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Sample records for anodic stripping voltammetry

  1. Anodic Stripping Voltammetry: An Instrumental Analysis Experiment.

    Science.gov (United States)

    Wang, Joseph

    1983-01-01

    Describes an experiment designed to acquaint students with the theory and applications of anodic stripping voltammetry (ASV) as well as such ASV problems as contamination associated with trace analysis. The experimental procedure, instrumentation, and materials discussed are designed to minimize cost and keep procedures as simple as possible. (JM)

  2. Basic Principles of Anodic Stripping Voltammetry (ASV)

    OpenAIRE

    2012-01-01

    In this interactive exercise, the basic principles of Anodic Stripping Voltammetry are shown. Each step of the voltammetric process is described using simulated animations. This activity illustrates what takes place in the voltammetric cell when this technique is applied to the determination of cadmium as well as to the simultaneous determination of copper and cadmium.

  3. Digital simulation of anodic stripping voltammetry from thin film electrodes

    International Nuclear Information System (INIS)

    The anodic stripping voltammetry (ASV) is routinely applied to control of Cu(II) in heavy water in the primary cooling loop of the Nuclear Power Reactor. The anodic stripping voltammetry (ASV) is a very well-known technique in electroanalytical chemistry. However, due to the complexity of the phenomena, it is practised with the fundamentals of empiric considerations. A geometric model for the anodic stripping voltammetry (ASV) from thin film electrodes which can be calculated by explicit digital simulation method is proposed as a possibility of solving the electrochemically reversible, cuasi-reversible and irreversible reactions under linear potential scan and multiple potential scans. (Until now the analytical mathematical method was applied to reversible reactions). All the results are compared with analytical solutions and experimental results and it permits to conclude that the anodic stripping voltammetry (ASV) can be studied with the simplicity and potentialities of explicit digital simulation methods. (M.E.L.)

  4. Anodic stripping voltammetry of technetium alkaline media

    International Nuclear Information System (INIS)

    A method of direct determination of technetium in 0.1 M NaOH by anodic stripping voltametry at glassy carbon electrode has been elaborated. The peak height of anodic TcO2(OH)2 dissolution was found to be linearly dependent on preconcentration time, and the concentration of technetium in the range 5.0 * 10-8 -6 M. The detection limit for the Tc determination by ASV technique under study was found to be 5.0 * 10-8 M with standard deviation 5-7% (p2(OH)2 anodic dissolution peak current. Addition of 1.0* 10-6 M U(UI) to the sample solution was found to shift the peak of the TcO2(OH)2 100 mV towards negative direction and disturb the linearity of the calibration curve. Therefore; for a successful application of the developed ASV technique for Tc determination in the alkaline media, uranium should be removed from the analyte before determination

  5. Anodic stripping voltammetry – ASV for determination of heavy metals

    International Nuclear Information System (INIS)

    Although voltammetric methods presented a number of difficulties in its early stages, nowadays ''ASV'' anodic stripping voltammetry is considered one of the most sensitive electro-analytical and suitable for trace-level determination of many metals and compounds in environmental samples, clinical and industrial. Its sensitivity is attributed to the combination of a step of pre-concentration effective together with an electrochemical advanced measurement of accumulated analyte. This paper presents an overview of the voltammetry, which includes a group of electro-analytical methods, in them the information about analyte is obtained from measurements of the current flowing in an electrochemical cell when applied a potential difference to an suitable electrode system

  6. Topics in Chemical Instrumentation: CII. Automated Anodic Stripping Voltammetry.

    Science.gov (United States)

    Stock, John T.; Ewing, Galen W., Ed.

    1980-01-01

    Presents details of anodic stripping analysis (ASV) in college chemistry laboratory experiments. Provides block diagrams of the analyzer system, circuitry and power supplies of the automated stripping analyzer, and instructions for implementing microcomputer control of the ASV. (CS)

  7. Cloud Point Extraction for Electroanalysis: Anodic Stripping Voltammetry of Cadmium.

    Science.gov (United States)

    Rusinek, Cory A; Bange, Adam; Papautsky, Ian; Heineman, William R

    2015-06-16

    Cloud point extraction (CPE) is a well-established technique for the preconcentration of hydrophobic species from water without the use of organic solvents. Subsequent analysis is then typically performed via atomic absorption spectroscopy (AAS), UV-vis spectroscopy, or high performance liquid chromatography (HPLC). However, the suitability of CPE for electroanalytical methods such as stripping voltammetry has not been reported. We demonstrate the use of CPE for electroanalysis using the determination of cadmium (Cd(2+)) by anodic stripping voltammetry (ASV). Rather than using the chelating agents which are commonly used in CPE to form a hydrophobic, extractable metal complex, we used iodide and sulfuric acid to neutralize the charge on Cd(2+) to form an extractable ion pair. This offers good selectivity for Cd(2+) as no interferences were observed from other heavy metal ions. Triton X-114 was chosen as the surfactant for the extraction because its cloud point temperature is near room temperature (22-25 °C). Bare glassy carbon (GC), bismuth-coated glassy carbon (Bi-GC), and mercury-coated glassy carbon (Hg-GC) electrodes were compared for the CPE-ASV. A detection limit for Cd(2+) of 1.7 nM (0.2 ppb) was obtained with the Hg-GC electrode. ASV with CPE gave a 20x decrease (4.0 ppb) in the detection limit compared to ASV without CPE. The suitability of this procedure for the analysis of tap and river water samples was demonstrated. This simple, versatile, environmentally friendly, and cost-effective extraction method is potentially applicable to a wide variety of transition metals and organic compounds that are amenable to detection by electroanalytical methods.

  8. Manganese Detection with a Metal Catalyst Free Carbon Nanotube Electrode: Anodic versus Cathodic Stripping Voltammetry

    OpenAIRE

    Yue, Wei; Bange, Adam; Riehl, Bill L.; Riehl, Bonnie D.; Johnson, Jay M.; Papautsky, Ian; Heineman, William R.

    2012-01-01

    Anodic stripping voltammetry (ASV) and cathodic stripping voltammetry (CSV) were used to determine Mn concentration using metal catalyst free carbon nanotube (MCFCNT) electrodes and square wave stripping voltammetry (SWSV). The MCFCNTs are synthesized using a Carbo Thermal Carbide Conversion method which results in a material that does not contain residual transition metals. Detection limits of 120 nM and 93 nM were achieved for ASV and CSV, respectively, with a deposition time of 60 s. CSV w...

  9. Differential Pulse Anodic Stripping Voltammetry for Mercury Determination

    OpenAIRE

    Vereștiuc Paul C.; Tucaliuc Oana-Maria; Breabăn Iuliana G.; Crețescu Igor; Nemțoi Gheorghe

    2015-01-01

    In the present work voltammetric investigations have been performed on HgCl2 aqueous solutions prepared from a Cz 9024 reagent. Carbon paste electrode (CPE), eriochrome black T modified carbon paste electrode (MCPE/EBT) and KCl 1M as background electrolyte, were involved within the experimental procedures. Cyclic voltammetry (CV) has been performed in order to compare the behaviour of the two electrodes in both K3[Fe(CN)6] and mercury calibration aqueous solution. Differential pulse anodic st...

  10. DETERMINATION OF ZINC, CADMIUM, LEAD, AND COPPER IN WATER BY ANODIC STRIPPING VOLTAMMETRY

    Science.gov (United States)

    The Tennessee Valley Authority developed a method of differential pulse anodic stripping voltammetry for determining total concentrations of cadmium and lead in water samples from ash ponds at steam-electric generating plants. After digestion of the sample and addition of reagent...

  11. Lead-Testing Service to Elementary and Secondary Schools Using Anodic Stripping Voltammetry

    Science.gov (United States)

    Goebel, Amanda; Vos, Tracy; Louwagie, Anne; Lundbohm, Laura; Brown, Jay H.

    2004-01-01

    The undergraduate chemistry club of the Southwest Minnesota State University offers assistance in lead-testing through the anodic stripping voltammetry (ASV) technique to elementary and secondary schools. Emphasis is given to this community service activity, which has increased club membership, and promoted discussion of water quality problems in…

  12. Detection of heavy metals in biological samples through anodic stripping voltammetry

    OpenAIRE

    Buzea, Vlad; Florescu, Monica; Badea, Mihaela

    2012-01-01

    The toxicological aspects due to the presence of heavy metals in biological samples impose to have accurate and rapid methods for their detection. This paper is aimed to review approaches to anodic stripping voltammetry (ASV) determination of several heavy metals (lead, cadmium, copper, mercury, zinc) in biological matrices (blood, urine, saliva, tissue sample). Analytical performances (LOD, data linearity range, sensitivity) of the reviewed methods were presented for several electrochemical ...

  13. Self-assessment test on concepts related to Anodic Stripping Voltammetry (ASV)

    OpenAIRE

    Milla González, Miguel; Espada Bellido, Estrella

    2014-01-01

    This exercise is intended to reinforce and assess knowledge on Anodic Stripping Voltammetry (ASV) as an electroanalytical technique. It is designed as a multiple entry test in which several options for a concept related to this analysis technique is proposed. The exercise can be resolved page to page (answers are ticked and the truth or falsity of the chosen option is obtained) or globally. In the latter, the user ticks the "correct" answers and obtains a grade at the end of the test. Going ...

  14. Anodic Stripping Voltammetry at Nanoelectrodes: Trapping of Mn2+ by Crown Ethers

    International Nuclear Information System (INIS)

    The work presented here describes the development and characterization of platinum-mercury hemispherical nanoelectrodes for the spatially resolved quantitative detection of manganese cations. The electrochemical probes were made by electrodeposition of metallic mercury from a mercuric ion solution onto Pt/quartz laser-pulled concentric disk nanoelectrodes (with disk radii ranging from 3 to 500 nm). The nanoelectrodes were characterized by steady-state voltammetry, scanning electrochemical microscopy, environmental scanning electron microscopy, energy-dispersive X-ray spectroscopy and calibrated with respect to the concentration of Mn2+ ions using anodic stripping voltammetry. The fully characterized probes were employed for the quantitative detection of Mn2+. The technique has been used to evaluate the impact of a novel approach for mitigating the undesirable consequences of manganese dissolution in Li-ion batteries

  15. Anodic stripping voltammetry of antimony using gold nanoparticle-modified carbon screen-printed electrodes

    International Nuclear Information System (INIS)

    Carbon screen-printed electrodes (CSPE) modified with gold nanoparticles present an interesting alternative in the determination of antimony using differential pulse anodic stripping voltammetry. Metallic gold nanoparticles deposits have been obtained by direct electrochemical deposition. Scanning electron microscopy measurements show that the electrochemically synthesized gold nanoparticles are deposited in aggregated form. Any undue effects caused by the presence of foreign ions in the solution were also analyzed to ensure that common interferents in the determination of antimony by ASV. The detection limit for Sb(III) obtained was 9.44 x 10-10 M. In terms of reproducibility, the precision of the above mentioned method in %R.S.D. values was calculated at 2.69% (n = 10). The method was applied to determine levels of antimony in seawater samples and pharmaceutical preparations

  16. Anodic stripping voltammetry with graphite felt electrodes for the trace analysis of silver.

    Science.gov (United States)

    Davies, Trevor J

    2016-08-01

    Graphite felt (GF) is a mass produced porous carbon electrode material commonly used in redox flow batteries. Previous studies have suggested GF may have valuable applications in electroanalysis as a low cost disposable carbon electrode material, although most GF sensors have used flow cell arrangements. In this work, an elegant wetting technique is employed that allows GF electrodes to be used in quiescent solution to detect trace levels of silver in water via anodic stripping voltammetry. GF electrodes display good repeatability and a limit of detection of 25 nM of Ag(+) in 0.1 M HNO3, with a linear range spanning two orders of magnitude. This compares to a value of around 140 nM when using conventional carbon electrodes. Combined with their low cost and disposable nature, the results suggest GF electrodes can make a valuable contribution to electroanalysis. PMID:27276994

  17. Direct analysis of palladium in active pharmaceutical ingredients by anodic stripping voltammetry.

    Science.gov (United States)

    Rosolina, Samuel M; Chambers, James Q; Xue, Zi-Ling

    2016-03-31

    Anodic stripping voltammetry, a classical electroanalytical method has been optimized to analyze trace Pd(II) in active pharmaceutical ingredient matrices. The electroanalytical approach with an unmodified glassy carbon electrode was performed in both aqueous and 95% DMSO/5% water (95/5 DMSO/H2O) solutions, without pretreatment such as acid digestion or dry ashing to remove the organics. Limits of detection (LODs) in the presence of caffeine and ketoprofen were determined to be 11 and 9.6 μg g(-1), with a relative standard deviation (RSD) of 5.7% and 2.3%, respectively. This method is simple, highly reproducible, sensitive, and robust. The instrumentation has the potential to be portable and the obviation of sample pretreatment makes it an ideal approach for determining lost catalytic metals in pharmaceutical-related industries. Furthermore, the simultaneous detection of Pd(II) with Cd(II) and Pb(II) in the low μg L(-1) range indicates that this system is capable of simultaneous multi-analyte analysis in a variety of matrices. PMID:26965326

  18. Direct analysis of palladium in active pharmaceutical ingredients by anodic stripping voltammetry.

    Science.gov (United States)

    Rosolina, Samuel M; Chambers, James Q; Xue, Zi-Ling

    2016-03-31

    Anodic stripping voltammetry, a classical electroanalytical method has been optimized to analyze trace Pd(II) in active pharmaceutical ingredient matrices. The electroanalytical approach with an unmodified glassy carbon electrode was performed in both aqueous and 95% DMSO/5% water (95/5 DMSO/H2O) solutions, without pretreatment such as acid digestion or dry ashing to remove the organics. Limits of detection (LODs) in the presence of caffeine and ketoprofen were determined to be 11 and 9.6 μg g(-1), with a relative standard deviation (RSD) of 5.7% and 2.3%, respectively. This method is simple, highly reproducible, sensitive, and robust. The instrumentation has the potential to be portable and the obviation of sample pretreatment makes it an ideal approach for determining lost catalytic metals in pharmaceutical-related industries. Furthermore, the simultaneous detection of Pd(II) with Cd(II) and Pb(II) in the low μg L(-1) range indicates that this system is capable of simultaneous multi-analyte analysis in a variety of matrices.

  19. Stripping voltammetry of flavonoids

    International Nuclear Information System (INIS)

    The electrochemical behavior of the flavonoids hesperidin, quercetin, naringin, rutin, catechin, epicatechin and caffeic acid at the mercury electrode (HMDE, DME) and at a glassy carbon electrode has been studied by differential pulse polarography. Determination of flavonoids can be achieved either by direct reduction of the carbonyl group in the gamma-pyron ring, indirectly by cathodic stripping voltammetry via the formation of different flavonoid-mercury complexes at the mercury electrode surface and by adsorptive stripping voltammetry via the direct oxidation of aromatic o-dihydroxy groups. The advantage of stripping voltammetry is higher sensitivity and due to the possibility of higher sample dilution less influence of matrix effects. The application by cathodic stripping voltammetry to the determination of hesperidin in orange juice, hesperidin and rutin in helopyrin(R) tablets, a phytopharmaceutical preparation, naringin in grapefruit juice is demonstrated. Also the application by adsorptive stripping voltammetry at a glassy carbon electrode to the determination of quercetin in blood and sinupret, a phytopharmaceutical preparation and catechin in beer is demonstrated. Both methods are suitable for the determination of low flavonoid concentrations down to the ppb concentration range. (author)

  20. Theory of Anodic Stripping Square Wave Voltammetry on Spherical Mercury Electrodes

    OpenAIRE

    Komorsky-Lovrić, Šebojka; Lovrić, Milivoj

    2014-01-01

    Relationships between dimensionless anodic stripping square-wave voltammetric net peak currents and the dimensionless inverse electrode radius are curves with two asymptotes that depend on the duration of accumulation. The theory applies to reversible reduction of amalgam forming ions on stationary mac-ro and micro spherical and hemispherical mercury electrodes.

  1. Investigations on the use of anodic stripping voltammetry for the analyses of lead in saline environments

    Energy Technology Data Exchange (ETDEWEB)

    Case, C.W.

    1978-08-01

    Research is reported directed to modification of the anodic stripping voltammetry (ASV) analytic method in order to acquire data for lead from ambient sea water conditions, and development of a chemical model which uses these data to identify inorganic lead species for saline environments. Laboratory and field samples were analyzed for lead partitioning in: (a) KCl electrolyte solutions; (b) I.A.P.S.O. Standard Sea Water; (c) seawater samples from Quatsino Sound, British Columbia; (d) a series of seawater samples from San Francisco Bay; and (e) seawater samples from the Gulf of Mexico. The electrochemical traits of the lead species and the ASV oxidation potential expression are the fundamental constituents of the chemical model. The model uses the data from the analyses to provide the mass balance relationships for lead partitioned among the major anions in seawater. The laboratory analyses of KCl electrolyte and Standard Seawater give the following results. The modified ASV method and chemical model provide information on ambient labile and non-labile inorganic lead complexes in these saline solutions down to the parts-per-billion level. No purge and the simple electrodes cause some erratic behavior and spurious potentials, but the data are reproducible. In addition to Pb/sup 2 +/, the most dominant measured lead species in order include PbCO/sub 3//sup 0/, PbSO/sub 4//sup 0/, PbCl/sup +/, and Pb(NO/sub 3/)/sub 2//sup 0/ from the lead additions solution. The analyses of the field samples give the following results. Samples were taken from the partially anoxic basin in Quatsino Sound, British Columbia with one successful analysis which is for somewhat normal dissolved oxygen conditions. Data show that lead is partitioned among Pb/sup 2 +/, Pb(OH)/sub 2//sup 0/, PbCO/sub 3//sup 0/, and PbSO/sub 4//sup 0/. The analyses with purge for the San Francisco Bay water partitions lead among Pb/sup 2 +/, PbCO/sub 3//sup 0/, PbSO/sub 4//sup 0/, PbCl/sup +/, and Pb

  2. Determination of Soil Base—Soluble Se by Anodic Stripping Voltammetry with Aurum Thin—Film Electrode

    Institute of Scientific and Technical Information of China (English)

    YANGZENG; HEYING; 等

    1994-01-01

    Determination of soil Se by anodic stripping voltammetry(ASV) with aurum thin-film electrode(ATFE)overcomes the interference of gold peak with selenium peak,and thus has a higher sensitivity with the miniumum detectable concentration being 0.017μg/mL,the standard deviation of the measured results leww than 0.012μg/g,the coefficient of variation lwoer than 10% ,and the recovery rate between 86% to 103%.Besides the measurement conditions,the digestion of soil sample was also studied in detail.

  3. Lab-on-a-Chip Sensor with Evaporated Bismuth Film Electrode for Anodic Stripping Voltammetry of Zinc

    Science.gov (United States)

    Kang, Wenjing; Pei, Xing; Yue, Wei; Bange, Adam; Heineman, William R.; Papautsky, Ian

    2013-01-01

    In this work, we report on the development of a lab-on-a-chip electrochemical sensor that uses an evaporated bismuth electrode to detect zinc using square wave anodic stripping voltammetry. The microscale electrochemical cell consists of a bismuth working electrode, an integrated silver/silver chloride reference electrode, and a gold auxiliary electrode. The sensor demonstrated linear response in 0.1 M acetate buffer at pH 6 with zinc concentrations ranging from 1 μM to 30 μM and a calculated detection limit of 60 nM. The sensor was also able to successfully detect zinc in a bovine serum extract and the results were verified with independent AAS measurements. These results demonstrate the advantageous qualities of this lab-on-a-chip electrochemical sensor for clinical applications, which include a small sample volume (μL scale), reduced cost, short response time and high accuracy at low concentrations of analyte. PMID:24436575

  4. International comparison of Cd content in a quality control material of Navajuelas (Tagelus dombeii) determined by anodic stripping voltammetry, atomic absorption spectrometry and neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Queirolo, F. (Universidad Catolica del Norte, Antofagasta (Chile). Dept. of Chemistry Forschungszentrum Juelich GmbH (Germany, F.R.). Inst. fuer Angewandte Physikalische Chemie Universidad de Extremadura, Badajoz (Spain). Dept. of Analytical Chemistry and Electrochemistry); Ostapczuk, P. (Forschungszentrum Juelich GmbH (Germany, F.R.). Inst. fuer Angewandte Physikalische Chemie); Valenta, P.; Stegen, S. (Forschungszentrum Juelich GmbH (Germany, F.R.). Inst. fuer Angewandte Physikalische Chemie Universidad de Extremadura, Badajoz (Spain). Dept. of Analytical Chemistry and Electrochemistry); Marin, C.; Vinagre, F.; Sanchez, A. (Universidad de Extremadura, Badajoz (Spain). Dept. of Analytical Chemistry and Electrochemistry)

    1991-05-01

    The determination of Cd was performed by neutron activation analysis (NAA), atomic absorption spectrometry (AAS) with flame or in the electrothermal mode and anodic stripping voltammetry in the differential pulse mode (DPASV) and the square wave mode (SWASV). (orig./EF).

  5. Linear sweep anodic stripping voltammetry: Determination of Chromium (VI) using synthesized gold nanoparticles modified screen-printed electrode

    Indian Academy of Sciences (India)

    Salamatu Aliyu Tukur; Nor Azah Yusof; Reza Hajian

    2015-06-01

    A highly sensitive electrochemical sensor has been constructed for determination of Cr(VI) with the lowest limit of detection (LOD) reported to date using gold nanoparticles (AuNPs) modified screen-printed electrode (SPE). The modification of SPE by casting pure AuNPs increases the sensitivity for detection of Cr(VI) ion using anodic stripping voltammetry. Cr(VI) ions are reduced to chromium metal on SPE-AuNPs by applying deposition potential of –1.1 V for 180 s. Afterwards, the oxidation peak current of chromium is obtained by linear sweep voltammetry in the range of −1.0 V to 0.2 V. Under the optimized conditions (HClO4, 0.06 mol L−1; deposition potential, –1.1 V; deposition time, 180s; scan rate, 0.1 V s−1), the limit of detection (LOD) was 1.6 pg mL−1. The fabricated electrode was successfully used for detection of Cr(VI) in tap and seawater.

  6. An Environmentally Friendly, Cost-Effective Determination of Lead in Environmental Samples Using Anodic Stripping Voltammetry

    Science.gov (United States)

    Goldcamp, Michael J.; Underwood, Melinda N.; Cloud, Joshua L.; Harshman, Sean

    2008-01-01

    Contamination of the environment with heavy metals such as lead presents many health risks. Simple, effective, and field-portable methods for the measurement of toxic metals in environmental samples are vital tools for evaluating the risks that these contaminants pose. This article describes the use of new developments in anodic stripping…

  7. Trace metal characterization and speciation in geothermal effluent by multiple scanning anodic stripping voltammetry and atomic absorption analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kowalski, B.R.

    1979-05-25

    Recent studies have shown geothermal power plants to have a significant environmental impact on the ground water of the area. The heavy metals arsenic and mercury are special problems, as both are concentrated by flora and fauna exposed to the effluent waters. Because the toxicity of these and other metallic pollutants present in geothermal effluent depends on the chemical form, or speciation, of the particular metal, any serious study of the environmental impact of a geothermal development should include studies of trace metal speciation, in addition to trace metal concentration. This proposal details a method for determining metal speciation in dilute waters. The method is based on ion-exchange and backed by atomic absorption spectrometry and multiple scanning anodic stripping voltammetry. Special laboratory studies will be performed on mercury, arsenic and selenium speciation in synthetic geothermal water. The method will be applied to three known geothermal areas in Washington and Oregon, with emphasis on the speciation of mercury, arsenic and selenium in these waters. The computer controlled electrochemical instrumentation was built and tested. Using this instrumentation, a new experimental procedure was developed to determine the chemical form (speciation) of metal ions in very dilute solutions (ng/ml). This method was tested on model systems including Pb, Cd, and As with C1/sup -/, CO/sub 3//sup 2 -/ and glycine ligands. Finally, the speciation of lead in a geothermal water was examined and the PbC1/sup +/ complex was observed and quantified.

  8. Preparation and Evaluation of Acetabularia-Modified Carbon Paste Electrode in Anodic Stripping Voltammetry of Copper and Lead Ions

    Directory of Open Access Journals (Sweden)

    Muhammad Raziq Rahimi Kooh

    2013-01-01

    Full Text Available Seaweed is well known about for potential in chelating heavy metals. In this study, carbon paste electrodes were fabricated with siphonous seaweed Acetabularia acetabulum as the modifiers to sense lead (II and copper (II by square-wave anodic stripping voltammetry. Various scan rates and deposition potentials were measured to obtain the optimal peak current for Pb(II and Cu(II. Optimum conditions of Acetabularia-CPE for sensing Pb(II were at the scan rate of 75 mV/s and deposition potential of −800 mV, while for Cu(II sensing were at 100 mV/s and −300 mV, respectively. The electrodes were characterized by the duration of accumulation time, preconcentration over a range of standards, supporting electrolyte, and standard solutions of various pH values. Interference studies were carried out. Both Zn(II and Cu(II were found to interfere with Pb(II sensing, whereas only Zn(II causes interference with Cu(II sensing. The electrode was found to have good regeneration ability via electrochemical cleaning. Preliminary testing of complex samples such as NPK fertilisers, black soil, and sea salt samples was included.

  9. Determination of Antimony (III in Real Samples by Anodic Stripping Voltammetry Using a Mercury Film Screen-Printed Electrode

    Directory of Open Access Journals (Sweden)

    Olga Domínguez-Renedo

    2009-01-01

    Full Text Available This paper describes a procedure for the determination of antimony (III by differential pulse anodic stripping voltammetry using a mercury film screen-printed electrode as the working electrode. The procedure has been optimized using experimental design methodology. Under these conditions, in terms of Residual Standard Deviation (RSD, the repeatability (3.81 % and the reproducibility (5.07 % of the constructed electrodes were both analyzed. The detection limit for Sb (III was calculated at a value of 1.27×10–8 M. The linear range obtained was between 0.99 × 10–8 – 8.26 × 10–8 M. An analysis of possible effects due to the presence of foreign ions in the solution was performed and the procedure was successfully applied to the determination of antimony levels in pharmaceutical preparations and sea water samples.

  10. Highly sensitive determination of mercury using copper enhancer by diamond electrode coupled with sequential injection–anodic stripping voltammetry

    International Nuclear Information System (INIS)

    Highlights: • Highly sensitive determination of Hg(II) using SI–ASV-BDD was achieved. • Electrochemical detection of Hg(II) using Cu(II) enhancer was accomplished. • LOD and LOQ were found to be very low at 40.0 ppt and 135.0 ppt. • This method was successfully applied for determination of Hg(II) in real samples. - Abstract: A highly sensitive determination of mercury in the presence of Cu(II) using a boron-doped diamond (BDD) thin film electrode coupled with sequential injection–anodic stripping voltammetry (SI–ASV) was proposed. The Cu(II) was simultaneously deposited with Hg(II) in a 0.5 M HCl supporting electrolyte by electrodeposition. In presence of an excess of Cu(II), the sensitivity for the determination of Hg(II) was remarkably enhanced. Cu(II) and Hg(II) were on-line deposited onto the BDD electrode surface at −1.0 V (vs. Ag/AgCl, 3 M KCl) for 150 s with a flow rate of 14 μL s−1. An anodic stripping voltammogram was recorded from −0.4 V to 0.25 V using a frequency of 60 Hz, an amplitude of 50 mV, and a step potential of 10 mV at a stopped flow. Under the optimal conditions, well-defined peaks of Cu(II) and Hg(II) were found at −0.25 V and +0.05 V (vs. Ag/AgCl, 3 M KCl), respectively. The detection of Hg(II) showed two linear dynamic ranges (0.1–30.0 ng mL−1 and 5.0–60.0 ng mL−1). The limit of detection (S/N = 3) obtained from the experiment was found to be 0.04 ng mL−1. The precision values for 10 replicate determinations were 1.1, 2.1 and 2.9% RSD for 0.5, 10 and 20 ng mL−1, respectively. The proposed method has been successfully applied for the determination of Hg(II) in seawater, salmon, squid, cockle and seaweed samples. A comparison between the proposed method and an inductively coupled plasma optical emission spectrometry (ICP-OES) standard method was performed on the samples, and the concentrations obtained via both methods were in agreement with the certified values of Hg(II), according to the paired t-test at a

  11. Differential pulse anodic stripping voltammetry for detection of As (III) by Chitosan-Fe(OH)3 modified glassy carbon electrode: A new approach towards speciation of arsenic.

    Science.gov (United States)

    Saha, Suparna; Sarkar, Priyabrata

    2016-09-01

    An efficient electrochemical sensor for As(III) was developed based on adsorption of arsenic on a specially modified electrodes at some applied potential and subsequent i) stripping at a fixed potential by anodic stripping voltammetry ii) analysis by generating surface plasmon resonance (SPR). The working glassy carbon electrode was modified by Chitosan-Fe(OH)3 composite and a reducing agent L-cysteine. The composite enhanced adsorption of As(III) and subsequent reduction to As(O) moieties and measurement by anodic stripping. The surface property of modified electrode was characterized by SEM, AFM, FTIR, XPS and electrochemistry was analyzed by impedance spectroscopy (EIS). Surface Plasmon resonance (SPR) was also employed to investigate the As(III) binding capability of polymer matrix. Several optimum voltammetric parameters e.g supporting electrolyte; 0.1M acetate buffer (pH 5.2) deposition potential, -0.9V; deposition time, 100s were established for anodic stripping voltammetry (ASV). A linear correlation was obtained in the range of 2-100ppb for ASV (R(2) 0.974) with limit of detection 0.072ppb. A variety of common coexistent ions such as Mn, Zn, Pb, Cu, Cd in water samples showed no interferences on the As (III) determination. The method was applied successfully to real samples collected from arsenic affected areas of West Bengal, India. PMID:27343601

  12. ANODIC STRIPPING VOLTAMMETRY AT A MERCURY FILM ELECTRODE: BASELINE CONCENTRATIONS OF CADMIUM, LEAD, AND COPPER IN SELECTED NATURAL WATERS

    Science.gov (United States)

    A simple, rapid, and inexpensive anodic stripping voltammetric method with a mercury thin film electrode is reported for the establishment of baseline concentrations of cadmium, lead, and copper in natural waters. The procedure for routine surface preparation of wax-impregnated g...

  13. DETERMINATION OF BACKGROUND LEVELS OF LEAD AND CADMIUM IN RAW AGRICULTURAL CROPS BY USING DIFFERENTIAL PULSE ANODIC STRIPPING VOLTAMMETRY

    Science.gov (United States)

    A method is described for the simultaneous determination of ultratrace levels of lead and cadmium in selected agricultural crop samples by differential pulse anodic stripping voltametry. Samples are dry ashed at high temperature with H2SO4 as an ashing aid. Techniques are describ...

  14. LabVIEW-based sequential-injection analysis system for the determination of trace metals by square-wave anodic and adsorptive stripping voltammetry on mercury-film electrodes

    OpenAIRE

    Anastasios Economou; Anastasios Voulgaropoulos

    2003-01-01

    The development of a dedicated automated sequential-injection analysis apparatus for anodic stripping voltammetry (ASV) and adsorptive stripping voltammetry (AdSV) is reported. The instrument comprised a peristaltic pump, a multiposition selector valve and a home-made potentiostat and used a mercury-film electrode as the working electrodes in a thin-layer electrochemical detector. Programming of the experimental sequence was performed in LabVIEW 5.1. The sequence of operations included format...

  15. Trace analysis of Cd, Cu, Pb and Zn in various materials using differential pulse anodic stripping voltammetry

    International Nuclear Information System (INIS)

    Sampling and sample preparation methods have been described. Digestion methods for different types of materials and acid purification systems have been developed. For trace analysis purposes cleaning methods for glassware etc. have been described. Differential pulse anodic stripping voltametric (DPASV) method has been worked out for the trace analysis of zn, cd, pb and Cu in different types of materials. Linearity of the method has been checked by drawing concentration versus currents (peak height) curves. Precision of the method has been checked by analysing a number of actual samples. of the method has been verified by analysing standards of U.S.A. Comparative studies have been done between Differential pulse anodic stripping voltammetric method and Atomic Absorption spectroscopic method. Problems of contamination and systematic errors during trace and ultra-trace analysis have been discussed. A variety of samples including soil, spinach, wheat flour, rice flour, dry milk, coriander, kidney stones, bladder stones etc. have been analysed and preliminary results have been reported. (author)

  16. Kinetic and equilibrium studies for the adsorption process of cadmium(II) and copper(II) onto Pseudomonas aeruginosa using square wave anodic stripping voltammetry method

    International Nuclear Information System (INIS)

    A novel method for the simultaneous determination of cadmium(II) and copper(II) during the adsorption process onto Pseudomonas aeruginosa was developed. The concentration of the free metal ions was successfully detected by square wave anodic stripping voltammetry (SWASV) on the mercaptoethane sulfonate (MES) modified gold electrode, while the P. aeruginosa was efficiently avoided approaching to the electrode surface by the MES monolayer. And the anodic stripping peaks of Cd2+ and Cu2+ appear at -0.13 and 0.34 V respectively, at the concentration range of 5-50 μM, the peak currents of SWASV present linear relationships with the concentrations of cadmium and copper respectively. As the determination of Cd2+ and Cu2+ was in real time and without pretreatment, the kinetic characteristics of the adsorption process were studied and all the corresponding regression parameters were obtained by fitting the electrochemical experimental data to the pseudo-second-order kinetic model. Moreover, Langmuir and Freundlich models well described the biosorption isotherms. And there were some differences in the amount of metal ion adsorbed at equilibrium (qe) and other kinetics parameters when the two ions coexisted were compared with the unaccompanied condition, which were also discussed in this paper. The proposed electrode system provides excellent platform for the simultaneous determination of trace metals in complex biosorption process.

  17. Functionalized Nanoporous Track-Etched b-PVDF Membrane Electrodes for Heavy Metal Determination by Square-Wave Anodic Stripping Voltammetry

    Directory of Open Access Journals (Sweden)

    Bessbousse H.

    2013-04-01

    Full Text Available Track-etched functionalized nanoporous β-PVDF membrane electrodes, or functionalized membrane electrodes (FMEs, are electrodes made from track-etched, poly(acrylic acid (PAA functionalized nanoporous β-poly(vinylidene fluoride (β-PVDF membranes with thin porous Au films sputtered on each side as electrodes. To form the β-PVDF nanoporous membranes, β-PVDF films are irradiated by swift heavy ions. After irradiation, radical tracks are stable in the membranes. Chemical etching removes some of the radical tracks revealing nanopores. Radicals, remaining in the pores, initiate radio grafting of PAA from the pore walls of the nanoporous β-PVDF. PAA is a cation exchange polymer that adsorbs metal ions, such as Pb2+, from aqueous solutions thus concentrating the ions into the membrane. After a calibrated time the FME is transferred to an electrochemical cell for square-wave anodic stripping voltammetry analysis.

  18. On-site fuel electroanalysis: determination of lead, copper and mercury in fuel bioethanol by anodic stripping voltammetry using screen-printed gold electrodes.

    Science.gov (United States)

    Almeida, Eduardo S; Richter, Eduardo M; Munoz, Rodrigo A A

    2014-07-21

    The potential application of commercial screen-printed gold electrodes (SPGEs) for the trace determination of lead, copper, and mercury in fuel bioethanol is demonstrated. Samples were simply diluted in 0.067 mol L(-1) HCl solution prior to square-wave anodic stripping voltammetry (SWASV) measurements recorded with a portable potentiostat. The proposed method presented a low detection limit (<2 μg L(-1)) for a 240 s deposition time, linear range between 5 and 300 μg L(-1), and adequate recovery values (96-104%) for spiked samples. This analytical method shows great promise for on-site trace metal determination in fuel bioethanol once there is no requirement for sample treatment or electrode modification.

  19. Determination of Cd2+ and Pb2+ Based on Mesoporous Carbon Nitride/Self-Doped Polyaniline Nanofibers and Square Wave Anodic Stripping Voltammetry

    Directory of Open Access Journals (Sweden)

    Chang Zhang

    2016-01-01

    Full Text Available The fabrication and evaluation of a glassy carbon electrode (GCE modified with self-doped polyaniline nanofibers (SPAN/mesoporous carbon nitride (MCN and bismuth for simultaneous determination of trace Cd2+ and Pb2+ by square wave anodic stripping voltammetry (SWASV are presented here. The morphology properties of SPAN and MCN were characterized by transmission electron microscopy (TEM, and the electrochemical properties of the fabricated electrode were characterized by cyclic voltammetry (CV. Experimental parameters, such as deposition time, pulse potential, step potential, bismuth concentration and NaCl concentration, were optimized. Under the optimum conditions, the fabricated electrode exhibited linear calibration curves ranging from 5 to 80 nM for Cd2+ and Pb2+. The limits of detection (LOD were 0.7 nM for Cd2+ and 0.2 nM for Pb2+ (S/N = 3. Additionally, the repeatability, reproducibility, anti-interference ability and application were also investigated, and the proposed electrode exhibited excellent performance. The proposed method could be extended for other heavy metal determination.

  20. Simultaneous Determination of Zinc (Zn, Cadmium (Cd, Lead (Pb and Copper (Cu in Blood Using Differential- Pulse Anodic-Stripping Voltammetry

    Directory of Open Access Journals (Sweden)

    A.K. Jaiswal

    2015-05-01

    Full Text Available The salts of Zinc (Zn, Cadmium (Cd, Lead (Pb, Copper (Cu, are of great toxicological importance and can causes poisoning. Therefore quantitative determination of traces of zinc, cadmium, lead, copper, in blood is very essential. Routinely, inductive coupled plasma, atomic absorption spectrometry, graphite furnace atomic absorption spectrometry were used for analysis. An attempt has been made to develop new method for simultaneous determination of traces of zinc, cadmium, lead, copper, in blood done by differential-pulse anodic-stripping voltammetry. Blood was processed by wet digestion method using concentrated nitric acid and sulphuric acid. Determination of zinc, cadmium, lead, copper, was made in acetate buffer (pH 4.6 with a sweep rate (scan rate of 60.0 mV/s and pulse amplitude 50 mV by Hanging Mercury Dropping Electrode (HMDE by standard addition method. The solution was stirred during pre-electrolysis at -1150 mV (vs. Ag/ AgCl for 90 s and the potential was scanned from - 1150m V to +100m V (vs. Ag/ AgCl. Under these conditions the limit of detection of zinc, cadmium, lead, and copper were 1.0 μg/L, 1.0 μg/L, 0.1 μg/L, 1.0 μg/L and respectively

  1. Cd, Pb and Cu in spring waters of the Sibylline Mountains National Park (Central Italy, determined by square wave anodic stripping voltammetry

    Directory of Open Access Journals (Sweden)

    Truzzi C.

    2013-04-01

    Full Text Available Square wave anodic stripping voltammetry (SWASV was used to determine Cd, Pb and Cu in spring waters of the Sibylline Mountains National Park, Central Italy. Samples were collected from three different areas of the Park (Mount Bove North, Mount Bove South and Springs of River Nera during the period 2004-2011. Physical-chemical parameters were also determined to obtain a general characterization of the waters. Very low metal concentrations were observed (i.e., Cd 1.3±0.4 ng L-1, Pb 13.8±5.6 ng L-1, Cu 157±95 ng L-1, well below the legal limits and also below the medians of known Italian and European data. Comparing the three areas it was noted that waters from the area of the Nera Springs are the poorest in heavy metals and the richest in minerals, that conversely the waters of Mt. Bove North are the richest in heavy metals and the poorest in mineral salts, and finally that intermediate values both for heavy metals and mineral salts were observed for the waters of Mt. Bove South.

  2. Determination of trace heavy metals in herbs by sequential injection analysis-anodic stripping voltammetry using screen-printed carbon nanotubes electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Injang, Uthaitip; Noyrod, Peeyanun [Sensor Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330 (Thailand); Siangproh, Weena [Department of Chemistry, Faculty of Science, Srinakharinwirot University, Sukumvit 23 Rd., Wattana, Bangkok 10110 (Thailand); Dungchai, Wijitar [Sensor Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330 (Thailand); Motomizu, Shoji [Department of Chemistry, Faculty of Science, Okayama University, 3-1-1 Tsushimanaka, Okayama 700-8530 (Japan); Chailapakul, Orawon, E-mail: corawon@chula.ac.th [Sensor Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330 (Thailand); Center for Petroleum, Petrochemicals and Advanced Materials, Chulalongkorn University, Patumwan, Bangkok 10330 (Thailand)

    2010-05-23

    A method for the simultaneous determination of Pb(II), Cd(II), and Zn(II) at low {mu}g L{sup -1} concentration levels by sequential injection analysis-anodic stripping voltammetry (SIA-ASV) using screen-printed carbon nanotubes electrodes (SPCNTE) was developed. A bismuth film was prepared by in situ plating of bismuth on the screen-printed carbon nanotubes electrode. Operational parameters such as ratio of carbon nanotubes to carbon ink, bismuth concentration, deposition time and flow rate during preconcentration step were optimized. Under the optimal conditions, the linear ranges were found to be 2-100 {mu}g L{sup -1} for Pb(II) and Cd(II), and 12-100 {mu}g L{sup -1} for Zn(II). The limits of detection (S{sub bl}/S = 3) were 0.2 {mu}g L{sup -1} for Pb(II), 0.8 {mu}g L{sup -1} for Cd(II) and 11 {mu}g L{sup -1} for Zn(II). The measurement frequency was found to be 10-15 stripping cycle h{sup -1}. The present method offers high sensitivity and high throughput for on-line monitoring of trace heavy metals. The practical utility of our method was also demonstrated with the determination of Pb(II), Cd(II), and Zn(II) by spiking procedure in herb samples. Our methodology produced results that were correlated with ICP-AES data. Therefore, we propose a method that can be used for the automatic and sensitive evaluation of heavy metals contaminated in herb items.

  3. Analytical possibilities of microelectrode use for stripping voltammetry

    Energy Technology Data Exchange (ETDEWEB)

    Matysik, F.M. (Leipzig Univ. (Germany). Dept. of Chemistry); Glaeser, P. (Leipzig Univ. (Germany). Dept. of Chemistry); Werner, G. (Leipzig Univ. (Germany). Dept. of Chemistry)

    1994-07-01

    The analytical utility of microelectrodes for stripping voltammetry is discussed from several points of view. The application of microelectrodes for microanalysis is demonstrated using a novel capillary flow injection system. Heavy metals at [mu]g l[sup -1] concentrations have been determined in [mu]l-samples. The influence of electrode size and convection during the deposition period of anodic stripping voltammetry on the reproducibility of trace metal determination was studied for various types of electrodes. In the case of mercury film microelectrodes, the precision can be improved if the accumulation of the analyte is performed under quiescent conditions. Practical examples of stripping voltammetry with microelectrodes such as copper determination in whisky and trace metal measurements in drinking water are given. (orig.)

  4. Determination of picomolar silver concentrations by differential pulse anodic stripping voltammetry at a carbon paste electrode modified with phenylthiourea-functionalized high ordered nanoporous silica gel

    International Nuclear Information System (INIS)

    This study introduces the design of an anodic stripping voltammetric (ASV) method for the silver ion determination at a carbon paste electrode (CPE), chemically modified with phenylthiourea-nanoporous silica gel (Tu-SBA-15-CPE). The electroanalytical pro includes two steps: preconcentration of metal ions at an electrode surface, followed by quantification of the accumulated species by differential pulse anodic stripping voltammetric methods. Factors affecting the performance of the anodic stripping were investigated, including the modifier quantity in the paste, the electrolyte concentrations, the solution pH and the accumulation potential or time. The most sensitive and reliable electrode contained 10% Tu-SBA-15 and 90% carbon paste. The accumulation potential and time were set at, -200 mV and 300 s, respectively, and the scan rate at 50 mV s-1 in the scan range of -200 to 700 mV. The resulting electrode demonstrated a linear response over range of silver ion concentration of 8.0-80 pmol/L with detection limit (S/N = 3) of 5 pmol/L. The prepared electrodes were used for the silver determination in sea and tap water samples and very good recovery results were obtained. The accuracy was assessed through recovery experiments and independent analysis by graphite furnace atomic absorption spectrometry.

  5. Design of heavy metal detector for anodic stripping voltammetry%水质阳极伏安法重金属检测仪设计

    Institute of Scientific and Technical Information of China (English)

    郑英; 王迷迷; 李香菊; 张立珍

    2015-01-01

    This paper designs an instrument for the detection of heavy metals in water by anodic voltammetry.In this paper,we analyze the principle of the detection,design the hardware circuit,the software programming and the prototype.The instrument can detect the concentration of copper,lead,cadmium, zinc and other heavy metals in the water environment,and the measurement data is stored and printed.The system has the advantages of good sensitivity,high efficiency,high efficiency,high information storage capacity, friendly man-machine interface and so on.%本文设计一种采用阳极伏安法对水环境重金属进行检测的仪器.本文分析了伏安法检测原理,设计了硬件电路,软件编程并制作样机.通过该仪器能够检测水环境中的铜、铅、镉、锌等多种重金属的浓度,并对测量数据进行存储和打印.通过对多种重金属进行测试验证,该系统具有灵敏度好、效率高、信息存储量大,友好的人机界面等特点,具有良好的重金属检测功能.

  6. Bismuth electrodes, an alternative in stripping voltammetry

    International Nuclear Information System (INIS)

    The heavy metals are known as highly toxic contaminants, the processes carried out in industry contribute that finally they remain dispersed in effluents and sewage, doing part of the food chain. The importance of controlling the levels of these heavy metals has become an international policy, so it has generated interest in developing new analytical methodologies for its determination [1, 2, 3, 4]. The stripping voltammetry has been considered as a family of electro-sensitive analytical techniques useful for the determination of trace levels of many metals in environmental, clinical and industrial samples [3, 4]. This work presents an overview of these bismuth-based electrodes which were introduced around 2000, which have interesting characteristics for detection of heavy metals and which represent an alternative to mercury electrodes

  7. Bismuth electrodes, an alternative in stripping voltammetry

    Science.gov (United States)

    Barón-Jaimez, J.; Joya, M. R.; Barba-Ortega, J.

    2013-11-01

    The heavy metals are known as highly toxic contaminants, the processes carried out in industry contribute that finally they remain dispersed in effluents and sewage, doing part of the food chain. The importance of controlling the levels of these heavy metals has become an international policy, so it has generated interest in developing new analytical methodologies for its determination [1, 2, 3, 4]. The stripping voltammetry has been considered as a family of electro-sensitive analytical techniques useful for the determination of trace levels of many metals in environmental, clinical and industrial samples [3, 4]. This work presents an overview of these bismuth-based electrodes which were introduced around 2000, which have interesting characteristics for detection of heavy metals and which represent an alternative to mercury electrodes.

  8. Differential Pulse Anodic Stripping Voltammetry Determination Of Copper (II) At Glassy Carbon Electrode In The Presence Of Bis(Benzylidene)Ethylenediamine As A Novel Complexing Agent

    International Nuclear Information System (INIS)

    This paper reports on the application of synthesized Schiff base bis(benzylidene)ethylenediamine (BBE) to increase the detection sensitivity of copper (II) at 0.01 V vs Ag/ AgCl using glassy carbon electrode. Aliquot of 2.0x10-3 M of BBE in DMF solution containing BR buffer pH 6 was introduced into the voltammetric cell followed by the addition of Cu(II) ions and then further proceeded to differential pulse anodic-stripping scan from -1.4 V to +0.3 V vs Ag/ AgCl. The optimum parameters obtained were; scan rate; 25 mV/ s, accumulation time; 200 sec and accumulation potential; -0.6 V. Under the optimal conditions, the detection limit of 0.4 μgL-1 and a linear response in the range of 1-10 μgL-1 were obtained. The effects of interfering ions such as Cd(II), Cr(III), Fe(II), Pb(II) and Zn(II) were also investigated. The practical applicability of this technique was illustrated by the determination of Cu(II) ions at 3 μgL-1 concentration level in tap water with 94.43 % of recovery. (author)

  9. Practical measurement of silicon in low alloy steels by differential pulse stripping voltammetry

    International Nuclear Information System (INIS)

    A sensitive differential pulse anodic stripping voltammetry has been adapted to allow the determination of Si in low-alloy steels using a hanging mercury drop electrode. The method has been qualified using certified ASTM standards and is now running in routine. The present report describes the experimental details, thereby allowing the reader to carry out the measurements precisely. (author)

  10. Application of silica fume as a new SP-extractor for trace determination of Zn(II) and Cd(II) in pharmaceutical and environmental samples by square-wave anodic stripping voltammetry

    Science.gov (United States)

    Ahmed, Salwa A.; Gaber, Ahmed A. Abdel; Rahim, Asmaa M. Abdel

    2015-04-01

    In this work, silica fume (SF) is used as a solid-phase extractor for extraction of Zn(II) and Cd(II) from aqueous solutions. Characterization of SF is performed by Fourier transform infrared, X-ray diffraction, transmission and scanning electron microscopy. The optimum experimental conditions for the two metal ions are investigated using batch and column techniques. The maximum adsorption capacity values are found to be 54.13 and 121.28 mg g-1 at the optimum pH 6.0 and 8.0 for Zn(II) and Cd(II), respectively. The equilibrium data are analyzed using the Langmuir, Freundlich, and Temkin isotherms by nonlinear regression analysis. Also, the kinetics analysis revealed that the overall adsorption process is successfully fitted with the pseudo-second-order model. The method is applied for determination of the target metal ions in pharmaceutical and environmental samples using square-wave anodic stripping voltammetry. The limit of detection (LOD) values are 0.102 and 1.43 × 10-3 mg L-1 for Zn(II) and Cd(II), respectively. The percentage recovery values are 98.8-100.5 % which indicate the success of the proposed method for determination of Zn(II) and Cd(II) without interfering effects.

  11. Self-doped anthranilic acid-pyrrole copolymer/gold electrodes for selective preconcentration and determination of Cu(I) by differential pulse anodic stripping voltammetry.

    Science.gov (United States)

    Nateghi, M R; Fallahian, M H

    2007-05-01

    Electropolymerization of anthranilic acid/pyrrole (AA/PY) at solid substrate electrodes (platinum, gold, and glassy carbon) gave stable and water-insoluble films under a wide range of pH. Combining high conductivity of the polypyrrole (PPY) and pH independence of the electrochemical activity of the self-doped carboxylic acid-substituted polyaniline allows us to prepare an improved functionalized PPY-modified electrode to collect and measure Cu(I) species. The differential pulse stripping analysis of the copper ions using a polyanthranilic acid-co-polypyrrole (PAA/PPY)-modified electrode consisted of three steps: accumulation, electrochemical reduction to the elemental copper and stripping step. Factors affecting these steps, including electropolymerization conditions, accumulation and stripping medium, reduction potential, reduction time and accumulation time, were systematically investigated. A detection limit of 5.3 x 10(-9) M Cu(I) was achieved for a 7.0 min accumulation. For 12 determinations of Cu(I) at concentrations of 1.0 x 10(-8) M, an RSD of 3.5% was obtained. The log I(p) was found to vary linearly with log[Cu(I)] in the concentration range from 7.0 x 10(-9) to 1.0 x 10(-5) M.

  12. Determination of trace silver by anodic stripping voltammetry with multi-wall carbon nanotube modified electrode%多壁碳纳米管修饰电极阳极溶出伏安法测定痕量银

    Institute of Scientific and Technical Information of China (English)

    明亮; 习霞

    2011-01-01

    A linear sweep stripping voltammetry for the determination of trace silver was developed by using multi-wall carbon nanotube (MWCNT) modified glassy carbon electrode (GCE) and optimizing the determination conditions such as supporting electrolyte and pH, the amount of modifier, the accumulation potential and time. In NaAc-HAc buffer solution at pH 4. 0, an anodic stripping peak with high sensitivity and good shape appeared at 0. 46 V after accumulation at -0. 10 V for 5 min. The stripping peak current varied linearly with the concentration of Ag+ in the range of 3. 0× 10-8 to 5. 0 ×10-5 mol/L. The detection limit of Ag+ was 1. 0 × 10-8 mol/L. Under the optimized experimental conditions, some common metal ions did not interfere in the determination of silver. The proposed method was applied to the determination of trace silver in environmental water and zinc alloy samples.The average recoverics for addition standard were between 96% and 103%.%利用多壁碳纳米管修饰玻碳电极,通过优化支持电解质及pH值、修饰剂用量、富集电位及时间等测定条件,建立了测定痕量银的线性扫描阳极溶出伏安分析法.在pH 4.0的NaAc-HAc缓冲液中,-0.10 V电位下富集5 min后,于0.46 V处出现一灵敏度高、峰形较好的银阳极溶出峰,溶出峰电流与Ag+浓度在3.0×10-8~5.0×10-5 mol/L的范围呈良好的线性关系,Ag+的检出限为1.0×10-8 mol/L,在选定的最佳实验条件下一些常见的金属离子几乎不干扰银的测定.该法用于环境水样及锌合金样品中痕量银的测定,平均回收率在96%~103%之间.

  13. Graphene electroanalysis: inhibitory effects in the stripping voltammetry of cadmium with surfactant free graphene.

    Science.gov (United States)

    Brownson, Dale A C; Lacombe, Alexandre C; Kampouris, Dimitrios K; Banks, Craig E

    2012-01-21

    We explore the use of surfactant free graphene towards the electroanalytical sensing of cadmium(II) ions via anodic stripping voltammetry. In line with literature methodologies, we modify an electrode substrate which exhibits relatively fast electron transfer with commercially available graphene which is free from surfactants. Surprisingly, we find that graphene reduces the analytical performance and hence inhibits the electrochemical detection of cadmium(II) ions, with calibration plots in model aqueous solutions revealing no advantages of employing graphene in this analytical context.

  14. Determination of mobile form contents of Zn, Cd, Pb and Cu in soil extracts by combined stripping voltammetry

    Energy Technology Data Exchange (ETDEWEB)

    Nedeltcheva, T. [Department of Analytical Chemistry, University of Chemical Technology and Metallurgy, 8 Kl. Ohridsi Blvd., 1756 Sofia (Bulgaria)]. E-mail: nedel@uctm.edu; Atanassova, M. [Department of Analytical Chemistry, University of Chemical Technology and Metallurgy, 8 Kl. Ohridsi Blvd., 1756 Sofia (Bulgaria); Dimitrov, J. [N. Pushkarov Institute of Soil Science and Agroecology, 7 Shosse Bankya St., 1080 Sofia (Bulgaria); Stanislavova, L. [N. Pushkarov Institute of Soil Science and Agroecology, 7 Shosse Bankya St., 1080 Sofia (Bulgaria)

    2005-01-10

    The amount of mobile forms of Zn, Pb, Cd and Cu in extracts obtained by treating soil samples with ammonium nitrate were determined by an appropriate combination of anodic and cathodic stripping voltammetry with hanging mercury drop electrode. Every analysis required three mercury drops: on the first one, zinc was determined; on the second, cadmium and lead; on the third, copper was determined. Zinc, lead and cadmium were determined by conventional differential-pulse anodic stripping voltammetry. For copper determination, adsorptive differential-pulse cathodic stripping voltammetry with amalgamation using chloride ions as a complexing agent was applied. The standard deviation of the results was from 1 to 10% depending on the metal content in the sample. Voltammetric results were in good agreement with the AAS analysis. No microwave digestion of soil extracts was necessary.

  15. Determination of Zinc(II) Ions Released into Artificial Digestive Juices from Culinary-Medicinal Button Mushroom, Agaricus bisporus (Agaricomycetidae), Biomass of In Vitro Cultures Using an Anodic Stripping Voltammetry Method.

    Science.gov (United States)

    Kala, Katarzyna; Muszynska, Bozena; Zajac, Magdalena; Krezalek, Remigiusz; Opoka, Wlodzimierz

    2016-01-01

    Zinc is one of those microelements that are essential for the proper functioning of the human body and must be supplemented in our food at a daily dose of 15 mg. It is well known that mushrooms accumulate elements; thus, in order to determine the extent of accumulation and the level of zinc released from mushrooms, in vitro cultures of Agaricus bisporus were established. The cultures were run on a modified Oddoux medium (a control culture) as well as on the same medium with the addition of zinc hydroaspartate (100 and 200 mg/L) and zinc sulfate (87.23 and 174.47 mg/L). These compounds were chosen to help estimate which form, organic or inorganic, results in a better assimilation of zinc(II) ions by biomass. As the next step, the level of zinc(II) ions released from the lyophilized biomass of in vitro cultures to the digestive juices, under thermal conditions of the human body (37°C), was determined. For this purpose, artificial digestive juices, imitating the composition of human digestive juices, were used. For determination of zinc(II) ions in the digestive tract, an anodic stripping voltammetry method was employed. The amount of zinc released into artificial saliva over 1 minute varied from 0.15 mg/100 g d.w. in the control culture to 2.35 mg/100 g d.w. in the biomass in the medium to which 200 mg/L zinc hydroaspartate had been added. Values were higher in gastric juice and depended on incubation time (2.66 to 30.63 mg/100 g d.w.). In intestinal juice, the highest value of the released zinc grew to 24.20 mg/100 g d.w. (biomass of A. bisporus in vitro cultures in medium with the addition of 200 mg/L zinc hydroaspartate). Total average amount of zinc released into artificial digestive juices was the highest (56.26 mg/100 g d.w.) from A. bisporus biomass of in vitro cultures in the medium to which 200 mg/L zinc hydroaspartate had been added. PMID:27279537

  16. On-line detection of Cu (II) in bioleaching system by anodic stripping differential pulse voltammetry%差分脉冲伏安法对生物冶金中铜(II)的在线检测

    Institute of Scientific and Technical Information of China (English)

    金妍; 陈淼; 金庆辉; 赵建龙

    2014-01-01

    采用差分脉冲阳极伏安法实现生物冶金中铜(II)浓度的在线检测。结果表明,当体系中仅有铜(II)存在且其浓度范围为1μmol/L~1 mmol/L时,差分脉冲阳极伏安法所测阳极氧化峰电流与浓度间有很好的线性度。当此体系中含有0.2 mol/L KCl时,铜离子检测的线性范围从1 mmol/L (64 mg/L)扩展到100 mmol/L (6.4 g/L)。在此条件下,二价铜离子的还原分为两步连续的单电子转移过程,中间态为Cu+的络合物CuCl-。此外,在铜的生物冶金体系中,经常会有铁离子存在,因此对铜离子检测的铁离子干扰也进行了研究,结果表明,当铁离子浓度低于100 mmol/L (5.6 g/L)时,其对铜离子检测的干扰可忽略。%On-line Cu (II) ion concentration detection in bioleaching system was achieved by anodic stripping differential pulse voltammetry (ASDPV). Good linearity between Cu (II) concentration and oxidation peak current was obtained when Cu (II) existed in 0K media in the concentration range of 1μmol/L (64μg/L) to 1 mmol/L (64 mg/L). Moreover, when 0.2 mol/L KCl was added into this media, the linear detection range could be extended from 1 mmol/L to 100 mmol/L (6.4 g/L). The reduction of Cu (II) to metallic copper was shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu+) was complexed by chloride to form the dichlorocuprous anion (CuCl-). In addition, interference effect was also investigated when Fe3+existed in the media, which was the common situation in the copper bioleaching system. The results showed no interference effect once the concentration of Fe3+was less than 100 mmol/L (5.6 g/L).

  17. Batch-injection stripping voltammetry of zinc at a gold electrode: application for fuel bioethanol analysis

    International Nuclear Information System (INIS)

    Graphical abstract: Display Omitted - Highlights: • Anodic stripping voltammetry of Zn at gold electrode for fuel bioethanol analysis. • Portable batch injection analysis coupled to anodic stripping voltammetry. • Efficient gold electrode cleaning between measurements of Zn in fuel bioethanol. • Adequate sensitivity, recovery values and no sample treatment required. • On-site determination of metals on fuel bioethanol using mercury-free electrode. - Abstract: This article reports for the first time the anodic stripping voltammetric (ASV) detection of Zn at a gold disk macroelectrode for the analysis of fuel bioethanol. The accurate determination of Zn at gold macroelectrodes was only possible with the aid of batch injection analysis (BIA) associated with ASV; this statement was proved by comparison with a conventional three-electrode system. The BIA system consisted of injections of bioethanol sample plugs (up to 1 mL) at 28.3 μL s−1 directly onto a working (gold disc) electrode immersed in 0.04 mol L−1 Britton-Robinson buffer (pH 7) solution through an electronic micropipette and the Zn deposition occurs simultaneously. The highest analytical response for Zn was obtained for a deposition time of 90 s, which indicated that Zn deposition also occurred from diffusion after the injection ended. The proposed method presented a low detection limit (5 μg L−1), a linear range between 25 and 250 μg L−1, and adequate recovery values (88–104%) for spiked samples, but no sample treatment was required. Such remarkable analytical features associated with the portability characteristics of BIA demonstrated the promising application of the proposed method for routine and on-site determination of metals in fuel bioethanol

  18. Determination of Pesticide Ethion by Linear Sweep Stripping Voltammetry

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The presence of the pesticide ethion was determined using an electroanalytical method, i. e. , linear sweep stripping voltammetry at a hanging mercury drop electrode in the Britton-Robbinson buffer with pH = 8. 36, based on its reduction peak observed at - 690 mV following its alkaline hydrolysis. The experimental parameters, namely, the preconcentration potential, the preconcentration time, and the scan rate were investigated and -300 mV (vs. Ag/AgCl), 270 s, and 100 mV/s were selected as the optimal values, respectively. The linear relationship between the peak current and the concentration was found to be in the range of 0. 02-0. 16 mg/L, with a detection limit of 0.0087 mg/L. The proposed method was applied to the determination of ethion in spiked vegetable and fruit samples via a preextraction with anhydrous ethanol.

