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Sample records for angular bipyridyl ligands

  1. Supramolecular architectures constructed using angular bipyridyl ligands

    International Nuclear Information System (INIS)

    Barnett, Sarah Ann

    2003-01-01

    This work details the synthesis and characterization of a series of coordination frameworks that are formed using bidentate angular N-donor ligands. Pyrimidine was reacted with metal(ll) nitrate salts. Reactions using Cd(NO 3 ) 2 receive particular focus and the analogous reactions using the linear ligand, pyrazine, were studied for comparison. In all cases, two-dimensional coordination networks were prepared. Structural diversity is observed for the Cd(ll) centres including metal-nitrate bridging. In contrast, first row transition metal nitrates form isostructural one-dimensional chains with only the bridging N-donor ligands generating polymeric propagation. The angular ligand, 2,4-bis(4-pyridyl)-1,3,5-triazine (dpt), was reacted with Cd(NO 3 ) 2 and Zn(NO 3 ) 2 . Whereas Zn(NO 3 ) 2 compounds exhibit solvent mediated polymorphism, a range of structures were obtained for the reactions with Cd(NO 3 ) 2 , including the first example of a doubly parallel interpenetrated 4.8 2 net. 4,7-phenanthroline, was reacted with various metal(ll) nitrates as well as cobalt(ll) and copper(ll) halides. The ability of 4,7-phenanthroline to act as both a N-donor ligand and a hydrogen bond acceptor has been discussed. Reactions of CuSCN with pyrimidine yield an unusual three-dimensional structure in which polymeric propagation is not a result of ligand bridging. The reaction of CuSCN with dpt yielded structural supramolecular isomers. (author)

  2. Actinide-lanthanide separation by bipyridyl-based ligands. DFT calculations and experimental results

    International Nuclear Information System (INIS)

    Borisova, Nataliya E.; Eroshkina, Elizaveta A.; Korotkov, Leonid A.; Ustynyuk, Yuri A.; Alyapyshev, Mikhail Yu.; Eliseev, Ivan I.; Babain, Vasily A.

    2011-01-01

    In order to gain insights into effect of substituents on selectivity of Am/Eu separation, the synthesis and extractions tests were undertaken on the series of bipyridyl-based ligands (amides of 2,2'-bipyridyl-6,6'-dicarboxylic acid: L Ph - N,N'-diethyl-N,N'-diphenyl amide; L Bu2 - tetrabutyl amide; L Oct2 - tetraoctyl amide; L 3FPh - N,N'-diethyl-N,N'-bis-(3-fluorophenyl) amide; as well as N,N'-diethyl-N,N'-diphenyl amide of 4,4'-dibrom-2,2'-bipyridyl-6,6'-dicarboxylic acid and N,N'-diethyl-N,N'-diphenyl amide of 4,4'-dinitro-2,2'-bipyridyl-6,6'-dicarboxylic acid) as well as structure and stability of their complexes with lanthanides and actinides were studied. The extraction tests were performed for Am, lanthanide series and transition metals in polar diluents in presence of chlorinated cobalt dicarbolide and have shown high distribution coefficients for Am. Also was found that the type of substituents on amidic nitrogen exerts great influence on the extraction of light lanthanides. For understanding of the nature of this effect we made QC-calculations at DFT level, binding constants determination and X-Ray structure determination of the complexes. The UV/VIS titration performed show that the composition of all complexes of the amides with lanthanides in solution is 1:1. In spite of the binding constants are high (lgβ about 6-7 in acetonitrile solution), lanthanide ions have binding constants with the same order of magnitude for dialkyl substituted extractants. The X-Ray structures of the complexes of bipyridyl-based amides show the composition of 1:1 and the coordination number of the ions being 10. The DFT optimized structures of the compounds are in good agreement with that obtained by X-Ray. The gas phase affinity of the amides to lanthanides shows strong correlation with the distribution ratios. We can infer that the bipyridyl-based amides form complexes with metal nitrates which have similar structure in solid and gas phases and in solution, and the DFT

  3. Sulfur Bridged Multidentate Ligands Based on (Bipyridyl-(Bi-1,3,4-Thiadiazolyl Conjugates

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    M. Teresa Clasadonte

    2003-03-01

    Full Text Available The synthesis of a series of mixed (bipyridyl/(bi1,3,4-thiadiazolyl ligands, derived from the condensation of 2-mercapto-5-methylthio-1,3,4-thiadiazole or 5-mercapto-5'-methylthio-2,2'-bi-1,3,4-thiadiazole with 2,6-bis(chloromethylpyridine or 6,6’-bis(chloromethyl-2,2’-bipyridine (compounds L1–L4, and of 2,5-dimercapto-1,3,4-thiadiazole or 5,5'-dimercapto-2,2'-di-1,3,4-thiadiazole with picolyl chloride hydrochloride or 6-chloromethyl-6'-methyl-2,2'-bipyridine (compounds L5–L8 in the presence of triethylamine is described. All new compounds have been characterized by FAB (+ spectrometry and NMR spectroscopy. 13C-NMR spectra are crucial to firmly establish the thiol structure of the title ligands.

  4. Two new coordination polymers with flexible alicyclic carboxylate and bipyridyl co-ligands bearing trinuclear [Ni3(COO)6] SBUs: Synthesis, crystal structures, and magnetic properties

    Science.gov (United States)

    Zhu, Xian-Dong; Li, Yong; Gao, Jian-Gang; Wang, Fen-Hua; Li, Qing-Hai; Yang, Hong-Xun; Chen, Lei

    2017-02-01

    Two new coordination polymers generally formulated as [Ni3(Hchda)2(chda)2(bpy)2(H2O)2]n (1) and [Ni3(Hchda)2(chda)2(bpp)2(H2O)2]n (2) [H2chda = 1,1'-cyclohexanediacetic acid, bpy = 4,4'-bipyridine and bpp = 1,3-bis(4-pyridyl)propane], have been successfully assembled through mixed-ligands synthetic strategy with flexible alicyclic carboxylate and bipyridyl ligands. There structures feature trinuclear nickel secondary building units connected via the bridging bipyridyl spacers to form two-dimensional (4,4) grid layer. The nature of the different N-donor auxiliary ligands leads to the discrepancy in supramolecular structure of the two compounds. Magnetic studies indicate the ferromagnetic intra-complex magnetic interaction in the molecule for 1 and 2.

  5. The chemistry of polypyridine complexes of ruthenium. Communication 5. Electronic structure of mixed-ligand bipyridyl-diphosphine complexes of ruthenium(2)

    International Nuclear Information System (INIS)

    Sizova, O.V.; Ivanova, N.V.; Ershov, A.Yu.

    2001-01-01

    Comparative analysis of donor-acceptor abilities of diphosphine ligands for two series of complex compounds: cis-[Ru(bpy) 2 (LL) q+ [LL=2,2'-bipyridyl(bpy), o-benzoquinonediimine (bqdi), cis-1,2-bis(diphenylphosphino)ethane, cis-1,2-bis(diphenylphosphino)ethylene (dppen), (NH 3 ) 2 and (CO) 2 ] and [Ru(NH 3 ) 4 (LL)] 2+ (LL = bpy, dppen and bqdi) was carried out on the basis of results of quantum chemical calculations. It is shown that diphosphines are the strongest σ-donors; their π-acceptor abilities stemming from d-orbitals of phosphorus are comparable in value with π-acceptor abilities of 2,2'-bipyridyl, being essentially lower than those of o-benzoquinonediimine and carbonyl [ru

  6. pH-metric studies on the mixed ligand-chelates of oxovanadium(IV) with 2,2'-bipyridyl and dicarboxylic or hydroxy acids

    Energy Technology Data Exchange (ETDEWEB)

    Jain, A K; Kumari, V; Chaturvedi, G K [Agra Coll. (India)

    1978-12-01

    The interaction of vanadyl ion with 2,2'-bipyridyl and some dicarboxylic or hydroxy acids (where dicarboxylic acid = oxalic (OX), malonic (MALN), phthalic (PHA), maleic (MAL) acids; hydroxy acids salicylic (SA), 5-sulfosalicylic (5-SSA), mandelic (MAND) and glycollic (HG) acids was studied potentiometrically. pH-titrations of the reaction mixtures containing vanadyl sulphate, 2,2'-bipyridyl and one of the dicarboxylic or hydroxy acids (OX, MALN, PHA, MAL, SA, 5-SSA, MAND and HG acids) in equimolar ratio exhibited the formation of 1:1:1 mixed ligand chelates. The formation constants of the resulting biligand chelates were calculated, at 35/sup +/-1/sup 0/ and 45/sup +/-1/sup 0/ and also the thermodynamic functions viz. ..delta..F, ..delta..H and ..delta..S (..mu..=0.1M KNO/sub 3/) (auth.).

  7. pH-metric studies on the mixed ligand-chelates of oxovanadium(IV) with 2,2'-bipyridyl and dicarboxylic or hydroxy acids

    International Nuclear Information System (INIS)

    Jain, A.K.; Kumari, V.; Chaturvedi, G.K.

    1978-01-01

    The interaction of vanadyl ion with 2,2'-bipyridyl and some dicarboxylic or hydroxy acids (where dicarboxylic acid = oxalic (OX), malonic (MALN), phthalic (PHA), maleic (MAL) acids; hydroxy acids salicylic (SA), 5-sulfosalicylic (5-SSA), mandelic (MAND) and glycollic (HG) acids was studied potentiometrically. pH-titrations of the reaction mixtures containing vanadyl sulphate, 2,2'-bipyridyl and one of the dicarboxylic or hydroxy acids (OX, MALN, PHA, MAL, SA, 5-SSA, MAND and HG acids) in equimolar ratio exhibited the formation of 1:1:1 mixed ligand chelates. The formation constants of the resulting biligand chelates were calculated, at 35 + -1 0 and 45 + -1 0 and also the thermodynamic functions viz. ΔF, ΔH and ΔS (μ=0.1M KNO 3 ) (auth.)

  8. Synthesis And Characterization Of 6,6'-Bis (2-Hydroxyphenyl)-2,2'-Bipyridyl Ligand And Its Platinum Complex for the Interaction with CT-DNA

    International Nuclear Information System (INIS)

    Norhidayah Selamat; Heng, L.Y.; Nurul Izzaty Hassan; Nurul Huda Abd Karim

    2016-01-01

    A tetradentate ligand with four donor atoms OONN and its platinum metal complex were synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6 ' -dibromo-2,2 ' -bipyridyl and 2-hydroxy phenylboronic acid with the presence of palladium (II) acetate. The formation of platinum complex was done by introducing the ligand with platinum (II) chloride in benzonitrile. Both ligand and complex structures were confirmed by 1 H, 2D cosy and 13 C NMR spectroscopy, ESIMS spectrometry and FTIR spectroscopy. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs or sensors targeted on DNA. In this study, the binding interaction between the synthesized ligand and complex with calf thymus DNA (CT-DNA) has been investigated using UV-Visible and emission DNA titration. From the UV-Visible DNA study, it showed that platinum (II) bipyridine complex had higher affinity towards CT-DNA with binding constant K b =(3.1 ± 0.02 x 10 5 ) ± 0.02 M -1 compared to that of bis(phenoxy) bipyridine ligand with binding constant (K b ) = (1.19 ± 0.08) x 10 3 M -1 . These findings will be valuable for the potential use of platinum (II) bipyridine complex as a phosphorescent probe in optical sensor DNA. (author)

  9. 3D coordination polymers with nitrilotriacetic and 4,4'-bipyridyl mixed ligands: structural variation based on dinuclear or tetranuclear subunits assisted by Na-O and/or O-H...O interactions.

    Science.gov (United States)

    Lü, Xing-Qiang; Jiang, Ji-Jun; Chen, Chun-Long; Kang, Bei-Sheng; Su, Cheng-Yong

    2005-06-27

    The reactions of Cu(II) with the mixed nitrilotriacetic acid (H3NTA) and 4,4'-bipyridyl (4,4'-bpy) ligands in different metal-to-ligand ratios in the presence of NaOH and NaClO4 afforded two complexes, Na3[Cu2(NTA)2(4,4'-bpy)]ClO4 x 5H2O (1) and [Cu2(NTA) (4,4'-bpy)2]ClO4 x 4H2O (2). The two complexes have been characterized by elemental analysis, IR, XRD, and single-crystal X-ray diffraction. 1 contains a basic doubly negatively charged [Cu2(NTA)2(4,4'-bpy)]2- dinuclear unit which was further assembled via multiple Na-O and O-H...O interactions into a three-dimensional (3D) pillared-layer structure. 2 features a two-dimensional (2D) undulated brick-wall architecture containing a basic doubly positively charged [Cu4(NTA)2(4,4'-bpy)2]2+ tetranuclear unit. The 2D network possesses large cavities hosting guest molecules and was further assembled via O-H...O hydrogen bonds into a 3D structure with several channels running in different directions.

  10. Synthesis, Photophysical and Electrochemical Properties of a Mixed Bipyridyl-Phenanthrolyl Ligand Ru(II Heteroleptic Complex Having trans-2-Methyl-2-butenoic Acid Functionalities

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    Adewale O. Adeloye

    2011-09-01

    Full Text Available In this work, two ligands: 4-(trans-2-Methyl-2-butenoic acid-2,2'-bipyridine (L1 and 5-(trans-2-methyl-2-butenoic acid-1,10-phenanthroline (L2, with the corresponding mixed-ligand heteroleptic Ru(II complex were synthesized and characterized by FT-IR, 1H-, 13C-NMR spectroscopy and elemental analysis. The influence of the mixed functionalized polypyridyl ruthenium(II complex on the photophysical and electrochemical properties were investigated and compared to individual single-ligand homoleptic complexes. Interestingly, the mixed-ligand complex formulated as [RuL1L2(NCS2] exhibits broad and intense metal-to-ligand charge transfer (MLCT absorption with a high molar extinction coefficient (λmax = 514 nm, ε = 69,700 M−1 cm−1, better than those of individual single-ligand complexes, [Ru(L12(NCS2] and [Ru(L22(NCS2], and a strong photoluminescence intensity ratio in the red region at λem = 686 nm. The electrochemical properties of the complex indicated that the redox processes are ligand-based.

  11. Structures of nitrato-(2-hydroxybenzaldehydo) (2,2 Prime -bipyridyl)copper and nitrato-(2-hydroxy-5-nitrobenzaldehydo)(2,2 Prime -bipyridyl)copper

    Energy Technology Data Exchange (ETDEWEB)

    Chumakov, Yu. M. [Academy of Sciences of Moldova, Institute of Applied Physics (Moldova, Republic of); Paladi, L. G. [Moldova State University (Moldova, Republic of); Antosyak, B. Ya.; Simonov, Yu. A. [Academy of Sciences of Moldova, Institute of Applied Physics (Moldova, Republic of); Tsapkov, V. I., E-mail: vtsapkov@gmail.com [Moldova State University (Moldova, Republic of); Bocelli, G. [Institute of Materials for Electronics and Magnetism (Italy); Gulea, A. P. [Moldova State University (Moldova, Republic of); Ginju, D. [Alexandru Ioan Cuza University of Iasi (Romania); Palomares-Sanchez, S. A. [Autonomous University of San Luis Potosi (Mexico)

    2011-03-15

    Nitrato-(2-hydroxy-5-nitrobenzaldehydo)(2,2 Prime -bipyridyl)copper (I) and nitrato-(2-hydroxybenzaldehydo)(2,2 Prime -bipyridyl)copper (II) were synthesized and characterized by X-ray diffraction. The coordination polyhedron of the central copper atom in complex I can be described as a distorted tetragonal pyramid whose base is formed by the phenol and carbonyl oxygen atoms of the monodeprotonated 2-hydroxy-5nitrobenzaldehyde molecule and the nitrogen atoms of the 2,2 Prime -bipyridyl ligand and whose apex is occupied by the oxygen atom of the nitrato group. In the crystal structure, complexes I are linked by the acido ligands and the NO{sub 2} groups of the aldehyde molecule into infinite chains. In complex II, the central copper atom is coordinated by 2-hydroxybenzaldehyde, 2,2 Prime -bipyridyl, and the nitrato group, resulting in the formation of centrosymmetric dimers. The coordination polyhedron of the central copper atom can be described as a bipyramid (4 + 1 + 1) with the same base as in complex I. The axial vertices of the bipyramid are occupied by the oxygen atom of the nitrato group and the bridging phenol oxygen atom of the adjacent complex related to the initial complex by a center of symmetry. In the crystal structure, complexes II are hydrogen bonded into infinite chains.

  12. Do nonbonded H--H interactions in phenanthrene stabilize it relative to anthracene? A possible resolution to this question and its implications for ligands such as 2,2'-bipyridyl.

    Science.gov (United States)

    Hancock, Robert D; Nikolayenko, Igor V

    2012-08-23

    The problem of whether interactions between the hydrogen atoms at the 1,10-positions in the "cleft" of the "bent" phenanthrene stabilize the latter molecule thermodynamically relative to "linear" anthracene, or whether the higher stability of phenanthrene is due to a more energetically favorable π-system, is considered. DFT calculations at the X3LYP/cc-pVTZ(-f)++ level of the ground state energies (E) of anthracene, phenanthrene, and the set of five benzoquinolines are reported. In the gas phase, "bent" phenanthrene was computed to be thermodynamically more stable than "linear" anthracene by -28.5 kJ mol(-1). This fact was attributed predominantly to the phenomenon of higher aromatic stabilization of the π-system of phenanthrene relative to anthracene, and not to the stabilizing influence of the nonbonding H--H interactions in its cleft. In fact, these interactions in phenanthrene were shown to be destabilizing. Similar calculations for five benzoquinolines (bzq) indicate that ΔE values vary as: 6,7-bzq (linear) ≤ 2,3-bzq (linear) < 5,6-bzq (bent) ≤ 3,4-bzq (bent) < 7,8-bzq (bent, no H--H nonbonding interactions in cleft), supporting the idea that it is a more stable π-system that favors 7,8-bzq over 2,3-bzq and 6,7-bzq, and that the H--H interactions in the clefts of 3,4-bzq and 5,6-bzq are destabilizing. Intramolecular hydrogen bonding in the cleft of 7,8-bzq plays a secondary role in its stabilization relative 6,7-bzq. The question of whether H--H nonbonded interactions between H atoms at the 3 and 3' positions of 2,2'-bipyridyl (bpy) coordinated to metal ions are stabilizing or destabilizing is then considered. The energy of bpy is scanned as a function of N-C-C-N torsion angle (χ) in the gas-phase, and it is found that the trans form is 32.8 kJ mol(-1) more stable than the cis conformer. A relaxed coordinate scan of energy of bpy in aqueous solution as a function of χ is modeled using the PBF approach, and it is found that the trans conformer is

  13. A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II Complex: Synthesis, Photophysical and Electrochemical Properties

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    Peter A. Ajibade

    2011-06-01

    Full Text Available In our quest to develop good materials as photosensitizers for photovoltaic dye-sensitized solar cells (DSSCs, cis-dithiocyanato-4-(2,3-dimethylacrylic acid-2,2'-bipyridyl-4-(9-anthracenyl-(2,3-dimethylacrylic-2,2'-bipyridyl ruthenium(II complex, a high molar extinction coefficient charge transfer sensitizer, was designed, synthesized and characterized by spectroscopy and electrochemical techniques. Earlier studies on heteroleptic ruthenium(II complex analogues containing functionalized oligo-anthracenyl phenanthroline ligands have been reported and documented. Based on a general linear correlation between increase in the length of π-conjugation bond and the molar extinction coefficients, herein, we report the photophysical and electrochemical properties of a Ru(II bipyridyl complex analogue with a single functionalized anthracenyl unit. Interestingly, the complex shows better broad and intense metal-to ligand charge transfer (MLCT band absorption with higher molar extinction coefficient (λmax = 518 nm, e = 44900 M−1cm−1, and appreciable photoluminescence spanning the visible region than those containing higher anthracenyl units. It was shown that molar absorption coefficient of the complexes may not be solely depended on the extended π-conjugation but are reduced by molecular aggregation in the molecules.

  14. Poly[[diaqua-μ2-4,4′-bipyridyl-μ2-o-phthalato-nickel(II] dihydrate

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    Bing Li

    2008-02-01

    Full Text Available In the title layer complex, {[Ni(C8H4O4(C10H8N2(H2O2]·2H2O}n, the Ni atom has a distorted octahedral environment, defined by the phthalate and 4,4′-bipyridyl ligands which link the Ni atoms, forming a square lattice in the bc plane. This extends into a three-dimensional supramolecular network through O—H...O hydrogen-bonding interactions. The Ni atom lies on, and both ligands are bisected by, a crystallographic twofold axis.

  15. Investigation of hyperfine interactions in hafnium compounds with F1-, OH1-, and EDTA ligands by perturbed γ-γ angular correlation

    International Nuclear Information System (INIS)

    Amaral, Antonio A.; Silva, Andreia dos S.; Lapolli, Andre L.; Carbonari, Artur W.; Saxena, Rajendra N.

    2011-01-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using 181 Hf → 181 Ta, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH between 4 and 5 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  16. Application of the perturbed angular correlation in the investigation of hyperfine interactions in compounds of hafnium, indium and cadmium with F1-, OH1- and EDTA ligands

    International Nuclear Information System (INIS)

    Amaral, Antonio Acleto

    2011-01-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using 111 In → 111 Cd, 181 Hf → 181 Ta and 111m Cd → 111 Cd, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH 4.3 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  17. Investigation of hyperfine interactions in hafnium compounds with F{sup 1-}, OH{sup 1-}, and EDTA ligands by perturbed {gamma}-{gamma} angular correlation

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Antonio A.; Silva, Andreia dos S.; Lapolli, Andre L.; Carbonari, Artur W.; Saxena, Rajendra N., E-mail: alapolli@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using {sup 181}Hf {yields}{sup 181}Ta, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH between 4 and 5 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  18. Crystal structure of (4,4′-bipyridyl-κNbis[N-(2-hydroxyethyl-N-isopropyldithiocarbamato-κ2S,S′]zinc(II–4,4′-bipyridyl (2/1 and its isostructural cadmium(II analogue

    Directory of Open Access Journals (Sweden)

    Yee Seng Tan

    2017-11-01

    Full Text Available The title structures, [M(C6H12NOS22(C10H8N2]·0.5C10H8N2, for M = Zn, (I, and Cd, (II, feature terminally bound 4,4′-bipyridyl ligands and non-coordinating 4,4′-bipyridyl molecules, with the latter disposed about a centre of inversion. The coordination geometry about the metal atom is defined by two non-symmetrically chelating dithiocarbamate ligands and a pyridyl N atom. The NS4 donor sets are distorted but, approximate to trigonal bipyramidal in each case. In the crystal, hydroxy-O—H...O(hydroxy and hydroxy-O—H...N(pyridyl hydrogen bonds between the zinc-containing molecules lead to a supramolecular layer parallel to (100. The three-dimensional architecture arises as the layers are linked via methine-C—H...S, pyridyl-C—H...O(hydroxy and π–π [inter-centroid distance between coordinated pyridyl rings = 3.6246 (18 Å] interactions. Channels along the c-axis direction are occupied by the non-coordinating 4,4′-bipyridine molecules, which are held in place by C—H...π(chelate ring contacts.

  19. Synthesis, Structural Characterization, and Antitumor Activity of a Ca(II Coordination Polymer Based on 1,6-Naphthalenedisulfonate and 4,4′-Bipyridyl

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    Xishi Tai

    2013-08-01

    Full Text Available A novel Ca(II coordination polymer, [CaL(4,4′-bipyridyl(H2O4]n (L = 1,6-naphthalenedisulfonate, was synthesized by reaction of calcium perchlorate with 1,6-naphthalenedisulfonic acid disodium salt and 4,4′-bipyridyl in CH3CH2OH/H2O. It was characterized by elemental analysis, IR, molar conductivity and thermogravimetric analysis. X-ray crystallography reveals that the Ca(II coordination polymer belongs to the orthorhombic system, with space group P212121. The geometry of the Ca(II ion is a distorted CaNO6 pengonal bipyramid, arising from its coordination by four water molecules, one nitrogen atom of 4,4′-bipyridyl molecule, and two oxygen atoms from two L ligands. The complex molecules form a helical chain by self-assembly. The antitumor activity of 1,6-naphthalenedisulfonic acid disodium salt and the Ca(II coordination polymer against human hepatoma smmc-7721 cell line and human lung adenocarcinoma A549 cell line reveals that the Ca(II coordination polymer inhibits cell growth of human lung adenocarcinoma A549 cell line with IC50 value of 27 μg/mL, and is more resistive to human lung adenocarcinoma A549 cell line as compared to 1,6-naphthalenedisulfonic acid disodium salt.

  20. Ultrafast relaxation dynamics of amine-substituted bipyridyl ruthenium(II) complexes

    Science.gov (United States)

    Song, Hongwei; Wang, Xian; Yang, WenWen; He, Guiying; Kuang, Zhuoran; Li, Yang; Xia, Andong; Zhong, Yu-Wu; Kong, Fan'ao

    2017-09-01

    The excited state properties of a series of ruthenium(II) amine-substituted bipyridyl complexes, [Ru(bpy)n(NNbpy)3-n]2+, were investigated by steady-state and transient absorption spectroscopy, as well as quantum chemical calculations. The steady-state absorption spectra of these complexes in CH3CN show a distinct red-shift of the 1MLCT absorption with increasing numbers of amine substituent, whereas the emission spectra indicate an energy gap order of [Ru(bpy)3]2+ > [Ru(bpy)2(NNbpy)]2+ > [Ru(NNbpy)3]2+ > [Ru(bpy)(NNbpy)2]2+. Nanosecond, femtosecond transient absorption and electrochemical measurements suggest that NNbpy ligand has a strong influence on the electronic and emission properties of these complexes, due to electron-rich amine substituent. We illustrate how the numbers of amine substituent modulate the spectroscopic properties of transition metal complexes, which is related to the design of new electro-active systems with novel photoelectrochemical properties.

  1. Pyrrolidine constrained bipyridyl-dansyl click fluoroionophore as selective Al(3+)sensor.

    Science.gov (United States)

    Maity, Debabrata; Govindaraju, T

    2010-07-07

    A pyrrolidine constrained bipyridyl-dansyl (ionophore-fluorophore) conjugate with triazole linker was synthesised through click chemistry. The fluoroionophore serves as a selective ratiometric and colorimetric chemosensor for Al(3+) based on internal charge transfer (ICT).

  2. Synthesis, spectroscopy and biological investigations of manganese(III) Schiff base complexes derived from heterocyclic β-diketone with various primary amine and 2,2'-bipyridyl

    Science.gov (United States)

    Surati, Kiran R.

    2011-06-01

    The mixed ligand mononuclear complex [Mn(bipy)(HPMFP)(OAc)]ClO 4 was synthesized by reaction of Mn(OAc) 3·2H 2O with HPMFP and 2,2'-bipyridyl. The corresponding Schiff base complexes were prepared by condensation of [Mn(bipy)(HPMFP)(OAc)]ClO 4 with ethylenediamine, ethanolamine and glycine (where HPMFP = 1-phenyl-3methyl-4-formyl-2-pyrazolin-5one, bipy = 2,2'-bipyridyl). All the compounds have been characterized by elemental analysis, magnetic susceptibility, conductometry measurements and 1H and 13C NMR, FT-IR, mass spectrometry. Electronic spectral and magnetic susceptibility measurements indicate square pyramidal geometry around manganese(III) ion. The thermal stabilities, activation energy E*, entropy change Δ S*, enthalpy change Δ H* and heat capacity of thermal degradation for these complexes were determined by TGA and DSC. The in vitro antibacterial and antifungal activity of four coordination compounds and ligand HPMFP were investigated. In vitro activates of Bacillus subtillis (MTCC-619), Staphylococcus aureus (MTCC-96), Escherichia coli (MTCC-722) and Klebsiella pneumonia (MTCC-109) bacteria and the fungus Candida albicans (ATCC-90028) were determined. All the compounds showed good antimicrobial activity. The antimicrobial activities increased as formation of Schiff base.

  3. Uptake of some lanthanides on γ-zirconium phosphate-phosphite and its 1,10-phenanthroline and 2,2-bipyridyl intercalated products

    International Nuclear Information System (INIS)

    Shakshooki, S.K.; El Hanash, H.B.; El-Mehdawi, R.M.; El-Mellah, M.A.; Arafa, E.A.; Bejey, A.M.

    1999-01-01

    γ-zirconium phosphate-phosphite, γ-Zr x PO 4 x H 2 PO 3 x 2H 2 O, (γ-ZrPP), was prepared and characterized. Direct treatment of γ-zirconium phosphate-phosphite with an ethanol solution of 0.1M 1,10-phenanthrolin and 2,2'-bipyridyl gave the well defined composites, γ-Zr x PO 4 x H 2 PO 3 (phen) 0.15 x H 2 O and γ-Zr x PO 4 x H 2 PO 3 (bipy) 0.18 x 0.6H 2 O respectively. K d values of a mixture of lanthanide ions: La 3+ , Sm 3+ , Eu 3+ and Yb 3+ for the intercalated products and for γ-ZrPP in HNO 3 solution at room temperature and at pH 2 and 4 were determined by a radiotracer technique. 140 La, 152m Eu, 153 Sm and 175 Yb radioisotopes were used for the equilibration experiment using 500 μl (4.0 x 10 -5 mmole) each of the solutions of the tracers as a mixture in 7.5 M HNO 3 solution at the desired pH with 0.1 g of γ-ZrPP and of the intercalated products. The selectivity order was found to be dependent on the nature of the ligand and on the pH. The 2,2'-bipyridyl product possesses, at pH 2 in general, a high K d value, specially for Sm 3+ (9815.9) compared to that of the 1,10-phenanthrolin product (3375.5) and to γ-ZrPP (419.8). This could be attributed to partial deintercalation of the 2,2' -bipyridyl at pH 2 and increasing of ionogenic groups. (author)

  4. Effect of Particle Association on 2,2'-Bipyridyl Adsorption onto Kaolinite.

    Science.gov (United States)

    Helmy, A. K.; Ferreiro, E. A.; de Bussetti, S. G.

    2000-05-15

    The effect of particle concentration, in kaolin suspensions, on the adsorption of 2,2'-bipyridyl was studied. Adsorption expressed in units of micromoles per gram decreased as a result of the increase in particle concentration and also as a result of the presence of coagulant (0.25 M NaCl). Dispersion treatment with sodium hexametaphosphate increased the adsorption of bipyridyl. The decrease in adsorption with the increase in particle concentration suggests a possible relation between adsorption and flocculation phenomena. On the basis of classic flocculation theory a straight-line relation was obtained between the square root of the adsorption maximum (mmol/L) and particle concentration (g/L). It is concluded that particle association, which is a function of particle concentration, reduces the surface/aqueous interface and consequently the adsorption of bipyridyl. Copyright 2000 Academic Press.

  5. Novel cocrystal of N-phthaloyl-β-alanine with 2,2-bipyridyl: Synthesis, computational and free radical scavenging activity studies

    Science.gov (United States)

    Chahkandi, Mohammad; Bhatti, Moazzam H.; Yunus, Uzma; Rehman, Naima; Nadeem, Muhammad; Tahir, Muhammad Nawaz; Zakria, Muhammad

    2018-01-01

    In the present work a novel cocrystal adduct of N-phthaloyl-β-alanine and 2,2-bipyridyl as compound 1 with molecular formula C16H13N3O4 was synthesized by slow evaporation process of the ethanoic solution containing these two moieties. In followings, the crystal structure and photophysical properties of 1 was characterized by single X-ray crystal analysis, FTIR, and UV-Vis spectra. The thermal behavior was analyzed by the Thermogravimetric/Differential Thermal Analyzer (TG-DTA). The cocrystal belong to monoclinic crystallographic system with space group P21/n, Z = 4. DPPH radical scavenging activity of the title cocrystal is slightly higher than coformer with lower IC50 value. Finally, using DFT calculations executed at hybrid B3LYP/6-311+G (d, p) level of theory the geometric and electronic structures of the crystalline network of C16H13N3O4 (1), studied. Inter-molecular conventional Osbnd H⋯N as well as the non-conventional Csbnd H⋯O hydrogen bonds (HBs) and Csbnd H···π and Csbnd O···π stacking interactions gathered the monomeric structures of 1 (1-mon) to create the 3D architecture of the network (1-net). The dispersion corrected density functional theory (DFT-D) calculations indicate that Osbnd H⋯N and Csbnd H⋯O HBs, govern the 1-net formation. The calculated UV-Vis spectrum in vacuo has agreement with the experimental one that shows five major bands in the range of 170-271 nm that could assigned to transitions between 2,2-bipyridyl and N-phthaloyl-β-alanine parts of 1 with n → π∗ and π → π* ligand-ligand-charge transfer (LLCT) character. The calculated electronic spectra in solvents (water, acetonitrile, methanol, and n-heptane) comparing with the vacuo one show broad bands with blue shifts.

  6. Ruthenium(II)- bipyridyl with extended π-system: Improved thermo ...

    Indian Academy of Sciences (India)

    aInorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Uppal Road, Tarnaka, ... A new extended thermo-stable high molar extinction coefficient bipyridyl ruthenium(II) complex ... cyanines and metal free organic sensitizers have been ..... Iodide-based ionic liquids are more viscous than.

  7. Application of the perturbed angular correlation in the investigation of hyperfine interactions in compounds of hafnium, indium and cadmium with F{sup 1-}, OH{sup 1-} and EDTA ligands; Aplicacao da espectroscopia de correlacao angular perturbada na investigacao de interacoes hiperfinas em compostos de hafnio, indio e cadmio com os ligantes F{sup 1-}, OH{sup 1-} e EDTA

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Antonio Acleto

    2011-07-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using {sup 111}In {yields} {sup 111}Cd, {sup 181}Hf {yields} {sup 181}Ta and {sup 111m}Cd {yields}{sup 111}Cd, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH 4.3 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  8. A bioinspired copper 2,2-bipyridyl complex immobilized MWCNT modified electrode prepared by a new strategy for elegant electrocatalytic reduction and sensing of hydrogen peroxide

    International Nuclear Information System (INIS)

    Mayuri, Pinapeddavari; Saravanan, Natarajan; Senthil Kumar, Annamalai

    2017-01-01

    Owing to facile electron-transfer reaction, metal complex based molecular architecture has attracted much interest in electrochemistry, especially for bioinspired electrocatalytic and electrochemical sensor applications. Indeed, preparation of stable surface-confined molecular system is a challenging task. In general, derivatization methodology, in which, a specific functional groups such as thiol, carboxylic acid, pyrene and amino bearing inorganic complexes synthesized discreetly by chemical approach have been attached suitably on electrode surface via any one of the following techniques; self-assembly, covalent immobilization, electrostatic interaction, ionic exchange and encapsulation. Herein, we report a copper-bipyridyl complex immobilized multiwalled carbon nanotube (MWCNT)-Nafion (Nf) modified glassy carbon electrode (GCE/Nf-MWCNT@bpy-Cu"2"+) prepared by a new strategy in which sequential modification of bipyridyl (bpy) ligand on MWCNT via π-π interaction followed by in-situ complexation with copper ion for efficient electrochemical reduction of H_2O_2. The copper species chemically modified electrode showed highly stable and well-defined surface-confined Cu"2"+"/"1"+ redox peak response, without any Cu"1"+"/"0 redox transition, at an equilibrium potential, E_1_/_2 = −135 mV vs Ag/AgCl in a pH 7 phosphate buffer solution. Detailed physico-chemical characterization by SEM, FT-IR, Raman and ESI-MS and electrochemical characterization reveals that [Cu(bpy)_2(H_2O)_2]"+ (molecular weight 413.4) like species was immobilized as a major species on the modified electrode. A bioinspired electro-catalytic reduction of H_2O_2 was studied using cyclic voltammetric and rotating disc electrode techniques. In further, electrochemical sensing of H_2O_2 by amperometric i-t and flow injection analysis methods with a detection limit values 4.5 and 0.49 μM respectively were demonstrated.

  9. Angular Momentum

    Science.gov (United States)

    Shakur, Asif; Sinatra, Taylor

    2013-01-01

    The gyroscope in a smartphone was employed in a physics laboratory setting to verify the conservation of angular momentum and the nonconservation of rotational kinetic energy. As is well-known, smartphones are ubiquitous on college campuses. These devices have a panoply of built-in sensors. This creates a unique opportunity for a new paradigm in…

  10. Experimental studies on the nature of bonding of DNA/bipyridyl-(ethylenediamine)platinum(II) and DNA/netropsin complexes in solution and oriented wet-spun films

    Science.gov (United States)

    Marlowe, R. L.; Szabo, A.; Lee, S. A.; Rupprecht, A.

    2002-03-01

    The stability of complexes of NaDNA with bipyridyl-(ethylenediamine)platinum(II) (abbreviated [(bipy)Pt(en)]) and with netropsin has been studied using two techniques: (i) ultraviolet melting experiments were done on NaDNA/[(bipy)Pt(en)], showing that the [(bipy)Pt(en)] ligand stabilizes the DNA double helix structure; and (ii) swelling measurements (via optical microscopy) as a function of relative humidity were done on wet-spun oriented films of NaDNA/[(bipy)Pt(en)] and of NaDNA/netropsin. The swelling data shows that an irreversible transition of the films occurs at high relative humidity, first for the NaDNA/netropsin, then for pure NaDNA, and lastly for the NaDNA/[(bipy)Pt(en)]. These results are indicative that the [(bipy)Pt(en)] complex stabilizes the intermolecular bonds which mediate the film swelling characteristics. A model is suggested for the binding of [(bipy)Pt(en)] to DNA to explain why the swelling experiments show this ligand as increasing the intermolecular bond strength between the DNA double helices, while netropsin decreases this degree of stabilization.

  11. (Carbonato-κ(2)O,O')bis-(5,5'-dimethyl-2,2'-bipyridyl-κ(2)N,N')cobalt(III) bromide trihydrate.

    Science.gov (United States)

    Arun Kumar, Kannan; Meera, Parthsarathi; Amutha Selvi, Madhavan; Dayalan, Arunachalam

    2012-04-01

    In the title complex, [Co(CO(3))(C(12)H(12)N(2))(2)]Br·3H(2)O, the Co(III) cation has a distorted octa-hedral coordination environment. It is chelated by four N atoms of two different 5,5'-dimethyl-2,2'-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water mol-ecules are disordered and their H atoms were not located, there are typical O⋯O distances between 2.8 and 3.0 Å, indicating O-H⋯O hydrogen bonding. The crystal packing is consolidated by C-H⋯O and C-H⋯Br hydrogen bonds, as well as π-π stacking inter-actions between adjacent pyridine rings of the dmbpy ligands, with centroid-centroid distances of 3.694 (3) and 3.7053 (3) Å.

  12. A sensitive method for assay of beryllium with chromazurol S and 2,2'-bipyridyl

    International Nuclear Information System (INIS)

    Buhl, F.; Kwapulinska, G.

    1980-01-01

    A spectrophotometric method of assay for microgram amounts of beryllium by means of chromazurol S in presence of 2,2'-bipyridyl was described. The latter appreciably enhances the sensitivity of the method; epsilonsub(lambda=610nm) is 5.4X10 4 . The complex compound obeys the Lambert-Beer law in the concentration range 0.002 to 0.2 ppm Be. The maximum colour intensity is immediately attained at pH 5. The molar ratio Be: CHAS: bip is 1 : 2 : 1. The suggested method is sensitive and has satisfactory selectivity when EDTA is applied as masking agent. (author)

  13. Femtosecond double proton transfer dynamics in [2,2'-bipyridyl]-3,3'-diol in sol-gel glasses

    NARCIS (Netherlands)

    Prosposito, P.; Marks, D.R.A.; Zhang, H.; Glasbeek, M.

    1998-01-01

    Abstract: Intramolecular excited state double proton-transfer dynamics has been studied for [2,2'-bipyridyl]-3,3'-diol (BP(OH)2) in sol-gel glass. By means of the femtosecond fluorescence up-conversion technique, the spectral dependence of the fluorescence transients obtained for BP(OH)2 in a few

  14. Bis(2,2'-bipyridyl-κN,N')(carbonato-κO,O')cobalt(III) bromide trihydrate.

    Science.gov (United States)

    Ma, Peng-Tao; Wang, Yu-Xia; Zhang, Guo-Qian; Li, Ming-Xue

    2007-12-06

    The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H⋯Br and O-H⋯O hydrogen bonds, generating a one-dimensional chain.

  15. Synthesis and characterization of 6,6'-bis(2-hydroxyphenyl)-2,2'-bipyridine ligand and its interaction with ct-DNA

    Science.gov (United States)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd

    2015-09-01

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6'-dibromo-2,2'-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6'-bis(2-methoxyphenyl)-2,2'-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by 1H, 2D cosy and 13C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant Kb = 1.19 × 103 ± 0.08 M-1.

  16. Synthesis and characterization of 6,6’-bis(2-hydroxyphenyl)-2,2’-bipyridine ligand and its interaction with ct-DNA

    International Nuclear Information System (INIS)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd

    2015-01-01

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6’-dibromo-2,2’-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6’-bis(2-methoxyphenyl)-2,2’-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by 1 H, 2D cosy and 13 C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant K b = 1.19 × 10 3 ± 0.08 M −1

  17. Synthesis and characterization of 6,6’-bis(2-hydroxyphenyl)-2,2’-bipyridine ligand and its interaction with ct-DNA

    Energy Technology Data Exchange (ETDEWEB)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43650 Bangi, Selangor (Malaysia)

    2015-09-25

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6’-dibromo-2,2’-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6’-bis(2-methoxyphenyl)-2,2’-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by {sup 1}H, 2D cosy and {sup 13}C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant K{sub b} = 1.19 × 10{sup 3} ± 0.08 M{sup −1}.

  18. Tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based electrochemiluminescence coupled with capillary zone electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jingwu [Department of Chemistry, Nanchang University, Nanchang 330031 (China)], E-mail: wangjingwu@ncu.edu.cn; Zhang Xiaojun; Pi Fangfang [Department of Chemistry, Nanchang University, Nanchang 330031 (China); Wang Xiaoxia [Graduate School of Engineering, University of Fukui, Fukui 910-8507 (Japan); Yang Nianjun [Diamond Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Central 2-13, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)], E-mail: nianjun.yang@iaf.fraunhofer.de

    2009-03-01

    Capillary zone electrophoresis (CZE) coupled with tris(2,2'-bipyridyl) ruthenium(II)-based end-column electrogenerated chemiluminescence (ECL) has been utilized to detect bisoprolol in drugs and tablets after its separation from metoprolol. Tetrahydrofuran was used as an additive in the running buffer to obtain the absolute ECL peak of bisoprolol. Bisoprolol reacts as a co-reactant in tris(2,2'-bipyridyl) ruthenium(II) ECL system. Under the optimized experimental conditions, bisoprolol was separated successfully and efficiently from metoprolol and other co-existed materials in tablets and urine samples. The ECL intensity of tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based system is linear with the concentration of bisoprolol from 1.5 {mu}M to 0.3 mM with a detection limit of 0.3 {mu}M. Relative standard derivations of the ECL intensity are 2.58% for the detection of 15 {mu}M bisoprolol. This method is a simple, rapid, selective, and sensitive. It was applied successfully for the monitoring of bisoprolol in market available tablets and human urine samples.

  19. Ruthenium(II) chloro-bis(bipyridyl) complexes with substituted pyridine ligands: interpretation of their electronic absorption spectra

    International Nuclear Information System (INIS)

    Sizova, O.V.; Ershov, A.Yu.; Ivanova, N.V.; Shashko, A.D.; Kutejkina-Teplyakova, A.V.

    2003-01-01

    A number of complexes cis-[Ru(Bipy) 2 (L)(Cl)](BF 4 ), where Bipy-2,2'-bipyridine, L-pyridine, 4-aminopyridine, 4-picoline, nicotinamide, isonicotinamide, 3- and 4-cyanopyridine, 4,4'-bipyridine, trans-1,2-bis(4-pyridyl)ethylene, 4,4'-azopyridine, pyrazine, imidazole and NH 3 , were prepared. Using the CINDO-CI semiempirical method the energies and intensities of transition in electronic absorption spectra (EAS) of the complexes were calculated. It is shown that major differences in EAS of the compounds stem from position of transitions with charge transfer d π (Ru)→π*(L) [ru

  20. Nafion/2,2'-bipyridyl-modified bismuth film electrode for anodic stripping voltammetry

    International Nuclear Information System (INIS)

    Torma, Ferenc; Kadar, Mihaly; Toth, Klara; Tatar, Eniko

    2008-01-01

    This paper describes the fabrication, characterisation and the application of a Nafion/2,2'-bipyridyl/bismuth composite film-coated glassy carbon electrode (NC(Bpy)BiFE) for the anodic stripping voltammetric determination of trace metal ions (Zn 2+ , Cd 2+ and Pb 2+ ). The NC(Bpy)BiFE electrode is prepared by first applying a 2.5 mm 3 drop of a coating solution containing 0.5 wt% Nafion and 0.1% (w/v) 2,2'-bipyridil (Bpy) onto the surface of a glassy carbon electrode, while the Bi film was plated in situ simultaneously with the target metal ions at -1.4 V. The main advantage of the polymer coated bismuth film electrode is that the sensitivity of the stripping responses is increased considerably due to the incorporation of the neutral chelating agent of 2,2'-bipyridyl (Bpy) in the Nafion film, while the Nafion coating improved the mechanical stability of the bismuth film and its resistance to the interference of surfactants. The key experimental parameters relevant to both the electrode fabrication and the voltammetric measurement were optimized on the basis of the stripping signals. With a 2 min deposition time in the presence of oxygen, linear calibration curves were obtained in a wide concentration range (about 2-0.001 μM) with detection limits of 8.6 nM (0.56 μg dm -3 ) for Zn 2+ , 1.1 nM (0.12 μg dm -3 ) for Cd 2+ and 0.37 nM (0.077 μg dm -3 ) for Pb 2+ . For nine successive preconcentration/determination/electrode renewal experiments the standard deviations were between 3 and 5% at 1.2 μM for zinc and 0.3-0.3 μM concentration level for lead and cadmium, respectively, and the method exhibited excellent selectivity in the presence of the excess of several potential interfering metal ions. The analytical utility of the stripping voltammetric method elaborated was tested in the assay of heavy metals in some real samples and the method was validated by ICP-MS technique

  1. (Carbonato-κ2 O,O′)bis­(5,5′-dimethyl-2,2′-bipyridyl-κ2 N,N′)cobalt(III) bromide trihydrate

    Science.gov (United States)

    Arun Kumar, Kannan; Meera, Parthsarathi; Amutha Selvi, Madhavan; Dayalan, Arunachalam

    2012-01-01

    In the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octa­hedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water mol­ecules are disordered and their H atoms were not located, there are typical O⋯O distances between 2.8 and 3.0 Å, indicating O—H⋯O hydrogen bonding. The crystal packing is consolidated by C—H⋯O and C—H⋯Br hydrogen bonds, as well as π–π stacking inter­actions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694 (3) and 3.7053 (3) Å. PMID:22589773

  2. Professional AngularJS

    CERN Document Server

    Karpov, Valeri

    2015-01-01

    A comprehensive guide to AngularJS, Google's open-source client-side framework for app development. Most of the existing guides to AngularJS struggle to provide simple and understandable explanations for more advanced concepts. As a result, some developers who understand all the basic concepts of AngularJS struggle when it comes to building more complex real-world applications. Professional AngularJS provides a thorough understanding of AngularJS, covering everything from basic concepts, such as directives and data binding, to more advanced concepts like transclusion, build systems, and auto

  3. Angular correlation methods

    International Nuclear Information System (INIS)

    Ferguson, A.J.

    1974-01-01

    An outline of the theory of angular correlations is presented, and the difference between the modern density matrix method and the traditional wave function method is stressed. Comments are offered on particular angular correlation theoretical techniques. A brief discussion is given of recent studies of gamma ray angular correlations of reaction products recoiling with high velocity into vacuum. Two methods for optimization to obtain the most accurate expansion coefficients of the correlation are discussed. (1 figure, 53 references) (U.S.)

  4. Rotations and angular momentum

    International Nuclear Information System (INIS)

    Nyborg, P.; Froyland, J.

    1979-01-01

    This paper is devoted to the analysis of rotational invariance and the properties of angular momentum in quantum mechanics. In particular, the problem of addition of angular momenta is treated in detail, and tables of Clebsch-Gordan coefficients are included

  5. Angular Acceleration without Torque?

    Science.gov (United States)

    Kaufman, Richard D.

    2012-01-01

    Hardly. Just as Robert Johns qualitatively describes angular acceleration by an internal force in his article "Acceleration Without Force?" here we will extend the discussion to consider angular acceleration by an internal torque. As we will see, this internal torque is due to an internal force acting at a distance from an instantaneous center.

  6. Flow injection chemiluminescent determination of N-nitrosodimethylamine using photogenerated tris(2,2'-bipyridyl) ruthenium (III)

    International Nuclear Information System (INIS)

    Perez-Ruiz, Tomas; Martinez-Lozano, Carmen; Tomas, Virginia; Martin, Jesus

    2005-01-01

    A flow injection configuration was developed and evaluated for the chemiluminescent determination of N-nitrosodimethylamine. The method is based on the on-line cleavage of the N-NO bond of the nitrosamine by irradiation with ultraviolet light. The dimethylamine generated was subsequently reacted with tris(2,2'-bipyridyl) ruthenium (III), which was generated through the on-line photo-oxidation of tris(2,2'-bipyridyl) ruthenium (II) with peroxydisulfate. After selecting the best operating parameters, the emitted light showed a linear relationship with the concentration of N-nitrosodimethylamine between 1.5 and 148 ng ml -1 , with a detection limit of 0.29 ng ml -1 . The repeatability was 1.6% expressed as relative standard deviation (n = 10) and the reproducibility, studied on five consecutive days, was 3.2%. The sample throughput was 50 injections per hour. The method was applied to studying the recoveries of N-nitrosodimethylamine in water and different cured meat products

  7. Mixed-ligand Ru(II) complexes with 2,2'-bipyridine and aryldiazo-beta-diketonato auxillary ligands: synthesis, physico-chemical study and antitumour properties.

    Science.gov (United States)

    Mishra, Lallan; Yadaw, Ajay K; Bhattacharya, Subrato; Dubey, Santosh K

    2005-05-01

    The complexes of Ru(II)-2,2'-bipyridyl with substituted diazopentane-2,4-diones (L1H-L5H) were synthesized and characterized by elemental analyses, conductance, FAB (fast atom bombardment) mass and spectral (IR, UV/Vis (UV/visible), NMR) studies. Molecular geometry optimization of the complexes was also made. None of the complexes luminesce. However, facilitated oxidation of Ru(II) to Ru(III) was evidenced from their lower reduction potential data. The ligands and their complexes were tested for their antitumour activity against a variety of tumour cell lines. Though activity is found to vary with the type of tumour cell lines used, yet complex 5 with naphtyldiazopentane-2,4-dione as co-ligand was found to be a potential compound as it showed in general significant activity against all cell lines studied.

  8. Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Burkardt Matthias

    2015-01-01

    Full Text Available Definitions of orbital angular momentum based on Wigner distributions are used as a framework to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. We find that the difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asymmetries in semi-inclusive deep-inelastic scattering.

  9. Optical Angular Momentum

    International Nuclear Information System (INIS)

    Arimondo, Ennio

    2004-01-01

    For many years the Institute of Physics has published books on hot topics based on a collection of reprints from different journals, including some remarks by the editors of each volume. The book on Optical Angular Momentum, edited by L Allen, S M Barnett and M J Padgett, is a recent addition to the series. It reproduces forty four papers originally published in different journals and in a few cases it provides direct access to works not easily accessible to a web navigator. The collection covers nearly a hundred years of progress in physics, starting from an historic 1909 paper by Poynting, and ending with a 2002 paper by Padgett, Barnett and coworkers on the measurement of the orbital angular momentum of a single photon. The field of optical angular momentum has expanded greatly, creating an interdisciplinary attraction for researchers operating in quantum optics, atomic physics, solid state physics, biophysics and quantum information theory. The development of laser optics, especially the control of single mode sources, has made possible the specific design of optical radiation modes with a high degree of control on the light angular momentum. The editors of this book are important figures in the field of angular momentum, having contributed to key progress in the area. L Allen published an historical paper in 1999, he and M J Padgett (together with M Babiker) produced few years ago a long review article which is today still the most complete basic introduction to the angular momentum of light, while S M Barnett has contributed several high quality papers to the progress of this area of physics. The editors' choice provides an excellent overview to all readers, with papers classified into eight different topics, covering the basic principles of the light and spin and orbital angular momentum, the laboratory tools for creating laser beams carrying orbital angular momentum, the optical forces and torques created by laser beams carrying angular momentum on

  10. Angular Accelerating White Light

    CSIR Research Space (South Africa)

    Dudley, Angela L

    2015-08-01

    Full Text Available wavelength dependence. By digitally simulating free-space propagation on the SLM, The authors compare the effects of real and digital propagation on the angular rotation rates of the resulting optical fields for various wavelengths. The development...

  11. Angular trap for macroparticles

    International Nuclear Information System (INIS)

    Aksyonov, D.S.

    2013-01-01

    Properties of angular macroparticle traps were investigated in this work. These properties are required to design vacuum arc plasma filters. The correlation between trap geometry parameters and its ability to absorb macroparticles were found. Calculations allow one to predict the behaviour of filtering abilities of separators which contain such traps in their design. Recommendations regarding the use of angular traps in filters of different builds are given.

  12. Electrochemical ion transfer mediated by a lipophilic Os(ii)/Os(iii) dinonyl bipyridyl probe incorporated in thin film membranes.

    Science.gov (United States)

    Jansod, Sutida; Wang, Lu; Cuartero, Maria; Bakker, Eric

    2017-09-28

    A new lipophilic dinonyl bipyridyl Os(ii)/Os(iii) complex successfully mediates ion transfer processes across voltammetric thin membranes. An added lipophilic cation-exchanger may impose voltammetric anion or cation transfer waves of Gaussian shape that are reversible and repeatable. The peak potential is found to shift with the ion concentration in agreement with the Nernst equation. The addition of tridodecylmethylammonium nitrate to the polymeric film dramatically reduces the peak separation from 240 mV to 65 mV, and the peak width to a near-theoretical value of 85 mV, which agrees with a surface confined process. It is suggested that the cationic additive serves as a phase transfer catalyst.

  13. Symmetric bi-pyridyl banana-shaped molecule and its intermolecular hydrogen bonding liquid-crystalline complexes

    Science.gov (United States)

    Sui, Dan; Hou, Qiufei; Chai, Jia; Ye, Ling; Zhao, Liyan; Li, Min; Jiang, Shimei

    2008-11-01

    A new symmetric bi-pyridyl banana-shaped molecule 1,3-phenylene diisonicotinate (PDI) was designed and synthesized. Its molecular structure was confirmed by FTIR, Elemental analysis and 1H NMR. X-ray crystallographic study reveals that there is an angle of approximate 118° among the centroids of the three rings (pyridyl-phenyl-pyridyl) in each PDI molecule indicating a desired banana shape. In addition, a series of liquid crystal complexes nBA:PDI:nBA induced by intermolecular hydrogen bonding between PDI (proton acceptor) and 4-alkoxybenzoic acids (nBA, proton donor) were synthesized and characterized. The mesomorphism properties and optical textures of the complex of nBA:PDI:nBA were investigated by differential scanning calorimetry, polarizing optical microscope and X-ray diffraction.

