consist of a mean conventional part and a remaining one depending on the maximum local density. The first mean part does not show a significant cluster effect on F_2. However, we propose that the remaining one could explain the anonymous JLab slope, and it is associated with high densities created by the cluster formation in Be-9. The JLab measurement is possibly the first signature of clustering effects in high-energy nuclear reactions. A responsible phys...

  5. Spin Seebeck Effect vs. Anomalous Nernst Effect in Ta/CoFeB /Ta Structures

    Science.gov (United States)

    Yang, Bowen; Xu, Yadong; Schneider, Mike; Shi, Jing; Univ of California-Riverside Team; Everspin Technologies Inc. Team

    2014-03-01

    We have studied the spin Seebeck effect (SSE) and anomalous Nernst effect (ANE) in a vertical trilayer structure under a vertical temperature gradient. The structure consists of a 3nm CoFeB layer sandwiched by β-phase tantalum (Ta) layers. The samples are deposited by magnetron sputtering. The existence of Ta β-phase is verified by the resistivity and its negative temperature coefficient of resistance(TCR). Under a fixed vertical temperature gradient, the measured transverse thermoelectric voltage is linearly proportional to the total sample resistance when the Ta thickness exceeds 2 nm, which can be explained by a shunting resistor model. When the Ta thickness is below 2 nm, the voltage deviates from the linear resistance dependence and merges to the ANE voltage of the CoFeB single layer, due to a weakened inverse spin Hall effect (ISHE) in Ta thinner than the spin diffusion length. In the linear regime, the slope contains both a varying SSE and a fixed ANE responses, thus the SSE contribution could be quantitatively separated out from the ANE of CoFeB. Our results indicate a large SSE from the β-phase Ta due to its large Spin Hall Angle. This work was supported by CNN/DMEA and DOE.

  6. Structural Features of Algebraic Quantum Notations

    Science.gov (United States)

    Gire, Elizabeth; Price, Edward

    2015-01-01

    The formalism of quantum mechanics includes a rich collection of representations for describing quantum systems, including functions, graphs, matrices, histograms of probabilities, and Dirac notation. The varied features of these representations affect how computations are performed. For example, identifying probabilities of measurement outcomes…

  7. Anomalous Hyperfine Structure of the $^{229}$Th Ground-State Doublet in Muonic Atom

    CERN Document Server

    Tkalya, E V

    2016-01-01

    The hyperfine splitting of the ground and low-energy $3/2^+(7.8 \\pm 0.5$ eV) levels in the $^{229}$Th nucleus in muonic atom ($\\mu^-_{1S_{1/2}}{}^{229}$Th$)^*$ has been calculated considering the distribution of the nuclear magnetization in the framework of collective nuclear model with the wave functions of the Nilsson model for the unpaired neutron. It is shown that (a) the hyperfine splitting of the $3/2^+$ isomeric state is anomalously weak, and the reduction of hyperfine structure in comparison with the model of a point nuclear magnetic dipole is close to 100\\%, (b) partial inversion of levels of the $^{229}$Th ground-state doublet and spontaneous decay of the ground state with excitation of the isomeric state take place, (c) the energy of the isomeric transition lies in the range of 120--140 eV, which makes possible the direct observation of the transition, registration of conversion electrons and measurement of the nuclear matrix element.

  8. Temperature-induced anomalous structural changes of Al-12wt.%Sn-4wt.%Si melt and its influence on as-cast structure

    Directory of Open Access Journals (Sweden)

    Wang Zhiming

    2010-05-01

    Full Text Available The temperature dependence of the viscosity of liquid Al-12wt.%Sn-4wt.%Si was studied with a high-temperature viscosity apparatus. Anomalous changes of viscosity of the melt were found at 1,103 K and 968 K in the cooling process, which indicates anomalous structural changes of the melt. It is calculated that the anomalous structural change is associated with an abrupt decrease of atomic clusters’ size and activation energy in the melt. According to the temperature of the anomalous structural changes, melt heat treatment process (quenching from superheat to pouring temperature was performed on Al-12wt.%Sn-4wt.%Si melt prior to pouring, aimed to keep the small atomic clusters from higher temperature to lower pouring temperature. The results suggest that relatively small atomic clusters at the pouring temperature in the melt could generate a deep under-cooling of nucleation in the subsequent solidification process, and refine the as-cast structure. After being quenched from superheating to pouring temperature, the relatively small atomic clusters, especially the Si-Si clusters in the melt will grow to equilibrium state (relatively big atomic clusters with holding time, resulting in the prominent coarsening of the Si morphology in the as-cast structure.

  9. Structural features of neutral and cationic cyclams

    Science.gov (United States)

    Alves, Luis G.; Duarte, M. Teresa; Martins, Ana M.

    2015-10-01

    Dicationic compounds of general formula [1,8-R2-1,4,8,11-tetraazatricyclo[9.3.1.14,8]hexadecane]X2, where R = H, Me or Bn' and X is a halogen counterion were obtained by reactions of 1,4,8,11-tetraazatricyclo[9.3.1.14,8]hexadecane with different electrophiles. The solid-state molecular structures of the compounds reveal that the hydrogen, methyl or benzyl groups are located on the nitrogen atoms that are not only the less sterically hindered but also have the electron lone pair pointing out of the macrocycle backbone. In all compounds it is observed a bond shortening between the N-Caminal and the two other C-N bonds that may be attributed to an inductive effect. These compounds afford the corresponding trans-N,N'-disubstituted cyclams upon hydrolysis in basic medium.

  10. Parameterized type expansion in the feature structure formalism TDL

    OpenAIRE

    Schäfer, Ulrich

    1995-01-01

    Over the last few years, unification-based grammar formalisms have become the predominant paradigm in natural language processing systems because of their monotonicity, declarativeness, and reversibility. From the viewpoint of computer science, typed feature structures can be seen as data structures that allow representation of linguistic knowledge in a uniform fashion. Type expansion is an operation that makes the constraints on a typed feature structure explicit and determines their satisfi...

  11. Anomalously low amplitude of S waves produced by the 3D structures in the lower mantle

    Science.gov (United States)

    To, Akiko; Capdeville, Yann; Romanowicz, Barbara

    2016-07-01

    Direct S and Sdiff phases with anomalously low amplitudes are recorded for the earthquakes in Papua New Guinea by seismographs in northern America. According to the prediction by a standard 1D model, the amplitudes are the lowest at stations in southern California, at a distance and azimuth of around 95° and 55°, respectively, from the earthquake. The amplitude anomaly is more prominent at frequencies higher than 0.03 Hz. We checked and ruled out the possibility of the anomalies appearing because of the errors in the focal mechanism used in the reference synthetic waveform calculations. The observed anomaly distribution changes drastically with a relatively small shift in the location of the earthquake. The observations indicate that the amplitude reduction is likely due to the 3D shear velocity (Vs) structure, which deflects the wave energy away from the original ray paths. Moreover, some previous studies suggested that some of the S and Sdiff phases in our dataset are followed by a prominent postcursor and show a large travel time delay, which was explained by placing a large ultra-low velocity zone (ULVZ) located on the core-mantle boundary southwest of Hawaii. In this study, we evaluated the extent of amplitude anomalies that can be explained by the lower mantle structures in the existing models, including the previously proposed ULVZ. In addition, we modified and tested some models and searched for the possible causes of low amplitudes. Full 3D synthetic waveforms were calculated and compared with the observations. Our results show that while the existing models explain the trends of the observed amplitude anomalies, the size of such anomalies remain under-predicted especially at large distances. Adding a low velocity zone, which is spatially larger and has less Vs reduction than ULVZ, on the southwest side of ULVZ, contributes to explain the low amplitudes observed at distances larger than 100° from the earthquake. The newly proposed low velocity zone

  12. Ochronotic arthropathy: structural and ultrastructural features.

    Science.gov (United States)

    Melis, M; Onori, P; Aliberti, G; Vecci, E; Gaudio, E

    1994-01-01

    Fragments of articular cartilage and synovial membrane in a case of ochronosis were studied by light microscopy (LM), polarized light, and transmission electron microscopy (TEM). Granular and/or shard-shaped pigments were observed in the synovia, cartilage, and subchondral tissue, and dispersed pigment was also seen in the synovial fluid. Zones of the articular cartilage surface showed small erosions near shards, and sometimes, when the degenerative process was in an advanced stage, a substitutive fibrosis of the cartilage edge was demonstrated. LM and TEM observations of the samples studied revealed an alteration of collagen fibrils that appeared wavy and sometimes fragmented with loss of periodicity. They were always mixed with the dispersed pigment. A peculiar finding that characterized this ochronotic case was the complete absence of inflammatory infiltrates or signs of monocyte-macrophage activation. These structural and ultrastructural observations suggest that the pigment deposition in the articular surfaces was due to the synovial fluid circulation and partially to subchondral blood flow, which transports and stores the ochronotic pigments in the synovia and cartilage. These etiopathologic elements associated with the mechanical pathogenesis naturally present in the joints can contribute to the explanation of the pathogenesis and origin of ochronotic arthropathy. PMID:7809996

  13. The 2006-2007 Active Phase of Anomalous X-ray Pulsar 4U 0142+61: Radiative and Timing Changes, Bursts, and Burst Spectral Features

    CERN Document Server

    Gavriil, Fotis P; Kaspi, Victoria M

    2009-01-01

    After at least 6 years of quiescence, Anomalous X-ray Pulsar (AXP) 4U 0142+61 entered an active phase in 2006 March that lasted several months and included six X-ray bursts as well as many changes in the persistent X-ray emission. The bursts, the first seen from this AXP in >11 years of Rossi X-ray Timing Explorer monitoring, all occurred in the interval between 2006 April 6 and 2007 February 7. The burst durations ranged from 8-3x10^3 s. The first five burst spectra are well modeled by blackbodies, with temperatures kT ~ 2-6 keV. However, the sixth burst had a complicated spectrum that is well characterized by a blackbody plus three emission features whose amplitude varied throughout the burst. The most prominent feature was at 14.0 keV. Upon entry into the active phase the pulsar showed a significant change in pulse morphology and a likely timing glitch. The glitch had a total frequency jump of 1.9+/-0.4 x 10^-7 Hz, which recovered with a decay time of 17+/-2 days by more than the initial jump, implying a n...

  14. Detecting Lo cal Manifold Structure for Unsup ervised Feature Selection

    Institute of Scientific and Technical Information of China (English)

    FENG Ding-Cheng; CHEN Feng; XU Wen-Li

    2014-01-01

    Unsupervised feature selection is fundamental in statistical pattern recognition, and has drawn persistent attention in the past several decades. Recently, much work has shown that feature selection can be formulated as nonlinear dimensionality reduction with discrete constraints. This line of research emphasizes utilizing the manifold learning techniques, where feature selection and learning can be studied based on the manifold assumption in data distribution. Many existing feature selection methods such as Laplacian score, SPEC (spectrum decomposition of graph Laplacian), TR (trace ratio) criterion, MSFS (multi-cluster feature selection) and EVSC (eigenvalue sensitive criterion) apply the basic properties of graph Laplacian, and select the optimal feature subsets which best preserve the manifold structure defined on the graph Laplacian. In this paper, we propose a new feature selection perspective from locally linear embedding (LLE), which is another popular manifold learning method. The main difficulty of using LLE for feature selection is that its optimization involves quadratic programming and eigenvalue decomposition, both of which are continuous procedures and different from discrete feature selection. We prove that the LLE objective can be decomposed with respect to data dimensionalities in the subset selection problem, which also facilitates constructing better coordinates from data using the principal component analysis (PCA) technique. Based on these results, we propose a novel unsupervised feature selection algorithm, called locally linear selection (LLS), to select a feature subset representing the underlying data manifold. The local relationship among samples is computed from the LLE formulation, which is then used to estimate the contribution of each individual feature to the underlying manifold structure. These contributions, represented as LLS scores, are ranked and selected as the candidate solution to feature selection. We further develop a

  15. Addendum to ``Off-shell structure of the anomalous Z and γ self-couplings''

    Science.gov (United States)

    Gounaris, G. J.; Layssac, J.; Renard, F. M.

    2002-01-01

    We point out that the lowest dimension operators that preserve SU(2)×U(1) gauge invariance and induce gauge boson self-interactions affecting only the neutral gauge bosons are just two dim=8 operators. If these operators constitute the only new physics source, there will then exist only two independent anomalous couplings affecting Z and γ: i.e., one CP conserving and one CP violating. On this basis, we give the corresponding relations among the ZZZ, ZZγ, and γγZ couplings used up to now in the analyses of experimental data. A reanalysis taking these relations into account should produce much more stringent constraints on the anomalous couplings.

  16. Anomalous capacitance characteristics of TFTs with LDD structures in the saturation region

    International Nuclear Information System (INIS)

    The effect of lightly doped drain (LDD) doping concentration on the capacitance of a low-temperature polycrystalline silicon (LTPS) thin-film transistor (TFT) is investigated. An anomalous gate-to-source capacitance phenomenon is observed: first, the capacitance decreases, and then it increases according to the gate voltage in the saturation region. This phenomenon is not affected by the subgap density-of-states and arises as the doping concentration of the LDD region is reduced. To investigate the effects of each source and the drain LDD dose on the gate-to-source capacitance, two-dimensional device simulations were conducted in which each dose of the source and drain LDD was changed individually. The reduced controllability of the source voltage to the gate charge in the saturation region due to the increased resistance of the source LDD region with low LDD dose is identified as the reason for this anomalous capacitance phenomenon. (paper)

  17. Anomalous capacitance characteristics of TFTs with LDD structures in the saturation region

    Science.gov (United States)

    Kim, Miryeon; Sun, Wookyung; Shin, Minho; Kim, Kiwoo; Kang, Jongseuk; Shin, Hyungsoon

    2016-05-01

    The effect of lightly doped drain (LDD) doping concentration on the capacitance of a low-temperature polycrystalline silicon (LTPS) thin-film transistor (TFT) is investigated. An anomalous gate-to-source capacitance phenomenon is observed: first, the capacitance decreases, and then it increases according to the gate voltage in the saturation region. This phenomenon is not affected by the subgap density-of-states and arises as the doping concentration of the LDD region is reduced. To investigate the effects of each source and the drain LDD dose on the gate-to-source capacitance, two-dimensional device simulations were conducted in which each dose of the source and drain LDD was changed individually. The reduced controllability of the source voltage to the gate charge in the saturation region due to the increased resistance of the source LDD region with low LDD dose is identified as the reason for this anomalous capacitance phenomenon.

  18. Origins of Anomalous Transport in Disordered Media: Structural and Dynamic Controls

    CERN Document Server

    Edery, Yaniv; Guadagnini, Alberto; Berkowitz, Brian

    2013-01-01

    We quantitatively identify the origin of anomalous transport in a representative model of a heterogeneous system---tracer migration in the complex flow patterns of a lognormally distributed hydraulic conductivity ($K$) field. The transport, determined by a particle tracking technique, is characterized by breakthrough curves; the ensemble averaged curves document anomalous transport in this system, which is entirely accounted for by a truncated power-law distribution of local transition times $\\psi(t)$ within the framework of a continuous time random walk. Unique to this study is the linking of $\\psi(t)$ directly to the system heterogeneity. We assess the statistics of the dominant preferred pathways by forming a particle-visitation weighted histogram $\\{wK\\}$. Converting the ln($K$) dependence of $\\{wK\\}$ into time yields the equivalence of $\\{wK\\}$ and $\\psi(t)$, and shows the part of $\\{wK\\}$ that forms the power-law of $\\psi(t)$, which is the origin of anomalous transport. We also derive an expression defi...

  19. Origins of Anomalous Transport in Disordered Media: Structural and Dynamic Controls

    Science.gov (United States)

    Edery, Y.; Scher, H.; Guadagnini, A.; Berkowitz, B.

    2013-12-01

    We quantitatively identify the origin of anomalous transport in a representative model of a heterogeneous system-tracer migration in the complex flow patterns of a lognormally distributed hydraulic conductivity (K) field. The transport, determined by a particle tracking technique, is characterized by breakthrough curves; the ensemble averaged curves document anomalous transport in this system, which is entirely accounted for by a truncated power-law distribution of local transition times ψ(t) within the framework of a continuous time random walk. Unique to this study is the linking of ψ(t) directly to the system heterogeneity. We assess the statistics of the dominant preferred pathways by forming a particle-visitation weighted histogram {wK}. Converting the ln(K) dependence of {wK} into time yields the equivalence of {wK} and ψ(t), and shows the part of {wK} that forms the power-law of ψ(t), which is the origin of anomalous transport. We also derive an expression defining the power law exponent in terms of the {wK} parameters. This equivalence is a remarkable result, particularly given the correlated K-field, the complexity of the flow field and the statistics of the particle transitions.

  20. Novel method for detection of anomalous structure characteristics of ID precision ultrathin monocrystalline silicon section cutting tool

    Institute of Scientific and Technical Information of China (English)

    陈宗农; 郭明; 王庆九; 余学功

    2002-01-01

    The structure characteristics of ID precision uhrathin monoerystaUine silicon section cutting machine-tool spindle with force-monitoring bearings functioning as force measuring sensors were detected with the new Hilbert theory based signal-wave envelope detection method, presented to replace the conventional hardware device in order to ensure that the signal is measured online with high fidelity.According to the probability of anomalous incidents in the cutting process, a mathematical recognition model has been designed and verified on an STC-22ID machine.

  1. Novel method for detection of anomalous structure characteristics of ID precision ultrathin monocrystalline silicon section cutting tool

    Institute of Scientific and Technical Information of China (English)

    陈宗农; 郭明; 王庆九; 余学功

    2002-01-01

    The structure characteristics of ID precision ultrathin monocrystalline silicon section cutting machine-tool spindle with force-monitoring bearings functioning as force measuring sensors were detected with the new Hilbert theory based signal-wave envelope detection method, presented to replace the conventional hardware device in order to ensure that the signal is measured online with high fidelity. According to the probability of anomalous incidents in the cutting process, a mathematical recognition model has been designed and verified on an STC-22ID machine.

  2. Understanding Protein-Protein Interactions Using Local Structural Features

    DEFF Research Database (Denmark)

    Planas-Iglesias, Joan; Bonet, Jaume; García-García, Javier;

    2013-01-01

    Protein-protein interactions (PPIs) play a relevant role among the different functions of a cell. Identifying the PPI network of a given organism (interactome) is useful to shed light on the key molecular mechanisms within a biological system. In this work, we show the role of structural features...... interacting and non-interacting protein pairs to classify the structural features that sustain the binding (or non-binding) behavior. Our study indicates that not only the interacting region but also the rest of the protein surface are important for the interaction fate. The interpretation of this...... classification suggests that the balance between favoring and disfavoring structural features determines if a pair of proteins interacts or not. Our results are in agreement with previous works and support the funnel-like intermolecular energy landscape theory that explains PPIs. We have used these features to...

  3. STRUCTURAL FEATURES OF PLANT CHITINASES AND CHITIN-BINDING PROTEINS

    NARCIS (Netherlands)

    BEINTEMA, JJ

    1994-01-01

    Structural features of plant chitinases and chitin-binding proteins are discussed. Many of these proteins consist of multiple domains,of which the chitin-binding hevein domain is a predominant one. X-ray and NMR structures of representatives of the major classes of these proteins are available now,

  4. The 2006-2007 Active Phase of Anomalous X-Ray Pulsar 4U 0142+61: Radiative and Timing Changes, Bursts,and Burst Spectral Features

    Science.gov (United States)

    Gavriil, Fotis P.; Dib, Rim; Kaspi, Victoria M.

    2011-01-01

    After at least 6 years of quiescence, Anomalous X-ray Pulsar (AXP) 4U 0142+61 entered an active phase in 2006 March that lasted several months and included six X-ray bursts as well as many changes in the persistent X-ray emission. The bursts, the first seen from this AXP in > 11 years of Rossi X-ray Timing Explorer monitoring, all occurred in the interval between 2006 April 6 and 2007 February 7. The burst durations ranged from 0.4 - 1.8 x 10(exp 3) s. The first five burst spectra are well modeled by blackbodies, with temperatures kT approx 2 - 9 keV. However, the sixth burst had a complicated spectrum that is well characterized by a blackbody plus two emission features whose amplitude varied throughout the burst. The most prominent feature was at 14.0 keV. Upon entry into the active phase the pulsar showed a significant change in pulse morphology and a likely timing glitch. The glitch had a total frequency jump of (1.9+/-0.4) x 10(exp -7) Hz, which recovered with a decay time of 17+/-2 days by more than the initial jump, implying a net spin-down of the pulsar. Within the framework of the magnetar model, the net spin-down of the star could be explained by regions of the superfluid that rotate. slower than the rest. The bursts, flux enhancements, and pulse morphology changes can be explained as arising from crustal deformations due to stresses imposed by the highly twisted internal magnetic field. However, unlike other AXP outbursts, we cannot account for a major twist being implanted in the magnetosphere.

  5. Structural health monitoring feature design by genetic programming

    International Nuclear Information System (INIS)

    Structural health monitoring (SHM) systems provide real-time damage and performance information for civil, aerospace, and other high-capital or life-safety critical structures. Conventional data processing involves pre-processing and extraction of low-dimensional features from in situ time series measurements. The features are then input to a statistical pattern recognition algorithm to perform the relevant classification or regression task necessary to facilitate decisions by the SHM system. Traditional design of signal processing and feature extraction algorithms can be an expensive and time-consuming process requiring extensive system knowledge and domain expertise. Genetic programming, a heuristic program search method from evolutionary computation, was recently adapted by the authors to perform automated, data-driven design of signal processing and feature extraction algorithms for statistical pattern recognition applications. The proposed method, called Autofead, is particularly suitable to handle the challenges inherent in algorithm design for SHM problems where the manifestation of damage in structural response measurements is often unclear or unknown. Autofead mines a training database of response measurements to discover information-rich features specific to the problem at hand. This study provides experimental validation on three SHM applications including ultrasonic damage detection, bearing damage classification for rotating machinery, and vibration-based structural health monitoring. Performance comparisons with common feature choices for each problem area are provided demonstrating the versatility of Autofead to produce significant algorithm improvements on a wide range of problems. (paper)

  6. Nonparametric statistical structuring of knowledge systems using binary feature matches

    DEFF Research Database (Denmark)

    Mørup, Morten; Glückstad, Fumiko Kano; Herlau, Tue;

    2014-01-01

    matches and structure the data into groups at the level in which they have statistical support. The model naturally extends to structuring and aligning an arbitrary number of systems. We analyze three datasets on educational concepts and their features and demonstrate how the proposed model can both be...... statistical support and how this approach generalizes to the structuring and alignment of knowledge systems. We propose a non-parametric Bayesian generative model for structuring binary feature data that does not depend on a specific choice of similarity measure. We jointly model all combinations of binary...... used to structure each system separately or to jointly align two or more systems. The proposed method forms a promising new framework for the statistical modeling and alignment of structure across an arbitrary number of systems....

  7. Anomalous equivalent potential temperature: an atmospheric feature predicting days with higher risk for fatal outcome in acute ischemic stroke-a preliminary study.

    Science.gov (United States)

    Folyovich, András; Biczó, Dávid; Al-Muhanna, Nadim; Béres-Molnár, Anna K; Fejős, Ádám; Pintér, Ádám; Bereczki, Dániel; Fischer, Antal; Vadasdi, Károly; Pintér, Ferenc

    2015-09-01

    Acute stroke is a life-threatening condition. Fatal outcome is related to risk factors, some of these affected by climatic changes. Forecasting potentially harmful atmospheric processes may therefore be of practical importance in the acute care of stroke patients. We analyzed the history of all patients with acute ischemic stroke (N = 184) confirmed by neuroimaging including those who died (N = 35, 15 males) at our hospital department in the winter months of 2009. Patient data were anonymized, and the human meteorologists were only aware of patients' age, gender, and exact time of death. Of the meteorological parameters, equivalent potential temperature (EPT) has been chosen for analysis. EPT is generally used for forecasting thunderstorms, but in the case of synoptic scale airflow (10(6) m), it is suitable for characterizing the air mass inflowing from different regions. The behavior of measured EPT values was compared to the climatic (30 years) averages. We developed meteorological criteria for anomalous periods of EPT and tested if such periods are associated with higher rate of fatal outcome. The duration of anomalous and non-anomalous periods was nearly equal during the studied 3 months. Stroke onset distributed similarly between anomalous and non-anomalous days; however, of the 35 deaths, 27 occurred during anomalous periods: on average, 0.56 deaths occurred on anomalous days and 0.19 on non-anomalous days. Winter periods meeting the criteria of anomalous EPT may have a significant adverse human-meteorological impact on the outcome in acute ischemic stroke. PMID:26233665

  8. Anomalous Magnetohydrodynamics

    OpenAIRE

    Giovannini, Massimo

    2013-01-01

    Anomalous symmetries induce currents which can be parallel rather than orthogonal to the hypermagnetic field. Building on the analogy with charged liquids at high magnetic Reynolds numbers, the persistence of anomalous currents is scrutinized for parametrically large conductivities when the plasma approximation is accurate. Different examples in globally neutral systems suggest that the magnetic configurations minimizing the energy density with the constraint that the helicity be conserved co...

  9. FeatureMap3D - a tool to map protein features and sequence conservation onto homologous structures in the PDB

    DEFF Research Database (Denmark)

    Wernersson, Rasmus; Rapacki, Krzysztof; Stærfeldt, Hans Henrik;

    2006-01-01

    FeatureMap3D is a web-based tool that maps protein features onto 3D structures. The user provides sequences annotated with any feature of interest, such as post-translational modifications, protease cleavage sites or exonic structure and FeatureMap3D will then search the Protein Data Bank (PDB) for...

  10. Predicting protein function from structure: Unique structural features of proteases

    OpenAIRE

    Stawiski, Eric W.; Baucom, Albion E.; Lohr, Scott C.; Gregoret, Lydia M.

    2000-01-01

    We have noted consistent structural similarities among unrelated proteases. In comparison with other proteins of similar size, proteases have smaller than average surface areas, smaller radii of gyration, and higher Cα densities. These findings imply that proteases are, as a group, more tightly packed than other proteins. There are also notable differences in secondary structure content between these two groups of proteins: proteases have fewer helices and more loops. We speculate that both h...

  11. Understanding Structural Features of Microbial Lipases—An Overview

    Directory of Open Access Journals (Sweden)

    Satoru Takeuchi

    2008-01-01

    Full Text Available The structural elucidations of microbial lipases have been of prime interest since the 1980s. Knowledge of structural features plays an important role in designing and engineering lipases for specific purposes. Significant structural data have been presented for few microbial lipases, while, there is still a structure-deficit, that is, most lipase structures are yet to be resolved. A search for ‘lipase structure’ in the RCSB Protein Data Bank (http://www.rcsb.org/pdb/ returns only 93 hits (as of September 2007 and, the NCBI database (http://www.ncbi.nlm.nih.gov reports 89 lipase structures as compared to 14719 core nucleotide records. It is therefore worthwhile to consider investigations on the structural analysis of microbial lipases. This review is intended to provide a collection of resources on the instrumental, chemical and bioinformatics approaches for structure analyses. X-ray crystallography is a versatile tool for the structural biochemists and is been exploited till today. The chemical methods of recent interests include molecular modeling and combinatorial designs. Bioinformatics has surged striking interests in protein structural analysis with the advent of innumerable tools. Furthermore, a literature platform of the structural elucidations so far investigated has been presented with detailed descriptions as applicable to microbial lipases. A case study of Candida rugosa lipase (CRL has also been discussed which highlights important structural features also common to most lipases. A general profi le of lipase has been vividly described with an overview of lipase research reviewed in the past.

  12. Quantifying sequence and structural features of protein-RNA interactions.

    Science.gov (United States)

    Li, Songling; Yamashita, Kazuo; Amada, Karlou Mar; Standley, Daron M

    2014-09-01

    Increasing awareness of the importance of protein-RNA interactions has motivated many approaches to predict residue-level RNA binding sites in proteins based on sequence or structural characteristics. Sequence-based predictors are usually high in sensitivity but low in specificity; conversely structure-based predictors tend to have high specificity, but lower sensitivity. Here we quantified the contribution of both sequence- and structure-based features as indicators of RNA-binding propensity using a machine-learning approach. In order to capture structural information for proteins without a known structure, we used homology modeling to extract the relevant structural features. Several novel and modified features enhanced the accuracy of residue-level RNA-binding propensity beyond what has been reported previously, including by meta-prediction servers. These features include: hidden Markov model-based evolutionary conservation, surface deformations based on the Laplacian norm formalism, and relative solvent accessibility partitioned into backbone and side chain contributions. We constructed a web server called aaRNA that implements the proposed method and demonstrate its use in identifying putative RNA binding sites. PMID:25063293

  13. The Structure and Rainfall Features of Tropical Cyclone Rammasun (2002)

    Institute of Scientific and Technical Information of China (English)

    马雷鸣; 端义宏; 朱永褆

    2004-01-01

    Tropical Rainfall Measuring Mission (TRMM) data [TRMM Microwave Imager/Precipitation Radar/Visible and Infrared Scanner (TMI/PR/VIRS)] and a numerical model are used to investigate the structure and rainfall features of Tropical Cyclone (TC) Rammasun (2002). Based on the analysis of TRMM data, which are diagnosed together with NCEP/AVN [Aviation (global model)] analysis data,some typical features of TC structure and rainfall are preliminary discovered. Since the limitations of TRMM data are considered for their time resolution and coverage, the world observed by TRMM at several moments cannot be taken as the representation of the whole period of the TC lifecycle, therefore the picture should be reproduced by a numerical model of high quality. To better understand the structure and rainfall features of TC Rammasun, a numerical simulation is carried out with mesoscale model MM5in which the validations have been made with the data of TRMM and NCEP/AVN analysis.

  14. The quantum anomalous Hall effect

    OpenAIRE

    LIU, CHAO-XING; Zhang, Shou-Cheng; Qi, Xiao-Liang

    2015-01-01

    The quantum anomalous Hall effect is defined as a quantized Hall effect realized in a system without external magnetic field. Quantum anomalous Hall effect is a novel manifestation of topological structure in many-electron systems, and may have potential applications in future electronic devices. In recent years, quantum anomalous Hall effect has been proposed theoretically and realized experimentally. In this review article, we provide a systematic overview of the theoretical and experimenta...

  15. Anomalous scaling of low-order structure functions of turbulent velocity

    International Nuclear Information System (INIS)

    It is now believed that the scaling exponents of moments of velocity increments are anomalous, or that the departures from Kolmogorov's (1941) self-similar scaling increase nonlinearly with the increasing order of the moment. This appears to be true whether one considers velocity increments themselves or their absolute values. However, moments of order lower than 2 of the absolute values of velocity increments have not been investigated thoroughly for anomaly. Here, we discuss the importance of the scaling of non-integer moments of order between +2 and -1, and obtain them from direct numerical simulations at moderate Taylor microscale Reynolds numbers Rλ ≤ 450, and experimental data at high Reynolds numbers (Rλ ∼ 10 000). The relative difference between the measured exponents and Kolmogorov's prediction increases as the moment order decreases towards -1, thus showing that the anomaly is manifested in low-order moments as well. (author)

  16. Absorbed films containing tetrazole on steel surface. 2. Structural features

    International Nuclear Information System (INIS)

    By the method of X-ray electron spectroscopy, AFM the mechanism of formation and structural features of the protective films containing tetrazole is investigated. Continuous film (thickness is about 80 A) of polymeric complex reinforced by Fe2O3 is formed on the steel surface by idsorbtion from corrosion-active solution. 11 refs.; 4 figs

  17. Electrophysical properties and structural features of shungite (natural nanostructured carbon)

    Science.gov (United States)

    Golubev, E. A.

    2013-05-01

    This paper presents the results of investigations of the electrical conductive properties with a nanoscale locality at nanoampere currents and the results of an analysis of the correlation between the electrical conductivity and structural features of natural glassy carbon, i.e., shungite. The investigations have been performed using atomic force microscopy, electric force spectroscopy, scanning spreading resistance microscopy, X-ray spectroscopic analysis, and Raman spectroscopy. It has been found that there are differences in electrical conductive properties of the structurally similar shungite samples formed under different PT conditions. Based on the analysis of the structural parameters and specific features of the shungite compositions, it has been shown that the effect of intercalation of impurities into boundary layers of graphene sheets has the most significant influence on the electrical and physical properties of the shungites. The differences in types and values of conductivity of the shungite samples are determined by the different degrees of intercalation.

  18. Anomalous scaling of structure functions and sub-grid models for large eddy simulations of strong turbulence

    CERN Document Server

    Yakhot, Victor

    2011-01-01

    The original goal of Large Eddy Simulations of fully developed turbulent flows was to accurately describe large-scale flow features ${\\bf u}(\\Delta)$ at the scales $r\\geq \\Delta$ where $\\Delta$ is a size of computational mesh. The effect of small-scale velocity fluctuations ($r<\\Delta$) was to be accounted for by effective transport coefficients (subgrid models) in the coarse-grained Navier-Stokes equations. It is shown in this paper that, due to anomalous inertial range scaling (intermittency) of the moments of velocity difference, the existing subgrid models are intrinsically incapable of quantitatively describing flow features at the scales $r

  19. Sequence-derived structural features driving proteolytic processing.

    Science.gov (United States)

    Belushkin, Alexander A; Vinogradov, Dmitry V; Gelfand, Mikhail S; Osterman, Andrei L; Cieplak, Piotr; Kazanov, Marat D

    2014-01-01

    Proteolytic signaling, or regulated proteolysis, is an essential part of many important pathways such as Notch, Wnt, and Hedgehog. How the structure of the cleaved substrate regions influences the efficacy of proteolytic processing remains underexplored. Here, we analyzed the relative importance in proteolysis of various structural features derived from substrate sequences using a dataset of more than 5000 experimentally verified proteolytic events captured in CutDB. Accessibility to the solvent was recognized as an essential property of a proteolytically processed polypeptide chain. Proteolytic events were found nearly uniformly distributed among three types of secondary structure, although with some enrichment in loops. Cleavages in α-helices were found to be relatively abundant in regions apparently prone to unfolding, while cleavages in β-structures tended to be located at the periphery of β-sheets. Application of the same statistical procedures to proteolytic events divided into separate sets according to the catalytic classes of proteases proved consistency of the results and confirmed that the structural mechanisms of proteolysis are universal. The estimated prediction power of sequence-derived structural features, which turned out to be sufficiently high, presents a rationale for their use in bioinformatic prediction of proteolytic events. PMID:24227478

  20. Anomalous structural disorder and distortion in metal-to-insulator-transition Ti{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, In-Hui; Jin, Zhenlan; Park, Chang-In; Han, Sang-Wook, E-mail: shan@jbnu.ac.kr [Department of Physics Education and Institute of Fusion Science, Jeonbuk(Chonbuk) National University, Jeonju 561-756 (Korea, Republic of); Jiang, Bingzhi [Department of Physics, Yanbian University, Yanji 133002 (China)

    2016-01-07

    Mott proposed that impurity bands in corundum-symmetry Ti{sub 2}O{sub 3} at high temperatures caused a collapse in the bandgap. However, the origin of the impurity bands has not yet been clarified. We examine the local structural properties of metal-to-insulator-transition Ti{sub 2}O{sub 3} using in-situ x-ray absorption fine structure (XAFS) measurements at the Ti K edge in the temperature range from 288 to 739 K. The Ti{sub 2}O{sub 3} powder is synthesized by using a chemical reaction method. X-ray diffraction (XRD) measurements from Ti{sub 2}O{sub 3} with a Rietveld refinement demonstrate a single-phased R-3c symmetry without additional distortion. Extended-XAFS combined with XRD reveals a zigzag patterned Ti position and an anomalous structural disorder in Ti-Ti pairs, accompanied by a bond length expansion of the Ti-Ti pairs along the c-axis for T > 450 K. The local structural distortion and disorder of the Ti atoms would induce impurity levels in the band gap between the Ti 3d a{sub 1g} and e{sub g}{sup π} bands, resulting in a collapse of the band gap for T > 450 K.

  1. Influence of structural features on portuguese toddler child care quality

    OpenAIRE

    Manuela Pessanha; Cecília Aguiar; Joaquim Bairrão

    2007-01-01

    Whereas child care quality has been extensively studied in the U.S., there is much less information about the quality of child care in other countries.With one of the highest maternal employment rates in Europe, it is important to examine child care in Portugal. Thirty toddler classrooms in child care centers were observed. The purpose of this studywas to determine whether structural features account for overall toddler child care quality. Results showed younger and better-paid teach...

  2. Structural and morphological features of Piaractus mesopotamicus (Holmberg, 1887 gills

    Directory of Open Access Journals (Sweden)

    SEVERI W.

    2000-01-01

    Full Text Available The pacu Piaractus mesopotamicus (Holmberg, 1887, is a commercially important serrasalmid fish endemic to the Paraná-Paraguay River basin, and one of the most widely cultivated native fish species in the Neotropics. As a migratory species, also inhabiting temporary pools subjected to hypoxic conditions, the species presents a high plasticity concerning respiratory adaptations. In order to supplement basic knowledge on the respiratory physiology and morphology of this species, some structural features of pacu gills, such as filament and lamellae structure, and circulatory pattern are described in this paper.

  3. The structure of the rare-earth phosphate glass (Sm2O3)0.205(P2O5)0.795 studied by anomalous dispersion neutron diffraction

    International Nuclear Information System (INIS)

    The role of the Sm3+ ions in the structure of vitreous Sm2O3·4P2O5 has been investigated using the neutron diffraction anomalous dispersion technique, which employs the wavelength dependence of the real and imaginary parts of the neutron scattering length close to an absorption resonance. The data described here represent the first successful complete neutron anomalous dispersion study on an amorphous material. This experimental methodology permits one to determine exclusively the closest Sm-Sm separation. Knowledge of the R - R (R = rare-earth) pairwise correlation is key to understanding the optical and magnetic properties of rare-earth phosphate glasses. The anomalous difference correlation function, ΔT''(r), shows a dominant feature pertaining to a Sm - Sm separation, centred at 4.8 A. The substantial width and marked asymmetry of this peak indicates that the minimum approach of Sm3+ ions could be as close as 4 A. Information on other pairwise correlations is also revealed via analysis of T(r) and ΔT(r) correlation functions: Sm3+ ions display an average co-ordination number, nSm(O), of 7, with a mean Sm-O bond length of 2.375(5) A whilst the PO4 tetrahedra have a mean P-O bond length of 1.538(2) A. Second- and third-neighbour correlations are also identified. These results corroborate previous findings. Such consistency lends support to the application of the anomalous dispersion technique to determine Sm - Sm separations

  4. Feature and Statistical Model Development in Structural Health Monitoring

    Science.gov (United States)

    Kim, Inho

    All structures suffer wear and tear because of impact, excessive load, fatigue, corrosion, etc. in addition to inherent defects during their manufacturing processes and their exposure to various environmental effects. These structural degradations are often imperceptible, but they can severely affect the structural performance of a component, thereby severely decreasing its service life. Although previous studies of Structural Health Monitoring (SHM) have revealed extensive prior knowledge on the parts of SHM processes, such as the operational evaluation, data processing, and feature extraction, few studies have been conducted from a systematical perspective, the statistical model development. The first part of this dissertation, the characteristics of inverse scattering problems, such as ill-posedness and nonlinearity, reviews ultrasonic guided wave-based structural health monitoring problems. The distinctive features and the selection of the domain analysis are investigated by analytically searching the conditions of the uniqueness solutions for ill-posedness and are validated experimentally. Based on the distinctive features, a novel wave packet tracing (WPT) method for damage localization and size quantification is presented. This method involves creating time-space representations of the guided Lamb waves (GLWs), collected at a series of locations, with a spatially dense distribution along paths at pre-selected angles with respect to the direction, normal to the direction of wave propagation. The fringe patterns due to wave dispersion, which depends on the phase velocity, are selected as the primary features that carry information, regarding the wave propagation and scattering. The following part of this dissertation presents a novel damage-localization framework, using a fully automated process. In order to construct the statistical model for autonomous damage localization deep-learning techniques, such as restricted Boltzmann machine and deep belief network

  5. Systematic Limitations in Concentration Analysis via Anomalous Small-Angle X-ray Scattering in the Small Structure Limit

    Directory of Open Access Journals (Sweden)

    Guenter Goerigk

    2016-03-01

    Full Text Available Anomalous small angle scattering measurements have been applied to diluted solutions of anionic polyacrylates decorated by specifically-interacting Pb2+ cations, revealing partial collapse of the polyacrylate into pearl-like subdomains with a size on the order of a few nanometers. From the pure-resonant scattering contribution of the Pb2+ cations, and from subsequent analysis of the resonant-invariant, the amount of Pb2+ cations condensed onto the polyanions with respect to the total amount of Pb2+ cations in the solvent was estimated. In order to scrutinize systematic limitations in the determination of the chemical concentrations of resonant scattering counterions in the collapsed phase, Monte Carlo simulations have been performed. The simulations are based on structural confinements at variable size in the range of few nanometers, which represent the collapsed subdomains in the polyanions. These confinements were gradually filled to a high degree of the volume fraction with resonant scattering counterions giving access to a resonant-invariant at a variable degree of filling. The simulations revealed in the limit of small structures a significant underestimation of the true degree of filling of the collapsed subdomains when determining chemical concentrations of Pb2+ cations from the resonant invariant.

  6. Revisiting the structural features of arabinoxylans from brewers' spent grain.

    Science.gov (United States)

    Coelho, Elisabete; Rocha, M Angélica M; Moreira, Ana S P; Domingues, M Rosário M; Coimbra, Manuel A

    2016-03-30

    The brewers' spent grain (BSG) arabinoxylans (AX) have been described to be composed by a backbone of (β1→4)-linked xylose residues containing only single units of arabinose as side chains. However, this is not in accordance with the structural features of AX from other cereal sources. Aiming to disclose the possibility of additional structural details, fractions enriched in AX were obtained by sequential extraction from BSG. The AX richest fraction was hydrolysed with xylanase, fractioned by size-exclusion chromatography, and analysed by electrospray tandem mass spectrometry (ESI-MS(n)). Methylation analysis showed that the amount of terminally linked arabinose residues was not in accordance with the number of xylose branching points. This was due to the presence of O-acetyl, hexose, hexuronic acid, and methylated uronic acid residues. AXs presenting these structural features can be a potential source of a large screening prebiotic, providing, in the same molecule, areas of fast and slow probiotic fermentation rates. PMID:26794960

  7. Clinical features and long-term prognosis of patients with anomalous origin of the left coronary artery from the pulmonary artery

    Institute of Scientific and Technical Information of China (English)

    ZHENG Jian-yong; ZHAO Qu-ming; HAN Ling; DING Wen-hong; JIN Mei; ZHANG Gui-zhen; XIAO Yan-yan; LUO Yi; CHENG Pei; MENG Xu

    2010-01-01

    Background Anomalous origin of the left coronary artery from the pulmonary artery (ALCAPA) is a rare congenital heart anomaly. We aimed to illustrate the clinical features and long-term prognosis of patients with ALCAPA.Methods Twenty three patients (13 males and 10 females, ages ranging from 2.5 months to 65 years) identified as ALCAPA in Beijing Anzhen Hospital from April 1984 to June 2009 were divided into two groups, based on the age of onset: group 1 (≤12 months, n=16) and group 2 (>12 months, n=7).Results Fifty six point three percent of patients in group 1 had been misdiagnosed as endocardial fibroelastosis (9/16),18.8% as dilated cardiomyopathy (3/16) and 6.3% as myocardial infarction (1/16). Patients in group 2 were usually diagnosed as coronary heart disease, myocarditis, or patent ductus arteriosus. Electrocardiography in group 1 revealed abnormal Q waves with T wave inversion in leads I, avL, V4-V6, especially in lead avL (deep and wide Q wave); but no specific manifestations in group 2. A higher percentage of patients in group 1 had cardiomegaly on chest radiograph (86.7% vs. 33.3%, P=0.031), while pulmonary artery protrusion was more common in group 2 (26.7% vs. 83.3%,P=0.046). Lower left ventricular ejection fraction (LVEF) was present in group 1 than in group 2 ((48.5±11.5)% vs.(65.0±6.1)%, P <0.001). Apical ventricular aneurysm (62.5% vs. 0%, P=0.007), enhanced echogenicity of papillary muscles (87.5% vs. 28.6%, P=0.011) and endocardial thickening (93.8% vs. 14.3%, P <0.001) were more frequent in group 1 than in group 2. The ratio of the proximal right coronary artery (RCA) diameter to the aortic root diameter exceeded 0.14 in all cases, more prominent in group 2 (0.26±0.05 vs. 0.33±0.03, P=0.009). Increased coronary artery collaterals within the interventricular septum were detected in 18 patients (78.3%) by Doppler imaging. Twenty one patients underwent cardiac surgery, including left coronary artery (LCA) ligation (1/21), LCA

  8. Anomalous structural behavior of the superconducting compound La/sub 1.85/Ba/sub 0.15/CuO4

    International Nuclear Information System (INIS)

    High-resolution neutron powder diffraction experiments on the superconducting compound La/sub 1.85/Ba/sub 0.15/CuO4 have revealed the presence of a tetragonal to orthorhombic phase transition at 180 K, together with subtle, anomalous structural instabilities at lower temperatures. These experiments demonstrate a correlation between the structural anomalies and changes in the electrical resistivity

  9. Random projections based feature-specific structured imaging.

    Science.gov (United States)

    Baheti, Pawan K; Neifeld, Mark A

    2008-02-01

    We present a feature-specific imaging system based on the use of structured illumination. The measurements are defined as inner products between the illumination patterns and the object reflectance function, measured on a single photodetector. The illumination patterns are defined using random binary patterns and thus do not employ prior knowledge about the object. Object estimates are generated using L(1)-norm minimization and gradient-projection sparse reconstruction algorithms. The experimental reconstructions show the feasibility of the proposed approach by using 42% fewer measurements than the object dimensionality. PMID:18542256

  10. Structural and surface features of multiwall carbon nanotube

    Energy Technology Data Exchange (ETDEWEB)

    Hembram, K.P.S.S., E-mail: hembram@isu.iisc.ernet.in [Department of Instrumentation, Indian Institute of Science, Bangalore, 560012 (India); Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560064 (India); Rao, G. Mohan [Department of Instrumentation, Indian Institute of Science, Bangalore, 560012 (India)

    2011-04-15

    We present the direct evidence of defective and disorder places on the surface of multiwall carbon nanotube (MWCNT), visualizing the presence of amorphous carbon at those sites. These defective surfaces being higher in energy are the key features of functionalization with different materials. The interaction of the {pi} orbital electrons of different carbon atoms of adjacent layers is more at the bent portion, than that of regular portion of the CNT. Hence the tubular structure of the bent portion of nanotubes is spaced more than that of regular portion of the nanotubes, minimizing the stress.

  11. Structural and surface features of multiwall carbon nanotube

    Science.gov (United States)

    Hembram, K. P. S. S.; Rao, G. Mohan

    2011-04-01

    We present the direct evidence of defective and disorder places on the surface of multiwall carbon nanotube (MWCNT), visualizing the presence of amorphous carbon at those sites. These defective surfaces being higher in energy are the key features of functionalization with different materials. The interaction of the π orbital electrons of different carbon atoms of adjacent layers is more at the bent portion, than that of regular portion of the CNT. Hence the tubular structure of the bent portion of nanotubes is spaced more than that of regular portion of the nanotubes, minimizing the stress.

  12. Anomalous behavior of the structural relaxation dispersion function of a carborane-containing siloxane

    Energy Technology Data Exchange (ETDEWEB)

    Pawlus, Sebastian; Paluch, Marian; Ziolo, Jerzy [Institute of Physics, University of Silesia, Uniwersytecka 4, Katowice 40-007 (Poland); Kolel-Veetil, Manoj K [Chemistry Division, Code 6127, Naval Research Laboratory, Washington, DC 20375-5342 (United States)

    2010-10-20

    Broadband dielectric spectroscopic investigations of a vinyl-terminated carboranylenesiloxane, VCS, were performed at ambient and elevated pressures. At a constant structural relaxation time, results show that the structural relaxation dispersion function of VCS narrows with both increasing pressure and temperature. This narrowing is substantial in the case of pressurization and, consequently, the breakdown of the temperature-pressure superposition rule is observed. The interpretation of this breakdown is presented.

  13. Structural features of the ribonucleotide reductase of Aujeszky's disease virus.

    Science.gov (United States)

    Kaliman, A V; Boldogköi, Z; Fodor, I

    1994-01-01

    A gene construct of the Aujeszky's disease virus (ADV) genome was prepared and the DNA fragment encoding the ribonucleotide reductase was structurally characterized. We determined the entire DNA sequence of two adjacent open reading frames of the ribonucleotide reductase genes with the intergenic sequence of nine base pairs. From the sequence analysis we predict that Aujeszky's disease virus encodes a ribonucleotide reductase which comprises two polypeptides--large and small subunits, with sizes of 835 and 303 amino acids, respectively. Nucleotide and amino acid sequences of the large and small subunits of the Aujeszky's disease virus ribonucleotide reductase have been compared with that of other herpesviruses, and structural features of both proteins have been characterized. PMID:7810419

  14. Chemical and structural features influencing the biological activity of curcumin.

    Science.gov (United States)

    Priyadarsini, K Indira

    2013-01-01

    Curcumin, a polyphenolic natural product, exhibits therapeutic activity against a number of diseases, attributed mainly to its chemical structure and unique physical, chemical, and biological properties. It is a diferuloyl methane molecule [1,7-bis (4-hydroxy-3- methoxyphenyl)-1,6-heptadiene-3,5-dione)] containing two ferulic acid residues joined by a methylene bridge. It has three important functionalities: an aromatic o-methoxy phenolic group, α, β-unsaturated β-diketo moiety and a seven carbon linker. Extensive research in the last two decades has provided evidence for the role of these different functional groups in its crucial biological activities. A few highlights of chemical structural features associated with the biological activity of curcumin are: The o-methoxyphenol group and methylenic hydrogen are responsible for the antioxidant activity of curcumin, and curcumin donates an electron/ hydrogen atom to reactive oxygen species. Curcumin interacts with a number of biomolecules through non-covalent and covalent binding. The hydrogen bonding and hydrophobicity of curcumin, arising from the aromatic and tautomeric structures along with the flexibility of the linker group are responsible for the non-covalent interactions. The α, β-unsaturated β-diketone moiety covalently interacts with protein thiols, through Michael reaction. The β-diketo group forms chelates with transition metals, there by reducing the metal induced toxicity and some of the metal complexes exhibit improved antioxidant activity as enzyme mimics. New analogues with improved activity are being developed with modifications on specific functional groups of curcumin. The physico-chemical and structural features associated with some of the biological activities of curcumin and important analogues are summarized in this article. PMID:23116315

  15. Pedestrian Detection with Spatially Pooled Features and Structured Ensemble Learning.

    Science.gov (United States)

    Paisitkriangkrai, Sakrapee; Shen, Chunhua; Hengel, Anton van den

    2016-06-01

    Many typical applications of object detection operate within a prescribed false-positive range. In this situation the performance of a detector should be assessed on the basis of the area under the ROC curve over that range, rather than over the full curve, as the performance outside the prescribed range is irrelevant. This measure is labelled as the partial area under the ROC curve (pAUC). We propose a novel ensemble learning method which achieves a maximal detection rate at a user-defined range of false positive rates by directly optimizing the partial AUC using structured learning. In addition, in order to achieve high object detection performance, we propose a new approach to extracting low-level visual features based on spatial pooling. Incorporating spatial pooling improves the translational invariance and thus the robustness of the detection process. Experimental results on both synthetic and real-world data sets demonstrate the effectiveness of our approach, and we show that it is possible to train state-of-the-art pedestrian detectors using the proposed structured ensemble learning method with spatially pooled features. The result is the current best reported performance on the Caltech-USA pedestrian detection dataset. PMID:26336118

  16. Anomalous Development of Brain Structure and Function in Spina Bifida Myelomeningocele

    Science.gov (United States)

    Juranek, Jenifer; Salman, Michael S.

    2010-01-01

    Spina bifida myelomeningocele (SBM) is a specific type of neural tube defect whereby the open neural tube at the level of the spinal cord alters brain development during early stages of gestation. Some structural anomalies are virtually unique to individuals with SBM, including a complex pattern of cerebellar dysplasia known as the Chiari II…

  17. Theory of anomalous resistivity associated with structural phase transitions in IV-VI compounds

    Science.gov (United States)

    Katayama, S.; Mills, D. L.

    1980-07-01

    A theoretical description of electrical-resistivity anomalies associated with structural phase transitions of IV-VI compound semiconductors is presented, taking account of interband electron-soft-TO-phonon scattering. The sublattice displacement and rhombohedral strain in the low-temperature phase are calculated within the framework of a self-consistent mean-field theory, with emphasis on the effect of electron-phonon couplings. The resistivity due to the scattering of free carriers from acoustic phonons and optic phonons is examined, including the carrier transfer among the four valleys due to valley splitting below the transition temperature (Tc). The theoretical calculations of electrical resistivity as well as order parameters are in good accord with data on p-type SnTe at the quantitative level.

  18. Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid

    CERN Document Server

    Gramotnev, D K; Nieminen, T A; Gramotnev, Dmitri K.; Mather, Melissa L.; Nieminen, Timo A.

    2003-01-01

    It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface.

  19. Anomalous magnetic hyperfine structure of the 229Th ground-state doublet in muonic atoms

    Science.gov (United States)

    Tkalya, E. V.

    2016-07-01

    The magnetic hyperfine (MHF) splitting of the ground and low-energy 3 /2+(7.8 ±0.5 eV) levels in the 229Th nucleus in the muonic atom (μ1S1 /2 -229Th) * is calculated considering the distribution of the nuclear magnetization in the framework of the collective nuclear model with wave functions of the Nilsson model for the unpaired neutron. It is shown that (a) deviation of the MHF structure of the isomeric state exceeds 100% from its value for a pointlike nuclear magnetic dipole (the order of sublevels is reversed); (b) partial inversion of levels of the 229Th ground-state doublet and spontaneous decay of the ground state to the isomeric state occur; (c) the E 0 transition, which is sensitive to differences in the mean-square charge radii of the doublet states, is possible between mixed sublevels with F =2 ; and (d) MHF splitting of the 3 /2+ isomeric state may be in the optical range for certain values of the intrinsic gK factor and a reduced probability of a nuclear transition between the isomeric and the ground states.

  20. The sequence, structure and evolutionary features of HOTAIR in mammals

    Directory of Open Access Journals (Sweden)

    Zhu Hao

    2011-04-01

    the full HOTAIR in mammals. Conclusions HOTAIR exists in mammals, has poorly conserved sequences and considerably conserved structures, and has evolved faster than nearby HoxC genes. Exons of HOTAIR show distinct evolutionary features, and a 239 bp domain in the 1804 bp exon6 is especially conserved. These features, together with the absence of some exons and sequences in mouse, rat and kangaroo, suggest ab initio generation of HOTAIR in marsupials. Structure prediction identifies two fragments in the 5' end exon1 and the 3' end domain B of exon6, with sequence and structure invariably occurring in various predicted structures of exon1, the domain B of exon6 and the full HOTAIR.

  1. Features of deformation of poroelastic media with low structural strength

    Science.gov (United States)

    Goldstein, Robert; Gordeev, Yurii; Kornev, Konstantin

    Many natural and technological processes are associated with deformation and fracture of saturated or being saturated poroelastic media. Among such processes one can mention fluid soaking through a dam, fluid inflow to the cracks of hydraulic fracture, polishing using porous materials and special fluids, flow in catalytic pellets. All these processes are accompanied by deformation and fracture of a matrix with fluid flow. The effects at the interface porous body-fluid are essential for the processes. The specific features of deformation of poroelastic media with low structural strength are considered in this paper. The compressibility of the matrix skeleton is larger as compared to the compressibility of the saturating fluid in such media. It is shown that the oozing of the fluid at the surface of the poroelastic medium occurs in the consolidated flow regime under the action of `fluid piston' like loads if the structural strength of the medium is low. This result is obtained for both plane (deformation of a layer or halfinfinite medium) and centrally symmetric (deformation of a sphere) problems.

