WorldWideScience

Sample records for angular bipyridyl ligands

  1. Supramolecular architectures constructed using angular bipyridyl ligands

    CERN Document Server

    Barnett, S A

    2003-01-01

    This work details the synthesis and characterization of a series of coordination frameworks that are formed using bidentate angular N-donor ligands. Pyrimidine was reacted with metal(ll) nitrate salts. Reactions using Cd(NO sub 3) sub 2 receive particular focus and the analogous reactions using the linear ligand, pyrazine, were studied for comparison. In all cases, two-dimensional coordination networks were prepared. Structural diversity is observed for the Cd(ll) centres including metal-nitrate bridging. In contrast, first row transition metal nitrates form isostructural one-dimensional chains with only the bridging N-donor ligands generating polymeric propagation. The angular ligand, 2,4-bis(4-pyridyl)-1,3,5-triazine (dpt), was reacted with Cd(NO sub 3) sub 2 and Zn(NO sub 3) sub 2. Whereas Zn(NO sub 3) sub 2 compounds exhibit solvent mediated polymorphism, a range of structures were obtained for the reactions with Cd(NO sub 3) sub 2 , including the first example of a doubly parallel interpenetrated 4.8 sup...

  2. Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.

    Science.gov (United States)

    Gavette, Jesse V; Klug, Christina M; Zakharov, Lev N; Shores, Matthew P; Haley, Michael M; Johnson, Darren W

    2014-07-11

    A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

  3. Structural diversity and photocatalytic properties of Cd(II) coordination polymers constructed by a flexible V-shaped bipyridyl benzene ligand and dicarboxylate derivatives.

    Science.gov (United States)

    Liu, Lei-Lei; Yu, Cai-Xia; Ma, Feng-Ji; Li, Ya-Ru; Han, Jing-Jing; Lin, Lu; Ma, Lu-Fang

    2015-01-28

    Hydrothermal reactions of Cd(OAc)2·2H2O with a flexible V-shaped bipyridyl benzene ligand and five benzenedicarboxylic acid derivatives gave rise to five new coordination polymers i.e., [Cd(1,4-BDC)(bpmb)(H2O)]n (1), {[Cd(1,3-BDC)(bpmb)]·0.125H2O}n (2), [Cd2(5-Me-1,3-BDC)2(bpmb)2]n (3), [Cd(5-NO2-1,3-BDC)(bpmb)(H2O)]n (4) and [Cd(5-OH-1,3-BDC)(bpmb)(H2O)]n (5) (bpmb = 1,3-bis(pyridine-3-ylmethoxy)benzene, 1,4-H2BDC = 1,4-benzenedicarboxylic acid, 1,3-H2BDC = 1,3-benzenedicarboxylic acid, 5-Me-1,3-H2BDC = 5-methyl-1,3-benzenedicarboxylic acid, 5-NO2-1,3-H2BDC = 5-nitro-1,3-benzenedicarboxylic acid, 5-OH-1,3-H2BDC = 5-hydroxy-1,3-benzenedicarboxylic acid). Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Compound 1 is a two-fold interpenetrating network showing the coexistence of polyrotaxane and polycatenane characters. Compounds 2 and 3 exhibit similar 2D (3,5)-connected (4(2)·6(7)·8)(4(2)·6) nets in which the bpmb ligands work as lockers in interlocking 1D [Cd(1,3-BDC/5-Me-1,3-BDC)]n chains. Compound 4 shows a 2D 4-connected (6(6)) sandwich-like structure with differently oriented [Cd(5-NO2-1,3-BDC)]n chains. Compound 5 is a 3D supramolecular pcu net based on a 1D ladder-shaped chain. These results suggest that the substituted positions of carboxylate groups and changes in substituted R groups in the 5-position of BDC ligands have significant effect on the final structures. These compounds exhibited relatively good photocatalytic activity towards the degradation of methylene blue (MB) in aqueous solution under UV irradiation. Moreover, solid-state photoluminescence properties of 1-5 were also investigated.

  4. Mixed-ligand binuclear copper(II) complex of 5-methylsalicylaldehyde and 2,2'-bipyridyl: Synthesis, crystal structure, DNA binding and nuclease activity

    Indian Academy of Sciences (India)

    Perumal Gurumoorthy; Jayaram Ravichandran; Aziz Kalilur Rahiman

    2014-05-01

    A new mixed-ligand binuclear copper(II) complex [Cu(MS)(bpy)]2.(ClO4)2, built of 5-methylsalicylaldehyde and 2,2'-bipyridyl has been synthesized and characterized by using elemental analysis, IR and UV-Vis spectroscopy. Crystal structure of the complex shows that copper(II) ion lies in a square pyramidal coordination environment. The structure consists of two symmetrical half units in which the copper(II) ion of one half unit connected with the phenolate oxygen atom of other half unit along with one perchlorate anion in the crystal lattice as free molecule. Presence of uncoordinated perchlorate anion was also confirmed by IR spectroscopy. Absorption spectroscopy exhibits d-d transition at 628 nm, which further supports the square pyramidal geometry around the copper(II) ions. EPR spectrum of the copper(II) complex at room temperature shows a broad signal without any splitting pattern at ∥ = 2.26, ⊥ = 2.03 and the magnetic moment (eff = 1.31 BM) obtained at room temperature indicate an antiferromagnetic interaction between the two copper(II) ions through phenoxide-bridge. Binding studies reveal that the complex possesses good binding propensity (b = 5.2 ± 1.7 × 104 M-1) and bind to nitrogenous bases of DNA through intercalation. Nuclease activity of the complex with pBR322 DNA shows that the effect of hydrolytic cleavage is dose-dependent and the oxidative cleavage indicates the involvement of hydroxyl radical and singlet-oxygen as reactive oxygen species.

  5. Comparison of bipyridyl, maltol and kojic acid action as organic vanadium ligands on activity of galactosyltransferase (EC 2.4.1.38), some physiological parameters and ultrastructure of Golgi complexes in rat hepatocytes.

    Science.gov (United States)

    Dabros, Wojciech; Kordowiak, Anna

    2007-01-01

    The biochemical activity and morphology of control and streptozotocin-diabetic rat liver Golgi complexes were previously investigated by us under influence of some vanadium [V(IV)] compounds. The effectiveness of these derivatives depends on the kind of complexing ligands. This paper presents the investigation of the effect of bipyridyl, the ligand of a new vanadium compound, tested by us with maltol and kojic acid (two ligands studied by the present and other authors). The three ligands alone action was tested under the same experimental conditions as in the case of whole compounds with vanadium and applied to liver Golgi complexes of control rats. A preliminary study for maltol and kojic acid had been previously carried out by us parallel with tests of whole vanadium complexes, but valuable differences in biological action found in our condition of experiments suggested the extension of studies to include the two above-mentioned ligands and to compare the effects of the three investigated ligands. The supplementary part of the experiment focused mainly on the ultrastructure of Golgi complexes in hepatocytes. Four groups of animals were used: C - control rats, C + M (maltol), C + (ka)2 (kojic acid) and C + (bpy)2 (bipyridyl). The control rats received 0.09M NaCl as drinking liquid; all the other animals were given 3.6 mmol/L of appropriate ligand solution in 0.09M NaCl during 7 days. All the animals survived the experiments. Only in group C + (bpy)2 did the authors observe statistically significant differences as compared with the controls (group C). The differences were detected in physiological studies and manifested as body weight decreased by approximately 20% during the experiment, lower liquid (pfood (pvanadium compounds were employed in our earlier experiments. As it follows, the ligands alone were demonstrated to be much more toxic to morphology of control liver Golgi apparatus as compared to complex compounds, which showed the ability of the former to

  6. Comparison of bipyridyl, maltol and kojic acid action as organic vanadium ligands on activity of galactosyltransferase (EC 2.4.1.38, some physiological parameters and ultrastructure of Golgi complexes in rat hepatocytes.

    Directory of Open Access Journals (Sweden)

    Wojciech Dabros

    2007-10-01

    Full Text Available The biochemical activity and morphology of control and streptozotocin-diabetic rat liver Golgi complexes were previously investigated by us under influence of some vanadium [V(IV] compounds. The effectiveness of these derivatives depends on the kind of complexing ligands. This paper presents the investigation of the effect of bipyridyl, the ligand of a new vanadium compound, tested by us with maltol and kojic acid (two ligands studied by the present and other authors. The three ligands alone action was tested under the same experimental conditions as in the case of whole compounds with vanadium and applied to liver Golgi complexes of control rats. A preliminary study for maltol and kojic acid had been previously carried out by us parallel with tests of whole vanadium complexes, but valuable differences in biological action found in our condition of experiments suggested the extension of studies to include the two above-mentioned ligands and to compare the effects of the three investigated ligands. The supplementary part of the experiment focused mainly on the ultrastructure of Golgi complexes in hepatocytes. Four groups of animals were used: C - control rats, C + M (maltol, C + (ka2 (kojic acid and C + (bpy2 (bipyridyl. The control rats received 0.09M NaCl as drinking liquid; all the other animals were given 3.6 mmol/L of appropriate ligand solution in 0.09M NaCl during 7 days. All the animals survived the experiments. Only in group C + (bpy2 did the authors observe statistically significant differences as compared with the controls (group C. The differences were detected in physiological studies and manifested as body weight decreased by approximately 20% during the experiment, lower liquid (p<0.001 and food (p<0.01 intake and increase of free blood sugar level (p<0.01. The yield of Golgi membrane isolation decreased in this group (p<0.01. The main investigated biochemical parameter, i.e. the activity of liver Golgi marker enzyme

  7. Synthesis, Photophysical and Electrochemical Properties of a Mixed Bipyridyl-Phenanthrolyl Ligand Ru(II Heteroleptic Complex Having trans-2-Methyl-2-butenoic Acid Functionalities

    Directory of Open Access Journals (Sweden)

    Adewale O. Adeloye

    2011-09-01

    Full Text Available In this work, two ligands: 4-(trans-2-Methyl-2-butenoic acid-2,2'-bipyridine (L1 and 5-(trans-2-methyl-2-butenoic acid-1,10-phenanthroline (L2, with the corresponding mixed-ligand heteroleptic Ru(II complex were synthesized and characterized by FT-IR, 1H-, 13C-NMR spectroscopy and elemental analysis. The influence of the mixed functionalized polypyridyl ruthenium(II complex on the photophysical and electrochemical properties were investigated and compared to individual single-ligand homoleptic complexes. Interestingly, the mixed-ligand complex formulated as [RuL1L2(NCS2] exhibits broad and intense metal-to-ligand charge transfer (MLCT absorption with a high molar extinction coefficient (λmax = 514 nm, ε = 69,700 M−1 cm−1, better than those of individual single-ligand complexes, [Ru(L12(NCS2] and [Ru(L22(NCS2], and a strong photoluminescence intensity ratio in the red region at λem = 686 nm. The electrochemical properties of the complex indicated that the redox processes are ligand-based.

  8. Kinetics and mechanism of the ligand substitution reaction of di--hydroxobis(bipyridyl)dipalladium(II) ion with diethyldithiocarbamate anion in aqueous solution

    Indian Academy of Sciences (India)

    Subhasis Mallick; Biplab K Bera; Subala Mondal; Parnajyoti Karmakar; Arup Mandal; Alak K Ghosh

    2011-05-01

    The kinetics of the interaction between diethyldithiocarbamate (Et2DTC) and the title complex has been studied spectrophotometrically in aqueous medium as a function of nucleophile concentration, temperature and pH at constant ionic strength. The reaction is a two-step process in which the first step is liganddependent, but the second step is ligand-independent and is assigned to ring closure. The rate and activation parameters, conductivity studies and IR data were used to deduce a plausible mechanism.

  9. Assembly, characterization, and electrochemical properties of immobilized metal bipyridyl complexes on silicon(111) surfaces.

    Science.gov (United States)

    Lattimer, Judith R C; Blakemore, James D; Sattler, Wesley; Gul, Sheraz; Chatterjee, Ruchira; Yachandra, Vittal K; Yano, Junko; Brunschwig, Bruce S; Lewis, Nathan S; Gray, Harry B

    2014-10-28

    Silicon(111) surfaces have been functionalized with mixed monolayers consisting of submonolayer coverages of immobilized 4-vinyl-2,2'-bipyridyl (1, vbpy) moieties, with the remaining atop sites of the silicon surface passivated by methyl groups. As the immobilized bipyridyl ligands bind transition metal ions, metal complexes can be assembled on the silicon surface. X-ray photoelectron spectroscopy (XPS) demonstrates that bipyridyl complexes of [Cp*Rh], [Cp*Ir], and [Ru(acac)2] were formed on the surface (Cp* is pentamethylcyclopentadienyl, acac is acetylacetonate). For the surface prepared with Ir, X-ray absorption spectroscopy at the Ir LIII edge showed an edge energy as well as post-edge features that were essentially identical with those observed on a powder sample of [Cp*Ir(bpy)Cl]Cl (bpy is 2,2'-bipyridyl). Charge-carrier lifetime measurements confirmed that the silicon surfaces retain their highly favorable photoelectronic properties upon assembly of the metal complexes. Electrochemical data for surfaces prepared on highly doped, n-type Si(111) electrodes showed that the assembled molecular complexes were redox active. However the stability of the molecular complexes on the surfaces was limited to several cycles of voltammetry.

  10. Detection of zinc ions under aqueous conditions using chirality assisted solid-state fluorescence of a bipyridyl based fluorophore.

    Science.gov (United States)

    Sreejith, Sivaramapanicker; Divya, Kizhumuri P; Ajayaghosh, Ayyappanpillai

    2008-07-07

    A pyrrole end-capped bipyridyl ligand incorporating a chiral handle exhibited high solid-state emission when compared to the achiral analogue 1b and to the racemic molecule 1c which allowed the design of a reusable fluorescent probe for the selective detection of Zn2+ under aqueous conditions.

  11. Do nonbonded H--H interactions in phenanthrene stabilize it relative to anthracene? A possible resolution to this question and its implications for ligands such as 2,2'-bipyridyl.

    Science.gov (United States)

    Hancock, Robert D; Nikolayenko, Igor V

    2012-08-23

    The problem of whether interactions between the hydrogen atoms at the 1,10-positions in the "cleft" of the "bent" phenanthrene stabilize the latter molecule thermodynamically relative to "linear" anthracene, or whether the higher stability of phenanthrene is due to a more energetically favorable π-system, is considered. DFT calculations at the X3LYP/cc-pVTZ(-f)++ level of the ground state energies (E) of anthracene, phenanthrene, and the set of five benzoquinolines are reported. In the gas phase, "bent" phenanthrene was computed to be thermodynamically more stable than "linear" anthracene by -28.5 kJ mol(-1). This fact was attributed predominantly to the phenomenon of higher aromatic stabilization of the π-system of phenanthrene relative to anthracene, and not to the stabilizing influence of the nonbonding H--H interactions in its cleft. In fact, these interactions in phenanthrene were shown to be destabilizing. Similar calculations for five benzoquinolines (bzq) indicate that ΔE values vary as: 6,7-bzq (linear) ≤ 2,3-bzq (linear) < 5,6-bzq (bent) ≤ 3,4-bzq (bent) < 7,8-bzq (bent, no H--H nonbonding interactions in cleft), supporting the idea that it is a more stable π-system that favors 7,8-bzq over 2,3-bzq and 6,7-bzq, and that the H--H interactions in the clefts of 3,4-bzq and 5,6-bzq are destabilizing. Intramolecular hydrogen bonding in the cleft of 7,8-bzq plays a secondary role in its stabilization relative 6,7-bzq. The question of whether H--H nonbonded interactions between H atoms at the 3 and 3' positions of 2,2'-bipyridyl (bpy) coordinated to metal ions are stabilizing or destabilizing is then considered. The energy of bpy is scanned as a function of N-C-C-N torsion angle (χ) in the gas-phase, and it is found that the trans form is 32.8 kJ mol(-1) more stable than the cis conformer. A relaxed coordinate scan of energy of bpy in aqueous solution as a function of χ is modeled using the PBF approach, and it is found that the trans conformer is

  12. Complexes of 5,5'-aminoacido-substituted 2,2'-bipyridyl ligands: control of diastereoselectivity with a pH switch and a chloride-responsive combinatorial library.

    Science.gov (United States)

    Telfer, Shane G; Yang, Xiao-Juan; Williams, Alan F

    2004-03-07

    The synthesis and coordination chemistry of a new chiral ligand, 2,2'-bipyridine substituted at the 5 and 5' positions by N-methyl-L-valine methyl ester (5), is presented. The ligand readily forms complexes [M(5)3]2+ where M = Co(II) and Fe(II) in CH3CN, and the complexation reaction is slightly diastereoselective (d.e. =ca. 20%) in favour of the Delta diastereomer. The addition of six equivalents of HCl to these complexes [M(II)(5)3]2+ leads to formation of Delta-[M(II)(5H2)3]8+ with a d.e. of 100%. This high diastereoselectivity can be reversed by the addition of base i.e. the diastereoselectivity can be controlled by the pH. Delta-[Fe(5H2)3]8+ was found to bind chloride ions in CD3OD-CD3CN (6:1) with a binding constant of 260 M(-1). [Co(II)(5)3]2+ can be oxidised to Delta-[Co(III)(5H2)3]9+. Formation constants for both [Co(II)(5)3]2+ and [Co(II)(5H2)3]8+ in acetonitrile were obtained by spectrophotometric titrations. In the former case, the stability constant, log beta3 = 19.5(8), is very similar to that measured for [Co(II)(bipy)3]2+ (log beta3 = 19.3(7)) but this drops significantly when the amine groups of are protonated (log beta3 = 16.5(2)). A dynamic combinatorial library was prepared by mixing three equivalents of, three equivalents of bipy, and two equivalents of Co(II) in CD3CN. The presence of all possible Delta- and Lambda-[Co(II)(5)x(bipy)(3-x)]2+ complexes was inferred from 1H NMR and ES-MS spectra. Addition of protons to this library reduced the number of components by inducing diastereoselectivity, and presence of chloride further simplified the 1H NMR spectrum, indicating that [Cl2 ligand Delta-[Co(II)(5H2)3

  13. Facile synthesis of one-dimensional organometallic-organic hybrid polymers based on a diphosphorus complex and flexible bipyridyl linkers.

    Science.gov (United States)

    Elsayed Moussa, M; Attenberger, B; Peresypkina, E V; Fleischmann, M; Balázs, G; Scheer, M

    2016-08-21

    The selective synthesis of a series of new "ladderlike" one-dimensional organometallic-organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(η(2)-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity. This unique behaviour is supported by DFT calculations.

  14. A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II Complex: Synthesis, Photophysical and Electrochemical Properties

    Directory of Open Access Journals (Sweden)

    Peter A. Ajibade

    2011-06-01

    Full Text Available In our quest to develop good materials as photosensitizers for photovoltaic dye-sensitized solar cells (DSSCs, cis-dithiocyanato-4-(2,3-dimethylacrylic acid-2,2'-bipyridyl-4-(9-anthracenyl-(2,3-dimethylacrylic-2,2'-bipyridyl ruthenium(II complex, a high molar extinction coefficient charge transfer sensitizer, was designed, synthesized and characterized by spectroscopy and electrochemical techniques. Earlier studies on heteroleptic ruthenium(II complex analogues containing functionalized oligo-anthracenyl phenanthroline ligands have been reported and documented. Based on a general linear correlation between increase in the length of π-conjugation bond and the molar extinction coefficients, herein, we report the photophysical and electrochemical properties of a Ru(II bipyridyl complex analogue with a single functionalized anthracenyl unit. Interestingly, the complex shows better broad and intense metal-to ligand charge transfer (MLCT band absorption with higher molar extinction coefficient (λmax = 518 nm, e = 44900 M−1cm−1, and appreciable photoluminescence spanning the visible region than those containing higher anthracenyl units. It was shown that molar absorption coefficient of the complexes may not be solely depended on the extended π-conjugation but are reduced by molecular aggregation in the molecules.

  15. Investigation of hyperfine interactions in hafnium compounds with F{sup 1-}, OH{sup 1-}, and EDTA ligands by perturbed {gamma}-{gamma} angular correlation

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Antonio A.; Silva, Andreia dos S.; Lapolli, Andre L.; Carbonari, Artur W.; Saxena, Rajendra N., E-mail: alapolli@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using {sup 181}Hf {yields}{sup 181}Ta, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH between 4 and 5 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  16. Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: Crystal structure, photoluminescence and photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Bisht, Kamal Kumar; Rachuri, Yadagiri [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Academy of Scientific and Innovative Research (AcSIR), CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Parmar, Bhavesh [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Suresh, Eringathodi, E-mail: esuresh@csmcri.org [Analytical Discipline and Centralized Instrument Facility, CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India); Academy of Scientific and Innovative Research (AcSIR), CSIR—Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G. B. Marg, Bhavnagar-364 002, Gujarat (India)

    2014-05-01

    Four ternary coordination polymers (CPs) namely, ([Ni(SDB)(BITMB)(H{sub 2}O)]·H{sub 2}O){sub n} (CP1), ([Cd(SDB)(BITMB) (H{sub 2}O)]·(THF)(H{sub 2}O)){sub n} (CP2), ([Zn{sub 2}(SDB){sub 2}(BITMB)]·(THF){sub 2}){sub n} (CP3) and ([Co{sub 2}(SDB){sub 2}(BITMB)]·(Dioxane){sub 3}){sub n} (CP4) composed of angular dicarboxylate SDB (4,4'-sulfonyldibenzoate) and N-donor BITMB (1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethyl benzene) have been synthesized by solvothermal reactions and characterized by single crystal X-ray diffraction and other physico-chemical techniques. CP1 possesses one-dimensional ribbon type metal–organic motifs glued together by H-bonds and π⋯π interactions, whereas CP2–CP4, exhibit non-interpenetrated sql networks supported by weak supramolecular interactions. Structural diversity of these CPs can be attributed to the coordination geometry adopted by the metal nodes, versatile coordination modes of SDB and conformational flexibility of BITMB. Solid state luminescence properties of CP1–CP4 were explored. Photocatalytic performance of all CPs for the decomposition of metanil yellow by dilute hydrogen peroxide in the presence of visible light was also investigated. 25–83% dye removal from aqueous solutions in the presence of CP1–CP4 was observed. - Graphical abstract: Four new ternary transition metal CPs have been hydrothermally prepared and their structural aspects as well as photocatalytic activity for decolourization of metanil yellow (MY) dye have been investigated. - Highlights: • Four ternary coordination polymers containing Ni, Cd, Zn and Co center are prepared. • Crystal structure and thermal stability of all four CPs has been described. • PL and diffuse reflectance spectra of synthesized CPs have also been examined. • Band gap values suggest semiconducting behavior of prepared CPs. • Photocatalytic activity of CPs for oxidative degradation of metanil yellow is studied.

  17. Theoretical Investigation on the Absorption and Emission Properties of the Three Isomers of Bis(thiocyanato)(2,2'-bipyridyl)platinum(Ⅱ)

    Institute of Scientific and Technical Information of China (English)

    HU,Xiao-Ying; LIU,Xiao-Juan; FENG,Ji-Kang

    2007-01-01

    This paper presents a Density Functional or Time Dependent Density Functional (DFT/TDDFT) study of the molecular and electronic structures, optical absorption and emission spectra of three linkage isomers:bis(isothiocyanato-S)(2,2'-bipyridyl) platinum(Ⅱ) ([Pt(SCN)2(bpy)]), (isothiocyanato-S)(thiocyanato-N)-(2,2'-bipyridyl) platinum(Ⅱ) ([Pt(SCN)(NCS)(bpy)]), and bis(thiocyanato-N)(2,2')-bipyridyl)platinum(Ⅱ) ([Pt(NCS)2(bpy)]),in which different coordination ligands based on the N- and S-coordination of the thiocyanato ligands control the luminescent color. The electronic structures were studied using the B3LYP functional. Optimized geometries were compared to the experimentally observed structures. TDDFT calculation was carried out to investigate the excited singlet and triplet states. Calculations have been performed both in vacuo and in solvents, using a polarized continuum model (PCM) to account for solute-solvent interactions. Inclusion of the solvent led to a significant energy change, and as a consequence, the computed spectrum calculated in the presence of the solvent was in good agreement with the experimental determinations. The first two absorptions were found to originate from mixed platinum-SCN (or NSC) to bipyridyl-π* transitions rather than pure metal-to-ligand-charge-transfer (MLCT) transitions,whereas the higher-energy bands arose from intraligand π→π* transitions. The stretching frequencies of C≡N have been calculated both in the ground and excited states, which are relative to the charge transition during the excitation. In addition, different sizes of basis sets were also discussed in this paper.

  18. Inherent helicity in an extended tris-bipyridyl molecular cage

    Energy Technology Data Exchange (ETDEWEB)

    Perkins, D.; Lindoy, L.; Meehan, G.; Turner, P. (University of Sydney)

    2010-11-16

    A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(II) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends {approx}22 {angstrom} along the axial length of the molecule.

  19. Synthesis, Structural Characterization, and Antitumor Activity of a Ca(II Coordination Polymer Based on 1,6-Naphthalenedisulfonate and 4,4′-Bipyridyl

    Directory of Open Access Journals (Sweden)

    Xishi Tai

    2013-08-01

    Full Text Available A novel Ca(II coordination polymer, [CaL(4,4′-bipyridyl(H2O4]n (L = 1,6-naphthalenedisulfonate, was synthesized by reaction of calcium perchlorate with 1,6-naphthalenedisulfonic acid disodium salt and 4,4′-bipyridyl in CH3CH2OH/H2O. It was characterized by elemental analysis, IR, molar conductivity and thermogravimetric analysis. X-ray crystallography reveals that the Ca(II coordination polymer belongs to the orthorhombic system, with space group P212121. The geometry of the Ca(II ion is a distorted CaNO6 pengonal bipyramid, arising from its coordination by four water molecules, one nitrogen atom of 4,4′-bipyridyl molecule, and two oxygen atoms from two L ligands. The complex molecules form a helical chain by self-assembly. The antitumor activity of 1,6-naphthalenedisulfonic acid disodium salt and the Ca(II coordination polymer against human hepatoma smmc-7721 cell line and human lung adenocarcinoma A549 cell line reveals that the Ca(II coordination polymer inhibits cell growth of human lung adenocarcinoma A549 cell line with IC50 value of 27 μg/mL, and is more resistive to human lung adenocarcinoma A549 cell line as compared to 1,6-naphthalenedisulfonic acid disodium salt.

  20. Visualization of Metal-to-Ligand and Ligand-to-Ligand Charge Transfer in Metal-Ligand Complexes

    Institute of Scientific and Technical Information of China (English)

    Yong Ding; Jian-xiu Guo; Xiang-si Wang; Sha-sha Liu; Feng-cai Ma

    2009-01-01

    Three methods including the atomic resolved density of state, charge difference density, and the transition density matrix are used to visualize metal to ligand charge transfer (MLCT) in ruthenium(Ⅱ) ammine complex. The atomic resolved density of state shows that there is density of Ru on the HOMOs. All the density is localized on the ammine, which reveals that the excited electrons in the Ru complex are delocalized over the ammine ligand. The charge difference density shows that all the holes are localized on the Ru and the electrons on the ammine. The localization explains the MLCT on excitation. The transition density matrix shows that there is electron-hole coherence between Ru and ammine. These methods are also used to examine the MLCT in Os(bpy)(p0p)Cl ("Osp0p"; bpy=2,2'-bipyridyl; p0p=4,4'-bipyridyl) and the ligand-to-ligand charge transfer (LLCT) in Alq3. The calculated results show that these methods are powerful to examine MLCT and LLCT in the metal-ligand system.

  1. Fabrication of Copper(I) Bipyridyl Complex Based Dye Sensitized Solar Cells

    Science.gov (United States)

    Vuong, Son; Nguyen-Dang, Ha-My; Tran, Quang Thinh; Luong, Thi Thu Thuy; Pham, Trang T. T.; Nguyen-Tran, Thuat; Mai, Anh Tuan

    2017-01-01

    This study investigates the performance of dye-sensitized solar cells (DSSC) based on a copper(I) complex. A simple form of copper(I) complex dye was synthesized with a structure of [Cu(L)(CH3CN)], where L is the 6,6'-dimethyl-4,4'-bis(phenylethynyl)-2,2'-bipyridine ligand. The full structure of DSSC investigated in this study is as follows: FTO/TiO2/dye Cu(I) bipyridyl/3I-/I3 - electrolyte/graphite/FTO. The TiO2 photoanodes were deposited from apoly(vinylpyrrolidone)-based paste using a spin coating technique. Different conditions of fabrication, such as paste dispersion time and total TiO2 thickness, were systematically studied in order to optimize the performance of the DSSC. The trigonal planar complex [Cu(L)CH3CN] was revealed to be suitable for applications in DSSC. The highest exhibited short circuit current density was found to be 0.48 mA/cm2, with an open voltage of 477 mV, a form factor of 34% and a power conversion efficiency of 0.08% for the cell with photoanodes thickness of about 2.2 μm. It was shown that the dye and the paste formulation had great potential for applications in DSSC.

  2. Synthesis, spectroscopy and biological investigations of manganese(III) Schiff base complexes derived from heterocyclic β-diketone with various primary amine and 2,2'-bipyridyl

    Science.gov (United States)

    Surati, Kiran R.

    2011-06-01

    The mixed ligand mononuclear complex [Mn(bipy)(HPMFP)(OAc)]ClO 4 was synthesized by reaction of Mn(OAc) 3·2H 2O with HPMFP and 2,2'-bipyridyl. The corresponding Schiff base complexes were prepared by condensation of [Mn(bipy)(HPMFP)(OAc)]ClO 4 with ethylenediamine, ethanolamine and glycine (where HPMFP = 1-phenyl-3methyl-4-formyl-2-pyrazolin-5one, bipy = 2,2'-bipyridyl). All the compounds have been characterized by elemental analysis, magnetic susceptibility, conductometry measurements and 1H and 13C NMR, FT-IR, mass spectrometry. Electronic spectral and magnetic susceptibility measurements indicate square pyramidal geometry around manganese(III) ion. The thermal stabilities, activation energy E*, entropy change Δ S*, enthalpy change Δ H* and heat capacity of thermal degradation for these complexes were determined by TGA and DSC. The in vitro antibacterial and antifungal activity of four coordination compounds and ligand HPMFP were investigated. In vitro activates of Bacillus subtillis (MTCC-619), Staphylococcus aureus (MTCC-96), Escherichia coli (MTCC-722) and Klebsiella pneumonia (MTCC-109) bacteria and the fungus Candida albicans (ATCC-90028) were determined. All the compounds showed good antimicrobial activity. The antimicrobial activities increased as formation of Schiff base.

  3. Tris(2,2'-bipyridyl) Ruthenium(Ⅱ) Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties

    Institute of Scientific and Technical Information of China (English)

    WEI Hui; DU Yan; KANG Jian-Zhen; XU Guo-Bao; WANG Er-Kang

    2007-01-01

    An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis(bipyridyl)-4,4'-dicarboxy-2,2'-bipyridyl-ruthenium to (3-aminopropyl)-triethoxysilane.The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol-gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.

  4. The effects of nonionic surfactants on the tris(2,2'-bipyridyl)ruthenium(II)--tripropylamine electrochemiluminescence system.

    Science.gov (United States)

    Workman, S; Richter, M M

    2000-11-15

    The electrochemistry and electrogenerated chemiluminescence (ECL) of Ru(bpy)3(2+) (bpy = 2,2'-bipyridyl) were studied in the presence of the nonionic surfactants Triton X-100, Thesit, and Nonidet P40. The anodic oxidation of Ru(bpy)3(2+) produces ECL in the presence of tri-n-propylamine in both aqueous and surfactant solutions. Increases in both ECL efficiency (> or =8-fold) and duration of the ECL signal were observed in surfactant media. A shift to lower energies of the Ru(bpy)3(2+) ECL emission by approximately 8 nm was also observed. The one-electron oxidation of Ru(bpy)3(2+) to Ru(bpy)3(3t) occurs at + 1.03 V vs Ag/AgCl in aqueous buffered (0.2 M potassium phosphate) solution as found by square wave voltammetry. This potential did not shift in surfactant systems, indicating that the redshifts in ECL emission are due to stabilization of ligand pi* orbitals in the metal-to-ligand charge-transfer excited state. These results are consistent with hydrophobic interactions between Ru(bpy)3(2+) and the nonionic surfactants.

  5. Application of the perturbed angular correlation in the investigation of hyperfine interactions in compounds of hafnium, indium and cadmium with F{sup 1-}, OH{sup 1-} and EDTA ligands; Aplicacao da espectroscopia de correlacao angular perturbada na investigacao de interacoes hiperfinas em compostos de hafnio, indio e cadmio com os ligantes F{sup 1-}, OH{sup 1-} e EDTA

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Antonio Acleto

    2011-07-01

    In this study the hyperfine parameters, including the dynamical nature, Perturbed Angular Correlation (PAC) spectroscopy was used to measure the hyperfine parameters in molecules of ligand compounds in solutions. The measurements were carried out at 295 K and 77 K using {sup 111}In {yields} {sup 111}Cd, {sup 181}Hf {yields} {sup 181}Ta and {sup 111m}Cd {yields}{sup 111}Cd, as probe nuclei. Samples were prepared by adding a small volume of radioactive solution containing the probe nuclei in aqueous solution, buffer solution and ethylenediaminetetraacetic acid (EDTA) used as a ligand with pH 4.3 which correspond to the pH of the saturated EDTA solution and in buffer solution with pH between 9 and 10. The results made possible to understand the impact of each method for PAC measurements. Finally a comparative analysis for the several methods of inserting of the probe nuclei in the sample was made, considering chemical and nuclear aspects. The lack of measurements in this kind of samples justifies the importance of the obtained results. (author)

  6. Angular Momentum

    Science.gov (United States)

    Shakur, Asif; Sinatra, Taylor

    2013-01-01

    The gyroscope in a smartphone was employed in a physics laboratory setting to verify the conservation of angular momentum and the nonconservation of rotational kinetic energy. As is well-known, smartphones are ubiquitous on college campuses. These devices have a panoply of built-in sensors. This creates a unique opportunity for a new paradigm in…

  7. Synthesis, spectroscopic, electrochemical and luminescence studies of ruthenium (II) polypyridyls containing multifunctionalized 1,2,4-triazole as co-ligand

    Indian Academy of Sciences (India)

    L Mishra; A K Yadaw

    2000-08-01

    Ruthenium (II) 2,2 -bipyridyl and 1,10-phenanthroline complexes with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (LH2) as co-ligand were synthesised and characterized by elemental analysis, IR, UV/Vis, 1H NMR spectra and FAB-mass data. The electrochemical and luminescent properties of the complexes were also studied.

  8. Catalytic C-H imidation of aromatic cores of functional molecules: ligand-accelerated Cu catalysis and application to materials- and biology-oriented aromatics.

    Science.gov (United States)

    Kawakami, Takahiro; Murakami, Kei; Itami, Kenichiro

    2015-02-25

    Versatile imidation of aromatic C-H bonds was accomplished. In the presence of copper bromide and 6,6'-dimethyl-2,2'-bipyridyl, a range of aromatics, such as polycyclic aromatic hydrocarbons, aromatic bowls, porphyrins, heteroaromatics, and natural products, can be imidated by N-fluorobenzenesulfonimide. A dramatic ligand-accelerated copper catalysis and an interesting kinetic profile were uncovered.

  9. Effect of second ligand on the luminescence of Samarium (III) dibenzoylmethane complexes: Syntheses, crystal structures, thermal analysis and luminescence study

    Indian Academy of Sciences (India)

    Muhammad Idiris Saleh; Min Yee Choo; Tai Wei Chan; Mohd R Razali

    2015-12-01

    The ternary complexes of Sm(III) with dibenzoylmethane (dbm) were synthesized by introducing 1,10-phenanthroline (phen), 4,7-dimethyl-1,10-phenanthroline (dmphen), 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen), 4,7-diphenyl-1,10-phenanthroline (dpphen), 2,2-bipyridyl (bpy), 4,4’-dimethyl-2,2-bipyridyl (4,4-dmbpy), 5,5’-dimethyl-2,2-bipyridyl (5,5-dmbpy) and 4,4’-di-tert-butyl-2,2-bipyridyl (4,4-dtbbpy) as a second ligand. The complexes were isolated and characterized by elemental analysis (CHN), thermogravimetric analysis (TGA), IR spectroscopy, luminescence spectroscopy and single crystal X-ray diffraction. Structural study shows that in all complexes Sm(III) is in square antiprism geometry. All complexes emit strong luminescence under ultraviolet excitation. The strongest emission is at 643 nm which can be assigned for 4G5/2 to 6H9/2 transition, equivalent to energy of 15550 cm−1. The addition of the second ligand has increased the emission intensity of the complexes while the transition is maintained.

  10. Effect of methylene spacers on the spectral, electrochemical, and structural properties of bis(4,4'-disubstituted-2,2'-bipyridyl) ruthenium(II) dye analogues.

    Science.gov (United States)

    Lense, Sheri; Hardcastle, Kenneth I; MacBeth, Cora E

    2009-09-28

    Two new ruthenium complexes, [Ru(L1OMe)2(NCS)2] and [Ru(L2OMe)2(NCS)2] (where L1OMe = 2,2'-bipyridine-4,4'-di(methyl ethanoate) and L2OMe = 2,2'-bipyridine-4,4'-di(methyl propionate)), have been synthesized and characterized using spectroscopic and electrochemical techniques. The [Ru(L2OMe)2(NCS)2] complex has also been characterized by X-ray diffraction studies and reveals a distorted octahedral coordination geometry about the ruthenium center. Cyclic voltammetry studies of both complexes exhibit quasi-reversible Ru(II/III) couples and a number of ligand reduction events. The complex with one methylene spacer between the bipyridyl ligand and the methyl ester functional group, [Ru(L1OMe)2(NCS)2], was particularly unstable under reducing conditions. The properties of these complexes are compared with the ethyl ester analogue of the N3 photosensitizer [Ru(L0OEt)2(NCS)2].

  11. Ruthenium(II)- bipyridyl with extended -system: Improved thermo-stable sensitizer for efficient and long-term durable dye sensitized solar cells

    Indian Academy of Sciences (India)

    M Chandrasekharam; G Rajkumar; Ch Srinivasa Rao; T Suresh; P Y Reddy; Y Soujanya

    2011-09-01

    A new extended thermo-stable high molar extinction coefficient bipyridyl ruthenium(II) complex "cis-Ru(4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine)(Ln)(NCS)2 H101", where Ln = 4,4'-dicarboxylic acid-2,2'-bipyridine; was synthesized and characterized by 1H-NMR, FT-IR and ESI-MASS spectroscopes. The H101 sensitized solar cell constructed with an active area of 0.54 cm2 in combination with an ionic liquid electrolyte exhibited broader photocurrent action spectrum with solar-to-electric energy conversion efficiency () of 5.89 (JSC = 12.14 mA/cm2, VOC = 690 V, fill factor = 0.699) under Air Mass (AM) 1.5 sunlight, while the reference `cis-Ru(4,4'-dinonyl-2,2'-bipyridine)(Ln)(NCS)2', Z907 sensitized solar cell exhibited -value of 5.17% (JSC = 11.93 mA/cm2, VOC = 650 V, fill factor = 0.666). TGA analysis of H101 showed extended thermal-stability and under continuous light exposure and aging at 55°C, the DSSC retained 85% of its initial -value, while under comparable conditions Z907 sensitized solar cell retained 88%. As compared to 4,4'-dinonyl-2,2'-bipyridine in Z907, the new ancillary bipyridyl ligand `4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine’ in H101 shifts the absorption bands remarkably towards blue. The Density Functional Theory (DFT) and Time-Dependent DFT excited state calculations of the new sensitizer show that the first three HOMOs have t2g character with sizeable mixing from the NCS ligands with -bonding orbitals of 4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine. The LUMO is a *-orbital localized on the 4,4-dicarboxylic acid-2,2'-bipyridine and higher un-occupied frontier orbitals have *-combinations with 4,4'-bis(3,5-di-tert-butylphenyl)-2,2'-bipyridine.

  12. μ-4,4′-Bipyridyl-1:2κ2N:N′-methanol-2κO-tetrakis(tri-tert-butoxysilanethiolato-1κ4O,S;2κ2S-dizinc(II

    Directory of Open Access Journals (Sweden)

    Katarzyna Baranowska

    2008-05-01

    Full Text Available The title compound, [Zn2(C12H27O3SSi4(C10H8N2(CH4O], is a binuclear complex with the two ZnII atoms linked via a bridging 4,4′-bipyridyl ligand. One of the ZnII atoms is penta-coordinated by two O,S-chelating tri-tert-butoxysilanethiolate units and one N atom of a 4,4′-bipyridine ligand, and the other ZnII atom is tetrahedrally coordinated by two tri-tert-butoxysilanethiolate anions acting as monodentate S ligands, the methanol O atom and the other N atom of the 4,4′-bipyridine ligand. This non-symmetrical coordination induces twisting and bending in the 4,4′-bipyridine ligand and introduces chirality into the system. The crystal studied exhibits inversion twinning. One tert-butyl group is disordered approximately equally over two positions.

  13. Professional AngularJS

    CERN Document Server

    Karpov, Valeri

    2015-01-01

    A comprehensive guide to AngularJS, Google's open-source client-side framework for app development. Most of the existing guides to AngularJS struggle to provide simple and understandable explanations for more advanced concepts. As a result, some developers who understand all the basic concepts of AngularJS struggle when it comes to building more complex real-world applications. Professional AngularJS provides a thorough understanding of AngularJS, covering everything from basic concepts, such as directives and data binding, to more advanced concepts like transclusion, build systems, and auto

  14. Photocatalytic degradation of bromothymol blue with Ruthenium(II) bipyridyl complex in aqueous basic solution

    Science.gov (United States)

    Fui, Mark Lee Wun; Hang, Ng Kim; Arifin, Khuzaimah; Minggu, Lorna Jeffery; Kassim, Mohammad Bin

    2016-11-01

    Ru(II) bipyridyl photocatalyst with the formula, [Ru(bpy)2(o-CH3-bzpypz)](PF6)2] (Ru01) and [Ru(bpy)2(o-Cl-bzpypz)](PF6)2] (Ru02), where bpy = 2,2'-bipyridyl, o-CH3-bzpypz = (3-(pyridin-2-yl)-1H-pyrazol-1-yl)(o-tolyl)methanone and o-Cl-bzpypz = (2-chlorophenyl)(3-(pyridin-2-yl)-1H-pyrazol-1-yl)methanone, has been successfully synthesized and characterized on the basis of C, H, N elemental analysis, IR, UV-Vis and NMR spectroscopy. Both Ru(II) complexes showed Infrared stretching frequencies at 1742-1736 cm-1 v(C=O), 1605 cm-1 v(C=N) and 842-837 cm-1 v(PF). Full geometry optimization of the complex structures were carried out using DFT method with B3LYP exchange-correlation functional and 6-31G (d,p) basis-set for H, C, N, O and Cl; and LAN2LDZ basis set as effective core potential for the ruthenium centre. The highest-occupied molecular orbital (HOMO) energy levels of Ru01 and Ru02 are -5.63 and -5.55 eV, respectively. The photocatalytic properties of the Ru(II) complexes were evaluated by studying the degradation of aqueous bromothymol blue (BTB) under light illumination. The mechanisms are presented and discussed to highlight the role of the ruthenium complex in the degradation process.

  15. Rectification in tunneling junctions: 2,2'-bipyridyl-terminated n-alkanethiolates.

    Science.gov (United States)

    Yoon, Hyo Jae; Liao, Kung-Ching; Lockett, Matthew R; Kwok, Sen Wai; Baghbanzadeh, Mostafa; Whitesides, George M

    2014-12-10

    Molecular rectification is a particularly attractive phenomenon to examine in studying structure-property relationships in charge transport across molecular junctions, since the tunneling currents across the same molecular junction are measured, with only a change in the sign of the bias, with the same electrodes, molecule(s), and contacts. This type of experiment minimizes the complexities arising from measurements of current densities at one polarity using replicate junctions. This paper describes a new organic molecular rectifier: a junction having the structure Ag(TS)/S(CH2)11-4-methyl-2,2'-bipyridyl//Ga2O3/EGaIn (Ag(TS): template-stripped silver substrate; EGaIn: eutectic gallium-indium alloy) which shows reproducible rectification with a mean r(+) = |J(+1.0 V)|/|J(-1.0 V)| = 85 ± 2. This system is important because rectification occurs at a polarity opposite to that of the analogous but much more extensively studied systems based on ferrocene. It establishes (again) that rectification is due to the SAM, and not to redox reactions involving the Ga2O3 film, and confirms that rectification is not related to the polarity in the junction. Comparisons among SAM-based junctions incorporating the Ga2O3/EGaIn top electrode and a variety of heterocyclic terminal groups indicate that the metal-free bipyridyl group, not other features of the junction, is responsible for the rectification. The paper also describes a structural and mechanistic hypothesis that suggests a partial rationalization of values of rectification available in the literature.

  16. On Angular Momentum

    Science.gov (United States)

    Schwinger, J.

    1952-01-26

    The commutation relations of an arbitrary angular momentum vector can be reduced to those of the harmonic oscillator. This provides a powerful method for constructing and developing the properties of angular momentum eigenvectors. In this paper many known theorems are derived in this way, and some new results obtained. Among the topics treated are the properties of the rotation matrices; the addition of two, three, and four angular momenta; and the theory of tensor operators.

  17. Tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based electrochemiluminescence coupled with capillary zone electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jingwu [Department of Chemistry, Nanchang University, Nanchang 330031 (China)], E-mail: wangjingwu@ncu.edu.cn; Zhang Xiaojun; Pi Fangfang [Department of Chemistry, Nanchang University, Nanchang 330031 (China); Wang Xiaoxia [Graduate School of Engineering, University of Fukui, Fukui 910-8507 (Japan); Yang Nianjun [Diamond Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Central 2-13, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)], E-mail: nianjun.yang@iaf.fraunhofer.de

    2009-03-01

    Capillary zone electrophoresis (CZE) coupled with tris(2,2'-bipyridyl) ruthenium(II)-based end-column electrogenerated chemiluminescence (ECL) has been utilized to detect bisoprolol in drugs and tablets after its separation from metoprolol. Tetrahydrofuran was used as an additive in the running buffer to obtain the absolute ECL peak of bisoprolol. Bisoprolol reacts as a co-reactant in tris(2,2'-bipyridyl) ruthenium(II) ECL system. Under the optimized experimental conditions, bisoprolol was separated successfully and efficiently from metoprolol and other co-existed materials in tablets and urine samples. The ECL intensity of tris(2,2'-bipyridyl) ruthenium(II)-bisoprolol-based system is linear with the concentration of bisoprolol from 1.5 {mu}M to 0.3 mM with a detection limit of 0.3 {mu}M. Relative standard derivations of the ECL intensity are 2.58% for the detection of 15 {mu}M bisoprolol. This method is a simple, rapid, selective, and sensitive. It was applied successfully for the monitoring of bisoprolol in market available tablets and human urine samples.

  18. Synthesis and characterization of 6,6’-bis(2-hydroxyphenyl)-2,2’-bipyridine ligand and its interaction with ct-DNA

    Energy Technology Data Exchange (ETDEWEB)

    Selamat, Norhidayah; Heng, Lee Yook; Hassan, Nurul Izzaty; Karim, Nurul Huda Abd [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43650 Bangi, Selangor (Malaysia)

    2015-09-25

    The tetradentate ligand with four donor atoms OONN was synthesized. Bis(phenoxy)bipyridine ligand was prepared by Suzuki coupling reaction between 6,6’-dibromo-2,2’-bipyridyl and 2-hydroxyphenylboronic acid with presence of palladium (II) acetate. Bis(phenoxy)bipyridine ligand was also synthesized by demethylating of 6,6’-bis(2-methoxyphenyl)-2,2’-bipyridyl ligand through solvent free reaction using pyridine hydrocloride. The formation of both phenoxy and methoxy ligands was confirmed by {sup 1}H, 2D cosy and {sup 13}C NMR spectroscopy, ESI-MS spectrometry, FTIR spectroscopy. The purity of the ligand was confirmed by melting point. Binding studies of small molecules with DNA are useful to understand the reaction mechanism and to provide guidance for the application and design of new and more efficient drugs targeted to DNA. In this study, the binding interaction between the synthesized ligand with calf thymus-DNA (ct-DNA) has been investigated by UV/Vis DNA titration study. From the UV/Vis DNA study, it shows that bis(phenoxy)bipyridine ligand bind with ct-DNA via outside binding with binding contant K{sub b} = 1.19 × 10{sup 3} ± 0.08 M{sup −1}.

  19. Factors affecting the electrochemical regeneration of NADH by (2,2'-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: impact on their immobilization onto electrode surfaces.

    Science.gov (United States)

    Walcarius, Alain; Nasraoui, Rihab; Wang, Zhijie; Qu, Fengli; Urbanova, Veronika; Etienne, Mathieu; Göllü, Mehmet; Demir, Ayhan S; Gajdzik, Janine; Hempelmann, Rolf

    2011-08-01

    Complexes of the (2,2'-bipyridyl) (pentamethylcyclopentadienyl)-rhodium family ([Cp*Rh(bpy)Cl](+), which is actually hydrolyzed in the form of [Cp*Rh(bpy)H(2)O](2+) in aqueous medium) are suitable solution-phase mediators likely to regenerate nicotinamide cofactors associated to dehydrogenases involved in many biocatalytic applications. Their practical application as bioelectrocatalysts, e.g., in fine chemicals synthesis or biosensors, remains however restricted to their durable immobilization in an active form onto solid electrode surfaces. This paper reports some new observations on the electrocatalytic properties of this mediator towards NAD(+) reduction, notably the critical effect of pH and cofactor-to-mediator concentration ratio, and investigates the behavior of a series of ([Cp*Rh(bpy)Cl](+)) derivatives bearing various substituents on the bipyridine ligand in view of their subsequent integration in electrochemical bioreactors. It will be shown that such compounds containing S- or N- moieties (i.e., often used as precursors to functionalize electrode surfaces) lead to inactivation of the electrocatalyst because their interaction with the Rh center prevents the formation of the active rhodium hydride complex. It was thus necessary to find another strategy of immobilization, and we found that adsorption of [Cp*Rh(bpy)Cl](+) by π-stacking on single-walled carbon nanotubes is an effective mean to reach this goal, leading to efficient and stable catalytic responses for NAD(+) reduction. Preliminary electroenzymatic experiments in the presence of d-sorbitol dehydrogenase further point out the interest of this approach for bioelectrocatalysis purposes and provide the proof-of-concept for this immobilization strategy.

  20. Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Burkardt Matthias

    2015-01-01

    Full Text Available Definitions of orbital angular momentum based on Wigner distributions are used as a framework to discuss the connection between the Ji definition of the quark orbital angular momentum and that of Jaffe and Manohar. We find that the difference between these two definitions can be interpreted as the change in the quark orbital angular momentum as it leaves the target in a DIS experiment. The mechanism responsible for that change is similar to the mechanism that causes transverse single-spin asymmetries in semi-inclusive deep-inelastic scattering.

  1. Recurrence of angular cheilitis.

    Science.gov (United States)

    Ohman, S C; Jontell, M; Dahlen, G

    1988-08-01

    The incidence of recurrence of angular cheilitis following a successful antimicrobial treatment was studied in 48 patients. Clinical assessments including a microbial examination were carried out 8 months and 5 yr after termination of treatment. Eighty percent of the patients reported recurrence of their angular cheilitis on one or more occasions during the observation period. Patients with cutaneous disorders associated with dry skin or intraoral leukoplakia had an increased incidence of recrudescence. Neither the presence of denture stomatitis nor the type of microorganisms isolated from the original lesions of angular cheilitis, i.e. Candida albicans and/or Staphylococcus aureus, were associated with the number of recurrences. The present observations indicate that treatment of the majority of patients with angular cheilitis should be considered in a longer perspective than previously supposed, due to the short lasting therapeutic effects of the antimicrobial therapy.

  2. [Malignant angular cheilitis].

    Science.gov (United States)

    Seoane, J; Vázquez, J; Cazenave, A; de la Cruz Mera, A; Argila, F; Aguado, A

    1996-01-01

    A case of chronic angular cheilitis is reported. Candida albicans was isolated repeatedly and the process developed into epitheliomatous carcinoma. The etiopathogenic role of Candida albicans and possible mechanism of action are discussed.

  3. Angular Cheilitis Pada Anak

    OpenAIRE

    Gema Nazriyanti

    2008-01-01

    Angular cheilitis adalah inflamasi akut atau kronis pada sudut mulut yang ditandai dengan adanya flsur-fisur, retak-retak pada sudut bibir, berwarna kemerahan, mengalami ulserasi disertai rasa terbakar, nyeri dan rasa kering pada sudut mulut. Dapat mengenai orang tua, dewasa dan anak-anak. Banyak pendapat yang mengemukakan tentang etiologi dari angular cheilitis, antara lain defisiensi vitamin B kompleks, denture soremouth, defisiensi besi, kebiasaan bernafas melalui mulut, membasahi bib...

  4. Electronic structure and electro-optical properties of ion radicals formed during the reduction of N, N'-dialkylsubstituted salts of 4,4'-bipyridyl

    Science.gov (United States)

    Zakirov, M. I.; Efimov, N. N.; Mel'nikov, P. V.; Nodova, E. L.; Minin, V. V.

    2013-08-01

    Symmetric N, N'-disubstituted salts of 4,4'-bipyridyl (viologens) are synthesized and described. It is shown by cyclic voltammetry that disubstituted salts of 4,4'-bipyridyl have a tendency toward reversible two-electron reduction. Normal first and second step oxidation-reduction potentials with respect to saturated silver chloride electrodes at various potential scan rates are found. The spectra of the high-resolution electron paramagnetic resonance of viologen cation radicals formed during the reduction of N, N'-disubstituted salts of 4,4'-bipyridyl are obtained and interpreted. It is established that the nature of substitutes and counterions in a viologen molecule considerably influences the distribution of its spin density, voltammetric curves, and electro-optical properties.

  5. Cyclometalated platinum(II) with ethynyl-linked azobenzene ligands: an original switching mode.

    Science.gov (United States)

    Savel, Paul; Latouche, Camille; Roisnel, Thierry; Akdas-Kilig, Huriye; Boucekkine, Abdou; Fillaut, Jean-Luc

    2013-12-28

    The photophysical properties of 6-phenyl-2,2'-bipyridyl platinum(ii) complexes bearing different σ-alkynyl-linked azobenzene ancillary ligands were investigated. These complexes exhibited strong, broad, structureless charge-transfer bands in the visible region, which were red-shifted when the electron-donating ability of the para substituent on the azo-acetylide ligand increased. When excited at the charge-transfer absorption band, the complexes exhibited weak green emission, which was assigned to a triplet metal-to-ligand charge transfer/interligand charge transfer emission ((3)MLCT/(3)L'LCT). The presence of an amino substituent in the azobenzene moiety opened the possibility of protonation, which led to the formation of an azonium based derivative and resulted in drastic perturbations of the molecular orbitals and photophysical properties of the Pt-acetylide complex. These studies are fully supported by DFT and TD-DFT calculations.

  6. Optical orbital angular momentum

    Science.gov (United States)

    Barnett, Stephen M.; Babiker, Mohamed; Padgett, Miles J.

    2017-01-01

    We present a brief introduction to the orbital angular momentum of light, the subject of our theme issue and, in particular, to the developments in the 13 years following the founding paper by Allen et al. (Allen et al. 1992 Phys. Rev. A 45, 8185 (doi:10.1103/PhysRevA.45.8185)). The papers by our invited authors serve to bring the field up to date and suggest where developments may take us next. This article is part of the themed issue ‘Optical orbital angular momentum’. PMID:28069775

  7. Optical orbital angular momentum

    Science.gov (United States)

    Barnett, Stephen M.; Babiker, Mohamed; Padgett, Miles J.

    2017-02-01

    We present a brief introduction to the orbital angular momentum of light, the subject of our theme issue and, in particular, to the developments in the 13 years following the founding paper by Allen et al. (Allen et al. 1992 Phys. Rev. A 45, 8185 (doi:10.1103/PhysRevA.45.8185)). The papers by our invited authors serve to bring the field up to date and suggest where developments may take us next. This article is part of the themed issue 'Optical orbital angular momentum'.

  8. Induced Angular Momentum

    Science.gov (United States)

    Parker, G. W.

    1978-01-01

    Discusses, classically and quantum mechanically, the angular momentum induced in the bound motion of an electron by an external magnetic field. Calculates the current density and its magnetic moment, and then uses two methods to solve the first-order perturbation theory equation for the required eigenfunction. (Author/GA)

  9. "Angular" plasma cell cheilitis.

    Science.gov (United States)

    da Cunha Filho, Roberto Rheingantz; Tochetto, Lucas Baldissera; Tochetto, Bruno Baldissera; de Almeida, Hiram Larangeira; Lorencette, Nádia Aparecida; Netto, José Fillus

    2014-03-17

    Plasma cell cheilitis is an extremely rare disease, characterized by erythematous-violaceous, ulcerated and asymptomatic plaques, which evolve slowly. The histological characteristics include dermal infiltrate composed of mature plasmocytes. We report a case of Plasma cell angular cheilitis in a 58-year-old male, localized in the lateral oral commissure.

  10. "Angular" plasma cell cheilitis

    OpenAIRE

    da Cunha Filho, Roberto Rheingantz; Tochetto, Lucas Baldissera; Tochetto, Bruno Baldissera; de Almeida Jr, Hiram Larangeira; Lorencette, Nadia Aparecida; Netto, Jose Fillus

    2014-01-01

    Plasma cell cheilitis is an extremely rare disease, characterized by erythematous-violaceous, ulcerated and asymptomatic plaques, which evolve slowly. The histological characteristics include dermal infiltrate composed of mature plasmocytes. We report a case of Plasma cell angular cheilitis in a 58-year-old male, localized in the lateral oral commissure.

  11. Photophysical characterization of the interactions among tris(2,2'-bipyridyl)ruthenium(II) complexes ion-exchanged within zirconium phosphate.

    Science.gov (United States)

    Martí, Angel A; Colón, Jorge L

    2010-08-16

    We studied the structures, luminescence, and self-quenching properties of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)(3)(2+)) two-dimensional arrangements within the layers of zirconium phosphate (ZrP). The intercalation of Ru(bpy)(3)(2+) was accomplished using a hydrated form of zirconium phosphate ZrP. Varying the Ru(bpy)(3)(2+)/ZrP intercalation ratio, different Ru(bpy)(3)(2+)-exchanged ZrP loading levels were achieved. The ion exchange of Ru(bpy)(3)(2+) within ZrP produces a red shift in the metal-to-ligand charge-transfer (MLCT) absorption band of the complex from 452 nm in aqueous solution to 460 nm in ZrP. Steady state luminescence spectra of the Ru(bpy)(3)(2+)-exchanged ZrP materials show an increase in the luminescence intensity with an increase in the Ru(bpy)(3)(2+) loading level until about 0.77 M, where subsequent increases in the loading level produce a decrease in the luminescence (self-quenching region). Time-resolved luminescence measurements are consistent with the steady state luminescence measurements. Analysis of the time domain luminescence measurements in loadings higher than 0.77 M leads to the determination of a collisional quenching rate constant of (1.67 +/- 0.05) x 10(6) M(-1) s(-1). Stern-Volmer analysis of the luminescence quantum yield of Ru(bpy)(3)(2+)-exchanged ZrP materials indicates that static quenching is also involved in the Ru(bpy)(3)(2+) self-quenching mechanism. The quantum yield data behavior might be explained by a model that takes into account collisional quenching and the quasi-static Perrin mechanism. The calculation yields a quenching sphere of action of 14.8 A, which is slightly larger than the collisional radii of two Ru(bpy)(3)(2+) ions (12.2 A), as predicted by the model.

  12. Angular cheilitis after tonsillectomy.

    Science.gov (United States)

    England, R J; Lau, M; Ell, S R

    1999-08-01

    The operation of tonsillectomy requires the oral cavity to be held open mechanically in an unconscious patient, and intra-oral instrumentation to occur. Angular cheilitis may arise as a result of this after operation. This can cause morbidity and delay the re-establishment of a normal diet. The aim of this study was to identify what factors increase the likelihood of developing this problem postoperatively. Sixty patients were randomly selected in a prospective manner. Preoperative, intraoperative and postoperative variables were recorded. The frequency of development of postoperative angular cheilitis was recorded. The prevalence of the condition was related to the prerecorded variables. Parametric analysis showed that the chance of developing angular cheilitis was directly related to the use of diathermy haemostasis (P = 0.05). Logistic regression analysis showed that the odds ratio of developing this complication if diathermy was used is 3.5 (95% confidence intervals 0.99, 12.4) and operation difficulty may also be a relevant variable. No other recorded variables were found to be significant.

