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Sample records for anion relay chemistry

  1. Evolution of Multi-Component Anion Relay Chemistry (ARC): Construction of Architecturally Complex Natural and Unnatural Products#**

    OpenAIRE

    Smith, Amos B.; Wuest, William M.

    2008-01-01

    Efficient construction of architecturally complex natural and unnatural products is the hallmark of organic chemistry. Anion Relay Chemistry (ARC) - a multi-component coupling protocol - has the potential to provide the chemist with a powerful synthetic tactic, enabling efficient, rapid elaboration of structurally complex scaffolds in a single operation with precise stereochemical control. The ARC tactic can be subdivided into two main classes, comprising the relay of negative charge either t...

  2. Evolution of multi-component anion relay chemistry (ARC): construction of architecturally complex natural and unnatural products.

    Science.gov (United States)

    Smith, Amos B; Wuest, William M

    2008-12-01

    Efficient construction of architecturally complex natural and unnatural products is the hallmark of organic chemistry. Anion relay chemistry (ARC)-a multi-component coupling protocol-has the potential to provide the chemist with a powerful synthetic tactic, enabling efficient, rapid elaboration of structurally complex scaffolds in a single operation with precise stereochemical control. The ARC tactic can be subdivided into two main classes, comprising the relay of negative charge either through bonds or through space, the latter with aid of a transfer agent. This review will present the current state of through-space anion relay, in conjunction with examples of natural and unnatural product syntheses that illustrate the utility of this synthetic method. PMID:19030533

  3. The chemistry of gold as an anion.

    Science.gov (United States)

    Jansen, Martin

    2008-09-01

    Due to relativistic and classical shell structure effects, the 6s orbital of gold is significantly contracted and energetically stabilized. This is reflected by a strikingly high electron affinity, and a distinct tendency to adopt negatively polarized valence states. This tutorial review focuses on the chemistry of gold as an anion, displaying the integral ionic charge number of 1-. Two synthetic approaches to compounds containing monoatomic gold anions have become available: (1) reacting elemental gold with molten caesium and an oxide, e.g. Cs2O; (2) metathesis reactions involving Au- dissolved in liquid ammonia. Both procedures have proven to be rather versatile. Aurides synthesized along these routes are surveyed, in particular with respect to their structures and bonding properties. PMID:18762832

  4. Materials chemistry approach to anion-sensor design

    Czech Academy of Sciences Publication Activity Database

    Anzenbacher Jr., P.; Jursiková, K.; Aldakov, D.; Marquez, M.; Pohl, Radek

    2004-01-01

    Roč. 60, č. 49 (2004), s. 11163-11168. ISSN 0040-4020 Institutional research plan: CEZ:AV0Z4055905 Keywords : conductive polymer * anion sensing * polythiophene Subject RIV: CC - Organic Chemistry Impact factor: 2.643, year: 2004

  5. Advanced polymer chemistry of organometallic anions

    Energy Technology Data Exchange (ETDEWEB)

    Chamberlin, R.M.; Abney, K.D. [Los Alamos National Lab., NM (United States); Balaich, G.J.; Fino, S.A. [Air Force Academy, CO (United States)

    1997-11-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of the project was to prepare and characterize new polymers incorporating cobalt dicarbollide. Specific goals were to prepare polymerizable cobalt dicarbollide monomers using the nucleophilic substitution route discovered in laboratories and to establish the reaction conditions required to form polymers from these complexes. This one-year project resulted in two publications (in press), and provided the foundation for further investigations into polymer synthesis and characterization using cobalt dicarbollide and other metallocarboranes. Interest in synthesizing organometallic polymers containing the cobalt bis(dicarbollide) anion is motivated by their possible application as cation exchange materials for the remediation of cesium-137 and strontium-90 from nuclear wastes.

  6. GAS-GRAIN MODELS FOR INTERSTELLAR ANION CHEMISTRY

    International Nuclear Information System (INIS)

    Long-chain hydrocarbon anions CnH– (n = 4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive effects, the depletion of oxygen atoms onto dust results in substantially greater polyyne and anion abundances in high-density gas (with nH2∼>105 cm–3). The large abundances of carbon-chain-bearing species observed in the envelopes of protostars such as L1527 can thus be explained without the need for warm carbon-chain chemistry. The C6H– anion-to-neutral ratio is found to be most sensitive to the atomic O and H abundances and the electron density. Therefore, as a core evolves, falling atomic abundances and rising electron densities are found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray desorption of atoms in high-density models delays freeze-out, which results in a more temporally stable anion-to-neutral ratio, in better agreement with observations. Our models include reactions between oxygen atoms and carbon-chain anions to produce carbon-chain-oxide species C6O, C7O, HC6O, and HC7O, the abundances of which depend on the assumed branching ratios for associative electron detachment.

  7. GAS-GRAIN MODELS FOR INTERSTELLAR ANION CHEMISTRY

    Energy Technology Data Exchange (ETDEWEB)

    Cordiner, M. A. [Also at Institute for Astrophysics and Computational Sciences, Catholic University of America, Washington, DC 20064 (United States); Charnley, S. B., E-mail: martin.cordiner@nasa.gov [Astrochemistry Laboratory and Goddard Center for Astrobiology, Mailstop 691, NASA Goddard Space Flight Center, 8800 Greenbelt Road, Greenbelt, MD 20770 (United States)

    2012-04-20

    Long-chain hydrocarbon anions C{sub n}H{sup -} (n = 4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive effects, the depletion of oxygen atoms onto dust results in substantially greater polyyne and anion abundances in high-density gas (with n{sub H{sub 2}}{approx}>10{sup 5} cm{sup -3}). The large abundances of carbon-chain-bearing species observed in the envelopes of protostars such as L1527 can thus be explained without the need for warm carbon-chain chemistry. The C{sub 6}H{sup -} anion-to-neutral ratio is found to be most sensitive to the atomic O and H abundances and the electron density. Therefore, as a core evolves, falling atomic abundances and rising electron densities are found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray desorption of atoms in high-density models delays freeze-out, which results in a more temporally stable anion-to-neutral ratio, in better agreement with observations. Our models include reactions between oxygen atoms and carbon-chain anions to produce carbon-chain-oxide species C{sub 6}O, C{sub 7}O, HC{sub 6}O, and HC{sub 7}O, the abundances of which depend on the assumed branching ratios for associative electron detachment.

  8. Gas-Grain Models for Interstellar Anion Chemistry

    Science.gov (United States)

    Cordiner, M. A.; Charnely, S. B.

    2012-01-01

    Long-chain hydrocarbon anions C(sub n) H(-) (n = 4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive effects, the depletion of oxygen atoms onto dust results in substantially greater polyyne and anion abundances in high-density gas (with n(sub H2) approx > / cubic cm). The large abundances of carbon-chain-bearing species observed in the envelopes of protostars such as L1527 can thus be explained without the need for warm carbon-chain chemistry. The C6H(-) anion-to-neutral ratio is found to be most sensitive to the atomic O and H abundances and the electron density. Therefore, as a core evolves, falling atomic abundances and rising electron densities are found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray desorption of atoms in high-density models delays freeze-out, which results in a more temporally stable anion-to-neutral ratio, in better agreement with observations. Our models include reactions between oxygen atoms and carbon-chain anions to produce carbon-chain-oxide species C6O, C7O, HC6O, and HC7O, the abundances of which depend on the assumed branching ratios for associative electron detachment

  9. Chemistry of nitrile anions in the interstellar medium

    International Nuclear Information System (INIS)

    Despite the extreme conditions of temperature (down to 10K) and density (down to 100 molecules/cm3), the giant molecular clouds and the circumstellar envelopes present a rich and complex chemistry. To date, more than 180 molecules have been detected in the InterStellar Medium (ISM) with a large abundance of nitriles (RC≡N). In addition, several anions have been recently observed in this medium: C4H¯, C6H¯, C8H¯, CN¯, C3N¯ and C5N¯. These last species should play a key role in the molecular growth towards complexity. To explore this hypothesis, their reactivity must be studied in the laboratory. The FALP-MS and the CRESU experimental apparatuses of the Rennes University are able to measure absolute rate coefficient of various chemical reactions, including the ion – molecule reactions, in gas phase at low temperature (from 300K for the FALP-MS down to 15K for the CRESU). Therefore, these experimental tools are particularly adapted to the kinetic studies of reactions potentially involved in the Interstellar Medium. One of the difficulties encountered in experiments with anions is their generation. We describe here the formation of the CN¯ and C3N¯ anions by dissociative electron attachment on the molecular precursors BrCN and BrC3N

  10. Chemistry of nitrile anions in the interstellar medium

    Energy Technology Data Exchange (ETDEWEB)

    Carles, S.; Le Garrec, J.-L.; Biennier, L. [Institut de Physique de Rennes, Département de Physique Moléculaire, Astrophysique de Laboratoire, UMR CNRS 6251, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex (France); Guillemin, J.-C. [Institut des Sciences Chimiques de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, 11 Allée de Beaulieu, CS 50837,35708 Rennes Cedex 7 (France)

    2015-12-31

    Despite the extreme conditions of temperature (down to 10K) and density (down to 100 molecules/cm{sup 3}), the giant molecular clouds and the circumstellar envelopes present a rich and complex chemistry. To date, more than 180 molecules have been detected in the InterStellar Medium (ISM) with a large abundance of nitriles (RC≡N). In addition, several anions have been recently observed in this medium: C{sub 4}H{sup ¯}, C{sub 6}H{sup ¯}, C{sub 8}H{sup ¯}, CN{sup ¯}, C{sub 3}N{sup ¯} and C{sub 5}N{sup ¯}. These last species should play a key role in the molecular growth towards complexity. To explore this hypothesis, their reactivity must be studied in the laboratory. The FALP-MS and the CRESU experimental apparatuses of the Rennes University are able to measure absolute rate coefficient of various chemical reactions, including the ion – molecule reactions, in gas phase at low temperature (from 300K for the FALP-MS down to 15K for the CRESU). Therefore, these experimental tools are particularly adapted to the kinetic studies of reactions potentially involved in the Interstellar Medium. One of the difficulties encountered in experiments with anions is their generation. We describe here the formation of the CN{sup ¯} and C{sub 3}N{sup ¯} anions by dissociative electron attachment on the molecular precursors BrCN and BrC{sub 3}N.

  11. The saccharinate anion: a versatile and fascinating ligand in coordination chemistry

    Directory of Open Access Journals (Sweden)

    Enrique J. Baran

    2005-03-01

    Full Text Available The saccharinate anion, obtained by deprotonation of the N-H moiety of saccharin (o-sulfobenzimide is a very versatile and polyfunctional ligand in coordination chemistry. In this review the different forms of metal-to-ligand interactions involving this anion and some other coordination peculiarities are briefly discussed on the basis of some selected examples.

  12. Supramolecular Chemistry of Selective Anion Recognition for Anions of Environmental Relevance

    International Nuclear Information System (INIS)

    The major thrust of this project, led by the University of Kansas (Prof. Kristin Bowman-James), entails an exploration of the basic determinants of anion recognition and their application to the design, synthesis, and testing of novel sulfate extractants. A key scientific inspiration for the work comes from the need, codified in simple-to-appreciate terms by the Oak Ridge National Laboratory component of the team (viz. Dr. Bruce Moyer), for chemical entities that can help in the extractive removal of species that have low solubilities in borosilicate glass. Among such species, sulfate anion, has been identified as particularly insidious. Its presence interferes with the vitrification process, thus rendering the remediation of tank waste from, e.g., the Hanford site far more difficult and expensive. The availability of effective extractants, that would allow for the separation of separating sulfate from the major competing anions in the waste, especially nitrate, could allow for pre-vitrification removal of sulfate via liquid-liquid extraction. The efforts at The University of Texas, the subject of this report, have thus concentrated on the development of new sulfate receptors. These systems are designed to increase our basic understanding of anion recognition events and set the stage for the development of viable sulfate anion extractants. In conjunction with the Oak Ridge National Laboratory (ORNL) members of the research team, several of these new receptors were studied as putative extractants, with two of the systems being shown to act as promising synergists for anion exchange.

  13. Gas-grain models for interstellar anion chemistry

    OpenAIRE

    Cordiner, M. A.; Charnley, S. B.

    2012-01-01

    Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances ...

  14. Supramolecular chemistry of selective anion recognition for anions of environmental relevance. 1998 annual progress report

    Energy Technology Data Exchange (ETDEWEB)

    Bowman-James, K.; Wilson, G.S.; Kuczera, K. [Univ. of Kansas, Lawrence, KS (US); Moyer, B. [Oak Ridge National Lab., TN (US)

    1998-06-01

    'This project has as its focus the design and synthesis of polyammonium macrocyclic receptors for oxoanions of environmental importance. The basic research aspects of this project involve: (1) synthesis (and the search for improved synthetic methods); (2) solid state structure determination and thermodynamics studies (to ascertain structural criteria for and strength of anion binding); and (3) molecular dynamics simulations (to assess solution characteristics of the interactions between anions and their receptors). Applications-oriented goals include the fabrication of more selective anion-selective electrodes and the use of these compounds in liquid-liquid separations. The latter goal comprises the subcontract with Dr. Bruce Moyer at Oak Ridge National Laboratory. This report summarizes work after 1 year and 7 months of a 3-year project. To date, the authors have focussed on the design and synthesis of selective receptors for nitrate and phosphate.'

  15. Gas-phase chemistry of the silaformyl anion, HSiO sup minus

    Energy Technology Data Exchange (ETDEWEB)

    Gronert, S.; Prodnuk, S.; DePuy, C.H. (Univ. of Colorado, Boulder (USA)); O' Hair, R.A.J. (Univ. of Adelaide (Australia)); Suelzle, D. (Institut fuer Organische Chemie der Technischen Universitaet Berlin (West Germany)); Damrauer, R. (Univ. of Colorado, Denver (USA))

    1990-01-31

    The silaformyl anion, HSiO{sup {minus}}, has been prepared by collisionally induced dissociation (CID) of H{sub 3}SiO{sup {minus}} in a tandem flowing afterglow selected ion flow tube (FA-SIFT). The chemistry of the silaformyl anion has been studied in detail. Reactions with CO{sub 2}, COS, CS{sub 2}, SO{sub 2}, O{sub 2}, acetic acid, nitromethane, and hexafluorobenzene reveal a rich chemistry. For example, the sailaformyl anion reacts with CO{sub 2} by both an oxidative pathway giving HSiO{sub 2}{sup {minus}} and CO and a reductive path giving SiO and HCO{sub 2}{sup {minus}}. Typically, the silaformyl anion, which could have several sites of reactivity, behaves both as an oxygen nucleophile and as a hydride donor. Detailed mechanistic studies have been carried out on many of these reactions with isotopically labeled H{sup 29}SiO{sup {minus}} and HSi{sup 18}O{sup {minus}}. In addition to its reaction chemistry, the heat of formation of the silaformyl anion, its basicity, and the heat of formation of its parent compound have been estimated. Ab initio computations on the silaformyl anion have been carried out and demonstrate that HSiO{sup {minus}} is more than 40 kcal/mol more stable than HOSi{sup {minus}}.

  16. Anion Chemistry on Titan: systematic studies of the growth and stability of large negative ions

    Czech Academy of Sciences Publication Activity Database

    Žabka, Ján; Polášek, Miroslav; Křížová, Věra; Zymak, Illia; Romanzin, C.; Alcaraz, Ch.

    2015-01-01

    Roč. 635, - (2015), 032086. ISSN 1742-6588. [XXIX International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC2015). 22.07.2015-28.07.2015, Toledo] R&D Projects: GA MŠk(CZ) LD14024; GA ČR(CZ) GA14-19693S Grant ostatní: COST(XE) CM1204 Institutional support: RVO:61388955 Keywords : anion chemistry * Titan * Cassini CAPS-ELS Subject RIV: CF - Physical ; Theoretical Chemistry

  17. Update 1 of: Chemistry of the carba-closo-dodecaborate(-) anion, CB11H12(-)

    Czech Academy of Sciences Publication Activity Database

    Douvris, Christos; Michl, Josef

    2013-01-01

    Roč. 113, č. 10 (2013), PR179-PR233. ISSN 0009-2665 Grant ostatní: NSF(US) CHE-0848477 Institutional support: RVO:61388963 Keywords : carboranes * carborane anions * electrochemistry * spectroscopy * synthesis Subject RIV: CC - Organic Chemistry Impact factor: 45.661, year: 2013

  18. Supramolecular Chemistry of Selective Anion Recognition for Anions of Environmental Relevance. Final Report

    International Nuclear Information System (INIS)

    increased understanding of the chemical rules that govern the selective sequestration of anions.

  19. Supramolecular Chemistry: New chemodosimeters and hybrid materials for the chromo-fluorogenic detection of anions and neutral molecules

    OpenAIRE

    EL SAYED SHEHATA NASR, SAMEH

    2015-01-01

    [EN] Abstract The present PhD thesis entitled "Supramolecular Chemistry: New chemodosimeters and hybrid materials for the chromo-fluorogenic detection of anions and neutral molecules" is based on the application of supramolecular chemistry and material science principles for the development of optical chemosensors for anions and neutral molecules detection. The second chapter of this PhD thesis is devoted to the preparation of chemodosimeters for the chromo-fluorogenic detection of f...

  20. Relay race

    CERN Multimedia

    Staff Association

    2011-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 19th May starting at 12:15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. Details on the course, and how to register your team for the relay race, can be found at: https://espace.cern.ch/Running-Club/CERN-Relay Some advice for all runners from the medical service can also be found here: https://espace.cern.ch/Running-Club/CERN-Relay/RelayPagePictures/MedicalServiceAnnoncement.pdf

  1. Relay race

    CERN Multimedia

    Staff Association

    2011-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 19th May starting at 12·15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. Details on the course, and how to register your team for the relay race, can be found at: https://espace.cern.ch/Running-Club/CERN-Relay Some advice for all runners from the medical service can also be found here: https://espace.cern.ch/Running-Club/CERN-Relay/RelayPagePictures/MedicalServiceAnnoncement.pdf

  2. Protective relay technique

    International Nuclear Information System (INIS)

    This book gives description of protective relay. The contents of the first part are protective relay on general introduction, explanation of the terms and characteristic, classification of protective relay, structure of protective relay, operating of protective relay, short-circuit fault, earth fault and analyze of fault area, right using of protective relay. The last parts consist of current relay and voltage real y with over current relay, connection of wire of CT and over current relay and changing of current tap of OCR on using, over voltage relay and under voltage relay and voltage suppressor relay short-circuit relay for current compensation ground relay, directional relay, selective relay, directional relay and indication relay, distance relay, balance relay, TR relay, power control relay and another protective relay.

  3. Supramolecular chemistry of selective anion recognition for anions of environmental relevance. Progress report, October 1996--July 1997

    Energy Technology Data Exchange (ETDEWEB)

    Bowman-James, K.; Wilson, G.S.; Kuczera, K. [Univ. of Kansas, Lawrence, KS (US); Moyer, B. [Oak Ridge National Lab., TN (US)

    1997-01-01

    'This project has as its focus the design and synthesis of polyammonium macrocyclic receptors for oxoanions of environmental importance. The basic research aspects of this project involve synthesis (and the search for improved synthetic methods), solid state structure determination and thermodynamics studies (to ascertain structural criteria for and strength of anion binding), and molecular dynamics simulations (to assess solution characteristics of the interactions between anions and their receptors). Applications-oriented goals include the fabrication of more efficient anion-selective electrodes and the use of these compounds in liquid- liquid separations. The latter goal is the subcontract with Bruce Moyer at Oak Ridge National Laboratory. This first year the authors have focused on nitrates and phosphates. Considerable progress has been made in the basic areas of synthesis, solid state Structure, and molecular dynamics. Anion selective electrodes have also be made which show promising selectivities for oxoanions of interest. Below are described the major findings and significance in the categories of synthesis, structure and molecular dynamics, and electrode studies. Synthesis. The synthesis of polyaza macrocycles which are the focus of these studies is often tedious and time-consuming. A major breakthrough which the authors have made this year is to identify other polyaza macrocycles, which also bind the desired anions, but which are simpler to synthesize via a two step Schiff base/reduction process with high yields. This is truly significant since now the authors can obtain large quantities of the macrocycles and do multiple studies at once (crystallizations, thermodynamics, electrode, and eventually separations). Most of their studies to date have focused on monocyclic systems, but they are now beginning to examine bicyclic macrocycles, which can be synthesized by the same method starting with the tetraamine known as tren.'

  4. Reactions of substituted benzene anions with N and O atoms: Chemistry in Titan's upper atmosphere and the interstellar medium

    Science.gov (United States)

    Wang, Zhe-Chen; Bierbaum, Veronica M.

    2016-06-01

    The likely existence of aromatic anions in many important extraterrestrial environments, from the atmosphere of Titan to the interstellar medium (ISM), is attracting increasing attention. Nitrogen and oxygen atoms are also widely observed in the ISM and in the ionospheres of planets and moons. In the current work, we extend previous studies to explore the reactivity of prototypical aromatic anions (deprotonated toluene, aniline, and phenol) with N and O atoms both experimentally and computationally. The benzyl and anilinide anions both exhibit slow associative electron detachment (AED) processes with N atom, and moderate reactivity with O atom in which AED dominates but ionic products are also formed. The reactivity of phenoxide is dramatically different; there is no measurable reaction with N atom, and the moderate reactivity with O atom produces almost exclusively ionic products. The reaction mechanisms are studied theoretically by employing density functional theory calculations, and spin conversion is found to be critical for understanding some product distributions. This work provides insight into the rich gas-phase chemistry of aromatic ion-atom reactions and their relevance to ionospheric and interstellar chemistry.

  5. Anion chemistry on Titan: A possible route to large N-bearing hydrocarbons

    Czech Academy of Sciences Publication Activity Database

    Žabka, Ján; Romanzin, C.; Alcaraz, Ch.; Polášek, Miroslav

    2012-01-01

    Roč. 219, č. 1 (2012), s. 161-167. ISSN 0019-1035 R&D Projects: GA ČR GAP208/11/0446; GA MŠk(CZ) OC10046 Institutional research plan: CEZ:AV0Z40400503 Keywords : chemistry * ionospheres * titan Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.161, year: 2012

  6. FT-ICR studies of anionic reactions for the chemistry of planetary ionospheres

    Czech Academy of Sciences Publication Activity Database

    Romanzin, C.; Louarn, E.; Lemaire, J.; Žabka, Ján; Polášek, Miroslav; Guillemin, J.-C.; Alcaraz, Ch.

    2015-01-01

    Roč. 635, - (2015), 032112. ISSN 1742-6588. [XXIX International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC2015). 22.07.2015-28.07.2015, Toledo] R&D Projects: GA ČR GAP208/11/0446 Grant ostatní: COST(XE) CM0805 Institutional support: RVO:61388955 Keywords : FT-ICR studies * ionisphere * Titan Subject RIV: CF - Physical ; Theoretical Chemistry

  7. Relay race

    CERN Multimedia

    Staff Association

    2012-01-01

    The CERN Relay Race will take place around the Meyrin site on Thursday 24th May at 12:00. This annual event is for teams of six runners covering distances of 1000 m, 800 m, 800 m, 500 m, 500 m and 300 m respectively. Teams may be entered in the Seniors, Veterans, Ladies, Mixed or Open categories. There will also this year be a Nordic Walking event, as part of the Medical Service’s initiative “Move more, eat better!” The registration fee is 10 CHF per runner, and each runner will receive a souvenir prize. There will be a programme of entertainment from 12:00 on the arrival area (the lawn in front of Restaurant 1): 12:00 - 12:45  Music from the Old Bottom Street band 12:15 Start of the race 12:45 - 13h Demonstrations by the Fitness club and Dancing club 13:00 Results and prize giving (including a raffle to win an iPad2 3G offered by the Micro club) 13:20 à 14:00 Music from “What’s next” And many information st...

  8. Efficient incremental relaying

    KAUST Repository

    Fareed, Muhammad Mehboob

    2013-07-01

    We propose a novel relaying scheme which improves the spectral efficiency of cooperative diversity systems by utilizing limited feedback from destination. Our scheme capitalizes on the fact that relaying is only required when direct transmission suffers deep fading. We calculate the packet error rate for the proposed efficient incremental relaying scheme with both amplify and forward and decode and forward relaying. Numerical results are also presented to verify their analytical counterparts. © 2013 IEEE.

  9. 80537 based distance relay

    DEFF Research Database (Denmark)

    Pedersen, Knud Ole Helgesen

    1999-01-01

    A method for implementing a digital distance relay in the power system is described.Instructions are given on how to program this relay on a 80537 based microcomputer system.The problem is used as a practical case study in the course 53113: Micocomputer applications in the power system.The relay is...

  10. Beyond interfacial anion/cation pairing: The role of Cu(I) coordination chemistry in additive-controlled copper plating

    International Nuclear Information System (INIS)

    Highlights: ► We study synergistic and antagonistic ensemble effects of various polymeric suppressor additives and MPS relevant for copper electroplating. ► Type-I suppressors (e.g. PEGs) show a purely antagonistic interaction with MPS. ► Type-II suppressors (e.g. PEIs) show a purely synergistic interaction with MPS. ► Hybrid suppressors (e.g. Imep) reveal both synergistic and antagonistic effects depending on the MPS concentration. ► We identify a combination of Cu(I) coordination chemistry and an inner salt formation as key to the understanding of the suppressing mode of polymeric leveler additives. - Abstract: This study reinvestigates the electrochemical characteristics of three different suppressor additives that are used in context of industrial copper plating (Damascene, Through-Silicon-Via). It is the particular aim of this contribution to further substantiate our recently introduced classification scheme of suppressor chemistries that relies on their antagonistic and synergistic interplay with MPS (mercaptopropane sulfonic acid/sulfonate). The latter appears as intermediate species in the course of copper electrodeposition in the presence of SPS (bis-(sodium-sulfopropyl)-disulfide). Both the linear sweep voltammetry and potential transient experiments reveal a purely antagonistic interaction between PAG (polyalkylene glycol) based suppressor ensembles and the SPS (MPS precursor) which is rationalized in terms of the coordinative dissolution of a hyper-branched PAG-Cu(I)-Cl coordination network by the MPS. Such purely antagonistic suppressor/MPS interplay is our criterion for a so-called type-I suppressor. A purely synergistic suppressor/MPS interaction is observed for the PEI (polyethylene-imine) which can be considered as a prototypical type-II suppressor. Beyond classical interfacial anion/cation pairing the partly protonated, poly-cationic PEI is capable to form MPS-stabilized Cu(I) adducts. Their suppressing effect relies on an in situ hyper

  11. Anions in Cometary Comae

    Science.gov (United States)

    Charnley, Steven B.

    2011-01-01

    The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions 0-, OH-, C-, CH- and CN- have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu (Chaizy et al. 1991). Organic molecular anions are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas-phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been explored. We present details of the first attempt to model the chemistry of anions in cometary comae. Based on the combined chemical and hydro dynamical model of Rodgers & Charnley (2002), we investigate the role of large carbon-chain anions in cometary coma chemistry. We calculate the effects of these anions on coma thermodynamics, charge balance and examine their impact on molecule formation.

  12. CERN Relay Race

    CERN Multimedia

    CERN Running Club

    2010-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 20 May, starting at 12.15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. Details on the route, and how to register your team for the relay race, can be found at: https://espace.cern.ch/Running-Club/CERN-Relay

  13. Protective relay principles

    CERN Document Server

    Sleva, Anthony F

    2009-01-01

    This title lets you improve failure detection and optimize protection. In the ever-evolving field of protective relay technology, an engineer's personal preference and professional judgment are as important to power system protection as the physical relays used to detect and isolate abnormal conditions. With invaluable insights from an experienced expert, ""Protective Relay Principles"" focuses on probable power system failure modes and the important characteristics of the protective relays used to detect these postulated failures.This book presents useful new concepts in a way that is easier

  14. Anion-π Catalysis of Enolate Chemistry: Rigidified Leonard Turns as a General Motif to Run Reactions on Aromatic Surfaces.

    Science.gov (United States)

    Cotelle, Yoann; Benz, Sebastian; Avestro, Alyssa-Jennifer; Ward, Thomas R; Sakai, Naomi; Matile, Stefan

    2016-03-18

    To integrate anion-π, cation-π, and ion pair-π interactions in catalysis, the fundamental challenge is to run reactions reliably on aromatic surfaces. Addressing a specific question concerning enolate addition to nitroolefins, this study elaborates on Leonard turns to tackle this problem in a general manner. Increasingly refined turns are constructed to position malonate half thioesters as close as possible on π-acidic surfaces. The resulting preorganization of reactive intermediates is shown to support the disfavored addition to enolate acceptors to an absolutely unexpected extent. This decisive impact on anion-π catalysis increases with the rigidity of the turns. The new, rigidified Leonard turns are most effective with weak anion-π interactions, whereas stronger interactions do not require such ideal substrate positioning to operate well. The stunning simplicity of the motif and its surprisingly strong relevance for function should render the introduced approach generally useful. PMID:26916316

  15. Part I. Student success in intensive versus traditional introductory chemistry courses. Part II. Synthesis of salts of the weakly coordinating trisphat anion

    Science.gov (United States)

    Hall, Mildred V.

    Part I. Intensive courses have been shown to be associated with equal or greater student success than traditional-length courses in a wide variety of disciplines and education levels. Student records from intensive and traditional-length introductory general chemistry courses were analyzed to determine the effects, of the course format, the level of academic experience, life experience (age), GPA, academic major and gender on student success in the course. Pretest scores, GPA and ACT composite scores were used as measures of academic ability and prior knowledge; t-tests comparing the means of these variables were used to establish that the populations were comparable prior to the course. Final exam scores, total course points and pretest-posttest differences were used as measures of student success; t-tests were used to determine if differences existed between the populations. ANCOVA analyses revealed that student GPA, pretest scores and course format were the only variables tested that were significant in accounting for the variance of the academic success measures. In general, the results indicate that students achieved greater academic success in the intensive-format course, regardless of the level of academic experience, life experience, academic major or gender. Part II. Weakly coordinating anions have many important applications, one of which is to function as co-catalysts in the polymerization of olefins by zirconocene. The structure of tris(tetrachlorobenzenedialato) phosphate(V) or "trisphat" anion suggests that it might be an outstanding example of a weakly coordinating anion. Trisphat acid was synthesized and immediately used to prepare the stable tributylammonium trisphat, which was further reacted to produce trisphat salts of Group I metal cations in high yields. Results of the 35Cl NQR analysis of these trisphat salts indicate only very weak coordination between the metal cations and the chlorine atoms of the trisphat anion.

  16. Power system relaying

    CERN Document Server

    Horowitz, Stanley H; Niemira, James K

    2013-01-01

    The previous three editions of Power System Relaying offer comprehensive and accessible coverage of the theory and fundamentals of relaying and have been widely adopted on university and industry courses worldwide. With the third edition, the authors have added new and detailed descriptions of power system phenomena such as stability, system-wide protection concepts and discussion of historic outages. Power System Relaying, 4th Edition continues its role as an outstanding textbook on power system protection for senior and graduate students in the field of electric power engineering and a refer

  17. CERN Relay Race

    CERN Document Server

    2008-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 5 June starting at 12:15 p.m. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. Details on how to register your team for the relay race are given on the Staff Association Bulletin web site. You can access the online registration form at: http://cern.ch/club-running-relay/form.html

  18. Ready, steady… relay!

    CERN Document Server

    2008-01-01

    Thursday 5 June. With another year comes another success for CERN’s Relay Race. With 76 teams taking part it was the second highest turnout in the race’s history. ‘The Shabbys’ won the relay race in 10 minutes 51 seconds.As popular as ever, this year the relay race took on the atmosphere of a mini carnival. Gathering on the lawn outside Restaurant 1, various stalls and attractions added to the party feeling of the event, with beer courtesy of ‘AGLUP’, the Belgian beer club, and a wandering jazz group entertaining spectators and competitors alike. Reflecting the greater involvement of other associations in the relay race, the president of the Staff Association Clubs Committee, James Purvis, was the guest of honour, launching the start of the race and presenting the prizes. As regular followers of the race could have probably predicted, The Shabbys were once again victorious and claimed first place. The team members th...

  19. Multifunction protective relay

    Science.gov (United States)

    Harlow, J.; Yalla, M.; Kantor, J.

    1991-11-01

    Since the enactment of the National Energy Act of 1979, many private energy producers have been planning and building small generation and cogeneration facilities in order to sell power to the local utility. Many of the non-utility generators built after 1979 are connected directly to the closest utility distribution circuit. Aware of the problems associated with connecting generators in this manner, electric utilities across the country developed specifications and standards to allow safe and reliable interconnection. The report describes a malfunction protective relay which uses state-of-the-art digital signal processing procedures to accomplish the objective of providing most of the relay requirements of utility electrical interconnections. The relay has been demonstrated to be suitable for this critical application through extensive laboratory and in-service field testing. The relay, incorporating thirteen distinct protection functions affords the user the savings of the initial capital cost plus simplicity of installation and use.

  20. CERN Relay Race 2009

    CERN Document Server

    2009-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 14th May starting at 12:15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. More details on how to register your team for the relay race

  1. Opportunistic relaying in multipath and slow fading channel: Relay selection and optimal relay selection period

    KAUST Repository

    Sungjoon Park,

    2011-11-01

    In this paper we present opportunistic relay communication strategies of decode and forward relaying. The channel that we are considering includes pathloss, shadowing, and fast fading effects. We find a simple outage probability formula for opportunistic relaying in the channel, and validate the results by comparing it with the exact outage probability. Also, we suggest a new relay selection algorithm that incorporates shadowing. We consider a protocol of broadcasting the channel gain of the previously selected relay. This saves resources in slow fading channel by reducing collisions in relay selection. We further investigate the optimal relay selection period to maximize the throughput while avoiding selection overhead. © 2011 IEEE.

  2. Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion

    Czech Academy of Sciences Publication Activity Database

    Carr, MJ.; Clegg, W.; Kennedy, J.D.; Londesborough, Michael Geoffrey Stephen; Kilner, C. A.

    2010-01-01

    Roč. 75, č. 8 (2010), s. 807-812. ISSN 0010-0765 Institutional research plan: CEZ:AV0Z40320502 Keywords : borane cluster * thiaborane * macropolyhedral Subject RIV: CA - Inorganic Chemistry Impact factor: 0.853, year: 2010

  3. Alternate MIMO relaying with three AF relays using interference alignment

    KAUST Repository

    Park, Kihong

    2012-06-01

    In this paper, we study a two-hop half-duplex relaying network with one source, one destination, and three amplify-and-forward (AF) relays equipped with M antennas each. We consider alternate transmission to compensate for the inherent loss of capacity pre-log factor 1/2 in half duplex mode, where source transmit message to two relays and the other relay alternately. The inter-relay interference caused by alternate transmission is aligned to make additional degrees of freedom (DOFs). It is shown that the proposed scheme enables us to exploit 3M/4 DOFs compared with the M/2 DOFs of conventional AF relaying. More specifically, suboptimal linear filter designs for a source and three relays are proposed to maximize the achievable sum-rate. We verify using some selected numerical results that the proposed filter designs give significant improvement of the sum-rate over a naive filter and conventional relaying schemes. © 2012 IEEE.

  4. CERN Relay Race

    CERN Document Server

    2011-01-01

    The CERN relay race will take place around the Meyrin site on Thursday 19 May starting at 12-15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. Thank you for your cooperation. Details of the course and of how to register your team for the relay race can be found here. Some advice for all runners from the Medical Service can also be found here.   

  5. BITNET relay system

    International Nuclear Information System (INIS)

    It is becoming indispensable for researchers to use international computer network for research information exchange, supported by rapid progress of technologies related to computer and communication. At the Computing Center, JAERI, a software system for computer network relays has been developed to join the international computer network, BITNET via FACOM computer system of JAERI. Owing to this software, it has become possible for JAERI personnel to use the BITNET in April, 1989. In this report, the description of the BITNET relay system is presented. (author)

  6. CERN Relay Race

    CERN Document Server

    2009-01-01

    The CERN relay race, now in its 39th year, is already a well-known tradition, but this year the organizers say the event will have even more of a festival feeling. Just off the starting line of the CERN relay race.For the past few years, spectators and runners at the CERN relay race have been able to enjoy a beer while listening to music from the CERN music and jazz clubs. But this year the organizers are aiming for "even more of a festival atmosphere". As David Nisbet, President of the CERN running club and organizer of the relay race, says: "Work is not just about getting your head down and doing the theory, it’s also about enjoying the company of your colleagues." This year, on top of music from the Santa Luis Band and the Canettes Blues Band, there will be demonstrations from the Aikido and softball clubs, a stretching session by the Fitness club, as well as various stalls and of course, the well-earned beer from AGLUP, the B...

  7. Opportunistic Relay Selection in Multicast Relay Networks using Compressive Sensing

    KAUST Repository

    Elkhalil, Khalil

    2014-12-01

    Relay selection is a simple technique that achieves spatial diversity in cooperative relay networks. However, for relay selection algorithms to make a selection decision, channel state information (CSI) from all cooperating relays is usually required at a central node. This requirement poses two important challenges. Firstly, CSI acquisition generates a great deal of feedback overhead (air-time) that could result in significant transmission delays. Secondly, the fed back channel information is usually corrupted by additive noise. This could lead to transmission outages if the central node selects the set of cooperating relays based on inaccurate feedback information. In this paper, we introduce a limited feedback relay selection algorithm for a multicast relay network. The proposed algorithm exploits the theory of compressive sensing to first obtain the identity of the “strong” relays with limited feedback. Following that, the CSI of the selected relays is estimated using linear minimum mean square error estimation. To minimize the effect of noise on the fed back CSI, we introduce a back-off strategy that optimally backs-off on the noisy estimated CSI. For a fixed group size, we provide closed form expressions for the scaling law of the maximum equivalent SNR for both Decode and Forward (DF) and Amplify and Forward (AF) cases. Numerical results show that the proposed algorithm drastically reduces the feedback air-time and achieves a rate close to that obtained by selection algorithms with dedicated error-free feedback channels.

  8. Intrinsic anion oxidation potentials.

    Science.gov (United States)

    Johansson, Patrik

    2006-11-01

    Anions of lithium battery salts have been investigated by electronic structure calculations with the objective to find a computational measure to correlate with the observed (in)stability of nonaqueous lithium battery electrolytes vs oxidation often encountered in practice. Accurate prediction of intrinsic anion oxidation potentials is here made possible by computing the vertical free energy difference between anion and neutral radical (Delta Gv) and further strengthened by an empirical correction using only the anion volume as a parameter. The 6-311+G(2df,p) basis set, the VSXC functional, and the C-PCM SCRF algorithm were used. The Delta Gv calculations can be performed using any standard computational chemistry software. PMID:17078600

  9. Laser Communications Relay Demonstration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Laser Communications Relay Demonstration project will advance optical communications technology, expanding industry’s capability to produce competitive,...

  10. Chemistry

    International Nuclear Information System (INIS)

    The chemical research and development efforts related to the design and ultimate operation of molten-salt breeder reactor systems are concentrated on fuel- and coolant-salt chemistry, including the development of analytical methods for use in these systems. The chemistry of tellurium in fuel salt is being studied to help elucidate the role of this element in the intergranular cracking of Hastelloy N. Studies were continued of the effect of oxygen-containing species on the equilibrium between dissolved UF3 and dissolved UF4, and, in some cases, between the dissolved uranium fluorides and graphite, and the UC2. Several aspects of coolant-salt chemistry are under investigation. Hydroxy and oxy compounds that could be formed in molten NaBF4 are being synthesized and characterized. Studies of the chemistry of chromium (III) compounds in fluoroborate melts were continued as part of a systematic investigation of the corrosion of structural alloys by coolant salt. An in-line voltammetric method for determining U4+/U3+ ratios in fuel salt was tested in a forced-convection loop over a six-month period. (LK)

  11. CERN Relay Race

    CERN Multimedia

    Running Club

    2010-01-01

    This year’s CERN Relay Race will take place around the Meyrin site on Thursday 20th May at 12h00. This annual event is for teams of 6 runners covering distances of 1000m, 800m, 800m, 500m, 500m and 300m respectively. Teams may be entered in the Seniors, Veterans, Ladies, Mixed or Open categories. The registration fee is 10 CHF per runner, and each runner receives a souvenir prize. As usual, there will be a programme of entertainments from 12h in the arrival area, in front of the Restaurant no. 1. Drinks, food, CERN club information and music will be available for the pleasure of both runners and spectators. The race starts at 12h15, with results and prize giving at 13:15.   For details of the race, and of how to sign up a team, please visit: https://espace.cern.ch/Running-Club/CERN-Relay The event is organised by the CERN Running Club with the support of the CERN Staff Association.  

  12. Voz sobre frame relay

    OpenAIRE

    D´Elia, Gabriel Anibal

    2000-01-01

    Esta tesis trata el tema de VOFR, desde la digitalización de la voz hasta su transmisión a través de dicha red, así también como la comparación con otros medios de transporte como VOIP. Dada las características del protocolo frame relay y su disponibilidad se eligió como el medio más apropiado para la transmisión de voz y datos en forma integrada sobre una misma red. El trabajo comienza con una breve explicación de la voz, su digitalización y forma actual de transmisión a través de una red di...

  13. CERN Relay Race

    CERN Multimedia

    2005-01-01

    The CERN Relay Race will take place around the Meyrin site on Wednesday 18 May between 12.15 and 12.35. This year, weather permitting, there will be some new attractions in the start/finish area on the field behind the Main Building. You will be able to: listen to music played by the CERN Jazz Club; buy drinks at the bar organised by the CERN Running Club; buy lunch served directly on the terrace by the restaurant Novae. ATTENTION: concerning traffic, the recommendations are the same as always: If possible, please avoid driving on the site during this 20 minute period. If you do meet runners in your car, please STOP until they all have passed. Thank you for your understanding.

  14. Chemistry

    International Nuclear Information System (INIS)

    Research progress is reported in programs on fuel-salt chemistry, properties of compounds in the Li--Te system, Te spectroscopy UF4--H equilibria, porous electrode studies of molten salts, fuel salt-coolant salt reactions, thermodynamic properties of transition-metal fluorides, and properties of sodium fluoroborate. Developmental work on analytical methods is summarized including in-line analysis of molten MSBR fuel, analysis of coolant-salts for tritium, analysis of molten LiF--BeF2--ThF4 for Fe and analysis of LiF--BeF--ThF4 for Te

  15. The 2009 Relay Race

    CERN Document Server

    2009-01-01

    The 2009 CERN Relay Race was as popular as ever, with a record number of 88 teams competing. var flash_video_player=get_video_player_path(); insert_player_for_external('Video/Public/Movies/2009/CERN-MOVIE-2009-048/CERN-MOVIE-2009-048-0753-kbps-480x360-25-fps-audio-64-kbps-44-kHz-stereo', 'mms://mediastream.cern.ch/MediaArchive/Video/Public/Movies/2009/CERN-MOVIE-2009-048/CERN-MOVIE-2009-048-Multirate-200-to-753-kbps-480x360.wmv', 'false', 288, 216, 'https://mediastream.cern.ch/MediaArchive/Video/Public/Movies/2009/CERN-MOVIE-2009-048/CERN-MOVIE-2009-048-posterframe-480x360-at-10-percent.jpg', '1178303', true, 'Video/Public/Movies/2009/CERN-MOVIE-2009-048/CERN-MOVIE-2009-048-0600-kbps-maxH-360-25-fps-audio-128-kbps-48-kHz-stereo.mp4'); Even the rain didn’t dampen the spirits, and it still managed to capture the ‘festival feeling’ with live music, beer and stalls from various CERN clubs set up outside Restaurant 1. The Powercuts on the podium after win...

  16. The power relay satellite

    Science.gov (United States)

    Glaser, Peter E.

    The availability and use of renewable energy sources compatible with reducing risks to the global environment are key to sustainable development. Large-scale, renewable energy resources at undeveloped or underutilized sites are potentially available on several continents. The Power Relay Satellite (PRS) concept has the potential to access these remote energy resources by coupling primary electricity generation from terrestrial transmission lines. A global PRS network can be envisioned to provide a high degree of flexibility for supplying energy demands worldwide with wireless power transmitted from sites on Earth to geosynchronous orbit and then reflected to receivers interfacing with terrestrial power transmision networks. Past developments in wireless power transmission (WPT) are reviewed and recent successful results are noted. The origins of the PRS concept, and a possible configuration are discussed, principles of WPT at microwave frequencies, functional requirements, and system design contraints are outlined, and space transportation concepts presented. PRS assessments including applicable technologies, economic projections, and societal issues are highlighted. It is concluded that the PRS provides a promising option to access renewable resources at great distances from major markets, and represents an important stage in the future development in the future of solar power satellites.

  17. Chemistry

    International Nuclear Information System (INIS)

    Research and development activities dealing with the chemical problems related to design and ultimate operation of molten-salt reactor systems are described. An experimental test stand was constructed to expose metallurgical test specimens to Te2 vapor at defined temperatures and deposition rates. To better define the chemistry of fluoroborate coolant, several aspects are being investigated. The behavior of hydroxy and oxy compounds in molten NaBF4 is being investigated to define reactions and compounds that may be involved in corrosion and/or could be involved in methods for trapping tritium. Two corrosion products of Hastelloy N, Na3CrF6 and Na5Cr3F14, were identified from fluoroborate systems. The evaluation of fluoroborate and alternate coolants continued. Research on the behavior of hydrogen and its isotopes is summarized. The solubilities of hydrogen, deuterium, and helium in Li2BeF4 are very low. The sorption of tritium on graphite was found to be significant (a few milligrams of tritium per kilogram of graphite), possibly providing a means of sequestering a portion of the tritium produced. Development of analytical methods continued with emphasis on voltammetric and spectrophotometric techniques for the in-line analysis of corrosion products such as Fe2+ and Cr3+ and the determination of the U3+/U4+ ratio in MSBR fuel salt. Similar studies were conducted with the NaBF4--NaF coolant salt. Information developed during the previous operation of the CSTF has been assessed and used to formulate plans for evaluation of in-line analytical methods in future CSTF operations. Electroanalytical and spectrophotometric research suggests that an electroactive protonic species is present in molten NaBF4--NaF, and that this species rapidly equilibrates with a volatile proton-containing species. Data obtained from the CSTF indicated that tritium was concentrated in the volatile species. (JGB)

  18. Chemical Modeling of Cometary Anions

    Science.gov (United States)

    Cordiner, Martin; Charnley, S. B.

    2009-09-01

    The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of 1P/Halley. The anions O-, OH-, C-, CH- and CN- have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu (Chaizy et al. 1991). Organic molecular anions are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas-phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not previously been explored. We present details of the first attempt to model the chemistry of anions in cometary comae. Based on the combined chemical and hydrodynamical model of Rodgers & Charnley (2002), we investigate the role of the hydrocarbon and nitrile anions Cn-, CnH- and CnN- in the coma. We calculate the effects of these anions on the charge balance and examine their impact on cometary coma chemistry. References: Chaizy, P. et al. 1991, Nature, 349, 393 Rodgers, S.D. & Charnley, S.B. 2002, MNRAS, 330, 660

  19. Macropolyhedral boron-containing cluster chemistry. The reversible disassembly and reassembly of the hexagonal pyramidal {B7} feature in the [S2B18H19]- anion.

    Science.gov (United States)

    Ormsby, Daniel L; Greatrex, Robert; Kennedy, John D

    2008-03-28

    The [S(2)B(18)H(19)](-) anion 1, from syn-B(18)H(22) 2 with NaH and elemental sulfur, has an unusual arachno-type eleven-vertex {SB(10)} subcluster that has an open hexagonal pyramidal {B(7)} structural feature. This is conjoined, with two boron atoms in common, to a second {SB(10)} subcluster of conventional nido eleven-vertex geometry. Protonation of 1 forms neutral [S(2)B(18)H(20)] 4. Subsequent deprotonation of 4 yields the fluxional [S(2)B(18)H(19)](-) anion 5, which is isomeric with 1. Neutral 4and anion 5 do not have the {B(7)} hexagonal pyramidal feature. Neutral 4 consists of conventional nido eleven-vertex {SB(10)} and arachno ten-vertex {SB(9)} subclusters conjoined with a single spiro boron atom in common. Anion 5 is closely related to 4, but with an additional inter-boron intercluster link. Anion 5 spontaneously reverts to anion 1 over a few hours at room temperature, remarkable in that the open {B(7)} hexagonal pyramid is regenerated. DFT B3LYP/6-31G* calculations suggest definitive structures for 4 and 5 that are substantiated by agreement between observed NMR delta((11)B) values and boron nuclear shielding as calculated by the GIAO approach on the DFT-calculated structures. Extension of this approach additionally defines transition states and intermediates for the fluxionality of 5, and also for the reassembly of the starting anion 1, together with its {B(7)} feature, from fluxional 5. The fluxionality of 5 involves the inter-subcluster transfer of a {BH} unit. The reassembly of 1 from 5 involves a DSD rearrangement and two successive hydrogen-atom hops. Confidence in the application of this method to these large macropolyhedral assemblies is afforded in the first instance by good agreement between delta((11)B)(OBS) and delta((11)B)(CALC) for the structurally characterised original anion 1, the only species amongst these to be crystallographically established. PMID:18335146

  20. Performance limitations of relay neurons.

    Directory of Open Access Journals (Sweden)

    Rahul Agarwal

    Full Text Available Relay cells are prevalent throughout sensory systems and receive two types of inputs: driving and modulating. The driving input contains receptive field properties that must be transmitted while the modulating input alters the specifics of transmission. For example, the visual thalamus contains relay neurons that receive driving inputs from the retina that encode a visual image, and modulating inputs from reticular activating system and layer 6 of visual cortex that control what aspects of the image will be relayed back to visual cortex for perception. What gets relayed depends on several factors such as attentional demands and a subject's goals. In this paper, we analyze a biophysical based model of a relay cell and use systems theoretic tools to construct analytic bounds on how well the cell transmits a driving input as a function of the neuron's electrophysiological properties, the modulating input, and the driving signal parameters. We assume that the modulating input belongs to a class of sinusoidal signals and that the driving input is an irregular train of pulses with inter-pulse intervals obeying an exponential distribution. Our analysis applies to any [Formula: see text] order model as long as the neuron does not spike without a driving input pulse and exhibits a refractory period. Our bounds on relay reliability contain performance obtained through simulation of a second and third order model, and suggest, for instance, that if the frequency of the modulating input increases or the DC offset decreases, then relay increases. Our analysis also shows, for the first time, how the biophysical properties of the neuron (e.g. ion channel dynamics define the oscillatory patterns needed in the modulating input for appropriately timed relay of sensory information. In our discussion, we describe how our bounds predict experimentally observed neural activity in the basal ganglia in (i health, (ii in Parkinson's disease (PD, and (iii in PD during

  1. DESIGN FOR SIMULATION KIT FOR TESTING RELAY.

    Directory of Open Access Journals (Sweden)

    ISHWARI TIWARI

    2013-10-01

    Full Text Available The companies, manufacturing relays are bound to test their products for specifications and compatibility. The production line in a company manufactures exceeds thousands of relays each day. This fact necessitates rapid and accurate testing of relays. A single person can’t handle the work alone. Even if he manages to handle, thetime consumption is more and a mistake may occur. So, it is necessary to employ an automation system for the testing of relays. The use of automated system facilitates less time consumption with the least possibility of error as relays are most important part of the circuitand they can be used as automatic switches, we are developing simulator for relay. The project is capable of testing a relay (either SPDT or DPDT along with generation of the relay testing report and its specifications on the desktop.