  14. Fission fragment angular momentum

    International Nuclear Information System (INIS)

    Frenne, D. De

    1991-01-01

    Most of the energy released in fission is converted into translational kinetic energy of the fragments. The remaining excitation energy will be distributed among neutrons and gammas. An important parameter characterizing the scission configuration is the primary angular momentum of the nascent fragments. Neutron emission is not expected to decrease the spin of the fragments by more than one unit of angular momentum and is as such of less importance in the determination of the initial fragment spins. Gamma emission is a suitable tool in studying initial fragment spins because the emission time, number, energy, and multipolarity of the gammas strongly depend on the value of the primary angular momentum. The main conclusions of experiments on gamma emission were that the initial angular momentum of the fragments is large compared to the ground state spin and oriented perpendicular to the fission axis. Most of the recent information concerning initial fragment spin distributions comes from the measurement of isomeric ratios for isomeric pairs produced in fission. Although in nearly every mass chain isomers are known, only a small number are suitable for initial fission fragment spin studies. Yield and half-life considerations strongly limit the number of candidates. This has the advantage that the behavior of a specific isomeric pair can be investigated for a number of fissioning systems at different excitation energies of the fragments and fissioning nuclei. Because most of the recent information on primary angular momenta comes from measurements of isomeric ratios, the global deexcitation process of the fragments and the calculation of the initial fragment spin distribution from measured isomeric ratios are discussed here. The most important results on primary angular momentum determinations are reviewed and some theoretical approaches are given. 45 refs., 7 figs., 2 tabs

  15. Detection of pyrrolizidine alkaloids using flow analysis with both acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence

    International Nuclear Information System (INIS)

    Gorman, Bree A.; Barnett, Neil W.; Bos, Richard

    2005-01-01

    For the first time, analytically useful chemiluminescence was elicited from the reactions of the pyrrolizidine alkaloids. Heliotrine, retronecine, supinine, monocrotaline and echinatine N-oxide yielded chemiluminescence upon reaction with tris(2,2'-bipyridyl)ruthenium(II) whilst lasiocarpine, its N-oxide and supinine elicited light upon reaction with acidic potassium permanganate. Detection limits for heliotrine were 1.25 x 10 -7 M and 9 x 10 -9 M for tris(2,2'-bipyridyl)ruthenium(III) perchlorate with flow injection analysis (FIA) and the silica-immobilised reagent (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2,2'-bipyridine)bis (2,2'-bipyridyl)ruthenium(II) with sequential injection analysis (SIA), respectively. Lasiocarpine was detectable at 1.4 x 10 -7 M using acidic potassium permanganate with FIA. Additionally, the silica-immobilised reagent was optimised with respect to the oxidant (ammonium ceric nitrate) concentration and the aspiration times which afforded a detection limit for codeine of 5 x 10 -10 M using SIA

  16. Detection of pyrrolizidine alkaloids using flow analysis with both acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence

    Energy Technology Data Exchange (ETDEWEB)

    Gorman, Bree A. [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia); Barnett, Neil W. [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia)]. E-mail: barnie@deakin.edu.au; Bos, Richard [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia)

    2005-06-13

    For the first time, analytically useful chemiluminescence was elicited from the reactions of the pyrrolizidine alkaloids. Heliotrine, retronecine, supinine, monocrotaline and echinatine N-oxide yielded chemiluminescence upon reaction with tris(2,2'-bipyridyl)ruthenium(II) whilst lasiocarpine, its N-oxide and supinine elicited light upon reaction with acidic potassium permanganate. Detection limits for heliotrine were 1.25 x 10{sup -7} M and 9 x 10{sup -9} M for tris(2,2'-bipyridyl)ruthenium(III) perchlorate with flow injection analysis (FIA) and the silica-immobilised reagent (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2,2'-bipyridine)bis (2,2'-bipyridyl)ruthenium(II) with sequential injection analysis (SIA), respectively. Lasiocarpine was detectable at 1.4 x 10{sup -7} M using acidic potassium permanganate with FIA. Additionally, the silica-immobilised reagent was optimised with respect to the oxidant (ammonium ceric nitrate) concentration and the aspiration times which afforded a detection limit for codeine of 5 x 10{sup -10} M using SIA.

  17. Structural and Electrochemical Consequences of [Cp*] Ligand Protonation.

    Science.gov (United States)

    Peng, Yun; Ramos-Garcés, Mario V; Lionetti, Davide; Blakemore, James D

    2017-09-05

    There are few examples of the isolation of analogous metal complexes bearing [η 5 -Cp*] and [η 4 -Cp*H] (Cp* = pentamethylcyclopentadienyl) complexes within the same metal/ligand framework, despite the relevance of such structures to catalytic applications. Recently, protonation of Cp*Rh(bpy) (bpy = 2,2'-bipyridyl) has been shown to yield a complex bearing the uncommon [η 4 -Cp*H] ligand, rather than generating a [Rh III -H] complex. We now report the purification and isolation of this protonated species, as well as characterization of analogous complexes of 1,10-phenanthroline (phen). Specifically, reaction of Cp*Rh(bpy) or Cp*Rh(phen) with 1 equiv of Et 3 NH + Br - affords rhodium compounds bearing endo-η 4 -pentamethylcyclopentadiene (η 4 -Cp*H) as a ligand. NMR spectroscopy and single-crystal X-ray diffraction studies confirm protonation of the Cp* ligand, rather than formation of metal hydride complexes. Analysis of new structural data and electronic spectra suggests that phen is significantly reduced in Cp*Rh(phen), similar to the case of Cp*Rh(bpy). Backbonding interactions with olefinic motifs are activated by formation of [η 4 -Cp*H]; protonation of [Cp*] stabilizes the low-valent metal center and results in loss of reduced character on the diimine ligands. In accord with these changes in electronic structure, electrochemical studies reveal a distinct manifold of redox processes that are accessible in the [Cp*H] complexes in comparison with their [Cp*] analogues; these processes suggest new applications in catalysis for the complexes bearing endo-η 4 -Cp*H.

  18. Angular momentum projected semiclassics

    International Nuclear Information System (INIS)

    Hasse, R.W.

    1986-10-01

    By using angular momentum projected plane waves as wave functions, we derive semiclassical expressions for the single-particle propagator, the partition function, the nonlocal density matrix, the single-particle density and the one particle- one hole level density for fixed angular momentum and fixed z-component or summed over the z-components. Other quantities can be deduced from the propagator. In coordinate space (r, r') the relevant quantities depend on vertical stroker - r 3 vertical stroke instead of vertical stroker - r'vertical stroke and in Wigner space (R, P) they become proportional to the angular momentum constraints δ(vertical strokeRxPvertical stroke/ℎ - l) and δ((RxP) z /ℎ - m). As applications we calculate the single-particle and one particle- one hole level densities for harmonic oscillator and Hill-Wheeler box potentials and the imaginary part of the optical potential and its volume integral with an underlying harmonic oscillator potential and a zero range two-body interaction. (orig.)

  19. Catalytic behaviors of Co{sup II} and Mn{sup II} compounds bearing α-Diimine ligands for oxidative polymerization or drying oils

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Gilvan E.S.; Nunes, Everton V.; Dantas, Roberta C.; Meneghetti, Mario R.; Meneghetti, Simoni M.P., E-mail: simoni.plentz@gmail.com [Universidade Federal de Alagoas (UFAL), Maceió, AL (Brazil). Grupo de Catálise e Reatividade Química; Simone, Carlos A. de [Universidade de Sao Paulo (USP), São Carlos, USP, SP (Brazil). Instituto de Física

    2018-05-01

    The oxidative polymerization of linseed oil was investigated comparing the classical catalysts cobalt(II) 2-ethylhexanoate and manganese(II) 2-ethylhexanoate and their derivatives modified by the presence of chelating nitrogen ligands, i.e., 2,2’-bipyridyl, 2-(acetyl-2,6-diisopropylphenylimine)- pyridine and [N-(2,6-diisopropylphenyl)imine]acenaphthoquinone. The suitable stoichiometries between the two precursor complexes with the three ligands were determined by UV-visible spectroscopy. All complexes were characterized by infrared spectroscopy, and one complex was characterized also by X-ray diffraction. The apparent kinetic constants of oxidative polymerization of linseed oil was determined, for each catalytic system, via the periodic measurements of the oil viscosity during the oxidation reaction. The results indicated that the modifications of the classical two complexes with the chelating nitrogen ligands improved the catalytic efficiency at least to the manganese complex. (author)

  20. Bridging cobalt-calixarene subunits into a Co8 entity or a chain with 4,4‧-bipyridyl

    Science.gov (United States)

    Liu, Wei; Liu, Mei; Du, Shangchao; Li, Yafeng; Liao, Wuping

    2014-02-01

    Two novel calixarene-based compounds, {[Co4Cl(TC4A)(HCOO)3]2(4,4‧-bpy)2} (CIAC-206) and {[Co3(H2O)(SC4A-SO2)(HCOO)2]2(4,4‧-bpy)}n (CIAC-207) (H4TC4A = p-tert-butylthiacalix[4]arene, SC4A-SO2 = p-tert-butylsulfonylcalix[4]arene, 4,4‧-bpy = 4,4‧-bipyridyl) were synthesized under solvothermal conditions, and characterized by single crystal X-ray diffraction analysis, TG-DSC analysis, elemental analysis and IR spectroscopy. These two structures are featured with isolated Z-shaped Co8 entities containing two Co4-TC4A subunits bridged by two parallel 4,4‧-bpy (CIAC-206) and some zigzag chains with [Co3-SC4A-SO2]2 dimers bridged by single 4,4‧-bpy (CIAC-207), respectively. In order to evaluate their properties, the N2 sorption behavior and magnetic property were examined.

  1. Electrogenerated chemiluminescence: An oxidative-reductive mechanism between quinolone antibiotics and tris(2,2'-bipyridyl)ruthenium(II)

    Energy Technology Data Exchange (ETDEWEB)

    Burkhead, Matthew S.; Wang, Heeyoung; Fallet, Marcel [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States); Gross, Erin M. [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States)], E-mail: eringross@creighton.edu

    2008-04-21

    The cyclic voltammetry and electrogenerated chemiluminescent (ECL) reactions of a series of quinolone and fluoroquinolone antibiotics were investigated in a flow injection analysis (FIA) system. 7-Piperazinyl fluoroquinolone antibiotics were found to participate as a coreactant in an oxidative-reductive ECL mechanism with tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy){sub 3}{sup 2+}) as the luminescent reagent. The reaction mechanism was investigated in order to understand and optimize the processes leading to light emission. The optimal conditions included a solution pH {approx}7 at a flow rate of 3.0 mL min{sup -1} with no added organic modifier and application of 1.2 V vs. a Pt quasi-reference electrode (QRE). Fluoroquinolones containing a tertiary distal nitrogen on the piperazine ring, such as enrofloxacin and ofloxacin, reacted to produce more intense ECL than those with a secondary nitrogen, such as ciprofloxacin and norfloxacin. The method linear range, precision, detection limits, and sensitivity for the detection of enrofloxacin and ciprofloxacin were compared to that of tripropylamine. The method was applied to the determination of the ciprofloxacin content in a pharmaceutical preparation. The assay is discussed in terms of its analytical figures of merit, ease of use, speed, accuracy and application to pharmaceutical samples.

  2. Electrogenerated chemiluminescence: An oxidative-reductive mechanism between quinolone antibiotics and tris(2,2'-bipyridyl)ruthenium(II)

    International Nuclear Information System (INIS)

    Burkhead, Matthew S.; Wang, Heeyoung; Fallet, Marcel; Gross, Erin M.

    2008-01-01

    The cyclic voltammetry and electrogenerated chemiluminescent (ECL) reactions of a series of quinolone and fluoroquinolone antibiotics were investigated in a flow injection analysis (FIA) system. 7-Piperazinyl fluoroquinolone antibiotics were found to participate as a coreactant in an oxidative-reductive ECL mechanism with tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy) 3 2+ ) as the luminescent reagent. The reaction mechanism was investigated in order to understand and optimize the processes leading to light emission. The optimal conditions included a solution pH ∼7 at a flow rate of 3.0 mL min -1 with no added organic modifier and application of 1.2 V vs. a Pt quasi-reference electrode (QRE). Fluoroquinolones containing a tertiary distal nitrogen on the piperazine ring, such as enrofloxacin and ofloxacin, reacted to produce more intense ECL than those with a secondary nitrogen, such as ciprofloxacin and norfloxacin. The method linear range, precision, detection limits, and sensitivity for the detection of enrofloxacin and ciprofloxacin were compared to that of tripropylamine. The method was applied to the determination of the ciprofloxacin content in a pharmaceutical preparation. The assay is discussed in terms of its analytical figures of merit, ease of use, speed, accuracy and application to pharmaceutical samples

  3. Optical angular momentum and atoms.

    Science.gov (United States)

    Franke-Arnold, Sonja

    2017-02-28

    Any coherent interaction of light and atoms needs to conserve energy, linear momentum and angular momentum. What happens to an atom's angular momentum if it encounters light that carries orbital angular momentum (OAM)? This is a particularly intriguing question as the angular momentum of atoms is quantized, incorporating the intrinsic spin angular momentum of the individual electrons as well as the OAM associated with their spatial distribution. In addition, a mechanical angular momentum can arise from the rotation of the entire atom, which for very cold atoms is also quantized. Atoms therefore allow us to probe and access the quantum properties of light's OAM, aiding our fundamental understanding of light-matter interactions, and moreover, allowing us to construct OAM-based applications, including quantum memories, frequency converters for shaped light and OAM-based sensors.This article is part of the themed issue 'Optical orbital angular momentum'. © 2017 The Author(s).

  4. Optical angular momentum and atoms

    Science.gov (United States)

    2017-01-01

    Any coherent interaction of light and atoms needs to conserve energy, linear momentum and angular momentum. What happens to an atom’s angular momentum if it encounters light that carries orbital angular momentum (OAM)? This is a particularly intriguing question as the angular momentum of atoms is quantized, incorporating the intrinsic spin angular momentum of the individual electrons as well as the OAM associated with their spatial distribution. In addition, a mechanical angular momentum can arise from the rotation of the entire atom, which for very cold atoms is also quantized. Atoms therefore allow us to probe and access the quantum properties of light’s OAM, aiding our fundamental understanding of light–matter interactions, and moreover, allowing us to construct OAM-based applications, including quantum memories, frequency converters for shaped light and OAM-based sensors. This article is part of the themed issue ‘Optical orbital angular momentum’. PMID:28069766

  5. AngularJS directives

    CERN Document Server

    Vanston, Alex

    2013-01-01

    This book uses a practical, step-by-step approach, starting with how to build directives from the ground up before moving on to creating web applications comprised of multiple modules all working together to provide the best user experience possible.This book is intended for intermediate JavaScript developers who are looking to enhance their understanding of single-page web application development with a focus on AngularJS and the JavaScript MVC frameworks.It is expected that readers will understand basic JavaScript patterns and idioms and can recognize JSON formatted data.

  6. Angular Distribution of GRBs

    Directory of Open Access Journals (Sweden)

    L. G. Balázs

    2012-01-01

    Full Text Available We studied the complete randomness of the angular distribution of BATSE gamma-ray bursts (GRBs. Based on their durations and peak fluxes, we divided the BATSE sample into 5 subsamples (short1, short2, intermediate, long1, long2 and studied the angular distributions separately. We used three methods to search for non-randomness in the subsamples: Voronoi tesselation, minimal spanning tree, and multifractal spectra. To study any non-randomness in the subsamples we defined 13 test-variables (9 from Voronoi tesselation, 3 from the minimal spanning tree and one from the multifractal spectrum. We made Monte Carlo simulations taking into account the BATSE’s sky-exposure function. We tested therandomness by introducing squared Euclidean distances in the parameter space of the test-variables. We recognized that the short1, short2 groups deviate significantly (99.90%, 99.98% from the fully random case in the distribution of the squared Euclidean distances but this is not true for the long samples. In the intermediate group, the squared Euclidean distances also give significant deviation (98.51%.

  7. Perturbed angular correlation

    International Nuclear Information System (INIS)

    Fabris, J.D.

    1977-01-01

    The electric quadrupolar interaction in some hafnium complexes, measured at the metal nucleus level is studied. For that purpose, the technique of γ-γ perturbed angular correlation is used: the frequencies of quadrupolar interaction are compared with some hafnium α-hydroxicarboxilates, namely glycolate, lactate, mandelate and benzylate; the influence of the temperature on the quadrupolar coupling on the hafnium tetramandelate is studied; finally, the effects associated with the capture of thermal neutrons by hafnium tetramandelate are examined locally at the nuclear level. The first group of results shows significant differences in a series of complexes derived from glycolic acid. On the other hand, the substitution of the protons in hafnium tetramandelate structure by some alkaline cations permits to verify a correlation between the variations in the quadrupolar coupling and the electronegativities of the substituent elements. Measurements at high temperatures show that this complex is thermally stable at 100 and 150 0 C. It is possible to see the appearance of two distinct sites for the probe nucleus, after heating the sample at 100 0 C for prolonged time. This fact is attributed to a probable interconversion among the postulated structural isomers for the octacoordinated compounds. Finally, measurements of angular correlation on the irradiated complex show that there is an effective destruction of the target molecule by neutron capture [pt

  8. Galaxy angular momentum

    International Nuclear Information System (INIS)

    Thompson, L.A.

    1974-01-01

    In order to test the theories which purport to explain the origin of galaxy angular momentum, this study presents new data for about 1000 individual galaxies in eight rich clusters. The clusters which are studied include Virgo, A 119, A 400, A 1656 (Coma), A 2147, A 2151 (Hercules), A 2197, and A 2199. Selected samples of these data are used to investigate systematic alignment effects in clusters of galaxies and to investigate the intrinsic ellipticities of E, SO, and spiral galaxies. The following new results are reported: Galaxies in the cluster A 2197 show a significant alignment effect (chi 2 probability less than 0.0002), and the preferential direction of alignment corresponds approximately to the major axis of the overall cluster elongation. None of the other seven clusters show any significant alignment trends. The spiral galaxy samples in four clusters (Virgo, A 1656, A 2151, and A 2197) were large enough to analyze the number distributions of forward and reverse winding spirals. Large and small spiral galaxies have identical ellipticity distributions. Large E and SO galaxies tend to be more spherical, and small E and SO galaxies more flattened. The intrinsic ellipticities of E, SO, and spiral galaxies are the same for galaxies in the ''field'' and for galaxies in rich clusters. Six models of galaxy formation are reviewed, and the major []mphasis is placed on how each model explains the origin of galaxy angular momentum. (Diss. Abstr. Int., B)

  9. Angular mining conveyor

    Energy Technology Data Exchange (ETDEWEB)

    Sender, A; Mura, A; Liduchowski, L; Zok, P; Skolik, W; Szyngiel, S; Rojek, H; Gajda, B; Major, M; Stanislawski, P; Sliwiok, H; Sikora, J

    1988-10-19

    Angular mining conveyor provided with a drag chain extending along the axis of its path of movement, and a corner member, inside which the drag chain is led in a forced way, characterized in that the drag chain, where its path curves around the corner member, is located by supporting of the vertical links of the chain along the required curved section of the conveyor path around said corner member, and the supporting line of the links is so chosen, that, within the said curved section of the conveyor path, a space is maintained between the vertical end surface of the scrapers and the outer curved surface of the radially inner side wall of a corner trough associated with the corner member, through which corner trough the scrapers pass. 10 figs.

  10. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Lin Mengshan [Department of Chemistry, Tamkang University, Tamsui 25137, Taiwan (China)], E-mail: mslin@mail.tku.edu.tw; Wang Junsheng; Lai Chienhung [Department of Chemistry, Tamkang University, Tamsui 25137, Taiwan (China)

    2008-11-01

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy){sub 3}{sup 2+}/nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy){sub 3}{sup 2+}/nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy){sub 3}{sup 2+}/nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L{sup -1} (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 {mu}mol L{sup -1}) with R-value of 0.997. The relative standard deviation with 5 {mu}mol L{sup -1} concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications.

  11. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Meng Shan; Wang, Jun Sheng; Lai, Chien Hung [Department of Chemistry, Tamkang University, Tamsui 25137 (China)

    2008-11-01

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy){sub 3}{sup 2+}/nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy){sub 3}{sup 2+}/nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy){sub 3}{sup 2+}/nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L{sup -1} (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 {mu}mol L{sup -1}) with R-value of 0.997. The relative standard deviation with 5 {mu}mol L{sup -1} concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications. (author)

  12. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    International Nuclear Information System (INIS)

    Lin Mengshan; Wang Junsheng; Lai Chienhung

    2008-01-01

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy) 3 2+ /nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy) 3 2+ /nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy) 3 2+ /nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L -1 (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 μmol L -1 ) with R-value of 0.997. The relative standard deviation with 5 μmol L -1 concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications

  13. Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Wenshan; Lukens, Wayne W.; Zi, Guofu; Maron, Laurent; Walter, Marc D.

    2012-01-12

    Bipyridyl thorium metallocenes [5-1,2,4-(Me3C)3C5H2]2Th(bipy) (1) and [5-1,3-(Me3C)2C5H3]2Th(bipy) (2) have been investigated by magnetic susceptibility and computational studies. The magnetic susceptibility data reveal that 1 and 2 are not diamagnetic, but they behave as temperature independent paramagnets (TIPs). To rationalize this observation, density functional theory (DFT) and complete active space SCF (CASSCF) calculations have been undertaken, which indicated that Cp2Th(bipy) has indeed a Th(IV)(bipy2-) ground state (f0d0 2, S = 0), but the open-shell singlet (f0d1 1, S = 0) (almost degenerate with its triplet congener) is lying only 9.2 kcal/mol higher in energy. Complexes 1 and 2 react cleanly with Ph2CS to give [ 5-1,2,4-(Me3C)3C5H2]2Th[(bipy)(SCPh2)] (3) and [ 5-1,3-(Me3C)2C5H3]2Th[(bipy)(SCPh2)] (4), respectively, in quantitative conversions. Since no intermediates were observed experimentally, this reaction was also studied computationally. Coordination of Ph2CS to 2 in its S = 0 ground state is not possible, but Ph2CS can coordinate to 2 in its triplet state (S = 1) upon which a single electron transfer (SET) from the (bipy2-) fragment to Ph2CS followed by C-C coupling takes place.

  14. Angular integrals in d dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Somogyi, Gabor

    2011-01-15

    We discuss the evaluation of certain d dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications. (orig.)

  15. Angular momentum in general relativity

    International Nuclear Information System (INIS)

    Cresswell, A.; Zimmerman, R.L.; Oregon Univ., Eugene

    1986-01-01

    It is argued that the correct expressions for the angular momentum flux carried by gravitational radiation should follow directly from the momentum currents. Following this approach, the authors compute the angular momentum associated with several different choices of energy-momentum prescriptions. (author)

  16. Angular integrals in d dimensions.

    OpenAIRE

    Somogyi, G.

    2011-01-01

    We discuss the evaluation of certain d dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications.

  17. Angular integrals in d dimensions

    International Nuclear Information System (INIS)

    Somogyi, Gabor

    2011-01-01

    We discuss the evaluation of certain d-dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications.

  18. Angular integrals in d dimensions

    Science.gov (United States)

    Somogyi, Gábor

    2011-08-01

    We discuss the evaluation of certain d-dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications.

  19. Angular integrals in d dimensions

    International Nuclear Information System (INIS)

    Somogyi, Gabor

    2011-01-01

    We discuss the evaluation of certain d dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications. (orig.)

  20. Angular Momentum in Dwarf Galaxies

    Directory of Open Access Journals (Sweden)

    Del Popolo A.

    2014-06-01

    Full Text Available We study the “angular momentum catastrophe” in the framework of interaction among baryons and dark matter through dynamical friction. By means of Del Popolo (2009 model we simulate 14 galaxies similar to those investigated by van den Bosch, Burkert and Swaters (2001, and calculate the distribution of their spin parameters and the angular momenta. Our model gives the angular momentum distribution which is in agreement with the van den Bosch et al. observations. Our result shows that the “angular momentum catastrophe” can be naturally solved in a model that takes into account the baryonic physics and the exchange of energy and angular momentum between the baryonic clumps and dark matter through dynamical friction.

  1. Angular momentum of dwarf galaxies

    Science.gov (United States)

    Kurapati, Sushma; Chengalur, Jayaram N.; Pustilnik, Simon; Kamphuis, Peter

    2018-05-01

    Mass and specific angular momentum are two fundamental physical parameters of galaxies. We present measurements of the baryonic mass and specific angular momentum of 11 void dwarf galaxies derived from neutral hydrogen (HI) synthesis data. Rotation curves were measured using 3D and 2D tilted ring fitting routines, and the derived curves generally overlap within the error bars, except in the central regions where, as expected, the 3D routines give steeper curves. The specific angular momentum of void dwarfs is found to be high compared to an extrapolation of the trends seen for higher mass bulge-less spirals, but comparable to that of other dwarf irregular galaxies that lie outside of voids. As such, our data show no evidence for a dependence of the specific angular momentum on the large scale environment. Combining our data with the data from the literature, we find a baryonic threshold of ˜109.1 M⊙ for this increase in specific angular momentum. Interestingly, this threshold is very similar to the mass threshold below which the galaxy discs start to become systematically thicker. This provides qualitative support to the suggestion that the thickening of the discs, as well as the increase in specific angular momentum, are both results of a common physical mechanism, such as feedback from star formation. Quantitatively, however, the amount of star formation observed in our dwarfs appears insufficient to produce the observed increase in specific angular momentum. It is hence likely that other processes, such as cold accretion of high angular momentum gas, also play a role in increasing the specific angular momentum.

  2. AngularJS testing cookbook

    CERN Document Server

    Bailey, Simon

    2015-01-01

    This book is intended for developers who have an understanding of the basic principles behind both AngularJS and test-driven development. You, as a developer, are interested in eliminating the fear related to either introducing tests to an existing codebase or starting out testing on a fresh AngularJS application. If you're a team leader or part of a QA team with the responsibility of ensuring full test coverage of an application, then this book is ideal for you to comprehend the full testing scope required by your developers. Whether you're new to or are well versed with AngularJS, this book

  3. Angular momentum from tidal torques

    International Nuclear Information System (INIS)

    Barnes, J.; Efstathiou, G.; Cambridge Univ., England)

    1987-01-01

    The origin of the angular momentum of bound objects in large N-body simulations is studied using three sets of models. One model with white-noise initial conditions is analyzed as well as two in which the initial conditions have more power on large scales, as predicted in models with cold dark matter. The growth and distribution of angular momentum in individual objects is studied and it is found that the specific angular momentum distribution of bound clumps increases in a near linear fashion with radius while the orientation of the angular momentum in the inner high-density regions is often poorly correlated with that of the outer parts. It is also found that the dimensionless spin parameter is insensitive to the initial perturbation spectrum and has a median value of about 0.05. 61 references

  4. Lidar Orbital Angular Momentum Sensor

    Data.gov (United States)

    National Aeronautics and Space Administration — The recognition in recent decades that electromagnetic fields have angular momentum (AM) in the form of not only polarization (or spin AM) but also orbital (OAM) has...

  5. Synthesis and structure of bivalent ytterbocenes and their coordination chemistry with pi-acceptor ligands

    Energy Technology Data Exchange (ETDEWEB)

    Schultz, Madeleine [Univ. of California, Berkeley, CA (United States)

    2000-05-01

    The bivalent lanthanide metallocenes [1,3-(Me3C)2C5H3]2Yb and (Me4C5H)2Yb have been synthesized and their structures have been determined by X-ray crystallography. Comparison with the known structures of (Me5C5)2Yb and [1,3 -(Me3Si)2C5H3]2Yb leads to an understanding of the role of intermolecular contacts in stabilizing these coordinatively unsaturated molecules. The optical spectra of the base-free ytterbocenes and their Lewis-base adducts have been measured; the position of the HOMO - LUMO transition can be correlated with the degree of bending of the complexes in solution according to a molecular orbital model. Electron - electron repulsion, resulting from additional σ-donor ligands, also affects the HOMO - LUMO transition by increasing the energy of the filled f-orbitals. The base-free metallocene (Me5C5)2Yb coordinates carbon monoxide, resulting in a decrease in Vco relative to that of fi-ee carbon monoxide. This behavior is reminiscent of d-transition metallocene chemistry. Other base-free ytterbocenes also coordinate carbon monoxide and the degree of back-donation is related to the substituents on the cyclopentadienide rings. Isocyanides are coordinated in a 1:2 ratio by the ytterbocenes, giving complexes having vcN higher than those of the free isocyanides. An electrostatic bonding model has been used to explain the changes in CN stretching frequencies. The optical spectra of the carbonyl and isocyanide complexes are consistent with the molecular orbital model of the variation in the HOMO - LUMO gap upon bending, and the increase in electron - electron repulsion due to the additional ligands. The complex (Me5C5)2Yb(bipy) exhibits optical, infrared and NMIZ spectroscopy and an X-ray crystal

  6. Reduction of dinitrogen ligands

    International Nuclear Information System (INIS)

    Richards, R.L.

    1983-01-01

    Processes of dinitrogen ligand reduction in complexes of transition metals are considered. The basic character of the dinitrogen ligand is underlined. Data on X-ray photoelectronic spectroscopy and intensities of bands ν (N 2 ) in IR-spectra of nitrogen complexes are given. The mechanism of protonation of an edge dinitrogen ligand is discussed. Model systems and mechanism of nitrogenogenase are compared

  7. Antioxidant activities of nano-bubble hydrogen-dissolved water assessed by ESR and 2,2′-bipyridyl methods

    International Nuclear Information System (INIS)

    Kato, Shinya; Matsuoka, Daigo; Miwa, Nobuhiko

    2015-01-01

    We prepared nano-bubble hydrogen-dissolved water (nano-H water) which contained hydrogen nano-bubbles of < 717-nm diameter for 54% of total bubbles. In the DMPO-spin trap electron spin resonance (ESR) method, the DMPO-OH:MnO ratio, being attributed to amounts of hydroxyl radicals (·OH), was 2.78 for pure water (dissolved hydrogen [DH] ≤ 0.01 ppm, oxidation-reduction potential [ORP] = + 324 mV), 2.73 for tap water (0.01 ppm, + 286 mV), 2.93 for commercially available hydrogen water (0.075 ppm, + 49 mV), and 2.66 for manufactured hydrogen water (0.788 ppm, − 614 mV), whereas the nano-H water (0.678 ppm, − 644 mV) exhibited 2.05, showing the superiority of nano-H water to other types of hydrogen water in terms of ·OH-scavenging activity. Then, the reduction activity of nano-H water was assessed spectrophotometrically by the 2,2′-bipyridyl method. Differential absorbance at 530 nm was in the order: 0.018 for pure water, 0.055 for tap water, 0.079 for nano-H water, 0.085 for commercially available hydrogen water, and 0.090 for manufactured hydrogen water, indicating a prominent reduction activity of hydrogen water and nano-H water against oxidation in ascorbate-coupled ferric ion–bipyridyl reaction. Thus, nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level, indicating the more marked importance of nano-bubbles rather than the concentration of hydrogen in terms of ·OH-scavenging. - Highlights: • We assessed the antioxidant activity of nano-bubble hydrogen-dissolved water (nano-H water). • Nano-H water exhibited superior ·OH-scavenging activity in DMPO-spin trap ESR. • A reduction ability of nano-H water was shown in 2,2′-bipyridyl reaction. • Nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level. • Results indicated the importance of nano-bubbles rather than the concentration of hydrogen

  8. Uncertainty principle for angular position and angular momentum

    International Nuclear Information System (INIS)

    Franke-Arnold, Sonja; Barnett, Stephen M; Yao, Eric; Leach, Jonathan; Courtial, Johannes; Padgett, Miles

    2004-01-01

    The uncertainty principle places fundamental limits on the accuracy with which we are able to measure the values of different physical quantities (Heisenberg 1949 The Physical Principles of the Quantum Theory (New York: Dover); Robertson 1929 Phys. Rev. 34 127). This has profound effects not only on the microscopic but also on the macroscopic level of physical systems. The most familiar form of the uncertainty principle relates the uncertainties in position and linear momentum. Other manifestations include those relating uncertainty in energy to uncertainty in time duration, phase of an electromagnetic field to photon number and angular position to angular momentum (Vaccaro and Pegg 1990 J. Mod. Opt. 37 17; Barnett and Pegg 1990 Phys. Rev. A 41 3427). In this paper, we report the first observation of the last of these uncertainty relations and derive the associated states that satisfy the equality in the uncertainty relation. We confirm the form of these states by detailed measurement of the angular momentum of a light beam after passage through an appropriate angular aperture. The angular uncertainty principle applies to all physical systems and is particularly important for systems with cylindrical symmetry

  9. Ligands in PSI structures

    International Nuclear Information System (INIS)

    Kumar, Abhinav; Chiu, Hsiu-Ju; Axelrod, Herbert L.; Morse, Andrew; Elsliger, Marc-André; Wilson, Ian A.; Deacon, Ashley

    2010-01-01

    A survey of the types and frequency of ligands that are bound to PSI structures is analyzed as well as their utility in functional annotation of previously uncharacterized proteins. Approximately 65% of PSI structures report some type of ligand(s) that is bound in the crystal structure. Here, a description is given of how such ligands are handled and analyzed at the JCSG and a survey of the types, variety and frequency of ligands that are observed in the PSI structures is also compiled and analyzed, including illustrations of how these bound ligands have provided functional clues for annotation of proteins with little or no previous experimental characterization. Furthermore, a web server was developed as a tool to mine and analyze the PSI structures for bound ligands and other identifying features

  10. Thin-layer chromatography of ternary complexes of group-IIIA metals with 2-thenoyltrifluoroacetone and 2,2'-bipyridyl on cellulose layer

    Energy Technology Data Exchange (ETDEWEB)

    Chao, H E; Saitoh, K; Suzuki, N [Tohoku Univ., Sendai (Japan). Faculty of Science

    1980-11-11

    Normal phase thin-layer chromatographic behaviour of several ternary complexes of group-IIIA metals with 2-thenoyltrifluoroacetone (TTA) and 2,2'bipyridyl (bpy) has been investigated on cellulose layer. The ternary complexes of lanthanide metals show higher mutual separability than the complexes with TTA alone. Mutual separation of TTA complexes with La(III), Ce(III), Eu(III) or Y(III), Sc(III), Th(IV), and U(VI) has been successfully achieved by two-dimensional TLC, primarily with carbon tetrachloride-benzene (75:25) containing 0.02M TTA, and secondary with carbon tetrachloride-hexane (35:65) containing both 0.02M TTA and 0.02M bpy.

  11. Instant AngularJS starter

    CERN Document Server

    Menard, Dan

    2013-01-01

    Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. This book is written in an easytoread style, with a strong emphasis on realworld, practical examples. Stepbystep explanations are provided for performing important tasks.This book is for web developers familiar with JavascriptIt doesn't cover the history of AngularJS, and it's not a pitch to convince you that AngularJS is the best framework on the entire web. It's a guide to help you learn everything you need to know about AngularJS in as few pa

  12. Automated Angular Momentum Recoupling Algebra

    Science.gov (United States)

    Williams, H. T.; Silbar, Richard R.

    1992-04-01

    We present a set of heuristic rules for algebraic solution of angular momentum recoupling problems. The general problem reduces to that of finding an optimal path from one binary tree (representing the angular momentum coupling scheme for the reduced matrix element) to another (representing the sub-integrals and spin sums to be done). The method lends itself to implementation on a microcomputer, and we have developed such an implementation using a dialect of LISP. We describe both how our code, called RACAH, works and how it appears to the user. We illustrate the use of RACAH for several transition and scattering amplitude matrix elements occurring in atomic, nuclear, and particle physics.

  13. High angular resolution at LBT

    Science.gov (United States)

    Conrad, A.; Arcidiacono, C.; Bertero, M.; Boccacci, P.; Davies, A. G.; Defrere, D.; de Kleer, K.; De Pater, I.; Hinz, P.; Hofmann, K. H.; La Camera, A.; Leisenring, J.; Kürster, M.; Rathbun, J. A.; Schertl, D.; Skemer, A.; Skrutskie, M.; Spencer, J. R.; Veillet, C.; Weigelt, G.; Woodward, C. E.

    2015-12-01

    High angular resolution from ground-based observatories stands as a key technology for advancing planetary science. In the window between the angular resolution achievable with 8-10 meter class telescopes, and the 23-to-40 meter giants of the future, LBT provides a glimpse of what the next generation of instruments providing higher angular resolution will provide. We present first ever resolved images of an Io eruption site taken from the ground, images of Io's Loki Patera taken with Fizeau imaging at the 22.8 meter LBT [Conrad, et al., AJ, 2015]. We will also present preliminary analysis of two data sets acquired during the 2015 opposition: L-band fringes at Kurdalagon and an occultation of Loki and Pele by Europa (see figure). The light curves from this occultation will yield an order of magnitude improvement in spatial resolution along the path of ingress and egress. We will conclude by providing an overview of the overall benefit of recent and future advances in angular resolution for planetary science.

  14. Angular momentum projection with Pfaffian

    International Nuclear Information System (INIS)

    Oi, M.

    2011-01-01

    Recent developments to rewrite the Onishi formula for an evaluation of the so-called norm overlap kernel necessary in angular momentum projection are to be discussed. The essential ingredients in the development, that is, the Fermion coherent states, the Grassmann numbers, and the Pfaffian, are explained. (author)

  15. Angular overlap model in actinides

    International Nuclear Information System (INIS)

    Gajek, Z.; Mulak, J.

    1991-01-01

    Quantitative foundations of the Angular Overlap Model in actinides based on ab initio calculations of the crystal field effect in the uranium (III) (IV) and (V) ions in various crystals are presented. The calculations justify some common simplifications of the model and fix up the relations between the AOM parameters. Traps and limitations of the AOM phenomenology are discussed

  16. Angular overlap model in actinides

    Energy Technology Data Exchange (ETDEWEB)

    Gajek, Z.; Mulak, J. (Polska Akademia Nauk, Wroclaw (PL). Inst. Niskich Temperatur i Badan Strukturalnych)

    1991-01-01

    Quantitative foundations of the Angular Overlap Model in actinides based on ab initio calculations of the crystal field effect in the uranium (III) (IV) and (V) ions in various crystals are presented. The calculations justify some common simplifications of the model and fix up the relations between the AOM parameters. Traps and limitations of the AOM phenomenology are discussed.

  17. Angular momentum in general relativity

    International Nuclear Information System (INIS)

    Prior, C.R.

    1977-01-01

    The definition of angular momentum proposed in part I of this series (Prior. Proc. R. Soc. Lond.; A354:379 (1977)) is investigated when applied to rotating black holes. It is shown how to use the formula to evaluate the angular momentum of a stationary black hole. This acts as a description of a background space on which the effect of first matter and then gravitational perturbations is considered. The latter are of most interest and the rate of change of angular momentum, dJ/dt, is found as an expression in the shear induced in the event horizon by the perturbation and in its time integral. Teukolsky's solutions (Astrophys. J.; 185:635 (1973)) for the perturbed component of the Weyl tensor are then used to find this shear and hence to give an exact answer for dJ/dt. One of the implications of the result is a direct verification of Bekenstein's formula (Phys. Rev.; 7D:949 (1973)) relating in a simple way the rate of change of angular momentum to the rate of change of mass caused by a plane wave. A more general expression is also given for dM/dt. Considering only stationary perturbations, it is shown how to generalize the definition of angular momentum so as to include information about its direction as well. Three problems are particularly discussed - a single moon, two or more moons and a ring of matter causing the perturbation - since they provide illustrations of all the main features of the black hole's behaviour. In every case it is found that the black hole realigns its axis of rotation so that the final configuration is axisymmetric if possible; otherwise is slows down completely to reach a static state. (author)

  18. Ag-ligand modified tungstovandates and their efficient catalysis degradation properties for methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Ran; Zhang, Huixia; Liu, Yunping; Wang, Xiaoxiao; Han, Zhangang, E-mail: hanzg116@126.com

    2017-02-15

    Two polytungstovandates [Ag(mbpy){sub 2}][Ag{sub 2}(mbpy){sub 3}][VW{sub 5}O{sub 19}]·H{sub 2}O (1) and [Ag(mbpy)]{sub 2}[Ag(mbpy){sub 2}]{sub 4}[VW{sub 12}O{sub 40}] (2) (mbpy =4,4′-dimethyl-2,2′-bipyridyl), had been hydrothermally synthesized and characterized by IR, TG, and single-crystal X-ray diffraction techniques. Single-crystal structural analysis revealed that the polyanionic clusters in two compounds are different: Lindqvist-type in 1 and α-Keggin-type in 2, respectively, while the cationic moieties in them are Ag-mbpy units. The experiments showed that this kind of hybrid crystal materials possesses more efficiently catalytic performance for the degradation of organic dye methylene blue (MB) in water solution under the UV irradiation. The significant degradation rate of MB can reach 89.9%, 94.9% by crystals 1 and 2 (40 mg) in the course of about 5 min. - Graphical abstract: Two Ag-ligand modified polytungstovandates had been synthesized and characterized, which were active in the catalytic degradation of organic dye methylene blue under the UV irradiation. - Highlights: • Two Ag-ligand modified tungstovandates were synthesized and characterized. • Weak interactions play important roles in constructing crystal frameworks. • Compounds are active to catalyze the degradation of methylene blue.

  19. Highly efficient quenching of tris(2,2'-bipyridyl)ruthenium(II) electrochemiluminescence by ozone using formaldehyde, methylglyoxal, and glyoxalate as co-reactants and its application to ozone sensing.

    Science.gov (United States)

    Gao, Ying; Liu, Xiaoyun; Qi, Wenjing; Gao, Wenyue; Li, Yunhui; Xu, Guobao

    2015-06-21

    Most electrochemiluminescence (ECL) systems require high concentrations of quencher to totally quench ECL. In this study, we found that ozone can quench tris(2,2'-bipyridyl)ruthenium(II) ECL using formaldehyde, methylglyoxal, or glyoxalate as co-reactants at a glassy carbon electrode with remarkable efficiencies even when the concentration of ozone is merely 0.25% of that of the co-reactant. The strongest quenching is observed with the tris(2,2'-bipyridyl)ruthenium(II)/formaldehyde ECL system. The tris(2,2'-bipyridyl)ruthenium(II)/formaldehyde ECL intensities decrease linearly with the ozone concentration over the range of 0.025-25 μM (r = 0.9947) with a limit of detection of 8 nM. The method is more sensitive and faster than most methods. It shows high selectivity in the presence of other ROS or oxidants and some metal ions, such as H2O2, ClO(-), Mg(2+), Ni(2+), etc. The method exhibits high recoveries for the detection of ozone in a ventilated photocopy room.

  20. Schiff base ligand

    Indian Academy of Sciences (India)

    Unknown

    Low-temperature stoichiometric Schiff base reaction in air in 3 : 1 mole ratio between benz- aldehyde and triethylenetetramine (trien) in methanol yields a novel tetraaza µ-bis(bidentate) acyclic ligand L. It was .... electrochemical work was performed as reported in ..... change in ligand shape through change in oxidation.

  1. On Dunkl angular momenta algebra

    Energy Technology Data Exchange (ETDEWEB)

    Feigin, Misha [School of Mathematics and Statistics, University of Glasgow,15 University Gardens, Glasgow G12 8QW (United Kingdom); Hakobyan, Tigran [Yerevan State University,1 Alex Manoogian, 0025 Yerevan (Armenia); Tomsk Polytechnic University,Lenin Ave. 30, 634050 Tomsk (Russian Federation)

    2015-11-17

    We consider the quantum angular momentum generators, deformed by means of the Dunkl operators. Together with the reflection operators they generate a subalgebra in the rational Cherednik algebra associated with a finite real reflection group. We find all the defining relations of the algebra, which appear to be quadratic, and we show that the algebra is of Poincaré-Birkhoff-Witt (PBW) type. We show that this algebra contains the angular part of the Calogero-Moser Hamiltonian and that together with constants it generates the centre of the algebra. We also consider the gl(N) version of the subalgebra of the rational Cherednik algebra and show that it is a non-homogeneous quadratic algebra of PBW type as well. In this case the central generator can be identified with the usual Calogero-Moser Hamiltonian associated with the Coxeter group in the harmonic confinement.

  2. Angular momentum in QGP holography

    Directory of Open Access Journals (Sweden)

    Brett McInnes

    2014-10-01

    Full Text Available The quark chemical potential is one of the fundamental parameters describing the quark–gluon plasma produced by sufficiently energetic heavy-ion collisions. It is not large at the extremely high temperatures probed by the LHC, but it plays a key role in discussions of the beam energy scan programmes at the RHIC and other facilities. On the other hand, collisions at such energies typically (that is, in peripheral collisions give rise to very high values of the angular momentum density. Here we explain that holographic estimates of the quark chemical potential of a rotating sample of plasma can be very considerably improved by taking the angular momentum into account.

  3. Angular momentum content of galaxies

    International Nuclear Information System (INIS)

    Shaya, E.J.; Tully, R.B.

    1984-01-01

    A schema of galaxy formation is developed in which the environmental influence of large-scale structure plays a dominant role. This schema was motivated by the observation that the fraction of E and S0 galaxies is much higher in clusters than in low-density regions and by an inference that those spirals that are found in clusters probably have fallen in relatively recently from the low-density regions. It is proposed that the tidal field of the Local Supercluster acts to determine the morphology of galaxies through two complementary mechanisms. In the first place, the supercluster can apply torques to protogalaxies. Galaxies which collapsed while expanding away from the central cluster decoupled from the external tidal field and conserved the angular momentum that they acquired before collapse. Galaxies which formed in the cluster while the cluster collapsed continued to feel the tidal field. In the latter case, the spin of outer collapsing layers can be halted and reversed, and tends to cancel the spin of inner layers. The result is a reduction of the total angular momentum content of the galaxy. In addition, the supercluster tidal field can regulate accretion of fresh material onto the galaxies since the field creates a Roche limit about galaxies and material beyond this limit is lost. Any material that has not collapsed onto a galaxy by the time the galaxy falls into a cluster will be tidally stripped. The angular momentum content of that part of the protogalactic cloud which has not yet collapsed . continues to grow linearly with time due to the continued torquing by the supercluster and neighbors. Galaxies at large distances from the cluster core can continue to accrete this high angular momentum material until the present, but galaxies that enter the cluster are cut off from replenishing material

  4. Angular dependence of shallow dose

    International Nuclear Information System (INIS)

    Alvarez, J.L.

    1986-01-01

    The theoretical response of a detector is discussed and compared to measurements of shallow dose with tissue and phantom response detectors. A definite energy dependent angular response of dose and measurement was observed which could not be explained by simple trigonometric arguments. The response is back scatter dependent and must be considered in detector design and dose measurements. It is not possible for standard detectors to follow this response

  5. AngularJS test-driven development

    CERN Document Server

    Chaplin, Tim

    2015-01-01

    This book is for developers who want to learn about AngularJS development by applying testing techniques. You are assumed to have a basic knowledge and understanding of HTML, JavaScript, and AngularJS.

  6. Angular-momentum transport in nuclear collisions

    International Nuclear Information System (INIS)

    Wolschin, G.; Ayik, S.; Noerenberg, W.

    1978-01-01

    Among the various relaxation processes that can be observed in heavy-ion collisions, the dissipation of relative angular momentum into intrinsic angular momentum of the fragments attracts increasing attention. Here we present a transport theoretical description of angular-momentum and mass transport that allows for a transparent interpretation of the data. (orig.) [de

  7. AngularJS web application development

    CERN Document Server

    Darwin, Peter Bacon

    2013-01-01

    The book will be a step-by-step guide showing the readers how to build a complete web app with AngularJSJavaScript developers who want to learn AngularJS for developing web apps. Knowledge of JavaScript and HTML is expected. No knowledge of AngularJS is required.

  8. Ligand modeling and design

    Energy Technology Data Exchange (ETDEWEB)

    Hay, B.P. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-10-01

    The purpose of this work is to develop and implement a molecular design basis for selecting organic ligands that would be used in the cost-effective removal of specific radionuclides from nuclear waste streams. Organic ligands with metal ion specificity are critical components in the development of solvent extraction and ion exchange processes that are highly selective for targeted radionuclides. The traditional approach to the development of such ligands involves lengthy programs of organic synthesis and testing, which in the absence of reliable methods for screening compounds before synthesis, results in wasted research effort. The author`s approach breaks down and simplifies this costly process with the aid of computer-based molecular modeling techniques. Commercial software for organic molecular modeling is being configured to examine the interactions between organic ligands and metal ions, yielding an inexpensive, commercially or readily available computational tool that can be used to predict the structures and energies of ligand-metal complexes. Users will be able to correlate the large body of existing experimental data on structure, solution binding affinity, and metal ion selectivity to develop structural design criteria. These criteria will provide a basis for selecting ligands that can be implemented in separations technologies through collaboration with other DOE national laboratories and private industry. The initial focus will be to select ether-based ligands that can be applied to the recovery and concentration of the alkali and alkaline earth metal ions including cesium, strontium, and radium.

  9. DNA binding and biological activity of mixed ligand complexes of Cu(II, Ni(II and Co(II with quinolones and N donor ligand

    Directory of Open Access Journals (Sweden)

    S.M M Akram

    2015-10-01

    Full Text Available  AbstractMixed ligand complexes of  Cu(II, Ni(II and Co(II have been synthesized by using levofloxacin and bipyridyl and characterized using spectral and analytical techniques. The binding behavior of the Ni(II and Cu(II complexes with herring sperm DNA(Hs-DNA were determined using electronic absorption titration, viscometric measurements and cyclic voltammetry measurements. The binding constant calculated  for Cu(II and Ni(II complexes are 2.0 x 104 and 4.0 x 104 M-1 respectively. Detailed analysis reveals that these metal complexes interact with DNA through intercalative binding mode. The nuclease activity of  Cu(II and Ni(II complexes with ct-DNA was carried out using agarose gel electrophoresis technique. The antioxidant activities for the synthesized complexes have been tested and the antibacterial activity for Ni(II complex was also checked.Key words: Intercalation, hypochromism, red shift and  peak potential.

  10. Electron angular distribution axial channeling

    International Nuclear Information System (INIS)

    Khokonov, A.Kh.; Khokonov, M.Kh.

    1989-01-01

    Angular distributions of ultra-relativistic electrons are calculated in the assumption about presence of statistical equilibrium. Analysis is based on numerical solution of Fokker-Planck type kinetic equation. It is shown that in contrast to case of amorphous medium, the multiple scattering at axial channeling of negative particles results in self-focusing of the initial beam particles and due to it number of electrons moving at an angles to the chain, which are smaller, than critical angle of channeling, may increase by several times as compared to the initial one

  11. Influence of different ruthenium(II) bipyridyl complex on the photocatalytic H{sub 2} evolution over TiO{sub 2} nanoparticles with mesostructures

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Tianyou [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China); Hubei Key Laboratory for Catalysis and Material Science, College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074 (China); Ke, Dingning; Cai, Ping; Dai, Ke; Ma, Liang; Zan, Ling [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China)

    2008-05-15

    H{sub 2} production over dye-sensitized Pt/TiO{sub 2} nanoparticles with mesostructures (m-TiO{sub 2}) under visible light ({lambda} > 420 nm) was investigated by using methanol as electron donors. Experimental results indicate that three types of ruthenium(II) bipyridyl complex dyes (one binuclear Ru, two mononuclear Ru), which can be attached to Pt/m-TiO{sub 2} with different linkage modes, show different photosensitization effects due to their different coordination circumstances and physicochemical properties. The dye tightly linked with m-TiO{sub 2} has better durability but the lowest H{sub 2} evolution efficiency, whereas the loosely attached dyes possess higher H{sub 2} evolution efficiency and preferable durability. It seems that the dynamic equilibrium between the linkage of the ground state dye with TiO{sub 2} and the divorce of the oxidization state dye from the surfaces plays a crucial role in the photochemical behavior during the photocatalyst sensitization process. It is helpful to improve the H{sub 2} evolution efficiency by enhancing the electron injection and hindering the backward transfer. The binuclear Ru(II) dye shows a better photosensitization in comparison with mononuclear Ru(II) dyes due to its large molecular area, conjugation system, and ''antenna effect'', which, in turn, improve the visible light harvesting and electron transfer between the dye molecules and TiO{sub 2}. (author)

  12. Palladium(II/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water

    Directory of Open Access Journals (Sweden)

    Fu-Yu Tsai

    2010-01-01

    Full Text Available A water-soluble and air-stable Pd(NH32Cl2/cationic 2,2’-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu3N as a base. The reaction was conducted at 140 °C in a sealed tube in air with a catalyst loading as low as 0.0001 mol % for the coupling of activated aryl iodides with butyl and ethyl acrylates, providing the corresponding products in good to excellent yields with very high turnover numbers. In the case of styrene, Mizoroki-Heck coupling products were obtained in good to high yields by using a greater catalyst loading (1 mol % and TBAB as a phase-transfer agent. After extraction, the residual aqueous solution could be reused several times with only a slight decrease in its activity, making the Mizoroki-Heck reaction “greener”.

  13. Sol-gel-immobilized Tris(2,2'-bipyridyl)ruthenium(II) electrogenerated chemiluminescence sensor for high-performance liquid chromatography

    International Nuclear Information System (INIS)

    Choi, Han Nim; Cho, Sung-Hee; Park, Yu-Jin; Lee, Dai Woon; Lee, Won-Yong

    2005-01-01

    The sol-gel-immobilized Tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy) 3 2+ ] electrogenerated chemiluminescence (ECL) sensor was applied to the reversed-phase high-performance liquid chromatography (HPLC) determination of phenothiazine derivatives (promazine, chlorpromazine, triflupromazine, thioridazine, and trifluoperazine) and erythromycin in human urine samples. In this method, Ru(bpy) 3 2+ was immobilized in sol-gel-derived titania (TiO 2 )-Nafion nanocomposite films coated on a dual platinum electrode. This method eliminates an extra pump needed for the delivery of Ru(bpy) 3 2+ reagent into a reaction/observation zone in front of photomultiplier tube because the immobilized-Ru(bpy) 3 2+ is recycled on the electrode surface by an applied potential at +1.3 V versus Ag/AgCl (3 M NaCl) reference electrode. The resulting analytical performances such as detection limit, working range, sensitivity, and measurement precision were slightly worse than those obtained with the conventional post-column Ru(bpy) 3 2+ addition approach. The lack of significant interferences and the low detection limits for phenothiazine derivatives and erythromycin indicate that the proposed HPLC-Ru(bpy) 3 2+ ECL detection method is suitable for the determination of those compounds in biological fluids

  14. Angular Positioning Sensor for Space Mechanisms

    Science.gov (United States)

    Steiner, Nicolas; Chapuis, Dominique

    2013-09-01

    Angular position sensors are used on various rotating mechanisms such as solar array drive mechanisms, antenna pointing mechanisms, scientific instruments, motors or actuators.Now a days, potentiometers and encoders are mainly used for angular measurement purposes. Both of them have their own pros and cons.As alternative, Ruag Space Switzerland Nyon (RSSN) is developing and qualifying two innovative technologies of angular position sensors which offer easy implementation, medium to very high lifetime and high flexibility with regards to the output signal shape/type.The Brushed angular position sensor uses space qualified processes which are already flying on RSSN's sliprings for many years. A large variety of output signal shape can be implemented to fulfill customer requirements (digital, analog, customized, etc.).The contactless angular position sensor consists in a new radiation hard Application Specific Integrated Circuit (ASIC) based on the Hall effect and providing the angular position without complex processing algorithm.

  15. Oral candidiasis and angular cheilitis.

    Science.gov (United States)

    Sharon, Victoria; Fazel, Nasim

    2010-01-01

    Candidiasis, an often encountered oral disease, has been increasing in frequency. Most commonly caused by the overgrowth of Candida albicans, oral candidiasis can be divided into several categories including acute and chronic forms, and angular cheilitis. Risk factors for the development of oral candidiasis include immunosuppression, wearing of dentures, pharmacotherapeutics, smoking, infancy and old age, endocrine dysfunction, and decreased salivation. Oral candidiasis may be asymptomatic. More frequently, however, it is physically uncomfortable, and the patient may complain of burning mouth, dysgeusia, dysphagia, anorexia, and weight loss, leading to nutritional deficiency and impaired quality of life. A plethora of antifungal treatments are available. The overall prognosis of oral candidiasis is good, and rarely is the condition life threatening with invasive or recalcitrant disease.

  16. Angular distributions as lifetime probes

    Energy Technology Data Exchange (ETDEWEB)

    Dror, Jeff Asaf; Grossman, Yuval [Department of Physics, LEPP, Cornell University,Ithaca, NY 14853 (United States)

    2014-06-27

    If new TeV scale particles are discovered, it will be important to determine their width. There is, however, a problematic region, where the width is too small to be determined directly, and too large to generate a secondary vertex. For a collection of colored, spin polarized particles, hadronization depolarizes the particles prior to their decay. The amount of depolarization can be used to probe the lifetime in the problematic region. In this paper we apply this method to a realistic scenario of a top-like particle that can be produced at the LHC. We study how depolarization affects the angular distributions of the decay products and derive an equation for the distributions that is sensitive to the lifetime.

  17. Orbital angular momentum in phase space

    International Nuclear Information System (INIS)

    Rigas, I.; Sanchez-Soto, L.L.; Klimov, A.B.; Rehacek, J.; Hradil, Z.

    2011-01-01

    Research highlights: → We propose a comprehensive Weyl-Wigner formalism for the canonical pair angle-angular momentum. → We present a simple and useful toolkit for the practitioner. → We derive simple evolution equations in terms of a star product in the semiclassical limit. - Abstract: A comprehensive theory of the Weyl-Wigner formalism for the canonical pair angle-angular momentum is presented. Special attention is paid to the problems linked to rotational periodicity and angular-momentum discreteness.

