Enhanced magnetocaloric effect material
Lewis, Laura J. H.
2006-07-18
A magnetocaloric effect heterostructure having a core layer of a magnetostructural material with a giant magnetocaloric effect having a magnetic transition temperature equal to or greater than 150 K, and a constricting material layer coated on at least one surface of the magnetocaloric material core layer. The constricting material layer may enhance the magnetocaloric effect by restriction of volume changes of the core layer during application of a magnetic field to the heterostructure. A magnetocaloric effect heterostructure powder comprising a plurality of core particles of a magnetostructural material with a giant magnetocaloric effect having a magnetic transition temperature equal to or greater than 150 K, wherein each of the core particles is encapsulated within a coating of a constricting material is also disclosed. A method for enhancing the magnetocaloric effect within a giant magnetocaloric material including the step of coating a surface of the magnetocaloric material with a constricting material is disclosed.
Who discovered the magnetocaloric effect?
DEFF Research Database (Denmark)
Smith, Anders
2013-01-01
A magnetic body changes its thermal state when subjected to a changing magnetic field. In particular, if done under adiabatic conditions, its temperature changes. For the past 15 years the magnetocaloric effect has been the focus of significant research due to its possible application for efficient...... refrigeration near room temperature. At the same time, it has become common knowledge within the magnetic refrigeration research community that the magnetocaloric effect was discovered by the German physicist E. Warburg in 1881. We re-examine the original literature and show that this is a misleading reading...
Magnetic Refrigeration and the Magnetocaloric Effect
DEFF Research Database (Denmark)
Petersen, Thomas Frank; Pryds, Nini; Smith, Anders;
2006-01-01
Magnetic refrigeration at room temperature is an emerging technology for refrigeration, which promises low energy consumption and is environmentalle friendly. Magnetic refrigeration is based on the magnetocaloric effect, which manifests itself as a reversibel increase in temperature when magnetic...... material are plased in a magnetic field. This paper introduces and describes magnetic refrigeration cycles and the magnetocaloric effect, and shows how magnetic refrigeration can be an alternative to vapour-compression refrigeration,. A review of the Danish research on magnetic refrigeration at Risø...
Magnetocaloric effect: Overcoming the magnetic limit
Energy Technology Data Exchange (ETDEWEB)
Plaza, E.J.R. [Instituto de Fisica ' Gleb Wataghin' , Universidade Estadual de Campinas, Unicamp, Zeferino Vaz s/n, 13083-970 Campinas, SP (Brazil); Instituto de Fisica, Universidade do Estado do Rio de Janeiro-UERJ, Rua Sao Francisco Xavier, 524, 20550-013 RJ (Brazil)], E-mail: plaza@ifi.unicamp.br; Campoy, J.C.P. [Instituto de Fisica ' Gleb Wataghin' , Universidade Estadual de Campinas, Unicamp, Zeferino Vaz s/n, 13083-970 Campinas, SP (Brazil)
2009-03-15
We have studied anomalous peaks observed in magnetocaloric -{delta}S(T) curves for systems that undergo first-order magnetostructural transitions. The origin of those peaks, which can exceed the conventional magnetic limit, R ln(2J+1), is discussed on thermodynamic bases by introducing an additional-exchange contribution (due to exchange constant variation arising from magnetostructural transition). We also applied a semiphenomenological model to include this additional-exchange contribution in Gd{sub 5}Si{sub 2}Ge{sub 2}- and MnAs-based systems, obtaining excellent results for the observed magnetocaloric effect.
Magnetocaloric effect: Overcoming the magnetic limit
Plaza, E. J. R.; Campoy, J. C. P.
2009-03-01
We have studied anomalous peaks observed in magnetocaloric -Δ S( T) curves for systems that undergo first-order magnetostructural transitions. The origin of those peaks, which can exceed the conventional magnetic limit, R ln(2 J+1), is discussed on thermodynamic bases by introducing an additional-exchange contribution (due to exchange constant variation arising from magnetostructural transition). We also applied a semiphenomenological model to include this additional-exchange contribution in Gd 5Si 2Ge 2- and MnAs-based systems, obtaining excellent results for the observed magnetocaloric effect.
Magnetocaloric effect at cryogenic temperature in gadolinium oxide nanotubes
Paul, Rima; Paramanik, Tapas; Das, Kalipada; Sen, Pintu; Satpati, B.; Das, I.
2016-11-01
We have synthesized fascinating nano-structure of Gadolinium oxide (Gd2O3) using controlled template-assisted electrochemical deposition technique which showed interesting anisotropic magnetic behavior. The nanotubes of Gd2O3 with average diameter 200 nm, length 10 μm and wall thickness 20 nm are constituted of nanoclusters with average diameter 7.5 nm. The tubes are aligned and are almost uniform throughout their length. Detailed magnetic measurements of aligned Gd2O3 nanotubes have been performed for both parallel and perpendicular magnetic field orientations with respect to the axis of the Gd2O3 nanotube array. Significant differences in magnetization values have been observed between the parallel and perpendicular orientations. Experimental results indicate the superparamagnetic nature of the nanomaterial. Large magnetocaloric effect, associated with the sharp change in magnetization of the Gd2O3 nanotubes, has been observed in the cryogenic temperature regime that shows anisotropic behavior.
Magnetocaloric Studies of the Peak Effect in Nb
Daniilidis, N. D.; Dimitrov, I. K.; Mitrovic, V F; Elbaum, C.; Ling, X. S.
2006-01-01
We report a magnetocaloric study of the peak effect and Bragg glass transition in a Nb single crystal. The thermomagnetic effects due to vortex flow into and out of the sample are measured. The magnetocaloric signature of the peak effect anomaly is identified. It is found that the peak effect disappears in magnetocaloric measurements at fields significantly higher than those reported in previous ac-susceptometry measurements. Investigation of the superconducting to normal transition reveals t...
Evaluating the effect of magnetocaloric properties on magnetic refrigeration performance
Engelbrecht, Kurt; Bahl, Christian Robert Haffenden
2010-01-01
Active magnetic regenerator (AMR) refrigerators represent an alternative to vapor compression technology that relies on the magnetocaloric effect in a solid refrigerant. Magnetocaloric materials are in development and properties are reported regularly. Recently, there has been an emphasis on developing materials with a high entropy change with magnetization while placing lower emphasis on the adiabatic temperature change. This work uses model magnetocaloric materials and a numerical AMR model...
Review of the magnetocaloric effect in manganite materials
Phan, Manh-Huong; Yu, Seong-Cho
2007-01-01
A thorough understanding of the magnetocaloric properties of existing magnetic refrigerant materials has been an important issue in magnetic refrigeration technology. This paper reviews a new class of magnetocaloric material, that is, the ferromagnetic perovskite manganites (R 1-xM xMnO 3, where R=La, Nd, Pr and M=Ca, Sr, Ba, etc.). The nature of these materials with respect to their magnetocaloric properties has been analyzed and discussed systematically. A comparison of the magnetocaloric effect of the manganites with other materials is given. The potential manganites are nominated for a variety of large- and small-scale magnetic refrigeration applications in the temperature range of 100-375 K. It is believed that the manganite materials with the superior magnetocaloric properties in addition to cheap materials-processing cost will be the option of future magnetic refrigeration technology.
Evaluating the effect of magnetocaloric properties on magnetic refrigeration performance
DEFF Research Database (Denmark)
Engelbrecht, Kurt; Bahl, Christian Robert Haffenden
2010-01-01
on developing materials with a high entropy change with magnetization while placing lower emphasis on the adiabatic temperature change. This work uses model magnetocaloric materials and a numerical AMR model to predict how the temperature change and entropy change with magnetization interact and how they affect......Active magnetic regenerator (AMR) refrigerators represent an alternative to vapor compression technology that relies on the magnetocaloric effect in a solid refrigerant. Magnetocaloric materials are in development and properties are reported regularly. Recently, there has been an emphasis...
Magnetocaloric effect in ferroelectric Ising chain magnet
Qi, Yan; Liu, Jia; Yu, Nai-sen; Du, An
2016-05-01
We investigate the magnetocaloric effect (MCE) in multiferroic chain system by adopting the elastic Ising-chain model. Based on the transfer-matrix method, the magnetothermal quantities of characterizing MCE behaviors including the entropy, entropy change and adiabatic cooling rate are rigorously determined. Combined with analysis of ground-state, we mainly discuss results in an antiferromagnetic regime associated with ferroelectric transition. Our results show that the entropy change is greatly enhanced near the saturation field as frustration parameter varies in this regime, and accompanied with remarkable inverse MCE, indicating the enormous potential of multiferroic system in low-temperature refrigeration. Meanwhile we also observe a prominent temperature variation in the isoentropy curves close to zero-temperature ferroelectric transition, but this enhancing MCE signal is very sensitive to the thermal fluctuations, and can be strongly suppressed even under a small temperature.
Tunable magnetocaloric effect in transition metal alloys
Belyea, Dustin D.; Lucas, M. S.; Michel, E.; Horwath, J.; Miller, Casey W.
2015-10-01
The unpredictability of geopolitical tensions and resulting supply chain and pricing instabilities make it imperative to explore rare earth free magnetic materials. As such, we have investigated fully transition metal based “high entropy alloys” in the context of the magnetocaloric effect. We find the NiFeCoCrPdx family exhibits a second order magnetic phase transition whose critical temperature is tunable from 100 K to well above room temperature. The system notably displays changes in the functionality of the magnetic entropy change depending on x, which leads to nearly 40% enhancement of the refrigerant capacity. A detailed statistical analysis of the universal scaling behavior provides direct evidence that heat treatment and Pd additions reduce the distribution of exchange energies in the system, leading to a more magnetically homogeneous alloy. The general implications of this work are that the parent NiFeCoCr compound can be tuned dramatically with FCC metal additives. Together with their relatively lower cost, their superior mechanical properties that aid manufacturability and their relative chemical inertness that aids product longevity, NiFeCoCr-based materials could ultimately lead to commercially viable magnetic refrigerants.
The effect of demagnetization on the magnetocaloric properties of gadolinium
DEFF Research Database (Denmark)
Bahl, Christian Robert Haffenden; Nielsen, Kaspar Kirstein
2009-01-01
Gadolinium displays a strong magnetocaloric effect at temperatures close to room temperature making it useful in the field of room temperature magnetic refrigeration. We discuss the importance of including the effects of the demagnetization field when considering the magnetocaloric properties...... of gadolinium. The adiabatic temperature change DeltaTad of gadolinium sheets upon application of a magnetic field has been measured at a range of applied magnetic fields and sample orientations. A significant dependence of DeltaTad on the sample orientation is observed. This can be accounted...
Thermodynamic model of the magnetocaloric effect near the first-order magnetic phase transitions
Energy Technology Data Exchange (ETDEWEB)
Spichkin, Y.I. [Advanced Magnetic Technologies and Consulting, Ltd., Moscow 115114 (Russian Federation)]. E-mail: spichkin@ndfeb.ru; Tishin, A.M. [Physics Faculty of M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation)
2005-04-15
Magnetocaloric effect (MCE) arising in the materials with the first-order magnetic phase transitions (such as heavy rare earth metals, FeRh and GdSiGe alloys, lanthanides) has been considered in the framework of thermodynamic approach. The exchange, magnetoelastic, anisotropic and magnetic energy contributions to the MCE and their temperature dependences were calculated in the vicinity of the first-order transition. It was shown that the model adequately describes the MCE and gives the values of the adiabatic temperature change and isothermal magnetic entropy change, which are in accord with direct experimental measurements. Possible mechanisms of the MCE near the first-order transitions are discussed.
Barocaloric and Magnetocaloric Effects in Fe49Rh51
Stern-Taulats, E.; Planes, Antoni; Lloveras Muntané, Pol Marcel; Barrio Casado, María del; Tamarit Mur, José Luis; Pramanick, Sabyasachi; Majumdar, Subham; Frontera, Carlos; Mañosa, Lluís
2014-01-01
We report on calorimetry under applied hydrostatic pressure and magnetic field at the antiferromagnetic (AFM)-ferromagnetic (FM) transition of Fe$_{49}$Rh$_{51}$. Results demonstrate the existence of a giant barocaloric effect in this alloy, a new functional property that adds to the magnetocaloric and elastocaloric effects previously reported for this alloy. All caloric effects originate from the AFM/FM transition which encompasses changes in volume, magnetization and entropy. The strong sen...
Consequenses of the magnetocaloric effect on magnetometry measurements
DEFF Research Database (Denmark)
Hansen, Britt Rosendahl; Bahl, Christian Robert Haffenden; Kuhn, Luise Theil;
2010-01-01
Magnetization curves recorded at high sweep-rates on magnetic materials near a phase transition temperature can be affected by temperature changes in the material due to the magnetocaloric effect. This change in the sample temperature is a result of the quasiadiabatic conditions that can occur...... and without a direct measurement of the sample temperature, one can determine an appropriate sweep-rate of the magnetic field....
International Nuclear Information System (INIS)
A simple thermodynamic theory is proposed for the quantitative description of giant magnetocaloric effect observed in metamagnetic shape memory alloys. Both the conventional magnetocaloric effect at the Curie temperature and the inverse magnetocaloric effect at the transition from the ferromagnetic austenite to a weakly magnetic martensite are considered. These effects are evaluated from the Landau-type free energy expression involving exchange interactions in a system of a two magnetic sublattices. The findings of the thermodynamic theory agree with first-principles calculations and experimental results from Ni-Mn-In-Co and Ni-Mn-Sn alloys, respectively
Energy Technology Data Exchange (ETDEWEB)
L' vov, Victor A. [Institute of Magnetism, Kyiv 03142 (Ukraine); Taras Shevchenko National University, Kyiv 01601 (Ukraine); Kosogor, Anna, E-mail: annakosogor@gmail.com [Institute of Magnetism, Kyiv 03142 (Ukraine); National University of Science and Technology ‘MISiS’, Moscow 119049 (Russian Federation); Barandiaran, Jose M. [BCMaterials and University of Basque Country, UPV/EHU, Bilbao 48080 (Spain); Chernenko, Volodymyr A. [BCMaterials and University of Basque Country, UPV/EHU, Bilbao 48080 (Spain); Ikerbasque, Basque Foundation for Science, Bilbao 48013 (Spain)
2016-01-07
A simple thermodynamic theory is proposed for the quantitative description of giant magnetocaloric effect observed in metamagnetic shape memory alloys. Both the conventional magnetocaloric effect at the Curie temperature and the inverse magnetocaloric effect at the transition from the ferromagnetic austenite to a weakly magnetic martensite are considered. These effects are evaluated from the Landau-type free energy expression involving exchange interactions in a system of a two magnetic sublattices. The findings of the thermodynamic theory agree with first-principles calculations and experimental results from Ni-Mn-In-Co and Ni-Mn-Sn alloys, respectively.
Magnetocaloric effect in ribbon samples of Heusler alloys Ni-Mn-M (M=In,Sn)
Aliev, A. M.; Batdalov, A. B.; Kamilov, I. K.; Koledov, V. V.; Shavrov, V. G.; Buchelnikov, V. D.; García, J.; Prida, V. M.; Hernando, B.
2010-11-01
Direct measurements of the magnetocaloric effect in samples of rapidly quenched ribbons of Mn50Ni40In10 and Ni50Mn37Sn13 Heusler alloys with potential applications in magnetic refrigeration technology are carried out. The measurements were made by a precise method based on the measurement of the oscillation amplitude of the temperature in the sample while is subjected to a modulated magnetic field. In the studied compositions both direct and inverse magnetocaloric effects associated with magnetic (paramagnet-ferromagnet-antiferromagnet) and structural (austenite-martensite) phase transitions are found. Additional inverse magnetocaloric effects of small value are observed around the ferromagnetic transitions.
Inconvenient magnetocaloric effect in ferromagnetic shape memory alloys
Energy Technology Data Exchange (ETDEWEB)
Khovaylo, Vladimir, E-mail: khovaylo@misis.ru [National University of Science and Technology “MISiS”, Moscow 119049 (Russian Federation)
2013-11-15
Highlights: ► Critical analysis of the available experimental results on isothermal magnetic entropy change in ferromagnetic shape memory alloys Ni–Mn–X (X = Ga, In, Sn, Sb) is given. ► Based on available in literature experimental data on total entropy change at martensitic transformation it is shown that the isothermal magnetic entropy change in Ni–Mn–X (X = Ga, In, Sn, Sb) should not greatly exceed 30 J/kg K. -- Abstract: Critical analysis available in the literature experimental results on magnetocaloric effect in ferromagnetic shape memory alloys Ni–Mn–X (X = Ga, In, Sn, Sb) is given. Based on a model developed by Pecharsky et al. [22], it is shown that the isothermal magnetic field-induced entropy change in the Ni–Mn–X alloys should not greatly exceed 30 J/kg K. Considering thermodynamics of temperature- and magnetic field-induced martensitic transformations, it is demonstrated that a contribution of the structural subsystem to the magnetocaloric effect in the Ni–Mn–X alloys studied so far is irreversible in magnetic fields below 5 T. This makes ferromagnetic shape memory alloys an inconvenient system for the practical application in modern magnetic refrigeration technology.
Magnetocaloric effect in rare-earth intermetallics: Recent trends
Indian Academy of Sciences (India)
R Nirmala; A V Morozkin; S K Malik
2015-06-01
Magnetocaloric effect (MCE) is the change in isothermal magnetic entropy (m)and adiabatic temperature (ad) that accompany magnetic transitions in materials during the application or the removal of magnetic field under adiabatic conditions. The physics of MCE gets enriched by correlated spin-lattice degrees of freedom. This phenomenon has been actively investigated over the past few decades as it holds a promise for an alternate method of refrigeration/heat pumping. This has already resulted in several reviews on this topic. This paper focusses on some recent trends in this field and prospects of using rare-earth-based materials as active magnetic refrigerants over a broad temperature range that includes gas liquefaction and near-room temperature refrigeration/heating.
Large magnetocaloric effect in sintered ferromagnetic EuS
Matsumoto, Koichi; Li, Liang; Hirai, Shinji; Nakamura, Eiji; Murayama, Daiki; Ura, Yutaro; Abe, Satoshi
2016-10-01
We present magnetocaloric effect measurements of the ferromagnetic semiconductor EuS in the vicinity of its ordering temperature. Single phase EuS powder was synthesized by CS2 gas sulfurization of Eu2O3. A sintered compact with relative density over 95% was prepared by pulsed electric current sintering of the powder. Temperature and magnetic field dependence of the magnetization and specific heat were characteristic of a paramagnetic to ferromagnetic second order phase transition. The entropy change induced by an external magnetic field and the specific heat were both close to those of a single crystal. We obtained an entropy-temperature (S-T) diagram of the EuS sintered compact. Carnot cycle liquefaction of hydrogen using EuS was compared with several other materials, with results indicating that sintered EuS is an excellent magnetic refrigerant for hydrogen liquefaction.
DEFF Research Database (Denmark)
Lipsø, Hans Kasper Wigh; Nielsen, Kaspar Kirstein; Christensen, Dennis;
2011-01-01
The effect of demagnetization in a stack of gadolinium plates is determined experimentally by using spatially resolved measurements of the adiabatic temperature change due to the magnetocaloric effect. The number of plates in the stack, the spacing between them and the position of the plate...
Competing-fluctuation-induced anomalous magnetocaloric effects in perovskite manganites
Sakai, Hideaki; Taguchi, Yasujiro; Tokura, Yoshinori
2010-03-01
A magnetocaloric (MC) effect refers to the isothermal entropy change induced by applying (or removing) a magnetic field to the materials, which is a performance index of the magnetic refrigeration technology. In this study, the variation of MC effects has been systematically investigated for colossal magnetoresistive manganites R0.6Sr0.4MnO3 (R=La-Gd) by controlling the R-dependent one-electron bandwidth. With decreasing the bandwidth, the temperature profile of entropy change exhibits a larger peak at the ferromagnetic transition temperature and a steeper drop below it, due to the first-order nature of the transition promoted by a competing charge-orbital ordering instability. For the smallest-bandwidth systems adjacent to the metal- insulator phase boundary, a rectangular-shaped profile for the entropy change emerges with an anomalously wide temperature range. Model calculations have indicated that the bicritical fluctuation enhanced in the phase-competing region has a strong impact on such MC features [1]. [1] H. Sakai et al., J. Phys. Soc. Jpn. 78, 113708 (2009).
Colossal magnetocaloric effect in magneto-auxetic systems
Dudek, M. R.; Wojciechowski, K. W.; Grima, J. N.; Caruana-Gauci, R.; Dudek, K. K.
2015-08-01
We show that a mechanically driven magnetocaloric effect (MCE) in magneto-auxetic systems (MASs) in the vicinity of room temperature is possible and the effect can be colossal. Even at zero external magnetic field, the magnetic entropy change in this reversible process can be a few times larger in magnitude than in the case of the giant MCE discovered by Pecharsky and Gschneidner in Gd5(Si2Ge2). MAS represent a novel class of metamaterials having magnetic insertions embedded within a non-magnetic matrix which exhibits a negative Poisson’s ratio. The auxetic behaviour of the non-magnetic matrix may either enhance the magnetic ordering process or it may result in a transition to the disordered phase. In the MAS under consideration, a spin 1/2 system is chosen for the magnetic component and the well-known Onsager solution for the two-dimensional square lattice Ising model at zero external magnetic field is used to show that the isothermal change in magnetic entropy accompanying the auxetic behaviour can take a large value at room temperature. The practical importance of our findings is that MCE materials used in present engineering applications may be further enhanced by changing their geometry such that they exhibit auxetic behaviour.
Giant enhancement of magnetocaloric effect in metallic glass matrix composite
Institute of Scientific and Technical Information of China (English)
WANG YongTian; BAI HaiYang; PAN MingXiang; ZHAO DeQian; WANG WeiHua
2008-01-01
The magnetocaloric effect (MCE) has made great success in very low temperature refrigeration, which is highly desirable for application to the extended higher tem-perature range. Here we report the giant enhancement of MCE in the metallic glass composite. The large magnetic refrigerant capacity (RC) up to 103 J·kg-1 is more than double the RC of the well-known crystalline magnetic refrigerant compound Gd5Si2Ge1.9Fe0.1 (357 J·kg-1) and MnFeP0.45As0.55 (390 J·kg-1)(containing either ex-orbitant-cost Ge or poisonous As). The full width at half maximum of the magnetic entropy change (△Sm) peak almost spreads over the whole low-temperature range (from 303 to 30 K), which is five times wider than that of the Gd5Si2Ge1.9Fe0.1 and pure Gd. The maximum △Sm approaches a nearly constant value in a wide tem-perature span over 100 K, and however, such a broad table-like region near room temperature has seldom been found in alloys and compounds. In combination with the intrinsic amorphous nature, the metallic glass composite may be potential for the ideal Ericsson-cycle magnetic refrigeration over a broad temperature range near room temperature.
Giant enhancement of magnetocaloric effect in metallic glass matrix composite
Institute of Scientific and Technical Information of China (English)
2008-01-01
The magnetocaloric effect (MCE) has made great success in very low temperature refrigeration, which is highly desirable for application to the extended higher tem-perature range. Here we report the giant enhancement of MCE in the metallic glass composite. The large magnetic refrigerant capacity (RC) up to 103 J·kg-1 is more than double the RC of the well-known crystalline magnetic refrigerant compound Gd5Si2Ge1.9Fe0.1 (357 J·kg-1) and MnFeP0.45As0.55 (390 J·kg-1)(containing either ex-orbitant-cost Ge or poisonous As). The full width at half maximum of the magnetic entropy change (ΔSm) peak almost spreads over the whole low-temperature range (from 303 to 30 K), which is five times wider than that of the Gd5Si2Ge1.9Fe0.1 and pure Gd. The maximum ΔSm approaches a nearly constant value in a wide tem-perature span over 100 K, and however, such a broad table-like region near room temperature has seldom been found in alloys and compounds. In combination with the intrinsic amorphous nature, the metallic glass composite may be potential for the ideal Ericsson-cycle magnetic refrigeration over a broad temperature range near room temperature.
Smith, Anders; Nielsen, Kaspar K.; Bez, Henrique N.; Bahl, Christian R. H.
2016-08-01
We measure the magnetocaloric effect of the manganite series La0.67Ca0.33 -xSrxMnO3 by determining the isothermal entropy change upon magnetization, using variable-field calorimetry. The results demonstrate that the field dependence of the magnetocaloric effect close to the critical temperature is not given uniquely by the critical exponents of the ferromagnetic-paramagnetic phase transition, i.e., the scaling is nonuniversal. A theoretical description based on the Bean-Rodbell model and taking into account compositional inhomogeneities is shown to be able to account for the observed field dependence. In this way the determination of the nonuniversal field dependence of the magnetocaloric effect close to a phase transition can be used as a method to gain insight into the strength of the spin-lattice interactions of magnetic materials. The approach is shown also to be applicable to first-order transitions.
Magnetocaloric effect of Gd5Si2Ge2 alloys in low magnetic field
Indian Academy of Sciences (India)
Hong Zeng; Chunjiang Kuang; Jiuxing Zhang; Ming Yue
2011-07-01
The magnetocaloric effect of Gd5Si2Ge2 alloys under heat treatment conditions are investigated in low magnetic fields. The magnetocaloric effect (MCE) is studied by measuring magnetic entropy change ( M) and adiabatic temperature change ( ad) in a magnetic field of 1.5 T using a vibrating sample magnetometer (VSM) and a home-made magnetocaloric effect measuring apparatus, respectively. The maximum M of the alloys increases by 200% from 4.38 to 13.32 J kg-1 K-1, the maximum ad increases by 105% from 1.9 to 3.9 K when compared to the as-cast due to the homogeneous composition distribution and microstructure, while the magnetic ordering temperature is slightly reduced. These results indicate that the annealed Gd5Si2Ge2 compounds are promising as high-performance magnetic refrigerants working room temperature in relatively low magnetic fields.
Magnetocaloric effect in temperature-sensitive magnetic fluids
Indian Academy of Sciences (India)
Kinnari Parekh; R V Upadhyay; R V Mehta
2000-04-01
The magnetocaloric properties of three different temperature-sensitive magnetic fluids were studied. The pyromagnetic coefficient for all the materials were obtained and it was found that this property depends on physical and magnetic properties like size, magnetization and Curie temperature. A theoretical model was developed to explain the behaviour of change in entropy with temperature.
Magnetocaloric effect in Ni-Fe-Ga Heusler alloys with Co and Al substitutions
Directory of Open Access Journals (Sweden)
Tolea F.
2015-01-01
Full Text Available The functionality of the ferromagnetic shape memory alloys is related to the martensitic and magnetic order-disorder transformations, both of which may be tailored by doping with other elements or by suitable thermal treatments, so that alloys with concomitant (or sequential but close structural and magnetic phase transitions may be obtained. Concerning the magnetocaloric applications, it is assumed that the thin melt-spun ribbons assure a more efficient heat transfer. In the present work we investigate the influence of Co and Al substitutions on magnetocaloric effect characteristics of NiFeGa in bulk and also in ribbons prepared by melt spinning method and subjected to different thermal treatments. X-ray diffraction, differential scanning calorimetry, magnetocaloric and magnetoresistive characterizations have been performed. The results highlight the differences between the bulk and the ribbons (both as prepared and annealed and the role of substitutions.
Energy Technology Data Exchange (ETDEWEB)
Jeppesen, Stinus
2008-10-15
New and improved magnetocaloric materials are one of the cornerstones in the development of room temperature magnetic refrigeration. Magnetic refrigeration has been used since the 1930ies in cryogenic applications, but has since the discovery of room temperature refrigerants received enormous attention. This Ph.D. work has been mainly concerned with developing a new technique to characterize the magnetocaloric effect (MCE) and using this technique in the investigations on new and improved magnetocaloric materials. For this purpose a novel differential scanning calorimeter (DSC) with applied magnetic fields was developed for measuring heat capacity as function of magnetic field. Measurements using the developed DSC demonstrate a very high sensitivity, fast measurements and good agreement with results obtained by other techniques. Furthermore, two material systems have been described in this work. Both systems take basis in the mixed-valence manganite system La{sub 1-x}Ca{sub x}MnO{sub 3} well known from research on colossal magnetoresistance (CMR). The mixed-valence manganite crystallizes in the perovskite structure of general formula ABO{sub 3}. The first material system is designed to investigate the influence of low level Cu doping on the B-site. Six different samples were prepared with over-stoichiometric compositions La{sub 0.67}Ca{sub 0.33}Mn{sub 1.05}Cu{sub x}O{sub 3}, x=0, 1, 2, 3, 4 and 5%. All compositions crystallized well in the same perovskite structure, but the morphology of the samples changed drastically with doping. Investigation on the magnetocaloric properties revealed that small levels of Cu up to around 3% could improve the magnetocaloric performance of the materials. Furthermore, Cu could be used to tune the temperature interval without deteriorating the MCE, which is a much desired characteristic for potential use in magnetic refrigerators. A less comprehensive part of the work has been concerned with the investigation of doping on the A
International Nuclear Information System (INIS)
The effect of demagnetization in a stack of gadolinium plates is determined experimentally by using spatially resolved measurements of the adiabatic temperature change due to the magnetocaloric effect. The number of plates in the stack, the spacing between them and the position of the plate on which the temperature is measured are varied. The orientation of the magnetic field is also varied. The measurements are compared to a magnetostatic model previously described. The results show that the magnetocaloric effect, due to the change in the internal field, is sensitive to the stack configuration and the orientation of the applied field. This may have significant implications for the construction of a magnetic cooling device. - Highlights: → The magnetocaloric effect is used as an indirect measure of the internal magnetic field. → To our knowledge nobody has published experimental determination of demagnetizing field in stack configurations of plates of magnetic material. → We present good agreement between the experimental results and an established numerical model. → This serves to show that the model may be used further to predict, e.g., optimal configurations.
Giant magnetocaloric effect in antiferromagnetic DyVO4 compound
Midya, A.; Khan, N.; Bhoi, D.; Mandal, P.
2014-09-01
We have investigated the magnetic and magnetocaloric properties of DyVO4 by magnetization and heat capacity measurements. χ(T) shows antiferromagnetic to paramagnetic transition at TNDy~3.5 K. The compound undergoes a metamagnetic transition and exhibits a huge entropy change. The maximum values of magnetic entropy change (ΔSM), adiabatic temperature change (ΔTad) and refrigerant capacity (RC) reach 26 J kg-1 K-1, 17 K, and 526 J kg-1, respectively for a field change of 0-8 T. Moreover, the material is highly insulating and exhibits no thermal and field hysteresis, satisfying the necessary conditions for a good magnetic refrigerant material.
Magnetocaloric effect at the exchange–inversion with magnetoelastic coupling
Energy Technology Data Exchange (ETDEWEB)
Piazzi, Marco, E-mail: m.piazzi@inrim.it; Basso, Vittorio
2015-09-15
We develop a thermodynamic model to describe antiferro- (AFM) to ferromagnetic (FM) phase transitions through magnetoelastic coupling in the framework of Kittel's exchange–inversion mechanism. By including both magnetic and structural contributions to the free energy, we derive the conditions to have a direct AFM–FM transition. These are represented either by the presence of a non-zero intra-sublattice coupling constant or by a sufficiently high value of the magnetoelastic coupling parameter. In the paper we establish these conditions by analytical means and we discuss the physical meaning of the model in relation to possible applications to magnetocaloric materials with AFM–FM transitions.
Magnetocaloric effect at the exchange-inversion with magnetoelastic coupling
Piazzi, Marco; Basso, Vittorio
2015-09-01
We develop a thermodynamic model to describe antiferro- (AFM) to ferromagnetic (FM) phase transitions through magnetoelastic coupling in the framework of Kittel's exchange-inversion mechanism. By including both magnetic and structural contributions to the free energy, we derive the conditions to have a direct AFM-FM transition. These are represented either by the presence of a non-zero intra-sublattice coupling constant or by a sufficiently high value of the magnetoelastic coupling parameter. In the paper we establish these conditions by analytical means and we discuss the physical meaning of the model in relation to possible applications to magnetocaloric materials with AFM-FM transitions.
Energy Technology Data Exchange (ETDEWEB)
Agarwal, Sandeep [Haldia Institute of Technology, Haldia 721657, West Bengal (India); LCMP, Department of Condensed Matter Physics and Material Sciences, S.N. Bose National Centre for Basic Sciences, JD Block, Salt Lake, Kolkata 700098 (India); Stern-Taulats, Enric; Mañosa, Lluís [Departament d’Estructura i Constituents de la Matèria, Facultat de Física, Universitat de Barcelona, 08028 Barcelona, Catalonia (Spain); Mukhopadhyay, P.K., E-mail: pkm@bose.res.in [LCMP, Department of Condensed Matter Physics and Material Sciences, S.N. Bose National Centre for Basic Sciences, JD Block, Salt Lake, Kolkata 700098 (India)
2015-08-25
Highlights: • Magnetic properties of the system changed after secondary heat treatment. • MCE was enhanced after Al was partially replaced with Sn in Ni–Mn–Al system. • Suitable heat treatment further increased overall MCE in the sample. • Change in magnetic properties occurred due to change in atomic ordering. - Abstract: We studied the effect of low temperature annealing on the atomic ordering and consequent changes in the magnetization and magnetocaloric effect of the sample. The annealing at lower temperatures initially decreased the magnetization and magnetocaloric effect in the sample, but at higher annealing temperatures both increased. The changes in magnetization and magnetocaloric effect arise from the change in atomic ordering. We have shown that post quenching heat treatment offers easy way of optimizing the alloy for magnetocaloric effect. In order to verify that there was no overestimation in the measurement of magnetocaloric effect we also performed an infield calorimetric measurements and compared them with those from the magnetization measurements. We did not find remarkable difference between them.
Magnetocaloric effect in (TbcR1-c)Co2 (R=Er and Ho)
International Nuclear Information System (INIS)
Highlights: • Microscopical description of the chemical disorder in rare earth based compounds. • Magnetocaloric effect in compounds with first order phase transition. • Effect of impurities on the nature of the magnetic phase transition. - Abstract: In this paper we theoretically discuss the magnetocaloric effect in (TbcR1-c)Co2 (R = Er and Ho). To this end, we use a model Hamiltonian in which are included the 4f electrons from rare earth ions and the 3d electrons from Co ions. In the model is also included an extra term to account for the crystal electric field, which plays an important role in the magnetic and caloric properties of these compounds
Magnetic properties and magnetocaloric effects of Mn5Ge3-xGax
Institute of Scientific and Technical Information of China (English)
Liu Xi-Bin; Zhang Shao-Ying; Shen Bao-Gen
2004-01-01
We report on the magnetic properties and magnetocaloric effects of Mn5Ge3-xGax compounds with x=0.1, 0.2,0.3, 0.4, 0.6 and 0.9. All samples crystallize in the hexagonal Mn5Si3-type structure with space group P63/mcm and order ferromagnetically. The Curie temperature of these compounds decreases with increasing x, from 306K (x=0.1) to 274K (x=0.9). The average Mn magnetic moments increases with increasing Ga content, reaching a maximum value at x=0.6. The magnetic entropy changes in these compounds are determined from the temperature and field dependence of the magnetization using the thermodynamic Maxwell relation. The Ga substitution has two kinds of influence on the magnetocaloric effect (MCE) of Mn5Ge3. One is that the magnitude of the magnetic entropy change decreases, the other is that the MCE peak becomes broadened.
Staunton, J. B.; Banerjee, R.; dos Santos Dias, Manuel; Deak, A.; Szunyogh, L.
2014-01-01
We describe an ab-initio Disordered Local Moment Theory for materials with quenched static compositional disorder traversing first order magnetic phase transitions. It accounts quantitatively for metamagnetic changes and the magnetocaloric effect. For perfect stoichiometric B2-ordered FeRh, we calculate the transition temperature of the ferromagnetic-antiferromagnetic transition to be $T_t =$ 495K and a maximum isothermal entropy change in 2 Tesla of $|\\Delta S|= 21.1$ J~K$^{-1}$~kg$^{-1}$. A...
Large reversible magnetocaloric effect in a Ni-Co-Mn-In magnetic shape memory alloy
Huang, L.; Cong, D. Y.; Ma, L.; Nie, Z. H.; Wang, Z. L.; Suo, H. L.; Ren, Y.; Wang, Y. D.
2016-01-01
Reversibility of the magnetocaloric effect in materials with first-order magnetostructural transformation is of vital significance for practical magnetic refrigeration applications. Here, we report a large reversible magnetocaloric effect in a Ni49.8Co1.2Mn33.5In15.5 magnetic shape memory alloy. A large reversible magnetic entropy change of 14.6 J/(kg K) and a broad operating temperature window of 18 K under 5 T were simultaneously achieved, correlated with the low thermal hysteresis (˜8 K) and large magnetic-field-induced shift of transformation temperatures (4.9 K/T) that lead to a narrow magnetic hysteresis (1.1 T) and small average magnetic hysteresis loss (48.4 J/kg under 5 T) as well. Furthermore, a large reversible effective refrigeration capacity (76.6 J/kg under 5 T) was obtained, as a result of the large reversible magnetic entropy change, broad operating temperature window, and small magnetic hysteresis loss. The large reversible magnetic entropy change and large reversible effective refrigeration capacity are important for improving the magnetocaloric performance, and the small magnetic hysteresis loss is beneficial to reducing energy dissipation during magnetic field cycle in potential applications.
Elasticity and magnetocaloric effect in MnFe4Si3
Herlitschke, M.; Klobes, B.; Sergueev, I.; Hering, P.; Perßon, J.; Hermann, R. P.
2016-03-01
The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the influence of the magnetic transition and the magnetocaloric effect on lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low-energy, ˜ neV, phonon modes. A significant influence of the magnetic transition on the lattice dynamics is observed only in the low-energy, long-wavelength limit. MnFe4Si3 and other compounds in the Mn5 -xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements, and Mössbauer spectroscopy in order to study the magnetic transitions and to complement the results obtained on the lattice dynamics.
Field-induced reversible magnetocaloric effect in CoCl2
International Nuclear Information System (INIS)
Research highlights: The electronic structure and magnetic properties of CoCl2 have been investigated by several groups, but the magnetocaloric effect was not reported. In this paper, we study the magnetic and magnetocaloric properties of the antiferromagnet CoCl2 at low temperatures. A large negative magnetic-entropy change and a large cooling power are found together with a field-induced MCE conversion (the MCE changes its sign in the applied magnetic field). - Abstract: A sign change of the magnetocaloric effect is induced by a magnetic field, which is related to a field-induced transition from the antiferromagnetic to the ferromagnetic state below the Neel temperature of CoCl2 nanoparticles. The reversible magnetic-entropy change -ΔSm (4.1 and 11.5 J kg-1 K-1 at 27 K for a field change of 3 and 7 T, respectively) almost without hysteresis and the large cooling power (83.4 and 148 J kg-1, correspondingly) indicates that CoCl2 is a potential candidate for application in magnetic refrigeration in the low-temperature range.
Inverse magnetocaloric effect in Ce(Fe0.96Ru0.04)2: Effect of fast neutron irradiation
Dube, V.; Mishra, P. K.; Rajarajan, A. K.; Prajapat, C. L.; Sastry, P. U.; Thakare, S. V.; Singh, M. R.; Ravikumar, G.
2013-02-01
We have shown the effect of fast neutron irradiation on the magnetic phase transition and magnetocaloric effect (MCE) in a doped Ce(Fe0.96Ru0.04)2, intermettalic. We show that this leads to suppression of MCE and a to a disordered ferromagnetic phase.
Choudhury, D; Suzuki, T; Tokura, Y; Taguchi, Y
2014-01-01
Magnetocaloric effect is the phenomenon that temperature change of a magnetic material is induced by application of a magnetic field. This effect can be applied to environmentally-benign magnetic refrigeration technology. Here we show a key role of magnetic-field-induced structural instability in enhancing the magnetocaloric effect for MnCo(1-x)Zn(x)Ge alloys (x = 0-0.05). The increase in x rapidly reduces the martensitic transition temperature while keeping the ferromagnetic transition around room temperature. Fine tuning of x around x = 0.03 leads to the concomitant structural and ferromagnetic transition in a cooling process, giving rise to enhanced magnetocaloric effect as well as magnetic-field-induced structural transition. Analyses of the structural phase diagrams in the T-H plane in terms of Landau free-energy phenomenology accounts for the characteristic x-dependence of the observed magnetocaloric effect, pointing to the importance of the magnetostructural coupling for the design of high-performance magnetocalorics. PMID:25519919
Choudhury, D.; Suzuki, T.; Tokura, Y.; Taguchi, Y.
2014-01-01
Magnetocaloric effect is the phenomenon that temperature change of a magnetic material is induced by application of a magnetic field. This effect can be applied to environmentally-benign magnetic refrigeration technology. Here we show a key role of magnetic-field-induced structural instability in enhancing the magnetocaloric effect for MnCo1−xZnxGe alloys (x = 0–0.05). The increase in x rapidly reduces the martensitic transition temperature while keeping the ferromagnetic transition around room temperature. Fine tuning of x around x = 0.03 leads to the concomitant structural and ferromagnetic transition in a cooling process, giving rise to enhanced magnetocaloric effect as well as magnetic-field-induced structural transition. Analyses of the structural phase diagrams in the T-H plane in terms of Landau free-energy phenomenology accounts for the characteristic x-dependence of the observed magnetocaloric effect, pointing to the importance of the magnetostructural coupling for the design of high-performance magnetocalorics. PMID:25519919
Choudhury, D.; Suzuki, T.; Tokura, Y.; Taguchi, Y.
2014-12-01
Magnetocaloric effect is the phenomenon that temperature change of a magnetic material is induced by application of a magnetic field. This effect can be applied to environmentally-benign magnetic refrigeration technology. Here we show a key role of magnetic-field-induced structural instability in enhancing the magnetocaloric effect for MnCo1-xZnxGe alloys (x = 0-0.05). The increase in x rapidly reduces the martensitic transition temperature while keeping the ferromagnetic transition around room temperature. Fine tuning of x around x = 0.03 leads to the concomitant structural and ferromagnetic transition in a cooling process, giving rise to enhanced magnetocaloric effect as well as magnetic-field-induced structural transition. Analyses of the structural phase diagrams in the T-H plane in terms of Landau free-energy phenomenology accounts for the characteristic x-dependence of the observed magnetocaloric effect, pointing to the importance of the magnetostructural coupling for the design of high-performance magnetocalorics.
Variations of magnetocaloric effect and magnetoresistance across RCuGe (R=Tb, Dy, Ho, Er) compounds
Energy Technology Data Exchange (ETDEWEB)
Gupta, Sachin; Suresh, K.G., E-mail: suresh@phy.iitb.ac.in
2015-10-01
RCuGe (R=Tb–Er) compounds have been studied by structural, magnetic, magnetocaloric and magnetotransport measurements. All these compounds are iso-structural and show antiferromagnetic ordering below their Néel temperatures (T{sub N}). Except TbCuGe, all the studied compounds show large magnetocaloric effect (MCE), arising due to the field induced metamagnetic transition. They also show a sign reversal of magnetoresistance (MR) with change in temperature or field. The non-monotonic variation of the magnitude of MR is attributed to the competing effects of Lorentz force, changes in the spin disorder scattering and the spin fluctuations. - Highlights: • RCuGe (R=Tb–Er) compounds show low temperature antiferromagnetic ordering. • All compounds show field induced metamagnetic transitions. • These compounds show large magnetocaloric effect and magnetoresistance.
The influence of hysteresis on the determination of the magnetocaloric effect in Gd5Si2Ge2
DEFF Research Database (Denmark)
von Moos, Lars; Bahl, Christian; Nielsen, Kaspar Kirstein;
2015-01-01
We present a non-equilibrium Preisach-type hysteresis model based on the first order magnetocaloric material Gd5Si2Ge2. The model is developed from isofield magnetization measurements and first order reversal curves, both of which constitute a new and detailed approach to characterizing and model......We present a non-equilibrium Preisach-type hysteresis model based on the first order magnetocaloric material Gd5Si2Ge2. The model is developed from isofield magnetization measurements and first order reversal curves, both of which constitute a new and detailed approach to characterizing...... continuous magnetization cycles, which effectively limits the adiabatic temperature change by the amount of thermal hysteresis present. We suggest a straightforward method for realistic estimation of the magnetocaloric effect from indirect measurements....
Hysteresis in Magnetocaloric Materials
DEFF Research Database (Denmark)
von Moos, Lars
characterization of the magnetocaloric effect (MCE) in these materials is done through conventional indirect magnetometric and calorimetric methods, as well as newly developed direct methods. The determination of the MCE due to a magnetic field change is in principle given by the isofield material entropy curves......In this thesis the effects of hysteresis on magnetocaloric material properties and their performance in magnetic refrigeration devices are investigated. This is done through an experimental and model study of first order magnetocaloric materials MnFe(P,As) and Gd5Si2Ge2. The experimental......, obtained at the initial low and final high field. However, in first order materials thermal entropy hysteresis loops are obtained through characterization, corresponding to measurements done in an increasing and a decreasing temperature mode. Indirectly determining the MCE through the use of the Maxwell...
History dependence of directly observed magnetocaloric effects in (Mn, Fe)As
Bratko, Milan; Morrison, Kelly; de Campos, Ariana; Gama, Sergio; Lesley F. Cohen; Sandeman, Karl G.
2012-01-01
We use a calorimetric technique operating in sweeping magnetic field to study the thermomagnetic history- dependence of the magnetocaloric effect (MCE) in Mn0.985Fe0.015As. We study the magnetization history for which a "colossal" MCE has been reported when inferred indirectly via a Maxwell relation. We observe no colossal effect in the direct calorimetric measurement. We further examine the impact of mixed-phase state on the MCE and show that the first order contribution scales linearly with...
DEFF Research Database (Denmark)
von Moos, Lars; Bahl, Christian R.H.; Nielsen, Kaspar Kirstein;
2014-01-01
We quantify the effect of hysteresis on the performance of the magnetocaloric first order material Gd5Si2Ge2 undergoing an ideal active magnetic regenerator (AMR) cycle. The material is carefully characterized through magnetometry (VSM) and calorimetry (DSC) in order to enable an accurate model...... description of the phase transition at varying magnetic fields and temperatures. Using detailed experimental property data, a Preisach type model is used to describe the thermal hysteresis effects and simulate the material under realistic working conditions. We find that the adiabatic temperature change...... is limited by a significant fraction of the thermal hysteresis....
Magnetic properties and magnetocaloric effect in TbCo2-xFex compounds
Institute of Scientific and Technical Information of China (English)
Zou Jun-Ding; Shen Bao-Gen; Sun Ji-Rong
2007-01-01
Magnetic properties and magnetocaloric effect in TbCo2-xFex compounds are studied by DC magnetic measurement. With increasing content of Fe, the entropy changes decrease slightly, though the Curie temperature is tuned from 231 K (x = 0) to 303 K (x = 0.1). Magnetic entropies of TbCo2 compound are calculated by using mean field approximation (MFA). Results estimated by using Maxwell relation are consistent with that of MFA calculation. It si shown that the entropy changes are mainly derived from the magnetic entropy change. The lattice has almost no contribution to the entropy change in the vicinity of phase transition.
Large magnetocaloric effect in spinel CdCr2S4
Yan, L. Q.; Shen, J.; Li, Y. X.; Wang, F. W.; Jiang, Z. W.; Hu, F. X.; Sun, J. R.; Shen, B. G.
2007-06-01
Magnetocaloric effect in CdCr2S4 was investigated by magnetization and heat capacity measurements. CdCr2S4 is of a cubic spinel structure with soft ferromagnetism and performs reversible magnetic entropy in the whole experimental temperature range from 56to128K. A large magnetic entropy change ˜7.04J /kgK and adiabatic temperature change ΔTad˜2.6K are revealed for a field change of 0-5T near the Curie temperature of 87K. These results suggest that sulfospinel probably is a promising candidate as working material in magnetic refrigeration technology.
Rate dependence of the magnetocaloric effect in La-Fe-Si compounds
Directory of Open Access Journals (Sweden)
Sasso C.P.
2013-01-01
Full Text Available The dynamic magnetocaloric effect in La(FexCoySi1-x-y13 with x=0.9 and low Co content of y=0.015 was analysed by calorimetric measurements at constant magnetic field and constant temperature as well as magnetisation relaxation measurements. It is shown that the rate dependence of the measurement, which leads to an increased entropy hysteresis with increasing rate of the driving force (temperature or magnetic field, can be mainly attributed to a thermal contact resistance R between sample and thermal bath of the measurement setup.
DEFF Research Database (Denmark)
Smith, Anders; Nielsen, Kaspar Kirstein; Neves Bez, Henrique;
2016-01-01
is not given uniquely by the critical exponents of the ferromagnetic-paramagnetic phase transition, i.e., the scaling is nonuniversal. A theoretical description based on the Bean-Rodbell model and taking into account compositional inhomogeneities is shown to be able to account for the observed field dependence....... In this way the determination of the nonuniversal field dependence of the magnetocaloric effect close to a phase transition can be used as a method to gain insight into the strength of the spin-lattice interactions of magnetic materials. The approach is shown also to be applicable to first-order transitions....
Magnetic properties and magnetocaloric effect in Ni–Mn–Sn alloys
Energy Technology Data Exchange (ETDEWEB)
Dan, N.H., E-mail: dannh@ims.vast.ac.vn [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam); Duc, N.H.; Yen, N.H.; Thanh, P.T. [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam); Bau, L.V.; An, N.M. [Hong Duc University, 565 Quang Trung, Dong Ve, Thanh Hoa (Viet Nam); Anh, D.T.K.; Bang, N.A.; Mai, N.T. [Faculty of Physics, VNU University of Science, 334 Nguyen Trai, Hanoi (Viet Nam); Anh, P.K. [Vietnam Academy of Military Science, 322 Le Trong Tan, Thanh Xuan, Hanoi (Viet Nam); Thanh, T.D. [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam); Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Phan, T.L. [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Yu, S.C., E-mail: scyu@chungbuk.ac.kr [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)
2015-01-15
Magnetic and magnetocaloric properties in Ni{sub 50}Mn{sub 50−x}Sn{sub x} alloys with wide range of the Sn-concentration (x=0–40) were investigated. The alloys were prepared by arc-melting and subsequently annealing at 850 °C for 4 h. The X-ray diffraction analyses manifest the formation of the crystalline phases (Ni{sub 2}MnSn, NiMn, Ni{sub 3}Sn{sub 2}, Mn{sub 3}Sn, and MnSn{sub 2}) in the alloys with various compositions and fabrication conditions. With increasing x, the saturation magnetization first increases from near zero (at x=10) to above 40 emu/g (at x=20) and then decreases to below 10 emu/g (at x=40) for both the as-melted and annealed cases. The martensitic–austenitic transition was observed in the alloys with a narrow range of x (13–15). The magnetic transitions in the alloy can be controlled by changing Sn-concentration. The alloy reveals both the positive and negative entropy changes with quite large magnitude (∆S{sub m}>1 J/kg K with ∆H=12 kOe) with appropriate compositions and annealing conditions. - Highlights: • Crystalline phases and magnetic properties in Ni{sub 50}Mn{sub 50−x}Sn{sub x} alloys (x=0–40). • Simultaneous transitions of structural and magnetic phases. • Coexistence of positive and negative giant magnetocaloric effect in Heusler alloys. • Tuning giant magnetocaloric effect in room temperature region.
Effective medium theory for anisotropic metamaterials
Zhang, Xiujuan
2015-01-20
Materials with anisotropic material parameters can be utilized to fabricate many fascinating devices, such as hyperlenses, metasolids, and one-way waveguides. In this study, we analyze the effects of geometric anisotropy on a two-dimensional metamaterial composed of a rectangular array of elliptic cylinders and derive an effective medium theory for such a metamaterial. We find that it is possible to obtain a closed-form analytical solution for the anisotropic effective medium parameters, provided the aspect ratio of the lattice and the eccentricity of the elliptic cylinder satisfy certain conditions. The derived effective medium theory not only recovers the well-known Maxwell-Garnett results in the quasi-static regime, but is also valid beyond the long-wavelength limit, where the wavelength in the host medium is comparable to the size of the lattice so that previous anisotropic effective medium theories fail. Such an advance greatly broadens the applicable realm of the effective medium theory and introduces many possibilities in the design of structures with desired anisotropic material characteristics. A real sample of a recently theoretically proposed anisotropic medium, with a near-zero index to control the flux, is achieved using the derived effective medium theory, and control of the electromagnetic waves in the sample is clearly demonstrated.
Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain.
Moya, X; Hueso, L E; Maccherozzi, F; Tovstolytkin, A I; Podyalovskii, D I; Ducati, C; Phillips, L C; Ghidini, M; Hovorka, O; Berger, A; Vickers, M E; Defay, E; Dhesi, S S; Mathur, N D
2013-01-01
Large thermal changes driven by a magnetic field have been proposed for environmentally friendly energy-efficient refrigeration, but only a few materials that suffer hysteresis show these giant magnetocaloric effects. Here we create giant and reversible extrinsic magnetocaloric effects in epitaxial films of the ferromagnetic manganite La(0.7)Ca(0.3)MnO(3) using strain-mediated feedback from BaTiO(3) substrates near a first-order structural phase transition. Our findings should inspire the discovery of giant magnetocaloric effects in a wide range of magnetic materials, and the parallel development of nanostructured bulk samples for practical applications.
Analysis of the Magnetocaloric Effect in Powder Samples Obtained by Ball Milling
Blázquez, J. S.; Ipus, J. J.; Moreno-Ramírez, L. M.; Borrego, J. M.; Lozano-Pérez, S.; Franco, V.; Conde, C. F.; Conde, A.
2015-06-01
Since the discovery of the giant magnetocaloric effect (MCE) close to room temperature in FeRh and particularly in Gd5Si2Ge2 compounds, the study of this phenomenon has experienced an exponential growth. Among the different techniques used to produce magnetocaloric materials, ball milling has been shown as a very versatile one and presents several advantages over other preparation techniques ( e.g., easy scale-up to industrial production). Although a general decrease of the peak value of the magnetic entropy change is observed for milled samples, it can be compensated by the large broadening of the MCE peak, leading to an increase of the refrigeration capacity. In this short review, several aspects inherent to powder samples affecting MCE will be discussed, such as the relevant effect of the demagnetizing field, the possible multiphase character, and the presence of Curie temperature distributions. In mechanically alloyed samples, the two latter factors are typically affected by the degree of integration of the different starting constituents.
Torrico, J.; Rojas, M.; de Souza, S. M.; Rojas, Onofre
2016-10-01
Zero temperature non-plateau magnetization is a peculiar property of a quantum spin chain and it sometimes appears due to different gyromagnetic factors. In this study, we illustrate a quite unusual non-plateau magnetization property driven by XY-anisotropy in an Ising-XYZ diamond chain. Two particles with spin-1/2 are bonded by XYZ coupling and they are responsible for the emergence of non-plateau magnetization. These two quantum operator spins are bonded to two nodal Ising spins and this process is repeated infinitely to yield a diamond chain structure. Due to the non-plateau magnetization property, we focus our discussion on the magnetocaloric effect of this model by presenting the isentropic curves and the Grüneisen parameters, as well as showing the regions where the model exhibits an efficient magnetocaloric effect. Due to the existence of two phases located very close to each other, the strong XY-anisotropy exhibits a particular behavior with a magnetocaloric effect, with a wider interval in the magnetic field, where the magnetocaloric effect is efficient.
Large magnetocaloric effect of GdNiAl{sub 2} compound
Energy Technology Data Exchange (ETDEWEB)
Dembele, S.N.; Ma, Z.; Shang, Y.F. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Fu, H., E-mail: fuhao@uestc.edu.cn [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Balfour, E.A. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Hadimani, R.L.; Jiles, D.C. [Department of Electrical and Computer Engineering, Iowa State University, Ames, IA 50011 (United States); Ames Laboratory, US Department of Energy, Ames, IA 50011 (United States); Teng, B.H.; Luo, Y. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China)
2015-10-01
This paper presents the structure, magnetic properties, and magnetocaloric effect of the polycrystalline compound GdNiAl{sub 2}. Powder X-ray diffraction (XRD) measurement and Rietveld refinement revealed that GdNiAl{sub 2} alloy is CuMgAl{sub 2}-type phase structure with about 1 wt% GdNi{sub 2}Al{sub 3} secondary phase. Magnetic measurements suggest that the compound is ferromagnetic and undergoes a second-order phase transition near 28 K. The maximum value of magnetic entropy change reaches 16.0 J/kg K for an applied magnetic field change of 0–50 kOe and the relative cooling power was 6.4×10{sup 2} J/kg. It is a promising candidate as a magnetocaloric material working near liquid hydrogen temperature (~20 K) exhibiting large relative cooling power. - Highlights: • Preferred orientation with axis of [010] was found in the GdNiAl{sub 2} compound. • The ΔS{sub Mmax} and the RCP are 16.0 J/kg K and 640 J/kg, respectively, for ΔH=50 kOe. • Relative low rare earth content in GdNiAl{sub 2} comparing with other candidates.
Staunton, J. B.; Banerjee, R.; Dias, M. dos Santos; Deak, A.; Szunyogh, L.
2014-02-01
We describe an ab initio disordered local moment theory for materials with quenched static compositional disorder traversing first-order magnetic phase transitions. It accounts quantitatively for metamagnetic changes and the magnetocaloric effect. For perfect stoichiometric B2-ordered FeRh, we calculate the transition temperature of the ferromagnetic-antiferromagnetic transition to be Tt= 495 K and a maximum isothermal entropy change in 2 T of |ΔS|=21.1 J K-1 kg-1. A large (40%) component of |ΔS| is electronic. The transition results from a fine balance of competing electronic effects which is disturbed by small compositional changes; e.g., swapping just 2% Fe of "defects" onto the Rh sublattice makes Tt drop by 290 K. This hypersensitivity explains the narrow compositional range of the transition and impurity doping effects.
Madireddi, Sesha
Magnetic refrigeration (MR) is potentially a high efficiency, low cost, and greenhouse gas-free refrigeration technology, and with the looming phase out of HCFC and HFC fluorocarbons refrigerants is drawing more attention as an alternative to the existing vapor compression refrigeration. MR is based on the magnetocaloric effect (MCE), which occurs due to the coupling of a magnetic sublattice with an external magnetic field. With the magnetic spin system aligned by magnetic field, the magnetic entropy changes by Delta SM as a result of isothermal magnetization of a material. On the other hand, the sum of the lattice and electronic entropies of a solid must be changed by -DeltaSM as a result of adiabatically magnetizing the material, thus resulting in an increase of the lattice vibrations and the adiabatic temperature change, DeltaTad. Both the isothermal entropy change DeltaSM and adiabatic temperature change DeltaTad are important parameters in quantifying the MCE and performance of magnetocaloric materials (MCM). In general, DeltaSM and Delta Tad are obtained using magnetization and heat capacity data and the Maxwell equations. Although Maxwell equations can be used to calculate MCE for first order magnetic transition (FOMT) materials due to the fact that the transition is not truly discontinuous, there can be some errors depending on the numerical integration method used. Thus, direct measurements of DeltaTad are both useful and required to better understand the nature of the giant magnetocaloric effect (GMCE). Moreover, the direct measurements of DeltaTad allow investigation of dynamic performance of FOMT materials experiencing repeated magnetization/demagnetization cycles. This research utilized a special test facility to directly measure MCE of Gd5Si2Ge2, Gd5Si2.7 Ge1.3, MnFePAs, LaFeSiH, Ni55.2M 18.6Ga26.2, Dy, Tb, DyCo2, (Hf0.83 Ta0.17)Fe1.98, GdAl2 and Nd2Fe 17, MCMs, both FOMT and second order magnetic transition (SOMT) materials, at different magnetizing
Magnetocaloric effect in a cluster-glass system Ho5Pd2-xNix
Toyoizumi, Saori; Kitazawa, Hideaki; Morita, Kengo; Tamaki, Akira
2016-02-01
In order to investigate the effect of chemical pressure on the large magnetocaloric effect in Ho5 Pd2, we conducted X-ray diffraction, magnetization, and specific heat measurements on Ho5Pd2-xNix(0≤ x ≤ 1.0) rare-earth intermetallic compounds. The linear x dependence of the lattice constant a suggests that Ni is replaced with Pd in the case of Ho5Pd2-xNix (0 ≤ x ≤ 0.5). The spin-glass transition temperature Tg and paramagnetic Curie temperature θP indicate a weak oscillatory x dependence. However, the magnetic entropy change —ΔSm and the relative cooling power (RCP) are rapidly suppressed with increasing x. These large reductions in —ΔSm and RCP cannot be explained only in terms of normal Ruderman-Kittel- Kasuya-Yoshida (RKKY)-type indirect exchange interactions.
Magnetocaloric Effect in MnCo_(1-x)Al_xGe Compounds
Institute of Scientific and Technical Information of China (English)
Weiguang Zhang; O. Tegus; Yongli Wu; Yirgeltu; Huanying Yan; Song Lin
2009-01-01
The effects of substitution of Al for Co on magnetic and magnetocaloric properties of MnCo_(1-x)Al_xGe (x=0.00, 0.03, 0.05, 0.08, 0.10, 0.13, 0.15, and 0.20) compounds have been investigated by X-ray diffraction (XRD) and magnetization measurements. XRD exhibits that MnCo_(1-x)Al_xGe compounds crystallize in the orthorhombic TiNiSi-type structure for x0.03. Magnetic measurements show that the Curie temperature can be tuned between 286 and 347 K by changing the Co/Al ratio. The maximum magnetic entropy change determined from the isothermal magnetization measurement by Maxwell relation reaches 1.52 J/(kgK) for x=0.08 in a field change from 0 to 1.5 T around 310 K.
The giant magnetocaloric effect in Gd5Si2Ge2 with low purity gadolinium
Institute of Scientific and Technical Information of China (English)
ZHANG Tiebang; CHEN Yungui; FU Hao; TENG Baohua; TANG Yongbai; TU Mingjing
2005-01-01
The giant magnetocaloric effect Gd5Si2Ge2 alloy was prepared with 99wt% low purity commercial Gd. Powder XRD and magnetic measurements showed that the Gd5Si2Ge2 alloy annealed at 1200℃ for 1 h had a significant magnetic- crystallographic first order phase transition at about 270 K. The maximal magnetic entropy change is 17.55 J·kg-1·K-1 under a magnetic field change of 0―5 T. The distinct increase of magnetic entropy change belongs to the first-order phase transition from the orthorhombic Gd5Si4-type to the monoclinic Gd5Si2Ge2-type after high temperature heat-treatment.
Large rotating magnetocaloric effect in the orthorhombic DyMnO3 single crystal
Balli, M.; Mansouri, S.; Jandl, S.; Fournier, P.; Dimitrov, D. Z.
2016-07-01
A large magnetocaloric effect can be obtained around TN, Dy ̴8 K simply by spinning the orthorhombic DyMnO3 single crystal within the cb-plane in a constant magnetic field, instead of the standard magnetization-demagnetization process. Under 7 T, the maximum rotating entropy change (-ΔSR, cb) and the associated adiabatic temperature change (ΔTad, cb) are 16.3 J/kg K and 11 K, respectively. The corresponding refrigerant capacity is 440 J/kg, with no thermal and field hysteresis losses. Our findings show that the orthorhombic DyMnO3 could be used as a good refrigerant in more compact and efficient cryomagnetocaloric refrigerators.
Large magnetocaloric effects in magnetic intermetallics: First-principles and Monte Carlo studies
Directory of Open Access Journals (Sweden)
Entel Peter
2015-01-01
Full Text Available We have performed ab initio electronic structure calculations and Monte Carlo simulations of frustrated ferroic materials where complex magnetic configurations and chemical disorder lead to rich phase diagrams. With lowering of temperature, we find a ferromagnetic phase which transforms to an antiferromagnetic phase at the magnetostructural (martensitic phase transition and to a cluster spin glass at still lower temperatures. The Heusler alloys Ni-(Co-Mn-(Cr-(Ga, Al, In, Sn, Sb are of particular interest because of their large inverse magnetocaloric effect associated with the magnetostructural transition and the influence of Co/Cr doping. Besides spin glass features, strain glass behavior has been observed in Ni-Co-Mn-In. The numerical simulations allow a complete characterization of the frustrated ferroic materials including the Fe-Rh-Pd alloys.
Magnetic properties and magnetocaloric effects in Tb6Co1.67Si3 compound
Institute of Scientific and Technical Information of China (English)
Shen Jun; Wang Fang; Li Yang-Xian; Sun Ji-Rong; Shen Bao-Gen
2007-01-01
Magnetic properties and magnetocaloric effects of Tb6Co1.67Si3 have been investigated by magnetization measurement. This compound is of a hexagonal Ce6Ni2Si3-type structure with a saturation magnetization of 187 emu/g at 5 K and a reversible second-order magnetic transition at Curie temperature TC = 186 K. A magnetic entropy change is found to be 330 J/kg for fields ranging from 0 to 5 T. The large RC, the reversible magnetization around TC and the easy fabrication make the Tb6Co1.67Si3 compound a suitable candidate for magnetic refrigerants in a corresponding temperature range.