  19. Application of different methodologies in the preparation of organic matrices for determination of trace elements by differential pulse anodic stripping voltammetry; Aplicacao de diferentes metodologias na preparacao de matrizes organicas para a determinacao voltametrica de elementos traco

    Energy Technology Data Exchange (ETDEWEB)

    Sisti, Cristina

    2001-07-01

    The determination of trace elements in food samples is of great importance for the human health, considering the factors of essentiality and toxicity. On the other hand, the chemical analysis is largely affected for the steps of sample preparation; laboratory contamination of the sample and the reagents or still volatilization and losses of the elements. If these parameters are not controlled the achieved precision and accuracy could be low. In this work, the content of zinc, cadmium, lead and copper was determined in adults diet samples collected by duplicate portion technique and bovine liver, applying the differential pulse anodic stripping voltametry - (DP-ASV) technique. In the digestion of the matrices in acid medium, conventional methodologies were used, conductive heating in open recipients and equipment with microwaves source in open and closed vessels. The best procedure was the sample digestion by microwaves, in closed vessels and the other treatments made in controlled atmosphere with hood laminar-airflow class 100. The established methodology was validated with the use of a certified sample as reference (NIST - bovine liver 1577b). (author)

  20. Ultrasensitive non-enzymatic glucose sensing at near-neutral pH values via anodic stripping voltammetry using a glassy carbon electrode modified with Pt3Pd nanoparticles and reduced graphene oxide

    International Nuclear Information System (INIS)

    We describe an anodic stripping voltammetric (ASV) method for glucose sensing that widely expands the typical amperometric i-t response of glucose sensors. The electrode is based on a working electrode consisting of a glassy carbon electrode modified with Pt-Pd nanoparticles (NPs; in an atomic ratio of 3:1) on a reduced graphene oxide (rGO) support. The material was prepared via the spontaneous redox reaction between rGO, PdCl42− and PtCl42− without any additional reductant or surfactant. Unlike known Pt-based sensors, the use of Pt3Pd NPs results in an ultrasensitive ASV approach for sensing glucose even at near-neutral pH values. If operated at a working voltage as low as 0.06 V (vs. SCE), the modified electrode can detect glucose in the 2 nM to 300 μM concentration range. The lowest detectable concentration is 2 nM which is much lower than the LODs obtained with other amperometric i-t type sensing approaches, most of which have LODs at a μM level. The sensor is not interfered by the presence of 0.1 M of NaCl. (author)

  1. Determination of water in room temperature ionic liquids by cathodic stripping voltammetry at a gold electrode.

    Science.gov (United States)

    Zhao, Chuan; Bond, Alan M; Lu, Xunyu

    2012-03-20

    An electrochemical method based on cathodic stripping voltammetry at a gold electrode has been developed for the determination of water in ionic liquids. The technique has been applied to two aprotic ionic liquids, (1-butyl-3-ethylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium hexafluorophosphate), and two protic ionic liquids, (bis(2-hydroxyethyl)ammonium acetate and triethylammonium acetate). When water is present in an ionic liquid, electrooxidation of a gold electrode forms gold oxides. Thus, application of an anodic potential scan or holding the potential of the electrode at a very positive value leads to accumulation of an oxide film. On applying a cathodic potential scan, a sensitive stripping peak is produced as a result of the reduction of gold oxide back to gold. The magnitude of the peak current generated from the stripping process is a function of the water concentration in an ionic liquid. The method requires no addition of reagents and can be used for the sensitive and in situ determination of water present in small volumes of ionic liquids. Importantly, the method allows the determination of water in the carboxylic acid-based ionic liquids, such as acetate-based protic ionic liquids, where the widely used Karl Fischer titration method suffering from an esterification side reaction which generates water as a side product.

  2. Determination of Lead Ion in Water by Anodic Stripping Square Wave Voltammetry%阳极溶出方波伏安法测定水体中的铅离子

    Institute of Scientific and Technical Information of China (English)

    王兴磊; 闫秀玲; 何晓燕

    2015-01-01

    To establish a method for determination of the lead ion content of the water by square wave anodic stripping voltammeter. In solution of 0.10 mol/ L NH4Cl at pH=2~3, sensitive stripping peak of Pb (Ⅱ) was ob⁃served. The peak potential of the wave was -0.49 V (vs. SCE). Measured within the range of 0.03~5.0 mg/L, the mass concentration of Pb( Ⅱ) and peak height showed a good linear relationship (R2≥0.9942), linear regression equation was Y=0.17894X+1.87466. The average recovery rates were 89.3%~106.5%, and relative standard devia⁃tion (RSDs) were 3.2%~9.1%(n=6), at the spiked level 0.01, 0.02, 0.1 mg/L, in water which Cu(Ⅱ) content was 0.0581 mg/L. Limit of qualitative of the method(LOD)was 0.01 mg/L. Results show that the method was convenient operation, high sensitivity, good reproducibility, could meet determination of Pb(Ⅱ) content in surface water,waste⁃water and domestic water.%建立了阳极溶出方波伏安法测定水体中铅离子的方法.在pH=2~3,浓度为0.10 mol/L的NH4Cl溶液中,Pb2+于-0.49 V(vs. SCE)产生灵敏的溶出峰,其峰高与离子浓度在0.03~5.0 mg/L范围内,呈良好的线性关系,相关系数R2=0.9942,线性方程为Y=0.17894X+1.87466,在Pb2+本底值为0.0581 mg/L 水体中添加3个水平(0.01、0.02、0.1 mg/L),平均回收率在89.3%~106.5%之间,相对标准偏差(RSD)为3.2%~9.1%(n=6),检出限(LOD)为0.01 mg/L.本方法操作简便、安全、快速、灵敏度高、重现性好,适合于废水、地表水及生活用水中铅的测定.

  3. 阳极溶出方波伏安法测定水体中的铜离子%Determination of Copper Ion in Water by Anodic Stripping Square Wave Voltammetry

    Institute of Scientific and Technical Information of China (English)

    王兴磊; 张艺

    2015-01-01

    建立了阳极溶出方波伏安法测定水体中的铜离子的方法。在浓度为0.15 mol/L, pH=5.0的NH4 Cl溶液中,于-0.11 V( vs.SCE)产生Cu2+的灵敏峰,其峰高与离子浓度在0.02~2.0 mg/L范围内,呈良好的线性关系,相关系数R2=0.9992,线性方程为Y=60.2785X+0.1030,在Cu2+本底值为0.0208 mg/L水体中添加3个水平(0.02、0.04、0.10 mg/L)平均回收率在89.3%~106.5%之间,相对标准偏差(RSDs)为3.2%~9.1%(n=6),检出限(LOD)为0.005 mg/L。本方法操作简便迅速,灵敏度高,重现性好,能够满足水体中检测铜离子要求。%A method for determination of the copper ion content of the water by square wave anodic stripping voltammeter was established.In solution of 0.15 mol/L NH4 Cl at pH=5 , sensitive stripping peak of Cu (Ⅱ) was observed.The peak potential of the wave was-0.11 V ( vs.SCE) .Measured within the range of 0.02~2.0 mg/L, the mass concentration of Cu (Ⅱ) and peak height showed a good linear relationship ( R2≥0.9992 ) , linear regression equation was Y=60.2785X+0.1030.The average recovery rates were 89.3%~106.5%, and relative standard deviation (RSDs) were 3.2%~9.1%( n=6), at the spiked level 0.02, 0.04, 0.10 mg/L, in water with Cu (Ⅱ) content 0.0208 mg/L.Limit of qualitative of the method( LOD) was 0.005 mg/L.Results showed that the method was convenient operation, high sensitivity, good reproducibility, could meet determination of Cu(Ⅱ) content in water.

  4. Determination of water-soluble and insoluble (dilute-HCl-extractable) fractions of Cd, Pb and Cu in Antarctic aerosol by square wave anodic stripping voltammetry: distribution and summer seasonal evolution at Terra Nova Bay (Victoria Land)

    Energy Technology Data Exchange (ETDEWEB)

    Annibaldi, A.; Truzzi, C.; Illuminati, S.; Bassotti, E.; Scarponi, G. [Polytechnic University of Marche - Ancona, Department of Marine Science, Ancona (Italy)

    2007-02-15

    Eight PM10 aerosol samples were collected in the vicinity of the ''Mario Zucchelli'' Italian Antarctic Station (formerly Terra Nova Bay Station) during the 2000-2001 austral summer using a high-volume sampler and precleaned cellulose filters. The aerosol mass was determined by differential weighing of filters carried out in a clean chemistry laboratory under controlled temperature and humidity. A two-step sequential extraction procedure was used to separate the water-soluble and the insoluble (dilute-HCl-extractable) fractions. Cd, Pb and Cu were determined in the two fractions using an ultrasensitive square wave anodic stripping voltammetric (SWASV) procedure set up for and applied to aerosol samples for the first time. Total extractable metals showed maxima at midsummer for Cd and Pb and a less clear trend for Cu. In particular, particulate metal concentrations ranged as follows: Cd 0.84-9.2 {mu}g g{sup -1} (average 4.7 {mu}g g{sup -1}), Pb 13.2-81 {mu}g g{sup -1} (average 33 {mu}g g{sup -1}), Cu 126-628 {mu}g g{sup -1} (average 378 {mu}g g{sup -1}). In terms of atmospheric concentration, the values were: Cd 0.55-6.3 pg m{sup -3} (average 3.4 pg m{sup -3}), Pb 8.7-48 pg m{sup -3} (average 24 pg m{sup -3}), Cu 75-365 pg m{sup -3} (average 266 pg m{sup -3}). At the beginning of the season the three metals appear widely distributed in the insoluble (HCl-extractable) fraction (higher proportions for Cd and Pb, 90-100%, and lower for Cu, 70-90%) with maxima in the second half of December. The soluble fraction then increases, and at the end of the season Cd and Pb are approximately equidistributed between the two fractions, while for Cu the soluble fraction reaches its maximum level of 36%. Practically negligible contributions are estimated for crustal and sea-spray sources. Low but significant volcanic contributions are estimated for Cd and Pb ({proportional_to}10% and {proportional_to}5%, respectively), while there is an evident although not

  5. Determination of water-soluble and insoluble (dilute-HCl-extractable) fractions of Cd, Pb and Cu in Antarctic aerosol by square wave anodic stripping voltammetry: distribution and summer seasonal evolution at Terra Nova Bay (Victoria Land).

    Science.gov (United States)

    Annibaldi, A; Truzzi, C; Illuminati, S; Bassotti, E; Scarponi, G

    2007-02-01

    Eight PM10 aerosol samples were collected in the vicinity of the "Mario Zucchelli" Italian Antarctic Station (formerly Terra Nova Bay Station) during the 2000-2001 austral summer using a high-volume sampler and precleaned cellulose filters. The aerosol mass was determined by differential weighing of filters carried out in a clean chemistry laboratory under controlled temperature and humidity. A two-step sequential extraction procedure was used to separate the water-soluble and the insoluble (dilute-HCl-extractable) fractions. Cd, Pb and Cu were determined in the two fractions using an ultrasensitive square wave anodic stripping voltammetric (SWASV) procedure set up for and applied to aerosol samples for the first time. Total extractable metals showed maxima at midsummer for Cd and Pb and a less clear trend for Cu. In particular, particulate metal concentrations ranged as follows: Cd 0.84-9.2 microg g(-1) (average 4.7 microg g(-1)), Pb 13.2-81 microg g(-1) (average 33 microg g(-1)), Cu 126-628 microg g(-1) (average 378 microg g(-1)). In terms of atmospheric concentration, the values were: Cd 0.55-6.3 pg m(-3) (average 3.4 pg m(-3)), Pb 8.7-48 pg m(-3) (average 24 pg m(-3)), Cu 75-365 pg m(-3) (average 266 pg m(-3)). At the beginning of the season the three metals appear widely distributed in the insoluble (HCl-extractable) fraction (higher proportions for Cd and Pb, 90-100%, and lower for Cu, 70-90%) with maxima in the second half of December. The soluble fraction then increases, and at the end of the season Cd and Pb are approximately equidistributed between the two fractions, while for Cu the soluble fraction reaches its maximum level of 36%. Practically negligible contributions are estimated for crustal and sea-spray sources. Low but significant volcanic contributions are estimated for Cd and Pb (approximately 10% and approximately 5%, respectively), while there is an evident although not quantified marine biogenic source, at least for Cd. The estimated natural

  6. Bare and Polymer-Coated Indium Tin Oxide as Working Electrodes for Manganese Cathodic Stripping Voltammetry.

    Science.gov (United States)

    Rusinek, Cory A; Bange, Adam; Warren, Mercedes; Kang, Wenjing; Nahan, Keaton; Papautsky, Ian; Heineman, William R

    2016-04-19

    Though an essential metal in the body, manganese (Mn) has a number of health implications when found in excess that are magnified by chronic exposure. These health complications include neurotoxicity, memory loss, infertility in males, and development of a neurologic psychiatric disorder, manganism. Thus, trace detection in environmental samples is increasingly important. Few electrode materials are able to reach the negative reductive potential of Mn required for anodic stripping voltammetry (ASV), so cathodic stripping voltammetry (CSV) has been shown to be a viable alternative. We demonstrate Mn CSV using an indium tin oxide (ITO) working electrode both bare and coated with a sulfonated charge selective polymer film, polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene-sulfonate (SSEBS). ITO itself proved to be an excellent electrode material for Mn CSV, achieving a calculated detection limit of 5 nM (0.3 ppb) with a deposition time of 3 min. Coating the ITO with the SSEBS polymer was found to increase the sensitivity and lower the detection limit to 1 nM (0.06 ppb). This polymer modified electrode offers excellent selectivity for Mn as no interferences were observed from other metal ions tested (Zn(2+), Cd(2+), Pb(2+), In(3+), Sb(3+), Al(3+), Ba(2+), Co(2+), Cu(2+), Ni(3+), Bi(3+), and Sn(2+)) except Fe(2+), which was found to interfere with the analytical signal for Mn(2+) at a ratio 20:1 (Fe(2+)/Mn(2+)). The applicability of this procedure to the analysis of tap, river, and pond water samples was demonstrated. This simple, sensitive analytical method using ITO and SSEBS-ITO could be applied to a number of electroactive transition metals detectable by CSV. PMID:26980322

  7. Copper-Based Electrochemical Sensor with Palladium Electrode for Cathodic Stripping Voltammetry of Manganese

    OpenAIRE

    Kang, Wenjing; Pei, Xing; Bange, Adam; Haynes, Erin N.; Heineman, William R.; Papautsky, Ian

    2014-01-01

    In this work, we report on the development of a palladium-based, microfabricated point-of-care electrochemical sensor for the determination of manganese using square wave cathodic stripping voltammetry. Heavy metals require careful monitoring, yet current methods are too complex for a point-of-care system. Voltammetry offers an attractive approach to metal detection on the microscale, but traditional carbon, gold, or platinum electrodes are difficult or expensive to microfabricate, preventing...

  8. Anodic stripping voltammetric determination of Zn, Pb and Cu traces in whisky samples

    Energy Technology Data Exchange (ETDEWEB)

    Barbeira, P.J.S. [Departamento de Quimica - ICEx - UFMG, Belo Horizonte, MG (Brazil); Stradiotto, N.R. [Departamento de Quimica - FFCLRP - USP, Ribeirao Preto, SP (Brazil)

    1998-07-01

    The simultaneous ``in natura`` determination of trace Zn, Pb and Cu in whisky samples by anodic stripping voltammetry (ASV), using a hanging mercury drop electrode, without previous treatment or addition of supporting electrolyte is described. The choice of an appropriate stripping voltammetric method and deposition potential minimizes the influence of the organic content and ensures a good reproducibility of the measurements. The reliability of the method was tested comparing the results with those of atomic absorption spectroscopy (AAS), with differences of about 10%. The method allows the determination of heavy metal ions in the {mu}g L{sup -1} range. (orig.) With 3 figs., 1 tab., 18 refs.

  9. Characterization of bronzes by abrasive stripping voltammetry and thin layer chromatography

    OpenAIRE

    Komorsky-Lovrić, Šebojka; Horvat, Alka J.M.; Ivanković, Danijela

    2006-01-01

    Corrosion potentials of five samples of bronzes having different compositions and the stripping peak potentials of their main components were determined by abrasive stripping voltammetry. Using thin-layer chromatography in combination with electrochemical dissolution of bronzes in the two electrode sampler, the ions of tin, copper, lead and nickel were detected as the products of electro-oxidation of bronzes. It is shown that the dissolution of tin is preferential at low potential differences...

  10. Adsorptive Stripping Voltammetry of Environmental Indicators: Determination of Zinc in Algae

    Science.gov (United States)

    Collado-Sanchez, C.; Hernandez-Brito, J. J.; Perez-Pena, J.; Torres-Padron, M. E.; Gelado-Caballero, M. D.

    2005-01-01

    A method for sample preparation and for the determination of average zinc content in algae using adsorptive stripping voltammetry are described. The students gain important didactic advantages through metal determination in environmental matrices, which include carrying out clean protocols for sampling and handling, and digesting samples using…

  11. Determination of trace mercury in water based on N-octylpyridinium ionic liquids preconcentration and stripping voltammetry.

    Science.gov (United States)

    Li, Zhenhan; Xia, Shanhong; Wang, Jinfen; Bian, Chao; Tong, Jianhua

    2016-01-15

    A novel method for determination of trace mercury in water is developed. The method is performed by extracting mercury firstly with ionic liquids (ILs) and then detecting the concentration of mercury in organic media with anodic stripping voltammetry. Liquid-liquid extraction of mercury(II) ions by four ionic liquids with N-octylpyridinium cations ([OPy](+)) was studied. N-octylpyridinium tetrafluoroborate and N-octylpyridinium trifluoromethylsulfonate were found to be efficient and selective extractant for mercury. Temperature controlled dispersive liquid phase microextraction (TC-DLPME) technique was utilized to improve the performance of preconcentration. After extraction, precipitated IL was diluted by acetonitrile buffer and mercury was detected by differential pulse stripping voltammetry (DPSV) with gold disc electrode. Mercury was enriched by 17 times while interfering ions were reduced by two orders of magnitude in the organic media under optimum condition. Sensitivity and selectivity for electrochemical determination of mercury were improved by using the proposed method. Tap, pond and waste water samples were analyzed with recoveries ranging from 81% to 107% and detection limit of 0.05 μg/L.

  12. Disposable Copper-Based Electrochemical Sensor for Anodic Stripping Voltammetry

    OpenAIRE

    Pei, Xing; Kang, Wenjing; Yue, Wei; Bange, Adam; Heineman, William R.; Papautsky, Ian

    2014-01-01

    In this work, we report the first copper-based point-of-care sensor for electrochemical measurements demonstrated by zinc determination in blood serum. Heavy metals require careful monitoring, yet current methods are too complex for a point-of-care system. Electrochemistry offers a simple approach to metal detection on the microscale, but traditional carbon, gold (Au), or platinum (Pt) electrodes are difficult or expensive to microfabricate, preventing widespread use. Our sensor features a ne...

  13. Voltammetry at the Thin-Film Mercury Electrode (TFME).

    Science.gov (United States)

    Pomeroy, R. S.; And Others

    1989-01-01

    Reviewed is the use of the Thin-Film Mercury Electrode for anodic stripping voltammetry, simple voltammetry of solution cations and cathodic stripping voltammetry for the determination of an environmentally important molecule, thiourea. The construction of a simple potentiostat and applications for student laboratory courses are included. (CW)

  14. Square wave adsorptive stripping voltammetry of nickel and cobalt at wall-jet electrodes in continuous flow

    OpenAIRE

    Brett, Christopher M. A.; Garcia, M. Beatriz Quinaz; Lima, José L.F.C.

    1996-01-01

    Square wave adsorptive stripping voltammetry (SWAdSV) of nickel and cobalt at wall-jet electrodes in a continuous flow system has been evaluated. Characteristics and advantages relative to differential pulse adsorptive stripping voltammetry (DPAdSV) in continuous flow systems are explored. Under optimized experimental conditions, sensitivity is approximately a factor of ten higher than DPAdSV, and one-nanomolar detection limits are achieved. Solution deoxygenation is unnecessary and sample th...

  15. Anodic stripping voltammetric determination of arsenic(III) using a glassy carbon electrode modified with gold-palladium bimetallic nanoparticles

    International Nuclear Information System (INIS)

    A glassy carbon electrode (GC E) was modified by casting gold-palladium (Au-Pd) nanoparticles onto its surface and then used for the determination of As(III) by stripping voltammetry. The structure and electrochemical properties of the nanoparticles were characterized by UV-vis spectroscopy, high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and cyclic voltammetry. Anodic stripping voltammetry of the modified electrode was performed in solutions of pH 4.5 containing various concentrations of arsenite. The modified GC E exhibited good response towards As(III), with a limit of detection of around 0.25 ppb which is much lower than the current EPA standard of 10 ppb. The electrode is stable and not interfered by Pb(II), Cd(II), Mn(II), and Zn(II). (author)

  16. Copper-based electrochemical sensor with palladium electrode for cathodic stripping voltammetry of manganese.

    Science.gov (United States)

    Kang, Wenjing; Pei, Xing; Bange, Adam; Haynes, Erin N; Heineman, William R; Papautsky, Ian

    2014-12-16

    In this work, we report on the development of a palladium-based, microfabricated point-of-care electrochemical sensor for the determination of manganese using square wave cathodic stripping voltammetry. Heavy metals require careful monitoring, yet current methods are too complex for a point-of-care system. Voltammetry offers an attractive approach to metal detection on the microscale, but traditional carbon, gold, or platinum electrodes are difficult or expensive to microfabricate, preventing widespread use. Our sensor uses palladium working and auxiliary electrodes and integrates them with a copper-based reference electrode for simple fabrication and compatibility with microfabrication and printed circuit board processing, while maintaining competitive performance in electrochemical detection. Copper electrodes were prepared on glass substrate using a combination of microfabrication procedures followed by electrodeposition of palladium. The disposable sensor system was formed by bonding a poly(dimethylsiloxane) (PDMS) well to the glass substrate. Cathodic stripping voltammetry of manganese using our new disposable palladium-based sensors exhibited 334 nM (18.3 ppb) limit of detection in borate buffer. The sensor was used to demonstrate manganese determination in natural water samples from a pond in Burnet Woods, located in Cincinnati, OH, and the Ohio River. PMID:25476591

  17. Electrochemistry and analytical determination of lysergic acid diethylamide (LSD) via adsorptive stripping voltammetry.

    Science.gov (United States)

    Merli, Daniele; Zamboni, Daniele; Protti, Stefano; Pesavento, Maria; Profumo, Antonella

    2014-12-01

    Lysergic acid diethylamide (LSD) is hardly detectable and quantifiable in biological samples because of its low active dose. Although several analytical tests are available, routine analysis of this drug is rarely performed. In this article, we report a simple and accurate method for the determination of LSD, based on adsorptive stripping voltammetry in DMF/tetrabutylammonium perchlorate, with a linear range of 1-90 ng L(-1) for deposition times of 50s. LOD of 1.4 ng L(-1) and LOQ of 4.3 ng L(-1) were found. The method can be also applied to biological samples after a simple extraction with 1-chlorobutane.

  18. Determination of Lamotrigine in Pharmaceutical Preparations by Adsorptive Stripping Voltammetry Using Screen Printed Electrodes

    OpenAIRE

    M. Julia Arcos-Martínez; M. Encarnación Burgoa Calvo; Olga Domínguez-Renedo

    2008-01-01

    This paper describes a procedure that has been optimized for the determination of lamotrigine by Differential Pulse Adsorptive Stripping Voltammetry (DPAdSV) using carbon screen-printed electrodes (CSPE) and mercury coated carbon screen-printed electrodes. Selection of the experimental parameters was made using experimental design methodology. The detection limit found was 5.0 x 10-6 M and 2.0 x 10-6 M for the non modified and Hg modified CSPE, respectively. In terms of reproducibility, the p...

  19. Determination of copper in whole blood by differential pulse adsorptive stripping voltammetry

    Directory of Open Access Journals (Sweden)

    Tarik Attar

    2014-02-01

    Full Text Available A selective and sensitive method for determination of copper in blood by adsorptive differential pulse cathodic stripping voltammetry is presented. The method is based on adsorptive accumulation of the complexes of Cu (II ions with benzenesulfonyl hydrazide onto hanging mercury drop electrode (HMDE, followed by the reduction of the adsorbed species by differential pulse cathodic stripping voltammetry. The effect of various parameters such as supporting electrolyte, concentration of benzenesulfonyl hydrazide, accumulation potential, accumulation time and stirring rate on the selectivity and sensitivity were studied. The optimum conditions for determination of copper include perchloric acid 0.03 M, concentration of benzenesulfonyl hydrazide 7.5×10-5 M, the accumulation potential of -350 mV (vs. Ag/AgCl, the accumulation time of 50 s, and the scan rate of 50 mV s-1. Under optimized conditions, linear calibration curves were established for the concentration of Cu (II in the range of 0.62-275 ng mL-1, with detection limit of 0.186 ng mL-1 for Cu (II. The procedure was successfully applied to the determination of copper ion in whole blood samples.

  20. Redox magnetohydrodynamics enhancement of stripping voltammetry of lead(II), cadmium(II) and zinc(II) ions using 1,4-benzoquinone as an alternative pumping species.

    Science.gov (United States)

    Ensafi, Ali A; Nazari, Z; Fritsch, I

    2012-01-21

    Differential pulse anodic stripping voltammetry (DPASV) coupled with redox-magnetohydrodynamics (MHD) is used to enhance the anodic stripping voltammetry (ASV) response using a mercury thin film-glassy carbon electrode. The sensitivity increased to at least a factor of two (at 1.2 T) and is facilitated by using 20.0 mmol L(-1) 1,4-benzoquinone as an alternative pumping species to enhance ASV by redox-MHD. The MHD force formed by the cross-product of ion flux with magnetic field induces solution convection during the deposition step, enhancing mass transport of the analytes to the electrode surface and increasing their preconcentrated quantity in the mercury thin film. Therefore, larger ASV peaks and improved sensitivities are obtained, compared with analyses performed without a magnet. The influence of pH, 1,4-benzoquinone concentration, accumulation potential, and time are also investigated. Detection limits of 0.05, 0.09 and 2.2 ng mL(-1) Cd(II), Pb(II) and Zn(II) were established with an accumulation time of 65 s. The method is used for the analysis of Cd(II), Pb(II) and Zn(II) in different water samples, certified reference materials, and saliva samples with satisfactory results. PMID:22116833

  1. The Graphene/l-Cysteine/Gold-Modified Electrode for the Differential Pulse Stripping Voltammetry Detection of Trace Levels of Cadmium

    Directory of Open Access Journals (Sweden)

    Yu Song

    2016-06-01

    Full Text Available Cadmium(II is a common water pollutant with high toxicity. It is of significant importance for detecting aqueous contaminants accurately, as these contaminants are harmful to human health and environment. This paper describes the fabrication, characterization, and application of an environment-friendly graphene (Gr/l-cysteine/gold electrode to detect trace levels of cadmium (Cd by differential pulse stripping voltammetry (DPSV. The influence of hydrogen overflow was decreased and the current response was enhanced because the modified graphene extended the potential range of the electrode. The Gr/l-cysteine/gold electrode showed high electrochemical conductivity, producing a marked increase in anodic peak currents (vs. the glass carbon electrode (GCE and boron-doped diamond (BDD electrode. The calculated detection limits are 1.15, 0.30, and 1.42 µg/L, and the sensitivities go up to 0.18, 21.69, and 152.0 nA·mm−2·µg−1·L for, respectively, the BDD electrode, the GCE, and the Gr/l-cysteine/gold electrode. It was shown that the Gr/l-cysteine/gold-modified electrode is an effective means for obtaining highly selective and sensitive electrodes to detect trace levels of cadmium.

  2. Determination of Lamotrigine in Pharmaceutical Preparations by Adsorptive Stripping Voltammetry Using Screen Printed Electrodes

    Directory of Open Access Journals (Sweden)

    M. Julia Arcos-Martínez

    2008-07-01

    Full Text Available This paper describes a procedure that has been optimized for the determination of lamotrigine by Differential Pulse Adsorptive Stripping Voltammetry (DPAdSV using carbon screen-printed electrodes (CSPE and mercury coated carbon screen-printed electrodes. Selection of the experimental parameters was made using experimental design methodology. The detection limit found was 5.0 x 10-6 M and 2.0 x 10-6 M for the non modified and Hg modified CSPE, respectively. In terms of reproducibility, the precision of the above mentioned methods was calculated in %RSD values at 9.83% for CSPE and 2.73% for Hg-CSPE. The Hg-coated CSPEs developed in this work were successfully applied in the determination of lamotrigine in pharmaceutical preparations.

  3. Determination of selenium in freshwaters by cathodic stripping voltammetry after UV irradiation

    International Nuclear Information System (INIS)

    An analytical method was developed for the determination of total dissolved selenium in fresh waters, using linear sweep cathodic stripping voltammetry (CSV) in combination with UV photolytic digestion. Both the CSV method, based on the electrodeposition and stripping of Cu(2)Se, and the UV irradiation procedure were investigated in detail. In the presence of dissolved organic substances, as in freshwaters, Se(VI) is reduced to Se(IV) by UV irradiation in 0.1M hydrochloric acid. Glucose can be used as the carbon source in samples low in natural dissolved organic carbon (DOC). The photolytic yields of Se(IV) were about 90% in both cases. Five freshwater samples were analysed for total selenium by CSV after UV photolysis, and by hydride generation atomic absorption spectrometry (HG-AAS) after oxidative digestion followed by reduction with hydrochloric acid. The results agreed well and the concentrations were in the range 70-190 ng/l., well above the detection limit of the CSV method at 2 ng/l. (author)

  4. Speciation study of aluminium in beverages by Competitive Ligand Exchange-Adsorptive Stripping Voltammetry.

    Science.gov (United States)

    Magnier, A; Fekete, V; Van Loco, J; Bolle, F; Elskens, M

    2014-05-01

    Competitive Ligand Exchange-Adsorptive Stripping Voltammetry (CLE-AdSV) was used for determining the speciation of aluminium in commonly consumed beverages (water, tea, infusion, coffee, orange juice, tomato juice, beer and red wine). Aluminium determination involves the adsorption of Al-complexes with the ligand cupferron onto a hanging mercury drop electrode. All samples were studied at pH 6.5 with an accumulation step at -0.60 V (all potential values in the paper are given versus the Ag/AgCl, [KCl]=3 M reference electrode) during 60 s, and a final cupferron concentration of 4 × 10(-4)M. These conditions were used to establish (i) the concentration of electro-labile aluminium, (ii) the range of ligand concentrations and (iii) the conditional stability constants of beverage samples using titration procedures. The results based on Ruzic plots were compared to computer simulation with Visual MINTEQ. This comparison suggests that labile monomeric Al-forms and soluble organic complexes of low molecular weight can be quantified by the CLE-AdSV procedure. Overall the relative uncertainties on the determination of the electro-active Al fraction and the complexing parameters, i.e., concentration and conditional stability constant of natural ligands in the samples, are less than 15%. Thanks to these results, information on Al bioavailability in beverages was collected and discussed. This study also illustrates the value of computer simulations when complex, time-consuming voltammetric techniques are applied.

  5. Determination of Selenium in infant formula by differential pulse cathodic stripping voltammetry

    Directory of Open Access Journals (Sweden)

    "Oveisi MR

    2002-07-01

    Full Text Available Selenium as a nonmetallic chemical element has received high attention of biologists because of its dual role as an essential trace nutrient and a toxic element. This interest has created a need for reliable analytical methods for determination of selenium. In this investigation determination of selenium by differential pulse cathodic stripping voltammetry and the influence of various parameters such as deposition potentials, deposition time. Cu concentration pH, etc. on selenium peak in voltammogram are described. Determination of selenium was accomplished in mixture of acetic acid, hydrochloric acid and sodium chloride buffer (pH=1 with a scan rate of 60 mv/s and a pulse height of 100 my by hanging mercury drop electrode (HMDE as working electrode. The solution was stirred during pre-electrolysis at - 350 mv (vs SCE for 30 s and the potential was scanned between - 350 mv and - 800 mv. The determination limit of the method was 0.005 mg/kg for the sample. The calibration curves were linear in the range of 0-30 μg/L (R2=0.996, p<0.001. Repeatability of the method at concentrations of 30 and 0.5 μg/L were 2.5 and 10.5% respectively.

  6. Determination of Arsenite in Water by Anodic Stripping Voltammetry Using Au- Pd Bimetallic Nanoparticles Modified Glassy Carbon Electrode%金-钯双金属纳米颗粒修饰玻碳电极阳极溶出伏安法测定三价砷的方法研究

    Institute of Scientific and Technical Information of China (English)

    蓝月存; 罗汉金; 王灿

    2012-01-01

    An anodic stripping voltammetric method for the determination of arsenite using Au - Pd bimetallic nanoparticles( Au-Pd NPs) modified glassy carbon electrode (Au -Pd/GCE) was developed. The structural information and electrochemical activities of the synthesized Au - Pd nanoparti-cles were investigated with UV - Vis spectroscopy, high resolution transmission electron microscopy ( HRTEM) and cyclic voltammetric ( CV) method. The determination of arsenic was conducted by square wave voltammetric(SWV) method. Effects of deposition potential and SWV parameters (such as frequency, increment and amplitude) on the current intensity of arsenite were investigated. The results showed that Au - Pd bimetallic nanoparticles presented a core - shell structure in shape and the modified electrode exhibited the characteristic peaks of both Au and Pd. A sensitive anodic stripping peak of arsenite appeared at about 0. 30 V, and the peak current was linear with concentration of arsenite in the range of 0. 5-20 μg/L with a limit of detection ( LOD) of 0. 15 μg/L, which is far below the maximum guideline value(10μ/L) set by World Health Organization(WHO). The modified electrode exhibited a good repeatability toward the consecutive determination of arsenite. The interference experiments also showed that except for Cu( II ), the existance of Pb( II ) , Cd( H ) and Zn( II) would not affect the detection of As( 1).%研究了金-钯双金属纳米颗粒修饰电极测定痕量砷的阳极溶出伏安法.采用紫外可见分光光度法、高分辨透射电镜及循环伏安法对颗粒的结构和电化学特性进行表征.采用方波伏安法测定三价砷,探讨了富集电位和方波伏安参数如频率、增幅、波幅以及干扰离子等对测定结果的影响.实验结果表明:金-钯双金属纳米颗粒呈壳-核结构;砷在0.30 V出现灵敏的阳极溶出伏安峰,峰电流与砷质量浓度在0.5~20 μg/L范围内呈良好的线性关系,检出限为0.15 μg/L;

  7. A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc

    International Nuclear Information System (INIS)

    We report on a novel tin-bismuth alloy electrode (SnBiE) for the determination of trace concentrations of zinc ions by square-wave anodic stripping voltammetry without deoxygenation. The SnBiE has the advantages of easy fabrication and low cost, and does not require a pre-treatment (in terms of modification) prior to measurements. A study on the potential window of the electrode revealed a high hydrogen overvoltage though a limited anodic range due to the oxidation of tin. The effects of pH value, accumulation potential, and accumulation time were optimized with respect to the determination of trace zinc(II) at pH 5. 0. The response of the SnBiE to zinc(II) ion is linear in the 0.5-25 μM concentration range. The detection limit is 50 nM (after 60 s of accumulation). The SnBiE was applied to the determination of zinc(II) in wines and honeys, and the results were consistent with those of AAS. (author)

  8. Determination of tryptamine in foods using square wave adsorptive stripping voltammetry.

    Science.gov (United States)

    Costa, Daniel J E; Martínez, Ana M; Ribeiro, Williame F; Bichinho, Kátia M; Di Nezio, María Susana; Pistonesi, Marcelo F; Araujo, Mario C U

    2016-07-01

    Tryptamine, a biogenic amine, is an indole derivative with an electrophilic substituent at the C3 position of the pyrrole ring of the indole moiety. The electrochemical oxidation of tryptamine was investigated using glassy carbon electrode (GCE), and focusing on trace level determination in food products by square wave adsorptive stripping voltammetry (SWAdSV). The electrochemical responses of tryptamine were evaluated using differing voltammetric techniques over a wide pH range, a quasi-reversible electron-transfer to redox system represented by coupled peaks P1-P3, and an irreversible reaction for peak P2 were demonstrated. The proton and electron counts associated with the oxidation reactions were estimated. The nature of the mass transfer process was predominantly diffusion-limited for the oxidation process of P1, the most selective and sensitive analytical response (acetate buffer solution pH 5.3), being used for the development of SWAdSV method, under optimum conditions. The excellent response allowed the development of an electroanalytical method with a linear response range of from 4.7-54.5)×10(-)(8)molL(-1), low detection limit (0.8×10(-)(9)molL(-)(1)), and quantification limit (2.7×10(-9)molL(-1)), and acceptable levels of repeatability (3.6%), and reproducibility (3.8%). Tryptamine content was determined in bananas, tomatoes, cheese (mozzarella and gorgonzola), and cold meats (chicken sausage and pepperoni sausage), yielding recoveries above 90%, with excellent analytical performance using simple and low cost instrumentation. PMID:27154658

  9. Quantitative Analysis of Trace Chromium in Blood Samples. Combination of the Advanced Oxidation Process with Catalytic Adsorptive Stripping Voltammetry

    OpenAIRE

    Yong, Li; Armstrong, Kristie C.; Dansby-Sparks, Royce N.; Carrington, Nathan A.; Chambers, James Q.; Xue, Zi-Ling

    2006-01-01

    A new method for pretreating blood samples for trace Cr analysis is described. The Advanced Oxidation Process (AOP with H2O2 and 5.5-W irradiation for 60 min) is used to remove biological/organic species for subsequent analysis. Prior to the AOP pretreatment, acid (HNO3) is used at pH 3.0 to inhibit the enzyme catalase in the blood samples. Catalytic Adsorptive Stripping Voltammetry (CAdSV) at a bismuth film electrode (BiFE) gives Cr concentration of 6.0 ± 0.3 ppb in the blood samples. This c...

  10. Determination Of The Aflatoxin B1 In Ground Nut By Differential Pulse Cathodic Stripping Voltammetry (Dpcsv) Technique

    OpenAIRE

    Yaacob, Mohammad Hadzri; Yusoff, Abdull Rahim Hj. Mohd.; Ahamad, Rahmalan

    2009-01-01

    An electro analytical method has been developed for the detection and determination of the 2,3,6a,9a-tetrahydro- 4-methoxycyclo penta[c] furo[3’,2’:4,5] furo [2,3-h][l] benzopyran-1,11-dione (aflatoxin B1, AFB1) by a differential pulse cathodic stripping voltammetry on a hanging mercury drop electrode (HMDE) in aqueous solution with Britton-Robinson buffer (BRb) as supporting electrolyte. Effect of instrumental parameters such as accumulation potential (Eacc), accumulation time (tacc) and ...

  11. Differential Pulse Anodic Stripping Voltammetric Determination of Lead with Heparin Modified Electrode

    Institute of Scientific and Technical Information of China (English)

    LI,Nian-Bing(李念兵); DUAN,Jian-Ping(段建平); CHEN,Guo-Nan(陈国南)

    2004-01-01

    A novel differential pulse anodic stripping voltammetry for the determination of trace amounts of lead, using a biomacromolecule heparin drop-coated modified glassy carbon electrode, has been described. Pb2+ was deposited on the surface of a heparin-modified electrode at - 1.0 V (vs. SCE) via forming Pb2+-heparin and subsequent reduction at the electrode. In the following step, Pb-heparin was oxidized, and voltammograms were recorded by scanning the potential in a positive direction. Conditions were optimized with respect to the pH of the medium, the mass of drop-coated heparin, accumulation potential and accumulation time. The peak current was proportional to the Pb2+ concentration in the range of 2.0× 10-9 to 7.0× 10-7 mol/L, The detection limit was 3.0× 10-10 mol/L.The relative standard deviation was 4.83% for 1.0× 10-8mol/L Pb2- (n= 10). The developed method has been applied to the determination of Pb2- in water samples with satisfactory results.

  12. Hair analysis. Part 2. Differential pulse anodic stripping voltammetric determination of thallium in human hair samples of persons in permanent contact with lead in their workplace

    International Nuclear Information System (INIS)

    The determination of thallium in human hair samples by differential pulse anodic stripping voltammetry after microwave digestion has been presented. Hair samples were collected from the vertex of the scalps of donors who were employed in factories manufacturing lead-acid batteries. The results show that permanent contact with an environment polluted by lead makes it possible to absorb very large amounts of thallium, which is present in this environment only as an impurity of lead. The study also shows that absorption of thallium by workers is a few times 'better' than that of lead

  13. Electrochemical behavior of folic acid at calixarene based chemically modified electrodes and its determination by adsorptive stripping voltammetry

    Energy Technology Data Exchange (ETDEWEB)

    Vaze, Vishwanath D. [Department of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East), Mumbai 400098 (India); Srivastava, Ashwini K. [Department of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East), Mumbai 400098 (India)], E-mail: aksrivastava@chem.mu.ac.in

    2007-12-31

    Voltammetric behavior of folic acid at plain carbon paste electrode and electrode modified with calixarenes has been studied. Two peaks for irreversible oxidation were observed. Out of the three calixarenes chosen for modification of the electrodes, p-tert-butyl-calix[6]arene modified electrode (CME-6) was found to have better sensitivity for folic acid. Chronocoulometric and differential pulse voltammetric studies reveal that folic acid can assemble at CME-6 to form a monolayer whose electron transfer rate is 0.00273 s{sup -1} with 2-electron/2-proton transfer for the peak at +0.71 V against SCE. An adsorption equilibrium constant of 5 x 10{sup 3} l/mol for maximum surface coverage of 2.89 x 10{sup -10} mol/cm{sup 2} was obtained. The current is found to be rectilinear with concentration by differential pulse voltammetry. However, linearity in the lower range of concentration 8.79 x 10{sup -12} M to 1.93 x 10{sup -9} M with correlation coefficient of 0.9920 was achieved by adsorptive stripping voltammetry. The limit of detection obtained was found to be 1.24 x 10{sup -12} M. This method was used for the determination of folic acid in a variety of samples, viz. serum, asparagus, spinach, oranges and multivitamin preparations.

  14. Solar UV-assisted sample preparation of river water for ultra-trace determination of uranium by adsorptive stripping voltammetry

    International Nuclear Information System (INIS)

    The article describes how solar ultraviolet-A radiation can be used to digest samples as needed for voltammetric ultratrace determination of uranium(VI) in river water. We applied adsorptive stripping voltammetry (AdSV) using chloranilic acid as the complexing agent. Samples from the river Warnow in Rostock (Germany) were pretreated with either soft solar UV or wit artificial hard UV from a 30-W source emitting 254-nm light. Samples were irradiated for 12 h, and both methods yielded the same results. We were able to detect around 1 μg.L-1 of uranium(VI) in a sample of river water that also contained dissolved organic carbon at a higher mg.L-1 levels. No AdSV signal was obtained for U(VI) without any UV pre-treatment. Pseudo-polarographic experiments confirmed the dramatic effect of both digestion techniques the the AdSV response. The new method is recommended for use in mobile ultratrace voltammetry of heavy metals for most kinds of natural water samples including tap, spring, ground, sea, and river waters. The direct use of solar radiation for sample pre-treatment represents a sustainable technique for sample preparation that does not consume large quantities of chemicals or energy. (author)

  15. Stripping voltammetry glassy carbon on the study of Cd and Pb heavy metals pollution using anadara antiquata linn bioindicator

    International Nuclear Information System (INIS)

    The presence of cadmium and lead in sea water and shell fish (anadara antiquata linn) bioindicator in Gresik waters by glassy carbon stripping voltammetry was studied at menu 2 parameters as follows: time and potential plating-1000V and 90 second, sweep rate: 375 mV/second, strip time 2 second, electrolyte: aquatrides, pH = 0.4 (for shell fish) and -1000 V and 120 second, 999 mV/se con, 2 second, chloracetic, pH = 5.0. It was found that the mean of Cd and Pb contents in sea water at pH = 7.0, salinity = 28-29 ppm, oxygen content = 7.1-8.1 and temperature = 27-30oC which was monitoring at location 1.2 and location 3.4 were 0.01 and 0.17 ppm, 1.44 and 1.35 ppm respectively. Furthermore the mean of Cd and Pb contents in shell fish at location 1.2 and 3.4 (snail range and shell fish dry weight were reported) were 5.94 and 3.05 ppm, 0,03 and 0,03 ppm. The t-tes for Cd and Pb contents in sea waters and shell fish at location 1,2 compared with location 3.4 were significant and no significant. The accuracy of the method was tested with SRM coppepoda MA-A-1-A-a and W-4. (author)

  16. Determination of Sudan I in drinks containing Sunset yellow by adsorptive stripping voltammetry.

    Science.gov (United States)

    Gómez, Marisol; Arancibia, Verónica; Aliaga, Margarita; Núñez, Claudia; Rojas-Romo, Carlos

    2016-12-01

    An efficient, fast and sensitive method for the determination of Sudan I (SI) in drinks containing Sunset yellow (Sy) is developed and validated using an adsorptive stripping voltammetric procedure. Sy is currently added to a large number of foods; however during their synthesis SI may be produced. The determination is based on adsorption of Sy and SI onto HMDE and later reduction of the azo group at -0.71 and -0.82V, respectively. Using the best set of the experimental conditions (pH 12.3; Eads: -0.40V) for the determination of SI in Sy, a linear response for SI in the concentration range 0.5-27.2μgL(-1) was found, with a detection limit of 1.5μgL(-1) in a tads of only 30s. The method was applied to the determination of SI in commercial drinks with satisfactory results. The presence of SI was confirmed by mass spectrometry. PMID:27374598

  17. Some regularities of metal anodic dissolution in voltammetry with pressed two-electrode cell

    International Nuclear Information System (INIS)

    Mathematical expressions for the distribution of ion concentration of anode-solving metal in the near-electrode layer of a solution for the conditions of a clamp-type two-electrode electrolytic cell have been obtained. A possibility is shown of theoretical calculation of critical parameters of polarographic curves measured during operation according to the given technique. The obtained dependences are suggested to be taken as the basis in the choice of the optimum polarization conditions of the working electrode for determining the thickness of metal coatings using voltametry method. The calculated results have been experimentally tested on the example of anode dissolution of copper, cadmium and silver in the clamp-type cell. 1MNaSO4 (for Cu and Cd), 2MNH4F (for silver) at I=2.5 mA served as background electrolytes

  18. Simultaneous determination of lead, cadmium and zinc in Metro Manila air particulates by anodic stripping voltammetry

    International Nuclear Information System (INIS)

    Air particulate samples were collected from two monitoring stations in Metro Manila using a 'Gent' type dichotomous sampler for pollutant source apportionment studies. Samples were collected in two fractions: a fine fraction with aerodynamic diameter, dpp3: HCL: HF, 4: 1: 1) for at least 20 minutes with subsequent heating at lower power settings for a total of 20 minutes more, effectively decomposed the sample with complete recovery of the elements. The digests were evaporated to near dryness to eliminate the troublesome effect of HF and HNO3 and to decrease acidity of the electrolytic solution to pH ≥ 2. At pH 2, the addition of at least 0.01 M KCl was needed to improve sensitivity. The formation of Zn-Cu intermetallic compounds which interfered in the accurate quantitation of zinc was eliminated by addition of gallium as a 'third' element. The amount of gallium needed varied from sample to sample and was affected by the pH of the solution. The DPASV parameters found to be optimum for the analysis of the air particulate samples are as follows: pulse amplitude, 50 mV; scan rate, 10 mV/sec; Edep, - 1.30 V; tdep, 2 min; and RDE rotation rate, 1500 rpm. Detection limits of 0.2 ppb for zinc, 0.6 ppb for lead, and 0.05 ppb for cadmium in the sample matrix were obtained. The standard addition method was found to be reliable for the quantitative determination of the analytes in the sample. All R2 values obtained were > 0.9900 at 95% confidence level. Validation of the established analytical methodology by analyzing certified reference standards and performing parallel analysis by GF-AAS and flame AAS showed acceptable accuracy of the DPASV measurements. (Author)

  19. Mercury-Free Analysis of Lead in Drinking Water by Anodic Stripping Square Wave Voltammetry

    Science.gov (United States)

    Wilburn, Jeremy P.; Brown, Kyle L.; Cliffel, David E.

    2007-01-01

    The analysis of drinking water for lead, which has well-known health effects, is presented as an instructive example for undergraduate chemistry students. It allows the students to perform an experiment and evaluate to monitor risk factors and common hazard of everyday life.

  20. Anodic Voltammetry of Thioacetamide and its Amperometric Determination in Aqueous Media

    Directory of Open Access Journals (Sweden)

    Daniela Dascălu

    2008-08-01

    Full Text Available TAA is a harmful, presumptive pollutant in tap waters and waste waters. Several alternatives have been tested as new possibilities for the anodic determination of TAA in aqueous solutions, simulated waste waters and tap water. The electrochemical behaviour of thioacetamide (TAA was investigated at a boron-doped diamond (BDD electrode both in unbuffered 0.1 M Na2SO4 and buffered solutions as supporting electrolytes. The anodic oxidation of TAA showed well-defined limiting currents or current peaks and a good linearity of the amperometric signal vs. concentration plots. The analytical parameters of sensitivity, RSD and LOD, obtained under various experimental conditions, suggest the suitability of the BDD electrode for electroanalytical purposes. Low fouling effects, good reproducibility and stability, as well as the sharpness of the amperometric signals in both unbuffered/ buffered acidic or neutral media, highly superior to those obtained using a glassy carbon (GC electrode, recommend the unmodified BDD electrode as a promising potential amperometric sensor for environmental applications, regarding the direct anodic determination of TAA in aqueous media.

  1. Application of differential pulse stripping voltammetry and chemometrics for the determination of three antibiotic drugs in food samples

    Institute of Scientific and Technical Information of China (English)

    Yong Sheng Zhong; Yong Nian Ni; Serge Kokot

    2012-01-01

    A reliable method for simultaneous determination of three antibiotic drugs (levottoxacin,gatifloxacin and lomefloxacin) by differential pulse stripping voltammetry (DPSV) in Britton-Robinson buffer (pH 7.96) was presented.The method is based on adsorptive accumulation of the antibacterial drugs on a hanging mercury dropping electrode (HMDE),followed by the reduction of the adsorptive species by the technique of DPSV.Optimal conditions,the deposition time of 80 s,the deposition potential of - 1250 mV,and the scan rate of 25 mV/s,were obtained.The linear concentration ranges of 0.010-0.080 μg/mL were obtained for all these three antibiotic drugs,while the detection limits were 2.38,3.20 and 1.60 ng/mL for levofloxacin,gatifloxacin and lomefloxacin,respectively.In this work,chemometrics methods,such as classical least squares (CLS),partial least squares (PLS),principle component regression (PCR) and radial basis function-artificial neural networks (RBF-ANN),were used to quantitatively resolve the overlapping signals.It was found that PCR gave the best results with total relative prediction error (RPEr) of 7.71%.The proposed method was applied to determine these three drugs in several commercial food samples with spiked method and yielded satisfactory recoveries.

  2. Determination of Sb(III) using an ex-situ bismuth screen-printed carbon electrode by adsorptive stripping voltammetry.

    Science.gov (United States)

    Rojas-Romo, Carlos; Serrano, Núria; Ariño, Cristina; Arancibia, Verónica; Díaz-Cruz, José Manuel; Esteban, Miquel

    2016-08-01

    The determination of Sb(III) on an ex-situ bismuth screen-printed carbon electrode (ex-situ BiSPCE) by means of adsorptive stripping voltammetry (AdSV) using quercetin-5'-sulfonic acid as chelating agent was optimized. The effect of different experimental parameters such pH, ligand concentration (CQSA), accumulation potential (Eacc) and accumulation time (tacc) were studied to obtain a wide linear range, the highest sensitivity and the lowest detection limit. Ex-situ BiSPCE was analytically compared with a sputtered bismuth screen-printed electrode (BispSPE) under optimal conditions. The obtained analytical parameters suggest that ex-situ BiSPCE behaves much better than BispSPE and the first was selected for this study. Optimal parameters were pH=4.6; CQSA=10.0 to 20.0×10(-6)molL(-1); Eacc=-0.5V and tacc=60s. Peak area is proportional to Sb(III) concentration up to 100.0μgL(-1) (tacc 60s) and 45.0μgL(-1) (tacc 120s) range, with detection limits of 1.2μgL(-)(1) (tacc 60s) and 0.8μgL(-1) (tacc 120s). The relative standard deviation for a Sb(III) solution (20.0μgL(-1)) was 3.9% for ten successive assays. Thus, the effect of various interfering metal ions was studied and the methodology was validated using a spiked groundwater reference material with very satisfactory results. PMID:27216652

  3. The redox thermodynamics and kinetics of flavonoid rutin adsorbed at glassy carbon electrodes by stripping square wave voltammetry

    Energy Technology Data Exchange (ETDEWEB)

    Aragao Catunda, Francisco Eduardo; Araujo, Marcelo Francisco de [Departamento de Quimica, Instituto de Ciencias Exactas, Universidad Federal Rural do Rio de Janeiro, BR 465 KM 07, 23890-000, Seropedica, RJ (Brazil); Granero, Adrian Marcelo; Arevalo, Fernando Javier [Departamento de Quimica, Facultad de Ciencias Exactas, Fisico-Quimicas y Naturales, Universidad Nacional de Rio Cuarto, Agencia Postal No 3 - (5800), Rio Cuarto (Argentina); Carvalho, Mario Geraldo de [Departamento de Quimica, Instituto de Ciencias Exactas, Universidad Federal Rural do Rio de Janeiro, BR 465 KM 07, 23890-000, Seropedica, RJ (Brazil); Zon, Maria Alicia, E-mail: azon@exa.unrc.edu.ar [Departamento de Quimica, Facultad de Ciencias Exactas, Fisico-Quimicas y Naturales, Universidad Nacional de Rio Cuarto, Agencia Postal No 3 - (5800), Rio Cuarto (Argentina); Fernandez, Hector, E-mail: hfernandez@exa.unrc.edu.ar [Departamento de Quimica, Facultad de Ciencias Exactas, Fisico-Quimicas y Naturales, Universidad Nacional de Rio Cuarto, Agencia Postal No 3 - (5800), Rio Cuarto (Argentina)

    2011-11-30

    Highlights: > Adsorptive accumulation of rutin is studied at glassy carbon (GC) electrodes. > The Frumkin adsorption isotherm described the specific interaction. > Gibbs free energy of adsorption and the interaction parameter were determined. > Thermodynamics and kinetics of the surface redox process were characterized by SWV. > Detection limit for rutin was 2 x 10{sup -8} mol dm{sup -3} (12 ppb). - Abstract: The adsorptive accumulation of rutin (RU) at glassy carbon (GC) electrodes in 10% ethanol + 90% 1 mol dm{sup -3} HClO{sub 4} aqueous solution is studied by using cyclic (CV) and square wave (SWV) voltammetries. The Frumkin adsorption isotherm best described the specific interaction of rutin with carbon electrodes. By fitting the experimental data, values of -31.9 kJ mol{sup -1} and 0.54 {+-} 0.02 were obtained for the Gibbs free energy of adsorption and the interaction parameter, respectively. SWV fully characterized the thermodynamics and kinetics of the surface redox process, using a combination of the 'quasi-reversible maximum' and the 'splitting of SW peaks' methods. Average values of 0.644 {+-} 0.003 V and 0.44 {+-} 0.02 were obtained for the formal potential and the anodic transfer coefficient, respectively. Moreover, a formal rate constant of 6.1 x 10{sup 2} s{sup -1} was obtained. SWV was also employed to generate calibration curves. The lowest concentration of RU experimentally measured for a signal-to-noise ratio of 3:1 was 2 x 10{sup -8} mol dm{sup -3} (12 ppb).

  4. A Single Photon Imaging System Based on Wedge and Strip Anodes

    Institute of Scientific and Technical Information of China (English)

    MIAO Zhen-Hua; ZHAO Bao-Sheng; ZHANG Xing-Hua; LIU Yong-An

    2008-01-01

    A new prototype of single photon imaging system based on wedge and strip anodes is developed. The prototype can directly measure the intensity and position information for an ultra-weak radiant source which takes on the character of single photons. The image of the ultra-weak radiant source can be reconstructed with a wedge and strip anodes detector and an electronic readout subsystem by photon counting and photon position sensitive detecting in a period of time. With proper evaluation, the prototype reveals a spatial resolution superior to 150μm, a 66-kHz maximal counting rate and a dark-count below 0.67count/cm2s.

  5. Extraction of arsenic as the diethyl dithiophosphate complex with supercritical fluid and quantitation by cathodic stripping voltammetry.

    Science.gov (United States)

    Arancibia, Verónica; López, Alex; Zúñiga, M Carolina; Segura, Rodrigo

    2006-02-28

    The separation of arsenic based on in situ chelation with ammonium diethyl dithiophosphate (ADDTP) has been carried out using methanol-modified supercritical CO(2). Aliquots of extract were added to an electroanalytical cell and arsenic was determined by square wave cathodic stripping voltammetry (SWCSV) at a hanging mercury drop electrode (HMDE). Quantitative extractions of As(DDTP)(3) were achieved when the experiments were carried out at a pressure of 2500psi, a temperature of 90 degrees C, 2.0mL of methanol, 20.0min of static extraction and 5.0min of dynamic extraction in the presence of 18mg of ADDTP. Analysis of arsenic was made using 150mgL(-1) of Cu(II) in 1M HCl solution as supporting electrolyte in the presence of ADDTP as ligand. Preconcentration was carried out by deposition at a potential of -0.50V and the intermetallic compound Cu(x)As(y) was reduced at a potential of -0.77 to -0.82V, depending on ligand concentration. The results showed that the presence of ligand plays an important role, increasing the method's sensitivity and preventing the oxidation of As(III). The calibration graph of the As(DDTP)(3) solution was linear from 0.8 to 12.5mugL(-1) of arsenic (LOD 0.5mugL(-1), R=0.9992, t(acc)=60s). The method was validated using carrot pulp spiked with arsenic solution. This method was applied to the determination of arsenic in samples of carrots, beets and irrigation water. Arsenic in beets was: skin 4.10+/-0.18mgkg(-1); pulp 3.83+/-0.19mgkg(-1) and juice 0.71+/-0.09mgL(-1); arsenic in carrots was: skin 2.15+/-0.09mgkg(-1); pulp 0.59+/-0.11mgkg(-1) and juice 0.71+/-0.03mgL(-1). Arsenic in water were: Chiu-Chiu 0.08mgL(-1), Inacaliri 1.12mgL(-1), and Salado river 0.17+/-0.07mgL(-1). PMID:18970500

  6. Square-wave anodic-stripping voltammetric determination of Cd, Pb and Cu in wine: Set-up and optimization of sample pre-treatment and instrumental parameters

    International Nuclear Information System (INIS)

    For the first time, square-wave anodic-stripping voltammetry (SWASV) was set up and optimized for the determination of Cd, Pb and Cu in white wine after UV photo-oxidative digestion of the sample. The best procedure for the sample pre-treatment consisted in a 6-h UV irradiation of diluted, acidified wine, with the addition of ultrapure H2O2 (three sequential additions during the irradiation). Due to metal concentration differences, separate measurements were carried out for Cd (deposition potential −950 mV vs. Ag/AgCl/3 M KCl deposition time 15 min) and simultaneously for Pb and Cu (Ed −750 mV, td 30 s). The optimum set-up of the main instrumental parameters, evaluated also in terms of the signal-to-noise ratio, were as follows: ESW 20 mV, f 100 Hz, ΔEstep 8 mV, tstep 100 ms, twait 60 ms, tdelay 2 ms, tmeas 3 ms. The electrochemical behaviour was reversible bielectronic for Cd and Pb, and kinetically controlled monoelectronic for Cu. Good accuracy was found both when the recovery procedure was used and when the results were compared with data obtained by differential pulse anodic stripping voltammetry. The linearity of the response was verified up to ∼4 μg L−1 for Cd and Pb and ∼15 μg L−1 for Cu. The detection limits for td = 5 min in the 10 times diluted, UV digested sample were (ng L−1): Cd 7.0, Pb 1.2 and Cu 6.6, which are well below currently applied methods. Application to a Verdicchio dei Castelli di Jesi white wine revealed concentration levels of Cd ∼0.2, Pb ∼10, Cu ∼30 μg L−1 with repeatabilities of (±RSD%) Cd ±6%, Pb ±5%, Cu ±10%

  7. Ultra-sensitive quantification of sub-nanomolar levels of tin by adsorptive stripping voltammetry by using N-nitroso-N-phenylhydroxylamine as a selective chelating agent

    International Nuclear Information System (INIS)

    In present paper, a simple and sensitive adsorptive stripping voltammetry method was developed for detection of Sn by using N-Nitroso-N-Phenylhydroxylamine (Cupferron) as a selective complexing agent. The influence of ph and the nature of supporting electrolytes, concentration of ligand, preconcentration time and applied potential on were investigated. The detection limits were 0.12 ng/ml. The method has been applied for the determination of tin in human blood, edible oil and water samples with the satisfactory results. (author)

  8. Anodic stripping voltammetric determination of traces of Pb(II) and Cd(II) using a glassy carbon electrode modified with bismuth nanoparticles

    International Nuclear Information System (INIS)

    We report on a glassy carbon electrode modified with bismuth nanoparticles (NanoBiE) for the simultaneous determination Pb2+ and Cd2+ by anodic stripping voltammetry. Operational parameters such as bismuth nanoparticles labelling amount, deposition potential, deposition time and stripping parameters were optimized with respect to the determination of Pb2+ and Cd2+ in 0.1 M acetate buffer solution (pH 4.5). The NanoBiE gives well-defined, reproducible and sharp stripping peaks. The peak current response increases linearly with the metal concentration in a range of 5.0–60.0 μg L−1, with a detection limit of 0.8 and 0.4 μg L−1 for Pb2+ and Cd2+, respectively. The morphology and composition of the modified electrode before and after voltammetric measurements were analysed by scanning electron microscopy and energy dispersive X-ray analysis. The NanoBiE was successfully applied to analysis of Pb2+ and Cd2+ in real water samples and the method was validated by ICP-MS technique, suggesting that the electrode can be considered as an interesting alternative to the bismuth film electrode for possible use in electrochemical studies and electro analysis. (author)

  9. Voltammetric behaviour at gold electrodes immersed in the BCR sequential extraction scheme media Application of underpotential deposition-stripping voltammetry to determination of copper in soil extracts

    International Nuclear Information System (INIS)

    The development of mercury-free electroanalytical systems for in-field analysis of pollutants requires a foundation on the electrochemical behaviour of the chosen electrode material in the target sample matrices. In this work, the behaviour of gold working electrodes in the media employed in the BCR sequential extraction protocol, for the fractionation of metals in solid environmental matrices, is reported. All three of the BCR sequential extraction media are redox active, on the basis of acidity and oxygen content as well as the inherent reducing or oxidising nature of some of the reagents employed: 0.11 M acetic acid, 0.1 M hydroxylammonium chloride (adjusted to pH 2) and 1 M ammonium acetate (adjusted to pH 2) with added trace hydrogen peroxide. The available potential ranges together with the demonstrated detection of target metals in these media are presented. Stripping voltammetry of copper or lead in the BCR extract media solutions reveal a multi-peak behaviour due to the stripping of both bulk metal and underpotential metal deposits. A procedure based on underpotential deposition-stripping voltammetry (UPD-SV) was evaluated for application to determination of copper in 0.11 M acetic acid soil extracts. A preliminary screening step in which different deposition times are applied to the sample enables a deposition time commensurate with UPD-SV to be selected so that no bulk deposition or stripping occurs thus simplifying the shape and features of the resulting voltammograms. Choice of the suitable deposition time is then followed by standards addition calibration. The method was validated by the analysis of a number of BCR 0.11 M acetic acid soil extracts. Good agreement was obtained been the UPD-SV method and atomic spectroscopic results

  10. Low power readout electronics for a UV MCP detector with cross strip anode

    Science.gov (United States)

    Pfeifer, M.; Diebold, S.; Barnstedt, J.; Hermanutz, S.; Kalkuhl, C.; Kappelmann, N.; Schanz, T.; Werner, K.