  18. Management of Angular Cheilitis in children

    Directory of Open Access Journals (Sweden)

    Fajriani Fajriani

    2017-04-01

    Full Text Available Objective : Angular cheilitis is a type of oral soft tissue disease that can occur in children and adults, the condition is characterized by cracks and inflammation on both corners of the mouth. Although this disease can not cause severe disorder, it quite disturbs one's activity and physical appearance. Mild Angular cheilitis will recover itself over times. However severe conditions can cause pain and bleeding. This paper aims to inform colleagues about management of angular cheilitis in children.

  19. Management of angular cheilitis for children

    Directory of Open Access Journals (Sweden)

    Fajriani Fajriani

    2016-06-01

    Full Text Available Angular cheilitis is one type of oral soft tissue disease that can occur in both children and adults, the condition is characterized by cracks and inflammation in both corners of the mouth. Although this disease does not cause severe disruption but quite disturbing activity and also one's physical appearance. Angular cheilitis light will disappear on their own over time.Severe conditions that can cause pain and bleading. aims to give feedback on peers about managment angular cheilitis in children.

  20. AngularJS Performance: A Survey Study

    OpenAIRE

    Ramos, Miguel; Valente, Marco Tulio; Terra, Ricardo

    2017-01-01

    AngularJS is a popular JavaScript MVC-based framework to construct single-page web applications. In this paper, we report the results of a survey with 95 professional developers about performance issues of AngularJS applications. We report common practices followed by developers to avoid performance problems (e.g., use of third-party or custom components), the general causes of performance problems in AngularJS applications (e.g., inadequate architecture decisions taken by AngularJS users), a...

  1. Transverse and longitudinal angular momenta of light

    Energy Technology Data Exchange (ETDEWEB)

    Bliokh, Konstantin Y., E-mail: k.bliokh@gmail.com [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Nonlinear Physics Centre, RSPhysE, The Australian National University, Canberra, ACT 0200 (Australia); Nori, Franco [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Physics Department, University of Michigan, Ann Arbor, MI 48109-1040 (United States)

    2015-08-26

    We review basic physics and novel types of optical angular momentum. We start with a theoretical overview of momentum and angular momentum properties of generic optical fields, and discuss methods for their experimental measurements. In particular, we describe the well-known longitudinal (i.e., aligned with the mean momentum) spin and orbital angular momenta in polarized vortex beams. Then, we focus on the transverse (i.e., orthogonal to the mean momentum) spin and orbital angular momenta, which were recently actively discussed in theory and observed in experiments. First, the recently-discovered transverse spin  angular momenta appear in various structured fields: evanescent waves, interference fields, and focused beams. We show that there are several kinds of transverse spin angular momentum, which differ strongly in their origins and physical properties. We describe extraordinary features of the transverse optical spins and overview recent experiments. In particular, the helicity-independent transverse spin inherent in edge evanescent waves offers robust spin–direction coupling at optical interfaces (the quantum spin Hall effect of light). Second, we overview the transverse orbital angular momenta of light, which can be both extrinsic and intrinsic. These two types of the transverse orbital angular momentum are produced by spatial shifts of the optical beams (e.g., in the spin Hall effect of light) and their Lorentz boosts, respectively. Our review is underpinned by a unified theory of the angular momentum of light based on the canonical momentum and spin densities, which avoids complications associated with the separation of spin and orbital angular momenta in the Poynting picture. It allows us to construct a comprehensive classification of all known optical angular momenta based on their key parameters and main physical properties.

  2. Electrochemical sensing platform based on tris(2,2'-bipyridyl)cobalt(III) and multiwall carbon nanotubes-Nafion composite for immunoassay of carcinoma antigen-125

    International Nuclear Information System (INIS)

    Chen Shihong; Yuan Ruo; Chai Yaqin; Min Ligen; Li Wenjuan; Xu Yang

    2009-01-01

    A new strategy for constructing a sensitive mediator-type electrochemical immunosensor for the detection of carcinoma antigen-125 (CA125) was developed. In this strategy, mediator tris(2,2'-bipyridyl)cobalt(III) (Co(bpy) 3 3+ ) was incoporated into the multiwall carbon nanotubes-Nafion (MWNTs-Nafion) composite film via a simple ion-exchange route. Then, gold colloidal nanoparticles (nano-Au) were attached onto Co(bpy) 3 3+ /MWNTs-Nafion film through electrostatic interaction between negatively charged nano-Au and positively charged Co(bpy) 3 3+ . Finally, CA125 monoclonal antibody (anti-CA125), used as a model antibody, was assembled onto the surface of nano-Au to achieve an immunosensor for the determination of CA125 antigen. X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) were used to characterize the assembly process of the modified electrode. The resulting immunosensor showed a high sensitivity, wide dynamic range consisting of two linear parts from 1.0 to 30 U mL -1 and 30 to 150 U mL -1 with a low detection limit of 0.36 U mL -1 at 3 times the background noise. Moreover, it displayed good reproducibility and stability, and would be potentially attractive for clinical immunoassay of CA125. The integration of mediator Co(bpy) 3 3+ and MWNTs-Nafion composite would offer potential promise for the fabrication of biosensors and biocatalysts.

  3. Electron transfer study on graphene modified glassy carbon substrate via electrochemical reduction and the application for tris(2,2'-bipyridyl)ruthenium(II) electrochemiluminescence sensor fabrication.

    Science.gov (United States)

    Xu, Yuanhong; Cao, Mengmei; Liu, Huihui; Zong, Xidan; Kong, Na; Zhang, Jizhen; Liu, Jingquan

    2015-07-01

    In this study, electron transfer behavior of the graphene nanosheets attachment on glassy carbon electrode (GCE) via direct electrochemical reduction of graphene oxide (GO) is investigated for the first time. The graphene modified electrode was achieved by simply dipping the GCE in GO suspension, followed by cyclic voltammetric scanning in the potential window from 0V to -1.5V. Tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy)3(2+)] was immobilized on the graphene modified electrode and used as the redox probe to evaluate the electron transfer behavior. The electron transfer rate constant (Ks) was calculated to be 61.9±5.8s(-1), which is much faster than that of tiled graphene modified GCE (7.1±0.6s(-1)). The enhanced electron transfer property observed with the GCE modified by reductively deposited graphene is probably due to its standing configuration, which is beneficial to the electron transfer comparing with the tiled one. Because the abundant oxygen-containing groups are mainly located at the edges of GO, which should be much easier for the reduction to start from, the reduced GO should tend to stand on the electrode surface as evidenced by scanning electron microscopy analysis. In addition, due to the favored electron transfer and standing configuration, the Ru(bpy)3(2+) electrochemiluminescence sensor fabricated with standing graphene modified GCE provided much higher and more stable efficiency than that fabricated with tiled graphene. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. One-step immobilization of tris(2,2'-bipyridyl)ruthenium(II) via vapor-surface sol-gel deposition towards solid-state electrochemiluminescence detection

    International Nuclear Information System (INIS)

    Qian Lei; Yang Xiurong

    2008-01-01

    A novel method for immobilization of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy) 3 Cl 2 ) on electrode surfaces based on the vapor-surface sol-gel deposition strategy is first demonstrated in this paper. Ru(bpy) 3 Cl 2 immobilized sol-gel (Ru(bpy) 3 Cl 2 /sol-gel) films were characterized by UV-vis spectroscopy and field-emitted scanning electron microscopy (FE-SEM). These results showed that Ru(bpy) 3 Cl 2 was successfully incorporated into the silica sol-gel film. It was found that many irregular Ru(bpy) 3 Cl 2 /sol-gel clusters were formed on surfaces through one deposition and thick sol-gel films were observed after further deposition. Electrochemical properties and electrochemiluminescence (ECL) behaviors of Ru(bpy) 3 Cl 2 /sol-gel films could be easily adjusted by deposition numbers and time. At last, the Ru(bpy) 3 Cl 2 /sol-gel film modified electrode was used for solid-state ECL detection of tripropylamine. The linear range was from 5.8 x 10 -8 to 2.4 x 10 -4 M with the detection limit of 5 nM, which was three orders of magnitude lower than that from pure Nafion-modified electrodes. The ECL sensor also exhibited high stability, and still remained 92% response after being stored in air for 35 days. This method for immobilization of Ru(bpy) 3 Cl 2 is simple, convenient and low-cost relative to others, so it shows promising applications in solid-state ECL detection

  5. Glutamate receptor ligands

    DEFF Research Database (Denmark)

    Guldbrandt, Mette; Johansen, Tommy N; Frydenvang, Karla Andrea

    2002-01-01

    Homologation and substitution on the carbon backbone of (S)-glutamic acid [(S)-Glu, 1], as well as absolute stereochemistry, are structural parameters of key importance for the pharmacological profile of (S)-Glu receptor ligands. We describe a series of methyl-substituted 2-aminoadipic acid (AA...

  6. Dissociation and Dioxygen Formation in Hydroxide Solutions of Tris (2,2- bipyridyl) Iron (III) and Tris (1,10-phenanthroline) Iron (III)

    DEFF Research Database (Denmark)

    Nord, G.; Pedersen, B.; Bjergbakke, Erling

    1983-01-01

    The fast redox reactions of the title Fe(II1) complexes in basic solutions give the Fe(I1) complexes and coordinated ligand N-oxide as primary products. Further reactions by parallel paths include dissociation to give the free ligand N-oxide and catalysis by hydroxy Fe(II1) complexes leading...

  7. Experimental determination of high angular momentum states

    International Nuclear Information System (INIS)

    Barreto, J.L.V.

    1985-01-01

    The current knowledge of the atomic nucleus structure is summarized. A short abstract of the nuclear properties at high angular momentum and a more detailed description of the experimental methods used in the study of high angular momenta is made. (L.C.) [pt

  8. Exposing Library Services with AngularJS

    OpenAIRE

    Jakob Voß; Moritz Horn

    2014-01-01

    This article provides an introduction to the JavaScript framework AngularJS and specific AngularJS modules for accessing library services. It shows how information such as search suggestions, additional links, and availability can be embedded in any website. The ease of reuse may encourage more libraries to expose their services via standard APIs to allow usage in different contexts.

  9. Accelerated rotation with orbital angular momentum modes

    CSIR Research Space (South Africa)

    Schulze, C

    2015-04-01

    Full Text Available . As the angular acceleration takes place in a bounded space, the azimuthal degree of freedom, such fields accelerate periodically as they propagate. Notably, the amount of angular acceleration is not limited by paraxial considerations, may be tailored for large...

  10. Responsive web design with AngularJS

    CERN Document Server

    Patel, Sandeep Kumar

    2014-01-01

    If you are an AngularJS developer who wants to learn about responsive web application development, this book is ideal for you. Responsive Web Design with AngularJS is intended for web developers or designers with a basic knowledge of HTML, CSS, and JavaScript.

  11. Angular momentum projected wave-functions

    International Nuclear Information System (INIS)

    Bengtsson, R.; Haakansson, H.B.

    1978-01-01

    Angular momentum projection has become a vital link between intrinsic model-wavefunctions and the physical states one intends to describe. We discuss in general terms some aspects of angular momentum projection and present results from projection on e.g. cranking wavefunctions. Mass densities and spectroscopic factors are also presented for some cases. (author)

  12. Concepts of radial and angular kinetic energies

    DEFF Research Database (Denmark)

    Dahl, Jens Peder; Schleich, W.P.

    2002-01-01

    We consider a general central-field system in D dimensions and show that the division of the kinetic energy into radial and angular parts proceeds differently in the wave-function picture and the Weyl-Wigner phase-space picture, Thus, the radial and angular kinetic energies are different quantities...

  13. Perturbed angular correlations and distributions

    International Nuclear Information System (INIS)

    Makaryunas, K.

    1976-01-01

    The present index comprises original works and review papers on the perturbed angular correlations (PAC) and distributions (PAD). The articles published in the Soviet and foreign journals as well as the materials of conferences, monographs and collections published in the USSR and abroad, the preprints produced by various institutes and abstracts of disertations are included from 1948 up to 1973. The whole material compiled in this index is divided into three parts. Part one is a bibliographic index. All papers in this part are divided into three sections. Section one comprises the papers devoted to the theoretical works on PAC, review papers, monographs, materials of conferences. Section two deals with the works of methodical character where correlation spectrometers as well as the treatment of experimental data are described. In section three experimental works with concrete nuclei are compiled. Part two gives the characteristic of works performed with concrete nuclei. This part is presented in the form of the table in which the works are systematized according to the chemical elements and isotopes. The table shows the characteristics of the nuclear levels used in the investigations by PAC as well as brief characteristics of experiments and results obtained. Part three - appendix contains alphabetic index of the authors, the list of the used editions with the abbreviations of the titles of these editions. The lists indicating the dynamic of the quantity of works on PAC and the distribution according to the literature sources are also given

  14. Angular correlation in positron annihilation

    International Nuclear Information System (INIS)

    Arponen, J.; Pajanne, E.

    1978-01-01

    The angular correlation of the two gamma quanta emitted when a thermalized positron annihilates with metallic conduction electrons is investigated by applying the newly developed theory of electron gas as a system of interacting collective excitations. The method leads in a natural way to the appearance of high-momentum components (i.e. pair momentum p>psub(F) in the annihilation radiation already in the case of annihilation with conduction electrons only. The amount of these components is significant approximately (10 %) in a dilute electron gas (like alkali metals), but fairly irrelevant for higher densities. The momentum-dependence of the enhancement factor for a dense system (with rsub(s) approximately equal to 2) agrees well both with the earlier theories due to Kahana and others, and also with recent accurate experimental observations. As rsub(s) increases into the alkali-metal region, the enhancement factor for p< psub(F) becomes relatively more and more constant, in contrast with the trend in the Kahana theory. In this density regime the experimental results seem to vary widely, although most of them desagree with the present prediction. We discuss the possible discrepancy and try to account for the effects of the core annihilation by a simple model. (author)

  15. AMPA receptor ligands

    DEFF Research Database (Denmark)

    Strømgaard, Kristian; Mellor, Ian

    2004-01-01

    Alpha-amino-3-hydroxy-5-methyl-4-isoxazole propionic acid (AMPA) receptors (AMPAR), subtype of the ionotropic glutamate receptors (IGRs), mediate fast synaptic transmission in the central nervous system (CNS), and are involved in many neurological disorders, as well as being a key player in the f......Alpha-amino-3-hydroxy-5-methyl-4-isoxazole propionic acid (AMPA) receptors (AMPAR), subtype of the ionotropic glutamate receptors (IGRs), mediate fast synaptic transmission in the central nervous system (CNS), and are involved in many neurological disorders, as well as being a key player...... in the formation of memory. Hence, ligands affecting AMPARs are highly important for the study of the structure and function of this receptor, and in this regard polyamine-based ligands, particularly polyamine toxins, are unique as they selectively block Ca2+ -permeable AMPARs. Indeed, endogenous intracellular...

  16. Radiobiology with DNA ligands

    International Nuclear Information System (INIS)

    Weinreich, R.; Argentini, M.; Guenther, I.; Koziorowski, J.; Larsson, B.; Nievergelt-Egido, M.C.; Salt, C.; Wyer, L.; Dos Santos, D.F.; Hansen, H.J.

    1997-01-01

    The paper deals with the following topics: labelling of DNA ligands and other tumour-affinic compounds with 4.15-d 124 I, radiotoxicity of Hoechst 33258 and 33342 and of iodinated Hoechst 33258 in cell cultures, preparation of 76 Br-, 123 I-, and 221 At-labelled 5-halo-2'-deoxyuridine, chemical syntheses of boron derivatives of Hoechst 33258.III., Gadolinium neutron capture therapy

  17. Angular momentum conservation for uniformly expanding flows

    International Nuclear Information System (INIS)

    Hayward, Sean A

    2007-01-01

    Angular momentum has recently been defined as a surface integral involving an axial vector and a twist 1-form, which measures the twisting around the spacetime due to a rotating mass. The axial vector is chosen to be a transverse, divergence-free, coordinate vector, which is compatible with any initial choice of axis and integral curves. Then a conservation equation expresses the rate of the change of angular momentum along a uniformly expanding flow as a surface integral of angular momentum densities, with the same form as the standard equation for an axial Killing vector, apart from the inclusion of an effective energy tensor for gravitational radiation

  18. Staggering of angular momentum distribution in fission

    Science.gov (United States)

    Tamagno, Pierre; Litaize, Olivier

    2018-03-01

    We review here the role of angular momentum distributions in the fission process. To do so the algorithm implemented in the FIFRELIN code [?] is detailed with special emphasis on the place of fission fragment angular momenta. The usual Rayleigh distribution used for angular momentum distribution is presented and the related model derivation is recalled. Arguments are given to justify why this distribution should not hold for low excitation energy of the fission fragments. An alternative ad hoc expression taking into account low-lying collectiveness is presented as has been implemented in the FIFRELIN code. Yet on observables currently provided by the code, no dramatic impact has been found. To quantify the magnitude of the impact of the low-lying staggering in the angular momentum distribution, a textbook case is considered for the decay of the 144Ba nucleus with low excitation energy.

  19. Amplitude damping channel for orbital angular momentum

    CSIR Research Space (South Africa)

    Dudley, Angela L

    2010-03-01

    Full Text Available Since the pioneering work on the entanglement of the orbital angular momentum (OAM) states of light, much attention has been devoted to the subject, with particular attention into the quantum aspects of information processing using OAM. Furthermore...

  20. Radiofrequency encoded angular-resolved light scattering

    DEFF Research Database (Denmark)

    Buckley, Brandon W.; Akbari, Najva; Diebold, Eric D.

    2015-01-01

    The sensitive, specific, and label-free classification of microscopic cells and organisms is one of the outstanding problems in biology. Today, instruments such as the flow cytometer use a combination of light scatter measurements at two distinct angles to infer the size and internal complexity...... of cells at rates of more than 10,000 per second. However, by examining the entire angular light scattering spectrum it is possible to classify cells with higher resolution and specificity. Current approaches to performing these angular spectrum measurements all have significant throughput limitations...... Encoded Angular-resolved Light Scattering (REALS), this technique multiplexes angular light scattering in the radiofrequency domain, such that a single photodetector captures the entire scattering spectrum from a particle over approximately 100 discrete incident angles on a single shot basis. As a proof...

  1. Orbital-angular-momentum entanglement in turbulence

    CSIR Research Space (South Africa)

    Hamadou Ibrahim, A

    2013-06-01

    Full Text Available The turbulence-induced decay of orbital-angular-momentum (OAM) entanglement between two photons is investigated numerically and experimentally. To compare our resultswith previouswork,we simulate the turbulent atmosphere with a single phase screen...

  2. Staggering of angular momentum distribution in fission

    Directory of Open Access Journals (Sweden)

    Tamagno Pierre

    2018-01-01

    Full Text Available We review here the role of angular momentum distributions in the fission process. To do so the algorithm implemented in the FIFRELIN code [?] is detailed with special emphasis on the place of fission fragment angular momenta. The usual Rayleigh distribution used for angular momentum distribution is presented and the related model derivation is recalled. Arguments are given to justify why this distribution should not hold for low excitation energy of the fission fragments. An alternative ad hoc expression taking into account low-lying collectiveness is presented as has been implemented in the FIFRELIN code. Yet on observables currently provided by the code, no dramatic impact has been found. To quantify the magnitude of the impact of the low-lying staggering in the angular momentum distribution, a textbook case is considered for the decay of the 144Ba nucleus with low excitation energy.

  3. QCD angular correlations for muon pair production

    International Nuclear Information System (INIS)

    Kajantie, K.; Raitio, R.; Lindfors, J.

    1978-01-01

    Angular distributions of muons are discussed in the framework of a QCD treatment of muon pair production in hadron-hadron collisions. The predicted angular effects are independent of the infrared behavior of QCD. Measuring them will permit one to determine whether the origin of the large transverse momentum of the pair is in the quark transverse momenta or in a constituent-constituent subprocess. (author)

  4. Mastering AngularJD for .NET developers

    CERN Document Server

    Majid, Mohammad Wadood

    2015-01-01

    This book is envisioned for traditional developers and programmers who want to develop client-side applications using the AngularJS framework and ASP.NET Web API 2 with Visual Studio. .NET developers who have already built web applications or web services and who have a fundamental knowledge of HTML, JavaScript, and CSS and want to explore single-page applications will also find this guide useful. Basic knowledge of AngularJS would be helpful.

  5. Angular Spectra of Polarized Galactic Foregrounds

    OpenAIRE

    Cho, Jung; Lazarian, A.

    2003-01-01

    It is believed that magnetic field lines are twisted and bend by turbulent motions in the Galaxy. Therefore, both Galactic synchrotron emission and thermal emission from dust reflects statistics of Galactic turbulence. Our simple model of Galactic turbulence, motivated by results of our simulations, predicts that Galactic disk and halo exhibit different angular power spectra. We show that observed angular spectra of synchrotron emission are compatible with our model. We also show that our mod...

  6. Beam Angular Divergence Effects in Ion Implantation

    International Nuclear Information System (INIS)

    Horsky, T. N.; Hahto, S. K.; Bilbrough, D. G.; Jacobson, D. C.; Krull, W. A.; Goldberg, R. D.; Current, M. I.; Hamamoto, N.; Umisedo, S.

    2008-01-01

    An important difference between monomer ion beams and heavy molecular beams is a significant reduction in beam angular divergence and increased on-wafer angular accuracy for molecular beams. This advantage in beam quality stems from a reduction in space-charge effects within the beam. Such improved angular accuracy has been shown to have a significant impact on the quality and yield of transistor devices [1,12]. In this study, B 18 H x + beam current and angular divergence data collected on a hybrid scanned beam line that magnetically scans the beam across the wafer is presented. Angular divergence is kept below 0.5 deg from an effective boron energy of 200 eV to 3000 eV. Under these conditions, the beam current is shown analytically to be limited by space charge below about 1 keV, but by the matching of the beam emittance to the acceptance of the beam line above 1 keV. In addition, results of a beam transport model which includes variable space charge compensation are presented, in which a drift mode B 18 H x + beam is compared to an otherwise identical boron beam after deceleration. Deceleration is shown to introduce significant space-charge blow up resulting in a large on-wafer angular divergence. The divergence effects introduced by wafer charging are also discussed.

  7. Bexarotene ligand pharmaceuticals.

    Science.gov (United States)

    Hurst, R E

    2000-12-01

    Bexarotene (LGD-1069), from Ligand, was the first retinoid X receptor (RXR)-selective, antitumor retinoid to enter clinical trials. The company launched the drug for the treatment of cutaneous T-cell lymphoma (CTCL), as Targretin capsules, in the US in January 2000 [359023]. The company filed an NDA for Targretin capsules in June 1999, and for topical gel in December 1999 [329011], [349982] specifically for once-daily oral administration for the treatment of patients with early-stage CTCL who have not tolerated other therapies, patients with refractory or persistent early stage CTCL and patients with refractory advanced stage CTCL. The FDA approved Targretin capsules at the end of December 1999 for once-daily oral treatment of all stages of CTCL in patients refractory to at least one prior systemic therapy, at an initial dose of 300 mg/m2/day. After an NDA was submitted in December 1999 for Targretin gel, the drug received Priority Review status for use as a treatment of cutaneous lesions in patients with stage IA, IB or IIA CTCL [354836]. The FDA issued an approvable letter in June 2000, and granted marketing clearance for CTCL in the same month [370687], [372768], [372769], [373279]. Ligand had received Orphan Drug designation for this indication [329011]. At the request of the FDA, Ligand agreed to carry out certain post-approval phase IV and pharmacokinetic studies [351604]. The company filed an MAA with the EMEA for Targretin Capsules to treat lymphoma in November 1999 [348944]. The NDA for Targretin gel is based on a multicenter phase III trial that was conducted in the US, Canada, Europe and Australia involving 50 patients and a multicenter phase I/II clinical program involving 67 patients. Targretin gel was evaluated for the treatment of patients with early stage CTCL (IA-IIA) who were refractory to, intolerant to, or reached a response plateau for at least 6 months on at least two prior therapies. Efficacy results exceeded the protocol-defined response

  8. Angular distributions in quasi-fission reactions

    International Nuclear Information System (INIS)

    Luetzenkirchen, K.; Kratz, J.V.; Lucas, R.; Poitou, J.; Gregoire, C.; Wirth, G.; Bruechle, W.; Suemmerer, K.

    1985-10-01

    Angular distributions for fission-like fragments were measured in the systems 50 Ti, 56 Fe + 208 Pb by applying an off-line KX-ray activation technique. The distributions d 2 sigma/dTHETAdZ exhibit forward-backward asymmetries that are strongly Z-dependent. They result from a process (quasi-fission) which yields nearly symmetric masses in times comparable to the rotational period of the composite system. A method for obtaining the variance of the tilting angular momentum, K 0 2 , from these skewed, differential angular distributions is described. The results indicate that the tilting mode is not fully excited in quasi-fission reactions. The results are compared to the sum of the variances of all statistical spin components, measured via γ-multiplicities. Integration of the angular distributions d 2 sigma/dTHETAdZ over all values of Z yields integral angular distributions dsigma/dTHETA and dsigma/dΩ symmetric around 90 0 . The associated unusually large anisotropies do not at all provide an adequate basis for tests or modifications of the transition state theory. A deconvolution of d 2 sigma/dTHETAdZ is performed with gaussian distributions depending on rotational angles ΔTHETA extending over a range of up to 540 0 . From the mean values a time scale for the evolution of K 0 is calculated. (orig.)

  9. Angular distribution of oriented nucleus fission neutrons

    International Nuclear Information System (INIS)

    Barabanov, A.L.; Grechukhin, D.P.

    1982-01-01

    Calculations of anisotropy of angular distribution of oriented 235 U nuclei thermal fission neutrons have been carried out. the neutrons were assumed to evaporate isotropically by completely accelerated fragements in the fragment system with only its small part, i. e. fission-producing neutrons, emitted at the moment of neck break. It has been found out that at low energies of neutrons Esub(n)=1-2 MeV the sensitivity of the angular distribution anisotropy to variations of spectrum of neutron evaporation from fragments and the magnitude of a share of fission-producing neutrons reaches approximately 100%, which at high energies, Esub(n) > 5 MeV it does not exceed approximately 20%. Therefore the angular distribution of fast neutrons to a greater degree of confidence may be used for restoring the angular distribution anisotropy of fragments while the angular distribution of low energy neutrons may be used for deriving information on the fission process, but only in case 6f the experiment accuracy is better than approximately 3%

  10. Transverse angular momentum in topological photonic crystals

    Science.gov (United States)

    Deng, Wei-Min; Chen, Xiao-Dong; Zhao, Fu-Li; Dong, Jian-Wen

    2018-01-01

    Engineering local angular momentum of structured light fields in real space enables applications in many fields, in particular, the realization of unidirectional robust transport in topological photonic crystals with a non-trivial Berry vortex in momentum space. Here, we show transverse angular momentum modes in silicon topological photonic crystals when considering transverse electric polarization. Excited by a chiral external source with either transverse spin angular momentum or transverse phase vortex, robust light flow propagating along opposite directions is observed in several kinds of sharp-turn interfaces between two topologically-distinct silicon photonic crystals. A transverse orbital angular momentum mode with alternating phase vortex exists at the boundary of two such photonic crystals. In addition, unidirectional transport is robust to the working frequency even when the ring size or location of the pseudo-spin source varies in a certain range, leading to the superiority of the broadband photonic device. These findings enable one to make use of transverse angular momentum, a kind of degree of freedom, to achieve unidirectional robust transport in the telecom region and other potential applications in integrated photonic circuits, such as on-chip robust delay lines.

  11. Angular cheilitis: A clinical and microbial study

    Directory of Open Access Journals (Sweden)

    Nirima Oza

    2017-01-01

    Full Text Available Aims: The aim of the present study was to examine clinical types and microbiological flora isolated from angular chelitis. Materials and Methods: An eroded and/or erythematous, with or without fissure formation, nonvesicular lesion radiating from the angle of the mouth was considered to be angular chelitis. A sample of the present study comprised of 40 patients having unilateral or bilateral angular chelitis and 20 healthy individuals without any lip lesions. Clinical examination was done. In both test and control groups, the sample for microbial analysis was obtained from angle of the mouth. Results: Clinically, four types of angular cheilitis lesions were found, Type I, II, III, and IV. The most common type of lesion found was Type I lesion. Microorganisms isolated from the lesion were Staphylococcus aureus, Candida or Streptococci in 33 (82.5% cases either in pure culture or mixed culture. Among these 33 patients, S. aureus was found in 25 (75.5% cases, Candida in 16 (48.4% cases, and Streptococci in 5 (13.5% cases, respectively. Out of 16 cases positive for Candida, in 13 cases further isolation of Candida was possible. Candida albicans was found in 6 cases and Candida stellastodia in 7 cases. In majority of the dentulous and edentulous patients, S. aureus showed profuse growth. Conclusions: There are microorganisms associated with angular cheilitis.

  12. Ligand Depot: a data warehouse for ligands bound to macromolecules.

    Science.gov (United States)

    Feng, Zukang; Chen, Li; Maddula, Himabindu; Akcan, Ozgur; Oughtred, Rose; Berman, Helen M; Westbrook, John

    2004-09-01

    Ligand Depot is an integrated data resource for finding information about small molecules bound to proteins and nucleic acids. The initial release (version 1.0, November, 2003) focuses on providing chemical and structural information for small molecules found as part of the structures deposited in the Protein Data Bank. Ligand Depot accepts keyword-based queries and also provides a graphical interface for performing chemical substructure searches. A wide variety of web resources that contain information on small molecules may also be accessed through Ligand Depot. Ligand Depot is available at http://ligand-depot.rutgers.edu/. Version 1.0 supports multiple operating systems including Windows, Unix, Linux and the Macintosh operating system. The current drawing tool works in Internet Explorer, Netscape and Mozilla on Windows, Unix and Linux.

  13. Data-oriented development with AngularJS

    CERN Document Server

    Waikar, Manoj

    2015-01-01

    This book helps beginner-level AngularJS developers organize AngularJS applications by discussing important AngularJS concepts and best practices. If you are an experienced AngularJS developer but haven't written directives or haven't created custom HTML controls before, then this book is ideal for you.

  14. Angular correlations and high energy evolution

    International Nuclear Information System (INIS)

    Kovner, Alex; Lublinsky, Michael

    2011-01-01

    We address the question of to what extent JIMWLK evolution is capable of taking into account angular correlations in a high energy hadronic wave function. Our conclusion is that angular (and indeed other) correlations in the wave function cannot be reliably calculated without taking into account Pomeron loops in the evolution. As an example we study numerically the energy evolution of angular correlations between dipole scattering amplitudes in the framework of the large N c approximation to JIMWLK evolution (the 'projectile dipole model'). Target correlations are introduced via averaging over an (isotropic) ensemble of anisotropic initial conditions. We find that correlations disappear very quickly with rapidity even inside the saturation radius. This is in accordance with our physical picture of JIMWLK evolution. The actual correlations inside the saturation radius in the target QCD wave function, on the other hand, should remain sizable at any rapidity.

  15. Angular distributions in pre-equilibrium reactions

    International Nuclear Information System (INIS)

    Chatterjee, A.; Gupta, S.K.; Bhabha Atomic Research Centre, Bombay

    1982-10-01

    A new model is proposed for calculating angular distributions in preequilibrium reactions. In this model, as in the model of Feshbach et al. the system consisting of target plus projectile initially branches into two sets of states with either no particle in the continuum (multistep compound states) or with at least one particle in the continuum (multistep direct states). The two chains of states are treated independently by solving two sets of master equations. The multistep compound emission is assumed to be isotropic while the angular distribution of the multistep direct emission is described using the fast particle model of Mantzouranis et al. The angular distributions for 14.6 MeV neutrons calculated using this model are found to be in better agreement with the data than the fast particle model. (author)

  16. Angular momentum alignment in molecular beam scattering

    International Nuclear Information System (INIS)

    Treffers, M.A.

    1985-01-01

    It is shown how the angular momentum alignment in a molecular beam can be determined using laser-induced fluorescence in combination with precession of the angular momenta in a magnetic field. After a general analysis of the method, some results are presented to illustrate the possibilities of the method. Experimental data are presented on the alignment production for Na 2 molecules that made a collision induced angular momentum transition. Magnitude as well as direction of the alignment have been determined for scattering with several scattering partners and for a large number of scattering angles and transitions. The last chapter deals with the total alignment production in a final J-state, i.e. without state selection of the initial rotational state. (orig.)

  17. Metal-ligand interactions

    Science.gov (United States)

    Ervin, Kent M.

    Experimental studies of the interactions of small transition-metal cluster anions with carbonyl ligands are reviewed and compared with neutral and cationic clusters. Under thermal conditions, the reaction rates of transition-metal clusters with carbon monoxide are measured as a function of cluster size. Saturation limits for carbon monoxide addition can be related to the geometric structures of the clusters. Both energy-resolved threshold collision-induced dissociation experiments and time-resolved photodissociation experiments are used to measure metal-carbonyl binding energies. For platinum and palladium trimer anions, the carbonyl binding energies are assigned to different geometric binding sites. Platinum and palladium cluster anions catalyse the oxidation of carbon monoxide to carbon dioxide in a full catalytic cycle at thermal energies.

  18. Melatonin: functions and ligands.

    Science.gov (United States)

    Singh, Mahaveer; Jadhav, Hemant R

    2014-09-01

    Melatonin is a chronobiotic substance that acts as synchronizer by stabilizing bodily rhythms. Its synthesis occurs in various locations throughout the body, including the pineal gland, skin, lymphocytes and gastrointestinal tract (GIT). Its synthesis and secretion is controlled by light and dark conditions, whereby light decreases and darkness increases its production. Thus, melatonin is also known as the 'hormone of darkness'. Melatonin and analogs that bind to the melatonin receptors are important because of their role in the management of depression, insomnia, epilepsy, Alzheimer's disease (AD), diabetes, obesity, alopecia, migraine, cancer, and immune and cardiac disorders. In this review, we discuss the mechanism of action of melatonin in these disorders, which could aid in the design of novel melatonin receptor ligands. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Ghost Imaging Using Orbital Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    赵生妹; 丁建; 董小亮; 郑宝玉

    2011-01-01

    We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum. In the signal arm, object spatial information is encoded as a phase matrix. For an N-grey-scale object, different phase matrices, varying from 0 to K with increment n/N, are used for different greyscales, and then they are modulated to a signal beam by a spatial light modulator. According to the conservation of the orbital angular momentum in the ghost imaging system, these changes will give different coincidence rates in measurement, and hence the object information can be extracted in the idler arm. By simulations and experiments, the results show that our scheme can improve the resolution of the image effectively. Compared with another encoding method using orbital angular momentum, our scheme has a better performance for both characters and the image object.%We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum.In the signal arm,object spatial information is encoded as a phase matrix.For an N-grey-scale object,different phase matrices,varying from 0 to π with increment π/N,are used for different greyscales,and then they are modulated to a signal beam by a spatial light modulator.According to the conservation of the orbital angular momentum in the ghost imaging system,these changes will give different coincidence rates in measurement,and hence the object information can be extracted in the idler arm.By simulations and experiments,the results show that our scheme can improve the resolution of the image effectively.Compared with another encoding method using orbital angular momentum,our scheme has a better performance for both characters and the image object.

  20. Macrocyclic G-quadruplex ligands

    DEFF Research Database (Denmark)

    Nielsen, M C; Ulven, Trond

    2010-01-01

    are macrocyclic structures which have been modeled after the natural product telomestatin or from porphyrin-based ligands discovered in the late 1990s. These two structural classes of G-quadruplex ligands are reviewed here with special attention to selectivity and structure-activity relationships, and with focus...

  1. Total angular momentum from Dirac eigenspinors

    International Nuclear Information System (INIS)

    Szabados, Laszlo B

    2008-01-01

    The eigenvalue problem for Dirac operators, constructed from two connections on the spinor bundle over closed spacelike 2-surfaces, is investigated. A class of divergence-free vector fields, built from the eigenspinors, are found, which, for the lowest eigenvalue, reproduce the rotation Killing vectors of metric spheres, and provide rotation BMS vector fields at future null infinity. This makes it possible to introduce a well-defined, gauge invariant spatial angular momentum at null infinity, which reduces to the standard expression in stationary spacetimes. The general formula for the angular momentum flux carried away by the gravitational radiation is also derived

  2. Studying AGN Jets At Extreme Angular Resolution

    Science.gov (United States)

    Bruni, Gabriele

    2016-10-01

    RadioAstron is a 10m antenna orbiting on the Russian Speckt-R spacecraft, launched in 2011. Performing radio interferometry with a global array of ground telescopes, it is providing record angular resolution. The Key Science Project on AGN polarization is exploiting it to study in great detail the configuration of magnetic fields in AGN jets, and understand their formation and collimation. To date, the project has already achieved the highest angular resolution image ever obtained in Astronomy, and detected brightness temperatures exceeding the ones predicted by theory of AGN.

  3. Factorial correlators: angular scaling within QCD jets

    International Nuclear Information System (INIS)

    Peschanski, R.

    2001-01-01

    Factorial correlators measure the amount of dynamical correlation in the multiplicity between two separated phase-space windows. We present the analytical derivation of factorial correlators for a QCD jet described at the double logarithmic (DL) accuracy. We obtain a new angular scaling property for properly normalized correlators between two solid-angle cells or two rings around the jet axis. Normalized QCD factorial correlators scale with the angular distance and are independent of the window size. Scaling violations are expected beyond the DL approximation, in particular from the subject structure. Experimental tests are feasible, and thus would be welcome. (orig.)

  4. Synthesis of a ruthenium(II) bipyridyl complex coordinated by a functionalized Schiff base ligand: characterization, spectroscopic and isothermal titration calorimetry measurements of M2+ binding and sensing (M2+=Ca2+, Mg2+).

    Science.gov (United States)

    Dixit, Namrata; Mishra, Lallan; Mustafi, Sourajit M; Chary, Kandala V R; Houjou, Hirohiko

    2009-07-01

    Bis-[methylsalicylidine-4'benzoic acid]-ethylene (LH2) complexed with cis-Ru(bpy)2Cl(2).2H2O provides a complex of composition [Ru(bpy)2L].2NH4PF6 (1), which has been characterized spectroscopically. Its binding behaviour towards Mg2+ and Ca2+ ions is monitored using 1H NMR titration, isothermal titration calorimetry (ITC) and luminescence microscopy. The luminescent ruthenium complex binds Ca2+ in a more selective manner as compared to Mg2+.

  5. Canonical three-body angular basis

    International Nuclear Information System (INIS)

    Matveenko, A.V.

    2001-01-01

    Three-body problems are basic for the quantum mechanics of molecular, atomic, or nuclear systems. We demonstrate that their variational solution for rotational states can be greatly simplified. A special choice of coordinates (hyperspherical) and of the kinematics (body-fixed coordinate frame) allows one to choose basis functions in a form that makes the angular coupling trivial. (author)

  6. Probabilistic calculation for angular dependence collision

    International Nuclear Information System (INIS)

    Villarino, E.A.

    1990-01-01

    This collision probabilistic method is broadly used in cylindrical geometry (in one- or two-dimensions). It constitutes a powerful tool for the heterogeneous Response Method where, the coupling current is of the cosine type, that is, without angular dependence at azimuthal angle θ and proportional to μ (cosine of the θ polar angle). (Author) [es

  7. Wigner Functions and Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Mukherjee Asmita

    2015-01-01

    Full Text Available Wigner distributions contain combined position and momentum space information of the quark distributions and are related to both generalized parton distributions (GPDs and transverse momentum dependent parton distributions (TMDs. We report on a recent model calculation of the Wigner distributions for the quark and their relation to the orbital angular momentum.

  8. Wigner Functions and Quark Orbital Angular Momentum

    OpenAIRE

    Mukherjee, Asmita; Nair, Sreeraj; Ojha, Vikash Kumar

    2014-01-01

    Wigner distributions contain combined position and momentum space information of the quark distributions and are related to both generalized parton distributions (GPDs) and transverse momentum dependent parton distributions (TMDs). We report on a recent model calculation of the Wigner distributions for the quark and their relation to the orbital angular momentum.

  9. A Novel Permanent Magnetic Angular Acceleration Sensor

    Directory of Open Access Journals (Sweden)

    Hao Zhao

    2015-07-01

    Full Text Available Angular acceleration is an important parameter for status monitoring and fault diagnosis of rotary machinery. Therefore, we developed a novel permanent magnetic angular acceleration sensor, which is without rotation angle limitations and could directly measure the instantaneous angular acceleration of the rotating system. The sensor rotor only needs to be coaxially connected with the rotating system, which enables convenient sensor installation. For the cup structure of the sensor rotor, it has a relatively small rotational inertia. Due to the unique mechanical structure of the sensor, the output signal of the sensor can be directed without a slip ring, which avoids signal weakening effect. In this paper, the operating principle of the sensor is described, and simulated using finite element method. The sensitivity of the sensor is calibrated by torsional pendulum and angle sensor, yielding an experimental result of about 0.88 mV/(rad·s−2. Finally, the angular acceleration of the actual rotating system has been tested, using both a single-phase asynchronous motor and a step motor. Experimental result confirms the operating principle of the sensor and indicates that the sensor has good practicability.

  10. Angular-momentum-bearing modes in fission

    International Nuclear Information System (INIS)

    Moretto, L.G.; Peaslee, G.F.; Wozniak, G.J.

    1989-03-01

    The angular-momentum-bearing degrees of freedom involved in the fission process are identified and their influence on experimental observables is discussed. The excitation of these modes is treated in the ''thermal'' limit, and the resulting distributions of observables are calculated. Experiments demonstrating the role of these modes are presented and discussed. 61 refs., 12 figs

  11. Angular and linear momentum of excited ferromagnets

    NARCIS (Netherlands)

    Yan, P.; Kamra, A.; Cao, Y.; Bauer, G.E.W.

    2013-01-01

    The angular momentum vector of a Heisenberg ferromagnet with isotropic exchange interaction is conserved, while under uniaxial crystalline anisotropy the projection of the total spin along the easy axis is a constant of motion. Using Noether's theorem, we prove that these conservation laws persist

  12. Angular distribution in ternary cold fission

    International Nuclear Information System (INIS)

    Delion, D.S.; J.W. Goethe Univ., Frankfurt; Sandulescu, A.; J.W. Goethe Univ., Frankfurt; Greiner, W.

    2003-01-01

    We describe the spontaneous ternary cold fission of 252 Cf, accompanied by 4 He, 10 Be and 14 C. The light cluster decays from the first resonant eigenstate in the Coulomb potential plus a harmonic oscillator potential. We have shown that the angular distribution of the emitted light particle is strongly connected with its deformation and the equatorial distance. (author)

  13. Heteromodal conceptual processing in the angular gyrus.

    Science.gov (United States)

    Bonner, Michael F; Peelle, Jonathan E; Cook, Philip A; Grossman, Murray

    2013-05-01

    Concepts bind together the features commonly associated with objects and events to form networks in long-term semantic memory. These conceptual networks are the basis of human knowledge and underlie perception, imagination, and the ability to communicate about experiences and the contents of the environment. Although it is often assumed that this distributed semantic information is integrated in higher-level heteromodal association cortices, open questions remain about the role and anatomic basis of heteromodal representations in semantic memory. Here we used combined neuroimaging evidence from functional magnetic resonance imaging (fMRI) and diffusion tensor imaging (DTI) to characterize the cortical networks underlying concept representation. Using a lexical decision task, we examined the processing of concepts in four semantic categories that varied on their sensory-motor feature associations (sight, sound, manipulation, and abstract). We found that the angular gyrus was activated across all categories regardless of their modality-specific feature associations, consistent with a heteromodal account for the angular gyrus. Exploratory analyses suggested that categories with weighted sensory-motor features additionally recruited modality-specific association cortices. Furthermore, DTI tractography identified white matter tracts connecting these regions of modality-specific functional activation with the angular gyrus. These findings are consistent with a distributed semantic network that includes a heteromodal, integrative component in the angular gyrus in combination with sensory-motor feature representations in modality-specific association cortices. Copyright © 2013 Elsevier Inc. All rights reserved.

  14. ANGULAR MOMENTUM ACQUISITION IN GALAXY HALOS

    International Nuclear Information System (INIS)

    Stewart, Kyle R.; Brooks, Alyson M.; Bullock, James S.; Maller, Ariyeh H.; Diemand, Jürg; Wadsley, James; Moustakas, Leonidas A.

    2013-01-01

    We use high-resolution cosmological hydrodynamic simulations to study the angular momentum acquisition of gaseous halos around Milky-Way-sized galaxies. We find that cold mode accreted gas enters a galaxy halo with ∼70% more specific angular momentum than dark matter averaged over cosmic time (though with a very large dispersion). In fact, we find that all matter has a higher spin parameter when measured at accretion than when averaged over the entire halo lifetime, and is well characterized by λ ∼ 0.1, at accretion. Combined with the fact that cold flow gas spends a relatively short time (1-2 dynamical times) in the halo before sinking to the center, this naturally explains why cold flow halo gas has a specific angular momentum much higher than that of the halo and often forms ''cold flow disks.'' We demonstrate that the higher angular momentum of cold flow gas is related to the fact that it tends to be accreted along filaments.

  15. W UMa stars and angular momentum loss

    International Nuclear Information System (INIS)

    Vilhu, O.; Rahunen, T.

    1980-01-01

    The structure and evolution of W UMa stars is still unsolved although considerable progress has been achieved in recent years. The authors aim is to find out whether it is possible to obtain more extreme mass ratios, what is the angular momentum needed and what is the time scale. (Auth.)

  16. On the angular momentum in star formation

    International Nuclear Information System (INIS)

    Horedt, G.P.

    1978-01-01

    The author discusses the rotation of interstellar clouds which are in a stage immediately before star formation. Cloud collisions seem to be the principal cause of the observed rotation of interstellar clouds. The rotational motion of the clouds is strongly influenced by turbulence. Theories dealing with the resolution of the angular momentum problem in star formation are classified into five major groups. The old idea that the angular momentum of an interstellar cloud passes during star formation into the angular momentum of double star systems and/or circumstellar clouds, is developed. It is suggested that a rotating gas cloud contracts into a ring-like structure which fragments into self-gravitating subcondensations. By collisions and gas accretion these subcondensations accrete into binary systems surrounded by circumstellar clouds. Using some rough approximations the authors find analytical expressions for the semi-major axis of the binary system and for the density of the circumstellar clouds as a function of the initial density and of the initial angular velocity of an interstellar cloud. The obtained values are well within the observational limits. (Auth.)

  17. Variation in angular velocity and angular acceleration of a particle in rectilinear motion

    International Nuclear Information System (INIS)

    Mashood, K K; Singh, V A

    2012-01-01

    We discuss the angular velocity and angular acceleration associated with a particle in rectilinear motion with constant acceleration. The discussion was motivated by an observation that students and even teachers have difficulty in ascribing rotational motion concepts to a particle when the trajectory is a straight line. We present some details of our observations. A formal derivation of ω and α is presented which reveals ‘surprising’ and non-intuitive aspects, namely non-monotonic behaviour with an associated extremum. The special case of constant velocity is studied and we find that angular acceleration associated with it also has an extremum. We discuss a plausible source of difficulty. (paper)

  18. Two novel mixed-ligand complexes containing organosulfonate ligands.

    Science.gov (United States)

    Li, Mingtian; Huang, Jun; Zhou, Xuan; Fang, Hua; Ding, Liyun

    2008-07-01

    The structures reported herein, viz. bis(4-aminonaphthalene-1-sulfonato-kappaO)bis(4,5-diazafluoren-9-one-kappa(2)N,N')copper(II), [Cu(C(10)H(8)NO(3)S)(2)(C(11)H(6)N(2)O)(2)], (I), and poly[[[diaquacadmium(II)]-bis(mu-4-aminonaphthalene-1-sulfonato)-kappa(2)O:N;kappa(2)N:O] dihydrate], {[Cd(C(10)H(8)NO(3)S)(2)(H(2)O)(2)].2H(2)O}(n), (II), are rare examples of sulfonate-containing complexes where the anion does not fulfill a passive charge-balancing role, but takes an active part in coordination as a monodentate and/or bridging ligand. Monomeric complex (I) possesses a crystallographic inversion center at the Cu(II) atom, and the asymmetric unit contains one-half of a Cu atom, one complete 4-aminonaphthalene-1-sulfonate (ans) ligand and one 4,5-diazafluoren-9-one (DAFO) ligand. The Cu(II) atom has an elongated distorted octahedral coordination geometry formed by two O atoms from two monodentate ans ligands and by four N atoms from two DAFO molecules. Complex (II) is polymeric and its crystal structure is built up by one-dimensional chains and solvent water molecules. Here also the cation (a Cd(II) atom) lies on a crystallographic inversion center and adopts a slightly distorted octahedral geometry. Each ans anion serves as a bridging ligand linking two Cd(II) atoms into one-dimensional infinite chains along the [010] direction, with each Cd(II) center coordinated by four ans ligands via O and N atoms and by two aqua ligands. In both structures, there are significant pi-pi stacking interactions between adjacent ligands and hydrogen bonds contribute to the formation of two- and three-dimensional networks.

  19. Correcting ligands, metabolites, and pathways

    NARCIS (Netherlands)

    Ott, M.A.; Vriend, G.

    2006-01-01

    BACKGROUND: A wide range of research areas in bioinformatics, molecular biology and medicinal chemistry require precise chemical structure information about molecules and reactions, e.g. drug design, ligand docking, metabolic network reconstruction, and systems biology. Most available databases,

  20. Multichannel system for angular distribution measurements

    International Nuclear Information System (INIS)

    Burjan, V.; Kroha, V.; Putz, K.

    A description is given of the individual blocks of the spectrometric apparatus used for measuring the angular distribution of particle spectra and excitation functions of (d,p) reactions at an electrostatic accelerator and the U-120 M cyclotron, both operating at the Nuclear Physics Institute of the Czechoslovak Academy of Sciences at Rez. Main attention was devoted to attaining maximum energy resolution at a high measurement efficiency, this by installing 8 independent spectrometric chains allowing simultaneous measurement of angular distribution in 8 points of the beam. The semiconductor detectors were cooled to -40 degC to -60 degC, which significantly reduced the level of inherent detector noise. An energy resolution of 13 keV was attained using Tesla detectors at a particle energy of 11 MeV. A brief review of data processing and software is given. (B.S.)

  1. Quantum entanglement of high angular momenta.

    Science.gov (United States)

    Fickler, Robert; Lapkiewicz, Radek; Plick, William N; Krenn, Mario; Schaeff, Christoph; Ramelow, Sven; Zeilinger, Anton

    2012-11-02

    Single photons with helical phase structures may carry a quantized amount of orbital angular momentum (OAM), and their entanglement is important for quantum information science and fundamental tests of quantum theory. Because there is no theoretical upper limit on how many quanta of OAM a single photon can carry, it is possible to create entanglement between two particles with an arbitrarily high difference in quantum number. By transferring polarization entanglement to OAM with an interferometric scheme, we generate and verify entanglement between two photons differing by 600 in quantum number. The only restrictive factors toward higher numbers are current technical limitations. We also experimentally demonstrate that the entanglement of very high OAM can improve the sensitivity of angular resolution in remote sensing.

  2. Behavior of nuclei at high angular momentum

    International Nuclear Information System (INIS)

    Stephens, F.S.

    1982-07-01

    The present report begins with a brief overview of nuclear shapes and level structures at high-spin values. The new spectroscopy associated with angular-momentum alignments is described, and some of the exciting possibilities of this spectroscopy are explored. Nuclear moments of inertia are discussed and a somewhat different one is defined, together with a method for measuring it and some early results. Finally a few comments on the future prospects for high-spin physics are offered

  3. Chirality and angular momentum in optical radiation

    Science.gov (United States)

    Coles, Matt M.; Andrews, David L.

    2012-06-01

    This paper develops, in precise quantum electrodynamic terms, photonic attributes of the “optical chirality density,” one of several measures long known to be conserved quantities for a vacuum electromagnetic field. The analysis lends insights into some recent interpretations of chiroptical experiments, in which this measure, and an associated chirality flux, have been treated as representing physically distinctive “superchiral” phenomena. In the fully quantized formalism the chirality density is promoted to operator status, whose exploration with reference to an arbitrary polarization basis reveals relationships to optical angular momentum and helicity operators. Analyzing multimode beams with complex wave-front structures, notably Laguerre-Gaussian modes, affords a deeper understanding of the interplay between optical chirality and optical angular momentum. By developing theory with due cognizance of the photonic character of light, it emerges that only the spin-angular momentum of light is engaged in such observations. Furthermore, it is shown that these prominent measures of the helicity of chiral electromagnetic radiation have a common basis in differences between the populations of optical modes associated with angular momenta of opposite sign. Using a calculation of the rate of circular dichroism as an example, with coherent states to model the electromagnetic field, it is discovered that two terms contribute to the differential effect. The primary contribution relates to the difference in left- and right-handed photon populations; the only other contribution, which displays a sinusoidal distance dependence corresponding to the claim of nodal enhancements, is connected with the quantum photon number-phase uncertainty relation. From the full analysis, it appears that the term “superchiral” can be considered redundant.

  4. Coherent Control of Photoelectron Wavepacket Angular Interferograms

    OpenAIRE

    Hockett, Paul; Wollenhaupt, Matthias; Baumert, Thomas

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the cohere...

  5. Adaptive Angular Sampling for SPECT Imaging

    OpenAIRE

    Li, Nan; Meng, Ling-Jian

    2011-01-01

    This paper presents an analytical approach for performing adaptive angular sampling in single photon emission computed tomography (SPECT) imaging. It allows for a rapid determination of the optimum sampling strategy that minimizes image variance in regions-of-interest (ROIs). The proposed method consists of three key components: (a) a set of close-form equations for evaluating image variance and resolution attainable with a given sampling strategy, (b) a gradient-based algor...

  6. Angular distribution of laser ablation plasma

    International Nuclear Information System (INIS)

    Kondo, K.; Kanesue, T.; Dabrowski, R.; Okamura, M.

    2010-01-01

    An expansion of a laser induced plasma is fundamental and important phenomena in a laser ion source. To understand the expanding direction, an array of Langmuir probes were employed. The chosen ion for the experiment was Ag 1+ which was created by a second harmonics of a Nd-YAG laser. The obtained angular distribution was about ±10 degree. This result also indicates a proper positioning of a solenoid magnet which enhances ion beam current.

  7. Coincident-inclusive electrofission angular correlations

    International Nuclear Information System (INIS)

    Arruda Neto, J.D.T.

    1983-08-01

    A method for the joint analysis of coincident and inclusive electrofission data, in order to minimize effects of the model dependence of data interpretation, is developed. Explicit calculations of the (e,e'f) angular correlations are presented. The potentialities of the method to the study of sub- and near-barrier properties of the fission process, and to the study of the giant resonances fission mode, are discussed. (Author) [pt

  8. Positron annihilation and perturbed angular correlation studies of radiation damage

    International Nuclear Information System (INIS)

    Zhu Jiazheng; Li Anli; Xu Yongjun; Wang Zhiqiang; Zhou Dongmei; Zheng Yongnan; Zhu Shengyun; Iwata, T.

    2002-01-01

    The positron annihilation and perturbed angular correlation techniques have been employed to study radiation damage in Si and Nb. The results obtained by the positron annihilation are consistent with those given by the perturbed angular correlation

  9. Sorting and quantifying orbital angular momentum of laser beams

    CSIR Research Space (South Africa)

    Schulze, C

    2013-10-01

    Full Text Available We present a novel tool for sorting the orbital angular momentum and to determine the orbital angular momentum density of laser beams, which is based on the use of correlation filters....

  10. High Angular Momentum Rydberg Wave Packets

    Science.gov (United States)

    Wyker, Brendan

    2011-12-01

    High angular momentum Rydberg wave packets are studied. Application of carefully tailored electric fields to low angular momentum, high- n (n ˜ 300) Rydberg atoms creates coherent superpositions of Stark states with near extreme values of angular momentum, ℓ. Wave packet components orbit the parent nucleus at rates that depend on their energy, leading to periods of localization and delocalization as the components come into and go out of phase with each other. Monitoring survival probability signals in the presence of position dependent probing leads to observation of characteristic oscillations based on the composition of the wave packet. The discrete nature of electron energy levels is observed through the measurement of quantum revivals in the wave packet localization signal. Time-domain spectroscopy of these signals allows determination of both the population and phase of individual superposition components. Precise manipulation of wave packets is achieved through further application of pulsed electric fields. Decoherence effects due to background gas collisions and electrical noise are also detailed. Quantized classical trajectory Monte-Carlo simulations are introduced and agree remarkably well with experimental results.

