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Sample records for angular bipyridyl ligands

  1. Supramolecular architectures constructed using angular bipyridyl ligands

    CERN Document Server

    Barnett, S A

    2003-01-01

    This work details the synthesis and characterization of a series of coordination frameworks that are formed using bidentate angular N-donor ligands. Pyrimidine was reacted with metal(ll) nitrate salts. Reactions using Cd(NO sub 3) sub 2 receive particular focus and the analogous reactions using the linear ligand, pyrazine, were studied for comparison. In all cases, two-dimensional coordination networks were prepared. Structural diversity is observed for the Cd(ll) centres including metal-nitrate bridging. In contrast, first row transition metal nitrates form isostructural one-dimensional chains with only the bridging N-donor ligands generating polymeric propagation. The angular ligand, 2,4-bis(4-pyridyl)-1,3,5-triazine (dpt), was reacted with Cd(NO sub 3) sub 2 and Zn(NO sub 3) sub 2. Whereas Zn(NO sub 3) sub 2 compounds exhibit solvent mediated polymorphism, a range of structures were obtained for the reactions with Cd(NO sub 3) sub 2 , including the first example of a doubly parallel interpenetrated 4.8 sup...

  2. Supramolecular architectures constructed using angular bipyridyl ligands

    International Nuclear Information System (INIS)

    This work details the synthesis and characterization of a series of coordination frameworks that are formed using bidentate angular N-donor ligands. Pyrimidine was reacted with metal(ll) nitrate salts. Reactions using Cd(NO3)2 receive particular focus and the analogous reactions using the linear ligand, pyrazine, were studied for comparison. In all cases, two-dimensional coordination networks were prepared. Structural diversity is observed for the Cd(ll) centres including metal-nitrate bridging. In contrast, first row transition metal nitrates form isostructural one-dimensional chains with only the bridging N-donor ligands generating polymeric propagation. The angular ligand, 2,4-bis(4-pyridyl)-1,3,5-triazine (dpt), was reacted with Cd(NO3)2 and Zn(NO3)2. Whereas Zn(NO3)2 compounds exhibit solvent mediated polymorphism, a range of structures were obtained for the reactions with Cd(NO3)2, including the first example of a doubly parallel interpenetrated 4.82 net. 4,7-phenanthroline, was reacted with various metal(ll) nitrates as well as cobalt(ll) and copper(ll) halides. The ability of 4,7-phenanthroline to act as both a N-donor ligand and a hydrogen bond acceptor has been discussed. Reactions of CuSCN with pyrimidine yield an unusual three-dimensional structure in which polymeric propagation is not a result of ligand bridging. The reaction of CuSCN with dpt yielded structural supramolecular isomers. (author)

  3. Crystal structures of titanocene 2,2 '-bipyridyl complexes. Singlet versus triplet state dependence on methyl substituents at the cyclopentadienyl ligands

    NARCIS (Netherlands)

    Gyepes, R; Witte, PT; Horacek, M; Cisarova, [No Value; Mach, K

    1998-01-01

    The X-ray diffraction analysis of titanocene-2,2'-bipyridyl complexes (C5H5)(2)Ti(bpy) (1), (C5HMe4)(2)Ti(bpy) (2) and (C5Me5)(2)Ti(bpy) (3) revealed that the bpy ligand is inclined to one of the cyclopentadienyl ligands in 1 and 2 whereas in 3 it lies in the plane bisecting the CE-Ti-CE angle of th

  4. Ruthenium Bis-diimine Complexes with a Chelating Thioether Ligand: Delineating 1,10-Phenanthrolinyl and 2,2'-Bipyridyl Ligand Substituent Effects

    Energy Technology Data Exchange (ETDEWEB)

    Al-Rawashdeh, Nathir A. F.; Chatterjee, Sayandev; Krause, Jeanette A.; Connick, William B.

    2014-01-06

    A new series of ruthenium(II) bis-diimine complexes with a chelating thioether donor ligand has been prepared: Ru(diimine)2(dpte)2+ (diimine=1,10-phenanthroline (phen) (1); 5-CH3-phen (2), 5-Cl-phen (3); 5-Br-phen (4); 5-NO2-phen (5); 3,4,7,8-tetramethyl-phen (6); 4,7-diphenyl-phen (7); 5,5'-dimethyl-2,2'-bipyridine (8); 4,4'-di-tert-butyl-2,2'-bipyridine (9)). Crystal structures of 2, 5, 7 and 9 show that the complexes form 2 of the 12 possible conformational/configurational isomers, adopting compact C2-symmetric structures with short intramolecular transannular interactions between the diimine ligands and dpte phenyl groups; crystals of 2 and 5 contain non-statistical distributions of geometric isomers. In keeping with the π-acidity of the dpte, the Ru(III/II) couple, E°'(Ru3+/2+), occurs at relatively high potentials (1.4-1.7 V vs Ag/AgCl), and the lowest spin-allowed MLCT absorption band occurs near 400 nm. Surprisingly, the complexes also exhibit fluid-solution luminescence originating from a lowest MLCT excited state with lifetimes in the 140-750 ns time range; in acetonitrile, compound 8 undergoes photo-induced solvolysis. Variations in the MLCT energies and redox potentials are quantitatively described using a summative Hammett parameter (σT), as well as using Lever's electrochemical parameters (EL). Recommended parameterizations for 2,2'-bipyridyl and 1,10-phenanthrolinyl ligands were derived from analysis of correlations based on 199 measurements of E°'(Ru3+/2+) for 99 homo- and heteroleptic ruthenium(II) tris-diimine complexes. Variations in E°'(Ru3+/2+) due to substituents at the 4- and 4'-positions of bipyridyl ligands and 4- and 7-positions of phenanthrolinyl ligands are significantly more strongly correlated with σp+ than either σm or σp. Substituents at the 5- and 6-positions of phenanthrolinyl ligands are best described by σm and have effects comparable to those of substituents at the 3

  5. Synthesis and Crystal Structure of a Co(II) Coordination Polymer Derived from a Flexible Bipyridyl Derivative Ligand

    Institute of Scientific and Technical Information of China (English)

    GONG Ya-Qiong; WANG Rui-Hu; WU Ben-Lai; LOU Ben-Yong; HAN Lei; HONG Mao-Chun

    2005-01-01

    The self-assembly of a flexible bipyridyl ligand 2,2'-bis(4-pyridylmethyle- neoxy)-1,1'-biphenylene (4,4'-bpp) with cobalt(II) center gave rise to a one-dimensional chain complex [Co(μ-4,4'-bpp)2(SCN)2(H2O]n 1 which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in monoclinic, space group C2/c with unit cell parameters: a = 13.1888(13), b = 24.230(2), c = 15.4218(17) (A), β = 93.291(6)°, V = 4920.1(8) (A)3, Z = 4, C50H42CoN6O5S2, Mr = 929.95, Dc = 1.255 g/cm3, F(000) = 1932 and μ(MoKα) = 0.484 mm-1. The final R and wR are 0.0691 and 0.1670 for 3746 observed reflections with I > 2σ(I). 1 possesses an infinite 1-D polymeric chain structure consisting of the repeated basic square units Co2(μ-4,4'-bpp)2, where the Co(II) center acts as the joint of the square ring. The Co(II) center is coordinated in a slightly distorted octahedral geometry with four nitrogen atoms from four different 4,4'-bpp ligands in the equatorial plane and two trans thiocyanate ligands occupying the axial positions, preventing the formation of an extended framework.

  6. Synthesis and properties of new mononuclear Ru(ii)-based photocatalysts containing 4,4'-diphenyl-2,2'-bipyridyl ligands.

    Science.gov (United States)

    Coe, Benjamin J; Sánchez, Sergio

    2016-03-15

    The synthesis and characterisation of a series of eleven new 4,4'-diphenyl-2,2'-bipyridyl derivatives (N^N) with varying 4- or 3,5-substituents on the phenyl rings are reported. The molecular structures of two of these compounds, 4,4'-bis(3,5-diheptyloxyphenyl)-2,2'-bipyridyl and 4,4'-bis(3,5-di-4,4,5,5,5-pentafluoropentyloxyphenyl)-2,2'-bipyridyl are confirmed by X-ray crystallography. Fourteen neutral complexes trans-Ru(II)Cl2(N^N)(CO)2 are prepared by reacting the new proligands and three known ones with the polymeric precursor [Ru(II)Cl2(CO)2]n, and their optical and electrochemical properties are studied. Density functional theory (DFT) and time-dependent DFT calculations have been carried out on selected complexes in order to rationalise their electronic structures and absorption properties. The low energy electronic absorption bands have metal-to-ligand charge-transfer and ligand-to-ligand charge-transfer (LLCT) character, but these dominate only in the 4-substituted species. In the 3,5-disubstituted ones, intraligand charge-transfer (ILCT) within the bpy ligands becomes more important. The complexes show only irreversible reductive electrochemistry and no signs of polymerisation. The photocatalytic oxidation behaviour of selected trans-Ru(II)Cl2(N^N)(CO)2 complexes and their mono-aquo derivatives [Ru(II)(H2O)(CO)2Cl(N^N)](+) with 4-methoxybenzyl alcohol is studied. Turnover numbers of up to ca. 130 are achieved when using [Ru(II)(bpy)3](2+) (bpy = 2,2'-bipyridyl) as photosensitizer and [Co(III)(NH3)5Cl](2+) as a sacrificial oxidant. PMID:26890960

  7. The chemistry of polypyridine complexes of ruthenium. Communication 5. Electronic structure of mixed-ligand bipyridyl-diphosphine complexes of ruthenium(2)

    International Nuclear Information System (INIS)

    Comparative analysis of donor-acceptor abilities of diphosphine ligands for two series of complex compounds: cis-[Ru(bpy)2(LL)q+ [LL=2,2'-bipyridyl(bpy), o-benzoquinonediimine (bqdi), cis-1,2-bis(diphenylphosphino)ethane, cis-1,2-bis(diphenylphosphino)ethylene (dppen), (NH3)2 and (CO)2] and [Ru(NH3)4(LL)]2+ (LL = bpy, dppen and bqdi) was carried out on the basis of results of quantum chemical calculations. It is shown that diphosphines are the strongest σ-donors; their π-acceptor abilities stemming from d-orbitals of phosphorus are comparable in value with π-acceptor abilities of 2,2'-bipyridyl, being essentially lower than those of o-benzoquinonediimine and carbonyl

  8. Spectroscopy and quantum-chemical calculations of nitro-bis-bipyridyl complexes of ruthenium(II) with 4-substituted pyridine ligands

    Science.gov (United States)

    Reshetova, K. I.; Krauklis, I. V.; Litke, S. V.; Ershov, A. Yu.; Chizhov, Yu. V.

    2016-04-01

    The luminescence, absorption, and luminescence excitation spectra of complexes cis-[Ru(bpy)2(L)(NO2)]+ [bpy = 2,2'-bipyridyl, L = pyridine, 4-aminopyridine, 4-dimethylaminopyridine, 4-picoline, isonicotinamide, or 4,4'-bipyridyl] in alcoholic (4 : 1 EtOH-MeOH) solutions are studied at 77 K. A linear correlation is established between the energy of the lowest electronically excited metal-toligand charge transfer state d π(Ru) → π*(bpy) of the complexes and the pKa parameter of the free 4-substituted pyridines used as ligands L. The B3LYP/[6-31G(d)+LanL2DZ(Ru)] hybrid density functional method is used to optimize the geometry of complexes and calculate their electronic structure and the charge distribution on the atoms of the nearest environment of ruthenium(II) ions. It is shown that there exists a mutually unambiguous correspondence between the charge on the nitrogen atom of ligands L coordinated in the complex and the pK a parameter of ligands. The calculated energies of the electronically excited metal-to-ligand charge transfer states of complexes linearly (correlation coefficient 0.99) depend on the charge on the nitrogen atom of ligands L, which completely agrees with the experimental data.

  9. Mixed-ligand binuclear copper(II) complex of 5-methylsalicylaldehyde and 2,2'-bipyridyl: Synthesis, crystal structure, DNA binding and nuclease activity

    Indian Academy of Sciences (India)

    Perumal Gurumoorthy; Jayaram Ravichandran; Aziz Kalilur Rahiman

    2014-05-01

    A new mixed-ligand binuclear copper(II) complex [Cu(MS)(bpy)]2.(ClO4)2, built of 5-methylsalicylaldehyde and 2,2'-bipyridyl has been synthesized and characterized by using elemental analysis, IR and UV-Vis spectroscopy. Crystal structure of the complex shows that copper(II) ion lies in a square pyramidal coordination environment. The structure consists of two symmetrical half units in which the copper(II) ion of one half unit connected with the phenolate oxygen atom of other half unit along with one perchlorate anion in the crystal lattice as free molecule. Presence of uncoordinated perchlorate anion was also confirmed by IR spectroscopy. Absorption spectroscopy exhibits d-d transition at 628 nm, which further supports the square pyramidal geometry around the copper(II) ions. EPR spectrum of the copper(II) complex at room temperature shows a broad signal without any splitting pattern at ∥ = 2.26, ⊥ = 2.03 and the magnetic moment (eff = 1.31 BM) obtained at room temperature indicate an antiferromagnetic interaction between the two copper(II) ions through phenoxide-bridge. Binding studies reveal that the complex possesses good binding propensity (b = 5.2 ± 1.7 × 104 M-1) and bind to nitrogenous bases of DNA through intercalation. Nuclease activity of the complex with pBR322 DNA shows that the effect of hydrolytic cleavage is dose-dependent and the oxidative cleavage indicates the involvement of hydroxyl radical and singlet-oxygen as reactive oxygen species.

  10. Volatile different-ligand complexes of bis(diisobutyldithiocarbamato)cadmium with 1,10-phenanthroline, 2,2'-bipyridyl, and 4,4'-bipyridyl.Crystal and molecular structures of Cd((S2CN(i-C4H9)2)2(C12HgN2) complexes

    International Nuclear Information System (INIS)

    Volatile different-ligand complexes of diisobutyldithiocarbamate of cadmium Cd((S2CN(i-C4H9)2)2 with 1.10-phenanthroline (Phen), 2,2'-bipyridyl of the CdL2B (L=(i-C4H9)2 NCS2; B=Phen, 2.2'-Bipy and 4.4'-bipyridyl (4.4'-Bipy of the Cd2L4(4.4'Bipy) composition are synthesized. It is found through the RSA method that the Cd((S2CN(i-C4H9)2)2 complex has a monometric structure with distorted-octahedral coordination bond CdS4N2, formed by bidentate-cyclic ligands L and Phen. The complexes are quantitatively sublimated by the heating in vacuum (t=50-300 deg C p ∼ 10-3 mm mercury column) and form α-CdS by thermal decomposition in the air

  11. Kinetics and mechanism of the ligand substitution reaction of di--hydroxobis(bipyridyl)dipalladium(II) ion with diethyldithiocarbamate anion in aqueous solution

    Indian Academy of Sciences (India)

    Subhasis Mallick; Biplab K Bera; Subala Mondal; Parnajyoti Karmakar; Arup Mandal; Alak K Ghosh

    2011-05-01

    The kinetics of the interaction between diethyldithiocarbamate (Et2DTC) and the title complex has been studied spectrophotometrically in aqueous medium as a function of nucleophile concentration, temperature and pH at constant ionic strength. The reaction is a two-step process in which the first step is liganddependent, but the second step is ligand-independent and is assigned to ring closure. The rate and activation parameters, conductivity studies and IR data were used to deduce a plausible mechanism.

  12. Structures of nitrato-(2-hydroxybenzaldehydo) (2,2′-bipyridyl)copper and nitrato-(2-hydroxy-5-nitrobenzaldehydo)(2,2′-bipyridyl)copper

    International Nuclear Information System (INIS)

    Nitrato-(2-hydroxy-5-nitrobenzaldehydo)(2,2′-bipyridyl)copper (I) and nitrato-(2-hydroxybenzaldehydo)(2,2′-bipyridyl)copper (II) were synthesized and characterized by X-ray diffraction. The coordination polyhedron of the central copper atom in complex I can be described as a distorted tetragonal pyramid whose base is formed by the phenol and carbonyl oxygen atoms of the monodeprotonated 2-hydroxy-5nitrobenzaldehyde molecule and the nitrogen atoms of the 2,2′-bipyridyl ligand and whose apex is occupied by the oxygen atom of the nitrato group. In the crystal structure, complexes I are linked by the acido ligands and the NO2 groups of the aldehyde molecule into infinite chains. In complex II, the central copper atom is coordinated by 2-hydroxybenzaldehyde, 2,2′-bipyridyl, and the nitrato group, resulting in the formation of centrosymmetric dimers. The coordination polyhedron of the central copper atom can be described as a bipyramid (4 + 1 + 1) with the same base as in complex I. The axial vertices of the bipyramid are occupied by the oxygen atom of the nitrato group and the bridging phenol oxygen atom of the adjacent complex related to the initial complex by a center of symmetry. In the crystal structure, complexes II are hydrogen bonded into infinite chains.

  13. Synthesis of Two Novel Rhenium(I) Bipyridyl Photosensitive Dyes

    Institute of Scientific and Technical Information of China (English)

    Shi Guo SUN; Xiao Jun PENG; Ming Wen FAN; Yong Qian XU; Lei SHI; Li Cheng SUN

    2004-01-01

    Two novel rhenium(I) 2, 2'-bipyridyl complexes, [(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4'-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4'-di- COOEt- bipy) Re (CO)3 (pyridine)PF6], were synthesized.Their ground state electronic spectra and emission spectra were measured in acetonitrile.The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.

  14. Electrochemistry of complex combinations with organic ligands

    International Nuclear Information System (INIS)

    The electrochemical behaviour of Cd(2), Ni(2), Fe(2), Fe(3), In(3), Pb(2) complexes with organic bi-and polydentate ligands have been studied by methods of classical and alternating current polarography. Cadmium and indium complexing depending on pH value and the nature of the ligands (bipyridyl isomers, phosphoric acid esters) is discussed

  15. A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II Complex: Synthesis, Photophysical and Electrochemical Properties

    Directory of Open Access Journals (Sweden)

    Peter A. Ajibade

    2011-06-01

    Full Text Available In our quest to develop good materials as photosensitizers for photovoltaic dye-sensitized solar cells (DSSCs, cis-dithiocyanato-4-(2,3-dimethylacrylic acid-2,2'-bipyridyl-4-(9-anthracenyl-(2,3-dimethylacrylic-2,2'-bipyridyl ruthenium(II complex, a high molar extinction coefficient charge transfer sensitizer, was designed, synthesized and characterized by spectroscopy and electrochemical techniques. Earlier studies on heteroleptic ruthenium(II complex analogues containing functionalized oligo-anthracenyl phenanthroline ligands have been reported and documented. Based on a general linear correlation between increase in the length of π-conjugation bond and the molar extinction coefficients, herein, we report the photophysical and electrochemical properties of a Ru(II bipyridyl complex analogue with a single functionalized anthracenyl unit. Interestingly, the complex shows better broad and intense metal-to ligand charge transfer (MLCT band absorption with higher molar extinction coefficient (λmax = 518 nm, e = 44900 M−1cm−1, and appreciable photoluminescence spanning the visible region than those containing higher anthracenyl units. It was shown that molar absorption coefficient of the complexes may not be solely depended on the extended π-conjugation but are reduced by molecular aggregation in the molecules.

  16. Tris(2,2′-bipyridyl-κ2N,N′copper(II sulfate 7.5-hydrate

    Directory of Open Access Journals (Sweden)

    Wei Huang

    2009-02-01

    Full Text Available The title compound, [Cu(C10H8N23]SO4·7.5H2O, is a six-coordinate copper(II complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5, 5.2 (4 and 5.8 (5°. In the crystal, several O—H...O and C—H...O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions.

  17. Synthesis and structural characterization of copper(II) complex of 2,2'-bipyridyl and L-lysine

    Science.gov (United States)

    Thebo, K. H.; Shad, H. A.; Thebo, A. A.; Raftery, J.

    2014-12-01

    The mixed ligand copper(II) complex of 2,2'-bipyridyl and L-lysine was synthesized from 2,2'-bipyrdine, lysine monohydrochloride and copper perchlorate. The resultant complex was characterized by elemental analysis, X-ray crystallography, IR and thermogravimetric analysis. X-ray studies showed that the title complex is a dimer. The geometry around copper atom is distorted square planar in which the Cu atom is bonded with N and O atoms from L-lysine and N, N atoms of 2,2'-bipyridyl ligand. The crystal structure is orthorhombic with unit cell parameters a = 10.5330(9) Å, b = 13.2169(12) Å, c = 32.618(3) Å; V = 4540.9(7) Å, D x = 8, 1.705 Mg/m3, Mr = 582.83. IR spectral band has been studied and are agreed well with those obtained from the values of the expected CHN analyses and X-ray diffraction. Thermal decomposition of the complex has also been studied under an inert atmosphere.

  18. Application of the perturbed angular correlation in the investigation of hyperfine interactions in compounds of hafnium, indium and cadmium with F1-, OH1- and EDTA ligands

    International Nuclear Information System (INIS)

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using 111In → 111Cd, 181Hf → 181Ta and 111mCd →111Cd, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH 4.3 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  19. Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: Crystal structure, photoluminescence and photocatalytic activity

    International Nuclear Information System (INIS)

    Four ternary coordination polymers (CPs) namely, ([Ni(SDB)(BITMB)(H2O)]·H2O)n (CP1), ([Cd(SDB)(BITMB) (H2O)]·(THF)(H2O))n (CP2), ([Zn2(SDB)2(BITMB)]·(THF)2)n (CP3) and ([Co2(SDB)2(BITMB)]·(Dioxane)3)n (CP4) composed of angular dicarboxylate SDB (4,4'-sulfonyldibenzoate) and N-donor BITMB (1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethyl benzene) have been synthesized by solvothermal reactions and characterized by single crystal X-ray diffraction and other physico-chemical techniques. CP1 possesses one-dimensional ribbon type metal–organic motifs glued together by H-bonds and π⋯π interactions, whereas CP2–CP4, exhibit non-interpenetrated sql networks supported by weak supramolecular interactions. Structural diversity of these CPs can be attributed to the coordination geometry adopted by the metal nodes, versatile coordination modes of SDB and conformational flexibility of BITMB. Solid state luminescence properties of CP1–CP4 were explored. Photocatalytic performance of all CPs for the decomposition of metanil yellow by dilute hydrogen peroxide in the presence of visible light was also investigated. 25–83% dye removal from aqueous solutions in the presence of CP1–CP4 was observed. - Graphical abstract: Four new ternary transition metal CPs have been hydrothermally prepared and their structural aspects as well as photocatalytic activity for decolourization of metanil yellow (MY) dye have been investigated. - Highlights: • Four ternary coordination polymers containing Ni, Cd, Zn and Co center are prepared. • Crystal structure and thermal stability of all four CPs has been described. • PL and diffuse reflectance spectra of synthesized CPs have also been examined. • Band gap values suggest semiconducting behavior of prepared CPs. • Photocatalytic activity of CPs for oxidative degradation of metanil yellow is studied

  20. Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: Crystal structure, photoluminescence and photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Bisht, Kamal Kumar; Rachuri, Yadagiri [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Academy of Scientific and Innovative Research (AcSIR), CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Parmar, Bhavesh [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Suresh, Eringathodi, E-mail: esuresh@csmcri.org [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Academy of Scientific and Innovative Research (AcSIR), CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India)

    2014-05-01

    Four ternary coordination polymers (CPs) namely, ([Ni(SDB)(BITMB)(H{sub 2}O)]·H{sub 2}O){sub n} (CP1), ([Cd(SDB)(BITMB) (H{sub 2}O)]·(THF)(H{sub 2}O)){sub n} (CP2), ([Zn{sub 2}(SDB){sub 2}(BITMB)]·(THF){sub 2}){sub n} (CP3) and ([Co{sub 2}(SDB){sub 2}(BITMB)]·(Dioxane){sub 3}){sub n} (CP4) composed of angular dicarboxylate SDB (4,4'-sulfonyldibenzoate) and N-donor BITMB (1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethyl benzene) have been synthesized by solvothermal reactions and characterized by single crystal X-ray diffraction and other physico-chemical techniques. CP1 possesses one-dimensional ribbon type metal–organic motifs glued together by H-bonds and π⋯π interactions, whereas CP2–CP4, exhibit non-interpenetrated sql networks supported by weak supramolecular interactions. Structural diversity of these CPs can be attributed to the coordination geometry adopted by the metal nodes, versatile coordination modes of SDB and conformational flexibility of BITMB. Solid state luminescence properties of CP1–CP4 were explored. Photocatalytic performance of all CPs for the decomposition of metanil yellow by dilute hydrogen peroxide in the presence of visible light was also investigated. 25–83% dye removal from aqueous solutions in the presence of CP1–CP4 was observed. - Graphical abstract: Four new ternary transition metal CPs have been hydrothermally prepared and their structural aspects as well as photocatalytic activity for decolourization of metanil yellow (MY) dye have been investigated. - Highlights: • Four ternary coordination polymers containing Ni, Cd, Zn and Co center are prepared. • Crystal structure and thermal stability of all four CPs has been described. • PL and diffuse reflectance spectra of synthesized CPs have also been examined. • Band gap values suggest semiconducting behavior of prepared CPs. • Photocatalytic activity of CPs for oxidative degradation of metanil yellow is studied.

  1. Visualization of Metal-to-Ligand and Ligand-to-Ligand Charge Transfer in Metal-Ligand Complexes

    Institute of Scientific and Technical Information of China (English)

    Yong Ding; Jian-xiu Guo; Xiang-si Wang; Sha-sha Liu; Feng-cai Ma

    2009-01-01

    Three methods including the atomic resolved density of state, charge difference density, and the transition density matrix are used to visualize metal to ligand charge transfer (MLCT) in ruthenium(Ⅱ) ammine complex. The atomic resolved density of state shows that there is density of Ru on the HOMOs. All the density is localized on the ammine, which reveals that the excited electrons in the Ru complex are delocalized over the ammine ligand. The charge difference density shows that all the holes are localized on the Ru and the electrons on the ammine. The localization explains the MLCT on excitation. The transition density matrix shows that there is electron-hole coherence between Ru and ammine. These methods are also used to examine the MLCT in Os(bpy)(p0p)Cl ("Osp0p"; bpy=2,2'-bipyridyl; p0p=4,4'-bipyridyl) and the ligand-to-ligand charge transfer (LLCT) in Alq3. The calculated results show that these methods are powerful to examine MLCT and LLCT in the metal-ligand system.

  2. Conformational and Optical Characteristics of Unidirectionally Twisted Binaphthyl-Bipyridyl Cyclic Dyads.

    Science.gov (United States)

    Takaishi, Kazuto; Suzuki, Jun; Yabe, Tatsuya; Asano, Hikaru; Nishikawa, Michihiro; Hashizume, Daisuke; Muranaka, Atsuya; Uchiyama, Masanobu; Yokoyama, Akihiro

    2015-08-21

    An axially chiral binaphthyl-bipyridyl cyclic dyad in which the two units are connected by short -CH2O- linkers was synthesized. Experimental and theoretical analyses indicate that the (R)-binaphthyl unit in the dyad induces (R)-chirality in the bipyridyl unit, both in the solid state and in solution. It is shown that vibrational circular dichroism (VCD) is useful to determine the twisting pattern of 2,2'-bipyridyl compounds. The dyad shows crystallization-induced emission enhancement (CIEE). PMID:26263248

  3. Tris(2,2'-bipyridyl) Ruthenium(Ⅱ) Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties

    Institute of Scientific and Technical Information of China (English)

    WEI Hui; DU Yan; KANG Jian-Zhen; XU Guo-Bao; WANG Er-Kang

    2007-01-01

    An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis(bipyridyl)-4,4'-dicarboxy-2,2'-bipyridyl-ruthenium to (3-aminopropyl)-triethoxysilane.The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol-gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.

  4. catena-Poly[[[tetrakis(cyanido-κCtungstate(IV]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′manganese(II]-di-μ-cyanido-κ4N:C] hexahydrate

    Directory of Open Access Journals (Sweden)

    Noriaki Ozaki

    2011-06-01

    Full Text Available The polymeric title compound, {[MnII2WIV(CN8(C10H8N22(H2O4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinate distorted octahedral. Two pairs of CN ligands of W(CN8 are bridged to two MnII atoms, the remaining CN ligands being terminal. Each MnII atom is additionally coordinated by a bidentate 2,2′-bipyridyl ligand and two water molecules. The crystal structure is stabilized by O—H...O and O—H...N hydrogen bonds.

  5. Synthesis, spectroscopic, electrochemical and luminescence studies of ruthenium (II) polypyridyls containing multifunctionalized 1,2,4-triazole as co-ligand

    Indian Academy of Sciences (India)

    L Mishra; A K Yadaw

    2000-08-01

    Ruthenium (II) 2,2 -bipyridyl and 1,10-phenanthroline complexes with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (LH2) as co-ligand were synthesised and characterized by elemental analysis, IR, UV/Vis, 1H NMR spectra and FAB-mass data. The electrochemical and luminescent properties of the complexes were also studied.

  6. Tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based electrochemiluminescence coupled with capillary zone electrophoresis

    International Nuclear Information System (INIS)

    Capillary zone electrophoresis (CZE) coupled with tris(2,2'-bipyridyl) ruthenium(II)-based end-column electrogenerated chemiluminescence (ECL) has been utilized to detect bisoprolol in drugs and tablets after its separation from metoprolol. Tetrahydrofuran was used as an additive in the running buffer to obtain the absolute ECL peak of bisoprolol. Bisoprolol reacts as a co-reactant in tris(2,2'-bipyridyl) ruthenium(II) ECL system. Under the optimized experimental conditions, bisoprolol was separated successfully and efficiently from metoprolol and other co-existed materials in tablets and urine samples. The ECL intensity of tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based system is linear with the concentration of bisoprolol from 1.5 μM to 0.3 mM with a detection limit of 0.3 μM. Relative standard derivations of the ECL intensity are 2.58% for the detection of 15 μM bisoprolol. This method is a simple, rapid, selective, and sensitive. It was applied successfully for the monitoring of bisoprolol in market available tablets and human urine samples

  7. Angular Cheilitis

    Science.gov (United States)

    ... A This image displays a frequent location for candida infection (angular cheilitis), the corners of the mouth. Overview ... infection, those affected may also have thrush (oral candidiasis). The areas are generally slightly painful. The condition ...

  8. Synthesis and characterization of uranyl acetate complexes with some potentially bidentate ligands

    International Nuclear Information System (INIS)

    Complexes of uranyl acetate with three potentially bidentate ligands-nicotinic acid (NA), 2,2'-bipyridyl(2,2'-Bipy) and 4,4'-bipyridyl N,N'-dioxide (4,4'-BipyO2) have been synthesized and characterized on the basis of analytical data, electrical conductance, electronic and IR spectral studies. Uranyl acetate forms 1:1 complexes with 2,2'-Bipy and 4,4'-BipyO2 and a 1:2 complex with NA. It is shown that UO2(NA)2(CH3COO)2 and UO2(2,2'-Bipy)(CH3COO)2 have monomeric structures while UO2(4,4'-BipyO2)(CH3COO)2 has a polymeric chain structure. The acetate groups act as bidentate chelating ligands in these complexes. All the compounds studied are considered to have an overall coordination number eight around uranium(VI). (author). 16 refs

  9. Effect of second ligand on the luminescence of Samarium (III) dibenzoylmethane complexes: Syntheses, crystal structures, thermal analysis and luminescence study

    Indian Academy of Sciences (India)

    Muhammad Idiris Saleh; Min Yee Choo; Tai Wei Chan; Mohd R Razali

    2015-12-01

    The ternary complexes of Sm(III) with dibenzoylmethane (dbm) were synthesized by introducing 1,10-phenanthroline (phen), 4,7-dimethyl-1,10-phenanthroline (dmphen), 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen), 4,7-diphenyl-1,10-phenanthroline (dpphen), 2,2-bipyridyl (bpy), 4,4’-dimethyl-2,2-bipyridyl (4,4-dmbpy), 5,5’-dimethyl-2,2-bipyridyl (5,5-dmbpy) and 4,4’-di-tert-butyl-2,2-bipyridyl (4,4-dtbbpy) as a second ligand. The complexes were isolated and characterized by elemental analysis (CHN), thermogravimetric analysis (TGA), IR spectroscopy, luminescence spectroscopy and single crystal X-ray diffraction. Structural study shows that in all complexes Sm(III) is in square antiprism geometry. All complexes emit strong luminescence under ultraviolet excitation. The strongest emission is at 643 nm which can be assigned for 4G5/2 to 6H9/2 transition, equivalent to energy of 15550 cm−1. The addition of the second ligand has increased the emission intensity of the complexes while the transition is maintained.

  10. Ruthenium(II)- bipyridyl with extended -system: Improved thermo-stable sensitizer for efficient and long-term durable dye sensitized solar cells

    Indian Academy of Sciences (India)

    M Chandrasekharam; G Rajkumar; Ch Srinivasa Rao; T Suresh; P Y Reddy; Y Soujanya

    2011-09-01

    A new extended thermo-stable high molar extinction coefficient bipyridyl ruthenium(II) complex "cis-Ru(4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine)(Ln)(NCS)2 H101", where Ln = 4,4'-dicarboxylic acid-2,2'-bipyridine; was synthesized and characterized by 1H-NMR, FT-IR and ESI-MASS spectroscopes. The H101 sensitized solar cell constructed with an active area of 0.54 cm2 in combination with an ionic liquid electrolyte exhibited broader photocurrent action spectrum with solar-to-electric energy conversion efficiency () of 5.89 (JSC = 12.14 mA/cm2, VOC = 690 V, fill factor = 0.699) under Air Mass (AM) 1.5 sunlight, while the reference `cis-Ru(4,4'-dinonyl-2,2'-bipyridine)(Ln)(NCS)2', Z907 sensitized solar cell exhibited -value of 5.17% (JSC = 11.93 mA/cm2, VOC = 650 V, fill factor = 0.666). TGA analysis of H101 showed extended thermal-stability and under continuous light exposure and aging at 55°C, the DSSC retained 85% of its initial -value, while under comparable conditions Z907 sensitized solar cell retained 88%. As compared to 4,4'-dinonyl-2,2'-bipyridine in Z907, the new ancillary bipyridyl ligand `4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine’ in H101 shifts the absorption bands remarkably towards blue. The Density Functional Theory (DFT) and Time-Dependent DFT excited state calculations of the new sensitizer show that the first three HOMOs have t2g character with sizeable mixing from the NCS ligands with -bonding orbitals of 4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine. The LUMO is a *-orbital localized on the 4,4-dicarboxylic acid-2,2'-bipyridine and higher un-occupied frontier orbitals have *-combinations with 4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine.

  11. pH-metric studies of mixed ligand complexes of uranyl ion with 4-amino 2,6-dihydroxy pyrimidine and some selected ligands

    International Nuclear Information System (INIS)

    Interaction of uranyl ion with 4-amino 2, 6-dihydroxy pyrimidine (ADHP) in presence of other ligands such as oxalic acid (Ox), malonic acid (Mal), O-aminophenol (OAP). O-phenylenediamine (OPDA), 2,2' bipyridyl (Bipy), 1, 10-phenanthroline (Phen) and ethylenediamine (En) has been investigated by potentiometric studies. The ternary complexes are formed in stepwise manner in which ADHP behaves as secondary ligand. The stability constants of ternary complexes have been reported at 35 degC and at μ = 0.01M (KNO3) in aqueous medium. (author). 11 refs., 1 fig., 1 tab

  12. Crystal structures of three co-crystals of 4,4′-bipyridyl with 4-alkoxybenzoic acids: 4-ethoxybenzoic acid–4,4′-bipyridyl (2/1, 4-n-propoxybenzoic acid–4,4′-bipyridyl (2/1 and 4-n-butoxybenzoic acid–4,4′-bipyridyl (2/1

    Directory of Open Access Journals (Sweden)

    Yohei Tabuchi

    2015-11-01

    Full Text Available The crystal structures of three hydrogen-bonded co-crystals of 4-alkoxybenzoic acid–4,4′-bipyridyl (2/1, namely, 2C9H10O3·C10H8N2, (I, 2C10H12O3·C10H8N2, (II and 2C11H14O3·C10H8N2, (III, have been determined at 93 K. Although the structure of (I has been determined in the space group P21 with Z = 4 [Lai et al. (2008. J. Struct. Chem. 49, 1137–1140], the present study shows that the space group is P21/n with Z = 4. In each crystal, the components are linked by O—H...N hydrogen bonds, forming a linear hydrogen-bonded 2:1 unit of the acid and the base. The 2:1 unit of (I adopts nearly pseudo-C2 symmetry, viz. twofold rotation around an axis passing through the mid-point of the central C—C bond of 4,4′-bipyridyl, while the units of (II and (III, except for the terminal alkyl chains, have pseudo-inversion symmetry. The 2:1 units of (I, (II and (III are linked via C—H...O hydrogen bonds, forming sheet, double-tape and tape structures, respectively.

  13. The heterometallic cadmium-silver complex cis-bis[dicyanidoargentato(I)-κN]bis(5,5'-dimethyl-2,2'-bipyridyl-κ(2)N,N')cadmium(II) monohydrate.

    Science.gov (United States)

    Piromchom, Jureepan; Wannarit, Nanthawat; Pakawatchai, Chaveng; Youngme, Sujittra

    2013-10-01

    In the title complex, [Ag2Cd(CN)4(C12H12N2)2]·H2O or cis-[Cd{Ag(CN)2}2(5,5'-dmbpy)2]·H2O, where 5,5'-dmbpy is 5,5'-dimethyl-2,2'-bipyridyl, the asymmetric unit consists of a discrete neutral [Cd{Ag(CN)2}2(5,5'-dmbpy)2] unit and a solvent water molecule. The Cd(II) cation is coordinated by two bidentate chelate 5,5'-dmbpy ligands and two monodentate [Ag(I)(CN)2](-) anions, which are in a cis arrangement around the Cd(II) cation, leading to an octahedral CdN6 geometry. The overall structure is stabilized by a combination of intermolecular hydrogen bonding, and Ag(I)···Ag(I) and π-π interactions, forming a three-dimensional supramolecular network. PMID:24096502

  14. Interaction of 4-amino 6-hydroxy 2-thiopyrimidine with uranyl ion in presence of other ligands

    International Nuclear Information System (INIS)

    Interaction of uranyl ion with 4-amino 6-hydroxy 2-thiopyrimidine(AHTP) in presence of other ligands such as oxalic acid (Ox), malonic acid (Mal), O-aminophenol (OAP), o-phenylenediamine (OPDA), 2, 2'-bipyridyl (Bipy), 1, 10-phenanthrolene (Phen) and ethylenediamine (En) has been investigated by potentiometric method. The ternary complexes are formed in stepwise manner in which AHTP behaves as secondary ligand. The formation constants of ternary complexes have been reported at 35 degC and μ = 0.10 M (KNO3) in aqueous medium. (author)

  15. Premalignant and neoplastic skin lesions associated with occupational exposure to “tarry” byproducts during manufacture of 4,4'-bipyridyl

    OpenAIRE

    Bowra, G T; Duffield, D. P.; Osborn, A J; Purchase, I F H

    1982-01-01

    ABSTRACT Skin lesions have been identified in 20 workers manufacturing 4,4'-bipyridyl. The lesions were on the face, neck, and backs of the hands and arms. Larger localised lesions were removed surgically and examined histopathologically, but other lesions have been treated topically with fluorouracil cream. Histological diagnosis showed a progression from keratosis to Bowen's disease and, in six cases, to squamous cell carcinoma. Over 550 individuals associated with 4,4'-bipyridyl processes ...

  16. Tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based electrochemiluminescence coupled with capillary zone electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jingwu [Department of Chemistry, Nanchang University, Nanchang 330031 (China)], E-mail: wangjingwu@ncu.edu.cn; Zhang Xiaojun; Pi Fangfang [Department of Chemistry, Nanchang University, Nanchang 330031 (China); Wang Xiaoxia [Graduate School of Engineering, University of Fukui, Fukui 910-8507 (Japan); Yang Nianjun [Diamond Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Central 2-13, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)], E-mail: nianjun.yang@iaf.fraunhofer.de

    2009-03-01

    Capillary zone electrophoresis (CZE) coupled with tris(2,2'-bipyridyl) ruthenium(II)-based end-column electrogenerated chemiluminescence (ECL) has been utilized to detect bisoprolol in drugs and tablets after its separation from metoprolol. Tetrahydrofuran was used as an additive in the running buffer to obtain the absolute ECL peak of bisoprolol. Bisoprolol reacts as a co-reactant in tris(2,2'-bipyridyl) ruthenium(II) ECL system. Under the optimized experimental conditions, bisoprolol was separated successfully and efficiently from metoprolol and other co-existed materials in tablets and urine samples. The ECL intensity of tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based system is linear with the concentration of bisoprolol from 1.5 {mu}M to 0.3 mM with a detection limit of 0.3 {mu}M. Relative standard derivations of the ECL intensity are 2.58% for the detection of 15 {mu}M bisoprolol. This method is a simple, rapid, selective, and sensitive. It was applied successfully for the monitoring of bisoprolol in market available tablets and human urine samples.

  17. Synthesis and characterization of 6,6’-bis(2-hydroxyphenyl)-2,2’-bipyridine ligand and its interaction with ct-DNA

    International Nuclear Information System (INIS)

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6’-dibromo-2,2’-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6’-bis(2-methoxyphenyl)-2,2’-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by 1H, 2D cosy and 13C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant Kb = 1.19 × 103 ± 0.08 M−1

  18. Synthesis and characterization of 6,6'-bis(2-hydroxyphenyl)-2,2'-bipyridine ligand and its interaction with ct-DNA

    Science.gov (United States)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd

    2015-09-01

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6'-dibromo-2,2'-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6'-bis(2-methoxyphenyl)-2,2'-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by 1H, 2D cosy and 13C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant Kb = 1.19 × 103 ± 0.08 M-1.

  19. Synthesis and characterization of 6,6’-bis(2-hydroxyphenyl)-2,2’-bipyridine ligand and its interaction with ct-DNA

    Energy Technology Data Exchange (ETDEWEB)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43650 Bangi, Selangor (Malaysia)

    2015-09-25

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6’-dibromo-2,2’-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6’-bis(2-methoxyphenyl)-2,2’-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by {sup 1}H, 2D cosy and {sup 13}C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant K{sub b} = 1.19 × 10{sup 3} ± 0.08 M{sup −1}.

  20. Synthesis, structure and spectroscopic properties of complexes of rare earth dithiocarbamates with 2,2{prime}-bipyridyl or 1, 10-phenanthroline

    Energy Technology Data Exchange (ETDEWEB)

    Chengyong Su; Minyu Tan; Ning Tang; Xinmin Gan; Weisheng Liu [Lanzhou Univ. (China)] [and others

    1996-05-01

    Two series of rare earth complexes with the general formula [RE(Me{sub 2}Dtc){sub 3}](RE = La,Pr,Nd,Sm-Yb, Y;Me{sub 2}Dtc = N,N-dimethyldithiocarbamate; bipy = 2,2{prime}-bipyridyl) and [RE(Et{sub 2-}Dtc){sub 3}(phen)](RE = La,Pr,Nd,Sm-Lu, Y;Et{sub 2}Dtc = N,N-diethyldithiocarbamate; phen = 1, 10-phenanthroline) have been prepared and some of their chemical properties, IR spectra, electronic spectra and conductivity properties are reported. The structures of [Eu(Me{sub 2}Dtc){sub 3}(bipy)] and [Eu(Et{sub 2}Dtc){sub 3}(phen)] have been determined by single-crystal X-ray diffraction methods. [Eu(Et{sub 2}Dtc){sub 3}(phen)] crystallizes in the tetragonal system, space group I4{sub 1}/a with a = 16.753(1), c = 39.523 (3) {angstrom} and Z = 16, while [Eu(Et{sub 2}Dtc){sub 3}(phen)]crystallizes in the monoclinic system, space group P2{sub 1}/c with a = 17.029(3), b = 10.652(3), c = 18.726(3) {angstrom}, {beta} = 96.41(4){degrees} and Z = 4. The central Eu(III) atoms are both octa-coordinated and in a distorted square antiprismatic geometry, each being coordinated to six sulphur atoms of three bidentate dithiocarbamates and to two nitrogen atoms of bipy or phen ligands. Spectrum analyses indicate that both Me{sub 2}Dtc and Et{sub 2}Dtc show similar coordination structures in all complexes.

  1. (Carbonato-κ2O,O′bis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′cobalt(III bromide trihydrate

    Directory of Open Access Journals (Sweden)

    Kannan Arun Kumar

    2012-04-01

    Full Text Available In the title complex, [Co(CO3(C12H12N22]Br·3H2O, the CoIII cation has a distorted octahedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water molecules are disordered and their H atoms were not located, there are typical O...O distances between 2.8 and 3.0 Å, indicating O—H...O hydrogen bonding. The crystal packing is consolidated by C—H...O and C—H...Br hydrogen bonds, as well as π–π stacking interactions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694 (3 and 3.7053 (3 Å.

  2. Excited-state absorption of a bipyridyl platinum(II) complex with alkynyl-benzothiazolylfluorene units.

    Science.gov (United States)

    Pritchett, Timothy M; Sun, Wenfang; Zhang, Bingguang; Ferry, Michael J; Li, Yunjing; Haley, Joy E; Mackie, David M; Shensky, William; Mott, Andrew G

    2010-05-01

    The singlet excited-state lifetime of a bipyridyl platinum(II) complex containing two alkynyl-benzothiazolylfluorene units was determined to be 145+/-105 ps by fitting femtosecond transient difference absorption data, and the triplet quantum yield was measured to be 0.14. A ground-state absorption cross section of 6.1 x 10(-19) cm(2) at 532 nm was deduced from UV-visible absorption data. Excited-state absorption cross sections of (6.7+/-0.1) x 10(-17) cm(2) (singlet) and (4.6+/-0.1) x 10(-16) cm(2) (triplet) were obtained by using a five-level dynamic model to fit open-aperture Z scans at picosecond and nanosecond pulse widths and a variety of pulse energies. For this complex, the ratio of the triplet excited-state absorption cross section to the ground-state absorption cross section--long used as a figure of merit for reverse saturable absorbers--thus stands at 754, to our knowledge the largest ever reported at 532 nm wavelength. PMID:20436550

  3. Synthesis, Characterization, and Antifungal Studies of Cr(III Complex of Norfloxacin and Bipiridyl Ligand

    Directory of Open Access Journals (Sweden)

    Anamika Debnath

    2014-01-01

    Full Text Available A novel slightly distorted octahedral complex of Cr(III of norfloxacin (Nor with the formula [CrIII(Nor(BipyCl2]Cl·2CH3OH has been synthesized hydrothermally in the presence of a N-containing heterocyclic compound 2,2′-bipyridyl (Bipy. The complex was characterized with FT-IR, elemental analysis, UV-visible spectroscopy, and X-ray crystallography. Spectral studies suggest that the Nor acts as a deprotonated bidentate ligand. Thermal studies were also carried out. The synthesised complex was screened against four fungi Pythium aphanidermatum (PA, Sclerotinia rolfsii (SR, Rhizoctonia solani (RS, and Rhizoctonia bataticola (RB.

  4. Crystal structures of copper(II) nitrate complexes containing 4,4'-bipyridyl and halogen-substituted 2-[(2-hydroxyethylimino)methyl]phenols

    International Nuclear Information System (INIS)

    The crystal structures of (μ-4,4'-bipyridyl)-di{nitrato-2,4-dibromo-6-[(2-hydroxyethylimino)methyl] phenolo (1-)copper} (I), (μ-4,4'-bipyridyl)-di{nitrato-2,4-dichloro-6-[(2-hydroxyethylimino)methyl] phenolo(1-)copper} (II), and (μ-4,4'-bipyridyl)-{4-chloro-2-[(2-hydroxyethylimino)methyl]phenolo(2-) copper-nitrato-4-chloro-2-[(2-hydroxyethylimino)methyl]phenolo(1-)copper} tetrahydrate (III) are determined. The crystal structures of compounds I and II contain binuclear complexes, in which each copper atom is coordinated by the singly deprotonated tridentate molecule of the corresponding azomethine, the monodentate nitrate ion, and bipyridyl that plays the role of a bridge between the central atoms. In the structures of compounds I and II, the coordination polyhedra of the copper atoms are slightly distorted tetragonal pyramids. The pyramid base is formed by the imine and bipyridyl nitrogen atoms and the phenol and alcohol oxygen atoms. The axial vertices of the pyramids are occupied by the oxygen atoms of the monodentate nitrato groups. The crystal structure of compound III involves tetranuclear complexes in which the coordination polyhedra of the central copper atoms are (4 + 1 + 1) bipyramids. The base of these bipyramids is formed by the imine and bipyridyl nitrogen atoms and the phenol and alcohol oxygen atoms. One apical vertex is occupied by the bridging phenol oxygen atom of the nearest complex. The sixth coordination site of the first copper atom is occupied by the chlorine atom of the salicylidene fragment of the neighboring complex related to the initial complex through the center of symmetry. In turn, the sixth coordination site of the second copper atom is occupied by the oxygen atom of the monodentate nitrato group.

  5. Purification of Bipyridyl Ruthenium Dye and Its Application in Dye-Sensitized Solar Cells

    International Nuclear Information System (INIS)

    Bipyridyl ruthenium dye N3 and N719 was synthesized, purified by the gel chromatogram method and characterized by the proton NMR and UV-Vis spectra. After the purification most of the impurities that decreased the photoelectrochemical properties were removed and the open-circuit voltage (Voc), short-circuit photocurrent density (Jsc) and overall photo-electric conversion efficiency (η) of the dye-sensitized solar cells (DSCs) increased dramatically. The standard curve of absorbance vs. concentration of N3 and N719 dye was achieved by using UV-Vis quantitative analytic spectrophotometry. This method was employed to determine the concentration of the dye solution after coating of TiO2 films. The linear concentration range of absorbance vs. concentration of N719 was between 6.25 x 10-6 mol . L-1 and 1 x 10-4 mol . L-1 with the molar extinction coefficient (ε) 1.58 x 104 L . mol-1cm-1 at a wavelength of 533 ∼ 531 nm and 1.50 x 104 L . mol-1 . cm-1 at a wavelength of 393 ∼ 384 nm , accordingly. The linear concentration range of the N3 dye was 6.25 x 10-6 mol . L-1 to 1.5 x 10-4 mol . L-1 with ε of 1.47 x 104 L . mol-1 . cm-1 at a wavelength of 538 ∼ 535 nm and 1.48 x 104 L . mol-1 . cm-1 at a wavelength of 399 ∼ 393 nm

  6. Professional AngularJS

    CERN Document Server

    Karpov, Valeri

    2015-01-01

    A comprehensive guide to AngularJS, Google's open-source client-side framework for app development. Most of the existing guides to AngularJS struggle to provide simple and understandable explanations for more advanced concepts. As a result, some developers who understand all the basic concepts of AngularJS struggle when it comes to building more complex real-world applications. Professional AngularJS provides a thorough understanding of AngularJS, covering everything from basic concepts, such as directives and data binding, to more advanced concepts like transclusion, build systems, and auto

  7. Quark Orbital Angular Momentum

    OpenAIRE

    Burkardt Matthias

    2015-01-01

    Definitions of orbital angular momentum based on Wigner distributions are used as a framework to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. We find that the difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asy...

