WorldWideScience

Sample records for annular gas ionization

  1. Study on gas-liquid loop reactors with annular bubbling

    International Nuclear Information System (INIS)

    Fei, L.M.; Wang, S.X.; Wu, X.Q.; Lu, D.W.

    1987-01-01

    Bubbling column with draft tube is one of nearly developed reactor. On the background of hydrocarbon oxidations and biochemical engineerings, it has been widely used in chemical industry due to the well characteristics of mass and heat transfer. In this paper, the characteristics of fluid flow, such as gas hold-up, backmixing and mass transfer referred to the liquid volume were measured in a gas-liquid loop reactor with annular bubbling. Different materials - water, alcohol and oi l- were used in the study in measuring the gas hold-up in the annular of the reactor

  2. An annular ionization detector for quasi-elastic and transfer reaction studies

    CERN Document Server

    Dinesh, B V; Nayak, B K; Biswas, D C; Saxena, A; Pant, L M; Sahu, P K; Choudhury, R K

    2000-01-01

    An annular ionization chamber detector has been developed to study quasi-elastic and transfer reactions in heavy-ion collisions at near-barrier and sub-barrier energies. The important feature of the detector is that it has a near 2 pi coverage in the azimuthal angle phi for the particles entering in the detector at a given theta direction. This feature makes the detector very useful for measurement of the differential cross-sections at backward angles with respect to the beam direction, involving low cross-section reaction channels. The split anode configuration of the detector makes it capable of both particle identification and energy measurement for heavy ions and fission fragments. The detector has been tested using heavy-ion beams from the 14 MV-pelletron accelerator at Mumbai. Results on quasi-elastic excitation function measurements and barrier distribution studies in many heavy-ion reactions using this detector setup are discussed.

  3. Gas turbine structural mounting arrangement between combustion gas duct annular chamber and turbine vane carrier

    Science.gov (United States)

    Wiebe, David J.; Charron, Richard C.; Morrison, Jay A.

    2016-10-18

    A gas turbine engine ducting arrangement (10), including: an annular chamber (14) configured to receive a plurality of discrete flows of combustion gases originating in respective can combustors and to deliver the discrete flows to a turbine inlet annulus, wherein the annular chamber includes an inner diameter (52) and an outer diameter (60); an outer diameter mounting arrangement (34) configured to permit relative radial movement and to prevent relative axial and circumferential movement between the outer diameter and a turbine vane carrier (20); and an inner diameter mounting arrangement (36) including a bracket (64) secured to the turbine vane carrier, wherein the bracket is configured to permit the inner diameter to move radially with the outer diameter and prevent axial deflection of the inner diameter with respect to the outer diameter.

  4. Gas ionization by focused laser beams

    International Nuclear Information System (INIS)

    Brito, A.L. de.

    1984-01-01

    It is shown that the effect of line broadening by focusing may considerably contribute to the observed laser-induced ionization of gases when the ionization energy of the gas molecules is well above the mean photon energy of the laser radiation. (Author) [pt

  5. Droplets in annular-dispersed gas-liquid pipe-flows

    NARCIS (Netherlands)

    Van 't Westende, J.M.C.

    2008-01-01

    Annular-dispersed gas-liquid pipe-flows are commonly encountered in many industrial applications, and have already been studied for many decades. However, due to the great complexity of this type of flow, there are still many phenomena that are poorly understood. The aim of this thesis is to shed

  6. Gas-Dynamic Methods to Reduce Gas Flow Nonuniformity from the Annular Frames of Gas Turbine Engines

    Science.gov (United States)

    Kolmakova, D.; Popov, G.

    2018-01-01

    Gas flow nonuniformity is one of the main sources of rotor blade vibrations in the gas turbine engines. Usually, the flow circumferential nonuniformity occurs near the annular frames, located in the flow channel of the engine. This leads to the increased dynamic stresses in blades and consequently to the blade damage. The goal of the research was to find an acceptable method of reducing the level of gas flow nonuniformity. Two different methods were investigated during this research. Thus, this study gives the ideas about methods of improving the flow structure in gas turbine engine. Based on existing conditions (under development or existing engine) it allows the selection of the most suitable method for reducing gas flow nonuniformity.

  7. Structure of the gas-liquid annular two-phase flow in a nozzle section

    International Nuclear Information System (INIS)

    Yoshida, Kenji; Kataoka, Isao; Ohmori, Syuichi; Mori, Michitsugu

    2006-01-01

    Experimental studies on the flow behavior of gas-liquid annular two-phase flow passing through a nozzle section were carried out. This study is concerned with the central steam jet injector for a next generation nuclear reactor. In the central steam jet injector, steam/water annular two-phase flow is formed at the mixing nozzle. To make an appropriate design and to establish the high-performance steam injector system, it is very important to accumulate the fundamental data of the thermo-hydro dynamic characteristics of annular flow passing through a nozzle section. On the other hand, the transient behavior of multiphase flow, in which the interactions between two-phases occur, is one of the most interesting scientific issues and has attracted research attention. In this study, the transient gas-phase turbulence modification in annular flow due to the gas-liquid phase interaction is experimentally investigated. The annular flow passing through a throat section is under the transient state due to the changing cross sectional area of the channel and resultantly the superficial velocities of both phases are changed compared with a fully developed flow in a straight pipe. The measurements for the gas-phase turbulence were precisely performed by using a constant temperature hot-wire anemometer, and made clear the turbulence structure such as velocity profiles, fluctuation velocity profiles. The behavior of the interfacial waves in the liquid film flow such as the ripple or disturbance waves was also observed. The measurements for the liquid film thickness by the electrode needle method were also performed to measure the base film thickness, mean film thickness, maximum film thickness and wave height of the ripple or the disturbance waves. (author)

  8. The GBT Diffuse Ionized Gas Survey (GDIGS)

    Science.gov (United States)

    Luisi, Matteo; Anderson, Loren Dean; Liu, Bin; Bania, Thomas; Balser, Dana; Wenger, Trey; Haffner, Lawrence Matthew

    2018-01-01

    Diffuse ionized gas in the Galactic mid-plane known as the "Warm Ionized Medium" (WIM) makes up ~20% of the gas mass of the Milky Way and >90% of its ionized gas. It is the last major component of the interstellar medium (ISM) that has not yet been studied at high spatial and spectral resolution, and therefore many of its fundamental properties remain unclear. The Green Bank Telescope (GBT) Diffuse Ionized Gas Survey (GDIGS) is a new large survey of the Milky Way disk at C-band (4-8 GHz). The main goals of GDIGS are to investigate the properties of the WIM and to determine the connection between the WIM and high-mass star formation over the Galactic longitude and latitude range of 32 deg > l > -5 deg, |b| resolution of 0.5 km/s and rms sensitivities of ~3 mJy per beam. GDIGS observations are currently underway and are expected to be completed by late 2018. These data will allow us to: 1) Study for the first time the inner-Galaxy WIM unaffected by confusion from discrete HII regions, 2) determine the distribution of the inner Galaxy WIM, 3) investigate the ionization state of the WIM, 4) explore the connection between the WIM and HII regions, and 5) analyze the effect of leaked photons from HII regions on ISM dust temperatures.

  9. Several versions of forward gas ionization calorimeter

    International Nuclear Information System (INIS)

    Babintsev, V.V.; Kholodenko, A.G.; Rodnov, Yu.V.

    1994-01-01

    The properties of several versions of a gas ionization calorimeter are analyzed by means of the simulation with the GEANT code. The jet energy and coordinate resolutions are evaluated. Some versions of the forward calorimeter meet the ATLAS requirements. 13 refs., 15 figs., 7 tabs

  10. Monitoring system of depressurization valves of migrated gas in annular space of flexible risers

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Luiz A.; Santos, Joilson M.; Carvalho, Antonio L.; Loureiro, Patricia [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2005-07-01

    PETROBRAS Research and Development Center - CENPES developed an automatic system for monitoring pressure of annular space due to permeation of gas in flexible risers to inspect continuously integrity of such lines. To help maintaining physical integrity of flexible risers, two PSV's are installed to end fittings on top of riser, so that operation of any valve grants the maximum admissible gas pressure within the riser annular space, as overpressure might cause damages to external polymeric layer of flexible riser. Due to the fact that there is no mechanism allowing operation to verify correct PSV performance and frequency of valve's closings and openings, we felt to be necessary the development and implement an automatic instrumented system, integrated to platform's automation and control infrastructure. The objective of this instrumentation is to monitor and register pressure of annular space in flexible riser, as well as XV's depressurization frequency. Having such information registered and monitored, can infer some riser structural conditions, anticipating repairs and preventive maintenance. In this paper we present developed system details including instruments required, application, operation of associated screens that are used in the ECOS, with events, alarms and industrial automation services required (Application development and system integration). (author)

  11. Thermal hydraulic analysis of gas-cooled reactors with annular fuel rods

    International Nuclear Information System (INIS)

    Han, Kyu Hyun; Chang, Soon Heung

    2005-01-01

    More than half of the world's energy is used in industrial processes and for heating applications which have hardly been touched by the nuclear industry. Nuclear power could be brought into a wide range of applications for industrial processes, provided that gas outlet temperatures of gascooled reactors are sufficiently high. The most limiting core design requirement which controls the core outlet temperature is the maximum acceptable fuel compact temperature. An innovative fuel design is required for a significant decrease in the fuel temperature. This study investigated the possibilities of implementing internally and externally cooled annular fuel rods in a gas-cooled reactor

  12. Heat and mass transfer for turbulent flow of chemically reacting gas in eccentric annular channels

    International Nuclear Information System (INIS)

    Besedina, T.V.; Tverkovkin, B.E.; Udot, A.V.; Yakushev, A.P.

    1988-01-01

    Because of the possibility of using dissociating gases as coolants and working bodies of nuclear power plants, it is necessary to develop computational algorithms for calculating heat and mass transfer processes under conditions of nonequilibrium flow of chemically reacting gases not only in axisymmetric channels, but also in channels with a complex transverse cross section (including also in eccentric annular channels). An algorithm is proposed for calculating the velocity, temperature, and concentration fields under conditions of cooling of a cylindrical heat-releasing rod, placed off-center in a circular casing pipe, by a longitudinal flow of chemically reacting gas [N 2 O 4

  13. Analysis of spatial and temporal spectra of liquid film surface in annular gas-liquid flow

    Science.gov (United States)

    Alekseenko, Sergey; Cherdantsev, Andrey; Heinz, Oksana; Kharlamov, Sergey; Markovich, Dmitriy

    2013-09-01

    Wavy structure of liquid film in annular gas-liquid flow without liquid entrainment consists of fast long-living primary waves and slow short-living secondary waves. In present paper, results of spectral analysis of this wavy structure are presented. Application of high-speed LIF technique allowed us to perform such analysis in both spatial and temporal domains. Power spectra in both domains are characterized by one-humped shape with long exponential tail. Influence of gas velocity, liquid Reynolds number, liquid viscosity and pipe diameter on frequency of the waves is investigated. When gravity effect is much lesser than the shear stress, similarity of power spectra at different gas velocities is observed. Using combination of spectral analysis and identification of characteristic lines of primary waves, frequency of generation of secondary waves by primary waves is measured.

  14. State and trends of ionization gas analysis. 1

    International Nuclear Information System (INIS)

    Leonhardt, J.W.; Grosse, H.J.; Popp, P.

    1980-01-01

    The ionization gas analysis makes use of the fact that the ionization-induced conductivity of gases and gas mixtures changes with the composition of such mixtures. A general description is given of ionization detectors based on this principle and theory, properties, and main fields of application of electron capture detectors are discussed

  15. Resonance ionization spectroscopy: Counting noble gas atoms

    International Nuclear Information System (INIS)

    Hurst, G.S.; Payne, M.G.; Chen, C.H.; Willis, R.D.; Lehmann, B.E.; Kramer, S.D.

    1981-01-01

    The purpose of this paper is to describe new work on the counting of noble gas atoms, using lasers for the selective ionization and detectors for counting individual particles (electrons or positive ions). When positive ions are counted, various kinds of mass analyzers (magnetic, quadrupole, or time-of-flight) can be incorporated to provide A selectivity. We show that a variety of interesting and important applications can be made with atom-counting techniques which are both atomic number (Z) and mass number (A) selective. (orig./FKS)

  16. Thermocapillary and shear driven flows in gas/liquid system in annular duct

    International Nuclear Information System (INIS)

    Gaponenko, Yu; Shevtsova, V; Nepomnyashchy, A

    2011-01-01

    We report the results of numerical study of two-phase flows in annulus for different aspect ratios obtained in the frame of the JEREMI experiment preparation. The geometry of the physical problem is a cylindrical and non-deformable liquid bridge concentrically surrounded by an annular gas channel under conditions of zero gravity. Thermocapillary (Marangoni) convection in liquid bridge of Pr = 68 is analyzed in the case when the interface is subjected to an axial gas stream. The gas flow is counter-directed with respect to the Marangoni flow. The inlet gas velocity U 0 g , temperature difference ΔT between end rods of the liquid bridge and aspect ratio are the control parameters of the system. In the case when the gas stream comes from the cold side, it cools down the interface to a temperature lower than that of the liquid beneath, and in a certain region of the parameter space that cooling causes instability due to a temperature difference in the direction, perpendicular to the interface. The present study is focused on the influence of the aspect ratio on the existence and characteristic features of the oscillatory regime.

  17. Heat-and-mass transfer during a laminar dissociating gas flow in eccentric annular channels

    International Nuclear Information System (INIS)

    Besedina, T.V.; Udot, A.V.; Yakushev, A.P.

    1987-01-01

    An algorithm to calculate heat-and-mass transfer processes during dissociating gas laminar flow in an eccentric annular channels is considered. Analytical solutions of the heat transfer equations for a rod clodding and gap with boundary conditions of conjugation of temperatures and heat fluxes have been used to determine temperature field. This has made it possible to proceed from slution of the conjugate problem to solution of the equation of energy only for the coolant. The results of calculation of temperature distribution along the cladding for different values of its eccentricity and thermal conductivity coefficient both for the case of frozen flow and in the presence of chemical reactions in the flow are given. When calculating temperatures with conjugation boundary conditions temperature gradients in azimuthal direction are far less and heat transfer in concentration diffusion is carried out mainly in radial direction

  18. Theory on a partially ionized gas centrifuge

    International Nuclear Information System (INIS)

    Berg, M.S. van den.

    1982-01-01

    This thesis contains a study of some flow processes occurring in the Gaswhirl experiments. In this apparatus a partially ionized gas is forced into rotation by an azimuthal electromagnetic force. After a short introduction in which a motivation is given of our research project, a comprehensive treatment is presented of the principle of rotating plasmas. Further, a historical review is given of rotating plasma systems. A derivation of the fundamental equations is given which describe the flow system mathematically and these are applied to rotating plasmas. The occurrence of secondary flows with radial and axial components is considered. This qualitative picture of secondary whirls is confirmed by measurements reported in the next chapter. The last chapter offers a possible explanation of the occurrence of the transition process in the Gaswhirl apparatus. (Auth.)

  19. Effect of wall thermal conductivity on the heat transfer process in annular turbulent gas flow for constant wall temperature

    International Nuclear Information System (INIS)

    Groshev, A.I.; Anisimov, V.V.; Kashcheev, V.M.; Khudasko, V.V.; Yur'ev, Yu.S.

    1987-01-01

    The effect of wall material on convective heat transfer of turbulent gas flow in an annular tube with account of longitudinal diffusion both in the wall and in the liquid is studied numerically. The conjugated problem is solved for P r =0.7 (Re=10 4 -10 6 ). Based on numerical calculations it is stated that thermal conductivity of the wall and gas essentially affects the degree of preliminary heating of liquid in the range of a non-heated section

  20. A study on the effect of gas flow rate on the wave characteristics in two-phase gas-liquid annular flow

    International Nuclear Information System (INIS)

    Han Huawei; Zhu Zhenfeng; Gabriel, Kamiel

    2006-01-01

    Interfacial waves play a very important role in the mass, momentum and energy transport phenomena in annular flow. In this paper, film thickness time-trace measurements for air-water annular flow were collected in a small vertical tube using a parallel wire probe. Using the data, a typical disturbance wave shape was obtained and wave properties (e.g., width, height, speed and roughness) were presented. The liquid mass flux ranged from 100 to 200 kg/m 2 s and the gas mass flux ranged from 18 to 47 kg/m 2 s. Disturbance wave characteristics were defined and the effects of changing the gas flow rate on the wave spacing, wave width, wave peak height and wave base height were studied. An average velocity model for the wave and base regions has been developed to determine the wave velocity. The investigation method could be further extended to annular-mist flow which frequently occurs in boiling water reactors

  1. The first experience with LHC beam gas ionization monitor

    CERN Document Server

    Sapinski, M; Dehning, B; Guerrero, A; Patecki, M; Versteegen, R

    2012-01-01

    The Beam Gas Ionization Monitors (BGI) are used to measure beam emittance on LHC. This paper describes the detectors and their operation and discusses the issues met during the commissioning. It also discusses the various calibration procedures used to correct for non-uniformity of Multi-Channel plates and to correct the beam size for effects affecting the electron trajectory after ionization.

  2. Churn-annular flow pattern transition in a vertical upward gas-liquid two-phase flow in various conduits

    International Nuclear Information System (INIS)

    Takenaka, Nobuyuki; Ueda, Tadanobu; Asano, Hitoshi

    2008-01-01

    Void fraction was measured by neutron radiography for a vertical upward gas-water two-phase flow in a concentric annular tube with and with out a spacer, 4x4 rod bundle with and without a spacer and a tight rod bundle with and without a wrapping wire for various gas and liquid flow rates. The flow patterns of these two-phase flows were determined by the Mishima-Ishii flow pattern map and void fraction was calculated by the Ishii's drift flux model. The predicted values were compared with the experimental results. The void fraction was well predicted by the Mishima-Ishii flow pattern map and the Ishii's drift flux model except the annular flow region with void fraction lower than 0.8 for conduits with small equivalent diameter. A new churn-annular flow pattern transition condition of the void fraction equal to 0.8 was added. The void fraction for the present experimental condition was successful predicted with the new transition model. (author)

  3. State and trends of ionization gas analysis. 3

    International Nuclear Information System (INIS)

    Leonhardt, J.W.; Grosse, H.J.; Popp, P.

    1980-01-01

    Theory, properties, and main fields of application of noble gas detectors are discussed. The theory and design of the indirect electron mobility detector is presented. Conclusions are drawn with regard to possibilities of further development of detectors for the ionization gas analysis

  4. Experimental investigation of gas turbine airfoil aerodynamic performance without and with film cooling in an annular sector cascade

    Energy Technology Data Exchange (ETDEWEB)

    Wiers, S.H.

    2002-02-01

    The steady growing of industrialization, the densification of the anthroposphere, the increasing concern over the effects of gas turbine cruise emissions on the atmosphere threaten the growth of air transportation, and the perception about the possible climatic impact of CO{sub 2} emissions causes a public distinctive sense of responsibility. The conventional energy production techniques, which are based on fossil fuel, will keep its central importance within the global energy production. Forecasts about the increasing air transportation give duplication in the next 10-15 years. The optimization of the specific fuel consumption is necessary to decrease the running costs and the pollution emissions in the atmosphere, which makes an increased process efficiency of stationary turbines as well as of jet engines essential. This leads to the necessity of an increased thermodynamic efficiency of the overall process and the optimization of the aerodynamic components. Due to the necessity of more detailed three-dimensional data on the behavior of film cooled blades an annular sector cascade turbine test facility has gone into service. The annular sector cascade facility is a relative cost efficient solution compared to a full annular facility to investigate three-dimensional effects on a non cooled and cooled turbine blade. The aerodynamic investigations on the annular sector cascade facility are part of a broad perspective where experimental data from a hot annular sector cascade facility and the cold annular sector facility are used to verify, calibrate and understand the physics for both internal and external calculation methods for flow and heat transfer prediction. The objective of the present study is the design and validation of a cold flow annular sector cascade facility, which meets the flow conditions in a modem turbine as close as possible, with emphasis on achieving periodic flow conditions. The first part of this study gives the necessary background on this

  5. A novel method for producing multiple ionization of noble gas

    International Nuclear Information System (INIS)

    Wang Li; Li Haiyang; Dai Dongxu; Bai Jiling; Lu Richang

    1997-01-01

    We introduce a novel method for producing multiple ionization of He, Ne, Ar, Kr and Xe. A nanosecond pulsed electron beam with large number density, which could be energy-controlled, was produced by incidence a focused 308 nm laser beam onto a stainless steel grid. On Time-of-Flight Mass Spectrometer, using this electron beam, we obtained multiple ionization of noble gas He, Ne, Ar and Xe. Time of fight mass spectra of these ions were given out. These ions were supposed to be produced by step by step ionization of the gas atoms by electron beam impact. This method may be used as a ideal soft ionizing point ion source in Time of Flight Mass Spectrometer

  6. Annular pancreas

    Science.gov (United States)

    ... page: //medlineplus.gov/ency/article/001142.htm Annular pancreas To use the sharing features on this page, please enable JavaScript. An annular pancreas is a ring of pancreatic tissue that encircles ...

  7. Contributions of greenhouse gas forcing and the Southern Annular Mode to historical Southern Ocean surface temperature trends

    OpenAIRE

    Kostov, Yavor; Ferreira, David; Marshall, John; Armour, Kyle

    2018-01-01

    We examine the 1979-2014 Southern Ocean (SO) sea surface temperature (SST) trends simulated in an ensemble of coupled general circulation models and evaluate possible causes of the models’ inability to reproduce the observed 1979-2014 SO cooling. For each model we estimate the response of SO SST to step changes in greenhouse gas (GHG) forcing and in the seasonal indices of the Southern Annular Mode (SAM). Using these step-response functions, we skillfully reconstruct the models’ 1979-2014 SO ...

  8. Ionization chamber for monitoring radioactive gas

    International Nuclear Information System (INIS)

    Kotrappa, P.; Dempsey, J.

    1992-01-01

    This present invention provides simple, effective and accurate cumulative measurement of radioactive gas over a time period. Measurements of radioactive gas are important for many purposes. Tritium concentrations in potentially exposed workers are measured, for example, with periodic urine specimens. Carbon-14 serves as a useful research tool for monitoring the progress of many chemical and biological reactions and interactions. For example, many microorganisms break down carbon-14 containing compounds in sugar to produce carbon-14 dioxide gas which can be collected and measured to determine various characteristics of the microorganisms. Both tritium and carbon-14 dioxide produce low energy radiation which cannot be easily measured by conventional radioactivity detectors. (author). 4 figs

  9. Ionization chamber for monitoring radioactive gas

    Energy Technology Data Exchange (ETDEWEB)

    Kotrappa, P; Dempsey, J

    1992-09-22

    This present invention provides simple, effective and accurate cumulative measurement of radioactive gas over a time period. Measurements of radioactive gas are important for many purposes. Tritium concentrations in potentially exposed workers are measured, for example, with periodic urine specimens. Carbon-14 serves as a useful research tool for monitoring the progress of many chemical and biological reactions and interactions. For example, many microorganisms break down carbon-14 containing compounds in sugar to produce carbon-14 dioxide gas which can be collected and measured to determine various characteristics of the microorganisms. Both tritium and carbon-14 dioxide produce low energy radiation which cannot be easily measured by conventional radioactivity detectors. (author). 4 figs.

  10. The Formation and Physical Origin of Highly Ionized Cooling Gas

    Energy Technology Data Exchange (ETDEWEB)

    Bordoloi, Rongmon [MIT-Kavli Center for Astrophysics and Space Research, 77 Massachusetts Avenue, Cambridge, MA, 02139 (United States); Wagner, Alexander Y. [University of Tsukuba, Center for Computational Sciences, Tennodai 1-1-1, Tsukuba, Ibaraki (Japan); Heckman, Timothy M.; Norman, Colin A., E-mail: bordoloi@mit.edu, E-mail: bordoloi@mit.edu [Department of Physics and Astronomy, John Hopkins University, 21218, Baltimore, MD (United States)

    2017-10-20

    We present a simple model that explains the origin of warm, diffuse gas seen primarily as highly ionized absorption-line systems in the spectra of background sources. We predict the observed column densities of several highly ionized transitions such as O vi, O vii, Ne viii, N v, and Mg x, and we present a unified comparison of the model predictions with absorption lines seen in the Milky Way disk, Milky Way halo, starburst galaxies, the circumgalactic medium, and the intergalactic medium at low and high redshifts. We show that diffuse gas seen in such diverse environments can be simultaneously explained by a simple model of radiatively cooling gas. We show that most such absorption-line systems are consistent with being collisionally ionized, and we estimate the maximum-likelihood temperature of the gas in each observation. This model satisfactorily explains why O vi is regularly observed around star-forming low- z L* galaxies, and why N v is rarely seen around the same galaxies. We further present some consequences of this model in quantifying the dynamics of the cooling gas around galaxies and predict the shock velocities associated with such flows. A unique strength of this model is that while it has only one free (but physically well-constrained) parameter, it nevertheless successfully reproduces the available data on O vi absorbers in the interstellar, circumgalactic, intragroup, and intergalactic media, as well as the available data on other absorption lines from highly ionized species.

  11. Penning ionization cross sections of excited rare gas atoms

    International Nuclear Information System (INIS)

    Ukai, Masatoshi; Hatano, Yoshihiko.

    1988-01-01

    Electronic energy transfer processes involving excited rare gas atoms play one of the most important roles in ionized gas phenomena. Penning ionization is one of the well known electronic energy transfer processes and has been studied extensively both experimentally and theoretically. The present paper reports the deexcitation (Penning ionization) cross sections of metastable state helium He(2 3 S) and radiative He(2 1 P) atoms in collision with atoms and molecules, which have recently been obtained by the authors' group by using a pulse radiolysis method. Investigation is made of the selected deexcitation cross sections of He(2 3 S) by atoms and molecules in the thermal collisional energy region. Results indicate that the cross sections are strongly dependent on the target molecule. The deexcitation probability of He(2 3 S) per collision increases with the excess electronic energy of He(2 3 S) above the ionization potential of the target atom or molecule. Another investigation, made on the deexcitation of He(2 1 P), suggests that the deexcitation cross section for He(2 1 P) by Ar is determined mainly by the Penning ionization cross section due to a dipole-dipole interaction. Penning ionization due to the dipole-dipole interaction is also important for deexcitation of He(2 1 P) by the target molecules examined. (N.K.)

  12. A study on the effect of gas flow rate on the wave characteristics in two-phase gas-liquid annular flow

    Energy Technology Data Exchange (ETDEWEB)

    Han Huawei [Faculty of Engineering and Applied Science, University of Ontario Institute of Technology, Oshawa, Ont., L1H 7K4 (Canada)]. E-mail: colin.han@uoit.ca; Zhu Zhenfeng [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon, Sask., S7N 5A9 (Canada)]. E-mail: zhz752@mail.usask.ca; Gabriel, Kamiel [University of Ontario Institute of Technology, Oshawa, Ont., L1H 7K4 (Canada)]. E-mail: kamiel.gabriel@uoit.ca

    2006-12-15

    Interfacial waves play a very important role in the mass, momentum and energy transport phenomena in annular flow. In this paper, film thickness time-trace measurements for air-water annular flow were collected in a small vertical tube using a parallel wire probe. Using the data, a typical disturbance wave shape was obtained and wave properties (e.g., width, height, speed and roughness) were presented. The liquid mass flux ranged from 100 to 200 kg/m{sup 2} s and the gas mass flux ranged from 18 to 47 kg/m{sup 2} s. Disturbance wave characteristics were defined and the effects of changing the gas flow rate on the wave spacing, wave width, wave peak height and wave base height were studied. An average velocity model for the wave and base regions has been developed to determine the wave velocity. The investigation method could be further extended to annular-mist flow which frequently occurs in boiling water reactors.

  13. Ionization chamber for measurements of high-level tritium gas

    International Nuclear Information System (INIS)

    Carstens, D.H.W.; David, W.R.

    1980-01-01

    The construction and calibration of a simple ionization-chamber apparatus for measurement of high level tritium gas is described. The apparatus uses an easily constructed but rugged chamber containing the unknown gas and an inexpensive digital multimeter for measuring the ion current. The equipment after calibration is suitable for measuring 0.01 to 100% tritium gas in hydrogen-helium mixes with an accuracy of a few percent. At both the high and low limits of measurements deviations from the predicted theoretical current are observed. These are briefly discussed

  14. The effect of the gas-liquid density ratio on the liquid film thickness in vertical upward annular flow

    International Nuclear Information System (INIS)

    Mori, Shoji; Okuyama, Kunito

    2010-01-01

    Annular two phase flow is encountered in many industrial equipments, including flow near nuclear fuel rods in boiling water reactor (BWR). Especially, disturbance waves play important roles in the pressure drop, the generation of entrainments, and the dryout of the liquid film. Therefore, it is important to clarify the behavior of disturbance waves and base film. However, most of the previous studies have been performed under atmospheric pressure conditions that provide the properties of liquid and gas which are significantly different from those of a BWR. Therefore, the effect of properties in gas and liquid on liquid film characteristics should be clarified. In this paper we focus on the effect of gas-liquid density ratio on liquid film thickness characteristics. The experiments have been conducted at four density ratio conditions (ρ L /ρ G =763, 451, 231, and 31). As a result, it was found that liquid film thickness characteristics including the effect of liquid/gas density ratios were well correlated with a gas Weber number and the liquid Reynolds number in the wide range of experimental conditions (ρ L /ρ G : 31-763, We: 10-1800, Re L : 500-2200). (author)

  15. High concentration tritium gas measurement with small volume ionization chambers for fusion fuel gas monitors

    International Nuclear Information System (INIS)

    Uda, Tatsuhiko; Okuno, Kenji; Matsuda, Yuji; Naruse, Yuji

    1991-01-01

    To apply ionization chambers to fusion fuel gas processing systems, high concentration tritium gas was experimentally measured with small volume 0.16 and 21.6 cm 3 ionization chambers. From plateau curves, the optimum electric field strength was obtained as 100∼200 V/cm. Detection efficiency was confirmed as dependent on the ionization ability of the filled gas, and moreover on its stopping power, because when the range of the β-rays was shortened, the probability of energy loss by collisions with the electrode and chamber wall increased. Loss of ions by recombination was prevented by using a small volume ionization chamber. For example the 0.16 cm 3 ionization chamber gave measurement with linearity to above 40% tritium gas. After the tritium gas measurements, the concentration levels inside the chamber were estimated from their memory currents. Although more than 1/4,000 of the maximum, current was observed as a memory effect, the smaller ionization chamber gave a smaller memory effect. (author)

  16. Contributions of Greenhouse Gas Forcing and the Southern Annular Mode to Historical Southern Ocean Surface Temperature Trends

    Science.gov (United States)

    Kostov, Yavor; Ferreira, David; Armour, Kyle C.; Marshall, John

    2018-01-01

    We examine the 1979-2014 Southern Ocean (SO) sea surface temperature (SST) trends simulated in an ensemble of coupled general circulation models and evaluate possible causes of the models' inability to reproduce the observed 1979-2014 SO cooling. For each model we estimate the response of SO SST to step changes in greenhouse gas (GHG) forcing and in the seasonal indices of the Southern Annular Mode (SAM). Using these step-response functions, we skillfully reconstruct the models' 1979-2014 SO SST trends. Consistent with the seasonal signature of the Antarctic ozone hole and the seasonality of SO stratification, the summer and fall SAM exert a large impact on the simulated SO SST trends. We further identify conditions that favor multidecadal SO cooling: (1) a weak SO warming response to GHG forcing, (2) a strong multidecadal SO cooling response to a positive SAM trend, and (3) a historical SAM trend as strong as in observations.

  17. Ionized gas at the edge of the central molecular zone

    Science.gov (United States)

    Langer, W. D.; Goldsmith, P. F.; Pineda, J. L.; Velusamy, T.; Requena-Torres, M. A.; Wiesemeyer, H.

    2015-04-01

    Context. The edge of the central molecular zone (CMZ) is the location where massive dense molecular clouds with large internal velocity dispersions transition to the surrounding more quiescent and lower CO emissivity region of the Galaxy. Little is known about the ionized gas surrounding the molecular clouds and in the transition region. Aims: We determine the properties of the ionized gas at the edge of the CMZ near Sgr E using observations of N+ and C+. Methods: We observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C ii] 158 μm and [N ii] 205 μm fine structure lines at six positions with the GREAT instrument on SOFIA and in [C ii] using Herschel HIFI on-the-fly strip maps. We use the [N ii] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C ii] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. Results: We detect two [C ii] and [N ii] velocity components, one along the line of sight to a CO molecular cloud at - 207 km s-1 associated with Sgr E and the other at -174 km s-1 outside the edge of another CO cloud. From the [N ii] emission we find that the average electron density is in the range of ~5 to 21 cm-3 for these features. This electron density is much higher than that of the disk's warm ionized medium, but is consistent with densities determined for bright diffuse H ii nebula. The column density of the CO-dark H2 layer in the -207 km s-1 cloud is ~1-2 × 1021 cm-2 in agreement with theoretical models. The CMZ extends further out in Galactic radius by ~7 to 14 pc in ionized gas than it does in molecular gas traced by CO. Conclusions: The edge of the CMZ likely contains dense hot ionized gas surrounding the neutral molecular material. The high fractional abundance of N+ and high electron density require an intense EUV field with a photon flux of order 106 to 107 photons cm-2 s-1, and/or efficient proton charge exchange with

  18. Ionizing gas breakdown waves in strong electric fields.

    Science.gov (United States)

    Klingbeil, R.; Tidman, D. A.; Fernsler, R. F.

    1972-01-01

    A previous analysis by Albright and Tidman (1972) of the structure of an ionizing potential wave driven through a dense gas by a strong electric field is extended to include atomic structure details of the background atoms and radiative effects, especially, photoionization. It is found that photoionization plays an important role in avalanche propagation. Velocities, electron densities, and temperatures are presented as a function of electric field for both negative and positive breakdown waves in nitrogen.

  19. Angular intensity of a gas-phase field ionization source

    International Nuclear Information System (INIS)

    Orloff, J.; Swanson, L.W.

    1979-01-01

    Angular intensities of 1 μA sr -1 have been measured for a gas-phase field ionization source in an optical column under practical operating conditions. The source, which was differentially pumped and cooled to 77 K, utilized a -oriented iridium emitter and precooled hydrogen gas at 10 -2 Torr. The ion beam was collimated with an electrostatic lens and detected below an aperture subtending 0.164 msr. A transmitted current of approx.10 -10 A was measured at voltages corresponding to a field of approx. =2.2 V/A at the emitter

  20. Gas lift for annular flow in San Andres well No. 24

    Energy Technology Data Exchange (ETDEWEB)

    Zenteno, E B

    1968-10-01

    Gas lift is a method of artificial lift which utilizes the expansive energy of compressed gas to lift fluid from the formation up to the surface separation installation. A wide range of operations exists for gas lifting. For making a decision regarding the use of such a method, the following steps are recommended: (1) establish the well fluid characteristics, the productivity index, the oil/water relationship, the fluid properties, the diameter of the tubing and similar data; (2) for the range of production desired, calculate a pressure gradient curve for the fluid below the point of gas injection; (3) supposing there is a difference in the relationship of injected gas to oil, calculate a pressure gradient curve of the fluid above the point of gas injection (this assumes a constant surface discharge pressure); and (4) simultaneously solve (2) and (3), which will permit determination of the variation according to depth of the point of gas injection, together with the pressure of the injected gas, and also the relation between the injected gas and the oil. Finally, calculate the theoretical potential necessary for the desired compression of the gas to such surface pressure that it will discharge at an injection pressure that will produce optimized conditions for development of the desired production.

  1. Aerodynamic Effects in Weakly Ionized Gas: Phenomenology and Applications

    International Nuclear Information System (INIS)

    Popovic, S.; Vuskovic, L.

    2006-01-01

    Aerodynamic effects in ionized gases, often neglected phenomena, have been subject of a renewed interest in recent years. After a brief historical account, we discuss a selected number of effects and unresolved problems that appear to be relevant in both aeronautic and propulsion applications in subsonic, supersonic, and hypersonic flow. Interaction between acoustic shock waves and weakly ionized gas is manifested either as plasma-induced shock wave dispersion and acceleration or as shock-wave induced double electric layer in the plasma, followed by the localized increase of the average electron energy and density, as well as enhancement of optical emission. We describe the phenomenology of these effects and discuss several experiments that still do not have an adequate interpretation. Critical for application of aerodynamic effects is the energy deposition into the flow. We classify and discuss some proposed wall-free generation schemes with respect to the efficiency of energy deposition and overall generation of the aerodynamic body force

  2. Structure of anode plasma of gas discharge taking into account gas ionization burnout

    International Nuclear Information System (INIS)

    Zharinov, A.V.; Shumilin, V.P.

    2006-01-01

    One deals with a structure of an anode plasma of a gas discharge with intensive ionization ( b urnout ) of neutral atoms (neutrals). One derived analytical solutions of the quasi-neutrality equation for potential distribution, as well as, a condition of anode plasma existence in a unidimensional case at the arbitrary dependences of neutral burnout frequency and of electron concentration on the potential. One studied particular cases of the level frequency of neutral burnout, of ionization by the Maxwell electrons and of ionization by the intensive beam at collision-free motion of ions and the Boltzmann distribution of thermal electrons. Solutions for the first two cases at zero parameter of burnout, that is, at the level concentration of a gas coincide with the solutions obtained [1] by the power series expansion. It is shown that in case of ionization by the Maxwell electrons, anode plasma at the rational flow rates of a working gas may be produced under rather high temperature of electrons (if, for example, xenon serves as a working gas, so T e ≥5 eV). The stationary solutions of the quasi-neutrality at ionization by the intensive electron beam are found exclusively when the ratio between the electron beam density and the maximum density of thermal neutrons does not exceed a certain limiting value [ru

  3. Lean-rich axial stage combustion in a can-annular gas turbine engine

    Science.gov (United States)

    Laster, Walter R.; Szedlacsek, Peter

    2016-06-14

    An apparatus and method for lean/rich combustion in a gas turbine engine (10), which includes a combustor (12), a transition (14) and a combustor extender (16) that is positioned between the combustor (12) and the transition (14) to connect the combustor (12) to the transition (14). Openings (18) are formed along an outer surface (20) of the combustor extender (16). The gas turbine (10) also includes a fuel manifold (28) to extend along the outer surface (20) of the combustor extender (16), with fuel nozzles (30) to align with the respective openings (18). A method (200) for axial stage combustion in the gas turbine engine (10) is also presented.

  4. Research on insulating material affecting the property of gas ionization chamber

    International Nuclear Information System (INIS)

    Wang Liqiang; Wang Zhentao; Zheng Jian

    2014-01-01

    The insulating material in ionization chamber affects the internal gas pressure and ionic pulse shape in the research process of the ion drift velocity in high pressure gas ionization chamber. It will affect the ion drift velocity measurement. It is required to isolate by insulating material between electrode to electrode and between electrodes to the shell of gas ionization chamber. Insulating material in gas ionization chamber is indispensable. Therefore it needs to carefully study the insulating material affecting the performance of gas ionization chamber. First of all, it is found that Teflon can slowly adsorb the working gas in ionization chamber, and the gas pressure in it is reduced when we measure the sensitivity of gas ionization chamber over time. It is verified by experiment that insulating materials absorbing and releasing gas is dynamically reversible process. Then the adsorbing gas property of 95% aluminium oxide ceramic and Teflon is studied through experimental comparision. Gas adsorption equilibrium time of ceramic material is faster, generally it is about a few hours, and the gas adsorption capacity is relatively less. Gas adsorption equilibrium time of Teflon is slower, it is about a few days, and the gas adsorption capacity is relatively more. It is found that Teflon will release part of the gas at higher temperature through experimental research on the influence of Teflon adsorbing gas. Finally it is studied that the distribution of insulation in ionization chamber affects the time response speed of ionization chamber by measuring the signal pulse shape of ionization chamber under the pulse X-ray. Through these experimental research, it is presented that it need to pay attention to select insulation material and to design the internal structure and arrangement of insulating material when we design gas ionization chamber. (authors)

  5. Study on time response character for high pressure gas ionization chamber of krypton and xenon

    International Nuclear Information System (INIS)

    Tan Chunming; Wu Haifeng; Qing Shangyu; Wang Liqiang

    2006-01-01

    The time response character for Kr and Xe high pressure gas ionization chamber is analyzed and deduced. Compared with the measure data of pulse rising time for three gas-filled ionization chambers, the calculated and experimental results are equal to each other. The rising time less than 10 ms for this kind of ionization chamber can be achieved, so this ionization chamber is able to meet the requirement for imaging detection. (authors)

  6. First ECR-Ionized Noble Gas Radioisotopes at ISOLDE

    CERN Document Server

    Wenander, F; Gaubert, G; Jardin, P; Lettry, Jacques

    2004-01-01

    The production of light noble gas radioisotopes with high ionization potentials has been hampered by modest ionization efficiencies for standard plasma ion-sources. However, the decay losses are minimal as the lingering time of light noble gases within plasma ion-sources is negligible when compared to its diffusion out of the target material. Previous singly charged ECRIS have shown a higher efficiency but also a lingering time of the order of 1 s and a total weight that prevents remote handling by the ISOLDE robot. The compact MINIMONO efficiently addressed the lingering time and weight issues. In addition, the MINIMONO maintained the high off-line ionization efficiency for light noble gases. This paper describes a standard ISOLDE target unit equipped with a MINIMONO ion-source and the first tests. The ion-source has been tested off-line and equipped with a CaO target for on-line tests. Valuable information was gained about high current (100-500 muA) transport through the ISOLDE mass separators designed for ...

  7. Ultraviolet/Optical Emission of the Ionized Gas in AGN: Diagnostics of the Ionizing Source and Gas Properties

    Directory of Open Access Journals (Sweden)

    Anna Feltre

    2017-11-01

    Full Text Available Spectroscopic studies of active galactic nuclei (AGN are powerful means of probing the physical properties of the ionized gas within them. In particular, near future observational facilities, such as the James Webb Space Telescope (JWST, will allow detailed statistical studies of rest-frame ultraviolet and optical spectral features of the very distant AGN with unprecedented accuracy. In this proceedings, we discuss the various ways of exploiting new dedicated photoionization models of the narrow-line emitting regions (NLR of AGN for the interpretation of forthcoming revolutionary datasets.

  8. Ultraviolet/Optical Emission of the Ionized Gas in AGN: Diagnostics of the Ionizing Source and Gas Properties

    Energy Technology Data Exchange (ETDEWEB)

    Feltre, Anna [Univ Lyon, Univ Lyon1, Ens de Lyon, Centre National de la Recherche Scientifique, Centre de Recherche Astrophysique de Lyon UMR5574, Saint-Genis-Laval (France); Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Charlot, Stephane [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Mignoli, Marco [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Bongiorno, Angela [INAF-Osservatorio Astronomico di Roma, Monteporzio Catone (Italy); Calura, Francesco [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Chevallard, Jacopo [Scientific Support Office, Directorate of Science and Robotic Exploration, European Space Research and Technology Centre (ESTEC), European Space Agency (ESA), Noordwijk (Netherlands); Curtis-Lake, Emma [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Gilli, Roberto [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Plat, Adele, E-mail: anna.feltre@univ-lyon1.fr [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France)

    2017-11-02

    Spectroscopic studies of active galactic nuclei (AGN) are powerful means of probing the physical properties of the ionized gas within them. In particular, near future observational facilities, such as the James Webb Space Telescope (JWST), will allow detailed statistical studies of rest-frame ultraviolet and optical spectral features of the very distant AGN with unprecedented accuracy. In this proceedings, we discuss the various ways of exploiting new dedicated photoionization models of the narrow-line emitting regions (NLR) of AGN for the interpretation of forthcoming revolutionary datasets.

  9. The preliminary design of an annular combustor for a mini gas turbine

    CSIR Research Space (South Africa)

    Meyers, Bronwyn C

    2015-10-01

    Full Text Available This study involves the redesign of the combustor liner for a 200N mini gas turbine engine using first principles and the design methods of the NREC series as shown in Figure 1. The combustor design was performed using five different operating...

  10. CFD analysis of heat transfer in a vertical annular gas gap

    International Nuclear Information System (INIS)

    Borgohain, A.; Maheshwari, N.K.; Vijayan, P.K.

    2011-01-01

    Heat transfer analysis in a vertical annulus is carried out by using a CFD code TRIO-U. The results are used to understand heat transfer in the vertical annulus. An experimental study is taken from literature for the CFD analysis. The geometry of the test section of the experiment is simulated in TRIO-U. The operating conditions of the experiment are simulated by imposing appropriate boundary conditions. Three modes of the heat transfer, conduction, radiation and convection in the gas gap are considered in the analysis. From the analysis it is found that TRIO-U can successfully handle all modes heat transfer. The theoretical results for heat transfer have been compared with experimental data. This paper deals with the detailed CFD modelling and analysis. (author)

  11. Seal plate with concentrate annular segments for a gas turbine engine

    International Nuclear Information System (INIS)

    Harris, D.P.; Light, S.H.

    1991-01-01

    This patent describes a gas turbine engine. It comprises a radial outflow, rotary compressor; a radial inflow turbine wheel; means coupling the compressor and the turbine wheel in slightly spaced back to back relating so that the turbine wheel may drive the compressor; a housing surrounding the compressor and the turbine wheel; and a stationary seal mounted on the housing and extending into the space between the compressor and the turbine wheel, the seal including a main sealing and support section adjacent the compressor and a multiple piece diaphragm mounted to the main section, but generally spaced therefrom, the pieces of the diaphragm being movable with respect to each other and with respect to the main section, and including a radially inner ring and a radially outer ring, one of the rings including a lip which overlaps an edge of the other of the rings, the lip and the edge being in sliding, sealing engagement

  12. Mobilities of positive ions in gas ionization chambers

    International Nuclear Information System (INIS)

    Kusumegi, Asao

    1990-01-01

    Observed ion mobilities of organic molecules in Ar are compared with a complete polarization model to examine the performance of the model, and its applicability is discussed. In spite of its simplicity, the polarization model (small sphere limit) is found to agree satisfactorily with observed mobilities in the case of alkali ions in Ar. However, the model fails to account for the mobility of Ar + in Ar due to a resonant charge transfer interaction between the ion and the parent gas. On the other hand, the values of k, a parameter which depends on the kinetic and the potential energy of the relevant ion, derived from observed ion mobilities of organic molecules in Ar and in the parent gas are found to be close to each other. Except for few cases, it appears that the complete polarization model gives a reasonable approximation for the positive ion mobilities of organic molecules in Ar, though the importance of the ion mass identification is significant in considering the applicability of the model to the positive ion mobility of those organic molecules in Ar used in a gas ionization chamber. (N.K.)

  13. Electron kinetics modeling in a weakly ionized gas

    International Nuclear Information System (INIS)

    Boeuf, Jean-Pierre

    1985-01-01

    This work presents some features of electron kinetics in a weakly ionized gas. After a summary of the basis and recent developments of the kinetic theory, and a review of the most efficient numerical techniques for solving the Boltzmann equation, several aspects of electron motion in gases are analysed. Relaxation phenomena toward equilibrium under a uniform electric field, and the question of the existence of the hydrodynamic regime are first studied. The coupling between electron kinetics and chemical kinetics due to second kind collisions in Nitrogen is then analysed; a quantitative description of the evolution of the energy balance, accounting for electron-molecule as well as molecule-molecule energy transfer is also given. Finally, electron kinetics in space charge distorted, highly non uniform electric fields (glow discharges, streamers propagation) is investigated with microscopic numerical methods based on Boltzmann and Poisson equations. (author) [fr

  14. Cross section determination for the higher ionization of rare gas ions by electron collisions

    International Nuclear Information System (INIS)

    Becker, R.; Frodl, R.; Klein, H.; Schmidt, W.; Clausnitzer, G.; Klinger, H.; Mueller, A.; Salzborn, E.; Fuchs, G.; Viehboeck, F.

    1975-01-01

    The higher ionization of rare gas ions is reported on, which were excited by an electron beam using a crossed-beam technique. A detector for the identification of metastable excited rare gas ions was developed. (WL) [de

  15. Two-step laser ionization schemes for in-gas laser ionization and spectroscopy of radioactive isotopesa

    OpenAIRE

    Kudryavtsev, Yuri; Ferrer, Rafael; Huyse, Mark; Van den Bergh, Paul; Van Duppen, Piet; Vermeeren, L.

    2014-01-01

    The in-gas laser ionization and spectroscopy technique has been developed at the Leuven isotope separator on-line facility for the production and in-source laser spectroscopy studies of short-lived radioactive isotopes. In this article, results from a study to identify efficient optical schemes for the two-step resonance laser ionization of 18 elements are presented. © 2013 AIP Publishing LLC.

  16. The critical ionization velocity mechnism for the case of gas mixture

    International Nuclear Information System (INIS)

    Raadu, M.A.

    1982-08-01

    The theory of the critical ionization velocity mechnisms is discussed. In the case of gas mixture the critical velocity is expected to depend on the ionization cross sections. An analytic approximation is introduced which can be used to set limits on a generalized expression for the critical velocity of gas mixtures. (Author)

  17. Prediction of evaporation heat transfer coefficient based on gas-liquid two-phase annular flow regime in horizontal microfin tubes

    International Nuclear Information System (INIS)

    Wang Yueshe; Wang Yanling; Wang, G.-X.; Honda, Hiroshi

    2009-01-01

    A physical model of gas-liquid two-phase annular flow regime is presented for predicting the enhanced evaporation heat transfer characteristics in horizontal microfin tubes. The model is based on the equivalence of a periodical distortion of the disturbance wave in the substrate layer. Corresponding to the stratified flow model proposed previously by authors, the dimensionless quantity Fr 0 = G/[gd e ρ v (ρ l - ρ v )] 0.5 may be used as a measure for determining the applicability of the present theoretical model, which was used to restrict the transition boundary between the stratified-wavy flow and the annular/intermittent flows. Comparison of the prediction of the circumferential average heat transfer coefficient with available experimental data for four tubes and three refrigerants reveals that a good agreement is obtained or the trend is better than that of the previously developed stratified flow model for Fr 0 > 4.0 as long as the partial dry out of tube does not occur. Obviously, the developed annular model is applicable and reliable for evaporation in horizontal microfin tubes under the case of high heat flux and high mass flux.

  18. Prediction of evaporation heat transfer coefficient based on gas-liquid two-phase annular flow regime in horizontal microfin tubes

    Energy Technology Data Exchange (ETDEWEB)

    Wang Yueshe, E-mail: wangys@mail.xjtu.edu.cn [State Key Laboratory of Multiphase Flow in Power Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Yanling, Wang [State Key Laboratory of Multiphase Flow in Power Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Wang, G -X [Mechanical Engineering Department, The University of Akron, Akron, OH 44325-3903 (United States); Honda, Hiroshi [Kyushu University, 337 Kasuya-machi, Kasuya-gun, Kukuoka 811-2307 (Japan)

    2009-10-15

    A physical model of gas-liquid two-phase annular flow regime is presented for predicting the enhanced evaporation heat transfer characteristics in horizontal microfin tubes. The model is based on the equivalence of a periodical distortion of the disturbance wave in the substrate layer. Corresponding to the stratified flow model proposed previously by authors, the dimensionless quantity Fr{sub 0} = G/[gd{sub e}{rho}{sub v}({rho}{sub l} - {rho}{sub v})]{sup 0.5} may be used as a measure for determining the applicability of the present theoretical model, which was used to restrict the transition boundary between the stratified-wavy flow and the annular/intermittent flows. Comparison of the prediction of the circumferential average heat transfer coefficient with available experimental data for four tubes and three refrigerants reveals that a good agreement is obtained or the trend is better than that of the previously developed stratified flow model for Fr{sub 0} > 4.0 as long as the partial dry out of tube does not occur. Obviously, the developed annular model is applicable and reliable for evaporation in horizontal microfin tubes under the case of high heat flux and high mass flux.

  19. Resonance ionization in a gas cell: a feasibility study for a laser ion source

    International Nuclear Information System (INIS)

    Qamhieh, Z.N.; Vandeweert, E.; Silverans, R.E.; Duppen, P. van; Huyse, M.; Vermeeren, L.

    1992-01-01

    A laser ion source based on resonance photo-ionization in a gas cell is proposed. The gas cell, filled with helium, consists of a target chamber in which the recoil products are stopped and neutralized, and an ionization chamber where the atoms of interest are selectively ionized by the laser light. The extraction of the ions from the ionization chamber through the exit hole-skimmer setup is similar to the ion-guide system. The conditions to obtain an optimal system are given. The results of a two-step one-laser resonance photo-ionization of nickel and the first results of laser ionization in a helium buffer gas cell are presented. (orig.)

  20. Natural convection of high-temperature, high-pressure gas in a horizontal annular layer of thermal insulator, (1)

    International Nuclear Information System (INIS)

    Ogawa, Masuro; Takizuka, Takakazu; Sanokawa, Konomo

    1979-02-01

    Numerical calculations are described of the natural convection in a horizontal annular layer of thermal insulator. The purpose is to compare the numerical results for variable physical properties with those for constant properties. The numerical procedure and typical results are presented. (author)

  1. Three-Dimensional View of Ionized Gas Conditions in Galaxies

    Science.gov (United States)

    Juneau, Stephanie; NOAO Data Lab

    2018-06-01

    We present a 3D version of common emission line diagnostic diagrams used to identify the source of ionization in galaxies, and highlight interesting features in this new 3D space, which are associated with global galaxy properties. Namely, we combine the BPT and Mass-Excitation (MEx) diagrams, and apply it to a set of >300,000 galaxies from the SDSS survey. Among other features, we show that the usual “branch” of star-forming galaxies becomes a curved surface in the new 3D space. Understanding the underlying reasons can shed light on the nearby galaxy population but also aid our interpretation of high-redshift surveys, which indicate a strong evolution of emission line ratios. Despite efforts to explain the origin of this strong evolution, a consensus has not yet been reached. Yet, the implications are crucial to our understanding of galaxy growth across cosmic time, and in particular to assess how star forming regions differed at earlier times (gas properties? stellar properties? a combination?). We perform this analysis within the framework of the NOAO Data Lab (datalab.noao.edu) jointly with public visualization tools. The final workflow will be released publicly.

  2. Experimental analysis of heat transfer between a heated wire and a rarefied gas in an annular gap with high diameter ratio

    International Nuclear Information System (INIS)

    Chalabi, H; Lorenzini, M; Morini, G L; Buchina, O; Valougeorgis, D; Saraceno, L

    2012-01-01

    In this paper a first experimental attempt is performed to measure heat conduction through rarefied air at rest contained between two concentric cylinders. The heat transfer between a heated platinum wire having a diameter (d) of 0.15 mm, disposed along the axis of a cylindrical shell in stainless steel having an inner diameter (D) of 100 mm, and a surrounded rarefied gas has been studied experimentally and numerically. The ratio between the outer and inner diameter of the annular region filled by the gas is large (D/d=667). In the annular region filled with air the pressure was varied by using a vacuum pump from atmospheric value down to 10 −3 mbar. Temperature differences between the wire and the external stainless steel wall in the range 50-125 K were imposed and the heat power transferred from the wire to the surround was measured as a function of the gas pressure starting from air at atmospheric conditions down to 10 −3 mbar. The experimental results obtained in these tests were compared with the numerical results obtained by using the linear and nonlinear Shakhov kinetic models.

  3. Determination of equilibrium composition of thermally ionized monoatomic gas under different physical conditions

    Science.gov (United States)

    Romanova, M. S.; Rydalevskaya, M. A.

    2017-05-01

    Perfect gas mixtures that result from thermal ionization of spatially and chemically homogeneous monoatomic gases are considered. Equilibrium concentrations of the components of such mixtures are determined using integration over the momentum space and summation with respect to energy levels of the distribution functions that maximize the entropy of system under condition for constancy of the total number of nuclei and electrons. It is demonstrated that such a method allows significant simplification of the calculation of the equilibrium composition for ionized mixtures at different temperatures and makes it possible to study the degree of ionization of gas versus gas density and number in the periodic table of elements.

  4. Electron impact ionization of the gas-phase sorbitol

    Science.gov (United States)

    Chernyshova, Irina; Markush, Pavlo; Zavilopulo, Anatoly; Shpenik, Otto

    2015-03-01

    Ionization and dissociative ionization of the sorbitol molecule by electron impact have been studied using two different experimental methods. In the mass range of m/ z = 10-190, the mass spectra of sorbitol were recorded at the ionizing electron energies of 70 and 30 eV. The ion yield curves for the fragment ions have been analyzed and the appearance energies of these ions have been determined. The relative total ionization cross section of the sorbitol molecule was measured using monoenergetic electron beam. Possible fragmentation pathways for the sorbitol molecule were proposed.

  5. Pressure of a partially ionized hydrogen gas : numerical results from exact low temperature expansions

    OpenAIRE

    Alastuey , Angel; Ballenegger , Vincent

    2010-01-01

    8 pages; International audience; We consider a partially ionized hydrogen gas at low densities, where it reduces almost to an ideal mixture made with hydrogen atoms in their ground-state, ionized protons and ionized electrons. By performing systematic low-temperature expansions within the physical picture, in which the system is described as a quantum electron-proton plasma interacting via the Coulomb potential, exact formulae for the first five leading corrections to the ideal Saha equation ...

  6. Ionization processes in combined high-voltage nanosecond - laser discharges in inert gas

    Science.gov (United States)

    Starikovskiy, Andrey; Shneider, Mikhail; PU Team

    2016-09-01

    Remote control of plasmas induced by laser radiation in the atmosphere is one of the challenging issues of free space communication, long-distance energy transmission, remote sensing of the atmosphere, and standoff detection of trace gases and bio-threat species. Sequences of laser pulses, as demonstrated by an extensive earlier work, offer an advantageous tool providing access to the control of air-plasma dynamics and optical interactions. The avalanche ionization induced in a pre-ionized region by infrared laser pulses where investigated. Pre-ionization was created by an ionization wave, initiated by high-voltage nanosecond pulse. Then, behind the front of ionization wave extra avalanche ionization was initiated by the focused infrared laser pulse. The experiment was carried out in argon. It is shown that the gas pre-ionization inhibits the laser spark generation under low pressure conditions.

  7. Characteristics of Noble Gas-filled Ionization Chambers for a Low Dose Rate Monitoring

    International Nuclear Information System (INIS)

    Kim, Han Soo; Park, Se Hwan; Ha, Jan Ho; Lee, Jae Hyung; Lee, Nam Ho; Kim, Jung Bok; Kim, Yong Kyun; Kim, Do Hyun; Cho, Seung Yeon

    2007-01-01

    An ionization chamber is still widely used in fields such as an environmental radiation monitoring, a Radiation Monitoring System (RMS) in nuclear facilities, and an industrial application due to its operational stability for a long period and its designs for its applications. Ionization chambers for RMS and an environmental radiation monitoring are requested to detect a low dose rate at as low as 10-2 mR/h and several 3R/h, respectively. Filling gas and its pressure are two of the important factors for an ionization chamber development to use it in these fields, because these can increase the sensitivity of an ionization chamber. We developed cylindrical and spherical ionization chambers for a low dose rate monitoring. Response of a cylindrical ionization chamber, which has a 1 L active volume, was compared when it was filled with Air, Ar, and Xe gas respectively. Response of a spherical ionization chamber was also compared in the case of 9 atm and 25 atm filling-pressures. An inter-comparison with a commercially available high pressure Ar ionization chamber and a fabricated ionization chamber was also performed. A High Pressure Xenon (HPXe) ionization chamber, which was configured with a shielding mesh to eliminate an induced charge of positive ions, was fabricated both for the measurement of an environmental dose rate and for the measurement of an energy spectrum

  8. Influence of ionization on ultrafast gas-based nonlinear fiber optics.

    Science.gov (United States)

    Chang, W; Nazarkin, A; Travers, J C; Nold, J; Hölzer, P; Joly, N Y; Russell, P St J

    2011-10-10

    We numerically investigate the effect of ionization on ultrashort high-energy pulses propagating in gas-filled kagomé-lattice hollow-core photonic crystal fibers by solving an established uni-directional field equation. We consider the dynamics of two distinct regimes: ionization induced blue-shift and resonant dispersive wave emission in the deep-UV. We illustrate how the system evolves between these regimes and the changing influence of ionization. Finally, we consider the effect of higher ionization stages.

  9. Gas chromatography/chemical ionization triple quadrupole mass spectrometry analysis of anabolic steroids: ionization and collision-induced dissociation behavior.

    Science.gov (United States)

    Polet, Michael; Van Gansbeke, Wim; Van Eenoo, Peter; Deventer, Koen

    2016-02-28

    The detection of new anabolic steroid metabolites and new designer steroids is a challenging task in doping analysis. Switching from electron ionization gas chromatography triple quadrupole mass spectrometry (GC/EI-MS/MS) to chemical ionization (CI) has proven to be an efficient way to increase the sensitivity of GC/MS/MS analyses and facilitate the detection of anabolic steroids. CI also extends the possibilities of GC/MS/MS analyses as the molecular ion is retained in its protonated form due to the softer ionization. In EI it can be difficult to find previously unknown but expected metabolites due to the low abundance or absence of the molecular ion and the extensive (and to a large extent unpredictable) fragmentation. The main aim of this work was to study the CI and collision-induced dissociation (CID) behavior of a large number of anabolic androgenic steroids (AAS) as their trimethylsilyl derivatives in order to determine correlations between structures and CID fragmentation. Clarification of these correlations is needed for the elucidation of structures of unknown steroids and new metabolites. The ionization and CID behavior of 65 AAS have been studied using GC/CI-MS/MS with ammonia as the reagent gas. Glucuronidated AAS reference standards were first hydrolyzed to obtain their free forms. Afterwards, all the standards were derivatized to their trimethylsilyl forms. Full scan and product ion scan analyses were used to examine the ionization and CID behavior. Full scan and product ion scan analyses revealed clear correlations between AAS structure and the obtained mass spectra. These correlations were confirmed by analysis of multiple hydroxylated, methylated, chlorinated and deuterated analogs. AAS have been divided into three groups according to their ionization behavior and into seven groups according to their CID behavior. Correlations between fragmentation and structure were revealed and fragmentation pathways were postulated. Copyright © 2016 John Wiley

  10. Ionization detection system for aerosols

    International Nuclear Information System (INIS)

    Jacobs, M.E.

    1977-01-01

    This invention relates to an improved smoke-detection system of the ionization-chamber type. In the preferred embodiment, the system utilizes a conventional detector head comprising a measuring ionization chamber, a reference ionization chamber, and a normally non-conductive gas triode for discharging when a threshold concentration of airborne particulates is present in the measuring chamber. The improved system utilizes a measuring ionization chamber which is modified to minimize false alarms and reductions in sensitivity resulting from changes in ambient temperature. In the preferred form of the modification, an annular radiation shield is mounted about the usual radiation source provided to effect ionization in the measuring chamber. The shield is supported by a bimetallic strip which flexes in response to changes in ambient temperature, moving the shield relative to the source so as to vary the radiative area of the source in a manner offsetting temperature-induced variations in the sensitivity of the chamber. 8 claims, 7 figures

  11. PHYSICS OF A PARTIALLY IONIZED GAS RELEVANT TO GALAXY FORMATION SIMULATIONS-THE IONIZATION POTENTIAL ENERGY RESERVOIR

    Energy Technology Data Exchange (ETDEWEB)

    Vandenbroucke, B.; De Rijcke, S.; Schroyen, J. [Department of Physics and Astronomy, Ghent University, Krijgslaan 281, S9, B-9000 Gent (Belgium); Jachowicz, N. [Department of Physics and Astronomy, Ghent University, Proeftuinstraat 86, B-9000 Gent (Belgium)

    2013-07-01

    Simulation codes for galaxy formation and evolution take on board as many physical processes as possible beyond the standard gravitational and hydrodynamical physics. Most of this extra physics takes place below the resolution level of the simulations and is added in a ''sub-grid'' fashion. However, these sub-grid processes affect the macroscopic hydrodynamical properties of the gas and thus couple to the ''on-grid'' physics that is explicitly integrated during the simulation. In this paper, we focus on the link between partial ionization and the hydrodynamical equations. We show that the energy stored in ions and free electrons constitutes a potential energy term which breaks the linear dependence of the internal energy on temperature. Correctly taking into account ionization hence requires modifying both the equation of state and the energy-temperature relation. We implemented these changes in the cosmological simulation code GADGET2. As an example of the effects of these changes, we study the propagation of Sedov-Taylor shock waves through an ionizing medium. This serves as a proxy for the absorption of supernova feedback energy by the interstellar medium. Depending on the density and temperature of the surrounding gas, we find that up to 50% of the feedback energy is spent ionizing the gas rather than heating it. Thus, it can be expected that properly taking into account ionization effects in galaxy evolution simulations will drastically reduce the effects of thermal feedback. To the best of our knowledge, this potential energy term is not used in current simulations of galaxy formation and evolution.

  12. PHYSICS OF A PARTIALLY IONIZED GAS RELEVANT TO GALAXY FORMATION SIMULATIONS—THE IONIZATION POTENTIAL ENERGY RESERVOIR

    International Nuclear Information System (INIS)

    Vandenbroucke, B.; De Rijcke, S.; Schroyen, J.; Jachowicz, N.

    2013-01-01

    Simulation codes for galaxy formation and evolution take on board as many physical processes as possible beyond the standard gravitational and hydrodynamical physics. Most of this extra physics takes place below the resolution level of the simulations and is added in a ''sub-grid'' fashion. However, these sub-grid processes affect the macroscopic hydrodynamical properties of the gas and thus couple to the ''on-grid'' physics that is explicitly integrated during the simulation. In this paper, we focus on the link between partial ionization and the hydrodynamical equations. We show that the energy stored in ions and free electrons constitutes a potential energy term which breaks the linear dependence of the internal energy on temperature. Correctly taking into account ionization hence requires modifying both the equation of state and the energy-temperature relation. We implemented these changes in the cosmological simulation code GADGET2. As an example of the effects of these changes, we study the propagation of Sedov-Taylor shock waves through an ionizing medium. This serves as a proxy for the absorption of supernova feedback energy by the interstellar medium. Depending on the density and temperature of the surrounding gas, we find that up to 50% of the feedback energy is spent ionizing the gas rather than heating it. Thus, it can be expected that properly taking into account ionization effects in galaxy evolution simulations will drastically reduce the effects of thermal feedback. To the best of our knowledge, this potential energy term is not used in current simulations of galaxy formation and evolution.

  13. Air ionization as a control technology for off-gas emissions of volatile organic compounds.

    Science.gov (United States)

    Kim, Ki-Hyun; Szulejko, Jan E; Kumar, Pawan; Kwon, Eilhann E; Adelodun, Adedeji A; Reddy, Police Anil Kumar

    2017-06-01

    High energy electron-impact ionizers have found applications mainly in industry to reduce off-gas emissions from waste gas streams at low cost and high efficiency because of their ability to oxidize many airborne organic pollutants (e.g., volatile organic compounds (VOCs)) to CO 2 and H 2 O. Applications of air ionizers in indoor air quality management are limited due to poor removal efficiency and production of noxious side products, e.g., ozone (O 3 ). In this paper, we provide a critical evaluation of the pollutant removal performance of air ionizing system through comprehensive review of the literature. In particular, we focus on removal of VOCs and odorants. We also discuss the generation of unwanted air ionization byproducts such as O 3 , NOx, and VOC oxidation intermediates that limit the use of air-ionizers in indoor air quality management. Copyright © 2017. Published by Elsevier Ltd.

  14. Shock Structure Analysis and Aerodynamics in a Weakly Ionized Gas Flow

    Science.gov (United States)

    Saeks, R.; Popovic, S.; Chow, A. S.

    2006-01-01

    The structure of a shock wave propagating through a weakly ionized gas is analyzed using an electrofluid dynamics model composed of classical conservation laws and Gauss Law. A viscosity model is included to correctly model the spatial scale of the shock structure, and quasi-neutrality is not assumed. A detailed analysis of the structure of a shock wave propagating in a weakly ionized gas is presented, together with a discussion of the physics underlying the key features of the shock structure. A model for the flow behind a shock wave propagating through a weakly ionized gas is developed and used to analyze the effect of the ionization on the aerodynamics and performance of a two-dimensional hypersonic lifting body.