  11. Verification of angular dependence in MOSFET detector

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Clayton H.; Shorto, Julian M.B.; Siqueira, Paulo T.D.; Nunes, Maíra G.; Silva Junior, Iremar A.; Yoriyaz, Hélio, E-mail: chsouza@usp.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2017-07-01

    In vivo dosimetry is an essential tool for quality assurance programs, being a procedure commonly performed with thermoluminescent dosimeters (TLDs) or diodes. However, a type of dosimeter that has increasing popularity in recent years is the metal-oxide-semiconductor field effect transistor (MOSFET) detector. MOSFET dosimeters fulfill all the necessary characteristics to realize in vivo dosimetry since it has a small size, good precision and feasibility of measurement, as well as easy handling. Nevertheless, its true differential is to allow reading of the dose in real time, enabling immediate intervention in the correction of physical parameters deviations and anticipation of small anatomical changes in a patient during treatment. In order for MOSFET dosimeter to be better accepted in clinical routine, information reporting performance should be available frequently. For this reason, this work proposes to verify reproducibility and angular dependence of a standard sensitivity MOSFET dosimeter (TN-502RD-H) for Cs-137 and Co-60 sources. Experimental data were satisfactory and MOSFET dosimeter presented a reproducibility of 3.3% and 2.7% (1 SD) for Cs-137 and Co-60 sources, respectively. In addition, an angular dependence of up to 6.1% and 16.3% for both radioactive sources, respectively. It is conclusive that MOSFET dosimeter TN-502RD-H has satisfactory reproducibility and a considerable angular dependence, mainly for the Co-60 source. This means that although precise measurements, special attention must be taken for applications in certain anatomical regions in a patient. (author)

  12. Physics from angular projection of rectangular grids

    International Nuclear Information System (INIS)

    Singh, Ashmeet

    2015-01-01

    In this paper, we present a mathematical model for the angular projection of a rectangular arrangement of points in a grid. This simple yet interesting, problem has both scholarly value and applications for data extraction techniques to study the physics of various systems. Our work may help undergraduate students to understand subtle points in the angular projection of a grid and describes various quantities of interest in the projection with completeness and sufficient rigour. We show that for certain angular ranges, the projection has non-distinctness, and calculate the details of such angles, and correspondingly, the number of distinct points and the total projected length. We focus on interesting trends obtained for the projected length of the grid elements and present a simple application of the model to determine the geometry of an unknown grid whose spatial extensions are known, using measurement of the grid projection at two angles only. Towards the end, our model is shown to have potential applications in various branches of physical sciences, including crystallography, astrophysics, and bulk properties of materials. (paper)

  13. The Cosmology Large Angular Scale Surveyor (CLASS)

    Science.gov (United States)

    Harrington, Kathleen; Marriange, Tobias; Aamir, Ali; Appel, John W.; Bennett, Charles L.; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T.; Colazo, Felipe; hide

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from in ation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145/217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad frequency range, large sky coverage, control over systematics, and high sensitivity, CLASS will observe the reionization and recombination peaks of the CMB E- and B-mode power spectra. CLASS will make a cosmic variance limited measurement of the optical depth to reionization and will measure or place upper limits on the tensor-to-scalar ratio, r, down to a level of 0.01 (95% C.L.).

  14. The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Harrington, Kathleen; Marriage, Tobias; Ali, Aamir; Appel, John; Bennett, Charles; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T.; Colazo, Felipe; hide

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from inflation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad frequency range, large sky coverage, control over systematics, and high sensitivity, CLASS will observe the reionization and recombination peaks of the CMB E- and B-mode power spectra. CLASS will make a cosmic variance limited measurement of the optical depth to reionization and will measure or place upper limits on the tensor-to-scalar ratio, r, down to a level of 0.01 (95% C.L.).

  15. A neural circuit for angular velocity computation

    Directory of Open Access Journals (Sweden)

    Samuel B Snider

    2010-12-01

    Full Text Available In one of the most remarkable feats of motor control in the animal world, some Diptera, such as the housefly, can accurately execute corrective flight maneuvers in tens of milliseconds. These reflexive movements are achieved by the halteres, gyroscopic force sensors, in conjunction with rapidly-tunable wing-steering muscles. Specifically, the mechanosensory campaniform sensilla located at the base of the halteres transduce and transform rotation-induced gyroscopic forces into information about the angular velocity of the fly's body. But how exactly does the fly's neural architecture generate the angular velocity from the lateral strain forces on the left and right halteres? To explore potential algorithms, we built a neuro-mechanical model of the rotation detection circuit. We propose a neurobiologically plausible method by which the fly could accurately separate and measure the three-dimensional components of an imposed angular velocity. Our model assumes a single sign-inverting synapse and formally resembles some models of directional selectivity by the retina. Using multidimensional error analysis, we demonstrate the robustness of our model under a variety of input conditions. Our analysis reveals the maximum information available to the fly given its physical architecture and the mathematics governing the rotation-induced forces at the haltere's end knob.

  16. Continuous particle spectra and their angular distributions

    International Nuclear Information System (INIS)

    Sastry, Ch.V.; Jain, R.K.; Rama Rao, J.; Ernst, J.; Machner, H.

    1996-01-01

    The angular distribution of continuous particle spectra in pre-equilibrium reactions is still an unsolved problem, particularly so at forward angles. In the present work, the angular distributions of alpha particles emitted in (α, α',x) reactions in the target elements gold and rhodium have been studied in detail. Alpha particle beams of energy 60 MeV from the Variable Energy Cyclotron of Calcutta were used in these experiments. The theoretical calculations were done using an extended exciton model of Kalbach incorporated into the Computer Code PRECO-D2. The formalism used in the exciton model was modified to include division of pre equilibrium cross section into multi-step direct (MSD) and multi-step compound (MSC) components. These MSD and MSC cross sections were used to calculate the angular distributions in terms of Legendre polynomials whose coefficients are given by simple phenomenological relations. Even with a reasonable set of parameters, the agreement between theory and experiment was far from satisfactory at forward angles. Similar conclusion was also drawn in the case of continuous particle spectra of deuterons in (d, d'x) reactions at 25 MeV in various targets. (author). 10 refs., 2 figs

  17. Verification of angular dependence in MOSFET detector

    International Nuclear Information System (INIS)

    Souza, Clayton H.; Shorto, Julian M.B.; Siqueira, Paulo T.D.; Nunes, Maíra G.; Silva Junior, Iremar A.; Yoriyaz, Hélio

    2017-01-01

    In vivo dosimetry is an essential tool for quality assurance programs, being a procedure commonly performed with thermoluminescent dosimeters (TLDs) or diodes. However, a type of dosimeter that has increasing popularity in recent years is the metal-oxide-semiconductor field effect transistor (MOSFET) detector. MOSFET dosimeters fulfill all the necessary characteristics to realize in vivo dosimetry since it has a small size, good precision and feasibility of measurement, as well as easy handling. Nevertheless, its true differential is to allow reading of the dose in real time, enabling immediate intervention in the correction of physical parameters deviations and anticipation of small anatomical changes in a patient during treatment. In order for MOSFET dosimeter to be better accepted in clinical routine, information reporting performance should be available frequently. For this reason, this work proposes to verify reproducibility and angular dependence of a standard sensitivity MOSFET dosimeter (TN-502RD-H) for Cs-137 and Co-60 sources. Experimental data were satisfactory and MOSFET dosimeter presented a reproducibility of 3.3% and 2.7% (1 SD) for Cs-137 and Co-60 sources, respectively. In addition, an angular dependence of up to 6.1% and 16.3% for both radioactive sources, respectively. It is conclusive that MOSFET dosimeter TN-502RD-H has satisfactory reproducibility and a considerable angular dependence, mainly for the Co-60 source. This means that although precise measurements, special attention must be taken for applications in certain anatomical regions in a patient. (author)

  18. Diverse assemblies of the (4,4) grid layers exemplified in Zn(II)/Co(II) coordination polymers with dual linear ligands

    International Nuclear Information System (INIS)

    Liu, Guang-Zhen; Li, Xiao-Dong; Xin, Ling-Yun; Li, Xiao-Ling; Wang, Li-Ya

    2013-01-01

    Diverse (4,4) grid layers are exemplified in five two-dimensional coordination polymers with dual µ 2 -bridged ligands, namely, ([Zn(cbaa)(bpp)]·H 2 O) n (1), [Zn 2 (cbaa) 2 (bpy)] n (2), [Co 2 (cbaa) 2 (bpp) 2 ] n (3), [Co(cbaa)(bpp)] n (4), and [Co(bdaa)(bpp)(H 2 O) 2 ] n (5) (H 2 cbaa=4-carboxybenzeneacetic acid, bpp=1,3-di(4-pyridyl)propane, bpy=4,4′-bipyridyl, and H 2 bdaa=1,4-benzenediacrylic acid). For 1, two (4,4) grid layers with [ZnN 2 O 2 ] tetrahedron as the node are held together by lattice water forming a H-bonding bilayer. Individual (4,4) grid layer in 2 is based on (Zn 2 (OCO) 4 ) paddlewheel unit as the node. Two (4,4) grid layers with (Co 2 O(OCO) 2 ) dimer as the node are covalently interconnected by organic ligands affording a thick bilayer of 3 with new framework topology. The different entanglements between two coincident (4,4) grid layers with [CoN 2 O 4 ] octahedron as the node leads to two 2D→2D interpenetrated structures for 4 and 5. Furthermore, fluorescent properties of 1 and 2 as well as magnetic properties of 3 are investigated. - Graphical abstract: Diverse assemblies of the (4,4) grid layers with different network nodes forms five coordination polymers that are well characterized by IR, TGA, element analysis, fluorescent and magnetic measurement. - Highlights: • Diverse assemblies of the (4,4) grid layers with different structural units as the nodes. • A new topology type with the uninodal 6-connected net of (4 12 .5 2 .6) is found. • Intense fluorescence emissions with a rare blue-shift of 55 nm compared to free carboxylate ligand

  19. Natural roller bearing fault detection by angular measurement of true instantaneous angular speed

    Science.gov (United States)

    Renaudin, L.; Bonnardot, F.; Musy, O.; Doray, J. B.; Rémond, D.

    2010-10-01

    The challenge in many production activities involving large mechanical devices like power transmissions consists in reducing the machine downtime, in managing repairs and in improving operating time. Most online monitoring systems are based on conventional vibration measurement devices for gear transmissions or bearings in mechanical components. In this paper, we propose an alternative way of bearing condition monitoring based on the instantaneous angular speed measurement. By the help of a large experimental investigation on two different applications, we prove that localized faults like pitting in bearing generate small angular speed fluctuations which are measurable with optical or magnetic encoders. We also emphasize the benefits of measuring instantaneous angular speed with the pulse timing method through an implicit angular sampling which ensures insensitivity to speed fluctuation. A wide range of operating conditions have been tested for the two applications with varying speed, load, external excitations, gear ratio, etc. The tests performed on an automotive gearbox or on actual operating vehicle wheels also establish the robustness of the proposed methodology. By the means of a conventional Fourier transform, angular frequency channels kinematically related to the fault periodicity show significant magnitude differences related to the damage severity. Sideband effects are evidently seen when the fault is located on rotating parts of the bearing due to load modulation. Additionally, slip effects are also suspected to be at the origin of enlargement of spectrum peaks in the case of double row bearings loaded in a pure radial direction.

  20. Angular dispersion and deflection function for heavy ion elastic scattering

    International Nuclear Information System (INIS)

    Bai Zhen; Han Jianlong; Hu Zhengguo; Chinese Academy of Sciences, Beijing

    2007-01-01

    The differential cross sections for elastic scattering products of 17 F on 208 Pb have been measured. The angular dispersion plots of ln(dσ/dθ) versus θ 2 are obtained from the angular distribution of the elastic scattering differential cross sections. Systematical analysis on the angular dispersion for the available experimental data indicates that there is an angular dispersion turning angle at forward angular range within the grazing angle. This turning angle can be clarified as nuclear rainbow in classical deflection function. The exotic behaviour of the nuclear rainbow angle offers a new probe to investigate the halo and skin phenomena. (authors)

  1. Contrasts between the vibronic contributions in the tris-(2,2'-bipyridyl)osmium(II) emission spectrum and the implications of resonance-Raman parameters.

    Science.gov (United States)

    Ondongo, Onduru S; Endicott, John F

    2009-04-06

    The emission spectrum of the tris-(2,2'-bipyridine)osmium(II) metal-to-ligand charge transfer (MLCT) excited-state frozen solution at 77 K differs qualitatively from that expected based on its reported resonance-Raman (rR) parameters in that (1) the dominant vibronic contributions to the emission spectrum are in the low frequency regime (corresponding to nuclear displacements in largely to metal-ligand vibrational modes) and these contributions are negligible in the rR; and (2) the amplitude of the emission sideband components that correspond to envelopes of largely bpy centered vibrational modes is about 40% of that expected (relative to the amplitude observed for the band origin) for a simple vibronic progression in these modes. The distortions in low frequency vibrational modes are attributable to configurational mixing between metal centered (LF) and MLCT excited states, and the small amplitudes of the bpy-mode vibronic components may be a consequence of some intrinsic differences of the distortions of the (3)MLCT and (1)MLCT excited states such as the zero-field splitting of the (3)MLCT excited state and the different distortions of these excited-state components.

  2. Crystal structure of tetraaqua(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′iron(II sulfate

    Directory of Open Access Journals (Sweden)

    Yamine Belamri

    2014-12-01

    Full Text Available In the title compound, [Fe(C12H12N2(H2O4]SO4, the central FeII ion is coordinated by two N atoms from the 5,5′-dimethyl-2,2′-bipyridine ligand and four water O atoms in a distorted octahedral geometry. The Fe—O coordination bond lengths vary from 2.080 (3 to 2.110 (3 Å, while the two Fe—N coordination bonds have practically identical lengths [2.175 (3 and 2.177 (3 Å]. The chelating N—Fe—N angle of 75.6 (1° shows the largest deviation from an ideal octahedral geometry; the other coordination angles deviate from ideal values by 0.1 (1 to 9.1 (1°. O—H...O hydrogen bonding between the four aqua ligands of the cationic complex and four O-atom acceptors of the anion leads to the formation of layers parallel to the ab plane. Neighbouring layers further interact by means of C—H...O and π–π interactions involving the laterally positioned bipyridine rings. The perpendicular distance between π–π interacting rings is 3.365 (2 Å, with a centroid–centroid distance of 3.702 (3 Å.

  3. Angular Momentum and Galaxy Formation Revisited

    Science.gov (United States)

    Romanowsky, Aaron J.; Fall, S. Michael

    2012-12-01

    Motivated by a new wave of kinematical tracers in the outer regions of early-type galaxies (ellipticals and lenticulars), we re-examine the role of angular momentum in galaxies of all types. We present new methods for quantifying the specific angular momentum j, focusing mainly on the more challenging case of early-type galaxies, in order to derive firm empirical relations between stellar j sstarf and mass M sstarf (thus extending earlier work by Fall). We carry out detailed analyses of eight galaxies with kinematical data extending as far out as 10 effective radii, and find that data at two effective radii are generally sufficient to estimate total j sstarf reliably. Our results contravene suggestions that ellipticals could harbor large reservoirs of hidden j sstarf in their outer regions owing to angular momentum transport in major mergers. We then carry out a comprehensive analysis of extended kinematic data from the literature for a sample of ~100 nearby bright galaxies of all types, placing them on a diagram of j sstarf versus M sstarf. The ellipticals and spirals form two parallel j sstarf-M sstarf tracks, with log-slopes of ~0.6, which for the spirals are closely related to the Tully-Fisher relation, but for the ellipticals derives from a remarkable conspiracy between masses, sizes, and rotation velocities. The ellipticals contain less angular momentum on average than spirals of equal mass, with the quantitative disparity depending on the adopted K-band stellar mass-to-light ratios of the galaxies: it is a factor of ~3-4 if mass-to-light ratio variations are neglected for simplicity, and ~7 if they are included. We decompose the spirals into disks and bulges and find that these subcomponents follow j sstarf-M sstarf trends similar to the overall ones for spirals and ellipticals. The lenticulars have an intermediate trend, and we propose that the morphological types of galaxies reflect disk and bulge subcomponents that follow separate, fundamental j sstarf

  4. LigandRFs: random forest ensemble to identify ligand-binding residues from sequence information alone

    KAUST Repository

    Chen, Peng; Huang, Jianhua Z; Gao, Xin

    2014-01-01

    Protein-ligand binding is important for some proteins to perform their functions. Protein-ligand binding sites are the residues of proteins that physically bind to ligands. Despite of the recent advances in computational prediction

  5. The angular momentum of isolated white dwarfs

    Directory of Open Access Journals (Sweden)

    Brassard P.

    2013-03-01

    Full Text Available This is a very brief report on an ongoing program aimed at mapping the internal rotation profiles of stars through asteroseismology. Three years ago, we developed and applied successfully a new technique to the pulsating GW Vir white dwarf PG 1159−035, and were able to infer that it rotates very slowly and rigidly over some 99% of its mass. We applied the same approach to the three other GW Vir pulsators with available rotational splitting data, and found similar results. We discuss the implications of these findings on the question of the angular momentum of white dwarfs resulting from single star evolution.

  6. Projection of angular momentum via linear algebra

    Science.gov (United States)

    Johnson, Calvin W.; O'Mara, Kevin D.

    2017-12-01

    Projection of many-body states with good angular momentum from an initial state is usually accomplished by a three-dimensional integral. We show how projection can instead be done by solving a straightforward system of linear equations. We demonstrate the method and give sample applications to 48Cr and 60Fe in the p f shell. This new projection scheme, which is competitive against the standard numerical quadrature, should also be applicable to other quantum numbers such as isospin and particle number.

  7. Angular Position Tracking Control of a Quadcopter

    OpenAIRE

    T. V. Glazkov; A. E. Golubev

    2017-01-01

    The paper dwells on tracking the quad-copter angular position with desired quality parameters of transient processes. The aerial vehicle is considered as a rigid body with six degrees of freedom.  A full rigid body quad-copter mathematical model is considered without the assumption of smallness of the Euler angles.Among the most well known methods of non-linear stabilization are feedback linearization and backstepping. The backstepping approach allows us to have an effective solution of the s...

  8. Optical communication beyond orbital angular momentum

    CSIR Research Space (South Africa)

    Trichili, A

    2016-06-01

    Full Text Available :27674 | DOI: 10.1038/srep27674 www.nature.com/scientificreports Optical communication beyond orbital angular momentum Abderrahmen Trichili1, Carmelo Rosales-Guzmán2, Angela Dudley2,3, Bienvenu Ndagano2, Amine Ben Salem1, Mourad Zghal1,4 & Andrew Forbes2 Mode....rosalesguzman@wits.ac.za) received: 29 March 2016 Accepted: 24 May 2016 Published: 10 June 2016 OPEN www.nature.com/scientificreports/ 2Scientific RepoRts | 6:27674 | DOI: 10.1038/srep27674 Results Consider a LG mode in cylindrical coordinates, at its waist plane (z = 0), described...

  9. Angular momentum in multi-step photoionization

    International Nuclear Information System (INIS)

    Yoshida, Tadashi; Adachi, Hajime; Kuwako, Akira; Nittoh, Koichi; Araki, Yoshio; Watanabe, Takashi; Yoguchi, Itaru.

    1995-01-01

    The effect of the angular momenta on the multi-step laser-ionization efficiency was investigated numerically for cases with and without the hyperfine interactions. For either cases the ionization efficiency proved to depend appreciably on the values of J in the excitation ladder. In this respect, we elaborated a simple and efficient method of determining J, which was based on the laser polarization dependence of the excitation rate. Application of this method to a couple of real excitation ladders proved its usefulness and reliability. (author)

  10. Statistical analysis of angular correlation measurements

    International Nuclear Information System (INIS)

    Oliveira, R.A.A.M. de.

    1986-01-01

    Obtaining the multipole mixing ratio, δ, of γ transitions in angular correlation measurements is a statistical problem characterized by the small number of angles in which the observation is made and by the limited statistic of counting, α. The inexistence of a sufficient statistics for the estimator of δ, is shown. Three different estimators for δ were constructed and their properties of consistency, bias and efficiency were tested. Tests were also performed in experimental results obtained in γ-γ directional correlation measurements. (Author) [pt

  11. Time-dependent angularly averaged inverse transport

    International Nuclear Information System (INIS)

    Bal, Guillaume; Jollivet, Alexandre

    2009-01-01

    This paper concerns the reconstruction of the absorption and scattering parameters in a time-dependent linear transport equation from knowledge of angularly averaged measurements performed at the boundary of a domain of interest. Such measurement settings find applications in medical and geophysical imaging. We show that the absorption coefficient and the spatial component of the scattering coefficient are uniquely determined by such measurements. We obtain stability results on the reconstruction of the absorption and scattering parameters with respect to the measured albedo operator. The stability results are obtained by a precise decomposition of the measurements into components with different singular behavior in the time domain

  12. Angular momentum effects in subbarrier fusion

    International Nuclear Information System (INIS)

    Halbert, M.L.; Beene, J.R.; Hensley, D.C.; Honkanen, K.; Semkow, T.M.; Abenante, V.; Sarantites, D.G.; Li, Z.

    1987-01-01

    The authors discuss angular-momentum distributions σ l for the compound nucleus 164 Yb deduced from measurements of γ-ray multiplicity for all significant evaporation residues from fusion of 64 Ni and 100 Mo and 16 O + 148 Sm. At the lowest bombarding energies the σ l extend to higher l values than do predictions that include coupling of the principal inelastic channels, even if the coupling strengths are increased to match the experimental excitation function. Likewise, σ l from an energy-dependent real potential fitted to the excitation function fails to reproduce the experimental σ l distribution. No effects attributed to superdeformation were observed

  13. Energy flow in angularly dispersive optical systems

    International Nuclear Information System (INIS)

    Ware, M.; Dibble, W. E.; Glasgow, S. A.; Peatross, J.

    2001-01-01

    Light-pulse propagation in angularly dispersive systems is explored in the context of a center-of-mass definition of energy arrival time. In this context the time of travel is given by a superposition of group delays weighted by the spectral content of the pulse. With this description the time of travel from one point to the next for a pulse is found to be completely determined by the spectral content, independent of the state of chirp. The effect of sensor orientation on arrival time is also considered. [copyright] 2001 Optical Society of America

  14. Angular Speed of a Compact Disc

    Science.gov (United States)

    Sawicki, Mikolaj ``Mik''

    2006-09-01

    A spinning motion of a compact disc in a CD player offers an interesting and challenging problem in rotational kinematics with a nonconstant angular acceleration that can be incorporated into a typical introductory physics class for engineers and scientists. It can be used either as an example presented during the lecture, emphasizing application of calculus, or as a homework assignment that could be handled easily with the help of a spreadsheet, thus eliminating the calculus aspect altogether. I tried both approaches, and the spreadsheet study was favored by my students.

  15. A proposed measurement of optical orbital and spin angular momentum and its implications for photon angular momentum

    Science.gov (United States)

    Leader, Elliot

    2018-04-01

    The expression for the total angular momentum carried by a laser optical vortex beam, splits, in the paraxial approximation, into two terms which seem to represent orbital and spin angular momentum respectively. There are, however, two very different competing versions of the formula for the spin angular momentum, one based on the use of the Poynting vector, as in classical electrodynamics, the other related to the canonical expression for the angular momentum which occurs in Quantum Electrodynamics. I analyze the possibility that a sufficiently sensitive optical measurement could decide which of these corresponds to the actual physical angular momentum carried by the beam.

  16. Structural Diversity of Metallosupramolecular Assemblies Based on the Bent Bridging Ligand 4,4′-Dithiodipyridine

    Directory of Open Access Journals (Sweden)

    Rüdiger W. Seidel

    2013-05-01

    Full Text Available 4,4′-Dithiodipyridine (dtdp, also termed 4,4′-dipyridyldisulfide, is a bridging ligand of the 4,4′-bipyridine type. The introduction of the disulfide moiety inevitably leads to a relatively rigid angular structure, which exhibits axial chirality. More than 90 metal complexes containing the dtdp ligand have been crystallographically characterised until now. This review focuses on the preparation and structural diversity of discrete and polymeric metallosupramolecular assemblies constructed from dtdp as bridging ligands. These encompass metallamacrocycles with M2L2 topology and coordination polymers with periodicity in one or two dimensions. One-dimensional coordination polymers represent the vast majority of the metallosupramolecular structures obtained from dtdp. These include repeated rhomboids, zigzag, helical and arched chains among other types. In this contribution, we make an attempt to provide a comprehensive account of the structural data that are currently available for metallosupramolecular assemblies based on the bent bridging ligand dtdp.

  17. The determination of psilocin and psilocybin in hallucinogenic mushrooms by HPLC utilizing a dual reagent acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection system.

    Science.gov (United States)

    Anastos, Nicole; Lewis, Simon W; Barnett, Neil W; Sims, D Noel

    2006-01-01

    This paper describes a procedure for the determination of psilocin and psilocybin in mushroom extracts using high-performance liquid chromatography with postcolumn chemiluminescence detection. A number of extraction methods for psilocin and psilocybin in hallucinogenic mushrooms were investigated, with a simple methanolic extraction being found to be most effective. Psilocin and psilocybin were extracted from a variety of hallucinogenic mushrooms using methanol. The analytes were separated on a C12 column using a (95:5% v/v) methanol:10 mM ammonium formate, pH 3.5 mobile phase with a run time of 5 min. Detection was realized through a dual reagent chemiluminescence detection system of acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II). The chemiluminescence detection system gave improved detectability when compared with UV absorption at 269 nm, with detection limits of 1.2 x 10(-8) and 3.5 x 10(-9) mol/L being obtained for psilocin and psilocybin, respectively. The procedure was applied to the determination of psilocin and psilocybin in three Australian species of hallucinogenic mushroom.

  18. Rosetta Ligand docking with flexible XML protocols.

    Science.gov (United States)

    Lemmon, Gordon; Meiler, Jens

    2012-01-01

    RosettaLigand is premiere software for predicting how a protein and a small molecule interact. Benchmark studies demonstrate that 70% of the top scoring RosettaLigand predicted interfaces are within 2Å RMSD from the crystal structure [1]. The latest release of Rosetta ligand software includes many new features, such as (1) docking of multiple ligands simultaneously, (2) representing ligands as fragments for greater flexibility, (3) redesign of the interface during docking, and (4) an XML script based interface that gives the user full control of the ligand docking protocol.

  19. Orbital angular momentum of general astigmatic modes

    International Nuclear Information System (INIS)

    Visser, Jorrit; Nienhuis, Gerard

    2004-01-01

    We present an operator method to obtain complete sets of astigmatic Gaussian solutions of the paraxial wave equation. In case of general astigmatism, the astigmatic intensity and phase distribution of the fundamental mode differ in orientation. As a consequence, the fundamental mode has a nonzero orbital angular momentum, which is not due to phase singularities. Analogous to the operator method for the quantum harmonic oscillator, the corresponding astigmatic higher-order modes are obtained by repeated application of raising operators on the fundamental mode. The nature of the higher-order modes is characterized by a point on a sphere, in analogy with the representation of polarization on the Poincare sphere. The north and south poles represent astigmatic Laguerre-Gaussian modes, similar to circular polarization on the Poincare sphere, while astigmatic Hermite-Gaussian modes are associated with points on the equator, analogous to linear polarization. We discuss the propagation properties of the modes and their orbital angular momentum, which depends on the degree of astigmatism and on the location of the point on the sphere

  20. [Sensitivity of four representative angular cephalometric measures].

    Science.gov (United States)

    Xü, T; Ahn, J; Baumrind, S

    2000-05-01

    Examined the sensitivity of four representative cephalometric angles to the detection of different vectors of craniofacial growth. Landmark coordinate data from a stratified random sample of 48 adolescent subjects were used to calculate conventional values for changes between the pretreatment and end-of-treatment lateral cephalograms. By modifying the end-of-treatment coordinate values appropriately, the angular changes could be recalculated reflecting three hypothetical situations: Case 1. What if there were no downward landmark displacement between timepoints? Case 2. What if there were no forward landmark displacement between timepoints? Case 3. What if there were no Nasion change? These questions were asked for four representative cephalometric angles: SNA, ANB, NAPg and UI-SN. For Case 1, the associations (r) between the baseline and the modified measure for the three angles were very highly significant (P < 0.001) with r2 values no lower than 0.94! For Case 2, however, the associations were much weaker and no r value reached significance. These angular measurements are less sensitive for measuring downward landmark displacement than they are for measuring forward landmark displacement.

  1. Electromagnetic angular positioner based on DC micromotor

    Directory of Open Access Journals (Sweden)

    Bodnicki Maciej

    2018-01-01

    Full Text Available The presented works concerned launching of an angular positioner powered by an electromagnetic actuator, designed for performing angular micromovements within a range of few microradians. The principle of operation is based on balancing the electromagnetic torque of the motor with a torque that is twisting a compliant element. As electrodynamic actuators have no distinguished controlled positions, therefore in typical positioning systems desired positions are obtained applying a closed-loop position control. Usually, such systems employ also a feedback (dumping related to velocity of the moving elements, what simplifies forming of dynamics of the system. The design of the physical model employs a DC micromotor, whose rotor is coupled with a torsional torquemeter. A feedback signal is generated by resistive strain gauges. The paper presents a mathematical model of the positioning system, results of simulation study as well as results of experimental study. The simulation study indicates that it is possible to select such design features and such type of the micoromotor that a high dynamics of positioning is ensured.

  2. Practical scaling law for photoelectron angular distributions

    International Nuclear Information System (INIS)

    Guo Dongsheng; Zhang Jingtao; Xu Zhizhan; Li Xiaofeng; Fu Panming; Freeman, R.R.

    2003-01-01

    A practical scaling law that predicts photoelectron angular distributions (PADs) is derived using angular distribution formulas which explicitly contain spontaneous emission. The scaling law is used to analyze recent PAD measurements in above-threshold ionization, and to predict results of future experiments. Our theoretical and numerical studies show that, in the non-relativistic regime and long-wavelength approximation, the shapes of PADs are determined by only three dimensionless numbers: (1) u p ≡U p /(ℎ/2π)ω, the ponderomotive number (ponderomotive energy in units of laser photon energy); (2) ε b ≡E b /(ℎ/2π)ω, the binding number (atomic binding energy in units of the laser photon energy); (3) j, the absorbed-photon number. The scaling law is shown to be useful in predictions of results from strong-field Kapitza-Dirac effect measurements; specifically, the application of this scaling law to recently reported Kapitza-Dirac diffraction is discussed. Possible experimental tests to verify the scaling law are suggested

  3. The Cosmology Large Angular Scale Surveyor (CLASS)

    Science.gov (United States)

    Cleary, Joseph

    2018-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an array of four telescopes designed to measure the polarization of the Cosmic Microwave Background. CLASS aims to detect the B-mode polarization from primordial gravitational waves predicted by cosmic inflation theory, as well as the imprint left by reionization upon the CMB E-mode polarization. This will be achieved through a combination of observing strategy and state-of-the-art instrumentation. CLASS is observing 70% of the sky to characterize the CMB at large angular scales, which will measure the entire CMB power spectrum from the reionization peak to the recombination peak. The four telescopes operate at frequencies of 38, 93, 145, and 217 GHz, in order to estimate Galactic synchrotron and dust foregrounds while avoiding atmospheric absorption. CLASS employs rapid polarization modulation to overcome atmospheric and instrumental noise. Polarization sensitive cryogenic detectors with low noise levels provide CLASS the sensitivity required to constrain the tensor-to-scalar ratio down to levels of r ~ 0.01 while also measuring the optical depth the reionization to sample-variance levels. These improved constraints on the optical depth to reionization are required to pin down the mass of neutrinos from complementary cosmological data. CLASS has completed a year of observations at 38 GHz and is in the process of deploying the rest of the telescope array. This poster provides an overview and update on the CLASS science, hardware and survey operations.

  4. Inefficient Angular Momentum Transport in Accretion Disk Boundary Layers: Angular Momentum Belt in the Boundary Layer

    Science.gov (United States)

    Belyaev, Mikhail A.; Quataert, Eliot

    2018-04-01

    We present unstratified 3D MHD simulations of an accretion disk with a boundary layer (BL) that have a duration ˜1000 orbital periods at the inner radius of the accretion disk. We find the surprising result that angular momentum piles up in the boundary layer, which results in a rapidly rotating belt of accreted material at the surface of the star. The angular momentum stored in this belt increases monotonically in time, which implies that angular momentum transport mechanisms in the BL are inefficient and do not couple the accretion disk to the star. This is in spite of the fact that magnetic fields are advected into the BL from the disk and supersonic shear instabilities in the BL excite acoustic waves. In our simulations, these waves only carry a small fraction (˜10%) of the angular momentum required for steady state accretion. Using analytical theory and 2D viscous simulations in the R - ϕ plane, we derive an analytical criterion for belt formation to occur in the BL in terms of the ratio of the viscosity in the accretion disk to the viscosity in the BL. Our MHD simulations have a dimensionless viscosity (α) in the BL that is at least a factor of ˜100 smaller than that in the disk. We discuss the implications of these results for BL dynamics and emission.

  5. Crystallization of protein–ligand complexes

    International Nuclear Information System (INIS)

    Hassell, Anne M.; An, Gang; Bledsoe, Randy K.; Bynum, Jane M.; Carter, H. Luke III; Deng, Su-Jun J.; Gampe, Robert T.; Grisard, Tamara E.; Madauss, Kevin P.; Nolte, Robert T.; Rocque, Warren J.; Wang, Liping; Weaver, Kurt L.; Williams, Shawn P.; Wisely, G. Bruce; Xu, Robert; Shewchuk, Lisa M.

    2007-01-01

    Methods presented for growing protein–ligand complexes fall into the categories of co-expression of the protein with the ligands of interest, use of the ligands during protein purification, cocrystallization and soaking the ligands into existing crystals. Obtaining diffraction-quality crystals has long been a bottleneck in solving the three-dimensional structures of proteins. Often proteins may be stabilized when they are complexed with a substrate, nucleic acid, cofactor or small molecule. These ligands, on the other hand, have the potential to induce significant conformational changes to the protein and ab initio screening may be required to find a new crystal form. This paper presents an overview of strategies in the following areas for obtaining crystals of protein–ligand complexes: (i) co-expression of the protein with the ligands of interest, (ii) use of the ligands during protein purification, (iii) cocrystallization and (iv) soaks

  6. Untangling Galaxy Components - The Angular Momentum Parameter

    Science.gov (United States)

    Tabor, Martha; Merrifield, Michael; Aragon-Salamanca, Alfonso

    2017-06-01

    We have developed a new technique to decompose Integral Field spectral data cubes into separate bulge and disk components, allowing us to study the kinematic and stellar population properties of the individual components and how they vary with position. We present here the application of this method to a sample of fast rotator early type galaxies from the MaNGA integral field survey, and demonstrate how it can be used to explore key properties of the individual components. By extracting ages, metallicities and the angular momentum parameter lambda of the bulges and disks, we show how this method can give us new insights into the underlying structure of the galaxies and discuss what this can tell us about their evolution history.

  7. Coherent control of photoelectron wavepacket angular interferograms

    International Nuclear Information System (INIS)

    Hockett, P; Wollenhaupt, M; Baumert, T

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process, where the final (time-integrated) observable coherently samples all instantaneous states of the light–matter interaction. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable. (paper)

  8. Coherent control of photoelectron wavepacket angular interferograms

    Science.gov (United States)

    Hockett, P.; Wollenhaupt, M.; Baumert, T.

    2015-11-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process, where the final (time-integrated) observable coherently samples all instantaneous states of the light-matter interaction. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable.

  9. Angular biasing in implicit Monte-Carlo

    International Nuclear Information System (INIS)

    Zimmerman, G.B.

    1994-01-01

    Calculations of indirect drive Inertial Confinement Fusion target experiments require an integrated approach in which laser irradiation and radiation transport in the hohlraum are solved simultaneously with the symmetry, implosion and burn of the fuel capsule. The Implicit Monte Carlo method has proved to be a valuable tool for the two dimensional radiation transport within the hohlraum, but the impact of statistical noise on the symmetric implosion of the small fuel capsule is difficult to overcome. We present an angular biasing technique in which an increased number of low weight photons are directed at the imploding capsule. For typical parameters this reduces the required computer time for an integrated calculation by a factor of 10. An additional factor of 5 can also be achieved by directing even smaller weight photons at the polar regions of the capsule where small mass zones are most sensitive to statistical noise

  10. Angular filter refractometry analysis using simulated annealing.

    Science.gov (United States)

    Angland, P; Haberberger, D; Ivancic, S T; Froula, D H

    2017-10-01

    Angular filter refractometry (AFR) is a novel technique used to characterize the density profiles of laser-produced, long-scale-length plasmas [Haberberger et al., Phys. Plasmas 21, 056304 (2014)]. A new method of analysis for AFR images was developed using an annealing algorithm to iteratively converge upon a solution. A synthetic AFR image is constructed by a user-defined density profile described by eight parameters, and the algorithm systematically alters the parameters until the comparison is optimized. The optimization and statistical uncertainty calculation is based on the minimization of the χ 2 test statistic. The algorithm was successfully applied to experimental data of plasma expanding from a flat, laser-irradiated target, resulting in an average uncertainty in the density profile of 5%-20% in the region of interest.

  11. Intrinsic Orbital Angular Momentum States of Neutrons

    Science.gov (United States)

    Cappelletti, Ronald L.; Jach, Terrence; Vinson, John

    2018-03-01

    It has been shown that single-particle wave functions, of both photons and electrons, can be created with a phase vortex, i.e., an intrinsic orbital angular momentum (OAM). A recent experiment has claimed similar success using neutrons [C. W. Clark et al., Nature, 525, 504 (2015), 10.1038/nature15265]. We show that their results are insufficient to unambiguously demonstrate OAM, and they can be fully explained as phase contrast interference patterns. Furthermore, given the small transverse coherence length of the neutrons in the original experiment, the probability that any neutron was placed in an OAM state is vanishingly small. We highlight the importance of the relative size of the coherence length, which presents a unique challenge for neutron experiments compared to electron or photon work, and we suggest improvements for the creation of neutron OAM states.

  12. Nuclear scissors modes and hidden angular momenta

    Energy Technology Data Exchange (ETDEWEB)

    Balbutsev, E. B., E-mail: balbuts@theor.jinr.ru; Molodtsova, I. V. [Joint Institute for Nuclear Research (Russian Federation); Schuck, P. [Université Paris-Sud, Institut de Physique Nucléaire, IN2P3–CNRS (France)

    2017-01-15

    The coupled dynamics of low-lying modes and various giant resonances are studied with the help of the Wigner Function Moments method generalized to take into account spin degrees of freedom and pair correlations simultaneously. The method is based on Time-Dependent Hartree–Fock–Bogoliubov equations. The model of the harmonic oscillator including spin–orbit potential plus quadrupole–quadrupole and spin–spin interactions is considered. New low-lying spin-dependent modes are analyzed. Special attention is paid to the scissors modes. A new source of nuclear magnetism, connected with counter-rotation of spins up and down around the symmetry axis (hidden angular momenta), is discovered. Its inclusion into the theory allows one to improve substantially the agreement with experimental data in the description of energies and transition probabilities of scissors modes.

  13. Angular Spectrum Simulation of Pulsed Ultrasound Fields

    DEFF Research Database (Denmark)

    Du, Yigang; Jensen, Henrik; Jensen, Jørgen Arendt

    2009-01-01

    frequencies must be performed. Combining it with Field II, the generation of non-linear simulation for any geometry with any excitation array transducer becomes feasible. The purpose of this paper is to make a general pulsed simulation software using the modified ASA. Linear and phased array transducers......The optimization of non-linear ultrasound imaging should in a first step be based on simulation, as this makes parameter studies considerably easier than making transducer prototypes. Such a simulation program should be capable of simulating non-linear pulsed fields for arbitrary transducer...... geometries for any kind of focusing and apodization. The Angular Spectrum Approach (ASA) is capable of simulating monochromatic non-linear acoustic wave propagation. However, for ultrasound imaging the time response of each specific point in space is required, and a pulsed ASA simulation with multi temporal...

  14. Angular momentum of dark matter black holes

    Energy Technology Data Exchange (ETDEWEB)

    Frampton, Paul H., E-mail: paul.h.frampton@gmail.com

    2017-04-10

    We provide strongly suggestive evidence that the halo constituents of dark matter are Primordial Intermediate-Mass Black Holes (PIMBHs). PIMBHs are described by a Kerr metric with two parameters, mass M and angular momentum J. There has been little discussion of J since it plays no role in the upcoming attempt at PIMBH detection by microlensing. Nevertheless J does play a central role in understanding their previous lack of detection, especially by CMB distortion. We explain why bounds previously derived from lack of CMB distortion are too strong for PIMBHs with J non-vanishing and that, provided almost no dark matter black holes originate from stellar collapse, excessive CMB distortion is avoided.

  15. Angular reduction in multiparticle matrix elements

    International Nuclear Information System (INIS)

    Lehman, D.R.; Parke, W.C.

    1989-01-01

    A general method for reduction of coupled spherical harmonic products is presented. When the total angular coupling is zero, the reduction leads to an explicitly real expression in the scalar products of the unit vector arguments of the spherical harmonics. For nonscalar couplings, the reduction gives Cartesian tensor forms for the spherical harmonic products; tensors built from the physical vectors in the original expression. The reduction for arbitrary couplings is given in closed form, making it amenable to symbolic manipulation on a computer. The final expressions do not depend on a special choice of coordinate axes, nor do they contain azimuthal quantum number summations, or do they have complex tensor terms for couplings to a scalar; consequently, they are easily interpretable from the properties of the physical vectors they contain

  16. Angular discretization errors in transport theory

    International Nuclear Information System (INIS)

    Nelson, P.; Yu, F.

    1992-01-01

    Elements of the information-based complexity theory are computed for several types of information and associated algorithms for angular approximations in the setting of a on-dimensional model problem. For point-evaluation information, the local and global radii of information are computed, a (trivial) optimal algorithm is determined, and the local and global error of a discrete ordinates algorithm are shown to be infinite. For average cone-integral information, the local and global radii of information are computed, the local and global error tends to zero as the underlying partition is indefinitely refined. A central algorithm for such information and an optimal partition (of given cardinality) are described. It is further shown that the analytic first-collision source method has zero error (for the purely absorbing model problem). Implications of the restricted problem domains suitable for the various types of information are discussed

  17. Topological photonic orbital-angular-momentum switch

    Science.gov (United States)

    Luo, Xi-Wang; Zhang, Chuanwei; Guo, Guang-Can; Zhou, Zheng-Wei

    2018-04-01

    The large number of available orbital-angular-momentum (OAM) states of photons provides a unique resource for many important applications in quantum information and optical communications. However, conventional OAM switching devices usually rely on precise parameter control and are limited by slow switching rate and low efficiency. Here we propose a robust, fast, and efficient photonic OAM switch device based on a topological process, where photons are adiabatically pumped to a target OAM state on demand. Such topological OAM pumping can be realized through manipulating photons in a few degenerate main cavities and involves only a limited number of optical elements. A large change of OAM at ˜10q can be realized with only q degenerate main cavities and at most 5 q pumping cycles. The topological photonic OAM switch may become a powerful device for broad applications in many different fields and motivate a topological design of conventional optical devices.

  18. Angular response of hot wire probes

    International Nuclear Information System (INIS)

    Di Mare, L; Jelly, T O; Day, I J

    2017-01-01

    A new equation for the convective heat loss from the sensor of a hot-wire probe is derived which accounts for both the potential and the viscous parts of the flow past the prongs. The convective heat loss from the sensor is related to the far-field velocity by an expression containing a term representing the potential flow around the prongs, and a term representing their viscous effect. This latter term is absent in the response equations available in the literature but is essential in representing some features of the observed response of miniature hot-wire probes. The response equation contains only four parameters but it can reproduce, with great accuracy, the behaviour of commonly used single-wire probes. The response equation simplifies the calibration the angular response of rotated slanted hot-wire probes: only standard King’s law parameters and a Reynolds-dependent drag coefficient need to be determined. (paper)

  19. -Pincer Ligand Family through Ligand Post-Modification

    KAUST Repository

    Huang, Mei-Hui; Hu, Jinsong; Huang, Kuo-Wei

    2017-01-01

    A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

  20. -Pincer Ligand Family through Ligand Post-Modification

    KAUST Repository

    Huang, Mei-Hui

    2017-10-02

    A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

  1. Angular Position Tracking Control of a Quadcopter

    Directory of Open Access Journals (Sweden)

    T. V. Glazkov

    2017-01-01

    Full Text Available The paper dwells on tracking the quad-copter angular position with desired quality parameters of transient processes. The aerial vehicle is considered as a rigid body with six degrees of freedom.  A full rigid body quad-copter mathematical model is considered without the assumption of smallness of the Euler angles.Among the most well known methods of non-linear stabilization are feedback linearization and backstepping. The backstepping approach allows us to have an effective solution of the stabilization problems with uncertainties available in the system. However, in synthesis of the feedback through backstepping, there is still an urgent issue: how to ensure desirable quality of transients in the closed-loop system. The paper presents a solution of this problem using as an example the tracking a given (programmed change of the angular position of a quad-copter.The control algorithms obtained in this paper are implemented using the Rolling Spider MATLAB Toolbox (ROSMAT tool package on the Parrot Rolling Spider quad-copter. A numerical simulation and experiments have shown the efficiency of obtained control laws, with the transient processes taking into account the desired quality indicators. However, the experiments showed that lack of terms in the mathematical model to describe the aerodynamic effects, resulted in the instability of the quad-copter flight near the obstacle (the effect of the reflected airflow.Further research can be aimed at solving the control problem in question using a mathematical model of the quad-copter motion that takes into account various aerodynamic effects.One of the potential application areas for the theoretical results, obtained in the paper, is to solve the problems of automatic control of unmanned aerial vehicles.

  2. Reactivity of halide and pseudohalide ligands

    International Nuclear Information System (INIS)

    Kukushkin, Yu.N.

    1987-01-01

    Reactivity of halide and pseudohalide (cyanide, azide, thiocyanate, cyanate) ligands tending to form bridge bonds in transition metal (Re, Mo, W) complexes is considered. Complexes where transition metal salts are ligands of other, complex-forming ion, are described. Transformation of innerspheric pseudohalide ligands is an important way of directed synthesis of these metal coordination compounds

  3. Angular momentum of circularly polarized light in dielectric media

    OpenAIRE

    Mansuripur, Masud

    2014-01-01

    A circularly polarized plane-wave is known to have no angular momentum when examined through Maxwell's equations. This, however, contradicts the experimentally observed facts, where finite segments of plane waves are known to be capable of imparting angular momentum to birefringent platelets. Using a superposition of four plane-waves propagating at slightly different angles to a common direction, we derive an expression for the angular momentum density of a single plane-wave in the limit when...

  4. Orbital angular momentum exchange in post-collision interaction

    International Nuclear Information System (INIS)

    van der Burgt, P.J.M.; van Eck, J.; Heideman, H.G.M.

    1985-01-01

    The authors study the exchange of orbital angular mementum between the scattered and the ejected electron. The angular distribution of electrons ejected by the He (2s 2 ) 2 S autoionizing state after its excitation via the He (2s2p 2 ) 2 D resonance is measured. Taking into accout interference with electrons from the direct ionization of helium, the authors are able to show that the measured anisotropic angular distribution is the result of an orbital angular momentum exchange during the post-collision interaction

  5. An NMR strategy for fragment-based ligand screening utilizing a paramagnetic lanthanide probe

    International Nuclear Information System (INIS)

    Saio, Tomohide; Ogura, Kenji; Shimizu, Kazumi; Yokochi, Masashi; Burke, Terrence R.; Inagaki, Fuyuhiko

    2011-01-01

    A nuclear magnetic resonance-based ligand screening strategy utilizing a paramagnetic lanthanide probe is presented. By fixing a paramagnetic lanthanide ion to a target protein, a pseudo-contact shift (PCS) and a paramagnetic relaxation enhancement (PRE) can be observed for both the target protein and its bound ligand. Based on PRE and PCS information, the bound ligand is then screened from the compound library and the structure of the ligand–protein complex is determined. PRE is an isotropic paramagnetic effect observed within 30 Å from the lanthanide ion, and is utilized for the ligand screening in the present study. PCS is an anisotropic paramagnetic effect providing long-range (∼40 Å) distance and angular information on the observed nuclei relative to the paramagnetic lanthanide ion, and utilized for the structure determination of the ligand–protein complex. Since a two-point anchored lanthanide-binding peptide tag is utilized for fixing the lanthanide ion to the target protein, this screening method can be generally applied to non-metal-binding proteins. The usefulness of this strategy was demonstrated in the case of the growth factor receptor-bound protein 2 (Grb2) Src homology 2 (SH2) domain and its low- and high-affinity ligands.

  6. A proposed measurement of optical orbital and spin angular momentum and its implications for photon angular momentum

    Directory of Open Access Journals (Sweden)

    Elliot Leader

    2018-04-01

    Full Text Available The expression for the total angular momentum carried by a laser optical vortex beam, splits, in the paraxial approximation, into two terms which seem to represent orbital and spin angular momentum respectively. There are, however, two very different competing versions of the formula for the spin angular momentum, one based on the use of the Poynting vector, as in classical electrodynamics, the other related to the canonical expression for the angular momentum which occurs in Quantum Electrodynamics. I analyze the possibility that a sufficiently sensitive optical measurement could decide which of these corresponds to the actual physical angular momentum carried by the beam. Keywords: Photon, Angular momentum, Laser optics, Particle physics

  7. Crystal structure of μ-oxalodihydroxamato-bis[(2,2′-bipyridyl(dimethyl sulfoxide-κOcopper(II] bis(perchlorate

    Directory of Open Access Journals (Sweden)

    Irina A. Odarich

    2016-02-01

    Full Text Available The centrosymmetric binuclear complex, [Cu2(C2H2N2O4(C10H8N22(C2H6OS2](ClO42, contains two copper(II ions, connected through an N-deprotonated oxalodihydroxamic acid dianion, two terminal 2,2′-bipyridine ligands, and two apically coordinating dimethylsulfoxide molecules. Two non-coordinating perchlorate anions assure electrical neutrality. The copper(II ions in the complex dication [Cu2(C10H8N22(μ-C2H2N2O4(C2H6SO2]2+ are in an O2N3 square-pyramidal donor environment, the Cu–Cu separation being 5.2949 (4 Å. Two hydroxamate groups in the deprotonated oxalodihydroxamic acid are located trans to one each other. In the crystal, O—H...O and C—H...O hydrogen bonds link the complex cations to the perchlorate anions. Further C—H...O hydrogen bonds combine with π–π contacts with a centroid-to-centroid separation of 3.6371 (12 Å to stack the molecules along the a-axis direction.

  8. Antimicrobial mechanism of copper (II 1,10-phenanthroline and 2,2′-bipyridyl complex on bacterial and fungal pathogens

    Directory of Open Access Journals (Sweden)

    S. Chandraleka

    2014-12-01

    Full Text Available Copper based metallo drugs were prepared and their antibacterial, antifungal, molecular mechanism of [Cu(SAlaPhen]·H2O and [Cu(SAlabpy]·H2O complexes were investigated. The [Cu(SAlaPhen]·H2O and [Cu(SAlabpy]·H2O were derived from the Schiff base alanine salicylaldehyde. [Cu(SAlaPhen]·H2O showed noteworthy antibacterial and antifungal activity than the [Cu(SAlabpy]·H2O and ligand alanine, salicylaldehyde. The [Cu(SAlaPhen]·H2O complex showed significant antibacterial activity against Salmonella typhi, Staphylococcus aureus, Salmonella paratyphi and the antifungal activity against Candida albicans and Cryptococcus neoformans in well diffusion assay. The mode of action of copper (II complex was analyzed by DNA cleavage activity and in silico molecular docking. The present findings provide important insight into the molecular mechanism of copper (II complexes in susceptible bacterial and fungal pathogens. These results collectively support the use of [Cu(SAlaPhen]·H2O complex as a suitable drug to treat bacterial and fungal infections.

  9. Ligand-regulated peptide aptamers.

    Science.gov (United States)

    Miller, Russell A

    2009-01-01

    The peptide aptamer approach employs high-throughput selection to identify members of a randomized peptide library displayed from a scaffold protein by virtue of their interaction with a target molecule. Extending this approach, we have developed a peptide aptamer scaffold protein that can impart small-molecule control over the aptamer-target interaction. This ligand-regulated peptide (LiRP) scaffold, consisting of the protein domains FKBP12, FRB, and GST, binds to the cell-permeable small-molecule rapamycin and the binding of this molecule can prevent the interaction of the randomizable linker region connecting FKBP12 with FRB. Here we present a detailed protocol for the creation of a peptide aptamer plasmid library, selection of peptide aptamers using the LiRP scaffold in a yeast two-hybrid system, and the screening of those peptide aptamers for a ligand-regulated interaction.

  10. Ligand binding by PDZ domains

    DEFF Research Database (Denmark)

    Chi, Celestine N.; Bach, Anders; Strømgaard, Kristian

    2012-01-01

    , for example, are particularly rich in these domains. The general function of PDZ domains is to bring proteins together within the appropriate cellular compartment, thereby facilitating scaffolding, signaling, and trafficking events. The many functions of PDZ domains under normal physiological as well...... as pathological conditions have been reviewed recently. In this review, we focus on the molecular details of how PDZ domains bind their protein ligands and their potential as drug targets in this context....

  11. Bitopic Ligands and Metastable Binding Sites

    DEFF Research Database (Denmark)

    Fronik, Philipp; Gaiser, Birgit I; Sejer Pedersen, Daniel

    2017-01-01

    of orthosteric binding sites. Bitopic ligands have been employed to address the selectivity problem by combining (linking) an orthosteric ligand with an allosteric modulator, theoretically leading to high-affinity subtype selective ligands. However, it remains a challenge to identify suitable allosteric binding...... that have been reported to date, this type of bitopic ligands would be composed of two identical pharmacophores. Herein, we outline the concept of bitopic ligands, review metastable binding sites, and discuss their potential as a new source of allosteric binding sites....

  12. Radioiodinated ligands for dopamine receptors

    International Nuclear Information System (INIS)

    Kung, H.F.

    1994-01-01

    The dopamine receptor system is important for normal brain function; it is also the apparent action site for various neuroleptic drugs for the treatment of schizophrenia and other metal disorders. In the past few years radioiodinated ligands for single photon emission tomography (SPECT) have been successfully developed and tested in humans: [ 123 I]TISCH for D1 dopamine receptors; [ 123 I]IBZM, epidepride, IBF and FIDA2, four iodobenzamide derivatives, for D2/D3 dopamine receptors. In addition, [ 123 I]β-CIT (RTI-55) and IPT, cocaine derivatives, for the dopamine reuptake site are potentially useful for diagnosis of loss of dopamine neurons. The first iodinated ligand, (R)trans-7-OH-PIPAT, for D3 dopamine receptors, was synthesized and characterized with cloned cell lines (Spodoptera frugiperda, Sf9) expressing the D2 and D3 dopamine receptors and with rat basal forebrain membrane preparations. Most of the known iodobenzamides displayed similar potency in binding to both D2 and D3 dopamine receptors expressed in the cell lines. Initial studies appear to suggest that by fine tuning the structures it may be possible to develop agents specific for D2 and D3 dopamine receptors. It is important to investigate D2/D3 selectivity for this series of potent ligands

  13. Whole-body angular momentum during stair ascent and descent.

    Science.gov (United States)

    Silverman, Anne K; Neptune, Richard R; Sinitski, Emily H; Wilken, Jason M

    2014-04-01

    The generation of whole-body angular momentum is essential in many locomotor tasks and must be regulated in order to maintain dynamic balance. However, angular momentum has not been investigated during stair walking, which is an activity that presents a biomechanical challenge for balance-impaired populations. We investigated three-dimensional whole-body angular momentum during stair ascent and descent and compared it to level walking. Three-dimensional body-segment kinematic and ground reaction force (GRF) data were collected from 30 healthy subjects. Angular momentum was calculated using a 13-segment whole-body model. GRFs, external moment arms and net joint moments were used to interpret the angular momentum results. The range of frontal plane angular momentum was greater for stair ascent relative to level walking. In the transverse and sagittal planes, the range of angular momentum was smaller in stair ascent and descent relative to level walking. Significant differences were also found in the ground reaction forces, external moment arms and net joint moments. The sagittal plane angular momentum results suggest that individuals alter angular momentum to effectively counteract potential trips during stair ascent, and reduce the range of angular momentum to avoid falling forward during stair descent. Further, significant differences in joint moments suggest potential neuromuscular mechanisms that account for the differences in angular momentum between walking conditions. These results provide a baseline for comparison to impaired populations that have difficulty maintaining dynamic balance, particularly during stair ascent and descent. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Rabi like angular splitting in Surface Plasmon Polariton - Exciton interaction in ATR configuration

    Science.gov (United States)

    Hassan, Heba; Abdallah, T.; Negm, S.; Talaat, H.