  2. Speech-to-Speech Relay Service

    Science.gov (United States)

    ... an STS call from any telephone. You simply call the relay center by dialing 711, and indicate you wish to ... may also receive STS calls. The calling party calls the relay center by dialing 711 and asks the CA to ...

  3. Instantaneous Relaying: Optimal Strategies and Interference Neutralization

    CERN Document Server

    Ho, Zuleita

    2012-01-01

    In a multi-user wireless network equipped with multiple relay nodes, some relays are more intelligent than other relay nodes. The intelligent relays are able to gather channel state information, perform linear processing and forward signals whereas the dumb relays is only able to serve as amplifiers. As the dumb relays are oblivious to the source and destination nodes, the wireless network can be modeled as a relay network with *smart instantaneous relay* only: the signals of source-destination arrive at the same time as source-relay-destination. Recently, instantaneous relaying is shown to improve the degrees-of-freedom of the network as compared to classical cut-set bound. In this paper, we study an achievable rate region and its boundary of the instantaneous interference relay channel in the scenario of (a) uninformed non-cooperative source-destination nodes (source and destination nodes are not aware of the existence of the relay and are non-cooperative) and (b) informed and cooperative source-destination...

  4. Robust distributed cognitive relay beamforming

    KAUST Repository

    Pandarakkottilil, Ubaidulla

    2012-05-01

    In this paper, we present a distributed relay beamformer design for a cognitive radio network in which a cognitive (or secondary) transmit node communicates with a secondary receive node assisted by a set of cognitive non-regenerative relays. The secondary nodes share the spectrum with a licensed primary user (PU) node, and each node is assumed to be equipped with a single transmit/receive antenna. The interference to the PU resulting from the transmission from the cognitive nodes is kept below a specified limit. The proposed robust cognitive relay beamformer design seeks to minimize the total relay transmit power while ensuring that the transceiver signal-to-interference- plus-noise ratio and PU interference constraints are satisfied. The proposed design takes into account a parameter of the error in the channel state information (CSI) to render the performance of the beamformer robust in the presence of imperfect CSI. Though the original problem is non-convex, we show that the proposed design can be reformulated as a tractable convex optimization problem that can be solved efficiently. Numerical results are provided and illustrate the performance of the proposed designs for different network operating conditions and parameters. © 2012 IEEE.

  5. Energy-Efficient Relay Selection and Optimal Relay Location in Cooperative Cellular Networks with Asymmetric Traffic

    CERN Document Server

    Yang, Wei; Sun, Wanlu

    2010-01-01

    Energy-efficient communication is an important requirement for mobile relay networks due to the limited battery power of user terminals. This paper considers energy-efficient relaying schemes through selection of mobile relays in cooperative cellular systems with asymmetric traffic. The total energy consumption per information bit of the battery-powered terminals, i.e., the mobile station (MS) and the relay, is derived in theory. In the Joint Uplink and Downlink Relay Selection (JUDRS) scheme we proposed, the relay which minimizes the total energy consumption is selected. Additionally, the energy-efficient cooperation regions are investigated, and the optimal relay location is found for cooperative cellular systems with asymmetric traffic. The results reveal that the MS-relay and the relay-base station (BS) channels have different influence over relay selection decisions for optimal energy-efficiency. Information theoretic analysis of the diversity-multiplexing tradeoff (DMT) demonstrates that the proposed sc...

  6. Spoiled Onions: Exposing Malicious Tor Exit Relays

    OpenAIRE

    Winter, Philipp; Lindskog, Stefan

    2014-01-01

    Several hundred Tor exit relays together push more than 1 GiB/s of network traffic. However, it is easy for exit relays to snoop and tamper with anonymised network traffic and as all relays are run by independent volunteers, not all of them are innocuous. In this paper, we seek to expose malicious exit relays and document their actions. First, we monitored the Tor network after developing a fast and modular exit relay scanner. We implemented several scanning modules for detecting common attac...

  7. Anion Solvation in Carbonate Electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhengcheng

    2015-11-16

    With the correlation between Li+ solvation and interphasial chemistry on anodes firmly established in Li-ion batteries, the effect of cation–solvent interaction has gone beyond bulk thermodynamic and transport properties and become an essential element that determines the reversibility of electrochemistry and kinetics of Li-ion intercalation chemistries. As of now, most studies are dedicated to the solvation of Li+, and the solvation of anions in carbonate-based electrolytes and its possible effect on the electrochemical stability of such electrolytes remains little understood. As a mirror effort to prior Li+ solvation studies, this work focuses on the interactions between carbonate-based solvents and two anions (hexafluorophosphate, PF6–, and tetrafluoroborate, BF4–) that are most frequently used in Li-ion batteries. The possible correlation between such interaction and the interphasial chemistry on cathode surface is also explored.

  8. STBC AF relay for unmanned aircraft system

    Science.gov (United States)

    Adachi, Fumiyuki; Miyazaki, Hiroyuki; Endo, Chikara

    2015-01-01

    If a large scale disaster similar to the Great East Japan Earthquake 2011 happens, some areas may be isolated from the communications network. Recently, unmanned aircraft system (UAS) based wireless relay communication has been attracting much attention since it is able to quickly re-establish the connection between isolated areas and the network. However, the channel between ground station (GS) and unmanned aircraft (UA) is unreliable due to UA's swing motion and as consequence, the relay communication quality degrades. In this paper, we introduce space-time block coded (STBC) amplify-and-forward (AF) relay for UAS based wireless relay communication to improve relay communication quality. A group of UAs forms single frequency network (SFN) to perform STBC-AF cooperative relay. In STBC-AF relay, only conjugate operation, block exchange and amplifying are required at UAs. Therefore, STBC-AF relay improves the relay communication quality while alleviating the complexity problem at UAs. It is shown by computer simulation that STBC-AF relay can achieve better throughput performance than conventional AF relay.

  9. Alternate transmission with half-duplex relaying in MIMO interference relay networks

    KAUST Repository

    Park, Seongho

    2013-12-01

    In this paper, we consider an alternate transmission scheme for a multiple-input multiple-output interference relay channel where multiple sources transmit their own signals to their corresponding destinations via one of two relaying groups alternately every time phase. Each of the relaying groups has arbitrary number of relays, and each relay operates in half-duplex amplify-and-forward mode. In our scheme, the received signals at the relay nodes consist of desired signals and two different interference signals such as the inter-source interferences and the inter-group interferences which are caused by the phase incoherence of relaying. As such, we propose an iterative interference alignment algorithm to mitigate the interferences. We show that our proposed scheme achieves additional degrees of freedom compared to the conventional half-duplex relaying system in the interference relay channels. © 2013 IEEE.

  10. Lunar Exploration Communications Relay Microsatellite

    OpenAIRE

    Kolodziejski, Paul; Knowles, Steve; Dar, Kauser; Wetzel, Eric

    2007-01-01

    In 2005 Andrews Space, Inc. completed some preliminary microsatellite design work for a NASA Cislunar flight experiment known as Micro-X. This paper describes a low-risk satellite design option that leverages the work completed under the Micro-X contract and addresses NASA's near-term Robotic Lunar Exploration Program (RLEP) Objectives. Specifically, this paper describes enhancements to the Micro-X design that includes additional communication and data relay technologies with the Lunar Roboti...

  11. Energy efficient circuit design using nanoelectromechanical relays

    Science.gov (United States)

    Venkatasubramanian, Ramakrishnan

    Nano-electromechanical (NEM) relays are a promising class of emerging devices that offer zero off-state leakage and behave like an ideal switch. Recent advances in planar fabrication technology have demonstrated that microelectromechanical (MEMS) scale miniature relays could be manufactured reliably and could be used to build fully functional, complex integrated circuits. The zero leakage operation of relays has renewed the interest in relay based low power logic design. This dissertation explores circuit architectures using NEM relays and NEMS-CMOS heterogeneous integration. Novel circuit topologies for sequential logic, memory, and power management circuits have been proposed taking into consideration the NEM relay device properties and optimizing for energy efficiency and area. In nanoscale electromechanical devices, dispersion forces like Van der Waals' force (vdW) affect the pull-in stability of the relay devices significantly. Verilog-A electromechanical model of the suspended gate relay operating at 1V with a nominal air gap of 5 - 10nm has been developed taking into account all the electrical, mechanical and dispersion effects. This dissertation explores different relay based latch and flip-flop topologies. It has been shown that as few as 4 relay cells could be used to build flip-flops. An integrated voltage doubler based flip flop that improves the performance by 2X by overdriving Vgb has been proposed. Three NEM relay based parallel readout memory bitcell architectures have been proposed that have faster access time, and remove the reliability issues associated with previously reported serial readout architectures. A paradigm shift in design of power switches using NEM relays is proposed. An interesting property of the relay device is that the ON state resistance (Ron) of the NEM relay switch is constant and is insensitive to the gate slew rate. This coupled with infinite OFF state resistance (Roff ) offers significant area and power advantages over CMOS

  12. Opportunistic Relay Selection With Limited Feedback

    KAUST Repository

    Eltayeb, Mohammed E.

    2015-08-01

    Relay selection is a simple technique that achieves spatial diversity in cooperative relay networks. Generally, relay selection algorithms require channel state information (CSI) feedback from all cooperating relays to make a selection decision. This requirement poses two important challenges, which are often neglected in the literature. Firstly, the fed back channel information is usually corrupted by additive noise. Secondly, CSI feedback generates a great deal of feedback overhead (air-time) that could result in significant performance hits. In this paper, we propose a compressive sensing (CS) based relay selection algorithm that reduces the feedback overhead of relay networks under the assumption of noisy feedback channels. The proposed algorithm exploits CS to first obtain the identity of a set of relays with favorable channel conditions. Following that, the CSI of the identified relays is estimated using least squares estimation without any additional feedback. Both single and multiple relay selection cases are considered. After deriving closed-form expressions for the asymptotic end-to-end SNR at the destination and the feedback load for different relaying protocols, we show that CS-based selection drastically reduces the feedback load and achieves a rate close to that obtained by selection algorithms with dedicated error-free feedback. © 1972-2012 IEEE.

  13. Performance analysis of opportunistic nonregenerative relaying

    KAUST Repository

    Tourki, Kamel

    2013-01-01

    Opportunistic relaying in cooperative communication depends on careful relay selection. However, the traditional centralized method used for opportunistic amplify-and-forward protocols requires precise measurements of channel state information at the destination. In this paper, we adopt the max-min criterion as a relay selection framework for opportunistic amplify-and-forward cooperative communications, which was exhaustively used for the decode-and-forward protocol, and offer an accurate performance analysis based on exact statistics of the local signal-to-noise ratios of the best relay. Furthermore, we evaluate the asymptotical performance and deduce the diversity order of our proposed scheme. Finally, we validate our analysis by showing that performance simulation results coincide with our analytical results over Rayleigh fading channels, and we compare the max-min relay selection with their centralized channel state information-based and partial relay selection counterparts.

  14. Alternate transmission relaying based on interference alignment in 3-relay half-duplex MIMO systems

    KAUST Repository

    Park, Seongho

    2012-09-01

    In a half-duplex relaying, the capacity pre-log factor 1/2 is a major drawback in spectral efficiency. This paper proposes a linear precoding/decoding scheme and an alternate relaying protocol in a dual-hop half-duplex system where three relays help the communication between the source and the destination. In our proposed scheme, we consider a phase incoherent method in relays in which the source alternately transmits message signals to the different relays. In addition, we propose a linear interference alignment scheme which can suppress the inter-relay interference resulting from the phase incoherence of relaying. Based on our analysis of degrees of freedom and our simulation results, we show that our proposed scheme achieves additional degrees of freedom compared to the conventional half-duplex relaying. © 2012 IEEE.

  15. Linear beamformer schemes with simple relay selection in MIMO relay networks

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    This article considers a wireless multi-hop/mesh network where single multi-antenna source-destination pair communicates through a selected relay subset using simple relay selection under the constraint of fixed relay's number. Compared with random selection, the simple relay selection can yield certain capacity advantages while linear zero-forcing (ZF) receiver and linear beamformer are considered at the relay. For match-filter (MF) beamformer and amplified-and-forward (AF) beamformer with a fixed number of relays, the capacities are given. Furthermore, we extend the simple selection methods to the relaying scheme with orthogonal-triangular (QR) beamformer and investigate these linear beamformer schemes over spatially correlated multi-input multi-output (MIMO) links for both the backward and forward channel over the two-hop MIMO relay networks.

  16. Inhomogeneity induces relay synchronization in complex networks

    Science.gov (United States)

    Gambuzza, Lucia Valentina; Frasca, Mattia; Fortuna, Luigi; Boccaletti, Stefano

    2016-04-01

    Relay synchronization is a collective state, originally found in chains of interacting oscillators, in which uncoupled dynamical units synchronize through the action of mismatched inner nodes that relay the information but do not synchronize with them. It is demonstrated herein that relay synchronization is not limited to such simple motifs, rather it can emerge in larger and arbitrary network topologies. In particular, we show how this phenomenon can be observed in networks of chaotic systems in the presence of some mismatched units, the relay nodes, and how it is actually responsible for an enhancement of synchronization in the network.

  17. Relay self interference minimisation using tapped filter

    KAUST Repository

    Jazzar, Saleh

    2013-05-01

    In this paper we introduce a self interference (SI) estimation and minimisation technique for amplify and forward relays. Relays are used to help forward signals between a transmitter and a receiver. This helps increase the signal coverage and reduce the required transmitted signal power. One problem that faces relays communications is the leaked signal from the relay\\'s output to its input. This will cause an SI problem where the new received signal at the relay\\'s input will be added with the unwanted leaked signal from the relay\\'s output. A Solution is proposed in this paper to estimate and minimise this SI which is based upon using a tapped filter at the destination. To get the optimum weights for this tapped filter, some channel parameters must be estimated first. This is performed blindly at the destination without the need of any training. This channel parameter estimation method is named the blind-self-interference-channel-estimation (BSICE) method. The next step in the proposed solution is to estimate the tapped filter\\'s weights. This is performed by minimising the mean squared error (MSE) at the destination. This proposed method is named the MSE-Optimum Weight (MSE-OW) method. Simulation results are provided in this paper to verify the performance of BSICE and MSE-OW methods. © 2013 IEEE.

  18. Structural chemistry of A2MX4 compounds (X = O, F) with isolated tetrahedral anions: search for the densest structure types.

    Science.gov (United States)

    Nalbandyan, Vladimir; Novikova, Anastasiya

    2012-06-01

    The packing density of various structures is important not only for understanding and the prediction of high-pressure phase transitions, but also because of its reported correlation with thermodynamic stability. Plotting the cube root of formula volume against the cation radii (R) for nine morphotropic series with isolated tetrahedral anions, A(2)MO(4) (M = Si, Ge, S, Se, Cr, Mn, Mo, W) and A(2)BeF(4), permits the comparison of packing densities for 13 structure types (about 80 individual compounds and several solid solutions) stable at (or near) ambient temperature. The spinel type is the densest. The next densest types are those of K(2)MoO(4), Tl(2)CrO(4), β-Ca(2)SiO(4), β-K(2)SO(4), Ag(2)CrO(4) and Sr(2)GeO(4). In three series (M = Ge, Mo, W) the densest type comes with somewhat intermediate values of R, and not the largest, in contrast to the classical homology rule. Another contradiction with traditional views is that some of the densest phases have abnormally low overall binding energies. The correlation between packing density and coordination number (CN) is better when CN of A counts entire MX(4) groups rather than individual X atoms; many, but not all, A(2)MX(4) structures have binary A(2)M analogues (of course, A and M are not necessarily the same in these structure types). The most frequent arrangement of A around M is of the Ni(2)In type: a (distorted) pentacapped trigonal prism. PMID:22610673

  19. Relay Selection and Resource Allocation in One-Way and Two-Way Cognitive Relay Networks

    KAUST Repository

    Alsharoa, Ahmad M.

    2013-05-08

    In this work, the problem of relay selection and resource power allocation in one- way and two-way cognitive relay networks using half duplex channels with different relaying protocols is investigated. Optimization problems for both single and multiple relay selection that maximize the sum rate of the secondary network without degrading the quality of service of the primary network by respecting a tolerated interference threshold were formulated. Single relay selection and optimal power allocation for two-way relaying cognitive radio networks using decode-and-forward and amplify-and-forward protocols were studied. Dual decomposition and subgradient methods were used to find the optimal power allocation. The transmission process to exchange two different messages between two transceivers for two-way relaying technique takes place in two time slots. In the first slot, the transceivers transmit their signals simultaneously to the relay. Then, during the second slot the relay broadcasts its signal to the terminals. Moreover, improvement of both spectral and energy efficiency can be achieved compared with the one-way relaying technique. As an extension, a multiple relay selection for both one-way and two-way relaying under cognitive radio scenario using amplify-and-forward were discussed. A strong optimization tool based on genetic and iterative algorithms was employed to solve the 
formulated optimization problems for both single and multiple relay selection, where discrete relay power levels were considered. Simulation results show that the practical and low-complexity heuristic approaches achieve almost the same performance of the optimal relay selection schemes either with discrete or continuous power distributions while providing a considerable saving in terms of computational complexity.

  20. Demonstration Model of Self Inductance Using Relay

    Indian Academy of Sciences (India)

    2016-05-01

    Using an electrical component like a relay, the phenomenonof self inductance caneasily be demonstrated to undergraduatestudents. By wiring simple electrical components like relay,neon bulb and a DC power supply, intermittent backelectromotive force (emf) can be generated in the range from60 to 100 volt. The glowing of neon bulb provides visualevidence for the generation of large back emf due to selfinductance.

  1. Opportunistic Relay Selection with Cooperative Macro Diversity

    Directory of Open Access Journals (Sweden)

    Yu Chia-Hao

    2010-01-01

    Full Text Available We apply a fully opportunistic relay selection scheme to study cooperative diversity in a semianalytical manner. In our framework, idle Mobile Stations (MSs are capable of being used as Relay Stations (RSs and no relaying is required if the direct path is strong. Our relay selection scheme is fully selection based: either the direct path or one of the relaying paths is selected. Macro diversity, which is often ignored in analytical works, is taken into account together with micro diversity by using a complete channel model that includes both shadow fading and fast fading effects. The stochastic geometry of the network is taken into account by having a random number of randomly located MSs. The outage probability analysis of the selection differs from the case where only fast fading is considered. Under our framework, distribution of the received power is formulated using different Channel State Information (CSI assumptions to simulate both optimistic and practical environments. The results show that the relay selection gain can be significant given a suitable amount of candidate RSs. Also, while relay selection according to incomplete CSI is diversity suboptimal compared to relay selection based on full CSI, the loss in average throughput is not too significant. This is a consequence of the dominance of geometry over fast fading.

  2. On the achievable degrees of freedom of alternate MIMO relaying with multiple AF relays

    KAUST Repository

    Park, Kihong

    2012-03-01

    In this paper, we consider a two-hop relaying network where one source, one destination, and multiple amplify-and-forward (AF) relays equipped with M antennas operate in a half-duplex mode. In order to compensate for the inherent loss of capacity pre-log factor of 1/2 due to half-duplex relaying, we propose a new transmission protocol which combines alternate relaying and inter-relay interference alignment. We prove that the proposed scheme can (i) exploits M degrees of freedom (DOFs) and (ii) perfectly recover the pre-log factor loss if the number of relays is at least six. From our selected numerical results, we show that our proposed scheme gives significant improvement over conventional AF relaying which offers only M/2 DOFs. © 2012 IEEE.

  3. Decode and Zero-Forcing Forward Relaying with Relay Selection in Cognitive Radio Systems

    KAUST Repository

    Park, Kihong

    2014-05-01

    In this paper, we investigate a cognitive radio (CR) relay network with multiple relay nodes that help forwarding the signal of CR users. Best relay selection is considered to take advantage of its low complexity of implementation. When the primary user (PU) is located close to the relay nodes, the performance of the secondary network is severely degraded due to the interference power constraint during the transmission in the second hop. We propose a decode and zero-forcing forward scheme to suppress the interference power at the relay nodes and analyze the statistics of the end-to-end signal-to-noise ratio when the relay nodes are located arbitrarily and experience therefore non-identical Rayleigh fading channels. Numerical results validate our theoretical results and show that our proposed scheme improves the performance of the CR network when the PU is close to the relay nodes. © 2014 IEEE.

  4. Opportunistic Adaptive Relaying in Cognitive Radio Networks

    CERN Document Server

    Jaafar, Wael; Haccoun, David

    2012-01-01

    Combining cognitive radio technology with user cooperation could be advantageous to both primary and secondary transmissions. In this paper, we propose a first relaying scheme for cognitive radio networks (called "Adaptive relaying scheme 1"), where one relay node can assist the primary or the secondary transmission with the objective of improving the outage probability of the secondary transmission with respect to a primary outage probability threshold. Upper bound expressions of the secondary outage probability using the proposed scheme are derived over Rayleigh fading channels. Numerical and simulation results show that the secondary outage probability using the proposed scheme is lower than that of other relaying schemes. Then, we extend the proposed scheme to the case where the relay node has the ability to decode both the primary and secondary signals and also can assist simultaneously both transmissions. Simulations show the performance improvement that can be obtained due to this extension in terms of...

  5. On Alternate Relaying with Improper Gaussian Signaling

    KAUST Repository

    Gaafar, Mohamed

    2016-06-06

    In this letter, we investigate the potential benefits of adopting improper Gaussian signaling (IGS) in a two-hop alternate relaying (AR) system. Given the known benefits of using IGS in interference-limited networks, we propose to use IGS to relieve the inter-relay interference (IRI) impact on the AR system assuming no channel state information is available at the source. In this regard, we assume that the two relays use IGS and the source uses proper Gaussian signaling (PGS). Then, we optimize the degree of impropriety of the relays signal, measured by the circularity coefficient, to maximize the total achievable rate. Simulation results show that using IGS yields a significant performance improvement over PGS, especially when the first hop is a bottleneck due to weak source-relay channel gains and/or strong IRI.

  6. Secure Computation in a Bidirectional Relay

    CERN Document Server

    Kashyap, Navin; Thangaraj, Andrew

    2012-01-01

    Bidirectional relaying, where a relay helps two user nodes to exchange equal length binary messages, has been an active area of recent research. A popular strategy involves a modified Gaussian MAC, where the relay decodes the XOR of the two messages using the naturally-occurring sum of symbols simultaneously transmitted by user nodes. In this work, we consider the Gaussian MAC in bidirectional relaying with an additional secrecy constraint for protection against a honest but curious relay. The constraint is that, while the relay should decode the XOR, it should be fully ignorant of the individual messages of the users. We exploit the symbol addition that occurs in a Gaussian MAC to design explicit strategies that achieve perfect independence between the received symbols and individual transmitted messages. Our results actually hold for a more general scenario where the messages at the two user nodes come from a finite Abelian group, and the relay must decode the sum within the group of the two messages. We pr...

  7. Packet scheduling for OFDMA based relay networks

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The combination of relay networks with orthogonal frequency division multiple access (OFDMA) has been proposed as a promising solution for the next generation wireless system. Considering different traffic classes and user quality of service (QoS), three efficient scheduling algorithms are introduced in such networks. The round-robin (RR) algorithm in relay networks serves as a performance benchmark. Numerical results show that the proposed algorithms achieve significant improvement on system throughput and decrease system packet loss rate, compared with the RR and absence of relaying system (traditional network). Furthermore, comparisons have been carried out among the three proposed algorithms.

  8. Transmission line protection relay : an overview

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, R.P. [Compton Greaves Ltd., Mumbai (India). Global Research and Development Centre

    2008-07-01

    A protective relay senses abnormal conditions in power transmission grid and issues an alarm or trip signal. This paper described various functions in a transmission line protection relay. These functions use the voltages and currents at the relay location. Transmission line protection is based on the measurement of impedance. Various algorithms are used by different manufacturers to issue trip signal within a cycle. There is much scope in the transmission line protection with the incorporation of FACTS devices into the transmission system. This paper included a description of the protection functions, secondary supervision functions, as well as control and monitoring functions 5 refs., 2 figs.

  9. Study on reliability technology of contactor relay

    Institute of Scientific and Technical Information of China (English)

    LIU Guo-jin; ZHAO Jing-ying; WANG Hai-tao; YANG Chen-guang; SUN Shun-li

    2007-01-01

    In this paper, the reliability of contactor relay is studied. There are three main parts about reliability test and analysis. First, in order to analyze reliability level of contact relay, the failure ratio ranks are established as index base on the product level. Second, the reliability test method is put forward. The sample plan of reliability compliance test is gained from reliability sample theory. The failure criterion is ensured according to the failure modes of contactor relay. Third, after reliability test experiment, the analysis of failure physics is made and the failure reason is found.

  10. Application of a proposed overcurrent relay in radial distribution networks

    Energy Technology Data Exchange (ETDEWEB)

    Conde, A.; Vazquez, E. [Universidad Autonoma de Nuevo Leon, Facultad de Ingenieria Mecanica y Electrica, A.P. 36-F, CU, CP 66450, San Nicolas de los Garza, Nuevo Leon (Mexico)

    2011-02-15

    This paper contains the application criteria and coordination process for a proposed overcurrent relay in a radial power system with feed from one or multiple sources. This relay uses independent functions to detect faults and to calculate the operation time. Also this relay uses a time element function that allows it to reduce the time relay operation, enhancing the backup protection. Some of the proposed approaches improve the sensitivity of the relay. The selection of the best approach in the proposed relay is defined by the needs of the application. The proposed protection can be considered as an additional function protection to conventional overcurrent relays. (author)

  11. Time of arrival based location estimation for cooperative relay networks

    KAUST Repository

    Çelebi, Hasari Burak

    2010-09-01

    In this paper, we investigate the performance of a cooperative relay network performing location estimation through time of arrival (TOA). We derive Cramer-Rao lower bound (CRLB) for the location estimates using the relay network. The analysis is extended to obtain average CRLB considering the signal fluctuations in both relay and direct links. The effects of the channel fading of both relay and direct links and amplification factor and location of the relay node on average CRLB are investigated. Simulation results show that the channel fading of both relay and direct links and amplification factor and location of relay node affect the accuracy of TOA based location estimation. ©2010 IEEE.

  12. Distributed Antenna Channels with Regenerative Relaying: Relay Selection and Asymptotic Capacity

    Directory of Open Access Journals (Sweden)

    Aitor del Coso

    2007-11-01

    Full Text Available Multiple-input-multiple-output (MIMO techniques have been widely proposed as a means to improve capacity and reliability of wireless channels, and have become the most promising technology for next generation networks. However, their practical deployment in current wireless devices is severely affected by antenna correlation, which reduces their impact on performance. One approach to solve this limitation is relaying diversity. In relay channels, a set of N wireless nodes aids a source-destination communication by relaying the source data, thus creating a distributed antenna array with uncorrelated path gains. In this paper, we study this multiple relay channel (MRC following a decode-and-forward (D&F strategy (i.e., regenerative forwarding, and derive its achievable rate under AWGN. A half-duplex constraint on relays is assumed, as well as distributed channel knowledge at both transmitter and receiver sides of the communication. For this channel, we obtain the optimum relay selection algorithm and the optimum power allocation within the network so that the transmission rate is maximized. Likewise, we bound the ergodic performance of the achievable rate and derive its asymptotic behavior in the number of relays. Results show that the achievable rate of regenerative MRC grows as the logarithm of the Lambert W function of the total number of relays, that is, 𝒞=log⁡2(W0(N. Therefore, D&F relaying, cannot achieve the capacity of actual MISO channels.

  13. Distributed Antenna Channels with Regenerative Relaying: Relay Selection and Asymptotic Capacity

    Directory of Open Access Journals (Sweden)

    del Coso Aitor

    2007-01-01

    Full Text Available Multiple-input-multiple-output (MIMO techniques have been widely proposed as a means to improve capacity and reliability of wireless channels, and have become the most promising technology for next generation networks. However, their practical deployment in current wireless devices is severely affected by antenna correlation, which reduces their impact on performance. One approach to solve this limitation is relaying diversity. In relay channels, a set of wireless nodes aids a source-destination communication by relaying the source data, thus creating a distributed antenna array with uncorrelated path gains. In this paper, we study this multiple relay channel (MRC following a decode-and-forward (D&F strategy (i.e., regenerative forwarding, and derive its achievable rate under AWGN. A half-duplex constraint on relays is assumed, as well as distributed channel knowledge at both transmitter and receiver sides of the communication. For this channel, we obtain the optimum relay selection algorithm and the optimum power allocation within the network so that the transmission rate is maximized. Likewise, we bound the ergodic performance of the achievable rate and derive its asymptotic behavior in the number of relays. Results show that the achievable rate of regenerative MRC grows as the logarithm of the Lambert W function of the total number of relays, that is, . Therefore, D&F relaying, cannot achieve the capacity of actual MISO channels.

  14. Partial relay selection in underlay cognitive networks with fixed gain relays

    KAUST Repository

    Hussain, Syed Imtiaz

    2012-05-01

    In a communication system with multiple cooperative relays, selecting the best relay utilizes the available spectrum more efficiently. However, selective relaying poses a different problem in underlay cognitive networks compared to the traditional cooperative networks due to interference thresholds to the primary users. In most cases, a best relay is the one which provides the maximum end-to-end signal to noise ratio (SNR). This approach needs plenty of instantaneous channel state information (CSI). The CSI burden could be reduced by partial relay selection. In this paper, a partial relay selection scheme is presented and analyzed for an underlay cognitive network with fixed gain relays operating in the vicinity of a primary user. The system model is adopted in a way that each node needs minimal CSI to perform its task. The best relay is chosen on the basis of maximum source to relay link SNR which then forwards the message to the destination. We derive closed form expressions for the received SNR distributions, system outage, probability of bit error and average channel capacity of the system. The derived results are confirmed through simulations. © 2012 IEEE.

  15. Reversible photochromism of an N-salicylidene aniline anion

    OpenAIRE

    Jacquemin, Pierre-Loïc; Robeyns, Koen; Devillers, Michel; Garcia, Yann

    2014-01-01

    The first N-salicylidene aniline anion showing reversible solid state thermochromic and photochromic properties is described. The photo-isomerization involves a trans-keto form which is stabilized thanks to the local anion surrounding. This photochromic anion can be used as a guest for the preparation of hybrid materials by insertion into a cationic host matrix. © 2014 The Royal Society of Chemistry.

  16. Fluorinated and trifluoromethylated CB11 carborane anions and radicals

    Czech Academy of Sciences Publication Activity Database

    Higelin, Alexander; Šembera, Filip; Tamadon, F.; Wahab, Abdul; Janoušek, Zbyněk; Ludvík, Jiří; Klíma, Jiří; Crespo, R.; Piqueras, M. C.; Michl, Josef

    San Francisco: American Chemical Society, 2014. 37FLUO. [ACS National Meeting & Exposition /248./. 10.08.2014-14.08.2014, San Francisco] Institutional support: RVO:61388963 Keywords : carborane anions Subject RIV: CC - Organic Chemistry

  17. Relay Runners Catch The Rays

    CERN Multimedia

    2004-01-01

    Athletes sizzled around CERN on Wednesday 19 May at the 34th annual relay race. On one of the warmest days of the year so far, sunkissed competitors ran for the finish line and then straight for the drinks table. The Shabbys were on fire again, hurtling across the line first in a time of 10 min. 42.6 sec. and making an even stronger claim to being hailed as the traditional winners of the race with their fourth triumph in a row. Also on form were the Lynx Runners who won the Veteran's trophy, continuing their winning ways since 2002 and placing 29th overall. Ildefons Magrans of the ALICE Quarks on the Loose team ran the fastest 1000m in a time of 2 min. 47 sec. Second-placed Charmilles Technologies won the Open category in a time of 11 min. 03 sec., taking the prize for teams whose members work in different departments or who come from outside CERN. The OPALadies won the women's trophy and placed 48th. With 9 trophies up for grabs, more than 300 people in 55 teams ran the fun run, covering distances of 1000m ...

  18. Optimization of the relay selection scheme in cooperative retransmission networks

    OpenAIRE

    He, Xin; Li, Frank Yong

    2011-01-01

    Cooperative MAC protocol design has attracted much attention recently thanks to the development of relaying techniques. In single-relay C-ARQ, the relay selection scheme cannot work efficiently in a dense network, due to high collision probability among different contending relays. In this paper, the throughput performance impairment from the collision is analyzed in a typical network scenario. Thereby, we propose an optimized relay selection scheme aiming at maximizing system throughput by r...

  19. Relay selection from an effective capacity perspective

    KAUST Repository

    Yang, Yuli

    2013-09-01

    In this work, we consider a cooperative network where multiple relay nodes having different modulation capabilities assist the end-to-end communication between a source and its destination. Firstly, we evaluate the effective capacity (EC) performance of the network under study. According to the analysis, an EC-based relay selection criterion is proposed. Based on the proposed selection rule and half-duplex decode-and-forward protocol, the activated relays cooperatively help with the packet transmission from the source. At the destination, packet combining is taken into account to improve the quality of service. Compared to the popular scheme, opportunistic relay selection, numerical results are provided to prove the validity and advantages of our proposed scheme in certain scenarios. Moreover, the analysis presented herein offers a convenient tool to the relaying transmission design, specifically on which relay selection scheme should be used as well as how to choose the receiving strategy between with and without packet combining at the destination. © 2013 IEEE.

  20. Physical Layer Security Using Two-Path Successive Relaying.

    Science.gov (United States)

    Liau, Qian Yu; Leow, Chee Yen; Ding, Zhiguo

    2016-01-01

    Relaying is one of the useful techniques to enhance wireless physical-layer security. Existing literature shows that employing full-duplex relay instead of conventional half-duplex relay improves secrecy capacity and secrecy outage probability, but this is at the price of sophisticated implementation. As an alternative, two-path successive relaying has been proposed to emulate operation of full-duplex relay by scheduling a pair of half-duplex relays to assist the source transmission alternately. However, the performance of two-path successive relaying in secrecy communication remains unexplored. This paper proposes a secrecy two-path successive relaying protocol for a scenario with one source, one destination and two half-duplex relays. The relays operate alternately in a time division mode to forward messages continuously from source to destination in the presence of an eavesdropper. Analytical results reveal that the use of two half-duplex relays in the proposed scheme contributes towards a quadratically lower probability of interception compared to full-duplex relaying. Numerical simulations show that the proposed protocol achieves the ergodic achievable secrecy rate of full-duplex relaying while delivering the lowest probability of interception and secrecy outage probability compared to the existing half duplex relaying, full duplex relaying and full duplex jamming schemes. PMID:27294924

  1. Physical Layer Security Using Two-Path Successive Relaying

    Directory of Open Access Journals (Sweden)

    Qian Yu Liau

    2016-06-01

    Full Text Available Relaying is one of the useful techniques to enhance wireless physical-layer security. Existing literature shows that employing full-duplex relay instead of conventional half-duplex relay improves secrecy capacity and secrecy outage probability, but this is at the price of sophisticated implementation. As an alternative, two-path successive relaying has been proposed to emulate operation of full-duplex relay by scheduling a pair of half-duplex relays to assist the source transmission alternately. However, the performance of two-path successive relaying in secrecy communication remains unexplored. This paper proposes a secrecy two-path successive relaying protocol for a scenario with one source, one destination and two half-duplex relays. The relays operate alternately in a time division mode to forward messages continuously from source to destination in the presence of an eavesdropper. Analytical results reveal that the use of two half-duplex relays in the proposed scheme contributes towards a quadratically lower probability of interception compared to full-duplex relaying. Numerical simulations show that the proposed protocol achieves the ergodic achievable secrecy rate of full-duplex relaying while delivering the lowest probability of interception and secrecy outage probability compared to the existing half duplex relaying, full duplex relaying and full duplex jamming schemes.

  2. Performance Analysis of Relay Subset Selection for Amplify-and-Forward Cognitive Relay Networks

    Directory of Open Access Journals (Sweden)

    Kiran Sultan

    2014-01-01

    Full Text Available Cooperative communication is regarded as a key technology in wireless networks, including cognitive radio networks (CRNs, which increases the diversity order of the signal to combat the unfavorable effects of the fading channels, by allowing distributed terminals to collaborate through sophisticated signal processing. Underlay CRNs have strict interference constraints towards the secondary users (SUs active in the frequency band of the primary users (PUs, which limits their transmit power and their coverage area. Relay selection offers a potential solution to the challenges faced by underlay networks, by selecting either single best relay or a subset of potential relay set under different design requirements and assumptions. The best relay selection schemes proposed in the literature for amplify-and-forward (AF based underlay cognitive relay networks have been very well studied in terms of outage probability (OP and bit error rate (BER, which is deficient in multiple relay selection schemes. The novelty of this work is to study the outage behavior of multiple relay selection in the underlay CRN and derive the closed-form expressions for the OP and BER through cumulative distribution function (CDF of the SNR received at the destination. The effectiveness of relay subset selection is shown through simulation results.

  3. Relay Selection for Two-way Relaying with Amplify-and-Forward Protocols

    CERN Document Server

    Song, Lingyang

    2011-01-01

    In this paper, we propose a relay selection amplify-and-forward (RS-AF) protocol in general bi-directional relay networks with two sources and $N$ relays. In the proposed scheme, the two sources first transmit to all the relays simultaneously, and then a single relay with a minimum sum symbol error rate (SER) will be selected to broadcast the received signals back to both sources. To facilitate the selection process, we propose a simple sub-optimal Min-Max criterion for relay selection, where a single relay which minimizes the maximum SER of two source nodes will be selected. Simulation results show that the proposed Min-Max selection has almost the same performance as the optimal selection with lower complexity. We also present a simple asymptotic SER expression and make comparison with the conventional all-participate amplify-and-forward (AP-AF) relaying scheme. The analytical results are verified through simulations. To improve the system performance, optimum power allocation (OPA) between the sources and ...

  4. Reactive relay selection in underlay cognitive networks with fixed gain relays

    KAUST Repository

    Hussain, Syed Imtiaz

    2012-06-01

    Best relay selection is a bandwidth efficient technique for multiple relay environments without compromising the system performance. The problem of relay selection is more challenging in underlay cognitive networks due to strict interference constraints to the primary users. Generally, relay selection is done on the basis of maximum end-to-end signal to noise ratio (SNR). However, it requires large amounts of channel state information (CSI) at different network nodes. In this paper, we present and analyze a reactive relay selection scheme in underlay cognitive networks where the relays are operating with fixed gains near a primary user. The system model minimizes the amount of CSI required at different nodes and the destination selects the best relay on the basis of maximum relay to destination SNR. We derive close form expressions for the received SNR statistics, outage probability, bit error probability and average channel capacity of the system. Simulation results are also presented to confirm the validity of the derived expressions. © 2012 IEEE.

  5. A genetic algorithm for multiple relay selection in two-way relaying cognitive radio networks

    KAUST Repository

    Alsharoa, Ahmad M.

    2013-09-01

    In this paper, we investigate a multiple relay selection scheme for two-way relaying cognitive radio networks where primary users and secondary users operate on the same frequency band. More specifically, cooperative relays using Amplifyand- Forward (AF) protocol are optimally selected to maximize the sum rate of the secondary users without degrading the Quality of Service (QoS) of the primary users by respecting a tolerated interference threshold. A strong optimization tool based on genetic algorithm is employed to solve our formulated optimization problem where discrete relay power levels are considered. Our simulation results show that the practical heuristic approach achieves almost the same performance of the optimal multiple relay selection scheme either with discrete or continuous power distributions. Copyright © 2013 by the Institute of Electrical and Electronic Engineers, Inc.

  6. Anion exchange membrane

    Science.gov (United States)

    Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

    2013-05-07

    An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

  7. Cognitive Relay Networks: A Comprehensive Survey

    Directory of Open Access Journals (Sweden)

    Ayesha Naeem

    2015-07-01

    Full Text Available Cognitive radio is an emerging technology to deal with the scarcity and requirement of radio spectrum by dynamically assigning spectrum to unlicensed user . This revolutionary technology shifts the paradigm in the wireless system design by all owing unlicensed user the ability to sense, adapt and share the dynamic spectrum. Cognitive radio technology have been applied to different networks and applications ranging from wireless to public saf ety, smart grid, medical, rela y and cellular applications to increase the throughput and spectrum efficiency of the network. Among these applications, cognitive relay networks is one of the application where cognitive radio technology has been applied. Cognitiv e rela y network increases the network throughput by reducing the complete pa th loss and also by ensuring cooper ation among secondary users and cooperation among primary and secondary users. In this paper , our aim is to provide a survey on cognitive relay network. We also provide a detailed review on existing schemes in cognitive relay networks on the basis of relaying protocol, relay cooperation and channel model.

  8. COMPASS Final Report: Lunar Relay Satellite (LRS)

    Science.gov (United States)

    Oleson, Steven R.; McGuire, Melissa L.

    2012-01-01

    The Lunar Relay Satellite (LRS) COllaborative Modeling and Parametric Assessment of Space Systems (COMPASS) session was tasked to design a satellite to orbit in an elliptical lunar polar orbit to provide relay communications between lunar South Pole assets and the Earth. The design included a complete master equipment list, power requirement list, configuration design, and brief risk assessment and cost analysis. The LRS is a half-TDRSS sized box spacecraft, which provides communications and navigation relay between lunar outposts (via Lunar Communications Terminals (LCT)) or Sortie parties (with user radios) and large ground antennas on Earth. The LRS consists of a spacecraft containing all the communications and avionics equipment designed by NASA Jet Propulsion Laboratory s (JPL) Team X to perform the relay between lunar-based assets and the Earth. The satellite design is a standard box truss spacecraft design with a thermal control system, 1.7 m solar arrays for 1 kWe power, a 1 m diameter Ka/S band dish which provides relay communications with the LCT, and a Q-band dish for communications to/from the Earth based assets. While JPL's Team X and Goddard Space Flight Center s (GSFC) I M Design Center (IMDC) have completed two other LRS designs, this NASA Glenn Research Center (GRC) COMPASS LRS design sits between them in terms of physical size and capabilities.

  9. Aging assessment of circuit breakers and relays

    International Nuclear Information System (INIS)

    The aging of circuit breakers and relays is important since these devices provide critical services for safety related systems in nuclear plants. Failures of these devices can cause loss of vital functions as well as creating fire hazards. The aging assessments discussed in this paper were sponsored by the U.S. Nuclear Regulatory Commission's Nuclear Plant Aging Research (NPAR) Program. This research is the Phase II effort in which a test program was initiated to investigate and categorize the aging of circuit breakers and relays. The significant elements of the research consisted of the following: determination of current and advanced Inspection, Surveillance and Condition Monitoring (ISCM) Techniques for circuit breakers and relays; laboratory tests, in which new and aged samples of common circuit breakers and relays were tested using these ISCM techniques; in-situ efforts, in which ISCM techniques were performed on equipment in two nuclear plants, and degradation tests, in which ISCM techniques were performed on purposely degraded samples of circuit breakers and relays

  10. On Cooperative Relay in Cognitive Radio Networks

    Directory of Open Access Journals (Sweden)

    Donglin Hu

    2013-12-01

    Full Text Available Cognitive radios (CR and cooperative communications represent new paradigms that both can effectively improve the spectrum efficiency of future wireless networks. In this paper, we investigate the problem of cooperative relay in CR networks for further enhanced network performance. We investigate how to effectively integrate these two advanced wireless communications technologies. In particular, we focus on the two representative cooperative relay strategies, decode-and-forward (DF and amplify-and-forward (AF, and develop optimal spectrum sensing and p-Persistent CSMA for spectrum access.We develop an analysis for the comparison of these two relay strategies in the context of CR networks, and derive closed-form expressions for network-wide throughput achieved by DF, AF and direct link transmissions. Our analysis is validated by simulations. We find each of the strategies performs better in a certain parameter range; there is no case of dominance for the two strategies. The significant gaps between the cooperative relay results and the direct link results exemplify the diversity gain achieved by cooperative relays in CR networks.

  11. Quinones as Reversible Electron Relays in Artificial Photosynthesis.

    Science.gov (United States)

    Rodenberg, Alexander; Orazietti, Margherita; Mosberger, Mathias; Bachmann, Cyril; Probst, Benjamin; Alberto, Roger; Hamm, Peter

    2016-05-01

    We explore the potential of various hydroquinone/quinone redox couples as electron relays in a homogenous water reduction system between a Re-based photosensitizer and a sacrificial electron donor [tris-(2-carboxyethyl)-phosphine, TCEP]. By using transient IR spectroscopy, flash photolysis as well as stopped-flow techniques covering timescales from picoseconds to 100 ms, we determine quenching rates and cage escape yields, the kinetics of the follow-up chemistry of the semiquinone, the recombination rates, as well as the re-reduction rates by TCEP. The overall quantum yield of hydrogen production is low, and we show that the limiting factors are the small cage escape yields and, more importantly, the slow regeneration rate by TCEP in comparison to the undesired charge recombination with the reduced water reduction catalyst. PMID:26752324

  12. Non-Markovian Reactivation of Quantum Relays

    CERN Document Server

    Pirandola, Stefano; Jacobsen, Christian S; Spedalieri, Gaetana; Braunstein, Samuel L; Gehring, Tobias; Andersen, Ulrik L

    2015-01-01

    We consider a quantum relay which is used by two parties to perform several continuous-variable protocols: Entanglement swapping, distillation, quantum teleportation, and quantum key distribution. The theory of these protocols is extended to a non-Markovian model of decoherence characterized by correlated Gaussian noise. Even if bipartite entanglement is completely lost at the relay, we show that the various protocols can progressively be reactivated by the separable noise-correlations of the environment. In fact, above a critical amount, these correlations are able to restore the distribution of quadripartite entanglement, which can be localized into an exploitable bipartite form by the action of the relay. Our findings are confirmed by a proof-of-principle experiment and show the potential advantages of non-Markovian effects in a quantum network architecture.

  13. Robust Transmission for Cognitive Relay Networks

    Institute of Scientific and Technical Information of China (English)

    Cao Zhigang; Wang Jianyu; Liu Juan; Wang Xijun; Chen Wei

    2012-01-01

    In cognitive relay networks, the transmission of Secondary Users (SUs) suffers from the activity of Primary Users (PUs) and wireless channel fading. Therefore, how to achieve robust transmission for cognitive relay networks is a challenging task. In this paper, we propose a relaying transmission scheme which exploits robust beamforming at the physical layer and rateless codes at higher layers. We derive the optirml beamforng weight vector and analyze the perforrmnce of the pro- posed scheme when the channel estirmtion is not accurate between two SU nodes. We also study how the anaount of channel information between SU and PU impacts the system perforroance. Sinlation results validate our theoretical analysis and demonstrate that the proposed scheme can signifi- cantly enhance the system throughput.

  14. PSMG sets A and B protective relaying

    International Nuclear Information System (INIS)

    The ''TAN/LOFT 13.8 kV, 2.4 kV, and 480 V Relay and Circuit Breaker Coordination Study'' presented an analysis to determine overcurrent settings for the LOFT Power System protective relays including those for the drive motors of the PSMG sets. This LTR is written to form the basis of the relay settings entered in Specification ES-60238 Rev. B, for protection of the PSMG generator, primary coolant pump motor and interconnecting power cable. A momentary commercial power voltage dip occurred on January 10, 1978 which caused a trip of the PSMG field breakers. A corrective design to prevent reoccurrence is discussed and recommendations are presented

  15. CERN Relay Race: information for drivers

    CERN Document Server

    2012-01-01

    The CERN relay race will take place around the Meyrin site on Thursday, 24 May starting at 12.15. If possible, please avoid driving on the site during this 20-minute period. If you do meet runners while driving your car, please STOP until they have all passed. In addition, there will be a Nordic Walking event which will finish around 12.50. This should not block the roads, but please drive carefully during this time. Thank you for your cooperation. Details on how to register your team for the relay race can be found here.

  16. Outage performance of two-way DF relaying systems with a new relay selection metric

    KAUST Repository

    Hyadi, Amal

    2012-04-01

    This paper investigates a new constrained relay selection scheme for two-way relaying systems where two end terminals communicate simultaneously via a relay. The introduced technique is based on the maximization of the weighted sum rate of both users. To evaluate the performance of the proposed system, the outage probability is derived in a general case (where an arbitrary channel is considered), and then over independently but not necessarily identically distributed (i.n.i.d.) Rayleigh fading channels. The analytical results are verified through simulations. © 2012 IEEE.

  17. Advanced Strategic and Tactical Relay Request Management for the Mars Relay Operations Service

    Science.gov (United States)

    Allard, Daniel A.; Wallick, Michael N.; Gladden, Roy E.; Wang, Paul; Hy, Franklin H.