  15. Ionization and scintillation response of high-pressure xenon gas to alpha particles

    International Nuclear Information System (INIS)

    Álvarez, V; Cárcel, S; Cervera, A; Díaz, J; Ferrario, P; Gil, A; Gómez-Cadenas, J J; Borges, F I G; Conde, C A N; Fernandes, L M P; Freitas, E D C; Cebrián, S; Dafni, T; Gómez, H; Egorov, M; Gehman, V M; Goldschmidt, A; Esteve, R; Evtoukhovitch, P; Ferreira, A L

    2013-01-01

    High-pressure xenon gas is an attractive detection medium for a variety of applications in fundamental and applied physics. In this paper we study the ionization and scintillation detection properties of xenon gas at 10 bar pressure. For this purpose, we use a source of alpha particles in the NEXT-DEMO time projection chamber, the large scale prototype of the NEXT-100 neutrinoless double beta decay experiment, in three different drift electric field configurations. We measure the ionization electron drift velocity and longitudinal diffusion, and compare our results to expectations based on available electron scattering cross sections on pure xenon. In addition, two types of measurements addressing the connection between the ionization and scintillation yields are performed. On the one hand we observe, for the first time in xenon gas, large event-by-event correlated fluctuations between the ionization and scintillation signals, similar to that already observed in liquid xenon. On the other hand, we study the field dependence of the average scintillation and ionization yields. Both types of measurements may shed light on the mechanism of electron-ion recombination in xenon gas for highly-ionizing particles. Finally, by comparing the response of alpha particles and electrons in NEXT-DEMO, we find no evidence for quenching of the primary scintillation light produced by alpha particles in the xenon gas.

  16. Axisymmetric annular curtain stability

    International Nuclear Information System (INIS)

    Ahmed, Zahir U; Khayat, Roger E; Maissa, Philippe; Mathis, Christian

    2012-01-01

    A temporal stability analysis was carried out to investigate the stability of an axially moving viscous annular liquid jet subject to axisymmetric disturbances in surrounding co-flowing viscous gas media. We investigated in this study the effects of inertia, surface tension, the gas-to-liquid density ratio, the inner-to-outer radius ratio and the gas-to-liquid viscosity ratio on the stability of the jet. With an increase in inertia, the growth rate of the unstable disturbances is found to increase. The dominant (or most unstable) wavenumber decreases with increasing Reynolds number for larger values of the gas-to-liquid viscosity ratio. However, an opposite tendency for the most unstable wavenumber is predicted for small viscosity ratio in the same inertia range. The surrounding gas density, in the presence of viscosity, always reduces the growth rate, hence stabilizing the flow. There exists a critical value of the density ratio above which the flow becomes stable for very small viscosity ratio, whereas for large viscosity ratio, no stable flow appears in the same range of the density ratio. The curvature has a significant destabilizing effect on the thin annular jet, whereas for a relatively thick jet, the maximum growth rate decreases as the inner radius increases, irrespective of the surrounding gas viscosity. The degree of instability increases with Weber number for a relatively large viscosity ratio. In contrast, for small viscosity ratio, the growth rate exhibits a dramatic dependence on the surface tension. There is a small Weber number range, which depends on the viscosity ratio, where the flow is stable. The viscosity ratio always stabilizes the flow. However, the dominant wavenumber increases with increasing viscosity ratio. The range of unstable wavenumbers is affected only by the curvature effect. (paper)

  17. Ionization

    International Nuclear Information System (INIS)

    2002-01-01

    This document reprints the text of the French by-law from January 8, 2002 relative to the approval and to the controls and verifications of facilities devoted to the ionizing of food products for human beings and animals. The by-law imposes the operators of such facilities to perform measurements and dosimetric verifications all along the ionization process. (J.S.)

  18. Gauging Metallicity of Diffuse Gas under an Uncertain Ionizing Radiation Field

    Science.gov (United States)

    Chen, Hsiao-Wen; Johnson, Sean D.; Zahedy, Fakhri S.; Rauch, Michael; Mulchaey, John S.

    2017-06-01

    Gas metallicity is a key quantity used to determine the physical conditions of gaseous clouds in a wide range of astronomical environments, including interstellar and intergalactic space. In particular, considerable effort in circumgalactic medium (CGM) studies focuses on metallicity measurements because gas metallicity serves as a critical discriminator for whether the observed heavy ions in the CGM originate in chemically enriched outflows or in more chemically pristine gas accreted from the intergalactic medium. However, because the gas is ionized, a necessary first step in determining CGM metallicity is to constrain the ionization state of the gas which, in addition to gas density, depends on the ultraviolet background radiation field (UVB). While it is generally acknowledged that both the intensity and spectral slope of the UVB are uncertain, the impact of an uncertain spectral slope has not been properly addressed in the literature. This Letter shows that adopting a different spectral slope can result in an order of magnitude difference in the inferred CGM metallicity. Specifically, a harder UVB spectrum leads to a higher estimated gas metallicity for a given set of observed ionic column densities. Therefore, such systematic uncertainties must be folded into the error budget for metallicity estimates of ionized gas. An initial study shows that empirical diagnostics are available for discriminating between hard and soft ionizing spectra. Applying these diagnostics helps reduce the systematic uncertainties in CGM metallicity estimates.

  19. Gauging Metallicity of Diffuse Gas under an Uncertain Ionizing Radiation Field

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hsiao-Wen; Zahedy, Fakhri S. [Department of Astronomy and Astrophysics, The University of Chicago, 5640 S Ellis Avenue, Chicago, IL 60637 (United States); Johnson, Sean D. [Department of Astrophysics, Princeton University, Princeton, NJ (United States); Rauch, Michael; Mulchaey, John S., E-mail: hchen@oddjob.uchicago.edu [The Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

    2017-06-20

    Gas metallicity is a key quantity used to determine the physical conditions of gaseous clouds in a wide range of astronomical environments, including interstellar and intergalactic space. In particular, considerable effort in circumgalactic medium (CGM) studies focuses on metallicity measurements because gas metallicity serves as a critical discriminator for whether the observed heavy ions in the CGM originate in chemically enriched outflows or in more chemically pristine gas accreted from the intergalactic medium. However, because the gas is ionized, a necessary first step in determining CGM metallicity is to constrain the ionization state of the gas which, in addition to gas density, depends on the ultraviolet background radiation field (UVB). While it is generally acknowledged that both the intensity and spectral slope of the UVB are uncertain, the impact of an uncertain spectral slope has not been properly addressed in the literature. This Letter shows that adopting a different spectral slope can result in an order of magnitude difference in the inferred CGM metallicity. Specifically, a harder UVB spectrum leads to a higher estimated gas metallicity for a given set of observed ionic column densities. Therefore, such systematic uncertainties must be folded into the error budget for metallicity estimates of ionized gas. An initial study shows that empirical diagnostics are available for discriminating between hard and soft ionizing spectra. Applying these diagnostics helps reduce the systematic uncertainties in CGM metallicity estimates.

  20. X-ray detector for automatic exposure control using ionization chamber filled with xenon gas

    CERN Document Server

    Nakagawa, A; Yoshida, T

    2003-01-01

    This report refers to our newly developed X-ray detector for reliable automatic X-ray exposure control, which is to be widely used for X-ray diagnoses in various clinical fields. This new detector utilizes an ionization chamber filled with xenon gas, in contrast to conventional X-ray detectors which use ionization chambers filled with air. Use of xenon gas ensures higher sensitivity and thinner design of the detector. The xenon gas is completely sealed in the chamber, so that the influence of the changes in ambient environments is minimized. (author)

  1. Development of a gas-phase field ionization ion source

    International Nuclear Information System (INIS)

    Allan, G.L.; Legge, G.J.F.

    1983-01-01

    A field ionization ion source has been developed to investigate the suitability of using such a source with the Melbourne Proton Microprobe. Operating parameters have been measured, and the source has been found to be brighter than the radiofrequency ion source presently used in the Melbourne 5U Pelletron Accelerator. Improvements to the source geometry to increase the current output are planned

  2. Approximate thermodynamic state relations in partially ionized gas mixtures

    International Nuclear Information System (INIS)

    Ramshaw, John D.

    2004-01-01

    Thermodynamic state relations for mixtures of partially ionized nonideal gases are often approximated by artificially partitioning the mixture into compartments or subvolumes occupied by the pure partially ionized constituent gases, and requiring these subvolumes to be in temperature and pressure equilibrium. This intuitively reasonable procedure is easily shown to reproduce the correct thermal and caloric state equations for a mixture of neutral (nonionized) ideal gases. The purpose of this paper is to point out that (a) this procedure leads to incorrect state equations for a mixture of partially ionized ideal gases, whereas (b) the alternative procedure of requiring that the subvolumes all have the same temperature and free electron density reproduces the correct thermal and caloric state equations for such a mixture. These results readily generalize to the case of partially degenerate and/or relativistic electrons, to a common approximation used to represent pressure ionization effects, and to two-temperature plasmas. This suggests that equating the subvolume electron number densities or chemical potentials instead of pressures is likely to provide a more accurate approximation in nonideal plasma mixtures

  3. Alpha-ionization gas analyzer for air traces in hydrogen or deuterium at atmospheric pressure

    International Nuclear Information System (INIS)

    Mitrofanov, A.V.

    1975-01-01

    The constructional features and the principle of operation of and α-ionization gas analyzer are described. The analyzer is based on a radioactive monometric transducer MP-2 with a plutonium source, which makes it possible to measure the volume admixture of air in H 2 or D 2 in the range from 0 to 30% with an accuracy to about 0.3%. The operating principle of the instrument involves the dependence of the saturation current in the ionization chamber on the molecular weight of the gas analysed. As the output unit of the gas analyzer, either a microamperometer or a recording potentiometer is used. The sensitivity of the gas analyzer is about the same as that of instruments based on the phenomenon of heat conduction. The gas analyzer is explosion proof and reliable in operation, which enables it to compete with thermal gas analyzers [ru

  4. Lyman-continuum leakage as dominant source of diffuse ionized gas in the Antennae galaxy

    Science.gov (United States)

    Weilbacher, Peter M.; Monreal-Ibero, Ana; Verhamme, Anne; Sandin, Christer; Steinmetz, Matthias; Kollatschny, Wolfram; Krajnović, Davor; Kamann, Sebastian; Roth, Martin M.; Erroz-Ferrer, Santiago; Marino, Raffaella Anna; Maseda, Michael V.; Wendt, Martin; Bacon, Roland; Dreizler, Stefan; Richard, Johan; Wisotzki, Lutz

    2018-04-01

    The Antennae galaxy (NGC 4038/39) is the closest major interacting galaxy system and is therefore often studied as a merger prototype. We present the first comprehensive integral field spectroscopic dataset of this system, observed with the MUSE instrument at the ESO VLT. We cover the two regions in this system which exhibit recent star formation: the central galaxy interaction and a region near the tip of the southern tidal tail. In these fields, we detect HII regions and diffuse ionized gas to unprecedented depth. About 15% of the ionized gas was undetected by previous observing campaigns. This newly detected faint ionized gas is visible everywhere around the central merger, and shows filamentary structure. We estimate diffuse gas fractions of about 60% in the central field and 10% in the southern region. We are able to show that the southern region contains a significantly different population of HII regions, showing fainter luminosities. By comparing HII region luminosities with the HST catalog of young star clusters in the central field, we estimate that there is enough Lyman-continuum leakage in the merger to explain the amount of diffuse ionized gas that we detect. We compare the Lyman-continuum escape fraction of each HII region against emission line ratios that are sensitive to the ionization parameter. While we find no systematic trend between these properties, the most extreme line ratios seem to be strong indicators of density bounded ionization. Extrapolating the Lyman-continuum escape fractions to the southern region, we conclude that simply from the comparison of the young stellar populations to the ionized gas there is no need to invoke other ionization mechanisms than Lyman-continuum leaking HII regions for the diffuse ionized gas in the Antennae. FITS images and Table of HII regions are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/611/A95 and at http://muse-vlt.eu/science/antennae/

  5. Heat transfer to a particle exposed to a rarefield ionized-gas flow

    International Nuclear Information System (INIS)

    Chen, X.; He, P.

    1986-01-01

    Analytical results are presented concerning the heat transfer to a spherical particle exposed to a high temperature, ionized- gas flow for the extreme case of free-molecule flow regime. It has been shown that the presence of relative velocity between the particle and the ionized gas reduces the floating potential on the particle, enhances the heat flux and causes appreciably non-uniform distribution of the local heat flux. Pronounced difference is found between metallic and non-metallic particles in the floating potential and the local heat flux distributions, in particular for the case with high gas-flow temperature. Relative contribution of atoms to the total heat flux is dominant for the case of low gas-flow temperature, while the heat flux is mainly caused by ions and electrons for the case of high gas-flow temperature

  6. On the kinetic theory of a fully ionized gas

    International Nuclear Information System (INIS)

    Bezerra Junior, A.G.; Rodbard, M.G.; Kremer, G.M.

    1993-01-01

    An alternative method for kinetic theory recently proposed, that combines the features of the Chapman-Enskog and Grad methods, neither using a solution of the integral equation nor the field equations of the moments, is applied to ionized gases. Like in the Grad method, the deviation from equilibrium of the moments are used. Like in the method of Grad, the deviation from equilibrium of the distribution function is written in terms of the moments of the distribution function, but the constitutive equations follow direct from the Boltzmann equation through the Chapman-Enskog method. (author)

  7. Inverted annular flow experimental study

    International Nuclear Information System (INIS)

    De Jarlais, G.; Ishii, M.

    1985-04-01

    Steady-state inverted annular flow of Freon 113 in up flow was established in a transparent test section. Using a special inlet configuration consisting of long aspect-ratio liquid nozzles coaxially centered within a heated quartz tube, idealized inverted annular flow initial geometry (cylindrical liquid core surrounded by coaxial annulus of gas) could be established. Inlet liquid and gas flowrates, liquid subcooling, and gas density (using various gas species) were measured and varied systematically. The hydrodynamic behavior of the liquid core, and the subsequent downstream break-up of this core into slugs, ligaments and/or droplets of various sizes, was observed. In general, for low inlet liquid velocities it was observed that after the initial formation of roll waves on the liquid core surface, an agitated region of high surface area, with attendant high momentum and energy transfers, occurs. This agitated region appears to propagate downsteam in a quasi-periodic pattern. Increased inlet liquid flow rates, and high gas annulus flow rates tend to diminish the significance of this agitated region. Observed inverted annular flow (and subsequent downstream flow pattern) hydrodynamic behavior is reported, and comparisons are drawn to data generated by previous experimenters studying post-CHF flow

  8. The Application of Resonance-Enhanced Multiphoton Ionization Technique in Gas Chromatography Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Adan Li

    2014-01-01

    Full Text Available Gas chromatography resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (GC/REMPI-TOFMS using a nanosecond laser has been applied to analyze the 16 polycyclic aromatic hydrocarbons (PAHs. The excited-state lifetime, absorption characters, and energy of electronic states of the 16 PAHs were investigated to optimize the ionization yield. A river water sample pretreated by means of solid phase extraction was analyzed to evaluate the performance of the analytical instrument. The results suggested that REMPI is superior to electron impact ionization method for soft ionization and suppresses the background signal due to aliphatic hydrocarbons. Thus, GC/REMPI-TOFMS is a more reliable method for the determination of PAHs present in the environment.

  9. The capability of radial basis function to forecast the volume fractions of the annular three-phase flow of gas-oil-water.

    Science.gov (United States)

    Roshani, G H; Karami, A; Salehizadeh, A; Nazemi, E

    2017-11-01

    The problem of how to precisely measure the volume fractions of oil-gas-water mixtures in a pipeline remains as one of the main challenges in the petroleum industry. This paper reports the capability of Radial Basis Function (RBF) in forecasting the volume fractions in a gas-oil-water multiphase system. Indeed, in the present research, the volume fractions in the annular three-phase flow are measured based on a dual energy metering system including the 152 Eu and 137 Cs and one NaI detector, and then modeled by a RBF model. Since the summation of volume fractions are constant (equal to 100%), therefore it is enough for the RBF model to forecast only two volume fractions. In this investigation, three RBF models are employed. The first model is used to forecast the oil and water volume fractions. The next one is utilized to forecast the water and gas volume fractions, and the last one to forecast the gas and oil volume fractions. In the next stage, the numerical data obtained from MCNP-X code must be introduced to the RBF models. Then, the average errors of these three models are calculated and compared. The model which has the least error is picked up as the best predictive model. Based on the results, the best RBF model, forecasts the oil and water volume fractions with the mean relative error of less than 0.5%, which indicates that the RBF model introduced in this study ensures an effective enough mechanism to forecast the results. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Thermoregulated Nitric Cryosystem for Cooling Gas-Filled Detectors of Ionizing Radiation

    Directory of Open Access Journals (Sweden)

    Zharkov I.P.

    2015-09-01

    Full Text Available Cryosystem for cooling and filling of gas-filled detectors of ionizing radiation with compressed inert gas on the basis of wide-nitrogen cryostat, which provides detetector temperature control in a range of 173 — 293 K and its stabilization with accuracy of ± 1°. The work was carried out within the Ukraine — NATO Program of Collaboration, Grant SfP #984655.

  11. Aerosol ionization gas analyzer for continious detection of toxic compounds in industrial gaseous effluents

    International Nuclear Information System (INIS)

    Groze, Kh.; Dering, Kh.; Gleizberg, F.

    1979-01-01

    In is noted that the problem of the environment protection as well as protection of the personnel at their working places against influence of harmful substances in air, demands continious measuring of an increasing number of harmful substances with provision of high sensitivity and accuracy of measurements. The demands are listed to the gas analyzers developed for these purposes: flexibility towards solution of different problems of measurement; great number of the substances to be measured; acceptable threshold of determination of different substances concentration in air and small measurement error; simplicity of maintanance and technical service and high reliability in exploitation; economy of fabrication and application. The data are given for the aerosol ionization gas analyzer which, in many cases, met the requirements listed. In the gas analyzer described, the analysed substance is converted for measuring its concentration into an aerosol by means of the aerosol generator, especially designed for this substance or group of substances. The produced aerosol is introduced into an ionization chamber with build-in radiation source and caused decrease of the ionization current in it. According to the decrease of the ionization current, concentration of the harmful substance in air is determined. Characteristics and possibilities of the gas analyzer exploitation are given and discussed on the base of the results of determination of some harmful substances concentrations in air in the laboratory conditions and in the real conditions of industrial production and in the health protection system [ru

  12. Development of a sodium ionization detector for sodium-to-gas leaks

    International Nuclear Information System (INIS)

    Swaminathan, K.; Elumalai, G.

    1984-01-01

    A sensitive sodium-to-gas leak detector has been indigenously developed for use in liquid metal cooled fast breeder reactor. The detector relies on the relative ease with which sodium vapour or its aerosols including its oxides and hydroxides can be thermally ionized compared with other possible constituents such as nitrogen, oxygen, water vapour etc. in a carrier gas and is therefore called sodium ionization detector (SID). The ionization current is a measure of sodium concentration in the carrier gas sampled through the detector. Different sensor designs using platinum and rhodium as filament materials in varying sizes were constructed and their responses to different sodium aerosol concentrations in the carrier gas were investigated. Nitrogen was used as the carrier gas. Both the background current and speed of response were found to depend on the diameter of the filament. There was also a particular collector voltage which yielded maximum sensitivity of the detector. The sensor was therefore optimised considering influence of above factors and a detector has been built which demonstrates a sensitivity better than 0.3 nanogram of sodium per cubic centimetre of carrier gas for a signal to background ratio of 1:1. Its usefulness in detecting sodium fires in experimental area was also demonstrated. Currently efforts are under way to improve the life time of the filament used in the above detector. (author)

  13. Collisional energy dependence of molecular ionization by metastable rare gas atoms

    International Nuclear Information System (INIS)

    Martin, R.M.; Parr, T.P.

    1979-01-01

    The collisional energy dependence of several molecular total ionization cross sections by metastable rare gas atoms was studied over the thermal energy region using the crossed molecular beam time-of-flight method. Results are reported for the collision systems He, Ne, and Ar ionizing the geometric isomers cis- and trans-dichloroethylene and ortho- and para-dichlorobenzene. The He ionization cross sections oscillate about an energy dependence of E/sup -1/2/ over the energy range 0.004--1.0 eV, and the Ar*+para-dichlorobenzene cross section oscillates about an energy dependence of E/sup -2/5/ over the energy range 0.011--0.64 eV. The remaining systems are characterized by ''bent'' E/sup -m/ dependences with m values of 0.56--0.70 at low energies changing to 0.07--0.29 at higher energies. Comparison with the slopes of the He* systems and the Ar*+para-dichlorobenzene system shows that the ''bent'' and ''oscillating'' energy dependences are similar except for the form of the cross section functions at the lowest energies. No systematic differences are found between the cross section energy dependences for ionization of different geometric isomers or for ionization by the different metastable rare gas atoms

  14. Multiplate ionization total absorption spectrometer with a compressed gas

    International Nuclear Information System (INIS)

    Baskakov, V.I.; Dolgoshein, B.A.; Kantserov, V.A.

    1978-01-01

    The characteristics of a multiplate total absorption spectrometer working with the compressed xenon (up to 25 atm) containing up to 23 radiation lengths of matter are studied. The dependence of the spectrometer energy resolution on the detecting matter density, on the material and thickness of the absorber plates has been studied. The ability of the spectrometer with a tungsten absorber to select hadrons and electrons with P=6 GeV/c by total energy release and characteristics of the cascade longitudinal development has been also studied. The gas spectrometer as it is shown differs quite slightly from the similar spectrometer with liquid argon as for its time resolution it is much better

  15. Study of ionization losses in He-based gas mixtures

    CERN Document Server

    Borsato, E; Dal Corso, F; Morandin, M; Posocco, M; Stroili, R; Voci, C; Buccheri, A; Ferroni, F; Lacava, F; Lamanna, E; Mazzoni, M A; Morganti, S; Pastore, F C; Piredda, G; Pontecorvo, L

    1999-01-01

    Helium based gas mixtures are particularly interesting since they have a good tracking resolution because of the reduced multiple scattering. We have studied the differential energy loss dE/dx in several mixtures, He-isobutane and He-ethane. We present results from measurements performed with electrons, pions and protons in the momentum range between 1 and 5 GeV/c obtained in a prototype drift chamber with a 3 cm cell. The results show that helium performs well in measuring energy losses for charged particles.

  16. A study of the response of a gas ionization chamber to different sources of ionizing radiation

    International Nuclear Information System (INIS)

    Zamble-Dieguez, F.E.

    1988-05-01

    The response of the TAMU Forward Hadron Calorimeter Chambers to neutrons from a 2 39Pu-Be source was investigated in hope of developing a strategy to reduce the effects of the background events called /open quotes/Texas towers/close quotes/ in the CDF trigger for the next run. The response to a standard ( 5 5Fe γ-ray) energy source was also studied and found to be similar to that of the chambers installed at CDF. In addition, the effects of different sampling gases and intermediate absorbers on the rate of large energy pulses were investigated. The neutron data were compared with the energy spectrum measured in CDF and that simulated using Monte Carlo techniques. It was found that the large energy pulse frequency can be reduced by as much as 50% if a non-hydrogenous sampling gas is used in conjunction with a neutron moderator

  17. Familial Granuloma Annulare

    Directory of Open Access Journals (Sweden)

    Zennure Takci

    2015-09-01

    Full Text Available Granuloma annulare is a benign, asymptomatic, relatively common, often self-limited chronic granulomatos disorder of the skin that can affect both children and adults. The primary skin lesion usually is grouped papules in an enlarging annular shape, with color ranging from flesh-colored to erythematous. The two most common types of granuloma annulare are localized, which typically is found on the lateral or dorsal surfaces of the hands and feet; and disseminated, which is widespread. Rarely, familial cases of granuloma annulare has been reported. Herein, we report two sisters with annular papules and plaques diagnosed as granuloma annulare with the clinical and pathological findings. [J Contemp Med 2015; 5(3.000: 189-191

  18. Velocity Dispersion of Ionized Gas and Multiple Supernova Explosions

    Directory of Open Access Journals (Sweden)

    Vasiliev E. O.

    2015-06-01

    Full Text Available We use 3D numerical simulations to study the evolution of the Hα intensity and velocity dispersion for single and multiple supernova (SN explosions. We find that the IHα– σ diagram obtained for simulated gas flows is similar in shape to that observed in dwarf galaxies. We conclude that colliding SN shells with significant difference in age are responsible for high velocity dispersion that reaches up to ≳ 100 km s−1. Such a high velocity dispersion could be hardly obtained for a single SN remnant. Peaks of velocity dispersion in the IHα– σ diagram may correspond to several isolated or merged SN remnants with moderately different ages. Degrading the spatial resolution in the Hα intensity and velocity dispersion maps makes the simulated IHα– σ diagrams close to those observed in dwarf galaxies not only in shape, but also quantitatively.

  19. Mid-section of a can-annular gas turbine engine with a cooling system for the transition

    Science.gov (United States)

    Wiebe, David J.; Rodriguez, Jose L.

    2015-12-08

    A cooling system is provided for a transition (420) of a gas turbine engine (410). The cooling system includes a cowling (460) configured to receive an air flow (111) from an outlet of a compressor section of the gas turbine engine (410). The cowling (460) is positioned adjacent to a region of the transition (420) to cool the transition region upon circulation of the air flow within the cowling (460). The cooling system further includes a manifold (121) to directly couple the air flow (111) from the compressor section outlet to an inlet (462) of the cowling (460). The cowling (460) is configured to circulate the air flow (111) within an interior space (426) of the cowling (460) that extends radially outward from an inner diameter (423) of the cowling to an outer diameter (424) of the cowling at an outer surface.

  20. In-gas-cell laser ionization studies of plutonium isotopes at IGISOL

    International Nuclear Information System (INIS)

    Pohjalainen, I.; Moore, I.D.; Kron, T.; Raeder, S.; Sonnenschein, V.; Tomita, H.; Trautmann, N.; Voss, A.; Wendt, K.

    2016-01-01

    In-gas-cell resonance laser ionization has been performed on long-lived isotopes of Pu at the IGISOL facility, Jyväskylä. This initiates a new programme of research towards high-resolution optical spectroscopy of heavy actinide elements which can be produced in sufficient quantities at research reactors and transported to facilities elsewhere. In this work a new gas cell has been constructed for fast extraction of laser-ionized elements. Samples of "2"3"8"–"2"4"0","2"4"2Pu and "2"4"4Pu have been evaporated from Ta filaments, laser ionized, mass separated and delivered to the collinear laser spectroscopy station. Here we report on the performance of the gas cell through studies of the mass spectra obtained in helium and argon, before and after the radiofrequency quadrupole cooler-buncher. This provides valuable insight into the gas phase chemistry exhibited by Pu, which has been additionally supported by measurements of ion time profiles. The resulting monoatomic yields are sufficient for collinear laser spectroscopy. A gamma-ray spectroscopic analysis of the Pu samples shows a good agreement with the assay provided by the Mainz Nuclear Chemistry department.

  1. In-gas-cell laser ionization studies of plutonium isotopes at IGISOL

    Science.gov (United States)

    Pohjalainen, I.; Moore, I. D.; Kron, T.; Raeder, S.; Sonnenschein, V.; Tomita, H.; Trautmann, N.; Voss, A.; Wendt, K.

    2016-06-01

    In-gas-cell resonance laser ionization has been performed on long-lived isotopes of Pu at the IGISOL facility, Jyväskylä. This initiates a new programme of research towards high-resolution optical spectroscopy of heavy actinide elements which can be produced in sufficient quantities at research reactors and transported to facilities elsewhere. In this work a new gas cell has been constructed for fast extraction of laser-ionized elements. Samples of 238-240,242Pu and 244Pu have been evaporated from Ta filaments, laser ionized, mass separated and delivered to the collinear laser spectroscopy station. Here we report on the performance of the gas cell through studies of the mass spectra obtained in helium and argon, before and after the radiofrequency quadrupole cooler-buncher. This provides valuable insight into the gas phase chemistry exhibited by Pu, which has been additionally supported by measurements of ion time profiles. The resulting monoatomic yields are sufficient for collinear laser spectroscopy. A gamma-ray spectroscopic analysis of the Pu samples shows a good agreement with the assay provided by the Mainz Nuclear Chemistry department.

  2. Radiative transfer calculations of the diffuse ionized gas in disc galaxies with cosmic ray feedback

    Science.gov (United States)

    Vandenbroucke, Bert; Wood, Kenneth; Girichidis, Philipp; Hill, Alex S.; Peters, Thomas

    2018-05-01

    The large vertical scale heights of the diffuse ionized gas (DIG) in disc galaxies are challenging to model, as hydrodynamical models including only thermal feedback seem to be unable to support gas at these heights. In this paper, we use a three-dimensional Monte Carlo radiation transfer code to post-process disc simulations of the Simulating the Life-Cycle of Molecular Clouds project that include feedback by cosmic rays. We show that the more extended discs in simulations including cosmic ray feedback naturally lead to larger scale heights for the DIG which are more in line with observed scale heights. We also show that including a fiducial cosmic ray heating term in our model can help to increase the temperature as a function of disc scale height, but fails to reproduce observed DIG nitrogen and sulphur forbidden line intensities. We show that, to reproduce these line emissions, we require a heating mechanism that affects gas over a larger density range than is achieved by cosmic ray heating, which can be achieved by fine tuning the total luminosity of ionizing sources to get an appropriate ionizing spectrum as a function of scale height. This result sheds a new light on the relation between forbidden line emissions and temperature profiles for realistic DIG gas distributions.

  3. High spatial and time resolutions with gas ionization detectors

    International Nuclear Information System (INIS)

    Pouthas, J.

    2001-09-01

    This document presents the principles and the characteristics of the gaseous ionisation detectors used in position and timing measurements. The first two parts recall the main notions (electron and ion motions, gaseous amplification, signal formation) and their applications to the proportional counter and the wire chamber. The explanation of the signal formation makes use of the Ramo theorem. The third part is devoted to the different types of wire chambers: drift or cathode strip chambers, TPC (time projection chamber). Some aspects on construction and ageing are also presented. Part 4 is on the detectors in which the multiplication is performed by a 'Parallel Plate' system (PPAC, Pestov counter). Special attention is paid to the RPCs (Resistive Plate Chambers) and their timing resolutions. Part 5 concentrates on 'Micro-pattern detectors' which use different kinds of microstructure for gaseous amplification. The new detectors MICROMEGAS, CAT (compteur a trous) and GEM (gas electron multiplier) and some of their applications are presented. The last part is a bibliography including some comments on the documents. (author)

  4. Quantitative analysis of abused drugs in physiological fluids by gas chromatography/chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    Foltz, R.L.

    1978-01-01

    Methods have been developed for quantitative analysis of commonly abused drugs in physiological fluids using gas chromatography/chemical ionization mass spectrometry. The methods are being evaluated in volunteer analytical and toxicological laboratories, and analytical manuals describing the methods are being prepared. The specific drug and metabolites included in this program are: Δ 9 -tetrahydrocannabinol, methadone, phencyclidine, methaqualone, morphine, amphetamine, methamphetamine, mescaline, 2,5-dimethoxy-4-methyl amphetamine, cocaine, benzoylecgonine, diazepam, and N-desmethyldiazepam. The current analytical methods utilize relatively conventional instrumentation and procedures, and are capable of measuring drug concentrations as low as 1 ng/ml. Various newer techniques such as sample clean-up by high performance liquid chromatography, separation by glass capillary chromatography, and ionization by negative ion chemical ionization are being investigated with respect to their potential for achieving higher sensitivity and specificity, as well as their ability to facilitate simultaneous analysis of more than one drug and metabolite. (Auth.)

  5. Synthesis of refractory organic matter in the ionized gas phase of the solar nebula.

    Science.gov (United States)

    Kuga, Maïa; Marty, Bernard; Marrocchi, Yves; Tissandier, Laurent

    2015-06-09

    In the nascent solar system, primitive organic matter was a major contributor of volatile elements to planetary bodies, and could have played a key role in the development of the biosphere. However, the origin of primitive organics is poorly understood. Most scenarios advocate cold synthesis in the interstellar medium or in the outer solar system. Here, we report the synthesis of solid organics under ionizing conditions in a plasma setup from gas mixtures (H2(O)-CO-N2-noble gases) reminiscent of the protosolar nebula composition. Ionization of the gas phase was achieved at temperatures up to 1,000 K. Synthesized solid compounds share chemical and structural features with chondritic organics, and noble gases trapped during the experiments reproduce the elemental and isotopic fractionations observed in primitive organics. These results strongly suggest that both the formation of chondritic refractory organics and the trapping of noble gases took place simultaneously in the ionized areas of the protoplanetary disk, via photon- and/or electron-driven reactions and processing. Thus, synthesis of primitive organics might not have required a cold environment and could have occurred anywhere the disk is ionized, including in its warm regions. This scenario also supports N2 photodissociation as the cause of the large nitrogen isotopic range in the solar system.

  6. Influence of gas mixture and primary ionization on the performance of limit streamer mode tubes

    International Nuclear Information System (INIS)

    An Jigang; Anderson, K.J.; Merritt, F.S.; Oreglia, M.; Pilcher, J.E.; Possoz, A.; Schappert, W.; Chicago Univ., IL

    1988-01-01

    We report a study of the dependence of limited streamer mode operation on gas composition. Results are given for the plateau onset voltage, plateau length, charge versus voltage, charge spectra and pulse width for various fractions of (Ar, CO 2 , pentane) and (Ar, isobutane). In addition, a series of argon-free strong quenching gas mixtures has been studied which have very attractive characteristics. Chamber lifetime tests for these are also reported. As part of a study of the nature of the limited streamer mode mechanism, the response to X-rays and minimum ionizing particles are compared and differences noted. The character of the primary ionization is found to have a clear effect on the chamber response even in the streamer region. (orig.)

  7. Studies of Flow in Ionized Gas: Historical Perspective, Contemporary Experiments, and Applications

    International Nuclear Information System (INIS)

    Popovic, S.; Vuskovic, L.

    2007-01-01

    Since the first observations that a very small ionized fraction (order of 1 ppm) could strongly affect the gas flow, numerous experiments with partially or fully wall-free discharges have demonstrated the dispersion of shock waves, the enhancement of lateral forces in the flow, the prospects of levitation, and other aerodynamic effects with vast potential of application. A review of physical effects and observations are given along with current status of their interpretation. Special attention will be given to the physical problems of energy efficiency in generating wall-free discharges and the phenomenology of filamentary discharges. Comments and case examples are given on the current status of availability of necessary data for modelling and simulation of the aerodynamic phenomena in weakly ionized gas

  8. Development of residual gas ionization profile monitor for high intensity proton beams

    CERN Document Server

    Sato, Y; Hirose, E; Ieiri, M; Igarashi, Y; Inaba, S; Katoh, Y; Minakawa, M; Noumi, H; Saitó, M; Suzuki, Y; Takahashi, H; Takasaki, M; Tanaka, K; Toyoda, A; Yamada, Y; Yamanoi, Y; Watanabe, H

    2006-01-01

    Nondestructive beam profile monitor utilizing ionizations of residual gas has been developed for continuous monitoring of 3?0(J-PARC). Knock-on electrons produced in the ionizations of residual gas vacuumed to 1 Pa are collected with a uniform electric field applied between electrodes. Applying a uniform electric field parallel to the electric field is essential to reduce diffusion of electrons crossing over magnetic flux. A prototype monitor has been constructed and installed in EP2-C beam line at KEK 12 GeV proton synchrotron (12 Ge V-PS). The profiles measured with the present monitor agree with the ones measured with the existing destructive profile monitor. The present monitor shows sufficient performances as a candidate of the profile monitor at J-PARC. In the present article, the working principle of the present monitor, the results of test experiments, and further developments are described in detail.

  9. Subcutaneous granuloma annulare

    Directory of Open Access Journals (Sweden)

    Dhar Sandipan

    1994-01-01

    Full Text Available Two cases of subcutaneos granuloma annulare are reported. Clinical presentation was in the form of hard subcutaneous nodules; histopathology confirmed the clinical diagnosis. The cases were unique because of onset in adult hood, occurrence over unusual sites and absence of classical lesions of granuloma annulare elsewhere.

  10. Subcutaneous granuloma annulare

    Directory of Open Access Journals (Sweden)

    Dhar Sandipan

    1993-01-01

    Full Text Available Two cases of subcutaneous granuloma annulare are reported. Clinical presentation was in the form of hard subcutaneous nodules, histopathology confirmed the clinical diagnosis. The cases were unique because of onset in adult age, occurrence over unusual sites and absence of classical lesions of granuloma annulare elsewhere.

  11. Image simulation of high-speed imaging by high-pressure gas ionization detector

    International Nuclear Information System (INIS)

    Miao Jichen; Liu Ximing; Wu Zhifang

    2005-01-01

    The signal of the neighbor pixels is cumulated in Freight Train Inspection System because data fetch time is shorter than ion excursion time. This paper analyzes the pertinency of neighbor pixels and designs computer simulation method to generate some emulate images such as indicator image. The result indicates the high-pressure gas ionization detector can be used in high-speed digital radiography field. (authors)

  12. Thermal boundary conditions for electrons in a weakly ionized gas near a catalytic wall

    International Nuclear Information System (INIS)

    Chekmarev, I.

    1981-01-01

    A technique of matched asymptotic expansions is used to examine the derivation of hydrodynamic transport equations for the external region of a weakly ionized multitemperature gas near an absorbing and conducting wall. An approximate moment solution is constructed for the Knudsen boundary layer. The conditions for the matching of the external and internal expansions lead to a new form of the hydrodynamic boundary conditions, from which the singular behavior of the energy equation for electrons near the wall has been eliminated

  13. Breakdown voltage reduction by field emission in multi-walled carbon nanotubes based ionization gas sensor

    Energy Technology Data Exchange (ETDEWEB)

    Saheed, M. Shuaib M.; Muti Mohamed, Norani; Arif Burhanudin, Zainal, E-mail: zainabh@petronas.com.my [Centre of Innovative Nanostructures and Nanodevices, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2014-03-24

    Ionization gas sensors using vertically aligned multi-wall carbon nanotubes (MWCNT) are demonstrated. The sharp tips of the nanotubes generate large non-uniform electric fields at relatively low applied voltage. The enhancement of the electric field results in field emission of electrons that dominates the breakdown mechanism in gas sensor with gap spacing below 14 μm. More than 90% reduction in breakdown voltage is observed for sensors with MWCNT and 7 μm gap spacing. Transition of breakdown mechanism, dominated by avalanche electrons to field emission electrons, as decreasing gap spacing is also observed and discussed.

  14. Experimental analysis of heat conduction in a high diameter ratio annular gap filled with a rarefied gas

    International Nuclear Information System (INIS)

    Chalabi, H; Lorenzini, M; Morini, G L; Saraceno, L; Boccardi, G; Celata, G P

    2012-01-01

    A first experimental attempt has been realized in order to measure the heat transfer between a heated platinum wire having a diameter (d) of 0.15 mm, disposed along the axis of a cylindrical shell in stainless steel having an inner diameter (D) of 100 mm, and air from atmospheric conditions down to 10 −3 mbar. Temperature differences between the wire and the external stainless steel cylindrical shell in the range of 50–125 K were imposed and the heat power transferred from the wire to the surround was measured as a function of the gas pressure. The experimental results demonstrates that for an accurate measurement of the heat conduction when the pressure goes down to 0.05 mbar is very important to be able to quantify accurately the radiative contribution which becomes predominant at low pressure. The main limitations of the test rig described in this paper have been analysed in order to highlight the modifications which can be suggested to obtain experimental results comparable with theoretical models.

  15. The identification and rejection of energy-degraded events in gas ionization counters

    International Nuclear Information System (INIS)

    Ophel, T.R.; Fifield, L.K.; Catford, W.N.; Orr, N.A.; Woods, C.L.; Harding, A.; Clarkson, G.P.

    1988-05-01

    A common feature of the measurement of charged particles with gas detectors is the presence of a small fraction of events (∼0.1-0.2%) for which significantly less than total ionization is recorded. These events cause an energy tailing that can seriously impair the identification functions of gas detectors used either to instrument the focal plane of magnetic spectrometers or for accelerator mass spectrometry. The anomalous, energy-degraded events are shown to arise both from reactions between the incident ions and the detector gas and, more importantly from the scattering of ions by the gas. It is demonstrated that an appropriate detector configuration provides the means to reject most of the anomalous events, allowing the measurement of very low cross-section reactions without significant background interference from such events

  16. INTEGRAL-FIELD STELLAR AND IONIZED GAS KINEMATICS OF PECULIAR VIRGO CLUSTER SPIRAL GALAXIES

    International Nuclear Information System (INIS)

    Cortés, Juan R.; Hardy, Eduardo; Kenney, Jeffrey D. P.

    2015-01-01

    We present the stellar and ionized gas kinematics of 13 bright peculiar Virgo cluster galaxies observed with the DensePak Integral Field Unit at the WIYN 3.5 m telescope in order to look for kinematic evidence that these galaxies have experienced gravitational interactions or gas stripping. Two-dimensional maps of the stellar velocity V, stellar velocity dispersion σ, and the ionized gas velocity (Hβ and/or [O III]) are presented for the galaxies in the sample. The stellar rotation curves and velocity dispersion profiles are determined for 13 galaxies, and the ionized gas rotation curves are determined for 6 galaxies. Misalignments between the optical and kinematical major axes are found in several galaxies. While in some cases this is due to a bar, in other cases it seems to be associated with gravitational interaction or ongoing ram pressure stripping. Non-circular gas motions are found in nine galaxies, with various causes including bars, nuclear outflows, or gravitational disturbances. Several galaxies have signatures of kinematically distinct stellar components, which are likely signatures of accretion or mergers. For all of our galaxies, we compute the angular momentum parameter λ R . An evaluation of the galaxies in the λ R ellipticity plane shows that all but two of the galaxies have significant support from random stellar motions, and have likely experienced gravitational interactions. This includes some galaxies with very small bulges and truncated/compact Hα morphologies, indicating that such galaxies cannot be fully explained by simple ram pressure stripping, but must have had significant gravitational encounters. Most of the sample galaxies show evidence for ICM-ISM stripping as well as gravitational interactions, indicating that the evolution of a significant fraction of cluster galaxies is likely strongly impacted by both effects

  17. Neutron accelerator tube having improved ionization section

    International Nuclear Information System (INIS)

    Givens, W.W.

    1982-01-01

    A neutron accelerator tube is described having a target section, an ionization section, and a replenisher section for supplying accelerator gas to the ionization section. The ionization section is located between the target and the replenisher section and includes an ionization chamber adapted to receive accelerator gas from the replenisher section. The ionization section further includes spaced cathodes having opposed active surfaces exposed to the interior of the ionization chamber. An anode is located intermediate the cathodes whereby in response to an applied positive voltage, electrons created by field emission are transmitted between the opposed active surfaces of the cathodes and produce the emission of secondary electrons. The active surface of at least one of the cathodes is formulated of a material having a secondary electron emission factor of at least one cathode member located in the tube adjacent to th replenisher section may have a protuberant portion extending axially into the ionization chamber. The other cathode spaced from the first cathode member in the direction of the target has an aperture therein along the axis of the protuberant portion. An annular magnet extends around the exterior of the ionization chamber and envelops the anode member. Means are provided to establish a high permeability magnetic flux path extending outwardly from the opposed poles from the magnet to the active surfaces of the cathode members

  18. The sensitivity and dynamic response of field ionization gas sensor based on ZnO nanorods

    International Nuclear Information System (INIS)

    Min Jiahua; Liang Xiaoyan; Wang Bin; Wang Linjun; Zhao Yue; Shi Weimin; Xia Yiben

    2011-01-01

    Field ionization gas sensors based on ZnO nanorods (50–300 nm in diameter, and 3–8 μm in length) with and without a buffer layer were fabricated, and the influence of the orientation of nano-ZnO on the ionization response of devices was discussed, including the sensitivity and dynamic response of the ZnO nanorods with preferential orientation. The results indicated that ZnO nanorods as sensor anode could dramatically decrease the breakdown voltage. The XRD and SEM images illustrated that nano-ZnO with a ZnO buffer layer displayed high c-axis orientation, which helps to significantly reduce the breakdown voltage. Device A based on ZnO nanorods with a ZnO buffer layer could distinguish toluene and acetone. The dynamic responses of device A to the NO x compounds presented the sensitivity of 0.045 ± 0.007 ppm/pA and the response speed within 17–40 s, and indicated a linear relationship between NO x concentration and current response at low NO x concentrations. In addition, the dynamic responses to benzene, isopropyl alcohol, ethanol, and methanol reveals that the device has higher sensitivity to gas with larger static polarizability and lower ionization energy.

  19. Gas chromatography interfaced with atmospheric pressure ionization-quadrupole time-of-flight-mass spectrometry by low-temperature plasma ionization

    DEFF Research Database (Denmark)

    Norgaard, Asger W.; Kofoed-Sorensen, Vivi; Svensmark, Bo

    2013-01-01

    A low temperature plasma (LTP) ionization interface between a gas chromatograph (GC) and an atmospheric pressure inlet mass spectrometer, was constructed. This enabled time-of-flight mass spectrometric detection of GC-eluting compounds. The performance of the setup was evaluated by injection...

  20. Imaging spectrophotometry of ionized gas in NGC 1068. I - Kinematics of the narrow-line region

    Science.gov (United States)

    Cecil, Gerald; Bland, Jonathan; Tully, R. Brent

    1990-01-01

    The kinematics of collisionally excited forbidden N II 6548, 6583 across the inner 1 arcmin diameter of the nearby Seyfert galaxy NGC 1068 is mapped using an imaging Fabry-Perot interferometer and low-noise CCD. The stack of monochromatic images, which spatially resolved the high-velocity gas, was analyzed for kinematic and photometric content. Profiles agree well with previous long-slit work, and their complete spatial coverage makes it possible to constrain the gas volume distribution. It is found that the narrow-line region is distributed in a thick center-darkened, line-emitting cylinder that envelopes the collimated radio jet. Three distinct kinematic subsystems, of which the cylinder is composed, are discussed in detail. Detailed behavior of the emission-line profiles, at the few points in the NE quadrant with simple kinematics, argues that the ionized gas develops a significant component of motion perpendicular to the jet axis.

  1. Ionization instabilities of an electromagnetic wave propagating in a tenuous gas

    International Nuclear Information System (INIS)

    Bian Zhigang; Antonsen, Thomas M. Jr.

    2001-01-01

    A theory is developed to study the scattering instability that occurs when a laser pulse propagates through and ionizes a gas. The instability is due to the intensity dependence of the ionization rate, which leads to a transversely structured free electron density. The instability is convective in the frame of the laser pulse, but can have a relatively short growth length scaling as L g ∼k 0 /k p 2 , where k 0 is the laser wave number, k p 2 =ω p 2 /c 2 and ω p is the plasma frequency. The most unstable perturbations correspond to a scattering angle for which the transverse wave number is around the plasma wave number, k p . The scattered light is frequency upshifted. The comparison between simple analytic theory and numerical simulation shows good agreement

  2. Fabrication of gas sensor based on field ionization from SWCNTs with tripolar microelectrode

    Science.gov (United States)

    Cai, Shengbing; Zhang, Yong; Duan, Zhemin

    2012-12-01

    We report the nanofabrication of a sulfur dioxide (SO2) sensor with a tripolar on-chip microelectrode utilizing a film of single-walled carbon nanotubes (SWCNTs) as the field ionization cathode, where the ion flow current and the partial discharge current generated by the field ionization process of gaseous molecules can be gauged to gas species and concentration. The variation of the sensitivity is less than 4% for all of the tested devices, and the sensor has selectivity against gases such as He, NO2, CO, H2, SO2 and O2. Further, the sensor response presents well-defined and reproducible linear behavior with regard to concentration in the range investigated and a detection limitation of tripolar on-chip microelectrode with SWCNTs as a cathode exhibits an impressive performance with respect to stability and anti-oxidation behavior, which are significantly better than had been possible before in the traditional bipolar sensor under explicit circumstances at room temperature.

  3. The Electron Temperature of a Partially Ionized Gas in an Electric Field

    International Nuclear Information System (INIS)

    Robben, F.

    1968-03-01

    The electron temperature of a partially ionized gas in an electric field can be determined by the collision rate for momentum transfer and the collision rate for energy transfer. Mean values of these rates are defined such that a simple expression for the electron temperature is obtained, and which depends, among other things, on the ratio of these mean rates. This ratio is calculated in the Lorentz approximation for power law cross sections, and also as a function of the degree of ionization for a helium plasma. It is pointed out that the complete results of refined transport theory can be used in calculating electron mobility and electron temperature in a multicomponent plasma without undue difficulty

  4. The Electron Temperature of a Partially Ionized Gas in an Electric Field

    Energy Technology Data Exchange (ETDEWEB)

    Robben, F

    1968-03-15

    The electron temperature of a partially ionized gas in an electric field can be determined by the collision rate for momentum transfer and the collision rate for energy transfer. Mean values of these rates are defined such that a simple expression for the electron temperature is obtained, and which depends, among other things, on the ratio of these mean rates. This ratio is calculated in the Lorentz approximation for power law cross sections, and also as a function of the degree of ionization for a helium plasma. It is pointed out that the complete results of refined transport theory can be used in calculating electron mobility and electron temperature in a multicomponent plasma without undue difficulty.

  5. Annular pancreas (image)

    Science.gov (United States)

    Annular pancreas is an abnormal ring or collar of pancreatic tissue that encircles the duodenum (the part of the ... intestine that connects to stomach). This portion of pancreas can constrict the duodenum and block or impair ...

  6. Switch-shock wave structure in a magnetized partly-ionized gas

    International Nuclear Information System (INIS)

    Cramer, N.F.

    1975-01-01

    The effect of the interaction of plasma and neutral gas on the structure of switch-type shock waves propagating in a partly-ionized gas is studied. These shocks, in which the magnetic field is perpendicular to the shock front either upstream or downstream, exhibit a spiralling behaviour of the magnetic field in the shock transition region, if the Hall term is important in the Ohm's law. Observations of this behaviour for shocks propagating into a plasma with a residual neutral content of about 15% has implied an anomalously high resistivity of the plasma. We show that this can be partly explained by considering the collisions of ions with the neutral atoms in a magnetic field. We show that the extra dissipation due to the increase in resistivity goes primarily to the ions and neutrals. Thus even in the absence of viscous dissipation within each species, the heavy particles can be appreciably heated in a shock propagating into a partly-ionized gas in a magnetic field. (author)

  7. Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

    International Nuclear Information System (INIS)

    Saheed, Mohamed Shuaib Mohamed; Mohamed, Norani Muti; Burhanudin, Zainal Arif

    2012-01-01

    Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 μm. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 μm can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

  8. Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

    Energy Technology Data Exchange (ETDEWEB)

    Saheed, Mohamed Shuaib Mohamed; Mohamed, Norani Muti; Burhanudin, Zainal Arif [Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Fundamental and Applied Science, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia)

    2012-09-26

    Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 {mu}m. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 {mu}m can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

  9. The SAURON project : XVI. On the sources of ionization for the gas in elliptical and lenticular galaxies

    NARCIS (Netherlands)

    Sarzi, Marc; Shields, Joseph C.; Schawinski, Kevin; Jeong, Hyunjin; Shapiro, Kristen; Bacon, Roland; Bureau, Martin; Cappellari, Michele; Davies, Roger L.; de Zeeuw, P. Tim; Emsellem, Eric; Falcon-Barroso, Jesus; Krajnovic, Davor; Kuntschner, Harald; McDermid, Richard M.; Peletier, Reynier F.; van den Bosch, Remco C. E.; van de Ven, Glen; Yi, Sukyoung K.

    Following our study on the incidence, morphology and kinematics of the ionized gas in early-type galaxies, we now address the question of what is powering the observed nebular emission. To constrain the likely sources of gas excitation, we resort to a variety of ancillary data we draw from

  10. The SAURON project - XVI. On the sources of ionization for the gas in elliptical and lenticular galaxies

    NARCIS (Netherlands)

    Sarzi, Marc; Shields, Joseph C.; Schawinski, Kevin; Jeong, Hyunjin; Shapiro, Kristen; Bacon, Roland; Bureau, Martin; Cappellari, Michele; Davies, Roger L.; de Zeeuw, P. Tim; Emsellem, Eric; Falcón-Barroso, Jesús; Krajnović, Davor; Kuntschner, Harald; McDermid, Richard M.; Peletier, Reynier F.; van den Bosch, Remco C. E.; van de Ven, Glen; Yi, Sukyoung K.

    Following our study on the incidence, morphology and kinematics of the ionized gas in early-type galaxies, we now address the question of what is powering the observed nebular emission. To constrain the likely sources of gas excitation, we resort to a variety of ancillary data we draw from

  11. Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

    Science.gov (United States)

    Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

    2002-08-25

    Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

  12. Neutron accelerator tube having improved ionization section

    International Nuclear Information System (INIS)

    Givens, W.W.

    1981-01-01

    A neutron accelerator tube having a target section, an ionization section, and a replenisher section for supplying accelerator gas to the ionization section. The ionization section is located between the target and the replenisher section and includes an ionization chamber adapted to receive accelerator gas from the replenisher section. The ionization section further includes spaced cathodes having opposed active surfaces exposed to the interior of the ionization chamber. An anode is located intermediate the cathodes whereby in response to an applied positive voltage, electrons created by field emmission are transmitted between the opposed active surfaces of the cathodes and produce the emission of secondary electrons. The active surface of at least one of the cathodes is formulated of a material having a secondary electron emission factor of at least 2. One cathode member located in the tube adjacent to the replenisher section may have a protuberant portion extending axially into the ioization chamber. The other cathode spaced from the first cathode member in the direction of the target has an aperture therein along the axis of the protuberant portion. An annular magnet extends around the exterior of the ionization chamber and envelops the anode member. Means are provided to establish a high permeability magnetic flux path extending outwardly from the opposed poles from the magnet to the active surfaces of the cathode members

  13. A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge.

    Science.gov (United States)

    Kirk, Ansgar T; Last, Torben; Zimmermann, Stefan

    2017-02-03

    In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75×60×25mm 3 and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Ceramic gas turbine shroud

    Science.gov (United States)

    Shi, Jun; Green, Kevin E.

    2014-07-22

    An example gas turbine engine shroud includes a first annular ceramic wall having an inner side for resisting high temperature turbine engine gasses and an outer side with a plurality of radial slots. A second annular metallic wall is positioned radially outwardly of and enclosing the first annular ceramic wall and has a plurality of tabs in communication with the slot of the first annular ceramic wall. The tabs of the second annular metallic wall and slots of the first annular ceramic wall are in communication such that the first annular ceramic wall and second annular metallic wall are affixed.

  15. Development of gas ionization chambers with coplanar electrodes for alpha-ray spectrometry

    International Nuclear Information System (INIS)

    Iwasaki, Kenta; Tanaka, Naomichi; Murakami, Kohei; Hasebe, Nobuyuki; Kusano, Hiroki; Shibamura, Eido; Miyajima, Mitsuhiro

    2016-01-01

    A large-area alpha-ray spectrometer is required to measure the low level alpha emitters in environmental samples, which may be distributed in the vicinity of nuclear power plants. A gas ionization chamber with a coplanar electrode has attractive features such as with mechanical ruggedness, easy handling, easy fabrication of large electrode, and relatively well-known performance. We have investigated the performance of a gas ionization chamber with a coplanar electrode for alpha-ray spectrometry, particularly in the energy resolution. The present experiment shows that the energy resolution in the full width at half maximum (FWHM) is 129 keV (= 2.7%) for alpha-rays from Np with an energy of 4.78 MeV, 120 keV (= 2.2%) for those with 5.49 MeV from Am, and 109 keV (= 1.9%) for those with 5.81 MeV from Cm. It is found that the energy resolution obtained at the present experiment is dominated in the electronic noise caused by the large capacitance existed between the collecting anode (CA) and non-collecting anode (NCA) in the coplanar electrode. (author)

  16. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

    CERN Document Server

    Rondo, L.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

    2016-01-01

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosolnucleation. Based on quantum chemical calculations it has been suggested that the quantitative detectionof gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased inthe presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was setup at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection ofH2SO4in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time inthe CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF(Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutralsulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presenceof dimethylamine (<5 to 70 pptv) the sulfuric acid monomer measured by the CIMS...

  17. Collisions of fast multicharged ions in gas targets: charge transfer and ionization

    International Nuclear Information System (INIS)

    Schlachter, A.S.

    1981-05-01

    Measurements of cross sections for charge transfer and ionization of H 2 and rare-gas targets have been made with fast, highly stripped projectiles in charge states as high as 59+. We have found an empirical scaling rule for electron-capture cross section in H 2 valid at energies above 275 keV/amu. Similar scaling might exist for other target gases. Cross sections are generally in good agreement with theory. We have found a scaling rule for electron loss from H in collisions with a fast highly stripped projectile, based on Olson's classical-trajectory Monte-Carlo calculations, and confirmed by measurements in an H 2 target. We have found a similar scaling rule for net ionization of rare-gas targets, based on Olson's CTMC calculations and the independent-electron model. Measurements are essentially consistent with the scaled cross sections. Calculations and measurements of recoil-ion charge-state spectra show large cross sections for the production of highly charged slow recoil ions

  18. Classical electron ionization mass spectra in gas chromatography/mass spectrometry with supersonic molecular beams.

    Science.gov (United States)

    Gordin, Alexander; Fialkov, Alexander B; Amirav, Aviv

    2008-09-01

    A major benefit of gas chromatography/mass spectrometry (GC/MS) with a supersonic molecular beam (SMB) interface and its fly-through ion source is the ability to obtain electron ionization of vibrationally cold molecules (cold EI), which show enhanced molecular ions. However, GC/MS with an SMB also has the flexibility to perform 'classical EI' mode of operation which provides mass spectra to mimic those in commercial 70 eV electron ionization MS libraries. Classical EI in SMB is obtained through simple reduction of the helium make-up gas flow rate, which reduces the SMB cooling efficiency; hence the vibrational temperatures of the molecules are similar to those in traditional EI ion sources. In classical EI-SMB mode, the relative abundance of the molecular ion can be tuned and, as a result, excellent identification probabilities and very good matching factors to the NIST MS library are obtained. Classical EI-SMB with the fly-through dual cage ion source has analyte sensitivity similar to that of the standard EI ion source of a basic GC/MS system. The fly-through EI ion source in combination with the SMB interface can serve for cold EI, classical EI-SMB, and cluster chemical ionization (CCI) modes of operation, all easily exchangeable through a simple and quick change (not involving hardware). Furthermore, the fly-through ion source eliminates sample scattering from the walls of the ion source, and thus it offers full sample inertness, tailing-free operation, and no ion-molecule reaction interferences. It is also robust and enables increased column flow rate capability without affecting the sensitivity.

  19. Sediment particle entrainment in an obstructed annular

    Energy Technology Data Exchange (ETDEWEB)

    Loureiro, Bruno Venturini; Siqueira, Renato do Nascimento [Faculdade do Centro Leste (UCL), Serra, ES (Brazil). Lab. de Fenomenos de Transporte], e-mail: brunovl@ucl.br, e-mail: renatons@ucl.br

    2006-07-01

    Flow in an annular region with internal cylinder rotation is a classic problem in fluid mechanics and has been widely studied. Besides its importance as a fundamental problem, flow in annular regions has several practical applications. This project was motivated by an application of this kind of flow to the drilling of oil and gas wells. In this work, an erosion apparatus was constructed in order to study the effect of the internal cylinder rotation on particle entrainment in an obstructed annular space and bed package as well. The study also analyzed the influence of height of the particles bed on the process performance. The experiment was designed so that the internal cylinder rotation could be measured by an encoder. The fluid temperature was measured by a thermocouple and the experiments were carried out at the temperature of 25 deg C. The study revealed that the particle entrainment for the height of the bed that is close to the center of the cylinders is negligible and the internal cylinder rotation provokes the movement and packing of the bed. For lower height of the bed, with same dimension of the annular gap, the particle entrainment process was satisfactory and the bed compaction was smaller than in the previous case, leading to a more efficient cleaning process in the annular space. (author)

  20. Collisions of highly stripped ions at MeV energies in gas targets: charge transfer and ionization

    International Nuclear Information System (INIS)

    Schlachter, A.S.

    1980-01-01

    Cross sections have been measured for charge transfer and ionization in H 2 and rare-gas targets by fast, highly ionized carbon, iron, niobium, and lead ions in charge states +3 to +59, with energies in the range 0.1 to 4.8 MeV/amu. Experimental results are compared with classical-trajectory calculations; agreement is generally good. For a given target, the cross sections for net ionization reduce to a common curve when plotted as cross section divided by charge state versus energy per nucleon divided by charge state

  1. Radiation effects on polymer materials. Ionizing radiation induces degradation or improvement? (2) Gas evolution by irradiation

    International Nuclear Information System (INIS)

    Sasuga, Tsuneo

    2005-01-01

    The present article reviews gas evolution from organic polymers induced by ionizing radiations, focusing on gamma-ray irradiation of PE (polyethylene) and PP (polypropylene)-model compounds at temperatures from -77 to 55degC. In the polyolefins, the main gas evolved by irradiation is hydrogen with G-value of 3-4 at room temperatures and G(H 2 ) is 1.8 at 77K. For PE, G(H 2 ) is higher for the low-density PE than for higher-density PE. For the halogenated polymers as PVC, etc., evolved gas is hydrogen halogenated: G(HCl)=6.8 for PVC. For the case where the irradiation is accompanied with the oxidation of polymers, the de-oxygenation and formation of carboxylic radicals are remarkably high and known to emit a bad smell which depends on the thickness of oxidized layers. In conclusion, the gas evolution can be estimated by considering the molecular structure of polymer materials. (S.Ohno)

  2. Gas chromatography with simultaneous detection: Ultraviolet spectroscopy, flame ionization, and mass spectrometry.

    Science.gov (United States)

    Gras, Ronda; Luong, Jim; Haddad, Paul R; Shellie, Robert A

    2018-05-08

    An effective analytical strategy was developed and implemented to exploit the synergy derived from three different detector classes for gas chromatography, namely ultraviolet spectroscopy, flame ionization, and mass spectrometry for volatile compound analysis. This strategy was achieved by successfully hyphenating a user-selectable multi-wavelength diode array detector featuring a positive temperature coefficient thermistor as an isothermal heater to a gas chromatograph. By exploiting the non-destructive nature of the diode array detector, the effluent from the detector was split to two parallel detectors; namely a quadrupole mass spectrometer and a flame ionization detector. This multi-hyphenated configuration with the use of three detectors is a powerful approach not only for selective detection enhancement but also for improvement in structural elucidation of volatile compounds where fewer fragments can be obtained or for isomeric compound analysis. With the diode array detector capable of generating high resolution gas phase spectra, the information collected provides useful confirmatory information without a total dependence on the chromatographic separation process which is based on retention time. This information-rich approach to chromatography is achieved without incurring extra analytical time, resulting in improvements in compound identification accuracy, analytical productivity, and cost. Chromatographic performance obtained from model compounds was found to be acceptable with a relative standard deviation of the retention times of less than 0.01% RSD, and a repeatability at two levels of concentration of 100 and 1000 ppm (v/v) of less than 5% (n = 10). With this configuration, correlation of data between the three detectors was simplified by having near identical retention times for the analytes studied. Copyright © 2018 Elsevier B.V. All rights reserved.

  3. Preliminary study of silica aerogel as a gas-equivalent material in ionization chambers

    Science.gov (United States)

    Caresana, M.; Zorloni, G.

    2017-12-01

    Since about two decades, a renewed interest on aerogels has risen. These peculiar materials show fairly unique properties. Thus, they are under investigation for both scientific and commercial purposes and new optimized production processes are studied. In this work, the possibility of using aerogel in the field of radiation detection is explored. The idea is to substitute the gas filling in a ionization chamber with the aerogel. The material possesses a density about 100 times greater than ambient pressure air. Where as the open-pore structure should allow the charge carriers to move freely. Small hydrophobic silica aerogel samples were studied. A custom ionization chamber, capable of working both with aerogel or in the classic gas set up, was built. The response of the chamber in current mode was investigated using an X-ray tube. The results obtained showed, under proper conditions, an enhancement of about 60 times of the current signal in the aerogel configuration with respect to the classic gas one. Moreover, some unusual behaviours were observed, i.e. time inertia of the signal and super-/sub-linear current response with respect to the dose rate. While testing high electric fields, aerogel configuration seemed to enhance the Townsend's effects. In order to represent the observed trends, a trapping-detrapping model is proposed, which is capable to predict semi-empirically the steady state currents measured. The time evolution of the signal is semi-quantitatively represented by the same model. The coefficients estimated by the fits are in agreement with similar trapping problems in the literature. In particular, a direct comparison between the benchmark of the FET silica gates and aerogel case endorses the idea that the same type of phenomenon occurs in the studied case.

  4. Parametric Investigation of Miniaturized Cylindrical and Annular Hall Thrusters

    International Nuclear Information System (INIS)

    Smirnov, A.; Raitses, Y.; Fisch, N.J.

    2002-01-01

    Conventional annular Hall thrusters become inefficient when scaled to low power. An alternative approach, a 2.6-cm miniaturized cylindrical Hall thruster with a cusp-type magnetic field distribution, was developed and studied. Its performance was compared to that of a conventional annular thruster of the same dimensions. The cylindrical thruster exhibits discharge characteristics similar to those of the annular thruster, but it has a much higher propellant ionization efficiency. Significantly, a large fraction of multi-charged xenon ions might be present in the outgoing ion flux generated by the cylindrical thruster. The operation of the cylindrical thruster is quieter than that of the annular thruster. The characteristic peak in the discharge current fluctuation spectrum at 50-60 kHz appears to be due to ionization instabilities. In the power range 50-300 W, the cylindrical and annular thrusters have comparable efficiencies (15-32%) and thrusts (2.5-12 mN). For the annular configuration, a voltage less than 200 V was not sufficient to sustain the discharge at low propellant flow rates. The cylindrical thruster can operate at voltages lower than 200 V, which suggests that a cylindrical thruster can be designed to operate at even smaller power

  5. Pressure of a partially ionized hydrogen gas: numerical results from exact low temperature expansions

    Energy Technology Data Exchange (ETDEWEB)

    Alastuey, A. [Laboratoire de Physique, ENS Lyon, CNRS, Lyon (France); Ballenegger, V. [Institut UTINAM, Universite de Franche-Comte, CNRS, Besancon (France)

    2010-01-15

    We consider a partially ionized hydrogen gas at low densities, where it reduces almost to an ideal mixture made with hydrogen atoms in their ground-state, ionized protons and ionized electrons. By performing systematic low-temperature expansions within the physical picture, in which the system is described as a quantum electron-proton plasma interacting via the Coulomb potential, exact formulae for the first.ve leading corrections to the ideal Saha equation of state have been derived[A. Alastuey, V. Ballenegger et al., J. Stat. Phys. 130, 1119 (2008)]. Those corrections account for all effects of interactions and thermal excitations up to order exp(E{sub H} /kT) included, where E{sub H} {approx_equal} -13.6 eV is the ground state energy of the hydrogen atom. Among the.ve leading corrections, three are easy to evaluate, while the remaining ones involve suitably truncated internal partition functions of H{sub 2} molecules and H{sup -} and H{sub 2}{sup +} ions, for which no analytical formulae are available in closed form. We estimate those partitions functions at.nite temperature via a simple phenomenology based on known values of rotational and vibrational energies. This allows us to compute numerically the leading deviations to the Saha pressure along several isotherms and isochores. Our values are compared with those of the OPAL tables (for pure hydrogen) calculated within the ACTEX method (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Fabrication of gas sensor based on field ionization from SWCNTs with tripolar microelectrode

    International Nuclear Information System (INIS)

    Cai, Shengbing; Zhang, Yong; Duan, Zhemin

    2012-01-01

    We report the nanofabrication of a sulfur dioxide (SO 2 ) sensor with a tripolar on-chip microelectrode utilizing a film of single-walled carbon nanotubes (SWCNTs) as the field ionization cathode, where the ion flow current and the partial discharge current generated by the field ionization process of gaseous molecules can be gauged to gas species and concentration. The variation of the sensitivity is less than 4% for all of the tested devices, and the sensor has selectivity against gases such as He, NO 2 , CO, H 2 , SO 2 and O 2 . Further, the sensor response presents well-defined and reproducible linear behavior with regard to concentration in the range investigated and a detection limitation of <∼0.5 ppm for SO 2 . More importantly, a tripolar on-chip microelectrode with SWCNTs as a cathode exhibits an impressive performance with respect to stability and anti-oxidation behavior, which are significantly better than had been possible before in the traditional bipolar sensor under explicit circumstances at room temperature. (paper)

  7. Measurement of the first Townsend ionization coefficient in a methane-based tissue-equivalent gas

    Energy Technology Data Exchange (ETDEWEB)

    Petri, A.R. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Gonçalves, J.A.C. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Departamento de Física, Pontifícia Universidade Católica de São Paulo, 01303-050 São Paulo (Brazil); Mangiarotti, A. [Instituto de Física - Universidade de São Paulo, Cidade Universitária, 05508-080 São Paulo (Brazil); Botelho, S. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Bueno, C.C., E-mail: ccbueno@ipen.br [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil)

    2017-03-21

    Tissue-equivalent gases (TEGs), often made of a hydrocarbon, nitrogen, and carbon dioxide, have been employed in microdosimetry for decades. However, data on the first Townsend ionization coefficient (α) in such mixtures are scarce, regardless of the chosen hydrocarbon. In this context, measurements of α in a methane-based tissue-equivalent gas (CH{sub 4} – 64.4%, CO{sub 2} – 32.4%, and N{sub 2} – 3.2%) were performed in a uniform field configuration for density-normalized electric fields (E/N) up to 290 Td. The setup adopted in our previous works was improved for operating at low pressures. The modifications introduced in the apparatus and the experimental technique were validated by comparing our results of the first Townsend ionization coefficient in nitrogen, carbon dioxide, and methane with those from the literature and Magboltz simulations. The behavior of α in the methane-based TEG was consistent with that observed for pure methane. All the experimental results are included in tabular form in the .