  13. Quantum Heuristics of Angular Momentum

    Science.gov (United States)

    Levy-Leblond, Jean-Marc

    1976-01-01

    Discusses the quantization of angular momentum components, Heisenberg-type inequalities for their spectral dispersions, and the quantization of the angular momentum modulus, without using operators or commutation relations. (MLH)

  14. Replacing the hydrogen in the intermolecular hydrogen bond of the cyanuric acid-bipyridyl adduct by Ag(I)

    Indian Academy of Sciences (India)

    K Sivashankar; Anupama Ranganathan; V R Pedireddi

    2000-04-01

    A complex between cyanuric acid (CA), 4,4′-bipyridyl (BP) and Ag(I), with the composition, [Ag2(C3H2N3O3-N)2 (C10H8N2-N)] has been prepared. Crystal structure analysis shows that it has a chain structure in which the CA molecules are linked to the BP units through silver atoms by the formation of N-Ag-N bonds, wherein one of the hydrogens of CA is replaced by Ag(I), showing thereby the chains connected to one another by N-H${\\ldots}$O hydrogen bonds formed between the CA molecules. This intermolecular chain structure resembles the chain structure of the CA.BP adduct where CA-BP-CA chains formed by N-H${\\ldots}$N hydrogen bonds are linked to one another by N-H${\\ldots}$O hydrogen bonds between the CA molecules.

  15. AngularJS directives

    CERN Document Server

    Vanston, Alex

    2013-01-01

    This book uses a practical, step-by-step approach, starting with how to build directives from the ground up before moving on to creating web applications comprised of multiple modules all working together to provide the best user experience possible.This book is intended for intermediate JavaScript developers who are looking to enhance their understanding of single-page web application development with a focus on AngularJS and the JavaScript MVC frameworks.It is expected that readers will understand basic JavaScript patterns and idioms and can recognize JSON formatted data.

  16. Electrogenerated chemiluminescence biosensor with alcohol dehydrogenase and tris(2,2'-bipyridyl)ruthenium (II) immobilized in sol-gel hybrid material.

    Science.gov (United States)

    Xu, Zhiai; Guo, Zhihui; Dong, Shaojun

    2005-09-15

    An ethanol biosensor based on electrogenerated chemiluminescence detection was developed. Electrogenerated chemiluminescence reagent tris(2,2'-bipyridyl)ruthenium (II) and alcohol dehydrogenase were immobilized in the same sol-gel hybrid film. The copolymer poly(vinyl alcohol) with 4-vinylpyridine and cation exchanger Nafion were incorporated into sol-gel film to provide the microenvironment for retaining the activity of enzyme and immobilize tris(2,2'-bipyridyl)ruthenium (II). The design was simpler than the previous two-layer format. The experimental conditions, such as scan rate, pH and concentration of the cofactor were investigated. The intensity of electrogenerated chemiluminescence increased linearly with ethanol concentration from 2.5x10(-5) to 5.0x10(-2) M and detection limit was 1.0x10(-5) M. The prepared biosensor exhibited high sensitivity, wide linear range and good stability.

  17. Orbital angular momentum microlaser

    Science.gov (United States)

    Miao, Pei; Zhang, Zhifeng; Sun, Jingbo; Walasik, Wiktor; Longhi, Stefano; Litchinitser, Natalia M.; Feng, Liang

    2016-07-01

    Structured light provides an additional degree of freedom for modern optics and practical applications. The effective generation of orbital angular momentum (OAM) lasing, especially at a micro- and nanoscale, could address the growing demand for information capacity. By exploiting the emerging non-Hermitian photonics design at an exceptional point, we demonstrate a microring laser producing a single-mode OAM vortex lasing with the ability to precisely define the topological charge of the OAM mode. The polarization associated with OAM lasing can be further manipulated on demand, creating a radially polarized vortex emission. Our OAM microlaser could find applications in the next generation of integrated optoelectronic devices for optical communications in both quantum and classical regimes.

  18. Detection of pyrrolizidine alkaloids using flow analysis with both acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence

    Energy Technology Data Exchange (ETDEWEB)

    Gorman, Bree A. [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia); Barnett, Neil W. [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia)]. E-mail: barnie@deakin.edu.au; Bos, Richard [School of Biological and Chemical Sciences, Deakin University, Geelong, Vic. 3217 (Australia)

    2005-06-13

    For the first time, analytically useful chemiluminescence was elicited from the reactions of the pyrrolizidine alkaloids. Heliotrine, retronecine, supinine, monocrotaline and echinatine N-oxide yielded chemiluminescence upon reaction with tris(2,2'-bipyridyl)ruthenium(II) whilst lasiocarpine, its N-oxide and supinine elicited light upon reaction with acidic potassium permanganate. Detection limits for heliotrine were 1.25 x 10{sup -7} M and 9 x 10{sup -9} M for tris(2,2'-bipyridyl)ruthenium(III) perchlorate with flow injection analysis (FIA) and the silica-immobilised reagent (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2,2'-bipyridine)bis (2,2'-bipyridyl)ruthenium(II) with sequential injection analysis (SIA), respectively. Lasiocarpine was detectable at 1.4 x 10{sup -7} M using acidic potassium permanganate with FIA. Additionally, the silica-immobilised reagent was optimised with respect to the oxidant (ammonium ceric nitrate) concentration and the aspiration times which afforded a detection limit for codeine of 5 x 10{sup -10} M using SIA.

  19. Photochemistry of RuII 4,4′-Bi-1,2,3-triazolyl (btz) Complexes: Crystallographic Characterization of the Photoreactive Ligand-Loss Intermediate trans-[Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)]2+

    Science.gov (United States)

    Welby, Christine E; Armitage, Georgina K; Bartley, Harry; Wilkinson, Aaron; Sinopoli, Alessandro; Uppal, Baljinder S; Rice, Craig R; Elliott, Paul I P

    2014-01-01

    We report the unprecedented observation and unequivocal crystallographic characterization of the meta-stable ligand loss intermediate solvento complex trans-[Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)]2+ (1 a) that contains a monodentate chelate ligand. This and analogous complexes can be observed during the photolysis reactions of a family of complexes of the form [Ru()(btz)2]2+ (1 a–d: btz=1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl; =a) 2,2′-bipyridyl (bpy), b) 4,4′-dimethyl-2,2′-bipyridyl (dmbpy), c) 4,4′-dimethoxy-2,2′-bipyridyl (dmeobpy), d) 1,10-phenanthroline (phen)). In acetonitrile solutions, 1 a–d eventually convert to the bis-solvento complexes trans-[Ru()(btz)(NCMe)2]2+ (3 a–d) along with one equivalent of free btz, in a process in which the remaining coordinated bidentate ligands undergo a new rearrangement such that they become coplanar. X-ray crystal structure of 3 a and 3 d confirmed the co-planar arrangement of the and btz ligands and the trans coordination of two solvent molecules. These conversions proceed via the observed intermediate complexes 2 a–d, which are formed quantitatively from 1 a–d in a matter of minutes and to which they slowly revert back on being left to stand in the dark over several days. The remarkably long lifetime of the intermediate complexes (>12 h at 40 °C) allowed the isolation of 2 a in the solid state, and the complex to be crystallographically characterized. Similarly to the structures adopted by complexes 3 a and d, the bpy and κ2-btz ligands in 2 a coordinate in a square-planar fashion with the second monodentate btz ligand coordinated trans to an acetonitrile ligand. PMID:24889966

  20. Angular integrals in d dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Somogyi, Gabor

    2011-01-15

    We discuss the evaluation of certain d dimensional angular integrals which arise in perturbative field theory calculations. We find that the angular integral with n denominators can be computed in terms of a certain special function, the so-called H-function of several variables. We also present several illustrative examples of the general result and briefly consider some applications. (orig.)

  1. Intrinsic Angular Momentum of Light.

    Science.gov (United States)

    Santarelli, Vincent

    1979-01-01

    Derives a familiar torque-angular momentum theorem for the electromagnetic field, and includes the intrinsic torques exerted by the fields on the polarized medium. This inclusion leads to the expressions for the intrinsic angular momentum carried by the radiation traveling through a charge-free medium. (Author/MA)

  2. Angular momentum of sound pulses.

    Science.gov (United States)

    Lekner, John

    2006-07-05

    Three-dimensionally localized acoustic pulses in an isotropic fluid medium necessarily have transverse components of momentum density. Those with an azimuthal component of momentum density can carry angular momentum. The component of total pulse angular momentum along the direction of the total momentum is an invariant (constant in time and independent of choice of origin). The pulse energy, momentum and angular momentum are evaluated analytically for a family of localized solutions of the wave equation. In the limit where the pulses have many oscillations within their spatial extent ([Formula: see text], where k is the wavenumber and a determines the size of a pulse), the energy, momentum and angular momentum are consistent with a multiphonon representation of the pulse, each phonon having energy [Formula: see text], momentum [Formula: see text] and angular momentum [Formula: see text] (with integer m).

  3. A Novel Cu (Ⅱ) Complex with 2,2'-Bipyridyl and L-Methioninate--Synthesis, Characterization, Molecular Structure and Stability

    Institute of Scientific and Technical Information of China (English)

    LE,Xue-Yi; TONG,Ming-Liang; FU,Yin-Lian; JI,Liang-Nian

    2003-01-01

    The ternary Cu(Ⅱ) complex with 2,2'-bipyridyl (bipy) and L-methioninate (L-Met) has been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis spectra, IR spectra aad pH-potentiometric titration methods. The structure of the comby the X-ray diffraction analysis. It crystallizes in the triclinic system, space group P1 with four molecules in a unit cell of dimensions, a = 0.7656(2) nm, b = 1.3142(3) nm, c = 2.0596(4) nm,α=97.70(3)°, β = 97.96(3)°, γ = 94.33(3)°, V= 2.0244(8)nm3, R1 = 0.0441 and wR2 = 0.0678. The crystal contains four crystallographically independent [ Cu(L-Met)(bipy)(H2O) ] +complexed (Cu1-Cu4), having a distorted square-pyramidal geometry with the same coordinated atoms around each copper center. The base plane is occupied by two nitrogen atoms of one bipy,the amino nitrogen atom and one carboxylate oxygen atom from each independent L-Met moiety, and one water oxygen at aa axial position. Cu1 and Cu3 are essentially enantiomers of Cu2 and Cu4.The four molecules are packed with each other by intermolecular hydrogen-bonding and aromatic-ring stacking interactions.

  4. Electrogenerated chemiluminescence: An oxidative-reductive mechanism between quinolone antibiotics and tris(2,2'-bipyridyl)ruthenium(II)

    Energy Technology Data Exchange (ETDEWEB)

    Burkhead, Matthew S.; Wang, Heeyoung; Fallet, Marcel [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States); Gross, Erin M. [Department of Chemistry, Creighton University, Omaha, NE 68178 (United States)], E-mail: eringross@creighton.edu

    2008-04-21

    The cyclic voltammetry and electrogenerated chemiluminescent (ECL) reactions of a series of quinolone and fluoroquinolone antibiotics were investigated in a flow injection analysis (FIA) system. 7-Piperazinyl fluoroquinolone antibiotics were found to participate as a coreactant in an oxidative-reductive ECL mechanism with tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy){sub 3}{sup 2+}) as the luminescent reagent. The reaction mechanism was investigated in order to understand and optimize the processes leading to light emission. The optimal conditions included a solution pH {approx}7 at a flow rate of 3.0 mL min{sup -1} with no added organic modifier and application of 1.2 V vs. a Pt quasi-reference electrode (QRE). Fluoroquinolones containing a tertiary distal nitrogen on the piperazine ring, such as enrofloxacin and ofloxacin, reacted to produce more intense ECL than those with a secondary nitrogen, such as ciprofloxacin and norfloxacin. The method linear range, precision, detection limits, and sensitivity for the detection of enrofloxacin and ciprofloxacin were compared to that of tripropylamine. The method was applied to the determination of the ciprofloxacin content in a pharmaceutical preparation. The assay is discussed in terms of its analytical figures of merit, ease of use, speed, accuracy and application to pharmaceutical samples.

  5. Polyoxomatelate functionalized tris(2,2-bipyridyl)dichlororuthenium(II) as the probe for electrochemiluminescence sensing of histamine.

    Science.gov (United States)

    An, Dong; Chen, Zhuqiu; Zheng, Jiachun; Chen, Siyuan; Wang, Li; Su, Wenjin

    2016-03-01

    A novel electrochemiluminescence (ECL) sensing system was developed to determine histamine in aquatic food with tris(2,2-bipyridyl)dichlororuthenium(II) (Ru(bpy)3(2+)) and Keggin-type polyoxomatelate (H3PMo12O40). A hybrid material was synthesized by mixing Keggin H3PMo12O40 (PMo12) and Ru(bpy)3(2+) and it was applied in capillary electrophoresis-electrochemiluminescence (CE-ECL) as a histamine probe for the first time. Some factors which affected the performances of separation and detection were investigated. Under the optimized conditions, one single quantitative analysis of histamine was achieved at a separation voltage of 16kV, and the limit of detection (LOD, S/N=3) of histamine was 1.0×10(-3)mg/L. The linear concentration range was between 0.01 and 1mg/L and the relative standard deviation (RSD) of peak height was between 0.27% and 1.29%, while the RSD of migration time was between 0.96% and 1.87%. The results indicated that the proposed probe presented good characteristics in terms of higher sensitivity and better reproducibility for histamine detection than those of the Ru(bpy)3(2+) ECL system.

  6. Electrogenerated chemiluminescence of tris (2,2'-bipyridyl)ruthenium(II) ion-exchanged in nafion-silica composite films

    Science.gov (United States)

    Khramov; Collinson

    2000-07-01

    The voltammetry and electrogenerated chemiluminescence (ECL) of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)3 2+) ion-exchanged in Nafion and Nafion-silica composite materials have been investigated. The major goal of this work was to investigate and develop new materials and immobilization approaches for the fabrication of ECL-based sensors with improved reactivity and long-term stability. Nation-silica composite materials with varying contents of Nation (53-100 wt% relative to silica) were prepared via the two-step acid/base hydrolysis and condensation of tetramethoxysilane. The Nafion doped sols were spin cast on glassy carbon electrodes, dried, and then ion-exchanged with Ru(bpy)3 2+. The shapes of the cyclic voltammetric curves and the amount of Ru(bpy)3 2+ exchanged into the films strongly depends on the amount of Nafion incorporated into the hybrid sol. Nafion-silica films with a low content of Nafion ion-exchanged less Ru(bpy)3 2+ and exhibited tail-shaped voltammetry at 100 mV/s. The ECL of immobilized Ru(bpy)3 2+ in the presence of either tripropylamine or sodium oxalate in pH 5 acetate buffer was also strongly dependent on the amount of Nafion introduced into the composite with greater ECL observed for the Nafion-silica films relative to pure Nafion.

  7. Electrochemiluminescence from tris(2,2′-bipyridyl) ruthenium (Ⅱ) in the presence of aminocarboxylic acid co-reactants

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Due to the highly sensitive electrochemiluminescence (ECL), tris(2,2′-bipyridyl) ruthenium(II) (Ru(bpy)32+) is often used in the field of bioarrays with the help of co-reactants. However, the generally used co-reactant, tripropylamine (TPA), is toxic, corrosive and volatile. Therefore, the search for safe, sensitive and economical co-reactants is critical. Herein, three aminocarboxylic acids, ethylenediamine-tetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and 2-hydroxyethylethylene diaminetriacetic acid (HEDTA), have been investigated as potential co-reactants for promoting Ru(bpy)32+ ECL behaviour. A possible ECL mechanism is also presented. The experimental results suggested that the co-reactants have a different ECL behaviour compared to TPA, such as different pH- and surfactant-responses. The detection limits of Ru(bpy)32+ using NTA, EDTA and HEDTA as co-reactants are 1, 60 and 680 fmol·L-1, respectively. The results indicate that NTA has a much higher efficiency than TPA to excite Ru(bpy)3 2+ ECL under their own optimal conditions. NTA could be widely used in many fields because it is less toxic, corrosive and volatile than TPA. Moreover, using Ru(bpy)3 2+ ECL, a sensitive method for the detection of aminocarboxylic acids is also developed. An improvement of four orders of magnitude in detection limits is obtained for EDTA compared to the known Ru(bpy) 3 2+ chemiluminescent methods.

  8. AngularJS testing cookbook

    CERN Document Server

    Bailey, Simon

    2015-01-01

    This book is intended for developers who have an understanding of the basic principles behind both AngularJS and test-driven development. You, as a developer, are interested in eliminating the fear related to either introducing tests to an existing codebase or starting out testing on a fresh AngularJS application. If you're a team leader or part of a QA team with the responsibility of ensuring full test coverage of an application, then this book is ideal for you to comprehend the full testing scope required by your developers. Whether you're new to or are well versed with AngularJS, this book

  9. Laser Detection Of Latent Fingerprints: Tris(2,2'-Bipyridyl)Ruthenium(II) Chloride Hexahydrate As A Staining Dye For Time-Resolved Imaging

    Science.gov (United States)

    Menzel, E. R.

    1988-04-01

    The compound tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate is suitable for laser detection of latent fingerprints on difficult surfaces such as wood and masking tape, as well as surfaces such as polyethylene, metal, etc. The fingerprint treatment can Involve either dusting with powder blended with this compound or by solution staining. The compound displays a strong d-n phosphorescence with a lifetime of about 10-6 and is thus very well suited for time-resolved imaging to suppress background fluorescence.

  10. Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Wenshan; Lukens, Wayne W.; Zi, Guofu; Maron, Laurent; Walter, Marc D.

    2012-01-12

    Bipyridyl thorium metallocenes [5-1,2,4-(Me3C)3C5H2]2Th(bipy) (1) and [5-1,3-(Me3C)2C5H3]2Th(bipy) (2) have been investigated by magnetic susceptibility and computational studies. The magnetic susceptibility data reveal that 1 and 2 are not diamagnetic, but they behave as temperature independent paramagnets (TIPs). To rationalize this observation, density functional theory (DFT) and complete active space SCF (CASSCF) calculations have been undertaken, which indicated that Cp2Th(bipy) has indeed a Th(IV)(bipy2-) ground state (f0d0 2, S = 0), but the open-shell singlet (f0d1 1, S = 0) (almost degenerate with its triplet congener) is lying only 9.2 kcal/mol higher in energy. Complexes 1 and 2 react cleanly with Ph2CS to give [ 5-1,2,4-(Me3C)3C5H2]2Th[(bipy)(SCPh2)] (3) and [ 5-1,3-(Me3C)2C5H3]2Th[(bipy)(SCPh2)] (4), respectively, in quantitative conversions. Since no intermediates were observed experimentally, this reaction was also studied computationally. Coordination of Ph2CS to 2 in its S = 0 ground state is not possible, but Ph2CS can coordinate to 2 in its triplet state (S = 1) upon which a single electron transfer (SET) from the (bipy2-) fragment to Ph2CS followed by C-C coupling takes place.

  11. Electrochemiluminescence from tris(2,2'-bipyridyl) ruthenium (Ⅱ) in the presence of aminocarboxylic acid co-reactants

    Institute of Scientific and Technical Information of China (English)

    YIN XueBo; SHA BeiBei; HE XiWen

    2009-01-01

    Due to the highly sensitive electrochemiluminescence (ECL),tris(2,2'-bipyridyl) ruthenium(Ⅱ) (Ru(bpy)32+)is often used in the field of bioarrays with the help of co-reactants.However,the generally used co-reactant,tripropylamine (TPA),is toxic,corrosive and volatile.Therefore,the search for safe,sensitive and economical co-reactants is critical.Herein,three aminocarboxylic acids,ethylenediaminetetraacetic acid (EDTA),nitrilotriacetic acid (NTA),and 2-hydroxyethylethylene diaminetriacetic acid (HEDTA),have been investigated as potential co-reactants for promoting Ru(bpy)32+ ECL behaviour.A possible ECL mechanism is also presented.The experimental results suggested that the co-reactants have a different ECL behaviour compared to TPA,such as different pH-and surfactant-responses.The detection limits of Ru(bpy)32+ using NTA,EDTA and HEDTA as co-reactants are 1,60 and 680 fmoI.L1,respectively.The results indicate that NTA has a much higher efficiency than TPA to excite Ru(bpy)32+ ECL under their own optimal conditions.NTA could be widely used in many fields because it is less toxic,corrosive and volatile than TPA.Moreover,using Ru(bpy)32+ ECL,a sensitive method for the detection of aminocarboxylic acids is also developed.An improvement of four orders of magnitude in detection limits is obtained for EDTA compared to the known Ru(bpy)32+ chemiluminescent methods.

  12. Instant AngularJS starter

    CERN Document Server

    Menard, Dan

    2013-01-01

    Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. This book is written in an easytoread style, with a strong emphasis on realworld, practical examples. Stepbystep explanations are provided for performing important tasks.This book is for web developers familiar with JavascriptIt doesn't cover the history of AngularJS, and it's not a pitch to convince you that AngularJS is the best framework on the entire web. It's a guide to help you learn everything you need to know about AngularJS in as few pa

  13. Angular momentum in human walking.

    Science.gov (United States)

    Herr, Hugh; Popovic, Marko

    2008-02-01

    Angular momentum is a conserved physical quantity for isolated systems where no external moments act about a body's center of mass (CM). However, in the case of legged locomotion, where the body interacts with the environment (ground reaction forces), there is no a priori reason for this relationship to hold. A key hypothesis in this paper is that angular momentum is highly regulated throughout the walking cycle about all three spatial directions [|Lt| approximately 0], and therefore horizontal ground reaction forces and the center of pressure trajectory can be explained predominantly through an analysis that assumes zero net moment about the body's CM. Using a 16-segment human model and gait data for 10 study participants, we found that calculated zero-moment forces closely match experimental values (Rx2=0.91; Ry2=0.90). Additionally, the centroidal moment pivot (point where a line parallel to the ground reaction force, passing through the CM, intersects the ground) never leaves the ground support base, highlighting how closely the body regulates angular momentum. Principal component analysis was used to examine segmental contributions to whole-body angular momentum. We found that whole-body angular momentum is small, despite substantial segmental momenta, indicating large segment-to-segment cancellations ( approximately 95% medio-lateral, approximately 70% anterior-posterior and approximately 80% vertical). Specifically, we show that adjacent leg-segment momenta are balanced in the medio-lateral direction (left foot momentum cancels right foot momentum, etc.). Further, pelvis and abdomen momenta are balanced by leg, chest and head momenta in the anterior-posterior direction, and leg momentum is balanced by upper-body momentum in the vertical direction. Finally, we discuss the determinants of gait in the context of these segment-to-segment cancellations of angular momentum.

  14. Non-Colinearity of Angular Velocity and Angular Momentum

    Science.gov (United States)

    Burr, A. F.

    1974-01-01

    Discusses the principles, construction, and operation of an apparatus which serves to demonstrate the non-colinearity of the angular velocity and momentum vectors as well as the inertial tensors. Applications of the apparatus to teaching of advanced undergraduate mechanics courses are recommended. (CC)

  15. Olympic Wrestling and Angular Momentum.

    Science.gov (United States)

    Carle, Mark

    1988-01-01

    Reported is the use of a wrestling photograph in a noncalculus introductory physics course. The photograph presents a maneuver that could serve as an example for a discussion on equilibrium, forces, torque, and angular motion. Provided are some qualitative thoughts as well as quantitative calculations. (YP)

  16. Plate tectonics conserves angular momentum

    Directory of Open Access Journals (Sweden)

    C. Bowin

    2009-03-01

    Full Text Available A new combined understanding of plate tectonics, Earth internal structure, and the role of impulse in deformation of the Earth's crust is presented. Plate accelerations and decelerations have been revealed by iterative filtering of the quaternion history for the Euler poles that define absolute plate motion history for the past 68 million years, and provide an unprecedented precision for plate angular rotation variations with time at 2-million year intervals. Stage poles represent the angular rotation of a plate's motion between adjacent Euler poles, and from which the maximum velocity vector for a plate can be determined. The consistent maximum velocity variations, in turn, yield consistent estimates of plate accelerations and decelerations. The fact that the Pacific plate was shown to accelerate and decelerate, implied that conservation of plate tectonic angular momentum must be globally conserved, and that is confirmed by the results shown here (total angular momentum ~1.4 E+27 kgm2s−1. Accordingly, if a plate decelerates, other plates must increase their angular momentums to compensate. In addition, the azimuth of the maximum velocity vectors yields clues as to why the "bend" in the Emperor-Hawaiian seamount trend occurred near 46 Myr. This report summarizes processing results for 12 of the 14 major tectonic plates of the Earth (except for the Juan de Fuca and Philippine plates. Plate accelerations support the contention that plate tectonics is a product of torques that most likely are sustained by the sinking of positive density anomalies due to phase changes in subducted gabbroic lithosphere at depth in the upper lower mantle (above 1200 km depth. The tectonic plates are pulled along by the sinking of these positive mass anomalies, rather than moving at near constant velocity on the crests of convection cells driven by rising heat. These results imply that spreading centers are primarily passive reactive

  17. Synthesis, characterization and crystal structure determination of Mn (II) ion based 1D polymer constructed from 2, 2′ bipyridyl and azide group, its thermal stability, magnetic properties and Hirshfeld surface analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mudsainiyan, R.K., E-mail: mudsainiyanrk@gmail.com; Jassal, Amanpreet Kaur; Chawla, S.K., E-mail: sukhvinder.k.chawla@gmail.com

    2015-05-15

    The 1-D polymeric complex (I) is having formula [Mn(2,2′-BP).(N{sub 3}){sub 2}]{sub n}, which has been crystallized in distilled water and characterized by elemental analyses, FT-IR spectrum, powder X-ray diffraction analyses and single-crystal diffraction analysis. This polymer possesses 1D helical chains or coils where Mn–azide–Mn forms the base of the coil which is alternatively garlanded by rigid bi-pyridine rings, where coordinates are in anti-fashion. The Mn (II) ions in the repeating units are linked by two end-on azide groups which extend through the two end-to-end azide ligands to the next unit forming a 1-D polymeric chain. The present study suggests that the use of this rigid and neutral building block leads to give better arrangement of the polymeric motif with [010] chains in 2-c uninodal net. During investigation of strong or weak intermolecular interactions, X-ray diffraction analysis and Hirshfeld surface analysis give rise to comparable results but in Hirshfeld surface analysis, two-third times more results of close contacts are obtained. The fingerprint plots demonstrate that these weak non-bonding interactions are important for stabilizing the crystal packing. Magnetic properties of the complex (I) were analyzed on the basis of an alternating ferro- and antiferromagnetic Heisenberg chain of Mn (II) ions. The J-exchange parameters found are J{sub 1}=64.3 K (45.3 cm{sup −1}), and J{sub 2}=−75.7 K (−53.3 cm{sup −1}). Magnetic properties are discussed in comparison with those of other similar molecular magnets of [Mn(L–L)(N{sub 3}){sub 2}]{sub n} type. - - Highlights: • Synthesized 1-D polymeric complex of Mn (II) ions with 2, 2′ bipyridyl and azide group. • X-ray data of complex (I) is in a good agreement with TGA and other spectroscopic techniques. • DFT calculations were done and compared with the parameter of experimental and theoretical data. • Intermolecular interactions calculated by Hirshfeld surface analysis

  18. Photochemistry of RuII 4,4'-bi-1,2,3-triazolyl (btz) complexes: crystallographic characterization of the photoreactive ligand-loss intermediate trans-[Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)]2+.

    Science.gov (United States)

    Welby, Christine E; Armitage, Georgina K; Bartley, Harry; Wilkinson, Aaron; Sinopoli, Alessandro; Uppal, Baljinder S; Rice, Craig R; Elliott, Paul I P

    2014-07-01

    We report the unprecedented observation and unequivocal crystallographic characterization of the meta-stable ligand loss intermediate solvento complex trans-[Ru(bpy)(κ(2) -btz)(κ(1) -btz)(NCMe)](2+) (1 a) that contains a monodentate chelate ligand. This and analogous complexes can be observed during the photolysis reactions of a family of complexes of the form [Ru({NN})(btz)(2)](2+) (1 a-d: btz=1,1'-dibenzyl-4,4'-bi-1,2,3-triazolyl; {NN}=a) 2,2'-bipyridyl (bpy), b) 4,4'-dimethyl-2,2'-bipyridyl (dmbpy), c) 4,4'-dimethoxy-2,2'-bipyridyl (dmeobpy), d) 1,10-phenanthroline (phen)). In acetonitrile solutions, 1 a-d eventually convert to the bis-solvento complexes trans-[Ru({NN})(btz)(NCMe)(2)](2+) (3 a-d) along with one equivalent of free btz, in a process in which the remaining coordinated bidentate ligands undergo a new rearrangement such that they become coplanar. X-ray crystal structure of 3 a and 3 d confirmed the co-planar arrangement of the {NN} and btz ligands and the trans coordination of two solvent molecules. These conversions proceed via the observed intermediate complexes 2 a-d, which are formed quantitatively from 1 a-d in a matter of minutes and to which they slowly revert back on being left to stand in the dark over several days. The remarkably long lifetime of the intermediate complexes (>12 h at 40 °C) allowed the isolation of 2 a in the solid state, and the complex to be crystallographically characterized. Similarly to the structures adopted by complexes 3 a and d, the bpy and κ(2) -btz ligands in 2 a coordinate in a square-planar fashion with the second monodentate btz ligand coordinated trans to an acetonitrile ligand.

  19. Phonons with orbital angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Ayub, M. K. [Theoretical Plasma Physics Division, PINSTECH, P. O. Nilore, Islamabad (Pakistan); National Centre for Physics, Shahdra Valley Road, Quaid-i-Azam University Campus, Islamabad 44000 (Pakistan); Ali, S. [National Centre for Physics, Shahdra Valley Road, Quaid-i-Azam University Campus, Islamabad 44000 (Pakistan); Mendonca, J. T. [IPFN, Instituto Superior Tecnico, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal)

    2011-10-15

    Ion accoustic waves or phonon modes are studied with orbital angular momentum (OAM) in an unmagnetized collissionless uniform plasma, whose constituents are the Boltzmann electrons and inertial ions. For this purpose, we have employed the fluid equations to obtain a paraxial equation in terms of ion density perturbations and discussed its Gaussian beam and Laguerre-Gauss (LG) beam solutions. Furthermore, an approximate solution for the electrostatic potential problem is presented, allowing to express the components of the electric field in terms of LG potential perturbations. The energy flux due to phonons is also calculated and the corresponding OAM is derived. Numerically, it is shown that the parameters such as azimuthal angle, radial and angular mode numbers, and beam waist, strongly modify the profiles of the phonon LG potential. The present results should be helpful in understanding the phonon mode excitations produced by Brillouin backscattering of laser beams in a uniform plasma.

  20. Angular momentum in QGP holography

    Directory of Open Access Journals (Sweden)

    Brett McInnes

    2014-10-01

    Full Text Available The quark chemical potential is one of the fundamental parameters describing the quark–gluon plasma produced by sufficiently energetic heavy-ion collisions. It is not large at the extremely high temperatures probed by the LHC, but it plays a key role in discussions of the beam energy scan programmes at the RHIC and other facilities. On the other hand, collisions at such energies typically (that is, in peripheral collisions give rise to very high values of the angular momentum density. Here we explain that holographic estimates of the quark chemical potential of a rotating sample of plasma can be very considerably improved by taking the angular momentum into account.

  1. The integration of angular velocity

    CERN Document Server

    Boyle, Michael

    2016-01-01

    A common problem in physics and engineering is determination of the orientation of an object given its angular velocity. When the direction of the angular velocity changes in time, this is a nontrivial problem involving coupled differential equations. Several possible approaches are examined, along with various improvements over previous efforts. These are then evaluated numerically by comparison to a complicated but analytically known rotation that is motivated by the important astrophysical problem of precessing black-hole binaries. It is shown that a straightforward solution directly using quaternions is most efficient and accurate, and that the norm of the quaternion is irrelevant. Integration of the generator of the rotation can also be made roughly as efficient as integration of the rotation. Both methods will typically be twice as efficient naive vector- or matrix-based methods. Implementation by means of standard general-purpose numerical integrators is stable and efficient, so that such problems can ...

  2. AngularJS test-driven development

    CERN Document Server

    Chaplin, Tim

    2015-01-01

    This book is for developers who want to learn about AngularJS development by applying testing techniques. You are assumed to have a basic knowledge and understanding of HTML, JavaScript, and AngularJS.

  3. Antioxidant activities of nano-bubble hydrogen-dissolved water assessed by ESR and 2,2′-bipyridyl methods

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Shinya [Laboratory of Cell-Death Control BioTechnology, Faculty of Life and Environmental Sciences, Prefectural University of Hiroshima, Nanatsuka 562, Shobara, Hiroshima 727-0023 (Japan); Radio Isotope Facilities for Medical Science, Life Science Research Center, Mie University, Edobashi 2-174, Tsu, Mie 514-8507 (Japan); Matsuoka, Daigo [− 600 mV Co., Ltd. Matsuhama-cho 2-4-1, Fukuyama, Hiroshima 720-0802 (Japan); Miwa, Nobuhiko, E-mail: miwa@butsuryo.ac.jp [Laboratory of Cell-Death Control BioTechnology, Faculty of Life and Environmental Sciences, Prefectural University of Hiroshima, Nanatsuka 562, Shobara, Hiroshima 727-0023 (Japan); Department of Radiological Technology, Faculty of Health Sciences, Butsuryo College of Osaka, Otorikitamachi 3-33, Nishi-ku, Sakai, Osaka 593-8328 (Japan)

    2015-08-01

    We prepared nano-bubble hydrogen-dissolved water (nano-H water) which contained hydrogen nano-bubbles of < 717-nm diameter for 54% of total bubbles. In the DMPO-spin trap electron spin resonance (ESR) method, the DMPO-OH:MnO ratio, being attributed to amounts of hydroxyl radicals (·OH), was 2.78 for pure water (dissolved hydrogen [DH] ≤ 0.01 ppm, oxidation-reduction potential [ORP] = + 324 mV), 2.73 for tap water (0.01 ppm, + 286 mV), 2.93 for commercially available hydrogen water (0.075 ppm, + 49 mV), and 2.66 for manufactured hydrogen water (0.788 ppm, − 614 mV), whereas the nano-H water (0.678 ppm, − 644 mV) exhibited 2.05, showing the superiority of nano-H water to other types of hydrogen water in terms of ·OH-scavenging activity. Then, the reduction activity of nano-H water was assessed spectrophotometrically by the 2,2′-bipyridyl method. Differential absorbance at 530 nm was in the order: 0.018 for pure water, 0.055 for tap water, 0.079 for nano-H water, 0.085 for commercially available hydrogen water, and 0.090 for manufactured hydrogen water, indicating a prominent reduction activity of hydrogen water and nano-H water against oxidation in ascorbate-coupled ferric ion–bipyridyl reaction. Thus, nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level, indicating the more marked importance of nano-bubbles rather than the concentration of hydrogen in terms of ·OH-scavenging. - Highlights: • We assessed the antioxidant activity of nano-bubble hydrogen-dissolved water (nano-H water). • Nano-H water exhibited superior ·OH-scavenging activity in DMPO-spin trap ESR. • A reduction ability of nano-H water was shown in 2,2′-bipyridyl reaction. • Nano-H water has an improved antioxidant activity as compared to hydrogen water of similar DH-level. • Results indicated the importance of nano-bubbles rather than the concentration of hydrogen.

  4. Optical angular momentum in dispersive media

    CERN Document Server

    Philbin, T G

    2012-01-01

    The angular momentum density and flux of light in a dispersive, rotationally symmetric medium are derived from Noether's theorem. Optical angular momentum in a dispersive medium has no simple relation to optical linear momentum, even if the medium is homogeneous. A circularly polarized monochromatic beam in a homogeneous, dispersive medium carries a spin angular momentum per unit energy of $\\pm\\omega^{-1}$, as in vacuum. This result demonstrates the non-trivial interplay of dispersive contributions to optical angular momentum and energy.

  5. AngularJS web application development

    CERN Document Server

    Darwin, Peter Bacon

    2013-01-01

    The book will be a step-by-step guide showing the readers how to build a complete web app with AngularJSJavaScript developers who want to learn AngularJS for developing web apps. Knowledge of JavaScript and HTML is expected. No knowledge of AngularJS is required.

  6. The layered compound poly[mu2-4,4'-bipyridyl-di-mu2-chlorido-mercury(II)].

    Science.gov (United States)

    Xie, Yi-Ming; Wu, Ji-Huai

    2007-05-01

    The title compound, [HgCl2(C(10)H(8)N(2))]n, features two-dimensional [HgCl2(4,4'-bipy)]n neutral networks (4,4'-bipy is 4,4'-bipyridine), based on an octahedral Hg atom coordinated by four mu2-Cl atoms and two mu2-4,4'-bipy ligands in trans positions, yielding a HgCl(4)N(2) octahedron. The structure has mmm symmetry about the Hg atoms, with most of the atoms on at least one mirror plane, but the unsubstituted C atoms of the 4,4'-bipy rings are disordered across a mirror plane. Photoluminescent investigations reveal that the title compound displays a strong emission in the green region, which probably originates from a ligand-to-ligand charge-transfer transition.

  7. Specific solvent effects of linear alcohols on the emission spectrum and the excited state decay of tris(2,2'-bipyridyl) ruthenium(I)

    Science.gov (United States)

    Hartmann, Paul; Leiner, Marc J. P.; Draxler, Sonja; Lippitsch, Max E.

    1996-06-01

    This study aims at a quantitative extraction of specific solvent effects of hydroxylic solvents on the non-radiative decay of tris(2,2'-bipyridyl) ruthenium(II). For this purpose the emission spectra, quantum yields and excited state lifetimes of the dye were measured in a series of monovalent linear alcohols. Separation of the non-radiative decay via the energy gap was achieved by evaluating the temperature dependence of quantum yields to account for temperature-activated transitions. The parameters determining the shapes of the emission spectra were calculated by a modified Franck-Condon analysis including the anharmonic Morse potential, and correlated with the non-radiative rate with the help of the energy gap law. The specific effects of hydroxylic solvents were finally obtained by comparison with the well-known behavior in non-hydroxylic solvents, and interpreted with the help of the energy gap law theory.

  8. Magnetically modified single and turbostratic stacked graphenes from tris(2,2'-bipyridyl) iron(II) ion-exchanged graphite oxide.

    Science.gov (United States)

    Szabó, Tamás; Bakandritsos, Aristides; Tzitzios, Vassilis; Devlin, Eamonn; Petridis, Dimitris; Dékány, Imre

    2008-11-20

    Loading of graphite oxide (GO) with tris(2,2'-bipyridyl) iron(II) ions and subsequent calcination affords a novel graphene-based composite with magnetic and electrically conductive properties. The pH of the starting aqueous suspension and the washing procedure play a crucial role in the successful immobilization of the iron precursor, which is mainly governed by ion exchange. The complex is intercalated between the graphene oxide layers, where it adopts a distorted conformation. Rapid heating of this solid results in the deflagration of GO and the formation of ultrafine ( d = 2-14 nm) Fe2O3 particles with maghemite as the dominant phase. The superparamagnetic maghemite crystals are dispersed uniformly in the high-surface-area diamagnetic matrix built up from single or turbostratic stacked graphenes.

  9. Structure and spectroscopic properties of ruthenium(II) bipyridyl N-benzoyl-N'-(1,10-phenanthrolin-5-Yl)-thiourea

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Siew San [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Kassim, Mohammad B. [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2015-09-25

    Ruthenium bipyridyl incorporating phenanthroline with thiourea molecules, [Ru(bpy){sub 2}(Phen-BT)](PF{sub 6}){sub 2}], has been synthesized and characterized by spectroscopic and electrochemical techniques. The infrared spectra of the complex shows the characteristics stretching frequencies for N-H at 3646 and 3585 cm{sup −1}, ν(C-N){sub phen} 1426 cm{sup −1}, ν(C=O) 1675 cm{sup −1}, ν(C=S) 1246 cm{sup −1}, ν(C-H){sub aromatic} 3353-3086 cm{sup −1}, ν(C-N){sub aliphatic} 1169-1026 cm{sup −1}, ν(C-H){sub bend} 764 cm{sup −1} and ν(PF{sub 6}{sup −}){sub free} 842 cm{sup −1}. The complex reveals two π→π* absorption bands at 237 (ε=26,302) and 286 nm (ε=36,848), which were assigned to the phenanthroline and bipyridyl moieties, respectively. A slightly broad and low energy band in the UV-vis spectrum at 450 nm (ε=7,209) of the complex was assigned to a MLCT transition. Besides, the complex also exhibits an emission band at 615 nm that arises from an excitation with a 440 nm light energy. The cyclic voltammetry of the complex shows an oxidation potential at +1.305 V vs. SCE that corresponds to the formal oxidation of Ru(II) to Ru(III)

  10. Two-axis angular effector

    Energy Technology Data Exchange (ETDEWEB)

    Vaughn, Mark R. (Albuquerque, NM); Robinett, III, Rush D. (Tijeras, NM); Phelan, John R. (Albuquerque, NM); Van Zuiden, Don M. (Albuquerque, NM)

    1997-01-21

    A new class of coplanar two-axis angular effectors. These effectors combine a two-axis rotational joint analogous to a Cardan joint with linear actuators in a manner to produce a wider range of rotational motion about both axes defined by the joint. This new class of effectors also allows design of robotic manipulators having very high strength and efficiency. These effectors are particularly suited for remote operation in unknown surroundings, because of their extraordinary versatility. An immediate application is to the problems which arise in nuclear waste remediation.

  11. Two-axis angular effector

    Energy Technology Data Exchange (ETDEWEB)

    Vaughn, M.R.; Robinett, R.D. III; Phelan, J.R.; Zuiden, D.M. Van

    1997-01-21

    A new class of coplanar two-axis angular effectors is described. These effectors combine a two-axis rotational joint analogous to a Cardan joint with linear actuators in a manner to produce a wider range of rotational motion about both axes defined by the joint. This new class of effectors also allows design of robotic manipulators having very high strength and efficiency. These effectors are particularly suited for remote operation in unknown surroundings, because of their extraordinary versatility. An immediate application is to the problems which arise in nuclear waste remediation. 11 figs.

  12. Syntheses, structures and properties of three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jiancai; Zhang, Yudong; Shang, Sensen; Li, Yanzhou; Chen, Lijuan, E-mail: ljchen@henu.edu.cn; Zhao, Junwei, E-mail: zhaojunwei@henu.edu.cn

    2015-01-15

    Three new metal–organic complexes Cu[Hbpdc]{sub 2} (1), [Ni(bpdc)(H{sub 2}O)]·H{sub 2}O (2) and [Ni(H{sub 2}bpdc)(H{sub 2}O){sub 2}]SO{sub 4} (3) (H{sub 2}bpdc=2,2′-bipyridyl-5,5′-dicarboxylic acid) have been hydrothermally prepared and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 is a 3-D supramolecular architecture formed by hydrogen bonding interactions between carboxyl O atoms and strong face-to-face π⋯π stacking interactions between bipyridyl rings of Hbpdc{sup −} ligands, 2 exhibits an intriguing 2-D sheet constructed from [Ni(bpdc)(H{sub 2}O)] units and 3 displays an infinite 1-D chain built by ([Ni(H{sub 2}bpdc)(H{sub 2}O){sub 2}]{sup 2+}) fragments through SO{sub 4}{sup 2−}. Moreover, thermogravimetric (TG) and derivative thermogravimetric (DTG) analyses of 3 have been conducted and the TG curve shows two-stage weight loss between 300 and 950 K and the corresponding apparent activation energies are calculated by Ozawa–Flynn–Wall (OFW) method and Friedman method. The most probable kinetic model function of the dehydration reaction of 3 has been estimated by Coats–Redfern integral method and Achar–Bridly–Sharp differential method. - Graphical abstract: Three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands were synthesized and the thermal decomposition kinetics were investigated. - Highlights: • Metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands. • 3-D supramolecular architecture. • Thermal decomposition kinetics.

  13. Transverse and longitudinal angular momenta of light

    CERN Document Server

    Bliokh, Konstantin Y

    2015-01-01

    We review basic physics and novel types of optical angular momentum. We start with a theoretical overview of momentum and angular momentum properties of generic optical fields, and discuss methods for their experimental measurements. In particular, we describe the well-known longitudinal (i.e., aligned with the mean momentum) spin and orbital angular momenta in polarized vortex beams. Then, we focus on the transverse (i.e., orthogonal to the mean momentum) spin and orbital angular momenta, which were recently actively discussed in theory and observed in experiments. First, the recently-discovered transverse spin angular momenta appear in various structured fields: evanescent waves, interference fields, and focused beams. We show that there are several kinds of transverse spin angular momentum, which differ strongly in their origins and physical properties. We describe extraordinary features of the transverse optical spins and overview recent experiments. In particular, the helicity-independent transverse spin...

  14. Oral candidiasis and angular cheilitis.

    Science.gov (United States)

    Sharon, Victoria; Fazel, Nasim

    2010-01-01

    Candidiasis, an often encountered oral disease, has been increasing in frequency. Most commonly caused by the overgrowth of Candida albicans, oral candidiasis can be divided into several categories including acute and chronic forms, and angular cheilitis. Risk factors for the development of oral candidiasis include immunosuppression, wearing of dentures, pharmacotherapeutics, smoking, infancy and old age, endocrine dysfunction, and decreased salivation. Oral candidiasis may be asymptomatic. More frequently, however, it is physically uncomfortable, and the patient may complain of burning mouth, dysgeusia, dysphagia, anorexia, and weight loss, leading to nutritional deficiency and impaired quality of life. A plethora of antifungal treatments are available. The overall prognosis of oral candidiasis is good, and rarely is the condition life threatening with invasive or recalcitrant disease.

  15. Angular Distributions as Lifetime Probes

    CERN Document Server

    Dror, Jeff Asaf

    2013-01-01

    If new TeV scale particles are discovered, it will be important to determine their width. There is, however, a problematic region, where the width is too small to be determined directly, and too large to generate a secondary vertex. For a collection of colored, spin polarized particles, hadronization depolarizes the particles prior to their decay. The amount of depolarization can be used to probe the lifetime in the problematic region. In this paper we apply this method to a realistic scenario of a top-like particle that can be produced at the LHC. We study how depolarization affects the angular distributions of the decay products and derive an equation for the distributions that is sensitive to the lifetime.

  16. Chirality and the angular momentum of light

    Science.gov (United States)

    Cameron, Robert P.; Götte, Jörg B.; Barnett, Stephen M.; Yao, Alison M.

    2017-02-01

    Chirality is exhibited by objects that cannot be rotated into their mirror images. It is far from obvious that this has anything to do with the angular momentum of light, which owes its existence to rotational symmetries. There is nevertheless a subtle connection between chirality and the angular momentum of light. We demonstrate this connection and, in particular, its significance in the context of chiral light-matter interactions. This article is part of the themed issue 'Optical orbital angular momentum'.

  17. A Novel Permanent Magnetic Angular Acceleration Sensor

    OpenAIRE

    Hao Zhao; Hao Feng

    2015-01-01

    Angular acceleration is an important parameter for status monitoring and fault diagnosis of rotary machinery. Therefore, we developed a novel permanent magnetic angular acceleration sensor, which is without rotation angle limitations and could directly measure the instantaneous angular acceleration of the rotating system. The sensor rotor only needs to be coaxially connected with the rotating system, which enables convenient sensor installation. For the cup structure of the sensor rotor, it h...

  18. Magnetic Modulation of Stellar Angular Momentum Loss

    CERN Document Server

    Garraffo, Cecilia; Cohen, Ofer

    2014-01-01

    Angular Momentum Loss is important for understanding astrophysical phenomena such as stellar rotation, magnetic activity, close binaries, and cataclysmic variables. Magnetic breaking is the dominant mechanism in the spin down of young late-type stars. We have studied angular momentum loss as a function of stellar magnetic activity. We argue that the complexity of the field and its latitudinal distribution are crucial for angular momentum loss rates. In this work we discuss how angular momentum is modulated by magnetic cycles, and how stellar spin down is not just a simple function of large scale magnetic field strength.

  19. Transverse and longitudinal angular momenta of light

    Energy Technology Data Exchange (ETDEWEB)

    Bliokh, Konstantin Y., E-mail: k.bliokh@gmail.com [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Nonlinear Physics Centre, RSPhysE, The Australian National University, Canberra, ACT 0200 (Australia); Nori, Franco [Center for Emergent Matter Science, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Physics Department, University of Michigan, Ann Arbor, MI 48109-1040 (United States)

    2015-08-26

    We review basic physics and novel types of optical angular momentum. We start with a theoretical overview of momentum and angular momentum properties of generic optical fields, and discuss methods for their experimental measurements. In particular, we describe the well-known longitudinal (i.e., aligned with the mean momentum) spin and orbital angular momenta in polarized vortex beams. Then, we focus on the transverse (i.e., orthogonal to the mean momentum) spin and orbital angular momenta, which were recently actively discussed in theory and observed in experiments. First, the recently-discovered transverse spin  angular momenta appear in various structured fields: evanescent waves, interference fields, and focused beams. We show that there are several kinds of transverse spin angular momentum, which differ strongly in their origins and physical properties. We describe extraordinary features of the transverse optical spins and overview recent experiments. In particular, the helicity-independent transverse spin inherent in edge evanescent waves offers robust spin–direction coupling at optical interfaces (the quantum spin Hall effect of light). Second, we overview the transverse orbital angular momenta of light, which can be both extrinsic and intrinsic. These two types of the transverse orbital angular momentum are produced by spatial shifts of the optical beams (e.g., in the spin Hall effect of light) and their Lorentz boosts, respectively. Our review is underpinned by a unified theory of the angular momentum of light based on the canonical momentum and spin densities, which avoids complications associated with the separation of spin and orbital angular momenta in the Poynting picture. It allows us to construct a comprehensive classification of all known optical angular momenta based on their key parameters and main physical properties.

  20. Charge transfer interactions of a Ru(II) dye complex and related ligand molecules adsorbed on Au(111)

    Energy Technology Data Exchange (ETDEWEB)

    Britton, Andrew J.; Weston, Matthew; O' Shea, James N. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Nottingham Nanotechnology and Nanoscience Centre (NNNC), University of Nottingham, Nottingham NG7 2RD (United Kingdom); Taylor, J. Ben; Rienzo, Anna; Mayor, Louise C. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)

    2011-10-28

    The interaction of the dye molecule, N3 (cis-bis(isothiocyanato)bis(2,2{sup '}-bipyridyl-4,4{sup '}-dicarboxylato) -ruthenium(II)), and related ligand molecules with a Au(111) surface has been studied using synchrotron radiation-based electron spectroscopy. Resonant photoemission spectroscopy (RPES) and autoionization of the adsorbed molecules have been used to probe the coupling between the molecules and the substrate. Evidence of charge transfer from the states near the Fermi level of the gold substrate into the lowest unoccupied molecular orbital (LUMO) of the molecules is found in the monolayer RPES spectra of both isonicotinic acid and bi-isonicotinic acid (a ligand of N3), but not for the N3 molecule itself. Calibrated x-ray absorption spectroscopy and valence band spectra of the monolayers reveals that the LUMO crosses the Fermi level of the surface in all cases, showing that charge transfer is energetically possible both from and to the molecule. A core-hole clock analysis of the resonant photoemission reveals a charge transfer time of around 4 fs from the LUMO of the N3 dye molecule to the surface. The lack of charge transfer in the opposite direction is understood in terms of the lack of spatial overlap between the {pi}*-orbitals in the aromatic rings of the bi-isonicotinic acid ligands of N3 and the gold surface.

  1. Ligand modeling and design

    Energy Technology Data Exchange (ETDEWEB)

    Hay, B.P. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-10-01

    The purpose of this work is to develop and implement a molecular design basis for selecting organic ligands that would be used in the cost-effective removal of specific radionuclides from nuclear waste streams. Organic ligands with metal ion specificity are critical components in the development of solvent extraction and ion exchange processes that are highly selective for targeted radionuclides. The traditional approach to the development of such ligands involves lengthy programs of organic synthesis and testing, which in the absence of reliable methods for screening compounds before synthesis, results in wasted research effort. The author`s approach breaks down and simplifies this costly process with the aid of computer-based molecular modeling techniques. Commercial software for organic molecular modeling is being configured to examine the interactions between organic ligands and metal ions, yielding an inexpensive, commercially or readily available computational tool that can be used to predict the structures and energies of ligand-metal complexes. Users will be able to correlate the large body of existing experimental data on structure, solution binding affinity, and metal ion selectivity to develop structural design criteria. These criteria will provide a basis for selecting ligands that can be implemented in separations technologies through collaboration with other DOE national laboratories and private industry. The initial focus will be to select ether-based ligands that can be applied to the recovery and concentration of the alkali and alkaline earth metal ions including cesium, strontium, and radium.

  2. Quantum Correlation Coefficients for Angular Coherent States

    Institute of Scientific and Technical Information of China (English)

    CHEN Wei; HE Yan; GUO Hao

    2009-01-01

    Quantum covariance and correlation coefficients of angular or SU(2) coherent states are directly calculated for all irreducible unitary representations.These results explicitly verify that the angular coherent states minimize the Robertson-Schrodinger uncertainty relation for all spins, which means that they are the so-called intelligent states.The same results can be obtained by the Schwinger representation approach.

  3. Angular Momentum Eigenstates for Equivalent Electrons.

    Science.gov (United States)

    Tuttle, E. R.; Calvert, J. B.

    1981-01-01

    Simple and efficient methods for adding angular momenta and for finding angular momentum eigenstates for systems of equivalent electrons are developed. Several different common representations are used in specific examples. The material is suitable for a graduate course in quantum mechanics. (SK)

  4. Responsive web design with AngularJS

    CERN Document Server

    Patel, Sandeep Kumar

    2014-01-01

    If you are an AngularJS developer who wants to learn about responsive web application development, this book is ideal for you. Responsive Web Design with AngularJS is intended for web developers or designers with a basic knowledge of HTML, CSS, and JavaScript.

  5. Angular Momentum Distribution in the Transverse Plane

    CERN Document Server

    Adhikari, Lekha

    2016-01-01

    Several possibilities to relate the $t$-dependence of Generalized Parton Distributions (GPDs) to the distribution of angular momentum in the transverse plane are discussed. Using a simple spectator model we demonstrate that non of them correctly describes the orbital angular momentum distribution that for a longitudinally polarized nucleon obtained directly from light-front wavefunctions.

  6. Physical Angular Momentum Separation for QED

    CERN Document Server

    Sun, Weimin

    2016-01-01

    We study the non-uniqueness problem of the gauge-invariant angular momentum separation for the case of QED, which stems from the recent controversy concerning the proper definitions of the orbital angular momentum and spin operator of the individual parts of a gauge field system. For the free quantum electrodynamics without matter, we show that the basic requirement of Euclidean symmetry selects a unique physical angular momentum separation scheme from the multitude of the possible angular momentum separation schemes constructed using the various Gauge Invariant Extentions. Based on these results, we propose a set of natural angular momentum separation schemes for the case of interacting QED by invoking the formalism of asymptotic fields. Some perspectives on such a problem for the case of QCD are briefly discussed.

  7. Ligand modeling and design

    Energy Technology Data Exchange (ETDEWEB)

    Hay, B. [Pacific Northwest Lab., Richland, WA (United States)

    1996-10-01

    The purpose of this work is to develop and implement a molecular design basis for selecting organic ligands that would be used tin applications for the cost-effective removal of specific radionuclides from nuclear waste streams.

  8. Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes.

    Science.gov (United States)

    Ngo, Ken T; McKinnon, Meaghan; Mahanti, Bani; Narayanan, Remya; Grills, David C; Ertem, Mehmed Z; Rochford, Jonathan

    2017-02-22

    Electrocatalytic reduction of CO2 to CO is reported for the complex, {fac-Mn(I)([(MeO)2Ph]2bpy)(CO)3(CH3CN)}(OTf), containing four pendant methoxy groups, where [(MeO)2Ph]2bpy = 6,6'-bis(2,6-dimethoxyphenyl)-2,2'-bipyridine. In addition to a steric influence similar to that previously established [Sampson, M. D. et al. J. Am. Chem. Soc. 2014, 136, 5460-5471] for the 6,6'-dimesityl-2,2'-bipyridine ligand in [fac-Mn(I)(mes2bpy)(CO)3(CH3CN)](OTf), which prevents Mn(0)-Mn(0) dimerization, the [(MeO)2Ph]2bpy ligand introduces an additional electronic influence combined with a weak allosteric hydrogen-bonding interaction that significantly lowers the activation barrier for C-OH bond cleavage from the metallocarboxylic acid intermediate. This provides access to the thus far elusive protonation-first pathway, minimizing the required overpotential for electrocatalytic CO2 to CO conversion by Mn(I) polypyridyl catalysts, while concurrently maintaining a respectable turnover frequency. Comprehensive electrochemical and computational studies here confirm the positive influence of the [(MeO)2Ph]2bpy ligand framework on electrocatalytic CO2 reduction and its dependence upon the concentration and pKa of the external Brønsted acid proton source (water, methanol, trifluoroethanol, and phenol) that is required for this class of manganese catalyst. Linear sweep voltammetry studies show that both phenol and trifluoroethanol as proton sources exhibit the largest protonation-first catalytic currents in combination with {fac-Mn(I)([(MeO)2Ph]2bpy)(CO)3(CH3CN)}(OTf), saving up to 0.55 V in overpotential with respect to the thermodynamically demanding reduction-first pathway, while bulk electrolysis studies confirm a high product selectivity for CO formation. To gain further insight into catalyst activation, time-resolved infrared (TRIR) spectroscopy combined with pulse-radiolysis (PR-TRIR), infrared spectroelectrochemistry, and density functional theory calculations were used to establish

  9. DNA binding and biological activity of mixed ligand complexes of Cu(II, Ni(II and Co(II with quinolones and N donor ligand

    Directory of Open Access Journals (Sweden)

    S.M M Akram

    2015-10-01

    Full Text Available  AbstractMixed ligand complexes of  Cu(II, Ni(II and Co(II have been synthesized by using levofloxacin and bipyridyl and characterized using spectral and analytical techniques. The binding behavior of the Ni(II and Cu(II complexes with herring sperm DNA(Hs-DNA were determined using electronic absorption titration, viscometric measurements and cyclic voltammetry measurements. The binding constant calculated  for Cu(II and Ni(II complexes are 2.0 x 104 and 4.0 x 104 M-1 respectively. Detailed analysis reveals that these metal complexes interact with DNA through intercalative binding mode. The nuclease activity of  Cu(II and Ni(II complexes with ct-DNA was carried out using agarose gel electrophoresis technique. The antioxidant activities for the synthesized complexes have been tested and the antibacterial activity for Ni(II complex was also checked.Key words: Intercalation, hypochromism, red shift and  peak potential.

  10. Photodegradation of methyl orange and photoinactivation of bacteria by visible light activation of persulphate using a tris(2,2'-bipyridyl)ruthenium(II) complex.

    Science.gov (United States)

    Subramanian, Gokulakrishnan; Parakh, Priyadarshini; Prakash, Halan

    2013-03-01

    Persulphate is an emerging oxidant in the field of advanced oxidation processes for the degradation of environmentally persistent organic compounds. The present study shows that visible light activation of persulphate (2 mM) using tris(2,2'-bipyridyl)ruthenium(II) (complex 1) (1 μM) caused rapid degradation (98%) of model azo dye methyl orange (MO) (12 mg L(-1)) with significant mineralization (76%), and also complete inactivation of both Gram negative and positive bacteria (∼10(7) CFU mL(-1)). BacLight LIVE/DEAD assay, scanning electron microscopy and genomic DNA analysis revealed cell membrane damage and loss of chromosomal DNA, indicating oxidative stress caused to E. coli during photoinactivation. The effect of concentration of complex 1 : persulphate ratio and presence of inorganic ions (0.1 M), such as sodium hydrogen phosphate, sodium sulphate, and sodium hydrogen carbonate, on the photodegradation of MO and photoinactivation of E. coli were studied. In addition, the effect of the presence of the organic contaminant resorcinol on the photoinactivation of E. coli was also studied. Significant degradation of MO and complete inactivation of bacteria were observed in simulated ground water. The present study is the first to reveal that activation of persulphate using a visible light absorbing metal complex in aqueous media has the ability to cause degradation of organic contaminants as well as complete inactivation of bacteria.