    2014-03-01

    After the shutdown of the Hubble Space Telescope in a few years, new astronomical missions for the ultraviolet (UV) wavelength range between 91 and 300 nm with improved optics and detectors will be necessary. This fact drives our development of solar blind photon counting microchannel plate (MCP) UV detectors with high quantum efficiency, high spatial resolution, and low power readout electronics. We plan to use a cross-strip anode (XSA), which has a high spatial resolution and additionally allows a low gain operation of the MCPs which leads to an increased lifetime of the MCPs compared to detectors with other anode types. The main difficulty in implementing an XSA in a detector for space applications is the need for a (pre-) amplifier, a shaper, and an ADC for each of the strips, which means large power consumption and spatial requirements. The solution we are studying is the application of the so-called Beetle chip. This allows for an implementation of a readout electronics for an XSA with a power consumption of less then 10 W. For the tests of our readout electronics prototype, and for the burn-in of the MCPs, we recently finished a setup in a vacuum chamber that is similar to the configuration in the final detector. We present a brief overview of our detector design and details of the readout electronics setup as well as details of the setup in our vacuum chamber.

  11. Initial stages of anodic oxidation of silver in sodium hydroxide solution studied by potential sweep voltammetry and ellipsometry

    NARCIS (Netherlands)

    Droog, J.M.M.; Alderliesten, P.T.; Bootsma, G.A.

    1979-01-01

    The first stages of the oxidation of polycrystalline silver electrodes in NaOH solutions were studied by potential sweep voltammetry and ellipsometry. Formation of bulk Ag2O was found to be preceded by dissolution of silver species and deposition of a surface oxide. The equilibrium oxide coverage de

  12. Determination of oleuropein using multiwalled carbon nanotube modified glassy carbon electrode by adsorptive stripping square wave voltammetry.

    Science.gov (United States)

    Cittan, Mustafa; Koçak, Süleyman; Çelik, Ali; Dost, Kenan

    2016-10-01

    A multi-walled carbon nanotube modified glassy carbon electrode was used to prepare an electrochemical sensing platform for the determination of oleuropein. Results showed that, the accumulation of oleuropein on the prepared electrode takes place with the adsorption process. Electrochemical behavior of oleuropein was studied by using cyclic voltammetry. Compared to the bare GCE, the oxidation peak current of oleuropein increased about 340 times at MWCNT/GCE. Voltammetric determination of oleuropein on the surface of prepared electrode was studied using square wave voltammetry where the oxidation peak current of oleuropein was measured as an analytical signal. A calibration curve of oleuropein was performed between 0.01 and 0.70µM and a good linearity was obtained with a correlation coefficient of 0.9984. Detection and quantification limits of the method were obtained as 2.73 and 9.09nM, respectively. In addition, intra-day and inter-day precision studies indicated that the voltammetric method was sufficiently repeatable. Finally, the proposed electrochemical sensor was successfully applied to the determination of oleuropein in an olive leaf extract. Microwave-assisted extraction of oleuropein had good recovery values between 92% and 98%. The results obtained with the proposed electrochemical sensor were compared with liquid chromatography-tandem mass spectrometry (LC-MS/MS) analysis. PMID:27474292

  13. A novel model for calculating the inter-electrode capacitance of wedge-strip anode

    Science.gov (United States)

    Zhao, Airong; Ni, Qiliang

    2016-04-01

    The wedge strip anode (WSA) detector has been widely used in particle detection. In this work, a novel model for calculating the inter-electrode capacitance of WSA was proposed on the basis of conformal transformations and the partial capacitance method. Based on the model, the inter-electrode capacitance within a period was calculated besides the total inter-electrode capacitance. As a result, the effects of the WSA design parameters on the inter-electrode capacitance are systematically analyzed. It is found that the inter-electrode capacitance monotonically increases with insulated gap and substrate permittivity but not with the period. In order to prove the validation of the model, two round WSAs were manufactured by employing the picosecond laser micro-machining technology. It is found that 9%-15% errors between the theoretical and experimental results can be obtained, which is better than that obtained by employing ANSYS software.

  14. Cross strip anode readouts for microchannel plate detectors: developing flight qualified prototypes

    Science.gov (United States)

    Vallerga, John; Cooney, M.; Raffanti, R.; Varner, G.; Siegmund, O.; McPhate, J. B.; Tremsin, A.

    2014-01-01

    Photon counting microchannel plate (MCP) imagers have been the detector of choice for most UV astronomical missions over the last two decades (eg. EUVE, FUSE, COS on Hubble etc.). Over this duration, improvements in the MCP laboratory readout technology have resulted in better spatial resolution (x10), temporal resolution (x 1000) and output event rate (x100), all the while operating at lower gain (x 10) resulting in lower high voltage requirements and longer MCP lifetimes. One such technology is the parallel cross strip (PXS) readout. The PXS anode is a set of orthogonal conducting strips (80 x 80), typically spaced at a 635 micron pitch onto which charge clouds from MCP amplified events land. Each strip has its own charge sensitive amplifier that is sampled continuously by a dedicated analog to digital (ADC) converter at 50MHz. All of the 160 ADC digital output lines are fed into a field programmable gate array (FGPA) which can detect charge events landing on the strips, measure the peak amplitudes of those charge events and calculate their spatial centroid along with their time of arrival (X,Y,T). Laboratory versions of these electronics have demonstrated count rates on the order of 2 MHz, and temporal resolution of ~ 1ns. In 2012 the our group at U.C. Berkeley, along with our partners at the U. Hawaii, received a Strategic Astrophysics Technology grant to raise the TRL of the PXS detector from 4 to 6 by replacing most of the 19" rack mounted, high powered electronics with application specific integrated circuits (ASICs) which will lower the power, mass and volume requirements of the PXS detector. We were also tasked to design and fabricate a "standard" 50mm square active area MCP detector incorporating these electronics that can be environmentally qualified for flight (temperature, vacuum, vibration). This detector design could then be modified for individual flight opportunities with a higher level of confidence than starting from scratch. We will present the

  15. High-voltage electrodeposition conditions in the stripping voltammetry of metal ions: a mechanism and analytical prospects of the process

    International Nuclear Information System (INIS)

    Electrodeposition of 13 metals, including cadmium, from aqueous solutions is studied under high-voltage (up to 1000 V) conditions. It was found that the exaltation phenomenon in the parallel reduction of hydrogen ions from weak acids or water is responsible for the acceleration of the electrodeposition of metals under high-voltage conditions. Under these conditions, the rate of electrodeposition can be increased by 2 to 3 orders of magnitude compared to the rates of electrodeposition under standard conditions. At a constant high voltage of electrodeposition, the stripping peak currents of metals are proportional to the deposition time and the bulk concentration of analyte ions. Exaltation phenomena can be used in analysis not only for intensifying the process, but also for lowering the limit of detection, improving the selectivity, and decreasing the adverse effect of surfactants

  16. Determination of Xanthine in the Presence of Hypoxanthine by Adsorptive Stripping Voltammetry at the Mercury Film Electrode

    Science.gov (United States)

    Farias, Percio Augusto Mardini; Castro, Arnaldo Aguiar

    2014-01-01

    A stripping method for the determination of xanthine in the presence of hypoxanthine at the submicromolar concentration levels is described. The method is based on controlled adsorptive accumulation at the thin-film mercury electrode followed by a fast linear scan voltammetric measurement of the surface species. Optimum experimental conditions were found to be the use of 1.0 × 10−3 mol L−1 NaOH solution as supporting electrolyte, an accumulation potential of 0.00 V for xanthine and −0.50 V for hypoxanthine–copper, and a linear scan rate of 200 mV second−1. The response of xanthine is linear over the concentration ranges of 20–140 ppb. For an accumulation time of 30 minutes, the detection limit was found to be 36 ppt (2.3 × 10−10 mol L−1). Adequate conditions for measuring the xanthine in the presence of hypoxanthine, copper and other metals, uric acid, and other nitrogenated bases were also investigated. The utility of the method is demonstrated by the presence of xanthine associated with hypoxanthine, uric acid, nitrogenated bases, ATP, and ssDNA. PMID:24940040

  17. A glassy carbon electrode modified with bismuth nanotubes in a silsesquioxane framework for sensing of trace lead and cadmium by stripping voltammetry

    International Nuclear Information System (INIS)

    Single-walled bismuth nanotubes (sw-BiNTs) were self-assembled with octa(3-aminopropyl) silsesquioxane as a framework and to govern morphology. Deposited on a glassy carbon electrode (GCE), the sw-BiNTs were used for the simultaneous analysis of Pb(II) and Cd(II) by square wave stripping voltammetry. The sw-BiNTs were prepared by (a) coordination interaction between the amino groups of the silsesquioxane and the Bi(III) ions, and by (b) reduction with sodium borohydride. Transmission electron microscopy images revealed single-walled tubular structures with diameters of ∼4–6 nm, and with lengths of several hundreds nanometers. GCEs modified with such sw-BiNTs perform much better than bare GCEs in stripping analysis of Pb(II) and Cd(II). The effects of adsorption quantity of sw-BiNTs, solution pH, pulse amplitude, and pulse width were optimized. The modified electrode was then used for the analysis of Pb(II) and Cd(II) in a linear response range from 0.4 to 6 μM with a sensitivity of 4.692 μA μM−1 and 3.835 μA μM−1, and detection limits of 1 nM and 5 nM, respectively. The method was successfully applied to the analysis of Pb(II) and Cd(II) in toy leachates, and the results were in good agreement with those obtained with atomic absorption spectrometry. Sensitivity and detection limits were compared with other voltammetric methods, and the sw-BiNTs are deemed to be an attractive alternative for practical applications. Other features of the electrode include low costs, a well reproducible nanostructure, and ease of scale-up of the fabrication process. (author)

  18. Femtomolar detection of a cancer biomarker protein in serum with ultralow background current by anodic stripping voltammetry.

    Science.gov (United States)

    Shiddiky, Muhammad J A; Kithva, Prakash H; Rauf, Sakandar; Trau, Matt

    2012-05-22

    An electrochemical immunosensor for the detection of a cancer biomarker protein in serum at femtomolar concentrations with ultralow background response has been developed, which consists of (i) a hydrophilic polyacrylic acid brush-modified indium tin oxide substrate as an antifouling substrate and (ii) a graphene-quantum dots-antibody 'bionanoconjugate' as a signal amplification label in voltammetric detection of targets in a glassy carbon electrode. PMID:22618633

  19. Sensitive Bioanalysis Based on in-Situ Droplet Anodic Stripping Voltammetric Detection of CdS Quantum Dots Label after Enhanced Cathodic Preconcentration.

    Science.gov (United States)

    Qin, Xiaoli; Wang, Linchun; Xie, Qingji

    2016-01-01

    We report a protocol of CdS-labeled sandwich-type amperometric bioanalysis with high sensitivity, on the basis of simultaneous chemical-dissolution/cathodic-enrichment of the CdS quantum dot biolabel and anodic stripping voltammetry (ASV) detection of Cd directly on the bioelectrode. We added a microliter droplet of 0.1 M aqueous HNO₃ to dissolve CdS on the bioelectrode and simultaneously achieved the potentiostatic cathodic preconcentration of Cd by starting the potentiostatic operation before HNO₃ addition, which can largely increase the ASV signal. Our protocol was used for immunoanalysis and aptamer-based bioanalysis of several proteins, giving limits of detection of 4.5 fg·mL(-1) for human immunoglobulin G, 3.0 fg·mL(-1) for human carcinoembryonic antigen (CEA), 4.9 fg·mL(-1) for human α-fetoprotein (AFP), and 0.9 fM for thrombin, which are better than many reported results. The simultaneous and sensitive analysis of CEA and AFP at two screen-printed carbon electrodes was also conducted by our protocol. PMID:27563894

  20. Sensitive Bioanalysis Based on in-Situ Droplet Anodic Stripping Voltammetric Detection of CdS Quantum Dots Label after Enhanced Cathodic Preconcentration

    Science.gov (United States)

    Qin, Xiaoli; Wang, Linchun; Xie, Qingji

    2016-01-01

    We report a protocol of CdS-labeled sandwich-type amperometric bioanalysis with high sensitivity, on the basis of simultaneous chemical-dissolution/cathodic-enrichment of the CdS quantum dot biolabel and anodic stripping voltammetry (ASV) detection of Cd directly on the bioelectrode. We added a microliter droplet of 0.1 M aqueous HNO3 to dissolve CdS on the bioelectrode and simultaneously achieved the potentiostatic cathodic preconcentration of Cd by starting the potentiostatic operation before HNO3 addition, which can largely increase the ASV signal. Our protocol was used for immunoanalysis and aptamer-based bioanalysis of several proteins, giving limits of detection of 4.5 fg·mL−1 for human immunoglobulin G, 3.0 fg·mL−1 for human carcinoembryonic antigen (CEA), 4.9 fg·mL−1 for human α-fetoprotein (AFP), and 0.9 fM for thrombin, which are better than many reported results. The simultaneous and sensitive analysis of CEA and AFP at two screen-printed carbon electrodes was also conducted by our protocol. PMID:27563894

  1. Sensitive Bioanalysis Based on in-Situ Droplet Anodic Stripping Voltammetric Detection of CdS Quantum Dots Label after Enhanced Cathodic Preconcentration

    Directory of Open Access Journals (Sweden)

    Xiaoli Qin

    2016-08-01

    Full Text Available We report a protocol of CdS-labeled sandwich-type amperometric bioanalysis with high sensitivity, on the basis of simultaneous chemical-dissolution/cathodic-enrichment of the CdS quantum dot biolabel and anodic stripping voltammetry (ASV detection of Cd directly on the bioelectrode. We added a microliter droplet of 0.1 M aqueous HNO3 to dissolve CdS on the bioelectrode and simultaneously achieved the potentiostatic cathodic preconcentration of Cd by starting the potentiostatic operation before HNO3 addition, which can largely increase the ASV signal. Our protocol was used for immunoanalysis and aptamer-based bioanalysis of several proteins, giving limits of detection of 4.5 fg·mL−1 for human immunoglobulin G, 3.0 fg·mL−1 for human carcinoembryonic antigen (CEA, 4.9 fg·mL−1 for human α-fetoprotein (AFP, and 0.9 fM for thrombin, which are better than many reported results. The simultaneous and sensitive analysis of CEA and AFP at two screen-printed carbon electrodes was also conducted by our protocol.

  2. Recent Advances in Voltammetry

    Science.gov (United States)

    Batchelor-McAuley, Christopher; Kätelhön, Enno; Barnes, Edward O; Compton, Richard G; Laborda, Eduardo; Molina, Angela

    2015-01-01

    Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemical processes, voltammetry in ionic liquids, the development and interpretation of theories of electron transfer (Butler–Volmer and Marcus–Hush), advances in voltammetric pulse techniques, stochastic random walk models of diffusion, the influence of migration under conditions of low support, voltammetry at rough and porous electrodes, and nanoparticle electrochemistry. The review of the latter field encompasses both the study of nanoparticle-modified electrodes, including stripping voltammetry and the new technique of ‘nano-impacts’. PMID:26246984

  3. Simultaneous detection of metronidazole and chloramphenicol by differential pulse stripping voltammetry using a silver nanoparticles/sulfonate functionalized graphene modified glassy carbon electrode

    International Nuclear Information System (INIS)

    Graphical abstract: Display Omitted -- Highlights: • A novel and reliable AgNPs/SF-GR modified glassy carbon electrode was constructed and characterized. • The AgNPs/SF-GR/GCE was successfully applied in the shrimp for simultaneous determination of MTZ and CAP. • Under optimized conditions, common substances such as UA, AA, DA and ion did not interfered in the electrode performance. • The modified electrode exhibited considerable sensitivity, stability and reproducibility. • This fabricated electrode achieved a satisfactory level compared with other electrodes toward MTZ and CAP. -- Abstract: A novel silver nanoparticles/sulfonated functionalized graphene modified glassy carbon electrode (AgNPs/SF-GR/GCE) was fabricated to determine chloramphenicol and metronidazole simultaneously. Taking advantage of sulfonic group, AgNPs were successfully electrodeposited on functionalized GR immobilized on the surface of a GCE. Scanning electron microscopy and energy spectrum analysis results confirmed that AgNPs were deposited on the functionalized GR film. Compared to the bare GCE or the pristine SF-GR modified electrode, AgNPs/SF-GR/GCE exhibited excellent electroreduction towards chloramphenicol and metronidazole. In addition, the two antibacterial drugs were separated completely in 0.10 M citric acid-sodium citrate buffer (pH 4.0) by differential pulse stripping voltammetry under optimum conditions. The cathodic current was linearly related with 0.02∼20.0 μM chloramphenicol and 0.10∼20.0 μM metronidazole, with the detection limits of 0.01 μM and 0.05 μM respectively. Furthermore, AgNPs/SF-GR/GCE was applied to the simultaneous determination of chloramphenicol and metronidazole in an aquatic product

  4. A low noise front end electronics for micro-channel plate detector with wedge and strip anode

    International Nuclear Information System (INIS)

    A low noise Front End Electronics (FEE) for two-dimensional position sensitive Micro-Channel Plate (MCP) detector has been developed. The MCP detector is based on Wedge and Strip Anode (WSA) with induction readout mode. The WSA has three electrodes, the wedge electrode, the strip electrode, and the zigzag electrode. Then, three readout channels are designed in the Printed Circuit Board (PCB). The FEE is calibrated by a pulse generator from Agilent. We also give an analysis of the charge loss from the CSA. The noise levels of the three channels are less than 1 fC RMS at the shaping time of 200 ns. The experimental result shows that the position resolution of the MCP detector coupled with the designed PCB can reach up to 110 μm

  5. A low noise front end electronics for micro-channel plate detector with wedge and strip anode

    Science.gov (United States)

    Hu, K.; Li, F.; Liang, F.; Chen, L.; Jin, G.

    2016-03-01

    A low noise Front End Electronics (FEE) for two-dimensional position sensitive Micro-Channel Plate (MCP) detector has been developed. The MCP detector is based on Wedge and Strip Anode (WSA) with induction readout mode. The WSA has three electrodes, the wedge electrode, the strip electrode, and the zigzag electrode. Then, three readout channels are designed in the Printed Circuit Board (PCB). The FEE is calibrated by a pulse generator from Agilent. We also give an analysis of the charge loss from the CSA. The noise levels of the three channels are less than 1 fC RMS at the shaping time of 200 ns. The experimental result shows that the position resolution of the MCP detector coupled with the designed PCB can reach up to 110 μm.

  6. 阴极溶出伏安法检测二次盐水中碘离子%Determination of Iodine Ions in Secondary Brine with Cathodic Stripping Voltammetry

    Institute of Scientific and Technical Information of China (English)

    周国敏; 谢兴胜; 陈留平

    2013-01-01

    This paper makes a further study on the testing method of iodide ion in the secondary brine and introduces using cathode stripping voltammetry and standard addition method to test the iodide ion.And this paper first proposes the concept of removal of influence of dissolved oxygen on cathode stripping oxidation reduction potential through high purity nitrogen gas in the test sample solution.Meanwhile,it compares with the standard addition method and the standard curve method when using cathode stripping voltammetry to test the iodide ion in the secondary brine.%对二次盐水中碘离子的测定方法进行了深一步的研究,详细地介绍了利用阴极溶出伏安和标准加入法测定二次盐水中的碘离子测定,并首次提出了利用在检测样品溶液中通高纯氮气消除了溶解氧对阴极溶出氧化还原电位的影响,并对标准加入法和标准曲线法在阴极溶出伏安法测定二次盐水中碘离子进行了比较.

  7. Pulse Voltammetry.

    Science.gov (United States)

    Osteryoung, Janet

    1983-01-01

    Discusses the nature of pulse voltammetry, indicating that its widespread use arises from good sensitivity and detection limits and from ease of application and low cost. Provides analytical and mechanistic applications of the procedure. (JN)

  8. Cyclic Voltammetry.

    Science.gov (United States)

    Evans, Dennis H.; And Others

    1983-01-01

    Cyclic voltammetry is a simple experiment that has become popular in chemical research because it can provide useful information about redox reactions in a form which is easily obtained and interpreted. Discusses principles of the method and illustrates its use in the study of four electrode reactions. (Author/JN)

  9. Trace analysis of Ponceau 4R in soft drinks using differential pulse stripping voltammetry at SWCNTs composite electrodes based on PEDOT:PSS derivatives.

    Science.gov (United States)

    Wang, Zifei; Zhang, Hui; Wang, Zhipeng; Zhang, Jie; Duan, Xuemin; Xu, Jingkun; Wen, Yangping

    2015-08-01

    Ponceau 4R, an edible synthetic colorant used in drinks, syrups, and sweets, has been successfully detected using differential pulse voltammetry at a single-walled carbon nanotubes-modified composite electrode based on poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) and two derivatives thereof. The electrochemical parameters of three Ponceau 4R sensors, such as pH value, pre-concentration time, and scan rate, have been optimized, and their electrochemical performances have been compared. A poly(acrylate-modified 3,4-ethylenedioxythiophene-co-3,4-ethylenedioxythiophene):poly(styrene sulfonate)-single-walled carbon nanotubes-poly(vinyl alcohol)-modified electrode showed the best electrocatalytic activity, with the highest response current, lowest detection limit (1.8 nm), widest linear range (0.0055-110.6 μm), and best sensing stability. Additionally, the modified electrode has also been successfully employed for real sample analysis with soft drinks. Satisfactory results were obtained, demonstrating this to be an easy and effective approach for trace analysis of Ponceau 4R in food samples. PMID:25766817

  10. Sensitive and stable monitoring of lead and cadmium in seawater using screen-printed electrode and electrochemical stripping analysis

    International Nuclear Information System (INIS)

    Sensitive and stable monitoring of heavy metals in seawater using screen-printed electrodes (SPE) is presented. The analytical performance of SPE coupled with square wave anodic stripping voltammetry (SWASV) for the simultaneous determination of Pb and Cd in seawater samples, in the low μg L-1 range, is evaluated. The stripping response for the heavy metals following 2 min deposition was linear over the concentration range examined (10-2000 μg L-1) with detection limits of 1.8 and 2.9 μg L-1 for Pb and Cd, respectively. The accuracy of the method was validated by analyzing metal contents in different spiked seawater samples and comparing these results to those obtained with the well-established anodic stripping voltammetry using the hanging mercury drop electrode. Moreover, a certified reference material was also used and the results obtained were satisfactory

  11. Trace metal detection in Sibenik Bay, Croatia: Cadmium, Lead and Copper with anodic stripping voltammetry and manganese via sonoelectrochemistry. a case study

    International Nuclear Information System (INIS)

    The vertical profiles of the concentration of reactive Mn and total concentrations of Cd, Pb, and Cu ions in the water column of the Sibenik Bay (Krka river estuary) were determined. The measured ranges of concentrations are: 60-1300 ng 1-1for Mn, 5-13 ng 1-1 for Cd, 70-230 ng 1-1for Pb, and 375-840 ng 1-1for Cu. These values are comparable with the concentrations found in the unpolluted estuaries. The Krka river estuary is highly stratified, with the measured salinity gradient of 20% within a half meter of the freshwater-seawater interface . The main changes in the vertical profiles of the measured parameters occur in the freshwater-seawater interface: the temperature increases for 1digC and the pH decreases for 0.1 unit, whereas the metal concentrations show different behaviour. Generally, Mn, Pb, and Cd ions show the increase of concentrations in the freshwater-seawater interface , while copper concentration profile indicates anthropogenic pollution in the brackish layer caused by agriculture activities and by the paint with copper basis used as an antifoulant biocide for the ships. UV-digested samples show an increase in manganese concenbations for at least 3.5 times comparing to non UV-digested. This suggests that in natural water manganese exists mainly in the form of inert complexes and as associated to particulate matter (about 70-80%). UV irradiation has no influence on the concentration of cadmium, while for lead an increase of 50% in the seawater layer is observed. The twofold increase of the copper concentration in the upper freshwater layer and at least the fourfold one in the seawater layer were measured in the UV-digested samples. These results show that copper is strongly bound to inert complexes, and that UV-digestion is necessary step in determination of the total metal concentrations in natural water samples. No significant increase of the metal concentrations in the deeper seawater layer was observed, indicating the absence of the processes of remobilization or dissolution of metals from the sediment. Presented results confirm that the new method for the determination of manganese by CSV on boron-doped diamond electrode with ultrasound enhanced accumulation can be successfully applied to natural waters

  12. MICROFABRICATED ARRAY OF IRIDIUM MICRODISKS AS A SUBSTRATE FOR DIRECT DETERMINATION OF CU2+ OR HG2+USING SQUARE WAVE ANODIC STRIPPING VOLTAMMETRY. (R825511C022)

    Science.gov (United States)

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  13. The direct determination, by differential pulse anodic-stripping voltammetry at the thin mercury-film electrode, of cadmium, lead and copper

    International Nuclear Information System (INIS)

    This report describes the development and application of a voltammetric procedure for the direct, simultaneous determination of cadmium, lead, and copper in three SAROC reference materials (carbonatite, magnesite, and quartz). The electrolyte was a mixture of 1 M ammonium chloride, 0,1 M citric acid, and 0,025 M ascorbic acid. No interferences were encountered from Fe(III), As(III), Sb(V), Tl(I), or In(III) at the concentrations present in the samples. Intermetallic interferences were eliminated by the use of thin mercury-film electrodes not less than 80nm thick. Limits of detection were determined by the degree to which the supporting electrolyte could be purified, and were estimated to be 10ng/g, 250ng/g, and 150ng/g for cadmium, lead, and copper respectively

  14. Preparation and Electrochemical Application of Praseodymium Modified TiO2-NTs/SnO2-Sb Anode by Cyclic Voltammetry Method

    Institute of Scientific and Technical Information of China (English)

    王燕; 陈迓宾; 朱怀工; 张旭斌

    2016-01-01

    A Pr-doped TiO2-NTs/SnO2-Sb electrode was prepared by a simple method, cyclic voltammetry(CV). The methyl orange(MO)aqueous solution was selected as a simulated wastewater. The ordered microstructural TiO2-NTs substrate was synthesized by an electrochemical method to obtain large specific surface area and high space utilization. The phase structure, electrode surface morphology and electrochemical properties of electrodes were characterized by XRD, SEM and electrochemical technology, respectively. The results showed that praseo-dymium oxide was successfully doped into the SnO2-Sb film by CV method. Due to the doped Pr, the oxygen evo-lution potential increased from 2.25 V to 2.40 V. The degradation of MO was investigated by UV-vis. TheCt/C0(φ) was studied as a function to obtain the optimal parameters, such as the amount of doped Pr, current density and initial dye concentration. In addition, the degradation process followed pseudo-first-order reaction kinetics and the rate constant was 0.099 3 min-1. The result indicated that the introduction of Pr reduced the formation of oxygen vacancies or enhanced the formation of adsorbed hydroxyl radical groups on the surface, thus leading to better ac-tivity and stability.

  15. Determination of Trace Copper in Water Samples by Anodic Stripping Voltamme%阳极溶出伏安法测定水样中痕量铜离子的研究

    Institute of Scientific and Technical Information of China (English)

    黄灿灿; 简锦明; 曾立波; 邵卫伟; 蔡佳玲; 马勇; 蔡强

    2013-01-01

    A portable metal detector based on anodic stripping voltammetry(ASV) was proposed.The method is applied to determine the trace copper ions in water samples.A series of experimental conditions,such as the pH of the buffer solution,deposition time and and deposition potential were optimized.Determination of trace copper in tap water and effluents using self-made three-electrode system under the optimal conditions,the result shows that the sensor has high sensitivity,and the recovery of standard addition is from 97%-108%.Comparison with atomic absorption spectrometry,this method is simple with high accuracy and reproducibility.%设计了一种基于阳极溶出伏安法的便携式重金属检测仪,对测定水样中痕量铜离子的方法进行研究,并优化了缓冲液,沉积时间,沉积电位等实验条件.该仪器采用自制的三电极系统,测定自来水、污水等实际水样中的铜离子含量,灵敏度较高,加标回收率为97% ~108%,且测得的重复率较好,将测定结果与原子吸收光谱法检测结果对比,操作简便、快速,且具有较高的准确性和可靠性.

  16. STUDY ON DETERMINATION FOLIC ACID IN FOODSTUFF BY DIFFERENT PULSE STRIPPING VOLTAMMETRY%差示脉冲溶出伏安法测定粮食中叶酸的研究

    Institute of Scientific and Technical Information of China (English)

    张娟; 靳保辉; 刘灵芳; 冶保献

    2001-01-01

    利用差示脉冲溶出伏安技术和叶酸在电极表面的吸附特性,建立了测定痕量叶酸的电化学分析方法.方法具有快速、简便、灵敏度高、干扰少的优点.在不富集的实验条件下,差示峰电流与叶酸浓度在3.39×10-8~3.73×10-7mol/L范围内呈良好线性关系;而在-0.25V电位吸附富集70s条件下,其线性范围为6.78×-10~2.27×10-8mol/L,检测限达1.0×10-11mol/L。将该方法应用于小米和玉米中微量和痕量叶酸的测定,结果满意,回收率在94%~102%之间.%Electrochemical analysis is used to determine trace folic acid by Different Pulse Stripping Voltammetry and to absorb properties of folic acid in electrode face.This method has the characteristics of being fast,used easily,high-sensitivity and little interference.The peak currents have linear relation with folic acid concentration in the range 3.39×10-8~3.73×10-7mol/L without preconcentration,and 6.78×10-10~2.72×10-8mol/L with preconcentration for 70S under-0.25V.The detect limit is 1.0×10-11mol/L.This method has satisfactory result in determining trace folic acid in millet and maize.Its recovery rate is between 94% and 102%.

  17. Square-wave anodic-stripping voltammetric determination of Cd, Pb, and Cu in a hydrofluoric acid solution of siliceous spicules of marine sponges (from the Ligurian Sea, Italy, and the Ross Sea, Antarctica)

    Energy Technology Data Exchange (ETDEWEB)

    Truzzi, C.; Annibaldi, A.; Illuminati, S.; Bassotti, E.; Scarponi, G. [Polytechnic University of Marche, Ancona (Italy). Department of Marine Science

    2008-09-15

    Square-wave anodic-stripping voltammetry (SWASV) was set up and optimized for simultaneous determination of cadmium, lead, and copper in siliceous spicules of marine sponges, directly in the hydrofluoric acid solution ({proportional_to}0.55 mol L{sup -1} HF, pH {proportional_to}1.9). A thin mercury-film electrode (TMFE) plated on to an HF-resistant epoxy-impregnated graphite rotating-disc support was used. The optimum experimental conditions, evaluated also in terms of the signal-to-noise ratio, were as follows: deposition potential -1100 mV vs. Ag/AgCl, KCl 3 mol L{sup -1}, deposition time 3-10 min, electrode rotation 3000 rpm, SW scan from -1100 mV to +100 mV, SW pulse amplitude 25 mV, frequency 100 Hz, {delta}E{sub step} 8 mV, t{sub step} 100 ms, t{sub wait} 60 ms, t{sub delay} 2 ms, t{sub meas} 3 ms. Under these conditions the metal peak potentials were Cd -654{+-}1 mV, Pb -458 {+-} 1 mV, Cu -198{+-}1 mV. The electrochemical behaviour was reversible for Pb, quasi-reversible for Cd, and kinetically controlled (possibly following chemical reaction) for Cu. The linearity of the response with concentration was verified up to {proportional_to}4 {mu}g L{sup -1} for Cd and Pb and {proportional_to}20 {mu}g L{sup -1} for Cu. The detection limits were 5.8 ng L{sup -1}, 3.6 ng L{sup -1}, and 4.3 ng L{sup -1} for Cd, Pb, and Cu, respectively, with t{sub d}=5 min. The method was applied for determination of the metals in spicules of two specimens of marine sponges (Demosponges) from the Portofino natural reserve (Ligurian Sea, Italy, Petrosia ficiformis) and Terra Nova Bay (Ross Sea, Antarctica, Sphaerotylus antarcticus). The metal contents varied from tens of ng g{sup -1} to {proportional_to}1 {mu}g g{sup -1}, depending on the metal considered and with significant differences between the two sponge species. (orig.)

  18. Square-wave anodic-stripping voltammetric determination of Cd, Pb, and Cu in a hydrofluoric acid solution of siliceous spicules of marine sponges (from the Ligurian Sea, Italy, and the Ross Sea, Antarctica).

    Science.gov (United States)

    Truzzi, C; Annibaldi, A; Illuminati, S; Bassotti, E; Scarponi, G

    2008-09-01

    Square-wave anodic-stripping voltammetry (SWASV) was set up and optimized for simultaneous determination of cadmium, lead, and copper in siliceous spicules of marine sponges, directly in the hydrofluoric acid solution (approximately 0.55 mol L(-1) HF, pH approximately 1.9). A thin mercury-film electrode (TMFE) plated on to an HF-resistant epoxy-impregnated graphite rotating-disc support was used. The optimum experimental conditions, evaluated also in terms of the signal-to-noise ratio, were as follows: deposition potential -1100 mV vs. Ag/AgCl, KCl 3 mol L(-1), deposition time 3-10 min, electrode rotation 3000 rpm, SW scan from -1100 mV to +100 mV, SW pulse amplitude 25 mV, frequency 100 Hz, DeltaE(step) 8 mV, t(step) 100 ms, t(wait) 60 ms, t(delay) 2 ms, t(meas) 3 ms. Under these conditions the metal peak potentials were Cd -654 +/- 1 mV, Pb -458 +/- 1 mV, Cu -198 +/- 1 mV. The electrochemical behaviour was reversible for Pb, quasi-reversible for Cd, and kinetically controlled (possibly following chemical reaction) for Cu. The linearity of the response with concentration was verified up to approximately 4 microg L(-1) for Cd and Pb and approximately 20 microg L(-1) for Cu. The detection limits were 5.8 ng L(-1), 3.6 ng L(-1), and 4.3 ng L(-1) for Cd, Pb, and Cu, respectively, with t(d) = 5 min. The method was applied for determination of the metals in spicules of two specimens of marine sponges (Demosponges) from the Portofino natural reserve (Ligurian Sea, Italy, Petrosia ficiformis) and Terra Nova Bay (Ross Sea, Antarctica, Sphaerotylus antarcticus). The metal contents varied from tens of ng g(-1) to approximately 1 microg g(-1), depending on the metal considered and with significant differences between the two sponge species. PMID:18642105

  19. Affordable Cyclic Voltammetry

    Science.gov (United States)

    Stewart, Greg; Kuntzleman, Thomas S.; Amend, John R.; Collins, Michael J.

    2009-01-01

    Cyclic voltammetry is an important component of the undergraduate chemical curriculum. Unfortunately, undergraduate students rarely have the opportunity to conduct experiments in cyclic voltammetry owing to the high cost of potentiostats, which are required to control these experiments. By using MicroLab data acquisition interfaces in conjunction…

  20. Voltammetry Method Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Hoyt, N. [Argonne National Lab. (ANL), Argonne, IL (United States); Pereira, C. [Argonne National Lab. (ANL), Argonne, IL (United States); Willit, J. [Argonne National Lab. (ANL), Argonne, IL (United States); Williamson, M. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-07-29

    The purpose of the ANL MPACT Voltammetry project is to evaluate the suitability of previously developed cyclic voltammetry techniques to provide electroanalytical measurements of actinide concentrations in realistic used fuel processing scenarios. The molten salts in these scenarios are very challenging as they include high concentrations of multiple electrochemically active species, thereby creating a variety of complications. Some of the problems that arise therein include issues related to uncompensated resistance, cylindrical diffusion, and alloying of the electrodeposited metals. Improvements to the existing voltammetry technique to account for these issues have been implemented, resulting in good measurements of actinide concentrations across a wide range of adverse conditions.

  1. Recent Advances in Voltammetry

    OpenAIRE

    Batchelor-McAuley, Christopher; Kätelhön, Enno; Barnes, Edward O; Compton, Richard G.; Laborda, Eduardo; Molina, Angela

    2015-01-01

    Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemical processes, voltammetry in ionic liquids, the development and interpretation of theories of electr...

  2. Theoretical and experimental study of redox processes combined with adsorption phenomena under conditions of square-wave voltammetry

    OpenAIRE

    Gulaboski, Rubin

    2001-01-01

    Theoretical models of four electrode reactions coupled with adsorption phenomena under conditions of square-wave voltammetry are developed: simple surface redox reaction, surface catalytic reaction, cathodic stripping reaction of I order, and cathodic stripping reaction of II order.

  3. Electrochemical and microfabrication strategies for remotely operated smart chemical sensors: application of anodic stripping coulometry to calibration-free measurements of copper and mercury.

    Science.gov (United States)

    Marei, Mohamed M; Roussel, Thomas J; Keynton, Robert S; Baldwin, Richard P

    2013-11-25

    Remote unattended sensor networks are increasingly sought after to monitor the drinking water distribution grid, industrial wastewater effluents, and even rivers and lakes. One of the biggest challenges for application of such sensors is the issue of in-field device calibration. With this challenge in mind, we report here the use of anodic stripping coulometry (ASC) as the basis of a calibration-free micro-fabricated electrochemical sensor (CF-MES) for heavy metal determinations. The sensor platform consisted of a photo-lithographically patterned gold working electrode on SiO2 substrate, which was housed within a custom stopped-flow thin-layer cell, with a total volume of 2-4 μL. The behavior of this platform was characterized by fluorescent particle microscopy and electrochemical studies utilizing Fe(CN)6(3-/4-) as a model analyte. The average charge obtained for oxidation of 500 μM ferrocyanide after 60s over a 10 month period was 176 μC, corresponding to a volume of 3.65 μL (RSD = 2.4%). The response of the platform to copper concentrations ranging from 50 to 7500 ppb was evaluated, and the ASC results showed a linear dependence of charge on copper concentrations with excellent reproducibility (RSD ≤ 2.5%) and accuracy for most concentrations (≤ 5-10% error). The platform was also used to determine copper and mercury mixtures, where the total metallic content was measurable with excellent reproducibility (RSD ≤ 4%) and accuracy (≤ 6% error). PMID:24216196

  4. Comparative evaluation of scanned stripping techniques: SSCP vs. SSV

    NARCIS (Netherlands)

    Town, R.M.; Leeuwen, van H.P.

    2006-01-01

    The characteristic features of scanned deposition potential curves constructed from stripping chronopotentiometry (SSCP) and various modes of stripping voltammetry (SSV) are critically evaluated. The strengths and weaknesses of each method for identification of metal ion speciation features and susc

  5. Cyclic Voltammetry Experiment.

    Science.gov (United States)

    Van Benschoten, James J.; And Others

    1983-01-01

    Describes a three-part experiment designed to introduce cyclic voltammetry to graduate/undergraduate students. Part 1 demonstrates formal reduction potential, redox electron transfer, diffusion coefficient, and electrochemical reversibility. Part 2 investigates electrochemical behavior of acetaminophen. Part 3 examines such experimental variables…

  6. Voltammetry of Medical Biomaterials

    OpenAIRE

    Gulaboski, Rubin; Markovski, Velo

    2015-01-01

    The use of biomaterials in the medicine, dentistry and pharmacy represents probably a major breakthrough in tackling many diseases or disabilities in the last 50 years. We refer to varios techniques that are used for the characterization of the structure and the composition of the biomaterials. Voltammetry is an electrochemical technique that helps mainly in understanding the redox properties of various biomaterials containing some suitable redox centers in their structure. We give in this le...

  7. Boron doped diamond electrodes in voltammetry: new designs and applications (an overview)

    OpenAIRE

    Zavázalová, Jaroslava; Barek, Jiří; Pecková, Karolina

    2014-01-01

    In this overview, the recent progress in the development and applications of bare boron doped diamond electrodes in voltammetry of organic compounds is summarized. Attention is paid to important issues reflected in last five years in electroanalytical studies, e.g. fouling and pretreatment of BDD surface, influence of boron concentration on performance of BDD-based sensors, and application of adsorptive stripping voltammetry.

  8. Underpotential Deposition Study and Determination of Bismuth on Gold Electrode by Using Voltammetry

    Institute of Scientific and Technical Information of China (English)

    DU,Yong-Ling(杜永令); WANG,Chun-Ming(王春明)

    2002-01-01

    The cyclic voltammetry (CV) and the semidifferential anodic stripping voltanmetry (SdASV) were used for investigation of bismuth(Ⅲ) underpotential deposition (UPD) on gold electrode. Based on the excellent electrochemical properties of Au/Bi UPD system, a new method for determining bismuth (Ⅲ)was established. A solution of 0.1 mol/L HNO3 was selected as the supporting electrolyte. Factors affecting the Bi(Ⅲ) UPD and stripping steps were investigated and an opthmized analytical procedure was developed. The calibration plots for Bi(Ⅲ) concentration in the range 1.25 × 10-8-1.0 × 10-7 mol/L were obtained. The detection limit, calculated as three times the standard deviation of the analytical signal of 8.3×10-8 mol/L for a 90 s electrodeposition at 0.00 V (while the solution magnetically stirred at a speed of 300 rpm), was 7.5× 10-9 mol/ L. For8 successive determinations of 1.25 × 10-7 mol/L Bi(Ⅲ), the obtained RSD (relative standard deviation) was 0.4%. The developed method was applied to bismuth determining in medicine and urine samples. The analytical results were compared with that of atomic emission spectrometry (AES) method.

  9. Corrosive electrochemistry of jamesonite by cyclic voltammetry

    Institute of Scientific and Technical Information of China (English)

    余润兰; 胡岳华; 邱冠周; 覃文庆

    2004-01-01

    The corrosive electrochemistry of jamesonite was studied by cyclic voltammetry. Every peak in voltammograms was identified through thermodynamic calculation. The results show an irreversible electrode process by the strong adsorption of oxidation elemental sulfur on jamesonite. A deficient-metal and sulfur-rich compound is formed under the potential of 80 mV at pH 6.86. The passive action by elemental sulfur occurs from 80 to 470 mV and S2O23- , SO24- are produced at potential over 470 mV. The anodic peak producing SO24- is inhibited due to the deposition of PbSO4 at higher potential in Na2SO4 solution. The corrosive action of jamesonite becomes strong and the redox characterization similar to PbS, FeS and Sb2 S3 appears at pH 9.18.

  10. Voltammetry-Principles and Applications

    OpenAIRE

    Gulaboski, Rubin

    2008-01-01

    Voltammetry is a potentiodynamic technique that is inevitable tool in everyday experiments in many physicochemical and biological laboratories. The principles, potential applications and the advantages/disadvantages of various voltammetric techniques are described.

  11. Determination of Lead in Vegetables by Differential Pulse Stripping Voltammetry on Nafion Modified Mercury Film Electrode%Nafion修饰汞膜电极微分脉冲阳极溶出伏安法测定蔬菜中的铅

    Institute of Scientific and Technical Information of China (English)

    王志登; 孙汝东

    2013-01-01

    采用Nafion修饰汞膜电极微分脉冲阳极溶出伏安法测定蔬菜中的铅,选择0.1 mol/L NH4NO3作为支持电解质,富集时间420 s,搅拌速度300 r/min,Nafion修饰体积10 μL,考察了共存离子的干扰.方法在0.01 μg/L~ 14.0 μg/L范围内线性良好,检出限为0.2 μg/L,铅酸电池厂附近蔬菜样品的测定结果与石墨炉原子吸收光谱法相吻合,加标回收率为89.5%~106%.%A new method based on Nafion modified mercury film electrode has been established for detection of Pb2 + in vegetables from the vicinity of lead-acid battery factory by differential pulse stripping voltammetry. The parameters of this method is 0. 1 mol/L NH4NO3 as supporting electrolyte, accumulation time of 420 s, stirring rate of 300 r/min, the Nafion modified volume of 10μL and interfering ions were investigated. It showed good linear relationship between peak current and Pb2+ in the range of 0.01μg/L to 14.0μg/L. The detection limit was 0.2 μg/L. The vegetable sample measurement results using this method have good consistency with GFAAS, and the spiked recoveries ranged from 89.5% to 106%.

  12. Comparação da labilidade de metais empregando voltametria, difusão em filmes finos por gradiente de concentração (DGT e modelo computacional Comparison of the speciation of trace metals in freshwater employing voltammetry, diffusive gradients in thin films (DGT and a chemical equilibrium model

    Directory of Open Access Journals (Sweden)

    Vanessa E. dos Anjos

    2010-01-01

    Full Text Available Speciation of metals in a synthetic freshwater was comparatively evaluated using Anodic Stripping Voltammetry, Diffusive Gradients in Thin Films and a Chemical Equilibrium Model. The labile fractions of Cu and Zn quantified by DGT were similar to the ones measured by ASV. The labile species of Cd and Pb could not be determined by both experimental methods due to the formation of inert complexes with organic ligands in the sample. Despite the differences among the methods, the speciation results obtained by the use of DGT and ASV agreed well with predictions made by the chemical equilibrium model.

  13. Voltammetry of electrochemically heterogeneous surfaces

    OpenAIRE

    Ward, Kristopher R.; Compton, Richard G.

    2013-01-01

    In this thesis, mathematical modelling is used to theoretically investigate the electrochemical behaviour of surfaces which can be broadly classified as being ‘electrochemically heterogeneous’. Simulated voltammetry is used in the exploration of a number of specific systems as listed below.The cyclic voltammetry of electrodes composed of two different electroactive materials that differ in terms of their electrochemical rate constants towards any given redox couple. The effect of the distribu...

  14. Adsorption behavior of low concentration carbon monoxide on polymer electrolyte fuel cell anodes for automotive applications

    Science.gov (United States)

    Matsuda, Yoshiyuki; Shimizu, Takahiro; Mitsushima, Shigenori

    2016-06-01

    The adsorption behavior of CO on the anode around the concentration of 0.2 ppm allowed by ISO 14687-2 is investigated in polymer electrolyte fuel cells (PEFCs). CO and CO2 concentrations in the anode exhaust are measured during the operation of a JARI standard single cell at 60 °C cell temperature and 1000 mA cm-2 current density. CO coverage is estimated from the gas analysis and CO stripping voltammetry. The cell voltage decrease as a result of 0.2 ppm CO is 29 mV and the CO coverage is 0.6 at the steady state with 0.11 mg cm-2 of anode platinum loading. The CO coverage as a function of CO concentration approximately follows a Temkin-type isotherm. Oxygen permeated to the anode through a membrane is also measured during fuel cell operation. The exhaust velocity of oxygen from the anode was shown to be much higher than the CO supply velocity. Permeated oxygen should play an important role in CO oxidation under low CO concentration conditions.

  15. Modification of carbon screen-printed electrodes by adsorption of chemically synthesized Bi nanoparticles for the voltammetric stripping detection of Zn(II), Cd(II) and Pb(II).

    Science.gov (United States)

    Rico, Ma Angeles Granado; Olivares-Marín, Mara; Gil, Eduardo Pinilla

    2009-12-15

    A simple procedure for the chemical synthesis of bismuth nanoparticles and subsequent adsorption on commercial screen-printed carbon electrodes offer reliable quantitation of trace zinc, cadmium and lead by anodic stripping square-wave voltammetry in nondeareated water samples. The influence of two hydrodynamic configurations (convective cell and flow cell) and the effect of various experimental variables upon the stripping signals at the bismuth-coated sensor are explored. The square-wave peak current signal is linear over the low ng mL(-1) range (120 s deposition), with detections limits ranging from 0.9 to 4.9 ng mL(-1) and good precision. Applicability to waste water certified reference material and drinking water samples is demonstrated. The attractive behaviour of the new disposable Bi nanoparticles modified carbon strip electrodes, coupled with the negligible toxicity of bismuth, hold great promise for decentralized heavy metal testing in environmental and industrial effluents waters.

  16. Cross strip anode readouts for large format, photon counting microchannel plate detectors: developing flight qualified prototypes of the detector and electronics

    Science.gov (United States)

    Vallerga, John; Raffanti, Rick; Cooney, Michael; Cumming, Harley; Varner, Gary; Seljak, Andrej

    2014-07-01

    Photon counting microchannel plate (MCP) imagers have been the detector of choice for most UV astronomical missions over the last two decades (e.g. EUVE, FUSE, COS on Hubble etc.). Over this duration, improvements in the MCP laboratory readout technology have resulted in better spatial resolution (x10), temporal resolution (x1000) and output event rate (x100), all the while operating at lower gain (x 10) resulting in lower high voltage requirements and longer MCP lifetimes. One such technology is the parallel cross strip (PXS) readout. Laboratory versions of PXS electronics have demonstrated count rates on the order of 2 MHz, and temporal resolution of ~ 1ns. In 2012 our group at U.C. Berkeley, along with our partners at the U. Hawaii, received a Strategic Astrophysics Technology grant to raise the TRL of the PXS detector and electronics from 4 to 6 by replacing most of the high powered electronics with application specific integrated circuits (ASICs) which will lower the power, mass and volume requirements of the PXS detector. We were also tasked to design and fabricate a "standard" 50mm square active area MCP detector incorporating these electronics that can be environmentally qualified for flight (temperature, vacuum, vibration). The first ASICs designed for this program have been fabricated and are undergoing testing. We present the latest progress on these ASIC designs and performance and show imaging results from the new 50 x 50 mm XS detector.

  17. Development of a cathode strip chamber for minimum ionizing particles

    International Nuclear Information System (INIS)

    A cathode strip chamber (CSC) capable of measuring position information for minimum ionizing particles (MIPS) has been developed. The chamber operates in the proportional or limited proportional region, where the avalanche on the anode wire is localised to a small region around the anode wire. The position of the avalanche can be obtained by the pulse heights induced on the cathode strips which run perpendicular to direction of the anode wire. The pulse height induced on the cathode strips is proportional directly to the strip width and inversely to the distance between the strip centre to the avalanche location. Thus by measuring the pulse heights on at least three cathode strips for every event, one can reconstruct the centroid that would give the location of the avalanche on the anode

  18. Cyclic voltammetry of supported BLMs

    Science.gov (United States)

    Murgasova, Renata; Sabo, Jan; Ottova, Angelica L.; Tien, H. T.

    1996-06-01

    The transfer of an electron across a bilayer lipid membrane (BLM) is one of the BLMs most exciting processes. A number of well known electron mediators have been investigated using the method of cyclic voltammetry on a Teflon coated platinum wire, the tip of which has been modified by a self-assembled bilayer lipid membrane (s-BLM). The electrical capacitance of the s-BLM system was measured as a function of frequency. The results are discussed in terms of electron transfer and redox reactions.

  19. CO-Tolerant Pt–BeO as a Novel Anode Electrocatalyst in Proton Exchange Membrane Fuel Cells

    Directory of Open Access Journals (Sweden)

    Kyungjung Kwon

    2016-05-01

    Full Text Available Commercialization of proton exchange membrane fuel cells (PEMFCs requires less expensive catalysts and higher operating voltage. Substantial anodic overvoltage with the usage of reformed hydrogen fuel can be minimized by using CO-tolerant anode catalysts. Carbon-supported Pt–BeO is manufactured so that Pt particles with an average diameter of 4 nm are distributed on a carbon support. XPS analysis shows that a peak value of the binding energy of Be matches that of BeO, and oxygen is bound with Be or carbon. The hydrogen oxidation current of the Pt–BeO catalyst is slightly higher than that of a Pt catalyst. CO stripping voltammetry shows that CO oxidation current peaks at ~0.85 V at Pt, whereas CO is oxidized around 0.75 V at Pt–BeO, which confirms that the desorption of CO is easier in the presence of BeO. Although the state-of-the-art PtRu anode catalyst is dominant as a CO-tolerant hydrogen oxidation catalyst, this study of Be-based CO-tolerant material can widen the choice of PEMFC anode catalyst.

  20. Elimination Voltammetry with Linear Scan as a New Detection Method for DNA Sensors

    OpenAIRE

    Rene Kizek*; David Potesil; Vojtech Adam; Jitka Petrlova; Frantisek Jelen; Libuse Trnkova

    2005-01-01

    The paper describes successful coupling of adsorptive transfer stripping (AdTS) and elimination voltammetry with linear scan (EVLS) for the resolution of reduction signals of cytosine (C) and adenine (A) residues in hetero-oligodeoxynucleotides (ODNs). Short ODNs (9-mers and 20-mers) were adsorbed from a small volume on a hanging mercury drop electrode (HMDE). After washing of the ODN-modified electrode by water and its transferring to an electrochemical cell, voltammetric curves were measure...

  1. [Vernier Anode Design and Image Simulation].

    Science.gov (United States)

    Zhao, Ai-rong; Ni, Qi-liang; Song, Ke-fei

    2015-12-01

    Based-MCP position-sensitive anode photon-counting imaging detector is good at detecting extremely faint light, which includes micro-channel plate (MCP), position-sensitive anode and readout, and the performances of these detectors are mainly decided by the position-sensitive anode. As a charge division anode, Vernier anode using cyclically varying electrode areas which replaces the linearly varying electrodes of wedge-strip anode can get better resolution and greater electrode dynamic range. Simulation and design of the Vernier anode based on Vernier's decode principle are given here. Firstly, we introduce the decode and design principle of Vernier anode with nine electrodes in vector way, and get the design parameters which are the pitch, amplitude and the coarse wavelength of electrode. Secondly, we analyze the effect of every design parameters to the imaging of the detector. We simulate the electron cloud, the Vernier anode and the detector imaging using Labview software and get the relationship between the pitch and the coarse wavelength of the anode. Simultaneously, we get the corresponding electron cloud for the designing parameters. Based on the result of the simulation and the practical machining demand, a nine electrodes Vernier anode was designed and fabricated which has a pitch of 891 µm, insulation width of 25 µm, amplitude of 50 µm, coarse pixel numbers of 5. PMID:26964205

  2. Stripping chronopotentiometry at scanned deposition potential (SSCP). Part 5. Features of multi-metal systems

    NARCIS (Netherlands)

    Town, R.M.; Leeuwen, van H.P.

    2004-01-01

    This paper considers the mutual effects of metals on each other in scanned deposition potential stripping chronopotentiometry measurements (SSCP) on multi-metal systems. As compared to stripping voltammetry, depletive SSCP displays a certain resistance to the impact of intermetallic compounds, while

  3. Anodic oxidation

    CERN Document Server

    Ross, Sidney D; Rudd, Eric J; Blomquist, Alfred T; Wasserman, Harry H

    2013-01-01

    Anodic Oxidation covers the application of the concept, principles, and methods of electrochemistry to organic reactions. This book is composed of two parts encompassing 12 chapters that consider the mechanism of anodic oxidation. Part I surveys the theory and methods of electrochemistry as applied to organic reactions. These parts also present the mathematical equations to describe the kinetics of electrode reactions using both polarographic and steady-state conditions. Part II examines the anodic oxidation of organic substrates by the functional group initially attacked. This part particular

  4. Ultrafast cyclic voltammetry with asymmetrical potential scan

    Institute of Scientific and Technical Information of China (English)

    Zhi Yong Guo; Xiang Qin Lin

    2008-01-01

    Based on the perfect ohmic drop compensation by online electronic positive feedback, ultrafast cyclic voltammetry withasymmetrical potential scan is achieved for the first time, with the reduction of anthracene acting as the test system. Compared withthe traditional cyclic voltammetry utilizing symmetrical triangular waveform as the excitation one, the new method allows a simplerapproach to mechanistic analysis of ultrafast chemical reactions coupled with a charge transfer. And perhaps more important, it alsoprovides a way to eliminate the interference of the adsorbed product in dynamic monitoring.

  5. Electrochemical impedance spectroscopy and cyclic voltammetry studies of a proton exchange membrane fuel cell operated at low humidity conditions

    Energy Technology Data Exchange (ETDEWEB)

    Malevich, D. [Fuel Cell Research Centre, Kingston, ON (Canada)

    2007-07-01

    This study investigated water balance issue in polymer electrolyte membrane fuel cells (PEMFCs) using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry. Equivalent PEMFC circuits and microporous layers (MPL) were investigated. Bode and Nyquist plots were presented, and the effect of current density on EIS was explored. Membrane resistance, Warburg resistance, and electron transfer resistance was measured. The study also examined hydrogen underpotential deposition on platinum. Cyclic voltammetry was used to develop curves for electrochemically active surfaces and charge transfer resistance of the MPL. Polarization curves for the anode and cathode MPLs were presented along with impedance diagrams for the PEMFC operating at low humidity conditions. tabs., figs.

  6. Fundamental Investigation of Si Anode in Li-Ion Cells

    Science.gov (United States)

    Wu, James J.; Bennett, William R.

    2012-01-01

    Silicon is a promising and attractive anode material to replace graphite for high capacity lithium ion cells since its theoretical capacity is approximately 10 times of graphite and it is an abundant element on earth. However, there are challenges associated with using silicon as Li-ion anode due to the significant first cycle irreversible capacity loss and subsequent rapid capacity fade during cycling. In this paper, cyclic voltammetry and electrochemical impedance spectroscopy are used to build a fundamental understanding of silicon anodes. The results show that it is difficult to form the SEI film on the surface of Si anode during the first cycle, the lithium ion insertion and de-insertion kinetics for Si are sluggish, and the cell internal resistance changes with the state of lithiation after electrochemical cycling. These results are compared with those for extensively studied graphite anodes. The understanding gained from this study will help to design better Si anodes.

  7. Voltammetry at porous electrodes: A theoretical study

    OpenAIRE

    Barnes, Edward O; Chena, Xiaojun; Li, Peilin; Compton, Richard G.

    2014-01-01

    Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface.

  8. Fundamental Investigation of Silicon Anode in Lithium-Ion Cells

    Science.gov (United States)

    Wu, James J.; Bennett, William R.

    2012-01-01

    Silicon is a promising and attractive anode material to replace graphite for high capacity lithium ion cells since its theoretical capacity is 10 times of graphite and it is an abundant element on Earth. However, there are challenges associated with using silicon as Li-ion anode due to the significant first cycle irreversible capacity loss and subsequent rapid capacity fade during cycling. Understanding solid electrolyte interphase (SEI) formation along with the lithium ion insertion/de-insertion kinetics in silicon anodes will provide greater insight into overcoming these issues, thereby lead to better cycle performance. In this paper, cyclic voltammetry and electrochemical impedance spectroscopy are used to build a fundamental understanding of silicon anodes. The results show that it is difficult to form the SEI film on the surface of a Si anode during the first cycle; the lithium ion insertion and de-insertion kinetics for Si are sluggish, and the cell internal resistance changes with the state of lithiation after electrochemical cycling. These results are compared with those for extensively studied graphite anodes. The understanding gained from this study will help to design better Si anodes, and the combination of cyclic voltammetry with impedance spectroscopy provides a useful tool to evaluate the effectiveness of the design modifications on the Si anode performance.

  9. 微波消解-铋膜/Nation修饰电极溶出伏安法测定鳗鱼中的镉含量%Determination of Cadmium in Eel by Microwave Digestion Followed by Stripping Voltammetry on Bismuth/Nation Modified Electrode

    Institute of Scientific and Technical Information of China (English)

    李静; 李红波; 范大和; 王伟

    2011-01-01

    A stripping voltammetric method based on microwave digestion was developed for determining cadmium in eel on a bismuth/nafion modified electrode. Oxidation yield a well-defined square wave peak for Cd^2+ at about - 0.85 V. Nation concentration, bismuth film thickness, buffer solution pH, deposition potential accumulation time and other potential interference factors were investigated. A linear relationship was found between peak area and cadmium concentration over the range of 4.0 to 14.0 μg/L with a correlation coefficient of 0.9964. The limit of detection of the method was 0.2 μg/L. The sensor was highly sensitive and effective to detect cadmium even in the presence of several excess potential interference ions.%运用铋膜/Nation修饰电极耦合微波消解技术测定鳗鱼中的Cd^2+。Cd^2+在-0.85V处出现清晰的方波氧化峰。Nafion、铋膜的厚度、缓冲液的pH值、富集电位、富集时间及可能干扰物质的影响因素进行考察。Cd^2+在4.0~14.0μg/L质量浓度范围内线性关系,线性相关性系数为0.9964,检出限为0.2ug/L。结果表明,该传感器在过量的干扰离子存在条件下,表现出超灵敏性和有效性。

  10. Cyclic Voltammetry And Linear Sweep Voltammetry Study Of Cyclic Tertiary Amines

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    @@ Cyclic six membered a-aminonitrile have proved to be very versatile synthetic intermediates and have been widely used in the construction of a large number of indole alkaloids. In order to obtain some information about the mechanisn of electrochemical synthesis of aaminonitrile. Electrochemistry behaviors that include cyclic voltammetry and linear sweep voltammetry of cyclic tertiary amines which including N-benzylpiperidine (NBP), 1-(l-Methoxycarbonyl ethyl) piperidine (MCEP), N-methylcarbonylppiperidine (NMCP), Nethylpiperidine(NEP) was studied.