  8. Carbon-14 labelling of biomolecules induced by 14CO ionized gas

    International Nuclear Information System (INIS)

    Lier, J.E. van; Sanche, L.

    1979-01-01

    Ionized 14 CO gas provides a rapid method for producing 14 C-labelled biomolecules. The apparatus consists of a high vacuum system in which a small amount of 14 CO is ionized by electron impact. The resulting species drift towards a target where they interact with the molecule of interest to produce 14 C-labelled compounds. Since the reaction time is only 2 minutes, the method is particularly promising for producing tracer biomolecules with short-lived 11 C at high specific activities. The applicability of the method to various classes of compounds of biological importance, including steroids, alkaloids, prostaglandins, nucleosides, amino acids and proteins has been studied. All compounds treated gave rise to 14 C addition and degradation products. Furthermore, for some compounds, chromatographic analysis in multiple systems followed by derivatization and crystallization to constant specific activity, indicated that carbon exchange may occur to produce the labelled, but otherwise unaltered substrate in yields of the order of 10-100 mCi/mol. More conclusive proof of radiochemical identity must await production of larger quantities of material and rigorous purification including at least two different chromatographic techniques. (author)

  9. Identification of volatiles by headspace gas chromatography with simultaneous flame ionization and mass spectrometric detection.

    Science.gov (United States)

    Tiscione, Nicholas B; Yeatman, Dustin Tate; Shan, Xiaoqin; Kahl, Joseph H

    2013-10-01

    Volatiles are frequently abused as inhalants. The methods used for identification are generally nonspecific if analyzed concurrently with ethanol or require an additional analytical procedure that employs mass spectrometry. A previously published technique utilizing a capillary flow technology splitter to simultaneously quantitate and confirm ethyl alcohol by flame ionization and mass spectrometric detection after headspace sampling and gas chromatographic separation was evaluated for the detection of inhalants. Methanol, isopropanol, acetone, acetaldehyde, toluene, methyl ethyl ketone, isoamyl alcohol, isobutyl alcohol, n-butyl alcohol, 1,1-difluoroethane, 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane (Norflurane, HFC-134a), chloroethane, trichlorofluoromethane (Freon®-11), dichlorodifluoromethane (Freon®-12), dichlorofluoromethane (Freon®-21), chlorodifluoromethane (Freon®-22) and 1,2-dichlorotetrafluoroethane (Freon®-114) were validated for qualitative identification by this method. The validation for qualitative identification included evaluation of matrix effects, sensitivity, carryover, specificity, repeatability and ruggedness/robustness.

  10. Distribution and Kinematics of Ionized Gas in the central 500pc of Seyfert Galaxies

    Science.gov (United States)

    Hyland, Ella; Hicks, Erin K. S.; Kade, Kiana

    2018-06-01

    We have characterized the spatial distribution and kinematics of the ionized hydrogen gas in a sample of 40 Seyfert galaxies as part of the KONA (Keck OSIRIS Nearby AGN) survey. An analysis of the narrow Brackett Gamma emission (2.16 microns) in the central 500 pc of these local AGN will be presented. Measurements include the azimuthal averages of the flux distribution, velocity dispersion, and emission line equivalent width. In addition, the excitation of the Brackett Gamma emission is considered using the ratio of its flux with that of molecular hydrogen (2.12 microns) as a diagnostic. A comparison of the circumnuclear narrow Brackett Gamma emission characteristics in the Seyfert type 1 and type 2 subsamples will also be presented.

  11. Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

    International Nuclear Information System (INIS)

    Hong, Sung-Ha; Jenkins, A Toby A; Szili, Endre J; Short, Robert D

    2014-01-01

    This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine. (fast track communication)

  12. Determination of clebopride in plasma by capillary gas chromatography-negative-ion chemical ionization mass spectrometry.

    Science.gov (United States)

    Robinson, P R; Jones, M D; Maddock, J

    1988-11-18

    A procedure for the analysis of clebopride in plasma using capillary gas chromatography-negative-ion chemical ionization mass spectrometry has been developed. Employing an ethoxy analogue as internal standard, the two compounds were extracted from basified plasma using dichloromethane. Subsequent reaction with heptafluorobutyryl imidazole produced volatile monoheptafluorobutyryl derivatives whose ammonia negative-ion mass spectra proved ideal for selected-ion monitoring. The recovery of clebopride from plasma at 0.536 nmol/l was found to be 85.5 +/- 0.9% (n = 3) whilst measurement down to 0.268 nmol/l was possible with a coefficient of variation of 7.9%. Plasma levels of the compound are reported in two volunteers following ingestion of 1 mg of clebopride as the malate salt.

  13. Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

    Science.gov (United States)

    Hong, Sung-Ha; Szili, Endre J.; Jenkins, A. Toby A.; Short, Robert D.

    2014-09-01

    This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine.

  14. GAS BEARING

    Science.gov (United States)

    Skarstrom, C.W.

    1960-09-01

    A gas lubricated bearing for a rotating shaft is described. The assembly comprises a stationary collar having an annular member resiliently supported thereon. The collar and annular member are provided with cooperating gas passages arranged for admission of pressurized gas which supports and lubricates a bearing block fixed to the rotatable shaft. The resilient means for the annular member support the latter against movement away from the bearing block when the assembly is in operation.

  15. Ionizing radiation effects in Acai oil analysed by gas chromatography coupled to mass spectrometry technique

    International Nuclear Information System (INIS)

    Valli, Felipe; Fernandes, Carlos Eduardo; Moura, Sergio; Machado, Ana Carolina; Furasawa, Helio Akira; Pires, Maria Aparecida Faustino; Bustillos, Oscar Vega

    2007-01-01

    The Acai fruit is a well know Brazilian seed plant used in large scale as a source of feed stock, specially in the Brazilian North-east region. The Acai oil is use in many purposes from fuel sources to medicine. The scope of this paper is to analyzed the chemical structures modification of the acai oil after the ionizing radiation. The radiation were set in the range of 10 to 25 kGy in the extracted Acai oil. The analyses were made by gas chromatography coupled to mass spectrometry techniques. A GC/MS Shimatzu QP-5000 equipped with 30 meters DB-5 capillary column with internal diameter of 0.25 mm and 0.25 μm film thickness was used. Helium was used as carried gas and gave a column head pressure of 12 p.s.i. (1 p.s.i. = 6894.76 Pa) and an average flux of 1 ml/min. The temperature program for the GC column consisted of a 4-minutes hold at 75 deg C, a 15 deg C /min ramp to 200 deg C, 8 minutes isothermal. 20 deg C/min ramp to 250 deg C, 2 minutes isothermal. The extraction of the fatty acids was based on liquid-liquid method using chloroform as solvent. The chromatograms resulted shows the presences of the oleic acid and others fatty acids identify by the mass spectra library (NIST-92). The ionization radiation deplete the fatty acids presents in the Acai oil. Details on the chemical qualitative analytical is present as well in this work. (author)

  16. Single and multiple ionization of noble gas atoms by H0 impact

    International Nuclear Information System (INIS)

    Sarkadi, L.; Gulyas, L.; Herczku, P.; Kovacs, S.T.S.; Koever, A.

    2012-01-01

    Complete text of publication follows. The understanding of the mechanisms of collisions between energetic charged particles and neutral atoms is of fundamental significance, and it has large importance in many research fields (plasma physics, astrophysics, materials science, etc.), as well as in number of practical applications. In the present work we measured total direct ionization and electron loss cross sections for the collisions of H 0 atoms with noble gas atoms (He, Ne, Ar, Kr) in the energy range 75-300 keV. The experiment was carried out at the 1.5 MV Van de Graaff accelerator of Atomki by coincident detection of the recoil target ions and the charge-state analyzed scattered projectiles. With this study we wished to obtain information about the role played by the electron of the H 0 projectile in the process of the single and multiple vacancy production induced by the collision. For this purpose we repeated the measurements also with proton projectile under the same experimental conditions. For calibration of the measuring system and normalization of our data we used the cross section values of Ref. [1]. The experimental results were analysed with using the classical trajectory Monte Carlo (CTMC) method. CTMC describes well the experimental data for both projectiles for the single vacancy creation, however we observed increasing deviation between the theory and experiment with increasing number of the created vacancies, as well as with decreasing atomic number of the target atoms. Fig. 1 shows our results obtained for the single, double and triple ionization (q = 1, 2, 3) of Kr at H 0 impact for the two cases when the outgoing projectile is H 0 (a) and H + (b), i.e., for pure ionization of the target, and ionization of the target with simultaneous electron loss of the projectile. The curves in the figure were obtained by two versions of the three-body CTMC theory: a conventional model (dashed curves); and a model taking partially account of the many

  17. Cluster chemical ionization for improved confidence level in sample identification by gas chromatography/mass spectrometry.

    Science.gov (United States)

    Fialkov, Alexander B; Amirav, Aviv

    2003-01-01

    Upon the supersonic expansion of helium mixed with vapor from an organic solvent (e.g. methanol), various clusters of the solvent with the sample molecules can be formed. As a result of 70 eV electron ionization of these clusters, cluster chemical ionization (cluster CI) mass spectra are obtained. These spectra are characterized by the combination of EI mass spectra of vibrationally cold molecules in the supersonic molecular beam (cold EI) with CI-like appearance of abundant protonated molecules, together with satellite peaks corresponding to protonated or non-protonated clusters of sample compounds with 1-3 solvent molecules. Like CI, cluster CI preferably occurs for polar compounds with high proton affinity. However, in contrast to conventional CI, for non-polar compounds or those with reduced proton affinity the cluster CI mass spectrum converges to that of cold EI. The appearance of a protonated molecule and its solvent cluster peaks, plus the lack of protonation and cluster satellites for prominent EI fragments, enable the unambiguous identification of the molecular ion. In turn, the insertion of the proper molecular ion into the NIST library search of the cold EI mass spectra eliminates those candidates with incorrect molecular mass and thus significantly increases the confidence level in sample identification. Furthermore, molecular mass identification is of prime importance for the analysis of unknown compounds that are absent in the library. Examples are given with emphasis on the cluster CI analysis of carbamate pesticides, high explosives and unknown samples, to demonstrate the usefulness of Supersonic GC/MS (GC/MS with supersonic molecular beam) in the analysis of these thermally labile compounds. Cluster CI is shown to be a practical ionization method, due to its ease-of-use and fast instrumental conversion between EI and cluster CI, which involves the opening of only one valve located at the make-up gas path. The ease-of-use of cluster CI is analogous

  18. Displacement of an electric arc by a stationary transverse magnetic field to different pressures of the ionized gas

    International Nuclear Information System (INIS)

    Ramos, J.

    1987-01-01

    The displacement of a wall-stabilized electric arc by a stationary transverse magnetic field is measured to different pressures of the ionized gas. The increase of the pressure makes the heat transfer function and the mass flow velocity in the arc column to raise, and it makes the arc displacement to decrease. (author)

  19. Advantages of Atmospheric Pressure Chemical Ionization in Gas Chromatography Tandem Mass Spectrometry: Pyrethroid Insecticides as a Case Study

    NARCIS (Netherlands)

    Portolés, T.; Mol, J.G.J.; Sancho, J.V.; Hernández, F.

    2012-01-01

    Gas chromatography coupled to mass spectrometry (GC/MS) has been extensively applied for determination of volatile, nonpolar, compounds in many applied fields like food safety, environment, or toxicology. The wide majority of methods reported use electron ionization (EI), which may result in

  20. Dust trap formation in a non-self-sustained discharge with external gas ionization

    International Nuclear Information System (INIS)

    Filippov, A. V.; Babichev, V. N.; Pal’, A. F.; Starostin, A. N.; Cherkovets, V. E.; Rerikh, V. K.; Taran, M. D.

    2015-01-01

    Results from numerical studies of a non-self-sustained gas discharge containing micrometer dust grains are presented. The non-self-sustained discharge (NSSD) was controlled by a stationary fast electron beam. The numerical model of an NSSD is based on the diffusion drift approximation for electrons and ions and self-consistently takes into account the influence of the dust component on the electron and ion densities. The dust component is described by the balance equation for the number of dust grains and the equation of motion for dust grains with allowance for the Stokes force, gravity force, and electric force in the cathode sheath. The interaction between dust grains is described in the self-consistent field approximation. The height of dust grain levitation over the cathode is determined and compared with experimental results. It is established that, at a given gas ionization rate and given applied voltage, there is a critical dust grain size above which the levitation condition in the cathode sheath cannot be satisfied. Simulations performed for the dust component consisting of dust grains of two different sizes shows that such grains levitate at different heights, i.e., size separation of dust drains levitating in the cathode sheath of an NSSD takes place

  1. Dust trap formation in a non-self-sustained discharge with external gas ionization

    Energy Technology Data Exchange (ETDEWEB)

    Filippov, A. V., E-mail: fav@triniti.ru; Babichev, V. N.; Pal’, A. F.; Starostin, A. N.; Cherkovets, V. E.; Rerikh, V. K.; Taran, M. D. [Troitsk Institute for Innovation and Fusion Research (Russian Federation)

    2015-11-15

    Results from numerical studies of a non-self-sustained gas discharge containing micrometer dust grains are presented. The non-self-sustained discharge (NSSD) was controlled by a stationary fast electron beam. The numerical model of an NSSD is based on the diffusion drift approximation for electrons and ions and self-consistently takes into account the influence of the dust component on the electron and ion densities. The dust component is described by the balance equation for the number of dust grains and the equation of motion for dust grains with allowance for the Stokes force, gravity force, and electric force in the cathode sheath. The interaction between dust grains is described in the self-consistent field approximation. The height of dust grain levitation over the cathode is determined and compared with experimental results. It is established that, at a given gas ionization rate and given applied voltage, there is a critical dust grain size above which the levitation condition in the cathode sheath cannot be satisfied. Simulations performed for the dust component consisting of dust grains of two different sizes shows that such grains levitate at different heights, i.e., size separation of dust drains levitating in the cathode sheath of an NSSD takes place.

  2. Towards radiation detected resonance ionization spectroscopy on transfermium elements in a buffer gas cell

    Energy Technology Data Exchange (ETDEWEB)

    Lautenschlaeger, Felix; Walther, Thomas [Institut fuer Angewandte Physik, TU Darmstadt, 64289 Darmstadt (Germany); Laatiaoui, Mustapha; Block, Michael [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Helmholtz-Institut Mainz, 55128 Mainz (Germany); Lauth, Werner; Backe, Hartmut [Institut fuer Kernphysik, JGU Mainz, 55128 Mainz (Germany); Hessberger, Fritz-Peter [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany)

    2013-07-01

    The study of the atomic structure of transfermium elements like nobelium (No) and lawrencium (Lr) via Radiation Detected Resonance Ionization Spectroscopy (RADRIS) is one of the most fascinating disciplines of modern atomic physics. It allows the determination of relativistic effects at the heaviest elements and provides a critical test of theoretical predictions. For these transfermium elements no experimental data on atomic level schemes are available at present. First experiments on {sup 254}No were performed in 2007, in which a buffer gas cell with an overall efficiency of 1%. In this experiment the evaporation temperature of nobelium was determined for the first time. To increase the efficiency of the buffer gas cell, off-line measurements have been performed with nat. ytterbium, the chemical homologue of nobelium. Also on-line experiments during a parasitic beam-time in 2012 provided an insight into the critical parameters of our setup. The results of the off-line and on-line measurements are briefly summarized in this talk.

  3. Gas-phase pesticide measurement using iodide ionization time-of-flight mass spectrometry

    Directory of Open Access Journals (Sweden)

    T. Murschell

    2017-06-01

    Full Text Available Volatilization and subsequent processing in the atmosphere are an important environmental pathway for the transport and chemical fate of pesticides. However, these processes remain a particularly poorly understood component of pesticide lifecycles due to analytical challenges in measuring pesticides in the atmosphere. Most pesticide measurements require long (hours to days sampling times coupled with offline analysis, inhibiting observation of meteorologically driven events or investigation of rapid oxidation chemistry. Here, we present chemical ionization time-of-flight mass spectrometry with iodide reagent ions as a fast and sensitive measurement of four current-use pesticides. These semi-volatile pesticides were calibrated with injections of solutions onto a filter and subsequently volatilized to generate gas-phase analytes. Trifluralin and atrazine are detected as iodide–molecule adducts, while permethrin and metolachlor are detected as adducts between iodide and fragments of the parent analyte molecule. Limits of detection (1 s are 0.37, 0.67, 0.56, and 1.1 µg m−3 for gas-phase trifluralin, metolachlor, atrazine, and permethrin, respectively. The sensitivities of trifluralin and metolachlor depend on relative humidity, changing as much as 70 and 59, respectively, as relative humidity of the sample air varies from 0 to 80 %. This measurement approach is thus appropriate for laboratory experiments and potentially near-source field measurements.

  4. Delivering Transmembrane Peptide Complexes to the Gas Phase Using Nanodiscs and Electrospray Ionization

    Science.gov (United States)

    Li, Jun; Richards, Michele R.; Kitova, Elena N.; Klassen, John S.

    2017-10-01

    The gas-phase conformations of dimers of the channel-forming membrane peptide gramicidin A (GA), produced from isobutanol or aqueous solutions of GA-containing nanodiscs (NDs), are investigated using electrospray ionization-ion mobility separation-mass spectrometry (ESI-IMS-MS) and molecular dynamics (MD) simulations. The IMS arrival times measured for (2GA + 2Na)2+ ions from isobutanol reveal three different conformations, with collision cross-sections (Ω) of 683 Å2 (conformation 1, C1), 708 Å2 (C2), and 737 Å2 (C3). The addition of NH4CH3CO2 produced (2GA + 2Na)2+ and (2GA + H + Na)2+ ions, with Ω similar to those of C1, C2, and C3, as well as (2GA + 2H)2+, (2GA + 2NH4)2+, and (2GA + H + NH4)2+ ions, which adopt a single conformation with a Ω similar to that of C2. These results suggest that the nature of the charging agents, imparted by the ESI process, can influence dimer conformation in the gas phase. Notably, the POPC NDs produced exclusively (2GA + 2NH4)2+ dimer ions; the DMPC NDs produced both (2GA + 2H)2+ and (2GA + 2NH4)2+ dimer ions. While the Ω of (2GA + 2H)2+ is similar to that of C2, the (2GA + 2NH4)2+ ions from NDs adopt a more compact structure, with a Ω of 656 Å2. It is proposed that this compact structure corresponds to the ion conducting single stranded head-to-head helical GA dimer. These findings highlight the potential of NDs, combined with ESI, for transferring transmembrane peptide complexes directly from lipid bilayers to the gas phase. [Figure not available: see fulltext.

  5. Use of electron ionization and atmospheric pressure chemical ionization in gas chromatography coupled to time-of-flight mass spetrometry for screening and identification of organic pollutants in waters

    NARCIS (Netherlands)

    Portoles, T.; Mol, J.G.J.; Sancho, J.V.; Hernandez, F.

    2014-01-01

    A new approach has been developed for multiclass screening of organic contaminants in water based on the use of gas chromatography coupled to hybrid quadrupole high-resolution time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC–(APCI)QTOF MS). The soft ionization

  6. Simulation of the Interaction of X-rays with a Gas in an Ionization Chamber by the Monte Carlo Method

    International Nuclear Information System (INIS)

    Grau Carles, A.; Garcia Gomez-Tejedor, G.

    2001-01-01

    The final objective of any ionization chamber is the measurement of the energy amount or radiation dose absorbed by the gas into the chamber. The final value depends on the composition of the gas, its density and temperature, the ionization chamber geometry, and type and intensity of the radiation. We describe a Monte Carlo simulation method, which allows one to compute the dose absorbed by the gas for a X-ray beam. Verification of model has been carried out by simulating the attenuation of standard X-ray radiation through the half value layers established in the ISO 4037 report, while assuming a Weibull type energy distribution for the incident photons. (Author) 6 refs

  7. Quantitative study of the ionization-induced refraction of picosecond laser pulses in gas-jet targets

    International Nuclear Information System (INIS)

    Mackinnon, A.J.; Borghesi, M.; Iwase, A.; Jones, M.W.; Pert, G.J.; Rae, S.; Burnett, K.; Willi, O.

    1996-01-01

    A quantitative study of refractive whole beam defocusing and small scale breakup induced by optical ionization of subpicosecond and picosecond, 0.25 and 1 μm, laser pulses in gas-jet targets at densities above 1x10 19 cm -3 has been carried out. A significant reduction of the incident laser intensity was observed due to refraction from ionization-induced density gradients. The level of refraction measured with optical probing correlated well with the fraction of energy transmitted through the plasma. The numerical and analytical models were found to agree well with experimental observations. copyright 1996 The American Physical Society

  8. IZI: INFERRING THE GAS PHASE METALLICITY (Z) AND IONIZATION PARAMETER (q) OF IONIZED NEBULAE USING BAYESIAN STATISTICS

    International Nuclear Information System (INIS)

    Blanc, Guillermo A.; Kewley, Lisa; Vogt, Frédéric P. A.; Dopita, Michael A.

    2015-01-01

    We present a new method for inferring the metallicity (Z) and ionization parameter (q) of H II regions and star-forming galaxies using strong nebular emission lines (SELs). We use Bayesian inference to derive the joint and marginalized posterior probability density functions for Z and q given a set of observed line fluxes and an input photoionization model. Our approach allows the use of arbitrary sets of SELs and the inclusion of flux upper limits. The method provides a self-consistent way of determining the physical conditions of ionized nebulae that is not tied to the arbitrary choice of a particular SEL diagnostic and uses all the available information. Unlike theoretically calibrated SEL diagnostics, the method is flexible and not tied to a particular photoionization model. We describe our algorithm, validate it against other methods, and present a tool that implements it called IZI. Using a sample of nearby extragalactic H II regions, we assess the performance of commonly used SEL abundance diagnostics. We also use a sample of 22 local H II regions having both direct and recombination line (RL) oxygen abundance measurements in the literature to study discrepancies in the abundance scale between different methods. We find that oxygen abundances derived through Bayesian inference using currently available photoionization models in the literature can be in good (∼30%) agreement with RL abundances, although some models perform significantly better than others. We also confirm that abundances measured using the direct method are typically ∼0.2 dex lower than both RL and photoionization-model-based abundances

  9. IZI: INFERRING THE GAS PHASE METALLICITY (Z) AND IONIZATION PARAMETER (q) OF IONIZED NEBULAE USING BAYESIAN STATISTICS

    Energy Technology Data Exchange (ETDEWEB)

    Blanc, Guillermo A. [Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Kewley, Lisa; Vogt, Frédéric P. A.; Dopita, Michael A. [Research School of Astronomy and Astrophysics, Australian National University, Cotter Road, Weston, ACT 2611 (Australia)

    2015-01-10

    We present a new method for inferring the metallicity (Z) and ionization parameter (q) of H II regions and star-forming galaxies using strong nebular emission lines (SELs). We use Bayesian inference to derive the joint and marginalized posterior probability density functions for Z and q given a set of observed line fluxes and an input photoionization model. Our approach allows the use of arbitrary sets of SELs and the inclusion of flux upper limits. The method provides a self-consistent way of determining the physical conditions of ionized nebulae that is not tied to the arbitrary choice of a particular SEL diagnostic and uses all the available information. Unlike theoretically calibrated SEL diagnostics, the method is flexible and not tied to a particular photoionization model. We describe our algorithm, validate it against other methods, and present a tool that implements it called IZI. Using a sample of nearby extragalactic H II regions, we assess the performance of commonly used SEL abundance diagnostics. We also use a sample of 22 local H II regions having both direct and recombination line (RL) oxygen abundance measurements in the literature to study discrepancies in the abundance scale between different methods. We find that oxygen abundances derived through Bayesian inference using currently available photoionization models in the literature can be in good (∼30%) agreement with RL abundances, although some models perform significantly better than others. We also confirm that abundances measured using the direct method are typically ∼0.2 dex lower than both RL and photoionization-model-based abundances.

  10. Supercritical carbon dioxide extraction of electrolyte from spent lithium ion batteries and its characterization by gas chromatography with chemical ionization

    Science.gov (United States)

    Mönnighoff, Xaver; Friesen, Alex; Konersmann, Benedikt; Horsthemke, Fabian; Grützke, Martin; Winter, Martin; Nowak, Sascha

    2017-06-01

    The aging products of the electrolyte from a commercially available state-of-the-art 18650-type cell were investigated. During long term cycling a huge difference in their performance and lifetime at different temperatures was observed. By interpretation of a strong capacity fading of cells cycled at 20 °C compared to cells cycled at 45 °C a temperature depending aging mechanism was determined. To investigate the influence of the electrolyte on this fading, the electrolyte was extracted by supercritical fluid extraction (SFE) and then analyzed by gas chromatography (GC) with electron impact (EI) ionization and mass selective detection. To obtain more information with regard to the identification of unknown decomposition products further analysis with positive chemical ionization (PCI) and negative chemical ionization (NCI) was performed. 17 different volatile organic aging products were detected and identified. So far, seven of them were not yet known in literature and several formation pathways were postulated taking previously published literature into account.

  11. Ionized Gas Outflows from the MAGNUM Survey: NGC 1365 and NGC 4945

    Energy Technology Data Exchange (ETDEWEB)

    Venturi, Giacomo; Marconi, Alessandro [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Sesto Fiorentino (Italy); Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Mingozzi, Matilde [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Dipartimento di Fisica e Astronomia, Università di Bologna, Bologna (Italy); Carniani, Stefano [Cavendish Laboratory, Department of Physics, University of Cambridge, Cambridge (United Kingdom); Kavli Institute for Cosmology, University of Cambridge, Cambridge (United Kingdom); Cresci, Giovanni [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Risaliti, Guido [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Sesto Fiorentino (Italy); Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Mannucci, Filippo, E-mail: gventuri@arcetri.astro.it [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy)

    2017-11-24

    AGN feedback, acting through strong outflows accelerated in the nuclear region of AGN hosts, is invoked as a key ingredient for galaxy evolution by many models to explain the observed BH-galaxy scaling relations. Recently, some direct observational evidence of radiative mode feedback in action has been finally found in quasars at z >1.5. However, it is not possible to study outflows in quasars at those redshifts on small scales (≲100 pc), as spatial information is limited by angular resolution. This is instead feasible in nearby active galaxies, which are ideal laboratories to explore outflow structure and properties, as well as the effects of AGN on their host galaxies. In this proceeding we present preliminary results from the MAGNUM survey, which comprises nearby Seyfert galaxies observed with the integral field spectrograph VLT/MUSE. We focus on two sources, NGC 1365 and NGC 4945, that exhibit double conical outflows extending on distances >1 kpc. We disentangle the dominant contributions to ionization of the various gas components observed in the central ~5.3 kpc of NGC 1365. An attempt to infer outflow 3D structure in NGC 4945 is made via simple kinematic modeling, suggesting a hollow cone geometry.

  12. Ethanol analysis by headspace gas chromatography with simultaneous flame-ionization and mass spectrometry detection.

    Science.gov (United States)

    Tiscione, Nicholas B; Alford, Ilene; Yeatman, Dustin Tate; Shan, Xiaoqin

    2011-09-01

    Ethanol is the most frequently identified compound in forensic toxicology. Although confirmation involving mass spectrometry is desirable, relatively few methods have been published to date. A novel technique utilizing a Dean's Switch to simultaneously quantitate and confirm ethyl alcohol by flame-ionization (FID) and mass spectrometric (MS) detection after headspace sampling and gas chromatographic separation is presented. Using 100 μL of sample, the limits of detection and quantitation were 0.005 and 0.010 g/dL, respectively. The zero-order linear range (r(2) > 0.990) was determined to span the concentrations of 0.010 to 1.000 g/dL. The coefficient of variation of replicate analyses was less than 3.1%. Quantitative accuracy was within ±8%, ±6%, ±3%, and ±1.5% at concentrations of 0.010, 0.025, 0.080, and 0.300 g/dL, respectively. In addition, 1,1-difluoroethane was validated for qualitative identification by this method. The validated FID-MS method provides a procedure for the quantitation of ethyl alcohol in blood by FID with simultaneous confirmation by MS and can also be utilized as an identification method for inhalants such as 1,1-difluoroethane.

  13. Gas chromatography/multiphoton ionization/time-of-flight mass spectrometry of polychlorinated biphenyls

    International Nuclear Information System (INIS)

    Matsui, Taiki; Uchimura, Tomohiro; Imasaka, Totaro

    2011-01-01

    A sample mixture of polychlorinated biphenyls (PCBs) was measured by gas chromatography/multiphoton ionization/time-of-flight mass spectrometry (GC/MPI/TOF-MS) using four types of laser sources. When a fourth harmonic emission (266 nm) of a picosecond Nd:YAG laser (1064 nm) was utilized, highly chlorinated PCBs larger than hepta-CBs were not observed. A fifth harmonic emission (213 nm) of the picosecond Nd:YAG laser allowed the measurement of PCBs from di-CBs to octa-CBs, and the limit of detection (LOD) was several pg for each component of PCBs. The LOD for the total amount of PCBs, which was calculated using the protocol provided by the Ministry of the Environment, Japan, was 1000 pg. The signal intensity of the congeners with chlorine atoms at the ortho positions (non-coplanar PCBs) was enhanced by using the fifth harmonic emission. When the fourth harmonic emission remaining after fifth harmonic generation was simultaneously used, the LOD for total PCBs was improved to 667 pg. The PCB sample was also measured using a third harmonic emission (267 nm) of a femtosecond Ti:sapphire laser (800 nm), providing an LOD of 677 pg. Thus, the two-color beam (266/213 nm) of a picosecond Nd:YAG laser had a comparable, or even slightly superior, performance to the more expensive femtosecond Ti:sapphire laser.

  14. Ionized Gas Outflows from the MAGNUM Survey: NGC 1365 and NGC 4945

    Directory of Open Access Journals (Sweden)

    Giacomo Venturi

    2017-11-01

    Full Text Available AGN feedback, acting through strong outflows accelerated in the nuclear region of AGN hosts, is invoked as a key ingredient for galaxy evolution by many models to explain the observed BH-galaxy scaling relations. Recently, some direct observational evidence of radiative mode feedback in action has been finally found in quasars at z >1.5. However, it is not possible to study outflows in quasars at those redshifts on small scales (≲100 pc, as spatial information is limited by angular resolution. This is instead feasible in nearby active galaxies, which are ideal laboratories to explore outflow structure and properties, as well as the effects of AGN on their host galaxies. In this proceeding we present preliminary results from the MAGNUM survey, which comprises nearby Seyfert galaxies observed with the integral field spectrograph VLT/MUSE. We focus on two sources, NGC 1365 and NGC 4945, that exhibit double conical outflows extending on distances >1 kpc. We disentangle the dominant contributions to ionization of the various gas components observed in the central ~5.3 kpc of NGC 1365. An attempt to infer outflow 3D structure in NGC 4945 is made via simple kinematic modeling, suggesting a hollow cone geometry.

  15. III. Penning ionization, associative ionization and chemi-ionization processes

    International Nuclear Information System (INIS)

    Cermak, V.

    1975-01-01

    Physical mechanisms of three important ionization processes in a cold plasma and the methods of their experimental study are discussed. An apparatus for the investigation of the Penning ionization using ionization processes of long lived metastable rare gas atoms is described. Methods of determining interaction energies and ionization rates from the measured energy spectra of the originating electrons are described and illustrated by several examples. Typical associative ionization processes are listed and the ionization rates are compared with those of the Penning ionization. Interactions with short-lived excited particles and the transfer of excitation without ionization are discussed. (J.U.)

  16. [Determination of acetanilide herbicide residues in tea by gas chromatography-mass spectrometry with two different ionization techniques].

    Science.gov (United States)

    Shen, Weijian; Xu, Jinzhong; Yang, Wenquan; Shen, Chongyu; Zhao, Zengyun; Ding, Tao; Wu, Bin

    2007-09-01

    An analytical method of solid phase extraction-gas chromatography-mass spectrometry with two different ionization techniques was established for simultaneous determination of 12 acetanilide herbicide residues in tea-leaves. Herbicides were extracted from tea-leaf samples with ethyl acetate. The extract was cleaned-up on an active carbon SPE column connected to a Florisil SPE column. Analytical screening was determined by the technique of gas chromatography (GC)-mass spectrometry (MS) in the selected ion monitoring (SIM) mode with either electron impact ionization (EI) or negative chemical ionization (NCI). It is reliable and stable that the recoveries of all herbicides were in the range from 50% to 110% at three spiked levels, 10 microg/kg, 20 microg/kg and 40 microg/kg, and the relative standard deviations (RSDs) were no more than 10.9%. The two different ionization techniques are complementary as more ion fragmentation information can be obtained from the EI mode while more molecular ion information from the NCI mode. By comparison of the two techniques, the selectivity of NCI-SIM was much better than that of EI-SIM method. The sensitivities of the both techniques were high, the limit of quantitative (LOQ) for each herbicide was no more than 2.0 microg/kg, and the limit of detection (LOD) with NCI-SIM technique was much lower than that of EI-SIM when analyzing herbicides with several halogen atoms in the molecule.

  17. LARGE-SCALE SHOCK-IONIZED AND PHOTOIONIZED GAS IN M83: THE IMPACT OF STAR FORMATION

    International Nuclear Information System (INIS)

    Hong, Sungryong; Calzetti, Daniela; Dopita, Michael A.; Blair, William P.; Whitmore, Bradley C.; Bond, Howard E.; Balick, Bruce; Carollo, Marcella; Disney, Michael J.; Frogel, Jay A.; Hall, Donald; Holtzman, Jon A.; Kimble, Randy A.; McCarthy, Patrick J.; O'Connell, Robert W.; Paresce, Francesco; Saha, Abhijit; Silk, Joseph I.; Trauger, John T.; Walker, Alistair R.

    2011-01-01

    We investigate the ionization structure of the nebular gas in M83 using the line diagnostic diagram, [O III](5007 A)/Hβ versus [S II](6716 A+6731 A)/Hα, with the newly available narrowband images from the Wide Field Camera 3 (WFC3) of the Hubble Space Telescope (HST). We produce the diagnostic diagram on a pixel-by-pixel (0.''2 x 0.''2) basis and compare it with several photo- and shock-ionization models. We select four regions from the center to the outer spiral arm and compare them in the diagnostic diagram. For the photoionized gas, we observe a gradual increase of the log ([O III]/Hβ) ratios from the center to the spiral arm, consistent with the metallicity gradient, as the H II regions go from super-solar abundance to roughly solar abundance from the center out. Using the diagnostic diagram, we separate the photoionized from the shock-ionized component of the gas. We find that the shock-ionized Hα emission ranges from ∼2% to about 15%-33% of the total, depending on the separation criteria used. An interesting feature in the diagnostic diagram is a horizontal distribution around log ([O III]/Hβ) ∼ 0. This feature is well fit by a shock-ionization model with 2.0 Z sun metallicity and shock velocities in the range of 250-350 km s -1 . A low-velocity shock component, -1 , is also detected and is spatially located at the boundary between the outer ring and the spiral arm. The low-velocity shock component can be due to (1) supernova remnants located nearby, (2) dynamical interaction between the outer ring and the spiral arm, and (3) abnormal line ratios from extreme local dust extinction. The current data do not enable us to distinguish among those three possible interpretations. Our main conclusion is that, even at the HST resolution, the shocked gas represents a small fraction of the total ionized gas emission at less than 33% of the total. However, it accounts for virtually all of the mechanical energy produced by the central starburst in M83.

  18. A comparison between the four Geldart groups on the performance of a gas-phase annular fluidized bed photoreactor for volatile organic compound oxidation.

    Science.gov (United States)

    Diniz, Leonardo Almeida; Hewer, Thiago Lewis Reis; Matsumoto, Danielle; Teixeira, Antonio Carlos Silva Costa

    2018-05-07

    Heterogeneous photocatalytic oxidation (PCO) is a widely studied alternative for the elimination of volatile organic compounds (VOC) in air. In this context, research on novel photoreactor arrangements to enhance PCO rates is desired. Annular fluidized bed photoreactors (AFBPR) have yielded prominent results when compared to conventional thin film reactors. However, very few works aimed at optimizing AFBPR operation. In this study, TiO 2 photocalytic agglomerates were synthesized and segregated in specific size distributions to behave as Geldart groups A, B, C, and D fluidization. The TiO 2 agglomerates were characterized by XRD, FTIR spectra, and N 2 adsorption. Photocatalyst performances were compared in a 10-mm gapped AFBPR for degrading the model pollutant methyl-ethyl-ketone (MEK), using a 254-nm radiation source. Geldart group C showed to be inadequate for AFBPR operation due to the short operation range between fluidization and elutriation. In all the cases, photocatalytic reaction rates were superior to sole UV photolysis. Group A and group B demonstrated the highest reaction rates. Considerations based on mass transfer suggested that the reasons were enhanced UV distribution within the bed at lower flow rates and superior catalyst surface area at higher flow rates. Results also revealed that groups A, B, and D perform equally per catalyst area within an AFBPR if the fluidization numbers (FN) are high enough.

  19. SDSS-IV MaNGA: the impact of diffuse ionized gas on emission-line ratios, interpretation of diagnostic diagrams and gas metallicity measurements

    Science.gov (United States)

    Zhang, Kai; Yan, Renbin; Bundy, Kevin; Bershady, Matthew; Haffner, L. Matthew; Walterbos, René; Maiolino, Roberto; Tremonti, Christy; Thomas, Daniel; Drory, Niv; Jones, Amy; Belfiore, Francesco; Sánchez, Sebastian F.; Diamond-Stanic, Aleksandar M.; Bizyaev, Dmitry; Nitschelm, Christian; Andrews, Brett; Brinkmann, Jon; Brownstein, Joel R.; Cheung, Edmond; Li, Cheng; Law, David R.; Roman Lopes, Alexandre; Oravetz, Daniel; Pan, Kaike; Storchi Bergmann, Thaisa; Simmons, Audrey

    2017-04-01

    Diffuse ionized gas (DIG) is prevalent in star-forming galaxies. Using a sample of 365 nearly face-on star-forming galaxies observed by Mapping Nearby Galaxies at APO, we demonstrate how DIG in star-forming galaxies impacts the measurements of emission-line ratios, hence the interpretation of diagnostic diagrams and gas-phase metallicity measurements. At fixed metallicity, DIG-dominated low ΣHα regions display enhanced [S II]/Hα, [N II]/Hα, [O II]/Hβ and [O I]/Hα. The gradients in these line ratios are determined by metallicity gradients and ΣHα. In line ratio diagnostic diagrams, contamination by DIG moves H II regions towards composite or low-ionization nuclear emission-line region (LI(N)ER)-like regions. A harder ionizing spectrum is needed to explain DIG line ratios. Leaky H II region models can only shift line ratios slightly relative to H II region models, and thus fail to explain the composite/LI(N)ER line ratios displayed by DIG. Our result favours ionization by evolved stars as a major ionization source for DIG with LI(N)ER-like emission. DIG can significantly bias the measurement of gas metallicity and metallicity gradients derived using strong-line methods. Metallicities derived using N2O2 are optimal because they exhibit the smallest bias and error. Using O3N2, R23, N2 = [N II]/Hα and N2S2Hα to derive metallicities introduces bias in the derived metallicity gradients as large as the gradient itself. The strong-line method of Blanc et al. (IZI hereafter) cannot be applied to DIG to get an accurate metallicity because it currently contains only H II region models that fail to describe the DIG.

  20. Thermal Deformation Analysis of the Annular Fuel

    International Nuclear Information System (INIS)

    Kim, Ju Seong; Kim, Yong Soo; Yang, Yong Sik; Bang, Je Geon

    2009-01-01

    Recently Korea Atomic Energy Research Institute suggested 12 by 12 annular fuel assembly, claiming that this new design can be applied to PWR reactor of OPR-1000 that are using 16 by 16 assembly, Compared to current fuel system, heat transfer area is enlarged, and thus heat flux is diminished. This design demonstrates that CHF(critical heat flux) restricting the operation power condition. This advanced fuel is believed to many advantages such as lowered fuel temperature, reduced fission gas release, and so forth. Nevertheless, annular geometry has some difficulties in predicting fuel performance behavior. This new design, heat transfer takes place in two directions through inner and outer gap. This heat split ultimately determines the inner and outer gap conductances that are key variables governing the fuel performance

  1. Portal Annular Pancreas

    Science.gov (United States)

    Harnoss, Jonathan M.; Harnoss, Julian C.; Diener, Markus K.; Contin, Pietro; Ulrich, Alexis B.; Büchler, Markus W.; Schmitz-Winnenthal, Friedrich H.

    2014-01-01

    Abstract Portal annular pancreas (PAP) is an asymptomatic congenital pancreas anomaly, in which portal and/or mesenteric veins are encased by pancreas tissue. The aim of the study was to determine the role of PAP in pancreatic surgery as well as its management and potential complication, specifically, postoperative pancreatic fistula (POPF). On the basis of a case report, the MEDLINE and ISI Web of Science databases were systematically reviewed up to September 2012. All articles describing a case of PAP were considered. In summary, 21 studies with 59 cases were included. The overall prevalence of PAP was 2.4% and the patients' mean (SD) age was 55.9 (16.2) years. The POPF rate in patients with PAP (12 pancreaticoduodenectomies and 3 distal pancreatectomies) was 46.7% (in accordance with the definition of the International Study Group of Pancreatic Surgery). Portal annular pancreas is a quite unattended pancreatic variant with high prevalence and therefore still remains a clinical challenge to avoid postoperative complications. To decrease the risk for POPF, attentive preoperative diagnostics should also focus on PAP. In pancreaticoduodenectomy, a shift of the resection plane to the pancreas tail should be considered; in extensive pancreatectomy, coverage of the pancreatic remnant by the falciform ligament could be a treatment option. PMID:25207658

  2. A rapid novel derivatization of amphetamine and methamphetamine using 2,2,2-trichloroethyl chloroformate for gas chromatography electron ionization and chemical ionization mass spectrometric analysis.

    Science.gov (United States)

    Dasgupta, A; Spies, J

    1998-05-01

    Amphetamine and methamphetamine are commonly abused central nervous system stimulants. We describe a rapid new derivatization of amphetamine and methamphetamine using 2,2,2-trichloroethyl chloroformate for gas chromatography-mass spectrometric analysis. Amphetamine and methamphetamine, along with N-propyl amphetamine (internal standard), were extracted from urine using 1-chlorobutane. The derivatization with 2,2,2-trichloroethyl chloroformate can be achieved at room temperature in 10 minutes. The electron ionization mass spectrum of amphetamine 2,2,2-trichloroethyl carbamate showed two weak molecular ions at m/z 309 and 311, but showed diagnostic strong peaks at m/z 218, 220, and 222. In contrast, chemical ionization of the mass spectrum of amphetamine 2,2,2-trichloroethyl carbamate showed strong (M + 1) ions at m/z 310 and 312 and other strong diagnostic peaks at m/z 274 and 276. The major advantages of this derivative are the presence of a diagnostic cluster of peaks due to the isotopic effect of three chlorine atoms (isotopes 35 and 37) in the derivatized molecule and the relative ease of its preparation. We also observed strong molecular ions for derivatized methamphetamine in the chemical ionization mass spectrum, but the molecular ions were very weak in the electron ionization mass spectrum. We used the scan mode of mass spectrometry in all analyses. When using a urine standard containing 1,000 ng/mL of amphetamine (a 7.4-micromol/L concentration) and methamphetamine (a 6.7-micromol/L concentration), the within-run precisions were 4.8% for amphetamine and 3.6% for methamphetamine. The corresponding between-run precisions were 5.3% for amphetamine and 6.7% for methamphetamine. The assay was linear for amphetamine and methamphetamine concentrations of 250 to 5,000 ng/mL (amphetamine, 1.9-37.0 micromol/L; methamphetamine, 1.7-33.6 micromol/L). The detection limit was 100 ng/mL (amphetamine, 0.74 micromol/L; methamphetamine, 0.67 micromol/L) using the scan mode

  3. Identification of Guest-Host Inclusion Complexes in the Gas Phase by Electrospray Ionization-Mass Spectrometry

    Science.gov (United States)

    Mendes, De´bora C.; Ramamurthy, Vaidhyanathan; Da Silva, Jose´ P.

    2015-01-01

    In this laboratory experiment, students follow a step-by-step procedure to prepare and study guest-host complexes in the gas phase using electrospray ionization-mass spectrometry (ESI-MS). Model systems are the complexes of hosts cucurbit[7]uril (CB7) and cucurbit[8]uril (CB8) with the guest 4-styrylpyridine (SP). Aqueous solutions of CB7 or CB8…

  4. A new in-gas-laser ionization and spectroscopy laboratory for off-line studies at KU Leuven

    International Nuclear Information System (INIS)

    Kudryavtsev, Yu.; Creemers, P.; Ferrer, R.; Granados, C.; Gaffney, L.P.; Huyse, M.; Mogilevskiy, E.; Raeder, S.; Sels, S.; Van den Bergh, P.; Van Duppen, P.; Zadvornaya, A.

    2016-01-01

    The in-gas laser ionization and spectroscopy (IGLIS) technique is used to produce and to investigate short-lived radioactive isotopes at on-line ion beam facilities. In this technique, the nuclear reaction products recoiling out of a thin target are thermalized and neutralized in a high-pressure noble gas, resonantly ionized by the laser beams in a two-step process, and then extracted from the ion source to be finally accelerated and mass separated. Resonant ionization of radioactive species in the supersonic gas jet ensures very high spectral resolution because of essential reduction of broadening mechanisms. To obtain the maximum efficiency and the best spectral resolution, properties of the supersonic jet and the laser beams must be optimized. To perform these studies a new off-line IGLIS laboratory, including a new high-repetition-rate laser system and a dedicated off-line mass separator, has been commissioned. In this article, the specifications of the different components necessary to achieve optimum conditions in laser-spectroscopy studies of radioactive beams using IGLIS are discussed and the results of simulations are presented.

  5. The analog of Blanc's law for drift velocities of electrons in gas mixtures in weakly ionized plasma

    International Nuclear Information System (INIS)

    Chiflikian, R.V.

    1995-01-01

    The analog of Blanc's law for drift velocities of electrons in multicomponent gas mixtures in weakly ionized spatially homogeneous low-temperature plasma is derived. The obtained approximate-analytical expressions are valid for average electron energy in the 1--5 eV range typical for plasma conditions of low-pressure direct current (DC) discharges. The accuracy of these formulas is ±5%. The analytical criterion of the negative differential conductivity (NDC) of electrons in binary mixtures of gases is obtained. NDC of electrons is predicted in He:Kr and He:Xe rare gas mixtures. copyright 1995 American Institute of Physics

  6. Determination of polycyclic aromatic hydrocarbons in palm oil mill effluent by soxhlet extraction and gas chromatography-flame ionization detector

    International Nuclear Information System (INIS)

    Nor Fairolzukry Ahmad Rasdy; Mohd Marsin Sanagi; Wan Aini Wan Ibrahim; Ahmedy Abu Naim

    2008-01-01

    A method has been developed for the determination of polycyclic aromatic hydrocarbons (PAHs) from palm oil mill effluent based on gas chromatography-flame ionization detection. Extraction of spiked PAHs (napthalene, fluorene phenanthrene, fluoranthene and pyrene) in palm oil waste was carried out by Soxhlet extraction using hexane-dichloromethane (60:40 v/v) as the solvent. Excellent separations were achieved using temperature programmed GC on Ultra-1 fused-silica capillary column (30 m x 250 μm ID), carrier gas helium at a flow rate of 1 mL/ min. (author)

  7. Effective ionization coefficients, electron drift velocities, and limiting breakdown fields for gas mixtures of possible interest to particle detectors

    International Nuclear Information System (INIS)

    Datskos, P.G.

    1991-01-01

    We have measured the gas-density, N, normalized effective ionization coefficient, bar a/N, and the electron drift velocity, w, as a function of the density-reduced electric field, E/N, and obtained the limiting, (E/N) lim , value of E/N for the unitary gases Ar, CO 2 , and CF 4 , the binary gas mixtures CO 2 :Ar (20: 80), CO 2 :CH 4 (20:80), and CF 4 :Ar (20:80), and the ternary gas mixtures CO 2 :CF 4 :Ar (10:10:80) and H 2 O: CF 4 :Ar (2:18:80). Addition of the strongly electron thermalizing gas CO 2 or H 2 O to the binary mixture CF 4 :Ar (1)''cools'' the mixture (i.e., lowers the electron energies), (2) has only a small effect on the magnitude of w(E/N) in the E/N range employed in the particle detectors, and (3) increases bar a/N for E/N ≥ 50 x 10 -17 V cm 2 . The increase in bar a/N, even though the electron energies are lower in the ternary mixture, is due to the Penning ionization of CO 2 (or H 2 O) in collisions with excited Ar* atoms. The ternary mixtures -- being fast, cool, and efficient -- have potential for advanced gas-filled particle detectors such as those for the SCC muon chambers. 17 refs., 8 figs., 1 tab

  8. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): review.

    Science.gov (United States)

    Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J

    2015-09-03

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a "soft" ion source for preserving highly diagnostic molecular ion is desirable, as compared to the "hard" ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. Copyright © 2015. Published by Elsevier B.V.

  9. The Gaia-ESO Survey: dynamics of ionized and neutral gas in the Lagoon nebula (M 8)

    Science.gov (United States)

    Damiani, F.; Bonito, R.; Prisinzano, L.; Zwitter, T.; Bayo, A.; Kalari, V.; Jiménez-Esteban, F. M.; Costado, M. T.; Jofré, P.; Randich, S.; Flaccomio, E.; Lanzafame, A. C.; Lardo, C.; Morbidelli, L.; Zaggia, S.

    2017-08-01

    Aims: We present a spectroscopic study of the dynamics of the ionized and neutral gas throughout the Lagoon nebula (M 8), using VLT-FLAMES data from the Gaia-ESO Survey. The new data permit exploration of the physical connections between the nebular gas and the stellar population of the associated star cluster NGC 6530. Methods: We characterized through spectral fitting emission lines of Hα, [N II] and [S II] doublets, [O III], and absorption lines of sodium D doublet, using data from the FLAMES-Giraffe and UVES spectrographs, on more than 1000 sightlines toward the entire face of the Lagoon nebula. Gas temperatures are derived from line-width comparisons, densities from the [S II] doublet ratio, and ionization parameter from Hα/[N II] ratio. Although doubly-peaked emission profiles are rarely found, line asymmetries often imply multiple velocity components along the same line of sight. This is especially true for the sodium absorption, and for the [O III] lines. Results: Spatial maps for density and ionization are derived, and compared to other known properties of the nebula and of its massive stars 9 Sgr, Herschel 36 and HD 165052 which are confirmed to provide most of the ionizing flux. The detailed velocity fields across the nebula show several expanding shells, related to the cluster NGC 6530, the O stars 9 Sgr and Herschel 36, and the massive protostar M 8East-IR. The origins of kinematical expansion and ionization of the NGC 6530 shell appear to be different. We are able to put constrains on the line-of-sight (relative or absolute) distances between some of these objects and the molecular cloud. The data show that the large obscuring band running through the middle of the nebula is being compressed by both sides, which might explain its enhanced density. We also find an unexplained large-scale velocity gradient across the entire nebula. At larger distances, the transition from ionized to neutral gas is studied using the sodium lines. Based on observations

  10. Characteristics of A-150 plastic equivalent gas in A-150 plastic ionization chambers for p(66)Be(49) neutrons

    International Nuclear Information System (INIS)

    Awschalom, M.; Rosenberg, I.; Ten Haken, R.K.; Pearson, D.W.; DeLuca, P.M. Jr.; Attix, F.H.

    1982-01-01

    The average energy necessary to produce an electron-ion pair (anti W) of a gas mixture having an atomic composition very close to that of A-150 plastic has been studied through use in different size ionization chambers made of that plastic in a p(66)Be(49) neutron therapy beam. A tentative value for anti W(A-150-gas) of 27.3 +/ -0.5 J C -1 was derived. The anti W value of the A-150 equivalent gas mixture is compared to those of methane-based tissue-equivalent gas and of air for the p(66)Be(49) neutron beam as well as to corresponding values found in similar experiments using 14.8 MeV monoenergetic neutrons

  11. Liquid film characterization in horizontal, annular, two-phase, gas-liquid flow using time-resolved laser-induced fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Farias, P.S.C.; Martins, F.J.W.A.; Azevedo, L.F.A. [PUC-Rio, Department of Mechanical Engineering, Rio de Janeiro (Brazil); Sampaio, L.E.B. [LMTA/PGMEC, UFF, Department of Mechanical Engineering, Laboratory of Theoretical and Applied Mechanics, Rio de Janeiro (Brazil); Serfaty, R. [Petrobras R and D Center, Rio de Janeiro (Brazil)

    2012-03-15

    A non-intrusive optical technique was developed to provide time-resolved longitudinal and cross-sectional images of the liquid film in horizontal annular pipe flow of air and water, revealing the interfacial wave behavior. Quantitative information on the liquid film dynamics was extracted from the time-resolved images. The planar laser-induced fluorescence technique was utilized to allow for optical separation of the light emitted by the film from that scattered by the air-water interface. The visualization test section was fabricated from a tube presenting nearly the same refractive index as water, which allowed the visualization of the liquid film at regions very close to the pipe wall. Longitudinal images of the liquid film were captured using a high-frame-rate digital video camera synchronized with a high-repetition-rate laser. An image processing algorithm was developed to automatically detect the position of the air-water interface in each image frame. The thickness of the liquid film was measured at two axial stations in each processed image frame, providing time history records of the film thickness at two different positions. Wave frequency information was obtained by analyzing the time-dependent signals of film thickness for each of the two axial positions recorded. Wave velocities were measured by cross-correlating the amplitude signals from the two axial positions. For the film cross-section observations, two high-speed digital video cameras were used in a stereoscopic arrangement. Comparisons with results from different techniques available in literature indicate that the technique developed presents equivalent accuracy in measuring the liquid film properties. Time-resolved images of longitudinal and cross-section views of the film were recorded, which constitute valuable information provided by the technique implemented. (orig.)

  12. SIGGMA: A SURVEY OF IONIZED GAS IN THE GALAXY, MADE WITH THE ARECIBO TELESCOPE

    Energy Technology Data Exchange (ETDEWEB)

    Liu, B. [National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China); McIntyre, T. [University of New Mexico, Albuquerque, NM 87131 (United States); Terzian, Y. [Cornell University, Ithaca, NY 14853 (United States); Minchin, R. [Arecibo Observatory, HC03 Box 53995, Arecibo 00612, PR (United States); Anderson, L. [West Virginia University, Morgantown, WV 26506 (United States); Churchwell, E. [University of Wisconsin-Madison, Madison, WI 53706 (United States); Lebron, M. [University of Puerto Rico, P.O. Box 23323, 00931-3323, San Juan (Puerto Rico); Roshi, D. Anish [National Radio Astronomy Observatory, Green Bank and Charlottesville, VA 22903 (United States)

    2013-10-01

    A Survey of Ionized Gas in the Galaxy, made with the Arecibo telescope (SIGGMA), uses the Arecibo L-band Feed Array (ALFA) to fully sample the Galactic plane (30 Degree-Sign {<=} l {<=} 75 Degree-Sign and -2 Degree-Sign {<=} b {<=} 2 Degree-Sign ; 175 Degree-Sign {<=} l {<=} 207 Degree-Sign and -2 Degree-Sign {<=} b {<=} 1 Degree-Sign ) observable with the telescope in radio recombination lines (RRLs). Processed data sets are being produced in the form of data cubes of 2 Degree-Sign (along l) Multiplication-Sign 4 Degree-Sign (along b) Multiplication-Sign 151 (number of channels), archived and made public. The 151 channels cover a velocity range of 600 km s{sup -1} and the velocity resolution of the survey changes from 4.2 km s{sup -1} to 5.1 km s{sup -1} from the lowest frequency channel to the highest frequency channel. RRL maps with 3.'4 resolution and a line flux density sensitivity of {approx}0.5 mJy will enable us to identify new H II regions, measure their electron temperatures, study the physics of photodissociation regions with carbon RRLs, and investigate the origin of the extended low-density medium. Twelve Hn{alpha} lines fall within the 300 MHz bandpass of ALFA; they are resampled to a common velocity resolution to improve the signal-to-noise ratio (S/N) by a factor of three or more and preserve the line width. SIGGMA will produce the most sensitive fully sampled RRL survey to date. Here, we discuss the observing and data reduction techniques in detail. A test observation toward the H II region complex S255/S257 has detected Hn{alpha} and Cn{alpha} lines with S/N > 10.

  13. Discovery of nine extended ionized gas clouds in a z = 0.4 cluster

    International Nuclear Information System (INIS)

    Yagi, Masafumi; Koyama, Yusei; Kodama, Tadayuki; Gu, Liyi; Nakata, Fumiaki; Hattori, Takashi; Yoshida, Michitoshi

    2015-01-01

    From deep Hα imaging data of Suprime-Cam/Subaru, we discovered nine extended ionized gas clouds (EIG) around galaxies in the Abell 851 cluster (A851) at z = 0.4. We surveyed a 30 × 25 arcmin region, and the EIGs were found only near the cluster center (<2.3 arcmin ∼ 750 kpc). The parent galaxies of the EIGs are star-forming or post-starburst galaxies, all of which are spectroscopically confirmed members of the cluster. Four out of the nine parent galaxies show distortion of stellar distribution in the disk, which can be a sign of recent interaction, and the interaction may have made the EIGs. On the other hand, six parent galaxies (one overlaps those exhibiting distortion) show Hα emission without stars, which implies ram pressure stripping. The spectrum of the brightest parent galaxy shows a post-starburst signature and resembles the Hα stripped galaxies found in the Coma cluster. Meanwhile, two brightest parent galaxies in A851 are more massive than the EIG parent galaxies in the Coma cluster. This is consistent with a “downsizing” of star-forming galaxies, though it is still within the statistical variance. We also analyzed Suprime-Cam data of another z=0.39 cluster, CL0024+17, but found no EIGs. The key difference between A851 and CL0024+17 would be the existence of a subcluster colliding with the main body of A851, in which six or seven out of the nine parent galaxies in A851 exist, and the fraction of EIGs in the subcluster is significantly higher than the main subcluster of A851 and CL0024+17.

  14. Discovery of nine extended ionized gas clouds in a z = 0.4 cluster

    Energy Technology Data Exchange (ETDEWEB)

    Yagi, Masafumi; Koyama, Yusei; Kodama, Tadayuki [Optical and Infrared Astronomy Division, National Astronomical Observatory of Japan, 2-21-1, Osawa, Mitaka, Tokyo, 181-8588 (Japan); Gu, Liyi [Research Center for the Early Universe, School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0011 (Japan); Nakata, Fumiaki; Hattori, Takashi [Subaru Telescope, 650 North A' ohoku Place, Hilo, HI 96720 (United States); Yoshida, Michitoshi, E-mail: YAGI.Masafumi@nao.ac.jp [Hiroshima Astrophysical Science Center, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526 (Japan)

    2015-02-01

    From deep Hα imaging data of Suprime-Cam/Subaru, we discovered nine extended ionized gas clouds (EIG) around galaxies in the Abell 851 cluster (A851) at z = 0.4. We surveyed a 30 × 25 arcmin region, and the EIGs were found only near the cluster center (<2.3 arcmin ∼ 750 kpc). The parent galaxies of the EIGs are star-forming or post-starburst galaxies, all of which are spectroscopically confirmed members of the cluster. Four out of the nine parent galaxies show distortion of stellar distribution in the disk, which can be a sign of recent interaction, and the interaction may have made the EIGs. On the other hand, six parent galaxies (one overlaps those exhibiting distortion) show Hα emission without stars, which implies ram pressure stripping. The spectrum of the brightest parent galaxy shows a post-starburst signature and resembles the Hα stripped galaxies found in the Coma cluster. Meanwhile, two brightest parent galaxies in A851 are more massive than the EIG parent galaxies in the Coma cluster. This is consistent with a “downsizing” of star-forming galaxies, though it is still within the statistical variance. We also analyzed Suprime-Cam data of another z=0.39 cluster, CL0024+17, but found no EIGs. The key difference between A851 and CL0024+17 would be the existence of a subcluster colliding with the main body of A851, in which six or seven out of the nine parent galaxies in A851 exist, and the fraction of EIGs in the subcluster is significantly higher than the main subcluster of A851 and CL0024+17.

  15. Probing Conditions at Ionized/Molecular Gas Interfaces With High Resolution Near-Infrared Spectroscopy

    Science.gov (United States)

    Kaplan, Kyle Franklin

    2017-08-01

    Regions of star formation and star death in our Galaxy trace the cycle of gas and dust in the interstellar medium (ISM). Gas in dense molecular clouds collapses to form stars, and stars at the end of their lives return the gas that made up their outer layers back out into the Galaxy. Hot stars generate copious amounts of ultraviolet photons which interact with the surrounding medium and dominate the energetics, ionization state, and chemistry of the gas. The interface where molecular gas is being dissociated into neutral atomic gas by far-UV photons from a nearby hot source is called a photodissociation or photon-dominated region (PDR). PDRs are found primarily in star forming regions where O and B stars serve as the source of UV photons, and in planetary nebulae where the hot core of the dying star acts as the UV source. The main target of this dissertation is molecular hydrogen (H2), the most abundant molecule in the Universe, made from hydrogen formed during the Big Bang. H2 makes up the overwhelming majority of molecules found in the ISM and in PDRs. Far-UV radiation absorbed by H2 will excite an electron in the molecule. The molecule then either dissociates ( 10% of the time; Field et al. 1966) or decays into excited rotational and vibrational ("rovibrational") levels of the electronic ground state. These excited rovibrational levels then decay via a radiative cascade to the ground rovibrational state (v = 0, J = 0), giving rise to a large number of transitions observable in emission from the mid-IR to the optical (Black & van Dishoeck, 1987). These transitions provide an excellent probe of the excitation and conditions within the gas. These transitions are also observed in warm H2, such as in shocks, where collisions excite H2 to higher rovibrational levels. High resolution near-infrared spectroscopy, with its ability to see through dust, and avoid telluric absorption and emission, serves as an effective tool to detect emission from ions, atoms, and molecules

  16. Noble-gas ionization in the ion source with Penning effect

    International Nuclear Information System (INIS)

    Monchka, D.; Lyatushinskij, A.; Vasyak, A.

    1982-01-01

    By additional use of that the ion source efficiency can be increased the Penning ionization. The results of estimates of certain coefficients for the processes taking place in the plasma ion sources are presented

  17. CT diagnosis of annular pancreas

    International Nuclear Information System (INIS)

    Ueno, Eiko; Isobe, Yoshinori; Niimi, Akiko; Shimizu, Yasushi; Yamada, Akiyoshi; Hanyu, Fujio

    1987-01-01

    CT scan was performed in two cases of annular pancreas which could be found in one case preoperatively and in the other case retrospectively. CT scan demonstrated secondary changes of annular pancreas such as medial displacement and dilatation of the duodenal bulb in the former case and stenosis of the duodenal loop and thickened soft tissue density around the narrow segment of the duodenal loop in the latter case, although it failed to demonstrate the peninsular protrusion of the parenchyma of the pancreas head. These findings suggest high possibility of diagnosing annular pancreas by CT scan. (author)

  18. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

    International Nuclear Information System (INIS)

    Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J.

    2015-01-01

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

  19. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

    Energy Technology Data Exchange (ETDEWEB)

    Li, Du-Xin; Gan, Lin; Bronja, Amela [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany); Schmitz, Oliver J., E-mail: oliver.schmitz@uni-due.de [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany)

    2015-09-03

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

  20. Ionization of Local Interstellar Gas Based on STIS and FUSE spectra of Nearby Stars

    Science.gov (United States)

    Redfield, Seth; Linsky, J. L.

    2009-01-01

    The ultraviolet contains many resonance line transitions that are sensitive to a range of ionization stages of ions present in the local interstellar medium (LISM). We couple observations of high resolution ultraviolet spectrographs, STIS and GHRS on the Hubble Space Telescope (HST) and the Far-Ultraviolet Spectroscopic Explorer (FUSE) in order to make a comprehensive survey of the ionization structure of the local interstellar medium. In particular, we focus on the sight line toward G191-B2B, a nearby (69 pc) white dwarf. We present interstellar detections of highly ionized elements (e.g., SiIII, CIII, CIV, etc) and compare them directly to neutral or singly ionized LISM detections (e.g., SiII, CII, etc). The extensive observations of G191-B2B provides an opportunity for a broad study of ionization stages of several elements, while a survey of several sight lines provides a comprehensive look at the ionization structure of the LISM. We acknowledge support for this project through NASA FUSE Grant NNX06AD33G.

  1. Thermo-acoustic cross-talk between cans in a can-annular combustor

    NARCIS (Netherlands)

    Farisco, Federica; Panek, Lukasz; Kok, Jim B.W.

    2017-01-01

    Thermo-acoustic instabilities in gas turbine engines are studied to avoid engine failure. Compared to the engines with annular combustors, the can-annular combustor design should be less vulnerable to acoustic burner-to-burner interaction, since the burners are acoustically coupled only by the

  2. PRESENT-DAY GALACTIC EVOLUTION: LOW-METALLICITY, WARM, IONIZED GAS INFLOW ASSOCIATED WITH HIGH-VELOCITY CLOUD COMPLEX A

    Energy Technology Data Exchange (ETDEWEB)

    Barger, K. A.; Haffner, L. M.; Wakker, B. P.; Hill, Alex S. [Department of Astronomy, University of Wisconsin-Madison, Madison, WI 53706 (United States); Madsen, G. J. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Duncan, A. K., E-mail: kbarger@astro.wisc.edu, E-mail: haffner@astro.wisc.edu, E-mail: Alex.Hill@csiro.au, E-mail: wakker@astro.wisc.edu, E-mail: greg.madsen@sydney.edu.au [Rose-Hulman Institute of Technology, Terre Haute, IN 47803 (United States)

    2012-12-20

    The high-velocity cloud Complex A is a probe of the physical conditions in the Galactic halo. The kinematics, morphology, distance, and metallicity of Complex A indicate that it represents new material that is accreting onto the Galaxy. We present Wisconsin H{alpha} Mapper kinematically resolved observations of Complex A over the velocity range of -250 to -50 km s{sup -1} in the local standard of rest reference frame. These observations include the first full H{alpha} intensity map of Complex A across (l, b) = (124 Degree-Sign , 18 Degree-Sign ) to (171 Degree-Sign , 53 Degree-Sign ) and deep targeted observations in H{alpha}, [S II] {lambda}6716, [N II] {lambda}6584, and [O I] {lambda}6300 toward regions with high H I column densities, background quasars, and stars. The H{alpha} data imply that the masses of neutral and ionized material in the cloud are similar, both being greater than 10{sup 6} M{sub Sun }. We find that the Bland-Hawthorn and Maloney model for the intensity of the ionizing radiation near the Milky Way is consistent with the known distance of the high-latitude part of Complex A and an assumed cloud geometry that puts the lower-latitude parts of the cloud at a distance of 7-8 kpc. This compatibility implies a 5% ionizing photon escape fraction from the Galactic disk. We also provide the nitrogen and sulfur upper abundance solutions for a series of temperatures, metallicities, and cloud configurations for purely photoionized gas; these solutions are consistent with the sub-solar abundances found by previous studies, especially for temperatures above 10{sup 4} K or for gas with a high fraction of singly ionized nitrogen and sulfur.

  3. Propagating annular modes

    Science.gov (United States)

    Sheshadri, A.; Plumb, R. A.

    2017-12-01

    The leading "annular mode", defined as the dominant EOF of surface pressure or of zonal mean zonal wind variability, appears as a dipolar structure straddling the mean midlatitude jet and thus seems to describe north-south wobbling of the jet latitude. However, extratropical zonal wind anomalies frequently tend to migrate poleward. This behavior can be described by the first two EOFs, the first (AM1) being the dipolar structure, and the second (AM2) having a tripolar structure centered on the mean jet. Taken in isolation, AM1 thus describes a north-south wobbling of the jet position, while AM2 describes a strengthening and narrowing of the jet. However, despite the fact that they are spatially orthogonal, and their corresponding time series temporally orthogonal, AM1 and AM2 are not independent, but show significant lag-correlations which reveal the propagation. The EOFs are not modes of the underlying dynamical system governing the zonal flow evolution. The true modes can be estimated using principal oscillation pattern (POP) analysis. In the troposphere, the leading POPs manifest themselves as a pair of complex conjugate structures with conjugate eigenvalues thus, in reality, constituting a single, complex, mode that describes propagating anomalies. Even though the principal components associated with the two leading EOFs decay at different rates, each decays faster than the true mode. These facts have implications for eddy feedback and the susceptibility of the mode to external perturbations. If one interprets the annular modes as the modes of the system, then simple theory predicts that the response to steady forcing will usually be dominated by AM1 (with the longest time scale). However, such arguments should really be applied to the true modes. Experiments with a simplified GCM show that climate response to perturbations do not necessarily have AM1 structures. Implications of these results for stratosphere-troposphere interactions are explored. The POP

  4. Manufacture of annular cermet articles

    Science.gov (United States)

    Forsberg, Charles W.; Sikka, Vinod K.