  2. Structure of continental rifts: Role of older features and magmatism

    Energy Technology Data Exchange (ETDEWEB)

    Keller, G.R. [Univ. of Texas, El Paso, TX (United States)

    1996-12-31

    Recent geological and geophysical studies in several continental rifts have begun to shed light on the details of the processes which govern the structural evolution of these important exploration targets. In Kenya and Tanzania, the classic East African rift has been the object of several investigations which reveal that its location follows the boundary (suture ?) between the Tanzanian craton (Archean) and Mozambiquan belt (Proterozoic), The Baikal rift also follows a similar boundary, and the Mid-continent rift of North America appears to do the same. Rifts themselves often act as zones of weakness which are reactivated by younger tectonic regimes. The classic North American example of this effect is the Eocambrian Southern Oklahoma aulacogen which was deformed to create the Anadarko basin and Wichita uplift in the late Paleozoic. The Central basin platform has a similar history although the original rift formed at {approximately}1,100Ma. Integration of geophysical data with petrologic and geochemical data from several rift zones has also provided a new picture of the nature and extent of magmatic modification of the crust. An interesting contradiction is that Phanerozoic rifts, except the Afar region, show little evidence for major magmatic modification of the crust whereas, at least in North America, many Precambrian rifts are associated with very large mafic bodies in the crust. The Kenya rift displays evidence for modification of the lower crust in a two-phase magmatic history, but upper crustal magmatic features are limited to local intrusions associated with volcanoes. In this rift, complex basement structure plays a much more important role than previously realized, and the geophysical signatures of basement structure and magmatism are easy to confuse. If this is also the case in other rifts, additional rift basins remain to be discovered.

  3. Structure of continental rifts: Role of older features and magmatism

    Energy Technology Data Exchange (ETDEWEB)

    Keller, G.R. (Univ. of Texas, El Paso, TX (United States))

    1996-01-01

    Recent geological and geophysical studies in several continental rifts have begun to shed light on the details of the processes which govern the structural evolution of these important exploration targets. In Kenya and Tanzania, the classic East African rift has been the object of several investigations which reveal that its location follows the boundary (suture ) between the Tanzanian craton (Archean) and Mozambiquan belt (Proterozoic), The Baikal rift also follows a similar boundary, and the Mid-continent rift of North America appears to do the same. Rifts themselves often act as zones of weakness which are reactivated by younger tectonic regimes. The classic North American example of this effect is the Eocambrian Southern Oklahoma aulacogen which was deformed to create the Anadarko basin and Wichita uplift in the late Paleozoic. The Central basin platform has a similar history although the original rift formed at [approximately]1,100Ma. Integration of geophysical data with petrologic and geochemical data from several rift zones has also provided a new picture of the nature and extent of magmatic modification of the crust. An interesting contradiction is that Phanerozoic rifts, except the Afar region, show little evidence for major magmatic modification of the crust whereas, at least in North America, many Precambrian rifts are associated with very large mafic bodies in the crust. The Kenya rift displays evidence for modification of the lower crust in a two-phase magmatic history, but upper crustal magmatic features are limited to local intrusions associated with volcanoes. In this rift, complex basement structure plays a much more important role than previously realized, and the geophysical signatures of basement structure and magmatism are easy to confuse. If this is also the case in other rifts, additional rift basins remain to be discovered.

  4. Geologic structural features within the Kaiparowits Plateau study area, southern Utah (kaistrcg)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This is a line coverage of the geologic structural features within the Kaiparowits Plateau. Structural features include synclines, anticlines, folds and faults; and...

  5. Anomalous current structure in the eastern equatorial Indian Indian Ocean during the south-west monsoon of 1994

    Digital Repository Service at National Institute of Oceanography (India)

    Unnikrishnan, A.S.; Murty, V.S.N.; Babu, M.T.; Gopinathan, C.K.; Charyulu, R.J.K.

    . This undercurrent has a transport of 4 Sv at 80 degrees E. The westward flow in the upper layers north of he equator is anomalous, as the surface winds have an eastward zonal component. The associated westward transport is 44 Sv between 84 degrees and 88 degrees E...

  6. Structural features of DNA interaction with caffeine and theophylline

    Science.gov (United States)

    Nafisi, Shohreh; Manouchehri, Firouzeh; Tajmir-Riahi, Heidar-Ali; Varavipour, Maryam

    2008-03-01

    Caffeine and theophylline are strong antioxidants that prevent DNA damage. The anticancer and antiviral activities of these natural products are implicated in their mechanism of actions. However, there has been no information on the interactions of these xanthine derivatives with individual DNA at molecular level. The aim of this study was to examine the stability and structural features of calf-thymus DNA complexes with caffeine and theophylline in aqueous solution, using constant DNA concentration (6.25 mM) and various caffeine or theophylline/DNA(P) ratios of 1/80, 1/40, 1/20, 1/10, 1/5, 1/2 and 1/1. FTIR, UV-visible spectroscopic methods were used to determine the ligand external binding modes, the binding constant and the stability of caffeine, theophylline-DNA complexes in aqueous solution. Spectroscopic evidence showed that the complexation of caffeine and theophylline with DNA occurred via G-C and A-T and PO 2 group with overall binding constants of K(caffeine-DNA) = 9.7 × 10 3 M -1 and K(theophylline-DNA) = 1.7 × 10 4 M -1. The affinity of ligand-DNA binding is in the order of theophylline > caffeine. A partial B to A-DNA transition occurs upon caffeine and theophylline complexation.

  7. Structure in galactic soft X-ray features

    International Nuclear Information System (INIS)

    Observations are described of the soft X-ray background in a part of the northern hemisphere in the energy range 0.06 - 3.0 keV. The X-ray instruments, placed onboard a sounding rocket, are a one-dimensional focusing collector with multi-cell proportional counters in the focal plane and eight large area counters on deployable panels. A description of the instruments and their preflight calibration is given. Precautions were taken to prevent UV sensitivity of the X-ray instruments. The observation program, which consisted of a number of pre-programmed slow scans, is outlined. The spectral date on the soft X-ray background in these and previous observations showed that at least two components of different temperature are present. A low temperature component of approximately (3-10)x105 is found all over the sky. Components of higher temperature approximately 3x106 K are found in regions of soft X-ray enhancement; The North Polar Spur has been observed in two scans at the galactic latitude b=250 and b=750. The X-ray ridge structure is found to be strongly energy dependent. The low energy data (0 reveals two separate emission features on the ridge, both probably of finite extensions (approximately equal to 00.5). A wider X-ray ridge (approximately equal to 100) is observed above 0.4 keV. (Auth.)

  8. The Chemically-Specific Structure of an Amorphous Molybdenum Germanium Alloy by Anomalous X-ray Scattering

    International Nuclear Information System (INIS)

    Since its inception in the late 1970s, anomalous x-ray scattering (AXS) has been employed for chemically-specific structure determination in a wide variety of noncrystalline materials. These studies have successfully produced differential distribution functions (DDFs) which provide information about the compositionally-averaged environment of a specific atomic species in the sample. Despite the wide success in obtaining DDFs, there are very few examples of successful extraction of the fully chemically-specific partial pair distribution functions (PPDFs), the most detailed description of an amorphous sample possible by x-ray scattering. Extracting the PPDFs is notoriously difficult since the matrix equation involved is ill-conditioned and thus extremely sensitive to errors present in the experimental quantities that enter the equation. Instead of addressing this sensitivity by modifying the data through mathematical methods, sources of error have been removed experimentally: A focusing analyzer crystal was combined with a position-sensitive linear detector to experimentally eliminate unwanted inelastic scattering intensity over most of the reciprocal space range probed. This instrumentation has been used in data collection for the extraction of PPDFs from amorphous (a)-MoGe3. This composition arises as a phase separation endpoint in the Ge-rich region of the vapor-deposited Mo-Ge amorphous alloy system but is not present at equilibrium. Since the first Ge-rich compound in the Mo-Ge equilibrium system is MoGe2, previous workers have speculated that perhaps a unique MoGe3 compound exists in the amorphous system. Rather than indicating a distinct MoGe3 compound with definitive local structure, however, the coordination results are more consistent with a densely-packed alloy having a wide range of solid solubility. Significant improvement in the quality and reliability of experimental PPDFs from a-MoGe3 by AXS has been achieved solely through the experimental

  9. A combination of anomalous x-ray scattering and neutron diffraction for structural characterizations of Zr63Ni25Al12 metallic glass

    International Nuclear Information System (INIS)

    Zr63Ni25Al12 bulk metallic glass was investigated using neutron diffraction and anomalous x-ray scattering close to the Zr and Ni K edges. The experimental results were analyzed using reverse Monte Carlo modeling (RMC) to obtain partial structure factors and pair distribution functions. The obtained partial structural results were compared with RMC results when neutron diffraction data are not included in the analysis and the report of Zr60Ni25Al15 by Fukunaga et al. using high-energy x-ray and neutron total scattering data.

  10. The 3-loop pure singlet heavy flavor contributions to the structure function F2 (x ,Q2) and the anomalous dimension

    Science.gov (United States)

    Ablinger, J.; Behring, A.; Blümlein, J.; De Freitas, A.; von Manteuffel, A.; Schneider, C.

    2015-01-01

    The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function F2 (x, Q2) and the corresponding transition matrix element AQq(3), PS in the variable flavor number scheme are computed. In Mellin-N space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function F2 (x, Q2) are presented.

  11. The 3-loop pure singlet heavy flavor contributions to the structure function F2(x,Q2 and the anomalous dimension

    Directory of Open Access Journals (Sweden)

    J. Ablinger

    2015-01-01

    Full Text Available The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function F2(x,Q2 and the corresponding transition matrix element AQq(3,PS in the variable flavor number scheme are computed. In Mellin-N space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function F2(x,Q2 are presented.

  12. The 3-Loop Pure Singlet Heavy Flavor Contributions to the Structure Function $F_2(x,Q^2)$ and the Anomalous Dimension

    CERN Document Server

    Ablinger, J; Blümlein, J; De Freitas, A; von Manteuffel, A; Schneider, C

    2014-01-01

    The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function $F_2(x,Q^2)$ and the corresponding transition matrix element $A_{Qq}^{(3), \\sf PS}$ in the variable flavor number scheme are computed. In Mellin-$N$ space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function $F_2(x,Q^2)$ are presented.

  13. The 3-loop pure singlet heavy flavor contributions to the structure function F{sub 2}(x,Q{sup 2}) and the anomalous dimension

    Energy Technology Data Exchange (ETDEWEB)

    Ablinger, J. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Behring, A.; Blümlein, J.; De Freitas, A. [Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Manteuffel, A. von [PRISMA Cluster of Excellence, Institute of Physics, J. Gutenberg University, D-55099 Mainz (Germany); Schneider, C. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria)

    2015-01-15

    The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function F{sub 2}(x,Q{sup 2}) and the corresponding transition matrix element A{sub Qq}{sup (3),PS} in the variable flavor number scheme are computed. In Mellin-N space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function F{sub 2}(x,Q{sup 2}) are presented.

  14. The 3-loop pure singlet heavy flavor contributions to the structure function F{sub 2}(x,Q{sup 2}) and the anomalous dimension

    Energy Technology Data Exchange (ETDEWEB)

    Ablinger, J.; Schneider, C. [Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation; Behring, A.; Bluemlein, J.; Freitas, A. de [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Manteuffel, A. von [Mainz Univ. (Germany). Inst. fuer Physik

    2014-08-15

    The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function F{sub 2}(x,Q{sup 2}) and the corresponding transition matrix element A{sup (3),PS}{sub Qq} in the variable flavor number scheme are computed. In Mellin-N space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function F{sub 2}(x,Q{sup 2}) are presented.

  15. The 3-loop pure singlet heavy flavor contributions to the structure function F2(x,Q2) and the anomalous dimension

    International Nuclear Information System (INIS)

    The pure singlet asymptotic heavy flavor corrections to 3-loop order for the deep-inelastic scattering structure function F2(x,Q2) and the corresponding transition matrix element AQq(3),PS in the variable flavor number scheme are computed. In Mellin-N space these inclusive quantities depend on generalized harmonic sums. We also recalculate the complete 3-loop pure singlet anomalous dimension for the first time. Numerical results for the Wilson coefficients, the operator matrix element and the contribution to the structure function F2(x,Q2) are presented

  16. Nonlocal Anomalous Hall Effect

    Science.gov (United States)

    Zhang, Steven S.-L.; Vignale, Giovanni

    2016-04-01

    The anomalous Hall (AH) effect is deemed to be a unique transport property of ferromagnetic metals, caused by the concerted action of spin polarization and spin-orbit coupling. Nevertheless, recent experiments have shown that the effect also occurs in a nonmagnetic metal (Pt) in contact with a magnetic insulator [yttrium iron garnet (YIG)], even when precautions are taken to ensure that there is no induced magnetization in the metal. We propose a theory of this effect based on the combined action of spin-dependent scattering from the magnetic interface and the spin-Hall effect in the bulk of the metal. At variance with previous theories, we predict the effect to be of first order in the spin-orbit coupling, just as the conventional anomalous Hall effect—the only difference being the spatial separation of the spin-orbit interaction and the magnetization. For this reason we name this effect the nonlocal anomalous Hall effect and predict that its sign will be determined by the sign of the spin-Hall angle in the metal. The AH conductivity that we calculate from our theory is in order of magnitude agreement with the measured values in Pt /YIG structures.

  17. Structure and meaning features of the root verbs in Turkish

    Directory of Open Access Journals (Sweden)

    Mehmet Gedizli

    2013-10-01

    Full Text Available Turkish is a rich language in terms of verb types and words. This research is limited to Turkish spoken in Turkey, and its verb roots. Turkish dictionary of Turkish Language Association (2011 is the main source of this study. This study was prepared by taking into account of written, audio and visual resources during the period of Turkish spoken in Turkey. From basic education to university education, this dictionary is one of the most important sources of Turkish lessons. Within this framework, the verb roots that are in the dictionary have been accepted as Turkish spoken in Turkey’s verb roots and study field were established.The number of verb roots which wasn’t encountered in any source, including Turkish language grammar books previously, were determined in this study and these verb roots were classified in terms of structure and meaning. In terms of structure, the verb roots consist of at least two sounds at most six sounds but among these verb roots three-and four-sounded ones are outnumbered. And also in terms of their meaning features single and multi meaning verb roots are determined. In addition to this, this study focuses on the mental verb roots which have also drawn attention on them by the recently done Turkish researches and emphasized on the root verbs. This study was carried out on the basis of common methods in Turkish studies, but in the objective and outcome parts the lack of Turkish course books and teaching Turkish verb roots are emphasized. Verb type words in general in all languages but in particularly in Turkish form the staff of the basic words of Turkish language. In terms of Turkish which is an agglutinative language, affixes are as important as word roots. Turkish language that is rich in affixes and roots has a productive character. Attention was taken to this aspect of Turkish with the help of verb roots All in all, the subject of this study deserves to be highlighted in many ways. Besides providing new

  18. Anomalous time structure of extensive air shower particle flows in the knee region of primary cosmic ray spectrum

    International Nuclear Information System (INIS)

    We observe the new phenomenon of anomalous prolonged time distributions of neutron intensity using the 18NM64-type neutron monitor operating together with the shower installation of the Tian-Shan mountain cosmic ray station. We observe anomalous events in the core region of extensive air showers (EAS) with the size Ne>106. The threshold of their generation coincides with the 'knee' in the energy spectrum of primary cosmic rays (about 3x1015 eV). The prolonged neutron events are accompanied by the flows of EAS electrons and γ-quanta having time distributions similar to those of the neutrons. The discovered phenomenon may be a reason to make a principal change in the usual procedure of EAS exploration. (author)

  19. Systematic Limitations in Concentration Analysis via Anomalous Small-Angle X-ray Scattering in the Small Structure Limit

    OpenAIRE

    Guenter Goerigk; Sebastian Lages; Klaus Huber

    2016-01-01

    Anomalous small angle scattering measurements have been applied to diluted solutions of anionic polyacrylates decorated by specifically-interacting Pb2+ cations, revealing partial collapse of the polyacrylate into pearl-like subdomains with a size on the order of a few nanometers. From the pure-resonant scattering contribution of the Pb2+ cations, and from subsequent analysis of the resonant-invariant, the amount of Pb2+ cations condensed onto the polyanions with respect to the total amount o...

  20. Effect of processing on structural features of anodic aluminum oxides

    Science.gov (United States)

    Erdogan, Pembe; Birol, Yucel

    2012-09-01

    Morphological features of the anodic aluminum oxide (AAO) templates fabricated by electrochemical oxidation under different processing conditions were investigated. The selection of the polishing parameters does not appear to be critical as long as the aluminum substrate is polished adequately prior to the anodization process. AAO layers with a highly ordered pore distribution are obtained after anodizing in 0.6 M oxalic acid at 20 °C under 40 V for 5 minutes suggesting that the desired pore features are attained once an oxide layer develops on the surface. While the pore features are not affected much, the thickness of the AAO template increases with increasing anodization treatment time. Pore features are better and the AAO growth rate is higher at 20 °C than at 5 °C; higher under 45 V than under 40 V; higher with 0.6 M than with 0.3 M oxalic acid.

  1. Anomalous ionic conductivity of Sc sub 2 (WO sub 4) sub 3 mediated by structural changes at high pressures and temperatures

    CERN Document Server

    Secco, R A; Imanaka, N; Adachi, G

    2002-01-01

    The ionic conductivity of Sc sub 2 (WO sub 4) sub 3 at 400 deg. C shows a normal decrease with increase in pressure up to 2.9 GPa but then increases anomalously at pressures up to 4.3 GPa. Synchrotron in situ x-ray diffraction results show that Sc sub 2 (WO sub 4) sub 3 undergoes pressure-induced amorphization at pressures coincident with the reversal in conductivity behaviour. The loss of crystal structure at high pressure may be associated with the property of negative thermal expansion in Sc sub 2 (WO sub 4) sub 3.

  2. Improving the performance of link prediction by adaptively exploiting multiple structural features of networks

    CERN Document Server

    Ma, Chuang; Zhang, Hai-Feng

    2016-01-01

    So far, many network-structure-based link prediction methods have been proposed. However, these traditional methods were proposed by highlighting one or two structural features of networks, and then use the methods to implement link prediction in different networks. In many cases, the performance is not ideal since each network has its unique underlying structural features. In this article, by analyzing different real networks, we find that the structural features of different networks are remarkably different. In particular, even in the same networks, their inner structural features are utterly different. Inspired by these facts, an \\emph{adaptive} link prediction method is proposed to incorporate multiple structural features from the perspective of combination optimization. In the model, the weight of each structural feature is \\emph{adaptively } determined by logistic regression but not be artificially given in advance. According to our experimental results, we find that the logistic regression based link ...

  3. Anomalous x-ray scattering

    International Nuclear Information System (INIS)

    The availability of tunable synchrotron radiation has made it possible systematically to perform x-ray diffraction studies in regions of anomalous scattering near absorption edges, e.g. in order to derive phase information for crystal structure determination. An overview is given of recent experimental and theoretical work and discuss the properties of the anomalous atomic scattering factor, with emphasis on threshold resonances and damping effects. The results are applied to a discussion of the very strong anomalous dispersion recently observed near the L3 edge in a cesium complex. Also given is an overview of elements and levels where similar behavior can be expected. Finally, the influence of solid state and chemical effects on the absorption edge structure is discussed. 64 references

  4. Nano-structured titanium and aluminium nitride coatings: Study by grazing incidence X-ray diffraction and X-ray absorption and anomalous diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Tuilier, M.-H., E-mail: marie-helene.tuilier@uha.fr [Universite de Haute Alsace (UHA), Laboratoire Physique et Mecanique Textile (LPMT), EA 4365 -conventionnee au CNRS, Equipe PPMR, F-68093 Mulhouse (France); Pac, M.-J. [Universite de Haute Alsace (UHA), Laboratoire Physique et Mecanique Textile (LPMT), EA 4365 - conventionnee au CNRS, Equipe PPMR, F-68093 Mulhouse (France); Anokhin, D.V. [Universite de Haute Alsace (UHA), CNRS, Institut de Science des Materiaux de Mulhouse (IS2M), LRC 7228, F-68093 Mulhouse (France); Moscow State University, Faculty of Fundamental Physical and Chemical Engineering, 119991, Moscow, GSP-1, 1-51 Leninskie Gory (Russian Federation); Ivanov, D.A. [Universite de Haute Alsace (UHA), CNRS, Institut de Science des Materiaux de Mulhouse (IS2M), LRC 7228, F-68093 Mulhouse (France); Rousselot, C. [Universite de Franche-Comte, FEMTO-ST (UMR CNRS 6174), F-25211 Montbeliard (France); Thiaudiere, D. [Synchrotron Soleil, Saint Aubin, F-91192 Gif sur Yvette (France)

    2012-12-30

    Titanium and aluminium nitride thin films, Ti{sub 1-x}Al{sub x}N (x = 0, x = 0.5, x = 0.68), deposited by reactive magnetron sputtering on silicon substrates are investigated by combining two different X-ray diffraction experiments carried out using synchrotron radiation. Grazing-incidence X-ray diffraction and Ti K-edge diffraction anomalous near edge structure spectroscopy provide information on the micro- and nano-structure of the films respectively, which play a crucial role in the functionality of coatings. The spectroscopic data of Ti{sub 0.50}Al{sub 0.50}N film show that Ti atoms in crystallized domains and grain boundaries are all in octahedral cubic local order, but their growth mode is quite different. It is found that the crystallized part of the Ti{sub 0.50}Al{sub 0.50}N film has a single-crystalline nature, whereas the TiN one presents a fibrillar microstructure. For Ti{sub 0.32}Al{sub 0.68}N film, grazing-incidence X-ray diffraction provides information on the uniaxial texture along the [001] direction of the hexagonal lattice. A sharp Ti K pre-edge peak is observed in diffraction anomalous near edge spectrum that definitely shows that Ti atoms are incorporated in the hexagonal lattice of those fibrillar domains. Moreover, the difference observed between Ti K-edge diffraction anomalous and X-ray absorption pre-edge regions proves that a significant part of Ti atoms is located in nanocrystallites with cubic symmetry outside of the crystallized domains. - Highlights: Black-Right-Pointing-Pointer We study nano and micro-structures of TiN, Ti{sub 0.50}Al{sub 0.50}N and Ti{sub 0.32}Al{sub 0.68}N films. Black-Right-Pointing-Pointer Anomalous diffraction solves the crystallized part regardless of grain boundaries. Black-Right-Pointing-Pointer TiN microstructure is fibrillar, Ti{sub 0.5}Al{sub 0.5}N presents single crystalline domains. Black-Right-Pointing-Pointer For Ti{sub 0.32}Al{sub 0.68}N, Ti atoms are located in nanocrystallites with cubic symmetry

  5. Structural attributes for the recognition of weak and anomalous regions in coiled-coils of myosins and other motor proteins

    Directory of Open Access Journals (Sweden)

    Sunitha Margaret S

    2012-09-01

    Full Text Available Abstract Background Coiled-coils are found in different proteins like transcription factors, myosin tail domain, tropomyosin, leucine zippers and kinesins. Analysis of various structures containing coiled-coils has revealed the importance of electrostatic and hydrophobic interactions. In such domains, regions of different strength of interactions need to be identified since they could be biologically relevant. Findings We have updated our coiled-coil validation webserver, now called COILCHECK+, where new features were added to efficiently identify the strength of interaction at the interface region and measure the density of charged residues and hydrophobic residues. We have examined charged residues and hydrophobic ladders, using a new algorithm called CHAHO, which is incorporated within COILCHECK + server. CHAHO permits the identification of spatial charged residue patches and the continuity of hydrophobic ladder which stabilizes and destabilizes the coiled-coil structure. Conclusions The availability of such computational tools should be useful to understand the importance of spatial clustering of charged residues and the continuity of hydrophobic residues at the interface region of coiled-coil dimers. COILCHECK + is a structure based tool to validate coiled-coil stability; it can be accessed at http://caps.ncbs.res.in/coilcheckplus.

  6. Features for Exploiting Black-Box Optimization Problem Structure

    DEFF Research Database (Denmark)

    Tierney, Kevin; Malitsky, Yuri; Abell, Tinus

    2013-01-01

    Black-box optimization (BBO) problems arise in numerous scientic and engineering applications and are characterized by compu- tationally intensive objective functions, which severely limit the number of evaluations that can be performed. We present a robust set of features that analyze the tness...

  7. Non-Anomalous Semigroups and Real Numbers

    OpenAIRE

    Binder, Damon

    2016-01-01

    Motivated by intuitive properties of physical quantities, the notion of a non-anomalous semigroup is formulated. These are totally ordered semigroups where there are no `infinitesimally close' elements. The real numbers are then defined as the terminal object in a closely related category. From this definition a field structure on $\\mathbb R$ is derived, relating multiplication to morphisms between non-anomalous semigroups.

  8. Landscape Features Shape Genetic Structure in Threatened Northern Spotted Owls

    Science.gov (United States)

    Funk, W. Chris; Forsman, Eric D.; Mullins, Thomas D.; Haig, Susan M.

    2008-01-01

    Several recent studies have shown that landscape features can strongly affect spatial patterns of gene flow and genetic variation. Understanding landscape effects on genetic variation is important in conservation for defining management units and understanding movement patterns. The landscape may have little effect on gene flow, however, in highly mobile species such as birds. We tested for genetic breaks associated with landscape features in the northern spotted owl (Strix occidentalis caurina), a threatened subspecies associated with old forests in the U.S. Pacific Northwest and extreme southwestern Canada. We found little evidence for distinct genetic breaks in northern spotted owls using a large microsatellite dataset (352 individuals from across the subspecies' range genotyped at 10 loci). Nonetheless, dry low-elevation valleys and the Cascade and Olympic Mountains restrict gene flow, while the Oregon Coast Range facilitates it. The wide Columbia River is not a barrier to gene flow. In addition, inter-individual genetic distance and latitude were negatively related, likely reflecting northward colonization following Pleistocene glacial recession. Our study shows that landscape features may play an important role in shaping patterns of genetic variation in highly vagile taxa such as birds.

  9. The defining features of the modern entrepreneurship network structures

    Directory of Open Access Journals (Sweden)

    R.V. Kochubey

    2011-03-01

    Full Text Available In the article the various forms of network enterprises are analyzed, the key characteristics of network structures are identified. The relationship between network types and forms of business organization is shown. The studies of different types of network structures are systematized.

  10. Structural features for functional selectivity at serotonin receptors.

    Science.gov (United States)

    Wacker, Daniel; Wang, Chong; Katritch, Vsevolod; Han, Gye Won; Huang, Xi-Ping; Vardy, Eyal; McCorvy, John D; Jiang, Yi; Chu, Meihua; Siu, Fai Yiu; Liu, Wei; Xu, H Eric; Cherezov, Vadim; Roth, Bryan L; Stevens, Raymond C

    2013-05-01

    Drugs active at G protein-coupled receptors (GPCRs) can differentially modulate either canonical or noncanonical signaling pathways via a phenomenon known as functional selectivity or biased signaling. We report biochemical studies showing that the hallucinogen lysergic acid diethylamide, its precursor ergotamine (ERG), and related ergolines display strong functional selectivity for β-arrestin signaling at the 5-HT2B 5-hydroxytryptamine (5-HT) receptor, whereas they are relatively unbiased at the 5-HT1B receptor. To investigate the structural basis for biased signaling, we determined the crystal structure of the human 5-HT2B receptor bound to ERG and compared it with the 5-HT1B/ERG structure. Given the relatively poor understanding of GPCR structure and function to date, insight into different GPCR signaling pathways is important to better understand both adverse and favorable therapeutic activities. PMID:23519215

  11. Features of zirconium structure formation after severe plastic deformation

    International Nuclear Information System (INIS)

    Evolution of the texture and structural parameters of pure zirconium during the severe plastic deformation process by various methods has been investigated. It was found that the wire-drawing and combination of the ''compression-extrusion'' and wire-drawing are effective methods to obtain homogeneous Nanostructured state in pure zirconium. Possible mechanisms responsible for the observed structure transformation of zirconium during the deformation process are also discussed

  12. Structural Features and Healthy Properties of Polysaccharides Occurring in Mushrooms

    Directory of Open Access Journals (Sweden)

    Eva Guillamón

    2012-12-01

    Full Text Available Polysaccharides from mushrooms have attracted a great deal of attention due to the many healthy benefits they have demonstrated, such as immunomodulation, anticancer activity, prevention and treatment of cardiovascular diseases, antiviral and antimicrobial effects, among others. Isolation and purification of polysaccharides commonly involve several steps, and different techniques are actually available in order to increase extraction yield and purity. Studies have demonstrated that the molecular structure and arrangement significantly influence the biological activity; therefore, there is a wide range of analytical techniques for the elucidation of chemical structures. Different polysaccharides have been isolated from mushrooms, most of them consisting of β-linked glucans, such as lentinan from Lentinus edodes, pleuran from Pleurotus species, schizophyllan from Schizophyllum commune, calocyban from Calocybe indica, or ganoderan and ganopoly from Ganoderma lucidum. This article reviews the main methods of polysaccharide isolation and structural characterization, as well as some of the most important polysaccharides isolated from mushrooms and the healthy benefits they provide.

  13. Hemoglobin Neapolis, beta 126(H4)Val----Gly: a novel beta-chain variant associated with a mild beta-thalassemia phenotype and displaying anomalous stability features.

    Science.gov (United States)

    Pagano, L; Lacerra, G; Camardella, L; De Angioletti, M; Fioretti, G; Maglione, G; de Bonis, C; Guarino, E; Viola, A; Cutolo, R

    1991-12-01

    A novel beta-chain, beta 126(H4)Val----Gly, electrophoretically silent, was detected by reverse-phase high performance liquid chromatography in three unrelated families from Naples (Southern Italy) and accounted for about 30% of the total beta-chains. The amino acid substitution was detected by HPLC fingerprint. The eight heterozygous patients showed hematologic and biosynthetic alterations of mild beta-thalassemia type. The hemoglobin variant showed abnormal stability features. It was unstable in the heat stability and isopropanol precipitation tests, but did not cause a hemolytic syndrome in vivo and was stable in a time-course experiment of biosynthesis in vitro. DNA polymerase chain reaction direct sequencing of the mutated gene from 135 nt upstream of the cap site to 106 nt downstream of the polyadenylation site showed only the beta 126 GTG----GGG mutation, which was confirmed in the other patients by allele-specific oligonucleotide hybridization. The mutation was found to be associated with a type II beta-globin framework and restriction fragment length polymorphism haplotype V. The novel variant was named hemoglobin Neapolis. PMID:1954392

  14. Modeling the amorphous structure of mechanically alloyed Ti50Ni25Cu25 using anomalous wide-angle x-ray scattering and reverse Monte Carlo simulation

    International Nuclear Information System (INIS)

    An amorphous Ti50Ni25Cu25 alloy was produced by 19 h of mechanical alloying. Anomalous wide angle x-ray scattering data were collected at six energies and six total scattering factors were obtained. By considering the data collected at two energies close to the Ni and Cu K edges, two differential anomalous scattering factors about the Ni and Cu atoms were obtained, showing that the chemical environments around these atoms are different. Eight factors were used as input data to the reverse Monte Carlo method used to compute the partial structure factors STi3Ti(K), STi–Cu(K), STi–Ni(K), SCu3Cu(K), SCu–Ni(K) and SNi–Ni(K) and the partial pair distribution functions GTi3Ti(r), GTi–Cu(r), GTi–Ni(r), GCu3Cu(r), GCu–Ni(r) and GNi–Ni(r). From the RMC final atomic configuration and Gij(r) functions, the coordination numbers and interatomic atomic distances for the first neighbors were determined

  15. Effects of structural features of cotton cellulose on enzymatic hydrolysis

    International Nuclear Information System (INIS)

    Textile cotton wastes were treated with γ rays and 18% NaOH and 70% ZnCl2 solutions and were subjected to enzymatic hydrolysis. The untreated and treated samples were characterized both before and after hydrolysis by means of parameters concerning molecular structure (degree of polymerization), supermolecular structure (x-ray diffraction), accessibility, and reactivity (moisture regain, enzyme adsorption, and solubility in FeTNa). These parameters were correlated to kinetic parameters of the hydrolysis reaction. The V/sub max/ and K/sub m/ values were evaluated from Lineweaver-Burk plots at different temperatures. The V/sub max//K/sub m/ ratio, analogous to the specificity constant, proved to be less sensitive to experimental errors and more suitable for a comparison of the kinetic behavior of the samples. The modifications of both supermolecular structure and morphology of cellulose were of primary importance to attain high yields and rates of hydrolysis. Furthermore, the structural and morphologic parameters chosen to characterize the samples can be correlated to the kinetic parameters of enzymatic hydrolysis, in particular to K/sub m/ values

  16. Unusual Features of Crystal Structures of Some Simple Copper Compounds

    Science.gov (United States)

    Douglas, Bodie

    2009-01-01

    Some simple copper compounds have unusual crystal structures. Cu[subscript 3]N is cubic with N atoms at centers of octahedra formed by 6 Cu atoms. Cu[subscript 2]O (cuprite) is also cubic; O atoms are in tetrahedra formed by 4 Cu atoms. These tetrahedra are linked by sharing vertices forming two independent networks without linkages between them.…

  17. Features of noise in ultrathin gold nanowire structures

    Science.gov (United States)

    Handziuk, V.; Pud, S.; Coppola, M.; Kisner, A.; Vitusevich, S.

    2016-05-01

    Bundles of ultrathin gold nanowires (Au NWs, 2 nm in diameter) were fabricated and subsequently assembled onto electrodes. Electrical measurements and noise spectroscopy techniques were applied for sample characterization. The peculiarities of noise behavior in the system of bundles of ultrathin gold nanowires were studied. The measured power spectral density of flicker noise was proportional to current squared, which reflects ohmic behavior in NW structures. Lorentzian-shaped components were revealed in the noise spectra. They are suggested to be the result of the participation of molecules adsorbed on the NW surface in transport phenomena. The presence of molecular interfaces was confirmed by high-resolution transmission electron micrographs. The adsorbed molecules play an important role in charge transport and therefore determine electrical and noise properties of the NW structures. The results should be taken into account for the development of NW devices for sensing and molecular electronics applications.

  18. Structural features of free and covalently bound glycans

    OpenAIRE

    Blanchard, Véronique

    2006-01-01

    Carbohydrates act in many cellular functions and biological processes such as cell-cell recognition and adhesion, inflammation, fertilization, signal transduction, and development. In this context, structural information is required to understand molecular mechanisms involving carbohydrates. The placental glycoprotein hormone human chorionic gonadotropin (hCG) indirectly stimulates the corpus luteum to produce progesterone during the first trimester of pregnancy, until the placenta itself acq...

  19. Structural features of rabbits’ eyes and ultrasonic evaluation its dimensions

    OpenAIRE

    Sinkevičiūtė, Marija

    2007-01-01

    We have realized this work in cooperation with the Laboratory of Ophtalmology, Institute for Biomedical Research, Kaunas Medical University and Department of Anatomy and Physiology, Lithuanian Veterinary Academy. Using A-mode ultrasonography, we investigated structural parameters of the rabbit eye. The intraocular dimensions measured were as follows: distance between the anterior cornea to the anterior lens (CA), Thickness of the lens, distance between the surface of the retina (V), distance ...

  20. Structural characteristics and petroliferous features of Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Using the modern tectonic geology theories and methods such as the plate tectonic analysis, the paleo-struc- ture analysis, the structural-lithofacies analysis, and the fault related fold and petroleum system, and combining with the seismic data, well drilling data and the circumferential field geology, study on the structural characteristics and petroleum prospect in the Tarim Basin has been carried out. Results show that the Tarim Basin is a large superimposition and combination basin with continental crustal basement, composed of a Paleozoic craton and Meso-Cenozoic foreland basins. The characteristics of the basin are: the kernel part of the basin is the marine facies Paleozoic craton, superimposed 4 continental facies foreland basins. Though the scale of the paleozoic craton of the Tarim Basin is relatively small, the structure is steady. The petroleum prospect of the Paleozoic craton is: multiphase pool-generation and accumulation controlled by ancient uplift. The Meso-Cenozoic foreland basins in the Tarim Basin, which are distributed on the cratonic circumference and are a long-term subsidence, turned into rejuvenated foreland basins after the Meso-Cenozoic period. The petroleum prospects are: coal-bed generating hydrocarbon, abundant natural gas, pool-generation in later and recent periods, the oil and gas distribution controlled by the foreland thrust belt. The structural characteristics of Tarim provide it with a superimposition and combination petroleum system of multiple resources, multiple reservoirs and multiphase pool-generation. The oil and gas exploration prospect covers two large fields: the Paleozoic craton and the Meso-Cenozoic foreland thrust belt.

  1. Computing Posterior Probabilities of Structural Features in Bayesian Networks

    CERN Document Server

    Tian, Jin

    2012-01-01

    We study the problem of learning Bayesian network structures from data. Koivisto and Sood (2004) and Koivisto (2006) presented algorithms that can compute the exact marginal posterior probability of a subnetwork, e.g., a single edge, in O(n2n) time and the posterior probabilities for all n(n-1) potential edges in O(n2n) total time, assuming that the number of parents per node or the indegree is bounded by a constant. One main drawback of their algorithms is the requirement of a special structure prior that is non uniform and does not respect Markov equivalence. In this paper, we develop an algorithm that can compute the exact posterior probability of a subnetwork in O(3n) time and the posterior probabilities for all n(n-1) potential edges in O(n3n) total time. Our algorithm also assumes a bounded indegree but allows general structure priors. We demonstrate the applicability of the algorithm on several data sets with up to 20 variables.

  2. Anomalous extracellular diffusion in rat cerebellum.

    Science.gov (United States)

    Xiao, Fanrong; Hrabe, Jan; Hrabetova, Sabina

    2015-05-01

    Extracellular space (ECS) is a major channel transporting biologically active molecules and drugs in the brain. Diffusion-mediated transport of these substances is hindered by the ECS structure but the microscopic basis of this hindrance is not fully understood. One hypothesis proposes that the hindrance originates in large part from the presence of dead-space (DS) microdomains that can transiently retain diffusing molecules. Because previous theoretical and modeling work reported an initial period of anomalous diffusion in similar environments, we expected that brain regions densely populated by DS microdomains would exhibit anomalous extracellular diffusion. Specifically, we targeted granular layers (GL) of rat and turtle cerebella that are populated with large and geometrically complex glomeruli. The integrative optical imaging (IOI) method was employed to evaluate diffusion of fluorophore-labeled dextran (MW 3000) in GL, and the IOI data analysis was adapted to quantify the anomalous diffusion exponent dw from the IOI records. Diffusion was significantly anomalous in rat GL, where dw reached 4.8. In the geometrically simpler turtle GL, dw was elevated but not robustly anomalous (dw = 2.6). The experimental work was complemented by numerical Monte Carlo simulations of anomalous ECS diffusion in several three-dimensional tissue models containing glomeruli-like structures. It demonstrated that both the duration of transiently anomalous diffusion and the anomalous exponent depend on the size of model glomeruli and the degree of their wrapping. In conclusion, we have found anomalous extracellular diffusion in the GL of rat cerebellum. This finding lends support to the DS microdomain hypothesis. Transiently anomalous diffusion also has a profound effect on the spatiotemporal distribution of molecules released into the ECS, especially at diffusion distances on the order of a few cell diameters, speeding up short-range diffusion-mediated signals in less permeable

  3. Structural damage localisation for a frame structure from changes in curvature of approximate entropy feature vectors

    Science.gov (United States)

    An, Y. H.; Ou, J. P.

    2014-01-01

    At present, accurate vibration-based damage localisation cannot be achieved very well in mechanical and civil engineering fields due to high noise in the measurements and low accuracy in finite element (FE) model of the measured structures. To address these issues, a method for damage detection is proposed in this work, i.e. the mean curvature difference method of approximate entropy (ApEn) feature vectors, based on the ApEn theory and curvature method. Simulation results of both single and multiple damage cases under pulse excitation indicate that the proposed method can be utilised to determine whether the damage is present in the structure or not and to locate the damage accurately, and the method exhibits strong anti-noise ability: it is feasible for damage with 5% stiffness reduction even if the noise level is up to 25%. Moreover, the proposed method does not require a structural FE model. Experimental results of a six-storey shear frame model also validated the proposed method. All of these lay a good foundation for its application in shear frame structures.

  4. Some special features of formation of manyfunctional powders steels structure

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    It has been studied connection between composition, structure and properties of powder steels using technology of their own. Nitrogen containing powders were obtained by mechanical allowing (MA) of Fe-Cr and Fe Cr Ni-C mixtures in a high-energy planetary mill in the gaseous nitrogen environment. The contents of nitrogen after MA was 0. 7 % in Fe-Cr-N and 2.1% in Fe-Cr-Ni-C-N mixes. Phase composition after the mechanical alloying was: in system Fe-Cr-N - solid solution of chrome in iron and α - Fe, in system Fe-Cr-Ni-C-N-40% γ-phase (vol. fraction) , α - Fe and solid solution Cr-Fe.There are investigated physical-mechanical, tribo-technical and specify properties of the nitrous steels,are fixed the base dependences between parameters of process of MA and structure of steels. Introduction of nitrogen by rather new method of MA, as against saturation of melts, allows to run phase composition - to generate structure with more dispersible and uniform nitrides or with the nitrous austenite (depending on purpose of steel).It is demonstrated by means of X-ray diffraction and method of Raman spectrum analysis, that in a sintering process of powder steels, obtained by introduction of carbon in the form of cast-iron powder, a formation of metallofullerite phase Fex C60 at determined conditions. The possibility of fullerenes conception in powder carbon steels, diffusion of iron atoms at fullerite lattice and formation of metallofullerites during contact interaction of fullerene with iron is confirmed experimentally.Dependence of synthesis activity of fullerences from temperature of sintering, type and quantity of alloy elements is determined.

  5. Structures of 18 radio sources with peculiar optical features

    International Nuclear Information System (INIS)

    Radio positions, angular structure data, and polarizations were measured with the NRAO interferometer at 3.71 and 11.1 cm for 18 sources whose optical identifications seem to have jets, wisps, or close companions. Optical positions were measured with the University of Texas measuring machine. In five cases, alignment within 100 in position angle of the optical and the radio major axes was found. The quasar PHL 1093 (0137+012) may be similar to 3C273. There is a compact, flat-spectrum source at the quasar position and an extended, steep-spectrum component at the end of the optical jet

  6. Mapping the structural and dynamical features of kinesin motor domains.

    Directory of Open Access Journals (Sweden)

    Guido Scarabelli

    Full Text Available Kinesin motor proteins drive intracellular transport by coupling ATP hydrolysis to conformational changes that mediate directed movement along microtubules. Characterizing these distinct conformations and their interconversion mechanism is essential to determining an atomic-level model of kinesin action. Here we report a comprehensive principal component analysis of 114 experimental structures along with the results of conventional and accelerated molecular dynamics simulations that together map the structural dynamics of the kinesin motor domain. All experimental structures were found to reside in one of three distinct conformational clusters (ATP-like, ADP-like and Eg5 inhibitor-bound. These groups differ in the orientation of key functional elements, most notably the microtubule binding α4-α5, loop8 subdomain and α2b-β4-β6-β7 motor domain tip. Group membership was found not to correlate with the nature of the bound nucleotide in a given structure. However, groupings were coincident with distinct neck-linker orientations. Accelerated molecular dynamics simulations of ATP, ADP and nucleotide free Eg5 indicate that all three nucleotide states could sample the major crystallographically observed conformations. Differences in the dynamic coupling of distal sites were also evident. In multiple ATP bound simulations, the neck-linker, loop8 and the α4-α5 subdomain display correlated motions that are absent in ADP bound simulations. Further dissection of these couplings provides evidence for a network of dynamic communication between the active site, microtubule-binding interface and neck-linker via loop7 and loop13. Additional simulations indicate that the mutations G325A and G326A in loop13 reduce the flexibility of these regions and disrupt their couplings. Our combined results indicate that the reported ATP and ADP-like conformations of kinesin are intrinsically accessible regardless of nucleotide state and support a model where neck

  7. Cluster Features in Reactions and Structure of Heavy Nuclei

    CERN Document Server

    Adamian, G G; Jolos, R V; Scheid, W; Shneidman, T M

    2003-01-01

    Cluster effects in the structure of heavy nuclei are considered. The properties of the states of the alternating parity bands in Ra, Th, U and Pu isotopes are analyzed within a cluster model. The model is based on the assumption that cluster type shapes are produced by the motion of the nuclear system in the mass asymmetry coordinate. The results of calculations of the spin dependence of the parity splitting and of the electric multipole transition moments are in agreement with the experimental data.

  8. Structures of 18 radio sources with peculiar optical features

    Energy Technology Data Exchange (ETDEWEB)

    Ghigo, F.D.

    1978-11-01

    Radio positions, angular structure data, and polarizations were measured with the NRAO interferometer at 3.71 and 11.1 cm for 18 sources whose optical identifications seem to have jets, wisps, or close companions. Optical positions were measured with the University of Texas measuring machine. In five cases, alignment within 10/sup 0/ in position angle of the optical and the radio major axes was found. The quasar PHL 1093 (0137+012) may be similar to 3C273. There is a compact, flat-spectrum source at the quasar position and an extended, steep-spectrum component at the end of the optical jet.

  9. On the structural features of the substrates of protein kinase

    International Nuclear Information System (INIS)

    Structural integrity of case in and phosvitin as substrates of a mitochondrial protein kinase preparation has been examined with reference to maximal phosphate incorporation with AT32P. These proteins subjected to degradative treatments with trypsin and chymotrypsin gave rise to peptides which could still be phosphorylated by the kinase to the extent of 30.80% as compared to the parent proteins. The more active peptides from both casein and phosvitin contained high proportion of serine residue along with certain other amino acids. The hexosamine content in phosvitin did not determine its function as substrate of protein kinase. (author)

  10. Structural features of vanadyl porphyrins of petroleum of West Kazakhstan

    Energy Technology Data Exchange (ETDEWEB)

    Bakirova, S.F.; Kotova, A.V.; Yag' yaeva, S.; Fedorova, N.V.; Nadirov, N.K.

    1984-01-01

    During the past 10 to 15 years studies have been published concerning petroleum porphyrins in which a description was given of the composition and structure of porphyrins of petroleums found in various regions abroad and in the Soviet Union - West Siberia, the Kama region, Tajikistan. Porphyrin structure has been established using electron and IR spectroscopy, nuclear and paramagnetic resonance, mass-spectrometry (low and high resolution), these techniques enabled the form of the main nucleus and its peripheral substituents to be established and yielded information concerning the molar mass values and the number of carbon atoms in alkyl chains. Methods developed in the Tomsk Institute of Petroleum Chemistry, USSR Academy of Sciences were used in this study, which involve the following operations: (1) extraction of porphyrins from petroleum using dimethylformamide; (2) chromatographic purification of the separated porphyrins elution from columns packed with aluminas of different activities by organic solvents and their mixtures, in order of increasing polarities; (3) mass-spectrometric examination of the purified vanadyl-porphyrin samples. The composition of porphyrins and the ratio of etioporphyrins and desoxophylloerythro-etioporphyrins was deduced from the electron spectra obtained from the purified porphyrin samples separated from petroleums.

  11. Artificial-neural-network-based classification of mammographic microcalcifications using image structure features

    Science.gov (United States)

    Dhawan, Atam P.; Chitre, Yateen S.; Moskowitz, Myron

    1993-07-01

    Mammography associated with clinical breast examination and self-breast examination is the only effective and viable method for mass breast screening. It is however, difficult to distinguish between benign and malignant microcalcifications associated with breast cancer. Most of the techniques used in the computerized analysis of mammographic microcalcifications segment the digitized gray-level image into regions representing microcalcifications. We present a second-order gray-level histogram based feature extraction approach to extract microcalcification features. These features, called image structure features, are computed from the second-order gray-level histogram statistics, and do not require segmentation of the original image into binary regions. Several image structure features were computed for 100 cases of `difficult to diagnose' microcalcification cases with known biopsy results. These features were analyzed in a correlation study which provided a set of five best image structure features. A feedforward backpropagation neural network was used to classify mammographic microcalcifications using the image structure features. The network was trained on 10 cases of mammographic microcalcifications and tested on additional 85 `difficult-to-diagnose' microcalcifications cases using the selected image structure features. The trained network yielded good results for classification of `difficult-to- diagnose' microcalcifications into benign and malignant categories.

  12. Detecting key structural features within highly recombined genes.

    Directory of Open Access Journals (Sweden)

    John E Wertz

    2007-01-01

    Full Text Available Many microorganisms exhibit high levels of intragenic recombination following horizontal gene transfer events. Furthermore, many microbial genes are subject to strong diversifying selection as part of the pathogenic process. A multiple sequence alignment is an essential starting point for many of the tools that provide fundamental insights on gene structure and evolution, such as phylogenetics; however, an accurate alignment is not always possible to attain. In this study, a new analytic approach was developed in order to better quantify the genetic organization of highly diversified genes whose alleles do not align. This BLAST-based method, denoted BLAST Miner, employs an iterative process that places short segments of highly similar sequence into discrete datasets that are designated "modules." The relative positions of modules along the length of the genes, and their frequency of occurrence, are used to identify sequence duplications, insertions, and rearrangements. Partial alleles of sof from Streptococcus pyogenes, encoding a surface protein under host immune selection, were analyzed for module content. High-frequency Modules 6 and 13 were identified and examined in depth. Nucleotide sequences corresponding to both modules contain numerous duplications and inverted repeats, whereby many codons form palindromic pairs. Combined with evidence for a strong codon usage bias, data suggest that Module 6 and 13 sequences are under selection to preserve their nucleic acid secondary structure. The concentration of overlapping tandem and inverted repeats within a small region of DNA is highly suggestive of a mechanistic role for Module 6 and 13 sequences in promoting aberrant recombination. Analysis of pbp2X alleles from Streptococcus pneumoniae, encoding cell wall enzymes that confer antibiotic resistance, supports the broad applicability of this tool in deciphering the genetic organization of highly recombined genes. BLAST Miner shares with

  13. Structural features of ultradeformable archaeosomes for topical delivery of ovalbumin.

    Science.gov (United States)

    Carrer, Dolores C; Higa, Leticia H; Tesoriero, Maria Victoria Defain; Morilla, Maria Jose; Roncaglia, Diana I; Romero, Eder Lilia

    2014-09-01

    The ultradeformable archaeosomes (UDA, made of total polar archaeolipids (TPA) extracted from the extreme halophile archaea Halorubrum tebenquichense:soybean phosphatidylcholine (SPC):sodium cholate (NaChol), 3:3:1 w:w), are promising topical adjuvants showing high deformability, an essential property for intact skin penetration up to the viable epidermis/dermis. To gain insights on UDA structure, the interactions between TPA, SPC and the edge activator NaChol, were assessed by electrospray ionization mass spectroscopy (ESI-MS) and confocal fluorescence microscopy of giant unilamellar vesicles (GUV). The non covalent heterodimers NaChol-SPC, NaChol-phosphatidylglycerophosphate methyl ether (PGPMe), NaChol-sulfated diglycosyl diphytanyl-glycerol diether (SDGD5) and SPC-PGPMe detected in the gas phase by ESI-MS after direct infusion of UDA, together with the homogeneous partition of FASTDiO and DiIC18 in GUV suggested that in these proportions, lipids and NaChol were miscible. We propose therefore, a model where in UDA the SPC diluted sufficient enough in the rich PGPMe TPA, so as to the low lateral mobility of molecules (typical of rich in PGPMe bilayers) was no longer experienced. We also found that 50μm deep within in vitro human skin canyons, the fluorescence of Alexa fluor 647-ovalbumin in UDL was ∼1.5 folds higher than in UDA, indicating a potential steric hindrance of the voluminous structure of PGPMe UDA bilayer, to the penetration of a particulate cargo such as the 7nm diameter ovalbumin. According to these observations, a further reduction in PGPMe - a lipid playing no immune role - content could help to improve the performance of UDA as topical adjuvants. PMID:24974012

  14. Temperature dependence of the perpendicular magnetic anisotropy in Ta/Co2FeAl/MgO structures probed by Anomalous Hall Effect

    Science.gov (United States)

    Gabor, M. S.; Petrisor, T.; Pop, O.; Colis, S.; Tiusan, C.

    2015-10-01

    We report a detailed study of the temperature dependence of the magnetic anisotropy in Ta/Co2FeAl/MgO structures by means of Anomalous Hall Effect measurements. The volume magnetic anisotropy, although negligible at room temperature, shows a non-negligible value at low temperatures and favors an in-plane easy magnetization axis. The surface magnetic anisotropy, which promotes the perpendicular magnetic easy axis, shows an increase from 0.76 ± 0.05 erg /cm2 at 300 K, up to 1.08 ± 0.04 erg /cm2 at 5 K, attributed to the evolution of the Co2FeAl layer saturation magnetization with temperature.

  15. Atomic and Electronic-Band Structures of Anomalous Carbon Dimers on 3C-SiC (001)-c(2 [times] 2)

    Energy Technology Data Exchange (ETDEWEB)

    Yeom, H.W. (Research Center for Spectrochemistry, the University of Tokyo, Tokyo 113 (Japan)); Shimomura, M.; Kono, S. (Research Institute for Scientific Measurements, Tohoku University, Sendai 980-77 (Japan)); Kitamura, J.; Hara, S.; Yoshida, S.; Okushi, H.; Kajimura, K. (Electrotechnical Laboratory, Tsukuba, Ibaraki 305 (Japan)); Tono, K.; Matsuda, I.; Ohta, T. (Department of Chemistry, the University of Tokyo, Tokyo 113 (Japan)); Mun, B.S.; Mun, B.S.; Fadley, C.S.; Fadley, C.S. (Department of Physics, University of California at Davis, Davis, California 95616 (United States)); Huff, W.A. (KLA-Tencor, Milpitas, California 95035) (Department of Physics, Gifu University, Gifu, Gifu 501-1193 (Japan))

    1999-08-01

    The atomic structure of the c(2[times]2) reconstruction of the C -terminated 3C-SiC(001) surface was unambiguously determined by scanning tunneling microscopy and surface-core-level-resolved photoelectron diffraction studies. This surface is found to uniquely and uniformly consist of anomalous bridge-bonded C dimers with a C-C bond length of 1.22thinspthinsp[Angstrom]. Furthermore, an extensive angle-resolved photoemission study clearly identifies two occupied [pi] state bands due to the surface-normal and -parallel [pi] orbitals of the [ital triple-bonded] C dimers. This provides an electronic explanation of the stability of this unique surface reconstruction. [copyright] [ital 1999] [ital The American Physical Society

  16. Investigating the interplay between mechanisms of anomalous diffusion via fractional Brownian walks on a comb-like structure

    CERN Document Server

    Ribeiro, H V; Alves, L G A; Zola, R S; Lenzi, E L

    2014-01-01

    The comb model is a simplified description for anomalous diffusion under geometric constraints. It represents particles spreading out in a two-dimensional space where the motions in the x-direction are allowed only when the y coordinate of the particle is zero. Here, we propose an extension for the comb model via Langevin-like equations driven by fractional Gaussian noises (long-range correlated). By carrying out computer simulations, we show that the correlations in the y-direction affect the diffusive behavior in the x-direction in a non-trivial fashion, resulting in a quite rich diffusive scenario characterized by usual, superdiffusive or subdiffusive scaling of second moment in the x-direction. We further show that the long-range correlations affect the probability distribution of the particle positions in the x-direction, making their tails longer when noise in the y-direction is persistent and shorter for anti-persistent noise. Our model thus combines and allows the study/analysis of the interplay betwe...

  17. Chaotic features of nuclear structure and dynamics: selected topics

    Science.gov (United States)

    Zelevinsky, Vladimir; Volya, Alexander

    2016-03-01

    Quantum chaos has become an important element of our knowledge about physics of complex systems. In typical mesoscopic systems of interacting particles the dynamics invariably become chaotic when the level density, growing by combinatorial reasons, leads to the increasing probability of mixing simple mean-field (particle-hole) configurations. The resulting stationary states have exceedingly complicated structures that are comparable to those in random matrix theory. We discuss the main properties of mesoscopic quantum chaos and show that it can serve as a justification for application of statistical mechanics to mesoscopic systems. We show that quantum chaos becomes a powerful instrument for experimental, theoretical and computational work. The generalization to open systems and effects in the continuum are discussed with the help of the effective non-Hermitian Hamiltonian; it is shown how to formulate this approach for numerous problems of quantum signal transmission. The artificially introduced randomness can also be helpful for a deeper understanding of physics. We indicate the problems that require more investigation so as to be understood further.

  18. The structural features of distributed programmable wireless systems

    OpenAIRE

    Зайцев, С. В.; НАУ; Приступа, В. В.; НАУ

    2013-01-01

    This article investigates the structural characteristics of distributed programmable wireless systems based on the principles of Software Defined Radio with open architecture Software Communication Architecture Исследовано структурные особенности распределенных программируемых беспроводных систем, базирующихся на принципах Software Defined Radio с открытой архитектурой Software Communication Architecture Досліджено структурні особливості розподілених програмованих безпровідних систем, я...

  19. Effect of some structural features of coals on their reducibility

    Energy Technology Data Exchange (ETDEWEB)

    Grigor' eva, E.A.; Bakirova, E.V.; Lesnikova, E.B.; Larina, N.K.; Zharova, M.N.