  11. Influence of different ruthenium(II) bipyridyl complex on the photocatalytic H{sub 2} evolution over TiO{sub 2} nanoparticles with mesostructures

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Tianyou [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China); Hubei Key Laboratory for Catalysis and Material Science, College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074 (China); Ke, Dingning; Cai, Ping; Dai, Ke; Ma, Liang; Zan, Ling [College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 (China)

    2008-05-15

    H{sub 2} production over dye-sensitized Pt/TiO{sub 2} nanoparticles with mesostructures (m-TiO{sub 2}) under visible light ({lambda} > 420 nm) was investigated by using methanol as electron donors. Experimental results indicate that three types of ruthenium(II) bipyridyl complex dyes (one binuclear Ru, two mononuclear Ru), which can be attached to Pt/m-TiO{sub 2} with different linkage modes, show different photosensitization effects due to their different coordination circumstances and physicochemical properties. The dye tightly linked with m-TiO{sub 2} has better durability but the lowest H{sub 2} evolution efficiency, whereas the loosely attached dyes possess higher H{sub 2} evolution efficiency and preferable durability. It seems that the dynamic equilibrium between the linkage of the ground state dye with TiO{sub 2} and the divorce of the oxidization state dye from the surfaces plays a crucial role in the photochemical behavior during the photocatalyst sensitization process. It is helpful to improve the H{sub 2} evolution efficiency by enhancing the electron injection and hindering the backward transfer. The binuclear Ru(II) dye shows a better photosensitization in comparison with mononuclear Ru(II) dyes due to its large molecular area, conjugation system, and ''antenna effect'', which, in turn, improve the visible light harvesting and electron transfer between the dye molecules and TiO{sub 2}. (author)

  12. Electric response in the antiferroelectric crystal of 4,4‧-di-t-butyl-2,2‧-bipyridyl with chloranilic acid

    Science.gov (United States)

    Rok, M.; Piecha-Bisiorek, A.; Szklarz, P.; Bator, G.; Sobczyk, L.

    2015-05-01

    The electric response was analyzed in the vicinity of the structural phase transition at 412 K in the single crystals of 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) with 4,4‧-di-t-butyl-2,2‧-bipyridyl (dtBBP). The dielectric permittivity of the complex measured along the b direction between 300 and 440 K and at frequencies ranging from 500 Hz to 2 MHz indicates two phenomena. At low frequencies, dielectric losses are ascribed to the electric conductivity of the crystal, while at high frequencies, to the dielectric relaxation described by means of the Cole-Cole relationship. The parameters of the dielectric response: the relaxation time, τ, the dielectric increment, εο - ε∞, and the distribution parameter of the relaxation time, α, were estimated and analyzed. The low-temperature structure of the crystals indicates the antiferroelectric arrangement of the supramolecular hydrogen bonds. The dielectric results also presented for the deuterated crystals of dtBBP·CLA proved that the dynamics of protons in the hydrogen bonds are responsible for the mechanism of phase transition.

  13. Palladium(II/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water

    Directory of Open Access Journals (Sweden)

    Fu-Yu Tsai

    2010-01-01

    Full Text Available A water-soluble and air-stable Pd(NH32Cl2/cationic 2,2’-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu3N as a base. The reaction was conducted at 140 °C in a sealed tube in air with a catalyst loading as low as 0.0001 mol % for the coupling of activated aryl iodides with butyl and ethyl acrylates, providing the corresponding products in good to excellent yields with very high turnover numbers. In the case of styrene, Mizoroki-Heck coupling products were obtained in good to high yields by using a greater catalyst loading (1 mol % and TBAB as a phase-transfer agent. After extraction, the residual aqueous solution could be reused several times with only a slight decrease in its activity, making the Mizoroki-Heck reaction “greener”.

  14. Electron transfer study on graphene modified glassy carbon substrate via electrochemical reduction and the application for tris(2,2'-bipyridyl)ruthenium(II) electrochemiluminescence sensor fabrication.

    Science.gov (United States)

    Xu, Yuanhong; Cao, Mengmei; Liu, Huihui; Zong, Xidan; Kong, Na; Zhang, Jizhen; Liu, Jingquan

    2015-07-01

    In this study, electron transfer behavior of the graphene nanosheets attachment on glassy carbon electrode (GCE) via direct electrochemical reduction of graphene oxide (GO) is investigated for the first time. The graphene modified electrode was achieved by simply dipping the GCE in GO suspension, followed by cyclic voltammetric scanning in the potential window from 0V to -1.5V. Tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy)3(2+)] was immobilized on the graphene modified electrode and used as the redox probe to evaluate the electron transfer behavior. The electron transfer rate constant (Ks) was calculated to be 61.9±5.8s(-1), which is much faster than that of tiled graphene modified GCE (7.1±0.6s(-1)). The enhanced electron transfer property observed with the GCE modified by reductively deposited graphene is probably due to its standing configuration, which is beneficial to the electron transfer comparing with the tiled one. Because the abundant oxygen-containing groups are mainly located at the edges of GO, which should be much easier for the reduction to start from, the reduced GO should tend to stand on the electrode surface as evidenced by scanning electron microscopy analysis. In addition, due to the favored electron transfer and standing configuration, the Ru(bpy)3(2+) electrochemiluminescence sensor fabricated with standing graphene modified GCE provided much higher and more stable efficiency than that fabricated with tiled graphene.

  15. Novel Detection of Optical Orbital Angular Momentum

    Science.gov (United States)

    2014-11-16

    Spreeuw, J. P . Woerdman, “ Orbital angular momentum of light and the transformation of Laguerre-Gaussian laser modes,” Phys. Rev. A, 45(11), 8185-8189...AFRL-RD-PS- AFRL-RD-PS TR-2014-0045 TR-2014-0045 Novel Detection of Optical Orbital Angular Momentum David Voelz Klipsch... Orbital Angular Momentum FA9451-13-1-0261 GR0004113 David Voelz Klipsch School of ECE New Mexico State University MSC 3-O, PO Box 30001 Las Cruces, NM

  16. Radiofrequency encoded angular-resolved light scattering

    DEFF Research Database (Denmark)

    Buckley, Brandon W.; Akbari, Najva; Diebold, Eric D.

    2015-01-01

    The sensitive, specific, and label-free classification of microscopic cells and organisms is one of the outstanding problems in biology. Today, instruments such as the flow cytometer use a combination of light scatter measurements at two distinct angles to infer the size and internal complexity...... of cells at rates of more than 10,000 per second. However, by examining the entire angular light scattering spectrum it is possible to classify cells with higher resolution and specificity. Current approaches to performing these angular spectrum measurements all have significant throughput limitations...... Encoded Angular-resolved Light Scattering (REALS), this technique multiplexes angular light scattering in the radiofrequency domain, such that a single photodetector captures the entire scattering spectrum from a particle over approximately 100 discrete incident angles on a single shot basis. As a proof...

  17. Generalized Uncertainty Principle and Angular Momentum

    CERN Document Server

    Bosso, Pasquale

    2016-01-01

    Various models of quantum gravity suggest a modification of the Heisenberg's Uncertainty Principle, to the so-called Generalized Uncertainty Principle, between position and momentum. In this work we show how this modification influences the theory of angular momentum in Quantum Mechanics. In particular, we compute Planck scale corrections to angular momentum eigenvalues, the Hydrogen atom spectrum, the Stern-Gerlach experiment and the Clebsch-Gordan coefficients. We also examine effects of the Generalized Uncertainty Principle on multi-particle systems.

  18. Angular distribution in complex oscillation theory

    Institute of Scientific and Technical Information of China (English)

    WU Shengjian

    2005-01-01

    Let f1 and f2 be two linearly independent solutions of the differential equation f" + Af =0,where A is an entire function.Set E-f1f2.In this paper,we shall study the angular distribution of E and establish a relation between zero accumulation rays and Borel directions of E.Consequently we can obtain some results in the complex differential equation by using known results in angular distribution theory of meromorphic functions.

  19. Mastering AngularJD for .NET developers

    CERN Document Server

    Majid, Mohammad Wadood

    2015-01-01

    This book is envisioned for traditional developers and programmers who want to develop client-side applications using the AngularJS framework and ASP.NET Web API 2 with Visual Studio. .NET developers who have already built web applications or web services and who have a fundamental knowledge of HTML, JavaScript, and CSS and want to explore single-page applications will also find this guide useful. Basic knowledge of AngularJS would be helpful.

  20. Geometric absorption of electromagnetic angular momentum

    Science.gov (United States)

    Konz, C.; Benford, Gregory

    2003-10-01

    Circularly polarized electromagnetic fields carry both energy and angular momentum. We investigate the conditions under which a circularly polarized wave field transfers angular momentum to a perfectly conducting macroscopic object, using exact electromagnetic wave theory in a steady-state calculation. We find that axisymmetric perfect conductors cannot absorb or radiate angular momentum when illuminated. However, any asymmetry allows absorption. A rigorous, steady-state solution of the boundary value problem for the reflection from a perfectly conducting infinite wedge shows that waves convey angular momentum at the edges of asymmetries. Conductors can also radiate angular momentum, so their geometric absorption coefficient for angular momentum can be negative. Such absorption or radiation depends solely on the specific geometry of the conductor. The geometric absorption coefficient can be as high as 0.8, and the coefficient for radiation can be -0.4, larger than typical material absorption coefficients. We apply the results to recent experiments which spun roof-shaped aluminum sheets with polarized microwave beams. Applications of geometric, instead of material, absorption can be quite varied. Though experiments testing these ideas will be simpler at microwavelengths, the ideas work for optical ones as well.

  1. Reactivity and molecular modeling of new solvatochromic mixed-ligand copper(II) chelates of 2-acetylbutyrolactone and dinitrogen bases.

    Science.gov (United States)

    Taha, A; Adly, Omima M I; Shebl, Magdy

    2015-04-01

    A new series of solvatochromic mononuclear mixed ligand chelates with the general formula: Cu(AcBL)(L)X; where AcBL=2-acetylbutyrolactonate, L=N,N,N',N'-tetramethylethylenediamine (Me4en), N,N,N',N'-tetramethylpropylene diamine (Me4pn), 1,10-phenanthroline (Phen) or 2,2'-bipyridyl (Bipy) and X=ClO4-, NO3- or Br- have been synthesized and characterized by the analytical and spectral methods, as well as magnetic and molar conductance measurements. The d-d absorption bands of Me4en-chelates as Nujol mulls or weak donor solvents solutions revealed square-planar, distorted octahedral and/or distorted trigonal bipyramid geometries for the perchlorate, nitrate and bromide chelates, respectively. However, an octahedral structure is identified for chelates in strong donor solvents. Perchlorate chelates show a remarkable color change from violet to green as the Lewis basicity of the donor solvent increases, whereas bromide chelates are mainly affected by the Lewis acidity of solvent. Specific and non-specific interactions of solvent molecules with the chelates were investigated on the basis of unified solvation model. Structural parameters of the free ligands and their Cu(II)-chelates have been calculated on the basis of semiempirical PM3 level and correlated with the experimental data.

  2. Ligand effects on the structural dimensionality and antibacterial activities of silver-based coordination polymers.

    Science.gov (United States)

    Lu, Xinyi; Ye, Junwei; Sun, Yuan; Bogale, Raji Feyisa; Zhao, Limei; Tian, Peng; Ning, Guiling

    2014-07-14

    Four Ag-based coordination polymers [Ag(Bim)] (1), [Ag2(NIPH)(HBim)] (2), [Ag6(4-NPTA)(Bim)4] (3) and [Ag2(3-NPTA)(bipy)0.5(H2O)] (4) (HBim = 1H-benzimidazole, bipy = 4,4'-bipyridyl, H2NIPH = 5-nitroisophthalic acid, H2NPTA = 3-/4-nitrophthalic acid) have been synthesized by hydrothermal reaction of Ag(i) salts with N-/O-donor ligands. Single-crystal X-ray diffraction indicated that these coordination polymers constructed from mononuclear or polynuclear silver building blocks exhibit three typical structure features from 1-D to 3-D frameworks. These compounds favour a slow release of Ag(+) ions leading to excellent and long-term antimicrobial activities, which is distinguished by their different topological structures, towards both Gram-negative bacteria, Escherichia coli (E. coli) and Gram-positive bacteria, Staphylococcus aureus (S. aureus). In addition, these compounds show good thermal stability and light stability under UV-vis and visible light, which are important characteristics for their further application in antibacterial agents.

  3. Electric response in the antiferroelectric crystal of 4,4′-di-t-butyl-2,2′-bipyridyl with chloranilic acid

    Energy Technology Data Exchange (ETDEWEB)

    Rok, M., E-mail: magdalena.rok@chem.uni.wroc.pl; Piecha-Bisiorek, A.; Szklarz, P.; Bator, G.; Sobczyk, L.

    2015-05-01

    Highlights: • The semiconducting properties of the crystals were disclosed in the organic complex. • Dielectric relaxation and dc conductivity were investigated. • Activation energy for the thermally activated processes of the σ{sub dc} was estimated. • The effect of hydrogen bonds on the mechanism of the phase transition and the electric properties of the crystal was discussed. - Abstract: The electric response was analyzed in the vicinity of the structural phase transition at 412 K in the single crystals of 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) with 4,4′-di-t-butyl-2,2′-bipyridyl (dtBBP). The dielectric permittivity of the complex measured along the b direction between 300 and 440 K and at frequencies ranging from 500 Hz to 2 MHz indicates two phenomena. At low frequencies, dielectric losses are ascribed to the electric conductivity of the crystal, while at high frequencies, to the dielectric relaxation described by means of the Cole–Cole relationship. The parameters of the dielectric response: the relaxation time, τ, the dielectric increment, ε{sub ο} − ε{sub ∞}, and the distribution parameter of the relaxation time, α, were estimated and analyzed. The low-temperature structure of the crystals indicates the antiferroelectric arrangement of the supramolecular hydrogen bonds. The dielectric results also presented for the deuterated crystals of dtBBP·CLA proved that the dynamics of protons in the hydrogen bonds are responsible for the mechanism of phase transition.

  4. Dissociation and Dioxygen Formation in Hydroxide Solutions of Tris (2,2- bipyridyl) Iron (III) and Tris (1,10-phenanthroline) Iron (III)

    DEFF Research Database (Denmark)

    Nord, G.; Pedersen, B.; Bjergbakke, Erling

    1983-01-01

    The fast redox reactions of the title Fe(II1) complexes in basic solutions give the Fe(I1) complexes and coordinated ligand N-oxide as primary products. Further reactions by parallel paths include dissociation to give the free ligand N-oxide and catalysis by hydroxy Fe(II1) complexes leading...

  5. Ligand fitting with CCP4

    Science.gov (United States)

    2017-01-01

    Crystal structures of protein–ligand complexes are often used to infer biology and inform structure-based drug discovery. Hence, it is important to build accurate, reliable models of ligands that give confidence in the interpretation of the respective protein–ligand complex. This paper discusses key stages in the ligand-fitting process, including ligand binding-site identification, ligand description and conformer generation, ligand fitting, refinement and subsequent validation. The CCP4 suite contains a number of software tools that facilitate this task: AceDRG for the creation of ligand descriptions and conformers, Lidia and JLigand for two-dimensional and three-dimensional ligand editing and visual analysis, Coot for density interpretation, ligand fitting, analysis and validation, and REFMAC5 for macromolecular refinement. In addition to recent advancements in automatic carbohydrate building in Coot (LO/Carb) and ligand-validation tools (FLEV), the release of the CCP4i2 GUI provides an integrated solution that streamlines the ligand-fitting workflow, seamlessly passing results from one program to the next. The ligand-fitting process is illustrated using instructive practical examples, including problematic cases such as post-translational modifications, highlighting the need for careful analysis and rigorous validation. PMID:28177312

  6. Photochemistry of RuII 4,4′-Bi-1,2,3-triazolyl (btz) Complexes: Crystallographic Characterization of the Photoreactive Ligand-Loss Intermediate trans-[Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)]2+

    OpenAIRE

    Welby, Christine E.; Armitage, Georgina K.; Bartley, Harry; Wilkinson, Aaron; Sinopoli, Alessandro; Uppal, Baljinder S; Rice, Craig R.; Elliott, Paul I.

    2014-01-01

    We report the unprecedented observation and unequivocal crystallographic characterization of the meta-stable ligand loss intermediate solvento complex trans-[Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)]2+ (1 a) that contains a monodentate chelate ligand. This and analogous complexes can be observed during the photolysis reactions of a family of complexes of the form [Ru(equation image)(btz)2]2+ (1 a–d: btz=1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl; equation image=a) 2,2′-bipyridyl (bpy), b) 4,4′-dimethyl-2,2′-...

  7. An orbital angular momentum spectrometer for electrons

    Science.gov (United States)

    Harvey, Tyler; Grillo, Vincenzo; McMorran, Benjamin

    2016-05-01

    With the advent of techniques for preparation of free-electron and neutron orbital angular momentum (OAM) states, a basic follow-up question emerges: how do we measure the orbital angular momentum state distribution in matter waves? Control of both the energy and helicity of light has produced a range of spectroscopic applications, including molecular fingerprinting and magnetization mapping. Realization of an analogous dual energy-OAM spectroscopy with matter waves demands control of both initial and final energy and orbital angular momentum states: unlike for photons, final state post-selection is necessary for particles that cannot be annihilated. We propose a magnetic field-based mechanism for quantum non-demolition measurement of electron OAM. We show that OAM-dependent lensing is produced by an operator of form U =exp iLzρ2/ℏb2 where ρ =√{x2 +y2 } is the radial position operator, Lz is the orbital angular momentum operator along z, and b is the OAM dispersion length. We can physically realize this operator as a term in the time evolution of an electron in magnetic round lens. We discuss prospects and practical challenges for implementation of a lensing orbital angular momentum measurement. This work was supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under the Early Career Research Program Award # DE-SC0010466.

  8. Ultrafast angular momentum transfer in multisublattice ferrimagnets.

    Science.gov (United States)

    Bergeard, N; López-Flores, V; Halté, V; Hehn, M; Stamm, C; Pontius, N; Beaurepaire, E; Boeglin, C

    2014-03-11

    Femtosecond laser pulses can be used to induce ultrafast changes of the magnetization in magnetic materials. However, one of the unsolved questions is that of conservation of the total angular momentum during the ultrafast demagnetization. Here we report the ultrafast transfer of angular momentum during the first hundred femtoseconds in ferrimagnetic Co0.8Gd0.2 and Co0.74Tb0.26 films. Using time-resolved X-ray magnetic circular dichroism allowed for time-resolved determination of spin and orbital momenta for each element. We report an ultrafast quenching of the magnetocrystalline anisotropy and show that at early times the demagnetization in ferrimagnetic alloys is driven by the local transfer of angular momenta between the two exchange-coupled sublattices while the total angular momentum stays constant. In Co0.74Tb0.26 we have observed a transfer of the total angular momentum to an external bath, which is delayed by ~150 fs.

  9. Data-oriented development with AngularJS

    CERN Document Server

    Waikar, Manoj

    2015-01-01

    This book helps beginner-level AngularJS developers organize AngularJS applications by discussing important AngularJS concepts and best practices. If you are an experienced AngularJS developer but haven't written directives or haven't created custom HTML controls before, then this book is ideal for you.

  10. Localizing the Angular Momentum of Linear Gravity

    CERN Document Server

    Butcher, Luke M; Hobson, Michael; 10.1103/PhysRevD.86.084012

    2012-01-01

    In a previous article [Phys. Rev. D 82 104040 (2010)], we derived an energy-momentum tensor for linear gravity that exhibited positive energy density and causal energy flux. Here we extend this framework by localizing the angular momentum of the linearized gravitational field, deriving a gravitational spin tensor which possesses similarly desirable properties. By examining the local exchange of angular momentum (between matter and gravity) we find that gravitational intrinsic spin is localized, separately from orbital angular momentum, in terms of a gravitational spin tensor. This spin tensor is then uniquely determined by requiring that it obey two simple physically motivated algebraic conditions. Firstly, the spin of an arbitrary (harmonic-gauge) gravitational plane wave is required to flow in the direction of propagation of the wave. Secondly, the spin tensor of any transverse-traceless gravitational field is required to be traceless. (The second condition ensures that local field redefinitions suffice to ...

  11. Physics from Angular Projection of Rectangular Grids

    CERN Document Server

    Singh, Ashmeet

    2015-01-01

    In this paper, we present a mathematical model for the angular projection of a rectangular arrangement of points in a grid. This simple, yet interesting problem, has both a scholarly value and applications for data extraction techniques to study the physics of various systems. Our work can interest undergraduate students to understand subtle points in the angular projection of a grid and describes various quantities of interest in the projection with completeness and sufficient rigour. We show that for certain angular ranges, the projection has non-distinctness, and calculate the details of such angles, and correspondingly, the number of distinct points and the total projected length. We focus on interesting trends obtained for the projected length of the grid elements and present a simple application of the model to determine the geometry of an unknown grid whose spatial extensions are known, using measurement of the grid projection at two angles only. Towards the end, our model is shown to have potential ap...

  12. Angular momentum transport in protostellar discs

    CERN Document Server

    Salmeron, Roberto Aureliano; Wardle, M; Salmeron, Raquel; Konigl, Arieh; Wardle, Mark

    2006-01-01

    Angular momentum transport in protostellar discs can take place either radially, through turbulence induced by the magnetorotational instability (MRI), or vertically, through the torque exerted by a large-scale magnetic field that threads the disc. Using semi-analytic and numerical results, we construct a model of steady-state discs that includes vertical transport by a centrifugally driven wind as well as MRI-induced turbulence. We present approximate criteria for the occurrence of either one of these mechanisms in an ambipolar diffusion-dominated disc. We derive ``strong field'' solutions in which the angular momentum transport is purely vertical and ``weak field'' solutions that are the stratified-disc analogues of the previously studied MRI channel modes; the latter are transformed into accretion solutions with predominantly radial angular-momentum transport when we implement a turbulent-stress prescription based on published results of numerical simulations. We also analyze ``intermediate field strength'...

  13. Surface angular momentum of light beams.

    Science.gov (United States)

    Ornigotti, Marco; Aiello, Andrea

    2014-03-24

    Traditionally, the angular momentum of light is calculated for "bullet-like" electromagnetic wave packets, although in actual optical experiments "pencil-like" beams of light are more commonly used. The fact that a wave packet is bounded transversely and longitudinally while a beam has, in principle, an infinite extent along the direction of propagation, renders incomplete the textbook calculation of the spin/orbital separation of the angular momentum of a light beam. In this work we demonstrate that a novel, extra surface part must be added in order to preserve the gauge invariance of the optical angular momentum per unit length. The impact of this extra term is quantified by means of two examples: a Laguerre-Gaussian and a Bessel beam, both circularly polarized.

  14. Angular momentum transfer in incomplete fusion

    Indian Academy of Sciences (India)

    B S Tomar; K Surendra Babu; K Sudarshan; R Tripathi; A Goswami

    2005-02-01

    Isomeric cross-section ratios of evaporation residues formed in 12C+93Nb and 16O + 89Y reactions were measured by recoil catcher technique followed by off-line -ray spectrometry in the beam energy range of 55.7-77.5 MeV for 12C and 68-81 MeV for 16O. The isomeric cross-section ratios were resolved into that for complete and incomplete fusion reactions. The angular momentum of the intermediate nucleus formed in incomplete fusion was deduced from the isomeric cross-section ratio by considering the statistical de-excitation of the incompletely fused composite nucleus. The data show that incomplete fusion is associated with angular momenta slightly smaller than critical angular momentum for complete fusion, indicating the deeper interpenetration of projectile and target nuclei than that in peripheral collisions.

  15. Ghost Imaging Using Orbital Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    赵生妹; 丁建; 董小亮; 郑宝玉

    2011-01-01

    We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum. In the signal arm, object spatial information is encoded as a phase matrix. For an N-grey-scale object, different phase matrices, varying from 0 to K with increment n/N, are used for different greyscales, and then they are modulated to a signal beam by a spatial light modulator. According to the conservation of the orbital angular momentum in the ghost imaging system, these changes will give different coincidence rates in measurement, and hence the object information can be extracted in the idler arm. By simulations and experiments, the results show that our scheme can improve the resolution of the image effectively. Compared with another encoding method using orbital angular momentum, our scheme has a better performance for both characters and the image object.%We present a novel encoding scheme in a ghost-imaging system using orbital angular momentum.In the signal arm,object spatial information is encoded as a phase matrix.For an N-grey-scale object,different phase matrices,varying from 0 to π with increment π/N,are used for different greyscales,and then they are modulated to a signal beam by a spatial light modulator.According to the conservation of the orbital angular momentum in the ghost imaging system,these changes will give different coincidence rates in measurement,and hence the object information can be extracted in the idler arm.By simulations and experiments,the results show that our scheme can improve the resolution of the image effectively.Compared with another encoding method using orbital angular momentum,our scheme has a better performance for both characters and the image object.

  16. On the vector model of angular momentum

    Science.gov (United States)

    Saari, Peeter

    2016-09-01

    Instead of (or in addition to) the common vector diagram with cones, we propose to visualize the peculiarities of quantum mechanical angular momentum by a completely quantized 3D model. It spotlights the discrete eigenvalues and noncommutativity of components of angular momentum and corresponds to outcomes of measurements—real or computer-simulated. The latter can be easily realized by an interactive worksheet of a suitable program package of algebraic calculations. The proposed complementary method of visualization helps undergraduate students to better understand the counterintuitive properties of this quantum mechanical observable.

  17. Concepts of radial and angular kinetic energies

    DEFF Research Database (Denmark)

    Dahl, Jens Peder; Schleich, W.P.

    2002-01-01

    We consider a general central-field system in D dimensions and show that the division of the kinetic energy into radial and angular parts proceeds differently in the wave-function picture and the Weyl-Wigner phase-space picture, Thus, the radial and angular kinetic energies are different quantiti...... in the two pictures, containing different physical information, but the relation between them is well defined. We discuss this relation and illustrate its nature by examples referring to a free particle and to a ground-state hydrogen atom....

  18. Angular momentum and the electromagnetic top

    Indian Academy of Sciences (India)

    GIANFRANCO SPAVIERI; GEORGE T GILLIES

    2016-08-01

    The electric charge–magnetic dipole interaction is considered. If $\\Gamma_{\\rm em}$ is the electromagnetic and $\\Gamma_{\\rm mech}$ the mechanical angular momentum, the conservation law for the total angular momentum $\\Gamma_{\\rm tot}$ holds: $\\Gamma_{\\rm tot}$ =$\\Gamma_{\\rm em}$ + $\\Gamma_{\\rm mech}$ = ${\\rm const.}$, but when the dipole moment varies with time, $\\Gamma_{\\rm mech}$ is not conserved. We show that the non-conserved $\\Gamma_{\\rm mech}$ of such a macroscopic isolated system might be experimentally observable. With advanced technology, the strength of the interaction hints to the possibility of novel applications for gyroscopes, such as the electromagnetic top.

  19. Orbital angular momentum in the nucleons

    CERN Document Server

    Lorcé, Cédric

    2014-01-01

    In the last decade, it has been realized that the orbital angular momentum of partons inside the nucleon plays a major role. It contributes significantly to nucleon properties and is at the origin of many asymmetries observed in spin physics. It is therefore of paramount importance to determine this quantity if we want to understand the nucleon internal structure and experimental observables. This triggered numerous discussions and controversies about the proper definition of orbital angular momentum and its extraction from experimental data. We summarize the present situation and discuss recent developments in this field.

  20. Angular gyrus syndrome mimicking depressive pseudodementia.

    Science.gov (United States)

    Nagaratnam, Nages; Phan, Tai Anh; Barnett, Claire; Ibrahim, Neamat

    2002-09-01

    A 67-year-old left-handed woman with a diagnosis of pseudodementia was being treated for depression with little benefit. Neuropsychological evaluations revealed features of angular gyrus syndrome, namely, agraphia, alexia, Gerstmann's syndrome and behavioural manifestations such as depression, poor memory, frustration and irritability. A computed tomographic scan showed a right occipito-temporal infarction, which had occurred 18 months earlier. The patient demonstrated aspects of language dysfunction associated with the syndrome and showed reversed lateralization of cerebral functions. Recognizing and distinguishing between angular gyrus syndrome and depression is important because the appropriate therapies differ. The use of the term pseudodementia can be misleading.

  1. LigandRNA: computational predictor of RNA-ligand interactions.

    Science.gov (United States)

    Philips, Anna; Milanowska, Kaja; Lach, Grzegorz; Bujnicki, Janusz M

    2013-12-01

    RNA molecules have recently become attractive as potential drug targets due to the increased awareness of their importance in key biological processes. The increase of the number of experimentally determined RNA 3D structures enabled structure-based searches for small molecules that can specifically bind to defined sites in RNA molecules, thereby blocking or otherwise modulating their function. However, as of yet, computational methods for structure-based docking of small molecule ligands to RNA molecules are not as well established as analogous methods for protein-ligand docking. This motivated us to create LigandRNA, a scoring function for the prediction of RNA-small molecule interactions. Our method employs a grid-based algorithm and a knowledge-based potential derived from ligand-binding sites in the experimentally solved RNA-ligand complexes. As an input, LigandRNA takes an RNA receptor file and a file with ligand poses. As an output, it returns a ranking of the poses according to their score. The predictive power of LigandRNA favorably compares to five other publicly available methods. We found that the combination of LigandRNA and Dock6 into a "meta-predictor" leads to further improvement in the identification of near-native ligand poses. The LigandRNA program is available free of charge as a web server at http://ligandrna.genesilico.pl.

  2. Ligand-Receptor Interactions

    CERN Document Server

    Bongrand, Pierre

    2008-01-01

    The formation and dissociation of specific noncovalent interactions between a variety of macromolecules play a crucial role in the function of biological systems. During the last few years, three main lines of research led to a dramatic improvement of our understanding of these important phenomena. First, combination of genetic engineering and X ray cristallography made available a simultaneous knowledg of the precise structure and affinity of series or related ligand-receptor systems differing by a few well-defined atoms. Second, improvement of computer power and simulation techniques allowed extended exploration of the interaction of realistic macromolecules. Third, simultaneous development of a variety of techniques based on atomic force microscopy, hydrodynamic flow, biomembrane probes, optical tweezers, magnetic fields or flexible transducers yielded direct experimental information of the behavior of single ligand receptor bonds. At the same time, investigation of well defined cellular models raised the ...

  3. Angular and linear momentum of excited ferromagnets

    NARCIS (Netherlands)

    Yan, P.; Kamra, A.; Cao, Y.; Bauer, G.E.W.

    2013-01-01

    The angular momentum vector of a Heisenberg ferromagnet with isotropic exchange interaction is conserved, while under uniaxial crystalline anisotropy the projection of the total spin along the easy axis is a constant of motion. Using Noether's theorem, we prove that these conservation laws persist i

  4. A Novel Permanent Magnetic Angular Acceleration Sensor

    Directory of Open Access Journals (Sweden)

    Hao Zhao

    2015-07-01

    Full Text Available Angular acceleration is an important parameter for status monitoring and fault diagnosis of rotary machinery. Therefore, we developed a novel permanent magnetic angular acceleration sensor, which is without rotation angle limitations and could directly measure the instantaneous angular acceleration of the rotating system. The sensor rotor only needs to be coaxially connected with the rotating system, which enables convenient sensor installation. For the cup structure of the sensor rotor, it has a relatively small rotational inertia. Due to the unique mechanical structure of the sensor, the output signal of the sensor can be directed without a slip ring, which avoids signal weakening effect. In this paper, the operating principle of the sensor is described, and simulated using finite element method. The sensitivity of the sensor is calibrated by torsional pendulum and angle sensor, yielding an experimental result of about 0.88 mV/(rad·s−2. Finally, the angular acceleration of the actual rotating system has been tested, using both a single-phase asynchronous motor and a step motor. Experimental result confirms the operating principle of the sensor and indicates that the sensor has good practicability.

  5. A Novel Permanent Magnetic Angular Acceleration Sensor.

    Science.gov (United States)

    Zhao, Hao; Feng, Hao

    2015-07-03

    Angular acceleration is an important parameter for status monitoring and fault diagnosis of rotary machinery. Therefore, we developed a novel permanent magnetic angular acceleration sensor, which is without rotation angle limitations and could directly measure the instantaneous angular acceleration of the rotating system. The sensor rotor only needs to be coaxially connected with the rotating system, which enables convenient sensor installation. For the cup structure of the sensor rotor, it has a relatively small rotational inertia. Due to the unique mechanical structure of the sensor, the output signal of the sensor can be directed without a slip ring, which avoids signal weakening effect. In this paper, the operating principle of the sensor is described, and simulated using finite element method. The sensitivity of the sensor is calibrated by torsional pendulum and angle sensor, yielding an experimental result of about 0.88 mV/(rad·s(-2)). Finally, the angular acceleration of the actual rotating system has been tested, using both a single-phase asynchronous motor and a step motor. Experimental result confirms the operating principle of the sensor and indicates that the sensor has good practicability.

  6. Angular Momentum Transport in Accretion Disks

    DEFF Research Database (Denmark)

    E. Pessah, Martin; Chan, Chi-kwan; Psaltis, Dimitrios;

    2007-01-01

    if the resolution were set equal to the natural dissipation scale in astrophysical disks. We conclude that, in order for MRI-driven turbulent angular momentum transport to be able to account for the large value of the effective alpha viscosity inferred observationally, the disk must be threaded by a significant...

  7. ANGULAR MOMENTUM ACQUISITION IN GALAXY HALOS

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, Kyle R. [Department of Natural and Mathematical Sciences, California Baptist University, 8432 Magnolia Ave., Riverside, CA 92504 (United States); Brooks, Alyson M. [Department of Astronomy, University of Wisconsin-Madison, 475 N. Charter St., Madison, WI 53706 (United States); Bullock, James S. [Center for Cosmology, Department of Physics and Astronomy, University of California at Irvine, Irvine, CA 92697 (United States); Maller, Ariyeh H. [Department of Physics, New York City College of Technology, 300 Jay St., Brooklyn, NY 11201 (United States); Diemand, Juerg [Institute for Theoretical Physics, University of Zurich, 8057, Zurich (Switzerland); Wadsley, James [Department of Physics and Astronomy, McMaster University, Main Street West, Hamilton L85 4M1 (Canada); Moustakas, Leonidas A. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2013-05-20

    We use high-resolution cosmological hydrodynamic simulations to study the angular momentum acquisition of gaseous halos around Milky-Way-sized galaxies. We find that cold mode accreted gas enters a galaxy halo with {approx}70% more specific angular momentum than dark matter averaged over cosmic time (though with a very large dispersion). In fact, we find that all matter has a higher spin parameter when measured at accretion than when averaged over the entire halo lifetime, and is well characterized by {lambda} {approx} 0.1, at accretion. Combined with the fact that cold flow gas spends a relatively short time (1-2 dynamical times) in the halo before sinking to the center, this naturally explains why cold flow halo gas has a specific angular momentum much higher than that of the halo and often forms ''cold flow disks.'' We demonstrate that the higher angular momentum of cold flow gas is related to the fact that it tends to be accreted along filaments.

  8. Critical gravitational collapse with angular momentum

    CERN Document Server

    Gundlach, Carsten

    2016-01-01

    We derive a theoretical model of mass and angular momentum scaling in type-II critical collapse with rotation. We focus on the case where the critical solution has precisely one, spherically symmetric, unstable mode. We demonstrate excellent agreement with numerical results for critical collapse of a rotating radiation fluid, which falls into this case.

  9. A new method for angular displacement measurement

    Institute of Scientific and Technical Information of China (English)

    Caini Zhang(张彩妮); Xiangzhao Wang(王向朝)

    2003-01-01

    We describe a new method for angular displacement measurements that is based on a Fabry-Perot inter-ferometer. A measurement accuracy of 10-s rad is obtained by use of the sinusoidal phase modulatinginterferometry. Another Fabry-Perot interferometer is used to obtain the key initial angle of incidence.

  10. Optical angular momentum conversion in a nanoslit

    NARCIS (Netherlands)

    Chimento, P.F.; Alkemade, P.F.A.; T Hooft, G.W.; Eliel, E.R.

    2012-01-01

    We demonstrate partial conversion of circularly polarized light into orbital angular momentum-carrying vortex light with opposite-handed circular polarization. This conversion is accomplished in a novel manner using the birefringent properties of a circular subwavelength slit in a thin metal film. O

  11. Wigner Functions and Quark Orbital Angular Momentum

    Directory of Open Access Journals (Sweden)

    Mukherjee Asmita

    2015-01-01

    Full Text Available Wigner distributions contain combined position and momentum space information of the quark distributions and are related to both generalized parton distributions (GPDs and transverse momentum dependent parton distributions (TMDs. We report on a recent model calculation of the Wigner distributions for the quark and their relation to the orbital angular momentum.

  12. γ - γ Angular Correlation Measurements With GRIFFIN

    Science.gov (United States)

    Maclean, Andrew; Griffin Collaboration

    2015-10-01

    When an excited nuclear state emits successive γ-rays causing a γ - γ cascade an anisotropy is found in the spatial distribution of γ2 with respect to γ1. Defining the direction of γ1 as the z-axis, the intermediate level, in general will have an uneven distribution of m-states. This causes an anisotropy in the angular correlation of the second γ-ray with respect to the first. These angular correlations are expressed by the W (θ) that depends on numerical coefficients described by the sequence of spin-parity values for the nuclear states involved, the multipolarities and mixing ratios. Angular correlations can be used for the assignment of spins and parities for the nuclear states, and thus provide a powerful means to elucidate the structure of nuclei far from stability through β - γ - γ coincidence measurements. In order to explore the sensitivity of the new 16 clover-detector GRIFFIN γ-ray spectrometer at TRIUMF-ISAC to such γ - γ angular correlations, and to optimize its performance for these measurements we have studied a well known γ - γ cascade from 60Co decay through both experimental measurements and Geant4 simulation. Results will be shown in this talk. Work supported by the Canada Foundation for Innovation, the Natural Sciences and Engineering Research Council of Canada and the National Research Council of Canada.

  13. On the quantisation of the angular momentum

    CERN Document Server

    Ho, V B

    1994-01-01

    When a hydrogen-like atom is treated as a two dimensional system whose configuration space is multiply connected, then in order to obtain the same energy spectrum as in the Bohr model the angular momentum must be half-integral.

  14. Oral medicine in practice: angular cheilitis.

    Science.gov (United States)

    Lamey, P J; Lewis, M A

    1989-07-08

    In a series of twelve articles the authors aim to cover the more common oral medicine problems likely to be encountered in dental practice. Whenever possible, clinical photographs have been used to illustrate important points, and the text is deliberately succinct and without references. In the first article, the pathogenesis, investigation and management of angular cheilitis is reviewed.

  15. Angular vibration measurement using grating and laser interferometer

    Science.gov (United States)

    Zhang, Li; Peng, Jun

    2006-06-01

    Primary angular acceleration calibration standard is developed by CIMM to generate standard rotational angle, angular velocity and angular acceleration, which are traceable to the International System of Units (SI). It can be used to calibrate angular transducers, i.e. angular accelerometer, angular velocity transducer, and rotational angle transducer to obtain amplitude sensitivity and phase shift by sinusoidal vibration. The measurement systems based on grating and laser interferometers are introduced in this paper. The measurement system based on PXI bus instrument is used to control the angular exciter, measure the output signal of the laser interferometers and the transducer to be calibrated synchronously. The methods for calculating the amplitude and phase of sinusoidal angular movement are investigated and high performance has been achieved. It shows the standard can be used in angular movement calibration in the frequency range from 0.1Hz to 200Hz.

  16. Bexarotene ligand pharmaceuticals.

    Science.gov (United States)

    Hurst, R E

    2000-12-01

    Bexarotene (LGD-1069), from Ligand, was the first retinoid X receptor (RXR)-selective, antitumor retinoid to enter clinical trials. The company launched the drug for the treatment of cutaneous T-cell lymphoma (CTCL), as Targretin capsules, in the US in January 2000 [359023]. The company filed an NDA for Targretin capsules in June 1999, and for topical gel in December 1999 [329011], [349982] specifically for once-daily oral administration for the treatment of patients with early-stage CTCL who have not tolerated other therapies, patients with refractory or persistent early stage CTCL and patients with refractory advanced stage CTCL. The FDA approved Targretin capsules at the end of December 1999 for once-daily oral treatment of all stages of CTCL in patients refractory to at least one prior systemic therapy, at an initial dose of 300 mg/m2/day. After an NDA was submitted in December 1999 for Targretin gel, the drug received Priority Review status for use as a treatment of cutaneous lesions in patients with stage IA, IB or IIA CTCL [354836]. The FDA issued an approvable letter in June 2000, and granted marketing clearance for CTCL in the same month [370687], [372768], [372769], [373279]. Ligand had received Orphan Drug designation for this indication [329011]. At the request of the FDA, Ligand agreed to carry out certain post-approval phase IV and pharmacokinetic studies [351604]. The company filed an MAA with the EMEA for Targretin Capsules to treat lymphoma in November 1999 [348944]. The NDA for Targretin gel is based on a multicenter phase III trial that was conducted in the US, Canada, Europe and Australia involving 50 patients and a multicenter phase I/II clinical program involving 67 patients. Targretin gel was evaluated for the treatment of patients with early stage CTCL (IA-IIA) who were refractory to, intolerant to, or reached a response plateau for at least 6 months on at least two prior therapies. Efficacy results exceeded the protocol-defined response

  17. Ultra-sensitive and super-resolving angular rotation measurement based on photon orbital angular momentum using parity measurement.

    Science.gov (United States)

    Zhang, Zijing; Qiao, Tianyuan; Ma, Kun; Cen, Longzhu; Zhang, Jiandong; Wang, Feng; Zhao, Yuan

    2016-08-15

    Photon orbital angular momentum has led to many novel insights and applications in quantum measurement. Photon orbital angular momentum can increase the resolution and sensitivity of angular rotation measurement. However, quantum measurement strategy can further surpass this limit and improve the resolution of angular rotation measurement. This Letter proposes and demonstrates a parity measurement method in angular rotation measurement scheme for the first time. Parity measurement can make the resolution superior to the limit of the existing method. The sensitivity can be improved with higher orbital angular momentum photons. Moreover, this Letter gives a detailed discussion of the change of resolution and sensitivity in the presence of photon loss.

  18. Mass and Angular Momentum in General Relativity

    CERN Document Server

    Jaramillo, J L

    2010-01-01

    We present an introduction to mass and angular momentum in General Relativity. After briefly reviewing energy-momentum for matter fields, first in the flat Minkowski case (Special Relativity) and then in curved spacetimes with or without symmetries, we focus on the discussion of energy-momentum for the gravitational field. We illustrate the difficulties rooted in the Equivalence Principle for defining a local energy-momentum density for the gravitational field. This leads to the understanding of gravitational energy-momentum and angular momentum as non-local observables that make sense, at best, for extended domains of spacetime. After introducing Komar quantities associated with spacetime symmetries, it is shown how total energy-momentum can be unambiguously defined for isolated systems, providing fundamental tests for the internal consistency of General Relativity as well as setting the conceptual basis for the understanding of energy loss by gravitational radiation. Finally, several attempts to formulate q...

  19. Angular MET sensor for precise azimuth determination

    Science.gov (United States)

    Zaitsev, Dmitry; Antonov, Alexander; Krishtop, Vladimir

    2016-12-01

    This paper describes using a MET-based low-noise angular motion sensor to precisely determine azimuth direction in a dynamic-scheme method of measuring Earth's rotation velocity vector. The scheme includes installing a sensor on a rotating platform so that it could scan a space and seek for the position of highest Earth's rotation vector projection on its axis. This method is very efficient provided a low-noise sensor is used. We take a low-cost angular sensor based on MET (molecular electronic transduction) technology. Sensors of this kind were originally developed for the seismic activity monitoring and are well-known for very good noise performance and high sensitivity. This approach, combined with use of special signal processing algorithms, allowed for reaching the accuracy of 0.07° for a measurement time of 200 seconds.

  20. Angular momentum in cluster Spherical Collapse Model

    CERN Document Server

    Cupani, Guido; Mardirossian, Fabio

    2011-01-01

    Our new formulation of the Spherical Collapse Model (SCM-L) takes into account the presence of angular momentum associated with the motion of galaxy groups infalling towards the centre of galaxy clusters. The angular momentum is responsible for an additional term in the dynamical equation which is useful to describe the evolution of the clusters in the non-equilibrium region which is investigated in the present paper. Our SCM-L can be used to predict the profiles of several strategic dynamical quantities as the radial and tangential velocities of member galaxies, and the total cluster mass. A good understanding of the non-equilibrium region is important since it is the natural scenario where to study the infall in galaxy clusters and the accretion phenomena present in these objects. Our results corroborate previous estimates and are in very good agreement with the analysis of recent observations and of simulated clusters.

  1. CMB Anisotropies Total Angular Momentum Method

    CERN Document Server

    Hu, W; Hu, Wayne; White, Martin

    1997-01-01

    A total angular momentum representation simplifies the radiation transport problem for temperature and polarization anisotropy in the CMB. Scattering terms couple only the quadrupole moments of the distributions and each moment corresponds directly to the observable angular pattern on the sky. We develop and employ these techniques to study the general properties of anisotropy generation from scalar, vector and tensor perturbations to the metric and the matter, both in the cosmological fluids and from any seed perturbations (e.g.~defects) that may be present. The simpler, more transparent form and derivation of the Boltzmann equations brings out the geometric and model-independent aspects of temperature and polarization anisotropy formation. Large angle scalar polarization provides a robust means to distinguish between isocurvature and adiabatic models for structure formation in principle. Vector modes have the unique property that the CMB polarization is dominated by magnetic type parity at small angles and ...

  2. The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Marriage, Tobias; Ali, A.; Amiri, M.; Appel, J. W.; Araujo, D.; Bennett, C. L.; Boone, F.; Chan, M.; Cho, H.; Chuss, D. T.; Colazo, F.; Crowe, E.; Denis, K.; Dünner, R.; Eimer, J.; Essinger-Hileman, T.; Gothe, D.; Halpern, M.; Harrington, K.; Hilton, G.; Hinshaw, G. F.; Huang, C.; Irwin, K.; Jones, G.; Karakla, J.; Kogut, A. J.; Larson, D.; Limon, M.; Lowry, L.; Mehrle, N.; Miller, A. D.; Miller, N.; Moseley, S. H.; Novak, G.; Reintsema, C.; Rostem, K.; Stevenson, T.; Towner, D.; U-Yen, K.; Wagner, E.; Watts, D.; Wollack, E.; Xu, Z.; Zeng, L.

    2014-01-01

    Some of the most compelling inflation models predict a background of primordial gravitational waves (PGW) detectable by their imprint of a curl-like "B-mode" pattern in the polarization of the Cosmic Microwave Background (CMB). The Cosmology Large Angular Scale Surveyor (CLASS) is a novel array of telescopes to measure the B-mode signature of the PGW. By targeting the largest angular scales (>2°) with a multifrequency array, novel polarization modulation and detectors optimized for both control of systematics and sensitivity, CLASS sets itself apart in the field of CMB polarization surveys and opens an exciting new discovery space for the PGW and inflation. This poster presents an overview of the CLASS project.

  3. Quantum Entanglement of Very High Angular Momenta

    CERN Document Server

    Fickler, Robert; Plick, William N; Krenn, Mario; Schaeff, Christoph; Ramelow, Sven; Zeilinger, Anton

    2012-01-01

    Single photons with helical phase structure may carry a quantized amount of orbital angular momentum (OAM) and are of great interest in quantum information science and fundamental tests of quantum theory. Since there is no theoretical upper limit on how many quanta of OAM a single photon can carry, those systems offer the possibility to create superpositions for one particle and entanglement between two particles with an arbitrary high difference in the quantum number. By transferring polarization entanglement to the OAM degree-of-freedom with an interferometric scheme, we created and observed entanglement up to $600\\bar{h}$ difference in the orbital angular momentum. To our knowledge, we have thus demonstrated entanglement of the highest quantum number in any experiment so far. The only restrictive factor towards even higher numbers arises due to current technical limitations. Furthermore, we show experimentally that the entanglement of very high OAM can be used to improve applications, like the sensitivity ...

  4. Bell inequalities with continuous angular variables

    CERN Document Server

    Borges, Carolina V S; Keller, Arne

    2011-01-01

    We consider bipartite quantum systems characterized by a continuous angular variable \\theta \\in [-\\pi, \\pi[, representing, for instance, the position of a particle on a circle. We show how to reveal non-locality on this type of system using inequalities similar to CHSH ones, originally derived for bipartite spin 1/2 like systems. Such inequalities involve correlated measurement of continuous angular functions and are equivalent to the continuous superposition of CHSH inequalities acting on bidimensional subspaces of the infinite dimensional Hilbert space. As an example, we discuss in detail one application of our results, and we derive inequalities based on orientation correlation measurements. The introduced Bell-type inequalities open the perspective of new and simpler experiments to test non locality on a variety of quantum systems described by continuous variables.

  5. Coherent Control of Photoelectron Wavepacket Angular Interferograms

    OpenAIRE

    Hockett, Paul; Wollenhaupt, Matthias; Baumert, Thomas

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the cohere...

  6. Angular resolution of stacked resistive plate chambers

    CERN Document Server

    Samuel, Deepak; Murgod, Lakshmi P

    2016-01-01

    We present here detailed derivations of mathematical expressions for the angular resolution of a set of stacked resistive plate chambers (RPCs). The expressions are validated against experimental results using data collected from the prototype detectors (without magnet) of the upcoming India-based Neutrino Observatory (INO). In principle, these expressions can be used for any other detector with an architecture similar to that of RPCs.

  7. Angular Momentum Sharing in Dissipative Collisions

    Science.gov (United States)

    Casini, G.; Poggi, G.; Bini, M.; Calamai, S.; Maurenzig, P. R.; Olmi, A.; Pasquali, G.; Stefanini, A. A.; Taccetti, N.; Steckmeyer, J. C.; Laforest, R.; Saint-Laurent, F.

    1999-09-01

    Light charged particles emitted by the projectilelike fragment were measured in the direct and reverse collision of 93Nb and 116Sn at 25A MeV. The experimental multiplicities of hydrogen and helium particles as a function of the primary mass of the emitting fragment show evidence for a correlation with net mass transfer. The ratio of hydrogen and helium multiplicities points to a dependence of the angular momentum sharing on the net mass transfer.

  8. Angular momentum sharing in dissipative collisions

    CERN Document Server

    Casini, G; Bini, M; Calamai, S; Maurenzig, P R; Olmi, A; Pasquali, G; Stefanini, A A; Taccetti, N; Steckmeyer, J C; Laforest, R; Saint-Laurent, F

    1999-01-01

    Light charged particles emitted by the projectile-like fragment were measured in the direct and reverse collision of $^{93}$Nb and $^{116}$Sn at 25 AMeV. The experimental multiplicities of Hydrogen and Helium particles as a function of the primary mass of the emitting fragment show evidence for a correlation with net mass transfer. The ratio of Hydrogen and Helium multiplicities points to a dependence of the angular momentum sharing on the net mass transfer.

  9. Angular cheilitis, part 1: local etiologies.

    Science.gov (United States)

    Park, Kelly K; Brodell, Robert T; Helms, Stephen E

    2011-06-01

    Angular cheilitis (AC) is a common condition characterized by erythema, moist maceration, ulceration, and crusting at the corners of the mouth. This article focuses on the common local factors that act alone and in combination to produce AC. These factors are categorized as irritant, allergic, and infectious causes. Identifying the underlying etiology of AC is a critical step in developing an effective treatment plan for this condition.

  10. The Cosmology Large Angular Scale Surveyor

    CERN Document Server

    Harrington, Kathleen; Ali, Aamir; Appel, John W; Bennett, Charles L; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T; Colazo, Felipe; Dahal, Sumit; Denis, Kevin; Dünner, Rolando; Eimer, Joseph; Essinger-Hileman, Thomas; Fluxa, Pedro; Halpern, Mark; Hilton, Gene; Hinshaw, Gary F; Hubmayr, Johannes; Iuliano, Jeffery; Karakla, John; McMahon, Jeff; Miller, Nathan T; Moseley, Samuel H; Palma, Gonzalo; Parker, Lucas; Petroff, Matthew; Pradenas, Bastián; Rostem, Karwan; Sagliocca, Marco; Valle, Deniz; Watts, Duncan; Wollack, Edward; Xu, Zhilei; Zeng, Lingzhen

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from inflation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145/217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70\\% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad f...

  11. A neural circuit for angular velocity computation

    Directory of Open Access Journals (Sweden)

    Samuel B Snider

    2010-12-01

    Full Text Available In one of the most remarkable feats of motor control in the animal world, some Diptera, such as the housefly, can accurately execute corrective flight maneuvers in tens of milliseconds. These reflexive movements are achieved by the halteres, gyroscopic force sensors, in conjunction with rapidly-tunable wing-steering muscles. Specifically, the mechanosensory campaniform sensilla located at the base of the halteres transduce and transform rotation-induced gyroscopic forces into information about the angular velocity of the fly's body. But how exactly does the fly's neural architecture generate the angular velocity from the lateral strain forces on the left and right halteres? To explore potential algorithms, we built a neuro-mechanical model of the rotation detection circuit. We propose a neurobiologically plausible method by which the fly could accurately separate and measure the three-dimensional components of an imposed angular velocity. Our model assumes a single sign-inverting synapse and formally resembles some models of directional selectivity by the retina. Using multidimensional error analysis, we demonstrate the robustness of our model under a variety of input conditions. Our analysis reveals the maximum information available to the fly given its physical architecture and the mathematics governing the rotation-induced forces at the haltere's end knob.

  12. The Cosmology Large Angular Scale Surveyor (CLASS)

    Science.gov (United States)

    Harrington, Kathleen; Marriange, Tobias; Aamir, Ali; Appel, John W.; Bennett, Charles L.; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T.; Colazo, Felipe; Denis, Kevin; Moseley, Samuel H.; Rostem, Karwan; Wollack, Edward

    2016-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is a four telescope array designed to characterize relic primordial gravitational waves from in ation and the optical depth to reionization through a measurement of the polarized cosmic microwave background (CMB) on the largest angular scales. The frequencies of the four CLASS telescopes, one at 38 GHz, two at 93 GHz, and one dichroic system at 145/217 GHz, are chosen to avoid spectral regions of high atmospheric emission and span the minimum of the polarized Galactic foregrounds: synchrotron emission at lower frequencies and dust emission at higher frequencies. Low-noise transition edge sensor detectors and a rapid front-end polarization modulator provide a unique combination of high sensitivity, stability, and control of systematics. The CLASS site, at 5200 m in the Chilean Atacama desert, allows for daily mapping of up to 70% of the sky and enables the characterization of CMB polarization at the largest angular scales. Using this combination of a broad frequency range, large sky coverage, control over systematics, and high sensitivity, CLASS will observe the reionization and recombination peaks of the CMB E- and B-mode power spectra. CLASS will make a cosmic variance limited measurement of the optical depth to reionization and will measure or place upper limits on the tensor-to-scalar ratio, r, down to a level of 0.01 (95% C.L.).

  13. Angular cheilitis: a clinical and microbial study.

    Science.gov (United States)

    Ohman, S C; Dahlén, G; Möller, A; Ohman, A

    1986-04-01

    The purpose of this prospective study was to re-examine the relative importance of various factors in the pathogenesis of angular cheilitis. Sixty-four patients with cheilitis were examined clinically and microbiologically. In addition, a subsample of 23 patients was examined for serum iron and transferrin. The clinical appearance of the lip lesions fell into 4 categories. A ground rhagad at the corner of the mouth involving adjacent skin, was the most frequent type among dentate patients, whereas among denture wearers a deep lesion following the labial marginal sulcus was frequently observed. Dentate patients and denture wearers with cheilitis often had atopic constitution or cutaneous diseases. Pathogenic microorganisms were cultured from the lesions in all 64 patients; Staphylococcus aureus in 40 patients and Candida albicans in 45. The results of this study indicate a correlation between angular cheilitis and pathogenic microorganisms. Furthermore, among dentate patients, a correlation exists between cutaneous discomfort and angular cheilitis. Other etiological factors suggested for this disorder were found to be of subordinate importance.

  14. Angular momentum of a brane-world model

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    In this paper we discuss the properties of the general covariant angular momentum of a fivedimensional brane-world model. Through calculating the total angular momentum of this model, we are able to analyze the properties of the total angular momentum in the inflationary RS model. We show that the space-like components of the total angular momentum of the inflationary RS model are all zero while the others are non-zero, which agrees with the results from ordinary RS model.

  15. Localization of angular momentum in optical waves propagating through turbulence.

    Science.gov (United States)

    Sanchez, Darryl J; Oesch, Denis W

    2011-12-01

    This is the first in a series of papers demonstrating that photons with orbital angular momentum can be created in optical waves propagating through distributed turbulence. The scope of this first paper is much narrower. Here, we demonstrate that atmospheric turbulence can impart non-trivial angular momentum to beams and that this non-trivial angular momentum is highly localized. Furthermore, creation of this angular momentum is a normal part of propagation through atmospheric turbulence.

  16. Study of the Angular Distribution of Scintillation Photons

    CERN Document Server

    Fornaro, Giulia Alice; Ghezzi, Alessio; Knapitsch, Arno; Modrzynski, Pawel; Pizzichemi, Marco; Lecoq, Paul; Auffray, Etiennette

    2014-01-01

    This paper presents a characterization method to experimentally determine the angular distribution of scintillation light. By exciting LYSO crystals with a radioactive source, we measured the light angular profiles obtained with samples of different geometries in different conditions of wrapping. We also measured the angular distribution of light emitting in glue and compared it with the one emitting in air. Angular distribution of light output of photonic crystals is also provided. Consistency of the measurements is verified with conventional light output measurements.

  17. Angular Momentum of a Brane-world Model

    CERN Document Server

    Jia, Bei; Zhang, Peng-Ming

    2008-01-01

    In this paper we discuss the properties of the general covariant angular momentum of a five-dimensional brane-world model. Through calculating the total angular momentum of this model, we are able to analyze the properties of the total angular momentum in the inflationary RS model. We show that the space-like components of the total angular momentum of are all zero while the others are non-zero, which agrees with the results from ordinary RS model.

  18. Poly[[bis(μ-4,4′-bipyridyl-κ2N:N′bis(thiocyanato-κNmanganese(II] diethyl ether disolvate

    Directory of Open Access Journals (Sweden)

    Mario Wriedt

    2010-07-01

    Full Text Available In the title compound, {[Mn(NCS2(C10H8N22]·2C4H10O}n, the MnII ion is coordinated by four N-bonded 4,4′-bipyridine (bipy ligands and two N-bonded thiocyanate anions in a distorted octahedral coordination geometry. The asymmetric unit consists of one MnII ion and two bipy ligands each located on a twofold rotation axis, as well as one thiocyanate anion and one diethyl ether molecule in general positions. In the crystal structure, the metal centers with terminally bonded thicyanate anions are bridged by the bipy ligands into layers parallel to (001. The diethyl ether solvent molecules occupy the voids of the structure.

  19. The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Ali, Aamir; Appel, John W.; Bennett, Charles L.; Boone, Fletcher; Brewer, Michael; Chan, Manwei; Chuss, David T.; Colazo, Felipe; Dahal, Sumit; Denis, Kevin; Dünner, Rolando; Eimer, Joseph; Essinger-Hileman, Thomas; Fluxa, Pedro; Halpern, Mark; Hilton, Gene; Hinshaw, Gary F.; Hubmayr, Johannes; Iuliano, Jeffrey; Karakla, John; Marriage, Tobias; McMahon, Jeff; Miller, Nathan; Moseley, Samuel H.; Palma, Gonzalo; Parker, Lucas; Petroff, Matthew; Pradenas, Bastián; Rostem, Karwan; Sagliocca, Marco; Valle, Deniz; Watts, Duncan; Wollack, Edward; Xu, Zhilei; Zeng, Lingzhen

    2017-01-01

    The Cosmology Large Angular Scale Surveryor (CLASS) is a ground based telescope array designed to measure the large-angular scale polarization signal of the Cosmic Microwave Background (CMB). The large-angular scale CMB polarization measurement is essential for a precise determination of the optical depth to reionization (from the E-mode polarization) and a characterization of inflation from the predicted polarization pattern imprinted on the CMB by gravitational waves in the early universe (from the B-mode polarization). CLASS will characterize the primordial tensor-to-scalar ratio, r, to 0.01 (95% CL).CLASS is uniquely designed to be sensitive to the primordial B-mode signal across the entire range of angular scales where it could possibly dominate over the lensing signal that converts E-modes to B-modes while also making multi-frequency observations both high and low of the frequency where the CMB-to-foreground signal ratio is at its maximum. The design enables CLASS to make a definitive cosmic-variance-limited measurement of the optical depth to scattering from reionization.CLASS is an array of 4 telescopes operating at approximately 40, 90, 150, and 220 GHz. CLASS is located high in the Andes mountains in the Atacama Desert of northern Chile. The location of the CLASS site at high altitude near the equator minimizes atmospheric emission while allowing for daily mapping of ~70% of the sky.A rapid front end Variable-delay Polarization Modulator (VPM) and low noise Transition Edge Sensor (TES) detectors allow for a high sensitivity and low systematic error mapping of the CMB polarization at large angular scales. The VPM, detectors and their coupling structures were all uniquely designed and built for CLASS.We present here an overview of the CLASS scientific strategy, instrument design, and current progress. Particular attention is given to the development and status of the Q-band receiver currently surveying the sky from the Atacama Desert and the development of

  20. Angular Goos-Hänchen effect in curved dielectric microstructures.

    Science.gov (United States)

    Tran, N H; Dutriaux, L; Balcou, P; Floch, A L; Bretenaker, F

    1995-06-01

    A macroscopic angular Goos-Hänchen effect at total reflection on curved interfaces is studied experimentally. The results are compared with the complex-angular-momentum model of quasi-critical scattering. An extremum in angular deflection, which has not yet been predicted by any theory other than exact Mie scattering computations, is identified at low size parameters.