    2004-11-02

    A method to produce annular-shaped, metal-clad cermet components directly produces the form and avoids multiple fabrication steps such as rolling and welding. The method includes the steps of: providing an annular hollow form with inner and outer side walls; filling the form with a particulate mixture of ceramic and metal; closing, evacuating, and hermetically sealing the form; heating the form to an appropriate temperature; and applying force to consolidate the particulate mixture into solid cermet.

  5. Dynamics of Newtonian annular jets

    International Nuclear Information System (INIS)

    Paul, D.D.

    1978-12-01

    The main objectives of this investigation are to identify the significant parameters affecting the dynamics of Newtonian annular jets, and to develop theoretical models for jet break-up and collapse. This study has been motivated by recent developments in laser-fusion reactor designs; one proposed cavity design involves the use of an annular lithium jet to protect the cavity wall from the pellet debris emanating from the microexplosion

  6. In gas laser ionization and spectroscopy experiments at the Superconducting Separator Spectrometer (S3): Conceptual studies and preliminary design

    International Nuclear Information System (INIS)

    Ferrer, R.; Bastin, B.; Boilley, D.; Creemers, P.; Delahaye, P.; Liénard, E.; Fléchard, X.; Franchoo, S.; Ghys, L.; Huyse, M.; Kudryavtsev, Yu.; Lecesne, N.; Lu, H.; Lutton, F.; Mogilevskiy, E.; Pauwels, D.; Piot, J.; Radulov, D.; Rens, L.; Savajols, H.

    2013-01-01

    Highlights: • A setup to perform In-Gas Laser Ionization and Spectroscopy experiments at the Super Separator Spectrometer is presented. • The reported studies address important aspects necessary to applied the IGLIS technique to short-lived isotopes. • An R and D phase required to reach an enhanced spectral resolution will be carried out at KU Leuven. • High-sensitivity and enhanced-resolution laser spectroscopy studies will be possible with the IGLIS setup at S 3 . -- Abstract: The results of preparatory experiments and the preliminary designs of a new in-gas laser ionization and spectroscopy setup, to be coupled to the Super Separator Spectrometer S 3 of SPIRAL2-GANIL, are reported. Special attention is given to the development and tests to carry out a full implementation of the in-gas jet laser spectroscopy technique. Application of this novel technique to radioactive species will allow high-sensitivity and enhanced-resolution laser spectroscopy studies of ground- and excited-state properties of exotic nuclei

  7. Gas-phase reaction rate constants for atmospheric pressure ionization in ion-mobility spectrometry

    International Nuclear Information System (INIS)

    Vandiver, V.J.

    1987-01-01

    Ion-mobility spectrometry (IMS) is an instrumental technique in which gaseous ions are formed from neutral molecules by proton and charge transfer from reactant ions through collisional ionization. An abbreviated rate theory has been proposed for atmospheric pressure ionization (API) in IMS, but supporting experimental measurements have not been reported. The objectives of this thesis were (1) assessment of existing API rate theory using positive and negative product ions in IMS, (2) measurement of API equilibria and kinetics for binary mixtures, and (3) investigating of cross-ionizations with multiple-product ions in API reactions. Although IMS measurements and predictions from rate theory were comparable, shapes and slopes of response curves for both proton transfer and electron capture were not described exactly by existing theory. In particular, terms that are needed for calculation of absolute rate constants were unsuitable in the existing theory. These included recombination coefficients,initial number of reactant ions, and opposing ion densities

  8. Determination of low specific activity iodine-129 off-gas concentrations by GC separation and negative ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, S.J.; Rankin, R.A.; McManus, G.J.; Nielsen, R.A.; Delmore, J.E.; Hohorst, F.A.; Murphy, L.P.

    1983-09-01

    This document is the final report of the laboratory development of a method for determining the specific activity of the /sup 129/I emitted from a nuclear fuel reprocessing plant. The technique includes cryogenic sample collection, chemical form separation, quantitation by gas chromatography, and specific activity measurement of each chemical species by negative ionization mass spectrometry. The major conclusions were that both organic and elemental iodine can be quantitatively collected without fractionation and that specific activity measurements as low as one atom of /sup 129/I per 10/sup 5/ atoms of /sup 127/I are possible.

  9. Determination of low specific activity iodine-129 off-gas concentrations by GC separation and negative ionization mass spectrometry

    International Nuclear Information System (INIS)

    Fernandez, S.J.; Rankin, R.A.; McManus, G.J.; Nielsen, R.A.; Delmore, J.E.; Hohorst, F.A.; Murphy, L.P.

    1983-09-01

    This document is the final report of the laboratory development of a method for determining the specific activity of the 129 I emitted from a nuclear fuel reprocessing plant. The technique includes cryogenic sample collection, chemical form separation, quantitation by gas chromatography, and specific activity measurement of each chemical species by negative ionization mass spectrometry. The major conclusions were that both organic and elemental iodine can be quantitatively collected without fractionation and that specific activity measurements as low as one atom of 129 I per 10 5 atoms of 127 I are possible

  10. Annular MHD Physics for Turbojet Energy Bypass

    Science.gov (United States)

    Schneider, Steven J.

    2011-01-01

    The use of annular Hall type MHD generator/accelerator ducts for turbojet energy bypass is evaluated assuming weakly ionized flows obtained from pulsed nanosecond discharges. The equations for a 1-D, axisymmetric MHD generator/accelerator are derived and numerically integrated to determine the generator/accelerator performance characteristics. The concept offers a shockless means of interacting with high speed inlet flows and potentially offers variable inlet geometry performance without the complexity of moving parts simply by varying the generator loading parameter. The cycle analysis conducted iteratively with a spike inlet and turbojet flying at M = 7 at 30 km altitude is estimated to have a positive thrust per unit mass flow of 185 N-s/kg. The turbojet allowable combustor temperature is set at an aggressive 2200 deg K. The annular MHD Hall generator/accelerator is L = 3 m in length with a B(sub r) = 5 Tesla magnetic field and a conductivity of sigma = 5 mho/m for the generator and sigma= 1.0 mho/m for the accelerator. The calculated isentropic efficiency for the generator is eta(sub sg) = 84 percent at an enthalpy extraction ratio, eta(sub Ng) = 0.63. The calculated isentropic efficiency for the accelerator is eta(sub sa) = 81 percent at an enthalpy addition ratio, eta(sub Na) = 0.62. An assessment of the ionization fraction necessary to achieve a conductivity of sigma = 1.0 mho/m is n(sub e)/n = 1.90 X 10(exp -6), and for sigma = 5.0 mho/m is n(sub e)/n = 9.52 X 10(exp -6).

  11. Comparison of Gas Chromatography-Mass Spectrometry and Gas Chromatography-Tandem Mass Spectrometry with Electron Ionization and Negative-Ion Chemical Ionization for Analyses of Pesticides at Trace Levels in Atmospheric Samples

    Directory of Open Access Journals (Sweden)

    Renata Raina

    2008-01-01

    Full Text Available A comparison of detection limits of gas chromatography-mass spectrometry (GC-MS in selected ion monitoring (SIM with gas chromatography-tandem mass spectrometry (GC-MS/MS in selected reaction monitoring (SRM mode with both electron ionization (EI and negative-ion chemical ionization (NCI are presented for over 50 pesticides ranging from organochlorines (OCs, organophosphorus pesticides (OPs and pre-emergent herbicides used in the Canadian prairies (triallate, trifluralin, ethalfluralin. The developed GC-EI/SIM, GC-NCI/SIM, and GC-NCI/SRM are suitable for the determination of pesticides in air sample extracts at concentrations <100 pg µL -1 (< 100 pg m -3 in air. No one method could be used to analyze the range of pre-emergent herbicides, OPs, and OCs investigated. In general GC-NCI/SIM provided the lowest method detection limits (MDLs commonly 2.5-10 pg µL -1 along with best confirmation (<25% RSD of ion ratio, while GC-NCI/SRM is recommended for use where added selectivity or confirmation is required (such as parathion-ethyl, tokuthion, carbofenothion. GC-EI/SRM at concentration < 100 pg µL -1 was not suitable for most pesticides. GC-EI/SIM was more prone to interference issues than NCI methods, but gave good sensitivity (MDLs 1-10 pg µL -1 for pesticides with poor NCI response (OPs: sulfotep, phorate, aspon, ethion, and OCs: alachlor, aldrin, perthane, and DDE, DDD, DDT.

  12. The Effects of Added Hydrogen on Noble Gas Discharges Used as Ambient Desorption/Ionization Sources for Mass Spectrometry

    Science.gov (United States)

    Ellis, Wade C.; Lewis, Charlotte R.; Openshaw, Anna P.; Farnsworth, Paul B.

    2016-09-01

    We demonstrate the effectiveness of using hydrogen-doped argon as the support gas for the dielectric barrier discharge (DBD) ambient desorption/ionization (ADI) source in mass spectrometry. Also, we explore the chemistry responsible for the signal enhancement observed when using both hydrogen-doped argon and hydrogen-doped helium. The hydrogen-doped argon was tested for five analytes representing different classes of molecules. Addition of hydrogen to the argon plasma gas enhanced signals for gas-phase analytes and for analytes coated onto glass slides in positive and negative ion mode. The enhancements ranged from factors of 4 to 5 for gas-phase analytes and factors of 2 to 40 for coated slides. There was no significant increase in the background. The limit of detection for caffeine was lowered by a factor of 79 using H2/Ar and 2 using H2/He. Results are shown that help explain the fundamental differences between the pure-gas discharges and those that are hydrogen-doped for both argon and helium. Experiments with different discharge geometries and grounding schemes indicate that observed signal enhancements are strongly dependent on discharge configuration.

  13. Reliability of semiconductor and gas-filled diodes for over-voltage protection exposed to ionizing radiation

    Directory of Open Access Journals (Sweden)

    Stanković Koviljka

    2009-01-01

    Full Text Available The wide-spread use of semiconductor and gas-filled diodes for non-linear over-voltage protection results in a variety of possible working conditions. It is therefore essential to have a thorough insight into their reliability in exploitation environments which imply exposure to ionizing radiation. The aim of this paper is to investigate the influence of irradiation on over-voltage diode characteristics by exposing the diodes to californium-252 combined neutron/gamma radiation field. The irradiation of semiconductor over-voltage diodes causes severe degradation of their protection characteristics. On the other hand, gas-filled over-voltage diodes exhibit a temporal improvement of performance. The results are presented with the accompanying theoretical interpretations of the observed changes in over-voltage diode behaviour, based on the interaction of radiation with materials constituting the diodes.

  14. Analysis of benzene, toluene, ethylbenzene and xylenes in soils by headspace and gas chromatography/flame ionization detector

    Directory of Open Access Journals (Sweden)

    Jurandir Pereira Pinto

    2006-02-01

    Full Text Available The constituents of gasoline: benzene, toluene, ethylbenzene and xylenes (BTEX are frequently found in soils due to leaks in fuel storage tanks and they present chronic toxicity. In this work it was developed and validated a methodology of BTEX analysis in soil by gas chromatography/ flame ionization detector and static headspace. The recovery of BTEX in soil samples was evaluated using soils with different textures (sandy and loamy. The analysis method showed good resolution, in a low time of analysis (less than 30 minutes. Limits of quantification of 0.05 mg Kg¯¹ soil for benzene, toluene, ethylbenzene and xylenes are below the guiding values that range from 0.15 to 95 mg Kg¯¹ soil, established to determine soil quality. It was verified that the methodology enables the use of this method for BTEX analysis of soil samples for passive environmental identification of gas stations.

  15. Analysis of acylcarnitines as their N-demethylated ester derivatives by gas chromatography-chemical ionization mass spectrometry.

    Science.gov (United States)

    Huang, Z H; Gage, D A; Bieber, L L; Sweeley, C C

    1991-11-15

    A novel approach to the analysis of acylcarnitines has been developed. It involves a direct esterification using propyl chloroformate in aqueous propanol followed by ion-pair extraction with potassium iodide into chloroform and subsequent on-column N-demethylation of the resulting acylcarnitine propyl ester iodides. The products, acyl N-demethylcarnitine propyl esters, are volatile and are easily analyzed by gas chromatography-chemical ionization mass spectrometry. For medium-chain-length (C4-C12) acylcarnitine standards, detection limits are demonstrated to be well below 1 ng starting material using selected ion monitoring. Well-separated gas chromatographic peaks and structure-specific mass spectra are obtained with samples of synthetic and biological origin. Seven acylcarnitines have been characterized in the urine of a patient suffering from medium-chain acyl-CoA dehydrogenase deficiency.

  16. H ii REGION G46.5-0.2: THE INTERPLAY BETWEEN IONIZING RADIATION, MOLECULAR GAS, AND STAR FORMATION

    International Nuclear Information System (INIS)

    Paron, S.; Ortega, M. E.; Dubner, G.; Petriella, A.; Giacani, E.; Yuan, Jing-Hua; Li, Jin Zeng; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju; Wu, Yuefang

    2015-01-01

    H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey ( 13 CO J = 1–0) and from the James Clerk Maxwell Telescope data archive ( 12 CO, 13 CO, C 18 O J = 3–2, HCO + , and HCN J = 4–3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10′ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution

  17. H ii REGION G46.5-0.2: THE INTERPLAY BETWEEN IONIZING RADIATION, MOLECULAR GAS, AND STAR FORMATION

    Energy Technology Data Exchange (ETDEWEB)

    Paron, S.; Ortega, M. E.; Dubner, G.; Petriella, A.; Giacani, E. [Instituto de Astronomía y Física del Espacio (IAFE, CONICET-UBA), CC 67, Suc. 28, 1428 Buenos Aires (Argentina); Yuan, Jing-Hua; Li, Jin Zeng; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju [National Astronomical Observatories, Chinese Academy of Sciences, 20 A Datun Road, Chaoyang District, Beijing 100012 (China); Wu, Yuefang, E-mail: sparon@iafe.uba.ar [Department of Astronomy, Peking University, 100871 Beijing (China)

    2015-06-15

    H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey ({sup 13}CO J = 1–0) and from the James Clerk Maxwell Telescope data archive ({sup 12}CO, {sup 13}CO, C{sup 18}O J = 3–2, HCO{sup +}, and HCN J = 4–3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10′ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution.

  18. H II Region G46.5-0.2: The Interplay between Ionizing Radiation, Molecular Gas, and Star Formation

    Science.gov (United States)

    Paron, S.; Ortega, M. E.; Dubner, G.; Yuan, Jing-Hua; Petriella, A.; Giacani, E.; Zeng Li, Jin; Wu, Yuefang; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju

    2015-06-01

    H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey (13CO J = 1-0) and from the James Clerk Maxwell Telescope data archive (12CO, 13CO, C18O J = 3-2, HCO+, and HCN J = 4-3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10‧ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution.

  19. ANALYSIS AND IDENTIFICATION SPIKING CHEMICAL COMPOUNDS RELATED TO CHEMICAL WEAPON CONVENTION IN UNKNOWN WATER SAMPLES USING GAS CHROMATOGRAPHY AND GAS CHROMATOGRAPHY ELECTRON IONIZATION MASS SPECTROMETRY

    Directory of Open Access Journals (Sweden)

    Harry Budiman

    2010-06-01

    Full Text Available The identification and analysis of chemical warfare agents and their degradation products is one of important component for the implementation of the convention. Nowadays, the analytical method for determination chemical warfare agent and their degradation products has been developing and improving. In order to get the sufficient analytical data as recommended by OPCW especially in Proficiency Testing, the spiking chemical compounds related to Chemical Weapon Convention in unknown water sample were determined using two different techniques such as gas chromatography and gas chromatography electron-impact ionization mass spectrometry. Neutral organic extraction, pH 11 organic extraction, cation exchanged-methylation, triethylamine/methanol-silylation were performed to extract the chemical warfare agents from the sample, before analyzing with gas chromatography. The identification of chemical warfare agents was carried out by comparing the mass spectrum of chemicals with mass spectrum reference from the OPCW Central Analytical Database (OCAD library while the retention indices calculation obtained from gas chromatography analysis was used to get the confirmation and supported data of  the chemical warfare agents. Diisopropyl methylphosphonate, 2,2-diphenyl-2-hydroacetic acid and 3-quinuclidinol were found in unknown water sample. Those chemicals were classified in schedule 2 as precursor or reactant of chemical weapons compound in schedule list of Chemical Weapon Convention.   Keywords: gas chromatography, mass spectrometry, retention indices, OCAD library, chemical warfare agents

  20. Ionized and Molecular Gas Kinematics in a z = 1.4 Star-forming Galaxy

    Science.gov (United States)

    Übler, H.; Genzel, R.; Tacconi, L. J.; Förster Schreiber, N. M.; Neri, R.; Contursi, A.; Belli, S.; Nelson, E. J.; Lang, P.; Shimizu, T. T.; Davies, R.; Herrera-Camus, R.; Lutz, D.; Plewa, P. M.; Price, S. H.; Schuster, K.; Sternberg, A.; Tadaki, K.; Wisnioski, E.; Wuyts, S.

    2018-02-01

    We present deep observations of a z = 1.4 massive, star-forming galaxy (SFG) in molecular and ionized gas at comparable spatial resolution (CO 3–2, NOrthern Extended Millimeter Array (NOEMA); Hα, Large Binocular Telescope (LBT)). The kinematic tracers agree well, indicating that both gas phases are subject to the same gravitational potential and physical processes affecting the gas dynamics. We combine the one-dimensional velocity and velocity dispersion profiles in CO and Hα to forward-model the galaxy in a Bayesian framework, combining a thick exponential disk, a bulge, and a dark matter halo. We determine the dynamical support due to baryons and dark matter, and find a dark matter fraction within one effective radius of {f}DM}(≤slant {R}e)={0.18}-0.04+0.06. Our result strengthens the evidence for strong baryon-dominance on galactic scales of massive z ∼ 1–3 SFGs recently found based on ionized gas kinematics alone. Based on observations carried out with the IRAM Interferometer NOEMA. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain). Based on observations carried out with the LBT. The LBT is an international collaboration among institutions in the United States, Italy, and Germany. LBT Corporation partners are: LBT Beteiligungsgesellschaft, Germany, representing the Max-Planck Society, The Leibniz Institute for Astrophysics Potsdam, and Heidelberg University; The University of Arizona on behalf of the Arizona Board of Regents; Istituto Nazionale di Astrofisica, Italy; The Ohio State University, and The Research Corporation, on behalf of The University of Notre Dame, University of Minnesota and University of Virginia.

  1. Mid-section of a can-annular gas turbine engine with an improved rotation of air flow from the compressor to the turbine

    Science.gov (United States)

    Little, David A.; Schilp, Reinhard; Ross, Christopher W.

    2016-03-22

    A midframe portion (313) of a gas turbine engine (310) is presented and includes a compressor section with a last stage blade to orient an air flow (311) at a first angle (372). The midframe portion (313) further includes a turbine section with a first stage blade to receive the air flow (311) oriented at a second angle (374). The midframe portion (313) further includes a manifold (314) to directly couple the air flow (311) from the compressor section to a combustor head (318) upstream of the turbine section. The combustor head (318) introduces an offset angle in the air flow (311) from the first angle (372) to the second angle (374) to discharge the air flow (311) from the combustor head (318) at the second angle (374). While introducing the offset angle, the combustor head (318) at least maintains or augments the first angle (372).

  2. A combined segmented anode gas ionization chamber and time-of-flight detector for heavy ion elastic recoil detection analysis

    Science.gov (United States)

    Ström, Petter; Petersson, Per; Rubel, Marek; Possnert, Göran

    2016-10-01

    A dedicated detector system for heavy ion elastic recoil detection analysis at the Tandem Laboratory of Uppsala University is presented. Benefits of combining a time-of-flight measurement with a segmented anode gas ionization chamber are demonstrated. The capability of ion species identification is improved with the present system, compared to that obtained when using a single solid state silicon detector for the full ion energy signal. The system enables separation of light elements, up to Neon, based on atomic number while signals from heavy elements such as molybdenum and tungsten are separated based on mass, to a sample depth on the order of 1 μm. The performance of the system is discussed and a selection of material analysis applications is given. Plasma-facing materials from fusion experiments, in particular metal mirrors, are used as a main example for the discussion. Marker experiments using nitrogen-15 or oxygen-18 are specific cases for which the described improved species separation and sensitivity are required. Resilience to radiation damage and significantly improved energy resolution for heavy elements at low energies are additional benefits of the gas ionization chamber over a solid state detector based system.

  3. EXPLOSION OF ANNULAR CHARGE ON DUSTY SURFASE

    Directory of Open Access Journals (Sweden)

    A. Levin Vladimir

    2017-01-01

    Full Text Available This problem is related to the safety problem in the area of forest fires. It is well known that is possible to extinguish a fire, for example, by means of a powerful air stream. Such flow arises from the explosive shock wave. To enhance the im- pact of the blast wave can be used an explosive charge of annular shape. The shock wave, produced by the explosion, in- creased during moves to the center and can serve as a means of transportation dust in the seat of the fire. In addition, emerging after the collapse of a converging shock wave strong updraft can raise dust on a greater height and facilitate fire extinguishing, precipitating dust over a large area. This updraft can be dangerous for aircraft that are in the sky above the fire. To determine the width and height of the danger zone performed the numerical simulation of the ring of the explosion and the subsequent movement of dust and gas mixtures. The gas is considered ideal and perfect. The explosion is modeled as an instantaneous increase in the specific internal energy in an annular zone on the value of the specific heat of explosives. The flow is consid- ered as two-dimensional, and axisymmetric. The axis of symmetry perpendicular to the Earth surface. This surface is considered to be absolutely rigid and is considered as the boundary of the computational domain. On this surface is exhibited the condition of no motion. For the numerical method S. K. Godunov is used a movable grid. One system of lines of this grid is moved in accordance with movement of the shock wave. Others lines of this grid are stationary. The calculations were per- formed for different values of the radii of the annular field and for different sizes of rectangular cross-sectional of the annular field. Numerical results show that a very strong flow is occurring near the axis of symmetry and the particles rise high above the surface. These calculations allow us to estimate the sizes of the zone of danger in specific

  4. Nature of the ionizing source of the nuclear gas in NGC 1052

    International Nuclear Information System (INIS)

    Keel, W.C.; Miller, J.S.

    1983-01-01

    We examine the ionization and physical state of the emission-line region in the nucleus of elliptical galaxy NGC 1052. The [O III] lambda4363/lambda5007 ratio, frequently used as a diagnostic for ionization mechanisms, is very poorly determined because of difficulties in matching the underlying stellar continuum spectrum, which is unusual in having very strong lines for the galaxy luminosity. Within these limitations, we find the [O III] temperature to be only marginally compatible with shock models, and the overall emission spectrum to be better fitted by photoionization models with a very dilute flat-spectrum central source. In any event, the case for NGC 1052 as a shock-heated nucleus is not strong

  5. Propagation of fast ionization waves in long discharge tubes filled with a preionized gas

    International Nuclear Information System (INIS)

    Boutine, O.V.; Vasilyak, L.M.

    1999-01-01

    The propagation of fast ionization waves in discharge tubes is modeled with allowance for radial variations in the electric potential, nonlocal dependence of the plasma parameters on the electric field, and nonsteady nature of the electron energy distribution. The wave propagation dynamics and the wave attenuation in helium are described. The plasma parameters at the wave front and behind the front and the energy deposition in the discharge are found. The results obtained are compared with experimental data

  6. On the fast gas ionization wave in an intense laser beam

    International Nuclear Information System (INIS)

    Fisher, V.I.

    1980-01-01

    The transfer of the adsorption zone of laser radiation along a beam is considered. It is shown that for a sufficiently strong laser beam intensity, q 0 >q tilde, the conditions of wave propagation differ principally from those known previously. In particular, the plasma temperature behind the wave front Tsup(*) decreases with the increase of q 0 , whereas the wave velocity D(q 0 ) grows faster than a linear function. The structure and laws of propagation of the ionization wave are determined

  7. A tripolar-electrode ionization gas sensor using a carbon nanotube cathode for NO detection

    Science.gov (United States)

    Song, Hui; Li, Kun; Li, Quanfu

    2018-06-01

    Nitric oxide accounts for more than 95% of the total NO X emission from power plants, which is a major air pollutant. Therefore, it is imperative to accurately detect NO for environmental protection. A tripolar-electrode ionization sensor with a carbon nanotube (CNT) cathode is proposed for NO detection. The non-self-sustaining discharge state and the tripolar-electrode configuration ensures a long nanotube life, which ensures a good stability and fast response of the sensor. Experimental results demonstrate that the tripolar-electrode ionization sensor with 120 µm separations has an intrinsic monotonously decreasing response to NO and exhibits a fast response time of 7 s and recovery time of 8 s. More consumption of the two metastable states N2(A3  ∑  u +) and N2(aʹ1  ∑  u +) of N2 with the increasing of NO concentration is responsible for this. The tripolar-electrode ionization sensor also shows excellent long-term stability of at least one month due to the long CNT life. In addition, the weak effect of SO2 introduction on NO response indicates a good selectivity of the sensor to NO.

  8. A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

    Energy Technology Data Exchange (ETDEWEB)

    Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

    2008-12-05

    In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

  9. Reactions of metal ions and their clusters in the gas phase using laser ionization: ion cyclotron resonance spectroscopy

    International Nuclear Information System (INIS)

    Freiser, B.S.

    1981-04-01

    Two subjects are discussed in this report: advances in proposed studies on metal ion chemistry and expansion of laboratory facilities. The development of a combined pulsed laser source-ion cyclotron resonance spectrometer has proven to be a convenient and powerful method for generating metal ions and for studying their subsequent chemistry in the gas phase. The main emphasis of this research has been on the application of metal ions as a selective chemical ionization reagents and progress in this area are discussed. The goal is to identify trends in reactivity i.e. mechanisms useful in interpreting the chemical ionization spectra of unknown compounds and to test for the functional group selectivity of the various metal ions. The feasibility of these goals have been demonstrated in extensive studies on Cu + with esters and ketones, on Fe + with ethers, ketones, and hydrocarbons, and on Ti + with hydrocarbons. In addition, preliminary results on sulfur containing compounds and on a variety of other metallic ions have been obtained. Laboratory facilities were expanded from one ion cyclotron resonance (ICR) spectrometer to two, plus a third instrument the Fourier Transform Ion Cyclotron Resonance (FTICR) spectrometer

  10. Unified first principles description from warm dense matter to ideal ionized gas plasma: electron-ion collisions induced friction.

    Science.gov (United States)

    Dai, Jiayu; Hou, Yong; Yuan, Jianmin

    2010-06-18

    Electron-ion interactions are central to numerous phenomena in the warm dense matter (WDM) regime and at higher temperature. The electron-ion collisions induced friction at high temperature is introduced in the procedure of ab initio molecular dynamics using the Langevin equation based on density functional theory. In this framework, as a test for Fe and H up to 1000 eV, the equation of state and the transition of electronic structures of the materials with very wide density and temperature can be described, which covers a full range of WDM up to high energy density physics. A unified first principles description from condensed matter to ideal ionized gas plasma is constructed.

  11. The integrated radio continuum spectrum of M33 - Evidence for free-free absorption by cool ionized gas

    Science.gov (United States)

    Israel, F. P.; Mahoney, M. J.; Howarth, N.

    1992-01-01

    We present measurements of the integrated radio continuum flux density of M33 at frequencies between 22 and 610 MHz and discuss the radio continuum spectrum of M33 between 22 MHz and 10 GHz. This spectrum has a turnover between 500 and 900 MHz, depending on the steepness of the high frequency radio spectrum of M33. Below 500 MHz the spectrum is relatively flat. We discuss possible mechanisms to explain this spectral shape and consider efficient free-free absorption of nonthermal emission by a cool (not greater than 1000 K) ionized gas to be a very likely possibility. The surface filling factor of both the nonthermal and the thermal material appears to be small (of order 0.001), which could be explained by magnetic field/density fluctuations in the M 33 interstellar medium. We briefly speculate on the possible presence of a nuclear radio source with a steep spectrum.

  12. A method for measuring the electron drift velocity in working gas using a Frisch-grid ionization chamber

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Huaiyong; Wang, Zhimin; Zhang, Luyu; Chen, Jinxiang; Zhang, Guohui, E-mail: guohuizhang@pku.edu.cn

    2016-12-21

    A method for measuring the electron drift velocity in working gas is proposed. Based on the cathode and the anode signal waveforms of the Frisch-grid ionization chamber, the electron drift velocity is extracted. With this method, the electron drift velocities in Ar + 10% CH{sub 4}, Ar + 3.5% CO{sub 2} and Kr + 2.7% CO{sub 2} gases have been measured and the results are compared with the existing measurements and the simulating results. Using this method, the electron drift velocity can be monitored throughout the experiment of charged particle without bothering the measurement of other parameters, such as the energy and orientation.

  13. THE IONIZED GAS IN NEARBY GALAXIES AS TRACED BY THE [NII] 122 AND 205 μm TRANSITIONS

    Energy Technology Data Exchange (ETDEWEB)

    Herrera-Camus, R.; Bolatto, A.; Wolfire, M. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Smith, J. D. [Department of Physics and Astronomy, University of Toledo, 2801 West Bancroft Street, Toledo, OH 43606 (United States); Draine, B. [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Pellegrini, E. [Zentrum für Astronomie der Universität Heidelberg, Institut für Theoretische Astrophysik, Albert-Ueberle-Str. 2, D-69120 Heidelberg (Germany); Croxall, K. [Department of Astronomy, The Ohio State University, 4051 McPherson Laboratory, 140 West 18th Avenue, Columbus, OH 43210 (United States); Looze, I. de; Kennicutt, R. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA (United Kingdom); Calzetti, D. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Crocker, A. [Department of Physics, Reed College, Portland, OR 97202 (United States); Armus, L. [Spitzer Science Center, California Institute of Technology, MC 314-6, Pasadena, CA 91125 (United States); Van der Werf, P.; Brandl, B. [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands); Sandstrom, K. [Center for Astrophysics and Space Sciences, Department of Physics, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (United States); Galametz, M. [European Southern Observatory, Karl Schwarzschild Strasse 2, D-85748 Garching (Germany); Groves, B. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Rigopoulou, D. [Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Walter, F. [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); and others

    2016-08-01

    The [N ii] 122 and 205 μ m transitions are powerful tracers of the ionized gas in the interstellar medium. By combining data from 21 galaxies selected from the Herschel KINGFISH and Beyond the Peak surveys, we have compiled 141 spatially resolved regions with a typical size of ∼1 kpc, with observations of both [N ii] far-infrared lines. We measure [N ii] 122/205 line ratios in the ∼0.6–6 range, which corresponds to electron gas densities of n {sub e} ∼ 1–300 cm{sup −3}, with a median value of n {sub e} = 30 cm{sup −3}. Variations in the electron density within individual galaxies can be as high as a factor of ∼50, frequently with strong radial gradients. We find that n {sub e} increases as a function of infrared color, dust-weighted mean starlight intensity, and star-formation rate (SFR) surface density (Σ{sub SFR}). As the intensity of the [N ii] transitions is related to the ionizing photon flux, we investigate their reliability as tracers of the SFR. We derive relations between the [N ii] emission and SFR in the low-density limit and in the case of a log-normal distribution of densities. The scatter in the correlation between [N ii] surface brightness and Σ{sub SFR} can be understood as a property of the n {sub e} distribution. For regions with n {sub e} close to or higher than the [N ii] line critical densities, the low-density limit [N ii]-based SFR calibration systematically underestimates the SFR because the [N ii] emission is collisionally quenched. Finally, we investigate the relation between [N ii] emission, SFR, and n {sub e} by comparing our observations to predictions from the MAPPINGS-III code.

  14. THE IONIZED GAS IN NEARBY GALAXIES AS TRACED BY THE [NII] 122 AND 205 μm TRANSITIONS

    International Nuclear Information System (INIS)

    Herrera-Camus, R.; Bolatto, A.; Wolfire, M.; Smith, J. D.; Draine, B.; Pellegrini, E.; Croxall, K.; Looze, I. de; Kennicutt, R.; Calzetti, D.; Crocker, A.; Armus, L.; Van der Werf, P.; Brandl, B.; Sandstrom, K.; Galametz, M.; Groves, B.; Rigopoulou, D.; Walter, F.

    2016-01-01

    The [N ii] 122 and 205 μ m transitions are powerful tracers of the ionized gas in the interstellar medium. By combining data from 21 galaxies selected from the Herschel KINGFISH and Beyond the Peak surveys, we have compiled 141 spatially resolved regions with a typical size of ∼1 kpc, with observations of both [N ii] far-infrared lines. We measure [N ii] 122/205 line ratios in the ∼0.6–6 range, which corresponds to electron gas densities of n e ∼ 1–300 cm −3 , with a median value of n e = 30 cm −3 . Variations in the electron density within individual galaxies can be as high as a factor of ∼50, frequently with strong radial gradients. We find that n e increases as a function of infrared color, dust-weighted mean starlight intensity, and star-formation rate (SFR) surface density (Σ SFR ). As the intensity of the [N ii] transitions is related to the ionizing photon flux, we investigate their reliability as tracers of the SFR. We derive relations between the [N ii] emission and SFR in the low-density limit and in the case of a log-normal distribution of densities. The scatter in the correlation between [N ii] surface brightness and Σ SFR can be understood as a property of the n e distribution. For regions with n e close to or higher than the [N ii] line critical densities, the low-density limit [N ii]-based SFR calibration systematically underestimates the SFR because the [N ii] emission is collisionally quenched. Finally, we investigate the relation between [N ii] emission, SFR, and n e by comparing our observations to predictions from the MAPPINGS-III code.

  15. Improving quantitative gas chromatography-electron ionization mass spectrometry results using a modified ion source: demonstration for a pharmaceutical application.

    Science.gov (United States)

    D'Autry, Ward; Wolfs, Kris; Hoogmartens, Jos; Adams, Erwin; Van Schepdael, Ann

    2011-07-01

    Gas chromatography-mass spectrometry is a well established analytical technique. However, mass spectrometers with electron ionization sources may suffer from signal drifts, hereby negatively influencing quantitative performance. To demonstrate this phenomenon for a real application, a static headspace-gas chromatography method in combination with electron ionization-quadrupole mass spectrometry was optimized for the determination of residual dichloromethane in coronary stent coatings. Validating the method, the quantitative performance of an original stainless steel ion source was compared to that of a modified ion source. Ion source modification included the application of a gold coating on the repeller and exit plate. Several validation aspects such as limit of detection, limit of quantification, linearity and precision were evaluated using both ion sources. It was found that, as expected, the stainless steel ion source suffered from signal drift. As a consequence, non-linearity and high RSD values for repeated analyses were obtained. An additional experiment was performed to check whether an internal standard compound would lead to better results. It was found that the signal drift patterns of the analyte and internal standard were different, consequently leading to high RSD values for the response factor. With the modified ion source however, a more stable signal was observed resulting in acceptable linearity and precision. Moreover, it was also found that sensitivity improved compared to the stainless steel ion source. Finally, the optimized method with the modified ion source was applied to determine residual dichloromethane in the coating of coronary stents. The solvent was detected but found to be below the limit of quantification. Copyright © 2011 Elsevier B.V. All rights reserved.

  16. Subcutaneous granuloma annulare: radiologic appearance

    International Nuclear Information System (INIS)

    Kransdorf, M.J.; Murphey, M.D.; Temple, H.T.

    1998-01-01

    Objective. Granuloma annulare is an uncommon benign inflammatory dermatosis characterized by the formation of dermal papules with a tendency to form rings. There are several clinically distinct forms. The subcutaneous form is the most frequently encountered by radiologists, with the lesion presenting as a superficial mass. There are only a few scattered reports of the imaging appearance of this entity in the literature. We report the radiologic appearance of five cases of subcutaneous granuloma annulare. Design and patients. The radiologic images of five patients (three male, two female) with subcutaneous granuloma annulare were retrospectively studied. Mean patient age was 6.4 years (range, 2-13 years). The lesions occurred in the lower leg (two), foot, forearm, and hand. MR images were available for all lesions, gadolinium-enhanced imaging in three cases, radiographs in four, and bone scintigraphy in one. Results. Radiographs showed unmineralized nodular masses localized to the subcutaneous adipose tissue. The size range, in greatest dimension on imaging studies, was 1-4 cm. MR images show a mass with relatively decreased signal intensity on all pulse sequences, with variable but generally relatively well defined margins. There was extensive diffuse enhancement following gadolinium administration. Conclusion. The radiologic appearance of subcutaneous granuloma annulare is characteristic, typically demonstrating a nodular soft-tissue mass involving the subcutaneous adipose tissue. MR images show a mass with relatively decreased signal intensity on all pulse sequences and variable but generally well defined margins. There is extensive diffuse enhancement following gadolinium administration. Radiographs show a soft-tissue mass or soft-tissue swelling without evidence of bone involvement or mineralization. This radiologic appearance in a young individual is highly suggestive of subcutaneous granuloma annulare. (orig.)

  17. The VLT/MUSE view of the central galaxy in Abell 2052. Ionized gas swept by the expanding radio source

    Science.gov (United States)

    Balmaverde, Barbara; Capetti, Alessandro; Marconi, Alessandro; Venturi, Giacomo

    2018-04-01

    We report observations of the radio galaxy 3C 317 (at z = 0.0345) located at the center of the Abell cluster A2052, obtained with the VLT/MUSE integral field spectrograph. The Chandra images of this cluster show cavities in the X-ray emitting gas, which were produced by the expansion of the radio lobes inflated by the active galactic nucleus (AGN). Our exquisite MUSE data show with unprecedented detail the complex network of line emitting filaments enshrouding the northern X-ray cavity. We do not detect any emission lines from the southern cavity, with a luminosity asymmetry between the two regions higher than 75. The emission lines produced by the warm phase of the interstellar medium (WIM) enable us to obtain unique information on the properties of the emitting gas. We find dense gas (up to 270 cm-3) that makes up part of a global quasi spherical outflow that is driven by the radio source, and obtain a direct estimate of the expansion velocity of the cavities (265 km s-1). The emission lines diagnostic rules out ionization from the AGN or from star-forming regions, suggesting instead ionization from slow shocks or from cosmic rays. The striking asymmetric line emission observed between the two cavities contrasts with the less pronounced differences between the north and south sides in the hot gas; this represents a significant new ingredient for our understanding of the process of the exchange of energy between the relativistic plasma and the external medium. We conclude that the expanding radio lobes displace the hot tenuous phase of the interstellar medium (ISM), but also impact the colder and denser ISM phases. These results show the effects of the AGN on its host and the importance of radio mode feedback. The reduced datacube is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/612/A19

  18. Study on the emission characteristics of cathodes in an ionized gas flow

    International Nuclear Information System (INIS)

    Maslennikov, N.M.

    1975-01-01

    Emission characteristics of molybdenum, tungsten and tantalum cathodes in a flow of argon and argon-potassium plasma with gas pressure of 0.04 atm, 1 atm and 0.25 atm were investigated. Gas was heated in a plasmatron. Measuring electrodes were arranged across the gas flow. Investigations in an argon plasma were carried out with the object of comparing of current-voltage dependences for potassium-activated and nonactivated cathodes. In all cases the current-voltage characteristics were growing. No saturation was observed of a current between accurent electrodes. The increase of a current between the cathodes due to the thermionic emission from the cathode began to effect at the cathode temperature of 2.470 K. The work function was found to be 5 to 5.2 ev. The comparison of the results obtained experimentally in the paper show a qualitative coincidence with calculations by some authors and a discrepancy with theoretical conceptions of other authors

  19. Gemini Near Infrared Field Spectrograph Observations of the Seyfert 2 Galaxy MRK 573: In Situ Acceleration of Ionized and Molecular Gas Off Fueling Flows

    Science.gov (United States)

    Fischer, Travis C.; Machuca, C.; Diniz, M. R.; Crenshaw, D. M.; Kraemer, S. B.; Riffel, R. A.; Schmitt, H. R.; Baron, F.; Storchi-Bergmann, T.; Straughn, A. N.; hide

    2016-01-01

    We present near-infrared and optical emission-line and stellar kinematics of the Seyfert 2 galaxy Mrk 573 using the Near-Infrared Field Spectrograph (NIFS) at Gemini North and Dual Imaging Spectrograph at Apache Point Observatory, respectively. By obtaining full kinematic maps of the infrared ionized and molecular gas and stellar kinematics in approximately 700 x 2100 pc(exp 2) circumnuclear region of Mrk 573, we find that kinematics within the Narrow-Line Region are largely due to a combination of both rotation and in situ acceleration of material originating in the host disk. Combining these observations with large-scale, optical long-slit spectroscopy that traces ionized gas emission out to several kpcs, we find that rotation kinematics dominate the majority of the gas. We find that outflowing gas extends to distances less than 1 kpc, suggesting that outflows in Seyfert galaxies may not be powerful enough to evacuate their entire bulges.

  20. Propagation study of the ionization fronts in a gas subject to an impulse field

    International Nuclear Information System (INIS)

    Gayraud, Francois.

    1978-01-01

    We study the formation of a discharge in nitrogen and in nitrogen-methane mixtures (2,5% to 50% of methane) for pressures of several hundred torr and for electric-field-to-pressure ratio values between 110 and 150 V.cm -1 .torr -1 . The development of the discharge is observed by means of streak camera with a temporal resolution of 400 ps. The analysis of the recording allows to characterise several phases in the ionization fronts development. We give the variation of the speed of the fronts in function of the proportion of methane and of the ratio E/p. We explicit a streamer propagation model, based on the hypothesis that the plasma channel behind the front is assimilable to a perfect conductor. Thus, we obtain analytic expressions of the length and the speed of the streamer. The values obtained from these relations are in excellent agreement with the values measured [fr

  1. Annular beam shaping and optical trepanning

    Science.gov (United States)

    Zeng, Danyong

    Percussion drilling and trepanning are two laser drilling methods. Percussion drilling is accomplished by focusing the laser beam to approximately the required diameter of the hole, exposing the material to one or a series of laser pulses at the same spot to melt and vaporize the material. Drilling by trepanning involves cutting a hole by rotating a laser beam with an optical element or an x-y galvo-scanner. Optical trepanning is a new laser drilling method using an annular beam. The annular beams allow numerous irradiance profiles to supply laser energy to the workpiece and thus provide more flexibility in affecting the hole quality than a traditional circular laser beam. Heating depth is important for drilling application. Since there are no good ways to measure the temperature inside substrate during the drilling process, an analytical model for optical trepanning has been developed by considering an axisymmetric, transient heat conduction equation, and the evolutions of the melting temperature isotherm, which is referred to as the melt boundary in this study, are calculated to investigate the influences of the laser pulse shapes and intensity profiles on the hole geometry. This mathematical model provides a means of understanding the thermal effect of laser irradiation with different annular beam shapes. To take account of conduction in the solid, vaporization and convection due to the melt flow caused by an assist gas, an analytical two-dimensional model is developed for optical trepanning. The influences of pulse duration, laser pulse length, pulse repetition rate, intensity profiles and beam radius are investigated to examine their effects on the recast layer thickness, hole depth and taper. The ray tracing technique of geometrical optics is employed to design the necessary optics to transform a Gaussian laser beam into an annular beam of different intensity profiles. Such profiles include half Gaussian with maximum intensities at the inner and outer

  2. Performance of a high repetition pulse rate laser system for in-gas-jet laser ionization studies with the Leuven laser ion source LISOL

    International Nuclear Information System (INIS)

    Ferrer, R.; Sonnenschein, V.T.; Bastin, B.; Franchoo, S.; Huyse, M.; Kudryavtsev, Yu.; Kron, T.; Lecesne, N.; Moore, I.D.; Osmond, B.; Pauwels, D.; Radulov, D.; Raeder, S.; Rens, L.

    2012-01-01

    The laser ionization efficiency of the Leuven gas cell-based laser ion source was investigated under on- and off-line conditions using two distinctly different laser setups: a low-repetition rate dye laser system and a high-repetition rate Ti:sapphire laser system. A systematic study of the ion signal dependence on repetition rate and laser pulse energy was performed in off-line tests using stable cobalt and copper isotopes. These studies also included in-gas-jet laser spectroscopy measurements on the hyperfine structure of 63 Cu. A final run under on-line conditions in which the radioactive isotope 59 Cu (T 1/2 = 81.5 s) was produced, showed a comparable yield of the two laser systems for in-gas-cell ionization. However, a significantly improved time overlap by using the high-repetition rate laser system for in-gas-jet ionization was demonstrated by an increase of the overall duty cycle, and at the same time, pointed to the need for a better shaped atomic jet to reach higher ionization efficiencies.

  3. Average energy expended per ion pair, exciton enhanced ionization (Jesse effect), electron drift velocity, average electron energy and scintillation in rare gas liquids

    International Nuclear Information System (INIS)

    Doke, T.; Hitachi, A.; Hoshi, Y.; Masuda, K.; Hamada, T.

    1977-01-01

    Precise measurements of W-values, the average energy expended per electron-hole pair in liquid Ar and Xe, were made by the electron-pulse method, and that in liquid Kr by the steady conduction current method. The results showed that the W-values were clearly smaller than those in gaseous Ar, Xe and Kr as predicted by Doke. The results can be explained by the conduction bands which exist in these rare gas liquids as well as in the solid state. The enhanced ionization yield was observed for Xe-doped liquid Ar, and it was attributed to the ionizing excitation transfer process from Ar excitons to doped Xe. This is very similar to the Jesse effect in the gas phase. The saturated value of the enhanced ionization was in good agreement with the theoretical value, and it provides strong evidence for the existence of the exciton states in liquid Ar. Fano factors in liquid Ar, Kr, Xe and Xe-doped liquid Ar have been estimated from the Fano Formula, and they were smaller than those in the gas phase. The drift velocity of electrons in liquid Ar, liquid Ar-gas mixtures and liquid Xe have been measured with gridded ionization chambers. The average electron energy in liquid Ar has been measured. The electron-induced scintillations of liquid Xe and Ar have been studied. (Kato, T.)

  4. Hydrodynamics of annular-dispersed flow

    International Nuclear Information System (INIS)

    Ishii, M.; Kataoka, I.

    1982-01-01

    The interfacial drag, droplet entrainment, and droplet size distributions are important for detailed mechanistic modeling of annular dispersed two-phase flow. In view of this, recently developed correlations for these parameters are presented and discussed in this paper. The drag correlations for multiple fluid particle systems have been developed from a similarity hypothesis based on the mixture viscosity model. The results show that the drag coefficient depends on the particle Reynolds number and droplet concentration. The onset on droplet entrainment significantly alters the mechanisms of mass, momentum, and energy transfer between the film and gas core flow as well as the transfer between the two-phase mixture and the wall. By assuming the roll wave entrainment mechanism, the correlations for the amount of entrained droplet as well as for the droplet size distribution have been obtained from a simple model in collaboration with a large number of data

  5. Determination of electron impact ionization and excitation coefficients in He-Xe gas mixtures. He-Xe kongo gas ni okeru denshi shototsu denri keisu oyobi reiki keisu no sokutei to kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, K.; Tachibana, K. (Kyoto Inst. of Technology, Kyoto (Japan))

    1991-03-20

    The rare gas discharge gives a stable discharge and light emission characteristics at low temperature in comparison with the discharge of the vapor of such a metal as Hg. The present barrier for the commercialization of the color PDP lies in the lower level of its emission intensity and efficiency in comparison with that of CRT. In this report, an electron impact ionization coefficient in a gas mixture and an electron impact excitation coefficient for a XeIs {sub 4} level were analyzed using a Boltzmann equation by means of a steady state Townsend method using a drift tube. By comparing both, the elementary process in the gas mixture is investiagted to discuss the respective contributions for the effective ionization coefficient and the excitation coefficient. As a result, it was found that the ionization process in the He-Xe gas mixture could be described by the processes of direct ionization of Xe and He, and an indirect ionization (Penning effect) by an active helium. 37 refs., 12 figs.

  6. Development of a He/CdI$_2$ gas-jet system coupled to a surface-ionization type ion-source in JAEA-ISOL: towards determination of the first ionization potential of Lr (Z = 103)

    CERN Document Server

    Sato, T K; Sato, N; Tsukada, K; Toyoshima, A; Ooe, K; Miyashita, S; Kaneya, Y; Osa, A; Schädel, M; Nagame, Y; Ichikawa, S; Stora, T; Kratz, J V

    2015-01-01

    We report on development of a gas-jet transport system coupled to a surface ionization ion-source in the JAEA-ISOL (Isotope Separator On-Line) system. As a new aerosol material for the gas-jet system, CdI2, which has a low boiling point of 713 °C, is exploited to prevent deposition of the aerosol material on the surface of the ion-source. An additional filament is newly installed in the previous ion-source to provide uniform heating of an ionizer. The present system is applied to the measurement of absolute efficiencies of various short-lived lanthanide isotopes produced in nuclear reactions.

  7. The Physics of Partially Ionized Gas with Applications to Processes in the Interstellar Medium

    International Nuclear Information System (INIS)

    Greenfield, E. J.; Jokipii, J. R.; Giacalone, Joe

    2011-01-01

    The dynamical equations for a partially ionized plasma are a matter of some recent controversy. Understanding this problem is important in understanding the interaction of the interstellar medium with the heliosphere and for understanding the spectrum of interstellar turbulence. If collision scales are much smaller than the internal interaction scales such as the ion gyroradius, the fluid approximation may be used. The analysis then must deal with at least three fluids (protons, electrons, and neutrals) which are coupled to each other by collisions and/or electromagnetic fields. Often, the proton and electron gyro-radii are much smaller than the collision length scales, so the electric and magnetic fields dominate the motions of the electrons and protons. In this case, the only important particle-particle collisions are those of the electrons and protons with the neutral atoms. Since the three species have, in general, different velocities, it is not immediately clear which fluid velocity to use. This ambiguity in the choice of fluid velocity has led to recent confusion regarding the physics of partially ionized plasmas. If the neutrals have a significant fraction of the mass, working in the center-of-mass coordinate frame can result in dynamical equations that differ greatly from those of ideal MHD. This is because the magnetic field is not frozen into the frame moving at the center-of-mass velocity, which leads to additional effects on the magnetic field that can be difficult to understand intuitively. To the extent that the electron mass is negligible, the magnetic field is actually found to be frozen into the frame moving with the electron bulk velocity. If we then take U to be the bulk velocity of the proton fluid the resulting dynamical equations closely resemble those of ideal MHD with the exception of the Hall term in the induction equation. Similarly, the frequently used Cowling conductivity also depends on the choice of coordinate frame. These conclusions

  8. Coupling of gas chromatography and electrospray ionization high resolution mass spectrometry for the analysis of anabolic steroids as trimethylsilyl derivatives in human urine.

    Science.gov (United States)

    Cha, Eunju; Jeong, Eun Sook; Cha, Sangwon; Lee, Jaeick

    2017-04-29

    In this study, gas chromatography (GC) was interfaced with high resolution mass spectrometry (HRMS) with electrospray ionization source (ESI) and the relevant parameters were investigated to enhance the ionization efficiency. In GC-ESI, the distances (x-, y- and z) and angle between the ESI needle, GC capillary column and MS orifice were set to 7 (x-distance), 4 (y-distance), and 1 mm (z-distance). The ESI spray solvent, acid modifier and nebulizer gas flow were methanol, 0.1% formic acid and 5 arbitrary units, respectively. Based on these results, analytical conditions for GC-ESI/HRMS were established. In particular, the results of spray solvent flow indicated a concentration-dependent mechanism (peak dilution effect), and other parameters also greatly influenced the ionization performance. The developed GC-ESI/HRMS was then applied to the analysis of anabolic steroids as trimethylsilyl (TMS) derivatives in human urine to demonstrate its application. The ionization profiles of TMS-derivatized steroids were investigated and compared with those of underivatized steroids obtained from gas chromatography-electrospray ionization/mass spectrometry (GC-ESI/MS) and liquid chromatography-electrospray ionization/mass spectrometry (LC-ESI/MS). The steroids exhibited ionization profiles based on their structural characteristics, regardless of the analyte phase or derivatization. Groups I and II with conjugated or unconjugated keto functional groups at C3 generated the [M+H] + and [M+H-TMS] + ions, respectively. On the other hand, Groups III and IV gave rise to the characteristic fragment ions [M+H-TMS-H 2 O] + and [M+H-2TMS-H 2 O] + , corresponding to loss of a neutral TMS·H 2 O moiety from the protonated molecular ion by in-source dissociation. To the best of our knowledge, this is the first study to successfully ionize and analyze steroids as TMS derivatives using ESI coupled with GC. The present system has enabled the ionization of TMS derivatives under ESI conditions

  9. [Gas chromatography with a Pulsed discharge helium ionization detector for measurement of molecular hydrogen(H2) in the atmosphere].

    Science.gov (United States)

    Luan, Tian; Fang, Shuang-xi; Zhou, Ling-xi; Wang, Hong-yang; Zhang, Gen

    2015-01-01

    A high precision GC system with a pulsed discharge helium ionization detector was set up based on the commercial Agilent 7890A gas chromatography. The gas is identified by retention time and the concentration is calculated through the peak height. Detection limit of the system is about 1 x 10(-9) (mole fraction, the same as below). The standard deviation of 140 continuous injections with a standard cylinder( concentration is roughly 600 x 10(-9)) is better than 0.3 x 10(-9). Between 409.30 x 10(-9) and 867.74 x 10(-9) molecular hydrogen mole fractions and peak height have good linear response. By using two standards to quantify the air sample, the precision meets the background molecular hydrogen compatibility goal within the World Meteorological Organization/Global Atmosphere Watch (WMO/GAW) program. Atmospheric molecular hydrogen concentration at Guangzhou urban area was preliminarily measured by this method from January to November 2013. The results show that the atmospheric molecular hydrogen mole fraction varies from 450 x 10(-9) to 700 x 10(-9) during the observation period, with the lowest value at 14:00 (Beijing time, the same as below) and the peak value at 20:00. The seasonal variation of atmospheric hydrogen at Guangzhou area was similar with that of the same latitude stations in northern hemisphere.

  10. Study of the molecular and ionized gas in a possible precursor of an ultra-compact H II region

    Science.gov (United States)

    Ortega, M. E.; Paron, S.; Giacani, E.; Celis Peña, M.; Rubio, M.; Petriella, A.

    2017-10-01

    Aims: We aim to study the molecular and the ionized gas in a possible precursor of an ultra-compact H II region to contribute to the understanding of how high-mass stars build-up their masses once they have reached the zero-age main sequence. Methods: We carried out molecular observations toward the position of the Red MSX source G052.9221-00.4892, using the Atacama Submillimeter Telescope Experiment (ASTE; Chile) in the 12CO J = 3-2, 13CO J = 3-2, C18O J = 3-2, and HCO+J = 4-3 lines with an angular resolution of about 22''. We also present radio continuum observations at 6 GHz carried out with the Jansky Very Large Array (JVLA; USA) interferometer with a synthesized beam of 4.8 arcsec × 4.1 arcsec. The molecular data were used to study the distribution and kinematics of the molecular gas, while the radio continuum data were used to characterize the ionized gas in the region. Combining these observations with public infrared data allowed us to inquire about the nature of the source. Results: The analysis of the molecular observations reveals the presence of a kinetic temperature and H2 column density gradients across the molecular clump in which the Red MSX source G052.9221-00.4892 is embedded, with the hotter and less dense gas in the inner region. The 12CO J = 3-2 emission shows evidence of misaligned massive molecular outflows, with the blue lobe in positional coincidence with a jet-like feature seen at 8 μm. The radio continuum emission shows a slightly elongated compact radio source, with a flux density of about 0.9 mJy, in positional coincidence with the Red MSX source. The polar-like morphology of this compact radio source perfectly matches the hourglass-like morphology exhibited by the source in the Ks band. Moreover, the axes of symmetry of the radio source and the near-infrared nebula are perfectly aligned. Thus, based on the presence of molecular outflows, the slightly elongated morphology of the compact radio source matching the hourglass

  11. DENSITY OF WARM IONIZED GAS NEAR THE GALACTIC CENTER: LOW RADIO FREQUENCY OBSERVATIONS

    International Nuclear Information System (INIS)

    Roy, Subhashis

    2013-01-01

    We have observed the Galactic center (GC) region at 0.154 and 0.255 GHz with the Giant Metrewave Radio Telescope. A total of 62 compact likely extragalactic (EG) sources are detected. Their scattering sizes decrease linearly with increasing angular distance from the GC up to about 1°. The apparent scattering sizes of the sources are more than an order of magnitude less than predicted earlier by the NE2001 model of Galactic electron distribution within 359.°5 e is ∼10 cm –3 , which matches the NE2001 model. This model predicts the EG sources to be resolved out from 1.4 GHz interferometric surveys. However, out of 10 EG sources expected in the region, 8 likely EG are present in the 1.4 GHz catalog. Ionized interfaces of dense molecular clouds to the ambient medium are most likely responsible for strong scattering and low radio frequency absorption. However, dense GC clouds traced by CS J = 1-0 emission are found to have a narrow distribution of ∼0.°2 across the Galactic plane. Angular distribution of most EG sources seen through the so-called Hyperstrong Scattering Region are random in b, and typically ∼7 out of 10 sources will not be seen through the dense molecular clouds, which explains why most of them are not scatter broadened at 1.4 GHz

  12. Numerical study on the two-dimensional flows of plasma and ionizing gas using trial particles

    International Nuclear Information System (INIS)

    Brushlinskij, K.V.; Kozlov, A.N.; Morozov, A.I.

    1985-01-01

    Two-dimensional flows of plasma and ionized αs in a channel between two coaxial electrodes are considered in the MHD-model with account of Hall effect. Stationary solutions of the problem on the flow are obtained either analytically in approximation of a ''smooth'' channel - for ideal conducting plasma, or numerically using the methos of establishment - in the ge-neral case of finite conductivity. A method of further numerical analysis of some peculiarities of flow is suggested in the paper. It is based on studying dynamics of single ''test'' particles in fields of the main MHD plasma flow. Trajectory of the test ion is calculated with account for interaction forces with earlier determined electromagentic field and friction responsible for Coulomb collisions with particles of the background flow. The calculations display trajectories of test particles with different masses, initial positions and initial rates. They are shown to be dose to current lines of background medium in plasma of finite conductivity, that testified to the virtue of effectiveness of the MHD-model. In case of ideal conductivity trajectories of test and background particles can noticeably differ from one another. Stabilization effects of motion of particles accidentally knocked out from the flow and separation of pariticles of different mass by electromao.netic forces are considered

  13. The analysis of the annular fuel performance in steady state condition by using AFPAC code

    International Nuclear Information System (INIS)

    He Xiaojun; Ji Songtao; Zhang Yingchao

    2012-01-01

    The fuel performance code AFPAC v1.0 is used to analyze annular fuel's behavior under steady state conditions, including neutronics, thermal hydraulic, rod deformation, fission gas release and rod internal pressure. The calculation results show that: 1) Annular fuel has a good steady irradiation performance at 150% power level as current LWRs' with burnup up to 50 GWd/t, and all parameters, such as temperature, rod internal pressure and rod deformation, are meet the rod design criteria for current fuel of PWRs: 2) Compared to the solid fuel under the same irradiation condition. annular fuel has lower temperature, smaller deformation, lower fission gas release and lower pressure at EOL. From the point of view of steady irradiation performance, the safety of reactors can significantly improved by u sing the annular fuel. (authors)

  14. Hydrodynamics of adiabatic inverted annular flow: an experimental study

    International Nuclear Information System (INIS)

    De Jarlais, G.; Ishii, M.

    1983-01-01

    For low-quality film boiling in tubes or rod bundles, the flow pattern may consist of a liquid jet-like core surrounded by a vapor annulus, i.e., inverted annular flow. The stability, shape, and break-up mechanisms of this liquid core must be understood in order to model correctly this regime and to develop appropriate interfacial transfer correlations. This paper reports on a study in which inverted annular flow was simulated in an adiabatic system. Turbulent water jets, issuing downward from long-aspect nozzles were enclosed within cocurrent gas annuli. Jet-core diameter and velocity, and gas-annulus diameter, velocity, and species were varied, yielding liquid Reynolds numbers up to 33,000, void fractions from 0.29 to 0.95, and relative velocities from near zero to over 80 m/s. Jet-core break-up lengths and secondarily, core break-up mechanisms, were observed visually, using strobe lighting

  15. Hydrodynamic stability of inverted annular flow in an adiabatic simulation

    International Nuclear Information System (INIS)

    De Jarlais, G.; Ishii, M.; Linehan, J.

    1986-01-01

    Inverted annular flow was simulated adiabatically with turbulent water jets, issuing downward from large aspect ratio nozzles, enclosed in gas annuli. Velocities, diameters, and gas species were varied, and core jet length, shape, breakup mode, and dispersed core droplet sizes were recorded at approximately 750 data points. Inverted annular flow destabilization led to inverted slug flow at low relative velocities, and to dispersed droplet flow, core breakup length correlations were developed by extending work on free liquid jets to include this coaxial, jet disintegration phenomenon. The results show length dependence upon D/sub J/, Re/sub J/, We/sub J/, α, and We/sub G/,rel. Correlations for core shape, breakup mechanisms, and dispersed core droplet size were also developed, by extending the results of free jet stability, roll wave entrainment, and churn turbulent droplet stability studies

  16. Influence of Ionization Source Conditions on the Gas-Phase Protomer Distribution of Anilinium and Related Cations.

    Science.gov (United States)

    Attygalle, Athula B; Xia, Hanxue; Pavlov, Julius

    2017-08-01

    The gas-phase-ion generation technique and specific ion-source settings of a mass spectrometer influence heavily the protonation processes of molecules and the abundance ratio of the generated protomers. Hitherto that has been attributed primarily to the nature of the solvent and the pH. By utilizing electrospray ionization and ion-mobility mass spectrometry (IM-MS), we demonstrate, even in the seemingly trivial case of protonated aniline, that the protomer ratio strongly depends on the source conditions. Under low in-source ion activation, nearly 100% of the N-protomer of aniline is produced, and it can be subsequently converted to the C-protomer by collisional activation effected by increasing the electrical potential difference between the entrance and exit orifices of the first vacuum region. This activation and transformation process takes place even before the ion is mass-selected and subjected to IM separation. Despite the apparent simplicity of the problem, the preferred protonation site of aniline in the gas phase-the amino group or the aromatic ring-has been a topic of controversy. Our results not only provide unambiguous evidence that ring- and nitrogen-protonated aniline can coexist and be interconverted in the gas phase, but also that the ratio of the protomers depends on the internal energy of the original ion. There are many dynamic ion-transformation and fragmentation processes that take place in the different physical compartments of a Synapt G2 HDMS instrument. Such processes can dramatically change the very identity even of small ions, and therefore should be taken into account when interpreting product-ion mass spectra. Graphical Abstract ᅟ.

  17. Simultaneous determination of methanol, acetaldehyde, acetone, and ethanol in human blood by gas chromatography with flame ionization detection.

    Science.gov (United States)

    Schlatter, J; Chiadmi, F; Gandon, V; Chariot, P

    2014-01-01

    Methanol, acetaldehyde, acetone, and ethanol, which are commonly used as biomarkers of several diseases, in acute intoxications, and forensic settings, can be detected and quantified in biological fluids. Gas chromatography (GC)-mass spectrometry techniques are complex, require highly trained personnel and expensive materials. Gas chromatographic determinations of ethanol, methanol, and acetone have been reported in one study with suboptimal accuracy. Our objective was to improve the assessment of these compounds in human blood using GC with flame ionization detection. An amount of 50 µl of blood was diluted with 300 µl of sterile water, 40 µl of 10% sodium tungstate, and 20 µl of 1% sulphuric acid. After centrifugation, 1 µl of the supernatant was injected into the gas chromatograph. We used a dimethylpolysiloxane capillary column of 30 m × 0.25 mm × 0.25 µm. We observed linear correlations from 7.5 to 240 mg/l for methanol, acetaldehyde, and acetone and from 75 to 2400 mg/l for ethanol. Precision at concentrations 15, 60, and 120 mg/l for methanol, acetaldehyde, and acetone and 150, 600, and 1200 mg/ml for ethanol were 0.8-6.9%. Ranges of accuracy were 94.7-98.9% for methanol, 91.2-97.4% for acetaldehyde, 96.1-98.7% for acetone, and 105.5-111.6% for ethanol. Limits of detection were 0.80 mg/l for methanol, 0.61 mg/l for acetaldehyde, 0.58 mg/l for acetone, and 0.53 mg/l for ethanol. This method is suitable for routine clinical and forensic practices.

  18. Annular pulse column development studies

    International Nuclear Information System (INIS)

    Benedict, G.E.

    1980-01-01

    The capacity of critically safe cylindrical pulse columns limits the size of nuclear fuel solvent extraction plants because of the limited cross-sectional area of plutonium, U-235, or U-233 processing columns. Thus, there is a need to increase the cross-sectional area of these columns. This can be accomplished through the use of a column having an annular cross section. The preliminary testing of a pilot-plant-scale annular column has been completed and is reported herein. The column is made from 152.4-mm (6-in.) glass pipe sections with an 89-mm (3.5-in.) o.d. internal tube, giving an annular width of 32-mm (1.25-in.). Louver plates are used to swirl the column contents to prevent channeling of the phases. The data from this testing indicate that this approach can successfully provide larger-cross-section critically safe pulse columns. While the capacity is only 70% of that of a cylindrical column of similar cross section, the efficiency is almost identical to that of a cylindrical column. No evidence was seen of any non-uniform pulsing action from one side of the column to the other

  19. Gas-phase complexes formed between amidoxime ligands and vanadium or iron investigated using electrospray ionization mass spectrometry.

    Science.gov (United States)

    Mustapha, Adetayo M; Pasilis, Sofie P

    2016-08-15

    Amidoxime-functionalized sorbents can be used to extract uranium from seawater. Iron(III) and vanadium(V) may compete with uranium for adsorption sites. We use 2,6-dihydroxyiminopiperidine (DHIP) and N(1) ,N(5) -dihydroxypentanediimidamide (DHPD) to model amidoxime functional groups and characterize the vanadium(V) and iron(III) complexes with these ligands. We also examine the effect of iron(III) and vanadium(V) on uranyl(VI) complexation by DHIP and DHPD. The experiments were carried out in positive ion mode using a quadrupole ion trap mass spectrometer equipped with an electrospray ionization source. The effect on the mass spectra of changes in ligand, metal:ligand mole ratio, and pH was examined. Iron(III) formed a 1:2 metal:ligand complex with DHIP at all metal:ligand mole ratios and pH values investigated; it formed both 1:2 and 1:3 metal:ligand complexes with DHPD. Vanadium(V) formed 1:1 and 1:2 metal:ligand complexes with DHIP. A 1:2 metal:ligand complex was formed with DHPD at all vanadium(V):DHPD mole ratios investigated. Changes in solution pH did not affect the ions observed. The relative binding affinities of the metal ions towards DHIP followed the order iron(III) > vanadium(V) > uranyl(VI). This study presents a first look at the gas-phase vanadium(V)- and iron(III)-DHIP and -DHPD complexes using electrospray ionization mass spectrometry. These metals form stronger complexes with amidoxime ligands than uranyl(VI), and will affect uranyl(VI) adsorption to amidoxime-based sorbents. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  20. KINEMATICS AND EXCITATION OF THE RAM PRESSURE STRIPPED IONIZED GAS FILAMENTS IN THE COMA CLUSTER OF GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, Michitoshi [Hiroshima Astrophysical Science Center, Hiroshima University, Higashi-Hiroshima, Hiroshima 739-8526 (Japan); Yagi, Masafumi; Komiyama, Yutaka; Kashikawa, Nobunari [Optical and Infrared Astronomy Division, National Astronomical Observatory, Mitaka, Tokyo 181-8588 (Japan); Furusawa, Hisanori [Astronomical Data Center, National Astronomical Observatory of Japan, Mitaka, Tokyo 181-8588 (Japan); Hattori, Takashi [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A' Ohoku Place, Hilo, HI 96720 (United States); Okamura, Sadanori, E-mail: yoshidam@hiroshima-u.ac.jp [Department of Astronomy, University of Tokyo, Tokyo 113-0033 (Japan)

    2012-04-10

    We present the results of deep imaging and spectroscopic observations of very extended ionized gas (EIG) around four member galaxies of the Coma Cluster of galaxies: RB 199, IC 4040, GMP 2923, and GMP 3071. The EIGs were serendipitously found in an H{alpha} narrowband imaging survey of the central region of the Coma Cluster. The relative radial velocities of the EIGs with respect to the systemic velocities of the parent galaxies from which they emanate increase almost monotonically with the distance from the nucleus of the respective galaxies, reaching {approx} - 400 to - 800 km s{sup -1} at around 40-80 kpc from the galaxies. The one-sided morphologies and the velocity fields of the EIGs are consistent with the predictions of numerical simulations of ram pressure stripping. We found a very low velocity filament (v{sub rel} {approx} -1300 km s{sup -1}) at the southeastern edge of the disk of IC 4040. Some bright compact knots in the EIGs of RB 199 and IC 4040 exhibit blue continuum and strong H{alpha} emission. The equivalent widths of the H{alpha} emission exceed 200 A and are greater than 1000 Angstrom-Sign for some knots. The emission-line intensity ratios of the knots are basically consistent with those of sub-solar abundance H II regions. These facts indicate that intensive star formation occurs in the knots. Some filaments, including the low-velocity filament of the IC 4040 EIG, exhibit shock-like emission-line spectra, suggesting that shock heating plays an important role in ionization and excitation of the EIGs.