  8. Partonic orbital angular momentum

    Science.gov (United States)

    Arash, Firooz; Taghavi-Shahri, Fatemeh; Shahveh, Abolfazl

    2013-04-01

    Ji's decomposition of nucleon spin is used and the orbital angular momentum of quarks and gluon are calculated. We have utilized the so called valon model description of the nucleon in the next to leading order. It is found that the average orbital angular momentum of quarks is positive, but small, whereas that of gluon is negative and large. Individual quark flavor contributions are also calculated. Some regularities on the total angular momentum of the quarks and gluon are observed.

  9. Spectroscopic studies on the luminescence properties of ternary europium complexes with different ligands

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Xiao, E-mail: zhangx@simtech.a-star.edu.s [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore)

    2010-06-15

    In this paper, ligand effect of several bi-dental oxygen (O) and nitrogen (N) ligands on the red luminescence properties of europium ion (Eu{sup 3+}) was studied comprehensively. Absorption, emission, and excitation spectral properties of ternary europium complexes with different combinations of ligands including thenoyl trifluoroacetone (TTA), naphthyl trifluoroacetone (NTA), 2,2'-bipyridyl (bpy) and phenanthroline (Phen) were investigated. Efficient Eu{sup 3+} red emission was observed with all the combinations of the above mentioned ligands. The most intense emission was found with the all nitrogen coordinated complex Eu(bpy){sub 2}(Phen){sub 2} while the longest wavelength excitation band was recorded with oxygen-nitrogen mixed NTA-bpy complex Eu(NTA){sub 1}(bpy){sub 3}. With change of the ligands combination and ratio, the Eu{sup 3+} emission peak changes slightly from 612 to 618 nm. The absorption and excitation spectra of the europium complexes were compared and analyzed referring to the individual absorption spectral properties of the ligands. The relation between ligand-to-metal charge transfer states and luminescence intensities for different complexes was studied.

  10. Rotations and angular momentum

    International Nuclear Information System (INIS)

    This paper is devoted to the analysis of rotational invariance and the properties of angular momentum in quantum mechanics. In particular, the problem of addition of angular momenta is treated in detail, and tables of Clebsch-Gordan coefficients are included

  11. Replacing the hydrogen in the intermolecular hydrogen bond of the cyanuric acid-bipyridyl adduct by Ag(I)

    Indian Academy of Sciences (India)

    K Sivashankar; Anupama Ranganathan; V R Pedireddi

    2000-04-01

    A complex between cyanuric acid (CA), 4,4′-bipyridyl (BP) and Ag(I), with the composition, [Ag2(C3H2N3O3-N)2 (C10H8N2-N)] has been prepared. Crystal structure analysis shows that it has a chain structure in which the CA molecules are linked to the BP units through silver atoms by the formation of N-Ag-N bonds, wherein one of the hydrogens of CA is replaced by Ag(I), showing thereby the chains connected to one another by N-H${\\ldots}$O hydrogen bonds formed between the CA molecules. This intermolecular chain structure resembles the chain structure of the CA.BP adduct where CA-BP-CA chains formed by N-H${\\ldots}$N hydrogen bonds are linked to one another by N-H${\\ldots}$O hydrogen bonds between the CA molecules.

  12. Determination of disopyramide in human urine by capillary electrophoresis with electrochemiluminescence detection of tris(2,2'-bipyridyl) ruthenium (II)

    International Nuclear Information System (INIS)

    Capillary electrophoresis (CE) with electrochemiluminescence detection (ECL) of disopyramide based on tris(2,2'-bipyridyl) ruthenium(II) was described. After CE separation using a 50 μm i.d. uncoated capillary column and 10 mM running buffer solution at 15 kV of separation potential, the analyte was detected at the surface of platinum disk electrode (300 μm in diameter) working electrode. Parameters influencing separation and detection were optimized in detail. Under optimal condition the detection limit was 2.5 x 10-8 mol L-1 (S/N = 3). The method can be successfully applied for the determination of disopyramide in human urine after an easy, rapid and cheap extraction procedure. Extraction recovery rates were between 92.3 and 96.9%

  13. DVL Angular Velocity Recorder

    Science.gov (United States)

    Liebe, Wolfgang

    1944-01-01

    In many studies, especially of nonstationary flight motion, it is necessary to determine the angular velocities at which the airplane rotates about its various axes. The three-component recorder is designed to serve this purpose. If the angular velocity for one flight attitude is known, other important quantities can be derived from its time rate of change, such as the angular acceleration by differentiations, or - by integration - the angles of position of the airplane - that is, the angles formed by the airplane axes with the axis direction presented at the instant of the beginning of the motion that is to be investigated.

  14. Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Burkardt Matthias

    2015-01-01

    Full Text Available Definitions of orbital angular momentum based on Wigner distributions are used as a framework to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. We find that the difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asymmetries in semi-inclusive deep-inelastic scattering.

  15. Ylide Ligands

    OpenAIRE

    Esteban P. Urriolabeitia

    2010-01-01

    The use of ylides of P, N, As, or S as ligands toward transition metals is still a very active research area in organometallic chemistry. This fact is mainly due to the nucleophilic character of the ylides and to their particular bonding properties and coordination modes. They can behave as monodentate or bidentate chelate or bridging species, they can be used as chiral auxiliary reagents, and they are interesting reaction intermediates or useful starting materials in a wide ...

  16. Optical Angular Momentum

    International Nuclear Information System (INIS)

    For many years the Institute of Physics has published books on hot topics based on a collection of reprints from different journals, including some remarks by the editors of each volume. The book on Optical Angular Momentum, edited by L Allen, S M Barnett and M J Padgett, is a recent addition to the series. It reproduces forty four papers originally published in different journals and in a few cases it provides direct access to works not easily accessible to a web navigator. The collection covers nearly a hundred years of progress in physics, starting from an historic 1909 paper by Poynting, and ending with a 2002 paper by Padgett, Barnett and coworkers on the measurement of the orbital angular momentum of a single photon. The field of optical angular momentum has expanded greatly, creating an interdisciplinary attraction for researchers operating in quantum optics, atomic physics, solid state physics, biophysics and quantum information theory. The development of laser optics, especially the control of single mode sources, has made possible the specific design of optical radiation modes with a high degree of control on the light angular momentum. The editors of this book are important figures in the field of angular momentum, having contributed to key progress in the area. L Allen published an historical paper in 1999, he and M J Padgett (together with M Babiker) produced few years ago a long review article which is today still the most complete basic introduction to the angular momentum of light, while S M Barnett has contributed several high quality papers to the progress of this area of physics. The editors' choice provides an excellent overview to all readers, with papers classified into eight different topics, covering the basic principles of the light and spin and orbital angular momentum, the laboratory tools for creating laser beams carrying orbital angular momentum, the optical forces and torques created by laser beams carrying angular momentum on

  17. Average Angular Velocity

    OpenAIRE

    Van Essen, H.

    2004-01-01

    This paper addresses the problem of the separation of rotational and internal motion. It introduces the concept of average angular velocity as the moment of inertia weighted average of particle angular velocities. It extends and elucidates the concept of Jellinek and Li (1989) of separation of the energy of overall rotation in an arbitrary (non-linear) $N$-particle system. It generalizes the so called Koenig's theorem on the two parts of the kinetic energy (center of mass plus internal) to th...

  18. Angular velocity discrimination

    Science.gov (United States)

    Kaiser, Mary K.

    1990-01-01

    Three experiments designed to investigate the ability of naive observers to discriminate rotational velocities of two simultaneously viewed objects are described. Rotations are constrained to occur about the x and y axes, resulting in linear two-dimensional image trajectories. The results indicate that observers can discriminate angular velocities with a competence near that for linear velocities. However, perceived angular rate is influenced by structural aspects of the stimuli.

  19. Orbital angular momentum effects

    International Nuclear Information System (INIS)

    This paper reports that in the context of the parton model description of baryon structure orbital angular momentum effects have long been considered negligible. However, recent results obtained within the framework of QCD and presented in this talk indicate that a substantial fraction of the baryon spin may be carried as orbital angular momentum of its constituents. These results are of particular relevance in the light of new data on the spin structure of the proton recently published by the EMC collaboration

  20. Detection of pyrrolizidine alkaloids using flow analysis with both acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence

    International Nuclear Information System (INIS)

    For the first time, analytically useful chemiluminescence was elicited from the reactions of the pyrrolizidine alkaloids. Heliotrine, retronecine, supinine, monocrotaline and echinatine N-oxide yielded chemiluminescence upon reaction with tris(2,2'-bipyridyl)ruthenium(II) whilst lasiocarpine, its N-oxide and supinine elicited light upon reaction with acidic potassium permanganate. Detection limits for heliotrine were 1.25 x 10-7 M and 9 x 10-9 M for tris(2,2'-bipyridyl)ruthenium(III) perchlorate with flow injection analysis (FIA) and the silica-immobilised reagent (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2,2'-bipyridine)bis (2,2'-bipyridyl)ruthenium(II) with sequential injection analysis (SIA), respectively. Lasiocarpine was detectable at 1.4 x 10-7 M using acidic potassium permanganate with FIA. Additionally, the silica-immobilised reagent was optimised with respect to the oxidant (ammonium ceric nitrate) concentration and the aspiration times which afforded a detection limit for codeine of 5 x 10-10 M using SIA

  1. Fourier relationship between angular position and optical orbital angular momentum

    OpenAIRE

    Yao, E.; Franke-Arnold, S.; Courtial, J.; Barnett, S.; Padgett, M. J.

    2006-01-01

    We demonstrate the Fourier relationship between angular position and angular momentum for a light mode. In particular we measure the distribution of orbital angular momentum states of light that has passed through an aperture and verify that the orbital angular momentum distribution is given by the complex Fourier-transform of the aperture function. We use spatial light modulators, configured as diffractive optical components, to define the initial orbital angular momentum state of the beam, ...

  2. Separation of americium(III) and europium(III) from nitrate medium using a binary mixture of Cyanex-301 with neutral donor ligands

    International Nuclear Information System (INIS)

    Separation behaviour of Am3+ and Eu3+ was investigated from aqueous nitrate medium using a binary mixture of Cyanex-301 (bis(2,4,4- trimethylpentyl) dithiophosphinic acid) and several N, O or S donor ligands such as 1,10-phenanthroline (phen), TPTZ (2,4,6- tri(2-pyridyl)- 1,3,5- triazine), 2,2'-bipyridyl(bipy), hexa thia 18 crown 6 (S618C6), TBP (tri-n-butyl phosphate), TBTP (tri-n-butyl thiophosphate) in toluene. The S.F. values of >40,000 obtained with bipy and phen are the highest reported to date. (author)

  3. Ternary complexes in solution: complex formation between copper(II), zinc(II), cadmium(II) and ligands of biological importance

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, K.; Ram Prasad, D.; Nigam, P.C. (Indian Inst. of Tech., Kanpur. Dept. of Chemistry)

    1984-01-01

    The stability constants of ternary complexes of the MAL type have been determined for Cu(II), Zn(II) and Cd(II). The ligands chosen for this study belong to the biologically important ones viz. Bipyridyl (A) and nitrilotriacetic acid (L). Log Ksub(MAL) values for Cu(II), Zn(II) and Cd(II) are 11.42, 10.67 and 9.72, respectively, at temp. = 25/sup 0/C and ..mu.. = 0.1 M (KNO/sub 3/); the order is discussed.

  4. Fluidic angular velocity sensor

    Science.gov (United States)

    Berdahl, C. M. (Inventor)

    1986-01-01

    A fluidic sensor providing a differential pressure signal proportional to the angular velocity of a rotary input is described. In one embodiment the sensor includes a fluid pump having an impeller coupled to a rotary input. A housing forming a constricting fluid flow chamber is connected to the fluid input of the pump. The housing is provided with a fluid flow restrictive input to the flow chamber and a port communicating with the interior of the flow chamber. The differential pressure signal measured across the flow restrictive input is relatively noise free and proportional to the square of the angular velocity of the impeller. In an alternative embodiment, the flow chamber has a generally cylindrical configuration and plates having flow restrictive apertures are disposed within the chamber downstream from the housing port. In this embodiment, the differential pressure signal is found to be approximately linear with the angular velocity of the impeller.

  5. Metamaterial broadband angular selectivity

    Science.gov (United States)

    Shen, Yichen; Ye, Dexin; Wang, Li; Celanovic, Ivan; Ran, Lixin; Joannopoulos, John D.; Soljačić, Marin

    2014-09-01

    We demonstrate how broadband angular selectivity can be achieved with stacks of one-dimensionally periodic photonic crystals, each consisting of alternating isotropic layers and effective anisotropic layers, where each effective anisotropic layer is constructed from a multilayered metamaterial. We show that by simply changing the structure of the metamaterials, the selective angle can be tuned to a broad range of angles; and, by increasing the number of stacks, the angular transmission window can be made as narrow as desired. As a proof of principle, we realize the idea experimentally in the microwave regime. The angular selectivity and tunability we report here can have various applications such as in directional control of electromagnetic emitters and detectors.

  6. Metamaterial Broadband Angular Selectivity

    CERN Document Server

    Shen, Yichen; Wang, Zhiyu; Wang, Li; Celanovic, Ivan; Ran, Lixin; Joannopoulos, John D; Soljacic, Marin

    2014-01-01

    We demonstrate how broadband angular selectivity can be achieved with stacks of one-dimensionally periodic photonic crystals, each consisting of alternating isotropic layers and effective anisotropic layers, where each effective anisotropic layer is constructed from a multilayered metamaterial. We show that by simply changing the structure of the metamaterials, the selective angle can be tuned to a broad range of angles; and, by increasing the number of stacks, the angular transmission window can be made as narrow as desired. As a proof of principle, we realize the idea experimentally in the microwave regime. The angular selectivity and tunability we report here can have various applications such as in directional control of electromagnetic emitters and detectors.

  7. Supramolecular Terbium-SIP Complex Pillared by 4,4'-Bipyridyl,{[Tb(SIP)(H2O)5]2(bpy)3(H2O))n:Synthesis,Crystal Structure and Photoluminescence

    Institute of Scientific and Technical Information of China (English)

    WANG Yu-Ling; LIU Qing-Yan; XU Li; ZHONG Sheng-Liang

    2008-01-01

    The supramolecular terbium complex,{[To(SIP)(H2O)5]2(bpy)3(H2O)}n(NaH2SIP=5-sulfoisophthalic acid monosodium salt and bpy=4,4'-bipyridyl),has been synthesized by the hydrothermal reaction of Tb4O7 with NaH2SIP and bpy at 165℃,and characterized by single-crystal X-ray diffraction,elemental analysis,IR spectrum,powder X-ray diffraction and photoluminescence spectrum.It crystallizes in a monoclinic system,space group C2/c,with a=30.6840(1),b=10.9206(2),c=17.4967(3)(A),β=111.931(1)°,V=5438.65(14)(A)3,Z=4,C46H52N6O25S2Tb2,Mr=1470.90,Dc=1.796g/cm3,μ=2.747mm-1,F(000)=2928,the final R=0.0654 and wR=0.1322 for 3806 observed reflections with Ⅰ>2σ(Ⅰ).In the neural [Tb(SIP)(H2O)5]2 motif,the Tb(Ⅲ)ions are linked by the SIP ligands to form a one-dimensional zigzag chain propagating along the c axis.The zigzag chains are linked together by hydrogen bonds and π-π stacking interactions to form a two-dimensional supramolecular framework.The uncoordinated bpy molecules act as pillars to extend the two-dimensional sheets into a distinctive pillared three-dimensional supramolecular structure through O-H…N hydrogen bonds.The photoluminescence of the complex was investigated at room temperature in the solid state.

  8. Average Angular Velocity

    CERN Document Server

    Essén, H

    2003-01-01

    This paper addresses the problem of the separation of rotational and internal motion. It introduces the concept of average angular velocity as the moment of inertia weighted average of particle angular velocities. It extends and elucidates the concept of Jellinek and Li (1989) of separation of the energy of overall rotation in an arbitrary (non-linear) $N$-particle system. It generalizes the so called Koenig's theorem on the two parts of the kinetic energy (center of mass plus internal) to three parts: center of mass, rotational, plus the remaining internal energy relative to an optimally translating and rotating frame.

  9. Angular Scaling In Jets

    Energy Technology Data Exchange (ETDEWEB)

    Jankowiak, Martin; Larkoski, Andrew J.; /SLAC

    2012-02-17

    We introduce a jet shape observable defined for an ensemble of jets in terms of two-particle angular correlations and a resolution parameter R. This quantity is infrared and collinear safe and can be interpreted as a scaling exponent for the angular distribution of mass inside the jet. For small R it is close to the value 2 as a consequence of the approximately scale invariant QCD dynamics. For large R it is sensitive to non-perturbative effects. We describe the use of this correlation function for tests of QCD, for studying underlying event and pile-up effects, and for tuning Monte Carlo event generators.

  10. Electrogenerated chemiluminescence: An oxidative-reductive mechanism between quinolone antibiotics and tris(2,2'-bipyridyl)ruthenium(II)

    Energy Technology Data Exchange (ETDEWEB)

    Burkhead, Matthew S.; Wang, Heeyoung; Fallet, Marcel [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States); Gross, Erin M. [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States)], E-mail: eringross@creighton.edu

    2008-04-21

    The cyclic voltammetry and electrogenerated chemiluminescent (ECL) reactions of a series of quinolone and fluoroquinolone antibiotics were investigated in a flow injection analysis (FIA) system. 7-Piperazinyl fluoroquinolone antibiotics were found to participate as a coreactant in an oxidative-reductive ECL mechanism with tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy){sub 3}{sup 2+}) as the luminescent reagent. The reaction mechanism was investigated in order to understand and optimize the processes leading to light emission. The optimal conditions included a solution pH {approx}7 at a flow rate of 3.0 mL min{sup -1} with no added organic modifier and application of 1.2 V vs. a Pt quasi-reference electrode (QRE). Fluoroquinolones containing a tertiary distal nitrogen on the piperazine ring, such as enrofloxacin and ofloxacin, reacted to produce more intense ECL than those with a secondary nitrogen, such as ciprofloxacin and norfloxacin. The method linear range, precision, detection limits, and sensitivity for the detection of enrofloxacin and ciprofloxacin were compared to that of tripropylamine. The method was applied to the determination of the ciprofloxacin content in a pharmaceutical preparation. The assay is discussed in terms of its analytical figures of merit, ease of use, speed, accuracy and application to pharmaceutical samples.

  11. Inhibition of Pseudomonas aeruginosa biofilm formation by 2,2’-bipyridyl, lipoic, kojic and picolinic acids

    Directory of Open Access Journals (Sweden)

    Kübra Çevik

    2015-08-01

    Full Text Available Objective(s:The inhibitory effects of iron chelators, and FeCl3 chelation on biofilm formation and swarming motility were investigated against an opportunistic human pathogen Pseudomonas aeruginosa. Materials and Methods:The inhibitory activity of 2,2’-bipyridyl, lipoic acid, kojic acid and picolinic acidonbiofilm formation of P. aeruginosa strain PAO1 and three clinical isolates (P. aeruginosa  PAK01,P. aeruginosa PAK02 and P. aeruginosa PAK03 were investigated, based on crystal violet assay, and swarming motility test. Results:The kojic, lipoic and picolinic acid inhibited biofilm formation by 5-33% in all tested P. aeruginosa isolates. When chelated iron was added, biofilm inhibition rates were determined to be 39-57%. Among the tested chelators against P. aeruginosa, lipoic acid (84% and kojic acid (68% presented the highest inhibition of swarming motility. This is the first study to report the inhibitory effect of lipoic acid on biofilm formation and swarming motility of P. aeruginosa. Conclusion: It is considered that lipoic and picolinic acids can serve as alternatives for the treatment of the P. aeruginosa infections by inhibiting biofilm formation.

  12. A 3D POM–MOF composite based on Ni(ΙΙ) ion and 2,2′-bipyridyl-3,3′-dicarboxylic acid: Crystal structure and proton conductivity

    International Nuclear Information System (INIS)

    We have succeeded in constructing a 3D POM–MOF, (H[Ni(Hbpdc)(H2O)2]2[PW12O40]·8H2O)n (H2bpdc=2,2′-bipyridyl-3,3′-dicarboxylic acid), by the controllable self-assembly of H2bpdc, Keggin-anions and Ni2+ ions based on the electrostatic and coordination interactions. Interestingly, Hbpdc− as polydentate organic ligands and Keggin-anion as polydentate inorganic ligands are covalently linked transition-metal nickel at the same time. The title complex represents a new example of introducing the metal N-heterocyclic multi-carboxylic acid frameworks into POMs chemistry. Based on Keggin-anions being immobilized as part of the metal N-heterocyclic multi-carboxylic acid framework, the title complex realizes four approaches in the 1D hydrophilic channel used to engender proton conductivity in MOFs. Its water adsorption isotherm at room temperature and pressure shows that the water content in it was 31 cm3 g−1 at the maximum allowable humidity, corresponding to 3.7 water molecules per unit formula. It exhibits good proton conductivities (10−4–10−3 S cm−1) at 100 °C in the relative humidity range 35–98%. The corresponding activation energy (Ea) of conductivity was estimated to be 1.01 eV. - Graphical abstract: A POM–MOF composite constructed by Keggin-type polyanion, Ni2+ and H2bpdc shows good proton conductivities of 10−4–10−3 S cm−1 at 100 °C under 35–98% RH. - Highlights: • A POM–MOF was constructed by combining metal N-heterocyclic multi-carboxylic acid framework and Keggin anion. • It opens a pathway for design and synthesis of multifunctional hybrid materials based on two building units. • Three types of potential proton-carriers have been assembled in the 1D hydrophilic channels of the POM–MOF. • It achieved such proton conductivities as 10−4–10−3 S cm−1 at 100 °C in the RH range 35–98%

  13. Angular momentum projected semiclassics

    Science.gov (United States)

    Hasse, Rainer W.

    1987-06-01

    By using angular momentum projected plane waves as wave functions, we derive semiclassical expressions for the single-particle propagator, the partition function, the nonlocal density matrix, the single-particle density and the one particle-one hole level density for fixed angular momentum and fixed z-component or summed over the z-components. Other quantities can be deduced from the propagator. In coordinate space ( r, r') the relevant quantities depend on |r-r'| instead of | r- r'| and in Wigner space ( R, P) they become proportional to the angular momentum constraints δ(| R × P|/ h̵-l) and δ( R × P) z/ h̵-m) . As applications we calculate the single-particle and one-particle-one hole level densities for harmonic oscillator and Hill-Wheeler box potentials and the imaginary part of the optical potential and its volume integral with an underlying harmonic oscillator potential and a zero range two-body interaction.

  14. Synthesis, spectral, thermal, and antibacterial investigation of mixed ligand complexes of oxovanadium(IV)

    International Nuclear Information System (INIS)

    Novel mononuclear mixed-ligand oxovanadium(IV) complex [VO(PMFP)(Bipy)]ClO4 was prepared by the condensation of VOSO4·5H2O with ligands 1-phenyl-3-methyl-4-formyl-2-pyrazolin-5-one (PMFP) and 2,2'-bipyridyl (Bipy). The corresponding Schiff bases were prepared by the condensation of [VO(PMFP)(Bipy)]ClO4 with ethylenediamine, ethanolamine, and glycine. All the compounds have been characterized by elemental analysis, magnetic susceptibility, X-ray crystallography, conductometry measurement, 1H NMR, IR, ESR, electronic spectra, and mass spectrometry. Electronic spectra and magnetic susceptibility measurements indicate distorted octahedral stereochemistry of the oxovanadium(IV) complexes. Thermal stability, kinetic order, heat capacity, and activation energy of thermal degradation of these complexes were determined by TGA and DSC. The presence of one coordinate water molecule is suggested from the IR and TGA studies. Hamiltonian and bonding parameters were found from ESR spectra, indicating that the metal-ligand bonding is partial covalent. Antibacterial screening is reported for the ligand and complexes of oxovanadium(IV)

  15. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    International Nuclear Information System (INIS)

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy)32+/nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy)32+/nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy)32+/nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L-1 (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 μmol L-1) with R-value of 0.997. The relative standard deviation with 5 μmol L-1 concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications

  16. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Lin Mengshan [Department of Chemistry, Tamkang University, Tamsui 25137, Taiwan (China)], E-mail: mslin@mail.tku.edu.tw; Wang Junsheng; Lai Chienhung [Department of Chemistry, Tamkang University, Tamsui 25137, Taiwan (China)

    2008-11-01

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy){sub 3}{sup 2+}/nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy){sub 3}{sup 2+}/nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy){sub 3}{sup 2+}/nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L{sup -1} (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 {mu}mol L{sup -1}) with R-value of 0.997. The relative standard deviation with 5 {mu}mol L{sup -1} concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications.

  17. Electrochemiluminescent determination of nicotine based on tri(2,2'-bipyridyl) ruthenium (II) complex through flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Meng Shan; Wang, Jun Sheng; Lai, Chien Hung [Department of Chemistry, Tamkang University, Tamsui 25137 (China)

    2008-11-01

    This paper describes the electrogenerated chemiluminescence (ECL) processes of Ru(bpy){sub 3}{sup 2+}/nicotine system at ITO working electrode. An ECL-based method for rapid and sensitive detection of nicotine in phosphate buffer solution at pH 8.0 is established. Strong ECL emission was observed at a positive potential of 1.4 V vs. Ag/AgCl. A possible ECL mechanism is proposed for the Ru(bpy){sub 3}{sup 2+}/nicotine system, the oxidation product of nicotine at the electrode surface reacts with the 3+ state of ruthenium bipyridyl (2+) complex and form ruthenium complex exited state ions and thus releases photons. Effect of pH (medium/electrolyte), working potential, buffer composition, buffer concentration, reactant and co-reactant (nicotine) concentration, flow rate and loop size on the ECL spectrum of the Ru(bpy){sub 3}{sup 2+}/nicotine were studied. At the optimized experimental conditions, lower detection limit for nicotine was observed as 1.2 nmol L{sup -1} (S/N = 3). Linear relationship between ECL current and concentration of nicotine was observed (up to 100 {mu}mol L{sup -1}) with R-value of 0.997. The relative standard deviation with 5 {mu}mol L{sup -1} concentration of nicotine for 20 analyses was only 1.4%. A 94% recovery rate was observed in a real sample analysis without any complications/disturbance in measurement. Interferences of humid acid, camphor and SDS were not observed in their presence in the sample solution. The established procedure for nicotine quantification manifests fascinating results and can be suggested for further applications. (author)

  18. Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Wenshan; Lukens, Wayne W.; Zi, Guofu; Maron, Laurent; Walter, Marc D.

    2012-01-12

    Bipyridyl thorium metallocenes [5-1,2,4-(Me3C)3C5H2]2Th(bipy) (1) and [5-1,3-(Me3C)2C5H3]2Th(bipy) (2) have been investigated by magnetic susceptibility and computational studies. The magnetic susceptibility data reveal that 1 and 2 are not diamagnetic, but they behave as temperature independent paramagnets (TIPs). To rationalize this observation, density functional theory (DFT) and complete active space SCF (CASSCF) calculations have been undertaken, which indicated that Cp2Th(bipy) has indeed a Th(IV)(bipy2-) ground state (f0d0 2, S = 0), but the open-shell singlet (f0d1 1, S = 0) (almost degenerate with its triplet congener) is lying only 9.2 kcal/mol higher in energy. Complexes 1 and 2 react cleanly with Ph2CS to give [ 5-1,2,4-(Me3C)3C5H2]2Th[(bipy)(SCPh2)] (3) and [ 5-1,3-(Me3C)2C5H3]2Th[(bipy)(SCPh2)] (4), respectively, in quantitative conversions. Since no intermediates were observed experimentally, this reaction was also studied computationally. Coordination of Ph2CS to 2 in its S = 0 ground state is not possible, but Ph2CS can coordinate to 2 in its triplet state (S = 1) upon which a single electron transfer (SET) from the (bipy2-) fragment to Ph2CS followed by C-C coupling takes place.

  19. Quark Orbital Angular Momentum

    Science.gov (United States)

    Burkardt, Matthias

    2016-06-01

    Generalized parton distributions provide information on the distribution of quarks in impact parameter space. For transversely polarized nucleons, these impact parameter distributions are transversely distorted and this deviation from axial symmetry leads on average to a net transverse force from the spectators on the active quark in a DIS experiment. This force when acting along the whole trajectory of the active quark leads to transverse single-spin asymmetries. For a longitudinally polarized nucleon target, the transverse force implies a torque acting on the quark orbital angular momentum (OAM). The resulting change in OAM as the quark leaves the target equals the difference between the Jaffe-Manohar and Ji OAMs.

  20. Quark Orbital Angular Momentum

    Science.gov (United States)

    Burkardt, Matthias

    2016-03-01

    Generalized parton distributions provide information on the distribution of quarks in impact parameter space. For transversely polarized nucleons, these impact parameter distributions are transversely distorted and this deviation from axial symmetry leads on average to a net transverse force from the spectators on the active quark in a DIS experiment. This force when acting along the whole trajectory of the active quark leads to transverse single-spin asymmetries. For a longitudinally polarized nucleon target, the transverse force implies a torque acting on the quark orbital angular momentum (OAM). The resulting change in OAM as the quark leaves the target equals the difference between the Jaffe-Manohar and Ji OAMs.

  1. AngularJS directives

    CERN Document Server

    Vanston, Alex

    2013-01-01

    This book uses a practical, step-by-step approach, starting with how to build directives from the ground up before moving on to creating web applications comprised of multiple modules all working together to provide the best user experience possible.This book is intended for intermediate JavaScript developers who are looking to enhance their understanding of single-page web application development with a focus on AngularJS and the JavaScript MVC frameworks.It is expected that readers will understand basic JavaScript patterns and idioms and can recognize JSON formatted data.

  2. Structure and spectroscopic properties of ruthenium(II) bipyridyl N-benzoyl-N'-(1,10-phenanthrolin-5-Yl)-thiourea

    International Nuclear Information System (INIS)

    Ruthenium bipyridyl incorporating phenanthroline with thiourea molecules, [Ru(bpy)2(Phen-BT)](PF6)2], has been synthesized and characterized by spectroscopic and electrochemical techniques. The infrared spectra of the complex shows the characteristics stretching frequencies for N-H at 3646 and 3585 cm−1, ν(C-N)phen 1426 cm−1, ν(C=O) 1675 cm−1, ν(C=S) 1246 cm−1, ν(C-H)aromatic 3353-3086 cm−1, ν(C-N)aliphatic 1169-1026 cm−1, ν(C-H)bend 764 cm−1 and ν(PF6−)free 842 cm−1. The complex reveals two π→π* absorption bands at 237 (ε=26,302) and 286 nm (ε=36,848), which were assigned to the phenanthroline and bipyridyl moieties, respectively. A slightly broad and low energy band in the UV-vis spectrum at 450 nm (ε=7,209) of the complex was assigned to a MLCT transition. Besides, the complex also exhibits an emission band at 615 nm that arises from an excitation with a 440 nm light energy. The cyclic voltammetry of the complex shows an oxidation potential at +1.305 V vs. SCE that corresponds to the formal oxidation of Ru(II) to Ru(III)

  3. Orbital angular momentum microlaser

    Science.gov (United States)

    Miao, Pei; Zhang, Zhifeng; Sun, Jingbo; Walasik, Wiktor; Longhi, Stefano; Litchinitser, Natalia M.; Feng, Liang

    2016-07-01

    Structured light provides an additional degree of freedom for modern optics and practical applications. The effective generation of orbital angular momentum (OAM) lasing, especially at a micro- and nanoscale, could address the growing demand for information capacity. By exploiting the emerging non-Hermitian photonics design at an exceptional point, we demonstrate a microring laser producing a single-mode OAM vortex lasing with the ability to precisely define the topological charge of the OAM mode. The polarization associated with OAM lasing can be further manipulated on demand, creating a radially polarized vortex emission. Our OAM microlaser could find applications in the next generation of integrated optoelectronic devices for optical communications in both quantum and classical regimes.

  4. Orbital angular momentum microlaser.

    Science.gov (United States)

    Miao, Pei; Zhang, Zhifeng; Sun, Jingbo; Walasik, Wiktor; Longhi, Stefano; Litchinitser, Natalia M; Feng, Liang

    2016-07-29

    Structured light provides an additional degree of freedom for modern optics and practical applications. The effective generation of orbital angular momentum (OAM) lasing, especially at a micro- and nanoscale, could address the growing demand for information capacity. By exploiting the emerging non-Hermitian photonics design at an exceptional point, we demonstrate a microring laser producing a single-mode OAM vortex lasing with the ability to precisely define the topological charge of the OAM mode. The polarization associated with OAM lasing can be further manipulated on demand, creating a radially polarized vortex emission. Our OAM microlaser could find applications in the next generation of integrated optoelectronic devices for optical communications in both quantum and classical regimes. PMID:27471299

  5. On the relation between angular momentum and angular velocity

    Science.gov (United States)

    Silva, J. P.; Tavares, J. M.

    2007-01-01

    Students of mechanics usually have difficulties when they learn about the rotation of a rigid body. These difficulties are rooted in the relation between angular momentum and angular velocity, because these vectors are not parallel, and we need in general to utilize a rotating frame of reference or a time dependent inertia tensor. We discuss a series of problems that introduce both difficulties.

  6. Synthesis, characterization and crystal structure determination of Mn (II) ion based 1D polymer constructed from 2, 2′ bipyridyl and azide group, its thermal stability, magnetic properties and Hirshfeld surface analysis

    International Nuclear Information System (INIS)

    The 1-D polymeric complex (I) is having formula [Mn(2,2′-BP).(N3)2]n, which has been crystallized in distilled water and characterized by elemental analyses, FT-IR spectrum, powder X-ray diffraction analyses and single-crystal diffraction analysis. This polymer possesses 1D helical chains or coils where Mn–azide–Mn forms the base of the coil which is alternatively garlanded by rigid bi-pyridine rings, where coordinates are in anti-fashion. The Mn (II) ions in the repeating units are linked by two end-on azide groups which extend through the two end-to-end azide ligands to the next unit forming a 1-D polymeric chain. The present study suggests that the use of this rigid and neutral building block leads to give better arrangement of the polymeric motif with [010] chains in 2-c uninodal net. During investigation of strong or weak intermolecular interactions, X-ray diffraction analysis and Hirshfeld surface analysis give rise to comparable results but in Hirshfeld surface analysis, two-third times more results of close contacts are obtained. The fingerprint plots demonstrate that these weak non-bonding interactions are important for stabilizing the crystal packing. Magnetic properties of the complex (I) were analyzed on the basis of an alternating ferro- and antiferromagnetic Heisenberg chain of Mn (II) ions. The J-exchange parameters found are J1=64.3 K (45.3 cm−1), and J2=−75.7 K (−53.3 cm−1). Magnetic properties are discussed in comparison with those of other similar molecular magnets of [Mn(L–L)(N3)2]n type. - - Highlights: • Synthesized 1-D polymeric complex of Mn (II) ions with 2, 2′ bipyridyl and azide group. • X-ray data of complex (I) is in a good agreement with TGA and other spectroscopic techniques. • DFT calculations were done and compared with the parameter of experimental and theoretical data. • Intermolecular interactions calculated by Hirshfeld surface analysis compared with X-ray data

  7. Handling ligands with Coot

    OpenAIRE

    Debreczeni, Judit É.; Emsley, Paul

    2012-01-01

    Coot is a molecular-graphics application primarily aimed to assist in model building and validation of biological macromolecules. Recently, tools have been added to work with small molecules. The newly incorporated tools for the manipulation and validation of ligands include interaction with PRODRG, subgraph isomorphism-based tools, representation of ligand chemistry, ligand fitting and analysis, and are described here.

  8. Angular momentum in subbarrier fusion

    International Nuclear Information System (INIS)

    We have measured the ratio of the isomer to ground-state yields of 137Ce produced in the fusion reactions 128Te(12C,3n), 133Cs(7Li,3n), 136Ba(3He,2n), 136Ba(4He,3n), and 137Ba(3He,3n), from energies above the Coulomb barrier to energies typically 20--30% below the barrier by observing the delayed x- and γ-ray emission. We deduce the average angular momentum, , from the measured isomer ratios with a statistical model. In the first three reactions we observe that the values of exhibit the behavior predicted for low energies and the expected variation with the reduced mass of the entrance channel. We analyze these data and the associated cross sections with a barrier penetration model that includes the coupling of inelastic channels. Measurements of average angular momenta and cross sections made on other systems using the γ-multiplicity and fission-fragment angular correlation techniques are then analyzed in a similar way with this model. The discrepancies with theory for the γ-multiplicity data show correlations in cross section and angular momentum that suggest a valid model can be found. The measurements of angular momentum using the fission fragment angular correlation technique, however, do not appear reconcilable with the energy dependence of the cross sections. This systematic overview suggests, in particular, that our current understanding of the relationship of angular momentum and anisotropy in fission fragment angular correlations is incomplete. 26 refs

  9. Synthesis of New Ruthenium(Ⅱ)Bipyridyl Complexes and Studies on Their Photophysical and Photoelectrochemical Properties

    Institute of Scientific and Technical Information of China (English)

    宋林青; 刘普会; 王雪松; 侯原军; 张宝文; 曹怡; 李维盈; 张敬波; 肖绪瑞; 林原

    2003-01-01

    Two new mixed-ligand ruthenium(Ⅱ) complexes,Ru(dcbpy)-(LL)NCS)2[where dcbpy=4,4'-dicarboxyl-2,2''-bipyridine,LL=4,4'-bis(N-methyl-anilinomethyl)-2,2''-bipyridine(2)],were synthesized,and the tphotophysical properties of these complexes were studied.The metal-to-ligand charge transfer (MLCT) transitions of these complexes exhibited solvatochromic effect due to the existence of NCS ligands.The MLCT energies also strongly depend on the pH values of the solutions because of protonation and deprotonation of the carboxyl groups.The pKa values of the ground state,4.0 for 1 and 3.8 for 2,were obtained from the titration curves.The photoelectrochemical properties of 1 and 2 as sensitizers in sandwich-type solar cells have been studied.Complex 1 exhibited better photoelectrochemical behavior than complex 2 as expected.It was proved that the design of mixed-ligand complex by introducing electron donating group in one of the ligands should be a promising approach.

  10. Antioxidant activities of nano-bubble hydrogen-dissolved water assessed by ESR and 2,2′-bipyridyl methods

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Shinya [Laboratory of Cell-Death Control BioTechnology, Faculty of Life and Environmental Sciences, Prefectural University of Hiroshima, Nanatsuka 562, Shobara, Hiroshima 727-0023 (Japan); Radio Isotope Facilities for Medical Science, Life Science Research Center, Mie University, Edobashi 2-174, Tsu, Mie 514-8507 (Japan); Matsuoka, Daigo [− 600 mV Co., Ltd. Matsuhama-cho 2-4-1, Fukuyama, Hiroshima 720-0802 (Japan); Miwa, Nobuhiko, E-mail: miwa@butsuryo.ac.jp [Laboratory of Cell-Death Control BioTechnology, Faculty of Life and Environmental Sciences, Prefectural University of Hiroshima, Nanatsuka 562, Shobara, Hiroshima 727-0023 (Japan); Department of Radiological Technology, Faculty of Health Sciences, Butsuryo College of Osaka, Otorikitamachi 3-33, Nishi-ku, Sakai, Osaka 593-8328 (Japan)

    2015-08-01

    We prepared nano-bubble hydrogen-dissolved water (nano-H water) which contained hydrogen nano-bubbles of < 717-nm diameter for 54% of total bubbles. In the DMPO-spin trap electron spin resonance (ESR) method, the DMPO-OH:MnO ratio, being attributed to amounts of hydroxyl radicals (·OH), was 2.78 for pure water (dissolved hydrogen [DH] ≤ 0.01 ppm, oxidation-reduction potential [ORP] = + 324 mV), 2.73 for tap water (0.01 ppm, + 286 mV), 2.93 for commercially available hydrogen water (0.075 ppm, + 49 mV), and 2.66 for manufactured hydrogen water (0.788 ppm, − 614 mV), whereas the nano-H water (0.678 ppm, − 644 mV) exhibited 2.05, showing the superiority of nano-H water to other types of hydrogen water in terms of ·OH-scavenging activity. Then, the reduction activity of nano-H water was assessed spectrophotometrically by the 2,2′-bipyridyl method. Differential absorbance at 530 nm was in the order: 0.018 for pure water, 0.055 for tap water, 0.079 for nano-H water, 0.085 for commercially available hydrogen water, and 0.090 for manufactured hydrogen water, indicating a prominent reduction activity of hydrogen water and nano-H water against oxidation in ascorbate-coupled ferric ion–bipyridyl reaction. Thus, nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level, indicating the more marked importance of nano-bubbles rather than the concentration of hydrogen in terms of ·OH-scavenging. - Highlights: • We assessed the antioxidant activity of nano-bubble hydrogen-dissolved water (nano-H water). • Nano-H water exhibited superior ·OH-scavenging activity in DMPO-spin trap ESR. • A reduction ability of nano-H water was shown in 2,2′-bipyridyl reaction. • Nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level. • Results indicated the importance of nano-bubbles rather than the concentration of hydrogen.

  11. Angular signal radiography.

    Science.gov (United States)

    Li, Panyun; Zhang, Kai; Bao, Yuan; Ren, Yuqi; Ju, Zaiqiang; Wang, Yan; He, Qili; Zhu, Zhongzhu; Huang, Wanxia; Yuan, Qingxi; Zhu, Peiping

    2016-03-21

    Microscopy techniques using visible photons, x-rays, neutrons, and electrons have made remarkable impact in many scientific disciplines. The microscopic data can often be expressed as the convolution of the spatial distribution of certain properties of the specimens and the inherent response function of the imaging system. The x-ray grating interferometer (XGI), which is sensitive to the deviation angle of the incoming x-rays, has attracted significant attention in the past years due to its capability in achieving x-ray phase contrast imaging with low brilliance source. However, the comprehensive and analytical theoretical framework is yet to be presented. Herein, we propose a theoretical framework termed angular signal radiography (ASR) to describe the imaging process of the XGI system in a classical, comprehensive and analytical manner. We demonstrated, by means of theoretical deduction and synchrotron based experiments, that the spatial distribution of specimens' physical properties, including absorption, refraction and scattering, can be extracted by ASR in XGI. Implementation of ASR in XGI offers advantages such as simplified phase retrieval algorithm, reduced overall radiation dose, and improved image acquisition speed. These advantages, as well as the limitations of the proposed method, are systematically investigated in this paper. PMID:27136780

  12. On the discriminating and stability increasing properties of Alizarin maroon in mixed-ligand complexes of Yttrium(3)

    International Nuclear Information System (INIS)

    The stability constants of the yttrium(3) mixed ligand complexes (1:1:1) containing alizarin maroon (azm) and as a second ligand salicylic acid (sa), 5-sulphosalicylic acid (ssa), 5-nitrosalicylic acid (nsa), 2,2'-bipyridyl (bipy) and 1,10-phenanthroline (phen) have been determined potentiometrically in 20% (v/v) ethanol-water medium (I 100 mmoldm-3 NaClO4, 25±0,10C). The complexation equilibria of the different biligand systems were demonstrated. All of these mixed-ligand complexes are considerably more stable than expected from purely statistical reasons. The results obtained were discussed in relation to the nature of the secondary ligands involved. For the equilibrium, Y(azm)2+Y(L)2 rightleftdblarrow 2Y(azm)(L), the following constants, log X, were determined: Y(azm)(sa) 3,11 (0,46); Y(azm)(ssa) 2,76 (0,33); Y(azm)(nsa) 3,02 (0,48); Y(azm)(bipy) 3,96 (0,99); Y(azm)(phen) 4,33 (1,07). The constants given in parentheses correspond to Δlog KY [log KY(azm)Y(azm)(L)-log KYY(L)]. (Author)

  13. Structure and spectroscopic properties of ruthenium(II) bipyridyl N-benzoyl-N'-(1,10-phenanthrolin-5-Yl)-thiourea

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Siew San [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Kassim, Mohammad B. [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2015-09-25

    Ruthenium bipyridyl incorporating phenanthroline with thiourea molecules, [Ru(bpy){sub 2}(Phen-BT)](PF{sub 6}){sub 2}], has been synthesized and characterized by spectroscopic and electrochemical techniques. The infrared spectra of the complex shows the characteristics stretching frequencies for N-H at 3646 and 3585 cm{sup −1}, ν(C-N){sub phen} 1426 cm{sup −1}, ν(C=O) 1675 cm{sup −1}, ν(C=S) 1246 cm{sup −1}, ν(C-H){sub aromatic} 3353-3086 cm{sup −1}, ν(C-N){sub aliphatic} 1169-1026 cm{sup −1}, ν(C-H){sub bend} 764 cm{sup −1} and ν(PF{sub 6}{sup −}){sub free} 842 cm{sup −1}. The complex reveals two π→π* absorption bands at 237 (ε=26,302) and 286 nm (ε=36,848), which were assigned to the phenanthroline and bipyridyl moieties, respectively. A slightly broad and low energy band in the UV-vis spectrum at 450 nm (ε=7,209) of the complex was assigned to a MLCT transition. Besides, the complex also exhibits an emission band at 615 nm that arises from an excitation with a 440 nm light energy. The cyclic voltammetry of the complex shows an oxidation potential at +1.305 V vs. SCE that corresponds to the formal oxidation of Ru(II) to Ru(III)

  14. Functionalisation of bolaamphiphiles with mononuclear bis(2,2 '-bipyridyl)ruthenium(II) complexes for application in self assembled monolayers

    NARCIS (Netherlands)

    Killeen, JS; Browne, WR; Skupin, M; Fuhrhop, JH; Vos, JG

    2003-01-01

    A novel ruthenium(II) polypyridyl complex connected covalently to a bolaamphiphile, containing amide linkages to provide rigidity via hydrogen bonding in the monolayer, has been prepared. The ruthenium( II) complexes of this ligand and of the intermediates in the synthesis were prepared by modi. cat

  15. AngularJS testing cookbook

    CERN Document Server

    Bailey, Simon

    2015-01-01

    This book is intended for developers who have an understanding of the basic principles behind both AngularJS and test-driven development. You, as a developer, are interested in eliminating the fear related to either introducing tests to an existing codebase or starting out testing on a fresh AngularJS application. If you're a team leader or part of a QA team with the responsibility of ensuring full test coverage of an application, then this book is ideal for you to comprehend the full testing scope required by your developers. Whether you're new to or are well versed with AngularJS, this book

  16. Metal-ligand cooperation.

    Science.gov (United States)

    Khusnutdinova, Julia R; Milstein, David

    2015-10-12

    Metal-ligand cooperation (MLC) has become an important concept in catalysis by transition metal complexes both in synthetic and biological systems. MLC implies that both the metal and the ligand are directly involved in bond activation processes, by contrast to "classical" transition metal catalysis where the ligand (e.g. phosphine) acts as a spectator, while all key transformations occur at the metal center. In this Review, we will discuss examples of MLC in which 1) both the metal and the ligand are chemically modified during bond activation and 2) bond activation results in immediate changes in the 1st coordination sphere involving the cooperating ligand, even if the reactive center at the ligand is not directly bound to the metal (e.g. via tautomerization). The role of MLC in enabling effective catalysis as well as in catalyst deactivation reactions will be discussed. PMID:26436516

  17. The integration of angular velocity

    OpenAIRE

    Boyle, Michael

    2016-01-01

    A common problem in physics and engineering is determination of the orientation of an object given its angular velocity. When the direction of the angular velocity changes in time, this is a nontrivial problem involving coupled differential equations. Several possible approaches are examined, along with various improvements over previous efforts. These are then evaluated numerically by comparison to a complicated but analytically known rotation that is motivated by the important astrophysical...

  18. Achromatic orbital angular momentum generator

    OpenAIRE

    Bouchard, Frédéric; Mand, Harjaspreet; Mirhosseini, Mohammad; Karimi, Ebrahim; Boyd, Robert W

    2014-01-01

    We describe a novel approach for generating light beams that carry orbital angular momentum (OAM) by means of total internal reflection in an isotropic medium. A continuous space-varying cylindrically symmetric reflector, in the form of \\textit{two glued hollow axicons}, is used to introduce a nonuniform rotation of polarisation into a linearly polarised input beam. This device acts as a full spin-to-orbital angular momentum convertor. It functions by switching the helicity of the incoming be...

  19. MBL Experiment in Angular Momentum

    Science.gov (United States)

    Gluck, Paul

    2002-04-01

    Among the series of beautiful take-home experiments designed by A.P. French and J.G. King for MIT students, the one on angular momentum studies the loss and conservation of angular momentum using a small dc motor as generator. Here we describe a version of the experiment that increases its accuracy, enables students to perform detailed rotational dynamics calculations, and sharpens the ability to isolate the region where the collision occurs.

  20. Syntheses, structures and properties of three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jiancai; Zhang, Yudong; Shang, Sensen; Li, Yanzhou; Chen, Lijuan, E-mail: ljchen@henu.edu.cn; Zhao, Junwei, E-mail: zhaojunwei@henu.edu.cn

    2015-01-15

    Three new metal–organic complexes Cu[Hbpdc]{sub 2} (1), [Ni(bpdc)(H{sub 2}O)]·H{sub 2}O (2) and [Ni(H{sub 2}bpdc)(H{sub 2}O){sub 2}]SO{sub 4} (3) (H{sub 2}bpdc=2,2′-bipyridyl-5,5′-dicarboxylic acid) have been hydrothermally prepared and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 is a 3-D supramolecular architecture formed by hydrogen bonding interactions between carboxyl O atoms and strong face-to-face π⋯π stacking interactions between bipyridyl rings of Hbpdc{sup −} ligands, 2 exhibits an intriguing 2-D sheet constructed from [Ni(bpdc)(H{sub 2}O)] units and 3 displays an infinite 1-D chain built by ([Ni(H{sub 2}bpdc)(H{sub 2}O){sub 2}]{sup 2+}) fragments through SO{sub 4}{sup 2−}. Moreover, thermogravimetric (TG) and derivative thermogravimetric (DTG) analyses of 3 have been conducted and the TG curve shows two-stage weight loss between 300 and 950 K and the corresponding apparent activation energies are calculated by Ozawa–Flynn–Wall (OFW) method and Friedman method. The most probable kinetic model function of the dehydration reaction of 3 has been estimated by Coats–Redfern integral method and Achar–Bridly–Sharp differential method. - Graphical abstract: Three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands were synthesized and the thermal decomposition kinetics were investigated. - Highlights: • Metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands. • 3-D supramolecular architecture. • Thermal decomposition kinetics.

  1. Factors influencing perceived angular velocity

    Science.gov (United States)

    Kaiser, Mary K.; Calderone, Jack B.

    1991-01-01

    Angular velocity perception is examined for rotations both in depth and in the image plane and the influence of several object properties on this motion parameter is explored. Two major object properties are considered, namely, texture density which determines the rate of edge transitions for rotations in depth, i.e., the number of texture elements that pass an object's boundary per unit of time, and object size which determines the tangential linear velocities and 2D image velocities of texture elements for a given angular velocity. Results of experiments show that edge-transition rate biased angular velocity estimates only when edges were highly salient. Element velocities had an impact on perceived angular velocity; this bias was associated with 2D image velocity rather than 3D tangential velocity. Despite these biases judgements were most strongly determined by the true angular velocity. Sensitivity to this higher order motion parameter appeared to be good for rotations both in depth (y-axis) and parallel to the line of sight (z-axis).