    2013-01-01

    This software provides a new set of capabilities for the Mars Relay Operations Service (MaROS) in support of Strategic and Tactical relay, including a highly interactive relay request Web user interface, mission control over relay planning time periods, and mission management of allowed strategic vs. tactical request parameters. Together, these new capabilities expand the scope of the system to include all elements critical for Tactical relay operations. Planning of replay activities spans a time period that is split into two distinct phases. The first phase is called Strategic, which begins at the time that relay opportunities are identified, and concludes at the point that the orbiter generates the flight sequences for on board execution. Any relay request changes from this point on are called Tactical. Tactical requests, otherwise called Orbit - er Relay State Changes (ORSC), are highly restricted in terms of what types of changes can be made, and the types of parameters that can be changed may differ from one orbiter to the next. For example, one orbiter may be able to delay the start of a relay request, while another may not. The legacy approach to ORSC management involves exchanges of e-mail with "requests for change" and "acknowledgement of approval," with no other tracking of changes outside of e-mail folders. MaROS Phases 1 and 2 provided the infrastructure for strategic relay for all supported missions. This new version, 3.0, introduces several capabilities that fully expand the scope of the system to include tactical relay. One new feature allows orbiter users to manage and "lock" Planning Periods, which allows the orbiter team to formalize the changeover from Strategic to Tactical operations. Another major feature allows users to interactively submit tactical request changes via a Web user interface. A third new feature allows orbiter missions to specify allowed tactical updates, which are automatically incorporated into the tactical change process

  18. Filter-and-Forward Transparent Relay Design for OFDM Systems

    CERN Document Server

    Kim, Donggun; Sung, Youngchul

    2012-01-01

    In this paper, the filter-and-forward (FF) relay design for orthogonal frequency-division multiplexing (OFDM) transmission systems is considered to improve the system performance over simple amplify-and-forward (AF) relaying. Unlike conventional OFDM relays performing OFDM demodulation and remodulating, to reduce processing complexity, the proposed FF relay directly filters the incoming signal with a finite impulse response (FIR) and forwards the filtered signal to the destination. Two design criteria are considered to optimize the relay filter for given source power allocation. One is to minimize the relay transmit power subject to per-subcarrier signal-to-noise ratio (SNR) constraints and the other is to maximize the worst subcarrier channel SNR subject to the total relay transmit power constraint. It is shown that the two problems reduce to semi-definite programming (SDP) problems. Furthermore, the problem of joint source power allocation and relay filter design is considered for the second criterion, and ...

  19. Dynamic Relaying in 3GPP LTE-Advanced Networks

    Directory of Open Access Journals (Sweden)

    Van Phan Vinh

    2009-01-01

    Full Text Available Relaying is one of the proposed technologies for LTE-Advanced networks. In order to enable a flexible and reliable relaying support, the currently adopted architectural structure of LTE networks has to be modified. In this paper, we extend the LTE architecture to enable dynamic relaying, while maintaining backward compatibility with LTE Release 8 user equipments, and without limiting the flexibility and reliability expected from relaying. With dynamic relaying, relays can be associated with base stations on a need basis rather than in a fixed manner which is based only on initial radio planning. Proposals are also given on how to further improve a relay enhanced LTE network by enabling multiple interfaces between the relay nodes and their controlling base stations, which can possibly be based on technologies different from LTE, so that load balancing can be realized. This load balancing can be either between different base stations or even between different networks.

  20. Cyber and electromagnetic threats in modern relay protection

    CERN Document Server

    Gurevich, Vladimir

    2014-01-01

    PrefaceAbstractAuthorTechnological Advance in Relay Protection: Dangerous TendenciesIssues of Philosophy in Relay ProtectionExtrusion into the Historical DomainAbout Technological AdvanceSmart Grid: One More Dangerous Vector of the ""Technological Advantages"" in Power IndustrySmart Grid Russian StyleSmart Grid: Western StyleDangerous Tendencies in the Development of the Relay ProtectionWhat to Do?ReferencesNatural Electromagnetic Effects on Digital Protective RelaysElectro

  1. Upper-Bounding the Capacity of Relay Communications - Part I

    OpenAIRE

    Shams, Farshad; Luise, Marco

    2013-01-01

    This paper focuses on the capacity of point-to-point relay communications wherein the transmitter is assisted by an intermediate relay. We detail the mathematical model of cutset and amplify and forward (AF) relaying strategy. We present the upper bound capacity of each relaying strategy from information theory viewpoint and also in networks with Gaussian channels. We exemplify various outer region capacities of the addressed strategies with two different case studies. The results exhibit tha...

  2. An Asymptotically Optimal RFID Authentication Protocol Against Relay Attacks

    CERN Document Server

    Avoine, Gildas

    2008-01-01

    Relay attacks are a major concern for RFID systems: during an authentication process an adversary transparently relays messages between a verifier and a remote legitimate prover. We present an authentication protocol suited for RFID systems. Our solution is the first that prevents relay attacks without degrading the authentication security level: it minimizes the probability that the verifier accepts a fake proof of identity, whether or not a relay attack occurs.

  3. Kalman Filtering With Relays Over Wireless Fading Channels

    OpenAIRE

    Leong, Alex S.; Quevedo, Daniel E.

    2015-01-01

    This note studies the use of relays to improve the performance of Kalman filtering over packet dropping links. Packet reception probabilities are governed by time-varying fading channel gains, and the sensor and relay transmit powers. We consider situations with multiple sensors and relays, where each relay can either forward one of the sensors' measurements to the gateway/fusion center, or perform a simple linear network coding operation on some of the sensor measurements. Using an expected ...

  4. Microprocessor protection relays: new prospects or new problems?

    OpenAIRE

    Gurevich, Vladimir

    2006-01-01

    The internal architecture and principles of operation of microprocessor-based devices including so-called "microprocessor protective relays" have little in common with devices called "electric relays". But microprocessor-based relay protection devices are gradually driving out the traditional electromechanical and even electronic relay protection of virtually from all fields of power and electrical engineering. Advantages of microprocessor-based protection means over traditional ones are far ...

  5. Diversity of MIMO Multihop Relay Channels

    CERN Document Server

    Yang, Sheng

    2007-01-01

    We consider slow fading relay channels with a single multi-antenna source-destination terminal pair. The source signal arrives at the destination via N hops through N-1 layers of relays. We analyze the diversity of such channels with fixed network size at high SNR. In the clustered case where the relays within the same layer can have full cooperation, the cooperative decode-and-forward (DF) scheme is shown to be optimal in terms of the diversity-multiplexing tradeoff (DMT). The upper bound on the DMT, the cut-set bound, is attained. In the non-clustered case, we show that the naive amplify-and-forward (AF) scheme has the maximum multiplexing gain of the channel but is suboptimal in diversity, as compared to the cut-set bound. To improve the diversity, space-time relay processing is introduced through the parallel partition of the multihop channel. The idea is to let the source signal go through K different "AF paths" in the multihop channel. This parallel AF scheme creates a parallel channel in the time domai...

  6. Relay Feedback Analysis for Double Integral Plants

    Directory of Open Access Journals (Sweden)

    Zhen Ye

    2011-01-01

    Full Text Available Double integral plants under relay feedback are studied. Complete results on the uniqueness of solutions, existence, and stability of the limit cycles are established using the point transformation method. Analytical expressions are also given for determining the amplitude and period of a limit cycle from the plant parameters.

  7. First Things First: Internet Relay Chat Openings.

    Science.gov (United States)

    Rintel, E. Sean; Mulholland, Joan; Pittam, Jeffery

    2001-01-01

    Argues that Internet Relay Chat (IRC) research needs to systematically address links between interaction structures, technological mediation and the instantiation and development of interpersonal relationships. Finds that openings that occur directly following user's entries into public IRC channels are often ambiguous, can disrupt relationship…

  8. Verifying Relay Circuits using State Machines

    NARCIS (Netherlands)

    Eijk, P.H.J. van

    2008-01-01

    In this paper we present, illustrate and discuss a number of techniques that can be used in the modelling and verification of electro-mechanical relay circuits. These techniques are based on state machine descriptions of circuits and their functions, and on applying validation tools for properties o

  9. Uplink Capacity of 802.16j Mobile Multihop Relay Networks with Transparent Relays

    DEFF Research Database (Denmark)

    Wang, Hua; Andrews, Jeffrey G.; Iversen, Villy Bæk

    2009-01-01

    This paper analyzes the potential uplink capacity gains of a two-hop 802.16J relay network operating in transparent mode. Detailed channel models and adaptive modulation and coding (AMC) in the physical layer are developed. To mitigate the capacity loss due to multihop communications, multi......-input multi-output (MIMO) transmission is applied in the relay link. We derived the cell coverage and average spectral efficiency, as well as the system Erlang capacity supporting both voice and data traffic. The numerical results show that MIMO transmission in the relay link can significantly improve the end......-to-end spectral efficiency. Furthermore, the position and the number of relay stations (RSs) have a great impact on the capacity gain. These results are further verified in the evaluation of the system Erlang capacity. The study demonstrates that with proper deployment of RSs and use of MIMO transmission in the...

  10. A low complexity algorithm for multiple relay selection in two-way relaying Cognitive Radio networks

    KAUST Repository

    Alsharoa, Ahmad M.

    2013-06-01

    In this paper, a multiple relay selection scheme for two-way relaying cognitive radio network is investigated. We consider a cooperative Cognitive Radio (CR) system with spectrum sharing scenario using Amplify-and-Forward (AF) protocol, where licensed users and unlicensed users operate on the same frequency band. The main objective is to maximize the sum rate of the unlicensed users allowed to share the spectrum with the licensed users by respecting a tolerated interference threshold. A practical low complexity heuristic approach is proposed to solve our formulated optimization problem. Selected numerical results show that the proposed algorithm reaches a performance close to the performance of the optimal multiple relay selection scheme either with discrete or continuous power distributions while providing a considerable saving in terms of computational complexity. In addition, these results show that our proposed scheme significantly outperforms the single relay selection scheme. © 2013 IEEE.

  11. Optimal relay selection and power allocation for cognitive two-way relaying networks

    KAUST Repository

    Pandarakkottilil, Ubaidulla

    2012-06-01

    In this paper, we present an optimal scheme for power allocation and relay selection in a cognitive radio network where a pair of cognitive (or secondary) transceiver nodes communicate with each other assisted by a set of cognitive two-way relays. The secondary nodes share the spectrum with a licensed primary user (PU), and each node is assumed to be equipped with a single transmit/receive antenna. The interference to the PU resulting from the transmission from the cognitive nodes is kept below a specified limit. We propose joint relay selection and optimal power allocation among the secondary user (SU) nodes achieving maximum throughput under transmit power and PU interference constraints. A closed-form solution for optimal allocation of transmit power among the SU transceivers and the SU relay is presented. Furthermore, numerical simulations and comparisons are presented to illustrate the performance of the proposed scheme. © 2012 IEEE.

  12. Exact Outage Probability of Cognitive Underlay DF Relay Networks with Best Relay Selection

    Science.gov (United States)

    Bao, Vo Nguyen Quoc; Duong, Trung Quang

    In this letter, we address the performance analysis of underlay selective decode-and-forward (DF) relay networks in Rayleigh fading channels with non-necessarily identical fading parameters. In particular, a novel result on the outage probability of the considered system is presented. Monte Carlo simulations are performed to verify the correctness of our exact closed-form expression. Our proposed analysis can be adopted for various underlay spectrum sharing applications of cognitive DF relay networks.

  13. Distributed Soft Coding with a Soft Input Soft Output (SISO) Relay Encoder in Parallel Relay Channels

    CERN Document Server

    Li, Yonghui

    2012-01-01

    In this paper, we propose a new distributed coding structure with a soft input soft output (SISO) relay encoder for error-prone parallel relay channels. We refer to it as the distributed soft coding (DISC). In the proposed scheme, each relay first uses the received noisy signals to calculate the soft symbol estimate (SSE) of the source symbols. A simple SISO encoder is developed to encode the SSEs of source symbols based on a constituent code generator matrix. The SISO encoder outputs at different relays are then forwarded to the destination and form a distributed codeword. The performance of the proposed scheme is analyzed. It is shown that its performance is determined by the generator sequence weight (GSW) of the relay constituent codes, where the GSW of a constituent code is defined as the number of ones in its generator sequence. A new coding design criterion for optimally assigning the constituent codes to all the relays is proposed based on the analysis. Results show that the proposed DISC can effectiv...

  14. Relay Precoder Optimization in MIMO-Relay Networks With Imperfect CSI

    KAUST Repository

    Ubaidulla, P.

    2011-11-01

    In this paper, we consider robust joint designs of relay precoder and destination receive filters in a nonregenerative multiple-input multiple-output (MIMO) relay network. The network consists of multiple source-destination node pairs assisted by a MIMO-relay node. The channel state information (CSI) available at the relay node is assumed to be imperfect. We consider robust designs for two models of CSI error. The first model is a stochastic error (SE) model, where the probability distribution of the CSI error is Gaussian. This model is applicable when the imperfect CSI is mainly due to errors in channel estimation. For this model, we propose robust minimum sum mean square error (SMSE), MSE-balancing, and relay transmit power minimizing precoder designs. The next model for the CSI error is a norm-bounded error (NBE) model, where the CSI error can be specified by an uncertainty set. This model is applicable when the CSI error is dominated by quantization errors. In this case, we adopt a worst-case design approach. For this model, we propose a robust precoder design that minimizes total relay transmit power under constraints on MSEs at the destination nodes. We show that the proposed robust design problems can be reformulated as convex optimization problems that can be solved efficiently using interior-point methods. We demonstrate the robust performance of the proposed design through simulations. © 2011 IEEE.

  15. Using a micromachined magnetostatic relay in commutating a DC motor

    Science.gov (United States)

    Tai, Yu-Chong (Inventor); Wright, John A. (Inventor); Lilienthal, Gerald (Inventor)

    2004-01-01

    A DC motor is commutated by rotating a magnetic rotor to induce a magnetic field in at least one magnetostatic relay in the motor. Each relay is activated in response to the magnetic field to deliver power to at least one corresponding winding connected to the relay. In some cases, each relay delivers power first through a corresponding primary winding and then through a corresponding secondary winding to a common node. Specific examples include a four-pole, three-phase motor in which each relay is activated four times during one rotation of the magnetic rotor.

  16. Fundamental Relations Between Reactive and Proactive Relay-Selection Strategies

    OpenAIRE

    Xia, Minghua; AÏSSA, Sonia

    2015-01-01

    Two major relay-selection strategies widely applied in cooperative decode-and-forward (DF) relaying networks, namely, reactive relay selection (RRS) and proactive relay selection (PRS), are generally looked upon as independent and studied separately. In this paper, RRS and PRS are proven to be equivalent with respect to the end-to-end outage probability from the first principle, i.e. their respective relay-selection criteria. On the other hand, RRS is shown to be superior to PRS with respect ...

  17. Diversity-Multiplexing Tradeoffs in MIMO Relay Channels

    CERN Document Server

    Gunduz, Deniz; Poor, H Vincent

    2008-01-01

    A multi-hop relay channel with multiple antenna terminals in a quasi-static slow fading environment is considered. For both full-duplex and half-duplex relays the fundamental diversity-multiplexing tradeoff (DMT) is analyzed. It is shown that, while decode-and-forward (DF) relaying achieves the optimal DMT in the full-duplex relay scenario, the dynamic decode-and-forward (DDF) protocol is needed to achieve the optimal DMT if the relay is constrained to half-duplex operation. For the latter case, static protocols are considered as well, and the corresponding achievable DMT performance is characterized.

  18. Diversity-Multiplexing Tradeoffs in MIMO Relay Channels

    OpenAIRE

    Gunduz, Deniz; Goldsmith, Andrea; Poor, H. Vincent

    2008-01-01

    A multi-hop relay channel with multiple antenna terminals in a quasi-static slow fading environment is considered. For both full-duplex and half-duplex relays the fundamental diversity-multiplexing tradeoff (DMT) is analyzed. It is shown that, while decode-and-forward (DF) relaying achieves the optimal DMT in the full-duplex relay scenario, the dynamic decode-and-forward (DDF) protocol is needed to achieve the optimal DMT if the relay is constrained to half-duplex operation. For the latter ca...

  19. Lower Bounds on the Capacities of Quantum Relay Channels

    Institute of Scientific and Technical Information of China (English)

    石金晶; 施荣华; 彭小奇; 郭迎; 易留洋; 李门浩

    2012-01-01

    Three kinds of quantum relay communication models are proposed, i.e., the quantum single relay model, quantum serial multi-relay model and quantum parallel multi-relay model. The channel capacities of those three kinds of systems are analyzed with the theory of quantum Markov trace-preserving process and the generalized theory of simple multi-hop channel in quantum system. Motivated by the quantum Fano inequality, the lower bounds of that channel capacities are derived. The illustration and simulation present the trends of the lower bounds on the channel capacities of different quantum relay systems based on the depolarizing noisy channel.

  20. Relay Architectures for 3GPP LTE-Advanced

    Directory of Open Access Journals (Sweden)

    Peters StevenW

    2009-01-01

    Full Text Available The Third Generation Partnership Project's Long Term Evolution-Advanced is considering relaying for cost-effective throughput enhancement and coverage extension. While analog repeaters have been used to enhance coverage in commercial cellular networks, the use of more sophisticated fixed relays is relatively new. The main challenge faced by relay deployments in cellular systems is overcoming the extra interference added by the presence of relays. Most prior work on relaying does not consider interference, however. This paper analyzes the performance of several emerging half-duplex relay strategies in interference-limited cellular systems: one-way, two-way, and shared relays. The performance of each strategy as a function of location, sectoring, and frequency reuse are compared with localized base station coordination. One-way relaying is shown to provide modest gains over single-hop cellular networks in some regimes. Shared relaying is shown to approach the gains of local base station coordination at reduced complexity, while two-way relaying further reduces complexity but only works well when the relay is close to the handset. Frequency reuse of one, where each sector uses the same spectrum, is shown to have the highest network throughput. Simulations with realistic channel models provide performance comparisons that reveal the importance of interference mitigation in multihop cellular networks.

  1. Cooperative Jamming for Secure Communications in MIMO Relay Networks

    CERN Document Server

    Huang, Jing

    2011-01-01

    Secure communications can be impeded by eavesdroppers in conventional relay systems. This paper proposes cooperative jamming strategies for two-hop relay networks where the eavesdropper can wiretap the relay channels in both hops. In these approaches, the normally inactive nodes in the relay network can be used as cooperative jamming sources to confuse the eavesdropper. Linear precoding schemes are investigated for two scenarios where single or multiple data streams are transmitted via a decode-and-forward (DF) relay, under the assumption that global channel state information (CSI) is available. For the case of single data stream transmission, we derive closed-form jamming beamformers and the corresponding optimal power allocation. Generalized singular value decomposition (GSVD)-based secure relaying schemes are proposed for the transmission of multiple data streams. The optimal power allocation is found for the GSVD relaying scheme via geometric programming. Based on this result, a GSVD-based cooperative jam...

  2. Opportunistic Fixed Gain Bidirectional Relaying with Outdated CSI

    KAUST Repository

    Khan, Fahd Ahmed

    2015-05-01

    In a network with multiple relays, relay selection has been shown as an effective scheme to achieve diversity as well as to improve the overall throughput. This paper studies the impact of using outdated channel state information for relay selection on the performance of a network where two sources communicate with each other via fixed-gain amplify-and-forward relays. For a Rayleigh faded channel, closed-form expressions for the outage probability, moment generating function and symbol error rate are derived. Simulations results are also presented to corroborate the derived analytical results. It is shown that adding relays does not improve the performance if the channel is substantially outdated. Furthermore, relay location is also taken into consideration and it is shown that the performance can be improved by placing the relay closer to the source whose channel is more outdated. © 2015 IEEE.

  3. Joint Uplink and Downlink Relay Selection in Cooperative Cellular Networks

    CERN Document Server

    Yang, Wei; Wu, Gang; Wang, Haifeng; Wang, Ying

    2010-01-01

    We consider relay selection technique in a cooperative cellular network where user terminals act as mobile relays to help the communications between base station (BS) and mobile station (MS). A novel relay selection scheme, called Joint Uplink and Downlink Relay Selection (JUDRS), is proposed in this paper. Specifically, we generalize JUDRS in two key aspects: (i) relay is selected jointly for uplink and downlink, so that the relay selection overhead can be reduced, and (ii) we consider to minimize the weighted total energy consumption of MS, relay and BS by taking into account channel quality and traffic load condition of uplink and downlink. Information theoretic analysis of the diversity-multiplexing tradeoff demonstrates that the proposed scheme achieves full spatial diversity in the quantity of cooperating terminals in this network. And numerical results are provided to further confirm a significant energy efficiency gain of the proposed algorithm comparing to the previous best worse channel selection an...

  4. Pragmatic Analysis of Internet Relay Chat

    Institute of Scientific and Technical Information of China (English)

    张永芳

    2005-01-01

    This article presents a pragmatic analysis of Internet Relay chat. Text-only chat room conversation has been claimed to be interactionally incoherent due to limitations imposed by messaging systems on turn taking. The article tries to schematize the conversational relationships of the speakers in a text-based medium and apply a pragmatic point of view based on the model of turn allocation and the Cooperative Prjnciple. An extract of flowing logs in an on-line chat room is analyzed thoroughly in an attempt to explore the way in which Internet interactants behave in a virtual space. The paper shows that some pragmatic rules people follow in everyday oral conversation are followed in Internet relay chat too.

  5. Developing a Domain Model for Relay Circuits

    DEFF Research Database (Denmark)

    Haxthausen, Anne Elisabeth

    2009-01-01

    In this paper we stepwise develop a domain model for relay circuits as used in railway control systems. First we provide an abstract, property-oriented model of networks consisting of components that can be glued together with connectors. This model is strongly inspired by a network model for...... railways madeby Bjørner et.al., however our model is more general: the components can be of any kind and can later be refined to e.g. railway components or circuit components. Then we show how the abstract network model can be refined into an explicit model for relay circuits. The circuit model describes...... defined, checked to be legal, and the reaction to an input can be simulated....

  6. Hybrid Transmission Scheme for MIMO Relay Channels

    Directory of Open Access Journals (Sweden)

    Guangming Xu

    2009-11-01

    Full Text Available To improve the achievable rate for the MIMO channels, we propose a hybrid transmission (HT scheme that mixes half-duplex decode-and-forward cooperative relaying transmission (DFRH)with direct transmission (DT. In the HT scheme, the source message is divided into two parts: one is transmitted by DFRH scheme and another is transmitted by DT scheme. Precoding and decoding are considered to convert the original MIMO relay channel into several parallel subchannels so that resource allocation can be easily performed. We focus on the spatial subchannel and power allocation problem. The objective of this problem is to maximize the total achievable rate under the constraints of joint total transmission power. Simulation results show that significant capacity gain can be achieved by the HT scheme compared to the DT scheme and the pure DFRH scheme.

  7. Kahl relay common-mode failure

    Energy Technology Data Exchange (ETDEWEB)

    Hagen, E.W.

    1979-09-01

    The failure of the Kahl relays is the only generally acknowledged common-mode failure (CMF) to have occurred in any commercially operated light-water reactor that disabled or compromised the automatic reactor protection system. The incident occurred on July 29, 1965, at the Kahl (VAK) reactor, a 15-MW(e) boiling-water reactor located and operated at Kahl-am-Main in the Federal Republic of Germany.

  8. Advanced relay selection schemes for cooperative communications

    OpenAIRE

    Seyfi, Mehdi

    2013-01-01

    It is widely considered that cooperative diversity, in idealized conditions, can provide dramatic performance improvements in capacity and error probability. But non-ideal phenomena, such as fast time variations of the channel, channel estimation errors (CEE), feedback delay (FD) and co-channel interference, degrade the performance of the cooperative communication networks. This thesis studies the impact of these phenomena on advanced relay selection techniques in cooperative communication ne...

  9. Semantic Web Interaction on Internet Relay Chat

    OpenAIRE

    Golbeck, Jennifer; Mutton, Paul

    2004-01-01

    Internet Relay Chat (IRC) is a chat system that has millions of users. IRC robots (bots) are programs that sit in chat rooms and provide different services to users. The IRC bot as a mechanism for human interaction with the Semantic Web specifically with web services and knowledge bases is simple to program, has an intuitive, conversational interface for human users, and fits well with the inputs and outputs of Semantic Web queries. This paper presents implementations of bots for interacting ...

  10. On the Performance of Selection Relaying

    OpenAIRE

    Adinoyi, Abdulkareem; Fan, Yijia; Yanikomeroglu, Halim; Poor, H. Vincent

    2008-01-01

    Interest in selection relaying is growing. The recent developments in this area have largely focused on information theoretic analyses such as outage performance. Some of these analyses are accurate only at high SNR regimes. In this paper error rate analyses that are sufficiently accurate over a wide range of SNR regimes are provided. The motivations for this work are that practical systems operate at far lower SNR values than those supported by the high SNR analysis. To enable designers to m...

  11. Relaying Technologies for Smart Grid Communications

    OpenAIRE

    Sun, Hongjian; Tan, Bo; Jiang, Jing; Thompson, John S.; Nallanathan, Arumugam; Poor, H. Vincent

    2013-01-01

    Wireless technologies can support a broad range of smart grid applications including advanced metering infrastructure (AMI) and demand response (DR). However, there are many formidable challenges when wireless technologies are applied to the smart gird, e.g., the tradeoffs between wireless coverage and capacity, the high reliability requirement for communication, and limited spectral resources. Relaying has emerged as one of the most promising candidate solutions for addressing these issues. ...

  12. Reliable Remote Relay Protection in Smart Grid

    Institute of Scientific and Technical Information of China (English)

    Jiapeng Zhang; Yingfei Dong

    2015-01-01

    As the false trips of remote protection relays are among the main reasons behind cascading blackouts, it is critical to design reli⁃able relay protection. Even though common protection schemes on traditional power systems have been investigated for a few de⁃cades, cascading failures in recent years indicate more research needed in this area. Consequently, researchers have proposed agent⁃based methods on the Smart Grid (SG) to address this issue. However, these existing agent⁃based methods simply use TCP protocol without considering real⁃time communication requirements (such as bandwidth and delay). To deal with this issue, several methods for efficient network resource management are proposed. Furthermore, these existing methods do not consider the poten⁃tial issues in practical communication networks, which may result in delay violation and trigger relay false trips. We have dis⁃cussed simple backup solutions in the previous work. In this paper, in addition to network efficiency, we focus on improving the system reliability by exploring known power system information and minimizing the chances of false trips of important remote re⁃lays, e.g., defining power line priorities based on their importance. Moreover, to further improve the system reliability, we also in⁃vestigate the peer⁃to⁃peer protection approaches to address the single point of failure of centralized control center.

  13. Relaying Strategies and Protocols for Efficient Wireless Networks

    KAUST Repository

    Zafar, Ammar

    2014-10-01

    Next generation wireless networks are expected to provide high data rate and satisfy the Quality-of-Service (QoS) constraints of the users. A significant component of achieving these goals is to increase the effi ciency of wireless networks by either optimizing current architectures or exploring new technologies which achieve that. The latter includes revisiting technologies which were previously proposed, but due to a multitude of reasons were ignored at that time. One such technology is relaying which was initially proposed in the latter half of the 1960s and then was revived in the early 2000s. In this dissertation, we study relaying in conjunction with resource allocation to increase the effi ciency of wireless networks. In this regard, we differentiate between conventional relaying and relaying with buffers. Conventional relaying is traditional relaying where the relay forwards the signal it received immediately. On the other hand, in relaying with buffers or buffer-aided relaying as it is called, the relay can store received data in its buffer and forward it later on. This gives the benefit of taking advantage of good channel conditions as the relay can only transmit when the channel conditions are good. The dissertation starts with conventional relaying and considers the problem of minimizing the total consumed power while maintaining system QoS. After upper bounding the system performance, more practical algorithms which require reduced feedback overhead are explored. Buffer-aided relaying is then considered and the joint user-and-hop scheduler is introduced which exploits multi-user diversity (MUD) and 5 multi-hop diversity (MHD) gains together in dual-hop broadcast channels. Next joint user-and-hop scheduling is extended to the shared relay channel where two source-destination pairs share a single relay. The benefits of buffer-aided relaying in the bidirectional relay channel utilizing network coding are then explored. Finally, a new transmission protocol

  14. Synthesis and Binding Properties of Two New Artificial Anion Receptors

    Institute of Scientific and Technical Information of China (English)

    ZENG Zhen-Ya; HUANG Yan-Yan; HU Ling; WANG Fa-Jun; HE Yong-Bing

    2003-01-01

    @@ The development of anion receptor has attracted increasing interest in supramolecular chemistry, due to poten tial applications in clinical diagnosis, environmental monitoring and biological process. [1] In comparison with thelarge variety of ligands that have been described for cations, [2] the development of selective artificial receptors foranion is still very limited. [3] Two new neutral anion receptors (1 and 2) containing thiourea and amide groups weresynthesized as shown in Scheme 1.

  15. Balanced energy-efficient relay selection scheme in wireless mobile relay networks

    Institute of Scientific and Technical Information of China (English)

    Liu Wei; Ji Hong; Li Xi

    2010-01-01

    In order to resolve the relay selection problem in wireless mobile relay networks (WMRNs), a novel balanced energy-efficient mobile relay selection scheme is proposed in this paper.Compared with traditional counter-based algorithm, distance and energy consumption are considered from network respect to provide a better network lifetime performance in the proposed scheme.Also, it performs well when nodes move freely at high speed.A random assessment delay (RAD) mechanism is added to avoid collisions and improve transmission efficiency.Simulation results reveal that, the proposed scheme has advantages in prolonging network lifetime, balancing energy consumption and reducing the total energy consumption compared with existing counter-based scheme.

  16. RELAY ASSISTED TRANSMISSSION WITH BIT-INTERLEAVED CODED MODULATION

    Institute of Scientific and Technical Information of China (English)

    Meng Qingmin; You Xiaohu; John Boyer

    2006-01-01

    We investigate an adaptive cooperative protocol in a Two-Hop-Relay (THR) wireless system that combines the following: (1) adaptive relaying based on repetition coding; (2) single or two transmit antennas and one receive antenna configurations for all nodes, each using high order constellation; (3) Bit-Interleaved Coded Modulation (BICM). We focus on a simple decoded relaying (i.e. no error correcting at a relay node)and simple signal quality thresholds for relaying. Then the impact of the two simple thresholds on the system performance is studied. Our results suggest that compared with the traditional scheme for direct transmission,the proposed scheme can increase average throughput in high spectral efficiency region with low implementation-cost at the relay.

  17. Modern distance relays for protection of electric transmission lines

    Energy Technology Data Exchange (ETDEWEB)

    Shneerson, E.M.; Fedorov, E.K.; Virt, A.N.

    1985-08-01

    The already commercially produced protective distance relaying equipment of the latest design includes PDE 2001 panel replacing the DZ-503 panel for 500-750 kV transmission lines, ShDE 2801/2 cabinets replacing EPZ-1636 and PZ-201 panels, module BRE 2801 of impedance relays replacing KRS-2/3 sets, and module BRE 2701 of distance relays replacing the PZ-3 set for protection against any kind of short-circuit along 10-35 kV transmission lines, also a set of distance relays in the Sh2102 cabinet for protection of 330 kV autotransformers. Any of these new 3-step distance relays is designed for any kind of interphase short-circuit. The panels and the cabinets are designed to coordinate the operation of all protective relaying devices by proper interconnection and circuit matching, with inclusion of necessary reserve capacity.

  18. Generalized instantly decodable network coding for relay-assisted networks

    KAUST Repository

    Elmahdy, Adel M.

    2013-09-01

    In this paper, we investigate the problem of minimizing the frame completion delay for Instantly Decodable Network Coding (IDNC) in relay-assisted wireless multicast networks. We first propose a packet recovery algorithm in the single relay topology which employs generalized IDNC instead of strict IDNC previously proposed in the literature for the same relay-assisted topology. This use of generalized IDNC is supported by showing that it is a super-set of the strict IDNC scheme, and thus can generate coding combinations that are at least as efficient as strict IDNC in reducing the average completion delay. We then extend our study to the multiple relay topology and propose a joint generalized IDNC and relay selection algorithm. This proposed algorithm benefits from the reception diversity of the multiple relays to further reduce the average completion delay in the network. Simulation results show that our proposed solutions achieve much better performance compared to previous solutions in the literature. © 2013 IEEE.

  19. Energy and Throughput Optimization for Relay Based Heterogeneous Networks

    OpenAIRE

    Ouni, Anis; Saadani, Ahmed; Rivano, Hervé

    2013-01-01

    High data rate is a challenge for the next generation cellular networks. This objective needs a significant densification of relay nodes within macro cell. In the LTE-Advanced network, multi-hop relaying has been taken as a promising key technique to provide high throughput to the users and to improve the area coverage. Besides, minimizing the energy consumption and electromagnetic pollution is an economic challenge for the operators. This paper is focused on relay based heterogeneous cellula...

  20. Spectral efficiency enhancement with interference cancellation for wireless relay network

    DEFF Research Database (Denmark)

    Yomo, Hiroyuki; De Carvalho, Elisabeth

    The introduction of relaying into wireless communication system for coverage enhancement can cause severe decrease of spectral efficiency due to the requirement on extra radio resource. In this paper, we propose a method to increase spectral efficiency in such a wireless relay network by employing...... distance of identical radio resource. We analyze a simple scenario with BS, single RS, and 2 MSs, and show that the proposed method has significant potential to enhance spectral efficiency in wireless relay networks....

  1. Amplify-and-forward relaying in wireless communications

    CERN Document Server

    Rodriguez, Leonardo Jimenez; Le-Ngoc, Tho

    2015-01-01

    This SpringerBrief explores the advantage of relaying techniques in addressing the increasing demand for high data rates and reliable services over the air. It demonstrates how to design cost-effective relay systems that provide high spectral efficiency and fully exploit the diversity of the relay channel. The brief covers advances in achievable rates, power allocation schemes, and error performance for half-duplex (HD) and full-duplex (FD) amplify-and-forward (AF) single-relay systems. The authors discuss the capacity and respective optimal power allocation for a wide range of HD protocols ov

  2. Relay Telecommunications for the Coming Decade of Mars Exploration

    Science.gov (United States)

    Edwards, C.; DePaula, R.

    2010-01-01

    Over the past decade, an evolving network of relay-equipped orbiters has advanced our capabilities for Mars exploration. NASA's Mars Global Surveyor, 2001 Mars Odyssey, and Mars Reconnaissance Orbiter (MRO), as well as ESA's Mars Express Orbiter, have provided telecommunications relay services to the 2003 Mars Exploration Rovers, Spirit and Opportunity, and to the 2007 Phoenix Lander. Based on these successes, a roadmap for continued Mars relay services is in place for the coming decade. MRO and Odyssey will provide key relay support to the 2011 Mars Science Laboratory (MSL) mission, including capture of critical event telemetry during entry, descent, and landing, as well as support for command and telemetry during surface operations, utilizing new capabilities of the Electra relay payload on MRO and the Electra-Lite payload on MSL to allow significant increase in data return relative to earlier missions. Over the remainder of the decade a number of additional orbiter and lander missions are planned, representing new orbital relay service providers and new landed relay users. In this paper we will outline this Mars relay roadmap, quantifying relay performance over time, illustrating planned support scenarios, and identifying key challenges and technology infusion opportunities.

  3. Power supply devices and systems of relay protection

    CERN Document Server

    Gurevich, Vladimir

    2013-01-01

    Power Supply Devices and Systems of Relay Protection brings relay protection and electrical power engineers a single, concentrated source of information on auxiliary power supply systems and devices. The book also tackles specific problems and solutions of relay protection power supply systems and devices, which are often not dealt with in the literature. The author, an experienced engineer with more than 100 patents, draws on his own experience to offer practical, tested advice to readers. A Guide to Relay Protection Power Supply for Engineers and Technicians The first chapter reviews the ele

  4. Cooperative relay-based multicasting for energy and delay minimization

    KAUST Repository

    Atat, Rachad

    2012-08-01

    Relay-based multicasting for the purpose of cooperative content distribution is studied. Optimized relay selection is performed with the objective of minimizing the energy consumption or the content distribution delay within a cluster of cooperating mobiles. Two schemes are investigated. The first consists of the BS sending the data only to the relay, and the second scheme considers the scenario of threshold-based multicasting by the BS, where a relay is selected to transmit the data to the mobiles that were not able to receive the multicast data. Both schemes show significant superiority compared to the non-cooperative scenarios, in terms of energy consumption and delay reduction. © 2012 IEEE.

  5. Advance of the Ground Relay of the Line Protection

    Science.gov (United States)

    Inukai, Michihiko; Nishida, Tadashi; Noro, Jun; Matsuda, Akihiro

    This paper describes the advance of the ground relay of the line protection. First of all, we examined the ground fault in a resistively grounded power system. The protective relay detects the ground fault by the zero phase current in the system. There are two methods for the current input to the relay. One uses the residual circuit of CT secondary winding, and the other uses the CT tertiary winding. When the ground current is insufficient in the residual circuit, the CT tertiary winding is used. In order to omit the CT tertiary winding and to get more reliability, we reviewed the full-scale of relay and evaluating the error of CT. As result, almost all transmission lines could omit the CT tertiary winding. Next, we examined the ground fault with high fault resistance in a solidly grounded power system. When that fault occurs in the system, the PCM current differential relay acts by fault current. So, this relay possibly mal-operates when the CT secondary circuit is disconnected. Therefore, it uses a special CT to raise the reliability. Nowadays GIS has become small and the CT installation space has been decreased, it is needed to reduce these CT cores. In order to omit the special CT, we utilized the combination of the power relay and the rate of change of relay current. As a result, there is a prospect that the relay would not need the special CT. These improvements are effective to reduce cost too.

  6. On the Non-Coherent Wideband Multipath Fading Relay Channel

    OpenAIRE

    Fawaz, Nadia; Medard, Muriel

    2010-01-01

    We investigate the multipath fading relay channel in the limit of a large bandwidth, and in the non-coherent setting, where the channel state is unknown to all terminals, including the relay and the destination. We propose a hypergraph model of the wideband multipath fading relay channel, and show that its min-cut is achieved by a non-coherent peaky frequency binning scheme. The so-obtained lower bound on the capacity of the wideband multipath fading relay channel turns out to coincide with t...

  7. Buffer-Aided Relaying with Adaptive Link Selection

    CERN Document Server

    Zlatanov, Nikola; Popovski, Petar

    2012-01-01

    In this paper, we consider a simple network consisting of a source, a half-duplex decode-and-forward relay, and a destination. We propose a new relaying protocol employing adaptive link selection, i.e., in any given time slot, based on the channel state information of the source-relay and the relay-destination link a decision is made whether the source or the relay transmits. In order to avoid data loss at the relay, adaptive link selection requires the relay to be equipped with a buffer such that data can be queued until the relay-destination link is selected for transmission. We study both delay constrained and delay unconstrained transmission. For the delay unconstrained case, we characterize the optimal link selection policy, derive the corresponding throughput, and develop an optimal power allocation scheme. For the delay constrained case, we propose to starve the buffer of the relay by choosing the decision threshold of the link selection policy smaller than the optimal one and derive a corresponding up...

  8. Performance analysis of two-way amplify and forward relaying with adaptive modulation over multiple relay network

    KAUST Repository

    Hwang, Kyusung

    2011-02-01

    In this letter, we propose two-way amplify-and-forward relaying in conjunction with adaptive modulation in order to improve spectral efficiency of relayed communication systems while monitoring the required error performance. We also consider a multiple relay network where only the best relay node is utilized so that the diversity order increases while maintaining a low complexity of implementation as the number of relays increases. Based on the best relay selection criterion, we offer an upper bound on the signal-to-noise ratio to keep the performance analysis tractable. Our numerical examples show that the proposed system offers a considerable gain in spectral efficiency while satisfying the error rate requirements. © 2011 IEEE.

  9. Anion-π catalysis.

    Science.gov (United States)

    Zhao, Yingjie; Beuchat, César; Domoto, Yuya; Gajewy, Jadwiga; Wilson, Adam; Mareda, Jiri; Sakai, Naomi; Matile, Stefan

    2014-02-01

    The introduction of new noncovalent interactions to build functional systems is of fundamental importance. We here report experimental and theoretical evidence that anion-π interactions can contribute to catalysis. The Kemp elimination is used as a classical tool to discover conceptually innovative catalysts for reactions with anionic transition states. For anion-π catalysis, a carboxylate base and a solubilizer are covalently attached to the π-acidic surface of naphthalenediimides. On these π-acidic surfaces, transition-state stabilizations up to ΔΔGTS = 31.8 ± 0.4 kJ mol(-1) are found. This value corresponds to a transition-state recognition of KTS = 2.7 ± 0.5 μM and a catalytic proficiency of 3.8 × 10(5) M(-1). Significantly increasing transition-state stabilization with increasing π-acidity of the catalyst, observed for two separate series, demonstrates the existence of "anion-π catalysis." In sharp contrast, increasing π-acidity of the best naphthalenediimide catalysts does not influence the more than 12 000-times weaker substrate recognition (KM = 34.5 ± 1.6 μM). Together with the disappearance of Michaelis-Menten kinetics on the expanded π-surfaces of perylenediimides, this finding supports that contributions from π-π interactions are not very important for anion-π catalysis. The linker between the π-acidic surface and the carboxylate base strongly influences activity. Insufficient length and flexibility cause incompatibility with saturation kinetics. Moreover, preorganizing linkers do not improve catalysis much, suggesting that the ideal positioning of the carboxylate base on the π-acidic surface is achieved by intramolecular anion-π interactions rather than by an optimized structure of the linker. Computational simulations are in excellent agreement with experimental results. They confirm, inter alia, that the stabilization of the anionic transition states (but not the neutral ground states) increases with the π-acidity of the

  10. 78 FR 40581 - Structure and Practices of the Video Relay Service Program; Telecommunications Relay Services and...

    Science.gov (United States)

    2013-07-05

    ... subscribers, interconnected VoIP, and others. 40. To help combat such fraud, the Commission (i) directs the... definition, any software, hardware, or other technology issued, leased, or otherwise provided to VRS or IP... technology as ``VRS access technology'' and ``IP Relay access technology'' where appropriate, but decline...

  11. Vanadogermanate cluster anions.

    Science.gov (United States)

    Whitfield, T; Wang, X; Jacobson, A J

    2003-06-16

    Three novel vanadogermanate cluster anions have been synthesized by hydrothermal reactions. The cluster anions are derived from the (V(18)O(42)) Keggin cluster shell by substitution of V=O(2+) "caps" by Ge(2)O(OH)(2)(4+) species. In Cs(8)[Ge(4)V(16)O(42)(OH)(4)].4.7H(2)O, 1, (monoclinic, space group C2/c (No. 15), Z = 8, a = 44.513(2) A, b = 12.7632(7) A, c = 22.923(1) A, beta = 101.376(1) degrees ) and (pipH(2))(4)(pipH)(4)[Ge(8)V(14)O(50).(H(2)O)] (pip = C(4)N(2)H(10)), 2 (tetragonal, space group P4(2)/nnm (No. 134), Z = 2, a = 14.9950(7) A, c = 18.408(1) A), two and four VO(2+) caps are replaced, respectively, and each cluster anion encapsulates a water molecule. In K(5)H(8)Ge(8)V(12)SO(52).10H(2)O, 3, (tetragonal, space group I4/m (No. 87), Z = 2, a = 15.573(1) A, c = 10.963(1) A), four VO(2+) caps are replaced by Ge(2)O(OH)(2)(4+) species, and an additional two are omitted. The cluster ion in 3 contains a sulfate anion disordered over two positions. The cluster anions are analogous to the vanadoarsenate anions [V(18)(-)(n)()As(2)(n)()O(42)(X)](m)(-) (X = SO(3), SO(4), Cl; n = 3, 4) previously reported. PMID:12793808

  12. An economically viable space power relay system

    Science.gov (United States)

    Bekey, Ivan; Boudreault, Richard

    1999-09-01

    This paper describes and analyzes the economics of a power relay system that takes advantage of recent technological advances to implement a system that is economically viable. A series of power relay systems are described and analyzed which transport power ranging from 1,250 megawatts to 5,000 megawatts, and distribute it to receiving sites at transcontinental distances. Two classes of systems are discussed—those with a single reflector and delivering all the power to a single rectenna, and a second type which has multiple reflectors and distributes it to 10 rectenna sites, sharing power among them. It is shown that when offering electricity at prices competitive to those prevalent in developed cities in the US that a low IRR is inevitable, and economic feasibility of a business is unlikely. However, when the target market is Japan where the prevalent electricity prices are much greater, that an IRR exceeding 65% is readily attainable. This is extremely attractive to potential investors, making capitalization of a venture likely. The paper shows that the capital investment required for the system can be less than 1 per installed watt, contributing less than 0.02 /KW-hr to the cost of energy provision. Since selling prices in feasible regions range from 0.18 to over 030 $/kW-hr, these costs are but a small fraction of the operating expenses. Thus a very large IRR is possible for such a business.

  13. Aging assessment of circuit breakers and relays

    International Nuclear Information System (INIS)

    The aging of circuit breakers and relays is important since these devices provide critical services for safety related systems in nuclear plants. Failures of these devices can cause loss of vital functions as well as creating fire hazards. The aging assessments discussed in this paper were sponsored by the U.S. Nuclear Regulatory Commission's Nuclear Plant Aging Research (NPAR) Program. The research has concentrated on identifying inspection, surveillance and condition monitoring (ISCM) techniques which are useful for detecting age degradation in these devices. Significant elements of the research consisted of the following, laboratory tests, in-situ efforts and degraded parts in a laboratory environment. This includes five types of relays and three types of circuit breakers. Nineteen different ISCM techniques were evaluated. New and aged devices were used to determine the effectiveness of each technique to detect the effects of aging. Aging effects were noted to be significant if they caused failure of the equipment or resulted in some other significant event, such as a fire hazard. The following techniques detected significant aging: visual inspection, infrared thermal measurements, vibration monitoring, pick up voltage, drop out voltage, pole and contact resistance and smoke detection. After the laboratory tests, the techniques which were effective, as well as some which still showed promise, were further evaluated in Duke Power Company's Catawba Nuclear Plant

  14. CERN Relay Race: sporty and colourful

    CERN Multimedia

    Andy Butterworth, CERN Running Club

    2013-01-01

    On Thursday 23 May, the 43rd CERN Relay Race took place, with 108 teams on the starting line, the largest participation ever!       The DG was present at the start and said a few words to encourage the runners. At 12:15, the Solar Club and handbike racers, led by Jean-Yves Le Meur, were the first to set off. And as last year, the relay runners were accompanied by an enthusiastic group of Nordic walkers. The first team across the finish line was "Velo City", in a very fast time of 10'31". New this year was a prize category for the best fancy dress, which was won by Les Schtroumpfs from the BE Department. The challenge for the best represented department was won for the third year in a row by FP, but second and third were HR and IT, up from 6th and 9th places last year. To see all the pictures of the event, click here.

  15. Record Participation in the Relay Race!

    CERN Multimedia

    2002-01-01

    CERN has a more sporting spirit than ever before. This is not the result of any survey, but the impression you got as soon as you saw the 62 teams of six runners each speeding around the laboratory in the 32nd annual relay race. This year 11 more teams competed than in 2001.   First changeover: Hervé Cornet takes over from Camille Ruiz Llamas for The Shabbys, and Sebastian Dorthe from Daniel Matteazzi for Charmilles Technologies. Jérôme Bendotti (EP/TA1) just holding off the team from the WHO at the finish. A total of 372 people ran together last Wednesday in this year's relay race, making for a record participation. It also seems that women are becoming more and more attracted by this competition, since this year there were eight ladies teams, also a new record. The first team were The Shabbys in a time of 10 minutes 45 seconds, finishing almost before the second team had started its last 300 metre leg. The 6 runners in each team cover distances of 1000, 800, 800,...

  16. Understanding the Design, Function and Testing of Relays

    Science.gov (United States)

    Adams, Roger E.; Lindbloom, Trent

    2006-01-01

    The increased use of electronics in today's automobiles has complicated the control of circuits and actuators. Manufacturers use relays to control a variety of complex circuits--for example, those involving actuators and other components like the A/C clutch, electronic cooling fans, and blower motors. Relays allow a switch or processor to control…

  17. Protective relaying of power systems using mathematical morphology

    CERN Document Server

    Wu, QH; Ji, TY

    2009-01-01

    Discusses the development of novel protective relaying algorithms, using Mathematical Morphology (MM). This book introduces the fundamental principles of MM, and brings together the applications of MM to develop different protective relaying algorithms for the protection of a variety of power system components.

  18. 76 FR 65965 - Contributions to the Telecommunications Relay Services Fund

    Science.gov (United States)

    2011-10-25

    ...) Requires Internet protocol compatible customer premises equipment; and (ii) Does not include any service... the Telecommunications Relay Services Fund, Notice of Proposed Rulemaking, published at 76 FR 18490... Practices of the Video Relay Service Program, Order, published at 76 FR 44326, July 25, 2011....

  19. MaROS Strategic Relay Planning and Coordination Interfaces

    Science.gov (United States)

    Allard, Daniel A.

    2010-01-01

    The Mars Relay Operations Service (MaROS) is designed to provide planning and analysis tools in support of ongoing Mars Network relay operations. Strategic relay planning requires coordination between lander and orbiter mission ground data system (GDS) teams to schedule and execute relay communications passes. MaROS centralizes this process, correlating all data relevant to relay coordination to provide a cohesive picture of the relay state. Service users interact with the system through thin-layer command line and web user interface client applications. Users provide and utilize data such as lander view periods of orbiters, Deep Space Network (DSN) antenna tracks, and reports of relay pass performance. Users upload and download relevant relay data via formally defined and documented file structures including some described in Extensible Markup Language (XML). Clients interface with the system via an http-based Representational State Transfer (ReST) pattern using Javascript Object Notation (JSON) formats. This paper will provide a general overview of the service architecture and detail the software interfaces and considerations for interface design.

  20. Cognitive Spectrum Efficient Multiple Access Technique using Relay Systems

    DEFF Research Database (Denmark)

    Frederiksen, Flemming Bjerge; Prasad, Ramjee

    2007-01-01

    Methods to enhance the use of the frequency spectrum by automatical spectrum sensing plus spectrum sharing in a cognitive radio technology context will be presented and discussed in this paper. Ideas to increase the coverage of cellular systems by relay channels, relay stations and collaborate...... radio will be presented as well....

  1. 75 FR 16913 - Transmission Relay Loadability Reliability Standard

    Science.gov (United States)

    2010-04-02

    ...\\ Transmission Relay Loadability Reliability Standard, Notice of Proposed Rulemaking, 74 FR 35830 (Jul. 21, 2009... with protective relays, voltage and current sensing devices, station batteries, and DC control... in service. 3. Following the August 2003 blackout that affected parts of the Midwest and...