  1. Infrared imaging spectroscopy of the Galactic center - Distribution and motions of the ionized gas

    Science.gov (United States)

    Herbst, T. M.; Beckwith, S. V. W.; Forrest, W. J.; Pipher, J. L.

    1993-01-01

    High spatial spectral resolution IR images of the Galactic center in the Br-gamma recombination line of hydrogen were taken. A coherent filament of gas extending from north of IRS 1, curving around IRS 16/Sgr A complex, and continuing to the southwest, is seen. Nine stellar sources have associated Br-gamma emission. The total Br-gamma line flux in the filament is approximately 3 x 10 exp -15 W/sq m. The distribution and kinematics of the northern arm suggest orbital motion; the observations are accordingly fit with elliptical orbits in the field of a central point of mass.

  2. Multi-slice CT features of annular pancreas in neonates

    International Nuclear Information System (INIS)

    He Mingqing; Zhu Youzhi; Hu Kefei; Yin Chuangao; Hu Jun; Wang Song; Li Xu; Lu Zhongbin; Wang Yue; Liu Xiang

    2013-01-01

    Objective: To investigate the MSCT manifestations and their values in the diagnosis of annular pancreas in neonates. Methods: Retrospective analysis of clinical and CT findings in 27 cases with surgery-proved annular pancreas in neonates was made. The unenhanced and contrast-enhanced CT images were obtained in 20 patients. Two experienced radiologists determined the site and degree of obstruction, the relationship between the head of the pancreas and the obstruction point, and the surrounding tissue structure. Results: The direct signs included the fluid-filled or gas-filled bowel in the head of pancreas in 4 cases, the enhancement of surrounding soft tissue as enhanced pancreas in 17 cases, disappearance of the fat gap between the intestinal wall and the annular pancreas in 17 cases. The indirect signs included intestinal obstruction in 20 cases, 'single-bubble sign' in 2 cases, 'double-bubble sign' in 18 cases, the distal bowel without gas in 5 cases, small amount of gas in the distal bowel in 15 cases. In 12 of 18 cases showing 'double-bubble sign', the ratio of duodenal bubble diameter (Dd) to stomach bubble diameter (Ds)was over 1.0. The site of obstruction was located in the descending duodenum in 20 cases. The form of obstructed point presented with 'nipple sign' in 15 cases, with 'the mouse tail' in 5 cases. The expansion bowel was located in the head of pancreas in 1 case. Gas was found in the pancreatic duct in 1 case, and 'swirl sign' was shown in 2 cases. Conclusions: MSCT combined with three-dimensional reconstruction techniques can clearly demonstrate the annular pancreas' s shape, the site and degree of obstruction and other malformations. It can provide important information for clinical treatment. (authors)

  3. Determination of Pesticides by Gas Chromatography Combined with Mass Spectrometry Using Femtosecond Lasers Emitting at 267, 400, and 800 nm as the Ionization Source.

    Science.gov (United States)

    Yang, Xixiang; Imasaka, Tomoko; Imasaka, Totaro

    2018-04-03

    A standard sample mixture containing 51 pesticides was separated by gas chromatography (GC), and the constituents were identified by mass spectrometry (MS) using femtosecond lasers emitting at 267, 400, and 800 nm as the ionization source. A two-dimensional display of the GC/MS was successfully used for the determination of these compounds. A molecular ion was observed for 38 of the compounds at 267 nm and for 30 of the compounds at 800 nm, in contrast to 27 among 50 compounds when electron ionization was used. These results suggest that the ultraviolet laser is superior to the near-infrared laser for molecular weight determinations and for a more reliable analysis of these compounds. In order to study the conditions for optimal ionization, the experimental data were examined using the spectral properties (i.e., the excitation and ionization energies and absorption spectra for the neutral and ionized species) obtained by quantum chemical calculations. A few molecules remained unexplained by the currently reported rules, requiring additional rules for developing a full understanding of the femtosecond ionization process. The pesticides in the homogenized matrix obtained from kabosu ( citrus sphaerocarpa) were measured using lasers emitting at 267 and 800 nm. The pesticides were clearly separated and measured on the two-dimensional display, especially for the data measured at 267 nm, suggesting that this technique would have potential for use in the practical trace analysis of the pesticides in the environment.

  4. Acceleration of Vaporization, Atomization, and Ionization Efficiencies in Inductively Coupled Plasma by Merging Laser-Ablated Particles with Hydrochloric Acid Gas.

    Science.gov (United States)

    Nakazawa, Takashi; Izumo, Saori; Furuta, Naoki

    2016-01-01

    To accelerate the vaporization, atomization, and ionization efficiencies in laser ablation inductively coupled plasma mass spectrometry, we merged HCl gas with laser-ablated particles before introduction into the plasma, to convert their surface constituents from oxides to lower-melting chlorides. When particles were merged with HCl gas generated from a HCl solution at 200°C, the measured concentrations of elements in the particles were 135% higher on average than the concentrations in particles merged with ultrapure water vapor. Particle corrosion and surface roughness were observed by scanning electron microscopy, and oxide conversion to chlorides was confirmed by X-ray photoelectron spectroscopy. Under the optimum conditions, the recoveries of measured elements improved by 23% on average, and the recoveries of elements with high-melting oxides (Sr, Zr, and Th) improved by as much as 36%. These results indicate that vaporization, atomization, and ionization in the ICP improved when HCl gas was merged with the ablated particles.

  5. [S IV] IN THE NGC 5253 SUPERNEBULA: IONIZED GAS KINEMATICS AT HIGH RESOLUTION

    Energy Technology Data Exchange (ETDEWEB)

    Beck, Sara C. [Department of Physics and Astronomy, Tel Aviv University, Ramat Aviv (Israel); Lacy, John H. [Department of Astronomy, University of Texas at Austin, Austin, TX 78712 (United States); Turner, Jean L. [Department of Physics and Astronomy, UCLA, Los Angeles, CA 90095-1547 (United States); Kruger, Andrew; Richter, Matt [Department of Physics, University of California at Davis, Davis, CA 95616 (United States); Crosthwaite, Lucian P., E-mail: sara@wise.tau.ac.il [Northrop Grumman Aerospace Systems, San Diego, CA 92127 (United States)

    2012-08-10

    The nearby dwarf starburst galaxy NGC 5253 hosts a deeply embedded radio-infrared supernebula excited by thousands of O stars. We have observed this source in the 10.5 {mu}m line of S{sup +3} at 3.8 km s{sup -1} spectral and 1.''4 spatial resolution, using the high-resolution spectrometer TEXES on the IRTF. The line profile cannot be fit well by a single Gaussian. The best simple fit describes the gas with two Gaussians, one near the galactic velocity with FWHM 33.6 km s{sup -1} and another of similar strength and FWHM 94 km s{sup -1} centered {approx}20 km s{sup -1} to the blue. This suggests a model for the supernebula in which gas flows toward us out of the molecular cloud, as in a 'blister' or 'champagne flow' or in the H II regions modelled by Zhu.

  6. Domain-adaptive finite difference methods for collapsing annular liquid jets

    Science.gov (United States)

    Ramos, J. I.

    1993-01-01

    A domain-adaptive technique which maps a time-dependent, curvilinear geometry into a unit square is used to determine the steady state mass absorption rate and the collapse of annular liquid jets. A method of lines is used to solve the one-dimensional fluid dynamics equations written in weak conservation-law form, and upwind differences are employed to evaluate the axial convective fluxes. The unknown, time-dependent, axial location of the downstream boundary is determined from the solution of an ordinary differential equation which is nonlinearly coupled to the fluid dynamics and gas concentration equations. The equation for the gas concentration in the annular liquid jet is written in strong conservation-law form and solved by means of a method of lines at high Peclet numbers and a line Gauss-Seidel method at low Peclet numbers. The effects of the number of grid points along and across the annular jet, time step, and discretization of the radial convective fluxes on both the steady state mass absorption rate and the jet's collapse rate have been analyzed on staggered and non-staggered grids. The steady state mass absorption rate and the collapse of annular liquid jets are determined as a function of the Froude, Peclet and Weber numbers, annular jet's thickness-to-radius ratio at the nozzle exit, initial pressure difference across the annular jet, nozzle exit angle, temperature of the gas enclosed by the annular jet, pressure of the gas surrounding the jet, solubilities at the inner and outer interfaces of the annular jet, and gas concentration at the nozzle exit. It is shown that the steady state mass absorption rate is proportional to the inverse square root of the Peclet number except for low values of this parameter, and that the possible mathematical incompatibilities in the concentration field at the nozzle exit exert a great influence on the steady state mass absorption rate and on the jet collapse. It is also shown that the steady state mass absorption

  7. Low-frequency observations of Galactic supernova remnants and the distribution of low-density ionized gas in the interstellar medium

    International Nuclear Information System (INIS)

    Kassim, N.E.

    1989-01-01

    New long-wavelength observations of Galactic SNRs at 30.9 and 57.5 MHz are used to derive detailed low-frequency radio spectra for 32 SNRs. Of these, about two-thirds show turnovers at low frequencies, implying the presence of a widespread, but inhomogeneous, ionized absorbing medium along the lines of sight. These observations are combined with other low-frequency data to derive free-free optical depths toward 457 SNRs and to constrain the physical properties of the ionized gas responsible for the absorption. These optical depths are consistent with the expected absorbing properties of extended H II region envelopes. 43 refs

  8. Droplet sizes, dynamics and deposition in vertical annular flow

    International Nuclear Information System (INIS)

    Lopes, J.C.B.; Dukler, A.E.

    1985-10-01

    The role of droplets in vertical upwards annular flow is investigated, focusing on the droplet size distributions, dynamics, and deposition phenomena. An experimental program was performed based on a new laser optical technique developed in these laboratories and implemented here for annular flow. This permitted the simultaneous measurement of droplet size, axial and radial velocity. The dependence of droplet size distributions on flow conditions is analyzed. The Upper-Log Normal function proves to be a good model for the size distribution. The mechanism controlling the maximum stable drop size was found to result from the interaction of the pressure fluctuations of the turbulent flow of the gas core with the droplet. The average axial droplet velocity showed a weak dependence on gas rates. This can be explained once the droplet size distribution and droplet size-velocity relationship are analyzed simultaneously. The surprising result from the droplet conditional analysis is that larger droplet travel faster than smaller ones. This dependence cannot be explained if the drag curves used do not take into account the high levels of turbulence present in the gas core in annular flow. If these are considered, then interesting new situations of multiplicity and stability of droplet terminal velocities are encountered. Also, the observed size-velocity relationship can be explained. A droplet deposition is formulated based on the particle inertia control. This permitted the calculation of rates of drop deposition directly from the droplet size and velocities data

  9. Residual solvent determination by head space gas chromatography with flame ionization detector in omeprazole API

    Directory of Open Access Journals (Sweden)

    Saurabh Pandey

    2011-06-01

    Full Text Available Residual solvents in pharmaceutical samples are monitored using gas chromatography with head space. Based on good manufacturing practices, measuring residual solvents is mandatory for the release testing of all active pharmaceutical ingredients (API. The analysis of residual organic solvents (methanol, acetone, cyclohexane, dichloromethane, toluene in Omeprazole, an active pharmaceutical ingredient was investigated. Omeprazole is a potent reversible inhibitor of the gastric proton pump H+/K+-ATPase. The Head space gas chromatography (HSGC method described in this investigation utilized a SPB TM-624, Supelco, 30 m long x 0.25 mm internal diameter, 1.4µm-thick column. Since Omeprazole is a thermally labile compound, the selection of the proper injector temperature is critical to the success of the analysis. The injector temperature was set at 170ºC to prevent degradation. The initial oven temperature was set at 40ºC for 12 min and programmed at a rate of 10ºC min-1 to a final temperature of 220ºC for 5 min. Nitrogen was used as a carrier gas. The sample solvent selected was N,N-dimethylacetamide. The method was validated to be specific, linear, precise, sensitive, rugged and showed excellent recovery.Solventes residuais em amostras farmacêuticas são monitoradas utilizando-se cromatografia a gás "headspace". Com base nas boas práticas de fabricação, a medida de solventes residuais é obrigatória para o teste de liberação de todos os ingredientes farmacêuticos (API. Efetuou-se a análise de solventes orgânicos residuais (metanol, acetona, cicloexano, diclorometano, tolueno em omeprazol, ingrediente farmacêutico ativo. O omeprazol é potente inibidor reversível da bomba de prótons H+/K+-ATPase. A cromatografia a gás "headspace" (HSGC descrita nessa pesquisa utilizou um SPB TM-624, Supelco, de 30 m de comprimento x 0,25 mm de diâmetro interno, e coluna de 1,4 µm de espessura. Considerando-se que o omeprazol é termicamente l

  10. Biases in Metallicity Measurements from Global Galaxy Spectra: The Effects of Flux Weighting and Diffuse Ionized Gas Contamination

    Science.gov (United States)

    Sanders, Ryan L.; Shapley, Alice E.; Zhang, Kai; Yan, Renbin

    2017-12-01

    Galaxy metallicity scaling relations provide a powerful tool for understanding galaxy evolution, but obtaining unbiased global galaxy gas-phase oxygen abundances requires proper treatment of the various line-emitting sources within spectroscopic apertures. We present a model framework that treats galaxies as ensembles of H II and diffuse ionized gas (DIG) regions of varying metallicities. These models are based upon empirical relations between line ratios and electron temperature for H II regions, and DIG strong-line ratio relations from SDSS-IV MaNGA IFU data. Flux-weighting effects and DIG contamination can significantly affect properties inferred from global galaxy spectra, biasing metallicity estimates by more than 0.3 dex in some cases. We use observationally motivated inputs to construct a model matched to typical local star-forming galaxies, and quantify the biases in strong-line ratios, electron temperatures, and direct-method metallicities as inferred from global galaxy spectra relative to the median values of the H II region distributions in each galaxy. We also provide a generalized set of models that can be applied to individual galaxies or galaxy samples in atypical regions of parameter space. We use these models to correct for the effects of flux-weighting and DIG contamination in the local direct-method mass-metallicity and fundamental metallicity relations, and in the mass-metallicity relation based on strong-line metallicities. Future photoionization models of galaxy line emission need to include DIG emission and represent galaxies as ensembles of emitting regions with varying metallicity, instead of as single H II regions with effective properties, in order to obtain unbiased estimates of key underlying physical properties.

  11. Atmospheric Pressure Chemical Ionization Gas Chromatography Mass Spectrometry for the Analysis of Selected Emerging Brominated Flame Retardants in Foods

    Science.gov (United States)

    Lv, Surong; Niu, Yumin; Zhang, Jing; Shao, Bing; Du, Zhenxia

    2017-03-01

    Emerging brominated flame retardants (eBFRs) other than polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs) and their derivatives in foods have been in focus in recent years due to their increasing production volumes, indefinite information on toxicities and the lack of data on occurrence in environments, foods as well as humans. In this study, gas chromatography was coupled to an atmospheric pressure chemical ionization-tandem mass spectrometry (APGC-MS/MS) for the analysis of six eBFRs in pork, chicken, egg, milk and fish. A short section of unpacked capillary column coupled to the end of the analytical column was applied to improve the chromatographic behaviors of high boiling point compounds. The method was comprehensively validated with method limit of quantification (mLOQ) lower than 8 pg/g wet weight (w.w.). Samples from Chinese Total Diet study were quantified following the validated APGC-MS/MS method. 2,3,4,5-pentabromo-6-ethylbenzene (PBEB), hexabromobenzene (HBB), pentabromotoluene (PBT) and 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) were most frequently detected in samples. The highest concentration was found in fish with 351.9 pg/g w.w. of PBT. This is the first report on the presence of PBT in food samples with non-ignorable concentrations and detection rate.

  12. Atmospheric Pressure Chemical Ionization Gas Chromatography Mass Spectrometry for the Analysis of Selected Emerging Brominated Flame Retardants in Foods.

    Science.gov (United States)

    Lv, Surong; Niu, Yumin; Zhang, Jing; Shao, Bing; Du, Zhenxia

    2017-03-10

    Emerging brominated flame retardants (eBFRs) other than polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs) and their derivatives in foods have been in focus in recent years due to their increasing production volumes, indefinite information on toxicities and the lack of data on occurrence in environments, foods as well as humans. In this study, gas chromatography was coupled to an atmospheric pressure chemical ionization-tandem mass spectrometry (APGC-MS/MS) for the analysis of six eBFRs in pork, chicken, egg, milk and fish. A short section of unpacked capillary column coupled to the end of the analytical column was applied to improve the chromatographic behaviors of high boiling point compounds. The method was comprehensively validated with method limit of quantification (mLOQ) lower than 8 pg/g wet weight (w.w.). Samples from Chinese Total Diet study were quantified following the validated APGC-MS/MS method. 2,3,4,5-pentabromo-6-ethylbenzene (PBEB), hexabromobenzene (HBB), pentabromotoluene (PBT) and 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) were most frequently detected in samples. The highest concentration was found in fish with 351.9 pg/g w.w. of PBT. This is the first report on the presence of PBT in food samples with non-ignorable concentrations and detection rate.

  13. Seasonal variation of gastroprotective terpenoids in Maytenus robusta (Celastraceae) quantified by gas chromatography-flame ionization detection (GC-FID).

    Science.gov (United States)

    Zermiani, Tailyn; Junior, Antonio A S; Ferreira, Renê A; Wagner, Theodoro M; Machado, Marina S; Cechinel-Filho, Valdir; Niero, Rivaldo

    2016-11-01

    The triterpenes friedelin (1), β-friedelinol (2) and 3,15-dioxo-21α-hydroxyfriedelane (3) in the aerial parts of Maytenus robusta, a Brazilian medicinal plant with antiulcer potential, were seasonally quantified by gas chromatography flame-ionization detection (GC-FID) using an external standard. The method was found to be linear, precise and sensitive. Compounds 1 and 2 were found in M. robusta leaves and branches, with highest concentrations in the leaves collected in autumn, i.e. 3.21 ± 0.16 and 12.60 ± 1.49 mg g-1 dry weight of 1 and 2, respectively. On the other hand, compound 3 was found only in the branches, with the highest concentrations in winter and autumn (0.21 ± 0.01 and 0.20 ± 0.02 mg g-1). The results allow to define the optimal season and plant parts for the collection of M. robusta as a phytotherapeutic drug.

  14. [Determination of naphthenic acids in distillates of crude oil by gas chromatography/chemical ionization-mass spectrometry].

    Science.gov (United States)

    Lü, Zhenbo; Tian, Songbai; Zhai, Yuchun; Sun, Yanwei; Zhuang, Lihong

    2004-05-01

    The petroleum carboxylic acids in 200-420 degrees C distillate of crude oil were separated by the extraction with column chromatography on an anion exchange resin. The effect of the composition and structure of naphthenic acids on separation were studied by the infra-red (IR) spectroscopic techniques. Naphthenic acids and iso-butane reagent gas were introduced into the ion source for chemical ionization, in which the ions represented by [M + C4H9]+ were used to calculate the relative molecular mass for each acid. Based on the mass spectra of pure fatty and naphthenic acids, in combination with the z-series formula CnH(2n + z)O2, the naphthenic acids can be classified into fatty, mono-, bi- ... hexa-cyclic types. The results indicated that the relative molecular mass range of naphthenic acids in this distillates was 170-510, and the carbon number range was C10-C35. The contents of bi-cyclic and tri-cyclic naphthenic acids were higher than others.

  15. Determination of free amino compounds in betalainic fruits and vegetables by gas chromatography with flame ionization and mass spectrometric detection.

    Science.gov (United States)

    Kugler, Florian; Graneis, Stephan; Schreiter, Pat P-Y; Stintzing, Florian C; Carle, Reinhold

    2006-06-14

    Amino acids and amines are the precursors of betalains. Therefore, the profiles of free amino compounds in juices obtained from cactus pears [Opuntia ficus-indica (L.) Mill. cv. Bianca, cv. Gialla, and cv. Rossa], pitaya fruits [Selenicereus megalanthus (K. Schumann ex Vaupel) Moran, Hylocereus polyrhizus (Weber) Britton & Rose, and Hylocereus undatus (Haworth) Britton & Rose], and in extracts from differently colored Swiss chard [Beta vulgaris L. ssp. cicla (L.) Alef. cv. Bright Lights] petioles and red and yellow beets (B. vulgaris L. ssp. vulgaris var. conditiva Alef. cv. Burpee's Golden) were investigated for the first time. Amino compounds were derivatized with propyl chloroformate. While gas chromatography (GC) with mass spectrometry was used for peak assignment, GC flame ionization detection was applied for quantification of individual compounds. Whereas proline was the major free amino compound of cactus pear and pitaya fruit juices, glutamine dominated in Swiss chard stems and beets, respectively. Interestingly, extremely high concentrations of dopamine were detected in Swiss chard stems and beets. Furthermore, the cleavage of betaxanthins caused by derivatization in alkaline reaction solutions is demonstrated for the first time. Amino acids and amines thus released might increase the actual free amino compound contents of the respective sample. To evaluate the contribution of betaxanthin cleavage to total amino acid and amine concentration, isolated betaxanthins were derivatized according to the "EZ:faast" method prior to quantification of the respective amino compounds released. On a molar basis, betaxanthin contribution to overall amino compound contents was always below 6.4%.

  16. Studies on the profile measurement of hadron beams by means of residual-gas luminescence and ionization

    International Nuclear Information System (INIS)

    Boehme, Christian Gerhard Heinrich

    2011-01-01

    Modern particle accelerators are applied for a long time no more only in the fundamental physical research but in ever larger extent also in the concrete application for instance in the tumor irradiation or the microprocessor fabrication. The precise knowledge of the beam profile is thereby of great importance for the success. But in intermediate-energy hadron accelerators it hitherto not satisfyingly succeeds to measure the beam profiles not disturbingly. These study presents two not beam-disturbing measuring methods, which are based on the ion beam-residual gas interactions of luminescence and ionization. They were developed for different framework conditions at the JESSICA beam place of the COSY accelerator of the Juelich research center, an advance experiment of the planned European Spallation Source (ESS), as well at the proton synchrotron COSY itself, and the iThemba Laboratory for Accelerator Based Science, Somerset West, South Africa. Thereby the studies consider a large range of possible configuration parameters: Particle momenta from 3 MeV/c to 3 GeV/c, pressures from 1 mbar to 10 -11 mbar and time structures from DC beam to beam bunches of 100 ns length. The experimental arrangement, the application ranges, and the advantages and disadvantages of both methods are explained in this book.

  17. COMPLETE IONIZATION OF THE NEUTRAL GAS: WHY THERE ARE SO FEW DETECTIONS OF 21 cm HYDROGEN IN HIGH-REDSHIFT RADIO GALAXIES AND QUASARS

    Energy Technology Data Exchange (ETDEWEB)

    Curran, S. J. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Whiting, M. T., E-mail: sjc@physics.usyd.edu.au [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia)

    2012-11-10

    From the first published z {approx}> 3 survey of 21 cm absorption within the hosts of radio galaxies and quasars, Curran et al. found an apparent dearth of cool neutral gas at high redshift. From a detailed analysis of the photometry, each object is found to have a {lambda} = 1216 A continuum luminosity in excess of L {sub 1216} {approx} 10{sup 23} W Hz{sup -1}, a critical value above which 21 cm has never been detected at any redshift. At these wavelengths, and below, hydrogen is excited above the ground state so that it cannot absorb in 21 cm. In order to apply the equation of photoionization equilibrium, we demonstrate that this critical value also applies to the ionizing ({lambda} {<=} 912 A) radiation. We use this to show, for a variety of gas density distributions, that upon placing a quasar within a galaxy of gas, there is always an ultraviolet luminosity above which all of the large-scale atomic gas is ionized. While in this state, the hydrogen cannot be detected or engage in star formation. Applying the mean ionizing photon rate of all of the sources searched, we find, using canonical values for the gas density and recombination rate coefficient, that the observed critical luminosity gives a scale length (3 kpc) similar that of the neutral hydrogen (H I) in the Milky Way, a large spiral galaxy. Thus, this simple yet physically motivated model can explain the critical luminosity (L {sub 912} {approx} L {sub 1216} {approx} 10{sup 23} W Hz{sup -1}), above which neutral gas is not detected. This indicates that the non-detection of 21 cm absorption is not due to the sensitivity limits of current radio telescopes, but rather that the lines of sight to the quasars, and probably the bulk of the host galaxies, are devoid of neutral gas.

  18. Online Simultaneous Hydrogen/Deuterium Exchange of Multitarget Gas-Phase Molecules by Electrospray Ionization Mass Spectrometry Coupled with Gas Chromatography.

    Science.gov (United States)

    Jeong, Eun Sook; Cha, Eunju; Cha, Sangwon; Kim, Sunghwan; Oh, Han Bin; Kwon, Oh-Seung; Lee, Jaeick

    2017-11-21

    In this study, a hydrogen/deuterium (H/D) exchange method using gas chromatography-electrospray ionization/mass spectrometry (GC-ESI/MS) was first investigated as a novel tool for online H/D exchange of multitarget analytes. The GC and ESI source were combined with a homemade heated column transfer line. GC-ESI/MS-based H/D exchange occurs in an atmospheric pressure ion source as a result of reacting the gas-phase analyte eluted from GC with charged droplets of deuterium oxide infused as the ESI spray solvent. The consumption of the deuterated solvent at a flow rate of 2 μL min -1 was more economical than that in online H/D exchange methods reported to date. In-ESI-source H/D exchange by GC-ESI/MS was applied to 11 stimulants with secondary amino or hydroxyl groups. After H/D exchange, the spectra of the stimulants showed unexchanged, partially exchanged, and fully exchanged ions showing various degrees of exchange. The relative abundances corrected for naturally occurring isotopes of the fully exchanged ions of stimulants, except for etamivan, were in the range 24.3-85.5%. Methylephedrine and cyclazodone showed low H/D exchange efficiency under acidic, neutral, and basic spray solvent conditions and nonexchange for etamivan with an acidic phenolic OH group. The in-ESI-source H/D exchange efficiency by GC-ESI/MS was sufficient to determine the number of hydrogen by elucidation of fragmentation from the spectrum. Therefore, this online H/D exchange technique using GC-ESI/MS has potential as an alternative method for simultaneous H/D exchange of multitarget analytes.

  19. Entrainment in vertical annular two-phase flow

    International Nuclear Information System (INIS)

    Sawant, Pravin; Ishii, Mamoru; Mori, Michitsugu

    2009-01-01

    Prediction of amount of entrained droplets or entrainment fraction in annular two-phase flow is essential for the estimation of dryout condition and analysis of post dryout heat transfer in light water nuclear reactors and steam boilers. In this study, air-water and organic fluid (Freon-113) annular flow entrainment experiments have been carried out in 9.4 and 10.2 mm diameter test sections, respectively. Both the experiments covered three distinct pressure conditions and wide range of liquid and gas flow conditions. The organic fluid experiments simulated high pressure steam-water annular flow conditions. In each of the experiments, measurements of entrainment fraction, droplet entrainment rate and droplet deposition rate have been performed by using a liquid film extraction method. A simple, explicit and non-dimensional correlation developed by Sawant et al. (2008a) for the prediction of entrainment fraction is further improved in this study in order to account for the existence of critical gas and liquid flow rates below which no entrainment is possible. Additionally, a new correlation is proposed for the estimation of minimum liquid film flow rate at the maximum entrainment fraction condition. The improved correlation successfully predicted the newly collected air-water and Freon-113 entrainment fraction data. Furthermore, the correlations satisfactorily compared with the air-water, helium-water and air-genklene experimental data measured by Willetts (1987). (author)

  20. Effect of surface potential and intrinsic magnetic field on resistance of a body in a supersonic flow of rarefied partially ionized gas

    International Nuclear Information System (INIS)

    Shuvalov, V.A.

    1986-01-01

    The character of flow over a body, structure of the perturbed zone, and flow resistance in a supersonic flow of rarefied partially ionized gas are determined by the intrinsic magnetic field and surface potential of the body. There have been practically no experimental studies of the effect of intrinsic magnetic field on flow of a rarefied plasma. Studies of the effect of surface potential have been limited to the case R/λd 10 2 (where R is the characteristic dimension of the body and λd is the Debye radius). At the same time R/λd > 10 2 , the regime of flow over a large body, is of the greatest practical interest. The present study will consider the effect of potential and intrinsic magnetic field on resistance of a large (R/λd > 10 2 ) axisymmetric body (disk, sphere) in a supersonic flow of rarefield partially ionized gas

  1. A 350 MW HTR with an annular pebble bed core

    International Nuclear Information System (INIS)

    Wang Dazhong; Jiang Zhiqiang; Gao Zuying; Xu Yuanhui

    1992-12-01

    A conceptual design of HTR-module with an annular pebble bed core was proposed. This design can increase the unit power capacity of HTR-Module from 200 MWt to 350 MWt while it can keep the inherent safety characteristics of modular reactor. The preliminary safety analysis results for 350 MW HTR are given. In order to solve the problem of uneven helium outlet temperature distribution a gas flow mixing structure at bottom of core was designed. The experiment results of a gas mixing simulation test rig show that the mixing function can satisfy the design requirements

  2. Simulation of the Interaction of X-rays with a Gas in an Ionization Chamber by the Monte Carlo Method; Simulacion Monte Carlo de la Interaccion de Rays X con el Gas de una Camara de Ionizacion

    Energy Technology Data Exchange (ETDEWEB)

    Grau Carles, A.; Garcia Gomez-Tejedor, G.

    2001-07-01

    The final objective of any ionization chamber is the measurement of the energy amount or radiation dose absorbed by the gas into the chamber. The final value depends on the composition of the gas, its density and temperature, the ionization chamber geometry, and type and intensity of the radiation. We describe a Monte Carlo simulation method, which allows one to compute the dose absorbed by the gas for a X-ray beam. Verification of model has been carried out by simulating the attenuation of standard X-ray radiation through the half value layers established in the ISO 4037 report, while assuming a Weibull type energy distribution for the incident photons. (Author) 6 refs.

  3. Development of annular targets for 99Mo production

    International Nuclear Information System (INIS)

    Conner, C.; Lewandowski, E.F.; Snelgrove, J.L.; Liberatore, M.W.; Walker, D.E.; Wiencek, T.C.; McGann, D.J.; Hofman, G.L.; Vandegrift, G.F.

    1999-01-01

    During 1999, significant progress was made in the development of a low-enriched uranium (LEU) target for production of 99 Mo. Successful conversion requires an inexpensive, reliable target. To keep the target geometry the same when changing from high-enriched uranium (HEU) to LEU targets, a denser form of uranium is required in order to increase the amount of uranium per target by a factor of approximately five. Targets containing LEU in the form of a metal foil are being developed for producing 99 Mo from the fissioning of 235 U. A new annular target was developed this year, and seven targets were irradiated in the Indonesian RSG-GAS reactor. Results of development of this annular target and its performance during irradiation are described. (author)

  4. Kinetic theory of weakly ionized dilute gas of hydrogen-like atoms of the first principles of quantum statistics and dispersion laws of eigenwaves

    Science.gov (United States)

    Slyusarenko, Yurii V.; Sliusarenko, Oleksii Yu.

    2017-11-01

    We develop a microscopic approach to the construction of the kinetic theory of dilute weakly ionized gas of hydrogen-like atoms. The approach is based on the statements of the second quantization method in the presence of bound states of particles. The basis of the derivation of kinetic equations is the method of reduced description of relaxation processes. Within the framework of the proposed approach, a system of common kinetic equations for the Wigner distribution functions of free oppositely charged fermions of two kinds (electrons and cores) and their bound states—hydrogen-like atoms— is obtained. Kinetic equations are used to study the spectra of elementary excitations in the system when all its components are non-degenerate. It is shown that in such a system, in addition to the typical plasma waves, there are longitudinal waves of matter polarization and the transverse ones with a behavior characteristic of plasmon polaritons. The expressions for the dependence of the frequencies and Landau damping coefficients on the wave vector for all branches of the oscillations discovered are obtained. Numerical evaluation of the elementary perturbation parameters in the system on an example of a weakly ionized dilute gas of the 23Na atoms using the D2-line characteristics of the natrium atom is given. We note the possibility of using the results of the developed theory to describe the properties of a Bose condensate of photons in the diluted weakly ionized gas of hydrogen-like atoms.

  5. Experimental study of inverted-annular-flow hydrodynamics utilizing an adiabatic simulation

    International Nuclear Information System (INIS)

    De Jarlais, G.

    1983-03-01

    In experiments, inverted annular flow was simulated adiabatically with turbulent water jets, issuing downward from long aspect nozzles, enclosed in gas annuli. Velocities, diameters, and gas species were varied, and core jet length, shape, break-up mode, and dispersed-core droplet sizes were recorded at approximately 750 data points. Inverted annular flow was observed to develop into inverted slug flow at low relative velocities, and into dispersed droplet flow at high relative velocities. For both of the above transitions from inverted annular flow, correlations for core jet length were developed by extending work done on free liquid jets to include this new, coaxial, jet disintegration phenomenon. Jet break-up length is correlated as a function of jet diameter, jet Reynolds number, jet Weber number, void fraction, and gas Weber number. Correlations for core shape, break-up mechanisms and dispersed core droplet size for the case of transition to inverted slug flow were developed

  6. Thermal performance of annular-coated and sphere-pac LWR fuel rod designs

    International Nuclear Information System (INIS)

    Guenther, R.J.; Hsieh, K.A.; Barner, J.O.; Freshley, M.D.

    1980-01-01

    Two FCI-resistant UO 2 fuel rod designs are being compared to a reference design in irradiation tests in the Halden Boiling Water Reactor (HBWR) as part of the DOE-sponsored Fuel Performance Improvement Program (FPIP). The primary fuel design (annular-coated-pressurized) incorporates annular pellets, a graphite coating on the inner surface of the Zircaloy cladding, and pressurized helium fill gas. Also being investigated is an 87% smear density sphere-pac design with pressurized helium fill gas. The solid pellet (reference) and annular-coated designs described had helium fill gas at approx. 100 kPa and the sphere-pac rods were pressurized at approx. 455 kPa

  7. DECIPHERING THE IONIZED GAS CONTENT IN THE MASSIVE STAR-FORMING COMPLEX G75.78+0.34

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Monge, Alvaro [Osservatorio Astrofisico di Arcetri, INAF, Largo E. Fermi 5, I-50125 Firenze (Italy); Kurtz, Stan; Lizano, Susana [Centro de Radioastronomia y Astrofisica, Universidad Nacional Autonoma de Mexico, Apdo. Postal 3-72, 58090, Morelia, Michoacan (Mexico); Palau, Aina [Institut de Ciencies de l' Espai (CSIC-IEEC), Campus UAB-Facultat de Ciencies, Torre C5p 2, E-08193 Bellaterra, Catalunya (Spain); Estalella, Robert [Dpt d' Astronomia i Meteorologia (IEEC-UB), Institut de Ciencies del Cosmos, Universitat de Barcelona, Marti i Franques, 1, E-08028 Barcelona (Spain); Shepherd, Debra [NRAO, P.O. Box O, Socorro, NM 87801-0387 (United States); Franco, Jose [Instituto de Astronomia, Universidad Nacional Autonoma de Mexico, Apdo. Postal 70-264, 04510 Mexico, D.F. (Mexico); Garay, Guido, E-mail: asanchez@arcetri.astro.it [Departamento de Astronomia, Universidad de Chile, Camino el Observatorio 1515, Las Condes, Santiago (Chile)

    2013-04-01

    We present subarcsecond observations toward the massive star-forming region G75.78+0.34. We used the Very Large Array to study the centimeter continuum and H{sub 2}O and CH{sub 3}OH maser emission, and the Owens Valley Radio Observatory and Submillimeter Array to study the millimeter continuum and recombination lines (H40{alpha} and H30{alpha}). We found radio continuum emission at all wavelengths, coming from three components: (1) a cometary ultracompact (UC) H II region with an electron density {approx}3.7 Multiplication-Sign 10{sup 4} cm{sup -3}, excited by a B0 type star, and with no associated dust emission; (2) an almost unresolved UCH II region (EAST), located {approx}6'' to the east of the cometary UCH II region, with an electron density {approx}1.3 Multiplication-Sign 10{sup 5} cm{sup -3}, and associated with a compact dust clump detected at millimeter and mid-infrared wavelengths; and (3) a compact source (CORE), located {approx}2'' to the southwest of the cometary arc, with a flux density increasing with frequency, and embedded in a dust condensation of 30 M{sub Sun }. The CORE source is resolved into two compact and unresolved sources which can be well fit by two homogeneous hypercompact H II regions each one photoionized by a B0.5 zero-age main sequence star, or by free-free radiation from shock-ionized gas resulting from the interaction of a jet/outflow system with the surrounding environment. The spatial distribution and kinematics of water masers close to the CORE-N and S sources, together with excess emission at 4.5 {mu}m and the detected dust emission, suggest that the CORE source is a massive protostar driving a jet/outflow.

  8. DECIPHERING THE IONIZED GAS CONTENT IN THE MASSIVE STAR-FORMING COMPLEX G75.78+0.34

    International Nuclear Information System (INIS)

    Sánchez-Monge, Álvaro; Kurtz, Stan; Lizano, Susana; Palau, Aina; Estalella, Robert; Shepherd, Debra; Franco, José; Garay, Guido

    2013-01-01

    We present subarcsecond observations toward the massive star-forming region G75.78+0.34. We used the Very Large Array to study the centimeter continuum and H 2 O and CH 3 OH maser emission, and the Owens Valley Radio Observatory and Submillimeter Array to study the millimeter continuum and recombination lines (H40α and H30α). We found radio continuum emission at all wavelengths, coming from three components: (1) a cometary ultracompact (UC) H II region with an electron density ∼3.7 × 10 4 cm –3 , excited by a B0 type star, and with no associated dust emission; (2) an almost unresolved UCH II region (EAST), located ∼6'' to the east of the cometary UCH II region, with an electron density ∼1.3 × 10 5 cm –3 , and associated with a compact dust clump detected at millimeter and mid-infrared wavelengths; and (3) a compact source (CORE), located ∼2'' to the southwest of the cometary arc, with a flux density increasing with frequency, and embedded in a dust condensation of 30 M ☉ . The CORE source is resolved into two compact and unresolved sources which can be well fit by two homogeneous hypercompact H II regions each one photoionized by a B0.5 zero-age main sequence star, or by free-free radiation from shock-ionized gas resulting from the interaction of a jet/outflow system with the surrounding environment. The spatial distribution and kinematics of water masers close to the CORE-N and S sources, together with excess emission at 4.5 μm and the detected dust emission, suggest that the CORE source is a massive protostar driving a jet/outflow.

  9. Determination of 2-Octanone in Biological Samples Using Liquid–Liquid Microextractions Followed by Gas Chromatography–Flame Ionization Detectio

    Directory of Open Access Journals (Sweden)

    Abolghasem Jouyban, Maryam Abbaspour, Mir Ali Farajzadeh, Maryam Khoubnasabjafari

    2017-06-01

    Full Text Available Background: Analysis of chemicals in biological fluids is required in many areas of medical sciences. Rapid, highly efficient, and reliable dispersive and air assisted liquid–liquid microextraction methods followed by gas chromatography-flame ionization detection were developed for the extraction, preconcentration, and determination of 2-octanone in human plasma and urine samples. Methods: Proteins of plasma samples are precipitated by adding methanol and urine sample is diluted with water prior to performing the microextraction procedure. Fine organic solvent droplets are formed by repeated suction and injection of the mixture of sample solution and extraction solvent into a test tube with a glass syringe. After extraction, phase separation is performed by centrifuging and the enriched analyte in the sedimented organic phase is determined by the separation system. The main factors influencing the extraction efficiency including extraction solvent type and volume, salt addition, pH, and extraction times are investigated. Results: Under the optimized conditions, the proposed method showed good precision (relative standard deviation less than 7%. Limit of detection and lower limit of quantification for 2-octanone were obtained in the range of 0.1–0.5 µg mL−1. The linear ranges were 0.5-500 and 0.5-200 µg mL−1 in plasma and urine, respectively (r2 ≥ 0.9995. Enrichment factors were in the range of 13-37. Good recoveries (55–86% were obtained for the spiked samples. Conclusion: Preconcentration methods coupled with GC analysis were developed and could be used to monitor 2-octanone in biological samples.

  10. Qualitative and quantitative analysis of pyrolysis oil by gas chromatography with flame ionization detection and comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry.

    Science.gov (United States)

    Sfetsas, Themistoklis; Michailof, Chrysa; Lappas, Angelos; Li, Qiangyi; Kneale, Brian

    2011-05-27

    Pyrolysis oils have attracted a lot of interest, as they are liquid energy carriers and general sources of chemicals. In this work, gas chromatography with flame ionization detector (GC-FID) and two-dimensional gas chromatography with time-of-flight mass spectrometry (GC×GC-TOFMS) techniques were used to provide both qualitative and quantitative results of the analysis of three different pyrolysis oils. The chromatographic methods and parameters were optimized and solvent choice and separation restrictions are discussed. Pyrolysis oil samples were diluted in suitable organic solvent and were analyzed by GC×GC-TOFMS. An average of 300 compounds were detected and identified in all three samples using the ChromaToF (Leco) software. The deconvoluted spectra were compared with the NIST software library for correct matching. Group type classification was performed by use of the ChromaToF software. The quantification of 11 selected compounds was performed by means of a multiple-point external calibration curve. Afterwards, the pyrolysis oils were extracted with water, and the aqueous phase was analyzed both by GC-FID and, after proper change of solvent, by GC×GC-TOFMS. As previously, the selected compounds were quantified by both techniques, by means of multiple point external calibration curves. The parameters of the calibration curves were calculated by weighted linear regression analysis. The limit of detection, limit of quantitation and linearity range for each standard compound with each method are presented. The potency of GC×GC-TOFMS for an efficient mapping of the pyrolysis oil is undisputable, and the possibility of using it for quantification as well has been demonstrated. On the other hand, the GC-FID analysis provides reliable results that allow for a rapid screening of the pyrolysis oil. To the best of our knowledge, very few papers have been reported with quantification attempts on pyrolysis oil samples using GC×GC-TOFMS most of which make use of the

  11. Ionization chamber

    International Nuclear Information System (INIS)

    1977-01-01

    An improved ionization chamber type X-ray detector comprises a heavy gas at high pressure disposed between an anode and a cathode. An open grid structure is placed next to the anode and is maintained at a voltage intermediate between the cathode and anode potentials. The electric field which is produced by positive ions drifting towards the cathode is thus shielded from the anode. Current measuring circuits connected to the anode are, therefore, responsive only to electron current flow within the chamber and the recovery time of the chamber is shortened. The grid structure also serves to shield the anode from electrical currents which might otherwise be induced by mechanical vibrations in the ionization chamber structure

  12. IBEX - annular beam propagation experiment

    International Nuclear Information System (INIS)

    Mazarakis, M.G.; Miller, R.B.; Shope, S.L.; Poukey, J.W.; Ramirez, J.J.; Ekdahl, C.A.; Adler, R.J.

    1983-01-01

    IBEX is a 4-MV, 100-kA, 20-ns cylindrical isolated Blumlein accelerator. In the experiments reported here, the accelerator is fitted with a specially designed foilless diode which is completely immersed in a uniform magnetic field. Several diode geometries have been studied as a function of magnetic field strength. The beam propagates a distance of 50 cm (approx. 10 cyclotron wavelengths) in vacuum before either striking a beam stop or being extracted through a thin foil. The extracted beam was successfully transported 60 cm downstream into a drift pipe filled either with 80 or 640 torr air. The main objectives of this experiment were to establish the proper parameters for the most quiescent 4 MV, 20 to 40 kA annular beam, and to compare the results with available theory and numerical code simulations

  13. Combined Determination of Poly-β-Hydroxyalkanoic and Cellular Fatty Acids in Starved Marine Bacteria and Sewage Sludge by Gas Chromatography with Flame Ionization or Mass Spectrometry Detection

    Science.gov (United States)

    Odham, Göran; Tunlid, Anders; Westerdahl, Gunilla; Mårdén, Per

    1986-01-01

    Extraction of lipids from bacterial cells or sewage sludge samples followed by simple and rapid extraction procedures and room temperature esterification with pentafluorobenzylbromide allowed combined determinations of poly-β-hydroxyalkanoate constituents and fatty acids. Capillary gas chromatography and flame ionization or mass spectrometric detection was used. Flame ionization permitted determination with a coefficient of variation ranging from 10 to 27% at the picomolar level, whereas quantitative chemical ionization mass spectrometry afforded sensitivities for poly-β-hydroxyalkanoate constituuents in the attomolar range. The latter technique suggests the possibility of measuring such components in bacterial assemblies with as few as 102 cells. With the described technique using flame ionization detection, it was possible to study the rapid formation of poly-β-hydroxyalkanoate during feeding of a starved marine bacterium isolate with a complex medium or glucose and correlate the findings to changes in cell volumes. Mass spectrometric detection of short β-hydroxy acids in activated sewage sludge revealed the presence of 3-hydroxybutyric, 3-hydroxyhexanoic, and 3-hydroxyoctanoic acids in the relative proportions of 56, 5 and 39%, respectively. No odd-chain β-hydroxy acids were found. PMID:16347181

  14. Ionized Gas Kinematics around an Ultra-luminous X-Ray Source in NGC 5252: Additional Evidence for an Off-nuclear AGN

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Minjin [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of); Ho, Luis C. [Kavli Institute for Astronomy and Astrophysics, Peking University, Beijing 100871 (China); Im, Myungshin [Center for the Exploration of the Origin of the Universe (CEOU), Astronomy Program, Department of Physics and Astronomy, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul, 151-742 (Korea, Republic of)

    2017-08-01

    The Seyfert 2 galaxy NGC 5252 contains a recently identified ultra-luminous X-ray (ULX) source that has been suggested to be a possible candidate off-nuclear low-mass active galactic nucleus. We present follow-up optical integral-field unit observations obtained using Gemini Multi-Object Spectrographs on the Gemini-North telescope. In addition to confirming that the ionized gas in the vicinity of the ULX is kinematically associated with NGC 5252, the new observations reveal ordered motions consistent with rotation around the ULX. The close coincidence of the excitation source of the line-emitting gas with the position of the ULX further suggests that ULX itself is directly responsible for the ionization of the gas. The spatially resolved measurements of [N ii] λ 6584/H α surrounding the ULX indicate a low gas-phase metallicity, consistent with those of other known low-mass active galaxies but not that of its more massive host galaxy. These findings strengthen the proposition that the ULX is not a background source but rather that it is the nucleus of a small, low-mass galaxy accreted by NGC 5252.

  15. GEMINI NEAR INFRARED FIELD SPECTROGRAPH OBSERVATIONS OF THE SEYFERT 2 GALAXY MRK 573: IN SITU ACCELERATION OF IONIZED AND MOLECULAR GAS OFF FUELING FLOWS

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Travis C.; Straughn, A. N. [Astrophysics Science Division, Goddard Space Flight Center, Code 665, Greenbelt, MD 20771 (United States); Machuca, C.; Crenshaw, D. M.; Baron, F.; Revalski, M.; Pope, C. L. [Department of Physics and Astronomy, Georgia State University, Astronomy Offices, 25 Park Place, Suite 605, Atlanta, GA 30303 (United States); Diniz, M. R.; Riffel, R. A. [Departamento de Física, Centro de Ciências Naturais e Exatas, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil); Kraemer, S. B. [Institute for Astrophysics and Computational Sciences, Department of Physics, The Catholic University of America, Washington, DC 20064 (United States); Schmitt, H. R. [Naval Research Laboratory, Washington, DC 20375 (United States); Storchi-Bergmann, T., E-mail: travis.c.fischer@nasa.gov [Departamento de Astronomia, Universidade Federal do Rio Grande do Sul, IF, CP 15051, 91501-970 Porto Alegre, RS (Brazil)

    2017-01-01

    We present near-infrared and optical emission-line and stellar kinematics of the Seyfert 2 galaxy Mrk 573 using the Near-Infrared Field Spectrograph (NIFS) at Gemini North and Dual Imaging Spectrograph at Apache Point Observatory, respectively. By obtaining full kinematic maps of the infrared ionized and molecular gas and stellar kinematics in a ∼700 × 2100 pc{sup 2} circumnuclear region of Mrk 573, we find that kinematics within the Narrow-Line Region are largely due to a combination of both rotation and in situ acceleration of material originating in the host disk. Combining these observations with large-scale, optical long-slit spectroscopy that traces ionized gas emission out to several kpcs, we find that rotation kinematics dominate the majority of the gas. We find that outflowing gas extends to distances less than 1 kpc, suggesting that outflows in Seyfert galaxies may not be powerful enough to evacuate their entire bulges.

  16. Application of pyrolysis–mass spectrometry and pyrolysis–gas chromatography–mass spectrometry with electron-ionization or resonance-enhanced-multi-photon ionization for characterization of crude oils

    International Nuclear Information System (INIS)

    Otto, Stefan; Streibel, Thorsten; Erdmann, Sabrina; Sklorz, Martin; Schulz-Bull, Detlef; Zimmermann, Ralf

    2015-01-01

    Highlights: • Gas chromatography setup with two MS detectors applying different ionization methods. • In parallel structural information and sensitive detection of aromatic species. • Characterization of setup and application for crude oil samples. • Detection of polycyclic aromatic hydrocarbons next to sulfur containing aromatics. - Abstract: A novel analytical system for gas-chromatographic investigation of complex samples has been developed, that combines the advantages of several analytical principles to enhance the analytical information. Decomposition of high molecular weight structures is achieved by pyrolysis and a high separation capacity due to the chromatographic step provides both an universal as well as a selective and sensitive substance detection. The latter is achieved by simultaneously applying electron ionization quadrupole mass spectrometry (EI-QMS) for structural elucidation and [1 + 1]-resonance-enhanced-multi-photon ionization (REMPI) combined with time-of-flight mass spectrometry (ToFMS). The system has been evaluated and tested with polycyclic aromatic hydrocarbon (PAH) standards. It was applied to crude oil samples for the first time. In such highly complex samples several thousands of compounds are present and the identification especially of low concentrated chemical species such as PAH or their polycyclic aromatic sulfur containing heterocyclic (PASH) derivatives is often difficult. Detection of unalkylated and alkylated PAH together with PASH is considerably enhanced by REMPI–ToFMS, at times revealing aromatic structures which are not observable by EI-QMS due to their low abundance. On the other hand, the databased structure proposals of the EI-QMS analysis are needed to confirm structural information and isomers distinction. The technique allows a complex structure analysis as well as selective assessment of aromatic substances in one measurement. Information about the content of sulfur containing compounds plays a

  17. Application of pyrolysis–mass spectrometry and pyrolysis–gas chromatography–mass spectrometry with electron-ionization or resonance-enhanced-multi-photon ionization for characterization of crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Otto, Stefan [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Streibel, Thorsten, E-mail: thorsten.streibel@uni-rostock.de [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany); Erdmann, Sabrina [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Sklorz, Martin [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany); Schulz-Bull, Detlef [Marine Chemistry, Leibniz Institute for Baltic Sea Research, Warnemünde, Seestrasse 15, 18119 Rostock (Germany); Zimmermann, Ralf [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany)

    2015-01-15

    Highlights: • Gas chromatography setup with two MS detectors applying different ionization methods. • In parallel structural information and sensitive detection of aromatic species. • Characterization of setup and application for crude oil samples. • Detection of polycyclic aromatic hydrocarbons next to sulfur containing aromatics. - Abstract: A novel analytical system for gas-chromatographic investigation of complex samples has been developed, that combines the advantages of several analytical principles to enhance the analytical information. Decomposition of high molecular weight structures is achieved by pyrolysis and a high separation capacity due to the chromatographic step provides both an universal as well as a selective and sensitive substance detection. The latter is achieved by simultaneously applying electron ionization quadrupole mass spectrometry (EI-QMS) for structural elucidation and [1 + 1]-resonance-enhanced-multi-photon ionization (REMPI) combined with time-of-flight mass spectrometry (ToFMS). The system has been evaluated and tested with polycyclic aromatic hydrocarbon (PAH) standards. It was applied to crude oil samples for the first time. In such highly complex samples several thousands of compounds are present and the identification especially of low concentrated chemical species such as PAH or their polycyclic aromatic sulfur containing heterocyclic (PASH) derivatives is often difficult. Detection of unalkylated and alkylated PAH together with PASH is considerably enhanced by REMPI–ToFMS, at times revealing aromatic structures which are not observable by EI-QMS due to their low abundance. On the other hand, the databased structure proposals of the EI-QMS analysis are needed to confirm structural information and isomers distinction. The technique allows a complex structure analysis as well as selective assessment of aromatic substances in one measurement. Information about the content of sulfur containing compounds plays a

  18. Improvements in ionization chambers

    International Nuclear Information System (INIS)

    Whetten, N.R.; Zubal, C.

    1980-01-01

    A method of reducing mechanical vibrations transmitted to the parallel plate electrodes of ionization chamber x-ray detectors, commonly used in computerized x-ray axial tomography systems, is described. The metal plate cathodes and anodes are mounted in the ionizable gas on dielectric sheet insulators consisting of a composite of silicone resin and glass fibres. (UK)

  19. Dependence of charge collection distributions and dose on the gas type filling the ionization chamber for a p(66)Be(49) clinical neutron beam

    International Nuclear Information System (INIS)

    Awschalom, M.; Haken, R.K.T.

    1985-01-01

    Measurements of central axis depth charge distributions (CADCD) in a p(66)Be(49) clinical neutron beam using A-150 TE plastic ionization chambers (IC) have shown that these distributions are dependent on the gas type filling the ICs. IC volumes from 0.1 to 8 cm 3 and nine different gases were investigated. Off axis ratios and build-up measurements do not seem to be as sensitive to gas type. The gas dosimetry constants given in the AAPM Protocol for Neutron Beam Dosimetry for air and methane based TE gases were tested for consistency in water and in TE solution filled phantoms at depths of 10 cm, when used in conjunction with an IC having 5 mm thick walls of A-150. 29 refs., 7 figs., 1 tab

  20. Experimental Observation of Densification Behavior of UO2 Annular Pellet

    International Nuclear Information System (INIS)

    Kim, Dong-Joo; Rhee, Young-Woo; Kim, Jong-Hun; Yang, Jae-Ho; Kang, Ki-Won; Kim, Keon-Sik

    2007-01-01

    Recently, in the nuclear industry, one of the major issues is the improvement of a fuel economy. And many efforts have been made to develop a nuclear fuel for a high burnup and extended cycle. In the development of a high performance fuel, in-reactor fuel behavior (fission gas release, pellet-clad interaction, stress corrosion cracking, cladding corrosion, etc.) must be seriously reconsidered. Also, fuel fabrication (high enriched UO 2 powder handling, fuel rod and assembly manufacturing, fabricated fuel rod and assembly storage and transport, etc.) and an enrichment process (5 w/o criticality limit, etc.) must be discussed. A modification and an improvement of the nuclear fuel system will be also required. The typical fuel geometry of a PWR (Pressurized Water Reactor) is composed of a cylindrical pellet with a tubular cladding. And the outer surface of the cladding is cooled with water. However, to allow a substantial increase in the power density, an additional cooling is needed. One of the best ways is the application of the new fuel geometry that is of annular shape and has both internal and external cooling. From this point of view, the double cooled fuel is being developed by KAERI (Korea Atomic Energy Research Institute), and as a part of the project, the development of a fabrication process of a UO 2 annular pellet is now in progress. The dimensional behavior of UO 2 fuel is an important parameter in an irradiation performance. Various investigations (resintering test, model calculation, in-pile dimensional change measuring, etc.) had been performed. In designing a double cooled fuel, the importance of the dimensional behavior of a fuel pellet is higher, because the gap distance between a pellet and cladding can considerably affect on the in reactor fuel performance (gap conductance). And the dimensional behavior of an inner/outer gap is different with a cylindrical pellet, when the pellet shrinks (densification), the inner gap distance decreases and the

  1. CF3+ fragmentation by electron impact ionization of perfluoro-propyl-vinyl-ethers, C5F10O, in gas phase

    Science.gov (United States)

    Kondo, Yusuke; Ishikawa, Kenji; Hayashi, Toshio; Miyawaki, Yudai; Takeda, Keigo; Kondo, Hiroki; Sekine, Makoto; Hori, Masaru

    2015-04-01

    The gas phase fragmentations of perfluoro-propyl-vinyl ether (PPVE, C5F10O) are studied experimentally. Dominant fragmentations of PPVE are found to be the result of a dissociative ionization reaction, i.e., CF3+ via direct bond cleavage, and C2F3O- and C3F7O- via electron attachment. Regardless of the appearance energy of around 14.5 eV for the dissociative ionization of CF3+, the observed ion efficiency for the CF3+ ion was extremely large the order of 10-20 cm-2, compared with only 10-21 cm-2 for the other channels. PPVE characteristically generated CF3+ as the largest abundant ion are advantageous for use of feedstock gases in plasma etching processes.

  2. Evaluation of gas chromatography – electron ionization – full scan high resolution Orbitrap mass spectrometry for pesticide residue analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mol, Hans G.J., E-mail: hans.mol@wur.nl; Tienstra, Marc; Zomer, Paul

    2016-09-07

    Gas chromatography with electron ionization and full scan high resolution mass spectrometry with an Orbitrap mass analyzer (GC-EI-full scan Orbitrap HRMS) was evaluated for residue analysis. Pesticides in fruit and vegetables were taken as an example application. The relevant aspects for GC-MS based residue analysis, including the resolving power (15,000 to 120,000 FWHM at m/z 200), scan rate, dynamic range, selectivity, sensitivity, analyte identification, and utility of existing EI-libraries, are assessed and discussed in detail. The optimum acquisition conditions in full scan mode (m/z 50–500) were a resolving power of 60,000 and an automatic-gain-control target value of 3E6. These conditions provided (i) an optimum mass accuracy: within 2 ppm over a wide concentration range, with/without matrix, enabling the use of ±5 ppm mass extraction windows (ii) adequate scan speed: minimum 12 scans/peak, (iii) an intra-scan dynamic range sufficient to achieve LOD/LOQs ≤0.5 pg in fruit/vegetable matrices (corresponding to ≤0.5 μg kg{sup −1}) for most pesticides. EI-Orbitrap spectra were consistent over a very wide concentration range (5 orders) with good match values against NIST (EI-quadrupole) spectra. The applicability for quantitative residue analysis was verified by validation of 54 pesticides in three matrices (tomato, leek, orange) at 10 and 50 μg/kg. The method involved a QuEChERS-based extraction with a solvent switch into iso-octane, and 1 μL hot splitless injection into the GC-HRMS system. A recovery between 70 and 120% and a repeatability RSD <10% was obtained in most cases. Linearity was demonstrated for the range ≤5–250 μg kg{sup −1}. The pesticides could be identified according to the applicable EU criteria for GC-HRMS (SANTE/11945/2015). GC-EI-full scan Orbitrap HRMS was found to be highly suited for quantitative pesticide residue analysis. The potential of qualitative screening to extend the scope makes it an attractive

  3. Evaluation of gas chromatography – electron ionization – full scan high resolution Orbitrap mass spectrometry for pesticide residue analysis

    International Nuclear Information System (INIS)

    Mol, Hans G.J.; Tienstra, Marc; Zomer, Paul

    2016-01-01

    Gas chromatography with electron ionization and full scan high resolution mass spectrometry with an Orbitrap mass analyzer (GC-EI-full scan Orbitrap HRMS) was evaluated for residue analysis. Pesticides in fruit and vegetables were taken as an example application. The relevant aspects for GC-MS based residue analysis, including the resolving power (15,000 to 120,000 FWHM at m/z 200), scan rate, dynamic range, selectivity, sensitivity, analyte identification, and utility of existing EI-libraries, are assessed and discussed in detail. The optimum acquisition conditions in full scan mode (m/z 50–500) were a resolving power of 60,000 and an automatic-gain-control target value of 3E6. These conditions provided (i) an optimum mass accuracy: within 2 ppm over a wide concentration range, with/without matrix, enabling the use of ±5 ppm mass extraction windows (ii) adequate scan speed: minimum 12 scans/peak, (iii) an intra-scan dynamic range sufficient to achieve LOD/LOQs ≤0.5 pg in fruit/vegetable matrices (corresponding to ≤0.5 μg kg"−"1) for most pesticides. EI-Orbitrap spectra were consistent over a very wide concentration range (5 orders) with good match values against NIST (EI-quadrupole) spectra. The applicability for quantitative residue analysis was verified by validation of 54 pesticides in three matrices (tomato, leek, orange) at 10 and 50 μg/kg. The method involved a QuEChERS-based extraction with a solvent switch into iso-octane, and 1 μL hot splitless injection into the GC-HRMS system. A recovery between 70 and 120% and a repeatability RSD <10% was obtained in most cases. Linearity was demonstrated for the range ≤5–250 μg kg"−"1. The pesticides could be identified according to the applicable EU criteria for GC-HRMS (SANTE/11945/2015). GC-EI-full scan Orbitrap HRMS was found to be highly suited for quantitative pesticide residue analysis. The potential of qualitative screening to extend the scope makes it an attractive alternative to

  4. Divergent Field Annular Ion Engine, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed work investigates an approach that would allow an annular ion engine geometry to achieve ion beam currents approaching the Child-Langmuir limit. In this...

  5. Radial dynamics of an annular REB plasma

    International Nuclear Information System (INIS)

    Wilson, A.; Steen, P.G.; Waisman, E.M.

    1983-01-01

    The authors have examined the dynamics of annular plasma formed by a ring REB. A current is carried by an annular plasma shell and the current returns on two conducting concentric sleeves. The magnetic forces acting on the plasma tend to prevent it from pinching as the unperturbed magnetic field has a different sign on the two free surfaces (sides) of the plasma. Current flows through the plasma from cathode to anode and returns through the concentric inner and outer conductors

  6. Annular pancreas in adult: a case report

    International Nuclear Information System (INIS)

    Moreira Neto, M.

    1992-01-01

    A case of a patient complaining of recurrent symptomatology of the upper abdomen and sub occlusion of the gastrointestinal tract with stenosis of the second portion of duodenum and mass evolving the head of pancreas at echographic study, confirmed by CT is presented. Contrasted oral studies confirmed that the mass evolved the stenotic segment, suggesting annular pancreas. Surgery confirmed the presence of annular pancreas surrounding the second portion of duodenum. (author)

  7. Development of annular coupled structure

    International Nuclear Information System (INIS)

    Kageyama, T.; Morozumi, Y.; Yoshino, K.; Yamazaki, Y.

    1992-01-01

    A π/2-mode standing-wave linac of an Annular Coupled Structure (ACS) has been developed for the 1-GeV proton linac of the Japanese Hadron Project (JHP). This ACS has four coupling slots between accelerating and coupling cells in order to overcome difficulties in putting the ACS to practical use. Two prototypes of a four-slot ACS (f = 1296 MHz, β = v/c = 0.8) have been constructed and tested: one with a staggered slot-orientation from cell to cell; and the other with a uniform one. The staggered configuration gives a larger coupling constant and a larger shunt impedance than the uniform one with the same size of coupling slot. Both models have been conditioned up to the design input RF power. The four-slot ACS gives a distortion-free accelerating field around the beam axis, while a Side-Coupled Structure cavity gives an accelerating field mixed with a TE111-like mode. (Author) 7 figs., 2 tabs., 9 refs

  8. Method of making an aero-derivative gas turbine engine

    Science.gov (United States)

    Wiebe, David J.

    2018-02-06

    A method of making an aero-derivative gas turbine engine (100) is provided. A combustor outer casing (68) is removed from an existing aero gas turbine engine (60). An annular combustor (84) is removed from the existing aero gas turbine engine. A first row of turbine vanes (38) is removed from the existing aero gas turbine engine. A can annular combustor assembly (122) is installed within the existing aero gas turbine engine. The can annular combustor assembly is configured to accelerate and orient combustion gasses directly onto a first row of turbine blades of the existing aero gas turbine engine. A can annular combustor assembly outer casing (108) is installed to produce the aero-derivative gas turbine engine (100). The can annular combustor assembly is installed within an axial span (85) of the existing aero gas turbine engine vacated by the annular combustor and the first row of turbine vanes.

  9. Evaluation of a novel helium ionization detector within the context of (low-)flow modulation comprehensive two-dimensional gas chromatography.

    Science.gov (United States)

    Franchina, Flavio A; Maimone, Mariarosa; Sciarrone, Danilo; Purcaro, Giorgia; Tranchida, Peter Q; Mondello, Luigi

    2015-07-10

    The present research is focused on the use and evaluation of a novel helium ionization detector, defined as barrier discharge ionization detector (BID), within the context of (low-)flow modulation comprehensive two-dimensional gas chromatography (FM GC×GC). The performance of the BID device was compared to that of a flame ionization detector (FID), under similar FM GC×GC conditions. Following development and optimization of the FM GC×GC method, the BID was subjected to fine tuning in relation to acquisition frequency and discharge flow. Moreover, the BID performance was measured and compared to that of the FID, in terms of extra-column band broadening, sensitivity and dynamic range. The comparative study was carried out by using standard compounds belonging to different chemical classes, along with a sample of diesel fuel. Advantages and disadvantages of the BID system, also within the context of FM GC×GC, are critically discussed. In general, the BID system was characterized by a more limited dynamic range and increased sensitivity, compared to the FID. Additionally, BID and FID contribution to band broadening was found to be similar under the operational conditions applied. Particular attention was devoted to the behaviour of the FM GC×GC-BID system toward saturated and aromatic hydrocarbons, for a possible future use in the field of mineral-oil food contamination research. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Thermo-acoustic coupling in can-annular combustors : A numerical investigation

    NARCIS (Netherlands)

    Farisco, Federica; Panek, Lukasz; Kok, Jim B.W.; Pent, Jared; Rajaram, Rajesh

    2015-01-01

    Thermo-acoustic instabilities in modern, high power density gas turbines need to be predicted and understood in order to avoid unexpected damage and engine failure. While the annular combustor design is expected to suffer from the occurrence of transverse waves and burner-to-burner acoustic

  11. Resonance ionization and time-of-flight mass spectrometry for the analysis of trace substances in complex gas mixtures

    International Nuclear Information System (INIS)

    Nagel, Holger; Weickhardt, Christian; Boesl, Ulrich; Frey, Ruediger

    1995-01-01

    The analysis of mixtures of technical gases still comprises a lot of problems: the large number of components with very different and often rapidly varying concentrations makes great demands on analytical methods. By use of conventional analytical methods, signals of trace substances may interfere with signals of main components, whereas small signals representing low concentrations are covered by signals of main substances.The resonant-enhanced multiphoton ionization (REMPI) makes use of excited intermediate states of molecules. As these states are characteristic of each substance, one or more components of interest can be ionized with high efficiency without interference of other molecules by using a special laser-wavelength. The combination of the above mentioned ionization method with a reflectron time-of-flight mass spectrometer permits a very fast and sensitive detection of preselected trace substances.As ionization processes of higher order strongly depend on the laser intensity, there is no direct relation between ion signals and concentrations of exhaust components. Quantitative assessments are based on an especially developed calibration technique that makes use of internal standards. Applied under environmental aspects, this new analytical method helps to analyze a large number of components extracted from exhaust gases of combustion engines with high time resolution (<20 ms motor synchronously), high sensitivity (1 ppm) and high quantitative accuracy (more than 10%). A preliminary list of detectable compounds contains 30 substances

  12. The ATLAS3D project - X. On the origin of the molecular and ionized gas in early-type galaxies

    NARCIS (Netherlands)

    Davis, Timothy A.; Alatalo, Katherine; Sarzi, Marc; Bureau, Martin; Young, Lisa M.; Blitz, Leo; Serra, Paolo; Crocker, Alison F.; Krajnović, Davor; McDermid, Richard M.; Bois, Maxime; Bournaud, Frédéric; Cappellari, Michele; Davies, Roger L.; Duc, Pierre-Alain; de Zeeuw, P. Tim; Emsellem, Eric; Khochfar, Sadegh; Kuntschner, Harald; Lablanche, Pierre-Yves; Morganti, Raffaella; Naab, Thorsten; Oosterloo, Tom; Scott, Nicholas; Weijmans, Anne-Marie

    2011-01-01

    We make use of interferometric CO and H I observations, and optical integral-field spectroscopy from the ATLAS3D survey, to probe the origin of the molecular and ionized interstellar medium (ISM) in local early-type galaxies. We find that 36 ± 5 per cent of our sample of fast-rotating early-type

  13. The ATLAS3D project : X. On the origin of the molecular and ionized gas in early-type galaxies

    NARCIS (Netherlands)

    Davis, Timothy A.; Alatalo, Katherine; Sarzi, Marc; Bureau, Martin; Young, Lisa M.; Blitz, Leo; Serra, Paolo; Crocker, Alison F.; Krajnovic, Davor; McDermid, Richard M.; Bois, Maxime; Bournaud, Frederic; Cappellari, Michele; Davies, Roger L.; Duc, Pierre-Alain; de Zeeuw, P. Tim; Emsellem, Eric; Khochfar, Sadegh; Kuntschner, Harald; Lablanche, Pierre-Yves; Morganti, Raffaella; Naab, Thorsten; Oosterloo, Tom; Scott, Nicholas; Weijmans, Anne-Marie

    2011-01-01

    We make use of interferometric CO and H i observations, and optical integral-field spectroscopy from the ATLAS3D survey, to probe the origin of the molecular and ionized interstellar medium (ISM) in local early-type galaxies. We find that 36 +/- 5 per cent of our sample of fast-rotating early-type

  14. IONIZED GAS KINEMATICS AT HIGH RESOLUTION. V. [Ne ii], MULTIPLE CLUSTERS, HIGH EFFICIENCY STAR FORMATION, AND BLUE FLOWS IN HE 2–10

    International Nuclear Information System (INIS)

    Beck, Sara; Turner, Jean; Lacy, John; Greathouse, Thomas

    2015-01-01

    We measured the 12.8 μm [Ne ii] line in the dwarf starburst galaxy He 2–10 with the high-resolution spectrometer TEXES on the NASA IRTF. The data cube has a diffraction-limited spatial resolution of ∼1″ and a total velocity resolution, including thermal broadening, of ∼5 km s −1 . This makes it possible to compare the kinematics of individual star-forming clumps and molecular clouds in the three dimensions of space and velocity, and allows us to determine star formation efficiencies. The kinematics of the ionized gas confirm that the starburst contains multiple dense clusters. From the M/R of the clusters and the ≃30%–40% star formation efficiencies, the clusters are likely to be bound and long lived, like globulars. Non-gravitational features in the line profiles show how the ionized gas flows through the ambient molecular material, as well as a narrow velocity feature, which we identify with the interface of the H ii region and a cold dense clump. These data offer an unprecedented view of the interaction of embedded H ii regions with their environment

  15. Application of gas chromatography/flame ionization detector-based metabolite fingerprinting for authentication of Asian palm civet coffee (Kopi Luwak).