    1978-09-01

    Two samples of Kuzbass hard coal, each differing in the intensity of the conversion during hydrogenation (86.5% and 80.4% respectively) were investigated. Sample 1 differed from sample 2 in higher oxygen content, increased ratios of hydrogen to carbon and oxygen to carbon atoms, the presence of humic acid and a high ash content. The data from physical and chemical analysis demonstrate the process of destruction of unstable ester bonds. Sample 1 was characterized by an increased tendency to hydrolize which explained the more intense conversion during hydrogenation. The two raw samples as well as samples, hydrolized and demineralized by 3% hydrochloric acid were reduced. Sample 1 demonstrated an increased disposition to reduce and had a high content in the raw coal of easily hydrolized ester bonds. The behaviour of the coal during reduction by sodium boron hydride was directly dependent on the presence of easily hydrolized bonds in the organic mass, and on the form of bonding of the mineral components in the structure of the coal.

  20. Identification of anomalous motion of thunderstorms using daily rainfall fields

    Science.gov (United States)

    del Moral, Anna; Llasat, Maria Carmen; Rigo, Tomeu

    2016-04-01

    Adverse weather phenomena in Catalonia (NE of the Iberian Peninsula) is commonly associated to heavy rains, large hail, strong winds, and/or tornados, all of them caused by thunderstorms. In most of the cases with adverse weather, thunderstorms vary sharply their trajectories in a concrete moment, changing completely the motion directions that have previously followed. Furthermore, it is possible that a breaking into several cells may be produced, or, in the opposite, it can be observed a joining of different thunderstorms into a bigger system. In order to identify the main features of the developing process of thunderstorms and the anomalous motions that these may follow in some cases, this contribution presents a classification of the events using daily rainfall fields, with the purpose of distinguishing quickly anomalous motion of thunderstorms. The methodology implemented allows classifying the daily rainfall fields in three categories by applying some thresholds related with the daily precipitation accumulated values and their extension: days with "no rain", days with "potentially convective" rain and days with "non-potentially convective" rain. Finally, for those "potentially convective" daily rainfall charts, it also allows a geometrical identification and classification of all the convective structures into "ellipse" and "non-ellipse", obtaining then the structures with "normal" or "anomalous" motion pattern, respectively. The work is focused on the period 2008-2015, and presents some characteristics of the rainfall behaviour in terms of the seasonal distribution of convective rainfall or the geographic variability. It shows that convective structures are mainly found during late spring and summer, even though they can be recorded in any time of the year. Consequently, the maximum number of convective structures with anomalous motion is recorded between July and November. Furthermore, the contribution shows the role of the orography of Catalonia in the

  1. Crystal structure determination of solar cell materials: Cu2ZnSnS4 thin films using X-ray anomalous dispersion

    International Nuclear Information System (INIS)

    Highlights: ► Cu2ZnSnS4 thin films as a solar cell material were synthesized. ► The wavelength dependences of the diffraction intensity were measured. ► The crystal structures were clearly identified as kesterite structure for all samples. ► Crystal structure analysis revealed that the atomic compositions were Cu/(Zn + Sn) = 0.97 and Zn/Sn = 1.42 for the sample synthesized using stoichiometric amount of starting materials. - Abstract: The crystal structure of Cu2ZnSnS4 (CZTS) thin films fabricated by vapor-phase sulfurization was determined using X-ray anomalous dispersion. High statistic synchrotron radiation X-ray diffraction data were collected from very small amounts of powder. By analyzing the wavelength dependencies of the diffraction peak intensities, the crystal structure was clearly identified as kesterite. Rietveld analysis revealed that the atomic composition deviated from stoichiometric composition, and the compositions were Cu/(Zn + Sn) = 0.97, and Zn/Sn = 1.42.

  2. Structural features underlying raloxifene's biophysical interaction with bone matrix.

    Science.gov (United States)

    Bivi, Nicoletta; Hu, Haitao; Chavali, Balagopalakrishna; Chalmers, Michael J; Reutter, Christopher T; Durst, Gregory L; Riley, Anna; Sato, Masahiko; Allen, Matthew R; Burr, David D; Dodge, Jeffrey A

    2016-02-15

    Raloxifene, a selective estrogen receptor modulator (SERM), reduces fracture risk at least in part by improving the mechanical properties of bone in a cell- and estrogen receptor-independent manner. In this study, we determined that raloxifene directly interacts with the bone tissue. Through the use of multiple and complementary biophysical techniques including nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR), we show that raloxifene interacts specifically with the organic component or the organic/mineral composite, and not with hydroxyapatite. Structure-activity studies reveal that the basic side chain of raloxifene is an instrumental determinant in the interaction with bone. Thus, truncation of portions of the side chain reduces bone binding and also diminishes the increase in mechanical properties. Our results support a model wherein the piperidine interacts with bone matrix through electrostatic interactions with the piperidine nitrogen and through hydrophobic interactions (van der Waals) with the aliphatic groups in the side chain and the benzothiophene core. Furthermore, in silico prediction of the potential binding sites on the surface of collagen revealed the presence of a groove with sufficient space to accommodate raloxifene analogs. The hydroxyl groups on the benzothiophene nucleus, which are necessary for binding of SERMs to the estrogen receptor, are not required for binding to the bone surface, but mediate a more robust binding of the compound to the bone powder. In conclusion, we report herein a novel property of raloxifene analogs that allows them to interact with the bone tissue through potential contacts with the organic matrix and in particular collagen. PMID:26795112

  3. Compressive behavior of pervious concretes and a quantification of the influence of random pore structure features

    Energy Technology Data Exchange (ETDEWEB)

    Deo, Omkar [Department of Civil and Environmental Engineering, Clarkson University, Potsdam, NY 13699 (United States); Neithalath, Narayanan, E-mail: nneithal@clarkson.edu [Department of Civil and Environmental Engineering, Clarkson University, Potsdam, NY 13699 (United States)

    2010-11-25

    Research highlights: {yields} Identified the relevant pore structure features of pervious concretes, provided methodologies to extract those, and quantified the influence of these features on compressive response. {yields} A model for stress-strain relationship of pervious concretes, and relationship between model parameters and parameters of the stress-strain relationship developed. {yields} Statistical model for compressive strength as a function of pore structure features; and a stochastic model for the sensitivity of pore structure features in strength prediction. - Abstract: Properties of a random porous material such as pervious concrete are strongly dependent on its pore structure features, porosity being an important one among them. This study deals with developing an understanding of the material structure-compressive response relationships in pervious concretes. Several pervious concrete mixtures with different pore structure features are proportioned and subjected to static compression tests. The pore structure features such as pore area fractions, pore sizes, mean free spacing of the pores, specific surface area, and the three-dimensional pore distribution density are extracted using image analysis methods. The compressive stress-strain response of pervious concretes, a model to predict the stress-strain response, and its relationship to several of the pore structure features are outlined. Larger aggregate sizes and increase in paste volume fractions are observed to result in increased compressive strengths. The compressive response is found to be influenced by the pore sizes, their distributions and spacing. A statistical model is used to relate the compressive strength to the relevant pore structure features, which is then used as a base model in a Monte-Carlo simulation to evaluate the sensitivity of the predicted compressive strength to the model terms.

  4. Features of the vertical phytoplankton structure in the deep-sea parts of the Caspian Sea in summer

    Science.gov (United States)

    Pautova, L. A.; Kravchishina, M. D.; Vostokov, S. V.; Zernova, V. V.; Silkin, V. A.

    2015-06-01

    The new features of the vertical phytoplankton distribution in the central and southern deep-water parts of the Caspian Sea are identified on the basis of long-term observations (2004-2012, 419 samples). Systematic study of phytoplankton in the Middle Caspian for nine years has shown that the interannual variability in the dominant summer phytoplankton complex is due to traditional species of diatoms and dinoflagellates and also coccolithophores, a new systematic group for the Caspian Sea (June 2010). It was first determined that summer phytoplankton of the deep-water parts in the Middle and Southern Caspian is similar in species, quantitative, and spatial (vertical) structure. A zone of higher phytoplankton productivity was first found in the area of the Absheron Sill. Two types of communities and their boundary were first distinguished in the vertical structure of summer phytoplankton of the deep-sea parts: warm-water and cold-water (below the thermocline). The boundary between them corresponds to the lower boundary of the seasonal thermocline (maximum depths up to 50-60 m) with the highest wet total phytoplankton biomass and chlorophyll a concentrations. The intensity of stratification of the water column by temperature mainly causes the vertical phytoplankton structure. The anomalously large deep-sea accumulations of diatoms cells containing chlorophyll (remains of winter-spring blooms) were first found in the near-bottom layers of the northern slope of the Derbent Depression. Their presence at the depths of 300-400 m is probably caused by the slope cascading. The lower boundary (500 m) of phytoplankton abundance in the Caspian Sea with chlorophyll-containing cells of fresh water green algae were registered by the authors for the first time in the central areas of the Derbent and South Caspian depressions. This phenomenon was caused by the contribution of cold Caucasus rivers through a system of submarine canyons from the shelf to the deep sea areas.

  5. Structural features in TAR RNA of human and simian immunodeficiency viruses: a phylogenetic analysis.

    OpenAIRE

    Berkhout, B.

    1992-01-01

    A comparative analysis of TAR RNA structures in human and simian immunodeficiency viruses reveals the conservation of certain structural features despite the divergence in sequence. Both the TAR elements of HIV-1 and SIV-chimpanzee can be folded into relatively simple one-stem hairpin structures. Chemical and RNAase probes were used to analyze the more complex structure of HIV-2 TAR RNA, which folds into a branched hairpin structure. A surprisingly similar RNA conformation can be proposed for...

  6. A review of undulated sediment features on Mediterranean prodeltas: distinguishing sediment transport structures from sediment deformation

    OpenAIRE

    Urgeles, Roger; Cattaneo, Antonio; PUIG Pere; Liquete, Camino; Mol, Ben; Amblas, David; Sultan, Nabil; Trincardi, Fabio

    2011-01-01

    Most Mediterranean prodeltas show undulated sediment features on the foresets of their Holocene wedges. These features have been described all along the Mediterranean for the last 30 years and interpreted as either soft sediment deformation and incipient landsliding, and more recently, as sediment transport structures. We perform a review and detailed analysis of these undulated sediment features using ultrahigh-resolution seismic and bathymetric data as well as geotechnical information and h...

  7. Ht-Index for Quantifying the Fractal or Scaling Structure of Geographic Features

    OpenAIRE

    Jiang, Bin; Yin, Junjun

    2013-01-01

    Although geographic features, such as mountains and coastlines, are fractal, some studies have claimed that the fractal property is not universal. This claim, which is false, is mainly attributed to the strict definition of fractal dimension as a measure or index for characterizing the complexity of fractals. In this paper, we propose an alternative, the ht-index, to quantify the fractal or scaling structure of geographic features. A geographic feature has ht-index h if the pattern of far mor...

  8. Features of biomorphological structure of the steppe phytocenosises of Opuk Natural Reserve

    Directory of Open Access Journals (Sweden)

    Valentina Kobechinskaya

    2014-04-01

    Full Text Available Analysis of biomorphological structure of the steppe phytocenosises of Opuksky Natural Reserve revealed regional characteristics of vegetation which were based on adaptive features of growing species. On the basis of contingency coefficients between the groups of biomorphological features were marked eco-biomorphological types of plants, which allow complete investigation on the features of individual ecobiomorphs, identification of ecological identity of steppe landscape and planning of further environmental activities.

  9. Anomalous dispersion enhanced Cerenkov phase-matching

    Energy Technology Data Exchange (ETDEWEB)

    Kowalczyk, T.C.; Singer, K.D. [Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Physics; Cahill, P.A. [Sandia National Labs., Albuquerque, NM (United States)

    1993-11-01

    The authors report on a scheme for phase-matching second harmonic generation in polymer waveguides based on the use of anomalous dispersion to optimize Cerenkov phase matching. They have used the theoretical results of Hashizume et al. and Onda and Ito to design an optimum structure for phase-matched conversion. They have found that the use of anomalous dispersion in the design results in a 100-fold enhancement in the calculated conversion efficiency. This technique also overcomes the limitation of anomalous dispersion phase-matching which results from absorption at the second harmonic. Experiments are in progress to demonstrate these results.

  10. Handwritten Digit Recognition Using Structural, Statistical Features and K-nearest Neighbor Classifier

    Directory of Open Access Journals (Sweden)

    U Ravi Babu

    2014-02-01

    Full Text Available This paper presents a new approach to off-line handwritten numeral recognition based on structural and statistical features. Five different types of skeleton features: (horizontal, vertical crossings, end, branch, and cross points, number of contours in the image, Width-to-Height ratio, and distribution features are used for the recognition of numerals. We create two vectors Sample Feature Vector (SFV is a vector which contains Structural and Statistical features of MNIST sample data base of handwritten numerals and Test Feature Vector (TFV is a vector which contains Structural and Statistical features of MNIST test database of handwritten numerals. The performance of digit recognition system depends mainly on what kind of features are being used. The objective of this paper is to provide efficient and reliable techniques for recognition of handwritten numerals. A Euclidian minimum distance criterion is used to find minimum distances and k-nearest neighbor classifier is used to classify the numerals. MNIST database is used for both training and testing the system. A total 5000 numeral images are tested, and the overall accuracy is found to be 98.42%.

  11. Comparison study of feature extraction methods in structural damage pattern recognition

    Science.gov (United States)

    Liu, Wenjia; Chen, Bo; Swartz, R. Andrew

    2011-04-01

    This paper compares the performance of various feature extraction methods applied to structural sensor measurements acquired in-situ, from a decommissioned bridge under realistic damage scenarios. Three feature extraction methods are applied to sensor data to generate feature vectors for normal and damaged structure data patterns. The investigated feature extraction methods include identification of both time domain methods as well as frequency domain methods. The evaluation of the feature extraction methods is performed by examining distance values among different patterns, distance values among feature vectors in the same pattern, and pattern recognition success rate. The test data used in the comparison study are from the System Identification to Monitor Civil Engineering Structures (SIMCES) Z24 Bridge damage detection tests, a rigorous instrumentation campaign that recorded the dynamic performance of a concrete box-girder bridge under progressively increasing damage scenarios. A number of progressive damage test case data sets, including undamaged cases and pier settlement cases (different depths), are used to test the separation of feature vectors among different patterns and the pattern recognition success rate for different feature extraction methods is reported.

  12. Face Retrieval Based on Robust Local Features and Statistical-Structural Learning Approach

    Directory of Open Access Journals (Sweden)

    Irek Defée

    2008-05-01

    Full Text Available A framework for the unification of statistical and structural information for pattern retrieval based on local feature sets is pre-sented. We use local features constructed from coefficients of quantized block transforms borrowed from video compression which robustly preserving perceptual information under quantization. We then describe statistical information of patterns by histograms of the local features treated as vectors and similarity measure. We show how a pattern retrieval system based on the feature histograms can be optimized in a training process for the best performance. Next, we incorporate structural information description for patterns by considering decomposition of patterns into subareas and considering their feature histograms and their combinations by vectors and similarity measure for retrieval. This description of patterns allows flexible varying of the amount of statistical and structural information; it can also be used with training process to optimize the retrieval performance. The novelty of the presented method is in the integration of information contributed by local features, by statistics of feature distribution, and by controlled inclusion of structural information which are combined into a retrieval system whose parameters at all levels can be adjusted by training which selects contribution of each type of information best for the overall retrieval performance. The pro-posed framework is investigated in experiments using face databases for which standardized test sets and evaluation procedures exist. Results obtained are compared to other methods and shown to be better than for most other approaches.

  13. Observation of photonic anomalous Floquet Topological Insulators

    CERN Document Server

    Maczewsky, Lukas J; Nolte, Stefan; Szameit, Alexander

    2016-01-01

    Commonly, a two-dimensional topological insulator is characterized by non-zero Chern numbers associated with its band structure. In our work, we present the experimental demonstration of an anomalous topological insulator, for which the Chern numbers are always zero, and the winding number is the appropriate quantity describing the topological character of the system. We probe the robustness of the chiral edge states in such anomalous topological insulators and analyze the phase transition between topological and trivial phase.

  14. Detection and analysis of unusual features in the structural model and structure-factor data of a birch pollen allergen

    OpenAIRE

    Rupp, Bernhard

    2012-01-01

    Physically improbable features in the model of the birch pollen structure Bet v 1d (PDB entry 3k78) are faithfully reproduced in electron density generated with the deposited structure factors, but these structure factors themselves exhibit properties that are characteristic of data calculated from a simple model and are inconsistent with the data and error model obtained through experimental measurements. The refinement of the 3k78 model against these structure factors leads to an isomorphou...

  15. Anomalous Josephson Hall effect in magnet/triplet superconductor junctions

    OpenAIRE

    Yokoyama, Takehito

    2015-01-01

    We investigate anomalous Hall effect in a magnet coupled to a triplet superconductor under phase gradient. It is found that the anomalous Hall supercurrent arises from non-trivial structure of the magnetization. The magnetic structure manifested in the Hall supercurrent is characterized by even order terms of the exchange coupling, essentially different from that discussed in the context of anomalous Hall effect, reflecting the disspationless nature of supercurrent. We also discuss a possible...

  16. Anomalous flows in a sunspot penumbra

    CERN Document Server

    Louis, Rohan E; Mathew, Shibu K; Venkatakrishnan, P

    2014-01-01

    High-resolution spectropolarimetric observations of active region NOAA 11271 were obtained with the spectro-polarimeter on board Hinode to analyze the properties of an anomalous flow in the photosphere in a sunspot penumbra. We detect a blue-shifted feature that appeared on the limb-side penumbra of a sunspot and that was present intermittently during the next two hours. It exhibited a maximum blue-shift of 1.6 km/s, an area of 5.2 arcsec^2, and an uninterrupted lifetime of 1 hr. The blue-shifted feature, when present, lies parallel to red-shifts. Both blue and red shifts flank a highly inclined/horizontal magnetic structure that is radially oriented in the penumbra. The low-cadence SP maps reveal changes in size, radial position in the penumbra and line-of-sight velocity of the blue-shifted feature, from one scan to the other. There was an increase of nearly 500 G in the field strength and a marginal reduction in the field inclination of about 10 deg with the onset of the blue-shifts. In the chromosphere, in...

  17. The competitive growth of cubic domains in Ti(1-x)AlxN films studied by diffraction anomalous near-edge structure spectroscopy.

    Science.gov (United States)

    Pinot, Y; Tuilier, M-H; Pac, M-J; Rousselot, C; Thiaudière, D

    2015-11-01

    Titanium and aluminium nitride films deposited by magnetron sputtering generally grow as columnar domains made of oriented nanocrystallites with cubic or hexagonal symmetry depending on Al content, which are embedded in more disordered grain boundaries. The substitution of Al atoms for Ti in the cubic lattice of the films improves their resistance to wear and oxidation, allowing their use as protective coatings. Ti K-edge X-ray absorption spectroscopy, which probes both crystallized and more disordered grain boundaries, and X-ray diffraction anomalous fine structure, which is sensitive to short- and long-range order within a given crystallized domain, are carried out on a set of Ti(1-x)AlxN films deposited by magnetron sputtering on Si substrates. Attention is paid to the shape of the pre-edge region, which is sensitive to the symmetry of the site occupied by Ti atoms, either octahedral in face-centred-cubic Ti-rich (TiN, Ti0.54Al0.46N) samples or tetrahedral in hexagonal-close-packed Al-rich (Ti0.32Al0.68N) films. In order to obain information on the titanium environment in the well crystallized areas, subtraction of the smooth part of the energy-dependent structure factor for the Bragg reflections is applied to the pre-edge region of the diffraction anomalous data in order to restore their spectroscopic appearance. A flat pre-edge is related to the typical octahedral environment of Ti atoms for cubic reflections. The difference observed between pre-edge spectra associated with face-centred-cubic 200 and 111 Bragg reflections of Ti0.54Al0.46N is assigned to Ti enrichment of 111 large well ordered domains compared with the more disordered 200 ones. The sharp peak observed in the spectrum recorded from the hexagonal 002 peak of Ti0.32Al0.68N can be regarded as a standard for the pure tetrahedral Ti environment in hexagonal-close-packed nitride. PMID:26524309

  18. Elusive Structural, Functional, and Immunological Features of Act d 5, the Green Kiwifruit Kiwellin.

    Science.gov (United States)

    Offermann, Lesa R; Giangrieco, Ivana; Perdue, Makenzie L; Zuzzi, Sara; Santoro, Mario; Tamburrini, Maurizio; Cosgrove, Daniel J; Mari, Adriano; Ciardiello, Maria Antonietta; Chruszcz, Maksymilian

    2015-07-29

    Kiwellin (Act d 5) is an allergenic protein contained in kiwifruit pulp in high amounts. The aim of this study was to investigate the three-dimensional structure of the natural molecule from green kiwifruit and its possible function. Kiwellin was crystallized, and its structure, including post-translational modifications, was elucidated. The molecular weight and structural features, in solution, were analyzed by gel filtration and circular dichroism, respectively. Although structurally similar to expansin, kiwellin lacks expansin activity and carbohydrate binding. A specific algorithm was applied to investigate any possible IgE reactivity correlation between kiwellin and a panel of 102 allergens, including expansins and other carbohydrate-binding allergens. The available data suggest a strong dependence of the kiwellin structure on the environmental/experimental conditions. This dependence therefore poses challenges in detecting the correlations between structural, functional, and immunological features of this protein. PMID:26146952

  19. Anomalous gray matter structural networks in patients with hepatitis B virus-related cirrhosis without overt hepatic encephalopathy.

    Directory of Open Access Journals (Sweden)

    Xiao-Fei Lv

    Full Text Available Increasing evidence suggests that cirrhosis may affect the connectivity among different brain regions in patients before overt hepatic encephalopathy (OHE occurs. However, there has been no study investigating the structural reorganization of these altered connections at the network level. The primary focus of this study was to investigate the abnormal topological organization of the structural network in patients with hepatitis B virus-related cirrhosis (HBV-RC without OHE using structural MRI.Using graph theoretical analysis, we compared the global and regional topological properties of gray matter structural networks between 28 patients with HBV-RC without OHE and 30 age-, sex- and education-matched healthy controls. The structural correlation networks were constructed for the two groups based on measures of gray matter volume.The brain network of the HBV-RC group exhibited a significant decrease in the clustering coefficient and reduced small-worldness at the global level across a range of network densities. Regionally, brain areas with altered nodal degree/betweenness centrality were observed predominantly in association cortices (frontal and temporal regions (p < 0.05, uncorrected, including a significantly decreased nodal degree in the inferior temporal gyrus (p < 0.001, uncorrected. Furthermore, the HBV-RC group exhibited a loss of association hubs and the emergence of an increased number of non-association hubs compared with the healthy controls.The results of this large-scale gray matter structural network study suggest reduced topological organization efficiency in patients with HBV-RC without OHE. Our findings provide new insight concerning the mechanisms of neurobiological reorganization in the HBV-RC brain from a network perspective.

  20. Electrical properties and structural features of polycrystalline SmS films

    International Nuclear Information System (INIS)

    Dependences of electric parameters of polycrystalline SmS films (specific resistance, Hall factor, charge carrier mobility) on parameters of film structure (their thickness, crystallite size, lattice parameter) were investigated. The conclusions were made about peculiarities of film growth process, interrelation of mentioned parameters and the reason of relationship between structural and electric parameters. It lies in the fact, that the share of jump conductivity in electric transfer is proportional to Sm=3 ion concentration, which depends on structural features of the film

  1. Fine-structure Constant, Anomalous Magnetic Moment, Relativity Factor and the Golden Ratio that Divides the Bohr Radius

    OpenAIRE

    Heyrovska, R.; Narayan, S

    2005-01-01

    Sommerfeld introduced the fine-structure constant into physics, while he was taking into account the relativistic effects in the theory of the hydrogen atom. Ever since, it has puzzled many scientists like Eddington, Dirac, Feynman and others. Here the mysterious fine-structure constant, alpha = (Compton wavelength/de Broglie wavelength) = 1/137.036 = 2.627/360 is interpreted based on the finding that it is close to 2.618/360 = 1/137.508, where the Compton wavelength for hydrogen is a distanc...

  2. The Future of Primordial Features with Large-Scale Structure Surveys

    CERN Document Server

    Chen, Xingang; Huang, Zhiqi; Namjoo, Mohammad Hossein; Verde, Licia

    2016-01-01

    Primordial features are one of the most important extensions of the Standard Model of cosmology, providing a wealth of information on the primordial universe, ranging from discrimination between inflation and alternative scenarios, new particle detection, to fine structures in the inflationary potential. We study the prospects of future large-scale structure (LSS) surveys on the detection and constraints of these features. We classify primordial feature models into several classes, and for each class we present a simple template of power spectrum that encodes the essential physics. We study how well the most ambitious LSS surveys proposed to date, including both spectroscopic and photometric surveys, will be able to improve the constraints with respect to the current Planck data. We find that these LSS surveys will significantly improve the experimental sensitivity on features signals that are oscillatory in scales, due to the 3D information. For a broad range of models, these surveys will be able to reduce t...

  3. Proceedings of a one-week course on exploiting anomalous scattering in macromolecular structure determination (EMBO'07)

    International Nuclear Information System (INIS)

    This course, which was directed to young scientists, illustrated both theoretical and practical aspects of macromolecular crystal structure solution using synchrotron radiation. Some software dedicated to data collection, processing and analysis were presented. This document gathers only the slides of the presentations

  4. Proceedings of a one-week course on exploiting anomalous scattering in macromolecular structure determination (EMBO'07)

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, M.S.; Shepard, W.; Dauter, Z.; Leslie, A.; Diederichs, K.; Evans, G.; Svensson, O.; Schneider, T.; Bricogne, G.; Dauter, Z.; Flensburg, C.; Terwilliger, T.; Lamzin, V.; Leslie, A.; Kabsch, W.; Flensburg, C.; Terwilliger, T.; Lamzin, V.; Read, R.; Panjikar, S.; Pannu, N.S.; Dauter, Z.; Weiss, M.S.; McSweeney, S

    2007-07-01

    This course, which was directed to young scientists, illustrated both theoretical and practical aspects of macromolecular crystal structure solution using synchrotron radiation. Some software dedicated to data collection, processing and analysis were presented. This document gathers only the slides of the presentations.

  5. Observation of Anomalous Properties associated with the Low Temperature Structural Distortion in β-FeSe and Related Superconductorsa

    Directory of Open Access Journals (Sweden)

    Wu M. K.

    2012-03-01

    Full Text Available The discovery of Superconductivity in the tetragonal phase FeSe provides a unique platform for the detailed investigation of the correlation between the physical properties and crystal structure to better understand the possible origin of superconductivity in the new iron-based superconductors. We have carried out a series of properties characterizations by measuring magnetic susceptibility, Raman, NMR and femtosecond spectroscopy on single crystals and epitaxial thin films of the FeSe and Te-doped Fe(SeTe samples. Our results show clearly the presence of anomalies in all the characterized properties at the temperature where a structural distortion from tetragonal to orthorhombic (or monoclinic appears for all superconducting samples, but not in the non-superconducting ones. This structural distortion was observed not accompanied by a magnetic ordering as commonly occurs in the parent compounds of FeAs-based superconductors. All the observations suggest that the low temperature structural distortion is essential for the occurrence of superconductivity in the FeSe and related compounds. Details of the experimental results will be presented and discussed.

  6. Anomalous structural evolution and liquid fragility signatures in Cu-Zr and Cu-Hf liquids and glasses

    Energy Technology Data Exchange (ETDEWEB)

    Mauro, N. A.; Vogt, Adam J.; Johnson, Mark L.; Bendert, James C.; Soklaski, Ryan; Yang, Li; Kelton, K. F. [WU

    2013-11-18

    The results of high energy X-ray scattering studies of equilibrium and supercooled Cu100-xZrx (x = 46 and 54) and CuxHf100-x (x = 55 and 60.8) liquids and the corresponding glasses are presented. The liquid data were obtained in a containerless environment using the beamline electrostatic levitation (BESL) technique. The total structure factor and total pair correlation functions were measured as a function of temperature for the liquids, and for the glasses at room temperature. A developing asymmetry in the peak of the first coordination shell in the total pair correlation function suggests chemical ordering in the liquids with cooling. This asymmetry takes the form of two prominent peaks, suggesting two prominent ordering length scales. When the magnitudes of these peaks are extrapolated to the glass transition temperature a discontinuity is observed, indicating that an abrupt increase in the magnitude is required to match the observed peak heights in the glass. This suggests that the structure of the supercooled liquid orders more rapidly near the glass transition temperature, a conclusion that is supported by molecular dynamics simulations. This observed structural evolution of the liquid indicates that the concept of fragility, typically defined from the behavior of viscosity with temperature, has a measurable structural signature as well, which can be observed in X-ray diffraction studies.

  7. Isocolic Structures and Graphemic Features in the Croatian Church Slavic Regula Sancti Benedicti

    OpenAIRE

    Denis Crnković

    2006-01-01

    Isocolic Structures and Graphemic Features in the Croatian Church Slavic Regula Sancti Benedicti The article discusses the presence of the isocolon in the Croatian Church Slavic translation of the Regula Sancti Benedicti in light of the graphemic features of the fourteenth century codex unicus. After a brief review of the scholarly literature on the use of the isocolon in medieval Slavic literature in general and medieval Croatian literature in particular, the article looks in detail at ...

  8. Relevance of Echo-Structure and Texture Features: An Application in Ultrasound Breast Tumor Classification

    DEFF Research Database (Denmark)

    Karemore, Gopal Raghunath; Mullick, Jhinuk Basu; KV, Dr. Rajagopal;

    2011-01-01

    Aim: Echostructure is an essential parameter for the evaluation of circumscribed lesions and can be described as a texture feature on ultrasound images. Present study evaluates the possibility of distinguishing between benign and malignant breast tumors using various texture features. Materials a...... only are the shape and size but also the echo structure of the mass is important. This technique can be considered as assistance to the radiologist to provide additional information in differentiation of benign from malignant findings....

  9. Anomalous Chiral Superfluidity

    OpenAIRE

    Lublinsky, Michael(Physics Department, Ben-Gurion University of the Negev, Beer Sheva 84105, Israel); Zahed, Ismail

    2009-01-01

    We discuss both the anomalous Cartan currents and the energy-momentum tensor in a left chiral theory with flavour anomalies as an effective theory for flavored chiral phonons in a chiral superfluid with the gauged Wess-Zumino-Witten term. In the mean-field (leading tadpole) approximation the anomalous Cartan currents and the energy momentum tensor take the form of constitutive currents in the chiral superfluid state. The pertinence of higher order corrections and the Adler-Bardeen theorem is ...

  10. The 3-loop non-singlet heavy flavor contributions and anomalous dimensions for the structure function F2(x,Q2) and transversity

    Science.gov (United States)

    Ablinger, J.; Behring, A.; Blümlein, J.; De Freitas, A.; Hasselhuhn, A.; von Manteuffel, A.; Round, M.; Schneider, C.; Wißbrock, F.

    2014-09-01

    We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function F2(x,Q2) in the asymptotic region Q2≫m2 and the associated operator matrix element Aqq,Q(3),NS(N) to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable N. This matrix element is associated with the vector current and axial vector current for the even and the odd moments N, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to O(NF) and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in N space and harmonic polylogarithms in x-space. Numerical results are presented for the non-singlet charm quark contribution to F2(x,Q2).

  11. The 3-loop non-singlet heavy flavor contributions and anomalous dimensions for the structure function F2(x,Q2 and transversity

    Directory of Open Access Journals (Sweden)

    J. Ablinger

    2014-09-01

    Full Text Available We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function F2(x,Q2 in the asymptotic region Q2≫m2 and the associated operator matrix element Aqq,Q(3,NS(N to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable N. This matrix element is associated with the vector current and axial vector current for the even and the odd moments N, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to O(NF and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in N space and harmonic polylogarithms in x-space. Numerical results are presented for the non-singlet charm quark contribution to F2(x,Q2.

  12. The 3-Loop Non-Singlet Heavy Flavor Contributions and Anomalous Dimensions for the Structure Function $F_2(x,Q^2)$ and Transversity

    CERN Document Server

    Ablinger, J; Blümlein, J; De Freitas, A; Hasselhuhn, A; von Manteuffel, A; Round, M; Schneider, C; Wißbrock, F

    2014-01-01

    We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function $F_2(x,Q^2)$ in the asymptotic region $Q^2 \\gg m^2$ and the associated operator matrix element $A_{qq,Q}^{(3), \\rm NS}(N)$ to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable $N$. This matrix element is associated to the vector current and axial vector current for the even and the odd moments $N$, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to $O(N_F)$ and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in $N$ space and harmonic polylogarithms in $x$-space. Numerical results are presented for the non-singlet charm quark contribution to $F_2(x,Q^2)$.

  13. The 3-loop non-singlet heavy flavor contributions and anomalous dimensions for the structure function F2(x,Q2) and transversity

    International Nuclear Information System (INIS)

    We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function F2(x,Q2) in the asymptotic region Q2>>m2 and the associated operator matrix element A(3),NSqq,Q (N) to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable N. This matrix element is associated to the vector current and axial vector current for the even and the odd moments N, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to O(NF) and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in N space and harmonic polylogarithms in x-space. Numerical results are presented for the non-singlet charm quark contribution to F2(x,Q2).

  14. Structural Origin of the Anomalous Temperature Dependence of the Local Magnetic Moments in the CaFe2As2 Family of Materials

    Science.gov (United States)

    Ortenzi, L.; Gretarsson, H.; Kasahara, S.; Matsuda, Y.; Shibauchi, T.; Finkelstein, K. D.; Wu, W.; Julian, S. R.; Kim, Young-June; Mazin, I. I.; Boeri, L.

    2015-01-01

    We report a combination of Fe K β x-ray emission spectroscopy and density functional reduced Stoner theory calculations to investigate the correlation between structural and magnetic degrees of freedom in CaFe2(As1-xPx) 2 . The puzzling temperature behavior of the local moment found in rare earth-doped CaFe2As2 [H. Gretarsson et al., Phys. Rev. Lett. 110, 047003 (2013)] is also observed in CaFe2(As1-xPx) 2 . We explain this phenomenon based on first-principles calculations with scaled magnetic interaction. One scaling parameter is sufficient to describe quantitatively the magnetic moments in both CaFe2(As1-xPx) 2 (x =0.055 ) and Ca0.78La0.22Fe2As2 at all temperatures. The anomalous growth of the local moments with increasing temperature can be understood from the observed large thermal expansion of the c -axis lattice parameter combined with strong magnetoelastic coupling. These effects originate from the strong tendency to form As-As dimers across the Ca layer in the CaFe2As2 family of materials. Our results emphasize the dual local-itinerant character of magnetism in Fe pnictides.

  15. The 3-loop non-singlet heavy flavor contributions and anomalous dimensions for the structure function F{sub 2}(x,Q{sup 2}) and transversity

    Energy Technology Data Exchange (ETDEWEB)

    Ablinger, J. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Behring, A.; Blümlein, J.; De Freitas, A. [Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Hasselhuhn, A. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Manteuffel, A. von [PRISMA Cluster of Excellence and Institute of Physics, J. Gutenberg University, D-55099 Mainz (Germany); Round, M. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Schneider, C. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Wißbrock, F. [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstraße 69, A-4040 Linz (Austria); Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany)

    2014-09-15

    We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function F{sub 2}(x,Q{sup 2}) in the asymptotic region Q{sup 2}≫m{sup 2} and the associated operator matrix element A{sub qq,Q}{sup (3),NS}(N) to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable N. This matrix element is associated with the vector current and axial vector current for the even and the odd moments N, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to O(N{sub F}) and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in N space and harmonic polylogarithms in x-space. Numerical results are presented for the non-singlet charm quark contribution to F{sub 2}(x,Q{sup 2})

  16. The 3-loop non-singlet heavy flavor contributions and anomalous dimensions for the structure function F{sub 2}(x,Q{sup 2}) and transversity

    Energy Technology Data Exchange (ETDEWEB)

    Ablinger, J.; Hasselhuhn, A.; Schneider, C. [Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation; Behring, A.; Bluemlein, J.; Freitas, A. de [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Manteuffel, A. von [Mainz Univ. (Germany). PRISMA Cluster of Excellence; Mainz Univ. (Germany). Inst. fuer Physik; Round, M.; Wissbrock, F. [Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation; Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany)

    2014-06-15

    We calculate the massive flavor non-singlet Wilson coefficient for the heavy flavor contributions to the structure function F{sub 2}(x,Q{sup 2}) in the asymptotic region Q{sup 2}>>m{sup 2} and the associated operator matrix element A{sup (3),NS}{sub qq,Q} (N) to 3-loop order in Quantum Chromodynamics at general values of the Mellin variable N. This matrix element is associated to the vector current and axial vector current for the even and the odd moments N, respectively. We also calculate the corresponding operator matrix elements for transversity, compute the contributions to the 3-loop anomalous dimensions to O(N{sub F}) and compare to results in the literature. The 3-loop matching of the flavor non-singlet distribution in the variable flavor number scheme is derived. All results can be expressed in terms of nested harmonic sums in N space and harmonic polylogarithms in x-space. Numerical results are presented for the non-singlet charm quark contribution to F{sub 2}(x,Q{sup 2}).

  17. Structural attributes for the recognition of weak and anomalous regions in coiled-coils of myosins and other motor proteins

    OpenAIRE

    Sunitha Margaret S; Nair Anu G; Charya Amol; Jadhav Kamalakar; Mukhopadhyay Sami; Sowdhamini Ramanathan

    2012-01-01

    Abstract Background Coiled-coils are found in different proteins like transcription factors, myosin tail domain, tropomyosin, leucine zippers and kinesins. Analysis of various structures containing coiled-coils has revealed the importance of electrostatic and hydrophobic interactions. In such domains, regions of different strength of interactions need to be identified since they could be biologically relevant. Findings We have updated our coiled-coil validation webserver, now called COILCHECK...

  18. A Global Image Feature Construction Metho d Based on Local Jet Structure

    Institute of Scientific and Technical Information of China (English)

    XIE Jin; CAI Zi-Xing

    2014-01-01

    This article presents a novel and robust feature descriptor called the multi-scale autoconvolution on local jet structure (MSALJS), which is quasi-invariant to affine transformation. The MSALJS, a global image feature descriptor, is based on the deriva-tives that describe the image local structure to compute the multi-scale autoconvolution moment. Experimental data demonstrate that the MSALJS can be used in practical applications in which the object is deformed in various ways, such as particular occlusion, view angle change, and so on.

  19. Features Of Household Lexics, Their Characteristics And Structural Analysis In The Modern English Language

    Directory of Open Access Journals (Sweden)

    Aygun Yusifova

    2014-04-01

    Full Text Available The present paper aims to analyze the most inherent features and characteristics of household lexis in English. Special emphasis has been placed on their names of the objects used in everyday life, kitchen utensils, animal and birds. Lexical units concerning ceremonies, habits and traditions are also among the scope of the paper. Moreover, the study deals with the structural features of the units under consideration. It is believed that the thematic-semantic characterization of every-day lexis can have both pedagogical and linguistic implications, especially when dealing with comparative structures.

  20. Anomalous screening in two-dimensional materials with an extremum ring in the dispersion law

    OpenAIRE

    Kolomeisky, Eugene B.; Straley, Joseph P.

    2016-01-01

    A variety of two-dimensional materials possess a band structure with an energy extremal ridge along a ring in momentum space. Examples are biased bilayer graphene, and surfaces and interfaces with a Rashba spin-orbit interaction where at low doping the carriers fill an annulus. This topological feature causes an anomalous screening behavior, which we study using the Thomas-Fermi theory. Specifically, reducing the doping is predicted to enhance the linear screening response, while at zero dopi...

  1. Fine-structure Constant, Anomalous Magnetic Moment, Relativity Factor and the Golden Ratio that Divides the Bohr Radius

    CERN Document Server

    Heyrovska, R

    2005-01-01

    Sommerfeld introduced the fine-structure constant into physics, while he was taking into account the relativistic effects in the theory of the hydrogen atom. Ever since, it has puzzled many scientists like Eddington, Dirac, Feynman and others. Here the mysterious fine-structure constant, alpha = (Compton wavelength/de Broglie wavelength) = 1/137.036 = 2.627/360 is interpreted based on the finding that it is close to 2.618/360 = 1/137.508, where the Compton wavelength for hydrogen is a distance equivalent to an arc length on the circumference (given by the de Broglie wavelength) of a circle with the Bohr radius and 2.618 is the square of the Golden ratio, which was recently shown to divide the Bohr radius into two Golden sections at the point of electrical neutrality. From the data for the electron (e) and proton (p) g-factors, it is found that (137.508 - 137.036)= 0.472 = [g(p) - g(e)]/[g(p) + g(e)] (= 2/cube of the Golden ratio), and that (2.627 - 2.618)/360 = (small part of the Compton wavelength correspond...

  2. Anomalous Resistance in Critical Ionization Velocity Phenomena

    CERN Document Server

    Badin, V I

    2001-01-01

    To describe the generation of the electric field by a discontinuity of the Hall current, an equation of the third order is obtained using the electric charge conservation and Ohm laws. The solutions of this equation are used to model the electric impulses detected in experiments aimed to verify Alfven's hypothesis on the critical ionization velocity at collisions of neutral gas with magnetized plasma. A quantitative agreement with experiment is attained and the main features of measured signals are modeled under an assumption on the strong anomalous resistance behind the discontinuity. Apparently, the anomalous resistance occurs due to trapping the current carriers by a small-scaled modulation of the electric field.

  3. Structural class prediction of protein using novel feature extraction method from chaos game representation of predicted secondary structure.

    Science.gov (United States)

    Zhang, Lichao; Kong, Liang; Han, Xiaodong; Lv, Jinfeng

    2016-07-01

    Protein structural class prediction plays an important role in protein structure and function analysis, drug design and many other biological applications. Extracting good representation from protein sequence is fundamental for this prediction task. In recent years, although several secondary structure based feature extraction strategies have been specially proposed for low-similarity protein sequences, the prediction accuracy still remains limited. To explore the potential of secondary structure information, this study proposed a novel feature extraction method from the chaos game representation of predicted secondary structure to mainly capture sequence order information and secondary structure segments distribution information in a given protein sequence. Several kinds of prediction accuracies obtained by the jackknife test are reported on three widely used low-similarity benchmark datasets (25PDB, 1189 and 640). Compared with the state-of-the-art prediction methods, the proposed method achieves the highest overall accuracies on all the three datasets. The experimental results confirm that the proposed feature extraction method is effective for accurate prediction of protein structural class. Moreover, it is anticipated that the proposed method could be extended to other graphical representations of protein sequence and be helpful in future research. PMID:27084358

  4. Automatic classification of hepatocellular carcinoma images based on nuclear and structural features

    Science.gov (United States)

    Kiyuna, Tomoharu; Saito, Akira; Marugame, Atsushi; Yamashita, Yoshiko; Ogura, Maki; Cosatto, Eric; Abe, Tokiya; Hashiguchi, Akinori; Sakamoto, Michiie

    2013-03-01

    Diagnosis of hepatocellular carcinoma (HCC) on the basis of digital images is a challenging problem because, unlike gastrointestinal carcinoma, strong structural and morphological features are limited and sometimes absent from HCC images. In this study, we describe the classification of HCC images using statistical distributions of features obtained from image analysis of cell nuclei and hepatic trabeculae. Images of 130 hematoxylin-eosin (HE) stained histologic slides were captured at 20X by a slide scanner (Nanozoomer, Hamamatsu Photonics, Japan) and 1112 regions of interest (ROI) images were extracted for classification (551 negatives and 561 positives, including 113 well-differentiated positives). For a single nucleus, the following features were computed: area, perimeter, circularity, ellipticity, long and short axes of elliptic fit, contour complexity and gray level cooccurrence matrix (GLCM) texture features (angular second moment, contrast, homogeneity and entropy). In addition, distributions of nuclear density and hepatic trabecula thickness within an ROI were also extracted. To represent an ROI, statistical distributions (mean, standard deviation and percentiles) of these features were used. In total, 78 features were extracted for each ROI and a support vector machine (SVM) was trained to classify negative and positive ROIs. Experimental results using 5-fold cross validation show 90% sensitivity for an 87.8% specificity. The use of statistical distributions over a relatively large area makes the HCC classifier robust to occasional failures in the extraction of nuclear or hepatic trabecula features, thus providing stability to the system.

  5. A MATLAB Based Algorithm Design for New Structural Feature of Retinal Image Vasculature Pattern

    Directory of Open Access Journals (Sweden)

    Udaya Kumar Naluguru

    2013-01-01

    Full Text Available In this paper we illustrate the different point types in retinal images. The bifurcation structure is composed of a master bifurcation point and three connected neighbors. In this paper we present the illustration of featured based method, which is explained in detail and further image registration results are also discussed in detail. The advantage of the proposed structure-matching approach is the ability to handle translation, rotation and scaling with the available vascular trees of image pairs.

  6. Hydration characteristics and morphological features of concretes from structures in Australia, England and the United States

    International Nuclear Information System (INIS)

    Scanning electron microscope studies were carried out on concretes obtained from structures in Australia, England and the United States as part of an assessment of their durability performances. The ages of the structures ranged from nine to thirty years. All structures contained fly ash concretes in some sections, and, in a few cases, direct comparison between these concretes and ordinary portland cement (OPC) concretes was possible. Water: cement ratios of the concretes varied from 0.44 to 0.90. The sources of fly ash were identified in each case. The structures chosen had a range of use classifications encompassing building, hydraulic structures, bridge structures, towers and foundations. Deterioration effects of concretes in some structures were more common than in others. Based on observations, conclusions were drawn on the morphological features and hydration characteristics of the concretes

  7. Template Matching Method Based on Visual Feature Constraint and Structure Constraint

    Science.gov (United States)

    Li, Zhu; Tomotsune, Kojiro; Tomioka, Yoichi; Kitazawa, Hitoshi

    Template matching for image sequences captured with a moving camera is very important for several applications such as Robot Vision, SLAM, ITS, and video surveillance systems. However, it is difficult to realize accurate template matching using only visual feature information such as HSV histograms, edge histograms, HOG histograms, and SIFT features, because it is affected by several phenomena such as illumination change, viewpoint change, size change, and noise. In order to realize robust tracking, structure information such as the relative position of each part of the object should be considered. In this paper, we propose a method that considers both visual feature information and structure information. Experiments show that the proposed method realizes robust tracking and determine the relationships between object parts in the scenes and those in the template.

  8. Man-made Object Detection Based on Texture Clustering and Geometric Structure Feature Extracting

    Directory of Open Access Journals (Sweden)

    Fei Cai

    2011-03-01

    Full Text Available Automatic aerial image interpretation is one of new rising high-tech application fields, and it’s proverbially applied in the military domain. Based on human visual attention mechanism and texture visual perception, this paper proposes a new approach for man-made object detection and marking by extracting texture and geometry structure features. After clustering the texture feature to realize effective image segmentation, geometry structure feature is obtained to achieve final detection and marking. Thus a man-made object detection methodology is designed, by which typical man-made objects in complex natural background, including airplanes, tanks and vehicles can be detected. The experiments sustain that the proposed method is effective and rational.

  9. Can artificial reefs mimic natural reef communities? The roles of structural features and age.

    Science.gov (United States)

    Perkol-Finkel, S; Shashar, N; Benayahu, Y

    2006-03-01

    In light of the deteriorating state of coral reefs worldwide, the need to rehabilitate marine environments has greatly increased. Artificial reefs (ARs) have been suggested as a tool for reef conservation and rehabilitation. Although successions of AR communities have been thoroughly studied, current understanding of the interactions between artificial and natural reefs (NRs) is poor and a fundamental question still to be answered is that of whether AR communities can mimic adjacent NR communities. We suggest three alternative hypotheses: Neighboring ARs and NRs will (1) achieve a similar community structure given sufficient time; (2) be similar only if they possess similar structural features; (3) always differ, regardless of age or structural features. We examined these hypotheses by comparing the community structure on a 119-year old shipwreck to a neighboring NR. Fouling organisms, including stony and soft corals, sponges, tunicates, sea anemones and hydrozoans were recorded and measured along belt transects. The ahermatypic stony coral Tubastrea micrantha dominated vertical AR regions while the soft corals Nephthea sp. and Xenia sp. dominated both artificial and natural horizontal surfaces. Our results support the second hypothesis, indicating that even after a century an AR will mimic its adjacent NR communities only if it possesses structural features similar to those of the natural surroundings. However, if the two differ structurally, their communities will remain distinct. PMID:16198411

  10. Multiple-valued Feature Structure Description%多值特征结构描述

    Institute of Scientific and Technical Information of China (English)

    于江生; 程民德

    1999-01-01

    提出了信念格上的多值非循环有限自动机并给出了特征和的算法,分别与Rounds-Kasper和Dawar-Shanker的非循环有限自动机相比较,这一理论扩展了自然语言语义运算的能力.定义了最小不相容特征描述逻辑和它的语义,并为该逻辑提供了一个充分且完备的证明系统.最后,证明了最小不相容特征描述逻辑的可满足性问题是NP-完全的.%Feature structures are used in represention of linguistic knowledge. Rounds and Kasper proposed the acyclic finite automaton to describe the feature structures (f-structures) on which RoundsKasper Logic is defined. Later, several persons proposed various logics that include negation in RoundsKasper-like framework. In this article, a description of multiple-valued feature structures based on belief lattice is established, which extends the ability of semantic operations. Then, Minimally Inconsistent Feature Description Logic and its semantics are defined. We also showed some properties of them. Finally, we presented a sound and complete proof system for our logic and a theorem of NP-completeness.

  11. A novel feature of structural variegation in leaves of the tropical plant Schismatoglottis calyptrata.

    Science.gov (United States)

    Tsukaya, Hirokazu; Okada, Hiroshi; Mohamed, Maryati

    2004-12-01

    We report a novel feature of leaf variegation. As is often the case in tropical forest floor herbs, Schismatoglottis calyptrata leaves feature structural variegation. Examination of leaf anatomy in S. calyptrata revealed a novel feature of structural variegation, which was generated by variation in the spatial arrangement of the adaxial-most tip of the palisade cells. In fully green leaf parts, contact between the adaxial-most tip of the palisade cells and the cone-shaped base of the outer epidermis cells was tight, and palisade cells were arranged radially around each epidermal cell. In dull, grayish-green leaf parts, the contact was loose, and no particular spatial arrangement of palisade cells relative to epidermal cells was observed. This feature of structural variation could be disadvantageous for photosynthesis efficiency in view of the hypothesis that, for rainforest herbs, cone-shaped epidermal cells may function as lenses. However, the high frequency of leaf variegation of S. calyptrata in natural habits suggests that this structural variegation plays an unknown advantageous role. PMID:15538654

  12. A deep learning framework for modeling structural features of RNA-binding protein targets.

    Science.gov (United States)

    Zhang, Sai; Zhou, Jingtian; Hu, Hailin; Gong, Haipeng; Chen, Ligong; Cheng, Chao; Zeng, Jianyang

    2016-02-29

    RNA-binding proteins (RBPs) play important roles in the post-transcriptional control of RNAs. Identifying RBP binding sites and characterizing RBP binding preferences are key steps toward understanding the basic mechanisms of the post-transcriptional gene regulation. Though numerous computational methods have been developed for modeling RBP binding preferences, discovering a complete structural representation of the RBP targets by integrating their available structural features in all three dimensions is still a challenging task. In this paper, we develop a general and flexible deep learning framework for modeling structural binding preferences and predicting binding sites of RBPs, which takes (predicted) RNA tertiary structural information into account for the first time. Our framework constructs a unified representation that characterizes the structural specificities of RBP targets in all three dimensions, which can be further used to predict novel candidate binding sites and discover potential binding motifs. Through testing on the real CLIP-seq datasets, we have demonstrated that our deep learning framework can automatically extract effective hidden structural features from the encoded raw sequence and structural profiles, and predict accurate RBP binding sites. In addition, we have conducted the first study to show that integrating the additional RNA tertiary structural features can improve the model performance in predicting RBP binding sites, especially for the polypyrimidine tract-binding protein (PTB), which also provides a new evidence to support the view that RBPs may own specific tertiary structural binding preferences. In particular, the tests on the internal ribosome entry site (IRES) segments yield satisfiable results with experimental support from the literature and further demonstrate the necessity of incorporating RNA tertiary structural information into the prediction model. The source code of our approach can be found in https

  13. Anomalous Higgs couplings

    CERN Document Server

    González-Garciá, M Concepción

    1999-01-01

    We review the effects of new effective interactions on Higgs-boson phenomenology. New physics in the electroweak bosonic sector is expected to induce additional interactions between the Higgs doublet field and the electroweak gauge bosons, leading to anomalous Higgs couplings as well as anomalous gauge-boson self-interactions. Using a linearly realized SU(2)/sub L/*U(1)/sub Y/ invariant effective Lagrangian to describe the bosonic sector of the Standard Model, we review the effects of the new effective interactions on the Higgs- boson production rates and decay modes. We summarize the results from searches for the new Higgs signatures induced by the anomalous interactions in order to constrain the scale of new physics, in particular at CERN LEP and Fermilab Tevatron colliders. (43 refs).

  14. Nonlocal sparse model with adaptive structural clustering for feature extraction of aero-engine bearings

    Science.gov (United States)

    Zhang, Han; Chen, Xuefeng; Du, Zhaohui; Li, Xiang; Yan, Ruqiang

    2016-04-01

    Fault information of aero-engine bearings presents two particular phenomena, i.e., waveform distortion and impulsive feature frequency band dispersion, which leads to a challenging problem for current techniques of bearing fault diagnosis. Moreover, although many progresses of sparse representation theory have been made in feature extraction of fault information, the theory also confronts inevitable performance degradation due to the fact that relatively weak fault information has not sufficiently prominent and sparse representations. Therefore, a novel nonlocal sparse model (coined NLSM) and its algorithm framework has been proposed in this paper, which goes beyond simple sparsity by introducing more intrinsic structures of feature information. This work adequately exploits the underlying prior information that feature information exhibits nonlocal self-similarity through clustering similar signal fragments and stacking them together into groups. Within this framework, the prior information is transformed into a regularization term and a sparse optimization problem, which could be solved through block coordinate descent method (BCD), is formulated. Additionally, the adaptive structural clustering sparse dictionary learning technique, which utilizes k-Nearest-Neighbor (kNN) clustering and principal component analysis (PCA) learning, is adopted to further enable sufficient sparsity of feature information. Moreover, the selection rule of regularization parameter and computational complexity are described in detail. The performance of the proposed framework is evaluated through numerical experiment and its superiority with respect to the state-of-the-art method in the field is demonstrated through the vibration signals of experimental rig of aircraft engine bearings.

  15. Discriminative analysis of schizophrenia using support vector machine and recursive feature elimination on structural MRI images.

    Science.gov (United States)

    Lu, Xiaobing; Yang, Yongzhe; Wu, Fengchun; Gao, Minjian; Xu, Yong; Zhang, Yue; Yao, Yongcheng; Du, Xin; Li, Chengwei; Wu, Lei; Zhong, Xiaomei; Zhou, Yanling; Fan, Ni; Zheng, Yingjun; Xiong, Dongsheng; Peng, Hongjun; Escudero, Javier; Huang, Biao; Li, Xiaobo; Ning, Yuping; Wu, Kai

    2016-07-01

    Structural abnormalities in schizophrenia (SZ) patients have been well documented with structural magnetic resonance imaging (MRI) data using voxel-based morphometry (VBM) and region of interest (ROI) analyses. However, these analyses can only detect group-wise differences and thus, have a poor predictive value for individuals. In the present study, we applied a machine learning method that combined support vector machine (SVM) with recursive feature elimination (RFE) to discriminate SZ patients from normal controls (NCs) using their structural MRI data. We first employed both VBM and ROI analyses to compare gray matter volume (GMV) and white matter volume (WMV) between 41 SZ patients and 42 age- and sex-matched NCs. The method of SVM combined with RFE was used to discriminate SZ patients from NCs using significant between-group differences in both GMV and WMV as input features. We found that SZ patients showed GM and WM abnormalities in several brain structures primarily involved in the emotion, memory, and visual systems. An SVM with a RFE classifier using the significant structural abnormalities identified by the VBM analysis as input features achieved the best performance (an accuracy of 88.4%, a sensitivity of 91.9%, and a specificity of 84.4%) in the discriminative analyses of SZ patients. These results suggested that distinct neuroanatomical profiles associated with SZ patients might provide a potential biomarker for disease diagnosis, and machine-learning methods can reveal neurobiological mechanisms in psychiatric diseases. PMID:27472673

  16. AFM and XPA data on structural features and properties of films and powders based on naphthalocyanines

    Science.gov (United States)

    Ramonova, A. G.; Nakusov, A. T.; Sozanov, V. G.; Bliev, A. P.; Magkoev, T. T.

    2015-06-01

    The template synthesis is used to produce powders and films based on naphthalocyanines and the corresponding metal complexes (Pc, CuPc, and NiPc). The atomic-force microscopy (AFM) and X-ray phase analysis (XPA) are employed in the study of structure and phase of fine powders and nanostructured films. The AFM data are used to determine the orientation and density of primary particles packed in the film. The XPA method is used to study the chemical composition and crystal structure of the synthesized samples. The regularities related to the structural features that affect the electrophysical properties of the films under study are revealed.