  11. Wall-jet electrode linear sweep voltammetry

    OpenAIRE

    Compton, Richard G.; Fisher, Adrian C.; Latham, Mark H.; Brett, Christopher M. A.; Brett, Ana Maria C. F. Oliveira

    1992-01-01

    Theory is presented which predicts the linear sweep voltammetry behavior at the wall-jet electrode for a reversible couple. The scan rate and electrode geometry dependences are established, and hence the requirements for the measurement of true “steady state” hydrodynamic voltammograms are defmed. Theory is found to be in good agreement with experiments conducted on the oxidation of the ferrocyanide anion in aqueous solution

  12. Voltammetry: mathematical modelling and Inverse Problem

    CERN Document Server

    Koshev, N A; Kuzina, V V

    2016-01-01

    We propose the fast semi-analytical method of modelling the polarization curves in the voltammetric experiment. The method is based on usage of the special func- tions and shows a big calculation speed and a high accuracy and stability. Low computational needs of the proposed algorithm allow us to state the set of Inverse Problems of voltammetry for the reconstruction of metal ions concentrations or the other parameters of the electrolyte under investigation.

  13. Voltammetry as a Model for Teaching Chemical Instrumentation.

    Science.gov (United States)

    Gunasingham, H.; Ang, K. P.

    1985-01-01

    Voltammetry is used as a model for teaching chemical instrumentation to chemistry undergraduates at the National University of Singapore. Lists six criteria used to select a successful teaching model and shows how voltammetry satisfies each criterion. (JN)

  14. Ascorbic Acid Determination in Commercial Fruit Juice Samples by Cyclic Voltammetry

    OpenAIRE

    Slawomir Kalinowski; Aurelia Magdalena Pisoschi; Andrei Florin Danet

    2008-01-01

    A method was developed for assessing ascorbic acid concentration in commercial fruit juice by cyclic voltammetry. The anodic oxidation peak for ascorbic acid occurs at about 490 mV on a Pt disc working electrode (versus SCE). The influence of the potential sweep speed on the peak height was studied. The obtained calibration graph shows a linear dependence between peak height and ascorbic acid concentration in the domain (0.1–10 mmol·L−1). The equation of the calibration graph was y = 6.391x +...

  15. Determination of trace contaminants of Cu, Pb, Cd and Zn in fluorides of alkaline metals by inversion voltammetry method

    International Nuclear Information System (INIS)

    The method of determination of n·10-5-n·10-6% trace contaminants of copper, lead, cadmium and zink by means of inversion voltammetry method in fluorides of calcium and lithium is elaborated. Researches are conducted with application of mercury-graphite electrodes on polarographic analyzer and oscillograph polarography. The influence of conditions of electrochemical concentration on characteristics of anode peaks of copper, lead, cadmium and zinc is studied.

  16. 石墨烯基纳米复合物修饰印刷电极伏安法测定水中镉%Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets- Au Composite Nano-particles Modified Screen-printed Carbon Electrodes

    Institute of Scientific and Technical Information of China (English)

    杨欣; 徐玲玲; 周秋兰; 林世新; 李龙飞

    2011-01-01

    构建了基于石墨烯(GS) -纳米金(Au)复合纳米微粒修饰印刷电极(SPCEs)的电化学传感器(SPCEs |GS/Au),建立了微分脉冲溶出伏安(DPSV)法测定水中痕量镉的电分析方法.采用扫描电镜(SEM)对电极表面进行了表征,DPSV法研究了镉的电化学性质.在优化实验条件下,溶出峰电流与Cd2+的质量浓度在2.5×10-7~2.5×10-5 g/L范围内呈良好线性,相关系数为0.998 0,检出限为1.8×10-7 g/L.将该方法用于实际水样的测定,回收率为96%~ 107%,实验结果与石墨炉原子吸收光谱(GF - AAS)法一致.该传感器采用复合纳米微粒修饰SPCEs,既能富集Cd2+又能扩增响应电流,且一次使用可抛弃、样品用量少、操作简便,可快速、准确地测定水样中的痕量镉.%An electrochemical sensor based on graphene sheets ( GS ) and gold nano-particles ( Au ) composite nano-particles modified screen-printed carbon electrodes (SPCEs) was fabricated (SPCEs | GS/Au) , and an electrochemical method was developed for the determination of trace cadmium ( Cd) in water by differential pulse stripping voltammetric ( DPSV) method. Au preparation and the construction processes of SPCEs | GS/Au electrode were characterized by scanning electron micrography (SEM) , and the electrochemical properties of Cd 2+ were investigated. Under the optimum conditions, a good linear relationship was obtained between peak current and Cd2 + concentration in the range of 2. 5 x 10-7 -2. 5 x 10-5 g/L(r2 =0. 998 0) with a detection limit(3σ) of 1. 8 x 10-7 g/L. The method was applied in the determination of Cd2 + concentration in real water samples with recoveries of 96% -107% . The analytical results were consistent with those of the graphite furnace atomic absorption spectrometric(GF - AAS) method. The SPCEs | GS/Au electrode showed a high response current and an enrichment ability due to the modification of composite nano-particles. Therefore, the electrode was suitable for the

  17. Optimization of Stripping Voltammetric Sensor by a Back Propagation Artificial Neural Network for the Accurate Determination of Pb(II) in the Presence of Cd(II)

    Science.gov (United States)

    Zhao, Guo; Wang, Hui; Liu, Gang; Wang, Zhiqiang

    2016-01-01

    An easy, but effective, method has been proposed to detect and quantify the Pb(II) in the presence of Cd(II) based on a Bi/glassy carbon electrode (Bi/GCE) with the combination of a back propagation artificial neural network (BP-ANN) and square wave anodic stripping voltammetry (SWASV) without further electrode modification. The effects of Cd(II) in different concentrations on stripping responses of Pb(II) was studied. The results indicate that the presence of Cd(II) will reduce the prediction precision of a direct calibration model. Therefore, a two-input and one-output BP-ANN was built for the optimization of a stripping voltammetric sensor, which considering the combined effects of Cd(II) and Pb(II) on the SWASV detection of Pb(II) and establishing the nonlinear relationship between the stripping peak currents of Pb(II) and Cd(II) and the concentration of Pb(II). The key parameters of the BP-ANN and the factors affecting the SWASV detection of Pb(II) were optimized. The prediction performance of direct calibration model and BP-ANN model were tested with regard to the mean absolute error (MAE), root mean square error (RMSE), average relative error (ARE), and correlation coefficient. The results proved that the BP-ANN model exhibited higher prediction accuracy than the direct calibration model. Finally, a real samples analysis was performed to determine trace Pb(II) in some soil specimens with satisfactory results. PMID:27657083

  18. 纳米金修饰氧化铟锡电极阳极溶出伏安法测定水产品中痕量砷%Determination of arsenite in aquatic product by anodic stripping voltammetry with gold nanoparticles modified indium tin oxide electrode

    Institute of Scientific and Technical Information of China (English)

    杨阿喜; 鲁喆君; 狄俊伟

    2009-01-01

    研究了采用直接电化学沉积法制备的金纳米粒子修饰氧化铟锡(GNPs/ITO)电极,用阳极溶出伏安法测定痕量砷.对富集电位和时间、支持电解质及部分干扰离子等进行了实验.实验结果表明:砷在0.15 V出现灵敏的阳极溶出伏安峰,峰电流在砷浓度为0.053~9.3 μmol/L范围内呈良好的线性关系.方法灵敏、简便,可方便地应用于水产品中痕量砷的测定.

  19. 同时测定癌症病人血液中锌镉铅铜的微分脉冲阳极溶出伏安法%Simultaneous Determination of Zinc, Cadmium, Lead and Copper in Blood from Cancerous Patients by Differential Pulse Anodic Stripping Voltammetry

    Institute of Scientific and Technical Information of China (English)

    刘保启; 王玉春; 胡孝忠; 张玉华

    2003-01-01

    用微分脉冲阳极溶出伏安法同时测定癌症病人血液中的锌、镉、铅和铜,以为癌症与这 4种微量元素在血液中含量的相关性研究提供实验数据; 癌症病人血液用硝酸-高氯酸消化,消化后的白色固体加水溶解,以 0.100 mol/L硫酸铵为底液,在三电极体系中进行测定,以峰电位定性,峰电流定量; 用该法测定了 3 种癌症病人血液中的锌、镉、铅和铜,相对标准偏差为 2.9%~ 3.3% (n=6),加标回收率为 98%~ 110%; 该法不用除氧、干扰少、分辨率好、准确度高,适用于临床血液中锌、镉、铅和铜的测定和研究.

  20. Tests of Cathode Strip Chamber Prototypes

    CERN Document Server

    Bonushkin, Yuri; Chrisman, David; Durkin, S; Ferguson, Thomas; Giacomelli, Paolo; Gorn, William; Hauser, Jay; Hirschfelder, J; Hoftiezer, John; Hoorani, Hafeez R; Kisselev, Oleg; Klem, Daniel; Korytov, Andrey; Layter, John G; Lennous, Paul; Ling, Ta-Yung; Matthey, Christina; Medved, Serguei; Minor, C; Mitselmakher, Guenakh; Müller, Thomas; Otwinowski, Stanislaw; Preston, L; Prokofiev, O E; Rush, Chuck J; Schenk, P; Sedykh, Yu; Smirnov, Igor; Soulimov, V; Vaniachine, A; Vercelli, T; Wuest, Craig R; Zeng, Ji-Yang; von Goeler, Eberhard

    1997-01-01

    We report on the results of testing two six-layer 0.6 x 0.6 cm^2 cathode strip chamber ( CSC) prototypes in a muon beam at CERN. The prototypes were designed to simulate sections of the end-cap muon system of the Compact Muon Solenoid ( CMS) detector which will be installed at the Large Hadron Collider ( LHC). We measured the spatial and time resolutions of each chamber for different gains, different orientations with respect to the beam direction and different strength magnetic fields. The single-layer spatial resolution of a prototype with a strip pitch of 15.88 mm ranged from 78 micron to 468 micron, depending on whether the particle passed between two cathode strips or through the center of a strip; its six-layer resolution was found to be 44 micron. The single-layer spatial resolution of a prototype with a strip pitch of 6.35 mm ranged from 54 to 66 micron; its six-layer resolution w as found to be 23 micron. The efficiency for collecting an anode wire signal from one of six layers within a 20 ns time wi...

  1. Lateral flow strip assay

    Science.gov (United States)

    Miles, Robin R.; Benett, William J.; Coleman, Matthew A.; Pearson, Francesca S.; Nasarabadi, Shanavaz L.

    2011-03-08

    A lateral flow strip assay apparatus comprising a housing; a lateral flow strip in the housing, the lateral flow strip having a receiving portion; a sample collection unit; and a reagent reservoir. Saliva and/or buccal cells are collected from an individual using the sample collection unit. The sample collection unit is immersed in the reagent reservoir. The tip of the lateral flow strip is immersed in the reservoir and the reagent/sample mixture wicks up into the lateral flow strip to perform the assay.

  2. Asymmetric Marcus-Hush theory for voltammetry.

    Science.gov (United States)

    Laborda, Eduardo; Henstridge, Martin C; Batchelor-McAuley, Christopher; Compton, Richard G

    2013-06-21

    The current state-of-the-art in modeling the rate of electron transfer between an electroactive species and an electrode is reviewed. Experimental studies show that neither the ubiquitous Butler-Volmer model nor the more modern symmetric Marcus-Hush model are able to satisfactorily reproduce the experimental voltammetry for both solution-phase and surface-bound redox couples. These experimental deviations indicate the need for revision of the simplifying approximations used in the above models. Within this context, models encompassing asymmetry are considered which include different vibrational and solvation force constants for the electroactive species. The assumption of non-adiabatic electron transfer is also examined. These refinements have provided more satisfactory models of the electron transfer process and they enable us to gain more information about the microscopic characteristics of the system by means of simple electrochemical measurements.

  3. Steady state oxygen reduction and cyclic voltammetry

    DEFF Research Database (Denmark)

    Rossmeisl, Jan; Karlberg, Gustav; Jaramillo, Thomas;

    2008-01-01

    The catalytic activity of Pt and Pt3Ni for the oxygen reduction reaction is investigated by applying a Sabatier model based on density functional calculations. We investigate the role of adsorbed OH on the activity, by comparing cyclic voltammetry obtained from theory with previously published...... experimental results with and without molecular oxygen present. We find that the simple Sabatier model predicts both the potential dependence of the OH coverage and the measured current densities seen in experiments, and that it offers an understanding of the oxygen reduction reaction (ORR) at the atomic level....... To investigate kinetic effects we develop a simple kinetic model for ORR. Whereas kinetic corrections only matter close to the volcano top, an interesting outcome of the kinetic model is a first order dependence on the oxygen pressure. Importantly, the conclusion obtained from the simple Sabatier...

  4. FIELD MEASUREMENT TECHNOLOGY FOR MERCURY IN SOIL AND SEDIMENT MTI INC'S PDV 6000 STRIPPING VOLTAMMETRY

    Science.gov (United States)

    Monitoring Technologies International Pty. Ltd. (MTI) has developed a Portable Digital Voltammeter (PDV) designed to identify and measure the concentration of heavy metal ions. MTI's PDV 6000 was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Tec...

  5. Double-Polymer-Modified Pencil Lead for Stripping Voltammetry of Perchlorate in Drinking Water

    Science.gov (United States)

    Izadyar, Anahita; Kim, Yushin; Ward, Michelle M.; Amemiya, Shigeru

    2012-01-01

    The inexpensive and disposable electrode based on a double-polymer-modified pencil lead is proposed for upper-division undergraduate instrumental laboratories to enable the highly sensitive detection of perchlorate. Students fabricate and utilize their own electrodes in the 3-4 h laboratory session to learn important concepts and methods of…

  6. Investigation of carbon supported PtW catalysts as CO tolerant anodes at high temperature in proton exchange membrane fuel cell

    Science.gov (United States)

    Hassan, Ayaz; Paganin, Valdecir A.; Ticianelli, Edson A.

    2016-09-01

    The CO tolerance mechanism and the stability of carbon supported PtW electrocatalysts are evaluated in the anode of a proton exchange membrane fuel cell (PEMFC) at two different temperatures. The electrocatalysts are characterized by energy dispersive spectroscopy, X-ray diffraction, and transmission electron spectroscopy. Employed electrochemical techniques include cyclic voltammetry, CO stripping, fuel cell polarization, and online mass spectrometry. At a cell temperature of 85 °C, the PtW/C catalyst shows higher CO tolerance compared to Pt/C due an electronic effect of WOx in the Pt 5d band, which reduces the CO adsorption. An increase in hydrogen oxidation activity in the presence of CO is observed for both the catalysts at a higher temperature, due to the decrease of the Pt-CO coverage. A reduction in the current densities occurs for the PtW/C catalyst in both polarization curves and cyclic voltammograms after 5000 cycles of the anode in the range of 0.1-0.7 V vs. RHE at 50 mVs-1. This decrease in performance is assigned to the dissolution of W, with a consequent increase in the membrane resistivity. However, the observed decline of performance is small either in the presence of pure H2 or in the presence of H2/CO.

  7. Studies on anodic corrosion of the electroplated CdSe in aqueous and non-aqueous media for photoelectrochemical cells and characterization of the electrode/electrolyte interface

    International Nuclear Information System (INIS)

    Polycrystalline n-CdSe thin films were prepared by electrodeposition at controlled current density on conducting substrates. The optical characteristics were determined through transmittance spectra. Scanning electron microscopy and atomic force microscopy were employed to study the morphology of the semiconductor (SC) surfaces. Chemical composition of the SC film was established by EDAX analysis. The n-CdSe/electrolyte junctions in water and non-aqueous solvents like acetonitrile (ACN), dimethyl formamide (DMF), dimethyl sulphoxide (DMSO) and propylene carbonate (PC) were characterized by Mott-Schottky analysis using frequency response analyzer. The stability of CdSe layers in water and in non-aqueous solvents was determined through anodic polarization studies. Anodic stripping voltammetry was employed to find out the dissoluted Cd2+ in solution. Photovoltage was measured under illuminated conditions using ferrocene-ferricenium couple in aqueous and non-aqueous solvents throughout the temperature range of 20-70 deg. C. The results are indicative of the potential use of the electrodeposited n-CdSe in selected non-aqueous medium for solar energy conversion by photoelectrochemical (PEC) devices

  8. Ralicon anodes for image photon counting fabricated by electron beam lithography

    International Nuclear Information System (INIS)

    The Anger wedge and strip anode event location system developed for microchannel plate image photon detectors at the Space Sciences Laboratory of the University of California, Berkeley, has been extended in the present work by the use of electron beam lithography (EBL). This method of fabrication can be used to produce optical patterns for the subsequent manufacture of anodes by conventional photo-etching methods and has also enabled anodes to be produced directly by EBL microfabrication techniques. Computer-aided design methods have been used to develop several types of RALICON (Readout Anodes of Lithographic Construction) for use in photon counting microchannel plate imaging detectors. These anodes are suitable for linear, two dimensional or radial position measurements and they incorporate novel design features made possible by the EBL fabrication technique which significantly extend their application relative to published wedge-strip anode designs. (author)

  9. Anatomy comic strips.

    Science.gov (United States)

    Park, Jin Seo; Kim, Dae Hyun; Chung, Min Suk

    2011-01-01

    Comics are powerful visual messages that convey immediate visceral meaning in ways that conventional texts often cannot. This article's authors created comic strips to teach anatomy more interestingly and effectively. Four-frame comic strips were conceptualized from a set of anatomy-related humorous stories gathered from the authors' collective imagination. The comics were drawn on paper and then recreated with digital graphics software. More than 500 comic strips have been drawn and labeled in Korean language, and some of them have been translated into English. All comic strips can be viewed on the Department of Anatomy homepage at the Ajou University School of Medicine, Suwon, Republic of Korea. The comic strips were written and drawn by experienced anatomists, and responses from viewers have generally been favorable. These anatomy comic strips, designed to help students learn the complexities of anatomy in a straightforward and humorous way, are expected to be improved further by the authors and other interested anatomists. PMID:21634024

  10. Protein-film voltammetry: A theoretical study of the temperature effect using square-wave voltammetry

    OpenAIRE

    Gulaboski, Rubin; Lovrić, Milivoj; Mirceski, Valentin; Bogeski, Ivan; Hoth, Markus

    2008-01-01

    Square-wave voltammetry of surface redox reactions is considered as an adequate model for a protein-film voltammetric setup. Here we develop a theoretical approach to analyze the effects of temperature on squarewave voltammograms. The performed simulations address the surface redox reactions featuring slow, modest and fast electron transfer. The theoretical calculations show that the temperature affects the squarewave voltammetric responses in a complex way resulting in a variety ...

  11. Development of floating strip micromegas detectors

    Energy Technology Data Exchange (ETDEWEB)

    Bortfeldt, Jonathan

    2014-04-28

    Micromegas are high-rate capable, high-resolution micro-pattern gaseous detectors. Square meter sized resistive strip Micromegas are foreseen as replacement of the currently used precision tracking detectors in the Small Wheel, which is part of the forward region of the ATLAS muon spectrometer. The replacement is necessary to ensure tracking and triggering performance of the muon spectrometer after the luminosity increase of the Large Hadron Collider beyond its design value of 10{sup 34} cm{sup -2}s{sup -1} around 2020. In this thesis a novel discharge tolerant floating strip Micromegas detector is presented and described. By individually powering copper anode strips, the effects of a discharge are confined to a small region of the detector. This reduces the impact of discharges on the efficiency by three orders of magnitude, compared to a standard Micromegas. The physics of the detector is studied and discussed in detail. Several detectors are developed: A 6.4 x 6.4 cm{sup 2} floating strip Micromegas with exchangeable SMD capacitors and resistors allows for an optimization of the floating strip principle. The discharge behavior is investigated on this device in depth. The microscopic structure of discharges is quantitatively explained by a detailed detector simulation. A 48 x 50 cm{sup 2} floating strip Micromegas is studied in high energy pion beams. Its homogeneity with respect to pulse height, efficiency and spatial resolution is investigated. The good performance in high-rate background environments is demonstrated in cosmic muon tracking measurements with a 6.4 x 6.4 cm{sup 2} floating strip Micromegas under lateral irradiation with 550 kHz 20 MeV proton beams. A floating strip Micromegas doublet with low material budget is developed for ion tracking without limitations from multiple scattering in imaging applications during medical ion therapy. Highly efficient tracking of 20 MeV protons at particle rates of 550 kHz is possible. The reconstruction of the

  12. Anodic passivation of Pb-Ag-Nd anode in fluoride-containing H2SO4 solution

    Institute of Scientific and Technical Information of China (English)

    钟晓聪; 蒋良兴; 刘芳洋; 李劼; 刘业翔

    2015-01-01

    An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process was investigated using cyclic voltammetry, linear scanning voltammetry, environmental scanning electron microscopy and X-ray diffraction analysis. The results show that PbF2 and PbSO4 are formed near the potential of Pb/PbSO4 couple. The pre-treatment in fluoride-containing H2SO4 solution contributes to the formation of a thick, compact and adherent passive film. Furthermore, pre-treatment in fluoride-containing H2SO4 solution also facilitates the formation of PbO2 on the anodic layer, and the reason could be attributed to the formation of more PbF2 and PbSO4 during the pre-treatment which tend to transform to PbO2 during the following electrowinning process. In addition, the anodic layer on anode with pre-treatment in fluoride-containing H2SO4 solution is thick and compact, and its predominant composition isβ-PbO2. In summary, the pre-treatment in fluoride-containing H2SO4 solution benefits the formation of a desirable protective layer in a short time.

  13. Novel Ceramic Materials for Polymer Electrolyte Membrane Water Electrolysers' Anodes

    DEFF Research Database (Denmark)

    Polonsky, J.; Bouzek, K.; Prag, Carsten Brorson;

    2012-01-01

    Tantalum carbide was evaluated as a possible new support for the IrO2 for use in anodes of polymer electrolyte membrane water electrolysers. A series of supported electrocatalysts varying in mass content of iridium oxide was prepared. XRD, powder conductivity measurements and cyclic and linear...... sweep voltammetry were used to characterise the electrocatalysts. The most performing composition was found to lie between 50 and 90 wt.% IrO2 on TaC...

  14. ALICE silicon strip module

    CERN Multimedia

    Maximilien Brice

    2006-01-01

    This small silicon detector strip will be inserted into the inner tracking system (ITS) on the ALICE detector at CERN. This detector relies on state-of-the-art particle tracking techniques. These double-sided silicon strip modules have been designed to be as lightweight and delicate as possible as the ITS will eventually contain five square metres of these devices.

  15. Anatomy Comic Strips

    Science.gov (United States)

    Park, Jin Seo; Kim, Dae Hyun; Chung, Min Suk

    2011-01-01

    Comics are powerful visual messages that convey immediate visceral meaning in ways that conventional texts often cannot. This article's authors created comic strips to teach anatomy more interestingly and effectively. Four-frame comic strips were conceptualized from a set of anatomy-related humorous stories gathered from the authors' collective…

  16. Science Comic Strips

    Science.gov (United States)

    Kim, Dae Hyun; Jang, Hae Gwon; Shin, Dong Sun; Kim, Sun-Ja; Yoo, Chang Young; Chung, Min Suk

    2012-01-01

    Science comic strips entitled Dr. Scifun were planned to promote science jobs and studies among professionals (scientists, graduate and undergraduate students) and children. To this end, the authors collected intriguing science stories as the basis of scenarios, and drew four-cut comic strips, first on paper and subsequently as computer files.…

  17. Determination of antioxidant activity of spices and their active principles by differential pulse voltammetry.

    Science.gov (United States)

    Palma, Alberto; Ruiz Montoya, Mercedes; Arteaga, Jesús F; Rodríguez Mellado, Jose M

    2014-01-22

    The anodic oxidation of mercury in the presence of hydrogen peroxide in differential pulse voltammetry (DPV) was used to determine the antioxidant (AO) character of radical scavengers. Hydroperoxide radical is formed at the potentials of the oxidation peak on mercury electrodes, such radical reacting with the antioxidants in different extension. The parameter C10 (antioxidant concentration at which the peak area decreases by 10%) is used to measure the scavenging activity of the individual antioxidants. To establish the scavenging activity of antioxidant mixtures as a whole, the parameter, μ10 as the reverse of V10, V10 being the volume necessary to decrease the peak area in DPV by 10%, was selected. Higher μ10 values correspond to higher scavenging activity. The studies have been extended to aqueous extracts of some species. The results may be useful in explaining the effect of spices in vitro and in vivo studies.

  18. Ascorbic Acid Determination in Commercial Fruit Juice Samples by Cyclic Voltammetry

    Science.gov (United States)

    Pisoschi, Aurelia Magdalena; Danet, Andrei Florin; Kalinowski, Slawomir

    2008-01-01

    A method was developed for assessing ascorbic acid concentration in commercial fruit juice by cyclic voltammetry. The anodic oxidation peak for ascorbic acid occurs at about 490 mV on a Pt disc working electrode (versus SCE). The influence of the potential sweep speed on the peak height was studied. The obtained calibration graph shows a linear dependence between peak height and ascorbic acid concentration in the domain (0.1–10 mmol·L−1). The equation of the calibration graph was y = 6.391x + 0.1903 (where y represents the value of intensity measured for the anodic peak height, expressed as μA and x the analyte concentration, as mmol·L−1, r2 = 0.9995, r.s.d. = 1.14%, n = 10, Cascorbic acid = 2 mmol·L−1). The developed method was applied to ascorbic acid assessment in fruit juice. The ascorbic acid content determined ranged from 0.83 to 1.67 mmol·L−1 for orange juice, from 0.58 to 1.93 mmol·L−1 for lemon juice, and from 0.46 to 1.84 mmol·L−1 for grapefruit juice. Different ascorbic acid concentrations (from standard solutions) were added to the analysed samples, the degree of recovery being comprised between 94.35% and 104%. Ascorbic acid determination results obtained by cyclic voltammetry were compared with those obtained by the volumetric method with dichlorophenol indophenol. The results obtained by the two methods were in good agreement. PMID:19343183

  19. Enhancing hybrid direct carbon fuel cell anode performance using Ag2O

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Ippolito, Davide; Kammer Hansen, Kent

    2015-01-01

    A hybrid-direct carbon fuel cell (HDCFC), consisting of a molten slurry of solid carbon black and (Li-K)2CO3 added to the anode chamber of a solid oxide fuel cell, was characterized using current-potential-power density curves, electrochemical impedance spectroscopy, and cyclic voltammetry. Two t...

  20. Stoichiometry and Formation Constant Determination by Linear Sweep Voltammetry.

    Science.gov (United States)

    Schultz, Franklin A.

    1979-01-01

    In this paper an experiment is described in which the equilibrium constants necessary for determining the composition and distribution of lead (II)-oxalate species may be measured by linear sweep voltammetry. (Author/BB)

  1. Voltammetry of the Anticancer Drug Mitoxantrone and DNA

    OpenAIRE

    Erdem, Arzum; ÖZSÖZ, Mehmet

    2001-01-01

    The interaction of mitoxantrone (MTX) with calf thymus double-stranded DNA (dsDNA) and calf thymus single-stranded DNA (ssDNA) was studied electrochemically by using differential pulse voltammetry (DPV) and cyclic voltammetry (CV) at a carbon paste electrode (CPE). The changes in the experimental parameters (the concentration of MTX, the concentration of DNA and the accumulation time of MTX) were studied by DPV; in addition, the detection limit and the reproducibility were determined....

  2. Recent achievements in square-wave voltammetry (a review)

    OpenAIRE

    Mirceski, Valentin; Gulaboski, Rubin

    2014-01-01

    Recent advances in square-wave voltammetry for analytical purposes as well as for studying electrode mechanisms and kinetics are reviewed, mainly covering results published in the last decade. Analyzing only some typical analytically oriented studies, one confirms the well-known fact that the technique is attributed with superior analytical performance in the family of advance pulse voltammetric techniques. Covering all analytical studies where square-wave voltammetry is the worki...

  3. High-Rate Capable Floating Strip Micromegas

    CERN Document Server

    Bortfeldt, Jonathan; Biebel, Otmar; Danger, Helge; Flierl, Bernhard; Hertenberger, Ralf; Lösel, Philipp; Moll, Samuel; Parodi, Katia; Rinaldi, Ilaria; Ruschke, Alexander; Zibell, André

    2015-01-01

    We report on the optimization of discharge insensitive floating strip Micromegas (MICRO-MEsh GASeous) detectors, fit for use in high-energy muon spectrometers. The suitability of these detectors for particle tracking is shown in high-background environments and at very high particle fluxes up to 60MHz/cm$^2$. Measurement and simulation of the microscopic discharge behavior have demonstrated the excellent discharge tolerance. A floating strip Micromegas with an active area of 48cm$\\times$50cm with 1920 copper anode strips exhibits in 120GeV pion beams a spatial resolution of 50$\\mu$m at detection efficiencies above 95%. Pulse height, spatial resolution and detection efficiency are homogeneous over the detector. Reconstruction of particle track inclination in a single detector plane is discussed, optimum angular resolutions below $5^\\circ$ are observed. Systematic deviations of this $\\mu$TPC-method are fully understood. The reconstruction capabilities for minimum ionizing muons are investigated in a 6.4cm$\\time...

  4. Increased performance of a tubular microbial fuel cell with a rotating carbon-brush anode.

    Science.gov (United States)

    Liao, Qiang; Zhang, Jun; Li, Jun; Ye, Dingding; Zhu, Xun; Zhang, Biao

    2015-01-15

    A novel method was proposed to improve the power output of microbial fuel cells (MFCs) by rotating the carbon-brush anode. The MFC with a rotating anode produced a peak power density of 210±3 W/m(3) and a maximum current density of 945±43 A/m(3), 1.4 and 2.7 times higher than those of the non-rotating case, respectively. The difference of the electrochemical impedance spectroscopy and cyclic voltammetry before and after anode rotation clearly suggested that the mass transfer to the spiral space was enhanced by the rotating anode. Furthermore, Tafel plots analysis also revealed that the rotating anode can improve the electrochemical activity of the biofilm. PMID:25168763

  5. micro strip gas chamber

    CERN Multimedia

    1998-01-01

    About 16 000 Micro Strip Gas Chambers like this one will be used in the CMS tracking detector. They will measure the tracks of charged particles to a hundredth of a millimetre precision in the region near the collision point where the density of particles is very high. Each chamber is filled with a gas mixture of argon and dimethyl ether. Charged particles passing through ionise the gas, knocking out electrons which are collected on the aluminium strips visible under the microscope. Such detectors are being used in radiography. They give higher resolution imaging and reduce the required dose of radiation.

  6. E-tongue 2 REDOX response to heavy metals

    Science.gov (United States)

    Buehler, M. G.; Kuhlman, G. M.; Kounaves, S. P.

    2002-01-01

    E-Tongue 2 an array of electrochemical sensors including REDOX electrodes for Cylic Voltammetry and Anodic Stripping Voltammetry measurements, Galvanic cells for corrosion measurements, and Ion Selective Electrodes.

  7. ALICE Silicon Strip Detector

    CERN Multimedia

    Nooren, G

    2013-01-01

    The Silicon Strip Detector (SSD) constitutes the two outermost layers of the Inner Tracking System (ITS) of the ALICE Experiment. The SSD plays a crucial role in the tracking of the particles produced in the collisions connecting the tracks from the external detectors (Time Projection Chamber) to the ITS. The SSD also contributes to the particle identification through the measurement of their energy loss.

  8. Rapid Screening Method for Detecting Ethinyl Estradiol in Natural Water Employing Voltammetry

    Science.gov (United States)

    2016-01-01

    17α-Ethinyl estradiol (EE2), which is used worldwide in the treatment of some cancers and as a contraceptive, is often found in aquatic systems and is considered a pharmaceutically active compound (PhACs) in the environment. Current methods for the determination of this compound, such as chromatography, are expensive and lengthy and require large amounts of toxic organic solvents. In this work, a voltammetric procedure is developed and validated as a screening tool for detecting EE2 in water samples without prior extraction, clean-up, or derivatization steps. Application of the method we elaborate here to EE2 analysis is unprecedented. EE2 detection was carried out using differential pulse adsorptive cathodic stripping voltammetry (DP AdCSV) with a hanging mercury drop electrode (HMDE) in pH 7.0 Britton-Robinson buffer. The electrochemical process of EE2 reduction was investigated by cyclic voltammetry at different scan rates. Electroreduction of the hormone on a mercury electrode exhibited a peak at −1.16 ± 0.02 V versus Ag/AgCl. The experimental parameters were as follows: −0.7 V accumulation potential, 150 s accumulation time, and 60 mV s−1 scan rate. The limit of detection was 0.49 μg L−1 for a preconcentration time of 150 s. Relative standard deviations were less than 13%. The method was applied to the detection of EE2 in water samples with recoveries ranging from 93.7 to 102.5%. PMID:27738548

  9. Stripping voltammetric behavior of technetium at various chemically modified electrodes

    International Nuclear Information System (INIS)

    In monitoring of nuclear processing plants and storage facilities the necessity arises of assaying traces of the artificial radioactive element technetium. The oxidation states IV and VII are of particular interest. Stripping voltammetry is among the methods of assay which are suited for this purpose. It allows an enhanced selectivity to be achieved by preconcentration of the analyte and of an oxidation state of the analyte, respectively, at the electrode used. This specific enrichment is successful after appropriate chemical modification of the electrode through immobilization of a Tc-specific reagent. When various approaches of chemical modification of a glassy carbon electrode were examined, the tetraphenylarsonium chloride extractant, which is highly selective with respect to technetium, proved to be the best suited reagent, capable of fixation both by ionic and by covalent bonding on an electrodeposited polymer film. For ionic immobilization the reagent was reacted to m-sulfophenyltriphenyl arsonium and then bound to a copolymer of vinylferrocene and vinylpyridine, which had been provided with cations. It was possible to enrich Tc(VII) at such an electrode and to determine it by stripping voltammetry down to a concentration of 1x10-8 M after 5 minutes enrichment time. (orig./EF)

  10. Characterization and Calibration of Large Area Resistive Strip Micromegas Detectors

    CERN Document Server

    Losel, Philipp Jonathan; The ATLAS collaboration

    2015-01-01

    Resisitve strip Micromegas detectors behave discharge tolerant. They have been tested extensively as smaller detectors of about 10 x 10 cm$^2$ in size and they work reliably at high rates of 100\\,kHz/cm$^2$ and above. Tracking resolutions well below 100\\,$\\mu$m have been observed for 100 GeV muons and pions. Micromegas detectors are meanwhile proposed as large area muon precision trackers of 2-3\\,m$^2$ in size. To investigate possible differences between small and large detectors, a 1\\,m$^2$ detector with 2048 resistive strips at a pitch of 450 $\\mu$m was studied in the LMU Cosmic Ray Facility (CRF) using two 4 $\\times$ 2.2 m$^2$ large Monitored Drift Tube (MDT) chambers for cosmic muon reference tracking. Segmentation of the resistive strip anode plane in 57.6\\,mm x 95\\,mm large areas has been realized by the readout of 128 strips with one APV25 chip each and by 11 95\\,mm broad trigger scintillators placed along the readout strips.\\\\ This allows for mapping of homogenity in pulse height and efficiency, deter...

  11. Characterization and Calibration of Large Area Resistive Strip Micromegas Detectors

    CERN Document Server

    Losel, Philipp Jonathan; The ATLAS collaboration

    2015-01-01

    Resistive strip Micromegas detectors are discharge tolerant. They have been tested extensively as small detectors of about 10 x 10 cm$^2$ in size and they work reliably at high rates of 100 kHz/cm$^2$ and above. Tracking resolution well below 100 $\\mu$m has been observed for 100 GeV muons and pions. Micromegas detectors are meanwhile proposed as large area muon precision trackers of 2-3 m$^2$ in size. To investigate possible differences between small and large detectors, a 1 m$^2$ detector with 2048 resistive strips at a pitch of 450 $\\mu$m was studied in the LMU Cosmic Ray Measurement Facility (CRMF) using two 4 $\\times$ 2.2 m$^2$ large Monitored Drift Tube (MDT) chambers for cosmic muon reference tracking. A segmentation of the resistive strip anode plane in 57.6 mm x 93 mm large areas has been realized by the readout of 128 strips with one APV25 chip each and by eleven 93 mm broad trigger scintillators placed along the readout strips. This allows for mapping of homogeneity in pulse height and efficiency, d...

  12. Fast Selective Detection of Pyocyanin Using Cyclic Voltammetry

    DEFF Research Database (Denmark)

    Al Atraktchi, Fatima Al-Zahraa; Breum Andersen, Sandra; Johansen, Helle Krogh;

    2016-01-01

    selective method to detect pyocyanin in a complex electroactive environment using commercially available electrodes. It is shown that cyclic voltammetry measurements between –1.0 V to 1.0 V reveal a potential detection window of pyocyanin of 0.58–0.82 V that is unaffected by other redox-active interferents...

  13. Square wave voltammetry at the dropping mercury electrode: Theory

    Science.gov (United States)

    Christie, J.H.; Turner, J.A.; Osteryoung, R.A.

    1977-01-01

    The theoretical aspects of square wave voltammetry at the dropping mercury electrode are presented. The technique involves scanning the entire potential range of interest on a single drop of a DME. Asymmetries in the waveform as well as variations in current measurement parameters are discussed. Indications are that previous uses of the waveform may not have utilized all its capabilities.

  14. Protein-film voltammetry-Electrochemical Enzymatic Spectroscopy

    OpenAIRE

    Gulaboski, Rubin

    2013-01-01

    In this lecture, the new approach for studying the redox features of various enzymes is presented. Details are given about performing an electrochemical experiment with redox active proteins, while attention is paid to theoretical modeling of protein-film voltammetric experiments in cyclic and square-wave voltammetry. The use of this set-up for designing biosensors is also discussed.

  15. A Cyclic Voltammetry Experiment for the Instrumental Analysis Laboratory.

    Science.gov (United States)

    Baldwin, Richard P.; And Others

    1984-01-01

    Background information and procedures are provided for experiments that illustrate the nature of cyclic voltammetry and its application in the characterization of organic electrode processes. The experiments also demonstrate the concepts of electrochemical reversibility and diffusion-controlled mass transfer. (JN)

  16. Surface-plasmon voltammetry using a gold grating

    OpenAIRE

    Jory, M J; Cann, P S; J. R. Sambles

    2010-01-01

    Abstract Using a sensitive optical wavelength modulation technique the surface-plasmon excited on a gold grating surface immersed in sulphuric acid is studied at the same time as cyclic voltammetry is undertaken. Because of the optical sensitivity of the modulation technique significant optical effects are observed at potentials well below those at which any gross oxidation effects occur.

  17. Square-Wave Voltammetry: A Review on the Recent Progress

    OpenAIRE

    Mirceski, Valentin; Gulaboski, Rubin; Lovrić, Milivoj; Bogeski, Ivan; Kappl, Reinhard; Hoth, Markus

    2013-01-01

    A review on the recent progress of square-wave voltammetry is presented, covering the period of the last five years. The review addresses the new theoretical development of the technique as well as its application for mechanistic purposes, electrode kinetic measurements, biochemical and analytical applications. Besides, a few novel methodological modifications are proposed that might expand the scope and application of the technique.

  18. Anodic behaviour of WC-Co type hardmetal

    Energy Technology Data Exchange (ETDEWEB)

    Bozzini, B.; Fanigliulo, A.; Mele, C. [INFM - Dipartimento di Ingegneria dell' Innovazione, Universita di Lecce, v. Monteroni, I-73100 Lecce (Italy); De Gaudenzi, G.P. [Harditalia s.r.l. (OMCD Group) v. Genova 9, I-21040 Oggiona con S. Stefano (Italy)

    2003-05-01

    An understanding of the anodic behaviour of WC-Co type hardmetals is vital for the functional behaviour of this class of materials. The anodic oxidation of WC-13Co grade hardmetal in 0.1 M H{sub 2}SO{sub 4} was investigated. This study is based on electrochemical (linear sweep voltammetry, cyclic voltammetry, impedance spectroscopy), compositional (energy dispersive spectroscopy), structural (X-ray diffraction) and morphological (scanning electron microscopy) investigations. The potential range in which the oxidation of the Co-alloy takes place with respect to the nobler carbide phase was defined. Within this potential interval a passivating behaviour for the binder alloy was shown. The potential threshold for WC oxidation was identified by monitoring the inception of the electrochromic loop. The anodic attack gives rise to the formation of hydrous WO{sub 3}. The attack morphology is characterised by the alteration of the grain shape with formation of jelly-like microscopic and flaky macroscopic structures. (Abstract Copyright [2003], Wiley Periodicals, Inc.) [German] Das Verstaendnis des anodischen Verhaltens von Hartmetallen des Typs WC-Co ist entscheidend fuer das funktionale Verhalten dieser Werkstoffklasse. Das anodische Verhalten des Hartmetalls WC-13Co wurde in 0,1 M H{sub 2}SO{sub 4} untersucht. Diese Studie basiert auf elektrochemischen (lineare Abtastvoltammetrie, zyklische Voltammetrie, Impedanzspektroskopie), strukturellen (Roentgendiffraktometrie), morphologischen (Rasterelektronenmikroskopie) sowie Untersuchungen zur Zusammensetzung (energiedispersive Spektroskopie). Der Potentialbereich, in dem die Oxidation der Co-Legierung bezueglich der edleren Karbidphase stattfindet, wurde bestimmt. Innerhalb dieses Potentialintervalls konnte ein passivierendes Verhalten fuer die Bindemittelphase gezeigt werden. Der Potentialgrenzwert fuer die WC-Oxidation wurde durch Ueberwachung des Beginns der elektrochromischen Schleife identifiziert. Der anodische Angriff

  19. The influence of carbon dioxide on PEM fuel cell anodes

    Science.gov (United States)

    de Bruijn, F. A.; Papageorgopoulos, D. C.; Sitters, E. F.; Janssen, G. J. M.

    The influence of CO 2 on the performance of PEM fuel cells was investigated by means of fuel cell experiments and cyclic voltammetry. Depending on the composition and microstructure of the fuel cell anode, the effect varies from small to significant. Adsorbed hydrogen plays a dominant role in the formation of CO-like species via the reverse water-gas shift reaction. Platinum sites which are not utilized in the electrochemical oxidation of hydrogen are thought to catalyze this reverse-shift reaction. Alloying with ruthenium suppresses the reverse-shift reaction.

  20. Use of tungsten anodes in microgap gas chambers

    International Nuclear Information System (INIS)

    In a continuation of the authors' earlier tests, tungsten has been used for anode strips in the fabrication of microgap gas chambers (MGCs) in an attempt to find a metallization suitable for gas avalanche microdetectors (MSGCs or MGCs) that will be both highly robust against sparking and yet have sufficiently low resistivity to permit use of detectors of relatively larger sizes. MGCs having about 5,500 and 7,500 angstrom thick tungsten anodes were fabricated using a sputtering technique, and the sheet resistances for these layers were measured as 0.42 and 0.27 Ω/□, respectively. The detectors were subjected to sparks having a range of energies, and the damage to the anode strips was assessed using optical and scanning electron microscope (SEM) photographs, and by measuring leakage current before and after sparking. In this paper, the spark damage test results of tungsten anodes in MGCs are reported, and an interpretation is made regarding the viability of use of this metal for larger sizes of detectors

  1. A cyclic voltammetry study of the electrochemical behavior of platinum in oxide-ion rich LiCl melts

    International Nuclear Information System (INIS)

    Electrochemical behavior of platinum in LiCl and LiCl-(1-3) wt% Li2O melts at 650 °C was studied by cyclic voltammetry in the context of its use as anode in the direct electrochemical reduction of solid uranium oxide to uranium metal. By CV measurements with graphite and platinum (anodic polarization) and tungsten (cathodic polarization) working electrodes, the decomposition potential of LiCl and electrochemical potential of the reaction Pt + 2LiCl → PtCl2 + 2Li were determined as 3.46 V and 3.14 V respectively. Three anodic reactions viz. (i) formation of Li2PtO3, (ii) oxygen evolution and (iii) platinum dissolution were found to occur on the platinum electrode in Li2O containing LiCl melts. The Li2PtO3 formation was found to be a fast reaction with diffusion coefficient of O2− ions in the melt as 4.53 × 10−7cm2/s. Oxygen evolution showed very high current densities when compared to that of the surface area limiting Li2PtO3 formation. The platinum electrode surface was corroded by formation of Li2PtO3 when the electrode was polarized for a longer period of time in the melt. The results of the study indicated that LiCl-2 wt.% Li2O melt could be the optimum electrolyte composition in the electro-reduction of uranium oxide with platinum anode

  2. Exoelectrogenic bacterium phylogenetically related to Citrobacter freundii, isolated from anodic biofilm of a microbial fuel cell.

    Science.gov (United States)

    Huang, Jianjian; Zhu, Nengwu; Cao, Yanlan; Peng, Yue; Wu, Pingxiao; Dong, Wenhao

    2015-02-01

    An electrogenic bacterium, named Citrobacter freundii Z7, was isolated from the anodic biofilm of microbial fuel cell (MFC) inoculated with aerobic sewage sludge. Cyclic voltammetry (CV) analysis exhibited that the strain Z7 had relatively high electrochemical activity. When the strain Z7 was inoculated into MFC, the maximum power density can reach 204.5 mW/m(2) using citrate as electron donor. Series of substrates including glucose, glycerol, lactose, sucrose, and rhammose could be utilized to generate power. CV tests and the addition of anode solution as well as AQDS experiments indicated that the strain Z7 might transfer electrons indirectly via secreted mediators.

  3. Determination of 2,4,6-trichloroanisole by cyclic voltammetry

    OpenAIRE

    Freitas, Patrícia; Dias, L.G.; Peres, António M.; Luís M. de Castro; Veloso, Ana C. A.

    2012-01-01

    The electrochemical reduction of 2,4,6-trichloroanisole (TCA), which is a chlorinated arene with electron-donating substituents, was evaluated by cyclic voltammetry (CV). TCA is a major concern for the winery industry since it is related with “cork taint”, a wine defect. The results obtained in this work showed that CV could be used to detect and quantify TCA in preparative standard solutions. Linear relationships could be set between the current amplitude and TCA concentration (R...

  4. Plasmonic-based Imaging of Local Square Wave Voltammetry

    OpenAIRE

    Shan, Xiaonan; Wang, ShaoPeng; Wang, Wei; Tao, Nongjian

    2011-01-01

    Square wave voltammetry (SWV) is widely used in electrochemical analysis and sensors because of its high sensitivity and efficient rejection of background current, but SWV by conventional electrochemical detection method does not provide spatial resolution. We report here a plasmonic method to image local SWV, which opens the door for analyzing heterogeneous electrochemical reactions and for high throughput detections of microarrays. We describe the basic principle, validate the principle by ...

  5. New Cyclic Voltammetry Method for Examining Phase Transitions: Simulated Results

    OpenAIRE

    Hamad, I. Abou; Robb, D. T.; Rikvold, P. A.

    2006-01-01

    We propose a new experimental technique for cyclic voltammetry, based on the first-order reversal curve (FORC) method for analysis of systems undergoing hysteresis. The advantages of this electrochemical FORC (EC-FORC) technique are demonstrated by applying it to dynamical models of electrochemical adsorption. The method can not only differentiate between discontinuous and continuous phase transitions, but can also quite accurately recover equilibrium behavior from dynamic analysis of systems...

  6. Spray Rolling Aluminum Strip

    Energy Technology Data Exchange (ETDEWEB)

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  7. Thin-film voltammetry and its analytical applications: A review

    International Nuclear Information System (INIS)

    Highlights: • Electrochemistry at immiscible liquid–liquid interfaces is fundamentally important. • Methods for studying redox processes at liquid–liquid interfaces are reviewed. • Thin-film voltammetry is simple in experimental operation and kinetic data analysis. • Thin-film voltammetry’s analytical applications are prevailing and comprehensive. - Abstract: Electrochemical reactions at the interfaces of immiscible electrolyte solutions (ITIES) are of fundamental importance in the fields of chemical, biological and pharmaceutical sciences. Four-electrode cell setup, scanning electrochemical microscopy (SECM) and thin-film voltammetry are the three most frequently used methods for studying the electrochemical processes at these interfaces. The principle, experimental design, advantages and challenges of the three methods are described and compared. The thin-film voltammetry is highlighted for its simplicity in experimental operation and kinetic data analysis. Its versatile analytical applications are discussed in detail, including the study of redox properties of hydrophobic compounds, evaluation of interfacial electron transfer kinetics, synthesis of nanoparticles/nanostructures, and illustration of cross-membrane ion transport phenomena

  8. Comparison of Catalytic Activities of Carbon Supported Pt and Pt-Ru Catalysts for Methanol Oxidation in Neutral and Basic Media by Cyclic Voltammetry

    OpenAIRE

    KHAN, Abdul Sattar Ali; Ahmed, Riaz; MIRZA, Muhammad Latif

    2008-01-01

    The catalytic activities of an equal amount of 3 different carbon supported catalysts containing 10% Pt, 20% Pt + 10% Ru, and 30% Pt were evaluated in neutral and basic media for methanol oxidation by cyclic voltammetry. The prominent oxidation peak for methanol appeared in the forward anodic sweep at around 1.0 V in neutral medium, while in basic medium it appeared at significantly lower potential close to 0.2 V. The peak current for methanol oxidation was higher on a catalyst contai...

  9. Determination of Bosentan in Pharmaceutical Preparations by Linear Sweep, Square Wave and Differential Pulse Voltammetry Methods

    OpenAIRE

    Atila, Alptug; Yilmaz, Bilal

    2015-01-01

    In this study, simple, fast and reliable cyclic voltammetry (CV), linear sweep voltammetry (LSV), square wave voltammetry (SWV) and differential pulse voltammetry (DPV) methods were developed and validated for determination of bosentan in pharmaceutical preparations. The proposed methods were based on electrochemical oxidation of bosentan at platinum electrode in acetonitrile solution containing 0.1 M TBACIO4. The well-defined oxidation peak was observed at 1.21 V. The calibration curves were...

  10. Chemically modified flexible strips as electrochemical biosensors.

    Science.gov (United States)

    Thota, Raju; Ganesh, V

    2014-09-21

    A flexible and disposable strip sensor for non-enzymatic glucose detection is demonstrated in this work. The strips are prepared by using chemical modification processes followed by a simple electroless deposition of copper. Essentially, polyester overhead projector (OHP) transparent films are modified with a monolayer of 3-aminopropyltrimethoxysilane (APTMS) and polyaniline (PANI) conducting polymer. Later, nanostructured copper is deposited onto this modified film. Scanning electron microscope (SEM) and X-ray diffraction (XRD) studies are used for the structural, morphological and crystallinity characterization of the modified films. Electrochemical techniques, namely cyclic voltammetry (CV) and chronoamperometry (CA), are employed for the non-enzymatic detection of glucose. These studies clearly reveal the formation of homogeneous, close-packed spherical Cu particles converged into uniform film that exhibits a good catalytic activity towards the oxidation of glucose. The Cu/PANI/APTMS/OHP sensor displays a remarkable enhancement in the oxidation current density, a very high sensitivity value of 2.8456 mA cm(-2) per mM, and a linear concentration range from 100 μM to 6.5 mM associated with glucose detection. Detection limit is estimated to be 5 μM and the response time of the sensor is determined to be less than 5 s. For comparison, similar studies are performed without PANI, namely Cu/APTMS/OHP films for glucose detection. In this case, a sensitivity value of 2.4457 mA cm(-2) per mM and a linear concentration range of 100 μM-3 mM are estimated. The higher performance characteristics observed in the case of Cu/PANI/APTMS/OHP are attributed to the synergistic effects of the conducting polymer acting as an electron facilitator and the nanostructured Cu films. These disposable, flexible and low-cost strip sensors have also been applied to the detection of glucose in clinical blood serum samples and the results obtained agree very well with the actual glucose

  11. Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries

    Energy Technology Data Exchange (ETDEWEB)

    White, Ralph E.; Popov, Branko N.

    2002-10-31

    During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

  12. Direct electrodeposition of gold nanotube arrays of rough and porous wall by cyclic voltammetry and its applications of simultaneous determination of ascorbic acid and uric acid

    International Nuclear Information System (INIS)

    Gold nanotube arrays of rough and porous wall has been synthesized by direct electrodeposition with cyclic voltammetry utilizing anodic aluminum oxide template (AAO) and polycarbonate membrane (PC) during short time (only 3 min and 2 min, respectively). The mechanism of the direct electrodeposition of gold nanotube arrays by cyclic voltammetry (CV) has been discussed. The morphological characterizations of the gold nanotube arrays have been investigated by scanning electron microscopy (SEM). A simultaneous determination of ascorbic acid (AA) and uric acid (UA) by differential pulse voltammetry (DPV) was constructed by attaching gold nanotube arrays (using AAO) onto the surface of a glassy carbon electrode (GCE). The electrochemical behavior of AA and UA at this modified electrode has been studied by CV and differential pulse voltammetry (DPV). The sensor offers an excellent response for AA and UA and the linear response range for AA and UA were 1.02 × 10−7–5.23 × 10−4 mol L−1 and 1.43 × 10−7–4.64 × 10−4 mol L−1, the detection limits were 1.12 × 10−8 mol L−1 and 2.24 × 10−8 mol L−1, respectively. This sensor shows good regeneration, stability and selectivity and has been used for the determination of AA and UA in real human urine and serum samples with satisfied results. - Graphical abstract: The schematic diagram of formation of Au nanotube arrays (a) and the stepwise procedure of the sensor (b). Highlights: ► Gold nanotubes array has been synthesized by cyclic voltammetry. ► The mechanism of deposition of gold nanotube has been discussed. ► A determination of ascorbic acid and uric acid was constructed by gold array. ► A satisfied determination of samples can be obtained by this sensor.

  13. Strip shape control capability of hot wide strip rolling mills

    Institute of Scientific and Technical Information of China (English)

    Renzhong Wang; Quan Yang; Anrui He; Jian Shao; Haitao Bian

    2008-01-01

    The elasticity deformation of rolls was analyzed by means of two-dimensional f'mite element method (FEM) with vari-able thickness. Three typical mills were used as objects for analysis. A thorough study was done on the control capabilities of these mills on the strip shape. Then the strip shape control capabilities of the three mills was compared synthetically.

  14. Web-Based Cathode Strip Chamber Data Display

    CERN Multimedia

    Firmansyah, M

    2013-01-01

    Cathode Strip Chamber (CSC) is a detector that uses gas and high electric field to detect particles. When a particle goes through CSC, it will ionize gas particles and generate electric signal in the anode and cathode of the detector. Analysis of the electric signal data can help physicists to reconstruct path of the particles and determine what happen inside the detector. Using data display, analysis of CSC data becomes easier. One can determine which data is interesting, unusual, or maybe only contain noise.\

  15. Voltammetric and electrochemical impedance spectroscopy characterization of a cathodic and anodic pre-treated boron doped diamond electrode

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, S. Carlos B. [Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade de Coimbra, 3004-535 Coimbra (Portugal); Oliveira-Brett, Ana Maria, E-mail: brett@ci.uc.p [Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade de Coimbra, 3004-535 Coimbra (Portugal)

    2010-06-01

    The effect of boron doped diamond (BDD) surface termination, immediately after cathodic and anodic electrochemical pre-treatments, on the electrochemical response of a BDD electrode in aqueous media and the influence of the different supporting electrolytes utilized in these pre-treatments on the final surface termination was investigated with [Fe(CN){sub 6}]{sup 4-/3-}, as redox probe, by cyclic and differential pulse voltammetry and electrochemical impedance spectroscopy. The cyclic voltammetry results indicate that the electrochemical behavior for the redox couple [Fe(CN){sub 6}]{sup 4-/3-} is very dependent on the state of the BDD surface, and a reversible response was observed after the cathodic electrochemical pre-treatment, whereas a quasi-reversible response occurred after anodic electrochemical pre-treatment. Differential pulse voltammetry in acetate buffer also showed that the potential window is very much influenced by the electrochemical pre-treatment of the BDD surface. Electroactivity of non-diamond carbon surface species (sp{sup 2} inclusions) incorporated into the diamond structure was observed after cathodic and anodic pre-treatments. Electrochemical impedance spectroscopy confirmed the cyclic voltammetry results and indicates that the BDD surface resistance and capacitance vary significantly with the electrolyte and with the electrochemical pre-treatment, caused by different surface terminations of the BDD electrode surface.

  16. Complex zero strip decreasing operators

    OpenAIRE

    Cardon, David A.

    2013-01-01

    In this paper we study the effect of linear differential operators coming from the Laguerre-Polya class that act on functions in the extended Laguerre-Polya class with zeros in a horizontal strip in the complex plane. These operator decrease the size of the strip containing the zeros.

  17. Design and optimization of resistive anode for a two-dimensional imaging GEM detector

    Science.gov (United States)

    Ju, Xu-Dong; Dong, Ming-Yi; Zhao, Yi-Chen; Zhou, Chuan-Xing; Qun, Ou-Yang

    2016-08-01

    A resistive anode for two-dimensional imaging detectors, which consists of a series of high resistivity pads surrounded by low resistivity strips, can provide good spatial resolution while reducing the number of electronics channels required. The optimization of this kind of anode has been studied by both numerical simulations and experimental tests. It is found that to obtain good detector performance, the resistance ratio of the pads to the strips should be larger than 5, the nonuniformity of the pad surface resistivity should be less than 20%, a smaller pad width leads to a smaller spatial resolution, and when the pad width is 6 mm, the spatial resolution (σ) can reach about 105 μm. Based on the study results, a 2-D GEM detector prototype with optimized resistive anode is constructed and a good imaging performance is achieved. Supported by National Natural Science Foundation of China (11375219) and CAS Center for Excellence in Particle Physics (CCEPP)

  18. Ni3Mo3C as anode catalyst for high-performance microbial fuel cells.

    Science.gov (United States)

    Zeng, Li-Zhen; Zhao, Shao-Fei; Li, Wei-Shan

    2015-03-01

    Ni3Mo3C was prepared by a modified organic colloid method and explored as anode catalyst for high-performance microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae). The prepared sample was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and Brunauer-Emmett-Teller (BET). The activity of the sample as anode catalyst for MFC based on K. pneumoniae was investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and polarization curve measurement. The results show that the adding of nickel in Mo2C increases the BET surface area of Mo2C and improves the electrocatalytic activity of Mo2C towards the oxidation of microbial fermentation products. The power density of MFC with 3 mg cm(-2) Ni3Mo3C anode is far higher than that of the MFC with carbon felt as anode without any catalyst, which is 19 % higher than that of Mo2C anode and produced 62 % as much as that of Pt anode, indicating that Ni3Mo3C is comparative to noble metal platinum as anode electrocatalyst for MFCs by increasing the loading.

  19. Double anodization experiments in tantalum

    Energy Technology Data Exchange (ETDEWEB)

    Albella, J.M.; Fernandez, M.; Gomez-Aleixandre, C.; Martinez-Duart, J.M.; Montero, I.

    1985-10-01

    Based on our previous model of anodization, a new formula is given for the relation between the breakdown voltage V /SUB B/ during the anodic oxidation of tantalum and the anodization parameters. The formula predicts the well known diminution of V /SUB B/ with the logarithm of the electrolyte concentration. The model also explains the experimentally-observed fact that V /SUB B/ is solely determined by the latter electrolyte in double anodization experiments.

  20. In situ generation and detection of methyl radical by voltammetry

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In persulfate-acetate, dimethyl sulfoxide or tert-butyl alcohol systems, in situ generation and detection of methyl free radical are realized with voltammetry. It includes the following successive processes. The persulfate S2O82- is polarographically reduced via one-electron addition to sulfate radical SO4-., the SO4-. Initiates chain reaction with acetate, dimethyl sulfoxide, or tert-butyl alcohol on the electrode surface to produce a methyl radical, and one-electron reduction of the methyl radical yields its polarographic reduction wave. In comparison with the known techniques such as ultraviolet radiolysis coupling with electron spin resonance, etc., the proposed method is simple, sensitive and selective.

  1. Rapid Determination of Uranium in Water Samples by Adsorptive Cathodic Stripping Voltammetry Using a Tin-Bismuth Alloy Electrode

    International Nuclear Information System (INIS)

    In this work, the tin-bismuth alloy electrode (SnBiE) was used for U(VI) concentration determination for the first time. Compared to the conventional solid electrode (glassy carbon electrode and bismuth bulk electrode), the SnBiE possesses a higher hydrogen overpotential, which indicates that the tin-bismuth alloy can considerably extend the application of potentially available electrode detection systems. Combining with electrochemical behavior analysis and spectrometric measurements as well as theoretical calculation methods, the geometric structures of uranium-cupferron (N-nitrosophenylhydroxylamine) complexes have been revealed and a more detailed electrode mechanism has been proposed. The electroanalysis results show that the optimal sensitivity could be obtained by using diphenylguanidine as the auxiliary reagent. The calibration plot for U(VI) quantification was linear from 0.5 nM to 30 nM with a correlation coefficient of 0.999. In the meanwhile, a detection limit of 0.24 nM was obtained in connection with an accumulation time of 30 s, which is comparable with that of mercury analogues. The practical applications of SnBiE have been tentatively performed for the determination of UO22+ in real water samples and the results were well consistent with those by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). A very simple, convenient and cheap approach was established for the determination of UO22+ in natural water samples containing surfactants without the otherwise necessity of sample pretreatment, which drastically reduce the analysis time

  2. Modified strip saturation model for a cracked piezoelectric strip

    OpenAIRE

    R.R. Bhargava; A. Setia

    2008-01-01

    Purpose: The investigations aim to propose a model for arresting an electrical opening of a crack which weakensa narrow, poled and infinite piezoelectric strip. The edges of the strip are subjected to uniform, constant anti-planestresses and in-plane electrical displacements.Design/methodology/approach: The loads applied at the edges of the strip open the crack in a self-similar fashion.Consequently at each tip of the crack a saturation zone protrudes. To stop the crack from further opening t...