    Science.gov (United States)

    Jumhawan, Udi; Putri, Sastia Prama; Yusianto; Bamba, Takeshi; Fukusaki, Eiichiro

    2015-11-01

    Development of authenticity screening for Asian palm civet coffee, the world-renowned priciest coffee, was previously reported using metabolite profiling through gas chromatography/mass spectrometry (GC/MS). However, a major drawback of this approach is the high cost of the instrument and maintenance. Therefore, an alternative method is needed for quality and authenticity evaluation of civet coffee. A rapid, reliable and cost-effective analysis employing a universal detector, GC coupled with flame ionization detector (FID), and metabolite fingerprinting has been established for discrimination analysis of 37 commercial and non-commercial coffee beans extracts. gas chromatography/flame ionization detector (GC/FID) provided higher sensitivity over a similar range of detected compounds than GC/MS. In combination with multivariate analysis, GC/FID could successfully reproduce quality prediction from GC/MS for differentiation of commercial civet coffee, regular coffee and coffee blend with 50 wt % civet coffee content without prior metabolite details. Our study demonstrated that GC/FID-based metabolite fingerprinting can be effectively actualized as an alternative method for coffee authenticity screening in industries. Copyright © 2015. Published by Elsevier B.V.

  16. Partially ionized gas flow and heat transfer in the separation, reattachment, and redevelopment regions downstream of an abrupt circular channel expansion.

    Science.gov (United States)

    Back, L. H.; Massier, P. F.; Roschke, E. J.

    1972-01-01

    Heat transfer and pressure measurements obtained in the separation, reattachment, and redevelopment regions along a tube and nozzle located downstream of an abrupt channel expansion are presented for a very high enthalpy flow of argon. The ionization energy fraction extended up to 0.6 at the tube inlet just downstream of the arc heater. Reattachment resulted from the growth of an instability in the vortex sheet-like shear layer between the central jet that discharged into the tube and the reverse flow along the wall at the lower Reynolds numbers, as indicated by water flow visualization studies which were found to dynamically model the high-temperature gas flow. A reasonably good prediction of the heat transfer in the reattachment region where the highest heat transfer occurred and in the redevelopment region downstream can be made by using existing laminar boundary layer theory for a partially ionized gas. In the experiments as much as 90 per cent of the inlet energy was lost by heat transfer to the tube and the nozzle wall.

  17. Potential of atmospheric pressure chemical ionization source in gas chromatography tandem mass spectrometry for the screening of urinary exogenous androgenic anabolic steroids.

    Science.gov (United States)

    Raro, M; Portolés, T; Pitarch, E; Sancho, J V; Hernández, F; Garrostas, L; Marcos, J; Ventura, R; Segura, J; Pozo, O J

    2016-02-04

    The atmospheric pressure chemical ionization (APCI) source for gas chromatography-mass spectrometry analysis has been evaluated for the screening of 16 exogenous androgenic anabolic steroids (AAS) in urine. The sample treatment is based on the strategy currently applied in doping control laboratories i.e. enzymatic hydrolysis, liquid-liquid extraction (LLE) and derivatization to form the trimethylsilyl ether-trimethylsilyl enol ether (TMS) derivatives. These TMS derivatives are then analyzed by gas chromatography tandem mass spectrometry using a triple quadrupole instrument (GC-QqQ MS/MS) under selected reaction monitoring (SRM) mode. The APCI promotes soft ionization with very little fragmentation resulting, in most cases, in abundant [M + H](+) or [M + H-2TMSOH](+) ions, which can be chosen as precursor ions for the SRM transitions, improving in this way the selectivity and sensitivity of the method. Specificity of the transitions is also of great relevance, as the presence of endogenous compounds can affect the measurements when using the most abundant ions. The method has been qualitatively validated by spiking six different urine samples at two concentration levels each. Precision was generally satisfactory with RSD values below 25 and 15% at the low and high concentration level, respectively. Most the limits of detection (LOD) were below 0.5 ng mL(-1). Validation results were compared with the commonly used method based on the electron ionization (EI) source. EI analysis was found to be slightly more repeatable whereas lower LODs were found for APCI. In addition, the applicability of the developed method has been tested in samples collected after the administration of 4-chloromethandienone. The highest sensitivity of the APCI method for this compound, allowed to increase the period in which its administration can be detected. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Transport processes in ionized gases

    International Nuclear Information System (INIS)

    Kremer, G.M.

    1997-01-01

    Based on kinetic theory of gases and on the combined of Chapman-Enskog and Grad, the laws of Ohm, Fourier and Navier-Stokes are derived for a non-relativistic fully ionized gas. Moreover, the combined method is applied to the BGK model of the relativistic Boltzmann equation and the Ohm's law is derived for a relativistic fully ionized gas. (author)

  19. Effects of roll waves on annular flow heat transfer at horizontal condenser tube

    International Nuclear Information System (INIS)

    Kondo, Masaya; Nakamura, Hideo; Anoda, Yoshinari; Sakashita, Akihiro

    2002-01-01

    Heat removal characteristic of a horizontal in-tube condensation heat exchanger is under investigation to be used for a passive containment cooling system (PCCS) of a next generation-type BWR. Flow regime observed at the inlet of the condenser tube was annular flow, and the local heat transfer rate was ∼20% larger than the prediction by the Dobson-Chato correlation. Roll waves were found to appear on the liquid film in the annular flow. The measured local condensation heat transfer rate was being closely related to the roll waves frequency. Based on these observations, a model is proposed which predicts the condensation heat transfer coefficient for annular flows around the tube inlet. The proposed model predicts well the influences of pressure, local gas-phase velocity and film thickness. (author)

  20. Droplet behavior analysis in consideration of droplet entrainment from liquid film in annular dispersed flow

    International Nuclear Information System (INIS)

    Matsuura, Keizo; Otake, Hiroshi; Kataoka, Isao; Serizawa, Akimi

    2000-01-01

    A method of droplet behavior simulation in an annular dispersed flow has been developed. In this method, both droplet deposition and entrainment from liquid film are considered. The Lagrangian method and stochastic model are used to analyze droplet diffusion and deposition behavior in a turbulent flow, and droplet entrainment from liquid film is calculated by an entrainment correlation. For the verification of this method, Gill's experiment is analyzed, in which the transition from annular flow with no entrainment to equilibrium annular dispersed flow was observed. Analysis results can also show the similar transition tendency. The experimental results of radial distribution of droplet mass flux are compared with analysis results. The agreement is good for low liquid flow rate, but entrainment rate must be adjusted for high liquid flow rate, in which gas turbulence is thought to be modified by high droplet density. In future work the effect of high droplet density on turbulence should be considered. (author)

  1. Numerical simulation and experimental research for the natural convection in an annular space in LMFBR

    International Nuclear Information System (INIS)

    Wang Zhou; Luo Rui; Yang Xianyong; Liang Taofeng

    1999-01-01

    In a pool fast reactor, the roof structure is penetrated by a number of pumps and heat exchanger units to form some annular spaces with various sizes. The natural convection of argon gas happens in the pool sky and the small annular gaps between those components and the roof containment due to thermosiphonic effects. The natural convection is studied experimentally and numerically to predict the temperature distributions inside the annular space and its surrounding structure. Numerical simulation is performed by using LVEL turbulence model and extending computational domain to the entire pool sky. The predicted results are in fair agreement with the experimental data. In comparison with commonly used k-ε model, LVEL model has better accuracy for the turbulent flow in a gap space

  2. Gas-phase copper and silver complexes with phosphorothioate and phosphorodithioate pesticides investigated using electrospray ionization mass spectrometry.

    Science.gov (United States)

    Mustapha, Adetayo M; Pasilis, Sofie P

    2015-01-01

    Efforts to improve agricultural productivity have led to a growing dependency on organophosphorus pesticides. Phosphorothioate and phosphorodithioate pesticides are organophosphorus pesticide subclasses with widespread application for the control of insects feeding on vegetables and fruits. However, even low doses of these pesticides can cause neurological problems in humans; thus, their determination and monitoring in agricultural foodstuffs is important for human health. Phosphorothioate and phosphorodithioate pesticides may be poorly ionized during electrospray, adversely affecting limits of detection. These pesticides can form complexes with Cu(2+) and Ag(+) , however, potentially improving ionization. In the present work, we used electrospray ionization/mass spectrometry (ESI/MS) to study fenitrothion, parathion, diazinon, and malathion coordination complexes with silver and copper ions. Stable 1 : 1 and 1 : 2 metal/pesticide complexes were detected. Mass spectra acquired from pesticide solutions containing Ag(+) or Cu(2+) showed a significant increase in signal-to-background ratio over those acquired from solutions containing only the pesticides, with Ag(+) improving detection more effectively than Cu(2+). Addition of Ag(+) to a pesticide solution improved the limit of detection by ten times. The relative affinity of each pesticide for Ag(+) was related to complex stability, following the order diazinon > malathion > fenitrothion > parathion. The formation of Ag(+)-pesticide complexes can significantly improve the detection of phosphorothioate and phosphorodithioate pesticides using ESI/MS. The technique could potentially be used in reactive desorption electrospray ionization/mass spectrometry to detect phosphorothioate and phosphorodithioate pesticides on fruit and vegetable skins. Copyright © 2015 John Wiley & Sons, Ltd.

  3. SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

    Energy Technology Data Exchange (ETDEWEB)

    Bizyaev, D.; Pan, K.; Brinkmann, J. [Apache Point Observatory and New Mexico State University, Sunspot, NM 88349 (United States); Walterbos, R. A. M. [Department of Astronomy, New Mexico State University, Las Cruces, NM 88003 (United States); Yoachim, P. [Department of Astronomy, University of Washington, Seattle, WA 98195 (United States); Riffel, R. A. [Departamento de Física, CCNE, Universidade Federal de Santa Maria, Av. Roraima, 1000-97105-900, Santa Maria, RS (Brazil); Fernández-Trincado, J. G. [Institut Utinam, CNRS UMR 6213, Université de Franche-Comté, OSU THETA Franche-Comté-Bourgogne, Observatoire de Besançon, BP 1615, F-25010 Besançon Cedex (France); Diamond-Stanic, A. M. [Department of Astronomy, University of Wisconsin-Madison, Madison, WI 53706 (United States); Jones, A. [Max-Planck Institute for Astrophysics, Karl-Schwarzschild-Str 1, Garching, D-85748 (Germany); Thomas, D. [Institute of Cosmology and Gravitation, University of Portsmouth, Dennis Sciama Building, Portsmouth PO1 3FX (United Kingdom); Cleary, J. [Department of Physics and Astronomy, Johns Hopkins University, Bloomberg Center, 3400 North Charles Street, Baltimore, MD 21218 (United States)

    2017-04-20

    We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed H α emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

  4. SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

    International Nuclear Information System (INIS)

    Bizyaev, D.; Pan, K.; Brinkmann, J.; Walterbos, R. A. M.; Yoachim, P.; Riffel, R. A.; Fernández-Trincado, J. G.; Diamond-Stanic, A. M.; Jones, A.; Thomas, D.; Cleary, J.

    2017-01-01

    We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed H α emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

  5. SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

    Science.gov (United States)

    Bizyaev, D.; Walterbos, R. A. M.; Yoachim, P.; Riffel, R. A.; Fernández-Trincado, J. G.; Pan, K.; Diamond-Stanic, A. M.; Jones, A.; Thomas, D.; Cleary, J.; Brinkmann, J.

    2017-04-01

    We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed Hα emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

  6. Damping of cylindrical structures subject to annular flow

    International Nuclear Information System (INIS)

    Hobson, D.E.; Dolding, M.

    1989-01-01

    In previous reports theoretical methods have been described for estimating the aerodynamic forces acting on cylinders vibrating laterally when surrounded by an annulus carrying high velocity gas. For a certain restricted set of geometries it is possible to predict whether a particular structure is stable or unstable and to determine the level of aerodynamic damping positive or negative due to the presence of the gas. This report describes experimental work which validates the computer program in which the theoretical methods are embodied; in particular the damping, inertial and decentralising forces acting on a cylinder in an annulus are measured and compared with theory over a range of frequencies from 0 to 25 Hz, and of Reynolds numbers from zero to 10 4 . In addition a summary of simple relationships is provided which can be used to provide credible initial estimates of both the positive and negative damping of cylinders in a range of annular geometries. (author)

  7. Aceclofenac-induced erythema annulare centrifugum

    Directory of Open Access Journals (Sweden)

    Dilip Meena

    2018-01-01

    Full Text Available Erythema annulare centrifugum (EAC is characterised by slowly enlarging annular erythematous lesions and is thought to represent a clinical reaction pattern to infections, medications, and rarely, underlying malignancy. Causative drugs include chloroquine, cimetidine, gold sodium thiomalate, amitriptyline, finasteride, etizolam etc. We present a case of 40-year-old woman who presented to us with a 10 days history of nonpruritic, peripherally growing annular erythematous eruption. She had a history of recent onset of joint pain, for which she was taking aceclofenac 90 mg once a day for 5 days prior to the onset of the rash. This was confirmed on biopsy as EAC. The rash promptly subsided after stopping the drug. We report this case as there was no previous report of aceclofenac induced EAC.

  8. Miniature ionization chamber

    International Nuclear Information System (INIS)

    Alexeev, V.I.; Emelyanov, I.Y.; Ivanov, V.M.; Konstantinov, L.V.; Lysikov, B.V.; Postnikov, V.V.; Rybakov, J.V.

    1976-01-01

    A miniature ionization chamber having a gas-filled housing which accommodates a guard electrode made in the form of a hollow perforated cylinder is described. The cylinder is electrically associated with the intermediate coaxial conductor of a triaxial cable used as the lead-in of the ionization chamber. The gas-filled housing of the ionization chamber also accommodates a collecting electrode shaped as a rod electrically connected to the center conductor of the cable and to tubular members. The rod is disposed internally of the guard electrode and is electrically connected, by means of jumpers passing through the holes in the guard electrode, to the tubular members. The tubular members embrace the guard electrode and are spaced a certain distance apart along its entire length. Arranged intermediate of these tubular members are spacers secured to the guard electrode and fixing the collecting electrode throughout its length with respect to the housing of the ionization chamber

  9. Critical heat fluxes and liquid distribution in annular channels in the dispersion-annular flow

    International Nuclear Information System (INIS)

    Boltenko, Eh.A.; Pomet'ko, R.S.

    1984-01-01

    On the basis of using the dependence of intensity of total mass transfer between the flux nucleus and wall film obtained for tubes with uniform heat release and taking into account the peculiarities of mass transfer between the flux nucleus and wall film in annular channels the technique for calculating the liquid distribution and critical capacity of annular channels with internal, external and bilateral heating at uniform and non-uniform heat release over the length is proposed. The calculation of annular channels critical capacity according to the suggested technique is performed. A satisfactory agreement of calculation results with the experimental data is attained

  10. Ionization and breakdown of a low-density gas by a low-current nonrelativistic electron beam

    International Nuclear Information System (INIS)

    Alanakyan, Yu.R.; Shternov, N.P.

    1991-01-01

    In the present paper the authors study a plasma formed near a steady-state electron beam traveling in an unbounded low-pressure gas. Beam parameters below and at the breakdown threshold are considered, and the threshold beam parameters corresponding to gas breakdown with formation of a beam-plasma discharge are calculated. Theoretical studies of electron beam propagation in an unbounded gas are of interest in connection with rocket-borne atmospheric experiments laboratory investigations, and observations of natural phenomena in the upper atmosphere (aurora borealis and related phenomena)

  11. Resonance ionization and time-of-flight mass spectrometry for the analysis of trace substances in complex gas mixtures

    International Nuclear Information System (INIS)

    Nagel, H.; Weickhardt, C.; Boesl, U.; Frey, R.

    1995-01-01

    As ionization processes of higher order strongly depend on the laser intensity, there is no direct relation between ion signals and concentrations of exhaust components. Quantitative assessments are based on an especially developed calibration technique that makes use of internal standards. Applied under environmental aspects, this new analytical method helps to analyze a large number of components extracted from exhaust gases of combustion engines with high time resolution (<20 ms motor synchronously), high sensitivity (1 ppm) and high quantitative accuracy (more than 10%). A preliminary list of detectable compounds contains 30 substances. copyright 1995 American Institute of Physics

  12. Optimal Thrust Vectoring for an Annular Aerospike Nozzle, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Recent success of an annular aerospike flight test by NASA Dryden has prompted keen interest in providing thrust vector capability to the annular aerospike nozzle...

  13. Ionization particle detector

    International Nuclear Information System (INIS)

    Ried, L.

    1982-01-01

    A new device is claimed for detecting particles in a gas. The invention comprises a low cost, easy to assemble, and highly accurate particle detector using a single ionization chamber to contain a reference region and a sensing region. The chamber is designed with the radioactive source near one electrode and the second electrode located at a distance less than the distance of maximum ionization from the radioactive source

  14. The simultaneous separation and determination of chloropropanols in soy sauce and other flavoring with gas chromatography-mass spectrometry in negative chemical and electron impact ionization modes.

    Science.gov (United States)

    Xu, Xiaomin; Ren, Yiping; Wu, Pinggu; Han, Jianlong; Shen, Xianghong

    2006-02-01

    Both gas chromatography-mass spectrometry in electron ionization (GC-MS-EI) and negative chemical ionization (GC-MS-NCI) modes are reported in this paper for the simultaneous determination of 1,3-dichloropropan-2-ol (1,3-DCP), 2,3-dichloropropan-1-ol (2,3-DCP), 3-chloropropane-1,2-diol (3-MCPD) and 2-chloropropane-1,3-diol (2-MCPD) in soy sauce and other flavoring. D(5)-3-MCPD (for 3-MCPD and 2-MCPD) and d(5)-1,3-DCP (for 1,3-DCP and 2,3-DCP) were used as the deuterium isotopic labelled internal standards. The feasibility of using heptafluorobutyric anhydride modified with triethylamine (HFBA-Et(3)N) as a new derivatization reagent to replace heptafluorobutyrylimidazole (HFBI) is proposed. Liquid/liquid extraction with hexane was introduced for high lipid content samples. A small survey was carried out of soy sauces (103 samples) and instant noodles (45 samples) and the applicability of GC-MS-NCI and GC-MS-EI was assessed in these different matrices.

  15. Quantification of isomerically summed hydrocarbon contributions to crude oil by carbon number, double bond equivalent, and aromaticity using gas chromatography with tunable vacuum ultraviolet ionization.

    Science.gov (United States)

    Nowak, Jeremy A; Weber, Robert J; Goldstein, Allen H

    2018-03-12

    The ability to structurally characterize and isomerically quantify crude oil hydrocarbons relevant to refined fuels such as motor oil, diesel, and gasoline represents an extreme challenge for chromatographic and mass spectrometric techniques. This work incorporates two-dimensional gas chromatography coupled to a tunable vacuum ultraviolet soft photoionization source, the Chemical Dynamics Beamline 9.0.2 of the Advanced Light Source at the Lawrence Berkeley National Laboratory, with a time-of-flight mass spectrometer (GC × GC-VUV-TOF) to directly characterize and isomerically sum the contributions of aromatic and aliphatic species to hydrocarbon classes of four crude oils. When the VUV beam is tuned to 10.5 ± 0.2 eV, both aromatic and aliphatic crude oil hydrocarbons are ionized to reveal the complete chemical abundance of C 9 -C 30 hydrocarbons. When the VUV beam is tuned to 9.0 ± 0.2 eV only aromatic hydrocarbons are ionized, allowing separation of the aliphatic and aromatic fractions of the crude oil hydrocarbon chemical classes in an efficient manner while maintaining isomeric quantification. This technique provides an effective tool to determine the isomerically summed aromatic and aliphatic hydrocarbon compositions of crude oil, providing information that goes beyond typical GC × GC separations of the most dominant hydrocarbon isomers.

  16. Effect of annular secondary conductor in a linear electromagnetic ...

    Indian Academy of Sciences (India)

    This paper presents the variation of average axial force density in the annular secondary conductor of a linear electromagnetic stirrer. Different geometries of secondaries are considered for numerical and experimental validation namely, 1. hollow annular ring, 2. annular ring with a solid cylinder and 3. solid cylinder.

  17. Rapid analysis of ethanol and water in commercial products using ionic liquid capillary gas chromatography with thermal conductivity detection and/or barrier discharge ionization detection.

    Science.gov (United States)

    Weatherly, Choyce A; Woods, Ross M; Armstrong, Daniel W

    2014-02-26

    Analysis of ethanol and water in consumer products is important in a variety of processes and often is mandated by regulating agencies. A method for the simultaneous quantitation of ethanol and water that is simple, accurate, precise, rapid, and cost-effective is demonstrated. This approach requires no internal standard for the quantitation of both ethanol and water at any/all levels in commercial products. Ionic liquid based gas chromatography (GC) capillary columns are used to obtain a fast analysis with high selectivity and resolution of water and ethanol. Typical run times are just over 3 min. Examination of the response range of water and ethanol with GC, thermal conductivity detection (TCD), and barrier ionization detection (BID) is performed. Quantitation of both ethanol and water in consumer products is accomplished with both TCD and BID GC detectors using a nonlinear calibration. Validation of method accuracy is accomplished by using standard reference materials.

  18. Common pass decentered annular ring resonator

    Energy Technology Data Exchange (ETDEWEB)

    Holmes, D. A.; Waite, T. R.

    1985-04-30

    An optical resonator having an annular cylindrical gain region for use in a chemical laser or the like in which two ring-shaped mirrors having substantially conical reflecting surfaces are spaced apart along a common axis of revolution of the respective conical surfaces. A central conical mirror reflects incident light directed along said axis radially outwardly to the reflecting surface of a first one of the ring-shaped mirrors. The radial light rays are reflected by the first ring mirror to the second ring mirror within an annular cylindrical volume concentric with said common axis and forming a gain region. Light rays impinging on the second ring mirror are reflected to diametrically opposite points on the same conical mirror surfaces and back to the first ring mirror through the same annular cylindrical volume. The return rays are then reflected by the conical mirror surface of the first ring mirror back to the central conical mirror. The mirror surfaces are angled such that the return rays are reflected back along the common axis by the central mirror in a concentric annular cylindrical volume. A scraper mirror having a central opening centered on said axis and an offset opening reflects all but the rays passing through the two openings in an output beam. The rays passing through the second opening are reflected back through the first opening to provide feedback.

  19. [A rare form of granuloma annulare].

    Science.gov (United States)

    Bogdanowski, T; Wygledowska-Kania, M

    1995-01-01

    We present a four-year-old girl with a doubly rare form of granuloma annulare with non-typical localisation of superficial nodules on the palms and predisposition to ulceration which is very rare in this type of superficial nodules. The diagnosis was proved by histological examination. After the local cryotherapy (ethyl chloride) the lesions almost completely disappeared.

  20. Periduodenal Tuberculosis masquerading as Annular Pancreas ...

    African Journals Online (AJOL)

    We report a patient who succumbed to an isolated mid duodenal tuberculosis, diagnosed at laparatomy, whose clinical presentation, endoscopy and computerised tomography scans resembled annular pancreas. The limitations of clinical evaluation, endoscopy and radiology are highlighted as the importance of diagnostic ...

  1. Geometric size optimization and behavior analysis of a dual-cooled annular fuel

    International Nuclear Information System (INIS)

    Deng Yangbin; Wu Yingwei; Zhang Dalin; Tian Wenxi; Qiu Suizheng; Su Guanghui; Zhang Weixu; Wu Junmei

    2014-01-01

    The dual-cooled annular fuel is one of the innovative fuel concepts, which allows substantial power density increase while maintaining safety margins comparing with that used in currently operating PWRs. In this study, a thermal-hydraulic calculation code, on the basis of inner and outer cooling balance theory, was independently developed to optimize the geometric size of dual-cooled annular fuel elements. The optimization results show that the fuel element with the optimal geometric sizes presents fantastic symmetry in temperature distribution. The optimized geometric sizes agree well with the sizes obtained by MIT (Massachusetts Institute of Technology), which on the other side validates the code reliability and accuracy as well. In addition, a thermo-mechanical-burnup coupling code was developed to study the thermodynamic and mechanical characteristics of fuel elements with considering the irradiation and burnup effects. This coupling program was applied to perform the behavior analysis of annular fuels. The calculation results show that, when the power density increases on the order of up to 50%, the dual-cooled annular fuel elements have much lower fuel temperature and much less fission gas release comparing with conventional fuel rods. Furthermore, the results indicate that the thicknesses of inner and outer gas gap cannot remain the same with the burnup increasing due to the mechanical deformations of fuel pellets and claddings, which results in significantly asymmetric temperature distribution especially at the last phase of burnup. (author)

  2. Ionization front accelerator

    International Nuclear Information System (INIS)

    Olson, C.L.

    1975-01-01

    In a recently proposed linear collective accelerator, ions are accelerated in a steep, moving potential well created at the head of an intense relativistic electron beam. The steepness of the potential well and its motion are controlled by the external ionization of a suitable background gas. Calculations concerning optimum choices for the background gas and the ionization method are presented; a two-step photoionization process employing Cs vapor is proposed. In this process, a super-radiant light source is used to excite the gas, and a UV laser is used to photoionize the excited state. The appropriate line widths and coupled ionization growth rate equations are discussed. Parameter estimates are given for a feasibility experiment, for a 1 GeV proton accelerator, and for a heavy ion accelerator (50 MeV/nucleon uranium). (auth)

  3. Use of a hand-portable gas chromatograph-toroidal ion trap mass spectrometer for self-chemical ionization identification of degradation products related to O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX)

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Philip A., E-mail: Smith.Philip.A@dol.gov [Uniformed Services University of the Health Sciences, Department of Preventive Medicine and Biometrics, 4301 Jones Bridge Road, Bethesda, MD, 20814 (United States); Lepage, Carmela R. Jackson [Defence R and D Canada - Suffield, Box 400, Station Main, Medicine Hat, Alberta, T1A 8K6 (Canada); Savage, Paul B. [Brigham Young University, Department of Chemistry and Biochemistry, Provo, UT, 84602 (United States); Bowerbank, Christopher R.; Lee, Edgar D. [Torion Technologies Inc., 796 East Utah Valley Drive, Suite 200, American Fork, UT, 84003 (United States); Lukacs, Michael J. [Defence R and D Canada - Suffield, Box 400, Station Main, Medicine Hat, Alberta, T1A 8K6 (Canada)

    2011-04-01

    The chemical warfare agent O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX) and many related degradation products produce poorly diagnostic electron ionization (EI) mass spectra by transmission quadrupole mass spectrometry. Thus, chemical ionization (CI) is often used for these analytes. In this work, pseudomolecular ([M+H]{sup +}) ion formation from self-chemical ionization (self-CI) was examined for four VX degradation products containing the diisopropylamine functional group. A person-portable toroidal ion trap mass spectrometer with a gas chromatographic inlet was used with EI, and both fixed-duration and feedback-controlled ionization time. With feedback-controlled ionization, ion cooling (reaction) times and ion formation target values were varied. Evidence for protonation of analytes was observed under all conditions, except for the largest analyte, bis(diisopropylaminoethyl)disulfide which yielded [M+H]{sup +} ions only with increased fixed ionization or ion cooling times. Analysis of triethylamine-d{sub 15} provided evidence that [M+H]{sup +} production was likely due to self-CI. Analysis of a degraded VX sample where lengthened ion storage and feedback-controlled ionization time were used resulted in detection of [M+H]{sup +} ions for VX and several relevant degradation products. Dimer ions were also observed for two phosphonate compounds detected in this sample.

  4. Use of a hand-portable gas chromatograph-toroidal ion trap mass spectrometer for self-chemical ionization identification of degradation products related to O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX)

    International Nuclear Information System (INIS)

    Smith, Philip A.; Lepage, Carmela R. Jackson; Savage, Paul B.; Bowerbank, Christopher R.; Lee, Edgar D.; Lukacs, Michael J.

    2011-01-01

    The chemical warfare agent O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX) and many related degradation products produce poorly diagnostic electron ionization (EI) mass spectra by transmission quadrupole mass spectrometry. Thus, chemical ionization (CI) is often used for these analytes. In this work, pseudomolecular ([M+H] + ) ion formation from self-chemical ionization (self-CI) was examined for four VX degradation products containing the diisopropylamine functional group. A person-portable toroidal ion trap mass spectrometer with a gas chromatographic inlet was used with EI, and both fixed-duration and feedback-controlled ionization time. With feedback-controlled ionization, ion cooling (reaction) times and ion formation target values were varied. Evidence for protonation of analytes was observed under all conditions, except for the largest analyte, bis(diisopropylaminoethyl)disulfide which yielded [M+H] + ions only with increased fixed ionization or ion cooling times. Analysis of triethylamine-d 15 provided evidence that [M+H] + production was likely due to self-CI. Analysis of a degraded VX sample where lengthened ion storage and feedback-controlled ionization time were used resulted in detection of [M+H] + ions for VX and several relevant degradation products. Dimer ions were also observed for two phosphonate compounds detected in this sample.

  5. Potential of atmospheric pressure chemical ionization source in gas chromatography tandem mass spectrometry for the screening of urinary exogenous androgenic anabolic steroids

    International Nuclear Information System (INIS)

    Raro, M.; Portolés, T.; Pitarch, E.; Sancho, J.V.; Hernández, F.; Garrostas, L.; Marcos, J.; Ventura, R.; Segura, J.; Pozo, O.J.

    2016-01-01

    The atmospheric pressure chemical ionization (APCI) source for gas chromatography-mass spectrometry analysis has been evaluated for the screening of 16 exogenous androgenic anabolic steroids (AAS) in urine. The sample treatment is based on the strategy currently applied in doping control laboratories i.e. enzymatic hydrolysis, liquid–liquid extraction (LLE) and derivatization to form the trimethylsilyl ether-trimethylsilyl enol ether (TMS) derivatives. These TMS derivatives are then analyzed by gas chromatography tandem mass spectrometry using a triple quadrupole instrument (GC-QqQ MS/MS) under selected reaction monitoring (SRM) mode. The APCI promotes soft ionization with very little fragmentation resulting, in most cases, in abundant [M + H] + or [M + H-2TMSOH] + ions, which can be chosen as precursor ions for the SRM transitions, improving in this way the selectivity and sensitivity of the method. Specificity of the transitions is also of great relevance, as the presence of endogenous compounds can affect the measurements when using the most abundant ions. The method has been qualitatively validated by spiking six different urine samples at two concentration levels each. Precision was generally satisfactory with RSD values below 25 and 15% at the low and high concentration level, respectively. Most the limits of detection (LOD) were below 0.5 ng mL −1 . Validation results were compared with the commonly used method based on the electron ionization (EI) source. EI analysis was found to be slightly more repeatable whereas lower LODs were found for APCI. In addition, the applicability of the developed method has been tested in samples collected after the administration of 4-chloromethandienone. The highest sensitivity of the APCI method for this compound, allowed to increase the period in which its administration can be detected. - Highlights: • APCI source has been evaluated for the screening of 16 exogenous AAS in urine. • Suitable precision was

  6. Potential of atmospheric pressure chemical ionization source in gas chromatography tandem mass spectrometry for the screening of urinary exogenous androgenic anabolic steroids

    Energy Technology Data Exchange (ETDEWEB)

    Raro, M.; Portolés, T.; Pitarch, E.; Sancho, J.V.; Hernández, F. [Research Institute for Pesticides and Water, University Jaume I, E-12071 Castellón (Spain); Garrostas, L. [Bioanalysis Research Group, IMIM, Hospital del Mar Medical Research Institute, Doctor Aiguader 88, 08003 Barcelona (Spain); Marcos, J.; Ventura, R.; Segura, J. [Bioanalysis Research Group, IMIM, Hospital del Mar Medical Research Institute, Doctor Aiguader 88, 08003 Barcelona (Spain); Department of Experimental and Health Sciencies, Universitat Pompeu Fabra, Doctor Aiguader 88, 08003 Barcelona (Spain); Pozo, O.J., E-mail: opozo@imim.es [Bioanalysis Research Group, IMIM, Hospital del Mar Medical Research Institute, Doctor Aiguader 88, 08003 Barcelona (Spain)

    2016-02-04

    The atmospheric pressure chemical ionization (APCI) source for gas chromatography-mass spectrometry analysis has been evaluated for the screening of 16 exogenous androgenic anabolic steroids (AAS) in urine. The sample treatment is based on the strategy currently applied in doping control laboratories i.e. enzymatic hydrolysis, liquid–liquid extraction (LLE) and derivatization to form the trimethylsilyl ether-trimethylsilyl enol ether (TMS) derivatives. These TMS derivatives are then analyzed by gas chromatography tandem mass spectrometry using a triple quadrupole instrument (GC-QqQ MS/MS) under selected reaction monitoring (SRM) mode. The APCI promotes soft ionization with very little fragmentation resulting, in most cases, in abundant [M + H]{sup +} or [M + H-2TMSOH]{sup +} ions, which can be chosen as precursor ions for the SRM transitions, improving in this way the selectivity and sensitivity of the method. Specificity of the transitions is also of great relevance, as the presence of endogenous compounds can affect the measurements when using the most abundant ions. The method has been qualitatively validated by spiking six different urine samples at two concentration levels each. Precision was generally satisfactory with RSD values below 25 and 15% at the low and high concentration level, respectively. Most the limits of detection (LOD) were below 0.5 ng mL{sup −1}. Validation results were compared with the commonly used method based on the electron ionization (EI) source. EI analysis was found to be slightly more repeatable whereas lower LODs were found for APCI. In addition, the applicability of the developed method has been tested in samples collected after the administration of 4-chloromethandienone. The highest sensitivity of the APCI method for this compound, allowed to increase the period in which its administration can be detected. - Highlights: • APCI source has been evaluated for the screening of 16 exogenous AAS in urine. • Suitable

  7. Through an Annular Turbine Nozzle

    Directory of Open Access Journals (Sweden)

    Rainer Kurz

    1995-01-01

    is located in the gas turbine. The experiments were performed using total pressure probes and wall static pressure taps. The pitch variation modifies the flow field both upstream and downstream of the nozzle, although the experiments show that the effect is localized to the immediate neighborhood of the involved blades. The effects on the wakes and on the inviscid flow are discussed separately. The mean velocities show a strong sensitivity to the changes of the pitch, which is due to a potential flow effect rather than a viscous effect.

  8. SDSS IV MaNGA: Deep observations of extra-planar, diffuse ionized gas around late-type galaxies from stacked IFU spectra

    Science.gov (United States)

    Jones, A.; Kauffmann, G.; D'Souza, R.; Bizyaev, D.; Law, D.; Haffner, L.; Bahé, Y.; Andrews, B.; Bershady, M.; Brownstein, J.; Bundy, K.; Cherinka, B.; Diamond-Stanic, A.; Drory, N.; Riffel, R. A.; Sánchez, S. F.; Thomas, D.; Wake, D.; Yan, R.; Zhang, K.

    2017-03-01

    We have conducted a study of extra-planar diffuse ionized gas using the first year data from the MaNGA IFU survey. We have stacked spectra from 49 edge-on, late-type galaxies as a function of distance from the midplane of the galaxy. With this technique we can detect the bright emission lines Hα, Hβ, [O II]λλ3726, 3729, [O III]λ5007, [N II]λλ6549, 6584, and [S II]λλ6717, 6731 out to about 4 kpc above the midplane. With 16 galaxies we can extend this analysis out to about 9 kpc, I.e. a distance of 2Re, vertically from the midplane. In the halo, the surface brightnesses of the [O II] and Hα emission lines are comparable, unlike in the disk where Hα dominates. When we split the sample by specific star-formation rate, concentration index, and stellar mass, each subsample's emission line surface brightness profiles and ratios differ, indicating that extra-planar gas properties can vary. The emission line surface brightnesses of the gas around high specific star-formation rate galaxies are higher at all distances, and the line ratios are closer to ratios characteristic of H II regions compared with low specific star-formation rate galaxies. The less concentrated and lower stellar mass samples exhibit line ratios that are more like H II regions at larger distances than their more concentrated and higher stellar mass counterparts. The largest difference between different subsamples occurs when the galaxies are split by stellar mass. We additionally infer that gas far from the midplane in more massive galaxies has the highest temperatures and steepest radial temperature gradients based on their [N II]/Hα and [O II]/Hα ratios between the disk and the halo. SDSS IV.

  9. An argon–nitrogen–hydrogen mixed-gas plasma as a robust ionization source for inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Makonnen, Yoseif; Beauchemin, Diane, E-mail: diane.beauchemin@chem.queensu.ca

    2014-09-01

    Multivariate optimization of an argon–nitrogen–hydrogen mixed-gas plasma for minimum matrix effects, while maintaining analyte sensitivity as much as possible, was carried out in inductively coupled plasma mass spectrometry. In the presence of 0.1 M Na, the 33.9 ± 3.9% (n = 13 elements) analyte signal suppression on average observed in an all-argon plasma was alleviated with the optimized mixed-gas plasma, the average being − 4.0 ± 8.8%, with enhancement in several cases. An addition of 2.3% v/v N{sub 2} in the outer plasma gas, and 0.50% v/v H{sub 2} to the central channel, as a sheath around the nebulizer gas flow, was sufficient for this drastic increase in robustness. It also reduced the background from ArO{sup +} and Ar{sub 2}{sup +} as well as oxide levels by over an order of magnitude. On the other hand, the background from NO{sup +} and ArN{sup +} increased by up to an order of magnitude while the levels of doubly-charged ions increased to 7% (versus 2.7% in an argon plasma optimized for sensitivity). Furthermore, detection limits were generally degraded by 5 to 15 fold when using the mixed-gas plasma versus the argon plasma for matrix-free solution (although they were better for several elements in 0.1 M Na). Nonetheless, the drastically increased robustness allowed the direct quantitative multielement analysis of certified ore reference materials, as well as the determination of Mo and Cd in seawater, without using any matrix-matching or internal standardization. - Highlights: • Addition of N{sub 2} to the plasma gas and H{sub 2} as a sheath gas results in a very robust ICP. • ArO{sup +} and Ar{sub 2}{sup +} background and oxide levels are reduced by over an order of magnitude. • Multielement analysis of rock digests is possible with a simple external calibration. • No internal standardization or matrix-matching is required for accurate analysis. • Cd and Mo were accurately determined in undiluted seawater.

  10. A Laboratory Experiment To Measure Henry's Law Constants of Volatile Organic Compounds with a Bubble Column and a Gas Chromatography Flame Ionization Detector (GC-FID)

    Science.gov (United States)

    Lee, Shan-Hu; Mukherjee, Souptik; Brewer, Brittany; Ryan, Raphael; Yu, Huan; Gangoda, Mahinda

    2013-01-01

    An undergraduate laboratory experiment is described to measure Henry's law constants of organic compounds using a bubble column and gas chromatography flame ionization detector (GC-FID). This experiment is designed for upper-division undergraduate laboratory courses and can be implemented in conjunction with physical chemistry, analytical…

  11. Lipids and Fatty Acids in Algae: Extraction, Fractionation into Lipid Classes, and Analysis by Gas Chromatography Coupled with Flame Ionization Detector (GC-FID).

    Science.gov (United States)

    Guihéneuf, Freddy; Schmid, Matthias; Stengel, Dagmar B

    2015-01-01

    Despite the number of biochemical studies exploring algal lipids and fatty acid biosynthesis pathways and profiles, analytical methods used by phycologists for this purpose are often diverse and incompletely described. Potential confusion and potential variability of the results between studies can therefore occur due to change of protocols for lipid extraction and fractionation, as well as fatty acid methyl esters (FAME) preparation before gas chromatography (GC) analyses. Here, we describe a step-by-step procedure for the profiling of neutral and polar lipids using techniques such as solid-liquid extraction (SLE), thin-layer chromatography (TLC), and gas chromatography coupled with flame ionization detector (GC-FID). As an example, in this protocol chapter, analyses of neutral and polar lipids from the marine microalga Pavlova lutheri (an EPA/DHA-rich haptophyte) will be outlined to describe the distribution of fatty acid residues within its major lipid classes. This method has been proven to be a reliable technique to assess changes in lipid and fatty acid profiles in several other microalgal species and seaweeds.

  12. Atmospheric measurements of gas-phase HNO3 and SO2 using chemical ionization mass spectrometry during the MINATROC field campaign 2000 on Monte Cimone

    Directory of Open Access Journals (Sweden)

    M. Hanke

    2003-01-01

    Full Text Available The EU-project MINATROC (MINeral dust And TROpospheric Chemistry aims at enabling an estimation of the influence of mineral dust, a major, but to date largely ignored component of tropospheric aerosol, on tropospheric oxidant cycles. Within the scope of this project continuous atmospheric measurements of gas-phase HNO3 and SO2 were conducted in June and July 2000 at the CNR WMO station, situated on Monte Cimone (MTC (44°11' N --10°42' E, 2165 m asl, Italy. African air transporting dust is occasionally advected over the Mediterranean Sea to the site, thus mineral aerosol emitted from Africa will encounter polluted air masses and provide ideal conditions to study their interactions. HNO3 and SO2 were measured with an improved CIMS (chemical ionization mass spectrometry system for ground-based measurements that was developed and built at MPI-K Heidelberg. Since HNO3  is a very sticky compound special care was paid for the air-sampling and background-measurement system. Complete data sets could be obtained before, during and after major dust intrusions. For the first time these measurements might provide a strong observational indication of efficient uptake of gas-phase HNO3 by atmospheric mineral-dust aerosol particles.

  13. Modeling of annular two-phase flow using a unified CFD approach

    Energy Technology Data Exchange (ETDEWEB)

    Li, Haipeng, E-mail: haipengl@kth.se; Anglart, Henryk, E-mail: henryk@kth.se

    2016-07-15

    Highlights: • Annular two-phase flow has been modeled using a unified CFD approach. • Liquid film was modeled based on a two-dimensional thin film assumption. • Both Eulerian and Lagrangian methods were employed for the gas core flow modeling. - Abstract: A mechanistic model of annular flow with evaporating liquid film has been developed using computational fluid dynamics (CFD). The model is employing a separate solver with two-dimensional conservation equations to predict propagation of a thin boiling liquid film on solid walls. The liquid film model is coupled to a solver of three-dimensional conservation equations describing the gas core, which is assumed to contain a saturated mixture of vapor and liquid droplets. Both the Eulerian–Eulerian and the Eulerian–Lagrangian approach are used to describe the droplet and vapor motion in the gas core. All the major interaction phenomena between the liquid film and the gas core flow have been accounted for, including the liquid film evaporation as well as the droplet deposition and entrainment. The resultant unified framework for annular flow has been applied to the steam-water flow with conditions typical for a Boiling Water Reactor (BWR). The simulation results for the liquid film flow rate show good agreement with the experimental data, with the potential to predict the dryout occurrence based on criteria of critical film thickness or critical film flow rate.

  14. Modeling of annular two-phase flow using a unified CFD approach

    International Nuclear Information System (INIS)

    Li, Haipeng; Anglart, Henryk

    2016-01-01

    Highlights: • Annular two-phase flow has been modeled using a unified CFD approach. • Liquid film was modeled based on a two-dimensional thin film assumption. • Both Eulerian and Lagrangian methods were employed for the gas core flow modeling. - Abstract: A mechanistic model of annular flow with evaporating liquid film has been developed using computational fluid dynamics (CFD). The model is employing a separate solver with two-dimensional conservation equations to predict propagation of a thin boiling liquid film on solid walls. The liquid film model is coupled to a solver of three-dimensional conservation equations describing the gas core, which is assumed to contain a saturated mixture of vapor and liquid droplets. Both the Eulerian–Eulerian and the Eulerian–Lagrangian approach are used to describe the droplet and vapor motion in the gas core. All the major interaction phenomena between the liquid film and the gas core flow have been accounted for, including the liquid film evaporation as well as the droplet deposition and entrainment. The resultant unified framework for annular flow has been applied to the steam-water flow with conditions typical for a Boiling Water Reactor (BWR). The simulation results for the liquid film flow rate show good agreement with the experimental data, with the potential to predict the dryout occurrence based on criteria of critical film thickness or critical film flow rate.

  15. Parametric study of the relaxation zone behind strong normal shock waves in a dusty ionized monatomic gas

    International Nuclear Information System (INIS)

    Igra, O.; Ben-Dor, G.

    1982-01-01

    The conservation equations appropriate to a steady, one-dimensional flow of dusty ionized argon were solved numerically. The specific effect of each of the physical parameters of the dust upon the flow properties in the relaxation zone is studied. It is found that increasing the dust particle mass causes an increase in both the kinematic and thermal relaxation lengths. In addition to these changes, the flow field inside the relaxation zone is also affected. An increase in the dust mass (caused either by an increase in the dust density or its diameter) causes an increase in the plasma velocity, temperature and electron number density and a decrease in its density and pressure. Similar effects are encountered when the specific heat capacity of the dust is changed. An increase in the emissivity of the dust causes an increase in the plasma density and pressure and a decrease in its velocity, temperature and electron number density. Increasing the emissivity of the dust results in a decrease in the relaxation zone length. (author)

  16. 'Saddle-point' ionization

    International Nuclear Information System (INIS)

    Gay, T.J.; Hale, E.B.; Irby, V.D.; Olson, R.E.; Missouri Univ., Rolla; Berry, H.G.

    1988-01-01

    We have studied the ionization of rare gases by protons at intermediate energies, i.e., energies at which the velocities of the proton and the target-gas valence electrons are comparable. A significant channel for electron production in the forward direction is shown to be 'saddle-point' ionization, in which electrons are stranded on or near the saddle-point of electric potential between the receding projectile and the ionized target. Such electrons yield characteristic energy spectra, and contribute significantly to forward-electron-production cross sections. Classical trajectory Monte Carlo calculations are found to provide qualitative agreement with our measurements and the earlier measurements of Rudd and coworkers, and reproduce, in detail, the features of the general ionization spectra. (orig.)

  17. Annular pancreas causing extrahepatic biliary obstruction

    International Nuclear Information System (INIS)

    Ogulin, M.; Jamar, B.

    2004-01-01

    Background. Annular pancreas is an uncommon congenital abnormality, consisting of a flat band of pancreatic tissue, which encircles duodenum or extrahepatic biliary duct. We present a case of obstructive jaundice, caused by annular pancreas. Case report. A 46 years old female was admitted because of a sudden onset of abdominal pain, vomiting and jaundice. For the last six years she occasionally noticed her skin was light yellow, in the last year she felt distension in the upper abdomen, especially after fatty meals. Conclusions. Two US examinations, the first one six months before the admission, showed dilated hepatic ducts. The reason of dilatation was unclear, even after the endoscopic US examination. At operation an almost complete obstruction of the common hepatic duct was found, caused by a narrow band of pancreatic tissue. (author)

  18. Ionizing and non-ionizing radiations

    International Nuclear Information System (INIS)

    1994-01-01

    The monograph is a small manual to get a knowledge of ionizing and non-ionizing radiations. The main chapters are: - Electromagnetic radiations - Ionizing and non-ionizing radiations - Non-ionizing electromagnetic radiations - Ionizing electromagnetic radiation - Other ionizing radiations - Ionizing radiation effects - The Nuclear Safety Conseil

  19. Boundary vapor contentsin an annular channel

    International Nuclear Information System (INIS)

    Remizov, O.V.; Shurkin, N.G.; Podgornyj, K.K.; Gal'chenko, Eh.F.; Bukhteev, I.S.

    1978-01-01

    The work is aimed at the experimental investigation of the worsening of the heat transfer in an annular channel. The experiments have been carried out on the annular channel 32x28x3000 mm with the even distribution of the heat flux along the length at pressures of 6.9-19.6 MPa, flow rate of 350-1000 kg/m 2 s, and specific heat fluxes from 0.18 up to 0.6 MW/m 2 . Heating is external, oneside. Water monodistillate of the following composition has been used as a coolant: pH 9; dry residue - 0.8-1.2 mg/kg, oxygen -10-15 mg/kg. It is found out that the change character of the temperature field of the heating surface of the annular channel at the regime with the worsen of heat emission depends on the ratio of regime parameters. At pressures of 6.9-13.7 MPa and flow rate of 350-500 kg/m 2 s the channel wall temperature rises monotoneously, never reaching its maximum. With pressure rise > 13.7 MPa and mass velocity > 500 kg/m 2 s the temperature of the heat emitting surface reaches its maximum, and then slowly falls. At pressures of 6.9-11.8 MPa the boundary vapor content value within the whole range of mass velocities does not depend on the specific heat flux q. At pressures higher than 13.7 MPa and mass velocities of 350-1000 kg/m 2 s the boundary vapor content depends on q. The heating of the external or internal surface of the annular channel affects the value of the boundary vapor content within the whole range of regime parameters' change under investigation

  20. Injector design for liner-on-target gas-puff experiments

    Science.gov (United States)

    Valenzuela, J. C.; Krasheninnikov, I.; Conti, F.; Wessel, F.; Fadeev, V.; Narkis, J.; Ross, M. P.; Rahman, H. U.; Ruskov, E.; Beg, F. N.

    2017-11-01

    We present the design of a gas-puff injector for liner-on-target experiments. The injector is composed of an annular high atomic number (e.g., Ar and Kr) gas and an on-axis plasma gun that delivers an ionized deuterium target. The annular supersonic nozzle injector has been studied using Computational Fluid Dynamics (CFD) simulations to produce a highly collimated (M > 5), ˜1 cm radius gas profile that satisfies the theoretical requirement for best performance on ˜1-MA current generators. The CFD simulations allowed us to study output density profiles as a function of the nozzle shape, gas pressure, and gas composition. We have performed line-integrated density measurements using a continuous wave (CW) He-Ne laser to characterize the liner gas density. The measurements agree well with the CFD values. We have used a simple snowplow model to study the plasma sheath acceleration in a coaxial plasma gun to help us properly design the target injector.

  1. Gas chromatography-tandem mass spectrometry with atmospheric pressure chemical ionization for fluorotelomer alcohols and perfluorinated sulfonamides determination.

    Science.gov (United States)

    Portolés, Tania; Rosales, Luis E; Sancho, Juan V; Santos, F Javier; Moyano, Encarnación

    2015-09-25

    Ionization and in source-fragmentation behavior of four fluorotelomer alcohols (FTOH) (4:2 FTOH, 6:2 FTOH, 8:2 FTOH and 10:2 FTOH) and four N-alkyl fluorooctane sulfonamides/-ethanols (N-MeFOSA, N-EtFOSA, N-MeFOSE and N-EtFOSE) by APCI has been studied and compared with the traditionally used EI and CI. Protonated molecule was the base peak of the APCI spectrum in all cases giving the possibility of selecting it as a precursor ion for MS/MS experiments. Following, CID fragmentation showed common product ions for all FOSAs/FOSEs (C4F7 and C3F5). Nevertheless, the different functionality gave characteristic pattern fragmentations. For instance, FTOHs mainly loss H2O+HF, FOSAs showed the losses of SO2 and HF while FOSEs showed the losses of H2O and SO2. Linearity, repeatability and LODs have been studied obtaining instrumental LODs between 1 and 5fg. Finally, application to river water and influent and effluent waste water samples has been carried out in order to investigate the improvements in detection capabilities of this new source in comparison with the traditionally used EI/CI sources. Matrix effects in APCI have been evaluated in terms of signal enhancement/suppression when comparing standards in solvent and matrix. No matrix effects were observed and concentrations found in samples were in the range of 1-100pgL(-1) far below the LODs achieved with methods previously reported. Unknown related perfluoroalkyl substances, as methyl-sulfone and methyl-sulfoxide analogues for FTOHs, were also discovered and tentatively identified. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Annular centrifugal contactors for TRPO process test

    International Nuclear Information System (INIS)

    Duan, W.H.; Wang, J.C.; Chen, J.; Zhou, X.Z.; Zhou, J.Z.; Song, C.L.

    2005-01-01

    The TRPO process has been developed in China for removing TRU elements from high-level liquid waste (HLLW) since 1980s. Centrifugal contactors have several advantages such as low hold-up volume, short residence time, low solvent degradation, small space requirements and short start-up time. Therefore, they are favored for both the reprocessing of spent fuel and the treatment of HLLW. In order to meet study on the TRPO test, a series of annular centrifugal contactors have been developed in Institute of Nuclear and -New Energy Technology, Tsinghua University, China (INET). In particular, the 10-mm annular centrifugal contactor for the laboratory-scale test has been applied successfully in the cold and hot tests of the TRPO process. The 70-mm annular centrifugal contactor for the industry-scale test has two new design characteristics, namely a modular design and an overflow structure. The modular design makes the contactor to be disassembled and assembled fast by simply moving the modules up and down. With the overflow structure, even though one stage or non-adjacent stages of the multi-stage cascade in operation are ceased to work, the cascade can continue to operate. Both the hydraulic performance and the mass-transfer efficiency of these contactors are excellent, and the extraction stage efficiency is greater than 95% at suitable operating conditions.

  3. A subchannel based annular flow dryout model

    International Nuclear Information System (INIS)

    Hammouda, Najmeddine; Cheng, Zhong; Rao, Yanfei F.

    2016-01-01

    Highlights: • A modified annular flow dryout model for subchannel thermalhydraulic analysis. • Implementation of the model in Canadian subchannel code ASSERT-PV. • Assessment of the model against tube CHF experiments. • Assessment of the model against CANDU-bundle CHF experiments. - Abstract: This paper assesses a popular tube-based mechanistic critical heat flux model (Hewitt and Govan’s annular flow model (based on the model of Whalley et al.), and modifies and implements the model for bundle geometries. It describes the results of the ASSERT subchannel code predictions using the modified model, as applied to a single tube and the 28-element, 37-element and 43-element (CANFLEX) CANDU bundles. A quantitative comparison between the model predictions and experimental data indicates good agreement for a wide range of flow conditions. The comparison has resulted in an overall average error of −0.15% and an overall root-mean-square error of 5.46% with tube data representing annular film dryout type critical heat flux, and in an overall average error of −0.9% and an overall RMS error of 9.9% with Stern Laboratories’ CANDU-bundle data.

  4. Heat transfer characteristics of horizontally oriented multi-layered annular insulation, (1)

    International Nuclear Information System (INIS)

    Hino, Ryutaro; Simomura, Hiroaki

    1985-04-01

    A computer code has been developed to analyze the natural convection heat transfer in a horizontal annular insulation layer of a hot gas duct when local gaps and inhomogeneity of filling density of insulation materials exist. This computer code simulates local gaps and inhomogeneity of filling density by a multi-layer model. This report describes an analytical model, a numerical method, an outline of program and some calculation results. (author)

  5. Slug-annular transition with particular reference to narrow rectangular ducts

    International Nuclear Information System (INIS)

    Jones, O.C. Jr.; Zuber, N.

    1978-01-01

    The transition from slug-flow to annular-flow in two-phase, gas-liquid mixtures is analyzed. A transition equation is derived which agrees well when compared with objective data determined from the disappearance of the low-void peak in the void fluctuation probability density in a rectangular duct. Application to other geometries is suggested and tabular recommendations given for determination of the drift flux coefficient, K, based on results in the literature

  6. Radial midframe baffle for can-annular combustor arrangement having tangentially oriented combustor cans

    Science.gov (United States)

    Rodriguez, Jose L.

    2015-09-15

    A can-annular gas turbine engine combustion arrangement (10), including: a combustor can (12) comprising a combustor inlet (38) and a combustor outlet circumferentially and axially offset from the combustor inlet; an outer casing (24) defining a plenum (22) in which the combustor can is disposed; and baffles (70) configured to divide the plenum into radial sectors (72) and configured to inhibit circumferential motion of compressed air (16) within the plenum.

  7. Development of a gas-cylinder-free plasma desorption/ionization system for on-site detection of chemical warfare agents.

    Science.gov (United States)

    Iwai, Takahiro; Kakegawa, Ken; Aida, Mari; Nagashima, Hisayuki; Nagoya, Tomoki; Kanamori-Kataoka, Mieko; Miyahara, Hidekazu; Seto, Yasuo; Okino, Akitoshi

    2015-06-02

    A gas-cylinder-free plasma desorption/ionization system was developed to realize a mobile on-site analytical device for detection of chemical warfare agents (CWAs). In this system, the plasma source was directly connected to the inlet of a mass spectrometer. The plasma can be generated with ambient air, which is drawn into the discharge region by negative pressure in the mass spectrometer. High-power density pulsed plasma of 100 kW could be generated by using a microhollow cathode and a laboratory-built high-intensity pulsed power supply (pulse width: 10-20 μs; repetition frequency: 50 Hz). CWAs were desorbed and protonated in the enclosed space adjacent to the plasma source. Protonated sample molecules were introduced to the mass spectrometer by airflow through the discharge region. To evaluate the analytical performance of this device, helium and air plasma were directly irradiated to CWAs in the gas-cylinder-free plasma desorption/ionization system and the protonated molecules were analyzed by using an ion-trap mass spectrometer. A blister agent (nitrogen mustard 3) and nerve gases [cyclohexylsarin (GF), tabun (GA), and O-ethyl S-2-N,N-diisopropylaminoethyl methylphosphonothiolate (VX)] in solution in n-hexane were applied to the Teflon rod and used as test samples, after solvent evaporation. As a result, protonated molecules of CWAs were successfully observed as the characteristic ion peaks at m/z 204, 181, 163, and 268, respectively. In air plasma, the limits of detection were estimated to be 22, 20, 4.8, and 1.0 pmol, respectively, which were lower than those obtained with helium plasma. To achieve quantitative analysis, calibration curves were made by using CWA stimulant dipinacolyl methylphosphonate as an internal standard; straight correlation lines (R(2) = 0.9998) of the peak intensity ratios (target per internal standard) were obtained. Remarkably, GA and GF gave protonated dimer ions, and the ratios of the protonated dimer ions to the protonated

  8. Ionizing radiation

    International Nuclear Information System (INIS)

    Kruger, J.

    1989-01-01

    Ionizing radiation results in biological damage that differs from other hazardous substances and is highly dangerous to man. Ionizing radiation cannot be perceived by man's sense organs and the biological damage cannot be detected immediately afterwards (except in very high doses). Every human being is exposed to low doses of radiation. The structure of the atom; sources of ionizing radiation; radiation units; biological effects; norms for radiation protection; and the national control in South Africa are discussed. 1 fig., 5 refs

  9. Development, optimization, validation and application of faster gas chromatography - flame ionization detector method for the analysis of total petroleum hydrocarbons in contaminated soils.

    Science.gov (United States)

    Zubair, Abdulrazaq; Pappoe, Michael; James, Lesley A; Hawboldt, Kelly

    2015-12-18

    This paper presents an important new approach to improving the timeliness of Total Petroleum Hydrocarbon (TPH) analysis in the soil by Gas Chromatography - Flame Ionization Detector (GC-FID) using the CCME Canada-Wide Standard reference method. The Canada-Wide Standard (CWS) method is used for the analysis of petroleum hydrocarbon compounds across Canada. However, inter-laboratory application of this method for the analysis of TPH in the soil has often shown considerable variability in the results. This could be due, in part, to the different gas chromatography (GC) conditions, other steps involved in the method, as well as the soil properties. In addition, there are differences in the interpretation of the GC results, which impacts the determination of the effectiveness of remediation at hydrocarbon-contaminated sites. In this work, multivariate experimental design approach was used to develop and validate the analytical method for a faster quantitative analysis of TPH in (contaminated) soil. A fractional factorial design (fFD) was used to screen six factors to identify the most significant factors impacting the analysis. These factors included: injection volume (μL), injection temperature (°C), oven program (°C/min), detector temperature (°C), carrier gas flow rate (mL/min) and solvent ratio (v/v hexane/dichloromethane). The most important factors (carrier gas flow rate and oven program) were then optimized using a central composite response surface design. Robustness testing and validation of model compares favourably with the experimental results with percentage difference of 2.78% for the analysis time. This research successfully reduced the method's standard analytical time from 20 to 8min with all the carbon fractions eluting. The method was successfully applied for fast TPH analysis of Bunker C oil contaminated soil. A reduced analytical time would offer many benefits including an improved laboratory reporting times, and overall improved clean up

  10. Total OH reactivity measurements using a new fast Gas Chromatographic Photo-Ionization Detector (GC-PID

    Directory of Open Access Journals (Sweden)

    V. Sinha

    2012-12-01

    Full Text Available The primary and most important oxidant in the atmosphere is the hydroxyl radical (OH. Currently OH sinks, particularly gas phase reactions, are poorly constrained. One way to characterize the overall sink of OH is to measure directly the ambient loss rate of OH, the total OH reactivity. To date, direct measurements of total OH reactivity have been either performed using a Laser-Induced Fluorescence (LIF system ("pump-and-probe" or "flow reactor" or the Comparative Reactivity Method (CRM with a Proton-Transfer-Reaction Mass Spectrometer (PTR-MS. Both techniques require large, complex and expensive detection systems. This study presents a feasibility assessment for CRM total OH reactivity measurements using a new detector, a Gas Chromatographic Photoionization Detector (GC-PID. Such a system is smaller, more portable, less power consuming and less expensive than other total OH reactivity measurement techniques.

    Total OH reactivity is measured by the CRM using a competitive reaction between a reagent (here pyrrole with OH alone and in the presence of atmospheric reactive molecules. The new CRM method for total OH reactivity has been tested with parallel measurements of the GC-PID and the previously validated PTR-MS as detector for the reagent pyrrole during laboratory experiments, plant chamber and boreal field studies. Excellent agreement of both detectors was found when the GC-PID was operated under optimum conditions. Time resolution (60–70 s, sensitivity (LOD 3–6 s−1 and overall uncertainty (25% in optimum conditions for total OH reactivity were similar to PTR-MS based total OH reactivity measurements. One drawback of the GC-PID system was the steady loss of sensitivity and accuracy during intensive measurements lasting several weeks, and a possible toluene interference. Generally, the GC-PID system has been shown to produce closely comparable results to the PTR-MS and thus in suitable environments (e.g. forests it

  11. Novel annular flow electromagnetic measurement system for drilling engineering.

    OpenAIRE

    Ge, L.; Wei, G. H.; Wang, Q.; Hu, Z.; Li, J. L.

    2017-01-01

    Downhole micro-flux control drilling technology can effectively solve drilling accidents, such as kick and loss in narrow density window drilling scenarios. Using a downhole annular flow measurement system to obtain real-time information of downhole annular flow is the core and foundation of downhole micro-flux control drilling technology. The research work of electromagnetic flowmeters in recent years creates a challenge for downhole annular flow measurement. This paper proposes a new method...

  12. Radiologic findings of annular pancreas divisum : a case report

    International Nuclear Information System (INIS)

    Choi, Dong Sik; Lee, Dong Ho; Ko, Young Tae; Han, Tae Il; Yoon, Youp; Dong, Suk Ho

    1996-01-01

    Annular pancreas divisum is a very rare congenital anomaly involving the coexistence of an annular pancreas and pancreatic divisum in one pancreas, and showing characteristic radiologic findings of ring-like pancreatic tissue surrounding the second portion of the duodenum and no evidence of connection between ventral and dorsal ductal systems. We described the radiologic findings of annular pancreas divisum, diagnosed by hypotonic duodenography, CT and ERCP

  13. Quantification of low levels of organochlorine pesticides using small volumes (≤100 μl) of plasma of wild birds through gas chromatography negative chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    Rivera-Rodriguez, Laura B.; Rodriguez-Estrella, Ricardo; Ellington, James Jackson; Evans, John J.

    2007-01-01

    A solid phase extraction and gas chromatography with negative chemical ionization mass spectrometry in scan mode (GC-NCI-MS) method was developed to identify and quantify for the first time low levels of organochlorine pesticides (OCs) in plasma samples of less than 100 μl from wild birds. The method detection limits ranged from 0.012 to 0.102 pg/μl and the method reporting limit from 0.036 to 0.307 pg/μl for α, γ, β and δ-hexachlorocyclohexane (HCH), heptachlor, aldrin, heptachlor epoxide, endosulfan I, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p'-DDE), dieldrin, endrin, endosulfan-II, endrin-aldehyde and endosulfan-sulfate. Pesticide levels in small serum samples from individual Falco sparverius, Sturnella neglecta, Mimus polyglottos and Columbina passerina were quantified. Concentrations ranged from not detected (n/d) to 204.9 pg/μl for some OC pesticides. All levels in the food web in and around cultivated areas showed the presence of pesticides notwithstanding the small areas for agriculture existing in the desert of Baja California peninsula. - This technique allows small birds to be used as indicators of chemical contamination in habitats because pesticides can be quantified in very small volumes of plasma

  14. Quantification of low levels of organochlorine pesticides using small volumes ({<=}100 {mu}l) of plasma of wild birds through gas chromatography negative chemical ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Rivera-Rodriguez, Laura B. [Centro de Investigaciones Biologicas del Noroeste, S.C., Environmental Planning and Conservation Program, Mar Bermejo No. 195, Col. Playa Palo de Santa Rita, Ado. Postal 128, La Paz, BCS. 23090 (Mexico)]. E-mail: lrivera04@cibnor.mx; Rodriguez-Estrella, Ricardo [Centro de Investigaciones Biologicas del Noroeste, S.C., Environmental Planning and Conservation Program, Mar Bermejo No. 195, Col. Playa Palo de Santa Rita, Ado. Postal 128, La Paz, BCS. 23090 (Mexico); Ellington, James Jackson [National Exposure Research Laboratory, US Environmental Protection Agency, 960 College Station Road, Athens, GA 30605 (United States); Evans, John J. [National Exposure Research Laboratory, US Environmental Protection Agency, 960 College Station Road, Athens, GA 30605 (United States); Senior Service America Inc. (United States)

    2007-07-15

    A solid phase extraction and gas chromatography with negative chemical ionization mass spectrometry in scan mode (GC-NCI-MS) method was developed to identify and quantify for the first time low levels of organochlorine pesticides (OCs) in plasma samples of less than 100 {mu}l from wild birds. The method detection limits ranged from 0.012 to 0.102 pg/{mu}l and the method reporting limit from 0.036 to 0.307 pg/{mu}l for {alpha}, {gamma}, {beta} and {delta}-hexachlorocyclohexane (HCH), heptachlor, aldrin, heptachlor epoxide, endosulfan I, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p'-DDE), dieldrin, endrin, endosulfan-II, endrin-aldehyde and endosulfan-sulfate. Pesticide levels in small serum samples from individual Falco sparverius, Sturnella neglecta, Mimus polyglottos and Columbina passerina were quantified. Concentrations ranged from not detected (n/d) to 204.9 pg/{mu}l for some OC pesticides. All levels in the food web in and around cultivated areas showed the presence of pesticides notwithstanding the small areas for agriculture existing in the desert of Baja California peninsula. - This technique allows small birds to be used as indicators of chemical contamination in habitats because pesticides can be quantified in very small volumes of plasma.