    2018-05-01

    We have studied the coupling of propagating Surface Plasmon Polaritons (SPP) on silver films and excitons in CdS quantum dots (QDs). We employed the Kretschmann-Raether configuration of the attenuated total reflection (ATR) to propagate the SPP on silver film of thickness 47.5 nm at three different wavelengths. The CdS QD have been chemically synthesized with particular size such that its exciton of energy would resonate with SPP. High resolution transmission electron microscopy (HRTEM) and scan tunneling microscopy (STM) were used to measure the corresponding QDs size and confirm its shape. Further confirmation of the size has been performed by the effective mass approximation (EMA) model utilizing the band gap of the prepared QDs. The band gaps have been measured through UV-vis absorption spectra as well as scan tunneling spectroscopy (STS). The coupling has been observed as two branching dips in the ATR spectra indicating Rabi like splitting. To the best of our knowledge, this is the first time that Rabi interaction is directly observed in an ATR angular spectra. This observation is attributed to the use a high resolution angular scan (±0.005°), in addition to the Doppler width of the laser line as well as the energy distribution of the excitons. The effect of three different linker molecules (TOPO, HDA), (Pyridine) and (Tri-butylamine) as surface ligands, on SPP-Exciton interaction has been examined.

  15. Learning web development with Bootstrap and AngularJS

    CERN Document Server

    Radford, Stephen

    2015-01-01

    Whether you know a little about Bootstrap or AngularJS, or you're a complete beginner, this book will enhance your capabilities in both frameworks and you'll build a fully functional web app. A working knowledge of HTML, CSS, and JavaScript is required to fully get to grips with Bootstrap and AngularJS.

  16. Schmidt decomposition for non-collinear biphoton angular wave functions

    International Nuclear Information System (INIS)

    Fedorov, M V

    2015-01-01

    Schmidt modes of non-collinear biphoton angular wave functions are found analytically. The experimentally realizable procedure for their separation is described. Parameters of the Schmidt decomposition are used to evaluate the degree of the biphoton's angular entanglement. (paper)

  17. Isotropic gates in large gamma detector arrays versus angular distributions

    International Nuclear Information System (INIS)

    Iacob, V.E.; Duchene, G.

    1997-01-01

    The quality of the angular distribution information extracted from high-fold gamma-gamma coincidence events is analyzed. It is shown that a correct quasi-isotropic gate setting, available at the modern large gamma-ray detector arrays, essentially preserves the quality of the angular information. (orig.)

  18. Measuring Average Angular Velocity with a Smartphone Magnetic Field Sensor

    Science.gov (United States)

    Pili, Unofre; Violanda, Renante

    2018-01-01

    The angular velocity of a spinning object is, by standard, measured using a device called a tachometer. However, by directly using it in a classroom setting, the activity is likely to appear as less instructive and less engaging. Indeed, some alternative classroom-suitable methods for measuring angular velocity have been presented. In this paper,…

  19. Angular momentum dependence of the distribution of shell model eigenenergies

    International Nuclear Information System (INIS)

    Yen, M.K.

    1974-01-01

    In the conventional shell model calculation the many-particle energy matrices are constructed and diagonalized for definite angular momentum and parity. However the resulting set of eigenvalues possess a near normal behavior and hence a simple statistical description is possible. Usually one needs only about four parameters to capture the average level densities if the size of the set is not too small. The parameters are essentially moments of the distribution. But the difficulty lies in the yet unsolved problem of calculating moments in the fixed angular momentum subspace. We have derived a formula to approximate the angular momentum projection dependence of any operator averaged in a shell model basis. This approximate formula which is a truncated series in Hermite polynomials has been proved very good numerically and justified analytically for large systems. Applying this formula to seven physical cases we have found that the fixed angular momentum projection energy centroid, width and higher central moments can be obtained accurately provided for even-even nuclei the even and odd angular momentum projections are treated separately. Using this information one can construct the energy distribution for fixed angular momentum projection assuming normal behavior. Then the fixed angular momentum level densities are deduced and spectra are extracted. Results are in reasonably good agreement with the exact values although not as good as those obtained using exact fixed angular momentum moments. (Diss. Abstr. Int., B)

  20. Rotational speedups accompanying angular deceleration of a superfluid

    International Nuclear Information System (INIS)

    Campbell, L.J.

    1979-01-01

    Exact calculations of the angular deceleration of superfluid vortex arrays show momentary speedups in the angular velocity caused by coherent, multiple vortex loss at the boundary. The existence and shape of the speedups depend on the vortex friction, the deceleration rate, and the pattern symmetry. The phenomenon resembles, in several ways, that observed in pulsars

  1. Angular correlations near the Fermi energy

    International Nuclear Information System (INIS)

    Fox, D.; Cebra, D.A.; Karn, J.

    1988-01-01

    Angular correlations between light particles have been studied to probe the extent to which a thermally equilibrated system is formed in heavy ion collisions near the Fermi energy. Single-light-particle inclusive energy spectra and two-particle large-angle correlations were measured for 40 and 50 MeV/nucleon C+C, Ag, and Au. The single-particle inclusive energy spectra are well fit by a three moving source parametrization. Two-particle large-angle correlations are shown to be consistent with emission from a thermally equilibrated source when the effects of momentum conservation are considered. Single-particle inclusive spectra and light-particle correlations at small relative momentum were measured for 35 MeV/nucleon N+Ag. Source radii were extracted from the two-particle correlation functions and were found to be consistent with previous measurements using two-particle correlations and the coalescence model. The temperature of the emitting source was extracted from the relative populations of states using the quantum statistical model and was found to be 4.8/sub -2.4//sup +2.8/ MeV, compared to the 14 MeV temperature extracted from the slopes of the kinetic energy spectra

  2. A new CMOS Hall angular position sensor

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, R.S.; Drljaca, P. [Swiss Federal Inst. of Tech., Lausanne (Switzerland); Schott, C.; Racz, R. [SENTRON AG, Zug (Switzerland)

    2001-06-01

    The new angular position sensor consists of a combination of a permanent magnet attached to a shaft and of a two-axis magnetic sensor. The permanent magnet produces a magnetic field parallel with the magnetic sensor plane. As the shaft rotates, the magnetic field also rotates. The magnetic sensor is an integrated combination of a CMOS Hall integrated circuit and a thin ferromagnetic disk. The CMOS part of the system contains two or more conventional Hall devices positioned under the periphery of the disk. The ferromagnetic disk converts locally a magnetic field parallel with the chip surface into a field perpendicular to the chip surface. Therefore, a conventional Hall element can detect an external magnetic field parallel with the chip surface. As the direction of the external magnetic field rotates in the chip plane, the output voltage of the Hall element varies as the cosine of the rotation angle. By placing the Hall elements at the appropriate places under the disk periphery, we may obtain the cosine signals shifted by 90 , 120 , or by any other angle. (orig.)

  3. Nuclear structure at high angular momentum

    International Nuclear Information System (INIS)

    Stephens, F.S.

    1976-08-01

    There is considerable interest in high angular-momentum states of nuclei, and some recent progress in three areas is discussed. Part I considers transitional nuclei, where two types of rotational bands--decoupled and strongly coupled--are found to occur very frequently. These can be described by several collective models, but the required potential-energy surfaces seem to differ somewhat from those calculated microscopically. In Part II the processes that might cause backbending (irregularities in the rotational levels of certain nuclei) are discussed, and alignment of individual nucleons now seems to be the cause in most cases. The mixing of the ground band with this aligned band can be studied in some detail using Coulomb excitation with very heavy ions. Part III deals with the very high-spin states where effective moments of inertia have been obtained for spins up to 50h. Also structure has been seen in the spectra around these spin values which can be tentatively related to calculated shell effects. 74 references, 61 figures

  4. CLASS: The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Essinger-Hileman, Thomas; Ali, Aamir; Amiri, Mandana; Appel, John W.; Araujo, Derek; Bennett, Charles L.; Boone, Fletcher; Chan, Manwei; Cho, Hsiao-Mei; Chuss, David T.; hide

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an experiment to measure the signature of a gravitational wave background from inflation in the polarization of the cosmic microwave background (CMB). CLASS is a multi-frequency array of four telescopes operating from a high-altitude site in the Atacama Desert in Chile. CLASS will survey 70% of the sky in four frequency bands centered at 38, 93, 148, and 217 GHz, which are chosen to straddle the Galactic-foreground minimum while avoiding strong atmospheric emission lines. This broad frequency coverage ensures that CLASS can distinguish Galactic emission from the CMB. The sky fraction of the CLASS survey will allow the full shape of the primordial B-mode power spectrum to be characterized, including the signal from reionization at low-length. Its unique combination of large sky coverage, control of systematic errors, and high sensitivity will allow CLASS to measure or place upper limits on the tensor-to-scalar ratio at a level of r = 0:01 and make a cosmic-variance-limited measurement of the optical depth to the surface of last scattering, tau. (c) (2014) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  5. Angular velocity and centripetal acceleration relationship

    Science.gov (United States)

    Monteiro, Martín; Cabeza, Cecilia; Marti, Arturo C.; Vogt, Patrik; Kuhn, Jochen

    2014-05-01

    During the last few years, the growing boom of smartphones has given rise to a considerable number of applications exploiting the functionality of the sensors incorporated in these devices. A sector that has unexpectedly taken advantage of the power of these tools is physics teaching, as reflected in several recent papers. In effect, the use of smartphones has been proposed in several physics experiments spanning mechanics, electromagnetism, optics, oscillations, and waves, among other subjects. Although mechanical experiments have received considerable attention, most of them are based on the use of the accelerometer. An aspect that has received less attention is the use of rotation sensors or gyroscopes. An additional advance in the use of these devices is given by the possibility of obtaining data using the accelerometer and the gyroscope simultaneously. The aim of this paper is to consider the relation between the centripetal acceleration and the angular velocity. Instead of using a formal laboratory setup, in this experiment a smartphone is attached to the floor of a merry-go-round, found in many playgrounds. Several experiments were performed with the roundabout rotating in both directions and with the smart-phone at different distances from the center. The coherence of the measurements is shown.

  6. Angular-momentum effects in subbarrier fusion

    International Nuclear Information System (INIS)

    Halbert, M.L.; Beene, J.R.

    1993-01-01

    It has been known since about 1980 that fusion of heavy ions is greatly enhanced below the Coulomb barrier compared with normal barrier-penetration expectations. The excitation function for fusion of 64 Ni + 100 Mo measured in collaboration with a group at Washington University shows the effect clearly. The barrier energy is about 142 MeV; the lowest point is at about 90% of the barrier energy. The dotted curve is the prediction of a one-dimensional-barrier-penetration calculation of a type that reproduces the fusion of light projectiles very well. Several theoretical approaches have been successful in explaining the enhancement seen in much of the excitation-function data, but it cannot be said that a full understanding of the physics is in hand even after more than a decade of hard work. In fact, the reasonable success of several rather different models shows that the underlying phenomena are not well understood. Other types of data might be helpful in distinguishing among the many different theoretical approaches. An important kind of information not measured in most of the experiments is the dependence on ell, the angular momentum of the fusing system. We obtained such information on the cross sections, σ ell, as a function of ell for the fusion of 64 Ni and 100 Mo using the Spin Spectrometer. This paper will first review the experimental method and data and then present results from a more sophisticated analysis of the same data

  7. Cyclic transformation of orbital angular momentum modes

    International Nuclear Information System (INIS)

    Schlederer, Florian; Krenn, Mario; Fickler, Robert; Malik, Mehul; Zeilinger, Anton

    2016-01-01

    The spatial modes of photons are one realization of a QuDit, a quantum system that is described in a D-dimensional Hilbert space. In order to perform quantum information tasks with QuDits, a general class of D-dimensional unitary transformations is needed. Among these, cyclic transformations are an important special case required in many high-dimensional quantum communication protocols. In this paper, we experimentally demonstrate a cyclic transformation in the high-dimensional space of photonic orbital angular momentum (OAM). Using simple linear optical components, we show a successful four-fold cyclic transformation of OAM modes. Interestingly, our experimental setup was found by a computer algorithm. In addition to the four-cyclic transformation, the algorithm also found extensions to higher-dimensional cycles in a hybrid space of OAM and polarization. Besides being useful for quantum cryptography with QuDits, cyclic transformations are key for the experimental production of high-dimensional maximally entangled Bell-states. (paper)

  8. Angular momentum transport by tidal acoustic wave

    International Nuclear Information System (INIS)

    Sakurai, T.

    1976-01-01

    An analytical expression of the braking torque on a Jacobian ellipsoid rotating steadily in an enviromental gas is given, based on the assumption that the ellipsoid rotates around its shortest principal axis with an angular momentum slightly larger than that at the bifurcation point of the Maclaurin spheroid. This braking torque is effected by the gravitational interaction between the ellipsoid matter and a spiral density configuration in the environmental gas. This spiral configuration which is called a tidal acoustic wave, is caused by the zone of silence effect in a supersonic flow. With respect to a coordinates system rotating with the ellipsoid, a supersonic region appears outside a certain radius. In this supersonic region, the effect of the non-axisymmetric fluctuation in the ellipsoid potential propagates along the downstream branches of the Mach waves. This one-sided response of the supersonic part causes the tidal acoustic wave. The discussion is restricted to the equatorial plane, and an acoustic approximation of the basic equations is used under the assumption that the self-gravity effect of the environmental gas is negligable in comparison to the main gravity of the ellipsoid. The results are applied to the pre- and post-Main sequence phases of a rotating star, and relating astrophysical problems are discussed. (Auth.)

  9. Angular momentum transport by tidal acoustic wave

    Energy Technology Data Exchange (ETDEWEB)

    Sakurai, T [Kyoto Univ. (Japan). Faculty of Engineering

    1976-05-01

    An analytical expression of the braking torque on a Jacobian ellipsoid rotating steadily in an enviromental gas is given, based on the assumption that the ellipsoid rotates around its shortest principal axis with an angular momentum slightly larger than that at the bifurcation point of the Maclaurin spheroid. This braking torque is effected by the gravitational interaction between the ellipsoid matter and a spiral density configuration in the environmental gas. This spiral configuration which is called a tidal acoustic wave, is caused by the zone of silence effect in a supersonic flow. With respect to a coordinates system rotating with the ellipsoid, a supersonic region appears outside a certain radius. In this supersonic region, the effect of the non-axisymmetric fluctuation in the ellipsoid potential propagates along the downstream branches of the Mach waves. This one-sided response of the supersonic part causes the tidal acoustic wave. The discussion is restricted to the equatorial plane, and an acoustic approximation of the basic equations is used under the assumption that the self-gravity effect of the environmental gas is negligable in comparison to the main gravity of the ellipsoid. The results are applied to the pre- and post-Main sequence phases of a rotating star, and relating astrophysical problems are discussed.

  10. Angular distributions of sputtered particles from NiTi alloy

    International Nuclear Information System (INIS)

    Neshev, I.; Hamishkeev, V.; Chernysh, V.S.; Postnikov, S.; Mamaev, B.

    1993-01-01

    The angular distributions of sputtered Ni and Ti from a polycrystalline NiTi (50-50%) alloy are investigated by Auger electron spectroscopy and Rutherford backscattering spectroscopy. A difference in the angular distributions is observed with Ni being sputtered preferentially near the surface normal. A computer program for the calculation of the angular distributions of constituents sputtered from binary targets is created and used. The mechanisms responsible for the observed differences in the angular distributions are discussed. It is found that the collisional cascade theory is not directly applicable to the results of the constituents' angular distributions obtained in the presence of oxygen. The fitted coefficients of bombardment-induced segregation are found to be greater than the experimentally obtained ones. (author)

  11. Jet angularity measurements for single inclusive jet production

    Science.gov (United States)

    Kang, Zhong-Bo; Lee, Kyle; Ringer, Felix

    2018-04-01

    We study jet angularity measurements for single-inclusive jet production at the LHC. Jet angularities depend on a continuous parameter a allowing for a smooth interpolation between different traditional jet shape observables. We establish a factorization theorem within Soft Collinear Effective Theory (SCET) where we consistently take into account in- and out-of-jet radiation by making use of semi-inclusive jet functions. For comparison, we elaborate on the differences to jet angularities measured on an exclusive jet sample. All the necessary ingredients for the resummation at next-to-leading logarithmic (NLL) accuracy are presented within the effective field theory framework. We expect semiinclusive jet angularity measurements to be feasible at the LHC and we present theoretical predictions for the relevant kinematic range. In addition, we investigate the potential impact of jet angularities for quark-gluon discrimination.

  12. Photon beam polarization and non-dipolar angular distributions

    International Nuclear Information System (INIS)

    Peshkin, M.

    1996-01-01

    Angular distributions of ejecta from unoriented atoms and molecules depend upon the polarization state of the incident x-rays as well as upon the dynamics of the physical systems being studied. I recommend a simple geometrical way of looking at the polarization and its effects upon angular distributions. The polarization is represented as a vector in a parameter space that faithfully represents the polarization of the beam. The simple dependence of the angular dependence of the angular distributions on the polarization vector enables easy extraction of the dynamical information contained in those angular distributions. No new physical results emerge from this geometrical approach, but known consequences of the symmetries appear in an easily visualized form that I find pleasing and that has proved to be useful for planning experiments and for analyzing data

  13. Roles of Bridging Ligand Topology and Conformation in Controlling Exchange Interactions between Paramagnetic Molybdenum Fragments in Dinuclear and Trinuclear Complexes.

    Science.gov (United States)

    Ung VÂ, V&acaron;n Ân; Cargill Thompson, Alexander M. W.; Bardwell, David A.; Gatteschi, Dante; Jeffery, John C.; McCleverty, Jon A.; Totti, Federico; Ward, Michael D.

    1997-07-30

    The magnetic properties of two series of dinuclear complexes, and one trinuclear complex, have been examined as a function of the bridging pathway between the metal centers. The first series of dinuclear complexes is [{Mo(V)(O)(Tp)Cl}(2)(&mgr;-OO)], where "OO" is [1,4-O(C(6)H(4))(n)O](2)(-) (n = 1, 1; n = 2, 3), [4,4'-O(C(6)H(3)-2-Me)(2)O](2)(-) (4), or [1,3-OC(6)H(4)O](2)(-) (2) [Tp = tris(3,5-dimethylpyrazolyl)hydroborate]. The second series of dinuclear complexes is [{Mo(I)(NO)(Tp)Cl}(2)(&mgr;-NN)], where "NN" is 4,4'-bipyridyl (5), 3,3'-dimethyl-4,4'-bipyridine (6), 3,8-phenanthroline (7), or 2,7-diazapyrene (8). The trinuclear complex is [{Mo(V)(O)(Tp)Cl}(3)(1,3,5-C(6)H(3)O(3))] (9), whose crystal structure was determined [9.5CH(2)Cl(2): C(56)H(81)B(3)Cl(13)Mo(3)N(18)O(6); monoclinic, P2(1)/n; a = 13.443, b = 41.46(2), c = 14.314(6) Å; beta = 93.21(3) degrees; V = 7995(5) Å(3); Z = 4; R(1) = 0.106]. In these complexes, the sign and magnitude of the exchange coupling constant J is clearly related to both the topology and the conformation of the bridging ligand [where J is derived from H = -JS(1)().S(2)() for 1-8 and H = -J(S(1)().S(2)() + S(2)().S(3)() + S(1)().S(3)()) for 9]. The values are as follows: 1, -80 cm(-)(1); 2, +9.8 cm(-)(1); 3, -13.2 cm(-)(1); 4, -2.8 cm(-)(1); 5, -33 cm(-)(1); 6, -3.5 cm(-)(1); 7, -35.6 cm(-)(1); 8, -35.0 cm(-)(1); 9, +14.4 cm(-)(1). In particular the following holds: (1) J is negative (antiferromagnetic exchange) across the para-substituted bridges ligands of 1 and 3-8 but positive (ferromagnetic exchange) across the meta-substituted bridging ligands of 2 and 9. (2) J decreases in magnitude dramatically as the bridging ligand conformation changes from planar to twisted (compare 3 and 4, or 6 and 8). These observations are consistent with a spin-polarization mechanism for the exchange interaction, propagated across the pi-system of the bridging ligand by via overlap of bridging ligand p(pi) orbitals with the d(pi) magnetic

  14. Insights into an original pocket-ligand pair classification: a promising tool for ligand profile prediction.

    Directory of Open Access Journals (Sweden)

    Stéphanie Pérot

    Full Text Available Pockets are today at the cornerstones of modern drug discovery projects and at the crossroad of several research fields, from structural biology to mathematical modeling. Being able to predict if a small molecule could bind to one or more protein targets or if a protein could bind to some given ligands is very useful for drug discovery endeavors, anticipation of binding to off- and anti-targets. To date, several studies explore such questions from chemogenomic approach to reverse docking methods. Most of these studies have been performed either from the viewpoint of ligands or targets. However it seems valuable to use information from both ligands and target binding pockets. Hence, we present a multivariate approach relating ligand properties with protein pocket properties from the analysis of known ligand-protein interactions. We explored and optimized the pocket-ligand pair space by combining pocket and ligand descriptors using Principal Component Analysis and developed a classification engine on this paired space, revealing five main clusters of pocket-ligand pairs sharing specific and similar structural or physico-chemical properties. These pocket-ligand pair clusters highlight correspondences between pocket and ligand topological and physico-chemical properties and capture relevant information with respect to protein-ligand interactions. Based on these pocket-ligand correspondences, a protocol of prediction of clusters sharing similarity in terms of recognition characteristics is developed for a given pocket-ligand complex and gives high performances. It is then extended to cluster prediction for a given pocket in order to acquire knowledge about its expected ligand profile or to cluster prediction for a given ligand in order to acquire knowledge about its expected pocket profile. This prediction approach shows promising results and could contribute to predict some ligand properties critical for binding to a given pocket, and conversely

  15. Insights into an original pocket-ligand pair classification: a promising tool for ligand profile prediction.

    Science.gov (United States)

    Pérot, Stéphanie; Regad, Leslie; Reynès, Christelle; Spérandio, Olivier; Miteva, Maria A; Villoutreix, Bruno O; Camproux, Anne-Claude

    2013-01-01

    Pockets are today at the cornerstones of modern drug discovery projects and at the crossroad of several research fields, from structural biology to mathematical modeling. Being able to predict if a small molecule could bind to one or more protein targets or if a protein could bind to some given ligands is very useful for drug discovery endeavors, anticipation of binding to off- and anti-targets. To date, several studies explore such questions from chemogenomic approach to reverse docking methods. Most of these studies have been performed either from the viewpoint of ligands or targets. However it seems valuable to use information from both ligands and target binding pockets. Hence, we present a multivariate approach relating ligand properties with protein pocket properties from the analysis of known ligand-protein interactions. We explored and optimized the pocket-ligand pair space by combining pocket and ligand descriptors using Principal Component Analysis and developed a classification engine on this paired space, revealing five main clusters of pocket-ligand pairs sharing specific and similar structural or physico-chemical properties. These pocket-ligand pair clusters highlight correspondences between pocket and ligand topological and physico-chemical properties and capture relevant information with respect to protein-ligand interactions. Based on these pocket-ligand correspondences, a protocol of prediction of clusters sharing similarity in terms of recognition characteristics is developed for a given pocket-ligand complex and gives high performances. It is then extended to cluster prediction for a given pocket in order to acquire knowledge about its expected ligand profile or to cluster prediction for a given ligand in order to acquire knowledge about its expected pocket profile. This prediction approach shows promising results and could contribute to predict some ligand properties critical for binding to a given pocket, and conversely, some key pocket

  16. Ligand photo-isomerization triggers conformational changes in iGluR2 ligand binding domain.

    Directory of Open Access Journals (Sweden)

    Tino Wolter

    Full Text Available Neurological glutamate receptors bind a variety of artificial ligands, both agonistic and antagonistic, in addition to glutamate. Studying their small molecule binding properties increases our understanding of the central nervous system and a variety of associated pathologies. The large, oligomeric multidomain membrane protein contains a large and flexible ligand binding domains which undergoes large conformational changes upon binding different ligands. A recent application of glutamate receptors is their activation or inhibition via photo-switchable ligands, making them key systems in the emerging field of optochemical genetics. In this work, we present a theoretical study on the binding mode and complex stability of a novel photo-switchable ligand, ATA-3, which reversibly binds to glutamate receptors ligand binding domains (LBDs. We propose two possible binding modes for this ligand based on flexible ligand docking calculations and show one of them to be analogues to the binding mode of a similar ligand, 2-BnTetAMPA. In long MD simulations, it was observed that transitions between both binding poses involve breaking and reforming the T686-E402 protein hydrogen bond. Simulating the ligand photo-isomerization process shows that the two possible configurations of the ligand azo-group have markedly different complex stabilities and equilibrium binding modes. A strong but slow protein response is observed after ligand configuration changes. This provides a microscopic foundation for the observed difference in ligand activity upon light-switching.

  17. Development of immobilized ligands for actinide separations

    International Nuclear Information System (INIS)

    Paine, R.T.

    1994-01-01

    Primary goals during this grant period were to (1) synthesize new bifunctional chelating ligands, (2) characterize the structural features of the Ln and An coordination complexes formed by these ligands, (3) use structural data to iteratively design new classes of multifunctional ligands, and (4) explore additional routes for attachment of key ligands to solid supports that could be useful for chromatographic separations. Some highlights of recently published work as well as a summary of submitted, unpublished and/or still in progress research are outlined

  18. Control of Angular Intervals for Angle-Multiplexed Holographic Memory

    Science.gov (United States)

    Kinoshita, Nobuhiro; Muroi, Tetsuhiko; Ishii, Norihiko; Kamijo, Koji; Shimidzu, Naoki

    2009-03-01

    In angle-multiplexed holographic memory, the full width at half maximum of the Bragg selectivity curves is dependent on the angle formed between the medium and incident laser beams. This indicates the possibility of high density and high multiplexing number by varying the angular intervals between adjacent holograms. We propose an angular interval scheduling for closely stacking holograms into medium even when the angle range is limited. We obtained bit error rates of the order of 10-4 under the following conditions: medium thickness of 1 mm, laser beam wavelength of 532 nm, and angular multiplexing number of 300.

  19. Angular absorption of iridium - ICW12 needles: practical considerations

    International Nuclear Information System (INIS)

    Szymczyk, W.; Lesiak, J.

    1984-01-01

    An analysis was made of two potential sources of error in Ir 192 dosimetry: the effect of angular absorption and the differences in the ionization constants found in literature. Corrections for selfabsorption in the ICW12 iridium source were determined from measurements and calculations. It was found that the decrease in the dose caused by the angular absorption in the central therapeutic area of a typical implantation can exceed 5 percent. The need for employing the concept of ''constant exposure rate'' is stressed as well as that for using angular absorption in the form of absorption. 13 refs., 6 figs., 1 tab. (author)

  20. Nuclear spin measurement using the angular correlation method

    International Nuclear Information System (INIS)

    Schapira, J.-P.

    The double angular correlation method is defined by a semi-classical approach (Biendenharn). The equivalence formula in quantum mechanics are discussed for coherent and incoherent angular momentum mixing; the correlations are described from the density and efficiency matrices (Fano). The ambiguities in double angular correlations can be sometimes suppressed (emission of particles with a high orbital momentum l), using triple correlations between levels with well defined spin and parity. Triple correlations are applied to the case where the direction of linear polarization of γ-rays is detected [fr

  1. Measurement crankshaft angular speed of an OM403 engine

    Directory of Open Access Journals (Sweden)

    Biočanin Stojko

    2017-01-01

    Full Text Available In this paper, the methodology of the measurement of the angular speed of the crankshaft of a ten-cylinder diesel OM403 engine is presented, with regular and irregular engine operation. The angular velocity was measured under laboratory conditions, on already installed measuring equipment from the laboratory and on the break of a well known brand-Schenck, by using an optoelectronic incremental rotary encoder, a data acquisition module and the LabVIEW software for synchronization and management of the measuring equipment. The goal of this paper is to give a practical contribution to researches of measuring of crankshaft angular speed of the crankshaft engine OM 403.

  2. On Angular Sampling Methods for 3-D Spatial Channel Models

    DEFF Research Database (Denmark)

    Fan, Wei; Jämsä, Tommi; Nielsen, Jesper Ødum

    2015-01-01

    This paper discusses generating three dimensional (3D) spatial channel models with emphasis on the angular sampling methods. Three angular sampling methods, i.e. modified uniform power sampling, modified uniform angular sampling, and random pairing methods are proposed and investigated in detail....... The random pairing method, which uses only twenty sinusoids in the ray-based model for generating the channels, presents good results if the spatial channel cluster is with a small elevation angle spread. For spatial clusters with large elevation angle spreads, however, the random pairing method would fail...... and the other two methods should be considered....

  3. Notes on the quantum theory of angular momentum

    CERN Document Server

    Feenberg, Eugene

    1999-01-01

    This classic, concise text has served a generation of physicists as an exceptionally useful guide to the mysteries of angular momenta and Clebsch-Gordon Coefficients. Derived from notes originally prepared to assist graduate students in reading research papers on atomic, molecular, and nuclear structure, the text first reviews the basic elements of quantum theory. It then examines the development of the fundamental commutation relations for angular momentum components and vector operators, and the ways in which matrix elements and eigenvalues of the angular momentum operators are worked out f

  4. Syntheses, structures and properties of three new two-dimensional Cu(I)-Ln(III) heterometallic coordination polymers based on 2,2'-dipyridyl-5,5'-dicarboxylate ligands.

    Science.gov (United States)

    Zhao, Junwei; Cheng, Yamin; Shang, Sensen; Zhang, Fang; Chen, Li; Chen, Lijuan

    2013-12-01

    Three new two-dimensional Cu(I)-Ln(III) heterometallic coordination polymers [Ln(III)Cu2(I)(Hbpdc)4] · Cl · xH2O [Ln(III) = La(III), x = 8 (1); Ln(III) = Pr(III), x=9 (2); Ln(III) = Eu(III), x = 8 (3)] (H2bpdc = 2,2'-bipyridyl-5,5'-dicarboxylic acid) have been prepared under hydrothermal conditions and structurally characterized by elemental analyses, inductively coupled plasma atomic emission spectrometry (ICP-AES) analyses, IR spectra, X-ray photoelectron spectroscopy (XPS) and single-crystal X-ray diffraction. X-ray diffraction indicates that the isomorphic 1-3 display the two-dimensional sheet structure constructed from [Cu(I)(Hbpdc)2](-) fragments through Ln(3+) connectors. Moreover, the solid-state photoluminescence measurements of 3 indicate that the Eu(III) ions, Hbpdc(-) ligands and Cu(I) cations make contributions to its luminescent properties simultaneously. Copyright © 2013 Elsevier B.V. All rights reserved.

  5. The angular momentum dependence of complex fragment emission

    International Nuclear Information System (INIS)

    Sobtka, L.G.; Sarantites, D.G.; Li, Z.

    1987-01-01

    Large fragment (A > 4) production at high angular momentum is studied via the reaction, 200 MeV 45 Sc + 65 Cu. Comparisons of the fragment yields from this reaction (high angular momentum) to those from 93 Nb + Be (low angular momentum) are used to verify the strong angular momentum dependence of large fragment production predicted by equilibrium models. Details of the coincident γ-ray distributions not only confirm a rigidly rotating intermediate but also indicate that the widths of the primary L-wave distributions decrease with increasing symmetry in the decay channel. These data are used to test the asymmetry and L-wave dependence of emission barriers calculated from a rotating, finite range corrected, liquid drop model. 21 refs., 10 figs

  6. Manifest rotation symmetric expressions for angular momentum eigenfunctions

    International Nuclear Information System (INIS)

    Eeg, J.O.; Wroldsen, J.

    1983-01-01

    Manifest rotation symmetric expressions for eigenfunctions for spin s, orbital angular momentum l and total angular momentum j = l+s, .... , /l-s/ in terms of (2j+1) x (2s+1) multipole transition matrices (MTM) is given. These matrices, which are irreducible tensor matrices, have an algebra together with ordinary spin matrices for spin s and spin j. Explicit expressions for MTM's and their algebra are given for angular momenta <-3. By means of some examples it is shown that within this formalism angular integrations in central field problems will be simplified considerably. Thus the formalism turns out to be very useful for instance for calculations within the MIT-bag and also within spin-spin interactions in atomic physics. (Auth.)

  7. The INCAS Project: An Innovative Contact-Less Angular Sensor

    Science.gov (United States)

    Ghislanzoni, L.; Di Cintio, A.; Solimando, M.; Parzianello, G.

    2013-09-01

    Angular Positions sensors are widely used in all spacecrafts, including re-entry vehicles and launchers, where mechanisms and pointing-scanning devices are required. The main applications are on mechanisms for TeleMeasure (TM) related to the release and deployment of devices, or on rotary mechanisms such as Solar Array Drive Mechanism (SADM) and Antenna Pointing Mechanism (APM). Longer lifetime (up to 7- 10 years) is becoming a new driver for the coming missions and contact technology sensors often incur in limitations due to the wear of the contacting parts [1].A Self-Compensating Absolute Angular Encoder was developed and tested in the frame of an ESA's ARTES 5.2 project, named INCAS (INnovative Contact-less Angular Sensor). More in particular, the INCAS sensor addresses a market need for contactless angular sensors aimed at replacing the more conventional rotary potentiometers, while featuring the same level of accuracy performances and extending the expected lifetime.

  8. Electronic orbital angular momentum and magnetism of graphene

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Ji, E-mail: ji.luo@upr.edu

    2014-10-01

    Orbital angular momentum (OAM) of graphene electrons in a perpendicular magnetic field is calculated and corresponding magnetic moment is used to investigate the magnetism of perfect graphene. Variation in magnetization demonstrates its decrease with carrier-doping, plateaus in a large field, and de Haas–van Alphen oscillation. Regulation of graphene's magnetism by a parallel electric field is presented. The OAM originates from atomic-scale electronic motion in graphene lattice, and vector hopping interaction between carbon atomic orbitals is the building element. A comparison between OAM of graphene electrons, OAM of Dirac fermions, and total angular momentum of the latter demonstrates their different roles in graphene's magnetism. Applicability and relation to experiments of the results are discussed. - Highlights: • Orbital angular momentum of graphene electrons is calculated. • Orbital magnetic moment of graphene electrons is obtained. • Variation in magnetization of graphene is calculated. • Roles of different kinds of angular momentum are investigated.

  9. Efficient evaluation of angular power spectra and bispectra

    Science.gov (United States)

    Assassi, Valentin; Simonović, Marko; Zaldarriaga, Matias

    2017-11-01

    Angular statistics of cosmological observables are hard to compute. The main difficulty is due to the presence of highly-oscillatory Bessel functions which need to be integrated over. In this paper, we provide a simple and fast method to compute the angular power spectrum and bispectrum of any observable. The method is based on using an FFTlog algorithm to decompose the momentum-space statistics onto a basis of power-law functions. For each power law, the integrals over Bessel functions have a simple analytical solution. This allows us to efficiently evaluate these integrals, independently of the value of the multipole l. In particular, this method significantly speeds up the evaluation of the angular bispectrum compared to existing methods. To illustrate our algorithm, we compute the galaxy, lensing and CMB temperature angular power spectrum and bispectrum.

  10. Phase-space distributions and orbital angular momentum

    Directory of Open Access Journals (Sweden)

    Pasquini B.

    2014-06-01

    Full Text Available We review the concept of Wigner distributions to describe the phase-space distributions of quarks in the nucleon, emphasizing the information encoded in these functions about the quark orbital angular momentum.

  11. Helicons in uniform fields. II. Poynting vector and angular momenta

    Science.gov (United States)

    Stenzel, R. L.; Urrutia, J. M.

    2018-03-01

    The orbital and spin angular momenta of helicon modes have been determined quantitatively from laboratory experiments. The current density is obtained unambiguously from three dimensional magnetic field measurements. The only approximation made is to obtain the electric field from Hall Ohm's law which is usually the case for low frequency whistler modes. This allows the evaluation of the Poynting vector from which the angular momentum is obtained. Comparing two helicon modes (m = 0 and m = 1), one can separate the contribution of angular momentum of a rotating and non-rotating wave field. The orbital angular momentum is important to assess the wave-particle interaction by the transverse Doppler shift of rotating waves which has not been considered so far.

  12. Genetic characterization of angular leaf spot resistance in selected ...

    African Journals Online (AJOL)

    Mr Tryphone

    2015-10-28

    Oct 28, 2015 ... Angular leaf spot disease (ALS) caused by Pseudocercospora griseola is one ... Author(s) agree that this article remains permanently open access under the terms ... that results in shrivelled seeds of reduced size and quality.

  13. prevalence of angular leaf spot disease and sources of resistance

    African Journals Online (AJOL)

    USER

    2017-02-17

    Feb 17, 2017 ... Angular leaf spot (Pseudocercospora griseola Crous U, Brown) is one of the ..... Incidence of six foliar bean diseases in two agro ecological zones of eastern Democratic Republic of .... use of poor quality farmer-saved seed.

  14. Angular distributions of ions channeled in the Si crystals

    International Nuclear Information System (INIS)

    Petrovic, S.; Korica, S.; Kokkoris, M.; Neskovic, N.

    2002-01-01

    In this study we analyze the angular distributions of Ne 10+ ions channeled in the Si crystals. The ion energy is 60 MeV and the crystal thickness is varied from 286 to 3435 nm. This thickness range corresponds to the reduced crystal thickness range from 0.5 to 6, i.e. from the second to the twelfth rainbow cycle. The angular distributions were obtained via the numerical solution of the ion equations of motion and the computer simulation method. The analysis shows that the angular distribution has a periodic behavior. We also analyze the transmission patterns corresponding to the angular distributions. These patterns should be compared to the experimental patterns obtainable by a two-dimensional position sensitive detector. We demonstrate that, when the ion beam divergence is sufficiently large, i.e. much larger than the critical angle for channeling, the channeling star effect occurs in the transmission patterns

  15. Angular Momentum Transport in Quasi-Keplerian Accretion Disks ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Keplerian accretion disk yield results that are inconsistent with the generally accepted model. If correct, the ideas proposed by Hayashi &. Matsuda would radically alter our understanding of the nature of the angular momentum transport in the disk, ...

  16. The mass and angular momentum of reconstructed metric perturbations

    Science.gov (United States)

    van de Meent, Maarten

    2017-06-01

    We prove a key result regarding the mass and angular momentum content of linear vacuum perturbations of the Kerr metric obtained through the formalism developed by Chrzarnowski, Cohen, and Kegeles (CCK). More precisely, we prove that the Abbott-Deser mass and angular momentum integrals of any such perturbation vanish when that perturbation was obtained from a regular Fourier mode of the Hertz potential. As a corollary we obtain a generalization of previous results on the completion of the ‘no string’ radiation gauge metric perturbation generated by a point particle. We find that for any bound orbit around a Kerr black hole, the mass and angular momentum perturbations completing the CCK metric are simply the energy and angular momentum of the particle ‘outside’ the orbit and vanish ‘inside’ the orbit.

  17. Design and Implementation of a Digital Angular Rate Sensor

    Directory of Open Access Journals (Sweden)

    Zhen Peng

    2010-10-01

    Full Text Available With the aim of detecting the attitude of a rotating carrier, the paper presents a novel, digital angular rate sensor. The sensor consists of micro-sensing elements (gyroscope and accelerometer, signal processing circuit and micro-processor (DSP2812. The sensor has the feature of detecting three angular rates of a rotating carrier at the same time. The key techniques of the sensor, including sensing construction, sensing principles, and signal processing circuit design are presented. The test results show that the sensor can sense rolling, pitch and yaw angular rate at the same time and the measurement error of yaw (or pitch angular rate and rolling rate of the rotating carrier is less than 0.5%.

  18. Large-uncertainty intelligent states for angular momentum and angle

    International Nuclear Information System (INIS)

    Goette, Joerg B; Zambrini, Roberta; Franke-Arnold, Sonja; Barnett, Stephen M

    2005-01-01

    The equality in the uncertainty principle for linear momentum and position is obtained for states which also minimize the uncertainty product. However, in the uncertainty relation for angular momentum and angular position both sides of the inequality are state dependent and therefore the intelligent states, which satisfy the equality, do not necessarily give a minimum for the uncertainty product. In this paper, we highlight the difference between intelligent states and minimum uncertainty states by investigating a class of intelligent states which obey the equality in the angular uncertainty relation while having an arbitrarily large uncertainty product. To develop an understanding for the uncertainties of angle and angular momentum for the large-uncertainty intelligent states we compare exact solutions with analytical approximations in two limiting cases

  19. Macrocyclic ligands for uranium complexation

    International Nuclear Information System (INIS)

    Potts, K.T.

    1991-04-01

    A highly preorganized 24-macrocycle containing biuret, thiobiuret and pyridine subunits has been prepared by high dilution ring-closure procedures. Intermediate products to this macrocycle have been utilized to extend this synthetic route to include further representatives where solubility and stability will be influenced by substituent variation. A 1:1 complex has been formed from uranyl acetate and a quinquepyridine derivative, this representing a new type of ligand for the uranyl ion. A very convenient synthetic procedure that will allow the incorporation of these macrocycles into polymeric systems has been developed for the introduction of a vinyl substituent into the 4-position of the pyridine ring. Using triflate, vinyltributyltin and Pd 0 chemistry, this procedure should make a variety of substituted 4-vinylpyridines available for the first time. 3 refs

  20. The Effects of Isokinetic Strength Training on Strength at Different Angular Velocities: a Pilot Study

    Directory of Open Access Journals (Sweden)

    Tuğba Kocahan

    2017-09-01

    Conclusion: It was shown that angular velocity is important in isokinetic training, and that training at high angular velocities provides strength increases at lower angular velocities, but would not increase strength at angular velocities above the training level. For this reason, it is thought that in the preparation of an isokinetic strength training protocol, angular velocities need to be taken into account. For any athlete, the force at the angular velocity required in her/his sports branch needs to be considered.

  1. A Very Fast and Angular Momentum Conserving Tree Code

    International Nuclear Information System (INIS)

    Marcello, Dominic C.

    2017-01-01

    There are many methods used to compute the classical gravitational field in astrophysical simulation codes. With the exception of the typically impractical method of direct computation, none ensure conservation of angular momentum to machine precision. Under uniform time-stepping, the Cartesian fast multipole method of Dehnen (also known as the very fast tree code) conserves linear momentum to machine precision. We show that it is possible to modify this method in a way that conserves both angular and linear momenta.

  2. Existence of black holes due to concentration of angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Khuri, Marcus A. [Department of Mathematics, Stony Brook University,Stony Brook, NY 11794 (United States)

    2015-06-29

    We present a general sufficient condition for the formation of black holes due to concentration of angular momentum. This is expressed in the form of a universal inequality, relating the size and angular momentum of bodies, and is proven in the context of axisymmetric initial data sets for the Einstein equations which satisfy an appropriate energy condition. A brief comparison is also made with more traditional black hole existence criteria based on concentration of mass.

  3. Gamma-gamma angular correlation measurement in the 100 Ru

    International Nuclear Information System (INIS)

    Kenchian, G.

    1990-01-01

    An angular correlation automatic spectrometer with two Ge(Li) detectors has been developed. The spectrometer moves automatically, controlled by a microcomputer. The gamma-gamma directional angular correlations of coincidence transitions have been measured in 100 Ru nuclide, following the β + and electron capture of 100 Rh. The 100 Rh source has been produced with 100 Ru(p,n) 100 Rh reaction, using the proton beam of the Cyclotron Accelerator insiding in 100 Ru isotope. (author)

  4. A Very Fast and Angular Momentum Conserving Tree Code

    Energy Technology Data Exchange (ETDEWEB)

    Marcello, Dominic C., E-mail: dmarce504@gmail.com [Department of Physics and Astronomy, and Center for Computation and Technology Louisiana State University, Baton Rouge, LA 70803 (United States)

    2017-09-01

    There are many methods used to compute the classical gravitational field in astrophysical simulation codes. With the exception of the typically impractical method of direct computation, none ensure conservation of angular momentum to machine precision. Under uniform time-stepping, the Cartesian fast multipole method of Dehnen (also known as the very fast tree code) conserves linear momentum to machine precision. We show that it is possible to modify this method in a way that conserves both angular and linear momenta.

  5. Analytical scheme calculations of angular momentum coupling and recoupling coefficients

    Science.gov (United States)

    Deveikis, A.; Kuznecovas, A.

    2007-03-01

    We investigate the Scheme programming language opportunities to analytically calculate the Clebsch-Gordan coefficients, Wigner 6j and 9j symbols, and general recoupling coefficients that are used in the quantum theory of angular momentum. The considered coefficients are calculated by a direct evaluation of the sum formulas. The calculation results for large values of quantum angular momenta were compared with analogous calculations with FORTRAN and Java programming languages.

  6. Analytical scheme calculations of angular momentum coupling and recoupling coefficients

    International Nuclear Information System (INIS)

    Deveikis, A.; Kuznecovas, A.

    2007-01-01

    We investigate the Scheme programming language opportunities to analytically calculate the Clebsch-Gordan coefficients, Wigner 6j and 9j symbols, and general recoupling coefficients that are used in the quantum theory of angular momentum. The considered coefficients are calculated by a direct evaluation of the sum formulas. The calculation results for large values of quantum angular momenta were compared with analogous calculations with FORTRAN and Java programming languages

  7. Orbital and angular motion construction for low thrust interplanetary flight

    Science.gov (United States)

    Yelnikov, R. V.; Mashtakov, Y. V.; Ovchinnikov, M. Yu.; Tkachev, S. S.

    2016-11-01

    Low thrust interplanetary flight is considered. Firstly, the fuel-optimal control is found. Then the angular motion is synthesized. This motion provides the thruster tracking of the required by optimal control direction. And, finally, reaction wheel control law for tracking this angular motion is proposed and implemented. The numerical example is given and total operation time for thrusters is found. Disturbances from solar pressure, thrust eccentricity, inaccuracy of reaction wheels installation and errors of inertia tensor are taken into account.

  8. Spatial Angular Compounding for Elastography without the Incompressibility Assumption

    OpenAIRE

    Rao, Min; Varghese, Tomy

    2005-01-01

    Spatial-angular compounding is a new technique that enables the reduction of noise artifacts in ultrasound elastography. Previous results using spatial angular compounding, however, were based on the use of the tissue incompressibility assumption. Compounded elastograms were obtained from a spatially-weighted average of local strain estimated from radiofrequency echo signals acquired at different insonification angles. In this paper, we present a new method for reducing the noise artifacts in...

  9. Diffraction by a plane angular sector, a new derivation

    DEFF Research Database (Denmark)

    Hansen, Thokild B.

    1990-01-01

    An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)......An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)...

  10. Shape coexistence in 72Kr at finite angular momentum

    International Nuclear Information System (INIS)

    Almehed, Daniel; Walet, Niels R.

    2004-01-01

    We investigate shape coexistence in a rotating nucleus. We concentrate on the case of 72 Kr which exhibits an interesting interplay between prolate and oblate shaped states as a function of angular momentum. The calculation uses the local harmonic version of the method of self-consistent adiabatic large-amplitude collective motion. We analyse how the collective behaviour of the system changes with angular momentum and we focus on the role of non-axial shapes

  11. Spin and intrinsic angular momentum; application to the electromagnetic field

    International Nuclear Information System (INIS)

    Paillere, P.

    1993-05-01

    Within the framework of the field theory governed by a Lagrangian, function of the tensor quantities and their covariant first derivatives, and starting with the third order intrinsic angular momentum tensor obtained from a variational principle, the intrinsic angular momentum vector of the electromagnetic field in vacuum is determined. This expression leads to spin matrices for the electromagnetic field, with unity as eigenvalue, thus allowing to bridge the gap between continuous physics and quantum physics. 6 refs

  12. Effects of angular misalignment on optical klystron undulator radiation

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, G., E-mail: gmishra_dauniv@yahoo.co.in; Prakash, Bramh; Gehlot, Mona

    2015-11-21

    In this paper ,we analyze the important effects of optical klystron undulator radiation with an angular offset of the relativistic electron beam in the second undulator section. An anlytical expression for the undulator radiation is obtained through a transparent and simple procedure.It is shown that the effects of the angular offset is more severe for longer undulator lengths and with higher dispersive field strengths.Both these effects are less pronounced for undulators with large K values.

  13. CXCR4 Ligands : The Next Big Hit?

    NARCIS (Netherlands)

    Walenkamp, Annemiek M. E.; Lapa, Constantin; Herrmann, Ken; Wester, Hans-Juergen

    2017-01-01

    The G protein-coupled protein receptor C-X-C chemokine receptor 4 (CXCR4) is an attractive target for cancer diagnosis and treatment, as it is overexpressed in many solid and hematologic cancers. Binding of its ligand, C-X-C chemokine ligand 12 (CXCL12), results in receptor internalization and

  14. Ligand-receptor Interactions by NMR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Novak. P.

    2008-04-01

    Full Text Available Today NMR spectroscopy is a method of choice for elucidation of interactions between biomolecules and the potential ligands. Knowledge on these interactions is an essential prerequisite for the rational drug design. The most important contribution of NMR to drug design a few years ago was the 3D structure determination of proteins. Besides delivering the 3D structures of the free proteins as a raw material for the modeling studies on ligand binding, NMR can directly yield valuable experimental data on the biologically important protein-ligand complexes. In addition to X-ray diffraction, NMR spectroscopy can provide information on the internal protein dynamics ordynamics of intermolecular interactions. Changes in NMR parameters allow us to detect ("SAR by NMR" and quantitatively determine binding affinities (titration, diffusion NMR experiments, etc. of potential ligands. Also, it is possible to determine the binding site and conformations of ligands, receptors and receptor-ligand complexes with the help of NMR methods such as tr-NOESY. Epitopes or functional groups responsible for binding of ligands to the receptor can be identified by employing STD or WaterLOGSY experiments. In this review are described some of the most frequent NMR methods for the characterization of the interactions between biomolecules and ligands, together with their advantages and disadvantages.

  15. Autocrine signal transmission with extracellular ligand degradation

    Science.gov (United States)

    Muratov, C B; Posta, F; Shvartsman, S Y

    2009-03-01

    Traveling waves of cell signaling in epithelial layers orchestrate a number of important processes in developing and adult tissues. These waves can be mediated by positive feedback autocrine loops, a mode of cell signaling where binding of a diffusible extracellular ligand to a cell surface receptor can lead to further ligand release. We formulate and analyze a biophysical model that accounts for ligand-induced ligand release, extracellular ligand diffusion and ligand-receptor interaction. We focus on the case when the main mode for ligand degradation is extracellular and analyze the problem with the sharp threshold positive feedback nonlinearity. We derive expressions that link the speed of propagation and other characteristics of traveling waves to the parameters of the biophysical processes, such as diffusion rates, receptor expression level, etc. Analyzing the derived expressions we found that traveling waves in such systems can exhibit a number of unusual properties, e.g. non-monotonic dependence of the speed of propagation on ligand diffusivity. Our results for the fully developed traveling fronts can be used to analyze wave initiation from localized perturbations, a scenario that frequently arises in the in vitro models of epithelial wound healing, and guide future modeling studies of cell communication in epithelial layers.

  16. Organotellurium ligands – designing and complexation reactions

    Indian Academy of Sciences (India)

    Unknown

    membered rings it is negative and ~30 ppm only. Keywords. Organotellurium ligands; hybrid telluroether; platinum metal complexes; tellurium-125 NMR. 1. Introduction. Tellurium is the noblest metalloid which may act as a Lewis acid as well as Lewis base. The ligand chemistry of tellurium, which acts as a 'soft' donor, was ...

  17. Angular momentum of circularly polarized light in dielectric media

    Science.gov (United States)

    Mansuripur, Masud

    2005-07-01

    A circularly polarized plane-wave is known to have no angular momentum when examined through Maxwell’s equations. This, however, contradicts the experimentally observed facts, where finite segments of plane waves are known to be capable of imparting angular momentum to birefringent platelets. Using a superposition of four plane-waves propagating at slightly different angles to a common direction, we derive an expression for the angular momentum density of a single plane-wave in the limit when the propagation directions of the four beams come into alignment. We proceed to use this four-beam technique to analyze the conservation of angular momentum when a plane-wave enters a dielectric slab from the free space. The angular momentum of the beam is shown to decrease upon entering the dielectric medium, by virtue of the fact that the incident beam exerts a torque on the slab surface at the point of entry. When the beam leaves the slab, it imparts an equal but opposite torque to the exit facet, thus recovering its initial angular momentum upon re-emerging into the free-space. Along the way, we derive an expression for the outward-directed force of a normally incident, finite-diameter beam on a dielectric surface; the possible relationship between this force and the experimentally observed bulging of a liquid surface under intense illumination is explored.

  18. Investigation of angular and axial smoothing of PET data

    International Nuclear Information System (INIS)

    Daube-Witherspoon, M.E.; Carson, R.E.

    1996-01-01

    Radial filtering of emission and transmission data is routinely performed in PET during reconstruction in order to reduce image noise. Angular smoothing is not typically done, due to the introduction of a non-uniform resolution loss; axial filtering is also not usually performed on data acquired in 2D mode. The goal of this paper was to assess the effects of angular and axial smoothing on noise and resolution. Angular and axial smoothing was incorporated into the reconstruction process on the Scanditronix PC2048-15B brain PET scanner. In-plane spatial resolution and noise reduction were measured for different amounts of radial and angular smoothing. For radial positions away from the center of the scanner, noise reduction and degraded tangential resolution with no loss of radial resolution were seen. Near the center, no resolution loss was observed, but there was also no reduction in noise for angular filters up to a 7 degrees FWHM. These results can be understood by considering the combined effects of smoothing projections across rows (angles) and then summing (backprojecting). Thus, angular smoothing is not optimal due to its anisotropic noise reduction and resolution degradation properties. However, uniform noise reduction comparable to that seen with radial filtering can be achieved with axial smoothing of transmission data. The axial results suggest that combined radial and axial transmission smoothing could lead to improved noise characteristics with more isotropic resolution degradation

  19. A systematic construction of microstate geometries with low angular momentum

    Science.gov (United States)

    Bena, Iosif; Heidmann, Pierre; Ramírez, Pedro F.

    2017-10-01

    We outline a systematic procedure to obtain horizonless microstate geometries that have the same charges as three-charge five-dimensional black holes with a macroscopically-large horizon area and an arbitrarily-small angular momentum. There are two routes through which such solutions can be constructed: using multi-center Gibbons-Hawking (GH) spaces or using superstratum technology. So far the only solutions corre-sponding to microstate geometries for black holes with no angular momentum have been obtained via superstrata [1], and multi-center Gibbons-Hawking spaces have been believed to give rise only to microstate geometries of BMPV black holes with a large angular mo-mentum [2]. We perform a thorough search throughout the parameter space of smooth horizonless solutions with four GH centers and find that these have an angular momentum that is generally larger than 80% of the cosmic censorship bound. However, we find that solutions with three GH centers and one supertube (which are smooth in six-dimensional supergravity) can have an arbitrarily-low angular momentum. Our construction thus gives a recipe to build large classes of microstate geometries for zero-angular-momentum black holes without resorting to superstratum technology.

  20. Effect of nutritional intake towards Angular cheilitis of orphanage children

    Directory of Open Access Journals (Sweden)

    Nurdiani Rakhmayanthie

    2016-11-01

    Full Text Available Introduction: Angular cheilitis is one of the oral manifestations of iron, vitamin B12, and folate deficiency. This manifestation frequently seen in people at first and second decade. The purpose of this study was to obtain the prevalence of angular cheilitis and its classifications related to the nutritional intake level in 6-18 years old children. Methods: This research was a descriptive study with 53 children between 6-18 years old from Muhammadiyah Orphanage Bandung as the samples. The oral cavity was examined clinically and their food consumption in a week was noted in Food Recall 24 hours and Food Frequency Questionnaire (FFQ in order to measure their nutritional intake level. Results: There are 23 children with angular cheilitis. 13% has iron and folate deficiencies, and 87% has iron, vitamin B12, and folate deficiencies. Angular cheilitis types that has been found are Type I (39%, Type II (48% and Type III (13%. Conclusion: The prevalence of angular cheilitis in 6-18 years old children in Muhammadiyah Orphanage Bandung was moderately high, most of them were having iron, vitamin B12, and folate deficiencies. Type II angular cheilitis was the most frequently seen.