  3. Anodes for alkaline electrolysis

    Science.gov (United States)

    Soloveichik, Grigorii Lev

    2011-02-01

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  4. Inert Anode Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1999-07-01

    This ASME report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issues associated with these technologies from a technical, environmental, and economic viewpoint.

  5. The application of CVD diamond films in cyclic voltammetry

    Directory of Open Access Journals (Sweden)

    R. Torz-Piotrowska

    2009-12-01

    Full Text Available Purpose: The main purpose of these studies was to show the applicability of CVD (Chemical Vapour Deposition diamond layer in electrochemistry and to work out the technology of manufacturing diamond electrodes.Design/methodology/approach: The diamond films were deposited on tungsten substrate by HF CVD technique, and then, their quality was checked by Raman spectroscopy. It was shown, using Cyclic Voltammetry (CV measurements, that un-doped diamond films are chemically stable in aqueous solutions.Findings: The results of cyclic voltammetry measurements show that diamond electrode on tungsten substrate is electrochemically stable in aqueous solutions over a wide potential range (-3000 mV to 2000 mV. The Raman spectra confirmed the good quality of obtained diamond layer.Research limitations/implications: In particular, it was shown that diamond electrode showed a wide potential window, very low background current, chemical and physical stability.Practical implications: Presented results showed that CVD diamond films can find application in production of diamond electrodes for electrochemical application. The sensitivity of CVD diamond layers to the electroactive species indicates on possibility of application of this material for construction of chemical and biological sensors.Originality/value: The characteristics of diamond electrodes and the resistivity of this material to the chemical attack indicate that it can be employed in a number of electrochemical applications and additionally it can work in harsh environment. The HF CVD diamond layer seems to be the new, promising and versatile material for electrochemical applications.

  6. Hemispherical Shell Nanostructures from Metal-Stripped Embossed Alumina on Aluminum Templates

    DEFF Research Database (Denmark)

    Nielsen, Peter; Albrektsen, Ole; Simonsen, Adam Cohen;

    2011-01-01

    aluminum/ alumina (Al/Al2O3) templates as a novel and versatile nanofabrication procedure, and we demonstrate explicitly how to exploit the technique for developing large-area hexagonally close-packed hemispherical shell nanostructures by stripping noble metal layers from embossed templates fabricated from...... anodized Al. Utilizing for this process the linear relationship between anodization voltage and the resulting interpore distance in the formed oxide, it is possible to tune the radius of curvature of the resulting hemispherical shells continuously, which in turn results in tunable optical properties...

  7. ATLAS Strip Upgrade

    CERN Document Server

    Bernabeu, J; The ATLAS collaboration

    2012-01-01

    A phased upgrade of the Large Hadron Collider (LHC) at CERN is planned. The last upgrade phase (HL-LHC) is currently foreseen in 2022-2023. It aims to increase the integrated luminosity to about ten times the original LHC design luminosity. To cope with the harsh conditions in terms of particle rates and radiation dose expected during HL-LHC operation, the ATLAS collaboration is developing technologies for a complete tracker replacement. This new detector will need to provide extreme radiation hardness and a high granularity, within the tight constraints imposed by the existing detectors and their services. An all-silicon high granularity tracking detector is proposed. An international R&D collaboration is working on the strip layers for this new tracker. A number of large area prototype planar detectors produced on p-type wafers have been designed and fabricated for use at HL-LHC. These prototype detectors and miniature test detectors have been irradiated to a set of fluences matched to HL-LHC expectatio...

  8. ATLAS Strip Upgrade

    CERN Document Server

    Bernabeu, J; The ATLAS collaboration

    2012-01-01

    A phased upgrade of the Large Hadron Collider (LHC) at CERN is planned. The last upgrade phase (HL-LHC) is currently foreseen in 2022-2023. It aims to increase the integrated luminosity to about ten times the original LHC design luminosity. To cope with the harsh conditions in terms of particle rates and radiation dose expected during HL-LHC operation, the ATLAS collaboration is developing technologies for a complete tracker replacement. This new detector will need to provide extreme radiation hardness and a high granularity, within the tight constraints imposed by the existing detectors and their services. An all-silicon high-granularity tracking detector is proposed. An international R&D collaboration is working on the strip layers for this new tracker. A number of large area prototype planar detectors produced on p-type wafers have been designed and fabricated for use at HL-LHC. These prototype detectors and miniature test detectors have been irradiated to a set of fluences matched to HL-LHC expectatio...

  9. Oxidation of phenol and chlorophenols on platinized titanium anodes in an acidic medium

    Science.gov (United States)

    Mokbel, Saleh Mohammed; Kolosov, E. N.; Mikhalenko, I. I.

    2016-06-01

    A comparative study of oxidation of phenol, 3-chlorophenol, 4-chlorophenol, and 2,4-dichlorophenol on Pt/Ti and Ce,Pt/Ti electrocatalysts is performed via cyclic voltammetry. It is shown that the surface morphology and roughness of the anode do not change after modification with cerium. The formal kinetic orders of electrooxidation of all compounds are found to be less than one. It is shown that the β temperature coefficients of the rate of oxidation of chlorophenols grow by 10 to 50% when the Ce,Pt/Ti anode is used at a substrate concentration of 1 mM. A tenfold increase in concentration reduces the effect of cerium additive, except for 3-chlorophenol: the latter exhibits a 250% increase in the β value, compared to the Pt/Ti anode.

  10. Strip casting of stainless steels

    OpenAIRE

    Raabe, D.

    1997-01-01

    FLAT PRODUCTS OF STAINLESS STEELS ARE CONVENTIONALLY MANUFACTURED BY CONTINUOUS CASTING, HOT ROLLING, HOT BAND ANNEALING, PICKLING, COLD ROLLING AND RECRYSTALLISATION. IN THE LAST YEARS STRIP CASTING HAS INCREASINGLY ATTRACTED ATTENTION. IT OFFERS THREE IMPROVEMENTS IN COMPARISON TO THE CONVENTIONAL METHOD.1.) IT ALLOWS TO CAST STEEL SHEETS WITH THE SAME THICKNESS AND WIDTH AS THOSE PRODUCED BY HOT ROLLING. THIS MEANS THAT THE HOT ROLLING PROCESSIS BYPASSED. 2.) THE STRIP CAST STEEL REVEALS A...

  11. A new multi-strip ionization chamber used as online beam monitor for heavy ion therapy

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhiguo [Institute of Modern Physics, Chinese Academy of Sciences, 509 Nanchang Rd., Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Mao, Ruishi [Institute of Modern Physics, Chinese Academy of Sciences, 509 Nanchang Rd., Lanzhou 730000 (China); Duan, Limin, E-mail: lmduan@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Sciences, 509 Nanchang Rd., Lanzhou 730000 (China); She, Qianshun; Hu, Zhengguo; Li, He; Lu, Ziwei; Zhao, Qiecheng; Yang, Herun; Su, Hong; Lu, Chengui; Hu, Rongjiang; Zhang, Junwei [Institute of Modern Physics, Chinese Academy of Sciences, 509 Nanchang Rd., Lanzhou 730000 (China)

    2013-11-21

    A multi-strip ionization chamber has been built for precise and fast monitoring of the carbon beam spatial distribution at Heavy Ion Researched Facility of Lanzhou Cooling Storing Ring (HIRFL-CSR). All the detector's anode, cathode and sealed windows are made by 2μm aluminized Mylar film in order to minimize the beam lateral deflection. The sensitive area of the detector is (100×100)mm{sup 2}, with the anode segmented in 100 strips, and specialized front-end electronics has been developed for simplifying the data acquisition and quick feedback of the relevant parameters to beam control system. It can complete one single beam profile in 200μs.

  12. An investigation on formation and electrochemical capacitance of anodized titania nanotubes

    International Nuclear Information System (INIS)

    The mechanism of titania nanotubes formation and growth during anodization of titanium in NH4F/ethylene glycol electrolyte at 45 V applied voltage was investigated using field emission scanning electron microscopy (FESEM). The initial stage of the anodization occurs with the formation of a compact oxide layer with nanoscale pits. With the increase of anodization time, the pits transform to larger and deeper pores due to the integration of the smaller and larger pores, finally creating self-ordered titania nanotubes. The porous structure increases electrochemical capacitance from 18.3 μF cm−2 for 10 s anodization time to 49.9 μF cm−2 for 1800 s anodization time. The cyclic voltammetry (CV) transforms from a near symmetry rectangular shape to x-axis symmetry with higher current density as the anodization time increases due to increased specific surface area of the nanotubular structure. The larger CV size at more cathodic regions is characteristics of the n-type behaviour of titania materials, as also shown in the Mott–Schottky analysis.

  13. Anode Biofilms of Geoalkalibacter ferrihydriticus Exhibit Electrochemical Signatures of Multiple Electron Transport Pathways.

    Science.gov (United States)

    Yoho, Rachel A; Popat, Sudeep C; Rago, Laura; Guisasola, Albert; Torres, César I

    2015-11-17

    Thriving under alkaliphilic conditions, Geoalkalibacter ferrihydriticus (Glk. ferrihydriticus) provides new applications in treating alkaline waste streams as well as a possible new model organism for microbial electrochemistry. We investigated the electrochemical response of biofilms of the alkaliphilic anode-respiring bacterium (ARB) Glk. ferrihydriticus voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry. We observed there to be at least four dominant electron transfer pathways, with their contribution to the overall current produced dependent on the set anode potential. These pathways appear to be manifested at midpoint potentials of approximately -0.14 V, -0.2 V, -0.24 V, and -0.27 V vs standard hydrogen electrode. The individual contributions of the pathways change upon equilibration from a set anode potential to another anode potential. Additionally, the contribution of each pathway to the overall current produced is reversible when the anode potential is changed back to the original set potential. The pathways involved in anode respiration in Glk. ferrihydriticus biofilms follow a similar, but more complicated, pattern as compared to those in the model ARB, Geobacter sulfurreducens. This greater diversity of electron transport pathways in Glk. ferrihydriticus could be related to its wider metabolic capability (e.g., higher pH and larger set of possible substrates, among others). PMID:26488071

  14. MAPMT H7546B anode current response study for ILC SiD muon system prototype

    International Nuclear Information System (INIS)

    The proposed Silicon Detector (SiD) concept for the ILC has barrel and end cap muon systems. An SiD scintillator based muon system prototype has 256 strips and was constructed from extruded strips, WLS fibers, clear fibers, and multianode photo multiplier tubes (MAPMT) Hamamatsu H7546B. Six MAPMTs were used. As a first step to understand strip output, the response of every anode to a given brightness of light and applied voltage must be measured. For the test, a custom made light source was used. Each MAPMT output was measured independently. The anode currents were measured at constant (green) input light brightness and the same photocathode to anode voltage (800V). The anode currents have a wide spread; for all tubes the maximum value is 5.23 times larger than the minimum value. The MAPMT cross talk was measured for one of the central inputs. The maximum cross talk value is about 4.9%. The average cross talk for the nearest four neighboring channels is 3.9%, for the farthest four is 1%. To assure the reproducibility and repeatability of the measurements, the double reference method was used

  15. Study of quinones reactions with wine nucleophiles by cyclic voltammetry.

    Science.gov (United States)

    Oliveira, Carla M; Barros, António S; Ferreira, António C S; Silva, Artur M S

    2016-11-15

    Quinones are electrophilic species which can react with various nucleophiles, like wine antioxidants, such as sulfur dioxide or ascorbic acid, thiols, amino acids, and numerous polyphenols. These reactions are very important in wine aging because they mediate oxygen reactions during both production and bottle aging phases. In this work, the major challenge was to determine the interaction between ortho-quinones and wine nucleophiles (amino acids, thiols, and the antioxidants SO2 and ascorbic acid), by cyclic voltammetry. Wine-model solutions with gallic acid, caffeic acid, or (+)-catechin and nucleophilic compounds were used. To understand the effect of nucleophilic addition in wine, a white wine with the same added nucleophiles was also analysed. Cyclic voltammograms were taken with glassy carbon electrode or screen-printed carbon electrodes, respectively, for wine-model and white wines solutions, in the absence and in the presence of nucleophiles. A nucleophilic order profile related to the cathodic current intensity decrease was observed. PMID:27283600

  16. The Cathode Strip Chamber Data Acquisition System for CMS

    CERN Document Server

    Bylsma, B G; Gilmore, J R; Gu, J H; Ling, T Y

    2007-01-01

    The Cathode Strip Chamber (CSC) [1] Data Acquisition (DAQ) system for the CMS [2] experiment at the LHC [3] will be described. The CSC system is large, consisting of 218K cathode channels and 183K anode channels. This leads to a substantial data rate of ~1.5GByte/s at LHC design luminosity (1034cm-2s-1) and the CMS first level trigger (L1A) rate of 100KHz. The DAQ system consists of three parts. The first part is on-chamber Cathode Front End Boards (CFEB)[4], which amplify, shape, store, and digitise chamber cathode signals, and Anode Front End Boards (AFEB)[5], which amplify, shape and discriminate chamber anode signals. The second part is the Peripheral Crate Data Acquisition Motherboards (DAQMB), which control the onchamber electronics and the readout of the chamber. The third part is the off-detector DAQ interface boards, which perform real time error checking, electronics reset requests and data concentration. It passes the resulting data to a CSC local DAQ farm, as well as CMS main DAQ [6]. All electron...

  17. Carbon supported Cu-Pd nanoparticles as anode catalyst for direct borohydride-hydrogen peroxide fuel cells

    International Nuclear Information System (INIS)

    Carbon supported Cu-Pd bimetallic nanoparticles were prepared by a successive reduction method in aqueous solution and used as anode electrocatalyst for direct borohydride-hydrogen peroxide fuel cell (DBHFC). The physical and electrochemical properties of the as-prepared electrocatalysts are investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), cyclic voltammetry (CV), chronopotentiometry (CP), linear sweep voltammetry (LSV) and fuel cell test. The results show that the size of the crystallite is around 12.5 nm, the Cu1Pd1/C catalyst presents the highest catalytic activity among all the resultant catalysts, and the DBHFC using Cu1Pd1/C as anode catalyst and Pt mesh (1 cm × 1 cm) as cathode electrode obtains the maximum power density as high as 39.8 mW cm-2 at a discharge current density of 80.1 mA cm-2 at 20 °C

  18. Photoelectrochemical cell with nondissolving anode

    Science.gov (United States)

    Ellis, A. B.; Kaiser, S. W.; Wrighton, M. S.

    1980-01-01

    Improved electrolytic cells have efficiencies comparable to those of best silicon solar cells but are potentially less expensive to manufacture. Cells consist of light-sensitive n-type semiconductor anode and metallic cathode immersed in electrolytic solution. Reversible redox cells produce no chemical change in electrolyte and stabilize anode against dissolving. Cell can produce more than 500 mW of power per square centimeter of anode area at output voltage of 0.4 V.

  19. Synthesis and Characterization of Silicon Nanoparticles Inserted into Graphene Sheets as High Performance Anode Material for Lithium Ion Batteries

    OpenAIRE

    Yong Chen; Xuejun Zhang; Yanhong Tian; Xi Zhao

    2014-01-01

    Silicon nanoparticles have been successfully inserted into graphene sheets via a novel method combining freeze-drying and thermal reduction. The structure, electrochemical performance, and cycling stability of this anode material were characterized by SEM, X-ray diffraction (XRD), charge/discharge cycling, and cyclic voltammetry (CV). CV showed that the Si/graphene nanocomposite exhibits remarkably enhanced cycling performance and rate performance compared with bare Si nanoparticles for lithi...

  20. Performance and spark damage studies of microgap gas chambers fabricated with selected anode metals

    International Nuclear Information System (INIS)

    Microgap gas chambers (MGCs) fabricated with selected anode metals, including aluminum, gold, chromium, nickel and titanium/tungsten (10/90) have been used in order to study the effect of these different metals upon gas gain, aging, and spark damage. Gas mixtures used for systematic tests of performance are argon/ethane (50/50) and argon/dimethyl ether (50/50). The effects of spark damage by discharge are found to be very sensitive to the metal used for anode strips, and a systematic study of spark damage effects has been made to compare their relative sensitivity to failure, over a range of electrical discharge energies. (orig.)

  1. Cathodic adsorptive stripping voltammetric determination of uranium with potassium hydrogen phthalate.

    Science.gov (United States)

    Farghaly, O A; Ghandour, M A

    1999-06-01

    The adsorption properties of dioxouranium (II)-Phathalate complexes onto hanging mercury drop electrode are exploited in developing a highly sensitive and selective stripping voltammetric procedure for the determination of uranium (VI). The reduction current of adsorbed complex ions of U(VI) was measured by both linear sweep (LSCSV) and differential pulse cathodic stripping voltammetry (DPCSV), preceded by a period of preconcentration onto the electrode surface. As low as 2x10(-9) mol dm(-3) (0.5 mug/l) and 2x10(-8) mol dm(-3) (4.8 mug/l) with accumulation time 240 and 120 s using DPCSV and LSCSV, respectively, have been determined successfully. The relative standard deviation of 2.2% at the 5 ppm level was obtained. The interferences of some metal ions and anions were studied. The application of this method was tested in the determination of uranium in superphosphate fertilizer. PMID:18967571

  2. Intrabeam stripping in H- Linacs

    CERN Document Server

    Lebedev, V; Ostigy, J -F; Alexandrov, A; Shishlo, A

    2012-01-01

    A beam loss in the superconducting part of the SNS linac has been observed during its commissioning and operation. Although the loss does not prevent the SNS high power operation, it results in an almost uniform irradiation of linac components and increased radiation levels in the tunnel. Multi-particle tracking could neither account for the magnitude of the observed loss nor its dependence on machine parameters. It was recently found that the loss is consistent with the intrabeam particle collisions resulting in stripping of H- ions. The paper describes experimental observations and corresponding analytical estimates of the intrabeam stripping.

  3. Screened Anode N2 Laser

    OpenAIRE

    Sabry, M. Montaser Foad

    1985-01-01

    An experimental study of the effect of screening the discharge channel on the output energy is presented. It has been found that a screened anode nitrogen laser generates higher output energy than that of a screened cathode, and also higher than that when both cathode and anode are unshielded at higher pressures.

  4. Mesoporous Silicon-Based Anodes

    Science.gov (United States)

    Peramunage, Dharmasena

    2015-01-01

    For high-capacity, high-performance lithium-ion batteries. A new high-capacity anode composite based on mesoporous silicon is being developed. With a structure that resembles a pseudo one-dimensional phase, the active anode material will accommodate significant volume changes expected upon alloying and dealloying with lithium (Li).

  5. Cyclic voltammetry and RBS study of paint components

    Energy Technology Data Exchange (ETDEWEB)

    Bowman, Lynn [Center for Irradiation of Materials, Alabama A and M University, 4900 Meridian Street, P.O. Box 1447, Normal, AL 35762 (United States); Spencer, Dirk [Plant and Soil Science Department, Alabama A and M University, Normal, AL 35762-1447 (United States); Muntele, Claudiu [Center for Irradiation of Materials, Alabama A and M University, 4900 Meridian Street, P.O. Box 1447, Normal, AL 35762 (United States)]. E-mail: claudiu@cim.aamu.edu; Muntele, Iulia [Center for Irradiation of Materials, Alabama A and M University, 4900 Meridian Street, P.O. Box 1447, Normal, AL 35762 (United States); Ila, D. [Center for Irradiation of Materials, Alabama A and M University, 4900 Meridian Street, P.O. Box 1447, Normal, AL 35762 (United States)

    2007-08-15

    Heavy metals and metalloid ions are found in environmental matrices. The most toxic are lead, cadmium and mercury. These three heavy metals have no biological function and are toxic at all concentrations. Lead is one of the most insidious heavy metals and is introduced into the environment by many different means. It persists in both urban and rural settings, being found in paint chips, pottery, crystal and pharmaceutical and nutritional products. The analysis of heavy elements such as lead in soil is of particular importance [W.T. Sturges, R.M. Harrison, Sci. Total Environ. 44 (3) (1985) 225; M.L. Lepow, L. Bruckman, M. Gillette, S. Markowitz, R. Robino, J. Kapish, Environ. Res. 10 (3) (1975) 415; A.E. Daniels, J.R. Kominsky, P.J. Clark, J. Hazard. Mater. B 87 (2001) 117; G. Hutter, D. Moshman, J. Hazard. Mater. 40 (1995) 1]. In preparing the methods for lead detection in paint, we have used Rutherford backscattering spectrometry (RBS) in order to study the type and amount of heavy metal content in paint samples collected at various sites in the historic campus at A and M University (AAMU). We will show the results of our study with emphasis on comparison of what we learned about presence of lead in paints using our ion beam methods compared with the analysis of lead in paints using cyclic voltammetry.

  6. A brief review: Ultrafast electron diffractive voltammetry: General formalism and applications

    CERN Document Server

    Chang, Kiseok; Tao, Zhensheng; Han, Tzong-Ru T; Ruan, Chong-Yu

    2013-01-01

    We present a general formalism of ultrafast diffractive voltammetry approach as a contact-free tool to investigate the ultrafast surface charge dynamics in nanostructured interfaces. As case studies, the photoinduced surface charging processes in oxidized silicon surface and the hot electron dynamics in nanoparticle-decorated interface are examined based on the diffractive voltammetry framework. We identify that the charge redistribution processes appear on the surface, sub-surface, and vacuum levels when driven by intense femtosecond laser pulses. To elucidate the voltammetry contribution from different sources, we perform controlled experiments using shadow imaging techniques and N-particle simulations to aid the investigation of the photovoltage dynamics in the presence of pho- toemission. We show that voltammetry contribution associated with photoemission has a long decay tail and plays a more visible role in the nanosecond timescale, whereas the ultrafast voltammetry are dominated by local charge transfe...

  7. Electrochromic Properties of Iridium Oxide Films Prepared by Pulsed Anodic Electrodeposition

    Science.gov (United States)

    Jung, Youngwoo; Tak, Yongsug; Lee, Jaeyoung

    2002-12-01

    Thin films of iridium oxide to be used as an electrochromic material were prepared by pulsed anodic current electrodeposition onto indium tin oxide (ITO) coated glass substrates. Before the pulsed electrodeposition, iridium oxide films formed by cyclic voltammetry (CV) played an important role in good adhesion as a seed layer. Iridium oxide films with light-blue color (100 mC/cm2) were deposited when anodic current of 0.07 mA/cm2 for 0.5 sec was superimposed on off-time of 0.5 sec (i.e., zero current) in each cycle. During CV experiment in phosphate buffered saline solution, electrodeposited iridium oxide films exhibited anodic electrochromism of blue and black color at two oxidation potentials (i.e., the ejection of H+) of +0.5 V and +0.9 V (vs. SCE), respectively, while on the cathodic scan, black thin film became colorless due to the injection of H+. When +0.9 V and -0.7 V were applied for coloring and bleaching observation in different pulse voltammetry, minimal times needed for each process are 9 sec and 5 sec, respectively.

  8. Modified strip saturation model for a cracked piezoelectric strip

    Directory of Open Access Journals (Sweden)

    R.R. Bhargava

    2008-03-01

    Full Text Available Purpose: The investigations aim to propose a model for arresting an electrical opening of a crack which weakensa narrow, poled and infinite piezoelectric strip. The edges of the strip are subjected to uniform, constant anti-planestresses and in-plane electrical displacements.Design/methodology/approach: The loads applied at the edges of the strip open the crack in a self-similar fashion.Consequently at each tip of the crack a saturation zone protrudes. To stop the crack from further opening the rims ofdeveloped saturation zones are subjected to normal, cohesive linearly varying saturation limit electric displacement. Theedges of the strip are subjected to anti-plane deformation and in-plane electrical displacement. Fourier integral transformmethod employed reduces the problem to the solution of a Fredholm integral equation of second kind.Findings: The electrical displacement, stress intensity factor, the saturation zone length, crack opening displacementand crack growth rate have been calculated. The results obtained presented graphically, analysed and concluded.Research limitations/implications: The ceramic used for strip is being assumed to be electrically morebrittle. The investigations are carried at this level in the present paper. Also the small scale electrical yielding isconsidered. Consequently the developed saturation zone is proposed to lie in a line segment ahead of crack.Practical implications: Piezoelectric ceramics being widely used as transducers. Their wide utility hasprompted to study many attires of such ceramic and one such attire is fracture mechanics of these ceramics.Originality/value: The paper gives an assessment of the electrical load necessary to arrest the electrical crack opening.The investigations are useful to smart material design technology where sensors and actuators are manufactured.

  9. Anodic concentration loss and impedance characteristics in rotating disk electrode microbial fuel cells.

    Science.gov (United States)

    Shen, Liye; Ma, Jingxing; Song, Pengfei; Lu, Zhihao; Yin, Yao; Liu, Yongdi; Cai, Lankun; Zhang, Lehua

    2016-10-01

    A rotating disk electrode (RDE) was used to investigate the concentration loss and impedance characteristics of anodic biofilms in microbial fuel cells (MFCs). Amperometric time-current analysis revealed that at the rotation rate of 480 rpm, a maximum current density of 168 µA cm(-2) can be achieved, which was 22.2 % higher than when there was no rotation. Linear sweep voltammetry and electrochemical impedance spectroscopy tests showed that when the anodic potential was set to -300 mV vs. Ag/AgCl reference, the power densities could increase by 59.0  %, reaching 1385 mW m(-2), the anodic resistance could reduce by 19  %, and the anodic capacitance could increase by 36 %. These results concur with a more than 85 % decrease of the diffusion layer thickness. Data indicated that concentration loss, diffusion layer thickness, and the mixing velocity play important roles in anodic resistance reduction and power output of MFCs. These findings could be helpful to the design of future industrial-scale MFCs with mixed bacteria biofilms.

  10. Study on the Rare Earth Sealing Procedure of the Porous Film of Anodized 2024 Aluminum Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The rare earth sealing procedure of the porous film of anodized aluminum alloy 2024 was studied with the fieldemission scanning electron microscope (SEM) and X-ray energy dispersive spectroscopy (EDS). The results show thatRE solution can form cerium oxide/hydroxides precipitation in the pores of the anodized coating at the beginning ofsealing. At the same time, the spherical deposits formed on the surface of the anodized coating created a barrierto the precipitation of RE solution in the pores. When the pore-structured anodizing film is covered all with thespherical deposits, RE conversion coating will form on the surface of the anodized coating. The reaction of thecoating formation was investigated by employing cyclic voltammetry. The results indicate that accelerator H2O2 actsas the source of O2 by carrying chemical reaction in course of coating formation. In the mean time, it maybe carrieselectrochemical reaction to generate alkaline condition to accelerate the coating formation. The porous structure ofthe film is beneficial to the precipitation of the cerium hydroxides film.

  11. Anodic concentration loss and impedance characteristics in rotating disk electrode microbial fuel cells.

    Science.gov (United States)

    Shen, Liye; Ma, Jingxing; Song, Pengfei; Lu, Zhihao; Yin, Yao; Liu, Yongdi; Cai, Lankun; Zhang, Lehua

    2016-10-01

    A rotating disk electrode (RDE) was used to investigate the concentration loss and impedance characteristics of anodic biofilms in microbial fuel cells (MFCs). Amperometric time-current analysis revealed that at the rotation rate of 480 rpm, a maximum current density of 168 µA cm(-2) can be achieved, which was 22.2 % higher than when there was no rotation. Linear sweep voltammetry and electrochemical impedance spectroscopy tests showed that when the anodic potential was set to -300 mV vs. Ag/AgCl reference, the power densities could increase by 59.0  %, reaching 1385 mW m(-2), the anodic resistance could reduce by 19  %, and the anodic capacitance could increase by 36 %. These results concur with a more than 85 % decrease of the diffusion layer thickness. Data indicated that concentration loss, diffusion layer thickness, and the mixing velocity play important roles in anodic resistance reduction and power output of MFCs. These findings could be helpful to the design of future industrial-scale MFCs with mixed bacteria biofilms. PMID:27282165

  12. Electrodynamics on the Moebius Strip

    OpenAIRE

    Pauschenwein, Gernot,

    2004-01-01

    In this diploma work electrostatics and -dynamics of two dimensional structures are examined. Mathematica is used for visualisation and packages for Mathematica have been programmed which use subroutines written in C to improve numerical calculations. The well known Moebius Strip is used as an example structure throughout the work.

  13. Direct electrodeposition of gold nanotube arrays of rough and porous wall by cyclic voltammetry and its applications of simultaneous determination of ascorbic acid and uric acid

    Energy Technology Data Exchange (ETDEWEB)

    Yang Guangming, E-mail: yangguangmingbs@126.com [Department of Resources and Environment, Baoshan University, Baoshan 678000 (China); Li Ling [Department of Resources and Environment, Baoshan University, Baoshan 678000 (China); Jiang Jinhe; Yang Yunhui [College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092 (China)

    2012-08-01

    Gold nanotube arrays of rough and porous wall has been synthesized by direct electrodeposition with cyclic voltammetry utilizing anodic aluminum oxide template (AAO) and polycarbonate membrane (PC) during short time (only 3 min and 2 min, respectively). The mechanism of the direct electrodeposition of gold nanotube arrays by cyclic voltammetry (CV) has been discussed. The morphological characterizations of the gold nanotube arrays have been investigated by scanning electron microscopy (SEM). A simultaneous determination of ascorbic acid (AA) and uric acid (UA) by differential pulse voltammetry (DPV) was constructed by attaching gold nanotube arrays (using AAO) onto the surface of a glassy carbon electrode (GCE). The electrochemical behavior of AA and UA at this modified electrode has been studied by CV and differential pulse voltammetry (DPV). The sensor offers an excellent response for AA and UA and the linear response range for AA and UA were 1.02 Multiplication-Sign 10{sup -7}-5.23 Multiplication-Sign 10{sup -4} mol L{sup -1} and 1.43 Multiplication-Sign 10{sup -7}-4.64 Multiplication-Sign 10{sup -4} mol L{sup -1}, the detection limits were 1.12 Multiplication-Sign 10{sup -8} mol L{sup -1} and 2.24 Multiplication-Sign 10{sup -8} mol L{sup -1}, respectively. This sensor shows good regeneration, stability and selectivity and has been used for the determination of AA and UA in real human urine and serum samples with satisfied results. - Graphical abstract: The schematic diagram of formation of Au nanotube arrays (a) and the stepwise procedure of the sensor (b). Highlights: Black-Right-Pointing-Pointer Gold nanotubes array has been synthesized by cyclic voltammetry. Black-Right-Pointing-Pointer The mechanism of deposition of gold nanotube has been discussed. Black-Right-Pointing-Pointer A determination of ascorbic acid and uric acid was constructed by gold array. Black-Right-Pointing-Pointer A satisfied determination of samples can be obtained by this sensor.

  14. Using Comic Strips in Language Classes

    Science.gov (United States)

    Csabay, Noémi

    2006-01-01

    The author believes that using comic strips in language-learning classes has three main benefits. First, comic strips motivate younger learners. Second, they provide a context and logically connected sentences to help language learning. Third, their visual information is helpful for comprehension. The author argues that comic strips can be used in…

  15. Note: Simulation and test of a strip source electron gun

    Energy Technology Data Exchange (ETDEWEB)

    Iqbal, Munawar, E-mail: muniqbal.chep@pu.edu.pk [Centre for High Energy Physics, University of the Punjab, Lahore 45590 (Pakistan); Institute of High Energy Physics, Chinese Acedemy of Sciences, Beijing 100049 (China); Islam, G. U.; Misbah, I.; Iqbal, O. [Centre for High Energy Physics, University of the Punjab, Lahore 45590 (Pakistan); Zhou, Z. [Institute of High Energy Physics, Chinese Acedemy of Sciences, Beijing 100049 (China)

    2014-06-15

    We present simulation and test of an indirectly heated strip source electron beam gun assembly using Stanford Linear Accelerator Center (SLAC) electron beam trajectory program. The beam is now sharply focused with 3.04 mm diameter in the post anode region at 15.9 mm. The measured emission current and emission density were 1.12 A and 1.15 A/cm{sup 2}, respectively, that corresponds to power density of 11.5 kW/cm{sup 2}, at 10 kV acceleration potential. The simulated results were compared with then and now experiments and found in agreement. The gun is without any biasing, electrostatic and magnetic fields; hence simple and inexpensive. Moreover, it is now more powerful and is useful for accelerators technology due to high emission and low emittance parameters.

  16. Note: Simulation and test of a strip source electron gun

    International Nuclear Information System (INIS)

    We present simulation and test of an indirectly heated strip source electron beam gun assembly using Stanford Linear Accelerator Center (SLAC) electron beam trajectory program. The beam is now sharply focused with 3.04 mm diameter in the post anode region at 15.9 mm. The measured emission current and emission density were 1.12 A and 1.15 A/cm2, respectively, that corresponds to power density of 11.5 kW/cm2, at 10 kV acceleration potential. The simulated results were compared with then and now experiments and found in agreement. The gun is without any biasing, electrostatic and magnetic fields; hence simple and inexpensive. Moreover, it is now more powerful and is useful for accelerators technology due to high emission and low emittance parameters

  17. Note: Simulation and test of a strip source electron gun

    Science.gov (United States)

    Iqbal, Munawar; Islam, G. U.; Misbah, I.; Iqbal, O.; Zhou, Z.

    2014-06-01

    We present simulation and test of an indirectly heated strip source electron beam gun assembly using Stanford Linear Accelerator Center (SLAC) electron beam trajectory program. The beam is now sharply focused with 3.04 mm diameter in the post anode region at 15.9 mm. The measured emission current and emission density were 1.12 A and 1.15 A/cm2, respectively, that corresponds to power density of 11.5 kW/cm2, at 10 kV acceleration potential. The simulated results were compared with then and now experiments and found in agreement. The gun is without any biasing, electrostatic and magnetic fields; hence simple and inexpensive. Moreover, it is now more powerful and is useful for accelerators technology due to high emission and low emittance parameters.

  18. Suitability of the voltammetry of immobilized microparticles to detect and discriminate lead compounds in microsamples of ancient black cosmetics

    International Nuclear Information System (INIS)

    Lead compounds, in the form of galena, have been used as eye cosmetics since ancient times and they still appear in traditional products. The presence of some black pigments in several archaeological glass objects gave us the opportunity to study the nature of these products, in order to evaluate the results of an electrochemical method to characterise lead compounds when only heterogeneous microsamples are available and the material requires to be as less manipulated as possible. The present paper describes the data obtained with an electroanalytical methodology (Voltammetry of immobilised microparticles, VMP), and a complementary Scanning Electron Microscopy study, to detect these lead compounds. A simple and fast characterisation method is discussed in order to be able to monitor the presence of lead compounds without previous sample preparation, directly in the solid micro-sample, and using an affordable instrumentation. PbS could be identified and distinguished from other lead compounds in cosmetics by Differential Pulse VMP in 1 M NaCl medium by a set of three peaks (−0.63 V, −0.44 V, +0.45 V) in the anodic voltammogram and two peaks around −0.65 V and +0.45 V in the cathodic scan. The results showed the suitability of the electroanalytical method, offering valuable information about the chemical and mineral composition of the samples using a minimum amount of material, and illustrating the advantages in terms of time consuming, cost and accessibility of the laboratory facilities

  19. Recovery of valuable metals from anode material of hydrogen-nickel battery

    Institute of Scientific and Technical Information of China (English)

    WU Fang; XU Sheng-ming; LI Lin-yan; CHEN Song-zhe; XU Gang; XU Jing-ming

    2009-01-01

    Simultaneous recovery of rare earth, nickel and cobalt resources from the anode material of hydrogen-nickel battery was performed through a hydrometallurgical process. Most of rare earth elements are separated from nickel and cobalt in the form of sulfates when the anode material is firstly leached with sulfuric acid. Then, the precipitated rare earth sulfates are dissolved with sodium hydroxide to form rare earth hydroxides. The rare earth element, zinc and manganese ions in the lixivium are also separated from nickel and cobalt by using PC-88A extractant system, and the organic phase loaded rare earth is stripped with hydrochloric acid. By neutralizing the stripping solution with rare earth hydroxide, the rare earth chloride is obtained. Under the suitable leaching conditions of sulfuric acid 3 mol/L, leaching time 4 h and temperature 95 ℃, 94.5% of rare earth in the anode material is transformed into the sulfate precipitates, and the leaching ratios of nickel and cobalt can approach 99.5%. When the pH value of the extractive system is controlled in the range of 3.0-3.5, the rare earth elements in the lixivium can be extracted completely into the organic phase, and the stripping recovery of the rare earth can reach 98% in the extraction stage. The total recoveries of rare earth, nickel and cobalt are 98.9%, 98.4% and 98.5%, respectively.

  20. Multi-anode ionization chamber

    Energy Technology Data Exchange (ETDEWEB)

    Bolotnikov, Aleksey E. (South Setauket, NY); Smith, Graham (Port Jefferson, NY); Mahler, George J. (Rocky Point, NY); Vanier, Peter E. (Setauket, NY)

    2010-12-28

    The present invention includes a high-energy detector having a cathode chamber, a support member, and anode segments. The cathode chamber extends along a longitudinal axis. The support member is fixed within the cathode chamber and extends from the first end of the cathode chamber to the second end of the cathode chamber. The anode segments are supported by the support member and are spaced along the longitudinal surface of the support member. The anode segments are configured to generate at least a first electrical signal in response to electrons impinging thereon.

  1. Toward an in situ phosphate sensor in seawater using Square Wave Voltammetry.

    Science.gov (United States)

    Barus, C; Romanytsia, I; Striebig, N; Garçon, V

    2016-11-01

    A Square Wave Voltammetry electrochemical method is proposed to measure phosphate in seawater as pulse techniques offer a higher sensitivity as compared to classical cyclic voltammetry. Chronoamperometry cannot be either adapted for an in situ sensor since this method requires to have controlled convection which will be impossible in a miniaturised sensor. Tests and validation of Square Wave Voltammetry parameters have been performed using an open cell and for the first time with a small volume (position of the molybdenum electrode for the complexation step and moving the detection into another electrochemical cell allow to decrease the reaction time down to 5min.

  2. Fast variation method for elastic strip calculation.

    Science.gov (United States)

    Biryukov, Sergey V

    2002-05-01

    A new, fast, variation method (FVM) for determining an elastic strip response to stresses arbitrarily distributed on the flat side of the strip is proposed. The remaining surface of the strip may have an arbitrary form, and it is free of stresses. The FVM, as well as the well-known finite element method (FEM), starts with the variational principle. However, it does not use the meshing of the strip. A comparison of FVM results with the exact analytical solution in the special case of shear stresses and a rectangular strip demonstrates an excellent agreement.

  3. Triangular buckling patterns of twisted inextensible strips

    CERN Document Server

    Korte, A P; van der Heijden, G H M

    2010-01-01

    When twisting a strip of paper or acetate under high longitudinal tension, one observes, at some critical load, a buckling of the strip into a regular triangular pattern. Very similar triangular facets have recently been observed in solutions to a new set of geometrically-exact equations describing the equilibrium shape of thin inextensible elastic strips. Here we formulate a modified boundary-value problem for these equations and construct post-buckling solutions in good agreement with the observed pattern in twisted strips. We also study the force-extension and moment-twist behaviour of these strips by varying the mode number n of triangular facets.

  4. Electrocatalytic Oxidation of Hydroxylamine at a Quinizarine Modified Glassy Carbon Electrode: Application to Differential Pulse Voltammetry Detection of Hydroxylamine

    OpenAIRE

    MAZLOUMARDAKANI, Mohammad; KARAMI, Payam EBRAHIMI

    2008-01-01

    The electrocatalytic behavior of hydroxylamine was studied on a glassy carbon electrode modified by electrodeposition of quinizarine, using cyclic voltammetry, chronoamperometry, and rotating disk voltammetry as diagnostic techniques. Cyclic voltammetry showed that the catalytic current of the system depends on the concentration of hydroxylamine. The magnitude of the peak current for quinizarine increased sharply in the presence of hydroxylamine and proportional to hydroxylamine conc...

  5. Synthesis of Au/C and Au/Pani for anode electrodes in glucose microfluidic fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Guerra-Balcazar, M.; Morales-Acosta, D.; Castaneda, F.; Arriaga, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, 76703 Queretaro (Mexico); Ledesma-Garcia, J. [Division de Investigacion y Posgrado, Facultad de Ingenieria, Universidad Autonoma de Queretaro, 76010 Queretaro (Mexico)

    2010-06-15

    Gold nanoparticles have been prepared by two methods: chemical (ex-situ, Au/C) by two phase protocol, and electrochemical (in-situ, Au/Pani) by electroreduction of gold ions on a polyaniline film and compared as anode catalysts in a glucose microfluidic fuel cell. In this paper the structural characteristics and electrocatalytic properties were investigated by X-ray diffraction and electrochemical measurements. The catalytic behavior of both anodes was tested in a microfluidic fuel cell with a reference electrode incorporated, by means of linear sweep voltammetry (LSV), showing a cathodic shift in the glucose oxidation peak for Au/Pani. Results show a higher power density (0.5 mW cm{sup -} {sup 2}) for Au/C anode compared with an already reported value, where a glucose microfluidic fuel cell was used in similar conditions. (author)

  6. Adsorptive and stripping behavior of methylene blue at gold electrodes in the presence of cationic gemini surfactants

    Energy Technology Data Exchange (ETDEWEB)

    Li, Jiangwen; Zhao, Faqiong; Zhao, Jia; Zeng, Baizhao [Wuhan University, Wuhan (China). Department of Chemistry

    2005-10-10

    The adsorptive and stripping behavior of methylene blue (i.e. methylene blue chloride, MB) at a gold electrode has been studied with voltammetry, alternating current impedance spectra (ACIS) and quartz crystal microbalance (QCM). MB exhibits a pair of cyclic voltammetry peaks at about -0.3 V (versus SCE) in 0.05 M pH 6.9 phosphate buffer solutions. In the presence of cationic gemini surfactants such as C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 4}H{sub 8}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 4}-C{sub 16}), C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 4}H{sub 7}OH-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 4}OH-C{sub 16}), C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-CH{sub 2}-C{sub 6}H{sub 4}-CH{sub 2}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-ph-C{sub 16}) and C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 12}H{sub 24}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 12}-C{sub 16}), the anodic peak grows rapidly and moves in positive direction, but the cathodic peak gradually decreases, due to the association adsorption and electrostatic interaction of the geminis with MB and its reduced product (i.e. leuko methylene blue, LMB). With the aid of geminis the adsorption amount of MB increases under open-circuit, but the impedance of the mixed adsorption film to Fe(CN){sub 6}{sup 3-/4-} almost keeps unchanged, compared with either bare gold electrodes or MB film, while the adsorption film of geminis exhibits greater impedance. This probably is due to the electron medium action of MB in the film. Gemini surfactants with same alkyl-chain (i.e. -(CH{sub 2}){sub 15}CH{sub 3}) but different molecular structure, exhibit different influence. The enhancing action of geminis studied follows such order as: C{sub 16}-ph-C{sub 16} > C{sub 16}-C{sub 4}-C{sub 16} > C{sub 16}-C{sub 4}OH-C{sub 16} > C{sub 16}-C{sub 12}-C{sub 16}. The change of peak potential was ascribed to the interaction between MB and surfactants

  7. Adsorptive and stripping behavior of methylene blue at gold electrodes in the presence of cationic gemini surfactants

    Energy Technology Data Exchange (ETDEWEB)

    Li Jiangwen [Department of Chemistry, Wuhan University, Wuhan 430072 (China); Zhao Faqiong [Department of Chemistry, Wuhan University, Wuhan 430072 (China); Zhao Jia [Department of Chemistry, Wuhan University, Wuhan 430072 (China); Zeng Baizhao [Department of Chemistry, Wuhan University, Wuhan 430072 (China)]. E-mail: zengbz@chem.whu.edu.cn

    2005-10-10

    The adsorptive and stripping behavior of methylene blue (i.e. methylene blue chloride, MB) at a gold electrode has been studied with voltammetry, alternating current impedance spectra (ACIS) and quartz crystal microbalance (QCM). MB exhibits a pair of cyclic voltammetry peaks at about -0.3 V (versus SCE) in 0.05 M pH 6.9 phosphate buffer solutions. In the presence of cationic gemini surfactants such as C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 4}H{sub 8}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 4}-C{sub 16}), C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 4}H{sub 7}OH-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 4}OH-C{sub 16}), C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-CH{sub 2}-C{sub 6}H{sub 4}-CH{sub 2}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-ph-C{sub 16}) and C{sub 16}H{sub 33}N(CH{sub 3}){sub 2}-C{sub 12}H{sub 24}-N(CH{sub 3}){sub 2}C{sub 16}H{sub 33}Br{sub 2} (C{sub 16}-C{sub 12}-C{sub 16}), the anodic peak grows rapidly and moves in positive direction, but the cathodic peak gradually decreases, due to the association adsorption and electrostatic interaction of the geminis with MB and its reduced product (i.e. leuko methylene blue, LMB). With the aid of geminis the adsorption amount of MB increases under open-circuit, but the impedance of the mixed adsorption film to Fe(CN){sub 6} {sup 3-/4-} almost keeps unchanged, compared with either bare gold electrodes or MB film, while the adsorption film of geminis exhibits greater impedance. This probably is due to the electron medium action of MB in the film. Gemini surfactants with same alkyl-chain (i.e. -(CH{sub 2}){sub 15}CH{sub 3}) but different molecular structure, exhibit different influence. The enhancing action of geminis studied follows such order as: C{sub 16}-ph-C{sub 16} > C{sub 16}-C{sub 4}-C{sub 16} > C{sub 16}-C{sub 4}OH-C{sub 16} > C{sub 16}-C{sub 12}-C{sub 16}. The change of peak potential was ascribed to the interaction between MB and

  8. Antenna structure with distributed strip

    Science.gov (United States)

    Rodenbeck, Christopher T.

    2008-03-18

    An antenna comprises electrical conductors arranged to form a radiating element including a folded line configuration and a distributed strip configuration, where the radiating element is in proximity to a ground conductor. The folded line and the distributed strip can be electrically interconnected and substantially coplanar. The ground conductor can be spaced from, and coplanar to, the radiating element, or can alternatively lie in a plane set at an angle to the radiating element. Embodiments of the antenna include conductor patterns formed on a printed wiring board, having a ground plane, spacedly adjacent to and coplanar with the radiating element. Other embodiments of the antenna comprise a ground plane and radiating element on opposed sides of a printed wiring board. Other embodiments of the antenna comprise conductors that can be arranged as free standing "foils". Other embodiments include antennas that are encapsulated into a package containing the antenna.

  9. Nano structural anodes for radiation detectors

    Energy Technology Data Exchange (ETDEWEB)

    Cordaro, Joseph V.; Serkiz, Steven M.; McWhorter, Christopher S.; Sexton, Lindsay T.; Retterer, Scott T.

    2015-07-07

    Anodes for proportional radiation counters and a process of making the anodes is provided. The nano-sized anodes when present within an anode array provide: significantly higher detection efficiencies due to the inherently higher electric field, are amenable to miniaturization, have low power requirements, and exhibit a small electromagnetic field signal. The nano-sized anodes with the incorporation of neutron absorbing elements (e.g., .sup.10B) allow the use of neutron detectors that do not use .sup.3He.

  10. Subnanomolar detection limit of stripping voltammetric Ca²⁺-selective electrode: effects of analyte charge and sample contamination.

    Science.gov (United States)

    Kabagambe, Benjamin; Garada, Mohammed B; Ishimatsu, Ryoichi; Amemiya, Shigeru

    2014-08-01

    Ultrasensitive ion-selective electrode measurements based on stripping voltammetry are an emerging sensor technology with low- and subnanomolar detection limits. Here, we report on stripping voltammetry of down to 0.1 nM Ca(2+) by using a thin-polymer-coated electrode and demonstrate the advantageous effects of the divalent charge on sensitivity. A simple theory predicts that the maximum concentration of an analyte ion preconcentrated in the thin membrane depends exponentially on the charge and that the current response based on exhaustive ion stripping from the thin membrane is proportional to the square of the charge. The theoretical predictions are quantitatively confirmed by using a thin ionophore-doped polymer membrane spin-coated on a conducting-polymer-modified electrode. The potentiostatic transfer of hydrophilic Ca(2+) from an aqueous sample into the hydrophobic double-polymer membrane is facilitated by an ionophore with high Ca(2+) affinity and selectivity. The resultant concentration of the Ca(2+)-ionophore complex in the ~1 μm-thick membrane can be at least 5 × 10(6) times higher than the aqueous Ca(2+) concentration. The stripping voltammetric current response to the divalent ion is enhanced to achieve a subnanomolar detection limit under the condition where a low-nanomolar detection limit is expected for a monovalent ion. Significantly, charge-dependent sensitivity is attractive for the ultrasensitive detection of multivalent ions with environmental and biomedical importance such as heavy metal ions and polyionic drugs. Importantly, this stripping voltammetric approach enables the absolute determination of subnanomolar Ca(2+) contamination in ultrapure water containing 10 mM supporting electrolytes, i.e., an 8 orders of magnitude higher background concentration. PMID:24992261

  11. Anodic dissolution of gold in alkaline solutions containing thiourea, thiosulfate and sulfite ions

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Gold dissolves electrochemically in alkaline solutions containing ligands to form complex ions with gold ion. Therefore, selective leaching of noble metals is expected without dissolution of base metals such as steels, aluminum alloys in scrap treatment. Gold electrodes were investigated using linear sweep voltammetry, EQCM method and potentiostatic electrolysis in alkaline solutions containing thiourea, Na2SO3 and Na2S2O3. The solution composition, electrode potential affect gold dissolution rate and current efficiency. The gold dissolved from anode electrode forms complex ions, suspension particles as compound precipitates and deposits on cathode electrode as a metal. Anodic efficiency for gold dissolution is between 10% and 22%. This is caused by the oxidation decomposition of sulfite ions and thiourea. The stability of the alkaline solution containing these elements was also estimated by capillary electrophoresis technique.

  12. Evidence of tetraphenylporphyrin monoacids by ion-transfer voltammetry at polarized liquid|liquid interfaces

    OpenAIRE

    Su, Bin; Li, Fei; Partovi-Nia, Raheleh; Gros, Claude; Barbe, Jean-Michel; Samec, Zdenek; Girault, Hubert H.

    2008-01-01

    We present a simple methodology to illustrate the existence of tetraphenylporphyrin monoacid based on ion-transfer voltammetry at a polarized water|1,2-dichloroethane interface and organic pK values are also estimated.

  13. Theory of linear sweep voltammetry with diffuse charge: unsupported electrolytes, thin films, and leaky membranes

    CERN Document Server

    Yan, David; Pugh, Mary C; Dawson, Francis P

    2016-01-01

    Linear sweep and cyclic voltammetry techniques are important tools for electrochemists and have a variety of applications in engineering. Voltammetry has classically been treated with the Randles-Sevcik equation, which assumes an electroneutral supported electrolyte. No general theory of linear-sweep voltammetry is available, however, for unsupported electrolytes and for other situations where diffuse charge effects play a role. In this paper, we provide a historical review of previous models and experiments and present a comprehensive mathematical theory of voltammetry in electrochemical cells with diffuse charge. We solve the time-dependent Poisson-Nernst-Planck (PNP) equations with generalized Frumkin-Butler-Volmer (FBV) boundary conditions, and show theoretical and simulated current-voltage curves for liquid and solid thin films, cells with blocking electrodes, and membranes with fixed background charge. The full range of dimensionless parameters is considered, including the dimensionless Debye screening ...

  14. Polyaniline-Coated Carbon Nanotube Ultrafiltration Membranes: Enhanced Anodic Stability for In Situ Cleaning and Electro-Oxidation Processes.

    Science.gov (United States)

    Duan, Wenyan; Ronen, Avner; Walker, Sharon; Jassby, David

    2016-08-31

    Electrically conducting membranes (ECMs) have been reported to be efficient in fouling prevention and destruction of aqueous chemical compounds. In the current study, highly conductive and anodically stable composite polyaniline-carbon nanotube (PANI-CNT) ultrafiltration (UF) ECMs were fabricated through a process of electropolymerization of aniline on a CNT substrate under acidic conditions. The resulting PANI-CNT UF ECMs were characterized by scanning electron microscopy, atomic force microscopy, a four-point conductivity probe, cyclic voltammetry, and contact angle goniometry. The utilization of the PANI-CNT material led to significant advantages, including: (1) increased electrical conductivity by nearly an order of magnitude; (2) increased surface hydrophilicity while not impacting membrane selectivity or permeability; and (3) greatly improved stability under anodic conditions. The membrane's anodic stability was evaluated in a pH-controlled aqueous environment under a wide range of anodic potentials using a three-electrode cell. Results indicate a significantly reduced degradation rate in comparison to a CNT-poly(vinyl alcohol) ECM under high anodic potentials. Fouling experiments conducted with bovine serum albumin demonstrated the capacity of the PANI-CNT ECMs for in situ oxidative cleaning, with membrane flux restored to its initial value under an applied potential of 3 V. Additionally, a model organic compound (methylene blue) was electrochemically transformed at high efficiency (90%) in a single pass through the anodically charged ECM. PMID:27525344

  15. Cyclic Voltammetry and Impedance Spectroscopy Behavior Studies of Polyterthiophene Modified Electrode

    OpenAIRE

    Naima Maouche; Belkacem Nessark

    2011-01-01

    We present in this work a study of the electrochemical behaviour of terthiophene and its corresponding polymer, which is obtained electrochemically as a film by cyclic voltammetry (CV) on platinum electrode. The analysis focuses essentially on the effect of two solvents acetonitrile and dichloromethane on the electrochemical behaviour of the obtained polymer. The electrochemical behavior of this material was investigated by cyclic voltammetry and electrochemical impedance spectroscopy (EIS). ...

  16. Differential Cyclic Voltammetry - a Novel Technique for Selective and Simultaneous Detection using Redox Cycling Based Sensors

    OpenAIRE

    Odijk, M.; Wiedemair, J.; Megen, M.J.J; Olthuis, W.; Van den Berg, A.

    2010-01-01

    Redox cycling (RC) is an effect that is used to amplify electrochemical signals. However, traditional techniques such as cyclic voltammetry (CV) do not provide clear insight for a mixture of multiple redox couples while RC is applied. Thus, we have developed a new measurement technique which delivers electrochemical spectra of all reversible redox couples present based on concentrations and standard potentials. This technique has been named differential cyclic voltammetry (DCV). We have fabri...

  17. Voltammetry as a Tool for Characterization of CdTe Quantum Dots

    OpenAIRE

    Vojtech Adam; Pavlina Sobrova; Marketa Ryvolova; Jaromir Hubalek; Rene Kizek

    2013-01-01

    Electrochemical detection of quantum dots (QDs) has already been used in numerous applications. However, QDs have not been well characterized using voltammetry, with respect to their characterization and quantification. Therefore, the main aim was to characterize CdTe QDs using cyclic and differential pulse voltammetry. The obtained peaks were identified and the detection limit (3 S/N) was estimated down to 100 fg/mL. Based on the convincing results, a new method for how to study stability an...

  18. Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress

    OpenAIRE

    Gulaboski, Rubin; Mirceski, Valentin; Bogeski, Ivan; Hoth, Markus

    2012-01-01

    This review is focused on the basic principles, the main applications, and the theoretical models developed for various redox mechanisms in protein film voltammetry, with a special emphasis to square-wave voltammetry as a working technique. Special attention is paid to the thermodynamic and kinetic parameters of relevant enzymes studied in the last decade at various modified electrodes, and their use as a platform for the detection of reactive oxygen species is also di...

  19. A brief review: Ultrafast electron diffractive voltammetry: General formalism and applications

    OpenAIRE

    Chang, Kiseok; Murdick, Ryan A.; Tao, Zhensheng; Han, Tzong-Ru T.; Ruan, Chong-Yu

    2013-01-01

    We present a general formalism of ultrafast diffractive voltammetry approach as a contact-free tool to investigate the ultrafast surface charge dynamics in nanostructured interfaces. As case studies, the photoinduced surface charging processes in oxidized silicon surface and the hot electron dynamics in nanoparticle-decorated interface are examined based on the diffractive voltammetry framework. We identify that the charge redistribution processes appear on the surface, sub-surface, and vacuu...

  20. Voltametria de onda quadrada. Segunda parte: aplicações Square wave voltammetry. Second part: applications

    OpenAIRE

    Djenaine de Souza; Lúcia Codognoto; Andréa R. Malagutti; Renata A. Toledo; Valber A. Pedrosa; Robson T. S. Oliveira; Luiz H. Mazo; Luis A. Avaca; Machado, Sergio A. S.

    2004-01-01

    The aim of this work is to discuss some selected applications of square wave voltammetry published in the last five years. The applications focused here cover several electroanalytical fields such as: determination of pesticides; molecules with biological activity; metals and other environmental pollutants. Special attention is given to the work developed in the Grupo de Materiais Eletroquímicos e Métodos Eletroanalíticos - IQSC - USP concerning the utilization of square wave voltammetry, wit...

  1. The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol–gel procedure

    Directory of Open Access Journals (Sweden)

    R. ATANASOSKI

    2000-09-01

    Full Text Available The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.

  2. Oxygen evolution reaction of Ti/IrO$_2$–SnO$_2$ electrode: a study by cyclic voltammetry, Tafel lines, EIS and SEM

    Indian Academy of Sciences (India)

    GAYANI CHATHURIKA PATHIRAJA; NADEESHANI NANAYAKKARA; ATHULA WIJAYASINGHE

    2016-06-01

    The electrochemical characteristics towards oxygen evolution reaction of thermally prepared Ti/IrO$_2$–SnO$_2$ electrodes were examined. Two electrodes prepared with two different IrO$_2$ compositions were analysed in Na$_2$SO$_4$ electrolyte. Cyclic voltammetry, steady state polarization curves, impedance spectroscopy and open circuit potential were performed to investigate the performance and stability of these electrocatalysts. It has foundthat the surface electrochemistry of Ti/IrO$_2$–SnO$_2$ anodes are governed by the Ir(III)/Ir(IV) couple. The impedance spectroscopy investigation permitted to propose an equivalent circuit to describe the modifications occurred in differentpotentials during oxygen evolution reaction. The same equivalent circuit was found to describe both electrodes. Moreover, the double layer capacitance and microstructure analysis reflected that the inner surface makes a largecontribution to the electrochemically active surface area of Ti/IrO$_2$–SnO$_2$ anodes. It was found that the stability and the electrocatalytic activity mainly depend on changes in the IrO$_2$ composition of the electrode and its morphology during oxygen evolution reaction.

  3. Synthesis of á-aminonitrile through Anodic Cyanation of N-benzylpiperidine

    Institute of Scientific and Technical Information of China (English)

    Zhao Ping; Yin Ying-wu

    2004-01-01

    Electrochemistry behaviors including linear sweep voltammetry and cyclic voltammetry of tertiary cyclic amines with different substituted group were studied. The effect of different substituted group of the nitrogen on the oxidation potential was analyzed. The most suited potential used in αα-aminonitrile synthesis through potentiostatic anodic cyanation of cyclic teritary amines was found. The anodic cyanation of N-alkyl-substituted cyclic six-membered amines including N-benzylpiperidine and N-ethylpiperidine has been investigated. The reaction gives the corresponding á-aminonitrile and carried out at a platinum anode in methanolic solution of the amine, containing 2.5 equivalents of sodium cyanide per mol of substrate. In all the selected amines the introduction of the cyanide group occurs in the position α to the nitrogen atom. We obtained two α-aminonitrile isomers. One is cyanated in the ring, the other is cyanated in the side chain. 1 The reaction mechanism is analyzedt brough analyzing the product of the constant current electrolysis and potentiostatic electrolysis and explained why the difference in the relative amount of isomers of tertiary cyclic amines and in the reactivities of the alkyl group between the ring and the side chain.The amount of isomers could not affect by the anode potential, and decided by the adsorption status at the anode surface and stability of the intermediate.The intermediate formed in anodic cyanation of N-benzylpiperidine is a parallel reaction, so the yield of α-aminonitrile can be increased but the selectivity of the two isomers cannot be increased in the potentiostatic electrolysis.The mechanism of the anode cyanation of N-benzylpiperidine was studied In methanol-water solution, anode cyanation of N-benzylpiperidine gives not only monocyanation product α-cyanoamine but also dicyanation product α, α-dicyanoamine and other byproduct because of overoxidation of N-benzylpiperidine caused by polarization of the anode under

  4. Controlling the occurrence of power overshoot by adapting microbial fuel cells to high anode potentials

    KAUST Repository

    Zhu, Xiuping

    2013-04-01

    Power density curves for microbial fuel cells (MFCs) often show power overshoot, resulting in inaccurate estimation of MFC performance at high current densities. The reasons for power overshoot are not well understood, but biofilm acclimation and development are known factors. In order to better explore the reasons for power overshoot, exoelectrogenic biofilms were developed at four different anode potentials (-0.46 V, -0.24 V, 0 V, and 0.50 V vs. Ag/AgCl), and then the properties of the biofilms were examined using polarization tests and cyclic voltammetry (CV). The maximum power density of the MFCs was 1200±100 mW/m2. Power overshoot was observed in MFCs incubated at -0.46 V, but not those acclimated atmore positive potentials, indicating that bacterial activitywas significantly influenced by the anode acclimation potential. CV results further indicated that power overshoot of MFCs incubated at the lowest anode potential was associatedwith a decreasing electroactivity of the anodic biofilm in the high potential region,which resulted from a lack of sufficient electron transfer components to shuttle electrons at rates needed for these more positive potentials. © 2012 Elsevier B.V.

  5. Voltammetric characteristics of miconazole and its cathodic stripping voltammetric determination

    Directory of Open Access Journals (Sweden)

    PEREIRA FRANCISCO C.

    2002-01-01

    Full Text Available Miconazole is reduced at mercury electrode above pH 6 involving organometallic compound formation, responsible for an anomalous polarographic behavior. The electrodic process presents a large contribution of the adsorption effects. The drug can be determined by cathodic stripping voltammetry from 8.0 x 10-8 to 1, 5 x 10-6 molL-1 in Britton-Robinson buffer pH 8.0, when pre-accumulated for 30s at an accumulation potential of 0V. A relative standard deviation of 3.8% was obtained for ten measurements of 1.0 x 10-7 molL-1 miconazole in B-R buffer pH 8.0 and a limit detection of 1, 7 x 10-8 molL-1 was determined using 60s of deposition time and scan rate of 100 mVs-1. The proposed method is simple, precise and it was applied successfully for the determination of the miconazole in pure form and in commercial formulations, showing mean recoveries of 99.7-98.4%.