  17. Anomalous law of cooling

    Energy Technology Data Exchange (ETDEWEB)

    Lapas, Luciano C., E-mail: luciano.lapas@unila.edu.br [Universidade Federal da Integração Latino-Americana, Caixa Postal 2067, 85867-970 Foz do Iguaçu, Paraná (Brazil); Ferreira, Rogelma M. S., E-mail: rogelma.maria@gmail.com [Centro de Ciências Exatas e Tecnológicas, Universidade Federal do Recôncavo da Bahia, 44380-000 Cruz das Almas, Bahia (Brazil); Rubí, J. Miguel, E-mail: mrubi@ub.edu [Departament de Física Fonamental, Facultat de Física, Universitat de Barcelona, Av. Diagonal 647, 08028 Barcelona (Spain); Oliveira, Fernando A., E-mail: fernando.oliveira@pq.cnpq.br [Instituto de Física and Centro Internacional de Física da Matéria Condensada, Universidade de Brasília, Caixa Postal 04513, 70919-970 Brasília, Distrito Federal (Brazil)

    2015-03-14

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton’s law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics.

  18. Anomalous gauge boson interactions

    International Nuclear Information System (INIS)

    We discuss the direct measurement of the trilinear vector boson couplings in present and future collider experiments. The major goals of such experiments will be the confirmation of the Standard Model (SM) predictions and the search for signals of new physics. We review our current theoretical understanding of anomalous trilinear gauge-boson self interactions. If the energy scale of the new physics is ∼ 1 TeV, these low energy anomalous couplings are expected to be no larger than Ο(10-2). Constraints from high precision measurements at LEP and low energy charged and neutral current processes are critically reviewed

  19. Anomalous law of cooling

    International Nuclear Information System (INIS)

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton’s law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics

  20. Anomalous law of cooling

    Science.gov (United States)

    Lapas, Luciano C.; Ferreira, Rogelma M. S.; Rubí, J. Miguel; Oliveira, Fernando A.

    2015-03-01

    We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton's law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics.

  1. Anomalous transport effects in magnetically-confined plasma columns

    International Nuclear Information System (INIS)

    The evolution of density structure in a magnetized plasma column is analyzed accounting for anomalous diffusion due to the lower hybrid drift instability. The plasma column is found to be divided into regions of classical, anomalous, and intermediate diffusivity. The bulk behavior, described in terms of radial confinement time, depends most sensitively upon the particle line density (ion/cm). For broad plasmas (large line density), the transport is characteristic of classical diffusion, and for slender plasmas (small line density) the transport is characteristic of anomalous diffusion. For intermediate line densities, the transport undertakes a rapid transition from classical to anomalous. Correlations between the theoretical results and past experiments are described

  2. Detecting Structural Features in Metallic Glass via Synchrotron Radiation Experiments Combined with Simulations

    Directory of Open Access Journals (Sweden)

    Gu-Qing Guo

    2015-11-01

    Full Text Available Revealing the essential structural features of metallic glasses (MGs will enhance the understanding of glass-forming mechanisms. In this work, a feasible scheme is provided where we performed the state-of-the-art synchrotron-radiation based experiments combined with simulations to investigate the microstructures of ZrCu amorphous compositions. It is revealed that in order to stabilize the amorphous state and optimize the topological and chemical distribution, besides the icosahedral or icosahedral-like clusters, other types of clusters also participate in the formation of the microstructure in MGs. This cluster-level co-existing feature may be popular in this class of glassy materials.

  3. Structural details of the Orion Nebula - Detection of a network of stringlike ionized features

    Energy Technology Data Exchange (ETDEWEB)

    Yusef-Zadeh, F. (Northwestern Univ., Evanston, IL (USA))

    1990-09-01

    Continuum observations of the Orion Nebula, obtained at 20 cm using the A, B, C, and D configurations of the VLA during 1986-1987, are reported. Radio images of resolution 1.8 x 1.6 arcsec are presented and analyzed, with a focus on (1) the complex cone structure of M 42 and (2) an extended network of bright stringlike features concentrated near the Trapezium cluster. Possible theoretical explanations of these features are explored, starting from the blister model of H II regions developed by Tenorio and Tagle (1979). 28 refs.

  4. Structural details of the Orion Nebula - Detection of a network of stringlike ionized features

    International Nuclear Information System (INIS)

    Continuum observations of the Orion Nebula, obtained at 20 cm using the A, B, C, and D configurations of the VLA during 1986-1987, are reported. Radio images of resolution 1.8 x 1.6 arcsec are presented and analyzed, with a focus on (1) the complex cone structure of M 42 and (2) an extended network of bright stringlike features concentrated near the Trapezium cluster. Possible theoretical explanations of these features are explored, starting from the blister model of H II regions developed by Tenorio and Tagle (1979). 28 refs

  5. Structural Features of Human Memapsin 2 (β-Secretase) and Their Biological and Pathological Implications

    Institute of Scientific and Technical Information of China (English)

    Lin HONG; Xiangyuan HE; Xiangping HUANG; Wanpin CHANG; Jordan TANG

    2004-01-01

    Memapsin 2 (β-secretase) is the membrane-anchored aspartic protease that initiates the cleavage of β-amyloid precursor protein (APP) leading to the production of amyloid-β (Aβ), a major factor in the pathogenesis of Alzheimer's disease (AD). Since memapsin 2 is a major target for the development of inhibitor drugs for AD, it has been intensively studied during the past five years. Here we discuss the structural features of the catalytic/specificity apparatus, transmembrane domain, cytosolic domain and the implications of these features in the physiological and pathological roles of this protease.

  6. Structural phase transition causing anomalous photoluminescence behavior in perovskite (C6H11NH3)2[PbI4

    International Nuclear Information System (INIS)

    Optical and structural properties of the organic-inorganic hybrid perovskite-type (C6H11NH3)2[PbI4] (abbreviated as C6PbI4) were investigated using optical absorption, photoluminescence (PL), and x-ray diffraction measurements. Room temperature, optical absorption measurements, performed on spin-coated films of C6PbI4, revealed two absorption bands at 2.44 and 3.21 eV. Upon 325 nm (3.815 eV) laser irradiation, strong green PL emission peaks were observed at 2.41 eV (P1) and 2.24 eV (P2) and assigned to free and localized excitons, respectively. The exciton binding energy was estimated at 356 meV. At low temperature, two additional emission bands were detected at 2.366 eV (P3) and a large band (LB) at 1.97 eV. The former appeared only below 40 K and the latter emerged below 130 K. The thermal dependence of the PL spectra revealed an abnormal behavior accompanied by singularities in the peak positions and intensities at 40 and 130 K. X-ray diffraction studies performed on powder and single crystals as a function of temperature evidenced significant changes of the interlayer spacing at 50 K and ∼138 K. Around 138 K, a commensurate to incommensurate structural phase transition occurred on cooling. It involves a symmetry breaking leading to a distortion of the PbI6 octahedron. The resulting incommensurate spatial modulation of the Pb–I distances (and Pb–I–Pb angles) causes a spatial modulation of the band gap, which is at the origin of the emergence of the LB below ∼130 K and the anomalous behavior of the position of P1 below 130 K. The change of the interlayer spacing in the 40-50 K range may in turn be related to the significant decrease of the intensity of P2 and the maximum emission of the LB. These results underline the intricate character of the structural and the PL properties of the hybrid perovskites; understanding such properties should benefit to the design of optoelectronic devices with targeted properties

  7. Structural phase transition causing anomalous photoluminescence behavior in perovskite (C{sub 6}H{sub 11}NH{sub 3}){sub 2}[PbI{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Yangui, A. [Groupe d’Etudes de la Matière Condensée, UMR CNRS 8653-Université de Versailles Saint Quentin En Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles (France); Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, Route de Soukra km 3.5 BP 1171, 3018 Sfax (Tunisia); Pillet, S. [Laboratoire de Cristallographie, Résonance Magnétique et Modélisations, UMR-CNRS 7036, Institut Jean Barriol, Université de Lorraine, BP 239, 54506 Vandoeuvre-lès-Nancy (France); Mlayah, A. [Centre d’Elaboration de Matériaux et d’Etudes Structurales (CEMES), CNRS UPR 8011-Université de Toulouse, 29 rue Jeanne Marvig 31055, Toulouse, Cedex 4 (France); Lusson, A.; Bouchez, G.; Boukheddaden, K., E-mail: Younes.abid@fss.rnu.tn, E-mail: kbo@physique.uvsq.fr [Groupe d’Etudes de la Matière Condensée, UMR CNRS 8653-Université de Versailles Saint Quentin En Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles (France); Triki, S. [Laboratoire de Chimie, Electrochimie Moléculaires, Chimie Analytique, UMR CNRS 6521-Université de Bretagne Occidentale, BP 809, 29285 Brest (France); Abid, Y., E-mail: Younes.abid@fss.rnu.tn, E-mail: kbo@physique.uvsq.fr [Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, Route de Soukra km 3.5 BP 1171, 3018 Sfax (Tunisia)

    2015-12-14

    Optical and structural properties of the organic-inorganic hybrid perovskite-type (C{sub 6}H{sub 11}NH{sub 3}){sub 2}[PbI{sub 4}] (abbreviated as C{sub 6}PbI{sub 4}) were investigated using optical absorption, photoluminescence (PL), and x-ray diffraction measurements. Room temperature, optical absorption measurements, performed on spin-coated films of C{sub 6}PbI{sub 4}, revealed two absorption bands at 2.44 and 3.21 eV. Upon 325 nm (3.815 eV) laser irradiation, strong green PL emission peaks were observed at 2.41 eV (P1) and 2.24 eV (P2) and assigned to free and localized excitons, respectively. The exciton binding energy was estimated at 356 meV. At low temperature, two additional emission bands were detected at 2.366 eV (P3) and a large band (LB) at 1.97 eV. The former appeared only below 40 K and the latter emerged below 130 K. The thermal dependence of the PL spectra revealed an abnormal behavior accompanied by singularities in the peak positions and intensities at 40 and 130 K. X-ray diffraction studies performed on powder and single crystals as a function of temperature evidenced significant changes of the interlayer spacing at 50 K and ∼138 K. Around 138 K, a commensurate to incommensurate structural phase transition occurred on cooling. It involves a symmetry breaking leading to a distortion of the PbI{sub 6} octahedron. The resulting incommensurate spatial modulation of the Pb–I distances (and Pb–I–Pb angles) causes a spatial modulation of the band gap, which is at the origin of the emergence of the LB below ∼130 K and the anomalous behavior of the position of P1 below 130 K. The change of the interlayer spacing in the 40-50 K range may in turn be related to the significant decrease of the intensity of P2 and the maximum emission of the LB. These results underline the intricate character of the structural and the PL properties of the hybrid perovskites; understanding such properties should benefit to the design of optoelectronic devices with

  8. Narrow-band spectral features of structured silver surface with rectangular resonant cavities

    International Nuclear Information System (INIS)

    This paper is aimed to investigate spectral properties of structured silver surface with periodic rectangular hollow cavities. Numerical computation is conducted to obtain spectral distribution of surface absorptance with different structural parameters using the finite-difference time-domain (FDTD) method. By means of numerical examples, the effects of structural parameters, incident angle and azimuthal angle on the spectral features of the structured surface are discussed. It is found that the structured surface shows the characteristics of the peak absorption in the vicinity of resonant wavelength of rectangular cavity. For some special structure parameters, the peak absorptance of the incident plane wave can reach as high as above 80% due to the excitation of microcavity effect. The optimal narrow-band absorption can be achieved by the rational design of the structural parameters of rectangular cavity. The directional dependence of spectral absorptance is also analyzed and the results reveal that the absorption peak positions are incident-angle-independent. The results show that the microscaled rectangular cavities fabricated on the low-emissivity silver surface are very efficient for selective improvement of the radiative features, which provides guidance for the design of narrow-band infrared thermal emitters.

  9. Detection and analysis of unusual features in the structural model and structure-factor data of a birch pollen allergen

    International Nuclear Information System (INIS)

    The structure factors deposited with PDB entry 3k78 show properties inconsistent with experimentally observed diffraction data, and without uncertainty represent calculated structure factors. The refinement of the model against these structure factors leads to an isomorphous structure different from the deposited model with an implausibly small R value (0.019). Physically improbable features in the model of the birch pollen structure Bet v 1d are faithfully reproduced in electron density generated with the deposited structure factors, but these structure factors themselves exhibit properties that are characteristic of data calculated from a simple model and are inconsistent with the data and error model obtained through experimental measurements. The refinement of the model against these structure factors leads to an isomorphous structure different from the deposited model with an implausibly small R value (0.019). The abnormal refinement is compared with normal refinement of an isomorphous variant structure of Bet v 1l. A variety of analytical tools, including the application of Diederichs plots, Rσ plots and bulk-solvent analysis are discussed as promising aids in validation. The examination of the Bet v 1d structure also cautions against the practice of indicating poorly defined protein chain residues through zero occupancies. The recommendation to preserve diffraction images is amplified

  10. Feature-guided waves (FGW) in plate structures with 90° transverse bends

    Science.gov (United States)

    Yu, Xudong; Manogharan, Prabhakaran; Fan, Zheng; Rajagopal, Prabhu

    2015-03-01

    Ultrasonic guided waves are attractive for rapid remote screening of large structures and today they are widely used in several practical applications including the inspection of pipe and plate installations. More recently, guided wave modal solutions confined in extended local features have attracted much research interest, offering the possibility of inspecting complex geometric or topographical features. Such feature-guided wave (FGW) modes have been reported in plate waveguides with local cross-section variation or curvature, and in annular circular cylinders with cross-sectional anomalies. This paper focuses on FGW phenomena in 90 degree structural bends in plate structures, which commonly occur in various industrial structures. Modal studies are carried out using the Semi-Analytical Finite Element (SAFE) method, while 3D finite element (FE) simulations are used to gain visualization of results and also obtain cross-validation. Our studies reveal, perhaps for the first time, the possibility of bend-guided modes of the shear-horizontal (SH) family, in addition those of the Rayleigh-Lamb family reported earlier in the literature. This mode has attractive properties including low attenuation and limited dispersion. We investigate effects of plate thickness and bend radius on the physics of FGW in bends, arguing the strong role of geometry and curvature effects in causing mode confinement. Preliminary experiments have also been carried out to validate the existence of such bend-guided mode.

  11. Anomalous pion decay revisited

    CERN Document Server

    Battistel, O A; Nemes, M C; Hiller, B

    1999-01-01

    An implicit four dimensional regularization is applied to calculate the axial-vector-vector anomalous amplitude. The present technique always complies with results of Dimensional Regularization and can be easily applied to processes involving odd numbers of $\\gamma_5$ matrices. This is illustrated explicitely in the example of this letter.

  12. Anomalous Hall effect

    Czech Academy of Sciences Publication Activity Database

    Nagaosa, N.; Sinova, Jairo; Onoda, S.; MacDonald, A. H.; Ong, N. P.

    2010-01-01

    Roč. 82, č. 2 (2010), s. 1539-1592. ISSN 0034-6861 Institutional research plan: CEZ:AV0Z10100521 Keywords : anomalous Hall effect * spintronics Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 51.695, year: 2010

  13. Spatial structure and scale feature of the atmospheric pollution source impact of city agglomeration

    Institute of Scientific and Technical Information of China (English)

    XU; Xiangde; ZHOU; Xiuji; SHI; Xiaohui

    2005-01-01

    The spatial structure and multi-scale feature of the atmospheric pollution influence domain of Beijing and its peripheral areas (a rapidly developed city agglomeration) is dissected and analyzed in this paper on the basis of the atmospheric pollution dynamic-chemical process observation data of the urban building ensemble boundary layer of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter (February) and summer (August) 2003, and relevant meteorological elements and satellite retrieval aerosol optical depth (AOD), etc. comprehensive data with the dynamic-statistical integrated analysis of "point-surface" spatial structure. Results show that there existed significant difference in the contribution of winter/summer different pollution emission sources to the component character of atmospheric pollution, and the principal component analysis (PCA) results of statistical model also indicate that SO2 and NOX dominated in the component structure of winter aerosol particle; instead, CO and NOX dominated in summer. Surface layer atmospheric dynamic and thermal structures and various pollutant species at the upper boundary of building ensembles at urban different observational sites of Beijing in winter and summer showed an "in-phase" variation and its spatial scale feature of "influence domain". The power spectrum analysis (PSA) shows that the period spectrum of winter/summer particle concentration accorded with those of atmospheric wind field: the longer period was dominative in winter, but the shorter period in summer, revealing the impact of the seasonal scale feature of winter/summer atmospheric general circulation on the period of atmospheric pollution variations. It is found that from analyzing urban area thermal heterogeneity that the multiscale effect of Beijing region urban heat island (UHI) was associated with the heterogeneous expansion of tall buildings area. In urban atmospheric dynamical and thermal characteristic spatial structures, the

  14. Isocolic Structures and Graphemic Features in the Croatian Church Slavic Regula Sancti Benedicti

    Directory of Open Access Journals (Sweden)

    Denis Crnković

    2006-12-01

    Full Text Available Isocolic Structures and Graphemic Features in the Croatian Church Slavic Regula Sancti Benedicti The article discusses the presence of the isocolon in the Croatian Church Slavic translation of the Regula Sancti Benedicti in light of the graphemic features of the fourteenth century codex unicus. After a brief review of the scholarly literature on the use of the isocolon in medieval Slavic literature in general and medieval Croatian literature in particular, the article looks in detail at the visual appearance of the CrRSB on the manuscript pages. By examining selections of the CrRSB, the paper shows how the use of graphemic signs and markers, such as the page layout, the paragraph marker, the punctus and, most significantly, the “white space”, help indicate the rhythmical structure of the text. A thorough inspection of these passages indicates how graphemic features work in tandem with the rhetorical markers to indicate the textual isocola. The study concludes that the graphemic features of the CrRSB are completely consonant with the isocolic rhythmical patterns of the text and likely demonstrate that the manuscript’s scribes were not only aware of isocolic patterning, but used the graphical conventions of their day to indicate the proper way to read the text aloud.

  15. The role of emotion in musical improvisation: an analysis of structural features.

    Science.gov (United States)

    McPherson, Malinda J; Lopez-Gonzalez, Monica; Rankin, Summer K; Limb, Charles J

    2014-01-01

    One of the primary functions of music is to convey emotion, yet how music accomplishes this task remains unclear. For example, simple correlations between mode (major vs. minor) and emotion (happy vs. sad) do not adequately explain the enormous range, subtlety or complexity of musically induced emotions. In this study, we examined the structural features of unconstrained musical improvisations generated by jazz pianists in response to emotional cues. We hypothesized that musicians would not utilize any universal rules to convey emotions, but would instead combine heterogeneous musical elements together in order to depict positive and negative emotions. Our findings demonstrate a lack of simple correspondence between emotions and musical features of spontaneous musical improvisation. While improvisations in response to positive emotional cues were more likely to be in major keys, have faster tempos, faster key press velocities and more staccato notes when compared to negative improvisations, there was a wide distribution for each emotion with components that directly violated these primary associations. The finding that musicians often combine disparate features together in order to convey emotion during improvisation suggests that structural diversity may be an essential feature of the ability of music to express a wide range of emotion. PMID:25144200

  16. The role of emotion in musical improvisation: an analysis of structural features.

    Directory of Open Access Journals (Sweden)

    Malinda J McPherson

    Full Text Available One of the primary functions of music is to convey emotion, yet how music accomplishes this task remains unclear. For example, simple correlations between mode (major vs. minor and emotion (happy vs. sad do not adequately explain the enormous range, subtlety or complexity of musically induced emotions. In this study, we examined the structural features of unconstrained musical improvisations generated by jazz pianists in response to emotional cues. We hypothesized that musicians would not utilize any universal rules to convey emotions, but would instead combine heterogeneous musical elements together in order to depict positive and negative emotions. Our findings demonstrate a lack of simple correspondence between emotions and musical features of spontaneous musical improvisation. While improvisations in response to positive emotional cues were more likely to be in major keys, have faster tempos, faster key press velocities and more staccato notes when compared to negative improvisations, there was a wide distribution for each emotion with components that directly violated these primary associations. The finding that musicians often combine disparate features together in order to convey emotion during improvisation suggests that structural diversity may be an essential feature of the ability of music to express a wide range of emotion.

  17. Ht-Index for Quantifying the Fractal or Scaling Structure of Geographic Features

    CERN Document Server

    Jiang, Bin

    2013-01-01

    Although geographic features, such as mountains and coastlines, are fractal, some studies have claimed that the fractal property is not universal. This claim, which is false, is mainly attributed to the strict definition of fractal dimension as a measure or index for characterizing the complexity of fractals. In this paper, we propose an alternative, the ht-index, to quantify the fractal or scaling structure of geographic features. A geographic feature has ht-index h if the pattern of far more small things than large ones recurs (h-1) times at different scales. The higher the ht-index, the more complex the geographic feature. We conduct three case studies to illustrate how the computed ht-indices capture the complexity of different geographic features. We further discuss how the ht-index is complementary to fractal dimension, and elaborate on a dynamic view behind the ht-index that enables better understanding of geographic forms and processes. Keywords: Scaling of geographic space, fractal dimension, Richard...

  18. Summarization based on physical features and logical structure of multi documents

    Institute of Scientific and Technical Information of China (English)

    Qin Bing; Liu Ting; Li Sheng

    2005-01-01

    With the rapid development of the Internet, multi documents summarization is becoming a very hot research topic. In order to generate a summarization that can effectively characterize the original information from documents, this paper proposes a multi documents summarization approach based on the physical features and logical structure of the document set. This method firstly clusterssimilar sentences into several Logical Topics (LTs), and then orders these topics according to their physical features of multi documents. After that, sentences used for the summarization are extracted from these LTs, and finally the summarization is generated via certain sorting algorithms. Our experiments show that the information coverage rate of our method is 8.83% higher than those methods based solely on logical structures, and 14.31% higher than Top-N method.

  19. Structural Features and In-service Inspection of the LTNHR-200 Pressure Vessel

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The pressure vessel of 200 MW low temperature nuclear heating reactor (LTNHR-200) is the main part of primary pressure boundary and its reasonable and reliable structural design is the key point to assure the safe operation of LTNHR-200. The double-shell pressure vessels were designed. LTNHR-200 pressure vessel meets the condition of Leak Before Break and has a relatively low failure probability. Metal containment (outer pressure vessel) has the similar features to LTNHR-200 pressure vessel. There exists no LOCA and core melting with the double vessel. The in-service inspection of the pressure vessel can be simplified greatly because of the safety and structural features of the reactor.

  20. On the structural features of fiber suspensions in converging channel flow

    Institute of Scientific and Technical Information of China (English)

    林建忠; 张凌新

    2003-01-01

    The structural features of fiber suspensions are dependent on the fiber alignment in the flows. In this work the orientation distribution function and orientation tensors for semi-concentrated fiber suspensions in converging channel flow were calculated, and the evolutions of the fiber alignment and the bulk effective viscosity were analyzed. The results showed that the bulk stress and the effective viscosity were functions of the rate-of-strain tensor and the fiber orientation state; and that the fiber suspensions evolved to steady alignment and tended to concentrate to some preferred directions close to but not same as the directions of local streamlines. The bulk effective viscosity depended on the product of Reynolds number and time. The decrease of effective viscosity near the boundary benefited the increase of the rate of flow. Finally when the fiber alignment went into steady state, the structural features of fiber suspensions were not dependent on the Reynolds number but on the converging channel angle.

  1. Influence of design features on the structural integrity of threaded pipe connections

    OpenAIRE

    Galle, Timothy; De Waele, Wim; DE BAETS, Patrick; Van Wittenberghe, Jeroen

    2011-01-01

    When drilling and completing High Pressure High Temperature (HPHT) wells, the applied casing and tubing have to be able to withstand extreme conditions. Very often, the threaded connections are the most critical components in the entire chain. The overall design of several threaded and coupled (T&C) connections (eg. VAM TOP, JFEBear and the newest PatriotTC) is very similar. However, even by modifying one single feature of the geometry, an improved structural integrity (eg. fatigue resistance...

  2. Spatio-structural Symbol Description with Statistical Feature Add-on

    OpenAIRE

    K.C., Santosh; Lamiroy, Bart; Wendling, Laurent

    2013-01-01

    In this paper, we present a method for symbol description based on both spatio-structural and statistical features computed on elementary visual parts, called 'vocabulary'. This extracted vocabulary is grouped by type (e.g., circle, corner ) and serves as a basis for an attributed relational graph where spatial relational descriptors formalise the links between the vertices, formed by these types, labelled with global shape descriptors. The obtained attributed relational graph description has...

  3. Macro- and Microscopic Structural Features of the Cerebellar Dentate Nucleus in Humans

    OpenAIRE

    Shyian, D. M.

    2015-01-01

    Since ancient times the study of one part of the brain - the cerebellum - has attracted the attention of many researchers, however, neither anatomy of the cerebellum, nor its function remain fully studied. The nuclei of the cerebellum, including the dentate nucleus are not sufficiently studied. The structural features of the cerebellar dentate nucleus of human in ontogenesis and its topographic and anatomic location are important not only for anatomists, physiologists, but also for clinicians...

  4. Fabrication of small-scale structures with non-planar features

    Science.gov (United States)

    Burckel, David B.; Ten Eyck, Gregory A.

    2015-11-19

    The fabrication of small-scale structures is disclosed. A unit-cell of a small-scale structure with non-planar features is fabricated by forming a membrane on a suitable material. A pattern is formed in the membrane and a portion of the substrate underneath the membrane is removed to form a cavity. Resonators are then directionally deposited on the wall or sides of the cavity. The cavity may be rotated during deposition to form closed-loop resonators. The resonators may be non-planar. The unit-cells can be formed in a layer that includes an array of unit-cells.

  5. High-throughput screening for thermoelectric sulphides by using crystal structure features as descriptors

    Science.gov (United States)

    Zhang, Ruizhi; Du, Baoli; Chen, Kan; Reece, Mike; Materials Research Insititute Team

    With the increasing computational power and reliable databases, high-throughput screening is playing a more and more important role in the search of new thermoelectric materials. Rather than the well established density functional theory (DFT) calculation based methods, we propose an alternative approach to screen for new TE materials: using crystal structural features as 'descriptors'. We show that a non-distorted transition metal sulphide polyhedral network can be a good descriptor for high power factor according to crystal filed theory. By using Cu/S containing compounds as an example, 1600+ Cu/S containing entries in the Inorganic Crystal Structure Database (ICSD) were screened, and of those 84 phases are identified as promising thermoelectric materials. The screening results are validated by both electronic structure calculations and experimental results from the literature. We also fabricated some new compounds to test our screening results. Another advantage of using crystal structure features as descriptors is that we can easily establish structural relationships between the identified phases. Based on this, two material design approaches are discussed: 1) High-pressure synthesis of metastable phase; 2) In-situ 2-phase composites with coherent interface. This work was supported by a Marie Curie International Incoming Fellowship of the European Community Human Potential Program.

  6. Anomalous transport equations in toroidal plasmas

    International Nuclear Information System (INIS)

    Reduced transport equations for a toroidal plasma with fluctuations are derived. These equations include the effects of both anomalous and standard neoclassical transport, and allow clarification of the structure of convective fluxes caused by electrostatic and magnetic fluctuations. Special attention is paid to the combined effects of fluctuations and toroidicity on the transport. The formulation retains the effects of a magnetic field inhomogeneity on the anomalous transport. It is shown that phase space diffusion caused by the gradient in the equilibrium magnetic field appears as a pinch flux in the real space

  7. General features and master equations for structurization in complex dusty plasmas

    International Nuclear Information System (INIS)

    Dust structurization is considered to be typical for complex plasmas. Homogeneous dusty plasmas are shown to be universally unstable. The dusty plasma structurization instability is similar to the gravitational instability and can results in creation of different compact dust structures. A general approach for investigation of the nonlinear stage of structurization in dusty plasmas is proposed and master equations for the description of self-organized structures are formulated in the general form that can be used for any nonlinear model of dust screening. New effects due to the scattering of ions on the nonlinearly screened grains are calculated: nonlinear ion dust drag force and nonlinear ion diffusion. The physics of confinement of dust and plasma components in the equilibria of compact dust structures is presented and is supported by numerical calculations of master equations. The necessary conditions for the existence of equilibrium structures are found for an arbitrary nonlinearity in dust screening. Features of compact dust structures observed in recent experiments agree with the numerically calculated ones. Some proposals for future experiments in spherical chamber are given.

  8. Adaptive cellular structures and devices with internal features for enhanced structural performance

    Science.gov (United States)

    Pontecorvo, Michael Eugene

    This dissertation aims to develop a family of cellular and repeatable devices that exhibit a variety of force-displacement behaviors. It is envisioned that these cellular structures might be used either as stand-alone elements, or combined and repeated to create multiple types of structures (i.e. buildings, ship hulls, vehicle subfloors, etc.) with the ability to passively or actively perform multiple functions (harmonic energy dissipation, impact mitigation, modulus change) over a range of loading types, amplitudes, and frequencies. To accomplish this goal, this work combines repeatable structural frameworks, such as that provided by a hexagonal cellular structure, with internal structural elements such as springs, viscous dampers, buckling plates, bi-stable von Mises trusses (VMTs), and pneumatic artificial muscles (PAMs). The repeatable framework serves to position damping and load carrying elements throughout the structure, and the configuration of the internal elements allow each cell to be tuned to exhibit a desired force-displacement response. Therefore, gradient structures or structures with variable load paths can be created for an optimal global response to a range of loads. This dissertation focuses on the development of cellular structures for three functions: combined load-carrying capability with harmonic energy dissipation, impact mitigation, and cell modulus variation. One or more conceptual designs are presented for devices that can perform each of these functions, and both experimental measurements and simulations are used to gain a fundamental understanding of each device. Chapter 2 begins with a presentation of a VMT model that is the basis for many of the elements. The equations of motion for the VMT are derived and the static and dynamic behavior of the VMT are discussed in detail. Next, two metrics for the energy dissipation of the VMT - hysteresis loop area and loss factor - are presented. The responses of the VMT to harmonic displacement

  9. Anomalous velocity distributions in active Brownian suspensions

    OpenAIRE

    Fiege, Andrea; Vollmayr-Lee, Benjamin; Zippelius, Annette

    2013-01-01

    Large scale simulations and analytical theory have been combined to obtain the non-equilibrium velocity distribution, $f(v)$, of randomly accelerated particles in suspension. The simulations are based on an event-driven algorithm, generalised to include friction. They reveal strongly anomalous but largely universal distributions which are independent of volume fraction and collision processes, which suggests a one-particle model should capture all the essential features. We have formulated th...

  10. Inherent Structure-Based Multiview Learning With Multitemplate Feature Representation for Alzheimer's Disease Diagnosis.

    Science.gov (United States)

    Liu, Mingxia; Zhang, Daoqiang; Adeli, Ehsan; Shen, Dinggang

    2016-07-01

    Multitemplate-based brain morphometric pattern analysis using magnetic resonance imaging has been recently proposed for automatic diagnosis of Alzheimer's disease (AD) and its prodromal stage (i.e., mild cognitive impairment or MCI). In such methods, multiview morphological patterns generated from multiple templates are used as feature representation for brain images. However, existing multitemplate-based methods often simply assume that each class is represented by a specific type of data distribution (i.e., a single cluster), while in reality, the underlying data distribution is actually not preknown. In this paper, we propose an inherent structure-based multiview leaning method using multiple templates for AD/MCI classification. Specifically, we first extract multiview feature representations for subjects using multiple selected templates and then cluster subjects within a specific class into several subclasses (i.e., clusters) in each view space. Then, we encode those subclasses with unique codes by considering both their original class information and their own distribution information, followed by a multitask feature selection model. Finally, we learn an ensemble of view-specific support vector machine classifiers based on their, respectively, selected features in each view and fuse their results to draw the final decision. Experimental results on the Alzheimer's Disease Neuroimaging Initiative database demonstrate that our method achieves promising results for AD/MCI classification, compared to the state-of-the-art multitemplate-based methods. PMID:26540666

  11. Hydrovolcanic Breccia Pipe Structures-General Features and Genetic Criteria. I. Phreatomagmatic Breccias

    Directory of Open Access Journals (Sweden)

    Călin G. Tămas

    2002-04-01

    Full Text Available Two types of hydrovolcanic breccias are generally accepted: phreatomagmatic and phreatic. Due to their specific characteristics generated during the brecciation, characteristics that control the ore deposition, these breccias represent favourable hosts for mineralization. The depth of formation, the general form and dimensions, the breccia - host rock contact, as well as fragments, matrix, and open spaces altogether control the position and the size of the breccia hosted ore bodies and contribute in different degrees to the rise of the ore grades in phreatomagmatic and phreatic structures. Consequently, the recognition of the genetic type of breccia allows an appropriate strategy in mineral exploration. Describing a breccia necessarily implies a check of its general features, such as environment/depth of formation, general form/geometry, dimensions, breccia-host rock contact, fragments, matrix, alteration, mineralization, surface connection, as well as of its additional features, namely fluidization and facies changes (see Table 2. There are several characteristics with high genetic significance among the abundant descriptive features regarding breccia structures. To point out such evidences means to find out the keys for the genetic intrepretation. A complete list of genetic criteria is proposed for phreatomagmatic breccias (see Table 3.

  12. Influence of landscape features on the microgeographic genetic structure of a resident songbird.

    Science.gov (United States)

    Adams, R V; Lazerte, S E; Otter, K A; Burg, T M

    2016-08-01

    Landscape features influence individual dispersal and as a result can affect both gene flow and genetic variation within and between populations. The landscape of British Columbia, Canada, is already highly heterogeneous because of natural ecological and geological transitions, but disturbance from human-mediated processes has further fragmented continuous habitat, particularly in the central plateau region. In this study, we evaluated the effects of landscape heterogeneity on the genetic structure of a common resident songbird, the black-capped chickadee (Poecile atricapillus). Previous work revealed significant population structuring in British Columbia that could not be explained by physical barriers, so our aim was to assess the pattern of genetic structure at a microgeographic scale and determine the effect of different landscape features on genetic differentiation. A total of 399 individuals from 15 populations were genotyped for fourteen microsatellite loci revealing significant population structuring in this species. Individual- and population-based analyses revealed as many as nine genetic clusters with isolation in the north, the central plateau and the south. Moreover, a mixed modelling approach that accounted for non-independence of pairwise distance values revealed a significant effect of land cover and elevation resistance on genetic differentiation. These results suggest that barriers in the landscape influence dispersal which has led to the unexpectedly high levels of population isolation. Our study demonstrates the importance of incorporating landscape features when interpreting patterns of population differentiation. Despite taking a microgeographic approach, our results have opened up additional questions concerning the processes influencing dispersal and gene flow at the local scale. PMID:26905462

  13. THE MEDIUM RANGE STRUCTURE OF HYDROGENATED Cu-Ti AMORPHOUS ALLOYS STUDIED BY ANOMALOUS SMALL-ANGLE SCATTERING OF X-RAYS AND NEUTRON DIFFRACTION

    OpenAIRE

    Goudeau, P.; Naudon, A.; Rodmacq, B.; Mangin, P; Chamberod, A.

    1985-01-01

    Amorphous Cu-Ti alloys, when hydrogenated, reveal a strong small-angle scattered intensity. The anomalous X-ray scattering effect is used to analyse this SAS intensity on both copper and titanium edges. It allows to assert the presence of very small clusters of titanium hydride having the TiH2 composition. These results are in good agreement with those obtained by neutron scattering experiments when using either hydrogen (b 0) for the hydrogenation of the samples.

  14. Semi-isometric registration of line features for flexible fitting of protein structures.

    Science.gov (United States)

    Abeysinghe, S; Baker, M L; Chiu, W; Ju, T

    2010-01-01

    In this paper, we study a registration problem that is motivated by a practical biology problem - fitting protein structures to low-resolution density maps. We consider registration between two sets of lines features (e.g., helices in the proteins) that have undergone not a single, but multiple isometric transformations (e.g., hinge-motions). The problem is further complicated by the presence of symmetry in each set. We formulate the problem as a clique-finding problem in a product graph, and propose a heuristic solution that includes a fast clique-finding algorithm unique to the structure of this graph. When tested on a suite of real protein structures, the algorithm achieved high accuracy even for very large inputs containing hundreds of helices. PMID:21124809

  15. Structural and mechanical features of the order-disorder transition in experimental hard-sphere packings.

    Science.gov (United States)

    Hanifpour, M; Francois, N; Robins, V; Kingston, A; Allaei, S M Vaez; Saadatfar, M

    2015-06-01

    Here we present an experimental and numerical investigation on the grain-scale geometrical and mechanical properties of partially crystallized structures made of macroscopic frictional grains. Crystallization is inevitable in arrangements of monosized hard spheres with packing densities exceeding Bernal's limiting density ϕ(Bernal)≈0.64. We study packings of monosized hard spheres whose density spans over a wide range (0.59analysis, and numerical simulations to access precisely the geometry and the 3D structure of internal forces within the sphere packings. We show that clear geometrical transitions coincide with modifications of the mechanical backbone of the packing both at the grain and global scale. Notably, two transitions are identified at ϕ(Bernal)≈0.64 and ϕ(c)≈0.68. These results provide insights on how geometrical and mechanical features at the grain scale conspire to yield partially crystallized structures that are mechanically stable. PMID:26172700

  16. Drivers of structural features in gene regulatory networks: From biophysical constraints to biological function

    Science.gov (United States)

    Martin, O. C.; Krzywicki, A.; Zagorski, M.

    2016-07-01

    Living cells can maintain their internal states, react to changing environments, grow, differentiate, divide, etc. All these processes are tightly controlled by what can be called a regulatory program. The logic of the underlying control can sometimes be guessed at by examining the network of influences amongst genetic components. Some associated gene regulatory networks have been studied in prokaryotes and eukaryotes, unveiling various structural features ranging from broad distributions of out-degrees to recurrent "motifs", that is small subgraphs having a specific pattern of interactions. To understand what factors may be driving such structuring, a number of groups have introduced frameworks to model the dynamics of gene regulatory networks. In that context, we review here such in silico approaches and show how selection for phenotypes, i.e., network function, can shape network structure.

  17. Damage and noise sensitivity evaluation of autoregressive features extracted from structure vibration

    International Nuclear Information System (INIS)

    In the past few decades many types of structural damage indices based on structural health monitoring signals have been proposed, requiring performance evaluation and comparison studies on these indices in a quantitative manner. One tool to help accomplish this objective is analytical sensitivity analysis, which has been successfully used to evaluate the influences of system operational parameters on observable characteristics in many fields of study. In this paper, the sensitivity expressions of two damage features, namely the Mahalanobis distance of autoregressive coefficients and the Cosh distance of autoregressive spectra, will be derived with respect to both structural damage and measurement noise level. The effectiveness of the proposed methods is illustrated in a numerical case study on a 10-DOF system, where their results are compared with those from direct simulation and theoretical calculation. (paper)

  18. Influence of some structural features of a coal on its tendency to undergo reduction

    Energy Technology Data Exchange (ETDEWEB)

    Grigor' eva, E.A.; Bakirova, E.V.; Lesnikova, E.B.; Larina, N.K.; Zharova, M.N.; Dzhalyabova, L.V.

    1981-01-01

    Among the many factors determining the depth of conversion of a coal on hydrogenation, various structural features and, in particular, the nature and number of the labile oxygen-containing structures and bridge bonds, have an influence. There are statements that a direct relationship exists between the activity of a coal in destructive hydrogenation and the amount of oxygen in the ether/ester form, and also the nature of the bond of the mineral fraction of the coal with the organic constituents. The present paper is devoted to an investigation of the dependence of the tendancy of coal to undergo hydrogenation on the nature and number of the ether/ester and organomineral bonds in the structure of the coal. In experiments the researchers used the hydrolytic destruction of the coals and subsequent selective hydrogeneatin with sodium tetrahydroborate. 17 refs.

  19. Local appearance features for robust MRI brain structure segmentation across scanning protocols

    DEFF Research Database (Denmark)

    Achterberg, H.C.; Poot, D.H.J.; Van Der Lijn, F.;

    2013-01-01

    Segmentation of brain structures in magnetic resonance images is an important task in neuro image analysis. Several papers on this topic have shown the benefit of supervised classification based on local appearance features, often combined with atlas-based approaches. These methods require a...... representative annotated training set and therefore often do not perform well if the target image is acquired on a different scanner or with a different acquisition protocol than the training images. Assuming that the appearance of the brain is determined by the underlying brain tissue distribution and that...... brain tissue classification can be performed robustly for images obtained with different protocols, we propose to derive appearance features from brain-tissue density maps instead of directly from the MR images. We evaluated this approach on hippocampus segmentation in two sets of images acquired with...

  20. The RGD finger of Del-1 is a unique structural feature critical for integrin binding

    Energy Technology Data Exchange (ETDEWEB)

    Schürpf, Thomas; Chen, Qiang; Liu, Jin-huan; Wang, Rui; Springer, Timothy A.; Wang, Jia-huai (Harvard-Med)

    2012-11-13

    Developmental endothelial cell locus-1 (Del-1) glycoprotein is secreted by endothelial cells and a subset of macrophages. Del-1 plays a regulatory role in vascular remodeling and functions in innate immunity through interaction with integrin {alpha}{sub V}{beta}{sub 3}. Del-1 contains 3 epidermal growth factor (EGF)-like repeats and 2 discoidin-like domains. An Arg-Gly-Asp (RGD) motif in the second EGF domain (EGF2) mediates adhesion by endothelial cells and phagocytes. We report the crystal structure of its 3 EGF domains. The RGD motif of EGF2 forms a type II' {beta} turn at the tip of a long protruding loop, dubbed the RGD finger. Whereas EGF2 and EGF3 constitute a rigid rod via an interdomain calcium ion binding site, the long linker between EGF1 and EGF2 lends considerable flexibility to EGF1. Two unique O-linked glycans and 1 N-linked glycan locate to the opposite side of EGF2 from the RGD motif. These structural features favor integrin binding of the RGD finger. Mutagenesis data confirm the importance of having the RGD motif at the tip of the RGD finger. A database search for EGF domain sequences shows that this RGD finger is likely an evolutionary insertion and unique to the EGF domain of Del-1 and its homologue milk fat globule-EGF 8. The RGD finger of Del-1 is a unique structural feature critical for integrin binding.

  1. Observational Features of Large-Scale Structures as Revealed by the Catastrophe Model of Solar Eruptions

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Large-scale magnetic structures are the main carrier of major eruptions in the solar atmosphere. These structures are rooted in the photosphere and are driven by the unceasing motion of the photospheric material through a series of equilibrium configurations. The motion brings energy into the coronal magnetic field until the system ceases to be in equilibrium. The catastrophe theory for solar eruptions indicates that loss of mechanical equilibrium constitutes the main trigger mechanism of major eruptions, usually shown up as solar flares,eruptive prominences, and coronal mass ejections (CMEs). Magnetic reconnection which takes place at the very beginning of the eruption as a result of plasma instabilities/turbulence inside the current sheet, converts magnetic energy into heating and kinetic energy that are responsible for solar flares, and for accelerating both plasma ejecta (flows and CMEs) and energetic particles. Various manifestations are thus related to one another, and the physics behind these relationships is catastrophe and magnetic reconnection. This work reports on recent progress in both theoretical research and observations on eruptive phenomena showing the above manifestations. We start by displaying the properties of large-scale structures in the corona and the related magnetic fields prior to an eruption, and show various morphological features of the disrupting magnetic fields. Then, in the framework of the catastrophe theory,we look into the physics behind those features investigated in a succession of previous works,and discuss the approaches they used.

  2. An Matching Method for Vehicle-borne Panoramic Image Sequence Based on Adaptive Structure from Motion Feature

    Directory of Open Access Journals (Sweden)

    ZHANG Zhengpeng

    2015-10-01

    Full Text Available Panoramic image matching method with the constraint condition of local structure from motion similarity feature is an important method, the process requires multivariable kernel density estimations for the structure from motion feature used nonparametric mean shift. Proper selection of the kernel bandwidth is a critical step for convergence speed and accuracy of matching method. Variable bandwidth with adaptive structure from motion feature for panoramic image matching method has been proposed in this work. First the bandwidth matrix is defined using the locally adaptive spatial structure of the sampling point in spatial domain and optical flow domain. The relaxation diffusion process of structure from motion similarity feature is described by distance weighting method of local optical flow feature vector. Then the expression form of adaptive multivariate kernel density function is given out, and discusses the solution of the mean shift vector, termination conditions, and the seed point selection method. The final fusions of multi-scale SIFT the features and structure features to establish a unified panoramic image matching framework. The sphere panoramic images from vehicle-borne mobile measurement system are chosen such that a comparison analysis between fixed bandwidth and adaptive bandwidth is carried out in detail. The results show that adaptive bandwidth is good for case with the inlier ratio changes and the object space scale changes. The proposed method can realize the adaptive similarity measure of structure from motion feature, improves the correct matching points and matching rate, experimental results have shown our method to be robust.

  3. Strong Nonadditivity as a Key Structure–Activity Relationship Feature: Distinguishing Structural Changes from Assay Artifacts

    Science.gov (United States)

    2015-01-01

    Nonadditivity in protein–ligand affinity data represents highly instructive structure–activity relationship (SAR) features that indicate structural changes and have the potential to guide rational drug design. At the same time, nonadditivity is a challenge for both basic SAR analysis as well as many ligand-based data analysis techniques such as Free-Wilson Analysis and Matched Molecular Pair analysis, since linear substituent contribution models inherently assume additivity and thus do not work in such cases. While structural causes for nonadditivity have been analyzed anecdotally, no systematic approaches to interpret and use nonadditivity prospectively have been developed yet. In this contribution, we lay the statistical framework for systematic analysis of nonadditivity in a SAR series. First, we develop a general metric to quantify nonadditivity. Then, we demonstrate the non-negligible impact of experimental uncertainty that creates apparent nonadditivity, and we introduce techniques to handle experimental uncertainty. Finally, we analyze public SAR data sets for strong nonadditivity and use recourse to the original publications and available X-ray structures to find structural explanations for the nonadditivity observed. We find that all cases of strong nonadditivity (ΔΔpKi and ΔΔpIC50 > 2.0 log units) with sufficient structural information to generate reasonable hypothesis involve changes in binding mode. With the appropriate statistical basis, nonadditivity analysis offers a variety of new attempts for various areas in computer-aided drug design, including the validation of scoring functions and free energy perturbation approaches, binding pocket classification, and novel features in SAR analysis tools. PMID:25760829

  4. Seismically-induced structures in the Quaternary sediments of the NE Fennoscandian Shield: Features and age

    Directory of Open Access Journals (Sweden)

    Nikolaeva S. B.

    2016-03-01

    Full Text Available Results of studying secondary seismogenic deformations of the vibrational type (termed "seismites" in loose sediments of the north-eastern Baltic Shield (the Kola region have been provided. The features, types, formation patterns and age of seismites have been considered. On the basis of previous results the major periods of the region activation in the Holocene have been defined. Criteria of identifying similar structures with widely spread glaciodislocations have been suggested. Results of studying the sections with seismites in certain areas of the region have been provided

  5. Features of kinematic structure of motor actions technique in the freestyle wrestlers with different qualification

    Directory of Open Access Journals (Sweden)

    Tupeev Y.V.

    2010-02-01

    Full Text Available The sequence of educational steps in teaching basic technique elements in stance for young wrestlers at the initial training stage was determined by the expert assessment method. The biomechanical features of technique of a sprint by an inclination hold of legs for differently qualified wrestlers in freestyle were ascertained by the biomechanical videocomputer analysis. The results of research of kinematic structure of motor actions technique testify that performance duration of phases in sprint by an inclination hold of legs was characterized by the greater values for qualified wrestlers in comparison with highly skilled ones.

  6. Structural Features of Boron-Doped Si(113) Surfaces Simulated by ab initio Calculations

    Institute of Scientific and Technical Information of China (English)

    LIAO Long-Zhong; LIU Zheng-Hui; ZHANG Zhao-Hui

    2008-01-01

    Based on ab initio calculations, boron-doped Si(113) surfaces have been simulated and atomic structures of the surfaces have been proposed. It has been determined that surface features of empty and filled states that are separately localized at pentamers and adatoms indicates a low surface density of B atoms, while it is attributed to heavy doping of B atoms at the second layer that pentamers and adatoms are both present in an image of scanning tunnelling microscopy. B doping at the second layer should be balanced by adsorbed B or Si atoms beside the adatoms and inserted B interstitials below the adatoms.

  7. Spatial structure and scale feature of the atmospheric pollution source impact of city agglomeration

    Institute of Scientific and Technical Information of China (English)

    XU Xiangde; ZHOU Xiuji; SHI Xiaohui

    2005-01-01

    The spatial structure and multi-scale feature of the atmospheric pollution influence domain of Beijing and its peripheral areas (a rapidly developed city agglomeration) is dissected and analyzed in this paper on the basis of the atmospheric pollution dynamic-chemical process observation data of the urban building ensemble boundary layer of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter (February) and summer (August) 2003, and relevant meteorological elements and satellite retrieval aerosol optical depth (AOD), etc. comprehensive data with the dynamic-statistical integrated analysis of "point-surface" spatial structure. Results show that there existed significant difference in the contribution of winter/summer different pollution emission sources to the component character of atmospheric pollution, and the principal component analysis (PCA) results of statistical model also indicate that SO2 and NOX dominated in the component structure of winter aerosol particle; instead, CO and NOX dominated in summer. Surface layer atmospheric dynamic and thermal structures and various pollutant species at the upper boundary of building ensembles at urban different observational sites of Beijing in winter and summer showed an "in-phase" variation and its spatial scale feature of "influence domain". The power spectrum analysis (PSA) shows that the period spectrum of winter/summer particle concentration accorded with those of atmospheric wind field: the longer period was dominative in winter, but the shorter period in summer, revealing the impact of the seasonal scale feature of winter/summer atmospheric general circulation on the period of atmospheric pollution variations. It is found that from analyzing urban area thermal heterogeneity that the multiscale effect of Beijing region urban heat island (UHI) was associated with the heterogeneous expansion of tall buildings area. In urban atmospheric dynamical and thermal characteristic spatial structures, the

  8. Local structure around Pd atoms in Pd42.5Ni7.5Cu30P20 excellent glass-former studied by anomalous X-ray scattering

    International Nuclear Information System (INIS)

    In order to study local structure around the Pd atoms in Pd42.5Ni7.5Cu30P20 excellent metallic glass-former, an anomalous X-ray scattering (AXS) experiment was performed at energies close to the Pd K absorption edge at the beamline BM02 of the European Synchrotron Radiation Facility. The differential structure factor, ΔPdS(Q), was obtained with a good statistical quality, which demonstrates that a pre-shoulder at about 20nm-1, indicating the existence of an intermediate-range order, originates from the Pd-Pd atomic correlation. The first peak in the differential pair correlation function, ΔPdg(r), shows a longer inter-atomic length around the Pd atoms than the average value. The local structure around the Pd atoms is discussed in detail by comparing to the previous experiments of AXS and electronic structure. (author)

  9. Imposed, ordered dust structures and other plasma features in a strongly magnetized plasma

    Science.gov (United States)

    Thomas, Edward; Leblanc, Spencer; Lynch, Brian; Konopka, Uwe; Merlino, Robert; Rosenberg, Marlene

    2015-11-01

    The Magnetized Dusty Plasma Experiment (MDPX) device has been in operation for just over one year. In that time, the MDPX device has been operating using a uniform magnetic field configuration up to 3.0 Tesla and has successfully produced plasmas and dusty plasmas at high magnetic fields. In these experimental studies, we have made observations of a new type of imposed, ordered structure in a dusty plasma at magnetic fields above 1 T. These dusty plasma structures are shown to scale inversely with neutral pressure and are shown to reflect the spatial structure of a wire mesh placed in the plasma. Additionally, recent measurements have been made that give insights into the effective potential that establishes the ordered structures in the plasma. In this presentation, we report on details of the imposed, ordered dusty plasma structure as well as filamentary features that also appear in the plasma and modify the confinement of the dusty plasma. This work is supported with funding from the NSF and Department of Energy.

  10. Nuclear Magnetic Resonance Solution Structure of DNA Featuring Clustered 2'-Deoxyribonolactone and 8-Oxoguanine Lesions.

    Science.gov (United States)

    Zálešák, Jan; Constant, Jean-François; Jourdan, Muriel

    2016-07-19

    Ionizing radiation, free radicals, and reactive oxygen species produce hundreds of different DNA lesions. Clustered lesions are typical for ionizing radiation. They compromise the efficiency of the base excision repair (BER) pathway, and as a consequence, they are much more toxic and mutagenic than isolated lesions. Despite their biological relevance, e.g., in cancer radiotherapy and accidental exposure, they are not very well studied from a structural point of view, and while insights provided by structural studies contribute to the understanding of the repair process, only three nuclear magnetic resonance (NMR) studies of DNA containing clusters of lesions were reported. Herein, we report the first NMR solution structure of two DNAs containing a bistranded cluster with the 2'-deoxyribonolactone and 8-oxoguanine lesions. Both DNA duplexes feature a 2'-deoxyribonolactone site in the middle of the sequence of one strand and differ by the relative position of the 8-oxoguanine, staggered 3' or 5' side on the complementary strand at a three-nucleotide distance. Depending on its relative position, the repair of the 8-oxoguanine lesion by the base excision repair protein Fpg is either almost complete or inhibited. We found that the structures of the two DNAs containing a bistranded cluster of two lesions are similar and do not deviate very much from the standard B-form. As no obvious structural deformations were observed between the two duplexes, we concluded that the differences in Fpg activity are not due to differences in their global conformation. PMID:27322640

  11. Structural features of Ge(Ga) single crystals grown under conditions simulating the microgravity perturbation factors

    Energy Technology Data Exchange (ETDEWEB)

    Prokhorov, I.A.; Strelov, V.I.; Zakharov, B.G. [Space Materials Science Research Centre of the Crystallography Institute, RAS, Akademicheskaya 8, 248640 Kaluga (Russian Federation); Shul' pina, I.L.; Ratnikov, V.V. [Ioffe Physico-Technical Institute, RAS, Politekhnicheskaya 26, 194021 St. Petersburg (Russian Federation)

    2005-04-01

    Peculiarities of the real structure of Ge(Ga) single crystals grown under external mechanical perturbations of the crystallization process simulating actual microgravity environment aboard spacecrafts were investigated by X-ray topography and diffractometry methods, etching analysis and spreading resistance measurements. The applied perturbations included vibrations and variations of growth facility orientation with respect to the direction of gravity force. It has been shown that microinhomogeneity of the crystals grown is defined not only by formation of dopant growth striations at peculiar vibrational perturbations of a melt, but also by specific features of dislocation structure of crystals related with the formation of small angle boundaries, slip bands and other inhomogeneities in dislocation distribution. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  12. Structural features of anodic oxide films formed on aluminum substrate coated with self-assembled microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Asoh, Hidetaka [Department of Applied Chemistry, Faculty of Engineering, Kogakuin University, 2665-1 Nakano, Hachioji, Tokyo 192-0015 (Japan)], E-mail: asoh@cc.kogakuin.ac.jp; Uchibori, Kota; Ono, Sachiko [Department of Applied Chemistry, Faculty of Engineering, Kogakuin University, 2665-1 Nakano, Hachioji, Tokyo 192-0015 (Japan)

    2009-07-15

    The structural features of anodic oxide films formed on an aluminum substrate coated with self-assembled microspheres were investigated by scanning electron microscopy and atomic force microscopy. In the first anodization in neutral solution, the growth of a barrier-type film was partially suppressed in the contact area between the spheres and the underlying aluminum substrate, resulting in the formation of ordered dimple arrays in an anodic oxide film. After the subsequent second anodization in acid solution at a voltage lower than that of the first anodization, nanopores were generated only within each dimple. The nanoporous region could be removed selectively by post-chemical etching using the difference in structural dimensions between the porous region and the surrounding barrier region. The mechanism of anodic oxide growth on the aluminum substrate coated with microspheres through multistep anodization is discussed.

  13. Structural features of Ge(Ga) single crystals grown by the floating zone method in microgravity

    Science.gov (United States)

    Prokhorov, I. A.; Zakharov, B. G.; Senchenkov, A. S.; Egorov, A. V.; Camel, D.; Tison, P.

    2008-11-01

    Structural features of the Ge(Ga) single crystal grown by the floating zone (FZ) method in microgravity environment aboard the FOTON-9 spacecraft are investigated by methods of X-ray topography, double-crystal diffractometry, selective chemical etching and spreading resistance measurements. It is established that the crystal structure is characterized by the presence of an incompletely melted region and defects caused by its formation. Growth striations revealed in regrown part of the crystal, testify to development of non-stationary capillary Marangoni convection in melt at the realized parameters of FZ remelting under space conditions. Periodicity of the growth striations is compared to frequency characteristics of heat flux pulsations through the crystallization front, found as a result of numerical simulation of melt hydrodynamics.