  2. Efficient Resource Scheduling by Exploiting Relay Cache for Cellular Networks

    Directory of Open Access Journals (Sweden)

    Chun He

    2015-01-01

    Full Text Available In relay-enhanced cellular systems, throughput of User Equipment (UE is constrained by the bottleneck of the two-hop link, backhaul link (or the first hop link, and access link (the second hop link. To maximize the throughput, resource allocation should be coordinated between these two hops. A common resource scheduling algorithm, Adaptive Distributed Proportional Fair, only ensures that the throughput of the first hop is greater than or equal to that of the second hop. But it cannot guarantee a good balance of the throughput and fairness between the two hops. In this paper, we propose a Two-Hop Balanced Distributed Scheduling (TBS algorithm by exploiting relay cache for non-real-time data traffic. The evolved Node Basestation (eNB adaptively adjusts the number of Resource Blocks (RBs allocated to the backhaul link and direct links based on the cache information of relays. Each relay allocates RBs for relay UEs based on the size of the relay UE’s Transport Block. We also design a relay UE’s ACK feedback mechanism to update the data at relay cache. Simulation results show that the proposed TBS can effectively improve resource utilization and achieve a good trade-off between system throughput and fairness by balancing the throughput of backhaul and access link.

  3. 47 CFR 11.20 - State Relay Network.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false State Relay Network. 11.20 Section 11.20... Network. This network is composed of State Relay (SR) sources, leased common carrier communications facilities or any other available communication facilities. The network distributes State EAS...

  4. Opportunistic Cognitive Relaying: A Win-Win Spectrum Sharing Scheme

    Directory of Open Access Journals (Sweden)

    Luo Haiyan

    2010-01-01

    Full Text Available A cost-effective spectrum sharing architecture is proposed to enable the legacy noncognitive secondary system to coexist with the primary system. Specifically, we suggest to install a few intermediate nodes, namely, the cognitive relays, to conduct the spectrum sensing and coordinate the spectrum access. To achieve the goal of win-win between primary and secondary systems, the cognitive relay may act as a cooperator for both of them, and an Opportunistic Cognitive Relaying (OCR scheme is specially devised. In this scheme, the cognitive relay opportunistically switches among three different working modes, that is, Relay for Primary Link (RPL, Relay for Secondary Link (RSL, or Relay for Neither of the Links (RNL, respectively, based on the channel-dependent observation of both systems. In addition, the transmit power for cognitive relay and secondary transmitter in each mode are optimally determined by maximizing the transmission rate of secondary system while keeping or even reducing the outage probability of primary system. Simulation results validate the efficiency of the proposed spectrum sharing scheme.

  5. Discussion on dynamic reliability tolerance design technology of electromagnetic relay

    Institute of Scientific and Technical Information of China (English)

    YE Xue-rong; LIANG Hui-min; ZHAI Guo-fu

    2007-01-01

    Reliability tolerance design of electromagnetic relay during its design period plays an essential role in guaranteeing the consistencies of reliability and output characteristic. The reliability tolerance design can ensure that the products would work well under the influence of disturbing factors (including internal interference, external interference, and machining dispersion). Compared with static characteristic, dynamic characteristic of electromagnetic relay can describe its operating process better. This article researches influence of the three kinds of disturbing factors on the dynamic characteristic of electromagnetic relay based on calculating dynamic characteristic. Then, the dynamic reliability tolerance design method of electromagnetic relay is discussed considering three kinds of disturbing factors. Conclusions reached can help to assure the reliability of electromagnetic relay from the beginning of design.

  6. Sum-Rate Maximization of Coordinated Direct and Relay Systems

    DEFF Research Database (Denmark)

    Sun, Fan; Popovski, Petar; Thai, Chan;

    2012-01-01

    , where the constellation of traffic flows is more general than the two-way. Regardless of the actual traffic flows, in a CDR scheme the relay has a central role in managing the interference and boosting the overall system performance. In this paper we investigate the novel transmission modes, based on......Joint processing of multiple communication flows in wireless systems has given rise to a number of novel transmission techniques, notably the two-way relaying based on wireless network coding. Recently, a related set of techniques has emerged, termed coordinated direct and relay (CDR) transmissions...... amplify-and-forward, that arise when the relay is equipped with multiple antennas and can use beamforming. We focus on one representative traffic type, with one uplink and one downlink users and consider the achievable sum-rate maximization relay beamforming. The beamforming criterion leads to a non...

  7. An RSS based location estimation technique for cognitive relay networks

    KAUST Repository

    Qaraqe, Khalid A.

    2010-11-01

    In this paper, a received signal strength (RSS) based location estimation method is proposed for a cooperative wireless relay network where the relay is a cognitive radio. We propose a method for the considered cognitive relay network to determine the location of the source using the direct and the relayed signal at the destination. We derive the Cramer-Rao lower bound (CRLB) expressions separately for x and y coordinates of the location estimate. We analyze the effects of cognitive behaviour of the relay on the performance of the proposed method. We also discuss and quantify the reliability of the location estimate using the proposed technique if the source is not stationary. The overall performance of the proposed method is presented through simulations. ©2010 IEEE.

  8. Multiple relay selection for delay-limited applications

    KAUST Repository

    Alsharoa, Ahmad M.

    2013-12-01

    A multiple relay selection system model that implements the decode-and-forward mode is investigated. All communication nodes are assumed to be equipped by multiple antennas. Furthermore, lattices space-time coded multiple-input multiple-output half duplex channel is applied. The main goal is to increase the throughput of the system by selecting multiple number of relays. The selection criteria depends on the maximum decoding delay at relays where the system implements a decoding time-out algorithm at each relay. This leads to a significant saving in the overall system power consumptions and attempts to solve the relays synchronization problem. All results are presented using numerical simulations. © 2012 IEEE.

  9. Continuous-variable quantum cryptography with untrusted relays

    CERN Document Server

    Pirandola, Stefano; Spedalieri, Gaetana; Weedbrook, Christian; Braunstein, Samuel L

    2013-01-01

    We extend the field of continuous-variable quantum cryptography to a more robust formulation which can be applied to untrusted networks. We consider two remote parties connected to an untrusted relay by insecure quantum links. To generate correlations, they transmit coherent states to the relay where a continuous-variable Bell detection is performed. Despite the possibility that the working mechanism of the relay could be fully corrupted and the links subject to optimal coherent attacks, the parties are still able to extract a secret key. Furthermore, our analysis shows that very long distances and high rates can be reached when the relay is proximal to one of the parties, configuration typical of a mobile device connecting to a public access point. Thus, using the cheapest possible quantum resources, we show the possibility of long-distance high-rate quantum key distribution in network topologies where direct links are missing between two end-users and intermediate relays cannot be trusted.

  10. Relay Placement for Physical Layer Security: A Secure Connection Perspective

    CERN Document Server

    Mo, Jianhua; Liu, Yuan

    2012-01-01

    This work studies the problem of secure connection in cooperative wireless communication with two relay strategies, decode-and-forward (DF) and randomize-and-forward (RF). The four-node scenario and cellular scenario are considered. For the typical four-node (source, destination, relay, and eavesdropper) scenario, we derive the optimal power allocation for the DF strategy and find that the RF strategy is always better than the DF to enhance secure connection. In cellular networks, we show that without relay, it is difficult to establish secure connections from the base station to the cell edge users. The effect of relay placement for the cell edge users is demonstrated by simulation. For both scenarios, we find that the benefit of relay transmission increases when path loss becomes severer.

  11. Anionic polymerization and polyhomologation: An ideal combination to synthesize polyethylene-based block copolymers

    KAUST Repository

    Zhang, H.

    2013-08-07

    A novel one-pot methodology combining anionic polymerization and polyhomologation, through a "bridge" molecule (BF3OEt 2), was developed for the synthesis of polyethylene (PE)-based block copolymers. The anionically synthesized macroanion reacts with the "bridge" molecule to afford a 3-arm star (trimacromolecular borane) which serves as an initiator for the polyhomologation. 2013 The Royal Society of Chemistry.

  12. Anion Ordering in Bichalcogenides

    Directory of Open Access Journals (Sweden)

    Martin Valldor

    2016-07-01

    Full Text Available This review contains recent developments and new insights in the research on inorganic, crystalline compounds with two different chalcogenide ions (bichalcogenides. Anion ordering is used as a parameter to form structural dimensionalities as well as local- and global-electric polarities. The reason for the electric polarity is that, in the heterogeneous bichalcogenide lattice, the individual bond-lengths between cations and anions are different from those in a homogeneous anion lattice. It is also shown that heteroleptic tetrahedral and octahedral coordinations offer a multitude of new crystal fields and coordinations for involved cations. This coordination diversity in bichalcogenides seems to be one way to surpass electro-chemical redox potentials: three oxidation states of a single transition metal can be stabilized, e.g., Ba15V12S34O3. A new type of disproportionation, related to coordination, is presented and results from chemical pressure on the bichalcogenide lattices of (La,CeCrS2O, transforming doubly [CrS3/3S2/2O1/1]3− (5+1 into singly [CrS4/2S2/3]7/3− (6+0 and [CrS4/3O2/1]11/3− (4+2 coordinations. Also, magnetic anisotropy is imposed by the anion ordering in BaCoSO, where magnetic interactions via S or O occur along two different crystallographic directions. Further, the potential of the anion lattice is discussed as a parameter for future materials design.

  13. Anionic surfactant electrical and surface properties of polypyrrole containing

    Czech Academy of Sciences Publication Activity Database

    Omastová, M.; Chehimi, M. M.; Trchová, Miroslava; Stejskal, Jaroslav

    Dublin: Trinity College Dublin, 2006. 110-TH. [International Conference on Science and Technology of Synthetic Metals. 02.07.2006-07.07.2006, Dublin] Grant ostatní: Slovak Ministry of Education (SK) VEGA-2/4024/04 Institutional research plan: CEZ:AV0Z40500505 Keywords : polypyrrole * anionic polymerization Subject RIV: CD - Macromolecular Chemistry

  14. Anion-free bambus[6]uril and its supramolecular properties

    Czech Academy of Sciences Publication Activity Database

    Švec, J.; Dušek, Michal; Fejfarová, Karla; Štacko, P.; Klán, P.; Kaifer, A.E.; Li, W.; Hudečková, E.; Šindelář, V.

    2011-01-01

    Roč. 17, č. 20 (2011), s. 5605-5612. ISSN 0947-6539 Grant ostatní: AVČR(CZ) Praemium Academiae Institutional research plan: CEZ:AV0Z10100521 Keywords : anion receptors * halides * host-guest systems * macrocycles * supramolecular chemistry Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 5.925, year: 2011

  15. Anion complexation by calix[4]arene–TTF conjugates

    Czech Academy of Sciences Publication Activity Database

    Flídrová, K.; Tkadlecová, M.; Lang, Kamil; Lhoták, P.

    2012-01-01

    Roč. 92, č. 1 (2012), s. 668-673. ISSN 0143-7208 R&D Projects: GA ČR GA203/09/0691 Institutional research plan: CEZ:AV0Z40320502 Keywords : calix[4]arene * tetrathiafulvalene * anion recognition * receptor * NMR titration * UV/vis spectroscopy Subject RIV: CA - Inorganic Chemistry Impact factor: 3.532, year: 2012

  16. Metal ion separations using hydrophobic anions: Aspects of ligand design

    International Nuclear Information System (INIS)

    Metal ion extraction using hydrophobic anions has been investigated by several researchers for remediation of Cs-137 and Sr-90 in nuclear waste. The rich derivative chemistry of the cobalt bis-dicarbollide anion makes it amendable to systematic studies of the relative importance of anion structure, solvent, and synergists on the extraction selectivity and efficiency. Halogenation or alkylation of cobalt dicarbollide strongly influences the anion's solubility and stability but has little effect on extraction properties. Alkali metal selectivity depends primarily on solvent, while alkaline earth selectivity is driven by the concentration and molecular weight of polyethylene glycol synergists. Additional aspects of ligand design, including a simple extraction and recovery cycle based on redox-active metal centers, will be discussed

  17. CERN Relay Race | 5 June | Get ready!

    CERN Multimedia

    CERN Medical Service

    2014-01-01

    In anticipation of the CERN relay race, the Medical Service would like to remind all participants that preparing for this sporting activity is essential - even though it is a short event.   Progressive and regular training. Adequate nutrition and hydration. Advice and information is available at the infirmary in Building 57. Everyone should adapt their physical activity to match their fitness levels, bearing in mind that the aim of this race is not necessarily to achieve great success but to participate in a collective sporting event. In the framework of the "Move! Eat better" campaign and for the third successive year, a 2.4 km route is open to walkers, both beginners and experts. Before, during and after this event, test yourself with a pedometer, available from the CERN infirmary! 

  18. Generalized routing protocols for multihop relay networks

    KAUST Repository

    Khan, Fahd Ahmed

    2011-07-01

    Performance of multihop cooperative networks depends on the routing protocols employed. In this paper we propose the last-n-hop selection protocol, the dual path protocol, the forward-backward last-n-hop selection protocol and the forward-backward dual path protocol for the routing of data through multihop relay networks. The average symbol error probability performance of the schemes is analysed by simulations. It is shown that close to optimal performance can be achieved by using the last-n-hop selection protocol and its forward-backward variant. Furthermore we also compute the complexity of the protocols in terms of number of channel state information required and the number of comparisons required for routing the signal through the network. © 2011 IEEE.

  19. Satellite data-relay activities in Arizona

    Science.gov (United States)

    Boner, F.C.; Blee, J.W.; Shope, W.G.

    1985-01-01

    The U.S. Geological Survey (USGS) Arizona District collects data from automated streamflow stations for a wide variety of uses. Data from these stations are provided to Federal, State, and local agencies that have a responsibility to issue flood warnings; to generate forecasts of water availability; to monitor flow to insure compliance with treaties and other legal mandates; and to manage reservoirs for hydropower, flood abatement, and municipal and irrigation water supply. In the mid-1970's, the escalation of data collection costs and a need for more timely data led the Arizona District to examine alternatives for remote data acquisition. On the basis of successful data communications experiments with NASA 's Landsat satellite, an operational system for satellite-data relay was developed in 1976 using the National Oceanic and Atmospheric Administrations 's (NOAA) Geostationary Operational Environmental Satellite (GOES). A total of 62 data collection platforms (DCP's) was operated in 1983. Satellite telemetry operations are controlled at the remote data-collection stations by small battery-operated data collection platforms. The DCP 's periodically collect data from the sensors, store the data in computer memory, and at preset times transmit the data to the GOES satellite. The satellite retransmits the data to Earth where a ground-receive station transmits or transfers the data by land communications to the USGS computer in Reston, Virginia, for processing. The satellite relay transfers the data from sensor to computer in minutes; therefore, the data are available to users on a near real-time basis. (Author 's abstract)

  20. Optimum Overcurrent Relay Coordination of a Power Grid

    Directory of Open Access Journals (Sweden)

    Sheila Mahapatra

    2014-04-01

    Full Text Available Protective system plays a pivotal role in any power system operation. In a typical power system there are large numbers of circuit breakers and relays installed which constitute an integral part of the protective scheme. Relay is a device that senses and locates the fault and sends a command to the circuit breaker to disconnect the faulty element. Relay coordination is done to provide primary as well as back up protection from any fault that is likely to occur in the system. In this paper, overcurrent relay coordination is implemented on a 72 bus 220 KV substation. Load flow studies and the short circuit analysis on the test system is initially done followed by relay coordination. Fault current data obtained from short circuit studies enables us to obtain operating time of the relays used in the test system. The simulated value of operating time provides the coordinated operation of all the relays connected from 220kV to 33kV line thereby protecting the equipment of the test system. Keywords-

  1. On Diversity-Multiplexing Tradeoff in Multiple-Relay Networks

    CERN Document Server

    Gharan, Shahab Oveis; Khandani, Amir K

    2008-01-01

    This paper studies the setup of a multiple-relay network in which $K$ half-duplex multiple-antenna relays assist in the transmission between a/several multiple-antenna transmitter(s) and a multiple-antenna receiver. Each two nodes are assumed to be either connected through a quasi-static Rayleigh fading channel, or disconnected. We propose a new scheme, which we call random sequential (RS), based on the amplify-and-forward relaying. We prove that for general multiple-antenna multiple-relay networks, the proposed scheme achieves the maximum diversity gain. Furthermore, we derive diversity-multiplexing tradeoff (DMT) of the proposed RS scheme for general single-antenna multiple-relay networks. Finally, we show that for single-antenna multiple-access multiple-relay ($K>1$) networks (without direct link between the transmitter(s) and the receiver), the proposed RS scheme achieves the optimum DMT. However, for the case of multiple access single relay setup, the RS scheme reduces to the naive amplify-and-forward re...

  2. On chaotic oscillations in nuclear reactor with relay control system

    International Nuclear Information System (INIS)

    Steady motions in a nuclear reactor with relay automated system are studied. It is supposed that the reactor is oscilatory instable, and relay characteristics has the zones of hysteresis and insensitivity, if the control system is absent. It is shown that stochastic auto-oscillations may occur in the reactor together with periodic ones in this case, while the frequency of the relay system switching-on is much lower in the regime of stochastic oscillations as compared with that in periodic regimes. Utilization of stochastic motions in control system leads to its fuctioning quality improvement

  3. Turbo-coded CDMA-based two-way relaying

    OpenAIRE

    Ng, Soon Xin; Liao, Sha Sha

    2012-01-01

    In this contribution, we have studied the performance of a Turbo-Coded (TC) Code Division Multiple Access (CDMA) based two-way relaying scheme. More explicitly, we employ a seven-user CDMA model, where two of the CDMA users are communicating with each other with the aid of an additional relay node, while the other ¯ve CDMA users are interferers. More explicitly, two CDMA users exchange their information frames within two timeslots. Note that the conventional one-way relaying system can only t...

  4. Perspective: Electrospray photoelectron spectroscopy: From multiply-charged anions to ultracold anions

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Lai-Sheng, E-mail: Lai-Sheng-Wang@brown.edu [Department of Chemistry, Brown University, Providence, Rhode Island 02912 (United States)

    2015-07-28

    Electrospray ionization (ESI) has become an essential tool in chemical physics and physical chemistry for the production of novel molecular ions from solution samples for a variety of spectroscopic experiments. ESI was used to produce free multiply-charged anions (MCAs) for photoelectron spectroscopy (PES) in the late 1990 s, allowing many interesting properties of this class of exotic species to be investigated. Free MCAs are characterized by strong intramolecular Coulomb repulsions, which create a repulsive Coulomb barrier (RCB) for electron emission. The RCB endows many fascinating properties to MCAs, giving rise to meta-stable anions with negative electron binding energies. Recent development in the PES of MCAs includes photoelectron imaging to examine the influence of the RCB on the electron emission dynamics, pump-probe experiments to examine electron tunneling through the RCB, and isomer-specific experiments by coupling PES with ion mobility for biological MCAs. The development of a cryogenically cooled Paul trap has led to much better resolved PE spectra for MCAs by creating vibrationally cold anions from the room temperature ESI source. Recent advances in coupling the cryogenic Paul trap with PE imaging have allowed high-resolution PE spectra to be obtained for singly charged anions produced by ESI. In particular, the observation of dipole-bound excited states has made it possible to conduct vibrational autodetachment spectroscopy and resonant PES, which yield much richer vibrational spectroscopic information for dipolar free radicals than traditional PES.

  5. Perspective: Electrospray photoelectron spectroscopy: From multiply-charged anions to ultracold anions

    International Nuclear Information System (INIS)

    Electrospray ionization (ESI) has become an essential tool in chemical physics and physical chemistry for the production of novel molecular ions from solution samples for a variety of spectroscopic experiments. ESI was used to produce free multiply-charged anions (MCAs) for photoelectron spectroscopy (PES) in the late 1990 s, allowing many interesting properties of this class of exotic species to be investigated. Free MCAs are characterized by strong intramolecular Coulomb repulsions, which create a repulsive Coulomb barrier (RCB) for electron emission. The RCB endows many fascinating properties to MCAs, giving rise to meta-stable anions with negative electron binding energies. Recent development in the PES of MCAs includes photoelectron imaging to examine the influence of the RCB on the electron emission dynamics, pump-probe experiments to examine electron tunneling through the RCB, and isomer-specific experiments by coupling PES with ion mobility for biological MCAs. The development of a cryogenically cooled Paul trap has led to much better resolved PE spectra for MCAs by creating vibrationally cold anions from the room temperature ESI source. Recent advances in coupling the cryogenic Paul trap with PE imaging have allowed high-resolution PE spectra to be obtained for singly charged anions produced by ESI. In particular, the observation of dipole-bound excited states has made it possible to conduct vibrational autodetachment spectroscopy and resonant PES, which yield much richer vibrational spectroscopic information for dipolar free radicals than traditional PES

  6. A New Proposal of Inverse-Time Characteristics for Overcurrent Relay Based on Microcomputer

    Institute of Scientific and Technical Information of China (English)

    黄彦全; 肖建; 蔡勇; 唐磊

    2004-01-01

    The conventional time function of electromechanical relays is hard to coordinate with other relays. In order to promote the application of inverse-time overcurrent relays, a new time function for microprocessor-type relay is proposed. The setting of the trip time for this relay is performed by determining the shortest trip time and the longest trip time, respectively. The results of analysis show that with the new time function, the inverse-time overcurrent relay is easy to coordinate with other relays and has a comparatively shorter trip time, and that the fault happens in the protective zone.

  7. Overlay cognitive radio systems with adaptive two-way relaying

    KAUST Repository

    Hyadi, Amal

    2013-12-01

    In this paper, we propose a spectrum sharing mechanism with a two-phase two-way relaying protocol for an overlay cognitive network. The system comprises two primary users (PUs) and two secondary users (SUs). One of the SUs acts as a relay for the PUs and gains spectrum sharing as long as he respects outage probability constraints of the primary system. Moreover, we consider that the relaying node performs an optimal power allocation scheme that minimizes the outage performance of the secondary receiver. Closed form expressions for the outage probability are derived for the cases of Decode-and-Forward (DF), Amplify-and-Forward (AF), and adaptive relaying. Numerical simulations are presented to illustrate and compare the obtained results. © 2013 IEEE.

  8. Beamforming Design for Coordinated Direct and Relay Systems

    DEFF Research Database (Denmark)

    Sun, Fan; De Carvalho, Elisabeth; Thai, Chan;

    2012-01-01

    , where the constellation of traffic flows is more general than the two-way. Regardless of the actual traffic flows, in a CDR scheme the relay has a central role in managing the interference. In this paper we investigate the novel transmission modes, based on amplify-and-forward, that arise when the relay......Joint processing of multiple communication flows in wireless systems has given rise to a number of novel transmission techniques, notably the two-way relaying based on wireless network coding. Recently, a related set of techniques has emerged, termed coordinated direct and relay (CDR) transmissions...... is equipped with multiple antennas and can use beamforming. We focus on one representative traffic type, with two downlink users and consider three different beamforming criteria: egoistic, altruistic, and sum-rate maximization. The sum-rate criterion leads to a non-convex problem and we introduce an...

  9. Comprehensive aging assessment of circuit breakers and relays

    International Nuclear Information System (INIS)

    As part of the NRC Nuclear Plant Aging Research (NPAR) Program a comprehensive aging assessment was made of relays and circuit breakers. Relays and circuit breakers are important nuclear power plant equipment which are susceptible to degradation with time. This is a Phase II NPAR report which follows the NPAR strategy. Tests on naturally aged and degraded relays and circuit breakers were performed, in-situ measurements made and current, and improved methods for inspection, surveillance and monitoring (ISM) evaluated. Significant results described in this report were the identification of inspection, surveillance and monitoring methods which provide a higher level of assurance that aging will be detected and mitigated. The potential exists that implementation of the improved methods in nuclear plants would minimize and impact of aging and result in more cost effective maintenance on relays and circuit breakers

  10. London 2012 Olympic Torch Relay: look & feel style guide

    OpenAIRE

    2016-01-01

    The guidelines issued by the London Organising Committee of the Olympic Games and Paralympic Games Ltd (“LOCOG”) provide standards, requirements and guidelines for use of the London 2012 Olympic Torch Relay Emblem (the “Emblem”).

  11. Reliable quantum communication over a quantum relay channel

    International Nuclear Information System (INIS)

    We show that reliable quantum communication over an unreliable quantum relay channels is possible. The coding scheme combines the results on the superadditivity of quantum channels and the efficient quantum coding approaches

  12. Reliable quantum communication over a quantum relay channel

    Energy Technology Data Exchange (ETDEWEB)

    Gyongyosi, Laszlo, E-mail: gyongyosi@hit.bme.hu [Quantum Technologies Laboratory, Department of Telecommunications, Budapest University of Technology and Economics, 2 Magyar tudosok krt, Budapest, H-1117, Hungary and Information Systems Research Group, Mathematics and Natural Sciences, Hungarian Ac (Hungary); Imre, Sandor [Quantum Technologies Laboratory, Department of Telecommunications, Budapest University of Technology and Economics, 2 Magyar tudosok krt, Budapest, H-1117 (Hungary)

    2014-12-04

    We show that reliable quantum communication over an unreliable quantum relay channels is possible. The coding scheme combines the results on the superadditivity of quantum channels and the efficient quantum coding approaches.

  13. Reducibility of joint relay positioning and flow optimization problem

    CERN Document Server

    Thakur, Mohit; Médard, Muriel

    2012-01-01

    This paper shows how to reduce the otherwise hard joint relay positioning and flow optimization problem into a sequence a two simpler decoupled problems. We consider a class of wireless multicast hypergraphs mainly characterized by their hyperarc rate functions, that are increasing and convex in power, and decreasing in distance between the transmit node and the farthest end node of the hyperarc. The set-up consists of a single multicast flow session involving a source, multiple destinations and a relay that can be positioned freely. The first problem formulates the relay positioning problem in a purely geometric sense, and once the optimal relay position is obtained the second problem addresses the flow optimization. Furthermore, we present simple and efficient algorithms to solve these problems.

  14. New results on performance analysis of opportunistic regenerative relaying

    KAUST Repository

    Tourki, Kamel

    2013-12-01

    In this paper, we investigate an opportunistic relaying scheme where the selected relay assists the source-destination (direct) communication. In our study, we consider a regenerative opportunistic relaying scheme in which the direct path may be unusable, and takes into account the effect of the possible erroneously detected and transmitted data at the selected relay. We first derive the signal-to-noise (SNR) statistics for each hop, which are used to determine accurate closed form expressions for end-to-end bit-error rate (BER) of binary phase-shift keying (BPSK) modulation and end-to-end outage probability for a transmission rate R over Rayleigh fading channels. Furthermore, we evaluate the asymptotical performance and deduce the diversity order. Finally, we validate our analysis by showing that performance simulation results coincide with our analytical results over linear network architecture. © 2013 Elsevier B.V.

  15. Error-rate performance analysis of opportunistic regenerative relaying

    KAUST Repository

    Tourki, Kamel

    2011-09-01

    In this paper, we investigate an opportunistic relaying scheme where the selected relay assists the source-destination (direct) communication. In our study, we consider a regenerative opportunistic relaying scheme in which the direct path can be considered unusable, and takes into account the effect of the possible erroneously detected and transmitted data at the best relay. We first derive the exact statistics of each hop, in terms of probability density function (PDF). Then, the PDFs are used to determine accurate closed form expressions for end-to-end bit-error rate (BER) of binary phase-shift keying (BPSK) modulation where the detector may use maximum ration combining (MRC) or selection combining (SC). Finally, we validate our analysis by showing that performance simulation results coincide with our analytical results over linear network (LN) architecture and considering Rayleigh fading channels. © 2011 IEEE.

  16. Joint Relay Selection and Power Allocation for Cooperative Communication over Frequency Selective Fading Channels

    Directory of Open Access Journals (Sweden)

    Youhua Ma

    2012-08-01

    Full Text Available In this paper, we consider the joint problem of relay selection and optimal power allocation for multi-relay amplify-and-forward (AF cooperative communication system over frequency selective fading channels. An optimization model combined relay selection and power allocation under a total transmission power budget is formulated. Then, this combinatorial problem is solved in a distributed strategy. Relay selection with a new threshold-based multiple-relay selection (MRS scheme is implemented at first, and then power is allocated between source and the selected relays in an optimized way to maximize channel capacity. Simulation result shows that the proposed joint scenario with relay selection and power allocation achieves better throughput performance than that of parallel-relay scenario (means that random relay is selected to forward data and allocated part of total power on average. Furthermore, the performances of the new MRS scheme and other relay selection strategies are also investigated.

  17. Diversity Multiplexing Tradeoff of Asynchronous Cooperative Relay Networks

    CERN Document Server

    Krishnakumar, R N; Kumar, P Vijay

    2008-01-01

    The assumption of nodes in a cooperative communication relay network operating in synchronous fashion is often unrealistic. In the present paper, we consider two different models of asynchronous operation in cooperative-diversity networks experiencing slow fading and examine the corresponding diversity-multiplexing tradeoffs (DMT). For both models, we propose protocols and distributed space-time codes that asymptotically achieve the transmit diversity bound for all multiplexing gains and for any number of relays.

  18. A Cooperative Network Coding Strategy for the Interference Relay Channel

    CERN Document Server

    Bui, Huyen-Chi; Lacan, Jerome; Boucheret, Marie-Laure

    2012-01-01

    In this paper, we study an interference relay network with a satellite as relay. We propose a cooperative strategy based on physical layer network coding and superposition modulation decoding for uni-directional communications among users. The performance of our solution in terms of throughput is evaluated through capacity analysis and simulations that include practical constraints such as the lack of synchronization in time and frequency. We demonstrate throughputs significantly larger than the classical time sharing case.

  19. Quantum relays and noise suppression using linear optics

    OpenAIRE

    Jacobs, B.C.; Pittman, T. B.; Franson, J. D.

    2002-01-01

    Probabilistic quantum non-demolition (QND) measurements can be performed using linear optics and post-selection. Here we show how QND devices of this kind can be used in a straightforward way to implement a quantum relay, which is capable of extending the range of a quantum cryptography system by suppressing the effects of detector noise. Unlike a quantum repeater, a quantum relay system does not require entanglement purification or the ability to store photons.

  20. Opportunistic Relaying without CSI: Optimizing Variable-Rate HARQ

    OpenAIRE

    Khosravirad, Saeed R.; Szczecinski, Leszek; Labeau, Fabrice

    2014-01-01

    We analyze the opportunistic relaying based on HARQ transmission over the block-fading channel with absence of channel state information (CSI) at the transmitter nodes. We assume that both the source and the relay are allowed to vary their transmission rate between the HARQ transmission rounds. We solve the problem of throughput maximization with respect to the transmission rates using double-recursive Dynamic Programming. Simplifications are also proposed to diminish the complexity of the op...

  1. Multipair Massive MIMO Relaying with Pilot-Data Transmission Overlay

    OpenAIRE

    Pan, Leyuan; Dai, Yongyu; Xu, Wei; Dong, Xiaodai

    2016-01-01

    We propose a pilot-data transmission overlay scheme for multipair massive multiple-input multiple-output (MIMO) relaying systems employing either half- or full-duplex (HD or FD) communications at the relay station (RS). In the proposed scheme, pilots are transmitted in partial overlap with data to decrease the channel estimation overhead. The RS can detect the source data with minimal destination pilot interference by exploiting the asymptotic orthogonality of massive MIMO channels. Then pilo...

  2. Synthesis of (meth)acrylate block copolymers by ligated anionic polymerization

    Czech Academy of Sciences Publication Activity Database

    Vlček, Petr; Čadová, Eva; Janata, Miroslav; Látalová, Petra; Toman, Luděk; Kříž, Jaroslav; Kurková, Dana

    Goa : International Union of Pure and Applied Chemistry, 2005. s. 20-21. [International Symposium on Ionic Polymerization. 23.10.2005-28.10.2005, Goa ] R&D Projects: GA MŠk 1P05ME753 Institutional research plan: CEZ:AV0Z40500505 Keywords : block copolymers * anionic polymerization * tert-alkoxides Subject RIV: CD - Macromolecular Chemistry

  3. Properties of novel anion selective material with DABCO functional groups for alkaline water electrolysis

    Czech Academy of Sciences Publication Activity Database

    Hnát, J.; Žitka, Jan; Paidar, M.; Bouzek, K.

    Prague: University of Chemistry and Technology, Czech Hydrogen Technology Platform, 2015 - (Bouzek, K.; Doucek, A.). s. 28 ISBN 978-80-7080-920-4. [International Conference on Hydrogen Technologies /6./ - Hydrogen Days 2015. 18.03.2015-20.03.2015, Prague] Institutional support: RVO:61389013 Keywords : alkaline water electrolysis * anion selective polymer electrolyte * zero-gap arrangement Subject RIV: CD - Macromolecular Chemistry

  4. CERN Relay Race: a great success!

    CERN Multimedia

    Staff Association

    2016-01-01

    On Thursday May 19, the traditional relay race was held at CERN, organised jointly by the Running Club and the CERN Staff Association. In spite of the less than optimal weather, the 127 registered teams were not discouraged. Warmed by their efforts on the roads of CERN, the participants were able to withstand the chilly May weather. The start signal for the race was given by our Director General, demonstrating the interest in this event at the highest level of the Organization. Thank you for this much appreciated commitment! Can we hope for next year to see a team from the Directorate in the race? The many spectators who had come to cheer on the runners could also visit the stalls staffed by a few clubs and some of Interfon’s commercial partners. Refreshment and food stands contributed to the friendly atmosphere. The organisation of such an event requires however a substantial investment in order to cover all aspects of logistics, from preparation before the race, to the actual establishment ...

  5. CORELA: A cooperative relaying enhanced link adaptation algorithm for IEEE 802.11 WLANs

    OpenAIRE

    Li, L.; Kaleshi, D; Zhong, Fan

    2011-01-01

    One of the key challenges for cooperative relaying multi-rate wireless networks is the integration and interaction of relaying with link adaptation algorithms, in particular under incomplete and/or imprecise channel state information conditions. In this paper we propose a practical cooperative relaying link adaptation medium access protocol that considers the historical link quality to enable the relay terminal to adjust its transmission relaying rate by estimating the error probability based...

  6. PERFORMANCE ANALYSIS OF COOPERATION SCHEMES IN EAVESDROPPER ASSISTED RELAY CHANNEL

    Directory of Open Access Journals (Sweden)

    Vaibhav Kumar Gupta

    2014-06-01

    Full Text Available The prominence of the wireless communication has been urging the monotonically increasing demand of security and privacy. In wireless systems, the notion of perfect secrecy of information with respect to illegitimate nodes can be ensured via physical layer security (PLS techniques. Unfortunately, they can be made less effective if source- eavesdropper wiretap channel is better than the main source-receiver channel. The various node cooperation schemes can be employed to combat this limitation where a relay node assists the communication to improve the performance significantly. In this paper, a four node wireless communication system consisting of a source, a destination, a relay and an eavesdropper as wire-tapper has been considered. The performance of the traditional cooperation schemes in terms of secrecy rate has been investigated with a different scenario where relay node helps the eavesdropper to deteriorate the secrecy rate. In addition, since legitimate receiver can overhear the transmission of relay, it favours the achievable secrecy rate. We formulate an analytical expression of conditional secrecy outage probability for the investigated system. From the obtained simulation results, it has been observed that secrecy rate is monotonically increases with path loss index. Furthermore, the proper selection of the system parameters leads to enhance the secrecy performance of the system even if relay pertains to degrade the performance. Amplify-and-forward, cooperation, decode-and-Forward, secrecy rate, relay.

  7. Interference Cancellation in Multi-Access Wireless Relay Networks

    CERN Document Server

    Li, Liangbin; Jafarkhani, Hamid

    2010-01-01

    This paper studies multi-user transmission and detection schemes for multi-access relay networks (MARNs). In a $(J, J_a, R_a, M)$ MARN, $J$ source nodes, each equipped with $J_a$ antennas, send independent messages to one $M$-antenna destination node through one $R_a$-antenna relay node. For complexity considerations, nodes are subject to two linear constraints. The relay generates its output signal by linearly transforming its received signal without decoding. The receiver has linear decoding complexity in the number of users. A new protocol called IC-Relay-TDMA is proposed which takes two steps. In the first step, user symbols are transmitted concurrently to the relay to enhance transmission rates. At the relay, interference cancellation (IC) schemes, previously proposed for systems with direct transmission, are applied to decouple the information of multi-users without decoding. In the second step, symbols of different users are forwarded to the receiver in the time division multi-access (TDMA) fashion. At...

  8. Resonant spectra of quadrupolar anions

    CERN Document Server

    Fossez, K; Nazarewicz, W; Michel, N; Garrett, W R; Płoszajczak, M

    2016-01-01

    In quadrupole-bound anions, an extra electron is attached at a sufficiently large quadrupole moment of a neutral molecule, which is lacking a permanent dipole moment. The nature of the bound states and low-lying resonances of such anions is of interest for understanding the threshold behavior of open quantum systems in general. In this work, we investigate the properties of quadrupolar anions as extreme halo systems, the formation of rotational bands, and the transition from a subcritical to supercritical electric quadrupole moment. We solve the electron-plus-molecule problem using a non-adiabatic coupled-channel formalism by employing the Berggren ensemble, which explicitly contains bound states, narrow resonances, and the scattering continuum. We demonstrate that binding energies and radii of quadrupolar anions strictly follow the scaling laws for two-body halo systems. Contrary to the case of dipolar anions, ground-state band of quadrupolar anions smoothly extend into the continuum, and many rotational ban...

  9. Bound anionic states of adenine

    OpenAIRE

    Harańczyk, Maciej; Gutowski, Maciej; Li, Xiang; Bowen, Kit H.

    2007-01-01

    Anionic states of nucleic acid bases are involved in DNA damage by low-energy electrons and in charge transfer through DNA. Previous gas phase studies of free, unsolvated nucleic acid base parent anions probed only dipole-bound states, which are not present in condensed phase environments, but did not observe valence anionic states, which for purine bases are thought to be adiabatically unbound. Contrary to this expectation, we have demonstrated that some thus far ignored tautomers of adenine...

  10. Bad chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    General chemistry courses haven't changed significantly in forty years. Because most basic chemistry students are premedical students, medical schools have enormous influence and could help us start all over again to create undergraduate chemistry education that works.

  11. Relays from Mars demonstrate international interplanetary networking

    Science.gov (United States)

    2004-08-01

    On 4 August at 14:24 CEST, as Mars Express flew over one of NASA’s Mars exploration rovers, Opportunity, it successfully received data previously collected and stored by the rover. The data, including 15 science images from the rover's nine cameras, were then downlinked to ESA’s European Space Operations Centre in Darmstadt (Germany) and immediately relayed to the Mars Exploration Rovers team based at the Jet Propulsion Laboratory in Pasadena, USA. NASA orbiters Mars Odyssey and Mars Global Surveyor have so far relayed most of the data produced by the rovers since they landed in January. Communication compatibility between Mars Express and the rovers had already been demonstrated in February, although at a low rate that did not convey much data. The 4 August session, at a transmit rate of 42.6 megabits in about six minutes, set a new mark for international networking around another planet. The success of this demonstration is the result of years of groundwork and was made possible because both Mars Express and the Mars rovers use the same communication protocol. This protocol, called Proximity-1, was developed by the international Consultative Committee for Space Data Systems, an international partnership for standardising techniques for handling space data. Mars Express was 1400 kilometres above the Martian surface during the 4 August session with Opportunity, with the goal of a reliable transfer of lots of data. Engineers for both agencies plan to repeat this display of international cooperation today, 10 August, with another set of Opportunity images. “We're delighted how well this has been working, and thankful to have Mars Express in orbit,” said Richard Horttor of NASA's Jet Propulsion Laboratory, Pasadena, California, project manager for NASA's role in Mars Express. JPL engineer Gary Noreen of the Mars Network Office said: “the capabilities that our international teamwork is advancing this month could be important in future exploration of Mars

  12. Mobility-Based Mobile Relay Selection in MANETs

    Science.gov (United States)

    Kim, Gilnam; Lee, Hyoungjoo; Lee, Kwang Bok

    The future wireless mobile communication networks are expected to provide seamless wireless access and data exchange to mobile users. In particular, it is expected that the demand for ubiquitous data exchange between mobile users will increase with the widespread use of various wireless applications of the intelligent transportation system (ITS) and intelligent vehicles. Mobile ad hoc networks (MANETs) are one of the representative research areas pursuing the technology needed to satisfy the increasing mobile communication requirements. However, most of the works on MANET systems do not take into account the continuous and dynamic changes of nodal mobility to accommodate system design and performance evaluation. The mobility of nodes limits the reliability of communication between the source and the destination node since a link between two continuously moving nodes is established only when one node enters the transmission range of the other. To alleviate this problem, mobile relay has been studied. In particular, it is shown that relay selection is an efficient way to support nodal mobility in MANET systems. In this paper, we propose a mobility-based relay selection algorithm for the MANET environment. Firstly, we define the lifetime as the maximum link duration for which the link between two nodes remains active. Therefore, the lifetime indicates the reliability of the relay link which measures its capability to successfully support relayed communication when requested by the source node. Furthermore, we consider a series of realistic scenarios according to the randomness of nodal mobility. Thus, the proposed algorithm can be easily applied in practical MANET systems by choosing the appropriate node mobility behavior. The numerical results show that the improved reliability of the proposed algorithm's relayed communication is achieved with a proper number of mobile relay nodes rather than with the conventional selection algorithm. Lastly, we show that random

  13. Performance Analysis of Selective Decode-and-Forward Multinode Incremental Relaying with Maximal Ratio Combining

    KAUST Repository

    Hadjtaieb, Amir

    2013-09-12

    In this paper, we propose an incremental multinode relaying protocol with arbitrary N-relay nodes that allows an efficient use of the channel spectrum. The destination combines the received signals from the source and the relays using maximal ratio Combining (MRC). The transmission ends successfully once the accumulated signal-to-noise ratio (SNR) exceeds a predefined threshold. The number of relays participating in the transmission is adapted to the channel conditions based on the feedback from the destination. The use of incremental relaying allows obtaining a higher spectral efficiency. Moreover, the symbol error probability (SEP) performance is enhanced by using MRC at the relays. The use of MRC at the relays implies that each relay overhears the signals from the source and all previous relays and combines them using MRC. The proposed protocol differs from most of existing relaying protocol by the fact that it combines both incremental relaying and MRC at the relays for a multinode topology. Our analyses for a decode-and-forward mode show that: (i) compared to existing multinode relaying schemes, the proposed scheme can essentially achieve the same SEP performance but with less average number of time slots, (ii) compared to schemes without MRC at the relays, the proposed scheme can approximately achieve a 3 dB gain.

  14. Anion analysis using capillary electrophoresis in the Halden reactor

    International Nuclear Information System (INIS)

    A significant investment has been made over the last decade in water chemistry analysis capability at the Halden Reactor, reflecting both the need to maintain system reliability and to provide chemical analyses for the increasing number of corrosion and chemistry-related experiments being performed in the reactor. Control of concentrations of anionic species (chloride, sulphate and nitrate) is of crucial importance in reducing the potential of stainless steel components to undergo stress corrosion cracking. Currently at Halden, samples must be taken from the coolant in the reactor itself, several auxiliary systems and approximately 10 test loop systems. Previously, anion analyses were performed using ion chromatography. In 1996, this technique was superseded by capillary electrophoresis since the latter has several advantages over the former, including speed of analysis. This paper will present operational experience of using capillary electrophoresis from two different suppliers. A discussion of the advantages and disadvantages of the technique over ion chromatography is included. (author)

  15. Opportunistic Wireless Relay Networks: Diversity-Multiplexing Tradeoff

    CERN Document Server

    Abouelseoud, Mohamed

    2011-01-01

    Opportunistic analysis has traditionally relied on independence assumptions that break down in many interesting and useful network topologies. This paper develops techniques that expand opportunistic analysis to a broader class of networks, proposes new opportunistic methods for several network geometries, and analyzes them in the high-SNR regime. For each of the geometries studied in the paper, we analyze the opportunistic DMT of several relay protocols, including amplify-and-forward, decode-and-forward, compress-and-forward, non-orthogonal amplify-forward, and dynamic decode-forward. Among the highlights of the results: in a variety of multi-user single-relay networks, simple selection strategies are developed and shown to be DMT-optimal. It is shown that compress-forward relaying achieves the DMT upper bound in the opportunistic multiple-access relay channel as well as in the opportunistic nxn user network with relay. Other protocols, e.g. dynamic decode-forward, are shown to be near optimal in several cas...

  16. Efficient incremental relaying for packet transmission over fading channels

    KAUST Repository

    Fareed, Muhammad Mehboob

    2014-07-01

    In this paper, we propose a novel relaying scheme for packet transmission over fading channels, which improves the spectral efficiency of cooperative diversity systems by utilizing limited feedback from the destination. Our scheme capitalizes on the fact that relaying is only required when direct transmission suffers deep fading. We calculate the packet error rate for the proposed efficient incremental relaying (EIR) scheme with both amplify and forward and decode and forward relaying. We compare the performance of the EIR scheme with the threshold-based incremental relaying (TIR) scheme. It is shown that the efficiency of the TIR scheme is better for lower values of the threshold. However, the efficiency of the TIR scheme for higher values of threshold is outperformed by the EIR. In addition, three new threshold-based adaptive EIR are devised to further improve the efficiency of the EIR scheme. We calculate the packet error rate and the efficiency of these new schemes to provide the analytical insight. © 2014 IEEE.

  17. Implementing Strategic Planning Capabilities Within the Mars Relay Operations Service

    Science.gov (United States)

    Hy, Franklin; Gladden, Roy; Allard, Dan; Wallick, Michael

    2011-01-01

    Since the Mars Exploration Rovers (MER), Spirit and Opportunity, began their travels across the Martian surface in January of 2004, orbiting spacecraft such as the Mars 2001 Odyssey orbiter have relayed the majority of their collected scientific and operational data to and from Earth. From the beginning of those missions, it was evident that using orbiters to relay data to and from the surface of Mars was a vastly more efficient communications strategy in terms of power consumption and bandwidth compared to direct-to-Earth means. However, the coordination between the various spacecraft, which are largely managed independently and on differing commanding timelines, has always proven to be a challenge. Until recently, the ground operators of all these spacecraft have coordinated the movement of data through this network using a collection of ad hoc human interfaces and various, independent software tools. The Mars Relay Operations Service (MaROS) has been developed to manage the evolving needs of the Mars relay network, and specifically to standardize and integrate the relay planning and coordination data into a centralized infrastructure. This paper explores the journey of developing the MaROS system, from inception to delivery and acceptance by the Mars mission users.

  18. Relay communications strategies for Mars exploration through 2020

    Science.gov (United States)

    Edwards, C. D., Jr.; Arnold, B.; Depaula, R.; Kazz, G.; Lee, C.; Noreen, G.

    2006-07-01

    Mars exploration poses significant telecommunications challenges, including the return of large data volumes from high-resolution surface instruments, highly constrained mass, power, and energy for surface spacecraft, frequent telemetry and command sessions for supporting complex surface operations, and high-risk mission events such as entry, descent, and landing for which the capture of engineering telemetry is deemed critical. Relay telecommunication via Mars-orbiting spacecraft offers significant advantages in meeting these challenges, relative to conventional direct-to-Earth communications. NASA's Mars Global Surveyor and Mars Odyssey orbiters, along with ESA's Mars Express orbiter, represent an initial relay telecommunications infrastructure that has successfully supported the Spirit and Opportunity rovers. With the arrival of the Mars Reconnaissance Orbiter in 2006, this expanded relay network will provide key support to the 2007 Phoenix Lander and 2009 Mars Science Laboratory missions later this decade. Second-decade mission concepts will introduce new communications challenges; the provision of relay payloads on science orbiters provides a cost-effective means to sustain and evolve the Mars relay network.

  19. Relay Implementation in WiMAX System Level Simulator

    Science.gov (United States)

    Mumtaz, Shahid; Tu, Le Thanh; Sadeghi, Rasool; Gamerio, Atilio

    Future wireless communication systems are expected to provide more stable and higher data rate transmissions in the whole network. WiMAX is one of the technologies to cover diverse geographic regions. WiMAX covers the high dense urban areas and provide access over large geographic regions in remote rural area. However, in both scenarios it is challenging to cover the entire service area. In both cases relays are foreseen to extend the range of the BS and to increase the system throughput allowing for a cost-efficient deployment and service. As multi-hop/relay has complex interactions between the routing and medium access control decisions, the extent to which analytical expressions can be used to explore its benefits are limited. Consequently simulations tend to be the preferred way of assessing the performance of relays. In this paper, we explain, how to deploy fixed-relays by using computer simulation in WiMAX system and we consistently observed that the throughput is increased and the outage is decreased in the relay-augmented WiMAX network, which is converted to range extension without any capacity penalty, for the realistic range of values of the propagation and other system parameters investigated.

  20. Systematic Network Coding with the Aid of a Full-Duplex Relay

    DEFF Research Database (Denmark)

    Giacaglia, Giuliano; Shi, Xiaomeng; Kim, MinJi;

    2013-01-01

    deliver a given number of data packets to a receiver with the aid of a relay. The source broadcasts to both the receiver and the relay using one frequency, while the relay uses another frequency for transmissions to the receiver, allowing for a full-duplex operation of the relay. We analyze the decoding...... complexity and delay performance of two types of relays: one that preserves the systematic structure of the code from the source; another that does not. A systematic relay forwards uncoded packets upon reception, but transmits coded packets to the receiver after receiving the first coded packet from the...

  1. Alternate MIMO AF relaying networks with interference alignment: Spectral efficient protocol and linear filter design

    KAUST Repository

    Park, Kihong

    2013-02-01

    In this paper, we study a two-hop relaying network consisting of one source, one destination, and three amplify-and-forward (AF) relays with multiple antennas. To compensate for the capacity prelog factor loss of 1/2$ due to the half-duplex relaying, alternate transmission is performed among three relays, and the inter-relay interference due to the alternate relaying is aligned to make additional degrees of freedom. In addition, suboptimal linear filter designs at the nodes are proposed to maximize the achievable sum rate for different fading scenarios when the destination utilizes a minimum mean-square error filter. © 1967-2012 IEEE.

  2. Thermal behaviour of synthetic pyroaurite-like anionic clay

    Czech Academy of Sciences Publication Activity Database

    Kovanda, F.; Balek, Vladimír; Dorničák, V.; Martinec, Petr; Mašláň, M.; Vaculíková, Lenka; Koloušek, D.; Bountsewa, M.

    2003-01-01

    Roč. 71, - (2003), s. 727-737. ISSN 0368-4466 R&D Projects: GA ČR GA202/00/0982; GA ČR GA106/02/0523 Institutional research plan: CEZ:AV0Z4032918; CEZ:AV0Z3086906 Keywords : pyroaurite-like anionic clay * thermal decomposition Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 1.094, year: 2003

  3. Thermal behaviour of synthetic pyroaurite-like anionic clay

    Czech Academy of Sciences Publication Activity Database

    Kovanda, F.; Balek, Vladimír; Dorničák, V.; Martinec, P.; Mašláň, M.; Bílková, L.; Koloušek, D.; Bountsewa, I. M.