  1. Melatonin: functions and ligands.

    Science.gov (United States)

    Singh, Mahaveer; Jadhav, Hemant R

    2014-09-01

    Melatonin is a chronobiotic substance that acts as synchronizer by stabilizing bodily rhythms. Its synthesis occurs in various locations throughout the body, including the pineal gland, skin, lymphocytes and gastrointestinal tract (GIT). Its synthesis and secretion is controlled by light and dark conditions, whereby light decreases and darkness increases its production. Thus, melatonin is also known as the 'hormone of darkness'. Melatonin and analogs that bind to the melatonin receptors are important because of their role in the management of depression, insomnia, epilepsy, Alzheimer's disease (AD), diabetes, obesity, alopecia, migraine, cancer, and immune and cardiac disorders. In this review, we discuss the mechanism of action of melatonin in these disorders, which could aid in the design of novel melatonin receptor ligands.

  2. A critique of the angular momentum sum rules and a new angular momentum sum rule

    CERN Document Server

    Bakker, B L G; Trueman, T L

    2004-01-01

    We show that the expressions in the literature for the tensorial structure of the hadronic matrix elements of the angular momentum operators J are incorrect. Given this disagreement with the published results, we have taken pains to derive the correct expressions in three different ways, two involving explicit physical wave packets and the third, totally independent, based upon the rotational properties of the state vectors. Surprisingly it turns out that the results are very sensitive to the type of relativistic spin state used to describe the motion of the particle i.e. whether a canonical (i.e. boost) state or a helicity state is utilized. We present results for the matrix elements of the angular momentum operators, valid in an arbitrary Lorentz frame, both for helicity states and canonical states. These results are relevant for the construction of angular momentum sum rules, relating the angular momentum of a nucleon to the spin and orbital angular momentum of its constituents. Moreover, we show that it i...

  3. Macrocyclic G-quadruplex ligands

    DEFF Research Database (Denmark)

    Nielsen, M C; Ulven, Trond

    2010-01-01

    G-quadruplex stabilizing compounds have recently received increased interest due to their potential application as anticancer therapeutics. A significant number of structurally diverse G-quadruplex ligands have been developed. Some of the most potent and selective ligands currently known are macr...

  4. Angular Dispersion and Deflection Function for Heavy Ion Elastic Scattering

    Institute of Scientific and Technical Information of China (English)

    BAI Zhen; MAO Rui-Shi; YUAN Xiao-Hua; Xu Zhi-Guo; ZHANG Hong-Bin; XU Hua-Gen; QI Hui-Rong; WANG Yue; JIA Fei; WU Li-Jie; DING Xian-Li; WANG Qi; GAO Qi; GAO Hui; LI Song-Lin; LI Jun-Qing; ZHANG Ya-Peng; XIAO Guo-Qing; JIN Gen-Ming; REN Zhong-Zhou; ZHOU Shan-Gui; XU Wang; HAN Jian-Long; Fan Gong-Tao; ZHANG Shuang-Quan; PANG Dan-Yang; SERGEY Yu-Kun; XIAO Zhi-Gang; XU Hu-Shan; SUN Zhi-Yu; HU Zheng-Guo; ZHANG Xue-Ying; WANG Hong-Wei

    2007-01-01

    The differential cross sections for elastic scattering products of17 F on 208 Pb have been measured.The angular dispersion plots of In(dσ/dθ)versus θ2 are obtained from the angular distribution of the elastic scattering differential cross sections.Systematical analysis on the angular dispersion for the available experimental data indicates that there is an angular dispersion turning angle at forward angular range within the grazing angle.This turning angle can be clarified as nuclear rainbow in classical deflection function.The exotic behaviour of the nuclear rainbow angle offers a new probe to investigate the halo and skin phenomena.

  5. Angular momentum evolution in laser-plasma accelerators

    CERN Document Server

    Thaury, C; Corde, S; Lehe, R; Bouteiller, M Le; Phuoc, K Ta; Davoine, X; Rax, J -M; Rousse, A; Malka, V

    2013-01-01

    The transverse properties of an electron beam are characterized by two quantities, the emittance which indicates the electron beam extend in the phase space and the angular momentum which allows for non-planar electron trajectories. Whereas the emittance of electron beams produced in laser- plasma accelerator has been measured in several experiments, their angular momentum has been scarcely studied. It was demonstrated that electrons in laser-plasma accelerator carry some angular momentum, but its origin was not established. Here we identify one source of angular momentum growth and we present experimental results showing that the angular momentum content evolves during the acceleration.

  6. Angular-momentum evolution in laser-plasma accelerators.

    Science.gov (United States)

    Thaury, C; Guillaume, E; Corde, S; Lehe, R; Le Bouteiller, M; Ta Phuoc, K; Davoine, X; Rax, J M; Rousse, A; Malka, V

    2013-09-27

    The transverse properties of an electron beam are characterized by two quantities, the emittance which indicates the electron beam extent in the phase space and the angular momentum which allows for nonplanar electron trajectories. Whereas the emittance of electron beams produced in a laser-plasma accelerator has been measured in several experiments, their angular momentum has been scarcely studied. It was demonstrated that electrons in a laser-plasma accelerator carry some angular momentum, but its origin was not established. Here we identify one source of angular-momentum growth and we present experimental results showing that the angular-momentum content evolves during the acceleration.

  7. Angular-Momentum Evolution in Laser-Plasma Accelerators

    CERN Document Server

    Thaury, C; Corde, S; Lehe, R; Le Bouteiller, M; Ta Phuoc, K; Davoine, X; Rax, J M; Rousse, A; Malka, V; 10.1103/PhysRevLett.111.135002

    2013-01-01

    The transverse properties of an electron beam are characterized by two quantities, the emittance which indicates the electron beam extent in the phase space and the angular momentum which allows for nonplanar electron trajectories. Whereas the emittance of electron beams produced in a laser-plasma accelerator has been measured in several experiments, their angular momentum has been scarcely studied. It was demonstrated that electrons in a laser-plasma accelerator carry some angular momentum, but its origin was not established. Here we identify one source of angular-momentum growth and we present experimental results showing that the angular-momentum content evolves during the acceleration.

  8. Electron energy and angular distributions in radiotherapy

    Energy Technology Data Exchange (ETDEWEB)

    Deasy, J.O.

    1992-01-01

    Electron energy and angular distributions and associated effects for radiotherapy accelerators and beta-ray ophthalmic applicators have been measured and modeled. Ophthalmic applicator extrapolation chamber calibration geometries were studied using Monte Carlo calculations and analytic methods. A large interface effect increases the surface dose by a factor of about 1.5 and makes very small gap width measurements necessary (0.1--0.2 mm). Dose deposition in tissue near the surface was simulated using the Monte Carlo technique. Charge collection in the extrapolation chamber was analytically modeled on the basis of ionized free electrons back-diffusing into the cathode, while taking into account attachment to O[sub 2] ions. Two small, portable, magnetic spectrometers for the measurement of clinical radiotherapy electron beams were constructed. One employs film as a spectrograph and is suitable for routine measurements; the second is a 90[degree] single-focusing spectrometer and uses fast pulse counting electrons and pulse-height analysis. Spectra were measured for the University of Louisville's Theratronics T20 and Philips SL25 linear accelerators. The T20 spectra were all Gaussian with energy widths of about 5%. The SL25 energy spectra were of varied shapes, with energy widths of 10--20%. Evidence of 3--7% shifts in the average energy of the SL25 beams was observed. Angular measurements were made which showed the Gaussian angular spread of the incident beam. The Monte Carlo code CYLTRAN and measured spectra were used to reconstruct depth dose curves. The peak energy structure only marginally affects the shape of the depth-dose curve, and some features of the depth-dose curves must be affected by incident straggled or widely-scattered electrons. In the absence of lower energy straggled electrons, the range parameters and the maximum dose gradient depend on the mean energy of the peak electrons.

  9. Whole-body angular momentum during stair ascent and descent.

    Science.gov (United States)

    Silverman, Anne K; Neptune, Richard R; Sinitski, Emily H; Wilken, Jason M

    2014-04-01

    The generation of whole-body angular momentum is essential in many locomotor tasks and must be regulated in order to maintain dynamic balance. However, angular momentum has not been investigated during stair walking, which is an activity that presents a biomechanical challenge for balance-impaired populations. We investigated three-dimensional whole-body angular momentum during stair ascent and descent and compared it to level walking. Three-dimensional body-segment kinematic and ground reaction force (GRF) data were collected from 30 healthy subjects. Angular momentum was calculated using a 13-segment whole-body model. GRFs, external moment arms and net joint moments were used to interpret the angular momentum results. The range of frontal plane angular momentum was greater for stair ascent relative to level walking. In the transverse and sagittal planes, the range of angular momentum was smaller in stair ascent and descent relative to level walking. Significant differences were also found in the ground reaction forces, external moment arms and net joint moments. The sagittal plane angular momentum results suggest that individuals alter angular momentum to effectively counteract potential trips during stair ascent, and reduce the range of angular momentum to avoid falling forward during stair descent. Further, significant differences in joint moments suggest potential neuromuscular mechanisms that account for the differences in angular momentum between walking conditions. These results provide a baseline for comparison to impaired populations that have difficulty maintaining dynamic balance, particularly during stair ascent and descent.

  10. New relativistic Hamiltonian: the angular magnetoelectric coupling

    Science.gov (United States)

    Paillard, Charles; Mondal, Ritwik; Berritta, Marco; Dkhil, Brahim; Singh, Surendra; Oppeneer, Peter M.; Bellaiche, Laurent

    2016-10-01

    Spin-Orbit Coupling (SOC) is a ubiquitous phenomenon in the spintronics area, as it plays a major role in allowing for enhancing many well-known phenomena, such as the Dzyaloshinskii-Moriya interaction, magnetocrystalline anisotropy, the Rashba effect, etc. However, the usual expression of the SOC interaction ħ/4m2c2 [E×p] • σ (1) where p is the momentum operator, E the electric field, σ the vector of Pauli matrices, breaks the gauge invariance required by the electronic Hamiltonian. On the other hand, very recently, a new phenomenological interaction, coupling the angular momentum of light and magnetic moments, has been proposed based on symmetry arguments: ξ/2 [r × (E × B)] M, (2) with M the magnetization, r the position, and ξ the interaction strength constant. This interaction has been demonstrated to contribute and/or give rise, in a straightforward way, to various magnetoelectric phenomena,such as the anomalous Hall effect (AHE), the anisotropic magnetoresistance (AMR), the planar Hall effect and Rashba-like effects, or the spin-current model in multiferroics. This last model is known to be the origin of the cycloidal spin arrangement in bismuth ferrite for instance. However, the coupling of the angular momentum of light with magnetic moments lacked a fundamental theoretical basis. Starting from the Dirac equation, we derive a relativistic interaction Hamiltonian which linearly couples the angular momentum density of the electromagnetic (EM) field and the electrons spin. We name this coupling the Angular MagnetoElectric (AME) coupling. We show that in the limit of uniform magnetic field, the AME coupling yields an interaction exactly of the form of Eq. (2), thereby giving a firm theoretical basis to earlier works. The AME coupling can be expressed as: ξ [E × A] • σ (3) with A being the vector potential. Interestingly, the AME coupling was shown to be complementary to the traditional SOC, and together they restore the gauge invariance of the

  11. Angular Momentum of Dark Matter Black Holes

    CERN Document Server

    Frampton, Paul H

    2016-01-01

    The putative black holes which may constitute all the dark matter are described by a Kerr metric with only two parameters, mass M and angular momentum J. There has been little discussion of J since it plays no role in the upcoming attempt at detection by microlensing. Nevertheless J does play a central role in understanding the previous lack of detection, especially of CMB distortion. We explain why bounds previously derived from lack of CMB distortion are too strong for primordial black holes with J non-vanishing. Almost none of the dark matter black holes can be from stellar collapse, and nearly all are primordial, to avoid excessive CMB distortion.

  12. Angular Distributions of Discrete Mesoscale Mapping Functions

    Directory of Open Access Journals (Sweden)

    Kroszczyński Krzysztof

    2015-08-01

    Full Text Available The paper presents the results of analyses of numerical experiments concerning GPS signal propagation delays in the atmosphere and the discrete mapping functions defined on their basis. The delays were determined using data from the mesoscale non-hydrostatic weather model operated in the Centre of Applied Geomatics, Military University of Technology. A special attention was paid to investigating angular characteristics of GPS slant delays for low angles of elevation. The investigation proved that the temporal and spatial variability of the slant delays depends to a large extent on current weather conditions

  13. Angular momentum evolution of galaxies in EAGLE

    CERN Document Server

    Lagos, Claudia del P; Stevens, Adam R H; Cortese, Luca; Padilla, Nelson D; Davis, Timothy A; Contreras, Sergio; Croton, Darren

    2016-01-01

    We use EAGLE to study the specific angular momentum of galaxies, j, at z1.2, and then increase as lstars~a. Galaxy mergers reduce lstars by a factor of 2-3. These tracks are driven by both the evolution of the total jstars but also its radial distribution. Regardless of the aperture used to measure j, two distinct channels leading to low jstars in galaxies at z=0 are identified: (i) galaxy mergers, and (ii) early formation of most of the stars.

  14. Angular momentum sensitive two-center interference.

    Science.gov (United States)

    Ilchen, M; Glaser, L; Scholz, F; Walter, P; Deinert, S; Rothkirch, A; Seltmann, J; Viefhaus, J; Decleva, P; Langer, B; Knie, A; Ehresmann, A; Al-Dossary, O M; Braune, M; Hartmann, G; Meissner, A; Tribedi, L C; AlKhaldi, M; Becker, U

    2014-01-17

    In quantum mechanics the Young-type double-slit experiment can be performed with electrons either traveling through a double slit or being coherently emitted from two inversion symmetric molecular sites. In the latter one the valence photoionization cross sections of homonuclear diatomic molecules were predicted to oscillate over kinetic energy almost 50 years ago. Beyond the direct proof of the oscillatory behavior of these photoionization cross sections σ, we show that the angular distribution of the emitted electrons reveals hitherto unexplored information on the relative phase shift between the corresponding partial waves through two-center interference patterns.

  15. Lunar influence on equatorial atmospheric angular momentum

    Science.gov (United States)

    Bizouard, C.; Zotov, L.; Sidorenkov, N.

    2015-08-01

    This study investigates the relationship between the equatorial atmospheric angular momentum oscillation in the non-rotating frame and lunar tidal potential. Between 2 and 30 days, the corresponding equatorial component is mostly constituted of prograde circular motions, especially of a harmonic at 13.6 days, and of a weekly broad band variation. A simple equilibrium tide model explains the 13.6-day pressure term as result of the O1 lunar tide; the tidal lunar origin of the whole band from 2 to 30 days is attested by specific features, not occurring for seasonal band dominated by the solar thermal effect.

  16. The Cosmology Large Angular Scale Surveyor (CLASS)

    Science.gov (United States)

    Eimer, Joseph; Ali, A.; Amiri, M.; Appel, J. W.; Araujo, D.; Bennett, C. L.; Boone, F.; Chan, M.; Cho, H.; Chuss, D. T.; Colazo, F.; Crowe, E.; Denis, K.; Dünner, R.; Essinger-Hileman, T.; Gothe, D.; Halpern, M.; Harrington, K.; Hilton, G.; Hinshaw, G. F.; Huang, C.; Irwin, K.; Jones, G.; Karakla, J.; Kogut, A. J.; Larson, D.; Limon, M.; Lowry, L.; Marriage, T.; Mehrle, N.; Miller, A. D.; Miller, N.; Moseley, S. H.; Novak, G.; Reintsema, C.; Rostem, K.; Stevenson, T.; Towner, D.; U-Yen, K.; Wagner, E.; Watts, D.; Wollack, E.; Xu, Z.; Zeng, L.

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an array of telescopes designed to search for the signature of inflation in the polarization of the Cosmic Microwave Background (CMB). By combining the strategy of targeting large scales (>2 deg) with novel front-end polarization modulation and novel detectors at multiple frequencies, CLASS will pioneer a new frontier in ground-based CMB polarization surveys. In this talk, I give an overview of the CLASS instrument, survey, and outlook on setting important new limits on the energy scale of inflation.

  17. Angular Momentum Sensitive Two-Center Interference

    Science.gov (United States)

    Ilchen, M.; Glaser, L.; Scholz, F.; Walter, P.; Deinert, S.; Rothkirch, A.; Seltmann, J.; Viefhaus, J.; Decleva, P.; Langer, B.; Knie, A.; Ehresmann, A.; Al-Dossary, O. M.; Braune, M.; Hartmann, G.; Meissner, A.; Tribedi, L. C.; AlKhaldi, M.; Becker, U.

    2014-01-01

    In quantum mechanics the Young-type double-slit experiment can be performed with electrons either traveling through a double slit or being coherently emitted from two inversion symmetric molecular sites. In the latter one the valence photoionization cross sections of homonuclear diatomic molecules were predicted to oscillate over kinetic energy almost 50 years ago. Beyond the direct proof of the oscillatory behavior of these photoionization cross sections σ, we show that the angular distribution of the emitted electrons reveals hitherto unexplored information on the relative phase shift between the corresponding partial waves through two-center interference patterns.

  18. Angular processes related to Cauchy random walks

    CERN Document Server

    Cammarota, Valemtina

    2011-01-01

    We study the angular process related to random walks in the Euclidean and in the non-Euclidean space where steps are Cauchy distributed. This leads to different types of non-linear transformations of Cauchy random variables which preserve the Cauchy density. We give the explicit form of these distributions for all combinations of the scale and the location parameters. Continued fractions involving Cauchy random variables are analyzed. It is shown that the $n$-stage random variables are still Cauchy distributed with parameters related to Fibonacci numbers. This permits us to show the convergence in distribution of the sequence to the golden ratio.

  19. CMB anisotropies: Total angular momentum method

    Science.gov (United States)

    Hu, Wayne; White, Martin

    1997-07-01

    A total angular momentum representation simplifies the radiation transport problem for temperature and polarization anisotropy in the cosmic microwave background (CMB). Scattering terms couple only the quadrupole moments of the distributions and each moment corresponds directly to the observable angular pattern on the sky. We develop and employ these techniques to study the general properties of anisotropy generation from scalar, vector, and tensor perturbations to the metric and the matter, both in the cosmological fluids and from any seed perturbations (e.g., defects) that may be present. The simpler, more transparent form and derivation of the Boltzmann equations brings out the geometric and model-independent aspects of temperature and polarization anisotropy formation. Large angle scalar polarization provides a robust means to distinguish between isocurvature and adiabatic models for structure formation in principle. Vector modes have the unique property that the CMB polarization is dominated by magnetic-type parity at small angles (a factor of 6 in power compared with 0 for the scalars and 8/13 for the tensors) and hence potentially distinguishable independent of the model for the seed. The tensor modes produce a different sign from the scalars and vectors for the temperature-polarization correlations at large angles. We explore conditions under which one perturbation type may dominate over the others including a detailed treatment of the photon-baryon fluid before recombination.

  20. Detection and recognition of angular frequency patterns.

    Science.gov (United States)

    Wilson, Hugh R; Propp, Roni

    2015-05-01

    Previous research has extensively explored visual encoding of smoothly curved, closed contours described by sinusoidal variation of pattern radius as a function of polar angle (RF patterns). Although the contours of many biologically significant objects are curved, we also confront shapes with a more jagged and angular appearance. To study these, we introduce here a novel class of visual stimuli that deform smoothly from a circle to an equilateral polygon with N sides (AF patterns). Threshold measurements reveal that both AF and RF patterns can be discriminated from circles at the same deformation amplitude, approximately 18.0arcsec, which is in the hyperacuity range. Thresholds were slightly higher for patterns with 3.0 cycles than for those with 5.0 cycles. Discrimination between AF and RF patterns was 75% correct at an amplitude that was approximately 3.0 times the threshold amplitude, which implies that AF and RF patterns activate different neural populations. Experiments with jittered patterns in which the contour was broken into several pieces and shifted inward or outward had much less effect on AF patterns than on RF patterns. Similarly, thresholds for single angles of AF patterns showed no significant difference from thresholds for the entire AF pattern. Taken together, these results imply that the visual system incorporates angles explicitly in the representation of closed object contours, but it suggests that angular contours are represented more locally than are curved contours.

  1. The angular momentum of a relative equilibrium

    CERN Document Server

    Chenciner, Alain

    2011-01-01

    There are two main reasons why relative equilibria of N point masses under the influence of Newton attraction are mathematically more interesting to study when space dimension is at least 4: On the one hand, in a higher dimensional space, a relative equilibrium is determined not only by the initial configuration but also by the choice of a complex structure on the space where the motion takes place; in particular, its angular momentum depends on this choice; On the other hand, relative equilibria are not necessarily periodic: if the configuration is "balanced" but not central, the motion is in general quasi-periodic. In this exploratory paper we address the following question, which touches both aspects: what are the possible frequencies of the angular momentum of a given central (or balanced) configuration and at what values of these frequencies bifurcations from periodic to quasi-periodic relative equilibria do occur ? We give a full answer for relative equilibrium motions in dimension 4 and conjecture that...

  2. Tuning the cytotoxic properties of new ruthenium(III) and ruthenium(II) complexes with a modified bis(arylimino)pyridine Schiff base ligand using bidentate pyridine-based ligands.

    Science.gov (United States)

    Garza-Ortiz, Ariadna; Maheswari, Palanisamy Uma; Lutz, Martin; Siegler, Maxime A; Reedijk, Jan

    2014-06-01

    Synthesis, spectroscopy, characterization, structures, and cytotoxicity studies of 2,6-bis(2,6-diisopropylphenyliminomethyl)pyridine (LLL) ruthenium compounds are described. The starting compound [RuCl3(LLL)] has been fully characterized using IR spectroscopy, UV-vis spectroscopy, electrospray ionization mass spectrometry, and NMR spectroscopy. In addition, the crystal structure of the ligand LLL has been determined using single-crystal X-ray diffraction. With the ruthenium(III) trichloride compound as starting material, a new family of Ru(II) complexes with a number of neutral and charged bidentate co-ligands have been synthesized and used for characterization and cytotoxicity studies. The synthesis of the corresponding [Ru(II)LLL(LL)Cl](+/0) complexes with co-ligands- LL is 1,10-phenanthroline, 2,2'-bipyridyl, 2-(phenylazo)pyridine, 2-(phenylazo)-3-methylpyridine, 2-(tolylazo)pyridine, or the anionic 2-picolinate-is reported. Analytical, spectroscopic (IR spectroscopy, UV-vis spectroscopy, (1)H NMR spectroscopy, and electrospray ionization mass spectrometry), and structural characterization of the new compounds is described. Crystal structure analyses of two Ru(II) compounds show a slightly distorted octahedral Ru(II) geometry with tridentate LLL coordinated in a planar meridional fashion, and the chelating co-ligand (LL) and a chloride ion complete the octahedron. The co-ligand plays a significant role in modulating the physicochemical and cytotoxic properties of these new ruthenium complexes. The in vitro cytotoxicity of these new Ru(II) complexes (half-maximal inhibitory concentration, IC50, of 0.5-1.5 μM), in comparison with the parent Ru(III) compound (half-maximal inhibitory concentration of 3.9-4.3 μM) is higher for several of the human cancer cell lines tested. The cytotoxic activity of some of the new ruthenium compounds is even higher than that of cisplatin in the same cancer cell lines. The cytotoxicity of these new anticancer compounds is

  3. Glutamate receptor ligands

    DEFF Research Database (Denmark)

    Guldbrandt, Mette; Johansen, Tommy N; Frydenvang, Karla Andrea;

    2002-01-01

    Homologation and substitution on the carbon backbone of (S)-glutamic acid [(S)-Glu, 1], as well as absolute stereochemistry, are structural parameters of key importance for the pharmacological profile of (S)-Glu receptor ligands. We describe a series of methyl-substituted 2-aminoadipic acid (AA......-ray crystallographic analyses, chemical correlation, and CD spectral analyses. The effects of the individual stereoisomers at ionotropic and metabotropic (S)-Glu receptors (iGluRs and mGluRs) were characterized. Compounds with S-configuration at the alpha-carbon generally showed mGluR2 agonist activity of similar...... limited effect on pharmacology. Structure-activity relationships at iGluRs in the rat cortical wedge preparation showed a complex pattern, some compounds being NMDA receptor agonists [e.g., EC(50) =110 microM for (2S,5RS)-5-methyl-AA (6a,b)] and some compounds showing NMDA receptor antagonist effects [e...

  4. Thiodiacetate-manganese chemistry with N ligands: unique control of the supramolecular arrangement over the metal coordination mode.

    Science.gov (United States)

    Grirrane, Abdessamad; Pastor, Antonio; Galindo, Agustín; Alvarez, Eleuterio; Mealli, Carlo; Ienco, Andrea; Orlandini, Annabella; Rosa, Patrick; Caneschi, Andrea; Barra, Anne-Laure; Sanz, Javier Fernández

    2011-09-12

    Compounds based on the Mn-tda unit (tda=S(CH(2)COO)(2)(-2) ) and N co-ligands have been analyzed in terms of structural, spectroscopic, magnetic properties and DFT calculations. The precursors [Mn(tda)(H(2)O)](n) (1) and [Mn(tda)(H(2)O)(3)]·H(2)O (2) have been characterized by powder and X-ray diffraction, respectively. Their derivatives with bipyridyl-type ligands have formulas [Mn(tda)(bipy)](n) (3), [{Mn(N-N)}(2)(μ-H(2)O)(μ-tda)(2)](n) (N-N=4,4'-Me(2)bipy (4), 5,5'-Me(2)bipy, (5)) and [Mn(tda){(MeO)(2)bipy}·2H(2)O](n) (6). Depending on the presence/position of substituents at bipy, the supramolecular arrangement can affect the metal coordination type. While all the complexes consist of 1D coordination polymers, only 3 has a copper-acetate core with local trigonal prismatic metal coordination. The presence of substituents in 4-6, together with water co-ligands, reduces the supramolecular interactions and typical octahedral Mn(II) ions are observed. The unicity of 3 is also supported by magnetic studies and by DFT calculations, which confirm that the unusual Mn coordination is a consequence of extended noncovalent interactions (π-π stacking) between bipy ligands. Moreover, 3 is an example of broken paradigm for supramolecular chemistry. In fact, the desired stereochemical properties are achieved by using rigid metal building blocks, whereas in 3 the accumulation of weak noncovalent interactions controls the metal geometry. Other N co-ligands have also been reacted with 1 to give the compounds [Mn(tda)(phen)](2)·6H(2)O (7) (phen=1,10-phenanthroline), [Mn(tda)(terpy)](n) (8) (terpy=2,2':6,2''-terpyridine), [Mn(tda)(pyterpy)](n) (9) (pyterpy=4'-(4-pyridyl)-2,2':6,2''-terpyridine), [Mn(tda)(tpt)(H(2)O)]·2H(2)O (10) and [Mn(tda)(tpt)(H(2)O)](2)·2H(2)O (11) (tpt=2,4,6-tris(2-pyridyl)-1,3,5-triazine). Their identified mono-, bi- or polynuclear structures clearly indicate that hydrogen bonding is variously competitive with π-π stacking.

  5. An EM Induction Hi-Speed Rotation Angular Rate Sensor.

    Science.gov (United States)

    Li, Kai; Li, Yuan; Han, Yan

    2017-03-17

    A hi-speed rotation angular rate sensor based on an electromagnetic induction signal is proposed to provide a possibility of wide range measurement of high angular rates. An angular rate sensor is designed that works on the principle of electromagnetism (EM) induction. In addition to a zero-phase detection technique, this sensor uses the feedback principle of magnetic induction coils in response to a rotating magnetic field. It solves the challenge of designing an angular rate sensor that is suitable for both low and high rotating rates. The sensor was examined for angular rate measurement accuracy in simulation tests using a rotary table. The results show that it is capable of measuring angular rates ranging from 1 rps to 100 rps, with an error within 1.8‰ of the full scale (FS). The proposed sensor is suitable to measurement applications where the rotation angular rate is widely varied, and it contributes to design technology advancements of real-time sensors measuring angular acceleration, angular rate, and angular displacement of hi-speed rotary objects.

  6. Complexation Studies of Bidentate Heterocyclic N-Donor Ligands with Nd(III) and Am(III)

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, Mark; Hoch, Courtney L.; Sinkov, Sergey I.; Meier, Patrick; Lumetta, Gregg J.; Nash, Kenneth L.

    2011-11-28

    A new bidentate nitrogen donor complexing agent that combines pyridine and triazole functional groups, 2-((4-phenyl-1H-1,2,3-triazol-1-yl)methyl)pyridine (PTMP), has been synthesized. The strength of its complexes with trivalent americium (Am3+) and neodymium (Nd3+) in anhydrous methanol has been evaluated using spectrophotometric techniques. The purpose of this investigation is to assess this ligand (as representative of a class of similarly structured species) as a possible model compound for the challenging separation of trivalent actinides from lanthanides. This separation, important in the development of advanced nuclear fuel cycles, is best achieved through the agency of multidentate chelating agents containing some number of nitrogen or sulfur donor groups. To evaluate the relative strength of the bidentate complexes, the derived constants are compared to those of the same metal ions with 2,2*-bipyridyl (bipy), 1,10-phenanthroline (phen), and 2-pyridin-2-yl-1H-benzimidazole (PBIm). At issue is the relative affinity of the triazole moiety for trivalent f element ions. For all ligands, the derived stability constants are higher for Am3+ than Nd3+. In the case of Am3+ complexes with phen and PBIm, the presence of 1:2 (AmL2) species is indicated. Possible separations are suggested based on the relative stability and stoichiometry of the Am3+ and Nd3+ complexes. It can be noted that the 1,2,3-triazolyl group imparts a potentially useful selectivity for trivalent actinides (An(III)) over trivalent lanthanides (Ln(III)), though the attainment of higher complex stoichiometries in actinide compared with lanthanide complexes may be an important driver for developing successful separations.

  7. Electron Energy and Angular Distributions in Radiotherapy.

    Science.gov (United States)

    Deasy, Joseph Owen

    1992-01-01

    Electron energy and angular distributions and associated effects for radiotherapy accelerators and beta -ray ophthalmic applicators have been measured and modeled. Ophthalmic applicator extrapolation chamber calibration geometries were studied using Monte Carlo calculations and analytic methods. A large interface effect increases the surface dose by a factor of about 1.5 and makes very small gap width measurements necessary (0.1-0.2 mm). Dose deposition in tissue near the surface was simulated using the Monte Carlo technique. Charge collection in the extrapolation chamber was analytically modeled on the basis of ionized free electrons back-diffusing into the cathode, while taking into account attachment to O_2 ions. Previous models underpredict the charge loss, mainly because they assume that all the charge carriers are ions. Two small, portable, magnetic spectrometers for the measurement of clinical radiotherapy electron beams were constructed. One employs film as a spectrograph and is suitable for routine measurements; the second is a 90^circ single-focusing spectrometer and uses fast pulse counting electronics and pulse-height analysis. Tests with monoenergetic electron beams at the National Research Council of Canada's electron linear accelerator showed that the system is free from spectral distortion and verified the spectrometers' energy calibrations. Spectra were measured for the University of Louisville's Theratronics T20 and Philips SL25 linear accelerators. The T20 spectra were all nearly Gaussian in shape with energy widths of about 5%. The SL25 energy spectra were of varied shapes, with energy widths of 10-20%. Evidence of 3-7% shifts in the average energy of the SL25 beams was observed. Angular measurements were made which showed the Gaussian angular spread of the incident beam. The Monte Carlo code CYLTRAN and measured spectra were used to reconstruct depth dose curves. Comparisons with measured depth dose curves show that the peak energy structure

  8. Quantum correlations in optical angle-orbital angular momentum variables.

    Science.gov (United States)

    Leach, Jonathan; Jack, Barry; Romero, Jacqui; Jha, Anand K; Yao, Alison M; Franke-Arnold, Sonja; Ireland, David G; Boyd, Robert W; Barnett, Stephen M; Padgett, Miles J

    2010-08-06

    Entanglement of the properties of two separated particles constitutes a fundamental signature of quantum mechanics and is a key resource for quantum information science. We demonstrate strong Einstein, Podolsky, and Rosen correlations between the angular position and orbital angular momentum of two photons created by the nonlinear optical process of spontaneous parametric down-conversion. The discrete nature of orbital angular momentum and the continuous but periodic nature of angular position give rise to a special sort of entanglement between these two variables. The resulting correlations are found to be an order of magnitude stronger than those allowed by the uncertainty principle for independent (nonentangled) particles. Our results suggest that angular position and orbital angular momentum may find important applications in quantum information science.

  9. Creating high-harmonic beams with controlled orbital angular momentum.

    Science.gov (United States)

    Gariepy, Genevieve; Leach, Jonathan; Kim, Kyung Taec; Hammond, T J; Frumker, E; Boyd, Robert W; Corkum, P B

    2014-10-10

    A beam with an angular-dependant phase Φ = ℓϕ about the beam axis carries an orbital angular momentum of ℓℏ per photon. Such beams are exploited to provide superresolution in microscopy. Creating extreme ultraviolet or soft-x-ray beams with controllable orbital angular momentum is a critical step towards extending superresolution to much higher spatial resolution. We show that orbital angular momentum is conserved during high-harmonic generation. Experimentally, we use a fundamental beam with |ℓ| = 1 and interferometrically determine that the harmonics each have orbital angular momentum equal to their harmonic number. Theoretically, we show how any small value of orbital angular momentum can be coupled to any harmonic in a controlled manner. Our results open a route to microscopy on the molecular, or even submolecular, scale.

  10. The SKA as a Doorway to Angular Momentum

    CERN Document Server

    Obreschkow, D; Popping, A; Power, C; Quinn, P; Staveley-Smith, L

    2015-01-01

    Angular momentum is one of the most fundamental physical quantities governing galactic evolution. Differences in the colours, morphologies, star formation rates and gas fractions amongst galaxies of equal stellar/baryon mass M are potentially widely explained by variations in their specific stellar/baryon angular momentum j. The enormous potential of angular momentum science is only just being realised, thanks to the emergence of the first simulations of galaxies with converged spins, paralleled by a dramatic increase in kinematic observations. Such observations are still challenged by the fact that most of the stellar/baryon angular momentum resides at large radii. In fact, the radius that maximally contributes to the angular momentum of an exponential disk (3Re-4Re) is twice as large as the radius that maximally contributes to the disk mass; thus converged measurements of angular momentum require either extremely deep IFS data or, alternatively, kinematic measurements of neutral atomic hydrogen (HI), which ...

  11. Orbital angular momentum photonic quantum interface

    Institute of Scientific and Technical Information of China (English)

    Zhi-Yuan Zhou; Yan Li; Dong-Sheng Ding; Wei Zhang; Shuai Shi; Bao-Sen Shi; Guang-Can Guo

    2016-01-01

    Light-carrying orbital angular momentum (OAM) has great potential in enhancing the information channel capacity in both classical and quantum optical communications.Long distance optical communication requires the wavelengths of light are situated in the low-loss communication windows,but most quantum memories currently being developed for use in a quantum repeater work at different wavelengths,so a quantum interface to bridge the wavelength gap is necessary.So far,such an interface for OAM-carried light has not been realized yet.Here,we report the first experimental realization of a quantum interface for a heralded single photon carrying OAM using a nonlinear crystal in an optical cavity.The spatial structures of input and output photons exhibit strong similarity.More importantly,single-photon coherence is preserved during up-conversion as demonstrated.

  12. Four-photon orbital angular momentum entanglement

    CERN Document Server

    Hiesmayr, B C; Löffler, W

    2015-01-01

    Quantum entanglement shared between more than two particles is essential to foundational questions in quantum mechanics, and upcoming quantum information technologies. So far, up to 14 two-dimensional qubits have been entangled, and an open question remains if one can also demonstrate entanglement of higher-dimensional discrete properties of more than two particles. A promising route is the use of the photon orbital angular momentum (OAM), which enables implementation of novel quantum information protocols, and the study of fundamentally new quantum states. To date, only two of such multidimensional particles have been entangled albeit with ever increasing dimensionality. Here we use pulsed spontaneous parametric downconversion (SPDC) to produce photon quadruplets that are entangled in their OAM, or transverse-mode degrees of freedom; and witness genuine multipartite Dicke-type entanglement. Apart from addressing foundational questions, this could find applications in quantum metrology, imaging, and secret sh...

  13. High orbital angular momentum harmonic generation

    CERN Document Server

    Vieira, J; Alves, E P; Fonseca, R A; Mendonça, J T; Bingham, R; Norreys, P; Silva, L O

    2016-01-01

    We identify and explore a high orbital angular momentum (OAM) harmonics generation and amplification mechanism that manipulates the OAM independently of any other laser property, by preserving the initial laser wavelength, through stimulated Raman backscattering in a plasma. The high OAM harmonics spectra can extend at least up to the limiting value imposed by the paraxial approximation. We show with theory and particle-in-cell simulations that the orders of the OAM harmonics can be tuned according to a selection rule that depends on the initial OAM of the interacting waves. We illustrate the high OAM harmonics generation in a plasma using several examples including the generation of prime OAM harmonics. The process can also be realised in any nonlinear optical Kerr media supporting three-wave interactions.

  14. Optical communication beyond orbital angular momentum

    Science.gov (United States)

    Trichili, Abderrahmen; Rosales-Guzmán, Carmelo; Dudley, Angela; Ndagano, Bienvenu; Ben Salem, Amine; Zghal, Mourad; Forbes, Andrew

    2016-06-01

    Mode division multiplexing (MDM) is mooted as a technology to address future bandwidth issues, and has been successfully demonstrated in free space using spatial modes with orbital angular momentum (OAM). To further increase the data transmission rate, more degrees of freedom are required to form a densely packed mode space. Here we move beyond OAM and demonstrate multiplexing and demultiplexing using both the radial and azimuthal degrees of freedom. We achieve this with a holographic approach that allows over 100 modes to be encoded on a single hologram, across a wide wavelength range, in a wavelength independent manner. Our results offer a new tool that will prove useful in realizing higher bit rates for next generation optical networks.

  15. Angular response of hot wire probes

    Science.gov (United States)

    di Mare, L.; Jelly, T. O.; Day, I. J.

    2017-03-01

    A new equation for the convective heat loss from the sensor of a hot-wire probe is derived which accounts for both the potential and the viscous parts of the flow past the prongs. The convective heat loss from the sensor is related to the far-field velocity by an expression containing a term representing the potential flow around the prongs, and a term representing their viscous effect. This latter term is absent in the response equations available in the literature but is essential in representing some features of the observed response of miniature hot-wire probes. The response equation contains only four parameters but it can reproduce, with great accuracy, the behaviour of commonly used single-wire probes. The response equation simplifies the calibration the angular response of rotated slanted hot-wire probes: only standard King’s law parameters and a Reynolds-dependent drag coefficient need to be determined.

  16. Orbital angular momentum photonic quantum interface

    CERN Document Server

    Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Shi, Bao-Sen; Guo, Guang-Can

    2014-01-01

    High dimensional orbital angular momentum (OAM) light states are very important in enhancing the information carrying capacity in optical communications and quantum key distributions. Light at wavelengths of fiber communication windows or free space communication windows are suitable for long distance quantum communication, but most quantum processing tasks are performed in the visible wavelength ranges. The interface to bridge the wavelength gap of single photon with Gaussian shape has been realized, however, to create such interface for OAM-carrying light is a great challenge. We report the demonstration of such an interface to frequency up-conversion of herald single photon OAM state from 1560nm to 525nm with high efficiency by using nonlinear crystal in an external cavity. We show that different single photon OAM light shapes are observed directly by using single photon counting camera and the single photon entangled property is retained in the conversion process.

  17. Sharepoint Extranet AngularJS:llä

    OpenAIRE

    2016-01-01

    Tämä opinnäytetyö käsittelee Sharepoint-ratkaisua AngularJS-ohjelmistokehyksen avulla. Työn tarkoituksena oli toteuttaa uusi sivusto Sharepoint-dokumenttikirjastoja varten. Tämä työ tehtiin toimeksiantona Visualweb Oy:lle. Tavoitteena oli tehdä Sharepoint-sivusto, joka toimisi varsinaisen Sharepoint-palvelimen etusivuna ja käyttöliittymänä. Sivusto toimii asiakkaalla käyttöliittymänä dokumenttikirjastoon. Käyn työssä läpi ne teknologiat, joita projektissa käytettiin. Työssä esitellään A...

  18. Coherent control of photoelectron wavepacket angular interferograms

    Science.gov (United States)

    Hockett, P.; Wollenhaupt, M.; Baumert, T.

    2015-11-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process, where the final (time-integrated) observable coherently samples all instantaneous states of the light-matter interaction. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable.

  19. Coherent Control of Photoelectron Wavepacket Angular Interferograms

    CERN Document Server

    Hockett, Paul; Baumert, Thomas

    2015-01-01

    Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the observable photoelectron angular interferograms resulting from multi-photon atomic ionization with polarization-shaped laser pulses. We consider the polarization sensitivity of both the instantaneous and cumulative continuum wavefunction; the nature of the coherent control over the resultant photoelectron interferogram is thus explored in detail. Based on this understanding, the use of coherent control with polarization-shaped pulses as a methodology for a highly multiplexed coherent quantum metrology is also investigated, and defined in terms of the information content of the observable.

  20. Angular momentum of dark matter black holes

    Science.gov (United States)

    Frampton, Paul H.

    2017-04-01

    We provide strongly suggestive evidence that the halo constituents of dark matter are Primordial Intermediate-Mass Black Holes (PIMBHs). PIMBHs are described by a Kerr metric with two parameters, mass M and angular momentum J. There has been little discussion of J since it plays no role in the upcoming attempt at PIMBH detection by microlensing. Nevertheless J does play a central role in understanding their previous lack of detection, especially by CMB distortion. We explain why bounds previously derived from lack of CMB distortion are too strong for PIMBHs with J non-vanishing and that, provided almost no dark matter black holes originate from stellar collapse, excessive CMB distortion is avoided.

  1. Angular Spectrum Simulation of Pulsed Ultrasound Fields

    DEFF Research Database (Denmark)

    Du, Yigang; Jensen, Henrik; Jensen, Jørgen Arendt

    2009-01-01

    The optimization of non-linear ultrasound imaging should in a first step be based on simulation, as this makes parameter studies considerably easier than making transducer prototypes. Such a simulation program should be capable of simulating non-linear pulsed fields for arbitrary transducer...... geometries for any kind of focusing and apodization. The Angular Spectrum Approach (ASA) is capable of simulating monochromatic non-linear acoustic wave propagation. However, for ultrasound imaging the time response of each specific point in space is required, and a pulsed ASA simulation with multi temporal....... The RMS error of the pulses for all points in the simulated plane is 10.9%. The good agreement between ASA and Field II simulation for the pulsed ultrasound fields obtained in this paper makes it possible to expand Field II to non-linear pulsed fields....

  2. Effects of Angular Momentum on Halo Profiles

    CERN Document Server

    Lentz, Erik W; Rosenberg, Leslie J

    2016-01-01

    The near universality of DM halo density profiles provided by N-body simulations has proven to be robust against changes in total mass density, power spectrum, and some forms of initial velocity dispersion. In this letter we study the effects of coherently spinning up an isolated DM-only progenitor on halo structure. Halos with spins within several standard deviations of the simulated mean ($\\lambda \\lesssim 0.20$) produce profiles with negligible deviations from the universal form. Only when the spin becomes quite large ($\\lambda \\gtrsim 0.20$) do departures become evident. The angular momentum distribution also exhibits a near universal form, which is also independent of halo spin up to $\\lambda \\lesssim 0.20$. A correlation between these epidemic profiles and the presence of a strong bar in the virialized halo is also observed. These bar structures bear resemblance to the radial orbit instability in the rotationless limit.

  3. High Orbital Angular Momentum Harmonic Generation

    Science.gov (United States)

    Vieira, J.; Trines, R. M. G. M.; Alves, E. P.; Fonseca, R. A.; Mendonça, J. T.; Bingham, R.; Norreys, P.; Silva, L. O.

    2016-12-01

    We identify and explore a high orbital angular momentum (OAM) harmonics generation and amplification mechanism that manipulates the OAM independently of any other laser property, by preserving the initial laser wavelength, through stimulated Raman backscattering in a plasma. The high OAM harmonics spectra can extend at least up to the limiting value imposed by the paraxial approximation. We show with theory and particle-in-cell simulations that the orders of the OAM harmonics can be tuned according to a selection rule that depends on the initial OAM of the interacting waves. We illustrate the high OAM harmonics generation in a plasma using several examples including the generation of prime OAM harmonics. The process can also be realized in any nonlinear optical Kerr media supporting three-wave interactions.

  4. The Angular Trispectrum of the CMB

    CERN Document Server

    Hu, W

    2001-01-01

    We study the general properties of the CMB temperature four-point function, specifically its harmonic analogue the angular trispectrum, and illustrate its utility in finding optimal quadratic statistics through the weak gravitational lensing effect. We determine the general form of the trispectrum, under the assumptions of rotational, permutation, and parity invariance, its estimators on the sky, and their Gaussian noise properties. The signal-to-noise in the trispectrum can be highly configuration dependent and any quadratic statistic used to compress the information to a manageable two-point level must be carefully chosen. Through a systematic study, we determine that for the case of lensing a specific statistic, the divergence of a filtered temperature-weighted temperature-gradient map, contains the maximal signal-to-noise and reduces the variance of estimates of the large-scale convergence power spectrum by over an order of magnitude over previous gradient-gradient techniques. The total signal-to-noise fo...

  5. Moon influence on equatorial atmospheric angular momentum

    Science.gov (United States)

    Bizouard, Christian; Zotov, Leonid; Sidorenkov, Nikolay

    2014-05-01

    The variation of the equatorial atmospheric angular momentum function, coordinated with respect to a star-fixed system, is investigated in relation with the lunar tide. We isolate the rapid fluctuations, below 30 days, where Moon motion has a possible influence. First we notice that pressure term and wind term are almost proportional, by contrast to celestial seasonal band (S1). This would mean that, in this frequency band, the torque of the atmosphere on the solid Earth mostly results from the equatorial bulge. Spectrum reveals sharp lunar tidal peaks at 13.66 days (O1 diurnal tide in the terrestrial frame) and 13.63 days, reflecting the Moon influence on meridional circulation. We also observe powerful episodic fluctuations between 5 and 8 days (up to 10 mas), possibly resulting from non linear effect of the O1 tide, or tidal waves 2Q1 (6.86 days) and σ1 (7.095 days).

  6. Orbital angular momentum-entanglement frequency transducer

    CERN Document Server

    Zhou, Zhi-Yuan; Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Dong, Ming-Xin; Shi, Bao-Sen; Guo, Guang-Can

    2016-01-01

    Entanglement is a vital resource for realizing many tasks such as teleportation, secure key distribution, metrology and quantum computations. To effectively build entanglement between different quantum systems and share information between them, a frequency transducer to convert between quantum states of different wavelengths while retaining its quantum features is indispensable. Information encoded in the photons orbital angular momentum OAM degrees of freedom is preferred in harnessing the information carrying capacity of a single photon because of its unlimited dimensions. A quantum transducer, which operates at wavelengths from 1558.3 nm to 525 nm for OAM qubits, OAMpolarization hybrid entangled states, and OAM entangled states, is reported for the first time. Nonclassical properties and entanglements are demonstrated following the conversion process by performing quantum tomography, interference, and Bell inequality measurements. Our results demonstrate the capability to create an entanglement link betwe...

  7. Nuclear scissors modes and hidden angular momenta

    CERN Document Server

    Balbutsev, E B; Schuck, P

    2016-01-01

    The coupled dynamics of low lying modes and various giant resonances are studied with the help of the Wigner Function Moments method generalized to take into account spin degrees of freedom and pair correlations simultaneously. The method is based on Time Dependent Hartree-Fock-Bogoliubov equations. The model of the harmonic oscillator including spin-orbit potential plus quadrupole-quadrupole and spin-spin interactions is considered. New low lying spin dependent modes are analyzed. Special attention is paid to the scissors modes. A new source of nuclear magnetism, connected with counter-rotation of spins up and down around the symmetry axis (hidden angular momenta), is discovered. Its inclusion into the theory allows one to improve substantially the agreement with experimental data in the description of energies and transition probabilities of scissors modes.

  8. IDENTIFIKASI MIKROORGANISE STAPHYLOCOCCUS AUREUS PADA PENDERITA ANGULAR CHEILITIS

    OpenAIRE

    MINARTI, NURHAERATUL

    2012-01-01

    2011 Pada suatu penelitian tentang Angular cheilitis ditemukan Staphylococcus aureus hampir dua kali dari candida albicans. Oleh karena itu tujuan penelitian ini adalah untuk mengidentifikasi pengaruh Staphylococcus aureus pada penyakit Angular cheilitis. Sampel penelitian adalah 30 pasien yang datang ke Rumah Sakit Gigi dan Mulut Halimah Daeng Sikati Kandea Bagian Penyakit Gigi dan Mulut dalam periode waktu bulan Oktober-November 2011. Apusan pada permukaan lesi angular cheilitis dima...

  9. Ideal linear-chain polymers with fixed angular momentum.

    Science.gov (United States)

    Brunner, Matthew; Deutsch, J M

    2011-07-01

    The statistical mechanics of a linear noninteracting polymer chain with a large number of monomers is considered with fixed angular momentum. The radius of gyration for a linear polymer is derived exactly by functional integration. This result is then compared to simulations done with a large number of noninteracting rigid links at fixed angular momentum. The simulation agrees with the theory up to finite-size corrections. The simulations are also used to investigate the anisotropic nature of a spinning polymer. We find universal scaling of the polymer size along the direction of the angular momentum, as a function of rescaled angular momentum.

  10. Whole-body angular momentum in incline and decline walking.

    Science.gov (United States)

    Silverman, Anne K; Wilken, Jason M; Sinitski, Emily H; Neptune, Richard R

    2012-04-01

    Angular momentum is highly regulated over the gait cycle and is important for maintaining dynamic stability and control of movement. However, little is known regarding how angular momentum is regulated on irregular surfaces, such as slopes, when the risk of falling is higher. This study examined the three-dimensional whole-body angular momentum patterns of 30 healthy subjects walking over a range of incline and decline angles. The range of angular momentum was either similar or reduced on decline surfaces and increased on incline surfaces relative to level ground, with the greatest differences occurring in the frontal and sagittal planes. These results suggest that angular momentum is more tightly controlled during decline walking when the risk of falling is greater. In the frontal plane, the range of angular momentum was strongly correlated with the peak hip and knee abduction moments in early stance. In the transverse plane, the strongest correlation occurred with the knee external rotation peak in late stance. In the sagittal plane, all external moment peaks were correlated with the range of angular momentum. The peak ankle plantarflexion, knee flexion and hip extension moments were also strongly correlated with the sagittal-plane angular momentum. These results highlight how able-bodied subjects control angular momentum differently on sloped surfaces relative to level walking and provide a baseline for comparison with pathological populations that are more susceptible to falling.

  11. Sequential injection analysis (SIA)-chemiluminescence determination of indomethacin using tris[(2,2'-bipyridyl)]ruthenium(III) as reagent and its application to semisolid pharmaceutical dosage forms

    Energy Technology Data Exchange (ETDEWEB)

    Mervartova, Katerina [Department of Analytical Chemistry, Faculty of Pharmacy, Charles University, Heyrovskeho 1203, CZ-500 05 Hradec Kralove (Czech Republic)], E-mail: Katerina.Mervartova@faf.cuni.cz; Polasek, Miroslav [Department of Analytical Chemistry, Faculty of Pharmacy, Charles University, Heyrovskeho 1203, CZ-500 05 Hradec Kralove (Czech Republic); Calatayud, Jose Martinez [Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Valencia (Spain)

    2007-09-26

    Automated sequential injection (SIA) method for chemiluminescence (CL) determination of nonsteroidal anti-inflammatory drug indomethacin (I) was devised. The CL radiation was emitted in the reaction of I (dissolved in aqueous 50% v/v ethanol) with intermediate reagent tris(2,2'-bipyridyl)ruthenium(III) (Ru(bipy){sub 3}{sup 3+}) in the presence of acetate. The Ru(bipy){sub 3}{sup 3+} was generated on-line in the SIA system by the oxidation of 0.5 mM tris(2,2'-bipyridyl)ruthenium(II) (Ru(bipy){sub 3}{sup 2+}) with Ce(IV) ammonium sulphate in diluted sulphuric acid. The optimum sequence, concentrations, and aspirated volumes of reactant zones were: 15 mM Ce(IV) in 50 mM sulphuric acid 41 {mu}L, 0.5 mM Ru(bipy){sub 3}{sup 2+} 30 {mu}L, 0.4 M Na acetate 16 {mu}L and I sample 15 {mu}L; the flow rates were 60 {mu}L s{sup -1} for the aspiration into the holding coil and 100 {mu}L s{sup -1} for detection. Calibration curve relating the intensity of CL (peak height of the transient CL signal) to concentration of I was curvilinear (second order polynomial) for 0.1-50 {mu}M I (r = 0.9997; n = 9) with rectilinear section in the range 0.1-10 {mu}M I (r = 0.9995; n = 5). The limit of detection (3{sigma}) was 0.05 {mu}M I. Repeatability of peak heights (R.S.D., n = 10) ranged between 2.4% (0.5 {mu}M I) and 2.0% (7 {mu}M I). Sample throughput was 180 h{sup -1}. The method was applied to determination of 1 to 5% of I in semisolid dosage forms (gels and ointments). The results compared well with those of UV spectrophotometric method.

  12. 3D printed bio-inspired angular acceleration sensor

    NARCIS (Netherlands)

    Tiem, van Joël; Groenesteijn, Jarno; Sanders, Remco; Krijnen, Gijs

    2015-01-01

    We present a biomimetic angular acceleration sensor inspired by the vestibular system, as found e.g. in mammals and fish. The sensor consist of a fluid filled circular channel. When exposed to angular accelerations the fluid flows relative to the channel. Read-out is based on electromagnetic flow se

  13. Learning web development with Bootstrap and AngularJS

    CERN Document Server

    Radford, Stephen

    2015-01-01

    Whether you know a little about Bootstrap or AngularJS, or you're a complete beginner, this book will enhance your capabilities in both frameworks and you'll build a fully functional web app. A working knowledge of HTML, CSS, and JavaScript is required to fully get to grips with Bootstrap and AngularJS.

  14. Fundamental methods to measure the orbital angular momentum of light

    NARCIS (Netherlands)

    Berkhout, Gregorius Cornelis Gerardus (Joris)

    2011-01-01

    Light is a ubiquitous carrier of information. This information can be encoded in the intensity, direction, frequency and polarisation of the light and, which was described more recently, in its orbital angular momentum. Although creating light beams with orbital angular momentum is relatively easy,

  15. Angular Momentum Phase State Representation for Quantum Pendulum

    Institute of Scientific and Technical Information of China (English)

    FAN Hong-Yi; WANG Ji-Suo

    2005-01-01

    To consummate the quantum pendulum theory whose Hamiltonian takes bosonic operator formalism and manifestly exhibits its dynamic behaviour in the entangled state representation, we introduce angular momentum state representation and phase state representation. It turns out that the angular momentum state is the partial wave expansion of the entangled state.

  16. Relativistic calculations of angular dependent photoemission time delay

    CERN Document Server

    Kheifets, A S; Deshmukh, P C; Dolmatov, V K; Manson, S T

    2016-01-01

    Angular dependence of photoemission time delay for the valence $np_{3/2}$ and $np_{1/2}$ subshells of Ar, Kr and Xe is studied in the dipole relativistic random phase approximation. Strong angular anisotropy of the time delay is reproduced near respective Cooper minima while the spin-orbit splitting affects the time delay near threshold.

  17. Evolution equations for higher moments of angular momentum distributions

    CERN Document Server

    Hägler, P

    1998-01-01

    Based on a sumrule for the nucleon spin we expand quark and gluon orbital angular momentum operators and derive an evolution matrix for higher moments of the corresponding distributions. In combination with the spin-dependent DGLAP-matrix we find a complete set of spin and orbital angular momentum evolution equations.

  18. Angular cheilitis occurring during orthodontic treatment: a case series.

    Science.gov (United States)

    Cross, David L; Short, Laura J

    2008-12-01

    Clinical experience has shown that angular cheilitis can occur during orthodontic treatment and may persist into retention, but the incidence of the condition is unknown. The purpose of this paper is to increase the awareness among clinicians of angular cheilitis occurring during orthodontic treatment. It also proposes a treatment regime which may be used.

  19. Iron deficiency: an overlooked predisposing factor in angular cheilitis.

    Science.gov (United States)

    Murphy, N C; Bissada, N F

    1979-10-01

    Clinicians who recommend the use of antifungal agents for angular cheilitis may be treating the symptoms and not the predisposing cause of the disease. Iron deficiency should be considered as part of the differential diagnosis whenever angular cheilitis is encountered, especially in women of child-bearing age.

  20. Why mercury prefers soft ligands

    Energy Technology Data Exchange (ETDEWEB)

    Riccardi, Demian M [ORNL; Guo, Hao-Bo [ORNL; Gu, Baohua [ORNL; Parks, Jerry M [ORNL; Summers, Anne [University of Georgia, Athens, GA; Miller, S [University of California, San Francisco; Liang, Liyuan [ORNL; Smith, Jeremy C [ORNL

    2013-01-01

    Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources. Defining the factors that determine the relative affinities of different ligands for the mercuric ion, Hg2+, is critical to understanding its speciation, transformation, and bioaccumulation in the environment. Here, we use quantum chemistry to dissect the relative binding free energies for a series of inorganic anion complexes of Hg2+. Comparison of Hg2+ ligand interactions in the gaseous and aqueous phases shows that differences in interactions with a few, local water molecules led to a clear periodic trend within the chalcogenide and halide groups and resulted in the well-known experimentally observed preference of Hg2+ for soft ligands such as thiols. Our approach establishes a basis for understanding Hg speciation in the biosphere.

  1. Molecular Recognition and Ligand Association

    Science.gov (United States)

    Baron, Riccardo; McCammon, J. Andrew

    2013-04-01

    We review recent developments in our understanding of molecular recognition and ligand association, focusing on two major viewpoints: (a) studies that highlight new physical insight into the molecular recognition process and the driving forces determining thermodynamic signatures of binding and (b) recent methodological advances in applications to protein-ligand binding. In particular, we highlight the challenges posed by compensating enthalpic and entropic terms, competing solute and solvent contributions, and the relevance of complex configurational ensembles comprising multiple protein, ligand, and solvent intermediate states. As more complete physics is taken into account, computational approaches increase their ability to complement experimental measurements, by providing a microscopic, dynamic view of ensemble-averaged experimental observables. Physics-based approaches are increasingly expanding their power in pharmacology applications.

  2. CLASS: The Cosmology Large Angular Scale Surveyor

    CERN Document Server

    Essinger-Hileman, Thomas; Amiri, Mandana; Appel, John W; Araujo, Derek; Bennett, Charles L; Boone, Fletcher; Chan, Manwei; Cho, Hsiao-Mei; Chuss, David T; Colazo, Felipe; Crowe, Erik; Denis, Kevin; Dünner, Rolando; Eimer, Joseph; Gothe, Dominik; Halpern, Mark; Harrington, Kathleen; Hilton, Gene; Hinshaw, Gary F; Huang, Caroline; Irwin, Kent; Jones, Glenn; Karakla, John; Kogut, Alan J; Larson, David; Limon, Michele; Lowry, Lindsay; Marriage, Tobias; Mehrle, Nicholas; Miller, Amber D; Miller, Nathan; Moseley, Samuel H; Novak, Giles; Reintsema, Carl; Rostem, Karwan; Stevenson, Thomas; Towner, Deborah; U-Yen, Kongpop; Wagner, Emily; Watts, Duncan; Wollack, Edward; Xu, Zhilei; Zeng, Lingzhen

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an experiment to measure the signature of a gravita-tional-wave background from inflation in the polarization of the cosmic microwave background (CMB). CLASS is a multi-frequency array of four telescopes operating from a high-altitude site in the Atacama Desert in Chile. CLASS will survey 70\\% of the sky in four frequency bands centered at 38, 93, 148, and 217 GHz, which are chosen to straddle the Galactic-foreground minimum while avoiding strong atmospheric emission lines. This broad frequency coverage ensures that CLASS can distinguish Galactic emission from the CMB. The sky fraction of the CLASS survey will allow the full shape of the primordial B-mode power spectrum to be characterized, including the signal from reionization at low $\\ell$. Its unique combination of large sky coverage, control of systematic errors, and high sensitivity will allow CLASS to measure or place upper limits on the tensor-to-scalar ratio at a level of $r=0.01$ and make a cosmi...