DEFF Research Database (Denmark)
Jeppesen, Stinus; Linderoth, Søren; Pryds, Nini;
2008-01-01
system and the results were highly consistent with previous reported data for these materials. The DSC has a working range from 200 to 340 K and has been tested in magnetic fields reaching 1.8 T. The signal-to-noise ratio is in the range of 102–103 for the described experiments. Finally the results have......A simple and high-sensitivity differential scanning calorimeter (DSC) unit operating under magnetic field has been built for indirect determination of the magnetocaloric effect. The principle of the measuring unit in the calorimeter is based on Peltier elements as heat flow sensors. The high...... sensitivity of the apparatus combined with a suitable calibration procedure allows very fast and accurate heat capacity measurements under magnetic field to be made. The device was validated from heat capacity measurements for the typical DSC reference material gallium (Ga) and a La0.67Ca0.33MnO3 manganite...
Large reversible magnetocaloric effect in HoMn2O5
Institute of Scientific and Technical Information of China (English)
Ge Heng; Zhang Xiang-Qun; Ke Ya-Jiao; Jin Jin-Ling; Liao Zhi-Xin; Cheng Zhao-Hua
2013-01-01
Magnetocaloric effect (MCE) in polycrystalline HoMn2O5 was investigated by isothermal magnetization curves from 2 K to 50 K.A relatively large magnetic entropy change,ASM =7.8 J/(kg.K),was achieved with the magnetic field up to 70 kOe (1 Oe =79.5775 A·m-1).The magnetic entropy change is reversible in the whole range of temperature.The contributions of elastic and magnetoelastic energy to the changing of the magnetic entropy are discussed in terms of the Landau theory.The reversibility of MCE with maximal refrigerant capacity Rc =216.7 J/kg makes polycrystalline HoMn2O5 promising as a magnetic refrigerant.
Giant magnetocaloric effect, magnetization plateaux and jumps of the regular Ising polyhedra
Energy Technology Data Exchange (ETDEWEB)
Strečka, Jozef, E-mail: jozef.strecka@upjs.sk [Institute of Physics, Faculty of Science, P.J. Šafárik University, Park Angelinum 9, 040 01 Košice (Slovakia); Karľová, Katarína [Institute of Physics, Faculty of Science, P.J. Šafárik University, Park Angelinum 9, 040 01 Košice (Slovakia); Madaras, Tomáš [Institute of Mathematics, Faculty of Science, P.J. Šafárik University, Jesenná 5, 040 01 Košice (Slovakia)
2015-06-15
Magnetization process and adiabatic demagnetization of the antiferromagnetic Ising spin clusters with the shape of regular polyhedra (Platonic solids) are exactly examined within the framework of a simple graph-theoretical approach. While the Ising cube as the only unfrustrated (bipartite) spin cluster shows just one trivial plateau at zero magnetization, the other regular Ising polyhedra (tetrahedron, octahedron, icosahedron and dodecahedron) additionally display either one or two intermediate plateaux at fractional values of the saturation magnetization. The nature of highly degenerate ground states emergent at intermediate plateaux owing to a geometric frustration is clarified. It is evidenced that the regular Ising polyhedra exhibit a giant magnetocaloric effect in a vicinity of magnetization jumps, whereas the Ising octahedron and dodecahedron belong to the most prominent geometrically frustrated spin clusters that enable an efficient low-temperature refrigeration by the process of adiabatic demagnetization.
Exchange bias in a mixed metal oxide based magnetocaloric compound YFe0.5Cr0.5O3
Sharma, Mohit K.; Singh, Karan; Mukherjee, K.
2016-09-01
We report a detailed investigation of magnetization, magnetocaloric effect and exchange bias studies on a mixed metal oxide YFe0.5Cr0.5O3 belonging to perovskite family. Our results reveal that the compound is in canted magnetic state (CMS) where ferromagnetic correlations are present in an antiferromagnetic state. Magnetic entropy change of this compound follows a power law (∆SM∼Hm) dependence of magnetic field. In this compound, inverse magnetocaloric effect (IMCE) is observed below 260 K while conventional magnetocaloric effect (CMCE) above it. The exponent 'm' is found to be independent of temperature and field only in the IMCE region. Investigation of temperature and magnetic field dependence studies of exchange bias, reveal a competition between effective Zeeman energy of the ferromagnetic regions and anisotropic exchange energy at the interface between ferromagnetic and antiferromagnetic regions. Variation of exchange bias due to temperature and field cycling is also investigated.
Magnetocaloric effect in GdCu intermetallic compound
Energy Technology Data Exchange (ETDEWEB)
Oboz, M.; Talik, E.; Winiarski, A. [Institiute of Physics, University of Silesia, Katowice (Poland)
2012-03-15
A single crystal of GdCu of FeB-type was grown by the Czochralski method from a levitating melt and characterized using X-ray diffraction, dc -magnetization M(T) and ac -magnetic susceptibility (ac-{chi}). From ac and dc magnetic susceptibility a transition to the antiferromagnetic state has been found below T{sub N} = 37 K. The paramagnetic Curie temperature {theta}{sub p} and the effective magnetic moment {mu}{sub eff}were estimated assuming the Curie-Weiss law in the 100 to 300 K range and were found to be {theta}{sub p}=-37 K and {mu}{sub eff}=8.5 {mu}{sub B}. The last value is enhanced relatively to the free ion value of 7.94 {mu}{sub B} for Gd{sup 3+}. The calculated entropy changes {delta}S{sub m} for the examined compound amount to -1.22 J/K.kg, -0.6 J/K.kg and -0.09 J/K.kg at 7, 5 and 2 T respectively. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Magnetocaloric and Hopkinson effects in slowly and rapidly cooled Gd{sub 7}Pd{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Talik, Ewa; Guzik, Adam; Oboz, Monika; Zajdel, Pawel; Ziolkowski, Grzegorz [Silesia Univ., Katowice (Poland). Inst. of Physics
2016-01-15
Gd{sub 7}Pd{sub 3} intermetallic compound was prepared as slowly cooled polycrystal and rapidly cooled (rc) casts. The slowly cooled polycrystalline samples were obtained by melting in an induction coil. The rc-cast Gd{sub 7}Pd{sub 3} sample was obtained by means of a mould casting technique. The samples were characterized by means of X-ray diffraction, SQUID magnetometry and scanning electron microscopy in order to elucidate the Hopkinson effect and magnetocaloric properties in relation to the technological aspects. The investigated ferromagnetic system is sensitive to grain size. The magnetocaloric and Hopkinson effect decreases with the decrease of the grain size. The results were compared to the data of single crystal obtained by the Czochralski method from a levitating melt.
Magnetic properties,magnetoresistivity and magnetocaloric effect in GdxLa1-x-MnSi alloys
Institute of Scientific and Technical Information of China (English)
T.I.Ivanova; S.A.Nikitin; W.Suski; GA.Tskhadadze; I.A.Ovtchenkova; D.Badurski
2009-01-01
The results of magnetization,magnetoresistivity and magnetocaloric effect (MCE) studies performed on polycrystalline samples of the GdxLa1-xMnSi (x=0.5,0.6,0.7,0.8,0.9,1.0) compounds were presented.Complex measurements were carried out on the GdxLa1-xMnSi compounds to determine the influence of substitution in the rare earth (R) sublattice on the magnetic and related properties of these compounds.The compounds with x≤0.6 demonstrated two magnetic phase transitions (ferromagnetic to paramagnetic and antiferromagnetic to ferromagnetic) both of which were first order.Anomalies in the magnetocaloric effect,electroresistivity and magnetoresistivity were observed in the temperature ranges of the magnetic phase transitions.The temperature dependences of MCE and magnetoresistivity for these compounds correlated with the temperature dependence of magnetization.
Phase transitions and magnetocaloric effects in intermetallic compounds MnFeX (X=P, As, Si, Ge)
Institute of Scientific and Technical Information of China (English)
O.Tegus; Bao Li-Hong; Song Lin
2013-01-01
Since the discovery of giant magnetocaloric effect in MnFeP1-xAsx compounds,much valuable work has been performed to develop and improve Fe2P-type transition-metal-based magnetic refrigerants.In this article,the recent progress of our studies on fundamental aspects of theoretical considerations and experimental techniques,effects of atomic substitution on the magnetism and magnetocalorics of Fe2P-type intermetallic compounds MnFeX (X=P,As,Ge,Si) is reviewed.Substituting Si (or Ge) for As leads to an As-free new magnetic material MnFeP1-xSi(Ge)x.These new materials show large magnetocaloric effects resembling MnFe(P,As) near room temperature.Some new physical phenomena,such as huge thermal hysteresis and 'virgin' effect,were found in new materials.On the basis of Landau theory,a theoretical model was developed for studying the mechanism of phase transition in these materials.Our studies reveal that MnFe(P,Si) compound is a very promising material for room-temperature magnetic refrigeration and thermo-magnetic power generation.
Tereshina, I. S.; Chzhan, V. B.; Tereshina, E. A.; Khmelevskyi, S.; Burkhanov, G. S.; Ilyushin, A. S.; Paukov, M. A.; Havela, L.; Karpenkov, A. Yu.; Cwik, J.; Koshkid'ko, Yu. S.; Miller, M.; Nenkov, K.; Schultz, L.
2016-07-01
The influence of simultaneous substitution within the rare earth (R) and Co sublattices on the structural, magnetic, and magnetocaloric properties of the Laves phase RCo2-type compounds is studied. Main attention is devoted to the studies of the magnetostructural phase transitions and the transition types with respect to the alloy composition. Multicomponent alloys Tbx(Dy0.5Ho0.5)1-xCo2 and Tbx(Dy0.5Ho0.5)1-xCo1.75Al0.25 were prepared with the use of high purity metals. Majority of the Tbx(Dy0.5Ho0.5)1-xCo2 alloys exhibit magnetic transitions of the first-order type and a large magnetocaloric effect. The substitution of Al for Co in Tbx(Dy0.5Ho0.5)1-xCo2 increases the Curie temperature (TC) but changes the transition type from first-to the second-order. The discussion of the physical mechanisms behind the observed phenomena is given on the basis of the first principles electronic-structure calculations taking into account both the atomic disorder and the magnetic disorder effects at finite temperatures. The advantage of Al-containing materials is that sufficiently high magnetocaloric effect values are preserved at T > TC.
Electromagnetic Effects on Cracking of Anisotropic Polytropes
Sharif, M
2016-01-01
In this paper, we study the electromagnetic effects on stability of spherically symmetric anisotropic fluid distribution satisfying two polytropic equations of state and construct the corresponding generalized Tolman Oppenheimer Volkoff equations. We apply perturbations on matter variables via polytropic constant as well as polytropic index and formulate the force distribution function. It is found that the compact object is stable for feasible choice of perturbed polytropic index in the presence of charge.
Anomalous anisotropic magnetoresistance effects in graphene
Directory of Open Access Journals (Sweden)
Yiwei Liu
2014-09-01
Full Text Available We investigate the effect of external stimulus (temperature, magnetic field, and gases adsorptions on anisotropic magnetoresistance (AMR in multilayer graphene. The graphene sample shows superlinear magnetoresistance when magnetic field is perpendicular to the plane of graphene. A non-saturated AMR with a value of −33% is found at 10 K under a magnetic field of 7 T. It is surprisingly to observe that a two-fold symmetric AMR at high temperature is changed into a one-fold one at low temperature for a sample with an irregular shape. The anomalous AMR behaviors may be understood by considering the anisotropic scattering of carriers from two asymmetric edges and the boundaries of V+(V- electrodes which serve as active adsorption sites for gas molecules at low temperature. Our results indicate that AMR in graphene can be optimized by tuning the adsorptions, sample shape and electrode distribution in the future application.
Magnetism and magnetocaloric effect study of CaFe0.7Co0.3O3
Xia, H. L.; Y Yin, Y.; Dai, J. H.; Y Yang, J.; Qin, X. M.; Jin, C. Q.; Long, Y. W.
2015-04-01
The CaFe0.7Co0.3O3 single crystal was grown for the first time by a two-step method and its magnetism and magnetocaloric effect were investigated. This compound experiences a second-order paramagnetism-to-ferromagnetism transition in a wide temperature window between 200 and 150 K due to the presence of multiple ferromagnetic interactions. Since the spin entropy is gradually released above the ferromagnetic Curie temperature (˜177 K), no sharp λ-type anomaly is observed in specific heat. On the basis of magnetization measurements, however, a considerable entropy change is found in this perovskite oxide. More interesting, this compound exhibits a broadening working temperature, and a significant refrigerant capacity (˜355 J kg-1 at 6 T) which is comparable with those found in some giant magnetocaloric alloys with first-order magnetic transitions. The present study therefore provides an example on how to enhance the refrigerant capacity by extending the working temperature of magnetocaloric material.
Energy Technology Data Exchange (ETDEWEB)
Dube, V.; Mishra, P. K.; Prajapat, C. L.; Singh, M. R.; Ravikumar, G. [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai-4000085 (India); Rajarajan, A. K.; Sastry, P. U. [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai-4000085 (India); Thakare, S. V. [Radio Pharmaceuticals Division, Bhabha Atomic Research Centre, Mumbai-4000085 (India)
2013-02-05
We have shown the effect of fast neutron irradiation on the magnetic phase transition and magnetocaloric effect (MCE) in a doped Ce(Fe{sub 0.96}Ru{sub 0.04}){sub 2}, intermettalic. We show that this leads to suppression of MCE and a to a disordered ferromagnetic phase.
Giant rotating magnetocaloric effect induced by highly texturing in polycrystalline DyNiSi compound
Zhang, Hu; Li, Yawei; Liu, Enke; Ke, Yajiao; Jin, Jinling; Long, Yi; Shen, Baogen
2015-07-01
Large rotating magnetocaloric effect (MCE) has been observed in some single crystals due to strong magnetocrystalline anisotropy. By utilizing the rotating MCE, a new type of rotary magnetic refrigerator can be constructed, which could be more simplified and efficient than the conventional one. However, compared with polycrystalline materials, the high cost and complexity of preparation for single crystals hinder the development of this novel magnetic refrigeration technology. For the first time, here we observe giant rotating MCE in textured DyNiSi polycrystalline material, which is larger than those of most rotating magnetic refrigerants reported so far. This result suggests that DyNiSi compound could be attractive candidate of magnetic refrigerants for novel rotary magnetic refrigerator. By considering the influence of demagnetization effect on MCE, the origin of large rotating MCE in textured DyNiSi is attributed to the coexistence of strong magnetocrystalline anisotropy and highly preferred orientation. Our study on textured DyNiSi not only provides a new magnetic refrigerant with large rotating MCE for low temperature magnetic refrigeration, but also opens a new way to exploit magnetic refrigeration materials with large rotating MCE, which will be highly beneficial to the development of rotating magnetic refrigeration technology.
Practical system for the direct measurement of magneto-caloric effect by micro-thermocouples.
Kamarád, J; Kaštil, J; Arnold, Z
2012-08-01
A system for direct measurements of the magneto-caloric effect (MCE) exploits a rapid transport of a sample into or from magnetic field in permanent Halbach-type (1 T) or superconducting (4.7 T) magnets. Time dependence of induced changes of the sample temperature, ΔT(t), is detected directly by the differential Cu-Constantan-Cu micro-thermocouples with time steps of 300 ms. A sample placed inside an evacuated simple LN(2) cryostat is either totally isolated (adiabatic conditions) or partly connected with the copper sample holder (non-adiabatic conditions). The last arrangement (a model of the Brayton cycle) is used to simulate an application of MCE in refrigeration techniques. The relations describing ΔT(t) that allow an analysis of MCE of the studied materials are based on the general cooling law. The effect of the first-order magnetic transition on MCE of selected sample is also demonstrated by non-standard ΔT(t) curves measured in the last mentioned experimental arrangements. PMID:22938309
Magnetocaloric effects in Fe4MnSi3Bxr interstitial compounds
Institute of Scientific and Technical Information of China (English)
Yongli WU; O.Tegus; Weiguang ZHANG; S.Yiriyoltu; B.Mend; Songlin
2009-01-01
The magnetic properties and magnetocaloric effect in Fe_4MnSi_3B_x compounds with x=0, 0.05, 0.10, 0.15, 0.20, 0.25 have been investigated. X-ray diffraction study shows that all these compounds investigated crystallize in the Mn_5Si_3-type structure with space group P6_3/mcm. Boron insertion in the host ternary silicide Fe_4MnSi_3 does not change the crystal symmetry, only leads to an increase of the lattice parameters, indicating the B atoms entered the interstitial sites. With increasing B content, the Curie temperature shifts to higher temperatures. The maximal magnetic-entropy changes of the Fe_4MnSi_3B_x compounds with x=0, 0.10 and 0.20 are about 1.8 J/(kg·K), 1.8 J/(kg·K) and 1.6 J/(kg·K), respectively, for a field change from 0 to 1.5 T.
Critical behavior and magnetocaloric effect in layered structure Tb2C
Zhang, Xiao; Matsuishi, Satoru; Hosono, Hideo
2016-08-01
The critical behavior and magnetocaloric effects of the layered structure Tb2C have been investigated using magnetization measurements around the Curie temperature. Analyzing temperature and field dependence of magnetization reveals that the Tb2C system undergoes a second-order magnetic phase transition at T C = 266 K. Critical exponents obtained from modified Arrott, Kouvel–Fisher (KF) and scaling plots are consistent with each other. The critical exponents suggest that the magnetic phase transition in Tb2C can be described by the mean-field model. The exchange energy declines as J(r) ~ r ‑4.547, indicating that long-range interaction dominates the exchange interaction. Consequently, the field dependence magnetic entropy change (ΔS M) of Tb2C, calculated using the Maxwell relation, clearly demonstrates that the relationship between ‑ΔS M and (H/T C)2/3 obeys the mean-field theory, supporting our conclusion of the ferromagnetism phase transition in Tb2C following the mean-field theory.
Effect of Milling Time on the Blocking Temperature of Nanoparticles of Magnetocaloric Gd5Si4
Hadimani, Ravi; Gupta, Shalbh; Harstad, Shane; Pecharsky, Vitalij; Jiles, David; David C Jiles Team; Vitalij Pecharsky Collaboration
Extensive research has been done on giant magnetocaloric material Gd5(SixGe1-x)4 to improve adiabatic temperature/isothermal entropy change. However, there have been only a few reports on fabrication of nanostructure/nanoparticles that can be used to tune various properties by changing the length scale. Recently we have reported fabrication of room temperature ferromagnetic nanoparticles of Gd5Si4 using high energy ball milling. These nanoparticles have potential applications in biomedical engineering such as better T2 MRI contrast agents and in hypothermia. Here we report the effect of milling time on the blocking temperature, micro-structure, crystal structure, and magnetic properties of these nanoparticles. Magnetization vs. temperature at an applied field of 100 Oe is measured for all the ball milled samples. Bulk Gd5Si4 has a transition temperature of ~340 K. There are two phase transitions observed in the nanoparticles, one near 300 K corresponding to the Gd5Si4 phase and another between 75-150 K corresponding to Gd5Si3. Zero Field Cooling (ZFC) and Field Cooling (FC) were measured. The blocking temperatures for the nanoparticles increase with decrease in milling time.
Influence of fabrication conditions on giant magnetocaloric effect of Ni–Mn–Sn ribbons
International Nuclear Information System (INIS)
The magnetocaloric effect of Ni50Mn50−xSnx ribbons (x = 11–15) prepared by using melt-spinning and subsequent annealing has been investigated. The x-ray diffraction data of specimens show that all the samples are partially crystallized with Ni2MnSn phase. The magnetic transitions of these ribbons strongly depend on Sn-concentration and annealing process. Particularly, the antiferromagnetic–ferromagnetic transition is just observed at a narrow range of the Sn-concentration (x = 12–14). The positive magnetic entropy changes occurring at the transition temperature of the antiferromagnetic phase are quite large, |ΔSm|max = 5.7 J kg−1 K−1 (for x = 13) with external magnetic field change ΔH = 12 kOe. Besides that, the negative magnetic entropy changes take place near Curie temperature and their magnitude is also large, |ΔSm|max = 1.9 J kg−1 K−1 (for x = 13). The obtained results indicate that Ni50Mn50−xSnx ribbons are good candidates for magnetic refrigeration application at room temperature. (paper)
Brown, T. D.; Karaman, I.; Shamberger, P. J.
2016-07-01
Magnetic refrigeration technology based on the giant magnetocaloric effect in solid-state refrigerants is known qualitatively to be limited by dissipative mechanisms accompanying hysteresis in the magneto-structural solid-solid phase transition. In this paper, we quantitatively explore the dependence of cycle performance metrics (cooling power, temperature span, work input, and fractional Carnot efficiency) on hysteresis properties (thermal hysteresis, one-way transition width) of the magneto-structural phase transition in a Ni45Co5Mn36.6In13.4 alloy system. We investigate a variety of Ericsson-type magnetic refrigeration cycles, using a Preisach-based non-equilibrium thermodynamic framework to model the evolution of the alloy's magnetic and thermal properties. Performance metrics are found to depend strongly on hysteresis parameters, regardless of the cycle chosen. However, for a given hysteresis parameter set, the material's transformation temperatures determine a unique cycle that maximizes efficiency. For the model system used undergoing Ericsson cycles with 5 and 1.5 {{T}} maximum field constraint, fractional Carnot efficiencies in excess of 0.9 require thermal hysteresis below 1.5 {{K}} and 0.5 {{K}}, respectively. We conclude briefly with some general materials considerations for mitigating these hysteresis inefficiencies through microstructure design and other materials processing strategies.
Magnetic transitions and magnetocaloric effect in MnAs0.9P0.1
Institute of Scientific and Technical Information of China (English)
Naikun SUN; Feng LIU; Yinbo GAO; Jinjun LIU
2012-01-01
The compound MnAs0.9P0.1 exhibits a multistep magnetic order-order transition from a helimagnetic γ-phase with Hα-type magnetic order to a ferromagnetic β-phase at 80 K and then to a helimagnetic α-phase at 203 K.The γ-β transition exhibits the characteristics of a first-order transition with a thermal hysteresis as large as 6 K,while the β-α transition is of second order with a thermal hysteresis smaller than 2 K and without magnetic hysteresis.With these two successive helimagnetism-related transitions,magnetic-entropy changes of -2.1 J/(kg·K) at 203 K for a field change from 0 to 5 T and 0.1 J/(kg.K) at 83 K for a field change from 0 to 1 T are obtained.Investigation of the magnetocaloric effect associated with a transition from Hα-type magnetic order to FM order may open a new route to explore candidates for magnetic refrigeration.
Magnetic properties and magnetocaloric effect in Fe90- x Sn x Zr10 alloy ribbons
Phan, T. L.; Dan, N. H.; Thanh, T. D.; Mai, N. T.; Ho, T. A.; Yu, S. C.; Le, Anh-Tuan; Phan, M. H.
2015-04-01
This work points out the possibility of tuning the magnetocaloric (MC) effect in Fe90- x Sn x Zr10 alloy ribbons in the temperature range from 235 to 315 K by changing the Sn-doping content ( x). Under an applied field change from 0 to 50 kOe, the maximum magnetic-entropy changes around the ferromagnetic-paramagnetic phase transition are about 3.6, 4.1 and 3.3 J kg-1·K-1 for x = 0, 2 and 4, respectively, which correspond to relative cooling powers of 280 ˜ 410 J·kg-1. Studying the magnetic properties of the alloy ribbons based on Banerjee's criteria and assessing the magneticordering parameter n = dLn|Δ S m |/dLn H (where Δ S m and H are the magnetic-entropy change and the magnetic field, respectively) reveals that the alloys undergo a second-order phase transition and exhibit a short-range ferromagnetic order. The nature of these phenomena is further analyzed by means of the results obtained from the analyses of the crystal structure, the Curie-Weiss law, and the Griffith phase.
Room temperature table-like magnetocaloric effect in amorphous Gd50Co45Fe5 ribbon
Liu, G. L.; Zhao, D. Q.; Bai, H. Y.; Wang, W. H.; Pan, M. X.
2016-02-01
Gd50Co45Fe5 amorphous alloy ribbon with a table-like magnetocaloric effect (MCE) suitable for the ideal Ericsson cycle at room temperature has been developed. In addition to a high magnetic transition temperature of 289 K very close to that of Gd (294 K), a relatively large value of refrigerant capacity (~521 J kg-1) has been achieved under a field change of 5 T. This value of refrigerant capacity (RC) is about 27% and 70% larger than those of Gd (~410 J kg-1) and Gd5Si2Ge2 (~306 J kg-1). More importantly, the peak value of magnetic entropy change (-Δ S\\text{M}\\max ) approaches a nearly constant value of ~3.8 J ṡ kg-1 ṡ K-1 under an applied field change of 0~5 T in a wide temperature span over 40 K around room temperature, which could be used as the candidate working material in the Ericsson-cycle magnetic regenerative refrigerator around room temperature.
Institute of Scientific and Technical Information of China (English)
Ma Sheng-Can; Wang Dun-Hui; Xuan Hai-Cheng; Shen Ling-Jia; Cao Qing-Qi; Du You-Wei
2011-01-01
We have investigated the magnetic transition and magnetocaloric effects of Mn1+χCo1-χGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn (χ = 0.11) gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.
Magnetism in Complex Oxides Probed by Magnetocaloric Effect and Transverse Susceptibility
Bingham, Nicholas S.
Magnetic oxides exhibit rich complexity in their fundamental physical properties determined by the intricate interplay between structural, electronic and magnetic degrees of freedom. The common themes that are often present in these systems are the phase coexistence, strong magnetostructural coupling, and possible spin frustration induced by lattice geometry. While a complete understanding of the ground state magnetic properties and cooperative phenomena in this class of compounds is key to manipulating their functionality for applications, it remains among the most challenging problems facing condensed-matter physics today. To address these outstanding issues, it is essential to employ experimental methods that allow for detailed investigations of the temperature and magnetic field response of the different phases. In this PhD dissertation, I will demonstrate the relatively unconventional experimental methods of magnetocaloric effect (MCE) and radio-frequency transverse susceptibility (TS) as powerful probes of multiple magnetic transitions, glassy phenomena, and ground state magnetic properties in a large class of complex magnetic oxides, including La0.7Ca0.3- xSrxMnO3 (x = 0, 0.05, 0.1, 0.2 and 0.25), Pr0.5Sr0.5MnO3, Pr1-xSrxCoO 3 (x = 0.3, 0.35, 0.4 and 0.5), La5/8- xPrxCa3/8MnO3 (x = 0.275 and 0.375), and Ca3Co2O 6. First, the influences of strain and grain boundaries, via chemical substitution and reduced dimensionality, were studied via MCE in La0.7Ca 0.3-xSrxMnO 3. Polycrystalline, single crystalline, and thin-film La0.7Ca 0.3-xSrxMnO 3 samples show a paramagnetic to ferromagnetic transition at a wide variety of temperatures as well as an observed change in the fundamental nature of the transition (i.e. first-order magnetic transition to second order magnetic transition) that is dependent on the chemical concentration and dimensionality. Systematic TS and MCE experiments on Pr0.5Sr0.5MnO 3 and Pr0.5Sr0.5CoO3 have uncovered the different nature of low
Magnetocaloric Effect in Colossal Magnetoresistance Material (La0.6Dy0.1)Sr0.3MnO3
Institute of Scientific and Technical Information of China (English)
Cai Zhirang; Xu Sujun; Liu Ning; Sun Yong; Tong Wei; Zhang Yuheng
2005-01-01
The magnetocaloric effect in the A-site doping colossal magnetoresistance material (La0.6Dy0.1)Sr0.3MnO3 was studied. From the measurement and calculation of isothermal magnetization (M-H) curves under various temperatures, a large magnetocaloric effect with ferromagnetic-paramagnetic transition, additional magnetism exchange action introduces additional magnetic entropy change was discovered. This result suggests that (La0.6Dy0.1)Sr0.3MnO3 is a suitable candidate as working substance at room temperature in magnetic refrigeration technology.
Understanding the role played by Fe on the tuning of magnetocaloric effect in Tb5Si2Ge2
Energy Technology Data Exchange (ETDEWEB)
Pereira, Andre [University of Porto, Portugal; Moreira Dos Santos, Antonio F [ORNL; Magen Dominguez, Cesar [ORNL; Sousa, Joao Bessa [University of Porto, Portugal; Algarabel, Pedro A. [University of Zaragoza, Spain; Ren, Yang [Argonne National Laboratory (ANL); Ritter, Clemens [Institut Laue-Langevin (ILL); Morellon, Luis [University of Zaragoza, Spain; Ibarra, M. Ricardo [University of Zaragoza, Spain; Araujo, Joao Pedro [University of Porto, Portugal
2011-01-01
In this work, it is shown that when replacing Ge by Fe in Tb5Si2Ge2 the structural transition still occurs and enhances the Magnetocaloric effect (up to 66%) with maximum of MCE at a critical Fe amount where the magnetic and structural transitions become fully coupled. It is observed that Fe concentration is able to mimic the e?ect of external pressure as it induces a complex microstructure, that tunes long range strain ?elds. This knowledge is crucial for the development of strategies towards materials with improved performance for e?cient magnetic refrigeration applications.
Effective orthorhombic anisotropic models for wavefield extrapolation
Ibanez-Jacome, W.
2014-07-18
Wavefield extrapolation in orthorhombic anisotropic media incorporates complicated but realistic models to reproduce wave propagation phenomena in the Earth\\'s subsurface. Compared with the representations used for simpler symmetries, such as transversely isotropic or isotropic, orthorhombic models require an extended and more elaborated formulation that also involves more expensive computational processes. The acoustic assumption yields more efficient description of the orthorhombic wave equation that also provides a simplified representation for the orthorhombic dispersion relation. However, such representation is hampered by the sixth-order nature of the acoustic wave equation, as it also encompasses the contribution of shear waves. To reduce the computational cost of wavefield extrapolation in such media, we generate effective isotropic inhomogeneous models that are capable of reproducing the firstarrival kinematic aspects of the orthorhombic wavefield. First, in order to compute traveltimes in vertical orthorhombic media, we develop a stable, efficient and accurate algorithm based on the fast marching method. The derived orthorhombic acoustic dispersion relation, unlike the isotropic or transversely isotropic ones, is represented by a sixth order polynomial equation with the fastest solution corresponding to outgoing P waves in acoustic media. The effective velocity models are then computed by evaluating the traveltime gradients of the orthorhombic traveltime solution, and using them to explicitly evaluate the corresponding inhomogeneous isotropic velocity field. The inverted effective velocity fields are source dependent and produce equivalent first-arrival kinematic descriptions of wave propagation in orthorhombic media. We extrapolate wavefields in these isotropic effective velocity models using the more efficient isotropic operator, and the results compare well, especially kinematically, with those obtained from the more expensive anisotropic extrapolator.
Wu, Rongrong; Shen, Feiran; Hu, Fengxia; Wang, Jing; Bao, Lifu; Zhang, Lei; Liu, Yao; Zhao, Yingying; Liang, Feixiang; Zuo, Wenliang; Sun, Jirong; Shen, Baogen
2016-01-01
Magnetostructural coupling, which is the coincidence of crystallographic and magnetic transition, has obtained intense attention for its abundant magnetoresponse effects and promising technological applications, such as solid-state refrigeration, magnetic actuators and sensors. The hexagonal Ni2In-type compounds have attracted much attraction due to the strong magnetostructural coupling and the resulted giant negative thermal expansion and magnetocaloric effect. However, the as-prepared samples are quite brittle and naturally collapse into powders. Here, we report the effect of particle size on the magnetostructural coupling and magnetocaloric effect in the Ni2In-type Mn-Fe-Ni-Ge compound, which undergoes a large lattice change across the transformation from paramagnetic austenite to ferromagnetic martensite. The disappearance of martensitic transformation in a large amount of austenitic phase with reducing particle size, to our best knowledge, has not been reported up to now. The ratio can be as high as 40.6% when the MnNi0.8Fe0.2Ge bulk was broken into particles in the size range of 5~15 μm. Meanwhile, the remained magnetostructural transition gets wider and the magnetic hysteresis becomes smaller. As a result, the entropy change drops, but the effective cooling power RCeffe increases and attains to the maximum at particles in the range of 20~40 μm. These observations provide constructive information and highly benefit practical applications for this class of novel magnetoresponse materials. PMID:26883719
Wu, Rongrong; Shen, Feiran; Hu, Fengxia; Wang, Jing; Bao, Lifu; Zhang, Lei; Liu, Yao; Zhao, Yingying; Liang, Feixiang; Zuo, Wenliang; Sun, Jirong; Shen, Baogen
2016-02-17
Magnetostructural coupling, which is the coincidence of crystallographic and magnetic transition, has obtained intense attention for its abundant magnetoresponse effects and promising technological applications, such as solid-state refrigeration, magnetic actuators and sensors. The hexagonal Ni2In-type compounds have attracted much attraction due to the strong magnetostructural coupling and the resulted giant negative thermal expansion and magnetocaloric effect. However, the as-prepared samples are quite brittle and naturally collapse into powders. Here, we report the effect of particle size on the magnetostructural coupling and magnetocaloric effect in the Ni2In-type Mn-Fe-Ni-Ge compound, which undergoes a large lattice change across the transformation from paramagnetic austenite to ferromagnetic martensite. The disappearance of martensitic transformation in a large amount of austenitic phase with reducing particle size, to our best knowledge, has not been reported up to now. The ratio can be as high as 40.6% when the MnNi0.8Fe0.2Ge bulk was broken into particles in the size range of 5~15 μm. Meanwhile, the remained magnetostructural transition gets wider and the magnetic hysteresis becomes smaller. As a result, the entropy change drops, but the effective cooling power RCeffe increases and attains to the maximum at particles in the range of 20~40 μm. These observations provide constructive information and highly benefit practical applications for this class of novel magnetoresponse materials.
Magneto-caloric effect in the pseudo-binary intermetallic YPrFe{sub 17} compound
Energy Technology Data Exchange (ETDEWEB)
Alvarez, Pablo [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Gorria, Pedro, E-mail: pgorria@uniovi.es [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Sanchez Llamazares, Jose L. [Division de Materiales Avanzados, Instituto Potosino de Investigacion Cientifica y Tecnologica, Camino a la presa San Jose 2055, CP 78216, San Luis Potosi (Mexico); Perez, Maria J. [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Franco, Victorino [Departamento de Fisica de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, P.O. Box 1065, 41080 Sevilla (Spain); Reiffers, Marian; Kovac, Jozef [Institute of Experimental Physics, Watsonova 47, SK-04001 Kosice (Slovakia); Puente-Orench, Ines [Institute Laue Langevin, 6 rue Jules Horowitz, 38042 Grenoble (France); Blanco, Jesus A. [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain)
2011-12-15
Highlights: Black-Right-Pointing-Pointer YPrFe{sub 17} exhibits a broad {Delta}S{sub M}(T) associated with the ferro-to-paramagnetic phase transition (T{sub C} Almost-Equal-To 290 K). Black-Right-Pointing-Pointer We obtain |{Delta}S{sub M}| Almost-Equal-To 2.3 J kg{sup -1} K{sup -1} and RCP Almost-Equal-To 100 J kg{sup -1}for a magnetic field change of 1.5 T. Black-Right-Pointing-Pointer A single master curve for {Delta}S{sub M} is found when compared with other isostructural R{sub 2}Fe{sub 17} binary alloys. - Abstract: We have synthesized the intermetallic YPrFe{sub 17} compound by arc-melting. X-ray and neutron powder diffraction show that the crystal structure is rhombohedral with R3{sup Macron }m space group (Th{sub 2}Zn{sub 17}-type). The investigated compound exhibits a broad isothermal magnetic entropy change {Delta}S{sub M}(T) associated with the ferro-to-paramagnetic phase transition (T{sub C} Almost-Equal-To 290 K). The |{Delta}S{sub M}| ( Almost-Equal-To 2.3 J kg{sup -1} K{sup -1}) and the relative cooling power ( Almost-Equal-To 100 J kg{sup -1}) have been calculated for applied magnetic field changes up to 1.5 T. A single master curve for {Delta}S{sub M} under different values of the magnetic field change can be obtained by a rescaling of the temperature axis. The results are compared and discussed in terms of the magneto-caloric effect in the isostructural R{sub 2}Fe{sub 17} (R = Y, Pr and Nd) binary intermetallic alloys.
Magnetocaloric Materials and the Optimization of Cooling Power Density
Wikus, Patrick; Canavan, Edgar; Heine, Sarah Trowbridge; Matsumoto, Koichi; Numazawa, Takenori
2014-01-01
The magnetocaloric effect is the thermal response of a material to an external magnetic field. This manuscript focuses on the physics and the properties of materials which are commonly used for magnetic refrigeration at cryogenic temperatures. After a brief overview of the magnetocaloric effect and associated thermodynamics, typical requirements on refrigerants are discussed from a standpoint of cooling power density optimization. Finally, a compilation of the most important properties of several common magnetocaloric materials is presented.
Investigation on the magnetocaloric effect in RNi2 (R: Dy, tb) melt-spun ribbon
de Souza, M. V.
2016-08-01
We report a theoretical and experimental investigation on the magnetocaloric properties of the rare earth RNi2 (R=Dy,Tb) in melt-spun ribbon and bulk form. The theoretical calculations were performed using a Hamiltonian model including the Zeeman-exchange interactions and the crystalline electrical field. Thus the magnetocaloric potential was calculated in the easy magnetic axes, in order an average over all of the possible directions. The isothermal entropy-change dependence on temperature calculated was compared with available experimental data for melt-spun ribbon and bulk material. We also investigated, theoretically and experimentally, the behavior of a DyNi2 and TbNi2 composite with optimized molar proportions and discussed this in the context of the optimum regeneration Ericsson cycle.
A universal curve for the magnetocaloric effect: an analysis based on scaling relations
Energy Technology Data Exchange (ETDEWEB)
Franco, V; Conde, A; Blazquez, J S [Departamento de Fisica de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, PO Box 1065, 41080 Sevilla (Spain); Romero-Enrique, J M [Departamento de Fisica Atomica, Molecular y Nuclear, Area de Fisica Teorica, Universidad de Sevilla, PO Box 1065, 41080 Sevilla (Spain)
2008-07-16
The universal character of the recent experimentally found master curve for the magnetic entropy change, {delta}S{sub M}, in studies of the magnetocaloric response of materials is analytically justified by using scaling arguments. The validity of the obtained scaling relations is checked against experimental data as well as the mean field and Heisenberg models. The curves are unique for each universality class. It is shown that the universal curve can be practically constructed in two different ways, reducing the number of required parameters with respect to the previous phenomenological derivation. This opens the possibility of an inexpensive screening of the performance of magnetocaloric materials, as it allows extrapolations to magnetic fields or temperatures not available in some laboratories.
Assessment of the magnetocaloric effect in La,Pr(Fe,Si) under cycling
Kaeswurm, B.; Franco, V.; Skokov, K. P.; Gutfleisch, O.
2016-05-01
The response of a magnetocaloric material to periodic variations of magnetic field and temperature corresponding to those occurring during a magnetic refrigeration process is studied. A series of simple measurement protocols are suggested which are used to obtain a value for the cyclic response of the magnetic entropy change associated with the magnetic transition. The entropy values are compared to direct measurements of the temperature change under adiabatic conditions. The procedure is illustrated on the first order magnetocaloric material La0.6Pr0.4Fe11.6Si1.4 and provides a basis for comparison of the suitability of different hysteretic magnetocaloric materials for application in a magnetic refrigerator. For the alloy studied here the peak magnetic entropy change of -28±1 J kg-1 K-1 in a field change of 2 T is not affected by cycling, but the full width at half maximum of the peak decreases from 8.7 K to 3.8 K.
Ling-Wei, Li
2016-03-01
The magnetocaloric effect (MCE) in many rare earth (RE) based intermetallic compounds has been extensively investigated during the last two decades, not only due to their potential applications for magnetic refrigeration but also for better understanding of the fundamental problems of the materials. This paper reviews our recent progress on studying the magnetic properties and MCE in some binary or ternary intermetallic compounds of RE with low boiling point metal(s) (Zn, Mg, and Cd). Some of them exhibit promising MCE properties, which make them attractive for low temperature magnetic refrigeration. Characteristics of the magnetic transition, origin of large MCE, as well as the potential application of these compounds are thoroughly discussed. Additionally, a brief review of the magnetic and magnetocaloric properties in the quaternary rare earth nickel boroncarbides RENi2B2C superconductors is also presented. Project supported by the National Natural Science Foundation of China (Grant Nos. 11374081 and 11004044), the Fundamental Research Funds for the Central Universities, China (Grant Nos. N150905001, L1509006, and N140901001), the Japan Society for the Promotion of Science Postdoctoral Fellowships for Foreign Researchers (Grant No. P10060), and the Alexander von Humboldt (AvH) Foundation (Research stipend to L. Li).
Biswas, Anis; Bingham, N. S.; Phan, T. L.; Dan, N. H.; Yu, S. C.; Phan, M. H.; Srikanth, H.
2014-05-01
A systematic study of the inverse magnetocaloric effect (IMCE) in Ni50Mn35.8Sn14.2 and Pr0.5Sr0.5MnO3 has been performed to understand the impacts of first-order phase transition (FOPT) and phase coexistence on the universality of the temperature-dependent magnetic entropy change, ΔSM(T). We show that for Ni50Mn35.8Sn14.2—a system exhibiting IMCE associated with FOPT—it is possible to construct a universal master curve to describe ΔSM(T) in different applied fields without rescaling a temperature axis. However, the universality of IMCE does not hold for Pr0.5Sr0.5MnO3—a system with coexisting ferromagnetic and antiferromagnetic phases. The proposed universal curve provides a simple method for extrapolating ΔSM in a wide range of fields and temperatures, thus giving useful guidance to the design of magnetocaloric materials for active magnetic refrigeration technology.
Bao, Lifu
2014-01-03
The effect of Al doping in MnCoGe1-xAlx compounds has been investigated. The substitution of Al for Ge enhances Mn-Mn covalent bonding by shortening the distance of nearest Mn atom layers, and thus stabilizes the hexagonal structure. As a result, first-order magnetostructural transition between ferromagnetic martensite and paramagnetic austenite takes place for the optimized compositions (x = 0.01, 0.02). Accompanied with the magnetostructural transition, large magnetocaloric effect (MCE) is observed. More doping of Al(x = 0.03, 0.04) leads to the separation of magnetic and structural transitions and remarkable reduction of MCE. © 2014 IOP Publishing Ltd.
Liu, E. K.
2013-03-28
An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting antiferromagnetic martensite to ferromagnetic state, a 200 K Curie-temperature window was established between Curie temperatures of austenite and martensite phases. In the window, a first-order magnetostructural transition between paramagnetic austenite and ferromagnetic martensite occurs with a sharp jump in magnetization, showing a magnetic entropy change as large as −40 J kg−1 K−1 in a 50 kOe field change. This giant magnetocaloric effect enables Mn1− x Co x NiGe to become a potential magnetic refrigerant.
Magnetic transition and large reversible magnetocaloric effect in EuCu1.75P2 compound
Institute of Scientific and Technical Information of China (English)
Huo De-Xuan; Liao Luo-Bing; Li Ling-Wei; Li Miao; Qian Zheng-Hong
2013-01-01
The magnetocaloric effect (MCE) in EuCul.75P2 compound is studied by the magnetization and heat capacity measurements.Magnetization and modified Arrott plots indicate that the compound undergoes a second-order phase transition at Tc ～ 51 K.A large reversible MCE is observed around Tc.The values of maximum magnetic entropy change (-△SMmax)reach 5.6 J.kg-1.K-1 and 13.3 J.kg 1.K-1 for the field change of 2 T and 7 T,respectively,with no obvious hysteresis loss in the vicinity of Curie temperature.The corresponding maximum adiabatic temperature changes (△Taadmax) are evaluated to be 2.1 K and 5.0 K.The magnetic transition and the origin of large MCE in EuCu1.75P2 are also discussed.
Magnetocaloric Effect of Ni56Mn18.8Ga24.5Gd0.7 Alloy
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
With the addition of Gd, the Ni56Mn18.8Ga24.5Gd0.7 alloy exhibits non-modulated martensite phase at room temperature. From the illustration of Gd microstructure, it can be found that Gd exists along the subgrain boundaries. Hence,he crystalline size decreases and the mechanical properties improve. Ac-susceptibility results show that Ni56Mn18.8Ga24.5Gd0.7 alloy still undergoes simultaneous structural and magnetic transitions and transforms from ferromagnetic martensitic phase to paramagnetic austenitic phase with increasing temperature. The maximum magnetic entropy change is 13.4 J· (kg· K) - 1 under 1.9 T field at 338 K. The giant magnetocaloric effect found in Ni56Mn18.8Ga24.5Gd0.7 alloy is attributed to the concurrently occurring first-order structural- and magnetic-phase transitions.
Room temperature magnetocaloric effect of La-deficient bulk perovskite manganite La 0.7MnO 3- δ
Wang, Zhiming; Xu, Qingyu; Sun, Jingzhi; Pan, Jian; Zhang, He
2011-04-01
Room temperature magnetocaloric effect in La-deficient bulk perovskite manganite La 0.7MnO 3- δ prepared by conventional solid-state reaction has been reported. The maximum value of the magnetic entropy change (about-1.32 J/kg K) and the refrigerant capacity (approximately close to 37 J/kg) had been obtained at 290 K corresponding to a magnetic field variation of 1 T for La 0.7MnO 3- δ. It is the strong Jahn-Teller coupling that changes Mn-O bond length and Mn-O-Mn bond angles and then the canted spin arrangement and induces the strong double-exchange coupling to a comparatively high magnetic transition temperature. This Curie temperature near room temperature with easy fabrication and higher chemical stability makes La 0.7MnO 3- δ a potential candidate as a working substance in magnetic refrigeration technology.
Zhou, Tiejun; Cher, M. K.; Shen, L.; Hu, J. F.; Yuan, Z. M.
2013-12-01
We report temperature and field dependent lattice structure, magnetic properties and magnetocaloric effect in epitaxial Fe50Rh50 thin films with (001) texture. Temperature-dependent XRD measurements reveal an irreversible first-order phase transition with 0.66% lattice change upon heating/cooling. First-principle calculation shows a state change of Rh from non-magnetic (0 μB) for antiferromagnetic phase to magnetic (0.93 μB) state for ferromagnetic phase. A jump of magnetization at temperature of 305 K and field more than 5 T indicates a field-assisted magnetic state change of Ru that contributes to the jump. Giant positive magnetic entropy change was confirmed by isothermal magnetization measurements and an in-situ temperature rise of 15 K. The magnetic state change of Rh between antiferromagnetic and ferromagnetic states is the main origin of giant magnetic entropy change and large thermal hysteresis observed.
Energy Technology Data Exchange (ETDEWEB)
Zhou, Tiejun, E-mail: Zhou_Tiejun@dsi.a-star.edu.sg [Data Storage Institute, A*STAR (Agency for Science Technology and Research), 5 Engineering Drive 1, Singapore 117608 (Singapore); Cher, M.K. [Data Storage Institute, A*STAR (Agency for Science Technology and Research), 5 Engineering Drive 1, Singapore 117608 (Singapore); Shen, L. [Department of Physics, 2 Science Drive 3, National University of Singapore, Singapore 117542 (Singapore); Hu, J.F.; Yuan, Z.M. [Data Storage Institute, A*STAR (Agency for Science Technology and Research), 5 Engineering Drive 1, Singapore 117608 (Singapore)
2013-12-06
We report temperature and field dependent lattice structure, magnetic properties and magnetocaloric effect in epitaxial Fe{sub 50}Rh{sub 50} thin films with (001) texture. Temperature-dependent XRD measurements reveal an irreversible first-order phase transition with 0.66% lattice change upon heating/cooling. First-principle calculation shows a state change of Rh from non-magnetic (0 μ{sub B}) for antiferromagnetic phase to magnetic (0.93 μ{sub B}) state for ferromagnetic phase. A jump of magnetization at temperature of 305 K and field more than 5 T indicates a field-assisted magnetic state change of Ru that contributes to the jump. Giant positive magnetic entropy change was confirmed by isothermal magnetization measurements and an in-situ temperature rise of 15 K. The magnetic state change of Rh between antiferromagnetic and ferromagnetic states is the main origin of giant magnetic entropy change and large thermal hysteresis observed.
Energy Technology Data Exchange (ETDEWEB)
Soffner, M E; Mansanares, A M; Gandra, F C G; Coelho, A A [Instituto de Fisica Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), CP 6165, 13083-970, Campinas, SP (Brazil); Gama, S [Departamento de Ciencias Exatas e da Terra, Universidade Federal de Sao Paulo (UNIFESP), 09972-270, Diadema, SP (Brazil); Carvalho, A Magnus G; Pires, M J M [Instituto Nacional de Metrologia, Normalizacao e Qualidade Industrial (INMETRO), 25250-020, Duque de Caxias, RJ (Brazil); Guimaraes, A O; Silva, E C da, E-mail: manoel@ifi.unicamp.b [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, 28013-602, Campos dos Goytacazes, RJ (Brazil)
2010-11-10
In this paper we demonstrate the use of the acoustic detection as an alternative way to determine the entropy variation, {Delta}S{sub T}, a parameter normally used to characterize the magnetocaloric effect. The measurements were performed for a Gd sample in the 252-316 K temperature range for magnetic fields from zero up to 50 kOe. The reversible adiabatic curves were built in a T versus H diagram, and specific heat data obtained at zero-magnetic field were employed to assign the entropy values of each curve. Subsequently, the entropy was plotted as a function of temperature for fixed magnetic fields, and therefore the isothermal entropy variation, {Delta}S{sub T}, was found as a function of the temperature for several magnetic field steps.
Magnetocaloric effect in La(Fe0.89Si0.11)13 irradiated by protons
International Nuclear Information System (INIS)
The magnetic properties and the magnetic entropy change of La(Fe0.89Si0.11)13 compounds under proton irradiation were investigated. With increasing proton fluence, the atomic displacement increased, which gave rise to increase of the lattice constant and Curie temperature. The magnetic entropy change slightly decreased with increasing proton fluence, but still remained large. Among the demonstrated attractive features of the materials, the maximum hysteresis loss almost disappeared and the relative cooling power increased slightly under proton irradiation. - Research highlights: → La(Fe0.89Si0.11)13 is well known as a giant magnetocaloric effect (MCE). → To improve its MCE, the proton was irradiated. → Tc increased to 5%. → Magnetic refrigeration efficiency was considerably improved by proton irradiation.
Large magnetocaloric effect in single crystal Pr0.63Sr0.37MnO3
Phan, Manh-Huong; Peng, Hua-Xin; Yu, Seong-Cho
2005-05-01
This article reports the magnetocaloric effect in a single crystal Pr0.63Sr0.37MnO3, which undergoes a very sharp ferromagnetic-to-paramagnetic phase transition at ˜300K. A large magnetic entropy change of 8.52J/kgK and a large adiabatic temperature change of 5.65K for an applied field change of 50kOe were observed around 300K; this allows water to be used as a heat transfer fluid in the room-temperature magnetic refrigeration regime. The distribution of entropy change (ΔSM) was found to be very uniform and which is desirable for an Ericson-cycle magnetic refrigerator. The large magnetic entropy change induced by a relatively low magnetic field change is beneficial for household application.
Magnetic properties and magnetocaloric effects in NaZn13-type La(Fe, Al)13-based compounds
Institute of Scientific and Technical Information of China (English)
Shen Bao-Gen; Hu Feng-Xia; Dong Qiao-Yan; Sun Ji-Rong
2013-01-01
In this article,our recent progress concerning the effects of atomic substitution,magnetic field,and temperature on the magnetic and magnetocaloric properties of the LaFe13-xAlx compounds are reviewed.With an increase of the aluminum content,the compounds exhibit successively an antiferromagnetic (AFM) state,a ferromagnetic (FM) state,and a mictomagnetic state.Furthermore,the AFM coupling of LaFe13-xAlx can be converted to an FM one by substituting Si for Al,Co for Fe,and magnetic rare-earth R for La,or introducing interstitial C or H atoms.However,low doping levels lead to FM clusters embedded in an AFM matrix,and the resultant compounds can undergo,under appropriate applied fields,first an AFM-FM and then an FM-AFM phase transition while heated,with significant magnetic relaxation in the vicinity of the transition temperature.The Curie temperature of LaFe13-xAlx can be shifted to room temperature by choosing appropriate contents of Co,C,or H,and a strong magnetocaloric effect can be obtained around the transition temperature.For example,for the LaFe11.5Al1.5C0.2H1.0 compound,the maximal entropy change reaches 13.8 J·kg-1·K-1 for a field change of 0-5 T,occurring around room temperature.It is 42％ higher than that of Gd,and therefore,this compound is a promising room-temperature magnetic refrigerant.
Magnetocaloric refrigeration concepts: current state of the art
DEFF Research Database (Denmark)
Nielsen, Kaspar Kirstein
2014-01-01
Refrigeration devices based on the magnetocaloric effect have been prototyped in great numbers during the past decade. The search for the optimal combination of magnetic field source, regenerator geometry, magnetocaloric material composition and flow system design has resulted in a variety of des...
Anisotropic fluid from nonlocal tidal effects
Culetu, Hristu
2014-01-01
The Shiromizu et al. \\cite{SMS} covariant decomposition formalism is used to find out the brane properties rooted from the 5-dimensional Witten bubble spacetime. The non-local tensor $E_{ab}$ generated by the 5-dimensional Weyl tensor gives rise at an anisotropic energy-momentum tensor on the brane with negative energy density and $p = \\rho/3$ as equation of state. The tidal acceleration is towards the brane and that is in accordance with the negative energy density on the brane. The anisotropic fluid has vanishing "bulk" viscosity but the shear viscosity coefficient is $r$- and $t$- dependent. The brane is endowed with an apparent horizon which is exactly the radial null geodesic.
Table-like magnetocaloric effect of Fe88-xNdxCr8B4 composite materials
Lai, J. W.; Zheng, Z. G.; Zhong, X. C.; Franco, V.; Montemayor, R.; Liu, Z. W.; Zeng, D. C.
2015-09-01
The narrow working temperature range due to the sharp magnetic entropy change |ΔSM| peak and large thermal or magnetic hysteresis restricts the practical application of magnetocaloric materials. In this work, the table-like magnetocaloric effect (MCE) was obtained in the multilayer composite of Fe88-xNdxCr8B4 alloys with various Nd substitutions for Fe (x=5, 8, 10, 12, and 15), which were prepared by arc-melting followed by melt-spinning. The substation of Nd was found to enhance the glass-forming ability. For the alloys with Nd substitution from 5 at% to 15 at%, the Curie temperature (TC) ranged from 322 K to 350 K and the peak value of |ΔSM| remained almost constant, 3.4-3.5 J/(kg K) under an applied field of 0-5 T. The composite with various Nd contents was prepared by stocking the ribbons layer by layer. The |ΔSM| of the composite approached a nearly constant value of ˜3.2 J/(kg K) in a field change of 0-5 T in a wide temperature span over 40 K, resulting in large refrigerant capacity value of >408 J/kg. This |ΔSM| value was much larger than the previous reported Fe-based amorphous composite Fe78-xCexSi4Nb5B12Cu1. This composite can be used as the working material in the Ericsson-cycle magnetic regenerative refrigerator around room temperature.
Large magnetocaloric effect in La0.845Sr0.155Mn1-xMxO3 (M = Mn, Cu, Co) perovskites
Phan, Manh-Huong; Phan, The-Long; Yu, Seong-Cho; Tho, Nguyen Duc; Chau, Nguyen
2004-06-01
We present the results of an investigation on the magnetocaloric effect in the perovskites of La0.845Sr0.155Mn1-xMxO3 (M = Mn, Cu, Co). It is found that there was a large magnetic entropy change, i.e. a large magneto-caloric effect, in all these samples. Among them, the magnetic entropy change reaches a maximum value of 2.67 J/kg K at the applied field of 13.5 kOe for the Cu-doped sample, suggesting that this material would be a suitable candidate for the advanced magnetic refrigeration technology. The large magnetic entropy change produced by the abrupt reduction of magnetization is attributed to the strong coupling between spin and lattice that occurs in the vicinity of the ferromagnetic-paramagnetic transition temperature (TC) - which is experimentally verified by electron paramagnetic resonance study.
Indian Academy of Sciences (India)
C Madhu; A Sundaresan
2008-11-01
We have investigated the magnetocaloric effect across a first order structural transition coupled to the ferromagnetic transition (C ∼ 270 K) in Pr0.1Ce0.4Sr0.5MnO3 using magnetization and heat capacity measurements. The adiabatic magnetic entropy change || obtained from magnetization measurements for a magnetic field change of 2 T is around 1.3 J/kg K. A similar value of || was obtained from the analysis of heat capacity data.
Giant low-field magnetocaloric effect in single-crystalline EuTi0.85Nb0.15O3
Roy, S.; Khan, N.; Mandal, P.
2016-02-01
The magnetocaloric effect in ferromagnetic single crystal EuTi0.85Nb0.15O3 has been investigated using magnetization and heat capacity measurements. EuTi0.85Nb0.15O3 undergoes a continuous ferromagnetic phase transition at TC = 9.5 K due to the long range ordering of magnetic moments of Eu2+ (4f7). With the application of magnetic field, the spin entropy is strongly suppressed and a giant magnetic entropy change is observed near TC. The values of entropy change ΔSm and adiabatic temperature change ΔTad are as high as 51.3 J kg-1 K-1 and 22 K, respectively, for a field change of 0-9 T. The corresponding magnetic heating/cooling capacity is 700 J kg-1. This compound also shows large magnetocaloric effect even at low magnetic fields. In particular, the values of ΔSm reach 14.7 and 23.8 J kg-1 K-1 for field changes of 0-1 T and 0-2 T, respectively. The low-field giant magnetocaloric effect, together with the absence of thermal and field hysteresis makes EuTi0.85Nb0.15O3 a very promising candidate for low temperature magnetic refrigeration.
Giant low-field magnetocaloric effect in single-crystalline EuTi0.85Nb0.15O3
Directory of Open Access Journals (Sweden)
S. Roy
2016-02-01
Full Text Available The magnetocaloric effect in ferromagnetic single crystal EuTi0.85Nb0.15O3 has been investigated using magnetization and heat capacity measurements. EuTi0.85Nb0.15O3 undergoes a continuous ferromagnetic phase transition at TC = 9.5 K due to the long range ordering of magnetic moments of Eu2+ (4f7. With the application of magnetic field, the spin entropy is strongly suppressed and a giant magnetic entropy change is observed near TC. The values of entropy change ΔSm and adiabatic temperature change ΔTad are as high as 51.3 J kg−1 K−1 and 22 K, respectively, for a field change of 0–9 T. The corresponding magnetic heating/cooling capacity is 700 J kg−1. This compound also shows large magnetocaloric effect even at low magnetic fields. In particular, the values of ΔSm reach 14.7 and 23.8 J kg−1 K−1 for field changes of 0–1 T and 0–2 T, respectively. The low-field giant magnetocaloric effect, together with the absence of thermal and field hysteresis makes EuTi0.85Nb0.15O3 a very promising candidate for low temperature magnetic refrigeration.
Debonding analyses in anisotropic materials with strain- gradient effects
DEFF Research Database (Denmark)
Legarth, Brian Nyvang
2012-01-01
A unit cell approach is adopted to numerically analyze the effect of plastic anisotropy on damage evolution in a micro-reinforced composite. The matrix material exhibit size effects and a visco-plastic anisotropic strain gradient plasticity model accounting for such size effects is adopted. A con...
Debonding Analyses in Anisotropic Materials with Strain-Gradient Effects
DEFF Research Database (Denmark)
Legarth, Brian Nyvang
2012-01-01
A unit cell approach is adopted to numerically analyze the effect of plastic anisotropy on damage evolution in a microreinforced composite. The matrix material exhibit size effects and a visco-plastic anisotropic strain gradient plasticity model accounting for such size effects is adopted....... A conventional cohesive law is extended such that both the average as well as the jump in plastic strain across the fiber-matrix interface are accounted for. Results are shown for both conventional isotropic and anisotropic materials as well as for higher order isotropic and anisotropic materials...... with and without debonding. Generally, the strain gradient enhanced material exhibits higher load carry capacity compared to the corresponding conventional material. A sudden stress drop occurs in the macroscopic stress-strain response curve due to fiber-matrix debonding and the results show that a change in yield...
Scaling and universality in magnetocaloric materials
DEFF Research Database (Denmark)
Smith, Anders; Nielsen, Kaspar Kirstein; Bahl, Christian R. H.
2014-01-01
itself. However, this is only true in the critical region near Tc and for small fields; for finite fields, scaling with constant exponents, in general, break down, even at Tc. The field dependence can then be described by field-dependent scaling exponents. We show that the scaling exponents at finite...... the framework of the Bean-Rodbell model, we briefly consider the scaling properties of the magnetocaloric effect in first-order materials. Finally, we discuss the implications of our findings for a widely used phenomenological scaling procedure for magnetocaloric quantities.......The magnetocaloric effect of a magnetic material is characterized by two quantities, the isothermal entropy change and the adiabatic temperature change, both of which are functions of temperature and applied magnetic field. We discuss the scaling properties of these quantities close to a second...
Aeroelastic modal dynamics of wind turbines including anisotropic effects
DEFF Research Database (Denmark)
Skjoldan, Peter Fisker
and the computationally efficient implicit Floquet analysis in anisotropic conditions. The tool is validated against system identifications with the partial Floquet method on the nonlinear BHawC model of a 2.3 MW wind turbine. System identification results show that nonlinear effects on the 2.3 MW turbine in most cases...
Anisotropic Effects on Magnetoelastic Transition in Magnetic Molecular Rings
Institute of Scientific and Technical Information of China (English)
LI Peng-Fei; CHEN Yu-Guang; CHEN Hong
2006-01-01
@@ We numerically study the anisotropic effects on the magnetoelastic transition in an S = 1/2 XXZ model with a finite lattice number. It is found that the order of the magnetoelastic transition is strongly affected by the anisotropy parameter A and there may exist a critical λc dividing the first-order transition and the continuous transition.
Energy Technology Data Exchange (ETDEWEB)
Xuan, H.C. [College of Materials Science and Engineering, Taiyuan University of Technology (China); National Laboratory of Solid State Microstructures and Key Laboratory of Nanomaterials for Jiang Su Province, Nanjing University (China); Zhang, Y.Q.; Li, H.; Han, P.D. [College of Materials Science and Engineering, Taiyuan University of Technology (China); Wang, D.H.; Du, Y.W. [National Laboratory of Solid State Microstructures and Key Laboratory of Nanomaterials for Jiang Su Province, Nanjing University (China)
2015-09-15
The rapidly solidified Ni{sub 41.98}Mn{sub 42.97}V{sub 2.08}Sn{sub 12.97} ribbons are prepared by the melt-spinning technique. The microstructure, martensitic transformation (MT), and magnetocaloric effect of the ribbons are greatly affected by annealing treatment. The equiaxed crystallized grains with the relatively homogeneous size distribution are observed for these ribbons. After annealing, the grain size becomes obviously large, the lattice constants decreases, and the exchange bias effect gets improved. The MT temperatures increase obviously for the annealed ribbons. Large magnetic entropy change (ΔS) is obtained in the annealed Ni-Mn-V-Sn ribbons. The peak values of ΔS in the annealed ribbons are 41.6 and -2.3 J kg{sup -1} K{sup -1} in the vicinity of MT temperature and Curie temperature of austenite, respectively, for the field change of 30 kOe. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
de Paula, V. G.; da Silva, L. M.; dos Santos, A. O.; Lang, R.; Otubo, L.; Coelho, A. A.; Cardoso, L. P.
2016-03-01
The correlation between structural and magnetic properties of GdA l2 , focusing on the role played by the disorder in magnetic ordering and how it influences the magnetocaloric effect (MCE) are discussed. Micrometric-sized particles, consisting of nanocrystallites embedded in an amorphous matrix, were prepared by a mechanical milling technique and characterized by means of x-ray diffraction, scanning and high-resolution transmission electron microscopy as well as magnetic measurements as a function of an applied external magnetic field and temperature. The results show that the average particle size is just slightly diminished (≈7%) with the milling time (between 3 and 13 h), whereas the average crystallite size undergoes an expressive reduction (≈43%). For long milling times, structural disorders mostly associated with crystallite size singularly affect the magnetic properties, leading to a large tablelike MCE in the temperature range between 30 and 165 K. Below 30 K, nanocrystallites with dimensions below a given critical size cause an enhancement in the magnetic entropy change related to superparamagnetic behavior. In contrast, for low milling times, relative cooling power values are improved. These striking features along with the small magnetic hysteresis observed make the milled GdA l2 a promising material for application in the magnetic refrigeration technology. Finally, a discussion in an attempt to elucidate the origin of the spin-glass states previously reported in the literature for mechanically milled GdA l2 samples for very long times (400 and 1000 h) is presented.
