Stability of Poiseuille flow in a fluid overlying an anisotropic and inhomogeneous porous layer
Deepu, P.; Anand, Prateek; Basu, Saptarshi
2015-08-01
We present the linear stability analysis of horizontal Poiseuille flow in a fluid overlying a porous medium with anisotropic and inhomogeneous permeability. The generalized Darcy model is used to describe the flow in the porous medium with the Beavers-Joseph condition at the interface of the two layers and the eigenvalue problem is solved numerically. The effect of major system parameters on the stability characteristics is addressed in detail. It is shown that the anisotropic and inhomogeneous modulation of the permeability of the underlying porous layer provides an effective means for passive control of the flow stability.
Energy Technology Data Exchange (ETDEWEB)
Laha, P., E-mail: plaha@vub.ac.be; Terryn, H.; Ustarroz, J., E-mail: justarro@vub.ac.be [Research Group Electrochemical and Surface Engineering (SURF), Vrije Universiteit Brussel, Pleinlaan 2, 1050 Elsene, Brussels (Belgium); Nazarkin, M. Y., E-mail: mikleo@mail.ru; Gavrilov, S. A. [Department of Materials of Functional Electronics (MFE), National Research University of Electronic Technology, Bld. 5, Pas. 4806, Zelenograd, Moscow 124498 (Russian Federation); Volkova, A. V.; Simunin, M. M. [Department of Quantum Physics and Nanoelectronics (QPN), National Research University of Electronic Technology, Bld. 5, Pas. 4806, Zelenograd, Moscow 124498 (Russian Federation)
2015-03-09
ZnO films have increasingly been in the spotlight due to their largely varied electro-physical and optical properties. For several applications, porous anisotropic nanocrystalline layers are especially interesting. To study the growth kinetics of such films during different fabrication processes, a powerful non-destructive in-situ technique is required. In this work, both ex-situ and in-situ spectroscopic ellipsometry are used along with advanced modelling techniques that are able to take both the anisotropy and the porosity of the films into account. Scanning electron microscopy, along with nitrogen absorption methods for measuring porosity, validated the ellipsometric data and proposed model. The film, grown by chemical bath deposition, was monitored from around 700 to 1800 nm in thickness. This same principle can now be used to monitor any other porous and/or anisotropic structure in an effective in-situ manner, e.g., growth of porous anodic aluminium oxides, nano-porous silica films, etc.
Energy Technology Data Exchange (ETDEWEB)
Antonova, A.M.; Moiseikina, I.I. [Kiev Univ. (Ukraine)
1994-10-05
We consider nonstationary seepage in a bounded nonhomogeneously anisotropic fissured-porous layer. The layer contains by an imperfect well, which operates with a constant discharge. Formulas for the distribution of fluid pressure are obtained using the Laplace transform and the separation of variables method.
Onset of Darcy-Brinkman Convection in a Maxwell Fluid Saturated Anisotropic Porous Layer
Directory of Open Access Journals (Sweden)
S. N. Gaikwad
2016-01-01
Full Text Available In the present study, the onset of Darcy-Brinkman double diffusive convection in a Maxwell fluid-saturated anisotropic porous layer is studied analytically using stability analysis. The linear stability analysis is based on normal technique. The modified Darcy-Brinkmam Maxwell model is used for the momentum equation. The Rayleigh number for stationary, oscillatory and finite amplitude convection is obtained analytically. The effect of the stress relaxation parameter, solute Rayleigh number, Darcy number, Darcy-Prandtl number, Lewis number, mechanical and thermal anisotropy parameters, and normal porosity parameter on the stationary, oscillatory and finite amplitude convection is shown graphically. The nonlinear theory is based on the truncated representation of the Fourier series method and is used to find the heat and mass transfer. The transient behavior of the Nusselt and Sherwood numbers is obtained by solving the finite amplitude equations using the Runge-Kutta method.
Onset of Darcy-Brinkman Reaction-Convection in an Anisotropic Porous Layer
Directory of Open Access Journals (Sweden)
S. N. Gaikwad
2016-01-01
Full Text Available The linear and nonlinear stability analysis of double diffusive reaction-convection in a sparsely packed anisotropic porous layer subjected to chemical equilibrium on the boundaries is investigated analytically. The linear analysis is based on the usual normal mode method and the nonlinear theory on the truncated representation of Fourier series method. The Darcy-Brinkman model is employed for the momentum equation. The onset criterion for stationary, oscillatory and finite amplitude convection is derived analytically. The effect of Darcy number, Damkohler number, anisotropy parameters, Lewis number, and normalized porosity on the stationary, oscillatory, and finite amplitude convection is shown graphically. It is found that the effect of Darcy number and mechanical anisotropy parameter have destabilizing effect, while the thermal anisotropy parameter has stabilizing effect on the stationary, oscillatory and finite amplitude convection. The Damkohler number has destabilizing effect in the case of stationary mode, with stabilizing effect in the case of oscillatory and finite amplitude modes. Further, the transient behavior of the Nusselt and Sherwood numbers are investigated by solving the nonlinear system of ordinary differential equations numerically using the Runge-Kutta method.
Directory of Open Access Journals (Sweden)
S.N. Gaikwad
2014-01-01
Full Text Available In this paper, we have investigated theoretically the effect of Soret parameter on the onset of double diffusive rotating anisotropic convection in a horizontal sparsely packed porous layer using linear stability theory which is based on the usual normal mode technique. The Brinkman model that includes the Coriolis term is employed for the momentum equation. The effect of anisotropy parameters, Soret parameter, solute Rayleigh number, Taylor number, Lewis number, Darcy and Darcy Prandtl number on stationary and oscillatory convection is shown graphically.
Numerical investigation of nanoparticles transport in anisotropic porous media.
Salama, Amgad; Negara, Ardiansyah; El Amin, Mohamed; Sun, Shuyu
2015-10-01
In this work the problem related to the transport of nanoparticles in anisotropic porous media is investigated numerically using the multipoint flux approximation. Anisotropy of porous media properties is an essential feature that exists almost everywhere in subsurface formations. In anisotropic media, the flux and the pressure gradient vectors are no longer collinear and therefore interesting patterns emerge. The transport of nanoparticles in subsurface formations is affected by several complex processes including surface charges, heterogeneity of nanoparticles and soil grain collectors, interfacial dynamics of double-layer and many others. We use the framework of the theory of filtration in this investigation. Processes like particles deposition, entrapment, as well as detachment are accounted for. From the numerical methods point of view, traditional two-point flux finite difference approximation cannot handle anisotropy of media properties. Therefore, in this work we use the multipoint flux approximation (MPFA). In this technique, the flux components are affected by more neighboring points as opposed to the mere two points that are usually used in traditional finite volume methods. We also use the experimenting pressure field approach which automatically constructs the global system of equations by solving multitude of local problems. This approach facilitates to a large extent the construction of the global system. A set of numerical examples is considered involving two-dimensional rectangular domain. A source of nanoparticles is inserted in the middle of the anisotropic layer. We investigate the effects of both anisotropy angle and anisotropy ratio on the transport of nanoparticles in saturated porous media. It is found that the concentration plume and porosity contours follow closely the principal direction of anisotropy of permeability of the central domain.
Numerical investigation of nanoparticles transport in anisotropic porous media.
Salama, Amgad; Negara, Ardiansyah; El Amin, Mohamed; Sun, Shuyu
2015-10-01
In this work the problem related to the transport of nanoparticles in anisotropic porous media is investigated numerically using the multipoint flux approximation. Anisotropy of porous media properties is an essential feature that exists almost everywhere in subsurface formations. In anisotropic media, the flux and the pressure gradient vectors are no longer collinear and therefore interesting patterns emerge. The transport of nanoparticles in subsurface formations is affected by several complex processes including surface charges, heterogeneity of nanoparticles and soil grain collectors, interfacial dynamics of double-layer and many others. We use the framework of the theory of filtration in this investigation. Processes like particles deposition, entrapment, as well as detachment are accounted for. From the numerical methods point of view, traditional two-point flux finite difference approximation cannot handle anisotropy of media properties. Therefore, in this work we use the multipoint flux approximation (MPFA). In this technique, the flux components are affected by more neighboring points as opposed to the mere two points that are usually used in traditional finite volume methods. We also use the experimenting pressure field approach which automatically constructs the global system of equations by solving multitude of local problems. This approach facilitates to a large extent the construction of the global system. A set of numerical examples is considered involving two-dimensional rectangular domain. A source of nanoparticles is inserted in the middle of the anisotropic layer. We investigate the effects of both anisotropy angle and anisotropy ratio on the transport of nanoparticles in saturated porous media. It is found that the concentration plume and porosity contours follow closely the principal direction of anisotropy of permeability of the central domain. PMID:26212784
Numerical investigation of nanoparticles transport in anisotropic porous media
Salama, Amgad
2015-07-13
In this work the problem related to the transport of nanoparticles in anisotropic porous media is investigated numerically using the multipoint flux approximation. Anisotropy of porous media properties are an essential feature that exist almost everywhere in subsurface formations. In anisotropic media, the flux and the pressure gradient vectors are no longer collinear and therefore interesting patterns emerge. The transport of nanoparticles in subsurface formations is affected by several complex processes including surface charges, heterogeneity of nanoparticles and soil grain collectors, interfacial dynamics of double-layer and many others. We use the framework of the theory of filtration in this investigation. Processes like particles deposition, entrapment, as well as detachment are accounted for. From the numerical methods point of view, traditional two-point flux finite difference approximation cannot handle anisotropy of media properties. Therefore, in this work we use the multipoint flux approximation (MPFA). In this technique, the flux components are affected by more neighboring points as opposed to the mere two points that are usually used in traditional finite volume methods. We also use the experimenting pressure field approach which automatically constructs the global system of equations by solving multitude of local problems. This approach facilitates to a large extent the construction of the global system. A set of numerical examples is considered involving two-dimensional rectangular domain. A source of nanoparticles is inserted in the middle of the anisotropic layer. We investigate the effects of both anisotropy angle and anisotropy ratio on the transport of nanoparticles in saturated porous media. It is found that the concentration plume and porosity contours follow closely the principal direction of anisotropy of permeability of the central domain.
Indian Academy of Sciences (India)
Anup Saha; Santimoy Kundu; Shishir Gupta; Pramod Kumar Vaishnav
2016-06-01
The present paper is concerned with the propagation of torsional surface waves in an initially stressedanisotropic porous layer sandwiched between homogeneous and non-homogeneous half-space. We assumethe quadratic inhomogeneity in rigidity and density in the lower half-space and irregularity is taken inthe form of rectangle at the interface separating the layer from the lower half-space. The dispersionequation for torsional waves has been obtained in a closed form. Velocity equation is also obtained inthe absence of irregularity. The study reveals that the presence of irregularity, initial stress, porosity,inhomogeneity and anisotropy factor in the dispersion equation approves the significant effect of theseparameters in the propagation of torsional waves in porous medium. It has also been observed that fora uniform media, the velocity equation reduces to the classical result of Love wave.
Lifting a large object from an anisotropic porous bed
Karmakar, Timir; Raja Sekhar, G. P.
2016-09-01
An analytical study of two dimensional problem of lifting an object from the top of a fully saturated rigid porous bed is discussed. It is assumed that the porous bed is anisotropic in nature. The flow within the gap region between the object and the porous bed is assumed to be governed by Stokes equation while the flow within the porous bed is governed by Brinkman equation. The breakout phenomenon for different kinds of soil is reported. The effect of mechanical properties like anisotropic permeability, grain diameter size, and porosity on streamlines, velocity, and force is analyzed. Relevant comparison with C. C. Mei, R. W. Yeung, and K. F. Liu ["Lifting a large object from a porous bed," J. Fluid. Mech. 152, 203-215 (1985)] and Y. Chang, L. H. Huang and F. P. Y. Yang ["Two-dimensional lift-up problem for a rigid porous bed," Phys. Fluids, 27, 053101 (2015)] is done.
Anisotropic Optical Properties of Layered Germanium Sulfide
Tan, Dezhi; Wang, Feijiu; Mohamed, Nur Baizura; Mouri, Shinichiro; Sandhaya, Koirala; Zhang, Wenjing; Miyauchi, Yuhei; Ohfuchi, Mari; Matsuda, Kazunari
2016-01-01
Two-dimensional (2D) layered materials, transition metal dichalcogenides and black phosphorus, have attracted much interest from the viewpoints of fundamental physics and device applications. The establishment of new functionalities in anisotropic layered 2D materials is a challenging but rewarding frontier, owing to their remarkable optical properties and prospects for new devices. Here, we report the anisotropic optical properties of layered 2D monochalcogenide of germanium sulfide (GeS). Three Raman scattering peaks corresponding to the B3g, A1g, and A2g modes with strong polarization dependence are demonstrated in the GeS flakes, which validates polarized Raman spectroscopy as an effective method for identifying the crystal orientation of anisotropic layered GeS. Photoluminescence (PL) is observed with a peak at around 1.66 eV that originates from the direct optical transition in GeS at room temperature. Moreover, determination of the polarization dependent characteristics of the PL and absorption reveals...
Fundamental Solution of the Anisotropic Porous Medium Equation
Institute of Scientific and Technical Information of China (English)
Bin Heng SONG; Huai Yu JIAN
2005-01-01
We establish the existence of fundamental solutions for the anisotropic porous medium equation, ut = ∑n i=1(umi)xixi in sRn × (0,∞), where m1,m2,..., and mn are positive constants satisfying min1≤i≤n{mi} ≤ 1, Σni=i mi ＞ n -- 2, and max1≤i≤n{mi} ≤1/n+ Σi=1 mi).
Effective stress law for anisotropic double porous media
Institute of Scientific and Technical Information of China (English)
ZHAO Ying; CHEN Mian; ZHANG Guangqing
2004-01-01
An effective stress law is derived analytically to describe the effect of pore (fracture pore and matrix-block pore) fluid pressure on the linearly elastic response of anisotropic saturated dual-porous rocks, which exhibit anisotropy. For general anisotropy the difference between the effective stress and the applied stress is not hydrostatic simply multiplied by Biot coefficient. The effective stress law involves four constants for transversely isotropic response; these constants can be expressed in terms of the moduli of the single porous material, double porous material and of the solid material. These expressions are simplified considerably when the anisotropy is structural rather than intrinsic, i.e. in the case of an isotropic solid material with an anisotropic pore structure. In this case the effective stress law involves grain bulk modulus, four moduli and two compliances of the porous material for transverse isotropy. The law reduces, in the case of isotropic response, to that suggested by Li Shuiquan (2001). And reduction to the single-porosity (derived analytically by Carroll (1979)) is presented to demonstrate the conceptual consistency of the proposed law.
On Backus average for generally anisotropic layers
Bos, Len; Slawinski, Michael A; Stanoev, Theodore
2016-01-01
In this paper, following the Backus (1962) approach, we examine expressions for elasticity parameters of a homogeneous generally anisotropic medium that is long-wave-equivalent to a stack of thin generally anisotropic layers. These expressions reduce to the results of Backus (1962) for the case of isotropic and transversely isotropic layers. In over half-a-century since the publications of Backus (1962) there have been numerous publications applying and extending that formulation. However, neither George Backus nor the authors of the present paper are aware of further examinations of mathematical underpinnings of the original formulation; hence, this paper. We prove that---within the long-wave approximation---if the thin layers obey stability conditions then so does the equivalent medium. We examine---within the Backus-average context---the approximation of the average of a product as the product of averages, and express it as a proposition in terms of an upper bound. In the presented examination we use the e...
Electrically Anisotropic Layered Perovskite Single Crystal
Li, Ting-You
2016-04-01
Organic-inorganic hybrid perovskites (OIHPs), which are promising materials for electronic and optoelectronic applications (1-10), have made into layered organic-inorganic hybrid perovskites (LOIHPs). These LOIHPs have been applied to thin-film transistors, solar cells and tunable wavelength phosphors (11-18). It is known that devices fabricated with single crystal exhibit the superior performance, which makes the growth of large-sized single crystals critical for future device applications (19-23). However, the difficulty in growing large-sized LOIHPs single crystal with superior electrical properties limits their practical applications. Here, we report a method to grow the centimeter-scaled LOIHP single crystal of [(HOC2H4NH3)2PbI4], demonstrating the potentials in mass production. After that, we reveal anisotropic electrical and optoelectronic properties which proved the carrier propagating along inorganic framework. The carrier mobility of in-inorganic-plane (in-plane) devices shows the average value of 45 cm2 V–1 s–1 which is about 100 times greater than the record of LOIHP devices (15), showing the importance of single crystal in device application. Moreover, the LOIHP single crystals show its ultra-short carrier lifetime of 42.7 ps and photoluminescence quantum efficiency (PLQE) of 25.4 %. We expect this report to be a start of LOIHPs for advanced applications in which the anisotropic properties are needed (24-25), and meets the demand of high-speed applications and fast-response applications.
Fabric dependence of quasi-waves in anisotropic porous media.
Cardoso, Luis; Cowin, Stephen C
2011-05-01
Assessment of bone loss and osteoporosis by ultrasound systems is based on the speed of sound and broadband ultrasound attenuation of a single wave. However, the existence of a second wave in cancellous bone has been reported and its existence is an unequivocal signature of poroelastic media. To account for the fact that ultrasound is sensitive to microarchitecture as well as bone mineral density (BMD), a fabric-dependent anisotropic poroelastic wave propagation theory was recently developed for pure wave modes propagating along a plane of symmetry in an anisotropic medium. Key to this development was the inclusion of the fabric tensor--a quantitative stereological measure of the degree of structural anisotropy of bone--into the linear poroelasticity theory. In the present study, this framework is extended to the propagation of mixed wave modes along an arbitrary direction in anisotropic porous media called quasi-waves. It was found that differences between phase and group velocities are due to the anisotropy of the bone microarchitecture, and that the experimental wave velocities are more accurately predicted by the poroelastic model when the fabric tensor variable is taken into account. This poroelastic wave propagation theory represents an alternative for bone quality assessment beyond BMD. PMID:21568431
Anisotropic damage coupled modeling of saturated porous rock
Institute of Scientific and Technical Information of China (English)
无
2010-01-01
It is widely acknowledged that the natural rock mass is anisotropic and its failing type is also non-isotropic. An orthotropic elastic damaged model has been proposed in which the elastic deformation,the damaged deformation and irreversible deformation can be identified respectively. A second rank damage tensor is employed to characterize the induced damage and damage evolution related to the propagation conditions of microcracks. A specific form of the Gibbs free energy function is used to obtain the effective elastic stiffness and the limited scopes of damage parameters are suggested. The model’s parameter determination is proposed by virtue of conventional tri-axial test. Then,the proposed model is developed to simulate the coupled hydraulic mechanical responses and traction behaviors in different loading paths of porous media.
Institute of Scientific and Technical Information of China (English)
CAI; Ruixian; GOU; Chenhua; ZHANG; Na
2005-01-01
Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.
Electric double layer of anisotropic dielectric colloids under electric fields
Han, M.; Wu, H.; Luijten, E.
2016-07-01
Anisotropic colloidal particles constitute an important class of building blocks for self-assembly directed by electrical fields. The aggregation of these building blocks is driven by induced dipole moments, which arise from an interplay between dielectric effects and the electric double layer. For particles that are anisotropic in shape, charge distribution, and dielectric properties, calculation of the electric double layer requires coupling of the ionic dynamics to a Poisson solver. We apply recently proposed methods to solve this problem for experimentally employed colloids in static and time-dependent electric fields. This allows us to predict the effects of field strength and frequency on the colloidal properties.
Coupling two-phase fluid flow with two-phase darcy flow in anisotropic porous media
Chen, J.
2014-06-03
This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow. 2014 Jie Chen et al.
Modeling of CMUTs with Multiple Anisotropic Layers and Residual Stress
DEFF Research Database (Denmark)
Engholm, Mathias; Thomsen, Erik Vilain
2014-01-01
Usually the analytical approach for modeling CMUTs uses the single layer plate equation to obtain the deflection and does not take anisotropy and residual stress into account. A highly accurate model is developed for analytical characterization of CMUTs taking an arbitrary number of layers...... and residual stress into account. Based on the stress-strain relation of each layer and balancing stress resultants and bending moments, a general multilayered anisotropic plate equation is developed for plates with an arbitrary number of layers. The exact deflection profile is calculated for a circular...... clamped plate of anisotropic materials with residual bi-axial stress. From the deflection shape the critical stress for buckling is calculated and by using the Rayleigh-Ritz method the natural frequency is estimated....
Wave propagation in layered anisotropic media with application to composites
Nayfeh, AH
1995-01-01
Recent advances in the study of the dynamic behavior of layered materials in general, and laminated fibrous composites in particular, are presented in this book. The need to understand the microstructural behavior of such classes of materials has brought a new challenge to existing analytical tools. This book explores the fundamental question of how mechanical waves propagate and interact with layered anisotropic media. The chapters are organized in a logical sequence depending upon the complexity of the physical model and its mathematical treatment.
Sophia Haussener; Aldo Steinfeld
2012-01-01
High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct pore-level numerical simulations for determining the morphological and effective heat/mass transport properties of porous ceria, namely: porosity, specific surface area, pore size distribution, extinction coefficient, thermal conductivity, conv...
Modeling of plates with multiple anisotropic layers and residual stress
DEFF Research Database (Denmark)
Engholm, Mathias; Pedersen, Thomas; Thomsen, Erik Vilain
2016-01-01
Usually the analytical approach for modeling of plates uses the single layer plate equation to obtain the deflection and does not take anisotropy and residual stress into account. Based on the stress–strain relation of each layer and balancing stress resultants and bending moments, a general...... multilayered anisotropic plate equation is developed for plates with an arbitrary number of layers. The exact deflection profile is calculated for a circular clamped plate of anisotropic materials with residual bi-axial stress.From the deflection shape the critical stress for buckling is calculated......, and an excellent agreement between the two models is seen with a relative difference of less than 2% for all calculations. The model was also used to extract the cell capacitance, the parasitic capacitance and the residual stress of a pressure sensor composed of a multilayered plate of silicon and silicon oxide...
Plane strain consolidation of soil layer with anisotropic permeability
Institute of Scientific and Technical Information of China (English)
Zhi-yong AI; Chao WU
2009-01-01
This paper presents an alternative analytical technique to study a plane strain consolidation of a poroelastic soil by taking into account the anisotropy of permeability. From the governing equations of a saturated poroelastic soil, the relationship of basic variables for a point of a soil layer is established between the ground surface (z=0) and the depth z in the Laplace-Fourier transform domain. Combined with the boundary conditions, an exact solution is derived for plane strain Biot's consolidation of a finite soil layer with anisotropic permeability in the transform domain. Numerical inversions of the Laplace transform and the Fourier transform are adopted to obtain the actual solution in the physical domain. Numerical results of plane strain Biot's consolidation for a single soil layer show that the anisotropic of permeability has a great influence on the consolidation behavior of the soils.
Van der Waals interaction torque and force between dielectrically anisotropic layered media
Lu, Bing-Sui
2016-01-01
We analyse the van der Waals interaction for a pair of dielectrically anisotropic plane-layered media interacting across a dielectrically isotropic medium. We investigate the van der Waals torque and force for the following cases: (i) a pair of single anisotropic layers, (ii) a single anisotropic layer interacting with a multilayered slab consisting of alternating anisotropic and isotropic layers, and (iii) a pair of multilayered slabs each consisting of alternating anisotropic and isotropic layers, looking at the cases where the optical axes lie parallel and/or perpendicular to the plane of the layers. For the first case, the optical axes of the oppositely facing anisotropic layers of the two interacting slabs generally have an angular mismatch, and within each multilayered slab the optical axes may either be the same, or undergo constant angular increments across the anisotropic layers. In particular, we examine how the behaviors of the van der Waals torque and force can be "tuned" by adjusting the layer th...
Layer like porous materials with hierarchical structure.
Roth, Wieslaw J; Gil, Barbara; Makowski, Wacław; Marszalek, Bartosz; Eliášová, Pavla
2016-06-13
Many chemical compositions produce layered solids consisting of extended sheets with thickness not greater than a few nanometers. The layers are weakly bonded together in a crystal and can be modified into various nanoarchitectures including porous hierarchical structures. Several classes of 2-dimensional (2D) materials have been extensively studied and developed because of their potential usefulness as catalysts and sorbents. They are discussed in this review with focus on clays, layered transition metal oxides, silicates, layered double hydroxides, metal(iv) phosphates and phosphonates, especially zirconium, and zeolites. Pillaring and delamination are the primary methods for structural modification and pore tailoring. The reported approaches are described and compared for the different classes of materials. The methods of characterization include identification by X-ray diffraction and microscopy, pore size analysis and activity assessment by IR spectroscopy and catalytic testing. The discovery of layered zeolites was a fundamental breakthrough that created unprecedented opportunities because of (i) inherent strong acid sites that make them very active catalytically, (ii) porosity through the layers and (iii) bridging of 2D and 3D structures. Approximately 16 different types of layered zeolite structures and modifications have been identified as distinct forms. It is also expected that many among the over 200 recognized zeolite frameworks can produce layered precursors. Additional advances enabled by 2D zeolites include synthesis of layered materials by design, hierarchical structures obtained by direct synthesis and top-down preparation of layered materials from 3D frameworks. PMID:26489452
Slow wave cavity resonance in periodic stacks of anisotropic layers
Figotin, Alex
2007-01-01
We consider Fabry-Perot cavity resonance in periodic layered structures involving birefringent layers. Previously we have shown that the presence of birefringent layers with misaligned in-plane anisotropy can dramatically enhance the performance of the photonic-crystal cavity. It allows to reduce the size of a Fabry-Perot resonator by an order of magnitude without compromising on its performance. The key characteristic of the enhanced photonic-crystal cavity is that its Bloch dispersion relation displays a degenerate photonic band edge, rather than only regular ones. This can be realized in specially arranged stacks of misaligned anisotropic layers. On the down side, the presence of birefringent layers results in the Fabry-Perot resonance being coupled only with one (elliptic) polarization component of the incident wave, while the other polarization component is reflected back to space. In this paper we show how a small modification of the periodic layered array can solve the above fundamental problem and pro...
Elastodynamic analysis of anisotropic liquid-saturated porous medium due to mechanical sources
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
Elastodynamlc analysis of an anisotropic liquid-saturated porous medium is made to study a deformation problem of a transversely isotropic liquid-saturated porous medium due to mechanical sources. Certain physical problems are of the nature, in which the deformation takes place only in one direction, e.g., the problem relating to deformed structures and columns. In soil mechanics, an assumption of only vertical subsidence is often invoked and this leads to the one dimensional model of poroelasticity. By considering a model of one-dimensional deformation of the anisotropic liquid-saturated porous medium, variations in disturbances are observed with reference to time and distance.The distributions of displacements and stresses are affected due to the anisotropy of the medium, and also due to the type of sources causing the disturbances.
Fabric dependence of quasi-waves in anisotropic porous media
Cardoso, Luis; Cowin, Stephen C.
2011-01-01
Assessment of bone loss and osteoporosis by ultrasound systems is based on the speed of sound and broadband ultrasound attenuation of a single wave. However, the existence of a second wave in cancellous bone has been reported and its existence is an unequivocal signature of poroelastic media. To account for the fact that ultrasound is sensitive to microarchitecture as well as bone mineral density (BMD), a fabric-dependent anisotropic poroelastic wave propagation theory was recently developed ...
Equivalent medium theory of layered sphere particle with anisotropic shells
Li, Xingcai; Wang, Minzhong; Zhang, Beidou
2016-08-01
Researches on the optical properties of small particle have been widely concerned in the atmospheric science, astronomy, astrophysics, biology and medical science. This paper provides an equivalent dielectric theory for the functional graded particle with anisotropic shells, in which inhomogeneous and anisotropic particle was equivalently transformed into a new kind of homogeneous, continuous and isotropic sphere with same size but different permittivity, and then greatly simplify the calculation process of particle's optical property. Meanwhile, the paper also discusses whether the charge on the particle can change the expression of its equivalent permittivity or not. These results proposed in this paper can be used to simulate the electrical, optical properties of layered sphere, it also meet the research requirement in the design of functional graded particles in different subjects.
Anisotropic Josephson-vortex dynamics in layered organic superconductors
Energy Technology Data Exchange (ETDEWEB)
Yasuzuka, S., E-mail: yasuzuka@chem.tsukuba.ac.j [Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571 (Japan); Uji, S.; Satsukawa, H.; Kimata, M.; Terashima, T. [National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0003 (Japan); Koga, H.; Yamamura, Y.; Saito, K. [Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571 (Japan); Akutsu, H.; Yamada, J. [Department of Material Science, Graduate School of Material Science, University of Hyogo, Ako-gun, Hyogo 678-1297 (Japan)
2010-06-01
To study the anisotropic Josephson-vortex dynamics in the d-wave superconductors, the interplane resistance has been measured on layered organic superconductors {kappa}-(ET){sub 2}Cu(NCS){sub 2} and {beta}-(BDA-TTP){sub 2}SbF{sub 6} under magnetic fields precisely parallel to the conducting planes. For {kappa}-(ET){sub 2}Cu(NCS){sub 2}, in-plane angular dependence of the Josephson-vortex flow resistance is mainly described by the fourfold symmetry and dip structures appear when the magnetic field is applied parallel to the b- and c-axes. The obtained results have a relation to the d-wave superconducting gap symmetry. However, the absence of in-plane fourfold anisotropy was found for {beta}-(BDA-TTP){sub 2}SbF{sub 6}. The different anisotropic behavior is discussed in terms of the interlayer coupling strength.
Institute of Scientific and Technical Information of China (English)
蔡睿贤; 张娜
2002-01-01
Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model an improved Darcy model describing the natural convection in porous media. Besides their important theoretical meaning (for example, to analyze the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions to promoting the develop ment of computational heat and mass transfer. For instance, we can use them to check the accuracy,convergence and effectiveness of various numerical computational methods and to improve numerical calculation skills such as differential schemes and grid generation ways.
Generalization of the van der Waals equation for anisotropic fluids in porous media
Holovko, Myroslav; Shmotolokha, Volodymyr
2015-01-01
The generalized van der Waals equation of state for anisotropic liquids in porous media consists of two terms.One of them is based on the equation of state for hard spherocylinders in random porous media obtained from the scaled particle theory.The second term is expressed in terms of the mean value of attractive intermolecular interactions.The obtained equation is used for the investigation of the gas-liquid-nematic phase behavior of a molecular system depending on the anisotropy of molecule...
Debbaut, Charlotte; Vierendeels, Jan; Siggers, Jennifer H.; Repetto, Rodolfo; Monbaliu, Diethard; Segers, Patrick
2014-01-01
The hepatic blood circulation is complex, particularly at the microcirculatory level. Previously, 2D liver lobule models using porous media and a 3D model using real sinusoidal geometries have been developed. We extended these models to investigate the role of vascular septa (VS) and anisotropic permeability. The lobule was modelled as a hexagonal prism (with or without VS) and the tissue was treated as a porous medium (isotropic or anisotropic permeability). Models were solved using computat...
ON FREE WAVE PROPAGATION IN ANISOTROPIC LAYERED MEDIA
Institute of Scientific and Technical Information of China (English)
Yongqiang Guo; Weiqiu Chen
2008-01-01
The method of reverberation-ray matrix (MRRM) is extended and modified for the analysis of free wave propagation in anisotropic layered elastic media. A general, numerically stable formulation is established within the state space framework. The compatibility of physical variables in local dual coordinates gives the phase relation, from which exponentially growing functions are excluded. The interface and boundary conditions lead to the scattering relation,which avoids matrix inversion operation. Numerical examples are given to show the high accuracy of the present MRRM.
Computation of the transient flow in zoned anisotropic porous media by the boundary element method
Bruch, E.; Grilli, S.
Results on the application of the BEM to transient two-dimensional flows in zoned anisotropic porous media are presented, including the iterative calculation of the free surface seepage position. The classical BEM equations are discretized by linear, quadratic, or cubic elements, employing special singular numerical quadrature rules. The method is improved by the incorporation of a subregion division. The present technique is shown to be very accurate and to avoid previously encountered oscillation problems.
Imaging anisotropic layering with Bayesian inversion of multiple data types
Bodin, T.; Leiva, J.; Romanowicz, B.; Maupin, V.; Yuan, H.
2016-07-01
Azimuthal anisotropy is a powerful tool to reveal information about both the present structure and past evolution of the mantle. Anisotropic images of the upper mantle are usually obtained by analysing various types of seismic observables, such as surface wave dispersion curves or waveforms, SKS splitting data, or receiver functions. These different data types sample different volumes of the earth, they are sensitive to different length scales, and hence are associated with different levels of uncertainties. They are traditionally interpreted separately, and often result in incompatible models. We present a Bayesian inversion approach to jointly invert these different data types. Seismograms for SKS and P phases are directly inverted using a cross-convolution approach, thus avoiding intermediate processing steps, such as numerical deconvolution or computation of splitting parameters. Probabilistic 1-D profiles are obtained with a transdimensional Markov chain Monte Carlo scheme, in which the number of layers, as well as the presence or absence of anisotropy in each layer, are treated as unknown parameters. In this way, seismic anisotropy is only introduced if required by the data. The algorithm is used to resolve both isotropic and anisotropic layering down to a depth of 350 km beneath two seismic stations in North America in two different tectonic settings: the stable Canadian shield (station FFC) and the tectonically active southern Basin and Range Province (station TA-214A). In both cases, the lithosphere-asthenosphere boundary is clearly visible, and marked by a change in direction of the fast axis of anisotropy. Our study confirms that azimuthal anisotropy is a powerful tool for detecting layering in the upper mantle.
A robust absorbing layer method for anisotropic seismic wave modeling
Energy Technology Data Exchange (ETDEWEB)
Métivier, L., E-mail: ludovic.metivier@ujf-grenoble.fr [LJK, CNRS, Université de Grenoble, BP 53, 38041 Grenoble Cedex 09 (France); ISTerre, Université de Grenoble I, BP 53, 38041 Grenoble Cedex 09 (France); Brossier, R. [ISTerre, Université de Grenoble I, BP 53, 38041 Grenoble Cedex 09 (France); Labbé, S. [LJK, CNRS, Université de Grenoble, BP 53, 38041 Grenoble Cedex 09 (France); Operto, S. [Géoazur, Université de Nice Sophia-Antipolis, CNRS, IRD, OCA, Villefranche-sur-Mer (France); Virieux, J. [ISTerre, Université de Grenoble I, BP 53, 38041 Grenoble Cedex 09 (France)
2014-12-15
When applied to wave propagation modeling in anisotropic media, Perfectly Matched Layers (PML) exhibit instabilities. Incoming waves are amplified instead of being absorbed. Overcoming this difficulty is crucial as in many seismic imaging applications, accounting accurately for the subsurface anisotropy is mandatory. In this study, we present the SMART layer method as an alternative to PML approach. This method is based on the decomposition of the wavefield into components propagating inward and outward the domain of interest. Only outgoing components are damped. We show that for elastic and acoustic wave propagation in Transverse Isotropic media, the SMART layer is unconditionally dissipative: no amplification of the wavefield is possible. The SMART layers are not perfectly matched, therefore less accurate than conventional PML. However, a reasonable increase of the layer size yields an accuracy similar to PML. Finally, we illustrate that the selective damping strategy on which is based the SMART method can prevent the generation of spurious S-waves by embedding the source in a small zone where only S-waves are damped.
Thermal conduction in single-layer black phosphorus: highly anisotropic?
International Nuclear Information System (INIS)
The single-layer black phosphorus is characteristic for its puckered structure, which has led to distinct anisotropy in its optical, electronic, and mechanical properties. We use the non-equilibrium Green's function approach and the first-principles method to investigate the thermal conductance for single-layer black phosphorus in the ballistic transport regime, in which the phonon–phonon scattering is neglected. We find that the anisotropy in the thermal conduction is very weak for the single-layer black phosphorus—the difference between two in-plane directions is less than 4%. Our phonon calculations disclose that the out-of-plane acoustic phonon branch has lower group velocities in the direction perpendicular to the pucker, as the black phosphorus is softer in this direction, leading to a weakening effect for the thermal conductance in the perpendicular direction. However, the longitudinal acoustic phonon branch behaves abnormally; i.e., the group velocity of this phonon branch is higher in the perpendicular direction, although the single-layer black phosphorus is softer in this direction. The abnormal behavior of the longitudinal acoustic phonon branch is closely related to the highly anisotropic Poisson's ratio in the single-layer black phosphorus. As a result of the counteraction between the out-of-plane phonon mode and the in-plane phonon modes, the thermal conductance in the perpendicular direction is weaker than the parallel direction, but the anisotropy is pretty small. (paper)
Negara, Ardiansyah
2014-04-21
Carbon dioxide (CO2) sequestration in saline aquifers is considered as one of the most viable and promising ways to reduce CO2 concentration in the atmosphere. CO2 is injected into deep saline formations at supercritical state where its density is smaller than the hosting brine. This motivates an upward motion and eventually CO2 is trapped beneath the cap rock. The trapped CO2 slowly dissolves into the brine causing the density of the mixture to become larger than the host brine. This causes gravitational instabilities that is propagated and magnified with time. In this kind of density-driven flows, the CO2-rich brines migrate downward while the brines with low CO2 concentration move upward. With respect to the properties of the subsurface aquifers, there are instances where saline formations can possess anisotropy with respect to their hydraulic properties. Such anisotropy can have significant effect on the onset and propagation of flow instabilities. Anisotropy is predicted to be more influential in dictating the direction of the convective flow. To account for permeability anisotropy, the method of multipoint flux approximation (MPFA) in the framework of finite differences schemes is used. The MPFA method requires more point stencil than the traditional two-point flux approximation (TPFA). For example, calculation of one flux component requires 6-point stencil and 18-point stencil in 2-D and 3-D cases, respectively. As consequence, the matrix of coefficient for obtaining the pressure fields will be quite complex. Therefore, we combine the MPFA method with the experimenting pressure field technique in which the problem is reduced to solving multitude of local problems and the global matrix of coefficients is constructed automatically, which significantly reduces the complexity. We present several numerical scenarios of density-driven flow simulation in homogeneous, layered, and heterogeneous anisotropic porous media. The numerical results emphasize the
Energy Technology Data Exchange (ETDEWEB)
Berryman, J.G.
2009-11-20
Poroelastic analysis usually progresses from assumed knowledge of dry or drained porous media to the predicted behavior of fluid-saturated and undrained porous media. Unfortunately, the experimental situation is often incompatible with these assumptions, especially when field data (from hydrological or oil/gas reservoirs) are involved. The present work considers several different experimental scenarios typified by one in which a set of undrained poroelastic (stiffness) constants has been measured using either ultrasound or seismic wave analysis, while some or all of the dry or drained constants are normally unknown. Drained constants for such a poroelastic system can be deduced for isotropic systems from available data if a complete set of undrained compliance data for the principal stresses are available - together with a few other commonly measured quantities such as porosity, fluid bulk modulus, and grain bulk modulus. Similar results are also developed here for anisotropic systems having up to orthotropic symmetry if the system is granular (i.e., composed of solid grains assembled into a solid matrix, either by a cementation process or by applied stress) and the grains are known to be elastically homogeneous. Finally, the analysis is also fully developed for anisotropic systems with nonhomogeneous (more than one mineral type), but still isotropic, grains - as well as for uniform collections of anisotropic grains as long as their axes of symmetry are either perfectly aligned or perfectly random.
Transverse mixing in three-dimensional nonstationary anisotropic heterogeneous porous media
DEFF Research Database (Denmark)
Cirpka, Olaf; Chiogna, Gabriele; Rolle, Massimo;
2015-01-01
flow and transport results obtained for a nonstationary anisotropic log-hydraulic conductivity field to an equivalent stationary field with identical mean, variance, and two-point correlation function disregarding the nonstationarity. The nonstationary anisotropic field is affected by mean secondary......Groundwater plumes originating from continuously emitting sources are typically controlled by transverse mixing between the plume and reactants in the ambient solution. In two-dimensional domains, heterogeneity causes only weak enhancement of transverse mixing in steady-state flows. In three......-dimensional domains, more complex flow patterns are possible because streamlines can twist. In particular, spatially varying orientation of anisotropy can cause steady-state groundwater whirls. We analyze steady-state solute transport in three-dimensional locally isotropic heterogeneous porous media with blockwise...
Directory of Open Access Journals (Sweden)
Sophia Haussener
2012-01-01
Full Text Available High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct pore-level numerical simulations for determining the morphological and effective heat/mass transport properties of porous ceria, namely: porosity, specific surface area, pore size distribution, extinction coefficient, thermal conductivity, convective heat transfer coefficient, permeability, Dupuit-Forchheimer coefficient, and tortuosity and residence time distributions. Tailored foam designs for enhanced transport properties are examined by means of adjusting morphologies of artificial ceria samples composed of bimodal distributed overlapping transparent spheres in an opaque medium.
Deposited Micro Porous Layer as Lubricant Carrier in Metal Forming
DEFF Research Database (Denmark)
Arentoft, Mogens; Bay, Niels; Tang, Peter Torben;
2008-01-01
A new porous coating for carrying lubricant in metal forming processes is developed. The coating is established by simultaneous electrochemical deposition of two pure metals. One of them is subsequently etched away leaving a porous surface layer. Lubricant can be trapped in the pores acting as lu...
Lamb waves in a thin isotropic layer between two anisotropic layers
Institute of Scientific and Technical Information of China (English)
ZHANG Haiyan; ZHOU Quan; L(U) Donghui
2004-01-01
Attenuative Lamb wave propagation in adhesively bonded anisotropic composite plates is introduced. The isotropic adhesive exhibits viscous behavior to stimulate the poor curing of the middle layer. Viscosity is assumed to vary linearly with frequency, implying that attenuation per wavelength is constant. Attenuation can be implemented in the analysis through modification of elastic properties of isotropic adhesive. The new properties become complex, but cause no further complications in the analysis. The characteristic equation is the same as that used for the elastic plate case, except that both real and imaginary parts of the wave number (i.e., the attenuation) must be computed. Based on the Lowe's solution in finding the complex roots of characteristic equation, the effect of longitudinal and shear attenuation coefficients of the middle adhesive layer on phase velocity dispersion curves and attenuation dispersion curves of Lamb waves propagating in bonded anisotropic composites is visualized numerically.
Nanomechanical properties of thick porous silicon layers grown on p- and p+-type bulk crystalline Si
Energy Technology Data Exchange (ETDEWEB)
Charitidis, C.A., E-mail: charitidis@chemeng.ntua.gr [National Technical University of Athens, School of Chemical Engineering 9 Heroon Polytechniou St., 15780 Zographos, Athens (Greece); Skarmoutsou, A. [National Technical University of Athens, School of Chemical Engineering 9 Heroon Polytechniou St., 15780 Zographos, Athens (Greece); Nassiopoulou, A.G.; Dragoneas, A. [IMEL/NCSR Demokritos, P.O. Box 60228, 153 10 Aghia Paraskevi Attikis, Athens (Greece)
2011-11-15
Highlights: {yields} The nanomechanical properties of bulk crystalline Si. {yields} The nanomechanical properties of porous Si. {yields} The elastic-plastic deformation of porous Si compared to bulk crystalline quantified by nanoindentation data analysis. - Abstract: The nanomechanical properties and the nanoscale deformation of thick porous Si (PSi) layers of two different morphologies, grown electrochemically on p-type and p+-type Si wafers were investigated by the depth-sensing nanoindentation technique over a small range of loads using a Berkovich indenter and were compared with those of bulk crystalline Si. The microstructure of the thick PSi layers was characterized by field emission scanning electron microscopy. PSi layers on p+-type Si show an anisotropic mesoporous structure with straight vertical pores of diameter in the range of 30-50 nm, while those on p-type Si show a sponge like mesoporous structure. The effect of the microstructure on the mechanical properties of the layers is discussed. It is shown that the hardness and Young's modulus of the PSi layers exhibit a strong dependence on their microstructure. In particular, PSi layers with the anisotropic straight vertical pores show higher hardness and elastic modulus values than sponge-like layers. However, sponge-like PSi layers reveal less plastic deformation and higher wear resistance compared with layers with straight vertical pores.
Crack Growth along Interfaces in Porous Ceramic Layers
DEFF Research Database (Denmark)
Sørensen, Bent F.; Horsewell, Andy
2001-01-01
Crack growth along porous ceramic layers was studied experimentally. Double cantilever beam sandwich specimens were loaded with pure bending moments to obtain stable crack growth. The experiments were conducted in an environmental scanning electron microscope enabling in situ observations of...
Natural convection in superposed fluid-porous layers
Bagchi, Aniruddha
2013-01-01
Natural Convection in Composite Fluid-Porous Domains provides a timely overview of the current state of understanding on the phenomenon of convection in composite fluid-porous layers. Natural convection in horizontal fluid-porous layers has received renewed attention because of engineering problems such as post-accident cooling of nuclear reactors, contaminant transport in groundwater, and convection in fibrous insulation systems. Because applications of the problem span many scientific domains, the book serves as a valuable resource for a wide audience.
Debbaut, Charlotte; Vierendeels, Jan; Siggers, Jennifer H; Repetto, Rodolfo; Monbaliu, Diethard; Segers, Patrick
2014-01-01
The hepatic blood circulation is complex, particularly at the microcirculatory level. Previously, 2D liver lobule models using porous media and a 3D model using real sinusoidal geometries have been developed. We extended these models to investigate the role of vascular septa (VS) and anisotropic permeability. The lobule was modelled as a hexagonal prism (with or without VS) and the tissue was treated as a porous medium (isotropic or anisotropic permeability). Models were solved using computational fluid dynamics. VS inclusion resulted in more spatially homogeneous perfusion. Anisotropic permeability resulted in a larger axial velocity component than isotropic permeability. A parameter study revealed that results are most sensitive to the lobule size and radial pressure drop. Our model provides insight into hepatic microhaemodynamics, and suggests that inclusion of VS in the model leads to perfusion patterns that are likely to reflect physiological reality. The model has potential for applications to unphysiological and pathological conditions. PMID:23237543
Debbaut, Charlotte; Vierendeels, Jan; Siggers, Jennifer H; Repetto, Rodolfo; Monbaliu, Diethard; Segers, Patrick
2014-01-01
The hepatic blood circulation is complex, particularly at the microcirculatory level. Previously, 2D liver lobule models using porous media and a 3D model using real sinusoidal geometries have been developed. We extended these models to investigate the role of vascular septa (VS) and anisotropic permeability. The lobule was modelled as a hexagonal prism (with or without VS) and the tissue was treated as a porous medium (isotropic or anisotropic permeability). Models were solved using computational fluid dynamics. VS inclusion resulted in more spatially homogeneous perfusion. Anisotropic permeability resulted in a larger axial velocity component than isotropic permeability. A parameter study revealed that results are most sensitive to the lobule size and radial pressure drop. Our model provides insight into hepatic microhaemodynamics, and suggests that inclusion of VS in the model leads to perfusion patterns that are likely to reflect physiological reality. The model has potential for applications to unphysiological and pathological conditions.
Flow and dispersion in anisotropic porous media: a Lattice-Boltzmann study
Maggiolo, Dario; Guarnieri, Massimo
2016-01-01
Given their capability of spreading active chemical species and collecting electricity, porous media made of carbon fibers are extensively used as diffusion layers in energy storage systems, such as redox flow batteries. In spite of this, the dispersion dynamics of species inside porous media is still not well understood and often lends itself to different interpretations. Actually, the microscopic design of efficient porous media which can potentially and effectively improve the performances of flow batteries, is a still open challenge. The present study aims to investigate the effect of fibrous media micro-structure on dispersion, in particular the effect of fiber orientation on drag and dispersion dynamics. Several Lattice-Boltzmann simulations of {flows through} differently-oriented fibrous media coupled with Lagrangian simulations of particle tracers have been performed. Results show that orienting fibers preferentially along the streamwise direction minimizes the drag and maximizes the dispersion, which...
Olariu, C. S.; Padurariu, L.; Stanculescu, R.; Baldisserri, C.; Galassi, C.; Mitoseriu, L.
2013-12-01
Anisotropic porous Pb(Zr,Ti)O3 ceramics with various porosity degrees have been studied in order to determine the role of the pore shape and orientation on the low-field dielectric properties. Ceramic samples with formula Pb(Zr0.52Ti0.48)0.976Nb0.024O3 with different porosity degrees (dense, 10%, 20%, 40% vol.) have been prepared by solid state reaction. Taking into consideration the shape and orientation of the pore inclusions, the dielectric properties of porous ceramics have been described by using adapted mixing rules models. Rigorous bounds, derived on the basis on Variational Principle, were used to frame dielectric properties of porous composites. The finite element method (FEM) was additionally used to simulate the dielectric response of the porous composites under various applied fields. Among the few effective medium approximation models adapted for anisotropic oriented inclusions, the best results were obtained in case of needle-like shape inclusions (which do not correspond to the real shape of microstructure inclusions). The general case of Wiener bounds limited well the dielectric properties of anisotropic porous composites in case of parallel orientation. Among the theoretical approaches, FEM technique allowed to simulate the distribution of potential and electric field inside composites and provided a very good agreement between the computed permittivity values and experimental ones.
Calibration of Gurson-type models for porous sheet metals with anisotropic non-quadratic plasticity
Gologanu, M.; Kami, A.; Comsa, D. S.; Banabic, D.
2016-08-01
The growth and coalescence of voids in sheet metals are not only the main active mechanisms in the final stages of fracture in a necking band, but they also contribute to the forming limits via changes in the normal directions to the yield surface. A widely accepted method to include void effects is the development of a Gurson-type model for the appropriate yield criterion, based on an approximate limit analysis of a unit cell containing a single spherical, spheroidal or ellipsoidal void. We have recently [2] obtained dissipation functions and Gurson-type models for porous sheet metals with ellipsoidal voids and anisotropic non-quadratic plasticity, including yield criteria based on linear transformations (Yld91 and Yld2004-18p) and a pure plane stress yield criteria (BBC2005). These Gurson-type models contain several parameters that depend on the void and cell geometries and on the selected yield criterion. Best results are obtained when these key parameters are calibrated via numerical simulations using the same unit cell and a few representative loading conditions. The single most important such loading condition corresponds to a pure hydrostatic macroscopic stress (pure pressure) and the corresponding velocity field found during the solution of the limit analysis problem describes the expansion of the cavity. However, for the case of sheet metals, the condition of plane stress precludes macroscopic stresses with large triaxiality or ratio of mean stress to equivalent stress, including the pure hydrostatic case. Also, pure plane stress yield criteria like BBC2005 must first be extended to 3D stresses before attempting to develop a Gurson-type model and such extensions are purely phenomenological with no due account for the out- of-plane anisotropic properties of the sheet. Therefore, we propose a new calibration method for Gurson- type models that uses only boundary conditions compatible with the plane stress requirement. For each such boundary condition we use
Negara, Ardiansyah
2015-03-04
Numerical investigations of two-phase flows in anisotropic porous media have been conducted. In the flow model, the permeability has been considered as a full tensor and is implemented in the numerical scheme using the multipoint flux approximation within the framework of finite difference method. In addition, the experimenting pressure field approach is used to obtain the solution of the pressure field, which makes the matrix of coefficient of the global system easily constructed. A number of numerical experiments on the flow of two-phase system in two-dimensional porous medium domain are presented. In this work, the gravity is included in the model to capture the possible buoyancy-driven effects due to density differences between the two phases. Different anisotropy scenarios have been considered. From the numerical results, interesting patterns of the flow, pressure, and saturation fields emerge, which are significantly influenced by the anisotropy of the absolute permeability field. It is found that the two-phase system moves along the principal direction of anisotropy. Furthermore, the effects of anisotropy orientation on the flow rates and the cross flow index are also discussed in the paper.
Ultrasonic wave's interaction at fluid-porous piezoelectric layered interface.
Vashishth, Anil K; Gupta, Vishakha
2013-02-01
The complete description of acoustic propagation in a multilayered system is of great interest in a variety of applications such as non-destructive evaluation and acoustic design and there is need for a flexible model that can describe the reflection and transmission of ultrasonic waves in these media. The reflection and transmission of ultrasonic waves from a fluid loaded porous piezoelectric layered structure is studied analytically. The layered structure is considered to be consisting of n number of layers of porous piezoelectric materials. Transfer matrix technique is used to study the layered materials. The analytical expressions for the reflected, transmitted, interaction energy ratios and surface impedance are obtained. The effects of frequency, porosity, angle of incidence, layer thickness and number of layers on the energy ratios and surface impedance are studied for different configurations of the layered materials. The results obtained are deduced for the poro-elastic and fluid loaded porous piezoelectric half space case, which are in agreement with earlier established results. A comparison of the results, obtained by alternate numerical techniques, is made.
Layers of Porous Superhydrophobic Surfaces for Robust Water Repellency
Ahmadi, Farzad; Boreyko, Jonathan; Nature-Inspired Fluids; Interfaces Team
2015-11-01
In nature, birds exhibit multiple layers of superhydrophobic feathers that repel water. Inspired by bird feathers, we utilize porous superhydrophobic surfaces and compare the wetting and dewetting characteristics of a single surface to stacks of multiple surfaces. The superhydrophobic surfaces were submerged in water in a closed chamber. Pressurized gas was regulated to measure the critical pressure for the water to fully penetrate through the surfaces. In addition to using duck feathers, two-tier porous superhydrophobic surfaces were fabricated to serve as synthetic mimics with a controlled surface structure. The energy barrier for the wetting transition was modeled as a function of the number of layers and their orientations with respect to each other. Moreover, after partial impalement into a subset of the superhydrophobic layers, it was observed that a full dewetting transition was possible, which suggests that natural organisms can exploit their multiple layers to prevent irreversible wetting.
Boundary Layer Flows in Porous Media with Lateral Mass Flux
DEFF Research Database (Denmark)
Nemati, H; H, Bararnia; Noori, F;
2015-01-01
Solutions for free convection boundary layers on a heated vertical plate with lateral mass flux embedded in a saturated porous medium are presented using the Homotopy Analysis Method and Shooting Numerical Method. Homotopy Analysis Method yields an analytic solution in the form of a rapidly...
The propagation of Lamb waves in an anisotropic plate bordered with liquid layers
Institute of Scientific and Technical Information of China (English)
YAN Ping; ZHU Zhemin; DU Gonghuan
2002-01-01
Based on elastic wave propagation theory, the dispersion equation for a thin anisotropic plate (such as commonly used Zinc oxide in micro-transducers) bordered with liquid layers is derived. Higher symmetry crystals, such as orthorhombic, tetragonal, cubic, isotropic,are included in this analysis as well. For the case of one liquid layer loading, numerical calculations show that the phase velocity changes periodically with the thickness of the liquid layer.When the thickness 2d of the anisotropic plate is very small, mass sensing application of A0mode Lamb wave is also discussed.
Description of a Furnace for the Creation of Anisotropic Porous Metals
Energy Technology Data Exchange (ETDEWEB)
Gutsch, Thomas; Miszkiel, Mark; Schmale, David T.
1999-05-01
A furnace has been built for the purpose of producing anisotropic porous metals through solid-gas eutectic solidification. This process allows control of continuously formed anisotropic pores in metals and was discovered at the State Metallurgical Academic' University in Dnepropetrovsk Ukraine. The process incorporates hydrogen gas within the metal as it solidifies from the molten state. Metals which do not form hydrides, including iron, nickel, aluminum, copper and others can be formed in this manner. The furnace is housed within a ~.64 meter³ (30 ft³) ASME code stamped cylindrical stainless steel vacuum/pressure vessel. The vessel is a water chilled vertical cylinder with removable covers at the top and bottom. It can be evacuated to 20 mTorr or pressurized to 5.5 MPa (800 psi). A charge of 2700 cc (167 in³) of molten metal can be melted in a crucible in the upper portion within a watercooled 30 cm (12 in.) ID induction coil. A 175 kW Inductotherm power source energizes the coil. Vertical actuation of a ceramic stopper rod allows the molten metal to be tapped into a solidification mold beneath the melting crucible. The cylindrical mold rests on a water cooled copper base inducing directional solidification from the bottom. Mixtures of hydrogen and argon gases are introduced during the process. The system is remotely controlled and located in a structure with frangible walls specially designed for possible ambient pressure excursions as a result of equipment failure. This paper includes a general description of the furnace and operating procedure and a detailed description of the control, monitoring and interlock systems.
Coulomb drag in anisotropic systems: a theoretical study on a double-layer phosphorene
Saberi-Pouya, S.; Vazifehshenas, T.; Farmanbar, M.; Salavati-Fard, T.
2016-01-01
We theoretically study the Coulomb drag resistivity in a double-layer electron system with highly anisotropic parabolic band structure using Boltzmann transport theory. As an example, we consider a double-layer phosphorene on which we apply our formalism. This approach, in principle, can be tuned fo
Reddy, J. N.
1981-01-01
Finite element papers published in the open literature on the static bending and free vibration of layered, anisotropic, and composite plates and shells are reviewed. A literature review of large-deflection bending and large-amplitude free oscillations of layered composite plates and shells is also presented. Non-finite element literature is cited for continuity of the discussion.
Anisotropic Diffusion of Polyelectrolyte Chains within Multi-layer Films
Energy Technology Data Exchange (ETDEWEB)
Xu, Li [Stevens Institute of Technology, Hoboken, New Jersey; Kozlovskaya, Veronika [University of Alabama, Birmingham; Kharlampieva, Eugenia [University of Alabama, Birmingham; Ankner, John Francis [ORNL; Sukhishvili, Prof. Svetlana A. [Stevens Institute of Technology, Hoboken, New Jersey
2012-01-01
We found diffusion of polyelectrolyte chains within multilayer films to be highly anisotropic, with the preferential chain motion parallel to the substrate. The degree of anisotropy was quantified by a combination of fluorescence recovery after photobleaching and neutron reflectometry, probing chain diffusion in directions parallel and perpendicular to the substrate, respectively. Chain mobility was controlled by ionic strength of annealing solutions and steric hindrance to ionic pairing of interacting polyelectrolytes.
Yong Wang; Wenzheng Yue; Mo Zhang
2016-01-01
The anisotropic transport of thermal neutron in heterogeneous porous media is of great research interests in many fields. In this paper, it is the first time that a new model based on micron X-ray computed tomography (CT) has been proposed to simultaneously consider both the separation of matrix and pore and the distribution of mineral components. We apply the Monte Carlo method to simulate thermal neutrons transporting through the model along different directions, and meanwhile detect those ...
Okazaki, T.; Oshiman, N.; Yoshimura, R.
2016-11-01
Inferring geoelectric dimensionality (1D, 2D or 3D) and directionality (strike directions) from the impedance tensor is a basic procedure in magnetotelluric data processing. Given that electrical anisotropy is increasingly recognized in observations, it is valuable to understand the imprint of anisotropy in these analyses. In this paper, we analytically investigate the estimation of strike directions based on rotational invariants in 1D anisotropic layered media. We first show that if anisotropy axes are identical in all anisotropic layers, the estimated strike coincides with that direction. We then derive an analytical formula of the strike angle at long periods for general anisotropic layers with an isotropic basement. This formula shows a clear physical interpretation that the strike angle points where the conductance integrated along depth takes a maximum value.