  6. Dynamic Underground Stripping Demonstration Project

    International Nuclear Information System (INIS)

    LLNL is collaborating with the UC Berkeley College of Engineering to develop and demonstrate a system of thermal remediation and underground imaging techniques for use in rapid cleanup of localized underground spills. Called ''Dynamic Stripping'' to reflect the rapid and controllable nature of the process, it will combine steam injection, direct electrical heating, and tomographic geophysical imaging in a cleanup of the LLNL gasoline spill. In the first 8 months of the project, a Clean Site engineering test was conducted to prove the field application of the techniques before moving to the contaminated site in FY 92

  7. Method of stripping metals from organic solvents

    Science.gov (United States)

    Todd, Terry A.; Law, Jack D.; Herbst, R. Scott; Romanovskiy, Valeriy N.; Smirnov, Igor V.; Babain, Vasily A.; Esimantovski, Vyatcheslav M.

    2009-02-24

    A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

  8. Quantifiable Lateral Flow Assay Test Strips

    Science.gov (United States)

    2003-01-01

    As easy to read as a home pregnancy test, three Quantifiable Lateral Flow Assay (QLFA) strips used to test water for E. coli show different results. The brightly glowing control line on the far right of each strip indicates that all three tests ran successfully. But the glowing test line on the middle left and bottom strips reveal their samples were contaminated with E. coli bacteria at two different concentrations. The color intensity correlates with concentration of contamination.

  9. Solidification Structure of Low Carbon Steel Strips with Different Phosphorus Contents Produced by Strip Casting

    Institute of Scientific and Technical Information of China (English)

    Na LI; Zhenyu LIU; Yiqing QIU; Zhaosen LIN; Xianghua LIU; Guodong WANG

    2006-01-01

    In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains.

  10. High-rate capable, low-material budget floating strip Micromegas

    International Nuclear Information System (INIS)

    Floating strip Micromegas are versatile and high-rate capable particle detectors. Single particle tracking of medium-energy ions at fluxes up to 7 MHz/cm2 is possible, stable operation at rates of 2 GHz has been observed. Due to the nearly floating copper anode strips the detector is highly discharge tolerant. A detector system consisting of four low-material budget floating strip Micromegas with an active area of 6.4 cm x 6.4 cm and a scintillator based range telescope has been tested in 23 MeV proton beams at the tandem accelerator Garching. Fast Ne:CF4 based gas mixtures have been investigated which allow for a further increase of the high-rate capability by a factor of three. A synchronous readout of the strip detectors and the range telescope has been achieved. We report on the track inclination reconstruction capabilities in a single detector plane and on the measured electron drift velocity with the new gas mxitures. We furthermore present ion range radiography measurements with the combined system.

  11. Preparation and electrocatalytic properties of Ti/IrO2-Ta2O5 anodes for oxygen evolution

    Institute of Scientific and Technical Information of China (English)

    LI Bao-song; LIN An; GAN Fu-xing

    2006-01-01

    The preparation and electrocatalytic activity for oxygen evolution of the thermally prepared Ti anodes coated withIrO2 -Ta2O5 were studied. The structure and morphologies of the oxide films with different contents of IrO2 were determined by XRD and SEM respectively. Their electrochemical properties were studied by Linear Sweep Voltammetry, Tafel Plot and Cyclic Voltammetry. The results show that iridium and tantalum can form solid solution and the mutual solubility is affected by the ratio of Ir to Ta in coating solution. With increasing IrO2 content in the coatings, the amount of fine crystallites of IrO2 is increased and the electrocatalytic capability of oxygen evolution is strengthened. The coating adhesion and rigidity decrease, which affects electrochemical activity of the anode when the content of IrO2 is too high. The electrochemically active surface area is determined not only by the content of IrO2 but also the structure and morphology of the anode coatings. It is probably due to the existence of proper quantities of inert Ta2O5 which results in a typical morphology of cracks and solid solution structure.

  12. Hardy inequalities in strips on ruled surfaces

    Directory of Open Access Journals (Sweden)

    2006-01-01

    Full Text Available We consider the Dirichlet Laplacian in infinite two-dimensional strips defined as uniform tubular neighbourhoods of curves on ruled surfaces. We show that the negative Gauss curvature of the ambient surface gives rise to a Hardy inequality and we use this to prove certain stability of spectrum in the case of asymptotically straight strips about mildly perturbed geodesics.

  13. 33 CFR 157.128 - Stripping system.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Stripping system. 157.128 Section... Crude Oil Washing (COW) System on Tank Vessels Design, Equipment, and Installation § 157.128 Stripping system. (a) Each tank vessel having a COW system under § 157.10(e), § 157.10a(a)(2), or §...

  14. Water problems in Gaza Strip,Palestine

    Institute of Scientific and Technical Information of China (English)

    Ismail ALGHALBAN

    2001-01-01

    The only source for water in Gaza strip, southern Palestine, is the groundwater aquifer. The Pliocene - Pleistocene aquifer has two serious problems: quantity and quality. This study is an attempt to identify the problems and to suggest solutions for water problems in Gaza strip. In addition, some rules for rehabilitation of the aquifers were suggested.

  15. Smooth muscle strips for intestinal tissue engineering.

    Directory of Open Access Journals (Sweden)

    Christopher M Walthers

    Full Text Available Functionally contracting smooth muscle is an essential part of the engineered intestine that has not been replicated in vitro. The purpose of this study is to produce contracting smooth muscle in culture by maintaining the native smooth muscle organization. We employed intact smooth muscle strips and compared them to dissociated smooth muscle cells in culture for 14 days. Cells isolated by enzymatic digestion quickly lost maturity markers for smooth muscle cells and contained few enteric neural and glial cells. Cultured smooth muscle strips exhibited periodic contraction and maintained neural and glial markers. Smooth muscle strips cultured for 14 days also exhibited regular fluctuation of intracellular calcium, whereas cultured smooth muscle cells did not. After implantation in omentum for 14 days on polycaprolactone scaffolds, smooth muscle strip constructs expressed high levels of smooth muscle maturity markers as well as enteric neural and glial cells. Intact smooth muscle strips may be a useful component for engineered intestinal smooth muscle.

  16. Ultrasonic examination of JBK-75 strip material

    International Nuclear Information System (INIS)

    An ultrasonic inspection system was assembled to inspect the JBK-75 stainless steel sheath material (for the Large Coil Project) for the Westinghouse-Airco superconducting magnet program. The mechanical system provided for handling the 180-kg (400-lb) coils of strip material [1.6 mm thick by 78 mm wide by 90 to 120 m long (0.064 by 3.07 in. by 300 to 400 ft)], feeding the strip through the ultrasonic inspection and cleaning stations, and respooling the coils. We inspected 54 coils of strip for both longitudinal and laminar flaws. Simulated flaws were used to calibrate both inspections. Saw-cut notches [0.28 mm deep (0.011 in., about 17% of the strip thickness)] were used to calibrate the longitudinal flaw inspections; 1.59-mm-diam (0.063-in.) flat-bottom holes drilled halfway through a calibration strip were used to calibrate the laminar flaw tests

  17. Capacitively coupled pickup in MCP-based photodetectors using a conductive metallic anode

    CERN Document Server

    Angelico, Evan; Adams, Bernhard; Elagin, Andrey; Frisch, Henry; Spieglan, Eric

    2016-01-01

    We have designed and tested a robust 20 $\\times$ 20 cm$^2$ thin metal film internal anode capacitively coupled to an external array of signal pads or micro-strips for use in fast microchannel plate photodetectors. The internal anode, in this case a 10nm-thick NiCr film deposited on a 96% pure Al$_2$O$_3$ 3mm-thick ceramic plate and connected to HV ground, provides the return path for the electron cascade charge. The multi-channel pickup array consists of a printed-circuit card or glass plate with metal signal pickups on one side and the signal ground plane on the other. The pickup can be put in close proximity to the bottom outer surface of the sealed photodetector, with no electrical connections through the photodetector hermetic vacuum package other than a single ground connection to the internal anode. Two pickup patterns were tested using a small commercial MCP-PMT as the signal source: 1) parallel 50$\\Omega$ 25-cm-long micro-strips with an analog bandwidth of 1.5 GHz, and 2) a 20 $\\times$ 20 cm$^2$ array...

  18. Ellipsometry of anodic film growth

    Energy Technology Data Exchange (ETDEWEB)

    Smith, C.G.

    1978-08-01

    An automated computer interpretation of ellisometer measurements of anodic film growth was developed. Continuous mass and charge balances were used to utilize more fully the time dependence of the ellipsometer data and the current and potential measurements. A multiple-film model was used to characterize the growth of films which proceeds via a dissolution--precipitation mechanism; the model also applies to film growth by adsorption and nucleation mechanisms. The characteristic parameters for film growth describe homogeneous and heterogeneous crystallization rates, film porosities and degree of hydration, and the supersaturation of ionic species in the electrolyte. Additional descriptions which may be chosen are patchwise film formation, nonstoichiometry of the anodic film, and statistical variations in the size and orientation of secondary crystals. Theories were developed to describe the optical effects of these processes. An automatic, self-compensating ellipsometer was used to study the growth in alkaline solution of anodic films on silver, cadmium, and zinc. Mass-transport conditions included stagnant electrolyte and forced convection in a flow channel. Multiple films were needed to characterize the optical properties of these films. Anodic films grew from an electrolyte supersatuated in the solution-phase dissolution product. The degree of supersaturation depended on transport conditions and had a major effect on the structure of the film. Anodic reaction rates were limited by the transport of charge carriers through a primary surface layer. The primary layers on silver, zinc, and cadmium all appeared to be nonstoichiometric, containing excess metal. Diffusion coefficients, transference numbers, and the free energy of adsorption of zinc oxide were derived from ellipsometer measurements. 97 figures, 13 tables, 198 references.

  19. Reinterpretation of reduction potential measurements done by linear sweep voltammetry in silicate melts

    Science.gov (United States)

    Colson, R. O.; Haskin, L. A.; Keedy, C. R.

    1991-01-01

    The equilibrium concentrations of Ni between silicate melt and Pt were determined experimentally as a function of oxygen fugacity. The results demonstrate that metallic species derived in linear sweep voltammetry experiments in silicate melts are diffusing into Pt electrodes and not into the melt, as was concluded by previoius studies. This requires reinterpretation of previous linear sweep voltammetry results and recalculation and correction of reported reduction potentials. This paper reports these corrected reduction potentials. Also reported are the activity coefficients for Ni in synthetic basalt and diopsidic melts and for Co in diopsidic melt.

  20. Anode sheath transition in an anodic arc for synthesis of nanomaterials

    Science.gov (United States)

    Nemchinsky, V. A.; Raitses, Y.

    2016-06-01

    The arc discharge with ablating anode or so-called anodic arc is widely used for synthesis of nanomaterials, including carbon nanotubes and fullerens, metal nanoparticles etc. We present the model of this arc, which confirms the existence of the two different modes of the arc operation with two different anode sheath regimes, namely, with negative anode sheath and with positive anode sheath. It was previously suggested that these regimes are associated with two different anode ablating modes—low ablation mode with constant ablation rate and the enhanced ablation mode (Fetterman et al 2008 Carbon 46 1322). The transition of the arc operation from low ablation mode to high ablation mode is determined by the current density at the anode. The model can be used to self-consistently determine the distribution of the electric field, electron density and electron temperature in the near-anode region of the arc discharge. Simulations of the carbon arc predict that for low arc ablating modes, the current is driven mainly by the electron diffusion to the anode. For positive anode sheath, the anode voltage is close to the ionization potential of anode material, while for negative anode sheath, the anode voltage is an order of magnitude smaller. It is also shown that the near-anode plasma, is far from the ionization equilibrium.

  1. Anodic behavior and microstructure of Al/Pb-Ag anode during zinc electrowinning%Al/Pb-Ag阳极在锌电积过程中的阳极行为和微观结构

    Institute of Scientific and Technical Information of China (English)

    张永春; 陈步明; 杨海涛; 郭忠诚; 徐瑞东

    2014-01-01

    Anodic behaviors and oxygen evolution kinetics of Pb-0.8%Ag and Al/Pb-0.8%Ag anodes during the initial 24 h zinc electrowinning were investigated with cyclic voltammetry (CV) curves and electrochemical impedance spectroscopy (EIS). The results reveal that the anodic behaviors and reaction kinetics of the two anodes vary a lot during the anodic polarization which indicate the formation and stabilization of anodic layer. Compared with conventional Pb-0.8%Ag anode, Al/Pb-0.8%Ag anode has longer time of anodic polarization. At the very beginning of anodic polarization, the two anodes all exhibit higher potential of oxygen evolution reaction (OER) since the reaction is controlled by the transformation step of intermediates. Then, its OER potential is largely diminished and OER rate is deduced from the formation and adsorption of the first intermediate (S-OHads). In the prolonged anodic polarization, the anodic potential of Al/Pb-0.8%Ag gradually decreases and the final value is more stable than that of conventional Pb-0.8%Ag anode. On the anodic layer after 24 h of anodic polarization, the OER potential is controlled by the formation and adsorption of intermediate. The microstructures of Al/Pb-0.8%Ag and Pb-0.8%Ag anodes after 24 h of anodic polarization were analyzed by scanning electron microscope (SEM).%采用循环伏安曲线(CV)和电化学交流阻抗谱(EIS)研究Pb-0.8%Ag 和Al/Pb-0.8%Ag阳极在最初24 h锌电积过程中的阳极行为和析氧动力学。结果表明:2种阳极材料在阳极极化过程中的阳极行为和动力学的多种变化表明阳极表面膜的形成和稳定。与传统的Pb-0.8%Ag阳极相比,Al/Pb-0.8%Ag阳极具有较长的极化时间。在最初的电积过程中,阳极表面中间产物的转变使2种阳极都表现出较高的析氧电位。随着析氧电位降低,析氧反应速率可以由阳极表面最初的生成物和中间产物S-OHads推断。随着电积的持续进行,Al/Pb-0.8%Ag阳极的析

  2. Electrocatalysis of carbon anode in aluminium electrolysis

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The anodic overvoltage of the carbon anode in aluminum electrolysis isof the order of 0.6 V at normal current densities. However, it can be reduced somewhat by doping the anode carbon with various inorganic compounds. A new apparatus was designed to improve the precision of overvoltage measurements. Anodes were doped with MgAl2O4 and AlF3 both by impregnation of the coke and by adding powder, and the measured overvoltage was compared with that of undoped samples. For prebake type anodes baked at around 1150 oC, the anodic overvoltage was reduced by 40-60 mV, and for Soderberg type anodes, baked at 950 oC, by 60-80 mV.

  3. Electrochemical grafting of TiO2-based photo-anodes and its effect in dye-sensitized solar cells

    DEFF Research Database (Denmark)

    Lund, Torben; Phuong, Nguyen Tuyet; Ruhland, Thomas Gerhard Aloysius

    2015-01-01

    by the electrochemical reduction of 4-nitrobenzenediazonium tetrafluoroborate in acetonitrile. We found that the grafting surfaces were chemically inert to strong acids and bases. The grafted surfaces were characterized and analyzed by cyclic voltammetry (CV), attenuated total reflectance Fourier transform infrared...... spectroscopy (ATR–FTIR), X-ray photo electron spectroscopy (XPS), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX). Implementation of electrochemically grafted TiO2 particles as photo-anodes in dye-sensitized solar cells (DSCs) showed that the grafted surface is capable of suppressing...

  4. A Strip Cell in Pyroelectric Devices

    Science.gov (United States)

    Siao, An-Shen; Chao, Ching-Kong; Hsiao, Chun-Ching

    2016-01-01

    The pyroelectric effect affords the opportunity to convert temporal temperature fluctuations into usable electrical energy in order to develop abundantly available waste heat. A strip pyroelectric cell, used to enhance temperature variation rates by lateral temperature gradients and to reduce cell capacitance to further promote the induced voltage, is described as a means of improving pyroelectric energy transformation. A precision dicing saw was successfully applied in fabricating the pyroelectric cell with a strip form. The strip pyroelectric cell with a high-narrow cross section is able to greatly absorb thermal energy via the side walls of the strips, thereby inducing lateral temperature gradients and increasing temperature variation rates in a thicker pyroelectric cell. Both simulation and experimentation show that the strip pyroelectric cell improves the electrical outputs of pyroelectric cells and enhances the efficiency of pyroelectric harvesters. The strip-type pyroelectric cell has a larger temperature variation when compared to the trenched electrode and the original type, by about 1.9 and 2.4 times, respectively. The measured electrical output of the strip type demonstrates a conspicuous increase in stored energy as compared to the trenched electrode and the original type, by of about 15.6 and 19.8 times, respectively. PMID:26999134

  5. Transfusion and blood donation in comic strips.

    Science.gov (United States)

    Lefrère, Jean-Jacques; Danic, Bruno

    2013-07-01

    The representation of blood transfusion and donation of blood in the comic strip has never been studied. The comic strip, which is a relatively recent art, emerged in the 19th century before becoming a mass medium during the 20th century. We have sought, by calling on collectors and using the resources of Internet, comic strips devoted, wholly or in part, to the themes of transfusion and blood donation. We present some of them here in chronologic order, indicating the title, country of origin, year of publication, and names of authors. The theme of the superhero using transfusion to transmit his virtues or his powers is repeated throughout the 20th century in North American comic strips. More recently, comic strips have been conceived from the outset with a promotional aim. They perpetuate positive images and are directed toward a young readership, wielding humor to reduce the fear of venipuncture. Few comic strips denounce the abuse of the commercialization of products derived from the human body. The image of transfusion and blood donation given by the comic strips is not to be underestimated because their readership is primarily children, some of whom will become blood donors. Furthermore, if some readers are transfused during their lives, the impact of a memory more or less conscious of these childhood readings may resurface, both in hopes and in fears.

  6. Cyclic Voltammetry Simulations with DigiSim Software: An Upper-Level Undergraduate Experiment

    Science.gov (United States)

    Messersmith, Stephania J.

    2014-01-01

    An upper-division undergraduate chemistry experiment is described which utilizes DigiSim software to simulate cyclic voltammetry (CV). Four mechanisms were studied: a reversible electron transfer with no subsequent or proceeding chemical reactions, a reversible electron transfer followed by a reversible chemical reaction, a reversible chemical…

  7. CYCLIC VOLTAMMETRY OF ORGANIC AND INORGANIC N-CHLORAMINES IN AQUEOUS SOLUTION

    Science.gov (United States)

    Aqueous solutions or organic and inorganic N-chloramines as well as hypochlorite were examined by cyclic voltammetry at DH 8 and in strong acid (pH<2) with platinum and glassy carbon electrodes. The inorganic N-chloramines were characterized in 1 M HC104. NHC12 is reduced at abou...

  8. Carbon nanofiber electrode array for electrochemical detection of dopamine using fast scan cyclic voltammetry

    OpenAIRE

    Koehne, Jessica E.; Marsh, Michael; Boakye, Adwoa; Douglas, Brandon; Kim, In Yong; Chang, Su-Youne; Jang, Dong-Pyo; Bennet, Kevin E.; Kimble, Christopher; Andrews, Russell; Meyyappan, M.; Lee, Kendall H.

    2011-01-01

    A carbon nanofiber (CNF) electrode array was integrated with the Wireless Instantaneous Neurotransmitter Sensor System (WINCS) for detection of dopamine using fast scan cyclic voltammetry (FSCV). Dopamine detection performance by CNF arrays was comparable to that of traditional carbon fiber microelectrodes (CFMs), demonstrating that CNF arrays can be utilized as an alternative carbon electrodes for neurochemical monitoring.

  9. Development and Use of a Cyclic Voltammetry Simulator to Introduce Undergraduate Students to Electrochemical Simulations

    Science.gov (United States)

    Brown, Jay H.

    2015-01-01

    Cyclic voltammetry (CV) is a popular technique for the study of electrochemical mechanisms because the method can provide useful information on the redox couple. The technique involves the application of a potential ramp on an unstirred solution while the current is monitored, and then the ramp is reversed for a return sweep. CV is sometimes…

  10. The Rise of Voltammetry: From Polarography to the Scanning Electrochemical Microscope

    Science.gov (United States)

    Bard, Allen J.

    2007-01-01

    The drooping mercury electrode (DME) was previously used to carry out electrochemical experiments but invention of polarography technique changed this. Voltammetry with DME was given the term polarography and are used in measurement of current as a function of potential at small electrodes.

  11. Saving Energy Through Advanced Power Strips (Poster)

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, D.

    2013-10-01

    Advanced Power Strips (APS) look just like ordinary power strips, except that they have built-in features that are designed to reduce the amount of energy used by many consumer electronics. There are several different types of APSs on the market, but they all operate on the same basic principle of shutting off the supply power to devices that are not in use. By replacing your standard power strip with an APS, you can signifcantly cut the amount of electricity used by your home office and entertainment center devices, and save money on your electric bill. This illustration summarizes the different options.

  12. Instabilities and Solitons in Minimal Strips.

    Science.gov (United States)

    Machon, Thomas; Alexander, Gareth P; Goldstein, Raymond E; Pesci, Adriana I

    2016-07-01

    We show that highly twisted minimal strips can undergo a nonsingular transition, unlike the singular transitions seen in the Möbius strip and the catenoid. If the strip is nonorientable, this transition is topologically frustrated, and the resulting surface contains a helicoidal defect. Through a controlled analytic approximation, the system can be mapped onto a scalar ϕ^{4} theory on a nonorientable line bundle over the circle, where the defect becomes a topologically protected kink soliton or domain wall, thus establishing their existence in minimal surfaces. Demonstrations with soap films confirm these results and show how the position of the defect can be controlled through boundary deformation. PMID:27419593

  13. THE DEVELOPMENT OF FCC STRIPPING TECHNOLOGY

    Institute of Scientific and Technical Information of China (English)

    ZHANGZhen-qian

    2003-01-01

    This article briefly describes the major patents domestic and the abroad,and the current situation and achievements of FCC stripping technology in China.The develping trend of FCC stripping technology is presented,including further developments of FCC stripper to improve unit performance,combination of the stripper and pre-stripper within disengager to from a complete high-efficiency FCC stripping system.In addition to high efficiency,simple structure and easiness of installation and maintenance for a new FCC stripper are all of consideration.

  14. NH4-doped anodic WO3 prepared through anodization and subsequent NH4OH treatment for water splitting

    International Nuclear Information System (INIS)

    Highlights: • NN4-doped WO3 was successfully fabricated by a wet-based method using ammonium hydroxide (NH4OH). • (NH4)10W12O41 phase was formed during the NH4OH treatment. • Over-doped NH4 in WO3 led to reduced photo-electrochemical performance for OER. • The optimized surface was achieved by thermal treatment of anodic WO3 with 2 g of NH4OH solution. - Abstract: Tungsten trioxide (WO3) prepared by anodization of a W foil was doped with NH4 through NH4OH treatment at 450 °C. Since aqueous NH4OH was used during doping instead of NH3 gas, the treatment step does not require complicated annealing facilities. Moreover, the state of doped N is a form of NH3-W instead of W2N, which lowers the bandgap but increases photocorrosion. We found that incorporation of NH4 into WO3 leads to reduction of the bandgap from 2.9 eV to 2.2 eV, regardless of the amount of NH4OH treatment, lowering the onset potential and increasing the current density at fixed potential for oxygen evolution reaction under illumination. Scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy were employed to investigate the surface morphologies, crystallinities of tungsten oxides and existence of NH4 doping, respectively. The bandgap energy was determined by UV–Vis spectroscopy to measure the transmittance and refraction. The water splitting performance of each sample was measured by electrochemical linear sweep voltammetry in a 3-electrode configuration under illumination

  15. EFFECT OF TEFLON AND NAFION LOADING AT ANODE IN DIRECT FORMIC ACID FUEL CELL (DFAFC

    Directory of Open Access Journals (Sweden)

    M. S. MASDAR

    2016-08-01

    Full Text Available DFAFC has extensive hydrophilic nature and will cause problems in a limited mass transport in the anode side of electrode. Thus, the microporous layer (MPL of DFAFC needs a different in structure and morphology compared with that of PEMFC and DMFC because it will directly affect the performance. Therefore, in this study, the formulation of anode’s MPL has been investigated by varying the amount of Teflon and Nafion. Different loading of Teflon in MPL and Nafion in catalyst layer, i.e., 0 to 40% in weight, were used to fabricate the anode’s DFAFC. The characteristic of MPLs and anode (MPL with catalyst layer such as surface morphologies and resistivity, i.e., electrical impedance, have been analyzed using field emission scanning electron microscopy (FESEM and contact angle measurements as well as electrochemical impedance spectra (EIS. Meanwhile, the performance of fabricated anode was measured using cyclic voltammetry (CV technique with a half cell of DFAFC. From the result, it was obtained that the optimum content for both Teflon and Nafion on anode’s DFAFC was 20 wt% as shown in a highest electro-activity in electrode. The single cell DFAFC with optimum MEA formulation showed a good performance and hence, it is possible to apply the electricity power for electronic devices.

  16. Carbon nanotubes coated with platinum nanoparticles as anode of biofuel cell

    Institute of Scientific and Technical Information of China (English)

    Jianmei Zhang; Yihua Zhu; Cheng Chen; Xiaoling Yang; Chunzhong Li

    2012-01-01

    A hybrid system of carbon nanotubes (CNTs) coated with poly (amidoamine) (PAMAM) dendrimerencapsulated platinum nanoparticles (Pt-DENs) and glucose oxidase (GOx) was prepared through the layer-by-layer (LbL) self-assembly approach and then used as anode in enzyme-based biofuel cells (BFCs).The assembly process was monitored by ζ-potential measurement,and the as-resulted Pt-DENs/CNTs nanocomposites were characterized by transmission electron microscopy (TEM).The performance of electrodes modified by Pt-DENs/CNTs was also investigated by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV).We found that the Pt-DENs/CNTs could enhance the electron transfer between the redox centers in enzyme and the electrode surfaces.Furthermore,by employing the Pt-DENs/CNTs modified electrodes as anode,the enzyme-based BFCs operated in a solution containing glucose generated an open-circuit voltage of approximately 640.0 mV and a maximum current density of about 90.0 μA/cm2,suggesting that Pt-DENs/CNTs may serve as an alternative anode to previously used noble metals in BFC applications.

  17. Inapproximability of maximal strip recovery

    CERN Document Server

    Jiang, Minghui

    2009-01-01

    In comparative genomic, the first step of sequence analysis is usually to decompose two or more genomes into syntenic blocks that are segments of homologous chromosomes. For the reliable recovery of syntenic blocks, noise and ambiguities in the genomic maps need to be removed first. Maximal Strip Recovery (MSR) is an optimization problem proposed by Zheng, Zhu, and Sankoff for reliably recovering syntenic blocks from genomic maps in the midst of noise and ambiguities. Given $d$ genomic maps as sequences of gene markers, the objective of \\msr{d} is to find $d$ subsequences, one subsequence of each genomic map, such that the total length of syntenic blocks in these subsequences is maximized. For any constant $d \\ge 2$, a polynomial-time 2d-approximation for \\msr{d} was previously known. In this paper, we show that for any $d \\ge 2$, \\msr{d} is APX-hard, even for the most basic version of the problem in which all gene markers are distinct and appear in positive orientation in each genomic map. Moreover, we provi...

  18. A video strip chart program

    International Nuclear Information System (INIS)

    A strip chart recorder has been utilized for trend analysis of the Oak Ridge National Laboratory EN tandem since 1987. At the EN, the author could not afford the nice eight channel thermal pen recorder that was used at the 25 URC. He had to suffice with two channel fiber tip or capillary pen type recorders retrieved from salvage and maintained with parts from other salvaged recorders. After cycling through several machines that eventually became completely unserviceable, a search for a new thermal recorder was begun. As much as he hates to write computer code, he decided to try his hand at getting an old data acquisition unit, that had been retrieved several years ago from salvage, to meet his needs. A BASIC language compiler was used because time was not available to learn a more advanced language. While attempting to increase acquisition and scroll speed on the 6 MHz 80286 that the code was first developed on, it became apparent that scrolling only the first small portion of the screen at high speed and then averaging that region and histogramming the average provided both the speed necessary for capturing fairly short duration events, and a trend record without use of back scrolling and disk storage routines. This turned out to be quite sufficient

  19. Dynamic underground stripping demonstration project

    International Nuclear Information System (INIS)

    LLNL is collaborating with the UC Berkeley College of Engineering to develop and demonstrate a system of thermal remediation techniques for rapid cleanup of localized underground spills. Called dynamic stripping to reflect the rapid and controllable nature of the process, it will combine steam injection, direct electrical heating, and tomographic geophysical imaging in a cleanup of the LLNL gasoline spill. In the first eight months of the project, a Clean Site engineering test was conducted to prove the field application of the techniques. Tests then began on the contaminated site in FY 1992. This report describes the work at the Clean Site, including design and performance criteria, test results, interpretations, and conclusions. We fielded 'a wide range of new designs and techniques, some successful and some not. In this document, we focus on results and performance, lessons learned, and design and operational changes recommended for work at the contaminated site. Each section focuses on a different aspect of the work and can be considered a self-contained contribution

  20. Position sensitive anodes for MCP read-out using induced charge measurement

    CERN Document Server

    Jagutzki, O; Mergel, V; Schmidt-Böcking, H; Spillmann, U; Worth, L B C

    2002-01-01

    We investigate the method of an indirect detection of a MCP charge avalanche projected onto a resistive layer (G. Battistoni, et al., Nucl. Instr. and Meth., 202 (1982) 459). If the sheet resistance is favourable one can detect the charge cloud by the capacitive coupling to an anode structure a few millimetres behind the layer. The anode structure can be, for example, a wedge-and-strip electrode pattern (M. Unverzagt, Diplomarbeit, Universitaet Frankfurt 1992, private communication) as it is used for directly collecting the electron avalanche from a MCP. Detection of the induced charge is beneficial in several respects. Firstly, image distortions produced by secondary electron mediated charge redistribution are eliminated. Secondly, the noise component due to quantized charge collection, commonly referred to as partition noise, is not present. In addition, the dielectric substrate can function both as an element of the vacuum enclosure and HV insulator, making the electrical connections easily accessible and ...

  1. Micro thermal shear stress sensor based on vacuum anodic bonding and bulk-micromachining

    Institute of Scientific and Technical Information of China (English)

    Yi Liang; Ou Yi; Shi Sha-Li; Ma Jin; Chen Da-Peng; Ye Tian-Chun

    2008-01-01

    This paper describes a micro thermal shear stress sensor with a cavity underneath, based on vacuum anodic bonding and bulk micromachined technology. A Ti/Pt alloy strip, 2μmx100μm, is deposited on the top of a thin silicon nitride diaphragm and functioned as the thermal sensor element. By using vacuum anodic bonding and bulk-si anisotropic wet etching process instead of the sacrificial-layer technique, a cavity, functioned as the adiabatic vacuum chamber, 200μm×200μm×400μm, is placed between the silicon nitride diaphragm and glass (Corning 7740). This method totally avoid adhesion problem which is a major issue of the sacrificial-layer technique.

  2. Reactions on carbon anodes in aluminium electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Eidet, Trygve

    1997-12-31

    The consumption of carbon anodes and energy in aluminium electrolysis is higher than what is required theoretically. This thesis studies the most important of the reactions that consume anode materials. These reactions are the electrochemical anode reaction and the airburn and carboxy reactions. The first part of the thesis deals with the kinetics and mechanism of the electrochemical anode reaction using electrochemical impedance spectroscopy. The second part deals with air and carboxy reactivity of carbon anodes and studies the effects of inorganic impurities on the reactivity of carbon anodes in the aluminium industry. Special attention is given to sulphur since its effect on the carbon gasification is not well understood. Sulphur is always present in anodes, and it is expected that the sulphur content of available anode cokes will increase in the future. It has also been suggested that sulphur poisons catalyzing impurities in the anodes. Other impurities that were investigated are iron, nickel and vanadium, which are common impurities in anodes which have been reported to catalyze carbon gasification. 88 refs., 92 figs., 24 tabs.

  3. Stripping voltammetric determination of palladium, platinum and rhodium in freshwater and sediment samples from South African water resources.

    Science.gov (United States)

    van der Horst, C; Silwana, B; Iwuoha, E; Somerset, V

    2012-01-01

    Stripping voltammetry as technique has proved to be very useful in the analysis of heavy and other metal ions due to its excellent detection limits and its sensitivity in the presence of different metal species or interfering ions. Recent assessments of aquatic samples have shown increased levels of platinum group metals (PGMs) in aquatic ecosystems, caused by automobile exhaust emissions and mining activities. The development of an analytical sensor for the detection and characterisation of PGMs were investigated, since there is an ongoing need to find new sensing materials with suitable recognition elements that can respond selectively and reversibly to specific metal ions in environmental samples. The work reported shows the successful application of another mercury-free sensor electrode for the determination of platinum group metals in environmental samples. The work reported in this study entails the use of a glassy carbon electrode modified with a bismuth film for the determination of platinum (Pt(2+)), palladium (Pd(2+)) or rhodium (Rh(2+)) by means of adsorptive cathodic stripping voltammetry. Optimised experimental conditions included composition of the supporting electrolyte, complexing agent concentration, deposition potential, deposition time and instrumental voltammetry parameters for Pt(2+), Pd(2+) and Rh(2+) determination. Adsorptive differential pulse stripping voltammetric measurements for PGMs were performed in the presence of dimethylglyoxime (DMG) as complexing agent. The glassy carbon bismuth film electrode (GC/BiFE) employed in this study exhibit good and reproducible sensor characteristics. Application of GC/BiFE sensor exhibited well-defined peaks and highly linear behaviour for the stripping analysis of the PGMs in the concentration range between 0 and 3.5 μg/L. The detection limit of Pd, Pt and Rh was found to be 0.12 μg/L, 0.04 μg/L and 0.23 μg/L, respectively for the deposition times of 90 s (Pd) and 150 s (for both Pt and Rh). Good

  4. Fabrication of MMC Strip by CRB Process

    Science.gov (United States)

    Jamaati, Roohollah; Toroghinejad, Mohammad Reza

    2012-06-01

    In this study, Al/Al2O3 composite strips were produced by the cold roll bonding (CRB) process. Microhardness, tensile strength, and elongation of composite strips were investigated as a result of changes in thickness reduction, quantity of alumina particles, and the production method used. It was found that higher values of reduction and quantities of alumina improved microhardness and tensile strength but decreased elongation. Furthermore, as-received strips exhibited the highest values for microhardness and tensile strength but the lowest for elongation. In contrast, post-rolling annealed strips recorded the lowest values for microhardness and tensile strength but the highest for elongation. Finally, it was found that pre-rolling annealing was the best method for producing this composite via the CRB process.

  5. Ram Pressure Stripping: The Long Goodbye

    Science.gov (United States)

    Tonnesen, Stephanie; Lu, Yu; Benson, Andrew; Peter, Annika; Boylan-Kolchin, Michael; Wetzel, Andrew R.; Weisz, Daniel R.

    2016-01-01

    What turns off star formation in satellite galaxies? Ram pressure stripping, the removal of a galaxy's gas through direct interaction with the gas halo in which it orbits, is an attractive quenching mechanism, particularly in the Milky Way halo where the radial distribution of quenching is dramatic. However, many implementations of this process in semi-analytic models result in overly-rapid gas removal when compared with observations. We use high resolution hydrodynamical simulations run with Enzo to parameterize the stripping of disk and halo gas from an orbiting satellite galaxy for use in the semi-analytic modeling code Galacticus. We find that using the instantaneous ram pressure overestimates the amount of gas that is stripped, and present a physically-motivated module for including ram pressure stripping in semi-analytic models that uses the integral of the ram pressure experienced by a satellite galaxy. We will compare our results to observations of the Milky Way satellites.

  6. Potential profile in a conducting polymer strip

    DEFF Research Database (Denmark)

    Bay, Lasse; West, Keld; Vlachopoulos, Nikolaos;

    2002-01-01

    Many conjugated polymers show an appreciable difference in volume between their oxidized and reduced forms. This property can be utilized in soft electrochemically driven actuators, "artificial muscles". Several geometries have been proposed for the conversion of the volume expansion into useful...... mechanical work. In a particularly simple geometry, the length change of polymer strips is exploited. The polymer strips are connected to the driving circuit at the end of the strip that is attached to the support of the device. The other end of the strip is connected to the load. The advantage of this set......-up is simplicity and that the maximum force generated in the polymer can be transferred directly to the load. There is, however, an inherent problem in this design that will be examined in this paper. If the potential of the reduced state is below that for oxygen reduction, only a finite length of the free...

  7. Si strip detector with integrated coupling capacitors

    Energy Technology Data Exchange (ETDEWEB)

    Caccia, M.; Evensen, L.; Hansen, T.E.; Horisberger, R.; Hubbeling, L.; Peisert, A.; Tuuva, T.; Weilhammer, P.; Zalewska, A.

    1987-10-01

    A silicon microstrip detector with capacitive coupling of the diode strips to the metallization and with individual polysilicon resistors to each diode has been developed. The detector was tested in a minimum ionizing particle beam showing a performance similar to conventional strip detectors and a spatial resolution of 3.5 ..mu..m. Capacitive coupling allows the decoupling of the leakage current from the input to the charge sensitive preamplifier especially in the case of LSI electronics.

  8. A comparative study of enhanced electrochemical stability of tin–nickel alloy anode for high-performance lithium ion battery

    International Nuclear Information System (INIS)

    Highlights: • Sn and Sn–Ni alloy nanoparticles are synthesized by chemical co-precipitation method. • Sn–Ni alloy particles show different phase structure and morphology from Sn particles. • Cyclic voltammetry reveals distinct redox reaction behaviors at Sn and alloy anodes. • Impedance analyses show better stability of alloy electrodes over prolonged cycling. - Abstract: Sn and Sn–Ni alloy nanoparticles are synthesized readily by co-precipitation method for their applications in Li-ion batteries. It is found that nickel not only affects the phase structure and morphology of the alloy, but also impacts Li–Sn alloying and dealloying behaviors. In Li-ion batteries, the alloy electrodes deliver stronger cycling stability than the pure Sn anode. In tests the former exhibits a final capacity of 228.5 mA h g−1 over 50 cycles, while the latter displays 14.3 mA h g−1. Smaller current for battery cycles increases capacities of the alloys beyond 408.4 mA h g−1. The mechanism of enhanced stability of Sn–Ni alloys is examined. Redox reaction characteristics and Li-ion transfer kinetics at these anodes after different cycles are investigated by cyclic voltammetry and electrochemical impedance spectroscopy, which are considered to associate with buffering effects of nickel and structural integrity of electrodes. Li–Sn alloying and dealloying reactions cause volume changes and induce stress that releases in the formation of tiny cracks within the particles. The cracks accelerate side reactions and decelerate charge transport, detrimental to the electrode stability. Nickel cushions the volume variations and reduces the stress and cracks at Sn–Ni alloy anodes to allow them to maintain better electrode integrity and smaller charge resistance, thus yielding their improved Li-ion intercalation stability during long-term cycling

  9. A comparative study of enhanced electrochemical stability of tin–nickel alloy anode for high-performance lithium ion battery

    Energy Technology Data Exchange (ETDEWEB)

    Guan, Dongsheng; Li, Jianyang; Gao, Xianfeng; Yuan, Chris, E-mail: cyuan@uwm.edu

    2014-12-25

    Highlights: • Sn and Sn–Ni alloy nanoparticles are synthesized by chemical co-precipitation method. • Sn–Ni alloy particles show different phase structure and morphology from Sn particles. • Cyclic voltammetry reveals distinct redox reaction behaviors at Sn and alloy anodes. • Impedance analyses show better stability of alloy electrodes over prolonged cycling. - Abstract: Sn and Sn–Ni alloy nanoparticles are synthesized readily by co-precipitation method for their applications in Li-ion batteries. It is found that nickel not only affects the phase structure and morphology of the alloy, but also impacts Li–Sn alloying and dealloying behaviors. In Li-ion batteries, the alloy electrodes deliver stronger cycling stability than the pure Sn anode. In tests the former exhibits a final capacity of 228.5 mA h g{sup −1} over 50 cycles, while the latter displays 14.3 mA h g{sup −1}. Smaller current for battery cycles increases capacities of the alloys beyond 408.4 mA h g{sup −1}. The mechanism of enhanced stability of Sn–Ni alloys is examined. Redox reaction characteristics and Li-ion transfer kinetics at these anodes after different cycles are investigated by cyclic voltammetry and electrochemical impedance spectroscopy, which are considered to associate with buffering effects of nickel and structural integrity of electrodes. Li–Sn alloying and dealloying reactions cause volume changes and induce stress that releases in the formation of tiny cracks within the particles. The cracks accelerate side reactions and decelerate charge transport, detrimental to the electrode stability. Nickel cushions the volume variations and reduces the stress and cracks at Sn–Ni alloy anodes to allow them to maintain better electrode integrity and smaller charge resistance, thus yielding their improved Li-ion intercalation stability during long-term cycling.

  10. Speed Control and Coiling Temperature Control of Strip

    Institute of Scientific and Technical Information of China (English)

    CAI Xiao-hui; ZHANG Dian-hua; WANG Guo-dong; LIU Xiang-hua; FAN Lei

    2004-01-01

    Considering the strip speed during controlled laminar cooling on Baosteel 1580 hot strip mill in China, the influence of strip speed fluctuation on coiling temperature control for the tail and "neck" of the strip was analyzed. The optimization strategies were put forward and proved effective in operation.

  11. Excess Production Capacity Squeezes Profits of Brass Strip Enterprises

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>Between 2003 and 2006,under the backdrop of rapid growth of domestic demand for brass strip and soaring copper price,brass strip manufacturers made a fortune.And brass strip manufacturers mushroomed in Zhejiang,Anhui and Jiangsu.Large brass strip manufacturers

  12. Process development of thin strip steel casting

    Energy Technology Data Exchange (ETDEWEB)

    Sussman, R.C.; Williams, R.S.

    1990-12-01

    An important new frontier is being opened in steel processing with the emergence of thin strip casting. Casting steel directly to thin strip has enormous benefits in energy savings by potentially eliminating the need for hot reduction in a hot strip mill. This has been the driving force for numerous current research efforts into the direct strip casting of steel. The US Department of Energy initiated a program to evaluate the development of thin strip casting in the steel industry. In earlier phases of this program, planar flow casting on an experimental caster was studied by a team of engineers from Westinghouse Electric corporation and Armco Inc. A subsequent research program was designed as a fundamental and developmental study of both planar and melt overflow casting processes. This study was arranged as several separate and distinct tasks which were often completed by different teams of researchers. An early task was to design and build a water model to study fluid flow through different designs of planar flow casting nozzles. Another important task was mathematically modeling of melt overflow casting process. A mathematical solidification model for the formation of the strip in the melt overflow process was written. A study of the material and conditioning of casting substrates was made on the small wheel caster using the melt overflow casting process. This report discusses work on the development of thin steel casting.

  13. Anode Sheath Switching in a Carbon Nanotube Arc Plasma

    International Nuclear Information System (INIS)

    The anode ablation rate is investigated as a function of anode diameter for a carbon nanotube arc plasma. It is found that anomalously high ablation occurs for small anode diameters. This result is explained by the formation of a positive anode sheath. The increased ablation rate due to this positive anode sheath could imply greater production rate for carbon nanotubes.

  14. Anode Sheath Switching in a Carbon Nanotube Arc Plasma

    Energy Technology Data Exchange (ETDEWEB)

    Abe Fetterman, Yevgeny Raitses, and Michael Keidar

    2008-04-08

    The anode ablation rate is investigated as a function of anode diameter for a carbon nanotube arc plasma. It is found that anomalously high ablation occurs for small anode diameters. This result is explained by the formation of a positive anode sheath. The increased ablation rate due to this positive anode sheath could imply greater production rate for carbon nanotubes.

  15. Anodic Materials for Electrocatalytic Ozone Generation

    OpenAIRE

    Yun-Hai Wang; Qing-Yun Chen

    2013-01-01

    Ozone has wide applications in various fields. Electrocatalytic ozone generation technology as an alternative method to produce ozone is attractive. Anodic materials have significant effect on the ozone generation efficiency. The research progress on anodic materials for electrocatalytic ozone generation including the cell configuration and mechanism is addressed in this review. The lead dioxide and nickel-antimony-doped tin dioxide anode materials are introduced in detail, including their st...

  16. Novel photoresist stripping technology using steam-water mixture*

    Institute of Scientific and Technical Information of China (English)

    Wang Lei; Hui Yu; Gao Chaoqun; Jing Yupeng

    2011-01-01

    A novel wet vapor photoresist stripping technology is developed as an alternative to dry plasma ashing and wet stripping. Experiments using this technology to strip hard baked SU-8 photoresist, aurum and chromium film are carried out. Then the images of stripping results are shown and the mechanism is analyzed and discussed.The most striking result of this experiment is that the spraying mixture of steam and water droplets can strip photoresist and even metal film with ease.

  17. Modulation of Transmission Spectra of Anodized Alumina Membrane Distributed Bragg Reflector by Controlling Anodization Temperature

    OpenAIRE

    Zheng WenJun; Fei GuangTao; Wang Biao; Zhang Li

    2009-01-01

    Abstract We have successfully prepared anodized alumina membrane distributed Bragg reflector (DBR) using electrochemical anodization method. The transmission peak of this distributed Bragg reflector could be easily and effectively modulated to cover almost any wavelength range of the whole visible spectrum by adjusting anodization temperature.

  18. Modulation of Transmission Spectra of Anodized Alumina Membrane Distributed Bragg Reflector by Controlling Anodization Temperature

    Directory of Open Access Journals (Sweden)

    Zheng WenJun

    2009-01-01

    Full Text Available Abstract We have successfully prepared anodized alumina membrane distributed Bragg reflector (DBR using electrochemical anodization method. The transmission peak of this distributed Bragg reflector could be easily and effectively modulated to cover almost any wavelength range of the whole visible spectrum by adjusting anodization temperature.

  19. EC-FORC: A New Cyclic Voltammetry Based Method for Examining Phase Transitions and Predicting Equilibrium

    CERN Document Server

    Hamad, Ibrahim Abou; Novotny, Mark A; Rikvold, Per Arne

    2007-01-01

    We propose a new, cyclic-voltammetry based experimental technique that can not only differentiate between discontinuous and continuous phase transitions in an adsorbate layer, but also quite accurately recover equilibrium behavior from dynamic analysis of systems with a continuous phase transition. The Electrochemical first-order reversal curve (EC-FORC) diagram for a discontinuous phase transition (nucleation and growth), such as occurs in underpotential deposition, is characterized by a negative region, while such a region does not exist for a continuous phase transition, such as occurs in the electrosorption of Br on Ag(100). Moreover, for systems with a continuous phase transition, the minima of the individual EC-FORCs trace the equilibrium curve, even at very high scan rates. Since obtaining experimental data for the EC-FORC method would require only a simple reprogramming of the potentiostat used in conventional cyclic-voltammetry experiments, we believe that this method has significant potential for ea...

  20. Electrochemical-Voltammetry Behavior of Several Aromatic Aldehydes in Acid Solution

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The electrochemical-voltammetry behavior of vanillin, heliotropin, anisaldehyde on the surface ofPt, Au electrodes in acid solution has been studied by means of the electrochemical cyclic voltammetry method. I was found that the electrochemical processes of them are irreversible on both Pt and Au elec-trodes. The electrochemical activity of vanillin is stronger than heliotropin's and heliotropin's is stronger than, anisaldehyde's on Pt electrode. While the electrochemical activity of anisaldehyde is stronger than heliotropin's and vanillin's is the weakest on Au. The results indicate that when they are used as additives for electroplating, they must be consumptive, and it will improve the leveling ability of plating solution and brightness of the deposition layer.

  1. Characterization of AISI 1005 corrosion films grown under cyclic voltammetry of low sulfide ion concentrations

    International Nuclear Information System (INIS)

    Highlights: •The corrosion of AISI 1005 in sulfide solutions was investigated. •The mechanism of film growth on carbon steel in sulfide solutions was studied. •Film growth was characterized using SEM, EDX, XRD and Mössbauer spectroscopy. •Growth of AISI 1005 corrosion films under cyclic voltammetry. -- Abstract: The mechanism of AISI 1005 corrosion in sulfide ion solutions has been investigated using cyclic voltammetry, electrochemical impedance spectroscopy, X-ray diffraction (XRD) and Mössbauer spectroscopy (MS). The proposed mechanism occurs with the initial formation of oxygenated ferrous species followed by adsorption of HS− species, precipitation of iron monosulfides and their partial conversion to bisulfide iron. This mechanism was demonstrated by XRD results that revealed Fe-O and Fe-S phases and by MS results that detected pyrite as the major proportion (94%) of the iron species in the corrosion product

  2. Detection of food additives by voltammetry at the liquid-liquid interface.

    Science.gov (United States)

    Herzog, Grégoire; Kam, Victor; Berduque, Alfonso; Arrigan, Damien W M

    2008-06-25

    Electrochemistry at the liquid-liquid interface enables the detection of nonredoxactive species with electroanalytical techniques. In this work, the electrochemical behavior of two food additives, aspartame and acesulfame K, was investigated. Both ions were found to undergo ion-transfer voltammetry at the liquid-liquid interface. Differential pulse voltammetry was used for the preparation of calibration curves over the concentration range of 30-350 microM with a detection limit of 30 microM. The standard addition method was applied to the determination of their concentrations in food and beverage samples such as sweeteners and sugar-free beverages. Selective electrochemically modulated liquid-liquid extraction of these species in both laboratory solutions and in beverage samples was also demonstrated. These results indicate the suitability of liquid-liquid electrochemistry as an analytical approach in food analysis. PMID:18512937

  3. Voltametria de onda quadrada. Segunda parte: aplicações Square wave voltammetry. Second part: applications

    Directory of Open Access Journals (Sweden)

    Djenaine de Souza

    2004-10-01

    Full Text Available The aim of this work is to discuss some selected applications of square wave voltammetry published in the last five years. The applications focused here cover several electroanalytical fields such as: determination of pesticides; molecules with biological activity; metals and other environmental pollutants. Special attention is given to the work developed in the Grupo de Materiais Eletroquímicos e Métodos Eletroanalíticos - IQSC - USP concerning the utilization of square wave voltammetry, with different kinds of electrodes, for the determination of pesticides in natural waters and active principles in pharmaceutical formulations. The new methodology is simple, fast and sensitive when compared with the traditional ones such as chromatography and spectrophotometry. The satisfactory results obtained provide alternative procedures for the quality control of drugs and the monitoring of pesticides in natural environments.

  4. Depletive stripping chronopotentiometry : a major step forward in electrochemical stripping techniques for metal ion speciation analysis

    NARCIS (Netherlands)

    Town, R.M.; Leeuwen, van H.P.

    2004-01-01

    A comparative evaluation of the utility of the various modes of stripping chronopotentiometry (SCP) for trace metal speciation analysis is presented in the broad context of stripping voltammetric techniques. The remarkable fundamental advantages of depletive SCP at scanned deposition potential (SSCP

  5. Theory of Square-Wave Voltammetry of Two-Electron Reduction with the Adsorption of Intermediate

    OpenAIRE

    Milivoj Lovrić; Šebojka Komorsky-Lovrić

    2012-01-01

    Thermodynamically unstable intermediate of fast and reversible two-electron electrode reaction can be stabilized by the adsorption to the electrode surface. In square-wave voltammetry of this reaction mechanism, the split response may appear if the electrode surface is not completely covered by the adsorbed intermediate. The dependence of the difference between the net peak potentials of the prepeak and postpeak on the square-wave frequency is analyzed theoretically. This relationship can be ...

  6. Rapid Kinetics and Relative Reactivity of Some Five Membered Aromatic Heterocycles using Hydrodynamic Voltammetry

    OpenAIRE

    S. B. Walke; S. L. Bonde; R. P. Bhadane; V. T. Dangat; B. Jadhav

    2015-01-01

    Kinetics of the bromination of imidazole, pyrazole and thiazole by molecular bromine and N-bromosuccinimide has been studied in aqueous medium. Since the reactions are rapid special technique namely, hydrodyanamic voltammetry has been employed to follow the course of the reactions. These reactions follow second order kinetics. The comparative kinetic data determines the reactivity order for these heterocycles towards the bromination using two different brominating reagents. The study justifie...

  7. Electrochemical Etching of Indium Phosphide Surfaces Studied by Voltammetry and Scanned Probe Microscopes

    OpenAIRE

    Kaneshiro, Chinami; Sato, Taketomo; Hasegawa, Hideki

    1999-01-01

    Using voltammetry, X-ray photoemission spectroscopy (XPS), in situ electrochemical scanning tunneling microscopy (STM), ex situ atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements, electrochemical etching modes for n-InP surfaces were investigated and optimized for uniform and controlled etching in an HCl electrolyte. The voltammograms indicated the presence of active and passive regions. The surfaces obtained in the active region were clean and featureless with ...

  8. Portable Measurement System for Voltammetry and Impedance Spectroscopy. Application for TNT Detection

    OpenAIRE

    Masot Peris, Rafael; Alcañiz Fillol, Miguel; Garcia-Breijo, Eduardo; Olguín Pinatti, Cristian Ariel; Ibáñez Civera, Francisco Javier; Gil Sánchez, Luís

    2012-01-01

    This paper presents the design of a portable low-cost electronic tongue system that includes an electronic equipment based on a 16 bits microcontroller and a software application that runs on a personal computer. The designed system is able to carry out voltammetry and impedance spectroscopy measurements with different electrodes configurations in a single device, allowing the implementation of both techniques in a convenient and easy way. The designed system has been electrically characteriz...

  9. Electrodeposition of Iridium Oxide by Cyclic Voltammetry: Application of Response Surface Methodology

    OpenAIRE

    Kakooei Saeid; Ismaila Mokhtar Che; Ari-Wahjoedia Bambang

    2014-01-01

    The effects of scan rate, temperature, and number of cycles on the coating thickness of IrOX electrodeposited on a stainless steel substrate by cyclic voltammetry were investigated in a statistical system. The central composite design, combined with response surface methodology, was used to study condition of electrodeposition. All fabricated electrodes were characterized using electrochemical methods. Field emission scanning electron microscopy and energy-dispersive X-ray spectroscopy were p...

  10. Porosity Study of Hybrid Silica Mesostructure in Aluminium Oxide Membrane Columnar by Cyclic Voltammetry Method

    Directory of Open Access Journals (Sweden)

    M.N. Jalil

    2011-12-01

    Full Text Available Silica mesostructure has been grown within with a porous aluminium oxide membrane columnar material (hybrid-AOM. This was prepared using a sol-gel technique with Pluronic P123 triblock copolymer as the structure-directing agent and tetraethyl orthosilicate as the inorganic source. The porosity of the hybrid-AOM after ethanol extraction was calculated from the cyclic voltammetry response of a neutral probe (FcMeOH, using Randles-Sevčik equation.

  11. Quantification of tin and lead in binary alloys using voltammetry of immobilized microparticles

    OpenAIRE

    Arjmand Gholenji, Farzin; Adriaens, Annemie

    2011-01-01

    Voltammetry of immobilized microparticles (VMP) has been used in this work for the quantitative determination of tin and lead particles in their binary alloys. Carbon paste electrodes, which contained small amounts of tin and lead or their mixtures, were used as working electrodes and square wave voltammograms of each electrode were recorded. Quantification was performed using optimum experimental conditions, obtained by an experimental design technique. The calibration was made by measuring ...

  12. Supplement to the theory of normal pulse voltammetry and its application to the kinetic study of methanol oxidation on a polycrystalline platinum electrode.

    Science.gov (United States)

    Xu, Weilin; Lu, Tianhong; Liu, Changpeng; Xing, Wei

    2005-04-28

    The theory of normal pulse voltammetry (NPV) for complex multistep multielectron transfer processes on a plane electrode was advanced and applied to the completely irreversible process of methanol oxidation to formic acid in the potential range from 0.3 to 0.8 V versus Ag/AgCl. The kinetic parameters for this process, such as the standard rate constant (k0) and anodic transfer coefficient (alpha) for this irreversible heterogeneous electron transfer process at the electrode/solution interface and apparent diffusion coefficient (D(app)) for the homogeneous charge transfer process within liquid film near the electrode surface, were obtained with NPV theory from analyzing the dependence of current-potential curves upon the sampling times. The results showed that this process is truly a very slow, completely irreversible kinetic process, as k0 is in the order of 10(-9) cm/s for the rate-determining step. The values of k0 and D(app) decreased with the increase of methanol concentration, while alpha was independent of the concentration of methanol and its value was 0.35 +/- 0.05. Theoretical fitting is very consistent with the experimental data. PMID:16851917

  13. Effect of Load Distribution on Strip Crown in Hot Strip Rolling

    Institute of Scientific and Technical Information of China (English)

    Hongshuang DI; Jianzhong XU; Dianyao GONG; Xianghua LIU; Guodong WANG; Xiaoming HE; Liying BA

    2004-01-01

    In order to establish precision model, a software to calculate the strip crown of four-high hot rolling mill was developed by using affecting function method according to the strip crown calculation theory. The effect of work roll diameter, unit width rolling load, roll bending force, work roll crown, initial strip crown and reduction, etc, on load distribution effect rate was simulated by using the software. The results show that the load distribution effect rate increases with the increase of strip width, work roll diameter, unit width rolling load, roll bending force, work roll crown, initial strip crown and reduction. Based on the simulation results, base value of load distribution effect rate and fitting coefficients of six power polynomial of load distribution effect rate modification coefficient were determined considering all of the above parameters. A simplified mathematical model for calculating load distribution effect rate was established.

  14. Study on the adsorptive catalytic voltammetry of aloe-emodin at a carbon paste electrode

    Institute of Scientific and Technical Information of China (English)

    LI; Ju'nan; GAO; Peng; LI; Xiangling; YAN; Zhihong; MAO; Xu

    2005-01-01

    A new catalytic voltammetric method for the determination of anthraqunone medicines at a carbon paste electrode (CPE) was described for the first time. The mechanism of the catalytic reaction was investigated by using linear sweep voltammetry, cyclic voltammetry, constant potential electrolysis and so on. The experiment results indicate that aloe-emodin was efficiently accumulated at a CPE by adsorption. In the following potential scan, aloe-emodin was reduced to homologous anthrahydroquinone compound, then the compound was immediately oxidized to aloe-emodin by the dissolved oxygen, and the aloe-emodin was again reduced at the CPE. As a result, a cyclic catalytic reaction was established. But a reversible redox reaction of aloe-emodin can only be observed at a mercury electrode, no catalytic reaction occurs there. A sensitive catalytic voltammetric peak of aloe-emodin was obtained at about -0.60 V (vs. SCE) in 0.56 mol/L NH3-NH4Cl buffer (pH 8.9). The proposed method was applied to the determination of aloe-emodin in the Radix Rhei with satisfactory results. The determination results were in good agreement with reference values obtained by the HPLC. The adsorptive catalytic voltammetry for the determination of organic compound at CPE, chemically modified electrode and other solid electrodes could be significant in the studies on pharmacology, pharmacodynamics, toxicity of medicine, clinical medicine and biochemistry.

  15. Toward an in situ phosphate sensor in seawater using Square Wave Voltammetry.

    Science.gov (United States)

    Barus, C; Romanytsia, I; Striebig, N; Garçon, V

    2016-11-01

    A Square Wave Voltammetry electrochemical method is proposed to measure phosphate in seawater as pulse techniques offer a higher sensitivity as compared to classical cyclic voltammetry. Chronoamperometry cannot be either adapted for an in situ sensor since this method requires to have controlled convection which will be impossible in a miniaturised sensor. Tests and validation of Square Wave Voltammetry parameters have been performed using an open cell and for the first time with a small volume (<400µL) laboratory prototypes. Two designs of prototypes have been compared. Using high frequency (f=250Hz) allows to obtain a linear behaviour between 0.1 and 1µmolL(-1) with a very low limit of detection of 0.05 µmolL(-1) after 60min of complexation waiting time. In order to obtain a linear regression for a larger concentration range i.e. 0.25-4µmolL(-1), a lower frequency of 2.5Hz is needed. A limit of detection of 0.1µmolL(-1) is obtained in this case after 30min of complexation waiting time for the peak measured at E=0.12V. Changing the position of the molybdenum electrode for the complexation step and moving the detection into another electrochemical cell allow to decrease the reaction time down to 5min. PMID:27591632

  16. Area specific stripping factors for AGS. A method for extracting stripping factors from survey data

    Energy Technology Data Exchange (ETDEWEB)

    Aage, H.K.; Korsbech, U. [Technical Univ. of Denmark (Denmark)

    2006-04-15

    In order to use Airborne Gamma-ray Spectrometry (AGS) for contamination mapping, for source search etc. one must to be able to eliminate the contribution to the spectra from natural radioactivity. This in general is done by a stripping technique. The parameters for performing a stripping have until recently been measured by recording gamma spectra at special calibration sites (pads). This may be cumbersome and the parameters may not be correct when used at low gamma energies for environmental spectra. During 2000-2001 DTU tested with success a new technique for Carborne Gamma-ray Spectrometry (CGS) where the spectra from the surveyed area (or from a similar area) were used for calculating the stripping parameters. It was possible to calculate usable stripping ratios for a number of low energy windows - and weak source signals not detectable by other means were discovered with the ASS technique. In this report it is shown that the ASS technique also works for AGS data, and it has been used for recent Danish AGS tests with point sources. (Check of calibration of AGS parameters.) By using the ASS technique with the Boden data (Barents Rescue) an exercise source was detected that has not been detected by any of the teams during the exercise. The ASS technique therefore seems to be better for search for radiation anomalies than any other method known presently. The experiences also tell that although the stripping can be performed correctly at any altitude there is a variation of the stripping parameters with altitude that has not yet been quite understood. However, even with the oddly variations the stripping worked as expected. It was also observed that one might calculate a single common set of usable stripping factors for all altitudes from the entire data set i.e. some average a, b and c values. When those stripping factors were used the stripping technique still worked well. (au)

  17. Superconducting nano-strip particle detectors

    Science.gov (United States)

    Cristiano, R.; Ejrnaes, M.; Casaburi, A.; Zen, N.; Ohkubo, M.