Magnetocaloric effect in La(Fe{sub x}Si{sub 1-x}){sub 13} ferromagnets
Energy Technology Data Exchange (ETDEWEB)
Valiev, E. Z., E-mail: valiev@imp.uran.ru; Kazantsev, V. A. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation)
2011-12-15
The isothermal changes in the magnetic entropy and the lattice entropy and the adiabatic temperature change in La(Fe{sub 0.88}Si{sub 0.12}){sub 13} and La(Fe{sub 0.86}Si{sub 0.14}){sub 13} ferromagnets in a magnetic field are calculated. The calculations are performed with a generalized magnetostriction model of a ferromagnet; the calculation results are compared to experimental data. It is shown that the change in the lattice entropy decreases the magnetocaloric effect and makes it possible to explain the experimental data obtained for La(Fe{sub x}Si{sub 1-x}){sub 13} (x = 0.86, 0.88) ferromagnets. The temperature dependences of the bulk compression moduli of these ferromagnets are calculated, and these dependences indicate a strong lattice softening in the vicinity of the magnetic phase transition in them. The thermal expansion coefficient and some magnetic properties of the ferromagnet with x = 0.86 are measured to determine the numerical values of the parameters entering into calculation formulas.
Kazakov, Alexander; Prudnikov, Valerii; Granovsky, Alexander; Perov, Nikolai; Dubenko, Igor; Pathak, Arjun Kumar; Samanta, Tapas; Stadler, Shane; Ali, Naushad; Zhukov, Arcady; Ilyin, Maxim; Gonzalez, Julian
2012-09-01
The magnetic, magnetotransport, and magnetocaloric properties near compound phase transitions in Ni50Mn35In14Z (Z = In, Ge, Al), and Ni48Co2Mn35In15 Heusler alloys have been studied using VSM and SQUID magnetometers (at magnetic fields (H) up to 5 T), four-probe method (at H = 0.005-1.5 T), and an adiabatic magnetocalorimeter (for H changes up to deltaH = 1.8 T), respectively. The martensitic transformation (MT) is accompanied by large magnetoresistance (up to 70%), a significant change in resistivity (up to 200%), and a sign reversal of the ordinary Hall effect coefficient, all related to a strong change in the electronic spectrum at the MT. The field dependences of the Hall resistance are complex in the vicinity of the MT, indicating a change in the relative concentrations of the austenite and martensite phases at strong fields. Negative and positive changes in adiabatic temperatures of about -2 K and +2 K have been observed in the vicinity of MT and Curie temperatures, respectively, for deltaH = 1.8 T.
Table-like magnetocaloric effect in Gd56Ni15Al27Zr2 alloy and its field independence feature
Agurgo Balfour, E.; Ma, Z.; Fu, H.; Hadimani, R. L.; Jiles, D. C.; Wang, L.; Luo, Y.; Wang, S. F.
2015-09-01
In order to obtain "table-like" magnetocaloric effect (MCE), multiple-phase Gd56Ni15Al27Zr2 alloy was prepared by arc-melting followed by suck-casting method. Powder x-ray diffraction and calorimetric measurements reveal that the sample contains both glassy and crystalline phases. The fraction of the glassy phase is about 62%, estimated from the heat enthalpy of the crystallization. The crystalline phases, Gd2Al and GdNiAl further broadened the relatively wider magnetic entropy change (-ΔSM) peak of the amorphous phase, which resulted in the table-like MCE over a maximum temperature range of 52.5 K to 77.5 K. The plateau feature of the MCE was found to be nearly independent of the applied magnetic field from 3 T to 5 T. The maximum -ΔSM value of the MCE platforms is 6.0 J/kg K under applied magnetic field change of 5 T. Below 3 T, the field independence of the table-like feature disappears. The relatively large constant values of -ΔSM for the respective applied magnetic fields have promising applications in magnetic refrigeration using regenerative Ericsson cycle.
International Nuclear Information System (INIS)
The structure of known Gd4Co3 compound is re-determined as Gd6Co4.85, adopting the Gd6Co1.67Si3 structure type, which is characterized by two disorder Co sites filling the Gd octahedral and a short Gd-Gd distance within the octahedra. The compound shows uniaxial negative thermal expansion in paramagnetic state, significant negative expansion in ferromagnetic state, and positive expansion below ca. 140 K. It also exhibits large magnetocaloric effect, with an entropy change of −6.4 J kg−1 K−1 at 50 kOe. In the lattice of the compound, Co atoms at different sites show different spin states. It was confirmed by the X-ray photoelectron spectra and calculation of electronic structure and shed lights on the abnormal thermal expansion. The stability of such compound and the origin of its magnetism are also discussed based on measured and calculated electronic structures
Effective wavefield extrapolation in anisotropic media: Accounting for resolvable anisotropy
Alkhalifah, Tariq Ali
2014-04-30
Spectral methods provide artefact-free and generally dispersion-free wavefield extrapolation in anisotropic media. Their apparent weakness is in accessing the medium-inhomogeneity information in an efficient manner. This is usually handled through a velocity-weighted summation (interpolation) of representative constant-velocity extrapolated wavefields, with the number of these extrapolations controlled by the effective rank of the original mixed-domain operator or, more specifically, by the complexity of the velocity model. Conversely, with pseudo-spectral methods, because only the space derivatives are handled in the wavenumber domain, we obtain relatively efficient access to the inhomogeneity in isotropic media, but we often resort to weak approximations to handle the anisotropy efficiently. Utilizing perturbation theory, I isolate the contribution of anisotropy to the wavefield extrapolation process. This allows us to factorize as much of the inhomogeneity in the anisotropic parameters as possible out of the spectral implementation, yielding effectively a pseudo-spectral formulation. This is particularly true if the inhomogeneity of the dimensionless anisotropic parameters are mild compared with the velocity (i.e., factorized anisotropic media). I improve on the accuracy by using the Shanks transformation to incorporate a denominator in the expansion that predicts the higher-order omitted terms; thus, we deal with fewer terms for a high level of accuracy. In fact, when we use this new separation-based implementation, the anisotropy correction to the extrapolation can be applied separately as a residual operation, which provides a tool for anisotropic parameter sensitivity analysis. The accuracy of the approximation is high, as demonstrated in a complex tilted transversely isotropic model. © 2014 European Association of Geoscientists & Engineers.
Efficient anisotropic wavefield extrapolation using effective isotropic models
Alkhalifah, Tariq Ali
2013-06-10
Isotropic wavefield extrapolation is more efficient than anisotropic extrapolation, and this is especially true when the anisotropy of the medium is tilted (from the vertical). We use the kinematics of the wavefield, appropriately represented in the high-frequency asymptotic approximation by the eikonal equation, to develop effective isotropic models, which are used to efficiently and approximately extrapolate anisotropic wavefields using the isotropic, relatively cheaper, operators. These effective velocity models are source dependent and tend to embed the anisotropy in the inhomogeneity. Though this isotropically generated wavefield theoretically shares the same kinematic behavior as that of the first arrival anisotropic wavefield, it also has the ability to include all the arrivals resulting from a complex wavefield propagation. In fact, the effective models reduce to the original isotropic model in the limit of isotropy, and thus, the difference between the effective model and, for example, the vertical velocity depends on the strength of anisotropy. For reverse time migration (RTM), effective models are developed for the source and receiver fields by computing the traveltime for a plane wave source stretching along our source and receiver lines in a delayed shot migration implementation. Applications to the BP TTI model demonstrates the effectiveness of the approach.
Giant low-field magnetocaloric effect in single-crystalline EuTi{sub 0.85}Nb{sub 0.15}O{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Roy, S.; Khan, N.; Mandal, P., E-mail: prabhat.mandal@saha.ac.in [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Calcutta 700 064 (India)
2016-02-01
The magnetocaloric effect in ferromagnetic single crystal EuTi{sub 0.85}Nb{sub 0.15}O{sub 3} has been investigated using magnetization and heat capacity measurements. EuTi{sub 0.85}Nb{sub 0.15}O{sub 3} undergoes a continuous ferromagnetic phase transition at T{sub C} = 9.5 K due to the long range ordering of magnetic moments of Eu{sup 2+} (4f{sup 7}). With the application of magnetic field, the spin entropy is strongly suppressed and a giant magnetic entropy change is observed near T{sub C}. The values of entropy change ΔS{sub m} and adiabatic temperature change ΔT{sub ad} are as high as 51.3 J kg{sup −1} K{sup −1} and 22 K, respectively, for a field change of 0–9 T. The corresponding magnetic heating/cooling capacity is 700 J kg{sup −1}. This compound also shows large magnetocaloric effect even at low magnetic fields. In particular, the values of ΔS{sub m} reach 14.7 and 23.8 J kg{sup −1} K{sup −1} for field changes of 0–1 T and 0–2 T, respectively. The low-field giant magnetocaloric effect, together with the absence of thermal and field hysteresis makes EuTi{sub 0.85}Nb{sub 0.15}O{sub 3} a very promising candidate for low temperature magnetic refrigeration.
The Effect of Magnetic Domains on the Measurement of the Magnetocaloric effect
DEFF Research Database (Denmark)
Bahl, Christian R.H.; Smith, Anders; Nielsen, Kaspar Kirstein
2014-01-01
We discuss how magnetic domains influence the magnetic entropy change calculated from magnetisation data. In a simple qualitative model we show that the effect is to change the shape of the apparent isothermal entropy change curve compared to the true curve determined by the entropy. We further...... show that failure to correct for the magnetostatic demagnetisation will augment the apparent effect of domains....
Effective Elliptic Models for Efficient Wavefield Extrapolation in Anisotropic Media
Waheed, Umair bin
2014-05-01
Wavefield extrapolation operator for elliptically anisotropic media offers significant cost reduction compared to that of transversely isotropic media (TI), especially when the medium exhibits tilt in the symmetry axis (TTI). However, elliptical anisotropy does not provide accurate focusing for TI media. Therefore, we develop effective elliptically anisotropic models that correctly capture the kinematic behavior of the TTI wavefield. Specifically, we use an iterative elliptically anisotropic eikonal solver that provides the accurate traveltimes for a TI model. The resultant coefficients of the elliptical eikonal provide the effective models. These effective models allow us to use the cheaper wavefield extrapolation operator for elliptic media to obtain approximate wavefield solutions for TTI media. Despite the fact that the effective elliptic models are obtained by kinematic matching using high-frequency asymptotic, the resulting wavefield contains most of the critical wavefield components, including the frequency dependency and caustics, if present, with reasonable accuracy. The methodology developed here offers a much better cost versus accuracy tradeoff for wavefield computations in TTI media, considering the cost prohibitive nature of the problem. We demonstrate the applicability of the proposed approach on the BP TTI model.
Zverev, V. I.; Saletskij, A. M.; Gimaev, R. R.; Tishin, A. M.; Miyanaga, T.; Staunton, J. B.
2016-01-01
The large magnetocaloric effect (MCE), which accompanies the first order ferromagnetic/anti-ferromagnetic transition in CsCl-ordered Fe-Rh alloys, has been investigated by measurements in slowly cycled magnetic fields of up to 2 T in magnitude for a range of temperatures, 300K < T < 350K. A bulk sample with composition Fe(50.4)Rh(49.6) was used and the results were compared with those produced by the ab-initio density functional theory-based disordered local moment (DLM) theory of the MCE. Th...
Monte Carlo simulation of the magnetocaloric effect in La2/3Ca1/3MnO3 single crystal
Zouari, R.; Chehaidar, A.
2016-11-01
The present work is devoted to a theoretical simulation study of the magnetocaloric effect in magnetically homogeneous La2/3 Ca1/3 Mn O3 single crystal. Using the standard Monte Carlo-Metropolis algorithm and the classical Heisenberg model Hamiltonian, we have computed the two main magnetocaloric properties such as the isothermal entropy change and the adiabatic temperature change upon an abrupt variation of the intensity of the applied magnetic field, as function of temperature. A good qualitative agreement is observed between our simulation and experiment. We have shown that the maximum entropy change increases by increasing the intensity of the applied magnetic field. In addition, it occurs at the ferromagnetic-paramagnetic transition temperature regardless of the intensity of the applied magnetic field. Our simulation shows, moreover, that the adiabatic temperature change behaves as the isothermal entropy change with respect to the material temperature and the applied magnetic field variation. Quantitatively, however, the experimental data deviate more or less, depending on powder preparation conditions, from our simulation data. This demonstrates the deviation of the prepared powders with respect to an ideal magnetic structure, as expected experimentally. Our simulation expects a maximum isothermal entropy change of - 5.2 J / kg K and a maximum adiabatic temperature change of 5.7 K under a magnetic field variation of 5 T. On approaching room temperature, the magnitude of the magnetocaloric effect in La2/3 Ca1/3 Mn O3 single crystal decreases but remains significant under a magnetic field variation of at least 2 T.
Anisotropic Paramagnetic Meissner Effect by Spin-Orbit Coupling
Espedal, Camilla; Yokoyama, Takehito; Linder, Jacob
2016-03-01
Conventional s -wave superconductors repel an external magnetic field. However, a recent experiment [A. Di Bernardo et al., Phys. Rev. X 5, 041021 (2015)] has tailored the electromagnetic response of superconducting correlations via adjacent magnetic materials. We consider another route of altering the Meissner effect where spin-orbit interactions induce an anisotropic Meissner response that changes sign depending on the field orientation. The tunable electromagnetic response opens new paths in the utilization of hybrid systems comprising magnets and superconductors.
Properties of magnetocaloric materials with a distribution of Curie temperatures
International Nuclear Information System (INIS)
The magnetocaloric properties of inhomogeneous ferromagnets that contain distributions of Curie temperatures are considered as a function of the width of such a distribution. Assuming a normal distribution of the Curie temperature, the average adiabatic temperature change, ΔTad, the isothermal magnetic entropy change, Δs, and the heat capacity, cp, in zero magnetic field and an applied magnetic field of μ0H=1T, have been calculated using the mean field model of ferromagnetism. Interestingly, both the peak position and amplitude of each of these parameters vary differently with the width of the distribution, explaining the observed mismatch of peak temperatures reported in experiments. Also, the field dependence of ΔTad and Δs is found to depend on the width of the distribution. - Highlights: → Modeled distributions of Curie temperatures affect the measured magnetocaloric effect. → The magnetocaloric physical properties are affected differently. → A distribution affects the field dependence of the magnetocaloric effect.
Energy Technology Data Exchange (ETDEWEB)
Li, Hongwei; Feng, Shutong; Ren, Jian [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai 200072 (China); Laboratory for Microstructures, Shanghai University, Shanghai 200072 (China); Zhai, Qijie; Fu, Jianxun [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai 200072 (China); Luo, Zhiping [Department of Chemistry and Physics, Fayetteville State University, Fayetteville, NC 28301 (United States); Zheng, Hongxing, E-mail: hxzheng@shu.edu.cn [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai 200072 (China); Laboratory for Microstructures, Shanghai University, Shanghai 200072 (China)
2015-10-01
The magnetostructural transition behavior and magnetocaloric effect of Mn-rich Heusler Mn–Ni–In melt-spun ribbons have been investigated in the present study. Experimental results showed that the martensitic transition temperatures decreased by substituting small amounts of Ni with Mn in Mn{sub 49+x}Ni{sub 42−x}In{sub 9} (x=0,1,2). Within a temperature range from 100 K to 380 K, the Mn{sub 49}Ni{sub 41}In{sub 9} underwent a martensitic transformation from a paramagnetic L2{sub 1}-type cubic austenite to a ferromagnetic modulated fourteen-layered monoclinic (14M) martensite, followed with a ferromagnetic→weak-magnetic transition in martensite upon cooling. While for both Mn{sub 50}Ni{sub 41}In{sub 9} and Mn{sub 51}Ni{sub 40}In{sub 9}, the paramagnetic→ferromagnetic transition in austenite occurred prior to the martensitic transformation upon cooling. Under a magnetic field change of 30 kOe, the maximum magnetic entropy changes of the Mn{sub 50}Ni{sub 41}In{sub 9} melt-spun ribbons were found to be 5.7 J/kg K and −2.3 J/kg K in the vicinity of martensitic transformation and magnetic transition of austenite, respectively. An enhanced total effective refrigeration capacity as high as 184.2 J/kg was obtained in the Mn{sub 50}Ni{sub 41}In{sub 9} melt-spun ribbons. - Highlights: • Mn-rich Heusler Mn–Ni–In melt-spun ribbons were investigated in the present study. • The compositional dependence on the magnetostructural transition behavior was clarified. • An enhanced refrigeration capacity as high as 184.2 J/kg was obtained in Mn{sub 50}Ni{sub 41}In{sub 9}.
Strain modulated large magnetocaloric effect in Sm0.55Sr0.45MnO3 epitaxial films
Giri, S. K.; Dasgupta, Papri; Poddar, A.; Sahoo, R. C.; Paladhi, D.; Nath, T. K.
2015-01-01
Epitaxial Sm0.55Sr0.45MnO3 thin films were deposited on LAO (001), LSAT (001), and STO (001) single crystalline substrates by pulsed laser deposition technique to investigate the correlation between the substrate induced film lattice strain and magnetocaloric effect (MCE). The film on LAO substrate (S_LAO), which is under compressive strain, undergoes ferromagnetic → paramagnetic transition at TC ˜ 165 K. The films on STO (S_STO) and LSAT (S_LSAT) substrates are under tensile strain and have TC ˜ 120 K and 130 K, respectively. At T LSAT films, hysteresis is also observed between field cooled cooling and warming cycle in magnetization versus temperature measurement at low magnetic field similar to first order-like magnetic phase transition. No signature of first order magnetic phase transition has been observed in the case of S_LAO film. Most interestingly, both normal (i.e., negative ΔSM) and inverse (i.e., positive ΔSM) MCE around TC and above Tp, respectively, for S_STO and S_LSAT films have been observed with maximum value of MCE ˜ 10 J kg-1 K-1. The S_STO film also exhibits a large relative cooling power of 142 J/kg for a magnetic field change of 1 T. Our findings of substrate-induced strain modulated large MCE in epitaxial Sm0.55Sr0.45MnO3 films have been well explained through the substrate induced film lattice strain, and it may be useful for active magnetic refrigerant materials.
Energy Technology Data Exchange (ETDEWEB)
Akkera, Harish Sharma [Functional Nanomaterials Research Lab, Department of Physics, Indian Institute of Technology Roorkee, Uttarakhand 247667 (India); Choudhary, Nitin [Department of Materials Science and Engineering, University of North Texas, North Texas Discovery Park, 3940 North Elm St., Denton, TX 76207 (United States); Kaur, Davinder, E-mail: dkaurfph@iitr.ac.in [Functional Nanomaterials Research Lab, Department of Physics, Indian Institute of Technology Roorkee, Uttarakhand 247667 (India)
2015-08-15
Highlights: • The Al content leads to a increase in the martensitic transformation temperature. • A maximum ΔS{sub M} = 23 mJ/cm{sup 3} K at 300 K was observed in the N{sub 49.8}Mn{sub 32.97}Al{sub 4.43}Sb{sub 12.8}. • The refrigeration capacity RC = 64.4 mJ/cm{sup 3} at 2 T for N{sub 49.8}Mn{sub 32.97}Al{sub 4.43}Sb{sub 12.8} film. - Abstract: We systematically investigated the influence of aluminium (Al) content on the martensitic transformations and magnetocaloric effect (MCE) in Ni–Mn–Sb ferromagnetic shape memory alloy (FSMA) thin films. The temperature-dependent magnetization (M–T) and resistance (R–T) results displayed a monotonic increase in martensitic transformation temperature (T{sub M}) with increasing Al content. From the isothermal magnetization (M–H) curves, a large magnetic entropy change (ΔS{sub M}) of 23 mJ/cm{sup 3} K was observed in N{sub 49.8}Mn{sub 32.97}Al{sub 4.43}Sb{sub 12.8}. A remarkable enhancement of MCE could be attributed to the significant change in the magnetization of Ni–Mn–Sb films with increasing Al content. Furthermore, a high refrigerant capacity (RC) was observed in Ni–Mn–Sb–Al thin films as compared to pure Ni–Mn–Sb. The substitution of Al for Mn in Ni–Mn–Sb thin films with field induced MCE are potential candidates for micro length scale magnetic refrigeration applications where low magnetic fields are desirable.
Mastering hysteresis in magnetocaloric materials.
Gutfleisch, O; Gottschall, T; Fries, M; Benke, D; Radulov, I; Skokov, K P; Wende, H; Gruner, M; Acet, M; Entel, P; Farle, M
2016-08-13
Hysteresis is more than just an interesting oddity that occurs in materials with a first-order transition. It is a real obstacle on the path from existing laboratory-scale prototypes of magnetic refrigerators towards commercialization of this potentially disruptive cooling technology. Indeed, the reversibility of the magnetocaloric effect, being essential for magnetic heat pumps, strongly depends on the width of the thermal hysteresis and, therefore, it is necessary to understand the mechanisms causing hysteresis and to find solutions to minimize losses associated with thermal hysteresis in order to maximize the efficiency of magnetic cooling devices. In this work, we discuss the fundamental aspects that can contribute to thermal hysteresis and the strategies that we are developing to at least partially overcome the hysteresis problem in some selected classes of magnetocaloric materials with large application potential. In doing so, we refer to the most relevant classes of magnetic refrigerants La-Fe-Si-, Heusler- and Fe2P-type compounds.This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'.
Magnetotransport properties and magnetocaloric effects of Mn1.95Cr0.05Sb0.95Ga0.05 Compound
Institute of Scientific and Technical Information of China (English)
Liu Xi-Bin; Zhang Shao-Ying; Shen Bao-Gen; Yao Jin-Lei; Wang Fang
2004-01-01
The magnetotransport properties and magnetocaloric effects of the compound Mn1.95Cr0.05Sb0.95Ga0.05 have been studied. With decreasing temperature, a spontaneous first-order magnetic phase transition from ferrimagnetic (FI) to antiferromagnetic (AF) state takes place at Ts＝200K. A metamagnetic transition from the AF to FI state can be induced by an external field, accompanied by a giant magnetoresistance effect of 57%. The magnetic entropy changes are determined from the temperature and field dependence of the magnetization using the thermodynamic Maxwell relation. Mn1.95Cr0.05Sb0.95Ga0.05 exhibits a negative magnetocaloric effect, and the absolute values of △Smax M (T, △H) are 4.4, 4.1, 3.6, 2.8 and 1.5 J/(kg.K) for magnetic field changes of 0-5T, 0-4T, 0-3T, 0-2T and 0-1T,respectively.
Energy Technology Data Exchange (ETDEWEB)
Gourdon, Olivier, E-mail: gourdono@lanl.gov [Los Alamos Neutron Scattering Center, National Laboratory, Los Alamos, NM 87545 (United States); Gottschlich, Michael; Persson, Joerg [Jülich Center for Neutron Science JCNS-2 and Peter Grünberg Institut PGI-4, JARA-FIT, Forschungszentrum Jülich 52425 Jülich (Germany); Cruz, Clarina de la [Quantum Condensed Matter Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Petricek, Vaclav [Institute of Physics ASCR v.v.i., Na Slovance 2, 182 21 Prague (Czech Republic); McGuire, Michael A. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Brückel, Thomas [Jülich Center for Neutron Science JCNS-2 and Peter Grünberg Institut PGI-4, JARA-FIT, Forschungszentrum Jülich 52425 Jülich (Germany)
2014-08-15
The intermetallic compound MnFe{sub 4}Si{sub 3} has been studied by high-resolution Time of Flight (TOF) neutron powder diffraction. MnFe{sub 4}Si{sub 3} crystallizes in the hexagonal space group P6{sub 3}/mcm with lattice constants of a=b=6.8043(4) Å and c=4.7254(2) Å at 310 K. Magnetic susceptibility measurements show clearly the magnetic transition from paramagnetism to ferromagnetism at about 302(2) K. Magnetic structure refinements based on neutron powder diffraction data with and without external magnetic field reveal strong evidence on the origin of the large magnetocaloric effect (MCE) in this material as a partial reordering of the spins between ∼270 K and 300 K. In addition, electronic structure calculations using the self-consistent, spin-polarized Tight Binding-Linear MuffinTin Orbital (TB-LMTO) method were also accomplished to address the “coloring problem” (Mn/Fe site preference) as well as the unique ferromagnetic behavior of this intermetallic compound. - Graphical abstract: Theoretical and experimental reinvestigation of the magnetic structure of MnFe{sub 4}Si{sub 3} for a better understanding of its large magnetocaloric effect (MCE). - Highlights: • Strong magnetic transition from paramagnetism to ferromagnetism at about 302(2) K. • MCE associated to a partial reordering of the spins between ∼270 K and 300 K. • DFT calculations show strong relation between MCE and spintronic materials.
Energy Technology Data Exchange (ETDEWEB)
Liu, Xianguo; Feng, Chao; Xiao, Feng; Jin, Chuangui; Xia, Ailin, E-mail: liuxianguohugh@gmail.com, E-mail: eeswor@polyu.edu.hk [Anhui Key Laboratory of Metal Materials and Processing, School of Materials Science and Engineering, Anhui University of Technology, Ma' anshan, PR (China); Or, Siu Wing [Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Sun, Yuping [Center for Engineering Practice and Innovation Education, Anhui University of Technology, Ma' anshan, PR (China)
2014-01-15
A facile hydrothermal strategy is proposed to synthesize flower-like β- Co(OH){sub 2} hierarchical microspherical superstructures with a diameter of 0.5-1.5 µm, which are self-assembled by β - Co(OH){sub 2} nano sheets with the average thickness ranging between 20 and 40 nm. The magnetocaloric effect associated with magnetic phase transitions in Co(OH){sub 2} superstructures has been investigated. A sign change in the magnetocaloric effect is induced by a magnetic field, which is related to a filed-induced transition from the antiferromagnetic to the ferromagnetic state below the Néel temperature. The large reversible magnetic-entropy change –ΔS{sub m} (13.4 J/kg K at 15 K for a field change of 5 T) indicates that flower-like Co(OH){sub 2} superstructures is a potential candidate for application in magnetic refrigeration in the low-temperature range. (author)
Energy Technology Data Exchange (ETDEWEB)
Xing, Dawei; Jiang, Sida; Chen, Dongming; Liu, Yanfen; Sun, Jianfei [School of Materials Science and Engineering, Harbin Institute of Technology (China); Shen, Hongxian [School of Materials Science and Engineering, Harbin Institute of Technology (China); Institute of Materials and Department of Physics, University of South Florida, Tampa, FL (United States); Liu, Jingshun [School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot (China); Phan, Manh-Huong [Institute of Materials and Department of Physics, University of South Florida, Tampa, FL (United States); Wang, Huan; Qin, Faxiang [Institute for Composites Science and Innovation (InCSI), College of Materials Science and Engineering, Zhejiang University, Hangzhou (China)
2015-09-15
High-quality Gd{sub 60}Co{sub 15}Al{sub 25} microwires with an average diameter of 40 μm were successfully fabricated by the melt-extraction method. The as-cast microwires undergo a second-order paramagnetic to ferromagnetic (PM-FM) transition at ∝100 K. Large values of the magnetic entropy change (-ΔS{sub M} ∝9.73 J kg{sup -1} K{sup -1}) and the refrigerant capacity (RC ∝732 J kg{sup -1}) are achieved for a field change of 5 T. A careful analysis of critical exponents near the PM-FM transition indicates the significant effects of structural disorder on the long-range ferromagnetic interaction and the magnetocaloric response of the microwires. The excellent magnetocaloric properties make the Gd{sub 60}Co{sub 15}Al{sub 25} microwires very promising for use in magnetic refrigerators operating in the liquid nitrogen temperature range. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Energy Technology Data Exchange (ETDEWEB)
Blázquez, J.S., E-mail: jsebas@us.es [Dpto. Física de la Materia Condensada, Universidad de Sevilla, ICMSE-CSIC. P.O. Box 1065, 41080 Sevilla (Spain); Moreno-Ramírez, L.M.; Ipus, J.J. [Dpto. Física de la Materia Condensada, Universidad de Sevilla, ICMSE-CSIC. P.O. Box 1065, 41080 Sevilla (Spain); Kiss, L.F.; Kaptás, D.; Kemény, T. [Wigner Research Centre for Physics, Hungarian Academy of Sciences, P.O.Box 49, 1525 Budapest (Hungary); Franco, V.; Conde, A. [Dpto. Física de la Materia Condensada, Universidad de Sevilla, ICMSE-CSIC. P.O. Box 1065, 41080 Sevilla (Spain)
2015-10-15
In this work, the theoretical field dependence of the magnetic entropy change far away from the transition is used to analyze the field dependence of composite materials formed by fcc La(Fe,Si){sub 13} and bcc α-Fe(Si) phases. A non-interacting phases approximation is followed in the analysis and results are in good agreement with microstructural data obtained from X-ray diffraction and Mössbauer spectroscopy. The range of validity of the approximation is estimated. It is concluded that the quadratic field dependence of magnetic entropy change is reached a few tens of kelvin above the transition temperature at 1.5 T. However, the linear dependence (characteristic of ferromagnets well below its Curie temperature) is only reached a few hundred kelvin below the transition. The results presented here can be used in the deconvolution of the contribution of impurities to the MCE signal in composites. - Highlights: • Field dependence of the magnetocaloric effect is analyzed for two-phase systems. • Fraction of impurity phases is directly obtained from the analysis of field dependence of the magnetocaloric response. • The thermal range of validity of the present analysis is discussed.
Effective stress law for anisotropic double porous media
Institute of Scientific and Technical Information of China (English)
ZHAO Ying; CHEN Mian; ZHANG Guangqing
2004-01-01
An effective stress law is derived analytically to describe the effect of pore (fracture pore and matrix-block pore) fluid pressure on the linearly elastic response of anisotropic saturated dual-porous rocks, which exhibit anisotropy. For general anisotropy the difference between the effective stress and the applied stress is not hydrostatic simply multiplied by Biot coefficient. The effective stress law involves four constants for transversely isotropic response; these constants can be expressed in terms of the moduli of the single porous material, double porous material and of the solid material. These expressions are simplified considerably when the anisotropy is structural rather than intrinsic, i.e. in the case of an isotropic solid material with an anisotropic pore structure. In this case the effective stress law involves grain bulk modulus, four moduli and two compliances of the porous material for transverse isotropy. The law reduces, in the case of isotropic response, to that suggested by Li Shuiquan (2001). And reduction to the single-porosity (derived analytically by Carroll (1979)) is presented to demonstrate the conceptual consistency of the proposed law.
Spin Hall effect of a light beam in anisotropic metamaterials
Institute of Scientific and Technical Information of China (English)
Tang Ming; Zhou Xin-Xing; Luo Hai-Lu; Wen Shuang-Chun
2012-01-01
We theoretically investigate a switchable spin Hall effect of light (SHEL) in reflection for three specific dispersion relations at an air-anisotropic metamaterial interface.The displacements of horizontal and vertical polarization components vary with the incident angle at different dispersion relations.The transverse displacements can be obtained with the relevant metamaterial whose refractive index can be arbitrarily tailed.The results of the SHEL in the metamaterial provide a new way for manipulating the transverse displacements of a specific polarization component.
Das, Chinmoy; Vaidya, Shefali; Gupta, Tulika; Frost, Jamie M; Righi, Mattia; Brechin, Euan K; Affronte, Marco; Rajaraman, Gopalan; Shanmugam, Maheswaran
2015-10-26
Three cationic [Ln4 ] squares (Ln=lanthanide) were isolated as single crystals and their structures solved as [Dy4 (μ4 -OH)(HL)(H2 L)3 (H2 O)4 ]Cl2 ⋅(CH3 OH)4 ⋅(H2 O)8 (1), [Tb4 (μ4 -OH)(HL)(H2 L)3 (MeOH)4 ]Cl2 ⋅(CH3 OH)4 ⋅(H2 O)4 (2) and [Gd4 (μ4 -OH)(HL)(H2 L)3 (H2 O)2 (MeOH)2 ]Br2 ⋅(CH3 OH)4 ⋅(H2 O)3 (3). The structures are described as hydroxo-centered squares of lanthanide ions, with each edge of the square bridged by a doubly deprotonated H2 L(2-) ligand. Alternating current magnetic susceptibility measurements show frequency-dependent out-of-phase signals with two different thermally assisted relaxation processes for 1, whereas no maxima in χM " appears above 2.0 K for complex 2. For 1, the estimated effective energy barrier for these two relaxation processes is 29 and 100 K. Detailed ab initio studies reveal that complex 1 possesses a toroidal magnetic moment. The ab initio calculated anisotropies of the metal ions in complex 1 were employed to simulate the magnetic susceptibility by using the Lines model (POLY_ANISO) and this procedure yields J1 =+0.01 and J2 =-0.01 cm(-1) for 1 as the two distinct exchange interactions between the Dy(III) ions. Similar parameters are also obtained for complex 1 (and 2) from specific heat measurements. A very weak antiferromagnetic super-exchange interaction (J1 =-0.043 cm(-1) and g=1.99) is observed between the metal centers in 3. The magnetocaloric effect (MCE) was estimated by using field-dependent magnetization and temperature-dependent heat-capacity measurements. An excellent agreement is found for the -ΔSm values extracted from these two measurements for all three complexes. As expected, 3 shows the largest -ΔSm variation (23 J Kg(-1) K(-1) ) among the three complexes. The negligible magnetic anisotropy of Gd indeed ensures near degeneracy in the (2S+1) ground state microstates, and the weak super-exchange interaction facilitates dense population of low-lying excited states, all of
Microstructure and magnetocaloric effect in as-quenched GdGeSi alloys with addition of Ni and Ce
Energy Technology Data Exchange (ETDEWEB)
Hasiak, Mariusz [Department of Mechanics and Materials Science, Wroclaw University of Science and Technology (Poland)
2016-05-15
Microstructure as well as AC and DC thermomagnetic properties were studied for the as-quenched Gd{sub 80}Ge{sub 15}Si{sub 5}, Gd{sub 75}Ge{sub 15}Si{sub 5}Ni{sub 5} and Gd{sub 75}Ge{sub 15}Si{sub 5}Ce{sub 5} (wt.%) alloys in a wide range of magnetic fields. The structural investigations performed by X-ray diffractometry show the presence of Gd-based phases in the investigated alloys. These results were also confirmed by structure investigations as temperature dependence of specific heat capacity. Besides the crystalline phases discovered in the samples the regions with different atom concentration were observed in Ni and Ce-containing alloys. The Curie temperature for the Gd{sub 80}Ge{sub 15}Si{sub 5}, Gd{sub 75}Ge{sub 15}Si{sub 5}Ni{sub 5} and Gd{sub 75}Ge{sub 15}Si{sub 5}Ce{sub 5} alloys is 272, 235, and 284 K, respectively. The magnetocaloric effect (MCE) calculated as magnetic entropy change (-ΔS{sub M}) depends on magnetizing field and for the Gd{sub 80}Ge{sub 15}Si{sub 5} and Gd{sub 75}Ge{sub 15}Si{sub 5}Ni{sub 5} alloys reaches almost the same maximum value of 12 J kg{sup -1} K{sup -1}. Ce-containing sample shows about 2.4 times lower MCE than the master alloy. Magnetic entropy change (-ΔS{sub M}) versus temperature for the Gd{sub 80}Ge{sub 15}Si{sub 5}, Gd{sub 75}Ge{sub 15}Si{sub 5}Ni{sub 5}, and Gd{sub 75}Ge{sub 15}Si{sub 5}Ce{sub 5} alloys calculated for the maximum magnetizing field of 3 T. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Aeroelastic modal dynamics of wind turbines including anisotropic effects
Energy Technology Data Exchange (ETDEWEB)
Fisker Skjoldan, P.
2011-03-15
Several methods for aeroelastic modal analysis of a rotating wind turbine are developed and used to analyse the modal dynamics of two simplified models and a complex model in isotropic and anisotropic conditions. The Coleman transformation is used to enable extraction of the modal frequencies, damping, and periodic mode shapes of a rotating wind turbine by describing the rotor degrees of freedom in the inertial frame. This approach is valid only for an isotropic system. Anisotropic systems, e.g., with an unbalanced rotor or operating in wind shear, are treated with the general approaches of Floquet analysis or Hill's method which do not provide a unique reference frame for observing the modal frequency, to which any multiple of the rotor speed can be added. This indeterminacy is resolved by requiring that the periodic mode shape be as constant as possible in the inertial frame. The modal frequency is thus identified as the dominant frequency in the response of a pure excitation of the mode observed in the inertial frame. A modal analysis tool based directly on the complex aeroelastic wind turbine code BHawC is presented. It uses the Coleman approach in isotropic conditions and the computationally efficient implicit Floquet analysis in anisotropic conditions. The tool is validated against system identifications with the partial Floquet method on the nonlinear BHawC model of a 2.3 MW wind turbine. System identification results show that nonlinear effects on the 2.3 MW turbine in most cases are small, but indicate that the controller creates nonlinear damping. In isotropic conditions the periodic mode shape contains up to three harmonic components, but in anisotropic conditions it can contain an infinite number of harmonic components with frequencies that are multiples of the rotor speed. These harmonics appear in calculated frequency responses of the turbine. Extreme wind shear changes the modal damping when the flow is separated due to an interaction between
Fracture of anisotropic materials with plastic strain-gradient effects
DEFF Research Database (Denmark)
Legarth, Brian Nyvang
2013-01-01
A unit cell is adopted to numerically analyze the effect of plastic anisotropy on frac-ture evolution in a micro-reinforced fiber-composite. The matrix material exhibit size-effects and an anisotropic strain-gradient plasticity model accounting for such size-effects through a mate-rial length scale...... parameter is adopted. The fracture process along the fiber-matrix interface is modeled using a recently proposed cohesive law extension having an additional material length parameter. Due to the fiber-matrix fracture a sudden stress-drop is seen in the macroscopic stress-strain response which defines...... the failure strain of the composite. The effect of the two material length parameters on the failure strain of the composite is studied. For small values of the material length scale parameter conventional predictions are obtained. Larger values of the material length scale parameter result in corresponding...
Directory of Open Access Journals (Sweden)
Hyeon Seo
Full Text Available Subdural cortical stimulation (SuCS is an appealing method in the treatment of neurological disorders, and computational modeling studies of SuCS have been applied to determine the optimal design for electrotherapy. To achieve a better understanding of computational modeling on the stimulation effects of SuCS, the influence of anisotropic white matter conductivity on the activation of cortical neurons was investigated in a realistic head model. In this paper, we constructed pyramidal neuronal models (layers 3 and 5 that showed primary excitation of the corticospinal tract, and an anatomically realistic head model reflecting complex brain geometry. The anisotropic information was acquired from diffusion tensor magnetic resonance imaging (DT-MRI and then applied to the white matter at various ratios of anisotropic conductivity. First, we compared the isotropic and anisotropic models; compared to the isotropic model, the anisotropic model showed that neurons were activated in the deeper bank during cathodal stimulation and in the wider crown during anodal stimulation. Second, several popular anisotropic principles were adapted to investigate the effects of variations in anisotropic information. We observed that excitation thresholds varied with anisotropic principles, especially with anodal stimulation. Overall, incorporating anisotropic conductivity into the anatomically realistic head model is critical for accurate estimation of neuronal responses; however, caution should be used in the selection of anisotropic information.
Effect of Interplanetary Transients on Cosmic Ray Anisotropic Variations
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
In the present work the cosmic ray intensity data recorded with ground-based neutron monitor at Deep River has investigated taking into account the associated interplanetary magnetic field and solar wind plasma data during 1981-1994. A large number of days having abnormally high/low amplitudes for successive number of five or more days as compared to annual average amplitude of diurnal anisotropy have been taken as high/low amplitude anisotropic wave train events (HAE/LAE). The amplitude of the diurnal anisotropy of these events is found to increase on the days of magnetic cloud as compared to the days prior to the event and it found to decrease during the later period of the event as the cloud passes the Earth. The High-Speed Solar Wind Streams (HSSWS) do not play any significant role in causing these types of events. The interplanetary disturbances (magnetic clouds) are also effective in producing cosmic ray decreases. Hα solar flares have a good positive correlation with both amplitude and direction of the anisotropy for HAEs,whereas PMSs have a good positive correlation with both amplitude and direction of the anisotropy for LAEs.The source responsible for these unusual anisotropic wave trains in CR has been proposed.
Reciprocal relations for effective conductivities of anisotropic media
Nevard, John; Keller, Joseph B.
1985-11-01
Any pair of two-dimensional anisotropic media with local conductivity tensors that are functions of position and that are related to one another in a certain reciprocal way are considered. It is proved that their effective conductivity tensors are related to each other in the same way for both spatially periodic media and statistically stationary random media. An inequality involving the effective conductivity tensors of two three-dimensional media that are reciprocally related is also proved. These results extend the corresponding results for locally isotropic media obtained by Keller, Mendelsohn, Hansen, Schulgasser, and Kohler and Papanicolau. They also yield a relation satisfied by the effective conductivity tensor of a medium reciprocal to a translated or rotated copy of itself.
Strain dependent magnetocaloric effect in La0.67Sr0.33MnO3 thin-films
Suresh Kumar, V.; Rami Chukka; Zuhuang Chen; Ping Yang; Lang Chen
2013-01-01
The strain dependent magnetocaloric properties of La0.67Sr0.33MnO3 thin films deposited on three different substrates (001) LaAlO3 (LAO), (001) SrTiO3 (STO), and (001) La0.3Sr0.7Al0.65Ta0.35O9 (LSAT) have been investigated under low magnetic fields and around magnetic phase transition temperatures. Compared to bulk samples, we observe a remarkable decrease in the ferromagnetic transition temperature that is close to room temperature, closely matched isothermal magnetic entropy change and rela...
Feng, Shutong; Fang, Yue; Zhai, Qijie; Luo, Zhiping; Zheng, Hongxing
2016-10-01
A modified high-pressure optical zone-melting technique was adopted to grow a rare-earth-based LaFe11Si2 crystal in the present work. Dual-phase coupled microstructure was obtained where aligned α(Fe) phase distributed in the La(Fe,Si)13 matrix. Magnetic measurements showed that the produced crystal underwent a second-order magnetic transition in the vicinity of 250 K. Under a magnetic field change of 30 kOe, the refrigeration capacity (RC) of the produced crystal reached up to 162 J/kg. It was confirmed that zone-melting crystal growth technique is an effective approach to strikingly enhance the magnetocaloric effect of La-Fe-Si refrigeration materials.
Exchange Bias and Inverse Magnetocaloric Effect in Co and Mn Co-Doped Ni2MnGa Shape Memory Alloy
Directory of Open Access Journals (Sweden)
Yong Liu
2013-01-01
Full Text Available Exchange bias effect observed in the Ni1.68Co0.32Mn1.20Ga0.80 alloy confirms the coexistence of antiferromagnetic and ferromagnetic phases in the martensite phase. A large inverse magnetocaloric effect has been observed within the martensitic transformation temperature range, which is originated from modified magnetic order through magnetic-field-induced phase transformation from partially antiferromagnetic martensite to ferromagnetic austenite. The magnetic entropy change is 16.2 J kg−1 K−1 at 232 K under ΔH = 60 kOe, with the net refrigerant capacity of 68 J kg−1. These properties indicate Co and Mn co-doped Ni2MnGa alloy is a multifunctional material potentially suitable for magnetic refrigeration and spintronics applications.
Effective Orthorhombic Anisotropic Models for Wave field Extrapolation
Ibanez Jacome, Wilson
2013-05-01
Wavefield extrapolation in orthorhombic anisotropic media incorporates complicated but realistic models, to reproduce wave propagation phenomena in the Earth\\'s subsurface. Compared with the representations used for simpler symmetries, such as transversely isotropic or isotropic, orthorhombic models require an extended and more elaborated formulation that also involves more expensive computational processes. The acoustic assumption yields more efficient description of the orthorhombic wave equation that also provides a simplified representation for the orthorhombic dispersion relation. However, such representation is hampered by the sixth-order nature of the acoustic wave equation, as it also encompasses the contribution of shear waves. To reduce the computational cost of wavefield extrapolation in such media, I generate effective isotropic inhomogeneous models that are capable of reproducing the first-arrival kinematic aspects of the orthorhombic wavefield. First, in order to compute traveltimes in vertical orthorhombic media, I develop a stable, efficient and accurate algorithm based on the fast marching method. The derived orthorhombic acoustic dispersion relation, unlike the isotropic or transversely isotropic one, is represented by a sixth order polynomial equation that includes the fastest solution corresponding to outgoing P-waves in acoustic media. The effective velocity models are then computed by evaluating the traveltime gradients of the orthorhombic traveltime solution, which is done by explicitly solving the isotropic eikonal equation for the corresponding inhomogeneous isotropic velocity field. The inverted effective velocity fields are source dependent and produce equivalent first-arrival kinematic descriptions of wave propagation in orthorhombic media. I extrapolate wavefields in these isotropic effective velocity models using the more efficient isotropic operator, and the results compare well, especially kinematically, with those obtained from the
Magnetocaloric heat pump device, a heating or cooling system and a magnetocaloric heat pump assembly
DEFF Research Database (Denmark)
2014-01-01
The invention provides a magnetocaloric heat pump device, comprising a magnetocaloric bed; a magnetic field source, the magnetocaloric bed and the magnetic field source being arranged to move relative to each other so as to generate a magnetocaloric refrigeration cycle within the heat pump, wherein...
Giant magnetocaloric effect in magnetically frustrated EuHo2O4 and EuDy2O4 compounds
Midya, A.; Khan, N.; Bhoi, D.; Mandal, P.
2012-09-01
We have investigated the magnetic and magnetocaloric properties of EuHo2O4 and EuDy2O4 by magnetization and heat capacity measurements down to 2 K. These compounds undergo a field-induced antiferromagnetic to ferromagnetic transition and exhibit a huge entropy change. For a field change of 0-8 T, the maximum magnetic entropy and adiabatic temperature changes are 30 (25) J kg-1 K-1 and 12.7 (16) K, respectively, and the corresponding value of refrigerant capacity is 540 (415) J kg-1 for EuHo2O4 (EuDy2O4). These magnetocaloric parameters also remain large down to lowest temperature measured and are even larger than that for some of the potential magnetic refrigerants reported in the same temperature range. Moreover, these materials are highly insulating and exhibit no thermal and field hysteresis, fulfilling the necessary conditions for a good magnetic refrigerant in the low-temperature region.
Magnetocaloric effect in La(Fe{sub 0.89}Si{sub 0.11}){sub 13} irradiated by protons
Energy Technology Data Exchange (ETDEWEB)
Kim, Sol Ji [Department of Physics, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Lee, Kyu Jun; Jung, Myung Hwa [Department of Physics, Sogang University, Seoul 121-742 (Korea, Republic of); Oh, Hyun Jin [Department of Ophthalmic Optics, Masan University, Chanwon 630-729 (Korea, Republic of); Kwon, Yong Seung, E-mail: yskwon@skku.ac.k [Department of Physics, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)
2011-04-15
The magnetic properties and the magnetic entropy change of La(Fe{sub 0.89}Si{sub 0.11}){sub 13} compounds under proton irradiation were investigated. With increasing proton fluence, the atomic displacement increased, which gave rise to increase of the lattice constant and Curie temperature. The magnetic entropy change slightly decreased with increasing proton fluence, but still remained large. Among the demonstrated attractive features of the materials, the maximum hysteresis loss almost disappeared and the relative cooling power increased slightly under proton irradiation. - Research highlights: > La(Fe{sub 0.89}Si{sub 0.11}){sub 13} is well known as a giant magnetocaloric effect (MCE). > To improve its MCE, the proton was irradiated. > T{sub c} increased to 5%. > Magnetic refrigeration efficiency was considerably improved by proton irradiation.
Ulyanov, A. N.; Kang, Y. M.; Yoo, S. I.
2008-04-01
Metamagnetic transition was observed in low magnetic field for La0.7Ca0.3MnO3-δ lanthanum manganite prepared by solid-state technology. Magnetization shape causes giant low field magnetocaloric effect at Curie temperature TC=242K. Magnetic entropy changes ΔSm, deduced with isothermal magnetization curves, are equal to 7.0 and 8.0J /kgK in the field change from 0 to 1.0 and 2.0T, respectively. The obtained ΔSm are essentially higher than that reported before for lanthanum manganites with similar TC. The observation shows the way for the construction the magnetic refrigerants, working in the field of permanent magnets, which is beneficial for household and automotive applications.
Anisotropic hydrodynamics, holography and the chiral magnetic effect
Energy Technology Data Exchange (ETDEWEB)
Gahramanov, Ilmar; Kalaydzhyan, Tigran; Kirsch, Ingo [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Hamburg Univ. (Germany). Zentrum fuer Mathematische Physik
2012-03-15
We discuss a possible dependence of the chiral magnetic effect (CME) on the elliptic flow coefficient {upsilon}{sub 2}. We first study this in a hydrodynamic model for a static anisotropic plasma with multiple anomalous U(1) currents. In the case of two charges, one axial and one vector, the CME formally appears as a first-order transport coefficient in the vector current. We compute this transport coefficient and show its dependence on {upsilon}{sub 2}. We also determine the CME-coefficient from first-order corrections to the dual AdS background using the fluid-gravity duality. For small anisotropies, we find numerical agreement with the hydrodynamic result. (orig.)
An effective one-dimensional anisotropic fingerprint enhancement algorithm
Ye, Zhendong; Xie, Mei
2012-01-01
Fingerprint identification is one of the most important biometric technologies. The performance of the minutiae extraction and the speed of the fingerprint verification system rely heavily on the quality of the input fingerprint images, so the enhancement of the low fingerprint is a critical and difficult step in a fingerprint verification system. In this paper we proposed an effective algorithm for fingerprint enhancement. Firstly we use normalization algorithm to reduce the variations in gray level values along ridges and valleys. Then we utilize the structure tensor approach to estimate each pixel of the fingerprint orientations. At last we propose a novel algorithm which combines the advantages of onedimensional Gabor filtering method and anisotropic method to enhance the fingerprint in recoverable region. The proposed algorithm has been evaluated on the database of Fingerprint Verification Competition 2004, and the results show that our algorithm performs within less time.
Numerical analysis of anisotropic diffusion effect on ICF hydrodynamic instabilities
Directory of Open Access Journals (Sweden)
Olazabal-Loumé M.
2013-11-01
Full Text Available The effect of anisotropic diffusion on hydrodynamic instabilities in the context of Inertial Confinement Fusion (ICF flows is numerically assessed. This anisotropy occurs in indirect-drive when laminated ablators are used to modify the lateral transport [1,2]. In direct-drive, non-local transport mechanisms and magnetic fields may modify the lateral conduction [3]. In this work, numerical simulations obtained with the code PERLE [4], dedicated to linear stability analysis, are compared with previous theoretical results [5]. In these approaches, the diffusion anisotropy can be controlled by a characteristic coefficient which enables a comprehensive study. This work provides new results on the ablative Rayleigh-Taylor (RT, ablative Richtmyer-Meshkov (RM and Darrieus-Landau (DL instabilities.
Directory of Open Access Journals (Sweden)
Vladimir Sokolovskiy
2014-09-01
Full Text Available The complex magnetic and structural properties of Co-doped Ni-Mn-Ga Heusler alloys have been investigated by using a combination of first-principles calculations and classical Monte Carlo simulations. We have restricted the investigations to systems with 0, 5 and 9 at% Co. Ab initio calculations show the presence of the ferrimagnetic order of austenite and martensite depending on the composition, where the excess Mn atoms on Ga sites show reversed spin configurations. Stable ferrimagnetic martensite is found for systems with 0 (5 at% Co and a c=a ratio of 1.31 (1.28, respectively, leading to a strong competition of ferro- and antiferro-magnetic exchange interactions between nearest neighbor Mn atoms. The Monte Carlo simulations with ab initio exchange coupling constants as input parameters allow one to discuss the behavior at finite temperatures and to determine magnetic transition temperatures. The Curie temperature of austenite is found to increase with Co, while the Curie temperature of martensite decreases with increasing Co content. This behavior can be attributed to the stronger Co-Mn, Mn-Mn and Mn-Ni exchange coupling constants in austenite compared to the corresponding ones in martensite. The crossover from a direct to inverse magnetocaloric effect in Ni-Mn-Ga due to the substitution of Ni by Co leads to the appearance of a “paramagnetic gap” in the martensitic phase. Doping with In increases the magnetic jump at the martensitic transition temperature. The simulated magnetic and magnetocaloric properties of Co- and In-doped Ni-Mn-Ga alloys are in good qualitative agreement with the available experimental data.
Indian Academy of Sciences (India)
M’NASSRI R
2016-04-01
The magnetocaloric effect (MCE) and the field dependence of the magnetic entropy changes in the perovskite-type a$_{0.67}$Ca$_{0.33}$Mn$_{0.9}$Fe$_{0.1}$O$_3$ were studied using the phenomenological model. The model parameters were determined from the magnetization data adjustment and used to give better fits to magnetic transition and to calculate the magnetocaloric properties. The entropy curves have been observed to behave a symmetrical broadning of $\\Delta$S$_M$ peak with the increase in magnetic field. The values of maximum magnetic entropy change, full-width at half-maximum, relative cooling power (RCP) and the refrigerant capacity (RC), at several magnetic field variations, were calculated. The maximum magnetic entropy change of 1.17 J kg$^{−1}$K$^{−1}$ was obtained for 3 T. The theoretical calculations were compared with the available experimental data. The results were found to be in good accordance. The critical exponents associated with ferromagnetic transition have been determined from the MCE methods. By using the field dependence of $\\Delta S_{\\rm max} \\approx a (\\mu_0 H)^n$ and the ${\\rm RCP} \\approx v(\\mu_0H)^w$, the critical behaviour of La$_{0.67}$Ca$_{0.33}$Mn$_{0.9}$Fe$_{0.1}$O$_3$ was investigated. From the analysis of the relationship between the local exponent$n$ and $w$, other exponents $\\beta$, $\\gamma$ and $\\delta$ were calculated. Our results indicated that the ferromagnetic coupling in the La$_{0.67}$Ca$_{0.33}$Mn$_{0.9}$Fe$_{0.1}$O$_3$ can be well described by the 3D Heisenberg model. This reflects an existence of ferromagnetic short-range order in the sample.
Institute of Scientific and Technical Information of China (English)
肖素芬; 陈云贵; 管登高; 杨涛; 涂铭旌
2003-01-01
The relationship between isothermal magnetic entropy change ΔS and adiabatic temperature change ΔTad was deduced according to the principles of thermodynamics. The MCE and the engineering application were discussed for Gd and several new kinds of magnetic refrigerating materials near room temperature, Gd5Si2Ge2, MnFeP0.45As0.55 and LaFe11.2Co0.7Si 1.1. Isothermal entropy change is proportional to adiabatic temperature change with a factor of T/C (T is temperature, C is heat capacity). When the comparison of magnetacoloric effect is made for two different mate rials, we should consider isothermal entropy change as well as adiabatic tempera ture change.
Emre, Baris; Bruno, Nickolaus M.; Yuce Emre, Suheyla; Karaman, Ibrahim
2014-12-01
The effect of Nb substitution for Ni in Ni45Co5Mn40Sn10 magnetic shape memory alloys on their magnetic properties, martensitic transformation characteristics, transformation hysteresis, and magnetocaloric properties was studied using wavelength-dispersive X-ray spectroscopy, differential scanning calorimetry, and the temperature and field dependence of the magnetization. Ni45Co5Mn40Sn10 alloy has a very low transformation hysteresis; however, the martensitic transformation temperatures are notably above room temperature, which is not desirable for magnetic refrigeration applications. In this study, small quantities of Nb substitution were shown to drastically shift the transformation temperatures to lower temperatures, at a rate of 68 K/at. % Nb, which is needed for household refrigeration. The austenite Curie temperature also decreased with increasing Nb content. However, a decrease in the latent heat of the martensitic transition was observed, which negatively affects the magnetic field-induced adiabatic temperature change capability. Still, the relatively large transformation entropy and the low transformation hysteresis make the Nb-doped Ni45Co5Mn40Sn10 alloys potential candidates for solid state refrigeration near room temperature.
Energy Technology Data Exchange (ETDEWEB)
Emre, Baris [Department of Engineering Physics, Ankara University, 06100 Ankara (Turkey); Bruno, Nickolaus M. [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Yuce Emre, Suheyla [Department of Physics, Ondokuz Mayis University, 55139 Samsun (Turkey); Karaman, Ibrahim, E-mail: ikaraman@tamu.edu [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States)
2014-12-08
The effect of Nb substitution for Ni in Ni{sub 45}Co{sub 5}Mn{sub 40}Sn{sub 10} magnetic shape memory alloys on their magnetic properties, martensitic transformation characteristics, transformation hysteresis, and magnetocaloric properties was studied using wavelength-dispersive X-ray spectroscopy, differential scanning calorimetry, and the temperature and field dependence of the magnetization. Ni{sub 45}Co{sub 5}Mn{sub 40}Sn{sub 10} alloy has a very low transformation hysteresis; however, the martensitic transformation temperatures are notably above room temperature, which is not desirable for magnetic refrigeration applications. In this study, small quantities of Nb substitution were shown to drastically shift the transformation temperatures to lower temperatures, at a rate of 68 K/at. % Nb, which is needed for household refrigeration. The austenite Curie temperature also decreased with increasing Nb content. However, a decrease in the latent heat of the martensitic transition was observed, which negatively affects the magnetic field-induced adiabatic temperature change capability. Still, the relatively large transformation entropy and the low transformation hysteresis make the Nb-doped Ni{sub 45}Co{sub 5}Mn{sub 40}Sn{sub 10} alloys potential candidates for solid state refrigeration near room temperature.
DEFF Research Database (Denmark)
Lei, Tian; Engelbrecht, Kurt; Nielsen, Kaspar Kirstein;
2016-01-01
magnetocaloric refrigerators (MCR) demonstrated the great potential for these materials, but a thorough study on the impact of the moderate adiabatic temperature change and strong temperature dependence of the magnetocaloric effect (MCE) is lacking. Besides, comparing active magnetic regenerators (AMR) using...... MCE are quantified and analyzed by using artificially built magnetocaloric properties. Then, based on measured magnetocaloric properties of La(Fe,Mn,Si)13H y and Gd, an investigation on how to layer typical FOPT and SOPT materials with different temperature spans is carried out. Moreover, the...
Magnetocaloric effect in Gd6Co1.67Si3 compound with a second-order phase transition
Institute of Scientific and Technical Information of China (English)
Shen Jun; Li Yang-Xian; Dong Qiao-Yan; Wang Fang; Sun Ji-Rong
2008-01-01
The magnetic properties and the magnetic entropy change ΔS have been investigated for Gd6Co1.67Si3 compounds with a second-order phase transition. The saturation moment at 5 K and the Curie temperature TC are 38.1μB and 298 K, respectively. The AS originates from a reversible second-order magnetic transition around TC and its value reaches 5.2J/kg.K for a magnetic field change from 0 to 5T. The refrigerant capacity (RC) of Gd6Co1.67Si3 are calculated by using the methods given in Refs.[12] and [21], respectively, for a field change of 0-5 T and its values are 310 and 440 J/kg, which is larger than those of some magnetocaloric materials with a first-order phase transition.
Strain dependent magnetocaloric effect in La0.67Sr0.33MnO3 thin-films
Kumar, V. Suresh; Chukka, Rami; Chen, Zuhuang; Yang, Ping; Chen, Lang
2013-05-01
The strain dependent magnetocaloric properties of La0.67Sr0.33MnO3 thin films deposited on three different substrates (001) LaAlO3 (LAO), (001) SrTiO3 (STO), and (001) La0.3Sr0.7Al0.65Ta0.35O9 (LSAT) have been investigated under low magnetic fields and around magnetic phase transition temperatures. Compared to bulk samples, we observe a remarkable decrease in the ferromagnetic transition temperature that is close to room temperature, closely matched isothermal magnetic entropy change and relative cooling power values in tensile strained La0.67Sr0.33MnO3 films. The epitaxial strain plays a significant role in tuning the peak position of isothermal magnetic entropy change towards room temperature with improved cooling capacity.
Strain dependent magnetocaloric effect in La0.67Sr0.33MnO3 thin-films
Directory of Open Access Journals (Sweden)
V. Suresh Kumar
2013-05-01
Full Text Available The strain dependent magnetocaloric properties of La0.67Sr0.33MnO3 thin films deposited on three different substrates (001 LaAlO3 (LAO, (001 SrTiO3 (STO, and (001 La0.3Sr0.7Al0.65Ta0.35O9 (LSAT have been investigated under low magnetic fields and around magnetic phase transition temperatures. Compared to bulk samples, we observe a remarkable decrease in the ferromagnetic transition temperature that is close to room temperature, closely matched isothermal magnetic entropy change and relative cooling power values in tensile strained La0.67Sr0.33MnO3 films. The epitaxial strain plays a significant role in tuning the peak position of isothermal magnetic entropy change towards room temperature with improved cooling capacity.
Aeroelastic modal dynamics of wind turbines including anisotropic effects
Skjoldan, Peter Fisker; Hansen, Morten Hartvig; Rubak, Rune; Thomsen, Kenneth
2011-01-01
Several methods for aeroelastic modal analysis of a rotating wind turbine are developed and used to analyse the modal dynamics of two simplified models and a complex model in isotropic and anisotropic conditions. The Coleman transformation is used to enable extraction of the modal frequencies, damping, and periodic mode shapes of a rotating wind turbine by describing the rotor degrees of freedom in the inertial frame. This approach is valid only for an isotropic system. Anisotropic systems, e...
Effective Dirac Hamiltonian for anisotropic honeycomb lattices: Optical properties
Oliva-Leyva, M.; Naumis, Gerardo G.
2016-01-01
We derive the low-energy Hamiltonian for a honeycomb lattice with anisotropy in the hopping parameters. Taking the reported Dirac Hamiltonian for the anisotropic honeycomb lattice, we obtain its optical conductivity tensor and its transmittance for normal incidence of linearly polarized light. Also, we characterize its dichroic character due to the anisotropic optical absorption. As an application of our general findings, which reproduce the previous case of uniformly strained graphene, we study the optical properties of graphene under a nonmechanical distortion.
Constraints on the Adiabatic Temperature Change in Magnetocaloric Materials
DEFF Research Database (Denmark)
Nielsen, Kaspar Kirstein; Bahl, Christian Robert Haffenden; Smith, Anders
2010-01-01
The thermodynamics of the magnetocaloric effect implies constraints on the allowed variation in the adiabatic temperature change for a magnetocaloric material. An inequality for the derivative of the adiabatic temperature change with respect to temperature is derived for both first- and second......-order materials. For materials with a continuous adiabatic temperature change as a function of temperature, this inequality is shown to hold for all temperatures. However, discontinuous materials may violate the inequality. We compare our results with measured results in the literature and discuss...
Anisotropic Effects on Constitutive Model Parameters of Aluminum Alloys
Brar, Nachhatter; Joshi, Vasant
2011-06-01
Simulation of low velocity impact on structures or high velocity penetration in armor materials heavily rely on constitutive material models. The model constants are required input to computer codes (LS-DYNA, DYNA3D or SPH) to accurately simulate fragment impact on structural components made of high strength 7075-T651 aluminum alloys. Johnson-Cook model constants determined for Al7075-T651 alloy bar material failed to simulate correctly the penetration into 1' thick Al-7075-T651plates. When simulations go well beyond minor parameter tweaking and experimental results are drastically different it is important to determine constitutive parameters from the actual material used in impact/penetration experiments. To investigate anisotropic effects on the yield/flow stress of this alloy we performed quasi-static and high strain rate tensile tests on specimens fabricated in the longitudinal, transverse, and thickness directions of 1' thick Al7075-T651 plate. Flow stresses at a strain rate of ~1100/s in the longitudinal and transverse direction are similar around 670MPa and decreases to 620 MPa in the thickness direction. These data are lower than the flow stress of 760 MPa measured in Al7075-T651 bar stock.
Tlili, R.; Hammouda, R.; Bejar, M.; Dhahri, E.
2015-07-01
Based on a phenomenological model, the magnetic and magnetocaloric properties of La0.7(Ba, Sr)0.3Mn0.9Ga0.1O3 oxide have been studied. Indeed, the magnetic measurements have demonstrated that the sample exhibits a ferromagnetic-paramagnetic transition at room temperature. The value of the magnetocaloric effect such as magnetic entropy change, full width at half-maximum, relative cooling power and magnetic specific heat change has been determined from the calculation of magnetization as a function of temperature under different external magnetic fields. The maximum magnetic entropy change (- ΔSMmax) and the relative cooling power (RCP) are, respectively, 0.57 J kg-1 K-1 and 28.68 J kg-1 for a 10 kOe field change at 300 K, which are the characteristics of a good magnetocaloric material. Hence, the La0.7(Ba, Sr)0.3Mn0.9Ga0.1O3 compound can be considered as a promising material in magnetic refrigeration technology. According to the master curve behavior for the temperature dependence of ΔSM predicted for different maximum fields, this work has confirmed that the paramagnetic-ferromagnetic phase transition observed for our sample is of a second order.