Non—Darcian and Anisotropic Effects on Natural Convection in Horizontal Porous Media Enclosure
Institute of Scientific and Technical Information of China (English)
ZhangJingzhou; SunRenqia
1996-01-01
Natural convection heat transfer in a horizontal enclosure filled with anisotropic porous media,being isothermally heated at bettom and cooled at top while the vertical walls being adiabatic,is numerically studied by applying the Brinkman model-a modified form of Darcy model giving consideratioin to the viscous effect.The results show that:(1)a larger permeability ratio(K*) causes a lower flow intensity in the enclosure and a smaller Nusselt number,all Nusselt numbers approach unity in the limit of K*→∞;a larger thermal conductivity ratio(λ*) causes a stranger distortion of isotherms in the enclosure and a higher flow velocity near the walls,all the Nusselt numbers approach unity in the limit of λ*-→0,the permeability and thermal conductivity ratios generally have opposing effects on the Nusselt number.(2) an increasing Darcy number decreases the flow intensity and heat tansfer rates,which is more significant at a lower permeability ratio.In particular,with K*≤0.25,the Nusselt number for Da=10-3 would differ from that of Darcy flow up to an amount of 30%,an analysis neglecting the non-Darican effect will inevitably be of considerable error.
Plasma resonance in anisotropic layered high-Tc superconductors
DEFF Research Database (Denmark)
Sakai, Shigeki; Pedersen, Niels Falsig
1999-01-01
The plasma resonance is described theoretically by the inductive coupling model for a large stacked Josephson-junction system such as the intrinsic Josephson-junction array in anisotropic high- T-c superconductors. Eigenmodes of the plasma oscillation are analytically described and a numerical...... example for the large stack case N=50 is given. The scaling length characteristic of each mode is discussed. Numerical results for the plasma resonance for N= 50 in the presence of an external rf drive with wave number k are given. For k different from zero possible resonance modes among the eigen...... oscillation modes are shown, and it is further demonstrated that for k=0 the resonance takes place as a collection of N independent resonant Josephson junctions. Some guidelines for possible experiments are shown. It is also shown that, very recent microwave experiments for the plasma resonance can...
Coulomb drag in anisotropic systems: a theoretical study on a double-layer phosphorene
Saberi-Pouya, S.; Vazifehshenas, T.; Farmanbar, M.; Salavati-fard, T.
2016-07-01
We theoretically study the Coulomb drag resistivity in a double-layer electron system with highly anisotropic parabolic band structure using Boltzmann transport theory. As an example, we consider a double-layer phosphorene on which we apply our formalism. This approach, in principle, can be tuned for other double-layered systems with paraboloidal band structures. Our calculations show the rotation of one layer with respect to another layer can be considered a way of controlling the drag resistivity in such systems. As a result of rotation, the off-diagonal elements of the drag resistivity tensor have non-zero values at any temperature. In addition, we show that the anisotropic drag resistivity is very sensitive to the direction of momentum transfer between two layers due to highly anisotropic inter-layer electron–electron interaction and also the plasmon modes. In particular, the drag anisotropy ratio, {ρyy}/{ρxx} , can reach up to ∼ 3 by changing the temperature. Furthermore, our calculations suggest that including the local field correction in the dielectric function changes the results significantly. Finally, We examine the dependence of drag resistivity and its anisotropy ratio on various parameters like inter-layer separation, electron density, short-range interaction and insulating substrate/spacer.
POROUS MEMBRANE TEMPLATED SYNTHESIS OF POLYMER PILLARED LAYER
Institute of Scientific and Technical Information of China (English)
Zhong-wei Niu; Dan Li; Zhen-zhong Yang
2003-01-01
The anodic porous alumina membranes with a definite pore diameter and aspect ratio were used as templates to synthesize polymer pillared layer structures. The pillared polymer was produced in the template membrane pores, and the layer on the template surfaces. Rigid cured epoxy resin, polystyrene and soft hydrogel were chosen to confirm the methodology. The pillars were in the form of either tubes or fibers, which were controlled by the alumina membrane pore surface wettability. The structural features were confirmed by scanning electron microscopy results.
Negara, Ardiansyah
2015-05-01
Anisotropy of hydraulic properties of the subsurface geologic formations is an essential feature that has been established as a consequence of the different geologic processes that undergo during the longer geologic time scale. With respect to subsurface reservoirs, in many cases, anisotropy plays significant role in dictating the direction of flow that becomes no longer dependent only on driving forces like the pressure gradient and gravity but also on the principal directions of anisotropy. Therefore, there has been a great deal of motivation to consider anisotropy into the subsurface flow and transport models. In this dissertation, we present subsurface flow modeling in single and dual continuum anisotropic porous media, which include the single-phase groundwater flow coupled with the solute transport in anisotropic porous media, the two-phase flow with gravity effect in anisotropic porous media, and the natural gas flow in anisotropic shale reservoirs. We have employed the multipoint flux approximation (MPFA) method to handle anisotropy in the flow model. The MPFA method is designed to provide correct discretization of the flow equations for general orientation of the principal directions of the permeability tensor. The implementation of MPFA method is combined with the experimenting pressure field approach, a newly developed technique that enables the solution of the global problem breaks down into the solution of multitude of local problems. The numerical results of the study demonstrate the significant effects of anisotropy of the subsurface formations. For the single-phase groundwater flow coupled with the solute transport modeling in anisotropic porous media, the results shows the strong impact of anisotropy on the pressure field and the migration of the solute concentration. For the two-phase flow modeling with gravity effect in anisotropic porous media, it is observed that the buoyancy-driven flow, which emerges due to the density differences between the
Sanchez-Valencia, Juan Ramon; Longtin, Remi; Rossell, Marta D; Gröning, Pierangelo
2016-04-01
We report a new methodology based on glancing angle deposition (GLAD) of an organic molecule in combination with perpendicular growth of a second inorganic material. The resulting thin films retain a very well-defined tilted columnar microstructure characteristic of GLAD with the inorganic material embedded inside the columns. We refer to this new methodology as growth assisted by glancing angle deposition or GAGLAD, since the material of interest (here, the inorganic) grows in the form of tilted columns, though it is deposited under a nonglancing configuration. As a "proof of concept", we have used silver and zinc oxide as the perpendicularly deposited material since they usually form ill-defined columnar microstructures at room temperature by GLAD. By means of our GAGLAD methodology, the typical tilted columnar microstructure can be developed for materials that otherwise do not form ordered structures under conventional GLAD. This simple methodology broadens significantly the range of materials where control of the microstructure can be achieved by tuning the geometrical deposition parameters. The two examples presented here, Ag/Alq3 and ZnO/Alq3, have been deposited by physical vapor deposition (PVD) and plasma enhanced chemical vapor deposition (PECVD), respectively: two different vacuum techniques that illustrate the generality of the proposed technique. The two type of hybrid samples present very interesting properties that demonstrate the potentiality of GAGLAD. On one hand, the Ag/Alq3 samples present highly optical anisotropic properties when they are analyzed with linearly polarized light. To our knowledge, these Ag/Alq3 samples present the highest angular selectivity reported in the visible range. On the other hand, ZnO/Alq3 samples are used to develop highly porous ZnO thin films by using Alq3 as sacrificial material. In this way, antireflective ZnO samples with very low refractive index and extinction coefficient have been obtained. PMID:26954074
Institute of Scientific and Technical Information of China (English)
SunWeitao; YangHuizhu
2003-01-01
Based on the first-order Biot-equation with simplified coefficients, a staggered irregular-grid finite difference method (FDM) is developed to simulate elastic wave propagation in 3-D heterogeneous anisotropic porous media. The ‘slow' P wave in porous media wave simulation is highly dispersive. Finer grids are needed to get a precise wavefield calculation for models with curved interface and complex geometric structure. Fine grids in a global model greatly increase computation costs of regular grids scheme. Irregular fine or coarse grids in local fields not only cost less computing time than the conventional velocity-stress FDM, but also give a more accurate wavefield description. A dispersion analysis of the irregular-grid finite difference operator has confirmed the stability and high efficiency. The absorbing boundary condition is used to eliminate artificial reflections. Numerical examples show that this new irregular-grid finite difference method is of higher performance than conventional methods using regular rectangular grids in simulating elastic wave propagation in heterogeneous anisotropic porous media.
Time-dependent penetrative mixed convection in a porous layer
International Nuclear Information System (INIS)
In the last few decades, heat and mass transfer in porous media have been studied extensively by many investigators. The main motivations behind these studies were the wide range of applications and the interaction of multiple processes. Examples include geothermal energy production, drying of porous media, high level nuclear waste disposal, and energy-related engineering technologies. Here, a general two-dimensional, time-dependent model has been developed to investigate the transfer of heat and mass in a liquid saturated porous layer locally heated from above. Both free and mixed convection are considered. For mixed convection an eternal flow is assumed to enter the two-dimensional domain in the horizontal direction. At a finite segment of the top wall, two types of heat sources are applied: a constant flux heat source and a time varying heat, constant flux source. The latter is a representation of heat released by spent nuclear fuel in a mined repository located above the layer. Both time-dependent and steady solutions of the flow and temperature fields are obtained. For natural convection, the effects of Rayleigh number on the Nusselt number are obtained. For mixed convection, the effects of both Rayleigh and Peclet numbers are studied. In addition, the effects of the aspect ratio, as well as the length of the heated zone are examined
Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus
Fei, Ruixiang; Yang, Li
2014-05-01
Newly fabricated monolayer phosphorene and its few-layer structures are expected to be promising for electronic and optical applications because of their finite direct band gaps and sizable but anisotropic electronic mobility. By first-principles simulations, we show that this unique anisotropic conductance can be controlled by using simple strain conditions. With the appropriate biaxial or uniaxial strain, we can rotate the preferred conducting direction by 90 degrees. This will be of useful for exploring quantum Hall effects, and exotic electronic and mechanical applications based on phosphorene.
Directory of Open Access Journals (Sweden)
Amit kumar Mishra
2015-01-01
Full Text Available In this paper, we have analyzed the effect of time periodic temperature modulation on convective stability in anisotropic porous cavity. The cavity is heated from below and cooled from above. A weakly non-linear stability analysis is done to find Nusselt number governing the heat transport. The infinitely small disturbances are expanded in terms of power series of amplitude of modulation. Analytically the nonautonomous Ginzburg- landau amplitude equation is obtained for the stationary mode of convection. The effects of various parameters like Vadasz number, mechanical and thermal anisotropic parameters, amplitude of oscillations, frequency of modulation and aspect ratio of the cavity on heat transport is studied and plotted graphically. It is observed that the heat transport can also be controlled by suitably adjusting the external and internal parameters of the system.
Prediction of anisotropic transport in Nafion containing catalyst layers
Energy Technology Data Exchange (ETDEWEB)
Dorenbos, G.; Pomogaev, V.A.; Takigawa, M. [Knowledgenet Co., Lofty Chuo Bldg. (9F), 1-17-24, Shinkawa, Chuo-ku, Tokyo 104-0033 (Japan); Toyota Motor Co., Future Project Division, 1200 Mishuku, Susono, Shizuoka 410-1193 (Japan); Morohoshi, K. [Toyota Motor Co., Future Project Division, 1200 Mishuku, Susono, Shizuoka 410-1193 (Japan)
2010-01-15
Using dissipative particle dynamics we model phase separation within Nafion electrolytes of thickness between 5 and 10 nm containing 20 volume percent water, sandwiched between a carbon catalyst support (CCS) layer and air. The diffusion pathway for protons and water is probed by Monte Carlo trajectory calculations. While varying the interactions between CCS and water, diffusion parallel to the CCS is predicted to be highest and perpendicular diffusion to be lowest for a hydrophilic CCS. This is explained by variations in water density profiles along the perpendicular direction, which act as bottlenecks for diffusion. Increasing the hydrophobic character of the CCS lifts up these bottlenecks. (author)
Three-Dimensional Lattice Boltzmann Simulation of Liquid Water Transport in Porous Layer of PEMFC
Directory of Open Access Journals (Sweden)
Bo Han
2015-12-01
Full Text Available A three-dimensional two-phase lattice Boltzmann model (LBM is implemented and validated for qualitative study of the fundamental phenomena of liquid water transport in the porous layer of a proton exchange membrane fuel cell (PEMFC. In the present study, the three-dimensional microstructures of a porous layer are numerically reconstructed by a random generation method. The LBM simulations focus on the effects of the porous layer porosity and boundary liquid saturation on liquid water transport in porous materials. Numerical results confirm that liquid water transport is strongly affected by the microstructures in a porous layer, and the transport process prefers the large pores as its main pathway. The preferential transport phenomenon is more profound with a decreased porous layer porosity and/or boundary liquid saturation. In the transport process, the breakup of a liquid water stream can occur under certain conditions, leading to the formation of liquid droplets inside the porous layer. This phenomenon is related to the connecting bridge or neck resistance dictated by the surface tension, and happens more frequently with a smaller porous layer porosity. Results indicate that an optimized design of porous layer porosity and the combination of various pore sizes may improve both the liquid water removal and gaseous reactant transport in the porous layer of a PEMFC.
Augmentation of heat transfer from a solid cylinder wrapped with a porous layer
DEFF Research Database (Denmark)
Bhattacharyya, S.; Singh, Ashok
2009-01-01
In the present study, the heat transfer from a porous wrapped solid cylinder is considered. The heated cylinder is placed horizontally and is subjected to a uniform cross-flow. The aim is to investigate the heat transfer augmentation through the inclusion of a porous wrapper. The porous layer...... value of porous layer thickness for heat transfer augmentation and its dependence on other properties of the porous foam is obtained. The flow field is analyzed through a single domain approach in which the porous layer is considered as a pseudo-fluid and the composite region as a continuum. A pressure...... correction based iterative algorithm is used for computation. Our results show that a thin porous wrapper of high thermal conductivity can enhance the rate of heat transfer substantially. Periodic vortex shedding is observed from the porous shrouded solid cylinder for high values of Reynolds number...
Gravity-Driven Instability in a Liquid Film Overlying an Inhomogeneous Porous Layer
Institute of Scientific and Technical Information of China (English)
ZHAO Si-Cheng; LIU Qiu-Sheng; NGUYEN-THI Henri; BILLIA Bernard
2011-01-01
@@ A new model consisting of a liquid film overlying a saturated and inhomogeneous porous layer is investigated.We concentrate on effects of inhomogeneity on transition of instability modes.Influences of the averaged porosity and the gradient of porosity distribution on the instability behaviors of a liquid-porous layer system are emphasized.The average permeability of the porous layer is a key factor to determine the penetration of convection in the system.%A new model consisting of a liquid film overlying a saturated and inhomogeneous porous layer is investigated. We concentrate on effects of inhomogeneity on transition of instability modes. Influences of the averaged porosity and the gradient of porosity distribution on the instability behaviors of a liquid-porous layer system are emphasized.The average permeability of the porous layer is a key factor to determine the penetration of convection in the system.
Epitaxial Growth of High-Quality Silicon Films on Double-Layer Porous Silicon
Institute of Scientific and Technical Information of China (English)
黄宜平; 竺士炀; 李爱珍; 王瑾; 黄靖云; 叶志镇
2001-01-01
The epitaxial growth of a high-quality silicon layer on double-layer porous silicon by ultra-high vacuum/chemical vapour deposition has been reported. The two-step anodization process results in a double-layer porous silicon structure with a different porosity. This double-layer porous silicon structure and an extended low-temperature annealing in a vacuum system was found to be helpful in subsequent silicon epitaxial growth. X-ray diffraction,cross-sectional transmission electron microscopy and spreading resistance testing were used in this work to study the properties of epitaxial silicon layers grown on the double-layer porous silicon. The results show that the epitaxial silicon layer is of good crystallinity and the same orientation with the silicon substrate and the porous silicon layer.
Modeling Kinetics of Distortion in Porous Bi-layered Structures
DEFF Research Database (Denmark)
Tadesse Molla, Tesfaye; Frandsen, Henrik Lund; Bjørk, Rasmus;
2013-01-01
Shape distortions during constrained sintering experiment of bi-layer porous and dense cerium gadolinium oxide (CGO) structures have been modeled. Technologies like solid oxide fuel cells require co-firing thin layers with different green densities, which often exhibit differential shrinkage...... because of different sintering rates of the materials resulting in undesired distortions of the component. An analytical model based on the continuum theory of sintering has been developed to describe the kinetics of densification and distortion in the sintering processes. A new approach is used...... to extract the material parameters controlling shape distortion through optimizing the model to experimental data of free shrinkage strains. The significant influence of weight of the sample (gravity) on the kinetics of distortion is taken in to consideration. The modeling predictions indicate good agreement...
Ultralight anisotropic foams from layered aligned carbon nanotube sheets
Faraji, Shaghayegh; L. Stano, Kelly; Yildiz, Ozkan; Li, Ang; Zhu, Yuntian; Bradford, Philip D.
2015-10-01
In this work, we present large scale, ultralight aligned carbon nanotube (CNT) structures which have densities an order of magnitude lower than CNT arrays, have tunable properties and exhibit resiliency after compression. By stacking aligned sheets of carbon nanotubes and then infiltrating with a pyrolytic carbon (PyC), resilient foam-like materials were produced that exhibited complete recovery from 90% compressive strain. With density as low as 3.8 mg cm-3, the foam structure is over 500 times less dense than bulk graphite. Microscopy revealed that PyC coated the junctions among CNTs, and also increased CNT surface roughness. These changes in the morphology explain the transition from inelastic behavior to foam-like recovery of the layered CNT sheet structure. Mechanical and thermal properties of the foams were tuned for different applications through variation of PyC deposition duration while dynamic mechanical analysis showed no change in mechanical properties over a large temperature range. Observation of a large and linear electrical resistance change during compression of the aligned CNT/carbon (ACNT/C) foams makes strain/pressure sensors a relevant application. The foams have high oil absorption capacities, up to 275 times their own weight, which suggests they may be useful in water treatment and oil spill cleanup. Finally, the ACNT/C foam's high porosity, surface area and stability allow for demonstration of the foams as catalyst support structures.In this work, we present large scale, ultralight aligned carbon nanotube (CNT) structures which have densities an order of magnitude lower than CNT arrays, have tunable properties and exhibit resiliency after compression. By stacking aligned sheets of carbon nanotubes and then infiltrating with a pyrolytic carbon (PyC), resilient foam-like materials were produced that exhibited complete recovery from 90% compressive strain. With density as low as 3.8 mg cm-3, the foam structure is over 500 times less dense than
Theoretical Relationships of Fluid and Flow Quantities in Composite Porous Layers
Directory of Open Access Journals (Sweden)
W.S. Almalki
2016-02-01
Full Text Available In this work we consider the use of Brinkman’s equation in describing viscous fluid flow through porous media, and its applicability in describing flow through layered porous media when permeability is low. While available formulations of viscous fluid flow over porous layers impose conditions of velocity and shear stress continuity at the interface between layers, the case of flow through layered media with low permeability requires a formulation that captures the low shear stress across layers. To this end, we consider a formulation of Brinkman’s equation based on Williams’ constitutive equations in order to take into account Brinkman’s effective viscosity and how it influences the flow characteristics across the porous layers, and we derive theoretical relationships for fluid and flow quantities in composite porous layers.
Cuenca, Jacques; Göransson, Peter
2012-08-01
This paper presents a method for simultaneously identifying both the elastic and anelastic properties of the porous frame of anisotropic open-cell foams. The approach is based on an inverse estimation procedure of the complex stiffness matrix of the frame by performing a model fit of a set of transfer functions of a sample of material subjected to compression excitation in vacuo. The material elastic properties are assumed to have orthotropic symmetry and the anelastic properties are described using a fractional-derivative model within the framework of an augmented Hooke's law. The inverse estimation problem is formulated as a numerical optimization procedure and solved using the globally convergent method of moving asymptotes. To show the feasibility of the approach a numerically generated target material is used here as a benchmark. It is shown that the method provides the full frequency-dependent orthotropic complex stiffness matrix within a reasonable degree of accuracy.
The representation of flows to partially penetrating rivers from layered and anisotropic aquifers
Miles, J. C.
1987-11-01
It has previously been shown that it is possible to represent the flow of water from a homogeneous, isotropic aquifer to a river or drain by using a Dupuit-Forcheimer groundwater flow model coupled with equations to calculate the magnitude of the flow to the river. This work has now been extended to include anisotropic and layered aquifers. Results obtained from two-dimensional free surface seepage models are used to assess the accuracy of the results from the Dupuit-Forcheimer models. It is shown that such models can be used to accurately estimate the flow to a river for a wide variety of situations. Miles, 1985b.
Tan, Eng Leong
2005-12-01
This paper presents the recursive algorithm of stiffness matrix method with improved efficiency for computing the total and surface stiffness matrices for a general multilayered anisotropic media. Based on the eigensolutions commonly available for analysis of such media, the recursive algorithm deals with eigen-submatrices directly and bypasses all intermediate layer stiffness submatrices. The improved algorithm obviates the need to compute certain inverse of the original scheme and makes the stiffness matrix recursion more robust. In situation where transfer matrix is numerically stable and easily accessible, an improved recursive algorithm is also given directly in terms of transfer submatrices without involving their explicit inverse.
Gould, C; Rüster, C; Jungwirth, T; Girgis, E; Schott, G M; Giraud, R; Brunner, K; Schmidt, G; Molenkamp, L W
2004-09-10
We introduce a new class of spintronic devices in which a spin-valve-like effect results from strong spin-orbit coupling in a single ferromagnetic layer rather than from injection and detection of a spin-polarized current by two coupled ferromagnets. The effect is observed in a normal-metal-insulator-ferromagnetic-semiconductor tunneling device. This behavior is caused by the interplay of the anisotropic density of states in (Ga,Mn)As with respect to the magnetization direction and the two-step magnetization reversal process in this material. PMID:15447375
Polarisations of quasi-waves in a general anisotropic porous solid saturated with viscous liquid
Indian Academy of Sciences (India)
M D Sharma
2005-08-01
Wave propagation is studied in a general anisotropic poroelastic solid saturated with a viscous fluid flowing through its pores of anisotropic permeability. The extended version of Biot's theory is used to derive a system of modified Christoffel equations for the propagation of plane harmonic waves in such media. The non-trivial solution of this system is ensured by a biquadratic equation whose roots represent the complex velocities of four attenuating quasi-waves in the medium. These complex velocities define phase velocity and attenuation of each quasi-wave propagating along a given phase direction in three-dimensional space. The solution itself defines the polarisations of the quasi-waves along with phase shift. The variations of polarisations of quasi-waves with their phase direction, are computed for a realistic numerical model.
Zhong-yan Liu; Huan-zhen Chen
2014-01-01
By choosing the trial function space to the immersed finite element space and the test function space to be piecewise constant function space, we develop a discontinuous Galerkin immersed finite volume element method to solve numerically a kind of anisotropic diffusion models governed by the elliptic interface problems with discontinuous tensor-conductivity. The existence and uniqueness of the discrete scheme are proved, and an optimal-order energy-norm estimate and ${L}^{2}$ -norm estimate f...
Ortiz, Aurélie U.; Boutin, Anne; Fuchs, Alain H; Coudert, François-Xavier
2012-01-01
We performed ab initio calculations of the elastic constants of five flexible metal-organic frameworks: MIL-53(Al), MIL-53(Ga), MIL-47 and the square and lozenge structures of DMOF-1. Tensorial analysis of the elastic constants reveal a highly anisotropic elastic behavior, some deformation directions exhibiting very low Young's modulus and shear modulus. This anisotropy can reach a 400:1 ratio between the most rigid and weakest directions, in stark contrast with the case of non-flexible MOFs ...
Raman and Photoluminescence Studies of In-plane Anisotropic Layered Materials
Pant, Anupum
This thesis presents systematic studies on angle dependent Raman and Photoluminescence (PL) of a new class of layered materials, Transition Metal Trichalcogenides (TMTCs), which are made up of layers possessing anisotropic structure within the van-der-Waals plane. The crystal structure of individual layer of MX3 compounds consists of aligned nanowire like 1D chains running along the b-axis direction. The work focuses on the growth of two members of this family - ZrS3 and TiS3 - through Chemical Vapor Transport Method (CVT), with consequent angle dependent Raman and PL studies which highlight their in-plane optically anisotropic properties. Results highlight that the optical properties of few-layer flakes are highly anisotropic as evidenced by large PL intensity variation with polarization direction (in ZrS3) and an intense variation in Raman intensity with variation in polarization direction (in both ZrS3 and TiS3). Results suggest that light is efficiently absorbed when E-field of the polarized incident excitation laser is polarized along the chain (b-axis). It is greatly attenuated and absorption is reduced when field is polarized perpendicular to the length of 1D-like chains, as wavelength of the exciting light is much longer than the width of each 1D chain. Observed PL variation with respect to the azimuthal flake angle is similar to what has been previously observed in 1D materials like nanowires. However, in TMTCs, since the 1D chains interact with each other, it gives rise to a unique linear dichroism response that falls between 2D and 1D like behavior. These results not only mark the very first demonstration of high PL polarization anisotropy in 2D systems, but also provide a novel insight into how interaction between adjacent 1D-like chains and the 2D nature of each layer influences the overall optical anisotropy of Quasi-1D materials. The presented results are anticipated to have impact in technologies involving polarized detection, near-field imaging
Anisotropic thermoelectric properties in layered complex nitrides with α-NaFeO2-type structure
Ohkubo, Isao; Mori, Takao
2016-10-01
Electronic structures and thermoelectric transport properties of α-NaFeO2-type d0-electron layered complex nitrides AMN2 (A = Sr or Na; M = Zr, Hf, Nb, Ta) were evaluated using density-functional theory and Boltzmann theory calculations. Despite the layered crystal structure, all materials had three-dimensional electronic structures. Sr(Zr, Hf)N2 exhibited isotropic electronic transport properties because of the contribution of the Sr 4d orbitals to the conduction band minimums (CBMs) in addition to that of the Zr 4d (Hf 5d) orbitals. Na(Nb,Ta)N2 showed weak anisotropic electronic transport properties due to the main contribution of the Nb 4d (Ta 5d) and N 2p orbitals to the CBMs and no contribution of the Na orbitals.
Energy Technology Data Exchange (ETDEWEB)
Berryman, J.G.
2010-06-01
The mechanics of vertically layered porous media has some similarities to and some differences from the more typical layered analysis for purely elastic media. Assuming welded solid contact at the solid-solid interfaces implies the usual continuity conditions, which are continuity of the vertical (layering direction) stress components and the horizontal strain components. These conditions are valid for both elastic and poroelastic media. Differences arise through the conditions for the pore pressure and the increment of fluid content in the context of fluid-saturated porous media. The two distinct conditions most often considered between any pair of contiguous layers are: (1) an undrained fluid condition at the interface, meaning that the increment of fluid content is zero (i.e., {delta}{zeta} = 0), or (2) fluid pressure continuity at the interface, implying that the change in fluid pressure is zero across the interface (i.e., {delta}p{sub f} = 0). Depending on the types of measurements being made on the system and the pertinent boundary conditions for these measurements, either (or neither) of these two conditions might be directly pertinent. But these conditions are sufficient nevertheless to be used as thought experiments to determine the expected values of all the poroelastic coefficients. For quasi-static mechanical changes over long time periods, we expect drained conditions to hold, so the pressure must then be continuous. For high frequency wave propagation, the pore-fluid typically acts as if it were undrained (or very nearly so), with vanishing of the fluid increment at the boundaries being appropriate. Poroelastic analysis of both these end-member cases is discussed, and the general equations for a variety of applications to heterogeneous porous media are developed. In particular, effective stress for the fluid permeability of such poroelastic systems is considered; fluid permeabilities characteristic of granular media or tubular pore shapes are treated
Observation of anisotropic diffusion of light in compacted granular porous materials
Alerstam, Erik
2011-01-01
Employing spatially resolved photon time-of-flight spectroscopy, we reveal anisotropic diffusion of light in compressed granular media. Findings correlate well with recent reports of pore structural anisotropy and its pressure dependence, and significantly reshape our understanding of the optics of compacted granular matter. New routes to material characterization and investigations of compression-induced anisotropy are opened, and an urgent need for better understanding of the relation between compression, microstructure and light scattering is disclosed. Important implications for quantitative spectroscopy of powder compacts in general, and pharmaceutical tablets in particular, are also discussed.
Wacker, Josias B; Parashar, Virendra K; Gijs, Martin A M
2011-04-19
We report the microfluidic chip-based assembly of colloidal silanol-functionalized silica nanoparticles using monodisperse water-in-oil droplets as templates. The nanoparticles are linked via silica bridges, thereby forming superstructures that range from doublets to porous spherical or rod-like micro-objects. Adding magnetite nanoparticles to the colloid generates micro-objects that can be magnetically manipulated. We functionalized such magnetic porous assemblies with horseradish peroxidase and demonstrate the catalytic binding of fluorescent dye-labeled tyramide over the complete effective surface of the superstructure. Such nanoparticle assemblies permit easy manipulation and recovery after a heterogeneous catalytic process while providing a large surface similar to that of the individual nanoparticles. PMID:21417232
Layer-dependent anisotropic electronic structure of freestanding quasi-two-dimensional Mo S 2
Hong, Jinhua
2016-02-29
The anisotropy of the electronic transition is a well-known characteristic of low-dimensional transition-metal dichalcogenides, but their layer-thickness dependence has not been properly investigated experimentally until now. Yet, it not only determines the optical properties of these low-dimensional materials, but also holds the key in revealing the underlying character of the electronic states involved. Here we used both angle-resolved electron energy-loss spectroscopy and spectral analysis of angle-integrated spectra to study the evolution of the anisotropic electronic transition involving the low-energy valence electrons in the freestanding MoS2 layers with different thicknesses. We are able to demonstrate that the well-known direct gap at 1.8 eV is only excited by the in-plane polarized field while the out-of-plane polarized optical gap is 2.4 ± 0.2 eV in monolayer MoS2. This contrasts with the much smaller anisotropic response found for the indirect gap in the few-layer MoS2 systems. In addition, we determined that the joint density of states associated with the indirect gap transition in the multilayer systems and the corresponding indirect transition in the monolayer case has a characteristic three-dimensional-like character. We attribute this to the soft-edge behavior of the confining potential and it is an important factor when considering the dynamical screening of the electric field at the relevant excitation energies. Our result provides a logical explanation for the large sensitivity of the indirect transition to thickness variation compared with that for the direct transition, in terms of quantum confinement effect.
Ortiz, Aurélie U; Boutin, Anne; Fuchs, Alain H; Coudert, François-Xavier
2012-11-01
We performed ab initio calculations of the elastic constants of five flexible metal-organic frameworks (MOFs): MIL-53(Al), MIL-53(Ga), MIL-47, and the square and lozenge structures of DMOF-1. Tensorial analysis of the elastic constants reveals a highly anisotropic elastic behavior, some deformation directions exhibiting very low Young's modulus and shear modulus. This anisotropy can reach a 400:1 ratio between the most rigid and weakest directions, in stark contrast to the case of nonflexible MOFs such as MOF-5 and ZIF-8. In addition, we show that flexible MOFs can display extremely large negative linear compressibility. These results uncover the microscopic roots of stimuli-induced structural transitions in flexible MOFs, by linking the local elastic behavior of the material and its multistability. PMID:23215398
Brinkman, H.W.; Meijerink, J.; Vries, de K.J.; Burggraaf, A.J.
1996-01-01
By means of electrochemical vapour deposition (EVD), it is possible to grow thin (0.5-5 µm), dense zirconia/yttria layers on porous ceramic substrates. Kinetics of the EVD process, morphology and oxygen permeation properties of the grown layers are investigated. Very thin (~ 0.5 µm) layers are grown
Control of interfacial layers for high-performance porous Si lithium-ion battery anode.
Park, Hyungmin; Lee, Sungjun; Yoo, Seungmin; Shin, Myoungsoo; Kim, Jieun; Chun, Myungjin; Choi, Nam-Soon; Park, Soojin
2014-09-24
We demonstrate a facile synthesis of micrometer-sized porous Si particles via copper-assisted chemical etching process. Subsequently, metal and/or metal silicide layers are introduced on the surface of porous Si particles using a simple chemical reduction process. Macroporous Si and metal/metal silicide-coated Si electrodes exhibit a high initial Coulombic efficiency of ∼90%. Reversible capacity of carbon-coated porous Si gradually decays after 80 cycles, while metal/metal silicide-coated porous Si electrodes show significantly improved cycling performance even after 100 cycles with a reversible capacity of >1500 mAh g(-1). We confirm that a stable solid-electrolyte interface layer is formed on metal/metal silicide-coated porous Si electrodes during cycling, leading to a highly stable cycling performance.
Numerical investigation on active isolation of ground shock by soft porous layers
Wang, J. G.; Sun, W.; Anand, S.
2009-04-01
The mitigation and reduction of blast-induced ground shock in near field is an interesting topic worth considering for the protection of buried structures. Soft porous materials are usually used to form an isolation layer around the buried structures. However, the interaction of soft porous layer and surrounding geomedia as well as buried structures is not well understood. In this paper, the effects of soft porous layer barriers on the reduction of buried blast-induced ground shock are numerically studied. Based on the prototype dimensions of a centrifuge test, a numerical model is set up with two steel boxes symmetrically buried at two sides of the charge. One box is directly located in soil mass without protection (unprotected) and the other is located behind a soft porous layer barrier (protected). The soft porous layer barriers studied here include an open trench, an inundated water trench, three in-filled geofoam walls with different densities, and a concrete wall. The numerical responses of the two boxes are evaluated when subjected to the protection of different soft porous layer barriers. These numerical simulations show that both open trench and geofoam barriers can effectively reduce blast-induced stress waves. However, inundated water trench and concrete wall have almost no effect on the reduction of ground shock. Therefore, a geofoam barrier is more practicable in soil mass.
Instability modes of a two-layer Newtonian plane Couette flow past a porous medium
Praveen Kumar, A. Ananth; Goyal, Himanshu; Banerjee, Tamal; Bandyopadhyay, Dipankar
2013-06-01
We explore the salient features of the different instability modes of a pressure-driven two-layer plane Couette flow confined between a moving wall and a Darcy-Brinkman porous layer. A linear stability analysis of the conservation laws leads to an Orr-Sommerfeld system, which is solved numerically with appropriate boundary conditions to identify the time and length scales of the instability modes. The study reveals that the movement of the confining wall together with the slippage at the porous-liquid interface originating from the flow inside the porous layer can stimulate a pair of finite-wave-number shear modes in addition to the long-wave interfacial mode of instability. The shear modes dominate the interfacial mode, especially when the frictional influence at the liquid layers is smaller due to the movement of the confining plate or due to the larger slippage at the porous-liquid interface. The shear modes are found to be present under all combinations of the viscosity μr and thickness hr ratios of the liquid layers. This is in stark contrast to the two-layer flow confined between nonporous plates where the interfacial (shear) mode is observed only when μr>hr2 (μrflows where the presence of a bounding porous layer or moving wall can expedite the intermixing of layers to improve the multiphase mixing, heat and mass transfer, and emulsification characteristics.
Wang, Yong; Yue, Wenzheng; Zhang, Mo
2016-06-01
The anisotropic transport of thermal neutron in heterogeneous porous media is of great research interests in many fields. In this paper, it is the first time that a new model based on micron X-ray computed tomography (CT) has been proposed to simultaneously consider both the separation of matrix and pore and the distribution of mineral components. We apply the Monte Carlo method to simulate thermal neutrons transporting through the model along different directions, and meanwhile detect those unreacted thermal neutrons by an array detector on the other side of the model. Therefore, the anisotropy of pore structure can be imaged by the amount of received thermal neutrons, due to the difference of rock matrix and pore-filling fluids in the macroscopic reaction cross section (MRCS). The new model has been verified by the consistent between the simulated data and the pore distribution from X-ray CT. The results show that the evaluation of porosity can be affected by the anisotropy of media. Based on the research, a new formula is developed to describe the correlation between the resolution of array detectors and the quality of imaging. The formula can be further used to analyze the critical resolution and the suitable number of thermal neutrons emitted in each simulation. Unconventionally, we find that a higher resolution cannot always lead to a better image.
Sintering of bi-layered porous structures: Stress development and shape evolution
DEFF Research Database (Denmark)
Ni, De Wei; Esposito, Vincenzo; Ramousse, Severine;
Ce0.9Gd0.1O1.95 (CGO) and (La, Sr)MnO3 (LSM) are electro-ceramics materials with high potential for several electrochemical applications such as solid Oxide Fuel Cell (SOFC), gas separation membranes, and flue gas purification application. In the latter case, these materials are shaped as thick...... porous layers and sintered by co-firing process. In this work, porous CGO and LSM/CGO single layers were prepared by tape casting, and CGO-LSM/CGO bi-layer structures were obtained by lamination. The shrinkage characteristics of individual layers were measured by optical dilatometry and the uniaxial...
Institute of Scientific and Technical Information of China (English)
Peng Shan; Dieter Bohn; Jing Ren; N.Surken
2007-01-01
This study is an advanced investigation for the cooling of high temperature turbine vanes and blades. The efficient heat exchanging near the surface of a blade may be achieved by forcing a cooling air flow emitting out of a thin layer of the porous metal which is pasted on the structural high strength metal. The contents include the consideration on the computational model of heat transfer through a layer of porous material, the concrete modeling and the analysis of the model, the numerical survey of key parameters for both the two-layer porous materials and the heat transfer fluid flow passing through the model channels. The results revealed that the constructed system is reasonable. Proposed an evaluation formula for the porous material heat transfer efficiency.
Li, Fuping; Li, Jinshan; Kou, Hongchao; Huang, Tingting; Zhou, Lian
2015-09-01
Porous titanium and its alloys are believed to be promising materials for bone implant applications, since they can reduce the "stress shielding" effect by tailoring porosity and improve fixation of implant through bone ingrowth. In the present work, porous Ti6Al4V alloys for biomedical application were fabricated by diffusion bonding of alloy meshes. Compressive mechanical behavior and compatibility in the range of physiological strain rate were studied under quasi-static and dynamic conditions. The results show that porous Ti6Al4V alloys possess anisotropic structure with elongated pores in the out-of-plane direction. For porous Ti6Al4V alloys with 60-70 % porosity, more than 40 % pores are in the range of 200-500 μm which is the optimum pore size suited for bone ingrowth. Quasi-static Young's modulus and yield stress of porous Ti6Al4V alloys with 30-70 % relative density are in the range of 6-40 GPa and 100-500 MPa, respectively. Quasi-static compressive properties can be quantitatively tailored by porosity to match those of cortical bone. Strain rate sensitivity of porous Ti6Al4V alloys is related to porosity. Porous Ti6Al4V alloys with porosity higher than 50 % show enhanced strain rate sensitivity, which is originated from that of base materials and micro-inertia effect. Porous Ti6Al4V alloys with 60-70 % porosity show superior compressive mechanical compatibility in the range of physiological strain rate for cortical bone implant applications.
Gao, Kai
2016-01-01
The conventional Perfectly Matched Layer (PML) is unstable for certain kinds of anisotropic media. This instability is intrinsic and independent of PML formulation or implementation. The Multi-axial PML (MPML) removes such instability using a nonzero damping coefficient in the direction parallel with the interface between a PML and the investigated domain. The damping ratio of MPML is the ratio between the damping coefficients along the directions parallel with and perpendicular to the interface between a PML and the investigated domain. No quantitative approach is available for obtaining these damping ratios for general anisotropic media. We develop a quantitative approach to determining optimal damping ratios to not only stabilize PMLs, but also minimize the artificial reflections from MPMLs. Numerical tests based on finite-difference method show that our new method can effectively provide a set of optimal MPML damping ratios for elastic-wave propagation in 2D and 3D general anisotropic media.
Salama, Amgad
2014-09-01
In this work we apply the experimenting pressure field approach to the numerical solution of the single phase flow problem in anisotropic porous media using the multipoint flux approximation. We apply this method to the problem of flow in saturated anisotropic porous media. In anisotropic media the component flux representation requires, generally multiple pressure values in neighboring cells (e.g., six pressure values of the neighboring cells is required in two-dimensional rectangular meshes). This apparently results in the need for a nine points stencil for the discretized pressure equation (27 points stencil in three-dimensional rectangular mesh). The coefficients associated with the discretized pressure equation are complex and require longer expressions which make their implementation prone to errors. In the experimenting pressure field technique, the matrix of coefficients is generated automatically within the solver. A set of predefined pressure fields is operated on the domain through which the velocity field is obtained. Apparently such velocity fields do not satisfy the mass conservation equations entailed by the source/sink term and boundary conditions from which the residual is calculated. In this method the experimenting pressure fields are designed such that the residual reduces to the coefficients of the pressure equation matrix. © 2014 Elsevier B.V. All rights reserved.
Fathauer, R. W.; George, T.; Ksendzov, A.; Lin, T. L.; Pike, W. T.; Vasquez, R. P.; Wu, Z.-C.
1992-01-01
Simple immersion of Si in stain etches of HF:HNO3:H2O or NaNO2 in aqueous HF was used to produce films exhibiting luminescence in the visible similar to that of anodically-etched porous Si. All of the luminescent samples consist of amorphous porous Si in at least the near surface region. No evidence was found for small crystalline regions within these amorphous layers.
Research of Porization and Adsorptions in High-Porous Adsorptive Layers of Vermiculite
Directory of Open Access Journals (Sweden)
K. Syrmanova
2016-06-01
Full Text Available Adsorption capacity of the adsorbent is dependent on the concentration of the substance in the liquid or vapor phase, its partial pressure, temperature, and the initial state of the adsorbent. At the swelling a cellular porous structure is formed, total porosity that connects with the entered number and the content of the gaseous component masses. The rheological characteristics of porous masses have the decisive effect on the porous structure. Common state for all versions of swelling is a plastic-viscous porous mass condition during their porization. The interlayer structure and inter-packet intervals may be considered as vermiculite plate micropores with dimensions of 0.3 – 1.2 nm. Vermiculite cation exchange capacity is in the range of 100-150 mEq / 100 g, i.e. from clay minerals it is one of the most interchangeable. The research results of the internal structure of adsorption layers by the adsorption isotherms means indicative of the internal surface of the porous layer is characterized by an extremely complex and developed form and can be described by means of fractal geometry. A model of the geometric structure of mica materials formed in the process of blistering during heat treatment is developed. The presented model has sufficiently general form and can be used both in the organization of systematic experimental studies of porization and adsorption in the adsorption layers of highly porous, and for the porization vermiculite optimization.
Kim, Byunghyun; Sanders, Brett F.; Famiglietti, James S.; Guinot, Vincent
2015-04-01
Porous shallow-water models (porosity models) simulate urban flood flows orders of magnitude faster than classical shallow-water models due to a relatively coarse grid and large time step, enabling flood hazard mapping over far greater spatial extents than is possible with classical shallow-water models. Here the errors of both isotropic and anisotropic porosity models are examined in the presence of anisotropic porosity, i.e., unevenly spaced obstacles in the cross-flow and along-flow directions, which is common in practical applications. We show that porosity models are affected by three types of errors: (a) structural model error associated with limitations of the shallow-water equations, (b) scale errors associated with use of a relatively coarse grid, and (c) porosity model errors associated with the formulation of the porosity equations to account for sub-grid scale obstructions. Results from a unique laboratory test case with strong anisotropy indicate that porosity model errors are smaller than structural model errors, and that porosity model errors in both depth and velocity are substantially smaller for anisotropic versus isotropic porosity models. Test case results also show that the anisotropic porosity model is equally accurate as classical shallow-water models when compared directly to gage measurements, while the isotropic model is less accurate. Further, results show the anisotropic porosity model resolves flow variability at smaller spatial scales than the isotropic model because the latter is restricted by the assumption of a Representative Elemental Volume (REV) which is considerably larger than the size of obstructions. These results point to anisotropic porosity models as being well-suited to whole-city urban flood prediction, but also reveal that point-scale flow attributes relevant to flood risk such as localized wakes and wave reflections from flow obstructions may not be resolved.
Models for seismic wave propagation in periodically layered porous media
Kudarova, A.; Van Dalen, K.N.; Drijkoningen, G.G.
2014-01-01
Several models are discussed for seismic wave propagation in periodically layered poroelastic media where layers represent mesoscopic-scale heterogeneities that are larger than the pore and grain sizes but smaller than the wavelength. The layers behave according to Biot’s theory. Wave propagation no
Vortex pumps in the crossing lattices regime of highly anisotropic layered superconductors
International Nuclear Information System (INIS)
It is now well established that vortex dynamics in samples with a spatially asymmetric pinning potential can lead to rectifying vortex 'diode' behaviour. Spatial asymmetry is not a fundamental requirement for the control of vortex motion, however, and we demonstrate that vortex 'lensing' is possible in highly anisotropic layered superconductors simply under the action of non time-reversible trains of in-plane magnetic field pulses. Our devices depend crucially on the existence of 'crossing' pancake vortex (PV) and Josephson vortex (JV) lattices in Bi2Sr2CaCu2O8+δ (BSCCO) single crystals under tilted magnetic fields. An attractive interaction between these two sub-lattices makes it possible to indirectly manipulate the PV distribution by modifying the JV lattice, and a number of functional devices based on this principle have been proposed. In our experiments a BSCCO single crystal is placed on a Hall probe array, and cooled below T c in a small out-of- plane magnetic field. Trains of sawtooth in-plane field pulses are then applied to the system and different elements of the Hall array used to demonstrate PV lensing or antilensing behaviour, depending on the pulse shape. The mechanism leading to lensing will be discussed and results compared with molecular dynamics simulations
International Nuclear Information System (INIS)
Multi-component induction logging provides great assistance in the exploration of thinly laminated reservoirs. The 1D parametric inversion following an adaptive borehole correction is the key step in the data processing of multi-component induction logging responses. To make the inversion process reasonably fast, an efficient forward modelling method is necessary. In this paper, a modelling method has been developed to simulate the multi-component induction tools in deviated wells drilled in layered anisotropic formations. With the introduction of generalized reflection coefficients, the analytic expressions of magnetic field in the form of a Sommerfeld integral were derived. The fast numerical computation of the integral has been completed by using the fast Fourier–Hankel transform and fast Hankel transform methods. The latter is so time efficient that it is competent enough for real-time multi-parameter inversion. In this paper, some simulated results have been presented and they are in excellent agreement with the finite difference method code's solution. (paper)
Sainath, Kamalesh; Teixeira, Fernando L
2014-05-01
We discuss the application of complex-plane Gauss-Laguerre quadrature (CGLQ) to efficiently evaluate two-dimensional Fourier integrals arising as the solution to electromagnetic fields radiated by elementary dipole antennas embedded within planar-layered media exhibiting arbitrary material parameters. More specifically, we apply CGLQ to the long-standing problem of rapidly and efficiently evaluating the semi-infinite length "tails" of the Fourier integral path while simultaneously and robustly guaranteeing absolute, exponential convergence of the field solution despite diversity in the doubly anisotropic layer parameters, source type (i.e., electric or equivalent magnetic dipole), source orientation, observed field type (magnetic or electric), (nonzero) frequency, and (nonzero) source-observer separation geometry. The proposed algorithm exhibits robustness despite unique challenges arising for the fast evaluation of such two-dimensional integrals. Herein we develop the mathematical treatment to rigorously evaluate the tail integrals using CGLQ, as well as discuss and address the specific issues posed to the CGLQ method when anisotropic, layered media are present. To empirically demonstrate the CGLQ algorithm's computational efficiency, versatility, and accuracy, we perform a convergence analysis along with two case studies related to modeling of electromagnetic resistivity tools employed in geophysical prospection of layered, anisotropic Earth media and validating the ability of isoimpedance substrates to enhance the radiation performance of planar antennas placed in close proximity to metallic ground planes.
Institute of Scientific and Technical Information of China (English)
WANG Hui-fang; WANG Ming-yu
2012-01-01
Layered structures with upper porous and lower fractured media are widely distributed in the world.An experimental investigation on rainfall infiltration and solute transport in such layered structures can provide the necessary foundation for effectively preventing and forecasting water bursting in mines,controlling contamination of mine water,and accomplishing ecological restoration of mining areas.A typical physical model of the layered structures with porous and fractured media was created in this study.Then rainfall infiltration experiments were conducted after salt solution was sprayed on the surface of the layered structure.The volumetric water content and concentration of chlorine ions at different specified positions along the profile of the experiment system were measured in real-time.The experimental results showed that the lower fractured media,with a considerably higher permeability than that of the upper porous media,had significant effects on preventing water infiltration.Moreover,although the porous media were homogeneous statistically in the whole domain,spatial variations in the features of effluent concentrations with regards to time,or so called breakthrough curves,at various sampling points located at the horizontal plane in the porous media near the porous-fractured interface were observed,indicating the diversity of solute transport at small scales.Furthermore,the breakthrough curves of the outflow at the bottom,located beneath the underlying fractured rock,were able to capture and integrate features of the breakthrough curves of both the upper porous and fractured media,which exhibited multiple peaks,while the peak values were reduced one by one with time.
Directory of Open Access Journals (Sweden)
Hardiman M. Y
2008-01-01
Full Text Available is paper presents the comparison of engineering properties between single and double layer porous asphalt (SLPA and DLPA made of packing gradation. Three nominal maximum aggregate sizes (NMAS were tested each made up of 10, 14, and 20 mm for SLPA. While for the DLPA with 30, 20, and 15 mm top layer are made of 10 and 14 mm NMAS, with a base layer of 20 mm NMAS. Total thickness of all mixes is 70 mm. Binders used are 60/70 penetration base bitumen and polymer binder styrene-butadiene-styrene (SBS. The result shows that the properties of SLPA mix namely permeability and resistance to abrasion loss decreases when the NMAS in SLPA decreases. The abrasion loss of DLPA mixes increases when the porous asphalt top layer thickness decreases, while drainage time value decreases. However, SLPA with 20 mm NMAS exhibits higher abrasion loss compared to all DLPA mixes.
Water Transport in the Micro Porous Layer and Gas Diffusion Layer of a Polymer Electrolyte Fuel Cell
Qin, C.; Hassanizadeh, S. M.
2015-12-01
In this work, a recently developed dynamic pore-network model is presented [1]. The model explicitly solves for both water pressure and capillary pressure. A semi-implicit scheme is used in updating water saturation in each pore body, which considerably increases the numerical stability at low capillary number values. Furthermore, a multiple-time-step algorithm is introduced to reduce the computational effort. A number of case studies of water transport in the micro porous layer (MPL) and gas diffusion layer (GDL) are conducted. We illustrate the role of MPL in reducing water flooding in the GDL. Also, the dynamic water transport through the MPL-GDL interface is explored in detail. This information is essential to the reduced continua model (RCM), which was developed for multiphase flow through thin porous layers [2, 3]. C.Z. Qin, Water transport in the gas diffusion layer of a polymer electrolyte fuel cell: dynamic pore-network modeling, J Electrochimical. Soci., 162, F1036-F1046, 2015. C.Z. Qin and S.M. Hassanizadeh, Multiphase flow through multilayers of thin porous media: general balance equations and constitutive relationships for a solid-gas-liquid three-phase system, Int. J. Heat Mass Transfer, 70, 693-708, 2014. C.Z. Qin and S.M. Hassanizadeh, A new approach to modeling water flooding in a polymer electrolyte fuel cell, Int. J. Hydrogen Energy, 40, 3348-3358, 2015.
Improved Modeling Approaches for Constrained Sintering of Bi-Layered Porous Structures
DEFF Research Database (Denmark)
Tadesse Molla, Tesfaye; Frandsen, Henrik Lund; Esposito, Vincenzo;
2012-01-01
Shape instabilities during constrained sintering experiment of bi-layer porous and dense cerium gadolinium oxide (CGO) structures have been analyzed. An analytical and a numerical model based on the continuum theory of sintering has been implemented to describe the evolution of bow and densificat...
Porous layer open tubular columns with immobilized trypsin for protein digestion
Knob, R.
2013-01-01
We have developed a monolithic porous layer open tubular (PLOT) column with immobilized trypsin for protein digestion. The PLOT column was prepared in a 10 (mikro)m ID fused silica capillary. Trypsin was immobilized on the monolithic surface and the developed enzyme reactor was used for protein digestion followed by on-line ESI/MS analysis.
Hubarevich, Aliaksandr; Marus, Mikita; Fan, Weijun; Smirnov, Aliaksandr; Sun, Xiao Wei; Wang, Hong
2015-07-13
The theoretical comparison of optical and electronic properties of aluminum and silver nano-porous ultra-thin layers in terms of the arrangement and size of the pores was presented. The uniform nano-porous layers exhibit a slightly higher average transmittance (up to 10%) in the wavelength range of the plasmonic response in comparison to the randomly arranged ones. Compared to uniform nano-porous layers, a much larger sheet resistance (up to 12 times) for random nano-porous layers is observed. The uniform and random Ag nano-porous layers possessing the strong plasmonic response over whole visible range can reach an average transmittance of 90 and 80% at the sheet resistance of 10 and 20 Ohm/sq, respectively, which is comparable to widely used ITO electrodes.
Synthesis of a porous oxide layer on a multifunctional biomedical titanium by micro-arc oxidation
International Nuclear Information System (INIS)
To improve apatite forming ability of Ti-24Nb-4Zr-7.9Sn alloy, a porous oxidation layer has been synthesized by micro-arc oxidation in a calcium acetate electrolyte and subsequent heat treatment. These oxide layers were characterized by scanning electron microscopy, thin film X-ray diffraction and X-ray photoelectron spectroscopy. After the above treatments, the surface oxide consists of two layers: a thin, compact and uniform inner layer and a porous outer layer. Ca ions are incorporated into the oxide layer in the form of CaO while Ti, Nb and Sn participate in the oxidation to form TiO2, Nb2O5 and SnO2, respectively. After heat treatment at 600 deg. C, surfaces with such porous oxides have better apatite forming ability than the ground, smooth surface of the alloy, as evidenced by apatite formation within 7 days of soaking in a simulated body fluid. Preliminary in vitro cell test on rabbit's osteoblast show that these surfaces gain considerable improvement in cell proliferation.
Simon, Lin; Gidley, D W; Wetzel, J T; Monnig, K A; Ryan, E T; Simon, Jang; Douglas, Yu; Liang, M S; En, W G; Jones, E C; Sturm, J C; Chan, M J; Tiwari, S C; Hirose, M
2002-01-01
Positron Annihilation Lifetime Spectroscopy (PALS) is a useful tool to pre-screen metal barrier integrity for Si-based porous low-k dielectrics. Pore size of low-k, thickness of metal barrier Ta, positronium (Ps) leakage from PALS, trench sidewall morphology, electrical test from one level metal (1LM) pattern wafer and Cu diffusion analysis were all correlated. Macro-porous low-k (pore size >=200 AA) and large scale meso-porous low-k (>50~200 AA) encounter both Ps leakage and Cu diffusion into low-k dielectric in the 0.25 mu mL/0.3 mu mS structures when using SEMATECH in-house PVD Ta 250 AA as barrier layer. For small scale meso-porous (>20~50 AA) and micro- porous (<=20 AA) low-k, no Ps leakage and no Cu diffusion into low-k were observed even with PVD Ta 50 AA, which is proved also owing to sidewall densification to seal all sidewall pores due to plasma etch and ash. For future technology, smaller pore size of porous Si-based low-k (=<50 AA) will be preferential for dense low-k like trench sidewall to...
Electrochemical and optical characterizations of anodic porous n-InP(1 0 0) layers
Energy Technology Data Exchange (ETDEWEB)
Santinacci, Lionel, E-mail: santinacci@cinam.univ-mrs.f [Institut Lavoisier de Versailles (UMR CNRS 8180), University of Versailles Saint-Quentin, 45 avenue des Etats-Unis, F-78000 Versailles (France); Goncalves, Anne-Marie; Simon, Nathalie; Etcheberry, Arnaud [Institut Lavoisier de Versailles (UMR CNRS 8180), University of Versailles Saint-Quentin, 45 avenue des Etats-Unis, F-78000 Versailles (France)
2010-12-30
In this paper, electrochemical and optical characterizations of anodic porous n-InP(1 0 0) are reported. The direct relation between the observed pore morphology and the physical properties is demonstrated using electrochemical methods such as cyclic voltammetry and impedance spectroscopy as well as optical techniques like photocurrent spectroscopy and photoluminescence measurements. An enhancement of the interfacial capacitance, proportional to the anodic charge, is revealed by voltammetry and Mott-Schottky analysis. It is related to the drastic increase of the area of the porous electrode. However, when the porous samples are sufficiently reverse-biased, the capacitance enlargement disappears because the nanosized pore walls are fully depleted and the electroactive area recovers its initial value. Photocurrent spectroscopy and photoluminescence measurements show the porous film behaves like an absorbent layer. This effect is also ascribed to the specific geometry of the space charge layer within the pore walls. A model based on the absorption coefficient and the effective optical path length is thus used to describe the phenomenon. However the model is not sufficient to depict the phenomenon and the charge recombination in the additional surface states created during the pore formation and the long transit time of electrons in the porous matrix are also significant. Additional effects such as the initial enhancement of the photocurrent response and the redshift of the absorption edge of the photocurrent spectra are observed. Inversely, no shift of the photoluminescence peak is detected. However an exponential quenching of the photoluminescence is also attributed to an absorbent behavior of the porous layer.
Noise Control Using Coconut Coir Fiber Sound Absorber with Porous Layer Backing and Perforated Panel
Directory of Open Access Journals (Sweden)
Rozli Zulkifli
2010-01-01
Full Text Available Problem statement: Noise control was one of the major requirements to improve the living environment. One of the methods to do that is provided by sound absorber. Commonly, multi-layer sound absorbers are applied to absorb broadband noise that was composed of perforated plates, air space and porous material. However, multi-layers sound absorbers effectiveness depends on their construction. This study was conducted to investigate the potential of using coconut coir fiber as sound absorber. The effects of porous layer backing and perforated plate on sound absorption coefficient of sound absorber using coconut coir fiber were studied. Approach: Car boot liners made from woven cotton cloth were used as type of porous layer in the study. This material has been used widely in automotive industry. Perforated plate used was machined with perforation ratio of 0.20, thickness of 1 mm and holed diameter of 2 mm. The samples were tested at the acoustic lab of the Faculty of Engineering and Built Environment, University Kebangsaan Malaysia, according to ASTM E 1050-98 international standards for noise absorption coefficient. Results: The experiment data indicates that porous layer backing can improve noise absorption coefficient at low and high frequencies with significant increasing. 20 mm thick layer coconut coir fiber with porous layer backing exhibit peak value at frequencies between 2750-2825 Hz with maximum value of 0.97. The experimental results also found that the coconut coir fiber with perforated plate gives higher value for lower frequencies range from 600-2400 Hz. The optimum value for coconut coir fiber with perforated panel is around 0.94-0.95 for the frequency range 2600-2700 Hz. Conclusion: Noise absorption coefficient of coconut coir fiber was increased at all frequency when they were backing with Woven Cotton Cloth (WCC. At low frequency, the NAC have significant increasing. This is because WCC have higher flow resistivity than coconut coir
Energy Technology Data Exchange (ETDEWEB)
Atyaoui, Malek, E-mail: atyaoui.malek@yahoo.fr [Laboratoire de Photovoltaieque, Centre de recherches et des technologies de l' energie, technopole de Borj-Cedria, PB:95, Hammam Lif 2050 (Tunisia); Dimassi, Wissem; Khalifa, Marouan; Chtourou, Radhouane; Ezzaouia, Hatem [Laboratoire de Photovoltaieque, Centre de recherches et des technologies de l' energie, technopole de Borj-Cedria, PB:95, Hammam Lif 2050 (Tunisia)
2012-10-15
The influence of surface treatment of porous silicon (PS) in lanthanum (La) containing solution during different times on its photoluminescence and electrical properties has been investigated. For this purpose, chemical composition, structural, vibrational, photoluminescence and electrical characteristics of the porous silicon layer with and without lanthanum were examined using X-ray diffractometry (XRD), energy dispersive X-ray (EDX) spectroscopy, Fourier transmission infrared (FTIR) spectroscopy, photoluminescence (PL) spectroscopy and current-voltage (I-V) measurements. The results indicate that porous silicon layers treated with lanthanum exhibit an enhancement of photoluminescence intensity and show an improvement current intensity compared to untreated porous silicon layer. - Highlights: Black-Right-Pointing-Pointer Degradation of the electrical and the PL properties of PS remains a key issue for industrial production. Black-Right-Pointing-Pointer In order to solve this problem, the passivation of the PS surface by treating it with La is investigated. Black-Right-Pointing-Pointer To understand the effects of La on PL and electrical properties, EDX, FTIR, XRD, I-V and UV-vis analysis were performed.