  3. Tracing the Angular Dependence of the CGM

    Science.gov (United States)

    Nattinger, Michael; Christensen, Charlotte

    2017-01-01

    The circumgalactic media (CGM) is enriched with metals through a process called the baryon cycle, which may play a significant role in the regulation of star formation. While the relationship between the CGM’s baryonic makeup and impact parameter is well documented, the relationship between the baryonic distribution of the CGM and the azimuthal angle out of the plane of the galaxy remains an open question. We investigated the angular distribution of baryons in the CGM by creating mock-absorption line spectra for a high-resolution simulation of a Milky Way-like galaxy at redshift zero. By comparison with data from the Cosmic Origins Spectrograph-Halos survey, we determined that our equivalent widths of HI, MgII, CIII, SiII, and SiIII are consistent with observations. Using our data, we found that low ionization state material is more prevalent at low azimuthal angles and that high ionization state material is more prevalent at high angles within the virial radius. We attributed this increased ionization to higher temperatures at high angles. We also found that the highest metallicity levels appear at high and low azimuthal angles, with lower metallicities at middle angles. This evidence supports the recycled accretion model of CGM baryon flow.

  4. Angular velocity and centripetal acceleration relationship

    Science.gov (United States)

    Monteiro, Martín; Cabeza, Cecilia; Marti, Arturo C.; Vogt, Patrik; Kuhn, Jochen

    2014-05-01

    During the last few years, the growing boom of smartphones has given rise to a considerable number of applications exploiting the functionality of the sensors incorporated in these devices. A sector that has unexpectedly taken advantage of the power of these tools is physics teaching, as reflected in several recent papers. In effect, the use of smartphones has been proposed in several physics experiments spanning mechanics, electromagnetism, optics, oscillations, and waves, among other subjects. Although mechanical experiments have received considerable attention, most of them are based on the use of the accelerometer. An aspect that has received less attention is the use of rotation sensors or gyroscopes. An additional advance in the use of these devices is given by the possibility of obtaining data using the accelerometer and the gyroscope simultaneously. The aim of this paper is to consider the relation between the centripetal acceleration and the angular velocity. Instead of using a formal laboratory setup, in this experiment a smartphone is attached to the floor of a merry-go-round, found in many playgrounds. Several experiments were performed with the roundabout rotating in both directions and with the smart-phone at different distances from the center. The coherence of the measurements is shown.

  5. Cyclic transformation of orbital angular momentum modes

    Science.gov (United States)

    Schlederer, Florian; Krenn, Mario; Fickler, Robert; Malik, Mehul; Zeilinger, Anton

    2016-04-01

    The spatial modes of photons are one realization of a QuDit, a quantum system that is described in a D-dimensional Hilbert space. In order to perform quantum information tasks with QuDits, a general class of D-dimensional unitary transformations is needed. Among these, cyclic transformations are an important special case required in many high-dimensional quantum communication protocols. In this paper, we experimentally demonstrate a cyclic transformation in the high-dimensional space of photonic orbital angular momentum (OAM). Using simple linear optical components, we show a successful four-fold cyclic transformation of OAM modes. Interestingly, our experimental setup was found by a computer algorithm. In addition to the four-cyclic transformation, the algorithm also found extensions to higher-dimensional cycles in a hybrid space of OAM and polarization. Besides being useful for quantum cryptography with QuDits, cyclic transformations are key for the experimental production of high-dimensional maximally entangled Bell-states.

  6. Axions and the Galactic Angular Momentum Distribution

    CERN Document Server

    Banik, N

    2013-01-01

    We analyze the behavior of axion dark matter before it falls into a galactic gravitational potential well. The axions thermalize sufficiently fast by gravitational self-interactions that almost all go to their lowest energy state consistent with the total angular momentum acquired from tidal torquing. That state is a state of rigid rotation on the turnaround sphere. It predicts the occurrence and detailed properties of the caustic rings of dark matter for which observational evidence had been found earlier. We show that the vortices in the axion Bose-Einstein condensate (BEC) are attractive, unlike those in superfluid $^4$He and dilute gases. We expect that a large fraction of the vortices in the axion BEC join into a single big vortex along the rotation axis of the galaxy. The resulting enhancement of caustic rings explains the typical size of the rises in the Milky Way rotation curve attributed to caustic rings. We show that baryons and ordinary cold dark matter particles are entrained by the axion BEC and ...

  7. Orbital angular momentum divider of light

    CERN Document Server

    Dong, Hailong Zhou Jianji; Cai, Xinlun; Yu, SiYuan; Zhang, Xinliang

    2016-01-01

    Manipulation of orbital angular momentum (OAM) of light is essential in OAM-based optical systems. Especially, OAM divider, which can convert the incoming OAM mode into one or several new smaller modes in proportion at different spatial paths, is very useful in OAM-based optical networks. However, this useful tool was never reported yet. For the first time, we put forward a passive OAM divider based on coordinate transformation. The device consists of a Cartesian to log-polar coordinate converter and an inverse converter. The first converter converts the OAM light into a rectangular-shaped plane light with a transverse phase gradient. And the second converter converts the plane light into multiple diffracted light. The OAM of zeroth-order diffracted light is the product of the input OAM and the scaling parameter. The residual light is output from other diffracted orders. Furthermore, we extend the scheme to realize equal N-dividing of OAM and arbitrary dividing of OAM. The ability of dividing OAM shows huge p...

  8. Millimetre Wave with Rotational Orbital Angular Momentum

    Science.gov (United States)

    Zhang, Chao; Ma, Lu

    2016-09-01

    Orbital angular momentum (OAM) has been widely studied in fibre and short-range communications. The implementation of millimetre waves with OAM is expected to increase the communication capacity. Most experiments demonstrate the distinction of OAM modes by receiving all of the energy in the surface vertical to the radiation axis in space. However, the reception of OAM is difficult in free space due to the non-zero beam angle and divergence of energy. The reception of OAM in the space domain in a manner similar to that in optical fibres (i.e., receiving all of the energy rings vertical to the radiation axis) is impractical, especially for long-distance transmission. Here, we fabricate a prototype of the antenna and demonstrate that rather than in the space domain, the OAM can be well received in the time domain via a single antenna by rotating the OAM wave at the transmitter, i.e., the radio wave with rotational OAM. The phase and frequency measured in the experiment reveal that for different OAM modes, the received signals act as a commonly used orthogonal frequency division multiplexing (OFDM) signal in the time domain. This phase rotation has promising prospects for use in the practical reception of different OAMs of millimetre waves in long-distance transmission.

  9. Orbital Angular Momentum-Entanglement Frequency Transducer

    Science.gov (United States)

    Zhou, Zhi-Yuan; Liu, Shi-Long; Li, Yan; Ding, Dong-Sheng; Zhang, Wei; Shi, Shuai; Dong, Ming-Xin; Shi, Bao-Sen; Guo, Guang-Can

    2016-09-01

    Entanglement is a vital resource for realizing many tasks such as teleportation, secure key distribution, metrology, and quantum computations. To effectively build entanglement between different quantum systems and share information between them, a frequency transducer to convert between quantum states of different wavelengths while retaining its quantum features is indispensable. Information encoded in the photon's orbital angular momentum (OAM) degrees of freedom is preferred in harnessing the information-carrying capacity of a single photon because of its unlimited dimensions. A quantum transducer, which operates at wavelengths from 1558.3 to 525 nm for OAM qubits, OAM-polarization hybrid-entangled states, and OAM-entangled states, is reported for the first time. Nonclassical properties and entanglements are demonstrated following the conversion process by performing quantum tomography, interference, and Bell inequality measurements. Our results demonstrate the capability to create an entanglement link between different quantum systems operating in a photon's OAM degrees of freedom, which will be of great importance in building a high-capacity OAM quantum network.

  10. Millimetre Wave with Rotational Orbital Angular Momentum

    Science.gov (United States)

    Zhang, Chao; Ma, Lu

    2016-01-01

    Orbital angular momentum (OAM) has been widely studied in fibre and short-range communications. The implementation of millimetre waves with OAM is expected to increase the communication capacity. Most experiments demonstrate the distinction of OAM modes by receiving all of the energy in the surface vertical to the radiation axis in space. However, the reception of OAM is difficult in free space due to the non-zero beam angle and divergence of energy. The reception of OAM in the space domain in a manner similar to that in optical fibres (i.e., receiving all of the energy rings vertical to the radiation axis) is impractical, especially for long-distance transmission. Here, we fabricate a prototype of the antenna and demonstrate that rather than in the space domain, the OAM can be well received in the time domain via a single antenna by rotating the OAM wave at the transmitter, i.e., the radio wave with rotational OAM. The phase and frequency measured in the experiment reveal that for different OAM modes, the received signals act as a commonly used orthogonal frequency division multiplexing (OFDM) signal in the time domain. This phase rotation has promising prospects for use in the practical reception of different OAMs of millimetre waves in long-distance transmission. PMID:27596746

  11. Optical communications beyond orbital angular momentum

    Science.gov (United States)

    Rosales-Guzmán, Carmelo; Trichili, Abderrahmen; Dudley, Angela; Ndagano, Bienvenu; Ben Salem, Amine; Zghal, Mourad; Forbes, Andrew

    2016-09-01

    Current optical communication technologies are predicted to face a bandwidth capacity limit in the near future. The nature of the limitation is fundamental rather than technological and is set by nonlinearities in optical fibers. One solution, suggested over 30 years ago, comprises the use of spatial modes of light as information carriers. Along this direction, light beams endowed with orbital angular momentum (OAM) have been demonstrated as potential information carriers in both, free space and fibres. However, recent studies suggest that purely OAM modes does not increase the bandwidth of optical communication systems. In fact, in all work to date, only the azimuthal component of transverse spatial modes has been used. Crucially, all transverse spatial modes require two degrees of freedom to be described; in the context of Laguerre-Gaussian (LGp`) beams these are azimuthal (l) and radial (p), the former responsible for OAM. Here, we demonstrate a technique where both degrees of freedom of LG modes are used as information carrier over free space. We transfer images encoded using 100 spatial modes in three wavelengths as our basis, and employ a spatial demultiplexing scheme that detects all 100 modes simultaneously. Our scheme is a hybrid of MIMO and SMM, and serves as a proof-of-principle demonstration. The cross-talk between the modes is small and independent of whether OAM modes are used or not.

  12. Extraordinary photons with unusual angular momentum

    Institute of Scientific and Technical Information of China (English)

    YAO ZhiXin; ZHONG JianWei; MAO BangNing; PAN BaiLiang

    2009-01-01

    A series of novel state-vector functions (SVFs), which is the general solution of the Schrodinger equation for a photon, are constructed. Each set of these functions consists of a triplet of eigen-SVFs: The triplet can be broken down into a pair of nonzero/-order functions and a single zero-order function. The photons, described with a triplet of eigen-SVFs, possess all the quantum characteristics of a photon: In addition to common attributes like energy E=hω, and momentum Pz= hk; they also exhibit different angular momenta (AM) Lz+=Ih, Lz-= Ih, and Lz0=0, where I≥1. In other words, in addition to usual eigenvalues Lz±=±h, there are unusual nonzero/-order eigenvalues Lz±=±Ih and a zero-order eigenvalue Lz0 =0 for AM of a photon. By a series of SVFs, the pattern from nonzero /-order and zero-order Laguerre-Gaussian modes of a laser beam is explained well from a quantum mechanical point of view.

  13. Extraordinary photons with unusual angular momentum

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    A series of novel state-vector functions (SVFs), which is the general solution of the Schrdinger equa- tion for a photon, are constructed. Each set of these functions consists of a triplet of eigen-SVFs: The triplet can be broken down into a pair of nonzero l-order functions and a single zero-order function. The photons, described with a triplet of eigen-SVFs, possess all the quantum characteristics of a photon: In addition to common attributes like energy E = hω, and momentum pz = hκ, they also exhibit different angular momenta (AM) Lz+ = lh, Lz- = lh, and Lz0 = 0, where l≥1. In other words, in addition to usual ei- genvalues Lz±= ±h, there are unusual nonzero l-order eigenvalues Lz±= ±lh and a zero-order eigenvalue Lz0 = 0 for AM of a photon. By a series of SVFs, the pattern from nonzero l-order and zero-order La- guerre-Gaussian modes of a laser beam is explained well from a quantum mechanical point of view.

  14. Cyclic transformation of orbital angular momentum modes

    CERN Document Server

    Schlederer, Florian; Fickler, Robert; Malik, Mehul; Zeilinger, Anton

    2015-01-01

    The spatial modes of photons are one realization of a QuDit, a quantum system that is described in a D-dimensional Hilbert space. In order to perform quantum information tasks with QuDits, a general class of D-dimensional unitary transformations is needed. Among these, cyclic transformations are an important special case required in many high-dimensional quantum communication protocols. In this paper, we experimentally demonstrate a cyclic transformation in the high-dimensional space of photonic orbital angular momentum (OAM). Using simple linear optical components, we show a successful four-fold cyclic transformation of OAM modes. Interestingly, our experimental setup was found by a computer algorithm. In addition to the four-cyclic transformation, the algorithm also found extensions to higher-dimensional cycles in a hybrid space of OAM and polarization. Besides being useful for quantum cryptography with QuDits, cyclic transformations are key for the experimental production of high-dimensional maximally enta...

  15. CLASS: The Cosmology Large Angular Scale Surveyor

    Science.gov (United States)

    Essinger-Hileman, Thomas; Ali, Aamir; Amiri, Mandana; Appel, John W.; Araujo, Derek; Bennett, Charles L.; Boone, Fletcher; Chan, Manwei; Cho, Hsiao-Mei; Chuss, David T.; Colazo, Felipe; Crowe, Erik; Denis, Kevin; Dunner, Rolando; Eimer, Joseph; Gothe, Dominik; Halpern, Mark; Kogut, Alan J.; Miller, Nathan; Moseley, Samuel; Rostem, Karwan; Stevenson, Thomas; Towner, Deborah; U-Yen, Kongpop; Wollack, Edward

    2014-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) is an experiment to measure the signature of a gravitational wave background from inflation in the polarization of the cosmic microwave background (CMB). CLASS is a multi-frequency array of four telescopes operating from a high-altitude site in the Atacama Desert in Chile. CLASS will survey 70% of the sky in four frequency bands centered at 38, 93, 148, and 217 GHz, which are chosen to straddle the Galactic-foreground minimum while avoiding strong atmospheric emission lines. This broad frequency coverage ensures that CLASS can distinguish Galactic emission from the CMB. The sky fraction of the CLASS survey will allow the full shape of the primordial B-mode power spectrum to be characterized, including the signal from reionization at low-length. Its unique combination of large sky coverage, control of systematic errors, and high sensitivity will allow CLASS to measure or place upper limits on the tensor-to-scalar ratio at a level of r = 0:01 and make a cosmic-variance-limited measurement of the optical depth to the surface of last scattering, tau. (c) (2014) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  16. Non-gaussian CMBR angular power spectra

    CERN Document Server

    Magueijo, J

    1995-01-01

    In this paper we show how the prediction of CMBR angular power spectra C_l in non-Gaussian theories is affected by a cosmic covariance problem, that is (C_l,C_{l'}) correlations impart features on any observed C_l spectrum which are absent from the average C^l spectrum. Therefore the average spectrum is rendered a bad observational prediction, and two new prediction strategies, better adjusted to these theories, are proposed. In one we search for hidden random indices conditional to which the theory is released from the correlations. Contact with experiment can then be made in the form of the conditional power spectra plus the random index distribution. In another approach we apply to the problem a principal component analysis. We discuss the effect of correlations on the predictivity of non-Gaussian theories. We finish by showing how correlations may be crucial in delineating the borderline between predictions made by non-Gaussian and Gaussian theories. In fact, in some particular theories, correlations may ...

  17. Structural Diversity of Metallosupramolecular Assemblies Based on the Bent Bridging Ligand 4,4′-Dithiodipyridine

    Directory of Open Access Journals (Sweden)

    Rüdiger W. Seidel

    2013-05-01

    Full Text Available 4,4′-Dithiodipyridine (dtdp, also termed 4,4′-dipyridyldisulfide, is a bridging ligand of the 4,4′-bipyridine type. The introduction of the disulfide moiety inevitably leads to a relatively rigid angular structure, which exhibits axial chirality. More than 90 metal complexes containing the dtdp ligand have been crystallographically characterised until now. This review focuses on the preparation and structural diversity of discrete and polymeric metallosupramolecular assemblies constructed from dtdp as bridging ligands. These encompass metallamacrocycles with M2L2 topology and coordination polymers with periodicity in one or two dimensions. One-dimensional coordination polymers represent the vast majority of the metallosupramolecular structures obtained from dtdp. These include repeated rhomboids, zigzag, helical and arched chains among other types. In this contribution, we make an attempt to provide a comprehensive account of the structural data that are currently available for metallosupramolecular assemblies based on the bent bridging ligand dtdp.

  18. Nuclear Level Density with Non-zero Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    A.N. Behkami; M. Gholami; M. Kildir; M. Soltani

    2006-01-01

    The statistical properties of interacting fermions have been studied for various angular momentum with the inclusion of pairing interaction. The dependence of the critical temperature on angular momentum for several nuclei,have been studied. The yrast energy as a function of angular momentum for 28 Si and 24Mg nuclei have been calculated up to 60.0 MeV of excitation energy. The computed limiting angular momenta are compared with the experimental results for 26Al produced by 12C + 14N reaction. The relevant nuclear level densities for non-zero angular momentum have been computed for 44Ti and l36Ba nuclei. The results are compared with their corresponding values obtained from the approximateformulas.

  19. Towards optical intensity interferometry for high angular resolution stellar astrophysics

    CERN Document Server

    Nunez, Paul D

    2012-01-01

    Most neighboring stars are still detected as point sources and are beyond the angular resolution reach of current observatories. Methods to improve our understanding of stars at high angular resolution are investigated. Air Cherenkov telescopes (ACTs), primarily used for Gamma-ray astronomy, enable us to increase our understanding of the circumstellar environment of a particular system. When used as optical intensity interferometers, future ACT arrays will allow us to detect stars as extended objects and image their surfaces at high angular resolution. Optical stellar intensity interferometry (SII) with ACT arrays, composed of nearly 100 telescopes, will provide means to measure fundamental stellar parameters and also open the possibility of model-independent imaging. A data analysis algorithm is developed and permits the reconstruction of high angular resolution images from simulated SII data. The capabilities and limitations of future ACT arrays used for high angular resolution imaging are investigated via ...

  20. Alignment of wave functions for angular momentum projection

    CERN Document Server

    Taniguchi, Yasutaka

    2016-01-01

    Angular momentum projection is used to obtain eigen states of angular momentum from general wave functions. Multi-configuration mixing calculation with angular momentum projection is an important microscopic method in nuclear physics. For accurate multi-configuration mixing calculation with angular momentum projection, concentrated distribution of $z$ components $K$ of angular momentum in the body-fixed frame ($K$-distribution) is favored. Orientation of wave functions strongly affects $K$-distribution. Minimization of variance of $\\hat{J}_z$ is proposed as an alignment method to obtain wave functions that have concentrated $K$-distribution. Benchmark calculations are performed for $\\alpha$-$^{24}$Mg cluster structure, triaxially superdeformed states in $^{40}$Ar, and Hartree-Fock states of some nuclei. The proposed alignment method is useful and works well for various wave functions to obtain concentrated $K$-distribution.

  1. Angular Distribution and Angular Dispersion in Collision of 19F+27A1 at 114 MeV

    Institute of Scientific and Technical Information of China (English)

    WANG Qi; Li Zhi-Chang; LU Xiu-Qin; ZHAO Kui; LIU Jian-Cheng; SERGEY Yu-Kun; DONG Yu-Chuan; LI Song-Lin; DUAN Li-Min; XU Hu-Shan; XU Hua-Gen; CHEN Ruo-Fu; WU He-Yu; HAN Jian-Long

    2004-01-01

    Angular distributions of fragments B, C, N, O, F, Ne, Na, Mg and Al induced by the collision of 19F+27 A1 at 114MeV have been measured. Angular dispersion parameters are extracted from the experimental data and compared with the theoretical ones. The dynamic dispersions for dissipative products depend strongly on the charge number Z of the fragments.

  2. 1D zigzag chain and 0D monomer Cd(II)/Zn(II) compounds based on flexible phenylenediacetic ligand: Synthesis, crystal structures and fluorescent properties

    Science.gov (United States)

    Yang, Fang; Ren, Yixia; Li, Dongsheng; Fu, Feng; Qi, Guangcai; Wang, Yaoyu

    2008-12-01

    Three novel Cd(II)/Zn(II) compounds, [Cd 2(poda) 2(phen) 3(H 2O)] n· nEtOH·3 nH 2O (1), [Zn(poda) 2(bpy)(H 2O)] n(2) and [Zn(Hpoda) 2(bpy)] (3) (H 2poda = 1,2-phenylenediacetic acid, phen = 1,10-phenanthroline, bpy = 2,2'-bipyridyl), have been synthesized and characterized by IR, TG, fluorescent spectrum and single-crystal X-ray diffraction techniques. In 1, poda 2- anions link the adjacent Cd(II) centers to generate a 1D zigzag chain. Furthermore, an unprecedented four-footed "8-shaped" mixed water-ethanol (H 2O) 6(C 2H 5OH) 2 cluster connects four double chains based on 1D zigzag chain into 3D supramolecular architecture. By bis(chelate-monodentate) fashion of poda 2- ligand, compound 2 exhibits 1D zigzag chains, which forming a dense zipper-like 2D structure via strong π-π stacking interactions. Differed from 1 and 2, compound 3 has a mononuclear motif, and displays a 3D 6-connected α-Po net hydrogen-bonded topology. The structure-related solid-state fluorescence spectra of compounds 1 and 2 have been determined.

  3. Hydrogen bonded NHO chains formed by chloranilic acid (CLA) with 4,4‧-di-t-butyl-2,2‧-bipyridyl (dtBBP) in the solid state

    Science.gov (United States)

    Bator, G.; Sawka-Dobrowolska, W.; Sobczyk, L.; Owczarek, M.; Pawlukojć, A.; Grech, E.; Nowicka-Scheibe, J.

    2012-01-01

    In crystalline state 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) forms with 4,4'-di-t-butyl-2,2'-bipyridyl (dtBBP) the hydrogen bonded chains along the b-axis. From one side of the CLA molecule the proton transfer takes place and the hydrogen bond length is very short (2.615 Å). A continuous infrared absorption is observed for dtBBP·CLA in the wavenumber range between 3100 and 800 cm -1 also indicating the strong hydrogen bonds. The DSC measurements show a weak, close to continuous, phase transition at 414 K. The complex dielectric permittivity for a single crystal sample was measured in the temperature range 100-440 K and at frequencies between 200 Hz and 2 MHz. The dielectric response is a combination of semiconducting properties and a relaxation process most probably connected with the proton dynamics in the hydrogen bonds. The mechanism of the structural phase transition is discussed.

  4. Determination of propoxur in environmental samples by automated solid-phase extraction followed by flow-injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Ruiz, Tomas [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain)]. E-mail: tpr@um.es; Martinez-Lozano, Carmen [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain); Garcia, Maria Dolores [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain)

    2007-02-19

    A sensitive method for the analysis of propoxur in environmental samples has been developed. It involves an automated solid-phase extraction (SPE) procedure using a Gilson Aspec XLi and flow-injection analysis (FI) with chemiluminescence (CL) detection. The FI-CL system relies on the photolysis of propoxur by irradiation using a low-pressure mercury lamp (main spectral line 254 nm). The resultant methylamine is subsequently detected by CL using tris(2,2'-bipyridyl)ruthenium(III), which is on-line generated by photo-oxidation of the ruthenium(II) complex in the presence of peroxydisulfate. The linear concentration range of application was 0.05-5 {mu}g mL{sup -1} of propoxur, with a detection limit of 5 ng mL{sup -1}. The repeatability was 0.82% expressed as relative standard deviation (n = 10) and the reproducibility, studied on 5 consecutive days, was 2.1%. The sample throughput was 160 injection per hour. Propoxur residues below ng mL{sup -1} levels could be determined in environmental water samples when an SPE preconcentration device was coupled on-line with the FI system. This SPE-FI-CL arrangement provides a detection limit as low as 5 ng L{sup -1} using only 500 mL of sample. In the analysis of fruits and vegetables, the detection limit was about 10 {mu}g kg{sup -1}.

  5. Determination of propoxur in environmental samples by automated solid-phase extraction followed by flow-injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection.

    Science.gov (United States)

    Pérez-Ruiz, Tomás; Martínez-Lozano, Carmen; García, María Dolores

    2007-02-19

    A sensitive method for the analysis of propoxur in environmental samples has been developed. It involves an automated solid-phase extraction (SPE) procedure using a Gilson Aspec XLi and flow-injection analysis (FI) with chemiluminescence (CL) detection. The FI-CL system relies on the photolysis of propoxur by irradiation using a low-pressure mercury lamp (main spectral line 254 nm). The resultant methylamine is subsequently detected by CL using tris(2,2'-bipyridyl)ruthenium(III), which is on-line generated by photo-oxidation of the ruthenium(II) complex in the presence of peroxydisulfate. The linear concentration range of application was 0.05-5 microg mL(-1) of propoxur, with a detection limit of 5 ng mL(-1). The repeatability was 0.82% expressed as relative standard deviation (n=10) and the reproducibility, studied on 5 consecutive days, was 2.1%. The sample throughput was 160 injection per hour. Propoxur residues below ng mL(-1) levels could be determined in environmental water samples when an SPE preconcentration device was coupled on-line with the FI system. This SPE-FI-CL arrangement provides a detection limit as low as 5 ng L(-1) using only 500 mL of sample. In the analysis of fruits and vegetables, the detection limit was about 10 microg kg(-1).

  6. The determination of psilocin and psilocybin in hallucinogenic mushrooms by HPLC utilizing a dual reagent acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection system.

    Science.gov (United States)

    Anastos, Nicole; Lewis, Simon W; Barnett, Neil W; Sims, D Noel

    2006-01-01

    This paper describes a procedure for the determination of psilocin and psilocybin in mushroom extracts using high-performance liquid chromatography with postcolumn chemiluminescence detection. A number of extraction methods for psilocin and psilocybin in hallucinogenic mushrooms were investigated, with a simple methanolic extraction being found to be most effective. Psilocin and psilocybin were extracted from a variety of hallucinogenic mushrooms using methanol. The analytes were separated on a C12 column using a (95:5% v/v) methanol:10 mM ammonium formate, pH 3.5 mobile phase with a run time of 5 min. Detection was realized through a dual reagent chemiluminescence detection system of acidic potassium permanganate and tris(2,2'-bipyridyl)ruthenium(II). The chemiluminescence detection system gave improved detectability when compared with UV absorption at 269 nm, with detection limits of 1.2 x 10(-8) and 3.5 x 10(-9) mol/L being obtained for psilocin and psilocybin, respectively. The procedure was applied to the determination of psilocin and psilocybin in three Australian species of hallucinogenic mushroom.

  7. Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes

    Indian Academy of Sciences (India)

    Adewale O Adeloye; Peter A Ajibade; Frances R Cummings; Lukas J Le Roux; Sampson N Mamphweli; Edson L Meyer

    2013-01-01

    Four new amphiphilic ligands: 4-(2,3-dimethylacrylic acid)-2,2'-bipyridine (L1), 4-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-2,2'-bipyridine (L2), 5-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L3) and 5-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L4), with their corresponding homonuclear ruthenium(II) complexes formulated as cis-[Ru-(L1)3(PF6)2] (C1), cis-[Ru-(L2)3(PF6)2] (C2), cis-[Ru-(L3)3(PF6)2] (C3) and cis-[Ru-(L4)3(PF6)2] (C4), have been synthesized and characterized by elemental analysis, 1H- and 13C- NMR, FT-IR, UV-Vis and photoluminescence spectroscopy. The complexes exhibit broad and intense metal-to-ligand charge transfer (MLCT) transition bands in the visible region (400-700 nm), and red light emitting properties at room temperature. By comparison however, complexes C1 and C2 bipyridine moiety gave lower molar absorptivity coefficient at relatively similar wavelength characteristics (410-520 nm) when compared to C3 and C4 with phenanthroline based molecules. Cyclic voltammograms of the complexes revealed complex C4 with most reduction potential which might be due to increase in the conjugation of the anthracene functionalized units. Preliminary investigation of the solar cell efficiency of the complexes on TiO2 nanocrystalline films gave the best result with efficiency of 0.103% for C1 under illumination at 1000 W/m2 AM 1.5. Electrochemical impedance spectroscopy (EIS) technique however, revealed the charge transfer resistances (Rct) of the electrons on the TiO2 semiconductor.

  8. Angular dependent light emission from planar waveguides

    Energy Technology Data Exchange (ETDEWEB)

    Peter, Jaison, E-mail: jaison.peter@gmail.com [International School of Photonics, Cochin University of Science and Technology, Cochin 682022 (India); CRE" +E, IDEAS Research Institute, Robert Gordon University, Aberdeen AB10 7GJ (United Kingdom); Prabhu, Radhakrishna [CRE" +E, IDEAS Research Institute, Robert Gordon University, Aberdeen AB10 7GJ (United Kingdom); Radhakrishnan, P.; Vallabhan, C. P. G.; Nampoori, V. P. N.; Kailasnath, M. [International School of Photonics, Cochin University of Science and Technology, Cochin 682022 (India)

    2015-01-07

    We have investigated the angular dependence of amplified spontaneous emission (ASE) and laser emission from an asymmetric and free-standing polymer thin films doped with rhodamine 6G, which is transversely pumped by a pulsed Nd:YAG laser. A semi-leaky waveguide or quasi-waveguide structure has been developed by spin coating technique. In these waveguides, the light was confined by the film/air-film/glass substrate interfaces. At the film/substrate interface, a portion of light will reflect back into the film (guided mode) and the remaining refracted to the substrate resulting in cutoff modes. A blue-shift in ASE has been observed when the pump power was increased from 8 to 20 mW allowing a limited range of tuning of emission wavelength. To study the directionality of the ASE from the waveguide, we have measured the output intensity and FWHM of emission spectra as a function of viewing angle (θ) from the plane parallel to film. From the detailed examination of the output emission spectra, as +θ increases from 0° there has been an initial decrease in output intensity, but at a particular angle ≈10° an increase in output intensity was observed. This additional peak in output intensity as +θ is a clear indication of coexistence of the cutoff mode. We also present a compact solid-state laser based on leaky mode propagation from the dye-doped polymer free-standing film (∼50 μm thickness) waveguide. The partial reflections from the broad lateral surfaces of the free-standing films provided the optical feedback for the laser emission with high directionality. For a pump power of 22 mW, an intense line with FWHM <0.2 nm was observed at 578 nm.

  9. A race for RAGE ligands.

    Science.gov (United States)

    Schleicher, Erwin D

    2010-08-01

    In experimental animals a causal involvement of the multiligand receptor for advanced glycation end products (RAGE) in the development of diabetic vascular complications has been demonstrated. However, the nature of RAGE ligands present in patients with diabetic nephropathy has not yet been defined; this leaves open the relevance of the RAGE system to the human disease.

  10. The origin of angular momentum in dark matter halos

    CERN Document Server

    Vitvitska, M; Kravtsov, A V; Bullock, J S; Wechsler, R H; Primack, Joel R

    2002-01-01

    We propose a new explanation for the origin of angular momentum in galaxies and their dark halos, in which the halos obtain their spin through the cumulative acquisition of angular momentum from satellite accretion. In our model, the build-up of angular momentum is a random walk process associated with the mass assembly history of the halo's major progenitor. We assume no correlation between the angular momenta of accreted objects. Using the extended Press-Schechter approximation, we calculate the growth of mass, angular momentum, and spin parameter $\\lambda$ for many halos. Our random walk model reproduces the key features of the angular momentum of halos found in N-body simulations: a lognormal distribution in $\\lambda$ with an average of $ \\approx 0.04$, independent of mass and redshift. The evolution of the spin parameter in individual halos in this model is quite different from the steady increase with time of angular momentum in the tidal torque picture. We find both in N-body simulations and in our ran...

  11. Knee abduction angular impulses during prolonged running with wedged insoles.

    Science.gov (United States)

    Lewinson, Ryan T; Worobets, Jay T; Stefanyshyn, Darren J

    2013-07-01

    Wedged insoles may produce immediate effects on knee abduction angular impulses during running; however, it is currently not known whether these knee abduction angular impulse magnitudes are maintained throughout a run when fatigue sets in. If changes occur, this could affect the clinical utility of wedged insoles in treating conditions such as patellofemoral pain. Thus, the purpose of this study was to determine whether knee abduction angular impulses are altered during a prolonged run with wedged insoles. It was hypothesized that knee abduction angular impulses would be reduced following a prolonged run with wedged insoles. Nine healthy runners participated. Runners were randomly assigned to either a 6-mm medial wedge condition or a 6-mm lateral wedge condition and then ran continuously overground for 30 min. Knee abduction angular impulses were quantified at 0 and 30 min using a gait analysis procedure. After 2 days, participants returned to perform the same test but with the other wedge type. Two-way repeated-measures analysis of variance was used to evaluate main effects of wedge condition and time and interactions between wedge condition and time (α = 0.05). Paired t-tests were used for post hoc analysis (α = 0.01). No interaction effects (p = 0.958) were found, and knee abduction angular impulses were not significantly different over time (p = 0.384). Lateral wedge conditions produced lesser knee abduction angular impulses than medial conditions at 0 min (difference of 2.79 N m s, p = 0.006) and at 30 min (difference of 2.76 N m s, p < 0.001). It is concluded that significant knee abduction angular impulse changes within wedge conditions do not occur during a 30-min run. Additionally, knee abduction angular impulse differences between wedge conditions are maintained during a 30-min run.

  12. Coherent detection of orbital angular momentum in radio

    CERN Document Server

    Daldorff, L K S; Bergman, J E S; Isham, B; Al-Nuaimi, M K T; Forozesh, K; Carozzi, T D

    2015-01-01

    The angular momentum propagated by a beam of radiation has two contributions: spin angular momentum (SAM) and orbital angular momentum (OAM). SAM corresponds to wave polarisation, while OAM-carrying beams are characterized by a phase which is a function of azimuth. We demonstrate experimentally that radio beams propagating OAM can be generated and coherently detected using ordinary electric dipole antennas. The results presented here could pave the way for novel radio OAM applications in technology and science, including radio communication, passive remote sensing, and new types of active (continuous or pulsed transmission) electromagnetic measurements.

  13. On Angular Sampling Methods for 3-D Spatial Channel Models

    DEFF Research Database (Denmark)

    Fan, Wei; Jämsä, Tommi; Nielsen, Jesper Ødum

    2015-01-01

    This paper discusses generating three dimensional (3D) spatial channel models with emphasis on the angular sampling methods. Three angular sampling methods, i.e. modified uniform power sampling, modified uniform angular sampling, and random pairing methods are proposed and investigated in detail....... The random pairing method, which uses only twenty sinusoids in the ray-based model for generating the channels, presents good results if the spatial channel cluster is with a small elevation angle spread. For spatial clusters with large elevation angle spreads, however, the random pairing method would fail...... and the other two methods should be considered....

  14. Angular and radial mode analyzer for optical beams.

    Science.gov (United States)

    Abouraddy, Ayman F; Yarnall, Timothy M; Saleh, Bahaa E A

    2011-12-01

    We describe an approach to determining both the angular and the radial modal content of a scalar optical beam in terms of optical angular momentum modes. A modified Mach-Zehnder interferometer that incorporates a spatial rotator to determine the angular modes and an optical realization of the fractional Hankel transform (fHT) to determine the radial modes is analyzed. Varying the rotation angle and the order of the fHT produces a two-dimensional (2D) interferogram from which we extract the modal coefficients by simple 2D Fourier analysis.

  15. Control of Angular Intervals for Angle-Multiplexed Holographic Memory

    Science.gov (United States)

    Kinoshita, Nobuhiro; Muroi, Tetsuhiko; Ishii, Norihiko; Kamijo, Koji; Shimidzu, Naoki

    2009-03-01

    In angle-multiplexed holographic memory, the full width at half maximum of the Bragg selectivity curves is dependent on the angle formed between the medium and incident laser beams. This indicates the possibility of high density and high multiplexing number by varying the angular intervals between adjacent holograms. We propose an angular interval scheduling for closely stacking holograms into medium even when the angle range is limited. We obtained bit error rates of the order of 10-4 under the following conditions: medium thickness of 1 mm, laser beam wavelength of 532 nm, and angular multiplexing number of 300.

  16. Angular magnetoresistance in semiconducting undoped amorphous carbon thin films

    Energy Technology Data Exchange (ETDEWEB)

    Sagar, Rizwan Ur Rehman; Saleemi, Awais Siddique; Zhang, Xiaozhong, E-mail: xzzhang@tsinghua.edu.cn [Key Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, People' s Republic of China and Beijing National Center for Electron Microscopy, Beijing 100084 (China)

    2015-05-07

    Thin films of undoped amorphous carbon thin film were fabricated by using Chemical Vapor Deposition and their structure was investigated by using High Resolution Transmission Electron Microscopy and Raman Spectroscopy. Angular magnetoresistance (MR) has been observed for the first time in these undoped amorphous carbon thin films in temperature range of 2 ∼ 40 K. The maximum magnitude of angular MR was in the range of 9.5% ∼ 1.5% in 2 ∼ 40 K. The origin of this angular MR was also discussed.

  17. Induced Compression of White Dwarfs by Angular Momentum Loss

    CERN Document Server

    Boshkayev, Kuantay; Ruffini, Remo; Zhami, Bakytzhan

    2016-01-01

    We investigate isolated sub- and super-Chandrasekhar white dwarfs which lose angular momentum through magnetic dipole braking. We construct constant rest mass sequences by fulfilling all stability criteria of rotating configurations and show how the main structure of white dwarfs such as the central density, mean radius and angular velocity change with time. We explicitly demonstrate that all isolated white dwarfs regardless of their masses, by angular momentum loss, shrink and increase their central density. We also analyze the effects of the structure parameters on the evolution timescale both in the case of constant magnetic field and constant magnetic flux.

  18. Electro-optic analyzer of angular momentum hyperentanglement.

    Science.gov (United States)

    Wu, Ziwen; Chen, Lixiang

    2016-02-25

    Characterizing a high-dimensional entanglement is fundamental in quantum information applications. Here, we propose a theoretical scheme to analyze and characterize the angular momentum hyperentanglement that two photons are entangled simultaneously in spin and orbital angular momentum. Based on the electro-optic sampling with a proposed hyper-entanglement analyzer and the simple matrix operation using Cramer rule, our simulations show that it is possible to retrieve effectively both the information about the degree of polarization entanglement and the spiral spectrum of high-dimensional orbital angular momentum entanglement.

  19. Detection of a spinning object using light's orbital angular momentum.

    Science.gov (United States)

    Lavery, Martin P J; Speirits, Fiona C; Barnett, Stephen M; Padgett, Miles J

    2013-08-01

    The linear Doppler shift is widely used to infer the velocity of approaching objects, but this shift does not detect rotation. By analyzing the orbital angular momentum of the light scattered from a spinning object, we observed a frequency shift proportional to product of the rotation frequency of the object and the orbital angular momentum of the light. This rotational frequency shift was still present when the angular momentum vector was parallel to the observation direction. The multiplicative enhancement of the frequency shift may have applications for the remote detection of rotating bodies in both terrestrial and astronomical settings.

  20. Generation and detection of orbital angular momentum via metasurface.

    Science.gov (United States)

    Jin, Jinjin; Luo, Jun; Zhang, Xiaohu; Gao, Hui; Li, Xiong; Pu, Mingbo; Gao, Ping; Zhao, Zeyu; Luo, Xiangang

    2016-04-07

    Beams carrying orbital angular momentum possess a significant potential for modern optical technologies ranging from classical and quantum communication to optical manipulation. In this paper, we theoretically design and experimentally demonstrate an ultracompact array of elliptical nanoholes, which could convert the circularly polarized light into the cross-polarized vortex beam. To measure the topological charges of orbital angular momentum in a simple manner, another elliptical nanoholes array is designed to generate reference beam as a reference light. This approach may provide a new way for the generation and detection of orbital angular momentum in a compact device.

  1. Orbital angular momentum in optical fibers

    Science.gov (United States)

    Bozinovic, Nenad

    Internet data traffic capacity is rapidly reaching limits imposed by nonlinear effects of single mode fibers currently used in optical communications. Having almost exhausted available degrees of freedom to orthogonally multiplex data in optical fibers, researchers are now exploring the possibility of using the spatial dimension of fibers, via multicore and multimode fibers, to address the forthcoming capacity crunch. While multicore fibers require complex manufacturing, conventional multi-mode fibers suffer from mode coupling, caused by random perturbations in fibers and modal (de)multiplexers. Methods that have been developed to address the problem of mode coupling so far, have been dependent on computationally intensive digital signal processing algorithms using adaptive optics feedback or complex multiple-input multiple-output algorithms. Here we study the possibility of using the orbital angular momentum (OAM), or helicity, of light, as a means of increasing capacity of future optical fiber communication links. We first introduce a class of specialty fibers designed to minimize mode coupling and show their potential for OAM mode generation in fibers using numerical analysis. We then experimentally confirm the existence of OAM states in these fibers using methods based on fiber gratings and spatial light modulators. In order to quantify the purity of created OAM states, we developed two methods based on mode-image analysis, showing purity of OAM states to be 90% after 1km in these fibers. Finally, in order to demonstrate data transmission using OAM states, we developed a 4-mode multiplexing and demultiplexing systems based on free-space optics and spatial light modulators. Using simple coherent detection methods, we successfully transmit data at 400Gbit/s using four OAM modes at a single wavelength, over 1.1 km of fiber. Furthermore, we achieve data transmission at 1.6Tbit/s using 10 wavelengths and two OAM modes. Our study indicates that OAM light can exist

  2. Cosmology Large Angular Scale Surveyor (CLASS) Focal Plane Development

    CERN Document Server

    Chuss, D T; Amiri, M; Appel, J; Bennett, C L; Colazo, F; Denis, K L; Dünner, R; Essinger-Hileman, T; Eimer, J; Fluxa, P; Gothe, D; Halpern, M; Harrington, K; Hilton, G; Hinshaw, G; Hubmayr, J; Iuliano, J; Marriage, T A; Miller, N; Moseley, S H; Mumby, G; Petroff, M; Reintsema, C; Rostem, K; U-Yen, K; Watts, D; Wagner, E; Wollack, E J; Xu, Z; Zeng, L

    2015-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) will measure the polarization of the Cosmic Microwave Background to search for and characterize the polarized signature of inflation. CLASS will operate from the Atacama Desert and observe $\\sim$70% of the sky. A variable-delay polarization modulator (VPM) modulates the polarization at $\\sim$10 Hz to suppress the 1/f noise of the atmosphere and enable the measurement of the large angular scale polarization modes. The measurement of the inflationary signal across angular scales that span both the recombination and reionization features allows a test of the predicted shape of the polarized angular power spectra in addition to a measurement of the energy scale of inflation. CLASS is an array of telescopes covering frequencies of 38, 93, 148, and 217 GHz. These frequencies straddle the foreground minimum and thus allow the extraction of foregrounds from the primordial signal. Each focal plane contains feedhorn-coupled transition-edge sensors that simultaneously d...

  3. "Angle" Operator Conjugate to Photon's Intrinsic Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    范洪义

    2001-01-01

    We find the correct "angle" operator conjugate to the intrinsic angular momentum of the photon by introducing a suitable representation which involves both left-handed and right-handed polarization photon operators.

  4. General covariant conservative angular momentum as internal charges

    Institute of Scientific and Technical Information of China (English)

    赵德品

    1996-01-01

    The usual approach to internal conservative charges is used to obtain the conservation laws of angular-momentum in both Einstein gravity and gravitational anyons.The results are in complete agreement with those of references.

  5. Imaging the Earth's Interior: the Angular Distribution of Terrestrial Neutrinos

    CERN Document Server

    Fields, Brian D

    2004-01-01

    Decays of radionuclides throughout the Earth's interior produce geothermal heat, but also are a source of antineutrinos. The (angle-integrated) geoneutrino flux places an integral constraint on the terrestrial radionuclide distribution. In this paper, we calculate the angular distribution of geoneutrinos, which opens a window on the differential radionuclide distribution. We develop the general formalism for the neutrino angular distribution, and we present the inverse transformation which recovers the terrestrial radioisotope distribution given a measurement of the neutrino angular distribution. Thus, geoneutrinos not only allow a means to image the Earth's interior, but offering a direct measure of the radioactive Earth, both (1) revealing the Earth's inner structure as probed by radionuclides, and (2) allowing for a complete determination of the radioactive heat generation as a function of radius. We present the geoneutrino angular distribution for the favored Earth model which has been used to calculate g...

  6. Quantum optimal control of photoelectron spectra and angular distributions

    CERN Document Server

    Goetz, R Esteban; Santra, Robin; Koch, Christiane P

    2016-01-01

    Photoelectron spectra and photoelectron angular distributions obtained in photoionization reveal important information on e.g. charge transfer or hole coherence in the parent ion. Here we show that optimal control of the underlying quantum dynamics can be used to enhance desired features in the photoelectron spectra and angular distributions. To this end, we combine Krotov's method for optimal control theory with the time-dependent configuration interaction singles formalism and a splitting approach to calculate photoelectron spectra and angular distributions. The optimization target can account for specific desired properties in the photoelectron angular distribution alone, in the photoelectron spectrum, or in both. We demonstrate the method for hydrogen and then apply it to argon under strong XUV radiation, maximizing the difference of emission into the upper and lower hemispheres, in order to realize directed electron emission in the XUV regime.

  7. Pluto Moons exhibit Orbital Angular Momentum Quantization per Mass

    Directory of Open Access Journals (Sweden)

    Potter F.

    2012-10-01

    Full Text Available The Pluto satellite system of the planet plus five moons is shown to obey the quan- tum celestial mechanics (QCM angular momentum per mass quantization condition predicted for any gravitationally bound system.

  8. Uncertainty Relation between Angular Momentum and Angle Variable.

    Science.gov (United States)

    Roy, C. L.; Sannigrahi, A. B.

    1979-01-01

    Discusses certain pitfalls regarding the uncertainty relation between angular momentum and the angle variable from a pedagogic point of view. Further, an uncertainty relation has been derived for these variables in a simple and consistant manner. (Author/HM)

  9. Effect of angular momentum conservation on hydrodynamic simulations of colloids.

    Science.gov (United States)

    Yang, Mingcheng; Theers, Mario; Hu, Jinglei; Gompper, Gerhard; Winkler, Roland G; Ripoll, Marisol

    2015-07-01

    In contrast to most real fluids, angular momentum is not a locally conserved quantity in some mesoscopic simulation methods. Here we quantify the importance of this conservation in the flow fields associated with different colloidal systems. The flow field is analytically calculated with and without angular momentum conservation for the multiparticle collision dynamics (MPC) method, and simulations are performed to verify the predictions. The flow field generated around a colloidal particle moving under an external force with slip boundary conditions depends on the conservation of angular momentum, and the amplitude of the friction force is substantially affected. Interestingly, no dependence on the angular momentum conservation is found for the flow fields generated around colloids under the influence of phoretic forces. Moreover, circular Couette flow between a no-slip and a slip cylinder is investigated, which allows us to validate one of the two existing expressions for the MPC stress tensor.

  10. Orbital angular momentum in optical waves propagating through distributed turbulence.

    Science.gov (United States)

    Sanchez, Darryl J; Oesch, Denis W

    2011-11-21

    This is the second of two papers demonstrating that photons with orbital angular momentum can be created in optical waves propagating through distributed turbulence. In the companion paper, it is shown that propagation through atmospheric turbulence can create non-trivial angular momentum. Here, we extend the result and demonstrate that this momentum is, at least in part, orbital angular momentum. Specifically, we demonstrate that branch points (in the language of the adaptive optic community) indicate the presence of photons with non-zero OAM. Furthermore, the conditions required to create photons with non-zero orbital angular momentum are ubiquitous. The repercussions of this statement are wide ranging and these are cursorily enumerated.

  11. Relevance of angular momentum conservation in mesoscale hydrodynamics simulations.

    Science.gov (United States)

    Götze, Ingo O; Noguchi, Hiroshi; Gompper, Gerhard

    2007-10-01

    The angular momentum is conserved in fluids with a few exceptions such as ferrofluids. However, it can be violated locally in fluid simulations to reduce computational costs. The effects of this violation are investigated using a particle-based simulation method, multiparticle collision dynamics, which can switch on or off angular-momentum conservation. To this end, we study circular Couette flows between concentric and eccentric cylinders, where nonphysical torques due to the lack of the angular-momentum conservation are found whereas the velocity field is not affected. In addition, in simulations of fluids with different viscosities in contact and star polymers in solvent, incorrect angular velocities occur. These results quantitatively agree with the theoretical predictions based on the macroscopic stress tensor.

  12. Design and Implementation of a Digital Angular Rate Sensor

    Directory of Open Access Journals (Sweden)

    Zhen Peng

    2010-10-01

    Full Text Available With the aim of detecting the attitude of a rotating carrier, the paper presents a novel, digital angular rate sensor. The sensor consists of micro-sensing elements (gyroscope and accelerometer, signal processing circuit and micro-processor (DSP2812. The sensor has the feature of detecting three angular rates of a rotating carrier at the same time. The key techniques of the sensor, including sensing construction, sensing principles, and signal processing circuit design are presented. The test results show that the sensor can sense rolling, pitch and yaw angular rate at the same time and the measurement error of yaw (or pitch angular rate and rolling rate of the rotating carrier is less than 0.5%.

  13. Design and implementation of a digital angular rate sensor.

    Science.gov (United States)

    Wu, Li-Feng; Peng, Zhen; Zhang, Fu-Xue

    2010-01-01

    With the aim of detecting the attitude of a rotating carrier, the paper presents a novel, digital angular rate sensor. The sensor consists of micro-sensing elements (gyroscope and accelerometer), signal processing circuit and micro-processor (DSP2812). The sensor has the feature of detecting three angular rates of a rotating carrier at the same time. The key techniques of the sensor, including sensing construction, sensing principles, and signal processing circuit design are presented. The test results show that the sensor can sense rolling, pitch and yaw angular rate at the same time and the measurement error of yaw (or pitch) angular rate and rolling rate of the rotating carrier is less than 0.5%.

  14. Coriolis effects are principally caused by gyroscopic angular acceleration.

    Science.gov (United States)

    Isu, N; Yanagihara, M; Mikuni, T; Koo, J

    1994-07-01

    A cause of nausea evoked by cross-coupled rotation (termed Coriolis stimulus) was determined. Subjects were provided with two types of cross-coupled rotations: neck-forward flexion (Neck Flx) and upper body-forward flexion (Body Flx) during horizontal whole body rotation at a constant angular velocity. These Coriolis stimuli were given alternatively in an experimental sequence, and the severity of the nausea they evoked was compared by the subjects. The results indicated that the same quality of nausea was evoked by a slightly higher angular velocity during Body Flx (100.5 degrees/s) than during Neck Flx (90 degrees/s). While Body Flx generated Coriolis linear acceleration several times larger than Neck Flx, both the stimuli generated a similar magnitude of gyroscopic angular acceleration in this condition. Therefore, it was inferred that the nausea evoked by a Coriolis stimulus is principally caused by gyroscopic angular acceleration.

  15. All joint moments significantly contribute to trunk angular acceleration.

    Science.gov (United States)

    Nott, Cameron R; Zajac, Felix E; Neptune, Richard R; Kautz, Steven A

    2010-09-17

    Computationally advanced biomechanical analyses of gait demonstrate the often counter-intuitive roles of joint moments on various aspects of gait such as propulsion, swing initiation, and balance. Each joint moment can produce linear and angular acceleration of all body segments (including those on which the moment does not directly act) due to the dynamic coupling inherent in the interconnected musculoskeletal system. This study presents quantitative relationships between individual joint moments and trunk control with respect to balance during gait to show that the ankle, knee, and hip joint moments all affect the angular acceleration of the trunk. We show that trunk angular acceleration is affected by all joints in the leg with varying degrees of dependence during the gait cycle. Furthermore, it is shown that inter-planar coupling exists and a two-dimensional analysis of trunk balance neglects important out-of-plane joint moments that affect trunk angular acceleration.

  16. Angular dynamics of small crystals in viscous flows

    Science.gov (United States)

    Fries, Johan; Einarsson, Jonas; Mehlig, Bernhard

    2016-11-01

    The angular dynamics of a very small ellipsoidal particle in a viscous flow decouples from its translational dynamics, and the particle angular velocity is given by Jeffery's theory. It is known that cuboid particles share these properties. In the literature a special case is most frequently discussed, that of axisymmetric particles, with a continuous rotational symmetry. Here we compute the angular dynamics of crystals that possess a discrete rotational symmetry and certain mirror symmetries, but that do not have a continuous rotational symmetry. We give examples of such particles that nevertheless obey Jeffery's theory. But there are other examples where the angular dynamics is determined by a more general equation of motion. Vetenskapsrådet [Grant Number 2013-3992], Formas [Grant Number 2014-585], "Bottlenecks for particle growth in turbulent aerosols" from the Knut and Alice Wallenberg Foundation, Dnr. KAW 2014.0048, MPNS COST Action MP1305 "Flowing matter".

  17. Spatial-angular modeling of ground-based biaxial lidar

    Science.gov (United States)

    Agishev, Ravil R.

    1997-10-01

    Results of spatial-angular LIDAR modeling based on an efficiency criterion introduced are represented. Their analysis shows that a low spatial-angular efficiency of traditional VIS and NIR systems is a main cause of a low S/BR ratio at the photodetector input. It determines the considerable measurements errors and the following low accuracy of atmospheric optical parameters retrieval. As we have shown, the most effective protection against intensive sky background radiation for ground-based biaxial LIDAR's consist in forming of their angular field according to spatial-angular efficiency criterion G. Some effective approaches to high G-parameter value achievement to achieve the receiving system optimization are discussed.

  18. Mixed-ligand copper(II) phenolate complexes: Synthesis, spectral characterization, phosphate-hydrolysis, antioxidant, DNA interaction and cytotoxic studies

    Science.gov (United States)

    Gurumoorthy, Perumal; Mahendiran, Dharmasivam; Prabhu, Durai; Arulvasu, Chinnasamy; Rahiman, Aziz Kalilur

    2015-01-01

    A series of phenol-based mixed-ligand copper(II) complexes of the type [CuL1-4(diimine)] (1-8), where L1-4 = N1,N2-bis(5-substituted-2-hydroxybenzylidene)-1,2-ethylene/phenylenediimine and diimine = 2,2‧-bipyridyl (bpy) or 1,10-phenanthroline (phen), have been isolated and fully characterized by analytical and spectral techniques. Electronic spectra of complexes suggest Cu(II) cation has a d9 electronic configuration, adopting distorted octahedral geometry with axial elongation, due to Jahn-Teller effect. Electrochemical studies of complexes evidenced one-electron irreversible reduction wave in the cathodic region. The observed rate constant (k) values for the hydrolysis of 4-nitrophenylphosphate (4-NPP) are in the range of 0.25-3.82 × 10-2 min-1. The obtained room temperature magnetic moment values (1.79-1.90 BM) lies within the range observed for octahedral copper(II) complexes. Antioxidant studies revealed that these complexes possess considerable radical scavenging potency against DPPH. The binding studies of complexes with calf thymus DNA (CT-DNA) revealed intercalation with minor-groove binding, and the complex 4 exhibits highest binding activity than the other complexes. The cleavage activity on supercoiled pBR322 DNA revealed the involvement of hydroxyl radical and singlet-oxygen as reactive oxygen species, and complexes encourage binding to minor-groove. Further, the cytotoxicity of complex 4 on human hepatocellular liver carcinoma HepG2 cell line implies the cell death through apoptosis.

  19. Antimicrobial mechanism of copper (II 1,10-phenanthroline and 2,2′-bipyridyl complex on bacterial and fungal pathogens

    Directory of Open Access Journals (Sweden)

    S. Chandraleka

    2014-12-01

    Full Text Available Copper based metallo drugs were prepared and their antibacterial, antifungal, molecular mechanism of [Cu(SAlaPhen]·H2O and [Cu(SAlabpy]·H2O complexes were investigated. The [Cu(SAlaPhen]·H2O and [Cu(SAlabpy]·H2O were derived from the Schiff base alanine salicylaldehyde. [Cu(SAlaPhen]·H2O showed noteworthy antibacterial and antifungal activity than the [Cu(SAlabpy]·H2O and ligand alanine, salicylaldehyde. The [Cu(SAlaPhen]·H2O complex showed significant antibacterial activity against Salmonella typhi, Staphylococcus aureus, Salmonella paratyphi and the antifungal activity against Candida albicans and Cryptococcus neoformans in well diffusion assay. The mode of action of copper (II complex was analyzed by DNA cleavage activity and in silico molecular docking. The present findings provide important insight into the molecular mechanism of copper (II complexes in susceptible bacterial and fungal pathogens. These results collectively support the use of [Cu(SAlaPhen]·H2O complex as a suitable drug to treat bacterial and fungal infections.

  20. Students' Understanding of the Addition of Angular Momentum

    CERN Document Server

    Singh, Chandralekha

    2016-01-01

    We describe the difficulties advanced undergraduate and graduate students have with concepts related to the addition of angular momentum. We also describe the development and implementation of a research-based learning tool, a Quantum Interactive Learning Tutorial (QuILT), to reduce these difficulties. The preliminary evaluation shows that the QuILT on the addition of angular momentum is helpful in improving students' understanding of these concepts.

  1. Comparison between two concepts of angular glint:general considerations

    Institute of Scientific and Technical Information of China (English)

    Wang Chao; Yin Hongcheng; Huang Peikang

    2008-01-01

    Angular glint can be interpreted as a distortion of the radar echo signal phase front,or alternatively,a tilt of the direction of energy flow from the radial direction.As the complementarities and support of argumentation in our previous work,a general discussion about two concepts of angular glint is made based on electromagnetic theory to demonstrate that these two concepts are equivalent when geometrical optics approximation is used and the receiving antenna is linearly polarized.

  2. Four Cases of Angular Cheilitis in Orthodontic Patients

    OpenAIRE

    P Kafaie; S Yassaei

    2006-01-01

    Contact dermatitis is an inflammatory reaction of the skin and mucosa to either external or internal factors. It can be divided to two forms of irritant contact dermatitis and allergic contact dermatitis. Nickel is one of the most common materials that causes allergic contact dermatitis and is widely used in orthodontic appliances. The inflammatory reaction to this metal in orthodontics is usually stomatitis and angular cheilitis is very rare. We report 4 cases of angular cheilitis in orthodo...

  3. On the angular distribution of extensive air showers

    CERN Document Server

    Zotov, M Yu; Kulikov, G V; Sulakov, V P

    2009-01-01

    Angular distributions of extensive air showers with different number of charged particles in the range 2.5x10^5--4x10^7 are derived using the experimental data obtained with the EAS MSU array. Possible approximations of the obtained distributions with different empiric functions available in literature, are analysed. It is shown that the exponential function provides the best approximation of the angular distributions in the sense of the chi-squared criterion.

  4. Relativistic electron ring equilibrium with angular momentum spread

    Energy Technology Data Exchange (ETDEWEB)

    Croitoru, M.; Grecu, D. (Institutul de Fizica si Inginerie Nucleara, Bucharest (Romania))

    1980-01-01

    The equilibrium properties of a relativistic electron ring are determined by solving in a consistent way the Vlasov-Maxwell equations for a distribution function with an angular momentum spread. In the thin ring approximation there have been deduced general formulae for the electron density and the current density. A general theorem concerning the sharp form in space of the electron density is also obtained for the case of a microcanonical distribution function both in energy and angular momentum.

  5. Diffraction by a plane angular sector, a new derivation

    DEFF Research Database (Denmark)

    Hansen, Thokild B.