  14. On the use of attractor dimension as a feature in structural health monitoring

    Science.gov (United States)

    Nichols, J.M.; Virgin, L.N.; Todd, M.D.; Nichols, J.D.

    2003-01-01

    Recent works in the vibration-based structural health monitoring community have emphasised the use of correlation dimension as a discriminating statistic in seperating a damaged from undamaged response. This paper explores the utility of attractor dimension as a 'feature' and offers some comparisons between different metrics reflecting dimension. This focus is on evaluating the performance of two different measures of dimension as damage indicators in a structural health monitoring context. Results indicate that the correlation dimension is probably a poor choice of statistic for the purpose of signal discrimination. Other measures of dimension may be used for the same purposes with a higher degree of statistical reliability. The question of competing methodologies is placed in a hypothesis testing framework and answered with experimental data taken from a cantilivered beam.

  15. Features of construction of structures in long-term training acrobatics at the modern stage

    Directory of Open Access Journals (Sweden)

    Bachynska N.V.

    2015-02-01

    Full Text Available Purpose: the basic directions of the structure of long-term training in sports acrobatics are ground. The objectives of the study was to determine the leading requirements and criteria, the main stages of a multi-year training in acrobatics. Material : analysis of special scientific and methodical literature, revealing the specific features of the construction of long-term training in sports and gymnastics, acrobatic rock 'n' roll, a number of other sports. Results : general structure, goals, objectives and provisions of the basic stages of a multi-year training in sports acrobatics. Singled leading indicators and criteria for each of the main stages of long-term sports training in acrobatics. Recommended duration of training sessions and key requirements for the preparation of acrobats. Conclusions : outlines the main requirements and benchmarks that can guide the trainer in a training and competitive activity when working with acrobats all age groups and different sports qualification.

  16. Anomalous Growth of Aging Populations

    Science.gov (United States)

    Grebenkov, Denis S.

    2016-04-01

    We consider a discrete-time population dynamics with age-dependent structure. At every time step, one of the alive individuals from the population is chosen randomly and removed with probability q_k depending on its age, whereas a new individual of age 1 is born with probability r. The model can also describe a single queue in which the service order is random while the service efficiency depends on a customer's "age" in the queue. We propose a mean field approximation to investigate the long-time asymptotic behavior of the mean population size. The age dependence is shown to lead to anomalous power-law growth of the population at the critical regime. The scaling exponent is determined by the asymptotic behavior of the probabilities q_k at large k. The mean field approximation is validated by Monte Carlo simulations.

  17. Structural features of LC8-induced self-association of swallow.

    Science.gov (United States)

    Kidane, Ariam I; Song, Yujuan; Nyarko, Afua; Hall, Justin; Hare, Michael; Löhr, Frank; Barbar, Elisar

    2013-09-01

    Cell functions depend on the collective activity of protein networks within which a few proteins, called hubs, participate in a large number of interactions. Dynein light chain LC8, first discovered as a subunit of the motor protein dynein, is considered to have a role broader than that of dynein, and its participation in diverse systems fits the description of a hub. Among its partners is Swallow with which LC8 is essential for proper localization of bicoid mRNA at the anterior cortex of Drosophila oocytes. Why LC8 is essential in this process is not clear, but emerging evidence suggests that LC8 functions by promoting self-association and/or structural organization of its diverse binding partners. This work addresses the energetics and structural features of LC8-induced Swallow self-association distant from LC8 binding. Mutational design based on a hypothetical helical wheel, intermonomer nuclear Overhauser effects assigned to residues expected at interface positions, and circular dichroism spectral characteristics indicate that the LC8-promoted dimer of Swallow is a coiled coil. Secondary chemical shifts and (15)N backbone relaxation identify the boundaries and distinguishing structural features of the coiled coil. Thermodynamic analysis of Swallow polypeptides designed to decouple self-association from LC8 binding reveals that the higher binding affinity of the engineered bivalent Swallow is of purely entropic origin and that the linker separating the coiled coil from the LC8 binding site remains disordered. We speculate that the LC8-promoted coiled coil is critical for bicoid mRNA localization because it favors structural organization of Swallow, which except for the central LC8-promoted coiled coil is primarily disordered. PMID:23914803

  18. Automated measurement of CT noise in patient images with a novel structure coherence feature.

    Science.gov (United States)

    Chun, Minsoo; Choi, Young Hun; Kim, Jong Hyo

    2015-12-01

    While the assessment of CT noise constitutes an important task for the optimization of scan protocols in clinical routine, the majority of noise measurements in practice still rely on manual operation, hence limiting their efficiency and reliability. This study presents an algorithm for the automated measurement of CT noise in patient images with a novel structure coherence feature. The proposed algorithm consists of a four-step procedure including subcutaneous fat tissue selection, the calculation of structure coherence feature, the determination of homogeneous ROIs, and the estimation of the average noise level. In an evaluation with 94 CT scans (16 517 images) of pediatric and adult patients along with the participation of two radiologists, ROIs were placed on a homogeneous fat region at 99.46% accuracy, and the agreement of the automated noise measurements with the radiologists' reference noise measurements (PCC  =  0.86) was substantially higher than the within and between-rater agreements of noise measurements (PCCwithin  =  0.75, PCCbetween  =  0.70). In addition, the absolute noise level measurements matched closely the theoretical noise levels generated by a reduced-dose simulation technique. Our proposed algorithm has the potential to be used for examining the appropriateness of radiation dose and the image quality of CT protocols for research purposes as well as clinical routine. PMID:26561914

  19. Nuclear structure of the heaviest nuclei: K-isomers and other features

    Energy Technology Data Exchange (ETDEWEB)

    Ackermann, D.; Hessberger, F.P.; Block, M.; Heinz, S.; Kojouharov, I.; Mann, R.; Sulignano, B. [GSI, Darmstadt (Germany); Antalic, S.; Streicher, B.; Venhart, M. [Univ. Bratislava (Slovakia); Herzberg, R.D. [Univ. Liverpool (United Kingdom); Hofmann, S. [GSI, Darmstadt (Germany)]|[Univ. Frankfurt (Germany); Khuyagbaatar, J. [GSI, Darmstadt (Germany)]|[Univ. St. Petersburg (Russian Federation); Nishio, K. [JAEA, Tokai (Japan)

    2008-07-01

    The borderlines of the chart of nuclei are in the focus of interest of the nuclear physics community. Ambitious projects to reach extreme isospin and to push towards the limits of stability are on the books of the funding agencies worldwide. New features of nuclear matter are expected under these extreme conditions. The quantum mechanical properties and the evolution of the shell model will be probed. In our endeavour to approach the predicted ''Island of stability'' at Z=114,120 or 126 and N=184 we performed, apart from the search for new elements, also nuclear structure studies for heaviest nuclei. The isomeric states that we recently observed in {sup 252}No and {sup 270}Ds are only two examples of the many facets of interesting physics to be discovered in this region. Systematic investigation of the nuclear structure is also essential for a successful progress in element synthesis. In radioactive decay studies, i.e. evaporation residue (ER)-{alpha}-{gamma} coincidences of ERs implanted into a Si detector after a separator, we studied features like K-isomerism and the trend of single particle levels in isotopic and isotonic chains in the region of Z=100 (fermium) to 110 (darmstadtium).

  20. CFD Simulation of Flow Features and Vorticity Structures in Tuna-Like Swimming

    Institute of Scientific and Technical Information of China (English)

    YANG Liang; SU Yu-min

    2011-01-01

    The theoretical research on the propulsive principle of aquatic animal becomes more important and attracted more researchers to make efforts on it.In the present study,a computational fluid dynamic(CFD)simulation of a three-dimensional traveling-wave undulations body of tuna has been developed to investigate the fluid flow features and vorticity structures around this body when moving in a straight line.The undulation only takes place in the posterior half of the fish,and the tuna-tail is considered as a lunate fin oscillating with the mode combined swaying with yawing.A Reynolds-averaged Navier-Stokes(BANS)equation is developed,employing a control-volume method and a k-omega SST turbulent model;meanwhile an unstructured tetrahedral grid,which is generated for the three-dimensional geometry,is used based on the deformation of the hind parts of the body and corresponding movement of the tail.We calculated the hydrodynamic performance of tuna-like body when a tuna swims in a uniform velocity,and compared the input power coefficient,output power coefficient and propulsive efficiency of the oscillating tuna-tail with or without body vortex shedding.Additionally,the load distribution on the body,flow features and vorticity structures around the body were demonstrated.The effect of interaction between the body-generated vortices and the tail-generated vorticity on the hydrodynamic performance can be obtained.

  1. CFD simulation of flow features and vorticity structures in tuna-like swimming

    Science.gov (United States)

    Yang, Liang; Su, Yu-Min

    2011-03-01

    The theoretical research on the propulsive principle of aquatic animal becomes more important and attracted more researchers to make efforts on it. In the present study, a computational fluid dynamic (CFD) simulation of a three-dimensional traveling-wave undulations body of tuna has been developed to investigate the fluid flow features and vorticity structures around this body when moving in a straight line. The undulation only takes place in the posterior half of the fish, and the tuna-tail is considered as a lunate fin oscillating with the mode combined swaying with yawing. A Reynolds-averaged Navier-Stokes (RANS) equation is developed, employing a control-volume method and a k-omega SST turbulent model; meanwhile an unstructured tetrahedral grid, which is generated for the three-dimensional geometry, is used based on the deformation of the hind parts of the body and corresponding movement of the tail. We calculated the hydrodynamic performance of tuna-like body when a tuna swims in a uniform velocity, and compared the input power coefficient, output power coefficient and propulsive efficiency of the oscillating tuna-tail with or without body vortex shedding. Additionally, the load distribution on the body, flow features and vorticity structures around the body were demonstrated. The effect of interaction between the body-generated vortices and the tail-generated vorticity on the hydrodynamic performance can be obtained.

  2. SoftSearch: integration of multiple sequence features to identify breakpoints of structural variations.

    Directory of Open Access Journals (Sweden)

    Steven N Hart

    Full Text Available BACKGROUND: Structural variation (SV represents a significant, yet poorly understood contribution to an individual's genetic makeup. Advanced next-generation sequencing technologies are widely used to discover such variations, but there is no single detection tool that is considered a community standard. In an attempt to fulfil this need, we developed an algorithm, SoftSearch, for discovering structural variant breakpoints in Illumina paired-end next-generation sequencing data. SoftSearch combines multiple strategies for detecting SV including split-read, discordant read-pair, and unmated pairs. Co-localized split-reads and discordant read pairs are used to refine the breakpoints. RESULTS: We developed and validated SoftSearch using real and synthetic datasets. SoftSearch's key features are 1 not requiring secondary (or exhaustive primary alignment, 2 portability into established sequencing workflows, and 3 is applicable to any DNA-sequencing experiment (e.g. whole genome, exome, custom capture, etc.. SoftSearch identifies breakpoints from a small number of soft-clipped bases from split reads and a few discordant read-pairs which on their own would not be sufficient to make an SV call. CONCLUSIONS: We show that SoftSearch can identify more true SVs by combining multiple sequence features. SoftSearch was able to call clinically relevant SVs in the BRCA2 gene not reported by other tools while offering significantly improved overall performance.

  3. Automated measurement of CT noise in patient images with a novel structure coherence feature

    International Nuclear Information System (INIS)

    While the assessment of CT noise constitutes an important task for the optimization of scan protocols in clinical routine, the majority of noise measurements in practice still rely on manual operation, hence limiting their efficiency and reliability. This study presents an algorithm for the automated measurement of CT noise in patient images with a novel structure coherence feature. The proposed algorithm consists of a four-step procedure including subcutaneous fat tissue selection, the calculation of structure coherence feature, the determination of homogeneous ROIs, and the estimation of the average noise level. In an evaluation with 94 CT scans (16 517 images) of pediatric and adult patients along with the participation of two radiologists, ROIs were placed on a homogeneous fat region at 99.46% accuracy, and the agreement of the automated noise measurements with the radiologists’ reference noise measurements (PCC  =  0.86) was substantially higher than the within and between-rater agreements of noise measurements (PCCwithin  =  0.75, PCCbetween  =  0.70). In addition, the absolute noise level measurements matched closely the theoretical noise levels generated by a reduced-dose simulation technique. Our proposed algorithm has the potential to be used for examining the appropriateness of radiation dose and the image quality of CT protocols for research purposes as well as clinical routine. (paper)

  4. On the structural features of fiber suspensions in converging channel flow

    Institute of Scientific and Technical Information of China (English)

    林建忠; 张凌新

    2003-01-01

    The structural features of fiber suspensions are dependent on the fiber alignment in the flows. In this work the orientation distribution function and orientation tensors for semi-concentrated fiber suspensions in converging channel flow were calculated, and the evolutions of the fiber alignment and the bulk effective vis-cosity were analyzed. The results showed that the bulk stress and the effective viscosity were functions of therate-of-strain tensor and the fiber orientation state ; and that the fiber suspensions evolved to steady alignment and tended to concentrate to some preferred directions close to but not same as the directions of local stream-lines. The bulk effective viscosity depended on the product of Reynolds number and time. The decrease of ef-fective viscosity near the boundary benefited the increase of the rate of flow. Finally when the fiber alignment went into steady state, the structural features of fiber suspensions were not dependent on the Reynolds numberbut on the converging channel angle.

  5. Automated measurement of CT noise in patient images with a novel structure coherence feature

    Science.gov (United States)

    Chun, Minsoo; Choi, Young Hun; Hyo Kim, Jong

    2015-12-01

    While the assessment of CT noise constitutes an important task for the optimization of scan protocols in clinical routine, the majority of noise measurements in practice still rely on manual operation, hence limiting their efficiency and reliability. This study presents an algorithm for the automated measurement of CT noise in patient images with a novel structure coherence feature. The proposed algorithm consists of a four-step procedure including subcutaneous fat tissue selection, the calculation of structure coherence feature, the determination of homogeneous ROIs, and the estimation of the average noise level. In an evaluation with 94 CT scans (16 517 images) of pediatric and adult patients along with the participation of two radiologists, ROIs were placed on a homogeneous fat region at 99.46% accuracy, and the agreement of the automated noise measurements with the radiologists’ reference noise measurements (PCC  =  0.86) was substantially higher than the within and between-rater agreements of noise measurements (PCCwithin  =  0.75, PCCbetween  =  0.70). In addition, the absolute noise level measurements matched closely the theoretical noise levels generated by a reduced-dose simulation technique. Our proposed algorithm has the potential to be used for examining the appropriateness of radiation dose and the image quality of CT protocols for research purposes as well as clinical routine.

  6. Anomalous Dimensions of Conformal Baryons

    CERN Document Server

    Pica, Claudio

    2016-01-01

    We determine the anomalous dimensions of baryon operators for the three color theory as function of the number of massless flavours within the conformal window to the maximum known order in perturbation theory. We show that the anomalous dimension of the baryon is controllably small for a wide range of number of flavours. We also find that this is always smaller than the anomalous dimension of the fermion mass operator. These findings challenge the partial compositeness paradigm.

  7. The Structure of Neurexin 1[alpha] Reveals Features Promoting a Role as Synaptic Organizer

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Fang; Venugopal, Vandavasi; Murray, Beverly; Rudenko, Gabby (Michigan)

    2014-10-02

    {alpha}-Neurexins are essential synaptic adhesion molecules implicated in autism spectrum disorder and schizophrenia. The {alpha}-neurexin extracellular domain consists of six LNS domains interspersed by three EGF-like repeats and interacts with many different proteins in the synaptic cleft. To understand how {alpha}-neurexins might function as synaptic organizers, we solved the structure of the neurexin 1{alpha} extracellular domain (n1{alpha}) to 2.65 {angstrom}. The L-shaped molecule can be divided into a flexible repeat I (LNS1-EGF-A-LNS2), a rigid horseshoe-shaped repeat II (LNS3-EGF-B-LNS4) with structural similarity to so-called reelin repeats, and an extended repeat III (LNS5-EGF-B-LNS6) with controlled flexibility. A 2.95 {angstrom} structure of n1{alpha} carrying splice insert SS3 in LNS4 reveals that SS3 protrudes as a loop and does not alter the rigid arrangement of repeat II. The global architecture imposed by conserved structural features enables {alpha}-neurexins to recruit and organize proteins in distinct and variable ways, influenced by splicing, thereby promoting synaptic function.

  8. Topological features in crystal structures: a quotient graph assisted analysis of underlying nets and their embeddings.

    Science.gov (United States)

    Eon, Jean Guillaume

    2016-05-01

    Topological properties of crystal structures may be analysed at different levels, depending on the representation and the topology that has been assigned to the crystal. Considered here is the combinatorial or bond topology of the structure, which is independent of its realization in space. Periodic nets representing one-dimensional complexes, or the associated graphs, characterize the skeleton of chemical bonds within the crystal. Since periodic nets can be faithfully represented by their labelled quotient graphs, it may be inferred that their topological features can be recovered by a direct analysis of the labelled quotient graph. Evidence is given for ring analysis and structure decomposition into building units and building networks. An algebraic treatment is developed for ring analysis and thoroughly applied to a description of coesite. Building units can be finite or infinite, corresponding to 1-, 2- or even 3-periodic subnets. The list of infinite units includes linear chains or sheets of corner- or edge-sharing polyhedra. Decomposing periodic nets into their building units relies on graph-theoretical methods classified as surgery techniques. The most relevant operations are edge subdivision, vertex identification, edge contraction and decoration. Instead, these operations can be performed on labelled quotient graphs, evidencing in almost a mechanical way the nature and connection mode of building units in the derived net. Various examples are discussed, ranging from finite building blocks to 3-periodic subnets. Among others, the structures of strontium oxychloride, spinel, lithiophilite and garnet are addressed. PMID:27126104

  9. CDK1 structures reveal conserved and unique features of the essential cell cycle CDK

    Science.gov (United States)

    Brown, Nicholas R.; Korolchuk, Svitlana; Martin, Mathew P.; Stanley, Will A.; Moukhametzianov, Rouslan; Noble, Martin E. M.; Endicott, Jane A.

    2015-04-01

    CDK1 is the only essential cell cycle CDK in human cells and is required for successful completion of M-phase. It is the founding member of the CDK family and is conserved across all eukaryotes. Here we report the crystal structures of complexes of CDK1-Cks1 and CDK1-cyclin B-Cks2. These structures confirm the conserved nature of the inactive monomeric CDK fold and its ability to be remodelled by cyclin binding. Relative to CDK2-cyclin A, CDK1-cyclin B is less thermally stable, has a smaller interfacial surface, is more susceptible to activation segment dephosphorylation and shows differences in the substrate sequence features that determine activity. Both CDK1 and CDK2 are potential cancer targets for which selective compounds are required. We also describe the first structure of CDK1 bound to a potent ATP-competitive inhibitor and identify aspects of CDK1 structure and plasticity that might be exploited to develop CDK1-selective inhibitors.

  10. No evidence for anomalously low variance circles on the sky

    CERN Document Server

    Moss, Adam; Zibin, James P

    2010-01-01

    In a recent paper, Gurzadyan & Penrose claim to have found directions on the sky centred on which are circles of anomalously low variance in the cosmic microwave background (CMB). These features are presented as evidence for a particular picture of the very early Universe. We attempted to repeat the analysis of these authors, and we can indeed confirm that such variations do exist in the temperature variance for annuli around points in the data. However, we find that this variation is entirely expected in a sky which contains the usual CMB anisotropies. In other words, properly simulated Gaussian CMB data contain just the sorts of variations claimed. Gurzadyan & Penrose have not found evidence for pre-Big Bang phenomena, but have simply re-discovered that the CMB contains structure.

  11. Anomalous transport in high-temperature plasmas with applications to solenoidal fusion systems

    International Nuclear Information System (INIS)

    The linear, non-linear, and anomalous transport properties associated with various micro-instabilities driven by cross-field currents in high-temperature plasmas are reviewed. Particular emphasis is placed on instabilities pertinent to the implosion and post-implosion phases of theta-pinch plasmas, e.g. Buneman (electron-ion two-stream), ion acoustic, lower-hybrid-drift, electromagnetic ion cyclotron, and ion-ion cross-field instabilities. Analytic studies of the non-linear and quasi-linear evolution of these instabilities are presented, together with a detailed comparison with computer simulation experiments to test the validity of the various theoretical models and non-linear saturation mechanisms. A general theoretical formalism is presented which describes, in a self-consistent manner, the macroscopic transport produced by the (short-wave-length) turbulence associated with the microinstabilities enumerated above. The experimental evidence that such a self-consistent anomalous transport model is required for describing the implosion behaviour (characterized by diffuse current sheaths) in rapidly pulsed theta pinches is reviewed, together with the early attempts at modelling these implosions numerically with a one-fluid (MHD) model including artificial viscosity. It is shown that fluid-numerical simulations that include (at each space and time step) the effects of anomalous transport in a fully self-consistent manner, explain several features of the experimental observations. The relevance of reflected ions to sheath structure and implosion dynamics is also discussed, and state-of-the-art hybrid-numerical studies (Vlasov ions and fluid electrons) of pinch implosions are presented, which include reflected ion dynamics as well as the anomalous transport associated with cross-field instabilities. Finally, instability mechanisms for producing long-time interpenetration of plasma and magnetic field in post-implosion theta pinches are discussed, together with estimates

  12. GeneViTo: Visualizing gene-product functional and structural features in genomic datasets

    Directory of Open Access Journals (Sweden)

    Promponas Vasilis J

    2003-10-01

    Full Text Available Abstract Background The availability of increasing amounts of sequence data from completely sequenced genomes boosts the development of new computational methods for automated genome annotation and comparative genomics. Therefore, there is a need for tools that facilitate the visualization of raw data and results produced by bioinformatics analysis, providing new means for interactive genome exploration. Visual inspection can be used as a basis to assess the quality of various analysis algorithms and to aid in-depth genomic studies. Results GeneViTo is a JAVA-based computer application that serves as a workbench for genome-wide analysis through visual interaction. The application deals with various experimental information concerning both DNA and protein sequences (derived from public sequence databases or proprietary data sources and meta-data obtained by various prediction algorithms, classification schemes or user-defined features. Interaction with a Graphical User Interface (GUI allows easy extraction of genomic and proteomic data referring to the sequence itself, sequence features, or general structural and functional features. Emphasis is laid on the potential comparison between annotation and prediction data in order to offer a supplement to the provided information, especially in cases of "poor" annotation, or an evaluation of available predictions. Moreover, desired information can be output in high quality JPEG image files for further elaboration and scientific use. A compilation of properly formatted GeneViTo input data for demonstration is available to interested readers for two completely sequenced prokaryotes, Chlamydia trachomatis and Methanococcus jannaschii. Conclusions GeneViTo offers an inspectional view of genomic functional elements, concerning data stemming both from database annotation and analysis tools for an overall analysis of existing genomes. The application is compatible with Linux or Windows ME-2000-XP operating

  13. Light-harvesting features revealed by the structure of plant Photosystem I

    CERN Document Server

    Ben-Shem, A; Nelson, N; 10.1023/B:PRES.0000036881.23512.42

    2004-01-01

    Oxygenic photosynthesis is driven by two multi-subunit membrane protein complexes, Photosystem I and Photosystem II. In plants and green algae, both complexes are composed of two moieties: a reaction center (RC), where light-induced charge translocation occurs, and a peripheral antenna that absorbs light and funnels its energy to the reaction center. The peripheral antenna of PS I (LHC I) is composed of four gene products (Lhca 1-4) that are unique among the chlorophyll a/b binding proteins in their pronounced long-wavelength absorbance and in their assembly into dimers. The recently determined structure of plant Photosystem I provides the first relatively high- resolution structural model of a super-complex containing a reaction center and its peripheral antenna. We describe some of the structural features responsible for the unique properties of LHC I and discuss the advantages of the particular LHC I dimerization mode over monomeric or trimeric forms. In addition, we delineate some of the interactions betw...

  14. Novel RNA structural features of an alternatively splicing group II intron from Clostridium tetani.

    Science.gov (United States)

    McNeil, Bonnie A; Zimmerly, Steven

    2014-06-01

    Group II introns are ribozymes in bacterial and organellar genomes that function as self-splicing introns and as retroelements. Previously, we reported that the group II intron C.te.I1 of Clostridium tetani alternatively splices in vivo to produce five distinct coding mRNAs. Accurate fusion of upstream and downstream reading frames requires a shifted 5' splice site located 8 nt upstream of the usual 5' GUGYG motif. This site is specified by the ribozyme through an altered intron/exon-binding site 1 (IBS1-EBS1) pairing. Here we use mutagenesis and self-splicing assays to investigate in more detail the significance of the structural features of the C.te.I1 ribozyme. The shifted 5' splice site is shown to be affected by structures in addition to IBS1-EBS1, and unlike other group II introns, C.te.I1 appears to require a spacer between IBS1 and the GUGYG motif. In addition, the mechanism of 3' exon recognition is modified from the ancestral IIB mechanism to a IIA-like mechanism that appears to be longer than the typical single base-pair interaction and may extend up to 4 bp. The novel ribozyme properties that have evolved for C.te.I1 illustrate the plasticity of group II introns in adapting new structural and catalytic properties that can be utilized to affect gene expression. PMID:24751650

  15. GALT protein database: querying structural and functional features of GALT enzyme.

    Science.gov (United States)

    d'Acierno, Antonio; Facchiano, Angelo; Marabotti, Anna

    2014-09-01

    Knowledge of the impact of variations on protein structure can enhance the comprehension of the mechanisms of genetic diseases related to that protein. Here, we present a new version of GALT Protein Database, a Web-accessible data repository for the storage and interrogation of structural effects of variations of the enzyme galactose-1-phosphate uridylyltransferase (GALT), the impairment of which leads to classic Galactosemia, a rare genetic disease. This new version of this database now contains the models of 201 missense variants of GALT enzyme, including heterozygous variants, and it allows users not only to retrieve information about the missense variations affecting this protein, but also to investigate their impact on substrate binding, intersubunit interactions, stability, and other structural features. In addition, it allows the interactive visualization of the models of variants collected into the database. We have developed additional tools to improve the use of the database by nonspecialized users. This Web-accessible database (http://bioinformatica.isa.cnr.it/GALT/GALT2.0) represents a model of tools potentially suitable for application to other proteins that are involved in human pathologies and that are subjected to genetic variations. PMID:24990533

  16. Influence of structural features on immunostimulating activity of glucans extracted from Agaricus blazei mushroom

    Directory of Open Access Journals (Sweden)

    Kozarski Maja S.

    2009-01-01

    Full Text Available High molecular weight b-D-glucans derived from Basidiomycetes cell walls are able to specifically activate cellular and humoral components of the host immune system. The aim of this paper was to examine immunomodulating activity of native, chemically and enzimatically modified glucans from Agaricus blazei mushroom and to determine which structural features are of primary importance for their stimulation referring to humane immune cells. The immunomodulating activities were tested in vitro, by stimulation of peripheral blood mononuclear cells (PBMCs and measuring of interferon-gamma (IFN-g production by enzyme linked immunosorbent assay (ELISA. Measurements of immunomodulatory capacity of Agaricus blazei native glucans showed their expressive immunostimulating effect on activated PBMCs and synthesis of IFN-g. The results obtained after the stimulation of cells with 1M H2SO4 and 1M NaOH, the treated glucans showed that primary structure is of more importance than the tertiary structure of the triple helix for their immunostimulating activity and synthesis of IFN-g. Glucans of lower molecular weight obtained after acid hydrolysis appeared as effective immunostimulators of PBMC's. The results obtained after the incubation of cells with 1,6 b-glucanase modified glucans suggest that b-(1,6 binding of glucose monomers probably has no importance for the production of imunostimulating effects, in vitro. This confirmed that b-(1,3 bonds are the primary determinants of immunomodulatory activities and stimulation of IFN-g synthesis.

  17. Structural and Functional Features of Peroxidases with a Potential as Industrial Biocatalysts

    Science.gov (United States)

    Ruiz-Dueñas, Francisco J.; Martínez, Angel T.

    This chapter begins with a description of the main structural features of heme peroxidases representative of the two large superfamilies of plant-fungal-bacterial and animal peroxidases, and the four additional (super)families described to date. Then, we focus on several fungal peroxidases of high biotechnological potential as industrial biocatalysts. These include (1) ligninolytic peroxidases from white-rot basidiomycetes being able to oxidize high redox-potential substrates at an exposed protein radical; (2) heme-thiolate peroxidases that are structural hybrids of typical peroxidases and cytochrome P450 enzymes and, after their discovery in sooty molds, are being described in basidiomycetes with even more interesting catalytic properties, such as selective aromatic oxygenation; and (3) the so-called dye-decolorizing peroxidases that are still to be thoroughly investigated but have been identified in different basidiomycete genomes. The structural-functional description of these peroxidases includes an analysis of the heme environment and a description of their substrate oxidation sites, with the purpose of understanding their interesting catalytic properties and biotechnological potential.

  18. Features of rat skin structure in norm and at pyrogenalum action

    Directory of Open Access Journals (Sweden)

    Shapovalov D.A.

    2008-01-01

    Full Text Available On 48 rats-males of genesial age in mass 140-210, which have been parted on four groups: 1 group – control; 2, 3, 4 groups – experimental (entered Pyrogenalum in a dose of 3,0 mg/kg once a day throughout the days two and three accordingly features of a structure of a skin in norm have been studied and at Pyrogenalum introduction. The microscopic sections of a skin received in two is mutual perpendicular planes, dyed by hematoxylin-eosin and Mallory-Slinchenko's method. The obtained quantitative data processed with use of methods of variation statistics. After intraperitoneal introduction of Pyrogenalum in a dose of 3,0 mg / kg of change of a structure of a skin occur in all регионально various sites. They consist in augmentation of a thickness of separate layers of a skin, augmentation of diameter of lead-out ducts потовых glands, edemas of tissues, reduction of density of collagen fibers. To the greatest changes at a hyperthermia a vascular bed of a skin which are most expressed at early o'clock after Pyrogenalum introduction. At secondary introductions of Pyrogenalum of rasping changes in a skin does not occur and for 7 8 days the skin structure is similar to a skin of control group of animals.

  19. Automatic registration of Iphone images to LASER point clouds of the urban structures using shape features

    Science.gov (United States)

    Sirmacek, B.; Lindenbergh, R. C.; Menenti, M.

    2013-10-01

    Fusion of 3D airborne laser (LIDAR) data and terrestrial optical imagery can be applied in 3D urban modeling and model up-dating. The most challenging aspect of the fusion procedure is registering the terrestrial optical images on the LIDAR point clouds. In this article, we propose an approach for registering these two different data from different sensor sources. As we use iPhone camera images which are taken in front of the interested urban structure by the application user and the high resolution LIDAR point clouds of the acquired by an airborne laser sensor. After finding the photo capturing position and orientation from the iPhone photograph metafile, we automatically select the area of interest in the point cloud and transform it into a range image which has only grayscale intensity levels according to the distance from the image acquisition position. We benefit from local features for registering the iPhone image to the generated range image. In this article, we have applied the registration process based on local feature extraction and graph matching. Finally, the registration result is used for facade texture mapping on the 3D building surface mesh which is generated from the LIDAR point cloud. Our experimental results indicate possible usage of the proposed algorithm framework for 3D urban map updating and enhancing purposes.

  20. Probabilistic uncertainty quantification of wavelet-transform-based structural health monitoring features

    Science.gov (United States)

    Sarrafi, Aral; Mao, Zhu

    2016-04-01

    In the application of Structural Health Monitoring (SHM), processing the online-acquired data plays a very important role, among which wavelet transform is an outstanding tool and compared to Fourier transform, it handles the nonstationary behaviors in the time series in an adaptive fashion. When dealing with time-variant data, there are uncertainties from numerous resources inherent to the feature estimation, such as measurement noise, operational and environmental variability, hardware limitation, etc. The corruption from uncertainty will make the data interpretation ambiguous and thereby dramatically degrades the decision quality with regard to the occurrence, location, severity, and extent of damages. This paper derives a probabilistic model to quantify analytically the uncertainty of wavelet transform feature as a random variable, and variance is derived analytically in this work. Considering central limit theorem, Gaussian probability density function characterizes the distribution and this has been validated via Monte Carlo testing. By fully characterizing the uncertainty, the damage detection implementations may be facilitated with a quantified false alarm rate and miss catch rate.

  1. Structural contour, isopach and feature maps of quaternary sediments in Western Lake Ontario

    International Nuclear Information System (INIS)

    A systematic high-resolution acoustic reconnaissance survey of Quaternary sediments (> 50 m thick, in places) and the underlying bedrock surface was completed for western Lake Ontario between Burlington and Port Hope, Ontario, to determine if geophysical lineaments through the area of Pickering and Darlington nuclear power stations are potentially seismically active. A total of 2530 line-km of data were obtained along N-S and E-W lines spaced 10 and 5 km respectively, using a high-resolution subbottom profiler (boomer and IKB-SEISTEC), a 100 kHz sidescan sonar (150-m range) with 3.5 kHz profiler, a 10 or 40 cu. in. sleeve gun seismic reflection system, and, intermittently, a marine magnetometer. Six piston cores up to 15-m long were collected to compare sediment lithology with key regional seismic reflectors. Sediments deposited over the past 13,000 years were imaged with vertical resolution in the order of 10-30 cm just below the lakebed and less than 1 m at the bedrock surface; resolution for the sleeve gun system is approximately 3-5 m. Digital processing and rescaling of selected seismic profiles aided interpretation. Structural contour maps for three Quaternary sequence boundaries and the bedrock surface were generated together with the related sequence isopach maps. Three additional maps portray lakebed features identified on sidescan sonar records and subsurface features identified on seismic profiles. All maps are at 1:250,000 scale. (author). 2 tabs., 48 figs., 12 maps

  2. Raman imaging to study structural and chemical features of the dentin enamel junction

    Science.gov (United States)

    Alebrahim, M. Anwar; Krafft, C.; Popp, J.

    2015-10-01

    The structure and chemical features of the human dentin enamel junction (DEJ) were characterized using Raman spectroscopic imaging. Slices were prepared from 10 German, and 10 Turkish teeth. Raman images were collected at 785 nm excitation and the average Raman spectra were calculated for analysis. Univariate and multivariate spectral analysis were applied for investigation. Raman images were obtained based on the intensity ratios of CH at 1450 cm-1 (matrix) to phosphate at 960 cm-1 (mineral), and carbonate to phosphate (1070/960) ratios. Different algorithms (HCA, K-means cluster and VCA) also used to study the DEJ. The obtained results showed that the width of DEJ is about 5 pm related to univariate method while it varies from 6 to 12 μm based on multivariate spectral technique. Both spectral analyses showed increasing in carbonate content inside the DEJ compared to the dentin, and the amide I (collagen) peak in dentin spectra is higher than DEJ spectra peak.

  3. Multipotent natural agents to combat Alzheimer's disease. Functional spectrum and structural features

    Institute of Scientific and Technical Information of China (English)

    Hong-fang JI; Hong-yu ZHANG

    2008-01-01

    With the accelerated aging of human society, Alzheimer's disease (AD) is becoming one of the biggest threats to human health. Since multiple pathogenetic factors are implicated in the disease, the current hitting-one-target therapeutic strategy has proved inefficient to AD. As a result, finding multipotent agents that aim at multiple targets is attracting more and more attention. Although multifunc-tional anti-AD agents can be created by incorporating two or more pharmacophores in one scaffold, naturally occurring multipotent agents also attracted much attention. In this review, we first describe the functions of some typical naturally originated multipotent anti-AD compounds, then summarize their structural fea-tures and reveal that phenolics with certain flexibility predominate in these agents, which are of significance to find novel multipotent drugs to combat AD and other neurodegenerative diseases as well.

  4. Low-frequency features of the ultrasound echo from an adhesively bonded layer-substrate structure

    Institute of Scientific and Technical Information of China (English)

    WANG Xiaomin; LI Mingxuan; MAO Jie; LIAN Guoxuan

    2005-01-01

    The low-frequency features of the ultrasound reflection spectra from the structure of a single layer on a substrate bonded by a thin adhesive layer are theoretically studied; the low-frequency here means the frequency of the interrogating ultrasonic wave is less than the quart-wavelength resonance frequency of the adhesive layer. The possibility of the inversion of the thickness and the evaluation of the cohesion strength of the adhesive layer from the resonance frequency shifts of the layered system is indicated. An analytic solution to the nonlinear equation satisfied by the resonance frequency is presented by Taylor expansion method showing satisfactory agreement with the numerical results by Newton iterative method. The results indicate larger range for application than the traditional spring model for the thin adhesive layer. In a much lower frequency range the thin adhesive layer may be regarded to be a spring.

  5. Disturbance structures and its magnetic field features in plasma comet tail

    International Nuclear Information System (INIS)

    The solar wind disturbances result in the emergence of condensation structures in plasma comet tail. Most of them are correlated with plasma vortex flow. In this paper, we analyze the features of condensations basing on the theories of MHD and force-free field. Specifically, we discuss the construction and the distribution of magnetic field and its energy in condensations. We also analyze in detail the coupling process between an unsteady plasma motion and a magnetic field. The coupling effect will let the energy in comet tail change into the force-free field in condensations, so that the magnetic field energy in the condensations increases constantly. Many phenomena observed in comet tail can be explained with the model. (author). 22 refs

  6. Features of glycoproteins distribution in the pancreatic structures of newborn rats after prenatal antigenic influence

    Directory of Open Access Journals (Sweden)

    Grinivetska N.V.

    2014-03-01

    Full Text Available Background. Abnormalities of digestion and absorption are the most common syndromes associated with the digestive system diseases in children. Pancreatic enzyme failure leads to violation of different metabolic processes, especially in neonates. Exocrine pancreas is sensitive to a variety of factors, including virus. It emphasizes the importance of investigation of pancreatic secretory activity in children who was born from mothers exposed to viral infection during pregnancy. Objective. The purpose is to determine the features of glycoproteins distribution in the pancreatic structures of newborn rats after prenatal antigenic influence. Methods. Animals were divided into four groups: the 1st – intact, the 2nd – intrafetal injection of the antigen, the 3rd – animals administered with antigen into the amniotic fluid, and the 4th group – control (intrafetal injection of a normal salt solution. As antigen we used Vaxigrip vaccine. Results. It was revealed that on the14th day after birth antigen-exposed animals were characterized by the increase of glycoproteins (++ in a connective tissue capsule of pancreas and decreased content of glycoproteins in the cytoplasm of acinar cells and ducts comparing with the intact group (++/+. Taken together this data evidence the reduction of the synthetic activity of acinar cells after intrafetal administration of the antigen. This may cause a predisposition for the development of dyspepsia and food allergy. Further work is planned to investigate the dynamics of glycosaminoglycans redistribution in different parts of pancreas after prenatal antigenic administrations. Citation: Grinivetska NV. [Features of glycoproteins distribution in the pancreatic structures of newborn rats after prenatal antigenic influence]. Morphologia. 2014;8(1:30-4. Ukrainian.

  7. Anomalous enthalpy relaxation in vitreous silica

    DEFF Research Database (Denmark)

    Yue, Yuanzheng

    2015-01-01

    scans. It is known that the liquid fragility (i.e., the speed of the viscous slow-down of a supercooled liquid at its Tg during cooling) has impact on enthalpy relaxation in glass. Here, we find that vitreous silica (as a strong system) exhibits striking anomalies in both glass transition and enthalpy...... relaxation compared to fragile oxide systems. The anomalous enthalpy relaxation of vitreous silica is discovered by performing the hyperquenching-annealing-calorimetry experiments. We argue that the strong systems like vitreous silica and vitreous Germania relax in a structurally cooperative manner, whereas...... the fragile ones do in a structurally independent fashion. We discuss the origin of the anomalous enthalpy relaxation in the HQ vitreous silica....

  8. Medicinal properties of mangiferin, structural features, derivative synthesis, pharmacokinetics and biological activities.

    Science.gov (United States)

    Benard, Outhiriaradjou; Chi, Yuling

    2015-01-01

    The identification of biologically active and potentially therapeutically useful pharmacophores from natural products has been a long-term focus in the pharmaceutical industry. The recent emergence of a worldwide obesity and Type II diabetes epidemic has increased focus upon small molecules that can modulate energy metabolism, insulin sensitivity and fat biology. Interesting preliminary work done on mangiferin (MGF), the predominant constituent of extracts of the mango plant Mangifera indica L., portends potential for this pharmacophore as a novel parent compound for treating metabolic disorders. MGF is comprised of a C-glucosylated xanthone. Owing to the xanthone chemical structure, MGF has a redox active aromatic system and has antioxidant properties. MGF exerts varied and impressive metabolic effects in animals, improving metabolic disorders. For example we have discovered that MGF is a novel activator of the mammalian pyruvate dehydrogenase complex, leading to enhancement of carbohydrate utilization in oxidative metabolism, and leading to increased insulin sensitivity in animal models of obesity and insulin resistance. In addition, recent unbiased proteomics studies revealed that MGF upregulates proteins pivotal for mitochondrial bioenergetics and downregulates proteins controlling de novo lipogenesis in liver, helping to explain protective effects of MGF in prevention of liver steatosis. Several chemical studies have achieved synthesis of MGF, suggesting possible synthetic strategies to alter its chemical structure for development of structure-activity relationship (SAR) information. Ultimately, chemical derivatization studies could lead to the eventual development of novel therapeutics based upon the parent pharmacophore structure. Here we provide comprehensive review on chemical features of MGF, synthesis of its derivatives, its pharmacokinetics and biological activities. PMID:25827900

  9. Spectrum of anomalous magnetohydrodynamics

    Science.gov (United States)

    Giovannini, Massimo

    2016-05-01

    The equations of anomalous magnetohydrodynamics describe an Abelian plasma where conduction and chiral currents are simultaneously present and constrained by the second law of thermodynamics. At high frequencies the magnetic currents play the leading role, and the spectrum is dominated by two-fluid effects. The system behaves instead as a single fluid in the low-frequency regime where the vortical currents induce potentially large hypermagnetic fields. After deriving the physical solutions of the generalized Appleton-Hartree equation, the corresponding dispersion relations are scrutinized and compared with the results valid for cold plasmas. Hypermagnetic knots and fluid vortices can be concurrently present at very low frequencies and suggest a qualitatively different dynamics of the hydromagnetic nonlinearities.

  10. Detection of anomalous events

    Energy Technology Data Exchange (ETDEWEB)

    Ferragut, Erik M.; Laska, Jason A.; Bridges, Robert A.

    2016-06-07

    A system is described for receiving a stream of events and scoring the events based on anomalousness and maliciousness (or other classification). The system can include a plurality of anomaly detectors that together implement an algorithm to identify low-probability events and detect atypical traffic patterns. The anomaly detector provides for comparability of disparate sources of data (e.g., network flow data and firewall logs.) Additionally, the anomaly detector allows for regulatability, meaning that the algorithm can be user configurable to adjust a number of false alerts. The anomaly detector can be used for a variety of probability density functions, including normal Gaussian distributions, irregular distributions, as well as functions associated with continuous or discrete variables.

  11. Optically Anomalous Crystals

    CERN Document Server

    Shtukenberg, Alexander; Kahr, Bart

    2007-01-01

    Optical anomalies in crystals are puzzles that collectively constituted the greatest unsolved problems in crystallography in the 19th Century. The most common anomaly is a discrepancy between a crystal’s symmetry as determined by its shape or by X-ray analysis, and that determined by monitoring the polarization state of traversing light. These discrepancies were perceived as a great impediment to the development of the sciences of crystals on the basis of Curie’s Symmetry Principle, the grand organizing idea in the physical sciences to emerge in the latter half of the 19th Century. Optically Anomalous Crystals begins with an historical introduction covering the contributions of Brewster, Biot, Mallard, Brauns, Tamman, and many other distinguished crystallographers. From this follows a tutorial in crystal optics. Further chapters discuss the two main mechanisms of optical dissymmetry: 1. the piezo-optic effect, and 2. the kinetic ordering of atoms. The text then tackles complex, inhomogeneous crystals, and...

  12. Modeling the amorphous structure of mechanically alloyed Ti{sub 50}Ni{sub 25}Cu{sub 25} using anomalous wide-angle x-ray scattering and reverse Monte Carlo simulation

    Energy Technology Data Exchange (ETDEWEB)

    Lima, J.C. de, E-mail: fsc1jcd@fisica.ufsc.br [Departamento de Física, Universidade Federal de Santa Catarina, Campus Universitário Trindade, S/N, C.P. 476, 88040-900 Florianópolis, Santa Catarina (Brazil); Poffo, C.M. [Departamento de Engenharia Mecânica, Universidade Federal de Santa Catarina, Campus Universitário Trindade, S/N, C.P. 476, 88040-900 Florianópolis, Santa Catarina (Brazil); Departamento de Física, Universidade Federal do Amazonas, 3000 Japiim, 69077-000 Manaus, Amazonas (Brazil); Souza, S.M. [Departamento de Física, Universidade Federal do Amazonas, 3000 Japiim, 69077-000 Manaus, Amazonas (Brazil); Machado, K.D. [Departamento de Física, Centro Politécnico, Universidade Federal do Paraná, 81531-990 Curitiba, Paraná (Brazil); Trichês, D.M. [Departamento de Física, Universidade Federal do Amazonas, 3000 Japiim, 69077-000 Manaus, Amazonas (Brazil); Grandi, T.A. [Departamento de Física, Universidade Federal de Santa Catarina, Campus Universitário Trindade, S/N, C.P. 476, 88040-900 Florianópolis, Santa Catarina (Brazil); Biasi, R.S. de [Seção de Engenharia Mecânica e de Materiais, Instituto Militar de Engenharia, 22290-270 Rio de Janeiro, RJ (Brazil)

    2013-09-01

    An amorphous Ti{sub 50}Ni{sub 25}Cu{sub 25} alloy was produced by 19 h of mechanical alloying. Anomalous wide angle x-ray scattering data were collected at six energies and six total scattering factors were obtained. By considering the data collected at two energies close to the Ni and Cu K edges, two differential anomalous scattering factors about the Ni and Cu atoms were obtained, showing that the chemical environments around these atoms are different. Eight factors were used as input data to the reverse Monte Carlo method used to compute the partial structure factors S{sub Ti3Ti}(K), S{sub Ti–Cu}(K), S{sub Ti–Ni}(K), S{sub Cu3Cu}(K), S{sub Cu–Ni}(K) and S{sub Ni–Ni}(K) and the partial pair distribution functions G{sub Ti3Ti}(r), G{sub Ti–Cu}(r), G{sub Ti–Ni}(r), G{sub Cu3Cu}(r), G{sub Cu–Ni}(r) and G{sub Ni–Ni}(r). From the RMC final atomic configuration and G{sub ij}(r) functions, the coordination numbers and interatomic atomic distances for the first neighbors were determined.

  13. Dietary iron-loaded rat liver haemosiderin and ferritin: in situ measurement of iron core nanoparticle size and cluster structure using anomalous small-angle x-ray scattering

    Energy Technology Data Exchange (ETDEWEB)

    Bovell, Eliza; Buckley, Craig E.; Chua-anusorn, Wanida; Cookson, David; Kirby, Nigel; Saunders, Martin; St. Pierre, Timothy G. ((UWA)); ((Curtin U.)); ((ASRP))

    2009-03-16

    The morphology, particle size distribution and cluster structure of the hydrated iron(III) oxyhydroxide particles associated with haemosiderin and ferritin in dietary iron-loaded rat liver tissue have been investigated using transmission electron microscopy (TEM) and anomalous small-angle x-ray scattering (ASAXS). Rat liver tissue was removed from a series of female Porton rats which had been fed an iron-rich diet until sacrifice at various ages from 2-24 months. Hepatic iron concentrations ranged from 1 to 65 mg Fe g{sup -1} dry tissue. TEM studies showed both dispersed and clustered iron-containing nanoparticles. The dispersed particles were found to have mean sizes ({+-}standard deviation) of 54 {+-} 8 {angstrom} for the iron-loaded animals and 55 {+-} 7 {angstrom} for the controls. Superposition of particles in TEM images prevented direct measurement of nanoparticulate size in the clusters. The ASAXS data were modelled to provide a quantitative estimate of both the size and spacing of iron oxyhydroxide particles in the bulk samples. The modelling yielded close-packed particles with sizes of 60 to 78 {angstrom} which when corrected for anomalous scattering suggests sizes from 54 to 70 {angstrom}. Particle size distributions are of particular importance since they determine the surface iron to core iron ratios, which in turn are expected to be related to the molar toxicity of iron deposits in cells.

  14. Extra-zonal beech forests in Tuscany: structure, diversity and synecologic features

    Directory of Open Access Journals (Sweden)

    Viciani D

    2011-07-01

    Full Text Available The present paper focuses on the structural, synecological and floristic diversity features of beech-dominated forest communities in four major areas of the Antiapenninic Tyrrhenian system in Tuscany: Metalliferous hills, mountains to the south of Mt. Amiata, volcanic area of the upper Lente valley and Mt. Cetona. These are relict woodlands of Holo-Pleistocene origin with a special ecological and conservation value due to their extrazonal location in lowland submediterranean areas. Results show substantial among-area differences in structure, synecology and plant species composition, but in general a potential for coppices to reach the tall forest stage, as demonstrated by the old-growth stands of Pietraporciana and Sassoforte. Compared with montane Apenninic beechwoods, the relatively rich flora of the studied communities include thermophilous species with a southern Apennine-Balkan distribution, making their syntaxonomical position unclear. Closer affinities are found with the calcicolous Beech Forests of the association and with the silicicolous ones of the . Based on the Natura 2000 system, all the examined communities belong to the priority Habitat “Apennine beech forests with and ” (code: 9210*. Due their relict nature, these biotopes appear vulnerable to climate changes and to a production-oriented forest management. Criteria of naturalistic silviculture should instead promote the dynamic development of these communities towards tall forests and their natural regeneration.

  15. Trends in anomalous small-angle X-ray scattering in grazing incidence for supported nano-alloyed and core-shell metallic nano-particles

    International Nuclear Information System (INIS)

    As atomic structure and morphology of particles are directly correlated to their functional properties, experimental methods probing local and average features of particles at the nano-scale elicit a growing interest. Anomalous small-angle X-ray scattering (ASAXS) is a very attractive technique to investigate the size, shape and spatial distribution of nano-objects embedded in a homogeneous matrix or in porous media. The anomalous variation of the scattering factor close to an absorption edge enables element specific investigations. In the case of supported nano-objects, the use of grazing incidence is necessary to limit the probed depth. The combination of grazing incidence with the anomalous technique provides a powerful new method, anomalous grazing incidence small-angle X-ray scattering (AGISAXS), to disentangle complex chemical patterns in supported multi-component nano-structures. Nevertheless, a proper data analysis requires accurate quantitative measurements associated to an adapted theoretical framework. This paper presents anomalous methods applied to nano-alloys phase separation in the 1-10 nm size range, and focuses on the application of AGISAXS in bimetallic systems: nano-composite films and core-shell supported nano-particles

  16. Large anomalous Nernst effect in a skyrmion crystal

    Science.gov (United States)

    Mizuta, Yo Pierre; Ishii, Fumiyuki

    2016-06-01

    Thermoelectric properties of a model skyrmion crystal were theoretically investigated, and it was found that its large anomalous Hall conductivity, corresponding to large Chern numbers induced by its peculiar spin structure leads to a large transverse thermoelectric voltage through the anomalous Nernst effect. This implies the possibility of finding good thermoelectric materials among skyrmion systems, and thus motivates our quests for them by means of the first-principles calculations as were employed in this study.

  17. Analysis on Features of Agricultural Structure Change and Agricultural Competitiveness in Hubei Province

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The output data of crop farming,forestry,animal husbandry and fishery in the Hubei Statistical Yearbook-2009 is used to analyze the features of agricultural structure change in Hubei Province since 1983;according to the relevant data in Hubei Statistical Yearbook and China Statistical Yearbook in 2005 and 2009,and adopting the shift-share analysis model,the difference in agricultural economic growth between Hubei and other provinces in Central China as well as the difference among the 17 regions of Hubei Province during 2004-2008 are analyzed.Results show that,the agriculture in Hubei Province shows significant overall advantages in central China and has stronger competitiveness,but its crop farming and fishery structure are not quite reasonable,and the competitive advantages of its fishery and agricultural services still need to be strengthened;the agricultural structure within Hubei Province sees an obvious regional differences,viewed from the total deviation,Huanggang,Jingmen and Yichang enjoy competitive edge in the whole province,from the viewpoint of industrial sectors,Huanggang is the most competitive in its planting,forestry and animal husbandry,while Jingmen is the strongest in fishery and Xiangfan has a competitive edge over others in its agricultural services.Based on those results above,it is proposed that Hubei Province should fully recognize its natural conditions,resources endowment and current differences in the economic status of each places,work out measures to suit local conditions,take full use of its advantages,extend its production chain and go on the development road with regional characteristics.

  18. The Cenozoic volcanic province of Tibesti (Sahara of Chad): major units, chronology, and structural features

    Science.gov (United States)

    Deniel, C.; Vincent, P. M.; Beauvilain, A.; Gourgaud, A.

    2015-09-01

    Using both field relationships and some absolute ages, the sequence of volcanic units in the Cenozoic Tibesti Volcanic Province (TVP) (Chad) is established as follows: (1) plateau volcanism, between at least 17 and 8 Ma, consisting of flood basalts and silicic lava plugs, with intercalated ignimbritic sheets in the upper basalt succession increasing in amount upwards. Ages decrease from NE to SW, following the migration of the small NW-SE flexures concentrating the feeding dike swarms; (2) Late Miocene large central composite volcanoes exhibiting diverse and original structures. Some of them (Tarso Toon, Ehi Oyé, and Tarso Yéga) are located along a major NNE fault, representing the main tectonic direction in Tibesti since Precambrian times; (3) construction of three large ignimbritic volcanoes, associated with significant updoming of the basement, ending with the collapse of large calderas: Voon (about 5-7 Ma), Emi Koussi (2.4-1.33 Ma), and Yirrigué (0.43 Ma); (4) basaltic activity, starting at about 5-7 Ma, and essentially consisting of cinder cones and associated lava flows (Tarso Tôh, Tarso Ahon, and Tarso Emi Chi); and (5) final volcanic activity represented by post-Yirrigué caldera activity in the Tarso Toussidé Volcanic Complex, and especially Ehi Toussidé (the only active volcano in Tibesti), plus Ehi Timi and Ehi Mousgou volcanoes, similar to Ehi Toussidé. The two tectonic directions controlling some volcanic features of the province correspond to the major old lithospheric structures delimiting the volcanic province, namely, the great NW-SE Tassilian flexure to the SW and a major NE-NNE fault zone to the E. Unusual conditions of uplift and erosion in the TVP enable exceptional exposure of the internal structure of its volcanoes.

  19. Application of feature method to the modelling of composite structural elements

    Directory of Open Access Journals (Sweden)

    A. Baier

    2011-03-01

    Full Text Available Purpose: The paper describes the use of object-oriented methods in modelling and analysis of components made of fibre-based composites. Defined and specified the method for creating fibre primitives. An algorithm for the design of composite structures using object-oriented methods.Design/methodology/approach: The basic tool is an algorithm to build fibre facilities. Material properties can be found in the previously created databases of material objects. The whole is linked to the relevant formulas and diagrams.Findings: The basis for the introduction of object-oriented method was to systematize the processes of modelling and analysis of composite materials. Application issue features possible to determine the final form of composite structure.Research limitations/implications: Research direction is to create tools to support the work of the constructor during the construction of composite components. Material created a database of individual components of laminates, allows to build optimal in terms of established criteria of composite elements.Practical implications: The practical aspect of using object-oriented method is to use it to define the structure of the laminates. At the modelling stage it is possible to perform the parameterization formula of each phase of the composite. This recipe is especially important during the manufacture of composites.Originality/value: The paper presents a new approach to modelling of composites by defining a new elementary objects forming the basis for during the composite design process. Algorithms used in the work are particularly important for designers of new technical components made on the basis of fibre composites.

  20. Characterizing structural features of cuticle-degrading proteases from fungi by molecular modeling

    Directory of Open Access Journals (Sweden)

    Fu Yun-Xin

    2007-05-01

    Full Text Available Abstract Background Serine proteases secreted by nematode and insect pathogenic fungi are bio-control agents which have commercial potential for developing into effective bio-pesticides. A thorough understanding of the structural and functional features of these proteases would significantly assist with targeting the design of efficient bio-control agents. Results Structural models of serine proteases PR1 from entomophagous fungus, Ver112 and VCP1 from nematophagous fungi, have been modeled using the homology modeling technique based on the crystal coordinate of the proteinase K. In combination with multiple sequence alignment, these models suggest one similar calcium-binding site and two common disulfide bridges in the three cuticle-degrading enzymes. In addition, the predicted models of the three cuticle-degrading enzymes present an essentially identical backbone topology and similar geometric properties with the exception of a limited number of sites exhibiting relatively large local conformational differences only in some surface loops and the N-, C termini. However, they differ from each other in the electrostatic surface potential, in hydrophobicity and size of the S4 substrate-binding pocket, and in the number and distribution of hydrogen bonds and salt bridges within regions that are part of or in close proximity to the S2-loop. Conclusion These differences likely lead to variations in substrate specificity and catalytic efficiency among the three enzymes. Amino acid polymorphisms in cuticle-degrading enzymes were discussed with respect to functional effects and host preference. It is hoped that these structural models would provide a further basis for exploitation of these serine proteases from pathogenic fungi as effective bio-control agents.