  2. Achromatic orbital angular momentum generator

    CERN Document Server

    Bouchard, Frédéric; Mirhosseini, Mohammad; Karimi, Ebrahim; Boyd, Robert W

    2014-01-01

    We describe a novel approach for generating light beams that carry orbital angular momentum (OAM) by means of total internal reflection in an isotropic medium. A continuous space-varying cylindrically symmetric reflector, in the form of \\textit{two glued hollow axicons}, is used to introduce a nonuniform rotation of polarisation into a linearly polarised input beam. This device acts as a full spin-to-orbital angular momentum convertor. It functions by switching the helicity of the incoming beam's polarisation, and by conservation of total angular momentum thereby generates a well-defined value of OAM. Our device is broadband, since the phase shift due to total internal reflection is nearly independent of wavelength. We verify the broad-band behaviour by measuring the conversion efficiency of the device for three different wavelengths corresponding to the RGB colours, red, green and blue. An average conversion efficiency of $95\\%$ for these three different wavelengths is observed. %, which confirms its wavelen...

  3. Instant AngularJS starter

    CERN Document Server

    Menard, Dan

    2013-01-01

    Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. This book is written in an easytoread style, with a strong emphasis on realworld, practical examples. Stepbystep explanations are provided for performing important tasks.This book is for web developers familiar with JavascriptIt doesn't cover the history of AngularJS, and it's not a pitch to convince you that AngularJS is the best framework on the entire web. It's a guide to help you learn everything you need to know about AngularJS in as few pa

  4. Non-Colinearity of Angular Velocity and Angular Momentum

    Science.gov (United States)

    Burr, A. F.

    1974-01-01

    Discusses the principles, construction, and operation of an apparatus which serves to demonstrate the non-colinearity of the angular velocity and momentum vectors as well as the inertial tensors. Applications of the apparatus to teaching of advanced undergraduate mechanics courses are recommended. (CC)

  5. Quantum theory of angular momentum

    International Nuclear Information System (INIS)

    This monograph pertains to the angular momentum coupling and recoupling coefficients and their relation to generalized hypergeometric functions; their q-generalization; their polynomial zeros; their relation to orthogonal polynomials; and their numerical computation. The book builds on standard textbook material on Angular Momentum Theory and leads the reader to the recent developments in the selected topics. Fortran programs for the computation of the 3-j, 6-j and 9-j coefficients are included for use by atomic, molecular and nuclear physicists/chemists. (orig.)

  6. Ligand modeling and design

    Energy Technology Data Exchange (ETDEWEB)

    Hay, B.P. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-10-01

    The purpose of this work is to develop and implement a molecular design basis for selecting organic ligands that would be used in the cost-effective removal of specific radionuclides from nuclear waste streams. Organic ligands with metal ion specificity are critical components in the development of solvent extraction and ion exchange processes that are highly selective for targeted radionuclides. The traditional approach to the development of such ligands involves lengthy programs of organic synthesis and testing, which in the absence of reliable methods for screening compounds before synthesis, results in wasted research effort. The author`s approach breaks down and simplifies this costly process with the aid of computer-based molecular modeling techniques. Commercial software for organic molecular modeling is being configured to examine the interactions between organic ligands and metal ions, yielding an inexpensive, commercially or readily available computational tool that can be used to predict the structures and energies of ligand-metal complexes. Users will be able to correlate the large body of existing experimental data on structure, solution binding affinity, and metal ion selectivity to develop structural design criteria. These criteria will provide a basis for selecting ligands that can be implemented in separations technologies through collaboration with other DOE national laboratories and private industry. The initial focus will be to select ether-based ligands that can be applied to the recovery and concentration of the alkali and alkaline earth metal ions including cesium, strontium, and radium.

  7. Turbodrill rod angular velocity indicator

    Energy Technology Data Exchange (ETDEWEB)

    Rogachev, O.K.; Belozerova, L.P.; Konenkov, A.K.

    1984-01-01

    This paper outlines shortcomings of existing types of telemetry systems which resulted in production of the IChT-1 unit. Unit is intended for control of angular velocity of serially produced turbodrill rods, during drilling of wells up to 5000 m deep, and bottomhole temperatures to 100C. The paper provides a detailed description and diagrams for installing this unit.

  8. Fission at high angular momenta

    International Nuclear Information System (INIS)

    By studies on the system 40Ar+165Ho by means of selected measuring methods which made a differential selection of certain angular momentum ranges and by this a discrimination between ''fast fission'' and compound-nucleus fission possible the validity of fundamental predictions of the model of the ''fast fission'' hitherto experimentally no yet confirmed was studied: 1) At the turning point of the trajectory for ''fast fission'' calculated by Gregoire the corresponding shape of which must be responsible for the angular distribution the centers of the two fragments must be separated by about 11 fm. 2) The widths of the mass distributions after ''fast fission'' and compound-nucleus fission must be different by a factor 2. The measurements of the angular dependence showed that both prediction cannot be simultaneously brought into accordance with the experimental results. The results of coincidence measurements between fission fragments and alpha particles confirmed the assumption mentioned under topic 2. The analysis of the angular dependence then yielded for the shape of the nuclear complex leading to ''fast fission'' a more compact shape than that indicated by Gregoire, namely with a distance of the fragments of about 7 fm. (orig.)

  9. Ligand modeling and design

    Energy Technology Data Exchange (ETDEWEB)

    Hay, B. [Pacific Northwest Lab., Richland, WA (United States)

    1996-10-01

    The purpose of this work is to develop and implement a molecular design basis for selecting organic ligands that would be used tin applications for the cost-effective removal of specific radionuclides from nuclear waste streams.

  10. Inverse cascades of angular momentum

    International Nuclear Information System (INIS)

    Most theoretical and computational studies of turbulence in Navier-Stokes fluids and/or guiding-centre plasmas have been carried out in the presence of spatially periodic boundary conditions. In view of the frequently reproduced result that two-dimensional and/or MHD decaying turbulence leads to structures comparable in length scae to a box dimension, it is natural to ask if periodic boundary conditions are an adequate representation of any physical situation. Here, we study, computationally, the decay of two-dimensional turbulence in a Navier-Stokes fluid or guiding-centre plasma in the presence of circular no-slip rigid walls. The method is wholly spectral, and relies on a Galerkin approximation by a set of functions that obey two boundary conditions at the wall radius (analogues of the Chandrasekhar-Reid functions). It is possible to explore Reynolds numbers up to the order of 1250, based on an RMS velocity and a box radius. It is found that decaying turbulence is altered significantly by the no-slip boundaries. First, strong boundary layers serve as sources of vorticity and enstrophy and enhance the early-time energy decay rate, for a given Reynolds number, well above the periodic boundary condition values. More importantly, angular momentum turns out to be an even more slowly decaying ideal invariant than energy, and to a considerable extent governs the dynamics of the decay. Angular momentum must be taken into account, for example, in order to achieve quantitative agreement with the prediction of maximum entropy, or 'most probable', states. These are predictions of conditions that are established after several eddy turnover times but before the energy has decayed away. Angular momentum will cascade to lower azimuthal mode numbers, even if absent there initially, and the angular momentum modal spectrum is eventually dominated by the lowest mode available. When no initial angular momentum is present, no behaviour that suggests the likelihood of inverse cascades

  11. Investigation of complexes of zinc (2) and cadmium (2) di-n-butyldithiocarbamates with 2,2'-bipyridyl

    International Nuclear Information System (INIS)

    New different-ligand complexes Cd(S2CN(C4H)9)2)2(2,2'-Bipy) is synthesized. X-ray diffraction investigation of polycrystals is done and crystal structure is determined. Crystallographic data of C28H44CdN4S4 are: a=28.716(4), b=6.868(6), c=17.188(2) A, sp. gr. Pcca, V=3380.2(7) A3, Z=4, dcal=1.335 g/cm3. Structure is built of monomeric molecules cadmium atom in which has distorted octahedral surrounding. By the method of diffractometry of polycrystals degree of isomeric structure of complex investigated with known Zn(S2CN(C4H9)2)2(2,2'-Bipy) one is found out. Crystal chemical review of crystal structures on dialkyldithiocarbamates of metals are done and isostructural pairs of complexes with Zn and Cd are detected

  12. Electric response in the antiferroelectric crystal of 4,4′-di-t-butyl-2,2′-bipyridyl with chloranilic acid

    International Nuclear Information System (INIS)

    Highlights: • The semiconducting properties of the crystals were disclosed in the organic complex. • Dielectric relaxation and dc conductivity were investigated. • Activation energy for the thermally activated processes of the σdc was estimated. • The effect of hydrogen bonds on the mechanism of the phase transition and the electric properties of the crystal was discussed. - Abstract: The electric response was analyzed in the vicinity of the structural phase transition at 412 K in the single crystals of 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) with 4,4′-di-t-butyl-2,2′-bipyridyl (dtBBP). The dielectric permittivity of the complex measured along the b direction between 300 and 440 K and at frequencies ranging from 500 Hz to 2 MHz indicates two phenomena. At low frequencies, dielectric losses are ascribed to the electric conductivity of the crystal, while at high frequencies, to the dielectric relaxation described by means of the Cole–Cole relationship. The parameters of the dielectric response: the relaxation time, τ, the dielectric increment, εο − ε∞, and the distribution parameter of the relaxation time, α, were estimated and analyzed. The low-temperature structure of the crystals indicates the antiferroelectric arrangement of the supramolecular hydrogen bonds. The dielectric results also presented for the deuterated crystals of dtBBP·CLA proved that the dynamics of protons in the hydrogen bonds are responsible for the mechanism of phase transition

  13. Influence of different ruthenium(II) bipyridyl complex on the photocatalytic H{sub 2} evolution over TiO{sub 2} nanoparticles with mesostructures

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Tianyou [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China); Hubei Key Laboratory for Catalysis and Material Science, College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074 (China); Ke, Dingning; Cai, Ping; Dai, Ke; Ma, Liang; Zan, Ling [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China)

    2008-05-15

    H{sub 2} production over dye-sensitized Pt/TiO{sub 2} nanoparticles with mesostructures (m-TiO{sub 2}) under visible light ({lambda} > 420 nm) was investigated by using methanol as electron donors. Experimental results indicate that three types of ruthenium(II) bipyridyl complex dyes (one binuclear Ru, two mononuclear Ru), which can be attached to Pt/m-TiO{sub 2} with different linkage modes, show different photosensitization effects due to their different coordination circumstances and physicochemical properties. The dye tightly linked with m-TiO{sub 2} has better durability but the lowest H{sub 2} evolution efficiency, whereas the loosely attached dyes possess higher H{sub 2} evolution efficiency and preferable durability. It seems that the dynamic equilibrium between the linkage of the ground state dye with TiO{sub 2} and the divorce of the oxidization state dye from the surfaces plays a crucial role in the photochemical behavior during the photocatalyst sensitization process. It is helpful to improve the H{sub 2} evolution efficiency by enhancing the electron injection and hindering the backward transfer. The binuclear Ru(II) dye shows a better photosensitization in comparison with mononuclear Ru(II) dyes due to its large molecular area, conjugation system, and ''antenna effect'', which, in turn, improve the visible light harvesting and electron transfer between the dye molecules and TiO{sub 2}. (author)

  14. Palladium(II/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water

    Directory of Open Access Journals (Sweden)

    Fu-Yu Tsai

    2010-01-01

    Full Text Available A water-soluble and air-stable Pd(NH32Cl2/cationic 2,2’-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu3N as a base. The reaction was conducted at 140 °C in a sealed tube in air with a catalyst loading as low as 0.0001 mol % for the coupling of activated aryl iodides with butyl and ethyl acrylates, providing the corresponding products in good to excellent yields with very high turnover numbers. In the case of styrene, Mizoroki-Heck coupling products were obtained in good to high yields by using a greater catalyst loading (1 mol % and TBAB as a phase-transfer agent. After extraction, the residual aqueous solution could be reused several times with only a slight decrease in its activity, making the Mizoroki-Heck reaction “greener”.

  15. Flow injection chemiluminescence determination of cephalosporins in pharmaceutical preparations using tris (2,2'-bipyridyl) ruthenium (II)-potassium permanganate system

    International Nuclear Information System (INIS)

    A flow injection (FI) method using the tris(2,2'-bipyridyl) ruthenium(II) [Ru(bpy)32+]-potassium permanganate chemiluminescence(CL) was developed for the rapid and sensitive determination of cephalosporins such as cefoxitin, cefazolin, cephalexin, cefadroxil, cefaclor and cefoperazone. The method is based on the CL reaction of cephalosporins and Ru(bpy)32+ with potassium permanganate in the presence of perchloric acid, catalyzed by Mn(II). Under the optimum conditions, the calibration curves are linear over the range 0.10-12.0 μg ml-1 for cefoxitin, 0.10-10.0 μg ml-1 for cefoperazone and 0.10-15.0 μg ml-1 for cefazolin, cephalexin, cefadroxil, and cefaclor, respectively. The limits of detection (3σ) are 0.03 μg ml-1 for cefoxitin and cefadroxil, 0.06 μg ml-1 for cefoperazone and 0.08 μg ml-1 for cefazolin, cephalexin and cefaclor, respectively. The method was successfully applied to the determination of cefoxitin, cefazolin, cephalexin and cefadroxil in pharmaceutical formulations with a sample throughput of 90 h-1. There were no interference effects from some common excipients used in pharmaceutical preparations

  16. Plate tectonics conserves angular momentum

    Directory of Open Access Journals (Sweden)

    C. Bowin

    2009-03-01

    Full Text Available A new combined understanding of plate tectonics, Earth internal structure, and the role of impulse in deformation of the Earth's crust is presented. Plate accelerations and decelerations have been revealed by iterative filtering of the quaternion history for the Euler poles that define absolute plate motion history for the past 68 million years, and provide an unprecedented precision for plate angular rotation variations with time at 2-million year intervals. Stage poles represent the angular rotation of a plate's motion between adjacent Euler poles, and from which the maximum velocity vector for a plate can be determined. The consistent maximum velocity variations, in turn, yield consistent estimates of plate accelerations and decelerations. The fact that the Pacific plate was shown to accelerate and decelerate, implied that conservation of plate tectonic angular momentum must be globally conserved, and that is confirmed by the results shown here (total angular momentum ~1.4 E+27 kgm2s−1. Accordingly, if a plate decelerates, other plates must increase their angular momentums to compensate. In addition, the azimuth of the maximum velocity vectors yields clues as to why the "bend" in the Emperor-Hawaiian seamount trend occurred near 46 Myr. This report summarizes processing results for 12 of the 14 major tectonic plates of the Earth (except for the Juan de Fuca and Philippine plates. Plate accelerations support the contention that plate tectonics is a product of torques that most likely are sustained by the sinking of positive density anomalies due to phase changes in subducted gabbroic lithosphere at depth in the upper lower mantle (above 1200 km depth. The tectonic plates are pulled along by the sinking of these positive mass anomalies, rather than moving at near constant velocity on the crests of convection cells driven by rising heat. These results imply that spreading centers are primarily passive reactive

  17. Orbital angular momentum in phase space

    OpenAIRE

    Rigas, I.; Sanchez-Soto, L. L.; Klimov, A. B.; Rehacek, J.; Hradil, Z.

    2010-01-01

    A comprehensive theory of the Weyl-Wigner formalism for the canonical pair angle-angular momentum is presented. Special attention is paid to the problems linked to rotational periodicity and angular-momentum discreteness.

  18. AngularJS test-driven development

    CERN Document Server

    Chaplin, Tim

    2015-01-01

    This book is for developers who want to learn about AngularJS development by applying testing techniques. You are assumed to have a basic knowledge and understanding of HTML, JavaScript, and AngularJS.

  19. Phonons with orbital angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Ayub, M. K. [Theoretical Plasma Physics Division, PINSTECH, P. O. Nilore, Islamabad (Pakistan); National Centre for Physics, Shahdra Valley Road, Quaid-i-Azam University Campus, Islamabad 44000 (Pakistan); Ali, S. [National Centre for Physics, Shahdra Valley Road, Quaid-i-Azam University Campus, Islamabad 44000 (Pakistan); Mendonca, J. T. [IPFN, Instituto Superior Tecnico, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal)

    2011-10-15

    Ion accoustic waves or phonon modes are studied with orbital angular momentum (OAM) in an unmagnetized collissionless uniform plasma, whose constituents are the Boltzmann electrons and inertial ions. For this purpose, we have employed the fluid equations to obtain a paraxial equation in terms of ion density perturbations and discussed its Gaussian beam and Laguerre-Gauss (LG) beam solutions. Furthermore, an approximate solution for the electrostatic potential problem is presented, allowing to express the components of the electric field in terms of LG potential perturbations. The energy flux due to phonons is also calculated and the corresponding OAM is derived. Numerically, it is shown that the parameters such as azimuthal angle, radial and angular mode numbers, and beam waist, strongly modify the profiles of the phonon LG potential. The present results should be helpful in understanding the phonon mode excitations produced by Brillouin backscattering of laser beams in a uniform plasma.

  20. Phonons with orbital angular momentum

    International Nuclear Information System (INIS)

    Ion accoustic waves or phonon modes are studied with orbital angular momentum (OAM) in an unmagnetized collissionless uniform plasma, whose constituents are the Boltzmann electrons and inertial ions. For this purpose, we have employed the fluid equations to obtain a paraxial equation in terms of ion density perturbations and discussed its Gaussian beam and Laguerre-Gauss (LG) beam solutions. Furthermore, an approximate solution for the electrostatic potential problem is presented, allowing to express the components of the electric field in terms of LG potential perturbations. The energy flux due to phonons is also calculated and the corresponding OAM is derived. Numerically, it is shown that the parameters such as azimuthal angle, radial and angular mode numbers, and beam waist, strongly modify the profiles of the phonon LG potential. The present results should be helpful in understanding the phonon mode excitations produced by Brillouin backscattering of laser beams in a uniform plasma.

  1. Angular momentum in QGP holography

    Directory of Open Access Journals (Sweden)

    Brett McInnes

    2014-10-01

    Full Text Available The quark chemical potential is one of the fundamental parameters describing the quark–gluon plasma produced by sufficiently energetic heavy-ion collisions. It is not large at the extremely high temperatures probed by the LHC, but it plays a key role in discussions of the beam energy scan programmes at the RHIC and other facilities. On the other hand, collisions at such energies typically (that is, in peripheral collisions give rise to very high values of the angular momentum density. Here we explain that holographic estimates of the quark chemical potential of a rotating sample of plasma can be very considerably improved by taking the angular momentum into account.

  2. Angular distribution of coherent bremsstrahlung

    International Nuclear Information System (INIS)

    The angular distribution of the linearly polarised photon beam produced by coherent bremsstrahlung from an aligned diamond radiator has been measured at the MAMI A2 tagged photon facility. The measurements were made with a prototype position sensitive photon detector which utilises the pair production process and a double sided silicon strip detector. This polarised photon beam is used for nuclear and hadronic experiments and in their analysis the polarisation is obtained from a calculation, which matches the experimental intensity spectrum. As the polarisation is related to the photon beam angular distribution, the present measurements can be used to test this calculation. The overall agreement is found to be good although there are some regions where significant discrepancies exist.

  3. The integration of angular velocity

    CERN Document Server

    Boyle, Michael

    2016-01-01

    A common problem in physics and engineering is determination of the orientation of an object given its angular velocity. When the direction of the angular velocity changes in time, this is a nontrivial problem involving coupled differential equations. Several possible approaches are examined, along with various improvements over previous efforts. These are then evaluated numerically by comparison to a complicated but analytically known rotation that is motivated by the important astrophysical problem of precessing black-hole binaries. It is shown that a straightforward solution directly using quaternions is most efficient and accurate, and that the norm of the quaternion is irrelevant. Integration of the generator of the rotation can also be made roughly as efficient as integration of the rotation. Both methods will typically be twice as efficient naive vector- or matrix-based methods. Implementation by means of standard general-purpose numerical integrators is stable and efficient, so that such problems can ...

  4. On Dunkl angular momenta algebra

    Science.gov (United States)

    Feigin, Misha; Hakobyan, Tigran

    2015-11-01

    We consider the quantum angular momentum generators, deformed by means of the Dunkl operators. Together with the reflection operators they generate a subalgebra in the rational Cherednik algebra associated with a finite real reflection group. We find all the defining relations of the algebra, which appear to be quadratic, and we show that the algebra is of Poincaré-Birkhoff-Witt (PBW) type. We show that this algebra contains the angular part of the Calogero-Moser Hamiltonian and that together with constants it generates the centre of the algebra. We also consider the gl( N ) version of the subalge-bra of the rational Cherednik algebra and show that it is a non-homogeneous quadratic algebra of PBW type as well. In this case the central generator can be identified with the usual Calogero-Moser Hamiltonian associated with the Coxeter group in the harmonic confinement.

  5. Integrating rotation from angular velocity

    OpenAIRE

    Zupan, Eva; Saje, Miran

    2011-01-01

    Abstract The integration of the rotation from a given angular velocity is often required in practice. The present paper explores how the choice of the parametrization of rotation, when employed in conjuction with different numerical time-integration schemes, effects the accuracy and the computational efficiency. Three rotation parametrizations – the rotational vector, the Argyris tangential vector and the rotational quaternion – are combined with three different numerical time-integration ...

  6. Orbital angular momentum is dependent on polarization

    OpenAIRE

    Li, Chun-Fang

    2009-01-01

    It is shown that the momentum density of free electromagnetic field splits into two parts. One has no contribution to the net momentum due to the transversality condition. The other yields all the momentum. The angular momentum that originates from the former part is spin, and the angular momentum that originates from the latter part is orbital angular momentum. Expressions for the spin and orbital angular momentum are given in terms of the electric vector in reciprocal space. The spin and or...

  7. Achromatic orbital angular momentum generator

    International Nuclear Information System (INIS)

    We describe a novel approach for generating light beams that carry orbital angular momentum (OAM) by means of total internal reflection in an isotropic medium. A continuous space-varying cylindrically symmetric reflector, in the form of two glued hollow axicons, is used to introduce a nonuniform rotation of polarization into a linearly polarized input beam. This device acts as a full spin-to-orbital angular momentum convertor. It functions by switching the helicity of the incoming beam's polarization, and by conservation of total angular momentum thereby generates a well-defined value of OAM. Our device is broadband, since the phase shift due to total internal reflection is nearly independent of wavelength. We verify the broad-band behaviour by measuring the conversion efficiency of the device for three different wavelengths corresponding to the RGB colours, red, green and blue. An average conversion efficiency of 95% for these three different wavelengths is observed. This device may find applications in imaging from micro- to astronomical systems where a white vortex beam is needed. (paper)

  8. Spin Angular Momentum Imparted by Gravitational Waves

    OpenAIRE

    Sharif, M.

    2007-01-01

    Following the demonstration that gravitational waves impart linear momentum, it is argued that if they are polarized they should impart angular momentum to appropriately placed 'test rods' in their path. A general formula for this angular momentum is obtained and used to provide expressions for the angular momentum imparted by plane and cylindrical gravitational waves.

  9. Angular Momentum Decomposition for an Electron

    OpenAIRE

    Burkardt, Matthias; BC, Hikmat

    2008-01-01

    We calculate the orbital angular momentum of the `quark' in the scalar diquark model as well as that of the electron in QED (to order $\\alpha$). We compare the orbital angular momentum obtained from the Jaffe-Manohar decomposition to that obtained from the Ji relation and estimate the importance of the vector potential in the definition of orbital angular momentum.

  10. AngularJS web application development

    CERN Document Server

    Darwin, Peter Bacon

    2013-01-01

    The book will be a step-by-step guide showing the readers how to build a complete web app with AngularJSJavaScript developers who want to learn AngularJS for developing web apps. Knowledge of JavaScript and HTML is expected. No knowledge of AngularJS is required.

  11. Measurement of the Orbital Angular Momentum Spectrum of Partially Coherent Fields using Double Angular Slit Interference

    CERN Document Server

    Malik, Mehul; Leach, Jonathan; Boyd, Robert W

    2012-01-01

    We implement an interferometric method using two angular slits to measure the orbital angular momentum (OAM) mode spectrum of a partially coherent field. As the angular separation of the slits changes, an interference pattern for a particular OAM mode is obtained. The visibility of this interference pattern as a function of angular separation is equivalent to the angular correlation function of the field. By Fourier transforming the angular correlation function obtained from the double angular slit interference, we are able to calculate the OAM spectrum of the partially coherent field. This method has potential application for characterizing the OAM spectrum in high-dimensional quantum information protocols.

  12. Dependency injection with AngularJS

    CERN Document Server

    Knol, Alex

    2013-01-01

    This book is a practical, hands-on approach to using dependency injection and implementing test-driven development using AngularJS. Dependency Injection with AngularJS is aimed at developers who are aware of AngularJS but need to get started with using it in real life applications. Also, developers who want to get into test-driven development with AngularJS can use this book as practical guide. Even if you know about dependency injection, it can serve as a good reference on how it is used within AngularJS. Readers are expected to have some experience with JavaScript.

  13. Glutamate receptor ligands

    DEFF Research Database (Denmark)

    Guldbrandt, Mette; Johansen, Tommy N; Frydenvang, Karla Andrea; Bräuner-Osborne, Hans; Stensbøl, Tine B; Nielsen, Birgitte; Karla, Rolf; Santi, Flavio; Krogsgaard-Larsen, Povl; Madsen, Ulf

    2002-01-01

    Homologation and substitution on the carbon backbone of (S)-glutamic acid [(S)-Glu, 1], as well as absolute stereochemistry, are structural parameters of key importance for the pharmacological profile of (S)-Glu receptor ligands. We describe a series of methyl-substituted 2-aminoadipic acid (AA...

  14. AMPA receptor ligands

    DEFF Research Database (Denmark)

    Strømgaard, Kristian; Mellor, Ian

    2004-01-01

    polyamines are known to modulate the function of these receptors in vivo. In this study, recent developments in the medicinal chemistry of polyamine-based ligands are given, particularly focusing on the use of solid-phase synthesis (SPS) as a tool for the facile generation of libraries of polyamine toxin...

  15. Electric response in the antiferroelectric crystal of 4,4′-di-t-butyl-2,2′-bipyridyl with chloranilic acid

    Energy Technology Data Exchange (ETDEWEB)

    Rok, M., E-mail: magdalena.rok@chem.uni.wroc.pl; Piecha-Bisiorek, A.; Szklarz, P.; Bator, G.; Sobczyk, L.

    2015-05-01

    Highlights: • The semiconducting properties of the crystals were disclosed in the organic complex. • Dielectric relaxation and dc conductivity were investigated. • Activation energy for the thermally activated processes of the σ{sub dc} was estimated. • The effect of hydrogen bonds on the mechanism of the phase transition and the electric properties of the crystal was discussed. - Abstract: The electric response was analyzed in the vicinity of the structural phase transition at 412 K in the single crystals of 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) with 4,4′-di-t-butyl-2,2′-bipyridyl (dtBBP). The dielectric permittivity of the complex measured along the b direction between 300 and 440 K and at frequencies ranging from 500 Hz to 2 MHz indicates two phenomena. At low frequencies, dielectric losses are ascribed to the electric conductivity of the crystal, while at high frequencies, to the dielectric relaxation described by means of the Cole–Cole relationship. The parameters of the dielectric response: the relaxation time, τ, the dielectric increment, ε{sub ο} − ε{sub ∞}, and the distribution parameter of the relaxation time, α, were estimated and analyzed. The low-temperature structure of the crystals indicates the antiferroelectric arrangement of the supramolecular hydrogen bonds. The dielectric results also presented for the deuterated crystals of dtBBP·CLA proved that the dynamics of protons in the hydrogen bonds are responsible for the mechanism of phase transition.

  16. Electrochemiluminescence of Tris(2,2'-bipyridyl)ruthenium(II) with Ascorbic Acid and Dehydroascorbic Acid in Aqueous and Non-aqueous Solutions.

    Science.gov (United States)

    Takahashi, Fumiki; Hattori, Kaoru; Matsuoka, Masanori; Jin, Jiye

    2016-01-01

    The electrochemiluminescence (ECL) of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)3(2+)) is studied in non-aqueous media using dehydroascorbic acid (DHA) as coreactant to validate the evidence for the mechanism of the ascorbic acid (H2A)/Ru(bpy)3(2+) ECL system in an aqueous media. DHA is electrochemically reduced around -1.2 V vs. Ag/Ag(+) in pure acetonitrile to generate the ascorbyl radical anion (A(•-)), which is confirmed by in-situ UV-visible absorption measurements using a thin-layer spectroelectrochemical cell. The ECL of the DHA/Ru(bpy)3(2+) system in non-aqueous media is not observed in the potential range from 0 to +1.4 V in anodic potential sweep mode; however, distinct ECL is detected using double potential step electrolysis from -1.2 to +1.4 V vs. Ag/Ag(+). The ECL may be generated by a homogeneous charge-transfer process between A(•-) produced during the first pulse potential step (-1.2 V) and Ru(bpy)3(3+) generated during the second pulse potential step (+1.4 V). The calculated standard enthalpy (-ΔH°) for the charge-transfer reaction between A(•-) and Ru(bpy)3(3+) is 2.29 eV, which is larger than the lowest excited singlet state energy of Ru(bpy)3(2+) (*Ru(bpy)3(2+); 2.03 eV, 610 nm). It is determined that the generated intermediate A(•-) is crucial in the Ru(bpy)3(2+) ECL reaction. PMID:27063718

  17. Dissociation and Dioxygen Formation in Hydroxide Solutions of Tris (2,2- bipyridyl) Iron (III) and Tris (1,10-phenanthroline) Iron (III)

    DEFF Research Database (Denmark)

    Nord, G.; Pedersen, B.; Bjergbakke, Erling

    1983-01-01

    The fast redox reactions of the title Fe(II1) complexes in basic solutions give the Fe(I1) complexes and coordinated ligand N-oxide as primary products. Further reactions by parallel paths include dissociation to give the free ligand N-oxide and catalysis by hydroxy Fe(II1) complexes leading to...

  18. Matter waves with angular momentum

    CERN Document Server

    Bracher, C; Kleber, M; Bracher, Christian; Kramer, Tobias; Kleber, Manfred

    2003-01-01

    An alternative description of quantum scattering processes rests on inhomogeneous terms amended to the Schr\\"odinger equation. We detail the structure of sources that give rise to multipole scattering waves of definite angular momentum, and introduce pointlike multipole sources as their limiting case. Partial wave theory is recovered for freely propagating particles. We obtain novel results for ballistic scattering in an external uniform force field, where we provide analytical solutions for both the scattering waves and the integrated particle flux. As an illustration of the theory, we predict some properties of vortex-bearing atom laser beams outcoupled from a rotating Bose--Einstein condensate under the influence of gravity.

  19. Two-axis angular effector

    International Nuclear Information System (INIS)

    A new class of coplanar two-axis angular effectors is described. These effectors combine a two-axis rotational joint analogous to a Cardan joint with linear actuators in a manner to produce a wider range of rotational motion about both axes defined by the joint. This new class of effectors also allows design of robotic manipulators having very high strength and efficiency. These effectors are particularly suited for remote operation in unknown surroundings, because of their extraordinary versatility. An immediate application is to the problems which arise in nuclear waste remediation. 11 figs

  20. Synthesis, structures and reactivity of ruthenium nitrosyl complexes containing Kläui's oxygen tripodal ligand.

    Science.gov (United States)

    Ip, Ho-Fai; Yi, Xiao-Yi; Wong, Wai-Yeung; Williams, Ian D; Leung, Wa-Hung

    2011-11-01

    Ruthenium nitrosyl complexes containing the Kläui's oxgyen tripodal ligand L(OEt)(-) ([CpCo{P(O)(OEt)(2)}(3)](-) where Cp = η(5)-C(5)H(5)) were synthesized and their photolysis studied. The treatment of [Ru(N^N)(NO)Cl(3)] with [AgL(OEt)] and Ag(OTf) afforded [L(OEt)Ru(N^N)(NO)][OTf](2) where N^N = 4,4'-di-tert-butyl-2,2'-bipyridyl (dtbpy) (2·[OTf](2)), 2,2'-bipyridyl (bpy) (3·[OTf](2)), N,N,N'N'-tetramethylethylenediamine (4·[OTf](2)). Anion metathesis of 3·[OTf](2) with HPF(6) and HBF(4) gave 3·[PF(6)](2) and 3·[BF(4)](2), respectively. Similarly, the PF(6)(-) salt 4·[PF(6)](2) was prepared by the reaction of 4·[OTf](2) with HPF(6). The irradiation of [L(OEt)Ru(NO)Cl(2)] (1) with UV light in CH(2)Cl(2)-MeCN and tetrahydrofuran (thf)-H(2)O afforded [L(OEt)RuCl(2)(MeCN)] (5) and the chloro-bridged dimer [L(OEt)RuCl](2)(μ-Cl)(2) (6), respectively. The photolysis of complex [2][OTf](2) in MeCN gave [L(OEt)Ru(dtbpy)(MeCN)][OTf](2) (7). Refluxing complex 5 with RNH(2) in thf gave [L(OEt)RuCl(2)(NH(2)R)] (R = tBu (8), p-tol (9), Ph (10)). The oxidation of complex 6 with PhICl(2) gave [L(OEt)RuCl(3)] (11), whereas the reduction of complex 6 with Zn and NH(4)PF(6) in MeCN yielded [L(OEt)Ru(MeCN)(3)][PF(6)] (12). The reaction of 3·[BF(4)](2) with benzylamine afforded the μ-dinitrogen complex [{L(OEt)Ru(bpy)}(2)(μ-N(2))][BF(4)](2) (13) that was oxidized by [Cp(2)Fe]PF(6) to a mixed valence Ru(II,III) species. The formal potentials of the RuL(OEt) complexes have been determined by cyclic voltammetry. The structures of complexes 5,6,10,11 and 13 have been established by X-ray crystallography. PMID:21927766

  1. Controlling neutron orbital angular momentum.

    Science.gov (United States)

    Clark, Charles W; Barankov, Roman; Huber, Michael G; Arif, Muhammad; Cory, David G; Pushin, Dmitry A

    2015-09-24

    The quantized orbital angular momentum (OAM) of photons offers an additional degree of freedom and topological protection from noise. Photonic OAM states have therefore been exploited in various applications ranging from studies of quantum entanglement and quantum information science to imaging. The OAM states of electron beams have been shown to be similarly useful, for example in rotating nanoparticles and determining the chirality of crystals. However, although neutrons--as massive, penetrating and neutral particles--are important in materials characterization, quantum information and studies of the foundations of quantum mechanics, OAM control of neutrons has yet to be achieved. Here, we demonstrate OAM control of neutrons using macroscopic spiral phase plates that apply a 'twist' to an input neutron beam. The twisted neutron beams are analysed with neutron interferometry. Our techniques, applied to spatially incoherent beams, demonstrate both the addition of quantum angular momenta along the direction of propagation, effected by multiple spiral phase plates, and the conservation of topological charge with respect to uniform phase fluctuations. Neutron-based studies of quantum information science, the foundations of quantum mechanics, and scattering and imaging of magnetic, superconducting and chiral materials have until now been limited to three degrees of freedom: spin, path and energy. The optimization of OAM control, leading to well defined values of OAM, would provide an additional quantized degree of freedom for such studies. PMID:26399831

  2. Analysis of macromolecules, ligands and macromolecule-ligand complexes

    Science.gov (United States)

    Von Dreele, Robert B.

    2008-12-23

    A method for determining atomic level structures of macromolecule-ligand complexes through high-resolution powder diffraction analysis and a method for providing suitable microcrystalline powder for diffraction analysis are provided. In one embodiment, powder diffraction data is collected from samples of polycrystalline macromolecule and macromolecule-ligand complex and the refined structure of the macromolecule is used as an approximate model for a combined Rietveld and stereochemical restraint refinement of the macromolecule-ligand complex. A difference Fourier map is calculated and the ligand position and points of interaction between the atoms of the macromolecule and the atoms of the ligand can be deduced and visualized. A suitable polycrystalline sample of macromolecule-ligand complex can be produced by physically agitating a mixture of lyophilized macromolecule, ligand and a solvent.

  3. Ligand-Receptor Interactions

    CERN Document Server

    Bongrand, Pierre

    2008-01-01

    The formation and dissociation of specific noncovalent interactions between a variety of macromolecules play a crucial role in the function of biological systems. During the last few years, three main lines of research led to a dramatic improvement of our understanding of these important phenomena. First, combination of genetic engineering and X ray cristallography made available a simultaneous knowledg of the precise structure and affinity of series or related ligand-receptor systems differing by a few well-defined atoms. Second, improvement of computer power and simulation techniques allowed extended exploration of the interaction of realistic macromolecules. Third, simultaneous development of a variety of techniques based on atomic force microscopy, hydrodynamic flow, biomembrane probes, optical tweezers, magnetic fields or flexible transducers yielded direct experimental information of the behavior of single ligand receptor bonds. At the same time, investigation of well defined cellular models raised the ...

  4. Radiobiology with DNA ligands

    International Nuclear Information System (INIS)

    The paper deals with the following topics: labelling of DNA ligands and other tumour-affinic compounds with 4.15-d 124I, radiotoxicity of Hoechst 33258 and 33342 and of iodinated Hoechst 33258 in cell cultures, preparation of 76Br-, 123I-, and 221At-labelled 5-halo-2'-deoxyuridine, chemical syntheses of boron derivatives of Hoechst 33258.III., Gadolinium neutron capture therapy

  5. A novel solid-state electrochemiluminescence detector for capillary electrophoresis based on tris(2,2'-bipyridyl)ruthenium(II) immobilized in Nafion/PTC-NH2 composite film.

    Science.gov (United States)

    Liu, Huijing; Yuan, Ruo; Chai, Yaqing; Mao, Li; Yang, Xia; Zhuo, Ying; Yuan, Yali

    2011-04-15

    A new electrochemiluminescence (ECL) detector for capillary electrophoresis (CE) based on tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)(3)(2+)) immobilized in Nafion/PTC-NH(2) (an ammonolysis product of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA)) composite film was presented for the first time. The Nafion/PTC-NH(2) composite film could effectively immobilize tris(2,2'-bipyridyl)ruthenium(II) via ion-exchange and electrostatic interaction. Cyclic voltammetric and ECL behavior of Nafion/PTC-NH(2)/Ru composite film was investigated compared to Nafion/Ru composite. The Nafion/PTC-NH(2)/Ru composite film exhibited good ECL stability and simple operability. Then the CE with solid-state ECL detector system was successfully used to detect sophora - a quinolizidine type - alkaloids as sophoridine (SR) and matrine (MT). The CE-ECL parameters that affected separation and detection were optimized. Under the optimized conditions, the linear range was from 2.5 × 10(-8) to 2 × 10(-6)mol/L for SR, 1.0 × 10(-8) to 1.0 × 10(-6)mol/L for MT. The detection limit (S/N=3) was estimated to be 5 × 10(-9) and 10(-9)mol/L for SR and MT, respectively. It was shown that the CE coupling with solid-state ECL detector system exhibited satisfying sensitivity of analysis. PMID:21376962

  6. Imidazoline receptors ligands

    Directory of Open Access Journals (Sweden)

    Agbaba Danica

    2012-01-01

    Full Text Available Extensive biochemical and pharmacological studies have determined three different subtypes of imidazoline receptors: I1-imidazoline receptors (I1-IR involved in central inhibition of sympathicus that produce hypotensive effect; I2-imidazoline receptors (I2-IR modulate monoamine oxidase B activity (MAO-B; I3-imidazoline receptors (I3-IR regulate insulin secretion from pancreatic β-cells. Therefore, the I1/I2/I3 imidazoline receptors are selected as new, interesting targets for drug design and discovery. Novel selective I1/I2/I3 agonists and antagonists have been recently developed. In the present review, we provide a brief update to the field of imidazoline research, highlighting some of the chemical diversity and progress made in the 2D-QSAR, 3D-QSAR and quantitative pharmacophore development studies of I1-IR and I2-IR imidazoline receptor ligands. Theoretical studies of I3-IR ligands are not yet performed because of insufficient number of synthesized I3-IR ligands.

  7. The difficulty of measuring orbital angular momentum

    OpenAIRE

    Preece, D; Nieminen, T. A.; Asavei, T.; Heckenberg, N. R.; Rubinsztein-Dunlop, H.

    2011-01-01

    Light can carry angular momentum as well as energy and momentum; the transfer of this angular momentum to an object results in an optical torque. The development of a rotational analogue to the force measurement capability of optical tweezers is hampered by the difficulty of optical measurement of orbital angular momentum. We present an experiment with encouraging results, but emphasise the difficulty of the task.

  8. The difficulty of measuring orbital angular momentum

    Directory of Open Access Journals (Sweden)

    D. Preece

    2011-09-01

    Full Text Available Light can carry angular momentum as well as energy and momentum; the transfer of this angular momentum to an object results in an optical torque. The development of a rotational analogue to the force measurement capability of optical tweezers is hampered by the difficulty of optical measurement of orbital angular momentum. We present an experiment with encouraging results, but emphasise the difficulty of the task.

  9. Orbital angular momentum and the parton model

    Energy Technology Data Exchange (ETDEWEB)

    Ratcliffe, P.G.

    1987-06-25

    The role of orbital angular momentum is discussed within the framework of the parton model. It is shown that a consistent interpretation of the Altarelli-Parisi equations governing the Q/sup 2/-evolution of helicity-weighted parton distributions necessitates the assumption that partons carry a large orbital angular momentum, contrary to popular belief. In developing the arguments presented, the Altarelli-Parisi formalism is extended to include orbital angular momentum dependence.

  10. Photoionization with Orbital Angular Momentum Beams

    OpenAIRE

    Picón, A.; Mompart, J.; de Aldana, J. R. Vázquez; Plaja, L.; Calvo, G. F.; Roso, L.

    2010-01-01

    Intense laser ionization expands Einstein's photoelectric effect rules giving a wealth of phenomena widely studied over the last decades. In all cases, so far, photons were assumed to carry one unit of angular momentum. However it is now clear that photons can possess extra angular momentum, the orbital angular momentum (OAM), related to their spatial profile. We show a complete description of photoionization by OAM photons, including new selection rules involving more than one unit of angula...

  11. Quantum formulation of fractional orbital angular momentum

    OpenAIRE

    Götte, Jörg B; Franke-Arnold, Sonja; Zambrini, Roberta; Barnett, Stephen M.

    2007-01-01

    The quantum theory of rotation angles (S. M. Barnett and D. T. Pegg, Phys. Rev. A, 41, 3427-3425 (1990)) is generalised to non-integer values of the orbital angular momentum. This requires the introduction of an additional parameter, the orientation of a phase discontinuity associated with fractional values of the orbital angular momentum. We apply our formalism to the propagation of light modes with fractional orbital angular momentum in the paraxial and non-paraxial regime.

  12. Orbital angular momentum induced beam shifts

    OpenAIRE

    Hermosa N.; Merano M.; Aiello A.; Woerdman J.P.

    2011-01-01

    We present experiments on Orbital Angular Momentum (OAM) induced beam shifts in optical reflection. Specifically, we observe the spatial Goos-H\\"anchen shift in which the beam is displaced parallel to the plane of incidence and the angular Imbert-Fedorov shift which is a transverse angular deviation from the geometric optics prediction. Experimental results agree well with our theoretical predictions. Both beam shifts increase with the OAM of the beam; we have measured these for OAM indices u...

  13. Orbital angular momentum in phase space

    International Nuclear Information System (INIS)

    Research highlights: → We propose a comprehensive Weyl-Wigner formalism for the canonical pair angle-angular momentum. → We present a simple and useful toolkit for the practitioner. → We derive simple evolution equations in terms of a star product in the semiclassical limit. - Abstract: A comprehensive theory of the Weyl-Wigner formalism for the canonical pair angle-angular momentum is presented. Special attention is paid to the problems linked to rotational periodicity and angular-momentum discreteness.

  14. Useful angular selectivity in oblique columnar aluminum

    Science.gov (United States)

    Ditchburn, R. J.; Smith, G. B.

    1991-03-01

    A useful magnitude of angular selective transmittance of incident unpolarized light is demonstrated in obliquely deposited aluminum. Required deposition procedures and anisotropic optical properties are discussed. Angular selectivity is very strong at visible wavelengths but both experiment and theory indicate that a single oblique layer with well defined columns gives high transmittance at near-infrared wavelengths compared with normal films. There are ways of reducing this to enhance the energy control capability. Both solar and luminous angular selectivity are reported.

  15. The Angular Momentum of the Solar System

    Science.gov (United States)

    Cang, Rongquin; Guo, Jianpo; Hu, Juanxiu; He, Chaoquiong

    2016-05-01

    The angular momentum of the Solar System is a very important physical quantity to the formation and evolution of the Solar System. Previously, the spin angular momentum of the Sun and the orbital angular momentum of the Eight Giant Planets were only taken into consideration, when researchers calculated the angular momentum of the Solar System. Nowadays, it seems narrow and conservative. Using Eggleton's code, we calculate the rotational inertia of the Sun. Furthermore, we obtain that the spin angular momentum of the Sun is 1.8838 x 10^41 kg m^2 s^-1. Besides the spin angular momentum of the Sun and the orbital angular momentum of the Eight Giant Planets, we also account for the orbital angular momentum of the Asteroid Belt, the Kuiper Belt, the Oort Cloud, the Ninth Giant Planet and the Solar Companion. We obtain that the angular momentum of the whole Solar System is 3.3212 x 10^45 kg m^2 s^-1.

  16. Transverse and longitudinal angular momenta of light

    International Nuclear Information System (INIS)

    We review basic physics and novel types of optical angular momentum. We start with a theoretical overview of momentum and angular momentum properties of generic optical fields, and discuss methods for their experimental measurements. In particular, we describe the well-known longitudinal (i.e., aligned with the mean momentum) spin and orbital angular momenta in polarized vortex beams. Then, we focus on the transverse (i.e., orthogonal to the mean momentum) spin and orbital angular momenta, which were recently actively discussed in theory and observed in experiments. First, the recently-discovered transverse spin  angular momenta appear in various structured fields: evanescent waves, interference fields, and focused beams. We show that there are several kinds of transverse spin angular momentum, which differ strongly in their origins and physical properties. We describe extraordinary features of the transverse optical spins and overview recent experiments. In particular, the helicity-independent transverse spin inherent in edge evanescent waves offers robust spin–direction coupling at optical interfaces (the quantum spin Hall effect of light). Second, we overview the transverse orbital angular momenta of light, which can be both extrinsic and intrinsic. These two types of the transverse orbital angular momentum are produced by spatial shifts of the optical beams (e.g., in the spin Hall effect of light) and their Lorentz boosts, respectively. Our review is underpinned by a unified theory of the angular momentum of light based on the canonical momentum and spin densities, which avoids complications associated with the separation of spin and orbital angular momenta in the Poynting picture. It allows us to construct a comprehensive classification of all known optical angular momenta based on their key parameters and main physical properties

  17. Transverse and longitudinal angular momenta of light

    Energy Technology Data Exchange (ETDEWEB)

    Bliokh, Konstantin Y., E-mail: k.bliokh@gmail.com [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Nonlinear Physics Centre, RSPhysE, The Australian National University, Canberra, ACT 0200 (Australia); Nori, Franco [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Physics Department, University of Michigan, Ann Arbor, MI 48109-1040 (United States)

    2015-08-26

    We review basic physics and novel types of optical angular momentum. We start with a theoretical overview of momentum and angular momentum properties of generic optical fields, and discuss methods for their experimental measurements. In particular, we describe the well-known longitudinal (i.e., aligned with the mean momentum) spin and orbital angular momenta in polarized vortex beams. Then, we focus on the transverse (i.e., orthogonal to the mean momentum) spin and orbital angular momenta, which were recently actively discussed in theory and observed in experiments. First, the recently-discovered transverse spin  angular momenta appear in various structured fields: evanescent waves, interference fields, and focused beams. We show that there are several kinds of transverse spin angular momentum, which differ strongly in their origins and physical properties. We describe extraordinary features of the transverse optical spins and overview recent experiments. In particular, the helicity-independent transverse spin inherent in edge evanescent waves offers robust spin–direction coupling at optical interfaces (the quantum spin Hall effect of light). Second, we overview the transverse orbital angular momenta of light, which can be both extrinsic and intrinsic. These two types of the transverse orbital angular momentum are produced by spatial shifts of the optical beams (e.g., in the spin Hall effect of light) and their Lorentz boosts, respectively. Our review is underpinned by a unified theory of the angular momentum of light based on the canonical momentum and spin densities, which avoids complications associated with the separation of spin and orbital angular momenta in the Poynting picture. It allows us to construct a comprehensive classification of all known optical angular momenta based on their key parameters and main physical properties.

  18. Angular momentum of non-paraxial light beam: Dependence of orbital angular momentum on polarization

    OpenAIRE

    Li, Chun-Fang

    2009-01-01

    It is shown that the momentum density of free electromagnetic field splits into two parts. One has no contribution to the net momentum due to the transversality condition. The other yields all the momentum. The angular momentum that is associated with the former part is spin, and the angular momentum that is associated with the latter part is orbital angular momentum. Expressions for the spin and orbital angular momentum are given in terms of the electric vector in reciprocal space. The spin ...

  19. Experimental determination of high angular momentum states

    International Nuclear Information System (INIS)

    The current knowledge of the atomic nucleus structure is summarized. A short abstract of the nuclear properties at high angular momentum and a more detailed description of the experimental methods used in the study of high angular momenta is made. (L.C.)

  20. Orbital Angular Momentum in the Nucleon

    OpenAIRE

    Garvey, Gerald T.

    2010-01-01

    Analysis of the measured value of the integrated \\bar{d}-\\bar{u} asymmetry (Ifas = 0.147+-0.027) in the nucleon show it to arise from nucleon fluctuations into baryon plus pion. Requiring angular momentum conservation in these fluctuations shows the associated orbital angular momentum is equal to the value of the flavor asymmetry.

  1. Detecting orbital angular momentum in radio signals

    OpenAIRE

    Then, H.; Thidé, B.; Mendonça, J T; Carozzi, T.D.; Bergman, J.; Baan, W. A.; Mohammadi, S. (Siawoosh); Eliasson, B.

    2008-01-01

    Electromagnetic waves with an azimuthal phase shift are known to have a well defined orbital angular momentum. Different methods that allow for the detection of the angular momentum are proposed. For some, we discuss the required experimental setup and explore the range of applicability.

  2. The Orbital Angular Momentum Sum Rule

    Science.gov (United States)

    Aslan, Fatma; Burkardt, Matthias

    2015-10-01

    As an alternative to the Ji sum rule for the quark angular momentum, a sum rule for the quark orbital angular momentum, based on a twist-3 generalized parton distribution, has been suggested. We study the validity of this sum rule in the context of scalar Yukawa interactions as well as in QED for an electron.

  3. Responsive web design with AngularJS

    CERN Document Server

    Patel, Sandeep Kumar

    2014-01-01

    If you are an AngularJS developer who wants to learn about responsive web application development, this book is ideal for you. Responsive Web Design with AngularJS is intended for web developers or designers with a basic knowledge of HTML, CSS, and JavaScript.