    1990-01-01

    An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)......An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)...

  6. NUTRITIONAL STATUS ASSOCIATION WITH ANGULAR CHEILITIS IN PRIMARY STUDENT AGE

    OpenAIRE

    Sumintarti, Sumintarti

    2013-01-01

    ABSTRACT Student in primary level school is in fast and active growth. In this growth stage, they have to supplied by high enough nutrition in exact quality and quantity otherwise they will suffer with some oral disease such as angular cheilitis. This study aimed to measured any association of nutritional status and angular cheilitis occurrence in primary student of Lae-Lae II and Pampang elementary state schools. We used observational analytic with purposive sampling method. All student...

  7. A Role for Improved Angular Observations in Geosynchronous Orbit Determination

    Science.gov (United States)

    Sabol, Christopher Andrew

    1998-12-01

    The goal of this thesis is to show that improved angular observations can aid in the determination of satellite position and velocity in the geosynchronous orbit regime. Raven is a new sensor being developed by the U.S. Air Force Research Laboratory which should allow for angular observations of satellites to be made with a standard deviation of 1 arcsecond (which maps into approximately 170 meters at geosynchronous altitude); this is an order of magnitude improvement over traditional angular observation techniques and represents state of the art accuracy of angular observations for geosynchronous orbit determination work. Simulation studies are undertaken to show that these angular observations can be used in the orbit determination process both as the only cracking data source and as a supplement to other tracking data sources such as radar and radio transponder ranges. Results from the radio transponder range analysis are extended to cover Satellite Laser Ranging (SLR) and Global Positioning System (GPS) observation types as well. The studies target both space surveillance and owner/operator mission support aspects of orbit determination although the emphasis will be on mission support satellite operations. Parameters varied in the simulation studies include the number of observing stations, the density of the angular observations, and the number of nights of optical tracking. The data simulations are calibrated based on real data results from a geosynchronous satellite to ensure the integrity of the simulations and the accuracy of the results. The studies show that including the improved angular observations with traditional high accuracy range observations produces a significant improvement in orbit determination accuracy over the range observations alone. The studies also show single site geosynchronous orbit determination is an attractive alternative when combining improved angular and high accuracy range observations.

  8. Statistical Angular Resolution Limit for Ultrawideband MIMO Noise Radar

    OpenAIRE

    2015-01-01

    The two-dimensional angular resolution limit (ARL) of elevation and azimuth for MIMO radar with ultrawideband (UWB) noise waveforms is investigated using statistical resolution theory. First, the signal model of monostatic UWB MIMO noise radar is established in a 3D reference frame. Then, the statistical angular resolution limits (SARLs) of two closely spaced targets are derived using the detection-theoretic and estimation-theoretic approaches, respectively. The detection-theoretic approach i...

  9. Controlled-deactivation cannabinergic ligands.

    Science.gov (United States)

    Sharma, Rishi; Nikas, Spyros P; Paronis, Carol A; Wood, Jodianne T; Halikhedkar, Aneetha; Guo, Jason Jianxin; Thakur, Ganesh A; Kulkarni, Shashank; Benchama, Othman; Raghav, Jimit Girish; Gifford, Roger S; Järbe, Torbjörn U C; Bergman, Jack; Makriyannis, Alexandros

    2013-12-27

    We report an approach for obtaining novel cannabinoid analogues with controllable deactivation and improved druggability. Our design involves the incorporation of a metabolically labile ester group at the 2'-position on a series of (-)-Δ(8)-THC analogues. We have sought to introduce benzylic substituents α to the ester group which affect the half-lives of deactivation through enzymatic activity while enhancing the affinities and efficacies of individual ligands for the CB1 and CB2 receptors. The 1'-(S)-methyl, 1'-gem-dimethyl, and 1'-cyclobutyl analogues exhibit remarkably high affinities for both CB receptors. The novel ligands are susceptible to enzymatic hydrolysis by plasma esterases in a controllable manner, while their metabolites are inactive at the CB receptors. In further in vitro and in vivo experiments key analogues were shown to be potent CB1 receptor agonists and to exhibit CB1-mediated hypothermic and analgesic effects.

  10. Privileged chiral ligands and catalysts

    CERN Document Server

    Zhou, Qi-Lin

    2011-01-01

    This ultimate ""must have"" and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these ""privileged catalysts"". A novel concept that gives readers a much deeper insight into the topic.

  11. Tumor targeting via integrin ligands

    Directory of Open Access Journals (Sweden)

    Udaya Kiran eMarelli

    2013-08-01

    Full Text Available Selective and targeted delivery of drugs to tumors is a major challenge for an effective cancer therapy and also to overcome the side effects associated with current treatments. Overexpression of various receptors on tumor cells is a characteristic structural and biochemical aspect of tumors and distinguishes them from physiologically normal cells. This abnormal feature is therefore suitable for selectively directing anticancer molecules to tumors by using ligands that can preferentially recognize such receptors. Several subtypes of integrin receptors that are crucial for cell adhesion, cell signaling, cell viability and motility have been shown to have an upregulated expression on cancer cells. Thus, ligands that recognize specific integrin subtypes represent excellent candidates to be conjugated to drugs or drug carrier systems and be targeted to tumors. In this regard, integrins recognizing the RGD cell adhesive sequence have been extensively targeted for tumor specific drug delivery. Here we review key recent examples on the presentation of RGD-based integrin ligands by means of distinct drug delivery systems, and discuss the prospects of such therapies to specifically target tumor cells.

  12. Theoretical calculations, DNA interaction, topoisomerase I and phosphatidylinositol-3-kinase studies of water soluble mixed-ligand nickel(II) complexes.

    Science.gov (United States)

    Gurumoorthy, Perumal; Mahendiran, Dharmasivam; Kalilur Rahiman, Aziz

    2016-03-25

    Eight water soluble mixed-ligand nickel(II) complexes of the type [NiL(1-4)(diimine)H2O]·(ClO4)2, (1-8) where L(1-4) = 2-((2-(piperazin-1-yl)ethylimino)methyl)-4-substituted phenols, and diimine = 2,2'-bipyridyl (bpy) or 1,10-phenanthroline (phen) were synthesized and characterized by elemental analysis and spectroscopic methods. The uncoordinated perchlorate anions was ascertained form IR spectra of the complexes, and the absorption spectra reveal the octahedron geometry around nickel(II) ion with tridentate Schiff base ligand, diimine and a coordinated water molecule. Cyclic voltammograms of the complexes indicate the one-electron irreversible processes in the cathodic and anodic region. In vitro antioxidant activity proved the significant radical scavenging activity of the complexes against DPPH radical. The groove/electrostatic binding nature of complexes with CT-DNA (calf thymus deoxyribonucleic acid) were affirmed by absorption, hydrodynamic and voltammetric titration experiments and docking analysis. All the complexes exhibit significant cleavage activity on plasmid DNA via hydrolytic and oxidatively, in which the oxidative mechanism involves hydroxyl radicals and supports the possibility of minor-groove binding. The complex 4 shows significant topoisomerase I (Topo-I) inhibitory activity. The molecular modeling analysis of complexes with phosphatidylinositol-3-kinase (PI3K) receptor indicate the hydrogen bonding with Met1039, Asp837 and Leu1027, and hydrophobic interactions with Ser488, Asn498, Asp500, Gln662, Lys668, Ile844, Ile847, Ile850, Val941, Leu942, Leu1020, Met1034, Leu1035, Thr1037, Met1039, Gln1041 and Ile1051 of subdomain IIA of BSA. The complexes show σ-π interaction between diimines and amino groups of Leu1030 and Arg839.

  13. The Angular Momentum of Baryons and Dark Matter Halos Revisited

    Science.gov (United States)

    Kimm, Taysun; Devriendt, Julien; Slyz, Adrianne; Pichon, Christophe; Kassin, Susan A.; Dubois, Yohan

    2011-01-01

    Recent theoretical studies have shown that galaxies at high redshift are fed by cold, dense gas filaments, suggesting angular momentum transport by gas differs from that by dark matter. Revisiting this issue using high-resolution cosmological hydrodynamics simulations with adaptive-mesh refinement (AMR), we find that at the time of accretion, gas and dark matter do carry a similar amount of specific angular momentum, but that it is systematically higher than that of the dark matter halo as a whole. At high redshift, freshly accreted gas rapidly streams into the central region of the halo, directly depositing this large amount of angular momentum within a sphere of radius r = 0.1R(sub vir). In contrast, dark matter particles pass through the central region unscathed, and a fraction of them ends up populating the outer regions of the halo (r/R(sub vir) > 0.1), redistributing angular momentum in the process. As a result, large-scale motions of the cosmic web have to be considered as the origin of gas angular momentum rather than its virialised dark matter halo host. This generic result holds for halos of all masses at all redshifts, as radiative cooling ensures that a significant fraction of baryons remain trapped at the centre of the halos. Despite this injection of angular momentum enriched gas, we predict an amount for stellar discs which is in fair agreement with observations at z=0. This arises because the total specific angular momentum of the baryons (gas and stars) remains close to that of dark matter halos. Indeed, our simulations indicate that any differential loss of angular momentum amplitude between the two components is minor even though dark matter halos continuously lose between half and two-thirds of their specific angular momentum modulus as they evolve. In light of our results, a substantial revision of the standard theory of disc formation seems to be required. We propose a new scenario where gas efficiently carries the angular momentum generated

  14. Cytotoxicity of Cu(II) and Zn(II) 2,2'-bipyridyl complexes: dependence of IC50 on recovery time.

    Science.gov (United States)

    Shi, Yi; Toms, Bonnie B; Dixit, Namrata; Kumari, Niraj; Mishra, Lallan; Goodisman, Jerry; Dabrowiak, James C

    2010-08-16

    We measure the cytotoxicity of three metal complexes containing the 2,2'-bypyridine ligand, Cu(bpy)(NCS)(2), 1, [Cu(bpy)(2)(H(2)O)](PF(6))(2), 2, and Zn(bpy)(2)(NCS)(2), 3, toward neuroblastoma cells (SK-N-SH) and ovarian cancer cells (OVCAR-3) using two different cell assays. The cells were exposed to various concentrations of the compounds for 1 h and the percent inhibition of cell growth, I, measured for various times after exposure, i.e., as a function of the recovery time t. After developing the theory showing the relationship between I and t, the cytotoxicity data were analyzed to reveal that the two copper complexes, 1 and 2, cause the cells to divide at a slower rate than the controls during the recovery period, but the zinc complex, 3, had little or no effect on cell division during the recovery period. The usual metric for reporting cytotoxicity is IC(50), which is the concentration of agent required to inhibit cell growth to 50% of the control population. However, since IC(50) can depend on the recovery time, t, as is the case for 1 and 2, reporting IC(50) for a single recovery time can hide important information about the long-time effects of a cytotoxic agent on the health of the cell population. Mechanistic studies with the compounds revealed that the copper complexes, 1 and 2, cleave closed circular pBR322 DNA in the presence of ascorbate, while the zinc complex, 3, does not facilitate DNA cleavage under the same conditions. This difference in DNA cleavage activity may be related to the fact that Cu(II) is redox active and can readily change its oxidation state, while Zn(II) is redox inert and cannot participate in a redox cycle with ascorbate to break DNA.

  15. Smoothed dissipative particle dynamics with angular momentum conservation

    Energy Technology Data Exchange (ETDEWEB)

    Müller, Kathrin, E-mail: k.mueller@fz-juelich.de; Fedosov, Dmitry A., E-mail: d.fedosov@fz-juelich.de; Gompper, Gerhard, E-mail: g.gompper@fz-juelich.de

    2015-01-15

    Smoothed dissipative particle dynamics (SDPD) combines two popular mesoscopic techniques, the smoothed particle hydrodynamics and dissipative particle dynamics (DPD) methods, and can be considered as an improved dissipative particle dynamics approach. Despite several advantages of the SDPD method over the conventional DPD model, the original formulation of SDPD by Español and Revenga (2003) [9], lacks angular momentum conservation, leading to unphysical results for problems where the conservation of angular momentum is essential. To overcome this limitation, we extend the SDPD method by introducing a particle spin variable such that local and global angular momentum conservation is restored. The new SDPD formulation (SDPD+a) is directly derived from the Navier–Stokes equation for fluids with spin, while thermal fluctuations are incorporated similarly to the DPD method. We test the new SDPD method and demonstrate that it properly reproduces fluid transport coefficients. Also, SDPD with angular momentum conservation is validated using two problems: (i) the Taylor–Couette flow with two immiscible fluids and (ii) a tank-treading vesicle in shear flow with a viscosity contrast between inner and outer fluids. For both problems, the new SDPD method leads to simulation predictions in agreement with the corresponding analytical theories, while the original SDPD method fails to capture properly physical characteristics of the systems due to violation of angular momentum conservation. In conclusion, the extended SDPD method with angular momentum conservation provides a new approach to tackle fluid problems such as multiphase flows and vesicle/cell suspensions, where the conservation of angular momentum is essential.

  16. Ligand placement based on prior structures: the guided ligand-replacement method

    Energy Technology Data Exchange (ETDEWEB)

    Klei, Herbert E. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Moriarty, Nigel W., E-mail: nwmoriarty@lbl.gov; Echols, Nathaniel [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Terwilliger, Thomas C. [Los Alamos National Laboratory, Los Alamos, NM 87545-0001 (United States); Baldwin, Eric T. [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Natural Discovery LLC, Princeton, NJ 08542-0096 (United States); Pokross, Matt; Posy, Shana [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Adams, Paul D. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); University of California at Berkeley, Berkeley, CA 94720-1762 (United States)

    2014-01-01

    A new module, Guided Ligand Replacement (GLR), has been developed in Phenix to increase the ease and success rate of ligand placement when prior protein-ligand complexes are available. The process of iterative structure-based drug design involves the X-ray crystal structure determination of upwards of 100 ligands with the same general scaffold (i.e. chemotype) complexed with very similar, if not identical, protein targets. In conjunction with insights from computational models and assays, this collection of crystal structures is analyzed to improve potency, to achieve better selectivity and to reduce liabilities such as absorption, distribution, metabolism, excretion and toxicology. Current methods for modeling ligands into electron-density maps typically do not utilize information on how similar ligands bound in related structures. Even if the electron density is of sufficient quality and resolution to allow de novo placement, the process can take considerable time as the size, complexity and torsional degrees of freedom of the ligands increase. A new module, Guided Ligand Replacement (GLR), was developed in Phenix to increase the ease and success rate of ligand placement when prior protein–ligand complexes are available. At the heart of GLR is an algorithm based on graph theory that associates atoms in the target ligand with analogous atoms in the reference ligand. Based on this correspondence, a set of coordinates is generated for the target ligand. GLR is especially useful in two situations: (i) modeling a series of large, flexible, complicated or macrocyclic ligands in successive structures and (ii) modeling ligands as part of a refinement pipeline that can automatically select a reference structure. Even in those cases for which no reference structure is available, if there are multiple copies of the bound ligand per asymmetric unit GLR offers an efficient way to complete the model after the first ligand has been placed. In all of these applications, GLR

  17. A micromachined angular-acceleration sensor for geophysical applications

    Science.gov (United States)

    Liu, Huafeng; Pike, W. T.

    2016-10-01

    This paper presents an angular-acceleration sensor that works as either an angular accelerometer or a gravity gradiometer and is based on the micro electromechanical system (MEMS) technology. The changes in the angle of the sensor mass are sensed by a rotational capacitive array transducer that is formed by electrodes on both the stator and rotor dies of the flip-chip-bonded MEMS chip (21 mm × 12.5 mm × 1 mm). The prototype was characterized, demonstrating a fundamental frequency of 27 Hz, a quality factor of 230 in air, and a sensitivity of 6 mV/(rad/s2). The demonstrated noise floor was less than 0.003 rad/s2/ √{ Hz } within a bandwidth of 0.1 Hz to 10 Hz, which is comparable with the conventional angular accelerometer and is better than the other reported MEMS sensors in low-frequency ranges. The features of small size and low cost suggest that this MEMS angular-acceleration sensor could be mounted on a drone, a satellite or even a Mars rover, and it is promising to be used for monitoring angular accelerations, aiding seismic recording, mapping gravity anomalies, and other geophysical applications for large-scale terrestrial and space deployments.

  18. The human ocular torsion position response during yaw angular acceleration.

    Science.gov (United States)

    Smith, S T; Curthoys, I S; Moore, S T

    1995-07-01

    Recent results by Wearne [(1993) Ph.D. thesis] using the scleral search-coil method of measuring eye position indicate that changes in ocular torsion position (OTP) occur during yaw angular acceleration about an earth vertical axis. The present set of experiments, using an image processing method of eye movement measurement free from the possible confound of search coil slippage, demonstrates the generality and repeatability of this phenomenon and examines its possible causes. The change in torsion position is not a linear vestibulo-ocular reflex (LVOR) response to interaural linear acceleration stimulation of the otoliths, but rather the effect is dependent on the characteristics of the angular acceleration stimulus, commencing at the onset and decaying at the offset of the angular acceleration. In the experiments reported here, the magnitude of the angular acceleration stimulus was varied and the torsion position response showed corresponding variations. We consider that the change in torsion position observed during angular acceleration is most likely to be due to activity of the semicircular canals.

  19. The angular momentum of baryons and dark matter halos revisited

    CERN Document Server

    Kimm, Taysun; Slyz, Adrianne; Pichon, Christophe; Kassin, Susan A; Dubois, Yohan

    2011-01-01

    Recent theoretical studies have shown that galaxies at high redshift are fed by cold, dense gas filaments, suggesting angular momentum transport by gas differs from that by dark matter. Revisiting this issue using high-resolution cosmological hydrodynamics simulations with adaptive mesh refinement, we find that at the time of accretion, gas and dark matter do carry a similar amount of specific angular momentum, but that it is systematically higher than that of the dark matter halo as a whole. At high redshift, freshly accreted gas rapidly streams into the central region of the halo, directly depositing this large amount of angular momentum within a sphere of radius r=0.1rvir. In contrast, dark matter particles pass through the central region unscathed, and a fraction of them ends up populating the outer regions of the halo (r/rvir>0.1), redistributing angular momentum in the process. As a result, large-scale motions of the cosmic web have to be considered as the origin of gas angular momentum rather than its ...

  20. Polarization control of single photon quantum orbital angular momentum states.

    Science.gov (United States)

    Nagali, E; Sciarrino, F; De Martini, F; Piccirillo, B; Karimi, E; Marrucci, L; Santamato, E

    2009-10-12

    The orbital angular momentum of photons, being defined in an infinite-dimensional discrete Hilbert space, offers a promising resource for high-dimensional quantum information protocols in quantum optics. The biggest obstacle to its wider use is presently represented by the limited set of tools available for its control and manipulation. Here, we introduce and test experimentally a series of simple optical schemes for the coherent transfer of quantum information from the polarization to the orbital angular momentum of single photons and vice versa. All our schemes exploit a newly developed optical device, the so-called "q-plate", which enables the manipulation of the photon orbital angular momentum driven by the polarization degree of freedom. By stacking several q-plates in a suitable sequence, one can also have access to higher-order angular momentum subspaces. In particular, we demonstrate the control of the orbital angular momentum m degree of freedom within the subspaces of |m| = 2h and |m| = 4h per photon.

  1. Functional phases and angular momentum characteristics of Tkatchev and Kovacs.

    Science.gov (United States)

    Irwin, Gareth; Exell, Timothy A; Manning, Michelle L; Kerwin, David G

    2017-03-01

    Understanding the technical requirements and underlying biomechanics of complex release and re-grasp skills on high bar allows coaches and scientists to develop safe and effective training programmes. The aim of this study was to examine the differences in the functional phases between the Tkatchev and Kovacs skills and to explain how the angular momentum demands are addressed. Images of 18 gymnasts performing 10 Tkatchevs and 8 Kovacs at the Olympic Games were recorded (50 Hz), digitised and reconstructed (3D Direct Linear Transformation). Orientation of the functional phase action, defined by the rapid flexion to extension of the shoulders and extension to flexion of the hips as the performer passed through the lower vertical, along with shoulder and hip angular kinematics, angular momentum and key release parameters (body angle, mass centre velocity and angular momentum about the mass centre and bar) were compared between skills. Expected differences in the release parameters of angle, angular momentum and velocity were observed and the specific mechanical requirement of each skill were highlighted. Whilst there were no differences in joint kinematics, hip and shoulder functional phase were significantly earlier in the circle for the Tkatchev. These findings highlight the importance of the orientation of the functional phase in the preceding giant swing and provide coaches with further understanding of the critical timing in this key phase.

  2. Gamma-Gamma Angular Correlation Measurements With GRIFFIN

    Science.gov (United States)

    Maclean, Andrew; Griffin Collaboration

    2016-09-01

    The goal of this work was to explore the sensitivity of the Gamma-Ray Infrastructure For Fundamental Investigations of Nuclei (GRIFFIN) 16 clover-detector γ-ray spectrometer at TRIUMF-ISAC to such γ - γ angular correlations. The methodology was established using both experimental measurements and Geant4 simulations that were used to create angular correlation templates for the GRIFFIN geometry. Direct comparisons were made between experimental data sets and the simulated angular correlation templates. A first in-beam test of the γ - γ angular correlation measurements with GRIFFIN was performed with a radioactive beam of 66Ga. Mixing ratios of δ = - 2 . 1(2) and δ = - 0 . 08(3) were measured for the 2+ ->2+ ->0+ 833-1039 keV and 1+ ->2+ ->0+ 2752-1039 keV cascades in the daughter nucleus 66Zn. These results are in good agreement with pervious literature values and the mixing ratio for the 833-1039 keV cascade has a higher precision. Also, the sensitivity to the 1333-1039 keV cascade, with its pronounced 0+ ->2+ ->0+ angular correlation, was measured.A test measurement of the superallowed Fermi β emitter 62Ga will also be discussed. Canada Foundation of Innovation, Natural Sciences and Engineering Research Council of Canada, National Research Council of Canada and Canadian Research Chairs Program.

  3. Crystal structures of (2,2′-bipyridyl-κ2N,N′bis[N,N-bis(2-hydroxyethyldithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′bis[N-(2-hydroxyethyl-N-isopropyldithiocarbamato-κ2S,S′]zinc

    Directory of Open Access Journals (Sweden)

    Siti Artikah M. Safbri

    2016-02-01

    Full Text Available The common feature of the title compounds, [Zn(C5H10NO2S22(C10H8N2]·2H2O, (I, and [Zn(C6H12NOS22(C10H8N2], (II, is the location of the ZnII atoms on a twofold rotation axis. Further, each ZnII atom is chelated by two symmetry-equivalent and symmetrically coordinating dithiocarbamate ligands and a 2,2′-bipyridine ligand. The resulting N2S4 coordination geometry is based on a highly distorted octahedron in each case. In the molecular packing of (I, supramolecular ladders mediated by O—H...O hydrogen bonding are found whereby the uprights are defined by {...HO(water...HO(hydroxy...}n chains parallel to the a axis and with the rungs defined by `Zn[S2CN(CH2CH22]2'. The water molecules connect the ladders into a supramolecular layer parallel to the ab plane via water-O—H...S and pyridyl-C—H...O(water interactions, with the connections between layers being of the type pyridyl-C—H...S. In (II, supramolecular layers parallel to the ab plane are sustained by hydroxy-O—H...S hydrogen bonds with connections between layers being of the type pyridyl-C—H...S.

  4. Is the angular momentum of an electron conserved in a uniform magnetic field?

    Science.gov (United States)

    Greenshields, Colin R; Stamps, Robert L; Franke-Arnold, Sonja; Barnett, Stephen M

    2014-12-12

    We show that an electron moving in a uniform magnetic field possesses a time-varying "diamagnetic" angular momentum. Surprisingly this means that the kinetic angular momentum of the electron may vary with time, despite the rotational symmetry of the system. This apparent violation of angular momentum conservation is resolved by including the angular momentum of the surrounding fields.

  5. The large-scale angular correlations in CMB temperature maps

    CERN Document Server

    Bernui, A

    2005-01-01

    Observations show that the Cosmic Microwave Background (CMB) contains tiny variations at the 10^{-5} level around its black-body equilibrium temperature. The detection of these temperature fluctuations provides to modern Cosmology evidence for the existence of primordial density perturbations that seeded all the structures presently observed. The vast majority of the cosmological information is contained in the 2-point temperature function, which measures the angular correlation of these temperature fluctuations distributed on the celestial sphere. Here we study such angular correlations using a recently introduced statistic-geometrical method. Moreover, we use Monte Carlo simulated CMB temperature maps to show the equivalence of this method with the 2-point temperature function (best known as the 2-Point Angular Correlation Function). We also investigate here the robustness of this new method under possible divisions of the original catalog-data in sub-catalogs. Finally, we show some applications of this new...

  6. A Differential Reflective Intensity Optical Fiber Angular Displacement Sensor.

    Science.gov (United States)

    Jia, Binghui; He, Lei; Yan, Guodong; Feng, Yong

    2016-09-16

    In this paper, a novel differential reflective intensity optical fiber angular displacement sensor was proposed. This sensor can directly measure the angular and axial linear displacement of a flat surface. The structure of the sensor probe is simple and its basic principle was first analyzed according to the intensity modulation mechanisms. Secondly, in order to trim the dark output voltage to zero, the photoelectric conversion circuit was developed to adjust the signals. Then, the sensor model including the photoelectric conversion circuit has been established, and the influence of design parameters on the sensor output characteristic has been simulated. Finally, the design parameters of the sensor structure were obtained based on the simulation results; and an experimental test system was built for the sensor calibration. Experimental results show that the linear angular range and the sensitivity of the sensor were 74.4 and 0.051 V/°, respectively. Its change rules confirm the operating principle of the sensor well.

  7. Transfer of optical orbital angular momentum to a bound electron

    Science.gov (United States)

    Schmiegelow, Christian T.; Schulz, Jonas; Kaufmann, Henning; Ruster, Thomas; Poschinger, Ulrich G.; Schmidt-Kaler, Ferdinand

    2016-10-01

    Photons can carry angular momentum, not only due to their spin, but also due to their spatial structure. This extra twist has been used, for example, to drive circular motion of microscopic particles in optical tweezers as well as to create vortices in quantum gases. Here we excite an atomic transition with a vortex laser beam and demonstrate the transfer of optical orbital angular momentum to the valence electron of a single trapped ion. We observe strongly modified selection rules showing that an atom can absorb two quanta of angular momentum from a single photon: one from the spin and another from the spatial structure of the beam. Furthermore, we show that parasitic ac-Stark shifts from off-resonant transitions are suppressed in the dark centre of vortex beams. These results show how light's spatial structure can determine the characteristics of light-matter interaction and pave the way for its application and observation in other systems.

  8. Nanoradian angular stabilization of x-ray optical components.

    Science.gov (United States)

    Stoupin, Stanislav; Lenkszus, Frank; Laird, Robert; Goetze, Kurt; Kim, Kwang-Je; Shvyd'ko, Yuri

    2010-05-01

    An x-ray free-electron laser oscillator (XFELO) has been recently proposed [K. Kim et al., Phys. Rev. Lett. 100, 244802 (2008)]. Angular orientation and position in space of Bragg mirrors of the XFELO optical cavity must be continuously adjusted to compensate for the instabilities and maximize the output intensity. An angular stability of about 10 nrad (rms) is required [K. Kim and Y. Shvyd'ko, Phys. Rev. ST Accel. Beams 12, 030703 (2009)]. To approach this goal, a feedback loop based on a null-detection principle was designed and used for stabilization of a high-energy-resolution x-ray monochromator (DeltaE/E approximately 4 x 10(-8), E=23.7 keV) and a high-heat-load monochromator. Angular stability of about 13 nrad (rms) has been demonstrated for x-ray optical elements of the monochromators.

  9. Nanoradian angular stabilization of x-ray optical components

    CERN Document Server

    Stoupin, Stanislav; Laird, Robert; Goetze, Kurt; Kim, Kwang-Je; Shvydko, Yuri

    2010-01-01

    An x-ray free electron laser oscillator (XFELO) has been recently proposed [K. Kim, Y. Shvyd'ko, and S. Reiche, Phys. Rev. Lett. 100, 244802 (2008)]. Angular orientation and position in space of Bragg mirrors of the XFELO optical cavity must be continuously adjusted to compensate instabilities and maximize the output intensity. An angular stability of about 10 nrad (rms) is required [K. Kim and Y. Shvyd'ko Phys. Rev. STAB 12, 030703 (2009)]. To approach this goal, a feedback loop based on a null-detection principle was designed and used for stabilization of a high energy resolution x-ray monochromator ($\\Delta E/E \\simeq 4 \\times 10^{-8}$, $E$ = 23.7 keV) and a high heat load monochromator. Angular stability of about 13 nrad (rms) has been demonstrated for x-ray optical elements of the monochromators.

  10. A Differential Reflective Intensity Optical Fiber Angular Displacement Sensor

    Science.gov (United States)

    Jia, Binghui; He, Lei; Yan, Guodong; Feng, Yong

    2016-01-01

    In this paper, a novel differential reflective intensity optical fiber angular displacement sensor was proposed. This sensor can directly measure the angular and axial linear displacement of a flat surface. The structure of the sensor probe is simple and its basic principle was first analyzed according to the intensity modulation mechanisms. Secondly, in order to trim the dark output voltage to zero, the photoelectric conversion circuit was developed to adjust the signals. Then, the sensor model including the photoelectric conversion circuit has been established, and the influence of design parameters on the sensor output characteristic has been simulated. Finally, the design parameters of the sensor structure were obtained based on the simulation results; and an experimental test system was built for the sensor calibration. Experimental results show that the linear angular range and the sensitivity of the sensor were 74.4 and 0.051 V/°, respectively. Its change rules confirm the operating principle of the sensor well. PMID:27649199

  11. The angular magnetothermoelectric power of a charge density wave system

    Science.gov (United States)

    Krstovska, D.; Choi, E. S.; Steven, E.; Brooks, J. S.

    2012-07-01

    The angular dependence of the magnetothermopower of a charge transfer organic salt α-(ET)2KHg(SCN)4 below (4 K) and above (9 K) the phase transition temperature, Tp = 8 K, and under fields of 15 T and 25 T, below and above the ‘kinkfield’, has been studied. We find that for a longitudinal thermoelectric measurement both an interlayer thermopower (the Seebeck effect), Szz, and a transverse thermopower (the Nernst effect), Syz, exist in all three different B-T phases (the CDW 0, CDW x and metallic states) with large amplitude. Both thermoelectric effects display a resonant-like behavior without a sign reversal at the angles corresponding to angular magnetoresistance oscillation minima and maxima in this compound. The resonant behavior is most evident in the CDW0 state, indicating a mechanism involving the Fermi surface nesting. Angular dependences reveal different behaviors of the thermopower and Nernst effect in the high magnetic field (CDWx) state.

  12. Angular anisotropy of the fusion-fission and quasifission fragments

    CERN Document Server

    Nasirov, A K; Utamuratov, R K; Fazio, G; Giardina, G; Hanappe, F; Mandaglio, G; Manganaro, M; Scheid, W

    2007-01-01

    The anisotropy in the angular distribution of the fusion-fission and quasifission fragments for the $^{16}$O+$^{238}$U, $^{19}$F+$^{208}$Pb and $^{32}$S+$^{208}$Pb reactions is studied by analyzing the angular momentum distributions of the dinuclear system and compound nucleus which are formed after capture and complete fusion, respectively. The orientation angles of axial symmetry axes of colliding nuclei to the beam direction are taken into account for the calculation of the variance of the projection of the total spin onto the fission axis. It is shown that the deviation of the experimental angular anisotropy from the statistical model picture is connected with the contribution of the quasifission fragments which is dominant in the $^{32}$S+$^{208}$Pb reaction. Enhancement of anisotropy at low energies in the $^{16}$O+$^{238}$U reaction is connected with quasifission of the dinuclear system having low temperature and effective moment of inertia.

  13. Conservation of orbital angular momentum in air core optical fibers

    CERN Document Server

    Gregg, P; Ramachandran, S

    2014-01-01

    Light's orbital angular momentum (OAM) is a conserved quantity in cylindrically symmetric media; however, it is easily destroyed by free-space turbulence or fiber bends, because anisotropic perturbations impart angular momentum. We observe the conservations of OAM even in the presence of strong bend perturbations, with fibers featuring air cores that appropriately sculpt the modal density of states. In analogy to the classical reasoning for the enhanced stability of spinning tops with increasing angular velocity, these states' lifetimes with OAM magnitude. Consequently, contrary to convention wisdom that ground states of systems are the most stable, OAM longevity in air-core fiber increases with mode order. Aided by conservation of this fundamental quantity, we demonstrate fiber propagation of 12 distinct higher-order OAM modes, of which 8 remain low-loss and >98% pure from near-degenerate coupling after km-length propagation. The first realization of long-lived higher-order OAM states, thus far posited to ex...

  14. Angular distributions for two-photon double ionization of lithium

    Science.gov (United States)

    Armstrong, G. S. J.; Colgan, J.

    2012-08-01

    We present angular distributions for two-photon double ionization of lithium at photon energies of 50 eV (λ = 25 nm) and 59 eV (λ = 21 nm). The results are obtained from full-dimensional solution of the two-active-electron time-dependent Schrödinger equation using the time-dependent close-coupling method. We investigate two different double ionization mechanisms. First, we consider direct double ionization of the Li ground state following the absorption of two photons. Secondly, we consider an initial photoexcitation of the 1s2s2p doubly excited state, followed by photoionization of the 2s and 2p electrons. We find significant differences between the angular distributions obtained for these two distinct processes. We also compare the characteristics of the angular distributions for Li with those of other two-electron atoms.

  15. Valley-contrasting orbital angular momentum in photonic valley crystals

    CERN Document Server

    Chen, Xiaodong; Dong, Jianwen

    2016-01-01

    Valley, as a degree of freedom, has been exploited to realize valley-selective Hall transport and circular dichroism in two-dimensional layered materials. On the other hand, orbital angular momentum of light with helical phase distribution has attracted great attention for its unprecedented opportunity to optical communicagtions, atom trapping, and even nontrivial topology engineering. Here, we reveal valley-contrasting orbital angular momentum in all-dielectric photonic valley crystals. Selective excitation of valley chiral bulk states is realized by sources carrying orbital angular momentum with proper chirality. Valley dependent edge states, predictable by nonzero valley Chern number, enable to suppress the inter-valley scattering along zigzag boundary, leading to broadband robust transmission in Z-shape bend without corner morphological optimization. Our work may open up a new door towards the discovery of novel quantum states and the manipulation of spin-orbit interaction of light in nanophotonics.

  16. Probing angular momentum coherence in a twin-atom interferometer

    CERN Document Server

    de Carvalho, Carlos R; Impens, François; Robert, J; Medina, Aline; Zappa, F; Faria, N V de Castro

    2014-01-01

    We propose to use a double longitudinal Stern-Gerlach atom interferometer in order to investigate quantitatively the angular momentum coherence of molecular fragments. Assuming that the dissociated molecule has a null total angular momentum, we investigate the propagation of the corresponding atomic fragments in the apparatus. We show that the envisioned interferometer enables one to distinguish unambiguously a spin-coherent from a spin-incoherent dissociation, as well as to estimate the purity of the angular momentum density matrix associated with the fragments. This setup, which may be seen as an atomic analogue of a twin-photon interferometer, can be used to investigate the suitability of molecule dissociation processes -- such as the metastable hydrogen atoms H($2^2 S$)-H($2^2 S$) dissociation - for coherent twin-atom optics.

  17. Fractional angular momentum in cold-atom systems.

    Science.gov (United States)

    Zhang, Yuhe; Sreejith, G J; Gemelke, N D; Jain, J K

    2014-10-17

    The quantum statistics of bosons or fermions are manifest through the even or odd relative angular momentum of a pair. We show theoretically that, under certain conditions, a pair of certain test particles immersed in a fractional quantum Hall state possesses, effectively, a fractional relative angular momentum, which can be interpreted in terms of fractional braid statistics. We propose that the fractionalization of the angular momentum can be detected directly through the measurement of the pair correlation function in rotating ultracold atomic systems in the fractional quantum Hall regime. Such a measurement will also provide direct evidence for the effective magnetic field resulting from Berry phases arising from attached vortices, and of excitations with a fractional particle number, analogous to the fractional charge of the electron fractional quantum Hall effect.

  18. On-chip noninterference angular momentum multiplexing of broadband light.

    Science.gov (United States)

    Ren, Haoran; Li, Xiangping; Zhang, Qiming; Gu, Min

    2016-05-13

    Angular momentum division has emerged as a physically orthogonal multiplexing method in high-capacity optical information technologies. However, the typical bulky elements used for information retrieval from the overall diffracted field, based on the interference method, impose a fundamental limit toward realizing on-chip multiplexing. We demonstrate noninterference angular momentum multiplexing by using a mode-sorting nanoring aperture with a chip-scale footprint as small as 4.2 micrometers by 4.2 micrometers, where nanoring slits exhibit a distinctive outcoupling efficiency on tightly confined plasmonic modes. The nonresonant mode-sorting sensitivity and scalability of our approach enable on-chip parallel multiplexing over a bandwidth of 150 nanometers in the visible wavelength range. The results offer the possibility of ultrahigh-capacity and miniaturized nanophotonic devices harnessing angular momentum division.

  19. Transfer of orbital angular momentum through sub-wavelength waveguides.

    Science.gov (United States)

    Wang, Yanqin; Ma, Xiaoliang; Pu, Mingbo; Li, Xiong; Huang, Cheng; Pan, Wenbo; Zhao, Bo; Cui, Jianhua; Luo, Xiangang

    2015-02-01

    Data capacity of optical communication is achieving its limit owing to the non-linear effect of optical fiber. As an effective alternative, light carrying orbital angular momentum can greatly increase the capacity for its unprecedented degree of freedom. We demonstrate the propagation of orbital angular momentum with topological charge of 1 and 2 in plasmonic circular waveguide with sub-wavelength diameter with little propagation loss of 2.73 dB/μm, which has never been observed in optical fibers with sub-wavelength diameter. We also confirm that lights carrying orbital angular momentum can be maintained in sharp bended sub-wavelength waveguide. This plasmonic waveguide may serve as a key component in on-chip systems involving OAM.

  20. Fractional Angular Momentum in Cold-Atom Systems

    Science.gov (United States)

    Zhang, Yuhe; Sreejith, G. J.; Gemelke, N. D.; Jain, J. K.

    2014-10-01

    The quantum statistics of bosons or fermions are manifest through the even or odd relative angular momentum of a pair. We show theoretically that, under certain conditions, a pair of certain test particles immersed in a fractional quantum Hall state possesses, effectively, a fractional relative angular momentum, which can be interpreted in terms of fractional braid statistics. We propose that the fractionalization of the angular momentum can be detected directly through the measurement of the pair correlation function in rotating ultracold atomic systems in the fractional quantum Hall regime. Such a measurement will also provide direct evidence for the effective magnetic field resulting from Berry phases arising from attached vortices, and of excitations with a fractional particle number, analogous to the fractional charge of the electron fractional quantum Hall effect.

  1. Orbital angular momentum of scalar field generated by gravitational scatterings

    CERN Document Server

    Nishikawa, Ryusuke; Masuda, Atsuki; Nambu, Yasusada; Ishihara, Hideki

    2016-01-01

    It has been expected that astronomical observations to detect the orbital angular momenta of electromagnetic waves may give us a new insight into astrophysics. Previous works pointed out the possibility that a rotating black hole can produce orbital angular momenta of electromagnetic waves through gravitational scattering, and the spin parameter of the black hole can be measured by observing them. However, the mechanism how the orbital angular momentum of the electromagnetic wave is generated by the gravitational scattering has not been clarified sufficiently. In this paper, in order to understand it from a point of view of gravitational lensing effects, we consider an emitter which radiates a spherical wave of the real massless scalar field and study the deformation of the scalar wave by the gravitational scattering due to a black hole by invoking the geometrical optics approximation. We show that the frame dragging caused by the rotating black hole is not a necessary condition for generating the orbital ang...

  2. CB receptor ligands from plants.

    Science.gov (United States)

    Woelkart, Karin; Salo-Ahen, Outi M H; Bauer, Rudolf

    2008-01-01

    Advances in understanding the physiology and pharmacology of the endogenous cannabinoid system have potentiated the interest of cannabinoid receptors as potential therapeutic targets. Cannabinoids have been shown to modulate a variety of immune cell functions and have therapeutic implications on central nervous system (CNS) inflammation, chronic inflammatory conditions such as arthritis, and may be therapeutically useful in treating autoimmune conditions such as multiple sclerosis. Many of these drug effects occur through cannabinoid receptor signalling mechanisms and the modulation of cytokines and other gene products. Further, endocannabinoids have been found to have many physiological and patho-physiological functions, including mood alteration and analgesia, control of energy balance, gut motility, motor and co-ordination activities, as well as alleviation of neurological, psychiatric and eating disorders. Plants offer a wide range of chemical diversity and have been a growing domain in the search for effective cannabinoid ligands. Cannabis sativa L. with the known plant cannabinoid, Delta(9-)tetrahydrocannabinol (THC) and Echinacea species with the cannabinoid (CB) receptor-binding lipophilic alkamides are the best known herbal cannabimimetics. This review focuses on the state of the art in CB ligands from plants, as well their possible therapeutic and immunomodulatory effects.

  3. Ligand photo-isomerization triggers conformational changes in iGluR2 ligand binding domain.

    Directory of Open Access Journals (Sweden)

    Tino Wolter

    Full Text Available Neurological glutamate receptors bind a variety of artificial ligands, both agonistic and antagonistic, in addition to glutamate. Studying their small molecule binding properties increases our understanding of the central nervous system and a variety of associated pathologies. The large, oligomeric multidomain membrane protein contains a large and flexible ligand binding domains which undergoes large conformational changes upon binding different ligands. A recent application of glutamate receptors is their activation or inhibition via photo-switchable ligands, making them key systems in the emerging field of optochemical genetics. In this work, we present a theoretical study on the binding mode and complex stability of a novel photo-switchable ligand, ATA-3, which reversibly binds to glutamate receptors ligand binding domains (LBDs. We propose two possible binding modes for this ligand based on flexible ligand docking calculations and show one of them to be analogues to the binding mode of a similar ligand, 2-BnTetAMPA. In long MD simulations, it was observed that transitions between both binding poses involve breaking and reforming the T686-E402 protein hydrogen bond. Simulating the ligand photo-isomerization process shows that the two possible configurations of the ligand azo-group have markedly different complex stabilities and equilibrium binding modes. A strong but slow protein response is observed after ligand configuration changes. This provides a microscopic foundation for the observed difference in ligand activity upon light-switching.

  4. Measurement of protein-ligand complex formation.

    Science.gov (United States)

    Lowe, Peter N; Vaughan, Cara K; Daviter, Tina

    2013-01-01

    Experimental approaches to detect, measure, and quantify protein-ligand binding, along with their theoretical bases, are described. A range of methods for detection of protein-ligand interactions is summarized. Specific protocols are provided for a nonequilibrium procedure pull-down assay, for an equilibrium direct binding method and its modification into a competition-based measurement and for steady-state measurements based on the effects of ligands on enzyme catalysis.

  5. Zebra tape identification for the instantaneous angular speed computation and angular resampling of motorbike valve train measurements

    Science.gov (United States)

    Rivola, Alessandro; Troncossi, Marco

    2014-02-01

    An experimental test campaign was performed on the valve train of a racing motorbike engine in order to get insight into the dynamic of the system. In particular the valve motion was acquired in cold test conditions by means of a laser vibrometer able to acquire displacement and velocity signals. The valve time-dependent measurements needed to be referred to the camshaft angular position in order to analyse the data in the angular domain, as usually done for rotating machines. To this purpose the camshaft was fitted with a zebra tape whose dark and light stripes were tracked by means of an optical probe. Unfortunately, both manufacturing and mounting imperfections of the employed zebra tape, resulting in stripes with slightly different widths, precluded the possibility to directly obtain the correct relationship between camshaft angular position and time. In order to overcome this problem, the identification of the zebra tape was performed by means of the original and practical procedure that is the focus of the present paper. The method consists of three main steps: namely, an ad-hoc test corresponding to special operating conditions, the computation of the instantaneous angular speed, and the final association of the stripes with the corresponding shaft angular position. The results reported in the paper demonstrate the suitability of the simple procedure for the zebra tape identification performed with the final purpose to implement a computed order tracking technique for the data analysis.

  6. The angular momentum of condensations within elephant trunks

    CERN Document Server

    Lora, V; Esquivel, A

    2009-01-01

    The radiation from newly born stars photoevaporates their parental neutral cloud, leading to the formation of dense clumps that will eventually form stars. We present 3D simulations of the interaction of a neutral cloud with an external ionising radiation field, and compute the angular momenta of these collapsing clumps. The angular momenta of these collapsing clumps show that they have preferential orient mostly perpendicular to the direction of the incident ionising photon field. Therefore, the axes of the jet systems that will be eventually ejected (from the star + accretion disk systems that will form) will be oriented approximately perpendicular to the direction to the photoionising source.

  7. Efficient Sorting of Free Electron Orbital Angular Momentum

    CERN Document Server

    McMorran, Benjamin J; Lavery, Martin P J

    2016-01-01

    We propose a method for sorting electrons by orbital angular momentum (OAM). Several methods now exist to prepare electron wavefunctions in OAM states, but no technique has been developed for efficient, parallel measurement of pure and mixed electron OAM states. The proposed technique draws inspiration from the recent demonstration of the sorting of OAM through modal transformation. We show that the same transformation can be performed with electrostatic electron optical elements. Specifically, we show that a charged needle and an array of electrodes perform the transformation and phase correction necessary to sort orbital angular momentum states. This device may enable the analysis of the spatial mode distribution of inelastically scattered electrons.

  8. Continuous Variable Entanglement and Squeezing of Orbital Angular Momentum States

    DEFF Research Database (Denmark)

    Lassen, Mikael Østergaard; Leuchs, Gerd; Andersen, Ulrik Lund

    2009-01-01

    We report the first experimental characterization of the first-order continuous variable orbital angular momentum states. Using a spatially nondegenerate optical parametric oscillator (OPO) we produce quadrature entanglement between the two first-order Laguerre-Gauss modes. The family of orbital...... angular momentum modes is mapped on an orbital Poincaré sphere, where the mode's position on the sphere is spanned by the three orbital parameters. Using a nondegenerate OPO we produce squeezing of these parameters, and as an illustration, we reconstruct the “cigar-shaped” uncertainty volume...

  9. Angular Sensitivity of Gated Micro-Channel Plate Framing Cameras

    Energy Technology Data Exchange (ETDEWEB)

    Landen, O L; Lobban, A; Tutt, T; Bell, P M; Costa, R; Ze, F

    2000-07-24

    Gated, microchannel-plate-based (MCP) framing cameras have been deployed worldwide for 0.2 - 9 keV x-ray imaging and spectroscopy of transient plasma phenomena. For a variety of spectroscopic and imaging applications, the angular sensitivity of MCPs must be known for correctly interpreting the data. We present systematic measurements of angular sensitivity at discrete relevant photon energies and arbitrary MCP gain. The results can been accurately predicted by using a simple 2D approximation to the 3D MCP geometry and by averaging over all possible photon ray paths.

  10. Alignment of angular velocity sensors for a vestibular prosthesis

    Directory of Open Access Journals (Sweden)

    DiGiovanna Jack

    2012-02-01

    Full Text Available Abstract Vestibular prosthetics transmit angular velocities to the nervous system via electrical stimulation. Head-fixed gyroscopes measure angular motion, but the gyroscope coordinate system will not be coincident with the sensory organs the prosthetic replaces. Here we show a simple calibration method to align gyroscope measurements with the anatomical coordinate system. We benchmarked the method with simulated movements and obtain proof-of-concept with one healthy subject. The method was robust to misalignment, required little data, and minimal processing.

  11. Energy and angular momentum of dilaton black holes

    Directory of Open Access Journals (Sweden)

    Marcelo Samuel Berman

    2008-01-01

    Full Text Available Dando seguimiento a un art culo previo, revisamos los resultados para la energ a y momento angular de un hoyo negro de Kerr-Newman, y extendemos el c alculo para el caso de un dilaton en rotaci on, obtenido a partir del modelo de Gar nkle et al. (1991, 1992. Mostramos que hay, en lo que se re ere solamente a la energ a y momento angular, una interacci on entre los campos, de forma que, el gravitacional y el electromagn etico pueden ser ocultados por la intensidad del campo escalar.

  12. Angular velocity response of nanoparticles dispersed in liquid crystal

    Science.gov (United States)

    Huang, Pin-Chun; Shih, Wen-Pin

    2013-06-01

    A hybrid material of nanoparticles dispersed in liquid crystal changed capacitance after spinning beyond threshold angular velocity. Once the centrifugal force of nanoparticles overcomes the attractive force between liquid crystals, the nanoparticles begin to move. The order of highly viscous liquid crystals is disturbed by the nanoparticles' penetrative movement, and the dielectric constant of the liquid crystal cell changes as a result. We found that the angular velocity response of nanoparticles dispersed in liquid crystal with higher working temperature and nanoparticles' density provided higher sensitivity. The obtained results are important for the continuous improvement of liquid-crystal-based inertial sensors or nano-viscometers.

  13. Effect of Orbital Angular Momentum on Nondiffracting Ultrashort Optical Pulses.

    Science.gov (United States)

    Ornigotti, Marco; Conti, Claudio; Szameit, Alexander

    2015-09-01

    We introduce a new class of nondiffracting optical pulses possessing orbital angular momentum. By generalizing the X-wave solution of the Maxwell equation, we discover the coupling between angular momentum and the temporal degrees of freedom of ultrashort pulses. The spatial twist of propagation invariant light pulse turns out to be directly related to the number of optical cycles. Our results may trigger the development of novel multilevel classical and quantum transmission channels free of dispersion and diffraction. They may also find application in the manipulation of nanostructured objects by ultrashort pulses and for novel approaches to the spatiotemporal measurements in ultrafast photonics.

  14. Four Cases of Angular Cheilitis in Orthodontic Patients

    Directory of Open Access Journals (Sweden)

    P Kafaie

    2006-07-01

    Full Text Available Contact dermatitis is an inflammatory reaction of the skin and mucosa to either external or internal factors. It can be divided to two forms of irritant contact dermatitis and allergic contact dermatitis. Nickel is one of the most common materials that causes allergic contact dermatitis and is widely used in orthodontic appliances. The inflammatory reaction to this metal in orthodontics is usually stomatitis and angular cheilitis is very rare. We report 4 cases of angular cheilitis in orthodontic patients and discuss about their causes and treatments.

  15. Investigation of the dynamics of angular motion and construction of algorithms for controlling the angular momentum of spacecraft using a magnetic attitude control system

    Science.gov (United States)

    Egorov, Yu. G.; Kulkov, V. M.; Terentyev, V. V.; Firsyuk, S. O.; Shemyakov, A. O.

    2016-11-01

    The problem of controlling the angular momentum of spacecraft using magnetic attitude control systems interacting with the Earth's magnetic field is considered. A mathematical model for the angular motion dynamics of a spacecraft has been constructed. An approach to determining the parameters of the control law for a spacecraft attitude control and stabilization system that ensures angular momentum dissipation is proposed.

  16. Cosmology Large Angular Scale Surveyor (CLASS) Focal Plane Development

    Science.gov (United States)

    Chuss, D. T.; Ali, A.; Amiri, M.; Appel, J.; Bennett, C. L.; Colazo, F.; Denis, K. L.; Dünner, R.; Essinger-Hileman, T.; Eimer, J.; Fluxa, P.; Gothe, D.; Halpern, M.; Harrington, K.; Hilton, G.; Hinshaw, G.; Hubmayr, J.; Iuliano, J.; Marriage, T. A.; Miller, N.; Moseley, S. H.; Mumby, G.; Petroff, M.; Reintsema, C.; Rostem, K.; U-Yen, K.; Watts, D.; Wagner, E.; Wollack, E. J.; Xu, Z.; Zeng, L.

    2016-08-01

    The Cosmology Large Angular Scale Surveyor (CLASS) will measure the polarization of the Cosmic Microwave Background to search for and characterize the polarized signature of inflation. CLASS will operate from the Atacama Desert and observe ˜ 70 % of the sky. A variable-delay polarization modulator provides modulation of the polarization at ˜ 10 Hz to suppress the 1/ f noise of the atmosphere and enable the measurement of the large angular scale polarization modes. The measurement of the inflationary signal across angular scales that spans both the recombination and reionization features allows a test of the predicted shape of the polarized angular power spectra in addition to a measurement of the energy scale of inflation. CLASS is an array of telescopes covering frequencies of 38, 93, 148, and 217 GHz. These frequencies straddle the foreground minimum and thus allow the extraction of foregrounds from the primordial signal. Each focal plane contains feedhorn-coupled transition-edge sensors that simultaneously detect two orthogonal linear polarizations. The use of single-crystal silicon as the dielectric for the on-chip transmission lines enables both high efficiency and uniformity in fabrication. Integrated band definition has been implemented that both controls the bandpass of the single-mode transmission on the chip and prevents stray light from coupling to the detectors.

  17. The Angular Diameter and Fundamental Parameters of Sirius A

    CERN Document Server

    Davis, J; North, J R; Robertson, J G; Tango, W J; Tuthill, P G

    2010-01-01

    The Sydney University Stellar Interferometer (SUSI) has been used to make a new determination of the angular diameter of Sirius A. The observations were made at an effective wavelength of 694.1 nm and the new value for the limb-darkened angular diameter is 6.048 +/- 0.040mas (+/-0.66%). This new result is compared with previous measurements and is found to be in excellent agreement with a conventionally calibrated measurement made with the European Southern Observatory's Very Large Telescope Interferometer (VLTI) at 2.176 microns (but not with a second globally calibrated VLTI measurement). A weighted mean of the SUSI and first VLTI results gives the limb-darkened angular diameter of Sirius A as 6.041 +/- 0.017mas (+/-0.28%). Combination with the Hipparcos parallax gives the radius equal to 1.713 +/- 0.009R_sun. The bolometric flux has been determined from published photometry and spectrophotometry and, combined with the angular diameter, yields the emergent flux at the stellar surface equal to (5.32+/- 0.14)...

  18. Drell-Yan lepton angular distribution at small transverse momentum

    NARCIS (Netherlands)

    Boer, Daniel; Vogelsang, Werner

    2006-01-01

    We investigate the dependence of the Drell-Yan cross section on lepton polar and azimuthal angles, as generated by the lowest-order QCD annihilation and Compton processes. We focus, in particular, on the azimuthal-angular distributions, which are of the form cos phi and cos2 phi. At small transverse

  19. Demonstrating the Direction of Angular Velocity in Circular Motion

    Science.gov (United States)

    Demircioglu, Salih; Yurumezoglu, Kemal; Isik, Hakan

    2015-01-01

    Rotational motion is ubiquitous in nature, from astronomical systems to household devices in everyday life to elementary models of atoms. Unlike the tangential velocity vector that represents the instantaneous linear velocity (magnitude and direction), an angular velocity vector is conceptually more challenging for students to grasp. In physics…

  20. Data visualization with D3 and AngularJS

    CERN Document Server

    Körner, Christoph

    2015-01-01

    If you are a web developer with experience in AngularJS and want to implement interactive visualizations using D3.js, this book is for you. Knowledge of SVG or D3.js will give you an edge to get the most out of this book.

  1. Cosmology Large Angular Scale Surveyor (CLASS) Focal Plane Development

    Science.gov (United States)

    Chuss, D. T.; Ali, A.; Amiri, M.; Appel, J.; Bennett, C. L.; Colazo, F.; Denis, K. L.; Dunner, R.; Essinger-Hileman, T.; Eimer, J.; Fluxa, P.; Gothe, D.; Halpern, M.; Harrington, K.; Hilton, G.; Hinshaw, G.; Hubmayr, J.; Iuliano, J.; Marriage, T. A.; Miller, N.; Moseley, S. H.; Mumby, G.; Petroff, M.; Reintsema, C.; Rostem, K.; U-yen, K.; Watts, D.; Wagner, E.; Wollack, E. J.; Xu, Z.; Zeng, L.

    2015-01-01

    The Cosmology Large Angular Scale Surveyor (CLASS) will measure the polarization of the Cosmic Microwave Background to search for and characterize the polarized signature of inflation. CLASS will operate from the Atacama Desert and observe approx.70% of the sky. A variable-delay polarization modulator provides modulation of the polarization at approx.10Hz to suppress the 1/f noise of the atmosphere and enable the measurement of the large angular scale polarization modes. The measurement of the inflationary signal across angular scales that spans both the recombination and reionization features allows a test of the predicted shape of the polarized angular power spectra in addition to a measurement of the energy scale of inflation. CLASS is an array of telescopes covering frequencies of 38, 93, 148, and 217 GHz. These frequencies straddle the foreground minimum and thus allow the extraction of foregrounds from the primordial signal. Each focal plane contains feedhorn-coupled transition-edge sensors that simultaneously detect two orthogonal linear polarizations. The use of single-crystal silicon as the dielectric for the on-chip transmission lines enables both high efficiency and uniformity in fabrication. Integrated band definition has been implemented that both controls the bandpass of the single-mode transmission on the chip and prevents stray light from coupling to the detectors.

  2. Low Angular Momentum in Clumpy, Turbulent Disk Galaxies

    Science.gov (United States)

    Obreschkow, Danail; Glazebrook, Karl; Bassett, Robert; Fisher, David B.; Abraham, Roberto G.; Wisnioski, Emily; Green, Andrew W.; McGregor, Peter J.; Damjanov, Ivana; Popping, Attila; Jørgensen, Inger

    2015-12-01

    We measure the stellar specific angular momentum {j}s={J}s/{M}s in four nearby (z ≈ 0.1) disk galaxies that have stellar masses {M}s near the break {M}s* of the galaxy mass function but look like typical star-forming disks at z ≈ 2 in terms of their low stability (Q ≈ 1), clumpiness, high ionized gas dispersion (40-50 {km} {{{s}}}-1), high molecular gas fraction (20%-30%), and rapid star formation (˜ 20{M}⊙ {{yr}}-1). Combining high-resolution (Keck-OSIRIS) and large-radius (Gemini-GMOS) spectroscopic maps, only available at low z, we discover that these targets have ˜ 3 times less stellar angular momentum than typical local spiral galaxies of equal stellar mass and bulge fraction. Theoretical considerations show that this deficiency in angular momentum is the main cause of their low stability, while the high gas fraction plays a complementary role. Interestingly, the low {j}s values of our targets are similar to those expected in the {M}s* population at higher z from the approximate theoretical scaling {j}s\\propto {(1+z)}-1/2 at fixed {M}s. This suggests that a change in angular momentum, driven by cosmic expansion, is the main cause for the remarkable difference between clumpy {M}s* disks at high z (which likely evolve into early-type galaxies) and mass-matched local spirals.

  3. Remarks on the Total Angular Momentum in General Relativity

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xiao

    2003-01-01

    We verify that the total angular momentum 3-vector defined by the author [X. Zhang, Commun. Math.Phys. 206 (1999) 137] is equal to (0, 0, ma) forany time slice in both the Kerr and the Kerr-Newman spacetimes.

  4. Angular correlation of annihilation photons in ice single crystals

    DEFF Research Database (Denmark)

    Mogensen, O. E.; Kvajic, G.; Eldrup, Morten Mostgaard

    1971-01-01

    Linear-slit angular-correlation curves were obtained at - 148 °C for the [0001], [10¯10], and [11¯20] directions in single crystals of ice. Besides the narrow central peak, pronounced narrow side peaks were also observed. They occurred at angles θ=2πℏgz/mc, where gz is the projection of reciproca...

  5. Investigation of an angular spectrum approach for pulsed ultrasound fields

    DEFF Research Database (Denmark)

    Du, Yigang; Jensen, Henrik; Jensen, Jørgen Arendt

    2013-01-01

    An Angular Spectrum Approach (ASA)is formulated and employed to simulate linear pulsed ultra sound fields for high bandwidth signals. Ageometrically focused piston transducer is used as the acoustic source. Signals are cross-correlated to findthe true sound speed during the measurement to make th...