Wang, Hui
2014-05-01
This thesis addresses the efficiency improvement of seismic wave modeling and migration in anisotropic media. This improvement becomes crucial in practice as the process of imaging complex geological structures of the Earth\\'s subsurface requires modeling and migration as building blocks. The challenge comes from two aspects. First, the underlying governing equations for seismic wave propagation in anisotropic media are far more complicated than that in isotropic media which demand higher computational costs to solve. Second, the usage of whole prestack seismic data still remains a burden considering its storage volume and the existing wave equation solvers. In this thesis, I develop two approaches to tackle the challenges. In the first part, I adopt the concept of prestack exploding reflector model to handle the whole prestack data and bridge the data space directly to image space in a single kernel. I formulate the extrapolation operator in a two-way fashion to remove he restriction on directions that waves propagate. I also develop a generic method for phase velocity evaluation within anisotropic media used in this extrapolation kernel. The proposed method provides a tool for generating prestack images without wavefield cross correlations. In the second part of this thesis, I approximate the anisotropic models using effective isotropic models. The wave phenomena in these effective models match that in anisotropic models both kinematically and dynamically. I obtain the effective models through equating eikonal equations and transport equations of anisotropic and isotropic models, thereby in the high frequency asymptotic approximation sense. The wavefields extrapolation costs are thus reduced using isotropic wave equation solvers while the anisotropic effects are maintained through this approach. I benchmark the two proposed methods using synthetic datasets. Tests on anisotropic Marmousi model and anisotropic BP2007 model demonstrate the applicability of my
Magnetocaloric Pumping of Liquid Oxygen
Immer, Christopher; Kandula, Max; Lane, John; Youngquist, Robert
2004-01-01
The field-induced force density on a magnetic fluid is proportional to the magnetic susceptibility times the gradient of the magnetic field squared. The direction of the force is towards increasing magnetic field (positive gradient). Applying a magnetic field to a magnetic fluid will result in a force from all directions towards the location of peak field. Since the magnetic field is conservative and there are no magnetic monopoles, the net field-induced force on any fluid of constant susceptibly will be zero. The only manner to obtain a nonzero net field-induced force is to vary the susceptibility of the fluid. At the gas/liquid interface of liquid oxygen, the susceptibility varies drastically, and the exploitation of the resultant large net forces. An alternative method of varying the magnetic susceptibility is to vary the temperature of the fluid. The magnetic susceptibility of paramagnetic liquid oxygen obeys the Curie-Weiss law: it is inversely proportional to temperature. By applying a temperature gradient in the presence of a symmetric magnetic field, a nonzero net force results. Much of the theory of the so-called Magnetocaloric Effect has previously been developed for and applied to ferromagnetic fluids, or ferrofluids, but is readily applied to paramagnetic liquid oxygen.
DEFF Research Database (Denmark)
Han, Li; Hegelund Spangsdorf, Steeven; Van Nong, Ngo;
2016-01-01
-rate) using spark plasma sintering (SPS). The effects of SPS conditions on the anisotropic thermoelectric properties and microstructure evolutions were systematically investigated. The change of sintering temperature showed stronger influence than other sintering parameters to the resulting thermoelectric...
Thermal diffusivity and anisotropic effects in transparent polymers using colinear mirage detection
Pandey, G.; Boué, C.; D. Fournier; Boccara, A.
1994-01-01
Colinear mirage detection was found to be simple and efficient to solve the problem of thermal diffusivity measurements in transparent polymer foils. Both reliable values have been obtained and anisotropic effects revealed.
Simulated magnetocaloric properties of MnCr2O4 spinel
Mahmoud A. Hamad
2016-01-01
The magnetocaloric properties of MnCr2O4 spinel have been simulated based on a phenomenological model. The simulation of magnetization as function of temperature is used to explore magnetocaloric properties such as magnetic entropy change, heat capacity change, and relative cooling power. The results imply the prospective application of MnCr2O4 spinel to achieve magnetocaloric effect at cryogenic temperatures (20–60 K) near Curie temperatures (38–44 K). According to the obtained results it is...
Magnetocaloric effect and H gradient in bulk La(Fe,Si)13Hy magnetic refrigerants obtained by HDSH
DEFF Research Database (Denmark)
Neves Bez, Henrique; Eggert, Bruno G.F.; Lozano, Jaime;
2015-01-01
Results are reported on the preparation of bulk parts of La(Fe,Si)13Hy via the Hydrogen-Decrepitation-Sintering-Hydrogenation (HDSH) process. Net shape parts for application in room-temperature magnetic refrigeration have been produced in only 8 h of heat treatment which is considerably faster than...... parameters play an important role for the stability of the desired La(Fe,Si)13 phase during the process. Hydrogen desorption was seen to occur at two temperature ranges as a result of internal gradients. Dissimilar amounts of α-Fe were precipitated for different hydrogenation times. As a result, parts...... produced via HDSH with 2 and 4 h of hydrogenation exhibited different magnetocaloric behaviours. For a hydrogenation step of 4 h, parts with a demagnetization factor of 0.49 showed an adiabatic temperature change (ΔTadΔTad) higher than 1 K for a temperature range of 40 K with a maximum value of 1.57 K for...
Madiligama, A. S. B.; Ari-Gur, P.; Shavrov, V. G.; Koledov, V. V.; Calder, S.; Mashirov, A. V.; Kamantsev, A. P.; Dilmieva, E. T.; Gonzalez-Legarreta, L.; Grande, B. H.; Vega, V. V.; Kayani, A.
2016-08-01
Magnetic cooling is a green cooling technology, which is more energy efficient than existing fluid-compression cooling machines. Ni41Mn39In12Co8 alloy, which demonstrates promising magnetocaloric performances, was investigated using neutron diffraction and thermomagnetic measurements. The austenite structure is cubic L21 (Fm\\bar{3}m), while that of the martensite is a mix of 8 and 6 M modulated monoclinic structures (P\\quad 1\\quad 2/m\\quad 1). The austenitic site occupancy refinements reveal that all substituting Co atoms occupy Ni-sites. Most Mn atoms (65%) are in the Mn-sites and the rest go to In-sites (about 35%) and Ni-sites (less than 5%). This disorder of the magnetic atoms (Mn, Ni and Co) in the austenitic phase remains unchanged during the martensitic transition. The distortions of the interatomic distances due to the modulation of the martensitic structures further enhance the disorder in the magnetic interactions. Thermomagnetic measurements indicate that the austenitic phase is ferromagnetic. Cooling to below 250 K, where the alloy loses its ferromagnetic nature, and down to 50 K, the lack of any antiferromagnetic Bragg peaks suggests no antiferromagnetic ordering in the martensitic phase. At very low temperatures in the martensitic phase, spin glass magnetic nature is identified by magnetic measurements, and the spin-glass transition temperature is ∼19 K.
Lee, Hyung Jin; Lee, Heung Son; Ma, Pyung Sik; Kim, Yoon Young
2016-09-01
In this paper, the scattering (S-) parameter retrieval method is presented specifically for anisotropic elastic metamaterials; so far, no retrieval has been accomplished when elastic metamaterials exhibit fully anisotropic behavior. Complex constitutive property and intrinsic scattering behavior of elastic metamaterials make their characterization far more complicated than that for acoustic and electromagnetic metamaterials. In particular, elastic metamaterials generally exhibit anisotropic scattering behavior due to higher scattering modes associated with shear deformation. They also exhibit nonlocal responses to some degrees, which originate from strong multiple scattering interactions even in the long wavelength limit. Accordingly, the conventional S-parameter retrieval methods cannot be directly used for elastic metamaterials, because they determine only the diagonal components in effective tensor property. Also, the conventional methods simply use the analytic inversion formulae for the material characterization so that inherent nonlocality cannot be taken into account. To establish a retrieval method applicable to anisotropic elastic metamaterials, we propose an alternative S-parameter method to deal with full anisotropy of elastic metamaterials. To retrieve the whole effective anisotropic parameter, we utilize not only normal but also oblique wave incidences. For the retrieval, we first retrieve the ratio of the effective stiffness tensor to effective density and then determine the effective density. The proposed retrieval method is validated by characterizing the effective material parameters of various types of non-resonant anisotropic metamaterials. It is found that the whole effective parameters are retrieved consistently regardless of used retrieval conditions in spite of inherent nonlocality.
Effect of anisotropic plasticity on mixed mode interface crack growth
DEFF Research Database (Denmark)
Tvergaard, Viggo; Legarth, Brian Nyvang
2007-01-01
different anisotropic yield criteria to account for the plastic anisotropy. Conditions of small-scale yielding are assumed, and due to the mismatch of elastic properties across the interface the corresponding oscillating stress singularity field is applied as boundary conditions on the outer edge...
Table-like magnetocaloric effect of Fe{sub 88−x}Nd{sub x}Cr{sub 8}B{sub 4} composite materials
Energy Technology Data Exchange (ETDEWEB)
Lai, J.W.; Zheng, Z.G.; Zhong, X.C. [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Franco, V. [Departamento Física de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, P.O. Box 1065, 41080 Sevilla (Spain); Montemayor, R.; Liu, Z.W. [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Zeng, D.C., E-mail: medczeng@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China)
2015-09-15
The narrow working temperature range due to the sharp magnetic entropy change |ΔS{sub M}| peak and large thermal or magnetic hysteresis restricts the practical application of magnetocaloric materials. In this work, the table-like magnetocaloric effect (MCE) was obtained in the multilayer composite of Fe{sub 88−x}Nd{sub x}Cr{sub 8}B{sub 4} alloys with various Nd substitutions for Fe (x=5, 8, 10, 12, and 15), which were prepared by arc-melting followed by melt-spinning. The substation of Nd was found to enhance the glass-forming ability. For the alloys with Nd substitution from 5 at% to 15 at%, the Curie temperature (T{sub C}) ranged from 322 K to 350 K and the peak value of |ΔS{sub M}| remained almost constant, 3.4–3.5 J/(kg K) under an applied field of 0–5 T. The composite with various Nd contents was prepared by stocking the ribbons layer by layer. The |ΔS{sub M}| of the composite approached a nearly constant value of ∼3.2 J/(kg K) in a field change of 0–5 T in a wide temperature span over 40 K, resulting in large refrigerant capacity value of >408 J/kg. This |ΔS{sub M}| value was much larger than the previous reported Fe-based amorphous composite Fe{sub 78−x}Ce{sub x}Si{sub 4}Nb{sub 5}B{sub 12}Cu{sub 1}. This composite can be used as the working material in the Ericsson-cycle magnetic regenerative refrigerator around room temperature. - Highlights: • The T{sub C} ranges from 322 K to 350 K when increasing Nd substitution from 5 to 15 at%. • |ΔS{sub M}| remains relatively constant, about 3.4–3.5 J/(kg K) under H=0–5 T. • RC decreases from 93 to 78 J/kg in a field change of 1.5 T when Nd increasing. • Table-like MCE ,|ΔS{sub M}| ~3.2J/kg K under 0–5 T, appeared in the composite. • A wide working temperature range (40 K) and enhanced RC (>408J/kg) were obtained in the composite.
Magnetic properties and magnetocaloric effect in NdxLa1-xFe11.5Al1.5 compounds
Institute of Scientific and Technical Information of China (English)
Wang Fang; Wang Guang-Jun; Sun Ji-Rong; Shen Bao-Gen
2008-01-01
Effects of Nd-doping on the magnetic properties and magnetocaloric effects (MCEs) of NdxLa1-xFe11.5Al1.5 have been investigated. Substitution of Nd leads to a weakening of the antiferromagnetic (AFM) coupling and an enhancement of the ferromagnetic (FM) coupling. This in turn results in a complex magnetic behaviour for Nd0.2La0.8Fe11.52Al1.5 characterized by the occurrence of two phase transitions at ～188 K (PM-AFM) and ～159 K (AFM-FM). As a result, a table-like MCE (9 J/kg·K) is found in a wide temperature range (160-185 K) for a field change of 0-5 T around the transition temperature, as evidenced by both the magnetic and calorimetric measurements. Based on the analysis of low-temperature heat capacity, it is found that the AFM-FM phase transition modifies the electron density significantly, and the major contribution to the entropy change comes from the electronic entropy change.
Das, Kalipada; Das, I.
2016-03-01
Magnetocaloric effect (MCE) is the change in temperature or entropy of a material due to the application of external magnetic field. The temperature dependence of MCE shows maximum value near the ferromagnetic transition of the material. Material with large MCE near room temperature will make revolutionary change in cooling technology and will have large impact in human society. We have transformed antiferromagnetic bulk manganite material La0.48Ca0.52MnO3 to ferromagnetic material by the reduction of the particle size in nanometer scale. MCE, as well as the Relative cooling power (RCP) of the material at room temperature (RT) systematically increase with the reduction of the particle sizes. The RCP value for the 45 nm particle size sample at RT is about 400% larger compared with the bulk counterpart. Our detail study on the nano form of the compound highlights an effective way to enhance the MCE. It opens up a vast possibility of achieving giant enhancement of MCE of several already known materials just by the reduction of the particle size in nanometer scale.
Theoretical investigations on magnetocaloric effect in Er{sub 1−y}Tb{sub y}Al{sub 2} series
Energy Technology Data Exchange (ETDEWEB)
Ribeiro, P.O., E-mail: paula.ribeiro@gmail.com [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil); Alho, B.P.; Alvarenga, T.S.T.; Nóbrega, E.P.; Sousa, V.S.R. de [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil); Carvalho, A. Magnus G. [Laboratório Nacional de Luz Síncrotron, CNPEM, 13083-970 Campinas, SP (Brazil); Caldas, A. [Sociedade Unificada de Ensino Superior e Cultura, SUESC, 20211-351 Rio de Janeiro, RJ (Brazil); Oliveira, N.A. de; Ranke, P.J. von [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil)
2015-04-01
We report on the magnetic and magnetocaloric effect calculations in rare earth Er{sub 1−y}Tb{sub y}Al{sub 2} compounds (y=0.00, 0.25, 0.5, 0.75 and 1.00). Our model Hamiltonian has contributions of the crystalline electrical field anisotropy in both Er and Tb magnetic sublattices, disorder in exchange interactions among Er–Er, Tb–Tb and Er–Tb magnetic ions and the Zeeman effect. The magnetization, the isothermal entropy change (ΔS{sub T}) and the adiabatic temperature change (ΔT{sub ad}) dependence on temperature were simulated and, compared with the experimental data available. - Highlights: • Modeling Er{sub (1−y)}Tb{sub y}Al{sub 2} intermetallic compounds. • Magnetic entropy changes in Er{sub (1−y)}Tb{sub y}Al{sub 2}. • Adiabatic temperature changes in Er{sub 0.75}Tb{sub 0.25}Al{sub 2} and Er{sub 0.65}Tb{sub 0.35}Al{sub 2} compounds.
Energy Technology Data Exchange (ETDEWEB)
Balli, M., E-mail: mohamed.balli@usherbrooke.ca; Jandl, S. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, Quebec J1K 2R1 (Canada); Fournier, P. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, Quebec J1K 2R1 (Canada); Canadian Institute for Advanced Research, Toronto, Ontario M5G 1Z8 (Canada); Gospodinov, M. M. [Institute of Solid State Physics, Bulgarian Academy of Science, Sofia 1184 (Bulgaria)
2014-05-07
Magnetic and magnetocaloric properties of single crystal double perovskite La{sub 2}MnNiO{sub 6} have been investigated in details. Its ordered phase with a high Curie temperature (T{sub C} = 280 K) exhibits a significant refrigerant capacity around room temperature. A model based on the mean field theory approximation has been used in order to quantify the magnetic and magnetocaloric properties in the ordered La{sub 2}MnNiO{sub 6}. The magnetization and entropy changes were satisfactorily simulated as a function of temperature and magnetic field. On the other hand, the presence of cationic disorder in La{sub 2}MnNiO{sub 6} phases allows to shift the Curie point to low temperature without a significant change in the magnetocaloric performance.
Ishikawa, K; Maeda, N.
2001-01-01
Physical properties of anisotropic compressible quantum Hall states and their implications to integer quantum Hall effect are studied based on a mean field theory on the von Neumann lattice. It is found that the Hall gas has unusual thermodynamic properties such as negative pressure and negative compressibility and unusual transport properties. Transport properties and density profile of Hall gas states at half fillings agree with those of anisotropic states discovered experimentally in highe...
International Nuclear Information System (INIS)
This paper considers the effect of the anisotropic surface tension on the morphological stability of the planar interface during directional solidification. When the expression exhibiting the four-fold symmetry is included, the modified absolute stability criterion is obtained by employing the multi-variable expansion method. The linear stability analysis reveals that for the given temperature gradient, as the anisotropic surface tension parameter increases, the stability zone tends to decrease. (cross-disciplinary physics and related areas of science and technology)
Effects of Staggered Magnetic Field on Entanglement in the Anisotropic XY Model
Institute of Scientific and Technical Information of China (English)
SUN Zhe; WANG Xiao-Guang
2006-01-01
We investigate effects of staggered magnetic field on thermal entanglement in the anisotropic XY model.The analytic results of entanglement for the two-site cases are obtained. For the general case of even sites, we show that when the anisotropic parameter is zero, the entanglement in the XY model with a staggered magnetic field is the same as that with a uniform magnetic field.
Penetration Effect for Tangential Direction of the Anisotropy Axis in Anisotropic Medium
Directory of Open Access Journals (Sweden)
K.A. Vytovtov
2012-07-01
Full Text Available Anisotropic plane-parallel structure (both homogeneous and stratified with the direction of the anisotropy axis along the interfaces under tangential propagation of the incident wave is considered. The possibility of wave transmission through a plate (the penetration effect was analytically shown for the given particular case. Expressions for the wave-vector in anisotropic medium, field components, Poynting vector components were written and analyzed. It is shown that the structure has nonreciprocal properties.
Energy Technology Data Exchange (ETDEWEB)
Zhang, Jiliang [Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong (Hong Kong); Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716 (United States); Zheng, Zhigang [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Shan, Guangcun, E-mail: gshan2-c@my.cityu.edu.hk, E-mail: bobev@udel.edu, E-mail: apchshek@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong (Hong Kong); School of Instrumentation Science and Optoelectronics Engineering, Beihang University, Beijing 100191 (China); Bobev, Svilen, E-mail: gshan2-c@my.cityu.edu.hk, E-mail: bobev@udel.edu, E-mail: apchshek@cityu.edu.hk [Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716 (United States); Shek, Chan Hung, E-mail: gshan2-c@my.cityu.edu.hk, E-mail: bobev@udel.edu, E-mail: apchshek@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong (Hong Kong)
2015-10-07
The structure of known Gd{sub 4}Co{sub 3} compound is re-determined as Gd{sub 6}Co{sub 4.85}, adopting the Gd{sub 6}Co{sub 1.67}Si{sub 3} structure type, which is characterized by two disorder Co sites filling the Gd octahedral and a short Gd-Gd distance within the octahedra. The compound shows uniaxial negative thermal expansion in paramagnetic state, significant negative expansion in ferromagnetic state, and positive expansion below ca. 140 K. It also exhibits large magnetocaloric effect, with an entropy change of −6.4 J kg{sup −1} K{sup −1} at 50 kOe. In the lattice of the compound, Co atoms at different sites show different spin states. It was confirmed by the X-ray photoelectron spectra and calculation of electronic structure and shed lights on the abnormal thermal expansion. The stability of such compound and the origin of its magnetism are also discussed based on measured and calculated electronic structures.
Mao, Qianhui; Yang, Jinhu; Wang, Hangdong; Khan, Rajwali; Du, Jianhua; Zhou, Yuxing; Xu, Binjie; Chen, Qin; Fang, Minghu
2016-01-01
Magnetic refrigeration based on the magnetocaloric effect (MCE) is an environment-friendly, high-efficiency technology. It has been believed that a large MCE can be realized in the materials with a first-order magnetic transition (FOMT). Here, we found that TlFe3Te3 is a ferromagnetic metal with a first-order magnetic transition occurring at Curie temperature TC = 220 K. The maximum values of magnetic entropy change (Δ) along the crystallographic c-axis, estimated from the magnetization data, reach to 5.9 J kg−1K−1 and 7.0 J kg−1 K−1 for the magnetic field changes, ΔH = 0–1 T and 0–2 T, respectively, which is significantly larger than that of MCE materials with a second-order magnetic transition (SOMT). Besides the large ΔSM, the low-level both thermal and field hysteresis make TlFe3Te3 compound an attractive candidate for magnetic refrigeration. Our findings should inspire the exploration of high performance new MCE materials. PMID:27681203
Long, Y.; Zhang, Z. Y.; Wen, D.; Wu, G. H.; Ye, R. C.; Chang, Y. Q.; Wan, F. R.
2005-08-01
The Ni2MnGa-based Heusler alloys with high magnetocaloric effect have attracted considerable attention as a promising magnetic refrigerant. The phase-transition processes and magnetic entropy changes in the NiMnGa alloys with the concurrence of magnetic and structural phase transitions were studied. The ac magnetic susceptibility results showed the magnetic transition occurred during the reverse martensitic phase transition in the Ni55.5Mn20Ga24.5 alloy and the direct transition from the ferromagnetic matrensitic phase to the paramagnetic austenitic phase occurred in the Ni54.9Mn20.5Ga24.6 alloy. When the magnetic field had changed to 2 T, a comparable large magnetic entropy change was observed in both the Ni55.5Mn20Ga24.5 and Ni54.9Mn20.5Ga24.6 alloys, which is speculated as the result of the discontinuous change of magnetization near the phase transition.
Room temperature magnetocaloric effect and refrigerant capacitance in La0.7Sr0.3MnO3 nanotube arrays
Kumaresavanji, M.; Sousa, C. T.; Pires, A.; Pereira, A. M.; Lopes, A. M. L.; Araujo, J. P.
2014-08-01
High aspect ratio La0.7Sr0.3MnO3 nanotube (NT) arrays have been synthesized using nitrates based sol-gel precursor by nanoporous anodized aluminum oxide template assisted method. Their phase purity and microstructures were analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. Magnetocaloric effect (MCE) of as prepared NTs was investigated by means of field dependence magnetization measurements. Significant magnetic entropy change, -△SM = 1.6 J/kg K, and the refrigerant capacitance, RC = 69 J/kg, were achieved near the transition temperature at 315 K for 5 T. For comparison, a bulk sample was also prepared using the same precursor solution which gives a value of -△SM = 4.2 J/kg K and a RC = 165 J/kg. Though the bulk sample exhibits higher △SM value, the NTs present an expanded temperature dependence of -△SM curves that spread over a broad temperature range and assured to be appropriate for active magnetic refrigeration. The diminutive MCE observed in manganite NTs is explained by the increased influence of surface sites of nanograins which affect the structural phase transition occurred by external magnetic field due to the coupling between magnetism and the lattice in manganese perovskites. Our report paves the way for further investigation in 1D manganite nanostructured materials towards applications in such magnetic refrigeration technology or even on hyperthermia/drug delivery.
Li, Zhe; Xu, Kun; Zhang, Yuanlei; Tao, Chang; Zheng, Dong; Jing, Chao
2015-01-01
In the present work, two successive magneto-structural transformations (MSTs) consisting of martensitic and intermartensitic transitions have been observed in polycrystalline Ni55.8Mn18.1Ga26.1 Heusler alloy. Benefiting from the additional latent heat contributed from intermediate phase, this alloy exhibits a large transition entropy change ΔStr with the value of ~27 J/kg K. Moreover, the magnetocaloric effect (MCE) has been also evaluated in terms of Maxwell relation. For a magnetic field change of 30 kOe, it was found that the calculated value of refrigeration capacity in Ni55.8Mn18.1Ga26.1 attains to ~72 J/kg around room temperature, which significantly surpasses those obtained for many Ni-Mn based Heusler alloys in the same condition. Such an enhanced MCE can be ascribed to the fact that the isothermal entropy change ΔST is spread over a relatively wide temperature interval owing to existence of two successive MSTs for studied sample. PMID:26450663
Energy Technology Data Exchange (ETDEWEB)
Agurgo Balfour, E.; Ma, Z.; Fu, H., E-mail: fuhao@uestc.edu.cn, E-mail: rockingsandstorm@163.com; Wang, L.; Luo, Y. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Hadimani, R. L.; Jiles, D. C. [Department of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011 (United States); Ames Laboratory, U.S. Department of Energy, Ames, Iowa 50011 (United States); Wang, S. F., E-mail: fuhao@uestc.edu.cn, E-mail: rockingsandstorm@163.com [North Electronic Device Research Institute, Beijing 100141 (China)
2015-09-28
In order to obtain “table-like” magnetocaloric effect (MCE), multiple-phase Gd{sub 56}Ni{sub 15}Al{sub 27}Zr{sub 2} alloy was prepared by arc-melting followed by suck-casting method. Powder x-ray diffraction and calorimetric measurements reveal that the sample contains both glassy and crystalline phases. The fraction of the glassy phase is about 62%, estimated from the heat enthalpy of the crystallization. The crystalline phases, Gd{sub 2}Al and GdNiAl further broadened the relatively wider magnetic entropy change (−ΔS{sub M}) peak of the amorphous phase, which resulted in the table-like MCE over a maximum temperature range of 52.5 K to 77.5 K. The plateau feature of the MCE was found to be nearly independent of the applied magnetic field from 3 T to 5 T. The maximum −ΔS{sub M} value of the MCE platforms is 6.0 J/kg K under applied magnetic field change of 5 T. Below 3 T, the field independence of the table-like feature disappears. The relatively large constant values of −ΔS{sub M} for the respective applied magnetic fields have promising applications in magnetic refrigeration using regenerative Ericsson cycle.
The existence of giant magnetocaloric effect and laminar structure in Fe73.5-x Cr x Si13.5B9Nb3Cu1
International Nuclear Information System (INIS)
Amorphous soft magnetic ribbons Fe73.5-x Cr x Si13.5B9Nb3Cu1 (x=1-5) have been fabricated by rapid quenching on a single copper wheel. The differential scanning calorimetry (DSC) patterns showed that the crystallization temperature of α-Fe(Si) phase is ranging from 542 to 569 deg. C, a little higher than that of pure Finemet (x=0). With the same annealing regime, the crystallization volume fraction as well as the particle size of α-Fe(Si) crystallites decreased with increasing Cr amount substituted for Fe in studied samples. Especially, the interesting fact is that the laminar structure of heat-treated ribbons on the surface contacted to copper wheel in the fabricating process has been firstly discovered and explained to be related to the existence of Cr in studied samples. The hysteresis loop measurement indicated that there is the pinning of displacement of domain walls. The giant magnetocaloric effect (GMCE) has been found in amorphous state of the samples. After annealing, the soft magnetic properties of investigated nanocomposite materials are desirably improved
Study of magnetocaloric effect in LaFe11.5Si1.5 alloys prepared by different cooling methods
Indian Academy of Sciences (India)
Xiang Chen; Yungui Chen; Yongbo Tang
2014-06-01
LaFe11.5Si1.5 alloys are annealed at 1503 K for 5 h and cooled down to room temperature by furnace cooling, air cooling and quenching in ice water, respectively. The main phases are 1:13 phases in those alloys. The impurity phases are -Fe and the amount of LaFeSi phase is so small that it is hard to observe in their XRD patterns. The powder X-ray diffraction patterns and SEM show that the three cooling methods have little influence on the phase relation and microstructure of those LaFe11.5Si1.5 alloys. But the lattice constant of LaFe11.5Si1.5 alloy prepared by quenching in ice water is lesser than those of the other two alloys, respectively. For studying the influence of different cooling processes on magnetic properties, the Curie temperature, thermal and magnetic hysteresis, magnetocaloric effect and relative cooling power are investigated. The result shows that the Curie temperature of LaFe11.5Si1.5 prepared by quenching in ice water is 197.6 K, about 4 K lesser than those of the other two LaFe11.5Si1.5 alloys. The maximum M (, ) of LaFe11.5Si1.5 prepared by furnace cooling and quenching in ice water is the most and the least under the field of 0–2 , respectively.
Magnetocaloric effects in Mn1.35Fe0.65P1-xSix compounds
Institute of Scientific and Technical Information of China (English)
Geng Yao-Xiang; Tegus O; Bi Li-Ge
2012-01-01
The structural and magnetocaloric properties of Mn1.35Fe0.s5P1-xSix compounds are investigated. The Sisubstituted compounds,Mn1.35Fe0.65P1-xSix with x =0.52,0.54,0.55,0.56,and 0.57,are prepared by high-energy ball milling and the solid-state reaction.The X-ray diffraction shows that the compounds crystallize into the Fe2P-type hexagonal structure with space group P(6)2m.The magnetic measurements show that the Curie temperature of the compound increases from 253 K for x =0.52 to 296 K for x =0.56.The isothermal magnetic-entropy change of the Mn1.35Fe0.65P1-xSix compound decreases with the Si content increasing.The maximal value of the magnetic-entropy change is about 7.0 J/kg·K in the Mn1.35Feo.65Po.48Sio.52 compound with a field change of 1.5 T.The compound quenched in water possesses a larger magnetic entropy change and a smaller thermal hysteresis than the non-quenched samples.The thermal hysteresis of the compound is less than 3.5 K.The maximum adiabatic temperature change is about 1.4 K in the Mn1.35Feo.65P0.45Si0.55 compound with a field change of 1.48 T.
DEFF Research Database (Denmark)
Engelbrecht, Kurt; Bahl, Christian Robert Haffenden; Nielsen, Kaspar Kirstein
2011-01-01
refrigeration device for near room temperature applications, and it is driven by the magnetocaloric effect in the regenerator material. Several magnetocaloric materials with potential magnetic refrigeration applications have recently been developed and characterized; however, few of them have been tested...... in an experimental device. This paper compares the performance of three magnetocaloric material candidates for AMRs, La(Fe,Co,Si)13, (La,Ca,Sr)MnO3 and Gd, in an experimental active magnetic regenerator with a parallel plate geometry. The performance of single-material regenerators of each magnetocaloric material...... family were compared. In an attempt to improve system performance, graded two-material regenerators were made from two different combinations of La(Fe,Co,Si)13 compounds having different magnetic transition temperatures. One combination of the La(Fe,Co,Si)13 materials yielded a higher performance, while...
Magnetocaloric phenomena in Mg-ferrite nanoparticles
Energy Technology Data Exchange (ETDEWEB)
Burianova, S; Holec, P; Plocek, J [Charles University, Faculty of Science, Department of Inorganic chemistry, Prague (Czech Republic); Poltierova-Vejpravova, J, E-mail: burianovasimona@email.c, E-mail: jana@mag.mff.cuni.c
2010-01-01
A comparative study of magnetocaloric effect (MCE) in superparamagnetic (SPM) regime is reported in two different types of magnesium ferrite nanostructures. The samples were prepared either by microemulsion method as MgFe{sub 2}O{sub 4} nanoparticles encapsulated in amorphous SiO{sub 2}, or as matrix-less nanoparticles using hydrothermal synthesis in supercritical water conditions. The particle diameter in all prepared samples was obtained from XRD measurements and TEM analysis. All samples show a SPM behavior above the blocking temperature, T{sub B}. The entropy change, {Delta}S was finally derived from the measurements of magnetization, M(H,T) curves at defined temperature intervals. We observed, that all samples show a broad peak of {Delta}S in the temperature range that is fairly above the T{sub B}. The values of the {Delta}S also depend on the particle size, and they are of about two orders lower than those reported in the famous giant magnetocaloric materials.
Directory of Open Access Journals (Sweden)
Deepak Elamalayil Soman
2015-01-01
Full Text Available Magnetocaloric effects of various materials are getting more and more interesting for the future, as they can significantly contribute towards improving the efficiency of many energy intensive applications such as refrigeration, heating, and air conditioning. Accurate characterization of magnetocaloric effects, exhibited by various materials, is an important process for further studies and development of the suitable magnetocaloric heating and cooling solutions. The conventional test facilities have plenty of limitations, as they focus only on the thermodynamic side and use magnetic machines with moving bed of magnetocaloric material or magnet. In this work an entirely new approach for characterization of the magnetocaloric materials is presented, with the main focus on a flexible and efficient power electronic based excitation and a completely static test platform. It can generate a periodically varying magnetic field using superposition of an ac and a dc magnetic field. The scale down prototype uses a customized single phase H-bridge inverter with essential protections and an electromagnet load as actuator. The preliminary simulation and experimental results show good agreement and support the usage of the power electronic test platform for characterizing magnetocaloric materials.
Magnetocaloric properties of rare-earth substituted DyCrO{sub 3}
Energy Technology Data Exchange (ETDEWEB)
McDannald, A. [Material Science and Engineering Department, University of Connecticut, Storrs, Connecticut 06269 (United States); Jain, M., E-mail: menka.jain@uconn.edu [Institute of Material Science, University of Connecticut, Storrs, Connecticut 06269 (United States); Department of Physics, University of Connecticut, Storrs, Connecticut 06269 (United States)
2015-07-28
Recently, there has been a focus on the need for efficient refrigeration technology without the use of expensive or harmful working fluids, especially at temperatures below 30 K. Solid state refrigeration, based on the magnetocaloric effect, provides a possible solution to this problem. The rare-earth chromites (RCrO{sub 3}), especially DyCrO{sub 3}, with its large magnetic moment dysprosium ion, are potential candidates for such an application. The Dy{sup 3+} ordering transition at low temperatures (<10 K) likely causes a large magnetocaloric response in this material. This study investigates the possibility of tuning the magnetocaloric properties through the use of rare-earth substitution. Both Y{sup 3+} and Ho{sup 3+} substitutions were found to decrease the magnetocaloric response by disrupting the R{sup 3+} ordering. Whereas Er{sup 3+} substitution was found to increase the magnetocaloric response, likely due to an increase in the R{sup 3+} ordering temperature. The large magnetocaloric entropy change of Er{sup 3+} substituted DyCrO{sub 3} (10.92 J/kg K with a relative cooling power of 237 J/kg at 40 kOe and 5 K) indicates that this material system is well suited for low temperature (<30 K) solid state refrigeration applications.
Energy Technology Data Exchange (ETDEWEB)
Kumaresavanji, M., E-mail: vanji.hplt@gmail.com; Sousa, C. T.; Pires, A.; Pereira, A. M.; Araujo, J. P. [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Department of Physics and Astronomy, Faculty of Sciences, University of Porto, Porto (Portugal); Lopes, A. M. L. [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Department of Physics and Astronomy, Faculty of Sciences, University of Porto, Porto (Portugal); CFNUL, University of Lisbon, Lisbon (Portugal)
2014-08-25
High aspect ratio La{sub 0.7}Sr{sub 0.3}MnO{sub 3} nanotube (NT) arrays have been synthesized using nitrates based sol-gel precursor by nanoporous anodized aluminum oxide template assisted method. Their phase purity and microstructures were analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. Magnetocaloric effect (MCE) of as prepared NTs was investigated by means of field dependence magnetization measurements. Significant magnetic entropy change, −△S{sub M} = 1.6 J/kg K, and the refrigerant capacitance, RC = 69 J/kg, were achieved near the transition temperature at 315 K for 5 T. For comparison, a bulk sample was also prepared using the same precursor solution which gives a value of −△S{sub M} = 4.2 J/kg K and a RC = 165 J/kg. Though the bulk sample exhibits higher △S{sub M} value, the NTs present an expanded temperature dependence of −△S{sub M} curves that spread over a broad temperature range and assured to be appropriate for active magnetic refrigeration. The diminutive MCE observed in manganite NTs is explained by the increased influence of surface sites of nanograins which affect the structural phase transition occurred by external magnetic field due to the coupling between magnetism and the lattice in manganese perovskites. Our report paves the way for further investigation in 1D manganite nanostructured materials towards applications in such magnetic refrigeration technology or even on hyperthermia/drug delivery.
Kühn, M.; John, W.; Weigel, R.
2014-11-01
This contribution contains the mechanisms for calculation of magnetic shielding effectiveness from material samples, based on measured electrical parameters. For this, measurement systems for the electrical conductivity of high and low conductive material samples with respect to the direction of current flow are presented and discussed. Also a definition of isotropic and anisotropic materials with electrical circuit diagrams is given. For prediction of shielding effectiveness for isotropic and anisotropic materials, several analytical models are presented. Also adaptions to gain a near field solution are part of this contribution. All analytical models will also be validated with an adequate measurement system.
Jet quenching effects on the anisotropic flow at RHIC
Energy Technology Data Exchange (ETDEWEB)
Andrade, R.P.G. [Centro de Ciências Naturais e Humanas, Universidade Federal do ABC, Santo André, SP, 09210-170 (Brazil); Noronha, J. [Instituto de Física, Universidade de São Paulo, C.P. 66318, 05315-970 São Paulo, SP (Brazil); Denicol, Gabriel S. [Department of Physics, McGill University, 3600 University Street, Montreal, Quebec, H3A 2T8 (Canada)
2014-12-15
In this article we investigate how the energy and momentum deposited by partonic dijets in the quark–gluon plasma may perturb the geometry-induced hydrodynamic expansion of the bulk nuclear matter created in heavy ion collisions at the RHIC. The coupling between the jets and the medium is done through a source term in the energy–momentum conservation equations for ideal hydrodynamics. We concentrate our attention at mid-rapidity and solve the equations event-by-event imposing boost-invariance. For p{sub T}≳1 GeV the anisotropic flow is found to be considerably enhanced, if the dijets deposit on average more than 12 GeV in the medium (or equivalently 6 GeV for each jet of the pair), which corresponds, in our model, to an average suppression greater than 65% of the initial jet transverse energy.
Jet quenching effects on the anisotropic flow at RHIC
International Nuclear Information System (INIS)
In this article we investigate how the energy and momentum deposited by partonic dijets in the quark–gluon plasma may perturb the geometry-induced hydrodynamic expansion of the bulk nuclear matter created in heavy ion collisions at the RHIC. The coupling between the jets and the medium is done through a source term in the energy–momentum conservation equations for ideal hydrodynamics. We concentrate our attention at mid-rapidity and solve the equations event-by-event imposing boost-invariance. For pT≳1 GeV the anisotropic flow is found to be considerably enhanced, if the dijets deposit on average more than 12 GeV in the medium (or equivalently 6 GeV for each jet of the pair), which corresponds, in our model, to an average suppression greater than 65% of the initial jet transverse energy
Directory of Open Access Journals (Sweden)
Jingjia Han
2016-05-01
Full Text Available Enhancing the maturation of human pluripotent stem cell-derived cardiomyocytes (hPSC-CMs will facilitate their applications in disease modeling and drug discovery. Previous studies suggest that cell alignment could enhance hPSC-CM maturation; however, the robustness of this approach has not been well investigated. To this end, we examined if the anisotropic orientation of hPSC-CMs imposed by the underlying aligned fibers within a 3D microenvironment could improve the maturation of hPSC-CMs. Enriched hPSC-CMs were cultured for two weeks on Matrigel-coated anisotropic (aligned and isotropic (random polycaprolactone (PCL fibrous scaffolds, as well as tissue culture polystyrenes (TCPs as a control. As expected, hPSC-CMs grown on the two types of fibrous scaffolds exhibited anisotropic and isotropic orientations, respectively. Similar to cells on TCPs, hPSC-CMs cultured on these scaffolds expressed CM-associated proteins and were pharmacologically responsive to adrenergic receptor agonists, a muscarinic agonist, and a gap junction uncoupler in a dose-dependent manner. Although hPSC-CMs grown on anisotropic fibrous scaffolds displayed the highest expression of genes encoding a number of sarcomere proteins, calcium handling proteins and ion channels, their calcium transient kinetics were slower than cells grown on TCPs. These results suggest that electrospun anisotropic fibrous scaffolds, as a single method, have limited effect on improving the maturation of hPSC-CMs.
Effects of the Biot and the squirt-flow coupling interaction on anisotropic elastic waves
Institute of Scientific and Technical Information of China (English)
无
2000-01-01
Considering the velocity anisotropy of the solid/fluid relative motion and employment of the BISQ theory[1] based on the one-dimensional porous isotropic case, we establish a two-phase anisotropic elastic wave equation to simultaneously include the Biot and the squirt mechanisms in terms of both the basic principles of the fluid's mass conservation and the elastic-wave dynamical equations in the two-phase anisotropic rock. Numerical results, while the Biot-flow and the squirt-flow effects are simultaneously considered in the transversely isotropic (TI) poroelastic medium, show that the attenuation of the quasi P-wave and the quasi SV-wave strongly depend on the permeability anisotropy, and the attenuation behavior at low and high frequencies is contrary. Meanwhile, the attenuation and dispersion of the quasi P-wave are also affected seriously by the anisotropic solid/fluid coupling additional density.
The Effect of Anisotropic Conduction on the Thermal Instability in the Interstellar Medium
Choi, Ena
2011-01-01
Thermal instability (TI) can strongly affect the structure and dynamics of the interstellar medium (ISM) in the Milky Way and other disk galaxies. Thermal conduction plays an important role in the TI by stabilizing small scales and limiting the size of the smallest condensates. In the magnetized ISM, however, heat is conducted anisotropically (primarily along magnetic field lines). We investigate the effects of anisotropic thermal conduction on the nonlinear regime of the TI by performing two-dimensional magnetohydrodynamic simulations. We present models with magnetic fields of different initial geometries and strengths, and compare them to hydrodynamic models with isotropic conduction. We find anisotropic conduction does not significantly alter the overall density and temperature statistics in the saturated state of the TI. However, it can strongly affect the shapes and sizes of cold clouds formed by the TI. For example, for uniform initial fields long filaments of cold gas are produced that are reminiscent ...
Directory of Open Access Journals (Sweden)
Cobas Acosta R.
2014-07-01
Full Text Available We report the magnetocaloric effects and temperature coefficient of resistance (TCR of La0.85Ag0.15MnO3 epitaxial thin films grown on single-crystal substrates of LaAlO3 (001 and SrTiO3 (001 using the chemical solution approach of polymer-assisted deposition (PAD. The film thicknesses are in the range 30-35 nm. Magnetocaloric effects, with entropy changes of -2.14 J/kg.K, in the case of the LaAlO3 substrate and -2.72 J/kg.K for the SrTiO3 substrate, (corresponding to a magnetic field variation of 2T were obtained at room temperature. The refrigeration capacity at this field variation reached large values of 125 J/kg and 216 J/kg, indicating that these films prepared by PAD have the potential for microcooling applications. The temperature coefficient of resistance has been calculated from the resistivity measurements. A maximum TCR value of 3.01 % K-1 was obtained at 309 K, which shows that these films also have potential as uncooled thermometers for bolometric applications.
Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements.
Sharples, Joseph W; Collison, David; McInnes, Eric J L; Schnack, Jürgen; Palacios, Elias; Evangelisti, Marco
2014-10-22
Geometric spin frustration in low-dimensional materials, such as the two-dimensional kagome or triangular antiferromagnetic nets, can significantly enhance the change of the magnetic entropy and adiabatic temperature following a change in the applied magnetic field, that is, the magnetocaloric effect. In principle, an equivalent outcome should also be observable in certain high-symmetry zero-dimensional, that is, molecular, structures with frustrated topologies. Here we report experimental realization of this in a heptametallic gadolinium molecule. Adiabatic demagnetization experiments reach ~200 mK, the first sub-Kelvin cooling with any molecular nanomagnet, and reveal isentropes (the constant entropy paths followed in the temperature-field plane) with a rich structure. The latter is shown to be a direct manifestation of the trigonal antiferromagnetic net structure, allowing study of frustration-enhanced magnetocaloric effects in a finite system.
Energy Technology Data Exchange (ETDEWEB)
Zhang, Yikun, E-mail: zhangyk@epm.neu.edu.cn [Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110004 (China); Yang, Baijun [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)
2014-10-15
Highlights: • Magnetism and magnetocaloric effect in ErNi{sub 2−x}Fe{sub x}B{sub 2}C were studied. • Ni site Fe substitution can reduce the magnetic hysteresis of ErNi{sub 2}B{sub 2}C. • The origin of MCE and its potential application in ErNi{sub 2−x}Fe{sub x}B{sub 2}C were discussed. - Abstract: The magnetic properties and magnetocaloric effect (MCE) in ErNi{sub 2−x}Fe{sub x}B{sub 2}C have been studied. Substitution of Fe for Ni lowered the magnetic transition temperature T{sub M}, and reduced the magnetic hysteresis of ErNi{sub 2}B{sub 2}C. An inverse MCE was observed under low magnetic field and at low temperatures, which is attributed to the nature of antiferromagnetic state for the present ErNi{sub 2−x}Fe{sub x}B{sub 2}C compounds. A normal MCE was observed under higher magnetic field changes, which is related to a field-induced first order metamagnetic transition from antiferromagnetic to ferromagnetic state. The maximum values of magnetic entropy change −ΔS{sub M}{sup max} are 14.5, 12.7, and 10.6 J/kg K with a magnetic field change of 0–70 kOe for x = 0, 0.1, and 0.2 in ErNi{sub 2−x}Fe{sub x}B{sub 2}C, respectively.
Korotana, R. K.; Mallia, G.; Fortunato, N. M.; Amaral, J. S.; Gercsi, Z.; Harrison, N. M.
2016-07-01
Manganites with the formula La1‑x Ca x MnO3 for 0.2 electronic structure. An isotropic expansion of the La0.75Ca0.25MnO3 cell at the phase transition has been observed experimentally. It is expected that there will be a large entropy change at the transition due to its first order nature. Doped lanthanum manganite (LMO) is therefore of interest as the active component in a magnetocaloric cooling device. However, the maximum obtained value for the entropy change in Ca-doped manganites merely reaches a moderate value in the field of a permanent magnet. The present theoretical work aims to shed light on this discrepancy. A combination of finite temperature statistical mechanics and first principles theory is applied to determine individual contributions to the total entropy change of the system by treating the electronic, lattice and magnetic components independently. Hybrid-exchange density functional (B3LYP) calculations and Monte Carlo simulations are performed for La0.75Ca0.25MnO3. Through the analysis of individual entropy contributions, it is found that the electronic and lattice entropy changes oppose the magnetic entropy change. The results highlighted in the present work demonstrate how the electronic and vibrational entropy contributions can have a deleterious effect on the total entropy change and thus the potential cooling power of doped LMO in a magnetocaloric device.
International Nuclear Information System (INIS)
Highlights: • The Curie temperature of alloy series of Co50−xNixCr25Al25 decreases with increasing x. • The critical exponents behavior and scaling relation of the alloy series have been investigated. • Using M–H data, employing Modified Arrott plot and Kouvel–Fisher plot exponents are estimated. • The estimated critical exponent values match very well with the mean field theory. • Under a magnetic field maximum up to 5 T, normal magnetocaloric effect has been observed. - Abstract: This work reports the investigation of critical behavior of Co50−xNixCr25Al25 (x = 0 and 5) and magneto caloric effect (MCE) of bulk Co2CrAl full Heusler alloy system. The alloy series of Co50−xNixCr25Al25 (x = 0, 1, 2, 3, 4 and 5) have been prepared using arc melting technique. The magnetic properties of all the samples have been studied in the temperature range of 5–300 K. The value of Curie temperature (TC) is found to decrease with increasing doping concentration of the Ni (substitution of Ni at Co site). The critical exponents behavior and scaling relation have been investigated using magnetic isotherms in Co50−xNixCr25Al25 (x = 0 and 5) alloys. The critical exponents are estimated by various techniques such as, Modified Arrott plot, Kouvel–Fisher plot and critical isotherm technique. The value of critical exponents vicinity to the second order magnetic phase transition of Co50Cr25Al25 were found to be β = 0.488 (7), γ = 1.144 (16) and δ = 3.336 (5) with TC = 328.64 (5) K whereas for Co50Ni5Cr25Al25 the values are β = 0.522 (13), γ = 1.014 (6) and δ = 3.043 (7) with TC = 285.71 (11). The critical exponent values for both the samples are almost similar to the value as predicted by mean field theory. This has been best explained by long range mean field like ferromagnetic interaction in the entire Co50−xNixCr25Al25 (x = 0, 5) highly spin polarized full Heusler alloy system. Under an external magnetic field maximum up to 5 T, normal magneto caloric
The unique effect of in-plane anisotropic strain in the magnetization control by electric field
Zhao, Y. Y.; Wang, J.; Hu, F. X.; Liu, Y.; Kuang, H.; Wu, R. R.; Sun, J. R.; Shen, B. G.
2016-05-01
The electric field control of magnetization in both (100)- and (011)-Pr0.7Sr0.3MnO3/Pb(Mg1/3Nb2/3)0.7Ti0.3O3(PSMO/PMN-PT) heterostructures were investigated. It was found that the in-plane isotropic strain induced by electric field only slightly reduces the magnetization at low temperature in (100)-PSMO/PMN-PT film. On the other hand, for (011)-PSMO/PMN-PT film, the in-plane anisotropic strain results in in-plane anisotropic, nonvolatile change of magnetization at low-temperature. The magnetization, remanence and coercivity along in-plane [100] direction are suppressed by the electric field while the ones along [01-1] direction are enhanced, which is ascribed to the extra effective magnetic anisotropy induced by the electric field via anisotropic piezostrains. More interestingly, such anisotropic modulation behaviors are nonvolatile, demonstrating a memory effect.
The unique effect of in-plane anisotropic strain in the magnetization control by electric field
Directory of Open Access Journals (Sweden)
Y. Y. Zhao
2016-05-01
Full Text Available The electric field control of magnetization in both (100- and (011-Pr0.7Sr0.3MnO3/Pb(Mg1/3Nb2/30.7Ti0.3O3(PSMO/PMN-PT heterostructures were investigated. It was found that the in-plane isotropic strain induced by electric field only slightly reduces the magnetization at low temperature in (100-PSMO/PMN-PT film. On the other hand, for (011-PSMO/PMN-PT film, the in-plane anisotropic strain results in in-plane anisotropic, nonvolatile change of magnetization at low-temperature. The magnetization, remanence and coercivity along in-plane [100] direction are suppressed by the electric field while the ones along [01-1] direction are enhanced, which is ascribed to the extra effective magnetic anisotropy induced by the electric field via anisotropic piezostrains. More interestingly, such anisotropic modulation behaviors are nonvolatile, demonstrating a memory effect.
Energy Technology Data Exchange (ETDEWEB)
Thanh, Tran Dang [Chungbuk National University, Cheongju (Korea, Republic of); Vietnam Academy of Science and Technology, Hanoi (Viet Nam); Mai, Nguyen Thi [VNU University of Science, Hanoi (Viet Nam); Dan, Nguyen Huy [Vietnam Academy of Science and Technology, Hanoi (Viet Nam); Phan, The Long; Yu, Seong Cho [Chungbuk National University, Cheongju (Korea, Republic of)
2014-11-15
In this work, we present a detailed study of the magnetic properties and the magnetocaloric effect at room temperature of Ni{sub 50-x}Ag{sub x}Mn{sub 37}Sn{sub 13} alloys with x = 1, 2, and 4, which were prepared by using an arc-melting method. Experimental results reveal that a partial replacement of Ag for Ni leads to a decrease in the anti-FM phase in the alloys. In addition, the martensitic-austenitic phase transition shifts towards lower temperature and is broaded. The Curie temperature (T{sup A}{sub C} ) for the austenitic phase also shifts toward to lower temperature, but not by much. The Curie temperature was found to be 308, 305, and 298 K for x = 1, 2, and 4, respectively. The magnetic entropy change (ΔS{sub m}) of the samples was calculated by using isothermal magnetization data. Under an applied magnetic field change of 10 kOe, the maximum value of ΔS{sub m} (|ΔS{sub max}|) was achieved at around room temperature and did not change much (∼0.8 J·kg{sup -1}·K{sup -1}) with increasing Ag-doping concentration. Particularly, the M{sup 2} vs. H/M curves prove that all the samples exhibited a secondorder magnetic phase transition. Based on Landau's phase-transition theory and careful analyses of the magnetic data around the T{sup A}{sub C} , we have determined the critical parameters β, γ, δ, and T{sub C} . The results show that the β values are located between those expected for the 3D-Heisenberg model (β = 0.365) and mean-field theory (β = 0.5). Such a result proves the coexistence of short-range and long-range ferromagnetic interactions in Ni{sub 50-x}Ag{sub x}Mn{sub 37}Sn{sub 13} alloys. The nature of the changes in the critical parameters and the |ΔS{sub max}| is thoroughly discussed by means of structural analyses.
High performance magnetocaloric perovskites for magnetic refrigeration
VelÁzquez, David
2012-01-01
We have applied mixed valance manganite perovskites as magnetocaloric materials in a magnetic refrigeration device. Relying on exact control of the composition and a technique to process the materials into single adjoined pieces, we have observed temperature spans above 9 K with two materials. Reasonable correspondence is found between experiments and a 2D numerical model, using the measured magnetocaloric properties of the two materials as input. © 2012 American Institute of Physics.
International Nuclear Information System (INIS)
The earliest high-Tc oxide superconductors were generally studied in the form of porous polycrystalline pellets. As material preparation technology improved, resulting in samples with orientational order and a smaller concentration of impurity phases, the effects of granular behaviour did not disappear. In both the cases of disordered and partially-ordered structures, an important question arises as to how to interpret measured low-field resistivities in terms of the underlying anisotropic single-crystal values. This paper provides the answer to this question within the context of an effective-medium theory. The authors version of the effective-medium approximation attempts to describe the electrical properties of an inhomogeneous medium, consisting of a mixture of several types of anisotropic polycrystals with different degrees of orientational order. (author)
Magnetocaloric properties and critical behavior of high relative cooling power FeNiB nanoparticles
Chaudhary, V.; Maheswar Repaka, D. V.; Chaturvedi, A.; Sridhar, I.; Ramanujan, R. V.
2014-10-01
Low cost magnetocaloric nanomaterials have attracted considerable attention for energy efficient applications. We report a very high relative cooling power (RCP) in a study of the magnetocaloric effect in quenched FeNiB nanoparticles. RCP increases from 89.8 to 640 J kg-1 for a field change of 1 and 5 T, respectively, these values are the largest for rare earth free iron based magnetocaloric nanomaterials. To investigate the magnetocaloric behavior around the Curie temperature (TC), the critical behavior of these quenched nanoparticles was studied. Detailed analysis of the magnetic phase transition using the modified Arrott plot, Kouvel-Fisher method, and critical isotherm plots yields critical exponents of β = 0.364, γ = 1.319, δ = 4.623, and α = -0.055, which are close to the theoretical exponents obtained from the 3D-Heisenberg model. Our results indicate that these FeNiB nanoparticles are potential candidates for magnetocaloric fluid based heat pumps and low grade waste heat recovery.
Magnetocaloric properties and critical behavior of high relative cooling power FeNiB nanoparticles
Energy Technology Data Exchange (ETDEWEB)
Chaudhary, V. [Interdisciplinary Graduate School, Nanyang Technological University, Singapore 639798 (Singapore); Energy Research Institute @NTU, Nanyang Technological University, Singapore 637553 (Singapore); School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Maheswar Repaka, D. V.; Chaturvedi, A.; Ramanujan, R. V., E-mail: ramanujan@ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Sridhar, I. [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)
2014-10-28
Low cost magnetocaloric nanomaterials have attracted considerable attention for energy efficient applications. We report a very high relative cooling power (RCP) in a study of the magnetocaloric effect in quenched FeNiB nanoparticles. RCP increases from 89.8 to 640 J kg{sup −1} for a field change of 1 and 5 T, respectively, these values are the largest for rare earth free iron based magnetocaloric nanomaterials. To investigate the magnetocaloric behavior around the Curie temperature (T{sub C}), the critical behavior of these quenched nanoparticles was studied. Detailed analysis of the magnetic phase transition using the modified Arrott plot, Kouvel-Fisher method, and critical isotherm plots yields critical exponents of β = 0.364, γ = 1.319, δ = 4.623, and α = −0.055, which are close to the theoretical exponents obtained from the 3D-Heisenberg model. Our results indicate that these FeNiB nanoparticles are potential candidates for magnetocaloric fluid based heat pumps and low grade waste heat recovery.
Asoubar, Daniel; Zhang, Site; Wyrowski, Frank
2015-06-01
Birefringence effects can have a significant influence on the polarization state as well as on the transversal mode structure of laser resonators. This work introduces a flexible, fast and fully vectorial algorithm for the analysis of resonators containing homogeneous, anisotropic optical components. It is based on a generalization of the Fox and Li algorithm by field tracing, enabling the calculation of the dominant transversal resonator eigenmode. For the simulation of light propagation through the anisotropic media, a fast Fourier Transformation (FFT) based angular spectrum of plane waves approach is introduced. Besides birefringence effects, this technique includes intra-crystal diffraction and interface refraction at crystal surfaces. The combination with numerically efficient eigenvalue solvers, namely vector extrapolation methods, ensures the fast convergence of the method. Furthermore a numerical example is presented which is in good agreement to experimental measurements. PMID:26072756
Onofri, M; Malara, F; Veltri, P
2010-11-19
A compressible magnetohydrodynamics simulation of the reversed-field pinch is performed including anisotropic thermal conductivity. When the thermal conductivity is much larger in the direction parallel to the magnetic field than in the perpendicular direction, magnetic field lines become isothermal. As a consequence, as long as magnetic surfaces exist, a temperature distribution is observed displaying a hotter confined region, while an almost uniform temperature is produced when the magnetic field lines become chaotic. To include this effect in the numerical simulation, we use a multiple-time-scale analysis, which allows us to reproduce the effect of a large parallel thermal conductivity. The resulting temperature distribution is related to the existence of closed magnetic surfaces, as observed in experiments. The magnetic field is also affected by the presence of an anisotropic thermal conductivity. PMID:21231314
Dani, I.; Tahiri, N.; Ez-Zahraouy, H.; Benyoussef, A.
2016-08-01
In this paper we study, using mean field theory (MFT), the effect of the anisotropic Dzyaloshinskii-Moriya (DM) interaction on the phase diagrams of the spin-half Ashkin-Teller model on hypercubic lattice. Different new phase diagrams are found by varying the anisotropy of DM interaction. The multicritical behavior is studied as a function of four-spin interaction coefficient J4 /J1 and for two fixed values of spin interaction coefficient J2 /J1.
Sophia Haussener; Aldo Steinfeld
2012-01-01
High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct pore-level numerical simulations for determining the morphological and effective heat/mass transport properties of porous ceria, namely: porosity, specific surface area, pore size distribution, extinction coefficient, thermal conductivity, conv...
Energy Technology Data Exchange (ETDEWEB)
Wu, Yuye; Wang, Jingmin, E-mail: jingmin@buaa.edu.cn; Hua, Hui; Jiang, Chengbao; Xu, Huibin
2015-05-25
Highlights: • Effect of Tb addition on phase transition temperatures of Ni{sub 50}Mn{sub 29}Ga{sub 21} were clarified. • Coupled magneto-structural transition were observed in Ni{sub 50}Mn{sub 29}Ga{sub 21}Tb{sub 0.2} alloy. • Large magnetocaloric effect was monitored from the magneto-structural transition. - Abstract: Ni{sub 50}Mn{sub 29}Ga{sub 21−x}Tb{sub x} (0 ⩽ x ⩽ 1) alloys were studied with the microstructure, phase transition, and magnetocaloric effect. Dual-phase microstructure containing the martensite matrix and Tb-rich precipitations were formed. The martensitic transformation was observed over the whole composition range, with the transformation temperature T{sub M} significantly increased by the addition of terbium. The magnetic transition temperatures of the austenite and martensite, i.e. T{sub C}{sup A} and T{sub C}{sup M}, were monitored for 0 ⩽ x ⩽ 0.16 and 0.27 ⩽ x ⩽ 1, respectively. Both T{sub C}{sup A} and T{sub C}{sup M} were slightly decreased by the addition of terbium. For 0.16 ⩽ x ⩽ 0.27 the martensitic transformation was coincided with the magnetic transition in case of T{sub M} = T{sub C}, giving rise to the coupled magneto-structural transition from ferromagnetic martensite to paramagnetic austenite. Sizable magnetic entropy change was induced by magnetic field in the vicinity of the coupled magneto-structural transition.
Midya, A.; Khan, N.; Bhoi, D.; Mandal, P.
2013-08-01
We have investigated the influence of 3d-4f spin interaction on magnetic and magnetocaloric properties of DyCrO4 and HoCrO4 compounds by magnetization and heat capacity measurements. Both the compounds exhibit complicated magnetic properties and huge magnetic entropy change around the ferromagnetic transition due to the strong competition between ferromagnetic and antiferromagnetic superexchange interactions. For a field change of 8 T, the maximum values of magnetic entropy change (ΔSMmax), adiabatic temperature change (ΔTad), and refrigerant capacity (RC) reach 29 J kg-1 K-1, 8 K, and 583 J kg-1, respectively, for DyCrO4 whereas the corresponding values for HoCrO4 are 31 J kg-1 K-1, 12 K, and 622 J kg-1. ΔSMmax, ΔTad, and RC are also quite large for a moderate field change. The large values of magnetocaloric parameters suggest that the zircon-type DyCrO4 and HoCrO4 could be the potential magnetic refrigerant materials for liquefaction of hydrogen.
Ghofrani Tabari, Mehdi; Goodfellow, Sebastian; Young, R. Paul
2016-04-01
Although true-triaxial testing (TTT) of rocks is now more extensive worldwide, stress-induced heterogeneity due to the existence of several loading boundary effects is not usually accounted for and simplified anisotropic models are used. This study focuses on the enhanced anisotropic velocity structure to improve acoustic emission (AE) analysis for an enhanced interpretation of induced fracturing. Data from a TTT on a cubic sample of Fontainebleau sandstone is used in this study to evaluate the methodology. At different stages of the experiment the True-Triaxial Geophysical Imaging Cell (TTGIC), armed with an ultrasonic and AE monitoring system, performed several velocity surveys to image velocity structure of the sample. Going beyond a hydrostatic stress state (poro-elastic phase), the rock sample went through a non-dilatational elastic phase, a dilatational non-damaging elasto-plastic phase containing initial AE activity and finally a dilatational and damaging elasto-plastic phase up to the failure point. The experiment was divided into these phases based on the information obtained from strain, velocity and AE streaming data. Analysis of the ultrasonic velocity survey data discovered that a homogeneous anisotropic core in the center of the sample is formed with ellipsoidal symmetry under the standard polyaxial setup. Location of the transducer shots were improved by implementation of different velocity models for the sample starting from isotropic and homogeneous models going toward anisotropic and heterogeneous models. The transducer shot locations showed a major improvement after the velocity model corrections had been applied especially at the final phase of the experiment. This location improvement validated our velocity model at the final phase of the experiment consisting lower-velocity zones bearing partially saturated fractures. The ellipsoidal anisotropic velocity model was also verified at the core of the cubic rock specimen by AE event location of
Saving Moore’s Law Down To 1 nm Channels With Anisotropic Effective Mass
Ilatikhameneh, Hesameddin; Ameen, Tarek; Novakovic, Bozidar; Tan, Yaohua; Klimeck, Gerhard; Rahman, Rajib
2016-08-01
Scaling transistors’ dimensions has been the thrust for the semiconductor industry in the last four decades. However, scaling channel lengths beyond 10 nm has become exceptionally challenging due to the direct tunneling between source and drain which degrades gate control, switching functionality, and worsens power dissipation. Fortunately, the emergence of novel classes of materials with exotic properties in recent times has opened up new avenues in device design. Here, we show that by using channel materials with an anisotropic effective mass, the channel can be scaled down to 1 nm and still provide an excellent switching performance in phosphorene nanoribbon MOSFETs. To solve power consumption challenge besides dimension scaling in conventional transistors, a novel tunnel transistor is proposed which takes advantage of anisotropic mass in both ON- and OFF-state of the operation. Full-band atomistic quantum transport simulations of phosphorene nanoribbon MOSFETs and TFETs based on the new design have been performed as a proof.
A multicaloric material as a link between electrocaloric and magnetocaloric refrigeration
Ursic, Hana; Bobnar, Vid; Malic, Barbara; Filipic, Cene; Vrabelj, Marko; Drnovsek, Silvo; Jo, Younghun; Wencka, Magdalena; Kutnjak, Zdravko
2016-05-01
The existence and feasibility of the multicaloric, polycrystalline material 0.8Pb(Fe1/2Nb1/2)O3-0.2Pb(Mg1/2W1/2)O3, exhibiting magnetocaloric and electrocaloric properties, are demonstrated. Both the electrocaloric and magnetocaloric effects are observed over a broad temperature range below room temperature. The maximum magnetocaloric temperature change of ~0.26 K is obtained with a magnetic-field amplitude of 70 kOe at a temperature of 5 K, while the maximum electrocaloric temperature change of ~0.25 K is obtained with an electric-field amplitude of 60 kV/cm at a temperature of 180 K. The material allows a multicaloric cooling mode or a separate caloric-modes operation depending on the origin of the external field and the temperature at which the field is applied.