  4. Exposing Library Services with AngularJS

    OpenAIRE

    Jakob Voß; Moritz Horn

    2014-01-01

    This article provides an introduction to the JavaScript framework AngularJS and specific AngularJS modules for accessing library services. It shows how information such as search suggestions, additional links, and availability can be embedded in any website. The ease of reuse may encourage more libraries to expose their services via standard APIs to allow usage in different contexts.

  5. Angular-Rate Estimation Using Quaternion Measurements

    Science.gov (United States)

    Azor, Ruth; Bar-Itzhack, Y.; Deutschmann, Julie K.; Harman, Richard R.

    1998-01-01

    In most spacecraft (SC) there is a need to know the SC angular rate. Precise angular rate is required for attitude determination, and a coarse rate is needed for attitude control damping. Classically, angular rate information is obtained from gyro measurements. These days, there is a tendency to build smaller, lighter and cheaper SC, therefore the inclination now is to do away with gyros and use other means and methods to determine the angular rate. The latter is also needed even in gyro equipped satellites when performing high rate maneuvers whose angular-rate is out of range of the on board gyros or in case of gyro failure. There are several ways to obtain the angular rate in a gyro-less SC. When the attitude is known, one can differentiate the attitude in whatever parameters it is given and use the kinematics equation that connects the derivative of the attitude with the satellite angular-rate and compute the latter. Since SC usually utilize vector measurements for attitude determination, the differentiation of the attitude introduces a considerable noise component in the computed angular-rate vector.

  6. Angular momentum decomposition of Richardson's pairs

    International Nuclear Information System (INIS)

    The angular momentum decomposition of pairs obtained using Richardson's exact solution of the pairing Hamiltonian for the deformed 174Yb nucleus are displayed. The probabilities for low angular momenta of the collective pairs are strikingly different from the ones obtained in the BCS ground state

  7. Quark angular momentum in a spectator model

    International Nuclear Information System (INIS)

    We investigate the quark angular momentum in a model with the nucleon being a quark and a spectator. Both scalar and axial-vector spectators are included. We perform the calculations in the light-cone formalism where the parton concept is well defined. We calculate the quark helicity and canonical orbital angular momentum. Then we calculate the gravitational form factors which are often related to the kinetic angular momentums, and find that even in a no gauge field model we cannot identify the canonical angular momentums with half the sum of gravitational form factors. In addition, we examine the model relation between the orbital angular momentum and pretzelosity, and find it is violated in the axial-vector case

  8. Quark angular momentum in a spectator model

    Directory of Open Access Journals (Sweden)

    Tianbo Liu

    2015-02-01

    Full Text Available We investigate the quark angular momentum in a model with the nucleon being a quark and a spectator. Both scalar and axial-vector spectators are included. We perform the calculations in the light-cone formalism where the parton concept is well defined. We calculate the quark helicity and canonical orbital angular momentum. Then we calculate the gravitational form factors which are often related to the kinetic angular momentums, and find that even in a no gauge field model we cannot identify the canonical angular momentums with half the sum of gravitational form factors. In addition, we examine the model relation between the orbital angular momentum and pretzelosity, and find it is violated in the axial-vector case.

  9. Does high harmonic generation conserve angular momentum?

    CERN Document Server

    Fleischer, Avner; Diskin, Tzvi; Sidorenko, Pavel; Cohen, Oren

    2013-01-01

    High harmonic generation (HHG) is a unique and useful process in which infrared or visible radiation is frequency up converted into the extreme ultraviolet and x ray spectral regions. As a parametric process, high harmonic generation should conserve the radiation energy, momentum and angular momentum. Indeed, conservation of energy and momentum have been demonstrated. Angular momentum of optical beams can be divided into two components: orbital and spin (polarization). Orbital angular momentum is assumed to be conserved and recently observed deviations were attributed to propagation effects. On the other hand, conservation of spin angular momentum has thus far never been studied, neither experimentally nor theoretically. Here, we present the first study on the role of spin angular momentum in extreme nonlinear optics by experimentally generating high harmonics of bi chromatic elliptically polarized pump beams that interact with isotropic media. While observing that the selection rules qualitatively correspond...

  10. Physical Angular Momentum Separation for QED

    CERN Document Server

    Sun, Weimin

    2016-01-01

    We study the non-uniqueness problem of the gauge-invariant angular momentum separation for the case of QED, which stems from the recent controversy concerning the proper definitions of the orbital angular momentum and spin operator of the individual parts of a gauge field system. For the free quantum electrodynamics without matter, we show that the basic requirement of Euclidean symmetry selects a unique physical angular momentum separation scheme from the multitude of the possible angular momentum separation schemes constructed using the various Gauge Invariant Extentions. Based on these results, we propose a set of natural angular momentum separation schemes for the case of interacting QED by invoking the formalism of asymptotic fields. Some perspectives on such a problem for the case of QCD are briefly discussed.

  11. Molecular path for ligand search

    Institute of Scientific and Technical Information of China (English)

    Tao Lu; Yuan Yuan Qiao; Pan Wen Shen

    2011-01-01

    A ligand is a small molecule bind to several residues of a receptor. We adapt the concept of molecular path for effective ligand search with its contacting residues. Additionally, we allow wild type definitions on atoms and bonds of molecular paths for fuzzy algorithms on structural match. We choose hydrogen bond interactions to characterize the binding mode of a ligand by several proper molecular paths and use them to query the deposited ligands in PDBe that interact with their residues in the same way. Expression of molecular path and format of database entries are described with examples. Our molecular path provides a new approach to explore the ligand-receptor interactions and to provide structural framework reference on new ligand design.

  12. Perturbed angular correlations and distributions

    International Nuclear Information System (INIS)

    The present index comprises original works and review papers on the perturbed angular correlations (PAC) and distributions (PAD). The articles published in the Soviet and foreign journals as well as the materials of conferences, monographs and collections published in the USSR and abroad, the preprints produced by various institutes and abstracts of disertations are included from 1948 up to 1973. The whole material compiled in this index is divided into three parts. Part one is a bibliographic index. All papers in this part are divided into three sections. Section one comprises the papers devoted to the theoretical works on PAC, review papers, monographs, materials of conferences. Section two deals with the works of methodical character where correlation spectrometers as well as the treatment of experimental data are described. In section three experimental works with concrete nuclei are compiled. Part two gives the characteristic of works performed with concrete nuclei. This part is presented in the form of the table in which the works are systematized according to the chemical elements and isotopes. The table shows the characteristics of the nuclear levels used in the investigations by PAC as well as brief characteristics of experiments and results obtained. Part three - appendix contains alphabetic index of the authors, the list of the used editions with the abbreviations of the titles of these editions. The lists indicating the dynamic of the quantity of works on PAC and the distribution according to the literature sources are also given

  13. Macrocyclic G-quadruplex ligands

    DEFF Research Database (Denmark)

    Nielsen, M C; Ulven, Trond

    2010-01-01

    G-quadruplex stabilizing compounds have recently received increased interest due to their potential application as anticancer therapeutics. A significant number of structurally diverse G-quadruplex ligands have been developed. Some of the most potent and selective ligands currently known are...... macrocyclic structures which have been modeled after the natural product telomestatin or from porphyrin-based ligands discovered in the late 1990s. These two structural classes of G-quadruplex ligands are reviewed here with special attention to selectivity and structure-activity relationships, and with focus...

  14. Poly[[bis(μ-4,4′-bipyridyl-κ2N:N′bis(thiocyanato-κNmanganese(II] diethyl ether disolvate

    Directory of Open Access Journals (Sweden)

    Mario Wriedt

    2010-07-01

    Full Text Available In the title compound, {[Mn(NCS2(C10H8N22]·2C4H10O}n, the MnII ion is coordinated by four N-bonded 4,4′-bipyridine (bipy ligands and two N-bonded thiocyanate anions in a distorted octahedral coordination geometry. The asymmetric unit consists of one MnII ion and two bipy ligands each located on a twofold rotation axis, as well as one thiocyanate anion and one diethyl ether molecule in general positions. In the crystal structure, the metal centers with terminally bonded thicyanate anions are bridged by the bipy ligands into layers parallel to (001. The diethyl ether solvent molecules occupy the voids of the structure.

  15. Poly[[bis­(μ-4,4′-bipyridyl-κ2 N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate

    OpenAIRE

    Mario Wriedt; Inke Jess; Christian Näther

    2010-01-01

    In the title compound, {[Mn(NCS)2(C10H8N2)2]·2C4H10O}n, the MnII ion is coordinated by four N-bonded 4,4′-bipyridine (bipy) ligands and two N-bonded thiocyanate anions in a distorted octahedral coordination geometry. The asymmetric unit consists of one MnII ion and two bipy ligands each located on a twofold rotation axis, as well as one thiocyanate anion and one diethyl ether molecule in general positions. In the crystal structure, the metal centers with terminally bonded t...

  16. Angular velocity: a new dimension in nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Diamond, R.M.; Stephens, F.S.

    1984-08-09

    Nuclei can be studied from their ground states (approx.O(h/2..pi..)) up to angular momenta of order 100 (h/2..pi..), where they are literally pulled apart by centrifugal effects. This range of angular momenta can be viewed as resulting from cranking the nucleus around a rotation axis, where the critical variable is the cranking velocity. The calculated response of nuclei to such an imposed angular velocity corresponds well with recent observations, and includes a rich and varied interplay of collective and single-particle phenomena.

  17. Angular momentum conservation for dynamical black holes

    OpenAIRE

    Hayward, Sean A.

    2006-01-01

    Angular momentum can be defined by rearranging the Komar surface integral in terms of a twist form, encoding the twisting around of space-time due to a rotating mass, and an axial vector. If the axial vector is a coordinate vector and has vanishing transverse divergence, it can be uniquely specified under certain generic conditions. Along a trapping horizon, a conservation law expresses the rate of change of angular momentum of a general black hole in terms of angular momentum densities of ma...

  18. Quartz angular rate sensor for automotive navigation

    Energy Technology Data Exchange (ETDEWEB)

    Nozoe, Toshiyuki; Ichinose, Toshihiko; Kawasaki, Syusaku; Hatanaka, Masakazu; Kuroda, Keisuke [Matsushita Electronic Components Co. Ltd. (Japan); Yamamoto, Kohji; Ogata, Motoki; Takeno, Shoichi [Fukui Matsushita Electric Co. Ltd. (Japan); Ishihara, Minoru; Ishii, Tadashi; Umeki, Mitoshi [Nihonn Denpa Kogyo Co. Ltd. (Japan)

    1999-07-01

    Many of the recent automotive navigation systems are introducing an angular rate sensor that detect vehicle yaw in their system due to the advantage of higher accuracy, in addition to a conventional GPS (Global Positioning System) and vehicle speed signals. Though there are a couple of other methods to get a vehicle direction information, the angular rate sensor is the most suitable device as a gyro in accuracy and reliability point of view. Matsushita developed a new compact angular rate sensor using quartz crystal for automotive navigation systems. The sensor's operation is based upon Coriolis force imposed on a vibrating quartz tuning fork. (orig.)

  19. Ruthenium bistridentate complexes with non-symmetrical hexahydro-pyrimidopyrimidine ligands: a structural and theoretical investigation of their optical and electrochemical properties.

    Science.gov (United States)

    Laramée-Milette, Baptiste; Hanan, Garry S

    2016-08-01

    Six ruthenium complexes were synthesized based on three non-symmetrical tridentate ligands bearing the strongly electron-donating group 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-α]pyrimidine (hpp), bpyG (bpyG = 2,2'-bipyridyl-6-hpp), phenG (phenG = 2-hpp-1,10-phenanthroline) and QpyG (QpyG = 2-hpp-6-quinolylpyridyl). The fac-/mer-conformation of the homoleptic species has a dramatic effect on the optical properties, where the fac-isomer absorption is red-shifted by 150 nm, thus reaching the near-IR at approximately 850 nm. Owing to the interesting structural effect on the optical properties, density functional theory (DFT) and time-dependent DFT calculations have been implemented to enlighten the experimental data and prove that exciton coupling is at the origin of the observed shift. The electronic properties have been investigated and, as corroborated by electrochemical data, the presence of the hpp ligand strongly affects the oxidation potential of the ruthenium metal ion, which allows facile fine-tuning of the electronic properties. The luminescence properties of all the compounds have also been investigated (λmax emission = 781-817 nm) and the complexes have longer excited-state lifetimes at room temperature than the parent bis(2,2':6',2''-terpyridine)ruthenium(ii) by 10 to 30 times. PMID:27436338

  20. Gravitational waves carrying orbital angular momentum

    Science.gov (United States)

    Bialynicki-Birula, Iwo; Bialynicka-Birula, Zofia

    2016-02-01

    Spinorial formalism is used to map every electromagnetic wave into the gravitational wave (within the linearized gravity). In this way we can obtain the gravitational counterparts of Bessel, Laguerre-Gauss, and other light beams carrying orbital angular momentum.

  1. The physics of angular momentum radio

    CERN Document Server

    Thidé, B; Then, H; Someda, C G; Ravanelli, R A

    2014-01-01

    Wireless communications, radio astronomy and other radio science applications are mainly implemented with techniques built on top of the electromagnetic linear momentum (Poynting vector) physical layer. As a supplement and/or alternative to this conventional approach, techniques rooted in the electromagnetic angular momentum physical layer have been advocated, and promising results from proof-of-concept radio communication experiments using angular momentum were recently published. This sparingly exploited physical observable describes the rotational (spinning and orbiting) physical properties of the electromagnetic fields and the rotational dynamics of the pertinent charge and current densities. In order to facilitate the exploitation of angular momentum techniques in real-world implementations, we present a systematic, comprehensive theoretical review of the fundamental physical properties of electromagnetic angular momentum observable. Starting from an overview that puts it into its physical context among ...

  2. Angular Momentum Acquisition in Galaxy Halos

    CERN Document Server

    Stewart, Kyle R; Bullock, James S; Maller, Ariyeh H; Diemand, Juerg; Wadsley, James; Moustakas, Leonidas A

    2013-01-01

    We use high-resolution cosmological hydrodynamic simulations to study the angular momentum acquisition of gaseous halos around Milky Way sized galaxies. We find that cold mode accreted gas enters a galaxy halo with ~70% more specific angular momentum than dark matter averaged over cosmic time (though with a very large dispersion). In fact, we find that all matter has a higher spin parameter when measured at accretion than when averaged over the entire halo lifetime, and is well characterized by \\lambda~0.1, at accretion. Combined with the fact that cold flow gas spends a relatively short time (1-2 dynamical times) in the halo before sinking to the center, this naturally explains why cold flow halo gas has a specific angular momentum much higher than that of the halo and often forms "cold flow disks". We demonstrate that the higher angular momentum of cold flow gas is related to the fact that it tends to be accreted along filaments.

  3. Gravitational waves carrying orbital angular momentum

    CERN Document Server

    Bialynicki-Birula, Iwo

    2015-01-01

    Spinorial formalism is used to map every electromagnetic wave into the gravitational wave (within the linearized gravity). In this way we can obtain the gravitational counterparts of Bessel, Laguerre-Gauss, and other light beams carrying orbital angular momentum.

  4. Radiofrequency encoded angular-resolved light scattering

    DEFF Research Database (Denmark)

    Buckley, Brandon W.; Akbari, Najva; Diebold, Eric D.;

    2015-01-01

    The sensitive, specific, and label-free classification of microscopic cells and organisms is one of the outstanding problems in biology. Today, instruments such as the flow cytometer use a combination of light scatter measurements at two distinct angles to infer the size and internal complexity...... of cells at rates of more than 10,000 per second. However, by examining the entire angular light scattering spectrum it is possible to classify cells with higher resolution and specificity. Current approaches to performing these angular spectrum measurements all have significant throughput limitations...... Encoded Angular-resolved Light Scattering (REALS), this technique multiplexes angular light scattering in the radiofrequency domain, such that a single photodetector captures the entire scattering spectrum from a particle over approximately 100 discrete incident angles on a single shot basis. As a proof...

  5. ZKDR Distance, Angular Size and Phantom Cosmology

    OpenAIRE

    R.C. Santos; Lima, J. A. S.

    2006-01-01

    The influence of mass inhomogeneities on the angular size-redshift test is investigated for a large class of flat cosmological models driven by dark energy plus a cold dark matter component. The results are presented in two steps. First, the mass inhomogeneities are modeled by a generalized Zeldovich-Kantowski-Dyer-Roeder (ZKDR) distance which is characterized by a smoothness parameter $\\alpha(z)$ and a power index $\\gamma$, and, second, we provide a statistical analysis to angular size data ...

  6. Mastering AngularJD for .NET developers

    CERN Document Server

    Majid, Mohammad Wadood

    2015-01-01

    This book is envisioned for traditional developers and programmers who want to develop client-side applications using the AngularJS framework and ASP.NET Web API 2 with Visual Studio. .NET developers who have already built web applications or web services and who have a fundamental knowledge of HTML, JavaScript, and CSS and want to explore single-page applications will also find this guide useful. Basic knowledge of AngularJS would be helpful.

  7. Shell effects and fission fragments angular anisotropy

    International Nuclear Information System (INIS)

    The impact of the shell corrections attenuation effect with growth of the fissionable nuclei temperature on the angular anisotropy of the fission fragments is considered. The experimental data on the anisotropy of the fission fragments angular distributions of the compound nucleus, formed in the 4He + 238U reactions, are analyzed within the frames of the transition states model in the fission barriers saddle point and statistic theory of nuclear reactions. The obvious kind of the shell corrections attenuation function is obtained

  8. Integrating rotation and angular velocity from curvature

    OpenAIRE

    Saje, Miran; Treven, Anita

    2016-01-01

    The problem of integrating the rotational vector from a given angular velocity vector is met in such diverse fields as the navigation, robotics, computer graphics, optical tracking and non-linear dynamics of flexible beams. For example, if the numerical formulation of non-linear dynamics of flexible beams is based on the interpolation of curvature, one needs to derive the rotation from the assumed curvature field. The relation between the angular velocity and the rotation is described by the ...

  9. Angular velocity nonlinear observer from vector measurements

    OpenAIRE

    Magnis, Lionel; Petit, Nicolas

    2015-01-01

    The paper proposes a technique to estimate the angular velocity of a rigid body from vector measurements. Compared to the approaches presented in the literature, it does not use attitude information nor rate gyros as inputs. Instead, vector measurements are directly filtered through a nonlinear observer estimating the angular velocity. Convergence is established using a detailed analysis of the linear-time varying dynamics appearing in the estimation error equation. This equation stems from t...

  10. Generalized Uncertainty Principle and Angular Momentum

    CERN Document Server

    Bosso, Pasquale

    2016-01-01

    Various models of quantum gravity suggest a modification of the Heisenberg's Uncertainty Principle, to the so-called Generalized Uncertainty Principle, between position and momentum. In this work we show how this modification influences the theory of angular momentum in Quantum Mechanics. In particular, we compute Planck scale corrections to angular momentum eigenvalues, the Hydrogen atom spectrum, the Stern-Gerlach experiment and the Clebsch-Gordan coefficients. We also examine effects of the Generalized Uncertainty Principle on multi-particle systems.

  11. Multipolar expansion of orbital angular momentum modes

    OpenAIRE

    Molina-Terriza, Gabriel

    2008-01-01

    In this letter a general method for expanding paraxial beams into multipolar electromagnetic fields is presented. This method is applied to the expansion of paraxial modes with orbital angular momentum (OAM), showing how the paraxial OAM is related to the general angular momentum of an electromagnetic wave. This method can be extended to quasi-paraxial beams, i.e. highly focused laser beams. Some applications to the control of electronic transitions in atoms are discussed.

  12. Orbital angular momentum in the nucleons

    OpenAIRE

    Lorcé, Cédric

    2014-01-01

    In the last decade, it has been realized that the orbital angular momentum of partons inside the nucleon plays a major role. It contributes significantly to nucleon properties and is at the origin of many asymmetries observed in spin physics. It is therefore of paramount importance to determine this quantity if we want to understand the nucleon internal structure and experimental observables. This triggered numerous discussions and controversies about the proper definition of orbital angular ...

  13. Orbital angular momentum of partially coherent beams

    OpenAIRE

    Serna Galán, Julio; Movilla Serrano, Jesús María

    2001-01-01

    The definition of the orbital angular momentum established for coherent beams is extended to partially coherent beams, expressed in terms of two elements of the beam matrix. This extension is justified by use of the Mercer expansion of partially coherent fields. General Gauss-Schell-model fields are considered, and the relation between the twist; parameter and the orbital angular momentum is analyzed. © 2001 Optical Society of America.

  14. Entanglement of Polarization and Orbital Angular Momentum

    OpenAIRE

    Bhatti, Daniel; von Zanthier, Joachim; Agarwal, Girish S.

    2015-01-01

    We investigate two-photon entangled states using two important degrees of freedom of the electromagnetic field, namely orbital angular momentum (OAM) and spin angular momentum. For photons propagating in the same direction we apply the idea of $\\textit{entanglement duality}$ and develop schemes to do $\\textit{entanglement sorting}$ based either on OAM or polarization. In each case the entanglement is tested using appropriate witnesses. We finally present generalizations of these ideas to thre...

  15. Radio beam vorticity and orbital angular momentum

    OpenAIRE

    Thidé, Bo; Tamburini, Fabrizio; Mari, Elettra; Romanato, Filippo; Barbieri, Cesare

    2011-01-01

    It has been known for a century that electromagnetic fields can transport not only energy and linear momentum but also angular momentum. However, it was not until twenty years ago, with the discovery in laser optics of experimental techniques for the generation, detection and manipulation of photons in well-defined, pure orbital angular momentum (OAM) states, that twisted light and its pertinent optical vorticity and phase singularities began to come into widespread use in science and technol...

  16. Pretzelosity TMD and Quark Orbital Angular Momentum

    OpenAIRE

    Lorce, Cédric; Pasquini, B.

    2015-01-01

    We study the connection between the quark orbital angular momentum and the pretzelosity transverse-momentum dependent parton distribution function. We discuss the origin of this relation in quark models, identifying as key ingredient for its validity the assumption of spherical symmetry for the nucleon in its rest frame. Finally we show that the individual quark contributions to the orbital angular momentum obtained from this relation can not be interpreted as the intrinsic contributions, but...

  17. Topological Orbital Angular Momentum Hall Current

    OpenAIRE

    Hu, Jiangping

    2005-01-01

    We show that there is a fundamental difference between spin Hall current and orbital angular momentum Hall current in Rashba- Dresselhaus spin orbit coupling systems. The orbital angular momentum Hall current has a pure topological contribution which is originated from the existence of magnetic flux in momentum space while there is no such topological nature for the spin Hall current. Moreover, we show that the orbital Hall conductance is always larger than the spin Hall conductance in the pr...

  18. Complexation Studies of Bidentate Heterocyclic N-Donor Ligands with Nd(III) and Am(III)

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, Mark; Hoch, Courtney L.; Sinkov, Sergey I.; Meier, Patrick; Lumetta, Gregg J.; Nash, Kenneth L.

    2011-11-28

    A new bidentate nitrogen donor complexing agent that combines pyridine and triazole functional groups, 2-((4-phenyl-1H-1,2,3-triazol-1-yl)methyl)pyridine (PTMP), has been synthesized. The strength of its complexes with trivalent americium (Am3+) and neodymium (Nd3+) in anhydrous methanol has been evaluated using spectrophotometric techniques. The purpose of this investigation is to assess this ligand (as representative of a class of similarly structured species) as a possible model compound for the challenging separation of trivalent actinides from lanthanides. This separation, important in the development of advanced nuclear fuel cycles, is best achieved through the agency of multidentate chelating agents containing some number of nitrogen or sulfur donor groups. To evaluate the relative strength of the bidentate complexes, the derived constants are compared to those of the same metal ions with 2,2*-bipyridyl (bipy), 1,10-phenanthroline (phen), and 2-pyridin-2-yl-1H-benzimidazole (PBIm). At issue is the relative affinity of the triazole moiety for trivalent f element ions. For all ligands, the derived stability constants are higher for Am3+ than Nd3+. In the case of Am3+ complexes with phen and PBIm, the presence of 1:2 (AmL2) species is indicated. Possible separations are suggested based on the relative stability and stoichiometry of the Am3+ and Nd3+ complexes. It can be noted that the 1,2,3-triazolyl group imparts a potentially useful selectivity for trivalent actinides (An(III)) over trivalent lanthanides (Ln(III)), though the attainment of higher complex stoichiometries in actinide compared with lanthanide complexes may be an important driver for developing successful separations.

  19. Dirac Green function for angular projection potentials.

    Science.gov (United States)

    Zeller, Rudolf

    2015-11-25

    The aim of this paper is twofold: first, it is shown that the angular dependence of the Dirac Green function can be described analytically for potentials with non-local dependence on the angular variables if they are chosen as projection potentials in angular momentum space. Because the local dependence on the radial variable can be treated to any precision with present computing capabilities, this means that the Green function can be calculated practically exactly. Second, it is shown that a result of this kind not only holds for a single angular projection potential but also more generally, for instance if space is divided into non-overlapping cells and a separate angular projection potential is used in each cell. This opens the way for relativistic density-functional calculations within a different perspective than the conventional one. Instead of trying to obtain the density for a given potential approximately as well as possible, the density is determined exactly for non-local potentials which can approximate arbitrary local potentials as well as desired. PMID:26523824

  20. An orbital angular momentum spectrometer for electrons

    Science.gov (United States)

    Harvey, Tyler; Grillo, Vincenzo; McMorran, Benjamin

    2016-05-01

    With the advent of techniques for preparation of free-electron and neutron orbital angular momentum (OAM) states, a basic follow-up question emerges: how do we measure the orbital angular momentum state distribution in matter waves? Control of both the energy and helicity of light has produced a range of spectroscopic applications, including molecular fingerprinting and magnetization mapping. Realization of an analogous dual energy-OAM spectroscopy with matter waves demands control of both initial and final energy and orbital angular momentum states: unlike for photons, final state post-selection is necessary for particles that cannot be annihilated. We propose a magnetic field-based mechanism for quantum non-demolition measurement of electron OAM. We show that OAM-dependent lensing is produced by an operator of form U =exp iLzρ2/ℏb2 where ρ =√{x2 +y2 } is the radial position operator, Lz is the orbital angular momentum operator along z, and b is the OAM dispersion length. We can physically realize this operator as a term in the time evolution of an electron in magnetic round lens. We discuss prospects and practical challenges for implementation of a lensing orbital angular momentum measurement. This work was supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under the Early Career Research Program Award # DE-SC0010466.

  1. Angular distribution of oriented nucleus fission neutrons

    International Nuclear Information System (INIS)

    Calculations of anisotropy of angular distribution of oriented 235U nuclei thermal fission neutrons have been carried out. the neutrons were assumed to evaporate isotropically by completely accelerated fragements in the fragment system with only its small part, i. e. fission-producing neutrons, emitted at the moment of neck break. It has been found out that at low energies of neutrons Esub(n)=1-2 MeV the sensitivity of the angular distribution anisotropy to variations of spectrum of neutron evaporation from fragments and the magnitude of a share of fission-producing neutrons reaches approximately 100%, which at high energies, Esub(n) > 5 MeV it does not exceed approximately 20%. Therefore the angular distribution of fast neutrons to a greater degree of confidence may be used for restoring the angular distribution anisotropy of fragments while the angular distribution of low energy neutrons may be used for deriving information on the fission process, but only in case 6f the experiment accuracy is better than approximately 3%

  2. Dirac Green function for angular projection potentials

    Science.gov (United States)

    Zeller, Rudolf

    2015-11-01

    The aim of this paper is twofold: first, it is shown that the angular dependence of the Dirac Green function can be described analytically for potentials with non-local dependence on the angular variables if they are chosen as projection potentials in angular momentum space. Because the local dependence on the radial variable can be treated to any precision with present computing capabilities, this means that the Green function can be calculated practically exactly. Second, it is shown that a result of this kind not only holds for a single angular projection potential but also more generally, for instance if space is divided into non-overlapping cells and a separate angular projection potential is used in each cell. This opens the way for relativistic density-functional calculations within a different perspective than the conventional one. Instead of trying to obtain the density for a given potential approximately as well as possible, the density is determined exactly for non-local potentials which can approximate arbitrary local potentials as well as desired.

  3. Released ligand fluoroimmunoassay

    International Nuclear Information System (INIS)

    Radioimmunoassay (RIA) is one of the most sensitive and specific methods for analysis of proteins, drugs and other substances commonly found in biological fluids. Because of the limited stability and problems in handling radioisotopes (particularly 125I), there has been a continuous effort in recent years to develop non-isotopic immunoassays. Fluoroimmunoassay is one of the more promising alternatives to RIA, but has relatively low sensitivity due to background fluorescence from other substances in biological fluids. The authors have proposed an alternative type of fluoroimmunoassay, released ligand fluoroimmunoassay (RLFIA), wherein the fluorophore is released from the analyte and analyzed separately, thus reducing the problems of background fluorescence. 1-(4-(3-(2,3-dihydroxy-1-carboxyethyl))-phenyl)-3-(3-(7-diethylamino-4-methylcoumarinyl)) thiourea (IX), a fluorescent coumarin derivative with a periodate cleavable vic-glycol linkage, was synthesized and employed to demonstrate the principle of RLFIA. The principle of the RLFIA was tested by comparison with a commercially available kit Immuno-Fluor IgG Assay. Because of the lower quantum yield of the fluorophore used, the sensitivity of the resulting RLFIA was only one tenth that of the commercial kit. As an outgrowth of this project, a series of analogs of compound IX, having electron donating and withdrawing groups at the phenyl ring, were synthesized in order to study the effect of substituent on fluorescence yield. An interactive computer graphics system, Chemical Structure Drawing 2-Dimensional (CSD2D), developed by the author mainly for the generation of publication quality structure drawings is also described

  4. Data-oriented development with AngularJS

    CERN Document Server

    Waikar, Manoj

    2015-01-01

    This book helps beginner-level AngularJS developers organize AngularJS applications by discussing important AngularJS concepts and best practices. If you are an experienced AngularJS developer but haven't written directives or haven't created custom HTML controls before, then this book is ideal for you.

  5. Variation in Angular Velocity and Angular Acceleration of a Particle in Rectilinear Motion

    Science.gov (United States)

    Mashood, K. K.; Singh, V. A.

    2012-01-01

    We discuss the angular velocity ([image omitted]) and angular acceleration ([image omitted]) associated with a particle in rectilinear motion with constant acceleration. The discussion was motivated by an observation that students and even teachers have difficulty in ascribing rotational motion concepts to a particle when the trajectory is a…

  6. Nutraceuticals as Ligands of PPARγ

    OpenAIRE

    Meera Penumetcha; Nalini Santanam

    2012-01-01

    Peroxisome proliferator-activated receptors (PPARs) are ligand-activated nuclear receptors that respond to several exogenous and endogenous ligands by modulating genes related to lipid, glucose, and insulin homeostasis. PPARγ, expressed in adipose tissue and liver, regulates lipid storage and glucose metabolism and is the target of type 2 diabetes drugs, thiazolidinediones (TZDs). Due to high levels of toxicity associated with the first generation TZDs, troglitazone (Rezulin), rosiglitazone (...

  7. Validity of Ligand Efficiency Metrics

    OpenAIRE

    Murray, Christopher W; Erlanson, Daniel A.; Hopkins, Andrew L.; Keserü, György M; Leeson, Paul D.; Rees, David C.; Reynolds, Charles H.; Richmond, Nicola J.

    2014-01-01

    A recent viewpoint article (Improving the plausibility of success with inefficient metrics. ACS Med. Chem. Lett.2014, 5, 2–5) argued that the standard definition of ligand efficiency (LE) is mathematically invalid. In this viewpoint, we address this criticism and show categorically that the definition of LE is mathematically valid. LE and other metrics such as lipophilic ligand efficiency (LLE) can be useful during the multiparameter optimization challenge faced by med...

  8. Ligand Identification Scoring Algorithm (LISA)

    Science.gov (United States)

    Zheng, Zheng; Merz, Kenneth M.

    2011-01-01

    A central problem in de novo drug design is determining the binding affinity of a ligand with a receptor. A new scoring algorithm is presented that estimates the binding affinity of a protein-ligand complex given a three-dimensional structure. The method, LISA (Ligand Identification Scoring Algorithm), uses an empirical scoring function to describe the binding free energy. Interaction terms have been designed to account for van der Waals (VDW) contacts, hydrogen bonding, desolvation effects and metal chelation to model the dissociation equilibrium constants using a linear model. Atom types have been introduced to differentiate the parameters for VDW, H-bonding interactions and metal chelation between different atom pairs. A training set of 492 protein-ligand complexes was selected for the fitting process. Different test sets have been examined to evaluate its ability to predict experimentally measured binding affinities. By comparing with other well known scoring functions, the results show that LISA has advantages over many existing scoring functions in simulating protein-ligand binding affinity, especially metalloprotein-ligand binding affinity. Artificial Neural Network (ANN) was also used in order to demonstrate that the energy terms in LISA are well designed and do not require extra cross terms. PMID:21561101

  9. Angular analyses in relativistic quantum mechanics

    International Nuclear Information System (INIS)

    This work describes the angular analysis of reactions between particles with spin in a fully relativistic fashion. One particle states are introduced, following Wigner's method, as representations of the inhomogeneous Lorentz group. In order to perform the angular analyses, the reduction of the product of two representations of the inhomogeneous Lorentz group is studied. Clebsch-Gordan coefficients are computed for the following couplings: l-s coupling, helicity coupling, multipolar coupling, and symmetric coupling for more than two particles. Massless and massive particles are handled simultaneously. On the way we construct spinorial amplitudes and free fields; we recall how to establish convergence theorems for angular expansions from analyticity hypothesis. Finally we substitute these hypotheses to the idea of 'potential radius', which gives at low energy the usual 'centrifugal barrier' factors. The presence of such factors had never been deduced from hypotheses compatible with relativistic invariance. (author)

  10. Physics from Angular Projection of Rectangular Grids

    CERN Document Server

    Singh, Ashmeet

    2015-01-01

    In this paper, we present a mathematical model for the angular projection of a rectangular arrangement of points in a grid. This simple, yet interesting problem, has both a scholarly value and applications for data extraction techniques to study the physics of various systems. Our work can interest undergraduate students to understand subtle points in the angular projection of a grid and describes various quantities of interest in the projection with completeness and sufficient rigour. We show that for certain angular ranges, the projection has non-distinctness, and calculate the details of such angles, and correspondingly, the number of distinct points and the total projected length. We focus on interesting trends obtained for the projected length of the grid elements and present a simple application of the model to determine the geometry of an unknown grid whose spatial extensions are known, using measurement of the grid projection at two angles only. Towards the end, our model is shown to have potential ap...

  11. Localizing the Angular Momentum of Linear Gravity

    CERN Document Server

    Butcher, Luke M; Hobson, Michael; 10.1103/PhysRevD.86.084012

    2012-01-01

    In a previous article [Phys. Rev. D 82 104040 (2010)], we derived an energy-momentum tensor for linear gravity that exhibited positive energy density and causal energy flux. Here we extend this framework by localizing the angular momentum of the linearized gravitational field, deriving a gravitational spin tensor which possesses similarly desirable properties. By examining the local exchange of angular momentum (between matter and gravity) we find that gravitational intrinsic spin is localized, separately from orbital angular momentum, in terms of a gravitational spin tensor. This spin tensor is then uniquely determined by requiring that it obey two simple physically motivated algebraic conditions. Firstly, the spin of an arbitrary (harmonic-gauge) gravitational plane wave is required to flow in the direction of propagation of the wave. Secondly, the spin tensor of any transverse-traceless gravitational field is required to be traceless. (The second condition ensures that local field redefinitions suffice to ...

  12. Quark orbital angular momentum from lattice QCD

    Energy Technology Data Exchange (ETDEWEB)

    Mathur, N.; Dong, S. J.; Liu, K. F.; Mankiewicz, L.; Mukhopadhyay, N. C.

    2000-12-01

    We calculate the quark orbital angular momentum of the nucleon from the quark energy-momentum tensor form factors on the lattice with the quenched approximation. The disconnected insertion is estimated stochastically which employs the Z{sub 2} noise with an unbiased subtraction. This reduced the error by a factor of 3--4 with negligible overhead. The total quark contribution to the proton spin is found to be 0.30{+-}0.07. From this and the quark spin content we deduce the quark orbital angular momentum to be 0.17{+-}0.06 which is {approx}34% of the proton spin. We further predict that the gluon angular momentum is 0.20{+-}0.07; i.e., {approx}40% of the proton spin is due to the glue.

  13. Quark orbital angular momentum from lattice QCD

    Energy Technology Data Exchange (ETDEWEB)

    Liu, K.F.

    2000-01-10

    The authors calculate the quark orbital angular momentum of the nucleon from the quark energy-momentum tensor form factors on the lattice. The disconnected insertion is estimated stochastically which employs the Z{sub 2} noise with an unbiased subtraction. This reduced the error by a factor of 4 with negligible overhead. The total quark contribution to the proton spin is found to be 0.30{+-}0.07. From this and the quark spin content the authors deduce the quark orbital angular momentum to be 0.17{+-}0.06 which is {approximately} 34% of the proton spin. The authors further predict that the gluon angular momentum to be 0.20{+-}0.07, i. e. {approximately} 40% of the proton spin is due to the glue.

  14. Quark orbital angular momentum from lattice QCD

    International Nuclear Information System (INIS)

    The authors calculate the quark orbital angular momentum of the nucleon from the quark energy-momentum tensor form factors on the lattice. The disconnected insertion is estimated stochastically which employs the Z2 noise with an unbiased subtraction. This reduced the error by a factor of 4 with negligible overhead. The total quark contribution to the proton spin is found to be 0.30±0.07. From this and the quark spin content the authors deduce the quark orbital angular momentum to be 0.17±0.06 which is ∼ 34% of the proton spin. The authors further predict that the gluon angular momentum to be 0.20±0.07, i. e. approximately 40% of the proton spin is due to the glue

  15. Quark orbital angular momentum from lattice QCD

    International Nuclear Information System (INIS)

    We calculate the quark orbital angular momentum of the nucleon from the quark energy-momentum tensor form factors on the lattice with the quenched approximation. The disconnected insertion is estimated stochastically which employs the Z2 noise with an unbiased subtraction. This reduced the error by a factor of 3--4 with negligible overhead. The total quark contribution to the proton spin is found to be 0.30±0.07. From this and the quark spin content we deduce the quark orbital angular momentum to be 0.17±0.06 which is ∼34% of the proton spin. We further predict that the gluon angular momentum is 0.20±0.07; i.e., ∼40% of the proton spin is due to the glue

  16. Ghost Imaging Using Orbital Angular Momentum

    International Nuclear Information System (INIS)

    We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum. In the signal arm, object spatial information is encoded as a phase matrix. For an N-grey-scale object, different phase matrices, varying from 0 to π with increment π/N, are used for different greyscales, and then they are modulated to a signal beam by a spatial light modulator. According to the conservation of the orbital angular momentum in the ghost imaging system, these changes will give different coincidence rates in measurement, and hence the object information can be extracted in the idler arm. By simulations and experiments, the results show that our scheme can improve the resolution of the image effectively. Compared with another encoding method using orbital angular momentum, our scheme has a better performance for both characters and the image object. (fundamental areas of phenomenology(including applications))

  17. Chirality and angular momentum in optical radiation

    CERN Document Server

    Coles, Matt M

    2012-01-01

    This paper develops, in precise quantum electrodynamic terms, photonic attributes of the "optical chirality density", one of several measures long known to be conserved quantities for a vacuum electromagnetic field. The analysis lends insights into some recent interpretations of chiroptical experiments, in which this measure, and an associated chirality flux, have been treated as representing physically distinctive "superchiral" phenomena. In the fully quantized formalism the chirality density is promoted to operator status, whose exploration with reference to an arbitrary polarization basis reveals relationships to optical angular momentum and helicity operators. Analyzing multi-mode beams with complex wave-front structures, notably Laguerre-Gaussian modes, affords a deeper understanding of the interplay between optical chirality and optical angular momentum. By developing theory with due cognizance of the photonic character of light, it emerges that only the spin angular momentum of light is engaged in such...

  18. Radio beam vorticity and orbital angular momentum

    CERN Document Server

    Thidé, Bo; Mari, Elettra; Romanato, Filippo; Barbieri, Cesare

    2011-01-01

    It has been known for a century that electromagnetic fields can transport not only energy and linear momentum but also angular momentum. However, it was not until twenty years ago, with the discovery in laser optics of experimental techniques for the generation, detection and manipulation of photons in well-defined, pure orbital angular momentum (OAM) states, that twisted light and its pertinent optical vorticity and phase singularities began to come into widespread use in science and technology. We have now shown experimentally how OAM and vorticity can be readily imparted onto radio beams. Our results extend those of earlier experiments on angular momentum and vorticity in radio in that we used a single antenna and reflector to directly generate twisted radio beams and verified that their topological properties agree with theoretical predictions. This opens the possibility to work with photon OAM at frequencies low enough to allow the use of antennas and digital signal processing, thus enabling software con...

  19. Angular momentum transfer in incomplete fusion

    Indian Academy of Sciences (India)

    B S Tomar; K Surendra Babu; K Sudarshan; R Tripathi; A Goswami

    2005-02-01

    Isomeric cross-section ratios of evaporation residues formed in 12C+93Nb and 16O + 89Y reactions were measured by recoil catcher technique followed by off-line -ray spectrometry in the beam energy range of 55.7-77.5 MeV for 12C and 68-81 MeV for 16O. The isomeric cross-section ratios were resolved into that for complete and incomplete fusion reactions. The angular momentum of the intermediate nucleus formed in incomplete fusion was deduced from the isomeric cross-section ratio by considering the statistical de-excitation of the incompletely fused composite nucleus. The data show that incomplete fusion is associated with angular momenta slightly smaller than critical angular momentum for complete fusion, indicating the deeper interpenetration of projectile and target nuclei than that in peripheral collisions.

  20. Angular momentum alignment in molecular beam scattering

    International Nuclear Information System (INIS)

    It is shown how the angular momentum alignment in a molecular beam can be determined using laser-induced fluorescence in combination with precession of the angular momenta in a magnetic field. After a general analysis of the method, some results are presented to illustrate the possibilities of the method. Experimental data are presented on the alignment production for Na2 molecules that made a collision induced angular momentum transition. Magnitude as well as direction of the alignment have been determined for scattering with several scattering partners and for a large number of scattering angles and transitions. The last chapter deals with the total alignment production in a final J-state, i.e. without state selection of the initial rotational state. (orig.)

  1. Ghost Imaging Using Orbital Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    赵生妹; 丁建; 董小亮; 郑宝玉

    2011-01-01

    We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum. In the signal arm, object spatial information is encoded as a phase matrix. For an N-grey-scale object, different phase matrices, varying from 0 to K with increment n/N, are used for different greyscales, and then they are modulated to a signal beam by a spatial light modulator. According to the conservation of the orbital angular momentum in the ghost imaging system, these changes will give different coincidence rates in measurement, and hence the object information can be extracted in the idler arm. By simulations and experiments, the results show that our scheme can improve the resolution of the image effectively. Compared with another encoding method using orbital angular momentum, our scheme has a better performance for both characters and the image object.%We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum.In the signal arm,object spatial information is encoded as a phase matrix.For an N-grey-scale object,different phase matrices,varying from 0 to π with increment π/N,are used for different greyscales,and then they are modulated to a signal beam by a spatial light modulator.According to the conservation of the orbital angular momentum in the ghost imaging system,these changes will give different coincidence rates in measurement,and hence the object information can be extracted in the idler arm.By simulations and experiments,the results show that our scheme can improve the resolution of the image effectively.Compared with another encoding method using orbital angular momentum,our scheme has a better performance for both characters and the image object.

  2. Concepts of radial and angular kinetic energies

    DEFF Research Database (Denmark)

    Dahl, Jens Peder; Schleich, W.P.

    2002-01-01

    We consider a general central-field system in D dimensions and show that the division of the kinetic energy into radial and angular parts proceeds differently in the wave-function picture and the Weyl-Wigner phase-space picture, Thus, the radial and angular kinetic energies are different quantities...... in the two pictures, containing different physical information, but the relation between them is well defined. We discuss this relation and illustrate its nature by examples referring to a free particle and to a ground-state hydrogen atom....

  3. Time-resolved orbital angular momentum spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Noyan, Mehmet A.; Kikkawa, James M. [Department of Physics and Astronomy, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)

    2015-07-20

    We introduce pump-probe magneto-orbital spectroscopy, wherein Laguerre-Gauss optical pump pulses impart orbital angular momentum to the electronic states of a material and subsequent dynamics are studied with 100 fs time resolution. The excitation uses vortex modes that distribute angular momentum over a macroscopic area determined by the spot size, and the optical probe studies the chiral imbalance of vortex modes reflected off the sample. First observations in bulk GaAs yield transients that evolve on time scales distinctly different from population and spin relaxation, as expected, but with surprisingly large lifetimes.

  4. Time-resolved orbital angular momentum spectroscopy

    International Nuclear Information System (INIS)

    We introduce pump-probe magneto-orbital spectroscopy, wherein Laguerre-Gauss optical pump pulses impart orbital angular momentum to the electronic states of a material and subsequent dynamics are studied with 100 fs time resolution. The excitation uses vortex modes that distribute angular momentum over a macroscopic area determined by the spot size, and the optical probe studies the chiral imbalance of vortex modes reflected off the sample. First observations in bulk GaAs yield transients that evolve on time scales distinctly different from population and spin relaxation, as expected, but with surprisingly large lifetimes

  5. Wilson lines and orbital angular momentum

    International Nuclear Information System (INIS)

    We present an explicit realization of the Chen et al. approach to the proton spin decomposition in terms of Wilson lines, generalizing the light-front gauge-invariant extensions discussed recently by Hatta. Particular attention is drawn to the residual gauge freedom by further separating the pure-gauge term into contour and residual terms. We show that the kinetic orbital angular momentum operator can be expressed in terms of the Wigner operator only when the momentum variable is integrated over. Finally, we confirm from twist-2 arguments that the advanced, retarded and antisymmetric light-front canonical orbital angular momenta are the same

  6. Quark Orbital Angular Momentum from Lattice QCD

    OpenAIRE

    N. Mathur; Dong, S. J.; Liu, K. F.; Mankiewicz, L.; Mukhopadhyay, N. C.

    1999-01-01

    We calculate the quark orbital angular momentum of the nucleon from the quark energy-momentum tensor form factors on the lattice. The disconnected insertion is estimated stochastically which employs the $Z_2$ noise with an unbiased subtraction. This reduced the error by a factor of 4 with negligible overhead. The total quark contribution to the proton spin is found to be $0.30 \\pm 0.07$. From this and the quark spin content we deduce the quark orbital angular momentum to be $0.17 \\pm 0.06$ wh...

  7. Wilson lines and orbital angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Lorcé, Cédric, E-mail: cedric.lorce@googlemail.com [IPNO, Université Paris-Sud, CNRS/IN2P3, 91406 Orsay (France); LPT, Université Paris-Sud, CNRS, 91406 Orsay (France)

    2013-02-12

    We present an explicit realization of the Chen et al. approach to the proton spin decomposition in terms of Wilson lines, generalizing the light-front gauge-invariant extensions discussed recently by Hatta. Particular attention is drawn to the residual gauge freedom by further separating the pure-gauge term into contour and residual terms. We show that the kinetic orbital angular momentum operator can be expressed in terms of the Wigner operator only when the momentum variable is integrated over. Finally, we confirm from twist-2 arguments that the advanced, retarded and antisymmetric light-front canonical orbital angular momenta are the same.

  8. Angular momentum transfer in deep inelastic scattering

    International Nuclear Information System (INIS)

    The measured γ-ray multiplicities as a function of exit channel kinetic energy and mass asymmetry for the reactions Au, Ho, Ag + 620 MeV Kr are compared with a diffusion calculation based exclusively upon particle transfer and which reproduces the Z distributions as well as the angular distributions as function of Z. The model correctly predicts the energy and Z dependence of the γ-ray multiplicities, thus lending support to the one-body model on one hand and to the angular-momentum fractionation along the mass asymmetry coordinate on the other

  9. Angular momentum and the electromagnetic top

    Indian Academy of Sciences (India)

    GIANFRANCO SPAVIERI; GEORGE T GILLIES

    2016-08-01

    The electric charge–magnetic dipole interaction is considered. If $\\Gamma_{\\rm em}$ is the electromagnetic and $\\Gamma_{\\rm mech}$ the mechanical angular momentum, the conservation law for the total angular momentum $\\Gamma_{\\rm tot}$ holds: $\\Gamma_{\\rm tot}$ =$\\Gamma_{\\rm em}$ + $\\Gamma_{\\rm mech}$ = ${\\rm const.}$, but when the dipole moment varies with time, $\\Gamma_{\\rm mech}$ is not conserved. We show that the non-conserved $\\Gamma_{\\rm mech}$ of such a macroscopic isolated system might be experimentally observable. With advanced technology, the strength of the interaction hints to the possibility of novel applications for gyroscopes, such as the electromagnetic top.

  10. Orbital angular momentum in the nucleons

    CERN Document Server

    Lorcé, Cédric

    2014-01-01

    In the last decade, it has been realized that the orbital angular momentum of partons inside the nucleon plays a major role. It contributes significantly to nucleon properties and is at the origin of many asymmetries observed in spin physics. It is therefore of paramount importance to determine this quantity if we want to understand the nucleon internal structure and experimental observables. This triggered numerous discussions and controversies about the proper definition of orbital angular momentum and its extraction from experimental data. We summarize the present situation and discuss recent developments in this field.

  11. Wilson lines and orbital angular momentum

    CERN Document Server

    Lorcé, Cédric

    2012-01-01

    We present an explicit realization of the Chen et al. approach to the proton spin decomposition in terms of Wilson lines, generalizing the light-front gauge-invariant extensions discussed recently by Hatta. Particular attention is drawn to the residual gauge freedom by further separating the pure-gauge term into contour and residual terms. Contrarily to a recent claim, we show that the Wigner distributions do not give access to the kinetic orbital angular momentum. Finally, we confirm from twist-2 arguments that the advanced, retarded and antisymmetric light-front canonical orbital angular momenta are the same.

  12. Probing Angular Correlations in Sequential Double Ionization

    International Nuclear Information System (INIS)

    We study electron correlation in sequential double ionization of noble gas atoms and HCl in intense, femtosecond laser pulses. We measure the photoelectron angular distributions of Ne+ relative to the first electron in a pump-probe experiment with 8 fs, 800 nm, circularly polarized laser pulses at a peak intensity of a few 1015 W/cm2. Using a linear-linear pump-probe setup, we further study He, Ar, and HCl. We find a clear angular correlation between the two ionization steps in the sequential double ionization intensity regime.

  13. On the vector model of angular momentum

    Science.gov (United States)

    Saari, Peeter

    2016-09-01

    Instead of (or in addition to) the common vector diagram with cones, we propose to visualize the peculiarities of quantum mechanical angular momentum by a completely quantized 3D model. It spotlights the discrete eigenvalues and noncommutativity of components of angular momentum and corresponds to outcomes of measurements—real or computer-simulated. The latter can be easily realized by an interactive worksheet of a suitable program package of algebraic calculations. The proposed complementary method of visualization helps undergraduate students to better understand the counterintuitive properties of this quantum mechanical observable.