THERMAL CONSOLIDATION OF LAYERED POROUS HALF-SPACE TO VARIABLE THERMAL LOADING
Institute of Scientific and Technical Information of China (English)
BAI Bing
2006-01-01
An analytical method was derived for the thermal consolidation of layered,saturated porous half-space to variable thermal loading with time. In the coupled governing equations of linear thermoelastic media, the influences of thermo-osmosis effect and thermal filtration effect were introduced. Solutions in Laplace transform space were first obtained and then numerically inverted. The responses of a double-layered porous space subjected to exponential decaying thermal loading were studied. The influences of the differences between the properties of the two layers (e.g., the coefficient of thermal consolidation, elastic modulus) on thermal consolidation were discussed. The studies show that the coupling effects of displacement and stress fields on temperature field can be completely neglected, however, thc thermo-osmosis effect has an obvious influence on thermal responses.
Heng, Liping; Guo, Xieyou; Guo, Tianqi; Wang, Bin; Jiang, Lei
2016-07-21
Ordered porous polymeric films attract more and more attention because they have many advantages and broad application prospects in many fields. But because of their large flexibility and poor mechanical properties, some of the scope for application is greatly limited. Inspired by the ordered pore structure of the honeycomb and the layered structure of natural nacre, we prepared an ordered porous polymer film with a layered structure in the pore wall by the solvent-evaporation-restriction assisted hard template method. Compared with other samples, this kind of film with the layered structure showed both excellent mechanical properties and good stability. This kind of film with high mechanical strength, is considered to have wide applications in the areas of separation, biomedicine, precision instruments, aerospace, environmental protection and so on. PMID:27355160
Role of the buffer porous layer and dysprosium doping in GaInP-porGaAs-GaAs heterostructures
Energy Technology Data Exchange (ETDEWEB)
Domashevskaya, E.P.; Seredin, P.V.; Gordienko, N.N.; Glotov, A.V. [Physics Department, Voronezh State University (Russian Federation); Arsentyev, I.N.; Shishkov, M.V. [Ioffe Physical and Technical Institute, Russian Academy of Sciences, St. Petersburg (Russian Federation)
2009-07-15
In the samples with porous buffer layer the residual internal stresses caused by the difference in lattice parameters between the surface layer of ternary GaInP alloy and GaAs substrate are redistributed into the porous layer, which in this case plays a role of a ''sponge'' and completely removes the internal stresses. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Electrochemical Ionic Mass Transfer Correlation in Fluid-Saturated Porous Layer
Energy Technology Data Exchange (ETDEWEB)
Cho, Eun Su [Hoseo University, Asan (Korea, Republic of)
2015-12-15
A new ionic mass transfer correlation is derived for the fluid-saturated, horizontal porous layer. Darcy- Forchheimer model is used to explain characteristics of fluid motion. Based on the microscales of turbulence a backbone mass transfer relation is derived as a function of the Darcy-Rayleigh number, Ra{sub D} and the porous medium Schmidt number, Sc{sub p}. For the Darcy's limit of Sc{sub p}>>Ra{sub D}, the Sherwood number, Sh is a function of Ra{sub D} only. However, for the region of high Ra{sub D}, Sh can be related with Ra{sub D}Sc{sub p}. Based on the present backbone equation and the electrochemical mass transfer experiments which are electro plating or electroless plating, the new ionic mass transfer correlation is suggested in the porous media.
Cooperation of micro- and meso-porous carbon electrode materials in electric double-layer capacitors
Energy Technology Data Exchange (ETDEWEB)
Zheng, Cheng [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, Jilin Province (China); Graduate University of Chinese Academy of Sciences, Beijing 100039 (China); Qi, Li; Wang, Hongyu [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, Jilin Province (China); Yoshio, Masaki [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan)
2010-07-01
The capacitive characteristics of micro- and meso-porous carbon materials have been compared in cyclic voltammetric studies and galvanostatic charge-discharge tests. Meso-porous carbon can keep certain high capacitance values at high scan rates, whereas micro-porous carbon possesses very high capacitance values at low scan rates but fades quickly as the scan rate rises up. For better performance of electric double-layer capacitors (EDLCs), the cooperative application of both kinds of carbon materials has been proposed in the following two ways: mixing both kinds of carbons in the same electrode or using the asymmetric configuration of carbon electrodes in the same EDLC. The cooperative effect on the electrochemical performance has also been addressed. (author)
Structure, composition and morphology of bioactive titanate layer on porous titanium surfaces
Li, Jinshan; Wang, Xiaohua; Hu, Rui; Kou, Hongchao
2014-07-01
A bioactive coating was produced on pore surfaces of porous titanium samples by an amendatory alkali-heat treatment method. Porous titanium was prepared by powder metallurgy and its porosity and average size were 45% and 135 μm, respectively. Coating morphology, coating structure and phase constituents were examined by SEM, XPS and XRD. It was found that a micro-network structure with sizes of bioactive sodium titanate and rutile phases of TiO2 covered the interior and exterior of porous titanium cells, and redundant Ca ion was detected in the titanate layer. The concentration distribution of Ti, O, Ca and Na in the coating showed a compositional gradient from the intermediate layer toward the outer surface. These compositional gradients indicate that the coating bonded to Ti substrate without a distinct interface. After immersion into the SBF solution for 3 days, a bone-like carbonate-hydroxylapatite showing a good biocompatibility was detected on the coating surface. And the redundant Ca advanced the bioactivity of the coating. Thus, the present modification is expected to allow the use of the bioactive porous titanium as artificial bones even under load-bearing conditions.
Dariani, R. S.; Nazari, M.
2016-09-01
This paper describes characterization of mechanical properties of porous silicon (PS) layers with different porosities using high resolution XRD. The XRD measurement determined various mechanical properties of PS such as; Young modulus, Poisson's ratio, and lattice parameter expansion. Our results indicated that mechanical properties reduce with increasing porosity. Also, the mechanical properties of two different porous layers, either supported by or detached from the substrate were examined. Comparison of the two porous layers showed that the constraint in the interatomic spacing is the origin of the lattice constant expansion in the planes perpendicular to the surface. This phenomenon can be useful for gas sensor applications.
Two-Layer Microstructures Fabricated by One-Step Anisotropic Wet Etching of Si in KOH Solution
Directory of Open Access Journals (Sweden)
Han Lu
2016-01-01
Full Text Available Anisotropic etching of silicon in potassium hydroxide (KOH is an important technology in micromachining. The residue deposition from KOH etching of Si is typically regarded as a disadvantage of this technology. In this report, we make use of this residue as a second masking layer to fabricate two-layer complex structures. Square patterns with size in the range of 15–150 μm and gap distance of 5 μm have been designed and tested. The residue masking layer appears when the substrate is over-etched in hydrofluoric acid (HF solution over a threshold. The two-layer structures of micropyramids surrounded by wall-like structures are obtained according to the two different masking layers of SiO2 and residue. The residue masking layer is stable and can survive over KOH etching for long time to achieve deep Si etching. The process parameters of etchant concentration, temperature, etching time and pattern size have been investigated. With well-controlled two-layer structures, useful structures could be designed for applications in plasmonic and microfluidic devices in the future.
Convection in layered porous media: A comparison of boundary heating methods
International Nuclear Information System (INIS)
Convection in a horizontal, doubly layered porous medium has been investigated numerically. A two-dimensional, time dependent model has been developed to compute heat transfer in a saturated porous medium that is locally heated from either above or below. The primary objective is to ascertain how these modes of heating can be differentiated via an examination of the heat transfer results. Both natural and mixed convection are considered. For mixed convection in which a uniform horizontal flow is assumed to enter the domain, the qualitative relation between the Rayleigh and Peclet numbers is obtained over a large range for each. The effect of the length of the heating zone on the flow structure is also examined. The permeability ratio and the ratio of the thermal conductivity of the two layers is also allowed to vary, thus giving the computing Nusselt numbers a broad range of applicability in geophysical and engineered systems
Bazylak, A; Berejnov, V.; Markicevic, B.; Sinton, D.; Djilali, N.
2008-01-01
Pore network modelling has traditionally been used to study displacement processes in idealized porous media related to geological flows, with applications ranging from groundwater hydrology to enhanced oil recovery. Very recently, pore network modelling has been applied to model the gas diffusion layer (GDL) of a polymer electrolyte membrane (PEM) fuel cell. Discrete pore network models have the potential to elucidate transport phenomena in the GDL with high computational efficiency, in cont...
Natural convection boundary layer with suction and mass transfer in a porous medium
International Nuclear Information System (INIS)
The free convection boundary layer flow with simultaneous heat and mass transfer in a porous medium is studied when the boundary wall moves in its own plane with suction. The study also incorporates chemical reaction for the very simple model of a binary reaction with Arrhenius activation energy. For large suction asymptotic approximate solutions are obtained for the flow variables for various values of the activation energy. (author). 10 refs, 2 figs
Directory of Open Access Journals (Sweden)
Jyoti Prakash
2014-01-01
Full Text Available In the present paper, first of all, it is proved that the ‘principle of the exchange of stabilities’ is not, in general valid, for the case of free boundaries and then a sufficient condition is derived for the validity of this principle in ferromagnetic convection, for the case of free boundaries, in a horizontal ferrofluid saturated porous layer in the presence of a uniform vertical magnetic field and uniform rotation about the vertical axis.
Institute of Scientific and Technical Information of China (English)
M H SHOJAEIFARD; R TALEBITOOTI; B RANJBAR; R AHMADI
2014-01-01
The acoustic behavior of double-walled laminated composite panels consisting of two porous and air gap middle layers is studied within the classical laminated plate theory (CLPT). Thus, viscous and inertia coupling in a dynamic equation, as well as stress transfer, thermal and elastic coupling of porous material are based on the Biot theory. In addition, the wave equations are extracted according to the vibration equation of composite layers. The transmission loss (TL) of the structure is then calculated by solving these equations simultaneously. Statistical energy analysis (SEA) is developed to divide the structure into specific subsystems, and power transmission is extracted with balancing power flow equations of the subsystems. Comparison between the present work and the results reported elsewhere shows excellent agreement. The results also indicate that, although favorable enhancement is seen in noise control particularly at high frequencies, the corresponding parameters associated with fluid phase and solid phase of the porous layer are important on TL according to the boundary condition interfaces. Finally, the influence of composite material and stacking sequence on power transmission is discussed.
International Nuclear Information System (INIS)
TiO2 thin films were grown on highly-doped p-Si (100) macro- and mesoporous structures by atomic layer deposition (ALD) using TiCl4 and deionized water as precursors at 300 °C. The crystalline structure, chemical composition, and morphology of the deposited films and initial silicon nanostructures were investigated by scanning electron microscopy, transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, micro-Raman spectroscopy and X-ray diffraction (XRD). The mean size of TiO2 crystallites was determined by TEM, XRD and Raman spectroscopy. It was shown that the mean crystallite size and the crystallinity of the TiO2 are influenced dramatically by the morphology of the porous silicon, with the mesoporous silicon resulting in a much finer grain size and amorphous structure than the macroporous silicon having a partially crystal anatase phase. A simple model of the ALD layer growth inside the pores was presented. - Highlights: • The morphology and chemical composition of TiO2 and porous Si were established. • The approximate size of TiO2 nanocrystals was estimated. • The model of the atomic layer deposition coating in the porous Si was presented
Sakamoto, Kenji; Yasuda, Takeshi; Miki, Kazushi; Chikamatsu, Masayuki; Azumi, Reiko
2011-01-01
We have fabricated organic field-effect transistors (OFETs) with a highly oriented active layer of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene] (F8T2), which was formed with the help of a photoaligned polyimide film. Photoalignment is an attractive technique for integrating OFETs with aligned active layers on the same substrate, because of its potential capability of two-dimensional alignment patterning. The F8T2 layer formed on the photoaligned polyimide film showed an absorption dichroic ratio greater than 15 after annealing at 285 °C. Top-gate/bottom-contact-type OFETs with a parylene gate insulating layer exhibited an enhanced hole mobility (0.016 cm2 V-1 s-1) along the alignment direction of the F8T2 backbone structure and a suppressed one (0.002 cm2 V-1 s-1) along the perpendicular direction. This result shows that the photoaligned polyimide film is an attractive alignment layer for fabricating and integrating OFETs with aligned active layers. Current-direction-dependent bias stress effect was observed for those OFETs; when the current flowed parallel to the alignment direction of the F8T2 backbone structures, a larger negative threshold voltage shift was observed. This anisotropic bias stress effect was discussed on the basis of a microstructure model of aligned F8T2 films.
High-performance antireflective coatings with a porous nanoparticle layer for visible wavelengths.
Murata, Tsuyoshi; Ishizawa, Hitoshi; Tanaka, Akira
2011-03-20
Ghosts and flares are well-known problems that are caused by reflections from lens surfaces when we take photographs. It is more difficult to prevent such stray light in a digital camera than in a film camera because of high reflectance from the low-pass filter and diffraction from the image sensor. To prevent such stray light, we introduce an ultralow refractive index layer into the antireflective (AR) coatings. We used the solgel method to form porous fluoride layers with ultralow refractive indices, and we succeeded in developing a unique process to form AR coatings with superior performance. PMID:21460972
Energy Technology Data Exchange (ETDEWEB)
Ishak, Anuar [School of Mathematical Sciences, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Nazar, Roslinda [School of Mathematical Sciences, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)], E-mail: rmn72my@yahoo.com; Pop, Ioan [Faculty of Mathematics, University of Cluj, R-3400 Cluj, CP 253 (Romania)
2008-03-31
The mixed convection boundary layer flow through a stable stratified porous medium bounded by a vertical surface is investigated. The external velocity and the surface temperature are assumed to vary as x{sup m}, where x is measured from the leading edge of the vertical surface and m is a constant. Numerical solutions for the governing Darcy and energy equations are obtained. The results indicate that the thermal stratification significantly affects the surface shear stress as well as the surface heat transfer, besides delays the boundary layer separation.
Saad, Bilal Mohammed
2014-01-01
We study the convergence of a combined finite volume nonconforming finite element scheme on general meshes for a partially miscible two-phase flow model in anisotropic porous media. This model includes capillary effects and exchange between the phase. The diffusion term,which can be anisotropic and heterogeneous, is discretized by piecewise linear nonconforming triangular finite elements. The other terms are discretized by means of a cell-centered finite volume scheme on a dual mesh. The relative permeability of each phase is decentred according the sign of the velocity at the dual interface. The convergence of the scheme is proved thanks to an estimate on the two pressures which allows to show estimates on the discrete time and compactness results in the case of degenerate relative permeabilities. A key point in the scheme is to use particular averaging formula for the dissolution function arising in the diffusion term. We show also a simulation of CO
Influence of the anodic etching current density on the morphology of the porous SiC layer
Directory of Open Access Journals (Sweden)
Anh Tuan Cao
2014-03-01
Full Text Available In this report, we fabricated a porous layer in amorphous SiC thin films by using constant-current anodic etching in an electrolyte of aqueous diluted hydrofluoric acid. The morphology of the porous amorphous SiC layer changed as the anodic current density changed: At low current density, the porous layer had a low pore density and consisted of small pores that branched downward. At moderate current density, the pore size and depth increased, and the pores grew perpendicular to the surface, creating a columnar pore structure. At high current density, the porous structure remained perpendicular, the pore size increased, and the pore depth decreased. We explained the changes in pore size and depth at high current density by the growth of a silicon oxide layer during etching at the tips of the pores.
Directory of Open Access Journals (Sweden)
Jose I. Peña
2013-09-01
Full Text Available In this work, wear behavior and microstructural characterization of porous layers produced in glass-ceramic substrates by pulsed laser irradiation in the nanosecond range are studied under unidirectional sliding conditions against AISI316 and corundum counterbodies. Depending on the optical configuration of the laser beam and on the working parameters, the local temperature and pressure applied over the interaction zone can generate a porous glass-ceramic layer. Material transference from the ball to the porous glass-ceramic layer was observed in the wear tests carried out against the AISI316 ball counterface whereas, in the case of the corundum ball, the wear volume loss was concentrated in the porous layer. Wear rate and friction coefficient presented higher values than expected for dense glass-ceramics.
A combined SEM, CV and EIS study of multi-layered porous ceramic reactors for flue gas purification
DEFF Research Database (Denmark)
He, Zeming; Andersen, Kjeld Bøhm; Nygaard, Frederik Berg;
2013-01-01
The effect of sintering temperature of 12-layered porous ceramic reactors (comprising 5 cells) was studied using scanning electron microscopy (SEM), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The difference in microstructures of the reactors was evaluated by SEM...
Sainath, Kamalesh
2014-01-01
We discuss the application of Complex-Plane Gauss-Laguerre Quadrature (CGLQ) to efficiently evaluate two-dimensional Fourier integrals arising as the solution to electromagnetic fields radiated by elementary dipole antennas embedded within planar-layered media with arbitrary material parameters. More specifically, we apply CGLQ to the long-standing problem of rapidly and efficiently evaluating the semi-infinite length "tails" of the Fourier integral path while simultaneously and robustly guaranteeing absolute, exponential convergence of the field solution despite diversity in the doubly anisotropic layer parameters, source type (i.e., electric or equivalent magnetic dipole), source orientation, observed field type (magnetic or electric), (non-zero) frequency, and (non-zero) source-observer separation geometry. The proposed algorithm exhibits robustness despite unique challenges arising for the fast evaluation of such two-dimensional integrals. Herein, we (1) develop the mathematical treatment to rigorously ev...
Vishwakarma, Riteshkumar; Sharma, Subash; Shinde, Sachin M.; Sharma, Kamal P.; Thangaraja, Amutha; Kalita, Golap; Tanemura, Masaki
2016-05-01
Anisotropic etching of hexagonal boron nitride (h-BN) and boron-carbon-nitrogen (BCN) basal plane can be an exciting platform to develop well-defined structures with interesting properties. Here, we developed an etching process of atomically thin h-BN and BCN layers to fabricate nanoribbons (NRs) and other distinct structures by annealing in H2 and Ar gas mixture. BCN and h-BN films are grown on Cu foil by chemical vapor deposition (CVD) using solid camphor and ammonia borane as carbon, nitrogen and boron source, respectively. Formation of micron size well-defined etched holes and NRs are obtained in both h-BN and BCN layers by the post growth annealing process. The etching process of h-BN and BCN basal plane to fabricate NRs and other structures with pronounced edges can open up new possibilities in 2D hybrid materials.
Collins, David; Nesterenko, Ekaterina; Brabazon, Dermot; Paull, Brett
2012-01-01
An automated column fabrication technique that is based on a ultraviolet (UV) light-emitting diode (LED) array oven, and provides precisely controlled "in-capillary" ultraviolet (UV) initiated polymerization at 365 nm, is presented for the production of open tubular monolithic porous polymer layer capillary (monoPLOT) columns of varying length, inner diameter (ID), and porous layer thickness. The developed approach allows the preparation of columns of varying length, because of an automated c...
Douglas, Anna; Muralidharan, Nitin; Carter, Rachel; Share, Keith; Pint, Cary L.
2016-03-01
Here we demonstrate the first on-chip silicon-integrated rechargeable transient power source based on atomic layer deposition (ALD) coating of vanadium oxide (VOx) into porous silicon. A stable specific capacitance above 20 F g-1 is achieved until the device is triggered with alkaline solutions. Due to the rational design of the active VOx coating enabled by ALD, transience occurs through a rapid disabling step that occurs within seconds, followed by full dissolution of all active materials within 30 minutes of the initial trigger. This work demonstrates how engineered materials for energy storage can provide a basis for next-generation transient systems and highlights porous silicon as a versatile scaffold to integrate transient energy storage into transient electronics.Here we demonstrate the first on-chip silicon-integrated rechargeable transient power source based on atomic layer deposition (ALD) coating of vanadium oxide (VOx) into porous silicon. A stable specific capacitance above 20 F g-1 is achieved until the device is triggered with alkaline solutions. Due to the rational design of the active VOx coating enabled by ALD, transience occurs through a rapid disabling step that occurs within seconds, followed by full dissolution of all active materials within 30 minutes of the initial trigger. This work demonstrates how engineered materials for energy storage can provide a basis for next-generation transient systems and highlights porous silicon as a versatile scaffold to integrate transient energy storage into transient electronics. Electronic supplementary information (ESI) available: (i) Experimental details for ALD and material fabrication, ellipsometry film thickness, preparation of gel electrolyte and separator, details for electrochemical measurements, HRTEM image of VOx coated porous silicon, Raman spectroscopy for VOx as-deposited as well as annealed in air for 1 hour at 450 °C, SEM and transient behavior dissolution tests of uniformly coated VOx on
Visanko, Miikka; Liimatainen, Henrikki; Sirviö, Juho Antti; Haapala, Antti; Sliz, Rafal; Niinimäki, Jouko; Hormi, Osmo
2014-02-15
To fabricate a strong hydrophilic barrier layer for ultrafiltration (UF) membranes, 2,3-dicarboxylic acid cellulose nanofibrils with high anionic surface charge density (1.2 mekv/g at pH 7) and a width of 22 ± 4 nm were used. A simple vacuum filtration method combined with a solvent exchange procedure resulted in a porous layer with a thickness of ∼ 0.85 μm. The fabricated membranes reached high rejection efficiencies (74-80%) when aqueous dextrans up to 35-45 kDa were filtrated to evaluate the molecular weight cut-offs (MWCO). A linear correlation between the barrier layer thickness and the flux rate was observed in all tested cases. Further optimization of the barrier layer thickness can lead to an even more effective structure. PMID:24507322
International Nuclear Information System (INIS)
In this study, the warpage simulation of a multi-layer printed circuit board (PCB) was performed as a function of various copper (Cu) patterns/photoimageable solder resist (PSR) composite patterns and their anisotropic viscoelastic properties. The thermo-mechanical properties of Cu/PSR patterns were obtained from finite element analysis (virtual test) and homogenized with anisotropic composite shell models that considered the viscoelastic properties. The multi-layer PCB model was simplified based on the unit Cu/PSR patterns and the warpage simulation during the reflow process was performed by using ABAQUS combined with a user-defined subroutine. From these results, it was demonstrated that the proposed anisotropic viscoelastic composite shell simulation technique can be successfully used to predict warpage of multi-layer PCBs during the reflow process. (paper)
Institute of Scientific and Technical Information of China (English)
A.; TRESSAUD; C.; LABRUGèRE; E.; DURAND; C.; BRIGOULEIX; H.; ANDRIESSEN
2009-01-01
Conventional lithographic printing processes using porous alumina for offset applications generally use "wet" routes. Recently "dry" processes have been developed which are based on a heat-induced hydrophilic/oleophilic conversion of one or more layers of the coating so that a stronger affinity to-wards ink or water fountain is created at the exposed areas with respect to the surface of the unex-posed coating. Treatments involving rf plasma-enhanced fluorination (PEF) constitute exceptional tools for modifying the surface properties of materials. Many advantages of these techniques can be indeed outlined, when compared to more conventional methods: room-temperature reactions, chemical modi-fications limited to surface only without changing the bulk properties, possible non-equilibrium reac-tions. The influence of PEF treatments on porous alumina layer used in printing plates has been tested with various fluorinated gases (CF4, C3F8 and C4F8) and characterized by XPS. The hydrophobic prop-erties of the fluorinated layer have been deduced from contact angle measurements. Using C4F8 rf-PEF treatment, the outmost surface of the hydrophilic alumina substrate used for lithographic printing is hydrophobized, or in other words, the hydrophilic substrate is converted into a support with hydro-phobic properties. Once being hydrophobized, the surface layer may be rendered hydrophilic using a heat pulse, thus giving rise to switchable hydrophobic-hydrophilic properties of the material.
Institute of Scientific and Technical Information of China (English)
A.TRESSAUD; C.LABRUG(E)RE; E.DURAND; C.BRIGOULEIX; H.ANDRIESSEN
2009-01-01
Conventional lithographic printing processes using porous alumina for offset applications generally use "wet" routes. Recently "dry" processes have been developed which are based on a heat-induced hydrophilic/oleophilic conversion of one or more layers of the coating so that a stronger affinity to-wards ink or water fountain is created at the exposed areas with respect to the surface of the unex-posed coating. Treatments involving rf plasma-enhanced fluorination (PEF) constitute exceptional tools for modifying the surface properties of materials. Many advantages of these techniques can be indeed outlined, when compared to more conventional methods: room-temperature reactions, chemical modi-fications limited to surface only without changing the bulk properties, possible non-equilibrium reac-tions. The influence of PEF treatments on porous alumina layer used in printing plates has been tested with various fluorinated gases (CF4, C3F8and C4F8) and characterized by XPS. The hydrophobic prop-erties of the fluorinated layer have been deduced from contact angle measurements. Using C4Fs rf-PEF treatment, the outmost surface of the hydrophilic alumina substrate used for lithographic printing is hydrophobized, or in other words, the hydrophilic substrate is converted into a support with hydro-phobic properties. Once being hydrophobized, the surface layer may be rendered hydrophilic using a heat pulse, thus giving rise to switchable hydrophobic-hydrophilic properties of the material.
Bazylak, A; Markicevic, B; Sinton, D; Djilali, N
2008-01-01
Pore network modelling has traditionally been used to study displacement processes in idealized porous media related to geological flows, with applications ranging from groundwater hydrology to enhanced oil recovery. Very recently, pore network modelling has been applied to model the gas diffusion layer (GDL) of a polymer electrolyte membrane (PEM) fuel cell. Discrete pore network models have the potential to elucidate transport phenomena in the GDL with high computational efficiency, in contrast to continuum or molecular dynamics modelling that require extensive computational resources. However, the challenge in studying the GDL with pore network modelling lies in defining the network parameters that accurately describe the porous media as well as the conditions of fluid invasion that represent realistic transport processes. In this work, we discuss the first stage of developing and validating a GDL-representative pore network model. We begin with a two-dimensional pore network model with a single mobile pha...
Broadband quasi perfect absorption using chirped multi-layer porous materials
Jiménez, Noé; Cebrecos, Alejandro; Picó, Rubén; Sánchez-Morcillo, Víctor J; García-Raffi, Lluis M
2016-01-01
This work theoretically analyzes the sound absorption properties of a chirped multi-layer porous material including transmission, in particular showing the broadband unidirectional absorption properties of the system. Using the combination of the impedance matching condition and the balance between the leakage and the intrinsic losses as well as the critical coupling condition, the system is designed to have broadband unidirectional and nearly perfect absorption. The transfer and scattering matrix formalism, together with full wave numerical simulations are used to demonstrate the results showing excellent agreement between them. The proposed system allows to construct broadband sound absorbers with improved absorption in the low frequency regime using less than 15 \\% of the complete porous material.
Surface charging of thick porous water ice layers relevant for ion sputtering experiments
Galli, A.; Vorburger, A.; Pommerol, A.; Wurz, P.; Jost, B.; Poch, O.; Brouet, Y.; Tulej, M.; Thomas, N.
2016-07-01
We use a laboratory facility to study the sputtering properties of centimeter-thick porous water ice subjected to the bombardment of ions and electrons to better understand the formation of exospheres of the icy moons of Jupiter. Our ice samples are as similar as possible to the expected moon surfaces but surface charging of the samples during ion irradiation may distort the experimental results. We therefore monitor the time scales for charging and discharging of the samples when subjected to a beam of ions. These experiments allow us to derive an electric conductivity of deep porous ice layers. The results imply that electron irradiation and sputtering play a non-negligible role for certain plasma conditions at the icy moons of Jupiter. The observed ion sputtering yields from our ice samples are similar to previous experiments where compact ice films were sputtered off a micro-balance.
Electrochemical preparation of pore wall modification gradients across thin porous silicon layers.
Thompson, Corrina M; Nieuwoudt, Michel; Ruminski, Anne M; Sailor, Michael J; Miskelly, Gordon M
2010-05-18
Thin film porous silicon layers have been constructed in which the level of chemical modification to the pore walls is altered in a controlled gradient across the material. The gradient modification within such a nanoporous material represents a significant advance over gradients imposed across a flat surface. Gradients of methyl, pentyl acetate, and decyl groups are formed via electrochemical attachment of organohalides with an asymmetric electrode arrangement. The stability and hydrophobicity of the latter two systems have been improved through postprocess "end-capping" of the porous silicon with methyl groups. Two-dimensional mapping transmission FTIR microspectrophotometry and ATR-FTIR have been employed to characterize these new materials. Cleaving the surface-attached pentyl acetate groups to 5-hydroxypentyl groups leads to materials that can act as efficient visual indicators of the ethanol concentration in water over the range 1-10 vol %. PMID:20218688
Mesoscopic objects, porous layers and nanocomposites-Possibilities of sol-gel chemistry
International Nuclear Information System (INIS)
The goal of this study was to prepare mesoscopic objects, thin porous films and nanocomposite coatings with the use of sol-gel technique. Silica nanotubes, titania nanoparticles, porous titania and zirconia coatings as well as titania nanocomposites were successfully synthesized by changing the type of sol-gel precursor, sol composition and applying dip-coating deposition procedure in order to obtain thin films or coatings. All materials were visualized and characterized by the Atomic Force Microcscopy (AFM) technique. Moreover, characterization of titania nanocomposites was extended to the tribological tests performed by means of microtribometer operating in normal loads range of 30-100 mN. The AFM analysis of mesoscopic objects and nanoparticles showed that the diameter of synthesized silica nanotubes was 60-70 nm and the size of titania nanoparticles was 43 nm. In case of porous layers the pore size in titania and zirconia coatings oscillated between 100 and 240 nm, however their shape and distribution were irregular. Microtribological studies of nanocomposites revealed the moderate decrease of the coefficient of friction for samples containing 5, 15 and 5 wt.% of zirconia nanoparticles in titania coatings annealed at 100, 500 and 1000 deg. C respectively. An enhancement of antiwear properties was already observed for 1 wt.% of nanophase content, except the sample annealed at 500 deg. C. It was also found that the annealing at high temperatures is a primary factor which affects the reduction of friction and wear of titania coatings while the presence of nanoparticles has secondary effect. Investigations in this study carried out with the use of the AFM technique highlighted the potential and flexibility of sol-gel approach in designing of various types of advanced materials in a form of mesoscopic objects, porous coatings and composite layers. Results collected in this study clearly demonstrated that sol-gel technique can be applied effectively in preparation of
Liu, Rongzheng; Liu, Malin; Chang, Jiaxing; Shao, Youlin; Liu, Bing
2015-12-01
Tristructural-isotropic (TRISO) particle has been successful in high temperature gas cooled reactor (HTGR), but an improved design is required for future development. In this paper, the coating layers are reconsidered, and an improved design of TRISO particle with porous SiC inner layer is proposed. Three methods of preparing the porous SiC layer, called high methyltrichlorosilane (MTS) concentration method, high Ar concentration method and hexamethyldisilane (HMDS) method, are experimentally studied. It is indicated that porous SiC layer can be successfully prepared and the density of SiC layer can be adjusted by tuning the preparation parameters. Microstructure and characterization of the improved TRISO coated particle are given based on scanning electron microscope (SEM), X-ray diffraction (XRD), Raman scattering and energy dispersive X-ray (EDX) analysis. It can be found that the improved TRISO coated particle with porous SiC layer can be mass produced successfully. The formation mechanisms of porous SiC layer are also discussed based on the fluidized bed-chemical vapor deposition principle.
Assi, Hisham
2016-01-01
Numerical simulation of wave propagation in an infinite medium is made possible by surrounding a finite region by a perfectly matched layer (PML). Using this approach a generalized three-dimensional (3D) formulation is proposed for time-domain modeling of elastic wave propagation in an unbounded lossless anisotropic medium. The formulation is based on a second-order approach that has the advantages of, physical relationship to the underlying equations, and amenability to be implemented in common numerical schemes. Specifically, our formulation uses three second-order equations of the displacement field and nine auxiliary equations, along with the three time histories of the displacement field. The properties of the PML, which are controlled by a complex two-parameter stretch function, are such that it acts as near perfect absorber. Using finite element method (FEM) 3D numerical results are presented for a highly anisotropic medium. An extension of the formulation to the particular case of a Kelvin-Vogit visco...
Random Boundary Simulation of Pumping Groundwater on Two-layer Soft Soil Structure with Porous Media
Institute of Scientific and Technical Information of China (English)
无
2002-01-01
Based on random theory,fluid dynamics,porous media and soil mechanics,the porosity and random characteristic of the two-layer soft soil in Wuhan region were studied in this paper.The random seepage coefficient on the two-layer soft soil was analyzed,and the seepage model and its random distribution function were given.The groundwater flow differential equations related to the two layer soft soil structure were also established.The evaluation procedure of effect boundary on the pumping water in deep foundation pit was put forward.Moreover,with an engineering example,the probability distribution on random boundary prediction for pumping water of foundation pit was computed.
Sampath, Sridhar; Maydannik, Philipp; Ivanova, Tatiana; Shestakova, Marina; Homola, Tomáš; Bryukvin, Anton; Sillanpää, Mika; Nagumothu, Rameshbabu; Alagan, Viswanathan
2016-09-01
In the present study, TiO2 coated nano-porous silicon (TiO2/PS) was prepared by atomic layer deposition (ALD) whereas porous silicon was prepared by stain etching method for efficient solar photocatalytic activity. TiO2/PS was characterized by FESEM, AFM, XRD, XPS and DRS UV-vis spectrophotometer. Absorbance spectrum revealed that TiO2/PS absorbs complete solar light with wave length range of 300 nm-800 nm and most importantly, it absorbs stronger visible light than UV light. The reason for efficient solar light absorption of TiO2/PS is that nanostructured TiO2 layer absorbs UV light and nano-porous silicon layer absorbs visible light which is transparent to TiO2 layer. The amount of visible light absorption of TiO2/PS directly increases with increase of silicon etching time. The effect of silicon etching time of TiO2/PS on solar photocatalytic activity was investigated towards methylene blue dye degradation. Layer by layer solar absorption mechanism was used to explain the enhanced photocatalytic activity of TiO2/PS solar absorber. According to this, the photo-generated electrons of porous silicon will be effectively injected into TiO2 via hetero junction interface which leads to efficient charge separation even though porous silicon is not participating in any redox reactions in direct.
Series solutions of boundary-layer flows in porous media with lateral mass flux
Energy Technology Data Exchange (ETDEWEB)
Awang Kechil, Seripah [Universiti Tekonologi MARA, Department of Mathematics, Shah Alam Selangor (Malaysia); Hashim, Ishak [Universiti Kebangsaan Malaysia, School of Mathematical Sciences, UKM Bangi Selangor (Malaysia)
2008-08-15
Approximate analytical solutions for free convection boundary layers on a heated vertical plate with lateral mass flux embedded in a saturated porous medium are presented using the modified Adomian decomposition method and Pade technique. Several values of the wall temperature exponent for illustrating the effects of suction/injection parameter on the flow and heat transfer are considered. This study also includes the influence of the exponent on an impermeable surface. The results obtained are comparable to the exact analytical solutions and elucidate reliability and efficiency of the technique. (orig.)
Application of X-ray diffraction methods in the study of micrometer-sized porous Si layers
International Nuclear Information System (INIS)
An X-ray analysis of porous silicon layers (Sb-doped n+-Si(111)) obtained by anodic oxidation for different times with a current of 50 mA/cm2 is performed by the methods of double-crystal rocking curves and total external reflection. A nondestructive method for monitoring the stationary process of the formation of micrometer-sized porous silicon layers and estimating their porosity and thickness is proposed. The parameters obtained for porous silicon layers with a thickness of ∼6 μm are confirmed by the joint processing of diffraction curves for the 111 and 333 reflections on the basis of the developed model of dynamic scattering from layers while taking into account the strain profiles Δd(z)/d, the static Debye-Waller factor f(z), and the porosity P(z). The advantages and drawbacks of the proposed method are discussed.
Biodegradable polymer for sealing porous PEO layer on pure magnesium: An in vitro degradation study
Energy Technology Data Exchange (ETDEWEB)
Alabbasi, Alyaa; Mehjabeen, Afrin [Biomaterials and Engineering Materials (BEM) Laboratory, James Cook University, Townsville 4811, Queensland (Australia); Kannan, M. Bobby, E-mail: bobby.mathan@jcu.edu.au [Biomaterials and Engineering Materials (BEM) Laboratory, James Cook University, Townsville 4811, Queensland (Australia); Ye, Qingsong [Discipline of Dentistry, James Cook University, Townsville 4811, Queensland (Australia); Blawert, Carsten [Magnesium Innovation Centre, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502 (Germany)
2014-05-01
Graphical abstract: - Highlights: • Poly(L-lactide) was used to seal the porous PEO layer on Mg. • The dual-layer coating improved the in vitro degradation resistance of Mg. • Localized degradation was inhibited in the dual-layer coated Mg. - Abstract: An attempt was made to seal the porous silicate-based plasma electrolytic oxidation (PEO) layer on pure magnesium (Mg) with a biodegradable polymer, poly(L-lactide) (PLLA), to delay the localized degradation of magnesium-based implants in body fluid for better in-service mechanical integrity. Firstly, a silicate-based PEO coating on pure magnesium was performed using a pulsed constant current method. In order to seal the pores in the PEO layer, PLLA was coated using a two-step spin coating method. The performance of the PEO–PLLA Mg was evaluated using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The EIS results showed that the polarization resistance (R{sub p}) of the PEO–PLLA Mg was close to two orders of magnitude higher than that of the PEO Mg. While the corrosion current density (i{sub corr}) of the pure Mg was reduced by 65% with the PEO coating, the PEO–PLLA coating reduced the i{sub corr} by almost 100%. As expected, the R{sub p} of the PEO–PLLA Mg decreased with increase in exposure time. However, it was noted that the R{sub p} of the PEO–PLLA Mg even after 100 h was six times higher than that of the PEO Mg after 48 h exposure, and did not show any visible localized attack.
Du, Si-Hong; Wang, Li-Qun; Fu, Xiao-Ting; Chen, Ming-Ming; Wang, Cheng-Yang
2013-07-01
Porous starch was used as a precursor for hierarchical porous carbon microspheres. The preparation consisted of stabilisation, carbonisation and KOH activation, and the resultant hierarchical porous carbon microspheres had a large BET surface area of 3251 m(2)g(-1). Due to the large surface area and the hierarchical pore structure, electrodes made of the hierarchical porous carbon microsphere materials had high specific capacitances of 304 Fg(-1) at a current density of 0.05 Ag(-1) and 197 Fg(-1) at a current density of 180 Ag(-1) when used in a symmetric capacitor with 6M KOH as the electrolyte. After 10,000 cycles, the capacitor still exhibited a stable performance with a capacitance retention of 98%. These results indicate that porous starch is an excellent precursor to prepare high performance electrode materials for EDLCs.
Observation of anisotropic interlayer Raman modes in few-layer ReS{sub 2}
Energy Technology Data Exchange (ETDEWEB)
Nagler, Philipp; Plechinger, Gerd; Schueller, Christian; Korn, Tobias [Institut fuer Experimentelle und Angewandte Physik, Universitaet Regensburg, 93040, Regensburg (Germany)
2016-02-15
ReS{sub 2} has recently emerged as a new member in the rapidly growing family of two-dimensional materials. Unlike MoS{sub 2} or WSe{sub 2}, the optical and electrical properties of ReS{sub 2} are not isotropic due to the reduced symmetry of the crystal. Here, we present layer-dependent Raman measurements of ReS{sub 2} samples ranging from monolayers to ten layers in the ultralow frequency regime. We observe layer breathing and shear modes which allow for easy assignment of the number of layers. Polarization-dependent measurements give further insight into the crystal structure and reveal an energetic shift of the shear mode which stems from the in-plane anisotropy of the shear modulus in this material. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Computer-Aided Process Planning for the Layered Fabrication of Porous Scaffold Matrices
Starly, Binil
Rapid Prototyping (RP) technology promises to have a tremendous impact on the design and fabrication of porous tissue replacement structures for applications in tissue engineering and regenerative medicine. The layer-by-layer fabrication technology enables the design of patient-specific medical implants and complex structures for diseased tissue replacement strategies. Combined with advancements in imaging modalities and bio-modeling software, physicians can engage themselves in advanced solutions for craniofacial and mandibular reconstruction. For example, prior to the advancement of RP technologies, solid titanium parts used as implants for mandibular reconstruction were fashioned out of molding or CNC-based machining processes (Fig. 3.1). Titanium implants built using this process are often heavy, leading to increased patient discomfort. In addition, the Young's modulus of titanium is almost five times that of healthy cortical bone resulting in stress shielding effects [1,2]. With the advent of CAD/CAM-based tools, the virtual reconstruction of the implants has resulted in significant design improvements. The new generation of implants can be porous, enabling the in-growth of healthy bone tissue for additional implant fixation and stabilization. Newer implants would conform to the external shape of the defect site that is intended to be filled in. More importantly, the effective elastic modulus of the implant can be designed to match that of surrounding tissue. Ideally, the weight of the implant can be designed to equal the weight of the tissue that is being replaced resulting in increased patient comfort. Currently, such porous structures for reconstruction can only be fabricated using RP-based metal fabrication technologies such as Electron Beam Melting (EBM), Selective Laser Sintering (SLS®), and 3D™ Printing processes.
Tuncelli, Gülsevde; Ay, Ahmet Nedim; Zümreoglu-Karan, Birgül
2015-10-01
We report the synthesis, characterization and in vitro release behavior of anti-cancer drug carrying iron oxide@layered double hydroxide core-shell nanocomposites with sizes ranging from 40 to 300 nm, good drug loading capacities and soft ferromagnetic properties. HRTEM analyses verified that nearly spherical isotropic carriers were obtained by coating spherical magnetite particles while anisotropic carriers were obtained by coating spindle-shaped hematite particles. They both displayed a fluctuating in vitro release profile with a higher release percentage for the anisotropic carrier.
Magnetic texture of Nd2Fe14B solidified in the surface layer of anisotropic sintered-magnets
Institute of Scientific and Technical Information of China (English)
PAN Jing; LIU Xincai; TU Fenghua
2006-01-01
The arrangements of the easy magnetization axis [001] of columnar Nd2Fe14B crystals in the laser scanned layer on anisotropic sintered Nd15Fe77B8 magnets were investigated by XRD and the Bitter method. The results show that the common effects of both the heat flux and the substrate magnetization orientation constrain the columnar Nd2Fe14B solidified from the laser melting pool to form the c -axis texture orientated with the same direction as that of the substrate, when the geometric relationship between the heat flux in the laser scanning layer and c -axis texture orientation of the substrate is perpendicular to each other, and if the laser scanning velocity is no less than 25 mm·min-1 . The c -axes of columnar Nd2Fe14B crystals are no longer randomly distributed in the plane normal to their preferential growing direction as they are randomly done in both ingots cooled by water-cooling copper mould and directionally solidified Nd-Fe-B rods.
Lukianov, A.; Murakami, K.; Takazawa, C.; Ihara, M.
2016-05-01
Thin-film crystalline silicon is promising for photovoltaic application to reduce the cost of photovoltaic energy. Porous silicon structures have been intensively studied as a seed layer for epitaxial growth of thin Si film and layer-transfer process (LTP). In this article, another approach for LTP has been proposed. The seed layers for epitaxial silicon growth have been formed by zone-heating recrystallization of double-layer por-Si structures. The influence of annealing parameters on porous silicon structures was studied. The transformation of por-Si layer to crystalline Si was observed with the formation of smooth continuous surface with the roughness 0.3 nm, peak-to-valley distance around 3.5 nm, and reduced density of pores. The mechanism of the transformation of por-Si surface due to the action of hydrogen in the passivated pores with preventing surface oxidation was proposed.
Effects of zinc capping layers and annealing on the properties of porous silicon
Energy Technology Data Exchange (ETDEWEB)
Kim, Min Su; Yim, Kwang Gug; Kim, Soa Ram; Leem, Jae-Young; Nam, Gi Woong [Inje University, Gimhae (Korea, Republic of); Lee, Dong Yul [Samsung Electronics Co. Ltd., Yongin (Korea, Republic of); Kim, Jin Soo [Chonbuk National University, Jeonju (Korea, Republic of); Kim, Jong Su [Yeungnam University, Gyeongsan (Korea, Republic of); Son, Jeong Sik [Kyungwoon University, Gumi (Korea, Republic of)
2012-05-15
Porous silicon (PS) was prepared by using electrochemical anodization. Ultra-thin zinc layers were deposited on the PS by using plasma-assisted molecular beam epitaxy (PA-MBE). The effects of the zinc capping layers and annealing on the properties of the PS were investigated by using scanning electron microscopy (SEM) and photoluminescence (PL). The as-prepared PS has fissure-like pores over the entire surface. The irregular and randomly distributed nanosized pores became circular after deposition of zinc layers with a thickness of 120 A. As the annealing temperature was increased to 600 .deg. C, the diameter of the circular shaped pores increased. However, the contours of the circular shaped pores on the surface of the PS capped with the ultra-thin zinc layers (ZPS) became blurred slightly by further increases in the annealing temperature. The ZPS exhibited a higher intensity and an enhanced photostability of the red emission peak compared with conventional PS. The size and the number of the circular-shaped pores on the surface of the ZPS were increased by annealing, leading to increases in the intensities and the full width at half maximums and the redshifts of the emission peaks. Moreover, the annealing temperature of 600 .deg. C was the most suitable for enhancing the luminescent intensity of the ZPS.
Radial microstructure and optical properties of a porous silicon layer by pulse anodic etching*
Institute of Scientific and Technical Information of China (English)
Long Yongfu
2011-01-01
This paper investigates the radial refractive index and optical and physical thicknesses of porous silicon (PS) layers prepared by pulse etching by means of reflectance spectroscopy, photoluminescence spectroscopy and scanning electron microscopy (SEM). The relationship between the radial refractive index and optical thickness of the PS sample and the position away from the etched centre along the radial direction has been analyzed in detail.With the position farther away from the etched centre, the SEM image shows that the physical thickness of the PS sample decreases slowly, whereas intensely decreases from 2.48 to 1.72 μm near the edge at a distance of 58 μm. Moreover, the radial refractive index increases, indicating that the porosity becomes smaller. Meanwhile, the reflectance spectra exhibit the less intense interference oscillations, which mean that the uniformity and interface smoothness of the PS layers become worse, and the envelope curves of photoluminescence spectra exhibit a trend of blue-shift, indicating a reduction in nanocrystal dimensions. The PS micro-cavity is prepared to study the radial optical properties of the PS layer, and the results verify that the uniformity and smoothness of the PS layer in the centre are better than those at the edge.
Photoluminescence enhancement in porous SiC passivated by atomic layer deposited Al2O3 films
DEFF Research Database (Denmark)
Lu, Weifang; Iwasa, Yoshimi; Ou, Yiyu;
2016-01-01
Porous SiC co-doped with B and N was passivated by atomic layer deposited (ALD) Al2O3 films to enhance the photoluminescence. After optimizing the deposition conditions, as high as 14.9 times photoluminescence enhancement has been achieved.......Porous SiC co-doped with B and N was passivated by atomic layer deposited (ALD) Al2O3 films to enhance the photoluminescence. After optimizing the deposition conditions, as high as 14.9 times photoluminescence enhancement has been achieved....
Synthesis of PMA/Eu2O3 porous-layered nanocomposite by in situ polymerization and its morphology
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), and infrared ray (IR). Microscopic investigation of the nanocomposite was carried out by atomic force microscopy (AFM). The results showed that the shape of the composite was layered and porous. Eu2O3 was grafted when methyl acrylate (MA) polymerized; thus Eu2O3 particles appeared on both sides of the chains of polymeric methyl acrylate (PMA).
Tokudome, Yasuaki; Fukui, Megu; Tarutani, Naoki; Nishimura, Sari; Prevot, Vanessa; Forano, Claude; Poologasundarampillai, Gowsihan; Lee, Peter D; Takahashi, Masahide
2016-09-01
Hierarchically porous biocompatible Mg-Al-Cl-type layered double hydroxide (LDH) composites containing aluminum hydroxide (Alhy) have been prepared using a phase-separation process. The sol-gel synthesis allows for the hierarchical pores of the LDH-Alhy composites to be tuned, leading to a high specific solid surface area per unit volume available for high-molecular-weight protein adsorptions. A linear relationship between the effective surface area, SEFF, and loading capacity of a model protein, bovine serum albumin (BSA), is established following successful control of the structure of the LDH-Alhy composite. The threshold of the mean pore diameter, Dpm, above which BSA is effectively adsorbed on the surface of LDH-Alhy composites, is deduced as 20 nm. In particular, LDH-Alhy composite aerogels obtained via supercritical drying exhibit an extremely high capacity for protein loading (996 mg/g) as a result of a large mean mesopore diameter (>30 nm). The protein loading on LDH-Alhy is >14 times that of a reference LDH material (70 mg/g) prepared via a standard procedure. Importantly, BSA molecules pre-adsorbed on porous composites were successfully released on soaking in ionic solutions (HPO4(2-) and Cl(-) aqueous). The superior capability of the biocompatible LDH materials for loading, encapsulation, and releasing large quantities of proteins was clearly demonstrated. PMID:27501777
Zhang, Haitao; Zhang, Lei; Chen, Jun; Su, Hai; Liu, Fangyan; Yang, Weiqing
2016-05-01
With plenty of unique porous structure at micro-/nano scale, hierarchically porous carbons (HPCs) are promising for usage in advanced electric double layer supercapacitors (EDLCs) as the electrode materials. However, wide-range adoption of HPC for practical application is largely shadowed by its extremely complex synthesis process with considerably low production efficiency. Herein we reported a simple template-free, one-step sintering method, to massively produce the HPCs for high-performance EDLCs. Resorting to the 3D structure modification of the wide pore size distribution, high surface area of HPCs (up to 3000 m2 g-1) was achieved. By using 1 M Na2SO4 as electrolyte, the as-fabricated HPCs based EDLCs can be operated reversibly over a wide voltage window of 1.6 V with superior specific capacitance of 240 F g-1 under a current density of 0.5 A g-1. In the meanwhile, the EDLCs exhibit excellent rate capability (high power density of 16 kW kg-1 at 10.2 Wh kg-1) and long-term cycling stability with 9% loss of its initial capacitance after 2000 cycles. This output performance distinguished itself among most of the carbon-based EDLCs with neutral aqueous electrolyte. Thus, the template-free one-step sintering method produced HPCs for EDLCs represents a new approach for high-performance energy storage.
On the boundary layer structure near a highly permeable porous interface
Dalwadi, Mohit P; Waters, Sarah L; Oliver, James M
2015-01-01
The method of matched asymptotic expansions is used to study the canonical problem of steady laminar flow through a narrow two-dimensional channel blocked by a tight-fitting finite-length highly permeable porous obstacle. We investigate the behaviour of the local flow close to the interface between the single-phase and porous regions (governed by the incompressible Navier--Stokes and Darcy flow equations, respectively). We solve for the local flow in the limits of low and high Reynolds number, facilitating an understanding of the nature of the transition from Poiseuille to plug to Poiseuille flow in each of these limits. Significant analytic progress is made in the high-Reynolds-number limit, as we are able to explore in detail the rich boundary layer structure that occurs. We derive general results for the interfacial stress and for the conditions that couple the flow in the regions away from the interface. We consider the three-dimensional generalization to unsteady laminar flow through and around a tight-f...
Porous carbon with tailored pore size for electric double layer capacitors application
Chen, Hao; Wang, Fang; Tong, Shanshan; Guo, Shuangling; Pan, Xiumei
2012-06-01
A series of porous carbon samples as electric double layer capacitor electrode materials were prepared by a pyrolysis process using phenol formaldehyde resin (PF) as precursors and KOH/ZnCl2 as activation agents. Porous carbon samples were characterized by thermogravimetric analysis, X ray diffraction, nitrogen adsorption/desorption isotherms and transmission electron microscopy. The results showed that the KOH/ZnCl2/PF mass mixing ratio and activation temperature had a remarkable effect on the porosity, the specific surface area and the pore size of the carbons. The prepared carbon material PC-6 exhibits a high specific capacitance of 141.56 F/g and a average specific energy of 74.13 Wh/kg at a current density of 120 mA/g in the electrolyte of 1 M Et3MeNBF4/PC, and the average specific energy still remained 49.48 Wh/kg even at a high current density of 2000 mA/g. The excellent electrochemical behavior of PC-6 can be attributed to the highly development pore structure.
He, Xiao; Hu, Hengshan; Guan, Wei
2010-04-01
Dipole acoustic fields in an arbitrarily deviated well penetrating a homogeneous as well as a stratified transversely isotropic formation are simulated using a 3-D finite-difference time-domain algorithm in cylindrical coordinates. The modelling results show that a dipole source can excite a fast- and a slow-flexural mode due to the shear wave anisotropy when the borehole is inclined with respect to the symmetry axis of transverse isotropy. Both flexural slownesses change with the wellbore deviation angle. The splitting of flexural modes is prominent in full wave arrays when the shear anisotropy is strong enough. It is revealed that the dipole orientation influences the relative amplitudes of the fast- and slow-flexural waves but it has no effect on their slownesses or phases. In a vertical well parallel to the symmetry axis, the two flexural waves degenerate and propagate at the same speed. The degenerated flexural wave travels approximately at the shear speed along the borehole wall except in a few formations. Our study shows, for example, that it is about 10 per cent slower than the shear wave in Mesaverde clayshale 5501. Even in that kind of formations, however, extraction of the fast- and slow-shear velocities from the flexural modes is still possible if the borehole deviation is large enough. To examine the effect of layering, we modelled the full waves in a formation with a sandwich. When the well is perpendicular to the layer interfaces, reflection is obvious and can be recognized. It becomes weaker or even invisible as the deviation angle increases, so it is difficult to detect a thin layer embedded in a formation directly from reflected waves. The sandwich can, instead, be recognized from the irregularity in the spectra of the full waveforms displayed versus depth. [Correction added after online publication 25th February 2009; the original spelling of `homogenous' in the title has been corrected to `homogeneous'.[
de Jong, E. M. L. D.; Mannino, G.; Alberti, A.; Ruggeri, R.; Italia, M.; Zontone, F.; Chushkin, Y.; Pennisi, A. R.; Gregorkiewicz, T.; Faraci, G.
2016-05-01
Almost all physical processes in solids are influenced by phonons, but their effect is frequently overlooked. In this paper, we investigate the photoluminescence of large silicon nanoparticles (approximately 100 nm size, synthesized by chemical vapor deposition) in the visible to the infrared detection range. We find that upon increasing laser irradiance, an enormous photoluminescence emission band appears in the infrared. Its intensity exhibits a superlinear power dependence, increasing over four orders of magnitude in the investigated pump power range. Particles of different sizes as well as different shapes in porous layers are investigated. The results are discussed taking into account the efficient generation of phonons under high-power pumping, and the reduced capability, porosity dependent, of the silicon nanoparticles to exchange energy with each other and with the substrate. Our findings are relevant for heat management strategies in silicon.
Onset of Convection in a Nanofluid Saturated Porous Layer with Temperature Dependent Viscosity
Directory of Open Access Journals (Sweden)
I. S. Shivakumara
2014-04-01
Full Text Available The effect of nanofluid viscosity varying exponentially with temperature on the onset of convection in a layer of nanofluid saturated Darcy porous medium is investigated. The nanoparticle flux is zero condition on the boundaries is invoked to account for physically realistic situation. The resulting eigenvalue problem is solved numerically using the Galerkin method. It is observed that the instability sets in only as stationary convection and the occurrence of oscillatory convection is ruled out. The effect of viscosity parameter on the characteristics of stability is found to be significant and dual in nature. The onset of convection is hastened and the size of convection cells is enlarged with an increase in the value of modified diffusivity ratio, concentration Darcy-Rayleigh number, the modified particle density increment parameter and the Lewis number.
Formation of Porous Apatite Layer during In Vitro Study of Hydroxyapatite-AW Based Glass Composites
Directory of Open Access Journals (Sweden)
Pat Sooksaen
2015-01-01
Full Text Available This research discussed the fabrication, characterization, and in vitro study of composites based on the mixture of hydroxyapatite powder and apatite-wollastonite (AW based glass. AW based glass was prepared from the SiO2-CaO-MgO-P2O5-CaF2 glass system. This study focuses on the effect of composition and sintering temperature that influences the properties of these composites. Microstructural study revealed the formation of apatite layer on the composite surfaces when immersed in simulated body fluid (SBF solution at 37°C. Composites containing ≥50 wt% AW based glass showed good bioactivity after 7 days of immersion in the SBF. A porous calcium phosphate (potentially hydroxycarbonate apatite, HCA layer formed at the SBF-composite interface and the layer became denser at longer soaking period, for periods ranging from 7 to 28 days. Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES analysis showed that early stage of soaking occurred with the release of Ca and Si ions from the composites and the decrease of P ions with slow exchange rate.
Formation of a macro-porous SiO2 layer as an anti-reflective coating on glass substrates.
Park, No-Kuk; Kim, Yong Sul; Kim, Min Jung; Lee, Tae Jin; Lee, Seung Hyun; Lee, Seung Hun
2013-11-01
A macro-porous silica layer, consisting of a silica layer with macro-sized pores, was formed as an antireflective material on glass substrates. The silica layer and macro-pores were formed by the oxidative thermal decomposition of tetra-ethylorthorsilicate (TEOS) used as the precursor and polystyrene (PS) spherical beads used as the polymer template for the macro-pores at high temperatures. The size of pores was determined by the size of PS beads in the antireflective agent solution. The size of the PS spherical beads can be controlled by changing the concentration of styrene monomer, and the porosity of the macro pore in the silica layer could be controlled by the TEOS/PS ratio. The optimal thermal treating temperature for the formation of a macro-porous silica layer was found to be 650 degrees C. The size of the spherical type macro pores formed in the silica layer on the glass substrate was 100-150 nm. UV-Vis spectrophotometry confirmed the improved antireflective properties of the glass substrate with the macro-porous silica layer.
Capelli, R.; Mahne, N.; Koshmak, K.; Giglia, A.; Doyle, B. P.; Mukherjee, S.; Nannarone, S.; Pasquali, L.
2016-07-01
Resonant soft X-ray reflectivity at the carbon K edge, with linearly polarized light, was used to derive quantitative information of film morphology, molecular arrangement, and electronic orbital anisotropies of an ultrathin 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) film on Au(111). The experimental spectra were simulated by computing the propagation of the electromagnetic field in a trilayer system (vacuum/PTCDA/Au), where the organic film was treated as an anisotropic medium. Optical constants were derived from the calculated (through density functional theory) absorption cross sections of the single molecule along the three principal molecular axes. These were used to construct the dielectric tensor of the film, assuming the molecules to be lying flat with respect to the substrate and with a herringbone arrangement parallel to the substrate plane. Resonant soft X-ray reflectivity proved to be extremely sensitive to film thickness, down to the single molecular layer. The best agreement between simulation and experiment was found for a film of 1.6 nm, with flat laying configuration of the molecules. The high sensitivity to experimental geometries in terms of beam incidence and light polarization was also clarified through simulations. The optical anisotropies of the organic film were experimentally determined and through the comparison with calculations, it was possible to relate them to the orbital symmetry of the empty electronic states.