    2015-12-01

    We review progress in the development and applications of superconducting nano-strip particle detectors. Particle detectors based on superconducting nano-strips stem from the parent devices developed for single photon detection (SSPD) and share with them ultra-fast response times (sub-nanosecond) and the ability to operate at a relatively high temperature (2-5 K) compared with other cryogenic detectors. SSPDs have been used in the detection of electrons, neutral and charged ions, and biological macromolecules; nevertheless, the development of superconducting nano-strip particle detectors has mainly been driven by their use in time-of-flight mass spectrometers (TOF-MSs) where the goal of 100% efficiency at large mass values can be achieved. Special emphasis will be given to this case, reporting on the great progress which has been achieved and which permits us to overcome the limitations of existing mass spectrometers represented by low detection efficiency at large masses and charge/mass ambiguity. Furthermore, such progress could represent a breakthrough in the field. In this review article we will introduce the device concept and detection principle, stressing the peculiarities of the nano-strip particle detector as well as its similarities with photon detectors. The development of parallel strip configuration is introduced and extensively discussed, since it has contributed to the significant progress of TOF-MS applications.

  18. Beam stripping extraction from the VINCY cyclotron

    Directory of Open Access Journals (Sweden)

    Ristić-Đurović Jasna L.

    2006-01-01

    Full Text Available The extraction system of a cyclotron guides an ion beam from a spiral acceleration orbit, through an extraction trajectory, into a high energy transport line. The two methods commonly used to direct an ion into the extraction path are deflection, by the electric field of an electrostatic deflector, and ion stripping, by a thin carbon foil. Compared to the electrostatic deflector system, the stripping extraction provides a fast and easy change of the extracted ion energy and is easier to manufacture operate, and maintain. However, the extraction trajectory and dynamics of an ion beam after stripping are highly dependant on the ion energy and specific charge. Thus, when a multipurpose machine such as the VINCY Cyclotron is concerned, it is far from easy to deliver a variety of ion beams into the same high energy transport line and at the same time preserve a reasonable compactness of the extraction system. The front side stripping extraction system of the VINCY Cyclotron provides high (~70 MeV and mid (~30 MeV energy protons, as well as a number of heavy ions in broad energy ranges. The back side stripping extraction system extracts low energy protons (~18 MeV and enables their simultaneous use with high energy protons at the front side of the machine.

  19. Electrodeposited gold nanoparticles on carbon nanotube-textile: Anode material for glucose alkaline fuel cells

    KAUST Repository

    Pasta, Mauro

    2012-06-01

    In the present paper we propose a new anode material for glucose-gluconate direct oxidation fuel cells prepared by electrodepositing gold nanoparticles onto a conductive textile made by conformally coating single walled carbon nanotubes (SWNT) on a polyester textile substrate. The electrodeposition conditions were optimized in order to achieve a uniform distribution of gold nanoparticles in the 3D porous structure of the textile. On the basis of previously reported studies, the reaction conditions (pH, electrolyte composition and glucose concentration) were tuned in order to achieve the highest oxidation rate, selectively oxidizing glucose to gluconate. The electrochemical characterization was carried out by means of cyclic voltammetry. © 2012 Elsevier B.V. All rights reserved.

  20. Effect of the synthesis method of SnSb anode materials on their electrochemical properties

    Institute of Scientific and Technical Information of China (English)

    Chaoli Yin; Hailei Zhao; Hong Guo; Xianliang Huang; Weihua Qiu

    2007-01-01

    SnSb alloy powders for the anode of Li-ion batteries were synthesized by two kinds of reduction precipitation methods:solution titration and rapid mixing. Two kinds of SnSb alloy powders showed different phase compositions and particle morphologies although the same starting materials were used. The SnSb alloy electrode synthesized by titration exhibits high reversible specific capacity and good cycling stability, whereas the rapid-mixing sample shows high irreversible capacity and fast capacity fade. The broad particle size distribution of SnSb powders synthesized by titration is considered to be responsible for the improvement of cycling stability. The initial charge-discharge efficiency exceeding 80% has been obtained for the titration sample. The electrochemical reaction process of two kinds of synthesized SnSb composite electrodes was characterized by cyclic voltammetry and AC impedance techniques.

  1. Staining of wool using the reaction products of ABTS oxidation by Laccase : synergetic effects of ultrasound and cyclic voltammetry

    OpenAIRE

    Munteanu, Florentina-Daniela; Basto, Carlos; Gübitz, Georg M.; Paulo, Artur Cavaco

    2007-01-01

    The effects of ultrasound on 2,2′-Azinobis(3-ethylbenzothiazoline-6-sulfonate) enzymatic oxidation by laccase (Trametes villosa) has been studied by means of cyclic voltammetry. The reaction was allowed to proceed in the presence of a piece of wool and the coloration depth of the wool fabric was measured by means of K/S. It was observed that cyclic voltammetry is influenced the dyeing process and higher K/S values were obtained when the cyclic voltammetry was combined with the ultrasonic irra...

  2. Effect of Initial Crown on Shape of Hot Rolled Strip

    Institute of Scientific and Technical Information of China (English)

    HU Yu; GONG Dian-yao; JIANG Zheng-yi; XU Jian-zhong; ZHANG Dian-hua; LIU Xiang-hua

    2009-01-01

    Based on the influence coefficient method, the effect of entry strip crown on the shape of hot rolled strip was analyzed using the software of roll elastic deformation simulation. According to the practical condition of a domestic hot roiled strip plant, the unit strip crown change from the first stand to the last stand was calculated when the entry crown of hot strip varies. The calculated result shows that the entry strip crown does not significantly affect the target strip crown at the exit of the last finishing stand in respect to a fixed strip shape control reference (such as bending force). The calculation was analyzed, and the research is helpful in modeling strip shape setup and shape control.

  3. Characterisation of low power readout electronics for a UV microchannel plate detector with cross-strip readout

    Science.gov (United States)

    Pfeifer, M.; Barnstedt, J.; Diebold, S.; Hermanutz, S.; Kalkuhl, C.; Kappelmann, N.; Schanz, T.; Schütze, B.; Werner, K.

    2014-07-01

    Astronomical observations in the ultraviolet (UV) wavelength range between 91 and 300nm are fundamental for the progress in astrophysics. Scientific success of future UV observatories raises the need for technology development in the areas of detectors, optical components, and their coatings. We develop solar blind and photon counting microchannel plate (MCP) UV detectors as a contribution to the progress in UV observation technology. New combinations of materials for the photocathode (see paper No. 9144-111, this volume, for details) as well as a cross-strip (XS) anode, having 64 strips on each layer, are used. Pre-amplification of the charge deposited onto the anode is performed by the Beetle chip designed at the Max-Planck-Institute for Nuclear Physics in Heidelberg for LHCb at CERN. It features 128 pre-amplifiers on one die and provides the analogue output in a four-fold serial stream. This stream is digitised by only four ADCs and is processed in an FPGA. This concept results in a reduced power consumption well below 10W as well as a reduced volume, weight and complexity of the readout electronics compared to existing cross-strip readouts. We developed an electronics prototype assembly and a setup in a vacuum chamber that is similar to the configuration in the final detector. The setup in the chamber is used for the burn-in of the MCPs as well as for tests of the readout electronics prototype assembly incorporating realistic signals. In this paper, information on the XS anodes as well as on the hybrid PCB carrying the Beetle pre-amplifier chip is shown. Details on the readout electronics design as well as details of the setup in the vacuum chamber are presented. An outlook to the next steps in the development process is given.

  4. Ferrocene-Boronic Acid–Fructose Binding Based on Dual-Plate Generator–Collector Voltammetry and Square-Wave Voltammetry

    Science.gov (United States)

    Li, Meng; Xu, Su-Ying; Gross, Andrew J; Hammond, Jules L; Estrela, Pedro; Weber, James; Lacina, Karel; James, Tony D; Marken, Frank

    2015-01-01

    The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 m phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).

  5. An integrated electrochemical device based on immunochromatographic test strip and enzyme labels for sensitive detection of disease-related biomarkers

    Energy Technology Data Exchange (ETDEWEB)

    Zou, Zhexiang; Wang, Jun; Wang, Hua; Li, Yao Q.; Lin, Yuehe

    2012-05-30

    A novel electrochemical biosensing device that integrates an immunochromatographic test strip and a screen-printed electrode (SPE) connected to a portable electrochemical analyzer was presented for rapid, sensitive, and quantitative detection of disease-related biomarker in human blood samples. The principle of the sensor is based on sandwich immunoreactions between a biomarker and a pair of its antibodies on the test strip, followed by highly sensitive square-wave voltammetry (SWV) detection. Horseradish peroxidase (HRP) was used as a signal reporter for electrochemical readout. Hepatitis B surface antigen (HBsAg) was employed as a model protein biomarker to demonstrate the analytical performance of the sensor in this study. Some critical parameters governing the performance of the sensor were investigated in detail. The sensor was further utilized to detect HBsAg in human plasma with an average recovery of 91.3%. In comparison, a colorimetric immunochromatographic test strip assay (ITSA) was also conducted. The result shows that the SWV detection in the electrochemical sensor is much more sensitive for the quantitative determination of HBsAg than the colorimetric detection, indicating that such a sensor is a promising platform for rapid and sensitive point-of-care testing/screening of disease-related biomarkers in a large population

  6. Electrochemical Studies of 1,4-Bis[2-(2-pyridyl)-vinyl] Benzene and 1,4-Bis[2-(4-pyridyl) vinyl] Benzene Laser Dyes via Cyclic Voltammetry, Convolutive Voltammetry and Digital Simulation Methods

    Institute of Scientific and Technical Information of China (English)

    EL-DALY, Samy A; EL-HALLAG,Ibrahirn S; EBEED, Ezeiny M; GHONEIM, Mohamed M

    2009-01-01

    Electrochemical properties of two diolefinic laser dyes namely 1,4-bis[2-(2-pyddyl)-vinyl] benzene (2PVB) and 1,4-bis[2-(4-pyridyl) vinyl] benzene (4PVB) have been investigated using cyclic voltammetry and convolutive voltammetry combined with digital simulation at a platinum electrode in 0.1 mol/L tetrabutyl ammonium perchlo-rate (TBAP) in the two different solvents acetonitrile (CH3CN) and dimethylformamide (DMF). The species were reduced via consumption of two sequential electrons to form radical anion and dianion. In switching the potential to positive direction, the two compounds were oxidized by loss of one electron, which was followed by a fast isomeri-sation process. The electrode reaction pathway and the electrochemical parameters of the investigated compounds were determined using cyclic voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation and convolutive voltammetry methods.

  7. Electrochemical and optical characterizations of anodic porous n-InP(1 0 0) layers

    Energy Technology Data Exchange (ETDEWEB)

    Santinacci, Lionel, E-mail: santinacci@cinam.univ-mrs.f [Institut Lavoisier de Versailles (UMR CNRS 8180), University of Versailles Saint-Quentin, 45 avenue des Etats-Unis, F-78000 Versailles (France); Goncalves, Anne-Marie; Simon, Nathalie; Etcheberry, Arnaud [Institut Lavoisier de Versailles (UMR CNRS 8180), University of Versailles Saint-Quentin, 45 avenue des Etats-Unis, F-78000 Versailles (France)

    2010-12-30

    In this paper, electrochemical and optical characterizations of anodic porous n-InP(1 0 0) are reported. The direct relation between the observed pore morphology and the physical properties is demonstrated using electrochemical methods such as cyclic voltammetry and impedance spectroscopy as well as optical techniques like photocurrent spectroscopy and photoluminescence measurements. An enhancement of the interfacial capacitance, proportional to the anodic charge, is revealed by voltammetry and Mott-Schottky analysis. It is related to the drastic increase of the area of the porous electrode. However, when the porous samples are sufficiently reverse-biased, the capacitance enlargement disappears because the nanosized pore walls are fully depleted and the electroactive area recovers its initial value. Photocurrent spectroscopy and photoluminescence measurements show the porous film behaves like an absorbent layer. This effect is also ascribed to the specific geometry of the space charge layer within the pore walls. A model based on the absorption coefficient and the effective optical path length is thus used to describe the phenomenon. However the model is not sufficient to depict the phenomenon and the charge recombination in the additional surface states created during the pore formation and the long transit time of electrons in the porous matrix are also significant. Additional effects such as the initial enhancement of the photocurrent response and the redshift of the absorption edge of the photocurrent spectra are observed. Inversely, no shift of the photoluminescence peak is detected. However an exponential quenching of the photoluminescence is also attributed to an absorbent behavior of the porous layer.

  8. Ram pressure stripping of tilted galaxies

    CERN Document Server

    Jachym, P; Palous, J; Combes, F

    2009-01-01

    Ram pressure stripping of galaxies in clusters can yield gas deficient disks. Previous numerical simulations based on various approaches suggested that, except for near edge-on disk orientations, the amount of stripping depends very little on the inclination angle. Following our previous study of face-on stripping, we extend the set of parameters with the disk tilt angle and explore in detail the effects of the ram pressure on the interstellar content (ISM) of tilted galaxies that orbit in various environments of clusters, with compact or extended distributions of the intra-cluster medium (ICM). We further study how results of numerical simulations could be estimated analytically. A grid of numerical simulations with varying parameters is produced using the tree/SPH code GADGET with a modified method for calculating the ISM-ICM interaction. These SPH calculations extend the set of existing results obtained from different codes using various numerical techniques. The simulations confirm the general trend of le...

  9. Analysis of 'Coma strip' galaxy redshift catalog

    International Nuclear Information System (INIS)

    We present results of the analysis of a galaxy redshift catalog made at the 6-m telescope by Karachentsev and Kopylov (1990. Mon. Not. R. astr. Soc., 243, 390). The catalog covers a long narrow strip on the sky (10 arcmin by 630) and lists 283 galaxies up to limiting blue magnitude mB = 17.6. The strip goes through the core of Coma cluster and this is called the 'Coma strip' catalog. The catalog is almost two times deeper than the CfA redshift survey and creates the possibility of studying the galaxy distribution on scales of 100-250 Mpc. Due to the small number of galaxies in the catalog, we were able to estimate only very general and stable parameters of the distribution. (author)

  10. Spray forming lead strip. Final report

    Energy Technology Data Exchange (ETDEWEB)

    McHugh, K.

    1996-04-10

    A cooperative research project was conducted between the Idaho National Engineering Laboratory (INEL) and Johnson Controls, Inc. (JCI) to adapt the INEL spray forming process to produce near-net-shape lead alloy strip. The emphasis of the work was to spray form lead strip samples at INEL, using a variety of spray conditions, for characterization at JCI. An existing glove box apparatus was modified at INEL to spray form lead. The main spray forming components were housed inside the glove box. They included a spray nozzle, tundish (crucible), substrate assembly, gas heater and furnaces to heat the nozzle and tundish. To spray form metal strip, liquid metal was pressure-fed at a controlled rate through a series of circular orifices that span the width of the nozzle. There the metal contacted high velocity, high temperature inert gas (nitrogen) which atomized the molten material into fine droplets, entrained the droplets in a directed flow, and deposited them onto glass plates that were swept through the spray plume to form strip samples. In-flight convection cooling of the droplets followed by conduction and convection cooling at the substrate resulted in rapid solidification of the deposit. During operation, the inside of the glove box was purged with an inert gas to limit the effects of in-flight oxidation of the particles and spray-formed strips, as well as to protect personnel from exposure to airborne lead particulate. Remote controls were used to start/stop the spray and control the speed and position of the substrate. In addition, substrate samples were loaded into the substrate translator manually using the gloved side ports of the box. In this way, the glove box remained closed during a series of spray trials, and was opened only when loading the crucible with a lead charge or when removing lead strip samples for shipment to JCI.

  11. Spray Rolling Aluminum Strip for Transportation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Kevin M. McHugh; Y. Lin; Y. Zhou; E. J. Lavernia; J.-P. Delplanque; S. B. Johnson

    2005-02-01

    Spray rolling is a novel strip casting technology in which molten aluminum alloy is atomized and deposited into the roll gap of mill rolls to produce aluminum strip. A combined experimental/modeling approach has been followed in developing this technology with active participation from industry. The feasibility of this technology has been demonstrated at the laboratory scale and it is currently being scaled-up. This paper provides an overview of the process and compares the microstructure and properties of spray-rolled 2124 aluminum alloy with commercial ingot-processed material

  12. Lubrication in strip cold rolling process

    Institute of Scientific and Technical Information of China (English)

    Jianlin Sun; Yonglin Kang; Tianguo Xiao; Jianze Wang

    2004-01-01

    A lubrication model was developed for explaining how to form an oil film in the deformation zone, predicting the film thickness and determining the characteristics of lubrication in the strip rolling process, combined with the knowledge of hydrodythicknesses in the strip cold rolling. Results from the experiment and calculation show that the oil film forming in hydrodynamic lubrication is up to the bit angle and a higher rolling speed or a higher rolling oil viscosity. The mechanism of mechanical entrainment always affects the film thickness that increases with the rolling oil viscosity increasing or the reduction rate decreasing in rolling.

  13. Test strip and method for its use

    International Nuclear Information System (INIS)

    A test strip device is described which is useful in performing binding assays involving antigens, antibodies, hormones, vitamins, metabolites or pharmacological agents. The device is capable of application to analytical methods in which a set of sequential test reactions is involved and in which a minute sample size may be used. This test strip is particularly useful in radioimmunoassays. The use of the device is illustrated in radioimmunoassays for 1) thyroxine in serum, 2) the triiodothyronine binding capacity of serum and 3) folic acid and its analogues in serum. (U.K.)

  14. slice of LEP beamtube with getter strip

    CERN Multimedia

    1989-01-01

    A section of the LEP beam pipe. This is the chamber in which LEP's counter-rotating electron and positron beams travel. It is made of lead-clad aluminium. The beams circulate in the oval cross-section part of the chamber. In the rectangular cross-section part, LEP's innovative getter-strip vacuum pump is installed. After heating to purify the surface of the getter, the strip acts like molecular sticky tape, trapping any stray molecules left behind after the accelerator's traditional vacuum pumps have done their job.

  15. Multi-twist optical Mobius strips

    CERN Document Server

    Freund, Isaac

    2009-01-01

    Circularly polarized Gauss-Laguerre GL(0,0) and GL(0,1) laser beams that cross at their waists at a small angle are shown to generate a quasi-paraxial field that contains an axial line of circular polarization, a C line, surrounded by polarization ellipses whose major and minor axes generate multi-twist Mobius strips with twist numbers that increase with distance from the C point. These Mobius strips are interpreted in terms of Berry's phase for parallel transport of the ellipse axes around the C point.

  16. Asset Stripping in a Mature Market Economy

    DEFF Research Database (Denmark)

    Klarskov Jeppesen, Kim; Møller, Ulrik Gorm

    2011-01-01

    indicates that asset stripping may take place in mature market economies to the extent that perpetrators are able to circumvent the corporate governance system by giving lawyers, public accountants and banks incentives to act less critically towards dubious business transactions. Research limitations...... is to analyse why the asset-stripping schemes occurred in a mature market economy with a strong corporate governance system and a low level of corruption. Design/methodology/approach – The research is conducted as a longitudinal single case study based on documentary research. Findings – The Danish case...

  17. Instrumentation for fast-scan cyclic voltammetry combined with electrophysiology for behavioral experiments in freely moving animals

    OpenAIRE

    Takmakov, Pavel; McKinney, Collin J.; Carelli, Regina M.; Wightman, R Mark

    2011-01-01

    Fast-scan cyclic voltammetry is a unique technique for sampling dopamine concentration in the brain of rodents in vivo in real time. The combination of in vivo voltammetry with single-unit electrophysiological recording from the same microelectrode has proved to be useful in studying the relationship between animal behavior, dopamine release and unit activity. The instrumentation for these experiments described here has two unique features. First, a 2-electrode arrangement implemented for vol...

  18. The Nitrogen-Nitride Anode.

    Energy Technology Data Exchange (ETDEWEB)

    Delnick, Frank M.

    2014-10-01

    Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

  19. Conductive Anodic Filament (CAF) Formation

    Science.gov (United States)

    Caputo, Antonio

    Conductive anodic filament (CAF) is a failure mode in printed wiring boards (PWBs) which occurs under high humidity and high voltage gradient conditions. The filament, a copper salt, grows from anode to cathode along the epoxy-glass interface. Ready and Turbini (2000) identified this copper salt as the Cu 2(OH)3Cl, atacamite compound. This work has investigated the influence of polyethylene glycol (PEG) and polyethylene propylene glycol (PEPG) fluxing agents on the chemical nature of CAF. For coupons processed with PEPG flux, with and without chloride, a copper-chloride containing compound was formed in the polymer matrix. This compound was characterized using x-ray photoelectron spectroscopy (XPS) as CuCl and an electrochemical mechanism for the formation of the chloride-containing CAF has been proposed. For PEG flux, with and without chloride, it has been shown that CAF only formed, but no copper containing compound formed in the matrix. It appears for PEG fluxed coupons, a PEG-Cu-Cl complex forms, binds the available Cu and acts as a barrier to the formation of CuCl in the polymer matrix. Meeker and Lu Valle (1995) have previously proposed that CAF failure is best represented by two competing reactions -- the formation of a copper chloride corrosion compound (now identified as Cu2(OH)3Cl) and the formation of innocuous trapped chlorine compounds. Since no evidence of any trapped chloride compounds has been found, we propose that the formation of CAF is best represented by a single non-reversible reaction. For coupons processed with a high bromide-containing flux, bromide containing CAF was created and characterized using transmission electron microscopy (TEM) to be Cu2(OH)3Br. In addition, a copper-containing compound was formed in the polymer matrix and characterized using XPS as CuBr. An electrochemical mechanism for the formation of bromide-containing CAF has been proposed based on the XPS data.

  20. The CMS silicon strip tracker modules production

    CERN Document Server

    Giorgi, M

    2006-01-01

    To complete the construction of the CMS silicon strip tracker, about 16,000 silicon microstrip detector modules will be required. In order to guarantee the uniform quality of the produced modules and to be able to match the deadlines requested by the CMS collaboration, a semi-industrialized organization has been developed, and the different components are being presented here.

  1. Improved lower bound for online strip packing

    NARCIS (Netherlands)

    Harren, Rolf; Kern, Walter

    2015-01-01

    We study the online strip packing problem and derive an improved lower bound of ρ ≥ 2.589... for the competitive ratio of this problem. The construction is based on modified “Brown-Baker-Katseff sequences” (Brown et al. in Acta Inform. 18:207–225, 1982) using only two types of rectangles. In additio

  2. Nonlinear optical model for strip plasmonic waveguides

    DEFF Research Database (Denmark)

    Lysenko, Oleg; Bache, Morten; Lavrinenko, Andrei

    2016-01-01

    This paper presents a theoretical model of nonlinear optical properties for strip plasmonic waveguides. The particular waveguides geometry that we investigate contains a gold core, adhesion layers, and silicon dioxide cladding. It is shown that the third-order susceptibility of the gold core sign...

  3. Nanoscale Test Strips for Multiplexed Blood Analysis

    Science.gov (United States)

    Chan, Eugene

    2015-01-01

    A critical component of the DNA Medicine Institute's Reusable Handheld Electrolyte and Lab Technology for Humans (rHEALTH) sensor are nanoscale test strips, or nanostrips, that enable multiplexed blood analysis. Nanostrips are conceptually similar to the standard urinalysis test strip, but the strips are shrunk down a billionfold to the microscale. Each nanostrip can have several sensor pads that fluoresce in response to different targets in a sample. The strips carry identification tags that permit differentiation of a specific panel from hundreds of other nanostrip panels during a single measurement session. In Phase I of the project, the company fabricated, tested, and demonstrated functional parathyroid hormone and vitamin D nanostrips for bone metabolism, and thrombin aptamer and immunoglobulin G antibody nanostrips. In Phase II, numerous nanostrips were developed to address key space flight-based medical needs: assessment of bone metabolism, immune response, cardiac status, liver metabolism, and lipid profiles. This unique approach holds genuine promise for space-based portable biodiagnostics and for point-of-care (POC) health monitoring and diagnostics here on Earth.

  4. Characteristics of curcumin using cyclic voltammetry, UV–vis, fluorescence and thermogravimetric analysis

    International Nuclear Information System (INIS)

    Highlights: • Electrooxidation of curcumin was investigated with cyclic voltammetry. • The curcumin is irreversibly oxidized at the platinum electrode in anhydrous media. • Absorbance, fluorescence and thermogravimetric analysis of curcumin was studied. • The HOMO and Mapped Electron Densities were calculated using HyperChem. • Oxidation mechanism for curcumin proposed. -- Abstract: Curcumin, the yellow, primary bioactive component of turmeric, has recently received attention from chemists due its wide range of potential biological applications as an antioxidant, anti-inflammatory, and anti-carcinogenic agent. The electrochemical behaviour of curcumin at a platinum electrode has been studied by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The oxidation of curcumin is an irreversible process that proceeds in two steps in 0.1 M (C4H9)4NClO4 in acetonitrile. The process of oxidation and its kinetics have been investigated. The rate constant, electron transfer coefficient and diffusion coefficients for the electrochemical oxidation of curcumin were determined. A mechanism for the oxidation of curcumin is proposed. The data obtained are consistent with the current literature and suggest that voltammetric studies on mechanically transferred solids may be a convenient method for elucidating the electrochemical oxidation mechanisms of compounds in anhydrous media. Theoretical calculations regarding the optimization of curcumin, electronic properties like highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) were calculated using with HyperChem software by AM1 semi-empirical method. The properties of curcumin in a homogeneous environment were investigated using spectroscopic techniques and thermogravimetric analysis

  5. Refuges, flower strips, biodiversity and agronomic interest.

    Science.gov (United States)

    Roy, Grégory; Wateau, Karine; Legrand, Mickaël; Oste, Sandrine

    2008-01-01

    Several arthropods are natural predators of pests, and they are able to reduce and control their population development. FREDON Nord Pas-de-Calais (Federation Regionate de Defense contre les Organismes Nuisibles = Regional Federation for Pest Control) has begun for a long time to form farmers to the recognition of beneficial arthropods and to show them their usefulness. These beneficial insects or arachnids are present everywhere, in orchards and even in fields which are areas relatively poor in biodiversity. Adults feed in the flower strips instead larvae and some adults feed on preys such as aphids or caterpillars. Most of the time, beneficial insects can regulate pest but sometimes, in agricultural area, they can't make it early enough and efficiently. Their action begin too late and there biodiversity and number are too low. It's possible to enhance their action by manipulating the ecological infrastructures, like sewing flower strips or installing refuges. Flower strips increase the density of natural enemies and make them be present earlier in the field in order to control pests. Refuges permit beneficial's to spend winter on the spot. So they're able to be active and to grow in number earlier. From 2004 to 2007, on the one hand, FREDON Nord Pas-de-Calais has developed a research program. Its purpose was to inventory practices and also tools and means available and to judge the advisability of using such or such beneficial refuge in orchards. On the second hand, it studied the impact in orchard of refuges on population of beneficial's and the difference there were between manufactured refuges and homemade refuges. Interesting prospects were obtained with some of them. Otherwise, since 2003, FREDON has studied flower strips influence on beneficial population and their impact on pest control. In cabbage fields, results of trials have shown that flower strips lead to a reduction of aphid number under acceptable economic level, up to 50 meters from flower strips

  6. Dual Strip-Excited Dielectric Resonator Antenna with Parasitic Strips for Radiation Pattern Reconfigurability

    Directory of Open Access Journals (Sweden)

    M. Kamran Saleem

    2014-01-01

    Full Text Available A novel pattern reconfigurable antenna concept utilizing rectangular dielectric resonator antenna (DRA placed over dielectric substrate backed by a ground plane is presented. A dual strip excitation scheme is utilized and both excitation strips are connected together by means of a 50 Ω microstrip feed network placed over the substrate. The four vertical metallic parasitic strips are placed at corner of DRA each having a corresponding ground pad to provide a short/open circuit between the parasitic strip and antenna ground plane, through which a shift of 90° in antenna radiation pattern in elevation plane is achieved. A fractional bandwidth of approximately 40% at center frequency of 1.6 GHz is achieved. The DRA peak realized gain in whole frequency band of operation is found to be above 4 dB. The antenna configuration along with simulation and measured results are presented.

  7. Magnetic Fe3O4@TiO2 Nanoparticles-based Test Strip Immunosensing Device for Rapid Detection of Phosphorylated Butyrylcholinesterase

    Energy Technology Data Exchange (ETDEWEB)

    Ge, Xiaoxiao; Zhang, Weiying; Lin, Yuehe; Du, Dan

    2013-12-15

    An integrated magnetic nanoparticles-based test-strip immunosensing device was developed for rapid and sensitive quantification of phosphorylated butyrylcholinesterase (BChE), the biomarker of exposure to organophosphous pesticides (OP), in human plasma. In order to overcome the difficulty in scarce availability of OP-specific antibody, here magnetic Fe3O4@TiO2 nanoparticles were used and adsorbed on the test strip through a small magnet inserted in the device to capture target OP-BChE through selective binding between TiO2 and OP moiety. Further recognition was completed by horseradish peroxidase (HRP) and anti-BChE antibody (Ab) co-immobilized gold nanoparticles (GNPs). Their strong affinities among Fe3O4@TiO2, OP-BChE and HRP/Ab-GNPs were characterized by quartz crystal microbalance (QCM), surface plasmon resonance (SPR) and square wave voltammetry (SWV) measurements. After cutting off from test strip, the resulted immunocomplex (HRP/Ab-GNPs/OP-BChE/Fe3O4@TiO2) was measured by SWV using a screen printed electrode under the test zone. Greatly enhanced sensitivity was achieved by introduction of GNPs to link enzyme and antibody at high ratio, which amplifies electrocatalytic signal significantly. Moreover, the use of test strip for fast immunoreactions reduces analytical time remarkably. Coupling with a portable electrochemical detector, the integrated device with advanced nanotechnology displays great promise for sensitive, rapid and in-filed on-site evaluation of OP poisoning.

  8. A one-dimensional stochastic approach to the study of cyclic voltammetry with adsorption effects

    Science.gov (United States)

    Samin, Adib J.

    2016-05-01

    In this study, a one-dimensional stochastic model based on the random walk approach is used to simulate cyclic voltammetry. The model takes into account mass transport, kinetics of the redox reactions, adsorption effects and changes in the morphology of the electrode. The model is shown to display the expected behavior. Furthermore, the model shows consistent qualitative agreement with a finite difference solution. This approach allows for an understanding of phenomena on a microscopic level and may be useful for analyzing qualitative features observed in experimentally recorded signals.

  9. Electrochemical Studies of Betti Base and Its Copper(II) Complex by Cyclic and Elimination Voltammetry

    OpenAIRE

    Shardul Bhatt; Bhavna Trivedi

    2013-01-01

    The electrochemical behavior of Betti base 1-(α-amino benzyl)-2-naphthol (BB) and its copper(II) complex by cyclic and elimination voltammetry (EVLS) is reported in the present study. The cyclic voltammetric studies carried out at a glassy carbon working electrode, Ag/Ag+ reference electrode (0.01 M AgNO3 in acetonitrile) in DCM at 100 mV/sec, 200 mV/sec, and 400 mV/sec scan rates indicated a preceding chemical oxidation of the adsorbed BB species to form an iminium ion followed by formation ...

  10. Linear-sweep voltammetry of a soluble redox couple in a cylindrical electrode

    Science.gov (United States)

    Weidner, John W.

    1991-01-01

    An approach is described for using the linear sweep voltammetry (LSV) technique to study the kinetics of flooded porous electrodes by assuming a porous electrode as a collection of identical noninterconnected cylindrical pores that are filled with electrolyte. This assumption makes possible to study the behavior of this ideal electrode as that of a single pore. Alternatively, for an electrode of a given pore-size distribution, it is possible to predict the performance of different pore sizes and then combine the performance values.

  11. Theory of Square-Wave Voltammetry of Two-Electron Reduction with the Adsorption of Intermediate

    Directory of Open Access Journals (Sweden)

    Milivoj Lovric

    2012-01-01

    Full Text Available Thermodynamically unstable intermediate of fast and reversible two-electron electrode reaction can be stabilized by the adsorption to the electrode surface. In square-wave voltammetry of this reaction mechanism, the split response may appear if the electrode surface is not completely covered by the adsorbed intermediate. The dependence of the difference between the net peak potentials of the prepeak and postpeak on the square-wave frequency is analyzed theoretically. This relationship can be used for the estimation of adsorption constant.

  12. Electrodeposition of Iridium Oxide by Cyclic Voltammetry: Application of Response Surface Methodology

    Directory of Open Access Journals (Sweden)

    Kakooei Saeid

    2014-07-01

    Full Text Available The effects of scan rate, temperature, and number of cycles on the coating thickness of IrOX electrodeposited on a stainless steel substrate by cyclic voltammetry were investigated in a statistical system. The central composite design, combined with response surface methodology, was used to study condition of electrodeposition. All fabricated electrodes were characterized using electrochemical methods. Field emission scanning electron microscopy and energy-dispersive X-ray spectroscopy were performed for IrOX film characterization. Results showed that scan rate significantly affects the thickness of the electrodeposited layer. Also, the number of cycles has a greater effect than temperature on the IrOX thickness.

  13. Rapid Kinetics and Relative Reactivity of Some Five Membered Aromatic Heterocycles using Hydrodynamic Voltammetry

    Directory of Open Access Journals (Sweden)

    S. B. Walke

    2015-12-01

    Full Text Available Kinetics of the bromination of imidazole, pyrazole and thiazole by molecular bromine and N-bromosuccinimide has been studied in aqueous medium. Since the reactions are rapid special technique namely, hydrodyanamic voltammetry has been employed to follow the course of the reactions. These reactions follow second order kinetics. The comparative kinetic data determines the reactivity order for these heterocycles towards the bromination using two different brominating reagents. The study justifies the stereochemical principles ascertaining the relative reactivity of these heterocycles quantitatively using kinetics as an investigational tool.

  14. Feedback Effects in Combined Fast-Scan Cyclic Voltammetry-Scanning Electrochemical Microscopy

    OpenAIRE

    Schrock, Daniel S.; Wipf, David O.; Baur, John E.

    2007-01-01

    Fast-scan cyclic voltammetry at scan rates between 5 and 1000 Vs−1 was performed at the tip of a scanning electrochemical microscope immersed in a solution of redox mediator. The effect of conducting and insulating substrates on the voltammetric signal was investigated as a function of scan rate and tip-substrate distance. It was found that diffusional interactions between the tip and the substrate are greatest at lower scan rates and on the reverse sweep of the voltammogram. At the fastest s...

  15. Characterization of an electrochemical mercury sensor using alternating current, cyclic, square wave and differential pulse voltammetry

    Energy Technology Data Exchange (ETDEWEB)

    Guerreiro, Gabriela V.; Zaitouna, Anita J.; Lai, Rebecca Y., E-mail: rlai2@unl.edu

    2014-01-31

    Graphical abstract: -- Highlights: •An electrochemical Hg(II) sensor based on T–Hg(II)–T sensing motif was fabricated. •A methylene blue-modified DNA probe was used to fabricate the sensor. •Sensor performance was evaluated using ACV, CV, SWV, and DPV. •The sensor behaves as a “signal-off” sensor in ACV and CV. •The sensor behaves as either a “signal-on” or “signal-off” sensor in SWV and DPV. -- Abstract: Here we report the characterization of an electrochemical mercury (Hg{sup 2+}) sensor constructed with a methylene blue (MB)-modified and thymine-containing linear DNA probe. Similar to the linear probe electrochemical DNA sensor, the resultant sensor behaved as a “signal-off” sensor in alternating current voltammetry and cyclic voltammetry. However, depending on the applied frequency or pulse width, the sensor can behave as either a “signal-off” or “signal-on” sensor in square wave voltammetry (SWV) and differential pulse voltammetry (DPV). In SWV, the sensor showed “signal-on” behavior at low frequencies and “signal-off” behavior at high frequencies. In DPV, the sensor showed “signal-off” behavior at short pulse widths and “signal-on” behavior at long pulse widths. Independent of the sensor interrogation technique, the limit of detection was found to be 10 nM, with a linear dynamic range between 10 nM and 500 nM. In addition, the sensor responded to Hg{sup 2+} rather rapidly; majority of the signal change occurred in <20 min. Overall, the sensor retains all the characteristics of this class of sensors; it is reagentless, reusable, sensitive, specific and selective. This study also highlights the feasibility of using a MB-modified probe for real-time sensing of Hg{sup 2+}, which has not been previously reported. More importantly, the observed “switching” behavior in SWV and DPV is potentially generalizable and should be applicable to most sensors in this class of dynamics-based electrochemical biosensors.

  16. SPR imaging combined with cyclic voltammetry for the detection of neural activity

    Directory of Open Access Journals (Sweden)

    Hui Li

    2014-03-01

    Full Text Available Surface plasmon resonance (SPR detects changes in refractive index at a metal-dielectric interface. In this study, SPR imaging (SPRi combined with cyclic voltammetry (CV was applied to detect neural activity in isolated bullfrog sciatic nerves. The neural activities induced by chemical and electrical stimulation led to an SPR response, and the activities were recorded in real time. The activities of different parts of the sciatic nerve were recorded and compared. The results demonstrated that SPR imaging combined with CV is a powerful tool for the investigation of neural activity.

  17. Calculation and Analysis of Temperature Distribution in Hot Rolling Strip

    OpenAIRE

    Kaixiang Peng

    2013-01-01

    Modern steel grades require constant and reproducible production conditions both in the hot strip mill and in the cooling section to achieve constant material properties along the entire strip length and from strip to strip. Calculation of the temperature in final rolling process always utilizes factors such as the work piece's inner organizational structure, plastic deformation, and it's variations of properties and so on, also as well as the physical parameters such as gauge, shape, etc. In...

  18. Voltammetry of uranyl chloride in the LiCl - KCl eutectic; Voltammetrie du chlorure d'uranyle dans l'eutectique LiCl - KC1

    Energy Technology Data Exchange (ETDEWEB)

    Fondanaiche, J.C. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    Spent UO{sub 2} - PuO{sub 2} fuels can be reprocessed in a molten salt media. Uranium dioxide can easily be dissolved as UO{sub 2}Cl{sub 2} in a molten salt bath using chlorine gas. A study of quantitative analysis of an uranyl chloride solution in the LiCl-KCl eutectic at 400 C has been performed here using voltammetry (a large area-graphite indicator electrode has been employed). The precision which is obtained is around 6 per cent for concentrations below 10{sup -2} M. Precision decreases slightly for more concentrated solutions. The study of polarization curves allowed to give a reduction mechanism for the UO{sub 2}{sup ++} ion. For dilute solutions, this reduction proceeds through the UO{sub 2}{sup +} ion. But interpretation of current-potential curves is made difficult by the dismutation reaction of the UO{sub 2} ion and by the fact that the surface of the indicator electrode is not renewed. (author) [French] Le traitement des combustibles a base d'oxydes (UO{sub 2} - PUO{sub 2}) peut etre effectue au moyen des sels fondus. Le bioxyde d'uranium passe aisement en solution sous forme de UO{sub 2}Cl{sub 2} dans un bain de sels fondus par action du chlore. Nous avons etudie ici l'analyse quantitative d'une solution de chlorure d'uranyle dans l'eutectique LiCl - KCl a 400 C par voltammetrie (electrode indicatrice de graphite d'assez grande surface). La precision est d'environ 6 pour cent pour les concentrations inferieures a 10{sup -2} M; elle est legerement moins bonne pour les solutions plus concentrees. L'examen des courbes de polarisation a permis de donner un mecanisme de reduction de l'ion UO{sub 2}: pour les solutions diluees, cette reduction se fait par l'intermediaire de l'ion UO{sub 2}{sup +}. Mais l'interpretation des courbes intensite-potentiel est rendue delicate par la reaction de dismutation de l'ion UO{sub 2}{sup +} et par le fait que la surface de l'electrode indicatrice n

  19. Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes

    Science.gov (United States)

    Vedenyapina, M. D.; Kuznetsov, V. V.; Makhova, N. N.; Vedenyapin, A. A.

    2016-09-01

    The electrochemical corrosion of gold in solutions of 6,6-dimethyl-1,5-diazabicyclo[3.1.0]hexane ( I) and 6-methyl-1,5-diazabicyclo[3.1.0]hexane ( II) on a gold electrode is studied via cyclic voltammetry. It is shown that the galvanostatic electrolysis of weakly basic aqueous solutions of I and II on gold anodes results in the corrosion of Au electrodes, probably with the formation of organic complexes of gold that are reduced to form a gold mirror on the inner surface of an electrochemical cell during electrolysis. A mechanism is proposed for the investigated processes.

  20. Resolution Studies on Silicon Strip Sensors with fine Pitch

    CERN Document Server

    Haensel, S; Dolezal, Z; Dragicevic, M; Drasal, Z; Friedl, M; Hrubec, Josef; Irmler, C; Kiesenhofer, W; Krammer, M; Kvasnicka, P

    2009-01-01

    In June 2008 single-sided silicon strip sensors with 50~$\\mu$m readout pitch were tested in a pion beam at the SPS at CERN. The purpose of the test was to evaluate characteristic detector properties by varying the strip width and the number of intermediate strips. The experimental setup and first results for the spatial resolution are described.

  1. 21 CFR 880.2200 - Liquid crystal forehead temperature strip.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Liquid crystal forehead temperature strip. 880... Personal Use Monitoring Devices § 880.2200 Liquid crystal forehead temperature strip. (a) Identification. A liquid crystal forehead temperature strip is a device applied to the forehead that is used to...

  2. Chemo-mechanical softening during in situ nanoindentation of anodic porous alumina with anodization processing

    OpenAIRE

    Cheng, C; Ngan, AHW

    2013-01-01

    Simultaneous application of mechanical stresses on a material as it undergoes an electrochemical reaction can result in interesting coupling effects between the chemical and mechanical responses of the material. In this work, anodic porous alumina supported on Al is found to exhibit significant softening during in situ nanoindentation with anodization processing. Compared with ex situ nanoindentation without anodization processing, the in situ hardness measured on the alumina is found to be m...

  3. Pyrosequencing Reveals a Core Community of Anodic Bacterial Biofilms in Bioelectrochemical Systems from China.

    Science.gov (United States)

    Xiao, Yong; Zheng, Yue; Wu, Song; Zhang, En-Hua; Chen, Zheng; Liang, Peng; Huang, Xia; Yang, Zhao-Hui; Ng, I-Son; Chen, Bor-Yann; Zhao, Feng

    2015-01-01

    Bioelectrochemical systems (BESs) are promising technologies for energy and product recovery coupled with wastewater treatment, and the core microbial community in electrochemically active biofilm in BESs remains controversy. In the present study, 7 anodic communities from 6 bioelectrochemical systems in 4 labs in southeast, north and south-central of China are explored by 454 pyrosequencing. A total of 251,225 effective sequences are obtained for 7 electrochemically active biofilm samples at 3% cutoff level. While Alpha-, Beta-, and Gamma-proteobacteria are the most abundant classes (averaging 16.0-17.7%), Bacteroidia and Clostridia are the two sub-dominant and commonly shared classes. Six commonly shared genera i.e., Azospira, Azospirillum, Acinetobacter, Bacteroides, Geobacter, Pseudomonas, and Rhodopseudomonas dominate the electrochemically active communities and are defined as core genera. A total of 25 OTUs with average relative abundance >0.5% were selected and designated as core OTUs, and some species relating to these OTUs have been reported electrochemically active. Furthermore, cyclic voltammetry and chronoamperometry tests show that two strains from Acinetobacter guillouiae and Stappia indica, bacteria relate to two core OTUs, are electrochemically active. Using randomly selected bioelectrochemical systems, the study has presented extremely diverse bacterial communities in anodic biofilms, though, we still can suggest some potentially microbes for investigating the electrochemical mechanisms in bioelectrochemical systems. PMID:26733958

  4. Orthorhombic Lithium Titanium Phosphate as an Anode Material for Li-ion Rechargeable Battery

    International Nuclear Information System (INIS)

    Highlights: • Li-rich orthorhombic lithium titanium phosphate (OLTP) has been synthesized via a sol-gel route. • OLTP adopts a different space group from the previously reported rhombohedral lithium titanium phosphate (RLTP) and shows solid-solution charge/discharge curves. • OLTP shows higher Li+ diffusivity and electrical conductivity, which makes it an attractive alternative for RLTP. - Abstract: Rhombohedral lithium titanium phosphate, LiTi2(PO4)3, has been considered a suitable anode material for aqueous lithium-ion batteries. However, the electrochemical behaviors of pure lithium-rich polymorphs have not been described yet even Li-rich phase may show better electrochemical properties than conventional LiTi2(PO4)3 at the expense of somewhat lowered capacity. We have synthesized orthorhombic Li1.5Ti2(PO4)3 (OLTP) and rhombohedral LiTi2(PO4)3 (RLTP) via sol-gel reactions and studied their fundamental electrochemical properties using galvanostatic charge/discharge and cyclic voltammetry (CV). Their feasibility as anode materials in LiFePO4//LixTi2(PO4)3 configurations using aqueous electrolytes were also considered. The faster kinetics of the orthorhombic lithium titanium phosphate in this study were attributed to higher Li+ diffusivity and electrical conductivity, making this material an attractive alternative for conventional rhombohedral LiTi2(PO4)3

  5. Heat-treated stainless steel felt as scalable anode material for bioelectrochemical systems.

    Science.gov (United States)

    Guo, Kun; Soeriyadi, Alexander H; Feng, Huajun; Prévoteau, Antonin; Patil, Sunil A; Gooding, J Justin; Rabaey, Korneel

    2015-11-01

    This work reports a simple and scalable method to convert stainless steel (SS) felt into an effective anode for bioelectrochemical systems (BESs) by means of heat treatment. X-ray photoelectron spectroscopy and cyclic voltammetry elucidated that the heat treatment generated an iron oxide rich layer on the SS felt surface. The iron oxide layer dramatically enhanced the electroactive biofilm formation on SS felt surface in BESs. Consequently, the sustained current densities achieved on the treated electrodes (1 cm(2)) were around 1.5±0.13 mA/cm(2), which was seven times higher than the untreated electrodes (0.22±0.04 mA/cm(2)). To test the scalability of this material, the heat-treated SS felt was scaled up to 150 cm(2) and similar current density (1.5 mA/cm(2)) was achieved on the larger electrode. The low cost, straightforwardness of the treatment, high conductivity and high bioelectrocatalytic performance make heat-treated SS felt a scalable anodic material for BESs.

  6. Durable transition-metal-carbide-supported Pt-Ru anodes for direct methanol fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nishanth, K.G.; Sridhar, P.; Pitchumani, S. [CSIR-Central Electrochemical Research Institute, Madras Unit, CSIR Madras Complex, Chennai (India); Shukla, A.K. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore (India)

    2012-02-15

    Molybdenum carbide (MoC) and tungsten carbide (WC) are synthesized by direct carbonization method. Pt-Ru catalysts supported on MoC, WC, and Vulcan XC-72R are prepared, and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy in conjunction with electrochemistry. Electrochemical activities for the catalysts towards methanol electro-oxidation are studied by cyclic voltammetry. All the electro-catalysts are subjected to accelerated durability test (ADT). The electrochemical activity of carbide-supported electro-catalysts towards methanol electro-oxidation is found to be higher than carbon-supported catalysts before and after ADT. The study suggests that Pt-Ru/MoC and Pt-Ru/WC catalysts are more durable than Pt-Ru/C. Direct methanol fuel cells (DMFCs) with Pt-Ru/MoC and Pt-Ru/WC anodes also exhibit higher performance than the DMFC with Pt-Ru/C anode. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. MgO-decorated few-layered graphene as an anode for li-ion batteries.

    Science.gov (United States)

    Petnikota, Shaikshavali; Rotte, Naresh K; Reddy, M V; Srikanth, Vadali V S S; Chowdari, B V R

    2015-02-01

    Combustion of magnesium in dry ice and a simple subsequent acid treatment step resulted in a MgO-decorated few-layered graphene (FLG) composite that has a specific surface area of 393 m(2)/g and an average pore volume of 0.9 cm(3)/g. As an anode material in Li-ion batteries, the composite exhibited high reversible capacity and excellent cyclic performance in spite of high first-cycle irreversible capacity loss. A reversible capacity as high as 1052 mAh/g was measured during the first cycle. Even at the end of the 60th cycle, more than 83% of the capacity could be retained. Cyclic voltammetry results indicated pseudocapacitance behavior due to electrochemical absorption and desorption of lithium ions onto graphene. An increase in the capacity has been observed during long-term cycling owing to electrochemical exfoliation of graphene sheets. Owing to its good thermal stability and superior cyclic performance with high reversible capacities, MgO-decked FLG can be an excellent alternative to graphite as an anode material in Li-ion batteries, after suitable modifications.

  8. Pyrosequencing reveals a core community of anodic bacterial biofilms in bioelectrochemical systems from China

    Directory of Open Access Journals (Sweden)

    Yong eXiao

    2015-12-01

    Full Text Available Bioelectrochemical systems (BESs are promising technologies for energy and product recovery coupled with wastewater treatment, and the core microbial community in electrochemically active biofilm in BESs remains controversy. In the present study, 7 anodic communities from 6 bioelectrochemical systems in 4 labs in southeast, north and south-central of China are explored by 454 pyrosequencing. A total of 251,225 effective sequences are obtained for 7 electrochemically active biofilm samples at 3% cutoff level. While Alpha-, Beta- and Gamma-proteobacteria are the most abundant classes (averaging 16.0-17.7%, Bacteroidia and Clostridia are the two sub-dominant and commonly shared classes. Six commonly shared genera i.e. Azospira, Azospirillum, Acinetobacter, Bacteroides, Geobacter, Pseudomonas and Rhodopseudomonas dominate the electrochemically active communities and are defined as core genera. A total of 25 OTUs with average relative abundance >0.5% were selected and designated as core OTUs, and some species relating to these OTUs have been reported electrochemically active. Furthermore, cyclic voltammetry and chronoamperometry tests show that two strains from Acinetobacter guillouiae and Stappia indica, bacteria relate to two core OTUs, are electrochemically active. Using randomly selected bioelectrochemical systems, the study presented extremely diverse bacterial communities in anodic biofilms, though, we still can suggest some potential microbes for investigating the electrochemical mechanisms in bioelectrochemical systems.

  9. Technological aspects of development of pixel and strip detectors based on CdTe and CdZnTe

    Energy Technology Data Exchange (ETDEWEB)

    Gostilo, V.; Ivanov, V.; Kostenko, S.; Lisjutin, I.; Loupilov, A.; Nenonen, S.; Sipila, H.; Valpas, K

    2001-03-11

    Current and spectrometrical characteristics, stability in time and reliability of pixel and strip detectors depend on initial material properties, crystal processing quality and contacts manufacture technology. The work presents analysis of current-voltage and spectrometrical characteristics for initial CdTe and CdZnTe crystals applied for pixel and strip detectors manufacture. The crystal surface preparation before contacts manufacture comprises a modified technology. The contacts were made by photolithography with the surface protected by photoresist with further windows lift-off and crystal surface metallization in lifted-off windows. Metal pads were made by gold deposition from chloroauric acid. Thermocompression, ultrasonic and pulse wirebonding, as well as traditional contacts glueing method for CdTe and CdZnTe detectors have been tested for contacts wiring. The pulse wirebonding has revealed the best results. Wiring is made of gold wire with a diameter of 30 {mu}m and is good enough for pixel and strip wirebonding, providing rather low labour-intensiveness for their assembly by standard equipment. The possibility of fabrication of pressing contacts to strip and pixel detectors by Zebra elastomeric connectors has been investigated. The pressing contacts have provided qualitative and reliable electrical contact and signal layout from pixels and strips to readout electronics. Developed technologies were applied in the manufacture of the following CdTe and CdZnTe detectors: 4x4 pixels detector with rectangular pixels 0.65x0.65 mm and pitch 0.75 mm; 4x4 pixels ring miltiple-electrode detector with anode diameter 0.32 mm and pitch 0.75 mm; strip detector with 100 {mu}m width strip and 125 {mu}m pitch. The 4x4 pixels CdZnTe detector has provided at optimal temperature energy resolutions of 808 eV and 1.19 keV at energies of 5.9 and 59.6 keV, respectively. Interstrip resistance between two strips with a distance of 25 {mu}m on detector was 2-8 G{omega}.

  10. Technological aspects of development of pixel and strip detectors based on CdTe and CdZnTe

    International Nuclear Information System (INIS)

    Current and spectrometrical characteristics, stability in time and reliability of pixel and strip detectors depend on initial material properties, crystal processing quality and contacts manufacture technology. The work presents analysis of current-voltage and spectrometrical characteristics for initial CdTe and CdZnTe crystals applied for pixel and strip detectors manufacture. The crystal surface preparation before contacts manufacture comprises a modified technology. The contacts were made by photolithography with the surface protected by photoresist with further windows lift-off and crystal surface metallization in lifted-off windows. Metal pads were made by gold deposition from chloroauric acid. Thermocompression, ultrasonic and pulse wirebonding, as well as traditional contacts glueing method for CdTe and CdZnTe detectors have been tested for contacts wiring. The pulse wirebonding has revealed the best results. Wiring is made of gold wire with a diameter of 30 μm and is good enough for pixel and strip wirebonding, providing rather low labour-intensiveness for their assembly by standard equipment. The possibility of fabrication of pressing contacts to strip and pixel detectors by Zebra elastomeric connectors has been investigated. The pressing contacts have provided qualitative and reliable electrical contact and signal layout from pixels and strips to readout electronics. Developed technologies were applied in the manufacture of the following CdTe and CdZnTe detectors: 4x4 pixels detector with rectangular pixels 0.65x0.65 mm and pitch 0.75 mm; 4x4 pixels ring miltiple-electrode detector with anode diameter 0.32 mm and pitch 0.75 mm; strip detector with 100 μm width strip and 125 μm pitch. The 4x4 pixels CdZnTe detector has provided at optimal temperature energy resolutions of 808 eV and 1.19 keV at energies of 5.9 and 59.6 keV, respectively. Interstrip resistance between two strips with a distance of 25 μm on detector was 2-8 GΩ

  11. Performance and life-time behaviour of NiCu-CGO anodes for the direct electro-oxidation of methane in IT-SOFCs

    Science.gov (United States)

    Sin, A.; Kopnin, E.; Dubitsky, Y.; Zaopo, A.; Aricò, A. S.; La Rosa, D.; Gullo, L. R.; Antonucci, V.

    An anodic cermet of NiCu alloy and gadolinia doped ceria has been investigated for CH 4 electro-oxidation in IT-SOFCs. Polarization curves have been recorded in the temperature range from 650 to 800 °C. A maximum power density of 320 mW cm -2 at 800 °C has been obtained in the presence of dry methane in an electrolyte-supported cell. The electrochemical behaviour during 1300 h operation in dry methane and in the presence of redox-cycles has been investigated at 750 °C; variation of the electrochemical properties during these experiments have been interpreted in terms of anode morphology modifications. The methane cracking process at the anode catalyst has been investigated by analysing the oxidative stripping of deposited carbon species.

  12. Performance and life-time behaviour of NiCu-CGO anodes for the direct electro-oxidation of methane in IT-SOFCs

    Energy Technology Data Exchange (ETDEWEB)

    Sin, A.; Kopnin, E.; Dubitsky, Y.; Zaopo, A. [Pirelli Labs S.p.A., Viale Sarca 222, I-20126 Milan (Italy); Arico, A.S.; La Rosa, D.; Gullo, L.R.; Antonucci, V. [CNR-ITAE, Via Salita Santa Lucia Sopra Contesse 5, I-98125 Messina (Italy)

    2007-01-10

    An anodic cermet of NiCu alloy and gadolinia doped ceria has been investigated for CH{sub 4} electro-oxidation in IT-SOFCs. Polarization curves have been recorded in the temperature range from 650 to 800{sup o}C. A maximum power density of 320mWcm{sup -2} at 800{sup o}C has been obtained in the presence of dry methane in an electrolyte-supported cell. The electrochemical behaviour during 1300h operation in dry methane and in the presence of redox-cycles has been investigated at 750{sup o}C; variation of the electrochemical properties during these experiments have been interpreted in terms of anode morphology modifications. The methane cracking process at the anode catalyst has been investigated by analysing the oxidative stripping of deposited carbon species. (author)

  13. Use of hydrogen peroxide to achieve interference-free stripping voltammetric determination of copper at the bismuth-film electrode

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, Wagner F.; Miguel, Eliane M.; Ramos, Gabriel V. [Department of Chemistry, Pontificia Universidade Catolica do Rio de Janeiro (PUC-RJ), Rio de Janeiro, RJ 22451-900 (Brazil); Cardoso, Carlos E. [Department of Chemistry, Pontificia Universidade Catolica do Rio de Janeiro (PUC-RJ), Rio de Janeiro, RJ 22451-900 (Brazil); Natural and Technological Science Center, Universidade Severino Sombra, Vassouras, RJ 27700-000 (Brazil); Farias, Percio A.M. [Department of Chemistry, Pontificia Universidade Catolica do Rio de Janeiro (PUC-RJ), Rio de Janeiro, RJ 22451-900 (Brazil); Aucelio, Ricardo Q. [Department of Chemistry, Pontificia Universidade Catolica do Rio de Janeiro (PUC-RJ), Rio de Janeiro, RJ 22451-900 (Brazil)], E-mail: aucelior@rdc.puc-rio.br

    2008-09-05

    In this work, a new approach is presented to allow interference-free determination of Cu (II) by stripping voltammetry using the bismuth-film electrode. The addition of hydrogen peroxide to the electroanalytical cell has promoted complete resolution between re-dissolution peaks of Bi (III) and Cu (II). The absence of interference could be evaluated by the correlation coefficient (r > 0.99) between Cu (II) concentration and its shifted current peak (at +212 mV) while achieving a slightly fluctuation of the bismuth current peak at -180 mV. Studies were performed aiming towards the optimum conditions for trace determination of Cu (II) using hydrogen peroxide. The methodology was applied to a real sample (sugarcane spirits) and the results were compared to those from graphite furnace atomic absorption spectrometry. The analytical parameters of merit and the results of the analysis indicated that the analytical methodology could be readily used for trace determination of Cu (II)

  14. Macrokinetic relationships between anodic processes in chlorine electrolysis on ruthenium-titanium oxide anodes

    International Nuclear Information System (INIS)

    Effect of porosity on kinetics of the main (chlorine evolution) and side (oxygen evolution and anodic dissolution of ruthenium dioxide) reactions for chlorine electrolysis conditions has been analyzed. Making allowance for chlorine hydrolysis secondary reaction, the distribution of chlorine concentration, solution pH and current densities of the main and side processes over the porous anode depth, have been found. It is shown that solution acidification in the anode pores due to chlorine hydrolysis can bring about replacement of oxygen evolution and ruthenium dioxide dissolution side reactions toward the porous anode external sides thus affecting its selectivity and corrosion resistance

  15. The Voltammetric Analysis of Selenium Electrodeposition from H2SeO3 Solution on Gold Electrode

    OpenAIRE

    Kowalik R.

    2015-01-01

    The different voltammetry techniques were applied to understand the process of selenium deposition from sulfate solution on gold polycrystalline electrode. By applying the cycling voltammetry with different scan limits as well as the chronoamper-ometry combined with the cathodic and anodic linear stripping voltammetry, the different stages of the deposition of selenium were revealed. It was found that the process of reduction of selenous acid on gold surface exhibits a multistage character. T...

  16. Hydrodynamic voltammetry as a rapid and simple method for evaluating soil enzyme activities.

    Science.gov (United States)

    Sazawa, Kazuto; Kuramitz, Hideki

    2015-03-04

    Soil enzymes play essential roles in catalyzing reactions necessary for nutrient cycling in the biosphere. They are also sensitive indicators of ecosystem stress, therefore their evaluation is very important in assessing soil health and quality. The standard soil enzyme assay method based on spectroscopic detection is a complicated operation that requires the removal of soil particles. The purpose of this study was to develop a new soil enzyme assay based on hydrodynamic electrochemical detection using a rotating disk electrode in a microliter droplet. The activities of enzymes were determined by measuring the electrochemical oxidation of p-aminophenol (PAP), following the enzymatic conversion of substrate-conjugated PAP. The calibration curves of β-galactosidase (β-gal), β-glucosidase (β-glu) and acid phosphatase (AcP) showed good linear correlation after being spiked in soils using chronoamperometry. We also performed electrochemical detection using real soils. Hydrodynamic chronoamperometry can be used to assess the AcP in soils, with a detection time of only 90 s. Linear sweep voltammetry was used to measure the amount of PAP released from β-gal and β-glu by enzymatic reaction after 60 min. For the assessment of soil enzymes, the results of hydrodynamic voltammetry assay compared favorably to those using a standard assay procedure, but this new procedure is more user-friendly, rapid and simple.

  17. Hydrodynamic Voltammetry as a Rapid and Simple Method for Evaluating Soil Enzyme Activities

    Directory of Open Access Journals (Sweden)

    Kazuto Sazawa

    2015-03-01

    Full Text Available Soil enzymes play essential roles in catalyzing reactions necessary for nutrient cycling in the biosphere. They are also sensitive indicators of ecosystem stress, therefore their evaluation is very important in assessing soil health and quality. The standard soil enzyme assay method based on spectroscopic detection is a complicated operation that requires the removal of soil particles. The purpose of this study was to develop a new soil enzyme assay based on hydrodynamic electrochemical detection using a rotating disk electrode in a microliter droplet. The activities of enzymes were determined by measuring the electrochemical oxidation of p-aminophenol (PAP, following the enzymatic conversion of substrate-conjugated PAP. The calibration curves of β-galactosidase (β-gal, β-glucosidase (β-glu and acid phosphatase (AcP showed good linear correlation after being spiked in soils using chronoamperometry. We also performed electrochemical detection using real soils. Hydrodynamic chronoamperometry can be used to assess the AcP in soils, with a detection time of only 90 s. Linear sweep voltammetry was used to measure the amount of PAP released from β-gal and β-glu by enzymatic reaction after 60 min. For the assessment of soil enzymes, the results of hydrodynamic voltammetry assay compared favorably to those using a standard assay procedure, but this new procedure is more user-friendly, rapid and simple.