  14. γ - γ Angular Correlation Measurements With GRIFFIN

    Science.gov (United States)

    Maclean, Andrew; Griffin Collaboration

    2015-10-01

    When an excited nuclear state emits successive γ-rays causing a γ - γ cascade an anisotropy is found in the spatial distribution of γ2 with respect to γ1. Defining the direction of γ1 as the z-axis, the intermediate level, in general will have an uneven distribution of m-states. This causes an anisotropy in the angular correlation of the second γ-ray with respect to the first. These angular correlations are expressed by the W (θ) that depends on numerical coefficients described by the sequence of spin-parity values for the nuclear states involved, the multipolarities and mixing ratios. Angular correlations can be used for the assignment of spins and parities for the nuclear states, and thus provide a powerful means to elucidate the structure of nuclei far from stability through β - γ - γ coincidence measurements. In order to explore the sensitivity of the new 16 clover-detector GRIFFIN γ-ray spectrometer at TRIUMF-ISAC to such γ - γ angular correlations, and to optimize its performance for these measurements we have studied a well known γ - γ cascade from 60Co decay through both experimental measurements and Geant4 simulation. Results will be shown in this talk. Work supported by the Canada Foundation for Innovation, the Natural Sciences and Engineering Research Council of Canada and the National Research Council of Canada.

  15. Angular-momentum-bearing modes in fission

    International Nuclear Information System (INIS)

    The angular-momentum-bearing degrees of freedom involved in the fission process are identified and their influence on experimental observables is discussed. The excitation of these modes is treated in the ''thermal'' limit, and the resulting distributions of observables are calculated. Experiments demonstrating the role of these modes are presented and discussed. 61 refs., 12 figs

  16. On the "initial" Angular Momentum of Galaxies

    CERN Document Server

    Abel, T; Hernquist, L E; Abel, Tom; Croft, Rupert C.; Hernquist, Lars

    2001-01-01

    Spherical density profiles and specific angular momentum profiles of Dark Matter halos found in cosmological N-body simulations have been measured extensively. The distribution of the total angular momentum of dark matter halos is also used routinely in semi-analytic modeling of the formation of disk galaxies. However, it is unclear whether the initial (i.e. at the time the halo is assembled) angular momentum distributions of baryons is related to the dark matter at all. Theoretical models for ellipticities in weak lensing studies often rely on an assumed correlation of the angular momentum vectors of dark matter and gas in galaxies. Both of these assumptions are shown to be in reasonable agreement with high resolution cosmological smoothed particle hydrodynamical simulations that follow the dark matter as long as only adiabatic gas physics are included. However, we argue that in more realistic models of galaxy formation one expects pressure forces to play a significant role at turn--around. Consequently the ...

  17. Quantum Entanglement of High Angular Momenta

    International Nuclear Information System (INIS)

    Full text: Orbital angular momentum (OAM) of single photons represents a relatively novel optical degree of freedom for the entanglement of photons. One physical realization of OAM carrying light beams are the so called Laguerre-Gaussian modes which have the required helical phase structure. One big advantage over the well-known polarization degree of freedom is the possibility of realizing entanglement between two photons with very high quantum numbers and momenta respectively. However, the creation of photonic OAM entanglement by the widely used spontaneous parametric down conversion (SPDC) process is limited by the strongly reduced efficiency for higher momenta. We have realized a novel method to create entanglement between two photons which is not constrained by the SPDC efficiency or conservation law for the OAM degree of freedom. We created and measured the entanglement of two photons with up to 600ħ difference in their angular momentum by transferring the polarization entanglement to the orbital angular momentum degree of freedom within an interferometric scheme. Additionally, we used hybrid entangled biphoton states between polarization and OAM to show the angular resolution enhancement in possible remote sensing applications. (author)

  18. Wigner Functions and Quark Orbital Angular Momentum

    OpenAIRE

    Mukherjee Asmita; Nair Sreeraj; Ojha Vikash Kumar

    2014-01-01

    Wigner distributions contain combined position and momentum space information of the quark distributions and are related to both generalized parton distributions (GPDs) and transverse momentum dependent parton distributions (TMDs). We report on a recent model calculation of the Wigner distributions for the quark and their relation to the orbital angular momentum.

  19. Photon Orbital Angular Momentum in Astrophysics

    OpenAIRE

    Harwit, Martin

    2003-01-01

    Astronomical observations of the orbital angular momentum of photons, a property of electromagnetic radiation that has come to the fore in recent years, have apparently never been attempted. Here, I show that measurements of this property of photons have a number of astrophysical applications.

  20. Wigner Functions and Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Mukherjee Asmita

    2015-01-01

    Full Text Available Wigner distributions contain combined position and momentum space information of the quark distributions and are related to both generalized parton distributions (GPDs and transverse momentum dependent parton distributions (TMDs. We report on a recent model calculation of the Wigner distributions for the quark and their relation to the orbital angular momentum.

  1. A Novel Permanent Magnetic Angular Acceleration Sensor

    Directory of Open Access Journals (Sweden)

    Hao Zhao

    2015-07-01

    Full Text Available Angular acceleration is an important parameter for status monitoring and fault diagnosis of rotary machinery. Therefore, we developed a novel permanent magnetic angular acceleration sensor, which is without rotation angle limitations and could directly measure the instantaneous angular acceleration of the rotating system. The sensor rotor only needs to be coaxially connected with the rotating system, which enables convenient sensor installation. For the cup structure of the sensor rotor, it has a relatively small rotational inertia. Due to the unique mechanical structure of the sensor, the output signal of the sensor can be directed without a slip ring, which avoids signal weakening effect. In this paper, the operating principle of the sensor is described, and simulated using finite element method. The sensitivity of the sensor is calibrated by torsional pendulum and angle sensor, yielding an experimental result of about 0.88 mV/(rad·s−2. Finally, the angular acceleration of the actual rotating system has been tested, using both a single-phase asynchronous motor and a step motor. Experimental result confirms the operating principle of the sensor and indicates that the sensor has good practicability.

  2. Critical gravitational collapse with angular momentum

    CERN Document Server

    Gundlach, Carsten

    2016-01-01

    We derive a theoretical model of mass and angular momentum scaling in type-II critical collapse with rotation. We focus on the case where the critical solution has precisely one, spherically symmetric, unstable mode. We demonstrate excellent agreement with numerical results for critical collapse of a rotating radiation fluid, which falls into this case.

  3. Coulomb functions with complex angular momenta

    International Nuclear Information System (INIS)

    The subroutine CCOULM calculates regular and irregular Coulomb functions and their derivatives associated with complex angular momenta. This program may thus be used, for example, in locating Regge poles that appear in atomic and nuclear scattering problems. The calculation utilized the asymptotic expansion method of Froeberg. (Auth.)

  4. Probabilistic calculation for angular dependence collision

    International Nuclear Information System (INIS)

    This collision probabilistic method is broadly used in cylindrical geometry (in one- or two-dimensions). It constitutes a powerful tool for the heterogeneous Response Method where, the coupling current is of the cosine type, that is, without angular dependence at azimuthal angle θ and proportional to μ (cosine of the θ polar angle). (Author)

  5. Miniaturized photoelectric angular sensor with simplified design

    Science.gov (United States)

    Dumbravescu, Niculae; Schiaua, Silviu

    1999-09-01

    In building the movable elements of robots, peripheral devices and measuring apparata, increasing the resolution of the angular sensor systems, based on incremental rotary encoders, is essential, together with decreasing the complexity, dimensions and weight. Especially when the angular sensor is integrated in a measuring system, belonging to a programmed light airplane for surveillance, the key issue is to reduce both dimensions and weight. This can be done using a simplified design, which consists in the following solutions: replacement of the fragile Cr on glass substrate, 1.5 mm thick (normally used for the fabrication of incremental disks), with light Cr on polycarbonate substrate, with only 0.15 mm thick; the absence of collimating optics (based on microlenses, used in IR emitter-photocell receiver assembly), as a result of the good coupling efficiency (due to the possible approaching of these elements at minimum 0.45 mm); the shrinkage of the disk's diameters to only 14 mm; the use of surface mounting devices and the related surface mounting technology, enabling to reduce dimensions and weight. The maximum number of slits on a 14 mm diameter dividing disk, usually obtained in a Cr on polycarbonate version, being approx. 1000, no problem occurs in our case, for 360 slits. The requested angular resolution (only 0.5 degrees for the light airplane), using the whole classical '4x digital multiplication' is not necessary, but a lower one of only 2x, resulting in a simplified electronics. The proposed design permitted, that an original arrangement, for building a small size, lightweight, heavy-duty incremental transducer based angular sensor system, to be obtained, useful not only in avionics, but also in robotics, or other special applications. Besides, extending the number of fixed gratings (masks) allows, that many primary signals to be derived, and a further increase in resolution of even 6 angular minutes to be obtained from the initial 360 slits.

  6. Why mercury prefers soft ligands

    Energy Technology Data Exchange (ETDEWEB)

    Riccardi, Demian M [ORNL; Guo, Hao-Bo [ORNL; Gu, Baohua [ORNL; Parks, Jerry M [ORNL; Summers, Anne [University of Georgia, Athens, GA; Miller, S [University of California, San Francisco; Liang, Liyuan [ORNL; Smith, Jeremy C [ORNL

    2013-01-01

    Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources. Defining the factors that determine the relative affinities of different ligands for the mercuric ion, Hg2+, is critical to understanding its speciation, transformation, and bioaccumulation in the environment. Here, we use quantum chemistry to dissect the relative binding free energies for a series of inorganic anion complexes of Hg2+. Comparison of Hg2+ ligand interactions in the gaseous and aqueous phases shows that differences in interactions with a few, local water molecules led to a clear periodic trend within the chalcogenide and halide groups and resulted in the well-known experimentally observed preference of Hg2+ for soft ligands such as thiols. Our approach establishes a basis for understanding Hg speciation in the biosphere.

  7. A detection system with broad angular acceptance for particle identification and angular distribution measurements

    International Nuclear Information System (INIS)

    A new detection system for time-optimized heavy-ion angular distribution measurements has been designed and constructed. This device is composed by an ionization chamber with a segmented-grid anode and three position-sensitive silicon detectors. This particular arrangement allows identifying reaction products emitted within a 30° wide angular range with better than 1° angular resolution. As a demonstration of its capabilities, angular distributions of the elastic scattering cross-section and the production of alpha particles in the 7Li+27Al system, at an energy above the Coulomb barrier, are presented. -- Highlights: • We constructed a detection system for time-optimized heavy-ion angular distribution measurements. • We characterized this device and obtained an energy resolution of 3% and an angular resolution of 1°. • We measured elastic scattering cross-sections in 7Li+27Al finding good agreement with previous data. • The performed tests included the measurement of alpha particle production cross-sections in 7Li+27Al

  8. Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes

    Indian Academy of Sciences (India)

    Adewale O Adeloye; Peter A Ajibade; Frances R Cummings; Lukas J Le Roux; Sampson N Mamphweli; Edson L Meyer

    2013-01-01

    Four new amphiphilic ligands: 4-(2,3-dimethylacrylic acid)-2,2'-bipyridine (L1), 4-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-2,2'-bipyridine (L2), 5-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L3) and 5-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L4), with their corresponding homonuclear ruthenium(II) complexes formulated as cis-[Ru-(L1)3(PF6)2] (C1), cis-[Ru-(L2)3(PF6)2] (C2), cis-[Ru-(L3)3(PF6)2] (C3) and cis-[Ru-(L4)3(PF6)2] (C4), have been synthesized and characterized by elemental analysis, 1H- and 13C- NMR, FT-IR, UV-Vis and photoluminescence spectroscopy. The complexes exhibit broad and intense metal-to-ligand charge transfer (MLCT) transition bands in the visible region (400-700 nm), and red light emitting properties at room temperature. By comparison however, complexes C1 and C2 bipyridine moiety gave lower molar absorptivity coefficient at relatively similar wavelength characteristics (410-520 nm) when compared to C3 and C4 with phenanthroline based molecules. Cyclic voltammograms of the complexes revealed complex C4 with most reduction potential which might be due to increase in the conjugation of the anthracene functionalized units. Preliminary investigation of the solar cell efficiency of the complexes on TiO2 nanocrystalline films gave the best result with efficiency of 0.103% for C1 under illumination at 1000 W/m2 AM 1.5. Electrochemical impedance spectroscopy (EIS) technique however, revealed the charge transfer resistances (Rct) of the electrons on the TiO2 semiconductor.

  9. Studies on the uptake of some lanthanides on y-zirconium phosphate - phoshite and its 1,10-phenanthroline and 2,2- bipyridyl intercalated products by tracer technique

    International Nuclear Information System (INIS)

    y-zirconium phosphate-phosphite, yZr, PO4.H2PO3.2H2O, (yZrPP), was prepared and characterized. Direct treatment of yzirconium phosphate-phosphite with ethanol solution of 0.1 M 1,10 phenanthrolin and 2,2-bipyridyl gave well defined composites, yZr.PO4H2PO3. (bipy)0.18.0.6H2O respectively. Kd values of a mixture of lanthanide metal ions; La3+, Sm3+, Eu3+, and YB3+ on the resulted intercalated products and on yZrPP were determined by radio tracer technique in HNO3 solution at room temperature and at pH =2 and 4. The radio isotopes 140La, 152mEu, 153Sm, 175Yb were used for the equilibration experiment using 500 ul (4.0 x 10-5m. mole) each of the solutions of the tracers as a mixture plus 7.5M HNO3 solution of the desired pH to 0.1 gm of y-ZrPP and of the roducts for 24 hrs

  10. Hydrogen bonded NHO chains formed by chloranilic acid (CLA) with 4,4‧-di-t-butyl-2,2‧-bipyridyl (dtBBP) in the solid state

    Science.gov (United States)

    Bator, G.; Sawka-Dobrowolska, W.; Sobczyk, L.; Owczarek, M.; Pawlukojć, A.; Grech, E.; Nowicka-Scheibe, J.

    2012-01-01

    In crystalline state 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) forms with 4,4'-di-t-butyl-2,2'-bipyridyl (dtBBP) the hydrogen bonded chains along the b-axis. From one side of the CLA molecule the proton transfer takes place and the hydrogen bond length is very short (2.615 Å). A continuous infrared absorption is observed for dtBBP·CLA in the wavenumber range between 3100 and 800 cm -1 also indicating the strong hydrogen bonds. The DSC measurements show a weak, close to continuous, phase transition at 414 K. The complex dielectric permittivity for a single crystal sample was measured in the temperature range 100-440 K and at frequencies between 200 Hz and 2 MHz. The dielectric response is a combination of semiconducting properties and a relaxation process most probably connected with the proton dynamics in the hydrogen bonds. The mechanism of the structural phase transition is discussed.

  11. Determination of propoxur in environmental samples by automated solid-phase extraction followed by flow-injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection

    International Nuclear Information System (INIS)

    A sensitive method for the analysis of propoxur in environmental samples has been developed. It involves an automated solid-phase extraction (SPE) procedure using a Gilson Aspec XLi and flow-injection analysis (FI) with chemiluminescence (CL) detection. The FI-CL system relies on the photolysis of propoxur by irradiation using a low-pressure mercury lamp (main spectral line 254 nm). The resultant methylamine is subsequently detected by CL using tris(2,2'-bipyridyl)ruthenium(III), which is on-line generated by photo-oxidation of the ruthenium(II) complex in the presence of peroxydisulfate. The linear concentration range of application was 0.05-5 μg mL-1 of propoxur, with a detection limit of 5 ng mL-1. The repeatability was 0.82% expressed as relative standard deviation (n = 10) and the reproducibility, studied on 5 consecutive days, was 2.1%. The sample throughput was 160 injection per hour. Propoxur residues below ng mL-1 levels could be determined in environmental water samples when an SPE preconcentration device was coupled on-line with the FI system. This SPE-FI-CL arrangement provides a detection limit as low as 5 ng L-1 using only 500 mL of sample. In the analysis of fruits and vegetables, the detection limit was about 10 μg kg-1

  12. Polypharmacology of dopamine receptor ligands.

    Science.gov (United States)

    Butini, S; Nikolic, K; Kassel, S; Brückmann, H; Filipic, S; Agbaba, D; Gemma, S; Brogi, S; Brindisi, M; Campiani, G; Stark, H

    2016-07-01

    Most neurological diseases have a multifactorial nature and the number of molecular mechanisms discovered as underpinning these diseases is continuously evolving. The old concept of developing selective agents for a single target does not fit with the medical need of most neurological diseases. The development of designed multiple ligands holds great promises and appears as the next step in drug development for the treatment of these multifactorial diseases. Dopamine and its five receptor subtypes are intimately involved in numerous neurological disorders. Dopamine receptor ligands display a high degree of cross interactions with many other targets including G-protein coupled receptors, transporters, enzymes and ion channels. For brain disorders like Parkinsońs disease, schizophrenia and depression the dopaminergic system, being intertwined with many other signaling systems, plays a key role in pathogenesis and therapy. The concept of designed multiple ligands and polypharmacology, which perfectly meets the therapeutic needs for these brain disorders, is herein discussed as a general ligand-based concept while focusing on dopaminergic agents and receptor subtypes in particular. PMID:27234980

  13. Efficient separation of light's orbital angular momentum

    CERN Document Server

    Mirhosseini, Mohammad; Shi, Zhimin; Boyd, Robert W

    2013-01-01

    The orbital angular momentum (OAM) of light is an attractive degree of freedom for fundamentals studies in quantum mechanics. In addition, the discrete unbounded state-space provided by OAM has been used to enhance classical and quantum communications. The ability to unambiguously measure the OAM of single photons is a key part of all such experiments. However, state-of-the-art methods for sorting OAM modes are limited to a separation efficiency of about 80 percent. Here we demonstrate a method which uses a series of complex optical transformations to enable the measurement of light's OAM with a separation efficiency of more than 92 percent. Further, we demonstrate the separation of modes in the angular position basis, which is mutually unbiased with respect to the OAM basis. The high degree of certainty makes our approach particularly attractive for quantum key distribution systems employing spatial encoding.

  14. Phenomenological determination of the orbital angular momentum.

    Energy Technology Data Exchange (ETDEWEB)

    Ramsey, G. P.; High Energy Physics; Loyola Univ.

    2009-01-01

    Measurements involving the gluon spin, {Delta}G(x, t) and the corresponding asymmetry, A(x,t) = {Delta}G(x,t)/G(x,t) play an important role in quantitative understanding of proton structure. We have modeled the asymmetry perturbatively and calculated model corrections to obtain information about non-perturbative spin-orbit effects. These models are consistent with existing COMPASS and HERMES data on the gluon asymmetry. The J{sub z} = 1/2 sum rule is used to generate values of orbital angular momentum at LO and NLO. For models consistent with data, the orbital angular momentum is small. Our studies specify accuracy that future measurements should achieve to constrain theoretical models for nucleon structure.

  15. From transverse angular momentum to photonic wheels

    Science.gov (United States)

    Aiello, Andrea; Banzer, Peter; Neugebauer, Martin; Leuchs, Gerd

    2015-12-01

    Scientists have known for more than a century that light possesses both linear and angular momenta along the direction of propagation. However, only recent advances in optics have led to the notion of spinning electromagnetic fields capable of carrying angular momenta transverse to the direction of motion. Such fields enable numerous applications in nano-optics, biosensing and near-field microscopy, including three-dimensional control over atoms, molecules and nanostructures, and allowing for the realization of chiral nanophotonic interfaces and plasmonic devices. Here, we report on recent developments of optics with light carrying transverse spin. We present both the underlying principles and the latest achievements, and also highlight new capabilities and future applications emerging from this young yet already advanced field of research.

  16. The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Marriage, Tobias; Ali, A.; Amiri, M.; Appel, J. W.; Araujo, D.; Bennett, C. L.; Boone, F.; Chan, M.; Cho, H.; Chuss, D. T.; Colazo, F.; Crowe, E.; Denis, K.; Dünner, R.; Eimer, J.; Essinger-Hileman, T.; Gothe, D.; Halpern, M.; Harrington, K.; Hilton, G.; Hinshaw, G. F.; Huang, C.; Irwin, K.; Jones, G.; Karakla, J.; Kogut, A. J.; Larson, D.; Limon, M.; Lowry, L.; Mehrle, N.; Miller, A. D.; Miller, N.; Moseley, S. H.; Novak, G.; Reintsema, C.; Rostem, K.; Stevenson, T.; Towner, D.; U-Yen, K.; Wagner, E.; Watts, D.; Wollack, E.; Xu, Z.; Zeng, L.

    2014-01-01

    Some of the most compelling inflation models predict a background of primordial gravitational waves (PGW) detectable by their imprint of a curl-like "B-mode" pattern in the polarization of the Cosmic Microwave Background (CMB). The Cosmology Large Angular Scale Surveyor (CLASS) is a novel array of telescopes to measure the B-mode signature of the PGW. By targeting the largest angular scales (>2°) with a multifrequency array, novel polarization modulation and detectors optimized for both control of systematics and sensitivity, CLASS sets itself apart in the field of CMB polarization surveys and opens an exciting new discovery space for the PGW and inflation. This poster presents an overview of the CLASS project.

  17. Mass and Angular Momentum in General Relativity

    CERN Document Server

    Jaramillo, J L

    2010-01-01

    We present an introduction to mass and angular momentum in General Relativity. After briefly reviewing energy-momentum for matter fields, first in the flat Minkowski case (Special Relativity) and then in curved spacetimes with or without symmetries, we focus on the discussion of energy-momentum for the gravitational field. We illustrate the difficulties rooted in the Equivalence Principle for defining a local energy-momentum density for the gravitational field. This leads to the understanding of gravitational energy-momentum and angular momentum as non-local observables that make sense, at best, for extended domains of spacetime. After introducing Komar quantities associated with spacetime symmetries, it is shown how total energy-momentum can be unambiguously defined for isolated systems, providing fundamental tests for the internal consistency of General Relativity as well as setting the conceptual basis for the understanding of energy loss by gravitational radiation. Finally, several attempts to formulate q...

  18. Angular quadratures for improved transport computations

    International Nuclear Information System (INIS)

    This paper introduces new octant-range, composite-type Gauss and mid-point rule angular quadrature formulas for neutron and photon transport computations. A generalization to octant-range quadratures is also introduced in order to allow for discontinuities at material interfaces for two- and three-dimensional transport problems which can be modeled with 60-degree triangular or hexagonal mesh subdivisions in the x-y plane

  19. Clustering, Angular Size and Dark Energy

    OpenAIRE

    R.C. Santos; Lima, J. A. S.

    2008-01-01

    The influence of dark matter inhomogeneities on the angular size-redshift test is investigated for a large class of flat cosmological models driven by dark energy plus a cold dark matter component (XCDM model). The results are presented in two steps. First, the mass inhomogeneities are modeled by a generalized Zeldovich-Kantowski-Dyer-Roeder (ZKDR) distance which is characterized by a smoothness parameter $\\alpha(z)$ and a power index $\\gamma$, and, second, we provide a statistical analysis t...

  20. Jet angular distribution from quantum chromodynamics

    International Nuclear Information System (INIS)

    The quantum chromodynamic correction to jet (defined a la Sterman and Weinberg) angular distribution in energetic e+e- annihilation is calculated to order α/sub s/ keeping exact dependence on epsilon and delta. Deviations from the zeroth order distribution, 1 + cos2theta, for are found relatively large values of epsilon and delta. This effect could be tested at the existing e+e- colliding beam facilities

  1. Arbitrary orbital angular momentum of photons

    OpenAIRE

    Pan, Yue; Gao, Xu-Zhen; Ren, Zhi-Cheng; Wang, Xi-Lin; Tu, Chenghou; Li, Yongnan; Wang, Hui-Tian

    2015-01-01

    Orbital angular momentum (OAM) of photons, as a new fundamental degree of freedom, has excited a great diversity of interest, because of a variety of emerging applications. Arbitrarily tunable OAM has gained much attention, but its creation remains still a tremendous challenge. We demonstrate the realization of well-controlled arbitrary OAM in both theory and experiment. We present the concept of general OAM, which extends the OAM carried by the scalar vortex field to the OAM carried by the a...

  2. Quark Orbital Angular Momentum in the Baryon

    OpenAIRE

    Song, Xiaotong

    2000-01-01

    Analytical and numerical results, for the orbital and spin content carried by different quark flavors in the baryons, are given in the chiral quark model with symmetry breaking. The reduction of the quark spin, due to the spin dilution in the chiral splitting processes, is transferred into the orbital motion of quarks and antiquarks. The orbital angular momentum for each quark flavor in the proton as a function of the partition factor $\\kappa$ and the chiral splitting probability $a$ is shown...

  3. Wilson lines and orbital angular momentum

    OpenAIRE

    Lorce, Cédric

    2013-01-01

    We present an explicit realization of the Chen et al. approach to the proton spin decomposition in terms of Wilson lines, generalizing the light-front gauge-invariant extensions discussed recently by Hatta. Particular attention is drawn to the residual gauge freedom by further separating the pure-gauge term into contour and residual terms. We show that the kinetic orbital angular momentum operator can be expressed in terms of the Wigner operator only when the momentum variable is integrated o...

  4. Orbital angular momentum photonic quantum interface

    OpenAIRE

    Zhou, Zhi-Yuan; Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Shi, Bao-Sen; Guo, Guang-Can

    2014-01-01

    Light carrying orbital angular momentum (OAM) has great potential in enhancing the information channel capacity in both classical and quantum optical communications. Long distance optical communication requires the wavelengths of light are situated in the low-loss communication windows, but most quantum memories currently being developed for use in a quantum repeater work at different wavelengths, so a quantum interface to bridge the wavelength gap is necessary. So far, such an interface for ...

  5. Orbital angular momentum-entanglement frequency transducer

    OpenAIRE

    Zhou, Zhi-Yuan; Liu, Shi-Long; Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Dong, Ming-xin; Shi, Bao-Sen; Guo, Guang-Can

    2016-01-01

    Entanglement is a vital resource for realizing many tasks such as teleportation, secure key distribution, metrology and quantum computations. To effectively build entanglement between different quantum systems and share information between them, a frequency transducer to convert between quantum states of different wavelengths while retaining its quantum features is indispensable. Information encoded in the photons orbital angular momentum OAM degrees of freedom is preferred in harnessing the ...

  6. Wigner distributions and quark orbital angular momentum

    OpenAIRE

    Cedric LorceOrsay, IPN and Orsay, LPT; Barbara Pasquini(Pavia U. and INFN, Pavia)

    2015-01-01

    We discuss the quark phase-space or Wigner distributions of the nucleon which combine in a single picture all the information contained in the generalized parton distributions and the transverse-momentum dependent parton distributions. In particular, we present results for the distribution of unpolarized quarks in a longitudinally polarized nucleon obtained in a light-front constituent quark model. We show how the quark orbital angular momentum can be extracted from the Wigner distributions a...

  7. Orbital angular momentum entanglement in turbulence

    OpenAIRE

    Ibrahim, Alpha Hamadou; Roux, Filippus S.; McLaren, Melanie; Konrad, Thomas; Forbes, Andrew

    2013-01-01

    The turbulence induced decay of orbital angular momentum (OAM) entanglement between two photons is investigated numerically and experimentally. To compare our results with previous work, we simulate the turbulent atmosphere with a single phase screen based on the Kolmogorov theory of turbulence. We consider two different scenarios: in the first only one of the two photons propagates through turbulence, and in the second both photons propagate through uncorrelated turbulence. Comparing the ent...

  8. Four-photon orbital angular momentum entanglement

    OpenAIRE

    Hiesmayr, B. C.; De Dood, M.J.A.; Löffler, W.

    2015-01-01

    Quantum entanglement shared between more than two particles is essential to foundational questions in quantum mechanics, and upcoming quantum information technologies. So far, up to 14 two-dimensional qubits have been entangled, and an open question remains if one can also demonstrate entanglement of higher-dimensional discrete properties of more than two particles. A promising route is the use of the photon orbital angular momentum (OAM), which enables implementation of novel quantum informa...

  9. Moliere angular and lateral distributions with ionization

    International Nuclear Information System (INIS)

    The Moliere distribution for arbitrary linear combination between the deflection angle and the lateral displacement is improved to take into account ionization loss. The analytical results for lateral distribution derived through numerical integrations for dilogarithm function are compared with our detailed Monte Carlo results. Goudsmit-Saunderson angular distribution derived with Moliere parameters, is also confirmed to agree with our detailed Monte Carlo results. (author)

  10. Time-dependent angularly averaged inverse transport

    OpenAIRE

    Bal, Guillaume; Jollivet, Alexandre

    2009-01-01

    This paper concerns the reconstruction of the absorption and scattering parameters in a time-dependent linear transport equation from knowledge of angularly averaged measurements performed at the boundary of a domain of interest. We show that the absorption coefficient and the spatial component of the scattering coefficient are uniquely determined by such measurements. We obtain stability results on the reconstruction of the absorption and scattering parameters with respect to the measured al...

  11. Angular momentum distributions in subbarrier fusion reactions

    International Nuclear Information System (INIS)

    Interest in subbarrier heavy-ion fusion was stimulated by the realization that subbarrier fusion cross sections were enhanced by many orders of magnitude over what would be expected from quantum mechanical one-dimensional barrier penetration. This review focuses on the angular momentum (spin) distributions in heavy-ion fusion reactions. Experimental probes, theoretical considerations, and a comparison of experimental results with model calculations are given. 86 refs., 10 figs

  12. Angular resolution of stacked resistive plate chambers

    CERN Document Server

    Samuel, Deepak; Murgod, Lakshmi P

    2016-01-01

    We present here detailed derivations of mathematical expressions for the angular resolution of a set of stacked resistive plate chambers (RPCs). The expressions are validated against experimental results using data collected from the prototype detectors (without magnet) of the upcoming India-based Neutrino Observatory (INO). In principle, these expressions can be used for any other detector with an architecture similar to that of RPCs.

  13. Angular Momentum in Loop Quantum Gravity

    OpenAIRE

    Bojowald, Martin

    2000-01-01

    An angular momentum operator in loop quantum gravity is defined using spherically symmetric states as a non-rotating reference system. It can be diagonalized simultaneously with the area operator and has the familiar spectrum. The operator indicates how the quantum geometry of non-rotating isolated horizons can be generalized to rotating ones and how the recent computations of black hole entropy can be extended to rotating black holes.

  14. Angular Momentum of Dark Matter Black Holes

    OpenAIRE

    Frampton, Paul H.

    2016-01-01

    The putative black holes which may constitute all the dark matter are described by a Kerr metric with only two parameters, mass M and angular momentum J. There has been little discussion of J since it plays no role in the upcoming attempt at detection by microlensing. Nevertheless J does play a central role in understanding the previous lack of detection, especially of CMB distortion. We explain why bounds previously derived from lack of CMB distortion are too strong for primordial black hole...

  15. Coherent Control of Photoelectron Wavepacket Angular Interferograms

    OpenAIRE

    Hockett, Paul; Wollenhaupt, Matthias; Baumert, Thomas,

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the cohere...

  16. Angular Diameter Distances in Clumpy Friedmann Universes

    OpenAIRE

    Tomita, Kenji

    1998-01-01

    Solving null-geodesic equations, behavior of angular diameter distances is studied in inhomogeneous cosmological models, which are given by performing N-body simulations with the CDM spectrum. The distances depend on the separation angle of ray pairs, the mass and the radius of particles cosisting of galaxies and dark matter balls, and cosmological model parameters. The calculated distances are compared with the Dyer- Roeder distance, and after many ray-shooting, the average, dispersion and d...

  17. Angular quadratures for improved transport computations

    Energy Technology Data Exchange (ETDEWEB)

    Abu-Shumays, I.K.

    1999-07-22

    This paper introduces new octant-range, composite-type Gauss and mid-point rule angular quadrature formulas for neutron and photon transport computations. A generalization to octant-range quadratures is also introduced in order to allow for discontinuities at material interfaces for two- and three-dimensional transport problems which can be modeled with 60-degree triangular or hexagonal mesh subdivisions in the x-y plane.

  18. Contactless Measurement of Angular Velocity using Circularly Polarized Antennas

    OpenAIRE

    Sipal, Vit; Narbudowicz, Adam; Ammann, Max

    2014-01-01

    An innovative method to measure the angular velocity using circularly polarized antennas is proposed. Due to the properties of circular polarization, the angular velocity is frequency modulated (FM) on a wireless carrier. This enables a low-cost precise continuous measurement of angular velocity using a standard FM demodulator. The hardware can be easily adapted for both high and low angular velocity values. The precise alignment angle between the antennas can be determined if the initial ant...

  19. Quark Orbital-Angular-Momentum Distribution in the Nucleon

    OpenAIRE

    Hoodbhoy, Pervez; Ji, Xiangdong; Lu, Wei

    1998-01-01

    We introduce gauge-invariant quark and gluon angular momentum distributions after making a generalization of the angular momentum density operators. From the quark angular momentum distribution, we define the gauge-invariant and leading-twist quark {\\it orbital} angular momentum distribution $L_q(x)$. The latter can be extracted from data on the polarized and unpolarized quark distributions and the off-forward distribution $E(x)$ in the forward limit. We comment upon the evolution equations o...

  20. Study of the Angular Distribution of Scintillation Photons

    CERN Document Server

    Fornaro, Giulia Alice; Ghezzi, Alessio; Knapitsch, Arno; Modrzynski, Pawel; Pizzichemi, Marco; Lecoq, Paul; Auffray, Etiennette

    2014-01-01

    This paper presents a characterization method to experimentally determine the angular distribution of scintillation light. By exciting LYSO crystals with a radioactive source, we measured the light angular profiles obtained with samples of different geometries in different conditions of wrapping. We also measured the angular distribution of light emitting in glue and compared it with the one emitting in air. Angular distribution of light output of photonic crystals is also provided. Consistency of the measurements is verified with conventional light output measurements.

  1. A practical formula for the radiated angular momentum

    OpenAIRE

    Lousto, Carlos O.; Zlochower, Yosef

    2007-01-01

    We present a simple formula for the radiated angular momentum based on a spin-weighted spherical harmonic decomposition of the Weyl scalar psi_4 representing outgoing radiation in the Kinnersley tetrad. We test our formula by measuring the radiated angular momentum from three simulations of non-spinning equal-mass black-hole binary with orbital angular momentum aligned along the x, y, and z axes respectively. We find that the radiated angular momentum agrees with the differences in the remnan...

  2. Angular momentum nonconservation and conservation in quasiclassical Positronium

    OpenAIRE

    Lush, David C.

    2010-01-01

    It is shown that due to Thomas precession, angular momentum is not generally a constant of the motion in a quasiclassical model of the Positronium atom consisting of circular-orbiting point charges with intrinsic spin and associated magnetic moment. Despite absence of externally-applied torque, angular momentum is a constant of the motion only if the electron and positron intrinsic angular momentum vector components perpendicular to the orbital angular momentum are antiparallel and of equal m...

  3. Angular momentum of a strongly focussed Gaussian beam

    OpenAIRE

    Nieminen, Timo A.; Heckenberg, Norman R.; Rubinsztein-Dunlop, Halina

    2004-01-01

    A circularly polarized rotationally symmetric paraxial laser beams carries hbar angular momentum per photon as spin. Focussing the beam with a rotationally symmetric lens cannot change this angular momentum flux, yet the focussed beam must have spin less than hbar per photon. The remainder of the original spin is converted to orbital angular momentum, manifesting itself as a longitudinal optical vortex at the focus. This demonstrates that optical orbital angular momentum can be generated by a...

  4. Orbital and field angular momentum in the nucleon

    OpenAIRE

    Singleton, D; Dzhunushaliev, V.

    1998-01-01

    The nucleon spin problem raises experimental and theoretical questions regarding the contribution of the orbital angular momentum of the quarks to the total spin of the nucleon. In this article we examine the commutation relationships of various operators that contribute to the total angular momentum of the nucleon. We find that the sum of the orbital plus gluon field angular momentum should satisfy the angular momentum commutators, at least up to the one-loop level. This requirement on the s...

  5. On angular momentum operator in quantum field theory

    OpenAIRE

    Iliev, Bozhidar Z.

    2002-01-01

    Relations between two definitions of (total) angular momentum operator, as a generator of rotations and in the Lagrangian formalism, are explored in quantum field theory. Generally, these definitions result in different angular momentum operators, which are suitable for different purposes in the theory. From the spin and orbital angular momentum operators (in the Lagrangian formalism) are extracted additive terms which are conserved operators and whose sum is the total angular momentum operator.

  6. A neural circuit for angular velocity computation.

    Science.gov (United States)

    Snider, Samuel B; Yuste, Rafael; Packer, Adam M

    2010-01-01

    In one of the most remarkable feats of motor control in the animal world, some Diptera, such as the housefly, can accurately execute corrective flight maneuvers in tens of milliseconds. These reflexive movements are achieved by the halteres, gyroscopic force sensors, in conjunction with rapidly tunable wing steering muscles. Specifically, the mechanosensory campaniform sensilla located at the base of the halteres transduce and transform rotation-induced gyroscopic forces into information about the angular velocity of the fly's body. But how exactly does the fly's neural architecture generate the angular velocity from the lateral strain forces on the left and right halteres? To explore potential algorithms, we built a neuromechanical model of the rotation detection circuit. We propose a neurobiologically plausible method by which the fly could accurately separate and measure the three-dimensional components of an imposed angular velocity. Our model assumes a single sign-inverting synapse and formally resembles some models of directional selectivity by the retina. Using multidimensional error analysis, we demonstrate the robustness of our model under a variety of input conditions. Our analysis reveals the maximum information available to the fly given its physical architecture and the mathematics governing the rotation-induced forces at the haltere's end knob. PMID:21228902

  7. A neural circuit for angular velocity computation

    Directory of Open Access Journals (Sweden)

    Samuel B Snider

    2010-12-01

    Full Text Available In one of the most remarkable feats of motor control in the animal world, some Diptera, such as the housefly, can accurately execute corrective flight maneuvers in tens of milliseconds. These reflexive movements are achieved by the halteres, gyroscopic force sensors, in conjunction with rapidly-tunable wing-steering muscles. Specifically, the mechanosensory campaniform sensilla located at the base of the halteres transduce and transform rotation-induced gyroscopic forces into information about the angular velocity of the fly's body. But how exactly does the fly's neural architecture generate the angular velocity from the lateral strain forces on the left and right halteres? To explore potential algorithms, we built a neuro-mechanical model of the rotation detection circuit. We propose a neurobiologically plausible method by which the fly could accurately separate and measure the three-dimensional components of an imposed angular velocity. Our model assumes a single sign-inverting synapse and formally resembles some models of directional selectivity by the retina. Using multidimensional error analysis, we demonstrate the robustness of our model under a variety of input conditions. Our analysis reveals the maximum information available to the fly given its physical architecture and the mathematics governing the rotation-induced forces at the haltere's end knob.

  8. Quark Wigner distributions and orbital angular momentum

    International Nuclear Information System (INIS)

    We study the Wigner functions of the nucleon which provide multidimensional images of the quark distributions in phase space. These functions can be obtained through a Fourier transform in the transverse space of the generalized transverse-momentum dependent parton distributions. They depend on both the transverse position and the three-momentum of the quark relative to the nucleon, and therefore combine in a single picture all the information contained in the generalized parton distributions and the transverse-momentum dependent parton distributions. We focus the discussion on the distributions of unpolarized/longitudinally polarized quark in an unpolarized/longitudinally polarized nucleon. In this way, we can study the role of the orbital angular momentum of the quark in shaping the nucleon and its correlations with the quark and nucleon polarizations. The quark orbital angular momentum is also calculated from its phase-space average weighted with the Wigner distribution of unpolarized quarks in a longitudinally polarized nucleon. The corresponding results obtained within different light-cone quark models are compared with alternative definitions of the quark orbital angular momentum, as given in terms of generalized parton distributions and transverse-momentum dependent parton distributions.

  9. Study of the fission fragments angular momenta

    International Nuclear Information System (INIS)

    The work represents the results of angular distribution measurements performed for prompt gamma-rays in the range of 1.1. ... 1.2. MeV due to the 233U (n,f) and 239Pu (n,f) reactions. The measurements yielded anisotropy values found to be consistent with values previously measured and using the same technique at different gamma energy bands. Such consistency, also found to exist between anisotropy values previously measured for the 235U (n,f) reaction, is a strong evidence about the energy independence of the anisotropy and indicates that the gamma spectra (at 180deg and 90deg to the fission direction) are essentially the same. The average values of the fragment angular momentum were calculated according to Strutinsky and Nix-Swiatecki theories. It was found that the values of the average angular momentum calculated for 234U, 236U and 240Pu according to Strutinsky's formula (at different gamma energy bands) are consistent and yield average values which are in good agreement with those obtained from direct measurements. (orig.)

  10. The Cosmology Large Angular Scale Surveyor (CLASS)

    Science.gov (United States)

    Harrington, Kathleen; Marriange, Tobias; Aamir, Ali; Appel, John W.; Bennett, Charles L.; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T.; Colazo, Felipe; Denis, Kevin; Moseley, Samuel H.; Rostem, Karwan; Wollack, Edward

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from in ation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145/217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad frequency range, large sky coverage, control over systematics, and high sensitivity, CLASS will observe the reionization and recombination peaks of the CMB E- and B-mode power spectra. CLASS will make a cosmic variance limited measurement of the optical depth to reionization and will measure or place upper limits on the tensor-to-scalar ratio, r, down to a level of 0.01 (95% C.L.).

  11. The Cosmology Large Angular Scale Surveyor

    CERN Document Server

    Harrington, Kathleen; Ali, Aamir; Appel, John W; Bennett, Charles L; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T; Colazo, Felipe; Dahal, Sumit; Denis, Kevin; Dünner, Rolando; Eimer, Joseph; Essinger-Hileman, Thomas; Fluxa, Pedro; Halpern, Mark; Hilton, Gene; Hinshaw, Gary F; Hubmayr, Johannes; Iuliano, Jeffery; Karakla, John; McMahon, Jeff; Miller, Nathan T; Moseley, Samuel H; Palma, Gonzalo; Parker, Lucas; Petroff, Matthew; Pradenas, Bastián; Rostem, Karwan; Sagliocca, Marco; Valle, Deniz; Watts, Duncan; Wollack, Edward; Xu, Zhilei; Zeng, Lingzhen

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from inflation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145/217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70\\% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad f...

  12. Crystallization of protein–ligand complexes

    International Nuclear Information System (INIS)

    Methods presented for growing protein–ligand complexes fall into the categories of co-expression of the protein with the ligands of interest, use of the ligands during protein purification, cocrystallization and soaking the ligands into existing crystals. Obtaining diffraction-quality crystals has long been a bottleneck in solving the three-dimensional structures of proteins. Often proteins may be stabilized when they are complexed with a substrate, nucleic acid, cofactor or small molecule. These ligands, on the other hand, have the potential to induce significant conformational changes to the protein and ab initio screening may be required to find a new crystal form. This paper presents an overview of strategies in the following areas for obtaining crystals of protein–ligand complexes: (i) co-expression of the protein with the ligands of interest, (ii) use of the ligands during protein purification, (iii) cocrystallization and (iv) soaks

  13. A critique of the angular momentum sum rules and a new angular momentum sum rule

    CERN Document Server

    Bakker, B L G; Trueman, T L

    2004-01-01

    We show that the expressions in the literature for the tensorial structure of the hadronic matrix elements of the angular momentum operators J are incorrect. Given this disagreement with the published results, we have taken pains to derive the correct expressions in three different ways, two involving explicit physical wave packets and the third, totally independent, based upon the rotational properties of the state vectors. Surprisingly it turns out that the results are very sensitive to the type of relativistic spin state used to describe the motion of the particle i.e. whether a canonical (i.e. boost) state or a helicity state is utilized. We present results for the matrix elements of the angular momentum operators, valid in an arbitrary Lorentz frame, both for helicity states and canonical states. These results are relevant for the construction of angular momentum sum rules, relating the angular momentum of a nucleon to the spin and orbital angular momentum of its constituents. Moreover, we show that it i...

  14. Analysis of orbital angular momentum of a misaligned optical beam

    Energy Technology Data Exchange (ETDEWEB)

    Vasnetsov, M V [Optics Group, Department of Physics and Astronomy, University of Glasgow, Glasgow (United Kingdom); Pas' ko, V A [Institute of Physics, National Academy of Sciences of Ukraine, Prospect Nauki 46, Kiev 03028 (Ukraine); Soskin, M S [Institute of Physics, National Academy of Sciences of Ukraine, Prospect Nauki 46, Kiev 03028 (Ukraine)

    2005-02-01

    We report an analysis of the orbital angular momentum of an optical beam misaligned with respect to a reference axis. Both laterally displaced and angularly deflected Laguerre-Gaussian beams are represented in terms of the superposition of azimuthal harmonics with well-defined orbital angular momentum. Simultaneous parallel displacement and angular tilt cause the coupling between azimuthal harmonics and therefore change the projection of the orbital angular momentum on the reference axis. Rotation of beams around the reference axis was simulated by attributing corresponding rotational frequency shifts to the components.

  15. Angular Dispersion and Deflection Function for Heavy Ion Elastic Scattering

    Institute of Scientific and Technical Information of China (English)

    BAI Zhen; MAO Rui-Shi; YUAN Xiao-Hua; Xu Zhi-Guo; ZHANG Hong-Bin; XU Hua-Gen; QI Hui-Rong; WANG Yue; JIA Fei; WU Li-Jie; DING Xian-Li; WANG Qi; GAO Qi; GAO Hui; LI Song-Lin; LI Jun-Qing; ZHANG Ya-Peng; XIAO Guo-Qing; JIN Gen-Ming; REN Zhong-Zhou; ZHOU Shan-Gui; XU Wang; HAN Jian-Long; Fan Gong-Tao; ZHANG Shuang-Quan; PANG Dan-Yang; SERGEY Yu-Kun; XIAO Zhi-Gang; XU Hu-Shan; SUN Zhi-Yu; HU Zheng-Guo; ZHANG Xue-Ying; WANG Hong-Wei

    2007-01-01

    The differential cross sections for elastic scattering products of17 F on 208 Pb have been measured.The angular dispersion plots of In(dσ/dθ)versus θ2 are obtained from the angular distribution of the elastic scattering differential cross sections.Systematical analysis on the angular dispersion for the available experimental data indicates that there is an angular dispersion turning angle at forward angular range within the grazing angle.This turning angle can be clarified as nuclear rainbow in classical deflection function.The exotic behaviour of the nuclear rainbow angle offers a new probe to investigate the halo and skin phenomena.

  16. An NMR strategy for fragment-based ligand screening utilizing a paramagnetic lanthanide probe

    International Nuclear Information System (INIS)

    A nuclear magnetic resonance-based ligand screening strategy utilizing a paramagnetic lanthanide probe is presented. By fixing a paramagnetic lanthanide ion to a target protein, a pseudo-contact shift (PCS) and a paramagnetic relaxation enhancement (PRE) can be observed for both the target protein and its bound ligand. Based on PRE and PCS information, the bound ligand is then screened from the compound library and the structure of the ligand–protein complex is determined. PRE is an isotropic paramagnetic effect observed within 30 Å from the lanthanide ion, and is utilized for the ligand screening in the present study. PCS is an anisotropic paramagnetic effect providing long-range (∼40 Å) distance and angular information on the observed nuclei relative to the paramagnetic lanthanide ion, and utilized for the structure determination of the ligand–protein complex. Since a two-point anchored lanthanide-binding peptide tag is utilized for fixing the lanthanide ion to the target protein, this screening method can be generally applied to non-metal-binding proteins. The usefulness of this strategy was demonstrated in the case of the growth factor receptor-bound protein 2 (Grb2) Src homology 2 (SH2) domain and its low- and high-affinity ligands.

  17. Ligand chain length conveys thermochromism.

    Science.gov (United States)

    Ganguly, Mainak; Panigrahi, Sudipa; Chandrakumar, K R S; Sasmal, Anup Kumar; Pal, Anjali; Pal, Tarasankar

    2014-08-14

    Thermochromic properties of a series of non-ionic copper compounds have been reported. Herein, we demonstrate that Cu(II) ion with straight-chain primary amine (A) and alpha-linolenic (fatty acid, AL) co-jointly exhibit thermochromic properties. In the current case, we determined that thermochromism becomes ligand chain length-dependent and at least one of the ligands (A or AL) must be long chain. Thermochromism is attributed to a balanced competition between the fatty acids and amines for the copper(II) centre. The structure-property relationship of the non-ionic copper compounds Cu(AL)2(A)2 has been substantiated by various physical measurements along with detailed theoretical studies based on time-dependent density functional theory. It is presumed from our results that the compound would be a useful material for temperature-sensor applications. PMID:24943491

  18. Presentation of Ligands on Hydroxylapatite

    Science.gov (United States)

    Chu, Barbara C. F.; Orgel, Leslie E.

    1997-01-01

    Conjugates of biotin with the decamer of glutamic acid (glu(sub 10)) and the trimer of D,L-2-amino-5-phosphonovaleric acid (I) have been synthesized, and it has been shown that they mediate the binding of avidin to hydroxylapatite. In a similar way a conjugate of methotrexate with glu(sub 10) mediates the binding of dihydrofolate reductase to the mineral. The presentation of ligands on the hydroxylapatite component of bone may find applications in clinical medicine.

  19. Privileged chiral ligands and catalysts

    CERN Document Server

    Zhou, Qi-Lin

    2011-01-01

    This ultimate ""must have"" and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these ""privileged catalysts"". A novel concept that gives readers a much deeper insight into the topic.

  20. Tumor targeting via integrin ligands

    Directory of Open Access Journals (Sweden)

    HorstKessler

    2013-08-01

    Full Text Available Selective and targeted delivery of drugs to tumors is a major challenge for an effective cancer therapy and also to overcome the side effects associated with current treatments. Overexpression of various receptors on tumor cells is a characteristic structural and biochemical aspect of tumors and distinguishes them from physiologically normal cells. This abnormal feature is therefore suitable for selectively directing anticancer molecules to tumors by using ligands that can preferentially recognize such receptors. Several subtypes of integrin receptors that are crucial for cell adhesion, cell signaling, cell viability and motility have been shown to have an upregulated expression on cancer cells. Thus, ligands that recognize specific integrin subtypes represent excellent candidates to be conjugated to drugs or drug carrier systems and be targeted to tumors. In this regard, integrins recognizing the RGD cell adhesive sequence have been extensively targeted for tumor specific drug delivery. Here we review key recent examples on the presentation of RGD-based integrin ligands by means of distinct drug delivery systems, and discuss the prospects of such therapies to specifically target tumor cells.