Numerical modeling and analysis of micro-porous layer effects in polymer electrolyte fuel cells
Energy Technology Data Exchange (ETDEWEB)
Kang, Kyungmun; Ju, Hyunchul [School of Mechanical Engineering, Inha University, 253 Yonghyun-Dong, Nam-Gu, Incheon 402-751 (Korea)
2009-12-01
It is well known that a micro-porous layer (MPL) plays a crucial role in the water management of polymer electrolyte fuel cells (PEFCs), and thereby, significantly stabilizes and improves cell performance. To ascertain the exact roles of MPLs, a numerical MPL model is developed in this study and incorporated with comprehensive, multi-dimensional, multi-phase fuel-cell models that have been devised earlier. The effects of different porous properties and liquid-entry pressures between an MPL and a gas diffusion layer (GDL) are examined via fully three-dimensional numerical simulations. First, when the differences in pore properties and wettability between the MPL and GDL are taken into account but the difference in the entry pressures is ignored, the numerical MPL model captures a discontinuity in liquid saturation at the GDL vertical stroke MPL interface. The simulation does not, however, capture the beneficial effects of an MPL on cell performance, predicting even lower performance than in the case of no MPL. On the other hand, when a high liquid-entry pressure in an MPL is additionally considered, the numerical MPL model predicts a liquid-free MPL and successfully demonstrates the phenomenon that the high liquid-entry pressure of the MPL prevents any liquid water from entering the MPL. Consequently, it is found from the simulation results that a liquid-free MPL significantly enhances the back-flow of water across the membrane into the anode, which, in turn, helps to avoid membrane dehydration and alleviate the level of GDL flooding. As a result, the model successfully reports the beneficial effects of MPLs on PEFC performance and predicts higher performance in the presence of MPLs (e.g., an increase of 67 mV at 1.5 A cm{sup -2}). This study provides a fundamental explanation of the function of MPLs and quantifies the influence of their porous properties and the liquid-entry pressure on water transport and cell performance. (author)
Energy Technology Data Exchange (ETDEWEB)
Koontz, S.L.; Leger, L.J.; Wu, C.; Cross, J.B.; Jurgensen, C.W. [Los Alamos National Lab., NM (United States)]|[Bell Telephone Labs., Inc., Murray Hill, NJ (United States)
1994-05-01
Neutral atomic oxygen is the most abundant component of the ionospheric plasma in the low Earth orbit environment (LEO; 200 to 700 kilometers altitude) and can produce significant degradation of some spacecraft materials. In order to produce a more complete understanding of the materials chemistry of atomic oxygen, the chemistry and physics of O-atom interactions with materials were determined in three radically different environments: (1) The Space Shuttle cargo bay in low Earth orbit (the EOIM-3 space flight experiment), (2) a high-velocity neutral atom beam system (HVAB) at Los Alamos National Laboratory (LANL), and (3) a microwave-plasma flowing-discharge system at JSC. The Space Shuttle and the high velocity atom beam systems produce atom-surface collision energies ranging from 0.1 to 7 eV (hyperthermal atoms) under high-vacuum conditions, while the flowing discharge system produces a 0.065 eV surface collision energy at a total pressure of 2 Torr. Data obtained in the three different O-atom environments referred to above show that the rate of O-atom reaction with polymeric materials is strongly dependent on atom kinetic energy, obeying a reactive scattering law which suggests that atom kinetic energy is directly available for overcoming activation barriers in the reaction. General relationships between polymer reactivity with O atoms and polymer composition and molecular structure have been determined. In addition, vacuum ultraviolet photochemical effects have been shown to dominate the reaction of O atoms with fluorocarbon polymers. Finally, studies of the materials chemistry of O atoms have produced results which may be of interest to technologists outside the aerospace industry. Atomic oxygen `spin-off` or `dual use` technologies in the areas of anisotropic etching in microelectronic materials and device processing, as well as surface chemistry engineering of porous solid materials are described.
Koontz, Steve L.; Leger, Lubert J.; Wu, Corina; Cross, Jon B.; Jurgensen, Charles W.
1994-01-01
Neutral atomic oxygen is the most abundant component of the ionospheric plasma in the low Earth orbit environment (LEO; 200 to 700 kilometers altitude) and can produce significant degradation of some spacecraft materials. In order to produce a more complete understanding of the materials chemistry of atomic oxygen, the chemistry and physics of O-atom interactions with materials were determined in three radically different environments: (1) The Space Shuttle cargo bay in low Earth orbit (the EOIM-3 space flight experiment), (2) a high-velocity neutral atom beam system (HVAB) at Los Alamos National Laboratory (LANL), and (3) a microwave-plasma flowing-discharge system at JSC. The Space Shuttle and the high velocity atom beam systems produce atom-surface collision energies ranging from 0.1 to 7 eV (hyperthermal atoms) under high-vacuum conditions, while the flowing discharge system produces a 0.065 eV surface collision energy at a total pressure of 2 Torr. Data obtained in the three different O-atom environments referred to above show that the rate of O-atom reaction with polymeric materials is strongly dependent on atom kinetic energy, obeying a reactive scattering law which suggests that atom kinetic energy is directly available for overcoming activation barriers in the reaction. General relationships between polymer reactivity with O atoms and polymer composition and molecular structure have been determined. In addition, vacuum ultraviolet photochemical effects have been shown to dominate the reaction of O atoms with fluorocarbon polymers. Finally, studies of the materials chemistry of O atoms have produced results which may be of interest to technologists outside the aerospace industry. Atomic oxygen 'spin-off' or 'dual use' technologies in the areas of anisotropic etching in microelectronic materials and device processing, as well as surface chemistry engineering of porous solid materials are described.
Karim, Marwa; Martini, Roberto; Radhakrishnan, Hariharsudan Sivaramakrishnan; van Nieuwenhuysen, Kris; Depauw, Valerie; Ramadan, Wedgan; Gordon, Ivan; Poortmans, Jef
2014-07-01
Sintered porous silicon is a well-known seed for homo-epitaxy that enables fabricating transferrable monocrystalline foils. The crystalline quality of these foils depends on the surface roughness and the strain of this porous seed, which should both be minimized. In order to provide guidelines for an optimum foil growth, we present a systematic investigation of the impact of the thickness of this seed and of its sintering time prior to epitaxial growth on strain and surface roughness. Strain and surface roughness were monitored in monolayers and double layers with different porosities as a function of seed thickness and of sintering time by high-resolution X-ray diffraction and profilometry, respectively. Unexpectedly, we found that strain in double and monolayers evolves in opposite ways with respect to layer thickness. This suggests that an interaction between layers in multiple stacks is to be considered. We also found that if higher seed thickness and longer annealing time are to be preferred to minimize the strain in double layers, the opposite is required to achieve smoother layers. The impact of these two parameters may be explained by considering the morphological evolution of the pores upon sintering and, in particular, the disappearance of interconnections between the porous seed and the bulk as well as the enlargement of pores near the surface. An optimum epitaxial growth hence calls for a trade-off in seed thickness and annealing time, between minimum-strained layers and rougher surfaces.
Zouzelka, Radek; Kusumawati, Yuly; Remzova, Monika; Rathousky, Jiri; Pauporté, Thierry
2016-11-01
TiO2 nanoparticles are suitable building blocks nanostructures for the synthesis of porous functional thin films. Here we report the preparation of films using brookite, P25 titania and anatase pristine nanoparticles and of nanocomposite layers combining anatase nanoparticles and multi-walled carbon nanotube (MWCNT) at various concentrations. The structure and phase composition of the layers were characterized by X-ray diffraction and Raman spectroscopy. Their morphology and texture properties were determined by scanning electron microscopy and krypton adsorption experiments, respectively. Additionally to a strong absorption in the UV range, the composites exhibited light absorption in the visible range as well. The photocatalytic performance of the layers was tested in the degradation of aqueous solutions of 4-chlorophenol serving as a model of an eco-persistent pollutant. Besides the determination of the decrease in the concentration of 4-chlorophenol, also the formation of intermediate degradation products, namely hydroquinone and benzoquinone, was followed. The presence of MWCNTs had a beneficial effect on the photocatalytic performance, a marked increase in the photocatalytic degradation rate constant being observed even at very low concentrations of MWCNTs. Compared to a P25 reference layer, the first order rate reaction constant increased by about 100% for the composite films containing MWCNTs at concentrations above 0.6 wt%. The key parameters for the enhancement of the photocatalytic performance are discussed. The presence of carbon nanotubes influences beneficially the degradation of 4-chlorophenol by an attack of the primarily photoproduced hydroxyl radicals onto the 4-chlorophenol molecules. The degradation due to the direct charge transfer is practically not influenced at all. PMID:27262272
Directory of Open Access Journals (Sweden)
R. Sekar
2013-05-01
Full Text Available Instability of themocovection in a multi-component fluid has wide range of applications in ionospheric, geothermal and industries. In this analysis, the effect of rotation and vertical anisotropy on Soret-driven thermoconvective instability in a ferrofluid has been studied. The fluid layer is assumed to be horizontal and is heated from below and salted from above. In momentum equation, the effect of both substantial derivatives and coriolis terms are considered. The resulting eigen value problem is solved using Brinkman model. A linear stability analysis is used for both stationary and oscillatory instabilities for different parameters for which normal mode technique is applied. The effect of rotation tends to stabilize the system and anisotropy and Soret effects tend to destabilize the system.
Indian Academy of Sciences (India)
D Mandal; P C Pal; S Kumar
2014-04-01
The disturbance and propagation of SH-type waves in an anisotropic soil layer overlying an inhomogeneous elastic half-space by a moving stress discontinuity is considered. Stress discontinuity moves with non-uniform velocity and is impulsive in nature. The displacements are obtained in exact form by themethod due to Cagniard modified by de Hoop. The numerical result is calculated for special cases and the natures are depicted graphically.
Biodegradable polymer for sealing porous PEO layer on pure magnesium: An in vitro degradation study
Alabbasi, Alyaa; Mehjabeen, Afrin; Kannan, M. Bobby; Ye, Qingsong; Blawert, Carsten
2014-05-01
An attempt was made to seal the porous silicate-based plasma electrolytic oxidation (PEO) layer on pure magnesium (Mg) with a biodegradable polymer, poly(L-lactide) (PLLA), to delay the localized degradation of magnesium-based implants in body fluid for better in-service mechanical integrity. Firstly, a silicate-based PEO coating on pure magnesium was performed using a pulsed constant current method. In order to seal the pores in the PEO layer, PLLA was coated using a two-step spin coating method. The performance of the PEO-PLLA Mg was evaluated using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The EIS results showed that the polarization resistance (Rp) of the PEO-PLLA Mg was close to two orders of magnitude higher than that of the PEO Mg. While the corrosion current density (icorr) of the pure Mg was reduced by 65% with the PEO coating, the PEO-PLLA coating reduced the icorr by almost 100%. As expected, the Rp of the PEO-PLLA Mg decreased with increase in exposure time. However, it was noted that the Rp of the PEO-PLLA Mg even after 100 h was six times higher than that of the PEO Mg after 48 h exposure, and did not show any visible localized attack.
Hydrodynamics of two phase flow through homogeneous and stratified porous layers
International Nuclear Information System (INIS)
An experimental investigation of two-phase flow through porous layers formed of nonheated glass particles has been made. The effect of particle size, particle size distribution, bed porosity and bed stratification on void fraction and pressure drop through particulate beds formed in a cylindrical and rectangular test section has been investigated. A model based on drift flux approach has been developed for the void fraction in homogeneous beds. Using the two phase friction pressure drop data, the relative permeabilities of the two phases have been concluded with void fraction. The void fraction and two-phase friction pressure gradient in beds composed of mixtures of spherical particles as well as sharps of different nominal sizes have also been examined. It is found that the models for single size particles are also applicable to mixtures of particles if a mean particle diameter for the mixture is defined. The observations in stratified beds indicate depletion or build up of voids at the interface between high and low permeability regions. Blocking of the flow into one of the layers of laterally stratified beds caused the pressures at different horizontal locations at the same bed height to be different from each other
Zhao, Guijuan; Wang, Lianshan; Yang, Shaoyan; Li, Huijie; Wei, Hongyuan; Han, Dongyue; Wang, Zhanguo
2016-01-01
We report the anisotropic structural and optical properties of semi-polar (11-22) GaN grown on m-plane sapphire using a three-step growth method which consisted of a low temperature AlN buffer layer, followed by a high temperature AlN buffer layer and GaN growth. By introducing double AlN buffer layers, we substantially improve the crystal and optical qualities of semi-polar (11-22) GaN, and significantly reduce the density of stacking faults and dislocations. The high resolution x-ray diffraction measurement revealed that the in-plane anisotropic structural characteristics of GaN layer are azimuthal dependent. Transmission electron microscopy analysis showed that the majority of dislocations in the GaN epitaxial layer grown on m-sapphire are the mixed-type and the orientation of GaN layer was rotated 58.4° against the substrate. The room temperature photoluminescence (PL) spectra showed the PL intensity and wavelength have polarization dependence along parallel and perpendicular to the [1-100] axis (polarization degrees ~ 0.63). The realization of a high polarization semi-polar GaN would be useful to achieve III-nitride based lighting emission device for displays and backlighting.
Effect of aging treatment on the in vitro nickel release from porous oxide layers on NiTi
Huan, Z.; Fratila-Apachitei, L. E.; Apachitei, I.; Duszczyk, J.
2013-06-01
Despite the ability of creating porous oxide layers on nickel-titanium alloy (NiTi) surface for biofunctionalization, the use of plasma electrolytic oxidation (PEO) has raised concerns over the possible increased levels of Ni release. Therefore, the primary aim of this study was to investigate the effect of aging in boiling water on Ni release from porous NiTi surfaces that have been formed by the PEO process. Based on different oxidation conditions, e.g. electrolyte composition and electrical parameters, three kinds of oxide layers with various characteristics were prepared on NiTi substrate. The process was followed by aging in boiling water for different durations. The Ni release was assessed by immersion tests in phosphate buffer saline and the Ni concentration was measured using the flame atomic absorption spectrometry. The results showed that aging in boiling water can significantly reduce the Ni release from oxidized porous samples, given that the duration of the treatment is finely adjusted according to the parameters of the as-formed oxide layer. Surface examination of the samples before and after aging in boiling water suggested that such a treatment is non-destructive while improving the corrosion resistance of oxidized samples, as evidenced by potentiodynamic polarization tests. The results of this study indicate that water boiling may be a suitable post-treatment required to minimize Ni release from porous oxides produced on NiTi by PEO for biomedical applications.
Directory of Open Access Journals (Sweden)
Stavrinidou Eleni
2011-01-01
Full Text Available Abstract We report on the fabrication and morphology/structural characterization of a porous anodic alumina (PAA/PtSi nano-template for use as matrix in template-assisted Si nanowire growth on a Si substrate. The PtSi layer was formed by electroless deposition from an aqueous solution containing the metal salt and HF, while the PAA membrane by anodizing an Al film deposited on the PtSi layer. The morphology and structure of the PtSi layer and of the alumina membrane on top were studied by Scanning and High Resolution Transmission Electron Microscopies (SEM, HRTEM. Cross sectional HRTEM images combined with electron diffraction (ED were used to characterize the different interfaces between Si, PtSi and porous anodic alumina.
Energy Technology Data Exchange (ETDEWEB)
Berrigan, John D.; Cai, Ye; Sandhage, Kenneth H. [School of Materials Science and Engineering, Air Force Center of Excellence on Bio-Nano-Enabled Inorganic/Organic Nanocomposites and Improved Cognition (BIONIC), Georgia Institute of Technology, 771 Ferst Drive, Atlanta, Georgia 30332-0400 (United States); Kang, Tae-Sik; Deneault, James R.; Durstock, Michael F. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio, 45433-7702 (United States)
2011-05-10
An aqueous, protein-enabled (biomimetic), layer-by-layer titania deposition process is developed, for the first time, to convert aligned-nanochannel templates into high-aspect-ratio, aligned nanotube arrays with thin (34 nm) walls composed of co-continuous networks of pores and titania nanocrystals (15 nm ave. size). Alumina templates with aligned open nanochannels are exposed in an alternating fashion to aqueous protamine-bearing and titania precursor-bearing (Ti(IV) bis-ammonium-lactato-dihydroxide, TiBALDH) solutions. The ability of protamine to bind to alumina and titania, and to induce the formation of a Ti-O-bearing coating upon exposure to the TiBALDH precursor, enables the layer-by-layer deposition of a conformal protamine/Ti-O-bearing coating on the nanochannel surfaces within the porous alumina template. Subsequent protamine pyrolysis yields coatings composed of co-continuous networks of pores and titania nanoparticles. Selective dissolution of the underlying alumina template through the porous coating then yields freestanding, aligned, porous-wall titania nanotube arrays. The interconnected pores within the nanotube walls allow enhanced loading of functional molecules (such as a Ru-based N719 dye), whereas the interconnected titania nanoparticles enable the high-aspect-ratio, aligned nanotube arrays to be used as electrodes (as demonstrated for dye-sensitized solar cells with power conversion efficiencies of 5.2 {+-} 0.4%). (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Directory of Open Access Journals (Sweden)
Waqar A Khan
Full Text Available In this study, the steady forced convection flow and heat transfer due to an impermeable stretching surface in a porous medium saturated with a nanofluid are investigated numerically. The Brinkman-Forchheimer model is used for the momentum equations (porous medium, whereas, Bongiorno's model is used for the nanofluid. Uniform temperature and nanofluid volume fraction are assumed at the surface. The boundary layer equations are transformed to ordinary differential equations in terms of the governing parameters including Prandtl and Lewis numbers, viscosity ratio, porous medium, Brownian motion and thermophoresis parameters. Numerical results for the velocity, temperature and concentration profiles, as well as for the reduced Nusselt and Sherwood numbers are obtained and presented graphically.
Outgassing of icy bodies in the Solar System - II. Heat transport in dry, porous surface dust layers
Gundlach, Bastian
2011-01-01
In this work, we present a new model for the heat conductivity of porous dust layers in vacuum, based on an existing solution of the heat transfer equation of single spheres in contact. This model is capable to distinguish between two different types of dust layers: dust layers composed of single particles (simple model) and dust layers consisting of individual aggregates (complex model). Additionally, we describe laboratory experiments, which were used to measure the heat conductivity of porous dust layers, in order to test the model. We found that the model predictions are in an excellent agreement with the experimental results. Furthermore, the implications of this new model on the modeling of cometary activity are discussed. Finally, the two variants of the model are used to calculate the H2O ice outgassing rate of comets as a function of the thickness of the ice-free dust layer. Therewith, the pressure inside the dust layer is derived and compared with the tensile strength of the material in order to dis...
Wang, Ya; Dou, Hui; Wang, Jie; Ding, Bing; Xu, Yunling; Chang, Zhi; Hao, Xiaodong
2016-09-01
In this work, an exfoliated MXene (e-MXene) nanosheets/nickel-aluminum layered double hydroxide (MXene/LDH) composite as supercapacitor electrode material is fabricated by in situ growth of LDH on e-MXene substrate. The LDH platelets homogeneously grown on the surface of the e-MXene sheets construct a three-dimensional (3D) porous structure, which not only leads to high active sites exposure of LDH and facile liquid electrolyte penetration, but also alleviates the volume change of LDH during the charge/discharge process. Meanwhile, the e -MXene substrate forms a conductive network to facilitate the electron transport of active material. The optimized MXene/LDH composite exhibits a high specific capacitance of 1061 F g-1 at a current density of 1 A g-1, excellent capacitance retention of 70% after 4000 cycle tests at a current density of 4 A g-1 and a good rate capability with 556 F g-1 retention at 10 A g-1.
Harries, Megan; Bukovsky-Reyes, Santiago; Bruno, Thomas J
2016-01-15
This paper details the sampling methods used with the field portable porous layer open tubular cryoadsorption (PLOT-cryo) approach, described in Part I of this two-part series, applied to several analytes of interest. We conducted tests with coumarin and 2,4,6-trinitrotoluene (two solutes that were used in initial development of PLOT-cryo technology), naphthalene, aviation turbine kerosene, and diesel fuel, on a variety of matrices and test beds. We demonstrated that these analytes can be easily detected and reliably identified using the portable unit for analyte collection. By leveraging efficiency-boosting temperature control and the high flow rate multiple capillary wafer, very short collection times (as low as 3s) yielded accurate detection. For diesel fuel spiked on glass beads, we determined a method detection limit below 1 ppm. We observed greater variability among separate samples analyzed with the portable unit than previously documented in work using the laboratory-based PLOT-cryo technology. We identify three likely sources that may help explain the additional variation: the use of a compressed air source to generate suction, matrix geometry, and variability in the local vapor concentration around the sampling probe as solute depletion occurs both locally around the probe and in the test bed as a whole. This field-portable adaptation of the PLOT-cryo approach has numerous and diverse potential applications.
Directory of Open Access Journals (Sweden)
Syeda Khudeja Akbar
2015-08-01
Full Text Available The effect of chemical reaction on the linear stability of a viscoelastic fluid saturated horizontal densely-packed porous layer is investigated. The viscoelastic properties are given by Maxwell constitutive relations. The porous layer is cooled from the upper boundary while an adiabatic thermal boundary condition is imposed at the lower boundary. Linear stability analysis suggests that there is a competition between the processes of viscous relaxation and thermal diffusion that causes the first convective instability to be oscillatory rather than stationary. The effect of Deborah number, Darcy-Prandtl number, normalized porosity, and the Frank-Kamenetskii number on the stability of the system is investigated. Using a weighted residual method we calculate numerically the convective thresholds for both stationary and oscillatory instability. The effects of viscoelasticity and chemical reaction on the instability are emphasized. Some existing results are reproduced as the particular cases of the present study.
Directory of Open Access Journals (Sweden)
Ivanović Dečan
2005-01-01
Full Text Available Through the porous contour in perpendicular direction, the fluid of the same properties as incompressible fluid in basic flow, has been injected or ejected with velocity who is a function of the contour longitudinal coordinate and time. The corresponding equations of unsteady boundary layer, by introducing the appropriate variable transformations, momentum and energy equations and two similarity parameters sets, are transformed into generalized form. These parameters are expressing the influence of the outer flow velocity, the injection or ejection velocity and the flow history in boundary layer, on the boundary layer characteristics. Obtained generalized solutions are used to calculate the distributions of velocity, and shear stress in laminar-turbulent transition of unsteady incompressible boundary layer on different porous contours: circular cylinder, thin elliptical cylinder and aerofoil, whose centers velocities changes in time as a degree functions. The ejection of fluid postpones the boundary layer separation, i.e. laminar-turbulent transition, and vice versa the injection of fluid favors the separation. Boundary layer characteristics are found directly, no further numerical integration of momentum equation.
Zhao, R.; Biesheuvel, P.M.; Miedema, H.; Bruning, H.; Wal, van der A.
2010-01-01
Porous electrodes are important in many physical-chemical processes including capacitive deionization (CDI), a desalination technology where ions are adsorbed from solution into the electrostatic double layers formed at the electrode/solution interface inside of two juxtaposed porous electrodes. A k
Surface wave propagation in a double liquid layer over a liquid-saturated porous half-space
Indian Academy of Sciences (India)
Rajneesh Kumar; Aseem Miglani; N R Garg
2002-12-01
The frequency equation is derived for surface waves in a liquidsaturated porous half-space supporting a double layer, that of inhomogeneous and homogeneous liquids. Asymptotic approximations of Bessel functions are used for long and short wavelength cases. Certain other problems are discussed as special cases. Velocity ratio (phase and group velocity) is obtained as a function of wavenumber and the results are shown graphically.
KHEM CHAND
2011-01-01
The heat transfer and hydromagnetic boundary layer flow of an electrically conducting viscous ,incompressible fluid over a continuous flat surface moving in a parallel free stream is investigated. The porous infinite surface is subjected to a slightly sinusoidal transverse suction velocity distribution. The flow becomes three dimensional due to this type of suction velocity without taking into account the induced magnetic field; the mathematical analysis is presented for the hydromagnetic lam...
Growth of Strain Free GaN Layers on (0001) Oriented Sapphire by Using Quasi-Porous GaN Template
Institute of Scientific and Technical Information of China (English)
XIE Xin-Jian; CHEN Jia-Rong; CAO Xian-Cun; ZHONG Fei; QIU Kai; LIU Gui-Feng; YIN Zhi-Jun; WANG Yu-Qi; LI Xin-Hua; JI Chang-Jian; HAN Qi-Fen
2006-01-01
We report the reduced-strain gallium-nitride (GaN) epitaxial growth on (0001) oriented sapphire by using quasi-porous GaN template. A GaN film in thickness of about 1μm was initially grown on a (0001) sapphire substrate by molecular beam epitaxy. Then it was dealt by putting, into 45% NaOH solution at 100°C for Wmin. By this process a quasi-porous GaN Rim was formed. An epitaxial GaN layer was grown on the porous GaN layer at 1050°C in the hydride vapour phase epitaxy reactor. The epitaxial layer grown on the porous GaN is found to have no cracks on the surface. That is much improved from many cracks on the surface of the GaN epitaxial layer grown on the sapphire as the same as on GaN buffer directly.
Energy Technology Data Exchange (ETDEWEB)
Samanipour, F. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Bayati, M.R., E-mail: mbayati@ncsu.edu [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC (United States); Zargar, H.R. [Department of Metals and Materials Engineering, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Golestani-Fard, F. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Center of Excellence for Advanced Materials, Iran University of Science and Technology, P.O. Box 16845-195, Tehran (Iran, Islamic Republic of); Troczynski, T. [Department of Metals and Materials Engineering, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Taheri, M. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of)
2011-09-22
Highlights: > ZrO{sub 2}-HA-TiO{sub 2} composite layers were synthesized via EPD/MAO hybrid technique. > Effect of the growth time on properties of the layers was studied. > Effect of the electrolyte composition on properties of the layers was studied. - Abstract: Micro arc oxidation (MAO) and electrophoretic deposition (EPD) processes were simultaneously employed to grow ZrO{sub 2}-HAp-TiO{sub 2} porous layers on titanium substrates under different conditions. Influence of the electrolyte composition and the growth time on surface morphology, topography, phase structure, and stoichiometry of the layers was investigated. The utilized electrolytes consisted of {beta}-glycerophosphate, calcium acetate, sodium phosphate, and micron sized yttria-stabilized zirconia with different concentrations. AFM and SEM evaluations revealed a rough surface with a porous structure with a pores size of 50-750 nm. The pores size increased with the time and the electrolyte concentration. Based on the XRD and XPS results, the layers consisted of anatase, hydroxyapatite, monoclinic ZrO{sub 2}, tetragonal ZrO{sub 2}, ZrO, CaTiO{sub 3}, and {alpha}-TCP phases whose fractions were observed to change depending on the synthesis conditions. The average crystalline size of the HAp phase was determined as {approx}54 nm. The nano-sized zirconia particles (d = 20-60 nm) were dispersed not only on surface, but also in depth of the layers. Utilizing thicker electrolytes and prolonging the growth time resulted in decomposition of hydroxyapatite as well as tetragonal ZrO{sub 2} to monoclinic ZrO{sub 2}. EDX results also showed that the zirconium wt% in the layers increased with the time. EPD-enhanced MAO (EEMAO) technique was expressed as an efficient route to fabricate ZrO{sub 2}-HAp-TiO{sub 2} multiphase systems within short times and only in one step.
Energy Technology Data Exchange (ETDEWEB)
Dai, Wei [Institute for Fuel Cell Innovation, National Research Council (Canada); State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070 (China); Wang, Haijiang; Yuan, Xiao-Zi; Martin, Jonathan; Shen, Jun [Institute for Fuel Cell Innovation, National Research Council (Canada); Pan, Mu; Luo, Zhiping [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070 (China)
2009-03-01
Water management in a proton exchange membrane (PEM) fuel cell is one of the critical issues for improving fuel cell performance and durability, and water transport across the gas diffusion layer plays a key role in PEM fuel cell water management. In this work, we investigated the effects of polytetrafluoroethylene (PTFE) content and the application of a micro-porous layer (MPL) in the gas diffusion layer (GDL) on the water transport rate across the GDL. The results show that both PTFE and the MPL play a similar role of restraining water transport. The effects of different carbon loadings in the MPL on water transport were also investigated. The results demonstrate that the higher the carbon loading in the MPL, the more it reduces the water transport rate. Using the given cell hardware and components, the optimized operation conditions can be obtained based on a water balance analysis. (author)
Lv, Yongqin; Lin, Zhixing; Tan, Tianwei; Svec, Frantisek
2013-11-01
Monolithic 50 μm thin poly(4-methylstyrene-co-chloromethylstyrene-co-divinylbenzene) layers attached to 6.0 cm × 3.3 cm glass plates have been prepared, using a thermally initiated polymerization process. These layers had a well-defined porous structure with a globular morphology demonstrated with SEM images and exhibited superhydrophobic properties characterized with a water contact angle of 157°. They were then used for thin-layer chromatography of peptides and proteins fluorescently labeled with fluorescamine. The spots of individual separated compounds were visualized using UV light, and their identities were confirmed with a matrix-assisted laser desorption/ionization time of flight mass spectrometry. The presence of chloromethylstyrene units in the polymer enabled hypercrosslinking via a Friedel-Crafts alkylation reaction, and led to monoliths with much larger surface areas, which were suitable for separations of small dye molecules.
Zieliński, Tomasz G.
2014-07-01
Acoustics of stiff porous media with open porosity can be very effectively modelled using the so-called Johnson-Champoux-Allard-Pride-Lafarge model for sound absorbing porous media with rigid frame. It is an advanced semi-phenomenological model with eight parameters, namely, the total porosity, the viscous permeability and its thermal analogue, the tortuosity, two characteristic lengths (one specific for viscous forces, the other for thermal effects), and finally, viscous and thermal tortuosities at the frequency limit of 0 Hz. Most of these parameters can be measured directly, however, to this end specific equipment is required different for various parameters. Moreover, some parameters are difficult to determine. This is one of several reasons for the so-called multiscale approach, where the parameters are computed from specific finite-element analyses based on some realistic geometric representations of the actual microstructure of porous material. Such approach is presented and validated for layers made up of loosely packed small identical rigid spheres. The sound absorption of such layers was measured experimentally in the impedance tube using the so-called two-microphone transfer function method. The layers are characterised by open porosity and semi-regular microstructure: the identical spheres are loosely packed by random pouring and mixing under the gravity force inside the impedance tubes of various size. Therefore, the regular sphere packings were used to generate Representative Volume Elements suitable for calculations at the micro-scale level. These packings involve only one, two, or four spheres so that the three-dimensional finite-element calculations specific for viscous, thermal, and tortuous effects are feasible. In the proposed geometric packings, the spheres were slightly shifted in order to achieve the correct value of total porosity which was precisely estimated for the layers tested experimentally. Finally, in this paper some results based on
Directory of Open Access Journals (Sweden)
Wenjiong Chen
2016-01-01
Full Text Available We present a design method for calculating and optimizing sound absorption coefficient of multi-layered porous fibrous metals (PFM in the low frequency range. PFM is simplified as an equivalent idealized sheet with all metallic fibers aligned in one direction and distributed in periodic hexagonal patterns. We use a phenomenological model in the literature to investigate the effects of pore geometrical parameters (fiber diameter and gap on sound absorption performance. The sound absorption coefficient of multi-layered PFMs is calculated using impedance translation theorem. To demonstrate the validity of the present model, we compare the predicted results with the experimental data. With the average sound absorption (low frequency range as the objective function and the fiber gaps as the design variables, an optimization method for multi-layered fibrous metals is proposed. A new fibrous layout with given porosity of multi-layered fibrous metals is suggested to achieve optimal low frequency sound absorption. The sound absorption coefficient of the optimal multi-layered fibrous metal is higher than the single-layered fibrous metal, and a significant effect of the fibrous material on sound absorption is found due to the surface porosity of the multi-layered fibrous.
Energy Technology Data Exchange (ETDEWEB)
Ouattara, B; Khouzam, A; Mojtabi, A [Universite de Toulouse (France); INPT, UPS (France); IMFT (Institut de Mecanique des Fluides de Toulouse), Allee Camille Soula, F-31400 Toulouse (France); Charrier-Mojtabi, M C, E-mail: bouattar@imft.fr, E-mail: akhouzam@imft.fr, E-mail: mojtabi@imft.fr, E-mail: cmojtabi@cict.fr [PHASE, EA 810, UFR PCA, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex (France)
2012-06-01
The aim of this study was to investigate the effect of conducting boundaries on the onset of convection in a binary fluid-saturated porous layer. The isotropic saturated porous layer is bounded by two impermeable but thermally conducting plates, subjected to a constant heat flux. These plates have identical conductivity. Moreover, the conductivity of the plates is generally different from the porous layer conductivity. The overall layer is of large extent in both horizontal directions. The problem is governed by seven dimensionless parameters, namely the normalized porosity of the medium {epsilon}, the ratio of plates over the porous layer thickness {delta} and their relative thermal conductivities ratio d, the separation ratio {delta}, the Lewis number Le and thermal Rayleigh number Ra. In this work, an analytical and numerical stability analysis is performed. The equilibrium solution is found to lose its stability via a stationary bifurcation or a Hopf bifurcation depending on the values of the dimensionless parameters. For the long-wavelength mode, the critical Rayleigh number is obtained as Ra{sub cs}=12(1+2d{delta} )/[1+{psi} (2d{delta}Le+Le+1)] and k{sub cs}=0 for {psi}> {psi} {sub uni}> 0. This work extends an earlier paper by Mojtabi and Rees (2011 Int. J. Heat Mass Transfer 54 293-301) who considered a configuration where the porous layer is saturated by a pure fluid.
Directory of Open Access Journals (Sweden)
Zhixin Yang
Full Text Available The onset of double diffusive convection in a viscoelastic fluid-saturated porous layer is studied when the fluid and solid phase are not in local thermal equilibrium. The modified Darcy model is used for the momentum equation and a two-field model is used for energy equation each representing the fluid and solid phases separately. The effect of thermal non-equilibrium on the onset of double diffusive convection is discussed. The critical Rayleigh number and the corresponding wave number for the exchange of stability and over-stability are obtained, and the onset criterion for stationary and oscillatory convection is derived analytically and discussed numerically.
Sobera, M.P.; Kleijn, C.R.
2008-01-01
We study flow and heat transfer to a cylinder in cross flow at Re = 3,900–80,000 by means of three-dimensional transient RANS (T-RANS) simulations, employing an RNG k − ε turbulence model. Both the case of a bare solid cylinder and that of a solid cylinder surrounded at some fixed distance by a thin porous layer have been studied. The latter configuration is a standard test geometry for measuring the insulating and protective performance of garments. In this geometry, the flow in the space be...
Institute of Scientific and Technical Information of China (English)
LiuQiang; ZhangJiaxuntffu
1999-01-01
This paper presents the structure design of four kinds of circular pipes with porous layer and the experimental results of condensation heat transfer of the moist air outside the horizontal circular pipes,By comparison with the experiments on bare piper,it is concluded that,the designed pipes not only have good condensation heat transfer performance,but also have the ability to collect and remove condensed liquid under zero gravity.They can be applied to the thermal control system for future large spacecraft.
Du, Xuan; Wang, Li; Zhao, Wei; Wang, Yi; Qi, Tao; Li, Chang Ming
2016-08-01
Renewable clean energy and resources recycling have become inevitable choices to solve worldwide energy shortages and environmental pollution problems. It is a great challenge to recycle tons of waste printed circuit boards (PCB) produced every year for clean environment while creating values. In this work, low cost, high quality activated carbons (ACs) were synthesized from non-metallic fractions (NMF) of waste PCB to offer a great potential for applications of electrochemical double-layer capacitors (EDLCs). After recovering metal from waste PCB, hierarchical porous carbons were produced from NMF by carbonization and activation processes. The experimental results exhibit that some pores were formed after carbonization due to the escape of impurity atoms introduced by additives in NMF. Then the pore structure was further tailored by adjusting the activation parameters. Roles of micropores and non-micropores in charge storage were investigated when the hierarchical porous carbons were applied as electrode of EDLCs. The highest specific capacitance of 210 F g-1 (at 50 mA g-1) and excellent rate capability were achieved when the ACs possessing a proper micropores/non-micropores ratio. This work not only provides a promising method to recycle PCB, but also investigates the structure tailoring arts for a rational hierarchical porous structure in energy storage/conversion.
Directory of Open Access Journals (Sweden)
Dhananjay Yadav
2016-01-01
Full Text Available In this study, the effect of Hall current on the criterion for the onset of MHD convection in a porous medium layer saturated by a nanofluid is investigated. The model used for nanofluid combines the effect of Brownian motion and thermophoresis, while for a porous medium Brinkman model is used. A physically more realistic boundary condition than the previous ones on the nanoparticle volume fraction is considered i.e. the nanoparticle flux is assumed to be zero rather than prescribing the nanoparticle volume fraction on the boundaries. Using linear stability theory, the exact analytical expression for critical Rayleigh Darcy number is obtained in terms of various non-dimensional parameters. Results indicate that the magnetic field, Hall current, porous medium and nanoparticles significantly influence the stability characteristics of the system. The increase in the Hall current parameter, the Lewis number, the modified diffusivity ratio and the concentration Rayleigh Darcy number is to hasten the onset of convection while the magnetic Darcy number, the porosity parameter and the Darcy number has stabilized on the onset of convection.
Modified CVD of nanoscale structures in and EVD of thin layers on porous ceramic membranes
Haart, de L.G.J.; Lin, Y.S.; Vries, de K.J.; Burggraaf, A.J.
1991-01-01
Experiments on the modified chemical vapour deposition (CVD) and the electrochemical vapour deposition (EVD) of yttria-stabilized zirconia on porous substrates are reported. It is shown that, in the CVD stage, deposition occurs in a small (<20 um) region at the edge of the substrate, very likely lea
Synthesis of Indium Nitride Epitaxial Layers on a Substrate of Porous Indium Phosphide
Directory of Open Access Journals (Sweden)
J.A. Suchikova
2015-10-01
Full Text Available The paper presents a technique to obtain InN films on porous InP substrates by radical-beam gettering epitaxy. According to the results of the Auger spectroscopy, InN film thickness ranged from 100 nm to 0.5 microns depending on the etching conditions.
Gao, Xiang; Lu, Ke; Xu, Lei; Xu, Hua; Lu, Haifeng; Gao, Feng; Hou, Shifeng; Ma, Houyi
2016-01-01
A novel, highly effective and environmentally friendly film-forming material, phytic acid (PA)/silane (denoted as PAS) hybrid with a three-dimensional (3D) network structure, was prepared through a condensation reaction of PA with methyltrihydroxysilane generated from the hydrolysis of methyltriethoxysilane (MTES). Two kinds of PAS-based pretreatment layers, namely NaBrO3-free and NaBrO3-doped PAS layers, were fabricated on iron substrates using the dip-coating method. SEM and AFM observations showed that the as-fabricated PAS-based layers possessed a 3D porous microstructure at the nanoscale and a rough surface morphology. X-ray photoelectron spectroscopic (XPS) and attenuated total reflection infrared (ATR-IR) spectroscopic characterization demonstrated that the above PAS layers bound to the iron surface via the -P-O- bond. Moreover, analyses of steady-state polarization curves and electrochemical impedance spectroscopic (EIS) data indicated that the corrosion rates of the iron substrates decreased considerably in the presence of the two PAS-based pretreatment layers. In particular, the NaBrO3-dosed PAS layer displayed the better corrosion resistance ability as well as maintaining the original microstructure and surface morphology. The PAS-based pretreatment layers are expected to act as substitutes for chromate and phosphate conversion layers and will find widespread application in the surface pretreatment of iron and steel materials due to the advantages of being environmentally friendly, the rapid film-forming process, and, especially, the nanoporous microstructure and rough surface morphology.A novel, highly effective and environmentally friendly film-forming material, phytic acid (PA)/silane (denoted as PAS) hybrid with a three-dimensional (3D) network structure, was prepared through a condensation reaction of PA with methyltrihydroxysilane generated from the hydrolysis of methyltriethoxysilane (MTES). Two kinds of PAS-based pretreatment layers, namely Na
Yushin, Gleb; Evanoff, Kara; Magasinski, Alexander
2012-01-01
Thin Si films coated on porous 3D particles composed of curved 2D graphene sheets have been synthesized utilizing techniques that allow for tunable properties. Since graphene exhibits specific surface area up to 100 times higher than carbon black or graphite, the deposition of the same mass of Si on graphene is much faster in comparison -- a factor which is important for practical applications. In addition, the distance between graphene layers is tunable and variation in the thickness of the deposited Si film is feasible. Both of these characteristics allow for optimization of the energy and power characteristics. Thicker films will allow higher capacity, but slower rate capabilities. Thinner films will allow more rapid charging, or higher power performance. In this innovation, uniform deposition of Si and C layers on high-surface area graphene produced granules with specific surface area (SSA) of 5 sq. m/g.
Energy Technology Data Exchange (ETDEWEB)
Lara, J.L. [Ocean and Coastal Research Group, Universidad de Cantabria, E.T.S.I.C.C. y P., Av. Los Castros s/n, 39005 Santander (Spain); Cowen, E.A.; Sou, I.M. [DeFrees Hydraulics Laboratory, School of Civil and Environmental Engineering, Hollister Hall, Cornell University, Ithaca, NY 14853-3501 (United States)
2002-07-01
Boundary layer flows are ubiquitous in the environment, but their study is often complicated by their thinness, geometric irregularity and boundary porosity. In this paper, we present an approach to making laboratory-based particle image velocimetry (PIV) measurements in these complex flow environments. Clear polycarbonate spheres were used to model a porous and rough bed. The strong curvature of the spheres results in a diffuse volume illuminated region instead of the more traditional finite and thin light sheet illuminated region, resulting in the imaging of both in-focus and significantly out-of-focus particles. Results of a traditional cross-correlation-based PIV-type analysis of these images demonstrate that the mean and turbulent features of an oscillatory boundary layer driven by a free-surface wave over an irregular-shaped porous bed can be robustly measured. Measurements of the mean flow, turbulent intensities, viscous and turbulent stresses are presented and discussed. Velocity spectra have been calculated showing an inertial subrange confirming that the PIV analysis is sufficiently robust to extract turbulence. The presented technique is particularly well suited for the study of highly dynamic free-surface flows that prevent the delivery of the light sheet from above the bed, such as swash flows. (orig.)
Gao, Xiang; Lu, Ke; Xu, Lei; Xu, Hua; Lu, Haifeng; Gao, Feng; Hou, Shifeng; Ma, Houyi
2016-01-21
A novel, highly effective and environmentally friendly film-forming material, phytic acid (PA)/silane (denoted as PAS) hybrid with a three-dimensional (3D) network structure, was prepared through a condensation reaction of PA with methyltrihydroxysilane generated from the hydrolysis of methyltriethoxysilane (MTES). Two kinds of PAS-based pretreatment layers, namely NaBrO3-free and NaBrO3-doped PAS layers, were fabricated on iron substrates using the dip-coating method. SEM and AFM observations showed that the as-fabricated PAS-based layers possessed a 3D porous microstructure at the nanoscale and a rough surface morphology. X-ray photoelectron spectroscopic (XPS) and attenuated total reflection infrared (ATR-IR) spectroscopic characterization demonstrated that the above PAS layers bound to the iron surface via the -P-O- bond. Moreover, analyses of steady-state polarization curves and electrochemical impedance spectroscopic (EIS) data indicated that the corrosion rates of the iron substrates decreased considerably in the presence of the two PAS-based pretreatment layers. In particular, the NaBrO3-dosed PAS layer displayed the better corrosion resistance ability as well as maintaining the original microstructure and surface morphology. The PAS-based pretreatment layers are expected to act as substitutes for chromate and phosphate conversion layers and will find widespread application in the surface pretreatment of iron and steel materials due to the advantages of being environmentally friendly, the rapid film-forming process, and, especially, the nanoporous microstructure and rough surface morphology. PMID:26689810
Energy Technology Data Exchange (ETDEWEB)
Wu, Rui; Zhu, Xun; Liao, Qiang; Wang, Hong; Ding, Yu-dong; Li, Jun; Ye, Ding-ding [Institute of Engineering Thermophysics, Chongqing University, Chongqing 400044 (China)
2010-09-15
Water flooding in gas diffusion material (GDM) is an important limit in performance of proton exchange membrane fuel cell (PEFMC). Some efforts, such as modifying the pore structures in the GDM, have been made in order to facilitate water transport and to reduce flooding in PEMFC. Recent experimental studies have demonstrated that using a bi-layer GDM, consisting of a fine micro-porous layer (MPL) and a coarse gas diffusion layer (GDL), can be advantageous for water management in PEMFC. In this work, a pore network model with an invasion percolation algorithm is developed and used to investigate the effects of MPL properties, including thickness, wettability and connectivity, on water distribution in the bi-layer GDM from the viewpoint at the pore level. Furthermore, a reasonable inlet boundary condition is proposed to describe the actual phenomenon that the CL surface is covered with many independent water droplets which are much larger than pore sizes in MPL. Influences of water droplet size and coverage fraction are also clarified in the present study. (author)
Koshel, Konstantin V.; Shishkarev, A. A.
1993-09-01
On the basis of invariant imbedding method the disturbance theory for complex constants of the propagation is proposed. This approach allowed us to consider influence of layer and anisotropic fluctuations of refractive index on the beyond-the-horizon propagation in the adiabatic approximation at the existence of the evaporation duct. Finally, the paper considers some examples of the calculations and investigates stochastic effects.
Barazanchy, Darun; Giurgiutiu, Victor
2016-04-01
A unified approach was formulated to predict guided-wave propagation in a material regardless its degree of anisotropy, thereby having one solution method for both isotropic and anisotropic material. The unified approach was based on the coupled eigenvalue problem derived from Chirstoffels equation for a lamina. The eigenvalue problem yielded a set of eigenvalues, and corresponding eigenvectors that were used to obtain the stress-displacement matrix. The dispersion curves were obtained by applying the traction free boundary conditions to the stress-displacement matrix, and searching for sign changes in the complex determinant of the matrix. To search for sign changes, hence the velocity-wavenumber pairs which yielded a solution to the problem, the real and imaginary part of the complex determinant had to change sign simultaneously. A phase angle approach was, therefore, developed and successfully applied. A refinement algorithm was applied to refine the accuracy of the solution without increasing the computational time significantly. A high accuracy was required to calculated the correct partial-wave participation factors. The obtained partial-wave participation factors were used to calculate the modeshape through the thickness for each velocity-wavenumber pair. To identify the different wave types, A0, S0, SHS0, SHA0, a modeshape identification was applied successfully. The unified approach was evaluated for hybrid aerospace composites. In addition, the two most common solution methods: (i) the global matrix method; and (ii) the transfer matrix method were applied, and a comparative study between the different methods was performed.
Sadeghifar, Hamidreza
2016-09-01
Convective heat transfer inside fibrous gas diffusion layers (GDLs) noticeably impacts the heat and water management of air-cooled polymer electrolyte membrane fuel cells (PEMFCs). Cutting-edge experiments have recently proved that convective heat transfer inside fibrous GDLs increases their thermal resistances considerably. However, heat transfer coefficients are difficult to measure experimentally or compute numerically for the millions of the tiny pores inside microstructural GDLs. The present study provides robust analytic models for predicting the heat transfer coefficient for both through-plane and in-plane flows inside fibrous media such as GDLs. The model is based on the unit cell approach and the integral method. Closed-form formulas are developed for local and average heat transfer coefficients. The model considers the temperature variations of the fiber layers along the medium thickness while assuming the same temperature for all the fibers in each layer. The model is well verified by COMSOL numerical data for a few pores inside a GDL. The simple, closed-form easy-to-use formulas developed in this study can be readily employed for predicting Nusselt number inside multilayer fibrous porous materials.
Ceballos, L; Prat, M
2013-04-01
We study numerically the process of quasistatic invasion of a fluid in thin porous layers from multiple inlet injection sources focusing on the effect of trapping or mixed wettability, that is, when hydrophobic and hydrophilic pores coexist in the system. Two flow scenarios are considered. In the first one, referred to as the sequential scenario, the injection bonds at the inlet are activated one after the other. In the second one, referred to as the kinetic scenario, the injection bonds at the inlet are activated simultaneously. In contrast with the case of purely hydrophobic systems with no trapping, studied in a previous work, it is shown that the invasion pattern and the breakthrough point statistics at the end of the displacement depend on the flow scenario when trapping or mixed wettability effects are taken into account. The transport properties of the defending phase are also studied and it is shown that a one-to-one relationship between the overall diffusive conductance and the mean saturation cannot be expected in a thin system. In contrast with thick systems, the diffusive conductance also depends on the thickness when the system is thin. After consideration of various generic aspects characterizing thin porous systems, the main results are briefly discussed in relation with the water management problem in proton exchange membrane fuel cells.
Kang, Danmiao; Liu, Qinglei; Gu, Jiajun; Su, Yishi; Zhang, Wang; Zhang, Di
2015-11-24
Here we report a method to fabricate porous carbon with small mesopores around 2-4 nm by simple activation of charcoals derived from carbonization of seaweed consisting of microcrystalline domains formed by the "egg-box" model. The existence of mesopores in charcoals leads to a high specific surface area up to 3270 m(2) g(-1), with 95% surface area provided by small mesopores. This special pore structure shows high adaptability when used as electrode materials for an electric double layer capacitor, especially at high charge-discharge rate. The gravimetric capacitance values of the porous carbon are 425 and 210 F g(-1) and volumetric capacitance values are 242 and 120 F cm(-3) in 1 M H2SO4 and 1 M TEA BF4/AN, respectively. The capacitances even remain at 280 F g(-1) (160 F cm(-3)) at 100 A g(-1) and 156 F g(-1) (90 F cm(-3)) at 50 A g(-1) in the aqueous and organic electrolytes, demonstrating excellent high-rate capacitive performance. PMID:26418602
Evaluation of porous ceramic cathode layers for solid oxide fuel cells
Haart, de L.G.J.; Vries, de K.J.; Carvalho, A.P.M.; Frade, J.R.; Marques, F.M.B.
1991-01-01
Sr0.15La0.85MnO3 layers with 2 and 10 u thickness, deposited on zirconia based electrolytes, were evaluated as cathodes for high temperature applications. Different electrode layers were characterized in terms of thickness, porosity, three phase boundary line per unit area (TPBL), and concentration
Irreversible membrane fouling abatement through pre-deposited layer of hierarchical porous carbons.
Hamad, Juma Z; Dua, Rubal; Kurniasari, Novita; Kennedy, Maria D; Wang, Peng; Amy, Gary L
2014-11-15
In this work, dual-templated hierarchical porous carbons (HPCs), produced from a coupled ice-hard templating approach, are shown to be a highly effective solution to the commonly occurring problem of irreversible fouling of low-pressure membranes used for pre-treatment in wastewater reuse. For the first time, dual-templated HPCs, along with their respective counterparts - single-templated meso-porous carbon (MPCs) (without macropores) - are tested in terms of their fouling reduction capacity and ability to remove different effluent organic matter fractions present in wastewater and compared with a commercially available powdered activated carbon (PAC). The synthesized HPCs provided exceptional fouling abatement, a 4-fold higher fouling reduction as compared to the previously reported best performing commercial PAC and ∼2.5-fold better fouling reduction than their respective mesoporous counterpart. Thus, it is shown that not only mesoporosity, but macroporosity is also necessary to achieve high fouling reduction, thus emphasizing the need for dual templating. In the case of HPCs, the pre-deposition technique is also found to outperform the traditional sorbent-feed mixing approach, mainly in terms of removal of fouling components. Based on their superior performance, a high permeability (ultra-low-pressure) membrane consisting of the synthesized HPC pre-deposited on a large pore size membrane support (0.45 μm membrane), is shown to give excellent pre-treatment performance for wastewater reuse application. PMID:25128660
Irreversible membrane fouling abatement through pre-deposited layer of hierarchical porous carbons
Hamad, Juma
2014-11-01
In this work, dual-templated hierarchical porous carbons (HPCs), produced from a coupled ice-hard templating approach, are shown to be a highly effective solution to the commonly occurring problem of irreversible fouling of low-pressure membranes used for pre-treatment in wastewater reuse. For the first time, dual-templated HPCs, along with their respective counterparts - single-templated meso-porous carbon (MPCs) (without macropores) - are tested in terms of their fouling reduction capacity and ability to remove different effluent organic matter fractions present in wastewater and compared with a commercially available powdered activated carbon (PAC). The synthesized HPCs provided exceptional fouling abatement, a 4-fold higher fouling reduction as compared to the previously reported best performing commercial PAC and ~2.5-fold better fouling reduction than their respective mesoporous counterpart. Thus, it is shown that not only mesoporosity, but macroporosity is also necessary to achieve high fouling reduction, thus emphasizing the need for dual templating. In the case of HPCs, the pre-deposition technique is also found to outperform the traditional sorbent-feed mixing approach, mainly in terms of removal of fouling components. Based on their superior performance, a high permeability (ultra-low-pressure) membrane consisting of the synthesized HPC pre-deposited on a large pore size membrane support (0.45μm membrane), is shown to give excellent pre-treatment performance for wastewater reuse application. © 2014 Elsevier Ltd.
Mathematical Modeling of Onset of Convection in a porous Layer with Viscosity Variation
Institute of Scientific and Technical Information of China (English)
FariborzRashidi; AliBahrami
2000-01-01
Instability theory is applied to diffusion-convection phenomenon in porous media,where the area in direction of transfer is large and viscosity of the oil varies due to gas dissolutio.n important application of this theory arises where diffusion-convection is employed as an EOR technique in oil reservoirs.As a bed of gas if formed below a column of oil,gas starts to diffuse into the oil,Therefore,the oil becomes lighter and an inverse gradient of density is developed as more gas diffuses in.Although this inverse density gradient is potentially unstable,convection will not initiate until the gradient extends to a certain value.The condition at which convection begins is known as "the onset of convection" and is well specified by the dimensionless Rayleigh number.In this study ,an instability analysis is made for convection-diffusion in large porous media,Unlike other studies where viscosity is assumed constant,in this work viscosity is postulated to be a function of gas concentration.It is shown that the mathematical model developed reduces to previous models if the viscosity variations are ignored.
Pan, Shengqiang; Zhao, Yuting; Huang, Gaoshan; Wang, Jiao; Baunack, Stefan; Gemming, Thomas; Li, Menglin; Zheng, Lirong; Schmidt, Oliver G.; Mei, Yongfeng
2015-09-01
A titanium dioxide (TiO2) interconnected porous structure has been fabricated by means of atomic layer deposition of TiO2 onto a reticular sponge template. The obtained freestanding TiO2 with large surface area can be easily taken out of the water to solve a complex separation procedure. A compact and conformal nanocoating was evidenced by morphologic characterization. A phase transition, as well as production of oxygen vacancies with increasing annealing temperature, was detected by x-ray diffraction and x-ray photoelectron spectroscopy, respectively. The photocatalytic experimental results demonstrated that the powder with appropriate annealing treatment possessed excellent photocatalytic ability due to the co-action of high surface area, oxygen vacancies and the optimal crystal structure.
Energy Technology Data Exchange (ETDEWEB)
Ezzat, M.A. [Alexandria Univ. (Egypt). Dept. of Mathematics; Abd-Elaal, M.Z. [Alexandria Univ. (Egypt). Dept. of Mathematics
1997-08-01
The method of the matrix exponential, which constitutes the basis of the state space approach of modern control theory, is applied to the non-dimensional equations of a viscoelastic fluid flow of hydromagnetic fluctuating boundary-layer through a porous medium bounded by an infinite non-magnetic vertical plate. The formulation is valid for one-dimensional problems. The resulting formulation together with the Laplace transform technique is applied to a variety of problems. The solution to a problem of an electrically conducting viscoelastic fluid in the presence of a transverse magnetic field and to a problem for the flow between two parallel fixed plates is obtained. The inversion of the Laplace transforms is carried out using a nuermical approach. Numerical results for the velocity distribution and the induced magnetic field are given and illustrated graphically for each problem. (orig.)
Sun, Bao-Zhen; Ma, Zuju; He, Chao; Wu, Kechen
2015-11-28
Thermoelectrics interconvert heat to electricity and are of great interest in waste heat recovery, solid-state cooling and so on. Here we assessed the potential of SnS2 and SnSe2 as thermoelectric materials at the temperature gradient from 300 to 800 K. Reflecting the crystal structure, the transport coefficients are highly anisotropic between a and c directions, in particular for the electrical conductivity. The preferred direction for both materials is the a direction in TE application. Most strikingly, when 800 K is reached, SnS2 can show a peak power factor (PF) of 15.50 μW cm(-1) K(-2) along the a direction, while a relatively low value (11.72 μW cm(-1) K(-2)) is obtained in the same direction of SnSe2. These values are comparable to those observed in thermoelectrics such as SnSe and SnS. At 300 K, the minimum lattice thermal conductivity (κmin) along the a direction is estimated to be about 0.67 and 0.55 W m(-1) K(-1) for SnS2 and SnSe2, respectively, even lower than the measured lattice thermal conductivity of Bi2Te3 (1.28 W m(-1) K(-1) at 300 K). The reasonable PF and κmin suggest that both SnS2 and SnSe2 are potential thermoelectric materials. Indeed, the estimated peak ZT can approach 0.88 for SnSe2 and a higher value of 0.96 for SnS2 along the a direction at a carrier concentration of 1.94 × 10(19) (SnSe2) vs. 2.87 × 10(19) cm(-3) (SnS2). The best ZT values in SnX2 (X = S, Se) are comparable to that in Bi2Te3 (0.8), a typical thermoelectric material. We hope that this theoretical investigation will provide useful information for further experimental and theoretical studies on optimizing the thermoelectric properties of SnX2 materials.
Directory of Open Access Journals (Sweden)
Yoshiyuki Kuroda et al
2008-01-01
Full Text Available Core-shell particles were prepared by the layer-by-layer (LbL assembly of imogolite (IMO nanotubes and poly(sodium 4-styrenesulfonate (PSS on polystyrene particles (diameter: 800 nm coated preliminarily with poly(diallyldimethylammonium chloride (PDDA. PSS and imogolite were alternately adsorbed on the particles to form core-shell particles with one to three bilayers of PSS/IMO. Macroporous hollow spheres were formed by removing polystyrene cores via heat treatment or extraction when the number of bilayers was 2 or 3. The sample formed by extraction (the number of bilayer was 3 showed only macroporosity and PSS remained in the shell, whereas the heat-treated sample showed hierarchical micro- and macroporosities. When the diameter of polystyrene particles decreased from 800 nm to 300 or 100 nm, hollow spheres were deformed because of the increase in the relative length of imogolite nanotubes against the size of polystyrene particles. Imogolite is a promising building block of hierarchically porous materials with core-shell morphologies using LbL assembly.
Pore Structure Reconstruction and Moisture Migration in Porous Media
Zheng, Jiayi; Shi, Xing; Shi, Juan; Chen, Zhenqian
2014-09-01
Three kinds of porous media (isotropic, perpendicular anisotropic and parallel anisotropic porous media) with the same porosity, different pore size distributions and fractal spectral dimensions were reconstructed by random growth method. It was aimed to theoretically study the impact of microscopic pore structure on water vapor diffusion process in porous media. The results show that pore size distribution can only denote the static characteristics of porous media but cannot effectively reflect the dynamic transport characteristics of porous media. Fractal spectral dimension can effectively analyze and reflect pores connectivity and moisture dynamic transport properties of porous media from the microscopic perspective. The pores connectivity and water vapor diffusion performance in pores of porous media get better with the increase of fractal spectral dimension of porous media. Fractal spectral dimension of parallel anisotropic porous media is more than that of perpendicular anisotropic porous media. Fractal spectral dimension of isotropic porous media is between parallel anisotropic porous media and perpendicular anisotropic porous media. Other macroscopic parameters such as equilibrium diffusion coefficient of water vapor, water vapor concentration variation at right boundary in equilibrium, the time when water vapor diffusion process reaches a stable state also can characterize the pores connectivity and water vapor diffusion properties of porous media.