  6. Influence of the angular momentum on nuclear fission

    Energy Technology Data Exchange (ETDEWEB)

    Tanikawa, Masashi [Tokyo Univ. (Japan). Faculty of Science

    1996-03-01

    The effects of the angular momentum on the mechanism of nuclear fission are studied about the reaction systems of compound nucleus of {sup 210}P and {sup 239}Np by the time-of-flight (TOF) method. The reaction systems in this work are {sup 209}Bi+P, {sup 206}Pb+{alpha}, {sup 206}Po+{alpha}, {sup 198}Pt+{sup 12}C, {sup 238}U+P and {sup 232}Th+{sup 7}Li. Target was prepared by vacuum evaporating of each about 100 {mu}g/cm{sup 2} of {sup 209}Bi, {sup 206}Pb and {sup 198}Pt on 10 {mu}g/cm{sup 2} of carbon film. On compound nucleus {sup 210}Po, {sup 210}Po fissions at Ex=45McV but it fissions after 1 or 2 neutrons emission at higher excited energy (Ex=57 MeV). TKE shows almost the same values except higher value of {sup 209}Bi+P. The decreasing tendency of width of TKE distribution with increasing the angular momentum is found at the first time in this work. The effect of the angular momentum on the fission is small in the case of low angular momentum. On the compound nucleus {sup 239}Np, the effects are shown at the asymmetric fission part of the mass distribution. (S.Y.)

  7. Spin-Orbit Coupling and the Conservation of Angular Momentum

    Science.gov (United States)

    Hnizdo, V.

    2012-01-01

    In nonrelativistic quantum mechanics, the total (i.e. orbital plus spin) angular momentum of a charged particle with spin that moves in a Coulomb plus spin-orbit-coupling potential is conserved. In a classical nonrelativistic treatment of this problem, in which the Lagrange equations determine the orbital motion and the Thomas equation yields the…

  8. A Historical Discussion of Angular Momentum and its Euler Equation

    CERN Document Server

    Sparavigna, Amelia Carolina

    2015-01-01

    We propose a discussion of angular momentum and its Euler equation, with the aim of giving a short outline of their history. This outline can be useful for teaching purposes too, to amend some problems that students can have in learning this important physical quantity.

  9. Alignment of gold nanorods by angular photothermal depletion

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Adam B.; Chow, Timothy T. Y.; Chon, James W. M., E-mail: jchon@swin.edu.au [Centre for Micro-Photonics, Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, P.O. Box 218, Hawthorn, 3122 VIC (Australia)

    2014-02-24

    In this paper, we demonstrate that a high degree of alignment can be imposed upon randomly oriented gold nanorod films by angular photothermal depletion with linearly polarized laser irradiation. The photothermal reshaping of gold nanorods is observed to follow quadratic melting model rather than the threshold melting model, which distorts the angular and spectral hole created on 2D distribution map of nanorods to be an open crater shape. We have accounted these observations to the alignment procedures and demonstrated good agreement between experiment and simulations. The use of multiple laser depletion wavelengths allowed alignment criteria over a large range of aspect ratios, achieving 80% of the rods in the target angular range. We extend the technique to demonstrate post-alignment in a multilayer of randomly oriented gold nanorod films, with arbitrary control of alignment shown across the layers. Photothermal angular depletion alignment of gold nanorods is a simple, promising post-alignment method for creating future 3D or multilayer plasmonic nanorod based devices and structures.

  10. Obtaining the Electron Angular Momentum Coupling Spectroscopic Terms, jj

    Science.gov (United States)

    Orofino, Hugo; Faria, Roberto B.

    2010-01-01

    A systematic procedure is developed to obtain the electron angular momentum coupling (jj) spectroscopic terms, which is based on building microstates in which each individual electron is placed in a different m[subscript j] "orbital". This approach is similar to that used to obtain the spectroscopic terms under the Russell-Saunders (LS) coupling…

  11. Angular Momentum of Supersymmetric Non-isotropic Traps

    Institute of Scientific and Technical Information of China (English)

    XU Qiang

    2001-01-01

    A simple way to explain quantum behavior of supersymmetric non-isotropic traps is proposed in the framework of sermiunitary formulation of supersymmetric quantum mechanics. Using semiunitary formulation we can simultaneously supersymmetrize the complete set of observables, especially including angular moment.

  12. Optical angular momentum conversion in a nanoslit: reply

    NARCIS (Netherlands)

    Chimento, P.F.; Alkemade, P.F.A.; T Hooft, G.W.; Eliel, E.R.

    2013-01-01

    We respond to a Comment on our Letter [Opt. Lett. 37, 4946 (2012)], in which we reported on the spin-to-orbital optical angular momentum conversion of a circular nanoslit in a thin metal layer. We claimed, in an unfortunately worded sentence, that the conversion efficiency was independent of the sli

  13. Generation of the Stigmatic Beam with Orbital Angular Momentum

    Institute of Scientific and Technical Information of China (English)

    高春清; 魏光辉; Horst WEBER

    2001-01-01

    The stigmatic beam with orbital angular momentum is generated by transforming the Hermite-Gaussian beamof a diode-pumped Nd:YAG laser through a rotated cylindrical optical system. Behind the transformation optics,the output beam has an intensity distribution of ring shape and a twist phase. The beam transformation istheoretically calculated and the result has been confirmed in the experiments.

  14. The operator method for angular momentum and SU3

    NARCIS (Netherlands)

    Eekelen, H.A.M. van; Ruijgrok, Th.W.

    1966-01-01

    It is well known how Schwinger's1) operator method can be used to construct all representations of the angular momentum operators. We give a brief account of this method and show that it is very convenient for a short derivation of the general Clebsch-Gordan coefficients. The method is then applied

  15. Energy and linear and angular momenta in simple electromagnetic systems

    CERN Document Server

    Mansuripur, Masud

    2015-01-01

    We present examples of simple electromagnetic systems in which energy, linear momentum, and angular momentum exhibit interesting behavior. The systems are sufficiently simple to allow exact solutions of Maxwell's equations in conjunction with the electrodynamic laws of force, torque, energy, and momentum. In all the cases examined, conservation of energy and momentum is confirmed.

  16. Long-time tails in angular momentum correlations

    NARCIS (Netherlands)

    Lowe, C.P.; Frenkel, D.; Masters, A.J.

    1995-01-01

    We compare computer simulation results for the angular velocity autocorrelation function (AVACF) of a colloidal particle with theoretical predictions. We consider both spherical and nonspherical particles in two and three dimensions. The theoretical prediction for the long-time decay of the AVACF in

  17. Estimating Discrete Power Angular Spectra in Multiprobe OTA Setups

    DEFF Research Database (Denmark)

    Fan, Wei; Nielsen, Jesper Ødum; Pedersen, Gert Frølund

    2014-01-01

    The letter discusses over-the-air (OTA) testing for multiple-input–multiple-output (MIMO) capable terminals with emphasis on estimating discrete power angular spectrum modeled at the receiver (Rx) side in the test zone. Two techniques based on a uniform circular array (UCA) are proposed to obtain...

  18. Angular cheilitis: a case for the oral physician?

    Science.gov (United States)

    Williams, M

    1995-03-01

    It has been suggested that in the future the role of the dental practitioner increasingly will be that of the oral physician. This case report describes the difficulties encountered by a general dental practitioner while investigating and treating a patient with angular cheilitis.

  19. Exact angular momentum projection based on cranked HFB solution

    Energy Technology Data Exchange (ETDEWEB)

    Enami, Kenichi; Tanabe, Kosai; Yosinaga, Naotaka [Saitama Univ., Urawa (Japan). Dept. of Physics

    1998-03-01

    Exact angular momentum projection of cranked HFB solutions is carried out. It is reconfirmed from this calculation that cranked HFB solutions reproduce the intrinsic structure of deformed nucleus. The result also indicates that the energy correction from projection is important for further investigation of nuclear structure. (author)

  20. Angular momentum projection of tilted axis rotating states

    Energy Technology Data Exchange (ETDEWEB)

    Oi, M.; Onishi, N.; Tajima, N. [Tokyo Univ. (Japan); Horibata, T.

    1998-03-01

    We applied an exact angular momentum projection to three dimensional cranked HFB (3d-CHFB) states. Tilted axis rotating states (TAR) and principal axis rotating states (PAR) are compared. It is shown that TAR is more adequate than PAR for description of the back bending phenomena driven by tilted rotation or wobbling motion. (author)

  1. Simplified Generation of High-Angular-Momentum Light Beams

    Science.gov (United States)

    Savchenkov, Anatoliy; Maleki, Lute; Matsko, Andrey; Strekalov, Dmitry; Grudinin, Ivan

    2007-01-01

    A simplified method of generating a beam of light having a relatively high value of angular momentum (see figure) involves the use of a compact apparatus consisting mainly of a laser, a whispering- gallery-mode (WGM) resonator, and optical fibers. The method also can be used to generate a Bessel beam. ( Bessel beam denotes a member of a class of non-diffracting beams, so named because their amplitudes are proportional to Bessel functions of the radii from their central axes. High-order Bessel beams can have high values of angular momentum.) High-angular-momentum light beams are used in some applications in biology and nanotechnology, wherein they are known for their ability to apply torque to make microscopic objects rotate. High-angular-momentum light beams could also be used to increase bandwidths of fiber-optic communication systems. The present simplified method of generating a high-angular-momentum light beam was conceived as an alternative to prior such methods, which are complicated and require optical setups that include, variously, holograms, modulating Fabry-Perot cavities, or special microstructures. The present simplified method exploits a combination of the complex structure of the electromagnetic field inside a WGM resonator, total internal reflection in the WGM resonator, and the electromagnetic modes supported by an optical fiber. The optical fiber used to extract light from the WGM resonator is made of fused quartz. The output end of this fiber is polished flat and perpendicular to the fiber axis. The input end of this fiber is cut on a slant and placed very close to the WGM resonator at an appropriate position and orientation. To excite the resonant whispering- gallery modes, light is introduced into the WGM resonator via another optical fiber that is part of a pigtailed fiber-optic coupler. Light extracted from the WGM resonator is transformed into a high-angular- momentum beam inside the extraction optical fiber and this beam is emitted from the

  2. Power calculation of linear and angular incremental encoders

    Science.gov (United States)

    Prokofev, Aleksandr V.; Timofeev, Aleksandr N.; Mednikov, Sergey V.; Sycheva, Elena A.

    2016-04-01

    Automation technology is constantly expanding its role in improving the efficiency of manufacturing and testing processes in all branches of industry. More than ever before, the mechanical movements of linear slides, rotary tables, robot arms, actuators, etc. are numerically controlled. Linear and angular incremental photoelectric encoders measure mechanical motion and transmit the measured values back to the control unit. The capabilities of these systems are undergoing continual development in terms of their resolution, accuracy and reliability, their measuring ranges, and maximum speeds. This article discusses the method of power calculation of linear and angular incremental photoelectric encoders, to find the optimum parameters for its components, such as light emitters, photo-detectors, linear and angular scales, optical components etc. It analyzes methods and devices that permit high resolutions in the order of 0.001 mm or 0.001°, as well as large measuring lengths of over 100 mm. In linear and angular incremental photoelectric encoders optical beam is usually formulated by a condenser lens passes through the measuring unit changes its value depending on the movement of a scanning head or measuring raster. Past light beam is converting into an electrical signal by the photo-detecter's block for processing in the electrical block. Therefore, for calculating the energy source is a value of the desired value of the optical signal at the input of the photo-detecter's block, which reliably recorded and processed in the electronic unit of linear and angular incremental optoelectronic encoders. Automation technology is constantly expanding its role in improving the efficiency of manufacturing and testing processes in all branches of industry. More than ever before, the mechanical movements of linear slides, rotary tables, robot arms, actuators, etc. are numerically controlled. Linear and angular incremental photoelectric encoders measure mechanical motion and

  3. Rhodium olefin complexes of diiminate type ligands

    NARCIS (Netherlands)

    Willems, Sander Theodorus Hermanus

    2003-01-01

    The mono-anionic beta-diiminate ligand (ArNC(CH3)CHC(CH3)NAr) on several previous occasions proved useful in stabilising low coordination numbers for both early and late transition metals. In this thesis the reactivity of the rhodium olefin complexes of one of these beta-diiminate ligands (Ar = 2,6-

  4. Ligand sphere conversions in terminal carbide complexes

    DEFF Research Database (Denmark)

    Morsing, Thorbjørn Juul; Reinholdt, Anders; Sauer, Stephan P. A.

    2016-01-01

    Metathesis is introduced as a preparative route to terminal carbide complexes. The chloride ligands of the terminal carbide complex [RuC(Cl)2(PCy3)2] (RuC) can be exchanged, paving the way for a systematic variation of the ligand sphere. A series of substituted complexes, including the first exam...

  5. Flexible Ligand Docking Using Evolutionary Algorithms

    DEFF Research Database (Denmark)

    Thomsen, Rene

    2003-01-01

    The docking of ligands to proteins can be formulated as a computational problem where the task is to find the most favorable energetic conformation among the large space of possible protein–ligand complexes. Stochastic search methods such as evolutionary algorithms (EAs) can be used to sample large...

  6. The role of angular momentum conservation law in statistical mechanics

    Directory of Open Access Journals (Sweden)

    I.M. Dubrovskii

    2008-12-01

    Full Text Available Within the limits of Khinchin ideas [A.Y. Khinchin, Mathematical Foundation of Statistical Mechanics. NY, Ed. Dover, 1949] the importance of momentum and angular momentum conservation laws was analyzed for two cases: for uniform magnetic field and when magnetic field is absent. The law of momentum conservation does not change the density of probability distribution in both cases, just as it is assumed in the conventional theory. It is shown that in systems where the kinetic energy depends only on particle momenta canonically conjugated with Cartesian coordinates being their diagonal quadric form,the angular momentum conservation law changes the density of distribution of the system only in case the full angular momentum of a system is not equal to zero. In the gas of charged particles in a uniform magnetic field the density of distribution also varies if the angular momentum is zero [see Dubrovskii I.M., Condensed Matter Physics, 2206, 9, 23]. Two-dimensional gas of charged particles located within a section of an endless strip filled with gas in magnetic field is considered. Under such conditions the angular momentum is not conserved. Directional particle flows take place close to the strip boundaries, and, as a consequence, the phase trajectory of the considered set of particles does not remain within the limited volume of the phase space. In order to apply a statistical thermodynamics method, it was suggested to consider near-boundary trajectories relative to a reference system that moves uniformly. It was shown that if the diameter of an orbit having average thermal energy is much smaller than a strip width, the corrections to thermodynamic functions are small depending on magnetic field. Only the average velocity of near-boundary particles that form near-boundary electric currents creating the paramagnetic moment turn out to be essential.

  7. Helicon modes in uniform plasmas. III. Angular momentum

    Energy Technology Data Exchange (ETDEWEB)

    Stenzel, R. L.; Urrutia, J. M. [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States)

    2015-09-15

    Helicons are electromagnetic waves with helical phase fronts propagating in the whistler mode in magnetized plasmas and solids. They have similar properties to electromagnetic waves with angular momentum in free space. Helicons are circularly polarized waves carrying spin angular momentum and orbital angular momentum due to their propagation around the ambient magnetic field B{sub 0}. These properties have not been considered in the community of researchers working on helicon plasma sources, but are the topic of the present work. The present work focuses on the field topology of helicons in unbounded plasmas, not on helicon source physics. Helicons are excited in a large uniform laboratory plasma with a magnetic loop antenna whose dipole axis is aligned along or across B{sub 0}. The wave fields are measured in orthogonal planes and extended to three dimensions (3D) by interpolation. Since density and B{sub 0} are uniform, small amplitude waves from loops at different locations can be superimposed to generate complex antenna patterns. With a circular array of phase shifted loops, whistler modes with angular and axial wave propagation, i.e., helicons, are generated. Without boundaries radial propagation also arises. The azimuthal mode number m can be positive or negative while the field polarization remains right-hand circular. The conservation of energy and momentum implies that these field quantities are transferred to matter which causes damping or reflection. Wave-particle interactions with fast electrons are possible by Doppler shifted resonances. The transverse Doppler shift is demonstrated. Wave-wave interactions are also shown by showing collisions between different helicons. Whistler turbulence does not always have to be created by nonlinear wave-interactions but can also be a linear superposition of waves from random sources. In helicon collisions, the linear and/or orbital angular momenta can be canceled, which results in a great variety of field

  8. Thermal behaviour of hafnium diethylenetriaminepentaacetate studied using the perturbed angular correlation technique

    Energy Technology Data Exchange (ETDEWEB)

    Chain, Cecilia Y. [Universidad Nacional de La Plata (Argentina). Dept. de Fisica; Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires (Argentina); Rivas, Patricia [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires (Argentina); Universidad Nacional de La Plata (Argentina). Facultad de Ciencias Agrarias y Forestales; Pasquevich, Alberto F. [Universidad Nacional de La Plata (Argentina). Dept. de Fisica; Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), La Plata (Argentina). IFLP-CCT; Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CIC-PBA) (Argentina)

    2014-07-01

    Polyaminecarboxilic ligands like diethylenetriaminepentaacetic acid form stable complexes with many heavy metal ions, excelling as cation chelants especially in the field of radiopharmacy. The aim of this work is to characterize, by using the Time Differential Perturbed Angular Correlations (TDPAC) technique, the hyperfine interactions at hafnium sites in hafnium diethylenetriaminepentaacetate and to investigate their evolution as temperature increases. TDPAC results for KHfDTPA.3H{sub 2}O obtained by chemical synthesis yield a well defined and highly asymmetric interaction of quadrupole frequency ω{sub Q} = 141 Mrad/s, which is consistent with the existence of a unique site for the metal in the crystal lattice. The thermal behaviour of the chelate is investigated by means of differential scanning calorimetry and thermogravimetrical analyses revealing that an endothermic dehydration of KHfDTPA.3H{sub 2}O takes place in one step between 80 C and 180 C. The anhydrous KHfDTPA thus arising is characterized by a fully asymmetric and well defined interaction of quadrupole frequency ω{sub Q} = 168 Mrad/s. (orig.)

  9. LFP: A PC-program for ligand-field analysis of 3d(n) ions in Oh and lower symmetries

    Science.gov (United States)

    Kurzak

    2000-05-01

    A modular and efficient version of PC program for calculating ligand-field parameters, i.e. crystal-field model (CFM) and angular overlap model (AOM) is presented. The LFP program is designed to calculate the ligand-field parameters of low symmetry transition metal complexes. It is based on the general method for the analysis of central ion states distortion using group theory. The program has not closed form. It will be extended, according to spectroscopic studies in our laboratory. It is written in FORTRAN language.

  10. Ligand binding mechanics of maltose binding protein.

    Science.gov (United States)

    Bertz, Morten; Rief, Matthias

    2009-11-13

    In the past decade, single-molecule force spectroscopy has provided new insights into the key interactions stabilizing folded proteins. A few recent studies probing the effects of ligand binding on mechanical protein stability have come to quite different conclusions. While some proteins seem to be stabilized considerably by a bound ligand, others appear to be unaffected. Since force acts as a vector in space, it is conceivable that mechanical stabilization by ligand binding is dependent on the direction of force application. In this study, we vary the direction of the force to investigate the effect of ligand binding on the stability of maltose binding protein (MBP). MBP consists of two lobes connected by a hinge region that move from an open to a closed conformation when the ligand maltose binds. Previous mechanical experiments, where load was applied to the N and C termini, have demonstrated that MBP is built up of four building blocks (unfoldons) that sequentially detach from the folded structure. In this study, we design the pulling direction so that force application moves the two MBP lobes apart along the hinge axis. Mechanical unfolding in this geometry proceeds via an intermediate state whose boundaries coincide with previously reported MBP unfoldons. We find that in contrast to N-C-terminal pulling experiments, the mechanical stability of MBP is increased by ligand binding when load is applied to the two lobes and force breaks the protein-ligand interactions directly. Contour length measurements indicate that MBP is forced into an open conformation before unfolding even if ligand is bound. Using mutagenesis experiments, we demonstrate that the mechanical stabilization effect is due to only a few key interactions of the protein with its ligand. This work illustrates how varying the direction of the applied force allows revealing important details about the ligand binding mechanics of a large protein.

  11. Optical orbital angular momentum conservation during the transfer process from plasmonic vortex lens to light.

    Science.gov (United States)

    Yu, Haohai; Zhang, Huaijin; Wang, Yicheng; Han, Shuo; Yang, Haifang; Xu, Xiangang; Wang, Zhengping; Petrov, V; Wang, Jiyang

    2013-11-12

    We demonstrate the optical orbital angular momentum conservation during the transfer process from subwavelength plasmonic vortex lens (PVLs) to light and the generating process of surface plasmon polaritons (SPPs). Illuminating plasmonic vortex lenses with beams carrying optical orbital angular momentum, the SP vortices with orbital angular momentum were generated and inherit the optical angular momentum of light beams and PVLs. The angular momentum of twisting SP electromagnetic field is tunable by the twisted metal/dielectric interfaces of PVLs and angular momentum of illuminating singular light. This work may open the door for several possible applications of SP vortices in subwavelength region.

  12. Correcting ligands, metabolites, and pathways

    Directory of Open Access Journals (Sweden)

    Vriend Gert

    2006-11-01

    Full Text Available Abstract Background A wide range of research areas in bioinformatics, molecular biology and medicinal chemistry require precise chemical structure information about molecules and reactions, e.g. drug design, ligand docking, metabolic network reconstruction, and systems biology. Most available databases, however, treat chemical structures more as illustrations than as a datafield in its own right. Lack of chemical accuracy impedes progress in the areas mentioned above. We present a database of metabolites called BioMeta that augments the existing pathway databases by explicitly assessing the validity, correctness, and completeness of chemical structure and reaction information. Description The main bulk of the data in BioMeta were obtained from the KEGG Ligand database. We developed a tool for chemical structure validation which assesses the chemical validity and stereochemical completeness of a molecule description. The validation tool was used to examine the compounds in BioMeta, showing that a relatively small number of compounds had an incorrect constitution (connectivity only, not considering stereochemistry and that a considerable number (about one third had incomplete or even incorrect stereochemistry. We made a large effort to correct the errors and to complete the structural descriptions. A total of 1468 structures were corrected and/or completed. We also established the reaction balance of the reactions in BioMeta and corrected 55% of the unbalanced (stoichiometrically incorrect reactions in an automatic procedure. The BioMeta database was implemented in PostgreSQL and provided with a web-based interface. Conclusion We demonstrate that the validation of metabolite structures and reactions is a feasible and worthwhile undertaking, and that the validation results can be used to trigger corrections and improvements to BioMeta, our metabolite database. BioMeta provides some tools for rational drug design, reaction searches, and

  13. Fission fragment angular distributions in pre-actinide nuclei

    Science.gov (United States)

    Banerjee, Tathagata; Nath, S.; Jhingan, A.; Kaur, Gurpreet; Dubey, R.; Yadav, Abhishek; Laveen, P. V.; Shamlath, A.; Shareef, M.; Gehlot, J.; Saneesh, N.; Prasad, E.; Sugathan, P.; Pal, Santanu

    2016-10-01

    Background: Complete fusion of two nuclei leading to formation of a heavy compound nucleus (CN) is known to be hindered by various fission-like processes, in which the composite system reseparates after capture of the target and the projectile inside the potential barrier. As a consequence of these non-CN fission (NCNF) processes, fusion probability (PCN) starts deviating from unity. Despite substantial progress in understanding, the onset and the experimental signatures of NCNF and the degree of its influence on fusion have not yet been unambiguously identified. Purpose: This work aims to investigate the presence of NCNF, if any, in pre-actinide nuclei by systematic study of fission angular anisotropies and fission cross sections (σfis) in a number of nuclear reactions carried out at and above the Coulomb barrier (VB) . Method: Fission fragment angular distributions were measured for six 28Si-induced reactions involving isotopically enriched targets of 169Tm,176Yb,175Lu,180Hf,181Ta, and 182W leading to probable formation of CN in the pre-actinide region, at a laboratory energy (Elab) range of 129-146 MeV. Measurements were performed with large angular coverage (θlab=41∘ -170∘) in which fission fragments (FFs) were detected by nine hybrid telescope (E -Δ E ) detectors. Extracted fission angular anisotropies and σfis were compared with statistical model (SM) predictions. Results: Barring two reactions involving targets with large non-zero ground state spin (J ) , viz., 175Lu(7/2+) and 181Ta(7/2+) , experimental fission angular anisotropies were found to be higher in comparison with predictions of the statistical saddle point model (SSPM), at Ec .m . near VB. Comparison of present results with those from neighboring systems revealed that experimental anisotropies increasingly deviated from SSPM predictions as one moved from pre-actinide to actinide nuclei. For reactions involving targets with large nonzero J , this deviation was subdued. Comparison between

  14. Multicomponent mixtures for cryoprotection and ligand solubilization

    Directory of Open Access Journals (Sweden)

    Lidia Ciccone

    2015-09-01

    Full Text Available Mixed cryoprotectants have been developed for the solubilization of ligands for crystallization of protein–ligand complexes and for crystal soaking. Low affinity lead compounds with poor solubility are problematic for structural studies. Complete ligand solubilization is required for co-crystallization and crystal soaking experiments to obtain interpretable electron density maps for the ligand. Mixed cryo-preserving compounds are needed prior to X-ray data collection to reduce radiation damage at synchrotron sources. Here we present dual-use mixes that act as cryoprotectants and also promote the aqueous solubility of hydrophobic ligands. Unlike glycerol that increases protein solubility and can cause crystal melting the mixed solutions of cryo-preserving compounds that include precipitants and solubilizers, allow for worry-free crystal preservation while simultaneously solubilizing relatively hydrophobic ligands, typical of ligands obtained in high-throughput screening. The effectiveness of these mixture has been confirmed on a human transthyretin crystals both during crystallization and in flash freezing of crystals.

  15. Coordinate unsaturation with fluorinated ligands

    Energy Technology Data Exchange (ETDEWEB)

    Rack, J.L.; Hurlburt, P.K.; Anderson, O.P.; Strauss, S.H. [Colorado State Univ., Ft. Collins, CO (United States)

    1993-12-31

    The preparation and characterization of Zn(OTeF{sub 5}){sub 2} has resulted in a model compound with which to explore the concept of coordinative unsaturation. The coordination of solvents of varying donicity and dielectric constant to the Zn(II) ions in Zn(OTeF{sub 5}){sub 2} was studied by vapor phase monometry, NMR and IR spectroscopy, conductimetry, and X-Ray crystallography. The structures of [Zn(C{sub 6}H{sub 5}NO{sub 2}){sub 2}(OTeF{sub 5})2]2 and Zn(C{sub 6}H{sub 5}NO{sub 2}){sub 3}(OTEF{sub 5}){sub 2} demonstrate the electronic flexibility of some weakly coordinating solvents in that nitrobenzene can function as either an {eta}{sup 1}O or {eta}{sup 2}O,O`-ligand. The dependence of the number of bound solvent molecules and the degree of OTeF{sub 5}{minus} dissociation on solvent donor number and dielectric constant will be presented.

  16. Angular dependence of Wigner time delay: Relativistic Effects

    Science.gov (United States)

    Mandal, A.; Deshmukh, P. C.; Manson, S. T.; Kkeifets, A. S.

    2016-05-01

    Laser assisted photoionization time delay mainly consists of two parts: Wigner time delay, and time delay in continuum-continuum transition. Wigner time delay results from the energy derivative of the phase of the photoionization amplitude (matrix element). In general, the photoionization time delay is not the same in all directions relative to the incident photon polarization, although when a single transition dominates the amplitude, the resultant time delay is essentially isotropic. The relativistic-random-phase approximation is employed to determine the Wigner time delay in photoionization from the outer np subshells of the noble gas atoms, Ne through Xe. The time delay is found to significantly depend on angle, as well as energy. The angular dependence of the time delay is found to be quite sensitive to atomic dynamics and relativistic effects, and exhibit strong energy and angular variation in the neighborhood of Cooper minima. Work supported by DOE, Office of Chemical Sciences and DST (India).

  17. Efficient separation of the orbital angular momentum eigenstates of light.

    Science.gov (United States)

    Mirhosseini, Mohammad; Malik, Mehul; Shi, Zhimin; Boyd, Robert W

    2013-01-01

    Orbital angular momentum (OAM) of light is an attractive degree of freedom for fundamental studies in quantum mechanics. In addition, the discrete unbounded state-space of OAM has been used to enhance classical and quantum communications. Unambiguous measurement of OAM is a key part of all such experiments. However, state-of-the-art methods for separating single photons carrying a large number of different OAM values are limited to a theoretical separation efficiency of about 77%. Here we demonstrate a method which uses a series of unitary optical transformations to enable the measurement of light's OAM with an experimental separation efficiency of >92%. Furthermore, we demonstrate the separation of modes in the angular position basis, which is mutually unbiased with respect to the OAM basis. The high degree of certainty achieved by our method makes it particularly attractive for enhancing the information capacity of multi-level quantum cryptography systems.

  18. Scalable orbital-angular-momentum sorting without destroying photon states

    CERN Document Server

    Wang, Fang-Xiang; Yin, Zhen-Qiang; Wang, Shuang; Guo, Guang-Can; Han, Zheng-Fu

    2016-01-01

    Single photons with orbital angular momentum (OAM) have attracted substantial attention from researchers. A single photon can carry infinite OAM values theoretically. Thus, OAM photon states have been widely used in quantum information and fundamental quantum mechanics. Although there have been many methods for sorting quantum states with different OAM values, the nondestructive and efficient sorter of high-dimensional OAM remains a fundamental challenge. Here, we propose a scalable OAM sorter which can categorize different OAM states simultaneously, meanwhile, preserving both OAM and spin angular momentum. Fundamental elements of the sorter are composed of symmetric multiport beam splitters (BSs) and Dove prisms with cascading structure, which in principle can be flexibly and effectively combined to sort arbitrarily high-dimensional OAM photons. The scalable structures proposed here greatly reduce the number of BSs required for sorting high-dimensional OAMstates. In view of the nondestructive and extensible ...

  19. Angular output of hollow, metal-lined, waveguide Raman sensors

    Energy Technology Data Exchange (ETDEWEB)

    Biedrzycki, Stephen; Buric, Michael P.; Falk, Joel; Woodruff, Steven D.

    2012-04-20

    Hollow, metal-lined waveguides used as gas sensors based on spontaneous Raman scattering are capable of large angular collection. The collection of light from a large solid angle implies the collection of a large number of waveguide modes. An accurate estimation of the propagation losses for these modes is required to predict the total collected Raman power. We report a theory/experimental comparison of the Raman power collected as a function of the solid angle and waveguide length. New theoretical observations are compared with previous theory appropriate only for low-order modes. A cutback experiment is demonstrated to verify the validity of either theory. The angular distribution of Raman light is measured using aluminum and silver-lined waveguides of varying lengths.

  20. Angular Momentum Transport in Quasi-Keplerian Accretion Disks

    Indian Academy of Sciences (India)

    Prasad Subramanian; B. S. Pujari; Peter A. Becker

    2004-03-01

    We reexamine arguments advanced by Hayashi & Matsuda (2001), who claim that several simple, physically motivated derivations based on mean free path theory for calculating the viscous torque in a quasi-Keplerian accretion disk yield results that are inconsistent with the generally accepted model. If correct, the ideas proposed by Hayashi & Matsuda would radically alter our understanding of the nature of the angular momentum transport in the disk, which is a central feature of accretion disk theory. However, in this paper we point out several fallacies in their arguments and show that there indeed exists a simple derivation based on mean free path theory that yields an expression for the viscous torque that is proportional to the radial derivative of the angular velocity in the accretion disk, as expected. The derivation is based on the analysis of the epicyclic motion of gas parcels in adjacent eddies in the disk.

  1. Time and "angular" dependent backgrounds from stationary axisymmetric solutions

    CERN Document Server

    Obregón, O; Ryan, M P; Obregon, Octavio; Quevedo, Hernando; Ryan, Michael P.

    2004-01-01

    Backgrounds depending on time and on "angular" variable, namely polarized and unpolarized $S^1 \\times S^2$ Gowdy models, are generated as the sector inside the horizons of the manifold corresponding to axisymmetric solutions. As is known, an analytical continuation of ordinary $D$-branes, $iD$-branes allows one to find $S$-brane solutions. Simple models have been constructed by means of analytic continuation of the Schwarzchild and the Kerr metrics. The possibility of studying the $i$-Gowdy models obtained here is outlined with an eye toward seeing if they could represent some kind of generalized $S$-branes depending not only on time but also on an ``angular'' variable.

  2. Efficient polarization of high-angular-momentum systems

    CERN Document Server

    Rochester, Simon; Raizen, Mark; Pustelny, Szymon; Auzinsh, Marcis; Budker, Dmitry

    2016-01-01

    We propose methods of optical pumping that are applicable to open, high-angular-momentum transitions in atoms and molecules, for which conventional optical pumping would lead to significant population loss. Instead of applying circularly polarized cw light, as in conventional optical pumping, we propose to use techniques for coherent population transfer (e.g., adiabatic fast passage) to arrange the atoms so as to increase the entropy removed from the system with each spontaneous decay from the upper state. This minimizes the number of spontaneous-emission events required to produce a stretched state, thus reducing the population loss due to decay to other states. To produce a stretched state in a manifold with angular momentum J, conventional optical pumping requires about 2J spontaneous decays per atom; one of our proposed methods reduces this to about log_2(2J), while another of the methods reduces it to about one spontaneous decay, independent of J.

  3. Higher signal harmonics, LISA's angular resolution and dark energy

    CERN Document Server

    Arun, K G; Sathyaprakash, B S; Sinha, Siddhartha; Broeck, Chris Van Den

    2007-01-01

    It is generally believed that the angular resolution of the Laser Interferometer Space Antenna (LISA) for binary supermassive black holes (SMBH) will not be good enough to identify the host galaxy or galaxy cluster. This conclusion, based on using only the dominant harmonic of the binary SMBH signal, changes dramatically when higher signal harmonics are included in assessing the parameter estimation problem. We show that in a subset of the source parameter space the angular resolution increases by more than a factor of 10, thereby making it possible for LISA to identify the host galaxy/galaxy cluster. Thus, LISA's observation of certain binary SMBH coalescence events could constrain the dark energy equation of state to within a few percent, comparable to the level expected from other dark energy missions.

  4. Angular line scanning deflectometry using a laser pico projector

    Science.gov (United States)

    Zhan, Hao-Xun; Liang, Chao-Wen; Chien, Shih-Che

    2016-08-01

    In our previous publications, we had successfully made a deflectometry measurement by using a portable laser projector. In this research, we propose the beam weighting centroid method rather than previous the phase shifting method for quantification of the angular direction of the testing beam in the tested optics entrance pupil. By projecting the angular sequential lines on tested optics entrance pupil, the wavefront aberration is reconstructed from two orthogonal directions measurements, in a similar way to the line scanning deflectometry. The limited gray scale problem of laser projector during the phase shifting measurement is therefore eliminated. The reconstructed wavefront is proven to yield a more accurate result than the phase shifting methods at the cost of more image frames and acquisition time.

  5. Atmosphere-earth angular momentum exchange and ENSO cycle

    Institute of Scientific and Technical Information of China (English)

    钱维宏; 丑纪范

    1996-01-01

    The time series of the earth’s rotation rate, eastern equatorial Pacific sea surface temperature (Tss), sea level pressure (Psl) and atmospheric angular momentum (Maa) during 1976 -1989 are used to study the relation between atmosphere-earth angular momentum exchange and ENSO cycle. The result shows that (i) there are synergetic relationships among the variations of solid earth’s rotation, eastern equatorial Pacific T,, Psl, different latitude zonal Maa and global Maa; (ii) local atmosphere-ocean interaction over low-latitude area can form ENSO-like cycle through Hadley circulation; (iii) the solid earth and global atmosphere-ocean interaction can form some aperiodic behavior and asynchronous oscillations by mountain torque and earth spin anomalous friction torque acting on each component of solid earth-ocean-atmosphere system; and (iv) actual ENSO cycle is a phenomenon reflecting in Pacific basin through interaction among solid earth, global ocean and the atmosphere.

  6. Angular-dependent magnetization reversal processes in artificial spin ice

    Science.gov (United States)

    Burn, D. M.; Chadha, M.; Branford, W. R.

    2015-12-01

    The angular dependence of the magnetization reversal in interconnected kagome artificial spin ice structures has been studied through experimental MOKE measurements and micromagnetic simulations. This reversal is mediated by the propagation of magnetic domain walls along the interconnecting bars, which either nucleate at the vertex or arrive following an interaction in a neighboring vertex. The physical differences in these processes show a distinct angular dependence allowing the different contributions to be identified. The configuration of the initial magnetization state, either locally or on a full sublattice of the system, controls the reversal characteristics of the array within a certain field window. This shows how the available magnetization reversal routes can be manipulated and the system can be trained.

  7. Angular diameter distances reconsidered in the Newman and Penrose formalism

    CERN Document Server

    Kling, Thomas P

    2016-01-01

    Using the Newman and Penrose spin coefficient (NP) formalism, we provide a derivation of the Dyer-Roeder equation for the angular diameter distance in cosmological space-times. We show that the geodesic deviation equation written in NP formalism is precisely the Dyer-Roeder equation for a general Friedman-Robertson-Walker (FRW) space-time, and then we examine the angular diameter distance to redshift relation in the case that a flat FRW metric is perturbed by a gravitational potential. We examine the perturbation in the case that the gravitational potential exhibits the properties of a thin gravitational lens, demonstrating how the weak lensing shear and convergence act as source terms for the perturbed Dyer-Roeder equation.

  8. Photonic-phononic orbital angular momentum in Brillouin parametric conversion

    CERN Document Server

    Zhu, Zhihan; Mu, Chunyuan; Li, Hongwei

    2014-01-01

    Orbital angular momentum (OAM) is a fundamental photonic degree of freedom, showed by Allen and co-workers. Its most attractive feature is an inherently infinite dimensionality, which in recent years has obtained several ground-breaking demonstrations for high information-density communication and processing, both in classical and quantum. Here, by seeking the reason for photonic OAM non-conservation in stimulated Brillouin amplification, we report the first demonstration of the evolution law for OAM in Brillouin process. The parameter of OAM can conveniently transfer between the phonons and different polarized photons due to the photonic spin angular momentum conservation. Our results have revealed a parametric conversion mechanism of Brillouin process for Photonic-phononic OAM, demonstrated the role of phononic OAM and the vortex acoustic wave in this process, and suggested this mechanism may find important applications in OAM-based information communication and processing.

  9. Angular Momentum Transport via Internal Gravity Waves in Evolving Stars

    CERN Document Server

    Fuller, Jim; Cantiello, Matteo; Brown, Ben

    2014-01-01

    Recent asteroseismic advances have allowed for direct measurements of the internal rotation rates of many sub-giant and red giant stars. Unlike the nearly rigidly rotating Sun, these evolved stars contain radiative cores that spin faster than their overlying convective envelopes, but slower than they would in the absence of internal angular momentum transport. We investigate the role of internal gravity waves in angular momentum transport in evolving low mass stars. In agreement with previous results, we find that convectively excited gravity waves can prevent the development of strong differential rotation in the radiative cores of Sun-like stars. As stars evolve into sub-giants, however, low frequency gravity waves become strongly attenuated and cannot propagate below the hydrogen burning shell, allowing the spin of the core to decouple from the convective envelope. This decoupling occurs at the base of the sub-giant branch when stars have surface temperatures of roughly 5500 K. However, gravity waves can s...

  10. Investigating pointing tasks across angularly coupled display areas

    DEFF Research Database (Denmark)

    Hennecke, Fabian; De Luca, Alexander; Nguyen, Ngo Dieu Huong;

    2013-01-01

    Pointing tasks are a crucial part of today’s graphical user interfaces. They are well understood for flat displays and most prominently are modeled through Fitts’ Law. For novel displays (e.g., curved displays with multi-purpose areas), however, it remains unclear whether such models for predicting...... that the target position affects overall pointing speed and offset in both conditions. However, we also found that Fitts’ Law can in fact still be used to predict performance as on flat displays. Our results help designers to optimize user interfaces on angularly coupled displays when pointing tasks are involved....... user performance still hold – in particular when pointing is performed across differently oriented areas. To answer this question, we conducted an experiment on an angularly coupled display – the Curve – with two input conditions: direct touch and indirect mouse pointer. Our findings show...

  11. Nanoparticles at liquid interfaces: Rotational dynamics and angular locking

    Energy Technology Data Exchange (ETDEWEB)

    Razavi, Sepideh; Kretzschmar, Ilona [Department of Chemical Engineering, City College of City University of New York, New York, New York 10031 (United States); Koplik, Joel [Department of Physics and The Benjamin Levich Institute for Physico-chemical Hydrodynamics, City College of City University of New York, New York, New York 10031 (United States); Colosqui, Carlos E., E-mail: carlos.colosqui@stonybrook.edu [Department of Mechanical Engineering, Stony Brook University, Stony Brook, New York 11794 (United States)

    2014-01-07

    Nanoparticles with different surface morphologies that straddle the interface between two immiscible liquids are studied via molecular dynamics simulations. The methodology employed allows us to compute the interfacial free energy at different angular orientations of the nanoparticle. Due to their atomistic nature, the studied nanoparticles present both microscale and macroscale geometrical features and cannot be accurately modeled as a perfectly smooth body (e.g., spheres and cylinders). Under certain physical conditions, microscale features can produce free energy barriers that are much larger than the thermal energy of the surrounding media. The presence of these energy barriers can effectively “lock” the particle at specific angular orientations with respect to the liquid-liquid interface. This work provides new insights on the rotational dynamics of Brownian particles at liquid interfaces and suggests possible strategies to exploit the effects of microscale features with given geometric characteristics.

  12. Angular momentum and torque described with the complex octonion

    CERN Document Server

    Weng, Zi-Hua

    2015-01-01

    The paper aims to adopt the complex octonion to formulate the angular momentum, torque, and force etc in the electromagnetic and gravitational fields. Applying the octonionic representation enables one single definition of angular momentum (or torque, force) to combine some physics contents, which were considered to be independent of each other in the past. J. C. Maxwell used simultaneously two methods, the vector terminology and quaternion analysis, to depict the electromagnetic theory. It motivates the paper to introduce the quaternion space into the field theory, describing the physical feature of electromagnetic and gravitational fields. The spaces of two fields can be chosen as the quaternion spaces, while the coordinate component of quaternion space is able to be the complex number. The quaternion space of electromagnetic field is independent of that of gravitational field. These two quaternion spaces may compose one octonion space. Contrarily, one octonion space can be separated into two subspaces, the...

  13. Angular distribution and atomic effects in condensed phase photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R.F.

    1981-11-01

    A general concept of condensed phase photoelectron spectroscopy is that angular distribution and atomic effects in the photoemission intensity are determined by different mechanisms, the former being determined largely by ordering phenomena such as crystal momentum conservation and photoelectron diffraction while the latter are manifested in the total (angle-integrated) cross section. In this work, the physics of the photoemission process is investigated in several very different experiments to elucidate the mechanisms of, and correlation between, atomic and angular distribution effects. Theoretical models are discussed and the connection betweeen the two effects is clearly established. The remainder of this thesis, which describes experiments utilizing both angle-resolved and angle-integrated photoemission in conjunction with synchrotron radiation in the energy range 6 eV less than or equal to h ..nu.. less than or equal to 360 eV and laboratory sources, is divided into three parts.

  14. Optomechanics based on angular momentum exchange between light and matter

    Science.gov (United States)

    Shi, H.; Bhattacharya, M.

    2016-08-01

    The subject of optomechanics involves interactions between optical and mechanical degrees of freedom, and is currently of great interest as an enabler of fundamental investigations in quantum mechanics, as well as a platform for ultrasensitive measurement devices. The majority of optomechanical configurations rely on the exchange of linear momentum between light and matter. We will begin this tutorial with a brief description of such systems. Subsequently, we will introduce optomechanical systems based on angular momentum exchange. In this context, optical fields carrying polarization and orbital angular momentum will be considered, while for the mechanics, torsional and free rotational motion will be of relevance. Our overall aims will be to supply basic analyses of some of the existing theoretical proposals, to provide functional descriptions of some of the experiments conducted thus far, and to consider some directions for future research. We hope this tutorial will be useful to both theorists and experimentalists interested in the subject.

  15. Resolving enantiomers using the optical angular momentum of twisted light.

    Science.gov (United States)

    Brullot, Ward; Vanbel, Maarten K; Swusten, Tom; Verbiest, Thierry

    2016-03-01

    Circular dichroism and optical rotation are crucial for the characterization of chiral molecules and are of importance to the study of pharmaceutical drugs, proteins, DNA, and many others. These techniques are based on the different interactions of enantiomers with circularly polarized components of plane wave light that carries spin angular momentum (SAM). For light carrying orbital angular momentum (OAM), for example, twisted or helical light, the consensus is that it cannot engage with the chirality of a molecular system as previous studies failed to demonstrate an interaction between optical OAM and chiral molecules. Using unique nanoparticle aggregates, we prove that optical OAM can engage with materials' chirality and discriminate between enantiomers. Further, theoretical results show that compared to circular dichroism, mainly based on magnetic dipole contributions, the OAM analog helical dichroism (HD) is critically dependent on fundamentally different chiral electric quadrupole contributions. Our work opens new venues to study chirality and can find application in sensing and chiral spectroscopy.

  16. Unveiling pseudospin and angular momentum in photonic graphene.

    Science.gov (United States)

    Song, Daohong; Paltoglou, Vassilis; Liu, Sheng; Zhu, Yi; Gallardo, Daniel; Tang, Liqin; Xu, Jingjun; Ablowitz, Mark; Efremidis, Nikolaos K; Chen, Zhigang

    2015-02-17

    Pseudospin, an additional degree of freedom inherent in graphene, plays a key role in understanding many fundamental phenomena such as the anomalous quantum Hall effect, electron chirality and Klein paradox. Unlike the electron spin, the pseudospin was traditionally considered as an unmeasurable quantity, immune to Stern-Gerlach-type experiments. Recently, however, it has been suggested that graphene pseudospin is a real angular momentum that might manifest itself as an observable quantity, but so far direct tests of such a momentum remained unfruitful. Here, by selective excitation of two sublattices of an artificial photonic graphene, we demonstrate pseudospin-mediated vortex generation and topological charge flipping in otherwise uniform optical beams with Bloch momentum traversing through the Dirac points. Corroborated by numerical solutions of the linear massless Dirac-Weyl equation, we show that pseudospin can turn into orbital angular momentum completely, thus upholding the belief that pseudospin is not merely for theoretical elegance but rather physically measurable.

  17. Resilience of hybrid optical angular momentum qubits to turbulence.

    Science.gov (United States)

    Farías, Osvaldo Jiménez; D'Ambrosio, Vincenzo; Taballione, Caterina; Bisesto, Fabrizio; Slussarenko, Sergei; Aolita, Leandro; Marrucci, Lorenzo; Walborn, Stephen P; Sciarrino, Fabio

    2015-02-12

    Recent schemes to encode quantum information into the total angular momentum of light, defining rotation-invariant hybrid qubits composed of the polarization and orbital angular momentum degrees of freedom, present interesting applications for quantum information technology. However, there remains the question as to how detrimental effects such as random spatial perturbations affect these encodings. Here, we demonstrate that alignment-free quantum communication through a turbulent channel based on hybrid qubits can be achieved with unit transmission fidelity. In our experiment, alignment-free qubits are produced with q-plates and sent through a homemade turbulence chamber. The decoding procedure, also realized with q-plates, relies on both degrees of freedom and renders an intrinsic error-filtering mechanism that maps errors into losses.

  18. The angular diameter and distance of the Cepheid Zeta Geminorum

    CERN Document Server

    Kervella, P; Perrin, G; Schöller, M; Traub, W A; Lacasse, M D

    2001-01-01

    Cepheids are the primary distance indicators for extragalactic astronomy and therefore are of very high astrophysical interest. Unfortunately, they are rare stars, situated very far from Earth.Though they are supergiants, their typical angular diameter is only a few milliarcseconds, making them very challenging targets even for long-baseline interferometers. We report observations that were obtained in the K prime band (2-2.3 microns), on the Cepheid Zeta Geminorum with the FLUOR beam combiner, installed at the IOTA interferometer. The mean uniform disk angular diameter was measured to be 1.64 +0.14 -0.16 mas. Pulsational variations are not detected at a significant statistical level, but future observations with longer baselines should allow a much better estimation of their amplitude. The distance to Zeta Gem is evaluated using Baade-Wesselink diameter determinations, giving a distance of 502 +/- 88 pc.

  19. Measurement of polarization with the Degree Angular Scale Interferometer.

    Science.gov (United States)

    Leitch, E M; Kovac, J M; Pryke, C; Carlstrom, J E; Halverson, N W; Holzapfel, W L; Dragovan, M; Reddall, B; Sandberg, E S

    Measurements of the cosmic microwave background (CMB) radiation can reveal with remarkable precision the conditions of the Universe when it was approximately 400,000 years old. The three most fundamental properties of the CMB are its frequency spectrum (which determines the temperature), and the fluctuations in both the temperature and polarization across a range of angular scales. The frequency spectrum has been well determined, and considerable progress has been made in measuring the power spectrum of the temperature fluctuations. But despite many efforts to measure the polarization, detection of this property of the CMB has hitherto been beyond the reach of even the most sensitive observations. Here we describe the Degree Angular Scale Interferometer (DASI), an array of radio telescopes, which for the past two years has conducted polarization-sensitive observations of the CMB from the Amundsen-Scott South Pole research station.

  20. Analogies between optical and quantum mechanical angular momentum

    Science.gov (United States)

    Nienhuis, Gerard

    2017-02-01

    The insight that a beam of light can carry orbital angular momentum (AM) in its propagation direction came up in 1992 as a surprise. Nevertheless, the existence of momentum and AM of an electromagnetic field has been well known since the days of Maxwell. We compare the expressions for densities of AM in general three-dimensional modes and in paraxial modes. Despite their classical nature, these expressions have a suggestive quantum mechanical appearance, in terms of linear operators acting on mode functions. In addition, paraxial wave optics has several analogies with real quantum mechanics, both with the wave function of a free quantum particle and with a quantum harmonic oscillator. We discuss how these analogies can be applied. This article is part of the themed issue 'Optical orbital angular momentum'.

  1. MRI-driven angular momentum transport in protoplanetary disks

    CERN Document Server

    Fromang, Sebastien

    2013-01-01

    Angular momentum transport in accretion disk has been the focus of intense research in theoretical astrophysics for many decades. In the past twenty years, MHD turbulence driven by the magnetorotational instability has emerged as an efficient mechanism to achieve that goal. Yet, many questions and uncertainties remain, among which the saturation level of the turbulence. The consequences of the magnetorotational instability for planet formation models are still being investigated. This lecture, given in September 2012 at the school "Role and mechanisms of angular momentum transport in the formation and early evolution of stars" in Aussois (France), aims at introducing the historical developments, current status and outstanding questions related to the magnetorotational instability that are currently at the forefront of academic research.

  2. MRI-driven angular momentum transport in protoplanetary disks

    Science.gov (United States)

    Fromang, S.

    2013-09-01

    Angular momentum transport in accretion disk has been the focus of intense research in theoretical astrophysics for many decades. In the past twenty years, MHD turbulence driven by the magnetorotational instability has emerged as an efficient mechanism to achieve that goal. Yet, many questions and uncertainties remain, among which the saturation level of the turbulence. The consequences of the magnetorotational instability for planet formation models are still being investigated. This lecture, given in September 2012 at the school "Role and mechanisms of angular momentum transport in the formation and early evolution of stars" in Aussois (France), aims at introducing the historical developments, current status and outstanding questions related to the magnetorotational instability that are currently at the forefront of academic research.

  3. Hybrid nonlinear model of the angular vestibulo-ocular reflex.

    Science.gov (United States)

    Ranjbaran, Mina; Galiana, Henrietta L

    2013-01-01

    A hybrid nonlinear bilateral model for the horizontal angular vestibulo-ocular reflex (AVOR) is presented in this paper. The model relies on known interconnections between saccadic burst circuits in the brainstem and ocular premotor areas in the vestibular nuclei during slow and fast phase intervals. A viable switching strategy for the timing of nystagmus events is proposed. Simulations show that this hybrid model replicates AVOR nystagmus patterns that are observed in experimentally recorded data.

  4. Characterization of the Bell-Shaped Vibratory Angular Rate Gyro

    Directory of Open Access Journals (Sweden)

    Junfang Fan

    2013-08-01

    Full Text Available The bell-shaped vibratory angular rate gyro (abbreviated as BVG is a novel shell vibratory gyroscope, which is inspired by the Chinese traditional bell. It sensitizes angular velocity through the standing wave precession effect. The bell-shaped resonator is a core component of the BVG and looks like the millimeter-grade Chinese traditional bell, such as QianLong Bell and Yongle Bell. It is made of Ni43CrTi, which is a constant modulus alloy. The exciting element, control element and detection element are uniformly distributed and attached to the resonator, respectively. This work presents the design, analysis and experimentation on the BVG. It is most important to analyze the vibratory character of the bell-shaped resonator. The strain equation, internal force and the resonator's equilibrium differential equation are derived in the orthogonal curvilinear coordinate system. When the input angular velocity is existent on the sensitive axis, an analysis of the vibratory character is performed using the theory of thin shells. On this basis, the mode shape function and the simplified second order normal vibration mode dynamical equation are obtained. The coriolis coupling relationship about the primary mode and secondary mode is established. The methods of the signal processing and control loop are presented. Analyzing the impact resistance property of the bell-shaped resonator, which is compared with other shell resonators using the Finite Element Method, demonstrates that BVG has the advantage of a better impact resistance property. A reasonable means of installation and a prototypal gyro are designed. The gyroscopic effect of the BVG is characterized through experiments. Experimental results show that the BVG has not only the advantages of low cost, low power, long work life, high sensitivity, and so on, but, also, of a simple structure and a better impact resistance property for low and medium angular velocity measurements.

  5. Adaptive Neural Network Controller for Thermogenerator Angular Velocity Stabilization System

    OpenAIRE

    2013-01-01

    The paper presents an analytical and simulation approach for the selection of activation functions for the class of neural network controllers for ship’s thermogenerator angular velocity stabilization system. Such systems can be found in many ships. A Lyapunov-like stability analysis is performed in order to obtain a weight update law. A number of simulations were performed to find the best activation function using integral error criteria and statistical T-tests.

  6. Angular distributions and total yield of laser ablated silver

    DEFF Research Database (Denmark)

    Svendsen, Winnie Edith; Nordskov, A.; Schou, Jørgen;

    1997-01-01

    The angular distribution of laser ablated silver has been measured in situ with a newly constructed setup with an array of microbalances. The distribution is strongly peaked in the forward direction corresponding to cospθ, where p varies between 5 and 9 for laser fluences from 2 to 7 J/cm2 at 355...... nm for a beam spot of 0.015 cm2. The total deposited yield is of the order 1015 Ag-atoms per pulse....

  7. Angular correlation of annihilation photons in frozen aqueous solutions

    DEFF Research Database (Denmark)

    Milosevic-Kvajic, M.; Mogensen, O. E.; Kvajic, G.

    1972-01-01

    Linear‐slit angular correlation curves were obtained at about −140°C for frozen aqueous solutions of HF, HCl, HBr, HI, NH3, FeCl2, FeCl3, NaI, H2SO4, NHO3, MnSO4, KMnO4, K2Cr2O7, NaOH, and LiOH. We found no appreciable influence of a 4% concentration of the last seven impurities. Only halide‐cont...

  8. Angular correlations in the double Drell-Yan process

    Energy Technology Data Exchange (ETDEWEB)

    Kasemets, Tomas; Diehl, Markus

    2012-10-15

    We study the impact of parton correlations on the double Drell-Yan process, i.e. on the production of two electroweak gauge bosons by double parton scattering in a single proton-proton collision. Spin correlations between two partons in a proton are shown to change the overall rate of the process and to induce characteristic angular correlations between the decay leptons of the two gauge bosons.

  9. Shape evolution with angular momentum in Lu isotopes

    Science.gov (United States)

    Kardan, Azam; Sayyah, Sepideh

    2016-06-01

    The nuclear potential energies of Lu isotopes with neutron number N = 90 - 98 up to high spins are computed within the framework of the unpaired cranked Nilsson-Strutinsky method. The potential and the macroscopic Lublin-Strasbourg drop (LSD) energy-surface diagrams are analyzed in terms of quadrupole deformation and triaxiality parameter. The shape evolution of these isotopes with respect to angular momentum, as well as the neutron number is studied.

  10. BaF2 TIME DIFFERENTIAL PERTURBED ANGULAR DISTRIBUTION SPECTROMETER

    Institute of Scientific and Technical Information of China (English)

    朱升云; 勾振辉; 等

    1994-01-01

    A BaF2 time differential perturbed angular distribution spectrometer has been established at the HI-13 tandem accelerator in CIAE.The time resolution of the spectrometer is 195ps and the nonlinearity is less than 2%.The spectrometer works very stably and no time drift is found over a period of experimental runs.This spectrometer has been successfully used in the g-factor measurement of 43Sc(19/2-,3.1232MeV).

  11. Separability criteria with angular and Hilbert space averages

    Science.gov (United States)

    Fujikawa, Kazuo; Oh, C. H.; Umetsu, Koichiro; Yu, Sixia

    2016-05-01

    The practically useful criteria of separable states ρ =∑kwkρk in d = 2 × 2 are discussed. The equality G(a , b) = 4 [ - ] = 0 for any two projection operators P(a) and P(b) provides a necessary and sufficient separability criterion in the case of a separable pure state ρ = | ψ > Werner state is applied to two photon systems, it is shown that the Hilbert space average can judge its inseparability but not the geometrical angular average.

  12. Angular characteristics of a multimode fiber surface plasmon resonance sensor

    CERN Document Server

    Tan, Zhixin; Li, Xuejin; Chen, Yuzhi; Hong, Xueming; Fan, Ping

    2015-01-01

    In this paper the angular characteristics of a multimode fiber SPR sensor are investigated theoretically. By separating the contributions of beams incident at different angles, a compact model is presented to predict the shift of the resonance wavelength with respect to the angle and the environmental refractive index. The result suggests that the performance of conventional fiber SPR sensors can be substantially improved by optimizing the incident angle.

  13. Rueda de bicicleta en movimiento y momento angular

    OpenAIRE

    2013-01-01

    Somos capaces de mantenernos erguidos mientras la bicicleta que montamos semueve, pero si ésta se detiene, nos inclinamos con ella y caemos. En este video observaremos este fenómeno utilizando una demostración experimental de física basada en una rueda de bicicleta. También analizaremos lo que sucede empleando magnitudes físicas como el momento angular de la rueda y los momentos de fuerza que actúan sobre ella.

  14. Transport and influence of angular momentum in collapsing dense cores

    Science.gov (United States)

    Hennebelle, P.

    2013-09-01

    Angular momentum is playing a key role during the collapse of prestellar cores since it is leading to disk formation and to some extent to binary formation. On the other hand, it has long been recognized that the stars possess a tiny fraction of the initial momentum that their parent clouds retain, an issue known as the "angular momentum problem". In these lectures, we attempt to present the most recent calculations performed to investigate the angular momentum transport and the influence angular momentum has, during the collapse of prestellar cores. After a brief introduction of the star formation context and a broad description of the important features within collapsing cores, we discuss the so-called catastrophic braking. Indeed when magnetic field and rotation axis are aligned, the magnetic braking is so efficient that the formation of early disks is completely prevented. We then present the various studies which have attempted to explore the robustness of this efficient transport including influence of non-ideal MHD, misalignment between magnetic field and rotation axis and turbulence. While the role of the first, is not entirely clear; the two other effects diminish the efficacity of the magnetic braking making the issue less severe than in the pure ideal MHD aligned configuration. Finally, we discuss the fragmentation of low and high mass cores with particular emphasis on the impact of the magnetic field. In particular, we discuss the drastic stabilization that magnetic field has on low mass cores and the possible solution to this apparent conundrum. In the context of high mass stars, its influence is much more limited reducing the number of fragments by a factor of the order of two. However when both radiative feedback and magentic field are included, the fragmentation is very significantly reduced.

  15. Angular dependence of spin-orbit spin-transfer torques

    KAUST Repository

    Lee, Ki-Seung

    2015-04-06

    In ferromagnet/heavy-metal bilayers, an in-plane current gives rise to spin-orbit spin-transfer torque, which is usually decomposed into fieldlike and dampinglike torques. For two-dimensional free-electron and tight-binding models with Rashba spin-orbit coupling, the fieldlike torque acquires nontrivial dependence on the magnetization direction when the Rashba spin-orbit coupling becomes comparable to the exchange interaction. This nontrivial angular dependence of the fieldlike torque is related to the Fermi surface distortion, determined by the ratio of the Rashba spin-orbit coupling to the exchange interaction. On the other hand, the dampinglike torque acquires nontrivial angular dependence when the Rashba spin-orbit coupling is comparable to or stronger than the exchange interaction. It is related to the combined effects of the Fermi surface distortion and the Fermi sea contribution. The angular dependence is consistent with experimental observations and can be important to understand magnetization dynamics induced by spin-orbit spin-transfer torques.