    2003-01-01

    Roč. 72, č. 1 (2003), s. 727-737. ISSN 1388-6150 R&D Projects: GA MŠk LN00A028; GA ČR GA202/00/0982; GA ČR GA106/02/0523 Institutional research plan: CEZ:AV0Z4032918 Keywords : layered double hydroxide * pyroaurite-like anionic clay * thermal decomposition Subject RIV: CA - Inorganic Chemistry Impact factor: 1.094, year: 2003

  4. Complex chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bong Gon; Kim, Jae Sang; Kim, Jin Eun; Lee, Boo Yeon

    2006-06-15

    This book introduces complex chemistry with ten chapters, which include development of complex chemistry on history coordination theory and Warner's coordination theory and new development of complex chemistry, nomenclature on complex with conception and define, chemical formula on coordination compound, symbol of stereochemistry, stereo structure and isomerism, electron structure and bond theory on complex, structure of complex like NMR and XAFS, balance and reaction on solution, an organo-metallic chemistry, biology inorganic chemistry, material chemistry of complex, design of complex and calculation chemistry.

  5. Complex chemistry

    International Nuclear Information System (INIS)

    This book introduces complex chemistry with ten chapters, which include development of complex chemistry on history coordination theory and Warner's coordination theory and new development of complex chemistry, nomenclature on complex with conception and define, chemical formula on coordination compound, symbol of stereochemistry, stereo structure and isomerism, electron structure and bond theory on complex, structure of complex like NMR and XAFS, balance and reaction on solution, an organo-metallic chemistry, biology inorganic chemistry, material chemistry of complex, design of complex and calculation chemistry.

  6. Urea/thiourea derivatives and Zn(II)-DPA complex as receptors for anionic recognition—A brief account

    Indian Academy of Sciences (India)

    Priyadip Das; Prasenjit Mahato; Amrita Ghosh; Amal K Mandal; Tanmay Banerjee; Sukdeb Saha; Amitava Das

    2011-03-01

    This review covers few examples of anion complexation chemistry, with a special focus on urea/thiourea-based receptors and Zn(II)-dipicolyl amine-based receptors. This article specially focuses on structural aspects of the receptors and the anions for obtaining the desire specificity along with an efficient receptor-anion interaction. Two types of receptors have been described in this brief account; first one being the strong hydrogen bond donor urea/thiourea derivatives, which binds the anionic analytes through hydrogen bonded interactions; while, the second type of receptors are coordination complexes, where the coordination of the anion to the metal centre. In both the cases the anion binding modulate the energy gap between the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) and thereby the spectroscopic response. Appropriate choice of the signalling unit may allow probing the anion binding phenomena through visual detection.

  7. Accurate performance analysis of opportunistic decode-and-forward relaying

    KAUST Repository

    Tourki, Kamel

    2011-07-01

    In this paper, we investigate an opportunistic relaying scheme where the selected relay assists the source-destination (direct) communication. In our study, we consider a regenerative opportunistic relaying scheme in which the direct path may be considered unusable, and the destination may use a selection combining technique. We first derive the exact statistics of each hop, in terms of probability density function (PDF). Then, the PDFs are used to determine accurate closed form expressions for end-to-end outage probability for a transmission rate R. Furthermore, we evaluate the asymptotical performance analysis and the diversity order is deduced. Finally, we validate our analysis by showing that performance simulation results coincide with our analytical results over different network architectures. © 2011 IEEE.

  8. Telecommunications Relay Support of the Mars Phoenix Lander Mission

    Science.gov (United States)

    Edwards, Charles D., Jr.; Erickson, James K.; Gladden, Roy E.; Guinn, Joseph R.; Ilott, Peter A.; Jai, Benhan; Johnston, Martin D.; Kornfeld, Richard P.; Martin-Mur, Tomas J.; McSmith, Gaylon W.; Thomas, Reid C.; Varghese, Phil; Signori, Gina; Schmitz, Peter

    2010-01-01

    The Phoenix Lander, first of NASA's Mars Scout missions, arrived at the Red Planet on May 25, 2008. From the moment the lander separated from its interplanetary cruise stage shortly before entry, the spacecraft could no longer communicate directly with Earth, and was instead entirely dependent on UHF relay communications via an international network of orbiting Mars spacecraft, including NASA's 2001 Mars Odyssey (ODY) and Mars Reconnaissance Orbiter (MRO) spacecraft, as well as ESA's Mars Express (MEX) spacecraft. All three orbiters captured critical event telemetry and/or tracking data during Phoenix Entry, Descent and Landing. During the Phoenix surface mission, ODY and MRO provided command and telemetry services, far surpassing the original data return requirements. The availability of MEX as a backup relay asset enhanced the robustness of the surface relay plan. In addition to telecommunications services, Doppler tracking observables acquired on the UHF link yielded an accurate position for the Phoenix landing site.

  9. Outage analysis for underlay relay-assisted cognitive networks

    KAUST Repository

    Tourki, Kamel

    2012-12-01

    Cooperative relay technology was recently introduced into cognitive radio networks in order to enhance network capacity, scalability, and reliability of end-to-end communication. In this paper, we investigate an underlay cognitive network where the quality of service of the secondary link is maintained by triggering an opportunistic regenerative relaying once it falls under an unacceptable level. We first provide the exact cumulative density function (CDF) of received signal-to-noise (SNR) over each hop with co-located relays. Then, the CDFs are used to determine very accurate closed-form expression for the outage probability for a transmission rate R. We validate our analysis by showing that simulation results coincide with our analytical results in Rayleigh fading channels. © 2012 IEEE.

  10. Joint opportunistic scheduling and network coding for bidirectional relay channel

    KAUST Repository

    Shaqfeh, Mohammad

    2013-07-01

    In this paper, we consider a two-way communication system in which two users communicate with each other through an intermediate relay over block-fading channels. We investigate the optimal opportunistic scheduling scheme in order to maximize the long-term average transmission rate in the system assuming symmetric information flow between the two users. Based on the channel state information, the scheduler decides that either one of the users transmits to the relay, or the relay transmits to a single user or broadcasts to both users a combined version of the two users\\' transmitted information by using linear network coding. We obtain the optimal scheduling scheme by using the Lagrangian dual problem. Furthermore, in order to characterize the gains of network coding and opportunistic scheduling, we compare the achievable rate of the system versus suboptimal schemes in which the gains of network coding and opportunistic scheduling are partially exploited. © 2013 IEEE.

  11. Exact performance analysis of decode-and-forward opportunistic relaying

    KAUST Repository

    Tourki, Kamel

    2010-06-01

    In this paper, we investigate a dual-hop decode-and-forward opportunistic relaying scheme where the source may or may not be able to communicate directly with the destination. In our study, we consider a regenerative relaying scheme in which the decision to cooperate takes into account the effect of the possible erroneously detected and transmitted data at the best relay. We derive an exact closed-form expression for the end-to-end bit-error rate (BER) of binary phase-shift keying (BPSK) modulation based on the exact statistics of each hop. Unlike existing works where the analysis focused on high signal-to-noise ratio (SNR) regime, such results are important to enable the designers to take decisions regarding practical systems that operate at low SNR regime. We show that performance simulation results coincide with our analytical results.

  12. Outage rates and outage durations of opportunistic relaying systems

    CERN Document Server

    Hadzi-Velkov, Zoran; 10.1109/LCOMM.2010.02.091683

    2010-01-01

    Opportunistic relaying is a simple yet efficient cooperation scheme that achieves full diversity and preserves the spectral efficiency among the spatially distributed stations. However, the stations' mobility causes temporal correlation of the system's capacity outage events, which gives rise to its important second-order outage statistical parameters, such as the average outage rate (AOR) and the average outage duration (AOD). This letter presents exact analytical expressions for the AOR and the AOD of an opportunistic relaying system, which employs a mobile source and a mobile destination (without a direct path), and an arbitrary number of (fixed-gain amplify-and-forward or decode-and-forward) mobile relays in Rayleigh fading environment.

  13. Mathematical Chemistry

    OpenAIRE

    Trinajstić, Nenad; Gutman, Ivan

    2002-01-01

    A brief description is given of the historical development of mathematics and chemistry. A path leading to the meeting of these two sciences is described. An attempt is made to define mathematical chemistry, and journals containing the term mathematical chemistry in their titles are noted. In conclusion, the statement is made that although chemistry is an experimental science aimed at preparing new compounds and materials, mathematics is very useful in chemistry, among other things, to produc...

  14. A digital interface for Gaussian relay networks: lifting codes from the discrete superposition model to Gaussian relay networks

    CERN Document Server

    Anand, M

    2010-01-01

    For every Gaussian relay network with a single source-destination pair, it is known that there exists a corresponding deterministic network called the discrete superposition network that approximates its capacity uniformly over all SNR's to within a bounded number of bits. The next step in this program of rigorous approximation is to determine whether coding schemes for discrete superposition models can be lifted to Gaussian relay networks with a bounded rate loss independent of SNR. We establish precisely this property and show that the superposition model can thus serve as a strong surrogate for designing codes for Gaussian relay networks. We show that a code for a Gaussian relay network, with a single source-destination pair and multiple relay nodes, can be designed from any code for the corresponding discrete superposition network simply by pruning it. In comparison to the rate of the discrete superposition network's code, the rate of the Gaussian network's code only reduces at most by a constant that is ...

  15. Cooperative AF Relaying in Spectrum-Sharing Systems: Outage Probability Analysis under Co-Channel Interferences and Relay Selection

    KAUST Repository

    Xia, Minghua

    2012-11-01

    For cooperative amplify-and-forward (AF) relaying in spectrum-sharing wireless systems, secondary users share spectrum resources originally licensed to primary users to communicate with each other and, thus, the transmit power of secondary transmitters is strictly limited by the tolerable interference powers at primary receivers. Furthermore, the received signals at a relay and at a secondary receiver are inevitably interfered by the signals from primary transmitters. These co-channel interferences (CCIs) from concurrent primary transmission can significantly degrade the performance of secondary transmission. This paper studies the effect of CCIs on outage probability of the secondary link in a spectrum-sharing environment. In particular, in order to compensate the performance loss due to CCIs, the transmit powers of a secondary transmitter and its relaying node are respectively optimized with respect to both the tolerable interference powers at the primary receivers and the CCIs from the primary transmitters. Moreover, when multiple relays are available, the technique of opportunistic relay selection is exploited to further improve system performance with low implementation complexity. By analyzing lower and upper bounds on the outage probability of the secondary system, this study reveals that it is the tolerable interference powers at primary receivers that dominate the system performance, rather than the CCIs from primary transmitters. System designers will benefit from this result in planning and designing next-generation broadband spectrum-sharing systems.

  16. Power Allocation and Pricing in Multi-User Relay Networks Using Stackelberg and Bargaining Games

    CERN Document Server

    Cao, Qian; Jing, Yindi

    2012-01-01

    This paper considers a multi-user single-relay wireless network, where the relay gets paid for helping the users forward signals, and the users pay to receive the relay service. We study the relay power allocation and pricing problems, and model the interaction between the users and the relay as a two-level Stackelberg game. In this game, the relay, modeled as the service provider and the leader of the game, sets the relay price to maximize its revenue; while the users are modeled as customers and the followers who buy power from the relay for higher transmission rates. We use a bargaining game to model the negotiation among users to achieve a fair allocation of the relay power. Based on the proposed fair relay power allocation rule, the optimal relay power price that maximizes the relay revenue is derived analytically. Simulation shows that the proposed power allocation scheme achieves higher network sum-rate and relay revenue than the even power allocation. Furthermore, compared with the sum-rate-optimal so...

  17. Enhancing overcurrent relay performance using wavelet packet transform

    International Nuclear Information System (INIS)

    The function of a power system relaying is to cause the prompt removal of any element of power system from service when it is subjected to short circuit or it starts to operate in any abnormal manner that might cause damage or otherwise interfere with the effective operation of the rest of the system. Overcurrent protection is one of the most widely used relays in power system which is used for both primary and back-up protective relays, and applied in every protective zone in the system. The application of time overcurrent relays in power system presents serious limitations in terms of sensitivity and selectivity. Digital forms of such relays are being mostly used which have the advantages of data recording and adaptive features. This thesis introduces a technique based on Wavelet Packet Transform (WPT) to detect short circuit faults within wide variation in generating conditions, with very small voltage variation, and High-Impedance Faults (HIFs). Besides, it examines the load current continuously and changes the relay pick up value adaptively. WPT is used to estimate proper value for the RMS fundamental and hence calculate trip time accurately even that when the signals have been contaminated with other harmonics, inter harmonics or subharmonic. Simulation work was conducted using Alternative Transient Program (ATP) package. A radial distribution system and series compensated line are modeled as case studies. The performance of the proposed overcurrent scheme for both lines is extensively tested during different operating conditions including; normal, internal short circuit faults, HIFs and similar situations to HIFs: such as capacitor switching (in), capacitor switching (out), load switching, and no load line switching. This thesis also uses a technique that estimates the location of short circuit faults on a radial distribution system. The technique was tested to evaluate its suitability. The results indicate that the proposed technique works well. It also

  18. DISCOVERY OF INTERSTELLAR ANIONS IN CEPHEUS AND AURIGA

    International Nuclear Information System (INIS)

    We report the detection of microwave emission lines from the hydrocarbon anion C6H- and its parent neutral C6H in the star-forming region L1251A (in Cepheus), and the pre-stellar core L1512 (in Auriga). The carbon-chain-bearing species C4H, HC3N, HC5N, HC7N, and C3S are also detected in large abundances. The observations of L1251A constitute the first detections of anions and long-chain polyynes and cyanopolyynes (with more than five carbon atoms) in the Cepheus Flare star-forming region, and the first detection of anions in the vicinity of a protostar outside of the Taurus molecular cloud complex, indicating a possible wider importance for anions in the chemistry of star formation. Rotational excitation temperatures have been derived from the HC3N hyperfine structure lines and are found to be 6.2 K for L1251A and 8.7 K for L1512. The anion-to-neutral ratios are 3.6% and 4.1%, respectively, which are within the range of values previously observed in the interstellar medium, and suggest a relative uniformity in the processes governing anion abundances in different dense interstellar clouds. This research contributes toward the growing body of evidence that carbon chain anions are relatively abundant in interstellar clouds throughout the Galaxy, but especially in the regions of relatively high density and high depletion surrounding pre-stellar cores and young, embedded protostars.

  19. Protein Camouflage: Supramolecular Anion Recognition by Ubiquitin.

    Science.gov (United States)

    Mallon, Madeleine; Dutt, Som; Schrader, Thomas; Crowley, Peter B

    2016-04-15

    Progress in the field of bio-supramolecular chemistry, the bottom-up assembly of protein-ligand systems, relies on a detailed knowledge of molecular recognition. To address this issue, we have characterised complex formation between human ubiquitin (HUb) and four supramolecular anions. The ligands were: pyrenetetrasulfonic acid (4PSA), p-sulfonato-calix[4]arene (SCLX4), bisphosphate tweezers (CLR01) and meso-tetrakis (4-sulfonatophenyl)porphyrin (TPPS), which vary in net charge, size, shape and hydrophobicity. All four ligands induced significant changes in the HSQC spectrum of HUb. Chemical shift perturbations and line-broadening effects were used to identify binding sites and to quantify affinities. Supporting data were obtained from docking simulations. It was found that these weakly interacting ligands bind to extensive surface patches on HUb. A comparison of the data suggests some general indicators for the protein-binding specificity of supramolecular anions. Differences in binding were observed between the cavity-containing and planar ligands. The former had a preference for the arginine-rich, flexible C terminus of HUb. PMID:26818656

  20. Estimation of the LTE relay influence on the cell

    Directory of Open Access Journals (Sweden)

    V. Ya. Voropayeva

    2014-06-01

    Full Text Available Problem definition. Information technologies are constantly evolving. This process leads to an annual traffic increasing. Also requirements to infocommunication nerworks are increasing too. It stimulates the development of new technologies that will be able to satisfy the growing needs of users. At the present stage of evolution of world telecommunication technologies in mobile communications development and implementation of the fourth generation standard (4G networks are relevant. This type of networks provides a higher data rate and high quality of service with an overall decrease in operating costs of telecommunications equipment. One of the most relevant technologies is Long Term Evolution (LTE, which is the development of the third generation UMTS networks. Now there is a standard of 3GPP - LTE-Advanced, which is an improvement of LTE and the official wireless communications standard of the 4th generation. Relay Nodes has appeared in LTE-Advanced networks for more effective scheduling. Relay catches the signal from a Mobile Station, amplifies it and transmit it further to a Base Station. Selecting the optimal location of relay. In this paper we consider one LTE cell and one repeater type I (in-band, half-duplex. For this type of relay we calculate the best position of installation. The calculated value of the cell radius is 400 m for densely populated city. The type of division duplex is TDD, the frame configuration is 2, the width of the frequency band is 10 MHz. To calculate the cell radius COST231 Hata s 3GPP TS 25.996 v9.0.0 model for urban macro network is used. Scheduling scheme uses an algorithm Fair Work Conserving (FWC. FWC relates to such type of algorithms that operate on a resource allocation equally between the users. Users connect to the network at the speed of λ, which may be various. Estimation of the LTE relay influence on the cell. From these simulation results, we can conclude that the larger amount of resource blocks

  1. Overview and Status of the Laser Communication Relay Demonstration

    Science.gov (United States)

    Luzhanskiy, E.; Edwards, B.; Israel, D.; Cornwell, D.; Staren, J.; Cummings, N.; Roberts, T.; Patschke, R.

    2016-01-01

    NASA is presently developing first all optical high data rate satellite relay system, LCRD. To be flown on commercial geosynchronous satellite, it will communicate at DPSK and PPM modulation formats up to 1.244 Gbps. LCRD flight payload is being developed by NASA's Goddard Space Flight Center. The two ground stations, one on Table Mountain in CA, developed by NASA's Jet Propulsion Laboratory and another on Hawaiian island will enable bi-directional relay operation and ground sites diversity experiments. In this paper we will report on the current state of LCRD system development, planned operational scenarios and expected system performance.

  2. Resource allocation for relay assisted cognitive radio networks

    KAUST Repository

    Zafar, Ammar

    2012-09-16

    In this paper, we present two optimal resource allocation schemes that maximize throughput and symbol correct rate (SCR). The throughput and SCR are derived. The derived throughput and SCR are optimized with respect to the sensing time, the source transmission power and the relay transmission power. Numerical results show that the optimal sensing time is dependent on the primary user\\'s signal-to-noise-ratio (SNR). They also show that SCR increases with increase in the number of relays. © 2012 IEEE.

  3. Phosphazene-promoted anionic polymerization

    KAUST Repository

    Zhao, Junpeng

    2014-01-01

    In the recent surge of metal-free polymerization techniques, phosphazene bases have shown their remarkable potential as organic promoters/catalysts for the anionic polymerization of various types of monomers. By complexation with the counterion (e.g. proton or lithium cation), phosphazene base significantly improve the nucleophilicity of the initiator/chain-end resulting in rapid and usually controlled anionic/quasi-anionic polymerization. In this review, we will introduce the general mechanism, i.e. in situ activation (of initiating sites) and polymerization, and summarize the applications of such a mechanism on macromolecular engineering toward functionalized polymers, block copolymers and complex macromolecular architectures.

  4. HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials

    Czech Academy of Sciences Publication Activity Database

    Fete, M. G.; Havlas, Zdeněk; Michl, Josef

    2011-01-01

    Roč. 133, č. 11 (2011), s. 4123-4131. ISSN 0002-7863 R&D Projects: GA AV ČR IAA400550708 Grant ostatní: NSF(US) CHE-0848477 Institutional research plan: CEZ:AV0Z40550506 Keywords : icosahedral anions * fluorinated carbaborane anions * redox potentials * gas-phase elektron detachment energy Subject RIV: CC - Organic Chemistry Impact factor: 9.907, year: 2011

  5. Optimal Contract Design for Cooperative Relay Incentive Mechanism under Moral Hazard

    Directory of Open Access Journals (Sweden)

    Nan Zhao

    2015-01-01

    Full Text Available Cooperative relay can effectively improve spectrum efficiency by exploiting the spatial diversity in the wireless networks. However, wireless nodes may acquire different network information with various users’ location and mobility, channels’ conditions, and other factors, which results in asymmetric information between the source and the relay nodes (RNs. In this paper, the relay incentive mechanism between relay nodes and the source is investigated under the asymmetric information. By modelling multiuser cooperative relay as a labour market, a contract model with moral hazard for relay incentive is proposed. To effectively incentivize the potential RNs to participate in cooperative relay, the optimization problems are formulated to maximize the source’s utility while meeting the feasible conditions under both symmetric and asymmetric information scenarios. Numerical simulation results demonstrate the effectiveness of the proposed contract design scheme for cooperative relay.

  6. Secure relay selection based on learning with negative externality in wireless networks

    Science.gov (United States)

    Zhao, Caidan; Xiao, Liang; Kang, Shan; Chen, Guiquan; Li, Yunzhou; Huang, Lianfen

    2013-12-01

    In this paper, we formulate relay selection into a Chinese restaurant game. A secure relay selection strategy is proposed for a wireless network, where multiple source nodes send messages to their destination nodes via several relay nodes, which have different processing and transmission capabilities as well as security properties. The relay selection utilizes a learning-based algorithm for the source nodes to reach their best responses in the Chinese restaurant game. In particular, the relay selection takes into account the negative externality of relay sharing among the source nodes, which learn the capabilities and security properties of relay nodes according to the current signals and the signal history. Simulation results show that this strategy improves the user utility and the overall security performance in wireless networks. In addition, the relay strategy is robust against the signal errors and deviations of some user from the desired actions.

  7. Physical-Layer Security of a Buffer-Aided Full-Duplex Relaying System

    KAUST Repository

    El Shafie, Ahmed

    2016-07-07

    This letter proposes a novel hybrid half-/full-duplex relaying scheme to enhance the relay channel security. A source node (Alice) communicates with her destination node (Bob) in the presence of a buffer-aided full-duplex relay node (Rooney) and a potential eavesdropper (Eve). Rooney adopts two different relaying, namely randomize-and-forward and decode-andforward relaying strategies, to improve the security of the legitimate system. In the first relaying strategy, Rooney uses a codebook different from that used at Alice. In the second relaying strategy, Rooney and Alice use the same codebooks. In addition, Rooney switches between half-duplex and full-duplex modes to further enhance the security of the legitimate system. The numerical results demonstrate that our proposed scheme achieves a significant average secrecy end-to-end throughput improvement relative to the conventional bufferless full-duplex relaying scheme.

  8. Interference alignment for degrees of freedom improvement in 3-relay half-duplex systems

    KAUST Repository

    Park, Seongho

    2011-12-01

    In a half-duplex relaying, the capacity pre-log factor is a major drawback in spectral efficiency. This paper proposes a linear precoding scheme and an alternate relaying protocol in a dual-hop half-duplex system where three relays help the communication between the source and the destination. In our proposed scheme, we consider a phase incoherent method in relays in which the source alternately transmits message signals to the different relays. In addition, we propose a linear interference alignment scheme which can eliminate the inter-relay interference resulted from the phase incoherence of relaying. Based on our analysis of degrees of freedom and our simulation results, we show that our proposed scheme achieves additional degrees of freedom compared to the conventional half-duplex relaying. © 2011 IEEE.

  9. Anion Transport with Chalcogen Bonds.

    Science.gov (United States)

    Benz, Sebastian; Macchione, Mariano; Verolet, Quentin; Mareda, Jiri; Sakai, Naomi; Matile, Stefan

    2016-07-27

    In this report, we introduce synthetic anion transporters that operate with chalcogen bonds. Electron-deficient dithieno[3,2-b;2',3'-d]thiophenes (DTTs) are identified as ideal to bind anions in the focal point of the σ holes on the cofacial endocyclic sulfur atoms. Anion binding in solution and anion transport across lipid bilayers are found to increase with the depth of the σ holes of the DTT anionophores. These results introduce DTTs and related architectures as a privileged motif to engineer chalcogen bonds into functional systems, complementary in scope to classics such as 2,2'-bipyrroles or 2,2'-bipyridines that operate with hydrogen bonds and lone pairs, respectively. PMID:27433964

  10. Power Allocation Strategies across N Orthogonal Channels at Both Source and Relay

    OpenAIRE

    Ko, Youngwook; Ardakani, Masoud; Vorobyov, Sergiy A.

    2010-01-01

    We consider a wireless relay network with one source, one relay and one destination, where communications between nodes are preformed via N orthogonal channels. This, for example, is the case when orthogonal frequency division multiplexing is employed for data communications. Since the power available at the source and relay is limited, we study optimal power allocation strategies at the source and relay in order to maximize the overall source-destination capacity under individual power const...

  11. Joint Source-Channel Cooperative Transmission over Relay-Broadcast Networks

    OpenAIRE

    Gunduz, Deniz; Erkip, Elza; Goldsmith, Andrea; Poor, H. Vincent

    2012-01-01

    Reliable transmission of a discrete memoryless source over a multiple-relay relay-broadcast network is considered. Motivated by sensor network applications, it is assumed that the relays and the destinations all have access to side information correlated with the underlying source signal. Joint source-channel cooperative transmission is studied in which the relays help the transmission of the source signal to the destinations by using both their overheard signals, as in the classical channel ...

  12. Peculiarities of the relays intended for operating trip coils of the high-voltage circuit breakers

    Directory of Open Access Journals (Sweden)

    Gurevich Vladimir

    2007-01-01

    Full Text Available Parameters of the subminiature electromagnetic relays used as output elements in microprocessor relay protection, do not correspond to technical specifications on these relay protection. The reasons of this discrepancy are analyzed. Contradictions and discrepancies of the international standards in this area are considered. It is shown, that absence of clearness in standards and mistakes in technical specifications of manufacturers of microprocessor protection do not allow estimating correctly technical parameters and lead to decrease in reliability of relay protection.

  13. 49 CFR 236.206 - Battery or power supply with respect to relay; location.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Battery or power supply with respect to relay..., AND APPLIANCES Automatic Block Signal Systems Standards § 236.206 Battery or power supply with respect to relay; location. The battery or power supply for each signal control relay circuit, where an...

  14. 47 CFR 64.606 - VRS and IP Relay provider and TRS program certification.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false VRS and IP Relay provider and TRS program... Services and Related Customer Premises Equipment for Persons With Disabilities § 64.606 VRS and IP Relay... including notification in the Federal Register. (2) VRS and IP Relay provider. Any entity desiring...

  15. Improved Relay Node Placement Algorithm for Wireless Sensor Networks Application in Wind Farm

    DEFF Research Database (Denmark)

    Chen, Qinyin; Hu, Y.; Chen, Zhe;

    2013-01-01

    An emergent application of Wireless Sensor Network (WSN) technology is in the area of Wind Farm Monitoring (WFM), in which relays are used to connect sensors. Key problems to solve in WFM include how to balance loads across relay nodes and how to place relay nodes for redundancy and fault...

  16. Relay Techniques for MIMO Wireless Networks with Multiple Source and Destination Pairs

    Directory of Open Access Journals (Sweden)

    Shi Hui

    2006-01-01

    Full Text Available A multiple-input multiple-output (MIMO relay network comprises source, relay, and destination nodes, each of which is equipped with multiple antennas. In a previous work, we proposed a MIMO relay scheme for a relay network with a single source and destination pair in which each of the multiple relay nodes performs QR decompositions of the backward and forward channel matrices in conjunction with phase control (QR-P-QR. In this paper, we extend this scheme to a MIMO relay network employing multiple source and destination pairs. Towards this goal, we use a group nulling approach to decompose a multiple S-D MIMO relay channel into parallel independent S-D MIMO relay channels, and then apply the QR-P-QR scheme to each of the decomposed MIMO relay links. We analytically show the logarithmic capacity scaling of the proposed relay scheme. Numerical examples confirm that the proposed relay scheme offers higher capacity than existing relay schemes.

  17. 76 FR 26641 - Relay Services for Deaf-Blind Individuals

    Science.gov (United States)

    2011-05-09

    ..., Notice of Proposed Rulemaking, published at 76 FR 4838, January 27, 2011 (NDBEDP NPRM). In the NDBEDP... COMMISSION 47 CFR Part 64 Relay Services for Deaf-Blind Individuals AGENCY: Federal Communications Commission. ACTION: Final rule. SUMMARY: In this document, the Commission adopts rules to establish the National...

  18. 77 FR 20553 - Relay Services for Deaf-Blind Individuals

    Science.gov (United States)

    2012-04-05

    ... Relay Services for Deaf-Blind Individuals, Report and Order, document FCC 11-56, published at 76 FR... requirement in 47 CFR 64.610(f)(2), published at 76 FR 26641, May 9, 2011, has not been approved by the Office..., Notice, published at 77 FR 18813, March 28, 2012. In addition, the Commission notes that pursuant to...

  19. 76 FR 31261 - Relay Services for Deaf-Blind Individuals

    Science.gov (United States)

    2011-05-31

    ... final rule that appeared in the Federal Register of May 9, 2011, 76 FR 26641. The document adopts rules... INFORMATION: In FR Doc. 2011-10228 published in the Federal Register on Monday, May 9, 2011, 76 FR 26641, the... COMMISSION 47 CFR Part 64 Relay Services for Deaf-Blind Individuals AGENCY: Federal Communications...

  20. Degrees of Freedom of Asymmetrical Multi-Way Relay Networks

    DEFF Research Database (Denmark)

    Sun, Fan; De Carvalho, Elisabeth

    relay is equipped with NR antennas. To study the capacity of this network, the degree of freedom (DOF) is characterized to be 2 Σi=1K Mi if NR ≥ Σi=1K Mi. The DOF implies that the number of symbols any transmitter can deliver and receive is equivalent to its number of antennas. The DOF is achievable...

  1. Micro-relay technology for energy-efficient integrated circuits

    CERN Document Server

    Kam, Hei

    2015-01-01

    This book describes the design of relay-based circuit systems from device fabrication to circuit micro-architectures. This book is ideal for both device engineers as well as circuit system designers and highlights the importance of co-design across design hierarchies when optimizing system performance (in this case, energy-efficiency). This book is ideal for researchers and engineers focused on semiconductors, integrated circuits, and energy efficient electronics. This book also: ·         Covers microsystem fabrication, MEMS device design, circuit design, circuit micro-architecture, and CAD ·         Describes work previously done in the field and also lays the groundwork and criteria for future energy-efficient device and system design ·         Maximizes reader insights into the design and modeling of micro-relay, micro-relay reliability, integrated circuit design with micro-relays, and more

  2. 76 FR 18490 - Contributions to the Telecommunications Relay Service Fund

    Science.gov (United States)

    2011-04-04

    ... Internet protocol compatible customer premises equipment; and (ii) does not include any service that is an... Internet-based customer services or video games that generate revenue, or can the revenues associated with... otherwise noted. Subpart F--Telecommunications Relay Services and Related Customer Premises Equipment...

  3. Silver nanoparticle catalysed redox reaction: An electron relay effect

    International Nuclear Information System (INIS)

    A silver cluster shows efficient catalytic activity in a redox reaction because the cluster acts as the electron relay centre behaving alternatively as an acceptor and as a donor of electrons. An effective transfer of electrons is possible when the redox potential of the cluster is intermediate between the electron donor and electron acceptor system

  4. 76 FR 58424 - Transmission Relay Loadability Reliability Standard

    Science.gov (United States)

    2011-09-21

    ... protective relays set pursuant to criterion 12.\\28\\ \\28\\ Id. at 23-24. 4. Proposed Requirement R6 25. Requirement R6 of proposed Reliability Standard PRC-023-2 requires each planning coordinator to conduct an... coordinator pursuant to Requirement R6 are provided until the first day of the first calendar quarter...

  5. 77 FR 16435 - Transmission Relay Loadability Reliability Standard

    Science.gov (United States)

    2012-03-21

    ... NERC. \\44\\ 76 FR 58,424 (2011). IV. Discussion 36. Pursuant to section 215(d)(2) of the FPA, the... protective relays set pursuant to criterion 12.\\26\\ \\26\\ Id. at 20, 23. Requirement R6 24. Requirement R6 of... coordinator pursuant to Requirement R6 are provided until the first day of the first calendar quarter...

  6. Commercial Grade Item (CGI) Dedication for Leak Detection Relays

    International Nuclear Information System (INIS)

    This Test Plan provides a test method to dedicate the leak detection relays used on the new Pumping Instrumentation and Control (PIC) skids. The new skids are fabricated on-site. The leak detection system is a safety class system per the Authorization Basis

  7. Performance Analysis and Comparison of 6to4 Relay Implementations

    Directory of Open Access Journals (Sweden)

    Gábor Lencse

    2013-10-01

    Full Text Available the depletion of the public IPv4 address pool may speed up the deployment of IPv6. The coexistence of the two versions of IP requires some transition mechanisms. One of them is 6to4 which provides a solution for the problem of an IPv6 capable device in an IPv4 only environment. From among the several 6to4 relay implementations, the following ones were selected for testing: sit under Linux, stf under FreeBSD and stf under NetBSD. Their stability and performance were in¬ves¬ti¬gat¬ed in a test network. The increasing measure of the load of the 6to4 relay implementations was set by incrementing the number of the client computers that provided the traffic. The packet loss and the response time of the 6to4 relay as well as the CPU utilization and the memory consumption of the computer running the tested 6to4 relay im¬ple¬men¬ta¬tions were measured. The implementations were tested also under very heavy load conditions to see if they are safe to be used in production systems.

  8. London 2012 Olympic Torch Relay style guide for licensees

    OpenAIRE

    2015-01-01

    The guidelines issued by the London Organising Committee of the Olympic Games and Paralympic Games Ltd (“LOCOG”) provide standards, requirements and guidelines for use of the London 2012 Olympic Torch Relay Emblem (the “Emblem”), by authorised licensees only.

  9. CERN’s annual relay a runaway success

    CERN Multimedia

    Klaus Hanke for the CERN Running Club

    2016-01-01

    With a record participation of 128 teams of six runners each, this year’s CERN Relay Race took place on 19 May on the Meyrin site.   One of the many winning teams from the 2016 relay race. (Image: Sophia Bennett/CERN) With a record participation of 128 teams and 768 runners, this year’s CERN Relay Race took place on 19 May on the Meyrin site. The teams were mainly composed of CERN staff or contractors working on the CERN site.  A few external teams took also part in the race. Times ranged from 10 min 19 s to over 18 min. The Running Club website now has both the results, and the photos from race day. The CERN Relay Race is jointly organised every year by the CERN Running Club and the Staff Association. It is a tradition that is appreciated by many as a team building, rather than a competitive event. The CERN Running Club wishes to thank all runners and all volunteers for making this event a success.

  10. Staged-Fault Testing of Distance Protection Relay Settings

    Science.gov (United States)

    Havelka, J.; Malarić, R.; Frlan, K.

    2012-01-01

    In order to analyze the operation of the protection system during induced fault testing in the Croatian power system, a simulation using the CAPE software has been performed. The CAPE software (Computer-Aided Protection Engineering) is expert software intended primarily for relay protection engineers, which calculates current and voltage values during faults in the power system, so that relay protection devices can be properly set up. Once the accuracy of the simulation model had been confirmed, a series of simulations were performed in order to obtain the optimal fault location to test the protection system. The simulation results were used to specify the test sequence definitions for the end-to-end relay testing using advanced testing equipment with GPS synchronization for secondary injection in protection schemes based on communication. The objective of the end-to-end testing was to perform field validation of the protection settings, including verification of the circuit breaker operation, telecommunication channel time and the effectiveness of the relay algorithms. Once the end-to-end secondary injection testing had been completed, the induced fault testing was performed with three-end lines loaded and in service. This paper describes and analyses the test procedure, consisting of CAPE simulations, end-to-end test with advanced secondary equipment and staged-fault test of a three-end power line in the Croatian transmission system.

  11. Four-Way Relaying in Wireless Cellular Systems

    DEFF Research Database (Denmark)

    Liu, Huaping; Popovski, Petar; De Carvalho, Elisabeth; Zhao, Yuping; Sun, Fan

    2013-01-01

    Two-way relaying in wireless systems has initiated a large research effort during the past few years. Nevertheless, it represents only a specific traffic pattern and it is of interest to investigate other traffic patterns where such a simultaneous processing of information flows can bring...

  12. 76 FR 72124 - Internet-Based Telecommunications Relay Service Numbering

    Science.gov (United States)

    2011-11-22

    ... at 76 FR 59511, September 27, 2011. If you have any comments on the burden estimates listed below, or..., published at 76 FR 59551, September 27, 2011, adopting final rules--containing information collection...] Internet-Based Telecommunications Relay Service Numbering AGENCY: Federal Communications Commission....

  13. 77 FR 1039 - Internet-Based Telecommunications Relay Service Numbering

    Science.gov (United States)

    2012-01-09

    ... Service Numbering, published at 76 FR 59551, September 27, 2011, in WC Docket No. 10-191, and published... COMMISSION 47 CFR Part 64 Internet-Based Telecommunications Relay Service Numbering AGENCY: Federal... rules that govern access to toll-free numbers by users of Internet- based Telecommunications...

  14. Combinatorial chemistry

    DEFF Research Database (Denmark)

    Nielsen, John

    1994-01-01

    An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds.......An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds....

  15. Positronium chemistry

    CERN Document Server

    Green, James

    1964-01-01

    Positronium Chemistry focuses on the methodologies, reactions, processes, and transformations involved in positronium chemistry. The publication first offers information on positrons and positronium and experimental methods, including mesonic atoms, angular correlation measurements, annihilation spectra, and statistical errors in delayed coincidence measurements. The text then ponders on positrons in gases and solids. The manuscript takes a look at the theoretical chemistry of positronium and positronium chemistry in gases. Topics include quenching, annihilation spectrum, delayed coincidence

  16. Line Differential Protection Scheme Modelling for Underground 420 kV Cable Systems, EMTDC/PSCAD Relays Modelling

    DEFF Research Database (Denmark)

    Bak, Claus Leth; Sztykiel, Michal; Dollerup, Sebastian

    2011-01-01

    Based on the analysis of a specific relay model and an HVAC (High Voltage Alternating Current) cable system, a new approach to EMTDC/PSCAD modelling of protective relays is presented. Such approach allows creating complex and accurate relay models derived from the original algorithms. Relay model......-simulated and real world generated current signals connected to the relay.......Based on the analysis of a specific relay model and an HVAC (High Voltage Alternating Current) cable system, a new approach to EMTDC/PSCAD modelling of protective relays is presented. Such approach allows creating complex and accurate relay models derived from the original algorithms. Relay models...... can be applied with various systems, allowing obtaining the most optimal configuration of the protective relaying. The present paper describes modelling methodology on the basis of Siemens SIPROTEC 4 7SD522/610. Relay model was verified experimentally with its real equivalent by both EMTP...

  17. Spatial organisation and biomass development after relaying of mussel seed

    Science.gov (United States)

    Capelle, Jacob J.; Wijsman, Jeroen W. M.; Schellekens, Tim; van Stralen, Marnix R.; Herman, Peter M. J.; Smaal, Aad C.

    2014-01-01

    It is not known whether and by what factors spatial heterogeneity in mussels (Mytilus edulis L.) affects mussel production in human-created mussel beds. In a field experiment, the same number of mussels was relayed on four different areas within plots of the same size, resulting in four treatments with different mussel densities. Density, individual weight and spatial structure of mussels were followed per treatment. The uniformly placed mussels on different areas redistributed into new patches, but mussels did not spread out over a larger area. Initial mussel density affected redistribution and mussel survival. At high densities mussels redistributed into a uniform matrix or in a few larger patches, that showed larger losses than at low densities, where mussels redistributed into a high number of patches. Growth rate and condition index of the mussels did not differ between treatments and no relation was found between treatment and number of foraging shore crabs, which was the major predator of mussels in this experiment. We hypothesise that the relation between initial mussel density and mussel loss after relaying is associated with redistribution, with less competition for space when mussels are positioned at the edge of a mussel patch. The very high mussel losses that we observed in the experiment within four weeks after relaying were the major factor in biomass development. Mussel bed formation concerns mussel growers and managers involved in natural mussel bed restoration. Initial mussel survival determines the success of these activities. The present study shows the effects of mussel relaying on spatial redistribution for the first time under field conditions, and underlines the importance of edge effects in understanding mussel loss in redistribution. Mussel survival after relaying will be higher when the mussels are distributed homogeneously and in relatively low density.

  18. 77 FR 43538 - Misuse of Internet Protocol (IP) Relay Service; Telecommunications Relay Services and Speech-to...

    Science.gov (United States)

    2012-07-25

    ... Relay Service Program, CG Docket No. 10-51, Second Report and Order, FCC 11-118; published at 76 FR 47469, August 5, 2011 and at 76 FR 47476, August 5, 2011 (iTRS Certification Order) (defining iTRS to... Notice of Proposed Rulemaking, FCC 06-58; published at 71 FR 31131, 2006 (2006 FNPRM). The...

  19. Resource allocation using time division multiple access over wireless relay networks

    Institute of Scientific and Technical Information of China (English)

    DAI Qin-yun; RONG Lu; HU Hong-lin; SU Gang

    2008-01-01

    This article considers a wireless network consisting of multiple sources that communicate with the corresponding destination utilizing a single half-duplex relay, whereas, the sources use the relay opportunistically. By integrating the information theory with the concept of effective capacity, this article proposes a dynamic time allocation strategy over the wireless relay network that aims at maximizing the relay network throughput, subject to a given delay quality of service (QoS) constraint, where time division multiple access (TDMA) is applied in the relay network. The simulation results show that the proposed allocation strategy can significantly improve the effective capacity as compared to the traditional equal time allocation strategy.

  20. Relay-assited transmission and radio resource management for wireless networks

    OpenAIRE

    Agustín de Dios, Adrián

    2008-01-01

    La transmisión asistida por relay o transmisión cooperativa es una nueva técnica de diversidad espacial donde aparece un elemento nuevo (un relay o un usuario cooperativo) en la tradicional transmisión punto a punto (fuente a destino). Ahora en la comunicación intervienen tres enlaces: fuente-relay, relay-destino y fuente-destino. El relay, además de asistir a la fuente en la transmisión de un mensaje, permite combatir las degradaciones que puede sufrir el canal como el shadowing y el pathlos...

  1. Role of acidic chemistries in steam treatment of aluminium alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    2015-01-01

    The effect of acidic chemistry on the accelerated growth of oxide on aluminium alloys Peraluman 706TM and AA6060 under exposure to high temperature steam was investigated. Studied chemistries were based on citrates and phosphates. Results showed that the presence of citrate and phosphate anions...

  2. Asymptotic analysis for Nakagami-m fading channels with relay selection

    KAUST Repository

    Zhong, Caijun

    2011-06-01

    In this paper, we analyze the asymptotic outage probability performance of both decode-and-forward (DF) and amplify-and-forward (AF) relaying systems using partial relay selection and the "best" relay selection schemes for Nakagami-m fading channels. We derive their respective outage probability expressions in the asymptotic high signal-to-noise ratio (SNR) regime, from which the diversity order and coding gain are analyzed. In addition, we investigate the impact of power allocation between the source and relay terminals and derive the diversity-multiplexing tradeoff (DMT) for these relay selection systems. The theoretical findings suggest that partial relay selection can improve the diversity of the system and can achieve the same DMT as the "best" relay selection scheme under certain conditions. © 2011 IEEE.

  3. On the capacity of multiple cognitive links through common relay under spectrum-sharing constraints

    KAUST Repository

    Yang, Yuli

    2011-06-01

    In this paper, we consider an underlay cognitive relaying network consisting of multiple secondary users and introduce a cooperative transmission protocol using a common relay to help with the communications between all secondary source-destination pairs for higher throughput and lower realization complexity. A whole relay-assisted transmission procedure is composed of multiple access phase and broadcast phase, where the relay is equipped with multiple antennas, and the secondary sources and destinations are single-antenna nodes. Considering the spectrum-sharing constraints on the secondary sources and the relay, we analyze the capacity behaviors of the underlay cognitive relaying network under study. The corresponding numerical results provide a convenient tool for the presented network design and substantiate a distinguishing feature of introduced design in that multiple secondary users\\' communications do not rely on multiple relays, hence allowing for a more efficient use of the radio resources. © 2011 IEEE.

  4. G. Marconi: A Data Relay Satellite for Mars Communications

    Science.gov (United States)

    Dionisio, C.; Marcozzi, M.; Landriani, C.

    2002-01-01

    Mars has always been a source of intrigue and fascination. Recent scientific discoveries have stimulated this longstanding interest, leading to a renaissance in Mars exploration. Future missions to Mars will be capable of long-distance surface mobility, hyperspectral imaging, subsurface exploration, and even life-detection. Manned missions and, eventually, colonies may follow. No mission to the Red Planet stands alone. New scientific and technological knowledge is passed on from one mission to the next, not only improving the journey into space, but also providing benefits here on Earth. The Mars Relay Network, an international constellation of Mars orbiters with relay radios, directly supports other Mars missions by relaying communications between robotic vehicles at Mars and ground stations on Earth. The ability of robotic visitors from Earth to explore Mars will take a gigantic leap forward in 2007 with the launch of the Guglielmo Marconi Orbiter (GMO), the first spacecraft primarily dedicated to providing communication relay, navigation and timing services at Mars. GMO will be the preeminent node of the Mars Relay Network. GMO will relay communications between Earth and robotic vehicles near Mars. GMO will also provide navigation services to spacecraft approaching Mars. GMO will receive transmissions from ground stations on Earth at X-band and will transmit to ground stations on Earth at X- and Ka-bands. GMO will transmit to robotic vehicles at Mars at UHF and receive from these vehicles at UHF and X-band. GMO's baseline 4450 km circular orbit provides complete coverage of the planet for telecommunication and navigation support. GMO will arrive at Mars in mid-2008, just before the NetLander and Mars Scout missions that will be its first users. GMO is designed for a nominal operating lifetime of 10 years and will support nominal commanding and data acquisition, as well as mission critical events such as Mars Orbit Insertion, Entry, Descent and Landing, and Mars

  5. Pu Anion Exchange Process Intensification

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-08

    This project seeks to improve the efficiency of the plutonium anion-exchange process for purifying Pu through the development of alternate ion-exchange media. The objective of the project in FY15 was to develop and test a porous foam monolith material that could serve as a replacement for the current anion-exchange resin, Reillex® HPQ, used at the Savannah River Site (SRS) for purifying Pu. The new material provides advantages in efficiency over the current resin by the elimination of diffusive mass transport through large granular resin beads. By replacing the large resin beads with a porous foam there is much more efficient contact between the Pu solution and the anion-exchange sites present on the material. Several samples of a polystyrene based foam grafted with poly(4-vinylpyridine) were prepared and the Pu sorption was tested in batch contact tests.

  6. Molecular Anions in Protostars, Prestellar Cores and Dark Clouds

    Science.gov (United States)

    Cordiner, Martin; Charnley, Steven; Buckle, Jane; Wash, Catherine; Millar, Tom

    2011-01-01

    From our recent survey work using the Green Bank Telescope, microwave emission lines from the hydrocarbon anion C6H(-) and its parent neutral C6H have been detected in six new sources. Using HC3N = 10(exp -9) emission maps, we targeted the most carbon-chain-rich sources for our anion survey, which included the low-mass Class 0 protostar L1251A-IRS3, the prestellar cores L1389-SMM1 and L1512, and the interstellar clouds Ll172A, TMC-1C and L1495B. Derived [C6H(-)]/[C6H] anion-to-neutral ratios are approximately 1-10. The greatest C6H(-) column densities are found in the quiescent clouds TMC-1C and L1495B, but the anion-to-neutral ratios are greatest in the prestellar cores and protostars. These results are interpreted in terms of the physical and chemical properties of the sources, and the implications for molecular cloud chemistry are discussed.

  7. Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species

    OpenAIRE

    COMES NAVARRO, MARÍA

    2016-01-01

    [EN] The doctoral thesis presented under the title "Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species" has had as its main objective the synthesis and characterization of organic-inorganic hybrid materials based on the combination of the principles of Supramolecular Chemistry and Materials Science. Recent studies confirm that cooperation between these two areas of Chemistry allow the simulation of what natural living beings have been doing for m...

  8. A Novel Multipoint Relay based Secure Routing in MANET

    Directory of Open Access Journals (Sweden)

    Himadri Nath Saha

    2012-12-01

    Full Text Available Security in routing is a challenging issue in mobile ad-hoc (MANET network because of itsopen nature, infrastructure less property, mobility and energy constraints. Messages typically roam inmulti-hopped fashion and nodes may be powered by limited energy source and with limited physicalsecurity. So we proposed a new scheme which is significantly different from others available schemes toprovide security during routing in mobile ad hoc networks. In this paper, our proposed scheme, SecureMultipoint Relay based Routing in MANET (SMRR provides routing based on trust, which is an integervalue that helps to select Multipoint Relay (administrator inside the network for routing. We have alsoimplemented the message confidentiality and integrity in our proposed scheme. Our simulation resultsshow the robustness, reliability and trustworthiness of our scheme.

  9. Phase switching in Hindmarsh-Rose relay neurons

    Science.gov (United States)

    Thounaojam, Umeshkanta Singh; Sharma, Pooja Rani; Shrimali, Manish Dev

    2016-02-01

    A system of Hindmarsh-Rose relay neurons with time delay coupling is considered in which the relay (central) neuron has an additional feedback term that represents the interaction activity with a local environment. The strength of environmental coupling with the central neuron plays an important role in inducing synchronization and de-synchronization between the outer neurons. The strength of feedback developed from the environmental coupling has created a gradual quenching in the oscillations of the central neuron. At a higher feedback coupling strength, oscillation of the central neuron is suppressed drastically and a transition from a regime of synchronization to out-of-phase synchronization take place between the oscillations of the two outer neurons.

  10. Condensation and jumping relay of droplets on lotus leaf

    CERN Document Server

    Lv, Cunjing; Yao, Zhaohui; Song, Yu; Zhang, Xiwen; He, Feng

    2013-01-01

    Dynamic behavior of micro water droplet condensed on a lotus leaf with two-tier roughness is studied. Under laboratory environment, the contact angle of the micro droplet on single micro papilla increases smoothly from 80 deg to 160 deg during the growth of condensed water. The best-known "self-clean" phenomenon, will be lost. A striking observation is the out-of-plane jumping relay of condensed droplets triggered by falling droplets, as well as its sustained speed obtained in continuous jumping relays, enhance the automatic removal of dropwise condensation without the help from any external force. The surface tension energy dissipation is the main reason controlling the critical size of jumping droplet and its onset velocity of rebounding.