  1. The Angular Momentum of Baryons and Dark Matter Halos Revisited

    Science.gov (United States)

    Kimm, Taysun; Devriendt, Julien; Slyz, Adrianne; Pichon, Christophe; Kassin, Susan A.; Dubois, Yohan

    2011-01-01

    Recent theoretical studies have shown that galaxies at high redshift are fed by cold, dense gas filaments, suggesting angular momentum transport by gas differs from that by dark matter. Revisiting this issue using high-resolution cosmological hydrodynamics simulations with adaptive-mesh refinement (AMR), we find that at the time of accretion, gas and dark matter do carry a similar amount of specific angular momentum, but that it is systematically higher than that of the dark matter halo as a whole. At high redshift, freshly accreted gas rapidly streams into the central region of the halo, directly depositing this large amount of angular momentum within a sphere of radius r = 0.1R(sub vir). In contrast, dark matter particles pass through the central region unscathed, and a fraction of them ends up populating the outer regions of the halo (r/R(sub vir) > 0.1), redistributing angular momentum in the process. As a result, large-scale motions of the cosmic web have to be considered as the origin of gas angular momentum rather than its virialised dark matter halo host. This generic result holds for halos of all masses at all redshifts, as radiative cooling ensures that a significant fraction of baryons remain trapped at the centre of the halos. Despite this injection of angular momentum enriched gas, we predict an amount for stellar discs which is in fair agreement with observations at z=0. This arises because the total specific angular momentum of the baryons (gas and stars) remains close to that of dark matter halos. Indeed, our simulations indicate that any differential loss of angular momentum amplitude between the two components is minor even though dark matter halos continuously lose between half and two-thirds of their specific angular momentum modulus as they evolve. In light of our results, a substantial revision of the standard theory of disc formation seems to be required. We propose a new scenario where gas efficiently carries the angular momentum generated

  2. Diverse assemblies of the (4,4) grid layers exemplified in Zn(II)/Co(II) coordination polymers with dual linear ligands

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Guang-Zhen; Li, Xiao-Dong; Xin, Ling-Yun; Li, Xiao-Ling [College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022 (China); Wang, Li-Ya, E-mail: wlya@lynu.edu.cn [College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022 (China); College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan 473061 (China)

    2013-07-15

    Diverse (4,4) grid layers are exemplified in five two-dimensional coordination polymers with dual µ{sub 2}-bridged ligands, namely, ([Zn(cbaa)(bpp)]·H{sub 2}O){sub n} (1), [Zn{sub 2}(cbaa){sub 2}(bpy)]{sub n} (2), [Co{sub 2}(cbaa){sub 2}(bpp){sub 2}]{sub n} (3), [Co(cbaa)(bpp)]{sub n} (4), and [Co(bdaa)(bpp)(H{sub 2}O){sub 2}]{sub n} (5) (H{sub 2}cbaa=4-carboxybenzeneacetic acid, bpp=1,3-di(4-pyridyl)propane, bpy=4,4′-bipyridyl, and H{sub 2}bdaa=1,4-benzenediacrylic acid). For 1, two (4,4) grid layers with [ZnN{sub 2}O{sub 2}] tetrahedron as the node are held together by lattice water forming a H-bonding bilayer. Individual (4,4) grid layer in 2 is based on (Zn{sub 2}(OCO){sub 4}) paddlewheel unit as the node. Two (4,4) grid layers with (Co{sub 2}O(OCO){sub 2}) dimer as the node are covalently interconnected by organic ligands affording a thick bilayer of 3 with new framework topology. The different entanglements between two coincident (4,4) grid layers with [CoN{sub 2}O{sub 4}] octahedron as the node leads to two 2D→2D interpenetrated structures for 4 and 5. Furthermore, fluorescent properties of 1 and 2 as well as magnetic properties of 3 are investigated. - Graphical abstract: Diverse assemblies of the (4,4) grid layers with different network nodes forms five coordination polymers that are well characterized by IR, TGA, element analysis, fluorescent and magnetic measurement. - Highlights: • Diverse assemblies of the (4,4) grid layers with different structural units as the nodes. • A new topology type with the uninodal 6-connected net of (4{sup 12}.5{sup 2}.6) is found. • Intense fluorescence emissions with a rare blue-shift of 55 nm compared to free carboxylate ligand.

  3. Initial angular momentum and flow in high energy nuclear collisions

    Science.gov (United States)

    Fries, Rainer J.; Chen, Guangyao; Somanathan, Sidharth

    2018-03-01

    We study the transfer of angular momentum in high energy nuclear collisions from the colliding nuclei to the region around midrapidity, using the classical approximation of the color glass condensate (CGC) picture. We find that the angular momentum shortly after the collision (up to times ˜1 /Qs , where Qs is the saturation scale) is carried by the "β -type" flow of the initial classical gluon field, introduced by some of us earlier. βi˜μ1∇iμ2-μ2∇iμ1 (i =1 ,2 ) describes the rapidity-odd transverse energy flow and emerges from Gauss's law for gluon fields. Here μ1 and μ2 are the averaged color charge fluctuation densities in the two nuclei, respectively. Interestingly, strong coupling calculations using anti-de Sitter/conformal field theory (AdS/CFT) techniques also find an energy flow term featuring this particular combination of nuclear densities. In classical CGC the order of magnitude of the initial angular momentum per rapidity in the reaction plane, at a time 1 /Qs , is |d L2/d η |≈ RAQs-3ɛ¯0/2 at midrapidity, where RA is the nuclear radius, and ɛ¯0 is the average initial energy density. This result emerges as a cancellation between a vortex of energy flow in the reaction plane aligned with the total angular momentum, and energy shear flow opposed to it. We discuss in detail the process of matching classical Yang-Mills results to fluid dynamics. We will argue that dissipative corrections should not be discarded to ensure that macroscopic conservation laws, e.g., for angular momentum, hold. Viscous fluid dynamics tends to dissipate the shear flow contribution that carries angular momentum in boost-invariant fluid systems. This leads to small residual angular momentum around midrapidity at late times for collisions at high energies.

  4. Isotropic gates and large gamma detector arrays versus angular distributions

    International Nuclear Information System (INIS)

    Iacob, V.E.; Duchene, G.

    1997-01-01

    Angular information extracted from in-beam γ ray measurements are of great importance for γ ray multipolarity and nuclear spin assignments. In our days large Ge detector arrays became available allowing the measurements of extremely weak γ rays in almost 4π sr solid angle (e.g., EUROGAM detector array). Given the high detector efficiency it is common for the mean suppressed coincidence multiplicity to reach values as high as 4 to 6. Thus, it is possible to gate on particular γ rays in order to enhance the relative statistics of a definite reaction channel and/or a definite decaying path in the level scheme of the selected residual nucleus. As compared to angular correlations, the conditioned angular distribution spectra exhibit larger statistics because in the latter the gate-setting γ ray may be observed by all the detectors in the array, relaxing somehow the geometrical restrictions of the angular correlations. Since the in-beam γ ray emission is anisotropic one could inquire that gate setting as mentioned above, based on anisotropic γ ray which would perturb the angular distributions in the unfolded events. As our work proved, there is no reason to worry about this if the energy gate runs over the whole solid angle in an ideal 4π sr detector, i.e., if the gate is isotropic. In real quasi 4π sr detector arrays the corresponding quasi isotropic gate preserves the angular properties of the unfolded data, too. However extraction of precise angular distribution coefficient especially a 4 , requires the consideration of the deviation of the quasi isotropic gate relative to the (ideal) isotropic gate

  5. Smoothed dissipative particle dynamics with angular momentum conservation

    Energy Technology Data Exchange (ETDEWEB)

    Müller, Kathrin, E-mail: k.mueller@fz-juelich.de; Fedosov, Dmitry A., E-mail: d.fedosov@fz-juelich.de; Gompper, Gerhard, E-mail: g.gompper@fz-juelich.de

    2015-01-15

    Smoothed dissipative particle dynamics (SDPD) combines two popular mesoscopic techniques, the smoothed particle hydrodynamics and dissipative particle dynamics (DPD) methods, and can be considered as an improved dissipative particle dynamics approach. Despite several advantages of the SDPD method over the conventional DPD model, the original formulation of SDPD by Español and Revenga (2003) [9], lacks angular momentum conservation, leading to unphysical results for problems where the conservation of angular momentum is essential. To overcome this limitation, we extend the SDPD method by introducing a particle spin variable such that local and global angular momentum conservation is restored. The new SDPD formulation (SDPD+a) is directly derived from the Navier–Stokes equation for fluids with spin, while thermal fluctuations are incorporated similarly to the DPD method. We test the new SDPD method and demonstrate that it properly reproduces fluid transport coefficients. Also, SDPD with angular momentum conservation is validated using two problems: (i) the Taylor–Couette flow with two immiscible fluids and (ii) a tank-treading vesicle in shear flow with a viscosity contrast between inner and outer fluids. For both problems, the new SDPD method leads to simulation predictions in agreement with the corresponding analytical theories, while the original SDPD method fails to capture properly physical characteristics of the systems due to violation of angular momentum conservation. In conclusion, the extended SDPD method with angular momentum conservation provides a new approach to tackle fluid problems such as multiphase flows and vesicle/cell suspensions, where the conservation of angular momentum is essential.

  6. Correcting ligands, metabolites, and pathways

    Directory of Open Access Journals (Sweden)

    Vriend Gert

    2006-11-01

    Full Text Available Abstract Background A wide range of research areas in bioinformatics, molecular biology and medicinal chemistry require precise chemical structure information about molecules and reactions, e.g. drug design, ligand docking, metabolic network reconstruction, and systems biology. Most available databases, however, treat chemical structures more as illustrations than as a datafield in its own right. Lack of chemical accuracy impedes progress in the areas mentioned above. We present a database of metabolites called BioMeta that augments the existing pathway databases by explicitly assessing the validity, correctness, and completeness of chemical structure and reaction information. Description The main bulk of the data in BioMeta were obtained from the KEGG Ligand database. We developed a tool for chemical structure validation which assesses the chemical validity and stereochemical completeness of a molecule description. The validation tool was used to examine the compounds in BioMeta, showing that a relatively small number of compounds had an incorrect constitution (connectivity only, not considering stereochemistry and that a considerable number (about one third had incomplete or even incorrect stereochemistry. We made a large effort to correct the errors and to complete the structural descriptions. A total of 1468 structures were corrected and/or completed. We also established the reaction balance of the reactions in BioMeta and corrected 55% of the unbalanced (stoichiometrically incorrect reactions in an automatic procedure. The BioMeta database was implemented in PostgreSQL and provided with a web-based interface. Conclusion We demonstrate that the validation of metabolite structures and reactions is a feasible and worthwhile undertaking, and that the validation results can be used to trigger corrections and improvements to BioMeta, our metabolite database. BioMeta provides some tools for rational drug design, reaction searches, and

  7. Autocrine signal transmission with extracellular ligand degradation

    International Nuclear Information System (INIS)

    Muratov, C B; Posta, F; Shvartsman, S Y

    2009-01-01

    Traveling waves of cell signaling in epithelial layers orchestrate a number of important processes in developing and adult tissues. These waves can be mediated by positive feedback autocrine loops, a mode of cell signaling where binding of a diffusible extracellular ligand to a cell surface receptor can lead to further ligand release. We formulate and analyze a biophysical model that accounts for ligand-induced ligand release, extracellular ligand diffusion and ligand–receptor interaction. We focus on the case when the main mode for ligand degradation is extracellular and analyze the problem with the sharp threshold positive feedback nonlinearity. We derive expressions that link the speed of propagation and other characteristics of traveling waves to the parameters of the biophysical processes, such as diffusion rates, receptor expression level, etc. Analyzing the derived expressions we found that traveling waves in such systems can exhibit a number of unusual properties, e.g. non-monotonic dependence of the speed of propagation on ligand diffusivity. Our results for the fully developed traveling fronts can be used to analyze wave initiation from localized perturbations, a scenario that frequently arises in the in vitro models of epithelial wound healing, and guide future modeling studies of cell communication in epithelial layers

  8. Radiation induced ligand loss from cobalt complexes

    International Nuclear Information System (INIS)

    Funston, A. M.; McFadyen, W.D.; Tregloan, P.A.

    2000-01-01

    Full text: Due to the rapid nature of ligand dissociation from cobalt(II) complexes the study of the rate of ligand dissociation necessitates the use of a technique such as pulse radiolysis. This allows the rapid reduction of the corresponding cobalt(III) complex by a reducing radical, such as the aquated electron, to form the cobalt(II) complex. However, to date, no systematic study of either the mechanism of reduction or the influence of the electronic structure on the rate of ligand dissociation has been carried out. In order to understand these processes more fully the mechanism of reduction of a range of related cobalt(III) complexes by the aquated electron and the subsequent rate of ligand dissociation from the resulting cobalt(II) complexes is being investigated. It has been found that a number of processes are observed following the initial rapid reaction of the cobalt(III) complex with the aquated electron. Ultimately ligand loss is observed. Depending upon the complex, the initial processes observed may include the formation of coordinated radicals and electron transfer within the complex. For complexes containing aromatic ligands such as 2,2'-bipyridine, 1,10-phenanthroline and dipyrido[3,2-a:2',3'-c]phenazine the formation of a coordinated radical is observed as the initial reduction step. The kinetics of ligand dissociation of these complexes has been determined. The loss of monodentate ligands is fast and has been indistinguishable from the reduction processes when aromatic ligands are also present in the complex. However, for diamine chelates and diimine chelates spectra of the transient species can be resolved

  9. Labeled receptor ligands for spect

    International Nuclear Information System (INIS)

    Kung, H.F.

    1989-01-01

    Receptor specific imaging agents for single photon emission computed tomography (SPECT) can potentially be useful in the understanding of basic biochemistry and pharmacology of receptors. SPECT images may also provide tools for evaluation of density and binding kinetics of a specific receptor, information important for diagnosis and patient management. Basic requirements for receptor imaging agents are: (a) they are labeled with short-lived isotopes, (b) they show high selectivity and specific uptake, (c) they exhibit high target/background ratio, and (d) they can be modeled to obtain quantitative information. Several good examples of CNS receptor specific ligands labeled with I-123 have been developed, including iodoQNB, iodoestrogen iodobenzadiazepine, iodobenazepine, iodobenzamides for muscarinic, estrogen benzadiazepine, D-1 and D-2 dopamine receptors. With the advent of newer and faster SPECT imaging devices, it may be feasible to quantitate the receptor density by in vivo imaging techniques. These new brain imaging agents can provide unique diagnostic information, which may not be available through other imaging modalities, such as CT and MRI

  10. A Versatile Dinucleating Ligand Containing Sulfonamide Groups

    DEFF Research Database (Denmark)

    Sundberg, Jonas; Witt, Hannes; Cameron, Lisa

    2014-01-01

    ligand can be prepared in aqueous solutions using only divalent metal ions. Two of the copper(II) complexes, [Cu2(psmp)(OH)] and [Cu2(psmp)(OAc)2]-, demonstrate the anticipated 1:2 ligand/metal stoichiometry and show that the dimetallic binding site created for exogenous ligands possesses high inherent...... of antiferromagnetic coupling. This is corroborated computationally by broken-symmetry density functional theory, which for isotropic modeling of the coupling predicts an antiferromagnetic coupling strength of J = 70.5 cm-1....

  11. Modeling of the angular dependence of plasma etching

    International Nuclear Information System (INIS)

    Guo Wei; Sawin, Herbert H.

    2009-01-01

    An understanding of the angular dependence of etching yield is essential to investigate the origins of sidewall roughness during plasma etching. In this article the angular dependence of polysilicon etching in Cl 2 plasma was modeled as a combination of individual angular-dependent etching yields for ion-initiated processes including physical sputtering, ion-induced etching, vacancy generation, and removal. The modeled etching yield exhibited a maximum at ∼60 degree sign off-normal ion angle at low flux ratio, indicative of physical sputtering. It transformed to the angular dependence of ion-induced etching with the increase in the neutral-to-ion flux ratio. Good agreement between the modeling and the experiments was achieved for various flux ratios and ion energies. The variation of etching yield in response to the ion angle was incorporated in the three-dimensional profile simulation and qualitative agreement was obtained. The surface composition was calculated and compared to x-ray photoelectron spectroscopy (XPS) analysis. The modeling indicated a Cl areal density of 3x10 15 atoms/cm 2 on the surface that is close to the value determined by the XPS analysis. The response of Cl fraction to ion energy and flux ratio was modeled and correlated with the etching yields. The complete mixing-layer kinetics model with the angular dependence effect will be used for quantitative surface roughening analysis using a profile simulator in future work.

  12. Time variations of the angular momentum of the sun

    International Nuclear Information System (INIS)

    Schatten, K.H.

    1977-01-01

    Time variations of density models of the Sun are investigated. This is an attempt to estimate the changing moment of inertia of the Sun in order to calculate the internal solar angular velocity based upon Newton's equation of motion. Previous estimates of dI/dt disagree with those based upon central densities in a homologously contracting model. It is shown that the homologously contracting model leads to large errors in dI/dt. Based upon an integration of Sears's solar model, dI/dt=-5.5 x 10 34 gm cm 2 s -1 . This suggests a core angular velocity of /sub thetar-italic/ = (0.15 +- 0.03) x 10 -3 s -1 , corresponding to a period of 0.5 +- 0.1 days, assuming a constant angular velocity with time. The brackets indicate a weighting which is discussed

  13. Nuclear level density variation with angular momentum induced shape transition

    International Nuclear Information System (INIS)

    Aggarwal, Mamta

    2016-01-01

    Variation of Nuclear level density (NLD) with the excitation energy and angular momentum in particular has been a topic of interest in the recent past and there have been continuous efforts in this direction on the theoretical and experimental fronts but a conclusive trend in the variation of nuclear level density parameter with angular momentum has not been achieved so far. A comprehensive investigation of N=68 isotones around the compound nucleus 119 Sb from neutron rich 112 Ru (Z=44) to neutron deficient 127 Pr (Z= 59) nuclei is presented to understand the angular momentum induced variations in inverse level density parameter and the possible influence of deformation and structural transitions on the variations on NLd

  14. Orbital Angular Momentum Multiplexing over Visible Light Communication Systems

    Science.gov (United States)

    Tripathi, Hardik Rameshchandra

    This thesis proposes and explores the possibility of using Orbital Angular Momentum multiplexing in Visible Light Communication system. Orbital Angular Momentum is mainly applied for laser and optical fiber transmissions, while Visible Light Communication is a technology using the light as a carrier for wireless communication. In this research, the study of the state of art and experiments showing some results on multiplexing based on Orbital Angular Momentum over Visible Light Communication system were done. After completion of the initial stage; research work and simulations were performed on spatial multiplexing over Li-Fi channel modeling. Simulation scenarios which allowed to evaluate the Signal-to-Noise Ratio, Received Power Distribution, Intensity and Illuminance were defined and developed.

  15. Angular Magnetoresistance of Nanowires with Alternating Cobalt and Nickel Segments

    KAUST Repository

    Mohammed, Hanan

    2017-06-22

    Magnetization reversal in segmented Co/Ni nanowires with varying number of segments was studied using angular Magnetoresistance (MR) measurements on isolated nanowires. The MR measurements offer an insight into the pinning of domain walls within the nanowires. Angular MR measurements were performed on nanowires with two and multiple segments by varying the angle between the applied magnetic field and nanowire (−90° ≤θ≤90°). The angular MR measurements reveal that at lower values of θ the switching fields are nearly identical for the multisegmented and two-segmented nanowires, whereas at higher values of θ, a decrease in the switching field is observed in the case of two segmented nanowires. The two segmented nanowires generally exhibit a single domain wall pinning event, whereas an increased number of pinning events are characteristic of the multisegmented nanowires at higher values of θ. In-situ magnetic force microscopy substantiates reversal by domain wall nucleation and propagation in multisegmented nanowires.

  16. ANGULAR LIGHT-SCATTERING STUDIES ON ISOLATED MITOCHONDRIA

    Science.gov (United States)

    Gotterer, Gerald S.; Thompson, Thomas E.; Lehninger, Albert L.

    1961-01-01

    Angular light-scattering studies have been carried out on suspensions of isolated rat liver mitochondria. The angular scatter pattern has a large forward component, typical of large particles. Changes in dissymmetry and in the intensity of light scattered at 90° have been correlated with changes in optical density during the course of mitochondrial swelling and contraction. Such changes can be measured at mitochondrial concentrations much below those required for optical density measurements. Changes in mitochondrial geometry caused by factors "leaking" from mitochondria, not detectable by optical density measurements, have been demonstrated by measuring changes in dissymmetry. Angular light-scattering measurements therefore offer the advantages of increased sensitivity and of added indices of changes in mitochondrial conformation. PMID:19866589

  17. Characteristic evolutions in numerical relativity using six angular patches

    International Nuclear Information System (INIS)

    Reisswig, Christian; Bishop, Nigel T; Lai, Chi Wai; Thornburg, Jonathan; Szilagyi, Bela

    2007-01-01

    The characteristic approach to numerical relativity is a useful tool in evolving gravitational systems. In the past this has been implemented using two patches of stereographic angular coordinates. In other applications, a six-patch angular coordinate system has proved effective. Here we investigate the use of a six-patch system in characteristic numerical relativity, by comparing an existing two-patch implementation (using second-order finite differencing throughout) with a new six-patch implementation (using either second- or fourth-order finite differencing for the angular derivatives). We compare these different codes by monitoring the Einstein constraint equations, numerically evaluated independently from the evolution. We find that, compared to the (second-order) two-patch code at equivalent resolutions, the errors of the second-order six-patch code are smaller by a factor of about 2, and the errors of the fourth-order six-patch code are smaller by a factor of nearly 50

  18. Measuring average angular velocity with a smartphone magnetic field sensor

    Science.gov (United States)

    Pili, Unofre; Violanda, Renante

    2018-02-01

    The angular velocity of a spinning object is, by standard, measured using a device called a tachometer. However, by directly using it in a classroom setting, the activity is likely to appear as less instructive and less engaging. Indeed, some alternative classroom-suitable methods for measuring angular velocity have been presented. In this paper, we present a further alternative that is smartphone-based, making use of the real-time magnetic field (simply called B-field in what follows) data gathering capability of the B-field sensor of the smartphone device as the timer for measuring average rotational period and average angular velocity. The in-built B-field sensor in smartphones has already found a number of uses in undergraduate experimental physics. For instance, in elementary electrodynamics, it has been used to explore the well-known Bio-Savart law and in a measurement of the permeability of air.

  19. Angular Momentum Transport in Turbulent Flow between Independently Rotating Cylinders

    International Nuclear Information System (INIS)

    Paoletti, M. S.; Lathrop, D. P.

    2011-01-01

    We present measurements of the angular momentum flux (torque) in Taylor-Couette flow of water between independently rotating cylinders for all regions of the (Ω 1 , Ω 2 ) parameter space at high Reynolds numbers, where Ω 1 (Ω 2 ) is the inner (outer) cylinder angular velocity. We find that the Rossby number Ro=(Ω 1 -Ω 2 )/Ω 2 fully determines the state and torque G as compared to G(Ro=∞)≡G ∞ . The ratio G/G ∞ is a linear function of Ro -1 in four sections of the parameter space. For flows with radially increasing angular momentum, our measured torques greatly exceed those of previous experiments [Ji et al., Nature (London), 444, 343 (2006)], but agree with the analysis of Richard and Zahn [Astron. Astrophys. 347, 734 (1999)].

  20. Angular Magnetoresistance of Nanowires with Alternating Cobalt and Nickel Segments

    KAUST Repository

    Mohammed, Hanan; Corte-Leon, H.; Ivanov, Yurii P.; Moreno, J. A.; Kazakova, O.; Kosel, Jü rgen

    2017-01-01

    Magnetization reversal in segmented Co/Ni nanowires with varying number of segments was studied using angular Magnetoresistance (MR) measurements on isolated nanowires. The MR measurements offer an insight into the pinning of domain walls within the nanowires. Angular MR measurements were performed on nanowires with two and multiple segments by varying the angle between the applied magnetic field and nanowire (−90° ≤θ≤90°). The angular MR measurements reveal that at lower values of θ the switching fields are nearly identical for the multisegmented and two-segmented nanowires, whereas at higher values of θ, a decrease in the switching field is observed in the case of two segmented nanowires. The two segmented nanowires generally exhibit a single domain wall pinning event, whereas an increased number of pinning events are characteristic of the multisegmented nanowires at higher values of θ. In-situ magnetic force microscopy substantiates reversal by domain wall nucleation and propagation in multisegmented nanowires.

  1. Characteristic evolutions in numerical relativity using six angular patches

    Energy Technology Data Exchange (ETDEWEB)

    Reisswig, Christian [Max-Planck-Institut fuer Gravitationsphysik, Albert-Einstein-Institut, Am Muehlenberg 1, D-14476 Golm (Germany); Bishop, Nigel T [Department of Mathematical Sciences, University of South Africa, PO Box 392, Unisa 0003, South Africa (South Africa); Lai, Chi Wai [Department of Mathematical Sciences, University of South Africa, PO Box 392, Unisa 0003, South Africa (South Africa); Thornburg, Jonathan [Max-Planck-Institut fuer Gravitationsphysik, Albert-Einstein-Institut, Am Muehlenberg 1, D-14476 Golm (Germany); Szilagyi, Bela [Max-Planck-Institut fuer Gravitationsphysik, Albert-Einstein-Institut, Am Muehlenberg 1, D-14476 Golm (Germany)

    2007-06-21

    The characteristic approach to numerical relativity is a useful tool in evolving gravitational systems. In the past this has been implemented using two patches of stereographic angular coordinates. In other applications, a six-patch angular coordinate system has proved effective. Here we investigate the use of a six-patch system in characteristic numerical relativity, by comparing an existing two-patch implementation (using second-order finite differencing throughout) with a new six-patch implementation (using either second- or fourth-order finite differencing for the angular derivatives). We compare these different codes by monitoring the Einstein constraint equations, numerically evaluated independently from the evolution. We find that, compared to the (second-order) two-patch code at equivalent resolutions, the errors of the second-order six-patch code are smaller by a factor of about 2, and the errors of the fourth-order six-patch code are smaller by a factor of nearly 50.

  2. Ligand based pharmacophore modelling of anticancer histone ...

    African Journals Online (AJOL)

    USER

    2010-06-21

    Jun 21, 2010 ... The study was carried out using the software Ligand Scout (version .... Computer Science, for his great help and support. We are also grateful to Faculty of Engineering and applied. Sciences, Mohammad .... Aided Mol. Design ...

  3. Synthesis and characterization β-ketoamine ligands

    Science.gov (United States)

    Zaid, Nurzati Amani Mohamed; Hassan, Nur Hasyareeda; Karim, Nurul Huda Abd

    2018-04-01

    β-ketoamine ligands are important members of heterodonor ligand because of their ease of preparation and modification of both steric and/or electronic effects. Complexes with β-ketoamine has received much less attention and there has been no study about this complex with β-ketoamine in ionic liquid reported. Two type of β-ketoamine ligands which are 4-amino-3-pentene-2-onato (A) and 3-amino-2-butenoic acid methyl ester (B) have been synthesized in this work. The resulting compound formed was characterized using standard spectroscopic and structural techniques which includes 1H and 13C, NMR spectroscopy and FTIR spectroscopy. The 1H and 13C NMR spectrum displayed all the expected signals with correct integration and multiplicity. And it is proved that there are some differences between two ligands as observed in NMR and FTIR spectrum.

  4. EGFR Activation by Spatially Restricted Ligands

    National Research Council Canada - National Science Library

    Clouse, Katherine N; Goodrich, Jennifer S

    2006-01-01

    ...) activity has been associated with an increased prognosis of breast cancer. During cogenesis in Drosophila melanogaster local Egfr activation by the spatially-restricted TGFalpha-like ligand Gurken (Grk...

  5. EGFR Activation by Spatially Restricted Ligands

    National Research Council Canada - National Science Library

    Goodrich, Jennifer S

    2005-01-01

    ...) activity has been associated with an increased prognosis of breast cancer. During oogenesis in Drosophila melanogaster, local EGFR activation by the spatially restricted TGF alpha-like ligand, Gurken (Grk...

  6. Depth of origin and angular spectrum of sputtered atoms

    International Nuclear Information System (INIS)

    Vicanek, M.; Jimenez Rodriguez, J.J.; Sigmund, P.

    1989-01-01

    A theoretical analysis is presented of the depth of origin of atoms sputtered from a random target. The physical model aims at high energy sputtering under linear cascade conditions and assumes a dilute source of recoil atoms. The initial distribution of the recoils is assumed isotropic, and their energy distribution is E -2 like without an upper or lower cutoff. The scattering medium is either infinite or bounded by a plane surface. Atoms scatter according to the m=0 power cross section. Electronic stopping is ignored. The sputtered flux, differential in depth of origin, ejection energy and ejection angle has been evaluated by Monte Carlo simulation and by five distinct methods of solution of the linear Boltzmann equation reaching from continuous slowing down neglecting angular scattering to the P 3 approximation and a Gram-Charlier expansion going over spatial moments. The continuous slowing down approximation used in previous work leads to results that are identical to those found from a scheme that only ignores angular scattering but allows for energy loss straggling. Moreover, these predictions match more closely with the Monte Carlo results than any of the approximate analytical schemes that take account of angular scattering. The results confirm the common assertion that the depth of origin of sputtered atoms is determined mainly by the stopping of low energy recoil atoms. The effect of angular scattering turns out to be astonishingly small. The distributions in depth of origin, energy, and angle do not depend significantly on whether the scattering medium is a halfspace or an infinite medium with a reference plane. The angular spectrum comes out only very slightly over cosine from the model as it stands, in agreement with previous experience, but comments are made on essential features that are not incorporated in the physical model but might influence the angular spectrum. (orig./WL)

  7. Cell-specific targeting by heterobivalent ligands.

    Science.gov (United States)

    Josan, Jatinder S; Handl, Heather L; Sankaranarayanan, Rajesh; Xu, Liping; Lynch, Ronald M; Vagner, Josef; Mash, Eugene A; Hruby, Victor J; Gillies, Robert J

    2011-07-20

    Current cancer therapies exploit either differential metabolism or targeting to specific individual gene products that are overexpressed in aberrant cells. The work described herein proposes an alternative approach--to specifically target combinations of cell-surface receptors using heteromultivalent ligands ("receptor combination approach"). As a proof-of-concept that functionally unrelated receptors can be noncovalently cross-linked with high avidity and specificity, a series of heterobivalent ligands (htBVLs) were constructed from analogues of the melanocortin peptide ligand ([Nle(4), dPhe(7)]-α-MSH) and the cholecystokinin peptide ligand (CCK-8). Binding of these ligands to cells expressing the human Melanocortin-4 receptor and the Cholecystokinin-2 receptor was analyzed. The MSH(7) and CCK(6) were tethered with linkers of varying rigidity and length, constructed from natural and/or synthetic building blocks. Modeling data suggest that a linker length of 20-50 Å is needed to simultaneously bind these two different G-protein coupled receptors (GPCRs). These ligands exhibited up to 24-fold enhancement in binding affinity to cells that expressed both (bivalent binding), compared to cells with only one (monovalent binding) of the cognate receptors. The htBVLs had up to 50-fold higher affinity than that of a monomeric CCK ligand, i.e., Ac-CCK(6)-NH(2). Cell-surface targeting of these two cell types with labeled heteromultivalent ligand demonstrated high avidity and specificity, thereby validating the receptor combination approach. This ability to noncovalently cross-link heterologous receptors and target individual cells using a receptor combination approach opens up new possibilities for specific cell targeting in vivo for therapy or imaging.

  8. The angular gamma flux in an iron slab shield

    International Nuclear Information System (INIS)

    Penkuhn, H.

    1975-08-01

    The angular distribution of the photon energy and dose rate flux in a plane iron shield is investigated assuming an isotropic volume source. Near the shield axis (cos phi approximately 1, with phi=angle between shield axis and gamma direction) the angular spectrum is strongly space-dependent. For large phi, space-independent fits are given. Source energies from 0.662 to 6 MeV and penetrations from 6 to 60 cm are treated and the results are compared with a similar investigation on normal concrete. The differences iron-concrete are appreciable only for the lowest source energy

  9. AngularJS yksisivuisen web-applikaation kehitysalustana

    OpenAIRE

    Karhu, Tuomo

    2015-01-01

    Yksisivuiset web-applikaatiot (SPA-sovellukset) ovat yleistyneet viimeisten kymmenen vuoden aikana, ja näiden avulla on ollut mahdollista tuoda verkkosivuston käyttökokemus lähemmäksi aitojen ohjelmasovellusten vastaavaa. Yksisivuisten web-applikaatioitten kehitystyöhön tarkoitetuista sovelluskehyksistä AngularJS on yksi käytetyimmistä ja suosituimmista. Työn tavoitteena on selvittää miten AngularJS-sovelluskehys soveltuu SPA-sivustojen kehitykseen sovelluskehittäjän näkökulmasta, sekä mi...

  10. On angular distribution of nucleus fission fragments by fast neutrons

    International Nuclear Information System (INIS)

    Barabanov, A.L.; Grechukhin, D.P.

    1987-01-01

    Evaluation of amplitudes of quadrupole and hexadecapole components of angular distribution of nucleus fission fragments by neutrons with the energies E n < or approx. 6 MeV is conducted. Stability of this amplitude to permeability optical coefficient variations for neutrons is revealed. It is shown, that the ratio of these amplitudes as well as the character of their dependence on the target nucleus orientation degree are sensitive to the type of fission probability distribution along K projection if fissile nucleus J spin to the fragment scattering axis. This sensitivity may be used for fragment angular distribution anisotropy formation statistical model verification

  11. Gravitomagnetism and angular momenta of black-holes

    OpenAIRE

    Marcelo Samuel Berman

    2007-01-01

    We review the energy contents formulae of Kerr-Newman black-holes, where gravitomagnetic energy term comes into play (Berman 2004, 2006a,b). Then, we obtain the angular momenta formulae, which include the gravitomagnetic effect. Three theorems can be enunciated: (1) No black-hole has its energy confined to its interior; (2) Rotating black-holes do not have confined angular momenta; (3) The energy density of a black-hole is not confined to its interior. The difference between our calculation a...

  12. On the complex angular momentum theory of scattering

    International Nuclear Information System (INIS)

    Thylwe, K.-E.

    1983-01-01

    A contribution to the theory of complex angular momentum techniques in the field of atomic and molecular collisions is given. A new, flexible representation of the scattering amplitude on the basis of realistic assumptions for the behaviour of the S matrix in the complex angular momentum plane is derived. The representation has the form of a sum of steepest-descent integrals, S-matrix residue terms and a symmetry-type background integral. The flexibility is due to the presence of two integer parameters which may be chosen conveniently so as to make the residue sums sufficiently convergent and to minimise the total number of important terms. (author)

  13. Problems of angular momentum projection in nuclear physics

    Energy Technology Data Exchange (ETDEWEB)

    Sorensen, R A [Carnegie-Mellon Univ., Pittsburgh, Pa. (USA)

    1977-05-09

    In nuclear models approximate wave functions are often used which do not have sharp angular momentum as required of the exact wave functions. It seems obvious that model wave functions of this type should be improved by projection onto states of good angular momentum. It is not the purpose of this paper to discuss the technical difficulties of projection (which can be formidable for many particle systems), but rather to present in an elementary way certain fundamental ambiguities in the use of projection. An application to high spin states near the yrast line is suggested.

  14. Gamma-ray angular distribution and correlation measurement. II

    International Nuclear Information System (INIS)

    Twin, P.J.

    1975-01-01

    Angular correlations of γ-rays following nuclear reactions depend, in general, on some alignment of the γ-emitting initial state. The methods of alignment are briefly discussed and then the techniques and experimental methods associated with direct angular distributions, particle-gamma correlations, gamma-gamma correlations and linear polarization correlations are dealt with. Finally the inherent ambiguities which arise when different spin and delta values give identical correlations are discussed for the simple direct and particle-gamma correlations together with the question whether the larger information content of gamma-gamma and linear polarization correlations can resolve these ambiguities. (Auth.)

  15. Angular momentum fuctuation energy in the cranking model

    International Nuclear Information System (INIS)

    Goodman, A.L.

    1979-01-01

    Angular momentum is approximately projected from Hartree-Fock-Bogoliubov cranked (HFBC) wave functions. At each J the projected energy is Esub(proj)approximately Esub(HFBC). The spin-dependent fluctuation ΔJ includes contributions from Jsub(y) and Jsub(z) as well as Jsub(x). There are no correlations in the three angular momentum components. Projected energies are calculated for 168 170 Yb and 174 Hf. When compared to experimental energies, the projected spectra are less compressed than the HFBC spectra. At low spins the projected and experimental energies are in good agreement. (Aut.)

  16. Problems of angular momentum projection in nuclear physics

    International Nuclear Information System (INIS)

    Sorensen, R.A.

    1977-01-01

    In nuclear models approximate wave functions are often used which do not have sharp angular momentum as required of the exact wave functions. It seems obvious that model wave functions of this type should be improved by projection onto states of good angular momentum. It is not the purpose of this paper to discuss the technical difficulties of projection (which can be formidable for many particle systems), but rather to present in an elementary way certain fundamental ambiguities in the use of projection. An application to high spin states near the yrast line is suggested. (Auth.)

  17. Quantitatively measuring the orbital angular momentum density of light : Presentation

    CSIR Research Space (South Africa)

    Dudley, Angela L

    2013-08-01

    Full Text Available the orbital angular momentum density of light Angela Dudleya, Christian Schulzeb, Igor Litvina, Michael Duparréb and Andrew Forbes*a,c,d a CSIR National Laser Centre, PO Box 395, Pretoria 0001, South Africa; b Institute of Applied Optics, Friedrich...., “Generation of high-order Bessel beams by use of an axicon,” Opt. Commun. 177(1-6), 297–301 (2000). [3] Sztul, H. I. and Alfano, R. R., “The Poynting vector and angular momentum of Airy beams,” Opt. Express 16(13), 9411–9416 (2008). [4] Allen, L...

  18. Four Cases of Angular Cheilitis in Orthodontic Patients

    Directory of Open Access Journals (Sweden)

    P Kafaie

    2006-07-01

    Full Text Available Contact dermatitis is an inflammatory reaction of the skin and mucosa to either external or internal factors. It can be divided to two forms of irritant contact dermatitis and allergic contact dermatitis. Nickel is one of the most common materials that causes allergic contact dermatitis and is widely used in orthodontic appliances. The inflammatory reaction to this metal in orthodontics is usually stomatitis and angular cheilitis is very rare. We report 4 cases of angular cheilitis in orthodontic patients and discuss about their causes and treatments.

  19. Semiconductor Quantum Dots with Photoresponsive Ligands.

    Science.gov (United States)

    Sansalone, Lorenzo; Tang, Sicheng; Zhang, Yang; Thapaliya, Ek Raj; Raymo, Françisco M; Garcia-Amorós, Jaume

    2016-10-01

    Photochromic or photocaged ligands can be anchored to the outer shell of semiconductor quantum dots in order to control the photophysical properties of these inorganic nanocrystals with optical stimulations. One of the two interconvertible states of the photoresponsive ligands can be designed to accept either an electron or energy from the excited quantum dots and quench their luminescence. Under these conditions, the reversible transformations of photochromic ligands or the irreversible cleavage of photocaged counterparts translates into the possibility to switch luminescence with external control. As an alternative to regulating the photophysics of a quantum dot via the photochemistry of its ligands, the photochemistry of the latter can be controlled by relying on the photophysics of the former. The transfer of excitation energy from a quantum dot to a photocaged ligand populates the excited state of the species adsorbed on the nanocrystal to induce a photochemical reaction. This mechanism, in conjunction with the large two-photon absorption cross section of quantum dots, can be exploited to release nitric oxide or to generate singlet oxygen under near-infrared irradiation. Thus, the combination of semiconductor quantum dots and photoresponsive ligands offers the opportunity to assemble nanostructured constructs with specific functions on the basis of electron or energy transfer processes. The photoswitchable luminescence and ability to photoinduce the release of reactive chemicals, associated with the resulting systems, can be particularly valuable in biomedical research and can, ultimately, lead to the realization of imaging probes for diagnostic applications as well as to therapeutic agents for the treatment of cancer.

  20. Designer TGFβ superfamily ligands with diversified functionality.

    Directory of Open Access Journals (Sweden)

    George P Allendorph

    Full Text Available Transforming Growth Factor--beta (TGFβ superfamily ligands, including Activins, Growth and Differentiation Factors (GDFs, and Bone Morphogenetic Proteins (BMPs, are excellent targets for protein-based therapeutics because of their pervasiveness in numerous developmental and cellular processes. We developed a strategy termed RASCH (Random Assembly of Segmental Chimera and Heteromer, to engineer chemically-refoldable TGFβ superfamily ligands with unique signaling properties. One of these engineered ligands, AB208, created from Activin-βA and BMP-2 sequences, exhibits the refolding characteristics of BMP-2 while possessing Activin-like signaling attributes. Further, we find several additional ligands, AB204, AB211, and AB215, which initiate the intracellular Smad1-mediated signaling pathways more strongly than BMP-2 but show no sensitivity to the natural BMP antagonist Noggin unlike natural BMP-2. In another design, incorporation of a short N-terminal segment from BMP-2 was sufficient to enable chemical refolding of BMP-9, without which was never produced nor refolded. Our studies show that the RASCH strategy enables us to expand the functional repertoire of TGFβ superfamily ligands through development of novel chimeric TGFβ ligands with diverse biological and clinical values.

  1. LigandRFs: random forest ensemble to identify ligand-binding residues from sequence information alone

    KAUST Repository

    Chen, Peng

    2014-12-03

    Background Protein-ligand binding is important for some proteins to perform their functions. Protein-ligand binding sites are the residues of proteins that physically bind to ligands. Despite of the recent advances in computational prediction for protein-ligand binding sites, the state-of-the-art methods search for similar, known structures of the query and predict the binding sites based on the solved structures. However, such structural information is not commonly available. Results In this paper, we propose a sequence-based approach to identify protein-ligand binding residues. We propose a combination technique to reduce the effects of different sliding residue windows in the process of encoding input feature vectors. Moreover, due to the highly imbalanced samples between the ligand-binding sites and non ligand-binding sites, we construct several balanced data sets, for each of which a random forest (RF)-based classifier is trained. The ensemble of these RF classifiers forms a sequence-based protein-ligand binding site predictor. Conclusions Experimental results on CASP9 and CASP8 data sets demonstrate that our method compares favorably with the state-of-the-art protein-ligand binding site prediction methods.

  2. Studies of metal binding by the iron transport protein transferrin using time differential perturbed angular correlation spectroscopy

    International Nuclear Information System (INIS)

    Then, G.M.

    1987-01-01

    The binding of the transition metal hafnium to transferrin was studied under various chemical conditions using time differential perturbed γγ angular correlation spectroscopy (TDPAC). Observing the electric quadrupole interaction of the 181 Hf probe nuclei size and symmetry of the electric field gradient induced by the ligands of the metal ions can be determined. The experimental data suggest how homogeneous the binding conditions are and to which extend relaxation phenomena are involved. Due to the excellent time resolution obtained with new BaF 2 detectors the quadrupole coupling parameters of 181 Hf-transferrin could be determined very accurately. Under nearly physiological conditions different binding configurations were quantitatively characterized by spectroscopic means and distinguished with high specificity. (orig./PW) [de

  3. De novo design of ligands for metal separation. Annual progress report, September 15, 1996 - September 14, 1997

    International Nuclear Information System (INIS)

    1997-01-01

    'The specific aim of this report is to parameterize force field to reproduce geometries and relative energetics of metal-ligand complexes for cesium, strontium, plutonium, uranium, americium and other relevent alkali, transition, lanthanide and actinide metals. As an initial attempt to examine parametrization, Dr. Yasuo Takeuchi has examined parameters for iron in combination with the molecular mechanics force field. The authors realize that most of the current ad hoc methodologies used to model metal interactions in the past do not have a firm theoretical foundation for modeling the d and f orbitals. They have, therefore, started a collaboration with Prof. Anders Carlsson of the Department of Physics to provide a theoretically correct functional form for the metal force field. Prof. Carlsson has an extensive track record in the derivation of the form of angular force fields from analysis of the quantum-mechanical electronic structure. His most important related works have treated the angular forces around transition-metal (TM) atoms in an aluminum host, the angular forces in elemental bcc transition metals, and the origins of angular and torsional forces in well-bonded s-p systems. They propose to apply the basic ideas of these calculations to developing force laws for transition metal ions in biomolecules. Of particular relevance to the proposed work is his study analyzing angular forces around transition metal (TM) atoms embedded in an aluminum host. Such TM atoms have a profound effect on the host structure, often entirely reassembling the host structure in order to satisfy the angular bonding constraints around the TM atoms. For example, at a concentration of only 1 ∼ TM to 12 ∼ Al, the transition metals Mn, Mo, Tc, W, and Re form the Al 12 W structure, in which the underlying fcc aluminum lattice is disassembled and reassembled into icosahedra which surround the transition-metal atoms. The Al 12 W structure is a body-centered cubic arrangement of such

  4. Synthesis and characterization of mixed ligand chiral nanoclusters

    KAUST Repository

    Guven, Zekiye P.

    2016-06-22

    Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. © 2016 The Royal Society of Chemistry.

  5. Synthesis and characterization of mixed ligand chiral nanoclusters

    KAUST Repository

    Guven, Zekiye P.; Ustbas, Burcin; Harkness, Kellen M.; Coskun, Hikmet; Joshi, Chakra Prasad; Besong, Tabot M.D.; Stellacci, Francesco; Bakr, Osman; Akbulut, Ozge

    2016-01-01

    Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. © 2016 The Royal Society of Chemistry.

  6. Thermal behaviour of hafnium diethylenetriaminepentaacetate studied using the perturbed angular correlation technique

    Energy Technology Data Exchange (ETDEWEB)

    Chain, Cecilia Y. [Universidad Nacional de La Plata (Argentina). Dept. de Fisica; Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires (Argentina); Rivas, Patricia [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires (Argentina); Universidad Nacional de La Plata (Argentina). Facultad de Ciencias Agrarias y Forestales; Pasquevich, Alberto F. [Universidad Nacional de La Plata (Argentina). Dept. de Fisica; Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CIC-PBA) (Argentina)

    2014-07-01

    Polyaminecarboxilic ligands like diethylenetriaminepentaacetic acid form stable complexes with many heavy metal ions, excelling as cation chelants especially in the field of radiopharmacy. The aim of this work is to characterize, by using the Time Differential Perturbed Angular Correlations (TDPAC) technique, the hyperfine interactions at hafnium sites in hafnium diethylenetriaminepentaacetate and to investigate their evolution as temperature increases. TDPAC results for KHfDTPA.3H{sub 2}O obtained by chemical synthesis yield a well defined and highly asymmetric interaction of quadrupole frequency ω{sub Q} = 141 Mrad/s, which is consistent with the existence of a unique site for the metal in the crystal lattice. The thermal behaviour of the chelate is investigated by means of differential scanning calorimetry and thermogravimetrical analyses revealing that an endothermic dehydration of KHfDTPA.3H{sub 2}O takes place in one step between 80 C and 180 C. The anhydrous KHfDTPA thus arising is characterized by a fully asymmetric and well defined interaction of quadrupole frequency ω{sub Q} = 168 Mrad/s. (orig.)

  7. Thermal behaviour of hafnium diethylenetriaminepentaacetate studied using the perturbed angular correlation technique

    International Nuclear Information System (INIS)

    Chain, Cecilia Y.; Rivas, Patricia

    2014-01-01

    Polyaminecarboxilic ligands like diethylenetriaminepentaacetic acid form stable complexes with many heavy metal ions, excelling as cation chelants especially in the field of radiopharmacy. The aim of this work is to characterize, by using the Time Differential Perturbed Angular Correlations (TDPAC) technique, the hyperfine interactions at hafnium sites in hafnium diethylenetriaminepentaacetate and to investigate their evolution as temperature increases. TDPAC results for KHfDTPA.3H 2 O obtained by chemical synthesis yield a well defined and highly asymmetric interaction of quadrupole frequency ω Q = 141 Mrad/s, which is consistent with the existence of a unique site for the metal in the crystal lattice. The thermal behaviour of the chelate is investigated by means of differential scanning calorimetry and thermogravimetrical analyses revealing that an endothermic dehydration of KHfDTPA.3H 2 O takes place in one step between 80 C and 180 C. The anhydrous KHfDTPA thus arising is characterized by a fully asymmetric and well defined interaction of quadrupole frequency ω Q = 168 Mrad/s. (orig.)

  8. Application of perturbed angular correlations to chemistry and related areas of solid state physics

    Energy Technology Data Exchange (ETDEWEB)

    Rinneberg, H H [Freie Univ. Berlin (Germany, F.R.)

    1979-06-01

    The paper reviews the more recent applications of ..gamma..-..gamma.. time-differential perturbed angular correlation (TDPAC) to chemistry and related areas of solid state physics. Topics which are discussed in some detail include: Supertransferred hyperfine fields at diamagnetic impurities in antiferromagnetic transition metal compounds and their relation to the covalency of the transition metal-ligand bond; effects of charge transfer on the quadrupole interactions in various partially covalent insulators measured by PAC; fluctuating electric field gradients in heptafluorohafnates; the influence of charge density waves in TaS/sub 2/ and the effect of intercalating on the field gradients at /sup 181/Ta; recent advances in the understanding of electric field gradients in metals; information obtained by PAC on the microscopic structure of alloys as well as defects in pure metals after quenching, implantation or irradiation. Magnetic and electric phase transitions observed in PAC spectra are briefly mentioned. In addition, recent measurements in liquids and gases are reviewed. Three introductory sections are devoted to a brief discussion of the time-differential PAC technique, to a concise explanation of the theoretical expressions needed to analyse PAC spectra and to a short description of the experimental set-up. An outlook suggests some areas of possible future applications.

  9. Impact of protein and ligand impurities on ITC-derived protein-ligand thermodynamics.

    Science.gov (United States)

    Grüner, Stefan; Neeb, Manuel; Barandun, Luzi Jakob; Sielaff, Frank; Hohn, Christoph; Kojima, Shun; Steinmetzer, Torsten; Diederich, François; Klebe, Gerhard

    2014-09-01

    The thermodynamic characterization of protein-ligand interactions by isothermal titration calorimetry (ITC) is a powerful tool in drug design, giving valuable insight into the interaction driving forces. ITC is thought to require protein and ligand solutions of high quality, meaning both the absence of contaminants as well as accurately determined concentrations. Ligands synthesized to deviating purity and protein of different pureness were titrated by ITC. Data curation was attempted also considering information from analytical techniques to correct stoichiometry. We used trypsin and tRNA-guanine transglycosylase (TGT), together with high affinity ligands to investigate the effect of errors in protein concentration as well as the impact of ligand impurities on the apparent thermodynamics. We found that errors in protein concentration did not change the thermodynamic properties obtained significantly. However, most ligand impurities led to pronounced changes in binding enthalpy. If protein binding of the respective impurity is not expected, the actual ligand concentration was corrected for and the thus revised data compared to thermodynamic properties obtained with the respective pure ligand. Even in these cases, we observed differences in binding enthalpy of about 4kJ⋅mol(-1), which is considered significant. Our results indicate that ligand purity is the critical parameter to monitor if accurate thermodynamic data of a protein-ligand complex are to be recorded. Furthermore, artificially changing fitting parameters to obtain a sound interaction stoichiometry in the presence of uncharacterized ligand impurities may lead to thermodynamic parameters significantly deviating from the accurate thermodynamic signature. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. Equal channel angular pressing of pure aluminium—an analysis

    Indian Academy of Sciences (India)

    Abstract. Equal channel angular pressing (ECAP) is a novel technique for producing ultra fine grain struc- tures in submicron level by introducing a large amount of shear strain into the materials without changing the billet shape or dimensions. This process is well suited for aluminium alloys and is capable of producing ultra.

  11. Gravitational Field of Ultrarelativistic Objects with Angular Momentum

    International Nuclear Information System (INIS)

    Fursaev, Dmitri V

    2006-01-01

    A brief review of recently found gyraton metrics which describe the gravitational field of objects having an angular momentum and moving with the velocity of light is given. The gyraton metrics belong to a class of exact plane wave solutions of four and higher dimensional Einstein equations in vacuum or in the presence of a negative cosmological constant

  12. Modified hydraulic braking system limits angular deceleration to safe values

    Science.gov (United States)

    Briggs, R. S.; Council, M.; Green, P. M.

    1966-01-01

    Conventional spring actuated, hydraulically released, fail-safe disk braking system is modified to control the angular deceleration of a massive antenna. The hydraulic system provides an immediate preset pressure to the spring-loaded brake shoes and holds it at this value to decelerate the antenna at the desired rate.

  13. Obtaining the Electron Angular Momentum Coupling Spectroscopic Terms, jj

    Science.gov (United States)

    Orofino, Hugo; Faria, Roberto B.

    2010-01-01

    A systematic procedure is developed to obtain the electron angular momentum coupling (jj) spectroscopic terms, which is based on building microstates in which each individual electron is placed in a different m[subscript j] "orbital". This approach is similar to that used to obtain the spectroscopic terms under the Russell-Saunders (LS) coupling…

  14. Data visualization with D3 and AngularJS

    CERN Document Server

    Körner, Christoph

    2015-01-01

    If you are a web developer with experience in AngularJS and want to implement interactive visualizations using D3.js, this book is for you. Knowledge of SVG or D3.js will give you an edge to get the most out of this book.

  15. Earth Rotation and Coupling to Changes in Atmospheric Angular Momentum

    Science.gov (United States)

    Rosen, Richard D.; Frey, H. (Technical Monitor)

    2000-01-01

    The research supported under the contract dealt primarily with: (a) the mechanisms responsible for the exchange of angular momentum between the solid Earth and atmosphere; (b) the quality of the data sets used to estimate atmospheric angular momentum; and (c) the ability of these data and of global climate models to detect low-frequency signals in the momentum and, hence, circulation of the atmosphere. Three scientific papers reporting on the results of this research were produced during the course of the contract. These papers identified the particular torques responsible for the peak in atmospheric angular momentum and length-of-day during the 1982-93 El Nino event, and, more generally, the relative roles of torques over land and ocean in explaining the broad spectrum of variability in the length-of-day. In addition, a tendency for interannual variability in atmospheric angular momentum to increase during the last several decades of the 20th century was found in both observations and a global climate model experiment.

  16. Strong eld ionization of naphthalene: angular shifts and molecular potential

    DEFF Research Database (Denmark)

    Dimitrovski, Darko; Maurer, Jochen; Christensen, Lauge

    We analyze the photoelectron momentum distributions from strong eld ionization of xed-in-space naphthalene molecules by circularly polarized laser pulses. By direct comparison between experiment and theory, we show that the angular shifts in the photoelectron momentum distributions are very...... sensitive to the exact form of the molecular potential....

  17. Angular momentum transport with twisted exciton wave packets

    Science.gov (United States)

    Zang, Xiaoning; Lusk, Mark T.

    2017-10-01

    A chain of cofacial molecules with CN or CN h symmetry supports excitonic states with a screwlike structure. These can be quantified with the combination of an axial wave number and an azimuthal winding number. Combinations of these states can be used to construct excitonic wave packets that spiral down the chain with well-determined linear and angular momenta. These twisted exciton wave packets can be created and annihilated using laser pulses, and their angular momentum can be optically modified during transit. This allows for the creation of optoexcitonic circuits in which information, encoded in the angular momentum of light, is converted into excitonic wave packets that can be manipulated, transported, and then reemitted. A tight-binding paradigm is used to demonstrate the key ideas. The approach is then extended to quantify the evolution of twisted exciton wave packets in a many-body, multilevel time-domain density functional theory setting. In both settings, numerical methods are developed that allow the site-to-site transfer of angular momentum to be quantified.

  18. A perturbed angular correlation spectrometer for material science ...

    Indian Academy of Sciences (India)

    A four-detector perturbed angular correlation (PAC) spectrometer has been developed with ultra-fast BaF2 detectors to acquire four coincidence spectra simultaneously, two at 180° and two at 90°. This spectrometer has double efficiency compared to that of a three-detector set-up. Higher efficiency is desirable for PAC ...

  19. a kinematic model for calculating the magnitude of angular ...

    African Journals Online (AJOL)

    BARTH EKWUEME

    material falling into a gravitational source at their centers. Depending ... transportation of angular momentum to outer portion of the accretion ... ∆r1 of the first body is. ∆. ∆. E ... This is the basic action of the accretion disk; energy is released as.

  20. Synchronization of colloidal rotors through angular optical binding

    Czech Academy of Sciences Publication Activity Database

    Simpson, Stephen Hugh; Chvátal, Lukáš; Zemánek, Pavel

    2016-01-01

    Roč. 93, č. 2 (2016), 023842:1-12 ISSN 2469-9926 R&D Projects: GA ČR GB14-36681G Institutional support: RVO:68081731 Keywords : hydrodynamic properties * colloidal rotors * angular optical binding Subject RIV: BH - Optics, Masers, Lasers Impact factor: 2.925, year: 2016

  1. Photofragment angular momentum distribution beyond the axial recoil approximation: Predissociation

    International Nuclear Information System (INIS)

    Kuznetsov, Vladislav V.; Vasyutinskii, Oleg S.