Effective dielectric response of graded composite materials containing anisotropic particles
Institute of Scientific and Technical Information of China (English)
Sang Zhi-Fang; Li Zhen-Ya
2005-01-01
The effective dielectric response of granular composites, in which spheroidal particles with graded shells are randomly distributed in a host matrix, is investigated. General expressions for the effective dielectric constant of the composites and partial resonant condition are obtained in the dilute limit by use of a quasi-static approximation. In particular, spheroidal particles with a power-law gradation profile in the shells are studied in detail. We find that, by adjusting the dielectric gradient profile in the shells, the shape and structure of particles, it is possible to enhance the effective dielectric constant of the composite and to realize partial resonance. Under the partial resonant conditions,the coated spheroidal particles with graded shells within the host matrix can be regarded as equivalent homogeneous spheroids embedded in the same host. The equivalent spheroids have the same dielectric constant as the original cores and semiaxes equal to those of the original shells: i.e., the partial resonant system behaves as if the cores of the particles were enlarged and the shells were absent.
Critical behavior and magnetocaloric effect of Pr{sub 1−x}Ca{sub x}MnO{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Ho, T. A.; Phan, The-Long; Yu, S. C., E-mail: scyu@chungbuk.ac.kr [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Thanh, T. D. [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Institute of Materials Science, Vietnam Academy of Science and Technology, 18-Hoang Quoc Viet, Hanoi (Viet Nam); Yu, Yikyung; Tartakovsky, D. M. [Department of Mechanical and Aerospace Engineering, University of California, San Diego, California 92093-0411 (United States); Ho, T. O. [Institute of Chemistry, Vietnam Academy of Science and Technology, 18-Hoang Quoc Viet, Hanoi (Viet Nam); Thang, P. D. [Faculty of Engineering Physics and Nanotechnology, VNU University of Engineering and Technology, 144 Xuan Thuy, Cau Giay, Hanoi (Viet Nam); Le, Anh-Tuan [Department of Nanoscience and Nanotechnology, Advanced Institute for Science and Technology, Hanoi University of Science and Technology, 01 Dai Co Viet, Hai Ba Trung, Hanoi (Viet Nam)
2015-05-07
The critical behavior of Pr{sub 1−x}Ca{sub x}MnO{sub 3} samples with x = 0.25, 0.27, and 0.29 has been investigated. Detailed analyses of magnetic-field dependences of magnetization at temperatures around the paramagnetic-ferromagnetic transition, M(H, T), reveal that the samples undergo a second-order magnetic phase transition. The Arrott plot method predicts the values of critical parameters to be T{sub C} ≈ 118 K, β = 0.351 ± 0.003, γ = 1.372 ± 0.002, and δ = 4.90 ± 0.02 for x = 0.25; T{sub C} ≈ 116 K, β = 0.362 ± 0.002, γ = 1.132 ± 0.004, and δ = 4.09 ± 0.03 for x = 0.27; and T{sub C} ≈ 110 K, β = 0.521 ± 0.002, γ = 0.912 ± 0.005, and δ = 2.71 ± 0.02 for x = 0.29. The values of β = 0.351 (for x = 0.25) and β = 0.362 (for x = 0.27) are close to the value β = 0.365 expected for the 3D Heisenberg model, proving an existence of short-range ferromagnetic interactions in these samples. A slight increase in Ca-doping content (x = 0.29) leads to the shift of the β value (=0.521) towards that of the mean-field theory (with β = 0.5) characteristic of long-range ferromagnetic interactions. The samples also exhibit a magnetocaloric effect: around T{sub C} of Pr{sub 1−x}Ca{sub x}MnO{sub 3} compounds, magnetic-entropy change reaches the maximum values of about 5.0, 4.1, and 2.5 J kg{sup −1} K{sup −1} for x = 0.25, 0.27, and 0.29, respectively, under an applied-field change of 50 kOe. Magnetic-field dependences of the maximum magnetic-entropy change (ΔS{sub max}) obey a power law |ΔS{sub max}(H)| ∝ H{sup n}, where exponent values n = 0.68–0.74 are close to those obtained from the theoretical relation n = 1 + (β − 1)/(β + γ)
Diez, A.; Eisen, O.; Hofstede, C.; Lambrecht, A.; Mayer, C.; Miller, H.; Steinhage, D.; Binder, T.; Weikusat, I.
2015-02-01
We investigate the propagation of seismic waves in anisotropic ice. Two effects are important: (i) sudden changes in crystal orientation fabric (COF) lead to englacial reflections; (ii) the anisotropic fabric induces an angle dependency on the seismic velocities and, thus, recorded travel times. Velocities calculated from the polycrystal elasticity tensor derived for the anisotropic fabric from measured COF eigenvalues of the EDML ice core, Antarctica, show good agreement with the velocity trend determined from vertical seismic profiling. The agreement of the absolute velocity values, however, depends on the choice of the monocrystal elasticity tensor used for the calculation of the polycrystal properties. We make use of abrupt changes in COF as a common reflection mechanism for seismic and radar data below the firn-ice transition to determine COF-induced reflections in either data set by joint comparison with ice-core data. Our results highlight the possibility to complement regional radar surveys with local, surface-based seismic experiments to separate isochrones in radar data from other mechanisms. This is important for the reconnaissance of future ice-core drill sites, where accurate isochrone (i.e. non-COF) layer integrity allows for synchronization with other cores, as well as studies of ice dynamics considering non-homogeneous ice viscosity from preferred crystal orientations.
Simulations of the anisotropic kinetic and magnetic alpha effects
Brandenburg, A
2007-01-01
The validity of a closure called the minimal tau approximation (MTA), is tested in the context of dynamo theory, wherein triple correlations are assumed to provide relaxation of the turbulent electromotive force. Under MTA, the alpha effect in mean field dynamo theory becomes proportional to a relaxation time scale multiplied by the difference between kinetic and current helicities. It is shown that the value of the relaxation time is positive and, in units of the turnover time at the forcing wavenumber, it is of the order of unity. It is quenched by the magnetic field -- roughly independently of the magnetic Reynolds number. However, this independence becomes uncertain at large magnetic Reynolds number. Kinetic and current helicities are shown to be dominated by large scale properties of the flow.
Brewster effect in metafilms composed of bi-anisotropic split-ring resonators
Tamayama, Yasuhiro
2015-01-01
The Brewster effect is extended to single-layer metafilms. In contrast to bulk media, the Brewster effect in metafilms can be realized by tailoring the radiation pattern of a distribution of meta-atoms rather than the effective medium parameters. A metafilm composed of bi-anisotropic split-ring resonators is designed based on the theory, and its characteristics are numerically analyzed. The simulation demonstrates that there exists a condition for which the polarization of the reflected wave becomes independent of the incident polarization at a particular angle of incidence.
Effects of anisotropic winds on massive stars evolution
Cyril, Georgy; André, Maeder
2010-01-01
Whenever stars are rotating very fast ($\\Omega/\\Omega_\\mathrm{crit} > 0.7$, with $\\Omega_\\mathrm{crit}$ the Keplerian angular velocity of the star accounting for its deformation) radiative stellar winds are enhanced in polar regions. This theoretical prediction is now confirmed by interferometric observations of fast rotating stars.} Polar winds remove less angular momentum than spherical winds and thus allow the star to keep more angular momentum. We quantitatively assess the importance of this effect. First we use a semi-analytical approach to estimate the variation of the angular momentum loss when the rotation parameter increases. Then we compute complete 9 M$_\\odot$ stellar models at very high angular velocities (starting on the ZAMS with $\\Omega/\\Omega_\\mathrm{crit} = 0.8$ and reaching the critical velocity during the Main Sequence) with and without radiative wind anisotropies. When wind anisotropies are accounted for, the angular momentum loss rate is reduced by less than $4%$ for $\\Omega/\\Omega_\\mathr...
Interface crack growth for anisotropic plasticity with non-normality effects
DEFF Research Database (Denmark)
Tvergaard, Viggo; Legarth, Brian Nyvang
2007-01-01
an oscillating stress singularity, and with conditions of small scale yielding this solution is applied as boundary conditions on the outer edge of the region analyzed. Crack growth resistance curves are calculated numerically, and the effect of the near-tip mode mixity on the steady-state fracture toughness...... elastic–viscoplastic material model is applied, using an anisotropic yield criterion, and in each case analyzed the effect of non-normality is compared with results for the standard normality flow rule. Due to the mismatch of elastic properties across the interface the corresponding elastic solution has...
Extrinsic spin Hall effect from anisotropic Rashba spin-orbit coupling in graphene
Yang, H.-Y.; Huang, Chunli; Ochoa, H.; Cazalilla, M. A.
2016-02-01
We study the effect of anisotropy of the Rashba coupling on the extrinsic spin Hall effect due to spin-orbit active adatoms on graphene. In addition to the intrinsic spin-orbit coupling, a generalized anisotropic Rashba coupling arising from the breakdown of both mirror and hexagonal symmetries of pristine graphene is considered. We find that Rashba anisotropy can strongly modify the dependence of the spin Hall angle on carrier concentration. Our model provides a simple and general description of the skew scattering mechanism due to the spin-orbit coupling that is induced by proximity to large adatom clusters.
Energy Technology Data Exchange (ETDEWEB)
Assadi, Abbas, E-mail: assadi@aut.ac.ir; Salehi, Manouchehr, E-mail: msalehi@aut.ac.ir; Akhlaghi, Mehdi, E-mail: makhlagi@aut.ac.ir
2015-07-17
In this work, size dependent behavior of single crystalline normal and auxetic anisotropic nanoplates is discussed with consideration of material surface stresses via a generalized model. Bending of pressurized nanoplates and their fundamental resonant frequency are discussed for different crystallographic directions and anisotropy degrees. It is explained that the orientation effects are considerable when the nanoplates' edges are pinned but for clamped nanoplates, the anisotropy effect may be ignored. The size effects are the highest when the simply supported nanoplates are parallel to [110] direction but as the anisotropy gets higher, the size effects are reduced. The orientation effect is also discussed for possibility of self-instability occurrence in nanoplates. The results in simpler cases are compared with previous experiments for nanowires but with a correction factor. There are still some open questions for future studies. - Highlights: • Size effects in single crystalline anisotropic nanoplates are discussed. • A generalized model is established containing some physical assumptions. • Orientation dependent size effects due to material anisotropy are explained. • Bending, instability and frequencies are studied at normal/auxetic domain.
On the Newtonian anisotropic configurations
Energy Technology Data Exchange (ETDEWEB)
Shojai, F. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Institute for Research in Fundamental Sciences (IPM), Foundations of Physics Group, School of Physics, Tehran (Iran, Islamic Republic of); Fazel, M.R.; Stepanian, A. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Kohandel, M. [Alzahra University, Department of Sciences, Tehran (Iran, Islamic Republic of)
2015-06-15
In this paper we are concerned with the effects of an anisotropic pressure on the boundary conditions of the anisotropic Lane-Emden equation and the homology theorem. Some new exact solutions of this equation are derived. Then some of the theorems governing the Newtonian perfect fluid star are extended, taking the anisotropic pressure into account. (orig.)
Institute of Scientific and Technical Information of China (English)
JI An-Chun; TIAN Guang-Shan
2006-01-01
In the present paper, we calculate the Gaussian correction to the critical value Jc⊥ caused by quantum spin fluctuation in a two-dimensional spatially anisotropic Heisenberg antiferromagnet with integer spin S. Previously, someauthors computed this quantity by the mean-field theory based on the Schwinger boson representation of spin operators.However, for S = 1, their result is much less than the one derived by numerical calculations. By taking the effect ofquantum spin fluctuation into consideration, we are able to produce a greatly improved result.
Effect of strain path change on limits to ductility of anisotropic metal sheets
DEFF Research Database (Denmark)
Kuroda, M.; Tvergaard, Viggo
2000-01-01
Localized necking in thin metal sheets is analyzed by using the M-K-model approach, and the effect of a number of different non-proportional strain paths prior to the occurrence flow localization are considered. The analyses account for plastic anisotropy, using four different anisotropic...... plasticity models to fit a set of experimental data for cold-rolled steel sheet. The predicted forming limit diagrams show strong dependence on whether or not the load on the sheet is removed between two load steps on a non-proportional strain path. This dependence is investigated in detail for one...... response. (C) 2000 Elsevier Science Ltd. All rights reserved....
Thermofluid Analysis of Magnetocaloric Refrigeration
Energy Technology Data Exchange (ETDEWEB)
Abdelaziz, Omar [ORNL; Gluesenkamp, Kyle R [ORNL; Vineyard, Edward Allan [ORNL; Benedict, Michael [GE Appliances
2014-01-01
While there have been extensive studies on thermofluid characteristics of different magnetocaloric refrigeration systems, a conclusive optimization study using non-dimensional parameters which can be applied to a generic system has not been reported yet. In this study, a numerical model has been developed for optimization of active magnetic refrigerator (AMR). This model is computationally efficient and robust, making it appropriate for running the thousands of simulations required for parametric study and optimization. The governing equations have been non-dimensionalized and numerically solved using finite difference method. A parametric study on a wide range of non-dimensional numbers has been performed. While the goal of AMR systems is to improve the performance of competitive parameters including COP, cooling capacity and temperature span, new parameters called AMR performance index-1 have been introduced in order to perform multi objective optimization and simultaneously exploit all these parameters. The multi-objective optimization is carried out for a wide range of the non-dimensional parameters. The results of this study will provide general guidelines for designing high performance AMR systems.
Energy Technology Data Exchange (ETDEWEB)
Dhahri, Ja. [Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir (Tunisia); Dhahri, A., E-mail: abdessalem_dhahri@yahoo.fr [Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir (Tunisia); Center for Scientific Research, Department of Physics, Al-Qunfudah University College, Umm Al-Qura University (Saudi Arabia); Oummezzine, M. [Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir (Tunisia); Hlil, E.K. [Institut Ne´el, CNRS–Université J. Fourier, BP166, 38042 Grenoble (France)
2015-03-15
We have studied the structural, magnetic and magnetocaloric properties of La{sub 0.6}Nd{sub 0.1}Sr{sub 0.15}Ca{sub 0.15}Mn{sub 1−x}Fe{sub x}O{sub 3} (LNSCMFe{sub x}) perovskite samples. The samples were synthesized using the solid-state reaction at high temperature and were analyzed by XRD data based on the Rietveld refinement technique. LNSCMFe{sub x} samples crystallized in orthorhombic symmetry with Pnma space group. Besides, the curves of magnetization reveals that all samples exhibit a magnetic transition from the paramagnetic to ferromagnetic phase at the Curie temperature T{sub C}, which decreases from 327 K to 296 K with the increase of the Fe doping level from x=0 to x=0.1. The thermal evolution of magnetization in the ferromagnetic phase at low temperature varies as T{sup 3/2} in accordance with Bloch's law. The magnitude of the isothermal magnetic entropy, (−ΔS{sub M}{sup max}), at the FM Curie temperature increases from 3.79 J/kg K for x=0 composition to 5.8 J/kg K for x=0.1, under a magnetic field of 5 T. For an applied magnetic field of 5 T, the relative cooling power (RCP) values are found to vary between 173.66 and 231.76 J/kg. These results suggest that these materials could be used as an active magnetic refrigerant around room temperature. - Highlights: • La{sub 0.6}Nd{sub 0.1}Sr{sub 0.15}Ca{sub 0.15}Mn{sub 1−x}Fe{sub x}O{sub 3} samples were prepared using solid-state reaction. • The manganite phase crystallizes in an orthorhombic (Pnma) structure. • The samples exhibit a second order PM–FM phase transition at T{sub C}. • LNSCMFe{sub 0.05} and LNSCMFe{sub 0.1} are potential candidates for room-temperature magnetic refrigeration.
DEFF Research Database (Denmark)
Lei, Tian; Nielsen, Kaspar Kirstein; Engelbrecht, Kurt
2014-01-01
Compared to a conventional vapor compression refrigera-tion system, a magnetocaloric refrigerator has many advantages, such as potentially high efficiency, low vibration and avoidance of refrigerants that deplete the ozone layer and cause the green-house effect. As a main component of the active...
Magnetic structure and phase formation of magnetocaloric Mn-Fe-P-X compounds
Ou, Z.Q.
2013-01-01
This thesis presents a study of the crystal and magnetic structure, the magnetocaloric effect and related physical properties in Mn-Fe-P-X compounds. The influences of boron addition in (Mn,Fe)2(P,As) compounds have been studied. It is found that boron atoms occupy interstitial sites within the basa
Khan, Najeeb Alam
2016-01-01
This study deals with the investigation of MHD flow of Williamson fluid over an infinite rotating disk with the effects of Soret, Dufour, and anisotropic slip. The anisotropic slip and the Soret and Dufour effects are the primary features of this study, which greatly influence the flow, heat and mass transport properties. In simultaneous appearance of heat and mass transfer in a moving fluid, the mass flux generated by temperature gradients is known as the thermal-diffusion or Soret effect and the energy flux created by a composition gradient is called the diffusion-thermo or Dufour effect, however, difference in slip lengths in streamwise and spanwise directions is named as anisotropic slip. The system of nonlinear partial differential equations (PDEs), which governs the flow, heat and mass transfer characteristics, is transformed into ordinary differential equations (ODEs) with the help of von K\\'arm\\'an similarity transformation. A numerical solution of the complicated ODEs is carried out by a MATLAB routi...
Effects of anisotropic thermal conduction on wind properties in hot accretion flow
Bu, De-Fu; Yuan, Ye-Fei
2016-01-01
Previous works have clearly shown the existence of winds from black hole hot accretion flow and investigated their detailed properties. In extremely low accretion rate systems, the collisional mean-free path of electrons is large compared with the length-scale of the system, thus thermal conduction is dynamically important. When the magnetic field is present, the thermal conduction is anisotropic and energy transport is along magnetic field lines. In this paper, we study the effects of anisotropic thermal conduction on the wind production in hot accretion flows by performing two-dimensional magnetohydrodynamic simulations. We find that thermal conduction has only moderate effects on the mass flux of wind. But the energy flux of wind can be increased by a factor of $\\sim 10$ due to the increase of wind velocity when thermal conduction is included. The increase of wind velocity is because of the increase of driving forces (e.g. gas pressure gradient force and centrifugal force) when thermal conduction is includ...
Horgan, C. O.; Simmonds, J. G.
1994-12-01
Many useful thin-walled structures of interest to the U.S. Army, such as rifle barrels, automotive parts, rocket casings, helicopter blades, driveshafts, and containment vessels, are often constructed of layers of anisotropic, filament or fiber-reinforced materials. While many of these structures are subject to severe mechanical, inertial, or thermal loads, they often must be designed to remain elastic. This means that it is particularly important to be able to compute accurately global characteristics, such as buckling loads and natural frequencies, as well as local information such as stresses near holes or edges. Two important, complementary regions of such structures, have been studied, namely, the interior where there are no steep stress gradients, and the edge zone(s) where stress gradients are high. For both regions, simplified, cost-effective asymptotic methods have been developed. These considerations are particularly important in layered, anisotropic structures because many investigators have (1) claimed that higher-order (and hence computationally expensive) beam, plate, or shell theories are needed for such structures and (2) not paid sufficient attention to the particularly severe end effects (breakdown of Saint-Venant's principle) such structures engender.
Magnetic anisotropic effects and electronic correlations in MnBi ferromagnet
Energy Technology Data Exchange (ETDEWEB)
Antropov, VP; Antonov, VN; Bekenov, LV; Kutepov, A; Kotliar, G
2014-08-07
The electronic structure and numerous magnetic properties of MnBi magnetic systems are investigated using local spin density approximation (LSDA) with on-cite Coulomb correlations (LSDA+U) included. We show that the inclusion of Coulomb correlations provides a much better description of equilibrium magnetic moments on Mn atoms as well as the magnetic anisotropy energy behavior with temperature and magneto-optical effects. We found that the inversion of the anisotropic pairwise exchange interaction between Bi atoms is responsible for the observed spin reorientation transition at 90 K. This interaction appears as a result of strong spin orbit coupling on Bi atoms, large magnetic moments on Mn atoms, significant p-d hybridization between Mn and Bi atoms, and it depends strongly on lattice constants (anisotropic Bi-Bi exchange striction). A better agreement with the magneto-optical Kerr measurements at higher energies is obtained. We also present the detailed investigation of the Fermi surface, the de Haas-van Alphen effect, and the x-ray magnetic circular dichroism in MnBi.
Magnetic anisotropic effects and electronic correlations in MnBi ferromagnet
Energy Technology Data Exchange (ETDEWEB)
Antropov, V P [Ames Laboratory; Antonov, V N [Ames Laboratory; Bekenov, L V [Institute of metal Physics; Kutepov, A [Ames Laboratory; Kotliar, G [Rutgers University
2014-08-01
The electronic structure and numerous magnetic properties of MnBi magnetic systems are investigated using local spin density approximation (LSDA) with on-cite Coulomb correlations (LSDA+U) included. We show that the inclusion of Coulomb correlations provides a much better description of equilibrium magnetic moments on Mn atoms as well as the magnetic anisotropy energy behavior with temperature and magneto-optical effects. We found that the inversion of the anisotropic pairwise exchange interaction between Bi atoms is responsible for the observed spin reorientation transition at 90 K. This interaction appears as a result of strong spin orbit coupling on Bi atoms, large magnetic moments on Mn atoms, significant p-d hybridization between Mn and Bi atoms, and it depends strongly on lattice constants (anisotropic Bi-Bi exchange striction). A better agreement with the magneto-optical Kerr measurements at higher energies is obtained. We also present the detailed investigation of the Fermi surface, the de Haas–van Alphen effect, and the x-ray magnetic circular dichroism in MnBi.
Effect of initial stress on reflection at the free surface of anisotropic elastic medium
Indian Academy of Sciences (India)
M D Sharma
2007-12-01
The propagation of plane waves is considered in a general anisotropic elastic medium in the presence of initial stress. The Christoffel equations are solved into a polynomial of degree six. The roots of this polynomial represent the vertical slowness values for the six quasi-waves resulting from the presence of a discontinuity in the medium. Three of these six values are identified with the three quasi-waves traveling in the medium but away from its boundary. Reflection at the free plane surface is studied for partition of energy among the three reflected waves. For post-critical incidence, the reflected waves are inhomogeneous (evanescent) waves. Numerical examples are considered to exhibit the effects of initial stress on the phase direction, attenuation and reflection coefficients of the reflected waves. The phase velocities and energy shares of the reflected waves change significantly with initial stress as well as anisotropic symmetry. The presence of initial stress, however, has a negligible effect on the phase directions of reflected waves.
Effects of anisotropic thermal conduction on wind properties in hot accretion flow
Bu, De-Fu; Wu, Mao-Chun; Yuan, Ye-Fei
2016-06-01
Previous works have clearly shown the existence of winds from black hole hot accretion flow and investigated their detailed properties. In extremely low accretion rate systems, the collisional mean-free path of electrons is large compared with the length-scale of the system, thus thermal conduction is dynamically important. When the magnetic field is present, the thermal conduction is anisotropic and energy transport is along magnetic field lines. In this paper, we study the effects of anisotropic thermal conduction on the wind production in hot accretion flows by performing two-dimensional magnetohydrodynamic simulations. We find that thermal conduction has only moderate effects on the mass flux of wind. But the energy flux of wind can be increased by a factor of ˜10 due to the increase of wind velocity when thermal conduction is included. The increase of wind velocity is because of the increase of driving forces (e.g. gas pressure gradient force and centrifugal force) when thermal conduction is included. This result demonstrates that thermal conduction plays an important role in determining the properties of wind.
Developing a Magnetocaloric Domestic Heat Pump
DEFF Research Database (Denmark)
Bahl, Christian R.H.
2014-01-01
beverage coolers, A/Cs for cars and electronics cooling. Devices for heating have not been extensively demonstrated. Here we consider a promising application of magnetocaloric heat pumps for domestic heating. The task of designing and building such a device is a multidisciplinary one encompassing materials...
High performance magnetocaloric perovskites for magnetic refrigeration
DEFF Research Database (Denmark)
Bahl, Christian R. H.; Velazquez, David; Nielsen, Kaspar K.;
2012-01-01
We have applied mixed valance manganite perovskites as magnetocaloric materials in a magnetic refrigeration device. Relying on exact control of the composition and a technique to process the materials into single adjoined pieces, we have observed temperature spans above 9 K with two materials. Re...
Saving Moore's Law Down To 1 nm Channels With Anisotropic Effective Mass.
Ilatikhameneh, Hesameddin; Ameen, Tarek; Novakovic, Bozidar; Tan, Yaohua; Klimeck, Gerhard; Rahman, Rajib
2016-01-01
Scaling transistors' dimensions has been the thrust for the semiconductor industry in the last four decades. However, scaling channel lengths beyond 10 nm has become exceptionally challenging due to the direct tunneling between source and drain which degrades gate control, switching functionality, and worsens power dissipation. Fortunately, the emergence of novel classes of materials with exotic properties in recent times has opened up new avenues in device design. Here, we show that by using channel materials with an anisotropic effective mass, the channel can be scaled down to 1 nm and still provide an excellent switching performance in phosphorene nanoribbon MOSFETs. To solve power consumption challenge besides dimension scaling in conventional transistors, a novel tunnel transistor is proposed which takes advantage of anisotropic mass in both ON- and OFF-state of the operation. Full-band atomistic quantum transport simulations of phosphorene nanoribbon MOSFETs and TFETs based on the new design have been performed as a proof. PMID:27538849
Vuong, Van Hiep; Do Thi, Kim Anh; Thuan Nguyen, Khac; Le, Van Hong; Nhat Hoang, Nam
2016-10-01
The La-excess alloys La1+δ(Fe0.85Si0.15)13 (δ = 0.06 and 0.09) exhibit large magnetocaloric effect which has been attributed to the occurrence of itinerant-electron metamagnetic transition near the Curie temperature TC. The maximum entropy change -ΔSm was shown to be from 4.5 to 11.5 J/kg K for the applied field variation ΔH from 20 to 70 kOe, respectively. The estimated relative cooling power for ΔH = 70 kOe was 418 J/kg. The alloys show a typical NaZn13-type cubic structure, featuring a doping-induced magnetovolume effect with the increase in TC. Under the applied pressure up to 2 GPa, the TC as deduced from resistance measurements decreased linearly, ΔTC = 113 (for δ = 0.06) and 111 K (for δ = 0.09), together with a corresponding decrease of resistivity, Δρ = 6.1 μΩ m at room temperature for both samples. At a low pressure, the effect of spontaneous magnetostriction on TC caused by applying the pressure appeared to have a similar magnitude to that of the negative magnetovolume effect caused by La-excess doping. In comparison with other stoichiometric La(Fe1-xSix)13 compounds, the pressure in our case was shown to have a smaller influence on TC.
Simulation of field-temperature effects in magnetic media using anisotropic Preisach models
Energy Technology Data Exchange (ETDEWEB)
Adly, A.A. [Cairo Univ., Giza (Egypt); Mayergoyz, I.D. [Univ. of Maryland, College Park, MD (United States). Electrical Engineering Dept.
1998-07-01
Prediction of temperature effects on magnetic properties has always been a topic of wide interest. Studying these effects may be particularly crucial for estimating the reliability of magnetic recording media and/or proper electrical machine core designs when significant working temperature variations are expected. In this paper, simulation of field-temperature effects in magnetic media is proposed by using a 2-D anisotropic Preisach-type hysteresis model. A technique for solving the identification problem of this model is developed. Experimental testing of the proposed model has been carried out on two different thin film hard disk samples. Comparison between measured and computed values indicate that the suggested model can lead to good qualitative, as well as quantitative, simulation results.
Tailoring Effective Media by Mie Resonances of Radially-Anisotropic Cylinders
Directory of Open Access Journals (Sweden)
Henrik Kettunen
2015-05-01
Full Text Available This paper studies constructing advanced effective materials using arrays of circular radially-anisotropic (RA cylinders. Homogenization of such cylinders is considered in an electrodynamic case based on Mie scattering theory. The homogenization procedure consists of two steps. First, we present an effectively isotropic model for individual cylinders, and second, we discuss the modeling of a lattice of RA cylinders. Radial anisotropy brings us extra parameters, which makes it possible to adjust the desired effective response for a fixed frequency. The analysis still remains simple enough, enabling a derivation of analytical design equations. The considered applications include generating artificial magnetism using all-dielectric cylinders, which is currently a very sought-after phenomenon in optical frequencies. We also study how negative refraction is achieved using magnetodielectric RA cylinders.
Influence of Tb substitution on low-field magnetocaloric effect in Gd5Si1.72Ge2.28 alloy
Institute of Scientific and Technical Information of China (English)
DENG Jian-qiu; ZHUANG Ying-hong; WANG Ri-chu; YANG Zhen; XU Bin
2008-01-01
The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd1-xTbx)5Si1.72-Ge2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry and magnetization measurements. The results show that suitable partial substitution of Tb in Gd5Si1.72Ge2.28 compound remains the first-order magnetic-crystallographic transition and enhances the magnetic entropy change, although Tb substitution decreases the Curie temperature (Tc) of the compounds. The magnetic entropy change of (Gd1-xTbx)5Si1.72Ge2.28 alloys retains a large value in the low magnetic field of 1.0 T.The maximum magnetic entropy change for (Gd0.80Tb0.20)5Si1.72Ge2.28 alloy in the magnetic field from 0 to 1.0 T reaches 8.7 J/(kg·K),which is nearly 4 times as large as that of (Gd0.3Dy0.7)5Si4 compound (|△Smax| = 2.24 J/(kg·K), TC = 198 K).
DEFF Research Database (Denmark)
Turcaud, J.A.; Neves Bez, Henrique; Ruiz-Trejo, E.;
2015-01-01
The magnetocaloric performance of La0.67Ca0.27Sr0.06Mn1.05O3 is investigated as a function of the powder grain size and also as a function of decoration of grains with highly conductive silver particulates as a coating layer. We demonstrate that the thermal and electrical conductivities can...... be significantly modified by the Ag-particle coating when the material is examined in sintered pellet form and we compare results with a second manganite composition La0.67Ca0.33MnO3 with significantly smaller grain size. However, we find that this microstructural engineering does not improve the performance...... of the active magnetic regenerator cycle using the silver decorated material in powder form. The regenerator performance is improved by the reduction of the powder grain size of the refrigerant which we attribute to improved thermal management due to increased surface to volume ratio. © 2015 Acta Materialia Inc...
Energy Technology Data Exchange (ETDEWEB)
Triki, M., E-mail: mtriki_fss@yahoo.fr [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, B. P. 1171, 3000 Sfax (Tunisia); Dhahri, R. [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, B. P. 1171, 3000 Sfax (Tunisia); Bekri, M. [Physics Department, Rabigh College of Science and Art, King Abdulaziz University, P.O. Box 344, Rabigh 21911 (Saudi Arabia); Dhahri, E. [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, B. P. 1171, 3000 Sfax (Tunisia); Valente, M.A. [Physics Department (I3N), Aveiro University, Campus Universita rio de Santiago, 3800-193 Aveiro (Portugal)
2011-09-29
Highlights: > Study of magnetocaloric effect on magnetoelectric composites Pr{sub 0.6}Sr{sub 0.4}MnO{sub 3}/BaTiO{sub 3}. > Maximum magnetic entropy and RCP values are not affected for the low BTO content. > A typical second order magnetic transition near T{sub c}. > The calculated magnetic entropy shows a good agreement with experiment results. - Abstract: We have prepared composite materials composed of ferromagnetic and ferroelectric compounds having the general formula (1 - x)(Pr{sub 0.6}Sr{sub 0.4}MnO{sub 3})/x(BaTiO{sub 3}), with x is the molar ratio (x = 0.0, 0.03, 0.05, 0.10 and 0.30) using conventional ceramic double sintering process. We report the structural, magnetic and magnetocaloric properties of all samples. The presence of the two phases of Pr{sub 0.6}Sr{sub 0.4}MnO{sub 3} (PSMO) and BaTiO{sub 3} (BTO) was confirmed by X-ray diffraction (XRD) technique and the structural analysis. Magnetic measurements of magnetization versus temperature and magnetic applied field were performed. The temperature dependence of magnetization reveals that the composite samples show paramagnetic to ferromagnetic phase transition (PM-FM) when the temperature decreases. These samples have the same Curie temperature as the parent PSMO compound (T{sub c} {approx} 273 K). The magnetic entropy change |{Delta}S{sub M}| was deduced from the M(H) data by the Maxwell relation. Close to T{sub c}, a large change in magnetic entropy has been observed in all samples. The maximum value of the magnetic entropy |{Delta}S{sub M}{sup max}| decreases from 2.88 J kg{sup -1} K{sup -1} for x = 0-1.86 J kg{sup -1} K{sup -1} for x = 0.3 for an applied magnetic field of 2 T. At this value of magnetic field the relative cooling power (RCP) decreases equally from 63 J kg{sup -1} for the parent sample to 38.3 J kg{sup -1} for x = 0.3. The temperature dependence of the Landau coefficients has been deduced using the Landau expansion of the magnetic free energy, indicating the second order nature of
Ho, T. A.; Phan, M. H.; Phuc, N. X.; Lam, V. D.; Phan, T. L.; Yu, S. C.
2016-05-01
The Ti-substitution influence on the magnetic and magnetocaloric properties of La0.7Ba0.3Mn1- x Ti x O3 ( x = 0.05 and 0.1) was investigated. Based on Banerjee's criteria and Franco's universal curves, we proved the existence of a second-order magnetic phase transition in the samples. Using the modified Arrott plot method, we determined the critical parameters T C ≈ 245 K, β = 0.374 ± 0.013, γ = 1.228 ± 0.045, and δ = 4.26 ± 0.03 for x = 0.05, and T C ≈ 169 K, β = 0.339 ± 0.001, γ = 1.307 ± 0.003, and δ = 4.78 ± 0.02 for x = 0.1. With these critical values, the predictable scaling behavior of the M( H) data above and below T C proves that the calculated exponents are unambiguous and intrinsic. The values β = 0.374 for x = 0.05 and β = 0.339 for x = 0.1 suggest that the magnetic phase transition of the samples falls into the three-dimensional (3D) Heisenberg and 3D Ising universality classes, respectively, corresponding to short-range ferromagnetic (FM) order due to FM clusters in a wide temperature range even above T C, as confirmed by electron spin resonance studies. In reference to the magnetocaloric effect around T C, the magnetic entropy change reaches maximum values (|ΔSmax|) of about 4 and 3 J kg-1 K-1 for x = 0.05 and 0.1, respectively, for a magnetic field change 50 kOe. Magnetic field dependencies of |ΔSmax| obey a power function |ΔSmax( H)| ∝ H n , where exponent values n = 0.59 and 0.61 for x = 0.05 and 0.1, respectively, were determined from the relation n = 1 + ( β-1)/( β + γ). The difference between the experimental n values and the theoretical value n = 2/3 of the mean field model is due to the presence of short-range FM order in the samples.
Energy Technology Data Exchange (ETDEWEB)
Yamanoi, K.; Yokotani, Y. [Department of Physics, Kyushu University, 6-10-1 Hakozaki, Fukuoka 812-8581 (Japan); Cui, X. [Graduate School of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); Yakata, S. [Department of Information Electronics, Fukuoka Institute of Technology, 3-30-1 Wajiro-higashi, Higashi-ku, Fukuoka 811-0295 (Japan); Kimura, T., E-mail: t-kimu@phys.kyushu-u.ac.jp [Department of Physics, Kyushu University, 6-10-1 Hakozaki, Fukuoka 812-8581 (Japan); Research Center for Quantum Nano-Spin Sciences, Kyushu University, 6-10-1 Hakozaki, Fukuoka 812-8581 (Japan)
2015-12-21
We have investigated the stability for the resonant spin precession under the strong microwave magnetic field by a specially developed detection method using the anisotropic magnetoresistance effect. The electrically separated excitation and detection circuits enable us to investigate the influence of the heating effect and the nonuniform spin dynamics independently. The large detecting current is found to induce the field shift of the resonant spectra because of the Joule heating. From the microwave power dependence, we found that the linear response regime for the standing spin wave is larger than that for the ferromagnetic resonance. This robust characteristic of the standing spin wave is an important advantage for the high power operation of the spin-wave device.
Yamanoi, K.; Yokotani, Y.; Cui, X.; Yakata, S.; Kimura, T.
2015-12-01
We have investigated the stability for the resonant spin precession under the strong microwave magnetic field by a specially developed detection method using the anisotropic magnetoresistance effect. The electrically separated excitation and detection circuits enable us to investigate the influence of the heating effect and the nonuniform spin dynamics independently. The large detecting current is found to induce the field shift of the resonant spectra because of the Joule heating. From the microwave power dependence, we found that the linear response regime for the standing spin wave is larger than that for the ferromagnetic resonance. This robust characteristic of the standing spin wave is an important advantage for the high power operation of the spin-wave device.
Lei, T.; Engelbrecht, K.; Nielsen, K. K.; Neves Bez, H.; Bahl, C. R. H.
2016-09-01
Magnetocaloric materials (MCM) with a first order phase transition (FOPT) usually exhibit a large, although sharp, isothermal entropy change near their Curie temperature, compared to materials with a second order phase transition (SOPT). Experimental results of applying FOPT materials in recent magnetocaloric refrigerators (MCR) demonstrated the great potential for these materials, but a thorough study on the impact of the moderate adiabatic temperature change and strong temperature dependence of the magnetocaloric effect (MCE) is lacking. Besides, comparing active magnetic regenerators (AMR) using FOPT and SOPT materials is also of fundamental interest. We present modeling results of multi-layer AMRs using FOPT and SOPT materials based on a 1D numerical model. First the impact of isothermal entropy change, adiabatic temperature change and shape factor describing the temperature dependence of the MCE are quantified and analyzed by using artificially built magnetocaloric properties. Then, based on measured magnetocaloric properties of La(Fe,Mn,Si)13H y and Gd, an investigation on how to layer typical FOPT and SOPT materials with different temperature spans is carried out. Moreover, the sensitivity of variation in Curie temperature distribution for both groups of AMRs is investigated. Finally, a concept of mixing FOPT and SOPT materials is studied for improving the stability of layered AMRs with existing materials.
Reducing the nucleation barrier in magnetocaloric Heusler alloys by nanoindentation
Niemann, R.; Hahn, S.; Diestel, A.; Backen, A.; Schultz, L.; Nielsch, K.; Wagner, M. F.-X.; Fähler, S.
2016-06-01
Magnetocaloric materials are promising as solid state refrigerants for more efficient and environmentally friendly cooling devices. The highest effects have been observed in materials that exhibit a first-order phase transition. These transformations proceed by nucleation and growth which lead to a hysteresis. Such irreversible processes are undesired since they heat up the material and reduce the efficiency of any cooling application. In this article, we demonstrate an approach to decrease the hysteresis by locally changing the nucleation barrier. We created artificial nucleation sites and analyzed the nucleation and growth processes in their proximity. We use Ni-Mn-Ga, a shape memory alloy that exhibits a martensitic transformation. Epitaxial films serve as a model system, but their high surface-to-volume ratio also allows for a fast heat transfer which is beneficial for a magnetocaloric regenerator geometry. Nanoindentation is used to create a well-defined defect. We quantify the austenite phase fraction in its proximity as a function of temperature which allows us to determine the influence of the defect on the transformation.
The Effect of Anisotropic Viscosity on Cold Fronts in Galaxy Clusters
ZuHone, J A; Markevitch, M; Stone, J M; Biffi, V
2014-01-01
Cold fronts--contact discontinuities in the intracluster medium (ICM) of galaxy clusters--should be disrupted by Kelvin-Helmholtz (K-H) instabilities due to the associated shear velocity. However, many observed cold fronts appear stable. This opens the possibility to place constraints on microphysical mechanisms that stabilize them, such as the ICM viscosity and/or magnetic fields. We performed exploratory high-resolution simulations of cold fronts arising from subsonic gas sloshing in cluster cores using the grid-based Athena MHD code, comparing the effects of isotropic Spitzer and anisotropic Braginskii viscosity (expected in a magnetized plasma). Magnetized simulations with full Braginskii viscosity or isotropic Spitzer viscosity reduced by a factor f ~ 0.1 are both in qualitative agreement with observations in terms of suppressing K-H instabilities. The RMS velocity and turbulence within the sloshing region is only modestly reduced by Braginskii viscosity. We also performed unmagnetized simulations with a...
International Nuclear Information System (INIS)
The influence of a directly adjacent or an anisotropic surrounding medium alters the plasmonic properties of a nanoparticle because it provides a mechanism for symmetry breaking of the scattering. Given the success of ion irradiation induced embedment of rigid metallic nanospheroids into amorphous substrate, it is possible to examine the effect of the silica glass substrate on the plasmonic properties of these embedded nanospheroids. In this work presented here, discrete dipole approximation (DDA) calculations for the Au nanospheroids’ optical properties were performed based on 3–dimensional (3D) configuration extracted from planar SEM micrographs and cross–sectional TEM micrographs of the Au nanospheroids partially embedded in the silica glass, and the well–matched simulations with respect to the experimental measurements could demonstrate the dielectric constant at the near surface of silica glass decreased after Ar–ion irradiation
Geminate ion recombination in anisotropic media. Effects of initial distribution and external field
International Nuclear Information System (INIS)
Recently we presented [Chem. Phys. Lett. 142, 385 (1987)] a method for calculating the diffusion-controlled geminate escape probability of an ion pair in an anisotropic medium. The escape probability depends on both the length and the direction of the initial interion vector, and is reducible to a function of two dimensionless variables describing the overall anisotropy of the medium. In this paper the treatment is extended to include an initial distribution of interion distances and an external field. Inclusion of a field increases the number of independently variable parameters to five: two to describe the anisotropy of the medium and three to describe the intensity and direction of the applied field. It is shown that the effects of including anisotropy are not negligible for the typical case of anthracene and that the slope-to-intercept ratio of the field-dependent escape probability for a spherically averaged distribution depends on the direction of the applied field
Directory of Open Access Journals (Sweden)
Sophia Haussener
2012-01-01
Full Text Available High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct pore-level numerical simulations for determining the morphological and effective heat/mass transport properties of porous ceria, namely: porosity, specific surface area, pore size distribution, extinction coefficient, thermal conductivity, convective heat transfer coefficient, permeability, Dupuit-Forchheimer coefficient, and tortuosity and residence time distributions. Tailored foam designs for enhanced transport properties are examined by means of adjusting morphologies of artificial ceria samples composed of bimodal distributed overlapping transparent spheres in an opaque medium.
Qian, Jing
2016-01-01
We investigate the collective excitation effect in a scheme where three identical Rydberg atoms are arranged in an equilateral triangular lattice. By using a static electric field polarizing the atomic dipoles, the dipole-dipole interactions between two Rydberg atoms are essentially anisotropic and can even disappear in the several special resonance cases. For that fact, we observe collectively enhanced excitation probability of single Rydberg atom in resonant areas in the case of strong blockade, and that of double or triple Rydberg atoms in the case of partial blockade. To give more evidences for this collective excitation enhancement, we study the two-body quantum correlation between three Rydberg atoms, as well as the dependence of the blockade radius on the length of triangle sides, which present a good agreement with the excitation properties.
Anisotropic pressure effects on the charge order transition of (TMTTF){sub 2}X
Energy Technology Data Exchange (ETDEWEB)
Nagasawa, M., E-mail: nagasawa@chiba.dendai.ac.j [Department of Physics, Tokyo Denki University (Japan); Department of Green and Sustainable Chemistry, Tokyo Denki University (Japan); Nagasawa, T. [Department of Green and Sustainable Chemistry, Tokyo Denki University (Japan); Ichimura, K. [Division of Applied Physics, Hokkaido University (Japan); Nomura, K. [Division of Physics, Hokkaido University (Japan)
2010-06-01
We measured the conductivity along the a-direction {sigma}{sub a}(T) of the quasi one-dimensional organic conductor (TMTTF){sub 2}SbF{sub 6} under several anisotropic pressures of uniaxial strains which are parallel and perpendicular to the a-direction. The uniaxial strains were generated by so-called 'Frozen oil method'. It was found that the tendencies of the uniaxial strain dependence of the conductivity and the charge order (CO) transition temperature T{sub CO} are different. According to T{sub CO}, it decreases strongly with increasing uniaxial strain parallel to the a-direction; however, it is almost constant for that perpendicular to the a-direction. We discuss the effects of compressive uniaxial strains on the conductivity and the CO transition of (TMTTF){sub 2}SbF{sub 6}.
Directory of Open Access Journals (Sweden)
Kumar Rajneesh
2012-01-01
Full Text Available The aim of the present paper is to study the wave propagation in anisotropic viscoelastic medium in the context of the theory threephase- lag model of thermoelasticity. It is found that there exist two quasi-longitudinal waves (qP1, qP2 and two transverse waves (qS1, qS2. The governing equations for homogeneous transversely isotropic thermoviscoelastic are reduced as a special case from the considered model. Different characteristics of waves like phase velocity, attenuation coefficient, specific loss and penetration depth are computed from the obtained results. Viscous effect is shown graphically on different resulting quantities for two-phase-lag model and three-phase-lag model of thermoelasticity. Some particular cases of interest are also deduced from the present investigation.
Energy Technology Data Exchange (ETDEWEB)
Kaya, M. [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey); Yildirim, S. [Nanotechnology and Nanomedicine Division, Hacettepe University, Ankara 06800 (Turkey); Yüzüak, E. [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey); Department of Nanotechnology Engineering, Faculty of Engineering, Recep Tayyip Erdogan University, 53100 Rize (Turkey); Dincer, I., E-mail: idincer@eng.ankara.edu.tr [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey); Ellialtioglu, R. [Department of Engineering Physics, Faculty of Engineering Hacettepe University, Ankara 06800 (Turkey); Elerman, Y. [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey)
2014-11-15
The influence of Cu substitution for Mn on magnetic and magnetocaloric properties has been investigated in Ni{sub 50}Mn{sub 34−x}Cu{sub x}In{sub 16} (x=1.3 and 1.6) Heusler alloys by using calorimetric and magnetic measurements. The temperature dependent magnetization measurements and calorimetric studies indicate that martensitic transition temperatures shift to higher temperatures with increasing valence electron concentrations, e/a. The isothermal magnetization curves around the martensitic transition temperatures show a typical metamagnetic behavior. Associated with that, large positive values of magnetic entropy changes around structural transition region were determined by using the Maxwell and Clausius–Clapeyron relations. The maximum magnetic entropy change values were found to be 25.2 and 5.7 J kg{sup −1} K{sup −1} for Ni{sub 50}Mn{sub 34−x}Cu{sub x}In{sub 16} (x=1.3 and 1.6) alloys by Maxwell relation in a magnetic field change of 2 T. In order to understand the limit can be reached for, the magnetic entropy change values recalculated by Clausius–Clapeyron relation. Obtained maximum entropy change values are 22.8 and 16.3 J kg{sup −1} K{sup −1} for Ni{sub 50}Mn{sub 34−x}Cu{sub x}In{sub 16} (x=1.3 and 1.6) alloys by Clausius–Clapeyron relation. - Highlights: • Ni{sub 50}Mn{sub 34−x}Cu{sub x}In{sub 16} alloys are prepared by an arc-melting method. • Structural properties are characterized by XRD, DSC and SEM. • Magnetic entropy change values are estimated by Maxwell and Clausius–Clapeyron equations.
THE EFFECT OF ANISOTROPIC VISCOSITY ON COLD FRONTS IN GALAXY CLUSTERS
International Nuclear Information System (INIS)
Cold fronts—contact discontinuities in the intracluster medium (ICM) of galaxy clusters—should be disrupted by Kelvin-Helmholtz (K-H) instabilities due to the associated shear velocity. However, many observed cold fronts appear stable. This opens the possibility of placing constraints on microphysical mechanisms that stabilize them, such as the ICM viscosity and/or magnetic fields. We performed exploratory high-resolution simulations of cold fronts arising from subsonic gas sloshing in cluster cores using the grid-based Athena MHD code, comparing the effects of isotropic Spitzer and anisotropic Braginskii viscosity (expected in a magnetized plasma). Magnetized simulations with full Braginskii viscosity or isotropic Spitzer viscosity reduced by a factor f ∼ 0.1 are both in qualitative agreement with observations in terms of suppressing K-H instabilities. The rms velocity of turbulence within the sloshing region is only modestly reduced by Braginskii viscosity. We also performed unmagnetized simulations with and without viscosity and find that magnetic fields have a substantial effect on the appearance of the cold fronts, even if the initial field is weak and the viscosity is the same. This suggests that determining the dominant suppression mechanism of a given cold front from X-ray observations (e.g., viscosity or magnetic fields) by comparison with simulations is not straightforward. Finally, we performed simulations including anisotropic thermal conduction, and find that including Braginskii viscosity in these simulations does not significantly affect the evolution of cold fronts; they are rapidly smeared out by thermal conduction, as in the inviscid case
Anisotropic turbulence and zonal jets in rotating flows with a β-effect
Directory of Open Access Journals (Sweden)
B. Galperin
2006-01-01
Full Text Available Numerical studies of small-scale forced, two-dimensional turbulent flows on the surface of a rotating sphere have revealed strong large-scale anisotropization that culminates in the emergence of quasi-steady sets of alternating zonal jets, or zonation. The kinetic energy spectrum of such flows also becomes strongly anisotropic. For the zonal modes, a steep spectral distribution, E(n=CZ (Ω/R2 n-5, is established, where CZ=O(1 is a non-dimensional coefficient, Ω is the angular velocity, and R is the radius of the sphere, respectively. For other, non-zonal modes, the classical, Kolmogorov-Batchelor-Kraichnan, spectral law is preserved. This flow regime, referred to as a zonostrophic regime, appears to have wide applicability to large-scale planetary and terrestrial circulations as long as those are characterized by strong rotation, vertically stable stratification and small Burger numbers. The well-known manifestations of this regime are the banded disks of the outer planets of our Solar System. Relatively less known examples are systems of narrow, subsurface, alternating zonal jets throughout all major oceans discovered in state-of-the-art, eddy-permitting simulations of the general oceanic circulation. Furthermore, laboratory experiments recently conducted using the Coriolis turntable have basically confirmed that the lateral gradient of ''planetary vorticity'' (emulated via the topographic β-effect is the primary cause of the zonation and that the latter is entwined with the development of the strongly anisotropic kinetic energy spectrum that tends to attain the same zonal and non-zonal distributions, −5 and , respectively, in both the slope and the magnitude, as the corresponding spectra in other environmental conditions. The non-dimensional coefficient CZ in the −5 spectral law appears to be invariant, , in a variety of simulated and natural flows. This paper provides a brief review of the zonostrophic regime. The review includes the
Energy Technology Data Exchange (ETDEWEB)
Dincer, I., E-mail: idincer@eng.ankara.edu.tr [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey); Elerman, Y. [Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara (Turkey)
2013-01-15
Magnetocaloric and magnetoresistance properties of SmMn{sub 2-x}Fe{sub x}Ge{sub 2} (x=0.05 and 0.10) and SmMn{sub 2-x}Co{sub x}Ge{sub 2} (x=0.05 and 0.15) compounds have been studied by magnetic and resistance measurements in the temperature range between 30 and 350 K. All compounds exhibit metamagnetic transition from antiferromagnetism to ferromagnetism around the Sm moments ferromagnetic ordering temperature-T{sub Sm} and Mn moments antiferromagnetic ordering temperature-T{sub N1}. The magnetic entropy changes of these compounds are estimated from the Maxwell equation, Maxwell Clausius Clapeyron equation, Landau theory and mean-field theory. The maximum magnetic entropy change values of SmMn{sub 1.90}Fe{sub 0.10}Ge{sub 2} and SmMn{sub 1.85}Co{sub 0.15}Ge{sub 2} compounds are -8.1 J kg{sup -1} K{sup -1} and -5.1 J kg{sup -1} K{sup -1} in a magnetic field change of 5 T, respectively. These compounds show negative magnetoresistance around the magnetic phase transition temperatures. The magnetoresistance value of SmMn{sub 1.95}Fe{sub 0.05}Ge{sub 2} is -23% at T{sub Sm} which is bigger than the magnetoresistance value of SmMn{sub 2}Ge{sub 2} (-15%). - Highlights: Black-Right-Pointing-Pointer Magnetic entropy changes of these compounds are estimated from the Maxwell equation, Maxwell Clausius Clapeyron equation, Landau theory and mean-field theory. Black-Right-Pointing-Pointer Our results exhibit that the Maxwell Clausius Clapeyron equation should be used for compounds that have a first-order phase transition instead of using the Maxwell equation. Black-Right-Pointing-Pointer As a result, in the antiferromagnetic state, the resistance is higher than that in the ferromagnetic state, suggesting that the MR in compounds from the RMn{sub 2}X{sub 2} family may arise on the basis of a spin-valve mechanism.
(Magneto)caloric refrigeration: is there light at the end of the tunnel?
Pecharsky, Vitalij K; Cui, Jun; Johnson, Duane D
2016-08-13
Caloric cooling and heat pumping rely on reversible thermal effects triggered in solids by magnetic, electric or stress fields. In the recent past, there have been several successful demonstrations of using first-order phase transition materials in laboratory cooling devices based on both the giant magnetocaloric and elastocaloric effects. All such materials exhibit non-equilibrium behaviours when driven through phase transformations by corresponding fields. Common wisdom is that non-equilibrium states should be avoided; yet, as we show using a model material exhibiting a giant magnetocaloric effect, non-equilibrium phase-separated states offer a unique opportunity to achieve uncommonly large caloric effects by very small perturbations of the driving field(s).This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'. PMID:27402923
Model anisotropic quantum Hall states
Qiu, R. -Z.; Haldane, F.D.M.; Wan, Xin; Yang, Kun; Yi, Su
2012-01-01
Model quantum Hall states including Laughlin, Moore-Read and Read-Rezayi states are generalized into appropriate anisotropic form. The generalized states are exact zero-energy eigenstates of corresponding anisotropic two- or multi-body Hamiltonians, and explicitly illustrate the existence of geometric degrees of in the fractional quantum Hall effect. These generalized model quantum Hall states can provide a good description of the quantum Hall system with anisotropic interactions. Some numeri...
Shawish, Samir El; CIZELJ Leon; SIMONOVSKI IGOR
2012-01-01
In this work we propose an anisotropic elasto-plastic finite element model to account for various observations in the tensile test experiments on stainless steel specimen. Using Voronoi construction for the grains, grain boundaries and anisotropic Hill’s plastic potential function, we find a clear correlation between the computed average misorientation angle, measuring the change of local crystal orientations, and the applied plastic strain, in agreement with the electron backscatter diffract...
Non—Darcian and Anisotropic Effects on Natural Convection in Horizontal Porous Media Enclosure
Institute of Scientific and Technical Information of China (English)
ZhangJingzhou; SunRenqia
1996-01-01
Natural convection heat transfer in a horizontal enclosure filled with anisotropic porous media,being isothermally heated at bettom and cooled at top while the vertical walls being adiabatic,is numerically studied by applying the Brinkman model-a modified form of Darcy model giving consideratioin to the viscous effect.The results show that:(1)a larger permeability ratio(K*) causes a lower flow intensity in the enclosure and a smaller Nusselt number,all Nusselt numbers approach unity in the limit of K*→∞;a larger thermal conductivity ratio(λ*) causes a stranger distortion of isotherms in the enclosure and a higher flow velocity near the walls,all the Nusselt numbers approach unity in the limit of λ*-→0,the permeability and thermal conductivity ratios generally have opposing effects on the Nusselt number.(2) an increasing Darcy number decreases the flow intensity and heat tansfer rates,which is more significant at a lower permeability ratio.In particular,with K*≤0.25,the Nusselt number for Da=10-3 would differ from that of Darcy flow up to an amount of 30%,an analysis neglecting the non-Darican effect will inevitably be of considerable error.
Energy Technology Data Exchange (ETDEWEB)
Czaja, Paweł, E-mail: p.czaja@imim.pl [Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta Str., 30-059 Krakow (Poland); Maziarz, Wojciech [Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta Str., 30-059 Krakow (Poland); Przewoźnik, Janusz; Kapusta, Czesław [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Department of Solid State Physics, Al. Mickiewicza 30, 30-059 Krakow (Poland); Hawelek, Lukasz [Institute of Non Ferrous Metals, 5 Sowinskiego Str., Gliwice 44-100 (Poland); Chrobak, Artur [A. Chelkowski Institute of Physics, University of Silesia, 4 Uniwersytecka Str., Katowice 40-007 (Poland); Drzymała, Piotr [Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta Str., 30-059 Krakow (Poland); Fitta, Magdalena [The Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, 152 Radzikowskiego Str., 31-342 Krakow (Poland); Kolano-Burian, Aleksandra [Institute of Non Ferrous Metals, 5 Sowinskiego Str., Gliwice 44-100 (Poland)
2014-05-01
The influence of Al substitution for Sn on magnetocaloric properties and exchange bias behavior in Ni{sub 48}Mn{sub 39.5}Sn{sub 12.5−x}Al{sub x} (x=0, 1, 2, 3) melt spun ribbons have been investigated. All the studied ribbons undergo a martensitic and reverse transformation. At low temperature martensite region, below 100 K, the alloys exhibit exchange bias effect, which appears to enhance with the increase of Al concentration. The loop shift difference (ΔH{sub E}) of up to 7960 A m{sup −1} is recorded between the ribbon containing no Al and the ribbon with x=3. The presence of exchange bias behavior in these samples is attributed to the coexistence of antiferromagnetic and ferromagnetic exchange interactions. The magnetic entropy change and refrigerant capacity are evaluated for the ribbons studied around both the structural and magnetic transformations under the applied magnetic field induction of 2 T. The maximum entropy change around the magnetic transition and around the structural transition is reported for the Ni{sub 48}Mn{sub 39.5}Sn{sub 12.5} ribbon, and the entropy values amount to 1.8 and 7.8 J kg{sup −1} K{sup −1}, respectively. - Highlights: • Ni{sub 48}Mn{sub 39.5}Sn{sub 12.5−x}Al{sub x} (x=0, 1, 2, 3) melt spun ribbons are found to show exchange bias (EB) effect. • The Al for Sn substitution appears to enhance EB. • Around A{sub s} the magnetic field induces the RMT giving rise to the inverse MCE. • The highest ΔS{sub M} at H= 2 T is observed for the Ni{sub 48}Mn{sub 39.5}Sn{sub 12.5} ribbon.
Negara, Ardiansyah
2015-03-04
Numerical investigations of two-phase flows in anisotropic porous media have been conducted. In the flow model, the permeability has been considered as a full tensor and is implemented in the numerical scheme using the multipoint flux approximation within the framework of finite difference method. In addition, the experimenting pressure field approach is used to obtain the solution of the pressure field, which makes the matrix of coefficient of the global system easily constructed. A number of numerical experiments on the flow of two-phase system in two-dimensional porous medium domain are presented. In this work, the gravity is included in the model to capture the possible buoyancy-driven effects due to density differences between the two phases. Different anisotropy scenarios have been considered. From the numerical results, interesting patterns of the flow, pressure, and saturation fields emerge, which are significantly influenced by the anisotropy of the absolute permeability field. It is found that the two-phase system moves along the principal direction of anisotropy. Furthermore, the effects of anisotropy orientation on the flow rates and the cross flow index are also discussed in the paper.
de Santanna, Y. V. B.; de Melo, M. A. C.; Santos, I. A.; Coelho, A. A.; Gama, S.; Cótica, L. F.
2008-11-01
In this paper, structural, microstrucutural and magnetocaloric properties of Ni 2.18Mn 0.82Ga alloys submitted to high-energy ball milling are reported. A 7-layered orthorhombic martensitic ( Pnnm) phase was detected in post-milling annealed samples, which reached a microstrucuture composed predominantly by nanograins. The magnetocaloric effect is strongly weakened in comparison with as-cast samples of similar composition. This effect can be attributed to the absence of the mesoscale twin-related martensitic variants in the nanostructurated powders. However, post-milled samples annealed at 1123 K for 4 h present relative cooling powers as high as those observed for manganites. Therefore, these materials can be considered as potential candidates for use as regenerators in prototypal magnetic refrigerators.
Some Aspects of Scaling and Universality in Magnetocaloric Materials
DEFF Research Database (Denmark)
Smith, Anders; Nielsen, Kaspar Kirstein; Bahl, Christian R.H.
2014-01-01
order phase transition within the context of critical scaling theory. In the critical region the isothermal entropy change will exhibit universal scaling exponents. However, this is only true close to Tc and for small fields; we show that for finite fields the scaling exponents in general become field...... dependent, even at Tc. Furthermore, the scaling exponents at finite fields are not universal: Two models with the same critical exponents can exhibit markedly different scaling behaviour even at relatively low fields. Turning to the adiabatic temperature change, we argue that it is not determined......The magnetocaloric effect of a magnetic material is characterized by two quantities, the isothermal entropy change and the adiabatic temperature change, both of which are functions of temperature and applied magnetic field. We discuss the scaling properties of these quantities close to a second...
International Nuclear Information System (INIS)
Full text: In this paper, is a study of the transport properties in anisotropic polycrystalline superconducting. The presence of certain order of orientation of grains in polycrystalline superconducting (Bi,Pb)2 Sr2 Ca2 Cu3 O10+delta, is modeled by introducing a probability of orientation, gamma factor. In addition, is included in the model the concentration c, which characterize the contribution of porosity to the decrease in the conductivity of the Crystal, transparent. Assumes that pores and pimples are ellipsoid flattened with similar dimensions and takes into account the values of conductivity of beads in each direction. The calculation is based on the application of a generalization of the approximation of the effective way to the study of heterogeneous media, which is called coherent potential approximation (APC). The results are compared with an empirical model developed recently for samples of YBa2 Cu3 O7-delta (YBCO) which enriches its employment and applied to ceramic superconducting in general. (author)
Transverse anisotropic magnetoresistance effects in pseudo-single-crystal γ'-Fe4N thin films
Kabara, Kazuki; Tsunoda, Masakiyo; Kokado, Satoshi
2016-05-01
Transverse anisotropic magnetoresistance (AMR) effects, for which magnetization is rotated in an orthogonal plane to the current direction, were investigated at various temperatures, in order to clarify the structural transformation from a cubic to a tetragonal symmetry in a pseudo-single-crystal Fe4N film, which is predicted from the usual in-plane AMR measurements by the theory taking into account the spin-orbit interaction and crystal field splitting of 3d bands. According to a phenomenological theory of AMR, which derives only from the crystal symmetry, a cos 2θ component ( C2 tr ) exists in transverse AMR curves for a tetragonal system but does not for a cubic system. In the Fe4N film, the C2 tr shows a positive small value (0.12%) from 300 K to 50 K. However, the C2 t r increases to negative value below 50 K and reaches to -2% at 5 K. The drastic increasing of the C2 tr demonstrates the structural transformation from a cubic to a tetragonal symmetry below 50 K in the Fe4N film. In addition, the out-of-plane and in-plane lattice constants (c and a) were precisely determined with X-ray diffraction at room temperature using the Nelson-Riely function. As a result, the positive small C2 t r above 50 K is attributed to a slightly distorted Fe4N lattice (c/a = 1.002).
Directory of Open Access Journals (Sweden)
Zhao-Xia Tong
2013-01-01
Full Text Available The reliability of discrete element method (DEM numerical simulations is significantly dependent on the particle-scale parameters and boundary conditions. To verify the DEM models, two series of biaxial compression tests on ellipse-shaped steel rods are used. The comparisons on the stress-strain relationship, strength, and deformation pattern of experiments and simulations indicate that the DEM models are able to capture the key macro- and micromechanical behavior of inherently anisotropic granular materials with high fidelity. By using the validated DEM models, the boundary effects on the macrodeformation, strain localization, and nonuniformity of stress distribution inside the specimens are investigated using two rigid boundaries and one flexible boundary. The results demonstrate that the boundary condition plays a significant role on the stress-strain relationship and strength of granular materials with inherent fabric anisotropy if the stresses are calculated by the force applied on the wall. However, the responses of the particle assembly measured inside the specimens are almost the same with little influence from the boundary conditions. The peak friction angle obtained from the compression tests with flexible boundary represents the real friction angle of particle assembly. Due to the weak lateral constraints, the degree of stress nonuniformity under flexible boundary is higher than that under rigid boundary.
Preliminary Analysis of a Fully Solid State Magnetocaloric Refrigeration
Energy Technology Data Exchange (ETDEWEB)
Abdelaziz, Omar [ORNL
2016-01-01
Magnetocaloric refrigeration is an alternative refrigeration technology with significant potential energy savings compared to conventional vapor compression refrigeration technology. Most of the reported active magnetic regenerator (AMR) systems that operate based on the magnetocaloric effect use heat transfer fluid to exchange heat, which results in complicated mechanical subsystems and components such as rotating valves and hydraulic pumps. In this paper, we propose an alternative mechanism for heat transfer between the AMR and the heat source/sink. High-conductivity moving rods/sheets (e.g. copper, brass, iron, graphite, aluminum or composite structures from these) are utilized instead of heat transfer fluid significantly enhancing the heat transfer rate hence cooling/heating capacity. A one-dimensional model is developed to study the solid state AMR. In this model, the heat exchange between the solid-solid interfaces is modeled via a contact conductance, which depends on the interface apparent pressure, material hardness, thermal conductivity, surface roughness, surface slope between the interfaces, and material filled in the gap between the interfaces. Due to the tremendous impact of the heat exchange on the AMR cycle performance, a sensitivity analysis is conducted employing a response surface method, in which the apparent pressure, effective surface roughness and grease thermal conductivity are the uncertainty factors. COP and refrigeration capacity are presented as the response in the sensitivity analysis to reveal the important factors influencing the fully solid state AMR and optimize the solid state AMR efficiency. The performances of fully solid state AMR and traditional AMR are also compared and discussed in present work. The results of this study will provide general guidelines for designing high performance solid state AMR systems.