  11. Design and Implementation of O/C relay using Microprocessor

    Directory of Open Access Journals (Sweden)

    Dr.Abdul-Sattar H. Jasim

    2012-03-01

    Full Text Available This work presents the design and implementation of a versatile digital overcurrent (O/C relay using a single microprocessor. The relay is implemented by a combination of a look-up table and a counter. The software development and hardware testing are done using a microcomputer module based on a 8-bit microprocessor. The digital processing of measured currents enables a separate setting of operating values selection of all types of inverse or constant time characteristics overcurrent protection. This protection provides reasonably fast tripping, even at terminal close to the power source were the most serve faults can occur excluding the transient condition. So this method has an excellent compromise between accuracy hardware and speed

  12. Performance Analysis of Hybrid Relay Selection in Cooperative Wireless Systems

    CERN Document Server

    Liu, Tianxi; Li, Yonghui; Huo, Qiang; Jiao, Bingli

    2011-01-01

    The hybrid relay selection (HRS) scheme, which adaptively chooses amplify-and-forward (AF) and decode-and-forward (DF) protocols, is very effective to achieve robust performance in wireless networks. This paper analyzes the frame error rate (FER) of the HRS scheme in general cooperative wireless networks without and with utilizing error control coding at the source node. We first develop an improved signal-to-noise ratio (SNR) threshold-based FER approximation model. Then, we derive an analytical average FER expression as well as an asymptotic expression at high SNR for the HRS scheme and generalize to other relaying schemes. Simulation results are in excellent agreement with the theoretical analysis, which validates the derived FER expressions.

  13. Switched diversity strategies for dual-hop relaying systems

    KAUST Repository

    Gaaloul, Fakhreddine

    2011-04-29

    This paper investigates the effect of different switched diversity configurations on the implementation complexity and achieved performance of dual-hop amplify-and-forward (AF) relaying networks. A low-complexity model of the relay station is adopted, wherein single-input single-output antenna configuration is employed. Each of the transmitter and the receiver however employs multiple antennas to improve the overall link performance. Single-phase and two-phase based receive switching strategies are investigated assuming optimum first hop signal-to-noise ratio (SNR). Moreover, the simple scheme in which the switched diversity is applied independently over the two hops is studied using tight upper bounds. Thorough performance comparisons and switching thresholds optimization for the aforementioned strategies are presented. Simulation results are also provided to validate the mathematical development and to verify the numerical computations.

  14. The Case for Deep Space Telecommunications Relay Stations

    Science.gov (United States)

    Chandler, Charles W.; Miranda, Felix A. (Technical Monitor)

    2004-01-01

    Each future mission to Jupiter and beyond must carry the traditional suite of telecommunications systems for command and control and for mission data transmission to earth. The telecommunications hardware includes the large antenna and the high-power transmitters that enable the communications link. Yet future spacecraft will be scaled down from the hallmark missions of Galileo and Cassini to Jupiter and Saturn, respectively. This implies that a higher percentage of the spacecraft weight and power must be dedicated to telecommunications system. The following analysis quantifies this impact to future missions and then explores the merits of an alternative approach using deep space relay stations for the link back to earth. It will be demonstrated that a telecommunications relay satellite would reduce S/C telecommunications weight and power sufficiently to add one to two more instruments.

  15. Zone 3 Relay Blocking Scheme to Prevent Cascaded Events

    Institute of Scientific and Technical Information of China (English)

    LIM Seong-Il

    2008-01-01

    Defense systems are needed to prevent catastrophic failures of a power grid due to cas- caded events. Cascaded events can be attributed to improper operations of protective relays. The most challenging problem for the design and implementation of a defense system is the perform- ance in accuracy and speed in a real time environment. Protective devices are normally designed to operate fast in order to isolate the fault(s). This paper proposes a new methodology to distin- guish line overloads from actual faults for distance relays. In order to distinguish between line flow transfers from a line outage and an actual fault, the line outage distribution factor (LODF) and gen-eration shift factor (GSF) based power flow estimation method, and a secure peer to peer (P2P) communication structure are adopted. Computer simulations of cascaded events for a 6-bus sys- tem and the Korean power grid have been performed to establish the feasibility of the proposed scheme.

  16. The many ways of making anionic clays

    Indian Academy of Sciences (India)

    Michael Rajamathi; Grace S Thomas; P Vishnu Kamath

    2001-10-01

    Together with hydrotalcite-like layered double hydroxides, bivalent and trivalent metal hydroxides and their hydroxy salts are actually anionic clays consisting of positively charged hydroxide layers with anions intercalated in the interlayer region. The anionic clays exhibit anion sorption, anion diffusion and exchange properties together with surface basicity making them materials of importance for many modern applications. In this article, we discuss many different ways of making anionic clays and compare and contrast the rich diversity of this class of materials with the better-known cationic clays.

  17. Securing applications in personal computers: the relay race approach.

    OpenAIRE

    Wright, James Michael

    1991-01-01

    Approved for public release; distribution is unlimited This Thesis reviews the increasing need for security in a personal computer (PC) environment and proposes a new approach for securing PC applications at the application layer. The Relay Race Approach extends two standard approaches : data encryption and password access control at the main program level, to the subprogram level by the use of a special parameter, the "Baton" . The applicability of this approach is de...

  18. Coded Cooperation for Multiway Relaying in Wireless Sensor Networks †

    OpenAIRE

    Zhongwei Si; Junyang Ma; Ragnar Thobaben

    2015-01-01

    Wireless sensor networks have been considered as an enabling technology for constructing smart cities. One important feature of wireless sensor networks is that the sensor nodes collaborate in some manner for communications. In this manuscript, we focus on the model of multiway relaying with full data exchange where each user wants to transmit and receive data to and from all other users in the network. We derive the capacity region for this specific model and propose a coding strategy throug...

  19. Nested Polar Codes for Wiretap and Relay Channels

    CERN Document Server

    Andersson, Mattias; Thobaben, Ragnar; Kliewer, Joerg; Skoglund, Mikael

    2010-01-01

    We show that polar codes asymptotically achieve the whole capacity-equivocation region for the wiretap channel when the wiretapper's channel is degraded with respect to the main channel, and the weak secrecy notion is used. Our coding scheme also achieves the capacity of the physically degraded receiver-orthogonal relay channel. We show simulation results for moderate block length for the binary erasure wiretap channel, comparing polar codes and two edge type LDPC codes.

  20. Restrictions on running IRC (Internet Relay Chat) at CERN

    CERN Document Server

    2005-01-01

    Due to the large number of computer security incidents at CERN where intruders have used IRC (Internet Relay Chat) software to control computers, IRC connections will be blocked in the CERN firewall from 1st February 2005. Personal use of IRC software is not permitted at CERN. Further details of the restrictions on both personal and professional use of IRC are documented at http://cern.ch/security/IRC.

  1. Privacy Preserving Quantum Anonymous Transmission via Entanglement Relay

    OpenAIRE

    Wei Yang; Liusheng Huang; Fang Song

    2016-01-01

    Anonymous transmission is an interesting and crucial issue in computer communication area, which plays a supplementary role to data privacy. In this paper, we put forward a privacy preserving quantum anonymous transmission protocol based on entanglement relay, which constructs anonymous entanglement from EPR pairs instead of multi-particle entangled state, e.g. GHZ state. Our protocol achieves both sender anonymity and receiver anonymity against an active adversary and tolerates any number of...

  2. Spatial organisation and biomass development after relaying of mussel seed

    OpenAIRE

    Capelle, J.J.; Wijsman, J.W.M.; Schellekens, T.; van Stralen, M.R.; Herman, P.M.J.; Smaal, A. C.

    2014-01-01

    It is not known whether and by what factors spatial heterogeneity in mussels (Mytilus edulis L.) affects mussel production in human-created mussel beds. In a field experiment, the same number of mussels was relayed on four different areas within plots of the same size, resulting in four treatments with different mussel densities. Density, individual weight and spatial structure of mussels were followed per treatment. The uniformly placed mussels on different areas redistributed into new patch...

  3. Opportunistic Relaying in Wireless Body Area Networks: Coexistence Performance

    OpenAIRE

    Dong, Jie; SMITH, DAVID

    2012-01-01

    In this paper, a cooperative two-hop communication scheme, together with opportunistic relaying (OR), is applied within a mobile wireless body area network (WBAN). Its effectiveness in interference mitigation is investigated in a scenario where there are multiple closely-located networks. Due to a typical WBAN's nature, no coordination is used among different WBANs. A suitable time-division-multiple-access (TDMA) is adopted as both an intra-network and also an inter-network access scheme. Ext...

  4. Scalable DeNoise-and-Forward in Bidirectional Relay Networks

    DEFF Research Database (Denmark)

    Sørensen, Jesper Hemming; Krigslund, Rasmus; Popovski, Petar;

    2010-01-01

    in order to save transmissions. To ensure decodability at the end-nodes, a priori information about the content of the combined packets must be available. This is gathered during the initial transmissions to the relay. The trade-off between decodability and number of necessary transmissions is...... analysed and simulations show, that S-DNF is able to provide a better trade-off than traditional schemes at high SNR....

  5. Mems Electromagnetic Micro Relays Overview and Design Considerations

    OpenAIRE

    Zuraini Dahari, Thurai Vinay and Dinesh Sood

    2012-01-01

    Miniature electromagnetic relay matrices capable of switching currents up to one ampere range are  widely used in commercial applications such as instrumentation and telecommunication. Traditionally these devices have been fabricated from a number of discrete components, however in recent years the emergence of Micro Electro Mechanical System (MEMS) technology has opened up the possibility for batch fabrication of microrelays at much reduced unit cost. While several electromagnetic micro...

  6. A quantum relay chip based on telecommunication integrated optics technology

    OpenAIRE

    Martin, Anthony; Alibart, Olivier; Ostrowsky, Daniel Barry; De Micheli, Marc; Tanzilli, Sébastien

    2011-01-01

    We investigate an integrated optical circuit on lithium niobate designed to implement the teleportation-based quantum relay scheme for one-way quantum communication at a telecom wavelength. Such an advanced quantum circuit merges for the first time, both optical-optical and electro-optical non-linear functions necessary to implement the desired on-chip single qubit teleportation. On one hand, spontaneous parametric down-conversion is used to produce entangled photon-pairs. On the other hand, ...

  7. My Torch Relay Run——Canberra,24 April2008

    Institute of Scientific and Technical Information of China (English)

    Carol Keil

    2008-01-01

    <正>In October last year I was asked if I was happy to be nominated as a potential runner in the Beijing Olympics torch relay. I could hardly believe my ears and very excitedly said "yes!" When I was subsequently advised that I had been selected to be one of the five BOCOG runners and indeed one of only 80 Australian torch bearers I felt greatly honoured and privileged.

  8. State redistribution as merging: introducing the coherent relay

    OpenAIRE

    Oppenheim, Jonathan

    2008-01-01

    State redistribution allows one party to optimally send part of her state to another party. Here we show that this can be derived simply from two applications of coherent state-merging. This provides a protocol whereby a middle party acts as a relay station to help another party more efficiently transfer quantum states. This also gives a protocol for state splitting and the reverse Shannon theorem (assisted or unassisted by side information), and allows one to use less classical communication...

  9. Social Chemistry

    OpenAIRE

    Lichtfouse, Eric; Schwarzbauer, Jan; Robert, Didier

    2012-01-01

    International audience This article is both an essay to propose social chemistry as a new scientific discipline, and a preface of the book Environmental Chemistry for a Sustainable World. Environmental chemistry is a fast emerging discipline aiming at the understanding the fate of pollutants in ecosystems and at designing novel processes that are safe for ecosystems. Past pollution should be cleaned, future pollution should be predicted and avoided (Lichtfouse et al., 2005a). Such advices ...

  10. Computational chemistry

    OpenAIRE

    Truhlar, Donald G.; McKoy, Vincent

    2000-01-01

    Computational chemistry has come of age. With significant strides in computer hardware and software over the last few decades, computational chemistry has achieved full partnership with theory and experiment as a tool for understanding and predicting the behavior of a broad range of chemical, physical, and biological phenomena. The Nobel Prize award to John Pople and Walter Kohn in 1998 highlighted the importance of these advances in computational chemistry. With massively parallel computers ...

  11. Bioinorganic Chemistry

    OpenAIRE

    Bertini, Ivano; Gray, Harry B.; Lippard, Stephen J.; Valentine, Joan Selverstone

    1994-01-01

    This book covers material that could be included in a one-quarter or one-semester course in bioinorganic chemistry for graduate students and advanced undergraduate students in chemistry or biochemistry. We believe that such a course should provide students with the background required to follow the research literature in the field. The topics were chosen to represent those areas of bioinorganic chemistry that are mature enough for textbook presentation. Although each chapter presents material...

  12. Preparation and chromatographic performance of polymer-based anion exchangers for ion chromatography: A review.

    Science.gov (United States)

    Zatirakha, A V; Smolenkov, A D; Shpigun, O A

    2016-01-21

    In the last decade the developments in the field of ion chromatography (IC) were aimed at increasing the efficiency, sensitivity and rapidity of analysis, as well as on improving separation selectivity. Since selectivity and efficiency to the large extent depend on the surface chemistry of the stationary phase, the development of novel anion exchangers remains one of the priority tasks in modern IC. The exact chemistry of commercially available resins is not known and not many literature data devoted to the procedures of preparing anion exchangers for IC have become available in the last 10-15 years. However, the knowledge about the surface chemistry of anion exchangers can provide understanding of the trends in selectivity and efficiency changes, as well as help with the choice of the stationary phase type suitable for solving a particular analytical task. The current review is devoted to the methods of preparing anion exchangers based on polystyrene-divinylbenzene (PS-DVB) and ethylvinylbenzene-divinylbenzene (EVB-DVB) for IC of inorganic and small organic anions and is aimed at demonstrating the improvement of their performance over the years, which was brought by the development of the new types of stationary phase architecture. PMID:26724761

  13. Technetium chemistry

    International Nuclear Information System (INIS)

    Technetium chemistry is a young and developing field. Despite the limited knowledge of its chemistry, technetium is the workhorse for nuclear medicine. Technetium is also a significant environmental concern because it is formed as a byproduct of nuclear weapons production and fission-power generators. Development of new technetium radio-pharmaceuticals and effective environmental control depends strongly upon knowledge of basic technetium chemistry. The authors performed research into the basic coordination and organometallic chemistry of technetium and used this knowledge to address nuclear medicine and environmental applications. This is the final report of a three-year Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL)

  14. ATLAS participation to the 36th Annual CERN Relay Race

    CERN Multimedia

    Gagnon, P.

    On May 17, the Annual CERN relay race took place for the 36th time. This is a fun relay race where a team of six runners runs around the CERN site in Meyrin, up and down many hills, to cover the following distances: the first runner runs 1000 m, the second and third runners cover 800 m each, the fourth and fifth runners each have 500 m and finally, the sixth runner covers the last 300 m all the way to the finish line. Each year, serious and occasionnal runners who take this opportunity to make it their only running moment of the year, give it their best to run the 3.9 km loop in times ranging from a mere 10:39.9 for the best team this year to 18:14.3 for the last of the 65 teams that completed the race. Nobody was wasting time at the starting line of the CERN Annual Relay Race. ATLAS was better represented than ever with a record of eight ATLAS teams participating in this race organized by the CERN running club. The names of the ATLAS participants, as well as the team official times are given in the t...

  15. Energy-Efficient Relaying over Multiple Slots with Causal CSI

    CERN Document Server

    Ho, Chin Keong; Sun, Sumei

    2012-01-01

    In many communication scenarios, such as in cellular systems, the energy cost is substantial and should be conserved, yet there is a growing need to support many real-time applications that require timely data delivery. To model such a scenario, in this paper we consider the problem of minimizing the expected sum energy of delivering a message of a given size from a source to a destination subject to a deadline constraint. A relay is present and can assist after it has decoded the message. Causal channel state information (CSI), in the form of present and past SNRs of all links, is available for determining the optimal power allocation for the source and relay. We obtain the optimal power allocation policy by dynamic programming and explore its structure. We also obtain conditions for which the minimum expected sum energy is bounded given a general channel distribution. In particular, we show that for Rayleigh and Rician fading channels, relaying is necessary for the minimum expected sum energy to be bounded....

  16. Cognitive relaying and power allocation under channel state uncertainties

    KAUST Repository

    Pandarakkottilil, Ubaidulla

    2013-04-01

    In this paper, we present robust joint relay precoder designs and transceiver power allocations for a cognitive radio network under imperfect channel state information (CSI). The secondary (or cognitive) network consists of a pair of single-antenna transceiver nodes and a non-regenerative two-way relay with multiple antennas which aids the communication process between the transceiver pair. The secondary nodes share the spectrum with a licensed primary user (PU) while guaranteeing that the interference to the PU receiver is maintained below a specified threshold. We consider two robust designs: the first is based on the minimization of the total transmit power of the secondary relay node required to provide the minimum quality of service, measured in terms of mean-square error (MSE) of the transceiver nodes, and the second is based on the minimization of the sum-MSE of the transceiver nodes. The robust designs are based on worst-case optimization and take into account known parameters of the error in the CSI to render the performance immune to the presence of errors in the CSI. Though the original problem is non-convex, we show that the proposed designs can be reformulated as tractable convex optimization problems that can be solved efficiently. We illustrate the performance of the proposed designs through some selected numerical simulations. © 2013 IEEE.

  17. Outage analysis for underlay cognitive networks using incremental regenerative relaying

    KAUST Repository

    Tourki, Kamel

    2013-02-01

    Cooperative relay technology has recently been introduced into cognitive radio (CR) networks to enhance the network capacity, scalability, and reliability of end-to-end communication. In this paper, we investigate an underlay cognitive network where the quality of service (QoS) of the secondary link is maintained by triggering an opportunistic regenerative relaying once it falls under an unacceptable level. Analysis is conducted for two schemes, referred to as the channel-state information (CSI)-based and fault-tolerant schemes, respectively, where different amounts of CSI were considered. We first provide the exact cumulative distribution function (cdf) of the received signal-to-noise ratio (SNR) over each hop with colocated relays. Then, the cdf\\'s are used to determine a very accurate closed-form expression for the outage probability for a transmission rate $R$. In a high-SNR region, a floor of the secondary outage probability occurs, and we derive its corresponding expression. We validate our analysis by showing that the simulation results coincide with our analytical results in Rayleigh fading channels. © 1967-2012 IEEE.

  18. MALDI-TOF MS analysis of the self-termination products in the anionic methyl methacrylate/tert-butyl acrylate block copolymerization

    Czech Academy of Sciences Publication Activity Database

    Vlček, Petr; Čadová, Eva; Horský, Jiří; Janata, Miroslav

    2015-01-01

    Roč. 72, č. 9 (2015), s. 2227-2239. ISSN 0170-0839 Institutional support: RVO:61389013 Keywords : anionic polymerization * acrylates * block copolymer Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.438, year: 2014

  19. Line Differential Protection Scheme Modelling for Underground 420 kV Cable Systems:EMTDC/PSCAD Relays Modelling

    OpenAIRE

    Sztykiel, Michal; Bak, Claus Leth; Wiechowski, Wojciech; Dollerup, Sebastian

    2010-01-01

    Based on the analysis of a specific relay model and an HVAC (High Voltage Alternating Current) cable system, a new approach to EMTDC/PSCAD modelling of protective relays is presented. Such approach allows to create complex and accurate relay models derived from the original algorithms. Relay models can be applied with various systems, allowing to obtain the most optimal configuration of the protective relaying. The present paper describes modelling methodology on the basis of Siemens SIPROTEC...

  20. Anion binding in biological systems

    Energy Technology Data Exchange (ETDEWEB)

    Feiters, Martin C [Department of Organic Chemistry, Institute for Molecules and Materials, Faculty of Science, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen (Netherlands); Meyer-Klaucke, Wolfram [EMBL Hamburg Outstation at DESY, Notkestrasse 85, D-22607 Hamburg (Germany); Kostenko, Alexander V; Soldatov, Alexander V [Faculty of Physics, Southern Federal University, Sorge 5, Rostov-na-Donu, 344090 (Russian Federation); Leblanc, Catherine; Michel, Gurvan; Potin, Philippe [Centre National de la Recherche Scientifique and Universite Pierre et Marie Curie Paris-VI, Station Biologique de Roscoff, Place Georges Teissier, BP 74, F-29682 Roscoff cedex, Bretagne (France); Kuepper, Frithjof C [Scottish Association for Marine Science, Dunstaffnage Marine Laboratory, Oban, Argyll PA37 1QA, Scotland (United Kingdom); Hollenstein, Kaspar; Locher, Kaspar P [Institute of Molecular Biology and Biophysics, ETH Zuerich, Schafmattstrasse 20, Zuerich, 8093 (Switzerland); Bevers, Loes E; Hagedoorn, Peter-Leon; Hagen, Wilfred R, E-mail: m.feiters@science.ru.n [Department of Biotechnology, Delft University of Technology, Julianalaan 67, 2628 BC Delft (Netherlands)

    2009-11-15

    We compare aspects of biological X-ray absorption spectroscopy (XAS) studies of cations and anions, and report on some examples of anion binding in biological systems. Brown algae such as Laminaria digitata (oarweed) are effective accumulators of I from seawater, with tissue concentrations exceeding 50 mM, and the vanadate-containing enzyme haloperoxidase is implicated in halide accumulation. We have studied the chemical state of iodine and its biological role in Laminaria at the I K edge, and bromoperoxidase from Ascophyllum nodosum (knotted wrack) at the Br K edge. Mo is essential for many forms of life; W only for certain archaea, such as Archaeoglobus fulgidus and the hyperthermophilic archaeon Pyrococcus furiosus, and some bacteria. The metals are bound and transported as their oxo-anions, molybdate and tungstate, which are similar in size. The transport protein WtpA from P. furiosus binds tungstate more strongly than molybdate, and is related in sequence to Archaeoglobus fulgidus ModA, of which a crystal structure is known. We have measured A. fulgidus ModA with tungstate at the W L{sub 3} (2p{sub 3/2}) edge, and compared the results with the refined crystal structure. XAS studies of anion binding are feasible even if only weak interactions are present, are biologically relevant, and give new insights in the spectroscopy.

  1. Anion binding in biological systems

    Science.gov (United States)

    Feiters, Martin C.; Meyer-Klaucke, Wolfram; Kostenko, Alexander V.; Soldatov, Alexander V.; Leblanc, Catherine; Michel, Gurvan; Potin, Philippe; Küpper, Frithjof C.; Hollenstein, Kaspar; Locher, Kaspar P.; Bevers, Loes E.; Hagedoorn, Peter-Leon; Hagen, Wilfred R.

    2009-11-01

    We compare aspects of biological X-ray absorption spectroscopy (XAS) studies of cations and anions, and report on some examples of anion binding in biological systems. Brown algae such as Laminaria digitata (oarweed) are effective accumulators of I from seawater, with tissue concentrations exceeding 50 mM, and the vanadate-containing enzyme haloperoxidase is implicated in halide accumulation. We have studied the chemical state of iodine and its biological role in Laminaria at the I K edge, and bromoperoxidase from Ascophyllum nodosum (knotted wrack) at the Br K edge. Mo is essential for many forms of life; W only for certain archaea, such as Archaeoglobus fulgidus and the hyperthermophilic archaeon Pyrococcus furiosus, and some bacteria. The metals are bound and transported as their oxo-anions, molybdate and tungstate, which are similar in size. The transport protein WtpA from P. furiosus binds tungstate more strongly than molybdate, and is related in sequence to Archaeoglobus fulgidus ModA, of which a crystal structure is known. We have measured A. fulgidus ModA with tungstate at the W L3 (2p3/2) edge, and compared the results with the refined crystal structure. XAS studies of anion binding are feasible even if only weak interactions are present, are biologically relevant, and give new insights in the spectroscopy.

  2. IMPROVING OF ANION EXCHANGERES REGENERATION

    Directory of Open Access Journals (Sweden)

    Muzher M. Ibrahim

    2013-05-01

    Full Text Available Inthis study, Different basis [NaOH and KOH] of variable concentration are usedto reactivate Anion exchangers employing different schemes .The Laboratoryresults showed large improvement in efficiency of these exchangers ( i.eoperating time was increased from 12 to 42 hours .The results of this work showed that the environmentalload (waste water can be reduced greatly when using the proposed regenerationscheme .

  3. The diversity-multiplexing tradeoff of the symmetric MIMO half-duplex relay channel

    CERN Document Server

    Karmakar, Sanjay

    2010-01-01

    The diversity-multiplexing tradeoff (DMT) is obtained for the symmetric MIMO half-duplex (HD) relay channel where the source and the destination have $n$ antennas each and the relay node has $m$ antennas (hereafter, such a channel is referred to as an $(n,m)$-relay channel). The characterization of the DMT requires the joint eigenvalue distribution of three specially correlated central Wishart random matrices, which is derived using a related result in [1], [2]. The explicit characterization of the DMT, besides providing the theoretical benchmark for evaluating performance of practical cooperative protocols on this channel, reveals several interesting facts such as: a) the HD operation of the relay fundamentally limits relay channel performance in the sense that the DMT of the full-duplex (FD) relay channel can be strictly greater than that of the HD relay channel; b) an extra antenna at the relay node on a HD relay channel does not always improve the achievable diversity order, unlike that on an FD relay cha...

  4. Screening test of relays used under pressurized sulfur hexafluoride (SF6)

    International Nuclear Information System (INIS)

    Many measurement and control devices inside of a high voltage terminal of the JAEA-Tokai tandem accelerator are operated under pressurized sulfur hexafluoride gas (SF6) of 0.5 MPa. This screening test has been carried out to select a relay, which is usable under the pressurized SF6 for turn on and off a large current of the devices, from commercial relays used in the atmospheric condition. Four kinds of relays were tested: electromechanical relay (EMR), magnet contactor (MAG), solid-state relay (SSR) and hybrid relay (HYB). Temperature and appearance changes of the relay were collected as measurement items. In addition, a reason of contact trouble of the relays was considered from the results of qualitative elementary analysis and observation of the contact surface using the EDS (energy-dispersive X-ray spectroscopy) and the SEM (scanning electron microscope). As a result, the EMR and the MAG showed irregular contact in spite of input voltage and electric current had fed to an operational coil of the relay normally. It is caused by the sulfide or fluoride compounds, which were formed by chemical reaction between metals and sulfur or hydrogen fluoride due to dissociation of SF6 in electric arcs. On the other hand, the performance of the SSR and the HYB is better than the EMR and the MAG, and it was found that these relays are available in the pressurized SF6 of 0.5MPa in spite of the standard specification. (author)

  5. Information-guided transmission in decode-and-forward relaying systems: Spatial exploitation and throughput enhancement

    KAUST Repository

    Yang, Yuli

    2011-07-01

    In addressing the issue of achieving high throughput in half-duplex relay channels, we exploit a concept of information-guided transmission for the network consisting of a source node, a destination node, and multiple half-duplex relay nodes. For further benefiting from multiple relay nodes, the relay-selection patterns are defined as the arbitrary combinations of given relay nodes. By exploiting the difference among the spatial channels states, in each relay-help transmission additional information to be forwarded is mapped onto the index of the active relay-selection pattern besides the basic information mapped onto the traditional constellation, which is forwarded by the relay node(s) in the active relay-selection pattern, so as to enhance the relay throughtput. With iterative decoding, the destination node can achieve a robust detection by decoupling the signals forwarded in different ways. We investigate the proposed scheme considering "decode-and-forward" protocol and establish its achievable transmission rate. The analytical results on capacity behaviors prove the efficiency of the proposed scheme by showing that it achieves better capacity performance than the conventional scheme. © 2011 IEEE.

  6. Commercial grade item (CGI) dedication of MDR relays for nuclear safety related applications

    Science.gov (United States)

    Das, Ranjit K.; Julka, Anil; Modi, Govind

    1994-08-01

    MDR relays manufactured by Potter & Brumfield (P&B) have been used in various safety related applications in commercial nuclear power plants. These include emergency safety features (ESF) actuation systems, emergency core cooling systems (ECCS) actuation, and reactor protection systems. The MDR relays manufactured prior to May 1990 showed signs of generic failure due to corrosion and outgassing of coil varnish. P&B has made design changes to correct these problems in relays manufactured after May 1990. However, P&B does not manufacture the relays under any 10CFR50 Appendix B quality assurance (QA) program. They manufacture the relays under their commercial QA program and supply these as commercial grade items. This necessitates CGI Dedication of these relays for use in nuclear-safety-related applications. This paper presents a CGI dedication program that has been used to dedicate the MDR relays manufactured after been used to dedicate the MDR relays manufactured after May 1990. The program is in compliance with current Nuclear Regulatory Commission (NRC) and Electric Power Research Institute (EPRI) guidelines and applicable industry standards; it specifies the critical characteristics of the relays, provides the tests and analysis required to verify the critical characteristics, the acceptance criteria for the test results, performs source verification to quality P&B for its control of the critical characteristics, and provides documentation. The program provides reasonable assurance that the new MDR relays will perform their intended safety functions.

  7. Multihop Relay Techniques for Communication Range Extension in Near-Field Magnetic Induction Communication Systems

    Directory of Open Access Journals (Sweden)

    Mehrnoush Masihpour

    2013-05-01

    Full Text Available In this paper, multihop relaying in RF-based communications and near field magnetic induction communication (NFMIC is discussed. Three multihop relay strategies for NFMIC are proposed: Non Line of Sight Magnetic Induction Relay (NLoS-MI Relay, Non Line of Sight Master/Assistant Magnetic Induction Relay1 (NLoS-MAMI Relay1 and Non Line of Sight Master/Assistant Magnetic Induction Relay2 (NLoSMAMI Relay2. In the first approach only one node contributes to the communication, while in the other two techniques (which are based on a master-assistant strategy, two relaying nodes are employed. This paper shows that these three techniques can be used to overcome the problem of dead spots within a body area network and extend the communication range without increasing the transmission power and the antenna size or decreasing receiver sensitivity. The impact of the separation distance between the nodes on the achievable RSS and channel data rate is evaluated for the three techniques. It is demonstrated that the technique which is most effective depends on the specific network topology. Optimum selection of nodes as relay master and assistant based on the location of the nodes is discussed. The paper also studies the impact of the quality factor on achievable data rate. It is shown that to obtain the highest data rate, the optimum quality factor needs to be determined for each proposed cooperative communication method.

  8. Optimal transmit power allocation for MIMO two-way cognitive relay networks with multiple relays using AF strategy

    KAUST Repository

    Alsharoa, Ahmad M.

    2014-02-01

    In this letter, we consider a multiple-input multiple-output two-way cognitive radio system under a spectrum sharing scenario, where primary and secondary users operate on the same frequency band. The secondary terminals aims to exchange different messages with each other using multiple relays where each relay employs an amplify-and-forward strategy. The main objective of our work is to maximize the secondary sum rate allowed to share the spectrum with the primary users by respecting a primary user tolerated interference threshold. In this context, we derive an analytical expression of the optimal power allocated to each antenna of the terminals. We then discuss the impact of some system parameters on the performance in the numerical result section. © 2012 IEEE.

  9. Energy-efficient relay selection and optimal power allocation for performance-constrained dual-hop variable-gain AF relaying

    KAUST Repository

    Zafar, Ammar

    2013-12-01

    This paper investigates the energy-efficiency enhancement of a variable-gain dual-hop amplify-and-forward (AF) relay network utilizing selective relaying. The objective is to minimize the total consumed power while keeping the end-to-end signal-to-noise-ratio (SNR) above a certain peak value and satisfying the peak power constraints at the source and relay nodes. To achieve this objective, an optimal relay selection and power allocation strategy is derived by solving the power minimization problem. Numerical results show that the derived optimal strategy enhances the energy-efficiency as compared to a benchmark scheme in which both the source and the selected relay transmit at peak power. © 2013 IEEE.

  10. Determination of the ion-exchange capacity of anion-selective membranes

    Czech Academy of Sciences Publication Activity Database

    Karas, F.; Hnát, J.; Paidar, M.; Schauer, Jan; Bouzek, K.

    2014-01-01

    Roč. 39, č. 10 (2014), s. 5054-5062. ISSN 0360-3199 Institutional support: RVO:61389013 Keywords : ion-exchange capacity * anion-selective membranes * titration Subject RIV: CD - Macromolecular Chemistry Impact factor: 3.313, year: 2014

  11. Anionic polymerization of (meth)acrylate monomers with the ligated systems, metalloporphyrin and lanthanocene initiators

    Czech Academy of Sciences Publication Activity Database

    Vlček, Petr

    New York: Nova Science Publishers, Inc, 2006 - (Jagur-Grodzinski, J.), s. 289-342 ISBN 1-59454-330-5 Institutional research plan: CEZ:AV0Z40500505 Keywords : anionic polymerization * copolymers * (meth)acrylates Subject RIV: CD - Macromolecular Chemistry

  12. Carbon nanotube anions for the preparation of gold nanoparticle-nanocarbon hybrids.

    Science.gov (United States)

    Bayazit, Mustafa K; Hodge, Stephen A; Clancy, Adam J; Menzel, Robert; Chen, Shu; Shaffer, Milo S P

    2016-01-31

    Gold nanoparticles (AuNPs) can be evenly deposited on single-walled carbon nanotubes (SWCNTs) via the reduction of the highly stable complex, chloro(triphenylphosphine) gold(I), with SWCNT anions ('nanotubides'). This methodology highlights the unusual chemistry of nanotubides and provides a blueprint for the generation of many other hybrid nanomaterials. PMID:26679693

  13. Anion Receptors based on Ureidocalix[4]arenes Immobilised in the Partial cone Conformation

    Czech Academy of Sciences Publication Activity Database

    Hudeček, O.; Budka, J.; Dvořáková, H.; Cuřínová, Petra; Císařová, I.; Lhoták, P.

    2013-01-01

    Roč. 37, č. 1 (2013), s. 220-227. ISSN 1144-0546 R&D Projects: GA ČR GA203/09/0691; GA AV ČR IAAX08240901 Institutional support: RVO:67985858 Keywords : anion receptors * ureidocalix[4]arenes * partial cone conformation Subject RIV: CC - Organic Chemistry Impact factor: 3.159, year: 2013

  14. Good chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    The subject matter in chemistry courses reflects almost nothing of the issues that chemists are interested in. It is important to formulate a set of topics - and a Medical College Admissions Test reflecting them - that would leave chemistry departments no choice but to change their teaching.

  15. Efficient Amide Based Halogenide Anion Receptors

    Institute of Scientific and Technical Information of China (English)

    Hong Xing WU; Feng Hua LI; Hai LIN; Shou Rong ZHU; Hua Kuan LIN

    2005-01-01

    In this paper, we present the synthesis and anion recognition properties of the amide based phenanthroline derivatives 1, 2 and 3. In all cases 1:1 receptor: anion complexes were observed. The receptors were found to be selective for fluoride and chloride respectively over other putative anionic guest species.

  16. Partial relay selection based on shadowing side information over generalized composite fading channels

    KAUST Repository

    Yilmaz, Ferkan

    2011-11-01

    In this paper, in contrast to the relay selection protocols available in the literature, we propose a partial relay selection protocol utilizing only the shadowing side information of the relays instead of their full channel side information in order to select a relay in a dual-hop relaying system through the available limited feedback channels and power budget. We then presented an exact unified performance expression combining the average bit error probability, ergodic capacity, and moments-generating function of the proposed partial relay selection over generalized fading channels. Referring to the unified performance expression introduced in [1], we explicitly offer a generic unified performance expression that can be easily calculated and that is applicable to a wide variety of fading scenarios. Finally, as an illustration of the mathematical formalism, some numerical and simulation results are generated for an extended generalized-K fading environment, and these numerical and simulation results are shown to be in perfect agreement. © 2011 IEEE.

  17. Near optimal power allocation algorithm for OFDM-based cognitive using adaptive relaying strategy

    KAUST Repository

    Soury, Hamza

    2012-01-01

    Relayed transmission increases the coverage and achievable capacity of communication systems. Adaptive relaying scheme is a relaying technique by which the benefits of the amplifying or decode and forward techniques can be achieved by switching the forwarding technique according to the quality of the signal. A cognitive Orthogonal Frequency-Division Multiplexing (OFDM) based adaptive relaying protocol is considered in this paper. The objective is to maximize the capacity of the cognitive radio system while ensuring that the interference introduced to the primary user is below the tolerated limit. A Near optimal power allocation in the source and the relay is presented for two pairing techniques such that the matching and random pairing. The simulation results confirm the efficiency of the proposed adaptive relaying protocol, and the consequence of choice of pairing technique. © 2012 ICST.

  18. Simultaneous Wireless Information and Power Transfer for Decode-and-Forward MIMO Relay Communication Systems

    KAUST Repository

    Benkhelifa, Fatma

    2015-05-01

    In this paper, we investigate the simultaneous wireless information and power transfer (SWIPT) for a decode-and-forward (DF) multiple-input multiple-output (MIMO) relay system where the relay is an energy harvesting node. We consider the ideal scenario where both the energy harvesting (EH) receiver and information decoding (ID) receiver at the relay have access to the whole received signal and its energy. The relay harvests the energy while receiving the signal from the source and uses the harvested power to forward the signal to the destination. We obtain the optimal precoders at the source and the relay to maximize the achievable throughput rate of the overall link. In the numerical results, the effect of the transmit power at the source and the position of the relay between the source and the destination on the maximum achievable rate are investigated. © 2015 IEEE.

  19. Performance analysis of selective cooperation with fixed gain relays in Nakagami-m channels

    KAUST Repository

    Hussain, Syed Imtiaz

    2012-09-01

    Selecting the best relay using the maximum signal to noise ratio (SNR) among all the relays ready to cooperate saves system resources and utilizes the available bandwidth more efficiently compared to the regular all-relay cooperation. In this paper, we analyze the performance of the best relay selection scheme with fixed gain relays operating in Nakagami-. m channels. We first derive the probability density function (PDF) of upper bounded end-to-end SNR of the relay link. Using this PDF, we derive some key performance parameters for the system including average bit error probability and average channel capacity. The analytical results are verified through Monte Carlo simulations. © 2012 Elsevier B.V.

  20. Analysis of Polygonal Distance Protection Relay of Transmission Line Affected by SMES Device

    Science.gov (United States)

    Yang, Jun; Zhang, Wenjia

    Because of unique advantages in rapid response and independent control of act ve and reactive power, Superconducting Magnetic Energy Storage (SMES) device will be widely used in the power system. The SMES exchanges power with power grid in the charging and discharging process, so it may affect the performance of protection relay of transmission line, which will lead to mal-operation. Based on SMES model, the tripping characteristic of polygonal distance relay for single-machine-infinite-bus performance of polygonal distance relay with SMES. The simulation results show the measured impedance of polygonal distance relay is changed by SMES, and polygonal distance relay will make mal-operation when faults occur in the boundary of protection zone. Also an improving distance relay is proposed to solve the problem.

  1. Throughput maximization for buffer-aided hybrid half-/full-duplex relaying with self-interference

    KAUST Repository

    Khafagy, Mohammad Galal

    2015-06-01

    In this work, we consider a two-hop cooperative setting where a source communicates with a destination through an intermediate relay node with a buffer. Unlike the existing body of work on buffer-aided half-duplex relaying, we consider a hybrid half-/full-duplex relaying scenario with loopback interference in the full-duplex mode. Depending on the channel outage and buffer states that are assumed available at the transmitters, the source and relay may either transmit simultaneously or revert to orthogonal transmission. Specifically, a joint source/relay scheduling and relaying mode selection mechanism is proposed to maximize the end-to-end throughput. The throughput maximization problem is converted to a linear program where the exact global optimal solution is efficiently obtained via standard convex/linear numerical optimization tools. Finally, the theoretical findings are corroborated with event-based simulations to provide the necessary performance validation.

  2. On the Outage Performance of Full-Duplex Selective Decode-and-Forward Relaying

    KAUST Repository

    Khafagy, Mohammad Galal

    2013-02-25

    We evaluate the outage performance in a three-terminal full-duplex relay channel that adopts a selective decode-and-forward protocol, taking relay self-interference into account. Previous work focused on coverage extension scenarios where direct source-destination transmissions are neglected or considered as interference. In this work, we account for the relay self-interference, and exploit the cooperative diversity offered by the independently fading source/relay message replicas that arrive at the destination. We present an approximate, yet accurate, closed-form expression for the end-to-end outage probability that captures their joint effect. With the derived expression in hand, we propose a relay transmit power optimization scheme that only requires the relay knowledge of channel statistics. Finally, we corroborate our analysis with simulations.

  3. Throughput Maximization for the Gaussian Relay Channel with Energy Harvesting Constraints

    OpenAIRE

    Huang, Chuan; Zhang, Rui; Cui, Shuguang

    2011-01-01

    This paper considers the use of energy harvesters, instead of conventional time-invariant energy sources, in wireless cooperative communication. For the purpose of exposition, we study the classic three-node Gaussian relay channel with decode-and-forward (DF) relaying, in which the source and relay nodes transmit with power drawn from energy-harvesting (EH) sources. Assuming a deterministic EH model under which the energy arrival time and the harvested amount are known prior to transmission, ...

  4. Proactive Relay Selection with Joint Impact of Hardware Impairment and Co-channel Interference

    OpenAIRE

    Duy, Tran Trung; Duong, Trung Q.; da Costa, Daniel Benevides; Bao, Vo Ngyugen Quoc; Elkashlan, Maged

    2015-01-01

    In this paper, we investigate the end-to-end performance of dual-hop proactive decode-and-forward relaying networks with Nth best relay selection in the presence of two practical deleterious effects: i) hardware impairment and ii) cochannel interference. In particular, we derive new exact and asymptotic closed-form expressions for the outage probability and average channel capacity of Nth best partial and opportunistic relay selection schemes over Rayleigh fading channels. Insightful discussi...

  5. Joint Power Splitting and Secure Beamforming Design in the Wireless-powered Untrusted Relay Networks

    OpenAIRE

    Zhao, Mingxiong; Feng, Suili; Liu, Yuan; Wang, Xiangfeng; Zhang, Meng; Fu, Hao

    2015-01-01

    In this work, we maximize the secrecy rate of the wireless-powered untrusted relay network by jointly designing power splitting (PS) ratio and relay beamforming with the proposed global optimal algorithm (GOA) and local optimal algorithm (LOA). Different from the literature, artificial noise (AN) sent by the destination not only degrades the channel condition of the eavesdropper to improve the secrecy rate, but also becomes a new source of energy powering the untrusted relay based on PS. Henc...

  6. A Delay-Constrained General Achievable Rate and Certain Capacity Results for UWB Relay Channel

    OpenAIRE

    Yazd, Maryam Faramarzi; Hodtani, Ghosheh Abed

    2011-01-01

    In this paper, we derive UWB version of (i) general best achievable rate for the relay channel with decode-andforward strategy and (ii) max-flow min-cut upper bound, such that the UWB relay channel can be studied considering the obtained lower and upper bounds. Then, we show that by appropriately choosing the noise correlation coefficients, our new upper bound coincides with the lower bound in special cases of degraded and reversely degraded UWB relay channels. Finally, some numerical results...

  7. Quantum-Relay-Assisted Key Distribution over High Photon Loss Channels

    OpenAIRE

    Zhang, An-Ning; Chen, Yu-Ao; Lu, Chao-Yang; Zhou, Xiao-Qi; Zhao, Zhi; Qiang ZHANG; Yang, Tao; Pan, Jian-Wei

    2005-01-01

    The maximum distance of quantum communication is limited due to the photon loss and detector noise. Exploiting entanglement swapping, quantum relay could offer ways to extend the achievable distance by increasing the signal to noise ratio. In this letter we present an experimental simulation of long distance quantum communication, in which the superiority of quantum relay is demonstrated. Assisted by quantum relay, we greatly extend the distance limit of unconditional secure quantum communica...

  8. Trading wireless information and power transfer: Relay selection to minimize the outage probability

    OpenAIRE

    Butt, M. Majid; Nasir, Adnan; Mohamed, Amr; Guizani, Mohsen

    2014-01-01

    This paper studies the outage probability minimization problem for a multiple relay network with energy harvesting constraints. The relays are hybrid nodes used for simultaneous wireless information and power transfer from the source radio frequency (RF) signals. There is a trade-off associated with the amount of time a relay node is used for energy and information transfer. Large intervals of information transfer implies little time for energy harvesting from RF signals and thus, high probab...

  9. Autonomous Formation Flying of Micro Aerial Vehicles for Communication Relay Chains

    OpenAIRE

    Angermann, Michael; Frassl, Martin; Lichtenstern, Michael

    2011-01-01

    In this paper we describe the use of GNSS location determination for formation flying of multiple Micro Aerial Vehicles (MAVs). These MAVs are the core component of a system that realizes a chain of airborne communication relays to provide communication services to mobile terminals. This chain of communication relay nodes improves wireless radio communication by utilizing two effects. Firstly, a chain of relay nodes is able to convert an unfavorable non-line-of-sight condition to a line-of-si...

  10. Policy-Aware Virtual Relay Placement for Inter-Domain Path Diversity

    OpenAIRE

    Guo, Tao; Wang, Ning; Tafazolli, Rahim; Moessner, Klaus

    2010-01-01

    Exploiting path diversity to enhance communication reliability is a key desired property in Internet. While the existing routing architecture is reluctant to adopt changes, overlay routing has been proposed to circumvent the constraints of native routing by employing intermediary relays. However, the selfish interdomain relay placement may violate local routing policies at intermediary relays and thus affect their economic costs and performances. With the recent advance of the concept of n...

  11. On the malfunction of disk-type induction relay under seismic condition

    International Nuclear Information System (INIS)

    This paper deals with the malfunction of disk-type induction relay. Equations of motion for rotational movement of induction relay was formulated and the dynamic behavior was simulated under various kind of exciting conditions. Experimental verification was also performed using two dimensional shaker table for some actual relays. Sufficient agreement was recognized between experimental and analytical results and consequently the most critical reason to cause the malfunction was pointed out. (orig.)

  12. Laser Cooling of Molecular Anions

    CERN Document Server

    Yzombard, Pauline; Gerber, Sebastian; Doser, Michael; Comparat, Daniel

    2015-01-01

    We propose a scheme for laser cooling of negatively charged molecules. We briefly summarise the requirements for such laser cooling and we identify a number of potential candidates. A detailed computation study with C$\\_2^-$, the most studied molecular anion, is carried out. Simulations of 3D laser cooling in a gas phase show that this molecule could be cooled down to below 1 mK in only a few tens of milliseconds, using standard lasers. Sisyphus cooling, where no photo-detachment process is present, as well as Doppler laser cooling of trapped C$\\_2^-$, are also simulated. This cooling scheme has an impact on the study of cold molecules, molecular anions, charged particle sources and antimatter physics.

  13. Polymerization of anionic wormlike micelles.

    Science.gov (United States)

    Zhu, Zhiyuan; González, Yamaira I; Xu, Hangxun; Kaler, Eric W; Liu, Shiyong

    2006-01-31

    Polymerizable anionic wormlike micelles are obtained upon mixing the hydrotropic salt p-toluidine hydrochloride (PTHC) with the reactive anionic surfactant sodium 4-(8-methacryloyloxyoctyl)oxybenzene sulfonate (MOBS). Polymerization captures the cross-sectional radius of the micelles (approximately 2 nm), induces micellar growth, and leads to the formation of a stable single-phase dispersion of wormlike micellar polymers. The unpolymerized and polymerized micelles were characterized using static and dynamic laser light scattering, small-angle neutron scattering, 1H NMR, and stopped-flow light scattering. Stopped-flow light scattering was also used to measure the average lifetime of the unpolymerized wormlike micelles. A comparison of the average lifetime of unpolymerized wormlike micelles with the surfactant monomer propagation rate was used to elucidate the mechanism of polymerization. There is a significant correlation between the ratio of the average lifetime to the monomer propagation rate and the average aggregation number of the polymerized wormlike micelles. PMID:16430253

  14. Cooperative MIMO Relaying with Orthogonal Space-Time Block Codes in Wireless Channels with and without Keyholes

    Directory of Open Access Journals (Sweden)

    Tian Zhang

    2014-07-01

    Full Text Available Cooperative multiple-input multiple-output (MIMO relaying is investigated in the paper. We introduce DFAF selection MIMO relaying, where the relay equipped with multiple antennas can adaptively switch between decode-and-forward (DF and amplify-and-forward (AF according to its decoding state of the sourcemessage. We consider two wireless environment scenarios: 1The scenario with traditional channels are considered firstly. We analyze the outage performance of DF-AF selection MIMO relaying, and a closed-form expression is derived. In addition, the diversity order is obtained based on the expression. For comparison purpose, we also obtain the closed-form outage probability and the diversity order for the AF MIMO relaying and the DF MIMO relaying. 2We investigate the cooperative MIMO relaying in the presnece of keyholes secondly. We present performance analysis of orthogonal space-time block coded transmission for a cooperative MIMO relaying system with keyholes. For DF MIMO relaying, exact outage probability and symbol error probability (SEP are obtained. Regarding AF MIMO relaying and DF-AF selection MIMO relaying, the lower and upper bounds are derived. In both traditional and keyhole scenarios, theoretical analysis which has been further verified through Monte-Carlo simulations demonstrate that the DF-AF selection MIMO relaying has better performance than the AF MIMO relaying and the DF MIMO relaying.

  15. Performance of hybrid-ARQ with incremental redundancy over relay channels

    KAUST Repository

    Chelli, Ali

    2012-12-01

    In this paper, we consider a relay network consisting of a source, a relay, and a destination. The source transmits a message to the destination using hybrid automatic repeat request (HARQ) with incremental redundancy (IR). The relay overhears the transmitted messages over the different HARQ rounds and tries to decode the data packet. In case of successful decoding at the relay, both the relay and the source cooperate to transmit the message to the destination. A maximum number M of HARQ rounds is considered. The channel realizations are independent for different HARQ rounds. We assume Rayleigh fading channels for the links source-relay, source-destination, and relay-destination. We investigate the performance of HARQ-IR over relay channel from an information theoretic perspective. Analytical expressions are derived for the information outage probability, the average number of transmissions, and the average transmission rate. We illustrate through our investigation the benefit of relaying. We also show the impact of the target outage probability and the maximum number M of HARQ rounds on the outage probability, the average number of transmissions, and the average transmission rate. © 2012 IEEE.