  1. 3d Transition Metal Adsorption Induced the valley-polarized Anomalous Hall Effect in Germanene

    Science.gov (United States)

    Zhou, P.; Sun, L. Z.

    2016-06-01

    Based on DFT + U and Berry curvature calculations, we study the electronic structures and topological properties of 3d transition metal (TM) atom (from Ti to Co) adsorbed germanene (TM-germanene). We find that valley-polarized anomalous Hall effect (VAHE) can be realized in germanene by adsorbing Cr, Mn, or Co atoms on its surface. A finite valley Hall voltage can be easily detected in their nanoribbon, which is important for valleytronics devices. Moreover, different valley-polarized current and even reversible valley Hall voltage can be archived by shifting the Fermi energy of the systems. Such versatile features of the systems show potential in next generation electronics devices.

  2. Features of the structure Quaternary sediments in typical sections of Middle Dnieper.

    Directory of Open Access Journals (Sweden)

    Manyuk V.

    2013-09-01

    Full Text Available Considered the most important features of the geological feature of the Quaternary deposits, especially in their most typical sections. First we present new evidence about change margin distribution limnoglacial and fluvioglacial deposits.

  3. Jackpot Structural Features: Rollover Effect and Goal-Gradient Effect in EGM Gambling.

    Science.gov (United States)

    Li, En; Rockloff, Matthew J; Browne, Matthew; Donaldson, Phillip

    2016-06-01

    Relatively little research has been undertaken on the influence of jackpot structural features on electronic gaming machine (EGM) gambling behavior. This study considered two common features of EGM jackpots: progressive (i.e., the jackpot incrementally growing in value as players make additional bets), and deterministic (i.e., a guaranteed jackpot after a fixed number of bets, which is determined in advance and at random). Their joint influences on player betting behavior and the moderating role of jackpot size were investigated in a crossed-design experiment. Using real money, players gambled on a computer simulated EGM with real jackpot prizes of either $500 (i.e., small jackpot) or $25,000 (i.e., large jackpot). The results revealed three important findings. Firstly, players placed the largest bets (20.3 % higher than the average) on large jackpot EGMs that were represented to be deterministic and non-progressive. This finding was supportive of a hypothesized 'goal-gradient effect', whereby players might have felt subjectively close to an inevitable payoff for a high-value prize. Secondly, large jackpots that were non-deterministic and progressive also promoted high bet sizes (17.8 % higher than the average), resembling the 'rollover effect' demonstrated in lottery betting, whereby players might imagine that their large bets could be later recouped through a big win. Lastly, neither the hypothesized goal-gradient effect nor the rollover effect was evident among players betting on small jackpot machines. These findings suggest that certain high-value jackpot configurations may have intensifying effects on player behavior. PMID:26063627

  4. Structural Features of Ion Transport and Allosteric Regulation in Sodium-Calcium Exchanger (NCX) Proteins.

    Science.gov (United States)

    Giladi, Moshe; Tal, Inbal; Khananshvili, Daniel

    2016-01-01

    Na(+)/Ca(2+) exchanger (NCX) proteins extrude Ca(2+) from the cell to maintain cellular homeostasis. Since NCX proteins contribute to numerous physiological and pathophysiological events, their pharmacological targeting has been desired for a long time. This intervention remains challenging owing to our poor understanding of the underlying structure-dynamic mechanisms. Recent structural studies have shed light on the structure-function relationships underlying the ion-transport and allosteric regulation of NCX. The crystal structure of an archaeal NCX (NCX_Mj) along with molecular dynamics simulations and ion flux analyses, have assigned the ion binding sites for 3Na(+) and 1Ca(2+), which are being transported in separate steps. In contrast with NCX_Mj, eukaryotic NCXs contain the regulatory Ca(2+)-binding domains, CBD1 and CBD2, which affect the membrane embedded ion-transport domains over a distance of ~80 Å. The Ca(2+)-dependent regulation is ortholog, isoform, and splice-variant dependent to meet physiological requirements, exhibiting either a positive, negative, or no response to regulatory Ca(2+). The crystal structures of the two-domain (CBD12) tandem have revealed a common mechanism involving a Ca(2+)-driven tethering of CBDs in diverse NCX variants. However, dissociation kinetics of occluded Ca(2+) (entrapped at the two-domain interface) depends on the alternative-splicing segment (at CBD2), thereby representing splicing-dependent dynamic coupling of CBDs. The HDX-MS, SAXS, NMR, FRET, equilibrium (45)Ca(2+) binding and stopped-flow techniques provided insights into the dynamic mechanisms of CBDs. Ca(2+) binding to CBD1 results in a population shift, where more constraint conformational states become highly populated without global conformational changes in the alignment of CBDs. This mechanism is common among NCXs. Recent HDX-MS studies have demonstrated that the apo CBD1 and CBD2 are stabilized by interacting with each other, while Ca(2+) binding to CBD1

  5. Contrasted structuring effects of mesoscale features on the seabird community in the Mozambique Channel

    Science.gov (United States)

    Jaquemet, S.; Ternon, J. F.; Kaehler, S.; Thiebot, J. B.; Dyer, B.; Bemanaja, E.; Marteau, C.; Le Corre, M.

    2014-02-01

    of mescoscale features in structuring the tropical seabird community in the Mozambique Channel, in addition to segregating tropical and non-tropical species. The mechanisms underlying the segregation of tropical seabirds seem to partially differ from that of other tropical regions, and this may be a consequence of the strong local mesoscale activity, affecting prey size and availability schemes. Beyond characterising the foraging habitats of the seabird community of the Mozambique Channel, this study highlights the importance of this region as a hot spot for seabirds; especially the southern part, where several endangered sub-Antarctic species over-winter.

  6. Molecular structural visualization and micro-structural features of 4,6-dimethyl-3-cyanopyridine-(2H)-selenone

    International Nuclear Information System (INIS)

    Graphical abstract: Packing and spacefill unit cells of 4,6-dimethyl-3-cyanopyridine-(2H)-selenone with different plans of symmetry showing selenium-ion as nucleation center. Highlights: ► Compound(I) 4,6-dimethyl-3-cyanopyridine-(2H)-selenone is mainly belongs to monoclinic crystal structure with P21/n space group as confirmed in crystallographic data. ► XRD-powder diffraction could used as quantitative tool for estimating different phases for small nucleus of organic compounds. ► There are four types of H-bonding two are intra-H-bond in the same molecule of 4,6-dimethyl-3-cyanopyridine-(2H)-selenone which are Se⋯H⋯CN and Se⋯H⋯N while the others two inter-H-bond are Se⋯H⋯N and Se⋯H⋯Se, these four types of hydrogen bonding are responsible for forming 3D-framnet of 4,6-dimethyl-3-cyanopyridine-(2H)-selenone as solid array material. ► The visualized investigations exhibited good fitting with experimental data. ► The average grain size was calculated and found in between 1.13 μm and 2.91 μm which is relatively high in contrast with that calculated throughly applying Scherrer's formula for pure 4,6-dimethyl-3-cyanopyridine-(2H)-selenone monoclinic-phase (D ∼ 0.89 μm). - Abstract: The compound of selenium containing heterocycles namely (I) 4,6-dimethyl-3-cyanopyridine-(2H)-selenone (C8H8N2Se) was used as model to investigate the structural and micro-structural features of some selected selenones. Visualization of molecular structure of selenium containing moiety was accurately investigated to clarify role of selenium ion in nucleation process of forming 3D-framenet of H-bonded of substituted selenones. Bond distances, torsions on angles of investigated compound were compared with others crystal data to confirm crystal structures of substituted selenones which is monoclinic crystal form with P21/n space group.

  7. Some volcanic and structural features of Mare Serenitatis. [as determined by low angle lighting in Apollo 17 photography

    Science.gov (United States)

    Bryan, W. B.; Adams, M.

    1973-01-01

    Relationships between volcanic and structural features along the southern edge of Mare Serenitatis as determined from low angle lighting in Apollo 17 photographs are discussed. Observational summaries are given of: (1) contact relations between the dark border material and the central mare fill, (2) a late stage lava flow with associated cinder cones, and (3) certain structural features related to the development of the mare basin and its associated volcanic landforms. A chronologic summary is given of volcanic and structural events believed to be critical to understanding the development of Mare Serenitatis.

  8. Effects of spatial and feature attention on disparity-rendered structure-from-motion stimuli in the human visual cortex.

    Directory of Open Access Journals (Sweden)

    Ifan Betina Ip

    Full Text Available An important advance in the study of visual attention has been the identification of a non-spatial component of attention that enhances the response to similar features or objects across the visual field. Here we test whether this non-spatial component can co-select individual features that are perceptually bound into a coherent object. We combined human psychophysics and functional magnetic resonance imaging (fMRI to demonstrate the ability to co-select individual features from perceptually coherent objects. Our study used binocular disparity and visual motion to define disparity structure-from-motion (dSFM stimuli. Although the spatial attention system induced strong modulations of the fMRI response in visual regions, the non-spatial system's ability to co-select features of the dSFM stimulus was less pronounced and variable across subjects. Our results demonstrate that feature and global feature attention effects are variable across participants, suggesting that the feature attention system may be limited in its ability to automatically select features within the attended object. Careful comparison of the task design suggests that even minor differences in the perceptual task may be critical in revealing the presence of global feature attention.

  9. A partial structure factor investigation of the bulk metallic glass Zr63Ni25Al12 as studied by using a combination of anomalous X-ray scattering and reverse Monte Carlo modeling

    International Nuclear Information System (INIS)

    Anomalous X-ray scattering experiments were performed on Zr63Ni25Al12 bulk metallic glass. The results were analyzed using reverse Monte Carlo modeling to obtain local- and intermediate-range atomic configurations of this good metallic glass former. Although the Al-related partial information is not reliable due to the small values of their weighting factors in X-ray scattering, good partial information could be obtained from a reverse Monte Carlo analysis. The obtained structural information is given by parameters such as bond angle distributions, bond orientation order parameters, the Warren-Cowley order parameters, and Voronoi polyhedra. Results are compared to the previous results from Fukunaga et al. using X-ray and neutron total scattering. (orig.)

  10. Structural and Functional Features of a Developmentally Regulated Lipopolysaccharide-Binding Protein

    Science.gov (United States)

    Krasity, Benjamin C.; Troll, Joshua V.; Lehnert, Erik M.; Hackett, Kathleen T.; Dillard, Joseph P.; Apicella, Michael A.; Goldman, William E.

    2015-01-01

    ABSTRACT Mammalian lipopolysaccharide (LPS) binding proteins (LBPs) occur mainly in extracellular fluids and promote LPS delivery to specific host cell receptors. The function of LBPs has been studied principally in the context of host defense; the possible role of LBPs in nonpathogenic host-microbe interactions has not been well characterized. Using the Euprymna scolopes-Vibrio fischeri model, we analyzed the structure and function of an LBP family protein, E. scolopes LBP1 (EsLBP1), and provide evidence for its role in triggering a symbiont-induced host developmental program. Previous studies showed that, during initial host colonization, the LPS of V. fischeri synergizes with peptidoglycan (PGN) monomer to induce morphogenesis of epithelial tissues of the host animal. Computationally modeled EsLBP1 shares some but not all structural features of mammalian LBPs that are thought important for LPS binding. Similar to human LBP, recombinant EsLBP1 expressed in insect cells bound V. fischeri LPS and Neisseria meningitidis lipooligosaccharide (LOS) with nanomolar or greater affinity but bound Francisella tularensis LPS only weakly and did not bind PGN monomer. Unlike human LBP, EsLBP1 did not bind N. meningitidis LOS:CD14 complexes. The eslbp1 transcript was upregulated ~22-fold by V. fischeri at 24 h postinoculation. Surprisingly, this upregulation was not induced by exposure to LPS but, rather, to the PGN monomer alone. Hybridization chain reaction-fluorescent in situ hybridization (HCR-FISH) and immunocytochemistry (ICC) localized eslbp1 transcript and protein in crypt epithelia, where V. fischeri induces morphogenesis. The data presented here provide a window into the evolution of LBPs and the scope of their roles in animal symbioses. PMID:26463160

  11. PEG-induced osmotic stress in Mentha x piperita L.: Structural features and metabolic responses.

    Science.gov (United States)

    Búfalo, Jennifer; Rodrigues, Tatiane Maria; de Almeida, Luiz Fernando Rolim; Tozin, Luiz Ricardo Dos Santos; Marques, Marcia Ortiz Mayo; Boaro, Carmen Silvia Fernandes

    2016-08-01

    The present study investigated whether osmotic stress induced by the exposure of peppermint (Mentha x piperita L.) to moderate and severe stress for short periods of time changes the plant's physiological parameters, leaf anatomy and ultrastructure and essential oil. Plants were exposed to two levels of polyethyleneglycol (50 g L(-1) and 100 g L(-1) of PEG) in a hydroponic experiment. The plants exposed to 50 g L(-1) maintained metabolic functions similar to those of the control group (0 g L(-1)) without changes in gas exchange or structural characteristics. The increase in antioxidant enzyme activity reduced the presence of free radicals and protected membranes, including chloroplasts and mitochondria. In contrast, the osmotic stress caused by 100 g L(-1) of PEG inhibited leaf gas exchange, reduced the essential oil content and changed the oil composition, including a decrease in menthone and an increase in menthofuran. These plants also showed an increase in peroxidase activity, but this increase was not sufficient to decrease the lipid peroxidation level responsible for damaging the membranes of organelles. Morphological changes were correlated with the evaluated physiological features: plants exposed to 100 g L(-1) of PEG showed areas with collapsed cells, increases in mesophyll thickness and the area of the intercellular space, cuticle shrinkage, morphological changes in plastids, and lysis of mitochondria. In summary, our results revealed that PEG-induced osmotic stress in M. x piperita depends on the intensity level of the osmotic stress applied; severe osmotic stress changed the structural characteristics, caused damage at the cellular level, and reduced the essential oil content and quality. PMID:27107175

  12. Structural and immunological feature of rhamnogalacturonan I-rich polysaccharide from Korean persimmon vinegar.

    Science.gov (United States)

    Kim, Hoon; Hong, Hee-Do; Suh, Hyung-Joo; Shin, Kwang-Soon

    2016-08-01

    The crude polysaccharide (KPV-0) isolated from Korean persimmon vinegar was fractionated using gel filtration chromatography to enhance the immunostimulatory activity and to identify the structural features of active fraction. Among three fractions, KPV-I obtained in a void volume, demonstrated the potent production of macrophage-stimulating mediators, including tumor necrosis factor-α, interleukin (IL)-6, IL-12, and nitric oxide. KPV-I showed a combined single peak with high molecular weight of 55,000Da by high performance size exclusion chromatography. Component sugar analysis revealed that KPV-I contained mainly of arabinose, mannose, galactose, rhamnose and galacturonic acid. Single radial gel diffusion assay using β-glucosyl Yariv reagent showed that KPV-I contained arabinogalactan protein with 13.7%. Methylation analysis indicated that KPV-I contained 21 kinds of neutral glycosidic linkages, which seemed to be composed three kinds of polysaccharide; that is a rhamnogalacturonan-I (65-70%) derived from persimmon as a raw material, a mannan (20-25%) derived from fermentation-associated microorganisms, and a linear glucans (less than 10%). In conclusion, polysaccharide isolated from persimmon vinegar could augment the macrophage stimulation, and a large amounts of RG-I polysaccharide derived from persimmon is likely a crucial role in expression of the activity in persimmon vinegar. PMID:27131731

  13. Mental Imagery Scale: a new measurement tool to assess structural features of mental representations

    Science.gov (United States)

    D'Ercole, Martina; Castelli, Paolo; Giannini, Anna Maria; Sbrilli, Antonella

    2010-05-01

    Mental imagery is a quasi-perceptual experience which resembles perceptual experience, but occurring without (appropriate) external stimuli. It is a form of mental representation and is often considered centrally involved in visuo-spatial reasoning and inventive and creative thought. Although imagery ability is assumed to be functionally independent of verbal systems, it is still considered to interact with verbal representations, enabling objects to be named and names to evoke images. In literature, most measurement tools for evaluating imagery capacity are self-report instruments focusing on differences in individuals. In the present work, we applied a Mental Imagery Scale (MIS) to mental images derived from verbal descriptions in order to assess the structural features of such mental representations. This is a key theme for those disciplines which need to turn objects and representations into words and vice versa, such as art or architectural didactics. To this aim, an MIS questionnaire was administered to 262 participants. The questionnaire, originally consisting of a 33-item 5-step Likert scale, was reduced to 28 items covering six areas: (1) Image Formation Speed, (2) Permanence/Stability, (3) Dimensions, (4) Level of Detail/Grain, (5) Distance and (6) Depth of Field or Perspective. Factor analysis confirmed our six-factor hypothesis underlying the 28 items.

  14. Mental Imagery Scale: a new measurement tool to assess structural features of mental representations

    International Nuclear Information System (INIS)

    Mental imagery is a quasi-perceptual experience which resembles perceptual experience, but occurring without (appropriate) external stimuli. It is a form of mental representation and is often considered centrally involved in visuo-spatial reasoning and inventive and creative thought. Although imagery ability is assumed to be functionally independent of verbal systems, it is still considered to interact with verbal representations, enabling objects to be named and names to evoke images. In literature, most measurement tools for evaluating imagery capacity are self-report instruments focusing on differences in individuals. In the present work, we applied a Mental Imagery Scale (MIS) to mental images derived from verbal descriptions in order to assess the structural features of such mental representations. This is a key theme for those disciplines which need to turn objects and representations into words and vice versa, such as art or architectural didactics. To this aim, an MIS questionnaire was administered to 262 participants. The questionnaire, originally consisting of a 33-item 5-step Likert scale, was reduced to 28 items covering six areas: (1) Image Formation Speed, (2) Permanence/Stability, (3) Dimensions, (4) Level of Detail/Grain, (5) Distance and (6) Depth of Field or Perspective. Factor analysis confirmed our six-factor hypothesis underlying the 28 items

  15. Concept design and safety features of nuclear power plants mounted on gravity based structures

    International Nuclear Information System (INIS)

    Here, we summarize our recent study on the development of a new concept of an offshore nuclear power plant (ONPP) which uses a system-integrated modular advanced reactor (SMART) and the Advanced Power Reactor 1400 (APR1400), which were recently developed by the Republic of Korea. The proposed concept has enhanced safety features against earthquakes and tsunamis. The key idea is to mount NPPs on gravity based structures (GBSs), which have been widely used for offshore plants. They are typically made from steel-reinforced concrete in dry docks and are tugged to the destination site after being floated, meaning that the GBSs are transportable. Then, they sit on the seabed and bear the entire external load with their own weight during operation. This concept can be applied to a large-scale NPP and to SMR. We introduce the new concept, including the design parameters, design requirements, and the new total general arrangement. The inherent safety characteristics of GBS-type ONPPs against earthquakes and tsunamis are also briefly discussed. In addition, new passive cooling systems were devised and developed to enhance the inherent safety of the passive cooling systems of GBS-type ONPPs. (author)

  16. Segmentation of anatomical branching structures based on texture features and conditional random field

    Science.gov (United States)

    Nuzhnaya, Tatyana; Bakic, Predrag; Kontos, Despina; Megalooikonomou, Vasileios; Ling, Haibin

    2012-02-01

    This work is a part of our ongoing study aimed at understanding a relation between the topology of anatomical branching structures with the underlying image texture. Morphological variability of the breast ductal network is associated with subsequent development of abnormalities in patients with nipple discharge such as papilloma, breast cancer and atypia. In this work, we investigate complex dependence among ductal components to perform segmentation, the first step for analyzing topology of ductal lobes. Our automated framework is based on incorporating a conditional random field with texture descriptors of skewness, coarseness, contrast, energy and fractal dimension. These features are selected to capture the architectural variability of the enhanced ducts by encoding spatial variations between pixel patches in galactographic image. The segmentation algorithm was applied to a dataset of 20 x-ray galactograms obtained at the Hospital of the University of Pennsylvania. We compared the performance of the proposed approach with fully and semi automated segmentation algorithms based on neural network classification, fuzzy-connectedness, vesselness filter and graph cuts. Global consistency error and confusion matrix analysis were used as accuracy measurements. For the proposed approach, the true positive rate was higher and the false negative rate was significantly lower compared to other fully automated methods. This indicates that segmentation based on CRF incorporated with texture descriptors has potential to efficiently support the analysis of complex topology of the ducts and aid in development of realistic breast anatomy phantoms.

  17. Features of Bayou Choctaw SPR caverns and internal structure of the salt dome.

    Energy Technology Data Exchange (ETDEWEB)

    Munson, Darrell E.

    2007-07-01

    The intent of this study is to examine the internal structure of the Bayou Choctaw salt dome utilizing the information obtained from graphical representations of sonar survey data of the internal cavern surfaces. Many of the Bayou Choctaw caverns have been abandoned. Some existing caverns were purchased by the Strategic Petroleum Reserve (SPR) program and have rather convoluted histories and complex cavern geometries. In fact, these caverns are typically poorly documented and are not particularly constructive to this study. Only two Bayou Choctaw caverns, 101 and 102, which were constructed using well-controlled solutioning methods, are well documented. One of these was constructed by the SPR for their use while the other was constructed and traded for another existing cavern. Consequently, compared to the SPR caverns of the West Hackberry and Big Hill domes, it is more difficult to obtain a general impression of the stratigraphy of the dome. Indeed, caverns of Bayou Choctaw show features significantly different than those encountered in the other two SPR facilities. In the number of abandoned caverns, and some of those existing caverns purchased by the SPR, extremely irregular solutioning has occurred. The two SPR constructed caverns suggest that some sections of the caverns may have undergone very regular solutioning to form uniform cylindrical shapes. Although it is not usually productive to speculate, some suggestions that point to the behavior of the Bayou Choctaw dome are examined. Also the primary differences in the Bayou Choctaw dome and the other SPR domes are noted.

  18. Anomalous radiative transitions

    International Nuclear Information System (INIS)

    Anomalous transitions involving photons derived by many-body interaction of the form ∂μGμ in the standard model are studied for the first time. This does not affect the equation of motion in the bulk, but modifies the wavefunctions, and causes an unusual transition characterized by a time-independent probability. In the transition probability at a time interval T expressed generally in the form P=TΓ0+P(d), now with P(d)≠0. The diffractive term P(d) has its origin in the overlap of waves of the initial and final states, and reveals the characteristics of waves. In particular, the processes of the neutrino–photon interaction ordinarily forbidden by the Landau–Yang theorem (Γ0=0) manifest themselves through the boundary interaction. The new term leads physical processes over a wide energy range to have finite probabilities. New methods of detecting neutrinos using lasers are proposed, based on this diffractive term; these would enhance the detectability of neutrinos by many orders of magnitude

  19. Using Mixture Structures of Neural Networks in Order to Detect Cardiac Arrhythmias Using Fusion of Temporal and Wavelet Features

    Directory of Open Access Journals (Sweden)

    syed mohammd Razavi

    2011-05-01

    Full Text Available In recent years the use of intelligent systems in science and engineering, especially in the diagnosis of disease, is increasingly growing. In this paper a smart way to diagnose heart disease (cardiac arrhythmias is presented. This method is based on a combination of structures using neural networks for classification of normal operation and four abnormal heart functions. In the combination of these structures, some neural networks as a mediator, and some of them have been used as a specialist. In the proposed method firstly for removing noise from ECG signal, preprocessing was performed. The various time features (including fifteen properties and wavelet features (includes fifteen feature are extracted from the noise free signal and given the large number of selected features, principal components analysis is used for feature reduction to eight features. The proposed structures of MLP neural networks and RBF neural networks are appropriately trained for classification of arrhythmias and their performance has been evaluated. The results of the implementation of the proposed method on MIT / BIH database show the better performance in the diagnosis of cardiac arrhythmias compared to previous approaches.

  20. Petrology of Anomalous Eucrites

    Science.gov (United States)

    Mittlefehldt, D. W.; Peng, Z. X.; Ross, D. K.

    2015-01-01

    Most mafic achondrites can be broadly categorized as being "eucritic", that is, they are composed of a ferroan low-Ca clinopyroxene, high-Ca plagioclase and a silica phase. They are petrologically distinct from angritic basalts, which are composed of high-Ca, Al-Ti-rich clinopyroxene, Carich olivine, nearly pure anorthite and kirschsteinite, or from what might be called brachinitic basalts, which are composed of ferroan orthopyroxene and high-Ca clinopyroxene, intermediate-Ca plagioclase and ferroan olivine. Because of their similar mineralogy and composition, eucrite-like mafic achondrites formed on compositionally similar asteroids under similar conditions of temperature, pressure and oxygen fugacity. Some of them have distinctive isotopic compositions and petrologic characteristics that demonstrate formation on asteroids different from the parent of the HED clan (e.g., Ibitira, Northwest Africa (NWA) 011). Others show smaller oxygen isotopic distinctions but are otherwise petrologically and compositionally indistinguishable from basaltic eucrites (e.g., Pasamonte, Pecora Escarpment (PCA) 91007). The degree of uniformity in delta O-17 of eucrites and diogenites is one piece of evidence considered to favor of a magma-ocean scenario for their petrogenesis. Given that the O isotopic differences separating Pasamonte and PCA 91007 from other eucrites are small, and that there is an absence of other distinguishing characteristics, a legitimate question is: Did the HED parent asteroid fail to homogenize via a magma-ocean stage, thus explaining outliers like Pasamonte? We are initiating a program of study of anomalous eucrite-like achondrites as one part of our effort to seek a resolution of this issue. Here we present preliminary petrologic information on Asuka (A-) 881394, Elephant Moraine (EET) 87520 and EET 87542. We will have studied several more by conference time.

  1. Prediction of Conversion from Mild Cognitive Impairment to Alzheimer's Disease Using MRI and Structural Network Features.

    Science.gov (United States)

    Wei, Rizhen; Li, Chuhan; Fogelson, Noa; Li, Ling

    2016-01-01

    Optimized magnetic resonance imaging (MRI) features and abnormalities of brain network architectures may allow earlier detection and accurate prediction of the progression from mild cognitive impairment (MCI) to Alzheimer's disease (AD). In this study, we proposed a classification framework to distinguish MCI converters (MCIc) from MCI non-converters (MCInc) by using a combination of FreeSurfer-derived MRI features and nodal features derived from the thickness network. At the feature selection step, we first employed sparse linear regression with stability selection, for the selection of discriminative features in the iterative combinations of MRI and network measures. Subsequently the top K features of available combinations were selected as optimal features for classification. To obtain unbiased results, support vector machine (SVM) classifiers with nested cross validation were used for classification. The combination of 10 features including those from MRI and network measures attained accuracies of 66.04, 76.39, 74.66, and 73.91% for mixed conversion time, 6, 12, and 18 months before diagnosis of probable AD, respectively. Analysis of the diagnostic power of different time periods before diagnosis of probable AD showed that short-term prediction (6 and 12 months) achieved more stable and higher AUC scores compared with long-term prediction (18 months), with K-values from 1 to 30. The present results suggest that meaningful predictors composed of MRI and network measures may offer the possibility for early detection of progression from MCI to AD. PMID:27148045

  2. Prediction of Conversion from Mild Cognitive Impairment to Alzheimer's Disease Using MRI and Structural Network Features

    Science.gov (United States)

    Wei, Rizhen; Li, Chuhan; Fogelson, Noa; Li, Ling

    2016-01-01

    Optimized magnetic resonance imaging (MRI) features and abnormalities of brain network architectures may allow earlier detection and accurate prediction of the progression from mild cognitive impairment (MCI) to Alzheimer's disease (AD). In this study, we proposed a classification framework to distinguish MCI converters (MCIc) from MCI non-converters (MCInc) by using a combination of FreeSurfer-derived MRI features and nodal features derived from the thickness network. At the feature selection step, we first employed sparse linear regression with stability selection, for the selection of discriminative features in the iterative combinations of MRI and network measures. Subsequently the top K features of available combinations were selected as optimal features for classification. To obtain unbiased results, support vector machine (SVM) classifiers with nested cross validation were used for classification. The combination of 10 features including those from MRI and network measures attained accuracies of 66.04, 76.39, 74.66, and 73.91% for mixed conversion time, 6, 12, and 18 months before diagnosis of probable AD, respectively. Analysis of the diagnostic power of different time periods before diagnosis of probable AD showed that short-term prediction (6 and 12 months) achieved more stable and higher AUC scores compared with long-term prediction (18 months), with K-values from 1 to 30. The present results suggest that meaningful predictors composed of MRI and network measures may offer the possibility for early detection of progression from MCI to AD. PMID:27148045

  3. Structural features of sugars that trigger or support conidial germination in the filamentous fungus Aspergillus niger.

    Science.gov (United States)

    Hayer, Kimran; Stratford, Malcolm; Archer, David B

    2013-11-01

    The asexual spores (conidia) of Aspergillus niger germinate to produce hyphae under appropriate conditions. Germination is initiated by conidial swelling and mobilization of internal carbon and energy stores, followed by polarization and emergence of a hyphal germ tube. The effects of different pyranose sugars, all analogues of d-glucose, on the germination of A. niger conidia were explored, and we define germination as the transition from a dormant conidium into a germling. Within germination, we distinguish two distinct stages, the initial swelling of the conidium and subsequent polarized growth. The stage of conidial swelling requires a germination trigger, which we define as a compound that is sensed by the conidium and which leads to catabolism of d-trehalose and isotropic growth. Sugars that triggered germination and outgrowth included d-glucose, d-mannose, and d-xylose. Sugars that triggered germination but did not support subsequent outgrowth included d-tagatose, d-lyxose, and 2-deoxy-d-glucose. Nontriggering sugars included d-galactose, l-glucose, and d-arabinose. Certain nontriggering sugars, including d-galactose, supported outgrowth if added in the presence of a complementary triggering sugar. This division of functions indicates that sugars are involved in two separate events in germination, triggering and subsequent outgrowth, and the structural features of sugars that support each, both, or none of these events are discussed. We also present data on the uptake of sugars during the germination process and discuss possible mechanisms of triggering in the absence of apparent sugar uptake during the initial swelling of conidia. PMID:23995938

  4. Structural Features and Molecular Evolution of Bowman-Birk Protease Inhibitors and Their Potential Application

    Institute of Scientific and Technical Information of China (English)

    Rui-Feng QI; Zhan-Wu SONG; Cheng-Wu CHI

    2005-01-01

    The Bowman-Birk inhibitors (BBIs) are well-studied serine protease inhibitors that are abundant in dicotyledonous and monocotyledonous plants. BBIs from dicots usually have a molecular weight of 8k and are double-headed with two reactive sites, whereas those from monocots can be divided into two classes, one approximately 8 kDa in size with one reactive site (another reactive site was lost) and the other approximately 16 kDa in size with two reactive sites. The reactive site is located at unique exposed surfaces formed by a disulfide-linked β-sheet loop that is highly conserved, rigid and mostly composed of nine residues. The structural features and molecular evolution of inhibitors are described, focusing on the conserved disulfide bridges. The sunflower trypsin inhibitor-1 (SFTI-1), with 14 amino acid residues, is a recently discovered bicyclic inhibitor, and is the most small and potent naturally occurring Bowman-Birk inhibitor.Recently, BBIs have become a hot topic because of their potential applications. BBIs are now used for defense against pathogens and insects in transgenic plants, which has advantages over using toxic and polluting insecticides. BBIs could also be applied in the prevention of cancer, Dengue fever, and inflammatory and allergic disorders, because of their inhibitory activity with respect to the serine proteases that play a pivotal role in the development and pathogenesis of these diseases. The canonical nine-residue loop of BBIs/STFI-1 provides an ideal template for drug design of specific inhibitors to target their respective proteases.

  5. Visual odometry based on structural matching of local invariant features using stereo camera sensor.

    Science.gov (United States)

    Núñez, Pedro; Vázquez-Martín, Ricardo; Bandera, Antonio

    2011-01-01

    This paper describes a novel sensor system to estimate the motion of a stereo camera. Local invariant image features are matched between pairs of frames and linked into image trajectories at video rate, providing the so-called visual odometry, i.e., motion estimates from visual input alone. Our proposal conducts two matching sessions: the first one between sets of features associated to the images of the stereo pairs and the second one between sets of features associated to consecutive frames. With respect to previously proposed approaches, the main novelty of this proposal is that both matching algorithms are conducted by means of a fast matching algorithm which combines absolute and relative feature constraints. Finding the largest-valued set of mutually consistent matches is equivalent to finding the maximum-weighted clique on a graph. The stereo matching allows to represent the scene view as a graph which emerge from the features of the accepted clique. On the other hand, the frame-to-frame matching defines a graph whose vertices are features in 3D space. The efficiency of the approach is increased by minimizing the geometric and algebraic errors to estimate the final displacement of the stereo camera between consecutive acquired frames. The proposed approach has been tested for mobile robotics navigation purposes in real environments and using different features. Experimental results demonstrate the performance of the proposal, which could be applied in both industrial and service robot fields. PMID:22164016

  6. Visual Odometry Based on Structural Matching of Local Invariant Features Using Stereo Camera Sensor

    Directory of Open Access Journals (Sweden)

    Antonio Bandera

    2011-07-01

    Full Text Available This paper describes a novel sensor system to estimate the motion of a stereo camera. Local invariant image features are matched between pairs of frames and linked into image trajectories at video rate, providing the so-called visual odometry, i.e., motion estimates from visual input alone. Our proposal conducts two matching sessions: the first one between sets of features associated to the images of the stereo pairs and the second one between sets of features associated to consecutive frames. With respect to previously proposed approaches, the main novelty of this proposal is that both matching algorithms are conducted by means of a fast matching algorithm which combines absolute and relative feature constraints. Finding the largest-valued set of mutually consistent matches is equivalent to finding the maximum-weighted clique on a graph. The stereo matching allows to represent the scene view as a graph which emerge from the features of the accepted clique. On the other hand, the frame-to-frame matching defines a graph whose vertices are features in 3D space. The efficiency of the approach is increased by minimizing the geometric and algebraic errors to estimate the final displacement of the stereo camera between consecutive acquired frames. The proposed approach has been tested for mobile robotics navigation purposes in real environments and using different features. Experimental results demonstrate the performance of the proposal, which could be applied in both industrial and service robot fields.

  7. Features of manifestation of the long-range action in As-Ga transistor structures under combined action by different mass ions

    International Nuclear Information System (INIS)

    Anomalous differences in measurements of distribution profiles of charge carriers concentration over the depth of active regions of arsenide-gallium structures after irradiation on the side of substrate by molecular hydrogen and argon ions, separately and in a combined sequence, were detected. The greatest effect of irradiation was observed in the structures with increase content of defects in the buffer layer. The results are explained by restructuring of impurity-defective complexes near interfaces induced by elastic waves appearing due to relaxation of displacement peaks in the area of ion braking

  8. Stable feature selection for clinical prediction: exploiting ICD tree structure using Tree-Lasso.

    Science.gov (United States)

    Kamkar, Iman; Gupta, Sunil Kumar; Phung, Dinh; Venkatesh, Svetha

    2015-02-01

    Modern healthcare is getting reshaped by growing Electronic Medical Records (EMR). Recently, these records have been shown of great value towards building clinical prediction models. In EMR data, patients' diseases and hospital interventions are captured through a set of diagnoses and procedures codes. These codes are usually represented in a tree form (e.g. ICD-10 tree) and the codes within a tree branch may be highly correlated. These codes can be used as features to build a prediction model and an appropriate feature selection can inform a clinician about important risk factors for a disease. Traditional feature selection methods (e.g. Information Gain, T-test, etc.) consider each variable independently and usually end up having a long feature list. Recently, Lasso and related l1-penalty based feature selection methods have become popular due to their joint feature selection property. However, Lasso is known to have problems of selecting one feature of many correlated features randomly. This hinders the clinicians to arrive at a stable feature set, which is crucial for clinical decision making process. In this paper, we solve this problem by using a recently proposed Tree-Lasso model. Since, the stability behavior of Tree-Lasso is not well understood, we study the stability behavior of Tree-Lasso and compare it with other feature selection methods. Using a synthetic and two real-world datasets (Cancer and Acute Myocardial Infarction), we show that Tree-Lasso based feature selection is significantly more stable than Lasso and comparable to other methods e.g. Information Gain, ReliefF and T-test. We further show that, using different types of classifiers such as logistic regression, naive Bayes, support vector machines, decision trees and Random Forest, the classification performance of Tree-Lasso is comparable to Lasso and better than other methods. Our result has implications in identifying stable risk factors for many healthcare problems and therefore can

  9. Contrasted structuring effects of mesoscale features on the seabird community in the Mozambique Channel

    OpenAIRE

    Jaquemet, Sébastien; Ternon, Jean-François; Kaehler, S; Thiebot, J. B.; Dyer, B.; Bemanaja, E.; Marteau, C.; Le Corre, M.

    2014-01-01

    The Mozambique Channel (western Indian Ocean) is a dynamic environment characterised by strong mesoscale features, which influence all biological components of the pelagic ecosystem. We investigated the distribution, abundance and feeding behaviour of seabirds in the Mozambique Channel in relation to physical and biological environmental variables, with a specific interest in mesoscale features. Seabird censuses were conducted in summer and winter during 7 cruises in the southern and northern...

  10. Learner-controlled selection of tasks with different surface and structural features: effects on transfer and efficiency

    NARCIS (Netherlands)

    Corbalan, Gemma; Kester, Liesbeth; Van Merriënboer, Jeroen

    2010-01-01

    Corbalan, G., Kester, L., & Van Merriënboer, J. J. G. (2011). Learner-controlled selection of tasks with different surface and structural features: Effects on transfer and efficiency. Computers in Human Behavior, 27(1), 76-81. doi:10.1016/j.chb.2010.05.026

  11. Linguistic Features and Schematic Textual Structure in Look-Good Advertisements in the Indian Print Media in English

    Science.gov (United States)

    Singh, Sukhdev; Bedi, Navkiran Kaur

    2013-01-01

    Every text has a communicative purpose that it performs by dividing itself into generic stages. These stages are assigned specific goals and have differing linguistic structures. This paper makes an attempt to investigate whether there is a definable co-relation between linguistic features and stages in the genre of look-good advertisements. It…

  12. Does my face FIT?: a face image task reveals structure and distortions of facial feature representation.

    Directory of Open Access Journals (Sweden)

    Christina T Fuentes

    Full Text Available Despite extensive research on face perception, few studies have investigated individuals' knowledge about the physical features of their own face. In this study, 50 participants indicated the location of key features of their own face, relative to an anchor point corresponding to the tip of the nose, and the results were compared to the true location of the same individual's features from a standardised photograph. Horizontal and vertical errors were analysed separately. An overall bias to underestimate vertical distances revealed a distorted face representation, with reduced face height. Factor analyses were used to identify separable subconfigurations of facial features with correlated localisation errors. Independent representations of upper and lower facial features emerged from the data pattern. The major source of variation across individuals was in representation of face shape, with a spectrum from tall/thin to short/wide representation. Visual identification of one's own face is excellent, and facial features are routinely used for establishing personal identity. However, our results show that spatial knowledge of one's own face is remarkably poor, suggesting that face representation may not contribute strongly to self-awareness.

  13. Anomalous position of the gallbladder

    Energy Technology Data Exchange (ETDEWEB)

    Han, Tae II; Lim, Joo Won; Ko, Young Tae; Lee, Dong Ho; Yoon, Yup [Kyung Hee University Hospital, Seoul (Korea, Republic of)

    1994-12-15

    To determine the significance of anomalous position of the gallbladder. Sixteen patients with anomalous position of the gallbladder were evaluated for analysis. The diagnosis was confirmed by ultrasonography(15 patients) and oral cholecystography(1 patient). Among those, six patients underwent CT scan and a patient had 99mTc-DISIDA scan. The images were analysed with respect to the location of the GB and configuration and associated abnormality of the liver and hepatobiliary systems. Medical records of each patient were also reviewed. Among 16 patients having an anomalous position of the gallbladder, nine had retrodisplaced gallbladder, four had left-sided gallbladder, two had supra hepatic gallbladder, and one had floating gallbladder. Except for one patient, fifteen had abnormality in the liver such as focal atrophic or hypoplastic change and liver cirrhosis. Intrahepatic stones were demonstrated in 6 patients. Our results showed that anomalous position of the gallbladder was commonly associated with atrophy or hypoplasia of the liver rather than congenital in origin. The possibility of an anomalous location of gallbladder should be kept in mind when GB is not in its normal location.

  14. Anomalous Weyl superfluid in three-dimensional ultracold fermionic gases

    Science.gov (United States)

    Huang, Beibing

    2016-08-01

    In this paper we use layer construction method to construct an experimentally feasible model to realize one type of anomalous Weyl superfluids (WS) in the context of cold fermionic gases. This exotic phase still characterizes the Weyl points in the bulk but completely different Majorana Fermi arc surface state (MFASS) on the boundaries. In contrast to conventional WS, where MFASS only connects the projection of Weyl points, new MFASS continuously stretches to the border of surface Brillouin zone. We self-consistently determine the phase diagram of model at the mean-field level to claim the achievement of anomalous WS. In addition, inversion symmetry and band inversion in this model are analyzed in detail to provide unique feature of identifying anomalous WS experimentally by momentum-resolved radio-frequency spectroscopy.

  15. Anomalous Hydrodynamics of Two-Dimensional Vortex Fluid

    CERN Document Server

    Wiegmann, Paul

    2013-01-01

    Turbulent flows of incompressible liquid in two dimensions are comprised of dense systems of vortices. Such system of vortices can be treated as a fluid and itself could be described in terms of hydrodynamics. We develop the hydrodynamics of the vortex fluid. This hydrodynamics captures characteristics of fluid flows averaged over fast circulations in the inter-vortex space. The hydrodynamics of the vortex fluid features the anomalous stress absent in Euler's hydrodynamics. The anomalous stress yields a number of interesting effects. Some of them are: a deflection of stream lines, a correction to the Bernoulli law, accumulation of vortices in regions with high curvature in the curved space. The origin of the anomalous stresses is a divergence of inter-vortex interactions at the micro-scale which manifest at the macro-scale. We obtain the hydrodynamics of the vortex fluid from the Kirchhoff equations for dynamics of point-like vortices

  16. Rigorous assessment and integration of the sequence and structure based features to predict hot spots

    Directory of Open Access Journals (Sweden)

    Wang Yong

    2011-07-01

    Full Text Available Abstract Background Systematic mutagenesis studies have shown that only a few interface residues termed hot spots contribute significantly to the binding free energy of protein-protein interactions. Therefore, hot spots prediction becomes increasingly important for well understanding the essence of proteins interactions and helping narrow down the search space for drug design. Currently many computational methods have been developed by proposing different features. However comparative assessment of these features and furthermore effective and accurate methods are still in pressing need. Results In this study, we first comprehensively collect the features to discriminate hot spots and non-hot spots and analyze their distributions. We find that hot spots have lower relASA and larger relative change in ASA, suggesting hot spots tend to be protected from bulk solvent. In addition, hot spots have more contacts including hydrogen bonds, salt bridges, and atomic contacts, which favor complexes formation. Interestingly, we find that conservation score and sequence entropy are not significantly different between hot spots and non-hot spots in Ab+ dataset (all complexes. While in Ab- dataset (antigen-antibody complexes are excluded, there are significant differences in two features between hot pots and non-hot spots. Secondly, we explore the predictive ability for each feature and the combinations of features by support vector machines (SVMs. The results indicate that sequence-based feature outperforms other combinations of features with reasonable accuracy, with a precision of 0.69, a recall of 0.68, an F1 score of 0.68, and an AUC of 0.68 on independent test set. Compared with other machine learning methods and two energy-based approaches, our approach achieves the best performance. Moreover, we demonstrate the applicability of our method to predict hot spots of two protein complexes. Conclusion Experimental results show that support vector machine

  17. New fabrication methodology for fine-feature high-aspect-ratio structures made from high-Z materials

    Science.gov (United States)

    Desai, Upendra D.; Orwig, Larry E.; Clark, David; Appleby, Michael

    1999-08-01

    Radiological imagin relies heavily on collimators to achieve diagnostic x-ray images. These collimating structures are required due to the lack of efficient x-ray reflectors or refractors needed to make lenses or mirrors. In order to achieve higher resolution x-ray images, finer collimator geometries are needed. The two critical parameters that define the fineness of a collimator are the length of the collimator structure and the aperture size. Current collimator fabrication technology provides structures with coarse cell sizes, which require long structural lengths, to achieve image optimization. Finer collimator geometries would help reduce the overall length of collimating structures. Tecomet, of Woburn, MA has developed a new technology to fabricate fine-featured, high aspect ratio structures made from high Z materials. These collimating structures have been made from tungsten with aspect ratios above 50:1 and geometry features less than 20 microns. This technology has enabled advancements in the design of x-ray coded apertures. This has opened the door to new ideas for x-ray imaging. Optimization coders, made from tungsten, can now be designed and fabricated to achieve very high angular resolution. Significant reduction in weight is realized due to the reduction in collimator thickness. The collimators made using these fabrication methods also provide greater long-term structural stability compared to collimators used in diagnostic x-ray imaging using lead.

  18. A spectral-structural bag-of-features scene classifier for very high spatial resolution remote sensing imagery

    Science.gov (United States)

    Zhao, Bei; Zhong, Yanfei; Zhang, Liangpei

    2016-06-01

    Land-use classification of very high spatial resolution remote sensing (VHSR) imagery is one of the most challenging tasks in the field of remote sensing image processing. However, the land-use classification is hard to be addressed by the land-cover classification techniques, due to the complexity of the land-use scenes. Scene classification is considered to be one of the expected ways to address the land-use classification issue. The commonly used scene classification methods of VHSR imagery are all derived from the computer vision community that mainly deal with terrestrial image recognition. Differing from terrestrial images, VHSR images are taken by looking down with airborne and spaceborne sensors, which leads to the distinct light conditions and spatial configuration of land cover in VHSR imagery. Considering the distinct characteristics, two questions should be answered: (1) Which type or combination of information is suitable for the VHSR imagery scene classification? (2) Which scene classification algorithm is best for VHSR imagery? In this paper, an efficient spectral-structural bag-of-features scene classifier (SSBFC) is proposed to combine the spectral and structural information of VHSR imagery. SSBFC utilizes the first- and second-order statistics (the mean and standard deviation values, MeanStd) as the statistical spectral descriptor for the spectral information of the VHSR imagery, and uses dense scale-invariant feature transform (SIFT) as the structural feature descriptor. From the experimental results, the spectral information works better than the structural information, while the combination of the spectral and structural information is better than any single type of information. Taking the characteristic of the spatial configuration into consideration, SSBFC uses the whole image scene as the scope of the pooling operator, instead of the scope generated by a spatial pyramid (SP) commonly used in terrestrial image classification. The experimental

  19. Anomalous spectral laws in differential models of turbulence

    International Nuclear Information System (INIS)

    Differential models for hydrodynamic, passive-scalar and wave turbulence given by nonlinear first- and second-order evolution equations for the energy spectrum in the k-space were analysed. Both types of models predict formation an anomalous transient power-law spectra. The second-order models were analysed in terms of self-similar solutions of the second kind, and a phenomenological formula for the anomalous spectrum exponent was constructed using numerics for a broad range of parameters covering all known physical examples. The first-order models were examined analytically, including finding an analytical prediction for the anomalous exponent of the transient spectrum and description of formation of the Kolmogorov-type spectrum as a reflection wave from the dissipative scale back into the inertial range. The latter behaviour was linked to pre-shock/shock singularities similar to the ones arising in the Burgers equation. Existence of the transient anomalous scaling and the reflection-wave scenario are argued to be a robust feature common to the finite-capacity turbulence systems. The anomalous exponent is independent of the initial conditions but varies for for different models of the same physical system. (paper)

  20. Anomalous spectral laws in differential models of turbulence

    Science.gov (United States)

    Thalabard, Simon; Nazarenko, Sergey; Galtier, Sébastien; Medvedev, Sergey

    2015-07-01

    Differential models for hydrodynamic, passive-scalar and wave turbulence given by nonlinear first- and second-order evolution equations for the energy spectrum in the k-space were analysed. Both types of models predict formation an anomalous transient power-law spectra. The second-order models were analysed in terms of self-similar solutions of the second kind, and a phenomenological formula for the anomalous spectrum exponent was constructed using numerics for a broad range of parameters covering all known physical examples. The first-order models were examined analytically, including finding an analytical prediction for the anomalous exponent of the transient spectrum and description of formation of the Kolmogorov-type spectrum as a reflection wave from the dissipative scale back into the inertial range. The latter behaviour was linked to pre-shock/shock singularities similar to the ones arising in the Burgers equation. Existence of the transient anomalous scaling and the reflection-wave scenario are argued to be a robust feature common to the finite-capacity turbulence systems. The anomalous exponent is independent of the initial conditions but varies for for different models of the same physical system.

  1. SU-E-QI-16: Reproducibility of Computed Tomography Quantitative Structural Features Using the FDA Thoracic Phantom Image Database

    International Nuclear Information System (INIS)

    Purpose: To assess the reproducibility of quantitative structural features using images from the computed tomography thoracic FDA phantom database under different scanning conditions. Methods: Development of quantitative image features to describe lesion shape and size, beyond conventional RECIST measures, is an evolving area of research in need of benchmarking standards. Gavrielides et al. (2010) scanned a FDA-developed thoracic phantom with nodules of various Hounsfield units (HU) values, shapes and sizes close to vascular structures using several scanners and varying scanning conditions/parameters; these images are in the public domain. We tested six structural features, namely, Convexity, Perimeter, Major Axis, Minor Axis, Extent Mean and Eccentricity, to characterize lung nodules. Convexity measures lesion irregularity referenced to a convex surface. Previously, we showed it to have prognostic value in lung adenocarcinoma. The above metrics and RECIST measures were evaluated on three spiculated (8mm/-300HU, 12mm/+30HU and 15mm/+30HU) and two non-spiculated (8mm/+100HU and 10mm/+100HU) nodules (from layout 2) imaged at three different mAs values: 25, 100 and 200 mAs; on a Phillips scanner (16-slice Mx8000-IDT; 3mm slice thickness). The nodules were segmented semi-automatically using a commercial software tool; the same HU range was used for all nodules. Results: Analysis showed convexity having the lowest maximum coefficient of variation (MCV): 1.1% and 0.6% for spiculated and non-spiculated nodules, respectively, much lower compared to RECIST Major and Minor axes whose MCV were 10.1% and 13.4% for spiculated, and 1.9% and 2.3% for non-spiculated nodules, respectively, across the various mAs. MCVs were consistently larger for speculated nodules. In general, the dependence of structural features on mAs (noise) was low. Conclusion: The FDA phantom CT database may be used for benchmarking of structural features for various scanners and scanning conditions; we used

  2. Anomalous Earth flybys of spacecraft

    Science.gov (United States)

    Wilhelm, Klaus; Dwivedi, Bhola N.

    2015-07-01

    A small deviation from the potential is expected for the gravitational interaction of extended bodies. It is explained as a consequence of a recently proposed gravitational impact model (Wilhelm et al. in Astrophys. Space Sci. 343:135-144, 2013) and has been applied to anomalous perihelion advances by Wilhelm and Dwivedi (New Astron. 31:51-55, 2014). The effect—an offset of the effective gravitational centre from the geometric centre of a spherical symmetric body—might also be responsible for the observed anomalous orbital energy gains and speed increases during Earth flybys of several spacecraft. However, close flybys would require detailed considerations of the orbit geometry. In this study, an attempt is made to explain the anomalous Earth flybys of the Galileo, NEAR Shoemaker and Rosetta spacecraft.

  3. The evaluation of multi-structure, multi-atlas pelvic anatomy features in a prostate MR lymphography CAD system

    Science.gov (United States)

    Meijs, M.; Debats, O.; Huisman, H.

    2015-03-01

    In prostate cancer, the detection of metastatic lymph nodes indicates progression from localized disease to metastasized cancer. The detection of positive lymph nodes is, however, a complex and time consuming task for experienced radiologists. Assistance of a two-stage Computer-Aided Detection (CAD) system in MR Lymphography (MRL) is not yet feasible due to the large number of false positives in the first stage of the system. By introducing a multi-structure, multi-atlas segmentation, using an affine transformation followed by a B-spline transformation for registration, the organ location is given by a mean density probability map. The atlas segmentation is semi-automatically drawn with ITK-SNAP, using Active Contour Segmentation. Each anatomic structure is identified by a label number. Registration is performed using Elastix, using Mutual Information and an Adaptive Stochastic Gradient optimization. The dataset consists of the MRL scans of ten patients, with lymph nodes manually annotated in consensus by two expert readers. The feature map of the CAD system consists of the Multi-Atlas and various other features (e.g. Normalized Intensity and multi-scale Blobness). The voxel-based Gentleboost classifier is evaluated using ROC analysis with cross validation. We show in a set of 10 studies that adding multi-structure, multi-atlas anatomical structure likelihood features improves the quality of the lymph node voxel likelihood map. Multiple structure anatomy maps may thus make MRL CAD more feasible.

  4. Structural and Phylogenetic Analysis of Rhodobacter capsulatus NifF: Uncovering General Features of Nitrogen-fixation (nif-Flavodoxins

    Directory of Open Access Journals (Sweden)

    Inmaculada Pérez-Dorado

    2013-01-01

    Full Text Available Analysis of the crystal structure of NifF from Rhodobacter capsulatus and its homologues reported so far reflects the existence of unique structural features in nif flavodoxins: a leucine at the re face of the isoalloxazine, an eight-residue insertion at the C-terminus of the 50’s loop and a remarkable difference in the electrostatic potential surface with respect to non-nif flavodoxins. A phylogenetic study on 64 sequences from 52 bacterial species revealed four clusters, including different functional prototypes, correlating the previously defined as “short-chain” with the firmicutes flavodoxins and the “long-chain” with gram-negative species. The comparison of Rhodobacter NifF structure with other bacterial flavodoxin prototypes discloses the concurrence of specific features of these functional electron donors to nitrogenase.

  5. Control-group feature normalization for multivariate pattern analysis of structural MRI data using the support vector machine.

    Science.gov (United States)

    Linn, Kristin A; Gaonkar, Bilwaj; Satterthwaite, Theodore D; Doshi, Jimit; Davatzikos, Christos; Shinohara, Russell T

    2016-05-15

    Normalization of feature vector values is a common practice in machine learning. Generally, each feature value is standardized to the unit hypercube or by normalizing to zero mean and unit variance. Classification decisions based on support vector machines (SVMs) or by other methods are sensitive to the specific normalization used on the features. In the context of multivariate pattern analysis using neuroimaging data, standardization effectively up- and down-weights features based on their individual variability. Since the standard approach uses the entire data set to guide the normalization, it utilizes the total variability of these features. This total variation is inevitably dependent on the amount of marginal separation between groups. Thus, such a normalization may attenuate the separability of the data in high dimensional space. In this work we propose an alternate approach that uses an estimate of the control-group standard deviation to normalize features before training. We study our proposed approach in the context of group classification using structural MRI data. We show that control-based normalization leads to better reproducibility of estimated multivariate disease patterns and improves the classifier performance in many cases. PMID:26915498

  6. Effective actions for anomalous hydrodynamics

    International Nuclear Information System (INIS)

    We argue that an effective field theory of local fluid elements captures the constraints on hydrodynamic transport stemming from the presence of quantum anomalies in the underlying microscopic theory. Focussing on global current anomalies for an arbitrary flavour group, we derive the anomalous constitutive relations in arbitrary even dimensions. We demonstrate that our results agree with the constraints on anomaly governed transport derived hitherto using a local version of the second law of thermodynamics. The construction crucially uses the anomaly inflow mechanism and involves a novel thermofield double construction. In particular, we show that the anomalous Ward identities necessitate non-trivial interaction between the two parts of the Schwinger-Keldysh contour

  7. Anomalous Dynamical Responses in a Driven System

    CERN Document Server

    Dutta, Suman

    2016-01-01

    The interplay between structure and dynamics in non-equilibrium steady-state is far from understood. We address this interplay by tracking Brownian Dynamics trajectories of particles in a binary colloid of opposite charges in an external electric field, undergoing cross-over from homogeneous to lane state, a prototype of heterogeneous structure formation in non-equilibrium systems. We show that the length scale of structural correlations controls heterogeneity in diffusion and consequent anomalous dynamic responses, like the exponential tail in probability distributions of particle displacements and stretched exponential structural relaxation. We generalise our observations using equations for steady state density which may aid to understand microscopic basis of heterogeneous diffusion in condensed matter systems.