Energy Technology Data Exchange (ETDEWEB)
Giri, S.K. [Department of Physics, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India); Dasgupta, Papri; Poddar, A. [Experimental Condensed Matter Physics Division, Saha Institute of Nuclear Physics, West Bengal (India); Nath, T.K., E-mail: tnath@phy.iitkgp.ernet.in [Department of Physics, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India)
2015-05-15
Graphical abstract: ΔS{sub M} vs. T plots of nano (left) and bulk (right) samples at different magnetic fields. - Highlights: • Bulk to nano show first order FM → PM phase transition at low magnetic field. • Bulk sample exhibits normal and inverse MCE around T{sub C} and after T{sub g}, respectively. • The value of ΔS{sub M} at T{sub C} is almost three times larger than at T{sub g}. • The value of ΔS{sub M} also decreases with reduction of particles sizes. • The bulk sample also exhibits a large RCP of 43.5 J/kg for a magnetic field of 1 T. - Abstract: Magnetic and magnetocaloric properties of Sm{sub 0.35}Pr{sub 0.15}Sr{sub 0.5}MnO{sub 3} polycrystalline manganite (bulk and nanometric samples) are investigated in detail. It has been observed that all the particle sizes (bulk to nano) show first order ferromagnetic → paramagnetic phase transition at low magnetic field. Ferromagnetic transition temperature also decreases with decreasing the particle size. This suggests that ferromagnetism is weakened and the first order magnetic phase transition is softened. We have investigated the magnetocaloric effect (MCE) of both bulk and nanometric samples around their spin glass-like transition temperature, T{sub g} and Curie temperature, T{sub C}. It has been found that bulk sample exhibits both normal (i.e., negative ΔS{sub M}) and inverse (i.e., positive ΔS{sub M}) MCE around T{sub C} and after T{sub g}, respectively. The value of ΔS{sub M} (+3.17 J kg{sup −1} K{sup −1}) at T{sub C} is almost three times larger than at T{sub g} (ΔS{sub M} = −0.52 J kg{sup −1} K{sup −1}) for a magnetic field change of 7 T. The bulk sample also exhibits a large relative cooling power (RCP) of 43.5 J/kg for a magnetic field of 1 T. The corresponding adiabatic temperature change of bulk sample is observed to be ∼1.5 K for a magnetic field change of 3 T. The value of ΔS{sub M} also decreases with reduction of particles sizes. The temperature width of ΔS{sub M
Molecular anisotropic magnetoresistance
Otte, Fabian; Heinze, Stefan; Mokrousov, Yuriy
2015-12-01
Using density functional theory calculations, we demonstrate that the effect of anisotropic magnetoresistance (AMR) can be enhanced by orders of magnitude with respect to conventional bulk ferromagnets in junctions containing molecules sandwiched between ferromagnetic leads. We study ballistic transport in metal-benzene complexes contacted by 3 d transition-metal wires. We show that a gigantic AMR can arise from spin-orbit coupling effects in the leads, drastically enhanced by orbital-symmetry filtering properties of the molecules. We further discuss how this molecular anisotropic magnetoresistance (MAMR) can be tuned by the proper choice of materials and their electronic properties.
Florkowski, W.; Maj, R.
The recently introduced approach describing coupled quark and gluon anisotropic fluids is generalized to include explicitly the transitions between quarks and gluons. We study the effects of such processes on the thermalization rate of anisotropic systems. We find that the quark-gluon transitions may enhance the overall thermalization rate in the cases where the initial momentum anisotropies correspond to mixed oblate-prolate or prolate configurations. On the other hand, no effect on the thermalization rate is found in the case of oblate configurations. The observed regularities are connected with the late-time behavior of the analyzed systems which is described either by the exponential decay or the power law.
Florkowski, Wojciech
2013-01-01
The recently introduced approach describing coupled quark and gluon anisotropic fluids is generalized to include explicitly the transitions between quarks and gluons. We study the effects of such processes on the thermalization rate of anisotropic systems. We find that the quark-gluon transitions may enhance the overall thermalization rate in the cases where the initial momentum anisotropies correspond to mixed oblate-prolate or prolate configurations. On the other hand, no effect on the thermalization rate is found in the case of oblate configurations. The observed regularities are connected with the late-time behavior of the analyzed systems which is described either by the exponential decay or the power law.
The influence of non-magnetocaloric properties on the AMR performance
DEFF Research Database (Denmark)
Nielsen, Kaspar Kirstein; Bahl, Christian; Smith, Anders;
2012-01-01
The performance of Active Magnetic Regenerators (AMR) does not depend solely on the magnetocaloric effect of their constituents. Rather, it depends on several additional parameters, including, magnetic field, geometry (hydraulic diameter, cross-sectional area, regenerator length etc.), thermal...... properties (conductivity, specific heat and mass density) and operating parameters (utilization, frequency, number of transfer units etc.). In this paper we focus on the influence of three parameters on regenerator performance: 1) Solid thermal conductivity, 2) magnetostatic demagnetization and 3) flow...
Averaging anisotropic cosmologies
International Nuclear Information System (INIS)
We examine the effects of spatial inhomogeneities on irrotational anisotropic cosmologies by looking at the average properties of anisotropic pressure-free models. Adopting the Buchert scheme, we recast the averaged scalar equations in Bianchi-type form and close the standard system by introducing a propagation formula for the average shear magnitude. We then investigate the evolution of anisotropic average vacuum models and those filled with pressureless matter. In the latter case we show that the backreaction effects can modify the familiar Kasner-like singularity and potentially remove Mixmaster-type oscillations. The presence of nonzero average shear in our equations also allows us to examine the constraints that a phase of backreaction-driven accelerated expansion might put on the anisotropy of the averaged domain. We close by assessing the status of these and other attempts to define and calculate 'average' spacetime behaviour in general relativity
Evaluating the Poroelastic Effect on Anisotropic, Organic-Rich, Mudstone Systems
Suarez-Rivera, Roberto; Fjær, Erling
2013-05-01
Understanding the poroelastic effect on anisotropic organic-rich mudstones is of high interest and value for evaluating coupled effects of rock deformation and pore pressure, during drilling, completion and production operations in the oilfield. These applications include modeling and prevention of time-dependent wellbore failure, improved predictions of fracture initiation during hydraulic fracturing operations (Suarez-Rivera et al. Presented at the Canadian Unconventional Resources Conference held in Calgary, Alberta, Canada, 15-17 November 2011. CSUG/SPE 146998 2011), improved understanding of the evolution of pore pressure during basin development, including subsidence and uplift, and the equilibrated effective in situ stress (Charlez, Rock mechanics, vol 2 1997; Katahara and Corrigan, Pressure regimes in sedimentary basins and their prediction: AAPG Memoir, vol 76, pp 73-78 2002; Fjær et al. Petroleum related rock mechanics. 2nd edn 2008). In isotropic rocks, the coupled poro-elastic deformations of the solid framework and the pore fluids are controlled by the Biot and Skempton coefficients. These are the two fundamental properties that relate the rock framework and fluid compressibility and define the magnitude of the poroelastic effect. In transversely isotropic rocks, one desires to understand the variability of these coefficients along the directions parallel and longitudinal to the principal directions of material symmetry (usually the direction of bedding). These types of measurements are complex and uncommon in low-porosity rocks, and particularly problematic and scarce in tight shales. In this paper, we discuss a methodology for evaluating the Biot's coefficient, its variability along the directions parallel and perpendicular to bedding as a function of stress, and the homogenized Skempton coefficient, also as a function of stress. We also predict the pore pressure change that results during undrained compression. Most importantly, we provide values
Starinshak, David P.; Smith, Nathan D.; Wilson, Jeffrey D.
2008-01-01
The electromagnetic effects of conventional dielectrics, anisotropic dielectrics, and metamaterials were modeled in a terahertz-frequency folded-waveguide slow-wave circuit. Results of attempts to utilize these materials to increase efficiency are presented.
Quasiparticle anisotropic hydrodynamics
Alqahtani, Mubarak
2016-01-01
We study an azimuthally-symmetric boost-invariant quark-gluon plasma using quasiparticle anisotropic hydrodynamics including the effects of both shear and bulk viscosities. We compare results obtained using the quasiparticle method with the standard anisotropic hydrodynamics and viscous hydrodynamics. We consider the predictions of the three methods for the differential particle spectra and mean transverse momentum. We find that the three methods agree for small shear viscosity to entropy density ratio, $\\eta/s$, but show differences at large $\\eta/s$. Additionally, we find that the standard anisotropic hydrodynamics method shows suppressed production at low transverse-momentum compared to the other two methods, and the bulk-viscous correction can drive the primordial particle spectra negative at large $p_T$ in viscous hydrodynamics.
Energy Technology Data Exchange (ETDEWEB)
Liu, Jun, E-mail: junliu@illinois.edu; Choi, Gyung-Min; Cahill, David G. [Department of Materials Science and Engineering and Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801 (United States)
2014-12-21
We use pump-probe metrology based on the magneto-optic Kerr effect to measure the anisotropic thermal conductivity of (001)-oriented MoS{sub 2} crystals. A ≈20 nm thick CoPt multilayer with perpendicular magnetization serves as the heater and thermometer in the experiment. The low thermal conductivity and small thickness of the CoPt transducer improve the sensitivity of the measurement to lateral heat flow in the MoS{sub 2} crystal. The thermal conductivity of MoS{sub 2} is highly anisotropic with basal-plane thermal conductivity varying between 85–110 W m{sup -1} K{sup -1} as a function of laser spot size. The basal-plane thermal conductivity is a factor of ≈50 larger than the c-axis thermal conductivity, 2.0±0.3 W m{sup -1} K{sup -1}.
Pressure-induced changes in the magnetic and magnetocaloric properties of RMn2Ge2 (R=Sm,Gd)
Kumar, Pramod; Suresh, K. G.; Nigam, A. K.; Magnus, A.; Coelho, A. A.; Gama, S.
2008-06-01
We have studied the variation of magnetic and magnetocaloric properties of polycrystalline compounds SmMn2Ge2 and GdMn2Ge2 as a function of applied hydrostatic pressure. The magnetic transition temperatures are found to change considerably with pressure. The temperature regime of existence of antiferromagnetic (AFM) ordering is found to increase with pressure, in both the compounds. In SmMn2Ge2 , the sign of the magnetocaloric effect at the low-temperature ferromagnetic (FM)-AFM transition changes with pressure. The isothermal magnetic entropy change in this compound is found to increase by about 20 times as the pressure is increased from the ambient value to 6.8 kbar. Effect of pressure in GdMn2Ge2 is less compared to that in SmMn2Ge2 . The variations in the magnetic and magnetocaloric properties are attributed to the changes in the magnetic state of the Mn sublattice under pressure. The difference in R-Mn coupling in Sm and Gd compounds is also found to play a role in determining the magnetic and magnetocaloric properties, both at ambient as well as under applied pressures.
Effects of geometrical anisotropy on failure in a plastically anisotropic metal
DEFF Research Database (Denmark)
Legarth, Brian Nyvang
2005-01-01
Failure by debonding of rigid inclusions in a metal-matrix is numerically analyzed within a unit cell approach. Finite strain analyses are conducted under plane strain conditions assuming a plastically anisotropic matrix material. Focus is given to geometrical anisotropy induced by different aspect...
Institute of Scientific and Technical Information of China (English)
WU Ping; WANG Fengping; QIU Hong; PAN Liqing; TIAN Yue
2003-01-01
Ni83Fe17 films with a thickness of about 100 nm were deposited on thermal oxidized silicon substrates at ambient temperature, 240, 350, and 410℃ by DC magnetron sputtering. The deposition rate was about 0.11 nm/s. The as-deposited films were annealed at 450, 550, and 650℃, respectively, in a vacuum lower than 3 x 10-3 Pa for 1 h. The Ni83Fe17 films mainly grow with a crystalline orientation of [111] in the direction of the film growth. With the annealing temperature increasing, the [ 111] orientation enhances. For films deposited at all four different temperatures, the significant improvement on anisotropic magnetoresistance occurs at the annealing temperature higher than 550℃. But for films deposited at ambient temperatures and 240℃, the anisotropic magnetoresistance can only rise to about 1% after 650℃ annealing. For films deposited at 350℃ and 410℃, the anisotropic magnetoresistance rises to about 3.8% after 650℃ annealing. The atomic force microscopy (AFM) observation shows a significant increase in grain size of the film deposited at 350℃ atter 650℃annealing. The decrease in resistivity and the increase in anisotropic magnetoresistance are caused by the decrease in point defects, the increase in grain size, and the improvement in lattice structure integrity of the films.
Magnetocaloric Properties Response in High-Speed Melt-Spun La-Ce-Fe-Si Ribbons
Hou, Xueling; Han, Ning; Xue, Yun; Lu, Qianqian; Wang, Xiaochen; Phan, Manh-Huong
2016-10-01
The structure and magnetocaloric properties of La-Ce-Fe-Si alloys have been studied. The samples were prepared by melt spinning, the surface speed of the Cu wheel being 55 m/s. The as-spun ribbons were subsequently annealed at 1273 K for different times (10 min-1 h) and then quenched to room temperature. When the annealing time was 20 min, on a 1.5-T applied magnetic field, the maximum magnetic entropy change (Δ S M) of the ribbons reached values of 33.8 J/kg K at the Curie temperature of T C ˜ 182 K. When the annealing time was longer than 20 min, the maximum magnetic entropy change (|Δ S M,Max|) tended to decrease while the T C remained almost unchanged. In the annealing process, La/Ce located at grain boundaries was easily oxidized on the ribbon surface. The presence of large grain sizes and La2O3 or LaO were shown to degrade the magnetocaloric properties. On the other hand, the substitution of Ce for La improved the magnetocaloric effect of La-Fe-Si compounds, which is of practical importance for magnetic refrigeration.
Magnetocaloric Properties Response in High-Speed Melt-Spun La-Ce-Fe-Si Ribbons
Hou, Xueling; Han, Ning; Xue, Yun; Lu, Qianqian; Wang, Xiaochen; Phan, Manh-Huong
2016-06-01
The structure and magnetocaloric properties of La-Ce-Fe-Si alloys have been studied. The samples were prepared by melt spinning, the surface speed of the Cu wheel being 55 m/s. The as-spun ribbons were subsequently annealed at 1273 K for different times (10 min-1 h) and then quenched to room temperature. When the annealing time was 20 min, on a 1.5-T applied magnetic field, the maximum magnetic entropy change (ΔS M) of the ribbons reached values of 33.8 J/kg K at the Curie temperature of T C ˜ 182 K. When the annealing time was longer than 20 min, the maximum magnetic entropy change (|ΔS M,Max|) tended to decrease while the T C remained almost unchanged. In the annealing process, La/Ce located at grain boundaries was easily oxidized on the ribbon surface. The presence of large grain sizes and La2O3 or LaO were shown to degrade the magnetocaloric properties. On the other hand, the substitution of Ce for La improved the magnetocaloric effect of La-Fe-Si compounds, which is of practical importance for magnetic refrigeration.
Chaudhary, V.; Ramanujan, R. V.
2015-08-01
Earth-abundant, low-cost, and rare earth free magnetocaloric nanomaterials have attracted considerable attention for affordable, ‘green’, energy-efficient thermal management applications. Hence, we investigated the magnetocaloric properties and critical behavior of (Fe70Ni30)92Mn8 alloy nanoparticles. A near room temperature magnetocaloric effect, with a high relative cooling power (RCP), was obtained by alloying FeNi with Mn and fcc (γ) phase stabilization. The Curie temperature (T C) of the γ- phase was 40 K less than that of the T C of the bcc (α) phase. For a field change of 5 T, the RCP for the α- and γ- phase was found to be 507 J kg-1 and 466 J kg-1, respectively; these values are higher than those for Gd nanoparticles. The RCP exhibited a power law relationship with magnetic field H. Critical exponents values of δ = 4.71, β = 0.319 and γ = 1.195 were obtained, close to those obtained from the short range order 3D-Heisenberg model. Our results demonstrate the feasibility of developing high RCP, low-cost, rare earth free magnetocaloric nanoparticles for near room temperature applications.
Anisotropic universe with anisotropic sources
Energy Technology Data Exchange (ETDEWEB)
Aluri, Pavan K.; Panda, Sukanta; Sharma, Manabendra; Thakur, Snigdha, E-mail: aluri@iucaa.ernet.in, E-mail: sukanta@iiserb.ac.in, E-mail: manabendra@iiserb.ac.in, E-mail: snigdha@iiserb.ac.in [Department of Physics, IISER Bhopal, Bhopal - 462023 (India)
2013-12-01
We analyze the state space of a Bianchi-I universe with anisotropic sources. Here we consider an extended state space which includes null geodesics in this background. The evolution equations for all the state observables are derived. Dynamical systems approach is used to study the evolution of these equations. The asymptotic stable fixed points for all the evolution equations are found. We also check our analytic results with numerical analysis of these dynamical equations. The evolution of the state observables are studied both in cosmic time and using a dimensionless time variable. Then we repeat the same analysis with a more realistic scenario, adding the isotropic (dust like dark) matter and a cosmological constant (dark energy) to our anisotropic sources, to study their co-evolution. The universe now approaches a de Sitter space asymptotically dominated by the cosmological constant. The cosmic microwave background anisotropy maps due to shear are also generated in this scenario, assuming that the universe contains anisotropic matter along with the usual (dark) matter and vacuum (dark) energy since decoupling. We find that they contribute dominantly to the CMB quadrupole. We also constrain the current level of anisotropy and also search for any cosmic preferred axis present in the data. We use the Union 2 Supernovae data to this extent. An anisotropy axis close to the mirror symmetry axis seen in the cosmic microwave background data from Planck probe is found.
Material Induced Anisotropic Damage
Niazi, M.S.; Wisselink, H.H.; Meinders, V.T.; Boogaard, van den A.H.; Hora, P.
2012-01-01
The anisotropy in damage can be driven by two different phenomena; anisotropic defor-mation state named Load Induced Anisotropic Damage (LIAD) and anisotropic (shape and/or distribution) second phase particles named Material Induced Anisotropic Damage (MIAD). Most anisotropic damage models are based
Energy Technology Data Exchange (ETDEWEB)
Phan, The-Long; Jung, C. U.; Lee, B. W., E-mail: bwlee@hufs.ac.kr [Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies, Yongin 449-791 (Korea, Republic of); Ho, T. A.; Manh, T. V. [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Dang, N. T. [Institute of Research and Development, Duy Tan University, Da Nang (Viet Nam); Thanh, T. D. [Institute of Materials Science, Vietnam Academy of Science and Technology, Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam)
2015-10-14
We prepared orthorhombic La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} samples (x = 0, 0.04, 0.06, and 0.08) by conventional solid-state reaction and then studied their magnetic properties and magnetocaloric (MC) effect based on magnetization versus temperature and magnetic-field measurements, M(T, H). The experimental results revealed that an x increase in La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} reduced the ferromagnetic-paramagnetic transition temperature (T{sub C}) from 260 K (for x = 0) to ∼126 K (for x = 0.08). Around the T{sub C}, maximum magnetic-entropy changes for a magnetic-field variation interval H = 50 kOe are about 10.7, 8.5, 7.4, and 5.8 J·kg{sup −1}·K{sup −1} for x = 0, 0.04, 0.06, and 0.08, respectively, corresponding to refrigerant capacities RC = 250–280 J·kg{sup −1}. These values are comparable to those of some conventional MC materials, revealing the applicability of La{sub 0.7−x}Y{sub x}Ca{sub 0.3}MnO{sub 3} in magnetic refrigeration. Using the Arrott method and scaling hypothesis as analyzing high-field M(H, T) data, and the universal-curve construction of the magnetic entropy change, we found a magnetic-phase separation. While the samples x = 0−0.06 exhibit a first-order magnetic phase transition, x = 0.08 exhibits the crossover of the first-to-second-order phase transformation (with its critical-exponent values close to those expected for the tricritical mean-field theory) and has the presence of ferromagnetic clusters even above the T{sub C}. Such the variations in the magnetism and MC effect are related to the changes in structural parameters caused by the Y substitution for La because Y doping does not change the concentration ratio of Mn{sup 3+}/Mn{sup 4+}.
Effect of Initial Stress on a Fiber-Reinforced Anisotropic Thermoelastic Thick Plate
Abbas, Ibrahim A.; Abd-alla, Abo-el-nour N.
2011-05-01
The two-dimensional problem of generalized thermoelasticity for a fiber-reinforced anisotropic thick plate under initial stress is studied in the context of the Lord and Shulman theory. The upper surface of the plate is thermally insulated with prescribed surface loading while the lower surface of the plate rests on a rigid foundation and temperature. The problem is solved numerically using a finite element method. Numerical results for the temperature distribution, and the displacement and stress components are given and illustrated graphically. It is found from the graphs that the initial stress significantly influences the variations of field quantities. The results obtained in this paper may offer a theoretical basis and meaningful suggestions for the design of various fiber-reinforced anisotropic thermoelastic elements under loading to meet special engineering requirements.
New effect of ionizing irradiation: anisotropic expansion of a peptide crystal
Energy Technology Data Exchange (ETDEWEB)
Kuroda, S.; Kurita, Y.; Miyagawa, I.
1985-10-01
Expansion of crystals resulting from X irradiation was studied in the case of a peptide, N-acetyl-D, L-alanine. This expansion was discovered by examining several irradiated organic solids for possible expansion, which was suggested by the recent observation of crystal imperfections in another peptide. The expansion, which occurred anisotropically along the c axis, was found to depend on dose, the maximum being as large as 20% when assisted by heat treatment.
Energy Technology Data Exchange (ETDEWEB)
Phan, The-Long; Ho, T.A. [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Thang, P.D. [Faculty of Engineering Physics and Nanotechnology, VNU-University of Engineering and Technology, Xuan Thuy, Cau Giay, Hanoi (Viet Nam); Tran, Q.T. [Center for Science and Technology Communication, Ministry of Science and Technology, 113 Tran Duy Hung, Hanoi (Viet Nam); Thanh, T.D.; Phuc, N.X. [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi (Viet Nam); Phan, M.H. [Department of Physics, University of South Florida, Tampa, FL 33620 (United States); Huy, B.T. [Department of Chemistry, Changwon National University, Changwon 641-773 (Korea, Republic of); Yu, S.C., E-mail: scyu@chungbuk.ac.kr [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)
2014-12-05
Highlights: • Tricritical point in Y-doped Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3} manganites. • A large magnetic-entropy change. • Magnetic inhomogeneity and phase separation. - Abstract: We have determined the values of critical exponents of two polycrystalline samples (Nd{sub 1−x}Y{sub x}){sub 0.7}Sr{sub 0.3}MnO{sub 3} (x = 0 and 0.07) from the magnetization data versus temperature and magnetic field, M(H, T), to learn about their magnetic and magnetocaloric (MC) properties. The results reveal the samples exhibiting the crossover of first-order and second-order phase transitions, where the exponent values β = 0.271 and γ = 0.922 for x = 0, and β = 0.234–0.236 and γ = 1.044–1.063 for x = 0.07 determined by using modified Arrott plots and static-scaling hypothesis are close to those expected for the tricritical mean-field theory (β = 0.25 and γ = 1.0). Particularly, the T{sub C} of x = 0 and 0.07 can be any value in the temperature ranges of 240–255 K and 170–278 K, respectively, depending on the magnitude of applied magnetic field and determination techniques. Around the T{sub C}, studying the MC effect of the samples has revealed a large magnetic-entropy change (ΔS{sub m}) up to ∼8 J/kg K for the applied field interval ΔH = 50 kOe, corresponding to refrigerant capacity values of 200–245 J/kg. These phenomena are related to the crossover nature and the persisting of FM/anti-FM interactions even above the T{sub C}, as further confirmed by electron-spin-resonance data, Curie–Weiss law-based analyses, and an exponential parameter characteristic of magnetic order n = dLn|ΔS{sub m}|/dLnH.
Molecular anisotropic magnetoresistance
Otte, Fabian; Heinze, Stefan; Mokrousov, Yuriy
2015-01-01
Using density functional theory calculations, we demonstrate that the effect of anisotropic magnetoresistance (AMR) can be enhanced by orders of magnitude with respect to conventional bulk ferromagnets in junctions containing molecules sandwiched between ferromagnetic leads. We study ballistic transport in metal-benzene complexes contacted by $3d$ transition-metal wires. We show that the gigantic AMR can arise from spin-orbit coupling effects in the leads, drastically enhanced by orbital-symm...
Anisotropic Inflation with General Potentials
Shi, Jiaming; Qiu, Taotao
2015-01-01
Anomalies in recent observational data indicate that there might be some "anisotropic hair" generated in an inflation period. To obtain general information about the effects of this anisotropic hair to inflation models, we studied anisotropic inflation models that involve one vector and one scalar using several types of potentials. We determined the general relationship between the degree of anisotropy and the fraction of the vector and scalar fields, and concluded that the anisotropies behave independently of the potentials. We also generalized our study to the case of multi-directional anisotropies.
3-D and Anisotropic Effects on the Prediction of Burst in Aluminum Tube Hydroforming
Korkolis, Y. P.; Kyriakides, S.
2010-06-01
Thin-walled Al-6260-T4 aluminum tubes were hydroformed in a custom testing facility [1,8]. The major mode of failure observed in the experiments was bursting, despite the simultaneous application of axial compression while inflating the tubes. At the same time, a series of FE models were developed in the nonlinear code ABAQUS to simulate the experiments; however, initial computations failed to yield accurate predictions of burst. This was attributed to the adoption of the classical J2 plasticity, which is unsuitable for an anisotropic aluminum alloy, and led to an extensive study of the constitutive behavior of Al-6260-T4 and of its forming limits (see [2-4]). With the benefit of this improved understanding of the material behavior, the hydroforming simulations were revisited and models of different degrees of sophistication were developed. Starting with shell element models, the anisotropic yield functions calibrated earlier in [2-4] were shown to improve predictions over the J2 plasticity, but were found to still be deficient in predicting the failures observed in the experiments. This was in turn attributed to the fact that shell elements cannot capture the stress triaxiality associated with the gradual evolution of necking encountered in hydroforming. In addition, despite the relatively thin-walled geometries involved, significant through-thickness stresses develop in the regions of the tube in contact with the die. These stresses are again missed by a shell element discretization. Both of these observations point to the use of solid element models, to capture the stress triaxiality. We will show that when these models are run in conjunction with non-quadratic anisotropic constitutive models, accurate predictions of failure in tube hydroforming are obtained. The conclusion that solid elements are required for failure calculations in tube hydroforming and that shell element models are deficient in that respect, contrasts sharply the current industrial practice
Li, Ye; Zhang, Yixin; Zhu, Yun; Chen, Minyu
2016-07-01
Based on the spatial power spectrum of the refractive index of anisotropic turbulence, the average polarizability of the Gaussian Schell-model quantized beams and lateral coherence length of the spherical wave propagating through the ocean water channel are derived. Numerical results show that, in strong temperature fluctuation, the depolarization effects of anisotropic turbulence are inferior to isotropic turbulence, as the other parameters of two links are the same. The depolarization effects of salinity fluctuation are less than the effects of the temperature fluctuation; the average polarizability of beams increases when increasing the inner scale of turbulence and the source's transverse size; and the larger rate of dissipation of kinetic energy per unit mass of fluid enhances the average polarizability of beams. The region of the receiving radius is smaller than the characteristic radius and the average polarizability of beams in isotropy turbulence is smaller than that of beams in anisotropy turbulence. However, the receiving radius region is larger than a characteristic radius and the average polarizability of beams in isotropy turbulence is larger than that of beams in anisotropy turbulence.
Li, Ye; Zhang, Yixin; Zhu, Yun; Chen, Minyu
2016-07-01
Based on the spatial power spectrum of the refractive index of anisotropic turbulence, the average polarizability of the Gaussian Schell-model quantized beams and lateral coherence length of the spherical wave propagating through the ocean water channel are derived. Numerical results show that, in strong temperature fluctuation, the depolarization effects of anisotropic turbulence are inferior to isotropic turbulence, as the other parameters of two links are the same. The depolarization effects of salinity fluctuation are less than the effects of the temperature fluctuation; the average polarizability of beams increases when increasing the inner scale of turbulence and the source's transverse size; and the larger rate of dissipation of kinetic energy per unit mass of fluid enhances the average polarizability of beams. The region of the receiving radius is smaller than the characteristic radius and the average polarizability of beams in isotropy turbulence is smaller than that of beams in anisotropy turbulence. However, the receiving radius region is larger than a characteristic radius and the average polarizability of beams in isotropy turbulence is larger than that of beams in anisotropy turbulence. PMID:27409215
Anisotropic inflation in a 5D standing wave braneworld and effective dimensional reduction
International Nuclear Information System (INIS)
We investigate a cosmological solution within the framework of a 5D standing wave braneworld model generated by gravity coupled to a massless scalar phantom-like field. By obtaining a full exact solution of the model we found a novel dynamical mechanism in which the anisotropic nature of the primordial metric gives rise to (i) inflation along certain spatial dimensions, and (ii) deflation and a shrinking reduction of the number of spatial dimensions along other directions. This dynamical mechanism can be relevant for dimensional reduction in string and other higher-dimensional theories in the attempt of getting a 4D isotropic expanding space–time
Enhancement in magnetocaloric properties of holmium chromite by gadolinium substitution
Yin, S.; Jain, M.
2016-07-01
HoCrO3, Ho0.67Gd0.33CrO3, and GdCrO3 bulk powder samples were prepared by citrate route. The phase purity and the structural properties of the samples were examined by x-ray diffraction and Raman spectroscopic measurements. The dc magnetization data revealed that the Cr3+ ordering temperatures (Néel temperature) for the HoCrO3, Ho0.67Gd0.33CrO3, and GdCrO3 samples are 140 K, 148 K, and 167 K, respectively, while the ac magnetization data revealed that the rare-earth (Ho) ordering occurs at ˜8 K for HoCrO3 and Ho0.67Gd0.33CrO3 samples. Temperature-induced magnetization reversal and spin reorientation were observed in GdCrO3 bulk sample, which depends on applied magnetic field and disappears at ˜1500 Oe and 500 Oe, respectively. By fitting the dc magnetic data with Curie-Weiss law, the effective magnetic moments were calculated to be 11.66 μB, 10.23 μB, and 9.90 μB for the HoCrO3, Ho0.67Gd0.33CrO3, and GdCrO3 samples, respectively. The isothermal magnetization data showed that the magnetic behavior changed from canted antiferromagnetic in low temperature region (below Néel temperature) to paramagnetic at high temperature. It was found that Gd substitution considerably improves the magnetocaloric effect of HoCrO3. Pure GdCrO3 bulk sample showed giant magnetocaloric entropy change (31.6 J/kg K at temperature ˜5 K and at ˜70 kOe), which is higher than that for polycrystalline RMnO3, RCrO3, and RFeO3 bulk powder samples. This renders GdCrO3 useful for potential applications in low-temperature magnetic refrigeration.
Energy Technology Data Exchange (ETDEWEB)
Panda, J.; Saha, S.N.; Nath, T.K., E-mail: tnath@phy.iitkgp.ernet.in
2015-09-25
Highlights: • The Curie temperature of alloy series of Co{sub 50−x}Ni{sub x}Cr{sub 25}Al{sub 25} decreases with increasing x. • The critical exponents behavior and scaling relation of the alloy series have been investigated. • Using M–H data, employing Modified Arrott plot and Kouvel–Fisher plot exponents are estimated. • The estimated critical exponent values match very well with the mean field theory. • Under a magnetic field maximum up to 5 T, normal magnetocaloric effect has been observed. - Abstract: This work reports the investigation of critical behavior of Co{sub 50−x}Ni{sub x}Cr{sub 25}Al{sub 25} (x = 0 and 5) and magneto caloric effect (MCE) of bulk Co{sub 2}CrAl full Heusler alloy system. The alloy series of Co{sub 50−x}Ni{sub x}Cr{sub 25}Al{sub 25} (x = 0, 1, 2, 3, 4 and 5) have been prepared using arc melting technique. The magnetic properties of all the samples have been studied in the temperature range of 5–300 K. The value of Curie temperature (T{sub C}) is found to decrease with increasing doping concentration of the Ni (substitution of Ni at Co site). The critical exponents behavior and scaling relation have been investigated using magnetic isotherms in Co{sub 50−x}Ni{sub x}Cr{sub 25}Al{sub 25} (x = 0 and 5) alloys. The critical exponents are estimated by various techniques such as, Modified Arrott plot, Kouvel–Fisher plot and critical isotherm technique. The value of critical exponents vicinity to the second order magnetic phase transition of Co{sub 50}Cr{sub 25}Al{sub 25} were found to be β = 0.488 (7), γ = 1.144 (16) and δ = 3.336 (5) with T{sub C} = 328.64 (5) K whereas for Co{sub 50}Ni{sub 5}Cr{sub 25}Al{sub 25} the values are β = 0.522 (13), γ = 1.014 (6) and δ = 3.043 (7) with T{sub C} = 285.71 (11). The critical exponent values for both the samples are almost similar to the value as predicted by mean field theory. This has been best explained by long range mean field like ferromagnetic interaction in the
Franzone, P C; Guerri, L; Pennacchio, M; Taccardi, B
1998-01-15
We investigate a three-dimensional macroscopic model of wave-front propagation related to the excitation process in the left ventricular wall represented by an anisotropic bidomain. The whole left ventricle is modeled, whereas, in a previous paper, only a flat slab of myocardial tissue was considered. The direction of cardiac fibers, which affects the anisotropic conductivity of the myocardium, rotates from the epi- to the endocardium. If the ventricular wall is conceived as a set of packed surfaces, the fibers may be tangent to them or more generally may cross them obliquely; the latter case is described by an "imbrication angle." The effect of a simplified Purkinje network also is investigated. The cardiac excitation process, more particularly the depolarization phase, is modeled by a nonlinear elliptic equation, called an eikonal equation, in the activation time. The numerical solution of this equation is obtained by means of the finite element method, which includes an upwind treatment of the Hamiltonian part of the equation. By means of numerical simulations in an idealized model of the left ventricle, we try to establish whether the eikonal approach contains the essential basic elements for predicting the features of the activation patterns experimentally observed. We discuss and compare these results with those obtained in our previous papers for a flat part of myocardium. The general rules governing the spread of excitation after local stimulations, previously delineated for the flat geometry, are extended to the present, more realistic monoventricular model.
Institute of Scientific and Technical Information of China (English)
张学习; 苗生沛; 孙剑飞
2014-01-01
采用泰勒法制备了直径范围在30~100μm之间的玻璃包裹Ni-Mn-In-Co合金纤维。利用综合物性测量系统(PPMS)研究了磁场对制备态和退火态纤维马氏体相变温度的影响，并且从M-B曲线中分别计算得出了制备态和退火态纤维的磁热效应。研究结果表明：制备态纤维在室温下为7M马氏体结构。在制备态和退火态纤维中，奥氏体相变开始温度随外加磁场变化速率(ΔAs/ΔB)分别为-1.6和-4 K/T。退火态纤维在As点附近发生磁场诱发马氏体向奥氏体逆相变。退火态纤维最大磁熵变为3.0 J/(kg·K)，远大于制备态纤维的0.5 J/(kg·K)。Ni-Mn-In-Co合金纤维的大磁熵变和低成本使其成为最具潜力的磁制冷材料之一。%Ni-Mn-In-Co microwires with diameter of 30-100μm are prepared by glass-coated metal filaments (Taylor-Ulitovsky) method. The effects of magnetic field on martensite transformation temperature in the as-prepared and annealed microwires are investigated using a physical property measurement system (PPMS). Magnetocaloric effect (MCE) attributed to field-induced austenite transformation in the as-prepared and annealed microwires is analyzed indirectly from the isothermal magnetization (M-B) curves. The as-prepared microwire has a 7-layer modulated martensite structure (7M) at room temperature. The changes of austenite starting temperature induced by an external magnetic field (ΔAs/ΔB) in the as-prepared and annealed microwires are-1.6 and-4 K/T, respectively. Inverse martensite to austenite transformation exists in annealed microwires when an external magnetic field is applied at temperatures nearAs. The entropy change (ΔS) obtained in the annealed microwires is 3.0 J/(kg·K), which is much larger than that in the as-prepared microwires 0.5 J/(kg·K). The large entropy change and low price make Ni-Mn-In-Co microwires a potential working material in magnetic refrigeration.
Rotation and Anisotropic Molecular Orbital Effect in a Single H2TPP Molecule Transistor
Sakata, Shuichi; Yoshida, Kenji; Kitagawa, Yuichi; Ishii, Kazuyuki; Hirakawa, Kazuhiko
2013-12-01
Electron transport through a single molecule is determined not only by the intrinsic properties of the molecule but also by the configuration of the molecule with respect to the lead electrodes. Here, we show how electron transport through a single H2TPP molecule is modulated by changes in the configuration. The Coulomb stability diagram of a single H2TPP molecule transistor exhibited a few different patterns in different measurement scans. Furthermore, the sample exhibited negative differential resistance, the magnitude of which changed with the pattern in the Coulomb stability diagram. Such behavior can be explained by the rotation of the molecule with anisotropic molecular orbitals in the gap electrodes induced by electrical stress. Moreover, we find that the energy separations between molecular orbitals are also affected by the rotation, confirming that the metal-molecule interface configuration renormalizes the electronic levels in the molecule.
Energy Technology Data Exchange (ETDEWEB)
Gosalvez, M.A.; Foster, A.S.; Nieminen, R.M
2002-12-30
Atomistic simulations of anisotropic wet chemical etching of crystalline silicon have been performed in order to determine the dependence of the etch rates of different crystallographic orientations on surface coverage and clustering of OH radicals. We show that the etch rate is a non-monotonic function of OH coverage and that there always exists a coverage value at which the etch rate reaches a maximum. The dependence of the anisotropy of the etching process on coverage, including the dependence of the fastest-etched plane orientation, is implicitly contained in the model and predictions of convex corner under-etching structures are made. We show that the whole etching process is controlled by only a few surface configurations involving a particular type of next-nearest neighbours. The relative value of the removal probabilities of these confitions determines the balance in the occurrence of step propagation and etch pitting for all surface orientations.
Design, fabrication and thermal characterization of a magnetocaloric microcooler
Energy Technology Data Exchange (ETDEWEB)
Kim, S.; Ghirlanda, S.; Adams, C.; Bethala, B.; Sambandam, S.N.; Bhansali, S. [BioMEMS and Microsystems Laboratory, Department of Electrical Engineering, University of South Florida, 4202 E. Fowler Ave., ENB118, Tampa, FL 33620, (United States)
2006-12-11
Magnetocaloric cooling is an alternative, high-efficiency cooling technology. In this paper, we present the design and fabrication of a micromachined magnetocaloric cooler and demonstrate its ability to work in a small magnetic field (<1.2 T) with a cooling test. The cooler was built by fabricating Si microfluidic channels, and it was integrated with a Gd{sub 5}(Si{sub 2}Ge{sub 2}) magnetocaloric refrigeration element. The magnetic properties of the Gd{sub 5}(Si{sub 2}Ge{sub 2}) material were characterized to calculate the magnetic entropy change at different ambient temperatures. Three different methods to integrate the channel layer and the magnetocaloric element were evaluated to test sealing and cooling performance. The cooling tests were performed by providing a magnetic field using an electromagnet. A test jig was constructed between the poles of an electromagnet to maintain a steady temperature during the test. Cooling tests were performed on the magnetocaloric element at ambient temperatures ranging from 258 to 280 K using a magnetic field of 1.2 T. Experimental results showed a maximum temperature change of 7 K on the magnetocaloric element alone at an ambient temperature of 258 K. Cooling tests of the fully integrated coolers were also performed. A solution of anti-freeze fluid (propylene glycol) and water was used as the coolant. The temperature of the working fluid decreased by 4.6 and 9 K for the glass and Si intermediate layers, respectively, confirming that the thermal conductivity of the materials is also an important factor in cooler performance. (Author)
Energy Technology Data Exchange (ETDEWEB)
Gálisová, Lucia, E-mail: galisova.lucia@gmail.com [Department of Applied Mathematics and Informatics, Faculty of Mechanical Engineering, Technical University, Letná 9, 042 00 Košice (Slovakia); Strečka, Jozef, E-mail: jozef.strecka@upjs.sk [Department of Theoretical Physics and Astrophysics, Faculty of Science, P.J. Šafárik University, Park Angelinum 9, 040 01 Košice (Slovakia)
2015-10-16
Magnetocaloric effect in a double-tetrahedral chain, in which nodal lattice sites occupied by the localized Ising spins regularly alternate with three equivalent lattice sites available for mobile electrons, is exactly investigated by considering the one-third electron filling and the ferromagnetic Ising exchange interaction between the mobile electrons and their nearest Ising neighbours. The entropy and the magnetic Grüneisen parameter, which closely relate to the magnetocaloric effect, are exactly calculated in order to investigate the relation between the ground-state degeneracy and the cooling efficiency of the hybrid spin–electron system during the adiabatic demagnetization. - Highlights: • A double-tetrahedral chain of mobile electrons and localized Ising spins is studied. • Magnetic Grüneisen parameter for the system is exactly derived. • Macroscopically degenerate phases FRU and FM constitute the ground state. • MCE is three times higher nearby FRU–FM transition than in FRU phase at small fields.
Sundqvist, Jon O.; Owocki, Stanley P.; Cohen, David H.; Leutenegger, Maurice A.; Townsend, Richard H. D.
2011-01-01
We present a generalised formalism for treating the porosity-associated reduction in continuum opacity that occurs when individual clumps in a stochastic medium become optically thick. We consider geometries resulting in either isotropic or anisotropic effective opacity, and, in addition to an idealised model in which all clumps have the same local overdensity and scale, we also treat an ensemble of clumps with optical depths set by Markovian statistics. This formalism is then applied to the ...
Effects of the excess iron on phase and magnetocaloric property of LaFe11.6*xSi1.4 alloys
Institute of Scientific and Technical Information of China (English)
陈湘; 陈云贵; 唐永柏; 肖定全
2015-01-01
The effect of Fe on microstructure and magnetic thermal performance of LaFe11.6*xSi1.4 alloys were studied by X-ray dif-fraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and vibrating-sample magnetometer (VSM), respectively. The results showed that the excess Fe would make the 1:13 phase reduce in proportion and the easy corrosion phase LaFeSi phase disappear in LaFe11.6*xSi1.4 alloys. The LaFe11.6*xSi1.4 alloys kept the first order magnetic phase transition, and the maximum isothermal magnetic entropy changed and the relative cooling power reached the maximum in LaFe11.6*xSi1.4 alloys with x=1.05 and 1.1, respectively.
Universal behavior of magnetocaloric effect in a layered perovskite La1.2Sr1.8Mn2O7 single crystal
Thanh, Tran Dang; Manh, T. V.; Ho, T. A.; Telegin, Andrey; Phan, T. L.; Yu, S. C.
2016-04-01
In this paper, we present a detailed analysis on temperature and magnetic field dependences of the magnetic entropy change (ΔSm) near the ferromagnetic (FM)-paramagnetic (PM) phase transition of a La1.2Sr1.8Mn2O7 single crystal. Experimental results reveal the material exhibiting a FM-PM phase transition at TC=85 K, and belongs to a second-order phase transition (SOPT). Around TC, -ΔSm reaches the maximum value (|ΔSmax|), which increases with increasing an applied magnetic field change, ΔH. The |ΔSmax| values found are about 0.93, 1.73, 2.38, 2.91, and 3.33 J kg-1 K-1 for ΔH=10, 20, 30, 40, and 50 kOe, respectively. However, the peak position of the -ΔSm(T) curves is effectively shifted to higher temperatures when ΔH increases. Additionally, the ΔSm(T) curves measured at different ΔH values do not collapse into a universal curve when they are normalized to their respective ΔSmax value, and Prod. Type: rescaled the temperature axis with θ1=(T-TC)/(Tr-TC) for a reference temperature Tr>TC or TrTC.
Magnetocaloric properties of rare-earth substituted DyCrO3
McDannald, A.; Jain, M.
2015-07-01
Recently, there has been a focus on the need for efficient refrigeration technology without the use of expensive or harmful working fluids, especially at temperatures below 30 K. Solid state refrigeration, based on the magnetocaloric effect, provides a possible solution to this problem. The rare-earth chromites (RCrO3), especially DyCrO3, with its large magnetic moment dysprosium ion, are potential candidates for such an application. The Dy3+ ordering transition at low temperatures (cooling power of 237 J/kg at 40 kOe and 5 K) indicates that this material system is well suited for low temperature (<30 K) solid state refrigeration applications.
Magnetic refrigeration at room temperature - from magnetocaloric materials to a prototype
DEFF Research Database (Denmark)
Kuhn, Luise Theil; Pryds, Nini; Bahl, Christian Robert Haffenden;
2011-01-01
Based on the magnetocaloric effect, magnetic refrigeration at room temperature has for the past decade been a promising, environmentally friendly new energy technology predicted to have a significantly higher efficiency than the present conventional methods. However, so far only a few prototype...... materials, their shaping and graded composition for technological use. Modelling the performance of a permanent magnet with optimum use of the flux and relatively low weight, and designing and constructing a prototype continuous magnetic refrigeration device have also been major tasks in the project...
Trung, N.T.; Biharie, V.; Zhang, L.; Caron, L.; Buschow, K.H.J.; Brück, E.H.
2010-01-01
Substitution of some Cr for Mn atoms in MnCoGe was employed to control the magnetic and structural transitions in this alloy to coincide, leading to a single first-order magnetostructural transition from the ferromagnetic to the paramagnetic state with a giant magnetocaloric effect observed near roo
Ali, Aamir; Zubair; Hussain, Matloob; Rehman, Khaista; Toqeer, Muhammad
2016-08-01
Shales can be distributed in sand through four different ways; laminated, structural, dispersed and any combination of these aforementioned styles. A careful analysis of well log data is required for the determination of shale distribution in sand affecting its reservoir quality. The objective of this study is to characterize the effect of shale distribution on reservoir quality of sands using well log data. The correlation of well data in terms of lithology has revealed four sand and three shale layers in Lower Goru Formation acting as a major reservoir in the study area. Our results indicate that the laminated type of shale distribution prevails at the Basal sand level, which does not affect its reservoir quality greatly. The remaining layers of variable vertical extent show a variety of shale distribution models affecting their reservoir quality adversely. We also present anisotropic rock physics modelling for AVA analysis at Basal sand level.
Imaging the anisotropic nonlinear meissner effect in nodal YBa2 Cu3 O7-δ thin-film superconductors.
Zhuravel, Alexander P; Ghamsari, B G; Kurter, C; Jung, P; Remillard, S; Abrahams, J; Lukashenko, A V; Ustinov, Alexey V; Anlage, Steven M
2013-02-22
We have directly imaged the anisotropic nonlinear Meissner effect in an unconventional superconductor through the nonlinear electrodynamic response of both (bulk) gap nodes and (surface) Andreev bound states. A superconducting thin film is patterned into a compact self-resonant spiral structure, excited near resonance in the radio-frequency range, and scanned with a focused laser beam perturbation. At low temperatures, direction-dependent nonlinearities in the reactive and resistive properties of the resonator create photoresponse that maps out the directions of nodes, or of bound states associated with these nodes, on the Fermi surface of the superconductor. The method is demonstrated on the nodal superconductor YBa2Cu3O7-δ and the results are consistent with theoretical predictions for the bulk and surface contributions.
Direct measurements of the magnetocaloric effect
DEFF Research Database (Denmark)
Nielsen, Kaspar Kirstein; Bahl, Christian R.H.; Neves Bez, Henrique;
2014-01-01
We present an experimental setup recently developed at DTU Energy Conversion for measuring specific heat and direct isothermal entropy change in a varying magnetic field (DSC device) using calorimetry. The device operates in high vacuum (~1e-6 mbar) and measurements are fully automated with respect...... magnetic field scans under isothermal conditions (direct isothermal entropy change measurements)....
International Nuclear Information System (INIS)
Low field magnetic and magnetocaloric properties of the compound LaMn1.9Fe0.1Si2 have been investigated. Using the M-H data measured at various temperatures, we have derived the magnetic entropy change |ΔS| as a function of temperature and magnetic field, by using the Maxwell relation. The temperature dependence of the Landau coefficient has been derived by fitting the magnetization, using the Landau expansion of magnetic free energy and Arrott plots. The results show that LaMn1.9Fe0.1Si2 is ferromagnetically ordered around room temperature (285 K) and the nature of the phase transition at this temperature is found to be second order.
Anisotropic Stars Exact Solutions
Dev, K; Dev, Krsna; Gleiser, Marcelo
2000-01-01
We study the effects of anisotropic pressure on the properties of spherically symmetric, gravitationally bound objects. We consider the full general relativistic treatment of this problem and obtain exact solutions for various form of equations of state connecting the radial and tangential pressures. It is shown that pressure anisotropy can have significant effects on the structure and properties of stellar objects. In particular, the maximum value of 2M/R can approach unity (2M/R < 8/9 for isotropic objects) and the surface redshift can be arbitrarily large.
Anisotropic effective medium properties from interacting Ag nanoparticles in silicon dioxide.
Menegotto, Thiago; Horowitz, Flavio
2014-05-01
Films containing a layer of Ag nanoparticles embedded in silicon dioxide were produced by RF magnetron sputtering. Optical transmittance measurements at several angles of incidence (from normal to 75°) revealed two surface plasmon resonance (SPR) peaks, which depend on electric field direction: one in the ultraviolet and another red-shifted from the dilute Ag/SiO₂ system resonance at 410 nm. In order to investigate the origin of this anisotropic behavior, the structural properties were determined by transmission electron microscopy, revealing the bidimensional plane distribution of Ag nanoparticles with nearly spherical shape as well as the filling factor of metal in the composite. A simple model linked to these experimental parameters allowed description of the most relevant features of the SPR positions, which, depending on the field direction, were distinctly affected by the coupling of oscillations between close nanoparticles, as described by a modified Drude-Lorentz dielectric function introduced into the Maxwell-Garnett relation. This approach allowed prediction of the resonance for light at 75° incidence from the SPR position for light at normal incidence, in good agreement with experimental observation. PMID:24921871
Materials Challenges for High Performance Magnetocaloric Refrigeration Devices
DEFF Research Database (Denmark)
Smith, Anders; Bahl, Christian; Bjørk, Rasmus;
2012-01-01
Magnetocaloric materials with a Curie temperature near room temperature have attracted signifi cant interest for some time due to their possible application for high-effi ciency refrigeration devices. This review focuses on a number of key issues of relevance for the characterization, performance...
Properties of magnetocaloric materials with a distribution of Curie temperatures
DEFF Research Database (Denmark)
Bahl, Christian Robert Haffenden; Bjørk, Rasmus; Smith, Anders;
2012-01-01
The magnetocaloric properties of inhomogeneous ferromagnets that contain distributions of Curie temperatures are considered as a function of the width of such a distribution. Assuming a normal distribution of the Curie temperature, the average adiabatic temperature change, ΔTad, the isothermal...
Anisotropic mechanical properties of zircon and the effect of radiation damage
Beirau, Tobias; Nix, William D.; Bismayer, Ulrich; Boatner, Lynn A.; Isaacson, Scott G.; Ewing, Rodney C.
2016-06-01
This study provides new insights into the relationship between radiation-dose-dependent structural damage due to natural U and Th impurities and the anisotropic mechanical properties (Poisson's ratio, elastic modulus and hardness) of zircon. Natural zircon samples from Sri Lanka (see Muarakami et al. in Am Mineral 76:1510-1532, 1991) and synthetic samples, covering a dose range of zero up to 6.8 × 1018 α-decays/g, have been studied by nanoindentation. Measurements along the [100] crystallographic direction and calculations, based on elastic stiffness constants determined by Özkan (J Appl Phys 47:4772-4779, 1976), revealed a general radiation-induced decrease in stiffness (~54 %) and hardness (~48 %) and an increase in the Poisson's ratio (~54 %) with increasing dose. Additional indentations on selected samples along the [001] allowed one to follow the amorphization process to the point that the mechanical properties are isotropic. This work shows that the radiation-dose-dependent changes of the mechanical properties of zircon can be directly correlated with the amorphous fraction as determined by previous investigations with local and global probes (Ríos et al. in J Phys Condens Matter 12:2401-2412, 2000a; Farnan and Salje in J Appl Phys 89:2084-2090, 2001; Zhang and Salje in J Phys Condens Matter 13:3057-3071, 2001). The excellent agreement, revealed by the different methods, indicates a large influence of structural and even local phenomena on the macroscopic mechanical properties. Therefore, this study indicates the importance of acquiring better knowledge about the mechanical long-term stability of radiation-damaged materials.
Directory of Open Access Journals (Sweden)
Simone Fabbrici
2014-04-01
Full Text Available In Ni-Mn-Ga ferromagnetic shape memory alloys, Co-doping plays a major role in determining a peculiar phase diagram where, besides a change in the critical temperatures, a change of number, order and nature of phase transitions (e.g., from ferromagnetic to paramagnetic or from paramagnetic to ferromagnetic, on heating can be obtained, together with a change in the giant magnetocaloric effect from direct to inverse. Here we present a thorough study of the intrinsic magnetic and structural properties, including their dependence on hydrostatic pressure, that are at the basis of the multifunctional behavior of Co and In-doped alloys. We study in depth their magnetocaloric properties, taking advantage of complementary calorimetric and magnetic techniques, and show that if a proper measurement protocol is adopted they all merge to the same values, even in case of first order transitions. A simplified model for the estimation of the adiabatic temperature change that relies only on indirect measurements is proposed, allowing for the quick and reliable evaluation of the magnetocaloric potentiality of new materials starting from readily available magnetic measurements.
Efficient Wavefield Extrapolation In Anisotropic Media
Alkhalifah, Tariq
2014-07-03
Various examples are provided for wavefield extrapolation in anisotropic media. In one example, among others, a method includes determining an effective isotropic velocity model and extrapolating an equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. The effective isotropic velocity model can be based upon a kinematic geometrical representation of an anisotropic, poroelastic or viscoelastic wavefield. Extrapolating the equivalent propagation can use isotopic, acoustic or elastic operators based upon the determined effective isotropic velocity model. In another example, non-transitory computer readable medium stores an application that, when executed by processing circuitry, causes the processing circuitry to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. In another example, a system includes processing circuitry and an application configured to cause the system to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield.
Enhanced magnetocaloric properties of melt-extracted GdAlCo metallic glass microwires
Energy Technology Data Exchange (ETDEWEB)
Shen, Hongxian; Wang, Huan [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Jingshun, Liu [School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051 (China); Cao, Fuyang [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Qin, Faxiang [1D Nanomaterials Group, National Institute for Material Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Xing, Dawei; Chen, Dongming; Liu, Yanfen [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Sun, Jianfei, E-mail: jfsun_hit@263.net [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)
2014-12-15
Herein, we report high magnetocaloric performance of melt-extracted metallic glass Gd{sub 60}Al{sub 20}Co{sub 20} microwires, which exhibit a large and reversible magnetocaloric effect (MCE). The isothermal magnetic entropy change (−ΔS{sub m}) reaches as high as 10.1 J kg{sup −1} K{sup −1} and the refrigerant capacity (RC) has a large value of 681 J kg{sup −1} for a field change of 5 T. The as-obtained Gd-based metallic glass microwires hold a great promise for multifunctional applications in MCE-based refrigeration of liquid nitrogen temperature range. - Highlights: • Gd{sub 60}Al{sub 20}Co{sub 20} metallic glass wires were fabricated by melt-extraction method. • The microwires show superior MCE performance versus its counterpart in BMGs. • The excellent result was due to the size effect and amorphous state of wires.
Sakamoto, Kenji; Yasuda, Takeshi; Miki, Kazushi; Chikamatsu, Masayuki; Azumi, Reiko
2011-01-01
We have fabricated organic field-effect transistors (OFETs) with a highly oriented active layer of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene] (F8T2), which was formed with the help of a photoaligned polyimide film. Photoalignment is an attractive technique for integrating OFETs with aligned active layers on the same substrate, because of its potential capability of two-dimensional alignment patterning. The F8T2 layer formed on the photoaligned polyimide film showed an absorption dichroic ratio greater than 15 after annealing at 285 °C. Top-gate/bottom-contact-type OFETs with a parylene gate insulating layer exhibited an enhanced hole mobility (0.016 cm2 V-1 s-1) along the alignment direction of the F8T2 backbone structure and a suppressed one (0.002 cm2 V-1 s-1) along the perpendicular direction. This result shows that the photoaligned polyimide film is an attractive alignment layer for fabricating and integrating OFETs with aligned active layers. Current-direction-dependent bias stress effect was observed for those OFETs; when the current flowed parallel to the alignment direction of the F8T2 backbone structures, a larger negative threshold voltage shift was observed. This anisotropic bias stress effect was discussed on the basis of a microstructure model of aligned F8T2 films.
Zhang, Hai-Feng; Liu, Shao-Bin; Li, Bing-Xiang
2013-10-01
In this paper, the properties of photonic band gaps (PBGs) for three-dimensional magnetized plasma photonic crystals (MPPCs) composed of anisotropic dielectric (the uniaxial material) spheres immersed in homogeneous magnetized plasma background with simple-cubic lattices are theoretically investigated by the plane wave expansion (PWE) method, as the Voigt effects of magnetized plasma are considered. The equations for calculating the anisotropic PBGs in the first irreducible Brillouin zone are theoretically deduced. The anisotropic PBGs and two flatband regions can be obtained. The effects of the ordinary-refractive index, extraordinary-refractive index, filling factor, plasma frequency and plasma cyclotron frequency on the characteristics of anisotropic PBGs for the three-dimensional MPPCs are studied in detail and some corresponding physical explanations are also given. The numerical results show that the anisotropy can open partial band gaps in simple-cubic lattices and the complete PBGs can be found compared to the conventional three-dimensional MPPCs doped by the isotropic material. The bandwidths of PBGs can be enlarged by introducing the magnetized plasma into three-dimensional PCs containing the uniaxial material. It is also shown that the anisotropic PBGs can be manipulated by the ordinary-refractive index, extraordinary-refractive index, filling factor, plasma frequency and plasma cyclotron frequency. The locations of flatband regions cannot be tuned by any parameters except for the plasma frequency and plasma cyclotron frequency. Introducing the uniaxial material in three-dimensional magnetized plasma-dielectric photonic crystals can enlarge the PBGs and also provide a way to obtain the complete PBGs as the three-dimensional MPPCs with high symmetry.
Magnetocaloric response of amorphous and nanocrystalline Cr-containing Vitroperm-type alloys
Moreno-Ramírez, L. M.; Blázquez, J. S.; Franco, V.; Conde, A.; Marsilius, M.; Budinsky, V.; Herzer, G.
2016-07-01
The broad compositional range in which transition metal (TM) based amorphous alloys can be obtained, yields an easily tunable magnetocaloric effect (MCE) in a wide temperature range. In some TM-based alloys, anomalous behaviors are reported, as a non-monotonous trend with magnetic moment (e.g. FeZrB alloys). Moreover, in certain Cr-containing Vitroperm alloys anomalously high values of the magnetic entropy change were published. In this work, a systematic study on MCE response of Cr-containing amorphous alloys of composition Fe74-xCrxCu1Nb3Si15.5B6.5 (with x=2, 8, 10, 12, 13, 14 and 20) has been performed in a broad Curie temperature range from 100 K to 550 K. Curie temperature and magnetic entropy change peak of the amorphous alloys decrease with the increase of Cr content at rates of -25.6 K/at% Cr and -54 mJ kg-1 K-1/at% Cr, respectively, following a linear trend with the magnetic moment in both cases. The presence of nanocrystalline phases has been considered as a possible cause in order to explain the anomalies. The samples were nanocrystallized in different stages, however, the magnetocaloric response decreases as crystallization progresses due to the large separation of the Curie temperatures of the two phases.
Energy Technology Data Exchange (ETDEWEB)
Xia, Wei [Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University, Huhhot 010022 (China); Baotou Research Institute of Rare Earth, Baotou 014030 (China); Huang, Jiaohong, E-mail: jiaohongh@163.com [Baotou Research Institute of Rare Earth, Baotou 014030 (China); Sun, Naikun [School of Science, Shenyang Ligong University, Shenyang 110159 (China); Lui, Cuilan [Baotou Research Institute of Rare Earth, Baotou 014030 (China); Ou, Zhiqiang; Song, Lin [Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University, Huhhot 010022 (China)
2015-06-25
Highlights: • Bonded La{sub 0.9}Ce{sub 0.1}(Fe,Mn){sub 11.7}Si{sub 1.3}H{sub 1.8} are prepared by bonding technology. • After bonding the samples have better mechanical properties than bulk alloys. • The T{sub c} of La{sub 0.9}Ce{sub 0.1}Fe{sub 11.7}Si{sub 1.3}H{sub 1.8} is adjusted by adding Mn atoms. • After bonding the good magnetocaloric effects can be remained. - Abstract: Bonded samples of La{sub 0.9}Ce{sub 0.1}Fe{sub 11.7}Si{sub 1.3}H{sub 1.8} and La{sub 0.9}Ce{sub 0.1}Fe{sub 11.41}Mn{sub 0.29}Si{sub 1.3}H{sub 1.8} with NaZn{sub 13}-type cubic structure have been prepared, and their mechanical properties and magnetocaloric effects have been investigated. The bonded samples show a very good compressive strength of 320 and 332 MPa, about 10% and 14% higher than that of bulk LaFe{sub 10.99}Co{sub 0.91}Si{sub 1.1}B{sub 0.2} compound. By partial substitution of Mn for Fe, the Curie temperature (T{sub c}) of bonded La{sub 0.9}Ce{sub 0.1}Fe{sub 11.7}Si{sub 1.3}H{sub 1.8} decreases remarkably from 325 to 279 K. The magnetic entropy change (ΔS{sub m}) for bonded La{sub 0.9}Ce{sub 0.1}Fe{sub 11.7}Si{sub 1.3}H{sub 1.8} and La{sub 0.9}Ce{sub 0.1}Fe{sub 11.41}Mn{sub 0.29}Si{sub 1.3}H{sub 1.8} slightly reduces compared with hydride alloys, but still maintains large values of 8.8 and 7.9 J/kg K. The two bonded samples exhibit the same adiabatic temperature change (ΔT{sub ad}) of about 2.6 K under a field change from 0 to 1.5 T. The bonded La{sub 0.9}Ce{sub 0.1}(Fe,Mn){sub 11.7}Si{sub 1.3} hydrides samples with good magnetocaloric effects and better mechanical properties are promising as high performance magnetic refrigerants materials.
Energy Technology Data Exchange (ETDEWEB)
Nisha, P.; Savitha Pillai, S. [Materials and Minerals Division, National Institute for Interdisciplinary Science and Technology NIIST, CSIR, Trivandrum 695 019, Kerala (India); Darbandi, Azad [Gemeinschaftslabor Nanomaterialien, Forschungzentrum Karlsrhue/TU-Darmstadt, Petersenstr. 23 Gebaeude L2/01, 64287 Darmstadt (Germany); Varma, Manoj Raama, E-mail: manoj@niist.res.in [Materials and Minerals Division, National Institute for Interdisciplinary Science and Technology NIIST, CSIR, Trivandrum 695 019, Kerala (India); Suresh, K.G. [Department of Physics, Indian Institute of Technology Bombay, 400076 Mumbai (India); Hahn, Horst [Gemeinschaftslabor Nanomaterialien, Forschungzentrum Karlsrhue/TU-Darmstadt, Petersenstr. 23 Gebaeude L2/01, 64287 Darmstadt (Germany)
2012-09-14
The structure, critical exponents and magnetocaloric effect (MCE) of Nebulized Spray Pyrolysis (NSP) synthesized nano crystalline La{sub 0.67}Ca{sub 0.33}Mn{sub 1-x}Fe{sub x}O{sub 3} (x = 0.05, 0.2) were investigated. The Reitveld refinement of XRD patterns show that the samples adopt an orthorhombic structure with Pnma space group. TEM inspection reveals that the average particle size is about 15 nm and 42 nm for NSP synthesized LCMFe{sub 0.05} and LCMFe{sub 0.2} samples respectively. The temperature and field dependent magnetization studies reveal the superparamagnetic state of La{sub 0.67}Ca{sub 0.33}Mn{sub 0.95}Fe{sub 0.05}O{sub 3} and spin-glass-like state of La{sub 0.67}Ca{sub 0.33}Mn{sub 0.8}Fe{sub 0.2}O{sub 3}. The critical behaviour at the transition region studied using modified Arrott plot provides a second order nature of phase transition for both samples. The magnetocaloric studies show the maximum value of magnetic entropy change ({Delta}S{sub max}) is in the range 2.3 J kg{sup -1} K{sup -1} at 158 K for LCMFe{sub 0.05} and 0.3 J kg{sup -1} K at 92 K for LCMFe{sub 0.2} respectively at 5 T field. The field dependence of the magnetic entropy changes are also analysed, which show a power law dependence ({Delta}S{sub M} {infinity}H{sup n}, n = 0.72 (2)) at transition temperature, T{sub C} = 162 K for LCMFe{sub 0.05} and n = 1.11(3) at 92 K for LCMFe{sub 0.2}. -- Highlights: Black-Right-Pointing-Pointer Nano La{sub 0.67}Ca{sub 0.33}Mn{sub 1-x}Fe{sub x}O{sub 3} (x = 0.05, 0.2) are prepared by NSP method. Black-Right-Pointing-Pointer We examine changes in the structure of the compositions. Black-Right-Pointing-Pointer The temperature and field variations of magnetization were analysed. Black-Right-Pointing-Pointer Super paramagnetic clustered state is observed for La{sub 0.67}Ca{sub 0.33}Mn{sub 0.95}Fe{sub 0.05}O{sub 3}. Black-Right-Pointing-Pointer We report critical behaviour and magnetocaloric effect of LCMOFe{sub 0.05}.