  16. New resource allocation scheme for cognitive relay networks with opportunistic access

    KAUST Repository

    Zafar, Ammar

    2012-06-01

    In this paper, a new resource allocation scheme to minimize Symbol Error rate (SER) for relay assisted cognitive radio networks is studied. A cognitive relay network with amplify-and-forward (AF) fixed gain relays and opportunistic access to the licensed spectrum is considered. The SER objective function and the optimization constraints are derived first. The resource allocation algorithm is then derived using the Langrangian multiplier method. Closed form expressions are derived for the source and relay powers and, symbol time. Analytical results show that the optimal power allocation follows an extended water-filling solution. © 2012 IEEE.

  17. The broadcast classical-quantum capacity region of a two-phase bidirectional relaying channel

    Science.gov (United States)

    Boche, Holger; Cai, Minglai; Deppe, Christian

    2015-10-01

    We studied a three-node quantum network that enables bidirectional communication between two nodes with a half-duplex relay node for transmitting classical messages. A decode-and-forward protocol is used to perform the communication in two phases. In the first phase, the messages of two nodes are transmitted to the relay node. The capacity of the first phase is well known by previous works. In the second phase, the relay node broadcasts a re-encoded composition to the two nodes. We determine the capacity region of the broadcast phase. To the best of our knowledge, this is the first paper analyzing quantum bidirectional relay networks.

  18. Behavior Prediction of Untrusted Relays Based on Nonzero-Sum Game

    Institute of Scientific and Technical Information of China (English)

    Fu Xiaomei付晓梅; Wu Xiao吴晓; Wang Qing汪清

    2015-01-01

    To keep the secrecy performance from being badly influenced by untrusted relay(UR), a multi-UR net-work through amplify-and-forward (AF) cooperative scheme is put forward, which takes relay weight and harmful factor into account. A nonzero-sum game is established to capture the interaction among URs and detection strate-gies. Secrecy capacity is investigated as game payoff to indicate the untrusted behaviors of the relays. The maxi-mum probabilities of the behaviors of relay and the optimal system detection strategy can be obtained by using the proposed algorithm.

  19. Full-Duplex opportunistic relay selection in future spectrum-sharing networks

    KAUST Repository

    Khafagy, Mohammad Galal

    2015-06-01

    We propose and analyze the performance of full-duplex relay selection in primary/secondary spectrum-sharing networks. Contrary to half-duplex relaying, full-duplex relaying (FDR) enables simultaneous listening/forwarding at the secondary relay, thereby allowing for a higher spectral efficiency. However, since the source and relay simultaneously transmit in FDR, their superimposed signal at the primary receiver should now satisfy the existing interference constraint which can considerably limit the secondary network throughput. In this regard, relay selection can offer an adequate solution to boost the secondary throughput while satisfying the imposed interference limit. We first analyze the performance of opportunistic relay selection among a cluster of full-duplex decode-and-forward relays with self-interference by deriving the exact cumulative distribution function of its end-to-end signal-to-noise ratio. Second, we evaluate the end-to-end performance of relay selection with interference constraints due to the presence of a primary receiver. Finally, the presented exact theoretical findings are verified by numerical simulations.

  20. Optimum Power Allocations for Fading Decode-and-Forward Relay Channel

    CERN Document Server

    Davoodi, Arash Gholami; Aref, Mohammad Reza

    2012-01-01

    In this paper, for a fading decode-and-forward full-duplex relay channel, we analytically derive optimum power allocations. Individual power constraints for the source and the relay are assumed and the related optimization problem is analyzed for two scenarios. First, optimization is taken over the source power, the relay power, and the correlation coefficient between the transmitted signals of the source and the relay. Then, for a fixed value of correlation coefficient, the optimization problem is analyzed. It is also proven that the optimization problems are convex for these two scenarios. Finally, implications of theoretical results are discussed through simulations for each scenario.

  1. Proof-of-Work as Anonymous Micropayment: Rewarding a Tor Relay

    OpenAIRE

    Biryukov, Alex; Pustogarov, Ivan

    2015-01-01

    In this paper we propose a new micropayments scheme which can be used to reward Tor relay operators. Tor clients do not pay Tor relays with electronic cash directly but submit proof of work shares which the relays can resubmit to a crypto-currency mining pool. Relays credit users who submit shares with tickets that can later be used to purchase improved service. Both shares and tickets when sent over Tor circuits are anonymous. The analysis of the crypto-currencies market prices shows that th...

  2. Study on Reactance Relays for Single Phase to Earth Fault on EHV Transmission Lines

    Directory of Open Access Journals (Sweden)

    Yongqing Liu

    2013-07-01

    Full Text Available Two questions about zero-sequence-reactance relay to overcome the disadvantages of high fault resistance for single phase to earth fault of high voltage transmission lines are discussed in this paper. The first question is about the phase difference between the measured zero-sequence current and voltage at fault position for un-balanced transmission lines. The second question is about the “in-phase” problem in reactance relays (or fault component reactance relays. This paper analyzes the two questions theoretically and the reactance relay is improved by a new discriminative principle. The capability against the fault resistance is largely enhanced by the improved schemes.    

  3. Semi-Distributed Relay Selection Algorithm for Multi-User Cooperative Wireless Networks

    Directory of Open Access Journals (Sweden)

    Yafeng Wang

    2011-06-01

    Full Text Available In this paper, we propose a novel semi-distributed algorithm with low overhead and complexity for multi-user cooperative wireless networks with opportunistic relaying. The source is required to satisfy its minimum rate requirement with a feasible relay and help another source as a relay. The optimal solution can be obtained by exhaustive search with intractable computational complexity. Simulation results suggest that the proposed relay selection algorithm has the similar outage probability as the exhaustive search approach but with much less computational burden.

  4. Commercial grade item (CGI) dedication of MDR relays for nuclear safety related applications

    International Nuclear Information System (INIS)

    MDR relays manufactured by Potter and Brumfield (P and B) have been used in various safety related applications in commercial nuclear power plants. These include emergency safety features (ESF) actuation systems, emergency core cooling systems (ECCS) actuation, and reactor protection systems. The MDR relays manufactured prior to May 1990 showed signs of generic failure due to corrosion and outgassing of coil varnish. P and B has made design changes to correct these problems in relays manufactured after May 1990. However, P and B does not manufacture the relays under any 10CFR50 Appendix B quality assurance (QA) program. They manufacture the relays under their commercial QA program and supply these as commercial grade items. This necessitates CGI Dedication of these relays for use in nuclear-safety-related applications. This paper presents a CGI dedication program that has been used to dedicate the MDR relays manufactured after May 1990. The program is in compliance with current Nuclear Regulatory Commission (NRC) and Electric Power Research Institute (EPRI) guidelines and applicable industry standards; it specifies the critical characteristics of the relays, provides the tests and analysis required to verify the critical characteristics, the acceptance criteria for the test results, performs source verification to qualify P and B for its control of the critical characteristics, and provides documentation. The program provides reasonable assurance that the new MDR relays will perform their intended safety functions

  5. Location-based Relay Selection and Power Adaptation Enabling Simultaneous Transmissions

    DEFF Research Database (Denmark)

    Nielsen, Jimmy Jessen; Madsen, Tatiana Kozlova; Schwefel, Hans-Peter

    2010-01-01

    Relaying is a well known technique to extend coverage and improve conditions for nodes in the outer coverage region. In this paper we propose a relaying scheme that exploits the spatial separation of relay and destination pairs to improve throughput by allowing simultaneous transmissions. The...... takes into account MAC retransmissions and timing behavior of the IEEE 802.11 Distributed Coordination Function mode. Our results show an increase in throughput of approximately 20% is achievable for the proposed scheme when compared to two-hop relaying in the analyzed scenario....

  6. Relay selection in underlay cognitive networks with fixed transmission power nodes

    KAUST Repository

    Hussain, Syed Imtiaz

    2013-07-31

    Underlay cognitive networks operate simultaneously with primary networks satisfying stringent interference constraints, which reduces their transmission power and coverage area. To reach remote destinations, secondary sources use relaying techniques. Selecting the best relay among the available ones is a well known technique. Recently, selective cooperation is investigated in cognitive networks where the secondary nodes can adapt their transmission power to always satisfy the interference threshold. In this paper, we investigate a situation where the secondary nodes have a fixed transmission power and may violate the interference threshold. We present two relay selection schemes; the first one excludes the relays not satisfying the interference constraint and then picks up a relay from the remaining ones that can provide the maximum signal-to-noise ratio (SNR). The other scheme uses a quotient of the relay link SNR and the interference from the relay to the primary user and optimizes it to maximise the relay link SNR. We derive closed form expressions for outage probability, bit error rate, channel capacity and diversity of the system for both schemes by using tight approximations. We also study mutual effects of interference. Simulation results confirm the analytical results and reveal that the relay selection is feasible at low SNRs. Copyright © 2013 John Wiley & Sons, Ltd.

  7. Toward distributed relay selection for opportunistic amplify-and-forward transmission

    KAUST Repository

    Tourki, Kamel

    2011-05-01

    Opportunistic relaying in cooperative communication depends on careful relay selection. However the traditional centralized method used for opportunistic Amplify-and-Forward (OAF) protocols requires precise measurements of channel state information (CSI) at the destination (CSI-OAF). In this paper, we propose a distributed relay selection framework for opportunistic AF (D-OAF) cooperative communications and offer an accurate performance analysis based on exact statistics of the local signalto- noise ratios of the best relay. Furthermore, we validate our analysis by showing that performance simulation results coincide with our analytical results over different network architectures, and we compare our new results with their CSI-based counterparts. © 2011 IEEE.

  8. Quantum chemistry

    CERN Document Server

    Lowe, John P

    1993-01-01

    Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom,

  9. The sorption capacity of boron on anionic-exchange resin

    International Nuclear Information System (INIS)

    Boron sorption capacities on anionic-exchange resins vary with temperature, concentration, and resin cross-linkage. A semiempirical correlation, developed from boron solution chemistry, is presented to account for these variations. The relationship, based on boron chemistry and changes in Gibb's energy, can be stated approximately as Q = a1CBa2Za3 exp[-(a4T + a5T2 + a6Z0.5)]. Correlation parameters, which vary with resin type, are evaluated experimentally. Parameter values for macroporous resin Diaion PA 300 and for gel-type resins Diaion SA10 and Amberlite IRN 78LC are presented. The resulting expression is used to determine boron sorption and desorption limitations on ion exchangers at various temperatures and concentrations, and to determine the interfacial boron concentration in equilibrium and rate models

  10. A planar oxocuprate(II) array via heterometallic alkoxide chemistry

    International Nuclear Information System (INIS)

    Application of the molecular precursor method to the synthesis of copper-based high-temperature superconductors rests on the authors ability to produce copper containing heterometallic alkoxides. They have reported recently on the chemistry of the anion Zr2-(OiPr)9-, which is related to recent reports by the group of Mehrotra. They report here their investigation of the coupling of this and related anions to CuCl2 of relevance to hydrolytic routes to copper/oxo superconductors

  11. Life Cycle Assessment Guideline for Protection Relay : 615 series

    OpenAIRE

    Liimatainen, Viivi

    2012-01-01

    This thesis is made for ABB Oy, Medium Voltage Products in Vaasa. The main goal of the thesis is to make Life Cycle Assessment (LCA) guideline for protection and control relay product families because the earlier made LCA studies are not valid anymore and the guideline, LCA tool and database are not up-to-date. During the new LCA guideline process product family 615 series LCA study is carried out as an example. The LCA study is based on ISO 14040 standard series and the guideline so call...

  12. Performance Analysis and Comparison of 6to4 Relay Implementations

    OpenAIRE

    Gábor Lencse; Sándor Répás

    2013-01-01

    the depletion of the public IPv4 address pool may speed up the deployment of IPv6. The coexistence of the two versions of IP requires some transition mechanisms. One of them is 6to4 which provides a solution for the problem of an IPv6 capable device in an IPv4 only environment. From among the several 6to4 relay implementations, the following ones were selected for testing: sit under Linux, stf under FreeBSD and stf under NetBSD. Their stability and performance were in¬ves¬ti¬gat¬ed in a test ...

  13. Minimizing Symbol Error Rate for Cognitive Relaying with Opportunistic Access

    KAUST Repository

    Zafar, Ammar

    2012-12-29

    In this paper, we present an optimal resource allocation scheme (ORA) for an all-participate(AP) cognitive relay network that minimizes the symbol error rate (SER). The SER is derived and different constraints are considered on the system. We consider the cases of both individual and global power constraints, individual constraints only and global constraints only. Numerical results show that the ORA scheme outperforms the schemes with direct link only and uniform power allocation (UPA) in terms of minimizing the SER for all three cases of different constraints. Numerical results also show that the individual constraints only case provides the best performance at large signal-to-noise-ratio (SNR).

  14. Privacy Preserving Quantum Anonymous Transmission via Entanglement Relay

    Science.gov (United States)

    Yang, Wei; Huang, Liusheng; Song, Fang

    2016-06-01

    Anonymous transmission is an interesting and crucial issue in computer communication area, which plays a supplementary role to data privacy. In this paper, we put forward a privacy preserving quantum anonymous transmission protocol based on entanglement relay, which constructs anonymous entanglement from EPR pairs instead of multi-particle entangled state, e.g. GHZ state. Our protocol achieves both sender anonymity and receiver anonymity against an active adversary and tolerates any number of corrupt participants. Meanwhile, our protocol obtains an improvement in efficiency compared to quantum schemes in previous literature.

  15. Terrain dependant hop count selection for transparent relay transmissions

    Directory of Open Access Journals (Sweden)

    Cibile K. Kanjirathumkal

    2013-12-01

    Full Text Available In this Letter, the selection of the best hop count for a particular topography, in the context of enhanced connectivity using multi-hop transparent relay communication is addressed. Based on the coefficient of variation and the terrain specific fading severity factor of the distribution, it is possible to estimate the optimal hop count that can provide the required performance at detector. Two distribution models, which can adequately characterise the terrain fading effects on empirical data are considered for performance comparison. The results are useful in selecting branches, with low variability and optimal hop count for connectivity, in multi-stream switched diversity combining systems.

  16. Coordination procedure for radio relay and communication satellite services

    Science.gov (United States)

    Eckerman, J.

    1973-01-01

    A global rain rate statistic model is used to link microwave propagation statistics to measurable rain statistics in order to develop international telecommunication site criteria for radio relay and communication satellite services that minimize interference between receivers and transmitters. This rain coordination procedure utilizes a rain storm cell size, a statistical description of the rainfall rate within the cell valid for most of the earth's surface, approximations between Raleigh scatter and constancy of precipitation with altitude, and an analytic relation between radar reflectivity and rain rate.

  17. ON THE CAPACITY REGION OF WIRELESS AD HOC RELAY NETWORKS

    Institute of Scientific and Technical Information of China (English)

    Dai Qinyun; Yao Wangsheng; Peng Jianmin; Su Gang

    2006-01-01

    Network capacity is a key characteristic to evaluate the performance of wireless networks. The goal of this paper is to study the capacity of wireless ad hoc relay network. In the model, there is at most ns source nodes transmitting signal simultaneously in the network and the arbitrarily complex network coding is allowed. The upper capacity bound of the network model are derived from the max-flow min-cut theorem and the lower capacity bound are obtained by the rate-distortion function for the Gaussian source. Finally, simulation results show that the upper network capacity will decrease as the number of source nodes is increased.

  18. Materials Chemistry

    CERN Document Server

    Fahlman, Bradley D

    2011-01-01

    The 2nd edition of Materials Chemistry builds on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field. The 2nd edition continues to offer innovative coverage and practical perspective throughout. After briefly defining materials chemistry and its history, seven chapters discuss solid-state chemistry, metals, semiconducting materials, organic "soft" materials, nanomaterials, and materials characterization. All chapters have been thoroughly updated and expanded with, for example, new sections on ‘soft lithographic’ patterning, ‘click chemistry’ polymerization, nanotoxicity, graphene, as well as many biomaterials applications. The polymer and ‘soft’ materials chapter represents the largest expansion for the 2nd edition. Each ch...

  19. Introductory Chemistry

    OpenAIRE

    Baron, Mark; Gonzalez-Rodriguez, Jose; Stevens, Gary; Gray, Nathan; Atherton, Thomas; Winn, Joss

    2010-01-01

    Teaching and Learning resources for the 1st Year Introductory Chemistry course (Forensic Science). 30 credits. These are Open Educational Resources (OER), made available for re-use under a Creative Commons license.

  20. Separations chemistry

    International Nuclear Information System (INIS)

    Results of studies on the photochemistry of aqueous Pu solutions and the stability of iodine in liquid and gaseous CO2 are reported. Progress is reported in studies on: the preparation of macroporous bodies filled with oxides and sulfides to be used as adsorbents; the beneficiation of photographic wastes; the anion exchange adsorption of transition elements from thiosulfate solutions; advanced filtration applications of energy significance; high-resolution separations; and, the examination of the separation agents, octylphenylphosphoric acid (OPPA) and trihexyl phosphate (THP)

  1. Analytical chemistry

    International Nuclear Information System (INIS)

    This book is comprised of nineteen chapters, which describes introduction of analytical chemistry, experimental error and statistics, chemistry equilibrium and solubility, gravimetric analysis with mechanism of precipitation, range and calculation of the result, volume analysis on general principle, sedimentation method on types and titration curve, acid base balance, acid base titration curve, complex and firing reaction, introduction of chemical electro analysis, acid-base titration curve, electrode and potentiometry, electrolysis and conductometry, voltammetry and polarographic spectrophotometry, atomic spectrometry, solvent extraction, chromatograph and experiments.

  2. Cluster Chemistry

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    @@ Cansisting of eight scientists from the State Key Laboratory of Physical Chemistry of Solid Surfaces and Xiamen University, this creative research group is devoted to the research of cluster chemistry and creation of nanomaterials.After three-year hard work, the group scored a series of encouraging progresses in synthesis of clusters with special structures, including novel fullerenes, fullerene-like metal cluster compounds as well as other related nanomaterials, and their properties study.

  3. Green Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Collison, Melanie

    2011-05-15

    Green chemistry is the science of chemistry used in a way that will not use or create hazardous substances. Dr. Rui Resendes is working in this field at GreenCentre Canada, an offshoot of PARTEQ Innovations in Kingston, Ontario. GreenCentre's preliminary findings suggest their licensed product {sup S}witchable Solutions{sup ,} featuring 3 classes of solvents and a surfactant, may be useful in bitumen oil sands extraction.

  4. Anion-π interactions in complexes of proteins and halogen-containing amino acids.

    Science.gov (United States)

    Borozan, Sunčica Z; Zlatović, Mario V; Stojanović, Srđan Đ

    2016-06-01

    We analyzed the potential influence of anion-π interactions on the stability of complexes of proteins and halogen-containing non-natural amino acids. Anion-π interactions are distance and orientation dependent and our ab initio calculations showed that their energy can be lower than -8 kcal mol(-1), while most of their interaction energies lie in the range from -1 to -4 kcal mol(-1). About 20 % of these interactions were found to be repulsive. We have observed that Tyr has the highest occurrence among the aromatic residues involved in anion-π interactions, while His made the least contribution. Furthermore, our study showed that 67 % of total interactions in the dataset are multiple anion-π interactions. Most of the amino acid residues involved in anion-π interactions tend to be buried in the solvent-excluded environment. The majority of the anion-π interacting residues are located in regions with helical secondary structure. Analysis of stabilization centers for these complexes showed that all of the six residues capable of anion-π interactions are important in locating one or more of such centers. We found that anion-π interacting residues are sometimes involved in simultaneous interactions with halogens as well. With all that in mind, we can conclude that the anion-π interactions can show significant influence on molecular organization and on the structural stability of the complexes of proteins and halogen-containing non-natural amino acids. Their influence should not be neglected in supramolecular chemistry and crystal engineering fields as well. PMID:26910415

  5. Bilayer Beams and Relay Sharing based OFDMA Cellular Architecture

    Directory of Open Access Journals (Sweden)

    Yanxiong Pan

    2011-08-01

    Full Text Available Over the past decade, researchers have been putting a lot of energy on co-channel interference suppression in the forthcoming fourth generation (4G wireless networks. Existing approaches to interference suppression are mainly based on signal processing, cooperative communication or coordination techniques. Though good performance has been attained already, a more complex receiver is needed, and there is still room for improvement through other ways.Considering spatial frequency reuse, which provides an easier way to cope with the co-channel interference, this paper proposed a bilayer beams and relay sharing based (BBRS OFDMA cellular architecture and corresponding frequency planning scheme. The main features of the novel architecture are as follows. Firstly, the base station (BS uses two beams, one composed of six wide beams providing coverage to mobile stations (MSs that access to the BS, and the other composed of six narrow beams communicating with fixed relay stations (FRSs. Secondly, in the corresponding frequency planning scheme, soft frequency reuse is considered on all FRSs further. System-level simulation results demonstrate that better coverage performance is obtained and the mean data rate of MSs near the cell edge is improved significantly. The BBRS cellular architecture provides a practical method to interference suppression in 4G networks since a better tradeoff between performance and complexity is achieved.

  6. A quantum relay chip based on telecommunication integrated optics technology

    International Nuclear Information System (INIS)

    We investigate an integrated optical circuit on lithium niobate designed to implement a teleportation-based quantum relay scheme for one-way quantum communication at a telecom wavelength. Such an advanced quantum circuit merges for the first time both optical-optical and electro-optical nonlinear functions necessary for implementing the desired on-chip single-qubit teleportation. On the one hand, spontaneous parametric down-conversion is used to produce entangled photon pairs. On the other, we take advantage of two photon routers, consisting of electro-optically controllable couplers, to separate the paired photons and to carry out a Bell state measurement, respectively. After having validated all the individual functions in the classical regime, we performed a Hong-Ou-Mandel experiment to mimic a one-way quantum communication link. Such a quantum effect, seen as a prerequisite towards achieving teleportation, has been obtained at one of the routers when the chip was coupled to an external single-photon source. The two-photon interference pattern shows a net visibility of 80%, which validates the proof of principle of a ‘quantum relay circuit’ for qubits carried by telecom photons. In the case of optimized losses, such a chip could increase the maximal achievable distance of one-way quantum key distribution links by a factor of 1.8. Our approach and results emphasize the potential of integrated optics on lithium niobate as a key technology for future reconfigurable quantum information manipulation. (paper)

  7. Detecting relay attacks on RFID communication systems using quantum bits

    Science.gov (United States)

    Jannati, Hoda; Ardeshir-Larijani, Ebrahim

    2016-08-01

    RFID systems became widespread in variety of applications because of their simplicity in manufacturing and usability. In the province of critical infrastructure protection, RFID systems are usually employed to identify and track people, objects and vehicles that enter restricted areas. The most important vulnerability which is prevalent among all protocols employed in RFID systems is against relay attacks. Until now, to protect RFID systems against this kind of attack, the only approach is the utilization of distance-bounding protocols which are not applicable over low-cost devices such as RFID passive tags. This work presents a novel technique using emerging quantum technologies to detect relay attacks on RFID systems. Recently, it is demonstrated that quantum key distribution (QKD) can be implemented in a client-server scheme where client only requires an on-chip polarization rotator that may be integrated into a handheld device. Now we present our technique for a tag-reader scenario which needs similar resources as the mentioned QKD scheme. We argue that our technique requires less resources and provides lower probability of false alarm for the system, compared with distance-bounding protocols, and may pave the way to enhance the security of current RFID systems.

  8. Coded Cooperation for Multiway Relaying in Wireless Sensor Networks †

    Science.gov (United States)

    Si, Zhongwei; Ma, Junyang; Thobaben, Ragnar

    2015-01-01

    Wireless sensor networks have been considered as an enabling technology for constructing smart cities. One important feature of wireless sensor networks is that the sensor nodes collaborate in some manner for communications. In this manuscript, we focus on the model of multiway relaying with full data exchange where each user wants to transmit and receive data to and from all other users in the network. We derive the capacity region for this specific model and propose a coding strategy through coset encoding. To obtain good performance with practical codes, we choose spatially-coupled LDPC (SC-LDPC) codes for the coded cooperation. In particular, for the message broadcasting from the relay, we construct multi-edge-type (MET) SC-LDPC codes by repeatedly applying coset encoding. Due to the capacity-achieving property of the SC-LDPC codes, we prove that the capacity region can theoretically be achieved by the proposed MET SC-LDPC codes. Numerical results with finite node degrees are provided, which show that the achievable rates approach the boundary of the capacity region in both binary erasure channels and additive white Gaussian channels. PMID:26131675

  9. Coded Cooperation for Multiway Relaying in Wireless Sensor Networks.

    Science.gov (United States)

    Si, Zhongwei; Ma, Junyang; Thobaben, Ragnar

    2015-01-01

    Wireless sensor networks have been considered as an enabling technology for constructing smart cities. One important feature of wireless sensor networks is that the sensor nodes collaborate in some manner for communications. In this manuscript, we focus on the model of multiway relaying with full data exchange where each user wants to transmit and receive data to and from all other users in the network. We derive the capacity region for this specific model and propose a coding strategy through coset encoding. To obtain good performance with practical codes, we choose spatially-coupled LDPC (SC-LDPC) codes for the coded cooperation. In particular, for the message broadcasting from the relay, we construct multi-edge-type (MET) SC-LDPC codes by repeatedly applying coset encoding. Due to the capacity-achieving property of the SC-LDPC codes, we prove that the capacity region can theoretically be achieved by the proposed MET SC-LDPC codes. Numerical results with finite node degrees are provided, which show that the achievable rates approach the boundary of the capacity region in both binary erasure channels and additive white Gaussian channels. PMID:26131675

  10. Coded Cooperation for Multiway Relaying in Wireless Sensor Networks

    Directory of Open Access Journals (Sweden)

    Zhongwei Si

    2015-06-01

    Full Text Available Wireless sensor networks have been considered as an enabling technology for constructing smart cities. One important feature of wireless sensor networks is that the sensor nodes collaborate in some manner for communications. In this manuscript, we focus on the model of multiway relaying with full data exchange where each user wants to transmit and receive data to and from all other users in the network. We derive the capacity region for this specific model and propose a coding strategy through coset encoding. To obtain good performance with practical codes, we choose spatially-coupled LDPC (SC-LDPC codes for the coded cooperation. In particular, for the message broadcasting from the relay, we construct multi-edge-type (MET SC-LDPC codes by repeatedly applying coset encoding. Due to the capacity-achieving property of the SC-LDPC codes, we prove that the capacity region can theoretically be achieved by the proposed MET SC-LDPC codes. Numerical results with finite node degrees are provided, which show that the achievable rates approach the boundary of the capacity region in both binary erasure channels and additive white Gaussian channels.

  11. Speed of light exceeded in 31st CERN Relay

    CERN Multimedia

    2001-01-01

    In the closest-ever finish of the CERN relay race, Florian Marinet (number 54) of the Neutrinos to Gran Sasso team just fails to catch Pierre Maesen of The Shabbys on the line. The AThLetic AceS team (number 76) won the Veterans category by just 3 seconds from long-time participants The Lynx Runners, who didn't leave empty handed. They picked up the cup that is drawn at random. Evidence for new physics? No, simply evidence for faster legs. Only at CERN could the speed of light come third to a team called The Shabbys. But that's exactly what happened on Wednesday 23 May when the team from PS Division lifted the Opitz cup after winning the 31st CERN relay race. The Shabbys sped home in 10 minutes 53 seconds, just 0.3 of a second ahead of the 'Neutrinos to Gran Sasso' team. There's some logic there since it is the PS complex that will provide the protons that will give rise to the neutrino beam. As for 'c0 the speed of light', they took a relatively leisurely 11 minutes 1.6 seconds to cover the course. A total...

  12. CERN Relay Race: No records broken in a bumper year

    CERN Multimedia

    2007-01-01

    Tribute is paid to David Dallman, 20 times the organiser of the CERN Relay Race, who is now retiring.Solve the following mathematical problem for athletes: take the first and third-placed teams in the 2006 CERN Relay Race, randomly mix the runners to form two new teams, and what is the result? Answer: first place and fifth place. In short, the team which has reigned supreme in first place since 2001, the "Shabbys", decided to spice up the race this year by merging with their arch rivals, the "Latinos Volantes", themselves no strangers to the podium. And at the winning line, it was the hybrid formation, "Shabbys Volantes", which took the honours (no surprises there!). Sadly, they were unable to beat the Shabbys’ previous record nor get anywhere near the all-time race record of 10 minutes and 13 seconds for the 3.9-km course, held for a quarter of a century by the "UA1 Strollers". One of the members of that legendary team and race organiser 20 times, David Dallman, mar...

  13. Distribution Line Protection Relaying Scheme Based on Complex Number Operation

    Science.gov (United States)

    Tsuji, Kouichi

    In Japan, operational principles from the mechanical-type era, such as the directional ground relay (DG) and overcurrent relay (OC), are still used without modification for the protection of distribution lines. We are now facing various problems, such as ground faults with high fault resistance in systems isolated from the ground. A new operational principle to solve the above problems is summarized below. ·A fault is simulated by replacing a branched distribution line with a one-section single distribution line, in which loads are concentrated at its terminals. ·Lines with a one-line to ground fault are detected on the basis of the relationship between the fault-phase voltage E before the fault and the fault current using Ho and Thevenin's theorem. ·Faults are assumed to occur at both terminals in the section. If the signs of the obtained fault reactance Xf at the two terminals are opposite, it is judged that a fault point where Xf = 0 holds exists within the section. As a result of the simulation using the program we developed, it was confirmed that no errors in the detection of the internal and external ground faults with a high fault resistance of 0-30kΩ were observed.

  14. Energy-efficient Power Allocation Strategy in Cognitive Relay Networks

    Directory of Open Access Journals (Sweden)

    Z. Zhang

    2012-09-01

    Full Text Available Cognitive radio and cooperative technique are two essential techniques for the future generation green communication paradigm owing to its inherent advantages of adaptability and cognition. Typically, previous studies on power allocation in the cognitive relay networks often concentrate on two goals independently: the first goal is to minimize the transmit power to reduce energy consumption, as depicted in strategy 1; the second goal is to maximize the transmit rate, as depicted in strategy 2. In this paper, we shift our focus to energy-efficient-oriented design, that is, green power allocation between source and relay. Therefore, we present a novel power allocation strategy considering the two goals jointly, as depicted in strategy 3, and compare the proposed strategy with two previous strategies. Specifically, because the strategy 3 is nonlinear, we use the Lagrange dual method to solve it effectively. Finally, the numerical results are presented to validate our theoretical results through theory simulation and Monte Carlo simulation. Numerical performance results show that the proposed strategy works better than that of the two previous strategies from the viewpoints of energy-efficient.

  15. Polar On-Line Acquisition Relay and Transmission System (POLARATS)

    Energy Technology Data Exchange (ETDEWEB)

    Yuracko, K.

    2004-07-15

    POLARATS (Polar On-Line Acquisition Relay And Transmission System) is being developed by YAHSGS LLC (YAHSGS) and Oak Ridge National Laboratory (ORNL) to provide remote, unattended monitoring of environmental parameters under harsh environmental conditions. In particular, instrumental design and engineering is oriented towards protection of human health in the Arctic, and with the additional goal of advancing Arctic education and research. POLARATS will obtain and transmit environmental data from hardened monitoring devices deployed in locations important to understanding atmospheric and aquatic pollutant migration as it is biomagnified in Arctic food chains. An Internet- and personal computer (PC)-based educational module will provide real time sensor data, on-line educational content, and will be integrated with workbooks and textbooks for use in middle and high school science programs. The educational elements of POLARATS include an Internet-based educational module that will instruct students in the use of the data and how those data fit into changing Arctic environments and food chains. POLARATS will: (1) Enable students, members of the community, and scientific researchers to monitor local environmental conditions in real time over the Internet; and (2) Provide additional educational benefits through integration with middle- and high-school science curricula. Information will be relayed from POLARATS devices to classrooms and libraries along with custom-designed POLARATS teaching materials that will be integrated into existing curricula to enhance the educational benefits realized from the information obtained.

  16. Impact of Distributed Generation on Relay Protections of Distribution Grid

    Directory of Open Access Journals (Sweden)

    Zhou Bin

    2013-06-01

    Full Text Available Distributed Generation (DG generates electricity from many small distributed energy sources or even customer’s small power plants. It always comes up with the terminal customer power quality management and the technology of energy cascade utilization. DG has lots of characteristics such as one single point of access, being power and being load, two operating mode in a grid or as an island, a great deal of application of power electronic devices, easily influenced by natural environmental factors etc. DG has impacts to the original grid in terms of the grid structure, the direction of power flow, the fault current level when a fault happens, etc and subsequently the relay protection mechanism must be looked into. This paper analyses the impact of accessing the DG on the distributed grid in three cases which are the DG accessing to the end of the distributed feeders, to the middle, and the DG accessing to lines, on relay protections. At the end of the paper it also comes up with improvements in detail.

  17. Three Generations of Tracking and Data Relay Satellite (TDRS) Spacecraft

    Science.gov (United States)

    Zaleski, Ron

    2016-01-01

    The current Tracking and Data Relay Satellite configuration consists of nine in-orbit satellites (four first generation, three second generation and two third generation satellites) globally distributed in geosynchronous orbit to provide near continuous data relay service to missions like Hubble Space Telescope and the International Space Station. The 1st generation spacecraft were designed by TRW/Northrop Grumman with their launches of the five spacecraft ranging from 1983 through 1995. The 2nd and 3rd generation spacecraft were designed by Boeing with their launches ranging 2000 - 2002 and 2013 - 2017 respectively. TDRS-3 is now 27 years on orbit, continues to be a capable asset for the TDRS constellation. Lack of need for inclination control combined with large fuel reserves and redundancy on critical elements provides spacecraft that operate well past design life, all of which contributes to expanded TDRS constellation support capabilities. All spacecraft generations have issues. Significant issues will be summarized with the focus on the Boeing related problems. Degradations and failures are continually assessed and provide the foundation for yearly updates to spacecraft reliability models, constellation service projections and deorbit plans (in order to meet NASAs mandate of limiting orbital debris). Even when accounting for degradations and failures, the life expectancy for the Boeing delivered 2nd generation TDRS-8, 9 10 TDRS are anticipated to be 25+ years.

  18. Environmental behavior of inorganic anions

    International Nuclear Information System (INIS)

    Recent efforts have addressed two aspects of anion behavior in the soil/plant system. The first involves evaluation of the gaseous component of the terrestrial iodine cycle in soils and plants. Field analyses of 129I in soils and vegetation adjacent to a fuels reprocessing facility, which was idle for 10 years prior to the study, indicated that there may be a significant gaseous component to the terrestrial iodine cycle. Soil substrates, including a silt-sand, organic forest soil, quartz sand, and a sterilized soil, were amended with radioiodide, and the rates and quality of the volatile components evaluated

  19. Protection and relay planning in electric power systems on the West Bank

    International Nuclear Information System (INIS)

    This article describes a process for skills upgrading in relay engineers at a network company on the West Bank. The article also discusses selected topics from protection theory and describes briefly some methods for relay planning and documentation that also apply to other network companies

  20. Improving throughput of single-relay DF channel using linear constellation precoding

    KAUST Repository

    Fareed, Muhammad Mehboob

    2014-08-01

    In this letter, we propose a transmission scheme to improve the overall throughput of a cooperative communication system with single decode-and-forward relay. Symbol error rate and throughput analysis of the new scheme are presented to facilitate the performance comparison with the existing decode-and-forward relaying schemes. Simulation results are further provided to corroborate the analytical results. © 2012 IEEE.

  1. Relay-aided multi-cell broadcasting with random network coding

    DEFF Research Database (Denmark)

    Lu, Lu; Sun, Fan; Xiao, Ming;

    2010-01-01

    We investigate a relay-aided multi-cell broadcasting system using random network codes, where the focus is on devising efficient scheduling algorithms between relay and base stations. Two scheduling algorithms are proposed based on different feedback strategies; namely, a one-step scheduling...

  2. On the benefits of location-based relay selection in mobile wireless networks

    DEFF Research Database (Denmark)

    Nielsen, Jimmy Jessen; Madsen, Tatiana Kozlova; Schwefel, Hans-Peter

    2016-01-01

    We consider infrastructure-based mobile networks that are assisted by a single relay transmission where both the downstream destination and relay nodes are mobile. Selecting the optimal transmission path for a destination node requires up-to-date link quality estimates of all relevant links. If the...

  3. Optimized Policies for Improving Fairness of Location-based Relay Selection

    DEFF Research Database (Denmark)

    Nielsen, Jimmy Jessen; Olsen, Rasmus Løvenstein; Madsen, Tatiana Kozlova;

    2013-01-01

    For WLAN systems in which relaying is used to improve throughput performance for nodes located at the cell edge, node mobility and information collection delays can have a significant impact on the performance of a relay selection scheme. In this paper we extend our existing Markov Chain modeling...

  4. Best relay selection using SNR and interference quotient for underlay cognitive networks

    KAUST Repository

    Hussain, Syed Imtiaz

    2012-06-01

    Cognitive networks in underlay settings operate simultaneously with the primary networks satisfying stringent interference limits. This condition forces them to operate with low transmission powers and confines their area of coverage. In an effort to reach remote destinations, underlay cognitive sources make use of relaying techniques. Selecting the best relay among those who are ready to cooperate is different in underlay settings than traditional non-cognitive networks. In this paper, we present a relay selection scheme which uses the quotient of the relay link signal to noise ratio (SNR) and the interference generated from the relay to the primary user to choose the best relay. The proposed scheme optimizes this quotient in a way to maximize the relay link SNR above a certain value whereas the interference is kept below a defined threshold. We derive closed expressions for the outage probability and bit error probability of the system incorporating this scheme. Simulation results confirm the validity of the analytical results and reveal that the relay selection in cognitive environment is feasible in low SNR regions. © 2012 IEEE.

  5. Distributed Generalized Low-Density Codes for Multiple Relay Cooperative Communications

    Directory of Open Access Journals (Sweden)

    Han Changcai

    2008-01-01

    Full Text Available As a class of pseudorandom error correcting codes, generalized low-density (GLD codes exhibit excellent performance over both additive white Gaussian noise (AWGN and Rayleigh fading channels. In this paper, distributed GLD codes are proposed for multiple relay cooperative communications. Specifically, using the partial error detecting and error correcting capabilities of the GLD code, each relay node decodes and forwards some of the constituent codes of the GLD code to cooperatively form a distributed GLD code, which can work effectively and keep a fixed overall code rate when the number of relay nodes varies. Also, at relay nodes, a progressive processing procedure is proposed to reduce the complexity and adapt to the source-relay channel variations. At the destination, the soft information from different paths is combined for the GLD decoder thus diversity gain and coding gain are achieved simultaneously. Simulation results verify that distributed GLD codes with various number of relay nodes can obtain significant performance gains in quasistatic fading channels compared with the strategy without relays and the performance is further improved when more relays are employed.

  6. STUDI ANALISIS SETTING RELAY PENGAMAN DI PENYULANG NGURAH RAI I DAN PENYULANG NGURAH RAI II

    Directory of Open Access Journals (Sweden)

    I Komang Sutarjana

    2015-03-01

    Full Text Available Permasalahan gangguan di jaringan distribusi 20 kV seringkali menyebabkan terputusnya pasokan daya listrik kepada pelanggan. Salah satu penyebab keandalan sistem kurang baik adalah kesalahan koordinasi setting relay pada penyulang. Seperti yang terjadi pada penyulang Ngurah Rai I dan Penyulang Ngurah Rai II dimana terdapat kesalahan koordinasi setting antara relay pada pangkal penyulang yang terletak di Gardu Induk (GI dengan relay pada di ujung jaringan yang terletak di Gardu Hubung (GH. Untuk memecahkan masalah tersebut maka perlu dianalisis setting relay yang sudah ada (eksisting. Untuk membuktikan koordinasi setting relay sudah sempurna, maka akan dilakukan simulasi menggunakan bantuan program computer yaitu Electrical Transient Analysis Program (ETAP. Dari hasil analisis diperoleh nilai setting dimulai dari setting Over Current Relay (OCR pada pangkal penyulang (GI 360 A dan Tms 0,36 sedangkan untuk nilai setting arus OCR pada ujung penyulang (GH yang menggunakan relay directional 330 A dan TMS 0,16. Kemudian untuk setting GFR pada pangkal penyulang (GI diperoleh nilai 34 A dan TMS 0,2. Sedangkan setting GFR pada ujung penyulang (GH yang menggunakan relay directional diperoleh nilai 31 A dan TMS 0,1.

  7. Radiation Chemistry

    Science.gov (United States)

    Wojnárovits, L.

    Ionizing radiation causes chemical changes in the molecules of the interacting medium. The initial molecules change to new molecules, resulting in changes of the physical, chemical, and eventually biological properties of the material. For instance, water decomposes to its elements H2 and O2. In polymers, degradation and crosslinking take place. In biopolymers, e.g., DNS strand breaks and other alterations occur. Such changes are to be avoided in some cases (radiation protection), however, in other cases they are used for technological purposes (radiation processing). This chapter introduces radiation chemistry by discussing the sources of ionizing radiation (radionuclide sources, machine sources), absorption of radiation energy, techniques used in radiation chemistry research, and methods of absorbed energy (absorbed dose) measurements. Radiation chemistry of different classes of inorganic (water and aqueous solutions, inorganic solids, ionic liquids (ILs)) and organic substances (hydrocarbons, halogenated compounds, polymers, and biomolecules) is discussed in concise form together with theoretical and experimental backgrounds. An essential part of the chapter is the introduction of radiation processing technologies in the fields of polymer chemistry, food processing, and sterilization. The application of radiation chemistry to nuclear technology and to protection of environment (flue gas treatment, wastewater treatment) is also discussed.

  8. Research on electromagnetic relay's dynamic characteristics disturbed by uniform static magnetic field

    Institute of Scientific and Technical Information of China (English)

    Guo-fu ZHAI; Qi-ya WANG; Wan-bin REN

    2008-01-01

    Electromagnetic relay is a widely used apparatus which usually works in a magnetic disturbance environment. To evaluate its electromagnetic compatibility (EMC) in a static magnetic field, dynamic characteristics of a clapper relay in a uniform static magnetic field situation based on the finite element method (FEM) is studied. Influences of the magnetic field on dynamic parameters (delay time, pick-up time, end pressure, and final velocity) as well as a situation in which the relay cannot function normally are analyzed. Simulation reveals that the external magnetic field which weakens the relay's air-gap field has a greater influence on the relay's dynamic parameters than the one strengthening the field. The validity of the simulation is verified by measured results of coil current and armature displacement.

  9. Detect-and-forward in two-hop relay channels: a metrics-based analysis

    KAUST Repository

    Benjillali, Mustapha

    2010-06-01

    In this paper, we analyze the coded performance of a cooperative system with multiple parallel relays using "Detect-and-Forward" (DetF) strategy where each relay demodulates the overheard signal and forwards the detected binary words. The proposed method is based on the probabilistic characterization of the reliability metrics given under the form of L-values. First, we derive analytical expressions of the probability density functions (PDFs) of the L-values in the elementary two-hop DetF relay channel with different source-relay channel state information assumptions. Then, we apply the obtained expressions to calculate the theoretically achievable rates and compare them with the practical throughput of a simulated turbo-coded transmission. Next, we derive tight approximations for the end-to-end coded bit error rate (BER) of a general cooperative scheme with multiple parallel relays. Simulation results demonstrate the accuracy of our derivations for different cooperation configurations and conditions. © 2010 IEEE.

  10. Performance Enhancement of LTE, a Multi-Hop Relay Node, by Employing Half-Duplex Mode

    Directory of Open Access Journals (Sweden)

    Jaafar Adhab Al-Dhaiban

    2012-05-01

    Full Text Available Relay stations are usually used to improve the signal strength for users near a cell edge, thus extending cell coverage. This paper proposes a study on the performance of a multi-hop relay network. This work introduces half-duplex relay with two scenarios. The first scenario is that wherein the relay node (RN acts to amplify and forward (AF and decode and forward (DF, where the relay and user equipment (UE are fixed. The second scenario is that wherein the proposed UE moves with angular velocity around RN, whereas RN moves with horizontal velocity toward the base station (BS and UE. The performance measures of each scenario are represented, where the impact velocity on the latency time and system capacity is explained. Both simulation and analytical calculations are provided.

  11. Performance analysis of two-way amplify and forward relaying with adaptive modulation

    KAUST Repository

    Hwang, Kyusung

    2009-09-01

    In this paper, we study two-way amplify-and-forward relaying in conjunction with adaptive modulation over a multiple relay network. In order to keep the diversity order equal to the number of relays and maintain a low complexity, we consider the best relay selection scheme in this work. Based on the proposed selection criterion for the best relay, we analyze the average spectral efficiency by its approximated upper bound. In addition, we extend the proposed scheme to the case where a direct path between source and destination exists. Our numerical examples show that the proposed system offers a considerable gain in the spectral efficiency while satisfying the error rates requirements. ©2009 IEEE.

  12. An aging assessment of relays and circuit breakers and system interactions

    International Nuclear Information System (INIS)

    This report provides an assessment of the aging of circuit breakers and relays which are vital components of the nuclear power plant electrical safety system, and was conducted under the auspices of the NRC Nuclear Aging Research (NPAR) Program. The study included protective, control, and logic relays, and molded-case and metal-clad switchgear circuit breakers. The relay failures were attributable to coil deterioration, changes in dimensions of critical organic components, and changes in characteristics of timing diaphragms from thermal deterioriation. Some of the failure modes will prevent fail-safe operation. The electrical control and mechanical portions of metal-clad switchgear were found to be more failure prone than the main contacts and arc extinguishing systems. Circuit breakers and relays in a PWR safety injection system were evaluated with respect to the aging induced by system operation. The effect of circuit breaker and relay deterioration on the ability of the system to perform its safety functions was also evaluated

  13. Optimal Resource Allocation and Relay Selection in Bandwidth and Time Exchange Based Cooperative Forwarding

    CERN Document Server

    Islam, Muhammad Nazmul; Kompella, Sastry

    2011-01-01

    In this paper, we investigate joint optimal relay selection and resource allocation that are fundamental to the understanding of bandwidth exchange (BE) and time exchange (TE) enabled incentivized cooperative forwarding in wireless networks. We consider a network where N nodes transmit data in the uplink to an access point (AP) or base station (BS). We first consider the scenario where each node gets an initial amount (equal, optimal or arbitrary) of resource in the form of bandwidth or time, and uses this resource as a flexible incentive for two hop relaying. We focus on ?-fair network utility maximization (NUM) and total power minimization in this environment. For both BE and TE, we show the concavity or convexity of the resource allocation problem for a fixed relay set. Defining the link weights of each relay pair as the utility gain due to cooperation (over noncooperation), we show that the optimal relay selection, often a combinatorially cumbersome problem, reduces to the maximum weighted matching (MWM) ...

  14. Optimization Framework and Graph-Based Approach for Relay-Assisted Bidirectional OFDMA Cellular Networks

    CERN Document Server

    Liu, Yuan; Li, Bin; Shen, Hui

    2010-01-01

    This paper considers a relay-assisted bidirectional cellular network where the base station (BS) communicates with each mobile station (MS) using OFDMA for both uplink and downlink. The goal is to improve the overall system performance by exploring the full potential of the network in various dimensions including user, subcarrier, relay, and bidirectional traffic. In this work, we first introduce a novel three-time-slot time-division duplexing (TDD) transmission protocol. This protocol unifies direct transmission, one-way relaying and network-coded two-way relaying between the BS and each MS. Using the proposed three-time-slot TDD protocol, we then propose an optimization framework for resource allocation to achieve the following gains: cooperative diversity (via relay selection), network coding gain (via bidirectional transmission mode selection), and multiuser diversity (via subcarrier assignment). We formulate the problem as a combinatorial optimization problem, which is NP-complete. To make it more tracta...

  15. Joint Power and Resource Allocation for Block-Fading Relay-Assisted Broadcast Channels

    CERN Document Server

    Shaqfeh, Mohammad

    2012-01-01

    We provide the solution for optimizing the power and resource allocation over block-fading relay-assisted broadcast channels in order to maximize the long term average achievable rates region of the users. The problem formulation assumes regenerative (repetition coding) decode-and-forward (DF) relaying strategy, long-term average total transmitted power constraint, orthogonal multiplexing of the users messages within the channel blocks, possibility to use a direct transmission (DT) mode from the base station to the user terminal directly or a relaying (DF) transmission mode, and partial channel state information. We show that our optimization problem can be transformed into an equivalent "no-relaying" broadcast channel optimization problem with each actual user substituted by two virtual users having different channel qualities and multiplexing weights. The proposed power and resource allocation strategies are expressed in closed-form that can be applied practically in centralized relay-assisted wireless netw...

  16. Cooperation schemes for rate enhancement in detect-and-forward relay channels

    KAUST Repository

    Benjillali, Mustapha

    2010-05-01

    To improve the spectral efficiency of "Detect-and-Forward" (DetF) half-duplex relaying in fading channels, we propose a cooperation scheme where the relay uses a modulation whose order is higher than the one at the source. In a new common framework, we show that the proposed scheme offers considerable gains - in terms of achievable information rates - compared to the conventional DetF relaying schemes for both orthogonal and non-orthogonal source/relay cooperation. This allows us to propose an adaptive cooperation scheme based on the maximization of the information rate at the destination which needs to observe only the average signal-to-noise ratios of direct and relaying links. ©2010 IEEE.

  17. A joint time-invariant filtering approach to the linear Gaussian relay problem

    CERN Document Server

    Kim, Cheulsoon; Lee, Yong H

    2011-01-01

    In this paper, the linear Gaussian relay problem is considered. Under the linear time-invariant (LTI) model the problem is formulated in the frequency domain based on the Toeplitz distribution theorem. Under the further assumption of realizable input spectra, the LTI Gaussian relay problem is converted to a joint design problem of source and relay filters under two power constraints, one at the source and the other at the relay, and a practical solution to this problem is proposed based on the projected subgradient method. Numerical results show that the proposed method yields a noticeable gain over the instantaneous amplify-and-forward (AF) scheme in inter-symbol interference (ISI) channels. Also, the optimality of the AF scheme within the class of one-tap relay filters is established in flat-fading channels.

  18. Combined Decode-Forward and Layered Noisy Network Coding Schemes for Relay Channels

    CERN Document Server

    Zhong, Peng

    2012-01-01

    We propose two coding schemes combining decode-forward (DF) and noisy network coding (NNC) with different flavors. The first is a combined DF-NNC scheme for the one-way relay channel which includes both DF and NNC as special cases by performing rate splitting, partial block Markov encoding and NNC. The second combines two different DF strategies and layered NNC for the two-way relay channel. One DF strategy performs coherent block Markov encoding at the source at the cost of power splitting at the relay, the other performs independent source and relay encoding but with full relay power, and layered NNC allows a different compression rate for each destination. Analysis and simulation show that both proposed schemes supersede each individual scheme and take full advantage of both DF and NNC.