Energy Technology Data Exchange (ETDEWEB)
Atyaoui, Malek, E-mail: atyaoui.malek@yahoo.fr [Laboratoire de Photovoltaïque, Centre de recherches et des technologies de l' energie, technopole de Borj-Cédria, PB:95, Hammam Lif 2050 (Tunisia); Dimassi, Wissem [Laboratoire de Photovoltaïque, Centre de recherches et des technologies de l' energie, technopole de Borj-Cédria, PB:95,Hammam Lif 2050 (Tunisia); Atyaoui, Atef [Laboratoire de traitement des eaux usées, Centre de recherches et des technologies des eaux, technopole de Borj-Cédria, PB: 273, Soliman 8020 (Tunisia); Elyagoubi, Jalel; Ouertani, Rachid; Ezzaouia, Hatem [Laboratoire de Photovoltaïque, Centre de recherches et des technologies de l' energie, technopole de Borj-Cédria, PB:95,Hammam Lif 2050 (Tunisia)
2013-09-15
The performance improvement of solar cells due to the formation of a porous silicon layer treated with rare earth (Ce, La) in the n{sup +} emitter of silicon n{sup +}/p junctions has been investigated. The photovoltaic properties of the cells with and without treatment of the porous silicon layer are compared. From the reflection measurements, it was shown that the cells with treated PS layers have lower reflectivity value compared to cell with untreated PS layer. The main result is that the photovoltaic energy conversion efficiency of solar cells can be enhanced by using the treated porous silicon layers with the rare earth (Ce, La) as anti-reflection coatings. -- Highlights: • The reduction of optical loss in silicon (c-Si) solar cells attracts the attention of many researches to achieve high efficiencies. • To attain this aim, the treated PS layers with rare earth (La, Ce) are suggested to be used as an (ARC) of c-Si solar cell. • The result showed a decrease in the optical losses which can explain the improved photovoltaic properties.
Forbes Inskip, Nathaniel; Meredith, Philip; Gudmundsson, Agust
2016-04-01
While considerable effort has been expended on the study of fracture propagation in rocks in recent years, our understanding of how fractures propagate through layered sedimentary rocks with different mechanical and elastic properties remains poorly constrained. Yet this is a key issue controlling the propagation of both natural and anthropogenic hydraulic fractures in layered sequences. Here we report measurements of the contrasting mechanical and elastic properties of the Lower Lias at Nash Point, South Wales, which comprises an interbedded sequence of shale and limestone layers, and how those properties may influence fracture propagation. Elastic properties of both materials have been characterised via ultrasonic wave velocity measurements as a function of azimuth on samples cored both normal and parallel to bedding. The shale is highly anisotropic, with P-wave velocities varying from 2231 to 3890 m s-1, giving an anisotropy of ~55%. By contrast, the limestone is essentially isotropic, with a mean P-wave velocity of 5828 m s-1 and an anisotropy of ~2%. The dynamic Young's modulus of the shale, calculated from P- and S-wave velocity data, is also anisotropic with a value of 36 GPa parallel to bedding and 12 GPa normal to bedding. The modulus of the limestone is again isotropic with a value of 80 GPa. It follows that for a vertical fracture propagating (i.e. normal to bedding) the modulus contrast is 6.6. This is important because the contrast in elastic properties is a key factor in controlling whether fractures arrest, deflect, or propagate across interfaces between layers in a sequence. There are three principal mechanisms by which a fracture may deflect across or along an interface, namely: Cook-Gordon debonding, stress barrier, and elastic mismatch. Preliminary numerical modelling results (using a Finite Element Modelling software) of induced fractures at Nash Point suggest that all three are important. The results demonstrate a rotation of the maximum
Energy Technology Data Exchange (ETDEWEB)
Chun, Jeong Hwan; Park, Ki Tae; Jo, Dong Hyun; Lee, Ji Young; Kim, Sang Gon; Kim, Sung Hyun [Department of Chemical and Biological Engineering, Korea University, 1 Anam-Dong, Seongbuk-Ku, Seoul 136-713 (Korea); Lee, Eun Sook; Jyoung, Jy-Young [Energy Research Center, HyupJin I and C Co., LTD, 143-1 Gwelang-Ri, Jungnam-Myun, Hwasung-Si, Kyunggi-Do (Korea)
2010-10-15
In this paper, the effect of the pore size distribution of a micro-porous layer (MPL) on the performance of polymer electrolyte membrane fuel cells (PEMFC) was investigated using self-made gas diffusion layers (GDLs) with different MPLs for which the pore size distribution was modified using pore forming agents under different drying conditions. When MPL dried at high temperature, more macro pores, approximately 1,000-20,000 nm in diameter, and less micro pores, below 100 nm, were observed relative to when MPL was dried at low temperature. Self-made GDLs were characterized by a field-emission scanning electron microscope (FE-SEM), mercury porosimetry and self-made gas permeability measurement equipment. The performance of the single cells was measured under two different humidification conditions. The results demonstrate that the optimum pore size distribution of MPL depended on the cell operating humidification condition. The MPL dried at high temperature performed better than the MPL dried at low temperature under a low humidification condition; however, MPL dried at low temperature performed better under a high humidification condition. (author)
Celli, Michele; Barletta, Antonio; Storesletten, Leiv
2014-04-01
The effects of lack of local thermal equilibrium between the solid phase and the fluid phase are taken into account for the convective stability analysis of a horizontal porous layer. The layer is bounded by a pair of plane parallel walls which are impermeable and such that the lower wall is subject to a uniform flux heating, while the upper wall is isothermal. The local thermal non-equilibrium is modelled through a two-temperature formulation of the energy exchange between the phases, resulting in a pair of local energy balance equations: one for each phase. Small-amplitude disturbances of the basic rest state are envisaged to test the stability. Then, the standard normal mode procedure is adopted to detect the onset conditions of convective rolls. Beyond the Darcy-Rayleigh number, playing the role of order parameter for the transition to instability, the relevant dimensionless parameters are the inter-phase heat transfer parameter and the thermal conductivity ratio. The disturbance governing equations, formulated as an eigenvalue problem, are solved numerically by a shooting method. Results are reported for the neutral stability curves and for the critical values for the onset of instability.
DEFF Research Database (Denmark)
Johannesson, Björn; Janz, Mårten
2009-01-01
, with account also to sorption hysteresis. The different materials in the considered layered construction are assigned different properties, i.e. vapor and liquid water diffusivities and boundary (wetting and drying) sorption curves. Further, the scanning behavior between wetting and drying boundary curves...
Fabrication and surface passivation of porous 6H-SiC by atomic layer deposited films
DEFF Research Database (Denmark)
Lu, Weifang; Ou, Yiyu; Petersen, Paul Michael;
2016-01-01
photoluminescence was observed and the etching process was optimized in terms of etching time and thickness. Enormous enhancement as well as redshift and broadening of photoluminescence spectra were observed after the passivation by atomic layer deposited Al2O3 and TiO2 films. No obvious luminescence was observed...
Ji, Sanghoon; Cho, Gu Young; Yu, Wonjong; Su, Pei-Chen; Lee, Min Hwan; Cha, Suk Won
2015-02-11
Nanoscale yttria-stabilized zirconia (YSZ) electrolyte film was deposited by plasma-enhanced atomic layer deposition (PEALD) on a porous anodic aluminum oxide supporting substrate for solid oxide fuel cells. The minimum thickness of PEALD-YSZ electrolyte required for a consistently high open circuit voltage of 1.17 V at 500 °C is 70 nm, which is much thinner than the reported thickness of 180 nm using nonplasmatic ALD and is also the thinnest attainable value reported in the literatures on a porous supporting substrate. By further reducing the electrolyte thickness, the grain size reduction resulted in high surface grain boundary density at the cathode/electrolyte interface.
Fridman, A. Ya.; Tsivadze, A. Yu.; Morozova, E. M.; Sokolova, N. P.; Voloshchuk, A. M.; Bardyshev, I. I.; Gorbunov, A. M.; Polyakova, I. Ya.; Titova, V. N.; Yavich, A. A.; Shapokhina, O. P.; Petrova, N. V.; Averin, A. A.
2014-08-01
Porous layers of associates of adsorption-saturated and benzene- and hexane-solvated chloride and sulfate of hydroxyethylated cyclams with acid aqua complexes were synthesized on the surface of PVC-coated cellulose fabric. The porous structure of the layers includes a system of internal pores connected with the external pores via the diamine rings of the common walls of the hydroxyethylated cyclam nets; the internal pores are filled with the associates; the solvent molecules are adsorbed on the developed surface of the layers or solvate it. The H+ motion rate in a layer placed in solvent vapors or liquid solvents was measured; the layers were found to be nonlinear H+ conductors. The potential of H+ transition from the acid solution into the layer, the H+ mobility constant, and the field variation constant of the H+ mobility of the layer depend on the layer composition. The adsorption and solvation are accompanied by the formation of host-guest molecular complexes between the diamine rings of the cyclam nets and the benzene or hexane molecules, affecting the resistance of the associates to the incorporation of H+ ions and the H+ mobility in the associates.
Directory of Open Access Journals (Sweden)
Molotkov L.
2006-12-01
Full Text Available Elastic properties of finely layered media are of great interest for seismic exploration. Theoretical models give a dependence of overall properties on constituent parameters. On the one hand they help geophysicists to estimate possible ranges of anisotropy and on the other hand they provide a basis for interpretation of measured anisotropic parameters in terms of microstructure. Last forty years such models with elastic constituents have been extensively used. Recently they have been updated for describing fractured rocks (Hsu and Schoenberg, 1993. In this case thin, and soft elastic layer models fracture. However reservoir rocks are porous and permeable. Porosity and permeability are taken into account by well-known Biot model. Finely layered porous sequences have some distinctive properties which are the topic of modern research (Schoenberg, 1996. Therefore it is important to update developed concepts to porous medium. Bakulin and Molotkov (1998, 1997 who generalized Backus averaging on poroelastic medium have done first step. Here we pay attention to one special case when there is only one preferential direction of fluid flow in porous rock. This may be caused by presence of impermeable barriers or lenses, which are modeled as set of solid layers intersecting porous medium. Such model corresponds to highly hydraulically anisotropic rock, which has very strong anisotropy of pore space structure and permeability. Les propriétés élastiques des milieux finement stratifiés présentent un grand intérêt pour l'exploration sismique. Les modèles théoriques donnent les propriétés générales en fonction des paramètres des constituants. D'une part, ils aident les géophysiciens à évaluer les gammes d'anisotropie possibles, et d'autre part, ils offrent une base pour l'interprétation des paramètres d'anisotropie mesurés en termes de microstructure. De tels modèles, élastiques, ont été largement utilisés ces quarante dernières ann
Surface Modification of Nano Porous Materials for Electric Double Layer Capacitors Application
Tashima, Daisuke; Kurosawatsu, Kenji; Sung, Youl-Moon; Otsubo, Masahisa; Honda, Chikahisa
2007-01-01
In this work, carbonaceous materials were modified in order to improve capacitance and charge density in electric double layer capacitors (EDLCs). Optimal conditions for plasma surface treatment of activated carbon have been examined for times from 10 min to 1 h at 150 ℃. The plasma is a high-frequency glow discharge in N2. The pressure of the gas is 13.3 Pa. The electrode is set up so that the EDLC sample is covered with the glow discharge. Space charge density can be improved by plasma surf...
Energy Technology Data Exchange (ETDEWEB)
Bayati, M.R., E-mail: mbayati@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695 (United States); School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Golestani-Fard, F. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Center of Excellence for Advanced Materials, Iran University of Science and Technology, P.O. Box 16845-195, Tehran (Iran, Islamic Republic of); Moshfegh, A.Z. [Department of Physics, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Institute for Nanoscience and Nanotechnology, Sharif University of Technology, P.O. Box 14588-89694, Tehran (Iran, Islamic Republic of); Molaei, Roya [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of)
2011-10-15
Highlights: {yields} S-TiO{sub 2} layers were grown by MAO technique under pulse current for the first time. {yields} Effect of growth parameters on chemical composition, topography, and morphology of the layers was studied. {yields} A correlation between photocatalytic performance and growth conditions was proposed. -- Abstract: Micro arc oxidation technique, as a facile and efficient process, was employed to grow sulfur doped titania porous layers. This research sheds light on the photocatalytic performance of the micro arc oxidized S-TiO{sub 2} nano-porous layers fabricated under pulse current. Morphological and topographical studies, performed by SEM and AFM techniques, revealed that increasing the frequency and/or decreasing the duty cycle resulted in formation of finer pores and smoother surfaces. XRD and XPS results showed that the layers consisted of anatase and rutile phases whose fraction was observed to change depending on the synthesis conditions. The highest anatase relative content was obtained at the frequency of 500 Hz and the duty cycle of 5%. Furthermore, photocatalytic activity of the layers was examined by measuring the decomposition rate of methylene blue under both ultraviolet and visible photo irradiations. Maximum photodegradation reaction rate constants over the pulse-grown S-TiO{sub 2} layers were respectively measured as 0.0202 and 0.0110 min{sup -1} for ultraviolet and visible irradiations.
Yoo, Hyun Deog; Jang, Jong Hyun; Ryu, Ji Heon; Park, Yuwon; Oh, Seung M.
2014-12-01
Electrochemical impedance analysis is performed to predict the rate capability of two commercial activated carbon electrodes (RP20 and MSP20) for electric double-layer capacitor. To this end, ac impedance data are fitted with an equivalent circuit that comprises ohmic resistance and impedance of intra-particle pores. To characterize the latter, ionic accessibility into intra-particle pores is profiled by using the fitted impedance parameters, and the profiles are transformed into utilizable capacitance plots as a function of charge-discharge rate. The rate capability that is predicted from the impedance analysis is well-matched with that observed from a charge-discharge rate test. It is found that rate capability is determined by ionic accessibility as well as ohmic voltage drop. A lower value in ionic accessibility for MSP20 is attributed to smaller pore diameter, longer length, and higher degree of complexity in pore structure.
Coriolis effect on thermal convection in a couple-stress fluid-saturated rotating rigid porous layer
Energy Technology Data Exchange (ETDEWEB)
Shivakumara, I.S.; Devaraju, N. [Bangalore University, UGC-Centre for Advanced studies in Fluid Mechanics, Department of Mathematics, Bangalore (India); Sureshkumar, S. [Siddaganga Institute of Technology, Department of Mathematics, Tumkur (India)
2011-04-15
Both linear and weakly nonlinear stability analyses are performed to study thermal convection in a rotating couple-stress fluid-saturated rigid porous layer. In the case of linear stability analysis, conditions for the occurrence of possible bifurcations are obtained. It is shown that Hopf bifurcation is possible due to Coriolis force, and it occurs at a lower value of the Rayleigh number at which the simple bifurcation occurs. In contrast to the nonrotating case, it is found that the couple-stress parameter plays a dual role in deciding the stability characteristics of the system, depending on the strength of rotation. Nonlinear stability analysis is carried out by constructing a set of coupled nonlinear ordinary differential equations using truncated representation of Fourier series. Sub-critical finite amplitude steady motions occur depending on the choice of physical parameters but at higher rotation rates oscillatory convection is found to be the preferred mode of instability. Besides, the stability of steady bifurcating equilibrium solution is discussed using modified perturbation theory. Heat transfer is calculated in terms of Nusselt number. Also, the transient behavior of the Nusselt number is investigated by solving the nonlinear differential equations numerically using the Runge-Kutta-Gill method. It is noted that increase in the value of Taylor number and the couple-stress parameter is to dampen the oscillations of Nusselt number and thereby to decrease the heat transfer. (orig.)
Institute of Scientific and Technical Information of China (English)
Zhang Caizhen; Wang Yongshun; Wang Zaixing
2011-01-01
A new two-step phosphorous diffusion gettering (TSPDG) process using a sacrificial porous silicon layer (PSL) is proposed.Due to a decrease in high temperature time,the TSPDG (PSL) process weakens the deterioration in performances of PSL,and increases the capability of impurity clusters to dissolve and diffuse to the gettering regions.By means of the TSPDG (PSL) process under conditions of 900 ℃/60 min + 700 ℃/30 min,the effective lifetime of minority carriers in solar-grade (SOG) Si is increased to 14.3 times its original value,and the short-circuit current density of solar cells is improved from 23.5 o 28.7 mA/cm2,and the open-circuit voltage from 0.534 to 0.596 V along with the transform efficiency from 8.1% to 11.8%,which are much superior to the results achieved by the PDG (PSL) process at 900 ℃ for 90 min.
A study of water transport as a function of the micro-porous layer arrangement in PEMFCs
Energy Technology Data Exchange (ETDEWEB)
Kim, Taeyoung; Lee, Seungjae; Park, Heekyung [Department of Civil and Environmental Engineering, KAIST, Guseong-dong, Yuseong-gu, Daejeon, 305-701 (Korea)
2010-08-15
Electrochemical losses as a function of the micro-porous layer (MPL) arrangement in Proton Exchange Membrane Fuel Cells (PEMFCs) are investigated by electrochemical impedance spectroscopy (EIS). Net water flux across the polymer membrane in PEMFCs is investigated for various arrangements of the MPL, namely with MPL on the cathode side alone, with MPL on both the cathode and the anode sides and without MPL. EIS and water transport are recorded for various operating conditions, such as the relative humidity of the hydrogen inlet and current density, in a PEMFC fed by fully-saturated air. The cell with an MPL on the cathode side alone has better performance than two other types of cells. Furthermore, the cell with an MPL on only the cathode increases the water flux from cathode to anode as compared to the cells with MPLs on both electrodes and cells without MPL. Oxygen-mass-transport resistances of cells in the presence of an MPL on the cathode are lower than the values for the other two cells, which indicates that the molar concentration of oxygen at the reaction surface of the catalyst layer is higher. This suggests that the MPL forces the liquid water from the cathode side to the anode side and decreases the liquid saturation in GDL at high current densities. Consequently, the MPL helps in maintaining the water content in the polymer membrane and decreases the cathode charge transfer and oxygen-mass transport resistances in PEMFCs, even when the hydrogen inlet has a low relative humidity. (author)
Honeycomb-structured porous poly(3,4-ethylenedioxythiophene) composite layers on a gold electrode
Energy Technology Data Exchange (ETDEWEB)
Krzyczmonik, Paweł, E-mail: pawel@chemia.uni.lodz.pl [Department of Inorganic and Analytical Chemistry, Team of Electroanalysis and Electrochemistry, University of Lodz, Tamka 12, 91-403 Lodz (Poland); Socha, Ewelina; Skrzypek, Sławomira [Department of Inorganic and Analytical Chemistry, Team of Electroanalysis and Electrochemistry, University of Lodz, Tamka 12, 91-403 Lodz (Poland); Soliwoda, Katarzyna; Celichowski, Grzegorz; Grobelny, Jarosław [Department of Materials Technology and Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz (Poland)
2014-08-28
Three microstructured electrodes modified with poly(3,4-ethylenedioxythiophene) (PEDOT) were obtained. One electrode was modified with PEDOT doped with poly(4-lithium styrenesulfonic acid) (PSSLi), the second one with a PEDOT + polyacrylic acid composite doped with PSSLi, and the third one with a PEDOT + anthranilic acid composite doped with poly(4-styrenesulfonic acid). The three electrodes were prepared using templates of polystyrene latex spheres (PS). The templates were deposited on the electrode using our dip-coating-like technique that we developed by optimizing key parameters, such as PS and sodium dodecyl sulfate concentration, angle of inclination, and decantation rate. The structure of the templates was verified by optical microscopy. A conducting polymer layer was obtained by electropolymerization from appropriate monomer solutions. In the final stage, the template was dissolved in toluene and the morphology of the resulting honeycomb-structure was examined by atomic force microscopy and scanning electron microscopy methods. The electrochemical properties of the electrodes were tested by cyclic voltammetry and electrochemical impedance spectroscopy. - Highlights: • We developed microstructured electrodes based on conducting composites. • We obtained three composites with PEDOT, polyacrylic acid and anthranilic acid. • All structures were obtained on a polystyrene template via electropolymerization. • SDS surfactant plays a key role during template deposition process.
Energy Technology Data Exchange (ETDEWEB)
Wang, Zhaomeng; Li, Lin; Liu, Erjia, E-mail: mejliu@ntu.edu.sg
2013-10-01
Graphene ultrathin films were synthesized by means of solid-state carbon diffusion from amorphous carbon (a-C) thin layers deposited on silicon substrates, which was catalyzed by nickel layers coated on the top of the a-C layers. The graphene films were used as working electrodes that were modified by a polyaniline (PANI) porous layer together with in-situ deposited bismuth (Bi) nanoparticles for the detection of trace heavy metal ions (Pb{sup 2+} and Cd{sup 2+}) in acetate buffer solutions (pH 5.3) with square wave anodic stripping voltammetry. The graphene electrodes modified with PANI porous layers and Bi nanoparticles had excellent repeatability, ultrahigh sensitivity (as low as 0.33 nM) and good resistance to passivation caused by the surface active species adsorbed on the electrode surfaces. - Highlights: • Graphene fabricated by nickel-catalyzed carbon diffusion in solid state • Graphene electrodes modified by bismuth nanoparticles and polyaniline layers • High resistance of modified graphene electrodes to passivation in acetate solutions • Ultra-low detection limits of lead and cadmium ions by modified graphene electrodes.
Tsivadze, A. Yu.; Fridman, A. Ya.; Morozova, E. M.; Sokolova, N. P.; Voloshchuk, A. M.; Petukhova, G. A.; Bardyshev, I. I.; Novikov, A. K.; Gorbunov, A. M.; Polyakova, I. Ya.; Titova, V. N.; Yavich, A. A.; Petrova, N. V.
2015-02-01
Layers of polynuclear NaOH complexes with aza-crown groups are synthesized using a NaOH solution on porous layers with internal voids of macromolecular hydroxyethylated cyclams on a chemically modified PVC coating that encapsulates the fibers of a cellulose fabric. The porous structure of the layers is studied along with the adsorption of solvent vapors (benzene, hexane) and liquid solvents. The OH- conductivity of layers that act as electrochemical bridges is examined in air and the vapor and liquid phases of the solvent. It is established that the complexes occupy the voids and have a developed system of hydrogen bonds. The pores are filled during adsorption. Molecules of the solvent are connected by the macrocyclic groups of pore walls into a host-guest complex as the structural system of hydrogen bonds changes. It is observed that the motions of OH- ions start at a certain value of potential E over. An expression describing the dependence of velocity of voltage is obtained: v' = K 1( E - E over) + K 2( E - E over)2, where K 1 is the conductivity constant of a layer and K 2 is the constant of transfer acceleration, determined by the structural changes in the layer in a field of moving OH- ions. It is shown that the values of E over, K 1, and K 2 depend on the composition of the complex and the nature of solvents.
Aziz, Asim; Siddique, J I; Aziz, Taha
2014-01-01
In this paper, a simplified model of an incompressible fluid flow along with heat and mass transfer past a porous flat plate embedded in a Darcy type porous medium is investigated. The velocity, thermal and mass slip conditions are utilized that has not been discussed in the literature before. The similarity transformations are used to transform the governing partial differential equations (PDEs) into a nonlinear ordinary differential equations (ODEs). The resulting system of ODEs is then reduced to a system of first order differential equations which was solved numerically by using Matlab bvp4c code. The effects of permeability, suction/injection parameter, velocity parameter and slip parameter on the structure of velocity, temperature and mass transfer rates are examined with the aid of several graphs. Moreover, observations based on Schmidt number and Soret number are also presented. The result shows, the increase in permeability of the porous medium increase the velocity and decrease the temperature profile. This happens due to a decrease in drag of the fluid flow. In the case of heat transfer, the increase in permeability and slip parameter causes an increase in heat transfer. However for the case of increase in thermal slip parameter there is a decrease in heat transfer. An increase in the mass slip parameter causes a decrease in the concentration field. The suction and injection parameter has similar effect on concentration profile as for the case of velocity profile.
Anisotropic universe with anisotropic sources
Energy Technology Data Exchange (ETDEWEB)
Aluri, Pavan K.; Panda, Sukanta; Sharma, Manabendra; Thakur, Snigdha, E-mail: aluri@iucaa.ernet.in, E-mail: sukanta@iiserb.ac.in, E-mail: manabendra@iiserb.ac.in, E-mail: snigdha@iiserb.ac.in [Department of Physics, IISER Bhopal, Bhopal - 462023 (India)
2013-12-01
We analyze the state space of a Bianchi-I universe with anisotropic sources. Here we consider an extended state space which includes null geodesics in this background. The evolution equations for all the state observables are derived. Dynamical systems approach is used to study the evolution of these equations. The asymptotic stable fixed points for all the evolution equations are found. We also check our analytic results with numerical analysis of these dynamical equations. The evolution of the state observables are studied both in cosmic time and using a dimensionless time variable. Then we repeat the same analysis with a more realistic scenario, adding the isotropic (dust like dark) matter and a cosmological constant (dark energy) to our anisotropic sources, to study their co-evolution. The universe now approaches a de Sitter space asymptotically dominated by the cosmological constant. The cosmic microwave background anisotropy maps due to shear are also generated in this scenario, assuming that the universe contains anisotropic matter along with the usual (dark) matter and vacuum (dark) energy since decoupling. We find that they contribute dominantly to the CMB quadrupole. We also constrain the current level of anisotropy and also search for any cosmic preferred axis present in the data. We use the Union 2 Supernovae data to this extent. An anisotropy axis close to the mirror symmetry axis seen in the cosmic microwave background data from Planck probe is found.
Material Induced Anisotropic Damage
Niazi, M.S.; Wisselink, H.H.; Meinders, V.T.; Boogaard, van den A.H.; Hora, P.
2012-01-01
The anisotropy in damage can be driven by two different phenomena; anisotropic defor-mation state named Load Induced Anisotropic Damage (LIAD) and anisotropic (shape and/or distribution) second phase particles named Material Induced Anisotropic Damage (MIAD). Most anisotropic damage models are based
Farzadi, Arghavan; Solati-Hashjin, Mehran; Asadi-Eydivand, Mitra; Abu Osman, Noor Azuan
2014-01-01
Powder-based inkjet 3D printing method is one of the most attractive solid free form techniques. It involves a sequential layering process through which 3D porous scaffolds can be directly produced from computer-generated models. 3D printed products' quality are controlled by the optimal build parameters. In this study, Calcium Sulfate based powders were used for porous scaffolds fabrication. The printed scaffolds of 0.8 mm pore size, with different layer thickness and printing orientation, were subjected to the depowdering step. The effects of four layer thicknesses and printing orientations, (parallel to X, Y and Z), on the physical and mechanical properties of printed scaffolds were investigated. It was observed that the compressive strength, toughness and Young's modulus of samples with 0.1125 and 0.125 mm layer thickness were more than others. Furthermore, the results of SEM and μCT analyses showed that samples with 0.1125 mm layer thickness printed in X direction have more dimensional accuracy and significantly close to CAD software based designs with predefined pore size, porosity and pore interconnectivity.
Directory of Open Access Journals (Sweden)
Arghavan Farzadi
Full Text Available Powder-based inkjet 3D printing method is one of the most attractive solid free form techniques. It involves a sequential layering process through which 3D porous scaffolds can be directly produced from computer-generated models. 3D printed products' quality are controlled by the optimal build parameters. In this study, Calcium Sulfate based powders were used for porous scaffolds fabrication. The printed scaffolds of 0.8 mm pore size, with different layer thickness and printing orientation, were subjected to the depowdering step. The effects of four layer thicknesses and printing orientations, (parallel to X, Y and Z, on the physical and mechanical properties of printed scaffolds were investigated. It was observed that the compressive strength, toughness and Young's modulus of samples with 0.1125 and 0.125 mm layer thickness were more than others. Furthermore, the results of SEM and μCT analyses showed that samples with 0.1125 mm layer thickness printed in X direction have more dimensional accuracy and significantly close to CAD software based designs with predefined pore size, porosity and pore interconnectivity.
Ghani, Milad; Frizzarin, Rejane M; Maya, Fernando; Cerdà, Víctor
2016-07-01
Herein we report the use of cobalt porous coordination polymers (PCP) as intermediates to prepare advanced extraction media based on layered double hydroxides (LDH) supported on melamine polymer foam. The obtained dissolvable Ni-Co LDH composite sponges can be molded and used as sorbent for the in-syringe solid-phase extraction (SPE) of phenolic acids from fruit juices. The proposed sorbent is obtained due to the surfactant-assisted self-assembly of Co(II)/imidazolate PCPs on commercially available melamine foam, followed by the in situ conversion of the PCP into the final dissolvable LDH coating. Advantageous features for SPE are obtained by using PCPs with hierarchical porosity (HPCPs). The LDH-sponge prepared using intermediate HPCPs (HLDH-sponge) is placed in the headspace of a glass syringe, enabling flow-through extraction followed by analyte elution by the dissolution of the LDH coating in acidic conditions. Three phenolic acids (gallic acid, p-hydroxybenzoic acid and caffeic acid) were extracted and quantified using high performance liquid chromatography. Using a 5mL sample volume, the obtained detection limits were 0.15-0.35μgL(-1). The proposed method for the preparation of HLDH-sponges showed a good reproducibility as observed from the intra- and inter-day RSD's, which were <10% for all analytes. The batch-to-batch reproducibility for three different batches of HLDH-sponges was 10.6-11.2%. Enrichment factors of 15-21 were obtained. The HLDH-sponges were applied satisfactorily to the determination of phenolic acids in natural and commercial fruit juices, obtaining relative recoveries among 89.7-95.3%. PMID:27247213
Ghani, Milad; Frizzarin, Rejane M; Maya, Fernando; Cerdà, Víctor
2016-07-01
Herein we report the use of cobalt porous coordination polymers (PCP) as intermediates to prepare advanced extraction media based on layered double hydroxides (LDH) supported on melamine polymer foam. The obtained dissolvable Ni-Co LDH composite sponges can be molded and used as sorbent for the in-syringe solid-phase extraction (SPE) of phenolic acids from fruit juices. The proposed sorbent is obtained due to the surfactant-assisted self-assembly of Co(II)/imidazolate PCPs on commercially available melamine foam, followed by the in situ conversion of the PCP into the final dissolvable LDH coating. Advantageous features for SPE are obtained by using PCPs with hierarchical porosity (HPCPs). The LDH-sponge prepared using intermediate HPCPs (HLDH-sponge) is placed in the headspace of a glass syringe, enabling flow-through extraction followed by analyte elution by the dissolution of the LDH coating in acidic conditions. Three phenolic acids (gallic acid, p-hydroxybenzoic acid and caffeic acid) were extracted and quantified using high performance liquid chromatography. Using a 5mL sample volume, the obtained detection limits were 0.15-0.35μgL(-1). The proposed method for the preparation of HLDH-sponges showed a good reproducibility as observed from the intra- and inter-day RSD's, which were <10% for all analytes. The batch-to-batch reproducibility for three different batches of HLDH-sponges was 10.6-11.2%. Enrichment factors of 15-21 were obtained. The HLDH-sponges were applied satisfactorily to the determination of phenolic acids in natural and commercial fruit juices, obtaining relative recoveries among 89.7-95.3%.
Aziz, Asim; Ali, Yasir; Aziz, Taha; Siddique, J I
2015-01-01
In this paper, we investigate the slip effects on the boundary layer flow and heat transfer characteristics of a power-law fluid past a porous flat plate embedded in the Darcy type porous medium. The nonlinear coupled system of partial differential equations governing the flow and heat transfer of a power-law fluid is transformed into a system of nonlinear coupled ordinary differential equations by applying a suitable similarity transformation. The resulting system of ordinary differential equations is solved numerically using Matlab bvp4c solver. Numerical results are presented in the form of graphs and the effects of the power-law index, velocity and thermal slip parameters, permeability parameter, suction/injection parameter on the velocity and temperature profiles are examined.
Srinivasacharya, D.; Surender, Ontela
2015-01-01
The effect of thermal and mass stratification on mixed convection boundary layer flow over a vertical flat plate embedded in a porous medium saturated by a nanofluid has been investigated. The vertical plate is maintained at uniform and constant heat, mass and nanoparticle fluxes, and the behavior of the porous medium is described by the Darcy model. The model considered for nanofluids incorporates the effects of Brownian motion and thermophoresis. In addition, the thermal energy equations include regular diffusion and cross-diffusion terms. A suitable coordinate transformation is introduced, and the obtained system of non-similar, coupled and non-linear partial differential equations is solved numerically. The influence of pertinent parameters on the non-dimensional velocity, temperature, concentration and nanoparticle volume fraction are discussed. In addition, the variation of heat, mass and nanoparticle transfer rates at the plate are exhibited graphically for different values of physical parameters.
Increasing The Efficiency of Silicon Solar Cells via an Anti-reflecting Nano-porous Surface Layer
Coskuner, Ahmet; Gokce, Aisha; Altunay, Omer; Skarlatos, Yani; Ozatay, Ozhan
2015-03-01
Electrochemical etching of silicon in a controlled environment results in a porous surface that has many application areas from drug delivery to optoluminescent devices. There is vast interest in implementing porous silicon in silicon solar cells to increase light absorption and therefore the efficiency. Here we demonstrate successful formation of a nano-porous surface on mono-crystalline Si wafers as well as doped Si solar cells. Our results show that pre-cleaning and post-drying is crucial to acquire a smooth, non-cracked topography. We also find that under similar conditions, smaller pores in a denser arrangement and with shorter depths form in p-n junction type Si wafers compared to n-type or p-type Si. In ITO coated porous Si solar cells with Al back contacts, the measured efficiency increase is almost 50% of those without a porous surface. This is a promising result to further enhance the performance of Si solar cell devices.
DEFF Research Database (Denmark)
Ni, De Wei; Esposito, Vincenzo; Schmidt, Cristine Grings;
Gadolinium-doped cerium oxide (CGO) and lanthanum strontium manganate (LSM) are electro-ceramics materials with high potential for several electrochemical applications such as solid Oxide Fuel Cell (SOFC), gas separation membranes, and flue gas purification devices. Especially for novel electroch......Gadolinium-doped cerium oxide (CGO) and lanthanum strontium manganate (LSM) are electro-ceramics materials with high potential for several electrochemical applications such as solid Oxide Fuel Cell (SOFC), gas separation membranes, and flue gas purification devices. Especially for novel...... electrochemical flue gas purification devices, multilayer structures with alternating porous layers of CGO and a LSM/CGO mixture are used to achieve specific functional requirements. In a manufacturing process of such ceramic multilayer devices, co-firing is one of the critical steps as many defects...... such as cracks, de-lamination and shape distortion can result as a consequence of sintering mismatch stresses caused by the strain rate difference between layers. This work seeks to understand the underlying mechanisms that occur during the co-firing of porous CGO-LSM/CGO bi-layer laminates, by evaluating...
Energy Technology Data Exchange (ETDEWEB)
Janene, N.; Hajjaji, A.; Ben Rabha, M.; Bessais, B.; Gaidi, M. [Photovoltaic Laboratory Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia); El Khakani, M.A. [Institut National de la Recherche Scientifique, INRS-Energie, Materiaux et Telecommunications, 1650, Blvd. Lionel-Boulet, Varennes, Quebec J3X 1S2 (Canada)
2012-10-15
In this work a novel passivation technique is proposed for multicrystalline silicon wafers for the purpose of solar cell application. The new method combines the use of double treatment based on porous Si and TiO{sub 2} passivation. Porous silicon (PS) was prepared by electrochemical anodization of multi crystalline substrates (mc-Si) under different conditions of current density (The current density used is between 3 and 50 mA/cm{sup 2}). It was demonstrated that the porosity increases with increasing current density from 27, 66% to 81%. TiO{sub 2} nanoparticles with different nanometric sizes were incorporated inside pores by the way of the pulsed laser deposition (PLD) technique. The deposited layers have been characterized by spectrophotometry, Fourier transform infrared spectroscopy (FTIR) analysis. It was found that the binary structure of TiO{sub 2}/PS minimizes the average reflectivity of the mc-Si substrates from 36% for bare multi crystalline silicon to around 14% for treated substrate. The TiO{sub 2}/porous Si treated samples present high photoluminescence intensity and an enhancement of the optoelectronic properties. As a result the effective minority carrier lifetime shows a strong improvement after the combined treatment (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Linga Raju, T.; Neela Rao, B.
2016-05-01
An unsteady MHD two-layered fluid flow of electrically conducting fluids in a horizontal channel bounded by two parallel porous plates under the influence of a transversely applied uniform strong magnetic field in a rotating system is analyzed. The flow is driven by a common constant pressure gradient in a channel bounded by two parallel porous plates, one being stationary and the other oscillatory. The two fluids are assumed to be incompressible, electrically conducting with different viscosities and electrical conductivities. The governing partial differential equations are reduced to the linear ordinary differential equations using two-term series. The resulting equations are solved analytically to obtain exact solutions for the velocity distributions (primary and secondary) in the two regions respectively, by assuming their solutions as a combination of both the steady state and time dependent components of the solutions. Numerical values of the velocity distributions are computed for different sets of values of the governing parameters involved in the study and their corresponding profiles are also plotted. The details of the flow characteristics and their dependence on the governing parameters involved, such as the Hartmann number, Taylor number, porous parameter, ratio of the viscosities, electrical conductivities and heights are discussed. Also an observation is made how the velocity distributions vary with the rotating hydromagnetic interaction in the case of steady and unsteady flow motions. The primary velocity distributions in the two regions are seen to decrease with an increase in the Taylor number, but an increase in the Taylor number causes a rise in secondary velocity distributions. It is found that an increase in the porous parameter decreases both the primary and secondary velocity distributions in the two regions.
Directory of Open Access Journals (Sweden)
Linga Raju T.
2016-05-01
Full Text Available An unsteady MHD two-layered fluid flow of electrically conducting fluids in a horizontal channel bounded by two parallel porous plates under the influence of a transversely applied uniform strong magnetic field in a rotating system is analyzed. The flow is driven by a common constant pressure gradient in a channel bounded by two parallel porous plates, one being stationary and the other oscillatory. The two fluids are assumed to be incompressible, electrically conducting with different viscosities and electrical conductivities. The governing partial differential equations are reduced to the linear ordinary differential equations using two-term series. The resulting equations are solved analytically to obtain exact solutions for the velocity distributions (primary and secondary in the two regions respectively, by assuming their solutions as a combination of both the steady state and time dependent components of the solutions. Numerical values of the velocity distributions are computed for different sets of values of the governing parameters involved in the study and their corresponding profiles are also plotted. The details of the flow characteristics and their dependence on the governing parameters involved, such as the Hartmann number, Taylor number, porous parameter, ratio of the viscosities, electrical conductivities and heights are discussed. Also an observation is made how the velocity distributions vary with the rotating hydromagnetic interaction in the case of steady and unsteady flow motions. The primary velocity distributions in the two regions are seen to decrease with an increase in the Taylor number, but an increase in the Taylor number causes a rise in secondary velocity distributions. It is found that an increase in the porous parameter decreases both the primary and secondary velocity distributions in the two regions.
Gu, Tae-Ha; Gunjakar, Jayavant L; Kim, In Young; Patil, Sharad B; Lee, Jang Mee; Jin, Xiaoyan; Lee, Nam-Suk; Hwang, Seong-Ju
2015-08-26
Mesoporous hybrid network of reduced graphene oxide (rG-O) and layered MnO(2) nanosheets could act as an efficient immobilization matrix for improving the electrochemical activity of layered double hydroxide (LDH). The control of MnO(2) /rG-O ratio is crucial in optimizing the porous structure and electrical conductivity of the resulting hybrid structure. The immobilization of Co-Al-LDH on hybrid MnO(2) /rG-O network is more effective in enhancing its electrode activity compared with that of on pure rG-O network. The Co-Al-LDH-rG-O-MnO(2) nanohybrid deliveres a greater specific capacitance than does MnO(2) -free Co-Al-LDH-rG-O nanohybrid. The beneficial effect of MnO(2) incorporation on the electrode performance of nanohybrid is more prominent for higher current density and faster scan rate, underscoring the significant enhancement of the electron transport of Co-Al-LDH-rG-O. This is supported by electrochemical impedance spectroscopy. The present study clearly demonstrates the usefulness of the porously assembled hybrid network of graphene and metal oxide nanosheets as an effective platform for exploring efficient LDH-based functional materials. PMID:25930158
Tzivadze, A. Yu.; Fridman, A. Ya.; Morozova, E. M.; Sokolova, N. P.; Voloshchuk, A. M.; Petukhova, G. A.; Bardishev, I. I.; Gorbunov, A. M.; Novikov, A. K.; Polyakova, I. Ya.; Titova, V. N.; Yavich, A. A.; Petrova, N. V.
2016-08-01
The synthesis of bilayer materials with porous upper layers composed of PVC hydroxyethylcyclam derivatives filled with carbon and a layer consisting of hydroxyethylcyclam, cross-linked via Si-O-C groups with the silica chains of a developed surface of asbestos fabric, is described. The aza-crown groups in these materials are bound with aqua complexes of H2SO4 or NaOH. The structure of the materials is examined, their adsorption characteristics are determined, and the rate of motion of H+ or OH- ions in electrochemical bridges is measured, while the formation of H2 and O2 in their cathodic and anodic polarization is determined as a function of voltage. It is shown that the upper layer of these materials is adsorption-active and electronand H+- or OH-- conductive, while the bottom layer is only H+- or OH-- conductive; through it, the upper layer is supplied with the H+ or OH- ions needed for the regeneration of the aqua complexes broken down to H2 and O2 on carbon particles.
Singh, M.
2015-12-01
The instability of plane interface between two superposed Rivlin-Ericksen elastico-viscous fluids saturated through a porous medium has been studied to include the suspended (dust) particles effect. Following the linearized stability theory and normal mode analysis the dispersion relation is obtained. For stationary convection, the Rivlin-Ericksen elastico-viscous fluid behaves like Newtonian fluids. It found that for a potentially stable arrangement the Rivlin-Ericksen elastico-viscous fluid of different permeabilities in the presence of suspended particles in a porous medium is stable, whereas in a potentially unstable case instability of the system occurs. In the presence of a magnetic field for a potentially stable arrangement the system is always stable and for the potentially unstable arrangement, the magnetic field succeeds in stabilizing certain wave-number band which was unstable in the absence of the magnetic field.
Directory of Open Access Journals (Sweden)
Singh M.
2015-12-01
Full Text Available The instability of plane interface between two superposed Rivlin-Ericksen elastico-viscous fluids saturated through a porous medium has been studied to include the suspended (dust particles effect. Following the linearized stability theory and normal mode analysis the dispersion relation is obtained. For stationary convection, the Rivlin-Ericksen elastico-viscous fluid behaves like Newtonian fluids. It found that for a potentially stable arrangement the Rivlin-Ericksen elastico-viscous fluid of different permeabilities in the presence of suspended particles in a porous medium is stable, whereas in a potentially unstable case instability of the system occurs. In the presence of a magnetic field for a potentially stable arrangement the system is always stable and for the potentially unstable arrangement, the magnetic field succeeds in stabilizing certain wave-number band which was unstable in the absence of the magnetic field.
Han, Jinpeng; Xu, Guiyin; Dou, Hui; MacFarlane, Douglas R
2015-02-01
This research presents a simple and efficient method to synthesize porous nitrogen-doped carbon microspheres (PNCM) by the carbonization of microporous poly(terephthalaldehyde-pyrrole) organic frameworks (PtpOF). The common KOH activation process is used to tune the porous texture of the PNCM and produce an activated-PNCM (A-PNCM). The PNCM and A-PNCM with specific surface area of 921 and 1303 m(2) g(-1) , respectively, are demonstrated as promising candidates for EDLCs. At a current density of 0.5 A g(-1) , the specific capacitances of the PNCM and A-PNCM are 248 and 282 F g(-1) , respectively. At the relatively high current density of 20 A g(-1) , the capacitance remaining is 95 and 154 F g(-1) , respectively. Capacity retention of the A-PNCM is more than 92% after 10000 charge/discharge cycles at a current density of 2 A g(-1) . PMID:25469994
Energy Technology Data Exchange (ETDEWEB)
Saravanan, P. [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Hsu, Jen-Hwa, E-mail: jhhsu@phys.ntu.edu.tw; Tsai, C. L. [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Tsai, C. Y.; Lin, Y. H. [Graduate Institute of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Kuo, C. Y.; Wu, J.-C. [Department of Physics, National Chang Hua University of Education, Chang Hua 50000, Taiwan (China); Lee, C.-M. [Graduate School of Materials Science, National Yunlin University of Science and Technology, Douliou 64002, Taiwan (China)
2014-06-28
Films of L1{sub 1}-type CoPt/NiFe exchange springs were grown with different NiFe (Permalloy) layer thickness (t{sub NiFe} = 0–10 nm). X-ray diffraction analysis reveals that the characteristic peak position of NiFe(111) is not affected by the CoPt-layer—confirming the absence of any inter-diffusion between the CoPt and NiFe layers. Magnetic studies indicate that the magnetization orientation of NiFe layer can be tuned through varying t{sub NiFe} and the perpendicular magnetic anisotropy of L1{sub 1}-type CoPt/NiFe films cannot sustain for t{sub NiFe} larger than 3.0 nm due to the existence of exchange interaction at the interface of L1{sub 1}-CoPt and NiFe layers. Magnetic force microscopy analysis on the as-grown samples shows the changes in morphology from maze-like domains with good contrast to hazy domains when t{sub NiFe} ≥ 3.0 nm. The three-dimensional micro-magnetic simulation results demonstrate that the magnetization orientation in NiFe layer is not uniform, which continuously increases from the interface to the top of NiFe layer. Furthermore, the tilt angle of the topmost NiFe layers can be changed over a very wide range from a small number to about 75° by varying t{sub NiFe} from 1 to 10 nm. It is worth noting that there is an abrupt change in the magnetization direction at the interface, for all the t{sub NiFe} investigated. The results of present study demonstrate that the tunable tilted exchange springs can be realized with L1{sub 1}-type CoPt/NiFe bilayers for future applications in three-axis magnetic sensors or advanced spintronic devices demanding inclined magnetic anisotropy.
Sadeghifar, Hamidreza; Djilali, Ned; Bahrami, Majid
2015-01-01
This paper reports on measurements of thermal conductivity of a graphite bipolar plate (BPP) as a function of temperature and its thermal contact resistance (TCR) with treated and untreated gas diffusion layers (GDLs). The thermal conductivity of the BPP decreases with temperature and its thermal contact resistance with GDLs, which has been overlooked in the literature, is found to be dominant over a relatively wide range of compression. The effects of PTFE loading, micro porous layer (MPL), compression, and BPP out-of-flatness are also investigated experimentally. It is found that high PTFE loadings, MPL and even small BPP out-of-flatness increase the BPP-GDL thermal contact resistance dramatically. The paper also presents the effect of cyclic load on the total resistance of a GDL-BPP assembly, which sheds light on the behavior of these materials under operating conditions in polymer electrolyte membrane fuel cells.
Institute of Scientific and Technical Information of China (English)
HU Yi-Fan; SUN Jia-Ning; Gidley D.W.
2005-01-01
@@ Two kinds of Cu diffusion barrier layers, sealedfilms and capped fi1ms, on nanoporous low-dielectric-constant filmsare investigated by positronium annihilation lifetime spectroscopy (PALS). We have found that the minimumthickness of Ta to form an effective diffusion barrier is affected by the pore size. The films with large poresrequire thick barrier layers to form effective diffusion barriers. In addition, a possible ultra-thin diffusion barrier,i.e. a plasma-induced densification layer, has also been investigated. The PALS data confirm that a porouslow-dielectric-constant thin film can be shrunk by exposure to plasma. This shrinkage is confined to a surfacelayer of collapsed pores and forms a dense layer. The dense layer tends to behave as Ps (positronium) diffusionbarriers. Indeed, the controlled thin "skin" layer could prevent Cu diffusion into the underlying dielectrics.
Anisotropic Transport Properties of Complex Metallic Alloys
Smontara, Ana; Dolinšek, Janez
2010-01-01
Anisotropic transport properties (electrical resistivity, ρ, and thermal conductivity, κ) of the Y-phase Al-Ni-Co, o-Al13Co4 and Al4(Cr,Fe) complex metallic alloys were investigated. They belong to the class of decagonal approximant phases with stacked-layer crystallographic structure and allowed us to study the evolution of anisotropic transport properties with increasing structural complexity and the unit cell size.
Indian Academy of Sciences (India)
Satish M Manocha
2003-02-01
Carbon in dense as well as porous solid form is used in a variety of applications. Activated porous carbons are made through pyrolysis and activation of carbonaceous natural as well as synthetic precursors. Pyrolysed woods replicate the structure of original wood but as such possess very low surface areas and poor adsorption capacities. On activation, these exhibit increased adsorption volumes of 0.5–0.8 cm3 /gm and surface areas of 700–1800 m2 /gm depending on activation conditions, whether physical or chemical. Former carbons possess mixed pore size distribution while chemically activated carbons predominantly possess micropores. Thus, these carbons can be used for adsorption of wide distributions of molecules from gas to liquid. The molecular adsorption within the pores is due to single layer or multilayer molecule deposition at the pore walls and hence results in different types of adsorption isotherm. On the other hand, activated carbon ﬁbres with controlled microporous structure and surface area in the range of 2500 m2 /gm can be developed by controlled pyrolysis and physical activation of amorphous carbon ﬁbres. Active carbon ﬁbres with unmatchable pore structure and surface characteristics are present and futuristic porous materials for a number of applications from pollution control to energy storage.
Cho, Kyu Taek; Mench, Matthew M
2012-03-28
In this study, the high resolution hydrogen-deuterium contrast radiography method was applied to elucidate the impact of the micro-porous layer (MPL) on water distribution in the porous fuel cell media. At the steady state, deuterium replaced hydrogen in the anode stream, and the large difference in neutron attenuation of the D(2)O produced at the cathode was used to track the produced water. It was found that the water content peaked in the cathode-side diffusion media (DM) for the cell without MPL, but with an MPL on the anode and cathode DM, the peak water amount was pushed toward the anode, resulting in a relatively flattened water profile through components and demonstrating a liquid barrier effect. Additionally, the dynamic water behavior in diffusion media was analyzed to understand the effect of a MPL and operating conditions. The water content in the DM changed with applied current, although there is a significant amount of residual liquid content that does not appear to be part of capillary channels. The effect of the MPL on irreducible saturation in DM and cell performance was also investigated. PMID:22337210
Directory of Open Access Journals (Sweden)
P. K. Singh
2012-06-01
Full Text Available This paper deals with the problem of a steady two dimensional boundary layer flow of an incompressible, viscous and electrically conducting fluid, with heat and mass transfer, past a moving vertical porous plate in the presence of uniform magnetic field applied normal to the plate, taking into account the effects of variable viscosity and viscous dissipation. The equations of motion, heat and mass transfer are transformed into a system of coupled ordinary differential equations in the non-dimensional form which are solved numerically. The effects of various parameters such as Prandtl number, Eckert number and Schmidt number on the velocity, temperature and concentration fields are discussed with the help of graphs.
Directory of Open Access Journals (Sweden)
Chamkha Ali
2011-01-01
Full Text Available Abstract A boundary layer analysis is presented for the mixed convection past a vertical wedge in a porous medium saturated with a nano fluid. The governing partial differential equations are transformed into a set of non-similar equations and solved numerically by an efficient, implicit, iterative, finite-difference method. A parametric study illustrating the influence of various physical parameters is performed. Numerical results for the velocity, temperature, and nanoparticles volume fraction profiles, as well as the friction factor, surface heat and mass transfer rates have been presented for parametric variations of the buoyancy ratio parameter Nr, Brownian motion parameter Nb, thermophoresis parameter Nt, and Lewis number Le. The dependency of the friction factor, surface heat transfer rate (Nusselt number, and mass transfer rate (Sherwood number on these parameters has been discussed.
Gorla, Rama Subba Reddy; Chamkha, Ali Jawad; Rashad, Ahmed Mohamed
2011-01-01
A boundary layer analysis is presented for the mixed convection past a vertical wedge in a porous medium saturated with a nano fluid. The governing partial differential equations are transformed into a set of non-similar equations and solved numerically by an efficient, implicit, iterative, finite-difference method. A parametric study illustrating the influence of various physical parameters is performed. Numerical results for the velocity, temperature, and nanoparticles volume fraction profiles, as well as the friction factor, surface heat and mass transfer rates have been presented for parametric variations of the buoyancy ratio parameter Nr, Brownian motion parameter Nb, thermophoresis parameter Nt, and Lewis number Le. The dependency of the friction factor, surface heat transfer rate (Nusselt number), and mass transfer rate (Sherwood number) on these parameters has been discussed.
Tsubota, Toshiki; Maguchi, Yuta; Kamimura, Sunao; Ohno, Teruhisa; Yasuoka, Takehiro; Nishida, Haruo
2015-12-01
The combination of addition of Fe (as a catalyst for graphitization) and CO2 activation (a kind of gaseous activation) was applied to prepare a porous carbon material from bamboo powder (a waste product of superheated steam treatment). Regardless of the heat treatment temperature, many macropores were successfully formed after the heating process by removal of Fe compounds. A turbostratic carbon structure was generated in the Fe-added sample heated at 850°C. It was confirmed that the added Fe acted as a template for pore formation. Moreover, it was confirmed that the added Fe acted as a catalyst for graphitization. The resulting electrochemical performance as the electrode of an electrical double-layer capacitor, as demonstrated by cyclic voltammetry, electrochemical impedance spectroscopy, and charge-discharge testing, could be explained based on the graphitization and activation effects. Addition of Fe could affect the electrical properties of carbon material derived from bamboo.
Directory of Open Access Journals (Sweden)
Rashidi Mohammad Mehdi
2015-01-01
Full Text Available The similar solution on the equations of the revised Cheng-Minkowycz problem for natural convective boundary layer flow of nanofluid through a porous medium gives (using an analytical method, a system of non-linear partial differential equations which are solved by optimal homotopy analysis method. Effects of various drastic parameters on the fluid and heat transfer characteristics have been analyzed. A very good agreement is observed between the obtained results and the numerical ones. The entropy generation has been derived and a comprehensive parametric analysis on that has been done. Each component of the entropy generation has been analyzed separately and the contribution of each one on the total value of entropy generation has been determined. It is found that the entropy generation as an important aspect of the industrial applications has been affected by various parameters which should be controlled to minimize the entropy generation.
Directory of Open Access Journals (Sweden)
Md.Jashim Uddin
2015-10-01
Full Text Available The combined effects of viscous dissipation and slip effect on the momentum and thermal transport for the unsteady boundary layer flow over porous plate have been carried out. We have applied free parameter method to solve governing partial differential equations. The governing non-linear partial differential equations are transformed into a system of coupled non-linear ordinary differential equations using similarity transformations and then solved numerically using the Runge–Kutta method with shooting technique for better accuracy. The flow and temperature fields as well as the free convective parameter and heat transfer coefficient are determined and displayed graphically involved in the similarity transformation. Effects of the slip parameter, free convection parameter, Prandtl number and unsteadiness parameter on the flow and heat transfer are examined and analyzed
Lin, Yanhai; Zheng, Liancun; Zhang, Xinxin
2015-11-01
We present a research for the MHD Marangoni boundary layer flow and heat transfer in pseudo-plastic power law nanofluids over a porous medium driven by temperature gradient. A variable magnetic field is considered. Four different types of nanoparticles, copper, aluminum oxide, copper oxide, and titanium oxide are considered with pseudo-plastic power-law carboxy methyl cellulose (CMC)-water used as base fluids. A generalized Fourier law proposed by Zheng for varying thermal conductivity of nanofluids is taken into account, and the surface tension is assumed a quadratic function of the temperature. The governing partial differential equations (PDEs) are formulated, and similarity solutions are obtained numerically using shooting technique combined with Runge-Kutta iteration program and Newton's scheme. The effects of various physical parameters on horizontal velocity component and temperature curves are discussed and graphically illustrated in details.
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Kuen-Hsien Wu
2014-01-01
Full Text Available This paper demonstrated the fabrication and optoelectronic characteristics of ZnO ultraviolet (UV photodetectors fabricated on Si substrates with oxidized nano-porous-Si (ONPS buffer layers. ONPS layers were prepared on the surfaces of Si substrates by use of an electrochemical anodization technique following a rapid-thermal-oxidation process. Experimental results indicated that application of ONPS buffer layers not only improved the crystallinty of the deposited ZnO thin films but also greatly restricted the visible-to-infrared photoresponse that was generated from the light absorption of Si substrates. The developed ZnO-on-ONPS photodiodes achieved high photoresponsivity for the incident UV light of 300 ∼ 400 nm and got a large photo-to-dark current ratio up to 104 at wavelength of 375 nm under a bias of 5 V. Therefore, ZnO on ONPS provides a highly potential approach for the development of low-cost visible-blind UV photodetectors.
Prass, Sebastian; Hasanpour, Sadegh; Sow, Pradeep Kumar; Phillion, André B.; Mérida, Walter
2016-07-01
The interfacial morphology between the catalyst layer (CL) and micro porous layer (MPL) influences the performance of proton exchange membrane fuel cells (PEMFCs). Here we report a direct method to investigate the CL-MPL interfacial morphology of stacked and compressed gas diffusion layer (GDL with MPL)-catalyst coated membrane (CCM) assemblies. The area, origin and dimensions of interfacial gaps are studied with high-resolution X-ray micro computed tomography (X-μCT). The projected gap area (fraction of the CL-MPL interface separated by gaps) is higher for GDL-CCM assemblies with large differences in the surface roughness between CL and MPL but reduces with increasing compression and similarity in roughness. Relatively large continuous gaps are found in proximity to cracks in the MPL. These are hypothesized to form due to the presence of large pores on the surface of the GDL. Smaller gaps are induced by the surface roughness features throughout the CL-MPL interface. By modification of the pore sizes on the GDL surface serving as substrate for the MPL, the number and dimension of MPL crack induced gaps can be manipulated. Moreover, adjusting the CL and MPL surface roughness parameters to achieve similar orders of roughness can improve the surface mating characteristics of these two components.
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Aniedi Nyong
2014-02-01
Full Text Available The underwater contact angle behavior on oxide layers of varying thicknesses was studied. These oxide layers were grown by thermally oxidizing C84400 copper alloys in N2-0.75 wt.% O2 and N2-5 wt.% O2 gas mixtures at 650 °C. Characterization of the oxidized specimens was effected using X-ray diffraction, scanning electron microscope (SEM and contact angle goniometer. The results from the X-ray diffraction analyses confirmed the formation of CuO, ZnO and PbO. The average sizes of the oxide granules were in the range of 70 nm to 750 nm, with the average thickness of the oxide layer increasing with the increase in the weight percent of oxygen in the N2-O2 gas mixtures. The results showed that the oxide layer growth followed the parabolic law. The underwater oil contact angles increased, due to the change in the surface morphology and porosity of the oxide layer. The small sizes and irregular packing of the oxide granules cause hierarchical rough surface layers with pores. The estimated pore sizes, in the range of 88 ± 40 to 280 ± 76, were predominant on the oxide layers of the samples processed in the N2-5 wt.% O2 gas mixture. The presence of these pores caused an increase in the porosities as the thickness of the oxide layers increased. At oxide layer thickness above 25 microns, the measured contact angle exceeded 150° as underwater superoleophobicity was recorded.
van Kats, C. M.