Multidisciplinary approach to cylindrical anisotropic metamaterials
International Nuclear Information System (INIS)
Anisotropic characteristics of cylindrically corrugated microstructures are analyzed in terms of their acoustic and electromagnetic (EM) behavior paying special attention to their differences and similarities. A simple analytical model has been developed using effective medium theory to understand the anisotropic features of both types of waves in terms of radial and angular components of the wave propagation velocity. The anisotropic constituent parameters have been obtained by measuring the resonances of cylindrical cavities, as well as from numerical simulations. This permits one to characterize propagation of acoustic and EM waves and to compare the fundamental anisotropic features generated by the corrugated effective medium. Anisotropic coefficients match closely in both physics fields but other relevant parameters show significant differences in the behavior of both types of waves. (paper)
Sundqvist, Jon O; Cohen, David H; Leutenegger, Maurice A; Townsend, Richard H D
2011-01-01
We present a generalised formalism for treating the porosity-associated reduction in continuum opacity that occurs when individual clumps in a stochastic medium become optically thick. We consider geometries resulting in either isotropic or anisotropic effective opacity, and, in addition to an idealised model in which all clumps have the same local overdensity and scale, we also treat an ensemble of clumps with optical depths set by Markovian statistics. This formalism is then applied to the specific case of bound-free absorption of X-rays in hot star winds, a process not directly affected by clumping in the optically thin limit. We find that the Markov model gives surprisingly similar results to those found previously for the single clump model, suggesting that porous opacity is not very sensitive to details of the assumed clump distribution function. Further, an anisotropic effective opacity favours escape of X-rays emitted in the tangential direction (the `venetian blind' effect), resulting in a 'bump' of ...
Averaging anisotropic cosmologies
Barrow, J D; Barrow, John D.; Tsagas, Christos G.
2006-01-01
We examine the effects of spatial inhomogeneities on irrotational anisotropic cosmologies by looking at the average properties of pressure-free Bianchi-type models. Adopting the Buchert averaging scheme, we identify the kinematic backreaction effects by focussing on spacetimes with zero or isotropic spatial curvature. This allows us to close the system of the standard scalar formulae with a propagation equation for the shear magnitude. We find no change in the already known conditions for accelerated expansion. The backreaction terms are expressed as algebraic relations between the mean-square fluctuations of the models' irreducible kinematical variables. Based on these we investigate the early evolution of averaged vacuum Bianchi type $I$ universes and those filled with pressureless matter. In the latter case we show that the backreaction effects can modify the familiar Kasner-like singularity and potentially remove Mixmaster-type oscillations. We also discuss the possibility of accelerated expansion due to ...
The phonon splitting and anisotropic effect of B2H6 molecular in the C2v minima
International Nuclear Information System (INIS)
Based on Jahn-Teller effect theory, quantum theory and group theory, the phonon splitting and anisotropic phenomena of the E ⊗e' system for B2H6 molecules with D3h symmetry are studied in the C2v minima. The vibration frequency of the system after Jahn-Teller distortion is calculated using the unitary shift transformation and modified scale transformation, it is found that the doubly degenerate vibration state e' is split into two states and its degeneration is completely lifted because of Jahn-Teller distortion. No matter which of the four C2v minima the system is in, the phonon splitting of the system is completely same. The Jahn-Teller distortion results in that the ground state of the system has lower energy after the distortion than before the distortion, B2H6 molecules will achieve a more stable state after the distortion just for the energy lessening. The phonon splitting is further discussed using group theory in this paper, the discussed results show that the vibration state e' of the system is split into two states respectively with a1 and b2 symmetries under the group C2v. The phonon splitting signifies that the isotropy of B2H6 molecules is destroyed and its anisotropy should appear. (authors)
A novel magnetic valve using room temperature magnetocaloric materials
DEFF Research Database (Denmark)
Eriksen, Dan; Bahl, Christian; Pryds, Nini;
2012-01-01
Magnetocaloric materials with near-room-temperature tuneable Curie temperatures have been utilized to develop a novel magnetic valve technology. The temperature dependent attractive force between the materials and a permanent magnet assembly is used to actuate valves as a response to temperature...... changes. This is made possible by the strong temperature dependence of the magnetization close to the Curie temperature of the magnetocaloric materials. Different compositions of both La0.67(Ca,Sr)0.33MnO3 and La(Fe,Co,Si)13 have been considered for use in prototype valves. Based on measured magnetization....... On the basis of these calculations two temperature adjustable valve prototypes have been designed, built and tested. Possible applications of near-room-temperature valve actuation based on these materials originally developed for magnetic refrigeration are discussed on the background of the present...
Innovative ideas for future research on magnetocaloric technologies
Energy Technology Data Exchange (ETDEWEB)
Kitanovski, Andrej; Egolf, Peter W. [University of Applied Sciences of Western Switzerland, Institute for Thermal Sciences and Engineering, Route de Cheseaux 1, CH 1401 Yverdon-les-Bains (Switzerland)
2010-05-15
Magnetic heating, refrigeration and energy conversion have caused awareness of being promising future environmentally benign technologies with much potential to enter some existing markets. An increased research activity is observed, which to the end of the year 2010 lead to approximately forty-two prototypes. As most of these machines contain solid linear moving or rotating beds - consisting of magnetocaloric material - through static magnetic fields or moving magnets, which sweep a magnetic field over a static bed, all researchers face more or less the same problems. These concern materials, fluids, design and the operation characteristics. In this article innovative new system ideas are presented, which may have the potential to overcome existing barriers. The article is a proposal to the research community in the field of magnetocaloric technologies for future R and D activities. Taking into account all the limits and problems that researchers are facing at present, the best chance to bring magnetocaloric technologies to the market is to try some substantially new approaches that go beyond the present state-of-the-art. (author)
A study of phonon anisotropic scattering effect on silicon thermal conductivity at nanoscale
Energy Technology Data Exchange (ETDEWEB)
Bong, Victor N-S; Wong, Basil T. [Swinburne Sarawak Research Centre for Sustainable Technologies, Faculty of Engineering, Computing & Science, Swinburne University of Technology Sarawak Campus, 93350 Kuching, Sarawak (Malaysia)
2015-08-28
Previous studies have shown that anisotropy in phonon transport exist because of the difference in phonon dispersion relation due to different lattice direction, as observed by a difference in in-plane and cross-plane thermal conductivity. The directional preference (such as forward or backward scattering) in phonon propagation however, remains a relatively unexplored frontier. Our current work adopts a simple scattering probability in radiative transfer, which is called Henyey and Greenstein probability density function, and incorporates it into the phonon Monte Carlo simulation to investigate the effect of directional scattering in phonon transport. In this work, the effect of applying the anisotropy scattering is discussed, as well as its impact on the simulated thermal conductivity of silicon thin films. While the forward and backward scattering will increase and decrease thermal conductivity respectively, the extent of the effect is non-linear such that forward scattering has a more obvious effect than backward scattering.
The Effects of Anisotropic Viscosity on Turbulence and Heat Transport in the Intracluster Medium
Parrish, Ian J; Quataert, Eliot; Sharma, Prateek
2012-01-01
In the intracluster medium (ICM) of galaxy clusters, heat and momentum are transported almost entirely along (but not across) magnetic field lines. We perform the first fully self-consistent Braginskii-MHD simulations of galaxy clusters including both of these effects. Specifically, we perform local and global simulations of the magnetothermal instability (MTI) and the heat-flux-driven buoyancy instability (HBI) and assess the effects of viscosity on their saturation and astrophysical implications. We find that viscosity has only a modest effect on the saturation of the MTI. As in previous calculations, we find that the MTI can generate nearly sonic turbulent velocities in the outer parts of galaxy clusters, although viscosity somewhat suppresses the magnetic field amplification. At smaller radii in cool-core clusters, viscosity can decrease the linear growth rates of the HBI. However, it has less of an effect on the HBI's nonlinear saturation, in part because three-dimensional interchange motions (magnetic f...
Effects of anisotropic potentials on the energy gap of Bose gas
Directory of Open Access Journals (Sweden)
F Nabipoor
2010-09-01
Full Text Available We investigate the effect of dipole-dipole and quadrapole- quadrapole interaction of a weakly interacting Bose gas near the transition temperature on the energy spectra of the thermal and condensate parts. We use the two fluid model and mean field approximation. We show that the effects of the condensate part on the shift of energy is greater than the case of contact potential
Wang, Longfei; Liu, Shuhai; Wang, Zheng; Zhou, Yongli; Qin, Yong; Wang, Zhong Lin
2016-02-23
Effective piezoelectric semiconductor based hybrid photocatalysts are successfully developed by assembling TiO2 nanoparticles on ZnO monocrystalline nanoplatelets. The piezopotential can be introduced and tuned by thermal stress on the piezoelectric material of ZnO monocrystalline nanoplatelets through cooling hybrid photocatalysts from high temperature to room temperature with different rates based on the mismatched thermal expansion coefficient of the two materials, which can be used to engineer the heterojunction band structure and significantly enhance the photocatalytic performance in a wide range by improving charge separation. It is proposed that the piezotronic effect enhanced photocatalyst will provide a strategy for high-performance photocatalysis applications.
Thermodynamics of anisotropic branes
Ávila, Daniel; Patiño, Leonardo; Trancanelli, Diego
2016-01-01
We study the thermodynamics of flavor D7-branes embedded in an anisotropic black brane solution of type IIB supergravity. The flavor branes undergo a phase transition between a `Minkowski embedding', in which they lie outside of the horizon, and a `black hole embedding', in which they fall into the horizon. This transition depends on two independent dimensionless ratios, which are formed out of the black hole temperature, its anisotropy parameter, and the mass of the flavor degrees of freedom. It happens either at a critical temperature or at a critical anisotropy. A general lesson we learn from this analysis is that the anisotropy, in this particular realization, induces similar effects as the temperature. In particular, increasing the anisotropy bends the branes more and more into the horizon. Moreover, we observe that the transition becomes smoother for higher anisotropies.
Evolution of the effective moduli of an anisotropic, dense, granular material
La Ragione, L.; Magnanimo, V.
2012-01-01
We analyze the behavior of a dense granular aggregate made by identical, elastic spheres, uni-axially compressed at constant pressure. Our goal is to predict the evolution of the effective moduli along the loading path when small perturbations are applied to stressed states. The analytical model is
Magnetocaloric effect in manganite perovskites La 0.77Sr 0.23Mn 1- xCu xO 3(0.1≤ x≤0.3)
El-Hagary, M.; Shoker, Y. A.; Emam-Ismail, M.; Moustafa, A. M.; Abd El-Aal, A.; Ramadan, A. A.
2009-02-01
The magnetocaloric properties of the polycrystalline manganites perovskite La 0.77Sr 0.23Mn 1- xCu xO 3 with 0.1≤x≤0.3 have been investigated. The maximum magnetic entropy change, ΔSMmax, of Cu doped manganites increases gradually with increasing applied magnetic field. The maximum values of magnetic entropy changes of Cu doped manganites samples is found to decrease with the further increasing of Cu concentration in the romboherderal phase ( x≤0.2). However, with increasing Cu contents ( x≥ 0.3) structure transformed into orthorhombic phase and, hence ΔSMmax, start to increase again with increasing Cu doped concentration. It was found that the maximum value of the magnetic entropy change increases near their respective TC from 3.09 J/kg K at 0.1 T and reached highest value of 4.41 J/kg K at 1 T for compound with x=0.1. ΔSMmax in La 0.77Sr 0.23Mn 0.9Cu 0.1O 3 at 1 T is found to be 26% higher than that known for the prototype magnetic refrigerant with pure Gd. The relative cooling power (RCP) of La 0.77Sr 0.23Mn 1- xCu xO 3 is nearly 60% of pure Gd. Thus, due to the high ΔSMmax and RCP values, sample with x=0.1 (at μoΔH=1 T) is the most promising compound to be used as magnetomechnical materials.
Sundqvist, Jon O.; Owocki, Stanley P.; Cohen, David H.; Leutenegger, Maurice A.
2011-01-01
We present a generalised formalism for treating the porosity-associated reduction in continuum opacity that occurs when individual clumps in a stochastic medium become optically thick. As in previous work, we concentrate on developing bridging laws between the limits of optically thin and thick clumps. We consider geometries resulting in either isotropic or anisotropic effective opacity, and, in addition to an idealised model in which all clumps have the same local overdensity and scale, we also treat an ensemble of clumps with optical depths set by Markovian statistics. This formalism is then applied to the specific case of bound-free absorption of X- rays in hot star winds, a process not directly affected by clumping in the optically thin limit. We find that the Markov model gives surprisingly similar results to those found previously for the single clump model, suggesting that porous opacity is not very sensitive to details of the assumed clump distribution function. Further, an anisotropic effective opacity favours escape of X-rays emitted in the tangential direction (the venetian blind effect), resulting in a bump of higher flux close to line centre as compared to profiles computed from isotropic porosity models. We demonstrate how this characteristic line shape may be used to diagnose the clump geometry, and we confirm previous results that for optically thick clumping to significantly influence X-ray line profiles, very large porosity lengths, defined as the mean free path between clumps, are required. Moreover, we present the first X-ray line profiles computed directly from line-driven instability simulations using a 3-D patch method, and find that porosity effects from such models also are very small. This further supports the view that porosity has, at most, a marginal effect on X-ray line diagnostics in O stars, and therefore that these diagnostics do indeed provide a good clumping insensitive method for deriving O star mass-loss rates.
Sundqvist, Jon O.; Owocki, Stanley P.; Cohen, David H.; Leutenegger, Maurice A.; Townsend, Richard H. D.
2012-02-01
We present a generalized formalism for treating the porosity-associated reduction in continuum opacity that occurs when individual clumps in a stochastic medium become optically thick. As in previous work, we concentrate on developing bridging laws between the limits of optically thin and thick clumps. We consider geometries resulting in either isotropic or anisotropic effective opacity, and, in addition to an idealized model in which all clumps have the same local overdensity and scale, we also treat an ensemble of clumps with optical depths set by Markovian statistics. This formalism is then applied to the specific case of bound-free absorption of X-rays in hot star winds, a process not directly affected by clumping in the optically thin limit. We find that the Markov model gives surprisingly similar results to those found previously for the single-clump model, suggesting that porous opacity is not very sensitive to details of the assumed clump distribution function. Further, an anisotropic effective opacity favours escape of X-rays emitted in the tangential direction (the 'venetian blind' effect), resulting in a 'bump' of higher flux close to line centre as compared to profiles computed from isotropic porosity models. We demonstrate how this characteristic line shape may be used to diagnose the clump geometry, and we confirm previous results that for optically thick clumping to significantly influence X-ray line profiles, very large porosity lengths, defined as the mean free path between clumps, are required. Moreover, we present the first X-ray line profiles computed directly from line-driven instability simulations using a 3D patch method, and find that porosity effects from such models also are very small. This further supports the view that porosity has, at most, a marginal effect on X-ray line diagnostics in O stars, and therefore that these diagnostics do indeed provide a good 'clumping insensitive' method for deriving O star mass-loss rates.
Effects of anisotropic diffusion and finite island sizes in homoepitaxial growth Pt on Pt(100)-hex
DEFF Research Database (Denmark)
Mortensen, Jens Jørgen; Linderoth, T.R.; Jacobsen, Karsten Wedel;
1998-01-01
The diffusion, nucleation, and growth of Pt on the hexagonally reconstructed Pt(100)-hex surface are investigated. By means of Scanning Tunneling Microscopy (STM), the positions, sizes, and number densities of monoatomically high, rectangular. reconstructed Pt islands, formed in the submonolayer ...... channels. Rate equations incorporating this effect are solved, and a scaling exponent of chi=1/3 is derived in contrast to the chi=1/4 obtained for a 1-D point-island model. (C) 1998 Elsevier Science B.V....
Kwaadgras, B.W.
2013-01-01
We study the polarizability of colloidal particles, as well as their interparticle interactions in the presence or absence of an external electric field. To this end, we employ the Coupled Dipole Method (CDM), which models the particles as clusters of Lorentz atoms (i.e., inducible dipoles) and uses a Hamiltonian approach and large-matrix manipulation to account for all many-atom effects. In this way, we are able to numerically and, in some cases, analytically calculate London-Van der Waals f...
Magnetic fluctuations in anisotropic space plasmas: The effect of the plasma environment
Valdivia, J. A.; Toledo, B. A.; Gallo, N.; Muñoz, V.; Rogan, J.; Stepanova, M.; Moya, P. S.; Navarro, R. E.; Viñas, A. F.; Araneda, J.; López, R. A.; Díaz, M.
2016-11-01
The observations in the solar wind, which are usually organized in a beta-anisotropy diagram, seem to be constrained by linear instability thresholds. Unexpectedly, under these quasi-stable conditions, there is a finite level of electromagnetic fluctuations. A relevant component of these fluctuations can be understood in terms of the electromagnetic fields produced by the thermal motion of the charged particles. For the simple case of parallel propagating fields in an electron-proton plasma, we study the effect of the parameter ωpp /Ωc that characterizes the different space physics environments, and can affect the continuum spectrum produced by these fluctuations, which in turn may be used to understand the relevance of these processes occurring in a specific plasma environment.
Energy Technology Data Exchange (ETDEWEB)
Ranke, P. J. von, E-mail: von.ranke@uol.com.br; Nóbrega, E. P.; Ribeiro, P. O.; Alvarenga, T. S. T.; Lopes, P. H. O.; Sousa, V. S. R. de; Oliveira, N. A. de [Instituto de Física, Universidade do Estado do Rio de Janeiro—UERJ, Rua São Francisco Xavier, 524, 20550-013 Rio de Janeiro (Brazil); Caldas, A. [Sociedade Unificada de Ensino Superior e Cultura, SUESC, 20211-351 Rio de Janeiro (Brazil); Alho, B. P. [Instituto de Aplicação Fernando Rodrigues da Silveira, Universidade do Estado do Rio de Janeiro, Rua Santa Alexandrina, 288, 20260-232 Rio de Janeiro (Brazil); Carvalho, G. [Laboratório Nacional de Luz Sincroton—LNLS, 13083-970 Campinas, São Paulo (Brazil); Magnus, A.
2014-10-14
We report theoretical investigations on the magnetocaloric effect, described by the magnetic entropy change in rare earth—transition metal amorphous systems. The model includes the local anisotropy on the rare earth ions in Harris-Plischke-Zuckermann assumptions. The transition metals ions are treated in terms of itinerant electron ferromagnetism and the magnetic moment of rare earth ions is coupled to the polarized d-band by a local exchange interaction. The magnetocaloric effect was calculated in DyCo{sub 3.4} system, which presents amorphous sperimagnetic configuration. The calculations predict higher refrigerant capacity in the amorphous DyCo{sub 3.4} than in DyCo{sub 2} crystal, highlighting the importance of amorphous magnetocaloric materials. Our calculation of the magnetocaloric effect in Dy{sub 70}Zr{sub 30}, which presents amorphous asperomagnetic configuration, is in good agreement with the experimental result. Furthermore, magnetic entropy changes associated with crystal-amorphous configurations change are estimated.
Rainbow metric from quantum gravity: anisotropic cosmology
Assanioussi, Mehdi; Dapor, Andrea
2016-01-01
In this paper we present a construction of effective cosmological models which describe the propagation of a massive quantum scalar field on a quantum anisotropic cosmological spacetime. Each obtained effective model is represented by a rainbow metric in which particles of distinct momenta propagate on different classical geometries. Our analysis shows that upon certain assumptions and conditions on the parameters determining such anisotropic models, we surprisingly obtain a unique deformatio...
Directory of Open Access Journals (Sweden)
Chi-Ping Lin
2016-02-01
Full Text Available This study simulated the natural convection of dissolved carbon dioxide (CO2 in a small-scale heterogeneous saline formation using the state module ECO2N equation in the TOUGHREACT model. A one-way downscaling approach that involves using a series of sub-models in simulation procedures was proposed to efficiently simulate problems with high-scale discrepancies. This study evaluated the effects of different degrees of small-scale permeability variations on the vertical migration of dissolved CO2. The sequential Gaussian simulation model was used to generate unconditional random permeability fields for different natural logarithm of permeability (lnk variations (i.e., lnk variances and correlations in x and z directions. The results showed an identical transition zone of dissolved CO2 near the top boundary, where a constant CO2 gas saturation was specified. The local permeability variations can trigger fingerings and enhance the vertical convection of the dissolved CO2. The number of fingerings depends on the variations in permeability near the front interface of the dissolved CO2 (i.e., the bottom edge of the transition zone for the dissolved CO2. However, the fingering patterns and developments are constrained by the permeability variations along the fingering paths. At the same mean lnk permeability the convection fluxes increase with an increase in lnk variances. However, an increase in lateral correlations (i.e., increase in the correlation lengths in the x direction can slightly reduce the convection fluxes at the same lnk variance. The highly variable flux rates of the dissolved CO2 occur early and the variations in the flux rate decrease with time.
Energy Technology Data Exchange (ETDEWEB)
Berryman, J.G.
2010-06-01
The mechanics of vertically layered porous media has some similarities to and some differences from the more typical layered analysis for purely elastic media. Assuming welded solid contact at the solid-solid interfaces implies the usual continuity conditions, which are continuity of the vertical (layering direction) stress components and the horizontal strain components. These conditions are valid for both elastic and poroelastic media. Differences arise through the conditions for the pore pressure and the increment of fluid content in the context of fluid-saturated porous media. The two distinct conditions most often considered between any pair of contiguous layers are: (1) an undrained fluid condition at the interface, meaning that the increment of fluid content is zero (i.e., {delta}{zeta} = 0), or (2) fluid pressure continuity at the interface, implying that the change in fluid pressure is zero across the interface (i.e., {delta}p{sub f} = 0). Depending on the types of measurements being made on the system and the pertinent boundary conditions for these measurements, either (or neither) of these two conditions might be directly pertinent. But these conditions are sufficient nevertheless to be used as thought experiments to determine the expected values of all the poroelastic coefficients. For quasi-static mechanical changes over long time periods, we expect drained conditions to hold, so the pressure must then be continuous. For high frequency wave propagation, the pore-fluid typically acts as if it were undrained (or very nearly so), with vanishing of the fluid increment at the boundaries being appropriate. Poroelastic analysis of both these end-member cases is discussed, and the general equations for a variety of applications to heterogeneous porous media are developed. In particular, effective stress for the fluid permeability of such poroelastic systems is considered; fluid permeabilities characteristic of granular media or tubular pore shapes are treated
Influence of heat treatment on the magnetic and magnetocaloric properties in Nd0.6Sr0.4MnO3 compound
Ahmed, A. M.; Mohamed, H. F.; Diab, A. K.; Mohamed, Sara A.; García-Granda, S.; Martínez-Blanco, D.
2016-07-01
In the present investigation, the effect of annealing temperature on the structural, electrical transport and the magnetocaloric effect of Nd0.6Sr0.4MnO3 manganites have been studied. Rietveld refinement of XRD data reveals that all samples are single phase with a space group (Pnma). Heat treatment enhances the grain size and decreases the porosity. All samples suffer Curie transition from ferromagnetic to paramagnetic. Magnetocaloric parameters have been determined by the analysis of isothermal M (H) curves around Curie temperature (ΔH = 2 T) for samples. Heat treatment enhances magnetic entropy, which reaches a maximum at Tan = 900 °C. In addition, the rate cooling power records highest value at Tan = 700 °C.
Magnetic and magnetocaloric properties of martensitic Ni{sub 2}Mn{sub 1.4}Sn{sub 0.6} Heusler alloy
Energy Technology Data Exchange (ETDEWEB)
Chernenko, Volodymyr A., E-mail: vladimir_chernenko@ehu.es [Universidad del Pais Vasco, Dept. Electricidad y Electronica, PO Box 644, Bilbao 48080 (Spain); Ikerbasque, Basque Foundation for Science, Bilbao 48011 (Spain); Barandiaran, Jose M. [Universidad del Pais Vasco, Dept. Electricidad y Electronica, PO Box 644, Bilbao 48080 (Spain); Rodriguez Fernandez, Jesus; Rojas, Daniel P. [CITIMAC, Fac. Ciencias, Univ. Cantabria, Santander 39005 (Spain); Gutierrez, Jon; Lazpita, Patricia [Universidad del Pais Vasco, Dept. Electricidad y Electronica, PO Box 644, Bilbao 48080 (Spain); Orue, Inaki [SGiker, Vicerrectorado de Inv. UPV/EHU, Sarriena s/n, Leioa 48940 (Spain)
2012-10-15
The evolutions of magnetic properties at low temperatures and the influence of magnetic field on the temperature dependence of specific heat in martensitic Ni{sub 2}Mn{sub 1.4}Sn{sub 0.6} Heusler alloy are studied. The frequency-dependent blocking temperature and considerable exchange bias below it are measured in the martensitic phase. From the analysis of the specific heat curves under magnetic field, a large inverse magnetocaloric effect manifested as the magnetic field induced rise of isothermal magnetic entropy and/or magnetic field induced adiabatic temperature decrease in the vicinity of the reverse magnetostructural transformation and a significant value of the conventional magnetocaloric effect at the Curie temperature are obtained. The Debye temperature and electronic coefficient equal to {Theta}{sub D}=310{+-}2 K and {gamma}= 16.6{+-}0.3 mJ/K{sup 2}mol, respectively, do not depend on the magnetic field.
Estimation of magnetocaloric properties by using Monte Carlo method for AMRR cycle
Arai, R.; Tamura, R.; Fukuda, H.; Li, J.; Saito, A. T.; Kaji, S.; Nakagome, H.; Numazawa, T.
2015-12-01
In order to achieve a wide refrigerating temperature range in magnetic refrigeration, it is effective to layer multiple materials with different Curie temperatures. It is crucial to have a detailed understanding of physical properties of materials to optimize the material selection and the layered structure. In the present study, we discuss methods for estimating a change in physical properties, particularly the Curie temperature when some of the Gd atoms are substituted for non-magnetic elements for material design, based on Gd as a ferromagnetic material which is a typical magnetocaloric material. For this purpose, whilst making calculations using the S=7/2 Ising model and the Monte Carlo method, we made a specific heat measurement and a magnetization measurement of Gd-R alloy (R = Y, Zr) to compare experimental values and calculated ones. The results showed that the magnetic entropy change, specific heat, and Curie temperature can be estimated with good accuracy using the Monte Carlo method.
Trassinelli, M.; Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D.
2014-02-01
We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.
Energy Technology Data Exchange (ETDEWEB)
Trassinelli, M., E-mail: martino.trassinelli@insp.jussieu.fr; Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D. [CNRS, UMR 7588, Institut des NanoSciences de Paris (INSP), F-75005 Paris (France); Sorbonne Universités, UPMC Univ. Paris 06, UMR 7588, INSP, F-75005 Paris (France)
2014-02-24
We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.
Anisotropic Stars II Stability
Dev, K; Dev, Krsna; Gleiser, Marcelo
2003-01-01
We investigate the stability of self-gravitating spherically symmetric anisotropic spheres under radial perturbations. We consider both the Newtonian and the full general-relativistic perturbation treatment. In the general-relativistic case, we extend the variational formalism for spheres with isotropic pressure developed by Chandrasekhar. We find that, in general, when the tangential pressure is greater than the radial pressure, the stability of the anisotropic sphere is enhanced when compared to isotropic configurations. In particular, anisotropic spheres are found to be stable for smaller values of the adiabatic index $\\gamma$.
MnxZn1-xFe2-yRyO4 (R = Gd, Eu) Ferrite Nanocrystals for Potential Magnetocaloric Applications
Calderon-Ortiz, Eric; Perales-Perez, Oscar; Voyles, P.; Gutierrez, Gustavo; Tomar, M. S.
2007-01-01
The use of a ferromagnetic fluid for cooling applications represents an encouraging alternative to traditional methods ; the fact that the fluid can be pumped with no moving mechanical parts, using the magnetocaloric effect, can be a great advantage for many applications where high maintenance costs and power consumption are undesirable. The nanocrystalline material suitable for this specific application must exhibit certain specific properties, such as tunable Curie temperature (Tc) and high...
Directory of Open Access Journals (Sweden)
S.N. Gaikwad
2014-01-01
Full Text Available In this paper, we have investigated theoretically the effect of Soret parameter on the onset of double diffusive rotating anisotropic convection in a horizontal sparsely packed porous layer using linear stability theory which is based on the usual normal mode technique. The Brinkman model that includes the Coriolis term is employed for the momentum equation. The effect of anisotropy parameters, Soret parameter, solute Rayleigh number, Taylor number, Lewis number, Darcy and Darcy Prandtl number on stationary and oscillatory convection is shown graphically.
Order-disorder transition of vortex matter in Mg{sub 0.9}B{sub 2}: anisotropic effects
Energy Technology Data Exchange (ETDEWEB)
Oliveira, A A M; Ortiz, W A [Grupo de Supercondutividade e Magnetismo, Departamento de Fisica, Universidade Federal de Sao Carlos, SP (Brazil); Sharma, P A; Hur, N; Cheong, S-W, E-mail: ana@df.ufscar.b, E-mail: ana@df.ufscar.b [Rutgers Center for Emergent Materials and Department of Physics and Astronomy, Rutgers, NJ (United States)
2009-03-01
Third-harmonic susceptibility studies have been employed to probe the order-disorder transition of Vortex Matter of a magnesium-deficient sample of MgB{sub 2}. Our results reveal that the measured threshold is anisotropic for different orientations of the applied magnetic field, suggesting that the pinning efficiency of the magnesium-deficient regions depend on the orientation of the penetrated vortices.
Directory of Open Access Journals (Sweden)
U. C. Hasar
2015-01-01
Full Text Available We propose a retrieval method for reference-plane-invariant electromagnetic parameter measurements of bi-anisotropic metamaterial slabs without resorting to accurate information of the slab thickness and the branch index. To extract reference-plane distances, the slab thickness, and the branch index, we first approximate wave impedances and refractive index away from the slab resonance frequency and then use scattering parameters to calculate the refractive index and the branch index. Once these quantities are determined, they are used as inputs for the retrieval of electromagnetic properties of slabs over the whole band. Different approximations for refractive index and wave impedances are applied to demonstrate the applicability and accuracy of our proposed method. We tested our method for electromagnetic parameter extraction of bi-anisotropic split-ring-resonator and Omega-shaped MM slabs with different number of unit cells. From our analysis, we note that inaccurate information of reference-plane distances, the slab length, and the branch index not only changes the amplitude but also shifts the response of the electromagnetic properties. We show that the presented method can be applied for accurate electromagnetic parameter extraction of bi-anisotropic MM slabs.
Evidence of a canted magnetic state in self-doped LaMnO3+δ (δ = 0.04): a magnetocaloric study
International Nuclear Information System (INIS)
We report a detailed investigation of the magnetocaloric properties of self-doped polycrystalline LaMnO3+δ with δ = 0.04. Due to the self-doping effect, the system exhibits a magnetic transition from a paramagnetic to ferromagnetic-like canted magnetic state (CMS) at ∼120 K, which is associated with an appreciably large magnetocaloric effect (MCE). The CMS is an inhomogeneous magnetic phase developing due to a steady growth of antiferromagnetic correlation in its predominant ferromagnetic state below ∼120 K. The stabilization of CMS in this material is concluded from a comprehensive analysis of magnetocaloric data using Landau theory, which is in excellent agreement with our neutron diffraction study. The magnetic entropy change versus temperature curves for different applied fields collapse into a single curve, revealing a universal behavior of MCE. Our studies suggest that investigation of MCE is an effective technique to acquire fundamental understanding about the basic magnetic structure of a system with complex competing interactions.
Performance-oriented Analysis of a Hybrid magnetic Assembly for a Heat-pump Magnetocaloric Device
DEFF Research Database (Denmark)
Insinga, Andrea Roberto; Smith, Anders; Bahl, Christian R.H.;
2014-01-01
Conventional active-regenerator magnetocaloric devices include moving parts, with the purpose of generating an oscillating magnetic field in the magneto-caloric material, placed inside the regenerator. In this work a different design is analyzed, for application in a magnetocaloric heat pump....... In this design all the parts of the machine are static and the oscillating field is generated by varying the currents of electromagnets included in the hybrid magnetic assembly. The use of different permanent magnet materials is compared with the perspective of maximizing the coefficient of performance...
Placidi, Luca; Seddik, Hakime; Faria, Sergio H
2009-01-01
A complete theoretical presentation of the CAFFE model (Continuum-mechanical, Anisotropic Flow model, based on an anisotropic Flow Enhancement factor) is given. The CAFFE model is an application of the theory of mixtures with continuous diversity for the case of large ice masses in which the induced anisotropy can not be neglected. The anisotropic response of the material is considered via a simple anisotropic generalization of Glen's flow law based on a scalar anisotropic enhancement factor. Such an enhancement factor depends upon the orientation mass density, that corresponds to the distribution of lattice orientations or simply to the orientation distribution function. The evolution of anisotropy is assumed to be modeled by the evolution of the orientation mass density, that is governed by the balance of mass of the present mixture with continuous diversity and explicitly depends upon four distinct effects interpreted, respectively, with grain rotation, local rigid body rotation, grain boundary migration (...
Anisotropic Contrast Optical Microscope
Peev, D; Kananizadeh, N; Wimer, S; Rodenhausen, K B; Herzinger, C M; Kasputis, T; Pfaunmiller, E; Nguyen, A; Korlacki, R; Pannier, A; Li, Y; Schubert, E; Hage, D; Schubert, M
2016-01-01
An optical microscope is described that reveals contrast in the Mueller matrix images of a thin, transparent or semi-transparent specimen located within an anisotropic object plane (anisotropic filter). The specimen changes the anisotropy of the filter and thereby produces contrast within the Mueller matrix images. Here we use an anisotropic filter composed of a semi-transparent, nanostructured thin film with sub-wavelength thickness placed within the object plane. The sample is illuminated as in common optical microscopy but the light is modulated in its polarization using combinations of linear polarizers and phase plate (compensator) to control and analyze the state of polarization. Direct generalized ellipsometry data analysis approaches permit extraction of fundamental Mueller matrix object plane images dispensing with the need of Fourier expansion methods. Generalized ellipsometry model approaches are used for quantitative image analyses. We demonstrate the anisotropic contrast optical microscope by mea...
The new ternary silicide Gd5CoSi2: Structural, magnetic and magnetocaloric properties
International Nuclear Information System (INIS)
Gd5CoSi2 was prepared by annealing at 1003 K. Its investigation by the X-ray powder diffraction shows that the ternary silicide crystallizes in a tetragonal structure deriving from the Cr5B3-type (I4/mcm space group; a=7.5799(4) and c=13.5091(12) A as unit cell parameters). The Rietveld refinement shows a mixed occupancy on the (8h) site between Si and Co atoms. Magnetization and specific heat measurements performed on Gd5CoSi2 reveal a ferromagnetic behaviour below TC=168 K. This magnetic ordering is associated to an interesting magnetocaloric effect; the adiabatic temperature change ΔTad is about 3.1 and 5.9 K, respectively, for a magnetic field change of 2 and 4.6 T. -- Graphical abstract: The adiabatic temperature change ΔTad was determined by combining the heat capacity measurements and the magnetization data. As expected, a peak near the Curie temperature of the Gd5CoSi2 ternary silicide is observed, with a maximum of ΔTad around 3.1 and 5.9 K for ΔH=2 and 4.6 T, respectively. Display Omitted Research Highlights: → We prepare and characterize for the first time the ternary silicide Gd5CoSi2. → Gd5CoSi2 crystallizes in the tetragonal structure deriving from the Cr5B3-type. → Gd5CoSi2 shows a ferromagnetic behaviour below 168 K associated with magnetocaloric properties.
Jeppesen, Claus; Flyvbjerg, Henrik; Mouritsen, Ole G.
1989-11-01
Monte Carlo computer-simulation techniques are used to elucidate the equilibrium phase behavior as well as the late-stage ordering dynamics of some two-dimensional models with ground-state ordering of a high degeneracy Q. The models are Q-state Potts models with anisotropic grain-boundary potential on triangular lattices-essentially clock models, except that the potential is not a cosine, but a sine function of the angle between neighboring grain orientations. For not too small Q, these models display two thermally driven phase transitions, one which takes the system from a low-temperature Potts-ordered phase to an intermediate phase which lacks conventional long-range order, and another transition which takes the system to the high-temperature disordered phase. The linear nature of the sine potential used makes it a marginal case in the sense that it favors neither hard domain boundaries, like the standard Potts models do, nor a wetting of the boundaries, as the standard clock models do. Thermal fluctuations nevertheless cause wetting to occur for not too small temperatures. Specifically, we have studied models with Q=12 and 48. The models are quenched from infinity to zero as well as finite temperatures within the two low-temperature phases. The order parameter is a nonconserved quantity during these quenches. The nonequilibrium ordering process subsequent to the quench is studied as a function of time by calculating the interfacial energy, ΔE, associated with the entire grain-boundary network. The time evolution of this quantity is shown to obey the growth law, ΔE(t)~t-n, over an extended time range at late times. It is found that the zero-temperature dynamics is characterized by a special exponent value which for the Q=48 model is n~=0.25 in accordance with earlier work. However, for quenches to finite temperatures in the Potts-ordered phase there is a distinct crossover to the classical Lifshitz-Allen-Cahn exponent value, n=(1/2, for both values of Q. This
Anisotropic pressure and hyperons in neutron stars
Sulaksono, A
2014-01-01
We study the effects of anisotropic pressure on properties of the neutron stars with hyperons inside its core within the framework of extended relativistic mean field. It is found that the main effects of anisotropic pressure on neutron star matter is to increase the stiffness of the equation of state, which compensates for the softening of the EOS due to the hyperons. The maximum mass and redshift predictions of anisotropic neutron star with hyperonic core are quite compatible with the result of recent observational constraints if we use the parameter of anisotropic pressure model $h \\le 0.8$[1] and $\\Lambda \\le -1.15$ [2]. The radius of the corresponding neutron star at $M$=1.4 $M_\\odot$ is more than 13 km, while the effect of anisotropic pressure on the minimum mass of neutron star is insignificant. Furthermore, due to the anisotropic pressure in the neutron star, the maximum mass limit of higher than 2.1 $M_\\odot$ cannot rule out the presence of hyperons in the neutron star core.
Directory of Open Access Journals (Sweden)
Christianto V.
2007-04-01
Full Text Available In the light of some recent hypotheses suggesting plausible unification of thermostatistics where Fermi-Dirac, Bose-Einstein and Tsallis statistics become its special subsets, we consider further plausible extension to include non-integer Hausdorff dimension, which becomes realization of fractal entropy concept. In the subsequent section, we also discuss plausible extension of this unified statistics to include anisotropic effect by using quaternion oscillator, which may be observed in the context of Cosmic Microwave Background Radiation. Further observation is of course recommended in order to refute or verify this proposition.
Phase control studies in Gd{sub 5}Si{sub 2}Ge{sub 2} giant magnetocaloric compound
Energy Technology Data Exchange (ETDEWEB)
Belo, J.H. [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Fisica e Astronomia, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Pereira, A.M., E-mail: ampereira@fc.up.pt [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Fisica e Astronomia, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Ventura, J.; Oliveira, G.N.P. [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Fisica e Astronomia, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Araujo, J.P., E-mail: jearaujo@fc.up.pt [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Fisica e Astronomia, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Tavares, P.B.; Fernandes, L. [Departamento de Quimica and CQ-VR, Universidade de Tras-os-Montes e Alto Douro, 5001-801 Vila Real (Portugal); Algarabel, P.A. [Instituto de Ciencia de Materiales de Aragon, Universidad de Zaragoza and Consejo Superior de Investigaciones Cientificas, 50009 Zaragoza (Spain); Magen, C. [Instituto de Nanociencia de Aragon-ARAID, Universidad de Zaragoza, 50009 Zaragoza (Spain); Morellon, L. [Instituto de Ciencia de Materiales de Aragon, Universidad de Zaragoza and Consejo Superior de Investigaciones Cientificas, 50009 Zaragoza (Spain); Instituto de Nanociencia de Aragon, Universidad de Zaragoza, 50009 Zaragoza (Spain); and others
2012-07-15
Highlights: Black-Right-Pointing-Pointer Study of time dependence of O(I) to M phase. Black-Right-Pointing-Pointer Determination of the optimal annealing time. Black-Right-Pointing-Pointer New method for phase amount estimation (O(I) and M). Black-Right-Pointing-Pointer Effect of annealing on the MCE. Black-Right-Pointing-Pointer Analysis of the nature of the magnetic transition through the Arrot plot representation. - Abstract: A systematic set of annealings on arc-melted synthesized Gd{sub 5}Si{sub 2}Ge{sub 2} sample was performed. Through powder X-ray diffraction (XRD) and magnetometry measurements we monitored the effect of varying the annealing time with constant temperature (T = 1473 K) on the formation of the monoclinic (M) crystallographic phase fraction, which is the one responsible for the giant magnetocaloric effect (GMCE) in this compound. The conversion of the orthorhombic O(I) crystallographic phase into M was achieved, resulting in a significant increase of the M mass fraction. Such conversion led to a change in the magnetic transition nature, evolving from a second to a first order transition for the as-cast and annealed samples, respectively. An optimal annealing time range for the M phase conversion was identified to be within 80-120 min at T = 1473 K followed by a rapid quenching to liquid N{sub 2}. Furthermore, an increase up to {approx}50% of the magnetocaloric effect was obtained for the sample annealed during 120 min.
Energy Technology Data Exchange (ETDEWEB)
Pathak, Arjun K., E-mail: pathak@siu.ed [Department of Physics, Southern Illinois University Carbondale, 1245 Lincoln Dr., Carbondale, IL 62901 (United States); Basnyat, Prakash; Dubenko, Igor [Department of Physics, Southern Illinois University Carbondale, 1245 Lincoln Dr., Carbondale, IL 62901 (United States); Stadler, Shane [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Ali, Naushad [Department of Physics, Southern Illinois University Carbondale, 1245 Lincoln Dr., Carbondale, IL 62901 (United States)
2010-03-15
We have studied the magnetic, magnetocaloric, and magnetostriction properties of LaFe{sub 11.4}Si{sub 1.6} and La(Fe{sub 0.99}Z{sub 0.01}){sub 11.4}Si{sub 1.6} (Z=Ni, Cu, Cr, V) compounds using magnetization and strain gauge techniques. It was found that substitution of 1% of the Fe by Z-elements results in an increase in the Curie temperature (T{sub C}), and affects the magnetostriction and magnetocaloric properties of the parent compound, LaFe{sub 11.4}Si{sub 1.6}. A maximum shift in T{sub C} of about 11 K, and significantly smaller hysteresis losses in the vicinity of T{sub C} compared with those of the base compound, were found for Z=V. The maximum magnetovolume coupling constant was estimated to be n{sub dd}approx2.7x10{sup -3} (mu{sub B}/Fe atom){sup -2} for the parent compound. The changes in the volume magnetostriction, the magnetovolume coupling constant, and the magnetocaloric properties are strongly correlated with composition. The relative effects of the variation in cell parameters and electron concentration on the magnetostriction, T{sub C}, and the magnetocaloric properties are discussed.
International Nuclear Information System (INIS)
We have studied the magnetic, magnetocaloric, and magnetostriction properties of LaFe11.4Si1.6 and La(Fe0.99Z0.01)11.4Si1.6 (Z=Ni, Cu, Cr, V) compounds using magnetization and strain gauge techniques. It was found that substitution of 1% of the Fe by Z-elements results in an increase in the Curie temperature (TC), and affects the magnetostriction and magnetocaloric properties of the parent compound, LaFe11.4Si1.6. A maximum shift in TC of about 11 K, and significantly smaller hysteresis losses in the vicinity of TC compared with those of the base compound, were found for Z=V. The maximum magnetovolume coupling constant was estimated to be ndd∼2.7x10-3 (μB/Fe atom)-2 for the parent compound. The changes in the volume magnetostriction, the magnetovolume coupling constant, and the magnetocaloric properties are strongly correlated with composition. The relative effects of the variation in cell parameters and electron concentration on the magnetostriction, TC, and the magnetocaloric properties are discussed.
Jeppesen, Claus; Flyvbjerg, Henrik; Ole G. Mouritsen
1989-01-01
Monte Carlo computer-simulation techniques are used to elucidate the equilibrium phase behavior as well as the late-stage ordering dynamics of some two-dimensional models with ground-state ordering of a high degeneracy, Q. The models are Q-state Potts models with anisotropic grain-boundary potential on triangular lattices—essentially clock models, except that the potential is not a cosine, but a sine function of the angle between neighboring grain orientations. For not too small Q, these mode...
Searching the conditions for a table-like shape of the magnetic entropy in magneto-caloric materials
Energy Technology Data Exchange (ETDEWEB)
Álvarez, Pablo, E-mail: pablo.alvarez@ehu.es [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48940 Leioa (Spain); Departamento de Física, Universidad de Oviedo, c/ Calvo Sotelo, s/n, 33007 Oviedo (Spain); Gorria, Pedro, E-mail: pgorria@uniovi.es [Departamento de Física, Universidad de Oviedo, c/ Calvo Sotelo, s/n, 33007 Oviedo (Spain); Sánchez Llamazares, José L. [División de Materiales Avanzados, Instituto Potosino de Investigación Científica y Tecnológica, Camino a la presa San José 2055, CP 78216 San Luis Potosí (Mexico); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, c/ Calvo Sotelo, s/n, 33007 Oviedo (Spain)
2013-08-15
Highlights: •The magnetic entropy change for two-ribbon (amorphous) composite materials is investigated. •The conditions to obtain a table-like shape of the magnetic entropy change are specified. •We give the essential ingredients to maximize the effective refrigerant capacity and the efficiency. •Our findings could be used in other magneto-caloric materials to tune the temperature range for the table-like behavior. -- Abstract: We show a systematic study of the magneto-caloric response carried out on a series of FeZrB(Cu) amorphous ribbons with different Curie temperature values in the 210–320 K interval. The main aim of the work is to investigate the conditions to obtain, from the isothermal magnetic entropy change vs. temperature curves, ΔS{sub M}(T), a table-like behavior of the entropy using two-ribbon composites. Even though the maximum value of ΔS{sub M} for the composite is lower than those of the single components, the existence of a table-like behavior maximizes the effective refrigerant capacity, reaching values around 80 J/kg for an applied magnetic field change of 2 T. Furthermore, we discuss how the temperature range for such a table-like behavior can be tuned and the refrigerant capacity enhanced in terms of energy efficiency.
Large reversible caloric effect in FeRh thin films via a dual-stimulus multicaloric cycle
Liu, Yang; Phillips, Lee C; Mattana, Richard; Bibes, Manuel; Barthélémy, Agnès; Dkhil, Brahim
2016-01-01
Giant magnetocaloric materials are promising for solid-state refrigeration, as an alternative to hazardous gases used in conventional cooling devices. A giant magnetocaloric effect was discovered near room temperature in near-equiatomic FeRh alloys some years before the benchmark study in Gd5Si2Ge2 that launched the field. However, FeRh has attracted significantly less interest in cooling applications mainly due to irreversibility in magnetocaloric cycles associated with the large hysteresis ...
Directory of Open Access Journals (Sweden)
V. A. Shulepov
2016-05-01
Full Text Available The paper deals with optical scheme for research of polarization state transformation at the junction of anisotropic waveguides. It consists of a light source, polarization controller, multifunctional integrated optical scheme (MIOS, single-mode fiber for input and output of optical radiation in MIOS and the polarization scanning Michelson interferometer. Optical radiation from the source of the plant comes through the polarization controller in one of the MIOS ports. Further, in one of the opposite ports the radiation is received by different fibers, polished at the angles of 19.5˚, 10.5˚ and 0˚. After that, the optical radiation gets into polarization Michelson interferometer. With that, the picture visibility is analyzed at different displacement of one arm upon which the value has been determined in the polarization conversion point connections. At the course of work it was obtained that the polarization state conversion at a splicing point rises with the slant angle deviation from its optimal value. Anisotropic waveguides splicing is one of the main tasks during fabrication of any fiber-optic sensor with integrated optical elements. The results of this work are of great interest for the wide range of specialists in the optical waveguides application field.
McLeod, M.V.; Giri, A. K.; Paterson, B. A.; Dennis, C. L.; Zhou, L.; Vogel, S.C.; Gourdon, O.; Reiche, H. M.; Cho, K.C.; Sohn, Y. H.; Shull, R. D.; Majumdar, B.S.
2016-01-01
Currently, there is significant interest in magnetocaloric materials for solid state refrigeration. In this work, polycrystalline Heusler alloys belonging to the Ni2+xMn1−xGa family, with x between 0.08 and 0.24, were evaluated for the purpose of finding composition(s) with an enhanced magnetocaloric effect (MCE) close to room temperature. Differential scanning calorimetry (DSC) was successfully used to screen alloy composition for simultaneous magnetic and structural phase transformations; this coupling needed for a giant MCE. The alloy with x = 0.16 showed an excellent match of transformation temperatures and exhibited the highest magnetic entropy change, ΔSM, in the as-annealed state. Furthermore, the MCE increased by up to 84 % with a 2 Tesla (T) field change when the samples were thermally cycled through the martensite to austenite transformation temperature while held under a constant mechanical load. The highest ΔSM measured for our x = 0.16 alloy for a 2 T magnetic field change was −18 J/kg-K. Texture measurements suggest that preferential orientation of martensite variants contributed to the enhanced MCE in the stress-assisted thermally cycled state. PMID:27099566
Hwu, Chyanbin
2010-01-01
As structural elements, anisotropic elastic plates find wide applications in modern technology. The plates here are considered to be subjected to not only in plane load but also transverse load. In other words, both plane and plate bending problems as well as the stretching-bending coupling problems are all explained in this book. In addition to the introduction of the theory of anisotropic elasticity, several important subjects have are discussed in this book such as interfaces, cracks, holes, inclusions, contact problems, piezoelectric materials, thermoelastic problems and boundary element a
Pérez-Nadal, Guillem
2016-01-01
We consider a non-relativistic free scalar field theory with a type of anisotropic scale invariance in which the number of coordinates "scaling like time" is generically greater than one. We propose the Cartesian product of two curved spaces, with the metric of each space parameterized by the other space, as a notion of curved background to which the theory can be extended. We study this type of geometries, and find a family of extensions of the theory to curved backgrounds in which the anisotropic scale invariance is promoted to a local, Weyl-type symmetry.
Anisotropic models for compact stars
Maurya, S K; Ray, Saibal; Dayanandan, Baiju
2015-01-01
In the present paper we obtain an anisotropic analogue of Durgapal-Fuloria (1985) perfect fluid solution. The methodology consists of contraction of anisotropic factor $\\Delta$ by the help of both metric potentials $e^{\
Indian Academy of Sciences (India)
B B Bhowmik; A Rajput
2004-06-01
Anisotropic Bianchi Type-I cosmological models have been studied on the basis of Lyra's geometry. Two types of models, one with constant deceleration parameter and the other with variable deceleration parameter have been derived by considering a time-dependent displacement field.
Dynamics of Anisotropic Universes
Pérez, J
2006-01-01
We present a general study of the dynamical properties of Anisotropic Bianchi Universes in the context of Einstein General Relativity. Integrability results using Kovalevskaya exponents are reported and connected to general knowledge about Bianchi dynamics. Finally, dynamics toward singularity in Bianchi type VIII and IX universes are showed to be equivalent in some precise sence.
Magnetocaloric properties of a frustrated Blume-Capel antiferromagnet
Directory of Open Access Journals (Sweden)
Žukovič Milan
2014-07-01
Full Text Available Low-temperature magnetization processes and magnetocaloric properties of a geometrically frustrated spin-1 Blume-Capel model on a triangular lattice are studied by Monte Carlo simulations. The model is found to display qualitatively different behavior depending on the sign of the single-ion anisotropy D. For positive values of D we observe two magnetization plateaus, similar to the spin-1/2 Ising antiferromagnet, and negative isothermal entropy changes for any field intensity. For a range of small negative values of D there are four magnetization plateaus and the entropy changes can be either negative or positive, depending on the field. If D is negative but large in absolute value then the entropy changes are solely positive.
Zhao, Ying-Ying; Wang, Jing; Kuang, Hao; Hu, Feng-Xia; Liu, Yao; Wu, Rong-Rong; Zhang, Xi-Xiang; Sun, Ji-Rong; Shen, Bao-Gen
2015-04-01
Memory effect of electric-field control on magnetic behavior in magnetoelectric composite heterostructures has been a topic of interest for a long time. Although the piezostrain and its transfer across the interface of ferroelectric/ferromagnetic films are known to be important in realizing magnetoelectric coupling, the underlying mechanism for nonvolatile modulation of magnetic behaviors remains a challenge. Here, we report on the electric-field control of magnetic properties in wide-band (011)-Pr0.7Sr0.3MnO3/0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 heterostructures. By introducing an electric-field-induced in-plane anisotropic strain field during the cooling process from room temperature, we observe an in-plane anisotropic, nonvolatile modulation of magnetic properties in a wide-band Pr0.7Sr0.3MnO3 film at low temperatures. We attribute this anisotropic memory effect to the preferential seeding and growth of ferromagnetic (FM) domains under the anisotropic strain field. In addition, we find that the anisotropic, nonvolatile modulation of magnetic properties gradually diminishes as the temperature approaches FM transition, indicating that the nonvolatile memory effect is temperature dependent. By taking into account the competition between thermal energy and the potential barrier of the metastable magnetic state induced by the anisotropic strain field, this distinct memory effect is well explained, which provides a promising approach for designing novel electric-writing magnetic memories.
Zhao, Ying-Ying
2015-04-24
Memory effect of electric-field control on magnetic behavior in magnetoelectric composite heterostructures has been a topic of interest for a long time. Although the piezostrain and its transfer across the interface of ferroelectric/ferromagnetic films are known to be important in realizing magnetoelectric coupling, the underlying mechanism for nonvolatile modulation of magnetic behaviors remains a challenge. Here, we report on the electric-field control of magnetic properties in wide-band (011)-Pr0.7Sr0.3MnO3/0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 heterostructures. By introducing an electric-field-induced in-plane anisotropic strain field during the cooling process from room temperature, we observe an in-plane anisotropic, nonvolatile modulation of magnetic properties in a wide-band Pr0.7Sr0.3MnO3 film at low temperatures. We attribute this anisotropic memory effect to the preferential seeding and growth of ferromagnetic (FM) domains under the anisotropic strain field. In addition, we find that the anisotropic, nonvolatile modulation of magnetic properties gradually diminishes as the temperature approaches FM transition, indicating that the nonvolatile memory effect is temperature dependent. By taking into account the competition between thermal energy and the potential barrier of the metastable magnetic state induced by the anisotropic strain field, this distinct memory effect is well explained, which provides a promising approach for designing novel electric-writing magnetic memories.
Spin precession in anisotropic cosmologies
Energy Technology Data Exchange (ETDEWEB)
Kamenshchik, A.Yu. [Universita di Bologna, Dipartimento di Fisica e Astronomia, Bologna (Italy); L. D. Landau Institute for Theoretical Physics, Moscow (Russian Federation); INFN, Bologna (Italy); Teryaev, O.V. [Joint Institute for Nuclear Research, Bogoliubov Laboratory of Theoretical Physics, Dubna (Russian Federation); Lomonosov Moscow State University, Moscow (Russian Federation)
2016-05-15
We consider the precession of a Dirac particle spin in some anisotropic Bianchi universes. This effect is present already in the Bianchi-I universe. We discuss in some detail the geodesics and the spin precession for both the Kasner and the Heckmann-Schucking solutions. In the Bianchi-IX universe the spin precession acquires the chaotic character due to the stochasticity of the oscillatory approach to the cosmological singularity. The related helicity flip of fermions in the very early universe may produce the sterile particles contributing to dark matter. (orig.)
Anisotropic matching principle for the hydrodynamic expansion
Tinti, Leonardo
2016-10-01
Following the recent success of anisotropic hydrodynamics, I propose here a new, general prescription for the hydrodynamic expansion around an anisotropic background. The anisotropic distribution fixes exactly the complete energy-momentum tensor, just like the effective temperature fixes the proper energy density in the ordinary expansion around local equilibrium. This means that momentum anisotropies are already included at the leading order, allowing for large pressure anisotropies without the need of a next-to-leading-order treatment. The first moment of the Boltzmann equation (local four-momentum conservation) provides the time evolution of the proper energy density and the four-velocity. Differently from previous prescriptions, the dynamic equations for the pressure corrections are not derived from the zeroth or second moment of the Boltzmann equation, but they are taken directly from the exact evolution given by the Boltzmann equation. As known in the literature, the exact evolution of the pressure corrections involves higher moments of the Boltzmann distribution, which cannot be fixed by the anisotropic distribution alone. Neglecting the next-to-leading-order contributions corresponds to an approximation, which depends on the chosen form of the anisotropic distribution. I check the the effectiveness of the leading-order expansion around the generalized Romatschke-Stricklad distribution, comparing with the exact solution of the Boltzmann equation in the Bjorken limit with the collisional kernel treated in the relaxation-time approximation, finding an unprecedented agreement.
Bouncing Anisotropic Universes with Varying Constants
Barrow, John D
2013-01-01
We examine the evolution of a closed, homogeneous and anisotropic cosmology subject to a variation of the fine structure 'constant', \\alpha, within the context of the theory introduced by Bekenstein, Sandvik, Barrow and Magueijo, which generalises Maxwell's equations and general relativity. The variation of \\alpha permits an effective ghost scalar field, whose negative energy density becomes dominant at small length scales, leading to a bouncing cosmology. A thermodynamically motivated coupling which describes energy exchange between the effective ghost field and the radiation field leads to an expanding, isotropizing sequence of bounces. In the absence of entropy production we also find solutions with stable anisotropic oscillations around a static universe.
Energy Technology Data Exchange (ETDEWEB)
Mahjoub, Saoussen, E-mail: mahjoub.sawssen@gmail.com [Laboratoire de Physico-Chimie des Matériaux, Département de Physique, Faculté des Sciences de Monastir, Université de Monastir, 5019 Monastir (Tunisia); Baazaoui, Mohamed [Laboratoire de Physico-Chimie des Matériaux, Département de Physique, Faculté des Sciences de Monastir, Université de Monastir, 5019 Monastir (Tunisia); M’nassri, Rafik [Higher Institute of Applied Sciences and Technology of Kasserine, Kairouan University, Route Feriana, 1200 Kasserine (Tunisia); Rahmouni, Hedi [Laboratoire de Physique des Matériaux et des Nanomatériaux appliquée à l’Environnement, Faculté des Sciences de Gabès cité Erriadh, Université de Gabès, 6079 Gabès (Tunisia); Boudjada, Nassira Chniba [Institut NEEL, B.P. 166, 38042 Grenoble Cedex 9 (France); Oumezzine, Mohamed [Laboratoire de Physico-Chimie des Matériaux, Département de Physique, Faculté des Sciences de Monastir, Université de Monastir, 5019 Monastir (Tunisia)
2014-09-01
Highlights: • The Pr{sub 0.6}Ca{sub 0.1}Sr{sub 0.3}Mn{sub 1−x}Fe{sub x}O{sub 3} (x = 0, 0.025, 0.05, 0.075) compounds were synthesized using the Pechini sol–gel method. • Large magnetocaloric effect is reported based on second order phase transition. • Noticeable |ΔS{sub M}| at low field makes the system useful for magnetic refrigeration. - Abstract: The effects of partial substitution of manganese by iron on the physical properties of Pr{sub 0.6}Ca{sub 0.1}Sr{sub 0.3}Mn{sub 1−x}Fe{sub x}O{sub 3} (0 ⩽ x ⩽ 0.075) were investigated experimentally. Our samples were synthesized using the Pechini sol–gel method. X-ray diffraction analysis shows that our compounds crystallize in the orthorhombic structure with the Pbnm space group. Magnetic measurements show that all our materials exhibit a paramagnetic–ferromagnetic transition with decreasing temperature. The M(T) curves at μ{sub 0}H = 0.05 T indicate a monotonic drop in the Curie temperature (T{sub C}) from 270 K for x = 0.0–112 K for x = 0.075 as the Fe concentration is increased. The results of electrical resistivity versus temperature measurements show that all our samples exhibit a metallic behavior at low temperature. For higher values of temperature, metal–insulator transition is seen at temperature T{sub p}. From isothermal magnetization versus magnetic applied field, we deduced the magnetic entropy change ΔS{sub M}. The maximum values of the magnetic entropy change (-ΔS{sub M}{sup max}) at 5 T applied change in the magnetic field are 3.64 and 3.12 J/kg K for x = 0 and x = 0.075 samples respectively. Under an applied magnetic field of 5 T, the relative cooling power (RCP) values are found between 243 and 256 J/kg for undoped sample and x = 0.075 respectively. Our results are interesting enough and suggest that these materials may be suitable candidates as working substances in magnetic refrigeration.
International Nuclear Information System (INIS)
Dynamic anisotropic elastic constants of CANDU Zr-2.5Nb pressure tube materials were determined by high temperature resonant ultrasound spectroscopy (RUS). The resonance frequencies were measured using a couple of alumina waveguides and wide-band ultrasonic transducers in a small furnace. The rectangular parallelepiped specimens were fabricated along with the longitudinal, radial and transverse direction of the pressure tube. The initial estimates for RUS were obtained from the orientation distribution function by X-ray pole figure and elastic stiffness of single crystal zirconium. A nine elastic stiffness tensor for orthotropic symmetry was determined in the range of room temperature ∼500 deg. C. As the temperature increases, the elastic constant tensor, cij gradually decreases. Higher elastic constants along the transverse direction compared to those along the longitudinal or radial direction are similar to the case of Young's modulus or shear modulus. A crossing of elastic constants along the longitudinal direction and radial direction was observed near 120-150 deg. C. This fact could correlate to the crossing characteristics of c44 and c66 of a zirconium single crystal in the temperature range
Directory of Open Access Journals (Sweden)
Priyanka Singh
2015-01-01
Full Text Available The strain Bhargavaea indica DC1 isolated from four-year-old P. ginseng rhizospheric soil was used to perform rapid and extracellular biosynthesis of anisotropic silver nanoparticles. The ultraviolet-visible (UV-vis spectra of the reaction mixture containing silver nanoparticles showed a peak at 460 nm, corresponding to the surface plasmon absorbance of silver nanoparticles. Field-emission transmission electron microscopy (FE-TEM structural characterization revealed the nanobar, pentagon, spherical, icosahedron, hexagonal, truncated triangle, and triangular nanoparticles, with the size range from 30 to 100 nm. The energy-dispersive X-ray (EDX analysis and elemental mapping results also confirmed that the silver was the predominant component of isolated nanoparticles. The X-ray diffraction (XRD results correspond to the purity of silver nanoparticles and dynamic light scattering (DLS result indicated that the average diameter of particles was 111.6 nm. In addition, enhancement in antimicrobial activity of commercial antibiotics was observed against various pathogenic microorganisms such as Vibrio parahaemolyticus, Salmonella enterica, Staphylococcus aureus, Bacillus anthracis, Bacillus cereus, Escherichia coli, and Candida albicans.