  1. Radioiodinated ligands for dopamine receptors

    International Nuclear Information System (INIS)

    The dopamine receptor system is important for normal brain function; it is also the apparent action site for various neuroleptic drugs for the treatment of schizophrenia and other metal disorders. In the past few years radioiodinated ligands for single photon emission tomography (SPECT) have been successfully developed and tested in humans: [123I]TISCH for D1 dopamine receptors; [123I]IBZM, epidepride, IBF and FIDA2, four iodobenzamide derivatives, for D2/D3 dopamine receptors. In addition, [123I]β-CIT (RTI-55) and IPT, cocaine derivatives, for the dopamine reuptake site are potentially useful for diagnosis of loss of dopamine neurons. The first iodinated ligand, (R)trans-7-OH-PIPAT, for D3 dopamine receptors, was synthesized and characterized with cloned cell lines (Spodoptera frugiperda, Sf9) expressing the D2 and D3 dopamine receptors and with rat basal forebrain membrane preparations. Most of the known iodobenzamides displayed similar potency in binding to both D2 and D3 dopamine receptors expressed in the cell lines. Initial studies appear to suggest that by fine tuning the structures it may be possible to develop agents specific for D2 and D3 dopamine receptors. It is important to investigate D2/D3 selectivity for this series of potent ligands

  2. Angular Momentum and Galaxy Formation Revisited

    Science.gov (United States)

    Romanowsky, Aaron J.; Fall, S. Michael

    2012-12-01

    Motivated by a new wave of kinematical tracers in the outer regions of early-type galaxies (ellipticals and lenticulars), we re-examine the role of angular momentum in galaxies of all types. We present new methods for quantifying the specific angular momentum j, focusing mainly on the more challenging case of early-type galaxies, in order to derive firm empirical relations between stellar j sstarf and mass M sstarf (thus extending earlier work by Fall). We carry out detailed analyses of eight galaxies with kinematical data extending as far out as 10 effective radii, and find that data at two effective radii are generally sufficient to estimate total j sstarf reliably. Our results contravene suggestions that ellipticals could harbor large reservoirs of hidden j sstarf in their outer regions owing to angular momentum transport in major mergers. We then carry out a comprehensive analysis of extended kinematic data from the literature for a sample of ~100 nearby bright galaxies of all types, placing them on a diagram of j sstarf versus M sstarf. The ellipticals and spirals form two parallel j sstarf-M sstarf tracks, with log-slopes of ~0.6, which for the spirals are closely related to the Tully-Fisher relation, but for the ellipticals derives from a remarkable conspiracy between masses, sizes, and rotation velocities. The ellipticals contain less angular momentum on average than spirals of equal mass, with the quantitative disparity depending on the adopted K-band stellar mass-to-light ratios of the galaxies: it is a factor of ~3-4 if mass-to-light ratio variations are neglected for simplicity, and ~7 if they are included. We decompose the spirals into disks and bulges and find that these subcomponents follow j sstarf-M sstarf trends similar to the overall ones for spirals and ellipticals. The lenticulars have an intermediate trend, and we propose that the morphological types of galaxies reflect disk and bulge subcomponents that follow separate, fundamental j sstarf

  3. Theoretical calculations, DNA interaction, topoisomerase I and phosphatidylinositol-3-kinase studies of water soluble mixed-ligand nickel(II) complexes.

    Science.gov (United States)

    Gurumoorthy, Perumal; Mahendiran, Dharmasivam; Kalilur Rahiman, Aziz

    2016-03-25

    Eight water soluble mixed-ligand nickel(II) complexes of the type [NiL(1-4)(diimine)H2O]·(ClO4)2, (1-8) where L(1-4) = 2-((2-(piperazin-1-yl)ethylimino)methyl)-4-substituted phenols, and diimine = 2,2'-bipyridyl (bpy) or 1,10-phenanthroline (phen) were synthesized and characterized by elemental analysis and spectroscopic methods. The uncoordinated perchlorate anions was ascertained form IR spectra of the complexes, and the absorption spectra reveal the octahedron geometry around nickel(II) ion with tridentate Schiff base ligand, diimine and a coordinated water molecule. Cyclic voltammograms of the complexes indicate the one-electron irreversible processes in the cathodic and anodic region. In vitro antioxidant activity proved the significant radical scavenging activity of the complexes against DPPH radical. The groove/electrostatic binding nature of complexes with CT-DNA (calf thymus deoxyribonucleic acid) were affirmed by absorption, hydrodynamic and voltammetric titration experiments and docking analysis. All the complexes exhibit significant cleavage activity on plasmid DNA via hydrolytic and oxidatively, in which the oxidative mechanism involves hydroxyl radicals and supports the possibility of minor-groove binding. The complex 4 shows significant topoisomerase I (Topo-I) inhibitory activity. The molecular modeling analysis of complexes with phosphatidylinositol-3-kinase (PI3K) receptor indicate the hydrogen bonding with Met1039, Asp837 and Leu1027, and hydrophobic interactions with Ser488, Asn498, Asp500, Gln662, Lys668, Ile844, Ile847, Ile850, Val941, Leu942, Leu1020, Met1034, Leu1035, Thr1037, Met1039, Gln1041 and Ile1051 of subdomain IIA of BSA. The complexes show σ-π interaction between diimines and amino groups of Leu1030 and Arg839. PMID:26874211

  4. Statistical analysis of angular correlation measurements

    International Nuclear Information System (INIS)

    Obtaining the multipole mixing ratio, δ, of γ transitions in angular correlation measurements is a statistical problem characterized by the small number of angles in which the observation is made and by the limited statistic of counting, α. The inexistence of a sufficient statistics for the estimator of δ, is shown. Three different estimators for δ were constructed and their properties of consistency, bias and efficiency were tested. Tests were also performed in experimental results obtained in γ-γ directional correlation measurements. (Author)

  5. Angular momentum evolution of galaxies in EAGLE

    CERN Document Server

    Lagos, Claudia del P; Stevens, Adam R H; Cortese, Luca; Padilla, Nelson D; Davis, Timothy A; Contreras, Sergio; Croton, Darren

    2016-01-01

    We use EAGLE to study the specific angular momentum of galaxies, j, at z1.2, and then increase as lstars~a. Galaxy mergers reduce lstars by a factor of 2-3. These tracks are driven by both the evolution of the total jstars but also its radial distribution. Regardless of the aperture used to measure j, two distinct channels leading to low jstars in galaxies at z=0 are identified: (i) galaxy mergers, and (ii) early formation of most of the stars.

  6. Angular Momentum of Dark Matter Black Holes

    CERN Document Server

    Frampton, Paul H

    2016-01-01

    The putative black holes which may constitute all the dark matter are described by a Kerr metric with only two parameters, mass M and angular momentum J. There has been little discussion of J since it plays no role in the upcoming attempt at detection by microlensing. Nevertheless J does play a central role in understanding the previous lack of detection, especially of CMB distortion. We explain why bounds previously derived from lack of CMB distortion are too strong for primordial black holes with J non-vanishing. Almost none of the dark matter black holes can be from stellar collapse, and nearly all are primordial, to avoid excessive CMB distortion.

  7. All-fiber sensor of angular velocity

    Energy Technology Data Exchange (ETDEWEB)

    Andreev, A.TS.; Vlasenko, O.A.; Dianov, E.M.; Diankov, G.L.; Zafirova, B.S.

    1989-06-01

    The paper reports the construction of an all-fiber optical sensor of angular velocity whose operation is based on the Sagnac effect in a fiber ring interferometer. An all-fiber system does not require the use of external discrete optical elements; division, polarization, and modulation functions are performed by the fiber waveguide itself. The fiber elements and sensor are constructed on the basis of slightly anisotropic fiber waveguides. The sensitivity of the device was 0.0077 deg/sq rt hr, while the zero drift was 0.5 deg/hr. 6 refs.

  8. Orbital angular momentum of mixed vortex beams

    Czech Academy of Sciences Publication Activity Database

    Bouchal, Z.; Kollárová, V.; Zemánek, Pavel; Čižmár, Tomáš

    Bellingham : SPIE, 2007, 660907:1-7. ISBN 978-0-8194-6748-5. ISSN 0277-786X. [Czech-Polish-Slovak Conference Wave and Quantum Aspects of Contemporary Optics /15./. Liberec (CZ), 11.09.2006-15.09.2006] R&D Projects: GA MŠk(CZ) LC06007; GA MPO FT-TA2/059 Institutional research plan: CEZ:AV0Z20650511 Keywords : optical vortices * orbital angular momentum * spatial light modulator Subject RIV: BH - Optics, Masers, Lasers

  9. Time-dependent angularly averaged inverse transport

    International Nuclear Information System (INIS)

    This paper concerns the reconstruction of the absorption and scattering parameters in a time-dependent linear transport equation from knowledge of angularly averaged measurements performed at the boundary of a domain of interest. Such measurement settings find applications in medical and geophysical imaging. We show that the absorption coefficient and the spatial component of the scattering coefficient are uniquely determined by such measurements. We obtain stability results on the reconstruction of the absorption and scattering parameters with respect to the measured albedo operator. The stability results are obtained by a precise decomposition of the measurements into components with different singular behavior in the time domain

  10. Time-dependent angularly averaged inverse transport

    CERN Document Server

    Bal, Guillaume

    2009-01-01

    This paper concerns the reconstruction of the absorption and scattering parameters in a time-dependent linear transport equation from knowledge of angularly averaged measurements performed at the boundary of a domain of interest. We show that the absorption coefficient and the spatial component of the scattering coefficient are uniquely determined by such measurements. We obtain stability results on the reconstruction of the absorption and scattering parameters with respect to the measured albedo operator. The stability results are obtained by a precise decomposition of the measurements into components with different singular behavior in the time domain.

  11. Angular Momentum Sensitive Two-Center Interference

    Science.gov (United States)

    Ilchen, M.; Glaser, L.; Scholz, F.; Walter, P.; Deinert, S.; Rothkirch, A.; Seltmann, J.; Viefhaus, J.; Decleva, P.; Langer, B.; Knie, A.; Ehresmann, A.; Al-Dossary, O. M.; Braune, M.; Hartmann, G.; Meissner, A.; Tribedi, L. C.; AlKhaldi, M.; Becker, U.

    2014-01-01

    In quantum mechanics the Young-type double-slit experiment can be performed with electrons either traveling through a double slit or being coherently emitted from two inversion symmetric molecular sites. In the latter one the valence photoionization cross sections of homonuclear diatomic molecules were predicted to oscillate over kinetic energy almost 50 years ago. Beyond the direct proof of the oscillatory behavior of these photoionization cross sections σ, we show that the angular distribution of the emitted electrons reveals hitherto unexplored information on the relative phase shift between the corresponding partial waves through two-center interference patterns.

  12. Angular Diameter Distances in Clumpy Friedmann Universes

    CERN Document Server

    Tomita, K

    1998-01-01

    Solving null-geodesic equations, behavior of angular diameter distances is studied in inhomogeneous cosmological models, which are given by performing N-body simulations with the CDM spectrum. The distances depend on the separation angle of ray pairs, the mass and the radius of particles cosisting of galaxies and dark matter balls, and cosmological model parameters. The calculated distances are compared with the Dyer- Roeder distance, and after many ray-shooting, the average, dispersion and distribution of the clumpiness parameter are derived.

  13. Orbital angular momentum of general astigmatic modes

    International Nuclear Information System (INIS)

    We present an operator method to obtain complete sets of astigmatic Gaussian solutions of the paraxial wave equation. In case of general astigmatism, the astigmatic intensity and phase distribution of the fundamental mode differ in orientation. As a consequence, the fundamental mode has a nonzero orbital angular momentum, which is not due to phase singularities. Analogous to the operator method for the quantum harmonic oscillator, the corresponding astigmatic higher-order modes are obtained by repeated application of raising operators on the fundamental mode. The nature of the higher-order modes is characterized by a point on a sphere, in analogy with the representation of polarization on the Poincare sphere. The north and south poles represent astigmatic Laguerre-Gaussian modes, similar to circular polarization on the Poincare sphere, while astigmatic Hermite-Gaussian modes are associated with points on the equator, analogous to linear polarization. We discuss the propagation properties of the modes and their orbital angular momentum, which depends on the degree of astigmatism and on the location of the point on the sphere

  14. Angular anisotropy representation by probability tables

    International Nuclear Information System (INIS)

    In this paper, we improve point-wise or group-wise angular anisotropy representation by using probability tables. The starting point of this study was to give more flexibility (sensitivity analysis) and more accuracy (ray effect) to group-wise anisotropy representation by Dirac functions, independently introduced at CEA (Mao, 1998) and at IRSN (Le Cocq, 1998) ten years ago. Basing ourselves on our experience of cross-section description, acquired in CALENDF (Sublet et al., 2006), we introduce two kinds of moment based probability tables, Dirac (DPT) and Step-wise (SPT) Probability Tables where the angular probability distribution is respectively represented by Dirac functions or by a step-wise function. First, we show how we can improve equi-probable cosine representation of point-wise anisotropy by using step-wise probability tables. Then we show, by Monte Carlo techniques, how we can obtain a more accurate description of group-wise anisotropy than the one usually given by a finite expansion on a Legendre polynomial basis (that can induce negative values) and finally, we describe it by Dirac probability tables. This study is carried out in the framework of GALILEE project R and D activities (Coste-Delclaux, 2008). (authors)

  15. Understanding GRETINA using angular correlation method

    Science.gov (United States)

    Austin, Madeline

    2015-10-01

    The ability to trace the path of gamma rays through germanium is not only necessary for taking full advantage of GRETINA but also a promising possibility for homeland security defense against nuclear threats. This research tested the current tracking algorithm using the angular correlation method by comparing results from raw and tracked data to the theoretical model for Co-60. It was found that the current tracking method is unsuccessful in reproducing angular correlation. Variations to the tracking algorithm were made in the FM value, tracking angle, number of angles of separation observed, and window of coincidence in attempt to improve correlation results. From these variations it was observed that having a larger FM improved results, reducing the number of observational angles worsened correlation, and that overall larger tracking angles improved with larger windows of coincidence and vice-verse. Future research would be to refine the angle of measurement for raw data and to explore the possibility of an energy dependence by testing other elements. This work is supported by the United States Department of Energy, Office of Science, under Contract Number DE-AC02-06CH11357

  16. High-angular Resolution Laser Threat Warner

    Directory of Open Access Journals (Sweden)

    Sushil Kumar

    2007-07-01

    Full Text Available In this paper, the design and development aspects of a high-angular resolution laser-threat Warner developed at the Laser Science & Technology Centre (LASTEC, Delhi are presented. It describes a high-angular resolution laser-threat warner capable of giving warning with a resolution of i 3" when it is exposed to laser radiation from visible and near-IR pulsed solid-state laser source. It has a field of view of 90' in the azimuth direction, whereas the elevation coverage is between -5" and + 25". It is capable of handling multiple types of laser threats covering wavelength from 400 nm to 1100 nm and has an operational range of 4 km for a Q-switched laser source energy (10 ns of 10 mJ/pulse and output beam divergence of 1 mrad. The paper also describes its simulated evaluation process and field-testing which it has undergone. The result of field-testing confirms that it meets all its performance specifications mentioned above.

  17. Hydrogen bonded NHO chains formed by chloranilic acid (CLA) with 4,4′-di-t-butyl-2,2′-bipyridyl (dtBBP) in the solid state

    International Nuclear Information System (INIS)

    Graphical abstract: The molecular complex dtBBP·CLA, its crystal structure at 100 K, infrared, the DFT calculations, a phase transition at ca. 414 K, DSC, dielectric response analysis, proton dynamics, antiferroelectric properties. Highlights: ► We synthesized a novel molecular complex, dtBBP·CLA. ► We determined the crystal structure of dtBBP·CLA at 100 K. ► We detected a phase transition at 414 K in the complex and postulated its mechanism. ► We interpreted the infrared spectra of dtBBP·CLA. ► We used DFT to calculate the molecular structure of dtBBP·CLA in solid state. - Abstract: In crystalline state 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) forms with 4,4′-di-t-butyl-2,2′-bipyridyl (dtBBP) the hydrogen bonded chains along the b-axis. From one side of the CLA molecule the proton transfer takes place and the hydrogen bond length is very short (2.615 Å). A continuous infrared absorption is observed for dtBBP·CLA in the wavenumber range between 3100 and 800 cm−1 also indicating the strong hydrogen bonds. The DSC measurements show a weak, close to continuous, phase transition at 414 K. The complex dielectric permittivity for a single crystal sample was measured in the temperature range 100–440 K and at frequencies between 200 Hz and 2 MHz. The dielectric response is a combination of semiconducting properties and a relaxation process most probably connected with the proton dynamics in the hydrogen bonds. The mechanism of the structural phase transition is discussed.

  18. Ligand placement based on prior structures: the guided ligand-replacement method

    Energy Technology Data Exchange (ETDEWEB)

    Klei, Herbert E. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Moriarty, Nigel W., E-mail: nwmoriarty@lbl.gov; Echols, Nathaniel [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Terwilliger, Thomas C. [Los Alamos National Laboratory, Los Alamos, NM 87545-0001 (United States); Baldwin, Eric T. [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Natural Discovery LLC, Princeton, NJ 08542-0096 (United States); Pokross, Matt; Posy, Shana [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Adams, Paul D. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); University of California at Berkeley, Berkeley, CA 94720-1762 (United States)

    2014-01-01

    A new module, Guided Ligand Replacement (GLR), has been developed in Phenix to increase the ease and success rate of ligand placement when prior protein-ligand complexes are available. The process of iterative structure-based drug design involves the X-ray crystal structure determination of upwards of 100 ligands with the same general scaffold (i.e. chemotype) complexed with very similar, if not identical, protein targets. In conjunction with insights from computational models and assays, this collection of crystal structures is analyzed to improve potency, to achieve better selectivity and to reduce liabilities such as absorption, distribution, metabolism, excretion and toxicology. Current methods for modeling ligands into electron-density maps typically do not utilize information on how similar ligands bound in related structures. Even if the electron density is of sufficient quality and resolution to allow de novo placement, the process can take considerable time as the size, complexity and torsional degrees of freedom of the ligands increase. A new module, Guided Ligand Replacement (GLR), was developed in Phenix to increase the ease and success rate of ligand placement when prior protein–ligand complexes are available. At the heart of GLR is an algorithm based on graph theory that associates atoms in the target ligand with analogous atoms in the reference ligand. Based on this correspondence, a set of coordinates is generated for the target ligand. GLR is especially useful in two situations: (i) modeling a series of large, flexible, complicated or macrocyclic ligands in successive structures and (ii) modeling ligands as part of a refinement pipeline that can automatically select a reference structure. Even in those cases for which no reference structure is available, if there are multiple copies of the bound ligand per asymmetric unit GLR offers an efficient way to complete the model after the first ligand has been placed. In all of these applications, GLR

  19. Motion fading is driven by perceived, not actual angular velocity.

    Science.gov (United States)

    Kohler, P J; Caplovitz, G P; Hsieh, P-J; Sun, J; Tse, P U

    2010-06-01

    After prolonged viewing of a slowly drifting or rotating pattern under strict fixation, the pattern appears to slow down and then momentarily stop. Here we examine the relationship between such 'motion fading' and perceived angular velocity. Using several different dot patterns that generate emergent virtual contours, we demonstrate that whenever there is a difference in the perceived angular velocity of two patterns of dots that are in fact rotating at the same angular velocity, there is also a difference in the time to undergo motion fading for those two patterns. Conversely, whenever two patterns show no difference in perceived angular velocity, even if in fact rotating at different angular velocities, we find no difference in the time to undergo motion fading. Thus, motion fading is driven by the perceived rather than actual angular velocity of a rotating stimulus. PMID:20371254

  20. The SKA as a Doorway to Angular Momentum

    CERN Document Server

    Obreschkow, D; Popping, A; Power, C; Quinn, P; Staveley-Smith, L

    2015-01-01

    Angular momentum is one of the most fundamental physical quantities governing galactic evolution. Differences in the colours, morphologies, star formation rates and gas fractions amongst galaxies of equal stellar/baryon mass M are potentially widely explained by variations in their specific stellar/baryon angular momentum j. The enormous potential of angular momentum science is only just being realised, thanks to the emergence of the first simulations of galaxies with converged spins, paralleled by a dramatic increase in kinematic observations. Such observations are still challenged by the fact that most of the stellar/baryon angular momentum resides at large radii. In fact, the radius that maximally contributes to the angular momentum of an exponential disk (3Re-4Re) is twice as large as the radius that maximally contributes to the disk mass; thus converged measurements of angular momentum require either extremely deep IFS data or, alternatively, kinematic measurements of neutral atomic hydrogen (HI), which ...

  1. Angular momentum in quantum mechanics as a group study topic

    International Nuclear Information System (INIS)

    A largely practical approach to the teaching of angular momentum in quantum mechanics at the undergraduate level is described. In an intensive seven week period towards the end of their final year, undergraduates working in pairs perform experiments in nuclear physics which demonstrate some of the important properties of angular momentum. Three experiments are selected and discussed in this article to illustrate the teaching method. The existence of intrinsic spin and parity is investigated by measuring the polarisation of annihilation radiation; the conservation of angular momentum is demonstrated by a measurement of orbital angular momentum in a nucleon transfer reaction and the coupling of angular momenta is illustrated by the method of angular correlation. (author)

  2. Coherent detection of orbital angular momentum in radio

    OpenAIRE

    Daldorff, L. K. S.; S. M. Mohammadi; Bergman, J. E. S.; Isham, B.; Al-Nuaimi, M. K. T.; Forozesh, K.; Carozzi, T.D.

    2015-01-01

    The angular momentum propagated by a beam of radiation has two contributions: spin angular momentum (SAM) and orbital angular momentum (OAM). SAM corresponds to wave polarisation, while OAM-carrying beams are characterized by a phase which is a function of azimuth. We demonstrate experimentally that radio beams propagating OAM can be generated and coherently detected using ordinary electric dipole antennas. The results presented here could pave the way for novel radio OAM applications in tech...

  3. Angular velocity gradients in the solar convection zone

    Energy Technology Data Exchange (ETDEWEB)

    Gilman, P.A.; Foukal, P.V.

    1979-05-01

    We test the hypothesis that the weak influence of rotation upon solar supergranulation, resulting in fluid particles conserving their angular momentum while moving radially, is responsible for the outward decrease in angular velocity inferred from the difference between photospheric plasma and sunspot rotation rates. This test is performed using numerical integrations of a Boussinesq spherical convection model for a thin shell at small Taylor number (implying weak influence of rotation). We find that the convection does maintain an outward decrease in angular velocity, which approaches the limit implied by angular momentum conservation as the Rayleigh number or driving for convection is increased.By examining the energetics of the motion, we verify that the dominant process maintaining the calculated angular velocity profile against viscous diffusion is the inward transport of angular momentum by the convection. Axisymmetric meridional circulation plays virtually no role in this process. We further find there is no tendency for convection weakly influenced by rotation to form an equatorial acceleration. We argue from these and earlier calculations that the origin of the Sun's latitudinal gradient of angular velocity is deep in the convection zone. At these depths there may be a strong tendency for angular velocity to be constant on cylinders, implying a positive radial gradient of angular velocity. The latitude gradient is transmitted to the photosphere by supergranulation which locally produces the negative radial gradient in the top layers. We suggest from the rotation of various magnetic features that the transition from negative to positive radial angular velocity gradient occurs near the bottom of the supergranule layer. We argue that angular momentum conservation in radially moving fluid particles should produce a similar angular velocity profile in compressible convecting fluid layers.

  4. Angular momentum and conservation laws for dynamical black holes

    OpenAIRE

    Hayward, Sean A.

    2006-01-01

    Black holes can be practically located (e.g. in numerical simulations) by trapping horizons, hypersurfaces foliated by marginal surfaces, and one desires physically sound measures of their mass and angular momentum. A generically unique angular momentum can be obtained from the Komar integral by demanding that it satisfy a simple conservation law. With the irreducible (Hawking) mass as the measure of energy, the conservation laws of energy and angular momentum take a similar form, expressing ...

  5. Orbital angular momentum in /sup 3/He-A-italic

    Energy Technology Data Exchange (ETDEWEB)

    Balatskii-breve, A.V.; Mineev, V.P.

    1985-12-01

    The intrinsic angular momentum in the A-italic phase of superfluid /sup 3/He is found in terms of the response to the angular velocity of rotation. It is shown that in the weak-coupling approximation at an arbitrary temperature and with allowance for the Fermi-liquid renormalization the intrinsic angular momentum is small in accordance with the smallness of the asymmetry in the distribution of particles and holes.

  6. Quantum orbital angular momentum of elliptically-symmetric light

    OpenAIRE

    Plick, William N.; Krenn, Mario; Fickler, Robert; Ramelow, Sven; Zeilinger, Anton

    2012-01-01

    We present a quantum mechanical analysis of the orbital angular momentum of a class of recently discovered elliptically-symmetric stable light fields --- the so-called Ince-Gauss modes. We study, in a fully quantum formalism, how the orbital angular momentum of these beams varies with their ellipticity and discover several compelling features, including: non-monotonic behavior, stable beams with real continuous (non-integer) orbital angular momenta, and orthogonal modes with the same orbital ...

  7. Spin and orbital angular momentum of the tensor gauge field

    OpenAIRE

    Chen, Xiang-Song; Zhu, Ben-Chao; Murchadha, Niall Ó

    2011-01-01

    Following the recent studies of the trickiness in spin and orbital angular momentum of the vector gauge fields, we perform here a parallel analysis for the tensor gauge field, which has certain relation to gravitation. Similarly to the vector case, we find a nice feature that after removing all gauge degrees of freedom the angular momentum of the tensor gauge field vanishes for a stationary system. This angular momentum also shows a one-parameter invariance over the infinitely many ways of co...

  8. Quantitative measurement of orbital angular momentum in electron microscopy

    OpenAIRE

    Clark, L.; Béché, A.; Guzzinati, G.; Verbeeck, J.

    2014-01-01

    Abstract: Electron vortex beams have been predicted to enable atomic scale magnetic information measurement, via transfer of orbital angular momentum. Research so far has focused on developing production techniques and applications of these beams. However, methods to measure the outgoing orbital angular momentum distribution are also a crucial requirement towards this goal. Here, we use a method to obtain the orbital angular momentum decomposition of an electron beam, using a multipinhole int...

  9. Orbital angular momentum exchange in post-collision interaction

    Energy Technology Data Exchange (ETDEWEB)

    Burgt, P.J.M. van der; Eck, J. van; Heideman, H.G.M.

    1985-03-14

    The authors have measured the angular distribution of electrons ejected by the He**(2s/sup 2/)/sup 1/S autoionising state after its electron impact excitation via the He/sup -/(2s2p/sup 2/)/sup 2/D resonance. Taking into account interference with electrons from the direct ionisation of helium, analysis of this angular distribution provides evidence for angular momentum exchange between ejected and scattered electrons during the post-collision interaction.

  10. Parton Orbital Angular Momentum and Final State Interactions

    OpenAIRE

    Burkardt, Matthias

    2012-01-01

    Definitions of orbital angular momentum based on Wigner distributions are used as a framework to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar.We find that the difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asym...

  11. Quark Orbital Angular Momentum in the MIT Bag Model

    OpenAIRE

    Burkardt, Matthias; Jarrah, Abdullah

    2010-01-01

    Using the MIT bag model, we study the contribution from the gluon vector potential due to the spectators to the orbital angular momentum of a quark in the bag model. For $\\alpha_s = {\\cal O}(1)$, this spectator contribution to the quark orbital angular momentum in the gauge-covariant Ji decomposition is of the same order as the non gauge-covariant quark orbital angular momentum and its magnitude is larger for $d$ than for $u$ quarks and negative for both.

  12. Spin-orbit coupling and the conservation of angular momentum

    OpenAIRE

    Hnizdo, V.

    2011-01-01

    In nonrelativistic quantum mechanics, the total (i.e. orbital plus spin) angular momentum of a charged particle with spin that moves in a Coulomb plus spin-orbit-coupling potential is conserved. In a classical nonrelativistic treatment of this problem, in which the Lagrange equations determine the orbital motion and the Thomas equation yields the rate of change of the spin, the particle's total angular momentum in which the orbital angular momentum is defined in terms of the kinetic momentum ...

  13. Acoustic orbital angular momentum transfer to matter by chiral scattering

    OpenAIRE

    Wunenburger, Régis; Israel, Juan; Lozano, Vazquez; Brasselet, Etienne

    2015-01-01

    We report on orbital angular momentum exchange between sound and matter mediated by a non-dissipative chiral scattering process. An experimental demonstration is made possible by irradiating a three-dimensional printed, spiral-shaped chiral object with an incident ultrasonic beam carrying zero orbital angular momentum. Chiral refraction is shown to impart a nonzero orbital angular momentum to the scattered field and to rotate the object. This result constitutes a proof of concept of a novel k...

  14. Quark Orbital Angular Momentum and Final State Interactions

    OpenAIRE

    Burkardt, Matthias

    2014-01-01

    Definitions of orbital angular momentum based on Wigner distributions are used to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. The difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asymmetries in semi-inclusive d...

  15. Light with orbital angular momentum interacting with trapped ions

    OpenAIRE

    Schmiegelow, Christian Tomás; Schmidt-Kaler, Ferdinand

    2011-01-01

    We study the interaction of a light beams carrying angular momentum with a single, trapped and well localized ion. We provide a detailed calculation of selection rules and excitation probabilities for quadrupole transitions. The results show the dependencies on the angular momentum and polarization of the laser beam as well as the direction of the quantization magnetic field. In order to observe optimally the specific effects, focusing the angular momentum beam close to the diffraction limit ...

  16. Orbital Angular Momentum Parton Distributions in Light-Front Dynamics

    OpenAIRE

    Cano, F.; Faccioli, P.; Scopetta, S.; Traini, M.(Dipartimento di Fisica, Università degli studi di Trento and INFN — TIFPA, Via Sommarive 14, I-38123, Povo (Trento), Italy)

    2000-01-01

    We study the quark angular momentum distribution in the nucleon within a light-front covariant quark model. Special emphasis is put into the orbital angular momentum: a quantity which is very sensitive to the relativistic treatment of the spin in a light-front dynamical approach. Discrepancies with the predictions of the low-energy traditional quark models where relativistic spin effects are neglected, are visible also after perturbative evolution to higher momentum scales. Orbital angular mo...

  17. Orbital angular momentum from marginals of quadrature distributions

    OpenAIRE

    Sanchez-Soto, L. L.; Klimov, A. B.; de la Hoz, P.; Rigas, I.; J. Rehacek; Hradil, Z.; Leuchs, G.

    2013-01-01

    We set forth a method to analyze the orbital angular momentum of a light field. Instead of using the canonical formalism for the conjugate pair angle-angular momentum, we model this latter variable by the superposition of two independent harmonic oscillators along two orthogonal axes. By describing each oscillator by a standard Wigner function, we derive, via a consistent change of variables, a comprehensive picture of the orbital angular momentum. We compare with previous approaches and show...

  18. Angular momentum evolution in laser-plasma accelerators

    OpenAIRE

    Thaury, Cédric; E. Guillaume; Corde, Sébastien; Lehe, R.; Le Bouteiller, M.; Ta Phuoc, K.; X. Davoine; Rax, Jean-Marcel; Rax, J. M.; Rousse, Antoine; Malka, Victor

    2013-01-01

    The transverse properties of an electron beam are characterized by two quantities, the emittance which indicates the electron beam extend in the phase space and the angular momentum which allows for non-planar electron trajectories. Whereas the emittance of electron beams produced in laser- plasma accelerator has been measured in several experiments, their angular momentum has been scarcely studied. It was demonstrated that electrons in laser-plasma accelerator carry some angular momentum, bu...

  19. Ligand photo-isomerization triggers conformational changes in iGluR2 ligand binding domain.

    Directory of Open Access Journals (Sweden)

    Tino Wolter

    Full Text Available Neurological glutamate receptors bind a variety of artificial ligands, both agonistic and antagonistic, in addition to glutamate. Studying their small molecule binding properties increases our understanding of the central nervous system and a variety of associated pathologies. The large, oligomeric multidomain membrane protein contains a large and flexible ligand binding domains which undergoes large conformational changes upon binding different ligands. A recent application of glutamate receptors is their activation or inhibition via photo-switchable ligands, making them key systems in the emerging field of optochemical genetics. In this work, we present a theoretical study on the binding mode and complex stability of a novel photo-switchable ligand, ATA-3, which reversibly binds to glutamate receptors ligand binding domains (LBDs. We propose two possible binding modes for this ligand based on flexible ligand docking calculations and show one of them to be analogues to the binding mode of a similar ligand, 2-BnTetAMPA. In long MD simulations, it was observed that transitions between both binding poses involve breaking and reforming the T686-E402 protein hydrogen bond. Simulating the ligand photo-isomerization process shows that the two possible configurations of the ligand azo-group have markedly different complex stabilities and equilibrium binding modes. A strong but slow protein response is observed after ligand configuration changes. This provides a microscopic foundation for the observed difference in ligand activity upon light-switching.

  20. Studies on the local angular distortion and spin Hamiltonian parameters for the trigonal Co2+ center in MgCl2

    International Nuclear Information System (INIS)

    The local angular distortion and spin Hamiltonian parameters (g factor g verticalstrokeverticalstroke, g perpendicularto and the hyperfine structure constants) for the trigonal Co2+ center in MgCl2 are theoretically studied by diagonalizing the 6 x 6 energy matrix of ground 4T1 state for a trigonally distorted octahedral 3d7 cluster. Based on the cluster approach, the contributions from the admixtures of various J (= 1/2, 3/2, 5/2) states and the ligand orbital and spin-orbit coupling interactions are taken into account in a uniform way. The local impurity-ligand bond angle in the Co2+ center is found to be about 3.44 larger than the host metal-ligand bond angle in the pure crystal due to substitution of smaller Mg2+ by bigger Co2+, inducing a further compressed ligand octahedron. The calculated spin Hamiltonian parameters using the above local angular distortion are in good agreement with the experimental data. The present studies on the local structure and the spin Hamiltonian parameters for Co2+ in MgCl2 are tentatively extended to a more general case by comparing the relevant impurity behaviours for Co2+ in various trigonal environments.

  1. Studies on the Local Angular Distortion and Spin Hamiltonian Parameters for the Trigonal Co2+ Center in MgCl2

    Science.gov (United States)

    Hu, Xian-Fen; Wu, Shao-Yi; Kuang, Min-Quan; Li, Guo-Liang

    2014-11-01

    The local angular distortion and spin Hamiltonian parameters (g factors g||, g⊥ and the hyperfine structure constants) for the trigonal Co2+ center in MgCl2 are theoretically studied by diagonalizing the 6×6 energy matrix of ground 4T1 state for a trigonally distorted octahedral 3d7 cluster. Based on the cluster approach, the contributions from the admixtures of various J (= 1/2;3/2;5/2) states and the ligand orbital and spin-orbit coupling interactions are taken into account in a uniform way. The local impurity-ligand bond angle in the Co2+ center is found to be about 3.44° larger than the host metal-ligand bond angle in the pure crystal due to substitution of smaller Mg2+ by bigger Co2+, inducing a further compressed ligand octahedron. The calculated spin Hamiltonian parameters using the above local angular distortion are in good agreement with the experimental data. The present studies on the local structure and the spin Hamiltonian parameters for Co2+ in MgCl2 are tentatively extended to a more general case by comparing the relevant impurity behaviours for Co2+ in various trigonal environments.

  2. Optical communication beyond orbital angular momentum

    Science.gov (United States)

    Trichili, Abderrahmen; Rosales-Guzmán, Carmelo; Dudley, Angela; Ndagano, Bienvenu; Ben Salem, Amine; Zghal, Mourad; Forbes, Andrew

    2016-01-01

    Mode division multiplexing (MDM) is mooted as a technology to address future bandwidth issues, and has been successfully demonstrated in free space using spatial modes with orbital angular momentum (OAM). To further increase the data transmission rate, more degrees of freedom are required to form a densely packed mode space. Here we move beyond OAM and demonstrate multiplexing and demultiplexing using both the radial and azimuthal degrees of freedom. We achieve this with a holographic approach that allows over 100 modes to be encoded on a single hologram, across a wide wavelength range, in a wavelength independent manner. Our results offer a new tool that will prove useful in realizing higher bit rates for next generation optical networks. PMID:27283799

  3. Angular characteristics of pion-nucleus interaction

    International Nuclear Information System (INIS)

    In the present paper pion-nucleus interactions have been studied using nuclear emulsion technique. The investigation of these interactions is expected to provide some very useful information about the multiparticle production mechanism. Nuclear emulsion is a material which memorizes the tracks of charged particles. When a primary particle collides with a nucleus, it may interact with the nucleons of the target nucleus in two ways. In the first case, independent reactions may take place between the incident particle and the nucleons present in the target nucleus. Secondly the primary particle may interact coherently with the various nucleons of the target nucleus and the secondary particles are produced. Angular distribution of charged secondaries produced in these interactions has been studied for central collision events. Different workers have used different criterion for the selection of central collisions. We analysed the events with high shower particle multiplicity i.e., Ns ≥ 28 and call them as central collision events

  4. Arbitrarily tunable orbital angular momentum of photons.

    Science.gov (United States)

    Pan, Yue; Gao, Xu-Zhen; Ren, Zhi-Cheng; Wang, Xi-Lin; Tu, Chenghou; Li, Yongnan; Wang, Hui-Tian

    2016-01-01

    Orbital angular momentum (OAM) of photons, as a new fundamental degree of freedom, has excited a great diversity of interest, because of a variety of emerging applications. Arbitrarily tunable OAM has gained much attention, but its creation remains still a tremendous challenge. We demonstrate the realization of well-controlled arbitrarily tunable OAM in both theory and experiment. We present the concept of general OAM, which extends the OAM carried by the scalar vortex field to the OAM carried by the azimuthally varying polarized vector field. The arbitrarily tunable OAM we presented has the same characteristics as the well-defined integer OAM: intrinsic OAM, uniform local OAM and intensity ring, and propagation stability. The arbitrarily tunable OAM has unique natures: it is allowed to be flexibly tailored and the radius of the focusing ring can have various choices for a desired OAM, which are of great significance to the benefit of surprising applications of the arbitrary OAM. PMID:27378234

  5. Optical communication beyond orbital angular momentum

    Science.gov (United States)

    Trichili, Abderrahmen; Rosales-Guzmán, Carmelo; Dudley, Angela; Ndagano, Bienvenu; Ben Salem, Amine; Zghal, Mourad; Forbes, Andrew

    2016-06-01

    Mode division multiplexing (MDM) is mooted as a technology to address future bandwidth issues, and has been successfully demonstrated in free space using spatial modes with orbital angular momentum (OAM). To further increase the data transmission rate, more degrees of freedom are required to form a densely packed mode space. Here we move beyond OAM and demonstrate multiplexing and demultiplexing using both the radial and azimuthal degrees of freedom. We achieve this with a holographic approach that allows over 100 modes to be encoded on a single hologram, across a wide wavelength range, in a wavelength independent manner. Our results offer a new tool that will prove useful in realizing higher bit rates for next generation optical networks.

  6. Effects of Angular Momentum on Halo Profiles

    CERN Document Server

    Lentz, Erik W; Rosenberg, Leslie J

    2016-01-01

    The near universality of DM halo density profiles provided by N-body simulations has proven to be robust against changes in total mass density, power spectrum, and some forms of initial velocity dispersion. In this letter we study the effects of coherently spinning up an isolated DM-only progenitor on halo structure. Halos with spins within several standard deviations of the simulated mean ($\\lambda \\lesssim 0.20$) produce profiles with negligible deviations from the universal form. Only when the spin becomes quite large ($\\lambda \\gtrsim 0.20$) do departures become evident. The angular momentum distribution also exhibits a near universal form, which is also independent of halo spin up to $\\lambda \\lesssim 0.20$. A correlation between these epidemic profiles and the presence of a strong bar in the virialized halo is also observed. These bar structures bear resemblance to the radial orbit instability in the rotationless limit.

  7. Angular Spectrum Simulation of Pulsed Ultrasound Fields

    DEFF Research Database (Denmark)

    Du, Yigang; Jensen, Henrik; Jensen, Jørgen Arendt

    The optimization of non-linear ultrasound imaging should in a first step be based on simulation, as this makes parameter studies considerably easier than making transducer prototypes. Such a simulation program should be capable of simulating non-linear pulsed fields for arbitrary transducer...... geometries for any kind of focusing and apodization. The Angular Spectrum Approach (ASA) is capable of simulating monochromatic non-linear acoustic wave propagation. However, for ultrasound imaging the time response of each specific point in space is required, and a pulsed ASA simulation with multi temporal...... frequencies must be performed. Combining it with Field II, the generation of non-linear simulation for any geometry with any excitation array transducer becomes feasible. The purpose of this paper is to make a general pulsed simulation software using the modified ASA. Linear and phased array transducers are...

  8. Angular Size-Redshift: Experiment and Calculation

    CERN Document Server

    Amirkhanyan, V R

    2015-01-01

    In this paper the next attempt is made to clarify the nature of the Euclidean behavior of the boundary in the angular size-redshift cosmological test. It is shown experimentally that this can be explained by the selection determined by anisotropic morphology and anisotropic radiation of extended radio sources. A catalogue of extended radio sources with minimal flux densities of about 0.01 Jy at 1.4 GHz was compiled for conducting the test. Without the assumption of their size evolution, the agreement between the experiment and calculation was obtained both in the Lambda CDM model (Omega_m=0.27 , Omega_v=0.73.) and the Friedman model (Omega = 0.1 ).

  9. Arbitrarily tunable orbital angular momentum of photons

    Science.gov (United States)

    Pan, Yue; Gao, Xu-Zhen; Ren, Zhi-Cheng; Wang, Xi-Lin; Tu, Chenghou; Li, Yongnan; Wang, Hui-Tian

    2016-01-01

    Orbital angular momentum (OAM) of photons, as a new fundamental degree of freedom, has excited a great diversity of interest, because of a variety of emerging applications. Arbitrarily tunable OAM has gained much attention, but its creation remains still a tremendous challenge. We demonstrate the realization of well-controlled arbitrarily tunable OAM in both theory and experiment. We present the concept of general OAM, which extends the OAM carried by the scalar vortex field to the OAM carried by the azimuthally varying polarized vector field. The arbitrarily tunable OAM we presented has the same characteristics as the well-defined integer OAM: intrinsic OAM, uniform local OAM and intensity ring, and propagation stability. The arbitrarily tunable OAM has unique natures: it is allowed to be flexibly tailored and the radius of the focusing ring can have various choices for a desired OAM, which are of great significance to the benefit of surprising applications of the arbitrary OAM. PMID:27378234

  10. Colliding particles carrying nonzero orbital angular momentum

    International Nuclear Information System (INIS)

    Photons carrying nonzero orbital angular momentum (twisted photons) are well-known in optics. Recently, using Compton backscattering to boost optical twisted photons to high energies was suggested. Twisted electrons in the intermediate energy range have also been produced recently. Thus, collisions involving energetic twisted particles seem to be feasible and represent a new tool in high-energy physics. Here we discuss some generic features of scattering processes involving twisted particles in the initial and/or final state. In order to avoid additional complications arising from nontrivial polarization states, we focus here on scalar fields only. We show that processes involving twisted particles allow one to perform a Fourier analysis of the plane-wave cross section with respect to the azimuthal angles of the initial particles. In addition, using twisted states, one can probe the autocorrelation function of the amplitude, which is inaccessible in the plane-wave collisions. Finally, we discuss prospects for experimental study of these effects.

  11. Four-photon orbital angular momentum entanglement

    CERN Document Server

    Hiesmayr, B C; Löffler, W

    2015-01-01

    Quantum entanglement shared between more than two particles is essential to foundational questions in quantum mechanics, and upcoming quantum information technologies. So far, up to 14 two-dimensional qubits have been entangled, and an open question remains if one can also demonstrate entanglement of higher-dimensional discrete properties of more than two particles. A promising route is the use of the photon orbital angular momentum (OAM), which enables implementation of novel quantum information protocols, and the study of fundamentally new quantum states. To date, only two of such multidimensional particles have been entangled albeit with ever increasing dimensionality. Here we use pulsed spontaneous parametric downconversion (SPDC) to produce photon quadruplets that are entangled in their OAM, or transverse-mode degrees of freedom; and witness genuine multipartite Dicke-type entanglement. Apart from addressing foundational questions, this could find applications in quantum metrology, imaging, and secret sh...

  12. Arbitrary orbital angular momentum of photons

    CERN Document Server

    Pan, Yue; Ren, Zhi-Cheng; Wang, Xi-Lin; Tu, Chenghou; Li, Yongnan; Wang, Hui-Tian

    2015-01-01

    Orbital angular momentum (OAM) of photons, as a new fundamental degree of freedom, has excited a great diversity of interest, because of a variety of emerging applications. Arbitrarily tunable OAM has gained much attention, but its creation remains still a tremendous challenge. We demonstrate the realization of well-controlled arbitrary OAM in both theory and experiment. We present the concept of general OAM, which extends the OAM carried by the scalar vortex field to the OAM carried by the azimuthally varying polarized vector field. The arbitrary OAM has the same characteristics as the well-defined integer OAM: intrinsic OAM, uniform local OAM and intensity ring, and propagation stability. The arbitrary OAM has unique natures: it is allowed to be flexibly tailored and the radius of the focusing ring can have various choices for a desired OAM, which are of great significance to the benefit of surprising applications of the arbitrary OAM.

  13. Orbital angular momentum entanglement in turbulence

    CERN Document Server

    Ibrahim, Alpha Hamadou; McLaren, Melanie; Konrad, Thomas; Forbes, Andrew

    2013-01-01

    The turbulence induced decay of orbital angular momentum (OAM) entanglement between two photons is investigated numerically and experimentally. To compare our results with previous work, we simulate the turbulent atmosphere with a single phase screen based on the Kolmogorov theory of turbulence. We consider two different scenarios: in the first only one of the two photons propagates through turbulence, and in the second both photons propagate through uncorrelated turbulence. Comparing the entanglement evolution for different OAM values, we found the entanglement to be more robust in turbulence for higher OAM values. We derive an empirical formula for the distance scale at which entanglement decays in term of the scale parameters and the OAM value.

  14. Orbital angular momentum-entanglement frequency transducer

    CERN Document Server

    Zhou, Zhi-Yuan; Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Dong, Ming-Xin; Shi, Bao-Sen; Guo, Guang-Can

    2016-01-01

    Entanglement is a vital resource for realizing many tasks such as teleportation, secure key distribution, metrology and quantum computations. To effectively build entanglement between different quantum systems and share information between them, a frequency transducer to convert between quantum states of different wavelengths while retaining its quantum features is indispensable. Information encoded in the photons orbital angular momentum OAM degrees of freedom is preferred in harnessing the information carrying capacity of a single photon because of its unlimited dimensions. A quantum transducer, which operates at wavelengths from 1558.3 nm to 525 nm for OAM qubits, OAMpolarization hybrid entangled states, and OAM entangled states, is reported for the first time. Nonclassical properties and entanglements are demonstrated following the conversion process by performing quantum tomography, interference, and Bell inequality measurements. Our results demonstrate the capability to create an entanglement link betwe...

  15. Colliding particles carrying nonzero orbital angular momentum

    Science.gov (United States)

    Ivanov, Igor P.

    2011-05-01

    Photons carrying nonzero orbital angular momentum (twisted photons) are well-known in optics. Recently, using Compton backscattering to boost optical twisted photons to high energies was suggested. Twisted electrons in the intermediate energy range have also been produced recently. Thus, collisions involving energetic twisted particles seem to be feasible and represent a new tool in high-energy physics. Here we discuss some generic features of scattering processes involving twisted particles in the initial and/or final state. In order to avoid additional complications arising from nontrivial polarization states, we focus here on scalar fields only. We show that processes involving twisted particles allow one to perform a Fourier analysis of the plane-wave cross section with respect to the azimuthal angles of the initial particles. In addition, using twisted states, one can probe the autocorrelation function of the amplitude, which is inaccessible in the plane-wave collisions. Finally, we discuss prospects for experimental study of these effects.

  16. Coherent control of photoelectron wavepacket angular interferograms

    Science.gov (United States)

    Hockett, P.; Wollenhaupt, M.; Baumert, T.

    2015-11-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process, where the final (time-integrated) observable coherently samples all instantaneous states of the light-matter interaction. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable.

  17. Coherent Control of Photoelectron Wavepacket Angular Interferograms

    CERN Document Server

    Hockett, Paul; Baumert, Thomas

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable.

  18. Angular reduction in multiparticle matrix elements

    International Nuclear Information System (INIS)

    A general method for reduction of coupled spherical harmonic products is presented. When the total angular coupling is zero, the reduction leads to an explicitly real expression in the scalar products of the unit vector arguments of the spherical harmonics. For nonscalar couplings, the reduction gives Cartesian tensor forms for the spherical harmonic products; tensors built from the physical vectors in the original expression. The reduction for arbitrary couplings is given in closed form, making it amenable to symbolic manipulation on a computer. The final expressions do not depend on a special choice of coordinate axes, nor do they contain azimuthal quantum number summations, or do they have complex tensor terms for couplings to a scalar; consequently, they are easily interpretable from the properties of the physical vectors they contain

  19. Orbital angular momentum photonic quantum interface

    CERN Document Server

    Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Shi, Bao-Sen; Guo, Guang-Can

    2014-01-01

    High dimensional orbital angular momentum (OAM) light states are very important in enhancing the information carrying capacity in optical communications and quantum key distributions. Light at wavelengths of fiber communication windows or free space communication windows are suitable for long distance quantum communication, but most quantum processing tasks are performed in the visible wavelength ranges. The interface to bridge the wavelength gap of single photon with Gaussian shape has been realized, however, to create such interface for OAM-carrying light is a great challenge. We report the demonstration of such an interface to frequency up-conversion of herald single photon OAM state from 1560nm to 525nm with high efficiency by using nonlinear crystal in an external cavity. We show that different single photon OAM light shapes are observed directly by using single photon counting camera and the single photon entangled property is retained in the conversion process.

  20. Angular energy response of personnel thermoluminescent dosimeters

    International Nuclear Information System (INIS)

    The angular energy dependence of the response of two commercial thermoluminescent dosimeter systems was investigated. The first personnel dosimeter investigated was the Radi-Guard which is a multi-area LiF (TLD-700) locked in Teflon matrix and incorporated with a PB-2 holder developed by Teledyne Isotopes. The second one was the BG-7 which is comprised of two LiF (TLD-700) chips developed by Harshaw, but the TH-2 holder was fabricated at National Tsing Hua University. The angle of incidence was varied from perpendicular to parallel for 90Sr-90Y β radiation, 241Am and 60Co γ radiation. Experimental results are presented and discussed

  1. Optical communication beyond orbital angular momentum.

    Science.gov (United States)

    Trichili, Abderrahmen; Rosales-Guzmán, Carmelo; Dudley, Angela; Ndagano, Bienvenu; Ben Salem, Amine; Zghal, Mourad; Forbes, Andrew

    2016-01-01

    Mode division multiplexing (MDM) is mooted as a technology to address future bandwidth issues, and has been successfully demonstrated in free space using spatial modes with orbital angular momentum (OAM). To further increase the data transmission rate, more degrees of freedom are required to form a densely packed mode space. Here we move beyond OAM and demonstrate multiplexing and demultiplexing using both the radial and azimuthal degrees of freedom. We achieve this with a holographic approach that allows over 100 modes to be encoded on a single hologram, across a wide wavelength range, in a wavelength independent manner. Our results offer a new tool that will prove useful in realizing higher bit rates for next generation optical networks. PMID:27283799

  2. Ruthenium Cumulenylidene Complexes Bearing Heteroscorpionate Ligands

    OpenAIRE

    Strinitz, Frank

    2014-01-01

    In previous work of the BURZLAFF group, the design of suitable N,N,O ligands for a wide variety of applications ranging from catalysis to bioinorganic model compounds has been extensively investigated. Especially the methyl substituted bis(3,5-dimethylpyrazol-1-yl) acetate (bdmpza) ligand has shown manifold chemistry, comparable to the anionic cyclopentadienyl (Cp) and hydridotris(pyrazol-1-yl)borato (Tp) ligand. In the first part of this thesis the new tricarbonylmanganese(I) complexes be...