  18. Investigation of antioxidant capacity of the extracts of bilberry (VACCINUM MYRTILLIS L.) by voltammetry

    Science.gov (United States)

    Vtorushina, A. N.; Nikonova, E. D.

    2016-02-01

    This paper deals with the urgent issue of the search of new drugs based on plant raw materials that have an influence on various stages of oxidation processes occurring in the human body. The aim of this paper is to determine the antioxidant activity of the bilberry extracts that are used in the medicine practice by a cathodic voltammetry method. We consider the influence of water and alcohol bilberry extracts on the process of oxygen electroreduction. From these extracts the most activity relation to the process of cathodic oxygen reduction showed alcohol (40%) bilberry extract. It was also stated that the alcohol extract of bilberry has a greater antioxidant activity than other known antioxidants such as ascorbic acid, glucose, dihydroquercetin. Thus, after consideration of a number of plant objects, we showed the possibility of applying the method of cathodic voltammetry for the determination of total antioxidant activity of plant material and identifying and highlighting the most perspective sources of biologically active substances (BAS), as well as the ability of identifying extractants that fully extract BAS from plant raw materials. The activity data of extracts of plant raw materials gives an opportunity of establishing an effective yield phytopreparation based on bilberry that has an antioxidant effect.

  19. Assessing principal component regression prediction of neurochemicals detected with fast-scan cyclic voltammetry.

    Science.gov (United States)

    Keithley, Richard B; Wightman, R Mark

    2011-06-01

    Principal component regression is a multivariate data analysis approach routinely used to predict neurochemical concentrations from in vivo fast-scan cyclic voltammetry measurements. This mathematical procedure can rapidly be employed with present day computer programming languages. Here, we evaluate several methods that can be used to evaluate and improve multivariate concentration determination. The cyclic voltammetric representation of the calculated regression vector is shown to be a valuable tool in determining whether the calculated multivariate model is chemically appropriate. The use of Cook's distance successfully identified outliers contained within in vivo fast-scan cyclic voltammetry training sets. This work also presents the first direct interpretation of a residual color plot and demonstrated the effect of peak shifts on predicted dopamine concentrations. Finally, separate analyses of smaller increments of a single continuous measurement could not be concatenated without substantial error in the predicted neurochemical concentrations due to electrode drift. Taken together, these tools allow for the construction of more robust multivariate calibration models and provide the first approach to assess the predictive ability of a procedure that is inherently impossible to validate because of the lack of in vivo standards. PMID:21966586

  20. Square wave voltammetry with multivariate calibration tools for determination of eugenol, carvacrol and thymol in honey.

    Science.gov (United States)

    Tonello, Natalia; Moressi, Marcela Beatriz; Robledo, Sebastián Noel; D'Eramo, Fabiana; Marioli, Juan Miguel

    2016-09-01

    The simultaneous determination of eugenol (EU), thymol (Ty) and carvacrol (CA) in honey samples, employing square wave voltammetry (SWV) and chemometrics tools, is informed for the first time. For this purpose, a glassy carbon electrode (GCE) was used as working electrode. The operating conditions and influencing parameters (involving several chemical and instrumental parameters) were first optimized by cyclic voltammetry (CV). Thus, the effects of the scan rate, pH and analyte concentration on the electrochemical response of the above mentioned molecules were studied. The results show that the electrochemical responses of the three compounds are very similar and that the voltammetric traces present a high degree of overlap under all the experimental conditions used in this study. Therefore, two chemometric tools were tested to obtain the multivariate calibration model. One method was the partial least squares regression (PLS-1), which assumes a linear behaviour. The other nonlinear method was an artificial neural network (ANN). In this last case we used a supervised, feed-forward network with Levenberg-Marquardt back propagation training. From the accuracies and precisions analysis between nominal and estimated concentrations calculated by using both methods, it was inferred that the ANN method was a good model to quantify EU, Ty and CA in honey samples. Recovery percentages were between 87% and 104%, except for two samples whose values were 136% and 72%. The analytical methodology was simple, fast and accurate. PMID:27343610

  1. Electrochemical Studies of Betti Base and Its Copper(II Complex by Cyclic and Elimination Voltammetry

    Directory of Open Access Journals (Sweden)

    Shardul Bhatt

    2013-01-01

    Full Text Available The electrochemical behavior of Betti base 1-(α-amino benzyl-2-naphthol (BB and its copper(II complex by cyclic and elimination voltammetry (EVLS is reported in the present study. The cyclic voltammetric studies carried out at a glassy carbon working electrode, Ag/Ag+ reference electrode (0.01 M AgNO3 in acetonitrile in DCM at 100 mV/sec, 200 mV/sec, and 400 mV/sec scan rates indicated a preceding chemical oxidation of the adsorbed BB species to form an iminium ion followed by formation of a carbanion via two-step quasireversible reduction. The suggested reaction mechanism has been supported by the elimination voltammetry. The CV and EVLS studies revealed Cu(IIBB complex to undergo a chemical or a surface reaction before electron transfer from the electrode at −0.49 V to form Cu(IBB species. The oxidation of Cu(IBB species has been observed to be CV silent.

  2. Ultraviolet photoluminescence of porous anodic alumina films

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Photoluminescence (PL) properties of porous anodic alumina (PAA) films prepared by using electrochemical anodization technique in a mixed solution of oxalic and sulfuric acid have been investigated. The PAA films have an intensive ultraviolet PL emission around 350 nm, of which a possible PL mechanism has been proposed. It was found that the incorporated oxalic ions, which could transform into PL centers and exist in the PAA films, are responsible for this ultraviolet PL emission.

  3. Lithium Ion Battery Anode Aging Mechanisms

    Directory of Open Access Journals (Sweden)

    Victor Agubra

    2013-03-01

    Full Text Available Degradation mechanisms such as lithium plating, growth of the passivated surface film layer on the electrodes and loss of both recyclable lithium ions and electrode material adversely affect the longevity of the lithium ion battery. The anode electrode is very vulnerable to these degradation mechanisms. In this paper, the most common aging mechanisms occurring at the anode during the operation of the lithium battery, as well as some approaches for minimizing the degradation are reviewed.

  4. α-Fe2O3 lithium battery anodes by nanocasting strategy from ordered 2D and 3D templates

    International Nuclear Information System (INIS)

    Highlights: • Nanosized α-Fe2O3 lithium battery conversion anodes with tunable morphology. • Nanocasting technique using MCM-41 and MCM-48 silica moulds is adopted. • Textural/morphological characteristics define the electrochemical behaviour. • α-Fe2O3 replica of MCM-41 exhibits stable capacity (∼300 mA h g−1) after 100 cycles. • α-Fe2O3 replica of MCM-41 shows promising prospects as high-capacity Li-ion battery anode. - Abstract: Nanocasting strategy is here proposed as effective approach to tune structure and size of α-Fe2O3 active nanoparticles as a promising anode material for Li-ion cells. MCM-41 and MCM-48 silicas, presenting hexagonal 2D and cubic 3D symmetry, respectively, and regular pore diameter of about 4 nm are selected as moulds. The structural–morphological and electrochemical characteristics are assessed by X-ray diffraction, transmission electron microscopy, N2 physisorption at 77 K, cyclic voltammetry and galvanostatic discharge/charge cycling. It is here demonstrated that structural–morphological features change accordingly to the template used and careful control of the texture/particle characteristics is likely a fundamental variable noticeably affecting the cycling behaviour

  5. Anodic oxides on a beta type Nb-Ti alloy and their characterization by electrochemical impedance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Woldemedhin, Michael Teka; Hassel, Achim Walter [Max Planck Institut fuer Eisenforschung GmbH, Duesseldorf (Germany); Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University, Linz (Austria); Raabe, Dierk [Max Planck Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    2010-04-15

    Anodic oxides were grown on the surface of an electropolished (Ti-30 at% Nb) beta-titanium ({beta}-Ti) alloy by cyclic voltammetry. The scan rate was 100 mV s{sup -1} between 0 and 8 V in increments of l V in an acetate buffer of pH 6.0. Electrochemical impedance spectroscopy was carried out right after each anodic oxide growth increment to study the electronic properties of the oxide/electrolyte interface in a wide frequency range from 100 kHz to 10 MHz with an AC perturbation voltage of 10 mV. A film formation factor of 2.4 nm V{sup -1} was found and a relative permittivity number (dielectric constant) of 42.4 was determined for the oxide film formed. Mott-Schottky analysis on a potentiostatically formed 7 nm thick oxide film was performed to assess the semiconducting properties of the mixed anodic oxide grown on the alloy. A flat band potential of -0.47 V (standard hydrogen electrode, SHE) was determined, connected to a donor density of 8.2 x 10{sup 17} cm{sup -3}. {beta}-Ti being highly isotropic in terms of mechanical properties should be superior to the stiffer {alpha}-Ti compound. Its application, however, requires a passivation behaviour comparable or better than {alpha}-Ti which in fact is found. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  6. Electrochemical degradation of Reactive Brilliant Red K-2BP on Ti/RuTiIrSnMn oxide anode in a batch cell

    Directory of Open Access Journals (Sweden)

    LUO JIANCHENG

    2012-11-01

    Full Text Available Electrochemical degradation of Reactive Brilliant Red K-2BP on Ti/RuTiIrSnMn oxide anode in chloride containing solution was investigated by voltammetry and electrolysis in a batch cell. It is found that the degradation mechanism of K-2BP on Ti/RuTiIrSnMn oxide anode involves an indirect electrocatalytic oxidation, in which K-2BP is oxidized by the electrochemically generated active chlorine. This degradation reaction follows pseudo-first order reaction kinetics. Ti/RuTiIrSnMn oxide exhibits excellent electrocata­lytic activity toward the generation of active chlorine from chloride. Hence, K-2BP can be electrochemically degraded effectively in chloride containing solution. The decolorization efficiency was found to increase with the decrease in pH and with the increase in current density, NaCl concentration, temperature, and flow rate of the solution.

  7. Microflora cultivable from minocycline strips placed in persisting periodontal pockets

    OpenAIRE

    Leung, WK; Jin, L; Yau, JYY; Q. Sun; Corbet, EF

    2005-01-01

    The microflora that develops on minocycline strips, used as an adjunct in non-surgical periodontal therapy was studied. Minocycline (1.4 mg in polycaprolactone vehicle) and control strips were applied into all residual pockets (PD ≥ 5 mm, ≥2 pockets/subject) of patients with chronic periodontitis 1 month after a course of non-surgical periodontal therapy. Strips were inserted and retained for 3 days, changed to new strips for 3 more days and then removed. Strips were recovered from 14 (eight ...

  8. Shape Setup System for 1700 Hot Strip Mill

    Institute of Scientific and Technical Information of China (English)

    GUO Zhong-feng; XU Jian-zhong; LI Chang-sheng; LIU Xiang-hua

    2007-01-01

    Shape setup (SSU) system is the core technology for hot strip mill (HSM). A precise SSU system was used to improve the strip quality for HSM. The function of SSU, setup, and feedback was introduced. The main mathematical models of roll gap profile and longitudinal strain difference are set up. Strip profile allocation strategy was researched according to the SSU system of a domestic 1 700 mm HSM. The SSU system was put into practical use and the measurement results showed that strip flatness variation and strip profile variation could be controlled in target scope.

  9. Mechanics of Thin Strip Steering in Hot Rolling

    Science.gov (United States)

    Jiang, Zhengyi; Tieu, Kiet A.

    2004-06-01

    The hot rolling of thin strip can result in several problems in hot rolling, for instance, the control of strip steering, strip shape and flatness and surface roughness etc. Therefore, the hot rolling of thin strip brings out a requirement of innovative technologies such as the extended control of shape and flatness, steering control and reduction of load by roll gap lubrication. In this paper, the authors focus on the analysis of thin strip snaking movement, as well as solve the related problems such as the shape and flatness due to a larger reduction applied when the strip is thinner. A finite element method was used to simulate this nonsymmetricity rolling considering the non-uniform reduction along the strip width. The calculated spread is compared with the measured values obtained from the rolling mill in laboratory and the friction effect is also discussed.

  10. Antenna with distributed strip and integrated electronic components

    Science.gov (United States)

    Rodenbeck, Christopher T.; Payne, Jason A.; Ottesen, Cory W.

    2008-08-05

    An antenna comprises electrical conductors arranged to form a radiating element including a folded line configuration and a distributed strip configuration, where the radiating element can be in proximity to a ground conductor and/or arranged as a dipole. Embodiments of the antenna include conductor patterns formed on a printed wiring board, having a ground plane, spacedly adjacent to and coplanar with the radiating element. An antenna can comprise a distributed strip patterned on a printed wiring board, integrated with electronic components mounted on top of or below the distributed strip, and substantially within the extents of the distributed strip. Mounting of electronic components on top of or below the distributed strip has little effect on the performance of the antenna, and allows for realizing the combination of the antenna and integrated components in a compact form. An embodiment of the invention comprises an antenna including a distributed strip, integrated with a battery mounted on the distributed strip.

  11. The STAR Silicon Strip Detector (SSD)

    CERN Document Server

    Arnold, L; Bonnet, D; Boucham, A; Bouvier, S; Castillo, J; Coffin, J P; Drancourt, C; Erazmus, B; Gaudichet, L; Germain, M; Gojak, C; Grabski, J; Guilloux, G; Guedon, M; Hippolyte, B; Janik, M; Kisiel, A; Kuhn, C; Lakehal-Ayat, L; Lefèvre, F; Le Moal, C; Leszczynski, P; Lutz, Jean Robert; Maliszewski, A; Martin, L; Milletto, T; Pawlak, T; Peryt, W; Pluta, J; Przewlocki, M; Radomski, S; Ravel, O; Renard, C; Renault, G; Rigalleau, L M; Roy, C; Roy, D; Suire, C; Szarwas, P; Tarchini, A

    2003-01-01

    The STAR Silicon Strip Detector (SSD) completes the three layers of the Silicon Vertex Tracker (SVT) to make an inner tracking system located inside the Time Projection Chamber (TPC). This additional fourth layer provides two dimensional hit position and energy loss measurements for charged particles, improving the extrapolation of TPC tracks through SVT hits. To match the high multiplicity of central Au+Au collisions at RHIC the double sided silicon strip technology was chosen which makes the SSD a half million channels detector. Dedicated electronics have been designed for both readout and control. Also a novel technique of bonding, the Tape Automated Bonding (TAB), was used to fullfill the large number of bounds to be done. All aspects of the SSD are shortly described here and test performances of produced detection modules as well as simulated results on hit reconstruction are given.

  12. Electron capture by highly stripped ions

    International Nuclear Information System (INIS)

    This review describes theories of electron capture suitable for the description of rearrangement collisions between atomic hydrogen and completely stripped projectiles with charge greater than unity. The region of impact velocity considered lies between 0.05 and 3 au, which is of technological importance in fusion power devices. The semiclassical, impact parameter formalism is discussed and the use of atomic expansions at medium impact velocity is described. Experimental results for both completely and partially stripped projectiles are reviewed. The use of a molecular basis at low energy, and the role of pseudocrossings peculiar to the two centre Coulomb interaction are described. Finally, purely classical techniques, in which the electron wavefunction is represented by an ensemble of Kepler orbits are considered. The review was completed in February 1981. (author)

  13. The extent of the stop coannihilation strip

    Energy Technology Data Exchange (ETDEWEB)

    Ellis, John [King' s College London, Theoretical Particle Physics and Cosmology Group, Department of Physics, London (United Kingdom); CERN, Theory Division, Geneva 23 (Switzerland); Olive, Keith A. [University of Minnesota, School of Physics and Astronomy, Minneapolis, MN (United States); University of Minnesota, William I. Fine Theoretical Physics Institute, School of Physics and Astronomy, Minneapolis, MN (United States); Zheng, Jiaming [University of Minnesota, School of Physics and Astronomy, Minneapolis, MN (United States)

    2014-07-15

    Many supersymmetric models such as the constrained minimal supersymmetric extension of the Standard Model (CMSSM) feature a strip in parameter space where the lightest neutralino χ is identified as the lightest supersymmetric particle, the lighter stop squark t{sub 1} is the next-to-lightest supersymmetric particle (NLSP), and the relic χ cold darkmatter density is brought into the range allowed by astrophysics and cosmology by coannihilation with the lighter stop squark t{sub 1} NLSP. We calculate the stop coannihilation strip in the CMSSM, incorporating Sommerfeld enhancement effects, and we explore the relevant phenomenological constraints and phenomenological signatures. In particular, we show that the t{sub 1} may weigh several TeV, and its lifetime may be in the nanosecond range, features that are more general than the specific CMSSM scenarios that we study in this paper. (orig.)

  14. Operation of a Batch Stripping Distillation Column

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A stripping batch distillation column is preferred when the amount of the light component in the feed is small and the products are to be recovered at high purity. The operation modes of a batch stripping are believed to be the same as those of a rectifier. However, the control system of a stripper is different. In this paper, we explore three different control methods with Hysys (Hyprotech Ltd. 1997) for a batch stripper. The main difference is the control scheme for reboiler liquid level: (a) controlled by reflux flow; (b) controlled by reboiler heat duty; (c) controlled by bottom product flow. The main characteristics of operating a batch stripper with different control scheme are presented in this paper. Guidelines are provided for the startup of a batch stripper, the effects of somecontrol tuning parameters on the column performance are discussed.

  15. Frequency dependent magnetization of superconductor strip

    Energy Technology Data Exchange (ETDEWEB)

    Thakur, Kailash Prasad [Landcare Research, Palmerston North (New Zealand); Raj, Ashish [Computer Science in Radiology, Weill Medical College, Cornell University, NY (United States); Brandt, Ernst Helmut [Max-Planck-Institut fuer Metallforschung, POB 800665, D-70506 Stuttgart (Germany); Sastry, Pamidi V P S S, E-mail: thakurk@landcareresearch.co.nz, E-mail: asr2004@med.cornell.edu, E-mail: ehb@mf.mpg.de, E-mail: pamidi@caps.fsu.edu [Center for Advanced Power Systems, Florida State University, Tallahassee, FL 32310 (United States)

    2011-04-15

    The frequency dependence of magnetic ac loss of thin superconductor strip subjected to an ac magnetic field perpendicular to the surface of the strip is investigated by incorporating a flux creep model into the critical state model of Brandt and Indenbom. It is found that the reduced ac loss exhibits a maximum value at a frequency f{sub m}, which is a rapidly varying function of the applied ac magnetic field. At low magnetic field, f{sub m} becomes zero, and ac loss decreases with frequency as a power law ({approx}f{sup -2/n}). Whereas at high magnetic field f{sub m} becomes infinite and ac loss increases with frequency, still following the power law ({approx}f{sup 1/n}). The analytical results are substantiated with experimental data and the results of a 2D finite element simulation.

  16. Stage- vs. Channel-strip Metaphor

    DEFF Research Database (Denmark)

    Gelineck, Steven; Korsgaard, Dannie Michael; Büchert, Morten

    2015-01-01

    This study compares the stage metaphor and the channel strip metaphor in terms of performance. Traditionally, music mixing consoles employ a channels strip control metaphor for adjusting parameters such as volume and panning of each track. An alternative control metaphor, the so-called stage...... metaphor lets the user adjust volume and panning by positioning tracks relative to a virtual listening position. In this study test participants are given the task to adjust volume and panning of one channel (in mixes consisting of three channels) in order to replicate a series of simple pre-rendered mixes....... They do this using (1) a small physical mixing controller and (2) using an iPad app, which implements a simple stage metaphor interface. We measure how accurately they are able to replicate mixes in terms of volume and panning and how fast they are at doing so. Results reveal that performance...

  17. PRESUPPOSITIONS AND IMPLICATURES IN COMIC STRIPS

    Directory of Open Access Journals (Sweden)

    Ienneke Indra Dewi

    2008-05-01

    Full Text Available Article aimed to find out the role of presuppositions, implicatures, as well as to see the maxims violated or flouted in the comic strips i.e. to whether there is a miscommunication among the characters in the comic strips. Data were taken from the three comics, those are Peanuts, Andy, and Tintin, and were analysed based on the pattern that the sender made a presupposition before transferring information and the receiver would try to get the implied message. The results show that presuppositions and implicatures are much influenced by the background knowledge. The more the speaker and hearer know each other’s background, the better presuppositions and implicatures they make and finally, the less miscommunication occurred.

  18. Strip-till seeder for sugar beets

    Directory of Open Access Journals (Sweden)

    Peter Schulze Lammers

    2014-06-01

    Full Text Available Strip-till save costs by reducing tillage on the area of sugar beet rows only. The seeding system is characterized by a deep loosening of soil with a tine combined with a share and by following tools generating fine-grained soil as seed bed. In cooperation with the Kverneland company group Soest/Germany a strip tiller combined with precision seeder was designed and tested in field experiments. Tilling and seeding was performed in one path on fields with straw and mustard mulch. Even the plant development was slower as compared to conventional sawn sugar beets the yield was on equivalent level. Further field experiments are planned to attest constant yield, cost and energy efficiency of the seeding system.

  19. Coiling Temperature Control in Hot Strip Mill

    Science.gov (United States)

    Imanari, Hiroyuki; Fujiyama, Hiroaki

    Coiling temperature is one of the most significant factors in products of hot strip mill to determine material properties such as strength, toughness of steel, so it is very important to achieve accurate coiling temperature control (CTC). Usually there are a few pyrometers on the run out table in hot strip mill, therefore temperature model and its adapting system have large influences on the accuracy of CTC. Also unscheduled change of rolling speed has a bad effect to keep coiling temperature as its target. Newly developed CTC system is able to get very accurate coiling temperature against uncertain factors and disturbances by adopting easily identified temperature model, learning method and dynamic set up function. The features of the CTC system are discussed with actual data, and the effectiveness of the system is shown by actual control results.

  20. Development of Silicon Multi-strip Detector

    Institute of Scientific and Technical Information of China (English)

    TanJilian; JinGenming; WangHongwei; YuanXiaohua; DuanLiming; LiSonglin; LuZiwei; XuHushan; NingBaojun; TianDayu; WangWei; ZhangLu

    2003-01-01

    Position sensitive detector is very important for nuclear physics experiment. There several techniques can be used to fabricate position sensitive detector, for example, Si-surface barrier method, diffusion method, ion implantation and planar process etc. Among all the techniques mentioned above planar process is the best one. We have developed batch of position sensitive detector -- silicon multi-strip detector by using planar process.

  1. Transparent Helium in Stripped Envelope Supernovae

    OpenAIRE

    Piro, Anthony L.; Morozova, Viktoriya S.

    2014-01-01

    Using simple arguments based on photometric light curves and velocity evolution, we propose that some stripped envelope supernovae (SNe) show signs that a significant fraction of their helium is effectively transparent. The main pieces of evidence are the relatively low velocities with little velocity evolution, as are expected deep inside an exploding star, along with temperatures that are too low to ionize helium. This means that the helium should not contribute to the shaping of the main S...

  2. Hot Strip Laminar Cooling Control Model

    Institute of Scientific and Technical Information of China (English)

    WANG Jun; WANG Guo-dong; LIU Xiang-hua

    2004-01-01

    The control model of laminar cooling system for hot strip, including air-cooling model, water-cooling model, temperature distribution model along thickness direction, feedforward control model, feedback control model and self-learning model, was introduced. PID arithmetic and Smith predictor controller were applied to feedback control. The sample of model parameter classification was given. The calculation process was shown by flow chart. The model has been proved to be simple, effective and of high precision.

  3. Mastering Interproximal Stripping: With Innovations in Slenderization

    OpenAIRE

    Sharma, Narendra Shriram; Shrivastav, Sunita S; Hazarey, Pushpa V

    2012-01-01

    ABSTRACT Crowding and irregularity remain a consistent problem for children. Management of space problems continues to play an important role in a dental practice. It also represents an area of major interaction between the primary provider and the specialists. Proximal stripping is routinely carried out to avoid extraction in borderline cases where space discrepancy is less and in cases where there is a discrepancy between the mesio- distal width of maxillary and mandibular teeth to satisfy ...

  4. Multitwist optical Möbius strips.

    Science.gov (United States)

    Freund, Isaac

    2010-01-15

    Circularly polarized Gauss-Laguerre GL00 and GL01 laser beams that cross at their waists at a small angle are shown to generate a quasi-paraxial field that contains a line of circular polarization, a C line, surrounded by polarization ellipses whose major and minor axes generate multitwist Möbius strips with twist numbers that increase with the distance from the C point.

  5. Process Simulation Analysis of HF Stripping

    OpenAIRE

    Thaer A. Abdulla

    2013-01-01

       HYSYS process simulator is used for the analysis of existing HF stripping column in LAB plant (Arab Detergent Company, Baiji-Iraq). Simulated column performance and profiles curves are constructed. The variables considered are the thermodynamic model option, bottom temperature, feed temperature, and column profiles for the temperature, vapor flow rate, liquid flow rate and composition. The five thermodynamic models options used (Margules, UNIQUAC, van laar, Antoine, and Zudkevitch-Joffee),...

  6. A high dynamic Micro Strips Ionization Chamber featuring Embedded Multi DSP Processing

    CERN Document Server

    Voltolina, Francesco; Carrato, Sergio; 10.1109/NSSMIC.2004.1466924

    2010-01-01

    An X-ray detector will be presented that is the combination of a segmented ionization chamber featuring one-dimensional spatial resolution integrated with an intelligent ADC front-end, multi DSP processing and embedded PC platform. This detector is optimized to fan beam geometry with an active area of 192 mm (horizontal) and a vertical acceptance of 6 mm. Spatial resolution is obtained by subdividing the anode into readout strips, having pitch of 150 micrometers, which are connected to 20 custom made integrating VLSI chips (each capable of 64-channel read-out and multiplexing) and read out by 14 bits 10 MHz ADCs and fast adaptive PGAs into DSP boards. A bandwidth reaching 3.2Gbit/s of raw data, generated from the real time sampling of the 1280 micro strips, is cascaded processed with FPGA and DSP to allow data compression resulting in several days of uninterrupted acquisition capability. Fast acquisition rates reaching 10 kHz are allowed due to the MicroCAT structure utilized not only as a shielding grid in i...

  7. Small-Strip Thin Gap Chambers for the Muon Spectrometer Upgrade of the ATLAS Experiment

    CERN Document Server

    Perez Codina, Estel; The ATLAS collaboration

    2015-01-01

    For the forthcoming Phase-I upgrade to the LHC (2018/19), the first station of the ATLAS muon end-cap system, Small Wheel, needs to be replaced. The New Small Wheel (NSW) will have to operate in a high background radiation region while reconstructing muon tracks with high precision and providing information for the Level-1 trigger. In particular, the precision reconstruction of tracks requires a spatial resolution of about 100 μm, and the Level-1 trigger track segments have to be reconstructed with an angular resolution of approximately 1 mrad. The NSWs consist of eight layers each of Micromegas and small-strip Thin Gap Chambers (sTGC), both providing trigger and tracking capabilities. The single sTGC planes of a quadruplet consists of an anode layer of 50μm gold plated tungsten wire sandwiched between two resistive cathode layers. Behind one of the resistive cathode layers, a PCB with precise machined strips (thus the name sTGC) spaced every 3.2mm allows to achieve a position resolution that ranges from 70...

  8. Self-recovering superconducting strip detectors

    International Nuclear Information System (INIS)

    Using a 1.8 μm wide superconducting strip made of granular tungsten, we have observed self-recovering pulses when the detector is irradiated with a 55Fe 6 keV X-rays source. For low values of the bias current (i.e. Ibb=1.5K) the superconducting state is recovered in 10--50 ns giving voltage pulses across the strip of few hundred μv in amplitude. At high bias currents the detector did not self-recover and a constant counting efficiency has measured at different operating temperatures. There are good indications that this high counting rate can be extended to all the reduced bias currents where the detector is able to reset itself after every switch. The current threshold between collapsing and propagating switches and the time evolution of the voltage pulses can be described using a thermal propagation model developed in previous works. The ability of detectors to automatically recover the superconducting state in a short period of time after sensing a particle is encouraging in the feasibility study of fast superconducting microvertex detectors and also confirm the potential application of superconducting strips as high fast resolution X-rays detectors

  9. Multiple Electron Stripping of Heavy Ion Beams

    International Nuclear Information System (INIS)

    One approach being explored as a route to practical fusion energy uses heavy ion beams focused on an indirect drive target. Such beams will lose electrons while passing through background gas in the target chamber, and therefore it is necessary to assess the rate at which the charge state of the incident beam evolves on the way to the target. Accelerators designed primarily for nuclear physics or high energy physics experiments utilize ion sources that generate highly stripped ions in order to achieve high energies economically. As a result, accelerators capable of producing heavy ion beams of 10 to 40 Mev/amu with charge state 1 currently do not exist. Hence, the stripping cross-sections used to model the performance of heavy ion fusion driver beams have, up to now, been based upon theoretical calculations. We have investigated experimentally the stripping of 3.4 Mev/amu Kr 7+ and Xe +11 in N2; 10.2 MeV/amu Ar +6 in He, N2, Ar and Xe; 19 MeV/amu Ar +8 in He, N2, Ar and Xe; 30 MeV He 1 + in He, N2, Ar and Xe; and 38 MeV/amu N +6 in He, N2, Ar and Xe. The results of these measurements are compared with the theoretical calculations to assess their applicability over a wide range of parameters

  10. Bacterial Community Analysis, New Exoelectrogen Isolation and Enhanced Performance of Microbial Electrochemical Systems Using Nano-Decorated Anodes

    Science.gov (United States)

    Xu, Shoutao

    Microbial electrochemical systems (MESs) have attracted much research attention in recent years due to their promising applications in renewable energy generation, bioremediation, and wastewater treatment. In a MES, microorganisms interact with electrodes via electrons, catalyzing oxidation and reduction reactions at the anode and the cathode. The bacterial community of a high power mixed consortium MESs (maximum power density is 6.5W/m2) was analyzed by using denature gradient gel electrophoresis (DGGE) and 16S DNA clone library methods. The bacterial DGGE profiles were relatively complex (more than 10 bands) but only three brightly dominant bands in DGGE results. These results indicated there are three dominant bacterial species in mixed consortium MFCs. The 16S DNA clone library method results revealed that the predominant bacterial species in mixed culture is Geobacter sp (66%), Arcobacter sp and Citrobacter sp. These three bacterial species reached to 88% of total bacterial species. This result is consistent with the DGGE result which showed that three bright bands represented three dominant bacterial species. Exoelectrogenic bacterial strain SX-1 was isolated from a mediator-less microbial fuel cell by conventional plating techniques with ferric citrate as electron acceptor under anaerobic conditions. Phylogenetic analysis of the 16S rDNA sequence revealed that it was related to the members of Citrobacter genus with Citrobacter sp. sdy-48 being the most closely related species. The bacterial strain SX-1 produced electricity from citrate, acetate, glucose, sucrose, glycerol, and lactose in MFCs with the highest current density of 205 mA/m2 generated from citrate. Cyclic voltammetry analysis indicated that membrane associated proteins may play an important role in facilitating electron transfer from the bacteria to the electrode. This is the first study that demonstrates that Citrobacter species can transfer electrons to extracellular electron acceptors

  11. A novel capacitive micro-accelerometer with grid strip capacitances and sensing gap alterable capacitances

    Institute of Scientific and Technical Information of China (English)

    Dong Linxi; Chen Jindan; Yan Haixia; Huo Weihong; Li Yongjie; Sun Lingling

    2009-01-01

    The comb capacitances fabricated by deep reactive ion etching (RIE) process have high aspect ratio which is usually smaller than 30 : 1 for the complicated process factors, and the combs are usually not parallel due to the well-known micro-loading effect and other process factors, which restricts the increase of the seismic mass by increasing the thickness of comb to reduce the thermal mechanical noise and the decrease of the gap of the comb capacitances for increasing the sensitive capacitance to reduce the electrical noise. Aiming at the disadvantage of the deep RIE, a novel capacitive micro-accelerometer with grid strip capacitances and sensing gap alterable capacitances is developed. One part of sensing of inertial signal of the micro-accelerometer is by the grid strip capacitances whose overlapping area is variable and which do not have the non-parallel plate's effect caused by the deep RIE process. Another part is by the sensing gap alterable capacitances whose gap between combs can be reduced by the actuators. The designed initial gap of the alterable comb capacitances is relatively large to depress the effect of the maximum aspect ratio (30 : 1) of deep RIE process. The initial gap of the capacitance of the actuator is smaller than the one of the comb capacitances. The difference between the two gaps is the initial gap of the sensitive capacitor. The designed structure depresses greatly the requirement of deep RIE process. The effects of non-parallel combs on the accelerometer are also analyzed. The characteristics of the micro-accelerometer are discussed by field emission microscopy (FEM) tool ANSYS. The tested devices based on slide-film damping effect are fabricated, and the tested quality factor is 514, which shows that grid strip capacitance design can partly improve the resolution and also prove the feasibility of the designed silicon-glass anodically bonding process.

  12. New High-Energy Nanofiber Anode Materials

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiangwu; Fedkiw, Peter; Khan, Saad; Huang, Alex; Fan, Jiang

    2013-11-15

    The overall goal of the proposed work was to use electrospinning technology to integrate dissimilar materials (lithium alloy and carbon) into novel composite nanofiber anodes, which simultaneously had high energy density, reduced cost, and improved abuse tolerance. The nanofiber structure allowed the anodes to withstand repeated cycles of expansion and contraction. These composite nanofibers were electrospun into nonwoven fabrics with thickness of 50 μm or more, and then directly used as anodes in a lithium-ion battery. This eliminated the presence of non-active materials (e.g., conducting carbon black and polymer binder) and resulted in high energy and power densities. The nonwoven anode structure also provided a large electrode-electrolyte interface and, hence, high rate capacity and good lowtemperature performance capability. Following are detailed objectives for three proposed project periods. • During the first six months: Obtain anodes capable of initial specific capacities of 650 mAh/g and achieve ~50 full charge/discharge cycles in small laboratory scale cells (50 to 100 mAh) at the 1C rate with less than 20 percent capacity fade; • In the middle of project period: Assemble, cycle, and evaluate 18650 cells using proposed anode materials, and demonstrate practical and useful cycle life (750 cycles of ~70% state of charge swing with less than 20% capacity fade) in 18650 cells with at least twice improvement in the specific capacity than that of conventional graphite electrodes; • At the end of project period: Deliver 18650 cells containing proposed anode materials, and achieve specific capacities greater than 1200 mAh/g and cycle life longer than 5000 cycles of ~70% state of charge swing with less than 20% capacity fade.

  13. Porous and mesh alumina formed by anodization of high purity aluminum films at low anodizing voltage

    Energy Technology Data Exchange (ETDEWEB)

    Abd-Elnaiem, Alaa M., E-mail: alaa.abd-elnaiem@science.au.edu.eg [KACST-Intel Consortium Center of Excellence in Nano-manufacturing Applications (CENA), Riyadh (Saudi Arabia); Physics Department, Faculty of Science, Assiut University, Assiut 71516 (Egypt); Mebed, A.M. [Physics Department, Faculty of Science, Assiut University, Assiut 71516 (Egypt); Department of Physics, Faculty of Science, Al-Jouf University, Sakaka 2014 (Saudi Arabia); El-Said, Waleed Ahmed [Department of Chemistry, Faculty of Science, Assiut University, Assiut 71516 (Egypt); Abdel-Rahim, M.A. [Physics Department, Faculty of Science, Assiut University, Assiut 71516 (Egypt)

    2014-11-03

    Electrochemical oxidation of high-purity aluminum (Al) films under low anodizing voltages (1–10) V has been conducted to obtain anodic aluminum oxide (AAO) with ultra-small pore size and inter-pore distance. Different structures of AAO have been obtained e.g. nanoporous and mesh structures. Highly regular pore arrays with small pore size and inter-pore distance have been formed in oxalic or sulfuric acids at different temperatures (22–50 °C). It is found that the pore diameter, inter-pore distance and the barrier layer thickness are independent of the anodizing parameters, which is very different from the rules of general AAO fabrication. The brand formation mechanism has been revealed by the scanning electron microscope study. Regular nanopores are formed under 10 V at the beginning of the anodization and then serve as a template layer dominating the formation of ultra-small nanopores. Anodization that is performed at voltages less than 5 V leads to mesh structured alumina. In addition, we have introduced a simple one-pot synthesis method to develop thin walls of oxide containing lithium (Li) ions that could be used for battery application based on anodization of Al films in a supersaturated mixture of lithium phosphate and phosphoric acid as matrix for Li-composite electrolyte. - Highlights: • We develop anodic aluminum oxide (AAO) with small pore size and inter-pore distance. • Applying low anodizing voltages onto aluminum film leads to form mesh structures. • The value of anodizing voltage (1–10 V) has no effect on pore size or inter-pore distance. • Applying anodizing voltage less than 5 V leads to mesh structured AAO. • AAO can be used as a matrix for Li-composite electrolytes.

  14. Studies on the Nucleophilicity and Scavenge of Superoxide Ion by Cyclic Voltammetry

    Institute of Scientific and Technical Information of China (English)

    WeiYing-liang; DangXue-ping; HuSheng-shui

    2003-01-01

    Superoxide ion was generated by the electro-chemical reduction of oxygen at a platinum electrode in dimethylsulphoxide (DMSO). This work was focused on the nucleophilicity and scavenge of electrogenemted-superoxide ion by cyclic voltammetry. The nucleophilic displacement reactions of superoxide ion with ethyl acetate and diethyl adipate were discussed and the reason for remarkable influence of diethyl adipate was elucidated. The scavenging activity of ascorbic acid was evaluated and the result allowed the conclusion that the scavenging ability of ascorbic acid is much lower in DMSO than in aqueous phasc UV-spectrum of electrogenerated superoxide ion in DMSO exhibited a single absorption band with λmax at 275 nm, which certified further that the method of electrogeneration was reliable and superoxide ion was stable in DMSO.

  15. Studies on the Nucleophilicity and Scavenge of Superoxide Ion by Cyclic Voltammetry

    Institute of Scientific and Technical Information of China (English)

    Wei Ying-liang; Dang Xue-ping; Hu Sheng-shui

    2003-01-01

    Superoxide ion was generated by the electrochemical reduction of oxygen at a platinum electrode in dimethylsulphoxide (DMSO). This work was focused on the nucleophilicity and scavenge of electrogenerated-superoxide ion by cyclic voltammetry. The nucleophilic displacement reactions of superoxide ion with ethyl acetate and diethyl adipate were discussed and the reason for remarkable influence of diethyl adipate was elucidated. The scavenging activity of ascorbic acid was evaluated and the result allowed the conclusion that the scavenging ability of ascorbic acid is much lower in DMSO than in aqueous phase. UV-spectrum of electrogenerated superoxide ion in DMSO exhibited a single absorption band with λmax at 275 nm, which certified further that the method of electrogeneration was reliable and superoxide ion was stable in DMSO.

  16. Imprinted Polymeric Film-Based Sensor for the Detection of Dopamine Using Cyclic Voltammetry

    Institute of Scientific and Technical Information of China (English)

    郭洪声; 何锡文; 李一峻

    2003-01-01

    The imprinted polymeric film was synthesized on the glass-carbon electrodes dlrectly. The response to the template molecule-dopamine and other molecules with similar structure was measured by cyclic voltammetry. The response of dopamine on imprinted electrode was much higher than that of other molecules,because of the existing of micro-cavities in polymeric rdm fitting with the size and shape of dopamine in the imprinted polymer.Experimental results showed that dopamlne can be enriched by the imprinted film, therefore increasing the sensitivity of the sensor. The imprinted film could also efface the interference of ascorbic acid, indicating that dopamine can be determined with a large excess of ascorbic acid.

  17. Quantitative roughness characterization and 3D reconstruction of electrode surface using cyclic voltammetry and SEM image

    Energy Technology Data Exchange (ETDEWEB)

    Dhillon, Shweta; Kant, Rama, E-mail: rkant@chemistry.du.ac.in

    2013-10-01

    Area measurements from cyclic voltammetry (CV) and image from scanning electron microscopy (SEM) are used to characterize electrode statistical morphology, 3D surface reconstruction and its electroactivity. SEM images of single phased materials correspond to two-dimensional (2D) projections of 3D structures, leading to an incomplete characterization. Lack of third dimension information in SEM image is circumvented using equivalence between denoised SEM image and CV area measurements. This CV-SEM method can be used to estimate power spectral density (PSD), width, gradient, finite fractal nature of roughness and local morphology of the electrode. We show that the surface morphological statistical property like distribution function of gradient can be related to local electro-activity. Electrode surface gradient micrographs generated here can provide map of electro-activity sites. Finally, the densely and uniformly packed small gradient over the Pt-surface is the determining criterion for high intrinsic electrode activity.

  18. Voltammetry and In Situ Scanning Tunneling Microscopy of Cytochrome c Nitrite Reductase on Au(111)-Electrodes

    DEFF Research Database (Denmark)

    Gwyer, James; Zhang, Jingdong; Butt, Julea;

    2006-01-01

    density and orientational distribution of NrfA molecules are disclosed. The submonolayer coverage resolved by in situ STM is readily reconciled with the failure to detect nonturnover signals in cyclic voltammetry of the NrfA films. The molecular structures show a range of lateral dimensions. These are...... suggestive of a distribution of orientations that could account for the otherwise anomalously low turnover number calculated for the total population of adsorbed NrfA molecules when compared with that determined for solutions of NrfA. Thus, comparison of the voltammetric signals and in situ STM images offers...... enzyme undergoes direct electron exchange with the electrode. The adsorbed NrfA has been imaged to molecular resolution by in situ scanning tunneling microscopy (in situ STM) under full electrochemical potential control and under conditions where the enzyme is electrocatalytically active. Details of the...

  19. Electrochemical Determination of Alkaline Phosphatase in Human Serum by Differential Pulse Voltammetry

    Institute of Scientific and Technical Information of China (English)

    SUN Wei; JIAO Kui; WANG Hai-yu; LU Lu-de

    2004-01-01

    Differential pulse voltammetry(DPV) was applied to the determination of alkaline phosphatase(ALP) activity in human serum with phenyl phosphate as the substrate. Phenyl phosphate can enzymatically be hydrolyzed to produce phenol which is quantified by DPV at +660 mV(vs.Ag/AgCl) in the concentration range of 2.0-100 μmol/L. The standard curve for ALP is linear over the range from 0.06 to 1000 U/L with a relative standard deviation of 3.0%. The conditions for the enzymatic reaction and voltammetric detection were optimized and the kinetic constants were also examined.The human serum samples were tested by this method and the results were in good agreement with those obtained by the routine p-nitrophenyl phosphate spectrophotometric method.

  20. Chemical imaging with combined fast-scan cyclic voltammetry-scanning electrochemical microscopy.

    Science.gov (United States)

    Schrock, Daniel S; Baur, John E

    2007-09-15

    Fast-scan cyclic voltammetry (FSCV) is applied to the tip of a scanning electrochemical microscope (SECM) for imaging the distribution of chemical species near a substrate. This approach was used to image the diffusion layer of both a large substrate electrode (3-mm-diameter glassy carbon) and a microelectrode substrate (10-microm-diameter Pt). Additionally, oxygen depletion near living cells was measured and correlated to respiratory activity. Finally, oxygen and hydrogen peroxide were simultaneously detected during the oxidative burst of a zymosan-stimulated macrophage cell. These results demonstrate the utility of FSCV-SECM for chemical imaging when conditions are chosen such that feedback interactions with the substrate are minimal. PMID:17705555

  1. Electroanalytical Determination of Danofloxacin in Biological Samples Using Square Wave Voltammetry

    Directory of Open Access Journals (Sweden)

    Chirley Vanessa Boone

    2014-10-01

    Full Text Available The voltammetric behavior of danofloxacin (DFX has been studied, in aqueous solution, on a glassy carbon electrode using square wave voltammetry (SWV as electroanalytical technique. After optimization of the experimental conditions, DFX was analyzed in spiked biologic samples using a Britton-Robinson buffer with pH = 5.0 as the supporting electrolyte. Oxidation occurs at 0.98 V vs. Ag/AgCl in a two-electron process controlled by adsorption of the electrogenerated products on the electrode surface. A acceptable recovery was obtained for assay of spiked biologic samples, with value of 98.7% for the swine urine and 95.3 % for the bovine urine.

  2. Voltammetry and fluorescence studies on the interaction between Eu (phen)33+ and DNA

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The binding mode of Eu(phen) 33+ with DNA is studied by fluorescence and voltammetric methods. From theScatchard graph and the fluorescence quenching phenomenon, it is concluded that the mode of interaction betweenEu(phen) 33+ and DNA is intercalation bind by inserting the phen π-π conjugate surface between the base pairs of theDNA duplex. Voltammetry was used to confirm the results obtained from the fluorescence method, the result from bothmethods agrees with each other. The binding constant (K) and the binding site size (ns) were calculated from voltammetricdata such as the shifts in potential and limiting currents in the process of adding DNA, according to the positive shifts ofpeak potential. It was considered that the complex of the +2 ion interacted more favorably with the nucleotide bases thanthat of the +3 ion by hydrophobic interaction.

  3. CO adsorption on electrode of Pt nanoparticles investigated by cyclic voltammetry and in situ FTIR spectroscopy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Pt nanoparticles were prepared by the chemical reduction method. The average diameter of Pt nanoparticles was determined to be 2.5 nm by TEM. The electrochemical properties of Pt nanoparticles were studied by cyclic voltammetry. In comparison with massive Pt, the oxidation current peak of CO adsorbed on Pt nanoparticles is broader. Twin adsorbates of CO on Pt nanoparticles were determined by in situ FTIRS for the first time. It has revealed that the linear and twin-bonded CO can be converted into bridge-bonded CO with the variation of electrode potential. A series of special properties of Pt nanoparticles, such as enhanced IR absorption of CO adsorbates, were also observed.

  4. Investigation on Concentrated V(IV)/V(V) Redox Reaction by Rotating Disc Voltammetry

    Institute of Scientific and Technical Information of China (English)

    WEN Yue-Hua; ZHANG Hua-Min; QIAN Peng; MA Hai-Peng; YI Bao-Lian; YANG Yu-Sheng

    2007-01-01

    The kinetic characteristics of the concentrated V(IV)/V(V) couple have been studied at a glassy carbon electrode in sulfuric acid using rotating-disc electrode and cyclic voltammetry. The kinetics of the V(IV)/V(V) redox couple reaction was found to be electrochemically quasi-reversible with the slower kinetics for the V(V) reduction than that for the V(IV) oxidation. And, dependence of diffusion coefficients and kinetic parameters of V(IV) species on the V(IV) and H25O4 concentration was investigated. It is shown that the concentration of active species V(IV)centration, the diffusion coefficients of V(IV) were gradually reduced whereas its kinetics was improved considerably,espicially in the case of Ⅴ(Ⅳ)and H2SO4 up to 2 and 4 mol·L-1.

  5. Nonmetallic inclusions in SUS304 strip produced by twin-roll strip casting

    Institute of Scientific and Technical Information of China (English)

    Fuxiang Huang; Jiongming Zhang; Xinhua Wang; Yuan Fang; Yan Yu

    2008-01-01

    The shape, type, content, and dimension of nonmetallic inclusions in SUS304 strip produced by twin-roll strip casting were studied using scanning electron microscopy (SEM). The results show that the inclusions are mainly spherical Al2O3 and com- plex oxides composed of MnO, Al2O3., and SiO2. The percentage of fine oxides smaller than 3 μm reaches up to 51.8%. The theoreti- cal calculations show that fine oxides have precipitated during solidification. Therefore, it is concluded that during twin-roll strip casting, because of high cooling rate, the size of inclusions precipitated during solidification decreases, and the amount increases.

  6. Effect of boron on hot strips of low carbon steel produced by compact strip production

    Institute of Scientific and Technical Information of China (English)

    Hao Yu; Yonglin Kang

    2008-01-01

    The effect of boron on hot strips of low carbon steel produced by compact strip production (CSP) to reduce the strength to a certain degree was investigated, which is quite different from that of high-strength low alloy steel. The mechanical properties and microstructural evolution of the hot strip were studied using optical microscopy and tensile tests. By means of an electrolytic disso- lution technique and Thermo-Cal calculation, the precipitates containing boron were analyzed and detected. From the electron back- scattered diffraction analysis, it can be deciphered whether the microstructure has recrystallized or not. Furthermore, the effect of boron segregation on the recrystallization or non-recrystallization conditions can be distinguished. The segregation behavior of boron was investigated in boron-containing steel. The nonequilibrium segregation of boron during processing was discussed on the basis of the forming complexes with vacancies that migrate to the boundaries prior to annihilation, which was confirmed by the subsequent cold rolling with annealing experiments.

  7. Analytical solutions of the planar cyclic voltammetry process for two soluble species with equal diffusivities and fast electron transfer using the method of eigenfunction expansions

    OpenAIRE

    Adib Samin; Erik Lahti; Jinsuo Zhang

    2015-01-01

    Cyclic voltammetry is a powerful tool that is used for characterizing electrochemical processes. Models of cyclic voltammetry take into account the mass transport of species and the kinetics at the electrode surface. Analytical solutions of these models are not well-known due to the complexity of the boundary conditions. In this study we present closed form analytical solutions of the planar voltammetry model for two soluble species with fast electron transfer and equal diffusivities using th...

  8. Study of the physical processes involved in the operating mode of the micro-strips gas detector Micromegas

    International Nuclear Information System (INIS)

    Micromegas is a micro-strip gaseous detector invented in 1996. It consists of two volumes of gas separated by a micro-mesh. The first volume of gas, 3 mm thick, is used to liberate ionization electrons from the incident charged particle. In the second volume, only 100 μm thick, an avalanche phenomenon amplifies the electrons produced in the first volume. Strips printed on an insulating substrate collect the electrons from the avalanche. The geometrical configuration of Micromegas showed many advantages. The short anode-cathode distance combined with a high granularity provide high rate capabilities due to a fast collection of ions produced during the avalanche development. Moreover, the possibility to localize the avalanche with strips printed about every hundreds of micrometers allows to measure the position of the incident particle with a good resolution. In this work, experimental tests of Micromegas are presented along with detailed Monte Carlo simulations used to understand and optimize the detector's performances. The prototypes were tested several times at the PS accelerator at CERN. The analysis of the date showed a stable and efficient behavior of Micromegas combined with an excellent space resolution. In fact, spatial resolutions of less than 15 μm were obtained. In parallel with the in-beam tests, several simulations have been developed in order to gain a better understanding of the detector's response. (author)

  9. Electric current characteristic of anodic bonding

    International Nuclear Information System (INIS)

    In this paper, a novel current–time model of anodic bonding is proposed and verified experimentally in order to investigate underlying mechanisms of anodic bonding and to achieve real-time monitoring of bonding procedure. The proposed model provides a thorough explanation for the electric current characteristic of anodic bonding. More significantly, it explains two issues which other models cannot explain. One is the sharp rise in current when a voltage is initially applied during anodic bonding. The other is the unexpected large width of depletion layers. In addition, enlargement of the intimately contacted area during anodic bonding can be obtained from the proposed model, which can be utilized to monitor the bonding process. To verify the proposed model, Borofloat33 glass and silicon wafers were adopted in bonding experiments in SUSS SB6 with five different bonding conditions (350 °C 1200 V; 370 °C 1200 V; 380 °C 1200 V; 380 °C 1000 V; and 380 °C 1400 V). The results indicate that the observed current data highly coincide with the proposed current-time model. For widths of depletion layers, depth profiling using secondary ion mass spectrometry demonstrates that the calculated values by the model are basically consistent with the experimental values as well. (paper)

  10. CYCLIC VOLTAMMETRY STUDIES OF COPPER (II) AND TELLURIUM (IV) IONS IN ACIDIC AQUEOUS SOLUTIONS FOR THIN FILM DEPOSITION

    OpenAIRE

    SARAVANAN NAGALINGAM; GEOK BEE TEH

    2014-01-01

    Cyclic voltammetry studies of copper (II) and tellurium (IV) ions in acidic aqueous solutions were carried out to determine the optimum condition for copper telluride thin film deposition. The voltammetry studies include reversible scans at different solution pH. Based on the voltammogram, suitable deposition conditions was determined to be in the range of -0.35 V to -0.45 V versus Ag/AgCl at pH values between 2.0 to 2.2 under non diffusion-limited conditions.

  11. CYCLIC VOLTAMMETRY STUDIES OF COPPER (II AND TELLURIUM (IV IONS IN ACIDIC AQUEOUS SOLUTIONS FOR THIN FILM DEPOSITION

    Directory of Open Access Journals (Sweden)

    SARAVANAN NAGALINGAM

    2014-05-01

    Full Text Available Cyclic voltammetry studies of copper (II and tellurium (IV ions in acidic aqueous solutions were carried out to determine the optimum condition for copper telluride thin film deposition. The voltammetry studies include reversible scans at different solution pH. Based on the voltammogram, suitable deposition conditions was determined to be in the range of -0.35 V to -0.45 V versus Ag/AgCl at pH values between 2.0 to 2.2 under non diffusion-limited conditions.

  12. Anode current density distribution in a cusped field thruster

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Huan, E-mail: wuhuan58@qq.com; Liu, Hui, E-mail: hlying@gmail.com; Meng, Yingchao; Zhang, Junyou; Yang, Siyu; Hu, Peng; Chen, Pengbo; Yu, Daren [Mail Box 458, Harbin Institute of Technology (HIT), Harbin 150001 (China)

    2015-12-15

    The cusped field thruster is a new electric propulsion device that is expected to have a non-uniform radial current density at the anode. To further study the anode current density distribution, a multi-annulus anode is designed to directly measure the anode current density for the first time. The anode current density decreases sharply at larger radii; the magnitude of collected current density at the center is far higher compared with the outer annuli. The anode current density non-uniformity does not demonstrate a significant change with varying working conditions.

  13. Cyclic voitammetry, convolutive voltammetry, chrono-potentiometry and digital simulation studies of [Pt(C≡C tol)_2(dppm)_2Ir(CO)_2]~+PF_6~- complex

    Institute of Scientific and Technical Information of China (English)

    El-Hallag S Ibrahim

    2009-01-01

    The electrochemical behaviour of the heterobimetallic complex [Pt(C≡C tol)_2(dppm)_2-Ir(CO)_2]~+PF_6~-was studied via cyclic voltammetry, convolutive voltammetry and chronopotentiometry at glassy carbon electrode in dichloromethane solution. The electrochemical parameters calculated from experimental data were tested and confirmed by matching the experimental cyclic voltammograms with the simu-lated data. It was found that convolutive voltammetry provided higher sensitivity, better resolution and more accurate method for determination of the electrochemical parameters than ordinary cyclic volt-ammetry.

  14. NH{sub 4}-doped anodic WO{sub 3} prepared through anodization and subsequent NH{sub 4}OH treatment for water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Yong-Wook; Kim, Sunkyu; Seong, Mijeong; Yoo, Hyeonseok; Choi, Jinsub, E-mail: jinsub@inha.ac.kr

    2015-01-01

    Highlights: • NN{sub 4}-doped WO{sub 3} was successfully fabricated by a wet-based method using ammonium hydroxide (NH{sub 4}OH). • (NH{sub 4}){sub 10}W{sub 12}O{sub 41} phase was formed during the NH{sub 4}OH treatment. • Over-doped NH{sub 4} in WO{sub 3} led to reduced photo-electrochemical performance for OER. • The optimized surface was achieved by thermal treatment of anodic WO{sub 3} with 2 g of NH{sub 4}OH solution. - Abstract: Tungsten trioxide (WO{sub 3}) prepared by anodization of a W foil was doped with NH{sub 4} through NH{sub 4}OH treatment at 450 °C. Since aqueous NH{sub 4}OH was used during doping instead of NH{sub 3} gas, the treatment step does not require complicated annealing facilities. Moreover, the state of doped N is a form of NH{sub 3}-W instead of W{sub 2}N, which lowers the bandgap but increases photocorrosion. We found that incorporation of NH{sub 4} into WO{sub 3} leads to reduction of the bandgap from 2.9 eV to 2.2 eV, regardless of the amount of NH{sub 4}OH treatment, lowering the onset potential and increasing the current density at fixed potential for oxygen evolution reaction under illumination. Scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy were employed to investigate the surface morphologies, crystallinities of tungsten oxides and existence of NH{sub 4} doping, respectively. The bandgap energy was determined by UV–Vis spectroscopy to measure the transmittance and refraction. The water splitting performance of each sample was measured by electrochemical linear sweep voltammetry in a 3-electrode configuration under illumination.

  15. Microwave processing of tantalum capacitor anodes

    Energy Technology Data Exchange (ETDEWEB)

    Lauf, R J; Hamby, C; Holcombe, C E [Oak Ridge National Lab., TN (United States); Vierow, W F [AVX Tantalum Corp., Biddeford, ME (United States)

    1992-08-01

    Porous tantalum anodes were sintered at temperatures from 1600 to 1900{degrees}C using a conventional high-vacuum furnace as well as both 2.45 GHz fixed-frequency and 4--8 GHz variable-frequency microwave furnaces. Various insulation and casketing techniques were used to couple the microwave power to the tantalum compacts. Several types of tantalum powder were used to assess the effect of microwave processing on sintered surface area and impurity levels. Some microwave sintered anodes have an unusual surface rippling not seen on conventionally fired parts. The rippling suggests that a microscopic arcing or plasma might have been generated. Two important effects could be exploited if this phenomenon can be controlled. First, the effective tantalum surface area could be increased, yielding higher capacitance per volume. Second, surface impurities might be cleaned away, allowing the formation of a better dielectric film during the anodization process and, ultimately, higher working voltage.

  16. Uranium stripping from tributyl phosphate by urea solutions

    Science.gov (United States)

    Skripchenko, S. Yu.; Titova, S. M.; Smirnov, A. L.; Rychkov, V. N.

    2016-09-01

    The process of uranium stripping from tri-n-butyl phosphate in kerosene by urea solutions was investigated at the volume ratio of the organic and aqueous phases of (1-10) : 1 in the temperature range of 20-60 °C. The stripping of uranium from a loaded organic phase increased with increasing urea content in the solution and with increasing temperature. Maximum recovery of uranium from tributyl phosphate was obtained using a solution that contained 8-12 mol/l of urea. The application of a urea solution for uranium stripping resulted in the strip product solution containing 200-240 g/L of uranium. The process of uranium stripping by dilute nitric acid was also investigated. Results of uranium stripping by the two methods are compared and discussed.

  17. An Insoluble Titanium-Lead Anode for Sulfate Electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Ferdman, Alla

    2005-05-11

    The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having optimized composition and structure were produced for testing in operating conditions of copper electrowinning and EMD production. Bench-scale, mini-pilot scale and pilot scale tests were performed. The test anodes were of both a plate design and a flow-through cylindrical design. The cylindrical anodes were composed of cylinders containing titanium inner rods and fitting over titanium-lead bushings. The cylindrical design allows the electrolyte to flow through the anode, which enhances diffusion of the electrolyte reactants. The cylindrical anodes demonstrate higher mass transport capabilities and increased electrical efficiency compared to the plate anodes. Copper electrowinning represents the primary target market for the titanium-lead anode. A full-size cylindrical anode performance in copper electrowinning conditions was monitored over a year. The test anode to cathode voltage was stable in the 1.8 to 2.0 volt range. Copper cathode morphology was very smooth and uniform. There was no

  18. Preparation and application of a titanium dioxide/graphene oxide anode material for lithium-ion batteries

    Science.gov (United States)

    Siwińska-Stefańska, Katarzyna; Kurc, Beata

    2015-12-01

    This paper describes the synthesis and physicochemical properties of a new type of titania/graphene oxide (TA/GO) composite. Titania powder was synthesized via the sol-gel method, and its surface was functionalized with N-2-(aminoethyl)-3-aminopropyltrimethoxysilane (AAPTS) to increase its adhesion to graphene oxide. Transmission electron microscopy (TEM), non-invasive back scattering (NIBS), porous structure parameters (low-temperature nitrogen sorption), degree of modification of titania and TA/GO determined by Fourier-transform infrared spectroscopy (FT-IR), impedance analysis, charging/discharging and cyclic voltammetry were carried out. At a current density of 50 mA g-1, the good cyclability exhibited by the TA/GO anode can be readily retained at 370 mAh g-1 after 50 cycles, which is outstanding among the TiO2 composites reported in the literature.

  19. Rapid Prototyping of a High Sensitivity Graphene Based Glucose Sensor Strip

    Science.gov (United States)

    Tehrani, Farshad; Reiner, Lisa; Bavarian, Behzad

    2015-01-01

    A rapid prototyping of an inexpensive, disposable graphene and copper nanocomposite sensor strip using polymeric flexible substrate for highly sensitive and selective nonenzymatic glucose detection has been developed and tested for direct oxidization of glucose. The CuNPs were electrochemically deposited on to the graphene sheets to improve electron transfer rates and to enhance electrocatalytic activity toward glucose. The graphene based electrode with CuNPs demonstrated a high degree of sensitivity (1101.3±56 μA/mM.cm2), excellent selectivity (without an interference with Ascorbic Acid, Uric Acid, Dopamine, and Acetaminophen), good stability with a linear response to glucose ranging from 0.1 mM to 0.6 mM concentration, and detection limits of 0.025 mM to 0.9 mM. Characterization of the electrodes was performed by scanning electron microscopy (FESEM and SEM). The electrochemical properties of the modified graphene electrodes were inspected by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and amperometry. PMID:26678700

  20. Intelligent Control on Hot Strip Coiling Temperature

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A new intelligent control scheme for hot strip coiling temperature is presented. In this scheme, the prediction model of finishing temperature and the presetting model of main cooling zone are establish based on BP neural network, the feed-forward open-loop control model of main cooling zone is constructed based on T-S fuzzy neural network, a new improved structure of T-S fuzzy neural network is developed, and the feedback close-loop control model of precision cooling zone is obtained based on fuzzy control. The effectiveness of the proposed scheme has been demonstrated by computer simulation with a satisfactory result.