    2007-01-01

    We present the quantum mechanical expressions for the angular momentum distribution of the photofragments produced in slow predissociation. The paper is based on our recent theoretical treatment [J. Chem. Phys. 123, 034307 (2005)] of the recoil angle dependence of the photofragment multipole moments which explicitly treat the role of molecular axis rotation on the electronic angular momentum polarization of the fragments. The electronic wave function of the molecule was used in the adiabatic body frame representation. The rigorous expressions for the fragment state multipoles which have been explicitly derived from the scattering wave function formalism have been used for the case of slow predissociation where a molecule lives in the excited quasibound state much longer than a rotation period. Possible radial nonadiabatic interactions were taken into consideration. The optical excitation of a single rotational branch and the broadband incoherent excitation of all possible rotational branches have been analyzed in detail. The angular momentum polarization of the photofragments has been treated in the high-J limit. The polarization of the photofragment angular momenta predicted by the theory depends on photodissociation mechanism and can in many cases be significant

  2. Cosmology Large Angular Scale Surveyor (CLASS) Focal Plane Development

    Science.gov (United States)

    Chuss, D. T.; Ali, A.; Amiri, M.; Appel, J.; Bennett, C. L.; Colazo, F.; Denis, K. L.; Dunner, R.; Essinger-Hileman, T.; Eimer, J.; hide

    2015-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) will measure the polarization of the Cosmic Microwave Background to search for and characterize the polarized signature of inflation. CLASS will operate from the Atacama Desert and observe approx.70% of the sky. A variable-delay polarization modulator provides modulation of the polarization at approx.10Hz to suppress the 1/f noise of the atmosphere and enable the measurement of the large angular scale polarization modes. The measurement of the inflationary signal across angular scales that spans both the recombination and reionization features allows a test of the predicted shape of the polarized angular power spectra in addition to a measurement of the energy scale of inflation. CLASS is an array of telescopes covering frequencies of 38, 93, 148, and 217 GHz. These frequencies straddle the foreground minimum and thus allow the extraction of foregrounds from the primordial signal. Each focal plane contains feedhorn-coupled transition-edge sensors that simultaneously detect two orthogonal linear polarizations. The use of single-crystal silicon as the dielectric for the on-chip transmission lines enables both high efficiency and uniformity in fabrication. Integrated band definition has been implemented that both controls the bandpass of the single-mode transmission on the chip and prevents stray light from coupling to the detectors.

  3. Incorporation of resistance to angular leaf spot and bean common ...

    African Journals Online (AJOL)

    Luseko

    2013-07-03

    Jul 3, 2013 ... Angular leaf spot (ALS) caused by the fungus Pseudocercospora griseola and Bean common mosaic and necrosis virus (BCMV/BCMNV) are important diseases of common bean in Tanzania that can cause severe yield reduction when uncontrolled. This study was conducted to incorporate resistant genes ...

  4. THE SIMULATION OF SCATTERING OF ELECTROMAGNETIC WAVES ON ANGULAR STRUCTURES.

    Directory of Open Access Journals (Sweden)

    P. A. Preobrazhensky

    2017-02-01

    Full Text Available The paper discusses the characteristics of scattering of electromagnetic waves on the angular diffraction structures. The solution of the problem is based on the method of integral equations. A comparative analysis of the scattering characteristics of structures with different shape is carried out.

  5. The angular ordering in soft-gluon emission

    International Nuclear Information System (INIS)

    Tesima, K.

    1987-01-01

    The way to evaluate multi-parton cross-sections systematically is discussed. In the leading-double-log approximation in QCD, the successive emission of soft gluons is at successively smaller angles. The angular ordering, however, is violated in the next-to-leading order

  6. Angular anisotropy of the cosmic microwave background radiation

    International Nuclear Information System (INIS)

    Silk, J.

    1982-01-01

    The theory of fluctuations in the cosmic microwave background radiation is reviewed. Anisotropy on large-scale (dipole and quadrupole) and on small scales is discussed. The smoothing effects of secondary ionization (fractional ionization x) are found to be unimportant over an angular scale greater than approx.= 5(OMEGAx)sup(1/3) degrees. (author)

  7. Angular momentum projection of tilted axis rotating states

    Energy Technology Data Exchange (ETDEWEB)

    Oi, M; Onishi, N; Tajima, N [Tokyo Univ. (Japan); Horibata, T

    1998-03-01

    We applied an exact angular momentum projection to three dimensional cranked HFB (3d-CHFB) states. Tilted axis rotating states (TAR) and principal axis rotating states (PAR) are compared. It is shown that TAR is more adequate than PAR for description of the back bending phenomena driven by tilted rotation or wobbling motion. (author)

  8. Exact angular momentum projection based on cranked HFB solution

    Energy Technology Data Exchange (ETDEWEB)

    Enami, Kenichi; Tanabe, Kosai; Yosinaga, Naotaka [Saitama Univ., Urawa (Japan). Dept. of Physics

    1998-03-01

    Exact angular momentum projection of cranked HFB solutions is carried out. It is reconfirmed from this calculation that cranked HFB solutions reproduce the intrinsic structure of deformed nucleus. The result also indicates that the energy correction from projection is important for further investigation of nuclear structure. (author)

  9. Numerical simulation of side heating for controlling angular ...

    Indian Academy of Sciences (India)

    In the present study, a 3-D coupled transient thermal analysis model with auxiliary side heating (parallel heating) is developed to control angular distortion. During analysis, parallel heating flames are placed at several locations from weld line in cross direction. A user defined subroutine is used to apply transient heat source ...

  10. Continuous Variable Entanglement and Squeezing of Orbital Angular Momentum States

    DEFF Research Database (Denmark)

    Lassen, Mikael Østergaard; Leuchs, Gerd; Andersen, Ulrik Lund

    2009-01-01

    We report the first experimental characterization of the first-order continuous variable orbital angular momentum states. Using a spatially nondegenerate optical parametric oscillator (OPO) we produce quadrature entanglement between the two first-order Laguerre-Gauss modes. The family of orbital...

  11. Data compilation of angular distributions of sputtered atoms

    International Nuclear Information System (INIS)

    Yamamura, Yasunori; Takiguchi, Takashi; Tawara, Hiro.

    1990-01-01

    Sputtering on a surface is generally caused by the collision cascade developed near the surface. The process is in principle the same as that causing radiation damage in the bulk of solids. Sputtering has long been regarded as an undesirable dirty effect which destroys the cathodes and grids in gas discharge tubes or ion sources and contaminates plasma and the surrounding walls. However, sputtering is used today for many applications such as sputter ion sources, mass spectrometers and the deposition of thin films. Plasma contamination and the surface erosion of first walls due to sputtering are still the major problems in fusion research. The angular distribution of the particles sputtered from solid surfaces can possibly provide the detailed information on the collision cascade in the interior of targets. This report presents a compilation of the angular distribution of sputtered atoms at normal incidence and oblique incidence in the various combinations of incident ions and target atoms. The angular distribution of sputtered atoms from monatomic solids at normal incidence and oblique incidence, and the compilation of the data on the angular distribution of sputtered atoms are reported. (K.I.)

  12. Angular momentum transport and evolution of lopsided galaxies

    Science.gov (United States)

    Saha, Kanak; Jog, Chanda J.

    2014-10-01

    The surface brightness distribution in the majority of stellar galactic discs falls off exponentially. Often what lies beyond such a stellar disc is the neutral hydrogen gas whose distribution also follows a nearly exponential profile at least for a number of nearby disc galaxies. Both the stars and gas are commonly known to host lopsided asymmetry especially in the outer parts of a galaxy. The role of such asymmetry in the dynamical evolution of a galaxy has not been explored so far. Following Lindblad's original idea of kinematic density waves, we show that the outer part of an exponential disc is ideally suitable for hosting lopsided asymmetry. Further, we compute the transport of angular momentum in the combined stars and gas disc embedded in a dark matter halo. We show that in a pure star and gas disc, there is a transition point where the free precession frequency of a lopsided mode, Ω - κ, changes from retrograde to prograde and this in turn reverses the direction of angular momentum flow in the disc leading to an unphysical behaviour. We show that this problem is overcome in the presence of a dark matter halo, which sets the angular momentum flow outwards as required for disc evolution, provided the lopsidedness is leading in nature. This, plus the well-known angular momentum transport in the inner parts due to spiral arms, can facilitate an inflow of gas from outside perhaps through the cosmic filaments.

  13. Gravitational Field of Ultrarelativistic Objects with Angular Momentum

    Energy Technology Data Exchange (ETDEWEB)

    Fursaev, Dmitri V [Dubna International University and Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, 141 980, Dubna, Moscow Region (Russian Federation)

    2006-03-01

    A brief review of recently found gyraton metrics which describe the gravitational field of objects having an angular momentum and moving with the velocity of light is given. The gyraton metrics belong to a class of exact plane wave solutions of four and higher dimensional Einstein equations in vacuum or in the presence of a negative cosmological constant.

  14. Angular distribution of protons emitted from the hydrogen plasma focus

    Energy Technology Data Exchange (ETDEWEB)

    Antanasijevic, R.; Maric, Z.; Vukovic, J.; Grabez, B. E-mail: grabez@phy.bg.ac.yu; Djordjevic, D.; Joksimovic, D.; Udovicic, V.; Dragic, A.; Stanojevic, J.; Banjanac, R.; Jokovic, D

    2003-06-01

    Angular distribution of emitted protons was measured. The protons were detected with NTD LR-115 placed at the specially constructed semi-spherical holder, which contains 17 different pinhole cameras. The mechanism of proton acceleration and emission are studied theoretically and experimental results are compared with theoretical predictions.

  15. Angular distribution of protons emitted from the hydrogen plasma focus

    International Nuclear Information System (INIS)

    Antanasijevic, R.; Maric, Z.; Vukovic, J.; Grabez, B.; Djordjevic, D.; Joksimovic, D.; Udovicic, V.; Dragic, A.; Stanojevic, J.; Banjanac, R.; Jokovic, D.

    2003-01-01

    Angular distribution of emitted protons was measured. The protons were detected with NTD LR-115 placed at the specially constructed semi-spherical holder, which contains 17 different pinhole cameras. The mechanism of proton acceleration and emission are studied theoretically and experimental results are compared with theoretical predictions

  16. A new uncertainty relation for angular momentum and angle

    International Nuclear Information System (INIS)

    Kranold, H.U.

    1984-01-01

    An uncertainty relation of the form ΔL 2 ΔSo >=sup(h/2π)/sub(2) is derived for angular momentum and angle. The non-linear operator So measures angles and has a simple interpretation. Subject to very general conditions of rotational invariance the above relation is unique. Radial momentum is not quantized

  17. Angular dependence of EEDF in ion-beam plasma

    International Nuclear Information System (INIS)

    Dudin, S.V.

    1995-01-01

    In a previous paper the results of measurements of electron energy distribution function (EEDF) in ion-beam plasma created by low energy broad ion beam had been presented regardless of the angular dependence of the electron distribution. The present work is specifically aimed towards elucidating the spatial structure of the EEDF in the ion-beam plasma. To solve this problem combination of the techniques of cylindrical probe, large plate probe (5 x 5 mm) and two-grid enegoanalyzer was used. Directional operation of the probes makes possible measurement of angular dependence of electron distribution function which is anisotropic in high energy region. To optimize the construction of the probe-analyzer, experiments with grids were performed, which had different size, mesh, and transparency, under different potentials, and with different distances between grids. Numerical simulation of the analyzer was performed too. It is derived that optimal design for measurements in isotropic plasma is the most plate, thin two-grid probe with maximum angular covering. Investigation of angular dependence of EEDF has shown that the distribution of trapped electrons is completely isotropic, whereas in the energy range of var-epsilon > e var-phi pl (var-phi pl - plasma potential) a strong anisotropy of the EEDF is observed

  18. Search for new physics in dijet mass and angular distributions

    Indian Academy of Sciences (India)

    We present a search for physics beyond the Standard Model in proton–proton collisions at a centre-of-mass energy of s = 7 TeV, performed with the ATLAS detector at the Large Hadron Collider (LHC). No evidence for new physics is found in dijet mass and angular distributions and stringent limits are set on a variety of ...

  19. Incorporation of resistance to angular leaf spot and bean common ...

    African Journals Online (AJOL)

    Angular leaf spot (ALS) caused by the fungus Pseudocercospora griseola and Bean common mosaic and necrosis virus (BCMV/BCMNV) are important diseases of common bean in Tanzania that can cause severe yield reduction when uncontrolled. This study was conducted to incorporate resistant genes for ALS and ...

  20. Type I supernovae and angular anisotropy of the Hubble constant

    International Nuclear Information System (INIS)

    Le Denmat, Gerard; Vigier, J.-P.

    1975-01-01

    The observation of type I supernovae in distant galaxies yields an homogeneous sample of sources to evaluate their true distance. An examination of their distribution in the sky provides a significant confirmation of the angular anisotropy of the Hubble constant already observed by Rubin, Rubin and Ford [fr

  1. AngularJS : yksisivuisen web-sovelluksen käyttöliittymän toteutus AngularJS:llä

    OpenAIRE

    Suomijoki, Juha

    2015-01-01

    Opinnäytetyössä tutkittiin mikä on AngularJS-JavaScript-ohjelmistokehys ja miten se soveltuu yksisivuisen web-sovelluksen käyttöliittymän toteutukseen. AngularJS on vuonna 2012 julkaistu Googlen ylläpitämä JavaScript-ohjelmistokehys, joka on tarkoitettu ensisijaisesti yksisivuisten web-sovellusten kehittämiseen. Opinnäytetyön teoriaosuudessa tutkittiin mikä AngularJS on ja mitkä ovat AngularJS:n keskeiset konseptit ja sovelluskomponentit. Tarkastelu pohjautui AngularJS:stä kirjoitettu...

  2. Expression of nociceptive ligands in canine osteosarcoma.

    Science.gov (United States)

    Shor, S; Fadl-Alla, B A; Pondenis, H C; Zhang, X; Wycislo, K L; Lezmi, S; Fan, T M

    2015-01-01

    Canine osteosarcoma (OS) is associated with localized pain as a result of tissue injury from tumor infiltration and peritumoral inflammation. Malignant bone pain is caused by stimulation of peripheral pain receptors, termed nociceptors, which reside in the localized tumor microenvironment, including the periosteal and intramedullary bone cavities. Several nociceptive ligands have been determined to participate directly or indirectly in generating bone pain associated with diverse skeletal abnormalities. Canine OS cells actively produce nociceptive ligands with the capacity to directly or indirectly activate peripheral pain receptors residing in the bone tumor microenvironment. Ten dogs with appendicular OS. Expression of nerve growth factor, endothelin-1, and microsomal prostaglandin E synthase-1 was characterized in OS cell lines and naturally occurring OS samples. In 10 dogs with OS, circulating concentrations of nociceptive ligands were quantified and correlated with subjective pain scores and tumor volume in patients treated with standardized palliative therapies. Canine OS cells express and secrete nerve growth factor, endothelin-1, and prostaglandin E2. Naturally occurring OS samples uniformly express nociceptive ligands. In a subset of OS-bearing dogs, circulating nociceptive ligand concentrations were detectable but failed to correlate with pain status. Localized foci of nerve terminal proliferation were identified in a minority of primary bone tumor samples. Canine OS cells express nociceptive ligands, potentially permitting active participation of OS cells in the generation of malignant bone pain. Specific inhibitors of nociceptive ligand signaling pathways might improve pain control in dogs with OS. Copyright © 2015 The Authors. Journal of Veterinary Internal Medicine published by Wiley Periodicals, Inc. on behalf of American College of Veterinary Internal Medicine.

  3. Power calculation of linear and angular incremental encoders

    Science.gov (United States)

    Prokofev, Aleksandr V.; Timofeev, Aleksandr N.; Mednikov, Sergey V.; Sycheva, Elena A.

    2016-04-01

    Automation technology is constantly expanding its role in improving the efficiency of manufacturing and testing processes in all branches of industry. More than ever before, the mechanical movements of linear slides, rotary tables, robot arms, actuators, etc. are numerically controlled. Linear and angular incremental photoelectric encoders measure mechanical motion and transmit the measured values back to the control unit. The capabilities of these systems are undergoing continual development in terms of their resolution, accuracy and reliability, their measuring ranges, and maximum speeds. This article discusses the method of power calculation of linear and angular incremental photoelectric encoders, to find the optimum parameters for its components, such as light emitters, photo-detectors, linear and angular scales, optical components etc. It analyzes methods and devices that permit high resolutions in the order of 0.001 mm or 0.001°, as well as large measuring lengths of over 100 mm. In linear and angular incremental photoelectric encoders optical beam is usually formulated by a condenser lens passes through the measuring unit changes its value depending on the movement of a scanning head or measuring raster. Past light beam is converting into an electrical signal by the photo-detecter's block for processing in the electrical block. Therefore, for calculating the energy source is a value of the desired value of the optical signal at the input of the photo-detecter's block, which reliably recorded and processed in the electronic unit of linear and angular incremental optoelectronic encoders. Automation technology is constantly expanding its role in improving the efficiency of manufacturing and testing processes in all branches of industry. More than ever before, the mechanical movements of linear slides, rotary tables, robot arms, actuators, etc. are numerically controlled. Linear and angular incremental photoelectric encoders measure mechanical motion and

  4. Helicon modes in uniform plasmas. III. Angular momentum

    International Nuclear Information System (INIS)

    Stenzel, R. L.; Urrutia, J. M.

    2015-01-01

    Helicons are electromagnetic waves with helical phase fronts propagating in the whistler mode in magnetized plasmas and solids. They have similar properties to electromagnetic waves with angular momentum in free space. Helicons are circularly polarized waves carrying spin angular momentum and orbital angular momentum due to their propagation around the ambient magnetic field B 0 . These properties have not been considered in the community of researchers working on helicon plasma sources, but are the topic of the present work. The present work focuses on the field topology of helicons in unbounded plasmas, not on helicon source physics. Helicons are excited in a large uniform laboratory plasma with a magnetic loop antenna whose dipole axis is aligned along or across B 0 . The wave fields are measured in orthogonal planes and extended to three dimensions (3D) by interpolation. Since density and B 0 are uniform, small amplitude waves from loops at different locations can be superimposed to generate complex antenna patterns. With a circular array of phase shifted loops, whistler modes with angular and axial wave propagation, i.e., helicons, are generated. Without boundaries radial propagation also arises. The azimuthal mode number m can be positive or negative while the field polarization remains right-hand circular. The conservation of energy and momentum implies that these field quantities are transferred to matter which causes damping or reflection. Wave-particle interactions with fast electrons are possible by Doppler shifted resonances. The transverse Doppler shift is demonstrated. Wave-wave interactions are also shown by showing collisions between different helicons. Whistler turbulence does not always have to be created by nonlinear wave-interactions but can also be a linear superposition of waves from random sources. In helicon collisions, the linear and/or orbital angular momenta can be canceled, which results in a great variety of field topologies. The work

  5. Continuous theta burst stimulation of angular gyrus reduces subjective recollection.

    Directory of Open Access Journals (Sweden)

    Yasemin Yazar

    Full Text Available The contribution of lateral parietal regions such as the angular gyrus to human episodic memory has been the subject of much debate following widespread observations of left parietal activity in healthy volunteers during functional neuroimaging studies of memory retrieval. Patients with lateral parietal lesions are not amnesic, but recent evidence indicates that their memory abilities may not be entirely preserved. Whereas recollection appears intact when objective measures such as source accuracy are used, patients often exhibit reduced subjective confidence in their accurate recollections. When asked to recall autobiographical memories, they may produce spontaneous narratives that lack richness and specificity, but can remember specific details when prompted. Two distinct theoretical accounts have been proposed to explain these results: that the patients have a deficit in the bottom-up capturing of attention by retrieval output, or that they have an impairment in the subjective experience of recollection. The present study aimed to differentiate between these accounts using continuous theta burst stimulation (cTBS in healthy participants to disrupt function of specific left parietal subregions, including angular gyrus. Inconsistent with predictions of the attentional theory, angular gyrus cTBS did not result in greater impairment of free recall than cued recall. Supporting predictions of the subjective recollection account, temporary disruption of angular gyrus was associated with highly accurate source recollection accuracy but a selective reduction in participants' rated source confidence. The findings are consistent with a role for angular gyrus in the integration of memory features into a conscious representation that enables the subjective experience of remembering.

  6. The role of angular momentum conservation law in statistical mechanics

    Directory of Open Access Journals (Sweden)

    I.M. Dubrovskii

    2008-12-01

    Full Text Available Within the limits of Khinchin ideas [A.Y. Khinchin, Mathematical Foundation of Statistical Mechanics. NY, Ed. Dover, 1949] the importance of momentum and angular momentum conservation laws was analyzed for two cases: for uniform magnetic field and when magnetic field is absent. The law of momentum conservation does not change the density of probability distribution in both cases, just as it is assumed in the conventional theory. It is shown that in systems where the kinetic energy depends only on particle momenta canonically conjugated with Cartesian coordinates being their diagonal quadric form,the angular momentum conservation law changes the density of distribution of the system only in case the full angular momentum of a system is not equal to zero. In the gas of charged particles in a uniform magnetic field the density of distribution also varies if the angular momentum is zero [see Dubrovskii I.M., Condensed Matter Physics, 2206, 9, 23]. Two-dimensional gas of charged particles located within a section of an endless strip filled with gas in magnetic field is considered. Under such conditions the angular momentum is not conserved. Directional particle flows take place close to the strip boundaries, and, as a consequence, the phase trajectory of the considered set of particles does not remain within the limited volume of the phase space. In order to apply a statistical thermodynamics method, it was suggested to consider near-boundary trajectories relative to a reference system that moves uniformly. It was shown that if the diameter of an orbit having average thermal energy is much smaller than a strip width, the corrections to thermodynamic functions are small depending on magnetic field. Only the average velocity of near-boundary particles that form near-boundary electric currents creating the paramagnetic moment turn out to be essential.

  7. Immobilisation of ligands by radio-derivatized polymers; Immobilisering av ligander med radioderiverte polymerer

    Energy Technology Data Exchange (ETDEWEB)

    Varga, J.M.; Fritsch, P.

    1995-01-30

    The invention relates to radio-derivatized polymers and a method of producing them by contacting non-polymerizable conjugands with radiolysable polymers in the presence of irradiation. The resulting radio-derivatized polymers can be further linked with ligand of organic or inorganic nature to immobilize such ligands. 2 figs., 5 tabs.

  8. A General Ligand Design for Gold Catalysis allowing Ligand-Directed Anti Nucleophilic Attack of Alkynes

    Science.gov (United States)

    Wang, Yanzhao; Wang, Zhixun; Li, Yuxue; Wu, Gongde; Cao, Zheng; Zhang, Liming

    2014-01-01

    Most homogenous gold catalyses demand ≥0.5 mol % catalyst loading. Due to the high cost of gold, these reactions are unlikely to be applicable in medium or large scale applications. Here we disclose a novel ligand design based on the privileged biphenyl-2-phosphine framework that offers a potentially general approach to dramatically lowering catalyst loading. In this design, an amide group at the 3’ position of the ligand framework directs and promotes nucleophilic attack at the ligand gold complex-activated alkyne, which is unprecedented in homogeneous gold catalysis considering the spatial challenge of using ligand to reach antiapproaching nucleophile in a linear P-Au-alkyne centroid structure. With such a ligand, the gold(I) complex becomes highly efficient in catalyzing acid addition to alkynes, with a turnover number up to 99,000. Density functional theory calculations support the role of the amide moiety in directing the attack of carboxylic acid via hydrogen bonding. PMID:24704803

  9. A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

    KAUST Repository

    Li, Huaifeng

    2014-12-01

    Work on a new class of PN3-pincer ligands for metal-ligand cooperative catalysis is reviewed. While the field of the pyridine-based PN3-transition metal pincer complexes is still relatively young, many important applications of these complexes have already emerged. In several cases, the PN3-pincer complexes for metal-ligand cooperative catalysis result in significantly improved or unprecedented activities. The synthesis and coordination chemistry of PN3-pincer ligands are briefly summarized first to cover the synthetic routes for their preparation, followed by a focus review on their applications in catalysis. A specific emphasis is placed on the later section about the role of PN3-pincer ligands\\' dearomatization-rearomatization steps during the catalytic cycles. The mechanistic insights from density functional theory (DFT) calculations are also discussed.

  10. A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

    KAUST Repository

    Li, Huaifeng; Zheng, Bin; Huang, Kuo-Wei

    2014-01-01

    Work on a new class of PN3-pincer ligands for metal-ligand cooperative catalysis is reviewed. While the field of the pyridine-based PN3-transition metal pincer complexes is still relatively young, many important applications of these complexes have already emerged. In several cases, the PN3-pincer complexes for metal-ligand cooperative catalysis result in significantly improved or unprecedented activities. The synthesis and coordination chemistry of PN3-pincer ligands are briefly summarized first to cover the synthetic routes for their preparation, followed by a focus review on their applications in catalysis. A specific emphasis is placed on the later section about the role of PN3-pincer ligands' dearomatization-rearomatization steps during the catalytic cycles. The mechanistic insights from density functional theory (DFT) calculations are also discussed.

  11. Effects of PPARγ ligands on vascular tone.

    Science.gov (United States)

    Salomone, Salvatore; Drago, Filippo

    2012-06-01

    Peroxisome Proliferator-Activated Receptor γ (PPARγ), originally described as a transcription factor for genes of carbohydrate and lipid metabolism, has been more recently studied in the context of cardiovascular pathophysiology. Here, we review the available data on PPARγ ligands as modulator of vascular tone. PPARγ ligands include: thiazolidinediones (used in the treatment of type 2 diabetes mellitus), glitazars (bind and activate both PPARγ and PPARα), and other experimental drugs (still in development) that exploit the chemistry of thiazolidinediones as a scaffold for PPARγ-independent pharmacological properties. In this review, we examine both short (mostly from in vitro data)- and long (mostly from in vivo data)-term effects of PPARγ ligands that extend from PPARγ-independent vascular effects to PPARγ-dependent gene expression. Because endothelium is a master regulator of vascular tone, we have attempted to differentiate between endothelium-dependent and endothelium-independent effects of PPARγ ligands. Based on available data, we conclude that PPARγ ligands appear to influence vascular tone in different experimental paradigms, most often in terms of vasodilatation (potentially increasing blood flow to some tissues). These effects on vascular tone, although potentially beneficial, must be weighed against specific cardiovascular warnings that may apply to some drugs, such as rosiglitazone.

  12. LIBRA: LIgand Binding site Recognition Application.

    Science.gov (United States)

    Hung, Le Viet; Caprari, Silvia; Bizai, Massimiliano; Toti, Daniele; Polticelli, Fabio

    2015-12-15

    In recent years, structural genomics and ab initio molecular modeling activities are leading to the availability of a large number of structural models of proteins whose biochemical function is not known. The aim of this study was the development of a novel software tool that, given a protein's structural model, predicts the presence and identity of active sites and/or ligand binding sites. The algorithm implemented by ligand binding site recognition application (LIBRA) is based on a graph theory approach to find the largest subset of similar residues between an input protein and a collection of known functional sites. The algorithm makes use of two predefined databases for active sites and ligand binding sites, respectively, derived from the Catalytic Site Atlas and the Protein Data Bank. Tests indicate that LIBRA is able to identify the correct binding/active site in 90% of the cases analyzed, 90% of which feature the identified site as ranking first. As far as ligand binding site recognition is concerned, LIBRA outperforms other structure-based ligand binding sites detection tools with which it has been compared. The application, developed in Java SE 7 with a Swing GUI embedding a JMol applet, can be run on any OS equipped with a suitable Java Virtual Machine (JVM), and is available at the following URL: http://www.computationalbiology.it/software/LIBRAv1.zip. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  13. Dockomatic - automated ligand creation and docking.

    Science.gov (United States)

    Bullock, Casey W; Jacob, Reed B; McDougal, Owen M; Hampikian, Greg; Andersen, Tim

    2010-11-08

    The application of computational modeling to rationally design drugs and characterize macro biomolecular receptors has proven increasingly useful due to the accessibility of computing clusters and clouds. AutoDock is a well-known and powerful software program used to model ligand to receptor binding interactions. In its current version, AutoDock requires significant amounts of user time to setup and run jobs, and collect results. This paper presents DockoMatic, a user friendly Graphical User Interface (GUI) application that eases and automates the creation and management of AutoDock jobs for high throughput screening of ligand to receptor interactions. DockoMatic allows the user to invoke and manage AutoDock jobs on a single computer or cluster, including jobs for evaluating secondary ligand interactions. It also automates the process of collecting, summarizing, and viewing results. In addition, DockoMatic automates creation of peptide ligand .pdb files from strings of single-letter amino acid abbreviations. DockoMatic significantly reduces the complexity of managing multiple AutoDock jobs by facilitating ligand and AutoDock job creation and management.

  14. Dockomatic - automated ligand creation and docking

    Directory of Open Access Journals (Sweden)

    Hampikian Greg

    2010-11-01

    Full Text Available Abstract Background The application of computational modeling to rationally design drugs and characterize macro biomolecular receptors has proven increasingly useful due to the accessibility of computing clusters and clouds. AutoDock is a well-known and powerful software program used to model ligand to receptor binding interactions. In its current version, AutoDock requires significant amounts of user time to setup and run jobs, and collect results. This paper presents DockoMatic, a user friendly Graphical User Interface (GUI application that eases and automates the creation and management of AutoDock jobs for high throughput screening of ligand to receptor interactions. Results DockoMatic allows the user to invoke and manage AutoDock jobs on a single computer or cluster, including jobs for evaluating secondary ligand interactions. It also automates the process of collecting, summarizing, and viewing results. In addition, DockoMatic automates creation of peptide ligand .pdb files from strings of single-letter amino acid abbreviations. Conclusions DockoMatic significantly reduces the complexity of managing multiple AutoDock jobs by facilitating ligand and AutoDock job creation and management.

  15. Ligand identification using electron-density map correlations

    International Nuclear Information System (INIS)

    Terwilliger, Thomas C.; Adams, Paul D.; Moriarty, Nigel W.; Cohn, Judith D.

    2007-01-01

    An automated ligand-fitting procedure is applied to (F o − F c )exp(iϕ c ) difference density for 200 commonly found ligands from macromolecular structures in the Protein Data Bank to identify ligands from density maps. A procedure for the identification of ligands bound in crystal structures of macromolecules is described. Two characteristics of the density corresponding to a ligand are used in the identification procedure. One is the correlation of the ligand density with each of a set of test ligands after optimization of the fit of that ligand to the density. The other is the correlation of a fingerprint of the density with the fingerprint of model density for each possible ligand. The fingerprints consist of an ordered list of correlations of each the test ligands with the density. The two characteristics are scored using a Z-score approach in which the correlations are normalized to the mean and standard deviation of correlations found for a variety of mismatched ligand-density pairs, so that the Z scores are related to the probability of observing a particular value of the correlation by chance. The procedure was tested with a set of 200 of the most commonly found ligands in the Protein Data Bank, collectively representing 57% of all ligands in the Protein Data Bank. Using a combination of these two characteristics of ligand density, ranked lists of ligand identifications were made for representative (F o − F c )exp(iϕ c ) difference density from entries in the Protein Data Bank. In 48% of the 200 cases, the correct ligand was at the top of the ranked list of ligands. This approach may be useful in identification of unknown ligands in new macromolecular structures as well as in the identification of which ligands in a mixture have bound to a macromolecule

  16. Frame dependence of spin-one angular conditions in light front dynamics

    International Nuclear Information System (INIS)

    Bakker, Bernard L. G.; Ji Chuengryong

    2002-01-01

    We elaborate the frame dependence of the angular conditions for spin-1 form factors. An extra angular condition is found in addition to the usual angular condition relating the four helicity amplitudes. Investigating the frame dependence of angular conditions, we find that the extra angular condition is in general as complicated as the usual one, although it becomes very simple in the q + =0 frame involving only two helicity amplitudes. It is confirmed that the angular conditions are identical in frames that are connected by kinematical transformations. The high-Q 2 behavior of the physical form factors and the limiting behavior in special reference frames are also discussed

  17. Ligand sphere conversions in terminal carbide complexes

    DEFF Research Database (Denmark)

    Morsing, Thorbjørn Juul; Reinholdt, Anders; Sauer, Stephan P. A.

    2016-01-01

    Metathesis is introduced as a preparative route to terminal carbide complexes. The chloride ligands of the terminal carbide complex [RuC(Cl)2(PCy3)2] (RuC) can be exchanged, paving the way for a systematic variation of the ligand sphere. A series of substituted complexes, including the first...... example of a cationic terminal carbide complex, [RuC(Cl)(CH3CN)(PCy3)2]+, is described and characterized by NMR, MS, X-ray crystallography, and computational studies. The experimentally observed irregular variation of the carbide 13C chemical shift is shown to be accurately reproduced by DFT, which also...... demonstrates that details of the coordination geometry affect the carbide chemical shift equally as much as variations in the nature of the auxiliary ligands. Furthermore, the kinetics of formation of the sqaure pyramidal dicyano complex, trans-[RuC(CN)2(PCy3)2], from RuC has been examined and the reaction...

  18. Characteristic molecular vibrations of adenosine receptor ligands.

    Science.gov (United States)

    Chee, Hyun Keun; Yang, Jin-San; Joung, Je-Gun; Zhang, Byoung-Tak; Oh, S June

    2015-02-13

    Although the regulation of membrane receptor activation is known to be crucial for molecular signal transduction, the molecular mechanism underlying receptor activation is not fully elucidated. Here we study the physicochemical nature of membrane receptor behavior by investigating the characteristic molecular vibrations of receptor ligands using computational chemistry and informatics methods. By using information gain, t-tests, and support vector machines, we have identified highly informative features of adenosine receptor (AdoR) ligand and corresponding functional amino acid residues such as Asn (6.55) of AdoR that has informative significance and is indispensable for ligand recognition of AdoRs. These findings may provide new perspectives and insights into the fundamental mechanism of class A G protein-coupled receptor activation. Copyright © 2015 Federation of European Biochemical Societies. Published by Elsevier B.V. All rights reserved.

  19. Strong Ligand-Protein Interactions Derived from Diffuse Ligand Interactions with Loose Binding Sites.

    Science.gov (United States)

    Marsh, Lorraine

    2015-01-01

    Many systems in biology rely on binding of ligands to target proteins in a single high-affinity conformation with a favorable ΔG. Alternatively, interactions of ligands with protein regions that allow diffuse binding, distributed over multiple sites and conformations, can exhibit favorable ΔG because of their higher entropy. Diffuse binding may be biologically important for multidrug transporters and carrier proteins. A fine-grained computational method for numerical integration of total binding ΔG arising from diffuse regional interaction of a ligand in multiple conformations using a Markov Chain Monte Carlo (MCMC) approach is presented. This method yields a metric that quantifies the influence on overall ligand affinity of ligand binding to multiple, distinct sites within a protein binding region. This metric is essentially a measure of dispersion in equilibrium ligand binding and depends on both the number of potential sites of interaction and the distribution of their individual predicted affinities. Analysis of test cases indicates that, for some ligand/protein pairs involving transporters and carrier proteins, diffuse binding contributes greatly to total affinity, whereas in other cases the influence is modest. This approach may be useful for studying situations where "nonspecific" interactions contribute to biological function.

  20. Angular evolution of peripheral heavy ion reactions at intermediate energies

    International Nuclear Information System (INIS)

    Blumenfeld, Y.; Chomaz, P.; Frascaria, N.; Garron, J.P.; Jacmart, J.C; Roynette, J.C

    1985-01-01

    Energy spectra and angular distributions of projectile-like fragments have been measured in the vicinity of the grazing angle for the 40 Ar+ 40 Ca and 40 Ar+ 208 Pb reactions at 44MeV/nucleon. Measurements of the 40 Ar+ 40 Ca system at 27MeV/nucleon and 20 Ne+ 208 Pb reaction at 44MeV/nucleon at one angle have also been performed. For fragments with charge and mass close to the projectile numerous deviations from the standard fragmentation model have been observed including rapidly changing shapes of the angular distributions with the fragment mass. Moreover the isotopic distributions and mean fragment velocities are strongly dependent on detection angle. A surface transfer reaction component dominant at the grazing angle can be separated from a second component which cannot be entirely accounted for by a simple fragmentation mechanism

  1. Angular dependence of the exchange bias for the bistable state

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Yuhao [College of Physics and Electronic Information, Shanxi Normal University, Linfen 041004 (China); Research College of materials science, Shanxi Normal University, Linfen 041004 (China); Xu, Xiaohong, E-mail: xuxh@dns.sxnu.edu.cn [Research College of materials science, Shanxi Normal University, Linfen 041004 (China); Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Shanxi Normal University, Linfen 041004 (China)

    2017-06-15

    The angular dependence of the exchange bias (ADEB) has been investigated in detail when the exchange-coupled ferromagnetic (FM)/antiferromagnetic (AFM) bilayer is in the bistable state. Complete and incomplete jump phenomena were found at the intrinsic easy and hard axes, when they pass through two special positions making the angular deviation of 58.2826° and 121.7174° from the easy axis of the uniaxial anisotropy, respectively. The combination of these different types of the jump phenomena at the intrinsic easy and hard axes yields five distinct types of the ADEB. The physical condition for each type of ADEB is established. Additionally, the extreme value problem of the exchange bias field and coercivity are also discussed, which is an important technological issue in the design of the magnetoresistive and spintronic devices. These results enable us to make a comprehensive understanding of the experimental ADEB curves.

  2. Angular diameters of Magellanic Cloud plantary nebulae. I. Speckle interferometry

    International Nuclear Information System (INIS)

    Wood, P.R.; Bessell, M.S.; Dopita, M.A.

    1986-01-01

    Speckle interferometric angular diameters of Magellanic Cloud planetary nebulae are presented. The mass of ionized gas in each nebula has been derived from the angular diameter and published H-beta line fluxes; the derives masses range from less than 0.006 to more than 0.19 solar mass. The planetary nebulae observed were the brightest in the Magellanic Clouds; consequently, they are all relatively small, young, bright, and dense. They are almost certainly only partially ionized, so that the masses derived for the ionized parts of the nebula are lower limits to the total nebula mass. The properties of the Magellanic Cloud nebulae are compared with those of planetary nebulae at the galactic center. 27 references

  3. Angular distribution in proton-hydrogen charge-transfer collisions

    International Nuclear Information System (INIS)

    Glembocki, O.; Halpern, A.M.

    1977-01-01

    Theoretical angular distributions for p-H charge transfer to the 1s state for energies of 1 keV and above have been examined and compared for three approximation schemes: the plane-wave Born approximation of Jackson and Schiff (JS), the Coulomb projected Born approximation of Geltman (G), and the distorted-wave eikonal approximation of one of the authors (D). The sharp dip in the forward distribution characteristic of JS is found to exist in G and D as well. As expected, G and D give identical results for all but the lowest energies. In the cases of G and D the dip, which is located close to that of JS, disappears and then reappears as the energy rises. Analytic high-energy limits for the angular dependence in both the JS and G cases have been found and are discussed

  4. On the observability of the quark orbital angular momentum distribution

    Energy Technology Data Exchange (ETDEWEB)

    Courtoy, Aurore, E-mail: aurore.courtoy@ulg.be [IFPA, AGO Department, Université de Liège, Bât. B5, Sart Tilman, B-4000 Liège (Belgium); Laboratori Nazionali di Frascati, INFN, Frascati (Italy); Goldstein, Gary R., E-mail: gary.goldstein@tufts.edu [Department of Physics and Astronomy, Tufts University, Medford, MA 02155 (United States); Osvaldo Gonzalez Hernandez, J., E-mail: jog4m@virginia.edu [Istituto Nazionale di Fisica Nucleare (INFN) – Sezione di Torino, via P. Giuria, 1, 10125 Torino (Italy); Liuti, Simonetta, E-mail: sl4y@virginia.edu [University of Virginia – Physics Department, 382 McCormick Rd., Charlottesville, VA 22904 (United States); Laboratori Nazionali di Frascati, INFN, Frascati (Italy); Rajan, Abha, E-mail: ar5xc@virginia.edu [University of Virginia – Physics Department, 382 McCormick Rd., Charlottesville, VA 22904 (United States)

    2014-04-04

    We argue that due to parity constraints, the helicity combination of the purely momentum space counterparts of the Wigner distributions – the generalized transverse momentum distributions – that describes the configuration of an unpolarized quark in a longitudinally polarized nucleon can enter the deeply virtual Compton scattering amplitude only through matrix elements involving a final state interaction. The relevant matrix elements in turn involve light-cone operators projections in the transverse direction, or they appear in the deeply virtual Compton scattering amplitude at twist three. Orbital angular momentum or the spin structure of the nucleon was a major reason for these various distributions and amplitudes to have been introduced. We show that the twist three contributions associated with orbital angular momentum are related to the target-spin asymmetry in deeply virtual Compton scattering, already measured at HERMES.

  5. Angular resolution of the gaseous micro-pixel detector Gossip

    Science.gov (United States)

    Bilevych, Y.; Blanco Carballo, V.; van Dijk, M.; Fransen, M.; van der Graaf, H.; Hartjes, F.; Hessey, N.; Koppert, W.; Nauta, S.; Rogers, M.; Romaniouk, A.; Veenhof, R.

    2011-06-01

    Gossip is a gaseous micro-pixel detector with a very thin drift gap intended for a high rate environment like at the pixel layers of ATLAS at the sLHC. The detector outputs not only the crossing point of a traversing MIP, but also the angle of the track, thus greatly simplifying track reconstruction. In this paper we describe a testbeam experiment to examine the angular resolution of the reconstructed track segments in Gossip. We used here the low diffusion gas mixture DME/CO 2 50/50. An angular resolution of 20 mrad for perpendicular tracks could be obtained from a 1.5 mm thin drift volume. However, for the prototype detector used at the testbeam experiment, the resolution of slanting tracks was worsened by poor time resolution of the pixel chip used.

  6. Angular resolution of the gaseous micro-pixel detector Gossip

    Energy Technology Data Exchange (ETDEWEB)

    Bilevych, Y.; Blanco Carballo, V.; Dijk, M. van; Fransen, M.; Graaf, H. van der; Hartjes, F.; Hessey, N.; Koppert, W.; Nauta, S. [Nikhef, P.O. Box 41882, 1009 DB Amsterdam (Netherlands); Rogers, M. [Radboud University, P.O. Box 9102, 6500HC Nijmegen (Netherlands); Romaniouk, A.; Veenhof, R. [CERN, CH-1211, Geneve 23 (Switzerland)

    2011-06-15

    Gossip is a gaseous micro-pixel detector with a very thin drift gap intended for a high rate environment like at the pixel layers of ATLAS at the sLHC. The detector outputs not only the crossing point of a traversing MIP, but also the angle of the track, thus greatly simplifying track reconstruction. In this paper we describe a testbeam experiment to examine the angular resolution of the reconstructed track segments in Gossip. We used here the low diffusion gas mixture DME/CO{sub 2} 50/50. An angular resolution of 20 mrad for perpendicular tracks could be obtained from a 1.5 mm thin drift volume. However, for the prototype detector used at the testbeam experiment, the resolution of slanting tracks was worsened by poor time resolution of the pixel chip used.

  7. Angular resolution of the gaseous micro-pixel detector Gossip

    International Nuclear Information System (INIS)

    Bilevych, Y.; Blanco Carballo, V.; Dijk, M. van; Fransen, M.; Graaf, H. van der; Hartjes, F.; Hessey, N.; Koppert, W.; Nauta, S.; Rogers, M.; Romaniouk, A.; Veenhof, R.

    2011-01-01

    Gossip is a gaseous micro-pixel detector with a very thin drift gap intended for a high rate environment like at the pixel layers of ATLAS at the sLHC. The detector outputs not only the crossing point of a traversing MIP, but also the angle of the track, thus greatly simplifying track reconstruction. In this paper we describe a testbeam experiment to examine the angular resolution of the reconstructed track segments in Gossip. We used here the low diffusion gas mixture DME/CO 2 50/50. An angular resolution of 20 mrad for perpendicular tracks could be obtained from a 1.5 mm thin drift volume. However, for the prototype detector used at the testbeam experiment, the resolution of slanting tracks was worsened by poor time resolution of the pixel chip used.

  8. Cosmological forecasts from photometric measurements of the angular correlation function

    International Nuclear Information System (INIS)

    Sobreira, F.; Rosenfeld, R.; Simoni, F. de; Costa, L. A. N. da; Maia, M. A. G.; Makler, M.

    2011-01-01

    We study forecasts for the accuracy of the determination of cosmological parameters from future large-scale photometric surveys obtained using the full shape of the 2-point galaxy angular correlation function. The effects of linear redshift-space distortion, photometric redshift Gaussian errors, galaxy bias and nonlinearities in the power spectrum are included on our analysis. The Fisher information matrix is constructed with the full covariance matrix, including the correlation between nearby redshift shells arising from the photometric redshift error. We show that under some reasonable assumptions, a survey such as the imminent Dark Energy Survey should be able to constrain the dark energy equation of state parameter w and the cold dark matter density Ω cdm with a precision of the order of 20% and 13%, respectively, from the full shape of the angular correlation function alone. When combined with priors from other observations the precision in the determination of these parameters improve to 8% and 4%, respectively.

  9. Resolution of potential ambiguities through farside angular structure: Semiclassical analysis

    International Nuclear Information System (INIS)

    Fricke, S.H.; Brandan, M.E.; McVoy, K.W.

    1988-01-01

    The optical potential fits summarized in the preceding paper are subjected to a semiclassical analysis of the Ford-Wheeler--Knoll-Schaeffer type. The important broad dips in their farside cross sections, which are essential in greatly reducing potential ambiguities, are found (in partial agreement with a suggestion of Goldberg's) to be mainly weak ''Airy'' or rainbow minima, that serve to identify deeply penetrating trajectories. The semiclassical analysis also permits the identification and understanding of a new category of discrete and continuous potential ambiguities, and suggests the manner in which specific features of the angular distributions (such as spacings and depths of various angular minima) determine the Woods-Saxon parameters found by a chi-squared search

  10. Relativistic correction to the deuteron magnetic moment and angular condition

    International Nuclear Information System (INIS)

    Kondratyuk, L.A.; Strikman, M.I.

    1983-01-01

    The relativistic correction (RC) to the deuteron magnetic moment μsub(d) is investigated using the light-cone dynamics. The restrictions imposed by the angular condition on the electromagnetic current operator of deuteron are discussed in detail. It is shown that the additive model for the current operator of interacting consistuencies is consistent with the angular condition only for the two first terms of expansion of the ''good'' electromagnetic current component jsub(+) in powers of the momentum transfer q. The RC into μsub(d) is calculated using the mattix element of the ''good'' component. The account of RC decreases essentially the discrepancy between the theoretical and experimental values. The value of Δsub(μ) is determined for the Hamada-Johnston potential hard core potential (0.93x10 -2 ) for the Reid soft core potential (0.71x10 -2 ) and for the Paris potential (0.63x10 -2 )

  11. Analogies between optical and quantum mechanical angular momentum.

    Science.gov (United States)

    Nienhuis, Gerard

    2017-02-28

    The insight that a beam of light can carry orbital angular momentum (AM) in its propagation direction came up in 1992 as a surprise. Nevertheless, the existence of momentum and AM of an electromagnetic field has been well known since the days of Maxwell. We compare the expressions for densities of AM in general three-dimensional modes and in paraxial modes. Despite their classical nature, these expressions have a suggestive quantum mechanical appearance, in terms of linear operators acting on mode functions. In addition, paraxial wave optics has several analogies with real quantum mechanics, both with the wave function of a free quantum particle and with a quantum harmonic oscillator. We discuss how these analogies can be applied.This article is part of the themed issue 'Optical orbital angular momentum'. © 2017 The Author(s).

  12. Angular correlations in top quark decays in standard model extensions

    International Nuclear Information System (INIS)

    Batebi, S.; Etesami, S. M.; Mohammadi-Najafabadi, M.

    2011-01-01

    The CMS Collaboration at the CERN LHC has searched for the t-channel single top quark production using the spin correlation of the t-channel. The signal extraction and cross section measurement rely on the angular distribution of the charged lepton in the top quark decays, the angle between the charged lepton momentum and top spin in the top rest frame. The behavior of the angular distribution is a distinct slope for the t-channel single top (signal) while it is flat for the backgrounds. In this Brief Report, we investigate the contributions which this spin correlation may receive from a two-Higgs doublet model, a top-color assisted technicolor (TC2) and the noncommutative extension of the standard model.

  13. Angular distribution and atomic effects in condensed phase photoelectron spectroscopy

    International Nuclear Information System (INIS)

    Davis, R.F.

    1981-11-01

    A general concept of condensed phase photoelectron spectroscopy is that angular distribution and atomic effects in the photoemission intensity are determined by different mechanisms, the former being determined largely by ordering phenomena such as crystal momentum conservation and photoelectron diffraction while the latter are manifested in the total (angle-integrated) cross section. In this work, the physics of the photoemission process is investigated in several very different experiments to elucidate the mechanisms of, and correlation between, atomic and angular distribution effects. Theoretical models are discussed and the connection betweeen the two effects is clearly established. The remainder of this thesis, which describes experiments utilizing both angle-resolved and angle-integrated photoemission in conjunction with synchrotron radiation in the energy range 6 eV less than or equal to h ν less than or equal to 360 eV and laboratory sources, is divided into three parts

  14. Angular momentum projection of cranked PNC wave function

    International Nuclear Information System (INIS)

    Han Yong

    2000-01-01

    In studying the properties of nuclear higher-spin states, not only the K-mixture needed to be taken into account, but also the Coriolis interaction (the cranking term) should be introduced. The cranking term breaks the time reversal symmetry, and the projection of the single-particle angular momentum on the intrinsic symmetric axis is no longer a good quantum number. This makes the theoretical calculation somewhat complicated. However, considering some intrinsic symmetry in a nucleus, it is not very difficult to apply the angular momentum projection technique to the PNC wave functions including the cranking components (the cranked PNC wave functions). The fundamental expressions for calculating the nuclear energy spectra and the electromagnetic properties are deduced and evaluated in theory, consequently the feasibility of actualizing the present scheme is made clear

  15. Report on the ESO Workshop ''Astronomy at High Angular Resolution''

    Science.gov (United States)

    Boffin, H.; Schmidtobreick, L.; Hussain, G.; Berger, J.-Ph.

    2015-03-01

    A workshop took place in Brussels in 2000 on astrotomography, a generic term for indirect mapping techniques that can be applied to a huge variety of astrophysical systems, ranging from planets, single stars and binaries to active galactic nuclei. It appeared to be timely to revisit the topic given the many past, recent and forthcoming improvements in telescopes and instrumentation. We therefore decided to repeat the astrotomography workshop, but to put it into the much broader context of high angular resolution astronomy. Many techniques, from lucky and speckle imaging, adaptive optics to interferometry, are now widely employed to achieve high angular resolution and they have led to an amazing number of new discoveries. A summary of the workshop themes is presented.

  16. A New Shape Description Method Using Angular Radial Transform

    Science.gov (United States)

    Lee, Jong-Min; Kim, Whoi-Yul

    Shape is one of the primary low-level image features in content-based image retrieval. In this paper we propose a new shape description method that consists of a rotationally invariant angular radial transform descriptor (IARTD). The IARTD is a feature vector that combines the magnitude and aligned phases of the angular radial transform (ART) coefficients. A phase correction scheme is employed to produce the aligned phase so that the IARTD is invariant to rotation. The distance between two IARTDs is defined by combining differences in the magnitudes and aligned phases. In an experiment using the MPEG-7 shape dataset, the proposed method outperforms existing methods; the average BEP of the proposed method is 57.69%, while the average BEPs of the invariant Zernike moments descriptor and the traditional ART are 41.64% and 36.51%, respectively.

  17. Dijet angular distributions in direct and resolved photoproduction at HERA

    International Nuclear Information System (INIS)

    Derrick, M.; Krakauer, D.; Magill, S.

    1996-05-01

    Jet photoproduction, where the two highest transverse energy (E T jet ) jets have E T jet above 6 GeV and a jet-jet invariant mass above 23 GeV, has been studied with the ZEUS detector at the HERA ep collider. Resolved and direct photoproduction samples have been separated. The cross section as a function of the angle between the jet-jet axis and the beam direction in the dijet rest frame has been measured for the two samples. The measured angular distributions differ markedly from each other. They agree with the predictions of QCD calculations, where the different angular distributions reflect the different spins of the quark and gluon exchanged in the hard subprocess. (orig.)

  18. Angular signatures, and a space-borne measurement concept

    Energy Technology Data Exchange (ETDEWEB)

    Gerstl, S.A.W.

    1996-05-01

    The nature and value of angular signatures in remote sensing are reviewed with emphasis on the canopy hot-spot as a directionally localized angular signature and an important special case of a BRDF (bidirectional reflectance distribution function). A new concept is presented that allows hot spot measurements from space by using active (laser) illumination and bistatic detection. The detectors are proposed as imaging array sensors that are circulating the illumination source (or vice versa) and are connected with it through tethers in space which also provide the directional controls needed so that the entire system becomes pointable like a search light. Near infrared or IR operation in an atmospheric transmission winodw is envisioned with night-time data acquistion. Detailed feasibility and systems analyses have yet to be performed.

  19. Investigating pointing tasks across angularly coupled display areas

    DEFF Research Database (Denmark)

    Hennecke, Fabian; De Luca, Alexander; Nguyen, Ngo Dieu Huong

    2013-01-01

    Pointing tasks are a crucial part of today’s graphical user interfaces. They are well understood for flat displays and most prominently are modeled through Fitts’ Law. For novel displays (e.g., curved displays with multi-purpose areas), however, it remains unclear whether such models for predicting...... that the target position affects overall pointing speed and offset in both conditions. However, we also found that Fitts’ Law can in fact still be used to predict performance as on flat displays. Our results help designers to optimize user interfaces on angularly coupled displays when pointing tasks are involved....... user performance still hold – in particular when pointing is performed across differently oriented areas. To answer this question, we conducted an experiment on an angularly coupled display – the Curve – with two input conditions: direct touch and indirect mouse pointer. Our findings show...

  20. Angular-momentum nonclassicality by breaking classical bounds on statistics

    Energy Technology Data Exchange (ETDEWEB)

    Luis, Alfredo [Departamento de Optica, Facultad de Ciencias Fisicas, Universidad Complutense, E-28040 Madrid (Spain); Rivas, Angel [Departamento de Fisica Teorica I, Facultad de Ciencias Fisicas, Universidad Complutense, E-28040 Madrid (Spain)

    2011-10-15

    We derive simple practical procedures revealing the quantum behavior of angular momentum variables by the violation of classical upper bounds on the statistics. Data analysis is minimum and definite conclusions are obtained without evaluation of moments, or any other more sophisticated procedures. These nonclassical tests are very general and independent of other typical quantum signatures of nonclassical behavior such as sub-Poissonian statistics, squeezing, or oscillatory statistics, being insensitive to the nonclassical behavior displayed by other variables.

  1. Automatic spectrometer for γ-γ angular correlation

    International Nuclear Information System (INIS)

    Saxena, R.N.; Monteiro, M.T.S.; Bairrio Nuevo Junior, A.

    1974-01-01

    An automated γ-γ angular correlation spectrometer is described in detail. Eletronic arrangements used in integral and differential measurements have also been described. In part I there is a short theoretical introduction, the experimental arrangement is described in part II. The results of the directional correlation measurement of γ-cascades in 60 Ni and 75 As and of the lifetime measurement of excited states in 181 Ta and 81 Br have been described in part III

  2. Angular distributions and total yield of laser ablated silver

    DEFF Research Database (Denmark)

    Svendsen, Winnie Edith; Nordskov, A.; Schou, Jørgen

    1997-01-01

    The angular distribution of laser ablated silver has been measured in situ with a newly constructed setup with an array of microbalances. The distribution is strongly peaked in the forward direction corresponding to cospθ, where p varies between 5 and 9 for laser fluences from 2 to 7 J/cm2 at 355...... nm for a beam spot of 0.015 cm2. The total deposited yield is of the order 1015 Ag-atoms per pulse....