  8. Special Features of Development of the Present World Financial Market Structure

    Directory of Open Access Journals (Sweden)

    Oleh Patsenko

    2012-03-01

    Full Text Available The article analyzes the different approaches to definition of the world financial market. Basic criterion approaches to the present world financial market structuring have been examined. The own world financial market structure model has been proposed. Current trends in development of the world financial market have been revealed in the perspective of its geographical, functional, monetary and institutional structure.

  9. The use of anomalous scattering of uranium for the determination of biological macromolecules structures - From hard to soft X-rays

    International Nuclear Information System (INIS)

    In order to solve biological macromolecules structures, structure factor phases must be derived from the intensities diffracted by the crystal. The SAD and the MAD methods make use of variations in scattering factors measured at specific absorption edges of heavy atoms, bound to the protein. The phasing power depends on the occupancy of the binding sites and on the variations of the scattering factors at the absorption edge that is used. With uranyl, numerous sites with low occupancies are usually obtained. We used new colored uranyl complexes, which give higher occupancies, to solve de novo the lysozyme structure and an unknown structure. We have developed the use of the My absorption edge of uranium (λ = 3,5 Angstroms), where a variation of 120 electrons is observed in the scattering factors. With a helium atmosphere to limit the X-rays absorption, we have collected three data sets, on a single image. Data were processed both with 'classical' and specific programs. (author)

  10. Crust-mantle structure feature and the seismic activity of the main tectonic units in the North Tanlu fault zone

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Using recent data of geoscience transaction in Northeast China, the author analyses and studies the crust-upper mantle structure feature of the North Tanlu fault zone. The result shows the crust-mantle structure are obvious difference at both sides of the North Tanlu fault zone. The fault activity and segmentation are closely related with abruptly change zone of the crust-upper mantle structure. There is a clear mirror image relationship between the big geomorphic shape and asthenosphere undulate, the former restricts tectonic stability and tectonic style of different crustal units. The significantly strengthening seismicity of north set and south set in the North Tanlu fault zone just correspond to the low-velocity and high conductivity layer of crust-upper mantle. In the North Tanlu fault zone, the main controlling structure of the mid-strong seismic generally consists of the active fault sectors, whose crust-mantle structure is more complicated in rigidity massif.

  11. Distinctive Features of the Temperature Sensitivity of a Transistor Structure in a Bipolar Mode of Measurement

    Science.gov (United States)

    Karimov, A. V.; Dzhuraev, D. P.; Kuliev, Sh. M.; Turaev, A. A.

    2016-03-01

    Results are presented of an experimental investigation of the temperature sensitivity of an individual base-to-collector junction of a bipolar transistor structure and of this same structure in the case of series connection of blocking emitter and collector junctions. It is shown that the temperature-sensitivity coefficient of the transistor structure operating in a bipolar mode of measurement is an order of magnitude larger than an analogous coefficient of the base-to-collector junction.

  12. Anomalous bootstrap current due to drift waves

    International Nuclear Information System (INIS)

    An anomalous parallel current driven by radial flux in tokamak is discussed. Drift waves, which cause an anomalous cross field diffusion, can generate a parallel current in a sheared magnetic field, if the fluctuation level has radial dependence. (author)

  13. Anomalous-viscosity current drive

    Science.gov (United States)

    Stix, T.H.; Ono, M.

    1986-04-25

    The present invention relates to a method and apparatus for maintaining a steady-state current for magnetically confining the plasma in a toroidal magnetic confinement device using anomalous viscosity current drive. A second aspect of this invention relates to an apparatus and method for the start-up of a magnetically confined toroidal plasma.

  14. Anomalous magnetic moment of anyons

    CERN Document Server

    Gat, G; Gat, Gil; Ray, Rashmi

    1994-01-01

    The anomalous magnetic moment of anyons is calculated to leading order in a 1/N expansion. It is shown that the gyromagnetic ratio g remains 2 to the leading order in 1/N. This result strongly supports that obtained in \\cite{poly}, namely that g=2 is in fact exact.

  15. Electromagnetic turbulent structures: A ubiquitous feature of the edge region of toroidal plasma configurations

    Energy Technology Data Exchange (ETDEWEB)

    Spolaore, M., E-mail: monica.spolaore@igi.cnr.it; Vianello, N.; Agostini, M.; Cavazzana, R.; De Masi, G.; Martines, E.; Momo, B.; Scaggion, A.; Scarin, P.; Spagnolo, S.; Spizzo, G.; Zuin, M. [Consorzio RFX (CNR, ENEA, INFN, Università di Padova, Acciaierie Venete SpA), Corso Stati Uniti 4, 35127 Padova (Italy); Furno, I.; Avino, F.; Fasoli, A.; Theiler, C. [Centre de Recherches en Physique des Plasmas (CRPP), Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland); Carralero, D. [Laboratorio Nacional de Fusion, CIEMAT, Avda. Complutense, 40 28040 Madrid (Spain); Max Planck Institute for Plasma Physics, Boltzmannstr. 2, 85748 Garching (Germany); Alonso, J. A.; Hidalgo, C. [Laboratorio Nacional de Fusion, CIEMAT, Avda. Complutense, 40 28040 Madrid (Spain)

    2015-01-15

    Electromagnetic features of turbulent filaments, emerging from a turbulent plasma background, have been studied in four different magnetic configurations: the stellarator TJ-II, the Reversed Field Pinch RFX-mod, a device that can be operated also as a ohmic tokamak, and the Simple Magnetized Torus, TORPEX. By applying an analogous diagnostic concept in all cases, direct measurements of both field-aligned current density and vorticity were performed inside the filament. The inter-machine comparison reveals a clear dependence of the filament vorticity upon the local time-averaged E × B flow shear. Furthermore, a wide range of local beta was explored allowing concluding that this parameter plays a fundamental role in the appearance of filament electromagnetic features.

  16. Recognizing clinical entities in hospital discharge summaries using Structural Support Vector Machines with word representation features

    OpenAIRE

    Tang, Buzhou; Cao, Hongxin; WU, YONGHUI; Jiang, Min; Xu, Hua

    2013-01-01

    Background Named entity recognition (NER) is an important task in clinical natural language processing (NLP) research. Machine learning (ML) based NER methods have shown good performance in recognizing entities in clinical text. Algorithms and features are two important factors that largely affect the performance of ML-based NER systems. Conditional Random Fields (CRFs), a sequential labelling algorithm, and Support Vector Machines (SVMs), which is based on large margin theory, are two typica...

  17. Assessing the Permeability of Landscape Features to Animal Movement: Using Genetic Structure to Infer Functional Connectivity

    OpenAIRE

    Anderson, Sara J.; Kierepka, Elizabeth M.; Robert K Swihart; Emily K Latch; Olin E Rhodes

    2015-01-01

    Human-altered environments often challenge native species with a complex spatial distribution of resources. Hostile landscape features can inhibit animal movement (i.e., genetic exchange), while other landscape attributes facilitate gene flow. The genetic attributes of organisms inhabiting such complex environments can reveal the legacy of their movements through the landscape. Thus, by evaluating landscape attributes within the context of genetic connectivity of organisms within the landscap...

  18. Anomalous structural evolution and √ 3 x√ 3 reconstruction of a clean Si(111) surface observed after thermal desorption of thallium

    Czech Academy of Sciences Publication Activity Database

    Kocán, P.; Krejčí, Ondřej; Tochihara, H.

    2015-01-01

    Roč. 33, č. 2 (2015), "021408-1"-"021408-8". ISSN 0734-2101 Institutional support: RVO:68378271 Keywords : surface structure * Si(111) * thallium * LEED * STM Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.322, year: 2014

  19. One-step synthesis of mesoporous pentasil zeolite with single-unit-cell lamellar structural features

    Science.gov (United States)

    Tsapstsis, Michael; Zhang, Xueyi

    2015-11-17

    A method for making a pentasil zeolite material includes forming an aqueous solution that includes a structure directing agent and a silica precursor; and heating the solution at a sufficient temperature and for sufficient time to form a pentasil zeolite material from the silica precursor, wherein the structure directing agent includes a quaternary phosphonium ion.

  20. Design Features and Initial RF Performance of a Gradient Hardened 17 GHz TW Linac Structure

    International Nuclear Information System (INIS)

    To avoid surface erosion damage and to assist in studying RF breakdown thresholds in 17 GHz TW linac structures, a gradient hardened structure has been fabricated with high temperature brazed and machined stainless steel surfaces located in the peak E-field region of the beam apertures and the peak H-field regions of the input coupler cavity. The microwave design parameters and physical dimensions of this 22 cavity, 120 degree phase advance structure were chosen to allow the high gradient performance to be compared against a similar design all-copper structure that has been tested in a dual ring, power recirculating amplifier system. The final design parameters of the gradient hardened structure are discussed; the influence of stainless steel RF losses on the power buildup of the resonant ring and on the structure gradient distribution are described; waveforms are shown of the unique ability of the power amplifier to rapidly quench RF breakdown discharges in the linac structure by automatically sensing and redirecting the RF source power to a matched load; and preliminary test results during high power RF processing of the gradient hardened linac structure are presented.

  1. Structural features and gasification reactivity of coal chars formed in Ar and CO2 atmospheres at elevated pressures

    International Nuclear Information System (INIS)

    The structural features and gasification reactivity of chars derived from pyrolysis of a bituminous coal under Ar (Ar char) and CO2 atmosphere (CO2 char) have been investigated, respectively. The pyrolysis was performed in a fixed bed reactor at a final temperature of 700 °C and pressures ranging from 0.1 to 1.5 MPa. It was found that CO2 affect the char yield, pore structure and surface area. The N2 surface area of the CO2 char at ambient pressure increased by nearly 42 times compared to the Ar char. The chemical structure features were characterized by using Raman spectroscopy. The recorded spectra between 800 and 1800 cm−1 were curve-fitted with 10 Gaussian bands representing typical structural features of chars to quantitatively compare the char structure difference. The ratio I(Gr+Vl+Vr)/ID between the band intensities of amorphous char structures with small aromatic ring (3–5 rings) systems and condensed aromatic ring systems (>6 rings) is seen to decrease with increasing pyrolysis pressure. The I(Gr+Vl+Vr)/ID of CO2 char is always lower than that of Ar char in the whole pressure range. The non-isothermal CO2 gasification from 700 to 1000 °C in a TGA (thermogravimetric analyzer) indicates that the char prepared under Ar atmosphere was more reactive. - Highlights: • Pressurized coal pyrolysis experiments were run in fixed bed reactor using CO2 or Ar. • Small to large aromatic ring ratio for CO2 chars is always lower than for Ar chars. • Ar derived chars show a slightly enhanced reactivity over CO2 derived chars

  2. Soil profile, relief features and their relation to structure and distribution of Brazilian Atlantic rain forest trees

    OpenAIRE

    Frederico Augusto Guimarães Guilherme; Tiago Osório Ferreira; Marco Antonio Assis; Pablo Vidal Torrado; Leonor Patrícia Cerdeira Morellato

    2012-01-01

    In tropical forests, the environmental heterogeneity can provide niche partitioning at local scales and determine the diversity and plant species distribution. Thus, this study aimed to investigate the variations of tree species structure and distribution in response to relief and soil profile features in a portion of the largest remnant of Brazilian Atlantic rain forest. All trees ³ 5 cm diameter at breast height were recorded in two 0.99 ha plots. Topographic survey and a soil characterizat...

  3. Synaptic enrichment of microRNAs in adult mouse forebrain is related to structural features of their precursors

    OpenAIRE

    Smalheiser Neil R

    2008-01-01

    Abstract Within mouse forebrain, a subset of microRNAs are significantly enriched in synaptoneurosomes (a synaptic fraction containing pinched-off dendritic spines) and a subset are significantly depleted relative to total forebrain homogenate. Here I show that, as a group, the pre-miR hairpin precursors of synaptically enriched microRNAs exhibit significantly different structural features than those that are non-enriched or depleted. Precursors of synaptically enriched microRNAs tend to hav...

  4. Аssociation of spectral closeness of flicker-noise parameters with features of underlying structure of system

    OpenAIRE

    Kolodiy Z. A.; Kruk O. H.; Sanots’kyy Y. V.; Holynskyy V. D.; Kolodiy A. Z.; Depko P. I.

    2009-01-01

    The results of computer design of chaotic motion of elementary particles are resulted in a flat rectangle which can be put in accordance to a pellicle resistor with the electrons of conductivity. The analysis of spectral closeness of chaotic motion shows that one of parameters of flicker-noise depends only on the amount of elementary particles and middle rate of their movement. The second parameter of flicker-noise (time of relaxation) depends on the features of underlying structure of the sy...

  5. Structural Features of Nanocrystalline Magnetite Obtained by Different Syntheses According to X-Ray Diffraction and Electron Microscopy Data

    Directory of Open Access Journals (Sweden)

    A.N. Kalinkevich

    2011-01-01

    Full Text Available Structural features of nanosized magnetite Fe3O4 synthesized in the presence of polymeric matrices (polysaccharide chitosan, etc. were studied using transmission electron microscopy (TEM and X-ray diffraction analysis. The data obtained strongly suggest the influence of the polysaccharide matrix on the magnetite nanoparticles growth inhibition and size stabilization. The controlled size decrease of Fe3O4 nanoparticles is accompanied with the increase of crystal lattice imperfection and the decrease of the unit cell size. The utility of TEM and XRD complementary use for the determination of nanosized magnetite particles structure and substructure parameters is shown in the present paper.

  6. Anomalous velocity distributions in active Brownian suspensions.

    Science.gov (United States)

    Fiege, Andrea; Vollmayr-Lee, Benjamin; Zippelius, Annette

    2013-08-01

    Large-scale simulations and analytical theory have been combined to obtain the nonequilibrium velocity distribution, f(v), of randomly accelerated particles in suspension. The simulations are based on an event-driven algorithm, generalized to include friction. They reveal strongly anomalous but largely universal distributions, which are independent of volume fraction and collision processes, which suggests a one-particle model should capture all the essential features. We have formulated this one-particle model and solved it analytically in the limit of strong damping, where we find that f(v) decays as 1/v for multiple decades, eventually crossing over to a Gaussian decay for the largest velocities. Many particle simulations and numerical solution of the one-particle model agree for all values of the damping. PMID:24032806

  7. Multiresolution Analysis Techniques to Isolate, Detect and Characterize Morphologically Diverse Features of Structured ICF Capsule Implosions

    CERN Document Server

    Afeyan, Bedros; Jones, Peter; Starck, Jean Luc; Herrmann, Mark

    2012-01-01

    In order to capture just how nonuniform and degraded the symmetry may become of an imploding inertial confinement fusion capsule one may resort to the analysis of high energy X ray point projection backlighting generated radiographs. Here we show new results for such images by using methods of modern harmonic analysis which involve different families of wavelets, curvelets and WaSP (wavelet square partition) functions from geometric measure theory. Three different methods of isolating morphologically diverse features are suggested together with statistical means of quantifying their content for the purposes of comparing the same implosion at different times, to simulations and to different implosion images.

  8. Layout Optimization of Structures with Finite-size Features using Multiresolution Analysis

    DEFF Research Database (Denmark)

    Chellappa, S.; Diaz, A. R.; Bendsøe, Martin P.

    2004-01-01

    A scheme for layout optimization in structures with multiple finite-sized heterogeneities is presented. Multiresolution analysis is used to compute reduced operators (stiffness matrices) representing the elastic behavior of material distributions with heterogeneities of sizes that are comparable to...

  9. Nonstatistical UV Fragmentation of Gas-Phase Peptides Reveals Conformers and Their Structural Features.

    Science.gov (United States)

    Kopysov, Vladimir; Makarov, Alexander; Boyarkin, Oleg V

    2016-03-17

    Solving the 3D structure of a biomolecule requires recognition of its conformers and measurements of their individual structural identities, which can be compared with calculations. We employ the phenomenon of nonstatistical photofragmentation, detected by a combination of UV cold ion spectroscopy and high-resolution mass spectrometry, to identify the main conformers of gas-phase peptides and to recover individual UV absorption and mass spectra of all of these conformers in a single laser scan. We first validate this approach with a benchmark dipeptide, Tyr-Ala, and then apply it to a decapeptide, gramicidin S. The revealed characteristic structural difference between the conformers of the latter identifies some of the previously calculated structures of gramicidin S as the most likely geometries of its remaining unsolved conformer. PMID:26950179

  10. Effect of certain structural features of coal on Its tendency towards reduction

    Energy Technology Data Exchange (ETDEWEB)

    Grigor' yeva, Ye. A.; Bakirova, Ye.V.; Dzhalyabova, L.V.; Larina, N.K.; Lesnikova, Ye.B.; Zharova, M.N.,

    1981-01-01

    A study is made of the effect of easily destroyed ether groupings and organic-mineral bonds in coal structure on the tendency towards reduction with the help of hydrolytic destruction of coals and subsequent selective reduction by sodium borohydride.

  11. Structural and cellular features in metaphyseal and diaphyseal periosteum of osteoporotic rats

    OpenAIRE

    Fan, Wei; Bouwense, Stefan A. W.; Crawford, Ross; Xiao, Yin

    2010-01-01

    Despite the important physiological role of periosteum in the pathogenesis and treatment of osteoporosis, little is known about the structural and cellular characteristics of periosteum in osteoporosis. To study the structural and cellular differences in both diaphyseal and metaphyseal periosteum of osteoporotic rats, samples from the right femur of osteoporotic and normal female Lewis rats were collected and tissue sections were stained with hematoxylin and eosin, antibodies or staining kit ...

  12. Extracting structural features of rat sciatic nerve using polarization-sensitive spectral domain optical coherence tomography

    OpenAIRE

    Islam, M. S.; de Oliveira, M. C.; Wang, Y.; Henry, F.P.; Randolph, M.A.; Park, B. H.; Boer

    2012-01-01

    We present spectral domain polarization-sensitive optical coherence tomography (SD PS-OCT) imaging of peripheral nerves. Structural and polarization-sensitive OCT imaging of uninjured rat sciatic nerves was evaluated both qualitatively and quantitatively. OCT and its functional extension, PS-OCT, were used to image sciatic nerve structure with clear delineation of the nerve boundaries to muscle and adipose tissues. A long-known optical effect, bands of Fontana, was also observed. Postprocessi...

  13. Endotoxin Structures in the Psychrophiles Psychromonas marina and Psychrobacter cryohalolentis Contain Distinctive Acyl Features

    OpenAIRE

    Charles R. Sweet; Alpuche, Giancarlo M.; Corinne A. Landis; Sandman, Benjamin C.

    2014-01-01

    Lipid A is the essential component of endotoxin (Gram-negative lipopolysaccharide), a potent immunostimulatory compound. As the outer surface of the outer membrane, the details of lipid A structure are crucial not only to bacterial pathogenesis but also to membrane integrity. This work characterizes the structure of lipid A in two psychrophiles, Psychromonas marina and Psychrobacter cryohalolentis, and also two mesophiles to which they are related using MALDI-TOF MS and fatty acid methyl este...

  14. Secondary Structure as a Functional Feature in the Downstream Region of Mammalian Polyadenylation Signals

    OpenAIRE

    Wu, Chunxiao; Alwine, James C.

    2004-01-01

    Secondary structure within the downstream region of mammalian polyadenylation signals has been proposed to perform important functions. The simian virus 40 late polyadenylation signal (SVLPA) forms alternate secondary structures in equilibrium. Their formation correlates with cleavage-polyadenylation efficiency (H. Hans and J. C. Alwine, Mol. Cell. Biol. 20:2926-2932, 2000; M. I. Zarudnaya, I. M. Kolomiets, A. L. Potyahaylo, and D. M. Hovorun, Nucleic Acids Res. 3:1375-1386, 2003), and oligon...

  15. STRUCTURAL FEATURES OF RABBIT SHIN-BONE AFTER FLUOROSIS EXPERIMENTAL MODEL CREATION

    Directory of Open Access Journals (Sweden)

    V.N. Karmazov

    2009-03-01

    Full Text Available Impact of ecological factors and chronic intoxications on an organism is not accounted in treatment of bone injuries. The more significant osseous tissue modifications arise in case of fluoric intoxication accompanied by structural bone modifications. The main structural changes of more and less variability by mineral density of similar shin-bone zones of rabbit at fluorosis have been revealed in the research.

  16. Pseudoclassical Model of Spinning Particle with Anomalous Magnetic Momentum

    CERN Document Server

    Gitman, D M

    1993-01-01

    A generalization of the pseudoclassical action of a spinning particle in the presence of an anomalous magnetic momentum is given. The action is written in reparametrization and supergauge invariant form. The Dirac quantization, based on the Hamiltonian analyses of the model, leads to the Dirac-Pauli equation for a particle with an anomalous magnetic momentum in an external electromagnetic field. Due to the structure of first-class constraints in that case, the Dirac quantization demands for consistency to take into account an operators ordering problem.

  17. Anomalous heat conduction and anomalous diffusion in nonlinear lattices, single walled nanotubes, and billiard gas channels

    OpenAIRE

    Li, Baowen; Wang, Jiao; Wang, Lei; Zhang, Gang

    2004-01-01

    We study anomalous heat conduction and anomalous diffusion in low dimensional systems ranging from nonlinear lattices, single walled carbon nanotubes, to billiard gas channels. We find that in all discussed systems, the anomalous heat conductivity can be connected with the anomalous diffusion, namely, if energy diffusion is $\\sigma^2(t)\\equiv =2Dt^{\\alpha} (01$) implies an anomalous heat conduction with a divergent thermal conductivity ($\\beta>0$), and more interestingly, a subdiffusion ($\\a...

  18. Structural defect generation and band-structure features in the HfNi1−xCoxSn semiconductor

    International Nuclear Information System (INIS)

    The crystal and electronic structure and magnetic, energy, and kinetic properties of the n-HfNiSn semiconductor heavily doped with the Co acceptor impurity (HfNi1−xCoxSn) are investigated in the temperature and Co concentration ranges T = 80–400 K and NACo ≈ 9.5 × 1019-5.7 × 1021 cm−3 (x = 0.005–0.30), respectively, and under magnetic field H ≤ 10 kOe. It is established that the degree of compensation of the semiconductor changes due to transformation of the crystal structure upon doping, which leads to the generation of acceptor and donor structural defects. The calculated electronic structure is consistent with the experiment; the HfNi1−xCoxSn semiconductor is shown to be a promising thermoelectric material. The results obtained are discussed within the Shklovsky-Efros model for a heavily doped and compensated semiconductor

  19. Litho-structural and geophysics features of the Alto Paranaiba Uplift

    International Nuclear Information System (INIS)

    The Alto Paranaiba Uplift (APU) is an almost elliptical tectonic feature of the Western Minas Gerais/Southern Goias region, which was active mostly during the Cretaceous. It separated the Parana Basin, during the formation of the Sao Bento, Uberaba and Bauru sequences, from the Alto-Sanfranciscana Basin, at the time of formation of the Areado, Patos, Capacete and Urucuia sequences. The Bouguer anomaly data indicate that the APU developed at the southwestern border of the ancient Brasilia crustal block and is represented by an almost elliptical gravity high of 15 mgal, locally disturbed by positive and negative the presence of important lineaments of a NW-SE set, mostly crossing the southwestern half of the APU. The APU development, the magmatism and the lateral basin formation involved reactivation of preexisting discontinuities and are related to a mantle plume. The tectonic development was aborted at the uplift stage during Cretaceous, after the deposition of the Bauru and Urucuia sequences, as is indicated by the Pratinha peneplane, now elevated at about 1.100 m altitude, which sculpture ended at the beginning of the Tertiary. The APU is one tectonic feature like other similar anomalies also aborted in the uplift stage or in the rift stage, which developed in Southern Brazil during the time of Atlantic Ocean opening. (author)

  20. Molecular features related to HIV integrase inhibition obtained from structure- and ligand-based approaches.

    Directory of Open Access Journals (Sweden)

    Luciana L de Carvalho

    Full Text Available Among several biological targets to treat AIDS, HIV integrase is a promising enzyme that can be employed to develop new anti-HIV agents. The aim of this work is to propose a mechanistic interpretation of HIV-1 integrase inhibition and to rationalize the molecular features related to the binding affinity of studied ligands. A set of 79 HIV-1 integrase inhibitors and its relationship with biological activity are investigated employing 2D and 3D QSAR models, docking analysis and DFT studies. Analyses of docking poses and frontier molecular orbitals revealed important features on the main ligand-receptor interactions. 2D and 3D models presenting good internal consistency, predictive power and stability were obtained in all cases. Significant correlation coefficients (r(2 = 0.908 and q(2= 0.643 for 2D model; r(2= 0.904 and q(2= 0.719 for 3D model were obtained, indicating the potential of these models for untested compounds. The generated holograms and contribution maps revealed important molecular requirements to HIV-1 IN inhibition and several evidences for molecular modifications. The final models along with information resulting from molecular orbitals, 2D contribution and 3D contour maps should be useful in the design of new inhibitors with increased potency and selectivity within the chemical diversity of the data.

  1. Phenomenological Spin Transport Theory Driven by Anomalous Nernst Effect

    Science.gov (United States)

    Taniguchi, Tomohiro

    2016-07-01

    Several experimental efforts such as material investigation and structure improvement have been made recently to find a large anomalous Nernst effect in ferromagnetic metals. Here, we develop a theory of spin transport driven by the anomalous Nernst effect in a diffusive ferromagnetic/nonmagnetic multilayer. Starting from a phenomenological formula of a spin-dependent electric current, the theoretical formulas of electric voltage and spin torque generated by the anomalous Nernst effect are derived. The magnitude of the electric voltage generated from the spin current via the inverse spin Hall effect is on the order of 0.1 µV for currently available experimental parameter values. The temperature gradient necessary to switch the magnetization is quite larger than the typical experimental value. The separation of the contributions of the Seebeck and transverse spin Seebeck effects is also discussed.

  2. Fractal Model of a Compact Intracloud Discharge. I. Features of the Structure and Evolution

    Science.gov (United States)

    Iudin, D. I.; Davydenko, S. S.

    2015-12-01

    We propose a new model of a compact intracloud discharge considered as the result of interaction between two (or more) bipolar streamer structures formed in a strong large-scale electric field of a thundercloud. The model assumes two stages of the compact discharge development. At the preliminary stage, two or more bipolar streamer structures appear successively in the thundercloud in the region of a strong electric field (at the boundaries between the regions of the main positive and the main negative electric charges or between the main positive charge region and the top negative screening layer). The time of development of such structures is determined by the characteristics of the conducting channels that form them and can reach tens of milliseconds. Spatiotemporal synchronization of the bipolar streamer structures is provided by the altitude modulation of the electric field, which, in particular, can originate from a large-scale turbulence of the cloud medium or the stream instability. It is shown that a single bipolar streamer structure accumulates significant electric charges of different signs at its ends as it develops. The start of the main stage of a compact intracloud discharge corresponds to the occurrence of the conducting channel (breakdown of the gap) between the mature streamer structures. The electric charge accumulated at the adjacent ends of the structures at this stage is neutralized over a time much shorter than the duration of the preliminary stage. The parameters of the current pulse are in good agreement with the estimates of the current of a compact intracloud discharge which were obtained in the transmission-line approximation.

  3. Classification of Vessels in Single-Pol COSMO-SkyMed Images Based on Statistical and Structural Features

    Directory of Open Access Journals (Sweden)

    Fan Wu

    2015-05-01

    Full Text Available Vessel monitoring is one of the most important maritime applications of Synthetic Aperture Radar (SAR data. Because of the dihedral reflections between the vessel hull and sea surface and the trihedral reflections among superstructures, vessels usually have strong backscattering in SAR images. Furthermore, in high-resolution SAR images, detailed information on vessel structures can be observed, allowing for vessel classification in high-resolution SAR images. This paper focuses on the feature analysis of merchant vessels, including bulk carriers, container ships and oil tankers, in 3 m resolution COSMO-SkyMed stripmap HIMAGE mode images and proposes a method for vessel classification. After preprocessing, a feature vector is estimated by calculating the average value of the kernel density estimation, three structural features and the mean backscattering coefficient. Support vector machine (SVM classifier is used for the vessel classification, and the results are compared with traditional methods, such as the K-nearest neighbor algorithm (K-NN and minimum distance classifier (MDC. In situ investigations are conducted during the SAR data acquisition. Corresponding Automatic Identification System (AIS reports are also obtained as ground truth to evaluate the effectiveness of the classifier. The preliminary results show that the combination of the average value of the kernel density estimation and mean backscattering coefficient has good ability for classifying the three types of vessels. When adding the three structural features, the results slightly improve. The result of the SVM classifier is better than that of K-NN and MDC. However, the SVM requires more time, when the parameters of the kernel are estimated.

  4. Anomalous dielectric behaviour in centrosymmetric organic–inorganic hybrid chlorobismuthate(III) containing functional N,N-dimethylethylammonium ligand. Crystal structure and properties

    International Nuclear Information System (INIS)

    Graphical abstract: Display Omitted Highlights: ► Novel organic–inorganic hybrid chlorobismuthate(III). ► Unprecedented dielectric response in non-polar material. ► Dielectric relaxation characterized by an exceptionally large dielectric increment. ► The NMR measurements confirmed dynamic disorder of cations. -- Abstract: The structure of [C2H5NH(CH3)2+]3[BiCl6−] (abbreviated as DCB) was determined by a single-crystal X-ray diffraction at 115 K. The compound adopts tetragonal symmetry with the space group I41/acd; a = 23.35 Å, c = 17.60 Å, V = 9598 Å3 and Z = 16. The crystal structure of DCB is built up of isolated [BiCl6]3− units and N,N-dimethylethylammonium counterions that are accommodated in the large voids. At ambient temperature two-thirds of the counterions appear to be dynamically disordered. Dynamics of this type of cations contributes to the enhanced dielectric permittivity of DCB. A low frequency dielectric relaxation process that takes place between 200 and 300 K is characterized by an exceptionally large dielectric increment, Δε > 100, which is unprecedented in nonferroelectric materials. The molecular motions of the N,N-dimethylethylammonium cations were studied by means of 1H NMR spin-lattice relaxation time measurements.

  5. Anomalous dielectric behaviour in centrosymmetric organic–inorganic hybrid chlorobismuthate(III) containing functional N,N-dimethylethylammonium ligand. Crystal structure and properties

    Energy Technology Data Exchange (ETDEWEB)

    Piecha, A., E-mail: anna.piecha@chem.uni.wroc.pl [Faculty of Chemistry, University of Wrocław, Joliot–Curie 14, 50–383 Wrocław (Poland); Gągor, A. [Institute of Low Temperature and Structure Research, PAS, Okólna 2, 50–950 Wrocław (Poland); Węcławik, M.; Jakubas, R. [Faculty of Chemistry, University of Wrocław, Joliot–Curie 14, 50–383 Wrocław (Poland); Medycki, W. [Institute of Molecular Physics, PAS, M. Smoluchowskiego 17, 60-179 Poznań (Poland)

    2013-01-15

    Graphical abstract: Display Omitted Highlights: ► Novel organic–inorganic hybrid chlorobismuthate(III). ► Unprecedented dielectric response in non-polar material. ► Dielectric relaxation characterized by an exceptionally large dielectric increment. ► The NMR measurements confirmed dynamic disorder of cations. -- Abstract: The structure of [C{sub 2}H{sub 5}NH(CH{sub 3}){sub 2}{sup +}]{sub 3}[BiCl{sub 6}{sup −}] (abbreviated as DCB) was determined by a single-crystal X-ray diffraction at 115 K. The compound adopts tetragonal symmetry with the space group I4{sub 1}/acd; a = 23.35 Å, c = 17.60 Å, V = 9598 Å{sup 3} and Z = 16. The crystal structure of DCB is built up of isolated [BiCl{sub 6}]{sup 3−} units and N,N-dimethylethylammonium counterions that are accommodated in the large voids. At ambient temperature two-thirds of the counterions appear to be dynamically disordered. Dynamics of this type of cations contributes to the enhanced dielectric permittivity of DCB. A low frequency dielectric relaxation process that takes place between 200 and 300 K is characterized by an exceptionally large dielectric increment, Δε > 100, which is unprecedented in nonferroelectric materials. The molecular motions of the N,N-dimethylethylammonium cations were studied by means of {sup 1}H NMR spin-lattice relaxation time measurements.

  6. The discovery of an anomalous RGB in M 2

    CERN Document Server

    Lardo, C; Mucciarelli, A; Milone, A P

    2013-01-01

    Using UV images taken with the Telescopio Nazionale Galileo, we discovered an anomalous sequence in the color-magnitude diagram of M 2. This feature appears as a narrow poor-populated red giant branch, which extends down to the sub giant branch region. We speculate that this new feature could be the extension of the faint component of the split sub giant branch recently discovered by Piotto et al. We identified in our UV images two CH stars detected in previous studies. These stars, which are both cluster members, fall on this redder sequence, suggesting indeed that the anomalous RGB should have a peculiar chemical pattern. Unfortunately, no additional spectra were obtained for stars in this previously unknown substructure

  7. Relation between uranium mineralization and structural features, Gebel Gattar, north eastern desert, Egypt

    International Nuclear Information System (INIS)

    Gebel Gattar area is situated in the northern Eastern Desert of Egypt, SW Hurghada city and is considered as an area of high potentialities for uranium deposits. The area is covered by Hammamat sediments and Gattarian granites. The Hammamat sediments are dissected by different types of dykes, while Gebel Gattar granites are cut only by basic dykes. These granites are mentioned as the younger pink granites, perthitic leucogranites, calc-alkaline and within plate granites. The structural deformations of the study area are represented by primary structures and secondary ones. The most prevailing structures are folding, faulting and jointing. The faults, especially those trending in the NNE-SSW and N-S directions played as pass ways to the ascending uranium-bearing hydrothermal solutions carrying uranium mineralizations. Most of them are located within a large pull apart basin. It is found from the relation between structures and uranium mineralization within the highly pro missing shear zones that uranium mineralizations are located within a large pull-apart basin, having about 2 km length and 0.5 km width. This idea is based up on the distribution of uranium mineralized lenses as shown in a block diagram. This conclusion is based on the structural framework of the area, the shape of mineralization and its distribution and their mutual relationships of Gl, Gll and GVl shear zones

  8. Prediction of protein structural features by use of artificial neural networks

    DEFF Research Database (Denmark)

    Petersen, Bent

    like for example GenBank are increasing considerably in size and GenBank currently contains more than 132 million sequences. Similar the Protein Data Bank currently contains more than 71,000 experimentally determined structures of nucleic acids, proteins and nucleic acid/protein complexes. There is a...... huge over-representation of DNA sequences when comparing the amount of experimentally verified proteins with the amount of DNA sequences. The academic and industrial research community therefore has to rely on structure predictions instead of waiting for the time consuming experimentally determined...... structure data. This thesis describes the development of two new tools to study such genetic sequence data. NetSurfP was developed to predict the surface accessibility of amino acids in amino acid sequences. Knowledge of the degree of surface exposure of an amino acid is valuable and has been used to...

  9. Morphological, structural and adsorption features of oxide composites with silica and titania matrices

    International Nuclear Information System (INIS)

    Morphological, structural, electronic, and adsorption characteristics of complex oxides such as fumed silica/alumina and silica/titania, fumed silica with deposited oxides of Mg, Ti, Mn, Ni, Cu, Zn and Zr, silica gel with grafted ZrO2, sol-gel titania doped by 3d-metals (Cr, Fe, Mn, V) were compared using adsorption, TEM, AFM, XRD, XPS, Moessbauer and Raman spectroscopy data. It was shown that surface, volume, and phase compositions of oxides, particle size distributions (5 nm-3 μm), specific surface area (SBET ∼ 50-500 m2/g), and porosity (VP ∼ 0.1-2 cm3/g) affected by synthesis technique and subsequent treatment determine electronic structure (bandgap, valence band and core levels structure) of the materials, adsorption of molecules and metal ions as well as other characteristics.

  10. The features of human heart internal relief structure in prenatal ontogenesis

    Directory of Open Access Journals (Sweden)

    Savenkova О.О.

    2008-01-01

    Full Text Available We have reviewed the development of internal relief of 101 human hearts during prenatal ontogenesis. It was used a macroscopic, immunohystochemical research methods, which enabled us to trace the processes of vessel’s development, proliferation of cardiac wall cells, heteromorphy of its structure in various stages of development. The data indicate the involvement of cardiogel, primary cardiomyocytes, as well as mesenchymal cells in the development and statement of the structural components, which form the internal relief of the heart chambers. The process of heart wall’s delamination is a separate morphological mechanism. Delamination plates are embryo material for the formation of tendinous chords, papillary muscles and muscle trabecula. Process of forming of the internal structures of relief occurs during the prenatal period of 5-20 weeks ontogenesis. One of the first parts of the heart, in which the process of papillary-trabecular apparatus forming occurs, is the atrium’s wall.

  11. Catalogue of the morphological features in the Spitzer Survey of Stellar Structure in Galaxies (S$^4$G)

    CERN Document Server

    Herrera-Endoqui, M; Laurikainen, E; Salo, H

    2015-01-01

    A catalogue of the morphological features for the complete Spitzer Survey of Stellar Structure in Galaxies (S$^4$G), including 2352 nearby galaxies, is presented. The measurements are made using 3.6 $\\mu$m images, largely tracing the old stellar population; at this wavelength the effects of dust are also minimal. The measured features are the sizes, ellipticities, and orientations of bars, rings, ringlenses, and lenses. Measured in a similar manner are also barlenses (lens-like structures embedded in the bars), which are not lenses in the usual sense, being rather the more face-on counterparts of the boxy/peanut structures in the edge-on view. In addition, pitch angles of spiral arm segments are measured for those galaxies where they can be reliably traced. More than one pitch angle may appear for a single galaxy. All measurements are made in a human-supervised manner so that attention is paid to each galaxy. We used isophotal analysis, unsharp masking, and fitting ellipses to measured structures. We find tha...

  12. Features of the behavior of some magnetohydrodynamic structures in the interplanetary space

    Science.gov (United States)

    Grib, S. A.; Leora, S. N.

    2015-12-01

    Constant pressure structures moving together with a solar wind flux are described based on magnetohydrodynamic representations. The action of magnetic hole type structures on the bow shock wave before the Earth's magnetosphere is thus considered. In the presence of a rotational discontinuity in the magnetic cloud, it is shown that the decomposition of an arbitrary discontinuity generates a plateau with an increase in the density of charged particles and a decrease in the intensity of the interplanetary magnetic field, which is repeatedly observed on spacecrafts. The plateau coincides with the properties of the magnetic hole to a large extent but is of another origin (in fact, local).

  13. Structural features of flower trichomes in drug eyebright (Euphrasia stricta D. Wolff EX J. F. Lehm.

    Directory of Open Access Journals (Sweden)

    Weronika Haratym

    2014-01-01

    Full Text Available Euphrasia stricta D. Wolff ex J. F. Lehm. (Orobanchaceae is a representative of plants that are widely used in folk medicine, phytomedicine, and homeopathy. The medicinal raw material derived from the drug eyebright is applied primarily in treatment of ophthalmic diseases. The investigations of trichomes in drug eyebright (Euphrasia stricta D. Wolff ex J. F. Lehm were conducted in 2010–2011. Using light microscopy and scanning electron microscopy, their location and morphological and anatomical features were identified. Three types of non-glandular trichomes were found: short unicellular, long 1–2 celled, and long 2-celled with wall ornamentation. Additionally, 7 types of glandular trichomes were found; these included: unicellular clavate, 2–3-celled clavate, capitate with a unicellular head and a 3-cel- led stalk, capitate with a unicellular head and a 2-celled stalk, capitate with a 2-celled head, conical papillae, and ribbon-like trichomes with wall thickening.

  14. A simple model for the anomalous intrinsic viscosity of dendrimers

    OpenAIRE

    Lu, Yuyuan; Shi, Tongfei; An, Lijia; Jin, Liping; Wang, Zhen-Gang

    2010-01-01

    The intrinsic viscosity of dendrimers in solution shows several anomalous behaviors that have hitherto not been explained within the existing theoretical frameworks of either Zimm or Rouse. Here we propose a simple two-zone model based on the radial segmental density profile of the dendrimers and combine a non-draining core with a free-draining outer region description, to arrive at a simple formula that captures most of the main features in the intrinsic viscosity data obtained in experiments.

  15. Anomalous vascularization in a Wnt medulloblastoma: a case report

    OpenAIRE

    Di Giannatale, Angela; Carai, Andrea; Cacchione, Antonella; Marrazzo, Antonio; Dell’Anna, Vito Andrea; Colafati, Giovanna Stefania; Diomedi-Camassei, Francesca; Miele, Evelina; Po, Agnese; Ferretti, Elisabetta; Locatelli, Franco; Mastronuzzi, Angela

    2016-01-01

    Background Medulloblastoma is the most common malignant brain tumor in children. To date only few cases of medulloblastoma with hemorrhages have been reported in the literature. Although some studies speculate on the pathogenesis of this anomalous increased vascularization in medulloblastoma, the specific mechanism is still far from clearly understood. A correlation between molecular medulloblastoma subgroups and hemorrhagic features has not been reported, although recent preliminary studies ...

  16. 2D plasmonic and diffractive structures with sharp features by UV laser patterning

    Czech Academy of Sciences Publication Activity Database

    Peláez, R.J.; Afonso, C.N.; Bulíř, Jiří; Novotný, Michal; Lančok, Ján; Piksová, K.

    2013-01-01

    Roč. 24, č. 9 (2013), "095301-1"-"095301-7". ISSN 0957-4484 R&D Projects: GA AV ČR IAA100100718 Institutional support: RVO:68378271 Keywords : silver thin film * silver nanoparticles * plasmonics * diffractive structures * laser processing Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.672, year: 2013

  17. Decomposition of Diffuse Reflectance Images - Features for Monitoring Structure in Turbid Media

    DEFF Research Database (Denmark)

    Skytte, Jacob Lercke; Nielsen, Otto Højager Attermann; Andersen, Ulf; Carstensen, Jens Michael; Dahl, Anders Lindbjerg; Larsen, Rasmus; Møller, Flemming; Kamran, Faisal; Frisvad, Jeppe Revall

    2013-01-01

    Light scattering in turbid media can be related to the microstructure of media. Thus, light scattering can potentially be used for process control of products where the structure is a key component. However process control requires robust and sensitive input data to function properly. In this study...

  18. Structural and hydrogeological features of a Lias carbonate aquifer in the Triffa Plain, NE Morocco

    Science.gov (United States)

    Sardinha, J.; Carneiro, J. F.; Zarhloule, Y.; Barkaoui, A.; Correia, A.; Boughriba, M.; Rimi, A.; El Houadi, B.

    2012-09-01

    The rising demand for water and the contamination of shallow water table aquifers has led authorities in NE Morocco to look for deeper groundwater resources in the Triffa Plain, namely in Lower Jurassic (Lias) dolomitic limestones. The liassic aquifer is of strategic importance for the development of the region, however, its hydrodynamic behaviour is poorly understood due to lack of hydrogeological data and block structure. This article presents a first effort towards understanding the structure and hydraulic behaviour of the aquifer. Exploration borehole data and results from geophysical campaigns were integrated into a GIS environment to build a preliminary model of the aquifer structure. The aquifer behaves as an unconfined aquifer in the northern part of the Béni Snassen Mountains (the recharge area), but as it dips to the north, it becomes confined by marls and shales of the Middle/Upper Jurassic. Even though piezometric level data are scarce, a tentative piezometric map was produced. Three blocks separated by NW-SE trending faults in a horst and graben structure, with distinct flow behaviours were identified: Berkane, Fezouane and Sidi Rahmoun blocks. Those blocks also show differences in hydraulic conductivity distribution. As a result of the reaction with the dolomitic limestones, the groundwater is of calcium-magnesium bicarbonate type. Groundwater temperature as measured in springs ranges from 29 °C to 37 °C in springs and constitutes a potential low enthalpy geothermal resource.

  19. Analysis on anomalous degradation in silicon solar cell designed for space use

    Energy Technology Data Exchange (ETDEWEB)

    Ohshima, Takeshi; Morita, Yousuke; Nashiyama, Isamu [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment; Kawasaki, Osamu; Hisamatsu, Tadashi; Yamamoto, Yasunari; Matsuda, Sumio; Nakao, Tetsuya; Wakow, Yoshihito

    1997-03-01

    Recently, we have found the anomalous degradation of electrical performance in silicon solar cells irradiated with charged particles in a high-fluence region. This anomalous phenomenon has two typical features, which are sudden-drop-down of electrical performances in a high-fluence region and slight recovery of the short circuit current I{sub SC} just before the sudden-drop-down. These features cannot be understood by a conventional model coming from the decrease of minority-carriers life-time. We introduce this anomalous degradation of the electrical performance in Si solar cells irradiated with electrons or protons. We also report the result of simulation for the fluence dependence of the I{sub SC}, and discuss the mechanism of this anomalous phenomenon. (author)

  20. Minimal muon anomalous magnetic moment

    CERN Document Server

    Biggio, Carla

    2014-01-01

    We classify all possible one-particle (scalar and fermion) extensions of the Standard Model that can contribute to the anomalous magnetic moment of leptons. We review the cases already discussed in the literature and complete the picture by performing the calculation for a fermionic doublet with hypercharge -3/2. We conclude that, out of the listed possibilities, only two scalar leptoquarks and the pseudoscalar of a peculiar two-Higgs-doublet model could be the responsibles for the muon anomalous magnetic moment discrepancy. Were this the case, this particles could be seen in the next LHC run. To this aim, especially to test the leptoquark hypothesis, we suggest to look for final states with tops and muons.

  1. Features of morpho-anatomic structure of vegetative organs of Sedum antiquum Omelcz et Zaverucha (Crassulaceae DC.

    Directory of Open Access Journals (Sweden)

    Valentyna Berezkina

    2015-05-01

    Full Text Available The study results of biological features and morpho-anatomical structure of vegetative organs of Sedum antiquum Omelcz et Zaverucha (Crassulaceae DC. are given. S. antiquum is Eastern Carpathian-Opillia rare endemic species. It is listed in the Red Book of Ukraine and in the European Red List of Animals and Plants and is endangered in world scale. As a result of study of morpho-anatomic structure of leaves and stems of S. antiquum the anisocytic type of stomata and presence of cuticle have been determined. It was ascertained that structure of leaves is adapted to the accumulation of significant water reserves and its further gradual use. Ecological and phytocenotic conditions of growth are studied too. S. antiquum has been determined here as petrophyte, calcephyl, and succulent ephemer. This rare species need protection and control of population state in all natural habitats.

  2. Anomalous Diffusion in Velocity Space

    OpenAIRE

    Trigger, S. A.

    2009-01-01

    The problem of anomalous diffusion in the momentum space is considered on the basis of the appropriate probability transition function (PTF). New general equation for description of the diffusion of heavy particles in the gas of the light particles is formulated on basis of the new approach similar to one in coordinate space (S. Trigger et al.). The obtained results permit to describe the various situations when the probability transition function (PTF) has a long tail in the momentum space. ...

  3. Structural features of the GroEL-GroES nano-cage required for rapid folding of encapsulated protein

    DEFF Research Database (Denmark)

    Tang, Sheila Tuyet; Chang, HC; Roeben, A; Wischnewski, D; Wischnewski, N; Kerner, MJ; Hartl, FU; Hayer-Hartl, M

    2006-01-01

    . Additionally, interactions with the C-terminal, mildly hydrophobic Gly-Gly-Met repeat sequences of GroEL protruding into the cavity, and repulsion effects from the negatively charged cavity wall were required for rapid folding of some proteins. We suggest that by combining these features, the chaperonin cage......GroEL and GroES form a chaperonin nano-cage for proteins up to similar to 60 kDa to fold in isolation. Here we explored the structural features of the chaperonin cage critical for rapid folding of encapsulated substrates. Modulating the volume of the GroEL central cavity affected folding speed in...... accordance with confinement theory. Small proteins (similar to 30 kDa) folded more rapidly as the size of the cage was gradually reduced to a point where restriction in space slowed folding dramatically. For larger proteins (similar to 40-50 kDa), either expanding or reducing cage volume decelerated folding...

  4. Three-dimensional reconstruction of anomalous eutectic in laser remelted Ni-30 wt.% Sn alloy

    Science.gov (United States)

    Cao, Yong-Qing; Lin, Xin; Wang, Zhi-Tai; Wang, Li-Lin; Song, Meng-Hua; Yang, Hai-Ou; Huang, Wei-Dong

    2015-12-01

    Laser remelting has been performed on Ni-30 wt.% Sn hypoeutectic alloy. An anomalous eutectic formed at the bottom of the molten pool when the sample was remelted thoroughly. 3D morphologies of the α-Ni and Ni3Sn phases in the anomalous eutectic region were obtained and investigated using serial sectioning reconstruction technology. It is found that the Ni3Sn phase has a continuous interconnected network structure and the α-Ni phase is distributed as separate particles in the anomalous eutectic, which is consistent with the electron backscatter diffraction pattern examinations. The α-Ni particles in the anomalous eutectic are supersaturated with Sn element as compared with the equilibrium phase diagram. Meanwhile, small wavy lamella eutectics coexist with anomalous eutectics. The Trivedi-Magnin-Kurz model was used to estimate undercooling with lamellar spacing. The results suggest that the critical undercooling found in undercooling solidification is not a sufficient condition for anomalous eutectic formation. Besides, α-Ni particles in the anomalous eutectic do not exhibit a completely random misorientation and some neighboring α-Ni particles have the same orientation. It is shown that both the coupled and decoupled growth of the eutectic two phases can generate the α-Ni + Ni3Sn anomalous eutectic structure.

  5. Some specific features of domain structure of orthoferrite crystals in the range of spin reorientation

    International Nuclear Information System (INIS)

    Investigations of the domain structure of Smsub(0.55)Tbsub(0.45)FeOsub(3) plate-shaped monocrystals in the temperature range from 77 to 300 K were carried out. In the range of spin reorientation (210-300 K) the complex reconstruction of domain structure was observed. The process was accompanied by the appearance of four magnetic phases distributed along two axes of light magnetization. They form effectively the secondary system of macrodomains. The width of macrodomains are determined by the value of the tangential component of magnetization and the size of a pattern along the crystallographic axis a. It is found that the temperature intervals, where the change of spontaneous magnetic moment orientation takes place, don't coincide near the surface and within the volume of the crystal. This fact may be related to different temperature behaviour of magnetic anizotropy constants on the surface of the crystal and within it

  6. Influence of laser cladding regimes on structural features and mechanical properties of coatings on titanium substrates

    Science.gov (United States)

    Malyutina, Yulia N.; Lazurenko, Daria V.; Bataev, Ivan A.; Movtchan, Igor A.

    2015-10-01

    In this paper an influence of the tantalum content on the structure and properties of surface layers of the titanium alloy doped using a laser treatment technology was investigated. It was found that an increase of a quantity of filler powder per one millimeter of a track length contributed to a rise of the content of undissolved particles in coatings. The maximum thickness of a cladded layer was reached at the mass of powder per the length unit equaled to 5.5 g/cm. Coatings were characterized by the formation of a dendrite structure with attributes of segregation. The width of a quenched fusion zone grew with an increase in the rate of powder feed to the treated area. Significant strengthening of the titanium surface layer alloyed with tantalum was not observed; however, the presence of undissolved tantalum particles can decrease the hardness of titanium surface layers.

  7. Properties and features of structure formation CuCr-contact alloys in electron beam cladding

    Energy Technology Data Exchange (ETDEWEB)

    Durakov, Vasiliy G., E-mail: electron@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Dampilon, Bair V., E-mail: dampilon@ispms.tsc.ru, E-mail: gnusov@rambler.ru; Gnyusov, Sergey F., E-mail: dampilon@ispms.tsc.ru, E-mail: gnusov@rambler.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055, Russia and National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation)

    2014-11-14

    The microstructure and properties of the contact CuCr alloy produced by electron-beam cladding have been investigated. The effect of the electron beam cladding parameters and preheating temperature of the base metal on the structure and the properties of the coatings has been determined. The bimodal structure of the cladding coating has been established. The short circuit currents tests have been carried out according to the Weil-Dobke synthetic circuit simulating procedure developed for vacuum circuit breakers (VCB) test in real electric circuits. Test results have shown that the electron beam cladding (EBC) contact material has better breaking capacity than that of commercially fabricated sintered contact material. The application of the technology of electron beam cladding for production of contact material would significantly improve specific characteristics and reliability of vacuum switching equipment.

  8. Influence of laser cladding regimes on structural features and mechanical properties of coatings on titanium substrates

    Energy Technology Data Exchange (ETDEWEB)

    Malyutina, Yulia N., E-mail: iuliiamaliutina@gmail.ru; Lazurenko, Daria V., E-mail: pavlyukova-87@mail.ru; Bataev, Ivan A., E-mail: ivanbataev@ngs.ru [Novosibirsk State Technical University, Novosibirsk, 630073 (Russian Federation); Movtchan, Igor A., E-mail: igor.movtchan@enise.fr [National Engineering School in Saint-Etienne, Saint-Etienne, 42000 France (France)

    2015-10-27

    In this paper an influence of the tantalum content on the structure and properties of surface layers of the titanium alloy doped using a laser treatment technology was investigated. It was found that an increase of a quantity of filler powder per one millimeter of a track length contributed to a rise of the content of undissolved particles in coatings. The maximum thickness of a cladded layer was reached at the mass of powder per the length unit equaled to 5.5 g/cm. Coatings were characterized by the formation of a dendrite structure with attributes of segregation. The width of a quenched fusion zone grew with an increase in the rate of powder feed to the treated area. Significant strengthening of the titanium surface layer alloyed with tantalum was not observed; however, the presence of undissolved tantalum particles can decrease the hardness of titanium surface layers.

  9. Influence of laser cladding regimes on structural features and mechanical properties of coatings on titanium substrates

    International Nuclear Information System (INIS)

    In this paper an influence of the tantalum content on the structure and properties of surface layers of the titanium alloy doped using a laser treatment technology was investigated. It was found that an increase of a quantity of filler powder per one millimeter of a track length contributed to a rise of the content of undissolved particles in coatings. The maximum thickness of a cladded layer was reached at the mass of powder per the length unit equaled to 5.5 g/cm. Coatings were characterized by the formation of a dendrite structure with attributes of segregation. The width of a quenched fusion zone grew with an increase in the rate of powder feed to the treated area. Significant strengthening of the titanium surface layer alloyed with tantalum was not observed; however, the presence of undissolved tantalum particles can decrease the hardness of titanium surface layers

  10. Special Features of Polarization-Induced Relaxation in Structurally Disordered Finely Dispersed Systems

    Science.gov (United States)

    Shcherbachenko, L. A.; Tanaev, A. B.; Bezrukova, Ya. V.; Ezhova, L. I.; Baryshnikov, D. S.; Marchuk, S. D.; Berezovskii, P. P.

    2015-04-01

    Dielectric characteristics of finely dispersed hydrated natural coal from the Krasnoyarsk Strip Mine are measured in wide ranges of external measuring electric field frequencies, environmental temperatures, and humidities. The frequency, temperature, and concentration dispersions of the dielectric permittivity are revealed for the examined structures. An analysis of the results obtained demonstrates that a cluster layer of the polar aqueous matrix characterized by rigid fixing of water molecules is formed at the interphase boundaries of the examined system. It is demonstrated that this layer plays the role of the potential barrier that complicates transitions for both free water molecules and surface active dispersed coals oriented by the electric field. This layer can increase the electric strength of the examined disordered finely dispersed structures.

  11. Sensitivity of near field GIA response with respect to rheological features of the Earth structure

    OpenAIRE

    Jan Hagedoorn; V. Klemann; I. Sasgen; M. Thomas

    2016-01-01

    One task of the German National Climate Modeling Initiative PalMod will be to couple earth system models representing the atmospere, ocean and ice dynamics during the last glacial cycle with the dynamic loading response of a viscoelastic earth model. In preparation, we discuss in this study the influence of viscosity stratification and of lateral heterogeneities in the Earth structure on the solid-earth response to glacial loading. As discussed in literature, there is a controvers...

  12. Cruciform structures are a common DNA feature important for regulating biological processes

    Czech Academy of Sciences Publication Activity Database

    Brázda, Václav; Laister, R.C.; Jagelská, Eva; Arrowsmith, Ch.