  3. Phenotypic spandrel: absolute discrimination and ligand antagonism

    OpenAIRE

    François, Paul; Johnson, Kyle A.; Saunders, Laura N.

    2015-01-01

    We consider the general problem of absolute discrimination between categories of ligands irrespective of their concentration. An instance of this problem is immune discrimination between self and not-self. We connect this problem to biochemical adaptation, and establish that ligand antagonism - the ability of sub threshold ligands to negatively impact response - is a necessary consequence of absolute discrimination.Thus antagonism constitutes a "phenotypic spandrel": a phenotype existing as a...

  4. Angular Approach Scanning Ion Conductance Microscopy.

    Science.gov (United States)

    Shevchuk, Andrew; Tokar, Sergiy; Gopal, Sahana; Sanchez-Alonso, Jose L; Tarasov, Andrei I; Vélez-Ortega, A Catalina; Chiappini, Ciro; Rorsman, Patrik; Stevens, Molly M; Gorelik, Julia; Frolenkov, Gregory I; Klenerman, David; Korchev, Yuri E

    2016-05-24

    Scanning ion conductance microscopy (SICM) is a super-resolution live imaging technique that uses a glass nanopipette as an imaging probe to produce three-dimensional (3D) images of cell surface. SICM can be used to analyze cell morphology at nanoscale, follow membrane dynamics, precisely position an imaging nanopipette close to a structure of interest, and use it to obtain ion channel recordings or locally apply stimuli or drugs. Practical implementations of these SICM advantages, however, are often complicated due to the limitations of currently available SICM systems that inherited their design from other scanning probe microscopes in which the scan assembly is placed right above the specimen. Such arrangement makes the setting of optimal illumination necessary for phase contrast or the use of high magnification upright optics difficult. Here, we describe the designs that allow mounting SICM scan head on a standard patch-clamp micromanipulator and imaging the sample at an adjustable approach angle. This angle could be as shallow as the approach angle of a patch-clamp pipette between a water immersion objective and the specimen. Using this angular approach SICM, we obtained topographical images of cells grown on nontransparent nanoneedle arrays, of islets of Langerhans, and of hippocampal neurons under upright optical microscope. We also imaged previously inaccessible areas of cells such as the side surfaces of the hair cell stereocilia and the intercalated disks of isolated cardiac myocytes, and performed targeted patch-clamp recordings from the latter. Thus, our new, to our knowledge, angular approach SICM allows imaging of living cells on nontransparent substrates and a seamless integration with most patch-clamp setups on either inverted or upright microscopes, which would facilitate research in cell biophysics and physiology. PMID:27224490

  5. Angular dynamics of small crystals in viscous flow

    CERN Document Server

    Fries, J; Mehlig, B

    2016-01-01

    The angular dynamics of a very small ellipsoidal particle in a viscous flow decouples from its translational dynamics, and the particle angular velocity is given by Jeffery's theory. It is known that cuboid particles share these properties. In the literature a special case is most frequently discussed, that of axisymmetric particles, with a continuous rotational symmetry. Here we compute the angular dynamics of crystals that possess a discrete rotational symmetry and certain mirror symmetries, but that do not have a continuous rotational symmetry. We give examples of such particles that nevertheless obey Jeffery's theory. But there are other examples where the angular dynamics is determined by a more general equation of motion.

  6. Installation for e-γ angular correlation measurements

    International Nuclear Information System (INIS)

    A set-up for measurements of e-γ angular correlations consisting of Si(Li) conversion electron detector and either single Ge(Li) or two NaJ(Tl) gamma detectors is described. The Si(Li) detector chamber is designed in such a way as to enable to employ the perturbed e-γ and βγ angular correlation technique for measurements of e-γ angular correlations and for studies of quadrupole interactions. Operation of the set-up was tested via calibration measurements of angular correlations in decays of 169Tm

  7. Orbital Angular Momentum in the Chiral Quark Model

    OpenAIRE

    Song, Xiaotong

    1998-01-01

    We developed a new and unified scheme for describing both quark spin and orbital angular momenta in symmetry-breaking chiral quark model. The loss of quark spin in the chiral splitting processes is compensated by the gain of the orbital angular momentum carried by quarks and antiquarks. The sum of both spin and orbital angular momenta carried by quarks and antiquarks is 1/2. The analytic and numerical results for the spin and orbital angular momenta carried by quarks and antiquarks in the nuc...

  8. Quark orbital-angular-momentum distribution in the nucleon

    Energy Technology Data Exchange (ETDEWEB)

    Hoodbhoy, P.; Ji, X.; Lu, W. [Department of Physics, University of Maryland, College Park, Maryland 20742 (United States)

    1999-01-01

    We introduce gauge-invariant quark and gluon angular momentum distributions after making a generalization of the angular momentum density operators. From the quark angular momentum distribution, we define the gauge-invariant and leading-twist quark {ital orbital} angular momentum distribution L{sub q}(x). The latter can be extracted from data on the polarized and unpolarized quark distributions and the off-forward distribution E(x) in the forward limit. We comment upon the evolution equations obeyed by this as well as other orbital distributions considered in the literature. {copyright} {ital 1998} {ital The American Physical Society}

  9. On angular momentum transport in convection-dominated accretion flows

    CERN Document Server

    Igumenshchev, I V

    2002-01-01

    Convection-dominated accretion flow (CDAF) is a promising model to explain underluminous accreting black holes in X-ray binaries and galactic nuclei. I discuss effects of angular momentum transport in viscous hydrodynamical and MHD CDAFs. In hydrodynamical CDAFs, convection transports angular momentum inward, and this together with outward convection transport of thermal energy determine the radial structure of the flow. In MHD CDAFs, convection can transport angular momentum either inward or outward, depending on properties of turbulence in rotating magnetized plasma, which are not fully understood yet. Direction of convection angular momentum transport can affect the law of rotation of MHD CDAFs.

  10. Mechanical memory for photons with orbital angular momentum

    International Nuclear Information System (INIS)

    We propose to use an acoustic surface wave as a memory for a photon carrying orbital angular momentum. We clarify the physical mechanism that enables the transfer of information, derive the angular momentum selection rule that must be obeyed in the process and show how to optimize the optoacoustic coupling. We theoretically demonstrate that high fidelities can be achieved, using realistic parameters, for the transfer of a coherent optical Laguerre–Gaussian state, associated with large angular momentum, to a mechanical shear mode. Our results add a significant possibility to the ongoing efforts towards the implementation of quantum information processing using photonic orbital angular momentum. (fast track communication)

  11. Quantitative measurement of orbital angular momentum in electron microscopy

    CERN Document Server

    Clark, L; Guzzinati, G; Verbeeck, J

    2014-01-01

    Electron vortex beams have been predicted to enable atomic scale magnetic information measurement, via transfer of orbital angular momentum. Research so far has focussed on developing production techniques and applications of these beams. However, methods to measure the outgoing orbital angular momentum distribution are also a crucial requirement towards this goal. Here, we use a method to obtain the orbital angular momentum decomposition of an electron beam, using a multi-pinhole interferometer. We demonstrate both its ability to accurately measure orbital angular momentum distribution, and its experimental limitations when used in a transmission electron microscope.

  12. Quark orbital-angular-momentum distribution in the nucleon

    International Nuclear Information System (INIS)

    We introduce gauge-invariant quark and gluon angular momentum distributions after making a generalization of the angular momentum density operators. From the quark angular momentum distribution, we define the gauge-invariant and leading-twist quark orbital angular momentum distribution Lq(x). The latter can be extracted from data on the polarized and unpolarized quark distributions and the off-forward distribution E(x) in the forward limit. We comment upon the evolution equations obeyed by this as well as other orbital distributions considered in the literature. copyright 1998 The American Physical Society

  13. Mechanical memory for photons with orbital angular momentum

    CERN Document Server

    Shi, H

    2013-01-01

    We propose to use an acoustic surface wave as a memory for a photon carrying orbital angular momentum. We clarify the physical mechanism that enables the transfer of information, derive the angular momentum selection rule that must be obeyed in the process, and show how to optimize the optoacoustic coupling. We theoretically demonstrate that high fidelities can be achieved, using realistic parameters, for the transfer of a coherent optical Laguerre-Gaussian state, associated with large angular momentum, to a mechanical shear mode. Our results add a significant possibility to the ongoing efforts towards the implementation of quantum information processing using photonic orbital angular momentum.

  14. Acoustic orbital angular momentum transfer to matter by chiral scattering

    Science.gov (United States)

    Wunenburger, Régis; Israel Vazquez Lozano, Juan; Brasselet, Etienne

    2015-10-01

    We report on orbital angular momentum exchange between sound and matter mediated by a non-dissipative chiral scattering process. An experimental demonstration is made possible by irradiating a three-dimensional printed, spiral-shaped chiral object with an incident ultrasonic beam carrying zero orbital angular momentum. Chiral refraction is shown to impart a nonzero orbital angular momentum to the scattered field and to rotate the object. This result constitutes a proof of concept of a novel kind of acoustic angular manipulation of matter.

  15. Angular momentum transfer and equilibrium in heavy-ion reactions

    International Nuclear Information System (INIS)

    By concentrating on the microscopic degrees of freedom for two colliding ions, we have derived a probability density for angular momentum transfer assuming that, for equilibrium, this probability is proportional to the density of states taken from a fermi gas model. This density has been used to predict angular momentum transfer, assuming first, initial angular momentum fixed, and then, final energy fixed. The results are quite different. The density (final energy fixed) has been used to predict the results of angular momentum transfer experiments. The excellent agreement supports the validity of an assumption of equilibrium. (author)

  16. Clinical Use of PPARγ Ligands in Cancer

    Directory of Open Access Journals (Sweden)

    Jennifer L. Hatton

    2008-01-01

    Full Text Available The role of PPARγ in adipocyte differentiation has fueled intense interest in the function of this steroid nuclear receptor for regulation of malignant cell growth and differentiation. Given the antiproliferative and differentiating effects of PPARγ ligands on liposarcoma cells, investigation of PPARγ expression and ligand activation in other solid tumors such as breast, colon, and prostate cancers ensued. The anticancer effects of PPARγ ligands in cell culture and rodent models of a multitude of tumor types suggest broad applicability of these agents to cancer therapy. This review focuses on the clinical use of PPARγ ligands, specifically the thiazolidinediones, for the treatment and prevention of cancer.

  17. Development of immobilized ligands for actinide separations

    International Nuclear Information System (INIS)

    Primary goals during this grant period were to (1) synthesize new bifunctional chelating ligands, (2) characterize the structural features of the Ln and An coordination complexes formed by these ligands, (3) use structural data to iteratively design new classes of multifunctional ligands, and (4) explore additional routes for attachment of key ligands to solid supports that could be useful for chromatographic separations. Some highlights of recently published work as well as a summary of submitted, unpublished and/or still in progress research are outlined

  18. Labeling of receptor ligands with bromine radionuclides. Progress report, March 1, 1981-February 29, 1984

    International Nuclear Information System (INIS)

    We have developed techniques to label several types of organic molecules with radiobromine. We have emphasized techniques to label ligands for the estrogen receptor and have studied two brominated compounds in rat models. One of these compounds has been studied in a limited number of patients and estrogen containing tumors visualized by nuclear medicine imaging. We have recently expanded the size of the work to label receptor ligands with fluorine-18 and have carried out preliminary animal studies which suggest that a clinically useful compound can be prepared. In addition to the receptor studies, we have collaborated in assessing 77Br-labeled compounds as therapeutic agents and in studying 77Br-labeled compounds using perturbed angular correlation techniques

  19. Orbital angular momentum filter of photon based on spin-orbital angular momentum coupling

    Science.gov (United States)

    Chen, Dong-Xu; Zhang, Pei; Liu, Rui-Feng; Li, Hong-Rong; Gao, Hong; Li, Fu-Li

    2015-10-01

    Determination of the orbital angular momentum (OAM) of vortex beams has been hotly discussed. We propose a new type of method to determine the orbital angular momentum of photons, filtering. We present an OAM filter scheme which consists of a cavity with a polarization-based Mach-Zehnder interferometer inside. Our scheme can purify the specific OAM with unitary efficiency theoretically without the pre-knowledge of the OAM spectrum of the input light. We also implemented a proof-of-principle experiment to demonstrate the feasibility of our scheme by cascading three interferometers. Our method offers a new way to determine the OAM spectrum of a light and this method can also be exploited to prepare the eigenstate of vortex beams.

  20. Orbital angular momentum mode-demultiplexing scheme with partial angular receiving aperture.

    Science.gov (United States)

    Zheng, Shilie; Hui, Xiaonan; Zhu, Jiangbo; Chi, Hao; Jin, Xiaofeng; Yu, Siyuan; Zhang, Xianmin

    2015-05-01

    For long distance orbital angular momentum (OAM) based transmission, the conventional whole beam receiving scheme encounters the difficulty of large aperture due to the divergence of OAM beams. We propose a novel partial receiving scheme, using a restricted angular aperture to receive and demultiplex multi-OAM-mode beams. The scheme is theoretically analyzed to show that a regularly spaced OAM mode set remain orthogonal and therefore can be de-multiplexed. Experiments have been carried out to verify the feasibility. This partial receiving scheme can serve as an effective method with both space and cost savings for the OAM communications. It is applicable to both free space OAM optical communications and radio frequency (RF) OAM communications. PMID:25969311

  1. The calculation of angular and energy-angular distributions for n+D reactions

    International Nuclear Information System (INIS)

    The energy-angular distributions for secondary neutrons and protons of breakup reactions and the elastic angular distributions of n+D were calculated by the computer code TSD which was developed by Chu and his co-workers from the three-body integral equations based on Faddeev-AGS theory. The results are compiled in the ENDF/B-6 format, and they are stored in the second version of Chinese Evaluated Nuclear DAta Library, CENDL-2. Their errors of energy conservation for breakup are less than one percent. The differential cross sections of the elastic scattering and the double-differential cross sections for secondary neutrons and protons of breakup reactions were calculated from CENDL-2, the results are in good agreement with the experimental data

  2. Orbital angular momentum filter of photon based on spin-orbital angular momentum coupling

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Dong-Xu; Zhang, Pei, E-mail: zhangpei@mail.ustc.edu.cn; Liu, Rui-Feng; Li, Hong-Rong; Gao, Hong; Li, Fu-Li

    2015-10-16

    Highlights: • We propose a scheme that can filter the orbital angular momentum of photons. • Our scheme filters the specific mode with destroying the mode. • Our scheme can theoretically filter infinity modes. • The orientation of Dove lens and HWP decides which mode will output. - Abstract: Determination of the orbital angular momentum (OAM) of vortex beams has been hotly discussed. We propose a new type of method to determine the orbital angular momentum of photons, filtering. We present an OAM filter scheme which consists of a cavity with a polarization-based Mach–Zehnder interferometer inside. Our scheme can purify the specific OAM with unitary efficiency theoretically without the pre-knowledge of the OAM spectrum of the input light. We also implemented a proof-of-principle experiment to demonstrate the feasibility of our scheme by cascading three interferometers. Our method offers a new way to determine the OAM spectrum of a light and this method can also be exploited to prepare the eigenstate of vortex beams.

  3. Orbital angular momentum filter of photon based on spin-orbital angular momentum coupling

    International Nuclear Information System (INIS)

    Highlights: • We propose a scheme that can filter the orbital angular momentum of photons. • Our scheme filters the specific mode with destroying the mode. • Our scheme can theoretically filter infinity modes. • The orientation of Dove lens and HWP decides which mode will output. - Abstract: Determination of the orbital angular momentum (OAM) of vortex beams has been hotly discussed. We propose a new type of method to determine the orbital angular momentum of photons, filtering. We present an OAM filter scheme which consists of a cavity with a polarization-based Mach–Zehnder interferometer inside. Our scheme can purify the specific OAM with unitary efficiency theoretically without the pre-knowledge of the OAM spectrum of the input light. We also implemented a proof-of-principle experiment to demonstrate the feasibility of our scheme by cascading three interferometers. Our method offers a new way to determine the OAM spectrum of a light and this method can also be exploited to prepare the eigenstate of vortex beams

  4. Ligand-specific conformational changes in the alpha1 glycine receptor ligand-binding domain

    DEFF Research Database (Denmark)

    Pless, Stephan Alexander; Lynch, Joseph W

    2009-01-01

    residue responded differently to glycine and strychnine, thus underlining the importance of loop C in ligand discrimination. These results provide an important step toward mapping the domains crucial for ligand discrimination in the ligand-binding domain of glycine receptors and possibly other Cys loop...

  5. DFTB3 Parametrization for Copper: The Importance of Orbital Angular Momentum Dependence of Hubbard Parameters.

    Science.gov (United States)

    Gaus, Michael; Jin, Haiyun; Demapan, Darren; Christensen, Anders S; Goyal, Puja; Elstner, Marcus; Cui, Qiang

    2015-09-01

    We report the parametrization of a density functional tight binding method (DFTB3) for copper in a spin-polarized formulation. The parametrization is consistent with the framework of 3OB for main group elements (ONCHPS) and can be readily used for biological applications that involve copper proteins/peptides. The key to our parametrization is to introduce orbital angular momentum dependence of the Hubbard parameter and its charge derivative, thus allowing the 3d and 4s orbitals to adopt different sizes and responses to the change of charge state. The parametrization has been tested by applying to a fairly broad set of molecules of biological relevance, and the properties of interest include optimized geometries, ligand binding energies, and ligand proton affinities. Compared to the reference QM level (B3LYP/aug-cc-pVTZ, which is shown here to be similar to the B97-1 and CCSD(T) results, in terms of many properties of interest for a set of small copper containing molecules), our parametrization generally gives reliable structural properties for both Cu(I) and Cu(II) compounds, although several exceptions are also noted. For energetics, the results are more accurate for neutral ligands than for charged ligands, likely reflecting the minimal basis limitation of DFTB3; the results generally outperform NDDO based methods such as PM6 and even PBE with the 6-31+G(d,p) basis. For all ligand types, single-point B3LYP calculations at DFTB3 geometries give results very close (∼1-2 kcal/mol) to the reference B3LYP values, highlighting the consistency between DFTB3 and B3LYP structures. Possible further developments of the DFTB3 model for a better treatment of transition-metal ions are also discussed. In the current form, our first generation of DFTB3 copper model is expected to be particularly valuable as a method that drives sampling in systems that feature a dynamical copper binding site. PMID:26575916

  6. Macrocyclic ligands for uranium complexation

    International Nuclear Information System (INIS)

    A highly preorganized 24-macrocycle containing biuret, thiobiuret and pyridine subunits has been prepared by high dilution ring-closure procedures. Intermediate products to this macrocycle have been utilized to extend this synthetic route to include further representatives where solubility and stability will be influenced by substituent variation. A 1:1 complex has been formed from uranyl acetate and a quinquepyridine derivative, this representing a new type of ligand for the uranyl ion. A very convenient synthetic procedure that will allow the incorporation of these macrocycles into polymeric systems has been developed for the introduction of a vinyl substituent into the 4-position of the pyridine ring. Using triflate, vinyltributyltin and Pd0 chemistry, this procedure should make a variety of substituted 4-vinylpyridines available for the first time. 3 refs

  7. Synthesis and characterization of mixed ligand chiral nanoclusters

    OpenAIRE

    Güven, Zekiye Pelin; Guven, Zekiye Pelin; Üstbaş, Burçin; Ustbas, Burcin; Harkness, Kellen M.; Coşkun, Hikmet; Coskun, Hikmet; Joshi, Chakra P.; Besong, Tabot M. D.; Stellacci, Francesco; Bakr, Osman M.; Akbulut, Özge; Akbulut, Ozge

    2015-01-01

    Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. The ratio of the ligands was changed to track the formation of these clusters. While the chiral ligand lead to nanoparticles, Presence of the achiral ligand induced the formation of nanoclusters with chiral properties.

  8. Quark and gluon orbital angular momentum: Where are we?

    CERN Document Server

    Lorcé, Cédric

    2016-01-01

    The orbital angular momentum of quarks and gluons contributes significantly to the proton spin budget and attracted a lot of attention in the recent years, both theoretically and experimentally. We summarize the various definitions of parton orbital angular momentum together with their relations with parton distributions functions. In particular, we highlight current theoretical puzzles and give some prospects.

  9. Anomalous Magnetic Moments and Quark Orbital Angular Momentum

    OpenAIRE

    Burkardt, M.; Schnell, G.(University of the Basque Country UPV/EHU, 48080 Bilbao, Spain)

    2005-01-01

    We derive an inequality for the distribution of quarks with non-zero orbital angular momentum, and thus demonstrate, in a model-independent way, that a non-vanishing anomalous magnetic moment requires both a non-zero size of the target as well as the presence of wave function components with quark orbital angular momentum L_z>0.

  10. Quark and Gluon Orbital Angular Momentum: Where Are We?

    Science.gov (United States)

    Lorcé, Cédric; Liu, Keh-Fei

    2016-06-01

    The orbital angular momentum of quarks and gluons contributes significantly to the proton spin budget and attracted a lot of attention in the recent years, both theoretically and experimentally. We summarize the various definitions of parton orbital angular momentum together with their relations with parton distributions functions. In particular, we highlight current theoretical puzzles and give some prospects.

  11. Conservation of Orbital Angular Momentum in Stimulated Down-Conversion

    OpenAIRE

    Caetano, D. P.; Almeida, M. P.; Ribeiro, P. H. Souto; Huguenin, J. A. O.; Santos, B. Coutinho dos; Khoury, A. Z.

    2001-01-01

    We report on an experiment demonstrating the conservation of orbital angular momentum in stimulated down-conversion. The orbital angular momentum is not transferred to the individual beams of the spontaneous down-conversion, but it is conserved when twin photons are taken individually. We observe the conservation law for an individual beam of the down-conversion through cavity-free stimulated emission.

  12. Orbital Angular Momentum in Scalar Diquark Model and QED

    OpenAIRE

    BC, Hikmat; Burkardt, Matthias

    2011-01-01

    We compare the orbital angular momentum of the 'quark' in the scalar diquark model as well as that of the electron in QED (to order {\\alpha}) obtained from the Jaffe-Manohar de- composition to that obtained from the Ji relation. We estimate the importance of the vector potential in the definition of orbital angular momentum.

  13. Evolution Equations for Higher Moments of Angular Momentum Distributions

    OpenAIRE

    Haegler, P.; Schaefer, A

    1998-01-01

    Based on a sumrule for the nucleon spin we expand quark and gluon orbital angular momentum operators and derive an evolution matrix for higher moments of the corresponding distributions. In combination with the spin-dependent DGLAP-matrix we find a complete set of spin and orbital angular momentum evolution equations.

  14. Creation of orbital angular momentum states with chiral polaritonic lenses

    OpenAIRE

    Dall, Robert; Fraser, Michael D.; Desyatnikov, Anton S.; Li, Guangyao; Brodbeck, Sebastian; Kamp, Martin; Schneider, Christian; Höfling, Sven; Ostrovskaya, Elena A.

    2014-01-01

    Controlled transfer of orbital angular momentum to exciton-polariton Bose-Einstein condensate spontaneously created under incoherent, off-resonant excitation conditions is a long-standing challenge in the field of microcavity polaritonics. We demonstrate, experimentally and theoretically, a simple and efficient approach to generation of nontrivial orbital angular momentum states by using optically-induced potentials -- chiral polaritonic lenses.

  15. Non-negative Wigner functions for orbital angular momentum states

    OpenAIRE

    Rigas, I.; Sanchez-Soto, L. L.; Klimov, A. B.; J. Rehacek; Hradil, Z.

    2009-01-01

    The Wigner function of a pure continuous-variable quantum state is non-negative if and only if the state is Gaussian. Here we show that for the canonical pair angle and angular momentum, the only pure states with non-negative Wigner functions are the eigenstates of the angular momentum. Some implications of this surprising result are discussed.

  16. Orbital Angular Momentum in Scalar Diquark Model and QED

    International Nuclear Information System (INIS)

    We compare the orbital angular momentum of the 'quark' in the scalar diquark model as well as that of the electron in QED (to order α) obtained from the Jaffe-Manohar decomposition to that obtained from the Ji relation. We estimate the importance of the vector potential in the definition of orbital angular momentum. (author)

  17. Non-negative Wigner functions for orbital angular momentum states

    International Nuclear Information System (INIS)

    The Wigner function of a pure continuous-variable quantum state is non-negative if and only if the state is Gaussian. Here we show that for the canonical pair angle and angular momentum, the only pure states with non-negative Wigner functions are the eigenstates of the angular momentum. Some implications of this surprising result are discussed.

  18. Quark and Gluon Orbital Angular Momentum: Where Are We?

    Science.gov (United States)

    Lorcé, Cédric; Liu, Keh-Fei

    2016-02-01

    The orbital angular momentum of quarks and gluons contributes significantly to the proton spin budget and attracted a lot of attention in the recent years, both theoretically and experimentally. We summarize the various definitions of parton orbital angular momentum together with their relations with parton distributions functions. In particular, we highlight current theoretical puzzles and give some prospects.

  19. Distilling angular momentum nonclassical states in trapped ions

    Science.gov (United States)

    Militello, B.; Messina, A.

    2004-09-01

    In the spirit of quantum nondemolition measurements, we show that by exploiting suitable vibronic couplings and repeatedly measuring the atomic population of a confined ion, it is possible to distill center-of-mass vibrational states with a well-defined square of angular momentum or, alternatively, angular momentum projection Schrödinger cat states.

  20. Distilling angular momentum nonclassical states in trapped ions

    CERN Document Server

    Militello, B

    2004-01-01

    In the spirit of Quantum Non-Demolition Measurements, we show that exploiting suitable vibronic couplings and repeatedly measuring the atomic population of a confined ion, it is possible to distill center of mass vibrational states with well defined square of angular momentum or, alternatively, angular momentum projection Schr\\"odinger cat states.

  1. Relativistic calculations of angular dependent photoemission time delay

    CERN Document Server

    Kheifets, A S; Deshmukh, P C; Dolmatov, V K; Manson, S T

    2016-01-01

    Angular dependence of photoemission time delay for the valence $np_{3/2}$ and $np_{1/2}$ subshells of Ar, Kr and Xe is studied in the dipole relativistic random phase approximation. Strong angular anisotropy of the time delay is reproduced near respective Cooper minima while the spin-orbit splitting affects the time delay near threshold.

  2. BB mode angular power spectrum of CMB from massive gravity

    CERN Document Server

    Malsawmtluangi, N

    2016-01-01

    The primordial massive gravitational waves are placed in the squeezed vacuum state and corresponding $BB$-mode correlation angular power spectrum of the cosmic microwave background is obtained for various slow roll inflation models. The angular power spectrum is compared with the limit of BICEP2/Keck and Planck joint analysis data and the hybrid inflation model is found favorable.

  3. Learning web development with Bootstrap and AngularJS

    CERN Document Server

    Radford, Stephen

    2015-01-01

    Whether you know a little about Bootstrap or AngularJS, or you're a complete beginner, this book will enhance your capabilities in both frameworks and you'll build a fully functional web app. A working knowledge of HTML, CSS, and JavaScript is required to fully get to grips with Bootstrap and AngularJS.

  4. Angular Momentum Phase State Representation for Quantum Pendulum

    Institute of Scientific and Technical Information of China (English)

    FAN Hong-Yi; WANG Ji-Suo

    2005-01-01

    To consummate the quantum pendulum theory whose Hamiltonian takes bosonic operator formalism and manifestly exhibits its dynamic behaviour in the entangled state representation, we introduce angular momentum state representation and phase state representation. It turns out that the angular momentum state is the partial wave expansion of the entangled state.

  5. Ligand-receptor Interactions by NMR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Novak. P.

    2008-04-01

    Full Text Available Today NMR spectroscopy is a method of choice for elucidation of interactions between biomolecules and the potential ligands. Knowledge on these interactions is an essential prerequisite for the rational drug design. The most important contribution of NMR to drug design a few years ago was the 3D structure determination of proteins. Besides delivering the 3D structures of the free proteins as a raw material for the modeling studies on ligand binding, NMR can directly yield valuable experimental data on the biologically important protein-ligand complexes. In addition to X-ray diffraction, NMR spectroscopy can provide information on the internal protein dynamics ordynamics of intermolecular interactions. Changes in NMR parameters allow us to detect ("SAR by NMR" and quantitatively determine binding affinities (titration, diffusion NMR experiments, etc. of potential ligands. Also, it is possible to determine the binding site and conformations of ligands, receptors and receptor-ligand complexes with the help of NMR methods such as tr-NOESY. Epitopes or functional groups responsible for binding of ligands to the receptor can be identified by employing STD or WaterLOGSY experiments. In this review are described some of the most frequent NMR methods for the characterization of the interactions between biomolecules and ligands, together with their advantages and disadvantages.

  6. Magnetic nanoparticles linked to a ligand

    OpenAIRE

    Penadés, Soledad; Martín-Lomas, Manuel; Martínez de la Fuente, Jesús; Rademacher, Thomas W.

    2006-01-01

    Materials and methods for making small magnetic particles, e.g. clusters of metal atoms, which can be employed as a substrate for immobilising a plurality of ligands. Also disclosed are uses of these magnetic nanoparticles as therapeutic and diagnostic reagents, and in the study of ligand-mediated interactions.

  7. Ligand sphere conversions in terminal carbide complexes

    DEFF Research Database (Denmark)

    Morsing, Thorbjørn Juul; Reinholdt, Anders; Sauer, Stephan P. A.; Bendix, Jesper

    2016-01-01

    Metathesis is introduced as a preparative route to terminal carbide complexes. The chloride ligands of the terminal carbide complex [RuC(Cl)2(PCy3)2] (RuC) can be exchanged, paving the way for a systematic variation of the ligand sphere. A series of substituted complexes, including the first exam...

  8. Alignment of wave functions for angular momentum projection

    CERN Document Server

    Taniguchi, Yasutaka

    2016-01-01

    Angular momentum projection is used to obtain eigen states of angular momentum from general wave functions. Multi-configuration mixing calculation with angular momentum projection is an important microscopic method in nuclear physics. For accurate multi-configuration mixing calculation with angular momentum projection, concentrated distribution of $z$ components $K$ of angular momentum in the body-fixed frame ($K$-distribution) is favored. Orientation of wave functions strongly affects $K$-distribution. Minimization of variance of $\\hat{J}_z$ is proposed as an alignment method to obtain wave functions that have concentrated $K$-distribution. Benchmark calculations are performed for $\\alpha$-$^{24}$Mg cluster structure, triaxially superdeformed states in $^{40}$Ar, and Hartree-Fock states of some nuclei. The proposed alignment method is useful and works well for various wave functions to obtain concentrated $K$-distribution.

  9. Observables for Quarks and Gluons Orbital Angular Momentum Distributions

    Science.gov (United States)

    Liuti, Simonetta; Courtoy, Aurore; Goldstein, Gary R.; Hernandez, J. Osvaldo Gonzalez; Rajan, Abha

    2015-02-01

    We discuss the observables that have been recently put forth to describe quarks and gluons orbital angular momentum distributions. Starting from a standard parameterization of the energy momentum tensor in QCD one can single out two forms of angular momentum, a so-called kinetic term - Ji decomposition - or a canonical term - Jaffe-Manohar decomposition. Orbital angular momentum has been connected in each decomposition to a different observable, a Generalized Transverse Momentum Distribution (GTMD), for the canonical term, and a twist three Generalized Parton Distribution (GPD) for the kinetic term. While the latter appears as an azimuthal angular modulation in the longitudinal target spin asymmetry in deeply virtual Compton scattering, due to parity constraints, the GTMD associated with canonical angular momentum cannot be measured in a similar set of experiments.

  10. Cyclic transformation of orbital angular momentum modes

    Science.gov (United States)

    Schlederer, Florian; Krenn, Mario; Fickler, Robert; Malik, Mehul; Zeilinger, Anton

    2016-04-01

    The spatial modes of photons are one realization of a QuDit, a quantum system that is described in a D-dimensional Hilbert space. In order to perform quantum information tasks with QuDits, a general class of D-dimensional unitary transformations is needed. Among these, cyclic transformations are an important special case required in many high-dimensional quantum communication protocols. In this paper, we experimentally demonstrate a cyclic transformation in the high-dimensional space of photonic orbital angular momentum (OAM). Using simple linear optical components, we show a successful four-fold cyclic transformation of OAM modes. Interestingly, our experimental setup was found by a computer algorithm. In addition to the four-cyclic transformation, the algorithm also found extensions to higher-dimensional cycles in a hybrid space of OAM and polarization. Besides being useful for quantum cryptography with QuDits, cyclic transformations are key for the experimental production of high-dimensional maximally entangled Bell-states.

  11. Angular velocity and centripetal acceleration relationship

    Science.gov (United States)

    Monteiro, Martín; Cabeza, Cecilia; Marti, Arturo C.; Vogt, Patrik; Kuhn, Jochen

    2014-05-01

    During the last few years, the growing boom of smartphones has given rise to a considerable number of applications exploiting the functionality of the sensors incorporated in these devices. A sector that has unexpectedly taken advantage of the power of these tools is physics teaching, as reflected in several recent papers. In effect, the use of smartphones has been proposed in several physics experiments spanning mechanics, electromagnetism, optics, oscillations, and waves, among other subjects. Although mechanical experiments have received considerable attention, most of them are based on the use of the accelerometer. An aspect that has received less attention is the use of rotation sensors or gyroscopes. An additional advance in the use of these devices is given by the possibility of obtaining data using the accelerometer and the gyroscope simultaneously. The aim of this paper is to consider the relation between the centripetal acceleration and the angular velocity. Instead of using a formal laboratory setup, in this experiment a smartphone is attached to the floor of a merry-go-round, found in many playgrounds. Several experiments were performed with the roundabout rotating in both directions and with the smart-phone at different distances from the center. The coherence of the measurements is shown.

  12. Semiclassical model for attosecond angular streaking.

    Science.gov (United States)

    Smolarski, M; Eckle, P; Keller, U; Dörner, R

    2010-08-16

    Attosecond angular streaking is a new technique to achieve unsurpassed time accuracy of only a few attoseconds. Recently this has been successfully used to set an upper limit on the electron tunneling delay time in strong laser field ionization. The measurement technique can be modeled with either the time-dependent Schrödinger equation (TDSE) or a more simple semiclassical approach that describes the process in two steps in analogy to the three-step model in high harmonic generation (HHG): step one is the tunnel ionization and step two is the classical motion in the strong laser field. Here we describe in detail a semiclassical model which is based on the ADK theory for the tunneling step, with subsequent classical propagation of the electron in the laser field. We take into account different ellipticities of the laser field and a possible wavelength-dependent ellipticity that is typically observed for pulses in the two-optical-cycle regime. This semiclassical model shows excellent agreement with the experimental result. PMID:20721150

  13. Millimetre Wave with Rotational Orbital Angular Momentum.

    Science.gov (United States)

    Zhang, Chao; Ma, Lu

    2016-01-01

    Orbital angular momentum (OAM) has been widely studied in fibre and short-range communications. The implementation of millimetre waves with OAM is expected to increase the communication capacity. Most experiments demonstrate the distinction of OAM modes by receiving all of the energy in the surface vertical to the radiation axis in space. However, the reception of OAM is difficult in free space due to the non-zero beam angle and divergence of energy. The reception of OAM in the space domain in a manner similar to that in optical fibres (i.e., receiving all of the energy rings vertical to the radiation axis) is impractical, especially for long-distance transmission. Here, we fabricate a prototype of the antenna and demonstrate that rather than in the space domain, the OAM can be well received in the time domain via a single antenna by rotating the OAM wave at the transmitter, i.e., the radio wave with rotational OAM. The phase and frequency measured in the experiment reveal that for different OAM modes, the received signals act as a commonly used orthogonal frequency division multiplexing (OFDM) signal in the time domain. This phase rotation has promising prospects for use in the practical reception of different OAMs of millimetre waves in long-distance transmission. PMID:27596746

  14. CLASS: The Cosmology Large Angular Scale Surveyor

    CERN Document Server

    Essinger-Hileman, Thomas; Amiri, Mandana; Appel, John W; Araujo, Derek; Bennett, Charles L; Boone, Fletcher; Chan, Manwei; Cho, Hsiao-Mei; Chuss, David T; Colazo, Felipe; Crowe, Erik; Denis, Kevin; Dünner, Rolando; Eimer, Joseph; Gothe, Dominik; Halpern, Mark; Harrington, Kathleen; Hilton, Gene; Hinshaw, Gary F; Huang, Caroline; Irwin, Kent; Jones, Glenn; Karakla, John; Kogut, Alan J; Larson, David; Limon, Michele; Lowry, Lindsay; Marriage, Tobias; Mehrle, Nicholas; Miller, Amber D; Miller, Nathan; Moseley, Samuel H; Novak, Giles; Reintsema, Carl; Rostem, Karwan; Stevenson, Thomas; Towner, Deborah; U-Yen, Kongpop; Wagner, Emily; Watts, Duncan; Wollack, Edward; Xu, Zhilei; Zeng, Lingzhen

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an experiment to measure the signature of a gravita-tional-wave background from inflation in the polarization of the cosmic microwave background (CMB). CLASS is a multi-frequency array of four telescopes operating from a high-altitude site in the Atacama Desert in Chile. CLASS will survey 70\\% of the sky in four frequency bands centered at 38, 93, 148, and 217 GHz, which are chosen to straddle the Galactic-foreground minimum while avoiding strong atmospheric emission lines. This broad frequency coverage ensures that CLASS can distinguish Galactic emission from the CMB. The sky fraction of the CLASS survey will allow the full shape of the primordial B-mode power spectrum to be characterized, including the signal from reionization at low $\\ell$. Its unique combination of large sky coverage, control of systematic errors, and high sensitivity will allow CLASS to measure or place upper limits on the tensor-to-scalar ratio at a level of $r=0.01$ and make a cosmi...

  15. Cyclic transformation of orbital angular momentum modes

    CERN Document Server

    Schlederer, Florian; Fickler, Robert; Malik, Mehul; Zeilinger, Anton

    2015-01-01

    The spatial modes of photons are one realization of a QuDit, a quantum system that is described in a D-dimensional Hilbert space. In order to perform quantum information tasks with QuDits, a general class of D-dimensional unitary transformations is needed. Among these, cyclic transformations are an important special case required in many high-dimensional quantum communication protocols. In this paper, we experimentally demonstrate a cyclic transformation in the high-dimensional space of photonic orbital angular momentum (OAM). Using simple linear optical components, we show a successful four-fold cyclic transformation of OAM modes. Interestingly, our experimental setup was found by a computer algorithm. In addition to the four-cyclic transformation, the algorithm also found extensions to higher-dimensional cycles in a hybrid space of OAM and polarization. Besides being useful for quantum cryptography with QuDits, cyclic transformations are key for the experimental production of high-dimensional maximally enta...

  16. CLASS: The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Essinger-Hileman, Thomas; Ali, Aamir; Amiri, Mandana; Appel, John W.; Araujo, Derek; Bennett, Charles L.; Boone, Fletcher; Chan, Manwei; Cho, Hsiao-Mei; Chuss, David T.; Colazo, Felipe; Crowe, Erik; Denis, Kevin; Dunner, Rolando; Eimer, Joseph; Gothe, Dominik; Halpern, Mark; Kogut, Alan J.; Miller, Nathan; Moseley, Samuel; Rostem, Karwan; Stevenson, Thomas; Towner, Deborah; U-Yen, Kongpop; Wollack, Edward

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an experiment to measure the signature of a gravitational wave background from inflation in the polarization of the cosmic microwave background (CMB). CLASS is a multi-frequency array of four telescopes operating from a high-altitude site in the Atacama Desert in Chile. CLASS will survey 70% of the sky in four frequency bands centered at 38, 93, 148, and 217 GHz, which are chosen to straddle the Galactic-foreground minimum while avoiding strong atmospheric emission lines. This broad frequency coverage ensures that CLASS can distinguish Galactic emission from the CMB. The sky fraction of the CLASS survey will allow the full shape of the primordial B-mode power spectrum to be characterized, including the signal from reionization at low-length. Its unique combination of large sky coverage, control of systematic errors, and high sensitivity will allow CLASS to measure or place upper limits on the tensor-to-scalar ratio at a level of r = 0:01 and make a cosmic-variance-limited measurement of the optical depth to the surface of last scattering, tau. (c) (2014) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  17. Angular Distribution and Angular Dispersion in Collision of 19F+27A1 at 114 MeV

    Institute of Scientific and Technical Information of China (English)

    WANG Qi; Li Zhi-Chang; LU Xiu-Qin; ZHAO Kui; LIU Jian-Cheng; SERGEY Yu-Kun; DONG Yu-Chuan; LI Song-Lin; DUAN Li-Min; XU Hu-Shan; XU Hua-Gen; CHEN Ruo-Fu; WU He-Yu; HAN Jian-Long

    2004-01-01

    Angular distributions of fragments B, C, N, O, F, Ne, Na, Mg and Al induced by the collision of 19F+27 A1 at 114MeV have been measured. Angular dispersion parameters are extracted from the experimental data and compared with the theoretical ones. The dynamic dispersions for dissipative products depend strongly on the charge number Z of the fragments.

  18. Protein-ligand-based pharmacophores: generation and utility assessment in computational ligand profiling.

    Science.gov (United States)

    Meslamani, Jamel; Li, Jiabo; Sutter, Jon; Stevens, Adrian; Bertrand, Hugues-Olivier; Rognan, Didier

    2012-04-23

    Ligand profiling is an emerging computational method for predicting the most likely targets of a bioactive compound and therefore anticipating adverse reactions, side effects and drug repurposing. A few encouraging successes have already been reported using ligand 2-D similarity searches and protein-ligand docking. The current study describes the use of receptor-ligand-derived pharmacophore searches as a tool to link ligands to putative targets. A database of 68,056 pharmacophores was first derived from 8,166 high-resolution protein-ligand complexes. In order to limit the number of queries, a maximum of 10 pharmacophores was generated for each complex according to their predicted selectivity. Pharmacophore search was compared to ligand-centric (2-D and 3-D similarity searches) and docking methods in profiling a set of 157 diverse ligands against a panel of 2,556 unique targets of known X-ray structure. As expected, ligand-based methods outperformed, in most of the cases, structure-based approaches in ranking the true targets among the top 1% scoring entries. However, we could identify ligands for which only a single method was successful. Receptor-ligand-based pharmacophore search is notably a fast and reliable alternative to docking when few ligand information is available for some targets. Overall, the present study suggests that a workflow using the best profiling method according to the protein-ligand context is the best strategy to follow. We notably present concrete guidelines for selecting the optimal computational method according to simple ligand and binding site properties. PMID:22480372

  19. The origin of angular momentum in dark matter halos

    CERN Document Server

    Vitvitska, M; Kravtsov, A V; Bullock, J S; Wechsler, R H; Primack, Joel R

    2002-01-01

    We propose a new explanation for the origin of angular momentum in galaxies and their dark halos, in which the halos obtain their spin through the cumulative acquisition of angular momentum from satellite accretion. In our model, the build-up of angular momentum is a random walk process associated with the mass assembly history of the halo's major progenitor. We assume no correlation between the angular momenta of accreted objects. Using the extended Press-Schechter approximation, we calculate the growth of mass, angular momentum, and spin parameter $\\lambda$ for many halos. Our random walk model reproduces the key features of the angular momentum of halos found in N-body simulations: a lognormal distribution in $\\lambda$ with an average of $ \\approx 0.04$, independent of mass and redshift. The evolution of the spin parameter in individual halos in this model is quite different from the steady increase with time of angular momentum in the tidal torque picture. We find both in N-body simulations and in our ran...

  20. Autocrine signal transmission with extracellular ligand degradation

    International Nuclear Information System (INIS)

    Traveling waves of cell signaling in epithelial layers orchestrate a number of important processes in developing and adult tissues. These waves can be mediated by positive feedback autocrine loops, a mode of cell signaling where binding of a diffusible extracellular ligand to a cell surface receptor can lead to further ligand release. We formulate and analyze a biophysical model that accounts for ligand-induced ligand release, extracellular ligand diffusion and ligand–receptor interaction. We focus on the case when the main mode for ligand degradation is extracellular and analyze the problem with the sharp threshold positive feedback nonlinearity. We derive expressions that link the speed of propagation and other characteristics of traveling waves to the parameters of the biophysical processes, such as diffusion rates, receptor expression level, etc. Analyzing the derived expressions we found that traveling waves in such systems can exhibit a number of unusual properties, e.g. non-monotonic dependence of the speed of propagation on ligand diffusivity. Our results for the fully developed traveling fronts can be used to analyze wave initiation from localized perturbations, a scenario that frequently arises in the in vitro models of epithelial wound healing, and guide future modeling studies of cell communication in epithelial layers

  1. Angular dependent light emission from planar waveguides

    International Nuclear Information System (INIS)

    We have investigated the angular dependence of amplified spontaneous emission (ASE) and laser emission from an asymmetric and free-standing polymer thin films doped with rhodamine 6G, which is transversely pumped by a pulsed Nd:YAG laser. A semi-leaky waveguide or quasi-waveguide structure has been developed by spin coating technique. In these waveguides, the light was confined by the film/air-film/glass substrate interfaces. At the film/substrate interface, a portion of light will reflect back into the film (guided mode) and the remaining refracted to the substrate resulting in cutoff modes. A blue-shift in ASE has been observed when the pump power was increased from 8 to 20 mW allowing a limited range of tuning of emission wavelength. To study the directionality of the ASE from the waveguide, we have measured the output intensity and FWHM of emission spectra as a function of viewing angle (θ) from the plane parallel to film. From the detailed examination of the output emission spectra, as +θ increases from 0° there has been an initial decrease in output intensity, but at a particular angle ≈10° an increase in output intensity was observed. This additional peak in output intensity as +θ is a clear indication of coexistence of the cutoff mode. We also present a compact solid-state laser based on leaky mode propagation from the dye-doped polymer free-standing film (∼50 μm thickness) waveguide. The partial reflections from the broad lateral surfaces of the free-standing films provided the optical feedback for the laser emission with high directionality. For a pump power of 22 mW, an intense line with FWHM <0.2 nm was observed at 578 nm

  2. Angular momentum projection with quantum effects

    International Nuclear Information System (INIS)

    We have improved a simple and rapid method of calculating expectation values of operators in states of good angular momentum projected from a hedgehog baryon state introduced by Birse et al. We have included the contributions of quantum mesons, while in the original method only classical meson fields were included. The method has been applied to models where the mean-field approximation does not include loop terms. Hence, for reasons of consistency, contributions of quantum loops to the matrix elements have been dropped. The symmetry of the hedgehog state under grand reversal (the combined operation of time reversal and eiπI2, where I is the isospin operator) introduces remarkable simplification in the calculation of matrix elements of operators which do not contain time derivatives of meson fields. The quantum meson contributions turn out to be 3/2/left-angle B|J2|B right-angle times the classical meson-field contributions, with |B right-angle being the hedgehog state. Such operators are encountered in the calculation of nucleon magnetic moments, gA(0) and gπNN(0)/2M. Calculation of charge radii involves operators containing time derivatives of meson fields and requires the knowledge of wave functions of quantum mesons. Proper nonperturbative treatment, even though at the tree level, requires that these wave functions describe the motion of the mesons in the potential generated by the baryon. Fortunately, because of the neglect of the loop terms, one needs only the even-parity, grand-spin-1 states which are purely pionic. The Goldberger-Treiman relations, an exact result for the model, serves as a partial test of the method of calculation discussed here

  3. Improving protein-ligand docking with flexible interfacial water molecules using SWRosettaLigand.

    Science.gov (United States)

    Li, Linqing; Xu, Weiwei; Lü, Qiang

    2015-11-01

    Computational protein-ligand docking is of great importance in drug discovery and design. Conformational changes greatly affect the results of protein-ligand docking, especially when water molecules take part in mediating protein ligand interactions or when large conformational changes are observed in the receptor backbone interface. We have developed an improved protocol, SWRosettaLigand, based on the RosettaLigand protocol. This approach incorporates the flexibility of interfacial water molecules and modeling of the interface of the receptor into the original RosettaLigand. In a coarse sampling step, SWRosettaLigand pre-optimizes the initial position of the water molecules, docks the ligand to the receptor with explicit water molecules, and minimizes the predicted structure with water molecules. The receptor backbone interface is treated as a loop and perturbed and refined by kinematic closure, or cyclic coordinate descent algorithm, with the presence of the ligand. In two cross-docking test sets, it was identified that for 8 out of 14, and 16 out of 22, test instances, the top-ranked structures by SWRosettaLigand achieved better accuracy than other protocols. PMID:26515196

  4. Generation and detection of orbital angular momentum via metasurface

    Science.gov (United States)

    Jin, Jinjin; Luo, Jun; Zhang, Xiaohu; Gao, Hui; Li, Xiong; Pu, Mingbo; Gao, Ping; Zhao, Zeyu; Luo, Xiangang

    2016-04-01

    Beams carrying orbital angular momentum possess a significant potential for modern optical technologies ranging from classical and quantum communication to optical manipulation. In this paper, we theoretically design and experimentally demonstrate an ultracompact array of elliptical nanoholes, which could convert the circularly polarized light into the cross-polarized vortex beam. To measure the topological charges of orbital angular momentum in a simple manner, another elliptical nanoholes array is designed to generate reference beam as a reference light. This approach may provide a new way for the generation and detection of orbital angular momentum in a compact device.

  5. Angular correlation of electrons and positrons in internal pair conversion

    International Nuclear Information System (INIS)

    The angular distribution of electrons and positrons which are emitted in internal pair conversion (IPC) is calculated. Coulomb-distorted waves are used as electron wave functions. Nuclear transitions of various multipolarities L>0 and of magnetic (ML) and electric (EL) type are considered as well as E0-conversion. Analytical expressions for the angular correlation are derived which are evaluated numerically assuming a finite extension of the nucleus and, for the EL and ML conversion, also in point-nucleus approximation. The calculated angular correlations are compared with results obtained within the Born approximation and, for the E0 case, with experimental data. (orig.)

  6. Fission fragment angular distribution in heavy ion induced fission

    Directory of Open Access Journals (Sweden)

    S. Soheyli

    2006-06-01

    Full Text Available   We have calculated the fission fragment angular anisotropy for 16O + 232Th,12C + 236U , 11B + 237 Np , 14 N + 232 Th , 11B + 235U , 12C + 232Th systems with the saddle point statistical model and compared the fission fragment angular anisotropy for these systems. This comparison was done with two methods a without neutron correction and b with neutron correction. Also we studied normal and anomalous behavior of the fission fragment angular anisotropy. Finally, we have predicted the average emitted neutron from compound nuclei considering the best fit for each system.