2008-10-01
The driving forces for fundamental research in colloid science are the ability to manage the material properties of colloids and to unravel the forces that play a role between colloids to be able to control and understand the processes where colloids play an important role. Therefore we are searching for colloidal materials with specific physical properties to better understand our surrounding world.Until recently research in colloid science was mainly focused on spherical (isotropic) particles. Monodisperse spherical colloids serve as a model system as they exhibit similar phase behaviour as molecular and atomic systems. Nevertheless, in many cases the spherical shape is not sufficient to reach the desired research goals. Recently the more complex synthesis methods of anisotropic model colloids has strongly developed. This thesis should be regarded as a contribution to this research area. Anisotropic colloids can be used as a building block for complex structures and are expected not only to lead to the construction of full photonic band gap materials. They will also serve as new, more realistic, models systems for their molecular analogues. Therefore the term ‘molecular colloids” is sometimes used to qualify these anisotropic colloidal particles. In the introduction of this thesis, we give an overview of the main synthesis techniques for anisotropic colloids. Chapter 2 describes the method of etching silicon wafers to construct monodisperse silicon rods. They subsequently were oxidized and labeled (coated) with a fluorescent silica layer. The first explorative phase behaviour of these silica rods was studied. The particles showed a nematic ordering in charge stabilized suspensions. Chapter 3 describes the synthesis of colloidal gold rods and the (mesoporous) silica coating of gold rods. Chapter 4 describes the physical and optical properties of these particles when thermal energy is added. This is compared to the case where the particles are irradiated with
DEFF Research Database (Denmark)
Ni, De Wei; Schmidt, Cristine Grings; Teocoli, Francesca;
2013-01-01
The sintering behavior of porous Ce0.9Gd0.1O1.95(CGO10) tape cast layers was systematically investigated to establish fundamental kinetic parameters associated to densification and grain growth. Densification and grain growth were characterized by a set of different methods to determine the domin...
Badel, Pierre; Lessner, Susan; Sutton, Michael A; 10.1080/10255842.2011.586945
2012-01-01
The role of mechanics is known to be of primary order in many arterial diseases; however, determining mechanical properties of arteries remains a challenge. This paper discusses the identifiability of the passive mechanical properties of a mouse carotid artery, taking into account the orientation of collagen fibres in the medial and adventitial layers. On the basis of 3D digital image correlation measurements of the surface strain during an inflation/extension test, an inverse identification method is set up. It involves a 3D finite element mechanical model of the mechanical test and an optimisation algorithm. A two-layer constitutive model derived from the Holzapfel model is used, with five and then seven parameters. The five-parameter model is successfully identified providing layer-specific fibre angles. The seven-parameter model is over parameterised, yet it is shown that additional data from a simple tension test make the identification of refined layer-specific data reliable.
Energy Technology Data Exchange (ETDEWEB)
Tsuo, Y.S.; Menna, P.; Al-Jassim, M. [National Renewable Energy Lab., Golden, CO (United States)] [and others
1995-08-01
We have studied a novel extrinsic gettering method that utilizes the very large surface areas, produced by porous silicon etch on both front and back surfaces of the silicon wafer, as gettering sites. In this method, a simple and low-cost chemical etching is used to generate the porous silicon layers. Then, a high-flux solar furnace (HFSF) is used to provide high-temperature annealing and the required injection of silicon interstitials. The gettering sites, along with the gettered impurities, can be easily removed at the end the process. The porous silicon removal process consists of oxidizing the porous silicon near the end the gettering process followed by sample immersion in HF acid. Each porous silicon gettering process removes up to about 10 {mu}m of wafer thickness. This gettering process can be repeated so that the desired purity level is obtained.
Kim, Byoungsu; Hillman, Febrian; Ariyoshi, Miho; Fujikawa, Shigenori; Kenis, Paul J. A.
2016-04-01
With the development of better catalysts, mass transport limitations are becoming a challenge to high throughput electrochemical reduction of CO2 to CO. In contrast to optimization of electrodes for fuel cells, optimization of gas diffusion electrodes (GDE) - consisting of a carbon fiber substrate (CFS), a micro porous layer (MPL), and a catalyst layer (CL) - for CO2 reduction has not received a lot of attention. Here, we studied the effect of the MPL and CFS composition on cathode performance in electroreduction of CO2 to CO. In a flow reactor, optimized GDEs exhibited a higher partial current density for CO production than Sigracet 35BC, a commercially available GDE. By performing electrochemical impedance spectroscopy in a CO2 flow reactor we determined that a loading of 20 wt% PTFE in the MPL resulted in the best performance. We also investigated the influence of the thickness and wet proof level of CFS with two different feeds, 100% CO2 and the mixture of 50% CO2 and N2, determining that thinner and lower wet proofing of the CFS yields better cathode performance than when using a thicker and higher wet proof level of CFS.
Directory of Open Access Journals (Sweden)
M. H.M. Yasin
2013-01-01
Full Text Available An analysis of the steady mixed convection boundary layer flow past a vertical permeable surface embedded in a porous medium saturated by a nanofluid is performed in this study. Numerical solutions of the similarity equations are obtained using the shooting method. Three types of metallic or nonmetallic nanoparticles, namely Copper (Cu, Alumina (Al2O3 and Titania (TiO2 are considered by using a water-based fluid to investigate the effect of the solid volume fraction or nanoparticle volume fraction parameter ï Ï of the nanofluid. The numerical results of the skin friction coefficient and the velocity profiles are presented and discussed. It is found that the imposition of suction is to increase the velocity profiles and to delay the separation of boundary layer, while the injection parameter decreases the velocity profiles. On the other hand, the range of solutions for the injection case is largest for Al2O3 nanoparticles and smallest for Cu nanoparticles.
Indian Academy of Sciences (India)
M Tajuddin; G Narayan Reddy
2005-08-01
A transcendental equation is derived relating wave number and phase velocity of propagation of waves in a partially saturated layered half-space under plane strain conditions. The period equation is derived and discussed for two types of boundaries, permeable and impermeable. In the limiting cases, the problem reduces to more simpliﬁed forms as discussed by earlier researchers.
Inoue, Gen; Kawase, Motoaki
2016-09-01
It is important to reduce the oxygen diffusion resistance through PEFC porous electrode, because it is the key to reduce the PEFC cost. However, the gas diffusion coefficient of CL is lower than MPL in spite of framework consisted of same carbon blacks. In this study, in order to understand the reasons of the lower gas diffusion performance of CL, the relationship between a carbon black agglomerate structure and ionomer adhesion condition is evaluated by a numerical analysis with an actual reconstructed structure and a simulated structure. As a result, the gas diffusion property of CL strongly depends on the ionomer adhesion shape. In the case of adhesion shape with the same curvature of ionomer interface, each pore can not be connected enough. So the pore tortuosity increases. Moreover, in the case of existence of inefficient large pores formed by carbon black agglomerate and ununiformly coated ionomer, the gas diffusion performance decrease rapidly. As the measurement values in actual CL are almost equal to that with model structure with inefficient large pores. These characteristics can be confirmed by actual cross-section image obtained by FIB-SEM.
Fabricating porous silicon carbide
Shor, Joseph S. (Inventor); Kurtz, Anthony D. (Inventor)
1994-01-01
The formation of porous SiC occurs under electrochemical anodization. A sample of SiC is contacted electrically with nickel and placed into an electrochemical cell which cell includes a counter electrode and a reference electrode. The sample is encapsulated so that only a bare semiconductor surface is exposed. The electrochemical cell is filled with an HF electrolyte which dissolves the SiC electrochemically. A potential is applied to the semiconductor and UV light illuminates the surface of the semiconductor. By controlling the light intensity, the potential and the doping level, a porous layer is formed in the semiconductor and thus one produces porous SiC.
Kim, Myeongjin; Oh, Ilgeun; Kim, Jooheon
2015-07-01
Controlling the structure and morphology of porous electrode materials is an effective strategy for realizing a high surface area and efficient paths for ion diffusion. Moreover, excellent electrical conductivity can significantly decrease the internal resistance of an electrode by the formation of a conductive network and facilitate the application of electrostatic charges, which favors the accumulation of an electrical double layer. In light of these facts, we demonstrate the fabrication of β-polytype porous silicon carbide spheres (PSiCS) with a hierarchical pore structure in which micro- and mesopores are interconnected with a mesoporous network. Further, to investigate the effects of the electrolyte on the electrochemical and dynamic behavior, two-electrode symmetrical supercapacitors based on the PSiCS electrode with an aqueous electrolyte (1 M potassium chloride, KCl) or an organic electrolyte (1 M tetraethylammonium tetrafluoroborate in acetonitrile, TEABF4/AN) were assembled. The symmetrical supercapacitor based on the PSiCS electrode with the aqueous electrolyte exhibited a high charge-storage capacity with a specific capacitance of 82.9 F g(-1) at a scan rate of 5 mV s(-1), which is much higher than that obtained using the organic electrolyte (60.3 F g(-1) at a scan rate of 5 mV s(-1)). However, the energy density of the organic electrolyte system was 102.59 W h kg(-1) at a scan rate of 5 mV s(-1), which is greatly superior to that of the aqueous electrolyte system (energy density: 29.47 W h kg(-1)) owing to the wide cell operating voltage range. PMID:26051533
Ferdows, M.
2012-01-01
Magnetohydrodynamic (MHD) boundary layer flow of a nanofluid over an exponentially stretching sheet was studied. The governing boundary layer equations are reduced into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using the Nactsheim-Swigert shooting technique together with Runge-Kutta six-order iteration schemes. The effects of the governing parameters on the flow field and heat transfer characteristics were obtained and discussed. The numerical solutions for the wall skin friction coefficient, the heat and mass transfer coefficient, and the velocity, temperature, and concentration profiles are computed, analyzed, and discussed graphically. Comparison with previously published work is performed and excellent agreement is observed. 2012 M. Ferdows et al.
Directory of Open Access Journals (Sweden)
M. Ferdows
2012-01-01
Full Text Available Magnetohydrodynamic (MHD boundary layer flow of a nanofluid over an exponentially stretching sheet was studied. The governing boundary layer equations are reduced into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using the Nactsheim-Swigert shooting technique together with Runge-Kutta six-order iteration schemes. The effects of the governing parameters on the flow field and heat transfer characteristics were obtained and discussed. The numerical solutions for the wall skin friction coefficient, the heat and mass transfer coefficient, and the velocity, temperature, and concentration profiles are computed, analyzed, and discussed graphically. Comparison with previously published work is performed and excellent agreement is observed.
Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer
Guarnera, Simone
2015-02-05
© 2015 American Chemical Society. Hybrid perovskites represent a new paradigm for photovoltaics, which have the potential to overcome the performance limits of current technologies and achieve low cost and high versatility. However, an efficiency drop is often observed within the first few hundred hours of device operation, which could become an important issue. Here, we demonstrate that the electrode\\'s metal migrating through the hole transporting material (HTM) layer and eventually contacting the perovskite is in part responsible for this early device degradation. We show that depositing the HTM within an insulating mesoporous "buffer layer" comprised of Al2O3 nanoparticles prevents the metal electrode migration while allowing for precise control of the HTM thickness. This enables an improvement in the solar cell fill factor and prevents degradation of the device after 350 h of operation. (Graph Presented).
He, Jin; He, Feng-Li; Li, Da-Wei; Liu, Ya-Li; Yin, Da-Chuan
2016-06-01
A novel porous Fe/Fe-W alloy scaffold with a double-layer structured skeleton was prepared for the first time by electrodeposition. The microstructure of the scaffold was analysed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and mercury porosimetry. Mechanical property, in vitro degradability and biocompatibility were tested by tensile test, immersion and a cytotoxicity test. The results showed that the scaffolds exhibited a cellular structure that is similar to that of cancellous bone and had a considerably large specific surface area. The skeleton of the scaffolds showed a double-layer structure that was composed of a hollow Fe skeleton wrapped in a thin layer of Fe-W alloy. The tensile strength and the apparent density are close to that of cancellous bone. It was also found that the different surface microstructures showed different effects on in vitro degradability and biocompatibility. In the immersion test, the corrosion rate decreased gradually as the immersion time increased. In the cytotoxicity test, the extraction medium of the pure Fe scaffold showed the lowest cell viability, followed by that of 1.5FeW as a close second. The extraction media of FeW, Fe1.5W and Fe2W were similar, and their cell viability was far above that of the Fe and 1.5FeW scaffolds. The structural style of the scaffolds presented in this paper is potentially useful and applicable to developing degradable scaffolds with a tailored corrosion rate. PMID:26970820
Ke, Xinyou; Alexander, J Iwan D; Savinell, Robert F
2016-01-01
In this work, a two-dimensional mathematical model is developed to study the flow patterns and volumetric flow penetrations in the flow channel over the porous electrode layered system in vanadium flow battery with serpentine flow field design. The flow distributions at the interface between the flow channel and porous electrode are examined. It is found that the non-linear pressure distributions can distinguish the interface flow distributions under the ideal plug flow and ideal parabolic flow inlet boundary conditions. However, the volumetric flow penetration within the porous electrode beneath the flow channel through the integration of interface flow velocity reveals that this value is identical under both ideal plug flow and ideal parabolic flow inlet boundary conditions. The volumetric flow penetrations under the advection effects of flow channel and landing/rib are estimated. The maximum current density achieved in the flow battery can be predicted based on the 100% amount of electrolyte flow reactant ...
Yoon, Hongkyu; Oostrom, Mart; Wietsma, Thomas W; Werth, Charles J; Valocchi, Albert J
2009-10-13
The purpose of this work is to identify the mechanisms that govern the removal of carbon tetrachloride (CT) during soil vapor extraction (SVE) by comparing numerical and analytical model simulations with a detailed data set from a well-defined intermediate-scale flow cell experiment. The flow cell was packed with a fine-grained sand layer embedded in a coarse-grained sand matrix. A total of 499 mL CT was injected at the top of the flow cell and allowed to redistribute in the variably saturated system. A dual-energy gamma radiation system was used to determine the initial NAPL saturation profile in the fine-grained sand layer. Gas concentrations at the outlet of the flow cell and 15 sampling ports inside the flow cell were measured during subsequent CT removal using SVE. Results show that CT mass was removed quickly in coarse-grained sand, followed by a slow removal from the fine-grained sand layer. Consequently, effluent gas concentrations decreased quickly at first, and then started to decrease gradually, resulting in long-term tailing. The long-term tailing was mainly due to diffusion from the fine-grained sand layer to the coarse-grained sand zone. An analytical solution for a one-dimensional advection and a first-order mass transfer model matched the tailing well with two fitting parameters. Given detailed knowledge of the permeability field and initial CT distribution, we were also able to predict the effluent concentration tailing and gas concentration profiles at sampling ports using a numerical simulator assuming equilibrium CT evaporation. The numerical model predictions were accurate within the uncertainty of independently measured or literature derived parameters. This study demonstrates that proper numerical modeling of CT removal through SVE can be achieved using equilibrium evaporation of NAPL if detailed fine-scale knowledge of the CT distribution and physical heterogeneity is incorporated into the model. However, CT removal could also be fit by a
Institute of Scientific and Technical Information of China (English)
Maciej Zalas; Mariusz Walkowiak; Grzegorz Schroeder
2011-01-01
Modified with gadolinium-containing layer,nanoporous titania electrode and its application in dye-sensitized solar cells were reported.The electrode prepared was characterized with UV-Vis and X-ray diffraction (XRD) techniques.The amount of gadolinium was measured with inductively coupled plasma-optical emission spectrometry (ICP-OES) experiments.The modified electrode showed reduced N3 dye adsorption ability,but increased light conversion efficiency in comparison with the non-modified electrode.The overall conversion efficiencies,determined under 400 W/m2 irradiation with tungsten- halogen lamp at room temperature,were 0.55％ for non-modified and 0.74％ for modified electrodes.
Energy Technology Data Exchange (ETDEWEB)
Park, Jun-Young [Department of Advanced Materials Engineering, Sejong University, 98 Gunja-dong, Gwangjin-gu, Seoul 143-747 (Korea); Kim, Hee-Tak; Son, In-Hyuk; Han, Sangil [Energy Lab, Corporate R and D Center, Samsung SDI Co., LTD, 575, Shin-dong, Yeongtong-gu, Suwon-si, Gyeonggi-do 443-391 (Korea); Lee, Eun Sook [Energy Research Center, Jinwoo Engineering, Co., LTD., 143-2, Gwelang-Ri, Jungnam-Myun, Hwasung-City, Kyunggi-Do 445-963 (Korea)
2009-10-15
The effect of cathode gas diffusion media with microporous layers (MPLs) on direct methanol fuel cell (DMFC) performances is studied by combining electrochemical analysis and physicochemical investigation. The membrane electrode assemblies (MEAs) using MPL-modified cathode gas diffusion layers (GDLs, GDL-1) showed slightly better performances (117 mW cm{sup -2}) at 0.4 V and 70 C than commercial GDL (SIGRACET {sup registered} product version: GDL-35BC, SGL Co.) DMFC MEAs (110 mW cm{sup -2}). This might be due to high gas permeability, uniform pore distributions, and low water transport coefficient including methanol crossover. For GDL-1, the air permeability was 31.0 cm{sup 3} cm{sup -2} s{sup -1}, while the one for SGL 35BC GDLs was 21.7 cm{sup 3} cm{sup -2} s{sup -1}. Also, the GDL-1 in the pore-size distribution diagrams had distinct peaks due to more uniform distributions of macropores and micropores with smaller holes between aggregates of carbon particles compared to GDL-35 BC as confirmed by SEM images. Furthermore, the MEA using GDL-1 for the cathode had a lower water transfer coefficient compared to an MEA with a commercial 35 BC GDL. (author)
Scaffaro, R; Lopresti, F; Botta, L; Rigogliuso, S; Ghersi, G
2016-02-01
Interface tissue engineering (ITE) is used to repair or regenerate interface living tissue such as for instance bone and cartilage. This kind of tissues present natural different properties from a biological and mechanical point of view. With the aim to imitating the natural gradient occurring in the bone-cartilage tissue, several technologies and methods have been proposed over recent years in order to develop polymeric functionally graded scaffolds (FGS). In this study three-layered scaffolds with a pore size gradient were developed by melt mixing polylactic acid (PLA) and two water-soluble porogen agents: sodium chloride (NaCl) and polyethylene glycol (PEG). Pore dimensions were controlled by NaCl granulometry while PEG solvation created a micropores network within the devices. Scaffolds were characterized from a morphological and mechanical point of view in order to find a correlation between the preparation method, the pore architecture and compressive mechanical behavior. Biological tests were also performed in order to study the effect of pore size gradient on the permeation of different cell lines in co-culture. To imitate the physiological work condition, compressive tests were also performed in phosphate buffered saline (PBS) solution at 37°C. The presented preparation method permitted to prepare three-layered scaffolds with high control of porosity and pore size distribution. Furthermore mechanical behaviors were found to be strongly affected by pore architecture of tested devices as well as the permeation of osteoblast and fibroblast in-vitro.
Scaffaro, R; Lopresti, F; Botta, L; Rigogliuso, S; Ghersi, G
2016-02-01
Interface tissue engineering (ITE) is used to repair or regenerate interface living tissue such as for instance bone and cartilage. This kind of tissues present natural different properties from a biological and mechanical point of view. With the aim to imitating the natural gradient occurring in the bone-cartilage tissue, several technologies and methods have been proposed over recent years in order to develop polymeric functionally graded scaffolds (FGS). In this study three-layered scaffolds with a pore size gradient were developed by melt mixing polylactic acid (PLA) and two water-soluble porogen agents: sodium chloride (NaCl) and polyethylene glycol (PEG). Pore dimensions were controlled by NaCl granulometry while PEG solvation created a micropores network within the devices. Scaffolds were characterized from a morphological and mechanical point of view in order to find a correlation between the preparation method, the pore architecture and compressive mechanical behavior. Biological tests were also performed in order to study the effect of pore size gradient on the permeation of different cell lines in co-culture. To imitate the physiological work condition, compressive tests were also performed in phosphate buffered saline (PBS) solution at 37°C. The presented preparation method permitted to prepare three-layered scaffolds with high control of porosity and pore size distribution. Furthermore mechanical behaviors were found to be strongly affected by pore architecture of tested devices as well as the permeation of osteoblast and fibroblast in-vitro. PMID:26410761
Lorchat, Etienne; Froehlicher, Guillaume; Berciaud, Stéphane
2016-02-23
We investigate the interlayer phonon modes in N-layer rhenium diselenide (ReSe2) and rhenium disulfide (ReS2) by means of ultralow-frequency micro-Raman spectroscopy. These transition metal dichalcogenides exhibit a stable distorted octahedral (1T') phase with significant in-plane anisotropy, leading to sizable splitting of the (in-plane) layer shear modes. The fan-diagrams associated with the measured frequencies of the interlayer shear modes and the (out-of-plane) interlayer breathing modes are perfectly described by a finite linear chain model and allow the determination of the interlayer force constants. Nearly identical values are found for ReSe2 and ReS2. The latter are appreciably smaller than but on the same order of magnitude as the interlayer force constants reported in graphite and in trigonal prismatic (2Hc) transition metal dichalcogenides (such as MoS2, MoSe2, MoTe2, WS2, WSe2), demonstrating the importance of van der Waals interactions in N-layer ReSe2 and ReS2. In-plane anisotropy results in a complex angular dependence of the intensity of all Raman modes, which can be empirically utilized to determine the crystal orientation. However, we also demonstrate that the angular dependence of the Raman response drastically depends on the incoming photon energy, shedding light on the importance of resonant exciton-phonon coupling in ReSe2 and ReS2. PMID:26820232
Experimental Evidence of Helical Flow in Porous Media
DEFF Research Database (Denmark)
Ye, Yu; Chiogna, Gabriele; Cirpka, Olaf A.;
2015-01-01
Helical flow leads to deformation of solute plumes and enhances transverse mixing in porous media. We present experiments in which macroscopic helical flow is created by arranging different materials to obtain an anisotropic macroscopic permeability tensor with spatially variable orientation. The...... mixers, but in porous media....
Andisheh-Tadbir, Mehdi; Orfino, Francesco P.; Kjeang, Erik
2016-04-01
Modern hydrogen powered polymer electrolyte fuel cells (PEFCs) utilize a micro-porous layer (MPL) consisting of carbon nanoparticles and polytetrafluoroethylene (PTFE) to enhance the transport phenomena and performance while reducing cost. However, the underlying mechanisms are not yet completely understood due to a lack of information about the detailed MPL structure and properties. In the present work, the 3D phase segregated nanostructure of an MPL is revealed for the first time through the development of a customized, non-destructive procedure for monochromatic nano-scale X-ray computed tomography visualization. Utilizing this technique, it is discovered that PTFE is situated in conglomerated regions distributed randomly within connected domains of carbon particles; hence, it is concluded that PTFE acts as a binder for the carbon particles and provides structural support for the MPL. Exposed PTFE surfaces are also observed that will aid the desired hydrophobicity of the material. Additionally, the present approach uniquely enables phase segregated calculation of effective transport properties, as reported herein, which is particularly important for accurate estimation of electrical and thermal conductivity. Overall, the new imaging technique and associated findings may contribute to further performance improvements and cost reduction in support of fuel cell commercialization for clean energy applications.
Kazarian, Artaches A; Sanz Rodriguez, Estrella; Deverell, Jeremy A; McCord, James; Muddiman, David C; Paull, Brett
2016-01-28
Wall modified photonic crystal fibre capillary columns for in-capillary micro-extraction and liquid chromatographic separations is presented. Columns contained 126 internal parallel 4 μm channels, each containing a wall bonded porous monolithic type polystyrene-divinylbenzene layer in open tubular column format (PLOT). Modification longitudinal homogeneity was monitored using scanning contactless conductivity detection and scanning electron microscopy. The multichannel open tubular capillary column showed channel diameter and polymer layer consistency of 4.2 ± 0.1 μm and 0.26 ± 0.02 μm respectively, and modification of 100% of the parallel channels with the monolithic polymer. The modified multi-channel capillaries were applied to the in-capillary micro-extraction of water samples. 500 μL of water samples containing single μg L(-1) levels of polyaromatic hydrocarbons were extracted at a flow rate of 10 μL min(-1), and eluted in 50 μL of acetonitrile for analysis using HPLC with fluorescence detection. HPLC LODs were 0.08, 0.02 and 0.05 μg L(-1) for acenaphthene, anthracene and pyrene, respectively, with extraction recoveries of between 77 and 103%. The modified capillaries were also investigated briefly for direct application to liquid chromatographic separations, with the retention and elution of a standard protein (cytochrome c) under isocratic conditions demonstrated, proving chromatographic potential of the new column format, with run-to-run retention time reproducibility of below 1%.
Chiogna, Gabriele; Herrera, Paulo
2015-04-01
Several studies have demonstrated how plume deformation induced by flow heterogeneity in porous media can enhance mixing of reactants. This enhancement can have important impact on mixing controlled reactions such a biodegradation of plumes of organic compounds. On the other hand, recent studies have indicated the possibility of observing complex flow topology on groundwater flow that occurs in anisotropic yet homogenous porous media. Moreover, it has been demonstrated that those complex flow topologies can also enhance solute mixing. We study the effect of medium anisotropy on reactive solute transport for the case of a chemical reactor composed of two homogeneous anisotropic layers. We simulate different injection strategies for different chemical reactions that involve two reactants. We demonstrate the effect of the medium anisotropy by analyzing the results of the simulations and identify best strategies for the operation and design of the system to maximize reaction rates. These findings could have potential application in the design of new remediation systems for contaminated groundwater, chemical reactors and other engineering problems that involve flow through porous media.
Tunneling anisotropic magnetoresistance in organic spin valves
Grünewald, M; M. Wahler; Schumann, F; Michelfeit, M.; Gould, C.; Schmidt, R.; Würthner, F.; Schmidt, G.; Molenkamp, L. W.
2011-01-01
We report the observation of tunneling anisotropic magnetoresistance (TAMR) in an organic spin-valve-like structure with only one ferromagnetic electrode. The device is based on a new high mobility perylene diimide-based n-type organic semiconductor. The effect originates from the tunneling injection from the LSMO contact and can thus occur even for organic layers which are too thick to support the assumption of tunneling through the layer. Magnetoresistance measurements show a clear spin-val...
Anisotropic Stars II Stability
Dev, K; Dev, Krsna; Gleiser, Marcelo
2003-01-01
We investigate the stability of self-gravitating spherically symmetric anisotropic spheres under radial perturbations. We consider both the Newtonian and the full general-relativistic perturbation treatment. In the general-relativistic case, we extend the variational formalism for spheres with isotropic pressure developed by Chandrasekhar. We find that, in general, when the tangential pressure is greater than the radial pressure, the stability of the anisotropic sphere is enhanced when compared to isotropic configurations. In particular, anisotropic spheres are found to be stable for smaller values of the adiabatic index $\\gamma$.
Q-factor and absorption enhancement for plasmonic anisotropic nanoparticles
Liu, Wei; Miroshnichenko, Andrey E
2016-01-01
We investigate the scattering and absorption properties of anisotropic metal-dielectric core-shell nanoparticles. It is revealed that the radially anisotropic dielectric layer can accelerate the evanescent decay of the localized resonant surface modes, leading to Q-factor and absorption rate enhancement. Moreover, the absorption cross section can be maximized to reach the single resonance absorption limit. We further show that such artificial anisotropic cladding materials can be realized by isotropic layered structures, which may inspire many applications based on scattering and absorption of plasmonic nanoparticles.
Design of anisotropic reflector with birefringent thin films
Institute of Scientific and Technical Information of China (English)
Jianguo Wang; Kui Yi; Jianda Shao; Zhengxiu Fan
2005-01-01
A novel design for dielectric anisotropic mirrors with birefringent thin films for normal incidence is presented. This mirror consists of a stack of quarter-wave biaxial layers. The biaxial anisotropic layers can be fabricated by oblique deposition. The reflectance is different for two linear polarizations of light incidence on the mirrors. As a numerical example, the design is carried out on glass with TiO2 and ZrO2. These thin films could be applied to anisotropic reflective devices for lasers.
Thermal conductivities of sub-micron Bi2Te3 films sputtered on anisotropic substrates
Yan, Dan; Wu, Ping; Zhang, Shiping; Pei, Yili; Yang, Fan; Wang, Li
2016-07-01
Approximately 450 nm thick Bi2Te3 films were deposited on flat Al2O3 substrate and nanochannel alumina (NCA) templates with different pore diameters through radio-frequency magnetron sputtering. The structure and morphology of Bi2Te3 films were investigated by x-ray diffraction and field-emission scanning electron microscopy. Moreover, the thermal conductivities of the films deposited on anisotropic substrates were evaluated by micro-Raman method combined with numerical simulation and optimization conducted by COMSOL Multiphysics. The thermal conductivities of Bi2Te3 films deposited on NCA templates with discontinuous Φ20 and Φ100 nm pores and flat Al2O3 substrate were 0.80, 0.99 and 1.54 Wm‑1 K‑1, respectively. The lower thermal conductivities of Bi2Te3 films deposited on NCA templates are attributed to much smaller grain size, bottom porous layers, and rougher surfaces through analysis.
Anisotropic Contrast Optical Microscope
Peev, D; Kananizadeh, N; Wimer, S; Rodenhausen, K B; Herzinger, C M; Kasputis, T; Pfaunmiller, E; Nguyen, A; Korlacki, R; Pannier, A; Li, Y; Schubert, E; Hage, D; Schubert, M
2016-01-01
An optical microscope is described that reveals contrast in the Mueller matrix images of a thin, transparent or semi-transparent specimen located within an anisotropic object plane (anisotropic filter). The specimen changes the anisotropy of the filter and thereby produces contrast within the Mueller matrix images. Here we use an anisotropic filter composed of a semi-transparent, nanostructured thin film with sub-wavelength thickness placed within the object plane. The sample is illuminated as in common optical microscopy but the light is modulated in its polarization using combinations of linear polarizers and phase plate (compensator) to control and analyze the state of polarization. Direct generalized ellipsometry data analysis approaches permit extraction of fundamental Mueller matrix object plane images dispensing with the need of Fourier expansion methods. Generalized ellipsometry model approaches are used for quantitative image analyses. We demonstrate the anisotropic contrast optical microscope by mea...
Boundary layer control device for duct silencers
Schmitz, Fredric H. (Inventor); Soderman, Paul T. (Inventor)
1993-01-01
A boundary layer control device includes a porous cover plate, an acoustic absorber disposed under the porous cover plate, and a porous flow resistive membrane interposed between the porous cover plate and the acoustic absorber. The porous flow resistive membrane has a flow resistance low enough to permit sound to enter the acoustic absorber and high enough to damp unsteady flow oscillations.
Polarimetric characterization of optically anisotropic flexible substrates
Energy Technology Data Exchange (ETDEWEB)
Stchakovsky, M. [HORIBA Jobin-Yvon SAS, Z.A. de la Vigne aux Loups, 5 Avenue Arago, 91380 Chilly-Mazarin (France)], E-mail: michel.stchakovsky@jobinyvon.fr; Caillaud, C. [HORIBA Jobin-Yvon SAS, Z.A. de la Vigne aux Loups, 5 Avenue Arago, 91380 Chilly-Mazarin (France); Foldyna, M.; Ossikovski, R.; Garcia-Caurel, E. [Laboratoire de Physique des Interfaces et des Couches Minces, Ecole Polytechnique, 91128 Palaiseau (France)
2008-02-15
Phase Modulated Spectroscopic Ellipsometry as well as Liquid Crystal Mueller Matrix Polarimetry in reflection and in transmission configurations were used to systematically study five types of anisotropic polymer sheets: polyethylene-terephtalate (PET), polyethylene-naphtalate (PEN), polycarbonate (PC), polypropylene (PP) and triacetylcellulose (TAC). The measurements were performed at different sample azimuths in two ellipsometric configurations giving access to both standard ellipsometric data as well as to the entire Mueller matrix. Biaxial anisotropy, a common characteristic to all polymer types, as well as the in-depth optical properties, inhomogeneity present in the sheets were clearly evidenced. The data were interpreted in terms of a model consisting of a thick substrate (several microns) coated with a simple layer. Both, substrate and layer were anisotropic and characterized by a triplet of principal refractive indexes. The orientation of the principal indexes of the bulk and the layer were different revealing the in-depth inhomogeniety of the samples.
Fabrication of integrated porous glass for microfluidic applications
Sukas, S.; Tiggelaar, R.M.; Desmet, G.; Gardeniers, J.G.E.
2013-01-01
This paper presents a method for the fabrication of integrated porous silica layers in microfluidic channel networks by microfabrication techniques. Porous silica is obtained by anodization of silicon, followed by full conversion of the porous silicon network into porous silica by means of thermal o
Fabrication of anisotropic microparticles by laser ablation and laser heating
Energy Technology Data Exchange (ETDEWEB)
Fukuda, Kozue; Higuchi, Takeshi; Aita, Tadahiro, E-mail: aita@yz.yamagata-u.ac.jp
2015-02-01
Laser ablation and laser heating were used as micro-cutting and micro-bonding tools for fabrication of anisotropic microparticles. By using the techniques, two kinds of anisotropic microparticles to which a polymer film or magnetic particles was attached on their one hemisphere were fabricated from transparent spherical acrylic polymer particles of about 10 μm. In the fabrication of the anisotropic particles to which a polymer film attached, a mono-particle layer of the acrylic polymer particles formed on water surface was transferred on to a target plate coated with a polymer film and the plate was heated so that the particles strongly adhered to the polymer film. The plate was irradiated by 1064 nm or 532 nm pulse light from a Q-switched YAG laser to cause the ablation of the target. The ablation blew off the polymer film together with the acrylic polymer particles from the target plate, which gave the anisotropic particles. Anisotropic particles to which magnetic particles attached on their one hemisphere were fabricated by laser heating. A magnetic particle layer formed on water surface was transferred onto a quartz plate and then the monoparticle layer of the acrylic polymer particles was transferred onto the magnetic particle layer. The magnetic particles were heated by irradiation of 808 nm light from a CW diode laser, which caused the adhesion of the magnetic particles to the polymer particles. Rotation of the obtained magnetically anisotropic particles under rotating magnetic field was demonstrated. - Highlights: • Laser ablation and laser heating were used for fabrication of anisotropic particles. • Anisotropic microparticles having a polymer film or magnetic particles on their one hemisphere were fabricated. • The magnetically anisotropic microparticles rotated under a rotating magnetic field.
Scaling effect of breakthroughcharacter in porous media
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
Breakthrough phenomenon during fluids percolating through wet saturated porous layer is widely met in the study of heat and mass transfer in porous media. Breakthrough pressure (BP) is a characteristic pressure that indicates the intrinsic properties of seepage within porous media. Measuring results of BP for saturated narrow-sieved sand are reported here. The curve of BP varying with the height of porous layer was obtained. Experiment and analysis indicate that BP is independent of the height of particle packed layer if thick enough; however, when the height is less than a certain critical value, BP dimims hes with the decrease of the height according to a universal scaling law.
A positron moderator using porous metal
Institute of Scientific and Technical Information of China (English)
WANG Bao-Yi; YU Run-Sheng; ZHAO Fa-Ru; MA Chuang-Xin; ZHANG Tian-Bao; WEI Long
2004-01-01
Two types of porous metal moderators (i.e. porous nickel layer and multi-wire tungsten layer) are proposed and tested on a slow positron beam line. A moderation efficiency of about 2×10-4 has been achieved, which is higher than that for W vane geometry moderator by a factor of 4.
Quasiparticle anisotropic hydrodynamics
Alqahtani, Mubarak
2016-01-01
We study an azimuthally-symmetric boost-invariant quark-gluon plasma using quasiparticle anisotropic hydrodynamics including the effects of both shear and bulk viscosities. We compare results obtained using the quasiparticle method with the standard anisotropic hydrodynamics and viscous hydrodynamics. We consider the predictions of the three methods for the differential particle spectra and mean transverse momentum. We find that the three methods agree for small shear viscosity to entropy density ratio, $\\eta/s$, but show differences at large $\\eta/s$. Additionally, we find that the standard anisotropic hydrodynamics method shows suppressed production at low transverse-momentum compared to the other two methods, and the bulk-viscous correction can drive the primordial particle spectra negative at large $p_T$ in viscous hydrodynamics.
Averaging anisotropic cosmologies
International Nuclear Information System (INIS)
We examine the effects of spatial inhomogeneities on irrotational anisotropic cosmologies by looking at the average properties of anisotropic pressure-free models. Adopting the Buchert scheme, we recast the averaged scalar equations in Bianchi-type form and close the standard system by introducing a propagation formula for the average shear magnitude. We then investigate the evolution of anisotropic average vacuum models and those filled with pressureless matter. In the latter case we show that the backreaction effects can modify the familiar Kasner-like singularity and potentially remove Mixmaster-type oscillations. The presence of nonzero average shear in our equations also allows us to examine the constraints that a phase of backreaction-driven accelerated expansion might put on the anisotropy of the averaged domain. We close by assessing the status of these and other attempts to define and calculate 'average' spacetime behaviour in general relativity
Molecular anisotropic magnetoresistance
Otte, Fabian; Heinze, Stefan; Mokrousov, Yuriy
2015-12-01
Using density functional theory calculations, we demonstrate that the effect of anisotropic magnetoresistance (AMR) can be enhanced by orders of magnitude with respect to conventional bulk ferromagnets in junctions containing molecules sandwiched between ferromagnetic leads. We study ballistic transport in metal-benzene complexes contacted by 3 d transition-metal wires. We show that a gigantic AMR can arise from spin-orbit coupling effects in the leads, drastically enhanced by orbital-symmetry filtering properties of the molecules. We further discuss how this molecular anisotropic magnetoresistance (MAMR) can be tuned by the proper choice of materials and their electronic properties.
Hwu, Chyanbin
2010-01-01
As structural elements, anisotropic elastic plates find wide applications in modern technology. The plates here are considered to be subjected to not only in plane load but also transverse load. In other words, both plane and plate bending problems as well as the stretching-bending coupling problems are all explained in this book. In addition to the introduction of the theory of anisotropic elasticity, several important subjects have are discussed in this book such as interfaces, cracks, holes, inclusions, contact problems, piezoelectric materials, thermoelastic problems and boundary element a
Florkowski, W.; Maj, R.
The recently introduced approach describing coupled quark and gluon anisotropic fluids is generalized to include explicitly the transitions between quarks and gluons. We study the effects of such processes on the thermalization rate of anisotropic systems. We find that the quark-gluon transitions may enhance the overall thermalization rate in the cases where the initial momentum anisotropies correspond to mixed oblate-prolate or prolate configurations. On the other hand, no effect on the thermalization rate is found in the case of oblate configurations. The observed regularities are connected with the late-time behavior of the analyzed systems which is described either by the exponential decay or the power law.
Florkowski, Wojciech
2013-01-01
The recently introduced approach describing coupled quark and gluon anisotropic fluids is generalized to include explicitly the transitions between quarks and gluons. We study the effects of such processes on the thermalization rate of anisotropic systems. We find that the quark-gluon transitions may enhance the overall thermalization rate in the cases where the initial momentum anisotropies correspond to mixed oblate-prolate or prolate configurations. On the other hand, no effect on the thermalization rate is found in the case of oblate configurations. The observed regularities are connected with the late-time behavior of the analyzed systems which is described either by the exponential decay or the power law.
Pérez-Nadal, Guillem
2016-01-01
We consider a non-relativistic free scalar field theory with a type of anisotropic scale invariance in which the number of coordinates "scaling like time" is generically greater than one. We propose the Cartesian product of two curved spaces, with the metric of each space parameterized by the other space, as a notion of curved background to which the theory can be extended. We study this type of geometries, and find a family of extensions of the theory to curved backgrounds in which the anisotropic scale invariance is promoted to a local, Weyl-type symmetry.
Anisotropic models for compact stars
Maurya, S K; Ray, Saibal; Dayanandan, Baiju
2015-01-01
In the present paper we obtain an anisotropic analogue of Durgapal-Fuloria (1985) perfect fluid solution. The methodology consists of contraction of anisotropic factor $\\Delta$ by the help of both metric potentials $e^{\
Investigation of Porosity Evolution and Orthotropic Axes on Anisotropic Materials
Rahimi, Raheleh Mohammad
Advancement of porosities that happens in shear deformation of anisotropic materials is investigated by Dr. Kweon. As the hydrostatic stress in shear deformation is zero, in the solid mechanics' researches it is proved several times that porosity will not be expanded in shear deformation. Dr. Kweon showed that this statement can be wrong in large deformation of simple shear. He proposed anisotropic ductile fracture model to show that hydrostatic stress becomes nonzero and porosities are increased in the simple shear deformation of anisotropic materials. This study investigates the effect of the evolution of anisotropy which means the rotation of the orthotropic axes onto the porosity changes. Hill coefficient shows that how orthotropic materials indicate different ductile fracture manners in shear deformation. Also the effect of void aspect ratio on change of porosity is investigated. It has been found that the interaction among porosity, the matrix anisotropy and void aspect ratio play a crucial role in the ductile damage of porous materials.
On the Newtonian anisotropic configurations
Energy Technology Data Exchange (ETDEWEB)
Shojai, F. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Institute for Research in Fundamental Sciences (IPM), Foundations of Physics Group, School of Physics, Tehran (Iran, Islamic Republic of); Fazel, M.R.; Stepanian, A. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Kohandel, M. [Alzahra University, Department of Sciences, Tehran (Iran, Islamic Republic of)
2015-06-15
In this paper we are concerned with the effects of an anisotropic pressure on the boundary conditions of the anisotropic Lane-Emden equation and the homology theorem. Some new exact solutions of this equation are derived. Then some of the theorems governing the Newtonian perfect fluid star are extended, taking the anisotropic pressure into account. (orig.)
Indian Academy of Sciences (India)
B B Bhowmik; A Rajput
2004-06-01
Anisotropic Bianchi Type-I cosmological models have been studied on the basis of Lyra's geometry. Two types of models, one with constant deceleration parameter and the other with variable deceleration parameter have been derived by considering a time-dependent displacement field.
Dynamics of Anisotropic Universes
Pérez, J
2006-01-01
We present a general study of the dynamical properties of Anisotropic Bianchi Universes in the context of Einstein General Relativity. Integrability results using Kovalevskaya exponents are reported and connected to general knowledge about Bianchi dynamics. Finally, dynamics toward singularity in Bianchi type VIII and IX universes are showed to be equivalent in some precise sence.
Energy Technology Data Exchange (ETDEWEB)
Ruan, Weidong [Jilin University, State Key Laboratory of Supramolecular Structure and Materials (China); Zhou, Tieli [Changchun University, College of Food Engineering and Landscape Architecture (China); Sun, Chengbin; Tao, Yanchun; Lu, Fei; Wang, Xu; Zhao, Bing, E-mail: zhaob@mail.jlu.edu.cn [Jilin University, State Key Laboratory of Supramolecular Structure and Materials (China); Cui, Yinqiu, E-mail: cuiyq@jlu.edu.cn [Jilin University, School of Life Sciences (China)
2015-10-15
Composite films composed of polystyrene (PS) microsphere monolayers and gold (Au) and/or silver (Ag) nanoparticles (NPs) decorations were prepared by a novel size-dependent filtration effect on close-packed PS microsphere arrays. The uniform pores inlaid in the PS monolayer films acted as the transport tunnels for NPs. The steric restriction induced by the size of the pores was used as a main strategy to fabricate hybrid micro/nano films, which were composed of PS microspheres with inhomogeneous anisotropic decorations. The Au and Ag NPs were used as the building blocks to decorate the PS microspheres through a layer-by-layer self-assembly technique with the aid of polyelectrolyte coupling agents. Only the small particles which could pass through the micropores could reach to and deposit on the inner surfaces of the PS microsphere monolayer films. Large particles remained on the outside and could only deposit on the outer surfaces. Thus, the inhomogeneous anisotropic decoration was obtained. This study provides a novel strategy for fabricating anisotropic micro/nanostructures by the size-dependent filtration effect of NPs on porous films and has the potential in applications of anisotropic self-assembly, sensor, and surface modifications at nanoscale.
Electrochemical Method of Making Porous Particles Using a Constant Current Density
Ferrari, Mauro (Inventor); Liu, Xuewu (Inventor); Cheng, Ming-Cheng (Inventor)
2014-01-01
Provided is a particle that includes a first porous region and a second porous region that differs from the first porous region. Also provided is a particle that has a wet etched porous region and that does have a nucleation layer associated with wet etching. Methods of making porous particles are also provided.
Directory of Open Access Journals (Sweden)
Ravinder Kumar
2014-01-01
Full Text Available The present investigation is concerned with the study of propagation of shear waves in an anisotropic fluid saturated porous layer over a semi-infinite homogeneous elastic half-space lying under an elastic homogeneous layer with irregularity present at the interface with rigid boundary. The rectangular irregularity has been taken in the half-space. The dispersion equation for shear waves is derived by using the perturbation technique followed by Fourier transformation. Numerically, the effect of irregularity present is analysed. It is seen that the phase velocity is significantly influenced by the wave number and the depth of the irregularity. The variations of dimensionless phase velocity against dimensionless wave number are shown graphically for the different size of rectangular irregularities with the help of MATLAB.
Modeling anisotropic flow and heat transport by using mimetic finite differences
Chen, Tao; Clauser, Christoph; Marquart, Gabriele; Willbrand, Karen; Büsing, Henrik
2016-08-01
Modeling anisotropic flow in porous or fractured rock often assumes that the permeability tensor is diagonal, which means that its principle directions are always aligned with the coordinate axes. However, the permeability of a heterogeneous anisotropic medium usually is a full tensor. For overcoming this shortcoming, we use the mimetic finite difference method (mFD) for discretizing the flow equation in a hydrothermal reservoir simulation code, SHEMAT-Suite, which couples this equation with the heat transport equation. We verify SHEMAT-Suite-mFD against analytical solutions of pumping tests, using both diagonal and full permeability tensors. We compare results from three benchmarks for testing the capability of SHEMAT-Suite-mFD to handle anisotropic flow in porous and fractured media. The benchmarks include coupled flow and heat transport problems, three-dimensional problems and flow through a fractured porous medium with full equivalent permeability tensor. It shows firstly that the mimetic finite difference method can model anisotropic flow both in porous and in fractured media accurately and its results are better than those obtained by the multi-point flux approximation method in highly anisotropic models, secondly that the asymmetric permeability tensor can be included and leads to improved results compared the symmetric permeability tensor in the equivalent fracture models, and thirdly that the method can be easily implemented in existing finite volume or finite difference codes, which has been demonstrated successfully for SHEMAT-Suite.
Thermal effects in orthotropic porous elastic beams
Iaşan, D.
2009-01-01
This paper is concerned with the linear theory of anisotropic porous elastic bodies. The extension and bending of orthotropic porous elastic cylinders subjected to a plane temperature field is investigated. The work is motivated by the recent interest in the using of the orthotropic porous elastic solid as model for bones and various engineering materials. First, the thermoelastic deformation of inhomogeneous beams whose constitutive coefficients are independent of the axial coordinate is studied. Then, the extension and bending effects in orthotropic cylinders reinforced by longitudinal rods are investigated. The three-dimensional problem is reduced to the study of two-dimensional problems. The method is used to solve the problem of an orthotropic porous circular cylinder with a special kind of inhomogeneity.
Steady Counterflow he II Heat Transfer Through Porous Media
Dalban-Canassy, M.; Van Sciver, S. W.
2010-04-01
We present steady state counterflow measurements performed on porous samples saturated in He II. The experiment is composed of a vacuum insulated open channel whose top extremity is closed to a Minco® heater. The temperature and pressure differences across the plug are measured by two germanium TTR-G Microsensors® thermometers and a Validyne DP10-20 differential pressure sensor. Applied heat fluxes range up to 0.5 kW/m2 of sample cross section. Measurements were performed at temperatures ranging from 1.7 to 2.1 K on highly anisotropic samples provided by Composite Technology Development Inc.: circular pellets (3.08 mm thick and 28.58 mm in diameter) of 20 compressed layers of pre-impregnated woven magnet insulation. In the laminar regime, the permeability is estimated from the pressure drop measurements for comparison with room temperature data. In the turbulent regime, the model based on tortuosity developed previously fails to describe the heat transfer behavior of He II in this type of porous medium.
Inhomogeneous Anisotropic Cosmology
Kleban, Matthew
2016-01-01
In homogeneous and isotropic Friedmann-Robertson-Walker cosmology, the topology of the universe determines its ultimate fate. If the Weak Energy Condition is satisfied, open and flat universes must expand forever, while closed cosmologies can recollapse to a Big Crunch. A similar statement holds for homogeneous but anisotropic (Bianchi) universes. Here, we prove that ${\\it arbitrarily}$ inhomogeneous and anisotropic cosmologies with "flat" (including toroidal) and "open" (including compact hyperbolic) spatial topology that are initially expanding must continue to expand forever at least in some region, despite the presence of arbitrarily large density fluctuations and/or the formation of black holes. Because the set of 3-manifold topologies is countable, a single integer determines the ultimate fate of the universe, and, in a specific sense, most 3-manifolds are "flat" or "open". Our result has important implications for inflation: if there is a positive cosmological constant (or suitable inflationary potenti...
Force modulation microscopy of multilayered porous silicon samples
Sbrana, F.; Ghulinyan, M.; Pavesi, L.
2005-06-01
In this paper we report on Force Modulation Microscopy (FMM) study and force-distance curve analysis of porous silicon layers grown on silicon. The characterization has been carried out on the cross section of porous silicon. The FMM images allowed us to investigate the morphological thickness of the layers through local elasticity differences resolving both between porous silicon layers of different porosities and between porous silicon and silicon itself. Force-distance curves showed different adhesion behaviour: porous silicon is more hydrophobic than bulk silicon in cross sectional view.
Molecular anisotropic magnetoresistance
Otte, Fabian; Heinze, Stefan; Mokrousov, Yuriy
2015-01-01
Using density functional theory calculations, we demonstrate that the effect of anisotropic magnetoresistance (AMR) can be enhanced by orders of magnitude with respect to conventional bulk ferromagnets in junctions containing molecules sandwiched between ferromagnetic leads. We study ballistic transport in metal-benzene complexes contacted by $3d$ transition-metal wires. We show that the gigantic AMR can arise from spin-orbit coupling effects in the leads, drastically enhanced by orbital-symm...
Zhu, Dong; Miao, Zhao Yi; Yang, Rui Xiang; Wen, Hong Mei; Li, Wei; Chen, Jun; Kang, An; Shan, Chen-Xiao; Yu, Sheng; Hu, Yue
2016-08-17
The current widely utilized polymer or C8, C18 end-capped material-based sorbents for solid-phase extraction could not capture alkaloids well only based on "like dissolves like" principle. In this paper, a layer-by-layer functionalized porous Zinc sulfide nanospheres-based solid-phase extraction (SPE) combined with liquid chromatography time-of-flight/mass spectrometry (LC-TOF/MS) and gas chromatography-mass spectrometry (GC-MS) was developed for the specific enrichment and identification of alkaloids from complex matrixes, Crinum asiaticum var. sinicum crude extracts. The functionalized porous Zinc sulfide nanospheres were prepared by the amidation reaction of poly-(acrylic acid) (PAA) homopolymer with amino groups onto the porous ZnS nanospheres. Tandem LC-TOF/MS spectrometry presented that the almost all of the twenty-three main peaks in elution fraction from the SPE could be inferred as alkaloids with ion of mass according to the nitrogen rule and hit formula with Peak View1.2@software from AB SCIEX, and seven alkaloids including two new found chemical entities were directly identified from their GC-MS spectra and retention indices. We believe that this SPE protocol can also be utilized in the future to selectively enrich alkaloids from extracts of other plant species. PMID:27286770
International Nuclear Information System (INIS)
Enhancement of line x-ray emission from both solid and porous iron targets induced by irradiation of single and double laser pulses is studied numerically. The line emission from laser produced plasma is calculated within the extreme ultra-violet lithography wavelength range of 13.5–13.7 nm. The effects of pre-pulse intensity and delay time between two pulses (pre-pulse and main pulse) are examined. The results show that using double pulses irradiation in the conditions of porous target can reduce the x-ray enhancement. According to the results, the use of both pre-pulse and porous target leads to efficient absorption of the laser energy. Calculations also show that such enhanced laser absorption can ionize atoms of the target material to very high degrees of ionization, leading to decrease of the density of appropriate ions that are responsible for line emission in the selected wavelength region. By increasing the target porosity, x-ray yield was more reduced
Energy Technology Data Exchange (ETDEWEB)
Fazeli, R., E-mail: rfazeli@iust.ac.ir [Faculty of Science, Lahijan Branch, Islamic Azad University, Lahijan (Iran, Islamic Republic of); Mahdieh, M. H., E-mail: mahdm@iust.ac.ir [Department of Physics, Iran University of Science and Technology, Narmak, Tehran (Iran, Islamic Republic of)
2015-11-15
Enhancement of line x-ray emission from both solid and porous iron targets induced by irradiation of single and double laser pulses is studied numerically. The line emission from laser produced plasma is calculated within the extreme ultra-violet lithography wavelength range of 13.5–13.7 nm. The effects of pre-pulse intensity and delay time between two pulses (pre-pulse and main pulse) are examined. The results show that using double pulses irradiation in the conditions of porous target can reduce the x-ray enhancement. According to the results, the use of both pre-pulse and porous target leads to efficient absorption of the laser energy. Calculations also show that such enhanced laser absorption can ionize atoms of the target material to very high degrees of ionization, leading to decrease of the density of appropriate ions that are responsible for line emission in the selected wavelength region. By increasing the target porosity, x-ray yield was more reduced.
Energy Technology Data Exchange (ETDEWEB)
Sharma, Kashish [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309 (United States); Routkevitch, Dmitri; Varaksa, Natalia [InRedox, Longmont, Colorado 80544 (United States); George, Steven M., E-mail: Steven.George@Colorado.Edu [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309 and Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309 (United States)
2016-01-15
Spatial atomic layer deposition (S-ALD) was examined on flexible porous substrates utilizing a rotating cylinder reactor to perform the S-ALD. S-ALD was first explored on flexible polyethylene terephthalate polymer substrates to obtain S-ALD growth rates on flat surfaces. ZnO ALD with diethylzinc and ozone as the reactants at 50 °C was the model S-ALD system. ZnO S-ALD was then performed on nanoporous flexible anodic aluminum oxide (AAO) films. ZnO S-ALD in porous substrates depends on the pore diameter, pore aspect ratio, and reactant exposure time that define the gas transport. To evaluate these parameters, the Zn coverage profiles in the pores of the AAO films were measured using energy dispersive spectroscopy (EDS). EDS measurements were conducted for different reaction conditions and AAO pore geometries. Substrate speeds and reactant pulse durations were defined by rotating cylinder rates of 10, 100, and 200 revolutions per minute (RPM). AAO pore diameters of 10, 25, 50, and 100 nm were utilized with a pore length of 25 μm. Uniform Zn coverage profiles were obtained at 10 RPM and pore diameters of 100 nm. The Zn coverage was less uniform at higher RPM values and smaller pore diameters. These results indicate that S-ALD into porous substrates is feasible under certain reaction conditions. S-ALD was then performed on porous Li ion battery electrodes to test S-ALD on a technologically important porous substrate. Li{sub 0.20}Mn{sub 0.54}Ni{sub 0.13}Co{sub 0.13}O{sub 2} electrodes on flexible metal foil were coated with Al{sub 2}O{sub 3} using 2–5 Al{sub 2}O{sub 3} ALD cycles. The Al{sub 2}O{sub 3} ALD was performed in the S-ALD reactor at a rotating cylinder rate of 10 RPM using trimethylaluminum and ozone as the reactants at 50 °C. The capacity of the electrodes was then tested versus number of charge–discharge cycles. These measurements revealed that the Al{sub 2}O{sub 3} S-ALD coating on the electrodes enhanced the capacity stability. This S
ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars
Energy Technology Data Exchange (ETDEWEB)
Wang, Dong, E-mail: dong.wang@tu-ilmenau.de; Yan, Yong; Schaaf, Peter [Chair Materials for Electronics, Institute of Materials Engineering and Institute of Micro- and Nanotechnologies MacroNano, TU Ilmenau, Gustav-Kirchhoff-Str. 5, 98693 Ilmenau (Germany); Sharp, Thomas [Oxford Instruments Plasma Technology Ltd., Yatton, Bristol BS49 4AP (United Kingdom); Schönherr, Sven; Ronning, Carsten [Institute for Solid State Physics, Friedrich Schiller University Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Ji, Ran [SUSS MicroTec Lithography GmbH, Schleissheimer Str. 90, 85748 Garching (Germany)
2015-01-01
Porous Si nanopillar arrays are used as templates for atomic layer deposition of ZnO and TiO{sub 2}, and thus, ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars are fabricated. The diffusion of the precursor molecules into the inside of the porous structure occurs via Knudsen diffusion and is strongly limited by the small pore size. The luminescence of the ZnO/porous-Si nanocomposite nanopillars is also investigated, and the optical emission can be changed and even quenched after a strong plasma treatment. Such nanocomposite nanopillars are interesting for photocatalysis and sensors.
Model anisotropic quantum Hall states
Qiu, R. -Z.; Haldane, F.D.M.; Wan, Xin; Yang, Kun; Yi, Su
2012-01-01
Model quantum Hall states including Laughlin, Moore-Read and Read-Rezayi states are generalized into appropriate anisotropic form. The generalized states are exact zero-energy eigenstates of corresponding anisotropic two- or multi-body Hamiltonians, and explicitly illustrate the existence of geometric degrees of in the fractional quantum Hall effect. These generalized model quantum Hall states can provide a good description of the quantum Hall system with anisotropic interactions. Some numeri...
Material Induced Anisotropic Damage in DP600
Niazi, M.S.; Wisselink, H.H.; Meinders, V.T.; Boogaard, van den A.H.
2013-01-01
Plasticity induced damage development in metals is anisotropic by nature. The anisotropy in damage is driven by two different phenomena; anisotropic deformation state i.e. Load Induced Anisotropic Damage (LIAD) and anisotropic microstructure i.e. Material Induced Anisotropic Damage (MIAD). The contr
On the Relativistic anisotropic configurations
Shojai, F; Stepanian, A
2016-01-01
In this paper we study anisotropic spherical polytropes within the framework of general relativity. Using the anisotropic Tolman-Oppenheimer-Volkov (TOV) equations, we explore the relativistic anisotropic Lane-Emden equations. We find how the anisotropic pressure affects the boundary conditions of these equations. Also we argue that the behaviour of physical quantities near the center of star changes in the presence of anisotropy. For constant density, a class of exact solution is derived with the aid of a new ansatz and its physical properties are discussed.
On the relativistic anisotropic configurations
Energy Technology Data Exchange (ETDEWEB)
Shojai, F. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Institute for Research in Fundamental Sciences (IPM), Foundations of Physics Group, School of Physics, Tehran (Iran, Islamic Republic of); Kohandel, M. [Alzahra University, Department of Physics and Chemistry, Tehran (Iran, Islamic Republic of); Stepanian, A. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of)
2016-06-15
In this paper we study anisotropic spherical polytropes within the framework of general relativity. Using the anisotropic Tolman-Oppenheimer-Volkov equations, we explore the relativistic anisotropic Lane-Emden equations. We find how the anisotropic pressure affects the boundary conditions of these equations. Also we argue that the behavior of physical quantities near the center of star changes in the presence of anisotropy. For constant density, a class of exact solution is derived with the aid of a new ansatz and its physical properties are discussed. (orig.)