Inhomogeneous Anisotropic Cosmology
Kleban, Matthew
2016-01-01
In homogeneous and isotropic Friedmann-Robertson-Walker cosmology, the topology of the universe determines its ultimate fate. If the Weak Energy Condition is satisfied, open and flat universes must expand forever, while closed cosmologies can recollapse to a Big Crunch. A similar statement holds for homogeneous but anisotropic (Bianchi) universes. Here, we prove that ${\\it arbitrarily}$ inhomogeneous and anisotropic cosmologies with "flat" (including toroidal) and "open" (including compact hyperbolic) spatial topology that are initially expanding must continue to expand forever at least in some region, despite the presence of arbitrarily large density fluctuations and/or the formation of black holes. Because the set of 3-manifold topologies is countable, a single integer determines the ultimate fate of the universe, and, in a specific sense, most 3-manifolds are "flat" or "open". Our result has important implications for inflation: if there is a positive cosmological constant (or suitable inflationary potenti...
Anisotropic matching principle for the hydrodynamics expansion
Tinti, Leonardo
2015-01-01
Following the recent success of anisotropic hydrodynamics we propose a new, general prescription for the hydrodynamics expansion around an anisotropic background. The anisotropic distribution is fixing exactly the complete energy-momentum tensor, just like the effective temperature is fixing the proper energy density in the ordinary expansion around local equilibrium. This means that momen- tum anisotropies are already included at the leading order, allowing for large pressure anisotropies without the need of a next to leading order treatment. The first moment of the Boltzmann equation (local four-momentum conservation) provides the time evolution of the proper energy density and the four velocity. Differently from previous prescriptions, the dynamic equations for the pressure corrections are not derived from the zeroth or second moment of the Boltzmann equation, but they are taken directly from the exact evolution given by the Boltzmann equation. We check the effec- tiveness of this new approach by matching ...
Quasiparticle anisotropic hydrodynamics for central collisions
Alqahtani, Mubarak; Strickland, Michael
2016-01-01
We use quasiparticle anisotropic hydrodynamics to study an azimuthally-symmetric boost-invariant quark-gluon plasma including the effects of both shear and bulk viscosities. In quasiparticle anisotropic hydrodynamics, a single finite-temperature quasiparticle mass is introduced and fit to the lattice data in order to implement a realistic equation of state. We compare results obtained using the quasiparticle method with the standard method of imposing the equation of state in anisotropic hydrodynamics and viscous hydrodynamics. Using these three methods, we extract the primordial particle spectra, total number of charged particles, and average transverse momentum for various values of the shear viscosity to entropy density ratio eta/s. We find that the three methods agree well for small shear viscosity to entropy density ratio, eta/s, but differ at large eta/s. We find, in particular, that when using standard viscous hydrodynamics, the bulk-viscous correction can drive the primordial particle spectra negative...
CAVITATION BIFURCATION FOR COMPRESSIBLE ANISOTROPIC HYPERELASTIC MATERIALS
Institute of Scientific and Technical Information of China (English)
ChengChangjun; RenJiusheng
2004-01-01
The effect of material anisotropy on the bifurcation for void tormation in anisotropic compressible hyperelastic materials is examined. Numerical solutions are obtained in an anisotropic sphere, whose material is transversely isotropic in the radial direction. It is shown that the bifurcation may occur either to the right or to the left, depending on the degree of material anisotropy. The deformation and stress contribution in the sphere before cavitation are different from those after cavitation. The stability of solutions is discussed through a comparison of energy.
Electromagnetism on anisotropic fractal media
Ostoja-Starzewski, Martin
2013-04-01
Basic equations of electromagnetic fields in anisotropic fractal media are obtained using a dimensional regularization approach. First, a formulation based on product measures is shown to satisfy the four basic identities of the vector calculus. This allows a generalization of the Green-Gauss and Stokes theorems as well as the charge conservation equation on anisotropic fractals. Then, pursuing the conceptual approach, we derive the Faraday and Ampère laws for such fractal media, which, along with two auxiliary null-divergence conditions, effectively give the modified Maxwell equations. Proceeding on a separate track, we employ a variational principle for electromagnetic fields, appropriately adapted to fractal media, so as to independently derive the same forms of these two laws. It is next found that the parabolic (for a conducting medium) and the hyperbolic (for a dielectric medium) equations involve modified gradient operators, while the Poynting vector has the same form as in the non-fractal case. Finally, Maxwell's electromagnetic stress tensor is reformulated for fractal systems. In all the cases, the derived equations for fractal media depend explicitly on fractal dimensions in three different directions and reduce to conventional forms for continuous media with Euclidean geometries upon setting these each of dimensions equal to unity.
Nucleation in suspensions of anisotropic colloids
Schilling, T.; Frenkel, D.
2005-01-01
We report Monte Carlo studies of liquid crystal nucleation in two types of anisotropic colloidal systems: hard rods and hard ellipsoids. In both cases we find that nucleation pathways differ strongly from the pathways in systems of spherical particles. Short hard rods show an effect of self-poisonin
Spin Wave Theory of Strongly Anisotropic Magnets
DEFF Research Database (Denmark)
Lindgård, Per-Anker
1977-01-01
A strong anisotropy gives rise to a non-spherical precession of the spins with different amplitudes in the x and y directions. The highly anharmonic exchange interaction thereby becomes effectively anisotropic. The possibility of detecting a genuine two-ion anisotropy is discussed, and comments a...... are given on the interpretation of the spin wave data in Tb and Er....
Material Induced Anisotropic Damage in DP600
Niazi, M.S.; Wisselink, H.H.; Meinders, V.T.; Boogaard, van den A.H.
2013-01-01
Plasticity induced damage development in metals is anisotropic by nature. The anisotropy in damage is driven by two different phenomena; anisotropic deformation state i.e. Load Induced Anisotropic Damage (LIAD) and anisotropic microstructure i.e. Material Induced Anisotropic Damage (MIAD). The contr
Anisotropic Diffusion in Mesh-Free Numerical Magnetohydrodynamics
Hopkins, Philip F
2016-01-01
We extend recently-developed mesh-free Lagrangian methods for numerical magnetohydrodynamics (MHD) to arbitrary anisotropic diffusion equations, including: passive scalar diffusion, Spitzer-Braginskii conduction and viscosity, cosmic ray diffusion/streaming, anisotropic radiation transport, non-ideal MHD (Ohmic resistivity, ambipolar diffusion, the Hall effect), and turbulent 'eddy diffusion.' We study these as implemented in the code GIZMO for both new meshless finite-volume Godunov schemes (MFM/MFV) as well as smoothed-particle hydrodynamics (SPH). We show the MFM/MFV methods are accurate and stable even with noisy fields and irregular particle arrangements, and recover the correct behavior even in arbitrarily anisotropic cases. They are competitive with state-of-the-art AMR/moving-mesh methods, and can correctly treat anisotropic diffusion-driven instabilities (e.g. the MTI and HBI, Hall MRI). We also develop a new scheme for stabilizing anisotropic tensor-valued fluxes with high-order gradient estimators ...
On the Relativistic anisotropic configurations
Shojai, F; Stepanian, A
2016-01-01
In this paper we study anisotropic spherical polytropes within the framework of general relativity. Using the anisotropic Tolman-Oppenheimer-Volkov (TOV) equations, we explore the relativistic anisotropic Lane-Emden equations. We find how the anisotropic pressure affects the boundary conditions of these equations. Also we argue that the behaviour of physical quantities near the center of star changes in the presence of anisotropy. For constant density, a class of exact solution is derived with the aid of a new ansatz and its physical properties are discussed.
On the relativistic anisotropic configurations
Energy Technology Data Exchange (ETDEWEB)
Shojai, F. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of); Institute for Research in Fundamental Sciences (IPM), Foundations of Physics Group, School of Physics, Tehran (Iran, Islamic Republic of); Kohandel, M. [Alzahra University, Department of Physics and Chemistry, Tehran (Iran, Islamic Republic of); Stepanian, A. [University of Tehran, Department of Physics, Tehran (Iran, Islamic Republic of)
2016-06-15
In this paper we study anisotropic spherical polytropes within the framework of general relativity. Using the anisotropic Tolman-Oppenheimer-Volkov equations, we explore the relativistic anisotropic Lane-Emden equations. We find how the anisotropic pressure affects the boundary conditions of these equations. Also we argue that the behavior of physical quantities near the center of star changes in the presence of anisotropy. For constant density, a class of exact solution is derived with the aid of a new ansatz and its physical properties are discussed. (orig.)
Magnetic and magnetocaloric exploration of Fe rich (Mn,Fe)2(P,Ge)
Leitão, J. V.; van der Haar, M.; Lefering, A.; Brück, E.
2013-10-01
We explored the Fe rich side of the (Mn,Fe)2(P,Ge) magnetocaloric system. The transition temperature of this system is extremely easy to tune with careful manipulation of Fe and Ge content as well as stoichiometrical proportions, which give rise to the real possibility of lowering the price of this compound and thus make it economically viable for practical magnetocaloric applications. Novel and unexpected magnetic properties observed in this system suggest an exciting potential for permanent magnet application in a limited concentration range.
Anisotropically Inflating Universes
Barrow, J D; Barrow, John D.; Hervik, Sigbjorn
2008-01-01
We show that in theories of gravity that add quadratic curvature invariants to the Einstein-Hilbert action there exist expanding vacuum cosmologies with positive cosmological constant which do not approach the de Sitter universe. Exact solutions are found which inflate anisotropically. This behaviour is driven by the Ricci curvature invariant and has no counterpart in the general relativistic limit. These examples show that the cosmic no-hair theorem does not hold in these higher-order extensions of general relativity and raises new questions about the ubiquity of inflation in the very early universe and the thermodynamics of gravitational fields.
Energy Technology Data Exchange (ETDEWEB)
Chang, Jiwon [SEMATECH, 257 Fuller Rd #2200, Albany, New York 12203 (United States)
2015-06-07
Ballistic transport characteristics of metal-oxide semiconductor field effect transistors (MOSFETs) based on anisotropic two-dimensional materials monolayer HfS{sub 2} and phosphorene are explored through quantum transport simulations. We focus on the effects of the channel crystal orientation and the channel length scaling on device performances. Especially, the role of degenerate conduction band (CB) valleys in monolayer HfS{sub 2} is comprehensively analyzed. Benchmarking monolayer HfS{sub 2} with phosphorene MOSFETs, we predict that the effect of channel orientation on device performances is much weaker in monolayer HfS{sub 2} than in phosphorene due to the degenerate CB valleys of monolayer HfS{sub 2}. Our simulations also reveal that at 10 nm channel length scale, phosphorene MOSFETs outperform monolayer HfS{sub 2} MOSFETs in terms of the on-state current. However, it is observed that monolayer HfS{sub 2} MOSFETs may offer comparable, but a little bit degraded, device performances as compared with phosphorene MOSFETs at 5 nm channel length.
Directory of Open Access Journals (Sweden)
Xi-Nian Zuo
Full Text Available Neuroimaging community usually employs spatial smoothing to denoise magnetic resonance imaging (MRI data, e.g., Gaussian smoothing kernels. Such an isotropic diffusion (ISD based smoothing is widely adopted for denoising purpose due to its easy implementation and efficient computation. Beyond these advantages, Gaussian smoothing kernels tend to blur the edges, curvature and texture of images. Researchers have proposed anisotropic diffusion (ASD and non-local diffusion (NLD kernels. We recently demonstrated the effect of these new filtering paradigms on preprocessing real degraded MRI images from three individual subjects. Here, to further systematically investigate the effects at a group level, we collected both structural and functional MRI data from 23 participants. We first evaluated the three smoothing strategies' impact on brain extraction, segmentation and registration. Finally, we investigated how they affect subsequent mapping of default network based on resting-state functional MRI (R-fMRI data. Our findings suggest that NLD-based spatial smoothing maybe more effective and reliable at improving the quality of both MRI data preprocessing and default network mapping. We thus recommend NLD may become a promising method of smoothing structural MRI images of R-fMRI pipeline.
International Nuclear Information System (INIS)
Ballistic transport characteristics of metal-oxide semiconductor field effect transistors (MOSFETs) based on anisotropic two-dimensional materials monolayer HfS2 and phosphorene are explored through quantum transport simulations. We focus on the effects of the channel crystal orientation and the channel length scaling on device performances. Especially, the role of degenerate conduction band (CB) valleys in monolayer HfS2 is comprehensively analyzed. Benchmarking monolayer HfS2 with phosphorene MOSFETs, we predict that the effect of channel orientation on device performances is much weaker in monolayer HfS2 than in phosphorene due to the degenerate CB valleys of monolayer HfS2. Our simulations also reveal that at 10 nm channel length scale, phosphorene MOSFETs outperform monolayer HfS2 MOSFETs in terms of the on-state current. However, it is observed that monolayer HfS2 MOSFETs may offer comparable, but a little bit degraded, device performances as compared with phosphorene MOSFETs at 5 nm channel length
Zhang, Hai-Feng; Liu, Shao-Bin; Ding, Guo-Wen
2014-10-01
In this paper, the magneto-optical Voigt effects in surface plasmon modes and anisotropic photonic band gaps (PBGs) of the three-dimensional (3D) magnetized plasma photonic crystals (MPPCs) with face-centered-cubic lattices are theoretically investigated based on the modified plane wave expansion (PWE) method, which are the homogeneous Te (tellurium) spheres immersed in the homogeneous magnetized plasma background, as the mixed polarized modes are considered. The more general condition is considered, and the anisotropic PBGs are not only for the extraordinary and ordinary modes but also for mixed polarized modes. The equations for computing such anisotropic PBGs are theoretically deduced. Theoretical simulations show that the anisotropic PBGs and a flatbands region can be observed in the dispersive curve. Compared to the similar 3D MPPCs containing the isotropic dielectric or uniaxial material spheres, the larger PBGs can be obtained as the extraordinary axis of the inserted uniaxial material is along the Г-H symmetry line although the region of flatbands is also different. However, the relative bandwidths of PBGs for such two cases are almost the same. The interesting properties of surface plasmon modes can also be found, which are that the upper edge of flatbands region cannot be tuned by the filling factor but can almost linearly increase on increasing the plasma frequency and plasma cyclotron frequency (the external magnetic field), respectively. The effects of the filling factor, plasma frequency and plasma cyclotron frequency on the anisotropic PBGs are investigated in detail, respectively. Theoretical calculations also show that such PBGs can be manipulated by the parameters as mentioned above.
Anisotropic Diffusion for Medical Image Enhancement
Directory of Open Access Journals (Sweden)
Nezamoddin N. Kachouie
2010-10-01
Full Text Available Advances in digital imaging techniques have made possible the acquisition of large volumes of Transrectal Ultrasound (TRUS prostate images so that there is considerable demand for automated segmentation. Prostate cancer diagnosis and treatment rely on segmentation of these Transrectal Ultrasound (TRUS prostate images, a challenging and difficult task due to weak prostate boundaries, speckle noise and the narrow range of gray levels, leading most image segmentation methods to perform poorly. The enhancement of ultrasound images is challenging, however prostate segmentation can be effectively improved in contrast enhanced images. Anisotropic diffusion has been used for image analysis based on selective smoothness or enhancement of local features such as region boundaries. In its formal form, anisotropic diffusion tends to encourage within-region smoothness and avoid diffusion across different regions. In this paper we extend the anisotropic diffusion to multiple directions such that segmentation methods can effectively be applied based on rich extracted features. A preliminary segmentation method based on extended diffusion is proposed. Finally an adaptive anisotropic diffusion is introduced based on image statistics.
Gardiner, Thomas
2013-10-01
Anisotropic thermal diffusion in magnetized plasmas is an important physical phenomena for a diverse set of physical conditions ranging from astrophysical plasmas to MFE and ICF. Yet numerically simulating this phenomenon accurately poses significant challenges when the computational mesh is misaligned with respect to the magnetic field. Particularly when the temperature gradients are unresolved, one frequently finds entropy violating solutions with heat flowing from cold to hot zones for χ∥ /χ⊥ >=102 which is substantially smaller than the range of interest which can reach 1010 or higher. In this talk we present a new implicit algorithm for solving the anisotropic thermal diffusion equations and demonstrate its characteristics on what has become a fairly standard set of test problems in the literature. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2013-5687A.
Inhomogeneous anisotropic cosmology
Kleban, Matthew; Senatore, Leonardo
2016-10-01
In homogeneous and isotropic Friedmann-Robertson-Walker cosmology, the topology of the universe determines its ultimate fate. If the Weak Energy Condition is satisfied, open and flat universes must expand forever, while closed cosmologies can recollapse to a Big Crunch. A similar statement holds for homogeneous but anisotropic (Bianchi) universes. Here, we prove that arbitrarily inhomogeneous and anisotropic cosmologies with ``flat'' (including toroidal) and ``open'' (including compact hyperbolic) spatial topology that are initially expanding must continue to expand forever at least in some region at a rate bounded from below by a positive number, despite the presence of arbitrarily large density fluctuations and/or the formation of black holes. Because the set of 3-manifold topologies is countable, a single integer determines the ultimate fate of the universe, and, in a specific sense, most 3-manifolds are ``flat'' or ``open''. Our result has important implications for inflation: if there is a positive cosmological constant (or suitable inflationary potential) and initial conditions for the inflaton, cosmologies with ``flat'' or ``open'' topology must expand forever in some region at least as fast as de Sitter space, and are therefore very likely to begin inflationary expansion eventually, regardless of the scale of the inflationary energy or the spectrum and amplitude of initial inhomogeneities and gravitational waves. Our result is also significant for numerical general relativity, which often makes use of periodic (toroidal) boundary conditions.
Thanh, Tran Dang; Linh, Dinh Chi; Manh, Tien Van; Nan, Wen-Zhe; Yu, Seong-Cho; Piao, Hong-Guang; Pan, Liqing
2016-08-01
In this work, we present a detailed study on the magnetic and the magnetocaloric properties of Sm0.5+ x Sr0.5- x MnO3 compounds with x = 0 - 0.1, which were prepared by using a solid-state reaction method. The x-dependent magnetic, as well as magnetocaloric, properties, including the magnetic phase transition, have been studied. The increase in Sm/Sr ratio plays an important role in controlling the Curie temperature ( T C ). We point out that all the samples undergo a first-order phase transition and exhibit a giant magnetocaloric effect. The magnetic entropy change (Δ S m ) of samples was calculated based on isothermal M( H, T) data. The maximum value of Δ S m (denoted as |Δ S max|) at around T C is found to be 2.6 - 8.9 J·kg -1·K -1 for Δ H = 30 kOe and depends on the value of x. We have also used the universal master curve method for the temperature dependences of Δ S m curves measured at different Δ H values, Δ S m ( T,Δ H), to distinguish the magnetic order in the samples. Interestingly, none of the Δ S m ( T,Δ H) curves for the samples follow the universal master curve, Δ S m ( T,Δ H)/Δ S max versus θ = ( T -T C )/( T r - T C ). As a consequence, a breakdown in the universal behavior of Δ S m ( T,Δ H)/Δ S max versus θ curve is another feature confirming a first-order phase-transition nature.
Lax, M.; Narayanamurti, V.
1980-11-01
A new short derivation is given for the magnification of photons, phonons, and other wave phenomena in anisotropic media. The results, when specialized to the phonon case, agree with those of Maris and of Philip and Viswanathan. At nondegenerate points the magnification is shown, regardless of the nature of the wave phenomenon, to be expressible in terms of the Gaussian curvature K at the wave vector q--> of the surface ω(q-->)=ω. A representation of K, free of surface coordinates, is given as the cofactor of a 3×3 curvature tensor. The curvature tensor contains information beyond the Jacobian, such as the two principal magnifications for a given mode. Along degenerate directions (such as the [100] direction in cubic crystals) the results, even in the infinitesimal limit, are sensitive to the shape of the detector. Explicit expressions for circular, rectangular and square detectors are given and applied to the case of ballistic phonons in GaAs. Numerical calculation of finite aperture effects indicates significant qualitative as well as quantitative differences with infinitesimal aperture results.
Energy Technology Data Exchange (ETDEWEB)
Ricardo de Sousa, J. [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-000 Manaus, AM (Brazil); National Institute of Science and Technology for Complex Systems, 3000, Japiim, 69077-000 Manaus, AM (Brazil); Neto, Minos A., E-mail: minos@pq.cnpq.br [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-000 Manaus, AM (Brazil); Padilha, Igor T.; Salmon, Octavio D.R.; Viana, J. Roberto [Universidade Federal do Amazonas, Departamento de Física, 3000, Japiim, 69077-000 Manaus, AM (Brazil)
2013-12-15
We have studied the anisotropic three-dimensional nearest-neighbor Ising model with competitive interactions in an uniform longitudinal magnetic field H. The model consists of ferromagnetic interactions J{sub z}=λ{sub 2}J{sub x} in the x(z) direction and antiferromagnetic interactions J{sub y}=λ{sub 1}J{sub x} in the y direction (Ising superantiferromagnet). For the particular case λ{sub 1}=λ{sub 2}=1 we obtain the phase diagram in the H−T plane, using the framework of the differential operator technique in the effective-field theory with finite cluster of N=4 spins (EFT-4). It was observed first- and second-order transitions in the low and high temperature limits, respectively, with the presence of a tricritical point and a reentrant behavior is observed at low temperature. The critical curve in the classical approach is also obtained and the results are compared.
Cheng, Mingjian; Guo, Lixin; Li, Jiangting; Huang, Qingqing
2016-08-01
Rytov theory was employed to establish the transmission model for the optical vortices carried by Bessel-Gaussian (BG) beams in weak anisotropic turbulence based on the generalized anisotropic von Karman spectrum. The influences of asymmetry anisotropic turbulence eddies and source parameters on the signal orbital angular momentum (OAM) mode detection probability of partially coherent BG beams in anisotropic turbulence were discussed. Anisotropic characteristics of the turbulence could enhance the OAM mode transmission performance. The spatial partially coherence of the beam source would increase turbulent aberration's effect on the optical vortices. BG beams could dampen the influences of the turbulence because of their nondiffraction and self-healing characteristics. PMID:27505641
The Anisotropic Geometrodynamics For Cosmology
Siparov, Sergey V.
2009-05-01
The classical geometrodynamics (GRT) and its modern features based on the use of the Fridman-Robertson-Walker type metrics are still unable to explain several important issues of extragalactic observations like flat rotation curves of the spiral galaxies, Tully-Fisher law, globular clusters behavior in comparisson to that of the stars belonging to the galactic plane etc. The chalenging problem of the Universe expansion acceleration stemming from the supernovae observations demands the existence of the repulsion forces which brings one to the choice between the cosmological constant and some quintessence. The popular objects of discussion are now still dark (matter and energy), nevertheless, they are supposed to correspond to more than 95% of the Universe which seems to be far from satisfactory. According to the equivalence principle we can not experimentally distinguish between the inertial forces and the gravitational ones. Since there exist the inertial forces depending on velocity (Coriolis), it seems plausible to explore the velocity dependent gravitational forces. From the mathematical point of view it means that we should use the anisotropic metric. It immediately turns out that the expression for the Einstein-Hilbert action changes in a natural way - contrary to the cases of f(R)-theories, additional scalar fields, arbitrary MOND functions etc.. We use the linear approximation for the metric and derive the generalized geodesics and the equation for the gravity force that contains not only the Newton-Einstein term. The relation between the obtained results and those of Lense-Thirring approach are discussed. The resulting anisotropic geometrodynamics includes all the results of the GRT and is used to give the explanation to the problems mentioned above. One of the impressive consequences is the possibility to explain the observed Hubble red shift not by the Doppler effect as usually but by the gravitational red shift originating from the metric anisotropy.
van Kats, C. M.
2008-10-01
The driving forces for fundamental research in colloid science are the ability to manage the material properties of colloids and to unravel the forces that play a role between colloids to be able to control and understand the processes where colloids play an important role. Therefore we are searching for colloidal materials with specific physical properties to better understand our surrounding world.Until recently research in colloid science was mainly focused on spherical (isotropic) particles. Monodisperse spherical colloids serve as a model system as they exhibit similar phase behaviour as molecular and atomic systems. Nevertheless, in many cases the spherical shape is not sufficient to reach the desired research goals. Recently the more complex synthesis methods of anisotropic model colloids has strongly developed. This thesis should be regarded as a contribution to this research area. Anisotropic colloids can be used as a building block for complex structures and are expected not only to lead to the construction of full photonic band gap materials. They will also serve as new, more realistic, models systems for their molecular analogues. Therefore the term ‘molecular colloids” is sometimes used to qualify these anisotropic colloidal particles. In the introduction of this thesis, we give an overview of the main synthesis techniques for anisotropic colloids. Chapter 2 describes the method of etching silicon wafers to construct monodisperse silicon rods. They subsequently were oxidized and labeled (coated) with a fluorescent silica layer. The first explorative phase behaviour of these silica rods was studied. The particles showed a nematic ordering in charge stabilized suspensions. Chapter 3 describes the synthesis of colloidal gold rods and the (mesoporous) silica coating of gold rods. Chapter 4 describes the physical and optical properties of these particles when thermal energy is added. This is compared to the case where the particles are irradiated with
Modelling anisotropic damage and permeability of mortar under dynamic loads
Chen, W.; MAUREL, O.; REESS, T.; MATALLAH, M.; FERRON, A.; C. La Borderie; G. Pijaudier-Cabot
2011-01-01
This paper deals with the development of a model for concrete subjected to dynamic loads. Shock waves are generated by Pulsed Arc Electro-hydraulic Discharges (PAED) in water and applied to mortar samples. A diphasic model (liquid water and vapour) is implemented in order to describe the electrical discharge and the propagation of shock waves in water. An anisotropic damage model is devised, which takes account of the strain rate effect and the crack closure effect. Coupling between anisotrop...
Institute of Scientific and Technical Information of China (English)
HU Jie; FU Song; HUO Yan; LONG Yi; XUE Jianing
2016-01-01
Effect of impurity phase (α-Fe phase and La-rich phase) on corrosion resistance and magnetic entropy change of LaFe11.3Co0.4Si1.3C0.15 compound was studied using scanning electron microscopy, potentiodynamic polarization, electrochemical impedance spectroscopy techniques and magnetism testing. With the decrease of impurity phase, the corrosion resistance of LaFe11.3Co0.4Si1.3C0.15 compound was firstenhanced and then slightly impaired. Corrosion resistance could be significantly improved by the decrease ofα-Fe phase. However, the matrix phase was corroded if the La-rich phase as anode was too few. This caused the corrosion resistance to decrease slightly. After immersing the sample in distilled water for 15 d, –?Smax of the samples annealed for 3, 12 h, 3 and 7 d decreased about 50%, 41%, 16% and 17%, respectively.
Anisotropic Cosmological Model with Variable G and Lambda
Tripathy, S K; Routray, T R
2015-01-01
Anisotropic Bianchi-III cosmological model is investigated with variable gravitational and cosmological constants in the framework of Einstein's general relativity. The shear scalar is considered to be proportional to the expansion scalar. The dynamics of the anisotropic universe with variable G and Lambda are discussed. Without assuming any specific forms for Lambda and the metric potentials, we have tried to extract the time variation of G and Lambda from the anisotropic model. The extracted G and Lambda are in conformity with the present day observation. Basing upon the observational limits, the behaviour and range of the effective equation of state parameter are discussed.
Koshel', K. V.; Shishkarev, A. A.
1993-02-01
A perturbation theory for complex propagation constants is considered, based on the invariant imbedding method. This approach makes it possible to describe the effect of nonstratified fluctuations of the refractive index on transhorizon propagation of ultrashort waves in the framework of the adiabatic approximation in the case when an evaporation duct exists. Examples of calculations are presented, and characteristic stochastic effects are studied.
Desmorat, Rodrigue
2009-11-01
The effective stress concept, now classical in continuum damage mechanics, is generalized to the case of an initial anisotropy. In order to be used for both damage-elasticity and damage-(visco-)plasticity coupling, the effective stress should not depend on the elastic properties. Kelvin decomposition of the elasticity tensor allows to define such a stress for isotropic and cubic symmetries. For other material symmetries, the concept of multiple effective stresses is proposed. To cite this article: R. Desmorat, C. R. Mecanique 337 (2009).
Directory of Open Access Journals (Sweden)
R. Sekar
2013-05-01
Full Text Available Instability of themocovection in a multi-component fluid has wide range of applications in ionospheric, geothermal and industries. In this analysis, the effect of rotation and vertical anisotropy on Soret-driven thermoconvective instability in a ferrofluid has been studied. The fluid layer is assumed to be horizontal and is heated from below and salted from above. In momentum equation, the effect of both substantial derivatives and coriolis terms are considered. The resulting eigen value problem is solved using Brinkman model. A linear stability analysis is used for both stationary and oscillatory instabilities for different parameters for which normal mode technique is applied. The effect of rotation tends to stabilize the system and anisotropy and Soret effects tend to destabilize the system.
SH wave scattering problems in unbounded solid containing anisotropic inclusions
International Nuclear Information System (INIS)
A Volume Integral Equation Method (VIEM) is developed for the effective analysis of elastic wave scattering problems in unbounded solids containing general anisotropic inclusions. It should be noted that this newly developed numerical method does not require Green's function for anisotropic inclusions to solve this class of problems since only Green's function for the unbounded isotropic matrix is necessary for the analysis. This new method can also be applied to general two-dimensional elastodynamic and elastostatic problems with arbitrary shapes and number of anisotropic inclusions and voids or cracks. The detailed analysis of SH wave scattering problems are developed for unbounded isotropic matrix containing orthotropic cylindrical inclusions. Through the analysis of plane elastodynamic and elastostatic problems in unbounded isotropic matrix with orthotropic inclusions, it will be established that this new method is very accurate and effective for solving plane elastic problems in unbounded solids containing general anisotropic inclusions and voids or cracks.
Modeling and Measurements of CMUTs with Square Anisotropic Plates
DEFF Research Database (Denmark)
la Cour, Mette Funding; Christiansen, Thomas Lehrmann; Dahl-Petersen, Christian;
2013-01-01
The conventional method of modeling CMUTs use the isotropic plate equation to calculate the deflection, leading to deviations from FEM simulations including anisotropic effects of around 10% in center deflection. In this paper, the deflection is found for square plates using the full anisotropic...... plate equation and the Galerkin method. Utilizing the symmetry of the silicon crystal, a compact and accurate expression for the deflection can be obtained. The deviation from FEM in center deflection is light interferometer. Fitting...... the anisotropic calculated deflection to the measurement a deviation of 0.5-1.5% is seen for the fitted values. Finally it was also measured how the device behaved under increasing bias voltage and it is observed that the model including anisotropic effects is within the uncertainty interval of the measurements....
Rainbow metric from quantum gravity: anisotropic cosmology
Assanioussi, Mehdi
2016-01-01
In this paper we present a construction of effective cosmological models which describe the propagation of a massive quantum scalar field on a quantum anisotropic cosmological spacetime. Each obtained effective model is represented by a rainbow metric in which particles of distinct momenta propagate on different classical geometries. Our analysis shows that upon certain assumptions and conditions on the parameters determining such anisotropic models, we surprisingly obtain a unique deformation parameter $\\beta$ in the modified dispersion relation of the modes. Hence inducing an isotropic deformation despite the general starting considerations. We then ensure the recovery of the dispersion relation realized in the isotropic case, studied in [arXiv:1412.6000], when some proper symmetry constraints are imposed, and we estimate the value of the deformation parameter for this case in loop quantum cosmology context.
Magnetocaloric effect in ErCo2 compound
Institute of Scientific and Technical Information of China (English)
Zou Jun-Ding; Shen Bao-Gen; Sun Ji-Rong
2007-01-01
The ErCo2 compound is prepared by arc-melting and its entropy changes are calculated using Maxwell relation.Its entropy change reaches 38 J/(kg·K) and its refrigerant capacity achieves 291 J/kg at 0-5 T. The mean field approximation is used to calculate the magnetic entropy of ErCo2 compound. Results estimated by using the Maxwell relation deviate from mean field approximation calculations in ferrimagnetic state; however, the data obtained by the two ways are consistent in the vicinity of phase transition or at higher temperatures. This indicates that entropy changes are mainly derived from magnetic degree of freedom, and the lattice has almost no contribution to the entropy change in the vicinity of phase transition but its influence is obvious in the ferrimagnetic state below TC.
First-order phase transitions and giant magnetocaloric effect
Nguyen, T.T.
2010-01-01
Modern society relies on cooling technology for food safety, comfort and medical applications. The solid-state cooling technology known as magnetic refrigeration is one of the most promising techniques to replace the current vapor-compression cooling technology. To date, the search for suitable mate
Theoretical approach to the magnetocaloric effect with hysteresis
International Nuclear Information System (INIS)
In this paper a thermodynamic model with internal variables is presented and applied to ferromagnetic hysteresis. The out-of-equilibrium Gibbs free energy of a magnetic system is expressed as a function of the internal state of the Preisach model. Expressions for the system entropy and the entropy production are derived. By this approach it is possible to reproduce the characteristic features of the experimentally observed temperature changes (of the order of 10-4K around room temperature) induced by the magnetic field along the hysteresis loop performed in iron under adiabatic condition
Anisotropic magnetocapacitance in ferromagnetic-plate capacitors
Haigh, J. A.; Ciccarelli, C.; Betz, A. C.; Irvine, A.; Novák, V.; Jungwirth, T.; Wunderlich, J.
2015-04-01
The capacitance of a parallel-plate capacitor can depend on the applied magnetic field. Previous studies have identified capacitance changes induced via classical Lorentz force or spin-dependent Zeeman effects. Here we measure a magnetization direction-dependent capacitance in parallel-plate capacitors where one plate is a ferromagnetic semiconductor, gallium manganese arsenide. This anisotropic magnetocapacitance is due to the anisotropy in the density of states dependent on the magnetization through the strong spin-orbit interaction.
Tunneling anisotropic magnetoresistance in organic spin valves
Grünewald, M; M. Wahler; Schumann, F; Michelfeit, M.; Gould, C.; Schmidt, R.; Würthner, F.; Schmidt, G.; Molenkamp, L. W.
2011-01-01
We report the observation of tunneling anisotropic magnetoresistance (TAMR) in an organic spin-valve-like structure with only one ferromagnetic electrode. The device is based on a new high mobility perylene diimide-based n-type organic semiconductor. The effect originates from the tunneling injection from the LSMO contact and can thus occur even for organic layers which are too thick to support the assumption of tunneling through the layer. Magnetoresistance measurements show a clear spin-val...
Modeling operations back extrusion billets thick-walled anisotropic
ПЛАТОНОВ В.И.; Яковлев, С. С.
2014-01-01
The mathematical model is an inverse extrusion thick-walled tube blanks of material having anisotropic mechanical properties cylindrical. Relations are given to assess the kinematics of course materials la, stress and strain states, power operation modes reverse extrusion. The results of theoretical investigations of power modes. You are the manifest effects of process parameters on the power mode of operation isothermal reverse extrusion billets of high anisotropic materials in the short-ter...
Holographic study on the jet quenching parameter in anisotropic systems
Wang, Luying
2016-01-01
We first calculate the jet quenching parameter of an anisotropic plasma with a U(1) chemical potential via the AdS/CFT duality. The effects of charge, anisotropy parameter and quark motion direction on the jet quenching parameter are investigated. We then discuss the situation of anisotropic black brane in the IR region. We study both the jet quenching parameters along the longitudinal direction and transverse plane.
Photon states in anisotropic media
Indian Academy of Sciences (India)
Deepak Kumar
2002-08-01
Quantum aspects of optical polarization are discussed for waves traveling in anisotropic dielectric media with a view to relate the dynamics of polarization with that of photon spin and its manipulation by classical polarizers.
Gradient expansion for anisotropic hydrodynamics
Florkowski, Wojciech; Spaliński, Michał
2016-01-01
We compute the gradient expansion for anisotropic hydrodynamics. The results are compared with the corresponding expansion of the underlying kinetic-theory model with the collision term treated in the relaxation time approximation. We find that a recent formulation of anisotropic hydrodynamics based on an anisotropic matching principle yields the first three terms of the gradient expansion in agreement with those obtained for the kinetic theory. This gives further support for this particular hydrodynamic model as a good approximation of the kinetic-theory approach. We further find that the gradient expansion of anisotropic hydrodynamics is an asymptotic series, and the singularities of the analytic continuation of its Borel transform indicate the presence of non-hydrodynamic modes.
DEFF Research Database (Denmark)
Jeppesen, Claus; Flyvbjerg, Henrik; Mouritsen, Ole G.
1989-01-01
universality class, and that all models with nonconserved order parameter, independent of ordering degeneracy and softness and origin of domain boundaries, obey the classical growth law at finite temperatures. In quenches to the Potts-ordered phase vortices and antivortices occur and annihilate mutually...... without pinning the ordering process. The ordering dynamics for quenches into the intermediate phase is also found to be described by an effectively algebraic growth law....
Directory of Open Access Journals (Sweden)
Kamantsev Alexander
2014-07-01
Full Text Available High cooling power of magnetocaloric refrigeration can be achieved only at large amounts of heat, which can be transferred in one cycle from cold end hot end at quasi-isothermal conditions. The simple and robust experimental method of direct measuring of the transferred heat of materials with magnetocaloric effect (MCE in thermal contact with massive copper block with definite heat capacity in quasi-isothermal regime was proposed. The vacuum calorimeter for the specific transferred heat ΔQ and adiabatic temperature change ΔT measurements of MCE materials in the fields of Bitter coil magnet up to H = 140 kOe was designed and tested on samples of Ni43Mn37.9In12.1Co7 Heusler alloy with inverse MCE in the vicinity of meta-magnetostructural phase transition (PT. It was found, that the magnetic field H = 80 kOe produces complete PT from martensite to austenite with ΔQ = - 1600 J/kg at initial temperature 273 K.
Magnetic and magnetocaloric properties of Gd2In0.8X0.2 compounds (X=Al, Ga, Sn, Pb)
Tencé, Sophie; Chevalier, Bernard
2016-02-01
We show that it is possible to replace in Gd2In some amount of In by X=Al, Ga, Sn and Pb to obtain Gd2In1-xXx samples after melting. The magnetic and magnetocaloric properties of the Gd2In0.8X0.2 intermetallic compounds have been investigated through dc magnetization measurements. We evidence that the substitution of Al and Ga for In barely changes the Curie temperature TC but decreases the second magnetic transition temperature T‧ which corresponds to the transition from a ferromagnetic to an antiferromagnetic state. On the other hand, the substitution of Sn and Pb for In strongly increases TC and changes the nature or even suppresses the transition at lower temperature. This magnetic behavior gives rise to an interesting way to tune the Curie temperature near room temperature without diluting the Gd network and thus to modify the magnetocaloric effect in Gd2In1-xXx compounds.
Magnetocaloric properties of rapidly solidified Dy{sub 3}Co alloy ribbons
Energy Technology Data Exchange (ETDEWEB)
Sánchez Llamazares, J. L., E-mail: jose.sanchez@ipicyt.edu.mx; Flores-Zúñiga, H.; Sánchez-Valdés, C. F. [Instituto Potosino de Investigación Científica y Tecnológica A.C., Camino a la Presa San José 2055 Col. Lomas 4" a, San Luis Potosí, S.L.P. 78216 (Mexico); Álvarez-Alonso, Pablo [Departamento de Electricidad y Electrónica, UPV/EHU, 48940 Leioa (Spain); Lara Rodríguez, G. A. [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, Ciudad Universitaria, México, D. F. 04510 (Mexico); Fernández-Gubieda, M. L. [Departamento de Electricidad y Electrónica, UPV/EHU, 48940 Leioa (Spain); BC Materials, Camino de Ibaizabal, Edificio 500, Planta 1, Parque Científico y Tecnológico de Zamudio, 48160 Derio (Spain)
2015-05-07
The magnetic and magnetocaloric (MC) properties of melt-spun ribbons of the Dy{sub 3}Co intermetallic compound were investigated. Samples were fabricated in an Ar environment using a homemade melt spinner system at a linear speed of the rotating copper wheel of 40 ms{sup −1}. X-ray diffraction analysis shows that ribbons crystallize into a single-phase with the Fe{sub 3}C-type orthorhombic crystal structure. The M(T) curve measured at 5 mT reveals the occurrence of a transition at 32 K from a first to a second antiferromagnetic (AFM) state and an AFM-to-paramagnetic transition at T{sub N} = 43 K. Furthermore, a metamagnetic transition is observed below T{sub N}, but the magnetization change ΔM is well below the one reported for bulk alloys. Below 12 K, large inverse MC effect and hysteresis losses are observed. This behavior is related to the metamagnetic transition. For a magnetic field change of 5 T (2 T) applied along the ribbon length, the produced ribbons show a peak value of the magnetic entropy change ΔS{sub M}{sup peak} of −6.5 (− 2.1) Jkg{sup −1}K{sup −1} occurring close to T{sub N} with a full-width at half-maximum δT{sub FWHM} of 53 (37) K, and refrigerant capacity RC = 364 (83) Jkg{sup −1} (estimated from the product |ΔS{sub M}{sup peak}| × δT{sub FWHM})
Fermi Surface of Sr2 RuO4 : Spin-Orbit and Anisotropic Coulomb Interaction Effects
Zhang, Guoren; Gorelov, Evgeny; Sarvestani, Esmaeel; Pavarini, Eva
2016-03-01
The topology of the Fermi surface of Sr2 RuO4 is well described by local-density approximation calculations with spin-orbit interaction, but the relative size of its different sheets is not. By accounting for many-body effects via dynamical mean-field theory, we show that the standard isotropic Coulomb interaction alone worsens or does not correct this discrepancy. In order to reproduce experiments, it is essential to account for the Coulomb anisotropy. The latter is small but has strong effects; it competes with the Coulomb-enhanced spin-orbit coupling and the isotropic Coulomb term in determining the Fermi surface shape. Its effects are likely sizable in other correlated multiorbital systems. In addition, we find that the low-energy self-energy matrix—responsible for the reshaping of the Fermi surface—sizably differs from the static Hartree-Fock limit. Finally, we find a strong spin-orbital entanglement; this supports the view that the conventional description of Cooper pairs via factorized spin and orbital part might not apply to Sr2 RuO4 .
Fermi Surface of Sr_{2}RuO_{4}: Spin-Orbit and Anisotropic Coulomb Interaction Effects.
Zhang, Guoren; Gorelov, Evgeny; Sarvestani, Esmaeel; Pavarini, Eva
2016-03-11
The topology of the Fermi surface of Sr_{2}RuO_{4} is well described by local-density approximation calculations with spin-orbit interaction, but the relative size of its different sheets is not. By accounting for many-body effects via dynamical mean-field theory, we show that the standard isotropic Coulomb interaction alone worsens or does not correct this discrepancy. In order to reproduce experiments, it is essential to account for the Coulomb anisotropy. The latter is small but has strong effects; it competes with the Coulomb-enhanced spin-orbit coupling and the isotropic Coulomb term in determining the Fermi surface shape. Its effects are likely sizable in other correlated multiorbital systems. In addition, we find that the low-energy self-energy matrix-responsible for the reshaping of the Fermi surface-sizably differs from the static Hartree-Fock limit. Finally, we find a strong spin-orbital entanglement; this supports the view that the conventional description of Cooper pairs via factorized spin and orbital part might not apply to Sr_{2}RuO_{4}. PMID:27015496
International Nuclear Information System (INIS)
Systematic transport measurements have been performed on a series of La0.67Ca0.33MnO3 thin films with varying degrees of anisotropic strain. The strain is induced via epitaxial growth on NdGaO3(001) substrates and varied by controlling the thermal annealing time. An antiferromagnetic insulating (AFI) state, possibly associated with charge ordering, emerges upon thermal annealing. The Hall effect in these materials exhibits features that are indicative of a percolative phase transition and correlate closely with the emergence of the AFI state. In the paramagnetic phase, the Hall resistivity takes on two slopes in all samples: a decreasing negative slope with increasing temperature at low fields, which is attributed to the carrier hopping motion, and an almost temperature independent positive slope at high fields due to diffusive transport of holes. Significantly, the crossover fields of the Hall resistivity slope at different temperatures correspond to the same magnetization, which is interpreted as the critical point of a magnetic field-driven percolative phase transition. At lower temperatures near the zero-field metal–insulator transition, pronounced enhancement of the Hall coefficient with the development of the AFI state is observed. The enhancement peaks near the magnetic field-driven percolation; its magnitude correlates with the strength of the AFI state and is suppressed with the melting of the AFI state by an in-plane magnetic field. The observations resemble many features of the enhancement of the Hall coefficient in granular metal films near the composition-driven percolation. (paper)
Yasini, Siavash; Pierpaoli, Elena
2016-07-01
We present a novel mathematical formalism that allows us to easily compute the expected kinetic Sunyaev-Zeldovich (kSZ) signal in intensity and polarization due to an anisotropic primordial cosmic microwave background (CMB). We derive the expected intensity and polarization distortions in the direction of nonmoving galaxy clusters, and then we generalize our calculations for nonzero peculiar velocity. We show that, in the direction of moving clusters, low CMB multipoles impose intensity and polarization spectral distortions with different frequency dependences. The polarization signal primarily probes the quadrupole moment of the CMB, with a significant contribution from the primordial dipole and octupole moments. For a typical cluster velocity of 1000 km /s , corrections to the quadrupole-induced polarization of a nonmoving cluster are of the order of 2%-10% between 200-600 GHz, and depend on cluster's position on the sky, velocity magnitude, and direction of motion. We also find that the angular dependence of the signal varies with frequency of observation. The distinct frequency and angular dependences of the polarization induced by the primordial dipole and octupole can be exploited to measure them despite other physical effects and foregrounds. Contrary to polarization, intensity distortions are affected by all the CMB multipoles, so they cannot be readily used to probe the low multipoles at higher redshifts. However, correlations between intensity and polarization signals can be used to enhance the signal to noise ratio for the measurements of the primordial dipole, quadrupole, and octupole. The more general calculation of the aberration kernel presented in this work has applications reaching beyond the SZ cluster science addressed here. For example, it can be exploited to the deboost/deaberrate CMB multipoles as observed in our local frame.
Institute of Scientific and Technical Information of China (English)
CAI; Ruixian; GOU; Chenhua; ZHANG; Na
2005-01-01
Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.
Anisotropic thermal conduction in galaxy clusters with MHD in Gadget
Arth, Alexander; Beck, Alexander M; Petkova, Margarita; Lesch, Harald
2014-01-01
We present an implementation of thermal conduction including the anisotropic effects of magnetic fields for SPH. The anisotropic thermal conduction is mainly proceeding parallel to magnetic fields and suppressed perpendicular to the fields. We derive the SPH formalism for the anisotropic heat transport and solve the corresponding equation with an implicit conjugate gradient scheme. We discuss several issues of unphysical heat transport in the cases of extreme ansiotropies or unmagnetized regions and present possible numerical workarounds. We implement our algorithm into the GADGET code and study its behaviour in several test cases. In general, we reproduce the analytical solutions of our idealised test problems, and obtain good results in cosmological simulations of galaxy cluster formations. Within galaxy clusters, the anisotropic conduction produces a net heat transport similar to an isotropic Spitzer conduction model with an efficiency of one per cent. In contrast to isotropic conduction our new formalism ...
Khan, M. K. R.; Mori, Yoshihiro; Tanaka, Isao; Kojima, Hironao
1994-12-01
The oxygen annealing effect on the temperature-dependent electrical resistivity has been studied in La 1.91Ca 0.09CuO 4- y single crystals grown by the TSFZ method. In as-grown crystals, semiconducting-like electrical conduction has been observed, both in the ab-plane and the c-axis at the non-superconducting state. The onset transition temperature Tc-onset was about 17.5 K. After annealing in oxygen, ϱ ab( T) becomes metallic and shows a resistivity minimum at a certain temperature Tmin that separates regions of metallic behavior at T> Tmin from semiconducting behavior at Thopping law (VRH) in non-metallic samples.
Anisotropic Long-Range Spin Systems
Defenu, Nicolò; Ruffo, Stefano
2016-01-01
We consider anisotropic long-range interacting spin systems in $d$ dimensions. The interaction between the spins decays with the distance as a power law with different exponents in different directions: we consider an exponent $d_{1}+\\sigma_1$ in $d_1$ directions and another exponent $d_{2}+\\sigma_2$ in the remaining $d_2\\equiv d-d_1$ ones. We introduce a low energy effective action with non analytic power of the momenta. As a function of the two exponents $\\sigma_1$ and $\\sigma_2$ we show the system to have three different regimes, two where it is actually anisotropic and one where the isotropy is finally restored. We determine the phase diagram and provide estimates of the critical exponents as a function of the parameters of the system, in particular considering the case of one of the two $\\sigma$'s fixed and the other varying. A discussion of the physical relevance of our results is also presented.
Vargas, Jose M.; Gómez, Javier
2014-10-01
The effects of the electric and magnetic field variation on multiferroic heterostructure were studied in this work. Thin films of polycrystalline Fe50Pt50 (FePt) were grown by dc-sputtering on top of the commercial slabs of lead magnesium niobate-lead titanate (PMN-PT). The sample was a (011)-cut single crystal and had one side polished. In this condition, the PMN-PT/FePt operates in the L-T (longitudinal magnetized-transverse polarized) mode. A FePt thin film of 20 nm was used in this study to avoid the characteristic broad microwave absorption line associated with these films above thicknesses of 40 nm. For the in-plane easy magnetization axis (01-1), a microwave magnetoelectric (ME) coupling of 28 Oe cm kV -1 was estimated, whereas a value of 42 Oe cm kV -1 was obtained through the hard magnetization axis (100). Insight into the effects of the in-plane strain anisotropy on the ME coupling is obtained from the dc-magnetization loops. It was observed that the trend was opposite along the easy and hard magnetic directions. In particular, along the easy-magnetic axis (01-1), a square and narrow loop with a factor of Mr/MS of 0.96 was measured at 10 kV/cm. Along the hard-magnetic axis, a factor of 0.16 at 10 kV/cm was obtained. Using electric tuning via microwave absorption at X-band (9.78 GHz), we observe completely different trends along the easy and hard magnetic directions; Multiple absorption lines along the latter axis compared to a single and narrower absorption line along the former. In spite of its intrinsic complexity, we propose a model which gives good agreement both for static and microwave properties. These observations are of fundamental interest for future ME microwave components, such as filters, phase-shifters, and resonators.
Directory of Open Access Journals (Sweden)
Jose M. Vargas
2014-10-01
Full Text Available The effects of the electric and magnetic field variation on multiferroic heterostructure were studied in this work. Thin films of polycrystalline Fe50Pt50 (FePt were grown by dc-sputtering on top of the commercial slabs of lead magnesium niobate-lead titanate (PMN-PT. The sample was a (011-cut single crystal and had one side polished. In this condition, the PMN-PT/FePt operates in the L-T (longitudinal magnetized-transverse polarized mode. A FePt thin film of 20 nm was used in this study to avoid the characteristic broad microwave absorption line associated with these films above thicknesses of 40 nm. For the in-plane easy magnetization axis (01-1, a microwave magnetoelectric (ME coupling of 28 Oe cm kV −1 was estimated, whereas a value of 42 Oe cm kV −1 was obtained through the hard magnetization axis (100. Insight into the effects of the in-plane strain anisotropy on the ME coupling is obtained from the dc-magnetization loops. It was observed that the trend was opposite along the easy and hard magnetic directions. In particular, along the easy-magnetic axis (01-1, a square and narrow loop with a factor of Mr/MS of 0.96 was measured at 10 kV/cm. Along the hard-magnetic axis, a factor of 0.16 at 10 kV/cm was obtained. Using electric tuning via microwave absorption at X-band (9.78 GHz, we observe completely different trends along the easy and hard magnetic directions; Multiple absorption lines along the latter axis compared to a single and narrower absorption line along the former. In spite of its intrinsic complexity, we propose a model which gives good agreement both for static and microwave properties. These observations are of fundamental interest for future ME microwave components, such as filters, phase-shifters, and resonators.
Anisotropic diffusion-limited aggregation.
Popescu, M N; Hentschel, H G E; Family, F
2004-06-01
Using stochastic conformal mappings, we study the effects of anisotropic perturbations on diffusion-limited aggregation (DLA) in two dimensions. The harmonic measure of the growth probability for DLA can be conformally mapped onto a constant measure on a unit circle. Here we map m preferred directions for growth to a distribution on the unit circle, which is a periodic function with m peaks in [-pi,pi) such that the angular width sigma of the peak defines the "strength" of anisotropy kappa= sigma(-1) along any of the m chosen directions. The two parameters (m,kappa) map out a parameter space of perturbations that allows a continuous transition from DLA (for small enough kappa ) to m needlelike fingers as kappa--> infinity. We show that at fixed m the effective fractal dimension of the clusters D(m,kappa) obtained from mass-radius scaling decreases with increasing kappa from D(DLA) approximately 1.71 to a value bounded from below by D(min) = 3 / 2. Scaling arguments suggest a specific form for the dependence of the fractal dimension D(m,kappa) on kappa for large kappa which compares favorably with numerical results. PMID:15244564
Tunable waveguide bends with graphene-based anisotropic metamaterials
Chen, Zhao-xian
2016-01-15
We design tunable waveguide bends filled with graphene-based anisotropic metamaterials to achieve a nearly perfect bending effect. The anisotropic properties of the metamaterials can be described by the effective medium theory. The nearly perfect bending effect is demonstrated by finite element simulations of various structures with different bending curvatures and shapes. This effect is attributed to zero effective permittivity along the direction of propagation and matched effective impedance at the interfaces between the bending part and the dielectric waveguides. We envisage that the design will be applicable in the far-infrared and terahertz frequency ranges owing to the tunable dielectric responses of graphene.
International Nuclear Information System (INIS)
The anisotropic scattering influences both the transport and slowing processes of neutrons. Since Practical shields are usually anisotropic scatters, several parameterized, anisotropic scattering kernels were used to present a general class of anisotropies. To study the anisotropic sensitivity of the flux in thick shield medium, the feasibility of track- length distribution biasing for calculations of scalar and angular neutron flux and their sensitivity to anisotropic scattering was investigated. To represent more realistic angular distribution in a parameterized functional form, an exponential angular density for sampling the scattering angle is proposed, also an empirical formula for the choice of optimal parameter for track length biasing depending on the anisotropic scattering is proposed. The calculations are performed for a particle transport model having an exact solution. The results show that this distribution covers also isotropic and the anisotropic scattering case. The anisotropic effect has a great influence on the behavior of neutron distribution particularly in thick shield. (author)
DEFF Research Database (Denmark)
Lei, Tian; Engelbrecht, Kurt; Nielsen, Kaspar Kirstein;
2014-01-01
In active magnetic regeneration (AMR) systems, not only the magnetocaloric properties of materials, but also the regenerator geometry plays an important role in the system performance. Packed sphere regenerators are often employed in existing prototypes, however, the characteristics such as relat......In active magnetic regeneration (AMR) systems, not only the magnetocaloric properties of materials, but also the regenerator geometry plays an important role in the system performance. Packed sphere regenerators are often employed in existing prototypes, however, the characteristics...... such as relatively large pressure drop and almost fixed porosity make loss reductions and further optimization challenging. This paper proposes and focuses on packed screen regenerators, which may exhibit lower pressure drop and equivalent heat transfer performance to packed sphere regenerators. A 1D AMR model...
Acoustic anisotropic wavefields through perturbation theory
Alkhalifah, Tariq Ali
2013-09-01
Solving the anisotropic acoustic wave equation numerically using finite-difference methods introduces many problems and media restriction requirements, and it rarely contributes to the ability to resolve the anisotropy parameters. Among these restrictions are the inability to handle media with η<0 and the presence of shear-wave artifacts in the solution. Both limitations do not exist in the solution of the elliptical anisotropic acoustic wave equation. Using perturbation theory in developing the solution of the anisotropic acoustic wave equation allows direct access to the desired limitation-free solutions, that is, solutions perturbed from the elliptical anisotropic background medium. It also provides a platform for parameter estimation because of the ability to isolate the wavefield dependency on the perturbed anisotropy parameters. As a result, I derive partial differential equations that relate changes in the wavefield to perturbations in the anisotropy parameters. The solutions of the perturbation equations represented the coefficients of a Taylor-series-type expansion of the wavefield as a function of the perturbed parameter, which is in this case η or the tilt of the symmetry axis. The expansion with respect to the symmetry axis allows use of an acoustic transversely isotropic media with a vertical symmetry axis (VTI) kernel to estimate the background wavefield and the corresponding perturbation coefficients. The VTI extrapolation kernel is about one-fourth the cost of the transversely isotropic model with a tilt in the symmetry axis kernel. Thus, for a small symmetry axis tilt, the cost of migration using a first-order expansion can be reduced. The effectiveness of the approach was demonstrated on the Marmousi model.
Anisotropic Optical Properties of Layered Germanium Sulfide
Tan, Dezhi; Wang, Feijiu; Mohamed, Nur Baizura; Mouri, Shinichiro; Sandhaya, Koirala; Zhang, Wenjing; Miyauchi, Yuhei; Ohfuchi, Mari; Matsuda, Kazunari
2016-01-01
Two-dimensional (2D) layered materials, transition metal dichalcogenides and black phosphorus, have attracted much interest from the viewpoints of fundamental physics and device applications. The establishment of new functionalities in anisotropic layered 2D materials is a challenging but rewarding frontier, owing to their remarkable optical properties and prospects for new devices. Here, we report the anisotropic optical properties of layered 2D monochalcogenide of germanium sulfide (GeS). Three Raman scattering peaks corresponding to the B3g, A1g, and A2g modes with strong polarization dependence are demonstrated in the GeS flakes, which validates polarized Raman spectroscopy as an effective method for identifying the crystal orientation of anisotropic layered GeS. Photoluminescence (PL) is observed with a peak at around 1.66 eV that originates from the direct optical transition in GeS at room temperature. Moreover, determination of the polarization dependent characteristics of the PL and absorption reveals...
Tomizaki, Kin-ya; Kishioka, Kohei; Kobayashi, Hiroki; Kobayashi, Akitsugu; Yamada, Naoki; Kataoka, Shunsuke; Imai, Takahito; Kasuno, Megumi
2015-11-15
Gold nanocrystals are promising as catalysts and for use in sensing/imaging systems, photonic/plasmonic devices, electronics, drug delivery systems, and for photothermal therapy due to their unique physical, chemical, and biocompatible properties. The use of various organic templates allows control of the size, shape, structure, surface modification and topology of gold nanocrystals; in particular, currently the synthesis of gold nanorods requires a cytotoxic surfactant to control morphology. To control the shape of gold nanocrystals, we previously demonstrated the de novo design and synthesis of a β-sheet-forming nonapeptide (RU006: Ac-AIAKAXKIA-NH2, X=L-2-naphthylalanine, Nal) and the fabrication of gold nanocrystals by mixing RU006 and HAuCl4 in water. The reaction afforded ultrathin gold nanoribbons 50-100 nm wide, several nanometers high, and microns long. To understand the mechanism underlying gold nanoribbon formation by the RU006 system, we here report (i) the effects of replacement of the Nal aromatic side chain in the RU006 sequence with other aromatic moieties, (ii) the electrochemical properties of aromatic side chains in the de novo designed template peptides to estimate the redox potential and number of electrons participating in the gold crystallization process, and (iii) the stoichiometry of the RU006 system for gold nanoribbon synthesis. Interestingly, RU006 bearing a naphthalene moiety (oxidation peak potential of 1.50 V vs Ag/Ag(+)) and an analog [Ant(6)]-RU006 bearing a bulky anthracene moiety (oxidation peak potential of 1.05 V vs Ag/Ag(+)) allowed the growth of anisotropic (ribbon-like) and isotropic (round) gold nanocrystals, respectively. This trend in morphology of gold nanocrystals was attributed to spatially-arranged hydrophobic cavities sufficiently large to accommodate the gold precursor and to allow directed crystal growth driven by cross-linking reactions among the naphthalene rings. Support for this mechanism was obtained by
Continuum mechanics of anisotropic materials
Cowin, Stephen C
2013-01-01
Continuum Mechanics of Anisotropic Materials(CMAM) presents an entirely new and unique development of material anisotropy in the context of an appropriate selection and organization of continuum mechanics topics. These features will distinguish this continuum mechanics book from other books on this subject. Textbooks on continuum mechanics are widely employed in engineering education, however, none of them deal specifically with anisotropy in materials. For the audience of Biomedical, Chemical and Civil Engineering students, these materials will be dealt with more frequently and greater accuracy in their analysis will be desired. Continuum Mechanics of Anisotropic Materials' author has been a leader in the field of developing new approaches for the understanding of anisotropic materials.
Anisotropically structured magnetic aerogel monoliths
Heiligtag, Florian J.; Airaghi Leccardi, Marta J. I.; Erdem, Derya; Süess, Martin J.; Niederberger, Markus
2014-10-01
Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture.Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture. Electronic supplementary information (ESI) available: Digital photographs of dispersions and gels with different water-to-ethanol ratios; magnetic measurements of an anatase aerogel containing 0.25 mol% Fe3O4 nanoparticles; XRD patterns of the iron oxide and
Latest developments in anisotropic hydrodynamics
Tinti, Leonardo
2015-01-01
We discuss the leading order of anisotropic hydrodynamics expansion. It has already been shown that in the (0+1) and (1+1)-dimensional cases it is consistent with the second order viscous hydrodynamics, and it provides a striking agreement with the exact solutions of the Boltzmann equation. Quite recently, a new set of equations has been proposed for the leading order of anisotropic hydrodynamics, which is consistent with the second order viscous hydrodynamics in the most general (3+1)-dimensional case, and does not require a next-to-leading treatment for describing pressure anisotropies in the transverse plane.
Dynamical analysis of anisotropic inflation
Karčiauskas, Mindaugas
2016-06-01
The inflaton coupling to a vector field via the f(φ)2F μνFμν term is used in several contexts in the literature, such as to generate primordial magnetic fields, to produce statistically anisotropic curvature perturbation, to support anisotropic inflation, and to circumvent the η-problem. In this work, I perform dynamical analysis of this system allowing for the most general Bianchi I initial conditions. I also confirm the stability of attractor fixed points along phase-space directions that had not been investigated before.
Anisotropic hydrodynamics: Motivation and methodology
International Nuclear Information System (INIS)
In this proceedings contribution I review recent progress in our understanding of the bulk dynamics of relativistic systems that possess potentially large local rest frame momentum-space anisotropies. In order to deal with these momentum-space anisotropies, a reorganization of relativistic viscous hydrodynamics can be made around an anisotropic background, and the resulting dynamical framework has been dubbed “anisotropic hydrodynamics”. I also discuss expectations for the degree of momentum-space anisotropy of the quark–gluon plasma generated in relativistic heavy ion collisions at RHIC and LHC from second-order viscous hydrodynamics, strong-coupling approaches, and weak-coupling approaches
Magneto-caloric and magneto-resistive properties of La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Reves Dinesen, Anders
2004-08-01
This thesis presents results of an experimental investigation of magneto-caloric and magneto-resistive properties of a series of polycrystalline Ca- and Sr-doped lanthanum manganites, La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} (0{<=} x {<=} 0.33), with the perovskite structure. The samples consisted of sintered oxide powders prepared the glycine-nitrate combustion technique. The compounds were ferromagnetic and showed a Curie transition in the temperature range 267370 K (T{sub C} increased with increasing x). An analysis of the structural properties was carried out by means of x-ray diffraction and the Rietveld technique. The variation of the Ca/Sr ratio was found to cause a transition from orthorhombic to rhombohedral symmetry in the composition range 0.110 < x < 0.165. The analysis suggested a strong correlation between structural properties and magnetism, for instance a relationship between the mean MnOMn bond angle and the Curie temperature. The MnOMn bonds mediate ferromagnetism and electrical transport in these materials via the double-exchange mechanism. The magnetocaloric effect of the La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} samples was measured directly and indirectly (by means of magnetization measurements). All the samples showed a magnetocaloric effect in the vicinity of T{sub C}. A model for the mag-netocaloric effect based on Weiss mean field theory and classical theories for heat capacities was developed. The model provided reasonable predictions of the magneto-caloric properties of the samples. The compounds with low Sr content showed a magnetocaloric effect comparable to that of Gadolinium, the prototypical working material for magnetic refrigeration at room temperature. A less comprehensive part of the investigation regarded the magneto-resistive properties of the La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} system. It was found that th polycrystalline nature of the compounds played a decisive role for the magnetotransport properties
Energy Technology Data Exchange (ETDEWEB)
Morellon, L. E-mail: morellon@posta.unizar.es; Algarabel, P.A.; Magen, C.; Ibarra, M.R
2001-12-01
We have measured the zero-field electrical resistivity in the temperature range 5-295 K and magnetoresistance in magnetic fields of up to 12 T of Gd{sub 5}(Si{sub 0.1}Ge{sub 0.9}){sub 4}. The resistivity changes drastically at the magnetostructural first-order transition (T{sub C} congruent with 80 K on heating). This transition can be induced reversibly by the application of an external magnetic field above T{sub C}, producing a concomitant giant magnetoresistance (GMR) effect, {delta}{rho}/{rho} congruent with -50%. This study demonstrates that (in addition to giant magnetocaloric and magnetoelastic effects) GMR can be tuned between {approx}20 and {approx}290 K in Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} with x{<=}0.5 by simply adjusting the Si : Ge ratio.