  19. A study of optimization problem for amplify-and-forward relaying over weibull fading channels

    KAUST Repository

    Ikki, Salama Said

    2010-09-01

    This paper addresses the power allocation and relay positioning problems in amplify-and-forward cooperative networks operating in Weibull fading environments. We study adaptive power allocation (PA) with fixed relay location, optimal relay location with fixed power allocation, and joint optimization of the PA and relay location under total transmit power constraint, in order to minimize the outage probability and average error probability at high signal-to-noise ratios (SNR). Analytical results are validated by numerical simulations and comparisons between the different optimization schemes and their performance are provided. Results show that optimum PA brings only coding gain, while optimum relay location yields, in addition to the latter, diversity gains as well. Also, joint optimization improves both, the diversity gain and coding gain. Furthermore, results illustrate that the analyzed adaptive algorithms outperform uniform schemes. ©2010 IEEE.

  20. On achievable rates of interference and cognitive channels with a relay

    KAUST Repository

    Zorgui, Marwen

    2015-08-30

    We consider a two-user interference channel assisted by a relay. Treating interference as noise at the receivers, and adopting an amplify and forward (AF) strategy at the relay, we derive achievable rates of both users, for given powers. Next, we solve the optimal power allocation problem maximizing the weighted sum rate of both users with and without relay power optimization. In particular, we propose a simple iterative line search algorithm solving the joint optimization problem over the three transmit powers and show that optimizing the relay power enhances the performance of the system. Then, considering the first user as a primary user, we determine the maximum instantaneous rate that the secondary user can achieve subject to an outage constraint with respect to the primary user and a peak power constraint. We show that, likewise the first part, jointly optimizing the secondary user and the relay transmit powers enhances the secondary user performance.

  1. Cooperative joint precoding in a downlink cellular system with shared relay: Design and performance evaluation

    KAUST Repository

    Kwon, JaeWoo

    2012-10-01

    In this paper, we investigate a relay enhanced cellular system, where a relay station is located in the overlap area served by two base stations. We propose cooperative joint precoding schemes for the downlink transmission of such relay enhanced cellular system to maximize the system capacity while minimizing the interference at both the relay station and the mobile stations. We formulate the optimization problems to maximize the system capacity and design the multiuser precoding vectors at each base station and the relay station. We quantify the ergodic rate performance of the proposed multiuser precoding schemes through statistical analysis. The extensively derived ergodic expressions will facilitate the accurate performance evaluation of the proposed transmission schemes. Numerical results show that the proposed schemes can effectively cancel the interference and improve the sum rate and the outage performance for cell edge users. © 2002-2012 IEEE.

  2. Error-rate performance analysis of cooperative OFDMA system with decode-and-forward relaying

    KAUST Repository

    Fareed, Muhammad Mehboob

    2014-06-01

    In this paper, we investigate the performance of a cooperative orthogonal frequency-division multiple-access (OFDMA) system with decode-and-forward (DaF) relaying. Specifically, we derive a closed-form approximate symbol-error-rate expression and analyze the achievable diversity orders. Depending on the relay location, a diversity order up to (LSkD + 1) + σ M m = 1 min(LSkRm + 1, LR mD + 1) is available, where M is the number of relays, and LS kD + 1, LSkRm + 1, and LRmD + 1 are the lengths of channel impulse responses of source-to-destination, source-to- mth relay, and mth relay-to-destination links, respectively. Monte Carlo simulation results are also presented to confirm the analytical findings. © 2013 IEEE.

  3. Production and chemistry of transactinide elements

    International Nuclear Information System (INIS)

    Recent progress in production and chemistry of the transactinide elements, element 107 bohrium (Bh) and element 104 rutherfordium (Rf), is reviewed. First information on chemical properties of Bh was obtained in gas chromatographic experiments on an atom-at-a-time basis. Chemical separation and characterization of 6 atoms of 267Bh produced in the bombardment of a 249Bk target with 22Ne beams are outlined. Aqueous chemistry of Rf being performed at JAERI (Japan Atomic Energy Research Institute) is briefly summarized. On-line anion-exchange experiments in acidic solutions on 261Rf produced in the 248Cm(18O,5n) reaction were conducted with a rapid ion-exchange separation apparatus. Characteristic anion-exchange behavior of Rf is discussed. (author)

  4. Quantum chemistry

    CERN Document Server

    Lowe, John P

    2006-01-01

    Lowe's new edition assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry. It can serve as a primary text in quantum chemistry courses, and enables students and researchers to comprehend the current literature. This third edition has been thoroughly updated and includes numerous new exercises to facilitate self-study and solutions to selected exercises.* Assumes little initial mathematical or physical sophistication, developing insights and abilities in the context of actual problems* Provides thorough treatment

  5. Polymer Chemistry

    Science.gov (United States)

    Williams, Martha; Roberson, Luke; Caraccio, Anne

    2010-01-01

    This viewgraph presentation describes new technologies in polymer and material chemistry that benefits NASA programs and missions. The topics include: 1) What are Polymers?; 2) History of Polymer Chemistry; 3) Composites/Materials Development at KSC; 4) Why Wiring; 5) Next Generation Wiring Materials; 6) Wire System Materials and Integration; 7) Self-Healing Wire Repair; 8) Smart Wiring Summary; 9) Fire and Polymers; 10) Aerogel Technology; 11) Aerogel Composites; 12) Aerogels for Oil Remediation; 13) KSC's Solution; 14) Chemochromic Hydrogen Sensors; 15) STS-130 and 131 Operations; 16) HyperPigment; 17) Antimicrobial Materials; 18) Conductive Inks Formulations for Multiple Applications; and 19) Testing and Processing Equipment.

  6. Novel anion exchange polymer membranes

    Czech Academy of Sciences Publication Activity Database

    Žitka, Jan; Schauer, Jan; Bleha, M.; Hnát, J.; Bouzek, K.

    Praha : Orgit, 2012. s. 50. ISBN 978-80-905035-2-6. [Electromembrane Processes and Materials - ELMEMPRO 2012, Satellite Meeting of The International Society of Electrochemistry Annual Meeting /63./. 26.08.2012-29.08.2012, Český Krumlov] Institutional research plan: CEZ:AV0Z40500505 Keywords : AEM * alkaline electrolysis Subject RIV: CD - Macromolecular Chemistry

  7. Network Code Design for Orthogonal Two-hop Network with Broadcasting Relay: A Joint Source-Channel-Network Coding Approach

    OpenAIRE

    Joda, Roghayeh; Lahouti, Farshad

    2010-01-01

    This paper addresses network code design for robust transmission of sources over an orthogonal two-hop wireless network with a broadcasting relay. The network consists of multiple sources and destinations in which each destination, benefiting the relay signal, intends to decode a subset of the sources. Two special instances of this network are orthogonal broadcast relay channel and the orthogonal multiple access relay channel. The focus is on complexity constrained scenarios, e.g., for wirele...

  8. Novel Material Integration for Reliable and Energy-Efficient NEM Relay Technology

    Science.gov (United States)

    Chen, I.-Ru

    Energy-efficient switching devices have become ever more important with the emergence of ubiquitous computing. NEM relays are promising to complement CMOS transistors as circuit building blocks for future ultra-low-power information processing, and as such have recently attracted significant attention from the semiconductor industry and researchers. Relay technology potentially can overcome the energy efficiency limit for conventional CMOS technology due to several key characteristics, including zero OFF-state leakage, abrupt switching behavior, and potentially very low active energy consumption. However, two key issues must be addressed for relay technology to reach its full potential: surface oxide formation at the contacting surfaces leading to increased ON-state resistance after switching, and high switching voltages due to strain gradient present within the relay structure. This dissertation advances NEM relay technology by investigating solutions to both of these pressing issues. Ruthenium, whose native oxide is conductive, is proposed as the contacting material to improve relay ON-state resistance stability. Ruthenium-contact relays are fabricated after overcoming several process integration challenges, and show superior ON-state resistance stability in electrical measurements and extended device lifetime. The relay structural film is optimized via stress matching among all layers within the structure, to provide lower strain gradient (below 10E-3/microm -1) and hence lower switching voltage. These advancements in relay technology, along with the integration of a metallic interconnect layer, enable complex relay-based circuit demonstration. In addition to the experimental efforts, this dissertation theoretically analyzes the energy efficiency limit of a NEM switch, which is generally believed to be limited by the surface adhesion energy. New compact (<1 microm2 footprint), low-voltage (<0.1 V) switch designs are proposed to overcome this limit. The results

  9. Electron transfer in dinucleoside phosphate anions

    International Nuclear Information System (INIS)

    The electron transfer reaction within various dinucleoside phosphate radical anions has been investigated by ESR spectroscopy and pulse radiolysis. In the ESR work electrons are produced by photolysis of K4Fe(CN)6 in a 12 M LiCl glass at 770K. Upon photobleaching the electrons react with the dinucleoside phosphate to form the anion radical. The anions of the four DNA nucleosides were also produced and their ESR spectra were appropriately weighted and summed by computer to simulate the spectra found for the dinucleoside phosphate anions. From the analysis the relative amounts of each of the nucleoside anions in the dinucleoside phosphate anion were determined. Evidence suggests the electron affinity of the pyrimidine bases are greater than the purine bases; however, the results are not sufficient to distinguish between the individual purine or pyrimidine. When dinucleoside phosphate anions containing thymidine are warmed, protonation occurs only on thymine to produce the well known ''thymyl'' spectrum. Pulse radiolysis experiments on individual nucleotides (TMP, dAMP), mixtures of these nucleotides and the dinucleoside phosphate, TdA, in aqueous solution at room temperature show that in the TdA anion electron transfer occurs from adenine to thymine, whereas no electron transfer is found for mixtures of individual nucleotides. Protonation is found to occur only on thymine in the TdA anion in agreement with the ESR results

  10. Organic chemistry

    International Nuclear Information System (INIS)

    The activities of the mycotoxin research group are discussed. This includes the isolation and structure determination of mycotoxins, plant products, the biosyntheris of mycotoxins, the synthesis and characteristics of steroids, the synthesis and mechanistic aspects of heterocyclic chemistry and the functionality of steroids over long distances. Nmr spectra and mass spectroscopy are some of the techniques used

  11. Reinventing Chemistry

    OpenAIRE

    Whitesides, George McClelland

    2015-01-01

    Chemistry is in a period of change, from an era focused on molecules and reactions, to one in which manipulations of systems of molecules and reactions will be essential parts of controlling larger systems. This Essay traces paths from the past to possible futures.

  12. Chemistry Notes

    Science.gov (United States)

    School Science Review, 1972

    1972-01-01

    Short articles on the kinetics of the hydrogen peroxide-iodide ion reaction, simulation of fluidization catalysis, the use of Newman projection diagrams to represent steric relationships in organic chemistry, the use of synthetic substrates for proteolytic enzyme reactions, and two simple clock reactions"--hydrolysis of halogenoalkanes and…

  13. The Anion Gap is a Predictive Clinical Marker for Death in Patients with Acute Pesticide Intoxication.

    Science.gov (United States)

    Lee, Sun-Hyo; Park, Samel; Lee, Jung-Won; Hwang, Il-Woong; Moon, Hyung-Jun; Kim, Ki-Hwan; Park, Su-Yeon; Gil, Hyo-Wook; Hong, Sae-Yong

    2016-07-01

    Pesticide formulation includes solvents (methanol and xylene) and antifreeze (ethylene glycol) whose metabolites are anions such as formic acid, hippuric acid, and oxalate. However, the effect of the anion gap on clinical outcome in acute pesticide intoxication requires clarification. In this prospective study, we compared the anion gap and other parameters between surviving versus deceased patients with acute pesticide intoxication. The following parameters were assessed in 1,058 patients with acute pesticide intoxication: blood chemistry (blood urea nitrogen, creatinine, glucose, lactic acid, liver enzymes, albumin, globulin, and urate), urinalysis (ketone bodies), arterial blood gas analysis, electrolytes (Na(+), K(+), Cl(-) HCO3 (-), Ca(++)), pesticide field of use, class, and ingestion amount, clinical outcome (death rate, length of hospital stay, length of intensive care unit stay, and seriousness of toxic symptoms), and the calculated anion gap. Among the 481 patients with a high anion gap, 52.2% had a blood pH in the physiologic range, 35.8% had metabolic acidosis, and 12.1% had acidemia. Age, anion gap, pesticide field of use, pesticide class, seriousness of symptoms (all P < 0.001), and time lag after ingestion (P = 0.048) were significant risk factors for death in univariate analyses. Among these, age, anion gap, and pesticide class were significant risk factors for death in a multiple logistic regression analysis (P < 0.001). In conclusions, high anion gap is a significant risk factor for death, regardless of the accompanying acid-base balance status in patients with acute pesticide intoxication. PMID:27366016

  14. Outage analysis of opportunistic decode-and-forward relaying

    KAUST Repository

    Tourki, Kamel

    2010-09-01

    In this paper, we investigate a dual-hop opportunistic decode-and-forward relaying scheme where the source may or not be able to communicate directly with the destination. We first derive statistics based on exact probability density function (PDF) of each hop. Then, the PDFs are used to determine closed-form outage probability expression for a transmission rate R. Furthermore, we evaluate the asymptotic outage performance and the diversity order is deduced. Unlike existing works where the analysis focused on high signal-to-noise ratio (SNR) regime, such results are important to enable the designers to take decisions regarding practical systems that operate at low SNR regime. We show that performance simulation results coincide with our analytical results under practical assumption of unbalanced hops. © 2010 IEEE.

  15. Automation of servicibility of radio-relay station equipment

    Science.gov (United States)

    Uryev, A. G.; Mishkin, Y. I.; Itkis, G. Y.

    1985-03-01

    Automation of the serviceability of radio relay station equipment must ensure central gathering and primary processing of reliable instrument reading with subsequent display on the control panel, detection and recording of failures soon enough, advance enough warning based on analysis of detertioration symptoms, and correct remote measurement of equipment performance parameters. Such an inspection will minimize transmission losses while reducing nonproductive time and labor spent on documentation and measurement. A multichannel automated inspection system for this purpose should operate by a parallel rather than sequential procedure. Digital data processing is more expedient in this case than analog method and, therefore, analog to digital converters are required. Spepcial normal, above limit and below limit test signals provide means of self-inspection, to which must be added adequate interference immunization, stabilization, and standby power supply. Use of a microcomputer permits overall refinement and expansion of the inspection system while it minimizes though not completely eliminates dependence on subjective judgment.

  16. Experimental service of 3DTV broadcasting relay in Korea

    Science.gov (United States)

    Hur, Namho; Ahn, Chung-Hyun; Ahn, Chieteuk

    2002-11-01

    This paper introduces 3D HDTV relay broadcasting experiments of 2002 FIFA World Cup Korea/Japan using a terrestrial and satellite network. We have developed 3D HDTV cameras, 3D HDTV video multiplexer/demultiplexer, a 3D HDTV receiver, and a 3D HDTV OB van for field productions. By using a terrestrial and satellite network, we distributed a compressed 3D HDTV signal to predetermined demonstration venues which are approved by host broadcast services (HBS), KirchMedia, and FIFA. In this case, we transmitted a 40Mbps MPEG-2 transport stream (DVB-ASI) over a DS-3 network specified in ITU-T Rec. G.703. The video/audio compression formats are MPEG-2 main-profile, high-level and Dolby Digital AC-3 respectively. Then at venues, the recovered left and right images by the 3D HDTV receiver are displayed on a screen with polarized beam projectors.

  17. Buoy Relay Method for Instantaneous Fluid Flow with Free Surface

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Several methods have been used to approximate free surface boundaries in finite-difference numerical simulations. Each of these methods has its advantages and disadvantages. This paper presents a new technique for the numerical solution of transient incompressible free surface fluid flows. This powerful method, which is based on the concepts of "Buoy positioning" and "Buoy relaying", successfully represents the free surface using a Lagrangian method on a Eulerian grid by directly solving the free surface evolution equation. The Eulerian finite-difference forms of the full Navier-Stokes equations are solved by the Successive over Relaxation (SOR) method with a set of buoys to keep track of the free surface. The capabilities of the analysis procedure are demonstrated through viscous free surface fluid flow examples. The method is simpler and more efficient than other methods especially in treating complicated free boundary configurations.

  18. Long distance quantum teleportation in a quantum relay configuration

    CERN Document Server

    De Riedmatten, H; Tittel, W; Zbinden, H; Collins, D; Gisin, Nicolas

    2003-01-01

    A long distance quantum teleportation experiment with a fiber-delayed Bell State Measurement (BSM) is reported. The source creating the qubits to be teleported and the source creating the necessary entangled state are connected to the beam splitter realizing the BSM by two 2 km long optical fibers. In addition, the teleported qubits are analyzed after 2,2 km of optical fiber, in another lab separated by 55 m. Time bin qubits carried by photons at 1310 nm are teleported onto photons at 1550 nm. The fidelity is of 77%, above the maximal value obtainable without entanglement. This is the first realization of an elementary quantum relay over significant distances, which will allow an increase in the range of quantum communication and quantum key distribution.

  19. Relay telescope for high power laser alignment system

    Science.gov (United States)

    Dane, C. Brent; Hackel, Lloyd; Harris, Fritz B.

    2006-09-19

    A laser system includes an optical path having an intracavity relay telescope with a telescope focal point for imaging an output of the gain medium between an image location at or near the gain medium and an image location at or near an output coupler for the laser system. A kinematic mount is provided within a vacuum chamber, and adapted to secure beam baffles near the telescope focal point. An access port on the vacuum chamber is adapted for allowing insertion and removal of the beam baffles. A first baffle formed using an alignment pinhole aperture is used during alignment of the laser system. A second tapered baffle replaces the alignment aperture during operation and acts as a far-field baffle in which off angle beams strike the baffle a grazing angle of incidence, reducing fluence levels at the impact areas.

  20. The success of the 45th CERN Relay Race

    CERN Multimedia

    CERN Bulletin

    2015-01-01

    On Thursday, 21 May, 783 people (9 Nordic walkers and 129 teams of 6 runners each) took part in the 45th CERN Relay Race.   The teams were divided into eight different categories: three CERN categories (Seniors, Dames, Mixte) – in which the six runners in the team must belong to the same professional unit – and four “open” categories (Open, Veterans Open, Dames Open, Mixte Open) - in which the six runners in the team do not necessarily belong to the same professional unit and can include people from outside CERN. Each team covered 3,600 metres around the Meyrin site, with the race's fastest runners covering this distance in only 11 minutes and 5 seconds! (See all the results here. For more photos from the event, see here, here and here.)  

  1. Ursodeoxycholic acid and superoxide anion

    Institute of Scientific and Technical Information of China (English)

    Predrag Ljubuncic; Omar Abu-Salach; Arieh Bomzon

    2005-01-01

    AIM: To investigate the ability of ursodeoxycholic acid (UDCA) to scavenge superoxide anion (O2-).METHODS: We assessed the ability of UDCA to scavenge (O2-) generated by xanthine-xanthine oxidase (X-XO) in a cell-free system and its effect on the rate of O2--induced ascorbic acid (AA) oxidation in hepatic post-mitochondrial supernatants.RESULTS: UDCA at a concentration as high as 1 mmol/Ldid not impair the ability of the X-XO system to generate O2-, but could scavenge O2- at concentrations of 0.5 and 1 mmol/L, and decrease the rate of AA oxidation at a concentration of 100 μmol/L.CONCLUSION: UDCA can scavenge O2-, an action that may be beneficial to patients with primary biliary cirrhosis.

  2. Optimization of beamforming and path planning for UAV-assisted wireless relay networks

    Directory of Open Access Journals (Sweden)

    Ouyang Jian

    2014-04-01

    Full Text Available Recently, unmanned aerial vehicles (UAVs acting as relay platforms have attracted considerable attention due to the advantages of extending coverage and improving connectivity for long-range communications. Specifically, in the scenario where the access point (AP is mobile, a UAV needs to find an efficient path to guarantee the connectivity of the relay link. Motivated by this fact, this paper proposes an optimal design for beamforming (BF and UAV path planning. First of all, we study a dual-hop amplify-and-forward (AF wireless relay network, in which a UAV is used as relay between a mobile AP and a fixed base station (BS. In the network, both of the AP and the BS are equipped with multiple antennas, whereas the UAV has a single antenna. Then, we obtain the output signal-to-noise ratio (SNR of the dual-hop relay network. Based on the criterion of maximizing the output SNR, we develop an optimal design to obtain the solution of the optimal BF weight vector and the UAV heading angle. Next, we derive the closed-form outage probability (OP expression to investigate the performance of the dual-hop relay network conveniently. Finally, computer simulations show that the proposed approach can obtain nearly optimal flying path and OP performance, indicating the effectiveness of the proposed algorithm. Furthermore, we find that increasing the antenna number at the BS or the maximal heading angle can significantly improve the performance of the considered relay network.

  3. Interactive effects of relay and circuit breaker aging in a safety-related system

    International Nuclear Information System (INIS)

    This paper provides an overview of the results of a program to evaluate the aging of circuit breakers and relays and the effects of that aging on the function of a safety system used in nuclear power plants. The program was performed under the Nuclear Plant Aging Research (NPAR) Program of the US Nuclear Regulatory Commission under subcontract to Brookhaven National Laboratory. There were two primary aspects to the program. In the first, the aging and failure modes of relays and circuit breakers were determined by evaluating the construction, design, and materials and the failure data related to nuclear power plant service. In the second, the interactions between a safety system and its relays and circuit breakers were evaluated to determine the effects of relay and circuit breaker aging on the function of the safety system. The aging of relays and circuit breakers was assessed through evaluation of failure data bases, discussions with utility personnel, and evaluation of equipment operating and maintenance manuals. The interaction study was based on an analysis of the safety injection system of a pressurized water reactor. The effects of stresses from the system were analyzed for the tendency to cause deterioration of the relays and circuit breakers in the system. Then the effect of the deterioration of relays and circuit breakers on the functional capability of the safety system was evaluated

  4. Park-based and zero sequence-based relaying techniques with application to transformers protection

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, G.; Arboleya, P.; Gomez-Aleixandre, J. [University of Oviedo (Spain). Dept. of Electrical Engineering

    2004-09-01

    Two relaying techniques for protecting power transformers are presented and discussed. Very often, differential relaying is used for this purpose. A comparison between the two proposed techniques and conventional differential relaying is thus presented. The first technique, based on the measurements of zero sequence current within a delta winding, performs best in multiwinding transformers, since only measurement of the coil currents is needed. Thus, great simplicity is achieved. The second one is based on the differential procedure, but its analysis of asymmetries in the plot in Park's plane avoids problems related to spectral analysis in conventional differential relaying. The technique is justified from the analysis of symmetrical components. Misoperation in conventional differential relaying has been observed in some cases as a function of switching instant and fault location. This issue is discussed in the paper, and a statistical analysis of a large number of laboratory tests, in which both factors were controlled, is presented. As a conclusion, both relaying techniques proposed succeed in protecting the transformer. Additionally, the Park-based relay exhibits three characteristics of most importance: fastest performance, robustness and simplicity in its formulation. (author)

  5. 13.8-kV (ground) fault-bus-relaying study

    International Nuclear Information System (INIS)

    This study was made at the request of the committee appointed to investigate a power outage which occurred on May 5, 1980, at the ORGDP in Oak Ridge, Tennessee. A portion of this outage was due to a false ground on the 13.8-kV fault-bus-relaying system. This report covers the following five areas: (1) fundamentals of fault-bus relaying and application at ORGDP; (2) description of the false ground on the 13.8-kV fault-bus-relaying system and corrective actions taken at that time; (3) causes of the false 13.8-kV fault-bus-relay trip; (4) further possible corrective actions to reduce the possibility of another false 13.8-kV fault-bus-relay trip; and (5) effects of reducing ground-fault current magnitude and its effects on ground/relay coordination. Recommendations are presented concerning the reduction of the possibility of another false 13.8-kV fault-bus-relay trip and the reduction of the magnitude of ground-fault current

  6. Wireless Relay Selection in Pocket Switched Networks Based on Spatial Regularity of Human Mobility

    Directory of Open Access Journals (Sweden)

    Jianhui Huang

    2016-01-01

    Full Text Available Pocket switched networks (PSNs take advantage of human mobility to deliver data. Investigations on real-world trace data indicate that human mobility shows an obvious spatial regularity: a human being usually visits a few places at high frequencies. These most frequently visited places form the home of a node, which is exploited in this paper to design two HomE based Relay selectiOn (HERO algorithms. Both algorithms input single data copy into the network at any time. In the basic HERO, only the first node encountered by the source and whose home overlaps a destination’s home is selected as a relay while the enhanced HERO keeps finding more optimal relay that visits the destination’s home with higher probability. The two proposed algorithms only require the relays to exchange the information of their home and/or the visiting frequencies to their home when two nodes meet. As a result, the information update is reduced and there is no global status information that needs to be maintained. This causes light loads on relays because of the low communication cost and storage requirements. Additionally, only simple operations are needed in the two proposed algorithms, resulting in little computation overhead at relays. At last, a theoretical analysis is performed on some key metrics and then the real-world based simulations indicate that the two HERO algorithms are efficient and effective through employing only one or a few relays.

  7. Wireless Relay Selection in Pocket Switched Networks Based on Spatial Regularity of Human Mobility.

    Science.gov (United States)

    Huang, Jianhui; Cheng, Xiuzhen; Bi, Jingping; Chen, Biao

    2016-01-01

    Pocket switched networks (PSNs) take advantage of human mobility to deliver data. Investigations on real-world trace data indicate that human mobility shows an obvious spatial regularity: a human being usually visits a few places at high frequencies. These most frequently visited places form the home of a node, which is exploited in this paper to design two HomE based Relay selectiOn (HERO) algorithms. Both algorithms input single data copy into the network at any time. In the basic HERO, only the first node encountered by the source and whose home overlaps a destination's home is selected as a relay while the enhanced HERO keeps finding more optimal relay that visits the destination's home with higher probability. The two proposed algorithms only require the relays to exchange the information of their home and/or the visiting frequencies to their home when two nodes meet. As a result, the information update is reduced and there is no global status information that needs to be maintained. This causes light loads on relays because of the low communication cost and storage requirements. Additionally, only simple operations are needed in the two proposed algorithms, resulting in little computation overhead at relays. At last, a theoretical analysis is performed on some key metrics and then the real-world based simulations indicate that the two HERO algorithms are efficient and effective through employing only one or a few relays. PMID:26797609

  8. Impact of Primary User Traffic on Adaptive Transmission for Cognitive Radio with Partial Relay Selection

    KAUST Repository

    Rao, Anlei

    2012-09-08

    In a cognitive relay system, the secondary user is permitted to transmit data via a relay when licensed frequency bands are detected to be free. Previous studies mainly focus on reducing or limiting the interference of the secondary transmission on the primary users. On the other hand, however, the primary user traffic will also affect the data transmission performance of the secondary users. In this paper, we investigate the impact of the primary user traffic on the bit error rate (BER) of the secondary transmission, when the secondary user adopts adaptive transmission with a relay partially selected. From the numerical results, we can see that the primary user traffic seriously degrades average BER. The worse-link partial selection can perform almost as well as the global selection when the channel conditions of the source-relay links and the relay-destination links differ a lot. In addition, although the relay selection improves the spectral efficiency of the secondary transmission, numerical results show that it only has slight impact on the overall average BER, so that the robustness of the system will not be affected by the relay selection.

  9. Quimiossensores cromogênicos e fluorogênicos para a detecção de analitos aniônicos Chromogenic and fluorogenic chemosensors for detection of anionic analites

    OpenAIRE

    Lizandra Maria Zimmermann-Dimer; Vanderlei Gageiro Machado

    2008-01-01

    The detection of anionic species is a field which is currently attracting increasing interest. Research is carried out not only to gain a better understanding of biological events that anions participate in, but also to ascertain the potential contribution of the anionic chemosensors to the qualitative and quantitative analysis of species of interest in the areas of industry, medicine, the environment, and chemistry. This review summarizes several aspects related to the main strategies used i...

  10. Tripodal Receptors for Cation and Anion Sensors

    Directory of Open Access Journals (Sweden)

    David N. Reinhoudt

    2006-08-01

    Full Text Available This review discusses different types of artificial tripodal receptors for the selectiverecognition and sensing of cations and anions. Examples on the relationship between structure andselectivity towards cations and anions are described. Furthermore, their applications as potentiometricion sensing are emphasised, along with their potential applications in optical sensors or optodes.

  11. Test procedure for anion exchange chromatography

    International Nuclear Information System (INIS)

    Plutonium from stored nitrate solutions will be sorbed onto anion exchange resins and converted to storable plutonium dioxide. Useful information will be simultaneously gained on the thermal stability and ion exchange capacity of four commercially available anion exchange resins over several years and under severe degradative conditions. This information will prove useful in predicting the safe and efficient lifetimes of these resins

  12. Simultaneous anion and cation mobility in polypyrrole

    DEFF Research Database (Denmark)

    Skaarup, Steen; Bay, Lasse; Vidanapathirana, K.;

    2003-01-01

    Polypyrrole (PPy) polymer films permanently doped with large, immobile anion dodecyl benzene sulfonate (DBS) have been characterized by cyclic voltammetry in order to clarify the roles of cations and anions in the aqueous electrolyte as mobile ions in the film. Aqueous solutions of 0.05-0.1 M alk...

  13. Counterintuitive interaction of anions with benzene derivatives

    Science.gov (United States)

    Quiñonero, David; Garau, Carolina; Frontera, Antonio; Ballester, Pau; Costa, Antonio; Deyà, Pere M.

    2002-06-01

    Ab initio calculations were carried out on complexes between 1,3,5-trinitrobenzene (TNB) and anions, where the anion is positioned over the ring along the C3 axis. This study combines crystallographic and computational evidences to demonstrate an attractive interaction between the anion and the π-cloud of TNB. This interaction is rationalized based on the important role of the quadrupole moment of TNB and the anion-induced polarization. In addition, this study has been extended to 1,3,5-trifluorobenzene (TFB), which possesses a very small quadrupole moment. As a result, minimum energy complexes have been found between TFB and both anions and cations due to the stabilization obtained from the ion-induced polarization.

  14. IMPACT OF CRITICAL ANION SOIL SOLUTION CONCENTRATION ON ALUMINUM ACTIVITY IN ALPINE TUNDRA SOIL Andrew Evans, Jr.1 , Michael B. Jacobs2, and Jason R. Janke1, (1) Metropolitan State University of Denver, Dept. of Earth and Atmospheric Sciences, (2) Dept. of Chemistry, Denver, CO, United States.

    Science.gov (United States)

    Evans, A.

    2015-12-01

    Soil solution anionic composition can impact both plant and microbial activity in alpine tundra soils by altering biochemical cycling within the soil, either through base cation leaching, or shifts in aluminum controlling solid phases. Although anions play a critical role in the aqueous speciation of metals, relatively few high altitude field studies have examined their impact on aluminum controlling solid phases and aluminum speciation in soil water. For this study, thirty sampling sites were selected on Trail Ridge Road in Rocky Mountain National Park, Estes Park, CO, and sampled during July, the middle of the growing season. Sampling elevations ranged from approximately 3560 - 3710 m. Soil samples were collected to a depth of 15.24 cm, and the anions were extracted using a 2:1 D.I. water to soil ratio. Filtered extracts were analyzed using IC and ICP-MS. Soil solution NO3- concentrations were significantly higher for sampling locations east of Iceberg Pass (EIBP) (mean = 86.94 ± 119.8 mg/L) compared to locations west of Iceberg Pass (WIBP) (mean 1.481 ± 2.444 mg/L). Both F- and PO43- soil solution concentrations, 0.533 and 0.440 mg/L, respectively, were substantially lower, for sampling sites located EIBP, while locations WIBP averaged 0.773 and 0.829 mg/L respectively, for F- and PO43-. Sulfate concentration averaged 3.869 ± 3.059 mg/L for locations EIBP, and 3.891 ± 3.1970 for locations WIBP. Geochemical modeling of Al3+ in the soil solution indicated that a suite of aluminum hydroxyl sulfate minerals controlled Al3+ activity in the alpine tundra soil, with shifts between controlling solid phases occurring in the presence of elevated F- concentrations.

  15. Fine chemistry

    International Nuclear Information System (INIS)

    The 1988 progress report of the Fine Chemistry laboratory (Polytechnic School, France) is presented. The research programs are centered on the renewal of the organic chemistry most important reactions and on the invention of new, highly efficient and highly selective reactions, by applying low cost reagents and solvents. An important research domain concerns the study and fabrication of new catalysts. They are obtained by means of the reactive sputtering of the metals and metal oxydes thin films. The Monte Carlo simulations of the long-range electrostatic interaction in a clay and the obtention of acrylamides from anhydrous or acrylic ester are summarized. Moreover, the results obtained in the field of catalysis are also given. The published papers and the congress communications are included

  16. Organometallic chemistry

    OpenAIRE

    Bashkin, James K.; M.L.H. Green; Dr. M. L. H. Green

    1982-01-01

    Transition metal organometallic chemistry is a rapidly expanding field, which has an important relationship to industrial problems of petrochemical catalysis. This thesis describes studies of fundamental organometallic reaction processes, such as C-H and C-C bond formation and cleavage, and investigations of the structure and bonding of organometallic compounds. A number of techniques were used to pursue these studies, including synthesis, X-ray crystallography, and semi-em...

  17. Disk Chemistry*

    OpenAIRE

    Thi Wing-Fai

    2015-01-01

    The chemical species in protoplanetary disks react with each other. The chemical species control part of the thermal balance in those disks. How the chemistry proceeds in the varied conditions encountered in disks relies on detailed microscopic understanding of the reactions through experiments or theoretical studies. This chapter strives to summarize and explain in simple terms the different types of chemical reactions that can lead to complex species. The first part of the chapter deals wit...

  18. Interstellar chemistry

    OpenAIRE

    Klemperer, William

    2006-01-01

    In the past half century, radioastronomy has changed our perception and understanding of the universe. In this issue of PNAS, the molecular chemistry directly observed within the galaxy is discussed. For the most part, the description of the molecular transformations requires specific kinetic schemes rather than chemical thermodynamics. Ionization of the very abundant molecular hydrogen and atomic helium followed by their secondary reactions is discussed. The rich variety of organic species o...

  19. Analytical chemistry

    International Nuclear Information System (INIS)

    The division for Analytical Chemistry continued to try and develope an accurate method for the separation of trace amounts from mixtures which, contain various other elements. Ion exchange chromatography is of special importance in this regard. New separation techniques were tried on certain trace amounts in South African standard rock materials and special ceramics. Methods were also tested for the separation of carrier-free radioisotopes from irradiated cyclotron discs

  20. Classification of methods of transmission of relay stick is in track-and-field sport

    OpenAIRE

    Апайчев / Apaychev A., А. В.

    2012-01-01

    In article are considered of the ways of the issue of the relay stick, which were used in track-and-field sport in competition and are training in drill beginning and skilled athlete. On the grounds of analysis of the history development of the ways of the issue and factor, characterizing actions athlete in track-and-field relay-race, are presented by designed author classification ways of the issue of the relay stick and recommendations of their using in drill on different stage of the perma...

  1. The features of technical preparedness of athletes in a relay-race.

    Directory of Open Access Journals (Sweden)

    Karaulova S.I.

    2011-03-01

    Full Text Available Considered the questions about perfection of technical skills of athletes in relay race 4х100 m. In research taken part 10 sportsmen in age 18-19 years. Based on data analysis advanced coaching experience in the preparation of relay race teams that have been developed informative criteria estimate of technical preparations sportsman in relay race. Shown that the use of these criteria of assessing technical skills of athletes allowed to qualitatively assess effectiveness of training and competitive process in the annual cycle of preparation.

  2. Diversity-Multiplexing Tradeoff for the Interference Channel with a Relay

    OpenAIRE

    Zahavi, Daniel; Zhang, Lili; Maric, Ivana; Dabora, Ron; Goldsmith, Andrea J; Cui, Shuguang

    2014-01-01

    We study the diversity-multiplexing tradeoff (DMT) for the slow fading interference channel with a relay (ICR). We derive four inner bounds on the DMT region: the first is based on the compress-and-forward (CF) relaying scheme, the second is based on the decode-and-forward (DF) relaying scheme, and the last two bounds are based on the half-duplex (HD) and full-duplex (FD) amplify-and-forward (AF) schemes. For the CF and DF schemes, we find conditions on the channel parameters and the multiple...

  3. On the performance of spectrum sharing systems with two-way relaying and multiuser diversity

    KAUST Repository

    Yang, Liang

    2012-08-01

    In this letter, we consider a spectrum sharing network with two-way relaying and multi-user diversity. More specifically, one secondary transmitter with the best channel quality is selected and splits its partial power to relay its received signals to the primary users by using the amplify-and-forward relaying protocol. We derive a tight approximation for the resulting outage probability. Based on this formula, the performance of the spectral sharing region and the cell coverage are analyzed. Numerical results are given to verify our analysis and are discussed to illustrate the advantages of our newly proposed scheme. © 1997-2012 IEEE.

  4. Performance Analysis of Virtual MIMO Relaying Schemes Based on Detect–Split–Forward

    KAUST Repository

    Al-Basit, Suhaib M.

    2014-10-29

    © 2014, Springer Science+Business Media New York. Virtual multi-input multi-output (vMIMO) schemes in wireless communication systems improve coverage, throughput, capacity, and quality of service. In this paper, we propose three uplink vMIMO relaying schemes based on detect–split–forward (DSF). In addition, we investigate the effect of several physical parameters such as distance, modulation type and number of relays. Furthermore, an adaptive vMIMO DSF scheme based on VBLAST and STBC is proposed. In order to do that, we provide analytical tools to evaluate the performance of the propose vMIMO relaying scheme.

  5. Effect of the Primary User Traffic on Cognitive Relaying with Adaptive Transmission

    KAUST Repository

    Rao, Anlei

    2012-09-08

    In a cognitive-relay system, the secondary user is permitted to transmit data via a relay when the spectrum bands are detected to be free. The miss detection of spectrum sensing and the primary user traffic will affect the data transmission performance of the secondary user. In this paper, we investigate the impact of the status change of the primary user on the bit error rate (BER) of the adaptive transmission of the secondary user in a cognitive-relay system. Numerical results show that the primary user traffic can significantly degrade the BER of the secondary user transmission.

  6. Dynamic Channel Allocation for Interference Mitigation in Relay-assisted Wireless Body Networks

    OpenAIRE

    Ali, Mohamad Jaafar; Moungla, Hassine; Mehaoua, Ahmed

    2016-01-01

    We focus on interference mitigation and energy conservation within a single wireless body area network (WBAN). We adopt two-hop communication scheme supported by the the IEEE 802.15.6 standard (2012). In this paper, we propose a dynamic channel allocation scheme, namely DCAIM to mitigate node-level interference amongst the coexisting regions of a WBAN. At the time, the sensors are in the radius communication of a relay, they form a relay region (RG) coordinated by that relay using time divisi...

  7. Incorporating Multiple Energy Relay Dyes in Liquid Dye-Sensitized Solar Cells

    KAUST Repository

    Yum, Jun-Ho

    2011-01-05

    Panchromatic response is essential to increase the light-harvesting efficiency in solar conversion systems. Herein we show increased light harvesting from using multiple energy relay dyes inside dye-sensitized solar cells. Additional photoresponse from 400-590 nm matching the optical window of the zinc phthalocyanine sensitizer was observed due to Förster resonance energy transfer (FRET) from the two energy relay dyes to the sensitizing dye. The complementary absorption spectra of the energy relay dyes and high excitation transfer efficiencies result in a 35% increase in photovoltaic performance. © 2011 Wiley-VCH Verlag GmbH& Co. KGaA.

  8. Towards a Framework for Modelling and Verification of Relay Interlocking Systems

    DEFF Research Database (Denmark)

    Haxthausen, Anne Elisabeth

    This paper describes a framework currently under development for modelling, simulation, and verification of relay interlocking systems as used by the Danish railways. The framework is centred around a domain-specific language (DSL) for describing such systems, and provides (1) a graphical editor...... for creating DSL descriptions, (2) a data validator for checking that DSL descriptions follow the structural rules of the domain, (3) a graphical simulator for simulating the dynamic behaviour of relay interlocking systems, and (4) verification support for deriving and verifying safety properties of...... relay interlocking systems....

  9. A Delay-Constrained General Achievable Rate and Certain Capacity Results for UWB Relay Channel

    CERN Document Server

    Yazd, Maryam Faramarzi

    2011-01-01

    In this paper, we derive UWB version of (i) general best achievable rate for the relay channel with decode-andforward strategy and (ii) max-flow min-cut upper bound, such that the UWB relay channel can be studied considering the obtained lower and upper bounds. Then, we show that by appropriately choosing the noise correlation coefficients, our new upper bound coincides with the lower bound in special cases of degraded and reversely degraded UWB relay channels. Finally, some numerical results are illustrated.

  10. Computational chemistry

    Science.gov (United States)

    Arnold, J. O.

    1987-01-01

    With the advent of supercomputers, modern computational chemistry algorithms and codes, a powerful tool was created to help fill NASA's continuing need for information on the properties of matter in hostile or unusual environments. Computational resources provided under the National Aerodynamics Simulator (NAS) program were a cornerstone for recent advancements in this field. Properties of gases, materials, and their interactions can be determined from solutions of the governing equations. In the case of gases, for example, radiative transition probabilites per particle, bond-dissociation energies, and rates of simple chemical reactions can be determined computationally as reliably as from experiment. The data are proving to be quite valuable in providing inputs to real-gas flow simulation codes used to compute aerothermodynamic loads on NASA's aeroassist orbital transfer vehicles and a host of problems related to the National Aerospace Plane Program. Although more approximate, similar solutions can be obtained for ensembles of atoms simulating small particles of materials with and without the presence of gases. Computational chemistry has application in studying catalysis, properties of polymers, all of interest to various NASA missions, including those previously mentioned. In addition to discussing these applications of computational chemistry within NASA, the governing equations and the need for supercomputers for their solution is outlined.

  11. Green chemistry

    International Nuclear Information System (INIS)

    A grand challenge facing government, industry, and academia in the relationship of our technological society to the environment is reinventing the use of materials. To address this challenge, collaboration from an interdisciplinary group of stakeholders will be necessary. Traditionally, the approach to risk management of materials and chemicals has been through inerventions intended to reduce exposure to materials that are hazardous to health and the environment. In 1990, the Pollution Prevention Act encouraged a new tact-elimination of hazards at the source. An emerging approach to this grand challenge seeks to embed the diverse set of environmental perspectives and interests in the everyday practice of the people most responsible for using and creating new materials--chemists. The approach, which has come to be known as Green Chemistry, intends to eliminate intrinsic hazard itself, rather than focusing on reducing risk by minimizing exposure. This chapter addresses the representation of downstream environmental stakeholder interests in the upstream everyday practice that is reinventing chemistry and its material inputs, products, and waste as described in the '12 Principles of Green Chemistry'

  12. Green chemistry

    International Nuclear Information System (INIS)

    The depletion of world fossil fuel reserves and the involvement of greenhouse gases in the global warming has led to change the industrial and energy policies of most developed countries. The goal is now to reserve petroleum to the uses where it cannot be substituted, to implement renewable raw materials obtained from plants cultivation, and to consider the biodegradability of molecules and of manufactured objects by integrating the lifetime concept in their expected cycle of use. The green chemistry includes the design, development and elaboration of chemical products and processes with the aim of reducing or eliminating the use and generation of harmful compounds for the health and the environment, by adapting the present day operation modes of the chemical industry to the larger framework of the sustainable development. In addition to biofuels, this book reviews the applications of green chemistry in the different industrial processes in concern. Part 1 presents the diversity of the molecules coming from renewable carbon, in particular lignocellulose and the biotechnological processes. Part 2 is devoted to materials and treats of the overall available technological solutions. Part 3 focusses on functional molecules and chemical intermediates, in particular in sugar- and fats-chemistry. Part 4 treats of biofuels under the aspects of their production and use in today's technologies. The last part deals with the global approaches at the environmental and agricultural levels. (J.S.)

  13. Energy Density Functionals From the Strong-Coupling Limit Applied to the Anions of the He Isoelectronic Series

    OpenAIRE

    Mirtschink, André; Umrigar, C. J.; Morgan III, John D.; Gori-Giorgi, Paola

    2014-01-01

    Anions and radicals are important for many applications including environmental chemistry, semiconductors, and charge transfer, but are poorly described by the available approximate energy density functionals. Here we test an approximate exchange-correlation functional based on the exact strong-coupling limit of the Hohenberg-Kohn functional on the prototypical case of the He isoelectronic series with varying nuclear charge $Z

  14. Network Code Design for Orthogonal Two-hop Network with Broadcasting Relay: A Joint Source Channel Network Coding Approach

    CERN Document Server

    Joda, Roghayeh

    2010-01-01

    This paper addresses network code design for robust transmission of sources over an orthogonal two-hop wireless network with a broadcasting relay. The network consists of multiple sources and destinations in which each destination, benefiting the relay signal, intends to decode a subset of the sources. Two special instances of this network are orthogonal broadcast relay channel and the orthogonal multiple access relay channel. The focus is on complexity constrained scenarios, e.g., for wireless sensor networks, where channel coding is practically imperfect. Taking a source-channel and network coding approach, we design the code (mapping) at the relay such that the average reconstruction distortion at the destinations is minimized. To this end, by decomposing the source and channel-network distortions, an efficient design algorithm is proposed. The resulting network code at the relay is nonlinear and substantially outperforms the best performing linear network code at the relay. A motivating formulation of a f...

  15. Synthesis of (meth)acrylate block copolymers by ligated anionic polymerization

    Czech Academy of Sciences Publication Activity Database

    Vlček, Petr; Čadová, Eva; Janata, Miroslav; Látalová, Petra; Toman, Luděk; Kříž, Jaroslav; Kurková, Dana

    2006-01-01

    Roč. 240, č. 1 (2006), s. 141-150. ISSN 1022-1360. [International Symposium on Ionic Polymerization. Goa, 23.10.2005-28.10.2005] R&D Projects: GA MŠk 1P05ME753 Institutional research plan: CEZ:AV0Z40500505 Keywords : anionic polymerization * block copolymers * ester-enolates Subject RIV: CD - Macromolecular Chemistry Impact factor: 0.913, year: 2005

  16. Structural investigations on N'-substituted N-acylguanidines - Intermolecular interactions with solvents, anions and receptors

    OpenAIRE

    Kleinmaier, Roland

    2011-01-01

    Acylguanidines are an abundant class of compounds with various applications in organic and pharmaceutical chemistry. Within the subgroup of N’-substituted and especially monoalkylated N-acylguanidines, highly potent and selective ligands for G protein coupled receptors have been identified in recent years. In the field of molecular recognition, acylguanidines are valued for their ability to form strong fork-like hydrogen bond (H-bond) interactions with carboxylate anions. Although their basic...

  17. Improved synthesis of [closo-1-CB9H10 ](-) anion and new c-substituted derivatives

    Czech Academy of Sciences Publication Activity Database

    Ringstrand, B.; Bateman, D.; Shoemaker, R. K.; Janoušek, Zbyněk

    2009-01-01

    Roč. 74, č. 3 (2009), s. 419-431. ISSN 0010-0765 R&D Projects: GA MŠk LC523; GA MŠk ME 857 Grant ostatní: NSF(US) CHE-0446688; NSF(US) OISE-0532040 Institutional research plan: CEZ:AV0Z40320502 Keywords : boranes * carboranes * monocarbaborane anions Subject RIV: CA - Inorganic Chemistry Impact factor: 0.856, year: 2009

  18. N-Arylazetidines: Preparation through Anionic Ring Closure.

    Science.gov (United States)

    Quinodoz, Pierre; Drouillat, Bruno; Wright, Karen; Marrot, Jérôme; Couty, François

    2016-04-01

    We report herein an efficient synthesis of diversely substituted N-aryl-2-cyanoazetidines based on an anionic ring-closure reaction. These compounds can be prepared from β-amino alcohols in enantiomerically pure form through a three-step sequence involving (i) copper-catalyzed N-arylation, (ii) N-cyanomethylation of the secondary aniline, and (iii) one-pot mesylation followed by ring closure induced by a base. This high-yielding sequence gives access to azetidines with a predictable and adjustable substitution pattern and also with predictable diastereoselectivity. These compounds are susceptible to multiple further derivatizations through Suzuki coupling or nitrile transformation, thus appearing as valuable new scaffolds for medicinal chemistry. Their rigid shape, featuring an almost planar N-arylamine and a planar four-membered ring, was revealed by both AM1 calculations and X-ray crystallography. PMID:26932242

  19. Error-rate performance analysis of incremental decode-and-forward opportunistic relaying

    KAUST Repository

    Tourki, Kamel

    2010-10-01

    In this paper, we investigate an incremental opportunistic relaying scheme where the selected relay chooses to cooperate only if the source-destination channel is of an unacceptable quality. In our study, we consider regenerative relaying in which the decision to cooperate is based on a signal-to-noise ratio (SNR) threshold and takes into account the effect of the possible erroneously detected and transmitted data at the best relay. We derive a closed-form expression for the end-to-end biterror rate (BER) of binary phase-shift keying (BPSK) modulation based on the exact probability density function (PDF) of each hop. Furthermore, we evaluate the asymptotic error performance and the diversity order is deduced. We show that performance simulation results coincide with our analytical results. ©2010 IEEE.

  20. Multicast Gain for IPTV Transmission in WiMAX Multi-hop Relay Networks

    Directory of Open Access Journals (Sweden)

    Alireza Abdollahpouri

    2012-11-01

    Full Text Available Due to characteristics such as: multicast support, wide coverage range, high bandwidth and mobility support, WiMAX could be a leading solution to deliver bandwidth-hungry IPTV services to mobile users. Mobile multi-hop relay (MMR was proposed as an amendment of the current mobile WiMAX standard to provide relaying capabilities. Relays are deployed as a cost-effective solution to extent coverage area and increase throughput without deploying expensive base stations. In this paper, we introduce multicast gain as a performance criterion, which can be used for computing multicast efficiency. In order to quantify the benefits of multicasting, we analyze multicast transmission for delivery of live TV channels in MMR networks, and determine the gain of access and relay links. The quantification of the efficiency of multicasting can be used by IPTV service providers in resource provisioning, access control or decision support mechanisms in delivery of different TV channels.