Anisotropically Inflating Universes
Barrow, J D; Barrow, John D.; Hervik, Sigbjorn
2008-01-01
We show that in theories of gravity that add quadratic curvature invariants to the Einstein-Hilbert action there exist expanding vacuum cosmologies with positive cosmological constant which do not approach the de Sitter universe. Exact solutions are found which inflate anisotropically. This behaviour is driven by the Ricci curvature invariant and has no counterpart in the general relativistic limit. These examples show that the cosmic no-hair theorem does not hold in these higher-order extensions of general relativity and raises new questions about the ubiquity of inflation in the very early universe and the thermodynamics of gravitational fields.
Anisotropic Stars Exact Solutions
Dev, K; Dev, Krsna; Gleiser, Marcelo
2000-01-01
We study the effects of anisotropic pressure on the properties of spherically symmetric, gravitationally bound objects. We consider the full general relativistic treatment of this problem and obtain exact solutions for various form of equations of state connecting the radial and tangential pressures. It is shown that pressure anisotropy can have significant effects on the structure and properties of stellar objects. In particular, the maximum value of 2M/R can approach unity (2M/R < 8/9 for isotropic objects) and the surface redshift can be arbitrarily large.
Gardiner, Thomas
2013-10-01
Anisotropic thermal diffusion in magnetized plasmas is an important physical phenomena for a diverse set of physical conditions ranging from astrophysical plasmas to MFE and ICF. Yet numerically simulating this phenomenon accurately poses significant challenges when the computational mesh is misaligned with respect to the magnetic field. Particularly when the temperature gradients are unresolved, one frequently finds entropy violating solutions with heat flowing from cold to hot zones for χ∥ /χ⊥ >=102 which is substantially smaller than the range of interest which can reach 1010 or higher. In this talk we present a new implicit algorithm for solving the anisotropic thermal diffusion equations and demonstrate its characteristics on what has become a fairly standard set of test problems in the literature. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2013-5687A.
Inhomogeneous anisotropic cosmology
Kleban, Matthew; Senatore, Leonardo
2016-10-01
In homogeneous and isotropic Friedmann-Robertson-Walker cosmology, the topology of the universe determines its ultimate fate. If the Weak Energy Condition is satisfied, open and flat universes must expand forever, while closed cosmologies can recollapse to a Big Crunch. A similar statement holds for homogeneous but anisotropic (Bianchi) universes. Here, we prove that arbitrarily inhomogeneous and anisotropic cosmologies with ``flat'' (including toroidal) and ``open'' (including compact hyperbolic) spatial topology that are initially expanding must continue to expand forever at least in some region at a rate bounded from below by a positive number, despite the presence of arbitrarily large density fluctuations and/or the formation of black holes. Because the set of 3-manifold topologies is countable, a single integer determines the ultimate fate of the universe, and, in a specific sense, most 3-manifolds are ``flat'' or ``open''. Our result has important implications for inflation: if there is a positive cosmological constant (or suitable inflationary potential) and initial conditions for the inflaton, cosmologies with ``flat'' or ``open'' topology must expand forever in some region at least as fast as de Sitter space, and are therefore very likely to begin inflationary expansion eventually, regardless of the scale of the inflationary energy or the spectrum and amplitude of initial inhomogeneities and gravitational waves. Our result is also significant for numerical general relativity, which often makes use of periodic (toroidal) boundary conditions.
Directory of Open Access Journals (Sweden)
Matthew D. Jackson
2012-01-01
Full Text Available We find that the thin double layer assumption, in which the thickness of the electrical diffuse layer is assumed small compared to the radius of curvature of a pore or throat, is valid in a capillary tubes model so long as the capillary radius is >200 times the double layer thickness, while the thick double layer assumption, in which the diffuse layer is assumed to extend across the entire pore or throat, is valid so long as the capillary radius is >6 times smaller than the double layer thickness. At low surface charge density (0.5 M the validity criteria are less stringent. Our results suggest that the thin double layer assumption is valid in sandstones at low specific surface charge (<10 mC⋅m−2, but may not be valid in sandstones of moderate- to small pore-throat size at higher surface charge if the brine concentration is low (<0.001 M. The thick double layer assumption is likely to be valid in mudstones at low brine concentration (<0.1 M and surface charge (<10 mC⋅m−2, but at higher surface charge, it is likely to be valid only at low brine concentration (<0.003 M. Consequently, neither assumption may be valid in mudstones saturated with natural brines.
Energy Technology Data Exchange (ETDEWEB)
Bellettre, J.
1998-12-01
The flows and the heat transfer near and inside a porous wall subjected to an internal flow are numerically and experimentally studied. Numerical simulations of the main flow are performed using a classical model of turbulence (RNG k-{xi} model). A discrete modeling of blowing through a porous plate is developed in order to predict interactions between the main flow and the injected fluid. Numerical results are in good agreement with experimental data obtained with a subsonic wind tunnel. The coupling between the heat transfer near and inside porous plates is studied for different injection rates, main flow temperatures and internal exchange surfaces of porous media. Surfaces temperatures are calculated using a nodal model of internal heat transfer, linked to the model of boundary layer submitted to injection. By comparing numerical and experimental temperatures of walls, the heat transfer coefficients inside porous media are calculated. In order to improve the thermal protection of walls, the transpiration with a liquid is studied. Experimental results, obtained with ethanol injection whereas the main flow is gaseous, show an important enhancement of the protection process. The coolant evaporation rate is calculated using measurement of mass fraction in the boundary layer and is used for the numerical study of mass transfer in the boundary layer. (author)
Fauzi, Nur Fatihah; Ahmad, Syakila; Pop, Ioan
2014-07-01
The steady mixed convection flow of an incompressible viscous fluid over an isoflux sphere embedded in a porous medium with the existence of heat source/sink is theoretically considered for both the assisting and opposing flow cases with small Prandtl number. The transformed equations of the non-similar boundary layer at the lower stagnation point of the sphere are solved numerically using a finite-difference method known as the Keller-box scheme. Numerical results are presented for the skin friction coefficient and the local wall temperature, as well as the velocity and temperature profiles for different values of the porosity parameter, the heat source/sink parameter and the mixed convection parameter for air. It is noticed that the solution has two branches in a certain range of the mixed convection parameter.
Chaotic advection in 2D anisotropic porous media
Varghese, Stephen; Speetjens, Michel; Trieling, Ruben; Toschi, Federico
2015-11-01
Traditional methods for heat recovery from underground geothermal reservoirs employ a static system of injector-producer wells. Recent studies in literature have shown that using a well-devised pumping scheme, through actuation of multiple injector-producer wells, can dramatically enhance production rates due to the increased scalar / heat transport by means of chaotic advection. However the effect of reservoir anisotropy on kinematic mixing and heat transport is unknown and has to be incorporated and studied for practical deployment in the field. As a first step, we numerically investigate the effect of anisotropy (both magnitude and direction) on (chaotic) advection of passive tracers in a time-periodic Darcy flow within a 2D circular domain driven by periodically reoriented diametrically opposite source-sink pairs. Preliminary results indicate that anisotropy has a significant impact on the location, shape and size of coherent structures in the Poincare sections. This implies that the optimal operating parameters (well spacing, time period of well actuation) may vary strongly and must be carefully chosen so as to enhance subsurface transport. This work is part of the research program of the Foundation for Fundamental Research on Matter (FOM), which is part of Netherlands Organisation for Scientific Research (NWO). This research program is co-financed by Shell Global Solutions International B.V.
Energy Technology Data Exchange (ETDEWEB)
Brinkman, K
2009-01-08
Mixed conductive oxides are a topic of interest for applications in oxygen separation membranes as well as use in producing hydrogen fuel through the partial oxidation of methane. The oxygen flux through the membrane is governed both by the oxygen ionic conductivity as well as the material's electronic conductivity; composite membranes like Ce{sub 0.8}Gd{sub 0.2}O{sub 2-{delta}} (CGO)-CoFe{sub 2}O{sub 4} (CFO) use gadolinium doped ceria oxides as the ionic conducting material combined with cobalt iron spinel which serves as the electronic conductor. In this study we employ {approx} 50 nm sputtered CeO{sub 2} layers on the surface of porous CGO ceramic substrates which serve as solution 'blocking' layers during the thin film fabrication process facilitating the control of film thickness. Films with thickness of {approx} 2 and 4 microns were prepared by depositing 40 and 95 separate sol-gel layers respectively. Oxygen flux measurements indicated that the permeation increased with decreasing membrane thickness; thin film membrane with thickness on the micron level showed flux values an order of magnitude greater (0.03 {micro}mol/cm{sup 2} s) at 800 C as compared to 1mm thick bulk ceramic membranes (0.003 {micro}mol/cm{sup 2}).
Directory of Open Access Journals (Sweden)
Hyeon Seo
Full Text Available Subdural cortical stimulation (SuCS is an appealing method in the treatment of neurological disorders, and computational modeling studies of SuCS have been applied to determine the optimal design for electrotherapy. To achieve a better understanding of computational modeling on the stimulation effects of SuCS, the influence of anisotropic white matter conductivity on the activation of cortical neurons was investigated in a realistic head model. In this paper, we constructed pyramidal neuronal models (layers 3 and 5 that showed primary excitation of the corticospinal tract, and an anatomically realistic head model reflecting complex brain geometry. The anisotropic information was acquired from diffusion tensor magnetic resonance imaging (DT-MRI and then applied to the white matter at various ratios of anisotropic conductivity. First, we compared the isotropic and anisotropic models; compared to the isotropic model, the anisotropic model showed that neurons were activated in the deeper bank during cathodal stimulation and in the wider crown during anodal stimulation. Second, several popular anisotropic principles were adapted to investigate the effects of variations in anisotropic information. We observed that excitation thresholds varied with anisotropic principles, especially with anodal stimulation. Overall, incorporating anisotropic conductivity into the anatomically realistic head model is critical for accurate estimation of neuronal responses; however, caution should be used in the selection of anisotropic information.
Vertical Flow Lithography for Fabrication of 3D Anisotropic Particles.
Habasaki, Shohei; Lee, Won Chul; Yoshida, Shotaro; Takeuchi, Shoji
2015-12-22
A microfluidics-based method for the 3D fabrication of anisotropic particles is reported. The method uses a vertical microchannel where tunable light patterns solidify photocurable resins for stacking multiple layers of the resins, thus enabling an application of stereolithography concepts to conventional flow lithography. Multilayered, tapered, and angular compartmental microparticles are demonstrated. PMID:26551590
Thermodynamics of anisotropic branes
Ávila, Daniel; Patiño, Leonardo; Trancanelli, Diego
2016-01-01
We study the thermodynamics of flavor D7-branes embedded in an anisotropic black brane solution of type IIB supergravity. The flavor branes undergo a phase transition between a `Minkowski embedding', in which they lie outside of the horizon, and a `black hole embedding', in which they fall into the horizon. This transition depends on two independent dimensionless ratios, which are formed out of the black hole temperature, its anisotropy parameter, and the mass of the flavor degrees of freedom. It happens either at a critical temperature or at a critical anisotropy. A general lesson we learn from this analysis is that the anisotropy, in this particular realization, induces similar effects as the temperature. In particular, increasing the anisotropy bends the branes more and more into the horizon. Moreover, we observe that the transition becomes smoother for higher anisotropies.
Averaging anisotropic cosmologies
Barrow, J D; Barrow, John D.; Tsagas, Christos G.
2006-01-01
We examine the effects of spatial inhomogeneities on irrotational anisotropic cosmologies by looking at the average properties of pressure-free Bianchi-type models. Adopting the Buchert averaging scheme, we identify the kinematic backreaction effects by focussing on spacetimes with zero or isotropic spatial curvature. This allows us to close the system of the standard scalar formulae with a propagation equation for the shear magnitude. We find no change in the already known conditions for accelerated expansion. The backreaction terms are expressed as algebraic relations between the mean-square fluctuations of the models' irreducible kinematical variables. Based on these we investigate the early evolution of averaged vacuum Bianchi type $I$ universes and those filled with pressureless matter. In the latter case we show that the backreaction effects can modify the familiar Kasner-like singularity and potentially remove Mixmaster-type oscillations. We also discuss the possibility of accelerated expansion due to ...
Directory of Open Access Journals (Sweden)
Yuan Qiang
2013-01-01
Full Text Available BaCo0.7Fe0.2Nb0.1O3−δ (BCFN dense ceramic membrane with submicron-Ce0.8Y0.2O2−δ (YDC porous layer was investigated by the partial oxidation of coke oven gas (COG in hydrogen production. XRD analysis showed this composite had good stability and no chemical reaction at high temperature. SEM and TEM characterization further showed BCFN membrane was uniformly modified by YDC porous layer (about 5~6 μm thickness formed by the accumulation of relative nanoparticles. At the respective COG flux and air flux of 108 mL/min and 173 mL/min, the oxygen permeation flux of BCFN modified by submicron-YDC porous layer reached 16.62 mL·min−1·cm−2, which was about 23.5% higher than that of pure BCFN membrane. Therefore, submicron-YDC porous layer obviously improved the oxygen permeation flux of BCFN membrane and its stability at 875°C.
Assouline, Shmuel; Narkis, Kfir; Gherabli, Rivka; Lefort, Philippe; Prat, Marc
2014-05-01
The hydraulic properties of the layer at the vicinity of the soil surface have significant impact on evaporation and could be harnessed to reduce water losses. The effect of the properties of the upper layer on the evolution of phase distribution during the evaporation process is first illustrated from three-dimensional pore network simulations. This effect is then studied from experiments carried out on soil columns under laboratory conditions. Comparisons between homogeneous columns packed with coarse (sand) and fine (sandy loam) materials and heterogeneous columns packed with layers of fine overlying coarse material and coarse overlying fine material of different thicknesses are performed to assess the impact of upper layer properties on evaporation. Experiments are analyzed using the classical approach based on the numerical solution of Richards equation and semianalytical theoretical predictions. The theoretical analysis is based on the clear distinction between two drying regimes, namely, the capillary regime and the gravity-capillary regime, which are the prevailing regimes in our experiments. Simple relationships enabling to estimate the duration of stage 1 evaporation (S1) for both regimes are proposed. In particular, this led to defining the characteristic length for the gravity-capillary regime from the consideration of viscous effects at low water content differently from available expressions. The duration of S1, during which most of the water losses occur, for both the homogeneous and two-layer columns is presented and discussed. Finally, the impact of liquid films and its consequences on the soil hydraulic conductivity function are briefly discussed.
Energy Technology Data Exchange (ETDEWEB)
Barclay Jones
2005-06-27
A significant number of current PWRs around the world are experiencing anomalous crud deposition in the sub-cooled region of the core, resulting in an axial power shift or Axial Offset Anomaly (AOA), a condition that continues to elude prediction of occurrence and thermal/neutronic performance. This creates an operational difficulty of not being able to accurately determine power safety margin. In some cases this condition has required power ''down rating'' by as much as thirty percent and the concomitant considerable loss of revenue for the utility. This study examines two aspects of the issue: thermal performance of crud layer and effect of sub-cooled nucleate boiling on the solute concentration and its influence on initiation of crud deposition/formation on fuel pin surface.
Anisotropic Inflation with General Potentials
Shi, Jiaming; Qiu, Taotao
2015-01-01
Anomalies in recent observational data indicate that there might be some "anisotropic hair" generated in an inflation period. To obtain general information about the effects of this anisotropic hair to inflation models, we studied anisotropic inflation models that involve one vector and one scalar using several types of potentials. We determined the general relationship between the degree of anisotropy and the fraction of the vector and scalar fields, and concluded that the anisotropies behave independently of the potentials. We also generalized our study to the case of multi-directional anisotropies.
Photon states in anisotropic media
Indian Academy of Sciences (India)
Deepak Kumar
2002-08-01
Quantum aspects of optical polarization are discussed for waves traveling in anisotropic dielectric media with a view to relate the dynamics of polarization with that of photon spin and its manipulation by classical polarizers.
Gradient expansion for anisotropic hydrodynamics
Florkowski, Wojciech; Spaliński, Michał
2016-01-01
We compute the gradient expansion for anisotropic hydrodynamics. The results are compared with the corresponding expansion of the underlying kinetic-theory model with the collision term treated in the relaxation time approximation. We find that a recent formulation of anisotropic hydrodynamics based on an anisotropic matching principle yields the first three terms of the gradient expansion in agreement with those obtained for the kinetic theory. This gives further support for this particular hydrodynamic model as a good approximation of the kinetic-theory approach. We further find that the gradient expansion of anisotropic hydrodynamics is an asymptotic series, and the singularities of the analytic continuation of its Borel transform indicate the presence of non-hydrodynamic modes.
Formation of porous gas hydrates
Salamatin, Andrey N
2015-01-01
Gas hydrates grown at gas-ice interfaces are examined by electron microscopy and found to have a submicron porous texture. Permeability of the intervening hydrate layers provides the connection between the two counterparts (gas and water molecules) of the clathration reaction and makes further hydrate formation possible. The study is focused on phenomenological description of principal stages and rate-limiting processes that control the kinetics of the porous gas hydrate crystal growth from ice powders. Although the detailed physical mechanisms involved in the porous hydrate formation still are not fully understood, the initial stage of hydrate film spreading over the ice surface should be distinguished from the subsequent stage which is presumably limited by the clathration reaction at the ice-hydrate interface and develops after the ice grain coating is finished. The model reveals a time dependence of the reaction degree essentially different from that when the rate-limiting step of the hydrate formation at...
A crossover in anisotropic nanomechanochemistry of van der Waals crystals
International Nuclear Information System (INIS)
In nanoscale mechanochemistry, mechanical forces selectively break covalent bonds to essentially control chemical reactions. An archetype is anisotropic detonation of layered energetic molecular crystals bonded by van der Waals (vdW) interactions. Here, quantum molecular dynamics simulations reveal a crossover of anisotropic nanomechanochemistry of vdW crystal. Within 10−13 s from the passage of shock front, lateral collision produces NO2 via twisting and bending of nitro-groups and the resulting inverse Jahn-Teller effect, which is mediated by strong intra-layer hydrogen bonds. Subsequently, as we transition from heterogeneous to homogeneous mechanochemical regimes around 10−12 s, shock normal to multilayers becomes more reactive, producing H2O assisted by inter-layer N-N bond formation. These time-resolved results provide much needed atomistic understanding of nanomechanochemistry that underlies a wider range of technologies
A crossover in anisotropic nanomechanochemistry of van der Waals crystals
Energy Technology Data Exchange (ETDEWEB)
Shimamura, Kohei [Department of Physics, Kumamoto University, Kumamoto 860-8555 (Japan); Collaboratory for Advanced Computing and Simulations, Department of Physics and Astronomy, Department of Computer Science, Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-0242 (United States); Graduate School of System Informatics, Kobe University, Kobe 657-8501 (Japan); Misawa, Masaaki [Department of Physics, Kumamoto University, Kumamoto 860-8555 (Japan); Collaboratory for Advanced Computing and Simulations, Department of Physics and Astronomy, Department of Computer Science, Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-0242 (United States); Li, Ying [Argonne Leadership Computing Facility, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Kalia, Rajiv K.; Nakano, Aiichiro; Vashishta, Priya [Collaboratory for Advanced Computing and Simulations, Department of Physics and Astronomy, Department of Computer Science, Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-0242 (United States); Shimojo, Fuyuki [Department of Physics, Kumamoto University, Kumamoto 860-8555 (Japan)
2015-12-07
In nanoscale mechanochemistry, mechanical forces selectively break covalent bonds to essentially control chemical reactions. An archetype is anisotropic detonation of layered energetic molecular crystals bonded by van der Waals (vdW) interactions. Here, quantum molecular dynamics simulations reveal a crossover of anisotropic nanomechanochemistry of vdW crystal. Within 10{sup −13} s from the passage of shock front, lateral collision produces NO{sub 2} via twisting and bending of nitro-groups and the resulting inverse Jahn-Teller effect, which is mediated by strong intra-layer hydrogen bonds. Subsequently, as we transition from heterogeneous to homogeneous mechanochemical regimes around 10{sup −12} s, shock normal to multilayers becomes more reactive, producing H{sub 2}O assisted by inter-layer N-N bond formation. These time-resolved results provide much needed atomistic understanding of nanomechanochemistry that underlies a wider range of technologies.
On full-tensor permeabilities of porous media from numerical solutions of the Navier-Stokes equation
Wang, Y.
2013-01-01
A numerical method is proposed to compute full-tensor permeability of porous media without artificial simplification. Navier-Stokes (N-S) equation and Darcy\\'s law are combined to design these numerical experiments. This method can successfully detect the permeability values in principle directions of the porous media and the anisotropic degrees. It is found that the same configuration of porous media may possess isotropic features at lower Reynolds numbers while manifesting anisotropic features at higher Reynolds numbers due to the nonlinearity from convection. Anisotropy becomes pronounced especially when convection is dominant. 2013 Yi Wang et al.
Surface States and Photoluminescence From Porous Silicon
Md. Nazrul Islam; Satyendra Kumar
2011-01-01
Photoluminescence (PL) spectra of freshly electrochemically etched porous silicon layers anodized under various condition have been measured and analyzed according to quantum confinement (QC) model and surface state models. The results support the combination of QC and surface state models for visible PL from fresh PS layers.
Energy Technology Data Exchange (ETDEWEB)
Muhaimin, E-mail: muh003@yahoo.co [Computational Fluid Dynamics, FSSW, Universiti Tun Hussein Onn Malaysia, 86400, Parit Raja, Batu Pahat, Johor (Malaysia); Kandasamy, Ramasamy, E-mail: future990@gmail.co [Computational Fluid Dynamics, FSSW, Universiti Tun Hussein Onn Malaysia, 86400, Parit Raja, Batu Pahat, Johor (Malaysia); Hashim, Ishak [School of Mathematical Sciences, Faculty of Science and Technology, UKM, Bangi, Selangor (Malaysia)
2010-05-15
This work is concerned with the viscous flow due to a shrinking sheet in the presence of suction with variable stream conditions. The cases of two-dimensional and axisymmetric shrinking have been discussed. The governing partial differential equations of the problem, subjected to their boundary conditions, are solved numerically by applying an efficient solution scheme for local nonsimilarity boundary layer analysis. Favorable comparison with previously published work is performed. Numerical results for the dimensionless velocity, temperature and concentration profiles as well as for the skin friction, heat and mass transfer and deposition rate are obtained and displayed graphically for pertinent parameters to show interesting aspects of the solution.
A finite difference, multipoint flux numerical approach to flow in porous media: Numerical examples
Osman, Hossam
2012-06-17
It is clear that none of the current available numerical schemes which may be adopted to solve transport phenomena in porous media fulfill all the required robustness conditions. That is while the finite difference methods are the simplest of all, they face several difficulties in complex geometries and anisotropic media. On the other hand, while finite element methods are well suited to complex geometries and can deal with anisotropic media, they are more involved in coding and usually require more execution time. Therefore, in this work we try to combine some features of the finite element technique, namely its ability to work with anisotropic media with the finite difference approach. We reduce the multipoint flux, mixed finite element technique through some quadrature rules to an equivalent cell-centered finite difference approximation. We show examples on using this technique to single-phase flow in anisotropic porous media.
Energy Technology Data Exchange (ETDEWEB)
Li, XS; Michaelis, VK; Ong, TC; Smith, SJ; McKay, I; Muller, P; Griffin, RG; Wang, EN
2014-01-01
One-pot solvothermal synthesis of a robust tetranuclear sodium hexakis(glycolato)tris(methanolato)aluminate complex Na-3[Al-4(OCH3)(3)(OCH2CH2O)(6)] via a modified yet rigorous base-catalyzed transesterification mechanism is presented here. Single crystal X-ray diffraction (SCXRD) studies indicate that this unique Al complex contains three pentacoordinate Al3+ ions, each bound to two bidentate ethylene glycolate chelators and one monodentate methanolate ligand. The remaining fourth Al3+ ion is octahedrally coordinated to one oxygen atom from each of the six surrounding glycolate chelators, effectively stitching the three pentacoordinate Al moieties together into a novel tetranuclear Al complex. This aluminate complex is periodically self-assembled into well-ordered layers normal to the [110] axis with the intra-/inter-layer bonding involving extensive ionic bonds from the three charge-counterbalancing Na+ cations rather than the more typical hydrogen bonding interactions as a result of fewer free hydroxyl groups present in its structure. It can also serve as a valuable precursor toward the facile synthesis of high-surface-area alumina powders using a very efficient rapid pyrolysis technique.
Time resolved analysis of water drainage in porous asphalt concrete using neutron radiography.
Poulikakos, L D; Sedighi Gilani, M; Derome, D; Jerjen, I; Vontobel, P
2013-07-01
Porous asphalt as a road surface layer controls aquaplaning as rain water can drain through its highly porous structure. The process of water drainage through this permeable layer is studied using neutron radiography. Time-resolved water configuration and distribution within the porous structure are reported. It is shown that radiography depicts the process of liquid water transport within the complex geometry of porous asphalt, capturing water films, filled dead end pores and water islands.
Time resolved analysis of water drainage in porous asphalt concrete using neutron radiography.
Poulikakos, L D; Sedighi Gilani, M; Derome, D; Jerjen, I; Vontobel, P
2013-07-01
Porous asphalt as a road surface layer controls aquaplaning as rain water can drain through its highly porous structure. The process of water drainage through this permeable layer is studied using neutron radiography. Time-resolved water configuration and distribution within the porous structure are reported. It is shown that radiography depicts the process of liquid water transport within the complex geometry of porous asphalt, capturing water films, filled dead end pores and water islands. PMID:23500651
Coefficient adaptive triangulation for strongly anisotropic problems
Energy Technology Data Exchange (ETDEWEB)
D`Azevedo, E.F.; Romine, C.H.; Donato, J.M.
1996-01-01
Second order elliptic partial differential equations arise in many important applications, including flow through porous media, heat conduction, the distribution of electrical or magnetic potential. The prototype is the Laplace problem, which in discrete form produces a coefficient matrix that is relatively easy to solve in a regular domain. However, the presence of anisotropy produces a matrix whose condition number is increased, making the resulting linear system more difficult to solve. In this work, we take the anisotropy into account in the discretization by mapping each anisotropic region into a ``stretched`` coordinate space in which the anisotropy is removed. The region is then uniformly triangulated, and the resulting triangulation mapped back to the original space. The effect is to generate long slender triangles that are oriented in the direction of ``preferred flow.`` Slender triangles are generally regarded as numerically undesirable since they tend to cause poor conditioning; however, our triangulation has the effect of producing effective isotropy, thus improving the condition number of the resulting coefficient matrix.
Directory of Open Access Journals (Sweden)
P. Sreenivasulu
2015-01-01
Full Text Available This study investigates the influence of thermal radiation and heat generation/absorption on a two dimensional steady boundary layer flow near the stagnation-point on a permeable stretching sheet in a porous medium saturated with nanofluids. The governing partial differential equations with the appropriate boundary conditions are reduced to a set of ordinary differential equations via Lie-group analysis. The resultant equations are then solved numerically using Runge - Kutta fourth order method along with shooting technique. Two types of nanofluids, namely, copper-water and alumina-water are considered. The velocity and temperature as well as the shear stress and heat transfer rates are computed. The influence of pertinent parameters such as radiation parameter Nr, nanofluid volume fraction parameter , the ratio of free stream velocity and stretching velocity parameter a/c , the permeability parameter K1, suction/blowing parameter S, and heat source/sink parameter on the flow and heat transfer characteristics is discussed. The present study helps to understand the efficiency of heat transfer transport in nanofluids which are likely to be the smart coolants of the next generation.
Hou, Yang; Wen, Zhenhai; Cui, Shumao; Feng, Xinliang; Chen, Junhong
2016-04-13
Developing photoanodes with efficient sunlight harvesting, excellent charge separation and transfer, and fast surface reaction kinetics remains a key challenge in photoelectrochemical water splitting devices. Here we report a new strongly coupled ternary hybrid aerogel that is designed and constructed by in situ assembly of N-deficient porous carbon nitride nanosheets and NiFe-layered double hydroxide into a 3D N-doped graphene framework architecture using a facile hydrothermal method. Such a 3D hierarchical structure combines several advantageous features, including effective light-trapping, multidimensional electron transport pathways, short charge transport time and distance, strong coupling effect, and improved surface reaction kinetics. Benefiting from the desirable nanostructure, the ternary hybrid aerogels exhibited remarkable photoelectrochemical performance for water oxidation. Results included a record-high photocurrent density that reached 162.3 μA cm(-2) at 1.4 V versus the reversible hydrogen electrode with a maximum incident photon-to-current efficiency of 2.5% at 350 nm under AM 1.5G irradiation, and remarkable photostability. The work represents a significant step toward the development of novel 3D aerogel-based photoanodes for solar water splitting. PMID:26963768
Institute of Scientific and Technical Information of China (English)
张志民; 郭长友; 马波; 凌凤香; 苗升; 沈智奇; 翁蕾
2012-01-01
采用原子层沉积技术进行Al2O3表面钛改性,利用N2吸附-脱附、X射线衍射、X射线荧光分析、透射电镜和热重-微分热重-差示扫描量热等表征手段对改性前后的A12O3载体进行表征.结果表明,钛分散到Al2O3表面,Al2O3载体表面氧化钛为锐钛矿结构,改性后的载体具有良好的热稳定性.钛分散性与Al2O3表面化学环境有关,钛对多孔A12O3表面改性可以通过原子层沉积技术实现.%Atomic layer deposition technology was used to modify alumina surface with titanium. Alumina before and after modification was characterized by isothermal N2 adsorption-desorption, X-ray diffraction (XRD), X-ray fluorescence analysis (XRF), transmission electronic microscope (TEM) and thermo-gravimelry-differential thermogravimetry-differential scanning calorimetry (TG-DTG-DSC ). The results showed that Ti was dispersed on the surface of alumina as titania with anatase structure. Modified alumina exhibited excellent thermal stability. Dispersily of Ti is related to chemical environment of alumina surface. Ti modification of porous alumina is feasible using atomic layer deposition technology.
Continuum mechanics of anisotropic materials
Cowin, Stephen C
2013-01-01
Continuum Mechanics of Anisotropic Materials(CMAM) presents an entirely new and unique development of material anisotropy in the context of an appropriate selection and organization of continuum mechanics topics. These features will distinguish this continuum mechanics book from other books on this subject. Textbooks on continuum mechanics are widely employed in engineering education, however, none of them deal specifically with anisotropy in materials. For the audience of Biomedical, Chemical and Civil Engineering students, these materials will be dealt with more frequently and greater accuracy in their analysis will be desired. Continuum Mechanics of Anisotropic Materials' author has been a leader in the field of developing new approaches for the understanding of anisotropic materials.
Anisotropically structured magnetic aerogel monoliths
Heiligtag, Florian J.; Airaghi Leccardi, Marta J. I.; Erdem, Derya; Süess, Martin J.; Niederberger, Markus
2014-10-01
Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture.Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture. Electronic supplementary information (ESI) available: Digital photographs of dispersions and gels with different water-to-ethanol ratios; magnetic measurements of an anatase aerogel containing 0.25 mol% Fe3O4 nanoparticles; XRD patterns of the iron oxide and
Latest developments in anisotropic hydrodynamics
Tinti, Leonardo
2015-01-01
We discuss the leading order of anisotropic hydrodynamics expansion. It has already been shown that in the (0+1) and (1+1)-dimensional cases it is consistent with the second order viscous hydrodynamics, and it provides a striking agreement with the exact solutions of the Boltzmann equation. Quite recently, a new set of equations has been proposed for the leading order of anisotropic hydrodynamics, which is consistent with the second order viscous hydrodynamics in the most general (3+1)-dimensional case, and does not require a next-to-leading treatment for describing pressure anisotropies in the transverse plane.
Dynamical analysis of anisotropic inflation
Karčiauskas, Mindaugas
2016-06-01
The inflaton coupling to a vector field via the f(φ)2F μνFμν term is used in several contexts in the literature, such as to generate primordial magnetic fields, to produce statistically anisotropic curvature perturbation, to support anisotropic inflation, and to circumvent the η-problem. In this work, I perform dynamical analysis of this system allowing for the most general Bianchi I initial conditions. I also confirm the stability of attractor fixed points along phase-space directions that had not been investigated before.
Anisotropic hydrodynamics: Motivation and methodology
International Nuclear Information System (INIS)
In this proceedings contribution I review recent progress in our understanding of the bulk dynamics of relativistic systems that possess potentially large local rest frame momentum-space anisotropies. In order to deal with these momentum-space anisotropies, a reorganization of relativistic viscous hydrodynamics can be made around an anisotropic background, and the resulting dynamical framework has been dubbed “anisotropic hydrodynamics”. I also discuss expectations for the degree of momentum-space anisotropy of the quark–gluon plasma generated in relativistic heavy ion collisions at RHIC and LHC from second-order viscous hydrodynamics, strong-coupling approaches, and weak-coupling approaches
Jeong, Heon Jae; Kim, Jun Woo; Jang, Dong Young; Shim, Joon Hyung
2015-09-01
Pt-Ru bi-metallic catalysts are synthesized by atomic layer deposition (ALD) of Ru surface-coating on sputtered Pt mesh. The catalysts are evaluated in direct ethanol solid oxide fuel cells (DESOFCs) in the temperature range of 300-500 °C. Island-growth of the ALD Ru coating is confirmed by transmission electron microscopy and X-ray photoelectron spectroscopy (XPS) analyses. The performance of the DESOFCs is evaluated based on the current-voltage output and electrochemical impedance spectroscopy. Genuine reduction of the polarization impedance, and enhanced power output with improved surface kinetics are achieved with the optimized ALD Ru surface-coating compared to bare Pt. The chemical composition of the Pt/ALD Ru electrode surface after fuel cell operation is analyzed via XPS. Enhanced cell performance is clearly achieved, attributed to the effective Pt/ALD Ru bi-metallic catalysis, including oxidation of Cdbnd O by Ru, and de-protonation of ethanol and cleavage of C-C bonds by Pt, as supported by surface morphology analysis which confirms formation of a large amount of carbon on bare Pt after the ethanol-fuel-cell test.
Magnetic phase diagram of the anisotropic double-exchange model: a Monte Carlo study
International Nuclear Information System (INIS)
The magnetic phase diagram of highly anisotropic double-exchange model systems is investigated as a function of the ratio of the anisotropic hopping integrals, i.e., tc/tab, on a three-dimensional lattice by using Monte Carlo calculations. The magnetic domain structure at low temperature is found to be a generic property of the strong anisotropy region. Moreover, the tc/tab ratio is crucial in determining the anisotropic charge transport due to the relative spin orientation of the magnetic domains. As a result, we show the anisotropic hopping integral is the most likely cause of the magnetic domain structure. It is noted that the competition between the reduced interlayer double-exchange coupling and the thermal frustration of the ordered two-dimensional ferromagnetic layer seems to be crucial in understanding the properties of layered manganites
Characterization of highly anisotropic three-dimensionally nanostructured surfaces
Schmidt, Daniel
2013-01-01
Generalized ellipsometry, a non-destructive optical characterization technique, is employed to determine geometrical structure parameters and anisotropic dielectric properties of highly spatially coherent three-dimensionally nanostructured thin films grown by glancing angle deposition. The (piecewise) homogeneous biaxial layer model approach is discussed, which can be universally applied to model the optical response of sculptured thin films with different geometries and from diverse materials, and structural parameters as well as effective optical properties of the nanostructured thin films are obtained. Alternative model approaches for slanted columnar thin films, anisotropic effective medium approximations based on the Bruggeman formalism, are presented, which deliver results comparable to the homogeneous biaxial layer approach and in addition provide film constituent volume fraction parameters as well as depolarization or shape factors. Advantages of these ellipsometry models are discussed on the example ...
Institute of Scientific and Technical Information of China (English)
王旭龙琦; 张冬仙; 章海军
2011-01-01
By modeling and analyzing porous alumina ( PA), a method to modulate the colors of PA templates is proposed, which is based on the preparation of PA templates and the atomic layer deposition (ALD) technique. Referring to the experimentally prepared PA samples, theoretical simulations are carried out for a series of PA templates with the same bole-diameter and hole-interval, but with different hole-depths. The relationship between the modulated colors and the hole-depths are thus disclosed. By controlling the time of anodization in oxalic aeidolution, two PA samples with different hole-depths (296 nm and 373 nm) were prepared, both with an average hole-diameter of 40 nm and an average boleinterval of 100 nm, respectively. ALD proeessing is then applied to deposit a layer of Fe2O3 film with total thickness of 16. 8 nm on these samples. It was experimentally observed that the processed PA samples show different colors which change with hole-depths. The experimental results are in good agreement with the theoretical simulations, which proves the feasibility of color modulation with this method.%本文通过建立多孔氧化铝(porous alumina,PA)的物理模型及理论分析,提出与发展了一种基于PA和单原子沉积(atomic layer deposition,ALD)技术的颜色调控新方法.以实验制备的PA样品为原型,对孔径相同、孔中心距相同但孔深不同的一系列PA模板进行了颜色调控的仿真,揭示了调控色随孔深变化的规律;通过控制在草酸溶液中的阳极氧化时间,实验制备出平均孔径40 nm、平均孔中心距100nm、孔深分别为296 nm和373 nm的两个PA样品;之后采用ALD技术在它们表面均沉积一层膜厚为16.8 nm的Fe2O3薄膜;在白光照射下,可观察到这两个经ALD沉积后的PA样品呈现出不同的颜色.实验中得到的实际调控色,与理论仿真结果相符合,从而证明了这一颜色调控方法的可行性.
Porosity-dependent fractal nature of the porous silicon surface
Energy Technology Data Exchange (ETDEWEB)
Rahmani, N.; Dariani, R. S., E-mail: dariani@alzahra.ac.ir [Department of Physics, Alzahra University, Tehran, 1993893973 (Iran, Islamic Republic of)
2015-07-15
Porous silicon films with porosity ranging from 42% to 77% were fabricated by electrochemical anodization under different current density. We used atomic force microscopy and dynamic scaling theory for deriving the surface roughness profile and processing the topography of the porous silicon layers, respectively. We first compared the topography of bare silicon surface with porous silicon and then studied the effect of the porosity of porous silicon films on their scaling behavior by using their self-affinity nature. Our work demonstrated that silicon compared to the porous silicon films has the highest Hurst parameter, indicating that the formation of porous layer due to the anodization etching of silicon surface leads to an increase of its roughness. Fractal analysis revealed that the evolution of the nanocrystallites’ fractal dimension along with porosity. Also, we found that both interface width and Hurst parameter are affected by the increase of porosity.
Effects of the Biot and the squirt-flow coupling interaction on anisotropic elastic waves
Institute of Scientific and Technical Information of China (English)
无
2000-01-01
Considering the velocity anisotropy of the solid/fluid relative motion and employment of the BISQ theory[1] based on the one-dimensional porous isotropic case, we establish a two-phase anisotropic elastic wave equation to simultaneously include the Biot and the squirt mechanisms in terms of both the basic principles of the fluid's mass conservation and the elastic-wave dynamical equations in the two-phase anisotropic rock. Numerical results, while the Biot-flow and the squirt-flow effects are simultaneously considered in the transversely isotropic (TI) poroelastic medium, show that the attenuation of the quasi P-wave and the quasi SV-wave strongly depend on the permeability anisotropy, and the attenuation behavior at low and high frequencies is contrary. Meanwhile, the attenuation and dispersion of the quasi P-wave are also affected seriously by the anisotropic solid/fluid coupling additional density.
Magnetic relaxation in anisotropic magnets
DEFF Research Database (Denmark)
Lindgård, Per-Anker
1971-01-01
The line shape and the kinematic and thermodynamic slowing down of the critical and paramagnetic relaxation in axially anisotropic materials are discussed. Kinematic slowing down occurs only in the longitudinal relaxation function. The thermodynamic slowing down occurs in either the transverse or...
Anisotropic Poisson Processes of Cylinders
Spiess, Malte
2010-01-01
Main characteristics of stationary anisotropic Poisson processes of cylinders (dilated k-dimensional flats) in d-dimensional Euclidean space are studied. Explicit formulae for the capacity functional, the covariance function, the contact distribution function, the volume fraction, and the intensity of the surface area measure are given which can be used directly in applications.
Failure in imperfect anisotropic materials
DEFF Research Database (Denmark)
Legarth, Brian Nyvang
2005-01-01
The fundamental cause of crack growth, namely nucleation and growth of voids, is investigated numerically for a two phase imperfect anisotropic material. A unit cell approach is adopted from which the overall stress strain is evaluated. Failure is observed as a sudden stress drop and depending...
Hemker, K.; Bakker, M.
2006-01-01
Analytical solutions are derived for steady state groundwater flow in a heterogeneous, anisotropic, semiconfined aquifer. The aquifer consists of a number of horizontal layers, while each layer consists of a number of homogeneous cells with different hydraulic conductivity tensors. An exact solution
Wave Propagation in Fractured Anisotropic Media
Shao, S.; Pyrak-Nolte, L. J.
2012-12-01
Discontinuities such as fractures, joints and faults occur in the Earth's crusts in a variety of rock types. While much theoretical, experimental and computational research have examined seismic wave propagation in fractured isotropic rock, few experimental studies have investigated seismic wave propagation in fractured anisotropic media. The co-existence of fractures and layers can complicate the interpretation of seismic properties because of the discrete guided modes that propagate along or are confined by the fractures. In this study, we use seismic arrays and acoustic wavefront imaging techniques to examine the competing sources of seismic anisotropy from fractures and from layers. Samples with textural anisotropy (100 mm x 100 mm x 100 mm) were fabricated from garolite, an epoxy - cloth laminate, with layer thickness 0f ~ 0.5 mm. Two sets of fractured samples were fabricated: (1) two single fractured samples with one fracture either parallel or (and) perpendicular to layers, and (2) four multi-fractured samples with 5 parallel fractures oriented either parallel, 30 degrees, 60 degrees or perpendicular to the layers. An intact sample containing no fractures was used as a standard orthorhombic medium for reference. Seismic arrays were used on the first set of samples to measure bulk waves and fracture interface waves as a function of stress. The seismic array contained two compressional and five shear-wave source-receiver pairs with a central frequency of 1 MHz. Shear wave transducers were polarized both perpendicular and parallel to the layering as well as to the fracture. Measurements were made for a range of stresses (0.4 - 4MPa). From these measurements it was observed that a fractured layered medium appears more isotropic or anisotropic than the orthorhombic background, depending on the orientation of the fracture relative to layers. The matrix anisotropy was recovered by increasing the normal stress on a fracture (i.e., by closing the fracture). For the
Directory of Open Access Journals (Sweden)
Emad H. Aly
2015-01-01
Full Text Available In existence of the velocity slip model, suction/injection, and heat source/sink, the boundary layer flow near a stagnation-point over a heated stretching sheet in a porous medium saturated by a nanofluid, with effect of the thermal radiation and magnetic field, has been studied. The governing system of partial differential equations was transformed into a system of nonlinear ordinary equations using the appropriate similarity transforms. Then, the obtained system has been numerically solved by the Chebyshev pseudospectral differentiation matrix (ChPDM approach. It was found that, at some special cases, the current results are in a very good agreement with those presented in the literature. In addition, the flow velocity, surface shear stress, temperature, and concentration are strongly influenced on applying the slip model, which is, therefore, extremely important to predict the flow characteristics accurately in the nanofluid mechanics. It was proved that this velocity slip condition is mandatory and should be taken into account in nanoscale research; otherwise, false results and a spurious physical sight are to be gained. Further, it was deduced that the influence of the stream velocity and shear stress reaches very rapidly the stable manner for both cases of the velocity ratio. However, when this ratio is equal to one, the skin friction coefficient, reduced Nusselt number, and reduced Sherwood number are constant and equal to zero, 0.721082, and 3.06155, respectively. Furthermore, it was proved that the reduced Nusselt number decreases with increase of Brownian motion and thermophoresis; has a very weak effect on increasing Lewis number; increases with increase of Prandtl number; and is higher in the cases of suction, velocity ratio > 1 and heat source in comparison with injection, velocity ratio 1 in comparison with injection and velocity ratio < 1, respectively; and is approximately the same in the heat source and heat sink cases. Finally
Rao, B V Bhaskara; Yadav, Prasad; Aepuru, Radhamanohar; Panda, H S; Ogale, Satishchandra; Kale, S N
2015-07-28
In this study, a novel composite of Fe3O4 nanofiller-decorated single-layer graphene-assembled porous carbon (SLGAPC) with polyvinyl alcohol (PVA) having flexibility and a density of 0.75 g cm(-3) is explored for its dielectric and electromagnetic interference (EMI) response properties. The composite is prepared by the solution casting method and its constituents are optimized as 15 wt% SLGAPC and 20 wt% Fe3O4 through a novel solvent relaxation nuclear magnetic resonance experiment. The PVA-SLGAPC-Fe3O4 composite shows high dielectric permittivity in the range of 1 Hz-10 MHz, enhanced by a factor of 4 as compared to that of the PVA-SLGAPC composite, with a reduced loss by a factor of 2. The temperature dependent dielectric properties reveal the activation energy behaviour with reference to the glass transition temperature (80 °C) of PVA. The dielectric hysteresis with the temperature cycle reveals a remnant polarization. The enhanced dielectric properties are suggested to be the result of improvement in the localized polarization of the integrated interface system (Maxwell-Wagner-Sillars (MWS) polarization) formed by the uniform adsorption of Fe3O4 on the surface of SLGAPC conjugated with PVA. The EMI shielding property of the composite with a low thickness of 0.3 mm in the X-band (8.2-12.4 GHz) shows a very impressive shielding efficiency of ∼15 dB and a specific shielding effectiveness of 20 dB (g cm(-3))(-1), indicating the promising character of this material for flexible EMI shielding applications. PMID:26105548
Amine Functionalized Porous Network
Eddaoudi, Mohamed
2015-05-28
Amine groups can be introduced in porous materials by a direct (one pot) or post-synthetic modification (PSM) process on aldehyde groups, and the resulting porous materials have increased gas affinity.
Photonic Crystal Sensors Based on Porous Silicon
Directory of Open Access Journals (Sweden)
Claudia Pacholski
2013-04-01
Full Text Available Porous silicon has been established as an excellent sensing platform for the optical detection of hazardous chemicals and biomolecular interactions such as DNA hybridization, antigen/antibody binding, and enzymatic reactions. Its porous nature provides a high surface area within a small volume, which can be easily controlled by changing the pore sizes. As the porosity and consequently the refractive index of an etched porous silicon layer depends on the electrochemial etching conditions photonic crystals composed of multilayered porous silicon films with well-resolved and narrow optical reflectivity features can easily be obtained. The prominent optical response of the photonic crystal decreases the detection limit and therefore increases the sensitivity of porous silicon sensors in comparison to sensors utilizing Fabry-Pérot based optical transduction. Development of porous silicon photonic crystal sensors which allow for the detection of analytes by the naked eye using a simple color change or the fabrication of stacked porous silicon photonic crystals showing two distinct optical features which can be utilized for the discrimination of analytes emphasize its high application potential.
Anisotropic metasurface with near-unity circular polarization conversion
Wu, Xiaoxiao; Meng, Yan; Wang, Li; Tian, Jingxuan; Dai, Shiwei; Wen, Weijia
2016-05-01
We demonstrate a bi-layer ultrathin anisotropic metasurface which could near-completely convert the circular-polarized electromagnetic wave to its cross polarization. The bi-layer metasurface is composed of periodic 180°-twisted double-cut split ring resonators on both sides of an F4B substrate. At resonance, cross-polarized transmission larger than 94% is observed both in simulations and experiments. The resonant frequency of the metasurface could be effectively tuned by adjusting the geometric parameters of the metasurface, while relatively high conversion efficiency is preserved. The high efficiency and ease of fabrication suggest that the ultrathin metasurface could have potential applications in telecommunications.
Knox, D. J.
2013-11-14
© 2013 © The authors 2013. Published by Oxford University Press on behalf of the Institute of Mathematics and its Applications. All rights reserved. The squeeze-film flow of a thin layer of Newtonian fluid filling the gap between a flat impermeable surface moving under a prescribed constant load and a flat thin porous bed coating a stationary flat impermeable surface is considered. Unlike in the classical case of an impermeable bed, in which an infinite time is required for the two surfaces to touch, for a porous bed contact occurs in a finite contact time. Using a lubrication approximation, an implicit expression for the fluid layer thickness and an explicit expression for the contact time are obtained and analysed. In addition, the fluid particle paths are calculated, and the penetration depths of fluid particles into the porous bed are determined. In particular, the behaviour in the asymptotic limit of small permeability, in which the contact time is large but finite, is investigated. Finally, the results are interpreted in the context of lubrication in the human knee joint, and some conclusions are drawn about the contact time of the cartilage-coated femoral condyles and tibial plateau and the penetration of nutrients into the cartilage.
Amplified detection of protease activity using porous silicon nanostructures
Orosco, Manuel
This dissertation will focus on harnessing the optical properties of porous silicon to sense protease activity. Electrochemical etching of polished silicon wafers produces porous silicon with unique optical properties such as Fabry-Perot fringes or a dielectric mirror reflecting specific wavelengths. Porous silicon optical transducers are coupled to a biochemical reaction (protease activity) and optically measured in a label-free manner. The first chapter is an introductory chapter discussing the current methods of detecting protease activity. Also discussed is the use of porous silicon for label-free sensing. The second chapter discusses the use of thin protein layers that are spin coated on the surface of a porous silicon film and excluded from the porous matrix based on size. When active proteases are introduced to the protein layer, small peptide fragments are generated, causing a change in refractive index from low to high. This can be used as a tool to monitor protease activity and amplify the signal to the naked eye. To extend on the second chapter, a double layered porous silicon film with the first layer have large pores and the second layer etched below having small pores was used for sensing protease activity. Proteases are adsorbed into the first layer and introduction of whole protein substrate produces small peptide fragments that can enter the second layer (changing the effective optical thickness). The fourth chapter describes a method of using luminescent transducers coupled to protein films. An "on-off" sensor using protein coated luminescent porous silicon was used to detect a decrease in the intensity of luminescence due to degradation of the protein film. An "off-on" sensor involved a fluorescent dye housed in the porous film and capped with a protein coating. The release of the dye is caused by the action of a protease causing an increase in fluorescent intensity from the dye.
Anisotropic Inflation and Cosmological Observations
Emami, Razieh
2015-01-01
Recent observations opened up a new window on the inflationary model building. As it was firstly reported by the WMAP data, there may be some indications of statistical anisotropy on the CMB map, although the statistical significance of these findings are under debate. Motivated by these observations, people begun considering new inflationary models which may lead to statistical anisotropy. The simplest possible way to construct anisotropic inflation is to introduce vector fields. During the course of this thesis, we study models of anisotropic inflation and their observational implications such as power spectrum, bispectrum etc. Firstly we build a new model, which contains the gauge field which breaks the conformal invariance while preserving the gauge invariance. We show that in these kind of models, there can be an attractor phase in the evolution of the system when the back-reaction of the gauge field becomes important in the evolution of the inflaton field. We then study the cosmological perturbation the...
Stealths on Anisotropic Holographic Backgrounds
Ayón-Beato, Eloy; Juárez-Aubry, María Montserrat
2015-01-01
In this paper, we are interested in exploring the existence of stealth configurations on anisotropic backgrounds playing a prominent role in the non-relativistic version of the gauge/gravity correspondence. By stealth configuration, we mean a nontrivial scalar field nonminimally coupled to gravity whose energy-momentum tensor evaluated on the anisotropic background vanishes identically. In the case of a Lifshitz spacetime with a nontrivial dynamical exponent z, we spotlight the role played by the anisotropy to establish the holographic character of the stealth configurations, i.e. the scalar field is shown to only depend on the radial holographic direction. This configuration which turns out to be massless and without integration constants is possible for a unique value of the nonminimal coupling parameter. Then, using a simple conformal argument, we map this configuration into a stealth solution defined on the so-called hyperscaling violation metric which is conformally related to the Lifshitz spacetime. Thi...
Conductivities in an anisotropic medium
Khimphun, Sunly; Park, Chanyong
2016-01-01
In order to imitate anisotropic medium of a condensed matter system, we take into account an Einstein-Maxwell-dilaton-axion model as a dual gravity theory where the anisotropy is caused by different momentum relaxations. This gravity model allows an anisotropic charged black hole solution. On this background, we investigate how the linear responses of vector modes like electric, thermoelectric, and thermal conductivities rely on the anisotropy. We find that the electric conductivity in low frequency limit shows a Drude peak and that in the intermediate frequency regime it reveals the power law behavior. Especially, when the anisotropy increases the exponent of the power law becomes smaller. In addition, we find that there exist a critical value for the anisotropy at which the DC conductivity reaches to its maximum value.
Scattering characteristics from porous silicon
Directory of Open Access Journals (Sweden)
R. Sabet-Dariani
2000-12-01
Full Text Available Porous silicon (PS layers come into existance as a result of electrochemical anodization on silicon. Although a great deal of research has been done on the formation and optical properties of this material, the exact mechanism involved is not well-understood yet. In this article, first, the optical properties of silicon and porous silicon are described. Then, previous research and the proposed models about reflection from PS and the origin of its photoluminescence are reveiwed. The reflecting and scattering, absorption and transmission of light from this material, are then investigated. These experiments include,different methods of PS sample preparation their photoluminescence, reflecting and scattering of light determining different characteristics with respect to Si bulk.
Luminescence properties of Si-containing porous matrix–PbS nanoparticle systems
Energy Technology Data Exchange (ETDEWEB)
Tarasov, S. A., E-mail: satarasov@mail.ru; Aleksandrova, O. A.; Lamkin, I. A.; Maksimov, A. I.; Maraeva, E. V.; Mikhailov, I. I.; Moshnikov, V. A. [St. Petersburg State Electrotechnical University “LETI” (Russian Federation); Musikhin, S. F. [St. Petersburg State Polytechnic University (Russian Federation); Nalimova, S. S.; Permyakov, N. V.; Spivak, Yu. M.; Travkin, P. G. [St. Petersburg State Electrotechnical University “LETI” (Russian Federation)
2015-12-15
The luminescence properties of systems that contain lead-sulfide nanoparticles deposited onto substrates fabricated from porous silicon, oxidized porous silicon, and porous (tin-oxide)–(silicon-oxide) layers are studied. It is shown that the structure and composition of the matrix induce a strong effect on the luminescence spectra of colloidal quantum dots, defining their emission wavelength.
Institute of Scientific and Technical Information of China (English)
杨飒; 何国强; 李江; 刘洋; 李强; 孙翔宇; 胡淑芳
2011-01-01
In this paper, charring layers microstructures of EPDM insulation in different erosion conditions were analyzed,and the charring layers were determined as gas-saturated porous media with dense layer and porous layer . Particle erosion was classified into two groups; mechanical erosion and particle heating increment. Mechanical erosion model was established by analyzing the structure of charring layer under various state parameters of particle erosion, and particle heating increment was obtained by experiment tests. The formation of dense layer inside the charring layer was fit to the theory of CVD. The particle erosion model was coupled with thermo-chemical model considering the porous structure of charring layer. The numerical results for different erosion conditions were found to reasonably agree well with the available experimental data, and the calculate structures of charring layer were almost consistent with the photos of microscope.%分析不同颗粒冲刷状态下三元乙丙绝热材料炭化层的微观结构,确定炭化层为疏松多孔介质,整体结构为致密/疏松结构.颗粒侵蚀作用分为颗粒机械破坏和颗粒热增量,根据不同冲刷状态炭化层结构形态建立颗粒机械破坏模型；通过实验测试确定颗粒热增量模型.根据气相沉积原理拟合炭化层中致密结构,将颗粒侵蚀模型与考虑炭层孔隙结构的热化学烧蚀模型耦合,计算得到多个工况的炭化烧蚀率与实验结果吻合,且炭化层结构分布与实验得到的电镜结构基本一致.
Numerical modeling of boiling heat transfer in porous media
International Nuclear Information System (INIS)
Theoretical models were developed and validated to investigate boiling heat transfer in porous layers with and without the presence of chimneys. The critical heat flux and distributions of temperature, liquid saturation, liquid and vapor pressures, and liquid and vapor velocities were predicted numerically under typical PWR conditions. The results indicate that a porous layer produces a higher heat transfer coefficient in the nucleate boiling regime, as is well-known, and could potentially yield a much higher critical heat flux than a plain surface does. Moreover, a chimney-type porous layer can have a better thermal performance, i.e., heat transfer coefficient and critical heat flux than a homogeneous one, primarily due to the presence of chimneys providing pathways for vapor to escape from the porous layer with less resistance
Luminescent porous silicon prepared by reactive ion etching
International Nuclear Information System (INIS)
Realization of luminescent porous silicon structures by a sequential reactive ion etching is reported. The process is composed of one etching and two passivation subsequences. The impact of substrate resistivity, plasma power and the duration of the etching subsequence on the porosity and thickness of the fabricated porous silicon layer are investigated, as are the roles of two passivation subsequences. The porous silicon layer shows stable photoluminescence in the blue portion of the spectrum. Luminescence stability is due to the stable passivating oxyfluoride layer formed in the two passivation subsequences. Formation of the stable passivating layer is due to the controlled oxidation of the porous silicon surface and the passivation of the dangling bonds in the fluorination subsequence. Since the fabrication process is performed at room temperature, it can be used as a post-fabrication treatment to integrate light-emitting structures with microelectronic circuits. (paper)
Energy Technology Data Exchange (ETDEWEB)
BARTON,THOMAS J.; BULL,LUCY M.; KLEMPERER,WALTER G.; LOY,DOUGLAS A.; MCENANEY,BRIAN; MISONO,MAKOTO; MONSON,PETER A.; PEZ,GUIDO; SCHERER,GEORGE W.; VARTULI,JAMES C.; YAGHI,OMAR M.
1999-11-09
Tailoring of porous materials involves not only chemical synthetic techniques for tailoring microscopic properties such as pore size, pore shape, pore connectivity, and pore surface reactivity, but also materials processing techniques for tailoring the meso- and the macroscopic properties of bulk materials in the form of fibers, thin films and monoliths. These issues are addressed in the context of five specific classes of porous materials: oxide molecular sieves, porous coordination solids, porous carbons, sol-gel derived oxides, and porous heteropolyanion salts. Reviews of these specific areas are preceded by a presentation of background material and review of current theoretical approaches to adsorption phenomena. A concluding section outlines current research needs and opportunities.
Electrochemical properties of porous bismuth electrodes
Energy Technology Data Exchange (ETDEWEB)
Romann, T., E-mail: tavo.romann@ut.e [Institute of Chemistry, University of Tartu, Ravila 14A, 50411 Tartu (Estonia); Lust, E. [Institute of Chemistry, University of Tartu, Ravila 14A, 50411 Tartu (Estonia)
2010-08-01
The properties of Bi surfaces with different roughnesses were characterized by electron microscopy, cyclic voltammetry, and impedance spectroscopy. Two different strategies were used for preparation of porous bismuth layers onto Bi microelectrode surface in aqueous 0.1 M LiClO{sub 4} solution. Firstly, treatment at potential E < -2 V (vs. Ag|AgCl in sat. KCl) has been applied, resulting in bismuth hydride formation and decomposition into Bi nanoparticles which deposit at the electrode surface. Secondly, porous Bi layer was prepared by anodic dissolution (E = 1 V) of bismuth electrode followed by fast electroreduction of formed Bi{sup 3+} ions at cathodic potentials E = -2 V. The nanostructured porous bismuth electrode, with surface roughness factor up to 220, has negligible frequency dispersion of capacitance and higher hydrogen evolution overvoltage than observed for smooth Bi electrodes.