  7. Fission fragment angular distribution in heavy ion induced fission

    OpenAIRE

    S. Soheyli; I. Ziaeian

    2006-01-01

      We have calculated the fission fragment angular anisotropy for 16O + 232Th,12C + 236U , 11B + 237 Np , 14 N + 232 Th , 11B + 235U , 12C + 232Th systems with the saddle point statistical model and compared the fission fragment angular anisotropy for these systems. This comparison was done with two methods a) without neutron correction and b) with neutron correction. Also we studied normal and anomalous behavior of the fission fragment angular anisotropy. Finally, we have predicted the averag...

  8. Angular distributions by the conventional and the Doppler shift method

    International Nuclear Information System (INIS)

    The angular distribution of elastically scattered metastable Ne*(3P2) has been measured by the conventional and the Doppler shift method. The conventional method shows a good angular resolution and signal to noise ratio. For the Doppler shift method, the angular resolution and the signal to noise ratio are much worse. By Monte Carlo-calculations it is shown that the influence of the residual velocity profiles of the supersonic atomic beams is large for the Doppler method, but can nearly be neglected for the conventional method. For nonsymmetric systems (such as Na2-Xe) and for inelastic processes the Doppler method is expected to be more successful. (Auth.)

  9. The pretzelosity TMD and quark orbital angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Lorce, C. [IPNO, Universite Paris-Sud, CNRS/IN2P3, 91406 Orsay (France); LPT, Universite Paris-Sud, CNRS, 91406 Orsay (France); Pasquini, B., E-mail: pasquini@pv.infn.it [Dipartimento di Fisica, Universita degli Studi di Pavia, Pavia (Italy); Istituto Nazionale di Fisica Nucleare, Sezione di Pavia, Pavia (Italy)

    2012-04-12

    We study the connection between the quark orbital angular momentum and the pretzelosity transverse-momentum dependent parton distribution function. We discuss the origin of this relation in quark models, identifying as key ingredient for its validity the assumption of spherical symmetry for the nucleon in its rest frame. Finally we show that the individual quark contributions to the orbital angular momentum obtained from this relation cannot be interpreted as the intrinsic contributions, but include the contribution from the transverse centre of momentum which cancels out only in the total orbital angular momentum.

  10. Experimental Evidence for Partonic Orbital Angular Momentum at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Fields, Douglas E. [University of New Mexico, Department of Physics and Astronomy, Albuquerque, NM 871331 (United States)

    2011-12-14

    Although one might naively anticipate that the proton, being the lowest baryonic energy state, would be in a L = 0 state, the current theoretical understanding is that it must carry orbital angular momentum in order, for example, to have a non-zero anomalous magnetic moment. I will review the experimental evidence linked theoretically to orbital angular momentum of the proton's constituents from the RHIC experiments and summarize by presenting a challenge to the theory community--to develop a consistent framework which can explain the spin polarization asymmetries seen at RHIC and elsewhere, and give insight to the partonic wave-functions including orbital angular momentum.

  11. Femtosecond dynamics of spin and orbital angular momentum in nickel

    Energy Technology Data Exchange (ETDEWEB)

    Stamm, Christian; Pontius, Niko; Holldack, Karsten; Quast, Torsten; Kachel, Torsten; Wietstruk, Marko; Mitzner, Rolf; Duerr, Hermann A. [Elektronenspeicherring BESSY II, Helmholtz-Zentrum Berlin fuer Materialien und Energie GmbH, 12489 Berlin (Germany)

    2009-07-01

    At the BESSY femtoslicing source we measure X-ray magnetic circular dichroism (XMCD) with 100 fs time resolution. By virtue of the XMCD sum rules, we find that the spin and orbital momenta in a thin nickel film are quenched with a time constant of 150 fs upon excitation with a fs laser pulse. This represents the first unambiguous proof that the total electronic angular momentum is transferred to the lattice on the same ultrafast time scale. The quenching of orbital angular momentum also is a serious constraint for models of angular momentum dissipation.

  12. Angular resolution of air-shower array-telescopes

    Science.gov (United States)

    Linsley, J.

    1985-01-01

    A fundamental limit on the angular resolution of air shower array-telescopes is set by the finite number of shower particles coupled with the finite thickness of the particle swarm. Consequently the angular resolution which can be achieved in practice depends in a determinant manner on the size and number of detectors in an array-telescope, as well as on the detector separation and the timing resolution. It is also necessary to examine the meaning of particle density in whatever type of detector is used. Results are given which can be used to predict the angular resolution of a given instrument for showers of various sizes, and to compare different instruments.

  13. Identification of Observables for Quark and Gluon Orbital Angular Momentum

    CERN Document Server

    Courtoy, Aurore; Hernandez, J Osvaldo Gonzalez; Liuti, Simonetta; Rajan, Abha

    2014-01-01

    A new debate has recently arisen on the subject of orbital angular momentum in QCD, in particular on its observability and on its partonic interpretation. Orbital momentum can be defined in QCD using two different decomposition schemes that yield a kinetic and a canonical definition, respectively. We argue that kinetic orbital angular momentum is intrinsically associated with twist three generalized parton distributions, and it is therefore more readily observable, while, due to parity constraints, canonical angular momentum, if defined as suggested in the literature in terms of generalized transverse momentum distributions, cannot be observed in scattering processes involving a single hadronic reaction plane.

  14. Experimental Evidence for Partonic Orbital Angular Momentum at RHIC

    International Nuclear Information System (INIS)

    Although one might naively anticipate that the proton, being the lowest baryonic energy state, would be in a L = 0 state, the current theoretical understanding is that it must carry orbital angular momentum in order, for example, to have a non-zero anomalous magnetic moment. I will review the experimental evidence linked theoretically to orbital angular momentum of the proton's constituents from the RHIC experiments and summarize by presenting a challenge to the theory community--to develop a consistent framework which can explain the spin polarization asymmetries seen at RHIC and elsewhere, and give insight to the partonic wave-functions including orbital angular momentum.

  15. Quark Orbital Angular Momentum and Final State Interactions

    CERN Document Server

    Burkardt, Matthias

    2014-01-01

    Definitions of orbital angular momentum based on Wigner distributions are used to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. The difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asymmetries in semi-inclusive deep-inelastic scattering.

  16. The pretzelosity TMD and quark orbital angular momentum

    International Nuclear Information System (INIS)

    We study the connection between the quark orbital angular momentum and the pretzelosity transverse-momentum dependent parton distribution function. We discuss the origin of this relation in quark models, identifying as key ingredient for its validity the assumption of spherical symmetry for the nucleon in its rest frame. Finally we show that the individual quark contributions to the orbital angular momentum obtained from this relation cannot be interpreted as the intrinsic contributions, but include the contribution from the transverse centre of momentum which cancels out only in the total orbital angular momentum.

  17. How orbital angular momentum affects beam shifts in optical reflection

    International Nuclear Information System (INIS)

    It is well known that reflection of a Gaussian light beam (TEM00) by a planar dielectric interface leads to four beam shifts when compared to the geometrical-optics prediction. These are the spatial Goos-Haenchen (GH) shift, the angular GH shift, the spatial Imbert-Fedorov (IF) shift, and the angular IF shift. We report here, theoretically and experimentally, that endowing the beam with orbital angular momentum leads to coupling of these four shifts; this is described by a 4x4 mixing matrix.

  18. Coherent detection of orbital angular momentum in radio

    CERN Document Server

    Daldorff, L K S; Bergman, J E S; Isham, B; Al-Nuaimi, M K T; Forozesh, K; Carozzi, T D

    2015-01-01

    The angular momentum propagated by a beam of radiation has two contributions: spin angular momentum (SAM) and orbital angular momentum (OAM). SAM corresponds to wave polarisation, while OAM-carrying beams are characterized by a phase which is a function of azimuth. We demonstrate experimentally that radio beams propagating OAM can be generated and coherently detected using ordinary electric dipole antennas. The results presented here could pave the way for novel radio OAM applications in technology and science, including radio communication, passive remote sensing, and new types of active (continuous or pulsed transmission) electromagnetic measurements.

  19. Induced Compression of White Dwarfs by Angular Momentum Loss

    CERN Document Server

    Boshkayev, Kuantay; Ruffini, Remo; Zhami, Bakytzhan

    2016-01-01

    We investigate isolated sub- and super-Chandrasekhar white dwarfs which lose angular momentum through magnetic dipole braking. We construct constant rest mass sequences by fulfilling all stability criteria of rotating configurations and show how the main structure of white dwarfs such as the central density, mean radius and angular velocity change with time. We explicitly demonstrate that all isolated white dwarfs regardless of their masses, by angular momentum loss, shrink and increase their central density. We also analyze the effects of the structure parameters on the evolution timescale both in the case of constant magnetic field and constant magnetic flux.

  20. Notes on the quantum theory of angular momentum

    CERN Document Server

    Feenberg, Eugene

    1999-01-01

    This classic, concise text has served a generation of physicists as an exceptionally useful guide to the mysteries of angular momenta and Clebsch-Gordon Coefficients. Derived from notes originally prepared to assist graduate students in reading research papers on atomic, molecular, and nuclear structure, the text first reviews the basic elements of quantum theory. It then examines the development of the fundamental commutation relations for angular momentum components and vector operators, and the ways in which matrix elements and eigenvalues of the angular momentum operators are worked out f

  1. Control of Angular Intervals for Angle-Multiplexed Holographic Memory

    Science.gov (United States)

    Kinoshita, Nobuhiro; Muroi, Tetsuhiko; Ishii, Norihiko; Kamijo, Koji; Shimidzu, Naoki

    2009-03-01

    In angle-multiplexed holographic memory, the full width at half maximum of the Bragg selectivity curves is dependent on the angle formed between the medium and incident laser beams. This indicates the possibility of high density and high multiplexing number by varying the angular intervals between adjacent holograms. We propose an angular interval scheduling for closely stacking holograms into medium even when the angle range is limited. We obtained bit error rates of the order of 10-4 under the following conditions: medium thickness of 1 mm, laser beam wavelength of 532 nm, and angular multiplexing number of 300.

  2. Spin Rate of a Racquetball Due To Angular Impact

    Directory of Open Access Journals (Sweden)

    Dolev Illouz

    2014-12-01

    Full Text Available The relationship between the impact angle of a racquetball and the resulting angular velocity of the ball was investigated. Impact angles ranging from 0° to 80° were tested. The ball was dropped at constant speed on a plywood board that could be angled and the impact was filmed at 600 fps. The video was then analyzed to determine the angular velocity of the ball after the bounce. It was found that there is a proportional relationship between the incoming impact angle (θ and angular velocity (ω of the racquetball, for angles up to 50°, indicating that the ball did not slip during impact at these angles.

  3. MEASUREMENT OF ANGULAR VIBRATION AMPLITUDE BY ACTIVELY BLURRED IMAGES

    Institute of Scientific and Technical Information of China (English)

    GUAN Baiqing; WANG Shigang; LIU Chong; LI Qian

    2007-01-01

    A novel motion-blur-based method for measuring the angular amplitude of a high-frequency rotational vibration is schemed. The proposed approach combines the active vision concept and the mechanism of motion-from-blur, generates motion blur on the image plane actively by extending exposure time, and utilizes the motion blur information in polar images to estimate the angular amplitude of a high-frequency rotational vibration. This method obtains the analytical results of the angular vibration amplitude from the geometric moments of a motion blurred polar image and an unblurred image for reference. Experimental results are provided to validate the presented scheme.

  4. Electro-optic analyzer of angular momentum hyperentanglement.

    Science.gov (United States)

    Wu, Ziwen; Chen, Lixiang

    2016-01-01

    Characterizing a high-dimensional entanglement is fundamental in quantum information applications. Here, we propose a theoretical scheme to analyze and characterize the angular momentum hyperentanglement that two photons are entangled simultaneously in spin and orbital angular momentum. Based on the electro-optic sampling with a proposed hyper-entanglement analyzer and the simple matrix operation using Cramer rule, our simulations show that it is possible to retrieve effectively both the information about the degree of polarization entanglement and the spiral spectrum of high-dimensional orbital angular momentum entanglement. PMID:26911530

  5. On Angular Sampling Methods for 3-D Spatial Channel Models

    DEFF Research Database (Denmark)

    Fan, Wei; Jämsä, Tommi; Nielsen, Jesper Ødum; Pedersen, Gert Frølund

    2015-01-01

    This paper discusses generating three dimensional (3D) spatial channel models with emphasis on the angular sampling methods. Three angular sampling methods, i.e. modified uniform power sampling, modified uniform angular sampling, and random pairing methods are proposed and investigated in detail....... The random pairing method, which uses only twenty sinusoids in the ray-based model for generating the channels, presents good results if the spatial channel cluster is with a small elevation angle spread. For spatial clusters with large elevation angle spreads, however, the random pairing method would...

  6. Pluto Moons exhibit Orbital Angular Momentum Quantization per Mass

    OpenAIRE

    Potter F.

    2012-01-01

    The Pluto satellite system of the planet plus five moons is shown to obey the quan- tum celestial mechanics (QCM) angular momentum per mass quantization condition predicted for any gravitationally bound system.

  7. Pluto Moons exhibit Orbital Angular Momentum Quantization per Mass

    Directory of Open Access Journals (Sweden)

    Potter F.

    2012-10-01

    Full Text Available The Pluto satellite system of the planet plus five moons is shown to obey the quan- tum celestial mechanics (QCM angular momentum per mass quantization condition predicted for any gravitationally bound system.

  8. Stellar Diameters and Temperatures IV. Predicting Stellar Angular Diameters

    CERN Document Server

    Boyajian, Tabetha; von Braun, Kaspar

    2013-01-01

    The number of stellar angular diameter measurements has greatly increased over the past few years due to innovations and developments in the field of long baseline optical interferometry (LBOI). We use a collection of high-precision angular diameter measurements for nearby, main-sequence stars to develop empirical relations that allow the prediction of stellar angular sizes as a function of observed photometric color. These relations are presented for a combination of 48 broad-band color indices. We empirically show for the first time a dependence on metallicity to these relations using Johnson $(B-V)$ and Sloan $(g-r)$ colors. Our relations are capable of predicting diameters with a random error of less than 5% and represent the most robust and empirical determinations to stellar angular sizes to date.

  9. Two-color ghost imaging with enhanced angular resolving power

    International Nuclear Information System (INIS)

    This article reports an experimental demonstration on nondegenerate, two-color, biphoton ghost imaging which reproduced a ghost image with enhanced angular resolving power by means of a greater field of view compared with that of classical imaging. With the same imaging magnification, the enhanced angular resolving power and field of view compared with those of classical imaging are 1.25:1 and 1.16:1, respectively. The enhancement of angular resolving power depends on the ratio between the idler and the signal photon frequencies, and the enhancement of the field of view depends mainly on the same ratio and also on the distances of the object plane and the imaging lens from the two-photon source. This article also reports the possibility of reproducing a ghost image with the enhancement of the angular resolving power by means of a greater imaging amplification compared with that of classical imaging.

  10. Phase-space distributions and orbital angular momentum

    Directory of Open Access Journals (Sweden)

    Pasquini B.

    2014-06-01

    Full Text Available We review the concept of Wigner distributions to describe the phase-space distributions of quarks in the nucleon, emphasizing the information encoded in these functions about the quark orbital angular momentum.

  11. Electronic orbital angular momentum and magnetism of graphene

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Ji, E-mail: ji.luo@upr.edu

    2014-10-01

    Orbital angular momentum (OAM) of graphene electrons in a perpendicular magnetic field is calculated and corresponding magnetic moment is used to investigate the magnetism of perfect graphene. Variation in magnetization demonstrates its decrease with carrier-doping, plateaus in a large field, and de Haas–van Alphen oscillation. Regulation of graphene's magnetism by a parallel electric field is presented. The OAM originates from atomic-scale electronic motion in graphene lattice, and vector hopping interaction between carbon atomic orbitals is the building element. A comparison between OAM of graphene electrons, OAM of Dirac fermions, and total angular momentum of the latter demonstrates their different roles in graphene's magnetism. Applicability and relation to experiments of the results are discussed. - Highlights: • Orbital angular momentum of graphene electrons is calculated. • Orbital magnetic moment of graphene electrons is obtained. • Variation in magnetization of graphene is calculated. • Roles of different kinds of angular momentum are investigated.

  12. Phase-space distributions and orbital angular momentum

    OpenAIRE

    Pasquini B.; Lorcé C.

    2014-01-01

    We review the concept of Wigner distributions to describe the phase-space distributions of quarks in the nucleon, emphasizing the information encoded in these functions about the quark orbital angular momentum.

  13. Electronic orbital angular momentum and magnetism of graphene

    International Nuclear Information System (INIS)

    Orbital angular momentum (OAM) of graphene electrons in a perpendicular magnetic field is calculated and corresponding magnetic moment is used to investigate the magnetism of perfect graphene. Variation in magnetization demonstrates its decrease with carrier-doping, plateaus in a large field, and de Haas–van Alphen oscillation. Regulation of graphene's magnetism by a parallel electric field is presented. The OAM originates from atomic-scale electronic motion in graphene lattice, and vector hopping interaction between carbon atomic orbitals is the building element. A comparison between OAM of graphene electrons, OAM of Dirac fermions, and total angular momentum of the latter demonstrates their different roles in graphene's magnetism. Applicability and relation to experiments of the results are discussed. - Highlights: • Orbital angular momentum of graphene electrons is calculated. • Orbital magnetic moment of graphene electrons is obtained. • Variation in magnetization of graphene is calculated. • Roles of different kinds of angular momentum are investigated

  14. Angular Momentum Generation from Holographic Gravitational Chern-Simons Model

    CERN Document Server

    Wu, Chaolun

    2014-01-01

    We study parity-violating effects, particularly the generation of angular momentum density and its relation to the parity-odd and dissipationless transport coefficient Hall viscosity, in strongly-coupled quantum fluid systems in 2+1 dimensions using holographic method. We employ a (3+1)-dimensional holographic model of Einstein-Maxwell system with a gravitational Chern-Simons term coupled to a dynamical scalar field. The scalar can condensate and this breaks the parity spontaneously. We find that when the scalar condensates, a non-vanishing angular momentum density and an associated edge current are generated by the gravitational Chern-Simons term, together with the emergence of Hall viscosity. Both angular momentum density and Hall viscosity acquire membrane paradigm forms and are only determined by the geometry and condensate near the horizon. We present both general analytic results and numeric results which take back-reactions into account. The ratio between Hall viscosity and angular momentum density is ...

  15. A Compact Orbital Angular Momentum Spectrometer Using Quantum Zeno Interrogation

    OpenAIRE

    Bierdz, Paul; Deng, Hui

    2014-01-01

    We present a scheme to measure the orbital angular momentum spectrum of light using a precisely timed optical loop and quantum non-demolition measurements. We also discuss the influence of imperfect optical components.

  16. Demonstration of the angular uncertainty principle for single photons

    International Nuclear Information System (INIS)

    We present an experimental demonstration of a form of the angular uncertainty principle for single photons. Producing light from type I down-conversion, we use spatial light modulators to perform measurements on signal and idler photons. By measuring states in the angle and orbital angular momentum basis, we demonstrate the uncertainty relation of Franke-Arnold et al (2004 New J. Phys. 6 103). We consider two manifestations of the uncertainty relation. In the first we herald the presence of a photon by detection of its paired partner and demonstrate the uncertainty relation on this single photon. In the second, we perform orbital angular momentum measurements on one photon and angular measurements on its correlated partner exploring, in this way, the uncertainty relation through non-local measurements

  17. Portable device for characterizing the angular response of UV spectroradiometers

    International Nuclear Information System (INIS)

    This paper introduces a device that was developed to measure the angular response of UV spectroradiometers in the field. This device is designed to be used at the operating position of spectroradiometers; thus the derived angular response also includes any effects from imperfect leveling of the diffuser and corresponds to the actual operational angular response. The design and characterization of the device and the results from its application on 11 different spectroradiometers that operate at different European UV stations are presented. Various sources of uncertainties that were identified result in a combined uncertainty in determining the angular response, which ranges between approximately 1.5% and 10%, depending on the incidence angle and the characteristics of the diffuser. For the 11 instruments, the error in reporting the diffuse irradiance ranges between 2% and -13%, assuming isotropic distribution of the downwelling radiances

  18. Differential reflective fiber-optic angular displacement sensor

    Science.gov (United States)

    Shan, Mingguang; Min, Rui; Zhong, Zhi; Wang, Ying; Zhang, Yabin

    2015-05-01

    Using the characteristic that the distance apart between the emitting fiber and receiving fiber only shifts the angular-power curve, a differential reflective fiber-optic sensor for angular displacement measurement is presented through subtraction of two power signals from two receiving fibers placed on both sides of one emitting fiber. A theoretical model is established to characterize the performance of the differential reflective fiber-optic angular displacement sensor. The measurements made indicate that the general behavior of the experimental results agrees with that of the theoretical results, and the sensor can improve sensitivity by about 120%, resulting in the significant improvement of anti-interference capability, which will be more suitable for high accuracy bipolar absolute angular displacement measurement. Design guidelines are also suggested to achieve desired sensor performances.

  19. Quantum optimal control of photoelectron spectra and angular distributions

    CERN Document Server

    Goetz, R Esteban; Santra, Robin; Koch, Christiane P

    2016-01-01

    Photoelectron spectra and photoelectron angular distributions obtained in photoionization reveal important information on e.g. charge transfer or hole coherence in the parent ion. Here we show that optimal control of the underlying quantum dynamics can be used to enhance desired features in the photoelectron spectra and angular distributions. To this end, we combine Krotov's method for optimal control theory with the time-dependent configuration interaction singles formalism and a splitting approach to calculate photoelectron spectra and angular distributions. The optimization target can account for specific desired properties in the photoelectron angular distribution alone, in the photoelectron spectrum, or in both. We demonstrate the method for hydrogen and then apply it to argon under strong XUV radiation, maximizing the difference of emission into the upper and lower hemispheres, in order to realize directed electron emission in the XUV regime.

  20. Quantum optimal control of photoelectron spectra and angular distributions

    Science.gov (United States)

    Goetz, R. Esteban; Karamatskou, Antonia; Santra, Robin; Koch, Christiane P.

    2016-01-01

    Photoelectron spectra and photoelectron angular distributions obtained in photoionization reveal important information on, e.g., charge transfer or hole coherence in the parent ion. Here we show that optimal control of the underlying quantum dynamics can be used to enhance desired features in the photoelectron spectra and angular distributions. To this end, we combine Krotov's method for optimal control theory with the time-dependent configuration interaction singles formalism and a splitting approach to calculate photoelectron spectra and angular distributions. The optimization target can account for specific desired properties in the photoelectron angular distribution alone, in the photoelectron spectrum, or in both. We demonstrate the method for hydrogen and then apply it to argon under strong XUV radiation, maximizing the difference of emission into the upper and lower hemispheres, in order to realize directed electron emission in the XUV regime.

  1. Cosmology Large Angular Scale Surveyor (CLASS) Focal Plane Development

    CERN Document Server

    Chuss, D T; Amiri, M; Appel, J; Bennett, C L; Colazo, F; Denis, K L; Dünner, R; Essinger-Hileman, T; Eimer, J; Fluxa, P; Gothe, D; Halpern, M; Harrington, K; Hilton, G; Hinshaw, G; Hubmayr, J; Iuliano, J; Marriage, T A; Miller, N; Moseley, S H; Mumby, G; Petroff, M; Reintsema, C; Rostem, K; U-Yen, K; Watts, D; Wagner, E; Wollack, E J; Xu, Z; Zeng, L

    2015-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) will measure the polarization of the Cosmic Microwave Background to search for and characterize the polarized signature of inflation. CLASS will operate from the Atacama Desert and observe $\\sim$70% of the sky. A variable-delay polarization modulator (VPM) modulates the polarization at $\\sim$10 Hz to suppress the 1/f noise of the atmosphere and enable the measurement of the large angular scale polarization modes. The measurement of the inflationary signal across angular scales that span both the recombination and reionization features allows a test of the predicted shape of the polarized angular power spectra in addition to a measurement of the energy scale of inflation. CLASS is an array of telescopes covering frequencies of 38, 93, 148, and 217 GHz. These frequencies straddle the foreground minimum and thus allow the extraction of foregrounds from the primordial signal. Each focal plane contains feedhorn-coupled transition-edge sensors that simultaneously d...

  2. Fabrication of the planar angular rotator using the CMOS process

    Science.gov (United States)

    Dai, Ching-Liang; Chang, Chien-Liu; Chen, Hung-Lin; Chang, Pei-Zen

    2002-05-01

    In this investigation we propose a novel planar angular rotator fabricated by the conventional complementary metal-oxide semiconductor (CMOS) process. Following the 0.6 μm single poly triple metal (SPTM) CMOS process, the device is completed by a simple maskless, post-process etching step. The rotor of the planar angular rotator rotates around its geometric center with electrostatic actuation. The proposed design adopts an intelligent mechanism including the slider-crank system to permit simultaneous motion. The CMOS planar angular rotator could be driven with driving voltages of around 40 V. The design proposed here has a shorter response time and longer life, without problems of friction and wear, compared to the more common planar angular micromotor.

  3. Imaging the Earth's Interior: the Angular Distribution of Terrestrial Neutrinos

    CERN Document Server

    Fields, Brian D

    2004-01-01

    Decays of radionuclides throughout the Earth's interior produce geothermal heat, but also are a source of antineutrinos. The (angle-integrated) geoneutrino flux places an integral constraint on the terrestrial radionuclide distribution. In this paper, we calculate the angular distribution of geoneutrinos, which opens a window on the differential radionuclide distribution. We develop the general formalism for the neutrino angular distribution, and we present the inverse transformation which recovers the terrestrial radioisotope distribution given a measurement of the neutrino angular distribution. Thus, geoneutrinos not only allow a means to image the Earth's interior, but offering a direct measure of the radioactive Earth, both (1) revealing the Earth's inner structure as probed by radionuclides, and (2) allowing for a complete determination of the radioactive heat generation as a function of radius. We present the geoneutrino angular distribution for the favored Earth model which has been used to calculate g...

  4. Design and Implementation of a Digital Angular Rate Sensor

    Directory of Open Access Journals (Sweden)

    Zhen Peng

    2010-10-01

    Full Text Available With the aim of detecting the attitude of a rotating carrier, the paper presents a novel, digital angular rate sensor. The sensor consists of micro-sensing elements (gyroscope and accelerometer, signal processing circuit and micro-processor (DSP2812. The sensor has the feature of detecting three angular rates of a rotating carrier at the same time. The key techniques of the sensor, including sensing construction, sensing principles, and signal processing circuit design are presented. The test results show that the sensor can sense rolling, pitch and yaw angular rate at the same time and the measurement error of yaw (or pitch angular rate and rolling rate of the rotating carrier is less than 0.5%.

  5. Ligand Exchange Processes on Solvated Lithium Cations

    OpenAIRE

    Pasgreta, Ewa Maria

    2007-01-01

    In this work the solvation process of Li+ ion, as well as solvent and ligand exchange reactions on Li+ ion were studied. Li+ ions possess interesting properties and like other alkali metal ions are known to form complexes with macrocyclic ligands called cryptands. In this summary, an overview over the insights gained in the factors that control the reactivity of Li+ complexes with respect to the solvent and cryptand properties is presented. Three main questions were addressed: • How does the ...

  6. Chemistry of Marine Ligands and Siderophores

    OpenAIRE

    Vraspir, Julia M.; Butler, Alison

    2009-01-01

    Marine microorganisms are presented with unique challenges to obtain essential metal ions required to survive and thrive in the ocean. The production of organic ligands to complex transition metal ions is one strategy to both facilitate uptake of specific metals, such as iron, and to mitigate the potential toxic effects of other metal ions, such as copper. A number of important trace metal ions are complexed by organic ligands in seawater, including iron, cobalt, nickel, copper, zinc, and cad...

  7. Fas ligand deficiency in HIV disease

    OpenAIRE

    Sieg, Scott; Smith, Dawn; Yildirim, Zafer; Kaplan, David

    1997-01-01

    Apoptosis is postulated to be involved as an anti-viral immune mechanism by killing infected cells before viral replication has occurred. The Fas–Fas ligand interaction is a powerful regulator of T cell apoptosis and could potentially act as a potent anti-viral immune mechanism against T cell tropic virus such as human immunodeficiency virus (HIV). We investigated the status of Fas ligand in peripheral blood mononuclear cells (PBMCs) obtained from persons infected with HIV. We found that mono...

  8. Dynamical birth and thermal death of angular momentum in heavy ion reactions

    International Nuclear Information System (INIS)

    Dynamical and equilibrium angular momentum fractionation as well as equilibrium angular momentum distributions associated with a variety of collective modes of the intermediate complex are described. (orig.)

  9. Generation and detection of orbital angular momentum via metasurface

    OpenAIRE

    Jin, Jinjin; Luo, Jun; Zhang, Xiaohu; Gao, Hui; Li, Xiong; Pu, Mingbo; Gao, Ping; Zhao, Zeyu; Luo, Xiangang

    2016-01-01

    Beams carrying orbital angular momentum possess a significant potential for modern optical technologies ranging from classical and quantum communication to optical manipulation. In this paper, we theoretically design and experimentally demonstrate an ultracompact array of elliptical nanoholes, which could convert the circularly polarized light into the cross-polarized vortex beam. To measure the topological charges of orbital angular momentum in a simple manner, another elliptical nanoholes a...

  10. Asymmetry in the angular distributions of spectator-nucleons

    International Nuclear Information System (INIS)

    The asymmetry in the angular distributions of spectator-nucleons has been studied in dp interactions, and it has been found that the sign of the asymmetry depends on the reaction channel. It is shown that in the momentum interval 0-200 MeV/c of spectators basic features of the angular distributions can be reproduced in the framework of the spectator model taking into account the energy dependence of the NN cross section and the flux-factor

  11. Alignment of angular velocity sensors for a vestibular prosthesis

    OpenAIRE

    DiGiovanna Jack; Carpaneto Jacopo; Micera Silvestro; Merfeld Daniel M

    2012-01-01

    Abstract Vestibular prosthetics transmit angular velocities to the nervous system via electrical stimulation. Head-fixed gyroscopes measure angular motion, but the gyroscope coordinate system will not be coincident with the sensory organs the prosthetic replaces. Here we show a simple calibration method to align gyroscope measurements with the anatomical coordinate system. We benchmarked the method with simulated movements and obtain proof-of-concept with one healthy subject. The method was r...

  12. Alignment of angular velocity sensors for a vestibular prosthesis.

    Science.gov (United States)

    Digiovanna, Jack; Carpaneto, Jacopo; Micera, Silvestro; Merfeld, Daniel M

    2012-01-01

    Vestibular prosthetics transmit angular velocities to the nervous system via electrical stimulation. Head-fixed gyroscopes measure angular motion, but the gyroscope coordinate system will not be coincident with the sensory organs the prosthetic replaces. Here we show a simple calibration method to align gyroscope measurements with the anatomical coordinate system. We benchmarked the method with simulated movements and obtain proof-of-concept with one healthy subject. The method was robust to misalignment, required little data, and minimal processing. PMID:22329908

  13. Angular velocity nonlinear observer from single vector measurements

    OpenAIRE

    Magnis, Lionel; Petit, Nicolas

    2015-01-01

    The paper proposes a technique to estimate the angular velocity of a rigid body from single vector measurements. Compared to the approaches presented in the literature, it does not use attitude information nor rate gyros as inputs. Instead, vector measurements are directly filtered through a nonlinear observer estimating the angular velocity. Convergence is established using a detailed analysis of a linear-time varying dynamics appearing in the estimation error equation. This equation stems f...

  14. Mechanical Faraday effect for orbital angular momentum-carrying beams

    OpenAIRE

    Wisniewski-Barker, Emma; Gibson, Graham; Franke-Arnold, Sonja; Boyd, Robert W; Padgett, Miles J.

    2014-01-01

    When linearly polarised light is transmitted through a spinning window, the plane of polarisation is rotated. This rotation arises through a phase change that is applied to the circularly polarised states corresponding to the spin angular momentum (SAM). Here we show an analogous effect for the orbital angular momentum (OAM), where a differential phase between the positive and negative modes (±ℓ) is observed as a rotation of the transmitted image. For normal materials, this rotation is on the...

  15. A quantum memory for orbital angular momentum photonic qubits

    OpenAIRE

    Nicolas, A; Veissier, L.; Giner, L.; Giacobino, E.; Maxein, D.; Laurat, J.

    2013-01-01

    Among the optical degrees of freedom, the orbital angular momentum of light provides unique properties, including mechanical torque action with applications for light manipulation, enhanced sensitivity in imaging techniques and potential high-density information coding for optical communication systems. Recent years have also seen a tremendous interest in exploiting orbital angular momentum at the single-photon level in quantum information technologies. In this endeavor, here we demonstrate t...

  16. Fundamental methods to measure the orbital angular momentum of light

    OpenAIRE

    Berkhout, Gregorius Cornelis Gerardus (Joris)

    2011-01-01

    Light is a ubiquitous carrier of information. This information can be encoded in the intensity, direction, frequency and polarisation of the light and, which was described more recently, in its orbital angular momentum. Although creating light beams with orbital angular momentum is relatively easy, measuring this property has proven to be difficult. In this thesis we present two fundamental methods to solve this problem. First, we show that by analysing the interference pattern behind a multi...

  17. Spin-to-Orbital Angular Momentum Conversion in Semiconductor Microcavities

    OpenAIRE

    Manni, Francesco; Lagoudakis, Konstantinos G.; Paraïso, Taofiq; Cerna, Roland; Léger, Yoan; Liew, Timothy Chi Hin; Shelykh, Ivan; Kavokin, Alexey V.; Morier-Genoud, François; Deveaud-Plédran, Benoît

    2011-01-01

    We experimentally demonstrate a technique for the generation of optical beams carrying orbital angular momentum using a planar semiconductor microcavity. Despite being isotropic systems with no structural gyrotropy, semiconductor microcavities, because of the transverse-electric–transverse-magnetic polarization splitting that they feature, allow for the conversion of the circular polarization of an incoming laser beam into the orbital angular momentum of the transmitted light field. The proce...

  18. Orbital Angular Momentum and Generalized Transverse Momentum Distribution

    OpenAIRE

    Zhao, Yong; Liu, Keh-Fei; Yang, Yibo

    2015-01-01

    We show that, when boosted to the infinite momentum frame, the quark and gluon orbital angular momentum operators defined in the nucleon spin sum rule of X. S. Chen et al. are the same as those derived from generalized transverse momentum distributions. This completes the connection between the infinite momentum limit of each term in that sum rule and experimentally measurable observables. We also show that these orbital angular momentum operators can be defined locally, and discuss the strat...

  19. Total Internal Reflection of Orbital Angular Momentum Beams

    OpenAIRE

    Loffler W.; Hermosa N.; Aiello A.; Woerdman J.P.

    2012-01-01

    We investigate how beams with orbital angular momentum (OAM) behave under total internal reflection. This is studied in two complementary experiments: In the first experiment, we study geometric shifts of OAM beams upon total internal reflection (Goos-H\\"anchen and Imbert-Fedorov shifts, for each the spatial and angular variant), and in the second experiment we determine changes in the OAM mode spectrum of a beam, again upon total internal reflection. As a result we find that in the first cas...

  20. Comparison between two concepts of angular glint:general considerations

    Institute of Scientific and Technical Information of China (English)

    Wang Chao; Yin Hongcheng; Huang Peikang

    2008-01-01

    Angular glint can be interpreted as a distortion of the radar echo signal phase front,or alternatively,a tilt of the direction of energy flow from the radial direction.As the complementarities and support of argumentation in our previous work,a general discussion about two concepts of angular glint is made based on electromagnetic theory to demonstrate that these two concepts are equivalent when geometrical optics approximation is used and the receiving antenna is linearly polarized.

  1. Identification of Observables for Quark and Gluon Orbital Angular Momentum

    OpenAIRE

    Courtoy, Aurore; Goldstein, Gary R.; Hernandez, J. Osvaldo Gonzalez; Liuti, Simonetta; Rajan, Abha(University of Virginia – Physics Department, 382 McCormick Rd., Charlottesville, VA 22904, USA)

    2014-01-01

    A new debate has recently arisen on the subject of orbital angular momentum in QCD, in particular on its observability and on its partonic interpretation. Orbital momentum can be defined in QCD using two different decomposition schemes that yield a kinetic and a canonical definition, respectively. We argue that kinetic orbital angular momentum is intrinsically associated with twist three generalized parton distributions, and it is therefore more readily observable, while, due to parity constr...

  2. Angular Momentum of Electromagnetic Field in Areas of Polarization Singularities

    Directory of Open Access Journals (Sweden)

    Mokhun I.

    2006-06-01

    Full Text Available It is shown that physical manifestations of any optical singularity are, in one way or another, related to a specific temporal behaviour of the field, no matter scalar or vector cases are realized. Polarization singularities of the vector field are associated with a presence or absence of angular momentum of electromagnetic field. In the vicinity of -point the orbital angular momentum is observed if the sings of topological charge of the vibration phase and the handedness factor are different.

  3. Continuous Variable Entanglement and Squeezing of Orbital Angular Momentum States

    OpenAIRE

    Lassen, Mikael Østergaard; Leuchs, Gerd; Andersen, Ulrik Lund

    2009-01-01

    We report the first experimental characterization of the first-order continuous variable orbital angular momentum states. Using a spatially nondegenerate optical parametric oscillator (OPO) we produce quadrature entanglement between the two first-order Laguerre-Gauss modes. The family of orbital angular momentum modes is mapped on an orbital Poincaré sphere, where the mode's position on the sphere is spanned by the three orbital parameters. Using a nondegenerate OPO we produce squeezing of th...

  4. Quark Orbital Angular Momentum and Exclusive Processes at HERMES

    International Nuclear Information System (INIS)

    A first attempt for a model-dependent extraction of the orbital angular momentum of quarks in the nucleon has been made, based on HERMES data on exclusive processes and their description in terms of generalized parton distributions. An overview of the HERMES data on hard exclusive electroproduction of real photons (Deeply-Virtual Compton Scattering) and mesons is given, focusing on the measurements relevant to the extraction of quark orbital angular momentum

  5. Quark Orbital Angular Momentum and Exclusive Processes at HERMES

    Science.gov (United States)

    Ellinghaus, F.

    2006-11-01

    A first attempt for a model-dependent extraction of the orbital angular momentum of quarks in the nucleon has been made, based on HERMES data on exclusive processes and their description in terms of generalized parton distributions. An overview of the HERMES data on hard exclusive electroproduction of real photons (Deeply-Virtual Compton Scattering) and mesons is given, focusing on the measurements relevant to the extraction of quark orbital angular momentum.

  6. Nonzero orbital angular momentum superfluidity in ultracold Fermi gases

    OpenAIRE

    Iskin, M.; de Melo, C. A. R. Sá

    2006-01-01

    We analyze the evolution of superfluidity for nonzero orbital angular momentum channels from the Bardeen-Cooper-Schrieffer (BCS) to the Bose-Einstein condensation (BEC) limit in three dimensions. First, we analyze the low energy scattering properties of finite range interactions for all possible angular momentum channels. Second, we discuss ground state ($T = 0$) superfluid properties including the order parameter, chemical potential, quasiparticle excitation spectrum, momentum distribution, ...

  7. Mechanical memory for photons with orbital angular momentum

    OpenAIRE

    Shi, H.; Bhattacharya, M.

    2013-01-01

    We propose to use an acoustic surface wave as a memory for a photon carrying orbital angular momentum. We clarify the physical mechanism that enables the transfer of information, derive the angular momentum selection rule that must be obeyed in the process, and show how to optimize the optoacoustic coupling. We theoretically demonstrate that high fidelities can be achieved, using realistic parameters, for the transfer of a coherent optical Laguerre-Gaussian state, associated with large angula...

  8. Molecular chirality and the orbital angular momentum of light

    OpenAIRE

    Andrews, David L; Romero, Luciana C. Davila; Babiker, Mohamed

    2003-01-01

    Optical beams with a new and distinctive type of helicity have become the subject of much recent interest. While circularly polarised light comprises photons with spin angular momentum, these optically engineered 'twisted beams' (optical vortices) are endowed with orbital angular momentum. Here, the wave- front surface of the electromagnetic fields assumes helical form. To date, optical vortices have generally been studied only in their interactions with achiral matter. This study assesses wh...

  9. Conservation of orbital angular momentum in air core optical fibers

    OpenAIRE

    Gregg, P; Kristensen, P; Ramachandran, S.

    2014-01-01

    Light's orbital angular momentum (OAM) is a conserved quantity in cylindrically symmetric media; however, it is easily destroyed by free-space turbulence or fiber bends, because anisotropic perturbations impart angular momentum. We observe the conservation of OAM even in the presence of strong bend perturbations, with fibers featuring air cores that appropriately sculpt the modal density of states. In analogy to the classical reasoning for the enhanced stability of spinning tops with increasi...

  10. Relaxation times for angular momentum in damped nuclear reactions

    International Nuclear Information System (INIS)

    The evolution of the angular momentum distribution in damped nuclear reactions is discussed within the framework of the nucleon exchange transport model. First order equations are derived for the time evolution of the mean values and covariances of the spin variables. Solutions are given for 1400 MeV 165Ho + 165Ho reactions at various values of total angular momentum and total kinetic energy loss. Spin dispersions are well described by the calculations

  11. The angular momentum of baryons and dark matter halos revisited

    OpenAIRE

    Kimm, Taysun; Devriendt, Julien; Slyz, Adrianne; Pichon, Christophe; Kassin, Susan A.; Dubois, Yohan

    2011-01-01

    Recent theoretical studies have shown that galaxies at high redshift are fed by cold, dense gas filaments, suggesting angular momentum transport by gas differs from that by dark matter. Revisiting this issue using high-resolution cosmological hydrodynamics simulations with adaptive mesh refinement, we find that at the time of accretion, gas and dark matter do carry a similar amount of specific angular momentum, but that it is systematically higher than that of the dark matter halo as a whole....

  12. Students' Understanding of the Addition of Angular Momentum

    CERN Document Server

    Singh, Chandralekha

    2016-01-01

    We describe the difficulties advanced undergraduate and graduate students have with concepts related to the addition of angular momentum. We also describe the development and implementation of a research-based learning tool, a Quantum Interactive Learning Tutorial (QuILT), to reduce these difficulties. The preliminary evaluation shows that the QuILT on the addition of angular momentum is helpful in improving students' understanding of these concepts.

  13. Topological defects, geometric phases, and the angular momentum of light

    CERN Document Server

    Tiwari, S C

    2007-01-01

    Recent reports on the intriguing features of vector vortex bearing beams are analyzed using geometric phases in optics. It is argued that the spin redirection phase induced circular birefringence is the origin of topological phase singularities arising in the inhomogeneous polarization patterns. A unified picture of recent results is presented based on this proposition. Angular momentum shift within the light beam (OAM) has exact equivalence with the angular momentum holonomy associated with the geometric phase consistent with our conjecture.

  14. Construction of dinuclear complexes using multidentate ligands

    International Nuclear Information System (INIS)

    This work details the synthesis of novel copper(I), copper(II), nickel(II) and zinc(II) dinuclear complexes. Attempts have been made to control the co-ordination architectures of the metal centres by using bis-bidentate and tridentate chelating N,S- and N-donor ligands to generate dinuclear systems. The ligands were both symmetrically and asymmetrically disubstituted pyridazine-based and pyridine-based ligands consisting of a mixture of N-only and mixed N,S-donors. The study using the pyridazine-based ligands continues previous research in our group using 3,6-bis disubstituted pyridazine-based ligands to form complexes with copper(l) and copper(II). The pyridazine-based ligands have been seen to be bis-bidentate upon co-ordination of copper. The pyridazine-based ligands could be envisaged to generate dinuclear complexes by directly bridging between two metal ions. This study involved the formation of copper(l), nickel(II) and zinc(II) complexes with these ligands. The structural properties of two particular complexes have been explored using X-ray crystallography and spectroscopic techniques. Pyridine-based ligands have also been used previously in our group as tridentate chelating ligands. They have been seen to form dinuclear complexes with copper(I) and copper(II) when reacted with an additional bridging ligand e.g. 4,4'-bipyridine. This provides an alternative method for generating dinuclear complexes. Chapter 1 presents an introduction to the area of supramolecular chemistry from which we can learn the principles of polymer formation and them 'in reverse' to generate discrete dinuclear systems. Chapter 2 details the synthesis of the pyridazine and pyridine-based ligands including a detailed nmr study of the ligands. Since the ligands were synthesised using cyclic thioamides as terminal groups it has been found that thiol-thione tautomerisation occurred during synthesis giving rise to two possible ligand conformations. The nmr study has been used to try and

  15. Visualizing ligand molecules in twilight electron density

    International Nuclear Information System (INIS)

    A software script is presented for facilitating the analysis and visual inspection of ligand molecules in the context of the electron-density maps calculated from experimental data associated with protein structures determined by X-ray crystallography. Three-dimensional models of protein structures determined by X-ray crystallography are based on the interpretation of experimentally derived electron-density maps. The real-space correlation coefficient (RSCC) provides an easily comprehensible, objective measure of the residue-based fit of atom coordinates to electron density. Among protein structure models, protein–ligand complexes are of special interest, given their contribution to understanding the molecular underpinnings of biological activity and to drug design. For consumers of such models, it is not trivial to determine the degree to which ligand-structure modelling is biased by subjective electron-density interpretation. A standalone script, Twilight, is presented for the analysis, visualization and annotation of a pre-filtered set of 2815 protein–ligand complexes deposited with the PDB as of 15 January 2012 with ligand RSCC values that are below a threshold of 0.6. It also provides simplified access to the visualization of any protein–ligand complex available from the PDB and annotated by the Uppsala Electron Density Server. The script runs on various platforms and is available for download at http://www.ruppweb.org/twilight//

  16. Designer TGFβ superfamily ligands with diversified functionality.

    Directory of Open Access Journals (Sweden)

    George P Allendorph

    Full Text Available Transforming Growth Factor--beta (TGFβ superfamily ligands, including Activins, Growth and Differentiation Factors (GDFs, and Bone Morphogenetic Proteins (BMPs, are excellent targets for protein-based therapeutics because of their pervasiveness in numerous developmental and cellular processes. We developed a strategy termed RASCH (Random Assembly of Segmental Chimera and Heteromer, to engineer chemically-refoldable TGFβ superfamily ligands with unique signaling properties. One of these engineered ligands, AB208, created from Activin-βA and BMP-2 sequences, exhibits the refolding characteristics of BMP-2 while possessing Activin-like signaling attributes. Further, we find several additional ligands, AB204, AB211, and AB215, which initiate the intracellular Smad1-mediated signaling pathways more strongly than BMP-2 but show no sensitivity to the natural BMP antagonist Noggin unlike natural BMP-2. In another design, incorporation of a short N-terminal segment from BMP-2 was sufficient to enable chemical refolding of BMP-9, without which was never produced nor refolded. Our studies show that the RASCH strategy enables us to expand the functional repertoire of TGFβ superfamily ligands through development of novel chimeric TGFβ ligands with diverse biological and clinical values.

  17. LigandRFs: random forest ensemble to identify ligand-binding residues from sequence information alone

    KAUST Repository

    Chen, Peng

    2014-12-03

    Background Protein-ligand binding is important for some proteins to perform their functions. Protein-ligand binding sites are the residues of proteins that physically bind to ligands. Despite of the recent advances in computational prediction for protein-ligand binding sites, the state-of-the-art methods search for similar, known structures of the query and predict the binding sites based on the solved structures. However, such structural information is not commonly available. Results In this paper, we propose a sequence-based approach to identify protein-ligand binding residues. We propose a combination technique to reduce the effects of different sliding residue windows in the process of encoding input feature vectors. Moreover, due to the highly imbalanced samples between the ligand-binding sites and non ligand-binding sites, we construct several balanced data sets, for each of which a random forest (RF)-based classifier is trained. The ensemble of these RF classifiers forms a sequence-based protein-ligand binding site predictor. Conclusions Experimental results on CASP9 and CASP8 data sets demonstrate that our method compares favorably with the state-of-the-art protein-ligand binding site prediction methods.

  18. Fully Flexible Docking of Medium Sized Ligand Libraries with RosettaLigand

    Science.gov (United States)

    DeLuca, Samuel; Khar, Karen; Meiler, Jens

    2015-01-01

    RosettaLigand has been successfully used to predict binding poses in protein-small molecule complexes. However, the RosettaLigand docking protocol is comparatively slow in identifying an initial starting pose for the small molecule (ligand) making it unfeasible for use in virtual High Throughput Screening (vHTS). To overcome this limitation, we developed a new sampling approach for placing the ligand in the protein binding site during the initial ‘low-resolution’ docking step. It combines the translational and rotational adjustments to the ligand pose in a single transformation step. The new algorithm is both more accurate and more time-efficient. The docking success rate is improved by 10–15% in a benchmark set of 43 protein/ligand complexes, reducing the number of models that typically need to be generated from 1000 to 150. The average time to generate a model is reduced from 50 seconds to 10 seconds. As a result we observe an effective 30-fold speed increase, making RosettaLigand appropriate for docking medium sized ligand libraries. We demonstrate that this improved initial placement of the ligand is critical for successful prediction of an accurate binding position in the ‘high-resolution’ full atom refinement step. PMID:26207742

  19. Angular-velocity control approach for stance-control orthoses.

    Science.gov (United States)

    Lemaire, Edward D; Goudreau, Louis; Yakimovich, Terris; Kofman, Jonathan

    2009-10-01

    Currently, stance-control knee orthoses require external control mechanisms to control knee flexion during stance and allow free knee motion during the swing phase of gait. A new angular-velocity control approach that uses a rotary-hydraulic device to resist knee flexion when the knee angular velocity passes a preset threshold is presented. This angular-velocity approach for orthotic stance control is based on the premise that knee-flexion angular velocity during a knee-collapse event, such as a stumble or fall, is greater than that during walking. The new hydraulic knee-flexion control device does not require an external control mechanism to switch from free motion to stance control mode. Functional test results demonstrated that the hydraulic angular-velocity activated knee joint provided free knee motion during walking, engaged upon knee collapse, and supported body weight while the end-user recovered to a safe body position. The joint was tested to 51.6 Nm in single loading tests and passed 200,000 repeated loading cycles with a peak load of 88 Nm per cycle. The hydraulic, angular velocity activation approach has potential to improve safety and security for people with lower extremity weakness or when recovering from joint trauma. PMID:19497821

  20. Angular Impulse and Balance Regulation During the Golf Swing.

    Science.gov (United States)

    Peterson, Travis J; Wilcox, Rand R; McNitt-Gray, Jill L

    2016-08-01

    Our aim was to determine how skilled players regulate linear and angular impulse while maintaining balance during the golf swing. Eleven highly-skilled golf players performed swings with a 6-iron and driver. Components contributing to linear and angular impulse generated by the rear and target legs (resultant horizontal reaction force [RFh], RFh-angle, and moment arm) were quantified and compared across the group and within a player (α = .05). Net angular impulse generated by both the rear and target legs was greater for the driver than the 6-iron. Mechanisms used to regulate angular impulse generation between clubs varied across players and required coordination between the legs. Increases in net angular impulse with a driver involved increases in target leg RFh. Rear leg RFh-angle was maintained between clubs whereas target leg RFh became more aligned with the target line. Net linear impulse perpendicular to the target line remained near zero, preserving balance, while net linear impulse along the target line decreased in magnitude. These results indicate that the net angular impulse was regulated between clubs by coordinating force generation of the rear and target legs while sustaining balance throughout the task. PMID:26958870