  3. Spatial Angular Compounding Technique for H-Scan Ultrasound Imaging.

    Science.gov (United States)

    Khairalseed, Mawia; Xiong, Fangyuan; Kim, Jung-Whan; Mattrey, Robert F; Parker, Kevin J; Hoyt, Kenneth

    2018-01-01

    H-Scan is a new ultrasound imaging technique that relies on matching a model of pulse-echo formation to the mathematics of a class of Gaussian-weighted Hermite polynomials. This technique may be beneficial in the measurement of relative scatterer sizes and in cancer therapy, particularly for early response to drug treatment. Because current H-scan techniques use focused ultrasound data acquisitions, spatial resolution degrades away from the focal region and inherently affects relative scatterer size estimation. Although the resolution of ultrasound plane wave imaging can be inferior to that of traditional focused ultrasound approaches, the former exhibits a homogeneous spatial resolution throughout the image plane. The purpose of this study was to implement H-scan using plane wave imaging and investigate the impact of spatial angular compounding on H-scan image quality. Parallel convolution filters using two different Gaussian-weighted Hermite polynomials that describe ultrasound scattering events are applied to the radiofrequency data. The H-scan processing is done on each radiofrequency image plane before averaging to get the angular compounded image. The relative strength from each convolution is color-coded to represent relative scatterer size. Given results from a series of phantom materials, H-scan imaging with spatial angular compounding more accurately reflects the true scatterer size caused by reductions in the system point spread function and improved signal-to-noise ratio. Preliminary in vivo H-scan imaging of tumor-bearing animals suggests this modality may be useful for monitoring early response to chemotherapeutic treatment. Overall, H-scan imaging using ultrasound plane waves and spatial angular compounding is a promising approach for visualizing the relative size and distribution of acoustic scattering sources. Copyright © 2018 World Federation for Ultrasound in Medicine and Biology. Published by Elsevier Inc. All rights reserved.

  4. Monitoring Location and Angular Orientation of a Pill

    Science.gov (United States)

    Schipper, John F.

    2012-01-01

    A mobile pill transmitter system moves through, or adjacent to, one or more organs in an animal or human body, while transmitting signals from its present location and/or present angular orientation. The system also provides signals from which the present roll angle of the pill, about a selected axis, can be determined. When the location coordinates angular orientation and the roll angle of the pill are within selected ranges, an aperture on the pill container releases a selected chemical into, or onto, the body. Optionally, the pill, as it moves, provides a sequence of visually perceptible images. The times for image formation may correspond to times at which the pill transmitter system location or image satisfies one of at least four criteria. This invention provides and supplies an algorithm for exact determination of location coordinates and angular orientation coordinates for a mobile pill transmitter (PT), or other similar device that is introduced into, and moves within, a GI tract of a human or animal body. A set of as many as eight nonlinear equations has been developed and applied, relating propagation of a wireless signal between either two, three, or more transmitting antennas located on the PT, to four or more non-coplanar receiving antennas located on a signal receiver appliance worn by the user. The equations are solved exactly, without approximations or iterations, and are applied in several environments: (1) association of a visual image, transmitted by the PT at each of a second sequence of times, with a PT location and PT angular orientation at that time; (2) determination of a position within the body at which a drug or chemical substance or other treatment is to be delivered to a selected portion of the body; (3) monitoring, after delivery, of the effect(s) of administration of the treatment; and (4) determination of one or more positions within the body where provision and examination of a finer-scale image is warranted.

  5. Viscous damping of toroidal angular momentum in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Stacey, W. M. [Georgia Tech Fusion Research Center, Atlanta, Georgia 30332 (United States)

    2014-09-15

    The Braginskii viscous stress tensor formalism was generalized to accommodate non-axisymmetric 3D magnetic fields in general toroidal flux surface geometry in order to provide a representation for the viscous damping of toroidal rotation in tokamaks arising from various “neoclassical toroidal viscosity” mechanisms. In the process, it was verified that the parallel viscosity contribution to damping toroidal angular momentum still vanishes even in the presence of toroidal asymmetries, unless there are 3D radial magnetic fields.

  6. A program for performing angular integrations for transition operators

    International Nuclear Information System (INIS)

    Froese Fischer, C.; Godefroid, M.R.; Hibbert, A.

    1991-01-01

    The MCHF-MLTPOL program performs the angular integrations necessary for expressing the matrix elements of transition operators, E1, E2, ..., or M1, M2, ..., as linear combinations of radial integrals. All matrix elements for transitions between two lists of configuration states will be evaluated. A limited amount of non-orthogonality is allowed between orbitals of the initial and final state. (orig.)

  7. Angular dependence of the nanoDot OSL dosimeter

    International Nuclear Information System (INIS)

    Kerns, James R.; Kry, Stephen F.; Sahoo, Narayan; Followill, David S.; Ibbott, Geoffrey S.

    2011-01-01

    Purpose: Optically stimulated luminescent detectors (OSLDs) are quickly gaining popularity as passive dosimeters, with applications in medicine for linac output calibration verification, brachytherapy source verification, treatment plan quality assurance, and clinical dose measurements. With such wide applications, these dosimeters must be characterized for numerous factors affecting their response. The most abundant commercial OSLD is the InLight/OSL system from Landauer, Inc. The purpose of this study was to examine the angular dependence of the nanoDot dosimeter, which is part of the InLight system. Methods: Relative dosimeter response data were taken at several angles in 6 and 18 MV photon beams, as well as a clinical proton beam. These measurements were done within a phantom at a depth beyond the build-up region. To verify the observed angular dependence, additional measurements were conducted as well as Monte Carlo simulations in MCNPX. Results: When irradiated with the incident photon beams parallel to the plane of the dosimeter, the nanoDot response was 4% lower at 6 MV and 3% lower at 18 MV than the response when irradiated with the incident beam normal to the plane of the dosimeter. Monte Carlo simulations at 6 MV showed similar results to the experimental values. Examination of the results in Monte Carlo suggests the cause as partial volume irradiation. In a clinical proton beam, no angular dependence was found. Conclusions: A nontrivial angular response of this OSLD was observed in photon beams. This factor may need to be accounted for when evaluating doses from photon beams incident from a variety of directions.

  8. Angular dependence of the parallel plate ionization chambers of Ipen

    International Nuclear Information System (INIS)

    Albuquerque, M. da P.P.; Caldas, L.

    1989-08-01

    The ionization chambers with parallel plates designed and constructed at IPEN for the dosimetry of soft X-radiation fields were studied in relation to thein angular dependence between O and +- 90 0 . The objective of this study is to verify the chambers response variation for small positioning errors during the field dosimetry used in Radiotherapy. The results were compared with those of commercial parallel plate ionization chambers used as secondary and testiary standards. (author) [pt

  9. Tunnelling of orbital angular momentum in parallel optical waveguides

    International Nuclear Information System (INIS)

    Alexeyev, C N; Fadeyeva, T A; Yavorsky, M A; Boklag, N A

    2011-01-01

    We study the evolution of circularly polarized optical vortices (OVs) in the system of two coupled few-mode optical fibres. We demonstrate that upon propagation OVs tunnel into the adjacent fibre as a complex superposition of OVs that comprise also OVs of opposite polarization and topological charge. The initial OV may tunnel into the other fibre as the same vortex state of lesser energy. The evolution of the orbital angular momentum in coupled fibres is studied

  10. Angular momentum coupling in atom-atom collisions

    International Nuclear Information System (INIS)

    Grosser, J.

    1986-01-01

    The coupling between the electronic angular momentum and the rotating atom-atom axis in the initial or the final phase of an atom-atom collision is discussed, making use of the concepts of radial and rotational (Coriolis) coupling between different molecular states. The description is based on a limited number of well-understood approximations, and it allows an illustrative geometric representation of the transition from the body fixed to the space fixed motion of the electrons. (orig.)

  11. Determinantal method for complex angular momenta in potential scattering

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B. W. [University of Pennsylvania, Philadelphia, PA (United States)

    1963-01-15

    In this paper I would like do describe a formulation of the complex angular momenta in potential scattering based on the Lippmann-Schwinger integral equation rather than on the Schrödinger differential equation. This is intended as a preliminary to the paper by SAWYER on the Regge poles and high energy limits in field theory (Bethe-Salpeter amplitudes), where the integral formulation is definitely more advantageous than the differential formulation.

  12. Asymmetric photoelectron angular distributions from interfering photoionization processes

    International Nuclear Information System (INIS)

    Yin, Y.; Chen, C.; Elliott, D.S.; Smith, A.V.

    1992-01-01

    We have measured asymmetric photoelectron angular distributions for atomic rubidium. Ionization is induced by a one-photon interaction with 280 nm light and by a two-photon interaction with 560 nm light. Interference between the even- and odd-parity free-electron wave functions allows us to control the direction of maximum electron flux by varying the relative phase of the two laser fields

  13. Measurement of Dijet Angular Distributions and Search for Quark Compositeness

    International Nuclear Information System (INIS)

    Gomez, B.; Hoeneisen, B.; Mooney, P.; Negret, J.P.; Davis, K.; Fein, D.; Forden, G.E.; Guida, J.A.; James, E.; Johns, K.; Nang, F.; Narayanan, A.; Rutherfoord, J.; Butler, J.M.; Fatyga, M.; Featherly, J.; Gibbard, B.; Gordon, H.; Graf, N.; Kahn, S.; Kotcher, J.; Protopopescu, S.; Rajagopalan, S.; Bantly, J.; Cullen-Vidal, D.; Cutts, D.; Guida, J.M.; Hoftun, J.S.; Partridge, R.; Grinstein, S.; Piegaia, R.; Bloom, P.; Fisyak, Y.; Glenn, S.; Grim, G.; Klopfenstein, C.; Lander, R.; Mani, S.; Fahland, T.; Hall, R.E.; Boswell, C.; Choudhary, B.C.; Cochran, J.; Ellison, J.; Gartung, P.; Gounder, K.; Huehn, T.; Alves, G.A.; Carvalho, W.; Maciel, A.K.; Motta, H.; Nicola, M.; Santoro, A.; Castilla-Valdez, H.; Gonzalez Solis, J.L.; Hernandez-Montoya, R.; Magana-Mendoza, L.; Sanchez-Hernandez, A.; Adam, I.; Kotwal, A.V.; Bhattacharjee, M.; Ahn, S.; Baldin, B.; Bartlett, J.F.; Bhat, P.C.; Boehnlein, A.; Borcherding, F.; Brandt, A.; Bross, A.; Christenson, J.H.; Cooper, W.E.; Demarteau, M.; Denisov, D.; Diehl, H.T.; Diesburg, M.; Feher, S.; Fisk, H.E.; Flattum, E.; Fuess, S.; Genser, K.; Gerber, C.E.; Green, D.R.; Greenlee, H.; Grossman, N.; Haggerty, H.; Hansen, S.; Heintz, U.; Hobbs, J.

    1998-01-01

    We have measured the dijet angular distribution in √(s)=1.8 TeV p bar p collisions using the D0 detector. Order α 3 s QCD predictions are in good agreement with the data. At 95% confidence limit the data exclude models of quark compositeness in which the contact interaction scale is below 2TeV. copyright 1998 The American Physical Society

  14. Black hole mass and angular momentum in topologically massive gravity

    International Nuclear Information System (INIS)

    Bouchareb, Adel; Clement, Gerard

    2007-01-01

    We extend the Abbott-Deser-Tekin approach to the computation of the Killing charge for a solution of topologically massive gravity (TMG) linearized around an arbitrary background. This is then applied to evaluate the mass and angular momentum of black hole solutions of TMG with non-constant curvature asymptotics. The resulting values, together with the appropriate black hole entropy, fit nicely into the first law of black hole thermodynamics

  15. Black hole mass and angular momentum in topologically massive gravity

    Energy Technology Data Exchange (ETDEWEB)

    Bouchareb, Adel; Clement, Gerard [Laboratoire de Physique Theorique LAPTH (CNRS), BP 110, F-74941 Annecy-le-Vieux cedex (France)

    2007-11-21

    We extend the Abbott-Deser-Tekin approach to the computation of the Killing charge for a solution of topologically massive gravity (TMG) linearized around an arbitrary background. This is then applied to evaluate the mass and angular momentum of black hole solutions of TMG with non-constant curvature asymptotics. The resulting values, together with the appropriate black hole entropy, fit nicely into the first law of black hole thermodynamics.

  16. Characterization of the Bell-Shaped Vibratory Angular Rate Gyro

    Directory of Open Access Journals (Sweden)

    Junfang Fan

    2013-08-01

    Full Text Available The bell-shaped vibratory angular rate gyro (abbreviated as BVG is a novel shell vibratory gyroscope, which is inspired by the Chinese traditional bell. It sensitizes angular velocity through the standing wave precession effect. The bell-shaped resonator is a core component of the BVG and looks like the millimeter-grade Chinese traditional bell, such as QianLong Bell and Yongle Bell. It is made of Ni43CrTi, which is a constant modulus alloy. The exciting element, control element and detection element are uniformly distributed and attached to the resonator, respectively. This work presents the design, analysis and experimentation on the BVG. It is most important to analyze the vibratory character of the bell-shaped resonator. The strain equation, internal force and the resonator's equilibrium differential equation are derived in the orthogonal curvilinear coordinate system. When the input angular velocity is existent on the sensitive axis, an analysis of the vibratory character is performed using the theory of thin shells. On this basis, the mode shape function and the simplified second order normal vibration mode dynamical equation are obtained. The coriolis coupling relationship about the primary mode and secondary mode is established. The methods of the signal processing and control loop are presented. Analyzing the impact resistance property of the bell-shaped resonator, which is compared with other shell resonators using the Finite Element Method, demonstrates that BVG has the advantage of a better impact resistance property. A reasonable means of installation and a prototypal gyro are designed. The gyroscopic effect of the BVG is characterized through experiments. Experimental results show that the BVG has not only the advantages of low cost, low power, long work life, high sensitivity, and so on, but, also, of a simple structure and a better impact resistance property for low and medium angular velocity measurements.

  17. Cubature/ Unscented/ Sigma Point Kalman Filtering with Angular Measurement Models

    Science.gov (United States)

    2015-07-06

    similarly transformed to work with the Laplace distribution. Cubature formulae for w(x) = 1 over regions of various shapes could be used for evaluating...measurement and process non- linearities, such as the cubature Kalman filter, can perform ex- tremely poorly in many applications involving angular...in the form of the “unscented transform ”) consider just converting such measurements into Cartesian coordinates and feeding the converted measurements

  18. BAO from Angular Clustering: Optimization and Mitigation of Theoretical Systematics

    Energy Technology Data Exchange (ETDEWEB)

    Crocce, M.; et al.

    2018-01-13

    We study the theoretical systematics and optimize the methodology in Baryon Acoustic Oscillations (BAO) detections using the angular correlation function with tomographic bins. We calibrate and optimize the pipeline for the Dark Energy Survey Year 1 dataset using 1800 mocks. We compare the BAO fitting results obtained with three estimators: the Maximum Likelihood Estimator (MLE), Profile Likelihood, and Markov Chain Monte Carlo. The MLE method yields the least bias in the fit results (bias/spread $\\sim 0.02$) and the error bar derived is the closest to the Gaussian results (1% from 68% Gaussian expectation). When there is mismatch between the template and the data either due to incorrect fiducial cosmology or photo-$z$ error, the MLE again gives the least-biased results. The BAO angular shift that is estimated based on the sound horizon and the angular diameter distance agree with the numerical fit. Various analysis choices are further tested: the number of redshift bins, cross-correlations, and angular binning. We propose two methods to correct the mock covariance when the final sample properties are slightly different from those used to create the mock. We show that the sample changes can be accommodated with the help of the Gaussian covariance matrix or more effectively using the eigenmode expansion of the mock covariance. The eigenmode expansion is significantly less susceptible to statistical fluctuations relative to the direct measurements of the covariance matrix because the number of free parameters is substantially reduced [$p$ parameters versus $p(p+1)/2$ from direct measurement].

  19. Uniqueness for the inverse backscattering problem for angularly controlled potentials

    International Nuclear Information System (INIS)

    Rakesh; Uhlmann, Gunther

    2014-01-01

    We consider the problem of recovering a smooth, compactly supported potential on R 3 from its backscattering data. We show that if two such potentials have the same backscattering data and the difference of the two potentials has controlled angular derivatives, then the two potentials are identical. In particular, if two potentials differ by a finite linear combination of spherical harmonics with radial coefficients and have the same backscattering data then the two potentials are identical. (paper)

  20. Interaction of calreticulin with CD40 ligand, TRAIL and Fas ligand

    DEFF Research Database (Denmark)

    Duus, K; Pagh, R T; Holmskov, U

    2007-01-01

    is utilized by many other functionally diverse molecules and in this work the interaction of calreticulin with C1q and structurally similar molecules was investigated. In addition to C1q and MBL, CD40 ligand (CD40L), tumour necrosis factor-related apoptosis-inducing ligand (TRAIL) and Fas ligand (FasL) were...... found to bind calreticulin strongly. A low level or no binding was observed for adiponectin, tumour necrosis factor-alpha (TNF-alpha), CD30L, surfactant protein-A and -D and collagen VIII. The interaction with calreticulin required a conformational change in CD40L, TRAIL and FasL and showed the same...

  1. How we are building a complex Angular 2 application at Inspire

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    In this talk, at first we will talk about some basic and advanced Angular 2 concepts, then we will share our experiences with Angular 2 that we had so far while building a complex library and web applications at Inspire.

  2. Nuclear level density parameter 's dependence on angular momentum

    International Nuclear Information System (INIS)

    Aggarwal, Mamta; Kailas, S.

    2009-01-01

    Nuclear level densities represent a very important ingredient in the statistical Model calculations of nuclear reaction cross sections and help to understand the microscopic features of the excited nuclei. Most of the earlier experimental nuclear level density measurements are confined to low excitation energy and low spin region. A recent experimental investigation of nuclear level densities in high excitation energy and angular momentum domain with some interesting results on inverse level density parameter's dependence on angular momentum in the region around Z=50 has motivated us to study and analyse these experimental results in a microscopic theoretical framework. In the experiment, heavy ion fusion reactions are used to populate the excited and rotating nuclei and measured the α particle evaporation spectra in coincidence with ray multiplicity. Residual nuclei are in the range of Z R 48-55 with excitation energy range 30 to 40 MeV and angular momentum in 10 to 25. The inverse level density parameter K is found to be in the range of 9.0 - 10.5 with some exceptions

  3. Turbulent transport of toroidal angular momentum in low flow gyrokinetics

    International Nuclear Information System (INIS)

    Parra, Felix I; Catto, Peter J

    2010-01-01

    We derive a self-consistent equation for the turbulent transport of toroidal angular momentum in tokamaks in the low flow ordering that only requires solving gyrokinetic Fokker-Planck and quasineutrality equations correct to second order in an expansion on the gyroradius over scale length. We also show that according to our orderings the long wavelength toroidal rotation and the long wavelength radial electric field satisfy the neoclassical relation that gives the toroidal rotation as a function of the radial electric field and the radial gradients of pressure and temperature. Thus, the radial electric field can be solved for once the toroidal rotation is calculated from the transport of toroidal angular momentum. Unfortunately, even though this methodology only requires a gyrokinetic model correct to second order in gyroradius over scale length, current gyrokinetic simulations are only valid to first order. To overcome this difficulty, we exploit the smallish ratio B p /B, where B is the total magnetic field and B p is its poloidal component. When B p /B is small, the usual first order gyrokinetic equation provides solutions that are accurate enough to employ for our expression for the transport of toroidal angular momentum. We show that current δf and full f simulations only need small corrections to achieve this accuracy. Full f simulations, however, are still unable to determine the long wavelength, radial electric field from the quasineutrality equation.

  4. New energy levels of praseodymium with large angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Shamim; Siddiqui, Imran; Gamper, Bettina; Syed, Tanweer Iqbal; Guthoehrlein, Guenter H.; Windholz, Laurentius [Inst. f. Experimentalphysik, Techn. Univ. Graz, Petersgasse 16, A-8010 Graz (Austria)

    2011-07-01

    The electronic ground state configuration of praseodymium {sup 59}Pr{sub 141} is [Xe] 4f{sup 3}6s{sup 2}, with ground state level {sup 4}I{sub 9/2}. Our research is mainly devoted to find previously unknown energy levels by the investigation of spectral lines and their hyperfine structures. In a hollow cathode discharge lamp praseodymium atoms and ions in ground and excited states are excited to high lying states by laser light. The excitation source is a tunable ring-dye laser system, operated with R6G, Kiton Red, DCM and LD700. A high resolution Fourier transform spectrum is used for selecting promising excitation wavelengths. Then the laser wavelength is tuned to a strong hyperfine component of the spectral line to be investigated, and a search for fluorescence from excited levels is performed. From the observed hyperfine structure we determine J-values and hyperfine constants A of the combining levels. This information, together with excitation and fluorescence wavelengths, allows us to find the energies of involved new levels. Up to now we have discovered large number of previously unknown energy levels with various angular momentum values. We present here the data (energies, parities, angular momenta J, magnetic hyperfine constants A) of ca. 40 new, until now unknown energy levels with high angular momentum values: 15/2, 17/2, 19/2, 21/2.

  5. Angular power spectrum in publically released ALICE events

    Science.gov (United States)

    Llanes-Estrada, Felipe J.; Muñoz Martinez, Jose L.

    2018-02-01

    We study the particles emitted in the fireball following a Relativistic Heavy Ion Collision with the traditional angular analysis employed in cosmology and earth sciences, producing Mollweide plots of the number and pt distribution of a few actual, publically released ALICE-collaboration events and calculating their angular power spectrum. We also examine the angular spectrum of a simple two-particle correlation. While this may not be the optimal way of analyzing heavy ion data, our intention is to provide a one to one comparison to analysis in cosmology. With the limited statistics at hand, we do not find evidence for acoustic peaks but a decrease of Cl that is reminiscent of viscous attenuation, but subject to a strong effect from the rapidity acceptance which probably dominates (so we also subtract the m = 0 component). As an exercise, we still extract a characteristic Silk damping length (proportional to the square root of the viscosity over entropy density ratio) to illustrate the method. The absence of acoustic-like peaks is also compatible with a crossover from the QGP to the hadron gas (because a surface tension at domain boundaries would effect a restoring force that could have driven acoustic oscillations). Presently we do not understand a depression of the l = 6 multipole strength; perhaps ALICE could reexamine it with full statistics.

  6. Angular dependence of spin-orbit spin-transfer torques

    KAUST Repository

    Lee, Ki-Seung

    2015-04-06

    In ferromagnet/heavy-metal bilayers, an in-plane current gives rise to spin-orbit spin-transfer torque, which is usually decomposed into fieldlike and dampinglike torques. For two-dimensional free-electron and tight-binding models with Rashba spin-orbit coupling, the fieldlike torque acquires nontrivial dependence on the magnetization direction when the Rashba spin-orbit coupling becomes comparable to the exchange interaction. This nontrivial angular dependence of the fieldlike torque is related to the Fermi surface distortion, determined by the ratio of the Rashba spin-orbit coupling to the exchange interaction. On the other hand, the dampinglike torque acquires nontrivial angular dependence when the Rashba spin-orbit coupling is comparable to or stronger than the exchange interaction. It is related to the combined effects of the Fermi surface distortion and the Fermi sea contribution. The angular dependence is consistent with experimental observations and can be important to understand magnetization dynamics induced by spin-orbit spin-transfer torques.

  7. Mass and Angular Distributions of Charged Dihadron Production

    Energy Technology Data Exchange (ETDEWEB)

    Cummings, Mary Clare [Michigan U.

    1990-01-01

    Experiment 711, conducted at Fermilab. provided a unique handle towards understanding valence quark scattering by studying pairs of single. charged, high transverse momentum hadrons produced in collisions of 800 GeV /c protons on fixed metal targets. The apparatus consisted of a double-arm spectrometer. calorimetrically triggered. with high momentum resolution and a large angular acceptance for all charge states of particle pairs. The experiment was designed to select those hadron pairs that carrted most of the momentum and energy of the underlying scattered quarks and gluons. The charge of such "leading" hadrons is correlated with the charge of the quark that produced it. Quantum Chromodynamics (QCD) assumes that the scattering behavior of quarks ts independent of their charge, or "flavour": Experiment 711 could test this assumption. Tilis dissertation descrtbes the analysis of the mass and angular distributions of hadron pair production for three separate charge states: +-, ++ and --. The angular distributions are found to deviate from theory predictions of flavour symmetry. Also. the mass cross sections indicate ratios of positive to negative hard-scattered particles that are larger than expected from theory. These results could warrant reconsideration of the assumptions and approximations currently made in leading-order QCD calculations.

  8. Dual electromagnetism: helicity, spin, momentum and angular momentum

    International Nuclear Information System (INIS)

    Bliokh, Konstantin Y; Nori, Franco; Bekshaev, Aleksandr Y

    2013-01-01

    The dual symmetry between electric and magnetic fields is an important intrinsic property of Maxwell equations in free space. This symmetry underlies the conservation of optical helicity and, as we show here, is closely related to the separation of spin and orbital degrees of freedom of light (the helicity flux coincides with the spin angular momentum). However, in the standard field-theory formulation of electromagnetism, the field Lagrangian is not dual symmetric. This leads to problematic dual-asymmetric forms of the canonical energy–momentum, spin and orbital angular-momentum tensors. Moreover, we show that the components of these tensors conflict with the helicity and energy conservation laws. To resolve this discrepancy between the symmetries of the Lagrangian and Maxwell equations, we put forward a dual-symmetric Lagrangian formulation of classical electromagnetism. This dual electromagnetism preserves the form of Maxwell equations, yields meaningful canonical energy–momentum and angular-momentum tensors, and ensures a self-consistent separation of the spin and orbital degrees of freedom. This provides a rigorous derivation of the results suggested in other recent approaches. We make the Noether analysis of the dual symmetry and all the Poincaré symmetries, examine both local and integral conserved quantities and show that only the dual electromagnetism naturally produces a complete self-consistent set of conservation laws. We also discuss the observability of physical quantities distinguishing the standard and dual theories, as well as relations to quantum weak measurements and various optical experiments. (paper)

  9. Angular deflection of rotary nickel titanium files: a comparative study

    Directory of Open Access Journals (Sweden)

    Gianluca Gambarini

    2009-12-01

    Full Text Available A new manufacturing method of twisting nickel titanium wire to produce rotary nickel titanium (RNT files has recently been developed. The aim of the present study was to evaluate whether the new manufacturing process increased the angular deflection of RNT files, by comparing instruments produced using the new manufacturing method (Twisted Files versus instruments produced with the traditional grinding process. Testing was performed on a total of 40 instruments of the following commercially available RNT files: Twisted Files (TF, Profile, K3 and M2 (NRT. All instruments tested had the same dimensions (taper 0.06 and tip size 25. Test procedures strictly followed ISO 3630-1. Data were collected and statistically analyzed by means ANOVA test. The results showed that TF demonstrated significantly higher average angular deflection levels (P<0.05, than RNT manufactured by a grinding process. Since angular deflection represent the amount of rotation (and consequently deformation that a RNT file can withstand before torsional failure, such a significant improvement is a favorable property for the clinical use of the tested RNT files.

  10. Angular glint effects generation for false naval target verisimility requirements

    International Nuclear Information System (INIS)

    Kostis, Theodoros G; Galanis, Konstantinos G; Katsikas, Sokratis K

    2009-01-01

    A stimulating problem in the generation of coherent countermeasures for high range resolution radar systems is the inclusion of angular glint effects in the preparation of the false target mask. Since angular glint is representative of extended naval targets, this inclusion increases the credibility factor of the decoy playback signal at the adversary radar-operator station. In this paper, the ability of an interferometric inverse synthetic aperture radar (InISAR) simulator to provide a proof of concept towards the clarification of this challenging task is ascertained. The solution consists of three novel vector representations of the generated data, which are proven to behave according to the laws of physics governing the glint phenomenon. The first depiction is the angular glint injection at the target which is followed by the representation of the wavefront distortion at the radar. A value-added time procession integration of the target in pure roll motion provides an expected by ISAR theory side-view image of the naval extended false target. The effectiveness of the proposed approach through verification and validation of the results by using the method of pictorial evidence is established. A final argument is raised on the usage of this software tool for actual obfuscation and deception actions for air defence at sea applications

  11. Angular parallelization of a curvilinear Sn transport theory method

    International Nuclear Information System (INIS)

    Haghighat, A.

    1991-01-01

    In this paper a parallel algorithm for angular domain decomposition (or parallelization) of an r-dependent spherical S n transport theory method is derived. The parallel formulation is incorporated into TWOTRAN-II using the IBM Parallel Fortran compiler and implemented on an IBM 3090/400 (with four processors). The behavior of the parallel algorithm for different physical problems is studied, and it is concluded that the parallel algorithm behaves differently in the presence of a fission source as opposed to the absence of a fission source; this is attributed to the relative contributions of the source and the angular redistribution terms in the S s algorithm. Further, the parallel performance of the algorithm is measured for various problem sizes and different combinations of angular subdomains or processors. Poor parallel efficiencies between ∼35 and 50% are achieved in situations where the relative difference of parallel to serial iterations is ∼50%. High parallel efficiencies between ∼60% and 90% are obtained in situations where the relative difference of parallel to serial iterations is <35%

  12. Shocks in the relativistic transonic accretion with low angular momentum

    Science.gov (United States)

    Suková, P.; Charzyński, S.; Janiuk, A.

    2017-12-01

    We perform 1D/2D/3D relativistic hydrodynamical simulations of accretion flows with low angular momentum, filling the gap between spherically symmetric Bondi accretion and disc-like accretion flows. Scenarios with different directional distributions of angular momentum of falling matter and varying values of key parameters such as spin of central black hole, energy and angular momentum of matter are considered. In some of the scenarios the shock front is formed. We identify ranges of parameters for which the shock after formation moves towards or outwards the central black hole or the long-lasting oscillating shock is observed. The frequencies of oscillations of shock positions which can cause flaring in mass accretion rate are extracted. The results are scalable with mass of central black hole and can be compared to the quasi-periodic oscillations of selected microquasars (such as GRS 1915+105, XTE J1550-564 or IGR J17091-3624), as well as to the supermassive black holes in the centres of weakly active galaxies, such as Sgr A*.

  13. Enhanced angular overlap model for nonmetallic f -electron systems

    Science.gov (United States)

    Gajek, Z.

    2005-07-01

    An efficient method of interpretation of the crystal field effect in nonmetallic f -electron systems, the enhanced angular overlap model (EAOM), is presented. The method is established on the ground of perturbation expansion of the effective Hamiltonian for localized electrons and first-principles calculations related to available experimental data. The series of actinide compounds AO2 , oxychalcogenides AOX , and dichalcogenides UX2 where X=S ,Se,Te and A=U ,Np serve as probes of the effectiveness of the proposed method. An idea is to enhance the usual angular overlap model with ab initio calculations of those contributions to the crystal field potential, which cannot be represented by the usual angular overlap model (AOM). The enhancement leads to an improved fitting and makes the approach intrinsically coherent. In addition, the ab initio calculations of the main, AOM-consistent part of the crystal field potential allows one to fix the material-specific relations for the EAOM parameters in the effective Hamiltonian. Consequently, the electronic structure interpretation based on EAOM can be extended to systems of the lowest point symmetries or/and deficient experimental data. Several examples illustrating the promising capabilities of EAOM are given.

  14. Angular dependence of spin-orbit spin-transfer torques

    KAUST Repository

    Lee, Ki-Seung; Go, Dongwook; Manchon, Aurelien; Haney, Paul M.; Stiles, M. D.; Lee, Hyun-Woo; Lee, Kyung-Jin

    2015-01-01

    In ferromagnet/heavy-metal bilayers, an in-plane current gives rise to spin-orbit spin-transfer torque, which is usually decomposed into fieldlike and dampinglike torques. For two-dimensional free-electron and tight-binding models with Rashba spin-orbit coupling, the fieldlike torque acquires nontrivial dependence on the magnetization direction when the Rashba spin-orbit coupling becomes comparable to the exchange interaction. This nontrivial angular dependence of the fieldlike torque is related to the Fermi surface distortion, determined by the ratio of the Rashba spin-orbit coupling to the exchange interaction. On the other hand, the dampinglike torque acquires nontrivial angular dependence when the Rashba spin-orbit coupling is comparable to or stronger than the exchange interaction. It is related to the combined effects of the Fermi surface distortion and the Fermi sea contribution. The angular dependence is consistent with experimental observations and can be important to understand magnetization dynamics induced by spin-orbit spin-transfer torques.

  15. Angular momentum in non-relativistic QED and photon contribution to spin of hydrogen atom

    International Nuclear Information System (INIS)

    Chen Panying; Ji Xiangdong; Xu Yang; Zhang Yue

    2010-01-01

    We study angular momentum in non-relativistic quantum electrodynamics (NRQED). We construct the effective total angular momentum operator by applying Noether's theorem to the NRQED lagrangian. We calculate the NRQED matching for the individual components of the QED angular momentum up to one loop. We illustrate an application of our results by the first calculation of the angular momentum of the ground state hydrogen atom carried in radiative photons, α em 3 /18π, which might be measurable in future atomic experiments.

  16. Ligand Exchange Kinetics of Environmentally Relevant Metals

    Energy Technology Data Exchange (ETDEWEB)

    Panasci, Adele Frances [Univ. of California, Davis, CA (United States)

    2014-07-15

    The interactions of ground water with minerals and contaminants are of broad interest for geochemists but are not well understood. Experiments on the molecular scale can determine reaction parameters (i.e. rates of ligand exchange, activation entropy, activation entropy, and activation volume) that can be used in computations to gain insight into reactions that occur in natural groundwaters. Experiments to determine the rate of isotopic ligand exchange for three environmentally relevant metals, rhodium (Rh), iron (Fe), and neptunium (Np), are described. Many environmental transformations of metals (e.g. reduction) in soil occur at trivalent centers, Fe(III) in particular. Contaminant ions absorb to mineral surfaces via ligand exchange, and the reversal of this reaction can be dangerous, releasing contaminants into the environment. Ferric iron is difficult to study spectroscopically because most of its complexes are paramagnetic and are generally reactive toward ligand exchange; therefore, Rh(III), which is diamagnetic and less reactive, was used to study substitution reactions that are analogous to those that occur on mineral oxide surfaces. Studies on both Np(V) and Np(VI) are important in their own right, as 237Np is a radioactive transuranic element with a half-life of 2 million years.

  17. Ligand iron catalysts for selective hydrogenation

    Science.gov (United States)

    Casey, Charles P.; Guan, Hairong

    2010-11-16

    Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

  18. Programmed Death-Ligand 1 Immunohistochemistry Testing

    DEFF Research Database (Denmark)

    Büttner, Reinhard; Gosney, John R; Skov, Birgit Guldhammer

    2017-01-01

    Purpose Three programmed death-1/programmed death-ligand 1 (PD-L1) inhibitors are currently approved for treatment of non-small-cell lung cancer (NSCLC). Treatment with pembrolizumab in NSCLC requires PD-L1 immunohistochemistry (IHC) testing. Nivolumab and atezolizumab are approved without PD-L1...

  19. Versatile phosphite ligands based on silsesquioxane backbones

    NARCIS (Netherlands)

    van der Vlugt, JI; Ackerstaff, J; Dijkstra, TW; Mills, AM; Kooijman, H; Spek, AL; Meetsma, A; Abbenhuis, HCL; Vogt, D

    Silsesquioxanes are employed as ligand backbones for the synthesis of novel phosphite compounds with 3,3'-5,5'-tetrakis(tert-butyl)-2,2'-di-oxa-1,1'-biphenyl substituents. Both mono- and bidentate phosphites are prepared in good yields. Two types of silsesquioxanes are employed as starting

  20. Angular filter refractometry analysis using simulated annealing [An improved method for characterizing plasma density profiles using angular filter refractometry

    International Nuclear Information System (INIS)

    Angland, P.; Haberberger, D.; Ivancic, S. T.; Froula, D. H.

    2017-01-01

    Here, a new method of analysis for angular filter refractometry images was developed to characterize laser-produced, long-scale-length plasmas using an annealing algorithm to iterative converge upon a solution. Angular filter refractometry (AFR) is a novel technique used to characterize the density pro files of laser-produced, long-scale-length plasmas. A synthetic AFR image is constructed by a user-defined density profile described by eight parameters, and the algorithm systematically alters the parameters until the comparison is optimized. The optimization and statistical uncertainty calculation is based on a minimization of the χ2 test statistic. The algorithm was successfully applied to experimental data of plasma expanding from a flat, laser-irradiated target, resulting in average uncertainty in the density profile of 5-10% in the region of interest.

  1. The dependence of the period on the angular amplitude of a simple ...

    African Journals Online (AJOL)

    The timing of the oscillation was done as the bob passed through its rest position. The time for 50 oscillations was recorded for different lengths and angular amplitudes. It was observed that the period depends on length and angular amplitude of the pendulum. The variation of the period with the angular amplitude is not a ...

  2. Singularity in the Laboratory Frame Angular Distribution Derived in Two-Body Scattering Theory

    Science.gov (United States)

    Dick, Frank; Norbury, John W.

    2009-01-01

    The laboratory (lab) frame angular distribution derived in two-body scattering theory exhibits a singularity at the maximum lab scattering angle. The singularity appears in the kinematic factor that transforms the centre of momentum (cm) angular distribution to the lab angular distribution. We show that it is caused in the transformation by the…

  3. Ammonia formation by metal-ligand cooperative hydrogenolysis of a nitrido ligand

    Science.gov (United States)

    Askevold, Bjorn; Nieto, Jorge Torres; Tussupbayev, Samat; Diefenbach, Martin; Herdtweck, Eberhardt; Holthausen, Max C.; Schneider, Sven

    2011-07-01

    Bioinspired hydrogenation of N2 to ammonia at ambient conditions by stepwise nitrogen protonation/reduction with metal complexes in solution has experienced remarkable progress. In contrast, the highly desirable direct hydrogenation with H2 remains difficult. In analogy to the heterogeneously catalysed Haber-Bosch process, such a reaction is conceivable via metal-centred N2 splitting and unprecedented hydrogenolysis of the nitrido ligands to ammonia. We report the synthesis of a ruthenium(IV) nitrido complex. The high nucleophilicity of the nitrido ligand is demonstrated by unusual N-C coupling with π-acidic CO. Furthermore, the terminal nitrido ligand undergoes facile hydrogenolysis with H2 at ambient conditions to produce ammonia in high yield. Kinetic and quantum chemical examinations of this reaction suggest cooperative behaviour of a phosphorus-nitrogen-phosphorus pincer ligand in rate-determining heterolytic hydrogen splitting.

  4. Dynamic ligand-based pharmacophore modeling and virtual ...

    Indian Academy of Sciences (India)

    Five ligand-based pharmacophore models were generated from 40 different .... the Phase module of the Schrodinger program.35 Each model consisted of six types of ... ligand preparation included the OPLS_2005 force field and to retain the ...

  5. Substrate coated with receptor and labelled ligand for assays

    International Nuclear Information System (INIS)

    1980-01-01

    Improvements in the procedures for assaying ligands are described. The assay consists of a polystyrene tube on which receptors are present for both the ligand to be assayed and a radioactively labelled form of the ligand. The receptors on the bottom portion of the tube are also coated with labelled ligands, thus eliminating the necessity for separate addition of the labelled ligand and sample during an assay. Examples of ligands to which this method is applicable include polypeptides, nucleotides, nucleosides and proteins. Specific examples are given in which the ligand to be assayed is digoxin, the labelled form of the ligand is 3-0-succinyl digoxyigenin tyrosine ( 125 I) and the receptor is digoxin antibody. (U.K.)

  6. Role of ligand-ligand vs. core-core interactions in gold nanoclusters.

    Science.gov (United States)

    Milowska, Karolina Z; Stolarczyk, Jacek K

    2016-05-14

    The controlled assembly of ligand-coated gold nanoclusters (NCs) into larger structures paves the way for new applications ranging from electronics to nanomedicine. Here, we demonstrate through rigorous density functional theory (DFT) calculations employing novel functionals accounting for van der Waals forces that the ligand-ligand interactions determine whether stable assemblies can be formed. The study of NCs with different core sizes, symmetry forms, ligand lengths, mutual crystal orientations, and in the presence of a solvent suggests that core-to-core van der Waals interactions play a lesser role in the assembly. The dominant interactions originate from combination of steric effects, augmented by ligand bundling on NC facets, and related to them changes in electronic properties induced by neighbouring NCs. We also show that, in contrast to standard colloidal theory approach, DFT correctly reproduces the surprising experimental trends in the strength of the inter-particle interaction observed when varying the length of the ligands. The results underpin the importance of understanding NC interactions in designing gold NCs for a specific function.

  7. AutoSite: an automated approach for pseudo-ligands prediction—from ligand-binding sites identification to predicting key ligand atoms

    Science.gov (United States)

    Ravindranath, Pradeep Anand; Sanner, Michel F.

    2016-01-01

    Motivation: The identification of ligand-binding sites from a protein structure facilitates computational drug design and optimization, and protein function assignment. We introduce AutoSite: an efficient software tool for identifying ligand-binding sites and predicting pseudo ligand corresponding to each binding site identified. Binding sites are reported as clusters of 3D points called fills in which every point is labelled as hydrophobic or as hydrogen bond donor or acceptor. From these fills AutoSite derives feature points: a set of putative positions of hydrophobic-, and hydrogen-bond forming ligand atoms. Results: We show that AutoSite identifies ligand-binding sites with higher accuracy than other leading methods, and produces fills that better matches the ligand shape and properties, than the fills obtained with a software program with similar capabilities, AutoLigand. In addition, we demonstrate that for the Astex Diverse Set, the feature points identify 79% of hydrophobic ligand atoms, and 81% and 62% of the hydrogen acceptor and donor hydrogen ligand atoms interacting with the receptor, and predict 81.2% of water molecules mediating interactions between ligand and receptor. Finally, we illustrate potential uses of the predicted feature points in the context of lead optimization in drug discovery projects. Availability and Implementation: http://adfr.scripps.edu/AutoDockFR/autosite.html Contact: sanner@scripps.edu Supplementary information: Supplementary data are available at Bioinformatics online. PMID:27354702

  8. A response calculus for immobilized T cell receptor ligands

    DEFF Research Database (Denmark)

    Andersen, P S; Menné, C; Mariuzza, R A

    2001-01-01

    determine the level of T cell activation. When fitted to T cell responses against purified ligands immobilized on plastic surfaces, the 2D-affinity model adequately simulated changes in cellular activation as a result of varying ligand affinity and ligand density. These observations further demonstrated...

  9. Fullerenes as a new type of ligands for transition metals

    International Nuclear Information System (INIS)

    Sokolov, V.I.

    2007-01-01

    Fullerenes are considered as ligands in transition metal π-complexes. The following aspects are discussed: metals able to form π-complexes with fullerenes (Zr, V, Ta, Mo, W, Re, Ru, etc.); haptic numbers; homo- and hetero ligand complexes; ligand compatibility with fullerenes for different metals, including fullerenes with a disturbed structure of conjugation [ru

  10. New pinene-derived pyridines as bidentate chiral ligands

    Czech Academy of Sciences Publication Activity Database

    Malkov, A. V.; Stewart-Liddon, A.; Teplý, Filip; Kobr, L.; Muir, K. W.; Haigh, D.; Kočovský, P.

    2008-01-01

    Roč. 64, č. 18 (2008), s. 4011-4025 ISSN 0040-4020 Institutional research plan: CEZ:AV0Z40550506 Keywords : chiral ligands * transition metal catalysis * asymmetric catalysis * pyridine ligands * oxazoline ligands Subject RIV: CC - Organic Chemistry Impact factor: 2.897, year: 2008

  11. Speciation of aquatic Hg2+ in humic substances by time differential perturbed angular correlation

    International Nuclear Information System (INIS)

    Franke, K.; Kupsch, H.; Troger, W.; Butz, T.

    1997-01-01

    Humic substances are ubiquitous in waters and soils and act as complexing agents for different heavy metals, e.g. Cd, Hg. Toxicity, reactivity, fixation, and migration are therefore strongly influenced by the interactions between heavy metals and humic substances. Humic substances derive from postmortal materials such as rotten plants, have dark colours and usually a molecular weight between 500 and 10.000 Dalton. Complex formation studies with different heavy metal ions indicate at least two different kinds of metal sites. Usually, these studies are restricted to heavy metal concentrations 2 to 3 orders of magnitude higher that the natural heavy metal abundance (i.e. 10 -10 molar). This serious limitation can be overcome by the use of suitable radioisotope techniques capable of metal speciation at extreme sensitivity levels such as TDPAC (Time Differential Perturbed Angular Correlation of γ-Rays). Thus, we studied the interaction of heavy metals with humic substances by monitoring the nuclear quadrupole interaction (NQI)of the short-lived radioisotopes 111m Cd (τ l/2 = 49 min) and 199m Hg (τ 1/2 = 43 min) supplied by ISOLDE via γ-γ -TDPAC and compared the 111m Cd/ 199m Hg-NQIs in humic substances with the known NQI of model compounds (i.e. metal proteins, organometallic compounds). At lowest Hg(II) concentrations (10 -10 molar) only linear Hg(ll) coordinations with nitrogen and/or sulfur were observed, with increasing Hg(II) concentration additional distorted trigonal (at 2.5.10 -10 molar) and tetrahedral coordinations (at 2.5.10 -8 molar) with various ligands show up and start to become dominant at Hg(II) concentrations of 10 -7 molar and higher. Contrary to Hg(II), we observed unspecific binding for Cd(lI) in the 111m Cd-TDPAC experiments only, even in the 10 -10 molar concentration range

  12. Unidentified angular recurrent ulceration responsive to antiviral therapy

    Directory of Open Access Journals (Sweden)

    Rahmi Amtha

    2013-03-01

    Full Text Available Background: Recurrent ulcer on angular area is usually called stomatitis angularis. It is caused by many factors such as vertical dimension reduce, vitamin B12, and immune system deficiency, C. albicans and staphylococcus involvement. Clinically is characterized by painful fissure with erythematous base without fever. Purpose: to describe an unidentified angular ulcer proceeded by recurrent ulcers with no response of topical therapy. Case: An 18-years old male came to Oral Medicine clinic in RSCM who complained of angular recurrent ulcers since 3 years ago which developed on skin and bleed easily on mouth opening. Patient had fever before the onset of ulcers. Large, painful, irregular ulcers covered by red crustae on angular area bilaterally. Patient has been treated with various drugs without improvement and lead to mouth opening limitation. Intra oral shows herpetiformtype of ulcer and swollen of gingival. Case management: Provisional diagnosis was established as viral infection thus acyclovir 200 mg five times daily for two weeks and topical anti inflammation gel were administered. Blood test for IgG/IgM of HSV1 and HSV2 were non reactive, however ulceration showed a remarkable improvement. The ulcers healed completely after next 2 weeks with acyclovir. Conclusion: The angular ulceration on above patient failed to fulfill the criteria of stomatitis angularis or herpes labialis lesion. However it showed a good response to antiviral. Therefore, unidentified angular ulceration was appointed, as the lesion might be triggered by other type of human herpes virus or types of virus that response to acyclovir.Latar belakang: ulser rekuren pada sudut mulut biasanya disebut stomatitis angularis. Kelainan ini disebabkan oleh banyak faktor seperti berkurangnya dimensi vertikal, defisiensi vitamin B12 dan sistem kekebalan tubuh, infeksi C. albicans serta staphylococcus. Secara klinis kelainan ini ditandai dengan fisur sakit pada sudut mulut dengan dasar

  13. Locking of intrinsic angular momentum in collision complexes

    International Nuclear Information System (INIS)

    Berengolts, Alexander.

    1995-04-01

    A concept of locking of the intrinsic angular momentum of a fragment of a collision complex to a body-fixed axis is widely used in the description of heavy-particle dynamics. The aim of this work is to provide a semiclassical description of the locking phenomenon which occur in diatomic and three atomic collision complexes. The first part of this work is devoted to the semiclassical study of the locking of the electronic angular momentum that occurs in slow collisions of two atoms, one in the spherically symmetric state and the other in state with j= 1. Here we calculate explicitly the complete locking matrix for different types of interatomic interactions. The elements of this matrix directly enter into the semiclassical expression for the different cross sections of polarized atoms. Limitations to the notion of the the locking radius and slipping probability are discussed in connection with the steepness of the interaction. Numerical calculations confirm analytical result: the optimal criterion for determination of the locking radius is a condition for the accumulated phase difference between two molecular states. Analytical expressions are suggested for the locking angle and the slipping probability. Implication of the locking approximation for calculation of the quasiclassical scattering matrix is discussed. The second part considers the locking of the rotational angular momentum of a diatom in the decomposition of a triatomic complexes. We discuss here cases J = 1,2,3 and 4, but restrict ourselves to calculation of the so-called dynamic orientation of the diatomic fragment. The letter represents one of the characteristics of the locking matrix which in principle can be measured experimentally. The orientation is created as a result of the interplay between the adiabatic interaction in the atom- diatom exit channel and the rotationally non adiabatic coupling in the perturbed rotor region

  14. Developments for the 6He beta - nu angular correlation experiment

    Science.gov (United States)

    Zumwalt, David W.

    This thesis describes developments toward the measurement of the angular correlation between the beta and the antineutrino in the beta decay of 6He. This decay is a pure Gamow-Teller decay which is described in the Standard Model as a purely axial vector weak interaction. The angular correlation is characterized by the parameter abetanu = -1/3 in the Standard Model. Any deviation from this value would be evidence for tensor components in the weak interaction and would constitute new physics. A new method will be used to measure the parameter a betanu from 6He decays, featuring a magneto-optical trap that will measure the beta particle in coincidence with the recoiling 6Li daughter ion. This neutral atom trapping scheme provides cold, tightly confined atoms which will reduce systematic uncertainties related to the initial position of the decay. By knowing the initial position of the decay and measuring the time of flight of the recoiling 6Li daughter ion in coincidence with the beta, the angular correlation between the beta and the antineutrino can be deduced. We aim to measure a betanu first to the level of 1%, and eventually to the 0.1% level, which would represent an order of magnitude improvement in precision over past experiments. Towards this goal, we have designed, built, and successfully tested a liquid lithium target to provide >2×10. {10} 6He atoms/sto a low-background environment, which is the most intense source of 6He presently available. This allowed for an additional measurement of the 6He half-life (806.89 +/- 0.11stat +0.23-0.19syst ms) to be made with unprecedented precision, resolving discrepancies in past measurements. We have also tested our trapping and detection apparatus and have begun to record preliminary coincidence events.

  15. Angular momentum and torque described with the complex octonion

    International Nuclear Information System (INIS)

    Weng, Zi-Hua

    2014-01-01

    The paper aims to adopt the complex octonion to formulate the angular momentum, torque, and force etc in the electromagnetic and gravitational fields. Applying the octonionic representation enables one single definition of angular momentum (or torque, force) to combine some physics contents, which were considered to be independent of each other in the past. J. C. Maxwell used simultaneously two methods, the vector terminology and quaternion analysis, to depict the electromagnetic theory. It motivates the paper to introduce the quaternion space into the field theory, describing the physical feature of electromagnetic and gravitational fields. The spaces of electromagnetic field and of gravitational field can be chosen as the quaternion spaces, while the coordinate component of quaternion space is able to be the complex number. The quaternion space of electromagnetic field is independent of that of gravitational field. These two quaternion spaces may compose one octonion space. Contrarily, one octonion space can be separated into two subspaces, the quaternion space and S-quaternion space. In the quaternion space, it is able to infer the field potential, field strength, field source, angular momentum, torque, and force etc in the gravitational field. In the S-quaternion space, it is capable of deducing the field potential, field strength, field source, current continuity equation, and electric (or magnetic) dipolar moment etc in the electromagnetic field. The results reveal that the quaternion space is appropriate to describe the gravitational features, including the torque, force, and mass continuity equation etc. The S-quaternion space is proper to depict the electromagnetic features, including the dipolar moment and current continuity equation etc. In case the field strength is weak enough, the force and the continuity equation etc can be respectively reduced to that in the classical field theory

  16. Combined calculi for photon orbital and spin angular momenta

    Science.gov (United States)

    Elias, N. M.

    2014-08-01

    Context. Wavelength, photon spin angular momentum (PSAM), and photon orbital angular momentum (POAM), completely describe the state of a photon or an electric field (an ensemble of photons). Wavelength relates directly to energy and linear momentum, the corresponding kinetic quantities. PSAM and POAM, themselves kinetic quantities, are colloquially known as polarization and optical vortices, respectively. Astrophysical sources emit photons that carry this information. Aims: PSAM characteristics of an electric field (intensity) are compactly described by the Jones (Stokes/Mueller) calculus. Similarly, I created calculi to represent POAM characteristics of electric fields and intensities in an astrophysical context. Adding wavelength dependence to all of these calculi is trivial. The next logical steps are to 1) form photon total angular momentum (PTAM = POAM + PSAM) calculi; 2) prove their validity using operators and expectation values; and 3) show that instrumental PSAM can affect measured POAM values for certain types of electric fields. Methods: I derive the PTAM calculi of electric fields and intensities by combining the POAM and PSAM calculi. I show how these quantities propagate from celestial sphere to image plane. I also form the PTAM operator (the sum of the POAM and PSAM operators), with and without instrumental PSAM, and calculate the corresponding expectation values. Results: Apart from the vector, matrix, dot product, and direct product symbols, the PTAM and POAM calculi appear superficially identical. I provide tables with all possible forms of PTAM calculi. I prove that PTAM expectation values are correct for instruments with and without instrumental PSAM. I also show that POAM measurements of "unfactored" PTAM electric fields passing through non-zero instrumental circular PSAM can be biased. Conclusions: The combined PTAM calculi provide insight into mathematically modeling PTAM sources and calibrating POAM- and PSAM-induced measurement errors.

  17. Spin O decay angular distribution for interfering mesons in electroproduction

    Energy Technology Data Exchange (ETDEWEB)

    Funsten, H.; Gilfoyle, G.

    1994-04-01

    Self analyzing meson electroproduction experiments are currently being planned for the CEBAF CLAS detector. These experiments deduce the spin polarization of outgoing unstable spin s (?)0 mesons from their decay angular distribution, W({theta},{psi}). The large angular acceptance of the CLAS detector permits kinematic tracking of a sufficient number of these events to accurately determine electroproduction amplitudes from the deduced polarization. Maximum polarization information is obtained from W({theta},{psi}) for decay into spin 0 daughters. The helicity of the decaying meson is transferred to the daughter`s relative orbital angular momentum m-projection; none is {open_quotes}absorbed{close_quotes} into daughter helicities. The decaying meson`s helicity maximally appears in W({theta},{psi}). W({theta},{psi}) for spin 0 daughters has been derived for (1) vector meson electroproduction and (2) general interfering mesons produced by incident pions. This paper derives W({theta},{psi}) for electroproduction of two interfering mesons that decay into spin 0 daughters. An application is made to the case of interfering scalar and vector mesons. The derivation is an extension of work by Schil using the general decay formalism of Martin. The expressions can be easily extended to the case of N interfering mesons since interference occurs pairwise in the observable W ({theta},{psi}), a quadratic function of the meson amplitudes. The derivation uses the virtual photon density matrix of Schil which is transformed by a meson electroproduction transition operator, T. The resulting density matrix for the interfering mesons is then converted into a corresponding statistical tensor and contracted into the efficiency tensor for spin 0 daughters.

  18. Twisted molecular excitons as mediators for changing the angular momentum of light

    Science.gov (United States)

    Zang, Xiaoning; Lusk, Mark T.

    2017-07-01

    Molecules with CN or CN h symmetry can absorb quanta of optical angular momentum to generate twisted excitons with well-defined quasiangular momenta of their own. Angular momentum is conserved in such interactions at the level of a paraxial approximation for the light beam. A sequence of absorption events can thus be used to create a range of excitonic angular momenta. Subsequent decay can produce radiation with a single angular momentum equal to that accumulated. Such molecules can thus be viewed as mediators for changing the angular momentum of light. This sidesteps the need to exploit nonlinear light-matter interactions based on higher-order susceptibilities. A tight-binding paradigm is used to verify angular momentum conservation and demonstrate how it can be exploited to change the angular momentum of light. The approach is then extended to a time-dependent density functional theory setting where the key results are shown to hold in a many-body, multilevel setting.

  19. Angular momentum dependence of the nuclear level density parameter

    International Nuclear Information System (INIS)

    Aggarwal, Mamta; Kailas, S.

    2010-01-01

    Dependence of nuclear level density parameter on the angular momentum and temperature is investigated in a theoretical framework using the statistical theory of hot rotating nuclei. The structural effects are incorporated by including shell correction, shape, and deformation. The nuclei around Z≅50 with an excitation energy range of 30 to 40 MeV are considered. The calculations are in good agreement with the experimentally deduced inverse level density parameter values especially for 109 In, 113 Sb, 122 Te, 123 I, and 127 Cs nuclei.

  20. Mechanical Properties of Copper Processed by Equal Channel Angular Pressing

    Science.gov (United States)

    Sülleiová, K.; Ballóková, B.; Besterci, M.; Kvačkaj, T.

    2017-12-01

    The development of the nanostructure in commercial pure copper and the strength and ductility after severe plastic deformation (SPD) with the technology of equal channel angular pressing (ECAP) are analysed. Experimental results and analyses showed that both strength and ductility can be increased simultaneously by SPD. The final grain size decreased from the initial 50μm by SPD to 100-300 nm after 10 passes. An increase of the ductility together with an increase of strength caused by SPD are explained by a strong grain refinement and by a dynamic equilibrium of weakening and strengthening, and it is visible on the final static tensile test stress-strain charts.