  15. FastChem: A computer program for efficient complex chemical equilibrium calculations in the neutral/ionized gas phase with applications to stellar and planetary atmospheres

    Science.gov (United States)

    Stock, Joachim W.; Kitzmann, Daniel; Patzer, A. Beate C.; Sedlmayr, Erwin

    2018-06-01

    For the calculation of complex neutral/ionized gas phase chemical equilibria, we present a semi-analytical versatile and efficient computer program, called FastChem. The applied method is based on the solution of a system of coupled nonlinear (and linear) algebraic equations, namely the law of mass action and the element conservation equations including charge balance, in many variables. Specifically, the system of equations is decomposed into a set of coupled nonlinear equations in one variable each, which are solved analytically whenever feasible to reduce computation time. Notably, the electron density is determined by using the method of Nelder and Mead at low temperatures. The program is written in object-oriented C++ which makes it easy to couple the code with other programs, although a stand-alone version is provided. FastChem can be used in parallel or sequentially and is available under the GNU General Public License version 3 at https://github.com/exoclime/FastChem together with several sample applications. The code has been successfully validated against previous studies and its convergence behavior has been tested even for extreme physical parameter ranges down to 100 K and up to 1000 bar. FastChem converges stable and robust in even most demanding chemical situations, which posed sometimes extreme challenges for previous algorithms.

  16. Fundamental study of hydrogen-attachment-induced peptide fragmentation occurring in the gas phase and during the matrix-assisted laser desorption/ionization process.

    Science.gov (United States)

    Asakawa, Daiki; Takahashi, Hidenori; Iwamoto, Shinichi; Tanaka, Koichi

    2018-05-09

    Mass spectrometry with hydrogen-radical-mediated fragmentation techniques has been used for the sequencing of proteins/peptides. The two methods, matrix-assisted laser desorption/ionization in-source decay (MALDI-ISD) and hydrogen attachment/abstraction dissociation (HAD) are known as hydrogen-radical-mediated fragmentation techniques. MALDI-ISD occurs during laser induced desorption processes, whereas HAD utilizes the association of hydrogen with peptide ions in the gas phase. In this study, the general mechanisms of MALDI-ISD and HAD of peptides were investigated. We demonstrated the fragmentation of four model peptides and investigated the fragment formation pathways using density functional theory (DFT) calculations. The current experimental and computational joint study indicated that MALDI-ISD and HAD produce aminoketyl radical intermediates, which immediately undergo radical-induced cleavage at the N-Cα bond located on the C-terminal side of the radical site, leading to the c'/z˙ fragment pair. In the case of MALDI-ISD, the z˙ fragments undergo a subsequent reaction with the matrix to give z' and matrix adducts of the z fragments. In contrast, the c' and z˙ fragments react with hydrogen atoms during the HAD processes, and various fragment species, such as c˙, c', z˙ and z', were observed in the HAD-MS/MS mass spectra.

  17. Simultaneous determination of clebopride and a major metabolite N-desbenzylclebopride in plasma by capillary gas chromatography-negative-ion chemical ionization mass spectrometry.

    Science.gov (United States)

    Robinson, P R; Jones, M D; Maddock, J; Rees, L W

    1991-03-08

    A procedure for the simultaneous assay of clebopride and its major metabolite N-desbenzylclebopride in plasma has been developed. The method utilizes capillary gas chromatography-negative-ion chemical ionization mass spectrometry with selected-ion monitoring of characteristic ions. Employing 2-ethoxy analogues as internal standards, the benzamides were extracted from basified plasma using dichloromethane. Subsequent reaction with heptafluorobutyric anhydride produced volatile mono- and diheptafluorobutyryl derivatives of clebopride and N-desbenzylclebopride, respectively. The methane negative-ion mass spectra of these derivatives exhibited intense high-mass ions ideal for specific quantitation of low levels in biological fluids. Using this procedure the recovery of the drug and metabolite from human plasma was found to be 84.4 +/- 1.5% (n = 3) and 77.4 +/- 4.7% (n = 3), respectively, at 0.5 ng/ml. Measurement of both compounds down to 0.10 ng/ml with a coefficient of variation of less than 10.5% is described. Plasma levels are reported in four volunteers up to 24 h following oral administration of 1 mg of clebopride malate salt.

  18. Ethanol concentration in 56 refillable electronic cigarettes liquid formulations determined by headspace gas chromatography with flame ionization detector (HS-GC-FID).

    Science.gov (United States)

    Poklis, Justin L; Wolf, Carl E; Peace, Michelle R

    2017-10-01

    Personal battery-powered vaporizers or electronic cigarettes were developed as an alternative to traditional cigarettes. The modern electronic cigarettes were patented in 2004 by Hon Lik in China. In May 2016, the US Food and Drug Administration (FDA) imposed regulatory statutes on e-cigarettes and their liquid formulations (e-liquids); prior to that, they were unregulated. E-liquids are typically composed of propylene glycol and/or glycerin, flavouring component(s), and active ingredient(s), such as nicotine. Fifty-six commercially available e-liquids, purchased from various sources, contained a variety of flavours and active ingredients. A headspace gas chromatography with flame ionization detector (HS-GC-FID) method was used to analyze these e-liquids for volatiles content. Only one of the e-liquids listed ethanol as a component. The chromatographic separation of volatiles was performed on a Restek BAC-1 column. A linear calibration was generated for ethanol with limits of detection and quantification (LOD/LOQ) of 0.05 mg/mL. Ethanol concentrations in the 56 e-liquids ranged from none detected to 206 mg/mL. The ethanol determined in these products may have been used in flavourants or a solvent; the reason for inclusion cannot be fully ascertained. The implications of vaporizing ethanol as an e-liquid component are unknown. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

  19. CFD model of diabatic annular two-phase flow using the Eulerian–Lagrangian approach

    International Nuclear Information System (INIS)

    Li, Haipeng; Anglart, Henryk

    2015-01-01

    Highlights: • A CFD model of annular two-phase flow with evaporating liquid film has been developed. • A two-dimensional liquid film model is developed assuming that the liquid film is sufficiently thin. • The liquid film model is coupled to the gas core flow, which is represented using the Eulerian–Lagrangian approach. - Abstract: A computational fluid dynamics (CFD) model of annular two-phase flow with evaporating liquid film has been developed based on the Eulerian–Lagrangian approach, with the objective to predict the dryout occurrence. Due to the fact that the liquid film is sufficiently thin in the diabatic annular flow and at the pre-dryout conditions, it is assumed that the flow in the wall normal direction can be neglected, and the spatial gradients of the dependent variables tangential to the wall are negligible compared to those in the wall normal direction. Subsequently the transport equations of mass, momentum and energy for liquid film are integrated in the wall normal direction to obtain two-dimensional equations, with all the liquid film properties depth-averaged. The liquid film model is coupled to the gas core flow, which currently is represented using the Eulerian–Lagrangian technique. The mass, momentum and energy transfers between the liquid film, gas, and entrained droplets have been taken into account. The resultant unified model for annular flow has been applied to the steam–water flow with conditions typical for a Boiling Water Reactor (BWR). The simulation results for the liquid film flow rate show favorable agreement with the experimental data, with the potential to predict the dryout occurrence based on criteria of critical film thickness or critical film flow rate

  20. Granuloma annulare localized to the shaft of the penis

    DEFF Research Database (Denmark)

    Trap, R; Wiebe, B

    1993-01-01

    A case of granuloma annulare localized to the shaft of the penis is reported. The differential diagnoses are discussed. Penile granuloma annulare is a rare disorder and it is concluded that biopsies of penile lesions are recommended to verify the correct diagnosis.......A case of granuloma annulare localized to the shaft of the penis is reported. The differential diagnoses are discussed. Penile granuloma annulare is a rare disorder and it is concluded that biopsies of penile lesions are recommended to verify the correct diagnosis....

  1. Study on two phase flow characteristics in annular pulsed extraction column with different ratio of annular width to column diameter

    International Nuclear Information System (INIS)

    Qin Wei; Dai Youyuan; Wang Jiading

    1994-01-01

    Annular pulsed extraction column can successfully provide large throughput and can be made critically safe for fuel reprocessing. This investigation is to study the two phase flow characteristics in annular pulsed extraction column with four different annular width. 30% TBP (in kerosene)-water is used (water as continuous phase). Results show that modified Pratt correlation is valid under the experimental operation conditions for the annular pulsed extraction column. The characteristic velocity U K decreased with the increase of energy input and increased with the increase of the ratio of annular width to column diameter. Flooding velocity correlation is suggested. The deviation of the calculated values from the experimental data is within +20% for four annular width in a pulsed extraction column

  2. Ionizing radiations

    International Nuclear Information System (INIS)

    Anon.

    1999-01-01

    This is an update about the radiological monitoring in base nuclear installations. A departmental order of the 23. march 1999 (J.O.28. april, p.6309) determines the enabling rules by the Office of Protection against Ionizing Radiations of person having at one's disposal the results with names of individual exposure of workers put through ionizing radiations. (N.C.)

  3. Plasma production via field ionization

    Directory of Open Access Journals (Sweden)

    C. L. O’Connell

    2006-10-01

    Full Text Available Plasma production via field ionization occurs when an incoming particle beam is sufficiently dense that the electric field associated with the beam ionizes a neutral vapor or gas. Experiments conducted at the Stanford Linear Accelerator Center explore the threshold conditions necessary to induce field ionization by an electron beam in a neutral lithium vapor. By independently varying the transverse beam size, number of electrons per bunch, or bunch length, the radial component of the electric field is controlled to be above or below the threshold for field ionization. Additional experiments ionized neutral xenon and neutral nitric oxide by varying the incoming beam’s bunch length. A self-ionized plasma is an essential step for the viability of plasma-based accelerators for future high-energy experiments.

  4. The Prevalence of Ionized Gas Outflow Signatures in SDSS-IV MaNGA Active Galactic Nuclei

    Science.gov (United States)

    Flores, Anthony M.; Wylezalek, Dominika; Zakamska, Nadia

    2018-01-01

    Actively accreting supermassive black holes (AGN) can have a variety of effects on their host galaxies, from generating large regions of hot, photoionized gas, to driving AGN feedback in the form of galaxy wide outflows that may affect the evolution of the galaxy over time by quenching their star formation and by thus setting limits to the total mass of their host galaxy. The focus of this work is to assess the prevalence of AGN-driven outflows in low-redshift AGN of moderate power using IFU observations of 2778 galaxies available through SDSS-IV MaNGA.SDSS-IV MaNGA is an optical spectroscopic IFU survey which will have obtained spatially resolved spectroscopic observations of ~10,000 galaxies at z ≤ 0.1 and with stellar masses >10^9 solar masses over the next three years, allowing us to describe the kinematic properties of a large galaxy sample across different spatial regions.We have re-mapped the kinematics of the [O III] emission line to account for asymmetries and secondary kinematic components in the emission line brought on by potential AGN-driven outflows. Using all galaxies currently in the MaNGA survey, we implement a new fitting procedure to help determine the prevalence of these secondary components. Specifically, we use the non-parametric W80 value as a proxy for velocity dispersion, which we expect to be affected especially in the case of asymmetries and broadening of the emission lines. Separating these galaxies into two samples of independently identified AGN candidates and non-AGN, I will show that broad secondary components are twice as common in MaNGA-selected AGN compared to galaxies in MaNGA not classified as AGN. Moreover, when the underlying distribution of W80 values are compared between samples, I will show that the differences in these distributions are statistically significant. This demonstrates that large IFU survey like SDSS-IV MaNGA will uncover many previously unknown AGN and AGN feedback signatures. Outflows and feedback from low

  5. A New Annular Shear Piezoelectric Accelerometer

    DEFF Research Database (Denmark)

    Liu, Bin; Kriegbaum, B.

    2000-01-01

    This paper describes the construction and performance of a recently introduced Annular Shear piezoelectric accelerometer, Type 4511. The design has insulated and double-shielded case. The accelerometer housing is made of stainless steel, AISI 316L. Piezoceramic PZ23 is used. The seismic mass...... prototype. Reasonable agreement between the experimental results of the physical prototype and the simulation results is achieved. The design becomes more efficient. In addition, Type 4511 has a built in DeltaTronâ charge amplifier with ID and complies with IEEE-P1451.4 standard, which is a smart transducer...

  6. An annular laser for penetrating radiations

    International Nuclear Information System (INIS)

    Marie, G.R.P.

    1974-01-01

    Description is given of an annular laser generating an emission of X rays or gamma rays, from a pumping beam provided by a light wave or infra-red laser and applied to an active substance. Said laser essentially comprises a semi toroidal metal groove wherein is placed said active substance. That substance is illuminated by the pumping beam after reflection of the latter on a mirror provided with an opening through which pass X rays or gamma rays after several reflections on the groove bottom. The pumping-beam uses a revolution symmetry mode, the electric field lines of which are circles coaxial with said beam [fr

  7. Matrix Assisted and/or Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of WO3 Clusters Formation in Gas Phase. Nanodiamonds, Fullerene, and Graphene Oxide Matrices

    Science.gov (United States)

    Ausekar, Mayuri Vilas; Mawale, Ravi Madhukar; Pazdera, Pavel; Havel, Josef

    2018-03-01

    The formation of W x O y +●/-● clusters in the gas phase was studied by laser desorption ionization (LDI) and matrix assisted laser desorption ionization (MALDI) of solid WO3. LDI produced (WO3) n + ●/- ● ( n = 1-7) clusters. In MALDI, when using nano-diamonds (NDs), graphene oxide (GO), or fullerene (C60) matrices, higher mass clusters were generated. In addition to (WO3) n -● clusters, oxygen-rich or -deficient species were found in both LDI and MALDI (with the total number of clusters exceeding one hundred ≈ 137). This is the first time that such matrices have been used for the generation of(WO3) n + ●/-● clusters in the gas phase, while new high mass clusters (WO3) n -● ( n = 12-19) were also detected. [Figure not available: see fulltext.

  8. Studies on turbulence structure and liquid film behavior in annular two-phase flow flowing in a throat section

    International Nuclear Information System (INIS)

    Yoshida, Kenji; Miyabe, Masaya; Matsumoto, Tadayoshi; Kataoka, Isao; Ohmori, Shuichi; Mori, Michitsugu

    2004-01-01

    Experimental studies on turbulence structure and liquid film behavior in annular two-phase flow were carried out concerned with the steam injector systems for a next-generation nuclear reactor. In the steam injector, steam/water annular two-phase flow is formed at the mixing nozzle. To make an appropriate design for high-performance steam injector system, it is very important to accumulate the fundamental data of thermo-hydro dynamic characteristics of annular flow in the steam injector. Especially, the turbulence modification in multi-phase flow due to the phase interaction is one of the most important phenomena and has attracted research attention. In this study, the liquid film behavior and the resultant turbulence modification due to the phase interaction were investigated. The behavior of the interfacial waves on liquid film flow such as the ripple or disturbance waves were observed to make clear the interfacial velocity and the special structure of the interfacial waves by using the high-speed video camera and the digital camera. The measurements for gas-phase velocity profiles and turbulent intensity in annular flow passing through the throat section were precisely performed to investigate quantitatively the turbulent modification in annular flow by using the constant temperature hot-wire anemometer. The measurements for liquid film thickness by the electrode needle method were also carried out. (author)

  9. Non-polar lipids characterization of Quinoa (Chenopodium quinoa) seed by comprehensive two-dimensional gas chromatography with flame ionization/mass spectrometry detection and non-aqueous reversed-phase liquid chromatography with atmospheric pressure chemical ionization mass spectrometry detection.

    Science.gov (United States)

    Fanali, Chiara; Beccaria, Marco; Salivo, Simona; Tranchida, Peter; Tripodo, Giusy; Farnetti, Sara; Dugo, Laura; Dugo, Paola; Mondello, Luigi

    2015-07-08

    A chemical characterization of major lipid components, namely, triacylglycerols, fatty acids and the unsaponifiable fraction, in a Quinoa seed lipids sample is reported. To tackle such a task, non-aqueous reversed-phase high-performance liquid chromatography with mass spectrometry detection was employed. The latter was interfaced with atmospheric pressure chemical ionization for the analysis of triacylglycerols. The main triacylglycerols (>10%) were represented by OLP, OOL and OLL (P = palmitoyl, O = oleoyl, L = linoleoyl); the latter was present in the oil sample at the highest percentage (18.1%). Furthermore, fatty acid methyl esters were evaluated by gas chromatography with flame ionization detection. 89% of the total fatty acids was represented by unsaturated fatty acid methyl esters with the greatest percentage represented by linoleic and oleic acids accounting for approximately 48 and 28%, respectively. An extensive characterization of the unsaponifiable fraction of Quinoa seed lipids was performed for the first time, by using comprehensive two-dimensional gas chromatography with dual mass spectrometry/flame ionization detection. Overall, 66 compounds of the unsaponifiable fraction were tentatively identified, many constituents of which (particularly sterols) were confirmed by using gas chromatography with high-resolution time-of-flight mass spectrometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. NWIS Measurements for uranium metal annular castings

    International Nuclear Information System (INIS)

    Mattingly, J.K.; Valentine, T.E.; Mihalczo, J.T.

    1998-01-01

    This report describes measurements performed with annular uranium metal castings of different enrichments to investigate the use of 252 Cf-source-driven noise analysis measurements as a means to quantify the amount of special nuclear material (SNM) in the casting. This work in FY 97 was sponsored by the Oak Ridge Y-12 Plant and the DOE Office of Technology Development Programs. Previous measurements and calculational studies have shown that many of the signatures obtained from the source-driven measurement are very sensitive to fissile mass. Measurements were performed to assess the applicability of this method to standard annular uranium metal castings at the Oak Ridge Y-12 plant under verification by the International Atomic Energy Agency (IAEA) using the Nuclear Weapons Identification System (NWIS) processor. Before the measurements with different enrichments, a limited study of source-detector-casting moderator configurations was performed to enhance the correlated information. These configurations consisted of a casting with no reflector and with various thicknesses of polyethylene reflectors up to 10.16 cm in 2.54 cm steps. The polyethylene moderator thickness of 7.62 cm was used for measurements with castings of different enrichments reported here. The sensitivity of the measured parameters to fissile mass was investigated using four castings each with a different enrichment. The high sensitivity of this measurement method to fissile mass and to other material and configurations provides some advantages over existing safeguards methods

  11. The critical ionization velocity

    International Nuclear Information System (INIS)

    Raadu, M.A.

    1980-06-01

    The critical ionization velocity effect was first proposed in the context of space plasmas. This effect occurs for a neutral gas moving through a magnetized plasma and leads to rapid ionization and braking of the relative motion when a marginal velocity, 'the critical velocity', is exceeded. Laboratory experiments have clearly established the significance of the critical velocity and have provided evidence for an underlying mechanism which relies on the combined action of electron impact ionization and a collective plasma interaction heating electrons. There is experimental support for such a mechanism based on the heating of electrons by the modified two-stream instability as part of a feedback process. Several applications to space plasmas have been proposed and the possibility of space experiments has been discussed. (author)

  12. Limited Diffraction Maps for Pulsed Wave Annular Arrays

    DEFF Research Database (Denmark)

    Fox, Paul D.

    2002-01-01

    A procedure is provided for decomposing the linear field of flat pulsed wave annular arrays into an equivalent set of known limited diffraction Bessel beams. Each Bessel beam propagates with known characteristics, enabling good insight into the propagation of annular fields to be obtained...

  13. Obtention of an empirical equation for annular channels

    International Nuclear Information System (INIS)

    Diaz H, C.; Salinas R, G.A.

    1996-01-01

    Using a trial circuit, the experimental heat transfer coefficient is determined, in forced convection at one phase only within an annular channel in which water flows ascendantly and for this reason an empirical equation is determined. This work tries to contribute to the understanding of the forced convection phenomena in non tubular geometries like the annular channels. (Author)

  14. Determination of valproic acid in human plasma using dispersive liquid-liquid microextraction followed by gas chromatography-flame ionization detection

    Science.gov (United States)

    Fazeli-Bakhtiyari, Rana; Panahi-Azar, Vahid; Sorouraddin, Mohammad Hossein; Jouyban, Abolghasem

    2015-01-01

    Objective(s): Dispersive liquid-liquid microextraction coupled with gas chromatography (GC)-flame ionization detector was developed for the determination of valproic acid (VPA) in human plasma. Materials and Methods: Using a syringe, a mixture of suitable extraction solvent (40 µl chloroform) and disperser (1 ml acetone) was quickly added to 10 ml of diluted plasma sample containing VPA (pH, 1.0; concentration of NaCl, 4% (w/v)), resulting in a cloudy solution. After centrifugation (6000 rpm for 6 min), an aliquot (1 µl) of the sedimented organic phase was removed using a 1-µl GC microsyringe and injected into the GC system for analysis. One variable at a time optimization method was used to study various parameters affecting the extraction efficiency of target analyte. Then, the developed method was fully validated for its accuracy, precision, recovery, stability, and robustness. Results: Under the optimum extraction conditions, good linearity range was obtained for the calibration graph, with correlation coefficient higher than 0.998. Limit of detection and lower limit of quantitation were 3.2 and 6 μg/ml, respectively. The relative standard deviations of intra and inter-day analysis of examined compound were less than 11.5%. The relative recoveries were found in the range of 97 to 107.5%. Finally, the validated method was successfully applied to the analysis of VPA in patient sample. Conclusion: The presented method has acceptable levels of precision, accuracy and relative recovery and could be used for therapeutic drug monitoring of VPA in human plasma. PMID:26730332

  15. Gas chromatography/atmospheric pressure chemical ionization/mass spectrometry for the analysis of organochlorine pesticides and polychlorinated biphenyls in human serum.

    Science.gov (United States)

    Geng, Dawei; Jogsten, Ingrid Ericson; Dunstan, Jody; Hagberg, Jessika; Wang, Thanh; Ruzzin, Jerome; Rabasa-Lhoret, Rémi; van Bavel, Bert

    2016-07-01

    A method using a novel atmospheric pressure chemical ionization source for coupling gas chromatography (GC/APCI) to triple quadrupole mass spectrometry (MS/MS) for the determination of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) regulated by the Stockholm Convention is presented. One microliter injection of a six-point calibration curve of native PCBs and OCPs, ranging from 0.04 to 300pg/μL, was performed. The relative standard deviation (RSD) of the relative response factors (RRFs) was less than 15% with a coefficient of determination (r(2))>0.995. Meanwhile, two calibration solutions (CS), CS 2 (0.4pg/μL) and CS 3 (4pg/μL) were analyzed to study the repeatability calculated for both area and RRFs. The RSD for RRF ranged from 3.1 to 16% and 3.6 to 5.5% for CS 2 and CS 3, respectively. The limits of detection (LOD) determined by peak-to-peak signal-to-noise ratio (S/N) of 3 were compared between the GC/APCI/MS/MS and a GC coupled to high resolution mass spectrometry (GC/HRMS) system. GC/APCI/MS/MS resulted in lower LOD for most of the compounds, except for PCB#74, cis-chlordane and trans-chlordane. GC/APCI/MS/MS and GC/HRMS were also compared by performing analysis on 75 human serum samples together with eight QA/QC serum samples. The comparison between GC/APCI/MS/MS system and GC/HRMS system for 16 of the targeted compounds was carried out. No statistically significant difference was discovered. Due to increased sensitivity and user friendly operation under atmospheric pressure, GC/APCI/MS/MS is a powerful alternative technique that can easily meet the specification of GC/HRMS. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Quantitative Analysis of Mixed Halogen Dioxins and Furans in Fire Debris Utilizing Atmospheric Pressure Ionization Gas Chromatography-Triple Quadrupole Mass Spectrometry.

    Science.gov (United States)

    Organtini, Kari L; Myers, Anne L; Jobst, Karl J; Reiner, Eric J; Ross, Brian; Ladak, Adam; Mullin, Lauren; Stevens, Douglas; Dorman, Frank L

    2015-10-20

    Residential and commercial fires generate a complex mixture of volatile, semivolatile, and nonvolatile compounds. This study focused on the semi/nonvolatile components of fire debris to better understand firefighter exposure risks. Using the enhanced sensitivity of gas chromatography coupled to atmospheric pressure ionization-tandem mass spectrometry (APGC-MS/MS), complex fire debris samples collected from simulation fires were analyzed for the presence of potentially toxic polyhalogenated dibenzo-p-dioxins and dibenzofurans (PXDD/Fs and PBDD/Fs). Extensive method development was performed to create multiple reaction monitoring (MRM) methods for a wide range of PXDD/Fs from dihalogenated through hexa-halogenated homologue groups. Higher halogenated compounds were not observed due to difficulty eluting them off the long column used for analysis. This methodology was able to identify both polyhalogenated (mixed bromo-/chloro- and polybromo-) dibenzo-p-dioxins and dibenzofurans in the simulated burn study samples collected, with the dibenzofuran species being the dominant compounds in the samples. Levels of these compounds were quantified as total homologue groups due to the limitations of commercial congener availability. Concentration ranges in household simulation debris were observed at 0.01-5.32 ppb (PXDFs) and 0.18-82.11 ppb (PBDFs). Concentration ranges in electronics simulation debris were observed at 0.10-175.26 ppb (PXDFs) and 0.33-9254.41 ppb (PBDFs). Samples taken from the particulate matter coating the firefighters' helmets contained some of the highest levels of dibenzofurans, ranging from 4.10 ppb to 2.35 ppm. The data suggest that firefighters and first responders at fire scenes are exposed to a complex mixture of potentially hundreds to thousands of different polyhalogenated dibenzo-p-dioxins and dibenzofurans that could negatively impact their health.

  17. Magnetic covalent triazine framework for rapid extraction of phthalate esters in plastic packaging materials followed by gas chromatography-flame ionization detection.

    Science.gov (United States)

    Yan, Zijun; He, Man; Chen, Beibei; Gui, Bo; Wang, Cheng; Hu, Bin

    2017-11-24

    Covalent triazine frameworks (CTFs), featuring with high surface area, good thermal, chemical and mechanical stability, are good adsorbents in sample pretreatment. Herein, magnetic CTFs/Ni composite was prepared by in situ reduction of nickel ions on CTFs matrix with a solvothermal method. The prepared CTFs/Ni composite exhibited good preparation reproducibility, high chemical stability, and high extraction efficiency for targeted phthalate esters (PAEs) due to π-π interaction and hydrophobic effect. The porous structure of CTFs/Ni composite benefited the fast transfer of target PAEs from aqueous solution to the adsorbents, and the integrated magnetism contributed to the rapid separation of adsorbents from sample and elution solution. Based on it, a novel method of magnetic solid phase extraction (MSPE) combined with gas chromatography-flame ionization detector (GC-FID) was developed for the analysis of PAEs including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), benzyl butyl phthalate (BBP), di-2-ethylhexl phthalate (DEHP), and di-n-octyl phthalate (DNOP) in plastic packaging materials. Under the optimal experimental conditions, the limits of detection (LODs, S/N=3) for six PAEs were found to be in the range of 0.024-0.085mg/kg. The linear range was 0.32-16mg/kg for DMP, DEP, 0.08-80mg/kg for DBP, 0.16-32mg/kg for BBP, DEHP, and 0.32-32mg/kg for DNOP, respectively. The enrichment factors ranged from 59 to 88-fold (theoretical enrichment factor was 133-fold). The proposed method was successfully applied to the analysis of PAEs in various plastic packaging materials with recoveries in the range of 70.6-119% for the spiked samples. This method is characterized with short operation time, high sensitivity, low consumption of harmful organic solvents and can be extended to the analysis of other trace aromatic compounds. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. Quantitative Analysis of Humectants in Tobacco Products Using Gas Chromatography (GC with Simultaneous Mass Spectrometry (MSD and Flame Ionization Detection (FID

    Directory of Open Access Journals (Sweden)

    Rainey CL

    2014-12-01

    Full Text Available This paper describes the modification of an existing gas chromatographic (GC method to incorporate simultaneous mass spectrometric (MSD and flame ionization detection (FID into the analysis of tobacco humectants. Glycerol, propylene glycol, and triethylene glycol were analyzed in tobacco labeled as roll-your-own (RYO, cigar, cigarette, moist snuff, and hookah tobacco. Tobacco was extracted in methanol containing 1,3-butanediol (internal standard, filtered, and separated on a 15 m megabore DB-Wax column. Post-column flow was distributed using a microfluidic splitter between the MSD and FID for simultaneous detection. The limits of detection for the FID detector were 0.5 μg/mL (propylene glycol and triethylene glycol and 0.25 μg/mL (glycerol with a linear range of 2-2000 μg/mL (propylene glycol and triethylene glycol and 1-4000 μg/mL (glycerol. The limits of detection for the MSD detector were 2 μg/mL (propylene glycol and triethylene glycol and 4 μg/mL (glycerol with a linear range of 20-2000 μg/mL (propylene glycol and triethylene glycol and 40-4000 μg/mL (glycerol. Significant improvement in the sensitivity of the MSD can be achieved by employing selective ion monitoring (SIM detection mode. Although a high degree of correlation was observed between the results from FID and MSD analyses, marginal chromatographic resolution between glycerol and triethylene glycol limits the applicability of FID to samples containing low levels of both of these humectants. Utilizing MSD greatly improves the reliability of quantitative results because compensation for inadequate chromatographic resolution can be accomplished with mass selectivity in detection.

  19. Annotation of metabolites from gas chromatography/atmospheric pressure chemical ionization tandem mass spectrometry data using an in silico generated compound database and MetFrag.

    Science.gov (United States)

    Ruttkies, Christoph; Strehmel, Nadine; Scheel, Dierk; Neumann, Steffen

    2015-08-30

    Gas chromatography (GC) coupled to atmospheric pressure chemical ionization quadrupole time-of-flight mass spectrometry (APCI-QTOFMS) is an emerging technology in metabolomics. Reference spectra for GC/APCI-MS/MS barely exist; therefore, in silico fragmentation approaches and structure databases are prerequisites for annotation. To expand the limited coverage of derivatised structures in structure databases, in silico derivatisation procedures are required. A cheminformatics workflow has been developed for in silico derivatisation of compounds found in KEGG and PubChem, and validated on the Golm Metabolome Database (GMD). To demonstrate this workflow, these in silico generated databases were applied together with MetFrag to APCI-MS/MS spectra acquired from GC/APCI-MS/MS profiles of Arabidopsis thaliana and Solanum tuberosum. The Metabolite-Likeness of the original candidate structure was included as additional scoring term aiming at candidate structures of natural origin. The validation of our in silico derivatisation workflow on the GMD showed a true positive rate of 94%. MetFrag was applied to two datasets. In silico derivatisation of the KEGG and PubChem database served as a candidate source. For both datasets the Metabolite-Likeness score improved the identification performance. The derivatised data sources have been included into the MetFrag web application for the annotation of GC/APCI-MS/MS spectra. We demonstrated that MetFrag can support the identification of components from GC/APCI-MS/MS profiles, especially in the (common) case where reference spectra are not available. This workflow can be easily adapted to other types of derivatisation and is freely accessible together with the generated structure databases. Copyright © 2015 John Wiley & Sons, Ltd.

  20. Investigation of the profile of phenolic compounds in the leaves and stems of Pandiaka heudelotii using gas chromatography coupled with flame ionization detector.

    Science.gov (United States)

    Ifeanacho, Mercy O; Ikewuchi, Catherine C; Ikewuchi, Jude C

    2017-05-01

    The profile of phenolic compounds in the leaves and stems of Pandiaka heudelotii was investigated using gas chromatography coupled with flame ionization detector. The leaves and stems had high flavonoids and benzoic acid derivatives content, and moderate levels of lignans and hydroxycinnamates. Twenty-eight known flavonoids were detected, which consisted mainly of kaempferol (41.93% in leaves and 47.97% in stems), (+)-catechin (17.12% in leaves and 16.11% in stems), quercetin (13.83% in leaves and 9.39% in stems), luteolin (7.34% in leaves and 7.71% in stems), and artemetin (6.53% in leaves and 4.83% in stems). Of the six known hydroxycinnamates detected, chlorogenic acid (80.79% in leaves and 87.56% in stems) and caffeic acid (18.98% in leaves and 12.30% in stems) were the most abundant, while arctigenin (77.81% in leaves and 83.40% in stems) and retusin (13.82% in leaves and 10.59% in stems) were the most abundant of the nine known lignans detected. Twelve known benzoic acid derivatives were detected, consisting mainly of ellagic acid (65.44% in leaves and 72.89% in stems), p-hydroxybenzoic acid (25.10% in leaves and 18.95% in stems), and vanillic acid (8.80% in leaves and 7.30% in stems). The rich phytochemical profile of the leaves and stems is an indication of their ability to serve as sources of nutraceuticals.

  1. On-line purge-and-trap-gas chromatography with flame ionization detection as an alternative analytical method for dimethyl sulphide trace release from marine algae

    Energy Technology Data Exchange (ETDEWEB)

    Careri, M.; Musci, M.; Bianchi, F.; Mucchino, C. [Parma Univ., Parma (Italy). Dipt. di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica; Azzoni, R.; Viaroli, P. [Parma Univ., Parma (Italy). Dipt. di Scienze Ambientali

    2001-10-01

    The release of dimethyl sulphide (DMS) by the seaweed Ulva spp at trace level was studied in aqueous solutions at different salinities, temperature and light intensities. For this purpose, the purge-and-trap technique combined with gas chromatography-flame ionization detection was used. The analytical method was evaluated in terms of linearity range, limit of detection, precision and accuracy by considering 10% (w/v) and 30% (w/v) synthetic seawater as aqueous matrices. Calculation of the recovery function evidenced a matrix influence. The method of standard addition was then used for an accurate determination of DMS in synthetic seawater reproduction the matrix effect. DMS fluxes were analysed in batch cultures of Ulva spp reproducing the conditions which usually occur in the Sacca di Goro lagoon (Northern Adriatic Sea, Italy). [Italian] Il rilascio di dimetilsolfuro (DMS) in tracce da parte della macroalga Ulva spp e' stato studiato in soluzioni acquose di differente salinita' mediante la tecnica purge-and-trap accoppiata on-line alla gascromatografia con rivelazione a ionizzazione di fiamma (GC-FID). Il metodo analitico e' stato validato in termini di linearita' di risposta, di limite di rivelabilita', precisione e accuratezza considerando come matrice acqua di mare sintetica a diversa salinita' (10%0 m/v e 30%0 m/v). Il calcolo della funzione di recupero ha consentito di verificare la presenza di errori sistematici dovuti all'effetto matrice. Il metodo sviluppato e' stato quindi applicato a matrici ambientali allo scopo di verificare il rilascio di DMS da parte di Ulva spp, operando in condizioni ambientali simili a quelle che si verificano nella Sacca di Goro (Ferrara, Italia).

  2. Ionization chambers

    International Nuclear Information System (INIS)

    Boag, J.W.

    1987-01-01

    Although a variety of solid-state and chemical methods for measuring radiation dose have been developed in recent decades and calorimetry can now provide an absolute standard of reference, ionization dosimetry retains its position as the most widely used, most convenient, and, in most situations, most accurate method of measuring either exposure or absorbed dose. The ionization chamber itself is the central element in this system of dosimetry. In this chapter the principles governing the construction and operation of ionization chambers of various types are examined. Since the ionization chambers now in general use are nearly all of commercial manufacture, the emphasis is on operating characteristics and interpretation of measurements rather than on details of construction, although some knowledge of the latter is often required when applying necessary corrections to the measured quantities. Examples are given of the construction of typical chambers designed for particular purposes, and the methods of calibrating them are discussed

  3. Calcium - ionized

    Science.gov (United States)

    ... diuretics Thrombocytosis (high platelet count) Tumors Vitamin A excess Vitamin D excess Lower-than-normal levels may be due to: Hypoparathyroidism Malabsorption Osteomalacia Pancreatitis Renal failure Rickets Vitamin D deficiency Alternative Names Free calcium; Ionized calcium ...

  4. Ionization detector

    International Nuclear Information System (INIS)

    Solomon, E.E.

    1980-01-01

    A safe and reliable apparatus for detecting products of combustion and aerosols in the atmosphere was developed which uses a beta source. It is easy to adjust for optimum performance. The ionization detector comprises a double chamber; one of the chambers is the basic sensing chamber. The sensing chamber is ported to both the secondary chambers to account for slow ambient changes in the atmosphere outside of the chamber. The voltages from the ionization chamber are adjusted with electrodes in each chamber. The ionization chamber contains baffles to direct the air to be sensed as well as an electrostatic screen. A unique electronic circuit provides an inexpensive and reliable means for detecting the signal change which occurs in the ionization chamber. The decision level of the alarm circuit can be adjusted to allow for any desired sensitivity. (D.N.)

  5. Collisional ionization

    International Nuclear Information System (INIS)

    Arnaud, M.

    1985-07-01

    In low density, thin plasmas (such as stellar coronae, interstellar medium, intracluster medium) the ionization process is governed by collision between electrons and ions in their ground state. In view of the recent improvements we thought an updating of ionization rates was really needed. The work is based on both experimental data and theoretical works and give separate estimates for the direct and autoionization rates

  6. Ionization chamber

    International Nuclear Information System (INIS)

    Jilbert, P.H.

    1975-01-01

    The invention concerns ionization chambers with particular reference to air-equivalent ionization chambers. In order to ensure that similar chambers have similar sensitivities and responses the surface of the chamber bounding the active volume carries a conducting material, which may be a colloidal graphite, arranged in the form of lines so that the area of the conducting material occupies only a small proportion of the area of said surface. (U.S.)

  7. Ionization current in N2 gas. Part 7. ; Diffusion and reflection of metastable particles. N2 gas chu ni okeru denri denryu. 7. ; Jun antei reiki ryushi no kakusan to hansha

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, S.; Ito, H.; Sekizawa, H. (Chiba Inst. of Technology, Chiba (Japan)); Ikuta, N. (Tokushima Univ., Tokushima (Japan))

    1993-06-20

    The energy loss process in quenching of excited particles by collision to other ones and solid surfaces was investigated with metastable excited particles formed in weakly ionized gases. The measured lifetime of N2 metastable particles in N2, N2/CO, N2/CH3 gases during Townsent discharge did not agree with the Molnar's theoretical value which was obtained by solving diffusion equations using the boundary condition that assumes the density of excited particles to be zero at electrodes and tube walls. Strange behavior was observed too, that is, coefficients of diffusion and reaction rate determined by the theoretical lifetime change systematically with the distance between electrodes. Then, the novel boundary condition that takes reflection coefficient into account was applied to solve diffusion equations. The results obtained could account for experimental results without any discrepancy. The analysis of results clarified the dependence of various parameters of metastable excited particles on the reflection coefficient. The increase of reflection coefficient decreases the surface quenching of excited particles at electrodes and elongs effectively excited lifetime and increases the number of collisional quenching in gas phases. 16 refs., 8 figs.

  8. Analytical modeling of inverted annular film boiling

    International Nuclear Information System (INIS)

    Analytis, G.T.; Yadigaroglu, G.

    1987-01-01

    By employing a two-fluid formulation similar to the one used in the most recent LWR accident analysis codes, a model for the Inverted Annular Film Boiling region is developed. The conservation equations, together with appropriate closure relations are solved numerically. Successful comparisons are made between model predictions and heat transfer coefficient distributions measured in a series of single-tube reflooding experiments. Generally, the model predicts correctly the dependence of the heat transfer coefficient on liquid subcooling and flow rate; for some cases, however, heat transfer is still under-predicted, and an enhancement of the heat exchange from the liquid-vapour interface to the bulk of the liquid is required. The importance of the initial conditions at the quench front is also discussed. (orig.)

  9. Analytical modeling of inverted annular film boiling

    International Nuclear Information System (INIS)

    Analytis, G.T.; Yadigaroglu, G.

    1985-01-01

    By employing a two-fluid formulation similar to the one used in the most recent LWR accident analysis codes, a model for the Inverted Annular Film Boiling region is developed. The conservation equations, together with appropriate constitutive relations are solved numerically and successful comparisons are made between model predictions and heat transfer coefficient distributions measured in a series of single-tube reflooding experiments. The model predicts generally correctly the dependence of the heat transfer coefficient on liquid subcooling and flow rate, through, for some cases, heat transfer is still under-predicted, and an enhancement of the heat exchange from the liquid-vapour interface to the bulk of the liquid is required

  10. The Liquid Annular Reactor System (LARS) propulsion

    International Nuclear Information System (INIS)

    Powell, J.; Ludewig, H.; Horn, F.; Lenard, R.

    1990-01-01

    A concept for very high specific impulse (greater than 2000 seconds) direct nuclear propulsion is described. The concept, termed the liquid annular reactor system (LARS), uses liquid nuclear fuel elements to heat hydrogen propellant to very high temperatures (approximately 6000 K). Operating pressure is moderate (approximately 10 atm), with the result that the outlet hydrogen is virtually 100 percent dissociated to monatomic H. The molten fuel is contained in a solid container of its own material, which is rotated to stabilize the liquid layer by centripetal force. LARS reactor designs are described, together with neutronic and thermal-hydraulic analyses. Power levels are on the order of 200 megawatts. Typically, LARS designs use seven rotating fuel elements, are beryllium moderated, and have critical radii of approximately 100 cm (core L/D approximately equal to 1.5)

  11. Flow visualization study of post critical heat flux region for inverted bubbly, slug and annular flow regimes

    International Nuclear Information System (INIS)

    Denten, J.G.; Ishii, M.

    1988-11-01

    A visual study of film boiling using still photographic and high- speed motion picture methods was carried out in order to analyze the post-CHF hydrodynamics for steady-state inlet pre-CHF two-phase flow regimes. Pre-CHF two-phase flow regimes were established by introducing Freon 113 liquid and nitrogen gas into a jet core injection nozzle. An idealized, post-CHF two-phase core initial flow geometry (cylindrical multiphase jet core surrounded by a coaxial annulus of gas) was established at the nozzle exit by introducing nitrogen gas into the annular gap between the jet nozzle two-phase effluent and the heated test section inlet. For the present study three basic post-CHF flow regimes have been observed: the rough wavy regime (inverted annular flow preliminary break down), the agitated regime (transition between inverted annular and dispersed droplet flow), and the dispersed ligament/droplet regime. For pre-CHF bubbly flow in the jet nozzle, the post-CHF flow (beginning from jet nozzle exit/heated test section inlet) consists of the rough wavy regime, followed by the agitated and then the dispersed ligament/droplet regime. In the same way, for pre-CHF slug flow in the jet core, the post-CHF flow is comprised of the agitated regime at the nozzle exit, followed by the dispersed regime. Pre-CHF annular jet core flow results in a small, depleted post-CHF agitated flow regime at the nozzle exit, immediately followed by the dispersed ligament/droplet regime. Observed post dryout hydrodynamic behavior is reported, with particular attention given to the transition flow pattern between inverted annular and dispersed droplet flow. 43 refs., 20 figs., 5 tabs

  12. A simulation of the temperature overshoot observed at high burnup in annular fuel pellets

    Energy Technology Data Exchange (ETDEWEB)

    Baron, D [Electricite de France, Moret-sur-Loing (France); Couty, J C [Electricite de France (EDF), 69 - Villeurbanne (France)

    1997-08-01

    Instrumented experiments have been carried out in recent years to calibrate and improve temperature calculations at high burnup in PWR nuclear fuel rods. The introduction of a thermocouple in the fuel stack allows the experiment to record the centre-line temperature all along the irradiation or re-irradiation. The results obtained on fresh fuel have not revealed any abnormal behavior as have observations done on high burnup rods. In this case, a sudden overshoot has been recorded on the thermocouple temperature above an average power threshold. Several hypotheses have been suggested. Only two seem to be acceptable: one in relation to an effect of grain decohesion, another based on a modification of fuel chemistry. The apparent reversibility of the phenomena when power decreases led us to prefer the first explanation. Indeed, the introduction of a thermocouple means that annular fuel pellets must be used. These are either initially manufactured with a central hole or drilled after base irradiation, using the ``RISOE`` technique. One must bear in mind that the use of such annular pellets drastically changes the crack pattern as irradiation proceeds. This is due to a different stress field which, combined with a weakening of the grain binding energy, leads to a partial grain decohesion on the inner face of the annular pellet. Modification of the grain binding energy is related to the presence of an increasing local population of gas bubbles and metallic precipitates at grain boundaries, as swelling creates intergranular local stresses which also could probably enhance the grain decohesion process. This grain decohesion concerns a 250 to 350 {mu}m depth and shows a narrow cracks network through which released fission gas can flow, temporarily pushing the resident helium gas out. The low conductivity of these gaseous fission products and the numerous gas layers created this way could partly explain the unexpected temperatures measured in high burnup fuels. (Abstract

  13. Application of FIGAERO (Filter Inlet for Gases and AEROsol) coupled to a high resolution time of flight chemical ionization mass spectrometer to field and chamber organic aerosol: Implications for carboxylic acid formation and gas-particle partitioning from monoterpene oxidation

    Science.gov (United States)

    Lopez-Hilfiker, F.; Mohr, C.; Ehn, M.; Rubach, F.; Mentel, T. F.; Kleist, E.; Wildt, J.; Thornton, J. A.

    2013-12-01

    We present measurements of a large suite of gas and particle phase carboxylic acid containing compounds made with a Filter Inlet for Gas and AEROsol (FIGAERO) coupled to a high resolution time of flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. A prototype operated with acetate negative ion proton transfer chemistry was deployed on the Julich Plant Atmosphere Chamber to study a-pinene oxidation, and a modified version was deployed at the SMEAR II forest station in Hyytiälä, Finland and SOAS, in Brent Alabama. We focus here on results from JPAC and Hyytiälä, where we utilized the same ionization method most selective towards carboxylic acids. In all locations, 100's of organic acid compounds were observed in the gas and particles and many of the same composition acids detected in the gas-phase were detected in the particles upon temperature programmed thermal desorption. Particulate organics detected by FIGAERO are highly correlated with organic aerosol mass measured by an AMS, providing additional volatility and molecular level information about collected aerosol. The fraction of a given compound measured in the particle phase follows expected trends with elemental composition, but many compounds would not be well described by an absorptive partitioning model assuming unity activity coefficients. Moreover the detailed structure in the thermal desorption signals reveals a contribution from thermal decomposition of large molecular weight organics and or oligomers with implications for partitioning measurements and model validation

  14. Physics of partially ionized plasmas

    CERN Document Server

    Krishan, Vinod

    2016-01-01

    Plasma is one of the four fundamental states of matter; the other three being solid, liquid and gas. Several components, such as molecular clouds, diffuse interstellar gas, the solar atmosphere, the Earth's ionosphere and laboratory plasmas, including fusion plasmas, constitute the partially ionized plasmas. This book discusses different aspects of partially ionized plasmas including multi-fluid description, equilibrium and types of waves. The discussion goes on to cover the reionization phase of the universe, along with a brief description of high discharge plasmas, tokomak plasmas and laser plasmas. Various elastic and inelastic collisions amongst the three particle species are also presented. In addition, the author demonstrates the novelty of partially ionized plasmas using many examples; for instance, in partially ionized plasma the magnetic induction is subjected to the ambipolar diffusion and the Hall effect, as well as the usual resistive dissipation. Also included is an observation of kinematic dynam...

  15. Surface tension effects on vertical upward annular flows in a small diameter pipe

    Energy Technology Data Exchange (ETDEWEB)

    Sadatomi, Michio, E-mail: sadatomi@mech.kumamoto-u.ac.jp [Dept. of Advanced Mechanical Systems, Kumamoto Univ., 39-1, Kurokami 2-chome, Chuou-ku, Kumamoto 860-8555 (Japan); Kawahara, Akimaro [Dept. of Advanced Mechanical Systems, Kumamoto Univ., 39-1, Kurokami 2-chome, Chuou-ku, Kumamoto 860-8555 (Japan); Suzuki, Aruta [Plant Design & Engineering Dept., Environment, Energy & Plant Headquarters, Hitachi Zosen Corporation, 7-89, Nankokita 1-chome, Suminoe-ku, Osaka, 559-8559 (Japan)

    2016-12-15

    Highlights: • Surface tension effects were clarified on annular flow in a small diameter pipe. • The mean liquid film thickness became thinner with decreasing of surface tension. • The liquid droplet fraction and the interfacial shear stress became higher with it. • New prediction methods for the above parameters were developed and validated. - Abstract: Experiments were conducted to study the surface tension effects on vertical upward annular flows in a 5 mm I.D. pipe using water and low surface tension water with a little surfactant as the test liquid and air as the test gas. Firstly, the experimental results on the mean liquid film thickness, the liquid droplet fraction and the interfacial shear stress in annular flows together with some flow pictures are presented to clarify the surface tension effects. From these, the followings are clarified: In the low surface tension case, the liquid film surface becomes rough, the liquid film thickness thin, the liquid droplet fraction high, and the interfacial shear stress high. Secondary, correlations in literatures for the respective parameters are tested against the present data. The test results show that no correlation for the respective parameters could predict well the present data. Thus, correlations are revised by accounting for the surface tension effects. The results of the experiments, the correlations tests and their revisions mentioned above are presented in the present paper.

  16. Flow visualization study of inverted annular flow of post dryout heat transfer region

    International Nuclear Information System (INIS)

    Ishii, M.; De Jarlais, G.

    1987-01-01

    The inverted annular flow is important in the area of LWR accident analysis in terms of the maximum cladding temperature and effectiveness of the emergency core cooling. However, the inverted annular flow thermal-hydraulics is not well understood due to its special heat transfer condition of film boiling. In view of this, the inverted flow is studied in detail experimentally. A new experimental apparatus has been constructed in which film boiling heat transfer can be established in a transparent test section. Data on liquid core stability, core break-up mechanism, and dispersed-core liquid slug and droplet sizes are obtained using F 113 as a test fluid. Both high speed movies and flash photographs are used. The inlet section consists of specially designed coaxial nozzles for gas and liquid such that the ideal inverted annular flow can be generated. The roll wave formation, droplet entrainment from wave crests, agitated sections with large interfacial areas, classical sinuous jet instability, jet break-up into multiple liquid ligaments and drop formation from liquid ligaments have been observed in detail. (orig.)

  17. Plasma rotation in plasma centrifuge with an annular gap

    International Nuclear Information System (INIS)

    Lee, H.Y.; Hong, S.H.

    1982-01-01

    The steady-state rotation of plasma centrifuge is theoretically analyzed to understand the physics of rotating plasma and its feasibility for isotope separation. The centriguge system under consideration consists of an annular gap between coaxial cylindrical anode and cathod in the presence of an externally-applied axial magnetic field. A problem for coupled partial differential equations describing centrifuge fields is formulated on the basis of the magnetohydrodynamic equations. Two-dimensional solutions are found analytically in the form of Fourier-Bessel series. The current density and velocity distributions are discussed in terms of the Hartmann number and the geometrical parameter of the system. At typical conditions, rotational speeds of the plasma up to the order of 10 4 m/sec are achievable, and increase either with increasing Hartmann number, or with increasing ratio of the axial length to the inner radius of the cylinder. In view of much higher speeds of rotation which can be achieved in plasma centrifuge, it is expected that its efficiency is superior to mechanically driven gas centrifuges. (Author)

  18. Annular gap measurement between pressure tube and calandria tube by eddy current technique

    International Nuclear Information System (INIS)

    Bhole, V.M.; Rastogi, P.K.; Kulkarni, P.G.

    1992-01-01

    In pressurised heavy water reactor (PHWR) major distinguishing feature is that there are number of identical fuel channels in the reactor core. Each channel consists of pressure tube of Zr-2.5 Nb or zircaloy-2 through which high temperature, high pressure primary coolant is passing. The pressure tube contains fuel. Surrounding the pressure tube there is low pressure, cool heavy water (moderator). The moderator is thermally separated from coolant by the tube which is nominally concentric with pressure tube called calandria tube. There are four garter springs in the annular gap between pressure tube and calandria tube. During the life of the reactor there are number of factors by which the pressure tube sags, most important factors are irradiation creep, thermal creep, fuel load etc. Because of the sag of pressure tube it can touch the calandria tube resulting in formation of cold spot. This leads to hydrogen concentration at that spot by which the material at that place becomes brittle and can lead to catastrophic failure of pressure tube. There is no useful access for measurement of annular gap either through the gas annular space or from exterior of calandria tube. So the annular gap was measured from inside surface of pressure tube which is accessible. Eddy current technique was used for finding the gap. The paper describe the details of split coil design of bobbin probe, selection of operating point on normalised impedance diagram by choosing frequency. Experimental results on full scale mock up, and actual gap measurement in reactor channel, are also given. (author). 7 figs

  19. Coexistence of morphea and granuloma annulare: a rare case report

    Directory of Open Access Journals (Sweden)

    Şenay Ağırgöl

    2017-11-01

    Full Text Available ABSTRACT CONTEXT: Localized scleroderma (morphea is characterized by fibrosis of skin and subcutaneous tissue. Granuloma annulare is a relatively common disease that is characterized by dermal papules and arciform plaques. CASE REPORT: Here, we present the case of a 42-year-old woman who developed granuloma annulare on the dorsum of her feet and abdominal region, and morphea on the anterior side of her lower limbs. We also discuss the etiological and pathogenetic processes that may cause the rare coexistence of these two diseases. CONCLUSION: Only a few cases in the literature have described coexistence of morphea and granuloma annulare.

  20. Validation of a qualitative screening method for pesticides in fruits and vegetables by gas chromatography quadrupole-time of flight mass spectrometry with atmospheric pressure chemical ionization

    Energy Technology Data Exchange (ETDEWEB)

    Portolés, T. [Research Institute for Pesticides and Water, University Jaume I, 12071 Castellón (Spain); RIKILT Institute of Food Safety, Wageningen University and Research Centre, Akkermaalsbos 2, 6708 WB Wageningen (Netherlands); Mol, J.G.J. [RIKILT Institute of Food Safety, Wageningen University and Research Centre, Akkermaalsbos 2, 6708 WB Wageningen (Netherlands); Sancho, J.V.; López, Francisco J. [Research Institute for Pesticides and Water, University Jaume I, 12071 Castellón (Spain); Hernández, F., E-mail: hernandf@uji.es [Research Institute for Pesticides and Water, University Jaume I, 12071 Castellón (Spain)

    2014-08-01

    Highlights: • Applicability of GC-(APCI)QTOF MS as new tool for wide-scope screening of pesticides in fruits and vegetables demonstrated. • Validation of screening method according to SANCO/12571/2013. • Detection of the pesticides based on the presence of M+·/MH+ in most cases. • Screening detection limit 0.01 mg kg{sup −1} for 77% of the pesticides investigated. • Successful identification at 0.01 mg kg{sup −1} for 70% of the pesticides/matrix combinations. - Abstract: A wide-scope screening method was developed for the detection of pesticides in fruit and vegetables. The method was based on gas chromatography coupled to a hybrid quadrupole time-of-flight mass spectrometer with an atmospheric pressure chemical ionization source (GC-(APCI)QTOF MS). A non-target acquisition was performed through two alternating scan events: one at low collision energy and another at a higher collision energy ramp (MS{sup E}). In this way, both protonated molecule and/or molecular ion together with fragment ions were obtained in a single run. Validation was performed according to SANCO/12571/2013 by analysing 20 samples (10 different commodities in duplicate), fortified with a test set of 132 pesticides at 0.01, 0.05 and 0.20 mg kg{sup −1}. For screening, the detection was based on one diagnostic ion (in most cases the protonated molecule). Overall, at the 0.01 mg kg{sup −1} level, 89% of the 2620 fortifications made were detected. The screening detection limit for individual pesticides was 0.01 mg kg{sup −1} for 77% of the pesticides investigated. The possibilities for identification according to the SANCO criteria, requiring two ions with a mass accuracy ≤±5 ppm and an ion-ratio deviation ≤±30%, were investigated. At the 0.01 mg kg{sup −1} level, identification was possible for 70% of the pesticides detected during screening. This increased to 87% and 93% at the 0.05 and 0.20 mg kg{sup −1} level, respectively. Insufficient sensitivity for the second

  1. Ionizing radiations

    International Nuclear Information System (INIS)

    Newton, W.

    1984-01-01

    The purpose of this article is to simplify some of the relevant points of legislation, biological effects and protection for the benefit of the occupational health nurse not familiar with the nuclear industries. The subject is dealt with under the following headings; Understanding atoms. What is meant by ionizing radiation. Types of ionizing radiation. Effects of radiation: long and short term somatic effects, genetic effects. Control of radiation: occupational exposure, women of reproductive age, medical aspects, principles of control. The occupational health nurse's role. Emergency arrangements: national arrangements for incidents involving radiation, action to be taken by the nurse. Decontamination procedures: external and internal contamination. (U.K.)

  2. Modelling of Churn-Annular foam flows

    NARCIS (Netherlands)

    Westende, J.M.C. van 't; Shoeibi Omrani, P.; Vercauteren, F.F.; Nennie, E.D.

    2016-01-01

    Foam assisted lift is a deliquification method in the oil and gas industry, which aims to prevent or postpone countercurrent gas-liquid flow in maturing gas wells or to assist in removing downhole accumulated liquids. According to Nimwegen, who performed experiments with foam flows, foam

  3. Gas

    International Nuclear Information System (INIS)

    1996-01-01

    The French government has decided to modify the conditions of extension of local natural gas authorities to neighbouring districts. The European Union is studying the conditions of internal gas market with the objective of more open markets although considering public service requirements

  4. Ionizing radiation

    International Nuclear Information System (INIS)

    Dennis, J.A.

    1982-01-01

    The subject is discussed under the headings: characteristics of ionizing radiations; biological effects; comparison of radiation and other industrial risks; principles of protection; cost-benefit analysis; dose limits; the control and monitoring of radiation; reference levels; emergency reference levels. (U.K.)

  5. Ionizing radiation

    Science.gov (United States)

    Tobias, C. A.; Grigoryev, Y. G.

    1975-01-01

    The biological effects of ionizing radiation encountered in space are considered. Biological experiments conducted in space and some experiences of astronauts during space flight are described. The effects of various levels of radiation exposure and the determination of permissible dosages are discussed.

  6. Two-phase flow characteristic of inverted bubbly, slug and annular flow in post-critical heat flux region

    International Nuclear Information System (INIS)

    Ishii, M.; Denten, J.P.

    1988-01-01

    Inverted annular flow can be visualized as a liquid jet-like core surrounded by a vapor annulus. While many analytical and experimental studies of heat transfer in this regime have been performed, there is very little understanding of the basic hydrodynamics of the post-CHF flow field. However, a recent experimental study was done that was able to successfully investigate the effects of various steady-state inlet flow parameters on the post-CHF hydrodynamics of the film boiling of a single phase liquid jet. This study was carried out by means of a visual photographic analysis of an idealized single phase core inverted annular flow initial geometry (single phase liquid jet core surrounded by a coaxial annulus of gas). In order to extend this study, a subsequent flow visualization of an idealized two-phase core inverted annular flow geometry (two-phase central jet core, surrounded by a coaxial annulus of gas) was carried out. The objective of this second experimental study was to investigate the effect of steady-state inlet, pre-CHF two-phase jet core parameters on the hydrodynamics of the post-CHF flow field. In actual film boiling situations, two-phase flows with net positive qualities at the CHF point are encountered. Thus, the focus of the present experimental study was on the inverted bubbly, slug, and annular flow fields in the post dryout film boiling region. Observed post dryout hydrodynamic behavior is reported. A correlation for the axial extent of the transition flow pattern between inverted annular and dispersed droplet flow (the agitated regime) is developed. It is shown to depend strongly on inlet jet core parameters and jet void fraction at the dryout point. 45 refs., 9 figs., 4 tabs

  7. Two-phase flow characteristic of inverted bubbly, slug, and annular flow in post-critical heat flux region

    International Nuclear Information System (INIS)

    Ishii, M.; Denten, J.P.

    1989-01-01

    Inverted annular flow can be visualized as a liquid jet-like core surrounded by a vapor annulus. While many analytical and experimental studies of heat transfer in this regime have been performed, there is very little understanding of the basic hydrodynamics of the post-critical heat flux (CHF) flow field. However, a recent experimental study was done that was able to successfully investigate the effects of various steady-state inlet flow parameters on the post-CHF hydrodynamics of the film boiling of a single phase liquid jet. This study was carried out by means of a visual photographic analysis of an idealized single phase core inverted annular flow initial geometry (single phase liquid jet core surrounded by a coaxial annulus of gas). In order to extend this study, a subsequent flow visualization of an idealized two-phase core inverted annular flow geometry (two-phase central jet core, surrounded by a coaxial annulus of gas) was carried out. The objective of this second experimental study was to investigate the effect of steady-state inlet, pre-CHF two-phase jet core parameters on the hydrodynamics of the post-CHF flow field. In actual film boiling situations, two-phase flows with net positive qualities at the CHF point are encountered. Thus, the focus of the present experimental study was on the inverted bubbly, slug, and annular flow fields in the post dryout film boiling region. Observed post dryout hydrodynamic behavior is reported. A correlation for the axial extent of the transition flow pattern between inverted annular and dispersed droplet flow (the agitated regime) is developed. It is shown to depend strongly on inlet jet core parameters and jet void fraction at the dryout point

  8. Two suicidal fatalities due to the ingestion of chlorfenvinphos formulations: simultaneous determination of the pesticide and the petroleum distillates in tissues by gas chromatography-flame-ionization detection and gas chromatography-mass spectrometry.

    Science.gov (United States)

    Martínez, María A; Ballesteros, Salomé

    2012-01-01

    Chlorfenvinphos (CFVP) is an organophosporus insecticide designated as a threat agent by the National Institutes of Health (NIH). However, there are very few reported cases of poisonings in humans and none with postmortem toxicological analysis. We report the first two fatalities due to suicidal massive ingestion of a veterinary formulation containing CFVP and petroleum distillates. Case 1: A 24-year-old woman was found dead by her mother. According to the police records, the room was filled with an odor of solvents or pesticides and feces. There was an empty bottle of Supona(®) near the body and a suicide note on a Bible on a table. The only relevant postmortem finding was that the lungs appeared congested and edematous. Case 2: A 60-year-old man committed in his van by ingesting an unknown product. The vehicle was locked and had an odor that resembled an acid, sulfate, or solvent according to different witnesses. There was a suicide note as well as multiple containers containing automobile products nearby. The stomach of the victim was filled with abundant pale greenish fluid with a similar odor to that presented in the vehicle. The simultaneous toxicological screening and quantitation of CFVP and petroleum distillates [a mixture of trimethylbenzene isomers (TMBs)] was performed by means of gas chromatography with flame-ionization detection (GC-FID) and confirmation was performed using gas chromatography-mass spectrometry (GC-MS). Disposition of CFVP and TMBs in different tissues were, respectively, as follows: Case 1: heart blood, 8.6 and 3.7 mg/L; liver, 60.0 and 33.4 mg/kg; and stomach contents, 1132 mg/L (792.4 mg total) and 377.0 mg/L (263.9 mg total). Case 2: heart blood, 4.4 and 6.5 mg/L; urine, 1.4 and detected (distillates suitable for toxicological investigation in forensic and clinical cases. This is crucial to solving poisoning cases in which the poisoning source is uncertain.

  9. Annular linear induction pump with an externally supported duct

    International Nuclear Information System (INIS)

    1980-01-01

    An annular linear induction pump of increased efficiency is described, capable of being readily disassembled for repair or replacement of parts, and having one pass flow of the liquid metal through the pump. (U.K.)

  10. Deep Granuloma Annulare Mimicking Inflamed Cysts in a Teenager.

    Science.gov (United States)

    Guo, Emily L; Degesys, Catherine A; Jahan-Tigh, Richard; Chan, Audrey

    2017-07-01

    We describe deep granuloma annulare (DGA) of the forehead mimicking inflamed cysts. Reactive inflammation and sterile purulent drainage may be an underrecognized feature of DGA. © 2017 Wiley Periodicals, Inc.

  11. Interfacial friction in low flowrate vertical annular flow

    International Nuclear Information System (INIS)

    Kelly, J.M.; Freitas, R.L.

    1993-01-01

    During boil-off and reflood transients in nuclear reactors, the core liquid inventory and inlet flowrate are largely determined by the interfacial friction in the reactor core. For these transients, annular flow occurs at relatively modest liquid flowrates and at the low heat fluxes typical of decay heat conditions. The resulting low vapor Reynolds numbers, are out of the data range used to develop the generally accepted interfacial friction relations for annular flow. In addition, most existing annular flow data comes from air/liquid adiabatic experiments with fully developed flows. By contrast, in a reactor core, the flow is continuously developing along the heated length as the vapor flowrate increases and the flow regimes evolve from bubbly to annular flow. Indeed, the entire annular flow regime may exist only over tens of L/D's. Despite these limitations, many of the advanced reactor safety analysis codes employ the Wallis model for interfacial friction in annular flow. Our analyses of the conditions existing at the end-of-reflood in the PERICLES tests have indicated that the Wallis model seriously underestimates the interfacial shear for low vapor velocity cocurrent upflow. To extend the annular flow data base to diabatic low flowrate conditions, the DADINE tests were re-analyzed. In these tests, both pressure drop and local cross-section averaged void fractions were measured. Thus, both the wall and interfacial shear can be deduced. Based on the results of this analysis, a new correlation is proposed for interfacial friction in annular flow. (authors). 5 figs., 12 refs

  12. Magnetohydrodynamic instability in annular linear induction pump

    International Nuclear Information System (INIS)

    Araseki, Hideo; Kirillov, Igor R.; Preslitsky, Gennady V.; Ogorodnikov, Anatoly P.

    2006-01-01

    In the previous work, the authors showed some detailed aspects of the magnetohydrodynamic instability arising in an annular linear induction pump: the instability is accompanied with a low frequency pressure pulsation in the range of 0-10 Hz when the magnetic Reynolds number is larger than unity; the low frequency pressure pulsation is produced by the sodium vortices that come from some azimuthal non-uniformity of the applied magnetic field or of the sodium inlet velocity. In the present work, an experiment and a numerical analysis are carried out to verify the pump winding phase shift that is expected as an effective way to suppress the instability. The experimental data shows that the phase shift suppresses the instability unless the slip value is so high, but brings about a decrease of the developed pressure. The numerical results indicate that the phase shift causes a local decrease of the electromagnetic force, which results in the suppression of the instability and the decrease of the developed pressure. In addition, it is exhibited that the intensity of the double-supply-frequency pressure pulsation is in nearly the same level in the case with and without the phase shift

  13. Sonographic evaluation of digital annular pulley tears

    International Nuclear Information System (INIS)

    Martinoli, C.; Derchi, L.E.; Bianchi, S.; Garcia, J.F.; Nebiolo, M.

    2000-01-01

    Objective. To evaluate the sonographic (US) appearance of digital annular pulley (DAP) tears in high-level rock climbers. Design and patients. We performed a retrospective analysis of the US examinations of 16 high-level rock climbers with clinical signs of DAP lesions. MRI and surgical evaluation were performed in five and three patients respectively. The normal US and MRI appearances of DAP were evaluated in 40 and three normal fingers respectively. Results. Nine of 16 patients presented a DAP tear. In eight subjects (seven with complete tears involving the fourth finger and one the fifth finger), US diagnosis was based on the indirect sign of volar bowstringing of the flexor tendons. Injured pulleys were not appreciated by US. Tears concerned the A2 and A3 in six patients and the A3 and A4 in two patients. A2 pulley thickening and hypoechogenicity compatible with a partial tear was demonstrated in one patient. MRI and surgical data correlated well with the US findings. Four patients had tenosynovitis of the flexor tendons but no evidence of pulley disruption. US examinations of three patients were normal. In the healthy subjects US demonstrated DAP in 16 of 40 digits. Conclusion. US can diagnose DAP tears and correlates with the MRI and surgical data. Because of its low cost and non-invasiveness we suggest US as the first imaging modality in the evaluation of injuries of the digital pulley. (orig.)

  14. Sonographic evaluation of digital annular pulley tears

    Energy Technology Data Exchange (ETDEWEB)

    Martinoli, C.; Derchi, L.E. [Istituto di Radiologia, Universita di Genova, Genoa (Italy); Bianchi, S.; Garcia, J.F. [Dept. de Radiologie, Hopital Cantonal Universitaire de Geneve (Switzerland); Nebiolo, M. [Reparto Pronto Soccorso Medico, Pietra Ligure (Italy)

    2000-07-01

    Objective. To evaluate the sonographic (US) appearance of digital annular pulley (DAP) tears in high-level rock climbers. Design and patients. We performed a retrospective analysis of the US examinations of 16 high-level rock climbers with clinical signs of DAP lesions. MRI and surgical evaluation were performed in five and three patients respectively. The normal US and MRI appearances of DAP were evaluated in 40 and three normal fingers respectively. Results. Nine of 16 patients presented a DAP tear. In eight subjects (seven with complete tears involving the fourth finger and one the fifth finger), US diagnosis was based on the indirect sign of volar bowstringing of the flexor tendons. Injured pulleys were not appreciated by US. Tears concerned the A2 and A3 in six patients and the A3 and A4 in two patients. A2 pulley thickening and hypoechogenicity compatible with a partial tear was demonstrated in one patient. MRI and surgical data correlated well with the US findings. Four patients had tenosynovitis of the flexor tendons but no evidence of pulley disruption. US examinations of three patients were normal. In the healthy subjects US demonstrated DAP in 16 of 40 digits. Conclusion. US can diagnose DAP tears and correlates with the MRI and surgical data. Because of its low cost and non-invasiveness we suggest US as the first imaging modality in the evaluation of injuries of the digital pulley. (orig.)