    2011-01-01

    Roč. 12, č. 33 (2011), s. 1-16. ISSN 1471-2199 R&D Projects: GA ČR(CZ) GAP301/10/1211; GA MŠk(CZ) LC06035 Institutional research plan: CEZ:AV0Z50040507; CEZ:AV0Z50040702 Keywords : cruciform structure * inverted repeat * protein-DNA binding Subject RIV: BO - Biophysics Impact factor: 2.857, year: 2011

  13. Quantitative analysis of composition, structure and features of hemoglobin under the influence of radiation in vivo

    International Nuclear Information System (INIS)

    The literature data on the changes in composition, structure and properties of hemoglobin under the influence of ionizing radiation in vivo are reviewed. The algorithm of calculation of damaged hemoglobin molecule percentage is proposed. Four main realizations of radiation-chemical damage are considered. By the algorithm the estimation of the damaged molecules percentage resulted from the exposure to 10 Gy is given. Hemoglobin radiation damage is considered as one of the most important mechanisms triggering radiation sickness. 11 refs

  14. Structural and dynamical features of multiple metastable glassy states in a colloidal system with competing interactions

    OpenAIRE

    Klix, Christian L.; Royall, C. Patrick; Tanaka, Hajime

    2010-01-01

    Systems in which a short-ranged attraction and long-ranged repulsion compete are intrinsically frustrated, leading their structure and dynamics to be dominated either by mesoscopic order or by metastable disorder. Here we report the latter case in a colloidal system with long-ranged electrostatic repulsions and short-ranged depletion attractions. We find a variety of states exhibiting slow non-diffusive dynamics: a gel, a glassy state of clusters, and a state reminiscent of a Wigner glass. Va...

  15. Structural and electronic features of binary Li2S-P2S5 glasses

    Science.gov (United States)

    Ohara, Koji; Mitsui, Akio; Mori, Masahiro; Onodera, Yohei; Shiotani, Shinya; Koyama, Yukinori; Orikasa, Yuki; Murakami, Miwa; Shimoda, Keiji; Mori, Kazuhiro; Fukunaga, Toshiharu; Arai, Hajime; Uchimoto, Yoshiharu; Ogumi, Zempachi

    2016-02-01

    The atomic and electronic structures of binary Li2S-P2S5 glasses used as solid electrolytes are modeled by a combination of density functional theory (DFT) and reverse Monte Carlo (RMC) simulation using synchrotron X-ray diffraction, neutron diffraction, and Raman spectroscopy data. The ratio of PSx polyhedral anions based on the Raman spectroscopic results is reflected in the glassy structures of the 67Li2S-33P2S5, 70Li2S-30P2S5, and 75Li2S-25P2S5 glasses, and the plausible structures represent the lithium ion distributions around them. It is found that the edge sharing between PSx and LiSy polyhedra increases at a high Li2S content, and the free volume around PSx polyhedra decreases. It is conjectured that Li+ ions around the face of PSx polyhedra are clearly affected by the polarization of anions. The electronic structure of the DFT/RMC model suggests that the electron transfer between the P ion and the bridging sulfur (BS) ion weakens the positive charge of the P ion in the P2S7 anions. The P2S7 anions of the weak electrostatic repulsion would causes it to more strongly attract Li+ ions than the PS4 and P2S6 anions, and suppress the lithium ionic conduction. Thus, the control of the edge sharing between PSx and LiSy polyhedra without the electron transfer between the P ion and the BS ion is expected to facilitate lithium ionic conduction in the above solid electrolytes.

  16. Application of feature method to the modelling of composite structural elements

    OpenAIRE

    A. Baier; M. Majzner

    2011-01-01

    Purpose: The paper describes the use of object-oriented methods in modelling and analysis of components made of fibre-based composites. Defined and specified the method for creating fibre primitives. An algorithm for the design of composite structures using object-oriented methods.Design/methodology/approach: The basic tool is an algorithm to build fibre facilities. Material properties can be found in the previously created databases of material objects. The whole is linked to the relevant fo...

  17. Catastrophic volcanism as a cause of shocked features found at the K/T boundary and in cryptoexplosion structures

    Science.gov (United States)

    Loper, D. E.; Mccartney, K.

    1988-01-01

    The presence of quartz grains containing shock lamellae at the Cretaceous/Tertiary (K/T) boundary is viewed by many as the single most compelling evidence of meteoritic or cometary impact because there is no known endogenous mechanism for producing these features. Similarly the presence of shocked quartz, shatter cones, coesite and stishovite at cryptoexplosion structures is comonly taken as conclusive evidence of impact. However, several recent studies have cast doubt on this interpretation. It is argued that basaltic volcanism, although not normally explosive, can under exceptional circumstances produce overpressures sufficiently high to produce shock features. The exceptional circumstances include a high content of volatiles, usually CO2, and no preestablished pathway to the surface. Rapid cooling of the saturated basaltic magma can occur if it underlies a cooler more evolved magma in a chamber. Initial slow cooling and partial exsolution of the volatiles will cause the density of the basaltic magma to become less than that of the overlying magma, leading to overturning and mixing. Gas will escape the magma chamber along planar cracks once the pressure becomes sufficiently high. In the vicinity of the crack tip there is a smallscale deviatoric stress pattern which is thought to be sufficiently high to produce transient cracks along secondary axes in the quartz crystals, causing the planar features. The CO2-rich fluid inclusions which have been found along planar elements of quartz in basement rocks of the Vredefort Dome were likely to have been emplaced by such a process. If the mechanism described is capable of producing shocked features as above, it would require a reassessment of the origin of many cryptoexplosion structures as well as seriously weakening the case for an impact origin of the K/T event.

  18. Atomic layer deposition TiO2 coated porous silicon surface: Structural characterization and morphological features

    International Nuclear Information System (INIS)

    TiO2 thin films were grown on highly-doped p-Si (100) macro- and mesoporous structures by atomic layer deposition (ALD) using TiCl4 and deionized water as precursors at 300 °C. The crystalline structure, chemical composition, and morphology of the deposited films and initial silicon nanostructures were investigated by scanning electron microscopy, transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, micro-Raman spectroscopy and X-ray diffraction (XRD). The mean size of TiO2 crystallites was determined by TEM, XRD and Raman spectroscopy. It was shown that the mean crystallite size and the crystallinity of the TiO2 are influenced dramatically by the morphology of the porous silicon, with the mesoporous silicon resulting in a much finer grain size and amorphous structure than the macroporous silicon having a partially crystal anatase phase. A simple model of the ALD layer growth inside the pores was presented. - Highlights: • The morphology and chemical composition of TiO2 and porous Si were established. • The approximate size of TiO2 nanocrystals was estimated. • The model of the atomic layer deposition coating in the porous Si was presented

  19. Structural features of lignite humic acid in light of NMR and thermal degradation experiments

    Energy Technology Data Exchange (ETDEWEB)

    Peuravuori, J.; Simpson, A.J.; Lam, B.; Zbankova, P.; Pihlaja, K. [University of Turku, Turku (Finland). Dept. of Chemistry

    2007-01-29

    Structural composition of a lignite humic acid (HA) fraction was studied by means of solid-state {sup 13}C NMR, different solution-state {sup 1}H NMR pulse techniques and thermally assisted hydrolysis-methylation with TMAH and TMAAc followed-up with pyrolysis-GC-MS experiments. The results verified that certain aliphatic compounds have their special tasks in the complicated structural network of lignite HA material, and aprotic solvents with strong electron-donor powers are needed to release the tightly bound certain aliphatics from the macromolecular network for obtaining a fully dissolved HA solution. The occurrence of the relatively large content of different carboxylic acids as their free-acid forms was surprising. The structural interpretations performed by special {sup 1}H NMR pulse techniques verified the complexity of aliphatic moieties, the presence of hydroaromatic carbons, residual lignin derivatives, the abundance of aliphatic and aromatic carboxylic acids, and the ability of aliphatics to form inter-molecular bridges between aromatic building blocks.

  20. Emerging From the Unknown: Structural and Functional Features of Agnoprotein of Polyomaviruses.

    Science.gov (United States)

    Saribas, A Sami; Coric, Pascale; Hamazaspyan, Anahit; Davis, William; Axman, Rachael; White, Martyn K; Abou-Gharbia, Magid; Childers, Wayne; Condra, Jon H; Bouaziz, Serge; Safak, Mahmut

    2016-10-01

    Agnoprotein is an important regulatory protein of polyomaviruses, including JCV, BKV, and SV40. In the absence of its expression, these viruses are unable to sustain their productive life cycle. It is a highly basic phosphoprotein that localizes mostly to the perinuclear area of infected cells, although a small amount of the protein is also found in nucleus. Much has been learned about the structure and function of this important regulatory protein in recent years. It forms highly stable dimers/oligomers in vitro and in vivo through its Leu/Ile/Phe-rich domain. Structural NMR studies revealed that this domain adopts an alpha-helix conformation and plays a critical role in the stability of the protein. It associates with cellular proteins, including YB-1, p53, Ku70, FEZ1, HP1α, PP2A, AP-3, PCNA, and α-SNAP; and viral proteins, including small t antigen, large T antigen, HIV-1 Tat, and JCV VP1; and significantly contributes the viral transcription and replication. This review summarizes the recent advances in the structural and functional properties of this important regulatory protein. J. Cell. Physiol. 231: 2115-2127, 2016. © 2016 Wiley Periodicals, Inc. PMID:26831433

  1. Connections between structural jamming, local metabasin features, and relaxation dynamics in a supercooled glassy liquid

    Science.gov (United States)

    Frechero, M. A.; Alarcón, L. M.; Schulz, E. P.; Appignanesi, G. A.

    2007-01-01

    Dynamics in glass-forming liquids in the supercooled regime vary considerably from one point of the sample to another suggesting the existence of regions with different degrees of jamming. In fact, the existence of relatively compact regions with particles with an enhanced propensity for motion has been detected in model glassy systems. In turn, the structural relaxation has been shown to be accomplished by means of a series of fast transitions between metabasins in the potential energy landscape involving the collective motion of a substantial number of particles arranged in relatively compact clusters (democratic clusters or d clusters). In this work we shall complete this picture by identifying the connections between local structural jamming, metabasin confining strength, and d clusters. Thus we shall demonstrate that the degree of jamming of the local structure dictates the confining strength of the local metabasin and that the local high propensity regions and the d clusters are not only similar in nature but that they share a significant amount of particles.

  2. Very high resolution Earth observation features for monitoring plant and animal community structure across multiple spatial scales in protected areas

    Science.gov (United States)

    Mairota, Paola; Cafarelli, Barbara; Labadessa, Rocco; Lovergine, Francesco; Tarantino, Cristina; Lucas, Richard M.; Nagendra, Harini; Didham, Raphael K.

    2015-05-01

    Monitoring the status and future trends in biodiversity can be prohibitively expensive using ground-based surveys. Consequently, significant effort is being invested in the use of satellite remote sensing to represent aspects of the proximate mechanisms (e.g., resource availability) that can be related to biodiversity surrogates (BS) such as species community descriptors. We explored the potential of very high resolution (VHR) satellite Earth observation (EO) features as proxies for habitat structural attributes that influence spatial variation in habitat quality and biodiversity change. In a semi-natural grassland mosaic of conservation concern in southern Italy, we employed a hierarchical nested sampling strategy to collect field and VHR-EO data across three spatial extent levels (landscape, patch and plot). Species incidence and abundance data were collected at the plot level for plant, insect and bird functional groups. Spectral and textural VHR-EO image features were derived from a Worldview-2 image. Three window sizes (grains) were tested for analysis and computation of textural features, guided by the perception limits of different organisms. The modelled relationships between VHR-EO features and BS responses differed across scales, suggesting that landscape, patch and plot levels are respectively most appropriate when dealing with birds, plants and insects. This research demonstrates the potential of VHR-EO for biodiversity mapping and habitat modelling, and highlights the importance of identifying the appropriate scale of analysis for specific taxonomic groups of interest. Further, textural features are important in the modelling of functional group-specific indices which represent BS in high conservation value habitat types, and provide a more direct link to species interaction networks and ecosystem functioning, than provided by traditional taxonomic diversity indices.

  3. Alcohol adducts of alkoxides: Intramolecular hydrogen bonding as a general structural feature

    International Nuclear Information System (INIS)

    Characterization of Zr2(OiPr)8(iPrOH)2 by 1H and 13C NMR spectroscopy, ir spectroscopy, and single-crystal x-ray diffraction (-100 degree C) is reported. The unit cell contains four half-dimers in the asymmetric unit, all of which differ only in the rotational conformation about Zr-O and O-C bonds. In each dimer, the edge-shared bioctahedron has two μ-OiPr groups. On opposite sides of this Zr2(μ-OR)2 plane, each dimer forms two hydrogen bonds, one each between a coordinated alcohol and a terminal alkoxide. The NMR spectra at 25 degree C are so simple as to be structurally uninformative, a result of rapid fluxionality which includes, as one component, proton migration among all OiPr units. At -80 degree C in toluene, the NMR spectra are now too complex to be accounted for by a single edge-shared bioctahedral structure. The hafnium analogue is isomorphous with the zirconium compound. Although Ce2(OiPr)8(iPrOH)2 is not isomorphous, it exhibits an analogous hydrogen-bonded structure in which the O hor-ellipsis O distance is as short as it is in the Zr analogue, in spite of a metal-metal separation which is longer by 0.28 angstrom. The generality of hydrogen bonding between M-OR and M-O(H)R groups when they are aligned parallel in a metal cluster is reviewed. 44 refs., 2 figs., 4 tabs

  4. Unique Structural and Nucleotide Exchange Features of the Rho1 GTPase of Entamoeba histolytica

    Energy Technology Data Exchange (ETDEWEB)

    Bosch, Dustin E.; Wittchen, Erika S.; Qiu, Connie; Burridge, Keith; Siderovski, David P. (UNC)

    2012-08-10

    The single-celled human parasite Entamoeba histolytica possesses a dynamic actin cytoskeleton vital for its intestinal and systemic pathogenicity. The E. histolytica genome encodes several Rho family GTPases known to regulate cytoskeletal dynamics. EhRho1, the first family member identified, was reported to be insensitive to the Rho GTPase-specific Clostridium botulinum C3 exoenzyme, raising the possibility that it may be a misclassified Ras family member. Here, we report the crystal structures of EhRho1 in both active and inactive states. EhRho1 is activated by a conserved switch mechanism, but diverges from mammalian Rho GTPases in lacking a signature Rho insert helix. EhRho1 engages a homolog of mDia, EhFormin1, suggesting a role in mediating serum-stimulated actin reorganization and microtubule formation during mitosis. EhRho1, but not a constitutively active mutant, interacts with a newly identified EhRhoGDI in a prenylation-dependent manner. Furthermore, constitutively active EhRho1 induces actin stress fiber formation in mammalian fibroblasts, thereby identifying it as a functional Rho family GTPase. EhRho1 exhibits a fast rate of nucleotide exchange relative to mammalian Rho GTPases due to a distinctive switch one isoleucine residue reminiscent of the constitutively active F28L mutation in human Cdc42, which for the latter protein, is sufficient for cellular transformation. Nonconserved, nucleotide-interacting residues within EhRho1, revealed by the crystal structure models, were observed to contribute a moderating influence on fast spontaneous nucleotide exchange. Collectively, these observations indicate that EhRho1 is a bona fide member of the Rho GTPase family, albeit with unique structural and functional aspects compared with mammalian Rho GTPases.

  5. Features of structural function of selenito group in uranyl complexes with neutral ligands

    International Nuclear Information System (INIS)

    The structures of three uranyl selenitocomplexes are determined. All the crystals are monoclinic, in [UO2SeO3x2CO(NH2)2] (1) a=9.427 (2), b=13.855 (2), c=6.556 (2) A, #betta#=105.35 (4) deg, sp. gr. P21/m, Z=2, R=0.C36 for 1573 reflections; in [UO2(HSeO3)2H2O] (2) a=6.354 (1), b=12.578 (2), c=9.972 (2) A, #betta#=82.35 (1), sp. gr. A2/a, Z=4, R=0.046 for 975 reflections, and in [UO2SeO3CH2(CONH2)2] (3) a=8.935 (2), b=10.698 (2), c=10.037 (2) A, #betta#=90.37 (3) deg, ph. gr. P21/n, Z=4, R=0.036 for 1756 reflections. Uranium polyhedron in 1-3 has a pentagonal-bipyranidal structure, axial positions are taken by O-atoms of the uranyl group (U-O 1.76-1.79 (1) A, selenite group and the neutral ligand are coordinated in the equatorial plane. In all the compounds the motives of structures are different: in 1 - the bands are on the basis of tridentate bridge cyclic SeO32--groups (U-O bridge 2.35 (1) A, U-Osub(br-cycle) 2.45 (1) A), in 2-bands are on the basis of bridge hydroselenite groups (U-O 2.36-2.38 (1) A), and in 3-layers are on the basis of tridentate bridge SeO32--groups (U-O 2.316-2.346 (8) A). The comparison is made with uranyl phosphite complexes

  6. STRUCTURAL FEATURE AND EXCHANGE KINETICS OF CARBOXYLATED POLYPROPYLENE ION EXCHANGE RESIN

    Institute of Scientific and Technical Information of China (English)

    WU Chinyung; YANG Chaoshiung; YANG Chong

    1987-01-01

    The present article deals with the exchange process of bivalent metal ions, such as Zn2 +, Cd2 + and Hg2+, etc., taken up by non-crosslinked carboxylated polypropylene (CPP) resin. The control factor of the exchange rate deduced from the kinetic data is governed basically by the chemical reaction rather than the mass transfer effect particle diffusion and/or liquid film diffusion. In solution, all the graft chains in the outer shell ofa CPP resin could form a "quasi-macromolecular solution" domain. This opinion further demonstrates the structural pattern of CPP resin proposed in earlier paper[1].

  7. On the statistics and features of turbulent structures in RFX-mod

    Science.gov (United States)

    Vianello, N.; Spolaore, M.; Agostini, M.; Cavazzana, R.; De Masi, G.; Martines, E.; Momo, B.; Scarin, P.; Spagnolo, S.; Zuin, M.

    2016-04-01

    An extensive statistical characterization of the electromagnetic turbulence in the edge region of RFX-mod, operated as a tokamak and as a Reversed Field Pinch, is presented. Striking similarity are observed on the intermittent character of the electrostatic turbulence between the two configurations whereas the difference between magnetic turbulence is likely to be imputed to the different β value of the two configurations. Blobs are characterized in terms of their spatial structure, the associated enstrophy and energy and the mechanism of energy and enstrophy transfer between intermittent fluctuation at different scales is addressed.

  8. Altered features in the secondary structure of Vicia faba 5.8s rRNA.

    OpenAIRE

    Nazar, R N; Wildeman, A G

    1981-01-01

    We have re-examined the nucleotide sequence of Vicia faba (broad bean) 5.8S rRNA using partial chemical degradation and a new approach to high temperature (65-80 degrees C) sequencing gels. The results indicate that the secondary structure was not completely disrupted in previous studies (Tanaka, Y., Dyer, T.A. and Brownlee, G.G. (1980) Nucleic Acid Res. 8, 1259-1272) and explain ambiguities between the nucleotide sequence and T1 ribonuclease digests. Despite this revision, estimates in the s...

  9. Аssociation of spectral closeness of flicker-noise parameters with features of underlying structure of system

    Directory of Open Access Journals (Sweden)

    Kolodiy Z. A.

    2009-02-01

    Full Text Available The results of computer design of chaotic motion of elementary particles are resulted in a flat rectangle which can be put in accordance to a pellicle resistor with the electrons of conductivity. The analysis of spectral closeness of chaotic motion shows that one of parameters of flicker-noise depends only on the amount of elementary particles and middle rate of their movement. The second parameter of flicker-noise (time of relaxation depends on the features of underlying structure of the system. It can be used for prognostication of reliability as separate elements of electronics so apparatus as a whole on the measured level of their flicker-noise.

  10. Mapping the Structural and Dynamical Features of Multiple p53 DNA Binding Domains: Insights into Loop 1 Intrinsic Dynamics

    OpenAIRE

    Lukman, Suryani; Lane, David P; Verma, Chandra S.

    2013-01-01

    The transcription factor p53 regulates cellular integrity in response to stress. p53 is mutated in more than half of cancerous cells, with a majority of the mutations localized to the DNA binding domain (DBD). In order to map the structural and dynamical features of the DBD, we carried out multiple copy molecular dynamics simulations (totaling 0.8 μs). Simulations show the loop 1 to be the most dynamic element among the DNA-contacting loops (loops 1-3). Loop 1 occupies two major conformationa...

  11. Floristic and structural features of the coastal foreland vegetation south of the Berg River, western Cape Province, South Africa

    Directory of Open Access Journals (Sweden)

    C. Boucher

    1983-12-01

    Full Text Available Floristic and structural features of the three main vegetation types found in the coastal foreland of the western Cape Province, south of the Berg River, are outlined. Coastal Renosterveld. which occupies 6% of its former extent, is the most threatened type, followed by Coastal Fynbos (14% and West Coast Strandveld (41%. Coastal Renosterveld is closely related to Mountain Fynbos vegetation found on clay-rich soils together with West Coast Strandveld inclusions in specific habitats. Coastal Renosterveld is the product of recent regular disturbance by a short interval burning regime and overgrazing.

  12. Chemical composition and structural features of the macromolecular components of plantation Acacia mangium wood.

    Science.gov (United States)

    Pinto, Paula C; Evtuguin, Dmitry V; Pascoal Neto, Carlos

    2005-10-01

    The wood of Acacia mangium, a prominent fast-growing plantation species used in the pulp-and-paper industry and, so far, poorly investigated for its chemical structure, was submitted to a detailed characterization of its main macromolecular components. Lignin (28% wood weight) isolated by mild acidolysis and characterized by permanganate oxidation, 1H and 13C NMR, and GPC, showed a very low content of syringylpropane-derived units (S:G:H of 48:49:3), a high degree of condensation, a low content of beta-O-4 ( approximately 0.40-0.43 per C6) structures, and a Mw of 2230. Glucuronoxylan (14% wood weight) isolated by alkaline (KOH) or by dimethyl sulfoxide extraction was characterized by methylation analysis, 1H NMR, and GPC. About 10% of the xylopyranose (Xylp) units constituting the linear backbone were substituted at O-2 with 4-O-methylglucuronic acid residues. Almost half of the Xylp units (45%) were O-2 (18%), O-3 (24%) or O-2,3 (3%) acetylated. X-ray diffraction analysis of cellulose (46% wood weight), isolated according to the Kürschner-Hoffer method, showed a degree of crystallinity of 67.6%. PMID:16190642

  13. Extracting structural features of rat sciatic nerve using polarization-sensitive spectral domain optical coherence tomography

    Science.gov (United States)

    Islam, M. Shahidul; Oliveira, Michael C.; Wang, Yan; Henry, Francis P.; Randolph, Mark A.; Park, B. Hyle; de Boer, Johannes F.

    2012-05-01

    We present spectral domain polarization-sensitive optical coherence tomography (SD PS-OCT) imaging of peripheral nerves. Structural and polarization-sensitive OCT imaging of uninjured rat sciatic nerves was evaluated both qualitatively and quantitatively. OCT and its functional extension, PS-OCT, were used to image sciatic nerve structure with clear delineation of the nerve boundaries to muscle and adipose tissues. A long-known optical effect, bands of Fontana, was also observed. Postprocessing analysis of these images provided significant quantitative information, such as epineurium thickness, estimates of extinction coefficient and birefringence of nerve and muscle tissue, frequency of bands of Fontana at different stretch levels of nerve, and change in average birefringence of nerve under stretched condition. We demonstrate that PS-OCT combined with regular-intensity OCT (compared with OCT alone) allows for a clearer determination of the inner and outer boundaries of the epineurium and distinction of nerve and muscle based on their birefringence pattern. PS-OCT measurements on normal nerves show that the technique is promising for studies on peripheral nerve injury.

  14. Thermal stability of the structural features in the superhydrophobic boehmite films on austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Xiaoxue [Department of Materials Science, Tampere University of Technology, P.O. Box 589, FI-33101 Tampere (Finland)], E-mail: xiaoxue.zhang@tut.fi; Honkanen, Mari [Department of Materials Science, Tampere University of Technology, P.O. Box 589, FI-33101 Tampere (Finland); Jaern, Mikael; Peltonen, Jouko [Department of Physical Chemistry, Abo Akademi University, Porthaninkatu 3-5, FI-20500 Turku (Finland); Pore, Viljami [Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014 Helsinki (Finland); Levaenen, Erkki; Maentylae, Tapio [Department of Materials Science, Tampere University of Technology, P.O. Box 589, FI-33101 Tampere (Finland)

    2008-06-15

    Boehmite thin film with 50-100 nm surface flake structure has been synthesized on AISI 316 type austenitic stainless steel by immersing boehmite gel film into boiling water. When further coated with hydrolyzed (heptadecafluoro-1,1,2,2-tetrahydrodecyl) trimethoxysilane (FAS), the boehmite film becomes superhydrophobic with a contact angle for water of 152 deg. The superhydrophobic property results from both the nanoscale surface flake structure and the low surface energy of the FAS top layer. The topography of such film was revealed by atomic force microscope (AFM) and a set of roughness parameters of such film was discussed. The degradation of superhydrophobicity of the surface was studied as a function of the heat-treatment temperatures. Below 600 deg. C, the surface remained to be superhydrophobic with the FAS top layer. Above 700 deg. C, the surface was not superhydrophobic anymore due to a gradual loss in surface roughness which was revealed by field emission scanning electron microscope (FESEM). A phase change from boehmite to {gamma}-Al{sub 2}O{sub 3} occurred during the heat-treatments from 700 to 900 deg. C which was studied by the selected area electron diffraction (SAED) patterns from the transmission electron microscope (TEM) measurement.

  15. Thermal stability of the structural features in the superhydrophobic boehmite films on austenitic stainless steels

    International Nuclear Information System (INIS)

    Boehmite thin film with 50-100 nm surface flake structure has been synthesized on AISI 316 type austenitic stainless steel by immersing boehmite gel film into boiling water. When further coated with hydrolyzed (heptadecafluoro-1,1,2,2-tetrahydrodecyl) trimethoxysilane (FAS), the boehmite film becomes superhydrophobic with a contact angle for water of 152 deg. The superhydrophobic property results from both the nanoscale surface flake structure and the low surface energy of the FAS top layer. The topography of such film was revealed by atomic force microscope (AFM) and a set of roughness parameters of such film was discussed. The degradation of superhydrophobicity of the surface was studied as a function of the heat-treatment temperatures. Below 600 deg. C, the surface remained to be superhydrophobic with the FAS top layer. Above 700 deg. C, the surface was not superhydrophobic anymore due to a gradual loss in surface roughness which was revealed by field emission scanning electron microscope (FESEM). A phase change from boehmite to γ-Al2O3 occurred during the heat-treatments from 700 to 900 deg. C which was studied by the selected area electron diffraction (SAED) patterns from the transmission electron microscope (TEM) measurement

  16. Influence of structural features of carrageenan on the formation of polyelectrolyte complexes with chitosan.

    Science.gov (United States)

    Volod'ko, A V; Davydova, V N; Glazunov, V P; Likhatskaya, G N; Yermak, I M

    2016-03-01

    The polyelectrolyte complexes (PEC) of carrageenans (CG)-κ-, κ/β-, λ-and x-CG with chitosan were obtained. The formation of PEC was detected by Fourier-transform infrared (FTIR) spectroscopy and by centrifugation in a Percoll gradient. The influence of the structural peculiarities of CG on its interaction with chitosan was studied. The results of centrifugation showed that x-CG with a high degree of sulphation (SD) was completely bound to chitosan, unlike low SD κ-CG and κ/β-CG. Binding constant values showed there was a high affinity of CG for chitosan. CG with flexible macromolecule conformation and high SD exhibited the greatest binding affinity for chitosan. The full-atomic 3D-structures of the PEC κ-CG: chitosan in solution have been obtained by the experiments in silico for the first time. The amino groups of chitosan make the largest contribution to the energy of the complex formation by means of hydrogen and ionic bonds. The most probable complexes have stoichiometries of 1:1 and 1:1.5. PMID:26712704

  17. Synthesis and structural features of resorcinol-formaldehyde resin chars containing nickel nanoparticles

    Science.gov (United States)

    Galaburda, M. V.; Bogatyrov, V. M.; Skubiszewska-Zięba, J.; Oranska, O. I.; Sternik, D.; Gun'ko, V. M.

    2016-01-01

    A series of meso- and microporous carbons containing magnetic Ni nanoparticles (Ni/C) with a variety of Ni loadings were synthesized by a simple one-pot procedure through carbonization of resorcinol-formaldehyde polymers containing various amounts of nickel(II) acetate. Such composite materials were characterized by N2 sorption, Raman spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and Transmission electron microscope (TEM). The XRD patterns reveal peaks corresponding to face centered cubic nickel with the average size of crystallites of 17-18 nm. SEM and TEM results reveal that the formation of the nanoparticles took place mainly in the carbon spheres (1-2 μm in size) and on the outer surface as well. The as-prepared composites are characterized by a core-shell structure with well-crystallized graphitic shells about 8-15 nm in thickness. The Raman spectra show that Ni content influences the structure of the carbon. It was also shown that the morphology (particle shape and sizes) and porosity (pore volume and pore size distribution) of the chars are strongly dependent on water and nickel contents in the blends. One of the applications of Ni/C was demonstrated as a magnetically separable adsorbent.

  18. Mapping the mutual information network of enzymatic families in the protein structure to unveil functional features.

    Science.gov (United States)

    Aguilar, Daniel; Oliva, Baldo; Marino Buslje, Cristina

    2012-01-01

    Amino acids committed to a particular function correlate tightly along evolution and tend to form clusters in the 3D structure of the protein. Consequently, a protein can be seen as a network of co-evolving clusters of residues. The goal of this work is two-fold: first, we have combined mutual information and structural data to describe the amino acid networks within a protein and their interactions. Second, we have investigated how this information can be used to improve methods of prediction of functional residues by reducing the search space. As a main result, we found that clusters of co-evolving residues related to the catalytic site of an enzyme have distinguishable topological properties in the network. We also observed that these clusters usually evolve independently, which could be related to a fail-safe mechanism. Finally, we discovered a significant enrichment of functional residues (e.g. metal binding, susceptibility to detrimental mutations) in the clusters, which could be the foundation of new prediction tools. PMID:22848494

  19. Novel structural and regulatory features of rhoptry secretory kinases in Toxoplasma gondii

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Wei; Wernimont, Amy; Tang, Keliang; Taylor, Sonya; Lunin, Vladimir; Schapira, Matthieu; Fentress, Sarah; Hui, Raymond; Sibley, L. David; (Toronto); (WU-MED)

    2009-09-29

    Serine/threonine kinases secreted from rhoptry organelles constitute important virulence factors of Toxoplasma gondii. Rhoptry kinases are highly divergent and their structures and regulatory mechanism are hitherto unknown. Here, we report the X-ray crystal structures of two related pseudokinases named ROP2 and ROP8, which differ primarily in their substrate-binding site. ROP kinases contain a typical bilobate kinase fold and a novel N-terminal extension that both stabilizes the N-lobe and provides a unique means of regulation. Although ROP2 and ROP8 were catalytically inactive, they provided a template for homology modelling of the active kinase ROP18, a major virulence determinant of T. gondii. Autophosphorylation of key residues in the N-terminal extension resulted in ROP18 activation, which in turn phosphorylated ROP2 and ROP8. Mutagenesis and mass spectrometry experiments revealed that ROP18 was maximally activated when this phosphorylated N-terminus relieved autoinhibition resulting from extension of aliphatic side chains into the ATP-binding pocket. This novel means of regulation governs ROP kinases implicated in parasite virulence.

  20. Hydroxycinnamic acid bound arabinoxylans from millet brans-structural features and antioxidant activity.

    Science.gov (United States)

    Bijalwan, Vandana; Ali, Usman; Kesarwani, Atul Kumar; Yadav, Kamalendra; Mazumder, Koushik

    2016-07-01

    Hydroxycinnamic acid bound arabinoxylans (HCA-AXs) were extracted from brans of five Indian millet varieties and response surface methodology was used to optimize the extraction conditions. The optimal condition to obtain highest yield of millet HCA-AXs was determined as follows: time 61min, temperature 66°C, ratio of solvent to sample 12ml/g. Linkage analysis indicated that hydroxycinnamic acid bound arabinoxylan from kodo millet (KM-HCA-AX) contained comparatively low branched arabinoxylan consisting of 14.6% mono-substituted, 1.2% di-substituted and 41.2% un-substituted Xylp residues. The HPLC analysis of millet HCA-AXs showed significant variation in the content of three major bound hydroxycinnamic acids (caffeic, p-coumaric and ferulic acid). The antioxidant activity of millet HCA-AXs were evaluated using three in vitro assay methods (DPPH, FRAP and β-carotene linoleate emulsion assays) which suggested both phenolic acid composition and structural characteristics of arabinoxylans could be correlated to their antioxidant potential, the detailed structural analysis revealed that low substituted KM-HCA-AX exhibited relatively higher antioxidant activity compared to other medium and highly substituted HCA-AXs from finger (FM), proso (PM), barnyard (BM) and foxtail (FOXM) millet. PMID:27050114

  1. A non-intuitive design of a cyclic decapeptide library with unique backbone structural features.

    Science.gov (United States)

    Paul, P K C

    2003-12-01

    An analysis of hydrogen bonding patterns of cyclic decapeptide (CDP) beta-sheet structures has resulted in a 'non-intuitive' design of cyclic decapeptides wherein their beta-turns and residue positions can be fixed by choosing 2 of the 10 residues, i.e. positions i and i+4, to be Prolines or N-substituted residues. This sequence relationship between the two Pro or N-substituted residues is shown to uniquely define the conformation of the CDP. Furthermore, this design of the 2 beta-turn, beta-sheet CDP structure is expected to be characterised by residues disposed in an exclusive fashion in which four residues are on one side of the ring, two on the other and the four corner residues in the beta-turn are in the plane of the ring. This opens up the possibility of fine-tuning the four residues facing one way and /or the two residues facing the other way such that a library containing a myriad of chemically diverse systems could be obtained. The design process along with the molecular modelling of specific CDP-s and the building of a CDP library are discussed in detail. PMID:14683511

  2. X-Ray Crystal Structure of the Full Length Human Chitotriosidase (CHIT1) Reveals Features of Its Chitin Binding Domain

    Science.gov (United States)

    Fadel, Firas; Zhao, Yuguang; Cousido-Siah, Alexandra; Ruiz, Francesc X.; Mitschler, André; Podjarny, Alberto

    2016-01-01

    Chitinases are enzymes that catalyze the hydrolysis of chitin. Human chitotriosidase (CHIT1) is one of the two active human chitinases, involved in the innate immune response and highly expressed in a variety of diseases. CHIT1 is composed of a catalytic domain linked by a hinge to its chitin binding domain (ChBD). This latter domain belongs to the carbohydrate-binding module family 14 (CBM14 family) and facilitates binding to chitin. So far, the available crystal structures of the human chitinase CHIT1 and the Acidic Mammalian Chitinase (AMCase) comprise only their catalytic domain. Here, we report a crystallization strategy combining cross-seeding and micro-seeding cycles which allowed us to obtain the first crystal structure of the full length CHIT1 (CHIT1-FL) at 1.95 Å resolution. The CHIT1 chitin binding domain (ChBDCHIT1) structure shows a distorted β-sandwich 3D fold, typical of CBM14 family members. Accordingly, ChBDCHIT1 presents six conserved cysteine residues forming three disulfide bridges and several exposed aromatic residues that probably are involved in chitin binding, including the highly conserved Trp465 in a surface- exposed conformation. Furthermore, ChBDCHIT1 presents a positively charged surface which may be involved in electrostatic interactions. Our data highlight the strong structural conservation of CBM14 family members and uncover the structural similarity between the human ChBDCHIT1, tachycitin and house mite dust allergens. Overall, our new CHIT1-FL structure, determined with an adapted crystallization approach, is one of the few complete bi-modular chitinase structures available and reveals the structural features of a human CBM14 domain. PMID:27111557

  3. Homochiral Cu(II) and Ni(II) malates with tunable structural features

    International Nuclear Information System (INIS)

    Four new homochiral metal–organic frameworks (MOFs) based on S-malate anions and N-donor linkers of different length have been prepared under solvothermal conditions. [Cu(mal)(bpy)]·H2O (1), [Cu(mal)(bpe)]·2H2O (2), [Ni(mal)(bpy)]·1.3CH3OH (3) and [Ni(mal)(bpe)]·4H2O (4) (mal=S-malate, bpy=4,4′-bipyridil, bpe=trans-1,2-bis(4-pyridyl)ethylene) were characterized by a number of analytical methods including powder X-ray diffraction, elemental, thermogravimetric analyses, IR spectroscopy. Compounds 1–3 were structurally characterized by X-ray crystallography. The absence of the chiral ligand racemization under synthetic conditions was unambiguously confirmed by polarimetry experiments. Compounds 1 and 2 contain metal-malate layered motives, connected by N-donor linkers and contribute to the family of isoreticular Cu(II) malates and tartrates [Cu(mal)L] and [Cu(tart)L], (tart=tartrate; L=ditopic rigid organic ligand). The Ni-based compounds 3 and 4 share 1D chiral (Ni(mal)) motives and possess novel type of the chiral framework, previously unknown for chiral carboxylates. The linear N-donor linkers connect these chiral chains, thus controlling the channel diameter and guest accessible volume of the homochiral structure, which exceeds 60 %. - Graphical abstract: Four new homochiral metal–organic frameworks are built from Ni2+ or Cu2+ cations, S-malate anions and N-donor linkers of different length, which controls the size of pores and guest accessible volume of the homochiral structure. Display Omitted - Highlights: • Four new homohiral metal–organic frameworks based on Ni2+ and Cu2+. • Cu(II)–malate layers and Ni(II)–malate chains are connected by N-donor linkers. • N-donor linkers of different length control the size of pores

  4. Structural and Morphological Features of Acid-Bearing Polymers for PEM Fuel Cells

    DEFF Research Database (Denmark)

    Yang, Yunsong; Siu, Ana; Peckham, Timothy J.;

    2008-01-01

    Chemical structure, polymer microstructure, sequence distribution, and morphology of acid-bearing polymers are important factors in the design of polymer electrolyte membranes (PEMs) for fuel cells. The roles of ion aggregation and phase separation in vinylic- and aromatic-based polymers in proton...... conductivity and water transport are described. The formation, dimensions, and connectivity of ionic pathways are consistently found to play an important role in determining the physicochemical properties of PEMs. For polymers that possess low water content, phase separation and ionic channel formation...... significantly enhance the transport of water and protons. For membranes that contain a high content of water, phase separation is less influential. Continuity of ionic aggregates is influential on the diffusion of water and electroosmotic drag within a membrane. A balance of these properties must be considered...

  5. The foreland thrust belt in northwestern margin of Yangtze platform and the coalfield structure feature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, D.; Jing, Y. [Guangdon Bureau of Coal Geology (China)

    1997-12-01

    The accumulation and occurrence of coal resources in Yangtze platform and its northwest margin are controlled by the formation and evolution of foreland thrust belt in its northwest margin. The foreland thrust belt can be divided into root zone, middle zone and front zone. There is no coal accumulation root zone, the industrial coal resources are occurred in middle zone, and the coal resources occurred in the front zone are buried deeply. The coalfield structure deformation which is characterized by the imbricate thrusts, duplex thrust, parallel fold, inclined fold, klippen, thrust sheets and fault block, is resulted from the compressive stress of foreland thrust belt. The formation of the thrust belt is the result of long-time evolution of Tethys domain, in which the plates had collided three times along three sutures. 2 refs., 5 figs.

  6. [Mobile genetic element MDG4 (gypsy) in Drosophila melanogaster. Features of structure and regulation of transposition].

    Science.gov (United States)

    Kusulidu, L K; Karpova, N N; Razorenova, O V; Glukhov, I A; Kim, A I; Liubomirskaia, N V; Il'in, Iu V

    2001-12-01

    Distribution of two structural functional variants of the MDG4 (gypsy) mobile genetic element was examined in 44 strains of Drosophila melanogaster. The results obtained suggest that less transpositionally active MDG4 variant is more ancient component of the Drosophila genome. Using Southern blotting, five strains characterized by increased copy number of MDG4 with significant prevalence of the active variant over the less active one were selected for further analysis. Genetic analysis of these strains led to the suggestion that some of them carry factors that mobilize MDG4 independently from the cellular flamenco gene known to be responsible for transposition of this element. Other strains probably contained a suppressor of the flam- mutant allele causing active transpositions of the MDG4. Thus, the material for studying poorly examined relationships between the retrovirus and the host cell genome was obtained. PMID:11785284

  7. Features of the electronic structure of the ternary superconductors RRh4B4 (R = Y, Lu)

    International Nuclear Information System (INIS)

    First-principles calculations of the electronic structure and a number of thermodynamical characteristics are performed for the ternary superconducting systems RRh4B4 (R = Y, Lu) in the normal state. The analysis of electronic states and their interactions responsible for superconducting and magnetic properties of the investigated systems is carried out. It is found that in YRh4B4 and LuRh4B4 compounds the Fermi level is situated in close proximity to a peak in the density of electronic states, and about 1 eV above of the pseudo-gap in the electronic spectrum. The existence of a number of groups of quasi-degenerate electronic states with a small effective mass near the Fermi level is revealed. These states can be the origin of a substantial conduction electrons diamagnetic contribution to the magnetic susceptibility, and can provide strong temperature dependences of the susceptibility in the rhodium borides.

  8. Structural features of HNb3O8 nanosheets and their catalytic performance in toluene nitration

    Science.gov (United States)

    Zhou, Pan; Li, Qingjie; He, Jie; Li, Dewei; Li, Zhong

    2015-11-01

    HNb3O8 nanosheet aggregates ( e-HNb3O8) were prepared by exfoliation and aggregation of layered HNb3O8, which was obtained by protonation of KNb3O8. Especially, in this research, KNb3O8 was synthesized through a novel polymerized complex method (PC) from niobium oxalate. The as-prepared samples were characterized by SEM, HRTEM, XRD, LRS, NH3-TPD, and FT-IR methods. The toluene nitration was used to evaluate the acid catalytic performance of HNb3O8 and e-HNb3O8 samples. The catalytic activity in toluene nitration was related to the structure and acidity of the as-prepared samples. The results show that e-HNb3O8 has a higher specific surface area, stronger acidity and better para-selectivity than the precursor HNb3O8.

  9. Stabilized borata-alkene formation: structural features, reactions and the role of the counter cation.

    Science.gov (United States)

    Kohrt, Sonja; Dachwitz, Steffen; Daniliuc, Constantin G; Kehr, Gerald; Erker, Gerhard

    2015-12-28

    Dimethylbenzofulvene adds Piers' borane [HB(C6F5)2] at the indene double bond to give a mixture of regioisomeric boranes 8a,b. Subsequent isomerization under equilibrium conditions gives the isopropyl substituted 1H and 3H borylindenes 10a,b. Their treatment with the bulky LiTMP base under frustrated Lewis pair conditions resulted in a clean deprotonation reaction to give the borata-alkene 14. Its X-ray crystal structure analysis indicated a pronounced B[double bond, length as m-dash]C double bond character and thus a borata-benzofulvene description. The borata-alkene underwent (probably stepwise) [4 + 2] cycloaddition reactions with chalcone derivatives and a formal [6 + 2] cycloaddition with phenylmethylketene. Many products and derivatives were characterized by X-ray diffraction. PMID:26584629

  10. Effect of several structural features in coal on its tendency to reduce

    Energy Technology Data Exchange (ETDEWEB)

    Grigor' eva, E.A.; Bakirova, E.V.; Lesnikova, E.B.; Larina, N.K.; Zharova, M.N.; Dzhalyabova, L.V.

    1981-07-01

    Relationship between the tendency of coal to be reduced and the nature and quantity of the ether and organo-mineral bonds in the structure of coals is studied. The purpose of the study was to determine the intensity of the reaction during coal hydrogenation. Sodium borhydrate was used as a reducing agent because of its selective action on carbonyl groups and because of the possibility of describing the nature of hydrolyzed bonds in coal which form carbonyl groups. By hydrolysis of hard and brown coals and subsequent selective reduction, the effect of various carbonyl groups and organo-mineral bonds formed as a result of the destruction of ether groupings and carbon to carbon cross linkages were demonstrated. (17 refs.) (In Russian)

  11. Comparison of Algorithms for Prediction of Protein Structural Features from Evolutionary Data.

    Science.gov (United States)

    Bywater, Robert P

    2016-01-01

    Proteins have many functions and predicting these is still one of the major challenges in theoretical biophysics and bioinformatics. Foremost amongst these functions is the need to fold correctly thereby allowing the other genetically dictated tasks that the protein has to carry out to proceed efficiently. In this work, some earlier algorithms for predicting protein domain folds are revisited and they are compared with more recently developed methods. In dealing with intractable problems such as fold prediction, when different algorithms show convergence onto the same result there is every reason to take all algorithms into account such that a consensus result can be arrived at. In this work it is shown that the application of different algorithms in protein structure prediction leads to results that do not converge as such but rather they collude in a striking and useful way that has never been considered before. PMID:26963911

  12. Microscopic and mesoscopic structural features of an activated carbon sample, prepared from sorghum via activation by phosphoric acid

    International Nuclear Information System (INIS)

    Graphical abstract: Display Omitted Highlights: ► Preparation of a new activated carbon sample from sorghum. ► Characterization by adsorption/desorption methods. ► Determination of the structure by synchrotron X-ray diffraction. ► The sample is amorphous and contains distorted graphene fragments. ► A characteristic nanoscale distance is established from the radial distribution function. -- Abstract: An acidic chemical activation procedure has been used for preparing activated carbon with a surface area exceeding 1000 m2/g from sorghum. In order to reveal structural features, synchrotron X-ray diffraction measurements have been performed. The structure of the material has been characterized by the total scattering structure factor and the radial distribution function describing short-range arrangement of atoms at distances of the order of a few atomic diameters as well as correlations at a longer scale, of the order of nanometers. The atomic arrangement has been found to be consistent with that of amorphous graphite-like carbon. As far as the mesoscopic structure is concerned, the presence of a characteristic distance is suggested on the basis of the clear nanometer scale oscillations of the radial distribution function, which distance may be assigned as the mesopore size in the material. It is suggested that the approach devized here may later be applied routinely for other activated carbon samples, too, for characterizing atomic and nanoscale order simultaneously.

  13. Temperature and Magnetic Field Driven Modifications in the I-V Features of Gold-DNA-Gold Structure

    Directory of Open Access Journals (Sweden)

    Nadia Mahmoudi Khatir

    2014-10-01

    Full Text Available The fabrication of Metal-DNA-Metal (MDM structure-based high sensitivity sensors from DNA micro-and nanoarray strands is a key issue in their development. The tunable semiconducting response of DNA in the presence of external electromagnetic and thermal fields is a gift for molecular electronics. The impact of temperatures (25–55 °C and magnetic fields (0–1200 mT on the current-voltage (I-V features of Au-DNA-Au (GDG structures with an optimum gap of 10 μm is reported. The I-V characteristics acquired in the presence and absence of magnetic fields demonstrated the semiconducting diode nature of DNA in GDG structures with high temperature sensitivity. The saturation current in the absence of magnetic field was found to increase sharply with the increase of temperature up to 45 °C and decrease rapidly thereafter. This increase was attributed to the temperature-assisted conversion of double bonds into single bond in DNA structures. Furthermore, the potential barrier height and Richardson constant for all the structures increased steadily with the increase of external magnetic field irrespective of temperature variations. Our observation on magnetic field and temperature sensitivity of I-V response in GDG sandwiches may contribute towards the development of DNA-based magnetic sensors.

  14. Structural features of silver-doped phosphate glasses in zone of femtosecond laser-induced modification

    International Nuclear Information System (INIS)

    Femtosecond (fs) laser writing of two-dimensional microstructures (waveguides) is demonstrated in bulk phosphate glasses doped with silver ions. Silver-content phosphate and silver-content niobium–phosphate glasses with high concentration of silver oxide 55 mol% were used as samples for fs laser writing. The chemical network structure of the synthesized samples is analyzed through Raman spectroscopy and was found to be strongly sensitive to Nb incorporation. It was found that the direct laser writing process enables not only reorganization of glass network, but also formation of color centers and silver nanoparticles that are revealed in appearance of luminescence signal and plasmon absorption. The process of NPs' formation is more efficient for Nb-phosphate glass, while color centers are preferably formed in phosphate glass. - Graphical abstract: Formation of silver NPs on the surface of 0.5Ag2O–0.4P2O5–0,1Nb2O5 glass induced by CW laser irradiation. - Highlights: • The structure of 0.5Ag2O–0.1Nb2O5–0.4P2O5 and 0.55Ag2O–0.45P2O5 glasses was investigated by Raman spectroscopy. • Fs laser writing induces formation of silver NPs in investigated glasses. • Surface plasmon resonance in the absorption spectra confirms the formation of NP. • The possibility of CW laser induced formation of silver NPs on the surface of sample with niobium is shown

  15. Features of highly structured equatorial plasma irregularities deduced from CHAMP observations

    Directory of Open Access Journals (Sweden)

    C. Xiong

    2012-08-01

    Full Text Available In this study five years of CHAMP (Challenging Mini-satellite Payload fluxgate magnetometer (FGM data is used to investigate the characteristics of Equatorial Plasma Bubbles (EPBs. We filtered the FGM data by using band-passes with four different cut-off periods to get the EPBs with different maximum spatial scale sizes in the meridional plane ranging from 76–608 km. Associated with the EPB observations at about 400 km, the typical altitude of CHAMP during the year 2000–2005, we also investigate the post-sunset equatorial vertical plasma drift data from ROCSAT-1 (Republic of China Satellite 1. Since the height of the F-layer is highly correlated with the vertical plasma drift and solar flux, we sorted the ROCSAT-1 data into different groups by F10.7. From the integrated vertical drift we have estimated the post-sunset uplift of the ionosphere. By comparing the properties of EPB occurrence for different scale sizes with the global distribution of plasma vertical uplift, we have found that EPBs reaching higher altitudes are more structured than those which are sampled by CHAMP near the top side of the depleted fluxtube. Such a result is in accord with 3-D model simulations (Aveiro and Hysell, 2010. Small-scale EPB structures are observed by CHAMP when the irregularities reach apex heights of 800 km and more. Such events are encountered primarily in the Brazilian sector during the months around November, when the post-sunset vertical plasma drift is high.

  16. Structural features of silver-doped phosphate glasses in zone of femtosecond laser-induced modification

    Energy Technology Data Exchange (ETDEWEB)

    Vasileva, A.A., E-mail: anvsilv@gmail.com [Saint-Petersburg State University, Institute of Chemistry, Saint-Petersburg (Russian Federation); Nazarov, I.A. [Saint-Petersburg State University, Department of Physics, Saint-Petersburg (Russian Federation); Olshin, P.K.; Povolotskiy, A.V. [Saint-Petersburg State University, Institute of Chemistry, Saint-Petersburg (Russian Federation); Sokolov, I.A. [St.Petersburg State Polytechnical University, St.Petersburg (Russian Federation); LTD “AtomTjazhMash”, St.Petersburg (Russian Federation); Manshina, A.A. [Saint-Petersburg State University, Institute of Chemistry, Saint-Petersburg (Russian Federation)

    2015-10-15

    Femtosecond (fs) laser writing of two-dimensional microstructures (waveguides) is demonstrated in bulk phosphate glasses doped with silver ions. Silver-content phosphate and silver-content niobium–phosphate glasses with high concentration of silver oxide 55 mol% were used as samples for fs laser writing. The chemical network structure of the synthesized samples is analyzed through Raman spectroscopy and was found to be strongly sensitive to Nb incorporation. It was found that the direct laser writing process enables not only reorganization of glass network, but also formation of color centers and silver nanoparticles that are revealed in appearance of luminescence signal and plasmon absorption. The process of NPs' formation is more efficient for Nb-phosphate glass, while color centers are preferably formed in phosphate glass. - Graphical abstract: Formation of silver NPs on the surface of 0.5Ag{sub 2}O–0.4P{sub 2}O{sub 5}–0,1Nb{sub 2}O{sub 5} glass induced by CW laser irradiation. - Highlights: • The structure of 0.5Ag{sub 2}O–0.1Nb{sub 2}O{sub 5}–0.4P{sub 2}O{sub 5} and 0.55Ag{sub 2}O–0.45P{sub 2}O{sub 5} glasses was investigated by Raman spectroscopy. • Fs laser writing induces formation of silver NPs in investigated glasses. • Surface plasmon resonance in the absorption spectra confirms the formation of NP. • The possibility of CW laser induced formation of silver NPs on the surface of sample with niobium is shown.

  17. Investigation of the crystallization features, atomic structure, and microstructure of chromium-doped monticellite

    International Nuclear Information System (INIS)

    A series of Cr4+:CaMgSiO4 single crystals is grown using floating zone melting, and their microstructure, composition, and crystal structure are investigated. It is shown that regions with inclusions of second phases, such as forsterite, akermanite, MgO, and Ca4Mg2Si3O12, can form over the length of the sample. The composition of the single-phase regions of the single crystals varies from the stoichiometric monticellite CaMgSiO4 to the solid solution Ca(1-x)Mg(1+x)SiO4(x = 0.22). The Cr:(Ca0.88Mg0.12)MgSiO4 crystal is studied using X-ray diffraction. It is revealed that, in this case, the olivine-like orthorhombic crystal lattice is distorted to the monoclinic lattice with the parameters a = 6.3574(5) A, b = 4.8164(4) A, c = 11.0387(8) A, β = 90.30(1)o, Z = 4, V = 337.98 A3, and space group P21/c. In the monoclinic lattice, the M(1) position of the initial olivine structure is split into two nonequivalent positions with the center of symmetry, which are occupied only by Mg2+ cations with the average length of the Mg-O bond Rav = 2.128 A. The overstoichiometric Mg2+ cations partially replace Ca2+ cations (in the M(2) position of the orthorhombic prastructure) with the average bond length of 2.347 A in the [(Ca,Mg)-O6] octahedron. The average distance in SiO4 distorted tetrahedra is 1.541 A.

  18. Simulation and Experiments To Identify Factors Allowing Synthetic Control of Structural Features of Polymeric Nanoparticles.

    Science.gov (United States)

    Swope, William C; Rice, Julia E; Piunova, Victoria A; Carr, Amber C; Miller, Robert D; Sly, Joseph

    2016-08-01

    To develop a detailed picture of the microscopic structure of gelcore star polymers and to elucidate parameters of the synthetic process that might be exploited to control this structure, simulations of their synthesis were performed that were based on a particular synthetic approach. A range of results was observed from gelation at high reactant concentrations to the formation of various sizes and compositions of star polymers. Contrary to the prevailing experimental viewpoint, the simulations always suggest the production of a broad distribution of star polymer sizes. However, the GPC traces computed from simulation results are in good qualitative agreement with experiment. Topologically, the gelcore star polymers produced by simulation are not compact but, rather, sparse blobs loosely connected by filaments of linker when modeled in a good solvent. This is reflected in scaling relationships that relate polymer size (e.g., radius of gyration) and degree of polymerization. The arm-core composition is observed to be stoichiometric, strongly reflecting relative reactant concentrations during the synthesis. Reactions within star polymers that result in greater intramolecular cross-linking compete with those between star polymers that result in the production of larger star polymers from the joining of smaller ones. The balance in this competition can be controlled through the overall reactant concentration to limit and control resulting star polymer size. Therefore, the mean size, as well as the mean number of arms, can be controlled during synthesis by careful tuning of the overall ratio of the arm and linker reactant concentrations and the total reactant concentration. PMID:27385087

  19. Adjuvant properties of water extractable arabinoxylans with different structural features from wheat flour against model antigen ovalbumin.

    Science.gov (United States)

    Ma, Xiaoling; Wang, Lili; Wei, Hongyan; Huo, Xiaowei; Wang, Canhong; Liu, Dongyu; Zhou, Sumei; Cao, Li

    2016-03-16

    Despite the numerous benefits of AX on the immune system and gut bacteria, the potential adjuvant activity of WEAX on immune responses has not been adequately investigated. In the present study, three kinds of WEAX with different structural features were obtained and their adjuvant potential on the specific cellular and humoral immune responses in ovalbumin (OVA) immunized mice were assessed. Our data demonstrated that WEAX had potent effects on innate and acquired immune responses through up-regulating the NK cell activation and promoting the Th2 type immune response. Furthermore, this study also elucidated the possible relationship between the adjuvant activity of WEAX and the structure. Compared with the other characteristics of the WEAX, we found that the immunomodulatory activity may be related to their content of ferulic acid, and not to the molecular weight. PMID:26898981

  20. Structural features of metallic phase formed under the action of mechanical polishing of SmS polycrystalline specimens

    International Nuclear Information System (INIS)

    By means of X-ray diffractometry one investigated into structural features of a metallic phase film resulting from the balanced polishing of Sm1+xS semiconducting polycrystalline specimens within homogeneity range. One investigated into structural changes occurring in that case in semiconducting phase. On the basis of analysis of thickness dependence of metallic layers formed at the specimen surface on x one explains mechanism of influence of amount of samarium excessive ions on the transition parameters. The evaluations based on measurement results of dimensions of X-ray radiation coherent scattering ranges (CSR) in various composition specimens enabled to explain the reason of stabilization of SmS metallic modification upon termination of polishing. Occurrence and stabilization of metallic phase are associated with reduction and retaining of CSR dimensions