  16. Angular Momentum in the Formation of Disk Galaxies

    Institute of Scientific and Technical Information of China (English)

    LUO Zhi-Jian; SHU Cheng-Gang

    2004-01-01

    @@ Within the current framework of disk galaxy formation, we discuss the resulted surface-density profiles according to the theoretical angular momentum distributions (AMDs) presented by Bullock et al. [Astrophys. J.555 (2001) 240(B01)] for the ACDM cosmology in both spherical and cylindric coordinates. It is found that the derived surface density distribution of a disk in the outer region is in general similar to an exponential disk for both the theoretical AMDs. In the central region, the results from both the theoretical AMDs are inconsistent with observations whatever the disk bar-instability is taken into account or not. The cylindric form of the theoretical AMD leads to the bar-instability more easily for a give galaxy than that for spherical AMD, which could result in a more massive bulge. After comparing the model predictions with our Milky Way galaxy, we find that the theoretical AMDs predict larger mass fractions of baryons with low angular momentum than the observed ones, which would lead to the disk sizes to be smaller. Two possible processes which could solve the angular momentum problem are discussed.

  17. Optimisation of surface passivation for highly reliable angular AMR sensors

    Energy Technology Data Exchange (ETDEWEB)

    Isler, M.; Christoffer, B.; Schoer, G.; Philippsen, B.; Mahnke, M.; Thorns, A.; Riethmueller, W.; Matz, H.; Tobescu, C. [NXP Semiconductors, Stresemannallee 101, 22529 Hamburg (Germany); Vanhelmont, F.; Wolters, R. [NXP Semiconductors, High Tech Campus 4, 5656 AE Eindhoven (Netherlands); Engelen, R.; Opran, A. [Philips Applied Technologies, High Tech Campus 7, 5656 AE Eindhoven (Netherlands); Stolk, P. [NXP Semiconductors, Gerstweg 2, 6534 AE Nijmegen (Netherlands)

    2010-02-15

    For state-of-the-art angular sensors based on the anisotropic magnetoresistive (AMR) effect in NiFe layers, the angular accuracy over time is limited by a drift of the offset voltage of the Wheatstone bridge configuration. It is shown that the interaction of the passivation layer and the magnetic permalloy is crucial for the drift of the offset voltage. By investigating the time and temperature dependence, the offset drift is attributed to stress relief of the PECVD passivation layer due to microstructural changes. Hydrogen outdiffusion from the passivation layer is involved in the observed stress evolution. It is demonstrated that optimising the passivation layer composition as well as the time of the subsequent annealing is beneficial for stress stabilisation of the permalloy-passivation layer system. With this optimised passivation layer a significant offset drift reduction of the NiFe Wheatstone bridge has been achieved resulting in highly accurate and long-term stable angular AMR sensors. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  18. Angular dependence of primordial trispectra and CMB spectral distortions

    Science.gov (United States)

    Shiraishi, Maresuke; Bartolo, Nicola; Liguori, Michele

    2016-10-01

    Under the presence of anisotropic sources in the inflationary era, the trispectrum of the primordial curvature perturbation has a very specific angular dependence between each wavevector that is distinguishable from the one encountered when only scalar fields are present, characterized by an angular dependence described by Legendre polynomials. We examine the imprints left by curvature trispectra on the TTμ bispectrum, generated by the correlation between temperature anisotropies (T) and chemical potential spectral distortions (μ) of the Cosmic Microwave Background (CMB). Due to the angular dependence of the primordial signal, the corresponding TTμ bispectrum strongly differs in shape from TTμ sourced by the usual gNL or τNL local trispectra, enabling us to obtain an unbiased estimation. From a Fisher matrix analysis, we find that, in a cosmic-variance-limited (CVL) survey of TTμ, a minimum detectable value of the quadrupolar Legendre coefficient is d2 ~ 0.01, which is 4 orders of magnitude better than the best value attainable from the TTTT CMB trispectrum. In the case of an anisotropic inflationary model with a f(phi)F2 interaction (coupling the inflaton field phi with a vector kinetic term F2), the size of the curvature trispectrum is related to that of quadrupolar power spectrum asymmetry, g*. In this case, a CVL measurement of TTμ makes it possible to measure g* down to 10‑3.

  19. Low Angular Momentum in Clumpy, Turbulent Disk Galaxies

    CERN Document Server

    Obreschkow, Danail; Bassett, Robert; Fisher, David B; Abraham, Roberto G; Wisnioski, Emily; Green, Andrew W; McGregor, Peter J; Damjanov, Ivana; Popping, Attila; Jorgensen, Inger

    2015-01-01

    We measure the stellar specific angular momentum jstar=Jstar/Mstar in four nearby (redshift z~0.1) disk galaxies that have stellar masses Mstar near the break M* of the galaxy mass function, but look like typical star-forming disks at z~2 in terms of their low stability (Q~1), clumpiness, high ionized gas dispersion (40-50 km/s), high molecular gas fraction (20-30%) and rapid star formation (~20 Msun/yr). Combining high-resolution (Keck-OSIRIS) and large-radius (Gemini-GMOS) spectroscopic maps, only available at low z, we discover that these targets have ~3 times less stellar angular momentum than typical local spiral galaxies of equal stellar mass and bulge fraction. Theoretical considerations show that this deficiency in angular momentum is the main cause of their low stability, while the high gas fraction plays a complementary role. Interestingly, the low jstar values of our targets are similar to those expected in the M*-population at higher z from the approximate theoretical scaling jstar~(1+z)^(-1/2) at...

  20. Wigner functions for the pair angle and orbital angular momentum

    Science.gov (United States)

    Kastrup, H. A.

    2016-12-01

    The problem of constructing physically and mathematically well-defined Wigner functions for the canonical pair angle θ and angular momentum p is solved. While a key element for the construction of Wigner functions for the planar phase space {(q ,p ) ∈R2} is the Heisenberg-Weyl group, the corresponding group for the cylindrical phase space {(θ ,p ) ∈S1×R } is the Euclidean group E (2 ) of the plane and its unitary representations. Here the angle θ is replaced by the pair (cosθ ,sinθ ) , which corresponds uniquely to the points on the unit circle. The main structural properties of the Wigner functions for the planar and the cylindrical phase spaces are strikingly similar. A crucial role is played by the s i n c function, which provides the interpolation for the discontinuous quantized angular momenta in terms of the continuous classical ones, in accordance with the famous Whittaker cardinal function well known from interpolation and sampling theories. The quantum mechanical marginal distributions for the angle (continuous) and angular momentum (discontinuous) are, as usual, uniquely obtained by appropriate integrations of the (θ ,p ) Wigner function. Among the examples discussed is an elementary system of simple cat states.

  1. Quark Orbital Angular Momentum in the MIT Bag Model

    CERN Document Server

    Courtoy, A

    2016-01-01

    We present the results for the Generalized Transverse Momentum Distribution related to quark Orbital Angular Momentum, {\\it i.e.} $F_{14}$, in the MIT bag model. This model has been modified to include the Peierls--Yoccoz projection to restore translational invariance. Such a modification allows to fulfill more satisfactorily basic sum rules, that would otherwise be less elegantly carried out with the original version. Using the same model, we have calculated the twist-$3$ GPD that corresponds to Orbital Angular Momentum \\`a la Ji, through the Penttinen--Polyakov--Shuvaev--Strikman sum rule. Recently, a new relation between the two definitions of the quark Orbital Angular Momentum at the density level has been proposed, which we illustrate here within the model. The sum rule is fulfilled. Still within the framework of the MIT bag model, we analyze the Wandzura--Wilczek expression for the GPD of interest. The genuine quark-gluon contribution is evaluated directly thanks to the equation of motion of the bag, wh...

  2. Statistical mechanics of collisionless orbits. IV. Distribution of angular momentum

    CERN Document Server

    Williams, Liliya L R; Wojtak, Radoslaw

    2014-01-01

    It has been shown in previous work that DARKexp, which is a theoretically derived, maximum entropy, one shape parameter model for isotropic collisionless systems, provides very good fits to simulated and observed dark-matter halos. Specifically, it fits the energy distribution, N(E), and the density profiles, including the central cusp. Here, we extend DARKexp N(E) to include the distribution in angular momentum, L^2, for spherically symmetric systems. First, we argue, based on theoretical, semi-analytical, and simulation results, that while dark-matter halos are relaxed in energy, they are not nearly as relaxed in angular momentum, which precludes using maximum entropy to uniquely derive N(E,L^2). Instead, we require that when integrating N(E,L^2) over squared angular momenta one retrieves the DARKexp N(E). Starting with a general expression for N(E,L^2) we show how the distribution of particles in L^2 is related to the shape of the velocity distribution function, VDF, and velocity anisotropy profile, \\beta(...

  3. A universal angular momentum profile for dark matter haloes

    CERN Document Server

    Liao, Shihong; Chu, M -C

    2016-01-01

    The angular momentum distribution in dark matter haloes and galaxies is a key ingredient in understanding their formation. Especially, the internal distribution of angular momenta is closely related to the formation of disk galaxies. In this article, we use haloes identified from a high-resolution simulation, the Bolshoi simulation, to study the spatial distribution of specific angular momenta, $j(r,\\theta)$. We show that by stacking haloes with similar masses to increase the signal-to-noise ratio, the profile can be fitted as a simple function, $j(r,\\theta)=j_s \\sin^2(\\theta/\\theta_s) (r/r_s)^2/(1+r/r_s)^4 $, with three free parameters, $j_s, r_s$, and $\\theta_s$. Specifically, $j_s$ correlates with the halo mass $M_\\mathrm{vir}$ as $j_s\\propto M_\\mathrm{vir}^{2/3}$, $r_s$ has a weak dependence on the halo mass as $r_s \\propto M_\\mathrm{vir}^{0.040}$, and $\\theta_s$ is independent of $M_\\mathrm{vir}$. This profile agrees with that from a rigid shell model, though its origin is unclear. Our universal specific...

  4. Angular Momentum Constraints on GMC formation in M33

    Science.gov (United States)

    Rosolowsky, E.; Engargiola, G.; Plambeck, R.; Blitz, L.

    2001-12-01

    We present the results of the complete CO 12CO(1-> 0) survey of the molecular gas in M33. These observations represent the first survey of all of the GMCs in a spiral galaxy; CO surveys of the Milky Way are too severely blended in some regions to separate the GMCs from one another. These observations show that individual molecular clouds share many properties with those found in the Milky Way although the most massive GMC in M33 has a mass of only 7x 105 Msun and is not associated with an Hii region. Moreover, the specific angular momentum of the GMCs is more than an order of magnitude smaller than expected for basic formation scenarios. The observational campaign consists of two parts: 1) a complete survey of the star forming disk which represents a complete census of GMCs down to the Taurus cloud mass at low spatial resolution and high surface brightness sensitivity and 2) high resolution follow-up observations which spatially resolve the molecular clouds providing information on rotation properties, virial masses, and morphology. From the latter, we estimate the angular momentum imparted through galactic shear by Jeans collapse, the Toomre instability and the Parker instability, all of which impart much more angular momentum to the clouds than is observed. We propose the magnetic fields that thread the molecular clouds and connect to the diffuse interstellar medium brake the spin-up of the progenitor gas, suggesting that the formation of GMCs is a magnetohydrodynamic process.

  5. Angular Fock coefficients. Fixing the errors, and further development

    CERN Document Server

    Liverts, Evgeny Z

    2015-01-01

    The angular coefficients $\\psi_{k,p}(\\alpha,\\theta)$ of the Fock expansion characterizing the S-state wave function of the two-electron atomic system, are calculated in hyperspherical angular coordinates $\\alpha$ and $\\theta$. To solve the problem the Fock recurrence relations separated into the independent individual equations associated with definite power $j$ of the nucleus charge $Z$, are applied. The "pure" $j$-components of the angular Fock coefficients, orthogonal to of the hyperspherical harmonics $Y_{kl}$, are found for even values of $k$. To this end, the specific coupling equation is proposed and applied. Effective techniques for solving the individual equations with simplest nonseparable and separable right-hand sides are proposed. Some mistakes/misprints made earlier in representations of $\\psi_{2,0}$, were noted and corrected. All $j$-components of $\\psi_{4,1}$ and the majority of components and subcomponents of $\\psi_{3,0}$ are calculated and presented for the first time. All calculations were ...

  6. Revisiting the WMAP - NVSS angular cross correlation. A skeptic view

    CERN Document Server

    Hernandez-Monteagudo, Carlos

    2009-01-01

    In the context of the study of the ISW, we revisit the angular cross correlation of WMAP CMB data with the NVSS radio survey. We compute 2-point cross functions between the two surveys in real and in Fourier space, paying particular attention on the dependence of results on the flux of NVSS radio sources, the angular scales where correlations arise and the comparison with theoretical expectations. We reproduce previous results that claim an excess of correlation in the angular correlation function (ACF), and we also find some (low significance) similarity between the CMB and radio galaxy data in the multipole range $\\el \\in $ [10, 25]. However, the S/N in the ACFs increases with higher flux thresholds for NVSS sources, but drops a $\\sim$ 30 - 50% in separations of the order of a pixel size, suggesting some residual point source contribution. When restricting our analyses to multipoles $\\el \\gt $60, we fail to find any evidence for cross correlation in the range $\\el \\in [2,10]$, where according to the model p...

  7. Time-delay Cosmography: Increased Leverage with Angular Diameter Distances

    CERN Document Server

    Jee, Inh; Suyu, Sherry H; Huterer, Dragan

    2015-01-01

    Strong lensing time-delay systems constrain cosmological parameters via the so-called time-delay distance and the angular diameter distance to the lens. In previous studies, only the former information was used. In this paper, we show that the cosmological constraints improve significantly when the latter information is also included. Specifically, the angular diameter distance plays a crucial role in breaking the degeneracy between the curvature of the Universe and the time-varying equation of state of dark energy. Using a mock sample of 55 bright quadruple lens systems based on expectations for ongoing/future imaging surveys, we find that adding the angular diameter distance information to the time-delay distance information and the cosmic microwave background data of Planck improves the constraint on the constant equation of state by 30%, on the time variation in the equation of state by a factor of two, and on the Hubble constant in the flat $\\Lambda$CDM model by a factor of two. Therefore, previous forec...

  8. Unsafe but Calculable: Ratios of Angularities in Perturbative QCD

    CERN Document Server

    Larkoski, Andrew J

    2013-01-01

    Infrared- and collinear-safe (IRC-safe) observables have finite cross sections to each fixed-order in perturbative QCD. Generically, ratios of IRC-safe observables are themselves not IRC safe and do not have a valid fixed-order expansion. Nevertheless, in this paper we present an explicit method to calculate the cross section for a ratio observable in perturbative QCD with the help of resummation. We take the IRC-safe jet angularities as an example and consider the ratio formed from two angularities with different angular exponents. While the ratio observable is not IRC safe, it is "Sudakov safe", meaning that the perturbative Sudakov factor exponentially suppresses the singular region of phase space. At leading logarithmic (LL) order, the distribution is finite but has a peculiar expansion in the square root of the strong coupling constant, a consequence of IRC unsafety. The accuracy of the LL distribution can be further improved with higher-order resummation and fixed-order matching. Non-perturbative effect...

  9. Reconstructing the galaxy redshift distribution from angular cross power spectra

    CERN Document Server

    Sun, L; Tao, C

    2015-01-01

    The control of photometric redshift (photo-$z$) errors is a crucial and challenging task for precision weak lensing cosmology. The spacial cross-correlations (equivalently, the angular cross power spectra) of galaxies between tomographic photo-$z$ bins are sensitive to the true redshift distribution $n_i(z)$ of each bin and hence can help calibrate the photo-$z$ error distribution for weak lensing surveys. Using Fisher matrix analysis, we investigate the contributions of various components of the angular power spectra to the constraints of $n_i(z)$ parameters and demonstrate the importance of the cross power spectra therein, especially when catastrophic photo-$z$ errors are present. We further study the feasibility of reconstructing $n_i(z)$ from galaxy angular power spectra using Markov Chain Monte Carlo estimation. Considering an LSST-like survey with $10$ photo-$z$ bins, we find that the underlying redshift distribution can be determined with a fractional precision ($\\sigma(\\theta)/\\theta$ for parameter $\\...

  10. Time-delay cosmography: increased leverage with angular diameter distances

    Science.gov (United States)

    Jee, I.; Komatsu, E.; Suyu, S. H.; Huterer, D.

    2016-04-01

    Strong lensing time-delay systems constrain cosmological parameters via the so-called time-delay distance and the angular diameter distance to the lens. In previous studies, only the former information was used in forecasting cosmographic constraints. In this paper, we show that the cosmological constraints improve significantly when the latter information is also included. Specifically, the angular diameter distance plays a crucial role in breaking the degeneracy between the curvature of the Universe and the time-varying equation of state of dark energy. Using a mock sample of 55 bright quadruple lens systems based on expectations for ongoing/future imaging surveys, we find that adding the angular diameter distance information to the time-delay distance information and the Planck's measurements of the cosmic microwave background anisotropies improves the constraint on the constant equation of state by 30%, on the time variation in the equation of state by a factor of two, and on the Hubble constant in the flat ΛCDM model by a factor of two. Therefore, previous forecasts for the statistical power of time-delay systems were overly pessimistic, i.e., time-delay systems are more powerful than previously appreciated.

  11. Energy and angular momentum deposition during Common envelope evolution

    Directory of Open Access Journals (Sweden)

    Noam Soker

    2004-01-01

    Full Text Available Tomo en consideraci on tres procesos que incrementan la tasa de p erdida de masa de la envolvente com un de una gigante de la secuencia principal o de una compa~nera enana blanca que se precipita en espiral dentro de su envolvente. Considero el dep osito de energ a orbital y momento angular orbital en la envolvente de la gigante y la formaci on de \\jets" por la compa~nera acreciente que se propagan dentro de la envolvente. Encuentro que en muchos casos el dep osito del momento angular en la envolvente puede ser m as importante para el proceso de p erdida de masa que el dep osito de energ a orbital. En etapas tempranas de la evoluci on com un de la envolvente los "jets" que son expulsados por una compa~nera acreciente, en particular una enana blanca que orbita dentro de las regiones exteriores de la envolvente de la gigante, tambi en pueden dominar sobre el dep osito de energ a. Esto implica que los estudios que ignoran el dep osito del momento angular dentro de la envolvente y los efectos de la compa~nera acreciente pueden llegar a conclusiones err oneas.

  12. Stiffness and Angular Deflection analysis of Revolute Manipulator

    Directory of Open Access Journals (Sweden)

    Pundru Srinivasa Rao

    2014-03-01

    Full Text Available This paper proposed to determine the Cartesian stiffness matrix and angular deflection analysis of revolute manipulator. The selected manipulator has rigid fixed link, two movable links and two rotary joints with joint stiffness coefficients are taken into account. The kinematic model of revolute joint manipulator has considered as a planar kinematic chain, which is composed by rigid fixed link and two revolute joints with clearance and deformable elements. The calculation of stiffness matrix depends on Jacobian matrix and change of configuration. The rotational joints are modeled as torsion springs with the same stiffness constant. The relative angular deflections are proportional to the actuated torques taken into account. The subject of this paper has to describe a method for stiffness analysis of serial manipulator. In the present work is to derive the stiffness matrix and angular deflection equations in the Robotic manipulator under the consideration of two-link optimum geometry model for rotary joint manipulator. The stiffness values are measured by displacements of its revolute links loaded by force.

  13. How we are building a complex Angular 2 application at Inspire

    CERN Document Server

    CERN. Geneva

    2017-01-01

    In this talk, at first we will talk about some basic and advanced Angular 2 concepts, then we will share our experiences with Angular 2 that we had so far while building a complex library and web applications at Inspire.

  14. Effects of Turbulent Aberrations on Probability Distribution of Orbital Angular Momentum for Optical Communication

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yi-Xin; CANG Ji

    2009-01-01

    Effects of atmospheric turbulence tilt, defocus, astigmatism and coma aberrations on the orbital angular mo-mentum measurement probability of photons propagating in weak turbulent regime are modeled with Rytov approximation. By considering the resulting wave as a superposition of angular momentum eigenstates, the or-bital angular momentum measurement probabilities of the transmitted digit axe presented. Our results show that the effect of turbulent tilt aberration on the orbital angular momentum measurement probabilities of photons is the maximum among these four kinds of aberrations. As the aberration order increases, the effects of turbulence aberrations on the measurement probabilities of orbital angular momentum generally decrease, whereas the effect of turbulence defoens can be ignored. For tilt aberration, as the difference between the measured orbital angular momentum and the original orbital angular momentum increases, the orbital angular momentum measurement probabifity decreases.

  15. Ligand inducible assembly of a DNA tetrahedron.

    Science.gov (United States)

    Dohno, Chikara; Atsumi, Hiroshi; Nakatani, Kazuhiko

    2011-03-28

    Here we show that a small synthetic ligand can be used as a key building component for DNA nanofabrication. Using naphthyridinecarbamate dimer (NCD) as a molecular glue for DNA hybridization, we demonstrate NCD-triggered formation of a DNA tetrahedron.

  16. Lanthanide complexes derived from hexadentate macrocyclic ligand: synthesis, spectroscopic and thermal investigation.

    Science.gov (United States)

    Chandra, Sulekh; Tyagi, Monika; Rani, Soni; Kumar, Sumit

    2010-02-01

    The lanthanide complexes derived from (3,5,13,15-tetramethyl 2,6,12,16,21-22-hexaazatricyclo[15.3.I(1-17)I(7-11)]cosa-1(21),2,5,7,9,11(22),12,15,17,19-decane) were synthesized. The complexes were found to have general composition [Ln(L)X(2).H(2)O]X, where Ln=La(3+), Ce(3+), Nd(3+), Sm(3+) and Eu(3+) and X=NO(3)(-) and Cl(-). The ligand was characterized by elemental analyses, IR, Mass, and (1)H NMR spectral studies. All the complexes were characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, Mass, electronic spectral techniques and thermal studies. The ligand acts as a hexadentate and coordinates through four nitrogen atoms of azomethine groups and two nitrogen of pyridine ring. The lanthanum complexes are diamagnetic while the other Ln(III) complexes are paramagnetic. The spectral parameters i.e. nephelauxetic ratio (beta), covalency factor (b(1/2)), Sinha parameter (delta%) and covalency angular overlap parameter (eta) have been calculated from absorption spectra of Nd(III) and Sm(III) complexes. These parameters suggest the metal-ligand covalent bonding. In the present study, the complexes were found to have coordination number nine.

  17. Nye ligander for Pt-MOF strukturer

    OpenAIRE

    Jakobsen, Søren

    2006-01-01

    Metalorganic frameworks (MOFs) are a new type of compounds which have been intensely investigated during the last few years. They have been synthesized using a wide variety of metals and ligands constructing a vast number of 1, 2 and 3 dimensional structures, some of which possess zeolite-type physics and chemistry. Our approach is to incorporate platinum metal sites into the structures making them bimetallic and potentially catalytically active. Therefore a number of N-N-type ligands (dii...

  18. Suppression of angular momentum transfer in cold collisions of transition metal atoms in ground States with nonzero orbital angular momentum.

    Science.gov (United States)

    Hancox, Cindy I; Doret, S Charles; Hummon, Matthew T; Krems, Roman V; Doyle, John M

    2005-01-14

    The Zeeman relaxation rate in cold collisions of Ti(3d(2)4s(2) 3F2) with He is measured. We find that collisional transfer of angular momentum is dramatically suppressed due to the presence of the filled 4s(2) shell. The degree of electronic interaction anisotropy, which is responsible for Zeeman relaxation, is estimated to be about 200 times smaller in the Ti-He complex than in He complexes with typical non-S-state atoms.

  19. Method for probing the orbital angular momentum of optical vortices in electromagnetic waves from astronomical objects.

    Science.gov (United States)

    Berkhout, Gregorius C G; Beijersbergen, Marco W

    2008-09-05

    We present an efficient method for probing the orbital angular momentum of optical vortices of arbitrary sizes. This method, based on a multipoint interferometer, has its most important application in measuring the orbital angular momentum of light from astronomical sources, opening the way to interesting new astrophysics. We demonstrate its viability by measuring the orbital angular momentum of Laguerre-Gaussian laser beams.

  20. Designer TGFβ superfamily ligands with diversified functionality.

    Directory of Open Access Journals (Sweden)

    George P Allendorph

    Full Text Available Transforming Growth Factor--beta (TGFβ superfamily ligands, including Activins, Growth and Differentiation Factors (GDFs, and Bone Morphogenetic Proteins (BMPs, are excellent targets for protein-based therapeutics because of their pervasiveness in numerous developmental and cellular processes. We developed a strategy termed RASCH (Random Assembly of Segmental Chimera and Heteromer, to engineer chemically-refoldable TGFβ superfamily ligands with unique signaling properties. One of these engineered ligands, AB208, created from Activin-βA and BMP-2 sequences, exhibits the refolding characteristics of BMP-2 while possessing Activin-like signaling attributes. Further, we find several additional ligands, AB204, AB211, and AB215, which initiate the intracellular Smad1-mediated signaling pathways more strongly than BMP-2 but show no sensitivity to the natural BMP antagonist Noggin unlike natural BMP-2. In another design, incorporation of a short N-terminal segment from BMP-2 was sufficient to enable chemical refolding of BMP-9, without which was never produced nor refolded. Our studies show that the RASCH strategy enables us to expand the functional repertoire of TGFβ superfamily ligands through development of novel chimeric TGFβ ligands with diverse biological and clinical values.

  1. Fully Flexible Docking of Medium Sized Ligand Libraries with RosettaLigand.

    Directory of Open Access Journals (Sweden)

    Samuel DeLuca

    Full Text Available RosettaLigand has been successfully used to predict binding poses in protein-small molecule complexes. However, the RosettaLigand docking protocol is comparatively slow in identifying an initial starting pose for the small molecule (ligand making it unfeasible for use in virtual High Throughput Screening (vHTS. To overcome this limitation, we developed a new sampling approach for placing the ligand in the protein binding site during the initial 'low-resolution' docking step. It combines the translational and rotational adjustments to the ligand pose in a single transformation step. The new algorithm is both more accurate and more time-efficient. The docking success rate is improved by 10-15% in a benchmark set of 43 protein/ligand complexes, reducing the number of models that typically need to be generated from 1000 to 150. The average time to generate a model is reduced from 50 seconds to 10 seconds. As a result we observe an effective 30-fold speed increase, making RosettaLigand appropriate for docking medium sized ligand libraries. We demonstrate that this improved initial placement of the ligand is critical for successful prediction of an accurate binding position in the 'high-resolution' full atom refinement step.

  2. LigandRFs: random forest ensemble to identify ligand-binding residues from sequence information alone

    KAUST Repository

    Chen, Peng

    2014-12-03

    Background Protein-ligand binding is important for some proteins to perform their functions. Protein-ligand binding sites are the residues of proteins that physically bind to ligands. Despite of the recent advances in computational prediction for protein-ligand binding sites, the state-of-the-art methods search for similar, known structures of the query and predict the binding sites based on the solved structures. However, such structural information is not commonly available. Results In this paper, we propose a sequence-based approach to identify protein-ligand binding residues. We propose a combination technique to reduce the effects of different sliding residue windows in the process of encoding input feature vectors. Moreover, due to the highly imbalanced samples between the ligand-binding sites and non ligand-binding sites, we construct several balanced data sets, for each of which a random forest (RF)-based classifier is trained. The ensemble of these RF classifiers forms a sequence-based protein-ligand binding site predictor. Conclusions Experimental results on CASP9 and CASP8 data sets demonstrate that our method compares favorably with the state-of-the-art protein-ligand binding site prediction methods.

  3. Synthesis and characterization of mixed ligand chiral nanoclusters

    KAUST Repository

    Guven, Zekiye P.

    2016-06-22

    Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. © 2016 The Royal Society of Chemistry.

  4. Orbital angular momentum of the laser beam and the second order intensity moments

    Institute of Scientific and Technical Information of China (English)

    高春清[1; 魏光辉[2; HorstWeber[3

    2000-01-01

    From the wave equation of a generalized beam the orbital angular momentum is studied. It is shown that the orbital angular momentum exists not only in the Laguerre-Gaussian beam, but in any beam with an angular-dependent structure. By calculating the second order intensity moments of the beam the relation between the orbital angular momentum and the second order moments 〈xθy〉, 〈yθx〉 is given. As an example the orbital angular momentum of the general astigmatic Gaussian beam is studied.

  5. Orbital angular momentum of the laser beam and the second order intensity moments

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    From the wave equation of a generalized beam the orbital angular momentum is studied. It is shown that the orbital angular momentum exists not only in the Laguerre_Gaussian beam,but in any beam with an angular_dependent structure. By calculating the second order intensity moments of the beam the relation between the orbital angular momentum and the second order moments 〈xθy〉, 〈yθx〉 is given. As an example the orbital angular momentum of the general astigmatic Gaussian beam is studied.

  6. Unidentified angular recurrent ulceration responsive to antiviral therapy

    Directory of Open Access Journals (Sweden)

    Rahmi Amtha

    2013-03-01

    Full Text Available Background: Recurrent ulcer on angular area is usually called stomatitis angularis. It is caused by many factors such as vertical dimension reduce, vitamin B12, and immune system deficiency, C. albicans and staphylococcus involvement. Clinically is characterized by painful fissure with erythematous base without fever. Purpose: to describe an unidentified angular ulcer proceeded by recurrent ulcers with no response of topical therapy. Case: An 18-years old male came to Oral Medicine clinic in RSCM who complained of angular recurrent ulcers since 3 years ago which developed on skin and bleed easily on mouth opening. Patient had fever before the onset of ulcers. Large, painful, irregular ulcers covered by red crustae on angular area bilaterally. Patient has been treated with various drugs without improvement and lead to mouth opening limitation. Intra oral shows herpetiformtype of ulcer and swollen of gingival. Case management: Provisional diagnosis was established as viral infection thus acyclovir 200 mg five times daily for two weeks and topical anti inflammation gel were administered. Blood test for IgG/IgM of HSV1 and HSV2 were non reactive, however ulceration showed a remarkable improvement. The ulcers healed completely after next 2 weeks with acyclovir. Conclusion: The angular ulceration on above patient failed to fulfill the criteria of stomatitis angularis or herpes labialis lesion. However it showed a good response to antiviral. Therefore, unidentified angular ulceration was appointed, as the lesion might be triggered by other type of human herpes virus or types of virus that response to acyclovir.Latar belakang: ulser rekuren pada sudut mulut biasanya disebut stomatitis angularis. Kelainan ini disebabkan oleh banyak faktor seperti berkurangnya dimensi vertikal, defisiensi vitamin B12 dan sistem kekebalan tubuh, infeksi C. albicans serta staphylococcus. Secara klinis kelainan ini ditandai dengan fisur sakit pada sudut mulut dengan dasar

  7. Spin O decay angular distribution for interfering mesons in electroproduction

    Energy Technology Data Exchange (ETDEWEB)

    Funsten, H.; Gilfoyle, G.

    1994-04-01

    Self analyzing meson electroproduction experiments are currently being planned for the CEBAF CLAS detector. These experiments deduce the spin polarization of outgoing unstable spin s (?)0 mesons from their decay angular distribution, W({theta},{psi}). The large angular acceptance of the CLAS detector permits kinematic tracking of a sufficient number of these events to accurately determine electroproduction amplitudes from the deduced polarization. Maximum polarization information is obtained from W({theta},{psi}) for decay into spin 0 daughters. The helicity of the decaying meson is transferred to the daughter`s relative orbital angular momentum m-projection; none is {open_quotes}absorbed{close_quotes} into daughter helicities. The decaying meson`s helicity maximally appears in W({theta},{psi}). W({theta},{psi}) for spin 0 daughters has been derived for (1) vector meson electroproduction and (2) general interfering mesons produced by incident pions. This paper derives W({theta},{psi}) for electroproduction of two interfering mesons that decay into spin 0 daughters. An application is made to the case of interfering scalar and vector mesons. The derivation is an extension of work by Schil using the general decay formalism of Martin. The expressions can be easily extended to the case of N interfering mesons since interference occurs pairwise in the observable W ({theta},{psi}), a quadratic function of the meson amplitudes. The derivation uses the virtual photon density matrix of Schil which is transformed by a meson electroproduction transition operator, T. The resulting density matrix for the interfering mesons is then converted into a corresponding statistical tensor and contracted into the efficiency tensor for spin 0 daughters.

  8. Angular momenta, dynamical masses, and mergers of brightest cluster galaxies

    Energy Technology Data Exchange (ETDEWEB)

    Jimmy; Tran, Kim-Vy [George P. and Cynthia W. Mitchell Institute for Fundamental Physics and Astronomy, Department of Physics and Astronomy, Texas A and M University, College Station, TX 77843 (United States); Brough, Sarah [Australian Astronomical Observatory, P.O. Box 915, North Ryde, NSW 1670 (Australia); Gebhardt, Karl [Department of Astronomy, University of Texas at Austin, 1 University Station C1400, Austin, TX 78712 (United States); Von der Linden, Anja [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, 452 Lomita Mall, Stanford, CA 94305-4085 (United States); Couch, Warrick J. [Centre for Astrophysics and Supercomputing, Swinburne University, P.O. Box 218, Hawthorn, VIC 3122 (Australia); Sharp, Rob [Research School of Astronomy and Astrophysics, Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia)

    2013-12-01

    Using the VIMOS integral field unit (IFU) spectrograph on the Very Large Telescope, we have spatially mapped the kinematic properties of 10 nearby brightest cluster galaxies (BCGs) and 4 BCG companion galaxies located within a redshift of z = 0.1. In the hierarchical formation model, these massive galaxies (10{sup 10.5} M {sub ☉} < M {sub dyn} < 10{sup 11.9} M {sub ☉}) are expected to undergo more mergers than lower mass galaxies, and simulations show that dry minor mergers can remove angular momentum. We test whether BCGs have low angular momenta by using the λ {sub Re} parameter developed by the SAURON and ATLAS{sup 3D} teams and combine our kinematics with Sloan Digital Sky Survey photometry to analyze the BCGs' merger status. We find that 30% (3/10) of the BCGs and 100% of the companion galaxies (4/4) are fast rotators as defined by the ATLAS{sup 3D} criteria. Our fastest rotating BCG has a λ {sub Re} = 0.35 ± 0.05. We increase the number of BCGs analyzed from 1 in the combined SAURON and ATLAS{sup 3D} surveys to 11 BCGs total and find that above M {sub dyn} ∼ 11.5 M {sub ☉}, virtually all galaxies, regardless of environment, are slow rotators. To search for signs of recent merging, we analyze the photometry of each system and use the G – M {sub 20} selection criteria to identify mergers. We find that 40% ± 20% of our BCGs are currently undergoing or have recently undergone a merger (within 0.2 Gyr). Surprisingly, we find no correlation between galaxies with high angular momentum and morphological signatures of merging.

  9. The vorticity and angular momentum budgets of Asian summer monsoon

    Indian Academy of Sciences (India)

    P L S Rao; U C Mohanty; P V S Raju; M A Arain

    2004-09-01

    The study delineates the vorticity and angular momentum balances of Asian summer monsoon during the evolution and established phases. It also elucidates the differences between these balances in the National Centre for Environmental Prediction/National Centre for Atmospheric Research (NCEP/NCAR) reanalysis and the National Centre for Medium Range Weather Forecasts (NCM- RWF) analysis fields. The NCEP/NCAR reanalysis for a 40 year period (1958-97) and the NCM- RWF analysis for a three year (1994-96) period are made use of for the purpose. The time mean summer monsoon circulation is bifurcated into stable mean and transient eddy components and the mean component is elucidated. The generation of vorticity due to stretching of isobars balances most of the vorticity transported out of the monsoon domain during the evolution period. However, during the established period, the transportation by the relative and planetary vorticity components exceeds the generation due to stretching. The effective balancing mechanism is provided by vorticity generation due to sub-grid scale processes. The flux convergence of omega and relative momenta over the monsoon domain is effectively balanced by pressure torque during the evolution and established phases. Nevertheless, the balance is stronger during the established period due to the increase in the strength of circulation. Both the NCMRWF and NCEP fields indicate the mean features related to vorticity and angular momentum budgets realistically. Apart from the oceanic bias (strong circulation over oceans rather than continents), the summer monsoon circulation indicated by the NCEP is feeble compared to NCMRWF. The significant terms in the large-scale budgets of vorticity and angular momentum enunciate this aspect.

  10. On the transformations generated by the electromagnetic spin and orbital angular momentum operators

    CERN Document Server

    Fernandez-Corbaton, Ivan; Molina-Terriza, Gabriel

    2013-01-01

    We present a study of the properties of the transversal "spin angular momentum" and "orbital angular momentum" operators. We show that the "spin angular momentum" operators are generators of spatial translations which depend on helicity and frequency and that the "orbital angular momentum" operators generate transformations which are a sequence of this kind of translations and rotations. We give some examples of the use of these operators in light matter interaction problems. Their relationship with the helicity operator allows to involve the electromagnetic duality symmetry in the analysis. We also find that simultaneous eigenstates of the three "spin" operators and parity define a kind of standing modes which have been recently singled out for the interaction of light with chiral molecules. With respect to the relationship between "spin angular momentum", polarization, and total angular momentum, we show that, except for the case of a single plane wave, the total angular momentum of a beam is decoupled from...

  11. Angular anisoplanatism of a focused beam using beacons over horizontal path

    Science.gov (United States)

    Wu, Wu-ming; Ning, Yu

    2016-01-01

    The performance of the achieve laser beam propagation through atmospheric turbulence with adaptive optics is degraded by the fact that the wavefront aberrations difference. This error is only include the angular anisoplanatism when there is separation between the achieve laser beam and beacon. In the paper we derive an analytic expression for the effective angular anisoplanatism as a function of displacement angular when the turbulence profile is uniform. It shows that the effective angular anisoplanatism becomes weaker as the diameter of laser beams and the Fried transverse coherence length increase. We report results from field experiments that the effective angular anisoplanatism of a focused beam over horizontal path. It is found that measured and theoretical results are consistent. The effective wavefront variance increases with the strength of atmospheric turbulence and the angular displacement. And the constant phase of angular anisoplanatism has no effect on the Strehl ratio of the beam.

  12. Systematics in Metallicity Gradient Measurements I : Angular Resolution, Signal-to-Noise and Annuli Binning

    CERN Document Server

    Yuan, T -T; Rich, J

    2013-01-01

    With the rapid progress in metallicity gradient studies at high-redshift, it is imperative that we thoroughly understand the systematics in these measurements. This work investigates how the [NII]/Halpha ratio based metallicity gradients change with angular resolution, signal-to-noise (S/N), and annular binning parameters. Two approaches are used: 1. We downgrade the high angular resolution integral-field data of a gravitationally lensed galaxy and re-derive the metallicity gradients at different angular resolution; 2. We simulate high-redshift integral field spectroscopy (IFS) observations under different angular resolution and S/N conditions using a local galaxy with a known gradient. We find that the measured metallicity gradient changes systematically with angular resolution and annular binning. Seeing-limited observations produce significantly flatter gradients than higher angular resolution observations. There is a critical angular resolution limit beyond which the measured metallicity gradient is subst...

  13. A Stern-Gerlach-like approach to electron orbital angular momentum measurement

    CERN Document Server

    Harvey, Tyler R

    2016-01-01

    Many methods now exist to prepare free electrons into orbital angular momentum states, and the predicted applications of these electron states as probes of materials and scattering processes are numerous. The development of electron orbital angular momentum measurement techniques has lagged behind. We show that coupling between electron orbital angular momentum and a spatially varying magnetic field produces an angular momentum-dependent focusing effect. We propose a design for an orbital angular momentum measurement device built on this principle. As the method of measurement is non-interferometric, the device works equally well for mixed, superposed and pure final orbital angular momentum states. The energy and orbital angular momentum distributions of inelastically scattered electrons may be simultaneously measurable with this technique.

  14. Photon Angular Distribution and Polarization of Radiative Recombination

    Institute of Scientific and Technical Information of China (English)

    OU Wei-Ying; SHEN Tian-Ming; CHEN Chong-Yang; Roger Hutton; ZOU Ya-Ming

    2005-01-01

    @@ A systematic study is carried out on the angular distribution and polarization of photons emitted following radiative-recombination of bare and He-like ions of Ne, Ar, Ni and Mo with a unidirectional electron beam. In order to incorporate the screening effect due to inner-shell electrons, a distorted wave method is used. Scaling rules for polarization of the photon following radiative recombination to both bare and He-like ions are given for the incident energy regions up to six times the ionization threshold energy of the final state.

  15. Manipulating atomic states via optical orbital angular-momentum

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Optical orbital angular-momentum(OAM)has more complex mechanics than the spin degree of photons,and may have a broad range of application.Manipulating atomic states via OAM has become an interesting topic.In this paper,we first review the general theory of generating adiabatic gauge field in ultracold atomic systems by coupling atoms to external optical fields with OAM,and point out the applications of the generated adiabatic gauge field.Then,we review our work in this field,including the generation of macroscopic superposition of vortex-antivortex states and spin Hall effect(SHE)in cold atoms.

  16. Controlled angular redirection of light via nanoimprinted disordered gratings

    DEFF Research Database (Denmark)

    Buss, Thomas; Teisseire, Jérémie; Mazoyer, Simon

    2013-01-01

    Enhanced control of diffraction through transparent substrates is achieved via disordered gratings in a silica sol–gel film. Tailoring the degree of disorder allows tuning of the diffractive behavior from discrete orders into broad distributions over large angular range. Gratings of optical quality...... are formed by silica sol–gel nanoimprint lithography and an optical setup for the measurement of continuous diffraction patterns is presented. Sound agreement is found between measurements and simulation, validating both the approach for redirection of light and the fabrication process. The disordered...

  17. Angular dynamics of a small particle in turbulence

    CERN Document Server

    Candelier, F; Mehlig, B

    2016-01-01

    We compute the angular dynamics of a neutrally buoyant nearly spherical particle immersed in an unsteady fluid. We assume that the particle is small, that its translational slip velocity is negligible, and that unsteady and convective inertia are small perturbations. We derive an approximation for the torque on the particle that determines the first inertial corrections to Jeffery's equation. These corrections arise as a consequence of local vortex stretching, and can be substantial in turbulence where local vortex stretching is strong and closely linked to the irreversibility of turbulence.

  18. Full angular analysis of polarized τ → 3 μ decays

    Energy Technology Data Exchange (ETDEWEB)

    Brueser, Robin; Faller, Sven; Feldmann, Thorsten; Lange, Bjoern O.; Mannel, Thomas [Theoretische Elementarteilchenphysik, Naturwissenschaftlich-technische Fakultaet, Universitaet Siegen, 57068 Siegen (Germany); Turczyk, Sascha [PRISMA Cluster of Excellence and Mainz Institut for Theoretical Physics, Johannes Gutenberg University, 55099 Mainz (Germany)

    2015-07-01

    The lepton number violating decay τ → 3 μ is extremely suppressed in the Standard Model and its observation would be direct evidence of New Physics. We investigate the decay of polarized τ leptons in a bottom-up approach using dim 6 operators which respect the symmetries of the Standard Model. We show that useful information can be gained from a polarized initial τ, where the external polarization vector allows for a full angular decomposition of the phase space. Partial rates are then analysed to distinguish models with different helicity structures.

  19. New model for holographic storage by simultaneous angular multiplexing

    Science.gov (United States)

    Ibarra, J. C.; Urzua, D.; Olivares-Peréz, A.; Ortiz-Gutierrez, M.

    2006-05-01

    We describe a technique for holographic storage by simultaneous angular multiplexing to obtain a large-scale holographic memory. We recorded 72 objects at the same time in one point on holographic plate PFG-03M from Slavich Co., using a He-Ne laser (λ = 633 nm). Each object is placed on a circular photographic transparency, separate 0.94 degree each one. The technique allows us simultaneous reconstruction of the 72 images without cross-talk. The diffraction efficiency obtained at order one is 6%. Experimental results are shown.

  20. Area-angular-momentum inequality for axisymmetric black holes.

    Science.gov (United States)

    Dain, Sergio; Reiris, Martin

    2011-07-29

    We prove the local inequality A≥8π|J|, where A and J are the area and angular momentum of any axially symmetric closed stable minimal surface in an axially symmetric maximal initial data. From this theorem it is proved that the inequality is satisfied for any surface on complete asymptotically flat maximal axisymmetric data. In particular it holds for marginal or event horizons of black holes. Hence, we prove the validity of this inequality for all dynamical (not necessarily near equilibrium) axially symmetric black holes.

  1. Angular Distribution of Photons in Coherent Bremsstrahlung in Deformed Crystals

    CERN Document Server

    Parazian, V V

    2010-01-01

    We investigate the angular distribution of photons in the coherent bremsstrahlung process by high-energy electrons in a periodically deformed single crystal with a complex base. The formula for the corresponding differential cross-section is derived for an arbitrary deformation field. The case is considered in detail when the electron enters into the crystal at small angles with respect to a crystallographic axis. The results of the numerical calculations are presented for SiO2 single crystal and Moliere parameterization of the screened atomic potentials in the case of the deformation field generated by the acoustic wave of S -type.

  2. Photons, phonons, and plasmons with orbital angular momentum in plasmas

    CERN Document Server

    Chen, Qiang; Liu, Jian

    2016-01-01

    Exact eigen modes with orbital angular momentum (OAM) in the complex media of unmagnetized homogeneous plasma are studied. Three exact eigen modes with OAM are discovered, i.e., photons, phonons, and plasmons. It is found that an OAM photon can be excited by two familiar Bessel modes without OAM. For the phonons and plasmons, their OAM are carried by the electrons and ions. The OAM modes in plasmas and their characteristics can be explored for various potential applications in plasma physics and accelerator physics.

  3. Angular distribution of 6He+p elastic scattering

    Institute of Scientific and Technical Information of China (English)

    LIU Xin; SU Jun; ZENG Sheng; YAN Sheng-Quan; LIAN Gang; HUANG Wu-Zhen; LIU Wei-Ping; WANG You-Bao; LI Zhi-Hong; JIN Sun-Jun; WANG Bao-Xiang; LI Yun-Ju; LI Er-Tao; BAI Xi-Xiang; GUO Bing

    2012-01-01

    The angular distribution of 1H(6He,p)6He elastic scattering has been measured at Ec.m.=4.3 MeV by using a thick-target inverse kinematic method.The experimental differential cross sections are reproduced by the distorted-wave Born approximation calculation utilizing the CH89 global optical potential parameter set.The real part of CH89 is reduced comparing with other potentials,which may be attributed to the couplings necessary for the weakly bound nuclei.

  4. Measuring the Orbital Angular Momentum of Electron Beams

    CERN Document Server

    Guzzinati, Giulio; Béché, Armand; Verbeeck, Jo

    2014-01-01

    The recent demonstration of electron vortex beams has opened up the new possibility of studying orbital angular momentum (OAM) in the interaction between electron beams and matter. To this aim, methods to analyze the OAM of an electron beam are fundamentally important and a necessary next step. We demonstrate the measurement of electron beam OAM through a variety of techniques. The use of forked holographic masks, diffraction from geometric apertures, diffraction from a knife-edge and the application of an astigmatic lens are all experimentally demonstrated. The viability and limitations of each are discussed with supporting numerical simulations.

  5. ROTATING RINDLER SPACE TIME WITH CONSTANT ANGULAR VELOCITY

    Institute of Scientific and Technical Information of China (English)

    WANG YONG-CHENG

    2000-01-01

    A new space time metric is derived from Kerr metric if its mass and location approach to infinite in an appropriate way. The new space-time is an infinitesimal neighborhood nearby one of the two horizon poles of an infinite Kerr black hole. In other words, it is the second order infinitesimal neighborhood nearby one of the two horizon poles of a Kerr black hole. It is fiat and has event horizon and infinite red shift surface. We prove that it is a rotating Rindler space time with constant angular velocity.

  6. Measurements of electron density profiles using an angular filter refractometer

    Energy Technology Data Exchange (ETDEWEB)

    Haberberger, D., E-mail: dhab@lle.rochester.edu; Ivancic, S.; Hu, S. X.; Boni, R.; Barczys, M.; Craxton, R. S.; Froula, D. H. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14636 (United States)

    2014-05-15

    A novel diagnostic technique, angular filter refractometry (AFR), has been developed to characterize high-density, long-scale-length plasmas relevant to high-energy-density physics experiments. AFR measures plasma densities up to 10{sup 21} cm{sup −3} with a 263-nm probe laser and is used to study the plasma expansion from CH foil and spherical targets that are irradiated with ∼9 kJ of ultraviolet (351-nm) laser energy in a 2-ns pulse. The data elucidate the temporal evolution of the plasma profile for the CH planar targets and the dependence of the plasma profile on target radius for CH spheres.

  7. Energy and angular momentum sharing in dissipative collisions

    CERN Document Server

    Casini, G; Calamai, S; Laforest, R; Maurenzig, P R; Olmi, A; Pasquali, G; Piantelli, S; Poggi, G; Saint-Laurent, F; Steckmeyer, J C; Stefanini, A A; Taccetti, N

    2000-01-01

    Primary and secondary masses of heavy reaction products have been deduced from kinematics and E-ToF measurements, respectively, for the direct and reverse collisions of 93Nb and 116Sn at 25 AMeV. Light charged particles have also been measured in coincidence with the heavy fragments. Direct experimental evidence of the correlation of energy-sharing with net mass transfer has been found using the information from both the heavy fragments and the light charged particles. The ratio of Hydrogen and Helium multiplicities points to a further correlation of angular momentum sharing with net mass transfer.

  8. Energy and angular momentum sharing in dissipative collisions

    Science.gov (United States)

    Casini, G.; Bini, M.; Calamai, S.; Laforest, R.; Maurenzig, P. R.; Olmi, A.; Pasquali, G.; Piantelli, S.; Poggi, G.; Saint-Laurent, F.; Steckmeyer, J. C.; Stefanini, A. A.; Taccetti, N.

    Primary and secondary masses of heavy reaction products have been deduced from kinematics and E-ToF measurements, respectively, for the direct and reverse collisions of 93Nb and 116Sn at 25 AMeV. Light charged particles have also been measured in coincidence with the heavy fragments. Direct experimental evidence of the correlation of energy-sharing with net mass transfer has been found using information from both the heavy fragments and the light charged particles. The ratio of hydrogen and helium multiplicities points to a further correlation of angular momentum sharing with net mass transfer.

  9. Energy and angular momentum sharing in dissipative collisions

    Energy Technology Data Exchange (ETDEWEB)

    Casini, G.; Bini, M.; Calamai, S.; Maurenzig, P.R.; Olmi, A.; Pasquali, G.; Piantelli, S.; Poggi, G.; Stefanini, A.A.; Taccetti, N. [Istituto Nazionale di Fisica Nucleare, Florence (Italy); Laforest, R.; Steckmeyer, J.C. [Caen Univ., 14 (France). Lab. de Physique Corpusculaire; Saint-Laurent, F. [Grand Accelerateur National d' Ions Lourds (GANIL), 14 - Caen (France)

    2000-12-01

    Primary and secondary masses of heavy reaction products have been deduced from kinematics and E-ToF measurements, respectively, for the direct and reverse collisions of {sup 93}Nb and {sup 116}Sn at 25 AMeV. Light charged particles have also been measured in coincidence with the heavy fragments. Direct experimental evidence of the correlation of energy-sharing with net mass transfer has been found using information from both the heavy fragments and the light charged particles. The ratio of hydrogen and helium multiplicities points to a further correlation of angular momentum sharing with net mass transfer. (orig.)

  10. Supermode fiber for orbital angular momentum (OAM) transmission.

    Science.gov (United States)

    Li, Shuhui; Wang, Jian

    2015-07-13

    We present a multi-orbital-angular-momentum (OAM) multi-core supermode fiber (MOMCSF) to transmit OAM modes. The MOMCSF consists of equally-spaced and circularly-arranged multiple cores, in which the core pitch is small enough to support strong coupling OAM supermodes. The characteristics of OAM modes in MOMCSFs with different core pitches and core numbers are analyzed. The performances of mode coupling and nonlinearity are optimized by designing multiple degrees of freedom of the supermode fiber. The obtained results show that the designed MOMCSF can transmit multiple OAM modes with favorable performance of low mode coupling, low nonlinearity, and low modal dependent loss.

  11. Quantum Nuclear Pasta Calculations with Twisted Angular Boundary Conditions

    Science.gov (United States)

    Schuetrumpf, Bastian; Nazarewicz, Witold

    2015-10-01

    Nuclear pasta, expected to be present in the inner crust of neutron stars and core collapse supernovae, can contain a wide spectrum of different exotic shapes such as nuclear rods and slabs. There are also more complicated, network-like structures, the triply periodic minimal surfaces, already known e.g. in biological systems. These shapes are studied with the Hartree-Fock method using modern Skyrme forces. Furthermore twisted angular boundary conditions are utilized to reduce finite size effects in the rectangular simulation boxes. It is shown, that this improves the accuracy of the calculations drastically and additionally more insights into the mechanism of forming minimal surfaces can be gained.

  12. Energy and Angular Momentum Deposition During Common Envelope Evolution

    OpenAIRE

    2003-01-01

    Tomo en consideraci on tres procesos que incrementan la tasa de p erdida de masa de la envolvente com un de una gigante de la secuencia principal o de una compa~nera enana blanca que se precipita en espiral dentro de su envolvente. Considero el dep osito de energ a orbital y momento angular orbital en la envolvente de la gigante y la formaci on de \\jets" por la compa~nera acreciente que se propagan dentro de la envolvente. Encuentro que en muchos casos el dep osito del momento an...

  13. Engineering of orbital angular momentum supermodes in coupled optical waveguides

    CERN Document Server

    Turpin, A; Polo, J; Mompart, J; Ahufinger, V

    2016-01-01

    In this work we demonstrate the existence of orbital angular momentum (OAM) bright and dark supermodes in a three-evanescent coupled cylindrical waveguides system. Bright and dark supermodes are characterized by its coupling and decoupling from one of the waveguides, respectively. In addition, we demonstrate that complex couplings between modes of different waveguides appear naturally due to the characteristic spiral phase-front of OAM modes in two-dimensional configurations where the waveguides are arranged forming a triangle. Finally, by adding dissipation to the waveguide uncoupled to the dark supermode, we are able to filter it out, allowing for the design of OAM mode clonners and inverters.

  14. Light beams with orbital angular momentum for free space optics

    Institute of Scientific and Technical Information of China (English)

    Wu Jing-Zhi; Li Yang-Jun

    2007-01-01

    The light's orbital angular momentum (OAM) is a consequence of the spiral flow of the electromagnetic energy. In this paper, an analysis of light beams with OAM used for free space optics (FSO) is conducted. The basic description and conception of light's OAM are reviewed. Both encoding information into OAM states of single light beam and encoding information into spatial structure of the mixed optical vortex with OAM are discussed, and feasibility to improve the FSO's performance of security and obstruction of line of sight is examined.

  15. Effect of higher orbital angular momenta in the baryon spectrum

    CERN Document Server

    Garcilazo, H; Fernández, F

    2001-01-01

    We have performed a Faddeev calculation of the baryon spectrum for the chiral constituent quark model including higher orbital angular momentum states. We have found that the effect of these states is important, although a description of the baryon spectrum of the same quality as the one given by including only the lowest-order configurations can be obtained. We have studied the effect of the pseudoscalar quark-quark interaction on the relative position of the positive- and negative-parity excitations of the nucleon as well as the effect of varying the strength of the color-magnetic interaction.

  16. Photons, phonons, and plasmons with orbital angular momentum in plasmas

    Science.gov (United States)

    Chen, Qiang; Qin, Hong; Liu, Jian

    2017-01-01

    Exact eigen modes with orbital angular momentum (OAM) in the complex media of unmagnetized homogeneous plasmas are studied. Three exact eigen modes with OAM are derived, i.e., photons, phonons, and plasmons. The OAM of different plasma components are closely related to the charge polarities. For photons, the OAM of electrons and ions are of the same magnitude but opposite direction, and the total OAM is carried by the field. For the phonons and plasmons, their OAM are carried by the electrons and ions. The OAM modes in plasmas and their characteristics can be explored for potential applications in plasma physics and accelerator physics. PMID:28164998

  17. Correlation steering in the angularly multimode Raman atomic memory.

    Science.gov (United States)

    Mazelanik, Mateusz; Dąbrowski, Michał; Wasilewski, Wojciech

    2016-09-19

    We present the possibility of steering the direction of correlations between the off-resonant Raman scattered photons from the angularly multimode atomic memory based on warm rubidium vapors. Using acousto-optic deflectors (AOD) driven by different modulation frequencies, we experimentally change the angle of incidence of the laser beams on the atomic ensemble. By performing correlation measurements for various deflection angles, we verify that we can choose the anti-Stokes light propagation direction independently of the correlated Stokes scattered light in a continuous way. As a result we can select the spatial mode of photons retrieved from the memory, which may be important for future development of quantum information processing.

  18. Immobilisation of ligands by radio-derivatized polymers; Immobilisering av ligander med radioderiverte polymerer

    Energy Technology Data Exchange (ETDEWEB)

    Varga, J.M.; Fritsch, P.

    1995-01-30

    The invention relates to radio-derivatized polymers and a method of producing them by contacting non-polymerizable conjugands with radiolysable polymers in the presence of irradiation. The resulting radio-derivatized polymers can be further linked with ligand of organic or inorganic nature to immobilize such ligands. 2 figs., 5 tabs.

  19. Multiple ligand simultaneous docking: orchestrated dancing of ligands in binding sites of protein.

    Science.gov (United States)

    Li, Huameng; Li, Chenglong

    2010-07-30

    Present docking methodologies simulate only one single ligand at a time during docking process. In reality, the molecular recognition process always involves multiple molecular species. Typical protein-ligand interactions are, for example, substrate and cofactor in catalytic cycle; metal ion coordination together with ligand(s); and ligand binding with water molecules. To simulate the real molecular binding processes, we propose a novel multiple ligand simultaneous docking (MLSD) strategy, which can deal with all the above processes, vastly improving docking sampling and binding free energy scoring. The work also compares two search strategies: Lamarckian genetic algorithm and particle swarm optimization, which have respective advantages depending on the specific systems. The methodology proves robust through systematic testing against several diverse model systems: E. coli purine nucleoside phosphorylase (PNP) complex with two substrates, SHP2NSH2 complex with two peptides and Bcl-xL complex with ABT-737 fragments. In all cases, the final correct docking poses and relative binding free energies were obtained. In PNP case, the simulations also capture the binding intermediates and reveal the binding dynamics during the recognition processes, which are consistent with the proposed enzymatic mechanism. In the other two cases, conventional single-ligand docking fails due to energetic and dynamic coupling among ligands, whereas MLSD results in the correct binding modes. These three cases also represent potential applications in the areas of exploring enzymatic mechanism, interpreting noisy X-ray crystallographic maps, and aiding fragment-based drug design, respectively.

  20. Organotellurium ligands - designing and complexation reactions

    Indian Academy of Sciences (India)

    Ajai K Singh

    2002-08-01

    A variety of tellurium ligands has been designed and studied for their complexation reactions in the last decade. Of these hybrid telluroethers, halotellurium ligands and polytellurides are the most notable ones. RTe- and polytelluride ions have also been used to design clusters. Ligation of ditelluroethers and several hybrid telluroethers is extensively studied in our laboratories. The ditelluroether ligand RTeCH2TeR (where R = 4-MeOC6H4) (1), similar to dppm [1,2-bis(diphenylphosphino) methane], has been synthesized in good yield (∼80 %) by reacting CHCl3 with RTe- (generated in situ by borohydride reduction of R2Te2). Iodine reacts with 1 to give tetra-iodo derivative, which has intermolecular Te$\\cdots$I interactions resulting in a macro structure containing rectangular Te-I$\\cdots$Te bridges. 1 readily forms four membered rings with Pd(II) and Ru(II). On the formation of this chelate ring, the signal in 125Te NMR spectra shifts significantly upfield (50-60 ppm). The bridging mode of 1 has been shown in [Ru(-cymene)Cl2](-1)[Ru(-cymene)Cl2]. The hybrid telluroether ligands explored are of the types (Te, S), (Te, N) and (Te, O). The tellurium donor site has strong trans influence, which is manifested more strongly in square planar complexes of palladium(II). The morpholine N-donor site has been found to have weaker donor characteristics in (Te, N) ligands than pyridine and alkylamine donor sites of analogous ligands. The singlet oxygen readily oxidises the coordinated Te. This oxidation follows first order kinetics. The complexation reaction of RuCl3.H2O with N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (2) results in a novel (Te, N, O)-heterocycle, Te-chloro,Te-anisyl-1a-aza-4-oxa-3-tellura-1H, 2H, 4aH-9 fluorenone. The (Te, O) ligands can be used as hemilabile ligands, the oxygen atom temporarily protects the vacant coordination site before the arrival of the substrate. The chelate shifts observed in 125Te NMR spectra of metal complexes of Te-ligands have