Institute of Scientific and Technical Information of China (English)
Zhang Laiping; Zhao Zhong; Chang Xinghua; He Xin
2013-01-01
A hybrid grid generation technique and a multigrid/parallel algorithm are presented in this paper for turbulence flow simulations over three-dimensional (3D) complex geometries.The hybrid grid generation technique is based on an agglomeration method of anisotropic tetrahedrons.Firstly,the complex computational domain is covered by pure tetrahedral grids,in which anisotropic tetrahedrons are adopted to discrete the boundary layer and isotropic tetrahedrons in the outer field.Then,the anisotropic tetrahedrons in the boundary layer are agglomerated to generate prismatic grids.The agglomeration method can improve the grid quality in boundary layer and reduce the grid quantity to enhance the numerical accuracy and efficiency.In order to accelerate the convergence history,a multigrid/parallel algorithm is developed also based on anisotropic agglomeration approach.The numerical results demonstrate the excellent accelerating capability of this multigrid method.
DEFF Research Database (Denmark)
Rasmussen, F.B.
2001-01-01
Different approaches to the analysis of Small Angle X-ray Scattering experiments on the porous aluminum-hydroxide pseudo-boehmite are compared. Experimental data is analyzed both as scattering from mass fractal aggregates and polydisperse collections of anisotropic particles. Both types of analys...
Production of Porous ZnSe by Electrochemical Etching Method
Directory of Open Access Journals (Sweden)
А.F. Dyadenchuk
2013-10-01
Full Text Available Here we describe the production features of a porous layer on the surface of n-type single-crystalline zinc selenide. The surface structure is investigated and the photomicrographs of porous layers of the treated ZnSe crystal are represented. Process of the mosaic structure formation depending on the etching time is considered. The value of the flat-band potential with respect to the used electrolyte is calculated.
Wave Interaction with Porous Coastal Structures
DEFF Research Database (Denmark)
Jensen, Bjarne
of structures are rubble mound breakwaters and berm breakwaters where common structural elements are core material, filter layers and armour layers. The armour stones serves as the main protection of the filter and core material against wave action. Therefore the armour stones must maintain stable when exposed...... are also applied as part of investigating and designing breakwaters. The models can provide more detailed information on some topics, such as pressure attenuation through the porous core material, while it is more difficult to simulate the direct destabilisation and movements of individual stones...... the contribution to generation of turbulence, and destabilizing shear stresses, from the wave breaking, the armour layer, and the porous core was singled out. In Chapter 3 a similar detailed approach was taken towards experimental investigation of the pressure induced forces in the filter layers below the main...
Simulation of uncompressible fluid flow through a porous media
Energy Technology Data Exchange (ETDEWEB)
Ramirez, A. [Instituto Politecnico Nacional (SEPI-ESIQIE-IPN), Unidad Profesional Zacatenco, Laboratorio de Analisis Met. (Edif. ' Z' y Edif. ' 6' P.B.), Mexico City (Mexico)], E-mail: adaramil@yahoo.com.mx; Gonzalez, J.L. [Instituto Politecnico Nacional (SEPI-ESIQIE-IPN), Unidad Profesional Zacatenco, Laboratorio de Analisis Met. (Edif. ' Z' y Edif. ' 6' P.B.), Mexico City (Mexico); Carrillo, F. [Instituto Politecnico Nacional (SEPI-CICATA-IPN), Unidad Altamira Tamaulipas, Mexico (Mexico); Lopez, S. [Instituto Mexicano del Petroleo (I.M.P.-D.F.), Mexico (Mexico)
2009-02-28
Recently, a great interest has been focused for investigations about transport phenomena in disordered systems. One of the most treated topics is fluid flow through anisotropic materials due to the importance in many industrial processes like fluid flow in filters, membranes, walls, oil reservoirs, etc. In this work is described the formulation of a 2D mathematical model to simulate the fluid flow behavior through a porous media (PM) based on the solution of the continuity equation as a function of the Darcy's law for a percolation system; which was reproduced using computational techniques reproduced using a random distribution of the porous media properties (porosity, permeability and saturation). The model displays the filling of a partially saturated porous media with a new injected fluid showing the non-defined advance front and dispersion of fluids phenomena.
Simulation of uncompressible fluid flow through a porous media
International Nuclear Information System (INIS)
Recently, a great interest has been focused for investigations about transport phenomena in disordered systems. One of the most treated topics is fluid flow through anisotropic materials due to the importance in many industrial processes like fluid flow in filters, membranes, walls, oil reservoirs, etc. In this work is described the formulation of a 2D mathematical model to simulate the fluid flow behavior through a porous media (PM) based on the solution of the continuity equation as a function of the Darcy's law for a percolation system; which was reproduced using computational techniques reproduced using a random distribution of the porous media properties (porosity, permeability and saturation). The model displays the filling of a partially saturated porous media with a new injected fluid showing the non-defined advance front and dispersion of fluids phenomena.
Propagation of plane waves in poroviscoelastic anisotropic media
Institute of Scientific and Technical Information of China (English)
A.K.Vashishth,M.D.Sharma
2008-01-01
This study discusses wave propagation in perhaps the most general model of a poroelastic medium.The medium is considered as a viscoelastic,anisotropic and porous solid frame such that its pores of anisotropic permeability are filled with a viscous fluid.The anisotropy considered is of general type,and the attenuating waves in the medium are treated as the inhomogeneous waves.The complex slowness vector is resolved to define the phase velocity,homogeneous attenuation,inhomogeneous attenuation,and angle of attenuation for each of the four attenuating waves in the medium.A non-dimensional parameter measures the deviation of an inhomogeneous wave from its homogeneous version.An numerical model of a North-Sea sandstone is used to analyze the effects of the propagation direction,inhomogeneity parameter,frequency regime,anisotropy symmetry,anelasticity of the frame,and viscosity of the pore-fluid on the propagation characteristics of waves in such a medium.
Spin precession in anisotropic cosmologies
Energy Technology Data Exchange (ETDEWEB)
Kamenshchik, A.Yu. [Universita di Bologna, Dipartimento di Fisica e Astronomia, Bologna (Italy); L. D. Landau Institute for Theoretical Physics, Moscow (Russian Federation); INFN, Bologna (Italy); Teryaev, O.V. [Joint Institute for Nuclear Research, Bogoliubov Laboratory of Theoretical Physics, Dubna (Russian Federation); Lomonosov Moscow State University, Moscow (Russian Federation)
2016-05-15
We consider the precession of a Dirac particle spin in some anisotropic Bianchi universes. This effect is present already in the Bianchi-I universe. We discuss in some detail the geodesics and the spin precession for both the Kasner and the Heckmann-Schucking solutions. In the Bianchi-IX universe the spin precession acquires the chaotic character due to the stochasticity of the oscillatory approach to the cosmological singularity. The related helicity flip of fermions in the very early universe may produce the sterile particles contributing to dark matter. (orig.)
Anisotropic and nonlinear optical waveguides
Someda, CG
1992-01-01
Dielectric optical waveguides have been investigated for more than two decades. In the last ten years they have had the unique position of being simultaneously the backbone of a very practical and fully developed technology, as well as an extremely exciting area of basic, forefront research. Existing waveguides can be divided into two sets: one consisting of waveguides which are already in practical use, and the second of those which are still at the laboratory stage of their evolution. This book is divided into two separate parts: the first dealing with anisotropic waveguides, an
New charged anisotropic compact models
Kileba Matondo, D.; Maharaj, S. D.
2016-07-01
We find new exact solutions to the Einstein-Maxwell field equations which are relevant in the description of highly compact stellar objects. The relativistic star is charged and anisotropic with a quark equation of state. Exact solutions of the field equations are found in terms of elementary functions. It is interesting to note that we regain earlier quark models with uncharged and charged matter distributions. A physical analysis indicates that the matter distributions are well behaved and regular throughout the stellar structure. A range of stellar masses are generated for particular parameter values in the electric field. In particular the observed mass for a binary pulsar is regained.
Remarks on inhomogeneous anisotropic cosmology
Kaya, Ali
2016-08-01
Recently a new no-global-recollapse argument was given for some inhomogeneous and anisotropic cosmologies that utilizes surface deformation by the mean curvature flow. In this paper we discuss important properties of the mean curvature flow of spacelike surfaces in Lorentzian manifolds. We show that singularities may form during cosmic evolution, and the theorems forbidding the global recollapse lose their validity. The time evolution of the spatial scalar curvature that may kinematically prevent the recollapse is determined in normal coordinates, which shows the impact of inhomogeneities explicitly. Our analysis indicates a caveat in numerical solutions that give rise to inflation.
Electroless porous silicon formation applied to fabrication of boron-silica-glass cantilevers
DEFF Research Database (Denmark)
Teva, Jordi; Davis, Zachary James; Hansen, Ole
2010-01-01
This work describes the characterization and optimization of anisotropic formation of porous silicon in large volumes (0.5-1 mm3) of silicon by an electroless wet etching technique. The main goal is to use porous silicon as a sacrificial volume for bulk micromachining processes, especially in cases...... where etching of the full wafer thickness is needed. The porous silicon volume is formed by a metal-assisted etching in a wet chemical solution composed of hydrogen peroxide (30%), hydrofluoric acid (40%) and ethanol. This paper focuses on optimizing the etching conditions in terms of maximizing...... for bio-chemical sensors. The porous silicon volume is formed in an early step of the fabrication process, allowing easy handling of the wafer during all of the micromachining processes in the process flow. In the final process step, the porous silicon is quickly etched by immersing the wafer in a KOH...
Ben Slama, Sonia; Hajji, Messaoud; Ezzaouia, Hatem
2012-01-01
Porous silicon layers were elaborated by electrochemical etching of heavily doped p-type silicon substrates. Metallization of porous silicon was carried out by immersion of substrates in diluted aqueous solution of nickel. Amorphous silicon thin films were deposited by plasma-enhanced chemical vapor deposition on metalized porous layers. Deposited amorphous thin films were crystallized under vacuum at 750°C. Obtained results from structural, optical, and electrical characterizations show that...
Indian Academy of Sciences (India)
M D Sharma
2007-08-01
Anisotropic wave propagation is studied in a fluid-saturated porous medium, using two different approaches. One is the dynamic approach of Biot’s theories. The other approach known as homogenisation theory, is based on the averaging process to derive macroscopic equations from the microscopic equations of motion. The medium considered is a general anisotropic poroelastic (APE) solid with a viscous fluid saturating its pores of anisotropic permeability. The wave propagation phenomenon in a saturated porous medium is explained through two relations. One defines modified Christoffel equations for the propagation of plane harmonic waves in the medium. The other defines a matrix to relate the relative displacement of fluid particles to the displacement of solid particles. The modified Christoffel equations are solved further to get a quartic equation whose roots represent complex velocities of the four attenuating quasi-waves in the medium. These complex velocities define the phase velocities of propagation and quality factors for attenuation of all the quasi-waves propagating along a given phase direction in three-dimensional space. The derivations in the mathematical models from different theories are compared in order to work out the equivalence between them. The variations of phase velocities and attenuation factors with the direction of phase propagation are computed, for a realistic numerical model. Differences between the velocities and attenuations of quasi-waves from the two approaches are exhibited numerically.
Electromagnetism on anisotropic fractal media
Ostoja-Starzewski, Martin
2013-04-01
Basic equations of electromagnetic fields in anisotropic fractal media are obtained using a dimensional regularization approach. First, a formulation based on product measures is shown to satisfy the four basic identities of the vector calculus. This allows a generalization of the Green-Gauss and Stokes theorems as well as the charge conservation equation on anisotropic fractals. Then, pursuing the conceptual approach, we derive the Faraday and Ampère laws for such fractal media, which, along with two auxiliary null-divergence conditions, effectively give the modified Maxwell equations. Proceeding on a separate track, we employ a variational principle for electromagnetic fields, appropriately adapted to fractal media, so as to independently derive the same forms of these two laws. It is next found that the parabolic (for a conducting medium) and the hyperbolic (for a dielectric medium) equations involve modified gradient operators, while the Poynting vector has the same form as in the non-fractal case. Finally, Maxwell's electromagnetic stress tensor is reformulated for fractal systems. In all the cases, the derived equations for fractal media depend explicitly on fractal dimensions in three different directions and reduce to conventional forms for continuous media with Euclidean geometries upon setting these each of dimensions equal to unity.
Refractive index contrast in porous silicon multilayers
Energy Technology Data Exchange (ETDEWEB)
Nava, R.; Mora, M.B. de la; Tagueena-Martinez, J. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Temixco, Morelos (Mexico); Rio, J.A. del [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Temixco, Morelos (Mexico); Centro Morelense de Innovacion y Transferencia Tecnologica, Consejo de Ciencia y Tecnologia del Estado de Morelos (Mexico)
2009-07-15
Two of the most important properties of a porous silicon multilayer for photonic applications are flat interfaces and a relative large refractive index contrast between layers in the optical wavelength range. In this work, we studied the effect of the current density and HF electrolyte concentration on the refractive index of porous silicon. With the purpose of increasing the refractive index contrast in a multilayer, the refractive index of porous silicon produced at low current was studied in detail. The current density applied to produce the low porosity layers was limited in order to keep the electrolyte flow through the multilayer structure and to avoid deformation of layer interfaces. We found that an electrolyte composed of hydrofluoric acid, ethanol and glycerin in a ratio of 3:7:1 gives a refractive index contrast around 1.3/2.8 at 600 nm. Several multilayer structures with this refractive index contrast were fabricated, such as dielectric Bragg mirrors and microcavities. Reflectance spectra of the structures show the photonic quality of porous silicon multilayers produced under these electrochemical conditions. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Shakedown analysis of anisotropic asphalt concrete pavements with clay subgrade
Energy Technology Data Exchange (ETDEWEB)
Boulbibane, M.; Collins, I.F. [Auckland Univ., Auckland (New Zealand). Dept. of Engineering Science; Weichert, D. [RWTH-Aachen Inst. of General Mechanics, Aachen (Germany); Raad, L. [Alaska-Fairbanks Univ., Fairbanks, AK (United States). Transportation and Research Centre
2000-08-04
A mathematical model has been presented which can predict the effect of inherent anisotropic cohesion on the long-term behaviour of multilayered pavements. The model is based on the lower bound theorem of shakedown analysis and makes allowances for variations of soil strength with direction. Pavements operating above the critical shakedown load exhibit plastic strains under long term repeated loading conditions and eventually result in deep ruts. This model was used to examine the influence of subgrade properties on the shakedown behaviour of two-layer pavement systems consisting of an asphalt concrete layer and a granular base over a clay subgrade. The shakedown load for pavements under repeated loadings was estimated and the effects of variables such as temperature, asphalt thickness, stiffness and strength were determined. The materials in the various layers of the pavement were modeled as elastic-plastic Mohr-Coulomb materials. 38 refs., 3 tabs., 5 figs.
Low-Q whispering gallery modes in anisotropic metamaterial shells
Díaz-Rubio, Ana; Torrent, Daniel; Sánchez-Dehesa, José
2013-01-01
Anisotropic and inhomogeneous metamaterial shells are studied in order to exploit all their resonant mode richness. These multilayer structures are based on a cylindrical distribution of radially dependent constitutive parameters including an inner void cavity. Shell, cavity and whispering gallery modes are characterized, and special attention is paid to the latter ones. The whispering gallery modes are created at the boundary layers of the shell with the background and energy localization is produced with highly radiative characteristics. These low-Q resonant states have frequencies that are independent of the shell thickness. However, their quality factors can be controlled by the number of layers forming the shell, which allows confining electromagnetic waves at the interface layers (internal or external), and make them suitable for the harvesting of electromagnetic energy.
Anisotropic Expansion of the Black Hole Universe
Zhang, Tianxi
2009-01-01
Recently, Zhang proposed a new cosmological model called black hole universe. According to this model, the universe originated from a hot star-like black hole with several solar masses, and grew up through a supermassive black hole with billion solar masses to the present state of temperature and density with hundred billion-trillion solar masses due to continuously inhaling matter from its outside. The structure of the entire space is similarly hierarchical or layered and the evolution is iterative. In each of iteration a universe passes through birth, growth, and death. The entire life of a universe roughly divides into three periods with different rates of expansion: slowly growing child universe, fast expanding adult universe, and gradually dying aged universe. When one universe expands to die out, a new universe grows up from its inside. On the AAS 211th meeting, the black hole universe model was shown to be consistent with Mach's principle, observations, and Einstein's general relativity. This new cosmological model can explain the cosmic microwave background radiation, quasars, and element abundances with the well-developed physics. Dark energy is not required for the universe to accelerate. Inflation is not necessary because the black hole universe does not have the horizon problem. In this presentation, the author will explain why the expansion of the universe is anisotropic as shown by the observed anisotropy of the Hubble constant. He will also compare the significant differences between the black hole universe and the big bang cosmology.
ANISOTROPIC POLARIZATION TENSORS FOR ELLIPSES AND ELLIPSOIDS
Institute of Scientific and Technical Information of China (English)
Hyeonbae Kang; Kyoungsun Kim
2007-01-01
In this paper we present a systematic way of computing the polarization tensors,anisotropic as well as isotropic, based on the boundary integral method. We then use this method to compute the anisotropic polarization tensor for ellipses and ellipsoids. The computation reveals the pair of anisotropy and ellipses which produce the same polarization tensors.
Anisotropic weak Hardy spaces and interpolation theorems
Institute of Scientific and Technical Information of China (English)
2008-01-01
In this paper, the authors establish the anisotropic weak Hardy spaces associated with very general discrete groups of dilations. Moreover, the atomic decomposition theorem of the anisotropic weak Hardy spaces is also given. As some applications of the above results, the authors prove some interpolation theorems and obtain the boundedness of the singular integral operators on these Hardy spaces.
ANISOTROPIC BIQUADRATIC ELEMENT WITH SUPERCLOSE RESULT
Institute of Scientific and Technical Information of China (English)
Dongyang SHI; Shipeng MAO; Hui LIANG
2006-01-01
The main aim of this paper is to study the convergence of biquadratic finite element for the second order problem on anisotropic meshes. By using some novel approaches and techniques, the optimal error estimates are obtained. At the same time, the anisotropic superclose results are also achieved. Furthermore, the numerical results are given to demonstrate our theoretical analysis.
Efficient Wavefield Extrapolation In Anisotropic Media
Alkhalifah, Tariq
2014-07-03
Various examples are provided for wavefield extrapolation in anisotropic media. In one example, among others, a method includes determining an effective isotropic velocity model and extrapolating an equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. The effective isotropic velocity model can be based upon a kinematic geometrical representation of an anisotropic, poroelastic or viscoelastic wavefield. Extrapolating the equivalent propagation can use isotopic, acoustic or elastic operators based upon the determined effective isotropic velocity model. In another example, non-transitory computer readable medium stores an application that, when executed by processing circuitry, causes the processing circuitry to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. In another example, a system includes processing circuitry and an application configured to cause the system to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield.
Multidisciplinary approach to cylindrical anisotropic metamaterials
International Nuclear Information System (INIS)
Anisotropic characteristics of cylindrically corrugated microstructures are analyzed in terms of their acoustic and electromagnetic (EM) behavior paying special attention to their differences and similarities. A simple analytical model has been developed using effective medium theory to understand the anisotropic features of both types of waves in terms of radial and angular components of the wave propagation velocity. The anisotropic constituent parameters have been obtained by measuring the resonances of cylindrical cavities, as well as from numerical simulations. This permits one to characterize propagation of acoustic and EM waves and to compare the fundamental anisotropic features generated by the corrugated effective medium. Anisotropic coefficients match closely in both physics fields but other relevant parameters show significant differences in the behavior of both types of waves. (paper)
Designing Anisotropic Inflation with Form Fields
Ito, Asuka
2015-01-01
We study inflation with anisotropic hair induced by form fields. In four dimensions, the relevant form fields are gauge (one-form) fields and two-form fields. Assuming the exponential form of potential and gauge kinetic functions, we find new exact power-law solutions endowed with anisotropic hair. We also explore the phase space of anisotropic inflation and find fixed points corresponding to the exact power-law solutions. Moreover, we perform the stability analysis around the fixed points to reveal the structure of the phase space. It turns out that one of the fixed points becomes an attractor and others (if any) are saddle points. In particular, the one corresponding to anisotropic inflation becomes an attractor when it exists. We also argue that various anisotropic inflation models can be designed by choosing coupling constants.
Designing anisotropic inflation with form fields
Ito, Asuka; Soda, Jiro
2015-12-01
We study inflation with anisotropic hair induced by form fields. In four dimensions, the relevant form fields are gauge (one-form) fields and two-form fields. Assuming the exponential form of potential and gauge kinetic functions, we find new exact power-law solutions endowed with anisotropic hair. We also explore the phase space of anisotropic inflation and find fixed points corresponding to the exact power-law solutions. Moreover, we perform the stability analysis around the fixed points to reveal the structure of the phase space. It turns out that one of the fixed points becomes an attractor and others (if any) are saddle points. In particular, the one corresponding to anisotropic inflation becomes an attractor when it exists. We also argue that various anisotropic inflation models can be designed by choosing coupling constants.
Synthesis of anisotropic gold shell on carbon nanotube
Energy Technology Data Exchange (ETDEWEB)
Minati, L., E-mail: luminati@fbk.eu [CNR-IFN, CSMFO Lab. (Italy); Torrengo, S. [FBK (Italy); Ischia, G. [University of Trento, Department of Industrial Engineering (Italy); Speranza, G. [FBK (Italy)
2013-11-15
This paper reports a simple procedure to synthesize gold-coated carbon nanotubes. The method involves the reduction of gold precursor on oxidized carbon nanotubes. UV–Visible absorption spectroscopy and electron microscopy were used to study the gold precursor reduction on the carbon nanotubes. Scanning and transmission electron microscopy analysis showed the formation of an irregular gold layer around the CNT surface. The resulting nanoparticles show an anisotropic shape with dimensions between 100 and 200 nm. This hybrid material displays an intense absorption in the near infrared range with an absorption maximum at 840 nm.
Image theory for electric dipoles above a conducting anisotropic earth
Mahmoud, S. F.
1984-07-01
New image representations for vertical electric dipoles (VED) above an imperfectly conducting and axially anisotropic earth are developed. These include multidiscrete images at different depths below the air-earth interface and multipole image sources. It is shown that, in contrast with the available image representations in the literature, the developed ones predict the correct behavior of the fields in the far zone along the earth's surface. Extension to a layered earth's model is made. The theory is also extended to the horizontal electric dipole with similar conclusions to the case of the vertical dipole.
Gaussian beam diffraction in weakly anisotropic inhomogeneous media
Energy Technology Data Exchange (ETDEWEB)
Kravtsov, Yu.A., E-mail: kravtsov@am.szczecin.p [Institute of Physics, Maritime University of Szczecin, Szczecin 70-500 (Poland); Space Research Institute, Russian Academy of Science, Moscow 117 997 (Russian Federation); Berczynski, P., E-mail: pawel.berczynski@ps.p [Institute of Physics, West Pomeranian University of Technology, Szczecin 70-310 (Poland); Bieg, B., E-mail: b.bieg@am.szczecin.p [Institute of Physics, Maritime University of Szczecin, Szczecin 70-500 (Poland)
2009-08-10
Combination of quasi-isotropic approximation (QIA) of geometric optics with paraxial complex geometric optics (PCGO) is suggested, which allows describing both diffraction and polarization evolution of Gaussian electromagnetic beams in weakly anisotropic inhomogeneous media. Combination QIA/PCGO reduces Maxwell equations to the system of the ordinary differential equations of the first order and radically simplifies solution of various problems, related to microwave plasma diagnostics, including plasma polarimetry, interferometry and refractometry in thermonuclear reactors. Efficiency of the method is demonstrated by the example of electromagnetic beam diffraction in a linear layer of magnetized plasma with parameters, modeling tokamak plasma in the project ITER.
Gaussian beam diffraction in weakly anisotropic inhomogeneous media
International Nuclear Information System (INIS)
Combination of quasi-isotropic approximation (QIA) of geometric optics with paraxial complex geometric optics (PCGO) is suggested, which allows describing both diffraction and polarization evolution of Gaussian electromagnetic beams in weakly anisotropic inhomogeneous media. Combination QIA/PCGO reduces Maxwell equations to the system of the ordinary differential equations of the first order and radically simplifies solution of various problems, related to microwave plasma diagnostics, including plasma polarimetry, interferometry and refractometry in thermonuclear reactors. Efficiency of the method is demonstrated by the example of electromagnetic beam diffraction in a linear layer of magnetized plasma with parameters, modeling tokamak plasma in the project ITER.
Gaussian beam diffraction in weakly anisotropic inhomogeneous media
Kravtsov, Yu. A.; Berczynski, P.; Bieg, B.
2009-08-01
Combination of quasi-isotropic approximation (QIA) of geometric optics with paraxial complex geometric optics (PCGO) is suggested, which allows describing both diffraction and polarization evolution of Gaussian electromagnetic beams in weakly anisotropic inhomogeneous media. Combination QIA/PCGO reduces Maxwell equations to the system of the ordinary differential equations of the first order and radically simplifies solution of various problems, related to microwave plasma diagnostics, including plasma polarimetry, interferometry and refractometry in thermonuclear reactors. Efficiency of the method is demonstrated by the example of electromagnetic beam diffraction in a linear layer of magnetized plasma with parameters, modeling tokamak plasma in the project ITER.
Angular dependence of anisotropic magnetoresistance in magnetic systems
Zhang, Steven S.-L.; Zhang, Shufeng
2014-05-01
Anisotropic magnetoresistance (AMR), whose physical origin is attributed to the combination of spin dependent scattering and spin orbital coupling (SOC), usually displays simple angular dependence for polycrystalline ferromagnetic metals. By including generic spin dependent scattering and spin Hall (SH) terms in the Ohm's law, we explicitly show that various magneto-transport phenomena such as anomalous Hall (AH), SH, planar Hall (PH) and AMR could be quantitatively related for bulk polycrystalline ferromagnetic metals. We also discuss how AMR angular dependence is affected by the presence of interfacial SOC in magnetic layered structure.
Characteristics of porous zirconia coated with hydroxyapatite as human bones
Indian Academy of Sciences (India)
V V Narulkar; S Prakash; K Chandra
2007-08-01
Since hydroxyapatite has excellent biocompatibility and bone bonding ability, porous hydroxyapatite ceramics have been intensively studied. However, porous hydroxyapatite bodies are mechanically weak and brittle, which makes shaping and implantation difficult. One way to solve this problem is to introduce a strong porous network onto which hydroxyapatite coating is applied. In this study, porous zirconia and alumina-added zirconia ceramics were prepared by ceramic slurry infiltration of expanded polystyrene bead compacts, followed by firing at 1500°C. Then slurry of hydroxyapatite–borosilicate glass mixed powder was used to coat the porous ceramics, followed by firing at 1200°C. The porous structures without the coating had high porosities of 51–69%, high pore interconnectivity, and sufficiently large pore window sizes (300–500 m). The porous ceramics had compressive strengths of 5.3∼36.8 MPa, favourably comparable to the mechanical properties of cancellous bones. In addition, porous hydroxyapatite surface was formed on the top of the composite coating, whereas a borosilicate glass layer was found on the interface. Thus, porous zirconia-based ceramics were modified with a bioactive composite coating for biomedical applications.
Nanotube Arrays in Porous Anodic Alumina Membranes
Institute of Scientific and Technical Information of China (English)
Liang LI; Naoto KOSHIZAKI; Guanghai LI
2008-01-01
This review summarizes the various techniques developed for fabricating nanotube arrays in porous anodic alumina membranes (AAMs). After a brief introduction to the fabrication process of AAMs, taking carbons, metals, semiconductors, organics, biomoleculars, and heterojunctions as typical examples, attention will be focused on the recently established methods to fabricate nanotubes in AAM, including electrochemical deposition, surface sol-gel, modified chemical vapor deposition, atomic layer deposition, and layer-by-layer growth. Every method is demonstrated by one or two reported results. Finally, this review is concluded with some perspectives on the research directions and focuses on the AAM-based nanotubes fields.
Gashinova, M S; Kolmakov, Y A; Vendik, I B
2002-01-01
The electrodynamic analysis of the arbitrary multilayer medium, including the anisotropic layers and containing the arbitrary form conductors is carried out. Thin layers of the high-temperature superconductor (HTSC) are considered as conductors. Determination of the surface current density is a result of the numerical solution. Accounting for the losses in the HTSC is accomplished on the basis of determining the equivalent surface impedance and using the Leontovich boundary conditions. Anisotropy is accounted for in the determination of the Green spectral dyad for the structure with arbitrary number of the anisotropic or isotropic layers. Calculation of the surface current density distribution demonstrates the correctness of the proposed model
Bejan, A
2006-01-01
Provides an introduction to convection in porous media, such as fibrous insulation, geological strata, and catalytic reactors. This third edition covers ""designed"" porous media, the theory of deformable media, modeling viscous dissipation in hyperporous media, and more. It is useful for researchers, practicing engineers and students.
Hierarchical Porous Structures
Energy Technology Data Exchange (ETDEWEB)
Grote, Christopher John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2016-06-07
Materials Design is often at the forefront of technological innovation. While there has always been a push to generate increasingly low density materials, such as aero or hydrogels, more recently the idea of bicontinuous structures has gone more into play. This review will cover some of the methods and applications for generating both porous, and hierarchically porous structures.
One-way Penetration of the Boundary Wave in Anisotropic Structures
Directory of Open Access Journals (Sweden)
A.D. Arkhipov
2012-06-01
Full Text Available One-way penetration of the boundary wave in single-layer and multilayer anisotropic structures is investigated. We show that the conditions for minimal wave reflection from one side and full wave reflection from another side of the structure are possible. No conversation of polarization can be obtained for the considered effect.
Fresnel analysis of Kretschmann geometry with a uniaxial crystal layer on a three-layered film
Directory of Open Access Journals (Sweden)
Yu-Ju Hung
2016-04-01
Full Text Available The use of total internal reflection within the prism coupling scheme is a simple approach to the generation of surface plasmon polariton waves on a metal/dielectric interface. Unfortunately, an anisotropic layer on a metallic film complicates the derivation of resonance angle. In this study, we present clear Fresnel analysis of a liquid crystal film on a metal surface. Few current simulation packages enable the analysis of multiple layers with a single anisotropic layer. The proposed formulation process is applicable to multi-layered structures.
Warm anisotropic inflationary universe model
Energy Technology Data Exchange (ETDEWEB)
Sharif, M.; Saleem, Rabia [University of the Punjab, Department of Mathematics, Lahore (Pakistan)
2014-02-15
This paper is devoted to the study of warm inflation using vector fields in the background of a locally rotationally symmetric Bianchi type I model of the universe. We formulate the field equations, and slow-roll and perturbation parameters (scalar and tensor power spectra as well as their spectral indices) in the slow-roll approximation. We evaluate all these parameters in terms of the directional Hubble parameter during the intermediate and logamediate inflationary regimes by taking the dissipation factor as a function of the scalar field as well as a constant. In each case, we calculate the observational parameter of interest, i.e., the tensor-scalar ratio in terms of the inflaton. The graphical behavior of these parameters shows that the anisotropic model is also compatible with WMAP7 and the Planck observational data. (orig.)
Warm Anisotropic Inflationary Universe Model
Sharif, M
2014-01-01
This paper is devoted to study the warm inflation using vector fields in the background of locally rotationally symmetric Bianchi type I universe model. We formulate the field equations, slow-roll and perturbation parameters (scalar and tensor power spectra as well as their spectral indices) under slow-roll approximation. We evaluate all these parameters in terms of directional Hubble parameter during intermediate and logamediate inflationary regimes by taking the dissipation factor as a function of scalar field as well as a constant. In each case, we calculate the observational parameter of interest, i.e., tensor-scalar ratio in terms of inflation. The graphical behavior of these parameters shows that the anisotropic model is also compatible with WMAP7 and Planck observational data.
Anisotropic scaling of magnetohydrodynamic turbulence
Horbury, T S; Oughton, S
2008-01-01
We present a quantitative estimate of the anisotropic power and scaling of magnetic field fluctuations in inertial range magnetohydrodynamic turbulence, using a novel wavelet technique applied to spacecraft measurements in the solar wind. We show for the first time that, when the local magnetic field direction is parallel to the flow, the spacecraft-frame spectrum has a spectral index near 2. This can be interpreted as the signature of a population of fluctuations in field-parallel wavenumbers with a $k_{\\parallel}^{-2}$ spectrum but is also consistent with the presence of a "critical balance" style turbulent cascade. We also find, in common with previous studies, that most of the power is contained in wavevectors at large angles to the local magnetic field and that this component of the turbulence has a spectral index of 5/3.
Gravitational baryogenesis after anisotropic inflation
Fukushima, Mitsuhiro; Mizuno, Shuntaro; Maeda, Kei-ichi
2016-05-01
The gravitational baryogensis may not generate a sufficient baryon asymmetry in the standard thermal history of the Universe when we take into account the gravitino problem. Hence, it has been suggested that anisotropy of the Universe can enhance the generation of the baryon asymmetry through the increase of the time change of the Ricci scalar curvature. We study the gravitational baryogenesis in the presence of anisotropy, which is produced at the end of an anisotropic inflation. Although we confirm that the generated baryon asymmetry is enhanced compared with the original isotropic cosmological model, taking into account the constraint on the anisotropy by the recent CMB observations, we find that it is still difficult to obtain the observed baryon asymmetry only through the gravitational baryogenesis without suffering from the gravitino problem.
Yagi, Kent
2015-01-01
Certain physical quantities that characterize neutron stars and quark stars (e.g. their mass, spin angular momentum and quadrupole moment) are interrelated in a way that is approximately insensitive to their internal structure. Such approximately universal relations are useful to break degeneracies in data analysis for future radio, X-ray and gravitational wave observations. Although the pressure inside compact stars is most likely nearly isotropic, certain scenarios have been put forth that suggest otherwise, for example due to phase transitions. We here investigate whether pressure anisotropy affects the approximate universal relations and whether it prevents their use in future observations. We achieve this by numerically constructing slowly-rotating and tidally-deformed, anisotropic, compact stars in General Relativity to third order in spin. We find that anisotropy affects the universal relations only weakly; the relations become less universal by a factor of 1.5-3 relative to the isotropic case, but rem...
Gravitational Baryogenesis after Anisotropic Inflation
Fukushima, Mitsuhiro; Maeda, Kei-ichi
2016-01-01
The gravitational baryogensis may not generate a sufficient baryon asymmetry in the standard thermal history of the Universe when we take into account the gravitino problem. Hence it has been suggested that anisotropy of the Universe can enhance the generation of the baryon asymmetry through the increase of the time change of the Ricci scalar curvature. We study the gravitational baryogenesis in the presence of anisotropy, which is produced at the end of an anisotropic inflation. Although we confirm that the generated baryon asymmetry is enhanced compared with the original isotropic cosmological model, taking into account the constraint on the anisotropy by the recent CMB observations, we find that it is still difficult to obtain the observed baryon asymmetry only through the gravitational baryogenesis without suffering from the gravitino problem.
Instability of plane-parallel flow of incompressible liquid over a saturated porous medium
Lyubimova, T. P.; Lyubimov, D. V.; Baydina, D. T.; Kolchanova, E. A.; Tsiberkin, K. B.
2016-07-01
The linear stability of plane-parallel flow of an incompressible viscous fluid over a saturated porous layer is studied to model the instability of water flow in a river over aquatic plants. The saturated porous layer is bounded from below by a rigid plate and the pure fluid layer has a free, undeformable upper boundary. A small inclination of the layers is imposed to simulate the riverbed slope. The layers are inclined at a small angle to the horizon. The problem is studied within two models: the Brinkman model with the boundary conditions by Ochoa-Tapia and Whitaker at the interface, and the Darcy-Forchheimer model with the conditions by Beavers and Joseph. The neutral curves and critical Reynolds numbers are calculated for various porous layer permeabilities and relative thicknesses of the porous layer. The results obtained within the two models are compared and analyzed.
The Anisotropic Geometrodynamics For Cosmology
Siparov, Sergey V.
2009-05-01
The classical geometrodynamics (GRT) and its modern features based on the use of the Fridman-Robertson-Walker type metrics are still unable to explain several important issues of extragalactic observations like flat rotation curves of the spiral galaxies, Tully-Fisher law, globular clusters behavior in comparisson to that of the stars belonging to the galactic plane etc. The chalenging problem of the Universe expansion acceleration stemming from the supernovae observations demands the existence of the repulsion forces which brings one to the choice between the cosmological constant and some quintessence. The popular objects of discussion are now still dark (matter and energy), nevertheless, they are supposed to correspond to more than 95% of the Universe which seems to be far from satisfactory. According to the equivalence principle we can not experimentally distinguish between the inertial forces and the gravitational ones. Since there exist the inertial forces depending on velocity (Coriolis), it seems plausible to explore the velocity dependent gravitational forces. From the mathematical point of view it means that we should use the anisotropic metric. It immediately turns out that the expression for the Einstein-Hilbert action changes in a natural way - contrary to the cases of f(R)-theories, additional scalar fields, arbitrary MOND functions etc.. We use the linear approximation for the metric and derive the generalized geodesics and the equation for the gravity force that contains not only the Newton-Einstein term. The relation between the obtained results and those of Lense-Thirring approach are discussed. The resulting anisotropic geometrodynamics includes all the results of the GRT and is used to give the explanation to the problems mentioned above. One of the impressive consequences is the possibility to explain the observed Hubble red shift not by the Doppler effect as usually but by the gravitational red shift originating from the metric anisotropy.
Anisotropic microstructure near the sun
International Nuclear Information System (INIS)
Radio scattering observations provide a means of measuring a two-dimensional projection of the three-dimensional spatial spectrum of electron density, i.e., in the plane perpendicular to the line of sight. Earlier observations have shown that the microstructure at scales of the order of 10 km becomes highly field-aligned inside of 10 R· [Armstrong et al., 1990]. Earlier work has also shown that density fluctuations at scales larger than 1000 km have a Kolmogorov spectrum, whereas the smaller scale structure has a flatter spectrum and is considerably enhanced above the Kolmogorov ''background'' [Coles et al., 1991]. Here we present new observations made during 1990 and 1992. These confirm the earlier work, which was restricted to one source on a few days, but they suggest that the anisotropy changes abruptly near 6 R· which was not clear in the earlier data. The axial ratio measurements are shown on Figure 1 below. The new observations were made with a more uniform sampling of the spatial plane. They show that contours of constant correlation are elliptical. This is apparently inconsistent with the spatial correlation of the ISEE-3 magnetic field which shows a 'Maltese Cross' shape [Matthaeus et al., 1990]. However this inconsistency may be only apparent: the magnetic field and density correlations need not have the same shape; the scale of the magnetic field correlations is at least 4 orders of magnitude larger; they are much further from the sun; and they are point measurements whereas ours are path-integrated. We also made two simultaneous measurements, at 10 R·, of the anisotropy on scales of 200 to 4000 km. Significant anisotropy was seen on the smaller scales, but the larger scale structure was essentially isotropic. This suggests that the process responsible for the anisotropic microstructure is independent of the larger scale isotropic turbulence. It is then tempting to speculate that the damping of this anisotropic process inside of 6 R· contributes to
Energy Technology Data Exchange (ETDEWEB)
Maruska, P [Spire Corp., Bedford, MA (United States)
1996-09-01
The goal of the program was to demonstrate use of porous silicon in new solar cell structures. Porous silicon technology has been developed at Spire for producing visible light-emitting diodes (LEDs). The major aspects that they have demonstrated are the following: porous silicon active layers have been made to show photovoltaic action; porous silicon surface layers can act as antireflection coatings to improve the performance of single-crystal silicon solar cells; and porous silicon surface layers can act as antireflection coatings on polycrystalline silicon solar cells. One problem with the use of porous silicon is to achieve good lateral conduction of electrons and holes through the material. This shows up in terms of poor blue response and photocurrents which increase with increasing reverse bias applied to the diode.
Qin, C.Z.; Hassanizadeh, S.M.
2014-01-01
In this work, we propose a new approach to modeling multiphase flow and solute transport through a stack of thin porous layers. Currently, numerical simulation of thin layers involves discretization across the layer thickness. In our new approach, thin porous layers are treated as a bunch of two-dim
International Nuclear Information System (INIS)
The earliest high-Tc oxide superconductors were generally studied in the form of porous polycrystalline pellets. As material preparation technology improved, resulting in samples with orientational order and a smaller concentration of impurity phases, the effects of granular behaviour did not disappear. In both the cases of disordered and partially-ordered structures, an important question arises as to how to interpret measured low-field resistivities in terms of the underlying anisotropic single-crystal values. This paper provides the answer to this question within the context of an effective-medium theory. The authors version of the effective-medium approximation attempts to describe the electrical properties of an inhomogeneous medium, consisting of a mixture of several types of anisotropic polycrystals with different degrees of orientational order. (author)
Erbium doped stain etched porous silicon
Energy Technology Data Exchange (ETDEWEB)
Gonzalez-Diaz, B. [Departamento de Fisica Basica, Universidad de La Laguna, Avda. Astrofisico Francisco Sanchez, 38204 La Laguna, S/C de Tenerife (Spain); Diaz-Herrera, B. [Departamento de Energia Fotovoltaica, Instituto Tecnologico de Energias Renovables (ITER), Poligono Industrial de Granadilla, 38611 S/C Tenerife (Spain); Guerrero-Lemus, R. [Departamento de Fisica Basica, Universidad de La Laguna, Avda. Astrofisico Francisco Sanchez, 38204 La Laguna, S/C de Tenerife (Spain)], E-mail: rglemus@ull.es; Mendez-Ramos, J.; Rodriguez, V.D. [Departamento de Fisica Fundamental, Experimental Electronica y Sistemas, Universidad de La Laguna, Avda. Astrofisico Francisco Sanchez, 38204 La Laguna, S/C de Tenerife (Spain); Hernandez-Rodriguez, C. [Departamento de Fisica Basica, Universidad de La Laguna, Avda. Astrofisico Francisco Sanchez, 38204 La Laguna, S/C de Tenerife (Spain); Martinez-Duart, J.M. [Departamento de Fisica Aplicada, C-XII, Universidad Autonoma de Madrid, 28049 Cantoblanco, Madrid (Spain)
2008-01-15
In this work a simple erbium doping process applied to stain etched porous silicon layers (PSLs) is proposed. This doping process has been developed for application in porous silicon solar cells, where conventional erbium doping processes are not affordable because of the high processing cost and technical difficulties. The PSLs were formed by immersion in a HF/HNO{sub 3} solution to properly adjust the porosity and pore thickness to an optimal doping of the porous structure. After the formation of the porous structure, the PSLs were analyzed by means of nitrogen BET (Brunauer, Emmett and Teller) area measurements and scanning electron microscopy. Subsequently, the PSLs were immersed in a saturated erbium nitrate solution in order to cover the porous surface. Then, the samples were subjected to a thermal process to activate the Er{sup 3+} ions. Different temperatures and annealing times were used in this process. The photoluminescence of the PSLs was evaluated before and after the doping processes and the composition was analyzed by Fourier transform IR spectroscopy.
3-D Isotropic and Anisotropic S-velocity Structure in the North American Upper Mantle
Yuan, H.; Marone, F.; Romanowicz, B.; Abt, D.; Fischer, K.
2008-12-01
The tectonic diversity of the North American continent has led to a number of geological, tectonic and geodynamical models, many of which can be better tested with high resolution 3-d tomographic models of the isotropic and anisotropic mantle structure of the continent. In the framework of non-linear asymptotic coupling theory (NACT), we recently developed tools to invert long period seismic waveforms combined with SKS splitting data, for both isotropic and radial and azimuthal anisotropic S-wave velocity structure in the upper mantle at the continental scale (Marone et al., 2007; Marone and Romanowicz, 2007). Striking differences in both isotropic and anisotropic velocity structure were observed: beneath the high velocity stable cratonic region a distinct two-layer anisotropic domain is present, with the bottom layer fast axis direction aligned with the absolute plate motion, and a shallower lithospheric layer with north pointing fast axis most likely showing records of past tectonic history; under the active western US the direction of tomographically inferred anisotropy is stable with depth and compatible with the absolute plate motion direction. Here we present an updated model which includes nearly five more years of data, including data from newly operative USArray stations, and a somewhat more extended frequency band. Our new model confirms our previous results, and reveals greater yet complex details of the anisotropic velocity structure beneath the western U.S.. We also show initial results of incorporating constraints on the depth to the lithosphere-asthenosphere boundary (LAB) using teleseismic receiver functions. We discuss the different anisotropic domains resolved both laterally and in depth, in the context of tectonic history of the north American continent.
A new algorithm for anisotropic solutions
Indian Academy of Sciences (India)
M Chaisi; S D Maharaj
2006-02-01
We establish a new algorithm that generates a new solution to the Einstein field equations, with an anisotropic matter distribution, from a seed isotropic solution. The new solution is expressed in terms of integrals of an isotropic gravitational potential; and the integration can be completed exactly for particular isotropic seed metrics. A good feature of our approach is that the anisotropic solutions necessarily have an isotropic limit. We find two examples of anisotropic solutions which generalise the isothermal sphere and the Schwarzschild interior sphere. Both examples are expressed in closed form involving elementary functions only.
Nanostructure Neutron Converter Layer Development
Park, Cheol (Inventor); Sauti, Godfrey (Inventor); Kang, Jin Ho (Inventor); Lowther, Sharon E. (Inventor); Thibeault, Sheila A. (Inventor); Bryant, Robert G. (Inventor)
2016-01-01
Methods for making a neutron converter layer are provided. The various embodiment methods enable the formation of a single layer neutron converter material. The single layer neutron converter material formed according to the various embodiments may have a high neutron absorption cross section, tailored resistivity providing a good electric field penetration with submicron particles, and a high secondary electron emission coefficient. In an embodiment method a neutron converter layer may be formed by sequential supercritical fluid metallization of a porous nanostructure aerogel or polyimide film. In another embodiment method a neutron converter layer may be formed by simultaneous supercritical fluid metallization of a porous nanostructure aerogel or polyimide film. In a further embodiment method a neutron converter layer may be formed by in-situ metalized aerogel nanostructure development.
Annealing effect on InP vertical porous arrays
Institute of Scientific and Technical Information of China (English)
无
2010-01-01
InP vertical porous arrays were produced using electrochemical etching at room temperature.The as-etched InP samples were annealed in an ultra high vacuum camber.Cross-sectional analysis of the porous layer was conducted using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX).Annealing in vacuum was found to meliorate the structural quality of the porous layer.EDX results showed the composition change of the porous InP.By controlling the annealing process parameters,the content ratio of phosphorus (P) to indium (In) is tuneable.Raman property of the samples was also investigated at room temperature.Compared with the sample without annealing treatment,Raman spectrum from the annealed sample showed red-shifted LO and TO peaks together with sharpened LO peak and shortened TO peak.
Tunneling Anisotropic Magnetoresistance in Co/AlOx/Au Tunnel Junctions
Liu, R S; Canali, C M; Samuelson, L; Pettersson, H
2008-01-01
We observe spin-valve-like effects in nano-scaled thermally evaporated Co/AlOx/Au tunnel junctions. The tunneling magnetoresistance is anisotropic and depends on the relative orientation of the magnetization direction of the Co electrode with respect to the current direction. We attribute this effect to a two-step magnetization reversal and an anisotropic density of states resulting from spin-orbit interaction. The results of this study points to future applications of novel spintronics devices involving only one ferromagnetic layer.
Tunneling anisotropic magnetoresistance in Co/AlOx/Au tunnel junctions.
Liu, R S; Michalak, L; Canali, C M; Samuelson, L; Pettersson, H
2008-03-01
We observe spin-valve-like effects in nanoscaled thermally evaporated Co/AlOx/Au tunnel junctions. The tunneling magnetoresistance is anisotropic and depends on the relative orientation of the magnetization direction of the Co electrode with respect to the current direction. We attribute this effect to a two-step magnetization reversal and an anisotropic density of states resulting from spin-orbit interaction. The results of this study points to future applications of novel spintronics devices involving only one ferromagnetic layer. PMID:18254603
Study of porous silicon surface by mass spectroscopy methods
Берченко, Микола Миколайович; Єрохов, Валерій Юрійович; Нічкало, Степан Ігорович; Бережанський, Євген Іванович
2014-01-01
Silicon surfaces of multicrystalline substrates before and after the formation of porous silicon on them, used in the production of photovoltaic cells were studied by mass spectrometry methods. An analysis of the elemental surface composition by mass spectroscopy of secondary ions at various manufacturing stages, including before and after electrochemical etching to create a porous silicon layer was conducted in the research. Clean surfaces before etching in an electrolyte based on hydrofluor...
Ultimate permeation across atomically thin porous graphene.
Celebi, Kemal; Buchheim, Jakob; Wyss, Roman M; Droudian, Amirhossein; Gasser, Patrick; Shorubalko, Ivan; Kye, Jeong-Il; Lee, Changho; Park, Hyung Gyu
2014-04-18
A two-dimensional (2D) porous layer can make an ideal membrane for separation of chemical mixtures because its infinitesimal thickness promises ultimate permeation. Graphene--with great mechanical strength, chemical stability, and inherent impermeability--offers a unique 2D system with which to realize this membrane and study the mass transport, if perforated precisely. We report highly efficient mass transfer across physically perforated double-layer graphene, having up to a few million pores with narrowly distributed diameters between less than 10 nanometers and 1 micrometer. The measured transport rates are in agreement with predictions of 2D transport theories. Attributed to its atomic thicknesses, these porous graphene membranes show permeances of gas, liquid, and water vapor far in excess of those shown by finite-thickness membranes, highlighting the ultimate permeation these 2D membranes can provide. PMID:24744372
Collisionless magnetic reconnection under anisotropic MHD approximation
Hirabayashi, Kota; Hoshino, Masahiro
We study the formation of slow-mode shocks in collisionless magnetic reconnection by using one- and two-dimensional collisionless magneto-hydro-dynamic (MHD) simulations based on the double adiabatic approximation, which is an important step to bridge the gap between the Petschek-type MHD reconnection model accompanied by a pair of slow shocks and the observational evidence of the rare occasion of in-situ slow shock observation. According to our results, a pair of slow shocks does form in the reconnection layer. The resultant shock waves, however, are quite weak compared with those in an isotropic MHD from the point of view of the plasma compression and the amount of the magnetic energy released across the shock. Once the slow shock forms, the downstream plasma are heated in highly anisotropic manner and a firehose-sense (P_{||}>P_{⊥}) pressure anisotropy arises. The maximum anisotropy is limited by the marginal firehose criterion, 1-(P_{||}-P_{⊥})/B(2) =0. In spite of the weakness of the shocks, the resultant reconnection rate is kept at the same level compared with that in the corresponding ordinary MHD simulations. It is also revealed that the sequential order of propagation of the slow shock and the rotational discontinuity, which appears when the guide field component exists, changes depending on the magnitude of the guide field. Especially, when no guide field exists, the rotational discontinuity degenerates with the contact discontinuity remaining at the position of the initial current sheet, while with the slow shock in the isotropic MHD. Our result implies that the slow shock does not necessarily play an important role in the energy conversion in the reconnection system and is consistent with the satellite observation in the Earth's magnetosphere.
Combustion Characteristics of Butane Porous Burner for Thermoelectric Power Generation
Directory of Open Access Journals (Sweden)
K. F. Mustafa
2015-01-01
Full Text Available The present study explores the utilization of a porous burner for thermoelectric power generation. The porous burner was tested with butane gas using two sets of configurations: single layer porcelain and a stacked-up double layer alumina and porcelain. Six PbSnTe thermoelectric (TE modules with a total area of 54 cm2 were attached to the wall of the burner. Fins were also added to the cold side of the TE modules. Fuel-air equivalence ratio was varied between the blowoff and flashback limit and the corresponding temperature, current-voltage, and emissions were recorded. The stacked-up double layer negatively affected the combustion efficiency at an equivalence ratio of 0.20 to 0.42, but single layer porcelain shows diminishing trend in the equivalence ratio of 0.60 to 0.90. The surface temperature of a stacked-up porous media is considerably higher than the single layer. Carbon monoxide emission is independent for both porous media configurations, but moderate reduction was recorded for single layer porcelain at lean fuel-air equivalence ratio. Nitrogen oxides is insensitive in the lean fuel-air equivalence ratio for both configurations, even though slight reduction was observed in the rich region for single layer porcelain. Power output was found to be highly dependent on the temperature gradient.
Anisotropic surface tension of buckled fluid membrane
Noguchi, Hiroshi
2011-01-01
Solid sheets and fluid membranes exhibit buckling under lateral compression. Here, it is revealed that fluid membranes have anisotropic buckling surface tension contrary to solid sheets. Surprisingly, the surface tension perpendicular to the buckling direction shows stronger dependence than that parallel to it. Our theoretical predictions are supported by numerical simulations of a meshless membrane model. This anisotropic tension can be used to measure the membrane bending rigidity. It is al...
Theory of Compton scattering by anisotropic electrons
Poutanen, Juri; Vurm, Indrek
2010-01-01
Compton scattering plays an important role in various astrophysical objects such as accreting black holes and neutron stars, pulsars, and relativistic jets, clusters of galaxies as well as the early Universe. In most of the calculations it is assumed that the electrons have isotropic angular distribution in some frame. However, there are situations where the anisotropy may be significant due to the bulk motions, or anisotropic cooling by synchrotron radiation, or anisotropic source of seed so...
Anisotropic rectangular metric for polygonal surface remeshing
Pellenard, Bertrand
2013-06-18
We propose a new method for anisotropic polygonal surface remeshing. Our algorithm takes as input a surface triangle mesh. An anisotropic rectangular metric, defined at each triangle facet of the input mesh, is derived from both a user-specified normal-based tolerance error and the requirement to favor rectangle-shaped polygons. Our algorithm uses a greedy optimization procedure that adds, deletes and relocates generators so as to match two criteria related to partitioning and conformity.
Rainbow metric from quantum gravity: anisotropic cosmology
Assanioussi, Mehdi; Dapor, Andrea
2016-01-01
In this paper we present a construction of effective cosmological models which describe the propagation of a massive quantum scalar field on a quantum anisotropic cosmological spacetime. Each obtained effective model is represented by a rainbow metric in which particles of distinct momenta propagate on different classical geometries. Our analysis shows that upon certain assumptions and conditions on the parameters determining such anisotropic models, we surprisingly obtain a unique deformatio...
Anisotropic cosmological solutions in massive vector theories
Heisenberg, Lavinia; Kase, Ryotaro; Tsujikawa, Shinji
2016-01-01
In beyond-generalized Proca theories including the extension to theories higher than second order, we study the role of a spatial component $v$ of a massive vector field on the anisotropic cosmological background. We show that, as in the case of the isotropic cosmological background, there is no additional ghostly degrees of freedom associated with the Ostrogradski instability. In second-order generalized Proca theories we find the existence of anisotropic solutions on which the ratio between...
Anisotropic Stars: Exact Solutions and Stability
Dev, Krsna; Gleiser, Marcelo
2004-01-01
I report on recent work concerning the existence and stability of self-gravitating spheres with anisotropic pressure. After presenting new exact solutions, Chandrasekhar's variational formalism for radial perturbations is generalized to anisotropic objects and applied to investigate their stability. It is shown that anisotropy can not only support stars of mass M and radius R with 2M/R > 8/9 and arbitrarily large surface redshifts, but that stable configurations exist for values of the adiaba...
Stochastic porous media equations
Barbu, Viorel; Röckner, Michael
2016-01-01
Focusing on stochastic porous media equations, this book places an emphasis on existence theorems, asymptotic behavior and ergodic properties of the associated transition semigroup. Stochastic perturbations of the porous media equation have reviously been considered by physicists, but rigorous mathematical existence results have only recently been found. The porous media equation models a number of different physical phenomena, including the flow of an ideal gas and the diffusion of a compressible fluid through porous media, and also thermal propagation in plasma and plasma radiation. Another important application is to a model of the standard self-organized criticality process, called the "sand-pile model" or the "Bak-Tang-Wiesenfeld model". The book will be of interest to PhD students and researchers in mathematics, physics and biology.
Energy Technology Data Exchange (ETDEWEB)
Hajji, M., E-mail: mhajji2001@yahoo.fr [Laboratoire de Photovoltaïque, Centre de Recherche et des Technologies de l’Energie, Technopôle de Borj-Cédria BP 95, Hammam-Lif 2050 (Tunisia); Institut Supérieur d’Electronique et de Communication de Sfax, route Menzel Chaker Km 0.5, BP 868, Sfax 3018 (Tunisia); Khalifa, M.; Slama, S. Ben; Ezzaouia, H. [Laboratoire de Photovoltaïque, Centre de Recherche et des Technologies de l’Energie, Technopôle de Borj-Cédria BP 95, Hammam-Lif 2050 (Tunisia)
2013-11-01
This paper presents a new method to produce porous silicon which derived from the conventional stain etching (SE) method. But instead of one etching step that leads to formation of porous layer, the substrate is subjected to an initial etching step with a duration Δt{sub 0} followed by a number of supplementary short steps that differs from a layer to another. The duration of the initial step is just the necessary time to have a homogenous porous layer on the whole surface of the substrate. It was found that this duration is largely dependent of the doping type and level of the silicon substrate. The duration of supplementary steps was kept as short as possible to prevent the formation of bubbles on the silicon surface during silicon dissolution which leads generally to inhomogeneous porous layers. It is found from surface investigation by atomic force microscopy (AFM) that multistep stain etching (MS-SE) method allows to produce homogeneous porous silicon nanostructures compared to the conventional SE method. The chemical composition of the obtained porous layers has been evaluated using Fourier transform infrared spectroscopy (FTIR). Photoluminescence (PL) measurement shows that porous layers produced by SE and MS-SE methods have comparable spectra indicating that those layers are composed of nanocrystallites with comparable sizes. But the intensity of photoluminescence of layer elaborated by MS-SE method is higher than that elaborated by the SE method. Total reflectance characteristics show that the presented method allows the production of porous silicon layers with controllable thicknesses and optical properties. Results for porous silicon layers elaborated on heavily doped n-type silicon show that the reflectance can be reduced to values less than 3% in the major part of the spectrum.
Extending the Lifespan of Porous Asphalt Concrete
Zhang, Y.
2015-01-01
Porous Asphalt (PA) concrete is widely used as a surfacing layer on highways in the Netherlands. The service life of PA wearing courses is limited because of the fact that it is vulnerable to raveling. The possibilities of applying preventive maintenance to PA wearing courses by means of spraying rejuvenation products on the pavement surfaces are being investigated with high interest in the Netherlands. A material which has the ability to penetrate into the bituminous binder and soften (rejuv...
Anisotropic diffusion-limited aggregation.
Popescu, M N; Hentschel, H G E; Family, F
2004-06-01
Using stochastic conformal mappings, we study the effects of anisotropic perturbations on diffusion-limited aggregation (DLA) in two dimensions. The harmonic measure of the growth probability for DLA can be conformally mapped onto a constant measure on a unit circle. Here we map m preferred directions for growth to a distribution on the unit circle, which is a periodic function with m peaks in [-pi,pi) such that the angular width sigma of the peak defines the "strength" of anisotropy kappa= sigma(-1) along any of the m chosen directions. The two parameters (m,kappa) map out a parameter space of perturbations that allows a continuous transition from DLA (for small enough kappa ) to m needlelike fingers as kappa--> infinity. We show that at fixed m the effective fractal dimension of the clusters D(m,kappa) obtained from mass-radius scaling decreases with increasing kappa from D(DLA) approximately 1.71 to a value bounded from below by D(min) = 3 / 2. Scaling arguments suggest a specific form for the dependence of the fractal dimension D(m,kappa) on kappa for large kappa which compares favorably with numerical results. PMID:15244564