  15. Impulsively started, steady and pulsated annular inflows

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Raouf, Emad [General Field Engineer, Halliburton Energy Services 719 Hangar Dr, New Iberia, LA 70560, United States of America (United States); Sharif, Muhammad A R; Baker, John, E-mail: abdelraouf.em@gmail.com, E-mail: msharif@eng.ua.edu, E-mail: john.baker@eng.ua.edu [Aerospace Engineering and Mechanics Department, The University of Alabama, Tuscaloosa, Alabama 35487, United States of America (United States)

    2017-04-15

    A computational investigation was carried out on low Reynolds number laminar inflow starting annular jets using multiple blocking ratios and atmospheric ambient conditions. The jet exit velocity conditions are imposed as steady, unit pulsed, and sinusoidal pulsed while the jet surroundings and the far-field jet inlet upstream conditions are left atmospheric. The reason is to examine the flow behavior in and around the jet inlet under these conditions. The pulsation mode behavior is analyzed based on the resultant of the momentum and pressure forces at the entry of the annulus, the circulation and vortex formation, and the propulsion efficiency of the inflow jets. The results show that under certain conditions, the net force of inflow jets (sinusoidal pulsed jets in particular) could point opposite to the flow direction due to the adverse pressure drops in the flow. The propulsion efficiency is also found to increase with pulsation frequency and the sinusoidal pulsed inflow jets are more efficient than the unit pulsed inflow jets. In addition, steady inflow jets did not trigger the formation of vortices, while unit and sinusoidal pulsed inflow jets triggered the formation of vortices under a certain range of frequencies. (paper)

  16. Gridded ionization chamber

    International Nuclear Information System (INIS)

    Houston, J.M.

    1977-01-01

    An improved ionization chamber type x-ray detector comprises a heavy gas at high pressure disposed between an anode and a cathode. An open grid structure is disposed adjacent the anode and is maintained at a voltsge intermediate between the cathode and anode potentials. The electric field which is produced by positive ions drifting toward the cathode is thus shielded from the anode. Current measuring circuits connected to the anode are, therefore, responsive only to electron current flow within the chamber and the recovery time of the chamber is shortened. The grid structure also serves to shield the anode from electrical currents which might otherwise be induced by mechanical vibrations in the ionization chamber structure

  17. Efficient ionizer for polarized H- formation

    International Nuclear Information System (INIS)

    Alessi, J.G.

    1985-01-01

    An ionizer is under development for a polarized H - source based on the resonant charge exchange reaction polarized H 0 + D - → polarized H - + D 0 . The polarized H 0 beam passes through the center of a magnetron surface-plasma source having an annular geometry, where it crosses a high current (approx.0.5 A), 200 eV D - beam. Calculations predict an H 0 → H - ionization efficiency of approx.7%, more than an order of magnitude higher than that obtained on present ground state atomic beam sources. In initial experiments using an unpolarized H 0 beam, H - currents in excess of 100 μA have been measured. While the ionization efficiency is now only about the same as other methods (Cs beam, for example), the results are encouraging since it appears that by injecting positive ions to improve the space-charge neutralization, and by improving the extraction optics, considerable gains in intensity will be made. We will then use this ionizer with a polarized H 0 beam, and measure the polarization of the resulting H - beam. If no depolarization is observed this ionizer will be combined with an atomic beam, cooled to 5 to 6 K, to give a polarized H - beam expected to be in the milliampere range for use in the AGS

  18. Ionization detectors, ch. 3

    International Nuclear Information System (INIS)

    Sevcik, J.

    1976-01-01

    Most measuring devices used in gas chromatography consist of detectors that measure the ionization current. The process is based on the collision of a moving high-energy particle with a target particle that is ionised while an electron is freed. The discussion of the conditions of the collision reaction, the properties of the colliding particles, and the intensity of the applied field point to a unified classification of ionisation detectors. Radioactive sources suitable for use in these detectors are surveyed. The slow-down mechanism, recombination and background current effect are discussed

  19. Negative chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    Smit, A.L.C.

    1979-01-01

    This thesis describes some aspects of Negative Chemical Ionization (NCI) mass spectrometry. The reasons for the growing interest in NCI are: (i) to extend the basic knowledge of negative ions and their reactions in the gas phase; (ii) to investigate whether or not this knowledge of negative ions can be used successfully to elucidate the structure of molecules by mass spectrometry. (Auth.)

  20. Numerical investigation of a perturbed swirling annular two-phase jet

    Energy Technology Data Exchange (ETDEWEB)

    Siamas, George A. [Mechanical Engineering, School of Engineering and Design, Brunel University, Uxbridge UB8 3PH (United Kingdom)], E-mail: siamas@spidernet.com.cy; Jiang, Xi; Wrobel, Luiz C. [Mechanical Engineering, School of Engineering and Design, Brunel University, Uxbridge UB8 3PH (United Kingdom)

    2009-06-15

    A swirling annular gas-liquid two-phase jet flow system has been investigated by solving the compressible, time-dependent, non-dimensional Navier-Stokes equations using highly accurate numerical methods. The mathematical formulation for the flow system is based on an Eulerian approach with mixed-fluid treatment while an adjusted volume of fluid method is utilised to account for the gas compressibility. Surface tension effects are captured by a continuum surface force model. Swirling motion is applied at the inlet while a small helical perturbation is also applied to initiate the instability. Three-dimensional spatial direct numerical simulation has been performed with parallelisation of the code based on domain decomposition. The results show that the flow is characterised by a geometrical recirculation zone adjacent to the nozzle exit and by a central recirculation zone further downstream. Swirl enhances the flow instability and vorticity and promotes liquid dispersion in the cross-streamwise directions. A dynamic precessing vortex core is developed demonstrating that the growth of such a vortex in annular configurations can be initiated even at low swirl numbers, in agreement with experimental findings. Analysis of the averaged results revealed the existence of a geometrical recirculation zone and a swirl induced central recirculation zone in the flow field.

  1. Ionization detector

    International Nuclear Information System (INIS)

    Steele, D.S.

    1987-01-01

    An ionization detector having an array of detectors has, for example, grounding pads positioned in the spaces between some detectors (data detectors) and other detectors (reference detectors). The grounding pads are kept at zero electric potential, i.e. grounded. The grounding serves to drain away electrons and thereby prevent an unwanted accumulation of charge in the spaces, and cause the electric field lines to be more perpendicular to the detectors in regions near the grounding pads. Alternatively, no empty space is provided there being additional, grounded, detectors provided between the data and reference detectors. (author)

  2. Mixing and NOx Emission Calculations of Confined Reacting Jet Flows in Cylindrical and Annular Ducts

    Science.gov (United States)

    Oechsle, Victor L.; Connor, Christopher H.; Holdeman, James D. (Technical Monitor)

    2000-01-01

    Rapid mixing of cold lateral jets with hot cross-stream flows in confined configurations is of practical interest in gas turbine combustors as it strongly affects combustor exit temperature quality, and gaseous emissions in for example rich-lean combustion. It is therefore important to further improve our fundamental understanding of the important processes of dilution jet mixing especially when the injected jet mass flow rate exceeds that of the cross-stream. The results reported in this report describe some of the main flow characteristics which develop in the mixing process in a cylindrical duct. A three-dimensional computational fluid dynamics (CFD) code has been used to predict the mixing flow field characteristics and NOx emission in a quench section of a rich-burn/quick-mix/lean-burn (RQL) combustor. Sixty configurations have been analyzed in both circular and annular geometries in a fully reacting environment simulating the operating condition of an actual RQL gas turbine combustion liner. The evaluation matrix was constructed by varying the number of orifices per row and orifice shape. Other parameters such as J (momentum-flux ratio), MR (mass flowrate ratio), DR (density ratio), and mixer sector orifice ACd (effective orifice area) were maintained constant throughout the entire study. The results indicate that the mixing flow field can be correlated with the NOx production if they are referenced with the stoichiometric equivalence ratio value and not the equilibrium value. The mixing flowfields in both circular and annular mixers are different. The penetration of equal jets in both annular and circular geometries is vastly different which significantly affects the performance of the mixing section. In the computational results with the circular mixer, most of the NOx formation occurred behind the orifice starting at the orifice wake region. General trends have been observed in the NOx production as the number of orifices is changed and this appears to be

  3. Reference ionization chamber

    International Nuclear Information System (INIS)

    Golnik, N.; Zielczynski, M.

    1999-01-01

    The paper presents the design of ionization chamber devoted for the determination of the absolute value of the absorbed dose in tissue-equivalent material. The special attention was paid to ensure that the volume of the active gas cavity was constant and well known. A specific property of the chamber design is that the voltage insulators are 'invisible' from any point of the active volume. Such configuration ensures a very good time stability of the electrical field and defines the active volume. The active volume of the chamber was determined with accuracy of 0.3%. This resulted in accuracy of 0.8% in determination of the absorbed dose in the layer of material adherent to the gas cavity. The chamber was applied for calibration purposes at radiotherapy facility in Joint Institute for Nuclear Research in Dubna (Russia) and in the calibration laboratory of the Institute of Atomic Energy in Swierk. (author)

  4. Measurement of the rate of droplet deposition in vertical upward and downward annular flows

    International Nuclear Information System (INIS)

    Murakami, Toshihiro; Okawa, Tomio; Takei, Rei

    2008-01-01

    The deposition rate of droplets was measured for vertical annular two-phase flows in a small diameter tube by means of the double film extraction technique. The test section was a round tube of 5 mm in inside diameter, air and water were used as test fluids, and the flow direction was set to upward and downward; the system pressure and the flow rates of gas and liquid phases were changed parametrically. If the droplet velocity relative to the continuous gas phase is in the equilibrium state, the shear induced lift force acting on droplets is directed toward the tube centerline in upflow while toward the tube wall in downflow. Particular attention was therefore paid to the effect of flow direction. It was shown experimentally that the deposition rate of droplets in downward flow is greater than that in upward flow. The difference in the measured deposition rate may be attributed to the direction of lift force acting on droplets. (author)

  5. Experimental study of horizontal annular channels under non-developed conditions

    International Nuclear Information System (INIS)

    Delgadino, G.; Balino, J.; Carrica, P.

    1995-01-01

    In this work an experimental study of the two-phase air-water flow in a horizontal annular channel under non-developed conditions is presented. A conductive local probe was placed at the end of the channel to measure the local phase indication function under a wide range of gas and water flow rates. The signal was processed to obtain the void fraction and statistical distributions of liquid and gas residence times. From these data the topology of the flow could be inferred. A laser intermittence detector was also located close to the channel exit, in order to measure statistical parameters for intermittent flows by means of a two-probe method

  6. Experimental study of horizontal annular channels under non-developed conditions

    Energy Technology Data Exchange (ETDEWEB)

    Delgadino, G. [Rensselaer Polytechnic Institute, Troy, NY (United States); Balino, J.; Carrica, P. [Centro Atomico Bariloche e Instituto Balseriro (Argentina)

    1995-09-01

    In this work an experimental study of the two-phase air-water flow in a horizontal annular channel under non-developed conditions is presented. A conductive local probe was placed at the end of the channel to measure the local phase indication function under a wide range of gas and water flow rates. The signal was processed to obtain the void fraction and statistical distributions of liquid and gas residence times. From these data the topology of the flow could be inferred. A laser intermittence detector was also located close to the channel exit, in order to measure statistical parameters for intermittent flows by means of a two-probe method.

  7. Vibration Analysis of Annular Sector Plates under Different Boundary Conditions

    Directory of Open Access Journals (Sweden)

    Dongyan Shi

    2014-01-01

    Full Text Available An analytical framework is developed for the vibration analysis of annular sector plates with general elastic restraints along each edge of plates. Regardless of boundary conditions, the displacement solution is invariably expressed as a new form of trigonometric expansion with accelerated convergence. The expansion coefficients are treated as the generalized coordinates and determined using the Rayleigh-Ritz technique. This work allows a capability of modeling annular sector plates under a variety of boundary conditions and changing the boundary conditions as easily as modifying the material properties or dimensions of the plates. Of equal importance, the proposed approach is universally applicable to annular sector plates of any inclusion angles up to 2π. The reliability and accuracy of the current method are adequately validated through numerical examples.

  8. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

  9. An Experimental Study of Swirling Flows as Applied to Annular Combustors

    Science.gov (United States)

    Seal, Michael Damian, II

    1997-01-01

    This thesis presents an experimental study of swirling flows with direct applications to gas turbine combustors. Two separate flowfields were investigated: a round, swirling jet and a non-combusting annular combustor model. These studies were intended to allow both a further understanding of the behavior of general swirling flow characteristics, such as the recirculation zone, as well as to provide a base for the development of computational models. In order to determine the characteristics of swirling flows the concentration fields of a round, swirling jet were analyzed for varying amount of swirl. The experimental method used was a light scattering concentration measurement technique known as marker nephelometry. Results indicated the formation of a zone of recirculating fluid for swirl ratios (rotational speed x jet radius over mass average axial velocity) above a certain critical value. The size of this recirculation zone, as well as the spread angle of the jet, was found to increase with increase in the amount of applied swirl. The annular combustor model flowfield simulated the cold-flow characteristics of typical current annular combustors: swirl, recirculation, primary air cross jets and high levels of turbulence. The measurements in the combustor model made by the Laser Doppler Velocimetry technique, allowed the evaluation of the mean and rms velocities in the three coordinate directions, one Reynold's shear stress component and the turbulence kinetic energy: The primary cross jets were found to have a very strong effect on both the mean and turbulence flowfields. These cross jets, along with a large step change in area and wall jet inlet flow pattern, reduced the overall swirl in the test section to negligible levels. The formation of the strong recirculation zone is due mainly to the cross jets and the large step change in area. The cross jets were also found to drive a four-celled vortex-type motion (parallel to the combustor longitudinal axis) near the

  10. Patch Type Granuloma Annulare Imitating Cutaneous T-Cell Lymphoma

    Directory of Open Access Journals (Sweden)

    Şeval Doğruk Kaçar

    2015-03-01

    Full Text Available Granuloma annulare (GA is a benign inflammatory skin disease with distinct clinical and histopathological findings. Patch type GA is described with erythematous patches beyond the classical clinical appearance and an interstitial pattern is observed without histopathologically granulomas with disseminated histiocytes among collagen bundles and vessels. Here we report 46 year old woman diagnosed as patch type GA after a punch biopsy performed from the annular bordered patches in belly area, which is a classical area for mycosis fungoides (MF evolution, and lesions increasingly spreading out within a 2 year period.

  11. A void fraction model for annular two-phase flow

    Energy Technology Data Exchange (ETDEWEB)

    Tandon, T.N.; Gupta, C.P.; Varma, H.K.

    1985-01-01

    An analytical model has been developed for predicting void fraction in two-phase annular flow. In the analysis, the Lockhart-Martinelli method has been used to calculate two-phase frictional pressure drop and von Karman's universal velocity profile is used to represent the velocity distribution in the annular liquid film. Void fractions predicted by the proposed model are generally in good agreement with a available experimental data. This model appears to be as good as Smith's correlation and better than the Wallis and Zivi correlations for computing void fraction.

  12. Mitral-aortic annular enlargement: modification of Manouguian's technique

    Directory of Open Access Journals (Sweden)

    Costa Mario Gesteira

    2002-01-01

    Full Text Available We hereby present a technical modification for mitral-aortic annular enlargement. The mitral valve is replaced through the retro-septal approach, avoiding patches for left atrial roof closure. We report a mitral-aortic valve replacement in a patient whose original annuli would preclude adequate prostheses. The simultaneous annular enlargement may be necessary for avoiding patient-prosthesis mismatch and for reconstructing destroyed mitral and aortic annuli. The technique may minimize the risk of bleeding and of paravalvular leakage, using an approach well known to cardiac surgeons.

  13. Ionizing radiations

    International Nuclear Information System (INIS)

    2009-01-01

    After having recalled some fundamental notions and measurement units related to ionizing radiations, this document describes various aspects of natural and occupational exposures: exposure modes and sources, exposure levels, biological effects, health impacts. Then, it presents prevention principles aimed at, in an occupational context of use of radiation sources (nuclear industry excluded), reducing and managing these exposures: risk assessment, implementation of safety from the front end. Some practical cases illustrate the radiation protection approach. The legal and regulatory framework is presented: general notions, worker exposure, measures specific to some worker categories (pregnant and breast feeding women, young workers, temporary workers). A last part describes what is to be done in case of incident or accident (dissemination of radioactive substances from unsealed sources, anomaly occurring when using a generator or a sealed source, post-accident situation)

  14. A simulation of the temperature overshoot observed at high burnup in annular fuel pellets

    International Nuclear Information System (INIS)

    Baron, D.; Couty, J.C.

    1997-01-01

    Instrumented experiments have been carried out in recent years to calibrate and improve temperature calculations at high burnup in PWR nuclear fuel rods. The introduction of a thermocouple in the fuel stack allows the experiment to record the centre-line temperature all along the irradiation or re-irradiation. The results obtained on fresh fuel have not revealed any abnormal behavior as have observations done on high burnup rods. In this case, a sudden overshoot has been recorded on the thermocouple temperature above an average power threshold. Several hypotheses have been suggested. Only two seem to be acceptable: one in relation to an effect of grain decohesion, another based on a modification of fuel chemistry. The apparent reversibility of the phenomena when power decreases led us to prefer the first explanation. Indeed, the introduction of a thermocouple means that annular fuel pellets must be used. These are either initially manufactured with a central hole or drilled after base irradiation, using the ''RISOE'' technique. One must bear in mind that the use of such annular pellets drastically changes the crack pattern as irradiation proceeds. This is due to a different stress field which, combined with a weakening of the grain binding energy, leads to a partial grain decohesion on the inner face of the annular pellet. Modification of the grain binding energy is related to the presence of an increasing local population of gas bubbles and metallic precipitates at grain boundaries, as swelling creates intergranular local stresses which also could probably enhance the grain decohesion process. This grain decohesion concerns a 250 to 350 μm depth and shows a narrow cracks network through which released fission gas can flow, temporarily pushing the resident helium gas out. The low conductivity of these gaseous fission products and the numerous gas layers created this way could partly explain the unexpected temperatures measured in high burnup fuels. The purpose of

  15. The theory of ionizing shock waves in a magnetic field

    International Nuclear Information System (INIS)

    Liberman, M.A.; Velikovich, A.L.

    1981-01-01

    The general theory of ionizing shock waves in a magnetic field is constructed. The theory takes into account precursor ionization of a neutral gas ahead of the shock wave front, caused by photo-ionization, as well as by the impact ionization with electrons accelerated by a transverse electric field induced by the shock front in the incident flow of a neutral gas. The concept of shock wave ionization stability, being basic in the theory of ionizing shock waves in a magnetic field, is introduced. The ionizing shock wave structures are shown to transform from the GD regime at a low shock velocity to the MHD regime at an enhanced intensity of the shock wave. The abruptness of such a transition is determined by precursor photo-ionization. (author)

  16. Study of gas-puff Z-pinches on COBRA

    Energy Technology Data Exchange (ETDEWEB)

    Qi, N.; Rosenberg, E. W.; Gourdain, P. A.; Grouchy, P. W. L. de; Kusse, B. R.; Hammer, D. A.; Bell, K. S.; Shelkovenko, T. A.; Potter, W. M.; Atoyan, L.; Cahill, A. D.; Evans, M.; Greenly, J. B.; Hoyt, C. L.; Pikuz, S. A.; Schrafel, P. C. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); Kroupp, E.; Fisher, A.; Maron, Y. [Weizmann Institute of Science, Rehovot 76100 (Israel)

    2014-11-15

    Gas-puff Z-pinch experiments were conducted on the 1 MA, 200 ns pulse duration Cornell Beam Research Accelerator (COBRA) pulsed power generator in order to achieve an understanding of the dynamics and instability development in the imploding and stagnating plasma. The triple-nozzle gas-puff valve, pre-ionizer, and load hardware are described. Specific diagnostics for the gas-puff experiments, including a Planar Laser Induced Fluorescence system for measuring the radial neutral density profiles along with a Laser Shearing Interferometer and Laser Wavefront Analyzer for electron density measurements, are also described. The results of a series of experiments using two annular argon (Ar) and/or neon (Ne) gas shells (puff-on-puff) with or without an on- (or near-) axis wire are presented. For all of these experiments, plenum pressures were adjusted to hold the radial mass density profile as similar as possible. Initial implosion stability studies were performed using various combinations of the heavier (Ar) and lighter (Ne) gasses. Implosions with Ne in the outer shell and Ar in the inner were more stable than the opposite arrangement. Current waveforms can be adjusted on COBRA and it was found that the particular shape of the 200 ns current pulse affected on the duration and diameter of the stagnated pinched column and the x-ray yield.

  17. Upgrade of the Annular Core Pulse Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Reuscher, J A [Sandia Laboratories, Albuquerque, NM (United States)

    1976-07-01

    The Annular Core Pulse Reactor (ACPR) is a TRIGA type reactor which has been in operation at Sandia Laboratories since 1967. The reactor is utilized in a wide variety of experimental programs which include radiation effects, neutron radiography, activation analysis, and fast reactor safety. During the past two years, the ACPR has become an important experimental facility for the United States Fast Reactor Safety Research Program and questions of interest to the safety of the LMFBR are being addressed. In order to enhance the capabilities of the ACPR for reactor safety experiments, a project to improve the performance of the reactor was initiated. It is anticipated that the pulse fluence can be increased by a factor of 2.0 to 2.5 by utilizing a two-region core concept with high heat capacity fuel elements around the central irradiation cavity. In addition, the steady-state power of the reactor will be increased by about a factor of two. Preliminary studies have identified several potential approaches to the ACPR performance improvement. The most promising approach appears to be the two-region core concept. The inner region, surrounding the irradiation cavity, would consist of a high-heat capacity fuel capable of absorbing the fission energy associated with a large nuclear pulse. The number of fissions occurring near the cavity would be greatly increased which, in turn, would significantly increase the fluence in the cavity. The outer region would consist of a U-ZrH fuel to provide an overall negative temperature coefficient for the two region core. Two candidate high heat capacity fuels [(BeO-UO{sub 2} and UC-ZrC) - graphite] are under consideration. Since this reactor upgrade represents a modification to an existing facility, it can be achieved in a relatively short time. It is anticipated that most of the existing reactor structure can be used for the upgrade. The present core occupies about one-half of the location in the grid plate. The high-heat capacity fuel

  18. GAS-PHASE SYNTHESIS OF PRECURSORS OF INTERSTELLAR GLYCINE: A COMPUTATIONAL STUDY OF THE REACTIONS OF ACETIC ACID WITH HYDROXYLAMINE AND ITS IONIZED AND PROTONATED DERIVATIVES

    Energy Technology Data Exchange (ETDEWEB)

    Barrientos, Carmen; Redondo, Pilar; Largo, Laura; Rayon, Victor M.; Largo, Antonio, E-mail: alargo@qf.uva.es [Departamento de Quimica Fisica y Quimica Inorganica, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid (Spain)

    2012-04-01

    A computational study of the reactions of hydroxylamine and its ionized and protonated derivatives with acetic acid is provided. The reaction of neutral hydroxylamine with acetic acid, despite being clearly exothermic, involves a very large energy barrier. The reaction of ionized hydroxylamine with acetic acid is also clearly exothermic, but again a significant energy barrier is found (around 24 kcal mol{sup -1} at the CCSD(T) level). The reaction of the most stable protonated isomer of hydroxylamine, NH{sub 3}OH{sup +}, with acetic acid also involves a high barrier (more than 27 kcal mol{sup -1} at the CCSD(T) level). Only the higher energy isomer, NH{sub 2}OH{sup +}{sub 2}, leads to a sensibly lower energy barrier (about 2.3 kcal mol{sup -1} at the CCSD(T) level). Nevertheless, an estimate of the reaction coefficient at low temperatures such as those reigning in the interstellar medium gives very low values. Therefore, it seems that precursors of interstellar glycine could not be efficiently produced from the reactions of hydroxylamine-derived ions with acetic acid.

  19. GAS-PHASE SYNTHESIS OF PRECURSORS OF INTERSTELLAR GLYCINE: A COMPUTATIONAL STUDY OF THE REACTIONS OF ACETIC ACID WITH HYDROXYLAMINE AND ITS IONIZED AND PROTONATED DERIVATIVES

    International Nuclear Information System (INIS)

    Barrientos, Carmen; Redondo, Pilar; Largo, Laura; Rayón, Víctor M.; Largo, Antonio

    2012-01-01

    A computational study of the reactions of hydroxylamine and its ionized and protonated derivatives with acetic acid is provided. The reaction of neutral hydroxylamine with acetic acid, despite being clearly exothermic, involves a very large energy barrier. The reaction of ionized hydroxylamine with acetic acid is also clearly exothermic, but again a significant energy barrier is found (around 24 kcal mol –1 at the CCSD(T) level). The reaction of the most stable protonated isomer of hydroxylamine, NH 3 OH + , with acetic acid also involves a high barrier (more than 27 kcal mol –1 at the CCSD(T) level). Only the higher energy isomer, NH 2 OH + 2 , leads to a sensibly lower energy barrier (about 2.3 kcal mol –1 at the CCSD(T) level). Nevertheless, an estimate of the reaction coefficient at low temperatures such as those reigning in the interstellar medium gives very low values. Therefore, it seems that precursors of interstellar glycine could not be efficiently produced from the reactions of hydroxylamine-derived ions with acetic acid.

  20. Influence of the burner swirl on the azimuthal instabilities in an annular combustor

    Science.gov (United States)

    Mazur, Marek; Nygård, Håkon; Worth, Nicholas; Dawson, James

    2017-11-01

    Improving our fundamental understanding of thermoacoustic instabilities will aid the development of new low emission gas turbine combustors. In the present investigation the effects of swirl on the self-excited azimuthal combustion instabilities in a multi-burner annular annular combustor are investigated experimentally. Each of the burners features a bluff body and a swirler to stabilize the flame. The combustor is operated with an ethylene-air premixture at powers up to 100 kW. The swirl number of the burners is varied in these tests. For each case, dynamic pressure measurements at different azimuthal positions, as well as overhead imaging of OH* of the entire combustor are conducted simultaneously and at a high sampling frequency. The measurements are then used to determine the azimuthal acoustic and heat release rate modes in the chamber and to determine whether these modes are standing, spinning or mixed. Furthermore, the phase shift between the heat release rate and pressure and the shape of these two signals are analysed at different azimuthal positions. Based on the Rayleigh criterion, these investigations allow to obtain an insight about the effects of the swirl on the instability margins of the combustor. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant agreement n° 677931 TAIAC).

  1. Azimuthally spinning wave modes and heat release in an annular combustor

    Science.gov (United States)

    Nygard, Hakon; Mazur, Marek; Dawson, James R.; Worth, Nicholas A.

    2017-11-01

    In order to reduce NOx emissions from aeroengines and stationary gas turbines the fuel-air mixture can be made leaner, at the risk of introducing potentially damaging thermo-acoustic instabilities. At present this phenomenon is not understood well enough to eliminate these instabilities at the design stage. Recently, the presence of different azimuthal modes in annular combustors has been demonstrated both experimentally and numerically. These naturally occurring instabilities in annular geometry have been observed to constantly switch between spinning and standing modes, making it more difficult to analyse the flame structure and dynamics. Very recently this issue was partially addressed using novel acoustic forcing to generate a standing mode. In the present study this concept has been developed further by creating an azimuthal array of loud speakers, which for the first time permits predominantly spinning modes to be set up inside the combustion chamber. The use of pressure and high speed OH* measurements enables the study of the flame dynamics and heat release rate oscillations of the combustor, which will be reported in the current paper. The ability to precisely control the azimuthal mode of oscillation greatly enhances our further understanding of the phenomenon. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant Agreement No 677931 TAIAC).

  2. Flow of viscoplastic fluids in eccentric annular geometries

    DEFF Research Database (Denmark)

    Szabo, Peter; Hassager, Ole

    1992-01-01

    A classification of flowfields for the flow of a Bingham fluid in general eccentric annular geometries is presented. Simple arguments show that a singularity can exist in the stress gradient on boundaries between zones with yielded and un-yielded fluid respectively. A Finite Element code is used...

  3. Localized granuloma annulare and autoimmune thyroiditis in a ...

    African Journals Online (AJOL)

    The association of granuloma annulare (GA) and autoimmune thyroiditis has been documented in the literature in 13 previous cases. However, the pathogenesis of GA remains obscure. Possible pathogenetic factors suggested include: humoral and delayed type hypersensitivity, vascular damage, metabolic disorder, or, ...

  4. Design and simulation of double annular illumination mode for microlithography

    Science.gov (United States)

    Song, Qiang; Zhu, Jing; Yang, Baoxi; Liu, Lei; Wang, Jun; Huang, Huijie

    2013-08-01

    Methods of generating various illumination patterns remain as an attractive and important micro-optics research area for the development of resolution enhancement in advanced lithography system. In the current illumination system of lithography machine, off-axis illumination is widely used as an effective approach to enhance the resolution and increase the depth of focus (DOF). This paper proposes a novel illumination mode generation unit, which transform conventional mode to double annular shaped radial polarized (DARP) mode for improving the resolution of micro-lithography. Through LightToolsTM software simulation, double annular shaped mode is obtained from the proposed generation unit. The mathematical expressions of the radius variation of inner and outer rings are deduced. The impacts of conventional and dual concentric annular illumination pattern on critical dimension uniformity were simulated on an isolated line, square hole and corner. Lithography performance was compared between DARP illumination mode and corresponding single annular modes under critical dimension of 45nm. As a result, DARP illumination mode can improve the uniformity of aerial image at 45nm node through pitch varied in 300-500 nm to a certain extent.

  5. Imaging characteristics of Zernike and annular polynomial aberrations.

    Science.gov (United States)

    Mahajan, Virendra N; Díaz, José Antonio

    2013-04-01

    The general equations for the point-spread function (PSF) and optical transfer function (OTF) are given for any pupil shape, and they are applied to optical imaging systems with circular and annular pupils. The symmetry properties of the PSF, the real and imaginary parts of the OTF, and the modulation transfer function (MTF) of a system with a circular pupil aberrated by a Zernike circle polynomial aberration are derived. The interferograms and PSFs are illustrated for some typical polynomial aberrations with a sigma value of one wave, and 3D PSFs and MTFs are shown for 0.1 wave. The Strehl ratio is also calculated for polynomial aberrations with a sigma value of 0.1 wave, and shown to be well estimated from the sigma value. The numerical results are compared with the corresponding results in the literature. Because of the same angular dependence of the corresponding annular and circle polynomial aberrations, the symmetry properties of systems with annular pupils aberrated by an annular polynomial aberration are the same as those for a circular pupil aberrated by a corresponding circle polynomial aberration. They are also illustrated with numerical examples.

  6. Adjoint Optimisation of the Turbulent Flow in an Annular Diffuser

    DEFF Research Database (Denmark)

    Gotfredsen, Erik; Agular Knudsen, Christian; Kunoy, Jens Dahl

    2017-01-01

    In the present study, a numerical optimisation of guide vanes in an annular diffuser, is performed. The optimisation is preformed for the purpose of improving the following two parameters simultaneously; the first parameter is the uniformity perpen-dicular to the flow direction, a 1/3 diameter do...

  7. Thermal Hydraulic Analysis Of Thorium-Based Annular Fuel Assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Han, Kyu Hyun [Korea Institute of Nuclear Safety, 19, Guseong-dong, Yuseong-gu, Daejeon, 305-338 (Korea, Republic of)

    2008-07-01

    Thermal hydraulic characteristics of thorium-based fuel assemblies loaded with annular seed pins have been analyzed using AMAP combined with MATRA, and compared with those of the existing thorium-based assemblies. MATRA and AMAP showed good agreements for the pressure drops at the internal sub-channels. The pressure drop generally increased in the cases of the assemblies loaded with annular seed pins due to the larger wetted perimeter, but an exception existed. In the inner sub-channels of the seed pins, mass fluxes were high due to the grid form losses in the outer sub-channels. About 43% of the heat generated from the seed pin flowed into the inner sub-channel and the rest into the outer sub-channel, which implies the inner to outer wall heat flux ratio was approximately 1.2. The maximum temperatures of the annular seed pins were slightly above 500 deg. C. The MDNBRs of the assemblies loaded with annular seed pins were higher than those of the existing assemblies. Due to the fact that inter-channel mixing cannot occur in the inner sub-channels, temperatures and enthalpies were higher in the inner sub-channels. (author)

  8. Experimental study of interfacial wave on a liquid film in vertical annular flow

    International Nuclear Information System (INIS)

    Hazuku, T.; Fukamachi, N.; Takamasa, T.; Matsumoto, Y.

    2003-01-01

    In this study, a precise database of microscopic interfacial wave-structure for annular flow developing in a vertical pipe was obtained using a new measuring technique with a laser focus displacement meter. Adiabatic upward annular air-water flow experiments were conducted using a 3-m-long, 11- mm-ID pipe. Measurements of interfacial waves were conducted at 21 axial locations, spaced 110 mm apart, in the pipe. The axial distances from the inlet (L) normalized by the pipe diameter (D) varied over L/D = 50 to 250. Data were collected for predetermined gas and liquid flow conditions and for Reynolds numbers ranging from Reg = 31,800 to 98,300 for the gas phase and Ref = 1,050 to 9,430 for the liquid phase. Using this new technique, we obtained such local properties as the minimum thickness, maximum thickness, and passing frequency of the waves. The results revealed that the maximum film thickness and passing frequency of disturbance waves decreased gradually, with some oscillations, as flow developed. The flow development, i.e., decreases of film thickness and passing frequency, existed until the pipe exit, which means that the flow might never reach a fully developed condition. Minimum thickness of the film decreased with flow development and with increasing gas flow rate. These results are discussed, taking into account the buffer layer calculated from Karman's three-layer model. Correlation is proposed for the minimum film thickness obtained in regard to interfacial shear stress and the Reynolds number of the liquid. This correlation expresses the minimum film thickness obtained from the experiment within a 5% deviation

  9. Enhancing VVER annular proliferation resistance fuel with minor actinides

    International Nuclear Information System (INIS)

    Chang, G. S.

    2007-01-01

    Key aspects of the Global Nuclear Energy Partnership (GNEP) are to significantly advance the science and technology of nuclear energy systems and the Advanced Fuel Cycle (AFC) program. It consists of both innovative nuclear reactors and innovative research in separation and transmutation. To accomplish these goals, international cooperation is very important and public acceptance is crucial. The merits of nuclear energy are high-density energy, with low environmental impacts (i.e. almost zero greenhouse gas emission). Planned efforts involve near term and intermediate-term improvements in fuel utilization and recycling in current light water reactors (LWRs) as well as the longer-term development of new nuclear energy systems that offer much improved fuel utilization and proliferation resistance, along with continued advances in operational safety. The challenges are solving the energy needs of the world, protection against nuclear proliferation, the problem of nuclear waste, and the global environmental problem. To reduce spent fuel for storage and enhance the proliferation resistance for the intermediate-term, there are two major approaches (a) increase the discharged spent fuel burnup in the advanced LWR (Gen-III Plus), which not only can reduce the spent fuel for storage, but also increase the 2 38Pu and 2 40Pu isotopes ratio to enhance the proliferation resistance, and (b) use of transuranic nuclides ( 2 37Np and 2 41Am) in the high burnup fuel, which can drastically increase the proliferation resistance isotope ratio of 2 38Pu /Pu. For future advanced nuclear systems, the minor actinides (MA) are viewed more as a resource to be recycled, or transmuted to less hazardous and possibly more useful forms, rather than simply as a waste stream to be disposed of in expensive repository facilities. As a result, MAs play a much larger part in the design of advanced systems and fuel cycles, not only as additional sources of useful energy, but also as direct contributors

  10. Identification of alkylated phosphates by gas chromatography-mass spectrometric investigations with different ionization principles of a thermally aged commercial lithium ion battery electrolyte.

    Science.gov (United States)

    Weber, Waldemar; Kraft, Vadim; Grützke, Martin; Wagner, Ralf; Winter, Martin; Nowak, Sascha

    2015-05-15

    The thermal aging process of a commercial LiPF6 based lithium ion battery electrolyte has been investigated in view of the formation of volatile phosphorus-containing degradation products. Aging products were analyzed by GC-MS. Structure determination of the products was performed by support of chemical ionization MS in positive and negative modes. A fraction of the discovered compounds belongs to the group of fluorophosphates (phosphorofluoridates) which are in suspect of potential toxicity. This is well known for relative derivatives, e.g. diisopropyl fluorophosphate. Another fraction of the identified compounds belongs to the group of trialkyl phosphates. These compounds may provide a positive impact on the thermal and electrochemical performance of Li-based batteries as repeatedly described in the literature. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Kinetic simulation of neutral/ionized gas and electrically charged dust in the coma of comet 67P/Churyumov-Gerasimenko

    International Nuclear Information System (INIS)

    Tenishev, Valeriy; Rubin, Martin; Combi, Michael R.

    2011-01-01

    The cometary coma is a unique phenomenon in the solar system being a planetary atmosphere influenced by little or no gravity. As a comet approaches the sun, the water vapor with some fraction of other gases sublimate, generating a cloud of gas, ice and other refractory materials (rocky and organic dust) ejected from the surface of the nucleus. Sublimating gas molecules undergo frequent collisions and photochemical processes in the near-nucleus region. Owing to its negligible gravity, comets produce a large and highly variable extensive dusty coma with a size much larger than the characteristic size of the cometary nucleus.The Rosetta spacecraft is en route to comet 67P/Churyumov-Gerasimenko for a rendezvous, landing, and extensive orbital phase beginning in 2014. Both, interpretation of measurements and safety consideration of the spacecraft require modeling of the comet's dusty gas environment.In this work we present results of a numerical study of multispecies gaseous and electrically charged dust environment of comet Chyuryumov-Gerasimenko. Both, gas and dust phases of the coma are simulated kinetically. Photolytic reactions are taken into account. Parameters of the ambient plasma as well as the distribution of electric/magnetic fields are obtained from an MHD simulation of the coma connected to the solar wind. Trajectories of ions and electrically charged dust grains are simulated by accounting for the Lorentz force and the nucleus gravity.

  12. Study on natural convection characteristics in a narrow annular gap, 2

    International Nuclear Information System (INIS)

    Naohara, Nobuyuki; Uotani, Masaki; Kinoshita, Izumi; Arazeki, Hideo

    1987-01-01

    To clarify the characteristics of natural convection in a narrow annular gap at the roof-slab penetration in pool-type LMFBR, experimental study was carried out. Experiment is to investigate the effect of annular gap width. The results are summarized as follows. (1) A chart showing the presence of natural convection was drawn, and it was showed that the natural convection in an annular gap was influenced by gap width. (2) Dimensionless circumferential temperature in annular wall could be rearranged by new parameter taking account of the annular gap width and a characteristics curve was obtained. (author)

  13. Ring magnetron ionizer

    International Nuclear Information System (INIS)

    Alessi, J.G.

    1986-01-01

    A ring magnetron D - charge exchange ionizer has been built and tested. An H - current of 500 μA was extracted with an estimated H 0 density in the ionizer of 10 12 cm -3 . This exceeds the performance of ionizers presently in use on polarized H - sources. The ionizer will soon be tested with a polarized atomic beam

  14. Possibility of gas flow measurements using ionization produced by radioactive sources. Performance obtained using continuous and pulsed ionization; Etude des possibilites de mesure des debits gazeux par l'ionisation creee au moyen de sources radioactives performances obtenues par ionisation continue et par ionisation pulsee

    Energy Technology Data Exchange (ETDEWEB)

    Toudoire, B. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    Two methods for measuring gas flow have been studied, based on the ionization of the fluid by a radioactive source. In the first one, called the continuous method, use is made of the relationship between the flow and the ionic density at a point situated down-stream from the ionizing source. In the second method, called 'pulsed', the time for a burst of ions to pass between two points in the circuit is measured. An attempt has been made to predict and to justify theoretically the experimental results, and to determine to what extent these methods can provide absolute measurements or measurements requiring a calibration using known gas flows. These methods are characterized by the absence of moving parts or of parts under reduced pressure and can yield results with an accuracy of between a few per cent to a few tenths of a per cent. The information, provided in either analog or digital form, can be adapted for use in servo-mechanisms or automatic systems. Two applications of an industrial type are described; they concern gas-flow measurements in a railway braking circuit, and in tubes of 20 and 30 cm diameter. (author) [French] Deux methodes de mesure de debit gazeux ont ete etudiees, basees sur l'ionisation du fluide par une source radioactive. Dans la premiere, dite continue, on exploite la relation existant entre le debit et la densite ionique en un point situe a l'aval de la source ionisante. Dans la seconde, dite pulsee, on mesure le temps de transit de bouffees d'ions entre deux points de la conduite. On s'est efforce de prevoir et de justifier par la theorie les resultats experimentaux, et de preciser dans quelle mesure ces methodes peuvent fournir des mesures absolues ou necessitent un etalonnage a partir de debits connus. Caracterisees par l'absence d'organe mobile ou deprimogene, ces methodes sont susceptibles d'une precision de quelques pour-cent a quelques pour-mille. L'information, fournie sous forme

  15. Possibility of gas flow measurements using ionization produced by radioactive sources. Performance obtained using continuous and pulsed ionization; Etude des possibilites de mesure des debits gazeux par l'ionisation creee au moyen de sources radioactives performances obtenues par ionisation continue et par ionisation pulsee

    Energy Technology Data Exchange (ETDEWEB)

    Toudoire, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    Two methods for measuring gas flow have been studied, based on the ionization of the fluid by a radioactive source. In the first one, called the continuous method, use is made of the relationship between the flow and the ionic density at a point situated down-stream from the ionizing source. In the second method, called 'pulsed', the time for a burst of ions to pass between two points in the circuit is measured. An attempt has been made to predict and to justify theoretically the experimental results, and to determine to what extent these methods can provide absolute measurements or measurements requiring a calibration using known gas flows. These methods are characterized by the absence of moving parts or of parts under reduced pressure and can yield results with an accuracy of between a few per cent to a few tenths of a per cent. The information, provided in either analog or digital form, can be adapted for use in servo-mechanisms or automatic systems. Two applications of an industrial type are described; they concern gas-flow measurements in a railway braking circuit, and in tubes of 20 and 30 cm diameter. (author) [French] Deux methodes de mesure de debit gazeux ont ete etudiees, basees sur l'ionisation du fluide par une source radioactive. Dans la premiere, dite continue, on exploite la relation existant entre le debit et la densite ionique en un point situe a l'aval de la source ionisante. Dans la seconde, dite pulsee, on mesure le temps de transit de bouffees d'ions entre deux points de la conduite. On s'est efforce de prevoir et de justifier par la theorie les resultats experimentaux, et de preciser dans quelle mesure ces methodes peuvent fournir des mesures absolues ou necessitent un etalonnage a partir de debits connus. Caracterisees par l'absence d'organe mobile ou deprimogene, ces methodes sont susceptibles d'une precision de quelques pour-cent a quelques pour-mille. L'information, fournie sous forme analogique ou numerique, se prete a la realisation de

  16. Evidence for large-scale winds from starburst galaxies. I. The nature of the ionized gas in M82 and NGC 253

    International Nuclear Information System (INIS)

    Mccarthy, P.J.; Van breugel, W.; Heckman, T.; Maryland Univ., College Park)

    1987-01-01

    The results of long-slit spectroscopy and narrow-band imaging of M82 and NGC 253, the two nearest examples of FIR luminous galaxies believed to be undergoing intense bursts of star formation, are presented. The profile of the gas pressure in the emission-line filaments in M82 is derived and found to be in good agreement with the model of Chevalier and Clegg (1985) of a supernovae-driven wind from a starburst nucleus. Lower quality data from NGC 253 support the same interpretation. Analysis of the emission-line ratios suggests that the line-emitting gas may be heated by low-velocity shocks, although photoionization from dilute UV radiation from unusually hot stars in the central starburst may also be important. 56 references

  17. Transition from slug to annular flow in horizontal air-water flow

    International Nuclear Information System (INIS)

    Reismann, J.; John, H.; Seeger, W.

    1981-11-01

    The transition from slug to annular flow in horizontal air-water and steam-water flow was investigated. Test sections of 50; 66.6 and 80 mm ID were used. The system pressure was 0.2 and 0.5 MPa in the air-water experiments and 2.5; 5; 7.5 and 10 MPa in the steam-water experiments. For flow pattern detection local impedance probes were used. This method was compared in a part of the experiments with differential pressure and gamma-beam measurements. The flow regime boundary is shifting strongly to smaller values of the superficial gas velocity with increasing pressure. Correlations from literature fit unsatisfactorily the experimental results. A new correlation is presented. (orig.) [de

  18. Mixture formation of direct gasoline injection engine. In cylinder gas sampling using fast response ionization detector; Tonai funsha gasoline engine no kongoki keisei. Kosoku FID ni yoru tonai gas sampling

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, H; Marubara, M; Ota, N; Kudo, H; Yamamoto, H [Mazda Motor Corp., Hiroshima (Japan)

    1997-10-01

    Local mixture concentration near the spark plug of a direct gasoline injection engine was observed by a fast flame ionization detector. To ensure combustion stability and good fuel economy in DISC operation, the swirl ratio and the piston configuration were optimized. Swirl is needed to retain well-vaporized and stable mixture near the spark plug especially in light load. And adequate volume in piston cavity is required for trapping curved fuel spray in it. With these specifications, the fuel economy improvement of 13 to 30 % was realized. 2 refs., 13 figs., 1 tab.

  19. Simulation study of the ionizing front in the critical ionization velocity phenomenon

    International Nuclear Information System (INIS)

    Machida, S.; Goertz, C.K.; Lu, G.

    1988-01-01

    Simulations of the Critical Ionization Velocity (CIV) for a neutral gas cloud moving across the static magnetic field are made. We treat a low-β plasma and use a 2-1/2 D electrostatic code linked with our Plasma and Neutral Interaction Code (PANIC). Our study is focused on the understanding of the interface between the neutral gas cloud and the surrounding plasma where the strong interaction takes place. We assume the existence of some hot electrons in the ambient plasma to provide a seed ionization for CIV. When the ionization starts a sheath-like structure is formed at the surface of the neutral gas (Ionizing Front). In that region the crossfield component of the electric field causes the electron to E x B drift with a velocity of the order of the neutral gas velocity times the square root of the ion to electron mass ratio. Thus the kinetic energy of the drifting electrons can be large enough for electron impact ionization. In addition a diamagnetic drift of the electron occurs due to the number density and temperature inhomogeneity in the ionization front. These drift currents excite the lower-hybrid waves with the wave k-vectors almost perpendicular to the neutral flow and magnetic field again resulting in electron heating and additional ionization. The overall structure is studied by developing a simple analytic model as well as making simulation runs. (author)

  20. An empirical correlation for the entrainment fraction at the onset of annular flow based on 2006 CHF look-up table

    Energy Technology Data Exchange (ETDEWEB)

    Jiao, Bo; Yang, Dongyu [Department of Mechanical Engineering, Rongcheng Campus, Harbin University of Science and Technology, Rongcheng 264300, Shandong (China); Gan, Zhihua, E-mail: gan_zhihua@zju.edu.cn [Institute of Refrigeration and Cryogenics, Zhejiang University, Hangzhou (China); Key Laboratory of Refrigeration and Cryogenic Technology of Zhejiang Province, Hangzhou (China); National Quality Inspection Center of Refrigeration Equipment (Henan), Minquan (China)

    2017-06-15

    Highlights: • A parallel look-up table for the entrainment fraction at annular point was developed. • A correlation was given based on the selected database from 2006 CHF look-up table. • Its reliability on the other conditions in the look-up table was discussed. - Abstract: The critical heat flux (CHF) of gas-liquid flow plays an important role in the safety of industrial equipment. At present, the liquid film dryout model is widely used for predicting CHF in gas-liquid annular flow. Most parameters in this model can be determined by some empirical correlations which are valid under different conditions. However, up to now, the entrainment fraction at the onset of annular flow is always assumed due to the lack of relevant experimental data. In this paper, the normalized data of the 2006 CHF look-up table (LUT) which has been adopted widely, especially in the nuclear industry, were used. Firstly, the empirical correlations, provided for the onset of annular flow and the limiting quality, were employed. In the valid pressure and mass flux range of these correlations, the selected database from LUT was confirmed. Secondly, the liquid film model was built. The entrainment fraction at the onset of annular flow was obtained when the calculated CHF by the model agreed with the corresponding value in LUT. A parallel look-up table for it was developed. Its correlation including the Weber and the liquid Reynolds number at outlet was proposed. The errors are mostly within ±30%. Finally, its reliability on the other conditions in LUT, which are beyond the valid range of the empirical correlations used for determining the database, was discussed. All the conditions whose errors are outside ±30% of the predictions by the provided correlation were marked in the tables.

  1. Lab-In-Syringe automation of stirring-assisted room-temperature headspace extraction coupled online to gas chromatography with flame ionization detection for determination of benzene, toluene, ethylbenzene, and xylenes in surface waters.

    Science.gov (United States)

    Horstkotte, Burkhard; Lopez de Los Mozos Atochero, Natalia; Solich, Petr

    2018-06-22

    Online coupling of Lab-In-Syringe automated headspace extraction to gas chromatography has been studied. The developed methodology was successfully applied to surface water analysis using benzene, toluene, ethylbenzene, and xylenes as model analytes. The extraction system consisted of an automatic syringe pump with a 5 mL syringe into which all solutions and air for headspace formation were aspirated. The syringe piston featured a longitudinal channel, which allowed connecting the syringe void directly to a gas chromatograph with flame ionization detector via a transfer capillary. Gas injection was achieved via opening a computer-controlled pinch valve and compressing the headspace, upon which separation was initialized. Extractions were performed at room temperature; yet sensitivity comparable to previous work was obtained by high headspace to sample ratio V HS /V Sample of 1.6:1 and injection of about 77% of the headspace. Assistance by in-syringe magnetic stirring yielded an about threefold increase in extraction efficiency. Interferences were compensated by using chlorobenzene as an internal standard. Syringe cleaning and extraction lasting over 10 min was carried out in parallel to the chromatographic run enabling a time of analysis of <19 min. Excellent peak area repeatabilities with RSD of <4% when omitting and <2% RSD when using internal standard corrections on 100 μg L -1 level were achieved. An average recovery of 97.7% and limit of detection of 1-2 μg L -1 were obtained in analyses of surface water. Copyright © 2018 Elsevier B.V. All rights reserved.

  2. Tomographic scanning apparatus with ionization detector means

    International Nuclear Information System (INIS)

    1981-01-01

    This patent specification describes a tomographic scanning apparatus using a fan beam and digital output signal. Particular reference is made to the gas-pressurized ionization detector chamber, consisting of an array of side-by-side elongate ionization detection cells, the principal axis of each of the said cells being oriented along a radius extending towards the radiation source, and connection means for applying potentials across the cells for taking their output signals. (U.K.)

  3. Study of volume fractions for stratified and annular regime in multiphase flows using gamma-rays and artificial neural network

    International Nuclear Information System (INIS)

    Salgado, Cesar M.; Brandao, Luis Eduardo; Pereira, Claudio M.N.A.; Ramos, Robson; Schirru, Roberto; Silva, Ademir X.

    2007-01-01

    This work presents methodology based on the use of nuclear technique and artificial intelligence for attainment of volume fractions in stratified and annular multiphase flow regime, oil-water-gas, very frequent in the offshore industry petroliferous. Using the principles of absorption and scattering of gamma-rays and an adequate geometry scheme of detection with two detectors and two energies measurement are gotten and they vary as changes in the volume fractions of flow regime occur. The MCNP-X code was used in order to provide the data training for artificial neural network that matched such information with the respective actual volume fractions of each material. (author)

  4. Study of volume fractions for stratified and annular regime in multiphase flows using gamma-rays and artificial neural network

    Energy Technology Data Exchange (ETDEWEB)

    Salgado, Cesar M.; Brandao, Luis Eduardo; Pereira, Claudio M.N.A.; Ramos, Robson [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)]. E-mail: otero@ien.gov.br; brandao@ien.gov.br; cmnap@ien.gov.br; robson@ien.gov.br; Schirru, Roberto; Silva, Ademir X. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Energia Nuclear (PEN)]. E-mails: ademir@con.ufrj.br; schirru@lmp.ufrj.br

    2007-07-01

    This work presents methodology based on the use of nuclear technique and artificial intelligence for attainment of volume fractions in stratified and annular multiphase flow regime, oil-water-gas, very frequent in the offshore industry petroliferous. Using the principles of absorption and scattering of gamma-rays and an adequate geometry scheme of detection with two detectors and two energies measurement are gotten and they vary as changes in the volume fractions of flow regime occur. The MCNP-X code was used in order to provide the data training for artificial neural network that matched such information with the respective actual volume fractions of each material. (author)

  5. Gas-phase ion/molecule isotope-exchange reactions: methodology for counting hydrogen atoms in specific organic structural environments by chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    Hunt, D.F.; Sethi, S.K.

    1980-01-01

    Ion/molecule reactions are described which facilitate exchange of hydrogens for deuteriums in a variety of different chemical environments. Aromatic hydrogens in alkylbenzenes, oxygenated benzenes, m-toluidine, m-phenylenediamine, thiophene, and several polycyclic aromatic hydrocarbons and metallocenes are exchanged under positive ion CI conditions by using either D 2 O, EtOD, or ND 3 as the reagent gas. Aromatic hydrogens, benzylic hydrogens, and hydrogens on carbon adjacent to carbonyl groups suffer exchange under negative ion CI conditions in ND 3 , D 2 O, and EtOD, respectively. A possible mechanism for the exchange process is discussed. 1 figure, 2 tables

  6. High Thrust-to-Power Annular Engine Technology

    Science.gov (United States)

    Patterson, Michael J.; Thomas, Robert E.; Crofton, Mark W.; Young, Jason A.; Foster, John E.

    2015-01-01

    Gridded ion engines have the highest efficiency and total impulse of any mature electric propulsion technology, and have been successfully implemented for primary propulsion in both geocentric and heliocentric environments with excellent ground/in-space correlation of performance. However, they have not been optimized to maximize thrust-to-power, an important parameter for Earth orbit transfer applications. This publication discusses technology development work intended to maximize this parameter. These activities include investigating the capabilities of a non-conventional design approach, the annular engine, which has the potential of exceeding the thrust-to-power of other EP technologies. This publication discusses the status of this work, including the fabrication and initial tests of a large-area annular engine. This work is being conducted in collaboration among NASA Glenn Research Center, The Aerospace Corporation, and the University of Michigan.

  7. Sodium flow rate measurement method of annular linear induction pump

    International Nuclear Information System (INIS)

    Araseki, Hideo

    2011-01-01

    This report describes a method for measuring sodium flow rate of annular linear induction pumps arranged in parallel and its verification result obtained through an experiment and a numerical analysis. In the method, the leaked magnetic field is measured with measuring coils at the stator end on the outlet side and is correlated with the sodium flow rate. The experimental data and the numerical result indicate that the leaked magnetic field at the stator edge keeps almost constant when the sodium flow rate changes and that the leaked magnetic field change arising from the flow rate change is small compared with the overall leaked magnetic field. It is shown that the correlation between the leaked magnetic field and the sodium flow rate is almost linear due to this feature of the leaked magnetic field, which indicates the applicability of the method to small-scale annular linear induction pumps. (author)

  8. Optical description and design method with annularly stitched aspheric surface.

    Science.gov (United States)

    Cheng, De-Wen; Chen, Xue-Jiao; Xu, Chen; Hu, Yuan; Wang, Yong-Tian

    2015-12-01

    The relentless pressure for designs with new optical functions, small volume, and light weight has greatly increased the importance of aspheric surfaces. In this paper, we propose an annularly stitched aspheric surface (ASAS) description method to increase the freedom and flexibility of imaging system design. The rotationally symmetric ASAS consists of a circular central zone and one or more annular zones. Two neighboring zones are constrained to have the same derivatives on their joint curve, and this means the ASAS is C1 continuous. This finding is proved and verified by the mathematical deduction of the surface formulas. Two optimization strategies and two design methods with the C1 continuous constraints are also discussed. This surface can greatly facilitate the design and even achieve some previously impossible designs without increasing the fabrication difficulty. Two different systems with the proposed ASAS are optimized and the results are presented. The design results verified the practicability of the ASAS.

  9. Sheet Fluorescence and Annular Analysis of Ultracold Neutral Plasmas

    International Nuclear Information System (INIS)

    Castro, J.; Gao, H.; Killian, T. C.

    2009-01-01

    Annular analysis of fluorescence imaging measurements on Ultracold Neutral Plasmas (UNPs) is demonstrated. Spatially-resolved fluorescence imaging of the strontium ions produces a spectrum that is Doppler-broadened due to the thermal ion velocity and shifted due to the ion expansion velocity. The fluorescence excitation beam is spatially narrowed into a sheet, allowing for localized analysis of ion temperatures within a volume of the plasma with small density variation. Annular analysis of fluorescence images permits an enhanced signal-to-noise ratio compared to previous fluorescence measurements done in strontium UNPs. Using this technique and analysis, plasma ion temperatures are measured and shown to display characteristics of plasmas with strong coupling such as disorder induced heating and kinetic energy oscillations.

  10. Study of the diffraction in the microscope: Annular condenser

    International Nuclear Information System (INIS)

    Ciocci, L; Echarri, R M; Simon, J M

    2011-01-01

    In this work we study the diffraction in the microscope when an annular condenser is used to illuminate the object. We calculate the point spread function (PSF) for a pinhole in an opaque screen illuminated with an annular condenser, consisting in an 1D array of incoherent point sources. We compare it with the PSF for a self-luminous point object, finding that the central disk of the diffraction pattern is narrower and the first intensity minimum is deeper for illuminated objects. We also analyze the resolution of the system by means of the intensity profile produced by two points objects, finding that two self luminous point objects are better resolved than two illuminated objects at the same distance. This suggests that the correlation introduced in the object diminishes the resolution in the former case.

  11. Supercritical heat transfer in an annular channel with external heating

    International Nuclear Information System (INIS)

    Remizov, O.V.; Gal'chenko, Eh.F.; Shurkin, N.G.; Sergeev, V.V.

    1980-01-01

    Results are presented of experimental studies of the burnout heat transfer in a 32x28x3000 mm annular channel with a uniform distribution of a heat flow at pressures of 6.9-19.6 MPa and mass rates of 350-1000 kg/m 2 xs. The heating is electrical, external, one-sided. It is shown that dependencies of the heat-transfer coefficient on rated parameters in the annular channel and tube are similar. An empirical equation has been obtained for the calculation of the burnout heat transfer in the annual channels with external heating in the following range: pressure, 6.9 -13.7 MPa; mass rate 350-700 kg/m 2 xs, and steam content ranging from Xsub(crit) to 1

  12. Temperature Calculation of Annular Fuel Pellet by Finite Difference Method

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yong Sik; Bang, Je Geon; Kim, Dae Ho; Kim, Sun Ki; Lim, Ik Sung; Song, Kun Woo [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2009-10-15

    KAERI has started an innovative fuel development project for applying dual-cooled annular fuel to existing PWR reactor. In fuel design, fuel temperature is the most important factor which can affect nuclear fuel integrity and safety. Many models and methodologies, which can calculate temperature distribution in a fuel pellet have been proposed. However, due to the geometrical characteristics and cooling condition differences between existing solid type fuel and dual-cooled annular fuel, current fuel temperature calculation models can not be applied directly. Therefore, the new heat conduction model of fuel pellet was established. In general, fuel pellet temperature is calculated by FDM(Finite Difference Method) or FEM(Finite Element Method), because, temperature dependency of fuel thermal conductivity and spatial dependency heat generation in the pellet due to the self-shielding should be considered. In our study, FDM is adopted due to high exactness and short calculation time.

  13. Identification of chemical warfare agents from vapor samples using a field-portable capillary gas chromatography/membrane-interfaced electron ionization quadrupole mass spectrometry instrument with Tri-Bed concentrator.

    Science.gov (United States)

    Nagashima, Hisayuki; Kondo, Tomohide; Nagoya, Tomoki; Ikeda, Toru; Kurimata, Naoko; Unoke, Shohei; Seto, Yasuo

    2015-08-07

    A field-portable gas chromatograph-mass spectrometer (Hapsite ER system) was evaluated for the detection of chemical warfare agents (CWAs) in the vapor phase. The system consisted of Tri-Bed concentrator gas sampler (trapping time: 3s(-1)min), a nonpolar low thermal-mass capillary gas chromatography column capable of raising temperatures up to 200°C, a hydrophobic membrane-interfaced electron ionization quadrupole mass spectrometer evacuated by a non-evaporative getter pump for data acquisition, and a personal computer for data analysis. Sample vapors containing as little as 22μg sarin (GB), 100μg soman (GD), 210μg tabun (GA), 55μg cyclohexylsarin (GF), 4.8μg sulfur mustard, 390μg nitrogen mustard 1, 140μg of nitrogen mustard 2, 130μg nitrogen mustard 3, 120μg of 2-chloroacetophenone and 990μg of chloropicrin per cubic meter could be confirmed after Tri-Bed micro-concentration (for 1min) and automated AMDIS search within 12min. Using manual deconvolution by background subtraction of neighboring regions on the extracted ion chromatograms, the above-mentioned CWAs could be confirmed at lower concentration levels. The memory effects were also examined and we found that blister agents showed significantly more carry-over than nerve agents. Gasoline vapor was found to interfere with the detection of GB and GD, raising the concentration limits for confirmation in the presence of gasoline by both AMDIS search and manual deconvolution; however, GA and GF were not subject to interference by gasoline. Lewisite 1, and o-chlorobenzylidene malononitrile could also be confirmed by gas chromatography, but it was hard to quantify them. Vapors of phosgene, chlorine, and cyanogen chloride could be confirmed by direct mass spectrometric detection at concentration levels higher than 2, 140, and 10mg/m(3) respectively, by bypassing the micro-concentration trap and gas chromatographic separation. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Radionuclide measurements using resonantly enhanced collisional ionization

    International Nuclear Information System (INIS)

    Whitaker, T.J.; Bushaw, B.A.; Gerke, G.K.

    1987-01-01

    This report describes development of a laser-enhanced collisional ionization method for direct radionuclide measurements that are independent of radioactive decay. The technique uses two nitrogen-laser-pumped dye lasers to selectively excite the target isotope to an electronic state near the ionization threshold. The excited actinide atoms then undergo collisions with a buffer gas and are efficiently ionized. The resulting ions can be detected by conventional methods. The attributes of this approach include highly sensitive isotope analysis with relatively inexpensive lasers and a simple vacuum system. 9 refs., 3 figs

  15. On possible structures of transverse ionizing shock waves

    International Nuclear Information System (INIS)

    Liberman, M.A.; Velikovich, A.L.

    1978-01-01

    The possible structures of ionizing shock waves propagating in gases across the magnetic field are investigated taking account of both ionization kinetics and the non-isothermality of the plasma which is formed within the shock front. It is shown that a definite factor in shaping the structure of the transverse ionizing shock wave is photo-ionization of the neutral gas across the front. The paper includes a study of the evolution of the transverse ionizing shock front with regard to photo-ionization, disclosing that a stable stationary shock structure emerges only in boundary conditions which are close to magnetohydrodynamic ones, i.e. upsilon 1 H 1 = upsilon 2 H 2 . In the case of strong transverse ionizing shock waves, when the flux of ionizing radiation across the front is great, the shock structure is obviously magnetohydrodynamic. (author)

  16. Thermohydraulic analysis of smooth and finned annular ducts

    International Nuclear Information System (INIS)

    Braga, C.V.M.

    1987-01-01

    The present work is concerned with the turbulent heat transfer and pressure drop in smooth and finned annular ducts overage heat transfer coefficients have been obtained by means of the heat exchanger theory. In addition, friction factors have also been determined. The experiments were performed by utilizing four double-pipe heat exchangers. The flowing fluids, in the heat exchangers, were air and water. The average heat transfer coefficients, for air flowing in the annular section, were determined by measuring the overall heat transfer coefficients of the heat exchangers. In order to attain fully developed conditions, the heat exchangers had a starting length of 30 hydraulic diameters. The thermal boundary conditions consisted of uniform temperature on the inner surface, the outer surface being insulated. The heat transfer coefficients and friction factors are presented in dimensionaless forms, as functions of the Reynolds number of the flow. The results for the smooth and finned annular ducts were compared. The purpose of such comparison was to study the influence of the fins on the pressure drop and heat transfer rate. In the case of the finned nular ducts, it is shown that the fin efficiency has some fluence on the heat transfer rates. The, a two-dimensional at transfer analysis was performed in order to obtain the n efficiency and the annular region efficiency. It is also shown that the overall thermal performance of finned surfaces epends mainly on the Nusselt number and on the region eficiency. These parameters are presented as functions of the Reynolds number of the flow and the geometry of the problem. (author) [pt

  17. Modelling of Zirconium and Hafnium separation using continuous annular chromatography

    International Nuclear Information System (INIS)

    Moch-Setyadji; Endang Susiantini

    2014-01-01

    Nuclear degrees of zirconium in the form of a metal alloy is the main material for fuel cladding of NPP. Zirconium is also used as sheathing UO 2 kernel in the form of ZrC as a substitute of SiC in the fuel elements of High Temperature Reactor (HTR). Difficulty separating hafnium from zirconium because it has a lot of similarities in the chemical properties of Zr and Hf. Annular chromatography is a device that can be used for separating of zirconium and hafnium to obtain zirconium nuclear grade. Therefore, it is necessary to construct the mathematical modelling that can describe the separation of zirconium and hafnium in the annular chromatography containing anion resin dowex-1X8. The aim of research is to perform separation simulation by using the equilibrium model and mass transfer coefficient resulted from research. Zr and Hf feed used in this research were 26 and 1 g/l, respectively. Height of resin (L), angular velocity (ω) and the superficial flow rate (uz) was varied to determine the effect of each parameter on the separation of Zr and Hf. By using Kd and Dv values resulted previous research. Simulation results showed that zirconium and hafnium can be separated using a continuous annular chromatography with high resin (long bed) 50 cm, superficial flow rate of 0.001 cm/s, the rotation speed of 0.006 rad/min and 20 cm diameter annular. In these conditions the results obtained zirconium concentration of 10,303.226 g/m 3 and hafnium concentration of 12.324 g/m 3 (ppm). (author)

  18. Numerical Study of Transition of an Annular Lift Fan Aircraft

    OpenAIRE

    Yun Jiang; Bo Zhang

    2016-01-01

    The present study aimed at studying the transition of annular lift fan aircraft through computational fluid dynamics (CFD) simulations. The oscillations of lift and drag, the optimization for the figure of merit, and the characteristics of drag, yawing, rolling and pitching moments in transition are studied. The results show that a two-stage upper and lower fan lift system can generate oscillations of lift and drag in transition, while a single-stage inner and outer fan lift system can elimin...

  19. Excitational metamorphosis of surface flowfield under an impinging annular jet

    Czech Academy of Sciences Publication Activity Database

    Tesař, Václav; Trávníček, Zdeněk

    2008-01-01

    Roč. 144, č. 2 (2008), s. 312-316 ISSN 1385-8947 R&D Projects: GA ČR GA101/07/1499; GA AV ČR IAA200760705 Institutional research plan: CEZ:AV0Z20760514 Keywords : jets * impinging jets * flow topology * annular jets * stagnation points Subject RIV: BK - Fluid Dynamics Impact factor: 2.813, year: 2008 http://www.sciencedirect.com/

  20. Standing wave acoustic levitation on an annular plate

    Science.gov (United States)

    Kandemir, Mehmet Hakan; Çalışkan, Mehmet

    2016-11-01

    In standing wave acoustic levitation technique, a standing wave is formed between a source and a reflector. Particles can be attracted towards pressure nodes in standing waves owing to a spring action through which particles can be suspended in air. This operation can be performed on continuous structures as well as in several numbers of axes. In this study an annular acoustic levitation arrangement is introduced. Design features of the arrangement are discussed in detail. Bending modes of the annular plate, known as the most efficient sound generation mechanism in such structures, are focused on. Several types of bending modes of the plate are simulated and evaluated by computer simulations. Waveguides are designed to amplify waves coming from sources of excitation, that are, transducers. With the right positioning of the reflector plate, standing waves are formed in the space between the annular vibrating plate and the reflector plate. Radiation forces are also predicted. It is demonstrated that small particles can be suspended in air at pressure nodes of the standing wave corresponding to a particular bending mode.